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Sample records for tru waste drum

  1. MCNP Modeling Results for Location of Buried TRU Waste Drums

    International Nuclear Information System (INIS)

    Steinman, D K; Schweitzer, J S

    2006-01-01

    In the 1960's, fifty-five gallon drums of TRU waste were buried in shallow pits on remote U.S. Government facilities such as the Idaho National Engineering Laboratory (now split into the Idaho National Laboratory and the Idaho Completion Project [ICP]). Subsequently, it was decided to remove the drums and the material that was in them from the burial pits and send the material to the Waste Isolation Pilot Plant in New Mexico. Several technologies have been tried to locate the drums non-intrusively with enough precision to minimize the chance for material to be spread into the environment. One of these technologies is the placement of steel probe holes in the pits into which wireline logging probes can be lowered to measure properties and concentrations of material surrounding the probe holes for evidence of TRU material. There is also a concern that large quantities of volatile organic compounds (VOC) are also present that would contaminate the environment during removal. In 2001, the Idaho National Engineering and Environmental Laboratory (INEEL) built two pulsed neutron wireline logging tools to measure TRU and VOC around the probe holes. The tools are the Prompt Fission Neutron (PFN) and the Pulsed Neutron Gamma (PNG), respectively. They were tested experimentally in surrogate test holes in 2003. The work reported here estimates the performance of the tools using Monte-Carlo modelling prior to field deployment. A MCNP model was constructed by INEEL personnel. It was modified by the authors to assess the ability of the tools to predict quantitatively the position and concentration of TRU and VOC materials disposed around the probe holes. The model was used to simulate the tools scanning the probe holes vertically in five centimetre increments. A drum was included in the model that could be placed near the probe hole and at other locations out to forty-five centimetres from the probe-hole in five centimetre increments. Scans were performed with no chlorine in the

  2. Final environmental assessment: TRU waste drum staging building, Technical Area 55, Los Alamos National Laboratory

    International Nuclear Information System (INIS)

    1996-01-01

    Much of the US Department of Energy's (DOE's) research on plutonium metallurgy and plutonium processing is performed at Los Alamos National Laboratory (LANL), in Los Alamos, New Mexico. LANL's main facility for plutonium research is the Plutonium Facility, also referred to as Technical Area 55 (TA-55). The main laboratory building for plutonium work within the Plutonium Facility (TA-55) is the Plutonium Facility Building 4, or PF-4. This Environmental Assessment (EA) analyzes the potential environmental effects that would be expected to occur if DOE were to stage sealed containers of transuranic (TRU) and TRU mixed waste in a support building at the Plutonium Facility (TA-55) that is adjacent to PF-4. At present, the waste containers are staged in the basement of PF-4. The proposed project is to convert an existing support structure (Building 185), a prefabricated metal building on a concrete foundation, and operate it as a temporary staging facility for sealed containers of solid TRU and TRU mixed waste. The TRU and TRU mixed wastes would be contained in sealed 55-gallon drums and standard waste boxes as they await approval to be transported to TA-54. The containers would then be transported to a longer term TRU waste storage area at TA-54. The TRU wastes are generated from plutonium operations carried out in PF-4. The drum staging building would also be used to store and prepare for use new, empty TRU waste containers

  3. Performance Demonstration Program Plan for Nondestructive Assay of Drummed Wastes for the TRU Waste Characterization Program

    International Nuclear Information System (INIS)

    2005-01-01

    The Performance Demonstration Program (PDP) for Nondestructive Assay (NDA) is a test program designed to yield data on measurement system capability to characterize drummed transuranic (TRU) waste generated throughout the Department of Energy (DOE) complex. The tests are conducted periodically and provide a mechanism for the independent and objective assessment of NDA system performance and capability relative to the radiological characterization objectives and criteria of the Office of Characterization and Transportation (OCT). The primary documents requiring an NDA PDP are the Waste Acceptance Criteria for the Waste Isolation Pilot Plant (WAC), which requires annual characterization facility participation in the PDP, and the Quality Assurance Program Document (QAPD). This NDA PDP implements the general requirements of the QAPD and applicable requirements of the WAC. Measurement facilities must demonstrate acceptable radiological characterization performance through measurement of test samples comprised of pre-specified PDP matrix drum/radioactive source configurations. Measurement facilities are required to analyze the NDA PDP drum samples using the same procedures approved and implemented for routine operational waste characterization activities. The test samples provide an independent means to assess NDA measurement system performance and compliance per criteria delineated in the NDA PDP Plan. General inter-comparison of NDA measurement system performance among DOE measurement facilities and commercial NDA services can also be evaluated using measurement results on similar NDA PDP test samples. A PDP test sample consists of a 55-gallon matrix drum containing a waste matrix type representative of a particular category of the DOE waste inventory and nuclear material standards of known radionuclide and isotopic composition typical of DOE radioactive material. The PDP sample components are made available to participating measurement facilities as designated by the

  4. Characterization of void volume VOC concentration in vented TRU waste drums - an interim report

    International Nuclear Information System (INIS)

    Liekhus, K.J.

    1994-09-01

    A test program is underway at the Idaho National Engineering Laboratory to determine if the concentration of volatile organic compounds (VOCs) in the drum headspace is representative of the VOC concentration in the entire drum void space and to demonstrate that the VOC concentration in the void space of each layer of confinement can be estimated using a model incorporating diffusion and permeation transport principles and limited waste drum sampling data. An experimental test plan was developed requiring gas sampling of 66 transuranic (TRU) waste drums. This interim report summarizes the experimental measurements and model predictions of VOC concentration in the innermost layer of confinement from waste drums sampled and analyzed in FY 1994

  5. Performance Demonstration Program Plan for Nondestructive Assay of Drummed Wastes for the TRU Waste Characterization Program

    International Nuclear Information System (INIS)

    DOE Carlsbad Field Office

    2001-01-01

    The Performance Demonstration Program (PDP) for nondestructive assay (NDA) consists of a series of tests to evaluate the capability for NDA of transuranic (TRU) waste throughout the Department of Energy (DOE) complex. Each test is termed a PDP cycle. These evaluation cycles provide an objective measure of the reliability of measurements obtained from NDA systems used to characterize the radiological constituents of TRU waste. The primary documents governing the conduct of the PDP are the Waste Acceptance Criteria for the Waste Isolation Pilot Plant (WAC; DOE 1999a) and the Quality Assurance Program Document (QAPD; DOE 1999b). The WAC requires participation in the PDP; the PDP must comply with the QAPD and the WAC. The WAC contains technical and quality requirements for acceptable NDA. This plan implements the general requirements of the QAPD and applicable requirements of the WAC for the NDA PDP. Measurement facilities demonstrate acceptable performance by the successful testing of simulated waste containers according to the criteria set by this PDP Plan. Comparison among DOE measurement groups and commercial assay services is achieved by comparing the results of measurements on similar simulated waste containers reported by the different measurement facilities. These tests are used as an independent means to assess the performance of measurement groups regarding compliance with established quality assurance objectives (QAO's). Measurement facilities must analyze the simulated waste containers using the same procedures used for normal waste characterization activities. For the drummed waste PDP, a simulated waste container consists of a 55-gallon matrix drum emplaced with radioactive standards and fabricated matrix inserts. These PDP sample components are distributed to the participating measurement facilities that have been designated and authorized by the Carlsbad Field Office (CBFO). The NDA Drum PDP materials are stored at these sites under secure conditions to

  6. TRU drum corrosion task team report

    Energy Technology Data Exchange (ETDEWEB)

    Kooda, K.E.; Lavery, C.A.; Zeek, D.P.

    1996-05-01

    During routine inspections in March 1996, transuranic (TRU) waste drums stored at the Radioactive Waste Management Complex (RWMC) were found with pinholes and leaking fluid. These drums were overpacked, and further inspection discovered over 200 drums with similar corrosion. A task team was assigned to investigate the problem with four specific objectives: to identify any other drums in RWMC TRU storage with pinhole corrosion; to evaluate the adequacy of the RWMC inspection process; to determine the precise mechanism(s) generating the pinhole drum corrosion; and to assess the implications of this event for WIPP certifiability of waste drums. The task team investigations analyzed the source of the pinholes to be Hcl-induced localized pitting corrosion. Hcl formation is directly related to the polychlorinated hydrocarbon volatile organic compounds (VOCs) in the waste. Most of the drums showing pinhole corrosion are from Content Code-003 (CC-003) because they contain the highest amounts of polychlorinated VOCs as determined by headspace gas analysis. CC-001 drums represent the only other content code with a significant number of pinhole corrosion drums because their headspace gas VOC content, although significantly less than CC-003, is far greater than that of the other content codes. The exact mechanisms of Hcl formation could not be determined, but radiolytic and reductive dechlorination and direct reduction of halocarbons were analyzed as the likely operable reactions. The team considered the entire range of feasible options, ranked and prioritized the alternatives, and recommended the optimal solution that maximizes protection of worker and public safety while minimizing impacts on RWMC and TRU program operations.

  7. TRU drum corrosion task team report

    International Nuclear Information System (INIS)

    Kooda, K.E.; Lavery, C.A.; Zeek, D.P.

    1996-05-01

    During routine inspections in March 1996, transuranic (TRU) waste drums stored at the Radioactive Waste Management Complex (RWMC) were found with pinholes and leaking fluid. These drums were overpacked, and further inspection discovered over 200 drums with similar corrosion. A task team was assigned to investigate the problem with four specific objectives: to identify any other drums in RWMC TRU storage with pinhole corrosion; to evaluate the adequacy of the RWMC inspection process; to determine the precise mechanism(s) generating the pinhole drum corrosion; and to assess the implications of this event for WIPP certifiability of waste drums. The task team investigations analyzed the source of the pinholes to be Hcl-induced localized pitting corrosion. Hcl formation is directly related to the polychlorinated hydrocarbon volatile organic compounds (VOCs) in the waste. Most of the drums showing pinhole corrosion are from Content Code-003 (CC-003) because they contain the highest amounts of polychlorinated VOCs as determined by headspace gas analysis. CC-001 drums represent the only other content code with a significant number of pinhole corrosion drums because their headspace gas VOC content, although significantly less than CC-003, is far greater than that of the other content codes. The exact mechanisms of Hcl formation could not be determined, but radiolytic and reductive dechlorination and direct reduction of halocarbons were analyzed as the likely operable reactions. The team considered the entire range of feasible options, ranked and prioritized the alternatives, and recommended the optimal solution that maximizes protection of worker and public safety while minimizing impacts on RWMC and TRU program operations

  8. Characterization of voic volume VOC concentration in vented TRU waste drums. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Liekhus, K.J.

    1994-12-01

    A test program has been conducted at the Idaho National Engineering Laboratory to demonstrate that the concentration of volatile organic compounds within the innermost layer of confinement in a vented waste drum can be estimated using a model incorporating diffusion and permeation transport principles and limited waste drum sampling data. This final report summarizes the experimental measurements and model predictions for transuranic waste drums containing solidified sludges and solid waste.

  9. A model of gas generation and transport within TRU [transuranic] waste drums

    International Nuclear Information System (INIS)

    Smith, F.G. III.

    1987-01-01

    Gas generation from the radiolytic decomposition of organic material contaminated with plutonium is modeled. Concentrations of gas throughout the waste drum are determined using a diffusional transport model. The model accurately reproduces experimentally measured gas concentrations. With polyethylene waste in unvented drums, the model predicts that hydrogen gas can accumulate to concentrations greater than 4 mole percent (lower flammable limit) with about 5 Ci of plutonium. Polyethylene provides a worst case for combustible waste material. If the drum liner is punctured and a carbon composite filter vent is installed in the drum lid, the plutonium loading can be increased to 240 Ci without generating flammable gas mixtures. 5 refs., 7 figs., 4 tabs

  10. Performance Demonstration Program Plan for Nondestructive Assay of Drummed Wastes for the TRU Waste Characterization Program

    International Nuclear Information System (INIS)

    2009-01-01

    Each testing and analytical facility performing waste characterization activities for the Waste Isolation Pilot Plant (WIPP) participates in the Performance Demonstration Program (PDP) to comply with the Transuranic Waste Acceptance Criteria for the Waste Isolation Pilot Plant (WAC) (DOE/WIPP-02-3122) and the Quality Assurance Program Document (QAPD) (CBFO-94-1012). The PDP serves as a quality control check for data generated in the characterization of waste destined for WIPP. Single blind audit samples are prepared and distributed to each of the facilities participating in the PDP. The PDP evaluates analyses of simulated headspace gases, constituents of the Resource Conservation and Recovery Act (RCRA), and transuranic (TRU) radionuclides using nondestructive assay (NDA) techniques.

  11. Status of ERDA TRU waste packaging study

    International Nuclear Information System (INIS)

    Doty, J.W. Jr.

    1977-01-01

    This paper discusses the status of Task 3 of the TRU Waste Cyclone Drum Incinerator and Treatment System program. This task covers acceptable TRU packaging for interim storage and terminal isolation. The kind of TRU wastes generated by contractors and its transport are discussed. Both drum and box systems are desirable

  12. TRU waste-sampling program

    International Nuclear Information System (INIS)

    Warren, J.L.; Zerwekh, A.

    1985-08-01

    As part of a TRU waste-sampling program, Los Alamos National Laboratory retrieved and examined 44 drums of 238 Pu- and 239 Pu-contaminated waste. The drums ranged in age from 8 months to 9 years. The majority of drums were tested for pressure, and gas samples withdrawn from the drums were analyzed by a mass spectrometer. Real-time radiography and visual examination were used to determine both void volumes and waste content. Drum walls were measured for deterioration, and selected drum contents were reassayed for comparison with original assays and WIPP criteria. Each drum tested at atmospheric pressure. Mass spectrometry revealed no problem with 239 Pu-contaminated waste, but three 8-month-old drums of 238 Pu-contaminated waste contained a potentially hazardous gas mixture. Void volumes fell within the 81 to 97% range. Measurements of drum walls showed no significant corrosion or deterioration. All reassayed contents were within WIPP waste acceptance criteria. Five of the drums opened and examined (15%) could not be certified as packaged. Three contained free liquids, one had corrosive materials, and one had too much unstabilized particulate. Eleven drums had the wrong (or not the most appropriate) waste code. In many cases, disposal volumes had been inefficiently used. 2 refs., 23 figs., 7 tabs

  13. Neutron and gamma-ray nondestructive examination of contact-handled transuranic waste at the ORNL TRU Waste Drum Assay Facility

    International Nuclear Information System (INIS)

    Schultz, F.J.; Coffey, D.E.; Norris, L.B.; Haff, K.W.

    1985-03-01

    A nondestructive assay system, which includes the Neutron Assay System (NAS) and the Segmented Gamma Scanner (SGS), for the quantification of contact-handled (<200 mrem/h total radiation dose rate at contact with container) transuranic elements (CH-TRU) in bulk solid waste contained in 208-L and 114-L drums has been in operation at the Oak Ridge National Laboratory since April 1982. The NAS has been developed and demonstrated by Los Alamos National Laboratory (LANL) and the Oak Ridge National Laboratory (ORNL) for use by most US Department of Energy Defense Plant (DOE-DP) sites. More research and development is required, however, before the NAS can provide complete assay results for other than routine defense waste. To date, 525 ORNL waste drums have been assayed, with varying degrees of success. The isotopic complexity of the ORNL waste creates a correspondingly complex assay problem. The NAS and SGS assay data are presented and discussed. Neutron matrix effects, the destructive examination facility, and enriched uranium fuel-element assays are also discussed

  14. Survey of DOE NDA practices for CH-Tru waste certification--illustrated with a greater than 10,000 drum NDA data base

    International Nuclear Information System (INIS)

    Schultz, F.J.; Caldwell, J.T.; Smith, J.R.

    1988-01-01

    We have compiled a greater than 10,000 CH-TRU waste drum data base from seven DOE sites which have utilized such multiple NDA measurements within the past few years. Most of these nondestructive assay (NDA) technique assay result comparisons have been performed on well-characterized, segregated waste categories such as cemented sludges, combustibles, metals, graphite residues, glasses, etc., with well-known plutonium isotopic compositions. Waste segregation and categorization practices vary from one DOE site to another. Perhaps the most systematic approach has been in use for several years at the Rocky Flats Plant (RFP), operated by Rockwell International, and located near Golden, Colorado. Most of the drum assays in our data base result from assays of RFP wastes, with comparisons available between the original RFP assays and PAN assays performed independently at the Idaho National Engineering Laboratory (INEL) Solid Waste Examination Pilot Plant (SWEPP) facility. Most of the RFP assays were performed with hyperpure germanium (HPGe)-based SGS assay units. However, at least one very important waste category, processed first-stage sludges, is assayed at RFP using a sludge batch-sampling procedure, prior to filling of the waste drums. 5 refs., 5 figs

  15. Heat load limits for TRU drums on pads

    International Nuclear Information System (INIS)

    Steimke, J.L.; McKinley, M.S.

    1993-08-01

    Some of the Trans-Uranic (TRU) waste generated at SRS is packaged in 55 gallon, galvanized steel drums and stored on concrete pads that are exposed to the weather. It was necessary to compute how much heat can be generated by the waste in these drums without exceeding the temperature limits of the contents of the drum. This report documents the calculation of heat load limits for the drum, which depend on the temperature limits of the contents of the drum. The applicable temperature limits for the contents of the drum are the melting temperature of the polyethylene liner, 284 ± 8 F, the combustion temperature of paper, 450 F and the decomposition temperature of anionic resin, 190 F. One part of the analysis leading to the heat load limits was the collection of weather records on solar flux, wind speed and air temperature. Another part of the task was an experimental measurement of two important properties of the drum lid, the emittance and the absorptance. As used here, emittance is the rate at which an object emits infrared thermal radiation divided by the rate at which a perfect black body at the same temperature emits thermal radiation. Absorptance is the rate at which an object absorbs solar radiation divided by the rate at which a perfect black body absorbs radiation. For nine locations on each of eight typical weathered drum lids the measured emittance ranged from 0.73 ± 0.05 to 1.00 ± 0.07 (95% confidence level) and the average emittance for the eight lids was 0.85. For the eight drum lids the measured absorptance ranged from 0.64 ± 0.07 to 0.79 ± 0.07 with an average absorptance for the eight lids of 0.739

  16. Transuranic (TRU) Waste Phase I Retrieval Plan

    International Nuclear Information System (INIS)

    MCDONALD, K.M.

    1999-01-01

    From 1970 to 1987, TRU and suspect TRU wastes at Hanford were placed in the SWBG. At the time of placement in the SWBG these wastes were not regulated under existing Resource Conservation and Recovery Act (RCRA) regulations, since they were generated and disposed of prior to the effective date of RCRA at the Hanford Site (1987). From the standpoint of DOE Order 5820.2A', the TRU wastes are considered retrievably stored, and current plans are to retrieve these wastes for shipment to WIPP for disposal. This plan provides a strategy for the Phase I retrieval that meets the intent of TPA milestone M-91 and Project W-113, and incorporates the lessons learned during TRU retrieval campaigns at Hanford, LANL, and SRS. As in the original Project W-I13 plans, the current plan calls for examination of approximately 10,000 suspect-TRU drums located in the 218-W-4C burial ground followed by the retrieval of those drums verified to contain TRU waste. Unlike the older plan, however, this plan proposes an open-air retrieval scenario similar to those used for TRU drum retrieval at LANL and SRS. Phase I retrieval consists of the activities associated with the assessment of approximately 10,000 55-gallon drums of suspect TRU-waste in burial ground 218-W-4C and the retrieval of those drums verified to contain TRU waste. Four of the trenches in 218-W-4C (Trenches 1,4,20, and 29) are prime candidates for Phase I retrieval because they contain large numbers of suspect TRU drums, stacked from 2 to 5 drums high, on an asphalt pad. In fact, three of the trenches (Trenches 1,20, and 29) contain waste that has not been covered with soil, and about 1500 drums can be retrieved without excavation. The other three trenches in 218-W-4C (Trenches 7, 19, and 24) are not candidates for Phase I retrieval because they contain significant numbers of boxes. Drums will be retrieved from the four candidate trenches, checked for structural integrity, overpacked, if necessary, and assayed at the burial

  17. Transuranic (TRU) Waste Phase I Retrieval Plan

    International Nuclear Information System (INIS)

    MCDONALD, K.M.

    2000-01-01

    From 1970 to 1987, TRU and suspect TRU wastes at Hanford were placed in the SWBG. At the time of placement in the SWBG these wastes were not regulated under existing Resource Conservation and Recovery Act (RCRA) regulations, since they were generated and disposed of prior to the effective date of RCRA at the Hanford Site (1987). From the standpoint of DOE Order 5820.2A1, the TRU wastes are considered retrievably stored, and current plans are to retrieve these wastes for shipment to WIPP for disposal. This plan provides a strategy for the Phase I retrieval that meets the intent of TPA milestone M-91 and Project W-113, and incorporates the lessons learned during TRU retrieval campaigns at Hanford, LANL, and SRS. As in the original Project W-113 plans, the current plan calls for examination of approximately 10,000 suspect-TRU drums located in the 218-W-4C burial ground followed by the retrieval of those drums verified to contain TRU waste. Unlike the older plan, however, this plan proposes an open-air retrieval scenario similar to those used for TRU drum retrieval at LANL and SRS. Phase I retrieval consists of the activities associated with the assessment of approximately 10,000 55-gallon drums of suspect TRU-waste in burial ground 218-W-4C and the retrieval of those drums verified to contain TRU waste. Four of the trenches in 218-W-4C (Trenches 1, 4, 20, and 29) are prime candidates for Phase I retrieval because they contain large numbers of suspect TRU drums, stacked from 2 to 5 drums high, on an asphalt pad. In fact, three of the trenches (Trenches 1 , 20, and 29) contain waste that has not been covered with soil, and about 1500 drums can be retrieved without excavation. The other three trenches in 218-W-4C (Trenches 7, 19, and 24) are not candidates for Phase I retrieval because they contain significant numbers of boxes. Drums will be retrieved from the four candidate trenches, checked for structural integrity, overpacked, if necessary, and assayed at the burial

  18. Transuranic (TRU) Waste Phase I Retrieval Plan

    CERN Document Server

    McDonald, K M

    2000-01-01

    From 1970 to 1987, TRU and suspect TRU wastes at Hanford were placed in the SWBG. At the time of placement in the SWBG these wastes were not regulated under existing Resource Conservation and Recovery Act (RCRA) regulations, since they were generated and disposed of prior to the effective date of RCRA at the Hanford Site (1987). From the standpoint of DOE Order 5820.2A1, the TRU wastes are considered retrievably stored, and current plans are to retrieve these wastes for shipment to WIPP for disposal. This plan provides a strategy for the Phase I retrieval that meets the intent of TPA milestone M-91 and Project W-113, and incorporates the lessons learned during TRU retrieval campaigns at Hanford, LANL, and SRS. As in the original Project W-113 plans, the current plan calls for examination of approximately 10,000 suspect-TRU drums located in the 218-W-4C burial ground followed by the retrieval of those drums verified to contain TRU waste. Unlike the older plan, however, this plan proposes an open-air retrieval ...

  19. Quarter-scale modeling of room convergence effects on CH [contact-handled] TRU drum waste emplacements using WIPP [Waste Isolation Pilot Plant] reference design geometries

    International Nuclear Information System (INIS)

    VandeKraats, J.

    1987-11-01

    This study investigates the effect of horizontal room convergence on CH waste packages emplaced in the WIPP Reference Design geometry (rooms 13 feet high by 33 feet wide, with minus 3/8 inch screened backfill emplaced over and around the waste packages) as a function of time. Based on two tests, predictions were made with regard to full-scale 6-packs emplaced in the Reference Design geometry. These are that load will be transmitted completely through the stack within the first five years after waste emplacement and all drums in all 6-packs will be affected; that virtually all drums will show some deformation eight years after emplacement; that some drums may breach before the eighth year after emplacement has elapsed; and that based on criteria developed during testing, it is predicted that 1% of the drums emplaced will be breached after 8 years and, after 15 years, approximately 12% of the drums are predicted to be breached. 8 refs., 41 figs., 3 tabs

  20. Los Alamos National Laboratory TRU waste sampling projects

    International Nuclear Information System (INIS)

    Yeamans, D.; Rogers, P.; Mroz, E.

    1997-01-01

    The Los Alamos National Laboratory (LANL) has begun characterizing transuranic (TRU) waste in order to comply with New Mexico regulations, and to prepare the waste for shipment and disposal at the Waste Isolation Pilot Plant (WIPP), near Carlsbad, New Mexico. Sampling consists of removing some head space gas from each drum, removing a core from a few drums of each homogeneous waste stream, and visually characterizing a few drums from each heterogeneous waste stream. The gases are analyzed by GC/MS, and the cores are analyzed for VOC's and SVOC's by GC/MS and for metals by AA or AE spectroscopy. The sampling and examination projects are conducted in accordance with the ''DOE TRU Waste Quality Assurance Program Plan'' (QAPP) and the ''LANL TRU Waste Quality Assurance Project Plan,'' (QAPjP), guaranteeing that the data meet the needs of both the Carlsbad Area Office (CAO) of DOE and the ''WIPP Waste Acceptance Criteria, Rev. 5,'' (WAC)

  1. TRU waste transportation -- The flammable gas generation problem

    International Nuclear Information System (INIS)

    Connolly, M.J.; Kosiewicz, S.T.

    1997-01-01

    The Nuclear Regulatory Commission (NRC) has imposed a flammable gas (i.e., hydrogen) concentration limit of 5% by volume on transuranic (TRU) waste containers to be shipped using the TRUPACT-II transporter. This concentration is the lower explosive limit (LEL) in air. This was done to minimize the potential for loss of containment during a hypothetical 60 day period. The amount of transuranic radionuclide that is permissible for shipment in TRU waste containers has been tabulated in the TRUPACT-II Safety Analysis Report for Packaging (SARP, 1) to conservatively prevent accumulation of hydrogen above this 5% limit. Based on the SARP limitations, approximately 35% of the TRU waste stored at the Idaho National Engineering and Environmental Lab (INEEL), Los Alamos National Lab (LANL), and Rocky Flats Environmental Technology Site (RFETS) cannot be shipped in the TRUPACT-II. An even larger percentage of the TRU waste drums at the Savannah River Site (SRS) cannot be shipped because of the much higher wattage loadings of TRU waste drums in that site's inventory. This paper presents an overview of an integrated, experimental program that has been initiated to increase the shippable portion of the Department of Energy (DOE) TRU waste inventory. In addition, the authors will estimate the anticipated expansion of the shippable portion of the inventory and associated cost savings. Such projection should provide the TRU waste generating sites a basis for developing their TRU waste workoff strategies within their Ten Year Plan budget horizons

  2. Waste drum refurbishment

    International Nuclear Information System (INIS)

    Whitmill, L.J.

    1996-01-01

    Low-carbon steel, radioactive waste containers (55-gallon drums) are experiencing degradation due to moisture and temperature fluctuations. With thousands of these containers currently in use; drum refurbishment becomes a significant issue for the taxpayer and stockholders. This drum refurbishment is a non-intrusive, portable process costing between 1/2 and 1/25 the cost of repackaging, depending on the severity of degradation. At the INEL alone, there are an estimated 9,000 drums earmarked for repackaging. Refurbishing drums rather than repackaging can save up to $45,000,000 at the INEL. Based on current but ever changing WIPP Waste Acceptance Criteria (WAC), this drum refurbishment process will restore drums to a WIPP acceptable condition plus; drums with up to 40% thinning o the wall can be refurbished to meet performance test requirements for DOT 7A Type A packaging. A refurbished drum provides a tough, corrosion resistant, waterproof container with longer storage life and an additional containment barrier. Drums are coated with a high-pressure spray copolymer material approximately .045 inches thick. Increase in internal drum temperature can be held to less than 15 F. Application can be performed hands-on or the equipment is readily adaptable and controllable for remote operations. The material dries to touch in seconds, is fully cured in 48 hours and has a service temperature of -60 to 500 F. Drums can be coated with little or no surface preparation. This research was performed on drums however research results indicate the coating is very versatile and compatible with most any material and geometry. It could be used to provide abrasion resistance, corrosion protection and waterproofing to almost anything

  3. Characterizing cemented TRU waste for RCRA hazardous constituents

    International Nuclear Information System (INIS)

    Yeamans, D.R.; Betts, S.E.; Bodenstein, S.A.

    1996-01-01

    Los Alamos National Laboratory (LANL) has characterized drums of solidified transuranic (TRU) waste from four major waste streams. The data will help the State of New Mexico determine whether or not to issue a no-migration variance of the Waste Isolation Pilot Plant (WIPP) so that WIPP can receive and dispose of waste. The need to characterize TRU waste stored at LANL is driven by two additional factors: (1) the LANL RCRA Waste Analysis Plan for EPA compliant safe storage of hazardous waste; (2) the WIPP Waste Acceptance Criteria (WAC) The LANL characterization program includes headspace gas analysis, radioassay and radiography for all drums and solids sampling on a random selection of drums from each waste stream. Data are presented showing that the only identified non-metal RCRA hazardous component of the waste is methanol

  4. Safety evaluation for packaging (onsite) for the concrete-shielded RH TRU drum for the 327 Postirradiation Testing Laboratory

    International Nuclear Information System (INIS)

    Smith, R.J.

    1998-01-01

    This safety evaluation for packaging authorizes onsite transport of Type B quantities of radioactive material in the Concrete Shielded Remote-Handled Transuranic Waste (RH TRU) Drum per HNF-PRO-154, Responsibilities and Procedures for all Hazardous Material Shipments. The drum will be used for transport of 327 Building legacy waste from the 300 Area to a solid waste storage facility on the Hanford Site

  5. Savannah River Site Operating Experience with Transuranic (TRU) Waste Retrieval

    International Nuclear Information System (INIS)

    Stone, K.A.; Milner, T.N.

    2006-01-01

    Drums of TRU Waste have been stored at the Savannah River Site (SRS) on concrete pads from the 1970's through the 1980's. These drums were subsequently covered with tarpaulins and then mounded over with dirt. Between 1996 and 2000 SRS ran a successful retrieval campaign and removed some 8,800 drums, which were then available for venting and characterization for WIPP disposal. Additionally, a number of TRU Waste drums, which were higher in activity, were stored in concrete culverts, as required by the Safety Analysis for the Facility. Retrieval of drums from these culverts has been ongoing since 2002. This paper will describe the operating experience and lessons learned from the SRS retrieval activities. (authors)

  6. Repackaging SRS Black Box TRU Waste

    International Nuclear Information System (INIS)

    Swale, D. J.; Stone, K.A.; Milner, T. N.

    2006-01-01

    Historically, large items of TRU Waste, which were too large to be packaged in drums for disposal have been packaged in various sizes of custom made plywood boxes at the Savannah River Site (SRS), for many years. These boxes were subsequently packaged into large steel ''Black Boxes'' for storage at SRS, pending availability of Characterization and Certification capability, to facilitate disposal of larger items of TRU Waste. There are approximately 107 Black Boxes in inventory at SRS, each measuring some 18' x 12' x 7', and weighing up to 45,000 lbs. These Black Boxes have been stored since the early 1980s. The project to repackage this waste into Standard Large Boxes (SLBs), Standard Waste Boxes (SWB) and Ten Drum Overpacks (TDOP), for subsequent characterization and WIPP disposal, commenced in FY04. To date, 10 Black Boxes have been repackaged, resulting in 40 SLB-2's, and 37 B25 overpack boxes, these B25's will be overpacked in SLB-2's prior to shipping to WIPP. This paper will describe experience to date from this project

  7. Nondestructive assay of TRU waste using gamma-ray active and passive computed tomography

    International Nuclear Information System (INIS)

    Roberson, G.P.; Decman, D.; Martz, H.; Keto, E.R.; Johansson, E.M.

    1995-01-01

    The authors have developed an active and passive computed tomography (A and PCT) scanner for assaying radioactive waste drums. Here they describe the hardware components of their system and the software used for data acquisition, gamma-ray spectroscopy analysis, and image reconstruction. They have measured the performance of the system using ''mock'' waste drums and calibrated radioactive sources. They also describe the results of measurements using this system to assay a real TRU waste drum with relatively low Pu content. The results are compared with X-ray NDE studies of the same TRU waste drum as well as assay results from segmented gamma scanner (SGS) measurements

  8. The new Japanese policy for TRU-waste management

    International Nuclear Information System (INIS)

    Yamamoto, M.

    1992-01-01

    In July 1991, the Advisory Committee on Radioactive Waste of the Japan Atomic Energy Commission announced its report on a new Japanese policy for TRU-waste management. The total volume of radioactive wastes which contain TRU nuclides has reached the equivalent of about 40,000,200-liter drums, and is expected to grow to about 300,000 drums by the year 2010. Further development is required to reduce the volume of the existing waste and to decrease the amount of waste being generated. Wastes with concentration levels exceeding a threshold limit of 1 Giga-Becquerel per ton will be disposed in an underground facility. Those wastes with lower activities will be sent to a shallow-land burial facility. The goal of research and development is the completion of the disposal system by the late 1990's. (author)

  9. TRU waste transport economics: an overview

    International Nuclear Information System (INIS)

    Edling, D.A.; Hopkins, D.R.; Walls, H.C.

    1978-01-01

    There are currently three predominant methods used to transport transuranium contaminated waste. These are: (1) ATMX Railcars--500 and 600 series, (2) Super Tigers, and (3) Poly Panthers. Both the ATMX-500 and 600 series railcars are massive doubly walled steel railcars which provide the equivalent protection of a Type B package. In ATMX-600 the rapid loading and unloading of the 9 x 9 x 50 feet cargo space is achieved by prepackaging the TRU waste into standard 20-foot steel cargo containers. The ATMX-500 railcars are divided into three inside bays, having dimensions of 16 (l) x 9.25 (w) x 6.25 (h) feet. A typical load consists of 128 55-gallon drums (however, space can accommodate 192 drums), 12 fiberglass boxes (4 x 4 x 7), or a combination of palletized drums and boxes. A Super Tiger is an overpack authorized for Type A, Type B, and large quantities of radioactive materials having outside dimensions of 8 x 8 x 20 feet. Maximum payload is approximately 28,700 lb with a gross weight of 45,000 lb. The primary factors influencing transport costs are examined including freight rates of transport mode, effective cargo (weight and volume) management, effective utilization of available space (package design), transport mileage, and rental fees or initial capital outlay. Miscellaneous factors are also examined

  10. Case studies of corrosion of mixed waste and transuranic waste drums

    International Nuclear Information System (INIS)

    Kosiewicz, S.T.

    1993-01-01

    This paper presents three case studies of corrosion of waste drums at the Los Alamos National Laboratory (LANL). Corrosion was not anticipated by the waste generators, but occurred because of subtle chemical or physical mechanisms. In one case, drums of a cemented transuranic (TRU) sludge experienced general and pitting corrosion. In the second instance, a chemical from a commercial paint stripper migrated from its primary containment drums to chemically attack overpack drums made of mild carbon steel. In the third case, drums of mixed low level waste (MLLW) soil corroded drum packaging even though the waste appeared to be dry when it was placed in the drums. These case studies are jointly discussed as ''lessons learned'' to enhance awareness of subtle mechanisms that can contribute to the corrosion of radioactive waste drums during interim storage

  11. TRU waste characterization chamber gloveboxes

    International Nuclear Information System (INIS)

    Duncan, D. S.

    1998-01-01

    Argonne National Laboratory-West (ANL-W) is participating in the Department of Energy's (DOE) National Transuranic Waste Program in support of the Waste Isolation Pilot Plant (WIPP). The Laboratory's support currently consists of intrusive characterization of a selected population of drums containing transuranic waste. This characterization is performed in a complex of alpha containment gloveboxes termed the Waste Characterization Gloveboxes. Made up of the Waste Characterization Chamber, Sample Preparation Glovebox, and the Equipment Repair Glovebox, they were designed as a small production characterization facility for support of the Idaho National Engineering and Environmental Laboratory (INEEL). This paper presents salient features of these gloveboxes

  12. Los Alamos National Laboratory accelerated tru waste workoff strategies

    International Nuclear Information System (INIS)

    Kosiewicz, S.T.; Triay, I.R.; Rogers, P.Z.; Christensen, D.V.

    1997-01-01

    During 1996, the Los Alamos National Laboratory (LANL) developed two transuranic (TRU) waste workoff strategies that were estimated to save $270 - 340M through accelerated waste workoff and the elimination of a facility. The planning effort included a strategy to assure that LANL would have a significant quantity (3000+ drums) of TRU waste certified for shipment to the Waste Isolation Pilot Plant (WIPP) beginning in April of 1998, when WIPP was projected to open. One of the accelerated strategies can be completed in less than ten years through a Total Optimization of Parameters Scenario (open-quotes TOPSclose quotes). open-quotes TOPSclose quotes fully utilizes existing LANL facilities and capabilities. For this scenario, funding was estimated to be unconstrained at $23M annually to certify and ship the legacy inventory of TRU waste at LANL. With open-quotes TOPSclose quotes the inventory is worked off in about 8.5 years while shipping 5,000 drums per year at a total cost of $196M. This workoff includes retrieval from earthen cover and interim storage costs. The other scenario envisioned funding at the current level with some increase for TRUPACT II loading costs, which total $16M annually. At this funding level, LANL estimates it will require about 17 years to work off the LANL TRU legacy waste while shipping 2,500 drums per year to WIPP. The total cost will be $277M. This latter scenario decreases the time for workoff by about 19 years from previous estimates and saves an estimated $190M. In addition, the planning showed that a $70M facility for TRU waste characterization was not needed. After the first draft of the LANL strategies was written, Congress amended the WIPP Land Withdrawal Act (LWA) to accelerate the opening of WIPP to November 1997. Further, the No Migration Variance requirement for the WIPP was removed. This paper discusses the LANL strategies as they were originally developed. 1 ref., 3 figs., 2 tabs

  13. Hanford Site Transuranic (TRU) Waste Certification Plan

    International Nuclear Information System (INIS)

    GREAGER, T.M.

    2000-01-01

    As a generator of transuranic (TRU) and TRU mixed waste destined for disposal at the Waste Isolation Pilot Plant (WIPP), the Hanford Site must ensure that its TRU waste meets the requirements of US. Department of Energy (DOE) 0 435.1, ''Radioactive Waste Management,'' and the Contact-Handled (CH) Transuranic Waste Acceptance Criteria for the Waste Isolation Pilot Plant (WIPP-WAC). WIPP-WAC requirements are derived from the WIPP Technical Safety Requirements, WIPP Safety Analysis Report, TRUPACT-II SARP, WIPP Land Withdrawal Act, WIPP Hazardous Waste Facility Permit, and Title 40 Code of Federal Regulations (CFR) 191/194 Compliance Certification Decision. The WIPP-WAC establishes the specific physical, chemical, radiological, and packaging criteria for acceptance of defense TRU waste shipments at WIPP. The WPP-WAC also requires that participating DOE TRU waste generator/treatment/storage sites produce site-specific documents, including a certification plan, that describe their program for managing TRU waste and TRU waste shipments before transferring waste to WIPP. Waste characterization activities provide much of the data upon which certification decisions are based. Waste characterization requirements for TRU waste and TRU mixed waste that contains constituents regulated under the Resource Conservation and Recovery Act (RCRA) are established in the WIPP Hazardous Waste Facility Permit Waste Analysis Plan (WAP). The Hanford Site Quality Assurance Project Plan (QAPjP) (HNF-2599) implements the applicable requirements in the WAP and includes the qualitative and quantitative criteria for making hazardous waste determinations. The Hanford Site must also ensure that its TRU waste destined for disposal at WPP meets requirements for transport in the Transuranic Package Transporter-11 (TRUPACT-11). The US. Nuclear Regulatory Commission (NRC) establishes the TRUPACT-11 requirements in the Safety Analysis Report for the TRUPACT-II Shipping Package (TRUPACT-11 SARP). In

  14. Contamination control aspects of attaching waste drums to the WIPP Waste Characterization Chamber

    International Nuclear Information System (INIS)

    Rubick, L.M.; Burke, L.L.

    1998-01-01

    Argonne National Laboratory West (ANL-W) is verifying the characterization and repackaging of contact-handled transuranic (CH-TRU) mixed waste in support of the Waste Isolation Pilot Program (WIPP) project located in Carlsbad, New Mexico. The WIPP Waste Characterization Chamber (WCC) was designed to allow opening of transuranic waste drums for this process. The WCC became operational in March of 1994 and has characterized approximately 240 drums of transuranic waste. The waste drums are internally contaminated with high levels of transuranic radionuclides. Attaching and detaching drums to the glove box posed serious contamination control problems. Prior to characterizing waste, several drum attachment techniques and materials were evaluated. An inexpensive HEPA filter molded into the bagging material helps with venting during detachment. The current techniques and procedures used to attach and detach transuranic waste drums to the WCC are described

  15. A facility design for repackaging ORNL CH-TRU legacy waste in Building 3525

    International Nuclear Information System (INIS)

    Huxford, T.J.; Cooper, R.H. Jr.; Davis, L.E.; Fuller, A.B.; Gabbard, W.A.; Smith, R.B.; Guay, K.P.; Smith, L.C.

    1995-07-01

    For the last 25 years, the Oak Ridge National Laboratory (ORNL) has conducted operations which have generated solid, contact-handled transuranic (CH-TRU) waste. At present the CH-TRU waste inventory at ORNL is about 3400 55-gal drums retrievably stored in RCRA-permitted, aboveground facilities. Of the 3400 drums, approximately 2600 drums will need to be repackaged. The current US Department of Energy (DOE) strategy for disposal of these drums is to transport them to the Waste Isolation Pilot Plant (WIPP) in New Mexico which only accepts TRU waste that meets a very specific set of criteria documented in the WIPP-WAC (waste acceptance criteria). This report describes activities that were performed from January 1994 to May 1995 associated with the design and preparation of an existing facility for repackaging and certifying some or all of the CH-TRU drums at ORNL to meet the WIPP-WAC. For this study, the Irradiated Fuel Examination Laboratory (IFEL) in Building 3525 was selected as the reference facility for modification. These design activities were terminated in May 1995 as more attractive options for CH-TRU waste repackaging were considered to be available. As a result, this document serves as a final report of those design activities

  16. TRU waste form and package criteria meeting

    Energy Technology Data Exchange (ETDEWEB)

    None

    1977-08-01

    The broad subject of the meeting is the overall ERDA TRU waste management program, although the discussions also cover performance criteria for the Waste Isolation Pilot Plant and their implications for the overall TRU program. Separate abstracts were prepared for all ten presentations. (DLC)

  17. Hanford Site Transuranic (TRU) Waste Certification Plan

    International Nuclear Information System (INIS)

    GREAGER, T.M.

    1999-01-01

    The Hanford Site Transuranic Waste Certification Plan establishes the programmatic framework and criteria with in which the Hanford Site ensures that contract-handled TRU wastes can be certified as compliant with the WIPP WAC and TRUPACT-II SARP

  18. Hanford Site Transuranic (TRU) Waste Certification Plan

    Energy Technology Data Exchange (ETDEWEB)

    GREAGER, T.M.

    1999-09-09

    The Hanford Site Transuranic Waste Certification Plan establishes the programmatic framework and criteria within which the Hanford Site ensures that contract-handled TRU wastes can be certified as compliant with the WIPP WAC and TRUPACT-II SARP.

  19. CONCRETE CONTAINERS FOR LONG TERM STORAGE AND FINAL DISPOSAL OF TRU WASTE AND LONG LIVED ILW

    International Nuclear Information System (INIS)

    Sakamoto, H.; Asano, H.; Tunaboylu, K.; Mayer, G.; Klubertanz, G.; Kobayashi, S.; Komuro, T.; Wagner, E.

    2003-01-01

    Transuranic (TRU) waste packaging development has been conducted since 1998 by the Radioactive Waste Management Funding and Research Centre (RWMC) to support the TRU waste disposal concept in Japan. In this paper, the overview of development status of the reinforced concrete package is introduced. This package has been developed in order to satisfy the Japanese TRU waste disposal concept based on current technology and to provide a low cost package. Since 1998, the basic design work (safety evaluation, manufacturing and handling procedure, economic evaluation, elemental tests etc.) have been carried out. As a result, the basic specification of the package was decided. This report presents the concept as well as the results of basic design, focused on safety analysis and handling procedure of the package. Two types of the packages exist: - Package-A: for non-heat generating TRU waste from reprocessing in 200 l drums and - Package-B: for heat generating TRU-waste from reprocessing

  20. TRU waste from the Superblock

    International Nuclear Information System (INIS)

    Coburn, T.T.

    1997-01-01

    This data analysis is to show that weapons grade plutonium is of uniform composition to the standards set by the Waste-Isolation Pilot Plant (WIPP) Transuranic Waste Characterization Quality Assurance Program Plan (TRUW Characterization QAPP, Rev. 2, DOE, Carlsbad Area Office, November 15, 1996). The major portion of Superblock transuranic (TRU) waste is glove-box trash contaminated with weapons grade plutonium. This waste originates in the Building 332 (B332) radioactive-materials area (RMA). Because each plutonium batch brought into the B332 RMA is well characterized with regard to nature and quantity of transuranic nuclides present, waste also will be well characterized without further analytical work, provided the batches are quite similar. A sample data set was created by examining the 41 incoming samples analyzed by Ken Raschke (using a γ-ray spectrometer) for isotopic distribution and by Ted Midtaune (using a calorimeter) for mass of radionuclides. The 41 samples were from separate batches analyzed May 1993 through January 1997. All available weapons grade plutonium data in Midtaune's files were used. Alloys having greater than 50% transuranic material were included. The intention of this study is to use this sample data set to judge ''similarity.''

  1. TRU-ART: A cost-effective prototypical neutron imaging technique for transuranic waste certification systems

    International Nuclear Information System (INIS)

    Horton, W.S.

    1989-01-01

    The certification of defense radioactive waste as either transuranic or low-level waste requires very sensitive and accurate assay instrumentation to determine the specific radioactivity within an individual waste package. An assay instrument that employs a new technique (TRU-ART), which can identify the location of the radioactive material within a waste package, was designed, fabricated, and tested to potentially enhance the certification of problem defense waste drums. In addition, the assay instrumentation has potential application in radioactive waste reprocessing and neutron tomography. The assay instrumentation uses optimized electronic signal responses from an array of boral- and cadmium-shielded polyethylene-moderated 3 H detector packages. Normally, thermal neutrons that are detected by 3 H detectors have very poor spatial dependency that may be used to determine the location of the radioactive material. However, these shielded-detector packages of the TRU-ART system maintain the spatial dependency of the radioactive material in that the point of fast neutron thermalization is immediately adjacent to the 3 H detector. The TRU-ART was used to determine the location of radioactive material within three mock-up drums (empty, peat moss, and concrete) and four actual waste drums. The TRU-ART technique is very analogous to emission tomography. The mock-up drum and actual waste drum data, which were collected by the TRU-ART, were directly input into a algebraic reconstruction code to produce three-dimensional isoplots. Finally, a comprehensive fabrication cost estimate of the fielded drum assay system and the TRU-ART system was determined, and, subsequently, these estimates were used in a cost-benefit analysis to compare the economic advantage of the respective systems

  2. Design of benign matrix drums for the non-destructive assay performance demonstration program for the National TRU Program

    International Nuclear Information System (INIS)

    Becker, G.K.

    1996-09-01

    Regulatory compliance programs associated with the Department of Energy (DOE) Waste Isolation Pilot Plant (WIPP) Transuranic (TRU) Waste Characterization Program (the Program) require the collection of waste characterization data of known quality to support repository performance assessment, permitting, and associated activities. Blind audit samples, referred to as PDP (performance demonstration program) samples, are devices used in the NDA PDP program to acquire waste NDA system performance data per defined measurement routines. As defined under the current NDA PDP Program Plan, a PDP sample consists of a DOT 17C 55-gallon PDP matrix drum configured with insertable radioactive standards, working reference materials (WRMs). The particular manner in which the matrix drum and PDP standard(s) are combined is a function of the waste NDA system performance test objectives of a given cycle. The scope of this document is confined to the design of the PDP drum radioactive standard internal support structure, the matrix type and the as installed configuration. The term benign is used to designate a matrix possessing properties which are nominally non-interfering to waste NDA measurement techniques. Measurement interference sources are technique specific but include attributes such as: high matrix density, heterogeneous matrix distributions, matrix compositions containing high moderator/high Z element concentrations, etc. To the extent practicable the matrix drum design should not unduly bias one NDA modality over another due to the manner in which the matrix drum configuration manifests itself to the measurement system. To this end the PDP matrix drum configuration and composition detailed below is driven primarily by the intent to minimize the incorporation of matrix attributes known to interfere with fundamental waste NDA modalities, i.e. neutron and gamma based techniques

  3. The effect of vibration on alpha radiolysis of transuranic (TRU) waste

    International Nuclear Information System (INIS)

    Zerwekh, A.; Kosiewicz, S.; Warren, J.

    1993-01-01

    This paper reports on previously unpublished scoping work related to the potential for vibration to redistribute radionuclides on transuranic (TRU) waste. If this were to happen, the amount of gases generated, including hydrogen, could be increased above the undisturbed levels. This could be an important consideration for transport of TRU wastes either at DOE sites or from them to a future repository, e.g., the Waste Isolation Pilot Plant (WIPP). These preliminary data on drums of real waste seem to suggest that radionuclide redistribution does not occur. However improvements in the experimental methodology are suggested to enhance safety of future experiments on real wastes as well as to provide more rigorous data

  4. RH-TRU Waste Content Codes

    Energy Technology Data Exchange (ETDEWEB)

    Washington TRU Solutions

    2007-07-01

    The Remote-Handled Transuranic (RH-TRU) Content Codes (RH-TRUCON) document describes the inventory of RH-TRU waste within the transportation parameters specified by the Remote-Handled Transuranic Waste Authorized Methods for Payload Control (RH-TRAMPAC).1 The RH-TRAMPAC defines the allowable payload for the RH-TRU 72-B. This document is a catalog of RH-TRU 72-B authorized contents by site. A content code is defined by the following components: • A two-letter site abbreviation that designates the physical location of the generated/stored waste (e.g., ID for Idaho National Laboratory [INL]). The site-specific letter designations for each of the sites are provided in Table 1. • A three-digit code that designates the physical and chemical form of the waste (e.g., content code 317 denotes TRU Metal Waste). For RH-TRU waste to be transported in the RH-TRU 72-B, the first number of this three-digit code is “3.” The second and third numbers of the three-digit code describe the physical and chemical form of the waste. Table 2 provides a brief description of each generic code. Content codes are further defined as subcodes by an alpha trailer after the three-digit code to allow segregation of wastes that differ in one or more parameter(s). For example, the alpha trailers of the subcodes ID 322A and ID 322B may be used to differentiate between waste packaging configurations. As detailed in the RH-TRAMPAC, compliance with flammable gas limits may be demonstrated through the evaluation of compliance with either a decay heat limit or flammable gas generation rate (FGGR) limit per container specified in approved content codes. As applicable, if a container meets the watt*year criteria specified by the RH-TRAMPAC, the decay heat limits based on the dose-dependent G value may be used as specified in an approved content code. If a site implements the administrative controls outlined in the RH-TRAMPAC and Appendix 2.4 of the RH-TRU Payload Appendices, the decay heat or FGGR

  5. W-026, transuranic waste (TRU) glovebox acceptance test report

    International Nuclear Information System (INIS)

    Leist, K.J.

    1998-01-01

    On July 18, 1997, the Transuranic (TRU) glovebox was tested using glovebox acceptance test procedure 13021A-86. The primary focus of the glovebox acceptance test was to examine control system interlocks, display menus, alarms, and operator messages. Limited mechanical testing involving the drum ports, hoists, drum lifter, compacted drum lifter, drum tipper, transfer car, conveyors, sorting table, lidder/delidder device and the TRU empty drum compactor were also conducted. As of February 25, 1998, 10 of the 102 test exceptions that affect the TRU glovebox remain open. These items will be tracked and closed via the WRAP Master Test Exception Database. As part of Test Exception resolution/closure the responsible individual closing the Test Exception performs a retest of the affected item(s) to ensure the identified deficiency is corrected, and, or to test items not previously available to support testing. Test exceptions are provided as appendices to this report

  6. MANAGEING THE RETRIEVAL RISK OF BURIED TRANSURANIC (TRU) WASTE WITH UNIQUE CHARACTERISTICS

    International Nuclear Information System (INIS)

    WOJTASEK, R.D.; GREENWELL, R.D.

    2005-01-01

    United States-Department of Energy (DOE) sites that store transuranic (TRU) waste are almost certain to encounter waste packages with characteristics that are so unique as to warrant special precautions for retrieval. At the Hanford Site, a subgroup of stored TRU waste (12 drums) had special considerations due to the radioactive source content of plutonium oxide (PuO 2 ), and the potential for high heat generation, pressurization, criticality, and high radiation. These characteristics bear on the approach to safely retrieve, overpack, vent, store, and transport the waste package. Because of the potential risk to personnel, contingency planning for unexpected conditions played an effective roll in work planning and in preparing workers for the field inspection activity. As a result, the integrity inspections successfully confirmed waste package configuration and waste confinement without experiencing any perturbations due to unanticipated packaging conditions. This paper discusses the engineering and field approach to managing the risk of retrieving TRU waste with unique characteristics

  7. Determination of H2 Diffusion Rates through Various Closures on TRU Waste Bag-Out Bags

    International Nuclear Information System (INIS)

    Noll, Phillip D. Jr.; Callis, E. Larry; Norman, Kirsten M.

    1999-01-01

    The amount of H 2 diffusion through twist and tape (horse-tail), wire tie, plastic tie, and heat sealed closures on transuranic (TRU) waste bag-out bags has been determined. H 2 diffusion through wire and plastic tie closures on TRU waste bag-out bags has not been previously characterized and, as such, TRU waste drums containing bags with these closures cannot be certified and/or shipped to the Waste Isolation Pilot Plant (WIPP). Since wire ties have been used at Los Alamos National Laboratory (LANL) from 1980 to 1991 and the plastic ties from 1991 to the present, there are currently thousands of waste drums that cannot be shipped to the WIPP site. Repackaging the waste would be prohibitively expensive. Diffusion experiments performed on the above mentioned closures show that the diffusion rates of plastic tie and horse-tail closures are greater than the accepted value presented in the TRU-PACT 11 Safety Analysis Report (SAR). Diffusion rates for wire tie closures are not statistically different from the SAR value. Thus, drums containing bags with these closures can now potentially be certified which would allow for their consequent shipment to WIPP

  8. Solid waste drum array fire performance

    International Nuclear Information System (INIS)

    Louie, R.L.; Haecker, C.F.; Beitel, J.J.; Gottuck, D.T.; Rhodes, B.T.; Bayier, C.L.

    1995-09-01

    Fire hazards associated with drum storage of radioactively contaminated waste are a major concern in DOE waste storage facilities. This report is the second of two reports on fire testing designed to provide data relative to the propagation of a fire among storage drum arrays. The first report covers testing of individual drums subjected to an initiating fire and the development of the analytical methodology to predict fire propagation among storage drum arrays. This report is the second report, which documents the results of drum array fire tests. The purpose of the array tests was to confirm the analytical methodology developed by Phase I fire testing. These tests provide conclusive evidence that fire will not propagate from drum to drum unless an continuous fuel source other than drum contents is provided

  9. Thermal treatment for TRU waste sorting

    International Nuclear Information System (INIS)

    Sasaki, Toshiki; Aoyama, Yoshio; Yamashita, Toshiyuki

    2009-03-01

    A thermal treatment that can automatically unpack TRU waste and remove hazardous materials has been developed to reduce the risk of radiation exposure and save operation cost. The thermal treatment is a process of removing plastic wrapping and hazardous material from TRU waste by heating waste at 500 to 700degC. Plastic wrappings of simulated wastes were removed using a laboratory scale thermal treatment system. Celluloses and isoprene rubbers that must be removed from waste for disposal were pyrolyzed by the treatment. Although the thermal treatment can separate lead and aluminum from the waste, a further technical development is needed to separate lead and aluminum. A demonstration scale thermal treatment system that comprises a rotary kiln with a jacket water cooler and a rotating inner cage for lead and aluminum separation is discussed. A clogging prevention system against zinc chloride, a lead and aluminum accumulation system, and a detection system for spray cans that possibly cause explosion and fire are also discussed. Future technology development subjects for the TRU waste thermal treatment system are summarized. (author)

  10. Thermal processing systems for TRU mixed waste

    International Nuclear Information System (INIS)

    Eddy, T.L.; Raivo, B.D.; Anderson, G.L.

    1992-01-01

    This paper presents preliminary ex situ thermal processing system concepts and related processing considerations for remediation of transuranic (TRU)-contaminated wastes (TRUW) buried at the Radioactive Waste Management Complex (RWMC) of the Idaho National Engineering Laboratory (INEL). Anticipated waste stream components and problems are considered. Thermal processing conditions required to obtain a high-integrity, low-leachability glass/ceramic final waste form are considered. Five practical thermal process system designs are compared. Thermal processing of mixed waste and soils with essentially no presorting and using incineration followed by high temperature melting is recommended. Applied research and development necessary for demonstration is also recommended

  11. Evaluation of a TRU fundamental criterion and reference TRU waste units

    International Nuclear Information System (INIS)

    Klett, R.

    1993-01-01

    The comparison of two options for regulating transuranic (TRU) waste disposal is explained in this paper. The two options are (1) fundamental and derived standards developed specifically for the TRU waste and (2) a family of procedures that use a reference to the TRU waste unit with procedures that use a reference to the TRU waste unit with commercial high-level waste (HLW) criteria. Background information pertaining to both options is covered. A section on criteria specifically for TRUE waste suggests a methodology for developing or adapting fundamental and derived criteria that are consistent with all other aspects of the standards. The section on references TRU waste units covers all the parameter variations that have been suggested for this option. The technical bases of each approach is reviewed, implementation is discussed and their relative attributes and deficiencies are evaluated

  12. Pyrolysis/Steam Reforming Technology for Treatment of TRU Orphan Wastes

    International Nuclear Information System (INIS)

    Mason, J. B.; McKibbin, J.; Schmoker, D.; Bacala, P.

    2003-01-01

    Certain transuranic (TRU) waste streams within the Department of Energy (DOE) complex cannot be disposed of at the Waste Isolation Pilot Plant (WIPP) because they do not meet the shipping requirements of the TRUPACT-II or the disposal requirements of the Waste Analysis Plan (WAP) in the WIPP RCRA Part B Permit. These waste streams, referred to as orphan wastes, cannot be shipped or disposed of because they contain one or more prohibited items, such as liquids, volatile organic compounds (VOCs), hydrogen gas, corrosive acids or bases, reactive metals, or high concentrations of polychlorinated biphenyl (PCB), etc. The patented, non-incineration, pyrolysis and steam reforming processes marketed by THOR Treatment Technologies LLC removes all of these prohibited items from drums of TRU waste and produces a dry, inert, inorganic waste material that meets the existing TRUPACT-II requirements for shipping, as well as the existing WAP requirements for disposal of TRU waste at WIPP. THOR Treatment Technologies is a joint venture formed in June 2002 by Studsvik, Inc. (Studsvik) and Westinghouse Government Environmental Services Company LLC (WGES) to further develop and deploy Studsvik's patented THORSM technology within the DOE and Department of Defense (DoD) markets. The THORSM treatment process is a commercially proven system that has treated over 100,000 cu. ft. of nuclear waste from commercial power plants since 1999. Some of this waste has had contact dose rates of up to 400 R/hr. A distinguishing characteristic of the THORSM process for TRU waste treatment is the ability to treat drums of waste without removing the waste contents from the drum. This feature greatly minimizes criticality and contamination issues for processing of plutonium-containing wastes. The novel features described herein are protected by issued and pending patents

  13. Los Alamos waste drum shufflers users manual

    International Nuclear Information System (INIS)

    Rinard, P.M.; Adams, E.L.; Painter, J.

    1993-01-01

    This user manual describes the Los Alamos waste drum shufflers. The primary purpose of the instruments is to assay the mass of 235 U (or other fissile materials) in drums of assorted waste. It can perform passive assays for isotopes that spontaneously emit neutrons or active assays using the shuffler technique as described on this manual

  14. Waste Disposition Issues and Resolutions at the TRU Waste Processing Center at Oak Ridge TN

    International Nuclear Information System (INIS)

    Gentry, R.

    2009-01-01

    This paper prepared for the Waste Management Conference 2009 provides lessons learned from the Transuranic (TRU) Waste Processing Center (TWPC) associated with development of approaches used to certify and ensure disposition of problematic TRU wastes at the Waste Isolation Pilot Plant (WIPP) site. The TWPC is currently processing the inventory of available waste TRU waste at the Oak Ridge National Lab (ORNL). During the processing effort several waste characteristics were identified/discovered that did not conform to the normal standards and processes for disposal at WIPP. Therefore, the TWPC and ORNL were challenged with determining a path forward for this problematic, special case TRU wastes to ensure that they can be processed, packaged, and shipped to WIPP. Additionally, unexpected specific waste characteristics have challenged the project to identify and develop processing methods to handle problematic waste. The TWPC has several issues that have challenged the projects ability to process RH Waste. High Neutron Dose Rate resulting from both Californium and Curium in the waste stream challenge the RH-TRU 72-B limit for dose rate measured from the side of the package under normal conditions of transport, as specified in Chapter 5.0 of the RH-TRU 72-B SAR (i.e., ≤10 mrem/hour at 2 meters). Difficult to process waste in the hot cell has introduced processing and handling difficulties included problems associated with the disposition of prohibited items that fall out of the waste stream such as liquids, aerosol cans, etc. Lastly, multiple waste streams require characterization and AK challenge the ability to generate dose-to curie models for the waste. Repackaging is one solution to the high neutron dose rate issue. In parallel, an effort is underway to request a change to the TRAMPAC requirements to allow shielding in the drum or canister to reduce the impact of the high neutron dose rates. Due diligence on supporting AK efforts is important in ensuring adequate

  15. Predictions and implications of a poisson process model to describe corrosion of transuranic waste drums

    International Nuclear Information System (INIS)

    Lyon, B.F.; Holmes, J.A.; Wilbert, K.A.

    1995-01-01

    A risk assessment methodology is described in this paper to compare risks associated with immediate or near-term retrieval of transuranic (TRU) waste drums from bermed storage versus delayed retrieval. Assuming a Poisson process adequately describes corrosion, significant breaching of drums is expected to begin at - 15 and 24 yr for pitting and general corrosion, respectively. Because of this breaching, more risk will be incurred by delayed than by immediate retrieval

  16. Safety evaluation for packaging (onsite) for concrete-shielded RHTRU waste drum for the 327 postirradiation testing laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Adkins, H.E.

    1996-10-29

    This safety evaluation for packaging authorizes onsite transport of Type B quantities of radioactive material in the Concrete- Shielded Remote-Handled Transuranic Waste (RH TRU) Drum per WHC-CM-2-14, Hazardous Material Packaging and Shipping. The drum will be used for transport of 327 Building legacy waste from the 300 Area to the Transuranic Waste Storage and Assay Facility in the 200 West Area and on to a Solid Waste Storage Facility, also in the 200 Area.

  17. Characterization optimization for the National TRU waste system

    International Nuclear Information System (INIS)

    Basabilvazo, George T.; Countiss, S.; Moody, D.C.; Jennings, S.G.; Lott, S.A.

    2002-01-01

    On March 26, 1999, the Waste Isolation Pilot Plant (WIPP) received its first shipment of transuranic (TRU) waste. On November 26, 1999, the Hazardous Waste Facility Permit (HWFP) to receive mixed TRU waste at WIPP became effective. Having achieved these two milestones, facilitating and supporting the characterization, transportation, and disposal of TRU waste became the major challenges for the National TRU Waste Program. Significant challenges still remain in the scientific, engineering, regulatory, and political areas that need to be addressed. The National TRU Waste System Optimization Project has been established to identify, develop, and implement cost-effective system optimization strategies that address those significant challenges. Fundamental to these challenges is the balancing and prioritization of potential regulatory changes with potential technological solutions. This paper describes some of the efforts to optimize (to make as functional as possible) characterization activities for TRU waste.

  18. TRU waste transportation package development

    International Nuclear Information System (INIS)

    Eakes, R.G.; Lamoreaux, G.H.; Romesberg, L.E.; Sutherland, S.H.; Duffey, T.A.

    1980-01-01

    Inventories of the transuranic wastes buried or stored at various US DOE sites are tabulated. The leading conceptual design of Type-B packaging for contact-handled transuranic waste is the Transuranic Package Transporter (TRUPACT), a large metal container comprising inner and outer tubular steel frameworks which are separated by rigid polyurethane foam and sheathed with steel plate. Testing of TRUPACT is reported. The schedule for its development is given. 6 figures

  19. Storage drums for radio-active waste

    International Nuclear Information System (INIS)

    Knights, H.C.

    1982-01-01

    The lid of a storage drum for radioactive waste is secured by a series of clamps each of which has a hook for engaging the rim of the drum. Each clamp has an indicating means whereby a remote operator can check that the lid is secured to the drum. In a second embodiment, the position of an arm acts as a visual indication as to whether or not the clamp is in engagement with the container rim. (author)

  20. Leaching properties of solidified TRU waste forms

    International Nuclear Information System (INIS)

    Colombo, P.; Neilson, R.M. Jr.

    1979-01-01

    Safety analysis of waste forms requires an estimate of the ability of these forms to retain activity in the disposal environment. This program of leaching tests will determine the leaching properties of TRU contaminated incinerator ash waste forms using hydraulic cement, urea--formaldehyde, bitumen, and vinyl ester--styrene as solidification agents. Three types of leaching tests will be conducted, including both static and flow rate. Five generic groundwaters will be used. Equipment and procedures are described. Experiments have been conducted to determine plate out of 239 Pu, counter efficiency, and stability of counting samples

  1. CH-TRU Waste Content Codes

    Energy Technology Data Exchange (ETDEWEB)

    Washington TRU Solutions LLC

    2008-01-16

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments

  2. Waste Isolation Pilot Plant TruDock crane system analysis

    International Nuclear Information System (INIS)

    Morris, B.C.; Carter, M.

    1996-10-01

    The WIPP TruDock crane system located in the Waste Handling Building was identified in the WIPP Safety Analysis Report (SAR), November 1995, as a potential accident concern due to failures which could result in a dropped load. The objective of this analysis is to evaluate the frequency of failure of the TruDock crane system resulting in a dropped load and subsequent loss of primary containment, i.e. drum failure. The frequency of dropped loads was estimated to be 9.81E-03/year or approximately one every 102 years (or, for the 25% contingency, 7.36E-03/year or approximately one every 136 years). The dominant accident contributor was the failure of the cable/hook assemblies, based on failure data obtained from NUREG-0612, as analyzed by PLG, Inc. The WIPP crane system undergoes a rigorous test and maintenance program, crane operation is discontinued following any abnormality, and the crane operator and load spotter are required to be trained in safe crane operation, therefore it is felt that the WIPP crane performance will exceed the data presented in NUREG-0612 and the estimated failure frequency is felt to be conservative

  3. Development of a safe TRU transportation system (STRUTS) for DOE's TRU waste

    International Nuclear Information System (INIS)

    Edling, D.A.; Hopkins, D.R.; Walls, H.C.

    1978-01-01

    Transportation, the link between TRU waste generation and WIPP (Waste Isolation Pilot Project) and a vital link in the overall TRU waste management program, must be addressed. The program must have many facets: ensuring public and carrier acceptance, formation of a functional and current transportation data base, systems integration, maximum utilization of existing technology, and effective implementation and integration of the transport system into current and planned operational systems

  4. Development of SGS for various waste drums

    International Nuclear Information System (INIS)

    Kim, Ki-Hong; Ryu, Young-Gerl; Kwak, Kyung-Kil; Ji, Yong-Young

    2006-01-01

    Radioactive waste assay system was manufactured to measure the individual nuclides' activity in homogeneous and non-homogeneous waste drums and to exclude worker's exposure. After measuring the activities of all individual γ-emitters, our system was programmed to calculate the activities of α, Β emitters, automatically and then calculated total activities of drum by utilizing scaling factor (relationship between α, Β emitters and Co-60, Cs-137). In general, SGS (Segmented gamma Scanning system) divided a waste drum into 8 segments vertically, and also 8 sectors in one segment to minimize the error. And SGS can be determined the density of drum by using the several matrix correction methods such as transmission ratio, differential peak absorption and mean density correction, individually or by combination. However, from the NPPs and other nuclear facilities, various drum (100∼350L) could be generated. To analyze the activities of γ-emitters from various drums, we modified the collimator (horizontal and vertical) and added detector mover to the existing SGS system. As a results, the measurement error was <12% in a short distance (10 segments, Co-60; 47.87μCi and Cs-137; 101.16μCi) and was <25% in a long distance (8 segments, same sources). This system can be applied to the drum which TGS system does not analyze drum (for example, high density, high activities and large volume). (author)

  5. Gas generation from radiolytic attack of TRU-contaminated hydrogenous waste

    International Nuclear Information System (INIS)

    Zerwekh, A.

    1979-06-01

    In 1970, the Waste Management and Transportation Division of the Atomic Energy Commission ordered a segregation of transuranic (TRU)-contaminated solid wastes. Those below a contamination level of 10 nCi/g could still be buried; those above had to be stored retrievably for 20 y. The possibility that alpha-radiolysis of hydrogenous materials might produce toxic, corrosive, and flammable gases in retrievably stored waste prompted an investigation of gas identities and generation rates in the laboratory and field. Typical waste mixtures were synthesized and contaminated for laboratory experiments, and drums of actual TRU-contaminated waste were instrumented for field testing. Several levels of contamination were studied, as well as pressure, temperature, and moisture effects. G (gas) values were determined for various waste matrices, and degradation products were examined

  6. Development of nuclear waste concrete drum

    International Nuclear Information System (INIS)

    Wen Yinghui

    1995-06-01

    The raw materials selection and the properties for nuclear waste concrete drum, the formula and properties of the concrete, the specification and technical quality requirement of the drum were described. The manufacture essentials and technology, the experiments and checks as well as the effective quality control and quality assurance carried out in the course of production were presented. The developed nuclear waste drum has a simple structure, easily available raw materials and rational formula for concrete. The compressive strength of the drum is more than 70 MPa, the tensile strength is more than 5 MPa, the nitrogen permeability is (2.16∼3.6) x 10 -18 m 2 . The error of the drum in dimensions is +-2 mm. The external surface of the drum is smooth. The drum accords with China standards in the sandy surface, void and crack. The results shows China has the ability to develop and manufacture nuclear waste concrete container and lays the foundation for standardization and series of the nuclear waste container for packing and transporting nuclear wastes in China. (5 figs., 10 tabs.)

  7. DOE's plan for buried transuranic (TRU) contaminated waste

    International Nuclear Information System (INIS)

    Mathur, J.; D'Ambrosia, J.; Sease, J.

    1987-01-01

    Prior to 1970, TRU-contaminated waste was buried as low-level radioactive waste. In the Defense Waste Management Plan issued in 1983, the plan for this buried TRU-contaminated waste was to monitor the buried waste, take remedial actions, and to periodically evaluate the safety of the waste. In March 1986, the General Accounting Office (GAO) recommended that the Department of Energy (DOE) provide specific plans and cost estimates related to buried TRU-contaminated waste. This plan is in direct response to the GAO request. Buried TRU-contaminated waste and TRU-contaminated soil are located in numerous inactive disposal units at five DOE sites. The total volume of this material is estimated to be about 300,000 to 500,000 m 3 . The DOE plan for TRU-contaminated buried waste and TRU-contaminated soil is to characterize the disposal units; assess the potential impacts from the waste on workers, the surrounding population, and the environment; evaluate the need for remedial actions; assess the remedial action alternatives; and implement and verify the remedial actions as appropriate. Cost estimates for remedial actions for the buried TRU-contaminated waste are highly uncertain, but they range from several hundred million to the order of $10 billion

  8. Modeling VOC transport in simulated waste drums

    International Nuclear Information System (INIS)

    Liekhus, K.J.; Gresham, G.L.; Peterson, E.S.; Rae, C.; Hotz, N.J.; Connolly, M.J.

    1993-06-01

    A volatile organic compound (VOC) transport model has been developed to describe unsteady-state VOC permeation and diffusion within a waste drum. Model equations account for three primary mechanisms for VOC transport from a void volume within the drum. These mechanisms are VOC permeation across a polymer boundary, VOC diffusion across an opening in a volume boundary, and VOC solubilization in a polymer boundary. A series of lab-scale experiments was performed in which the VOC concentration was measured in simulated waste drums under different conditions. A lab-scale simulated waste drum consisted of a sized-down 55-gal metal drum containing a modified rigid polyethylene drum liner. Four polyethylene bags were sealed inside a large polyethylene bag, supported by a wire cage, and placed inside the drum liner. The small bags were filled with VOC-air gas mixture and the VOC concentration was measured throughout the drum over a period of time. Test variables included the type of VOC-air gas mixtures introduced into the small bags, the small bag closure type, and the presence or absence of a variable external heat source. Model results were calculated for those trials where the VOC permeability had been measured. Permeabilities for five VOCs [methylene chloride, 1,1,2-trichloro-1,2,2-trifluoroethane (Freon-113), 1,1,1-trichloroethane, carbon tetrachloride, and trichloroethylene] were measured across a polyethylene bag. Comparison of model and experimental results of VOC concentration as a function of time indicate that model accurately accounts for significant VOC transport mechanisms in a lab-scale waste drum

  9. TRU Waste Sampling Program: Volume I. Waste characterization

    International Nuclear Information System (INIS)

    Clements, T.L. Jr.; Kudera, D.E.

    1985-09-01

    Volume I of the TRU Waste Sampling Program report presents the waste characterization information obtained from sampling and characterizing various aged transuranic waste retrieved from storage at the Idaho National Engineering Laboratory and the Los Alamos National Laboratory. The data contained in this report include the results of gas sampling and gas generation, radiographic examinations, waste visual examination results, and waste compliance with the Waste Isolation Pilot Plant-Waste Acceptance Criteria (WIPP-WAC). A separate report, Volume II, contains data from the gas generation studies

  10. MCNP efficiency calculations of INEEL passive active neutron assay system for simulated TRU waste assays

    International Nuclear Information System (INIS)

    Yoon, W.Y.; Meachum, T.R.; Blackwood, L.G.; Harker, Y.D.

    2000-01-01

    The Idaho National Engineering and Environmental Laboratory Stored Waste Examination Pilot Plant (SWEPP) passive active neutron (PAN) radioassay system is used to certify transuranic (TRU) waste drums in terms of quantifying plutonium and other TRU element activities. Depending on the waste form involved, significant systematic and random errors need quantification in addition to the counting statistics. To determine the total uncertainty of the radioassay results, a statistical sampling and verification approach has been developed. In this approach, the total performance of the PAN nondestructive assay system is simulated using the computer models of the assay system, and the resultant output is compared with the known input to assess the total uncertainty. The supporting steps in performing the uncertainty analysis for the passive assay measurements in particular are as follows: (1) Create simulated waste drums and associated conditions; (2) Simulate measurements to determine the basic counting data that would be produced by the PAN assay system under the conditions specified; and (3) Apply the PAN assay system analysis algorithm to the set of counting data produced by simulating measurements to determine the measured plutonium mass. The validity of this simulation approach was verified by comparing simulated output against results from actual measurements using known plutonium sources and surrogate waste drums. The computer simulation of the PAN system performance uses the Monte Carlo N-Particle (MCNP) Code System to produce a neutron transport calculation for a simulated waste drum. Specifically, the passive system uses the neutron coincidence counting technique, utilizing the spontaneous fission of 240 Pu. MCNP application to the SWEPP PAN assay system uncertainty analysis has been very useful for a variety of waste types contained in 208-ell drums measured by a passive radioassay system. The application of MCNP to the active radioassay system is also feasible

  11. An approach for the reasonable TRU waste management in NUCEF

    International Nuclear Information System (INIS)

    Mineo, H.; Dojiri, S.; Takeshita, I.; Tsujino, T.; Matsumura, T.; Nishizawa, I.; Sugikawa, S.

    1995-01-01

    The Nuclear Fuel Cycle Safety Engineering Research Facility (NUCEF) has started its hot operation at the beginning of 1995, where TRU (transuranic) elements are used. The management of TRU waste arisen in the facility is very important issue. Liquid and solid wastes containing TRU elements are generated mainly from the Fuel Treatment System for critical experiments and from the researches of reprocessing process and TRU waste management for reprocessing plants using hot cells and glove-boxes. The TRU waste management in NUCEF is based on the classification of waste, and is to maximize the recycle of reagents and the reuse of TRU elements separated from the waste, as well as to reduce the waste volume and to lower the risk of waste by advanced separation and solidification. In the future, the separation and solidification of TRU elements in the tanks of liquid waste, and the classification and discrimination of solid wastes, will be carried out applying the outcomes of the development by the researches in NUCEF. (authors)

  12. Final Hanford Site Transuranic (TRU) Waste Characterization QA Project Plan

    International Nuclear Information System (INIS)

    GREAGER, T.M.

    2000-01-01

    The Quality Assurance Project Plan (QAPjP) has been prepared for waste characterization activities to be conducted by the Transuranic (TRU) Project at the Hanford Site to meet requirements set forth in the Waste Isolation Pilot Plan (WIPP) Hazardous Waste Facility Permit, 4890139088-TSDF, Attachment B, including Attachments B1 through B6 (WAP) (DOE, 1999a). The QAPjP describes the waste characterization requirements and includes test methods, details of planned waste sampling and analysis, and a description of the waste characterization and verification process. In addition, the QAPjP includes a description of the quality assurance/quality control (QA/QC) requirements for the waste characterization program. Before TRU waste is shipped to the WIPP site by the TRU Project, all applicable requirements of the QAPjP shall be implemented. Additional requirements necessary for transportation to waste disposal at WIPP can be found in the ''Quality Assurance Program Document'' (DOE 1999b) and HNF-2600, ''Hanford Site Transuranic Waste Certification Plan.'' TRU mixed waste contains both TRU radioactive and hazardous components, as defined in the WLPP-WAP. The waste is designated and separately packaged as either contact-handled (CH) or remote-handled (RH), based on the radiological dose rate at the surface of the waste container. RH TRU wastes are not currently shipped to the WIPP facility

  13. Major Components of the National TRU Waste System Optimization Project

    International Nuclear Information System (INIS)

    Moody, D.C.; Bennington, B.; Sharif, F.

    2002-01-01

    The National Transuranic (TRU) Program (NTP) is being optimized to allow for disposing of the legacy TRU waste at least 10 years earlier than originally planned. This acceleration will save the nation an estimated $713. The Department of Energy's (DOE'S) Carlsbad Field Office (CBFO) has initiated the National TRU Waste System Optimization Project to propose, and upon approvaI, implement activities that produce significant cost saving by improving efficiency, thereby accelerating the rate of TRU waste disposal without compromising safety. In its role as NTP agent of change, the National TRU Waste System Optimization Project (the Project) (1) interacts closely with all NTP activities. Three of the major components of the Project are the Central Characterization Project (CCP), the Central Confirmation Facility (CCF), and the MobiIe/Modular Deployment Program.

  14. A strategy for analysis of TRU waste characterization needs

    International Nuclear Information System (INIS)

    Leigh, C.D.; Chu, M.S.Y.; Arvizu, J.S.; Marcinkiewicz, C.J.

    1994-01-01

    Regulatory compliance and effective management of the nation's TRU waste requires knowledge about the constituents present in the waste. With limited resources, the DOE needs a cost-effective characterization program. In addition, the DOE needs a method for predicting the present and future analytical requirements for waste characterization. Thus, a strategy for predicting the present and future waste characterization needs that uses current knowledge of the TRU inventory and prioritization of the data needs is presented

  15. Low-Level Waste Drum Assay Intercomparison Study

    International Nuclear Information System (INIS)

    Greutzmacher, K.; Kuzminski, J.; Myers, S. C.

    2003-01-01

    Nuclear waste assay is an integral element of programs such as safeguards, waste management, and waste disposal. The majority of nuclear waste is packaged in drums and analyzed by various nondestructive assay (NDA) techniques to identify and quantify the radioactive content. Due to various regulations and the public interest in nuclear issues, the analytical results are required to be of high quality and supported by a rigorous Quality Assurance (QA) program. A valuable QA tool is an intercomparison program in which a known sample is analyzed by a number of different facilities. While transuranic waste (TRU) certified NDA teams are evaluated through the Performance Demonstration Program (PDP), low-level waste (LLW) assay specialists have not been afforded a similar opportunity. NDA specialists from throughout the DOE complex were invited to participate in this voluntary drum assay intercomparison study that was organized and facilitated by the Solid Waste Operations and the Safeguards Science and Technology groups at the Los Alamos National Laboratory and by Eberline Services. Each participating NDA team performed six replicate blind measurements of two 55-gallon drums with relatively low-density matrices (a 19.1 kg shredded paper matrix and a 54.4 kg mixed metal, rubber, paper and plastic matrix). This paper presents the results from this study, with an emphasis on discussing the lessons learned as well as desirable follow up programs for the future. The results will discuss the accuracy and precision of the replicate measurements for each NDA team as well as any issues that arose during the effort

  16. Plans for Managing Hanford Remote Handled Transuranic (TRU) Waste

    International Nuclear Information System (INIS)

    MCKENNEY, D.E.

    2001-01-01

    The current Hanford Site baseline and life-cycle waste forecast predicts that approximately 1,000 cubic meters of remote-handled transuranic (RH-TRU) waste will be generated by waste management and environmental restoration activities at Hanford. These 1,000 cubic meters, comprised of both transuranic and mixed transuranic (TRUM) waste, represent a significant portion of the total estimated inventory of RH-TRU to be disposed of at the Waste Isolation Pilot Plant (WIPP). A systems engineering approach is being followed to develop a disposition plan for each RH-TRU/TRUM waste stream at Hanford. A number of significant decision-making efforts are underway to develop and finalize these disposition plans, including: development and approval of a RH-TRU/TRUM Waste Project Management Plan, revision of the Hanford Waste Management Strategic Plan, the Hanford Site Options Study (''Vision 2012''), the Canyon Disposal Initiative Record-of-Decision, and the Hanford Site Solid (Radioactive and Hazardous) Waste Program Environmental Impact Statement (SW-EIS). Disposition plans may include variations of several options, including (1) sending most RH-TRU/TRUM wastes to WIPP, (2) deferrals of waste disposal decisions in the interest of both efficiency and integration with other planned decision dates and (3) disposition of some materials in place consistent with Department of Energy Orders and the regulations in the interest of safety, risk minimization, and cost. Although finalization of disposition paths must await completion of the aforementioned decision documents, significant activities in support of RH-TRU/TRUM waste disposition are proceeding, including Hanford participation in development of the RH TRU WIPP waste acceptance criteria, preparation of T Plant for interim storage of spent nuclear fuel sludge, sharing of technology information and development activities in cooperation with the Mixed Waste Focus Area, RH-TRU technology demonstrations and deployments, and

  17. Pre-title I safety evaluation for the retrieval operations of transuranic waste drums in the Solid Waste Disposal Facility. Revision 2

    International Nuclear Information System (INIS)

    Rabin, M.S.

    1992-08-01

    Phase I of the Transuranic (TRU) Waste Facility Line Item Project includes the retrieval and safe storage of the pad drums that are stored on TRU pads 2-6 in the Solid Waste Disposal Facility (SWDF). Drums containing TRU waste were placed on these pads as early as 1974. The pads, once filled, were mounded with soil. The retrieval activities will include the excavation of the soil, retrieval of the pad drums, placing the drums in overpacks (if necessary) and venting and purging the retrieved drums. Once the drums have been vented and purged, they will be transported to other pads within the SWDF or in a designated area until they are eventually treated as necessary for ultimate shipment to the Waste Isolation Pilot Plant in Carlsbad, New Mexico. This safety evaluation provides a bounding assessment of the radiological risk involved with the drum retrieval activities to the maximally exposed offsite individual and the co-located worker. The results of the analysis indicate that the risk to the maximally exposed offsite individual and the co-located worker using maximum frequencies and maximum consequences are within the acceptance criteria defined in WSRC Procedural Manual 9Q. The purpose of this evaluation is to demonstrate the incremental risk from the SWDF due to the retrieval activities for use as design input only. As design information becomes available, this evaluation can be revised to satisfy the safety analysis requirements of DOE Orders 4700 and 5480.23

  18. Performance test of a gamma/neutron mapper on stored TRU waste durms at the RWMC

    International Nuclear Information System (INIS)

    Gehrke, R.J.; Josten, N.E.; Lawrence, R.S.

    1995-01-01

    The results from a performance test of a γ- and neutron-radiation measurement instrument used to provide two-dimensional radiation field maps are reported. The performance test was conducted at the Transuranic Storage Area of the Radioactive Waste Management Complex (RWMC) where interim storage is provided for 55-gal. drums of TRU waste from the Department of Energy's Rocky Flats Plant. The performance test consisted of scanning drums stacked five high and five wide to identify high radiation areas and possible discrepancies with the waste manifest. Scans were taken at standoff distances of 15 cm, 30 cm, 45 cm and 90 cm. Data were acquired at scan speeds of 7.5 cm/s and 15 cm/s. The results of these scans are presented as one, two and three dimensional contour plots of the radiation fields. A comparison of these results with manifests of these drums are compared and discussed. While the T-radiation fields as measured by the Health Physicist and by the radiation maps are in general in agreement, the TRU content as given in the manifest did not often correlate with the neutron map

  19. Plasma processing of compacted drums of simulated radioactive waste

    International Nuclear Information System (INIS)

    Geimer, R.; Batdorf, J.; Larsen, M.M.

    1991-01-01

    The charter of the Department of Energy (DOE) Office of Technology Development (OTD) is to identify and develop technologies that have potential application in the treatment of DOE wastes. One particular waste of concern within the DOE is transuranic (TRU) waste, which is generated and stored at several DOE sites. High temperature DC arc generated plasma technology is an emerging treatment method for TRU waste, and its use has the potential to provide many benefits in the management of TRU. This paper begins by discussing the need for development of a treatment process for TRU waste, and the potential benefits that a plasma waste treatment system can provide in treating TRU waste. This is followed by a discussion of the results of a project conducted for the DOE to demonstrate the effectiveness of a plasma process for treating supercompacted TRU waste. 1 fig., 1 tab

  20. Centralized processing of contact-handled TRU waste feasibility analysis

    International Nuclear Information System (INIS)

    1986-12-01

    This report presents work for the feasibility study of central processing of contact-handled TRU waste. Discussion of scenarios, transportation options, summary of cost estimates, and institutional issues are a few of the subjects discussed

  1. Behavior of nuclides at plasma melting of TRU wastes

    International Nuclear Information System (INIS)

    Amakawa, Tadashi; Adachi, Kazuo

    2001-01-01

    Arc plasma heating technique can easily be formed at super high temperature, and can carry out stable heating without any effect of physical and chemical properties of the wastes. By focussing to these characteristics, this technique was experimentally investigated on behavior of TRU nuclides when applying TRU wastes forming from reprocessing process of used fuels to melting treatment by using a mimic non-radioactive nuclide. At first, according to mechanism determining the behavior of TRU nuclides, an element (mimic nuclide) to estimate the behavior was selected. And then, to zircaloy with high melting point or steel can simulated to metal and noncombustible wastes and fly ash, the mimic nuclide was added, prior to melting by using the arc plasma heating technique. As a result, on a case of either melting sample, it was elucidated that the nuclides hardly moved into their dusts. Then, the technique seems to be applicable for melting treatment of the TRU wastes. (G.K.)

  2. Hybrid Microwave Treatment of SRS TRU and Mixed Wastes

    International Nuclear Information System (INIS)

    Wicks, G.G.

    1999-01-01

    A new process, using hybrid microwave energy, has been developed as part of the Strategic Research and Development program and successfully applied to treatment of a wide variety of non-radioactive materials, representative of SRS transuranic (TRU) and mixed wastes. Over 35 simulated (non-radioactive) TRU and mixed waste materials were processed individually, as well as in mixed batches, using hybrid microwave energy, a new technology now being patented by Westinghouse Savannah River Company (WSRC)

  3. Press to compress contaminated wastes drums

    International Nuclear Information System (INIS)

    Prevost, J.

    1993-01-01

    This patent describes a press for contaminated wastes drums pressing. The press is made of a structure comprising a base and an upper stringer bind to the base by vertical bearers, a compression system comprising a main cylinder and a ram, connected to the upper stringer

  4. Gas formation in drum waste packages of Paks NPP

    International Nuclear Information System (INIS)

    Molnar, M.; Palcsu, L.; Svingor, E.; Szanto, Z.; Futo, I.; Ormai, P.

    2000-01-01

    Gas composition measurements have been carried out by mass spectrometry analysis of samples taken from the headspace of ten drum waste packages generated and temporarily stored at Paks NPP. Four drums contained compacted solid waste, three drums were filled with grouted (solidified) sludge and three drums contained solid waste without compaction. The drums have been equipped with a special gas outlet system to make repeated sampling possible. Based on the first measurements significant differences in the gas composition and the rate of gas generation among the drums were found. (author)

  5. Guidelines for developing certification programs for newly generated TRU waste

    International Nuclear Information System (INIS)

    Whitty, W.J.; Ostenak, C.A.; Pillay, K.K.S.; Geoffrion, R.R.

    1983-05-01

    These guidelines were prepared with direction from the US Department of Energy (DOE) Transuranic (TRU) Waste Management Program in support of the DOE effort to certify that newly generated TRU wastes meet the Waste Isolation Pilot Plant (WIPP) Waste Acceptance Criteria. The guidelines provide instructions for generic Certification Program preparation for TRU-waste generators preparing site-specific Certification Programs in response to WIPP requirements. The guidelines address all major aspects of a Certification Program that are necessary to satisfy the WIPP Waste Acceptance Criteria and their associated Compliance Requirements and Certification Quality Assurance Requirements. The details of the major element of a Certification Program, namely, the Certification Plan, are described. The Certification Plan relies on supporting data and control documentation to provide a traceable, auditable account of certification activities. Examples of specific parts of the Certification Plan illustrate the recommended degree of detail. Also, a brief description of generic waste processes related to certification activities is included

  6. MANAGEMENT OF TRANSURANIC (TRU) WASTE RETRIEVAL PROJECT RISKS SUCCESSES IN THE STARTUP OF THE HANFORD 200 AREA TRU WASTE RETRIEVAL PROJECT

    International Nuclear Information System (INIS)

    GREENWLL, R.D.

    2005-01-01

    A risk identification and mitigation method applied to the Transuranic (TRU) Waste Retrieval Project performed at the Hanford 200 Area burial grounds is described. Retrieval operations are analyzed using process flow diagramming. and the anticipated project contingencies are included in the Authorization Basis and operational plans. Examples of uncertainties assessed include degraded container integrity, bulged drums, unknown containers, and releases to the environment. Identification and mitigation of project risks contributed to the safe retrieval of over 1700 cubic meters of waste without significant work stoppage and below the targeted cost per cubic meter retrieved. This paper will be of interest to managers, project engineers, regulators, and others who are responsible for successful performance of waste retrieval and other projects with high safety and performance risks

  7. Repackaging of High Fissile TRU Waste at the Transuranic Waste Processing Center - 13240

    Energy Technology Data Exchange (ETDEWEB)

    Oakley, Brian; Heacker, Fred [WAI, TRU Waste Processing Center, 100 WIPP Road Lenoir City, TN 37771 (United States); McMillan, Bill [DOE, Oak Ridge Operations, Bldg. 2714, Oak Ridge, TN 37830 (United States)

    2013-07-01

    Twenty-six drums of high fissile transuranic (TRU) waste from Oak Ridge National Laboratory (ORNL) operations were declared waste in the mid-1980's and placed in storage with the legacy TRU waste inventory for future treatment and disposal at the Waste Isolation Pilot Plant (WIPP). Repackaging and treatment of the waste at the TRU Waste Packaging Center (TWPC) will require the installation of additional equipment and capabilities to address the hazards for handling and repackaging the waste compared to typical Contact Handled (CH) TRU waste that is processed at the TWPC, including potential hydrogen accumulation in legacy 6M/2R packaging configurations, potential presence of reactive plutonium hydrides, and significant low energy gamma radiation dose rates. All of the waste is anticipated to be repackaged at the TWPC and certified for disposal at WIPP. The waste is currently packaged in multiple layers of containers which presents additional challenges for repackaging activities due to the potential for the accumulation of hydrogen gas in the container headspace in quantities than could exceed the Lower Flammability Limit (LFL). The outer container for each waste package is a stainless steel 0.21 m{sup 3} (55-gal) drum which contains either a 0.04 m{sup 3} or 0.06 m{sup 3} (10-gal or 15-gal) 6M drum. The inner 2R container in each 6M drum is ∼12 cm (5 in) outside diameter x 30-36 cm (12-14 in) long and is considered to be a > 4 liter sealed container relative to TRU waste packaging criteria. Inside the 2R containers are multiple configurations of food pack cans, pipe nipples, and welded capsules. The waste contains significant quantities of high burn-up plutonium oxides and metals with a heavy weight percentage of higher atomic mass isotopes and the subsequent in-growth of significant quantities of americium. Significant low energy gamma radiation is expected to be present due to the americium in-growth. Radiation dose rates on inner containers are estimated

  8. Systematic evaluation of options to avoid generation of noncertifiable transuranic (TRU) waste at Los Alamos National Laboratory

    International Nuclear Information System (INIS)

    Boak, J.M.; Kosiewicz, S.T.; Triay, I.; Gruetzmacher, K.; Montoya, A.

    1998-03-01

    At present, >35% of the volume of newly generated transuranic (TRU) waste at Los Alamos National Laboratory is not certifiable for transport to the Waste Isolation Pilot Plant (WIPP). Noncertifiable waste would constitute 900--1,000 m 3 of the 2,600 m 3 of waste projected during the period of the Environmental Management (EM) Accelerated Cleanup: Focus on 2006 plan (DOE, 1997). Volume expansion of this waste to meet thermal limits would increase the shipped volume to ∼5,400 m 3 . This paper presents the results of efforts to define which TRU waste streams are noncertifiable at Los Alamos, and to prioritize site-specific options to reduce the volume of certifiable waste over the period of the EM Accelerated Cleanup Plan. A team of Los Alamos TRU waste generators and waste managers reviewed historic generation rates and thermal loads and current practices to estimate the projected volume and thermal load of TRU waste streams for Fiscal Years 1999--2006. These data defined four major problem TRU waste streams. Estimates were also made of the volume expansion that would be required to meet the permissible wattages for all waste. The four waste streams defined were: (1) 238 Pu-contaminated combustible waste from production of Radioactive Thermoelectric Generators (RTGs) with 238 Pu activity which exceeds allowable shipping limits by 10--100X. (2) 241 Am-contaminated cement waste from plutonium recovery processes (nitric and hydrochloric acid recovery) are estimated to exceed thermal limits by ∼3X. (3) 239 Pu-contaminated combustible waste, mainly organic waste materials contaminated with 239 Pu and 241 Am, is estimated to exceed thermal load requirements by a factor of ∼2X. (4) Oversized metal waste objects, (especially gloveboxes), cannot be shipped as is to WIPP because they will not fit in a standard waste box or drum

  9. DEVELOPMENT OF THE TRU WASTE TRANSPORTATION FLEET--A SUCCESS STORY

    International Nuclear Information System (INIS)

    Devarakonda, Murthy; Morrison, Cindy; Brown, Mike

    2003-01-01

    Since March 1999, the Waste Isolation Pilot Plant (WIPP), located in southeastern New Mexico, has been operated by the U.S. Department of Energy (DOE), Carlsbad Field Office (CBFO), as a repository for the permanent disposal of defense-related transuranic (TRU) waste. More than 1,450 shipments of TRU waste for WIPP disposal have been completed, and the WIPP is currently receiving 12 to 16 shipments per week from five DOE sites around the nation. One of the largest fleets of Type B packagings supports the transportation of TRU waste to WIPP. This paper discusses the development of this fleet since the original Certificate of Compliance (C of C) for the Transuranic Package Transporter-II (TRUPACT-II) was issued by the U.S. Nuclear Regulatory Commission (NRC) in 1989. Evolving site programs, closure schedules of major sites, and the TRU waste inventory at the various DOE sites have directed the sizing and packaging mix of this fleet. This paper discusses the key issues that guided this fleet development, including the following: While the average weight of a 55-gallon drum packaging debris could be less than 300 pounds (lbs.), drums containing sludge waste or compacted waste could approach the maximum allowable weight of 1,000 lbs. A TRUPACT-II shipment may consist of three TRUPACT-II packages, each of which is limited to a total weight of 19,250 lbs. Payload assembly weights dictated by ''as-built'' TRUPACT-II weights limit each drum to an average weight of 312 lbs when three TRUPACT-IIs are shipped. To optimize the shipment of heavier drums, the HalfPACT packaging was designed as a shorter and lighter version of the TRUPACT-II to accommodate a heavier load. Additional packaging concepts are currently under development, including the ''TRUPACT-III'' packaging being designed to address ''oversized'' boxes that are currently not shippable in the TRUPACT-II or HalfPACT due to size constraints. Shipment optimization is applicable not only to the addition of new

  10. Vitrification of TRU wastes at Rocky Flats Plant

    International Nuclear Information System (INIS)

    Williams, P.M.; Johnson, A.J.; Ledford, J.A.

    1979-01-01

    Immobilization of incinerator ash and various noncombustible TRU wastes was investigated. In three different research projects borosilicate glass proved to be the best candidate for TRU waste fixation. This glass has excellent chemical durability, long-term stability in the presence of radiation, and will withstand continuous temperatures up to 400 0 C without devitrification. In addition, wastes prepared in the form of glass will attain densities of approximately 2500 kg/m 3 (2.5 g/cc). The free forming method of producing glass buttons provides a very simple, consistent, low maintenance way of producing a final waste form for transporting and either retrievable or permanent storage for TRU waste. The vitrification process produces a durable glass from the low density ash generated by the fluidized bed incinerator process and provides volume and weight reductions that are superior to other fixation processes. This results in decreased transportation and storage costs

  11. Los Alamos Plutonium Facility newly generated TRU waste certification

    International Nuclear Information System (INIS)

    Gruetzmacher, K.; Montoya, A.; Sinkule, B.; Maez, M.

    1997-01-01

    This paper presents an overview of the activities being planned and implemented to certify newly generated contact handled transuranic (TRU) waste produced by Los Alamos National Laboratory's (LANL's) Plutonium Facility. Certifying waste at the point of generation is the most important cost and labor saving step in the WIPP certification process. The pedigree of a waste item is best known by the originator of the waste and frees a site from expensive characterization activities such as those associated with legacy waste. Through a cooperative agreement with LANLs Waste Management Facility and under the umbrella of LANLs WIPP-related certification and quality assurance documents, the Plutonium Facility will be certifying its own newly generated waste. Some of the challenges faced by the Plutonium Facility in preparing to certify TRU waste include the modification and addition of procedures to meet WIPP requirements, standardizing packaging for TRU waste, collecting processing documentation from operations which produce TRU waste, and developing ways to modify waste streams which are not certifiable in their present form

  12. The Advantages of Fixed Facilities in Characterizing TRU Wastes

    International Nuclear Information System (INIS)

    FRENCH, M.S.

    2000-01-01

    In May 1998 the Hanford Site started developing a program for characterization of transuranic (TRU) waste for shipment to the Waste Isolation Pilot Plant (WIPP) in New Mexico. After less than two years, Hanford will have a program certified by the Carlsbad Area Office (CAO). By picking a simple waste stream, taking advantage of lessons learned at the other sites, as well as communicating effectively with the CAO, Hanford was able to achieve certification in record time. This effort was further simplified by having a centralized program centered on the Waste Receiving and Processing (WRAP) Facility that contains most of the equipment required to characterize TRU waste. The use of fixed facilities for the characterization of TRU waste at sites with a long-term clean-up mission can be cost effective for several reasons. These include the ability to control the environment in which sensitive instrumentation is required to operate and ensuring that calibrations and maintenance activities are scheduled and performed as an operating routine. Other factors contributing to cost effectiveness include providing approved procedures and facilities for handling hazardous materials and anticipated contingencies and performing essential evolutions, and regulating and smoothing the work load and environmental conditions to provide maximal efficiency and productivity. Another advantage is the ability to efficiently provide characterization services to other sites in the Department of Energy (DOE) Complex that do not have the same capabilities. The Waste Receiving and Processing (WRAP) Facility is a state-of-the-art facility designed to consolidate the operations necessary to inspect, process and ship waste to facilitate verification of contents for certification to established waste acceptance criteria. The WRAP facility inspects, characterizes, treats, and certifies transuranic (TRU), low-level and mixed waste at the Hanford Site in Washington state. Fluor Hanford operates the $89

  13. RH-TRU Waste Content Codes (RH-TRUCON)

    International Nuclear Information System (INIS)

    2007-01-01

    The Remote-Handled Transuranic (RH-TRU) Content Codes (RH-TRUCON) document describes the inventory of RH-TRU waste within the transportation parameters specified by the Remote-Handled Transuranic Waste Authorized Methods for Payload Control (RH-TRAMPAC).1 The RH-TRAMPAC defines the allowable payload for the RH-TRU 72-B. This document is a catalog of RH-TRU 72-B authorized contents by site. A content code is defined by the following components: A two-letter site abbreviation that designates the physical location of the generated/stored waste (e.g., ID for Idaho National Laboratory [INL]). The site-specific letter designations for each of the sites are provided in Table 1. A three-digit code that designates the physical and chemical form of the waste (e.g., content code 317 denotes TRU Metal Waste). For RH-TRU waste to be transported in the RH-TRU 72-B, the first number of this three-digit code is '3.' The second and third numbers of the three-digit code describe the physical and chemical form of the waste. Table 2 provides a brief description of each generic code. Content codes are further defined as subcodes by an alpha trailer after the three-digit code to allow segregation of wastes that differ in one or more parameter(s). For example, the alpha trailers of the subcodes ID 322A and ID 322B may be used to differentiate between waste packaging configurations. As detailed in the RH-TRAMPAC, compliance with flammable gas limits may be demonstrated through the evaluation of compliance with either a decay heat limit or flammable gas generation rate (FGGR) limit per container specified in approved content codes. As applicable, if a container meets the watt*year criteria specified by the RH-TRAMPAC, the decay heat limits based on the dose-dependent G value may be used as specified in an approved content code. If a site implements the administrative controls outlined in the RH-TRAMPAC and Appendix 2.4 of the RH-TRU Payload Appendices, the decay heat or FGGR limits based

  14. RH-TRU Waste Content Codes (RH-TRUCON)

    Energy Technology Data Exchange (ETDEWEB)

    Washington TRU Solutions LLC

    2007-08-01

    The Remote-Handled Transuranic (RH-TRU) Content Codes (RH-TRUCON) document describes the inventory of RH-TRU waste within the transportation parameters specified by the Remote-Handled Transuranic Waste Authorized Methods for Payload Control (RH-TRAMPAC).1 The RH-TRAMPAC defines the allowable payload for the RH-TRU 72-B. This document is a catalog of RH-TRU 72-B authorized contents by site. A content code is defined by the following components: • A two-letter site abbreviation that designates the physical location of the generated/stored waste (e.g., ID for Idaho National Laboratory [INL]). The site-specific letter designations for each of the sites are provided in Table 1. • A three-digit code that designates the physical and chemical form of the waste (e.g., content code 317 denotes TRU Metal Waste). For RH-TRU waste to be transported in the RH-TRU 72-B, the first number of this three-digit code is “3.” The second and third numbers of the three-digit code describe the physical and chemical form of the waste. Table 2 provides a brief description of each generic code. Content codes are further defined as subcodes by an alpha trailer after the three-digit code to allow segregation of wastes that differ in one or more parameter(s). For example, the alpha trailers of the subcodes ID 322A and ID 322B may be used to differentiate between waste packaging configurations. As detailed in the RH-TRAMPAC, compliance with flammable gas limits may be demonstrated through the evaluation of compliance with either a decay heat limit or flammable gas generation rate (FGGR) limit per container specified in approved content codes. As applicable, if a container meets the watt*year criteria specified by the RH-TRAMPAC, the decay heat limits based on the dose-dependent G value may be used as specified in an approved content code. If a site implements the administrative controls outlined in the RH-TRAMPAC and Appendix 2.4 of the RH-TRU Payload Appendices, the decay heat or FGGR

  15. RH-TRU Waste Content Codes (RH-TRUCON)

    Energy Technology Data Exchange (ETDEWEB)

    Washington TRU Solutions

    2007-05-30

    The Remote-Handled Transuranic (RH-TRU) Content Codes (RH-TRUCON) document describes the inventory of RH-TRU waste within the transportation parameters specified by the Remote-Handled Transuranic Waste Authorized Methods for Payload Control (RH-TRAMPAC).1 The RH-TRAMPAC defines the allowable payload for the RH-TRU 72-B. This document is a catalog of RH-TRU 72-B authorized contents by site. A content code is defined by the following components: • A two-letter site abbreviation that designates the physical location of the generated/stored waste (e.g., ID for Idaho National Laboratory [INL]). The site-specific letter designations for each of the sites are provided in Table 1. • A three-digit code that designates the physical and chemical form of the waste (e.g., content code 317 denotes TRU Metal Waste). For RH-TRU waste to be transported in the RH-TRU 72-B, the first number of this three-digit code is “3.” The second and third numbers of the three-digit code describe the physical and chemical form of the waste. Table 2 provides a brief description of each generic code. Content codes are further defined as subcodes by an alpha trailer after the three-digit code to allow segregation of wastes that differ in one or more parameter(s). For example, the alpha trailers of the subcodes ID 322A and ID 322B may be used to differentiate between waste packaging configurations. As detailed in the RH-TRAMPAC, compliance with flammable gas limits may be demonstrated through the evaluation of compliance with either a decay heat limit or flammable gas generation rate (FGGR) limit per container specified in approved content codes. As applicable, if a container meets the watt*year criteria specified by the RH-TRAMPAC, the decay heat limits based on the dose-dependent G value may be used as specified in an approved content code. If a site implements the administrative controls outlined in the RH-TRAMPAC and Appendix 2.4 of the RH-TRU Payload Appendices, the decay heat or FGGR

  16. RH-TRU Waste Content Codes (RH-Trucon)

    International Nuclear Information System (INIS)

    2007-01-01

    The Remote-Handled Transuranic (RH-TRU) Content Codes (RH-TRUCON) document describes the inventory of RH-TRU waste within the transportation parameters specified by the Remote-Handled Transuranic Waste Authorized Methods for Payload Control (RH-TRAMPAC).1 The RH-TRAMPAC defines the allowable payload for the RH-TRU 72-B. This document is a catalog of RH-TRU 72-B authorized contents by site. A content code is defined by the following components: A two-letter site abbreviation that designates the physical location of the generated/stored waste (e.g., ID for Idaho National Laboratory [INL]). The site-specific letter designations for each of the sites are provided in Table 1. A three-digit code that designates the physical and chemical form of the waste (e.g., content code 317 denotes TRU Metal Waste). For RH-TRU waste to be transported in the RH-TRU 72-B, the first number of this three-digit code is '3.' The second and third numbers of the three-digit code describe the physical and chemical form of the waste. Table 2 provides a brief description of each generic code. Content codes are further defined as subcodes by an alpha trailer after the three-digit code to allow segregation of wastes that differ in one or more parameter(s). For example, the alpha trailers of the subcodes ID 322A and ID 322B may be used to differentiate between waste packaging configurations. As detailed in the RH-TRAMPAC, compliance with flammable gas limits may be demonstrated through the evaluation of compliance with either a decay heat limit or flammable gas generation rate (FGGR) limit per container specified in approved content codes. As applicable, if a container meets the watt*year criteria specified by the RH-TRAMPAC, the decay heat limits based on the dose-dependent G value may be used as specified in an approved content code. If a site implements the administrative controls outlined in the RH-TRAMPAC and Appendix 2.4 of the RH-TRU Payload Appendices, the decay heat or FGGR limits based

  17. Fire propagation through arrays of solid-waste storage drums

    International Nuclear Information System (INIS)

    Smith, S.T.; Hinkle, A.W.

    1995-01-01

    The extent of propagation of a fire through drums of solid waste has been an unresolved issue that affects all solid-waste projects and existing solid-waste storage and handling facilities at the Hanford site. The issue involves the question of how many drums of solid waste within a given fire area will be consumed in a design-basis fire for given parameters such as drum loading, storage arrays, initiating events, and facility design. If the assumption that all drums of waste within a given fire area are consumed proves valid, then the construction costs of solid waste facilities may be significantly increased

  18. Infrared thermography applied to monitoring of radioactive waste drums

    International Nuclear Information System (INIS)

    Kelmer, P.; Camarano, D.M.; Calado, F.; Phillip, B.; Viana, C.; Andrade, R.M.

    2013-01-01

    The use of thermography in the inspection of drums containing radioactive waste is being stimulated by the absence of physical contact. In Brazil the majority of radioactive wastes are compacted solids packed in metal drums stored temporarily for decades and requires special attention. These drums have only one qualitative indication of the radionuclides present. However, its structural condition is not followed systematically. The aim of this work is presents a methodology by applying thermography for monitoring the structural condition of drums containing radioactive waste in order to detect degraded regions of the drums. (author)

  19. RH-TRU Waste Content Codes (RH TRUCON)

    International Nuclear Information System (INIS)

    2007-01-01

    The Remote-Handled Transuranic (RH-TRU) Content Codes (RH-TRUCON) document describes the inventory of RH-TRU waste within the transportation parameters specified by the Remote-Handled Transuranic Waste Authorized Methods for Payload Control (RH-TRAMPAC).1 The RH-TRAMPAC defines the allowable payload for the RH-TRU 72-B. This document is a catalog of RH-TRU 72-B authorized contents by site. A content code is defined by the following components: (1) A two-letter site abbreviation that designates the physical location of the generated/stored waste (e.g., ID for Idaho National Laboratory [INL]). The site-specific letter designations for each of the sites are provided in Table 1. (2) A three-digit code that designates the physical and chemical form of the waste (e.g., content code 317 denotes TRU Metal Waste). For RH-TRU waste to be transported in the RH-TRU 72-B, the first number of this three-digit code is ''3''. The second and third numbers of the three-digit code describe the physical and chemical form of the waste. Table 2 provides a brief description of each generic code. Content codes are further defined as subcodes by an alpha trailer after the three-digit code to allow segregation of wastes that differ in one or more parameter(s). For example, the alpha trailers of the subcodes ID 322A and ID 322B may be used to differentiate between waste packaging configurations. As detailed in the RH-TRAMPAC, compliance with flammable gas limits may be demonstrated through the evaluation of compliance with either a decay heat limit or flammable gas generation rate (FGGR) limit per container specified in approved content codes. As applicable, if a container meets the watt*year criteria specified by the RH-TRAMPAC, the decay heat limits based on the dose-dependent G value may be used as specified in an approved content code. If a site implements the administrative controls outlined in the RH-TRAMPAC and Appendix 2.4 of the RH-TRU Payload Appendices, the decay heat or FGGR

  20. RH-TRU Waste Content Codes (RH TRUCON)

    Energy Technology Data Exchange (ETDEWEB)

    Washington TRU Solutions

    2007-05-01

    The Remote-Handled Transuranic (RH-TRU) Content Codes (RH-TRUCON) document describes the inventory of RH-TRU waste within the transportation parameters specified by the Remote-Handled Transuranic Waste Authorized Methods for Payload Control (RH-TRAMPAC).1 The RH-TRAMPAC defines the allowable payload for the RH-TRU 72-B. This document is a catalog of RH-TRU 72-B authorized contents by site. A content code is defined by the following components: • A two-letter site abbreviation that designates the physical location of the generated/stored waste (e.g., ID for Idaho National Laboratory [INL]). The site-specific letter designations for each of the sites are provided in Table 1. • A three-digit code that designates the physical and chemical form of the waste (e.g., content code 317 denotes TRU Metal Waste). For RH-TRU waste to be transported in the RH-TRU 72-B, the first number of this three-digit code is “3.” The second and third numbers of the three-digit code describe the physical and chemical form of the waste. Table 2 provides a brief description of each generic code. Content codes are further defined as subcodes by an alpha trailer after the three-digit code to allow segregation of wastes that differ in one or more parameter(s). For example, the alpha trailers of the subcodes ID 322A and ID 322B may be used to differentiate between waste packaging configurations. As detailed in the RH-TRAMPAC, compliance with flammable gas limits may be demonstrated through the evaluation of compliance with either a decay heat limit or flammable gas generation rate (FGGR) limit per container specified in approved content codes. As applicable, if a container meets the watt*year criteria specified by the RH-TRAMPAC, the decay heat limits based on the dose-dependent G value may be used as specified in an approved content code. If a site implements the administrative controls outlined in the RH-TRAMPAC and Appendix 2.4 of the RH-TRU Payload Appendices, the decay heat or FGGR

  1. TRU waste certification and TRUPACT-2 payload verification

    International Nuclear Information System (INIS)

    Hunter, E.K.; Johnson, J.E.

    1990-01-01

    The Waste Isolation Pilot Plant (WIPP) established a policy that requires each waste shipper to verify that all waste shipments meet the requirements of the Waste Acceptance Criteria (WAC) prior to being shipped. This verification provides assurance that transuranic (TRU) wastes meet the criteria while still retained in a facility where discrepancies can be immediately corrected. Each Department of Energy (DOE) TRU waste facility planning to ship waste to the Waste Isolation Pilot Plant (WIPP) is required to develop and implement a specific program including Quality Assurance (QA) provisions to verify that waste is in full compliance with WIPP's WAC. This program is audited by a composite DOE and contractor audit team prior to granting the facility permission to certify waste. During interaction with the Nuclear Regulatory Commission (NRC) on payload verification for shipping in TRUPACT-II, a similar system was established by DOE. The TRUPACT-II Safety Analysis Report (SAR) contains the technical requirements and physical and chemical limits that payloads must meet (like the WAC). All shippers must plan and implement a payload control program including independent QA provisions. A similar composite audit team will conduct preshipment audits, frequent subsequent audits, and operations inspections to verify that all TRU waste shipments in TRUPACT-II meet the requirements of the Certificate of Compliance issued by the NRC which invokes the SAR requirements. 1 fig

  2. An improved segmented gamma scanning for radioactive waste drums

    International Nuclear Information System (INIS)

    Liu Cheng; Wang Dezhong; Bai Yunfei; Qian Nan

    2010-01-01

    In this paper, the equivalent radius of radioactive sources in each segment is determined by analyzing the different responses of the two identical detectors, and an improved segmented gamma scanning is used to assay waste drums containing mainly organic materials, and proved by an established simulation model. The simulated radioactivity distributions in homogenous waste drum and an experimental heterogeneous waste drum were compared with those of traditional segmented gamma scanning. The results show that our method is good in performance and can be used for analyzing the waste drums. (authors)

  3. TRU waste-assay instrumentation and application in nuclear-facility decommissioning

    International Nuclear Information System (INIS)

    Umbarger, C.J.

    1982-01-01

    The Los Alamos TRU waste assay program is developing measurement techniques for TRU and other radioactive waste materials generated by the nuclear industry, including decommissioning programs. Systems are now being fielded for test and evaluation purposes at DOE TRU waste generators. The transfer of this technology to other facilities and the commercial instrumentation sector is well in progress. 6 figures

  4. Solidification of TRU wastes in a ceramic matrix

    International Nuclear Information System (INIS)

    Loida, A.; Schubert, G.

    1991-01-01

    Aluminumsilicate based ceramic materials have been evaluated as an alternative waste form for the incorporation of TRU wastes. These waste forms are free of water and - cannot generate hydrogen radiolyticly, - they show good compatibility between the compounds of the waste and the matrix, - they are resistent against aqueous solutions, heat and radiation. R and D-work has been performed to demonstrate the suitability of this waste form for the immobilization of TRU-wastes. Four kinds of original TRU-waste streams and a mixture of all of them have been immobilized by ceramization, using glove box and remote operation technique as well. Clay minerals, (kaolinite, bentonite) and reactive corundum were selected as ceramic raw materials (KAB 78) in an appropriate ratio yielding 78 wt% Al 2 O 3 and 22 wt%SiO 2 . The main process steps are (i) pretreatment of the liquid waste (concentration, denitration, neutralization, solid- liquid separation), (ii) mixing with ceramic raw materials and forming, (iii) heat treatment with T max. of 1300 0 C for 15 minutes. The waste load of the ceramic matrix has been increased gradually from 20 to 50, in some cases to 60 wt.%

  5. Preliminary fire hazard analysis for the PUTDR and TRU trenches in the Solid Waste Burial Ground

    International Nuclear Information System (INIS)

    Gaschott, L.J.

    1995-01-01

    This document represents the Preliminary Fire Hazards Analysis for the Pilot Unvented TRU Drum Retrieval effort and for the Transuranic drum trenches in the low level burial grounds. The FHA was developed in accordance with DOE Order 5480.7A to address major hazards inherent in the facility

  6. Progress report on disposal concept for TRU waste in Japan

    International Nuclear Information System (INIS)

    2000-03-01

    The object of this report is to contribute towards establishing a national TRU waste disposal program by integrating the results of research and development work carried out by JNC and the electricity utilities and summarizing the findings concerning safe methods for TRU waste disposal. The report consists of 5 chapters: the first describes the boundary conditions for the review of the TRU waste disposal concept (including geological conditions) and the basic concept adopted; the second describes the generation and characteristics of TRU waste and the third outlines the disposal technology; the fourth gives the key of the safety assessment and the fifth presents the conclusions of the report and lists issues for future consideration. The geological environment of Japan is simply classified into crystalline and sedimentary rock types (in terms of groundwater flow properties and rock strength) and a set of target conditions/properties for each rock type is then established. Based on this, a case which represents the basis for performance assessment (the reference case) will be defined. Alternatives to the reference case are studied to investigate the flexibility of the disposal concept. Under the conditions assumed in this study, the perturbing events considered showed no significant effects on the dose at the 100 meter evaluation point, owing to the relatively high efficiency of the natural barrier. However, the significant effect of these events on nuclide from the EBS shows that, in the case of a less efficient natural barrier, their effects could influence resulting dose. (S.Y.)

  7. Status of microwave process development for RH-TRU [remote-handled transuranic] wastes at Oak Ridge National Laboratory

    International Nuclear Information System (INIS)

    White, T.L.; Youngblood, E.L.; Berry, J.B.; Mattus, A.J.

    1990-01-01

    The Oak Ridge National Laboratory (ORNL) Waste Handling and Packaging Plant is developing a microwave process to reduce and solidify remote-handled transuranic (RH-TRU) liquids and sludges presently stored in large tanks at ORNL. Testing has recently begun on an in-drum microwave process using nonradioactive RH-TRU surrogates. The microwave process development effort has focused on an in-drum process to dry the RH-TRU liquids and sludges in the final storage container and then melt the salt residues to form a solid monolith. A 1/3-scale proprietary microwave applicator was designed, fabricated, and tested to demonstrate the essential features of the microwave design and to provide input into the design of the full-scale applicator. The microwave fields are uniform in one dimension to reduce the formation of hot spots on the microwaved wasteform. The final wasteform meets the waste acceptance criteria for the Waste Isolation Pilot Plant, a federal repository for defense transuranic wastes near Carlsbad, New Mexico. 7 refs., 1 fig., 1 tab

  8. Parametric Criticality Safety Calculations for Arrays of TRU Waste Containers

    Energy Technology Data Exchange (ETDEWEB)

    Gough, Sean T. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2017-10-26

    The Nuclear Criticality Safety Division (NCSD) has performed criticality safety calculations for finite and infinite arrays of transuranic (TRU) waste containers. The results of these analyses may be applied in any technical area onsite (e.g., TA-54, TA-55, etc.), as long as the assumptions herein are met. These calculations are designed to update the existing reference calculations for waste arrays documented in Reference 1, in order to meet current guidance on calculational methodology.

  9. Test Plan: WIPP bin-scale CH TRU waste tests

    International Nuclear Information System (INIS)

    Molecke, M.A.

    1990-08-01

    This WIPP Bin-Scale CH TRU Waste Test program described herein will provide relevant composition and kinetic rate data on gas generation and consumption resulting from TRU waste degradation, as impacted by synergistic interactions due to multiple degradation modes, waste form preparation, long-term repository environmental effects, engineered barrier materials, and, possibly, engineered modifications to be developed. Similar data on waste-brine leachate compositions and potentially hazardous volatile organic compounds released by the wastes will also be provided. The quantitative data output from these tests and associated technical expertise are required by the WIPP Performance Assessment (PA) program studies, and for the scientific benefit of the overall WIPP project. This Test Plan describes the necessary scientific and technical aspects, justifications, and rational for successfully initiating and conducting the WIPP Bin-Scale CH TRU Waste Test program. This Test Plan is the controlling scientific design definition and overall requirements document for this WIPP in situ test, as defined by Sandia National Laboratories (SNL), scientific advisor to the US Department of Energy, WIPP Project Office (DOE/WPO). 55 refs., 16 figs., 19 tabs

  10. Waste streams that preferentially corrode 55-gallon steel storage drums

    International Nuclear Information System (INIS)

    Zirker, L.R.; Beitel, G.A.; Reece, C.M.

    1995-06-01

    When 55-gal steel drum waste containers fail in service, i.e., leak, corrode or breach, the standard fix has been to overpack the drum. When a drum fails and is overpacked into an 83-gal overpack drum, there are several negative consequences. Identifying waste streams that preferentially corrode steel drums is essential to the pollution prevention philosophy that ''an ounce of prevention is worth a pound of cure.'' It is essential that facilities perform pollution prevention measures at the front end of processes to reduce pollution on the back end. If these waste streams can be identified before they are packaged, the initial drum packaging system could be fortified or increased to eliminate future drum failures, breaches, clean-ups, and the plethora of other consequences. Therefore, a survey was conducted throughout the US Department of Energy complex for information concerning waste streams that have demonstrated preferential corrosion of 55-gal steel drums. From 21 site contacts, 21 waste streams were so identified. The major components of these waste streams include acids, salts, and solvent liquids, sludges, and still bottoms. The solvent-based waste streams typically had the shortest time to failure, 0.5 to 2 years. This report provides the results of this survey and research

  11. TRU waste certification and TRUPACT-II payload verification

    International Nuclear Information System (INIS)

    Hunter, E.K.; Johnson, J.E.

    1990-01-01

    The Waste Isolation Pilot Plant (WIPP) established a policy (subsequently confirmed and required by DOE Order 5820.2A, Radioactive Waste Management, September 1988) that requires each waste shipper to verify that all waste shipments meet the requirements of the Waste Acceptance Criteria (WAC) prior to being shipped. This verification provides assurance that transuranic (TRU) wastes meet the criteria while still retained in a facility where discrepancies can be immediately corrected. In this manner, problems that would arise if WAC violations were discovered at the receiver, where corrective facilities are not available, are avoided. Each Department of Energy (DOE) TRU waste facility planning to ship waste to the Waste Isolation Pilot Plant (WIPP) is required to develop and implement a specific program including Quality Assurance (QA) provisions to verify that waste is in full compliance with WIPP's WAC. This program is audited by a composite DOE and contractor audit team prior to granting the facility permission to certify waste. During interaction with the Nuclear Regulatory Commission (NRC) on payload verification for shipping in TRUPACT-II, a similar system was established by DOE. The TRUPACT-II Safety Analysis Report (SAR) contains the technical requirements and physical and chemical limits that payloads must meet (like the WAC). All shippers must plan and implement a payload control program including independent QA provisions. A similar composite audit team will conduct preshipment audits, frequent subsequent audits, and operations inspections to verify that all TRU waste shipments in TRUPACT-II meet the requirements of the Certificate of Compliance (C of C) issued by the NRC which invokes the SAR requirements. 1 fig

  12. Development of waste packages for TRU-disposal. 5. Development of cylindrical metal package for TRU wastes

    International Nuclear Information System (INIS)

    Mine, Tatsuya; Mizubayashi, Hiroshi; Asano, Hidekazu; Owada, Hitoshi; Otsuki, Akiyoshi

    2005-01-01

    Development of the TRU waste package for hulls and endpieces compression canisters, which include long-lived and low sorption nuclides like C-14 is essential and will contribute a lot to a reasonable enhancement of safety and economy of the TRU-disposal system. The cylindrical metal package made of carbon steel for canisters to enhance the efficiency of the TRU-disposal system and to economically improve their stacking conditions was developed. The package is a welded cylindrical construction with a deep drawn upper cover and a disc plate for a bottom cover. Since the welding is mainly made only for an upper cover and a bottom disc plate, this package has a better containment performance for radioactive nuclide and can reduce the cost for construction and manufacturing including its welding control. Furthermore, this package can be laid down in pile for stacking in the circular cross section disposal tunnel for the sedimentary rock, which can drastically minimize the space for disposal tunnel as mentioned previously in TRU report. This paper reports the results of the study for application of newly developed metal package into the previous TRU-disposal system and for the stacking equipment for the package. (author)

  13. EXAMPLE OF A RISK-BASED DISPOSAL APPROVAL: SOLIDIFICATION OF HANFORD SITE TRANSURANIC (TRU) WASTE

    International Nuclear Information System (INIS)

    PRIGNANO AL

    2007-01-01

    The Hanford Site requested, and the U.S. Environmental Protection Agency (EPA) Region 10 approved, a Toxic Substances Control Act of 1976 (TSCA) risk-based disposal approval (RBDA) for solidifying approximately four cubic meters of waste from a specific area of one of the K East Basin: the North Loadout Pit (NLOP). The NLOP waste is a highly radioactive sludge that contained polychlorinated biphenyls (PCBs) regulated under TSCA. The prescribed disposal method for liquid PCB waste under TSCA regulations is either thermal treatment or decontamination. Due to the radioactive nature of the waste, however, neither thermal treatment nor decontamination was a viable option. As a result, the proposed treatment consisted of solidifying the material to comply with waste acceptance criteria at the Waste Isolation Pilot Plant (WPP) in Carlsbad, New Mexico, or possibly the Environmental Restoration Disposal Facility at the Hanford Site, depending on the resulting transuranic (TRU) content of the stabilized waste. The RBDA evaluated environmental risks associated with potential airborne PCBs. In addition, the RBDA made use of waste management controls already in place at the treatment unit. The treatment unit, the T Plant Complex, is a Resource Conservation and Recovery Act of 1976 (RCRA)-permitted facility used for storing and treating radioactive waste. The EPA found that the proposed activities did not pose an unreasonable risk to human health or the environment. Treatment took place from October 26,2005 to June 9,2006, and 332 208-liter (55-gallon) containers of solidified waste were produced. All treated drums assayed to date are TRU and will be disposed at WIPP

  14. Modeling unsteady-state VOC transport in simulated waste drums

    International Nuclear Information System (INIS)

    Liekhus, K.J.; Gresham, G.L.; Peterson, E.S.; Rae, C.; Hotz, N.J.; Connolly, M.J.

    1994-01-01

    This report is a revision of an EG ampersand G Idaho informal report originally titled Modeling VOC Transport in Simulated Waste Drums. A volatile organic compound (VOC) transport model has been developed to describe unsteady-state VOC permeation and diffusion within a waste drum. Model equations account for three primary mechanisms for VOC transport from a void volume within the drum. These mechanisms are VOC permeation across a polymer boundary, VOC diffusion across an opening in a volume boundary, and VOC solubilization in a polymer boundary. A series of lab-scale experiments was performed in which the VOC concentration was measured in simulated waste drums under different conditions. A lab-scale simulated waste drum consisted of a sized-down 55-gal metal drum containing a modified rigid polyethylene drum liner. Four polyethylene bags were sealed inside a large polyethylene bag, supported by a wire cage, and placed inside the drum liner. The small bags were filled with VOC-air gas mixture and the VOC concentration was measured throughout the drum over a period of time. Test variables included the type of VOC-air gas mixtures introduced into the small bags, the small bag closure type, and the presence or absence of a variable external heat source. Model results were calculated for those trials where the permeability had been measured

  15. TRU Waste Inventory Collection and Work-Off Plans for the Centralization of TRU Waste Characterization/Certification at INL - On Your Mark - Get Set

    International Nuclear Information System (INIS)

    McTaggart, J.; Lott, S.

    2009-01-01

    The U.S. Department of Energy (DOE) amended the Record of Decision (ROD) for the Waste Management Program: Treatment and Storage of Transuranic Waste to centralize transuranic (TRU) waste characterization/certification from fourteen TRU waste sites. This centralization will allow for treatment, characterization and certification of TRU waste from the fourteen sites, thirteen of which are sites with small quantities of TRU waste, at the Idaho National Laboratory (INL) prior to shipping the waste to the Waste Isolation Pilot Plant (WIPP) for disposal. Centralization of this TRU waste will avoid the cost of building treatment, characterization, certification, and shipping capabilities at each of the small quantity sites that currently do not have existing facilities. Advanced Mixed Waste Treatment Project (AMWTP) and Idaho Nuclear Technology and Engineering Center (INTEC) will provide centralized shipping facilities, to WIPP, for all of the small quantity sites. Hanford, the one large quantity site identified in the ROD, has a large number of waste in containers that are over-packed into larger containers which are inefficient for shipment to and disposal at WIPP. The AMWTP at the INL will reduce the volume of much of the CH waste and make it much more efficient to ship and dispose of at WIPP. In addition, the INTEC has a certified remote handled (RH) TRU waste characterization/certification program at INL to disposition TRU waste from the sites identified in the ROD. (authors)

  16. IMPLEMENTING HEAT SEALED BAG RELIEF and HYDROGEN and METANE TESTING TO REDUCE THE NEED TO REPACK HANFORD TRANSURANIC (TRU) WASTE

    International Nuclear Information System (INIS)

    MCDONALD, K.M.

    2005-01-01

    The Department of Energy's site at Hanford has a significant quantity of drums containing heat-sealed bags that required repackaging under previous revisions of the TRUPACT-II Authorized Methods for Payload Control (TRAMPAC) before being shipped to the Waste Isolation Pilot Plant (WIPP). Since glovebox repackaging is the most rate-limiting and resource-intensive step for accelerating Hanford waste certification, a cooperative effort between Hanford's TRU Program and the WIPP site significantly reduced the number of drums requiring repackaging. More specifically, recent changes to the TRAMPAC (Revision 19C), allow relief for heat-sealed bags having more than 390 square inches of surface area. This relief is based on data provided by Hanford on typical Hanford heat-sealed bags, but can be applied to other sites generating transuranic waste that have waste packaged in heat-sealed bags. The paper provides data on the number of drums affected, the attendant cost savings, and the time saved. Hanford also has a significant quantity of high-gram drums with multiple layers of confinement including heat-scaled bags. These higher-gram drums are unlikely to meet the decay-heat limits required for analytical category certification under the TRAMPAC. The combination of high-gram drums and accelerated reprocessing/shipping make it even more difficult to meet the decay-heat limits because of necessary aging requirements associated with matrix depletion. Hydrogen/methane sampling of headspace gases can be used to certify waste that does not meet decay-heat limits of the more restrictive analytical category using the test category. The number of drums that can be qualified using the test category is maximized by assuring that the detection limit for hydrogen and methane is as low as possible. Sites desiring to ship higher-gram drums must understand the advantages of using hydrogen/methane sampling and shipping under the test category. Headspace gas sampling, as specified by the WIPP

  17. Remote radioactive waste drum inspection with an autonomous mobile robot

    International Nuclear Information System (INIS)

    Heckendorn, F.M.; Ward, C.R.; Wagner, D.G.

    1992-01-01

    An autonomous mobile robot is being developed to perform remote surveillance and inspection task on large numbers of stored radioactive waste drums. The robot will be self guided through narrow storage aisles and record the visual image of each viewable drum for subsequent off line analysis and archiving. The system will remove the personnel from potential exposure to radiation, perform the require inspections, and improve the ability to assess the long term trends in drum conditions

  18. TRU waste inventory collection and work-off plans for the centralization of TRU waste characterization at INL - on your mark - get set - 9410

    International Nuclear Information System (INIS)

    Mctaggert, Jerri Lynne; Lott, Sheila; Gadbury, Casey

    2009-01-01

    The U.S. Department of Energy (DOE) amended the Record of Decision (ROD) for the Waste Management Program: Treatment and Storage ofTransuranic Waste to centralize transuranic (TRU) waste characterization/certification from fourteen TRU waste sites. This centralization will allow for treatment, characterization and certification ofTRU waste from the fourteen sites, thirteen of which are sites with small quantities ofTRU waste, at the Idaho National Laboratory (INL) prior to shipping the waste to the Waste Isolation Pilot Plant (WIPP) for disposal. Centralization ofthis TRU waste will avoid the cost ofbuilding treatment, characterization, certification, and shipping capabilities at each ofthe small quantity sites that currently do not have existing facilities. Advanced Mixed Waste Treatment Project (AMWTP) and Idaho Nuclear Technology and Engineering Center (INTEC) will provide centralized shipping facilities, to WIPP, for all ofthe small quantity sites. Hanford, the one large quantity site identified in the ROD, has a large number ofwaste in containers that are overpacked into larger containers which are inefficient for shipment to and disposal at WIPP. The AMWTP at the INL will reduce the volume ofmuch of the CH waste and make it much more efficient to ship and dispose of at WIPP. In addition, the INTEC has a certified remote handled (RH) TRU waste characterization/certification program at INL to disposition TRU waste from the sites identified in the ROD.

  19. Unvented Drum Handling Plan

    International Nuclear Information System (INIS)

    MCDONALD, K.M.

    2000-01-01

    This drum-handling plan proposes a method to deal with unvented transuranic drums encountered during retrieval of drums. Finding unvented drums during retrieval activities was expected, as identified in the Transuranic (TRU) Phase I Retrieval Plan (HNF-4781). However, significant numbers of unvented drums were not expected until excavation of buried drums began. This plan represents accelerated planning for management of unvented drums. A plan is proposed that manages unvented drums differently based on three categories. The first category of drums is any that visually appear to be pressurized. These will be vented immediately, using either the Hanford Fire Department Hazardous Materials (Haz. Mat.) team, if such are encountered before the facilities' capabilities are established, or using internal capabilities, once established. To date, no drums have been retrieved that showed signs of pressurization. The second category consists of drums that contain a minimal amount of Pu isotopes. This minimal amount is typically less than 1 gram of Pu, but may be waste-stream dependent. Drums in this category are assayed to determine if they are low-level waste (LLW). LLW drums are typically disposed of without venting. Any unvented drums that assay as TRU will be staged for a future venting campaign, using appropriate safety precautions in their handling. The third category of drums is those for which records show larger amounts of Pu isotopes (typically greater than or equal to 1 gram of Pu). These are assumed to be TRU and are not assayed at this point, but are staged for a future venting campaign. Any of these drums that do not have a visible venting device will be staged awaiting venting, and will be managed under appropriate controls, including covering the drums to protect from direct solar exposure, minimizing of container movement, and placement of a barrier to restrict vehicle access. There are a number of equipment options available to perform the venting. The

  20. Savannah River Site TRU Drum Waste Criticality Safety Margin Improvements

    International Nuclear Information System (INIS)

    Blanchard, A.; Hammer, K.

    1998-01-01

    The text of the paper will include an overview of the methodology used to determine the credible scenarios, summary of the analysis of the results, challenges overcome during compliance and implementation, and cost savings due to reduced operational expanses

  1. Characterization of radioactive-waste drum contents using real-time x-radiography

    International Nuclear Information System (INIS)

    Barna, B.A.; Bishoff, J.R.; Reinhardt, W.W.

    1982-01-01

    Low-level transuranic (TRU) waste is stored in a retrievable manner at the Radioactive Waste Management Complex (RWMC) operated by EG and G Idaho, Inc., for the Department of Energy. The waste, consisting of contaminated rags, paper, plastic, laboratory glassware, tools, scrap metal, wood, electrical components and parts, sludges, etc., is packed in various sized sealed containers, including 55 gallon drums. Waste which can be accurately characterized will be sent to the Waste Isolation Pilot Plant (WIPP) in New Mexico for long term storage if it is certified to meet the WIPP waste acceptance criteria. EG and G Idaho, Inc. is planning to install a real-time x-ray system designed for the automated and semi-automated examination of low-level TRU waste containers including 30, 55, and 83 gallon drums, 4 x 4 x 7 foot plywood boxes, and 4 x 5 x 6 foot metal bins during 1982. This system, designed for production, is capable of examining up to 20,000 waste containers per year using automated container handling, and features real-time x-ray imaging with a 420 kV, 10 ma constant potential source, digital image processing equipment, and video taping facilities (every container examination is required to be taped, for archival documentation). Work planned for the near future involves tests using real-time neutron radiography for waste characterization as a complement to real-time x-ray radiography. Ultimately, the NDE examinations will be combined with automated nondestructive assay (NDA) techniques for complete characterization of a given waste container's contents

  2. Observed TRU data from nuclear utility waste streams

    International Nuclear Information System (INIS)

    Wessman, R.A.; Floyd, J.G.; Leventhal, L.

    1990-01-01

    TMA/Norcal has performed 10CFR61 analysis of radioactive waste streams from BWR's and PWR's since 1983. Many standard and non-routine sample types have been received for analysis from nuclear power plants nation-wide. In addition to the 10CFR61 Tables I and II analyses, we also have analyzed for many of the supplementary isotopes. As part of this program TRU analyses are required. As a result, have accumulated a significant amount of data for plutonium, americium, and curium in radioactive waste for many different sample matrices from many different waste streams. This paper will present our analytical program for 10CFR61 TRU. The laboratory methodology including chemical and radiometric procedures is discussed. The sensitivity of our measurements and ability to meet the lower limits of detection is also discussed. Secondly, a review of TRU data is presented. Scaling factors and their ranges from selected PWR stations are included. We discuss some features of, and limits to, interpretation of these data. 8 refs., 3 tabs

  3. Gas generation and migration analysis for TRU waste disposal system

    International Nuclear Information System (INIS)

    Ando, Kenichi; Noda, Masaru; Yamamoto, Mikihiko; Mihara, Morihiro

    2005-09-01

    In TRU waste disposal system, significant quantities of gases may be generated due to metal corrosion, radiolysis effect and microorganism activities. It is therefore recommended that the potential impact of gas generation and migration on TRU waste repository should be evaluated. In this study, gas generation rates were calculated in the repository and gas migration analysis in the disposal system were carried out using two phase flow model with results of gas generation rates. First, the time dependencies of gas generation rate in each TRU waste repositories were evaluated based on amounts of metal, organic matter and radioactivity. Next, the accumulation pressure of gases and expelled pore water volume nuclides in the repository were calculated by TOUGH2 code. After that, the results showed that the increase of gas pressure was the range of 1.3 to 1.4 MPa. In the repository with and without buffer, the rate of expelled pore water was 0.006 - 0.009 m 3 /y and 0.018 - 0.24m 3 /y, respectively. In addition, the radioactive gas migration through the repository and geosphere are evaluated. And re-saturation analysis is also performed to evaluate the initial condition of the system. (author)

  4. Design and operation of a passive neutron monitor for assaying the TRU content of solid wastes

    International Nuclear Information System (INIS)

    Brodzinski, R.L.; Brown, D.P.; Rieck, H.G. Jr.; Rogers, L.A.

    1984-02-01

    A passive neutron monitor has been designed and built for determining the residual transuranic (TRU) and plutonium content of chopped leached fuel hulls and other solid wastes from spent Fast Flux Test Facility (FFTF) fuel. The system was designed to measure as little as 8 g of plutonium or 88 mg of TRU in a waste package as large as a 208-l drum which could be emitting up to 220,000 R/hr of gamma radiation. For practical purposes, maximum assay times were chosen to be 10,000 sec. The monitor consists of 96 10 BF 3 neutron sensitive proportional counting tubes each 5.08 cm in diameter and 183 cm in active length. Tables of neutron emission rates from both spontaneous fission and (α,n) reactions on oxygen are given for all contributing isotopes expected to be present in spent FFTF fuel. Tables of neutron yeilds from isotopic compositions predicted for various exposures and cooling times are also given. Methods of data reduction and sources, magnitude, and control of errors are discussed. Backgrounds and efficiencies have been measured and are reported. A section describing step-by-step operational procedures is included. Guidelines and procedures for quality control and troubleshooting are also given. 13 references, 15 figures, 4 tables

  5. Performance Demonstration Program Plan for Nondestructive Assay for the TRU Waste Characterization Program. Revision 1

    International Nuclear Information System (INIS)

    1997-01-01

    The Performance Demonstration Program (PDP) for Nondestructive Assay (NDA) consists of a series of tests conducted on a regular frequency to evaluate the capability for nondestructive assay of transuranic (TRU) waste throughout the Department of Energy (DOE) complex. Each test is termed a PDP cycle. These evaluation cycles provide an objective measure of the reliability of measurements performed with TRU waste characterization systems. Measurement facility performance will be demonstrated by the successful analysis of blind audit samples according to the criteria set by this Program Plan. Intercomparison between measurement groups of the DOE complex will be achieved by comparing the results of measurements on similar or identical blind samples reported by the different measurement facilities. Blind audit samples (hereinafter referred to as PDP samples) will be used as an independent means to assess the performance of measurement groups regarding compliance with established Quality Assurance Objectives (QAOs). As defined for this program, a PDP sample consists of a 55-gallon matrix drum emplaced with radioactive standards and fabricated matrix inserts. These PDP sample components, once manufactured, will be secured and stored at each participating measurement facility designated and authorized by Carlsbad Area Office (CAO) under secure conditions to protect them from loss, tampering, or accidental damage

  6. Direct measurement of γ-emitting radionuclides in waste drum

    International Nuclear Information System (INIS)

    Ma Ruwei; Mao Yong; Zhang Xiuzhen; Xia Xiaobin; Guo Caiping; Han Yueqin

    1993-01-01

    The low-level rad waste produced from nuclear power plant, nuclear facilities, and in the process of their decommissioning is stored in waste depository. For the safety of transport and storage of these wastes, some test must be done. One of them is to analyse the kinds and activities of radionuclides in each waste drum. Segmented scanning gamma spectrum analysis can be used for direct measurement of gamma-emitting radionuclides in drum. Gamma emitters such as Co-60, Cs-137, Ra-226 can be measured directly from outside of drum. A method and system for direct measuring gamma emitters in waste drum are described, and measuring apparatus and measurement results as well

  7. Potential problems from shipment of high-curie content contact-handled transuranic (CH-TRU) waste to WIPP

    International Nuclear Information System (INIS)

    Neill, R.H.; Channell, J.K.

    1983-08-01

    There are about 1000 drums of contact-handled transuranic (CH-TRU) wastes containing more than 100 Ci/drum of Pu-238 that are stored at the Savannah River Plant and at the Los Alamos National Laboratory. Studies performed at DOE laboratories have shown that large quantities of gases are generated in stored drums containing 100 Ci of 238 Pu. Concentrations of hydrogen gas in the void space of the drums are often found to be high enough to be explosive. None of the analyses in the DOE WIPP Final Environmental Impact Statement, Safety Analysis Report, and Preliminary Transportation Analysis have considered the possibility that the generation of hydrogen gas by radiolysis may create an explosive or flammable hazard that could increase the frequency and severity of accidental releases of radionuclides during transportation or handling. These high 238 Pu concentration containers would also increase the estimated doses received by individuals and populations from transportation, WIPP site operations, and human intrusion scenarios even if the possibility of gas-enhanced releases is ignored. The WIPP Project Office has evaluated this effect on WIPP site operations and is suggesting a maximum limit of 140 239 Pu equivalent curies (P-Ci) per drum so that postulated accidental off-site doses will not be larger than those listed in the FEIS. The TRUPACT container, which is being designed for the transportation of CH-TRU wastes to WIPP, does not appear to meet the Nuclear Regulatory Commission regulations requiring double containment for the transportation of plutonium in quantities >20 Ci. A 20 alpha Ci/shipment limit would require about 200,000 shipments for the 4 million curies of alpha emitters slated for WIPP

  8. TRU Waste Management Program. Cost/schedule optimization analysis

    International Nuclear Information System (INIS)

    Detamore, J.A.; Raudenbush, M.H.; Wolaver, R.W.; Hastings, G.A.

    1985-10-01

    This Current Year Work Plan presents in detail a description of the activities to be performed by the Joint Integration Office Rockwell International (JIO/RI) during FY86. It breaks down the activities into two major work areas: Program Management and Program Analysis. Program Management is performed by the JIO/RI by providing technical planning and guidance for the development of advanced TRU waste management capabilities. This includes equipment/facility design, engineering, construction, and operations. These functions are integrated to allow transition from interim storage to final disposition. JIO/RI tasks include program requirements identification, long-range technical planning, budget development, program planning document preparation, task guidance development, task monitoring, task progress information gathering and reporting to DOE, interfacing with other agencies and DOE lead programs, integrating public involvement with program efforts, and preparation of reports for DOE detailing program status. Program Analysis is performed by the JIO/RI to support identification and assessment of alternatives, and development of long-term TRU waste program capabilities. These analyses include short-term analyses in response to DOE information requests, along with performing an RH Cost/Schedule Optimization report. Systems models will be developed, updated, and upgraded as needed to enhance JIO/RI's capability to evaluate the adequacy of program efforts in various fields. A TRU program data base will be maintained and updated to provide DOE with timely responses to inventory related questions

  9. Research on safety evaluation for TRU waste disposal

    International Nuclear Information System (INIS)

    Senoo, M.; Shirahashi, K.; Sakamoto, Y.; Moriyama, N.; Konishi, M.

    1989-01-01

    Studies on adsorption behavior of transuranic (TRU) elements have been performed from the view point of validating the data for safety assessment and investigating adsorption behavior of TRU elements. Distribution coefficient (Kd value) of plutonium between groundwater and soils sampled at the planning site of low level waste disposal facility were measured for safety assessment. Kd values measured were the order of 10 3 ml/g. For investigating adsorption behavior, pH dependency of Kd value of neptunium and Am for soils were studied. It was concluded that pH dependency of Kd value of neptunium was mainly owing to amount of surface charge of soils, on the other hand that of Am was due to chemical form of Am. Influence of carbonation of cement for adsorption behavior of neptunium and plutonium was also investigated and it was concluded that Kd value of carbonated cement was lower than that of fresh cement

  10. Expected precision of neutron multiplicity measurements of waste drums

    International Nuclear Information System (INIS)

    Ensslin, N.; Krick, M.S.; Menlove, H.O.

    1995-01-01

    DOE facilities are beginning to apply passive neutron multiplicity counting techniques to the assay of plutonium scrap and residues. There is also considerable interest in applying this new measurement technique to 208-liter waste drums. The additional information available from multiplicity counting could flag the presence of shielding materials or improve assay accuracy by correcting for matrix effects such as (α,n) induced fission or detector efficiency variations. The potential for multiplicity analysis of waste drums, and the importance of better detector design, can be estimated by calculating the expected assay precision using a Figure of Merit code for assay variance. This paper reports results obtained as a function of waste drum content and detector characteristics. We find that multiplicity analysis of waste drums is feasible if a high-efficiency neutron counter is used. However, results are significantly poorer if the multiplicity analysis must be used to solve for detection efficiency

  11. Radiolytic decomposition of organic C-14 released from TRU waste

    International Nuclear Information System (INIS)

    Kani, Yuko; Noshita, Kenji; Kawasaki, Toru; Nishimura, Tsutomu; Sakuragi, Tomofumi; Asano, Hidekazu

    2007-01-01

    It has been found that metallic TRU waste releases considerable portions of C-14 in the form of organic molecules such as lower molecular weight organic acids, alcohols and aldehydes. Due to the low sorption ability of organic C-14, it is important to clarify the long-term behavior of organic forms under waste disposal conditions. From investigations on radiolytic decomposition of organic carbon molecules into inorganic carbonic acid, it is expected that radiation from TRU waste will decompose organic C-14 into inorganic carbonic acid that has higher adsorption ability into the engineering barriers. Hence we have studied the decomposition behavior of organic C-14 by gamma irradiation experiments under simulated disposal conditions. The results showed that organic C-14 reacted with OH radicals formed by radiolysis of water, to produce inorganic carbonic acid. We introduced the concept of 'decomposition efficiency' which expresses the percentage of OH radicals consumed for the decomposition reaction of organic molecules in order to analyze the experimental results. We estimated the effect of radiolytic decomposition on the concentration of organic C-14 in the simulated conditions of the TRU disposal system using the decomposition efficiency, and found that the concentration of organic C-14 in the waste package will be lowered when the decomposition of organic C-14 by radiolysis was taken into account, in comparison with the concentration of organic C-14 without radiolysis. Our prediction suggested that some amount of organic C-14 can be expected to be transformed into the inorganic form in the waste package in an actual system. (authors)

  12. CH-TRU Waste Content Codes (CH-TRUCON)

    International Nuclear Information System (INIS)

    2005-01-01

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes 'shipping categories' that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the 'General Case,' which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for 'Close-Proximity Shipments' (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for 'Controlled Shipments

  13. CH-TRU Waste Content Codes (CH-TRUCON)

    International Nuclear Information System (INIS)

    2007-01-01

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes 'shipping categories' that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the 'General Case,' which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for 'Close-Proximity Shipments' (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for 'Controlled Shipments

  14. CH-TRU Waste Content Codes (CH-TRUCON)

    International Nuclear Information System (INIS)

    2006-01-01

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes 'shipping categories' that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the 'General Case,' which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for 'Close-Proximity Shipments' (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for 'Controlled Shipments

  15. CH-TRU Waste Content Codes (CH-TRUCON)

    International Nuclear Information System (INIS)

    2008-01-01

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes 'shipping categories' that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the 'General Case,' which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for 'Close-Proximity Shipments' (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for 'Controlled Shipments

  16. CH-TRU Waste Content Codes (CH-TRUCON)

    International Nuclear Information System (INIS)

    2004-01-01

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes 'shipping categories' that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the 'General Case,' which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for 'Close-Proximity Shipments' (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for 'Controlled Shipments

  17. CH-TRU Waste Content Codes (CH-TRUCON)

    Energy Technology Data Exchange (ETDEWEB)

    Washington TRU Solutions LLC

    2006-09-15

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments

  18. CH-TRU Waste Content Codes (CH-TRUCON)

    Energy Technology Data Exchange (ETDEWEB)

    Washington TRU Solutions LLC

    2005-05-01

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments

  19. CH-TRU Waste Content Codes (CH-TRUCON)

    Energy Technology Data Exchange (ETDEWEB)

    Washington TRU Solutions LLC

    2007-02-15

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments

  20. CH-TRU Waste Content Codes (CH-TRUCON)

    Energy Technology Data Exchange (ETDEWEB)

    Washington TRU Solutions LLC

    2005-06-20

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments

  1. CH-TRU Waste Content Codes (CH-TRUCON)

    Energy Technology Data Exchange (ETDEWEB)

    Washington TRU Solutions LLC

    2006-06-20

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments

  2. CH-TRU Waste Content Codes (CH-TRUCON)

    Energy Technology Data Exchange (ETDEWEB)

    Washington TRU Solutions LLC

    2005-01-15

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codesand corresponding shipping categories for "Controlled Shipments

  3. CH-TRU Waste Content Codes (CH-TRUCON)

    Energy Technology Data Exchange (ETDEWEB)

    Washington TRU Solutions LLC

    2006-12-20

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments

  4. CH-TRU Waste Content Codes (CH-TRUCON)

    Energy Technology Data Exchange (ETDEWEB)

    Washington TRU Solutions LLC

    2006-08-15

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments

  5. CH-TRU Waste Content Codes (CH-TRUCON)

    Energy Technology Data Exchange (ETDEWEB)

    Washington TRU Solutions LLC

    2006-01-18

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments

  6. CH-TRU Waste Content Codes (CH-TRUCON)

    Energy Technology Data Exchange (ETDEWEB)

    Washington TRU Solutions LLC

    2004-10-01

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments

  7. CH-TRU Waste Content Codes (CH-TRUCON)

    Energy Technology Data Exchange (ETDEWEB)

    Washington TRU Solutions LLC

    2005-03-15

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments

  8. CH-TRU Waste Content Codes (CH-TRUCON)

    Energy Technology Data Exchange (ETDEWEB)

    Washington TRU Solutions LLC

    2007-09-20

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments

  9. CH-TRU Waste Content Codes (CH-TRUCON)

    Energy Technology Data Exchange (ETDEWEB)

    Washington TRU Solutions LLC

    2007-08-15

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments

  10. CH-TRU Waste Content Codes (CH TRUCON)

    Energy Technology Data Exchange (ETDEWEB)

    Washington TRU Solutions LLC

    2004-12-01

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments

  11. CH-TRU Waste Content Codes (CH-TRUCON)

    Energy Technology Data Exchange (ETDEWEB)

    Washington TRU Solutions LLC

    2005-11-20

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments

  12. CH-TRU Waste Content Codes (CH-TRUCON)

    Energy Technology Data Exchange (ETDEWEB)

    Washington TRU Solutions LLC

    2005-12-15

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments

  13. CH-TRU Waste Content Codes (CH-TRUCON)

    Energy Technology Data Exchange (ETDEWEB)

    Washington TRU Solutions LLC

    2005-01-30

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments

  14. CH-TRU Waste Content Codes (CH-TRUCON)

    Energy Technology Data Exchange (ETDEWEB)

    Washington TRU Solutions LLC

    2005-08-15

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments

  15. CH-TRU Waste Content Codes (CH-TRUCON)

    Energy Technology Data Exchange (ETDEWEB)

    Washington TRU Solutions LLC

    2007-06-15

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments

  16. Evaluation of overturning capacity of low level radioactive waste drum during earthquake. Part 2. Investigation of drum weight distribution effect and drum columns interaction by numerical analysis

    International Nuclear Information System (INIS)

    Tochigi, Hitoshi

    2011-01-01

    Numerical analysis case study is carried out for three layered and four layered low level radioactive waste drums by numerical models based on the results of shaking table test. First of all, numerical analysis results about drums displacement due to uplift and sliding on pallets during earthquake are compared with the experimental results and it is shown good agreement in both results. By this analytical model effects of drum weight distribution along height direction and drum columns interaction followed by each other drum's collisions on overturning capacity during earthquake are researched. From numerical analysis results the limit acceleration which is minimum value of input acceleration at storage building floor when three layered or four layered waste drums overturn is researched. It is shown that overturning capacity during earthquake decline when height of gravity center of three layered and four layered drums get large. So it is available to get down height of gravity center by controlling drum weight distribution along height direction. And as effect of drum columns interaction it is indicated that overturning capacity of single column arrangement drums is larger than that of many columns arrangement drums because phase deference between drum columns occur and decrease vibration amplitude by each other collisions. (author)

  17. Cookoff Modeling of a WIPP waste drum (68660)

    Energy Technology Data Exchange (ETDEWEB)

    Hobbs, Michael L. [Sandia National Laboratories, Albuquerque, NM (United States)

    2014-11-24

    A waste drum located 2150 feet underground may have been the root cause of a radiation leak on February 14, 2014. Information provided to the WIPP Technical Assessment Team (TAT) was used to describe the approximate content of the drum, which included an organic cat litter (Swheat Scoop®, or Swheat) composed of 100% wheat products. The drum also contained various nitrate salts, oxalic acid, and a nitric acid solution that was neutralized with triethanolamine (TEA). CTH-TIGER was used with the approximate drum contents to specify the products for an exothermic reaction for the drum. If an inorganic adsorbent such as zeolite had been used in lieu of the kitty litter, the overall reaction would have been endothermic. Dilution with a zeolite adsorbent might be a useful method to remediate drums containing organic kitty litter. SIERRA THERMAL was used to calculate the pressurization and ignition of the drum. A baseline simulation of drum 68660 was performed by assuming a background heat source of 0.5-10 W of unknown origin. The 0.5 W source could be representative of heat generated by radioactive decay. The drum ignited after about 70 days. Gas generation at ignition was predicted to be 300-500 psig with a sealed drum (no vent). At ignition, the wall temperature increases modestly by about 1°C, demonstrating that heating would not be apparent prior to ignition. The ignition location was predicted to be about 0.43 meters above the bottom center portion of the drum. At ignition only 3-5 kg (out of 71.6 kg total) has been converted into gas, indicating that most of the material remained available for post-ignition reaction.

  18. Transuranic (TRU) waste management at Savannah River - past, present and future

    International Nuclear Information System (INIS)

    D'Ambrosia, J.T.

    1985-01-01

    Defense TRU waste at Savannah River (SR) results from the Department of Energy's (DOE) national defense activities, including the operation of production reactors and fuel reprocessing plants and research and development activities. TRU waste is material declared as having negligible economic value, contaminated with alpha-emitting radionuclides of atomic number greater than 92, and half-lives longer than 20 years, in concentrations greater than 100 nCi/g. TRU waste has been retrievably stored at SR since 1974 awaiting disposal. The Waste Isolation Pilot Plant (WIPP), now under construction in New Mexico, is a research and development facility for demonstrating the safe disposal of defense TRU waste, including that in storage at SR. The major objective of the TRU program at SR is to support the TRU National Program, which is dedicated to preparing waste for, and emplacing waste in, the WIPP. Thus, the SR Program also supports WIPP operations. The SR Site specific goals are to phase out the indefinite storage of TRU waste, which has been the mode of waste management since 1974, and to dispose of SR's Defense TRU waste

  19. Analysis of TRU waste for RCRA-listed elements

    International Nuclear Information System (INIS)

    Mahan, C.; Gerth, D.; Yoshida, T.

    1996-01-01

    Analytical methods for RCRA listed elements on Portland cement type waste have been employed using both microwave and open hot plate digestions with subsequent analysis by inductively coupled plasma atomic emission spectroscopy (ICP-AES), inductively coupled plasma mass spectrometry (ICP-AES), inductively coupled plasma mass spectrometry (ICP-MS), graphite furnace atomic absorption (GFAA) and cold vapor atomic absorption and fluorescence (CVAA/CVAFS). Four different digestion procedures were evaluated including an open hot plate nitric acid digestion, EPA SW-846 Method 3051, and 2 methods using modifications to Method 3051. The open hot plate and the modified Method 3051, which used aqua regia for dissolution, were the only methods which resulted in acceptable data quality for all 14 RCRA-listed elements. Results for the nitric acid open hot plate digestion were used to qualify the analytical methods for TRU waste characterization, and resulted in a 99% passing score. Direct chemical analysis of TRU waste is being developed at Los Alamos National Laboratory in an attempt to circumvent the problems associated with strong acid digestion methods. Technology development includes laser induced breakdown spectroscopy (LIBS), laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS), dc arc CID atomic emission spectroscopy (DC-AES), and glow discharge mass spectrometry (GDMS). Analytical methods using the Portland cement matrix are currently being developed for each of the listed techniques. Upon completion of the development stage, blind samples will be distributed to each of the technology developers for RCRA metals characterization

  20. Waste Isolation Pilot Plant RH TRU waste preoperational checkout: Final report

    International Nuclear Information System (INIS)

    1988-06-01

    This report documents the results of the Waste Isolation Pilot Plant (WIPP) Remote-Handled Transuranic (RH TRU) Waste Preoperational Checkout. The primary objective of this checkout was to demonstrate the process of handling RH TRU waste packages, from receipt through emplacement underground, using equipment, personnel, procedures, and methods to be used with actual waste packages. A further objective was to measure operational time lines to provide bases for confirming the WIPP design through put capability and for projecting operator radiation doses. Successful completion of this checkout is a prerequisite to the receipt of actual RH TRU waste. This checkout was witnessed in part by members of the Environmental Evaluation Group (EEG) of the state of New Mexico. Further, this report satisfies a key milestone contained in the Agreement for Consultation and Cooperation with the state of New Mexico. 4 refs., 26 figs., 4 tabs

  1. Automation of a measurement systems of waste drum alpha activity

    International Nuclear Information System (INIS)

    Labarre, S.; Bardy, N.

    1985-10-01

    The alpha radiator activity in the two-hundred liter waste drums is found by an IN96, computerized analyzer of the society Intertechnique, from data delivered by a gamma detector (GeHP) and by neutron detection blocks (He counter). This computerized analyzer manages not only the drum rotation and position in front of the detector, but also the experimental data monitoring and their processing from specific programs (background noise, calibration, drum measurements). Thanks to this automation, the measurement number and their reliability are optimized [fr

  2. The method study for nuclide analysis of waste drum

    International Nuclear Information System (INIS)

    Ruan Guanglin; Huang Xianguo; Xing Shixiong

    2001-01-01

    The principle of waste drum nuclide analysis system and the principle of the detector chosen are introduced. The linear attenuation coefficient and mass attenuation coefficient of five environmental medium (water, soil, red brick, concrete and sands) have been measured with γ transmission method simulative equipment. The absorption coefficient and nuclide activity of three measuring conditions (collimation-columnar source, un-collimation-columnar source, and un-collimation-rotation-drum source) have been calculated

  3. A study for the safety evaluation of geological disposal of TRU waste and influence on disposal site design by change of amount of TRU waste (Joint research)

    International Nuclear Information System (INIS)

    Hasegawa, Makoto; Kondo, Hitoshi; Takahashi, Kuniaki; Funabashi, Hideaki; Kawatsuma, Shinji; Kamei, Gento; Hirano, Fumio; Mihara, Morihiro; Ueda, Hiroyoshi; Ohi, Takao; Hyodo, Hideaki

    2011-02-01

    In the safety evaluation of the geological disposal of the TRU waste, it is extremely important to share the information with the Research and development organization (JAEA: that is also the waste generator) by the waste disposal entrepreneur (NUMO). In 2009, NUMO and JAEA set up a technical commission to investigate the reasonable TRU waste disposal following a cooperation agreement between these two organizations. In this report, the calculation result of radionuclide transport for a TRU waste geological disposal system was described, by using the Tiger code and the GoldSim code at identical terms. Tiger code is developed to calculate a more realistic performance assessment by JAEA. On the other hand, GoldSim code is the general simulation software that is used for the computation modeling of NUMO TRU disposal site. Comparing the calculation result, a big difference was not seen. Therefore, the reliability of both codes was able to be confirmed. Moreover, the influence on the disposal site design (Capacity: 19,000m 3 ) was examined when 10% of the amount of TRU waste increased. As a result, it was confirmed that the influence of the site design was very little based on the concept of the Second Progress Report on Research and Development for TRU Waste Disposal in Japan. (author)

  4. TRU-waste decontamination and size reduction review, June 1983, US DOE/PNC technology exchange

    International Nuclear Information System (INIS)

    Becker, G.W. Jr.

    1983-01-01

    A review of transuranic (TRU) noncombustible waste decontamination and size reduction technology is presented. Electropolishing, vibratory cleaning, and spray decontamination processes developed at Battelle Pacific Northwest Laboratory (PNL) and Savannah River Laboratory (SRL) are highlighted. TRU waste size reduction processes at (PNL), Los Alamos National Laboratory (LANL), the Rocky Flats Plant (RFP), and SRL are also highlighted

  5. Simultaneous Thermal Analysis of WIPP and LANL Waste Drum Samples: A Preliminary Report

    Energy Technology Data Exchange (ETDEWEB)

    Wayne, David M. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2015-10-19

    On Friday, February 14, 2014, an incident in P7R7 of the WIPP underground repository released radioactive material into the environment. The direct cause of the event was a breached transuranic (TRU) waste container, subsequently identified as Drum 68660. Photographic and other evidence indicates that the breach of 68660 was caused by an exothermic event. Subsequent investigations (Britt, 2015; Clark and Funk, 2015; Wilson et al., 2015; Clark, 2015) indicate that the combination of nitrate salts, pH neutralizing chemicals, and organic-based adsorbent represented a potentially energetic mixture. The materials inside the breached steel drum consisted of remediated, 30- to 40-year old, Pu processing wastes from LANL. The contents were processed and repackaged in 2014. Processing activities at LANL included: 1) neutralization of acidic liquid contents, 2) sorption of the neutralized liquid, and 3) mixing of acidic nitrate salts with an absorber to meet waste acceptance criteria. The contents of 68660 and its sibling, 68685, were derived from the same parent drum, S855793. Drum S855793 originally contained ten plastic bags of acidic nitrate salts, and four bags of mixed nitrate and oxalate salts generated in 1985 by Pu recovery operations. These salts were predominantly oxalic acid, hydrated nitrate salts of Mg, Ca, and Fe, anhydrous Na(NO3), and minor amounts of anhydrous and hydrous nitrate salts of Pb, Al, K, Cr, and Ni. Other major components include sorbed water, nitric acid, dissolved nitrates, an absorbent (Swheat Scoop®) and a neutralizer (KolorSafe®). The contents of 68660 are described in greater detail in Appendix E of Wilson et al. (2015)

  6. Simultaneous Thermal Analysis of WIPP and LANL Waste Drum Samples: A Preliminary Report

    International Nuclear Information System (INIS)

    Wayne, David M.

    2015-01-01

    On Friday, February 14, 2014, an incident in P7R7 of the WIPP underground repository released radioactive material into the environment. The direct cause of the event was a breached transuranic (TRU) waste container, subsequently identified as Drum 68660. Photographic and other evidence indicates that the breach of 68660 was caused by an exothermic event. Subsequent investigations (Britt, 2015; Clark and Funk, 2015; Wilson et al., 2015; Clark, 2015) indicate that the combination of nitrate salts, pH neutralizing chemicals, and organic-based adsorbent represented a potentially energetic mixture. The materials inside the breached steel drum consisted of remediated, 30- to 40-year old, Pu processing wastes from LANL. The contents were processed and repackaged in 2014. Processing activities at LANL included: 1) neutralization of acidic liquid contents, 2) sorption of the neutralized liquid, and 3) mixing of acidic nitrate salts with an absorber to meet waste acceptance criteria. The contents of 68660 and its sibling, 68685, were derived from the same parent drum, S855793. Drum S855793 originally contained ten plastic bags of acidic nitrate salts, and four bags of mixed nitrate and oxalate salts generated in 1985 by Pu recovery operations. These salts were predominantly oxalic acid, hydrated nitrate salts of Mg, Ca, and Fe, anhydrous Na(NO 3 ), and minor amounts of anhydrous and hydrous nitrate salts of Pb, Al, K, Cr, and Ni. Other major components include sorbed water, nitric acid, dissolved nitrates, an absorbent (Swheat Scoop®) and a neutralizer (KolorSafe®). The contents of 68660 are described in greater detail in Appendix E of Wilson et al. (2015)

  7. TRU waste processing comparison: slagging pyrolysis versus modified glassmaker

    International Nuclear Information System (INIS)

    Bonner, W.F.; Cox, N.D.; Hootman, H.E.; Nelson, D.C.; Pye, D.

    1980-03-01

    A task force was assembled to make a technical comparison of the expected performance of two processing systems potentially applicable for treating TRU waste at the Idaho National Engineering Laboratory. One system contained a slagging pyrolysis incinerator; the other a modified Penberthy Electromelt glassmaker. Although the glassmaker technology is essentially undeveloped, it was assumed that the glassmaker could eventually be modified to operate as a combined waste incinerator and melter; that is, to perform the same functions as a slagger. Using a decision analysis methodology to evaluate figures-of-merit, the task force found no significant difference in the performance of the two systems. Some areas for future R and D efforts are recommended for both types of incinerators

  8. Remote Handled TRU Waste Status and Activities and Challenges at the Hanford Site

    International Nuclear Information System (INIS)

    MCKENNEY, D.E.

    2000-01-01

    A significant portion of the Department of Energy's forecast volume of remote-handled (RH) transuranic (TRU) waste will originate from the Hanford Site. The forecasted Hanford RH-TRU waste volume of over 2000 cubic meters may constitute over one-third of the forecast inventory of RH-TRU destined for disposal at the Waste Isolation Pilot Plant (WIPP). To date, the Hanford TRU waste program has focused on the retrieval, treatment and certification of the contact-handled transuranic (CH-TRU) wastes. This near-term focus on CH-TRU is consistent with the National TRU Program plans and capabilities. The first shipment of CH-TRU waste from Hanford to the WIPP is scheduled early in Calendar Year 2000. Shipments of RH-TRU from Hanford to the WIPP are scheduled to begin in Fiscal Year 2006 per the National TRU Waste Management Plan. This schedule has been incorporated into milestones within the Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement). These Tri-Party milestones (designated the ''M-91'' series of milestones) relate to development of project management plans, completion of design efforts, construction and contracting schedules, and initiation of process operations. The milestone allows for modification of an existing facility, construction of a new facility, and/or commercial contracting to provide the capabilities for processing and certification of RH-TRU wastes for disposal at the WIPP. The development of a Project Management Plan (PMP) for TRU waste is the first significant step in the development of a program for disposal of Hanford's RH-TRU waste. This PMP will address the path forward for disposition of waste streams that cannot be prepared for disposal in the Hanford Waste Receiving and Processing facility (a contact-handled, small container facility) or other Site facilities. The PMP development effort has been initiated, and the PMP will be provided to the regulators for their approval by June 30, 2000. This plan will detail the

  9. Statistical sampling plan for the TRU waste assay facility

    International Nuclear Information System (INIS)

    Beauchamp, J.J.; Wright, T.; Schultz, F.J.; Haff, K.; Monroe, R.J.

    1983-08-01

    Due to limited space, there is a need to dispose appropriately of the Oak Ridge National Laboratory transuranic waste which is presently stored below ground in 55-gal (208-l) drums within weather-resistant structures. Waste containing less than 100 nCi/g transuranics can be removed from the present storage and be buried, while waste containing greater than 100 nCi/g transuranics must continue to be retrievably stored. To make the necessary measurements needed to determine the drums that can be buried, a transuranic Neutron Interrogation Assay System (NIAS) has been developed at Los Alamos National Laboratory and can make the needed measurements much faster than previous techniques which involved γ-ray spectroscopy. The previous techniques are reliable but time consuming. Therefore, a validation study has been planned to determine the ability of the NIAS to make adequate measurements. The validation of the NIAS will be based on a paired comparison of a sample of measurements made by the previous techniques and the NIAS. The purpose of this report is to describe the proposed sampling plan and the statistical analyses needed to validate the NIAS. 5 references, 4 figures, 5 tables

  10. Quality assurance procedures for the analysis of TRU waste samples

    International Nuclear Information System (INIS)

    Glasgow, D.C. Giaquinto, J.M.; Robinson, L.

    1995-01-01

    The Waste Isolation Pilot Plant (WIPP) project was undertaken in response to the growing need for a national repository for transuranic (TRU) waste. Guidelines for WIPP specify that any waste item to be interred must be fully characterized and analyzed to determine the presence of chemical compounds designated hazardous and certain toxic elements. The Transuranic Waste Characterization Program (TWCP) was launched to develop analysis and quality guidelines, certify laboratories, and to oversee the actual waste characterizations at the laboratories. ORNL is participating in the waste characterization phase and brings to bear a variety of analytical techniques including ICP-AES, cold vapor atomic absorption, and instrumental neutron activation analysis (INAA) to collective determine arsenic, cadmium, barium, chromium, mercury, selenium, silver, and other elements. All of the analytical techniques involved participate in a cooperative effort to meet the project objectives. One important component of any good quality assurance program is determining when an alternate method is more suitable for a given analytical problem. By bringing to bear a whole arsenal of analytical techniques working toward common objectives, few analytical problems prove to be insurmountable. INAA and ICP-AES form a powerful pair when functioning in this cooperative manner. This paper will provide details of the quality assurance protocols, typical results from quality control samples for both INAA and ICP-AES, and detail method cooperation schemes used

  11. Waste Isolation Pilot Plant simulated RH TRU waste experiments: Data and interpretation pilot

    International Nuclear Information System (INIS)

    Molecke, M.A.; Argueello, G.J.; Beraun, R.

    1993-04-01

    The simulated, i.e., nonradioactive remote-handled transuranic waste (RH TRU) experiments being conducted underground in the Waste Isolation Pilot Plant (WIPP) were emplaced in mid-1986 and have been in heated test operation since 9/23/86. These experiments involve the in situ, waste package performance testing of eight full-size, reference RH TRU containers emplaced in horizontal, unlined test holes in the rock salt ribs (walls) of WIPP Room T. All of the test containers have internal electrical heaters; four of the test emplacements were filled with bentonite and silica sand backfill materials. We designed test conditions to be ''near-reference'' with respect to anticipated thermal outputs of RH TRU canisters and their geometrical spacing or layout in WIPP repository rooms, with RH TRU waste reference conditions current as of the start date of this test program. We also conducted some thermal overtest evaluations. This paper provides a: detailed test overview; comprehensive data update for the first 5 years of test operations; summary of experiment observations; initial data interpretations; and, several status; experimental objectives -- how these tests support WIPP TRU waste acceptance, performance assessment studies, underground operations, and the overall WIPP mission; and, in situ performance evaluations of RH TRU waste package materials plus design details and options. We provide instrument data and results for in situ waste container and borehole temperatures, pressures exerted on test containers through the backfill materials, and vertical and horizontal borehole-closure measurements and rates. The effects of heat on borehole closure, fracturing, and near-field materials (metals, backfills, rock salt, and intruding brine) interactions were closely monitored and are summarized, as are assorted test observations. Predictive 3-dimensional thermal and structural modeling studies of borehole and room closures and temperature fields were also performed

  12. Preliminary minimum detectable limit measurements in 208-L drums for selected actinide isotopes in mock-waste matrices

    International Nuclear Information System (INIS)

    Camp, D.C.; Wang, Tzu-Fang; Martz, H.E.

    1992-01-01

    Preliminary minimum detectable levels (MDLS) of selected actinide isotopes have been determined in full-scale, 55-gallon drums filled with a range of mock-waste materials from combustibles (0.14 g/CM 3 ) to sand (1.7 g/CM 3 ). Measurements were recorded from 100 to 10,000 seconds with selected actinide sources located in these drums at an edge position, on the center axis of a drum and midway between these two positions. Measurements were also made with a 166 Ho source to evaluate the attenuation of these mock-matrix materials as a function of energy. By knowing where the source activity is located within a drum, our preliminary results show that a simply collimated 90% HPGE detector can differentiate between TRU (>100 nCi/g) and LLW amounts of 239 Pu in only 100s of measurement time and with sufficient accuracy in both low and medium density, low Z materials. Other actinides measured so far include 235 U, 241 Am, and 244 Cm. These measurements begin to establish the probable MDLs achievable in the nondestructive assays of real waste drums when using active and passive CT. How future measurements may differ from these preliminary measurements is also discussed

  13. Transuranic (TRU) Waste Repackaging at the Nevada Test Site

    International Nuclear Information System (INIS)

    Di Sanza, E.F.; Pyles, G.; Ciucci, J.; Arnold, P.

    2009-01-01

    This paper describes the activities required to modify a facility and the process of characterizing, repackaging, and preparing for shipment the Nevada Test Site's (NTS) legacy transuranic (TRU) waste in 58 oversize boxes (OSB). The waste, generated at other U.S. Department of Energy (DOE) sites and shipped to the NTS between 1974 and 1990, requires size-reduction for off-site shipment and disposal. The waste processing approach was tailored to reduce the volume of TRU waste by employing decontamination and non-destructive assay. As a result, the low-level waste (LLW) generated by this process was packaged, with minimal size reduction, in large sea-land containers for disposal at the NTS Area 5 Radioactive Waste Management Complex (RWMC). The remaining TRU waste was repackaged and sent to the Idaho National Laboratory Consolidation Site for additional characterization in preparation for disposal at the Waste Isolation Pilot Plant (WIPP), near Carlsbad, New Mexico. The DOE National Nuclear Security Administration Nevada Site Office and the NTS Management and Operating (M and O) contractor, NSTec, successfully partnered to modify and upgrade an existing facility, the Visual Examination and Repackaging Building (VERB). The VERB modifications, including a new ventilation system and modified containment structure, required an approved Preliminary Documented Safety Analysis prior to project procurement and construction. Upgrade of the VERB from a radiological facility to a Hazard Category 3 Nuclear Facility required new rigor in the design and construction areas and was executed on an aggressive schedule. The facility Documented Safety Analysis required that OSBs be vented prior to introduction into the VERB. Box venting was safely completed after developing and implementing two types of custom venting systems for the heavy gauge box construction. A remotely operated punching process was used on boxes with wall thickness of up to 3.05 mm (0.120 in) to insert aluminum

  14. Hydrogen explosion testing with a simulated transuranic drum

    International Nuclear Information System (INIS)

    Dykes, K.L.; Meyer, M.L.

    1990-01-01

    Transuranic (TRU) waste generated at the Savannah River Site (SRS) is currently stored onsite for future retrieval and permanent disposal at the Waste Isolation Pilot Plant (WIPP). Some of the TRU waste is stored in vented 210-liter (55-gallon) drums and consists of gloves, wipes, plastic valves, tools, etc. Gas generation caused by radiolysis and biodegradation of these organic waste materials may produce a flammable hydrogen-air mixture (>4% v/v) in the multi-layer plastic waste bags. Using a worst case scenario, a drum explosion test program was carried out to determine the hydrogen concentration necessary to cause removal of the drum lid. Test results indicate an explosive mixture up to 15% v/v of hydrogen can be contained in an SRS TRU drum without total integrity failure via lid removal

  15. Feasibility analysis of constant TRU feeding in waste transmutation system using accelerator-driven subcritical system

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Kun Jai; Cho, Nam Zin; Jo, Chang Keun; Park, Chang Je; Kim, Do Sam; Park, Jeong Hwan [Korea Advanced Institute of Science and Technology, Taejon (Korea)

    1999-03-01

    It is probable that the issue of nuclear spent fuel and high-level waste can have negative impact on the future expansion of nuclear power programs. Accelerator-driven nuclear waste transmutation with constant composition TRU feeding which satisfies non-proliferation condition will help establish the long-range nuclear waste disposal strategy. In this study, current status of accelerator-driven transmutation of waste technology, and feasibility analysis of constant composition TRU feeding system were investigated. We ascertained that solid system using constant composition TRU is feasible with the the capability of transmutation. (author). 13 refs., 53 figs., 20 tabs.

  16. A Cask Processing Enclosure for the TRU Waste Processing Center - 13408

    Energy Technology Data Exchange (ETDEWEB)

    Newman, John T.; Mendez, Nicholas [IP Systems, Inc., 2685 Industrial Lane, Broomfield, Colorado 80020 (United States)

    2013-07-01

    This paper will discuss the key elements considered in the design, construction, and use of an enclosure system built for the TRU Waste Processing Center (TWPC). The TWPC system is used for the repackaging and volume reduction of items contaminated with radioactive material, hazardous waste and mixed waste. The modular structural steel frame and stainless steel skin was designed for rapid field erection by the use of interchangeable self-framing panel sections to allow assembly of a sectioned containment building and for ease of field mobility. The structure was installed on a concrete floor inside of an outer containment building. The major sections included an Outer Cask Airlock, Inner Cask Airlock, Cask Process Area, and Personnel Airlocks. Casks in overpacks containing transuranic waste are brought in via an inter-site transporter. The overpack lid is removed and the cask/overpack is transferred into the Outer Cask Airlock. A contamination cover is installed on the overpack body and the Outer Cask Airlock is closed. The cask/overpack is transferred into the Inner Cask Airlock on a cask bogie and the Inner Cask Airlock is closed. The cask lid is removed and the cask is transferred into the Cask Process Area where it is placed on a cask tilting station. Once the Cask Processing Area is closed, the cask tilt station is activated and wastes are removed, size reduced, then sorted and re-packaged into drums and standard waste boxes through bag ports. The modular system was designed and built as a 'Fast Track' project at IP Systems in Broomfield Colorado and then installed and is currently in use at the DOE TWPC located near Oak Ridge, Tennessee. (authors)

  17. Fire testing of 55 gallon metal waste drums for dry waste storage

    International Nuclear Information System (INIS)

    Hasegawa, H.K.; Staggs, K.J.; Doughty, S.M.

    1993-07-01

    The primary goal of this test program was to conduct a series of fire test to provide information on the fire performance of 55 gallon metal waste drums used for solid waste disposal at Department Of Energy (DOE) facilities. This program was limited in focus to three different types of 55 gallon drums, one radiant heat source, and one specific fire size. The initial test was a single empty 55 gallon drum exposed to a standard ASTME-119 time temperature curve for over 10 minutes. The full scale tests involved metal drums exposed to a 6' diameter flammable liquid fire for a prescribed period of time. The drums contained simulated dry waste materials of primarily class A combustibles. The test results showed that a conventional 55 gallon drum with a 1in. bung would blow its lid consistently

  18. Transuranic (Tru) waste volume reduction operations at a plutonium facility

    Energy Technology Data Exchange (ETDEWEB)

    Cournoyer, Michael E [Los Alamos National Laboratory; Nixon, Archie E [Los Alamos National Laboratory; Dodge, Robert L [Los Alamos National Laboratory; Fife, Keith W [Los Alamos National Laboratory; Sandoval, Arnold M [Los Alamos National Laboratory; Garcia, Vincent E [Los Alamos National Laboratory

    2010-01-01

    Programmatic operations at the Los Alamos National Laboratory Plutonium Facility (TA 55) involve working with various amounts of plutonium and other highly toxic, alpha-emitting materials. The spread of radiological contamination on surfaces, airborne contamination, and excursions of contaminants into the operator's breathing zone are prevented through use of a variety of gloveboxes (the glovebox, coupled with an adequate negative pressure gradient, provides primary confinement). Size-reduction operations on glovebox equipment are a common activity when a process has been discontinued and the room is being modified to support a new customer. The Actin ide Processing Group at TA-55 uses one-meter-long glass columns to process plutonium. Disposal of used columns is a challenge, since they must be size-reduced to get them out of the glovebox. The task is a high-risk operation because the glass shards that are generated can puncture the bag-out bags, leather protectors, glovebox gloves, and the worker's skin when completing the task. One of the Lessons Learned from these operations is that Laboratory management should critically evaluate each hazard and provide more effective measures to prevent personnel injury. A bag made of puncture-resistant material was one of these enhanced controls. We have investigated the effectiveness of these bags and have found that they safely and effectively permit glass objects to be reduced to small pieces with a plastic or rubber mallet; the waste can then be easily poured into a container for removal from the glove box as non-compactable transuranic (TRU) waste. This size-reduction operation reduces solid TRU waste generation by almost 2% times. Replacing one-time-use bag-out bags with multiple-use glass crushing bags also contributes to reducing generated waste. In addition, significant costs from contamination, cleanup, and preparation of incident documentation are avoided. This effort contributes to the Los Alamos

  19. Transuranic (Tru) waste volume reduction operations at a plutonium facility

    International Nuclear Information System (INIS)

    Cournoyer, Michael E.; Nixon, Archie E.; Dodge, Robert L.; Fife, Keith W.; Sandoval, Arnold M.; Garcia, Vincent E.

    2010-01-01

    Programmatic operations at the Los Alamos National Laboratory Plutonium Facility (TA 55) involve working with various amounts of plutonium and other highly toxic, alpha-emitting materials. The spread of radiological contamination on surfaces, airborne contamination, and excursions of contaminants into the operator's breathing zone are prevented through use of a variety of gloveboxes (the glovebox, coupled with an adequate negative pressure gradient, provides primary confinement). Size-reduction operations on glovebox equipment are a common activity when a process has been discontinued and the room is being modified to support a new customer. The Actin ide Processing Group at TA-55 uses one-meter-long glass columns to process plutonium. Disposal of used columns is a challenge, since they must be size-reduced to get them out of the glovebox. The task is a high-risk operation because the glass shards that are generated can puncture the bag-out bags, leather protectors, glovebox gloves, and the worker's skin when completing the task. One of the Lessons Learned from these operations is that Laboratory management should critically evaluate each hazard and provide more effective measures to prevent personnel injury. A bag made of puncture-resistant material was one of these enhanced controls. We have investigated the effectiveness of these bags and have found that they safely and effectively permit glass objects to be reduced to small pieces with a plastic or rubber mallet; the waste can then be easily poured into a container for removal from the glove box as non-compactable transuranic (TRU) waste. This size-reduction operation reduces solid TRU waste generation by almost 2% times. Replacing one-time-use bag-out bags with multiple-use glass crushing bags also contributes to reducing generated waste. In addition, significant costs from contamination, cleanup, and preparation of incident documentation are avoided. This effort contributes to the Los Alamos National

  20. Transuranic (TRU) waste volume reduction operations at a plutonium facility

    International Nuclear Information System (INIS)

    Cournoyer, Michael E.; Nixon, Archie E.; Fife, Keith W.; Sandoval, Arnold M.; Garcia, Vincent E.; Dodge, Robert L.

    2011-01-01

    Programmatic operations at the Los Alamos National Laboratory Plutonium Facility (TA-55) involve working with various amounts of plutonium and other highly toxic, alpha-emitting materials. The spread of radiological contamination on surfaces, airborne contamination, and excursions of contaminants into the operator's breathing zone are prevented through use of a variety of gloveboxes (the glovebox, coupled with an adequate negative pressure gradient, provides primary confinement). Size-reduction operations on glovebox equipment are a common activity when a process has been discontinued and the room is being modified to support a new customer. The Actinide Processing Group at TA-55 uses one-meter or longer glass columns to process plutonium. Disposal of used columns is a challenge, since they must be size-reduced to get them out of the glovebox. The task is a high-risk operation because the glass shards that are generated can puncture the bag-out bags, leather protectors, glovebox gloves, and the worker's skin when completing the task. One of the Lessons Learned from these operations is that Laboratory management should critically evaluate each hazard and provide more effective measures to prevent personnel injury. A bag made of puncture-resistant material was one of these enhanced controls. We have investigated the effectiveness of these bags and have found that they safely and effectively permit glass objects to be reduced to small pieces with a plastic or rubber mallet; the waste can then be easily poured into a container for removal from the glovebox as non-compactable transuranic (TRU) waste. This size-reduction operation reduces solid TRU waste volume generation by almost 2½ times. Replacing one-time-use bag-out bags with multiple-use glass crushing bags also contributes to reducing generated waste. In addition, significant costs from contamination, cleanup, and preparation of incident documentation are avoided. This effort contributes to the Los Alamos

  1. Handling 78,000 drums of mixed-waste sludge

    International Nuclear Information System (INIS)

    Berry, J.B.; Gilliam, T.M.; Harrington, E.S.; Youngblood, E.L.; Baer, M.B.

    1991-01-01

    The Oak Ridge Gaseous Diffusion Plant (now know as the Oak Ridge K-25 Site) prepared two mixed-waste surface impoundments for closure by removing the sludge and contaminated pond-bottom clay and attempting to process it into durable, nonleachable, concrete monoliths. Interim, controlled, above-ground storage of the stabilized waste was planned until final disposition. The strategy for disposal included delisting the stabilized pond sludge from hazardous to nonhazardous and disposing of the delisted monoliths as radioactive waste. Because of schedule constraints and process design and control deficiencies, ∼46,000 drums of material in various stages of solidification and ∼32,000 drums of unprocessed sludge are presently being stored. In addition, the abandoned treatment facility still contains ∼16,000 gal of raw sludge. Such conditions do not comply with the requirements set forth by the Resource Conservation and Recovery Act (RCRA) for the storage of listed waste. Various steps are being taken to bring the storage of ∼78,000 drums of mixed waste into compliance with RCRA. This paper (1) reviews the current situation, (2) discusses the plan for remediation of regulatory noncompliances, including decanting liquid from stabilized waste and dewatering untreated waste, and (3) provides an assessment of alternative raw-waste treatment processes. 1 ref., 6 figs., 2 tabs

  2. Qualitative and quantitative analysis of plutonium in solid waste drums

    International Nuclear Information System (INIS)

    Anno, Jacques; Escarieux, Emile

    1977-01-01

    An assessment of the results given by a study carried out for the development of qualitative and quantitative analysis, by γ spectrometry, of plutonium in solid waste drums is presented. After having reminded the standards and their incidence on the quantities of plutonium to be measured (application at industrial Pu: 20% of Pu 240 ) the equipment used is described. Measurement station provided with a mechanical system consisting of: a rail and a pulley block to bring the drums; a pit and a hydraulic jack with a rotating platform. The detection instrumentation consisting of: a high volume coaxial Ge(Li) detector with a γ ray resolution of 2 keV; an associated electronic; a processing of data by a 'Plurimat 20' minicomputer. Principles of the identification and measurements are specified and supported by experimental results. They are the following: determination of the quality of Pu by measuring the ratio between the γ ray intensities of the 239 Pu 129 keV and of the 241 Pu 148 keV; measurement of the 239 Pu mass by estimating the γ ray counting rate of the 375 keV from the calibrating curves given by plutonium samples varying from 32 mg to 80 g; correction of the results versus the source position into the drum and versus the filling in plastic materials into this drum. The experimental results obtained over 40 solid waste drums are presented along with the error estimates [fr

  3. Shuffler calibration and measurement of mixtures of uranium and plutonium TRU-waste in a plant environment

    International Nuclear Information System (INIS)

    Hurd, J.R.

    1998-01-01

    The active-passive shuffler installed and certified a few years ago in Los Alamos National Laboratory's plutonium facility has now been calibrated for different matrices to measure Waste Isolation Pilot Plant (WIPP)-destined transuranic (TRU)-waste. Little or no data presently exist for these types of measurements in plant environments where there may be sudden large changes in the neutron background radiation which causes distortions in the results. Measurements and analyses of twenty-two 55-gallon drums, consisting of mixtures of varying quantities of uranium and plutonium, have been recently completed at the plutonium facility. The calibration and measurement techniques, including the method used to separate out the plutonium component, will be presented and discussed. Particular attention will be directed to those problems identified as arising from the plant environment. The results of studies to quantify the distortion effects in the data will be presented. Various solution scenarios will be indicated, along with those adopted here

  4. Method of estimating maximum VOC concentration in void volume of vented waste drums using limited sampling data: Application in transuranic waste drums

    International Nuclear Information System (INIS)

    Liekhus, K.J.; Connolly, M.J.

    1995-01-01

    A test program has been conducted at the Idaho National Engineering Laboratory to demonstrate that the concentration of volatile organic compounds (VOCs) within the innermost layer of confinement in a vented waste drum can be estimated using a model incorporating diffusion and permeation transport principles as well as limited waste drum sampling data. The model consists of a series of material balance equations describing steady-state VOC transport from each distinct void volume in the drum. The primary model input is the measured drum headspace VOC concentration. Model parameters are determined or estimated based on available process knowledge. The model effectiveness in estimating VOC concentration in the headspace of the innermost layer of confinement was examined for vented waste drums containing different waste types and configurations. This paper summarizes the experimental measurements and model predictions in vented transuranic waste drums containing solidified sludges and solid waste

  5. On the efficiency calibration of a drum waste assay system

    CERN Document Server

    Dinescu, L; Cazan, I L; Macrin, R; Caragheorgheopol, G; Rotarescu, G

    2002-01-01

    The efficiency calibration of a gamma spectroscopy waste assay system, constructed by IFIN-HH, was performed. The calibration technique was based on the assumption of a uniform distribution of the source activity in the drum and also a uniform sample matrix. A collimated detector (HPGe--20% relative efficiency) placed at 30 cm from the drum was used. The detection limit for sup 1 sup 3 sup 7 Cs and sup 6 sup 0 Co is approximately 45 Bq/kg for a sample of about 400 kg and a counting time of 10 min. A total measurement uncertainty of -70% to +40% was estimated.

  6. Criticality safety evaluation for TRU waste in storage at the RWMC

    International Nuclear Information System (INIS)

    Shaw, M.E.; Briggs, J.B.; Atkinson, C.A.; Briscoe, G.J.

    1993-11-01

    Stored containers (drums, boxes, and bins) of transuranic waste at the Radioactive Waste Management Complex (RWMC) facility located at the Idaho National Engineering Laboratory (INEL) were evaluated based on inherent neutron absorption characteristics of the waste materials. It was demonstrated that these properties are sufficient to preclude an accidental criticality accident at the actual fissile levels present in the waste stored at the RWMC. Based on the database information available, the results reported herein confirm that the waste drums, boxes, and bins currently stored at the RWMC will remain safely subcritical if rearranged, restacked, or otherwise handled. Acceptance criteria for receiving future drum shipments were established based on fully infinite systems

  7. Analytical and experimental evaluation of solid waste drum fire performance volumes I and II

    Energy Technology Data Exchange (ETDEWEB)

    Hecker, C.F., [Los Alamos Technical Associates, Inc., Kennewick, WA (United States); Rhodes, B.T.; Beitel, J.J.; Gottuk, D.T.; Beyler, C.L.; Rosenbaum, E.R., [Hughes Associates, Inc., Columbia, MD (United States)

    1995-04-28

    Fire hazards associated with drum storage of radioactively contaminated wastes are a major concern in DOE facilities design for long term storage of solid wastes in drums. These facilities include drums stored in pallet arrays and in rack storage systems. This report details testing in this area

  8. Calculation of calibration factors and layout criteria for gamma scanning of waste drums from nuclear plants

    International Nuclear Information System (INIS)

    Inder Schmitten, W.; Sohnius, B.; Wehner, E.

    1990-01-01

    This paper present a procedure to calculate calibration factors for converting the measured gamma rate of waste drums into activity content and a layout and free release measurement criterion for waste drums. A computer program is developed that simulates drum scanning technique, which calculates calibration factors and eliminates laborious experimental measurements. The calculated calibration factors exhibit good agreement with experimentally determined values. By checking the calculated calibration factors for trial equipment layouts (including the waste drum and the scanning facility) using the layout and free release measurement criterion, a layout can be achieved that clearly determines whether there can be free release of a waste drum

  9. Los Alamos controlled air incinerator upgrade for TRU/mixed waste operations

    International Nuclear Information System (INIS)

    Vavruska, J.S.; Borduin, L.C.; Hutchins, D.A.; Warner, C.L.; Thompson, T.K.

    1989-01-01

    The Los Alamos Controlled Air Incinerator (CAI) is undergoing a major process upgrade to accept Laboratory-generated transuranic (TRU) and TRU mixed wastes on a production basis. In the interim,prior to the scheduled 1992 operation of a new on-site LLW/mixed waste incinerator, the CAI will also be accepting solid and liquid low-level mixed wastes. This paper describes major modifications that have been made to the process to enhance safety and ensure reliability for long-term, routine waste incineration operations. The regulatory requirements leading to operational status of the system are also briefly described. The CAI was developed in the mid-1970s as a demonstration system for volume reduction of TRU combustible solid wastes. It continues as a successful R and D system well into the 1980s during which incineration tests on a wide variety of radioactive and chemical waste forms were performed. In 1985, a DOE directive required Los Alamos to reduce the volume of its TRU waste prior to ultimate placement in the geological repository at the Waste Isolation Pilot Project (WIPP). With only minor modifications to the original process flowsheet, the Los Alamos CAI was judged capable of conversion to a TRU waste operations mode. 9 refs., 1 fig

  10. Monte Carlo method to characterize radioactive waste drums

    International Nuclear Information System (INIS)

    Lima, Josenilson B.; Dellamano, Jose C.; Potiens Junior, Ademar J.

    2013-01-01

    Non-destructive methods for radioactive waste drums characterization have being developed in the Waste Management Department (GRR) at Nuclear and Energy Research Institute IPEN. This study was conducted as part of the radioactive wastes characterization program in order to meet specifications and acceptance criteria for final disposal imposed by regulatory control by gamma spectrometry. One of the main difficulties in the detectors calibration process is to obtain the counting efficiencies that can be solved by the use of mathematical techniques. The aim of this work was to develop a methodology to characterize drums using gamma spectrometry and Monte Carlo method. Monte Carlo is a widely used mathematical technique, which simulates the radiation transport in the medium, thus obtaining the efficiencies calibration of the detector. The equipment used in this work is a heavily shielded Hyperpure Germanium (HPGe) detector coupled with an electronic setup composed of high voltage source, amplifier and multiport multichannel analyzer and MCNP software for Monte Carlo simulation. The developing of this methodology will allow the characterization of solid radioactive wastes packed in drums and stored at GRR. (author)

  11. Comparative assessment of TRU waste forms and processes. Volume I. Waste form and process evaluations

    International Nuclear Information System (INIS)

    Ross, W.A.; Lokken, R.O.; May, R.P.; Roberts, F.P.; Timmerman, C.L.; Treat, R.L.; Westsik, J.H. Jr.

    1982-09-01

    This study provides an assesses seven waste forms and eight processes for immobilizing transuranic (TRU) wastes. The waste forms considered are cast cement, cold-pressed cement, FUETAP (formed under elevated temperature and pressure) cement, borosilicate glass, aluminosilicate glass, basalt glass-ceramic, and cold-pressed and sintered silicate ceramic. The waste-immobilization processes considered are in-can glass melting, joule-heated glass melting, glass marble forming, cement casting, cement cold-pressing, FUETAP cement processing, ceramic cold-pressing and sintering, basalt glass-ceramic processing. Properties considered included gas generation, chemical durability, mechanical strength, thermal stability, and radiation stability. The ceramic products demonstrated the best properties, except for plutonium release during leaching. The glass and ceramic products had similar properties. The cement products generally had poorer properties than the other forms, except for plutonium release during leaching. Calculations of the Pu release indicated that the waste forms met the proposed NRC release rate limit of 1 part in 10 5 per year in most test conditions. The cast-cement process had the lowest processing cost, followed closely by the cold-pressed and FUETAP cement processes. Joule-heated glass melting had the lower cost of the glass processes. In-can melting in a high-quality canister had the highest cost, and cold-pressed and sintered ceramic the second highest. Labor and canister costs for in-can melting were identified. The major contributor to costs of disposing of TRU wastes in a defense waste repository is waste processing costs. Repository costs could become the dominant cost for disposing of TRU wastes in a commercial repository. It is recommended that cast and FUETAP cement and borosilicate glass waste-form systems be considered. 13 figures, 16 tables

  12. The Advancement of Public Awareness, Concerning TRU Waste Characterization, Using a Virtual Document

    International Nuclear Information System (INIS)

    West, T. B.; Burns, T. P.; Estill, W. G.; Riggs, M. J.; Taggart, D. P.; Punjak, W. A.

    2002-01-01

    Building public trust and confidence through openness is a goal of the DOE Carlsbad Field Office for the Waste Isolation Pilot Plant (WIPP). The objective of the virtual document described in this paper is to give the public an overview of the waste characterization steps, an understanding of how waste characterization instrumentation works, and the type and amount of data generated from a batch of drums. The document is intended to be published on a web page and/or distributed at public meetings on CDs. Users may gain as much information as they desire regarding the transuranic (TRU) waste characterization program, starting at the highest level requirements (drivers) and progressing to more and more detail regarding how the requirements are met. Included are links to: drivers (which include laws, permits and DOE Orders); various characterization steps required for transportation and disposal under WIPP's Hazardous Waste Facility Permit; physical/chemical basis for each characterization method; types of data produced; and quality assurance process that accompanies each measurement. Examples of each type of characterization method in use across the DOE complex are included. The original skeleton of the document was constructed in a PowerPoint presentation and included descriptions of each section of the waste characterization program. This original document had a brief overview of Acceptable Knowledge, Non-Destructive Examination, Non-Destructive Assay, Small Quantity sites, and the National Certification Team. A student intern was assigned the project of converting the document to a virtual format and to discuss each subject in depth. The resulting product is a fully functional virtual document that works in a web browser and functions like a web page. All documents that were referenced, linked to, or associated, are included on the virtual document's CD. WIPP has been engaged in a variety of Hazardous Waste Facility Permit modification activities. During the

  13. MICROBIAL TRANSFORMATIONS OF TRU AND MIXED WASTES: ACTINIDE SPECIATION AND WASTE VOLUME REDUCTION.

    Energy Technology Data Exchange (ETDEWEB)

    FRANCIS, A.J.; DODGE, C.J.

    2006-11-16

    The overall goals of this research project are to determine the mechanism of microbial dissolution and stabilization of actinides in Department of Energy's (DOE) TRU wastes, contaminated sludges, soils, and sediments. This includes (1) investigations on the fundamental aspects of microbially catalyzed radionuclide and metal transformations (oxidation/reduction reactions, dissolution, precipitation, chelation); (2) understanding of the microbiological processes that control speciation and alter the chemical forms of complex inorganic/organic contaminant mixtures; and (3) development of new and improved microbially catalyzed processes resulting in immobilization of metals and radionuclides in the waste with concomitant waste volume reduction.

  14. MICROBIAL TRANSFORMATIONS OF TRU AND MIXED WASTES: ACTINIDE SPECIATION AND WASTE VOLUME REDUCTION

    Energy Technology Data Exchange (ETDEWEB)

    Francis, A.J.; Dodge, C.J.

    2006-06-01

    The overall goals of this research project are to determine the mechanism of microbial dissolution and stabilization of actinides in Department of Energy’s (DOE) TRU wastes, contaminated sludges, soils, and sediments. This includes (i) investigations on the fundamental aspects of microbially catalyzed radionuclide and metal transformations (oxidation/reduction reactions, dissolution, precipitation, chelation); (ii) understanding of the microbiological processes that control speciation and alter the chemical forms of complex inorganic/organic contaminant mixtures; and (iii) development of new and improved microbially catalyzed processes resulting in immobilization of metals and radionuclides in the waste with concomitant waste volume reduction.

  15. MICROBIAL TRANSFORMATIONS OF TRU AND MIXED WASTES: ACTINIDE SPECIATION AND WASTE VOLUME REDUCTION

    Energy Technology Data Exchange (ETDEWEB)

    Francis, A.J.; Dodge, C.J.

    2006-06-01

    The overall goals of this research project are to determine the mechanism of microbial dissolution and stabilization of actinides in Department of Energy's (DOE) TRU wastes, contaminated sludges, soils, and sediments. This includes (1) investigations on the fundamental aspects of microbially catalyzed radionuclide and metal transformations (oxidation/reduction reactions, dissolution, precipitation, chelation); (2) understanding of the microbiological processes that control speciation and alter the chemical forms of complex inorganic/organic contaminant mixtures; and (3) development of new and improved microbially catalyzed processes resulting in immobilization of metals and radionuclides in the waste with concomitant waste volume reduction.

  16. Basic study on decontamination of TRU wastes with cerium mediated electrolytic oxidation method

    International Nuclear Information System (INIS)

    Ishii, Junichi; Kobayashi, Fuyumi; Uchida, Shoji; Sumiya, Masato; Kida, Takashi; Shirahashi, Koichi; Umeda, Miki; Sakuraba, Koichi

    2010-03-01

    At Nuclear Fuel Cycle Safety Engineering Research Facility (NUCEF), the cerium mediated electrolytic oxidation method which is a decontamination technique to decrease the radioactivity of TRU wastes to the clearance-level has been developed for the effective reduction of TRU wastes generated from the decommissioning of a nuclear fuel reprocessing facility and so on. This method corrodes the oxide layer and the surface of metallic TRU metal wastes by the strong oxidation power of Ce 4+ in nitric acid. In this study, parameter tests were conducted to optimize the solution condition of Ce 3+ initial concentrations and nitric acid concentrations. The target corrosion rate of metallic TRU wastes set to be 2 - 4 μm/h for the practical use of this method. Under the optimized solution condition, a dissolution test of stainless steel simulating wastes was carried out. From the result of the dissolution test, the average corrosion rate was 3.3 μm/h during the test time of 90 hours. Based on the supposition that the corrosion depth of metallic TRU wastes was 20 μm enough to achieve the clearance-level, the treatment time for the decontamination was about 6 hours. It was confirmed from the result that the decontamination could be performed within one day and the decontamination solution could repeatedly reuse 15 times. (author)

  17. A Novel and Cost Effective Approach to the Decommissioning and Decontamination of Legacy Glove Boxes - Minimizing TRU Waste and Maximizing LLW Waste - 13634

    Energy Technology Data Exchange (ETDEWEB)

    Pancake, Daniel; Rock, Cynthia M.; Creed, Richard [Argonne National Laboratory, 9700 South Cass Avenue, Lemont, IL 60439 (United States); Donohoue, Tom; Martin, E. Ray; Mason, John A. [ANTECH Corporation 9050 Marshall Court, Westminster, CO, 80031 (United States); Norton, Christopher J.; Crosby, Daniel [Environmental Alternatives, Inc., 149 Emerald Street, Suite R, Keene, NH 03431 (United States); Nachtman, Thomas J. [InstaCote, Inc., 160 C. Lavoy Road, Erie, MI, 48133 (United States)

    2013-07-01

    This paper describes the process of decommissioning two gloveboxes at the Argonne National Laboratory (ANL) that were employed for work with plutonium and other radioactive materials. The decommissioning process involved an initial phase of clearing tools and materials from the glove boxes and disconnecting them from the laboratory infrastructure. The removed materials, assessed as Transuranic (TRU) waste, were packaged into 55 gallon (200 litre) drums and prepared for ultimate disposal at the Waste Isolation Pilot Plant (WIPP) at Carlsbad New Mexico. The boxes were then sampled to determine the radioactive contents by means of smears that were counted with alpha and beta detectors to determine the residual surface contamination, especially in terms of alpha particle emitters that are an indicator of TRU activity. Paint chip samples were also collected and sent for laboratory analysis in order to ascertain the radioactive contamination contributing to the TRU activity as a fixed contamination. The investigations predicted that it may be feasible to reduce the residual surface contamination and render the glovebox structure low level waste (LLW) for disposal. In order to reduce the TRU activity a comprehensive decontamination process was initiated using chemical compounds that are particularly effective for lifting and dissolving radionuclides that adhere to the inner surfaces of the gloveboxes. The result of the decontamination process was a reduction in the TRU surface activity on the inner surfaces of the gloveboxes by four orders of magnitude in terms of disintegrations per unit area (DPA). The next phase of the process involved a comprehensive assay of the gloveboxes using a combination of passive neutron and gamma ray scintillation detectors and a shielded and collimated high purity Germanium (HPGe) gamma ray detector. The HPGe detector was used to obtain gamma ray spectra for a variety of measurement positions within the glovebox. The spectra were used to

  18. A Novel and Cost Effective Approach to the Decommissioning and Decontamination of Legacy Glove Boxes - Minimizing TRU Waste and Maximizing LLW Waste - 13634

    International Nuclear Information System (INIS)

    Pancake, Daniel; Rock, Cynthia M.; Creed, Richard; Donohoue, Tom; Martin, E. Ray; Mason, John A.; Norton, Christopher J.; Crosby, Daniel; Nachtman, Thomas J.

    2013-01-01

    This paper describes the process of decommissioning two gloveboxes at the Argonne National Laboratory (ANL) that were employed for work with plutonium and other radioactive materials. The decommissioning process involved an initial phase of clearing tools and materials from the glove boxes and disconnecting them from the laboratory infrastructure. The removed materials, assessed as Transuranic (TRU) waste, were packaged into 55 gallon (200 litre) drums and prepared for ultimate disposal at the Waste Isolation Pilot Plant (WIPP) at Carlsbad New Mexico. The boxes were then sampled to determine the radioactive contents by means of smears that were counted with alpha and beta detectors to determine the residual surface contamination, especially in terms of alpha particle emitters that are an indicator of TRU activity. Paint chip samples were also collected and sent for laboratory analysis in order to ascertain the radioactive contamination contributing to the TRU activity as a fixed contamination. The investigations predicted that it may be feasible to reduce the residual surface contamination and render the glovebox structure low level waste (LLW) for disposal. In order to reduce the TRU activity a comprehensive decontamination process was initiated using chemical compounds that are particularly effective for lifting and dissolving radionuclides that adhere to the inner surfaces of the gloveboxes. The result of the decontamination process was a reduction in the TRU surface activity on the inner surfaces of the gloveboxes by four orders of magnitude in terms of disintegrations per unit area (DPA). The next phase of the process involved a comprehensive assay of the gloveboxes using a combination of passive neutron and gamma ray scintillation detectors and a shielded and collimated high purity Germanium (HPGe) gamma ray detector. The HPGe detector was used to obtain gamma ray spectra for a variety of measurement positions within the glovebox. The spectra were used to

  19. The TRUEX [TRansUranium EXtraction] process and the management of liquid TRU [transuranic] waste

    International Nuclear Information System (INIS)

    Schulz, W.W.; Horwitz, E.P.

    1987-01-01

    The TRUEX process is a new generic liquid-liquid extraction process for removal of all actinides from acidic nitrate or chloride nuclear waste solutions. Because of its high efficiency and great flexibility, the TRUEX process appears destined to be widely used in the US and possibly in other countries for cost-effective management and disposal of transuranic (TRU) wastes. In the US, TRU wastes are those that contain ≥3.7 x 10 6 Bq/kg) of TRU elements with half-lives greater than 20 y. This paper gives a brief review of the relevant chemistry and summarizes the current status of development and deployment of the TRUEX (TRansUranium EXtraction) process flowsheets to treat specific acidic waste solutions at several US Department of Energy sites. 19 refs., 4 figs., 4 tabs

  20. Comparison of risk-dominant scenario assumptions for several TRU waste facilities in the DOE complex

    International Nuclear Information System (INIS)

    Foppe, T.L.; Marx, D.R.

    1999-01-01

    In order to gain a risk management perspective, the DOE Rocky Flats Field Office (RFFO) initiated a survey of other DOE sites regarding risks from potential accidents associated with transuranic (TRU) storage and/or processing facilities. Recently-approved authorization basis documents at the Rocky Flats Environmental Technology Site (RFETS) have been based on the DOE Standard 3011 risk assessment methodology with three qualitative estimates of frequency of occurrence and quantitative estimates of radiological consequences to the collocated worker and the public binned into three severity levels. Risk Class 1 and 2 events after application of controls to prevent or mitigate the accident are designated as risk-dominant scenarios. Accident Evaluation Guidelines for selection of Technical Safety Requirements (TSRs) are based on the frequency and consequence bin assignments to identify controls that can be credited to reduce risk to Risk Class 3 or 4, or that are credited for Risk Class 1 and 2 scenarios that cannot be further reduced. This methodology resulted in several risk-dominant scenarios for either the collocated worker or the public that warranted consideration on whether additional controls should be implemented. RFFO requested the survey because of these high estimates of risks that are primarily due to design characteristics of RFETS TRU waste facilities (i.e., Butler-type buildings without a ventilation and filtration system, and a relatively short distance to the Site boundary). Accident analysis methodologies and key assumptions are being compared for the DOE sites responding to the survey. This includes type of accidents that are risk dominant (e.g., drum explosion, material handling breach, fires, natural phenomena, external events, etc.), source term evaluation (e.g., radionuclide material-at-risk, chemical and physical form, damage ratio, airborne release fraction, respirable fraction, leakpath factors), dispersion analysis (e.g., meteorological

  1. Study on characteristics of spent PWR cladding hull for categorizing into Non-TRU waste

    International Nuclear Information System (INIS)

    Jung, In Ha; Kim, Jong Ho; Park, Jang Jin; Shin, Jin Myeong; Lee, Ho Hee; Yang, Myung Seung

    2005-01-01

    AFCI and GEN-IV programs aim for decreasing the high level radioactive wastes to be disposed. They also try to get valuable materials to recycle as resources such as uranium and plutonium. On the other hand, cladding hull expected to be one-thirds in volume of spent fuel assembly has not studied so much in the point view of recycling to reuse. Since traditional process of reprocessing was wet process, cladding hull generating through the reprocessing process was unavoidably contaminated with TRU by acid solvent during the process. Therefore, cladding hull has been classified into TRU wastes or high level wastes. According to the strategy for TRU high level radioactive wastes of USA as well as Korea, it regulates in two respects. One is activity and the other is heat generation. In respect of activity, TRU waste contains more than 100 nCi/kg of alpha emits with longer half life than 20 years and higher than 92 in atomic number. Also, wastes are categorized into TRU waste when it generates higher than 2kW/m3, in the respect of heat generation. Our results as well as literatures, almost all of TRU nuclides in the cladding hull are responsible for remained uranium and plutonium owing to pellet-cladding interaction. In addition, recoiled fission products on the surface of the cladding hull serve as heat generator. Up to now, decontamination of the cladding hull generating from the reprocessing of wet process is regarded as valueless and un-economic works owing to the amount of second waste produced

  2. Handling 78,000 drums of mixed-waste sludge

    International Nuclear Information System (INIS)

    Berry, J.B.; Harrington, E.S.; Mattus, A.J.

    1991-01-01

    The Oak Ridge Gaseous Diffusion Plant (now known as the Oak Ridge K-25 Site) closed two mixed-waste surface impoundments by removing the sludge and contaminated pond-bottom clay and attempting to process it into durable, nonleachable, concrete monoliths. Interim, controlled, above-ground storage included delisting the stabilized sludge from hazardous to nonhazardous and disposing of the delisted monoliths as Class 1 radioactive waste. Because of schedule constraints and process design and control deficiencies, ∼46,000 drums of material in various stages of solidification and ∼32,000 barrels of unprocessed sludge are stored. The abandoned treatment facility still contains ∼16,000 gal of raw sludge. Such storage of mixed waste does not comply with the Resource Conservation and Recovery Act (RCRA) guidelines. This paper describes actions that are under way to bring the storage of ∼78,000 drums of mixed waste into compliance with RCRA. Remediation of this problem by treatment to meet regulatory requirements is the focus of the discussion. 3 refs., 2 figs., 4 tabs

  3. Nuclear-waste-management technical support in the development of nuclear-waste-form criteria for the NRC. Task 2. Alternative TRU technologies

    International Nuclear Information System (INIS)

    Bida, G.; MacKenzie, D.R.

    1982-02-01

    Three main areas of transuranic (TRU) waste management are addressed: immobilization processes and waste forms for ultimate geologic disposal of TRU waste; decontamination as a method for TRU waste management; and potential problems associated with gas generation by certain TRU wastes. Waste forms are considered in terms of the regulations and criteria proposed in 10 CFR 60. Evaluation of the waste forms is based principally on ability to meet the release rate criterion of 10 -5 /year given in the Performance Objectives of Section 111, but also on the general requirements of Section 133. The two classes of metallic waste which are candidates for decontamination treatment are Zircaloy cladding hulls from light water reactor fuel elements, and failed facilities and equipment. Decontamination methods are addressed with regard to their ability to remove contamination to a level below the 10 nCi/g TRU limit. Other important factors are the volume reduction achieved, and compatibility of the secondary waste streams with acceptable waste forms. Gas generation by combustible TRU wastes and cast concretes containing TRU isotopes is discussed, and its potential for damage to a geologic repository is considered. Exclusion of combustible TRU waste from repositories is recommended. Conclusions are drawn about the suitability of various waste forms and recommendations are made regarding further work needed in the development of specific TRU waste forms

  4. Test Plan Addendum No. 1: Waste Isolation Pilot Plant bin-scale CH TRU waste tests

    International Nuclear Information System (INIS)

    Molecke, M.A.; Lappin, A.R.

    1990-12-01

    This document is the first major revision to the Test Plan: WIPP Bin-Scale CH TRU Waste Tests. Factors that make this revision necessary are described and justified in Section 1, and elaborated upon in Section 4. This addendum contains recommended estimates of, and details for: (1) The total separation of waste leaching/solubility tests from bin-scale gas tests, including preliminary details and quantities of leaching tests required for testing of Levels 1, 2, and 3 WIPP CH TRU wastes; (2) An initial description and quantification of bin-scale gas test Phase 0, added to provide a crucial tie to pretest waste characterization representatives and overall test statistical validation; (3) A revision to the number of test bins required for Phases 1 and 2 of the bin gas test program, and specification of the numbers of additional bin tests required for incorporating gas testing of Level 2 wastes into test Phase 3. Contingencies are stated for the total number of test bins required, both positive and negative, including the supporting assumptions, logic, and decision points. (4) Several other general test detail updates occurring since the Test Plan was approved and published in January, 1990. Possible impacts of recommended revisions included in this Addendum on WIPP site operations are called out and described. 56 refs., 12 tabs

  5. MWIR-1995 DOE national mixed and TRU waste database users guide

    International Nuclear Information System (INIS)

    1995-11-01

    The Department of Energy (DOE) National 1995 Mixed Waste Inventory Report (MWIR-1995) Database Users Guide provides information on computer system requirements and describes installation, operation, and navigation through the database. The MWIR-1995 database contains a detailed, nationwide compilation of information on DOE mixed waste streams and treatment systems. In addition, the 1995 version includes data on non- mixed, transuranic (TRU) waste streams. These were added to the data set as a result of coordination of the 1995 update with the National Transuranic Program Office's (NTPO's) data needs to support the Waste Isolation Pilot Plant (WIPP) TRU Waste Baseline Inventory Report (WTWBIR). However, the information on the TRU waste streams is limited to that associated with the core mixed waste data requirements. The additional, non-core data on TRU streams collected specifically to support the WTWBIR is not included in the MWIR-1995 database. With respect to both the mixed and TRU waste stream data, the data set addresses open-quotes storedclose quotes streams. In this instance, open-quotes storedclose quotes streams are defined as (a) streams currently in storage at both EM-30 and EM-40 sites and (b) streams that have yet to be generated but are anticipated within the next five years from sources other than environmental restoration and decontamination and decommissioning (ER/D ampersand D) activities. Information on future ER/D ampersand D streams is maintained in the EM-40 core database. The MWIR-1995 database also contains limited information for both waste streams and treatment systems that have been removed or deleted since the 1994 MWIR. Data on these is maintained only through Section 2, Waste Stream Identification/Tracking/Source, to document the reason for removal from the data set

  6. An autonomous mobil robot to perform waste drum inspections

    International Nuclear Information System (INIS)

    Peterson, K.D.; Ward, C.R.

    1994-01-01

    A mobile robot is being developed by the Savannah River Technology Center (SRTC) Robotics Group of Westinghouse Savannah River company (WSRC) to perform mandated inspections of waste drums stored in warehouse facilities. The system will reduce personnel exposure and create accurate, high quality documentation to ensure regulatory compliance. Development work is being coordinated among several DOE, academic and commercial entities in accordance with DOE's technology transfer initiative. The prototype system was demonstrated in November of 1993. A system is now being developed for field trails at the Fernald site

  7. The WIPP RCRA Part B permit application for TRU mixed waste disposal

    International Nuclear Information System (INIS)

    Johnson, J.E.

    1995-01-01

    In August 1993, the New Mexico Environment Department (NMED) issued a draft permit for the Waste Isolation Pilot Plant (WIPP) to begin experiments with transuranic (TRU) mixed waste. Subsequently, the Department of Energy (DOE) decided to cancel the on-site test program, opting instead for laboratory testing. The Secretary of the NMED withdrew the draft permit in 1994, ordering the State's Hazardous and Radioactive Waste Bureau to work with the DOE on submittal of a revised permit application. Revision 5 of the WIPP's Resource Conservation and Recovery Act (RCRA) Part B Permit Application was submitted to the NMED in May 1995, focusing on disposal of 175,600 m 3 of TRU mixed waste over a 25 year span plus ten years for closure. A key portion of the application, the Waste Analysis Plan, shifted from requirements to characterize a relatively small volume of TRU mixed waste for on-site experiments, to describing a complete program that would apply to all DOE TRU waste generating facilities and meet the appropriate RCRA regulations. Waste characterization will be conducted on a waste stream basis, fitting into three broad categories: (1) homogeneous solids, (2) soil/gravel, and (3) debris wastes. Techniques used include radiography, visually examining waste from opened containers, radioassay, headspace gas sampling, physical sampling and analysis of homogeneous wastes, and review of documented acceptable knowledge. Acceptable knowledge of the original organics and metals used, and the operations that generated these waste streams is sufficient in most cases to determine if the waste has toxicity characteristics, hazardous constituents, polychlorinated biphenyls (PBCs), or RCRA regulated metals

  8. Improved Hydrogen Gas Getters for TRU Waste -- Final Report

    International Nuclear Information System (INIS)

    Mark Stone; Michael Benson; Christopher Orme; Thomas Luther; Eric Peterson

    2005-01-01

    Alpha radiolysis of hydrogenous waste and packaging materials generates hydrogen gas in radioactive storage containers. For that reason, the Nuclear Regulatory Commission limits the flammable gas (hydrogen) concentration in the Transuranic Package Transporter-II (TRUPACT-II) containers to 5 vol% of hydrogen in air, which is the lower explosion limit. Consequently, a method is needed to prevent the build up of hydrogen to 5 vol% during the storage and transport of the TRUPACT-II containers (up to 60 days). One promising option is the use of hydrogen getters. These materials scavenge hydrogen from the gas phase and irreversibly bind it in the solid phase. One proven getter is a material called 1,4-bis (phenylethynyl) benzene, or DEB, characterized by the presence of carbon-carbon triple bonds. Carbon may, in the presence of suitable precious metal catalysts such as palladium, irreversibly react with and bind hydrogen. In the presence of oxygen, the precious metal may also eliminate hydrogen by catalyzing the formation of water. This reaction is called catalytic recombination. DEB has the needed binding rate and capacity for hydrogen that potentially could be generated in the TRUPACT II. Phases 1 and 2 of this project showed that uncoated DEB performed satisfactorily in lab scale tests. Based upon these results, Phase 3, the final project phase, included larger scale testing. Test vessels were scaled to replicate the ratio between void space in the inner containment vessel of a TRUPACT-II container and a payload of seven 55-gallon drums. The tests were run with an atmosphere of air for 63.9 days at ambient temperature (15-27 C) and a scaled hydrogen generation rate of 2.60E-07 moles per second (0.35 cc/min). A second type of getter known as VEI, a proprietary polymer hydrogen getter characterized by carbon-carbon double bonds, was also tested in Phase 3. Hydrogen was successfully ''gettered'' by both getter systems. Hydrogen concentrations remained below 5 vol% (in

  9. Improved Hydrogen Gas Getters for TRU Waste -- Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Mark Stone; Michael Benson; Christopher Orme; Thomas Luther; Eric Peterson

    2005-09-01

    Alpha radiolysis of hydrogenous waste and packaging materials generates hydrogen gas in radioactive storage containers. For that reason, the Nuclear Regulatory Commission limits the flammable gas (hydrogen) concentration in the Transuranic Package Transporter-II (TRUPACT-II) containers to 5 vol% of hydrogen in air, which is the lower explosion limit. Consequently, a method is needed to prevent the build up of hydrogen to 5 vol% during the storage and transport of the TRUPACT-II containers (up to 60 days). One promising option is the use of hydrogen getters. These materials scavenge hydrogen from the gas phase and irreversibly bind it in the solid phase. One proven getter is a material called 1,4-bis (phenylethynyl) benzene, or DEB, characterized by the presence of carbon-carbon triple bonds. Carbon may, in the presence of suitable precious metal catalysts such as palladium, irreversibly react with and bind hydrogen. In the presence of oxygen, the precious metal may also eliminate hydrogen by catalyzing the formation of water. This reaction is called catalytic recombination. DEB has the needed binding rate and capacity for hydrogen that potentially could be generated in the TRUPACT II. Phases 1 and 2 of this project showed that uncoated DEB performed satisfactorily in lab scale tests. Based upon these results, Phase 3, the final project phase, included larger scale testing. Test vessels were scaled to replicate the ratio between void space in the inner containment vessel of a TRUPACT-II container and a payload of seven 55-gallon drums. The tests were run with an atmosphere of air for 63.9 days at ambient temperature (15-27°C) and a scaled hydrogen generation rate of 2.60E-07 moles per second (0.35 cc/min). A second type of getter known as VEI, a proprietary polymer hydrogen getter characterized by carbon-carbon double bonds, was also tested in Phase 3. Hydrogen was successfully “gettered” by both getter systems. Hydrogen concentrations remained below 5 vol% (in

  10. Performance Demonstration Program Plan for Nondestructive Assay of Boxed Wastes for the TRU Waste Characterization Program

    International Nuclear Information System (INIS)

    2001-01-01

    The Performance Demonstration Program (PDP) for nondestructive assay (NDA) consists of a series of tests to evaluate the capability for NDA of transuranic (TRU) waste throughout the Department of Energy (DOE) complex. Each test is termed a PDP cycle. These evaluation cycles provide an objective measure of the reliability of measurements obtained from NDA systems used to characterize the radiological constituents of TRU waste. The primary documents governing the conduct of the PDP are the Waste Acceptance Criteria for the Waste Isolation Pilot Plant (WAC; DOE 1999a) and the Quality Assurance Program Document (QAPD; DOE 1999b). The WAC requires participation in the PDP; the PDP must comply with the QAPD and the WAC. The WAC contains technical and quality requirements for acceptable NDA. This plan implements the general requirements of the QAPD and applicable requirements of the WAC for the NDA PDP for boxed waste assay systems. Measurement facilities demonstrate acceptable performance by the successful testing of simulated waste containers according to the criteria set by this PDP Plan. Comparison among DOE measurement groups and commercial assay services is achieved by comparing the results of measurements on similar simulated waste containers reported by the different measurement facilities. These tests are used as an independent means to assess the performance of measurement groups regarding compliance with established quality assurance objectives (QAO's). Measurement facilities must analyze the simulated waste containers using the same procedures used for normal waste characterization activities. For the boxed waste PDP, a simulated waste container consists of a modified standard waste box (SWB) emplaced with radioactive standards and fabricated matrix inserts. An SWB is a waste box with ends designed specifically to fit the TRUPACT-II shipping container. SWB's will be used to package a substantial volume of the TRU waste for disposal. These PDP sample components

  11. Passive neutron design study for 200-L waste drums

    International Nuclear Information System (INIS)

    Menlove, H.O.; Beddingfield, D.B.; Pickrell, M.M.

    1997-09-01

    We have developed a passive neutron counter for the measurement of plutonium in 200-L drums of scrap and waste. The counter incorporates high efficiency for the multiplicity counting in addition to the traditional coincidence counting. The 252 Cf add-a-source feature is used to provide an accurate assay over a wide range of waste matrix materials. The room background neutron rate is reduced by using 30 cm of external polyethylene shielding and the cosmic-ray background is reduced by statistical filtering techniques. Monte Carlo Code calculations were used to determine the optimum detector design, including the gas pressure, size, number, and placement of the 3 He tubes in the moderator. Various moderators, including polyethylene, plastics, teflon, and graphite, were evaluated to obtain the maximum efficiency and minimum detectable mass of plutonium

  12. Terminating Safeguards on Excess Special Nuclear Material: Defense TRU Waste Clean-up and Nonproliferation - 12426

    Energy Technology Data Exchange (ETDEWEB)

    Hayes, Timothy [Los Alamos National Laboratory, Carlsbad Operations Group (United States); Nelson, Roger [Department Of Energy, Carlsbad Operations Office (United States)

    2012-07-01

    The Department of Energy (DOE) and the National Nuclear Security Administration (NNSA) manages defense nuclear material that has been determined to be excess to programmatic needs and declared waste. When these wastes contain plutonium, they almost always meet the definition of defense transuranic (TRU) waste and are thus eligible for disposal at the Waste Isolation Pilot Plant (WIPP). The DOE operates the WIPP in a manner that physical protections for attractiveness level D or higher special nuclear material (SNM) are not the normal operating condition. Therefore, there is currently a requirement to terminate safeguards before disposal of these wastes at the WIPP. Presented are the processes used to terminate safeguards, lessons learned during the termination process, and how these approaches might be useful for future defense TRU waste needing safeguards termination prior to shipment and disposal at the WIPP. Also described is a new criticality control container, which will increase the amount of fissile material that can be loaded per container, and how it will save significant taxpayer dollars. Retrieval, compliant packaging and shipment of retrievably stored legacy TRU waste has dominated disposal operations at WIPP since it began operations 12 years ago. But because most of this legacy waste has successfully been emplaced in WIPP, the TRU waste clean-up focus is turning to newly-generated TRU materials. A major component will be transuranic SNM, currently managed in safeguards-protected vaults around the weapons complex. As DOE and NNSA continue to consolidate and shrink the weapons complex footprint, it is expected that significant quantities of transuranic SNM will be declared surplus to the nation's needs. Safeguards termination of SNM varies due to the wide range of attractiveness level of the potential material that may be directly discarded as waste. To enhance the efficiency of shipping waste with high TRU fissile content to WIPP, DOE designed an

  13. Research and development for treatment and disposal technologies of TRU waste

    International Nuclear Information System (INIS)

    Kamei, Gento; Honda, Akira; Mihara, Morihiro; Oda, Chie; Murakami, Hiroshi; Masuda, Kenta; Yamaguchi, Kohei; Nakanishi, Hiroshi; Sasaki, Ryoichi; Ichige, Satoru; Takahashi, Kuniaki; Meguro, Yoshihiro; Yamaguchi, Hiromi; Aoyama, Yoshio

    2007-09-01

    After the publication of the 2nd progress report of geological disposal of TRU waste in Japan, policy and general scheme of future study for the waste disposal in Japan was published by ANRE and JAEA. This annual report summarized aim and progress of individual problem, which was assigned into JAEA in the published policy and general scheme. The problems are as follows; characteristics of TRU waste and its geologic disposal, treatment and waste production, quality control and inspection methodology for waste, mechanical analysis of near-field, data acquisition and preparation on radionuclides migration, cementitious material transition, bentonite and rock alteration in alkaline solution, nitrate effect, performance assessment of the disposal system and decomposition of nitrate as an alternative technology. (author)

  14. Process Description for the Retrieval of Earth Covered Transuranic (TRU) Waste Containers at the Hanford Site

    International Nuclear Information System (INIS)

    DEROSA, D.C.

    2000-01-01

    This document describes process and operational options for retrieval of the contact-handled suspect transuranic waste drums currently stored below grade in earth-covered trenches at the Hanford Site. Retrieval processes and options discussed include excavation, container retrieval, venting, non-destructive assay, criticality avoidance, incidental waste handling, site preparation, equipment, and shipping

  15. Process Description for the Retrieval of Earth Covered Transuranic (TRU) Waste Containers at the Hanford Site

    Energy Technology Data Exchange (ETDEWEB)

    DEROSA, D.C.

    2000-01-13

    This document describes process and operational options for retrieval of the contact-handled suspect transuranic waste drums currently stored below grade in earth-covered trenches at the Hanford Site. Retrieval processes and options discussed include excavation, container retrieval, venting, non-destructive assay, criticality avoidance, incidental waste handling, site preparation, equipment, and shipping.

  16. Validation testing of radioactive waste drum filter vents

    Energy Technology Data Exchange (ETDEWEB)

    Weber, L.D. [Pall Corp., Port Washington, NY (United States); Rahimi, R.S. [Pall Corp., Cortland, NY (United States); Edling, D. [Edling & Associates, Inc., Russel Springs, KY (United States)

    1997-08-01

    The minimum requirements for Drum Filter Vents (DFVs) can be met by demonstrating conformance with the Waste Isolation Pilot Plant (WIPP) Trupact II Safety Assessment Report (SAR), and conformance with U.S. Federal shipping regulations 49 CFR 178.350, DOT Spec 7A, for Type A packages. These together address a number of safety related performance parameters such as hydrogen diffusivity, flow related pressure drop, filtration efficiency and, separately, mechanical stability and the ability to prevent liquid water in-leakage. In order to make all metal DFV technology (including metallic filter medium) available to DOE sites, Pall launched a product development program to validate an all metal design to meet these requirements. Numerous problems experienced by DOE sites in the past came to light during this development program. They led us to explore enhancements to DFV design and performance testing addressing these difficulties and concerns. The result is a patented all metal DFV certified to all applicable regulatory requirements, which for the first time solves operational and health safety problems reported by DOE site personnel but not addressed by previous DFV`s. The new technology facilitates operations (such as manual, automated and semi-automated drum handling/redrumming), sampling, on-site storage, and shipping. At the same time, it upgrades filtration efficiency in configurations documented to maintain filter efficiency following mechanical stress. 2 refs., 2 figs., 10 tabs.

  17. W-026, transuranic waste restricted waste management (TRU RWM) glovebox operational test report

    Energy Technology Data Exchange (ETDEWEB)

    Leist, K.J.

    1998-02-18

    The TRU Waste/Restricted Waste Management (LLW/PWNP) Glovebox 401 is designed to accept and process waste from the Transuranic Process Glovebox 302. Waste is transferred to the glovebox via the Drath and Schraeder Bagless Transfer Port (DO-07401) on a transfer stand. The stand is removed with a hoist and the operator inspects the waste (with the aid of the Sampling and Treatment Director) to determine a course of action for each item. The waste is separated into compliant and non compliant. One Trip Port DO-07402A is designated as ``Compliant``and One Trip Port DO-07402B is designated as ``Non Compliant``. As the processing (inspection, bar coding, sampling and treatment) of the transferred items takes place, residue is placed in the appropriate One Trip port. The status of the waste items is tracked by the Data Management System (DMS) via the Plant Control System (PCS) barcode interface. As an item is moved for sampling or storage or it`s state altered by treatment, the Operator will track an items location using a portable barcode reader and entry any required data on the DMS console. The Operational Test Procedure (OTP) will perform evolutions (described here) using the Plant Operating Procedures (POP) in order to verify that they are sufficient and accurate for controlled glovebox operation.

  18. W-026, transuranic waste restricted waste management (TRU RWM) glovebox operational test report

    International Nuclear Information System (INIS)

    Leist, K.J.

    1998-01-01

    The TRU Waste/Restricted Waste Management (LLW/PWNP) Glovebox 401 is designed to accept and process waste from the Transuranic Process Glovebox 302. Waste is transferred to the glovebox via the Drath and Schraeder Bagless Transfer Port (DO-07401) on a transfer stand. The stand is removed with a hoist and the operator inspects the waste (with the aid of the Sampling and Treatment Director) to determine a course of action for each item. The waste is separated into compliant and non compliant. One Trip Port DO-07402A is designated as ''Compliant''and One Trip Port DO-07402B is designated as ''Non Compliant''. As the processing (inspection, bar coding, sampling and treatment) of the transferred items takes place, residue is placed in the appropriate One Trip port. The status of the waste items is tracked by the Data Management System (DMS) via the Plant Control System (PCS) barcode interface. As an item is moved for sampling or storage or it's state altered by treatment, the Operator will track an items location using a portable barcode reader and entry any required data on the DMS console. The Operational Test Procedure (OTP) will perform evolutions (described here) using the Plant Operating Procedures (POP) in order to verify that they are sufficient and accurate for controlled glovebox operation

  19. In Plant Measurement and Analysis of Mixtures of Uranium and Plutonium TRU-Waste Using a 252Cf Shuffler Instrument

    International Nuclear Information System (INIS)

    Hurd, J.R.

    1998-01-01

    The active-passive 252 Cf shuffler instrument, installed and certified several years ago in Los Alamos National Laboratory's plutonium facility, has now been calibrated for different matrices to measure Waste Isolation Pilot Plant (WIPP)-destined transuranic (TRU)-waste. Little or no data currently exist for these types of measurements in plant environments where sudden large changes in the neutron background radiation can significantly distort the results. Measurements and analyses of twenty-two 55-gallon drums, consisting of mixtures of varying quantities of uranium and plutonium in mostly noncombustible matrices, have been recently completed at the plutonium facility. The calibration and measurement techniques, including the method used to separate out the plutonium component, will be presented and discussed. Calculations used to adjust for differences in uranium enrichment from that of the calibration standards will be shown. Methods used to determine various sources of both random and systematic error will be indicated. Particular attention will be directed to those problems identified as arising from the plant environment. The results of studies to quantify the aforementioned distortion effects in the data will be presented. Various solution scenarios will be outlined, along with those adopted here

  20. Field test results for radioactive waste drum characterization with Waste Inspection Tomography (WIT)

    Energy Technology Data Exchange (ETDEWEB)

    Bernardi, R.T. [Bio-Imaging Research, Inc., Lincolnshire, IL (United States)

    1997-11-01

    This paper summarizes the design, fabrication, factory testing, evaluation and demonstration of waste inspection tomography (WIT). WIT consists of a self-sufficient, mobile semi-trailer for Non-Destructive Evaluation and Non-Destructive Assay (NDE/NDA) characterization of nuclear waste drums using X-ray and gamma-ray tomographic techniques. The 23-month WIT Phase I initial test results include 2 MeV Digital Radiography (DR), Computed Tomography (CT), Anger camera imaging, Single Photon Emission Computed Tomography (SPECT), Gamma-Ray Spectroscopy, Collimated Gamma Scanning (CGS), and Active and Passive Computed Tomography (A&PCT) using a 1.4 mCi source of {sup 166}Ho. These techniques were initially demonstrated on a 55-gallon phantom drum with three simulated waste matrices of combustibles, heterogeneous metals, and cement using check sources of gamma active isotopes. Waste matrix identification, isotopic identification, and attenuation-corrected gamma activity determination were all demonstrated nondestructively and noninvasively. Preliminary field tests results with nuclear waste drums are summarized. WIT has inspected drums with 0 to 20 grams plutonium 239. The minimum measured was 0.131 gram plutonium 239 in cement. 8 figs.

  1. Investigations with respect to pressure build-up in 200 l drums with supercompacted low level waste (LLW)

    International Nuclear Information System (INIS)

    Kroth, K.; Lammertz, H.

    1988-04-01

    In the drum storage facilities of various nuclear power stations, ballooning effects have recently been observed on a limited number of 200 l drums filled with hypercompacted mixed LLW. The ballooning of the drums lid and bottom is due to internal overpressure caused by gas formation in the waste. The internal drum pressures and the composition of the drum gases were measured on a considerable number of 200 l drums. Hydrogen, formed by chemical reactions between the waste components, was identified as the pressure generating gas. The reasons for the hydrogen formation were investigated on both real and simulated wastes. (orig.) [de

  2. Statistical analysis of radiochemical measurements of TRU radionuclides in REDC waste

    International Nuclear Information System (INIS)

    Beauchamp, J.; Downing, D.; Chapman, J.; Fedorov, V.; Nguyen, L.; Parks, C.; Schultz, F.; Yong, L.

    1996-10-01

    This report summarizes results of the study on the isotopic ratios of transuranium elements in waste from the Radiochemical Engineering Development Center actinide-processing streams. The knowledge of the isotopic ratios when combined with results of nondestructive assays, in particular with results of Active-Passive Neutron Examination Assay and Gamma Active Segmented Passive Assay, may lead to significant increase in precision of the determination of TRU elements contained in ORNL generated waste streams

  3. Nondestructive testing methods for 55-gallon, waste storage drums

    International Nuclear Information System (INIS)

    Ferris, R.H.; Hildebrand, B.P.; Hockey, R.L.; Riechers, D.M.; Spanner, J.C.; Duncan, D.R.

    1993-06-01

    The Westinghouse Hanford Company (WHC) authorized Pacific Northwest Laboratory (PNL) to conduct a feasibility study to identify promising nondestructive testing (NDT) methods for detecting general and localized (both pitting and pinhole) corrosion in the 55-gal drums that are used to store solid waste materials at the Hanford Site. This document presents results obtained during a literature survey, identifies the relevant reference materials that were reviewed, provides a technical description of the methods that were evaluated, describes the laboratory tests that were conducted and their results, identifies the most promising candidate methods along with the rationale for these selections, and includes a work plan for recommended follow-on activities. This report contains a brief overview and technical description for each of the following NDT methods: magnetic testing techniques; eddy current testing; shearography; ultrasonic testing; radiographic computed tomography; thermography; and leak testing with acoustic detection

  4. Hydrogen venting characteristics of commercial carbon-composite filters and applications to TRU waste

    International Nuclear Information System (INIS)

    Callis, E.L.; Marshall, R.S.; Cappis, J.H.

    1997-04-01

    The generation of hydrogen (by radiolysis) and of other potentially flammable gases in radioactive wastes which are in contact with hydrogenous materials is a source of concern, both from transportation and on-site storage considerations. Because very little experimental data on the generation and accumulation of hydrogen was available in actual waste materials, work was initiated to experimentally determine factors affecting the concentration of hydrogen in the waste containers, such as the hydrogen generation rate, (G-values) and the rate of loss of hydrogen through packaging and commercial filter-vents, including a new design suitable for plastic bags. This report deals only with the venting aspect of the problem. Hydrogen venting characteristics of two types of commercial carbon-composite filter-vents, and two types of PVC bag closures (heat-sealed and twist-and-tape) were measured. Techniques and equipment were developed to permit measurement of the hydrogen concentration in various layers of actual transuranic (TRU) waste packages, both with and without filter-vents. A test barrel was assembled containing known configuration and amounts of TRU wastes. Measurements of the hydrogen in the headspace verified a hydrogen release model developed by Benchmark Environmental Corporation. These data were used to calculate revised wattage Emits for TRU waste packages incorporating the new bag filter-vent

  5. A method to quantify tritium inside waste drums: He{sup 3} ingrowth method

    Energy Technology Data Exchange (ETDEWEB)

    Godot, A.; Lepeytre, C.; Hubinois, J.C. [CEA Valduc, Dept. Traitement Materiaux Nucleaires, Service Analyses- Dechets, Lab. Chimie Analytique, 21 - Is-sur-Tille (France); Arseguel, A.; Daclin, J.P.; Douche, C. [CEA Valduc, Dept. Traitement Materiaux Nucleaires, Service Analyses- Dechets, Lab. de Gestion des Dechets Trities, 21 - Is-sur-Tille (France)

    2008-07-15

    This method enables an indirect, non intrusive and non destructive measurement of the Tritium activity in wastes drums. The amount of tritium enclosed inside a wastes drum can be determined by the measurement of the leak rate of {sup 3}He of this latter. The simulation predicts that a few months are necessary for establishing the equilibrium between the {sup 3}He production inside the drum and the {sup 3}He drum leak. In practice, after one year of storage, sampling {sup 3}He outside the drum can be realized by the mean of a confining chamber that collect the {sup 3}He outflow. The apparatus, the experimental procedure and the calculation of tritium activity from mass spectrometric {sup 3}He measurements are detailed. The industrial device based on a confinement cell and the automated process to measure the {sup 3}He amount at the initial time and after the confinement time is described. Firstly, reference drums containing a certified tritium activity (HTO) in addition to organic materials have been measured to qualify the method and to evaluate its performances. Secondly, tritium activity of organic wastes drums issued from the storage building in Valduc have been determined. Results of the qualification and optimised values of the experimental parameters are reported in order to determine the performances of this industrial device. As a conclusion, the apparatus enables the measurement of an activity as low as 1 GBq of tritium in a 200 liters drum containing organic wastes. (authors)

  6. Techniques for improving shuffler assay results for 55-gallon waste drums

    International Nuclear Information System (INIS)

    Rinard, P.M.; Prettyman, T.H.; Stuenkel, D.

    1994-01-01

    Accurate assays of the fissile contents in waste drums are needed to ensure the most proper and economical handling and disposal of the waste. An improvement of accuracy will mean fewer drums disposed as transuranic waste when they really contain low-level waste, saving both money and burial sites. Shufflers are used for assaying waste drums and are very accurate with nonmoderating matrices (such as iron). In the active mode they count delayed neutrons released after fissions are induced by irradiation neutrons from a 252 Cf source. However, as the hydrogen density from matrices such as paper or gloves increases, the accuracy can suffer without proper attention. The neutron transport and fission probabilities change with the hydrogen density, causing the neutron count rate to vary with the position of the fissile material within the drum. The magnitude of this variation grows with the hydrogen density

  7. Preliminary identification of interfaces for certification and transfer of TRU waste to WIPP

    International Nuclear Information System (INIS)

    Whitty, W.J.; Ostenak, C.A.; Pillay, K.K.S.

    1982-02-01

    This study complements the national program to certify that newly generated and stored, unclassified defense transuranic (TRU) wastes meet the Waste Isolation Pilot Plant (WIPP) Waste Acceptance Criteria. The objectives of this study were to identify (1) the existing organizational structure at each of the major waste-generating and shipping sites and (2) the necessary interfaces between the waste shippers and WIPP. The interface investigations considered existing waste management organizations at the shipping sites and the proposed WIPP organization. An effort was made to identify the potential waste-certifying authorities and the lines of communication within these organizations. The long-range goal of this effort is to develop practicable interfaces between waste shippers and WIPP to enable the continued generation, interim storage, and eventual shipment of certified TRU wastes to WIPP. Some specific needs identified in this study include: organizational responsibility for certification procedures and quality assurance (QA) program; simple QA procedures; and specification and standardization of reporting forms and procedures, waste containers, and container labeling, color coding, and code location

  8. Development of an Alternative Treatment Scheme for Sr/TRU Removal: Permanganate Treatment of AN-107 Waste

    Energy Technology Data Exchange (ETDEWEB)

    RT Hallen; SA Bryan; FV Hoopes

    2000-08-04

    A number of Hanford tanks received waste containing organic complexants, which increase the volubility of Sr-90 and transuranic (TRU) elements. Wastes from these tanks require additional pretreatment to remove Sr-90 and TRU for immobilization as low activity waste (Waste Envelope C). The baseline pretreatment process for Sr/TRU removal was isotopic exchange and precipitation with added strontium and iron. However, studies at both Battelle and Savannah River Technology Center (SRTC) have shown that the Sr/Fe precipitates were very difficult to filter. This was a result of the formation of poor filtering iron solids. An alternate treatment technology was needed for Sr/TRU removal. Battelle had demonstrated that permanganate treatment was effective for decontaminating waste samples from Hanford Tank SY-101 and proposed that permanganate be examined as an alternative Sr/TRU removal scheme for complexant-containing tank wastes such as AW107. Battelle conducted preliminary small-scale experiments to determine the effectiveness of permanganate treatment with AN-107 waste samples that had been archived at Battelle from earlier studies. Three series of experiments were performed to evaluate conditions that provided adequate Sr/TRU decontamination using permanganate treatment. The final series included experiments with actual AN-107 diluted feed that had been obtained specifically for BNFL process testing. Conditions that provided adequate Sr/TRU decontamination were identified. A free hydroxide concentration of 0.5M provided adequate decontamination with added Sr of 0.05M and permanganate of 0.03M for archived AN-107. The best results were obtained when reagents were added in the sequence Sr followed by permanganate with the waste at ambient temperature. The reaction conditions for Sr/TRU removal will be further evaluated with a 1-L batch of archived AN-107, which will provide a large enough volume of waste to conduct crossflow filtration studies (Hallen et al. 2000a).

  9. Development of an Alternative Treatment Scheme for Sr/TRU Removal: Permanganate Treatment of AN-107 Waste

    International Nuclear Information System (INIS)

    Hallen, R.T.; Bryan, S.A.; Hoopes, F.V.

    2000-01-01

    A number of Hanford tanks received waste containing organic complexants, which increase the volubility of Sr-90 and transuranic (TRU) elements. Wastes from these tanks require additional pretreatment to remove Sr-90 and TRU for immobilization as low activity waste (Waste Envelope C). The baseline pretreatment process for Sr/TRU removal was isotopic exchange and precipitation with added strontium and iron. However, studies at both Battelle and Savannah River Technology Center (SRTC) have shown that the Sr/Fe precipitates were very difficult to filter. This was a result of the formation of poor filtering iron solids. An alternate treatment technology was needed for Sr/TRU removal. Battelle had demonstrated that permanganate treatment was effective for decontaminating waste samples from Hanford Tank SY-101 and proposed that permanganate be examined as an alternative Sr/TRU removal scheme for complexant-containing tank wastes such as AW107. Battelle conducted preliminary small-scale experiments to determine the effectiveness of permanganate treatment with AN-107 waste samples that had been archived at Battelle from earlier studies. Three series of experiments were performed to evaluate conditions that provided adequate Sr/TRU decontamination using permanganate treatment. The final series included experiments with actual AN-107 diluted feed that had been obtained specifically for BNFL process testing. Conditions that provided adequate Sr/TRU decontamination were identified. A free hydroxide concentration of 0.5M provided adequate decontamination with added Sr of 0.05M and permanganate of 0.03M for archived AN-107. The best results were obtained when reagents were added in the sequence Sr followed by permanganate with the waste at ambient temperature. The reaction conditions for Sr/TRU removal will be further evaluated with a 1-L batch of archived AN-107, which will provide a large enough volume of waste to conduct crossflow filtration studies (Hallen et al. 2000a)

  10. The Welding Effect on Mechanical Strength of Low Level Radioactive Waste Drum Container

    International Nuclear Information System (INIS)

    Aisyah; Herlan Martono

    2007-01-01

    The treatment of compactable low level solid waste was started by compaction of 100 liter drum containing the waste using 600 kN hydraulic press in 200 liters drum. The 200 liter drum of waste container containing of compacted waste then immobilized with cement and stored in interm storage. The 200 liter drum of waste container made of carbon steel material to comply with a good mechanical strength request in order to be able to retain the waste content for long period. Welding is a one step in a waste drum container fabrication process that has an opportunity in decreasing these mechanical strength. The research is carried out by welding the waste drum container material sample by electric arc welding. Mechanical strength test carried out by measuring the tensile strength by using the tensile strength machine, hardness test by using Vickers hardness test and microstructure observation by using the optic microscope. The result shows that the welding cause the microstructure changes, its meaning of forming ferro oxide phase on welding area that leads to the brittle material, so that the mechanical strength has a decreasing slightly. Nevertheless the decreasing of mechanical strength is still in the range of safety limit. (author)

  11. Review on technical issues influencing the performance of chemical barriers of TRU waste repository

    International Nuclear Information System (INIS)

    Fujita, Tomonari; Sugiyama, Daisuke; Tsukamoto, Masaki; Yokoyama, Hayaichi

    1997-01-01

    Studies of technical issues influencing the performance assessment of TRU waste disposal which is occurred from the nuclear fuel reprocessing were reviewed in related to the development of safety analysis method. Especially, the chemical containment was investigated as a key barrier to radionuclide migration. TRU waste including long-lived radionuclides need long-term performance assessment which could be assumed only by the chemical barrier. The description of technical issues concerned with the performance of TRU waste repository has been divided into the following categories: long-term degradation of cementitious materials as engineered barrier for radionuclide migration, effect of colloids, organic macromolecules and organic degradation products on chemical behavior of radionuclides, gas generation by corrosion of metallic wastes, and effects of microbial activity. Preliminary performance assessment indicated that important factors affecting performance of chemical barriers in near-field were the distribution coefficient and the solubility of radionuclides in near-field groundwater. Therefore, it was identified that key issues associated with performance of chemical barrier were evaluation of (a) the long-term change of distribution coefficient of cementitious material through the degradation under repository condition and (b) chemical speciation change of radionuclides such as increase of solubility by the presence of colloidal-size materials. (author)

  12. Potential Flammable Gas Explosion in the TRU Vent and Purge Machine

    International Nuclear Information System (INIS)

    Vincent, A

    2006-01-01

    The objective of the analysis was to determine the failure of the Vent and Purge (V and P) Machine due to potential explosion in the Transuranic (TRU) drum during its venting and/or subsequent explosion in the V and P machine from the flammable gases (e.g., hydrogen and Volatile Organic Compounds [VOCs]) vented into the V and P machine from the TRU drum. The analysis considers: (a) increase in the pressure in the V and P cabinet from the original deflagration in the TRU drum including lid ejection, (b) pressure wave impact from TRU drum failure, and (c) secondary burns or deflagrations resulting from excess, unburned gases in the cabinet area. A variety of cases were considered that maximized the pressure produced in the V and P cabinet. Also, cases were analyzed that maximized the shock wave pressure in the cabinet from TRU drum failure. The calculations were performed for various initial drum pressures (e.g., 1.5 and 6 psig) for 55 gallon TRU drum. The calculated peak cabinet pressures ranged from 16 psig to 50 psig for various flammable gas compositions. The blast on top of cabinet and in outlet duct ranged from 50 psig to 63 psig and 12 psig to 16 psig, respectively, for various flammable gas compositions. The failure pressures of the cabinet and the ducts calculated by structural analysis were higher than the pressure calculated from potential flammable gas deflagrations, thus, assuring that V and P cabinet would not fail during this event. National Fire Protection Association (NFPA) 68 calculations showed that for a failure pressure of 20 psig, the available vent area in the V and P cabinet is 1.7 to 2.6 times the required vent area depending on whether hydrogen or VOCs burn in the V and P cabinet. This analysis methodology could be used to design the process equipment needed for venting TRU waste containers at other sites across the Department of Energy (DOE) Complex

  13. Alkaline degradation of organic materials contained in TRU wastes under repository conditions

    International Nuclear Information System (INIS)

    Otsuka, Yoshiki; Banba, Tsunetaka

    2007-09-01

    Alkaline degradation tests for 9 organic materials were conducted under the conditions of TRU waste disposal: anaerobic alkaline conditions. The tests were carried out at 90degC for 91 days. The sample materials for the tests were selected from the standpoint of constituent organic materials of TRU wastes. It has been found that cellulose and plastic solidified products are degraded relatively easily and that rubbers are difficult to degrade. It could be presumed that the alkaline degradation of organic materials occurs starting from the functional group in the material. Therefore, the degree of degradation difficulty is expected to be dependent on the kinds of functional group contained in the organic material. (author)

  14. Development of crystalline ceramic for immobilization of TRU wastes in V.G. Khlopin Radium Institute

    International Nuclear Information System (INIS)

    Burakov, B.E.; Anderson, E.B.

    1999-01-01

    This paper discusses the Radium Institute's experience in the synthesis of crystalline ceramics based on two groups of actinide host-phases: 1) Zircon/zirconia-(Zn, Ac)SiO 4 /(Zr, Ac)O 2 , where Ac=Pu, Np, Am, Cm; 2) Garnet/perovskite-(Y, Gd, Ac) 3 (Al, Ga, Ac,..) 5 O 12 /(Y, Gd, Ac)(Al, Ga)O 3 . The zircon/zirconia ceramic was suggested as an universal waste form for the immobilization of TRU as well as weapon-grade Pu. Because the position of the Russian Ministry of Atomic Energy (Minatom) does not consider weapons Pu as a waste', the Radium Institute proposed the use of the same ceramic (mainly monophase zirconia ) as a Pu-fuel. The garnet/perovskite ceramic was suggested for the immobilization of military TRU wastes of complex chemical composition. The advantage of this ceramic is that Garnet and Perovskite host-phases can incorporate in their lattices not only actinides, but also other elements including neutron absorbers in a broad range of concentration and in different valence state. Sample of zircon/zirconia ceramic were prepared by hot uniaxial pressing (at temperature T=1300, 1400, 1500degC and pressure P=25 MPa) and sintering (at T=1450, 1490, 1500, 1600degC) methods using different types of initial precursor. Samples of garnet/perovskite ceramic were synthesized by melting method at T=2000degC. Ce, U, Gd were used as TRU stimulants for both types of ceramic. One sample of zircon/zirconia ceramic was doped with 10 wt.% of Pu 239 . Physico-chemical features of these ceramics are described. In conclusion we propose that the pressureless technology based on sintering or melting methods be used for the synthesis of ceramics for the immobilization of all types of TRU wastes. (author)

  15. Development of TRU waste mobile analysis methods for RCRA-regulated metals

    International Nuclear Information System (INIS)

    Mahan, C.A.; Villarreal, R.; Drake, L.; Figg, D.; Wayne, D.; Goldstein, S.

    1998-01-01

    This is the final report of a one-year, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). Glow-discharge mass spectrometry (GD-MS), laser-induced breakdown spectroscopy (LIBS), dc-arc atomic-emission spectroscopy (DC-ARC-AES), laser-ablation inductively-coupled-plasma mass spectrometry (LA-ICP-MS), and energy-dispersive x-ray fluorescence (EDXRF) were identified as potential solid-sample analytical techniques for mobile characterization of TRU waste. Each technology developers was provided with surrogate TRU waste samples in order to develop an analytical method. Following successful development of the analytical method, five performance evaluation samples were distributed to each of the researchers in a blind round-robin format. Results of the round robin were compared to known values and Transuranic Waste Characterization Program (TWCP) data quality objectives. Only two techniques, DC-ARC-AES and EDXRF, were able to complete the entire project. Methods development for GD-MS and LA-ICP-MS was halted due to the stand-down at the CMR facility. Results of the round-robin analysis are given for the EDXRF and DCARC-AES techniques. While DC-ARC-AES met several of the data quality objectives, the performance of the EDXRF technique by far surpassed the DC-ARC-AES technique. EDXRF is a simple, rugged, field portable instrument that appears to hold great promise for mobile characterization of TRU waste. The performance of this technique needs to be tested on real TRU samples in order to assess interferences from actinide constituents. In addition, mercury and beryllium analysis will require another analytical technique because the EDXRF method failed to meet the TWCP data quality objectives. Mercury analysis is easily accomplished on solid samples by cold vapor atomic fluorescence (CVAFS). Beryllium can be analyzed by any of a variety of emission techniques

  16. Comprehensive implementation plan for the DOE defense buried TRU- contaminated waste program

    International Nuclear Information System (INIS)

    Everette, S.E.; Detamore, J.A.; Raudenbush, M.H.; Thieme, R.E.

    1988-02-01

    In 1970, the US Atomic Energy Commission established a ''transuranic'' (TRU) waste classification. Waste disposed of prior to the decision to retrievably store the waste and which may contain TRU contamination is referred to as ''buried transuranic-contaminated waste'' (BTW). The DOE reference plan for BTW, stated in the Defense Waste Management Plan, is to monitor it, to take such remedial actions as may be necessary, and to re-evaluate its safety as necessary or in about 10-year periods. Responsibility for management of radioactive waste and byproducts generated by DOE belongs to the Secretary of Energy. Regulatory control for these sites containing mixed waste is exercised by both DOE (radionuclides) and EPA (hazardous constituents). Each DOE Operations Office is responsible for developing and implementing plans for long-term management of its radioactive and hazardous waste sites. This comprehensive plan includes site-by-site long-range plans, site characteristics, site costs, and schedules at each site. 13 figs., 15 tabs

  17. Evaluation of X-ray System for Nondestructive Testing on Radioactive Waste Drums

    International Nuclear Information System (INIS)

    Park, Jong Kil; Maeng, Seong Jun; Lee, Yeon Ee; Hwang, Tae Won

    2008-01-01

    The physical and chemical properties of radioactive waste drums, which have been temporarily stored on site, should be characterized before their shipment to a disposal facility in order to prove that the properties meet the acceptance guideline. The investigation of NDT(Nondestructive Test) method was figured out that the contents in drum, the quantitative analysis of free standing water and void fraction can be examined with X-ray NDT techniques. This paper describes the characteristics of X-ray NDT such as its principles, the considerations for selection of X-ray system, etc. And then, the waste drum characteristics such as drum type and dimension, contents in drum, etc. were examined, which are necessary to estimate the optimal X-ray energy for NDT of a drum. The estimation results were that: the proper X-ray energy is under 3 MeV to test the drums of 320 β and less; both X-ray systems of 450 keV and/or 3 MeV might be needed considering the economical efficiency and the realization. The number of drums that can be tested with 450 keV and 3 MeV X-ray system was figured out as 42,327 and 18,105 drums (based on storage of 2006. 12), respectively. Four testing scenarios were derived considering equipment procurement method, outsourcing or not, etc. The economical and feasibility assessment for the scenarios was resulted in that an optimal scenario is dependent on the acceptance guide line, the waste generator's policy on the waste treatment and the delivery to a disposal facility, etc. For example, it might be desirable that a waste generator purchases two 450 keV mobile system to examine the drums containing low density waste, and that outsourcing examination for the high density drums, if all NDT items such as quantitative analysis for 'free standing water' and 'void fraction', and confirmation of contents in drum have to be characterized. However, one 450 keV mobile system seems to be required to test only the contents in 13,000 drums per year.

  18. Composition and activity variations in bulk gas of drum waste packages of Paks NPP

    International Nuclear Information System (INIS)

    Molnar, M.; Palcsu, L.; Svingor, E.; Szanto, Zs.; Futo, I.; Ormai, P.

    2001-01-01

    To obtain reliable estimates of the quantities and rates of the gas production a series of measurements was carried out in drum waste packages generated and temporarily stored at the site of Paks Nuclear Power Plant (Paks NPP). Ten drum waste packages were equipped with sampling valves for repeated sampling. Nine times between 04/02/2000 and 19/07/2001 qualitative gas component analyses of bulk gases of drums were executed. Gas samples were delivered to the laboratory of the ATOMKI for tritium and radiocarbon content measurements.(author)

  19. Review and evaluation of metallic TRU nuclear waste consolidation methods

    International Nuclear Information System (INIS)

    Montgomery, D.R.; Nesbitt, J.F.

    1983-08-01

    The US Department of Energy established the Commercial Waste Treatment Program to develop, demonstrate, and deploy waste treatment technology. In this report, viable methods are identified that could consolidate the volume of metallic wastes generated in a fuel reprocessing facility. The purpose of this study is to identify, evaluate, and rate processes that have been or could be used to reduce the volume of contaminated/irradiated metallic waste streams and to produce an acceptable waste form in a safe and cost-effective process. A technical comparative evaluation of various consolidation processes was conducted, and these processes were rated as to the feasibility and cost of producing a viable product from a remotely operated radioactive process facility. Out of the wide variety of melting concepts and consolidation systems that might be applicable for consolidating metallic nuclear wastes, the following processes were selected for evaluation: inductoslay melting, rotating nonconsumable electrode melting, plasma arc melting, electroslag melting with two nonconsumable electrodes, vacuum coreless induction melting, and cold compaction. Each process was evaluated and rated on the criteria of complexity of process, state and type of development required, safety, process requirements, and facility requirements. It was concluded that the vacuum coreless induction melting process is the most viable process to consolidate nuclear metallic wastes. 11 references

  20. Induction melting for volume reduction of metallic TRU wastes

    International Nuclear Information System (INIS)

    Westsik, J.H. Jr.; Montgomery, D.R.; Katayama, Y.B.; Ross, W.A.

    1986-01-01

    Volume reduction of metallic transuranic wastes offers economic and safety incentives for treatment of wastes generated at a hypothetical commercial fuel reprocessing facility. Induction melting has been identified as the preferred process for volume reduction of spent fuel hulls, fuel assembly hardware, and failed equipment from a reprocessing plant. Bench-scale melting of Zircaloy and stainless steel mixtures has been successfully conducted in a graphite crucible inside a large vacuum chamber. A low-melting-temperature alloy forms that has demonstrated excellent leach resistance. The alloy can be used to encapsulate other metallic wastes that cannot be melted using the existing equipment design

  1. Induction melting for volume reduction of metallic TRU wastes

    International Nuclear Information System (INIS)

    Westsik, J.H. Jr.; Montgomery, D.R.; Katayama, Y.B.; Ross, W.A.

    1986-02-01

    Volume reduction of metallic transuranic wastes offers economic and safety incentives for treatment of wastes generated at a hypothetical commercial fuel reprocessing facility. Induction melting has been identified as the preferred process for volume reduction of spent fuel hulls, fuel assembly hardware, and failed equipment from a reprocessing plant. Bench-scale melting of Zircaloy and stainless steel mixtures has been successfully conducted in a graphite crucible inside a large vacuum chamber. A low-melting-temperature alloy forms that has demonstrated excellent leach resistance. The alloy can be used to encapsulate other metallic wastes that cannot be melted using the existing equipment design. 18 refs., 4 figs., 3 tabs

  2. Infrared thermography applied to monitoring of radioactive waste drums; Termografia infravermelha aplicada ao monitoramento de tambores de rejeitos radioativos

    Energy Technology Data Exchange (ETDEWEB)

    Kelmer, P.; Camarano, D.M. [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil); Calado, F.; Phillip, B.; Viana, C.; Andrade, R.M., E-mail: paulafuziki@yahoo.com.br, E-mail: flavio.arcalado@gmail.com, E-mail: bruno.phil@gmail.com, E-mail: criisviana@hotmail.com, E-mail: rma@ufmg.br, E-mail: dmc@cdtn.br [Universidade Federal de Minas Gerais (UFMG), Belo Horizonte, MG (Brazil). Departamento de Engenharia Eletrica

    2013-07-01

    The use of thermography in the inspection of drums containing radioactive waste is being stimulated by the absence of physical contact. In Brazil the majority of radioactive wastes are compacted solids packed in metal drums stored temporarily for decades and requires special attention. These drums have only one qualitative indication of the radionuclides present. However, its structural condition is not followed systematically. The aim of this work is presents a methodology by applying thermography for monitoring the structural condition of drums containing radioactive waste in order to detect degraded regions of the drums. (author)

  3. Demonstration of Entrained Solids and Sr/TRU Removal Processes with Archived AN-107 Waste

    International Nuclear Information System (INIS)

    Hallen, R.T.; Brooks, K.P.; Jagoda, L.K.

    2000-01-01

    Archived AN-107 waste was used to evaluate entrained solids removal, Sr/TRU decontamination of supernatant, and Sr/TRU solids removal. Even though most of the entrained solids had been previously removed from the archived sample, the residual entrained solids rapidly fouled the filter element resulting in very poor filter performance. An attempt to run at higher pressure resulted in more fouling, and reduced filter performance. Filtration efforts to remove entrained solids were abandoned and the waste was treated for Sr/TRU removal with the entrained solids present. The new processing scheme for Sr/TRU removal involving precipitation by added strontium and permanganate worked well. The decontamination factors for Sr and TRU components were significantly greater than the ILAW DF requirements for higher reagent concentrations of 1M hydroxide, 0.075M Sr, and 0.05M permanganate and lower reagent concentrations of 0.8M hydroxide, 0.05M Sr, and 0.03M permanganate. These results support the use of lower concentration of reagent additions in future tests. Optimization studies should be conducted to examine the reduction in added hydroxide from 1M to 0.5 M, reduction of Sr from 0.075M to 0.05M, and reduction in permanganate from 0.05M to 0.03M and the impact this reduction has on filtration performance with new samples from Tank AN-107. The combined entrained solids and Sr/TRU precipitate were successfully filtered in the single element, crossflow filtration unit. The filtrate flux was high, >0.1 gpm/ft 2 , at the initial test conditions of 53 psi and 11.2ft/s for the treated archived AN-107 sample. The filter flux rate dropped significantly with time as testing progressed and appears to be a result of shearing the agglomerated solids and fouling of the filter element by the resulting fine particles. The relatively low clean water flux rates obtained at the end of the test also indicate filter fouling. Chemical cleaning was required to restore clean water flux rates to pre

  4. Real-time radiography, digital radiography, and computed tomography for nonintrusive waste drum characterization

    International Nuclear Information System (INIS)

    Martz, H.E.; Schneberk, D.J.; Roberson, G.P.

    1994-07-01

    We are investigating and developing the application of x-ray nondestructive evaluation (NDE) and gamma-ray nondestructive assay (NDA) methods to nonintrusively characterize 208-liter (55-gallon) mixed waste drums. Mixed wastes contain both hazardous and radioactive materials. We are investigating the use of x-ray NDE methods to verify the content of documented waste drums and determine if they can be used to identify hazardous and nonconforming materials. These NDE methods are also being used to help waste certification and hazardous waste management personnel at LLNL to verify/confirm and/or determine the contents of waste. The gamma-ray NDA method is used to identify the intrinsic radioactive source(s) and to accurately quantify its strength. The NDA method may also be able to identify some hazardous materials such as heavy metals. Also, we are exploring techniques to combine both NDE and NDA data sets to yield the maximum information from these nonintrusive, waste-drum characterization methods. In this paper, we report an our x-ray NDE R ampersand D activities, while our gamma-ray NDA activities are reported elsewhere in the proceedings. We have developed a data, acquisition scanner for x-ray NDE real-time radiography (RTR), as well as digital radiography transmission computed tomography (TCT) along with associated computational techniques for image reconstruction, analysis, and display. We are using this scanner and real-waste drums at Lawrence Livermore National Laboratory (LLNL). In this paper, we discuss some issues associated with x-ray imaging, describe the design construction of an inexpensive NDE drum scanner, provide representative DR and TCT results of both mock- and real-waste drums, and end with a summary of our efforts and future directions. The results of these scans reveal that RTR, DR, and CT imaging techniques can be used in concert to provide valuable information about the interior of low-level-, transuranic-, and mock-waste drums without

  5. Long term stability of yttria-stabilized zirconia waste forms. Stability for secular change of partitioned TRU waste composition by disintegration

    International Nuclear Information System (INIS)

    Kuramoto, Ken-ichi; Banba, Tsunetaka; Mitamura, Hisayoshi; Sakai, Etsuro; Uno, Masayoshi; Kinoshita, H.; Yamanaka, Shinsuke

    1999-01-01

    In this study, the stability of YSZ waste forms for secular change of partitioned TRU waste composition by disintegration, one of important terms in long-term stability, is the special concern. Designed amount of waste and YSZ powder were mixed and sintered. These TRU waste forms were submitted to tests of phase stability, chemical durability, mechanical property and compactness. The results were compared with those of another YSZ waste forms, non-radioactive Ce and/or Nd doped YSZ samples, and glass and Synroc waste forms. Experimental results show following: (1) Phase stability of (Np+Am)-, (Np+U)-, and (Np+U+Bi)-doped YSZ waste forms could be maintained of that of the initial Np+Am-doped YSZ waste form permanently even when the composition of partitioned TRU waste were changed by disintegration. (2) Secular change also accelerated volume increase of YSZ waste forms as well as alpha-decay damage. (3) Hv, E and K IC of (Np+U)- and (Np+U+Bi)-doped YSZ waste forms were independent of the secular change of the partitioned TRU waste composition by disintegration. (4) Mechanical properties of YSZ waste forms were more than those of a glass and Synroc waste forms. (5) Compactness of YSZ waste forms was good as waste forms for the partitioned TRU wastes. (J.P.N.)

  6. Comparison of the leachability of three TRU cement waste forms

    International Nuclear Information System (INIS)

    Ross, W.A.; Westsik, J.H. Jr.; Roberts, F.P.; Harvey, C.O.

    1982-11-01

    Cement waste forms prepared by three processes, casting, cold pressing, and FUETAP (Formed Under Elevated Temperatures and Pressure) have been compared for their leachability by using the MCC-1 leach test. The results indicate that releases of plutonium are not controlled by the waste form matrix and that there is no significant overall advantage to any of the three cement processes from a leachability viewpoint

  7. Evaluation of alternatives for a second-generation transportation system for Department of Energy transuranic waste

    International Nuclear Information System (INIS)

    1984-01-01

    Department of Energy (DOE) waste storage sites will ship their contact-handled (CH) and remote-handled (RH) transuranic (TRU) waste to the Waste Isolation Pilot Plant (WIPP) beginning FY 1989. The CH-TRU waste will be shipped in the Transuranic Package Transported (TRUPACT-I), a new packaging being developed by Sandia National Laboratories, Albuquerque/Transportation Technology Center. Some of the DOE TRU waste, however, might be unsuitable for shipment in TRUPACT-I, and is designated special-shipped (SS) TRU waste. The purposes of this study were to: (1) identify the quantity and characteristics of SS-TRU waste stored and generated at DOE facilities; (2) identify alternatives for managing the SS-TRU waste; and (3) make overall recommendations for managing the SS-TRU waste. Data on quantity and characteristics were gathered through coordinating visits to the sites and extracting information from each site's records. Representatives of DOE organizations and contractors set objectives for managing the SS-TRU waste. Alternative shipping systems were then identified for CH SS-TRU waste and RH SS-TRU waste. Evaluations of these alternatives considered how well they would satisfy each objective, and associated potential problems. The study recommends delaying the decision on how best to transport the CH SS-TRU waste to WIPP until the amount of SS-TRU processed waste in heavy drums is known. These conditions and choices are presented: a relatively small number of processed, heavy drums could be shipped most economically via TRUPACT-I, mixed with lighter drums of unprocessed waste. If a large number of heavy drums is to be shipped, a shorter and narrower version of TRUPACT-I would be preferred alternative. The Defense High-Level Waste cask is the recommended alternative system for shipping RH SS-TRU waste. 12 references, 15 figures, 22 tables

  8. 40 CFR 264.316 - Disposal of small containers of hazardous waste in overpacked drums (lab packs).

    Science.gov (United States)

    2010-07-01

    ... HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES Landfills § 264.316 Disposal of small containers of hazardous waste in overpacked drums (lab packs). Small containers of hazardous waste in overpacked... hazardous waste in overpacked drums (lab packs). 264.316 Section 264.316 Protection of Environment...

  9. 40 CFR 265.316 - Disposal of small containers of hazardous waste in overpacked drums (lab packs).

    Science.gov (United States)

    2010-07-01

    ... OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES Landfills § 265.316 Disposal of small containers of hazardous waste in overpacked drums (lab packs). Small containers of hazardous waste... hazardous waste in overpacked drums (lab packs). 265.316 Section 265.316 Protection of Environment...

  10. Computed tomography of human joints and radioactive waste drums

    International Nuclear Information System (INIS)

    Martz, Harry E.; Roberson, G. Patrick; Hollerbach, Karin; Logan, Clinton M.; Ashby, Elaine; Bernardi, Richard

    1999-01-01

    X- and gamma-ray imaging techniques in nondestructive evaluation (NDE) and assay (NDA) have seen increasing use in an array of industrial, environmental, military, and medical applications. Much of this growth in recent years is attributed to the rapid development of computed tomography (CT) and the use of NDE throughout the life-cycle of a product. Two diverse examples of CT are discussed, 1.) Our computational approach to normal joint kinematics and prosthetic joint analysis offers an opportunity to evaluate and improve prosthetic human joint replacements before they are manufactured or surgically implanted. Computed tomography data from scanned joints are segmented, resulting in the identification of bone and other tissues of interest, with emphasis on the articular surfaces. 2.) We are developing NDE and NDA techniques to analyze closed waste drums accurately and quantitatively. Active and passive computed tomography (A and PCT) is a comprehensive and accurate gamma-ray NDA method that can identify all detectable radioisotopes present in a container and measure their radioactivity

  11. Identification of the fast and thermal neutron characteristics of transuranic waste drums

    Energy Technology Data Exchange (ETDEWEB)

    Storm, B.H. Jr.; Bramblett, R.L. [Lockheed Martin Specialty Components, Largo, FL (United States); Hensley, C. [Oak Ridge National Lab., TN (United States)

    1997-11-01

    Fissile and spontaneously fissioning material in transuranic waste drums can be most sensitively assayed using an active and passive neutron assay system such as the Active Passive Neutron Examination and Assay. Both the active and the passive assays are distorted by the presence of the waste matrix and containerization. For accurate assaying, this distortion must be characterized and accounted for. An External Matrix Probe technique has been developed that accomplishes this task. Correlations between in-drum neutron flux measurements and monitors in the Active Passive Neutron Examination and Assay chamber with various matrix materials provide a non-invasive means of predicting the thermal neutron flux in waste drums. Similarly, measures of the transmission of fast neutrons emitted from sources in the drum. Results obtained using the Lockheed Martin Specialty Components Active Passive Neutron Examination and Assay system are discussed. 12 figs., 1 tab.

  12. High temperature slagging incinerator for TRU-waste treatment

    International Nuclear Information System (INIS)

    Van De Voorde, N.; Hennart, D.; Gijbels, J.; Mergan, L.

    1984-01-01

    Since 1974 the Belgian Nuclear Study Center (SCK/CEN) at Mol, with the support of the European Communities, has developed an ''integral'' system for the treatment and the conditioning of radioactive contaminated wastes. The system converts directly, at high temperature (1500 0 C), mixtures of combustibles (paper, plastics, rubber etc.) and non-combustibles (metals, soil, sludge, concrete.) contaminated with transuranium elements as well as beta-gamma emitting isotopes, into a chemically inert and physically stable slag. More than 4000 hours of successful operation, with wide variety of simulated waste composition as well as real waste, have confirmed the safe operability of the high temperature sl'Gging incinerator and the connected installations, such as sorting cells, waste shredder, off-gas purification train, slag extraction system, remoted control, and the alpha-containment building. During the fall of 1983, a final confirmation of the performance of the installation was given by the successful accomplishment of an incineration campaign of 16 to 17 tons of simulated solid plutonium contaminated wastes

  13. Application of artificial neural networks on the characterization of radioactive waste drums

    International Nuclear Information System (INIS)

    Potiens Junior, Ademar Jose; Hiromoto, Goro

    2011-01-01

    The methodology consist of system simulation of drum-detector by Monte Carlo for obtention of counting efficiency. The obtained data were treated and a neural artificial network (RNA) were constructed for evaluation of total activity of drum. For method evaluation measurements were performed in ten position parallel to the drum axis and the results submitted to the RNA. The developed methodology showed to be effective for isotopic characterization of gamma emitter radioactive wastes distributed in a heterogeneous way in a 200 litters drum. The objective of this work as to develop a methodology of analyse for quantification and localization of radionuclides not homogeneous distributed in a 200 liters drum based on the mathematical techniques

  14. Position paper on flammability concerns associated with TRU waste destined for WIPP

    International Nuclear Information System (INIS)

    1991-04-01

    The Waste Isolation Pilot Plant (WIPP), in southeastern New Mexico,is an underground repository, designed for the safe geologic disposal of transuranic (TRU) wastes generated from defense-related activities of the US Department of Energy (DOE). The WIPP storage rooms are mined in a bedded salt (halite) formation, and are located 2150 feet below the surface. After the disposal of waste in the storage rooms, closure of the repository is expected to occur by creep (plastic flow) of the salt formation, with the waste being permanently isolated from the surrounding environment. This paper has evaluated the issue of flammability concerns associated with TRU waste to be shipped to WIPP, including a review of possible scenarios that can potentially contribute to the flammability. The paper discusses existing regulations that address potential flammability concerns, presents an analysis of previous flammability-related incidents at DOE sites with respect to the current regulations, and finally, examines the degree of assurance these regulations provide in safeguarding against flammability concerns during transportation and waste handling. 50 refs., 7 figs., 7 tabs

  15. Analysis of long-term impacts of TRU waste remaining at generator/storage sites for No Action Alternative 2

    International Nuclear Information System (INIS)

    Buck, J.W.; Bagaasen, L.M.; Bergeron, M.P.; Streile, G.P.

    1997-09-01

    This report is a supplement to the Waste Isolation Pilot Plant Disposal-Phase Final Supplemental Environmental Impact Statement (SEIS-II). Described herein are the underlying information, data, and assumptions used to estimate the long-term human-health impacts from exposure to radionuclides and hazardous chemicals in transuranic (TRU) waste remaining at major generator/storage sites after loss of institutional control under No Action Alternative 2. Under No Action Alternative 2, TRU wastes would not be emplaced at the Waste Isolation Pilot Plant (WIPP) but would remain at generator/storage sites in surface or near-surface storage. Waste generated at smaller sites would be consolidated at the major generator/storage sites. Current TRU waste management practices would continue, but newly generated waste would be treated to meet the WIPP waste acceptance criteria. For this alternative, institutional control was assumed to be lost 100 years after the end of the waste generation period, with exposure to radionuclides and hazardous chemicals in the TRU waste possible from direct intrusion and release to the surrounding environment. The potential human-health impacts from exposure to radionuclides and hazardous chemicals in TRU waste were analyzed for two different types of scenarios. Both analyses estimated site-specific, human-health impacts at seven major generator/storage sites: the Hanford Site (Hanford), Idaho National Engineering and Environmental Laboratory (INEEL), Lawrence Livermore National Laboratory (LLNL), Los Alamos National Laboratory (LANL), Oak Ridge National Laboratory (ORNL), Rocky Flats Environmental Technology Site (RFETS), and Savannah River Site (SRS). The analysis focused on these seven sites because 99 % of the estimated TRU waste volume and inventory would remain there under the assumptions of No Action Alternative 2

  16. Unresolved issues for the disposal of remote-handled transuranic waste in the Waste Isolation Pilot Plant

    International Nuclear Information System (INIS)

    Silva, M.K.; Neill, R.H.

    1994-09-01

    The purpose of the Waste Isolation Pilot Plant (WIPP) is to dispose of 176,000 cubic meters of transuranic (TRU) waste generated by the defense activities of the US Government. The envisioned inventory contains approximately 6 million cubic feet of contact-handled transuranic (CH TRU) waste and 250,000 cubic feet of remote handled transuranic (RH TRU) waste. CH TRU emits less than 0.2 rem/hr at the container surface. Of the 250,000 cubic feet of RH TRU waste, 5% by volume can emit up to 1,000 rem/hr at the container surface. The remainder of RH TRU waste must emit less than 100 rem/hr. These are major unresolved problems with the intended disposal of RH TRU waste in the WIPP. (1) The WIPP design requires the canisters of RH TRU waste to be emplaced in the walls (ribs) of each repository room. Each room will then be filled with drums of CH TRU waste. However, the RH TRU waste will not be available for shipment and disposal until after several rooms have already been filled with drums of CH TRU waste. RH TRU disposal capacity will be loss for each room that is first filled with CH TRU waste. (2) Complete RH TRU waste characterization data will not be available for performance assessment because the facilities needed for waste handling, waste treatment, waste packaging, and waste characterization do not yet exist. (3) The DOE does not have a transportation cask for RH TRU waste certified by the US Nuclear Regulatory Commission (NRC). These issues are discussed along with possible solutions and consequences from these solutions. 46 refs

  17. Hanford contact-handled transuranic drum retrieval project planning document

    International Nuclear Information System (INIS)

    DEMITER, J.A.

    1998-01-01

    The Hanford Site is one of several US Department of Energy (DOE) sites throughout the US that has generated and stored transuranic (TRU) wastes. The wastes were primarily placed in 55-gallon drums, stacked in trenches, and covered with soil. In 1970, the Nuclear Regulatory Commission ordered that TRU wastes be segregated from other radioactive wastes and placed in retrievable storage until such time that the waste could be sent to a geologic repository and permanently disposed. Retrievable storage also defined container storage life by specifying that a container must be retrievable as a contamination-free container for 20 years. Hanford stored approximately 37,400 TRU containers in 20-year retrievable storage from 1970 to 1988. The Hanford TRU wastes placed in 20-year retrievable storage are considered disposed under existing Resource Conservation and Recovery Act (RCRA) regulations since they were placed in storage prior to September 1988. The majority of containers were 55-gallon drums, but 20-year retrievable storage includes several TRU wastes covered with soil in different storage methods

  18. Artificial neural networks in the evaluation of the radioactive waste drums activity

    International Nuclear Information System (INIS)

    Potiens, J.R.A.J.; Hiromoto, G.

    2006-01-01

    The mathematical techniques are becoming more important to solve geometry and standard identification problems. The gamma spectrometry of radioactive waste drums would be a complex solution problem. The main difficulty is the detectors calibration for this geometry; the waste is not homogeneously distributed inside the drums, therefore there are many possible combinations between the activity and the position of these radionuclides inside the drums, making the preparation of calibration standards impracticable. This work describes the development of a methodology to estimate the activity of a 200 L radioactive waste drum, as well as a mapping of the waste distribution, using Artificial Neural Network. The neural network data set entry obtaining was based on the possible detection efficiency combination with 10 sources activities varying from 0 to 74 x 10 3 Bq. The set up consists of a 200 L drum divided in 5 layers. Ten detectors were positioned all the way through a parallel line to the drum axis, from 15 cm of its surface. The Cesium -137 radionuclide source was used. The 50 efficiency obtained values (10 detectors and 5 layers), combined with the 10 source intensities resulted in a 100,000 lines for 15 columns matrix, with all the possible combinations of source intensity and the Cs-137 position in the 5 layers of the drum. This archive was divided in 2 parts to compose the set of training: input and target files. The MatLab 7.0 module of neural networks was used for training. The net architecture has 10 neurons in the input layer, 18 in the hidden layer and 5 in the output layer. The training algorithm was the 'traincgb' and after 300 'epoch s' the medium square error was 0.00108172. This methodology allows knowing the detection positions answers in a heterogeneous distribution of radionuclides inside a 200 L waste drum; in consequence it is possible to estimate the total activity of the drum in the training neural network limits. The results accuracy depends

  19. Comparative assessment of disposal of TRU waste in a greater-confinement disposal facility

    International Nuclear Information System (INIS)

    Cohn, J.J.; Smith, C.F.; Ciminesi, F.J.; Dickman, P.T.; O'Neal, D.A.

    1982-11-01

    This study reviewed previous work that established generic limits for shallow land burial of TRU contaminated wastes and extended previous methodology to estimate approximate appropriate burial limits for TRU wastes in an arid zone greater confinement disposal facility (GCDF). An erosion scenario provided the limiting pathway in the previous determination of generic shallow land burial limits. Erosion removed the cover soil, exposing the waste mass to habitation and agriculture. For the deep burial concept (that is, burial at a depth greater than 10 m [33 ft]), the aquifer transport scenario was controlling. In both cases, the assumed site conditions were characteristic of a humid zone in which groundwater flows immediately below the waste deposit. In deriving limits for an arid site GCDF, either the erosion/reclaimer or the aquifer transport scenario could provide the controlling pathway, depending on the nuclide and the assumed burial depth. The derived limits were higher for the arid sited GCDF than those of the generic humid study. The physical processes that increase limits relative to the generic study include increased time during which radioactive decay occurs prior to release and increased dilution. Some nuclides were effectively unlimited in an arid zone GCDF, while others (notably Pu-239) were affected on a much smaller scale, primarily due to very long half-lives. As a final comment, the limit values derived in this report represent adjustments to the calculations of the Healy and Rodgers report (LA-UR-79-100). Those original calculations were very conservative, utilizing a worst case approach, but nevertheless involving significant levels of uncertainty in key assumptions. Consequently, the results are assumption dependent. Other approaches to such an analysis could, and should be used to develop site specific concentration limits for TRU wastes

  20. System to control contamination during retrieval of buried TRU waste

    Science.gov (United States)

    Menkhaus, Daniel E.; Loomis, Guy G.; Mullen, Carlan K.; Scott, Donald W.; Feldman, Edgar M.; Meyer, Leroy C.

    1993-01-01

    A system to control contamination during the retrieval of hazardous waste comprising an outer containment building, an inner containment building, within the outer containment building, an electrostatic radioactive particle recovery unit connected to and in communication with the inner and outer containment buildings, and a contaminate suppression system including a moisture control subsystem, and a rapid monitoring system having the ability to monitor conditions in the inner and outer containment buildings.

  1. Considerations for an active and passive scanner to assay nuclear waste drums

    International Nuclear Information System (INIS)

    Martz, H.E.; Azevedo, S.G.; Roberson, G.P.; Schneberk, D.J.; Koenig, Z.M.; Camp, D.C.

    1990-01-01

    Radioactive wastes are generated at many DOE laboratories, military facilities, fuel fabrication and enrichment plants, reactors, hospitals, and university research facilities. At all of these sites, wastes must be separated, packaged, categorized, and packed into some sort of container--usually 208-L (55-gal) drums--for shipment to waste-storage sites. Prior to shipment, the containers must be labeled, assayed, and certified; the assay value determines the ultimate disposition of the waste containers. An accurate nondestructive assay (NDA) method would identify all the radioisotopes present and provide a quantitative measurement of their activity in the drum. In this way, waste containers could be routed in the most cost-effective manner and without having to reopen them. Currently, the most common gamma-ray method used to assay nuclear waste drums is segmented gamma-ray scanning (SGS) spectrometer that crudely measures only the amount of 235 U or 239 Pu present in the drum. This method uses a spatially-averaged, integrated, emitted gamma-ray-intensity value. The emitted intensity value is corrected by an assumed constant-attenuation value determined by a spatially-averaged, transmission (or active) measurement. Unfortunately, this typically results in an inaccurate determination of the radioactive activities within a waste drum because this measurement technique is valid only for homogeneous-attenuation or known drum matrices. However, since homogeneous-attenuation matrices are not common and may be unknown, other NDA techniques based on active and Passive CT (A ampersand PCT) are under development. The active measurement (ACT) yields a better attenuation matrix for the drum, while the passive measurement (PCT) more accurately determines the identity of the radioisotopes present and their activities. 9 refs., 2 figs

  2. Documentation of acceptable knowledge for Los Alamos National Laboratory Plutonium Facility TRU waste stream

    International Nuclear Information System (INIS)

    Montoya, A.J.; Gruetzmacher, K.M.; Foxx, C.L.; Rogers, P.Z.

    1998-03-01

    Characterization of transuranic waste from the LANL Plutonium Facility for certification and transportation to WIPP includes the use of acceptable knowledge as specified in the WIPP Quality Assurance Program Plan. In accordance with a site specific procedure, documentation of acceptable knowledge for retrievably stored and currently generated transuranic waste streams is in progress at LANL. A summary overview of the TRU waste inventory is complete and documented in the Sampling Plan. This document also includes projected waste generation, facility missions, waste generation processes, flow diagrams, times, and material inputs. The second part of acceptable knowledge documentation consists of assembling more detailed acceptable knowledge information into auditable records and is expected to require several years to complete. These records for each waste stream must support final assignment of waste matrix parameters, EPA hazardous waste numbers, and radionuclide characterization. They must also include a determination whether waste streams are defense waste streams for compliance with the WIPP Land Withdrawal Act. The LANL Plutonium Facility's mission is primarily plutonium processing in basic special nuclear material (SNM) research activities to support national defense and energy programs. It currently has about 100 processes ranging from SNM recovery from residues to development of plutonium 238 heat sources for space applications. Its challenge is to characterize and certify waste streams from such diverse and dynamic operations using acceptable knowledge. This paper reports the progress on the certification of the first of these waste streams to the WIPP WAC

  3. Complexant Identification in Hanford Waste Simulant Sr/TRU Filtrate

    International Nuclear Information System (INIS)

    Bannochie, C.J.

    2003-01-01

    This project was designed to characterize the available multidentate ligand species and metal ion complexes of iron, strontium and manganese formed with the parent chelators, complexing agents and their fragment products. Complex identification was applied to AN-102 and AN-107 filtrate simulants for Hanford waste after an oxidation reaction with sodium permanganate to create a freshly precipitated manganese dioxide solid for adsorption of transuranic elements. Separation efficiency of different ligands was investigated based on the exchange capability of different ion exchange and ion exclusion analytical columns including Dionex IonPac AS-5A, AS-10, AS-11 and AS-6. The elution programs developed with different mobile phase concentrations were based on the change in the effective charge of the anionic species and therefore the retention on the stationary phase. In the present work, qualitative and quantitative assessments of multidentate ligands were investigated. Identification methods for the metal ion complexes responsible for solubilizing Fe, Mn and Sr were applied to aged and fresh simulant waste filtrates. Although concentration measurements of both fresh and 3-week aged filtrates showed that the degradation process occurs mainly due to the harsh chemical environment, it was found that the concentration of iron and manganese did not increase, within the error of the analytical measurements, after three weeks when compared with fresh filtrate

  4. TRUEX process: a new dimension in management of liquid TRU wastes

    International Nuclear Information System (INIS)

    Schulz, W.W.; Horwitz, E.P.

    1986-01-01

    The TRUEX process is one of the, if not the, most exciting and potentially useful nuclear separations processes to be developed since the PUREX process was developed and applied in the 1950s. Attesting to its potential widespread use, Rockwell Hanford and ANL investigators, in a joint effort, are developing and testing TRUEX process flow sheets for removal of TRU elements from several Hanford Site wastes including the Plutonium Finishing Plant and complexed concentrate wastes. The TRUEX process also appears to be well suited to removal of plutonium and Am from aqueous chloride wastes generated during plutonium processing operations at the Los Alamos National Lab. (LANL); collaborative efforts between LANL and ANL scientists to develop and demonstrate TRUEX process flow sheets for treatment of LANL site chloride wastes are currently under way

  5. Corrosion of steel drums containing simulated radioactive waste of low and intermediate level

    International Nuclear Information System (INIS)

    Farina, S.B.; Schulz Rodríguez, F.; Duffó, G.S.

    2013-01-01

    Ion-exchange resins are frequently used during the operation of nuclear power plants and constitute radioactive waste of low and intermediate level. For the final disposal inside the repository the resins are immobilized by cementation and placed inside steel drums. The eventful contamination of the resins with aggressive species may cause corrosion problems to the drums. In order to assess the incidence of this phenomenon and to estimate the lifespan of the steel drums, in the present work, the corrosion susceptibility of steel drums in contact with cemented ion-exchange resins contaminated with different aggressive species was studied. The aggressive species studied were chloride ions (main ionic species of concern) and sulphate ions (produced during radiolysis of the cationic exchange-resins after cementation). The corrosion rate of the steel was monitored over a time period of 900 days and a chemical and morphological analysis of the corrosion products formed on the steel in each condition was performed. When applying the results obtained in the present work to estimate the corrosion depth of the drums containing the cemented radioactive waste after a period of 300 years (foreseen durability of the Low and Intermediate Level Radioactive Waste facility in Argentina), it was found that in the most unfavourable case (high chloride contamination), the corrosion penetration will be considerably lower than the thickness of the wall of the steel drums. (author)

  6. Application of insoluble tannin to recovery of uranium, TRU and heavy metals elements form radioactive liquid waste

    International Nuclear Information System (INIS)

    Hamaguchi, Kazuhiko; Shirato, Wataru; Nakamura, Yasuo; Matsumura, Tatsuro; Takeshita, Kenji; Nakano, Yoshio

    1999-01-01

    Mitsubishi Nuclear Fuel Co., Ltd. (MNF) has developed a new adsorbent, TANNIX (tread mark), for the recovery of uranium, TRU and heavy metal elements in the liquid waste, in which TANNIX derived from a natural tannin polymer. TANNIX has same advantages that handling is easier than that of standard IX-resin, and that the volume of secondary waste is reduced by burning the used TANNIX. We have replaced its radioactive liquid waste treatment system from the conventional co-precipitation process to adsorption process by using TANNIX. TANNIX was founded to be more effective for the recovery of Pu, TRU, and hexavalent chromium Cr-(VI) as well as Uranium. (author)

  7. A preliminary evaluation of certain NDA techniques for RH-TRU characterization

    Energy Technology Data Exchange (ETDEWEB)

    Hartwell, J.K.; Yoon, W.Y.; Peterson, H.K. [Idaho National Engineering Lab., Idaho Falls, ID (United States)

    1997-11-01

    This report presents the results of modeling efforts to evaluate selected NDA assay methods for RH-TRU waste characterization. The target waste stream was Content Code 104/107 113-liter waste drums that comprise the majority of the INEL`s RH-TRU waste inventory. Two NDA techniques are treated in detail. One primary NDA technique examined is gamma-ray spectrometry to determine the drum fission and activation product content, and fuel sample inventory calculations using the ORIGEN code to predict the total drum inventory. A heavily shielded and strongly collimated HPGe spectrometer system was designed using MCNP modeling. Detection limits and expected precision of this approach were estimated by a combination of Monte Carlo modeling and synthetic gamma-ray spectrum generation. This technique may allow the radionuclide content of these wastes to be determined with relative standard deviations of 20 to 50% depending on the drum matrix and radionuclide. The INEL Passive/Active Neutron (PAN) assay system is the second primary technique considered. A shielded overpack for the 113-liter CC104/107 RH-TRU drums was designed to shield the PAN detectors from excessive gamma radiation. MCNP modeling suggests PAN detection limits of about 0.06 g {sup 235}U and 0.04 g {sup 239}Pu during active assays. 12 refs., 2 figs., 6 tabs.

  8. Application of the Monte Carlo method to estimate doses in a radioactive waste drum environment

    International Nuclear Information System (INIS)

    Rodenas, J.; Garcia, T.; Burgos, M.C.; Felipe, A.; Sanchez-Mayoral, M.L.

    2002-01-01

    During refuelling operation in a Nuclear Power Plant, filtration is used to remove non-soluble radionuclides contained in the water from reactor pool. Filter cartridges accumulate a high radioactivity, so that they are usually placed into a drum. When the operation ends up, the drum is filled with concrete and stored along with other drums containing radioactive wastes. Operators working in the refuelling plant near these radwaste drums can receive high dose rates. Therefore, it is convenient to estimate those doses to prevent risks in order to apply ALARA criterion for dose reduction to workers. The Monte Carlo method has been applied, using MCNP 4B code, to simulate the drum containing contaminated filters and estimate doses produced in the drum environment. In the paper, an analysis of the results obtained with the MCNP code has been performed. Thus, the influence on the evaluated doses of distance from drum and interposed shielding barriers has been studied. The source term has also been analysed to check the importance of the isotope composition. Two different geometric models have been considered in order to simplify calculations. Results have been compared with dose measurements in plant in order to validate the calculation procedure. This work has been developed at the Nuclear Engineering Department of the Polytechnic University of Valencia in collaboration with IBERINCO in the frame of an RD project sponsored by IBERINCO

  9. High-sensitivity measurements for low-level TRU wastes using advanced passive neutron techniques

    International Nuclear Information System (INIS)

    Menlove, H.O.; Eccleston, G.W.

    1992-01-01

    In recent years, both passive- and active-neutron nondestructive assay (NDA) systems have been used to measure the uranium and plutonium content in 200-ell drums. Because of the heterogeneity of the wastes, representative sampling is not possible and NDA methods are preferred over destructive analysis. Active-neutron assay systems are used to measure the fissile isotopes such as 235 U, 23 Pu, and 241 Pu; the isotopic ratios are used to infer the total plutonium content and thus the specific disintegration rate. The active systems include 14-MeV-neutron (DT) generators with delayed-neutron counting, (D,T) generators with the differential die-away technique, and 252 Cf delayed-neutron shufflers. Passive assay systems (for example, segmented gamma-ray scanners)5 have used gamma-ray sessions, while others (for example, passive drum counters) used passive-neutron signals. We have developed a new passive-neutron measurement technique to improve the accuracy and sensitivity of the NDA of plutonium scrap and waste. This new 200-ell-drum assay system combines the classical NDA method of counting passive-neutron totals and coincidences from plutonium with the new features of ''add-a-source'' (AS) and multiplicity counting to improve the accuracy of matrix corrections and statistical techniques that improve the low-level detectability limits. This paper describes the improvements we have made in passive-neutron assay systems and compares the accuracies and detectability limits of passive- and active-neutron assay systems

  10. Maximizing DOE R and D efforts in tru waste management learning from international programs

    International Nuclear Information System (INIS)

    Saxman, P.A.; Loughead, J.S.C.

    1990-01-01

    Through the International Technology Exchange Program, Department of Energy (DOE) technical specialists maintain a formal dialogue with research and Development (R and D) specialists from nuclear programs in other countries. The objective of these exchanges is to seek innovative waste management solutions, maximize progress for ongoing R and D activities, and minimize the development time required for implementation of transuranic (TRU) waste processing technologies and waste assay developments. Based on information provided by PNC during the exchange, DOE specialists evaluated PNC's efforts to implement technologies and techniques from their R and D program activities. This paper presents several projects with particular potential for DOE operations, and suggests several ways that these concepts could be used to advantage by DOE or commercial programs

  11. Analytical and empirical evaluation of low-level waste drum response to accident environments

    International Nuclear Information System (INIS)

    May, R.A.; Romesberg, L.E.; Yoshimura, H.R.; Baker, W.E.; Hokanson, J.C.

    1980-01-01

    Based on results of tests to date, it was found that the structural response of low-level waste drums to impact environments can be generally predicted, both analytically and with subscale models. As currently represented, only the 1/4 scale models would adequately represent full scale drum deformation; however, additional work has shown that with proper heat treating the strength of the material used in the 1/8 scale containers can be reduced to the correct value. Both analytical models give results that are expected to be within the range of behavior of the full scale drums. Failure of the drum closure can be adequately inferred from the radial deformation results of both subscale tests and computer analyses. 6 figures

  12. A prototype of radioactive waste drum monitor by non-destructive assays using gamma spectrometry

    International Nuclear Information System (INIS)

    Thanh, Tran Thien; Trang, Hoang Thi Kieu; Chuong, Huynh Dinh; Nguyen, Vo Hoang; Tran, Le Bao; Tam, Hoang Duc; Tao, Chau Van

    2016-01-01

    In this work, segmented gamma scanning and the gamma emission tomography were used to locate unknown sources in a radioactive waste drum. The simulated detector response function and full energy peak efficiency are compared to corresponding experimental data and show about 5.3% difference for an energy ranging from 81 keV to 1332.5 keV for point sources. Computation of the corresponding activity is in good agreement with the true values. - Highlights: • Segmented gamma scanning and gamma emission tomography are used to locate point source in waste drums. • The PENELOPE software is used to compute the detection efficiency of the localized point source in the waste drum. • The activity of "1"3"7Cs and "6"0Co point source could be determined with an accuracy better than 10% for air and sand matrices.

  13. Final Environmental Impact Statement for Treating Transuranic (TRU)/Alpha Low-level Waste at the Oak Ridge National Laboratory Oak Ridge, Tennessee

    Energy Technology Data Exchange (ETDEWEB)

    N/A

    2000-06-30

    The DOE proposes to construct, operate, and decontaminate/decommission a TRU Waste Treatment Facility in Oak Ridge, Tennessee. The four waste types that would be treated at the proposed facility would be remote-handled TRU mixed waste sludge, liquid low-level waste associated with the sludge, contact-handled TRU/alpha low-level waste solids, and remote-handled TRU/alpha low-level waste solids. The mixed waste sludge and some of the solid waste contain metals regulated under the Resource Conservation and Recovery Act and may be classified as mixed waste. This document analyzes the potential environmental impacts associated with five alternatives--No Action, the Low-Temperature Drying Alternative (Preferred Alternative), the Vitrification Alternative, the Cementation Alternative, and the Treatment and Waste Storage at Oak Ridge National Laboratory (ORNL) Alternative.

  14. In-situ stabilization of TRU/mixed waste project at the INEEL

    International Nuclear Information System (INIS)

    Milian, L.W.; Heiser, J.H.; Adams, J.W.; Rutenkroeger, S.P.

    1997-08-01

    Throughout the DOE complex, buried waste poses a threat to the environment by means of contaminant transport. Many of the sites contain buried waste that is untreated, prior to disposal, or insufficiently treated, by today's standards. One option to remedy these disposal problems is to stabilize the waste in situ. This project was in support of the Transuranic/Mixed Buried Waste - Arid Soils product line of the Landfill Focus Area, which is managed currently by the Idaho National Engineering Laboratory (BNL) provided the analytical laboratory and technical support for the various stabilization activities that will be performed as part of the In Situ Stabilization of TRU/Mixed Waste project at the INEL. More specifically, BNL was involved in laboratory testing that included the evaluation of several grouting materials and their compatibility, interaction, and long-term durability/performance, following the encapsulation of various waste materials. The four grouting materials chosen by INEL were: TECT 1, a two component, high density cementious grout, WAXFIX, a two component, molten wax product, Carbray 100, a two component elastomeric epoxy, and phosphate cement, a two component ceramic. A simulated waste stream comprised of sodium nitrate, Canola oil, and INEL soil was used in this study. Seven performance and durability tests were conducted on grout/waste specimens: compressive strength, wet-dry cycling, thermal analysis, base immersion, solvent immersion, hydraulic conductivity, and accelerated leach testing

  15. Development of techniques for measuring plutonium contents in TRU wastes by NDA methods

    International Nuclear Information System (INIS)

    Matsubayashi, Toshiyuki; Kuwana, Katsumi; Morita, Tomio; Izuhara, Shigeomi; Suzuki, Masahiro

    1983-01-01

    In order to develop a technique for measuring the amount of plutonium in plutonium-contaminated (TRU) wastes, a passive gamma method was selected from many candidate methods, and examined for the suitability by applying the method to low density wastes. A segmented gamma scanner was used for the experiment. The instrument is composed mainly of a Ge(Li) detector, multichannel analyser, data processing system, turntable and transmission radiation source of (75)Se. A sham waste was prepared by adding plutonium oxide powder as a radiation source to waste matrix in a 20-1 carton box. The sham waste was put on the turntable, and the detector was set at 50 cm distance from the center of the turntable. 414 keV gamma ray emitted from (239)Pu was utilized for the assay of plutonium in the experiment. The effects of combustible (paper) waste matrix, organic chlorinated material matrix, and the distribution of plutonium source in a box on the count rate were examined, and it was concluded that 1) about 10 mg of (239)Pu contained in both matrices should be assayed by the passive gamma method, 2) 50 mg of (239) Pu was measured at 30 % confidence level with 2000 sec measuring time, 3) the effect of distribution of plutonium in a waste was able to be reduced to a value of less than 15 % by rotating the waste on the turntable. (Yoshitake, I.)

  16. TRU waste cyclone drum incinerator and treatment system: January--March 1978

    International Nuclear Information System (INIS)

    Klingler, L.M.; Batchelder, D.M.; Lewis, E.L.

    1978-01-01

    The cyclone incinerator was operated throughout the past quarter, generating additional data on system characteristics, equipment life expectancies, and by-product generation. Several changes in the incinerator system are in various stages of completion. The lid assembly, secondary chamber, and expansion unit for the new exhaust equipment are nearly ready for installation. A new heat exchanger has been installed in the scrubber system. An ash handling system has been designed for possible future addition to the system. Continuing studies will determine the best delivery mechanism for continuously feeding the cyclone incinerator. Preliminary investigations are being conducted to select an independent system to treat incinerator scrubber solution for recycling and to remove salts and sludge for disposal. Metal samples of two possible materials for incinerator construction were examined for corrosion degradation suffered at the incinerator exhaust outlet. Controlled experiments were conducted on the pressed ash-cement pellet matrix to define compressive strength, mechanical stability, density, and effect of curing environment (wet cure and dry cure). Leachability studies were initiated on pressed sludge/cement matrix in distilled water at ambient temperature. Compressive strengths of sludge/cement pressed matrix samples were investigated. Physical and chemical attributes of incinerated ash were evaluated in relationship to the ash/cement matrix

  17. Assessment of the Mechanisms for Sr-90 and TRU Removal from Complexant-Containing Tank Wastes at Hanford

    International Nuclear Information System (INIS)

    Hallen, Richard T.; Geeting, John GH; Lilga, Michael A.; Hart, Todd R.; Hoopes, Francis V.

    2005-01-01

    Small-scale tests (∼20 mL) were conducted with samples from Hanford underground storage tanks AN-102 and AN-107 to assess the mechanisms for removing Sr-90 and transuranics (TRU) from the liquid (supernatant) portion of the waste. The Sr-90 and TRU must be removed (decontaminated), in addition to Cs-137 and the entrained solids, before the supernatant can be disposed of as low-activity waste. Experiments were conducted with various reagents and modified Sr/TRU removal process conditions to more fully understand the reaction mechanisms. The optimized treatment conditions--no added hydroxide, addition of Sr (0.02M target concentration) followed by sodium permanganate (0.02M target concentration) with mixing at ambient temperature--were used as a reference for comparison. The waste was initially two orders of magnitude undersaturated with Sr; the addition of nonradioactive Sr(NO?) ? saturated the supernatant, resulting in isotopic dilution and precipitation of Sr-90 as SrCO?. The reaction chemistry of Mn species relevant to the mechanism of TRU removal by permanganate treatment was evaluated, along with the importance of various mechanisms for decontamination, such as precipitation, absorption, ligand exchange, and oxidation of organic complexants. For TRU removal, permanganate addition generally gave the highest DF. The addition of Mn of lower oxidation states (II, IV, and VI) also resulted in good TRU removal, as did complexant oxidation with periodate and addition of Zr(IV) for ligand exchange. These results suggest that permanganate treatment leads to TRU removal by multiple routes

  18. Radiological analyses of intermediate and low level supercompacted waste drums by VQAD code

    International Nuclear Information System (INIS)

    Bace, M.; Trontl, K.; Gergeta, K.

    2004-01-01

    In order to increase the possibilities of the QAD-CGGP code, as well as to make the code more user friendly, modifications of the code have been performed. A general multisource option has been introduced into the code and a user friendly environment has been created through a Graphical User Interface. The improved version of the code has been used to calculate gamma dose rates of a single supercompacted waste drum and a pair of supercompacted waste drums. The results of the calculation were compared with the standard QAD-CGGP results. (author)

  19. Detection of free liquid in cement-solidified radioactive waste drums using computed tomography

    International Nuclear Information System (INIS)

    Steude, J.S.; Tonner, P.D.

    1991-01-01

    Acceptance criteria for disposal of radioactive waste drums require that the cement-solidified material in the drum contain minimal free liquid after the cement has hardened. Free liquid is to be avoided because it may corrode the drum, escape and cause environmental contamination. The DOE has requested that a nondestructive evaluation method be developed to detect free liquid in quantities in excess of 0.5% by volume. This corresponds to about 1 liter in a standard 208 liter (55 gallon) drum. In this study, the detection of volumes of free liquid in a 57 cm (2 ft.) diameter cement-solidified drum is demonstrated using high-energy X-ray computed tomography (CT0. In this paper it is shown that liquid concentrations of simulated radioactive waste inside glass tubes imbedded in cement can easily be detected, even for tubes with inner diameters less than 2 mm (0.08 in.). Furthermore, it is demonstrated that tubes containing water and liquid concentrations of simulated radioactive waste can be distinguished from tubes of the same size containing air. The CT images were obtained at a rate of about 6 minutes per slice on a commercially available CT system using a 9 MeV linear accelerator source

  20. Reconstruction of the isotope activity content of heterogeneous nuclear waste drums.

    Science.gov (United States)

    Krings, Thomas; Mauerhofer, Eric

    2012-07-01

    Radioactive waste must be characterized in order to verify its conformance with national regulations for intermediate storage or its disposal. Segmented gamma scanning (SGS) is a most widely applied non-destructive analytical technique for the characterization of radioactive waste drums. The isotope specific activity content is generally calculated assuming a homogeneous matrix and activity distribution for each measured drum segment. However, real radioactive waste drums exhibit non-uniform isotope and density distributions most affecting the reliability and accuracy of activities reconstruction in SGS. The presence of internal shielding structures in the waste drum contributes generally to a strong underestimation of the activity and this in particular for radioactive sources emitting low energy gamma-rays independently of their spatial distribution. In this work we present an improved method to quantify the activity of spatially concentrated gamma-emitting isotopes (point sources or hot spots) in heterogeneous waste drums with internal shielding structures. The isotope activity is reconstructed by numerical simulations and fits of the angular dependent count rate distribution recorded during the drum rotation in SGS using an analytical expression derived from a geometric model. First results of the improved method and enhancements of this method are shown and are compared to each other as well as to the conventional method which assumes a homogeneous matrix and activity distribution. It is shown that the new model improves the accuracy and the reliability of the activity reconstruction in SGS and that the presented algorithm is suitable with respect to the framework requirement of industrial application. Copyright © 2011 Elsevier Ltd. All rights reserved.

  1. Equipment for capping drums, especially with radioactive waste

    International Nuclear Information System (INIS)

    Bednarik, F.

    1987-01-01

    The equipment consists of a pneumatic cylinder, lever systems with jaws, guide bars, and of securing pins. The top cylinder lid and the bottom cylinder lid provided with openings are slidably attached to a shaft firmly connected to a piston and a support plate. Firmly attached to the bottom lid using brackets are pins holding connecting rods controlling the double-arm levers pivoted on pins, featuring jaws pivoted on forks firmly attached to the support plate and provided with a replaceable spacer insert. The guide bars are firmly attached to the support plate via braces and stiffeners. The securing pins are loaded with springs seated in the braces. The benefits of the equipment include that the lid closing levers with jaws, mechanically controlled using one pneumatic cylinder, thanks to their number and configuration, close the lid around the drum border provided with small recesses which do not reach above the circumference of the drum being closed. The equipment can also be used for carrying closed drums, this also during compressed air failures because the levers with jaws are secured in position with the pneumatic cylinder leg. (J.B.). 1 fig

  2. Criticality safety study of Pu contaminated carbon waste stored in 100 L steel drums

    International Nuclear Information System (INIS)

    Anno, J.; Simonneau, M.

    1995-01-01

    The notion of the minimum critical areal density (D minca ) used to ensure the Criticality-Safety of poor solid waste is recalled with its deficiencies. D minca is assumed constant, independent of the fissile material concentration. This assumption is only true for unreflected mediums. Corrective factors are established. Furthermore, the usual norm of the Pu-H 2 O, which is 0.20 g/cm 2 , (concrete reflected) is greater than that for other mediums, such as Pu contaminated graphite waste (Pu-C), which is 0.036 g/cm 2 . D minca calculated on infinite slabs is confirmed by calculations on infinite planar multilayers arrays of 100 l cubical waste drums. Moreover, d minca increases linearly with the steel thickness of the drums' walls and goes up to 0.17 g/cm 2 for 0.105 cm of steel. The safety analysis on a real storage case takes into account the limited amount of Pu (100 g) and C (100 kg), the minimum thickness of 0.07 cm of drums' steel, their geometrical arrangement, the heterogeneity and size of contamination and the occurrence of neutronic poison (N and Cl) in the waste. Because of these parameters, the Keff are very less than 0.95 and the taken norm of 0.1 g/cm 2 for the Pu-C waste is fulfilled. Finally, it is demonstrated that the mixing of Pu-C waste drums and Pu-H 2 O wastes drums is allowed. (authors). 14 refs., 5 figs., 6 tabs

  3. Development of an integrated facility for processing TRU solid wastes at the Savannah River Plant

    International Nuclear Information System (INIS)

    Boersma, M.D.; Hootman, H.E.; Permar, P.H.

    1977-01-01

    An integrated facility is being designed for processing solid wastes contaminated with long-lived alpha emitting (TRU) nuclides; this waste has been stored retrievably at the Savannah River Plant since 1965. The stored waste, having a volume of 10 4 m 3 and containing 3 x 10 5 Ci of transuranics, consists of both mixed combustible trash and failed and obsolete equipment primarily from transuranic production and associated laboratory operations. The facility for processing solid transuranic waste will consist of five processing modules: (1) unpackaging, sorting, and assaying; (2) treatment of combustibles by controlled air incineration; (3) size reduction of noncombustibles by plasma-arc cutting followed by decontamination by electropolishing; (4) fixation of the processed waste in cement; and (5) packaging for shipment to a federal repository. The facility is projected for construction in the mid-1980's. Pilot facilities, sized to manage currently generated wastes, will also demonstrate the key process steps of incineration of combustibles and size reduction/decontamination of noncombustibles; these facilities are projected for 1980-81. Development programs leading to these extensive new facilities are described

  4. Transuranic Waste Processing Center (TWPC) Legacy Tank RH-TRU Sludge Processing and Compliance Strategy - 13255

    Energy Technology Data Exchange (ETDEWEB)

    Rogers, Ben C.; Heacker, Fred K.; Shannon, Christopher [Wastren Advantage, Inc., Transuranic Waste Processing Center, 100 WIPP Road, Lenoir City, Tennessee 37771 (United States); and others

    2013-07-01

    The U.S. Department of Energy (DOE) needs to safely and efficiently treat its 'legacy' transuranic (TRU) waste and mixed low-level waste (LLW) from past research and defense activities at the Oak Ridge National Laboratory (ORNL) so that the waste is prepared for safe and secure disposal. The TWPC operates an Environmental Management (EM) waste processing facility on the Oak Ridge Reservation (ORR). The TWPC is classified as a Hazard Category 2, non-reactor nuclear facility. This facility receives, treats, and packages low-level waste and TRU waste stored at various facilities on the ORR for eventual off-site disposal at various DOE sites and commercial facilities. The Remote Handled TRU Waste Sludge held in the Melton Valley Storage Tanks (MVSTs) was produced as a result of the collection, treatment, and storage of liquid radioactive waste originating from the ORNL radiochemical processing and radioisotope production programs. The MVSTs contain most of the associated waste from the Gunite and Associated Tanks (GAAT) in the ORNL's Tank Farms in Bethel Valley and the sludge (SL) and associated waste from the Old Hydro-fracture Facility tanks and other Federal Facility Agreement (FFA) tanks. The SL Processing Facility Build-outs (SL-PFB) Project is integral to the EM cleanup mission at ORNL and is being accelerated by DOE to meet updated regulatory commitments in the Site Treatment Plan. To meet these commitments a Baseline (BL) Change Proposal (BCP) is being submitted to provide continued spending authority as the project re-initiation extends across fiscal year 2012 (FY2012) into fiscal year 2013. Future waste from the ORNL Building 3019 U-233 Disposition project, in the form of U-233 dissolved in nitric acid and water, down-blended with depleted uranyl nitrate solution is also expected to be transferred to the 7856 MVST Annex Facility (formally the Capacity Increase Project (CIP) Tanks) for co-processing with the SL. The SL-PFB project will construct

  5. Transuranic Waste Processing Center (TWPC) Legacy Tank RH-TRU Sludge Processing and Compliance Strategy - 13255

    International Nuclear Information System (INIS)

    Rogers, Ben C.; Heacker, Fred K.; Shannon, Christopher

    2013-01-01

    The U.S. Department of Energy (DOE) needs to safely and efficiently treat its 'legacy' transuranic (TRU) waste and mixed low-level waste (LLW) from past research and defense activities at the Oak Ridge National Laboratory (ORNL) so that the waste is prepared for safe and secure disposal. The TWPC operates an Environmental Management (EM) waste processing facility on the Oak Ridge Reservation (ORR). The TWPC is classified as a Hazard Category 2, non-reactor nuclear facility. This facility receives, treats, and packages low-level waste and TRU waste stored at various facilities on the ORR for eventual off-site disposal at various DOE sites and commercial facilities. The Remote Handled TRU Waste Sludge held in the Melton Valley Storage Tanks (MVSTs) was produced as a result of the collection, treatment, and storage of liquid radioactive waste originating from the ORNL radiochemical processing and radioisotope production programs. The MVSTs contain most of the associated waste from the Gunite and Associated Tanks (GAAT) in the ORNL's Tank Farms in Bethel Valley and the sludge (SL) and associated waste from the Old Hydro-fracture Facility tanks and other Federal Facility Agreement (FFA) tanks. The SL Processing Facility Build-outs (SL-PFB) Project is integral to the EM cleanup mission at ORNL and is being accelerated by DOE to meet updated regulatory commitments in the Site Treatment Plan. To meet these commitments a Baseline (BL) Change Proposal (BCP) is being submitted to provide continued spending authority as the project re-initiation extends across fiscal year 2012 (FY2012) into fiscal year 2013. Future waste from the ORNL Building 3019 U-233 Disposition project, in the form of U-233 dissolved in nitric acid and water, down-blended with depleted uranyl nitrate solution is also expected to be transferred to the 7856 MVST Annex Facility (formally the Capacity Increase Project (CIP) Tanks) for co-processing with the SL. The SL-PFB project will construct and install

  6. A new waste minimization method for the determination of total nonhalogenated volatile organic compounds in TRU wastes

    International Nuclear Information System (INIS)

    Sandoval, W.; Quintana, B.D.; Ortega, L.

    1997-01-01

    As part of the technical support CST-12 provides for a wide variety of defense and nondefense programs within Los Alamos National Laboratory (LANL) and the Department of Energy (DOE) complex, new waste minimization technique is under development for radiological volatile organic analysis (Hot VOA). Currently all HOT VOA must be run in a glovebox. Several types of sample contain TRU radiological waste in the form of particulates. By prefiltering the samples through a 1.2 micron syringe and counting the radioactivity, it has been found that many of the samples can be analyzed outside a glovebox. In the present investigation, the types of Hot VOA samples that can take advantage of this new technique, the volume and types of waste reduced and the experimental parameters will be discussed. Overall, the radioactive waste generated is minimized

  7. Analysis, scale modeling, and full-scale tests of low-level nuclear-waste-drum response to accident environments

    International Nuclear Information System (INIS)

    Huerta, M.; Lamoreaux, G.H.; Romesberg, L.E.; Yoshimura, H.R.; Joseph, B.J.; May, R.A.

    1983-01-01

    This report describes extensive full-scale and scale-model testing of 55-gallon drums used for shipping low-level radioactive waste materials. The tests conducted include static crush, single-can impact tests, and side impact tests of eight stacked drums. Static crush forces were measured and crush energies calculated. The tests were performed in full-, quarter-, and eighth-scale with different types of waste materials. The full-scale drums were modeled with standard food product cans. The response of the containers is reported in terms of drum deformations and lid behavior. The results of the scale model tests are correlated to the results of the full-scale drums. Two computer techniques for calculating the response of drum stacks are presented. 83 figures, 9 tables

  8. Current Program for the management of U.S. Department of Energy transuranic waste

    International Nuclear Information System (INIS)

    Harms, T.

    1994-01-01

    The existing inventory of TRU waste can be divided into tow distinct components: (1) retrievably stored TRU waste and (2) buried TRU waste. The distinction between open-quotes storedclose quotes and open-quotes buriedclose quotes TRU waste was established in 1970 when the Atomic Energy Commission (AEC) determined that TRU-contaminated waste, when disposed, should have more effective isolation from the environment than the confinement provided by burial in pits and trenches covered with soil. Buried TRU (and contaminated soils surrounding buried TRU) are the results of disposal operations carried out at DOE sites prior to the 1970 decision. The inventory of buried TRU is 190,600 m 3 . This waste is the responsibility of the Office of Environmental Restoration (EM-40). All TRU waste generated since 1970 has been placed in storage at six DOE sites. This storage was designed with a lifetime expected to be 20 years. The waste is stored in retrievable form for eventual shipment and disposal at a geologic repository. Currently, TRU waste is contained in a variety of packaging, including metal drums and wooden and metal boxes, and stored in earth-mounded berms, concrete culverts, or other facilities. At the end of 1991, there were approximately 64,000 m 3 of retrievably stored TRU waste. With the WIPP facility not becoming operational until the year 2000 or later, the DOE must effectively manage this waste in other manners. The issues regarding the management of TRU wastes is described

  9. Survey on depth distribution of underground structures for consideration of human intrusion into TRU waste repository

    International Nuclear Information System (INIS)

    Sakamoto, Yoshiaki; Senoo, Muneaki; Sugimoto, Junichiro; Ohishi, Kiyotaka; Okishio, Masanori; Shimizu, Haruo.

    1996-01-01

    Depth distributions of some kinds of underground structure in Japan have been investigated to get an information about suitable depth of underground repository for TRU waste that is arising from reprocessing and MOX fuel fabrication plants. The underground structures investigated in this work were foundation pile of multistoried building, that of elevated expressway, that of JR shinkansen railway, tunnel of subway and wells. The major depth distribution of the underground structures except for the wells was in range from 30 to 50m, and their maximum depth was less than 100m. On the other hand, the 99% of wells was less than 300m in depth. Maximum depth of the other underground structures has been also investigated for a survey of the utilization of underground by artificial structures in Japan. (author)

  10. Corrosion susceptibility of steel drums containing cemented intermediate level nuclear wastes

    Science.gov (United States)

    Duffó, Gustavo S.; Farina, Silvia B.; Schulz, Fátima M.; Marotta, Francesca

    2010-10-01

    Cementation processes are used as immobilization techniques for low or intermediate level radioactive waste for economical and safety reasons and for being a simple operation. In particular, ion-exchange resins commonly used for purification of radioactive liquid waste from nuclear reactors are immobilized before being stored to improve the leach resistance of the waste matrix and to maintain mechanical stability. Combustible solid radioactive waste can be incinerated and the resulting ashes can also be immobilized before storage. The immobilized resins and ashes are then contained in steel drums that may undergo corrosion depending on the presence of certain contaminants. The work described in this paper was aimed at evaluating the corrosion susceptibility of steel drums in contact with cemented ion-exchange resins and incineration ashes containing different concentrations of aggressive species (mostly chloride and sulphate ions). A special type of specimen was designed to simulate the cemented waste in the drum. The evolution of the corrosion potential and the corrosion current density of the steel, as well as the electrical resistivity of the matrix were monitored over a time period of 1 year. The results show the deleterious effect of chloride on the expected lifespan of the waste containers.

  11. Corrosion susceptibility of steel drums containing cemented intermediate level nuclear wastes

    International Nuclear Information System (INIS)

    Duffo, Gustavo S.; Farina, Silvia B.; Schulz, Fatima M.; Marotta, Francesca

    2010-01-01

    Cementation processes are used as immobilization techniques for low or intermediate level radioactive waste for economical and safety reasons and for being a simple operation. In particular, ion-exchange resins commonly used for purification of radioactive liquid waste from nuclear reactors are immobilized before being stored to improve the leach resistance of the waste matrix and to maintain mechanical stability. Combustible solid radioactive waste can be incinerated and the resulting ashes can also be immobilized before storage. The immobilized resins and ashes are then contained in steel drums that may undergo corrosion depending on the presence of certain contaminants. The work described in this paper was aimed at evaluating the corrosion susceptibility of steel drums in contact with cemented ion-exchange resins and incineration ashes containing different concentrations of aggressive species (mostly chloride and sulphate ions). A special type of specimen was designed to simulate the cemented waste in the drum. The evolution of the corrosion potential and the corrosion current density of the steel, as well as the electrical resistivity of the matrix were monitored over a time period of 1 year. The results show the deleterious effect of chloride on the expected lifespan of the waste containers.

  12. Microbial degradation of lignocellulosic fractions during drum composting of mixed organic waste

    Directory of Open Access Journals (Sweden)

    Vempalli Sudharsan Varma

    2017-11-01

    Full Text Available The study aimed to characterize the microbial population involved in lignocellulose degradation during drum composting of mixed organic waste i.e. vegetable waste, cattle manure, saw dust and dry leaves in a 550 L rotary drum composter. Lignocellulose degradation by different microbial populations was correlated by comparing results from four trials, i.e., Trial 1 (5:4, Trial 2 (6:3, Trial 3 (7:2 and Trial 4 (8:1 of varying waste combinations during 20 days of composting period. Due to proper combination of waste materials and agitation in drum composter, a maximum of 66.5 and 61.4 °C was achieved in Trial 1 and 2 by observing a temperature level of 55 °C for 4–6 d. The study revealed that combinations of waste materials had a major effect on the microbial degradation of waste material and quality of final compost due to its physical properties. However, Trial 1 was observed to have longer thermophilic phase leading to higher degradation of lignocellulosic fractions. Furthermore, Fourier transform infrared spectrometer and fluorescent spectroscopy confirmed the decrease in aliphatic to aromatic ratio and increase in polyphenolic compounds of the compost. Heterotrophic bacteria were observed predominantly due to the readily available organic matter during the initial period of composting. However, fungi and actinomycetes were active in the degradation of lignocellulosic fractions.

  13. Demonstration of a remotely operated TRU waste size-reduction and material handling process

    International Nuclear Information System (INIS)

    Stewart, J.A. III; Schuler, T.F.; Ward, C.R.

    1986-01-01

    Noncombustible Pu-238 and Pu-239 waste is generated as a result of normal operation and decommissioning activity at the Savannah River Plant and is being retrievably stored at the site. As part of the long-term plan to process the stored waste and current waste for permanent disposal, a remote size-reduction and material handling process is being tested at Savannah River Laboratory to provide design support for the plant TRU Waste Facility scheduled to be completed in 1993. The process consists of a large, low-speed shredder and material handling system, a remote worktable, a bagless transfer system, and a robotically controlled manipulator, or Telerobot. Initial testing of the shredder and material handling system and a cycle test of the bagless transfer system were completed. Initial Telerobot run-in and system evaluation was completed. User software was evaluated and modified to support complete menu-driven operation. Telerobot prototype size-reduction tooling was designed and successfully tested. Complete nonradioactive testing of the equipment is scheduled to be completed in 1987

  14. TRU [transuranic] waste certification compliance requirements for acceptance of newly generated contact-handled wastes to be shipped to the Waste Isolation Pilot Plant: Revision 2

    International Nuclear Information System (INIS)

    1989-01-01

    Compliance requirements are presented for certifying that unclassified, newly generated (NG), contact-handled (CH) transuranic (TRU) solid wastes from defense programs meet the Waste Isolation Pilot Plant (WIPP) Waste Acceptance Criteria (WAC). Where appropriate, transportation and interim storage requirements are incorporated; however, interim storage sites may have additional requirements consistent with these requirements. All applicable Department of Energy (DOE) orders must continue to be met. The compliance requirements for stored or buried waste are not addressed in this document. The compliance requirements are divided into four sections, primarily determined by the general feature that the requirements address. These sections are General Requirements, Waste Container Requirements, Waste Form Requirements, and Waste Package Requirements. The waste package is the combination of waste container and waste. 10 refs., 1 fig

  15. Nuclear waste calorimeter for very large drums with 385 litres sample volume

    Energy Technology Data Exchange (ETDEWEB)

    Jossens, G.; Mathonat, C. [SETARAM Instrumentation, Caluire (France); Bachelet, F. [CEA Valduc, Is sur Tille (France)

    2015-03-15

    Calorimetry is a very precise and well adapted tool for the classification of drums containing nuclear waste material depending on their level of activities (low, medium, high). A new calorimeter has been developed by SETARAM Instrumentation and the CEA Valduc in France. This new calorimeter is designed for drums having a volume bigger than 100 liters. It guarantees high operator safety by optimizing drum handling and air circulation for cooling, and optimized software for direct measurement of the quantity of nuclear material. The LVC1380 calorimeter makes it possible to work over the range 10 to 3000 mW, which corresponds to approximately 0.03 to 10 g of tritium or 3 to 955 g of {sup 241}Pu in a volume up to 385 liters. This calorimeter is based on the heat flow measurement using Peltier elements which surround the drum in the 3 dimensions and therefore measure all the heat coming from the radioactive stuff whatever its position inside the drum. Calorimeter's insulating layers constitute a thermal barrier designed to filter disturbances until they represent less than 0.001 Celsius degrees and to eliminate long term disturbances associated, for example, with laboratory temperature variations between day and night. A calibration device based on Joule effect has also been designed. Measurement time has been optimized but remains long compared with other methods of measurement such as gamma spectrometry but its main asset is to have a good accuracy for low level activities.

  16. The crane handling system for 500 litre drums of cemented radioactive waste

    International Nuclear Information System (INIS)

    Staples, A.T.

    1991-01-01

    As part of the AEA Technology strategy for dealing with radioactive wastes new waste treatment facilities are being built at the Winfrith Technology Centre (WTC), Dorset. One of the facilities at WTC is the Treated Radwaste Store (TRS) which is designed to store sealed 500 litre capacity drums of treated waste for an interim period until the national disposal facility is operational. Within the TRS two cranes have been incorporated, one spanning the entire width and travelling the length of the Store. The second operates within the area designated for drum handling during inspection work. The development of the design of these cranes and their associated control systems, to meet the complex requirements of operations whilst also satisfying the reliability and safety criteria, is discussed within the paper. (author)

  17. Artificial neural network application in isotopic characterization of radioactive waste drums

    International Nuclear Information System (INIS)

    Potiens Junior, Ademar Jose

    2005-01-01

    One of the most important aspects to the development of the nuclear technology is the safe management of the radioactive waste arising from several stages of the nuclear fuel cycles, as well as from production and use of radioisotope in the medicine, industry and research centers. The accurate characterization of this waste is not a simple task, given to its diversity in isotopic composition and non homogeneity in the space distribution and mass density. In this work it was developed a methodology for quantification and localization of radionuclides not non homogeneously distributed in a 200 liters drum based in the Monte Carlo Method and Artificial Neural Network (RNA), for application in the isotopic characterization of the stored radioactive waste at IPEN. Theoretical arrangements had been constructed involving the division of the radioactive waste drum in some units or cells and some possible configurations of source intensities. Beyond the determination of the detection positions, the respective detection efficiencies for each position in function of each cell of the drum had been obtained. After the construction and the training of the RNA's for each developed theoretical arrangement, the validation of the method were carried out for the two arrangements that had presented the best performance. The results obtained show that the methodology developed in this study could be an effective tool for isotopic characterization of radioactive wastes contained in many kind of packages. (author)

  18. JUSTIFICATION FOR A LIMIT OF 15 PERCENT HYDROGEN IN A 55-GALLON DRUM

    International Nuclear Information System (INIS)

    MARUSICH, R.M.

    2007-01-01

    The concentration of 15% hydrogen in air in a waste drum is used as the concentration at which the drum remains intact in the case of a deflagration. The following describes what could happen to the drum if 15% hydrogen or more in air were ignited. Table 2 of the Savannah River report WSRC-TR-90-165 ''TRU Drum Hydrogen Explosion Tests'' provides the results of tests performed in 55-gallon drums filled with hydrogen and air mixtures. The hydrogen-air mixtures were ignited by a hot-wire igniter. The results of the tests are shown in Table 1. They concluded that drums can withstand deflagration involving hydrogen concentration up to 15% hydrogen. Testing was performed at Idaho Falls and documented in a letter from RH Beers, Waste Technology Programs Division, EG and G Idaho, to CP Gertz, Radioactive Waste Technology Branch, DOE dated Sept. 29, 1983. In these tests, 55-gallon drums were filled with hydrogen-air mixtures which were ignited. The results in Table 2.2 showed that ignition for drums containing 11% and 14% hydrogen, the drum lid remained on the drum. Ignition in drum with 30% hydrogen resulted in lid loss. It is concluded from the results of these two tests that, for uncorroded drums, a 15% hydrogen in air mixture will not result in loss of drum integrity (i.e., lid remains on, walls remain intact). The drum walls however, may be thinned due to corrosion. The effect of the deflagration on thinner walls is assessed next. Assume a 15% hydrogen in air mixture exists in a drum. The pressure assuming adiabatic isochoric complete combustion (AICC) conditions is 69 psig (using the same deflagration pressure calculation method as in HNF-19492, ''Revised Hydrogen Deflagration Analysis which got 82 psig for 20% hydrogen in air)

  19. Corrosion susceptibility of steel drums to be used as containers for intermediate level nuclear waste

    International Nuclear Information System (INIS)

    Farina, S.; Schulz Rodriguez, F.; Duffo, G.

    2013-01-01

    The present work is a study of the corrosion susceptibility of steel drums in contact with cemented ion-exchange resins contaminated with different types and concentrations of aggressive species. A special type of specimen was manufactured to simulate the cemented ion-exchange resins in the drum. The evolution of the corrosion potential and the corrosion rate of the steel, as well as the electrical resistivity of the matrix were monitored over a time period of 900 days. The aggressive species studied were chloride ions (the main ionic species of concern) and sulphate ions (produced during radiolysis of the cationic exchange-resins after cementation). The work was complemented with an analysis of the corrosion products formed on the steel in each condition, as well as the morphology of the corrosion products. When applying the results obtained in the present work to estimate the corrosion depth of the steel drums containing the cemented radioactive waste after a period of 300 years (foreseen durability of the Intermediate Level Radioactive Waste facility in Argentina), it is found that in the most unfavourable case (high chloride contamination), the corrosion penetration will be considerably lower than the thickness of the wall of the steel drums. (authors)

  20. Assessment of gas flammability in transuranic waste container

    International Nuclear Information System (INIS)

    Connolly, M.J.; Loehr, C.A.; Djordjevic, S.M.; Spangler, L.R.

    1995-01-01

    The Safety Analysis Report for the TRUPACT-II Shipping Package [Transuranic Package Transporter-II (TRUPACT-II) SARP] set limits for gas generation rates, wattage limits, and flammable volatile organic compound (VOC) concentrations in transuranic (TRU) waste containers that would be shipped to the Waste Isolation Pilot Plant (WIPP). Based on existing headspace gas data for drums stored at the Idaho National Engineering Laboratory (INEL) and the Rocky Flats Environmental Technology Site (RFETS), over 30 percent of the contact-handled TRU waste drums contain flammable VOC concentrations greater than the limit. Additional requirements may be imposed for emplacement of waste in the WIPP facility. The conditional no-migration determination (NMD) for the test phase of the facility required that flame tests be performed if significant levels of flammable VOCs were present in TRU waste containers. This paper describes an approach for investigating the potential flammability of TRU waste drums, which would increase the allowable concentrations of flammable VOCS. A flammability assessment methodology is presented that will allow more drums to be shipped to WIPP without treatment or repackaging and reduce the need for flame testing on drums. The approach includes experimental work to determine mixture lower explosive limits (MLEL) for the types of gas mixtures observed in TRU waste, a model for predicting the MLEL for mixtures of VOCS, hydrogen, and methane, and revised screening limits for total flammable VOCs concentrations and concentrations of hydrogen and methane using existing drum headspace gas data and the model predictions

  1. EPA's Review of DOE's Inventory Tracking for TRU Wastes at Waste Control Specialists

    Science.gov (United States)

    On April 9, 2014, EPA's Waste Isolation Pilot Plant (WIPP) waste characterization team visited Waste Control Specialists (WCS) to determine whether DOE was meeting EPA's waste inventory tracking requirements at 40 CFR 194.24(c)(4).

  2. Radioactive waste slurry dehydrating and drum filling device

    International Nuclear Information System (INIS)

    Ichihashi, Toshio; Abe, Kazuaki; Hasegawa, Akira

    1981-01-01

    Purpose: To obtain a device for simultaneously filling and dehydrating radioactive waste in a waste can without the necessity of a special device for dehydration. Constitution: This device includes a radioactive waste storage tank, a pump for supplying the waste from the tank to a can, a drain tube having a filter at the lower end and installed displaceable in the axial direction of the can, and a drain pump. The slurry stored in the radioactive waste storage tank is supplied by the pump to the can, and the feedwater in the slurry is removed by another pump through a drain pipe having a filter which does not pass solid content from the can. Accordingly, as the slurry is filled in the can, the feedwater contained therein is removed. Consequently, it can simultaneously dehydrate and fill the dehydrated waste in the can. (Yoshihara, H.)

  3. Corrosion of steel drums containing cemented ion-exchange resins as intermediate level nuclear waste

    Science.gov (United States)

    Duffó, G. S.; Farina, S. B.; Schulz, F. M.

    2013-07-01

    Exhausted ion-exchange resins used in nuclear reactors are immobilized by cementation before being stored. They are contained in steel drums that may undergo internal corrosion depending on the presence of certain contaminants. The objective of this work is to evaluate the corrosion susceptibility of steel drums in contact with cemented ion-exchange resins with different aggressive species. The corrosion potential and the corrosion rate of the steel, and the electrical resistivity of the matrix were monitored for 900 days. Results show that the cementation of ion-exchange resins seems not to pose special risks regarding the corrosion of the steel drums. The corrosion rate of the steel in contact with cemented ion-exchange resins in the absence of contaminants or in the presence of 2.3 wt.% sulphate content remains low (less than 0.1 μm/year) during the whole period of the study (900 days). The presence of chloride ions increases the corrosion rate of the steel at the beginning of the exposure but, after 1 year, the corrosion rate drops abruptly reaching a value close to 0.1 μm/year. This is probably due to the lack of water to sustain the corrosion process. When applying the results obtained in the present work to estimate the corrosion depth of the steel drums containing the cemented radioactive waste after a period of 300 years, it is found that in the most unfavourable case (high chloride contamination), the corrosion penetration will be considerably lower than the thickness of the wall of the steel drums. Cementation of ion-exchange resins does not seem to pose special risks regarding the corrosion of the steel drums that contained them; even in the case the matrix is highly contaminated with chloride ions.

  4. Automated box/drum waste assay (252Cf shuffler) through the material access and accountability boundary

    International Nuclear Information System (INIS)

    Horley, E.C.; Bjork, C.W.; Bourret, S.C.; Polk, P.J.; Schneider, C.J.; Studley, R.V.

    1992-01-01

    For the first time, a shuffler waste-assay system has been made a part of material access and accountability boundary (MAAB). A 252 Cf Pass-Thru shuffler integrated with a conveyor handling system, will process box or drum waste across the MAAB. This automated system will significantly reduce personnel operating costs because security forces will not be required at the MAAB during waste transfer. Further, the system eliminates the chance of a mix-up between measured and nonmeasured waste. This Pass-Thru shuffler is to be installed in the Westinghouse Savannah River Company 321M facility to screen waste boxes and drums for 235 U. An automated conveyor will load waste containers into the shuffler, and upon verification, will transfer the containers across the MAAB. Verification will consist of a weight measurement followed by active neutron interrogation. Containers that pass low-level waste criteria will be conveyed to an accumulator section outside the MAAB. If a container fails to meet the waste criteria, it will be rejected and sent back to the load station for manual inspection and repackaging

  5. Design and testing of a unique active Compton-suppressed LaBr3(Ce) detector system for improved sensitivity assays of TRU in remote-handled TRU wastes

    Energy Technology Data Exchange (ETDEWEB)

    J. K. Hartwell; M. E. McIlwain; J. A. Kulisek

    2007-10-01

    The US Department of Energy’s transuranic (TRU) waste inventory includes about 4,500 m3 of remote-handled TRU (RH-TRU) wastes composed of a variety of containerized waste forms having a contact surface dose rate that exceeds 2 mSv/hr (200 mrem/hr) containing waste materials with a total TRU concentration greater than 3700 Bq/g (100 nCi/g). As part of a research project to investigate the use of active Compton-suppressed room-temperature gamma-ray detectors for direct non-destructive quantification of the TRU content of these RH-TRU wastes, we have designed and purchased a unique detector system using a LaBr3(Ce) primary detector and a NaI(Tl) suppression mantle. The LaBr3(Ce) primary detector is a cylindrical unit ~25 mm in diameter by 76 mm long viewed by a 38 mm diameter photomultiplier. The NaI(Tl) suppression mantle (secondary detector) is 175 mm by 175 mm with a center well that accommodates the primary detector. An important feature of this arrangement is the lack of any “can” between the primary and secondary detectors. These primary and secondary detectors are optically isolated by a thin layer (.003") of aluminized kapton, but the hermetic seal and thus the aluminum can surrounds the outer boundary of the detector system envelope. The hermetic seal at the primary detector PMT is at the PMT wall. This arrangement virtually eliminates the “dead” material between the primary and secondary detectors, a feature that preliminary modeling indicated would substantially improve the Compton suppression capability of this device. This paper presents both the expected performance of this unit determined from modeling with MCNPX, and the performance measured in our laboratory with radioactive sources.

  6. Non-intrusive measurement of tritium activity in waste drums by modelling a 3He leak quantified by mass spectrometry

    International Nuclear Information System (INIS)

    Demange, D.

    2002-01-01

    This study deals with a new method that makes it possible to measure very low tritium quantities inside radioactive waste drums. This indirect method is based on measuring the decaying product, 3 He, and requires a study of its behaviour inside the drum. Our model considers 3 He as totally free and its leak through the polymeric joint of the drum as two distinct phenomena: permeation and laminar flow. The numerical simulations show that a pseudo-stationary state takes place. Thus, the 3 He leak corresponds to the tritium activity inside the drum but it appears, however, that the leak peaks when the atmospheric pressure variations induce an overpressure in the drum. Nevertheless, the confinement of a drum in a tight chamber makes it possible to quantify the 3 He leak. This is a non-intrusive measurement of its activity, which was experimentally checked by using reduced models, representing the drum and its confinement chamber. The drum's confinement was optimised to obtain a reproducible 3 He leak measurement. The gaseous samples taken from the chamber were purified using selective adsorption onto activated charcoals at 77 K to remove the tritium and pre-concentrate the 3 He. The samples were measured using a leak detector mass spectrometer. The adaptation of the signal acquisition and the optimisation of the analysis parameters made it possible to reach the stability of the external calibrations using standard gases with a 3 He detection limit of 0.05 ppb. Repeated confinement of the reference drums demonstrated the accuracy of this method. The uncertainty of this non-intrusive measurement of the tritium activity in 200-liter drums is 15% and the detection limit is about 1 GBq after a 24 h confinement. These results led to the definition of an automated tool able to systematically measure the tritium activity of all storage waste drums. (authors)

  7. Validation of radioactive isotope activity measurement in homogeneous waste drum using Monte Carlo codes

    Energy Technology Data Exchange (ETDEWEB)

    Thanh, Tran Thien; Tran, Le Bao; Ton, Thai Van; Chuong, Huynh Dinh; Tao, Chau Van [VNUHCM-Univ. of Science, Ho Chi Minh City (Viet Nam). Dept. of Nuclear Physics; VNUHCM-Univ. of Science, Ho Chi Minh City (Viet Nam). Nuclear Technique Lab.; Tam, Hoang Duc [Ho Chi Minh City Univ. of Pedagogy (Viet Nam). Faculty of Physics; Quang, Ma Thuy [VNUHCM-Univ. of Science, Ho Chi Minh City (Viet Nam). Dept. of Nuclear Physics

    2017-07-15

    In this work, the angular dependent efficiency recorded by collimated NaI(Tl) detector is determined a quantification of the activity of mono- and multi-energy gamma emitting isotopes positioning in a waste drum. The simulated efficiencies using both MCNP5 and Geant4 are in good agreement with experimental results. Referring to these simulated efficiencies, we recalculated the source activity with the highest deviation of 13%.

  8. Validation of radioactive isotope activity measurement in homogeneous waste drum using Monte Carlo codes

    International Nuclear Information System (INIS)

    Thanh, Tran Thien; Tran, Le Bao; Ton, Thai Van; Chuong, Huynh Dinh; Tao, Chau Van; VNUHCM-Univ. of Science, Ho Chi Minh City; Tam, Hoang Duc; Quang, Ma Thuy

    2017-01-01

    In this work, the angular dependent efficiency recorded by collimated NaI(Tl) detector is determined a quantification of the activity of mono- and multi-energy gamma emitting isotopes positioning in a waste drum. The simulated efficiencies using both MCNP5 and Geant4 are in good agreement with experimental results. Referring to these simulated efficiencies, we recalculated the source activity with the highest deviation of 13%.

  9. Transportation considerations related to waste forms and canisters for Defense TRU wastes

    International Nuclear Information System (INIS)

    Schneider, K.J.; Andrews, W.B.; Schreiber, A.M.; Rosenthal, L.J.; Odle, C.J.

    1981-09-01

    This report identifies and discusses the considerations imposed by transportation on waste forms and canisters for contact-handled, solid transuranic wastes from the US Department of Energy (DOE) activities. The report reviews (1) the existing raw waste forms and potential immobilized waste forms, (2) the existing and potential future DOE waste canisters and shipping containers, (3) regulations and regulatory trends for transporting commercial transuranic wastes on the ISA, (4) truck and rail carrier requirements and preferences for transporting the wastes, and (5) current and proposed Type B external packagings for transporting wastes

  10. Dissolution kinetics of smectite in geological repository system of TRU waste

    International Nuclear Information System (INIS)

    Sato, Tsutomu

    2005-02-01

    Extensive use of cement for encapsulation, mine timbering, and grouting purposes is envisaged in geological repositories of TRU waste. Degradation of cement materials in the repositories can produce a high pH pore fluid initially ranging from pH 13.0 to 13.5. The high pH pore fluids can migrate and react chemically with the host rock and bentonites which were employed to enhance repository's integrity. These chemical reactions can effect the capacity of the rocks and bentonites in retarding the migration of radionuclides. Smectite, main component of bentonite, can lose some of their desirable properties at the early stages of bentonite-cement fluid interaction. This has been a key research issue in performance assessment of TRU waste disposal. In this study, firstly, the factors affected on dissolution rate of smectite and equations describing dissolution rate were reviewed. Secondly, the effect of dissolved silica on the dissolution behavior of Na-montmorillonite was investigated. Bulk sample flow-through dissolution experiments at alkaline condition (pH 13.3) with different dissolved silica concentrations at different temperatures were performed. Titration experiments were also carried out at similar conditions. Atomic Force Microscopy (AFM) ex situ observations (i.e. on samples from flow-through experiments) was also performed to obtain the dissolution rate. Current results from bulk sample surface titration experiments indicate that dissolved silica has no pronounced effect on the surface titration behavior of Na-montmorillonite at any temperature. However, the trends for the surface titration behavior represent the averaged behavior of all particle sizes (i.e. including colloids) such that within an order of magnitude change cannot be quantified appreciably. Bulk flow-through dissolution experiments coupled with ex situ AFM observations indicate that there is also no effect of dissolved silica with comparatively low concentration of the reacting solution on

  11. Packaging design criteria for the Type B Drum

    International Nuclear Information System (INIS)

    Edwards, W.S.; Smith, R.J.; Wells, A.H.

    1995-09-01

    The Type B Drum package is a transportation cask capable of shipping a single 55-gal (208 L) drum of transuranic (TRU) waste. The Type B Drum is smaller than existing certified packages, such as the TRUPACT-II cask, but will allow payloads with higher thermal and gas generation rates, thus providing greater operational flexibility. The Type B Drum package has double containment so that plutonium contents and other radioactive material may be transported in Type B quantities. Conceptual designs of unshielded and shielded versions of the Type B Drum were completed in Report on the Conceptual Design of the Unshielded Type B Drum Packaging and Report on the Conceptual Design of the Shielded type B Drum Packaging (WEC 1994a, WEC 1994b), which demonstrated the Type B Drum to be a viable packaging system. A Type B package containment system must withstand the normal conditions of transport and the hypothetical accident conditions, which include a 9-m (30-ft) drop onto an unyielding surface and a 1-m (3-ft) drop onto a 15-cm (6-in.) diameter pin, and a fire and immersion scenarios

  12. Development of the remote-handled transuranic waste radioassay data quality objectives. An evaluation of RH-TRU waste inventories, characteristics, radioassay methods and capabilities

    Energy Technology Data Exchange (ETDEWEB)

    Meeks, A.M.; Chapman, J.A.

    1997-09-01

    The Waste Isolation Pilot Plant will accept remote-handled transuranic waste as early as October of 2001. Several tasks must be accomplished to meet this schedule, one of which is the development of Data Quality Objectives (DQOs) and corresponding Quality Assurance Objectives (QAOs) for the assay of radioisotopes in RH-TRU waste. Oak Ridge National Laboratory (ORNL) was assigned the task of providing to the DOE QAO, information necessary to aide in the development of DQOs for the radioassay of RH-TRU waste. Consistent with the DQO process, information needed and presented in this report includes: identification of RH-TRU generator site radionuclide data that may have potential significance to the performance of the WIPP repository or transportation requirements; evaluation of existing methods to measure the identified isotopic and quantitative radionuclide data; evaluation of existing data as a function of site waste streams using documented site information on fuel burnup, radioisotope processing and reprocessing, special research and development activities, measurement collection efforts, and acceptable knowledge; and the current status of technologies and capabilities at site facilities for the identification and assay of radionuclides in RH-TRU waste streams. This report is intended to provide guidance in developing the RH-TRU waste radioassay DQOs, first by establishing a baseline from which to work, second, by identifying needs to fill in the gaps between what is known and achievable today and that which will be required before DQOs can be formulated, and third, by recommending measures that should be taken to assure that the DQOs in fact balance risk and cost with an achievable degree of certainty.

  13. Development of the remote-handled transuranic waste radioassay data quality objectives. An evaluation of RH-TRU waste inventories, characteristics, radioassay methods and capabilities

    International Nuclear Information System (INIS)

    Meeks, A.M.; Chapman, J.A.

    1997-09-01

    The Waste Isolation Pilot Plant will accept remote-handled transuranic waste as early as October of 2001. Several tasks must be accomplished to meet this schedule, one of which is the development of Data Quality Objectives (DQOs) and corresponding Quality Assurance Objectives (QAOs) for the assay of radioisotopes in RH-TRU waste. Oak Ridge National Laboratory (ORNL) was assigned the task of providing to the DOE QAO, information necessary to aide in the development of DQOs for the radioassay of RH-TRU waste. Consistent with the DQO process, information needed and presented in this report includes: identification of RH-TRU generator site radionuclide data that may have potential significance to the performance of the WIPP repository or transportation requirements; evaluation of existing methods to measure the identified isotopic and quantitative radionuclide data; evaluation of existing data as a function of site waste streams using documented site information on fuel burnup, radioisotope processing and reprocessing, special research and development activities, measurement collection efforts, and acceptable knowledge; and the current status of technologies and capabilities at site facilities for the identification and assay of radionuclides in RH-TRU waste streams. This report is intended to provide guidance in developing the RH-TRU waste radioassay DQOs, first by establishing a baseline from which to work, second, by identifying needs to fill in the gaps between what is known and achievable today and that which will be required before DQOs can be formulated, and third, by recommending measures that should be taken to assure that the DQOs in fact balance risk and cost with an achievable degree of certainty

  14. Radiological Characterization Methodology for INEEL-Stored Remote-Handled Transuranic (RH TRU) Waste from Argonne National Laboratory-East

    International Nuclear Information System (INIS)

    Kuan, P.; Bhatt, R.N.

    2003-01-01

    An Acceptable Knowledge (AK)-based radiological characterization methodology is being developed for RH TRU waste generated from ANL-E hot cell operations performed on fuel elements irradiated in the EBR-II reactor. The methodology relies on AK for composition of the fresh fuel elements, their irradiation history, and the waste generation and collection processes. Radiological characterization of the waste involves the estimates of the quantities of significant fission products and transuranic isotopes in the waste. Methods based on reactor and physics principles are used to achieve these estimates. Because of the availability of AK and the robustness of the calculation methods, the AK-based characterization methodology offers a superior alternative to traditional waste assay techniques. Using the methodology, it is shown that the radiological parameters of a test batch of ANL-E waste is well within the proposed WIPP Waste Acceptance Criteria limits

  15. Characterization of uranium in bituminized radioactive waste drums by self-induced X-ray fluorescence

    International Nuclear Information System (INIS)

    Pin, Patrick; Perot, Bertrand

    2013-06-01

    This paper reports the experimental qualification of an original uranium characterization method based on fluorescence X rays induced by the spontaneous gamma emission of bituminized radioactive waste drums. The main 661.7 keV gamma ray following the 137 Cs decay produces by Compton scattering in the bituminized matrix an intense photon continuum around 100 keV, i.e. in the uranium X-ray fluorescence region. 'Self-induced' X-rays produced without using an external source allow a quantitative assessment of uranium as 137 Cs and uranium are homogeneously mixed and distributed in the bituminized matrix. The paper presents the experimental qualification of the method with real waste drums, showing a detection limit well below 1 kg of uranium in 20 min acquisitions while the usual gamma rays of 235 U (185 keV) or 238 U (1001 keV of 234m Pa in the radioactive decay chain) are not detected. The relative uncertainty on the uranium mass assessed by self-induced X-ray fluorescence (SXRF) is about 50%, with a 95% confidence level, taking into account the correction of photon attenuation in the waste matrix. This last indeed contains high atomic numbers elements like uranium, but also barium, in quantities which are not known for each drum. Attenuation is estimated thanks to the peak-to-Compton ratio to limit the corresponding uncertainty. The SXRF uranium masses measured in the real drums are in good agreement with long gamma-ray spectroscopy measurements (1001 keV peak) or with radiochemical analyses. (authors)

  16. Liquide waste volume reduction by in-drum drying system

    International Nuclear Information System (INIS)

    Volaric, B.; Zorko, M.

    1998-01-01

    The disposal of radioactive waste is becoming increasingly difficult because of the lack of available volume on site, the rising disposal costs and the lack of ultimate disposal sites. Optimized treatment and volume reduction of concentrates and spent resins prior to interim storage, final disposal, and solidification processes are major step to counteract the situation.(author)

  17. Corrosion susceptibility of steel drums to be used as containers for intermediate level nuclear waste

    Science.gov (United States)

    Farina, S.; Schulz Rodriguez, F.; Duffó, G.

    2013-07-01

    The present work is a study of the corrosion susceptibility of steel drums in contact with cemented ion-exchange resins contaminated with different types and concentrations of aggressive species. A special type of specimen was manufactured to simulate the cemented ion-exchange resins in the drum. The evolution of the corrosion potential and the corrosion rate of the steel, as well as the electrical resistivity of the matrix were monitored over a time period of 900 days. The aggressive species studied were chloride ions (the main ionic species of concern) and sulphate ions (produced during radiolysis of the cationic exchange-resins after cementation). The work was complemented with an analysis of the corrosion products formed on the steel in each condition, as well as the morphology of the corrosion products. When applying the results obtained in the present work to estimate the corrosion depth of the steel drumscontaining the cemented radioactive waste after a period of 300 years (foreseen durability of the Intermediate Level Radioactive Waste facility in Argentina) , it is found that in the most unfavourable case (high chloride contamination), the corrosion penetration will be considerably lower than the thickness of the wall of the steel drums.

  18. Gamma-ray spectrometry method used for radioactive waste drums characterization for final disposal at National Repository for Low and Intermediate Radioactive Waste--Baita, Romania.

    Science.gov (United States)

    Done, L; Tugulan, L C; Dragolici, F; Alexandru, C

    2014-05-01

    The Radioactive Waste Management Department from IFIN-HH, Bucharest, performs the conditioning of the institutional radioactive waste in concrete matrix, in 200 l drums with concrete shield, for final disposal at DNDR - Baita, Bihor county, in an old exhausted uranium mine. This paper presents a gamma-ray spectrometry method for the characterization of the radioactive waste drums' radionuclides content, for final disposal. In order to study the accuracy of the method, a similar concrete matrix with Portland cement in a 200 l drum was used. © 2013 The Authors. Published by Elsevier Ltd All rights reserved.

  19. Characterizing and improving passive-active shufflers for assays of 208-Liter waste drums

    International Nuclear Information System (INIS)

    Rinard, P.M.; Adams, E.L.; Menlove, H.O.; Sprinkle, J.K. Jr.

    1992-01-01

    A passive and active neutron shuffler for 208-L waste drums has been used to perform over 1500 active and 500 passive measurements on uranium and plutonium samples in 28 different matrices. The shuffler is now better characterized and improvements have been implemented or suggested. An improved correction for the effects of the matrix material was devised from flux-monitor responses. The most important cause of inaccuracies in assays is a localized instead of a uniform distribution of fissile material in a drum; a technique for deducing the distribution from the assay data and then applying a correction is suggested and will be developed further. A technique is given to detect excessive amounts of moderator that could make hundreds of grams of 235 U assay as zero grams. Sensitivities (minimum detectable masses) for 235 U with active assays and for 240 Pu eff with passive assays are presented and the effects of moderators and absorbers on sensitivities noted

  20. Immobilization and Waste Form Product Acceptance for Low Level and TRU Waste Forms

    International Nuclear Information System (INIS)

    Holtzscheiter, E.W.; Harbour, J.R.

    1998-05-01

    The Tanks Focus Area is supporting technology development in immobilization of both High Level (HLW) and Low Level (LLW) radioactive wastes. The HLW process development at Hanford and Idaho is patterned closely after that of the Savannah River (Defense Waste Processing Facility) and West Valley Sites (West Valley Demonstration Project). However, the development and options open to addressing Low Level Waste are diverse and often site specific. To start, it is important to understand the breadth of Low Level Wastes categories

  1. Project Plan for the evaluation of REDC waste for TRU-waste radionuclides

    International Nuclear Information System (INIS)

    Nguyen, L.; Yong, L.; Chapman, J.

    1996-09-01

    This project plan describes the plan to determine whether the solid radioactive wastes generated by the Radiochemical Engineering Development Center (REDC) meet the Department of Energy's definition of transuranic wastes. Existing waste characterization methods will be evaluated, as well as historical data, and recommendations will be made as necessary

  2. Simultaneous correction of attenuation and geometric response in emission tomography applied to nuclear waste drums

    International Nuclear Information System (INIS)

    Thierry, Raphael

    1999-01-01

    Multi-photonic emission tomography is a non destructive technique applied to the control of radioactive waste drums. The emitted gamma rays are detected on the range [50 keV, 2 MeV] by a hyper pure germanium, of high resolution in energy, which enables to set up a detailed list of radionuclides contained within the drum. From different points of measurement located in a transaxial plane of the drum, the activity distribution is computed by a reconstruction algorithm. An algebraic modelling of the physical process has been developed in order to correct the different degrading phenomenon, in particular the attenuation and the detector geometric response. Attenuation through the materials constituting the barrel is the preponderant phenomena. Its ignorance prevents from accurate activity quantification. Its correction has been realised from an attenuation map obtained by a transmission tomograph. The detector geometric response, introducing a blurring within the detection, is compensated by an analytic model. An adequate modelling of those phenomenon is primordial: it highly contributes on a large scale the image quality and the quantification. The image reconstruction, requiring the resolution of sparse linear system, is realised by iterative algorithms. Due to the 'ill-posed' nature of tomographic reconstruction, it is necessary to use regularisation: by introducing an a priori information on the solution, the stabilisation of the methods is carried out. We chose to minimise the Maximum A Posteriori criterion. Its resolution is considered with a half-quadratic regularisation: it permits the preservation of natural discontinuities, and avoids global-over smoothing of the image. It is evaluated on real phantoms and waste drums. Efficient sampling of the data is considered. (author) [fr

  3. Report of conceptual design for TRU solid waste facilities adjacent to 200H Area: Savannah River Plant

    International Nuclear Information System (INIS)

    1978-02-01

    Facilities for consolidating Savannah River Plant solid transuranic (TRU) waste and placing in long-term safe, retrievable storage have been designed conceptually. A venture guidance appraisal of cost for the facilities has been prepared. The proposed site of the new processing area is adjacent to existing H Area facilities. The scopes of work comprising the conceptual design describe facilities for: exhuming high-level TRU waste from buried and pad-stored locations in the plant burial ground; opening, emptying, and sorting waste containers and their contents within shielded, regulated enclosures; volume-reducing the noncombustibles by physical processes and decontaminating the metal waste; burning combustibles; fixing the consolidated waste forms in a concrete matrix within a double-walled steel container; placing product containers in a retrievable surface storage facility adjacent to the existing plant burial ground; and maintaining accountability of all special nuclear materials. Processing, administration, and auxiliary service buildings are to be located adjacent to existing H Area facilities where certain power and waste liquid services will be shared

  4. Type B Drum packages

    International Nuclear Information System (INIS)

    Edwards, W.S.

    1995-11-01

    The Type B Drum package is a container in which a single drum containing Type B quantities of radioactive material will be packaged for shipment. The Type B Drum containers are being developed to fill a void in the packaging and transportation capabilities of the US Department of Energy (DOE), as no double containment packaging for single drums of Type B radioactive material is currently available. Several multiple-drum containers and shielded casks presently exist. However, the size and weight of these containers present multiple operational challenges for single-drum shipments. The Type B Drum containers will offer one unshielded version and, if needed, two shielded versions, and will provide for the option of either single or double containment. The primary users of the Type B Drum container will be any organization with a need to ship single drums of Type B radioactive material. Those users include laboratories, waste retrieval facilities, emergency response teams, and small facilities

  5. HANFORD Pu-238 DRUM INTEGRITY ASSESSMENT

    International Nuclear Information System (INIS)

    CANNELL, G.R.

    2004-01-01

    Hanford is presently retrieving contact-handled, transuranic (CH-TRU) waste drums from the site's Low-Level Burial Grounds (LLBG) for processing and disposition. A subgroup of these drums (12 total), referred to as Pu-238 drums, has some unique characteristics that may impact the current drum handling and processing activities. These characteristics include content, shielding, thermal, pressurization and criticality issues. An effort to evaluate these characteristics, for the purpose of developing a specific plan for safe retrieval of the Pu-238 drums, is underway. In addition to the above evaluation, the following integrity assessment of the inner container material and/or confinement properties, with primary emphasis on the Source Capsule (primary confinement barrier) and Shipping Container has been performed. Assessment included review of the inner container materials and the potential impact the service history may have had on material and/or confinement properties. Several environmental degradation mechanisms were considered with the objective of answering the following question: Is it likely the container material and/or confinement properties have been significantly altered as a result of service history?

  6. Subsurface Planar Vitrification Treatment of Problematic TRU Wastes: Status of a Technology Demonstration Program

    International Nuclear Information System (INIS)

    Morse, M.K.; Nowack, B.R.; Thompson, L.E.

    2006-01-01

    This paper provides a status of the In Situ Transuranic Waste Delineation and Removal Project in which the GeoMelt R Subsurface Planar Vitrification TM (SPV TM ) process is being evaluated for the in situ treatment of burial sites containing remote handled mixed transuranic (TRU) waste. The GeoMelt R SPV TM process was invented and patented by Geosafe Corporation. AMEC holds the exclusive worldwide license to use this technology. The current project is part of a three-phase demonstration program to evaluate the effectiveness of the GeoMelt R SPV TM process to treat waste contained in vertical pipe units (VPUs) and caissons that were used for the disposal of remote handled transuranic wastes located at Hanford's 618-10 and 618-11 burial grounds. This project is being performed for the US Department of Energy (DOE) for use at the Hanford site and other DOE installations. The Phase I evaluation determined that removal and treatment of the 618-10/11 VPUs are beyond what can be safely accomplished using conventional excavation methods. Accordingly, a careful stepwise non-intrusive delineation approach and treatment using the GeoMelt R SPV TM technology, followed by removal, characterization, and disposal of the resulting inert vitrified mass was identified as the preferred alternative. Phase II of the project, which started in July 2004, included a full-scale non-radioactive demonstration of AMEC's GeoMelt R SPV TM process on a mock VPU configured to match the actual VPUs. The non-radioactive demonstration (completed in May 2005) was performed to confirm the approach and design before proceeding to a radioactive ('hot') demonstration on an actual VPU. This demonstration took approximately 130 hours, processed the entire mock VPU, and resulted in a vitrified monolith weighing an estimated 90 tonnes. [1] Plans for a radioactive demonstration on an actual VPU are being developed for CY 2006. In addition to demonstrating GeoMelt R SPV TM , delineation techniques are being

  7. Characterization of mixed CH-TRU waste for the WIPP Experimental Test Program conducted at ANL-W

    Energy Technology Data Exchange (ETDEWEB)

    Dwight, C.C.; McClellan, G.C.; Guay, K.P. [Argonne National Lab., Idaho Falls, ID (United States); Courtney, J.C. [Louisiana State Univ., Baton Rouge, LA (United States); Duff, M.J. [Consolidated Technical Services, Inc., Walkersville, MD (United States)

    1992-02-01

    Argonne National Laboratory is participating in the Department of Energy`s Waste Isolation Pilot Plant (WIPP) Experimental Test Program by characterizing and repackaging mixed contact-handled transuranic waste. Characterization activities include gas sampling the waste containers, visually examining the waste contents, categorizing the contents according to their gas generation potentials, and weighing the contents. The waste is repackaged from 0.21m{sup 3} (55 gallon) drums into instrumented steel test bins which can hold up to six drum-equivalents in volume. Eventually the loaded test bins will be shipped to WIPP where they will be evaluated during a five-year test program. Three test bins of inorganic solids (primarily glass) were prepared between March and September 1991 and are ready for shipment to WIPP. The characterization activities confirmed process knowledge of the waste and verified the nondestructive examinations; the gas sample analyses showed the target constituents to be within allowable regulatory limits. A new waste characterization chamber is being developed at ANL-W which will improve worker safety, decrease the potential for contamination spread, and increase the waste characterization throughput. The new facility is expected to begin operations by Fall 1992. A comprehensive summary of the project is contained herein.

  8. Characterization of mixed CH-TRU waste for the WIPP Experimental Test Program conducted at ANL-W

    Energy Technology Data Exchange (ETDEWEB)

    Dwight, C.C.; McClellan, G.C.; Guay, K.P. (Argonne National Lab., Idaho Falls, ID (United States)); Courtney, J.C. (Louisiana State Univ., Baton Rouge, LA (United States)); Duff, M.J. (Consolidated Technical Services, Inc., Walkersville, MD (United States))

    1992-01-01

    Argonne National Laboratory is participating in the Department of Energy's Waste Isolation Pilot Plant (WIPP) Experimental Test Program by characterizing and repackaging mixed contact-handled transuranic waste. Characterization activities include gas sampling the waste containers, visually examining the waste contents, categorizing the contents according to their gas generation potentials, and weighing the contents. The waste is repackaged from 0.21m{sup 3} (55 gallon) drums into instrumented steel test bins which can hold up to six drum-equivalents in volume. Eventually the loaded test bins will be shipped to WIPP where they will be evaluated during a five-year test program. Three test bins of inorganic solids (primarily glass) were prepared between March and September 1991 and are ready for shipment to WIPP. The characterization activities confirmed process knowledge of the waste and verified the nondestructive examinations; the gas sample analyses showed the target constituents to be within allowable regulatory limits. A new waste characterization chamber is being developed at ANL-W which will improve worker safety, decrease the potential for contamination spread, and increase the waste characterization throughput. The new facility is expected to begin operations by Fall 1992. A comprehensive summary of the project is contained herein.

  9. Characterization of mixed CH-TRU waste for the WIPP Experimental Test Program conducted at ANL-W

    International Nuclear Information System (INIS)

    Dwight, C.C.; McClellan, G.C.; Guay, K.P.; Courtney, J.C.; Duff, M.J.

    1992-01-01

    Argonne National Laboratory is participating in the Department of Energy's Waste Isolation Pilot Plant (WIPP) Experimental Test Program by characterizing and repackaging mixed contact-handled transuranic waste. Characterization activities include gas sampling the waste containers, visually examining the waste contents, categorizing the contents according to their gas generation potentials, and weighing the contents. The waste is repackaged from 0.21m 3 (55 gallon) drums into instrumented steel test bins which can hold up to six drum-equivalents in volume. Eventually the loaded test bins will be shipped to WIPP where they will be evaluated during a five-year test program. Three test bins of inorganic solids (primarily glass) were prepared between March and September 1991 and are ready for shipment to WIPP. The characterization activities confirmed process knowledge of the waste and verified the nondestructive examinations; the gas sample analyses showed the target constituents to be within allowable regulatory limits. A new waste characterization chamber is being developed at ANL-W which will improve worker safety, decrease the potential for contamination spread, and increase the waste characterization throughput. The new facility is expected to begin operations by Fall 1992. A comprehensive summary of the project is contained herein

  10. Design and construction of a 208-L drum containing representative LLNL transuranic and low-level wastes

    International Nuclear Information System (INIS)

    Camp, D.C.; Pickering, J.; Martz, H.E.

    1994-01-01

    At the Lawrence Livermore National Laboratory (LLNL), we are developing the nondestructive analysis (NDA) technique of active (A) computed tomography (CT) to measure waste matrix attenuation as a function of gamma-ray energy (ACT); and passive. (P) Cr to locate and identify all gamma-ray emitting isotopes within a waste container. Coupling the ACT and PCT results will quantify each isotope identified, thereby categorize the amount of radioactivity within waste drums having volumes up to 416-liters (L), i.e., 110-gallon drums

  11. Waste Inspection Tomography (WIT)

    International Nuclear Information System (INIS)

    Bernardi, R.T.

    1995-01-01

    Waste Inspection Tomography (WIT) provides mobile semi-trailer mounted nondestructive examination (NDE) and assay (NDA) for nuclear waste drum characterization. WIT uses various computed tomography (CT) methods for both NDE and NDA of nuclear waste drums. Low level waste (LLW), transuranic (TRU), and mixed radioactive waste can be inspected and characterized without opening the drums. With externally transmitted x-ray NDE techniques, WIT has the ability to identify high density waste materials like heavy metals, define drum contents in two- and three-dimensional space, quantify free liquid volumes through density and x-ray attenuation coefficient discrimination, and measure drum wall thickness. With waste emitting gamma-ray NDA techniques, WIT can locate gamma emitting radioactive sources in two- and three-dimensional space, identify gamma emitting isotopic species, identify the external activity levels of emitting gamma-ray sources, correct for waste matrix attenuation, provide internal activity approximations, and provide the data needed for waste classification as LLW or TRU. The mobile feature of WIT allows inspection technologies to be brought to the nuclear waste drum storage site without the need to relocate drums for safe, rapid, and cost-effective characterization of regulated nuclear waste. The combination of these WIT characterization modalities provides the inspector with an unprecedented ability to non-invasively characterize the regulated contents of waste drums as large as 110 gallons, weighing up to 1,600 pounds. Any objects that fit within these size and weight restrictions can also be inspected on WIT, such as smaller waste bags and drums that are five and thirty-five gallons

  12. Seawater corrosion tests for low-level radioactive waste drum containers

    International Nuclear Information System (INIS)

    Maeda, Sho; Wadachi, Yoshiki

    1985-11-01

    This report is a part of corrosion tests of drums under various environmental conditions (seawater, river water, coastal sand, inland soil and indoor and outdoor atmosphere) done at Japan Atomic Energy Research Institute sponsored by the Science and Technology Agency. The corrosion tests were started in November, 1977 and complated at March, 1984. This report describes the results of the seawater corrosion tests which are part of the final report, ''Corrosion Safety Demonstration Test'' (Japanese), and it is expected to contribute the safety assessment of sea dumping of low-level radioactive waste packages. (author)

  13. The potential use of transmission tomographic techniques for the quality checking of cemented waste drums

    International Nuclear Information System (INIS)

    Huddleston, J.; Hutchinson, I.G.

    1986-01-01

    In support of the programme for the quality checking of encapsulated intermediate level waste, the possibilities of using transmission tomographic techniques for the determination of the physical properties of the drum are being considered. A literature survey has been undertaken and the possibilities of extracting data from video recordings of real time radiographs are considered. This work was carried out with financial support from British Nuclear Fuels plc and the UK Department of the Environment. In the DoE context, the results will be used in the formulation of Government Policy, but at this stage they do not necessarily represent Government Policy. (author)

  14. Gamma-ray spectrometry combined with acceptable knowledge (GSAK). A technique for characterization of certain remote-handled transuranic (RH-TRU) wastes. Part 1. Methodology and techniques

    International Nuclear Information System (INIS)

    Hartwell, J.K.; McIlwain, M.E.

    2005-01-01

    Gamma-ray spectrometry combined with acceptable knowledge (GSAK) is a technique for the characterization of certain remote-handled transuranic (RH-TRU) wastes. GSAK uses gamma-ray spectrometry to quantify a portion of the fission product inventory of RH-TRU wastes. These fission product results are then coupled with calculated inventories derived from acceptable process knowledge to characterize the radionuclide content of the assayed wastes. GSAK has been evaluated and tested through several test exercises. GSAK approach is described, while test results are presented in Part II. (author)

  15. Gamma-ray spectrometry combined with acceptable knowledge (GSAK). A technique for characterization of certain remote-handled transuranic (RH-TRU) wastes. Part 2. Testing and results

    International Nuclear Information System (INIS)

    Hartwell, J.K.; McIlwain, M.E.

    2005-01-01

    Gamma-ray spectrometry combined with acceptable knowledge (GSAK) is a technique for the characterization of certain remote-handled transuranic (RH-TRU) wastes. GSAK uses gamma-ray spectrometry to quantify a portion of the fission product inventory of RH-TRU wastes. These fission product results are then coupled with calculated inventories derived from acceptable process knowledge to characterize the radionuclide content of the assayed wastes. GSAK has been evaluated and tested through several test exercises. These tests and their results are described; while the former paper in this issue presents the methodology, equipment and techniques. (author)

  16. Combustion and fuel loading characteristics of Hanford Site transuranic solid waste

    International Nuclear Information System (INIS)

    Greenhalgh, W.O.

    1994-01-01

    The Waste Receiving and Processing (WRAP) Facility is being designed for construction in the north end of the Central Waste Complex. The WRAP Facility will receive, store, and process radioactive solid waste of both transuranic (TRU) and mixed waste (mixed radioactive-chemical waste) categories. Most of the waste is in 208-L (55-gal) steel drums. Other containers such as wood and steel boxes, and various sized drums will also be processed in the facility. The largest volume of waste and the type addressed in this report is TRU in 208-L (55-gal) drums that is scheduled to be processed in the Waste Receiving and Processing Facility Module 1 (WRAP 1). Half of the TRU waste processed by WRAP 1 is expected to be retrieved stored waste and the other half newly generated waste. Both the stored and new waste will be processed to certify it for permanent storage in the Waste Isolation Pilot Plant (WIPP) or disposal. The stored waste will go through a process of retrieval, examination, analysis, segregation, repackaging, relabeling, and documentation before certification and WIPP shipment. Newly generated waste should be much easier to process and certify. However, a substantial number of drums of both retrievable and newly generated waste will require temporary storage and handling in WRAP. Most of the TRU waste is combustible or has combustible components. Therefore, the presence of a substantial volume of drummed combustible waste raises concern about fire safety in WRAP and similar waste drum storage facilities. This report analyzes the fire related characteristics of the expected WRAP TRU waste stream

  17. Metrological tests of a 200 L calibration source for HPGE detector systems for assay of radioactive waste drums.

    Science.gov (United States)

    Boshkova, T; Mitev, K

    2016-03-01

    In this work we present test procedures, approval criteria and results from two metrological inspections of a certified large volume (152)Eu source (drum about 200L) intended for calibration of HPGe gamma assay systems used for activity measurement of radioactive waste drums. The aim of the inspections was to prove the stability of the calibration source during its working life. The large volume source was designed and produced in 2007. It consists of 448 identical sealed radioactive sources (modules) apportioned in 32 transparent plastic tubes which were placed in a wooden matrix which filled the drum. During the inspections the modules were subjected to tests for verification of their certified characteristics. The results show a perfect compliance with the NIST basic guidelines for the properties of a radioactive certified reference material (CRM) and demonstrate the stability of the large volume CRM-drum after 7 years of operation. Copyright © 2015 Elsevier Ltd. All rights reserved.

  18. TRU partnership-benefits to the national TRU program

    International Nuclear Information System (INIS)

    Lippis, J.; Lott, S.A.

    1995-01-01

    Because increased regulatory authority has been given to the states, the management of transuranic (TRU) wastes varies considerably. One effective tool for facilitating better communications, coordination, and cooperation among the generator/storage sites is the formation of topic specific interface working groups. The National TRU Program supports these groups, and in 1994, a policy was adopted to manage these interface working groups

  19. Analytical Chemistry and Materials Characterization Results for Debris Recovered from Nitrate Salt Waste Drum S855793

    Energy Technology Data Exchange (ETDEWEB)

    Martinez, Patrick Thomas [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Chamberlin, Rebecca M. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Schwartz, Daniel S. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Worley, Christopher Gordon [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Garduno, Katherine [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Lujan, Elmer J. W. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Borrego, Andres Patricio [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Castro, Alonso [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Colletti, Lisa Michelle [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Fulwyler, James Brent [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Holland, Charlotte S. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Keller, Russell C. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Klundt, Dylan James [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Martinez, Alexander [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Martin, Frances Louise [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Montoya, Dennis Patrick [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Myers, Steven Charles [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Porterfield, Donivan R. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Schake, Ann Rene [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Schappert, Michael Francis [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Soderberg, Constance B. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Spencer, Khalil J. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Stanley, Floyd E. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Thomas, Mariam R. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Townsend, Lisa Ellen [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Xu, Ning [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2015-09-16

    Solid debris was recovered from the previously-emptied nitrate salt waste drum S855793. The bulk sample was nondestructively assayed for radionuclides in its as-received condition. Three monoliths were selected for further characterization. Two of the monoliths, designated Specimen 1 and 3, consisted primarily of sodium nitrate and lead nitrate, with smaller amounts of lead nitrate oxalate and lead oxide by powder x-ray diffraction. The third monolith, Specimen 2, had a complex composition; lead carbonate was identified as the predominant component, and smaller amounts of nitrate, nitrite and carbonate salts of lead, magnesium and sodium were also identified. Microfocused x-ray fluorescence (MXRF) mapping showed that lead was ubiquitous throughout the cross-sections of Specimens 1 and 2, while heteroelements such as potassium, calcium, chromium, iron, and nickel were found in localized deposits. MXRF examination and destructive analysis of fragments of Specimen 3 showed elevated concentrations of iron, which were broadly distributed through the sample. With the exception of its high iron content and low carbon content, the chemical composition of Specimen 3 was within the ranges of values previously observed in four other nitrate salt samples recovered from emptied waste drums.

  20. X-Ray, Digital Imaging with Volumetric Density Measurement and Profiling, Applied to the Characterization of Waste Drums

    International Nuclear Information System (INIS)

    Huhtiniemi, I.; Gupta, N.; Halliwell, S.

    2006-01-01

    The European Commission's Joint Research Centre Ispra Site (JRC-Ispra) has initiated a decommissioning and waste management program that will span about two decades. The program includes a requirement to characterize the contents of about 6,500 radioactive, 220 litre waste drums whose documented history is incomplete. To render the characterization process more efficient, the drums will be initially divided into homogeneous groups, an activity that will be based on existing documentation and non-destructive examination (NDE) by X-ray digital imaging. This paper describes the X-ray imaging techniques chosen, and the planned performance validation of the equipment. (authors)

  1. 1994 Solid waste forecast container volume summary

    International Nuclear Information System (INIS)

    Templeton, K.J.; Clary, J.L.

    1994-09-01

    This report describes a 30-year forecast of the solid waste volumes by container type. The volumes described are low-level mixed waste (LLMW) and transuranic/transuranic mixed (TRU/TRUM) waste. These volumes and their associated container types will be generated or received at the US Department of Energy Hanford Site for storage, treatment, and disposal at Westinghouse Hanford Company's Solid Waste Operations Complex (SWOC) during a 30-year period from FY 1994 through FY 2023. The forecast data for the 30-year period indicates that approximately 307,150 m 3 of LLMW and TRU/TRUM waste will be managed by the SWOC. The main container type for this waste is 55-gallon drums, which will be used to ship 36% of the LLMW and TRU/TRUM waste. The main waste generator forecasting the use of 55-gallon drums is Past Practice Remediation. This waste will be generated by the Environmental Restoration Program during remediation of Hanford's past practice sites. Although Past Practice Remediation is the primary generator of 55-gallon drums, most waste generators are planning to ship some percentage of their waste in 55-gallon drums. Long-length equipment containers (LECs) are forecasted to contain 32% of the LLMW and TRU/TRUM waste. The main waste generator forecasting the use of LECs is the Long-Length Equipment waste generator, which is responsible for retrieving contaminated long-length equipment from the tank farms. Boxes are forecasted to contain 21% of the waste. These containers are primarily forecasted for use by the Environmental Restoration Operations--D ampersand D of Surplus Facilities waste generator. This waste generator is responsible for the solid waste generated during decontamination and decommissioning (D ampersand D) of the facilities currently on the Surplus Facilities Program Plan. The remaining LLMW and TRU/TRUM waste volume is planned to be shipped in casks and other miscellaneous containers

  2. Low-level waste drum staging building at Weapons Engineering Tritium Facility, TA-16, Los Alamos National Laboratory, Los Alamos, New Mexico. Environmental Assessment

    International Nuclear Information System (INIS)

    1994-08-01

    The proposed action is to place a 3 meter (m) by 4.5 m (10 ft x 15 ft) prefabricated storage building (transportainer) adjacent to the existing Weapons Engineering Tritium Facility (WETF) at Technical Area (TA-) 16, Los Alamos National Laboratory (LANL), and to use the building as a staging site for sealed 55 galllon drums of noncompactible waste contaminated with low levels of tritium (LLW). Up to eight drums of waste would be accumulated before the waste is moved by LANL Waste Management personnel to the existing on-site LLW disposal area at TA-54. The drum staging building would be placed on a bermed asphalt pad, near other existing accumulation structures for office trash and compactible LLW. The no-action alternative is to continue storing drums of LLW in the WETF laboratories where they occupy valuable work space, hamper movement of personnel and equipment, and require waste management personnel to enter those laboratories in order to remove filled drums. No new waste would be generated by implementing the proposed action; no changes or increases in WETF operations or waste production rate are anticipated as a result of staging drums of LLW outside the main laboratory building. The site for the LLW drum staging building would not impact any sensitive areas. Tritium emissions from the drums of LLW were included within the source term for normal operations at the WETF; the cumulative impacts would not be increased

  3. Determination of the germanium detector efficiency for measurements of the radionuclide activity contained in a radioactive waste drum

    International Nuclear Information System (INIS)

    Rodenas, J.; Gallardo, S.; Ballester, S.; Hoyler, F.

    2006-01-01

    One of the features in the characterization of a drum containing radioactive wastes is to verify the activity of radionuclides contained in the drum. An H.P. Ge detector can be used for this measurement. However, it is necessary to perform an efficiency calibration for all geometries involved. In the framework of a joint project between the Departamento de Ingenieria Quimica y Nuclear (Universidad Politecnica de Valencia, Spain) and the Fachbereich Angewandte Naturwissenschaften und Technik (Fachhochschule Aachen, Abteilung Julich, Germany), different configurations for a drum containing radioactive sources have been implemented in the laboratory. A cylindrical drum of 850 mm height, a diameter equal to 560 mm and 3 mm of steel thickness has been used in the experimental measurements. The drum contains a clay ceramic matrix whose chemical composition is 55% SiO 2 , 40% of Al 2 O 3 and 5% of TiO 2 . Several vertical PVC tubes having a diameter of 30 mm are inserted in the drum at different distances from the central axis. In the experiment, a pack of point sources with 133 Ba, 60 Co and 137 Cs is introduced into each one of the tubes. A ring-shape distributed source is generated by rotating the drum around its axis during the measurement. The detector efficiency is determined experimentally for these configurations. On the other hand, a Monte Carlo model, using the M.C.N.P. code, has been developed to simulate the drum, the clay matrix and the PVC tubes. The effect of the drum spinning has been reproduced simulating a ring source with different diameters. The model also includes detailed detector geometry. Using this Monte Carlo model, the detector efficiency is calculated for each configuration implemented in the laboratory. Comparison of results from Monte Carlo simulation and experimental measurements should permit the validation of the M.C.N.P. model. Consequently it will be possible to obtain efficiency curves without experimental measurements. Therefore, these

  4. Metrological tests of a 200 L calibration source for HPGE detector systems for assay of radioactive waste drums

    International Nuclear Information System (INIS)

    Boshkova, T.; Mitev, K.

    2016-01-01

    In this work we present test procedures, approval criteria and results from two metrological inspections of a certified large volume "1"5"2Eu source (drum about 200 L) intended for calibration of HPGe gamma assay systems used for activity measurement of radioactive waste drums. The aim of the inspections was to prove the stability of the calibration source during its working life. The large volume source was designed and produced in 2007. It consists of 448 identical sealed radioactive sources (modules) apportioned in 32 transparent plastic tubes which were placed in a wooden matrix which filled the drum. During the inspections the modules were subjected to tests for verification of their certified characteristics. The results show a perfect compliance with the NIST basic guidelines for the properties of a radioactive certified reference material (CRM) and demonstrate the stability of the large volume CRM-drum after 7 years of operation. - Highlights: • Large (200 L) volume drum source designed, produced and certified as CRM in 2007. • Source contains 448 identical sealed radioactive "1"5"2Eu sources (modules). • Two metrological inspections in 2011 and 2014. • No statistically significant changes of the certified characteristics over time. • Stable calibration source for HPGe-gamma radioactive waste assay systems.

  5. Waste inspection tomography (WIT)

    Energy Technology Data Exchange (ETDEWEB)

    Bernardi, R.T. [Bio-Imaging Research, Inc., Lincolnshire, IL (United States)

    1995-10-01

    Waste Inspection Tomography (WIT) provides mobile semi-trailer mounted nondestructive examination (NDE) and assay (NDA) for nuclear waste drum characterization. WIT uses various computed tomography (CT) methods for both NDE and NDA of nuclear waste drums. Low level waste (LLW), transuranic (TRU), and mixed radioactive waste can be inspected and characterized without opening the drums. With externally transmitted x-ray NDE techniques, WIT has the ability to identify high density waste materials like heavy metals, define drum contents in two- and three-dimensional space, quantify free liquid volumes through density and x-ray attenuation coefficient discrimination, and measure drum wall thickness. With waste emitting gamma-ray NDA techniques, WIT can locate gamma emitting radioactive sources in two- and three-dimensional space, identify gamma emitting, isotopic species, identify the external activity levels of emitting gamma-ray sources, correct for waste matrix attenuation, provide internal activity approximations, and provide the data needed for waste classification as LLW or TRU.

  6. Waste inspection tomography (WIT)

    International Nuclear Information System (INIS)

    Bernardi, R.T.

    1995-01-01

    Waste Inspection Tomography (WIT) provides mobile semi-trailer mounted nondestructive examination (NDE) and assay (NDA) for nuclear waste drum characterization. WIT uses various computed tomography (CT) methods for both NDE and NDA of nuclear waste drums. Low level waste (LLW), transuranic (TRU), and mixed radioactive waste can be inspected and characterized without opening the drums. With externally transmitted x-ray NDE techniques, WIT has the ability to identify high density waste materials like heavy metals, define drum contents in two- and three-dimensional space, quantify free liquid volumes through density and x-ray attenuation coefficient discrimination, and measure drum wall thickness. With waste emitting gamma-ray NDA techniques, WIT can locate gamma emitting radioactive sources in two- and three-dimensional space, identify gamma emitting, isotopic species, identify the external activity levels of emitting gamma-ray sources, correct for waste matrix attenuation, provide internal activity approximations, and provide the data needed for waste classification as LLW or TRU

  7. The differential dieaway technique applied to the measurement of the fissile content of drums of cement encapsulated waste

    International Nuclear Information System (INIS)

    Swinhoe, M.T.

    1986-01-01

    This report describes calculations of the differential dieaway technique as applied to cement encapsulated waste. The main difference from previous applications of the technique are that only one detector position is used (diametrically opposite the neutron source) and the chamber walls are made of concrete. The results show that by rotating the drum the response to fissile material across the central plane of the drum can be made relatively uniform. The absolute size of the response is about 0.4. counts per minute per gram fissile for a neutron source of 10 8 neutrons per second. Problems of neutron and gamma background and water content are considered. (author)

  8. High-Energy X-Ray Imaging Applied to Nondestructive Characterization of Large Nuclear Waste Drums

    Science.gov (United States)

    Estre, Nicolas; Eck, Daniel; Pettier, Jean-Luc; Payan, Emmanuel; Roure, Christophe; Simon, Eric

    2015-12-01

    As part of its R&D programs on non-destructive testing of nuclear waste drums, CEA is commissioning an irradiation cell named CINPHONIE, at Cadarache. This cell allows high-energy imaging (radiography and tomography) on large volumes (up to 5 m3) and heavy weights (up to 5 tons). A demonstrator has been finalized, based on existing components. The X-ray source is a 9 MeV LINAC which produces Bremsstrahlung X-rays (up to 23 Gy/min at 1 meter in the beam axis). The mechanical bench is digitally controlled on three axes (translation, rotation, elevation) and can handle objects up to 2 t. This bench performs trajectories necessary for acquisition of projections (sinograms) according to different geometries: Translation-Rotation, Fan-Beam and Cone-Beam. Two detection systems both developed by CEA-Leti are available. The first one is a large GADOX scintillating screen ( 800 ×600 mm2) coupled to a low-noise pixelated camera. The second one is a multi-CdTe semiconductor detector, offering measurements up to 5 decades of attenuation (equivalent to 25 cm of lead or 180 cm of standard concrete). At the end of the acquisition, a Filtered Back Projection-based algorithm is performed. Then, a density slice (fan-beam tomography) or a density volume (cone-beam tomography or helical tomography) is produced and used to examine the waste. Characterization of LINAC, associated detectors as well as the full acquisition chain, are presented. Experimental performances on phantoms and real drum are discussed and expected limits on defect detectability are evaluated by simulation. The final system, designed to handle objects up to 5 tons is then presented.

  9. Development of the ''measurement and sorting'' device for bituminized waste drums at Cogema Marcoule

    International Nuclear Information System (INIS)

    Chabalier, B.; Artaud, J.L.; Perot, B.; Passard, C.; Romeyer Dherbey, J.; Raoux, A.; Misraki, J.

    2000-01-01

    This programme is included in the scope of a specific task to retrieve bituminized waste drums stored on the Marcoule site. The objective is to define a non-destructive nuclear measurement facility that makes it possible to: - sort the packages stored on the site according to the radiological acceptance criteria for the waste packages in the surface storage facility, - establish the β and α activities of the packages to be stored in the surface storage facility, - estimate the activity of the packages that will be stored in the ''Entreposage Intermediaire Polyvalent'' (multiple purpose intermediate storage) built on the Marcoule site. A measurement facility, with measurement times compatible with the industrial flow of retrieval of the waste drums was studied, developed and will be validated. It features gamma spectrometry measurements and neutron measurement devices, associated to an imaging device by photonic transmission and an expert system. Studies associated to the definition of this facility mainly concern: - the imaging station: it enables to know up to what height the packages are filled, the actual density of the matrix, and to detect lacks of homogeneity. These data are required for a correct analysis of the neutron or gamma measurements and to minimise uncertainties, - the interpretation of active neutron measurement signals: a simultaneous detection of the prompt and delayed neutrons makes it possible to differentiate the masses of U-235 and of Pu-239 present in the packages, - the reduction of the detection limits: to that end, an ''asti-Compton'' detector was defined providing a gain on the detection limits at low energies according to the type of GeHP semi-conductor detector. - the expert system which performs the interpretation and coupling of measured data with data coming from the waste production files in order to determine the activity of the β γ, pure β and α radionuclides at 300 years. The validation program that will be conducted on a

  10. First Industrial Tests of a Matrix Monitor Correction for the Differential Die-away Technique of Historical Waste Drums

    Energy Technology Data Exchange (ETDEWEB)

    Antoni, Rodolphe; Passard, Christian; Perot, Bertrand [CEA Cadarache DEN/Nuclear Measurement Laboratory, 13108 Saint-Paul lez Durance (France); Batifol, Marc; Vandamme, Jean-Christophe [Nuclear Measurement Team, AREVA NC, La Hague plant F-50444 Beaumont-Hague (France); Grassi, Gabriele [AREVA NC, 1 place Jean-Millier, 92084 Paris-La-Defense cedex (France)

    2015-07-01

    The fissile mass in radioactive waste drums filled with compacted metallic residues (spent fuel hulls and nozzles) produced at AREVA NC La Hague reprocessing plant is measured by neutron interrogation with the Differential Die-away measurement Technique (DDT). In the next years, old hulls and nozzles mixed with Ion-Exchange Resins will be measured. The ion-exchange resins increase neutron moderation in the matrix, compared to the waste measured in the current process. In this context, the Nuclear Measurement Laboratory (LMN) of CEA Cadarache has studied a matrix effect correction method, based on a drum monitor, namely a 3He proportional counter located inside the measurement cavity. After feasibility studies performed with LMN's PROMETHEE 6 laboratory measurement cell and with MCNPX simulations, this paper presents first experimental tests performed on the industrial ACC (hulls and nozzles compaction facility) measurement system. A calculation vs. experiment benchmark has been carried out by performing dedicated calibration measurements with a representative drum and {sup 235}U samples. The comparison between calculation and experiment shows a satisfactory agreement for the drum monitor. The final objective of this work is to confirm the reliability of the modeling approach and the industrial feasibility of the method, which will be implemented on the industrial station for the measurement of historical wastes. (authors)

  11. First Industrial Tests of a Matrix Monitor Correction for the Differential Die-away Technique of Historical Waste Drums

    International Nuclear Information System (INIS)

    Antoni, Rodolphe; Passard, Christian; Perot, Bertrand; Batifol, Marc; Vandamme, Jean-Christophe; Grassi, Gabriele

    2015-01-01

    The fissile mass in radioactive waste drums filled with compacted metallic residues (spent fuel hulls and nozzles) produced at AREVA NC La Hague reprocessing plant is measured by neutron interrogation with the Differential Die-away measurement Technique (DDT). In the next years, old hulls and nozzles mixed with Ion-Exchange Resins will be measured. The ion-exchange resins increase neutron moderation in the matrix, compared to the waste measured in the current process. In this context, the Nuclear Measurement Laboratory (LMN) of CEA Cadarache has studied a matrix effect correction method, based on a drum monitor, namely a 3He proportional counter located inside the measurement cavity. After feasibility studies performed with LMN's PROMETHEE 6 laboratory measurement cell and with MCNPX simulations, this paper presents first experimental tests performed on the industrial ACC (hulls and nozzles compaction facility) measurement system. A calculation vs. experiment benchmark has been carried out by performing dedicated calibration measurements with a representative drum and 235 U samples. The comparison between calculation and experiment shows a satisfactory agreement for the drum monitor. The final objective of this work is to confirm the reliability of the modeling approach and the industrial feasibility of the method, which will be implemented on the industrial station for the measurement of historical wastes. (authors)

  12. Re-evaluation of the 1995 Hanford Large Scale Drum Fire Test Results

    International Nuclear Information System (INIS)

    Yang, J M

    2007-01-01

    A large-scale drum performance test was conducted at the Hanford Site in June 1995, in which over one hundred (100) 55-gal drums in each of two storage configurations were subjected to severe fuel pool fires. The two storage configurations in the test were pallet storage and rack storage. The description and results of the large-scale drum test at the Hanford Site were reported in WHC-SD-WM-TRP-246, ''Solid Waste Drum Array Fire Performance,'' Rev. 0, 1995. This was one of the main references used to develop the analytical methodology to predict drum failures in WHC-SD-SQA-ANAL-501, 'Fire Protection Guide for Waste Drum Storage Array,'' September 1996. Three drum failure modes were observed from the test reported in WHC-SD-WM-TRP-246. They consisted of seal failure, lid warping, and catastrophic lid ejection. There was no discernible failure criterion that distinguished one failure mode from another. Hence, all three failure modes were treated equally for the purpose of determining the number of failed drums. General observations from the results of the test are as follows: (lg b ullet) Trash expulsion was negligible. (lg b ullet) Flame impingement was identified as the main cause for failure. (lg b ullet) The range of drum temperatures at failure was 600 C to 800 C. This is above the yield strength temperature for steel, approximately 540 C (1,000 F). (lg b ullet) The critical heat flux required for failure is above 45 kW/m 2 . (lg b ullet) Fire propagation from one drum to the next was not observed. The statistical evaluation of the test results using, for example, the student's t-distribution, will demonstrate that the failure criteria for TRU waste drums currently employed at nuclear facilities are very conservative relative to the large-scale test results. Hence, the safety analysis utilizing the general criteria described in the five bullets above will lead to a technically robust and defensible product that bounds the potential consequences from postulated

  13. IMPROVEMENTS IN CONTAINER MANAGEMENT OF TRANSURANIC (TRU) AND LOW LEVEL RADIOACTIVE WASTE STORED AT THE CENTRAL WASTE COMPLEX (CWC) AT HANFORD

    International Nuclear Information System (INIS)

    UYTIOCO EM

    2007-01-01

    The Central Waste Complex (CWC) is the interim storage facility for Resource Conservation and Recovery Act (RCRA) mixed waste, transuranic waste, transuranic mixed waste, low-level and low-level mixed radioactive waste at the Department of Energy's (DOE'S) Hanford Site. The majority of the waste stored at the facility is retrieved from the low-level burial grounds in the 200 West Area at the Site, with minor quantities of newly generated waste from on-site and off-site waste generators. The CWC comprises 18 storage buildings that house 13,000 containers. Each waste container within the facility is scanned into its location by building, module, tier and position and the information is stored in a site-wide database. As waste is retrieved from the burial grounds, a preliminary non-destructive assay is performed to determine if the waste is transuranic (TRU) or low-level waste (LLW) and subsequently shipped to the CWC. In general, the TRU and LLW waste containers are stored in separate locations within the CWC, but the final disposition of each waste container is not known upon receipt. The final disposition of each waste container is determined by the appropriate program as process knowledge is applied and characterization data becomes available. Waste containers are stored within the CWC based on their physical chemical and radiological hazards. Further segregation within each building is done by container size (55-gallon, 85-gallon, Standard Waste Box) and waste stream. Due to this waste storage scheme, assembling waste containers for shipment out of the CWC has been time consuming and labor intensive. Qualitatively, the ratio of containers moved to containers in the outgoing shipment has been excessively high, which correlates to additional worker exposure, shipment delays, and operational inefficiencies. These inefficiencies impacted the LLW Program's ability to meet commitments established by the Tri-Party Agreement, an agreement between the State of Washington

  14. Feasibility of composting combinations of sewage sludge, olive mill waste and winery waste in a rotary drum reactor.

    Science.gov (United States)

    Fernández, Francisco J; Sánchez-Arias, Virginia; Rodríguez, Lourdes; Villaseñor, José

    2010-10-01

    Representative samples of the following biowastes typically generated in Castilla La Mancha (Spain) were composted using a pilot-scale closed rotary drum composting reactor provided with adequate control systems: waste from the olive oil industry (olive mill waste; OMW), winery-distillery waste containing basically grape stalk and exhausted grape marc (WDW), and domestic sewage sludge. Composting these biowastes was only successful when using a bulking agent or if sufficient porosity was supported. OMW waste composting was not possible, probably because of its negligible porosity, which likely caused anaerobic conditions. WDW was successfully composted using a mixture of solid wastes generated from the same winery. SS was also successfully composted, although its higher heavy metal content was a limitation. Co-composting was an adequate strategy because the improved mixture characteristics helped to maintain optimal operating conditions. By co-composting, the duration of the thermophilic period increased, the final maturity level improved and OMW was successfully composted. Using the proposed reactor, composting could be accelerated compared to classical outdoor techniques, enabling easy control of the process. Moisture could be easily controlled by wet air feeding and leachate recirculation. Inline outlet gas analysis helped to control aerobic conditions without excessive aeration. The temperature reached high values in a few days, and sufficient thermal requirements for pathogen removal were met. The correct combination of biowastes along with appropriate reactor design would allow composting as a management option for such abundant biowastes in this part of Spain. (c) 2010 Elsevier Ltd. All rights reserved.

  15. Development of waste packages for the long-term confinement of C-14 in TRU waste disposal. 2. Confinement container with titanium alloy

    International Nuclear Information System (INIS)

    Nakamura, Ario; Owada, Hitoshi; Asano, Hidekazu; Jintoku, Takashi; Nakayama, Gen

    2008-01-01

    The long-term integrity of TRU waste package, with a titanium alloy for the outer corrosion resistance layer and carbon steel for the inner structural vessel, has been evaluated. The target confinement period is settled at 60,000 years in this study (i.e., 10 times of half-life). So the outer corrosion resistance layer with titanium (Ti-Pd alloy) is developed through focus on the high corrosion resistance of Ti alloy as a technology that has long-term confinement. In investigation about integrity of its passive film, the thickness of corrosion layer of 60,000 years is calculated by building an empirical formula between temperature and corrosion current density, considering the results of constant voltage examination in the TRU waste repository assumed environment. About crevice corrosion, its occurrence conditions is investigated in the TRU waste repository assumed environment, then, Ti.Gr-17 is selected as candidate material of the corrosion resistance layer. In investigation about SCC in Ti alloy, using the models of growth of hydride-layer, the thickness of hydride-layer after 60,000 years is estimated by the results of constant currents tests. Then, the hydride-layer of this thickness is confirmed not to generate cracks, in consideration of destructive critical hydride cracking thickness and the models of crack propagation. The knowledge that the process of generation of hydrogenated layers changes with differences in acceleration conditions (i.e., current density) is obtained. So we must confirm the adequacy of this model by the examination with natural condition. (author)

  16. Final Hanford Site Transuranic (TRU) Waste Characterization Quality Assurance Project Plan

    International Nuclear Information System (INIS)

    GREAGER, T.M.

    1999-01-01

    The Transuranic Waste Characterization Quality Assurance Program Plan required each US Department of Energy (DOE) site that characterizes transuranic waste to be sent the Waste Isolation Pilot Plan that addresses applicable requirements specified in the QAPP

  17. Reliability evaluation methodologies for ensuring container integrity of stored transuranic (TRU) waste

    International Nuclear Information System (INIS)

    Smith, K.L.

    1995-06-01

    This report provides methodologies for providing defensible estimates of expected transuranic waste storage container lifetimes at the Radioactive Waste Management Complex. These methodologies can be used to estimate transuranic waste container reliability (for integrity and degradation) and as an analytical tool to optimize waste container integrity. Container packaging and storage configurations, which directly affect waste container integrity, are also addressed. The methodologies presented provide a means for demonstrating Resource Conservation and Recovery Act waste storage requirements

  18. Phenomenological study and modeling of tritium trapping in tritiated waste drums

    International Nuclear Information System (INIS)

    Le-Floch, Anais

    2016-01-01

    ITER (International Tokamak Experimental Reactor) is a fusion machine which should demonstrate scientific and technological feasibility of fusion energy by means of D-T fusion reaction. Therefore, most of the solid radioactive waste produced during operation and dismantling phase (around 34000 tons) will result not only from activation by 14 MeV neutrons, but also from contamination by tritium. One of the main issues in tritiated waste management is the confinement of tritium which presents a good ability to diffusion. One of the solutions is to trap the tritium directly in waste drums. In containers tritium is under gaseous form (HT and T_2), tritiated water vapor (HTO and T_2O) and organic bounded tritium species (OBT). as an hydrogen isotope, HT and T_2 trapping and conversion is possible thanks to a reaction with a mix of metal oxides MnO_2 and Ag_2O, which can be used for hydrogen hazards mitigation. an experimental study was conducted at the CEA on the study of tritium trapping by a mixture of 90% of manganese oxide and 10% of silver oxide. The tests showed that the addition of Pt and Pd catalysts did not improve the trapping capacity of the powder mixture, such as impregnation of the powder mixture when preparing the mixture, with solutions of KOH or NaOH. Crystal-chemical analysis revealed the formation of a mixed oxide in the preparation of powders, questioning the mechanisms previously established. Two new mechanisms have been proposed and a model on the trapping kinetics was presented. The results of modeling the competition between the trapping phenomenon and the diffusion of tritium through the wall of the waste package showed that the trapper decreased the value of the quantity of tritiated hydrogen degassed from the package. (author) [fr

  19. Research on changes of nitrate by interactions with metals under the wastes disposal environment containing TRU nuclide

    International Nuclear Information System (INIS)

    Wada, Ryutaro; Nishimura, Tsutomu; Masuda, Kaoru; Fujiwara, Kazuo; Imakita, Tsuyoshi; Tateishi, Tsuyoshi

    2003-02-01

    There exists the waste including a nitrate ion as a salt in the TRU waste materials. This nitrate ion can transferred to the nitrite ion and/or ammonia by reducing materials such as metals in the waste disposal environment, and has the possibility to affect on the disposal environment and nuclide transfer parameters. Therefore, electrochemical tests were conducted to evaluate the reaction rate parameters of the nitrate ion and metals under the low oxygen environment. The long-term reaction test using the glass-seal vessel was also conducted to grasp precisely the nitrate ion transition reaction rate and the gas generation rate caused by the reaction of metal and the nitrate ion coexist solution. (1) Reaction rate constants under various environments were obtained performing the potentiostatic holding tests with the parameters of the solution pH, temperature, and the nitrate and nitrite ion concentrations. The formula of the nitrate ion transition reaction rate was also examined based on these obtained data. (2) Conducting the immersion tests under the environment of the low oxygen and high-pH rainfall underground water site, the long-term reaction rate data were obtained on the reaction products (ammonia, hydrogen gas etc.) of metals (carbon steel, stainless steel and zircaloy etc.) with nitrate ion. The tests under the same conditions as in the past were also conducted to evaluate the test accuracy and error range of the long-term reaction test with the glass-seal vessels. (author)

  20. Annual technology assessment and progress report for the Buried Transuranic Waste Studies Program at the Idaho National Engineering Laboratory (1987)

    International Nuclear Information System (INIS)

    Loomis, G.G.; Low, J.O.

    1988-01-01

    This report presents FY-87 activities for the Buried Transuranic (TRU) Waste Studies Program at the Idaho National Engineering Laboratory (INEL). This program investigates techniques to provide long-term confinement of buried TRU waste, as well as methods of retrieval. The confinement method of in situ grouting was examined in a simulated shallow-land buried TRU waste pit constructed adjacent to the RWMC TRU waste burial pits. The in situ grouting technique involved an experimental dyanmic compaction process which simultaneously grouts and compacts the waste. The simulated waste pit consisted of regions of randomly dumped drums, stacked boxes, and stacked drums, thus representing the various conditions of buried waste at the RWMC. Simulated waste and airborne tracers were loaded into the various simulated buried waste containers. Pregrouting and post-grouting data, such as hydraulic conductivity, were obtained to assess the hydrological integrity of the grouted waste material. In addition, post-grouting destructive examinations were performed and the results analyzed. Retrieval and processing of the TRU buried waste is also being examined at the INEL. At a conceptual level, retrieval of TRU buried waste involves a movable containment building to confine airborne particulate, heavy equipment to remove the waste, processing equipment, and equipment to control the air quality within the building. Studies were performed in FY-87 to identify containment building requirements such as type, mobility, and ventilation. An experimental program to demonstrate the retrieval technique using existing INEL heavy equipment has also been identified. 11 refs., 17 figs., 11 tabs

  1. Final Hanford Site Transuranic (TRU) Waste Characterization Qualit Assurance Project Plan

    International Nuclear Information System (INIS)

    GREAGER, T.M.

    1999-01-01

    The Transuranic Waste Characterization Quality Assurance Program Plan required each U.S. Department of Energy (DOE) site that characterizes transuranic waste to be sent the Waste Isolation Pilot Plan that addresses applicable requirements specified in the quality assurance project plan (QAPP)

  2. Planning for the Management and Disposition of Newly Generated TRU Waste from REDC

    International Nuclear Information System (INIS)

    Coffey, D. E.; Forrester, T. W.; Krause, T.

    2002-01-01

    This paper describes the waste characteristics of newly generated transuranic waste from the Radiochemical Engineering and Development Center at the Oak Ridge National Laboratory and the basic certification structure that will be proposed by the University of Tennessee-Battelle and Bechtel Jacobs Company LLC to the Waste Isolation Pilot Plant for this waste stream. The characterization approach uses information derived from the active production operations as acceptable knowledge for the Radiochemical Engineering and Development Center transuranic waste. The characterization approach includes smear data taken from processing and waste staging hot cells, as well as analytical data on product and liquid waste streams going to liquid waste disposal. Bechtel Jacobs Company and University of Tennessee-Battelle are currently developing the elements of a Waste Isolation Pilot Plant-compliant program with a plan to be certified by the Waste Isolation Pilot Plant for shipment of newly generated transuranic waste in the next few years. The current activities include developing interface plans, program documents, and waste stream specific procedures

  3. Demonstration of remotely operated TRU waste size reduction and material handling equipment

    International Nuclear Information System (INIS)

    Looper, M.G.; Charlesworth, D.L.

    1988-01-01

    The Savannah River Laboratory (SRL) is developing remote size reduction and material handling equipment to prepare 238 Pu contaminated waste for permanent disposal at the Waste Isolation Pilot Plant (WIPP) in New Mexico. The waste is generated at the Savannah River Plant (SRP) from normal operation and decommissioning activity and is retrievably stored onsite. A Transuranic Waste Facility for preparing, size-reducing, and packaging this waste for disposal is scheduled for completion in 1995. A cold test facility for demonstrating the size reduction and material handling equipment was built, and testing began in January 1987. 9 figs., 1 tab

  4. NMT-7 plan for producing certifiable TRU debris waste for WIPP

    International Nuclear Information System (INIS)

    Montoya, A.J.

    1997-12-01

    Analysis of waste characterization data for debris items generated during a recent six month period indicates that the certifiability of TRUPACT II payload containers packaged at the Los Alamos National Laboratory Plutonium Facility (TA-55) can be increased from approximately 52% of solid waste payload containers to 78% by applying the simple strategies of screening out high decay heat items and sorting remaining items to maintain nuclear material loading at levels below WIPP waste acceptance limits. Implementation of these strategies will have negative impacts on waste minimization and waste management operations that must also be considered

  5. Comparison of slagging pyrolysis and molten salt incinerators for treating TRU waste at the INEL

    International Nuclear Information System (INIS)

    1977-11-01

    For the comparison, it is assumed that the waste product is required to meet the acceptance criteria of the Waste Isolation Pilot Plant, i.e., low leachability. Slagging pyrolysis incinerates combustible waste and melts noncombustible waste; the resulting slag forms a glass of low leachability. In the molten salt incinerator, combustion occurs at low temperatures with no accumulation of explosive gases, but the waste must have been previously sorted into combustibles and noncombustibles and then shredded. The economics, safety, and technical features are compared. Advantages, disadvantages, and areas of technical uncertainty of the two systems are listed. Development costs and schedules for the two types of incinerators are discussed

  6. Deep-Burn High Temperature Reactor - TRU Utilization and Nuclear Waste Management

    International Nuclear Information System (INIS)

    Tsvetkov, Pavel V.

    2013-01-01

    Summary of our historical and ongoing efforts: • We have a long history of R and Ds supporting DB-HTRs. Our R and Ds carry V and V and are consistent with ongoing benchmark efforts. • We are looking at DB-HTR configurations based on HTTR block and GA block (NGNP). Both offer advantages. • MAs as a Fuel lead to the designs of Ultra-Long Life VHTRs, which may be focused on Deep Burn or autonomy (not HLW management). • Our role in the Deep Burn Project R and D package was focused on 3D optimization and related software development. • Scenario studies towards an Environmentally Benign Sustainable and Secure Energy Source (integration of DB-HTRs within a fuel cycle) demonstrate advantages of DB-HTRs. • Advanced sensing and 3D mapping are of importance to DB-HTRs. • Fission product management in HTRs is a viable supplementary option in addition to their potential TRU management role in advanced fuel cycle scenarios

  7. Application of artificial neural networks on the characterization of radioactive waste drums; Aplicacao de redes neurais artificiais na caracterizacao de tambores de rejeito radioativo

    Energy Technology Data Exchange (ETDEWEB)

    Potiens Junior, Ademar Jose; Hiromoto, Goro, E-mail: apotiens@ipen.b, E-mail: hiromoto@ipen.b [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2011-10-26

    The methodology consist of system simulation of drum-detector by Monte Carlo for obtention of counting efficiency. The obtained data were treated and a neural artificial network (RNA) were constructed for evaluation of total activity of drum. For method evaluation measurements were performed in ten position parallel to the drum axis and the results submitted to the RNA. The developed methodology showed to be effective for isotopic characterization of gamma emitter radioactive wastes distributed in a heterogeneous way in a 200 litters drum. The objective of this work as to develop a methodology of analyse for quantification and localization of radionuclides not homogeneous distributed in a 200 liters drum based on the mathematical techniques

  8. Feasibility study of {sup 235}U and {sup 239}Pu characterization in radioactive waste drums using neutron-induced fission delayed gamma rays

    Energy Technology Data Exchange (ETDEWEB)

    Nicol, T. [CEA, DEN, Cadarache, Nuclear Measurement Laboratory, F-13108 Saint-Paul-lez-Durance (France); FZJ, Institute of Energy and Climate Research – Nuclear Waste Management and Reactor Safety, Wilhelm-Johnen-Straße, d-52425 Jülich (Germany); Pérot, B., E-mail: bertrand.perot@cea.fr [CEA, DEN, Cadarache, Nuclear Measurement Laboratory, F-13108 Saint-Paul-lez-Durance (France); Carasco, C. [CEA, DEN, Cadarache, Nuclear Measurement Laboratory, F-13108 Saint-Paul-lez-Durance (France); Brackx, E. [CEA, DEN, Marcoule, Metallography and Chemical Analysis Laboratory, F-30207 Bagnols-sur-Cèze (France); Mariani, A.; Passard, C. [CEA, DEN, Cadarache, Nuclear Measurement Laboratory, F-13108 Saint-Paul-lez-Durance (France); Mauerhofer, E. [FZJ, Institute of Energy and Climate Research – Nuclear Waste Management and Reactor Safety, Wilhelm-Johnen-Straße, d-52425 Jülich (Germany); Collot, J. [Laboratoire de Physique Subatomique et de Cosmologie, Université Grenoble Alpes, CNRS/IN2P3 Grenoble (France)

    2016-10-01

    This paper reports a feasibility study of {sup 235}U and {sup 239}Pu characterization in 225 L bituminized waste drums or 200 L concrete waste drums, by detecting delayed fission gamma rays between the pulses of a deuterium-tritium neutron generator. The delayed gamma yields were first measured with bare samples of {sup 235}U and {sup 239}Pu in REGAIN, a facility dedicated to the assay of 118 L waste drums by Prompt Gamma Neutron Activation Analysis (PGNAA) at CEA Cadarache, France. Detectability in the waste drums is then assessed using the MCNPX model of MEDINA (Multi Element Detection based on Instrumental Neutron Activation), another PGNAA cell dedicated to 200 L drums at FZJ, Germany. For the bituminized waste drum, performances are severely hampered by the high gamma background due to {sup 137}Cs, which requires the use of collimator and shield to avoid electronics saturation, these elements being very penalizing for the detection of the weak delayed gamma signal. However, for lower activity concrete drums, detection limits range from 10 to 290 g of {sup 235}U or {sup 239}Pu, depending on the delayed gamma rays of interest. These detection limits have been determined by using MCNPX to calculate the delayed gamma useful signal, and by measuring the experimental gamma background in MEDINA with a 200 L concrete drum mock-up. The performances could be significantly improved by using a higher interrogating neutron emission and an optimized experimental setup, which would allow characterizing nuclear materials in a wide range of low and medium activity waste packages.

  9. The nondestructive assay of 55-gallon drums containing uranium and transuranic waste using passive-active shufflers

    International Nuclear Information System (INIS)

    Rinard, P.M.; Adams, E.L.; Menlove, H.O.; Sprinkle, J.K. Jr.

    1992-11-01

    This study has been completed to characterize and improve the performance of passive-active neutron (PAN) shufflers in assaying 55gal. drums of nuclear facility waste for uranium and transuranic elements. Over 1700 active measurements and 800 passive measurements were made using 28 different matrices. Some of the matrices had homogeneous distributions of known amounts of moderating and absorbing materials, whereas others were less well characterized. Some of the well-characterized matrices simulate facility waste better than the others,especially matrices of paper, iron, polyethylene in nine different densities (with and without neutron poisons), alumina trap material, and concrete blocks

  10. The Transuranic Waste Program's integration and planning activities and the contributions of the TRU partnership

    International Nuclear Information System (INIS)

    Harms, T.C.; O'Neal, W.; Petersen, C.A.; McDonald, C.E.

    1994-02-01

    The Technical Support Division, EM-351 manages the integration and planning activities of the Transuranic Waste Program. The Transuranic Waste Program manager provides transuranic waste policy, guidance, and issue resolution to Headquarters and the Operations Offices. In addition, the program manager is responsible for developing and implementing an integrated, long-range waste management plan for the transuranic waste system. A steering committee, a core group of support contractors, and numerous interface working groups support the efforts of the program manager. This paper provides an overview of the US Department of Energy's transuranic waste integration activities and a long-range planning process that includes internal and external stakeholder participation. It discusses the contributions and benefits provided by the Transuranic Partnership, most significantly, the integration activities and the body of data collected and assembled by the Partnership

  11. Three dimensional reconstruction of activity profiles in 220 liters radioactive waste packages containing super-compacted 100 liters drums

    International Nuclear Information System (INIS)

    Van Velzen, L.P.M.; Maes, J.

    2007-01-01

    The 3DRedact project's main objective is the development of a non-destructive assay (NDA) system that can replace emission computer tomography (ECT) and transmission computer tomography (TCT) for the routine characterization of decayed radioactive waste 220 liters drums. The existing fast NDA scan system has been extended with a transmission system that fulfils the requirements of fast scan measurements. The design parameters and engineering are described. As a consequence of this extension the analyze program HOLIS had to be updated, so that HOLIS can make full advantage of the transmission data generated by the analysis of a 220 liters waste drum, containing different super compacted drums. The achievements of the new HOLIS version are presented. As a first assessment, based on the presented tests results, the accuracy of the calculated coordinates of hotspots can be assessed for all coordinates ± 1 cm and for the activity of the hot-spot ± 5 %. These accuracies are within the predefined requirements e.g. coordinates uncertainty ± 2 cm and activity less than 10 %. Further, additional safety systems have been installed to improve a healthy and save working environment. (authors)

  12. [TRU waste storage, technical data and calculations electropolishing, October 21, 1977--April 1978

    Energy Technology Data Exchange (ETDEWEB)

    Allen, R. P.

    1977-12-31

    This document contains copies of three reports on electropolishing. Electropolishing is a key step in the processing of solid wastes. It is the design basis for decontaminating alpha, as well as beta-gamma, waste metals in spite of incomplete data on the process and associated equipment.

  13. Preliminary report of the comparison of multiple non-destructive assay techniques on LANL Plutonium Facility waste drums

    International Nuclear Information System (INIS)

    Bonner, C.; Schanfein, M.; Estep, R.

    1999-01-01

    Prior to disposal, nuclear waste must be accurately characterized to identify and quantify the radioactive content. The DOE Complex faces the daunting task of measuring nuclear material with both a wide range of masses and matrices. Similarly daunting can be the selection of a non-destructive assay (NDA) technique(s) to efficiently perform the quantitative assay over the entire waste population. In fulfilling its role of a DOE Defense Programs nuclear User Facility/Technology Development Center, the Los Alamos National Laboratory Plutonium Facility recently tested three commercially built and owned, mobile nondestructive assay (NDA) systems with special nuclear materials (SNM). Two independent commercial companies financed the testing of their three mobile NDA systems at the site. Contained within a single trailer is Canberra Industries segmented gamma scanner/waste assay system (SGS/WAS) and neutron waste drum assay system (WDAS). The third system is a BNFL Instruments Inc. (formerly known as Pajarito Scientific Corporation) differential die-away imaging passive/active neutron (IPAN) counter. In an effort to increase the value of this comparison, additional NDA techniques at LANL were also used to measure these same drums. These are comprised of three tomographic gamma scanners (one mobile unit and two stationary) and one developmental differential die-away system. Although not certified standards, the authors hope that such a comparison will provide valuable data for those considering these different NDA techniques to measure their waste as well as the developers of the techniques

  14. Characterization of 618-11 solid waste burial ground, disposed waste, and description of the waste generating facilities

    Energy Technology Data Exchange (ETDEWEB)

    Hladek, K.L.

    1997-10-07

    The 618-11 (Wye or 318-11) burial ground received transuranic (TRTJ) and mixed fission solid waste from March 9, 1962, through October 2, 1962. It was then closed for 11 months so additional burial facilities could be added. The burial ground was reopened on September 16, 1963, and continued operating until it was closed permanently on December 31, 1967. The burial ground received wastes from all of the 300 Area radioactive material handling facilities. The purpose of this document is to characterize the 618-11 solid waste burial ground by describing the site, burial practices, the disposed wastes, and the waste generating facilities. This document provides information showing that kilogram quantities of plutonium were disposed to the drum storage units and caissons, making them transuranic (TRU). Also, kilogram quantities of plutonium and other TRU wastes were disposed to the three trenches, which were previously thought to contain non-TRU wastes. The site burial facilities (trenches, caissons, and drum storage units) should be classified as TRU and the site plutonium inventory maintained at five kilograms. Other fissile wastes were also disposed to the site. Additionally, thousands of curies of mixed fission products were also disposed to the trenches, caissons, and drum storage units. Most of the fission products have decayed over several half-lives, and are at more tolerable levels. Of greater concern, because of their release potential, are TRU radionuclides, Pu-238, Pu-240, and Np-237. TRU radionuclides also included slightly enriched 0.95 and 1.25% U-231 from N-Reactor fuel, which add to the fissile content. The 618-11 burial ground is located approximately 100 meters due west of Washington Nuclear Plant No. 2. The burial ground consists of three trenches, approximately 900 feet long, 25 feet deep, and 50 feet wide, running east-west. The trenches constitute 75% of the site area. There are 50 drum storage units (five 55-gallon steel drums welded together

  15. Characterization of 618-11 solid waste burial ground, disposed waste, and description of the waste generating facilities

    International Nuclear Information System (INIS)

    Hladek, K.L.

    1997-01-01

    The 618-11 (Wye or 318-11) burial ground received transuranic (TRTJ) and mixed fission solid waste from March 9, 1962, through October 2, 1962. It was then closed for 11 months so additional burial facilities could be added. The burial ground was reopened on September 16, 1963, and continued operating until it was closed permanently on December 31, 1967. The burial ground received wastes from all of the 300 Area radioactive material handling facilities. The purpose of this document is to characterize the 618-11 solid waste burial ground by describing the site, burial practices, the disposed wastes, and the waste generating facilities. This document provides information showing that kilogram quantities of plutonium were disposed to the drum storage units and caissons, making them transuranic (TRU). Also, kilogram quantities of plutonium and other TRU wastes were disposed to the three trenches, which were previously thought to contain non-TRU wastes. The site burial facilities (trenches, caissons, and drum storage units) should be classified as TRU and the site plutonium inventory maintained at five kilograms. Other fissile wastes were also disposed to the site. Additionally, thousands of curies of mixed fission products were also disposed to the trenches, caissons, and drum storage units. Most of the fission products have decayed over several half-lives, and are at more tolerable levels. Of greater concern, because of their release potential, are TRU radionuclides, Pu-238, Pu-240, and Np-237. TRU radionuclides also included slightly enriched 0.95 and 1.25% U-231 from N-Reactor fuel, which add to the fissile content. The 618-11 burial ground is located approximately 100 meters due west of Washington Nuclear Plant No. 2. The burial ground consists of three trenches, approximately 900 feet long, 25 feet deep, and 50 feet wide, running east-west. The trenches constitute 75% of the site area. There are 50 drum storage units (five 55-gallon steel drums welded together

  16. Characterization of mixed CH-TRU waste at Argonne-West

    International Nuclear Information System (INIS)

    Dwight, C.C.; Guay, K.P.; Courtney, J.C.; Higgins, P.J.

    1993-01-01

    Argonne National Laboratory is participating in the Department of Energy's Waste Isolation Pilot Plant (WIPP) Experimental Test Program by characterizing and repackaging mixed contact-handled transuranic waste. Argonne's initial activities in the Program were described last year at Waste Management '92. Since then, additional waste has been characterized and repackaged, resulting in six bins ready for shipment to WIPP upon the initiation of the bin tests. Lessons learned from these operations are being factored in the design and installation of a new characterization facility, the Enhanced Waste Characterization Facility (EWCF). The objectives of the WIPP Experimental Test Program have also undergone change since last year leading to an accelerated effort to factor sludge sampling capability into the EWCF. Consequently, the initiation of non-sludge operations in the waste characterization chamber has been delayed to Summer 1993 while the sludge sampling modifications are incorporated into the facility. Benefits in operational flexibility, effectiveness, and efficiency and reductions in potential facility and personnel contamination and exposure are expected from the enhanced waste characterization facility within the Hot Fuel Examination Facility at Argonne-West. This paper summarizes results and lessons learned from recent characterization and repackaging efforts and future plans for characterization. It also describes design features and status of the EWCF

  17. Results from simulated contact-handled transuranic waste experiments at the Waste Isolation Pilot Plant

    International Nuclear Information System (INIS)

    Molecke, M.A.; Sorensen, N.R.; Krumhansl, J.L.

    1993-01-01

    We conducted in situ experiments with nonradioactive, contact-handled transuranic (CH TRU) waste drums at the Waste Isolation Pilot Plant (WIPP) facility for about four years. We performed these tests in two rooms in rock salt, at WIPP, with drums surrounded by crushed salt or 70 wt % salt/30 wt % bentonite clay backfills, or partially submerged in a NaCl brine pool. Air and brine temperatures were maintained at ∼40C. These full-scale (210-L drum) experiments provided in situ data on: backfill material moisture-sorption and physical properties in the presence of brine; waste container corrosion adequacy; and, migration of chemical tracers (nonradioactive actinide and fission product simulants) in the near-field vicinity, all as a function of time. Individual drums, backfill, and brine samples were removed periodically for laboratory evaluations. Waste container testing in the presence of brine and brine-moistened backfill materials served as a severe overtest of long-term conditions that could be anticipated in an actual salt waste repository. We also obtained relevant operational-test emplacement and retrieval experience. All test results are intended to support both the acceptance of actual TRU wastes at the WIPP and performance assessment data needs. We provide an overview and technical data summary focusing on the WIPP CH TRU envirorunental overtests involving 174 waste drums in the presence of backfill materials and the brine pool, with posttest laboratory materials analyses of backfill sorbed-moisture content, CH TRU drum corrosion, tracer migration, and associated test observations

  18. Research on changes of nitrate by interactions with metals under the wastes disposal environment containing TRU nuclide. 2

    International Nuclear Information System (INIS)

    Wada, Ryutaro; Nishimura, Tsutomu; Masuda, Kaoru; Fujiwara, Kazuo; Imakita, Tsuyoshi; Tateishi, Tsuyoshi

    2004-02-01

    In TRU wastes, wastes containing nitrate ion as salt exist. In the disposal site environment, this nitrate ion changes into nitrite ion, ammonia, etc., and possibly affects disposal site environmental changes or nuclide migration parameters. In the present research, evaluation was carried out on the chemical interaction between nitrate ion and carbon steel, which is primary reducing agent, under the low-oxygen conditions simulating a disposal site. (1) In the electrochemical test, test data were generated in order to supplement influence parameters required for improvement of the accuracy of the nitrate reaction model (NEON). As the results, it was found that the influence of potential and pH is remarkable, also that of initial nitrate concentration is significant, while the temperature is not remarkable to the nitrate and nitrite reaction themselves. Besides, it was found that the difference in the surface condition of the electrodes is not remarkable. (2) Several long-term reaction tests were carried out to assume the effects of important parameters on the nitrate behavior with carbon steel under low-oxygen high-alkaline type simulated groundwater conditions using glass sealed apparatus (ampoule tests). As the results, it was found that initial nitrate ion concentration and temperature causes the increase of hydrogen generation as well as ammonia generation, while it was found that the difference of carbon steel composition doesn't affect significantly. (3) The parameter fitting NEON was reexamined to improve accuracy, gathering data of electrochemical tests and ampoule tests conducted in 2003 and 2000 through 2002. In addition by comparing the calculation results with experimental results, applicability of NEON was investigated. (4) Implementation of NEON to the mass transfer calculation code was carried out in order to enable the calculation of the nitrate ion behavior including incomings and outgoings of substance to and from the system, resulting in the

  19. Passive neutron coincidence counting with plastic scintillators for the characterization of radioactive waste drums

    Energy Technology Data Exchange (ETDEWEB)

    Deyglun, C.; Simony, B.; Perot, B.; Carasco, C. [CEA, DEN, Cadarache, Nuclear Measurement Laboratory, F-13108 Saint-Paul-lez-Durance (France); Saurel, N.; Colas, S. [CEA, DAM, Valduc, F-21120 Is-sur-Tille (France); Collot, J. [Laboratoire de Physique Subatomique et de Cosmologie, Universite Grenoble Alpes, CNRS/IN2P3, Grenoble (France)

    2015-07-01

    passive neutron coincidence counting system for radioactive waste drums using plastic scintillators have been studied using the Monte Carlo radiation transport code MCNPX-PoliMi v2.0 coupled to data processing algorithms developed with ROOT data analysis software. In addition to the correlated background, accidental coincidences are taken into account in the simulation by randomly merging pulses from different calculations with fission and (α,n) sources. (authors)

  20. TRU waste form studies with special reference to iron-enriched basalt: 1980. Annual report

    International Nuclear Information System (INIS)

    Flinn, J.E.; Henslee, S.P.; Kelsey, P.V. Jr.

    1981-06-01

    Material studies were performed on iron-enriched basalt (IEB) as a waste form containment medium for transuranic wastes. Specimens from laboratory scale, as well as large scale melts, were used in the evaluation. The studies included melting and casting, slag-refractory interaction, slag fruit assessments, volatility of sodium salts from IEB melts, chemical and structure homogeneity, metallic dissolution tests, physical properties, and devitrification associated with the development of mineral phases. In addition, durability tests, which included leaching and mechanical behavior, were performed

  1. Acceptable Knowledge Summary Report for Waste Stream: SR-T001-221F-HET/Drums

    Energy Technology Data Exchange (ETDEWEB)

    Lunsford, G.F.

    1998-10-26

    Since beginning operations in 1954, the Savannah River Site FB-Line produced Weapons Grade Plutonium for the United States National Defense Program. The facility mission was mainly to process dilute plutonium solution received from the 221-F Canyon into highly purified plutonium metal. As a result of various activities (maintenance, repair, clean up, etc.) in support of the mission, the facility generated a transuranic heterogeneous debris waste stream. Prior to January 25, 1990, the waste stream was considered suspect mixed transuranic waste (based on potential for inclusion of F-Listed solvent rags/wipes) and is not included in this characterization. Beginning January 25, 1990, Savannah River Site began segregation of rags and wipes containing F-Listed solvents thus creating a mixed transuranic waste stream and a non-mixed transuranic waste stream. This characterization addresses the non-mixed transuranic waste stream packaged in 55-gallon drums after January 25, 1990.Characterization of the waste stream was achieved using knowledge of process operations, facility safety basis documentation, facility specific waste management procedures and storage / disposal records. The report is fully responsive to the requirements of Section 4.0 "Acceptable Knowledge" from the WIPP Transuranic Waste Characterization Quality Assurance Plan, CAO-94-1010, and provides a sound, (and auditable) characterization that satisfies the WIPP criteria for Acceptable Knowledge.

  2. Potential use of transmission tomographic techniques for the quality checking of cemented waste drums. Progress report to 31 March 1985

    Energy Technology Data Exchange (ETDEWEB)

    Huddleston, J; Hutchinson, I G

    1986-01-01

    In support of the programme for the quality checking of encapsulated intermediate level waste, the possibilities of using transmission tomographic techniques for the determination of the physical properties of the drum are being considered. A literature survey has been undertaken and the possibilities of extracting data from video recordings of real time radiographs are considered. This work was carried out with financial support from British Nuclear Fuels plc and the UK Department of the Environment. In the DoE context, the results will be used in the formulation of Government Policy, but at this stage they do not necessarily represent Government Policy.

  3. HANFORD SITE RIVER PROTECTION PROJECT (RPP) TRANSURANIC (TRU) TANK WASTE IDENTIFICATION and PLANNING FOR REVRIEVAL TREATMENT and EVENTUAL DISPOSAL AT WIPP

    International Nuclear Information System (INIS)

    KRISTOFZSKI, J.G.; TEDESCHI, R.; JOHNSON, M.E.; JENNINGS, M

    2006-01-01

    The CH2M HILL Manford Group, Inc. (CHG) conducts business to achieve the goals of the Office of River Protection (ORP) at Hanford. As an employee owned company, CHG employees have a strong motivation to develop innovative solutions to enhance project and company performance while ensuring protection of human health and the environment. CHG is responsible to manage and perform work required to safely store, enhance readiness for waste feed delivery, and prepare for treated waste receipts for the approximately 53 million gallons of legacy mixed radioactive waste currently at the Hanford Site tank farms. Safety and environmental awareness is integrated into all activities and work is accomplished in a manner that achieves high levels of quality while protecting the environment and the safety and health of workers and the public. This paper focuses on the innovative strategy to identify, retrieve, treat, and dispose of Hanford Transuranic (TRU) tank waste at the Waste Isolation Pilot Plant (WIPP)

  4. Recent research in incinerator radioactive smoke filtration and improvements in a TRU waste incinerator plant

    International Nuclear Information System (INIS)

    Carpernier, S.; de Tassigny, C.; Hashimoto, Y.; Inove, A.

    1989-01-01

    In the area concerned, when incineration is carried out, it is always accompanied by the production of combustion gases which entrain fly ash, which is generally hazardous and/or a carrier of radioactivity, and which must be collected before the gasses are releases to the atmosphere. The fly ash concerned consists of secondary solid effluents which, with the consumable filters designed to stop them, tend to lower and quality of the waste volume and weight reduction factors, sometimes significantly. Hence it is an excellent idea to burn the organic part of the fly ash and also to stop thoroughly the inorganic parts by prefilters and final filters, carefully designed and selected for their performance and their longest possible service life, in order to minimize the process waste built up with time. This paper discusses the testing of ceramic and fiber candles for their refractive qualities, thermal shock behavior, commercial cost and efficiency for a given grain size distribution

  5. Using Aspen simulation package to determine solubility of mixed salts in TRU waste evaporator bottoms

    Energy Technology Data Exchange (ETDEWEB)

    Hatchell, J.L.

    1998-03-01

    Nitric acid from plutonium process waste is a candidate for waste minimization by recycling. Process simulation software packages, such as Aspen, are valuable tools to estimate how effective recovery processes can be, however, constants in equations of state for many ionic components are not in their data libraries. One option is to combine single salt solubility`s in the Aspen model for mixed salt system. Single salt solubilities were regressed in Aspen within 0.82 weight percent of literature values. These were combined into a single Aspen model and used in the mixed salt studies. A simulated nitric acid waste containing mixed aluminum, calcium, iron, magnesium and sodium nitrate was tested to determine points of solubility between 25 and 100 C. Only four of the modeled experimental conditions, at 50 C and 75 C, produced a saturated solution. While experimental results indicate that sodium nitrate is the first salt to crystallize out, the Aspen computer model shows that the most insoluble salt, magnesium nitrate, the first salt to crystallize. Possible double salt formation is actually taking place under experimental conditions, which is not captured by the Aspen model.

  6. Development of a method for determining the location of heterogeneous activity present in 200 litre waste drum using USB based MCS system

    International Nuclear Information System (INIS)

    Singh, Sarbjit; Mhatre, Amol; Sagar, Veena; Gupta, Nidhi

    2014-01-01

    A method was developed for determining the location of activity present in 200 litre waste drum using USB based MCS system coupled to a segmented gamma ray scanner. 137 Cs source was kept at various distances from centre of the drum along the axis of the detector. Drum was rotated and the activity profiles were determined as a function of angle of rotation. The plot of the count rate as a function of angle of rotation was found to have two peaks. The experimental and calculated data were found to match well at all angles. Present studies have shown that the ratio of height and width of the profile at angles of 0 ° and 180° can be used to determine the location of the activity in the drum. (author)

  7. Radiological Design Summary Report for TRU Vent and Purge Process

    International Nuclear Information System (INIS)

    Taus, L.B.

    2004-01-01

    This report contains top-level requirements for the various areas of radiological protection for workers. Detailed quotations of the requirements for applicable regulatory documents can be found in the accompanying Implementation Guide. For the purposes of demonstrating compliance with these requirements, per Engineering Standard 01064, shall consider / shall evaluate indicates that the designer must examine the requirement for the design and either incorporate or provide a technical justification as to why the requirement is not incorporated. The Transuranic Vent and Purge process is not a project, but is considered a process change. This process has been performed successfully by Solid Waste on lower activity TRU drums. This summary report applies a graded approach and describes how the Transuranic Vent and Purge process meets each of the applicable radiological design criteria and requirements specified in Manual WSRC-TM-95-1, Engineering Standard Number 01064

  8. Processing of transuranic waste at the Savannah River Plant

    International Nuclear Information System (INIS)

    Daugherty, B.A.; Gruber, L.M.; Mentrup, S.J.

    1986-01-01

    Transuranic wastes at the Savannah River Plant (SRP) have been retrievably stored on concrete pads since early 1972. This waste is stored primarily in 55-gallon drums and large carbon steel boxes. Higher activity drums are placed in concrete culverts. In support of a National Program to consolidate and permanently dispose of this waste, a major project is planned at SRP to retrieve and process this waste. This project, the TRU Waste Facility (TWF), will provide equipment and processes to retrieve TRU waste from 20-year retrievable storage and prepare it for permanent disposal at the Waste Isolation Pilot Plant (WIPP) geological repository in New Mexico. This project is an integral part of the SRP Long Range TRU Waste Management Program to reduce the amount of TRU waste stored at SRP. The TWF is designed to process 15,000 cubic feet of retrieved waste and 6200 cubic feet of newly generated waste each year of operation. This facility is designed to minimize direct personnel contact with the waste using state-of-the-art remotely operated equipment

  9. Type B drum packages

    International Nuclear Information System (INIS)

    McCoy, J.C.

    1994-08-01

    The Type B drum packages (TBD) are conceptualized as a family of containers in which a single 208 L or 114 L (55 gal or 30 gal) drum containing Type B quantities of radioactive material (RAM) can be packaged for shipment. The TBD containers are being developed to fill a void in the packaging and transportation capabilities of the U.S. Department of Energy as no container packaging single drums of Type B RAM exists offering double containment. Several multiple-drum containers currently exist, as well as a number of shielded casks, but the size and weight of these containers present many operational challenges for single-drum shipments. As an alternative, the TBD containers will offer up to three shielded versions (light, medium, and heavy) and one unshielded version, each offering single or optional double containment for a single drum. To reduce operational complexity, all versions will share similar design and operational features where possible. The primary users of the TBD containers are envisioned to be any organization desiring to ship single drums of Type B RAM, such as laboratories, waste retrieval activities, emergency response teams, etc. Currently, the TBD conceptual design is being developed with the final design and analysis to be completed in 1995 to 1996. Testing and certification of the unshielded version are planned to be completed in 1996 to 1997 with production to begin in 1997 to 1998

  10. The Challenges of Creating a Real-Time Data Management System for TRU-Mixed Waste at the Advanced Mixed Waste Treatment Plant

    International Nuclear Information System (INIS)

    Paff, S. W; Doody, S.

    2003-01-01

    This paper discusses the challenges associated with creating a data management system for waste tracking at the Advanced Mixed Waste Treatment Plant (AMWTP) at the Idaho National Engineering Lab (INEEL). The waste tracking system combines data from plant automation systems and decision points. The primary purpose of the system is to provide information to enable the plant operators and engineers to assess the risks associated with each container and determine the best method of treating it. It is also used to track the transuranic (TRU) waste containers as they move throughout the various processes at the plant. And finally, the goal of the system is to support paperless shipments of the waste to the Waste Isolation Pilot Plant (WIPP). This paper describes the approach, methodologies, the underlying design of the database, and the challenges of creating the Data Management System (DMS) prior to completion of design and construction of a major plant. The system was built utilizing an Oracle database platform, and Oracle Forms 6i in client-server mode. The underlying data architecture is container-centric, with separate tables and objects for each type of analysis used to characterize the waste, including real-time radiography (RTR), non-destructive assay (NDA), head-space gas sampling and analysis (HSGS), visual examination (VE) and coring. The use of separate tables facilitated the construction of automatic interfaces with the analysis instruments that enabled direct data capture. Movements are tracked using a location system describing each waste container's current location and a history table tracking the container's movement history. The movement system is designed to interface both with radio-frequency bar-code devices and the plant's integrated control system (ICS). Collections of containers or information, such as batches, were created across the various types of analyses, which enabled a single, cohesive approach to be developed for verification and

  11. Use of drum driers for processing various industrial wastes into high-grade animal feeding stuffs

    Energy Technology Data Exchange (ETDEWEB)

    Fritze, H

    1976-01-01

    Strict anti-pollution legislation governing admissible effluent concentrations and high charges are forcing certain industries (potato starch and dried potato flake factories, sugar factories and dairies) to install facilities for recovering valuable substances, which are used mainly as fodder. In this way the effluent charges can be reduced and a return is obtained on the investment and operating costs. Processes are described whereby such substances can be extracted efficiently when using Escher Wyss drum driers.

  12. Comparative assessment of TRU waste forms and processes. Volume II. Waste form data, process descriptions, and costs

    International Nuclear Information System (INIS)

    Ross, W.A.; Lokken, R.O.; May, R.P.; Roberts, F.P.; Thornhill, R.E.; Timmerman, C.L.; Treat, R.L.; Westsik, J.H. Jr.

    1982-09-01

    This volume contains supporting information for the comparative assessment of the transuranic waste forms and processes summarized in Volume I. Detailed data on the characterization of the waste forms selected for the assessment, process descriptions, and cost information are provided. The purpose of this volume is to provide additional information that may be useful when using the data in Volume I and to provide greater detail on particular waste forms and processes. Volume II is divided into two sections and two appendixes. The first section provides information on the preparation of the waste form specimens used in this study and additional characterization data in support of that in Volume I. The second section includes detailed process descriptions for the eight processes evaluated. Appendix A lists the results of MCC-1 leach test and Appendix B lists additional cost data. 56 figures, 12 tables

  13. Thermal Neutron Die-Way-Time Studies for P and DGNAA of Radioactive Waste Drums at the MEDINA Facility

    Energy Technology Data Exchange (ETDEWEB)

    Mildenberger, Frank; Mauerhofer, Eric [Institute of Energy and Climate Research - Nuclear Waste Management and Reactor Safety, Forschungszentrum Juelich GmbH, 52425 Juelich (Germany)

    2015-07-01

    In Germany, radioactive waste with negligible heat production has to pass through a process of quality checking in order to check its conformance with national regulations prior to its transport, intermediate storage and final disposal. Additionally to its radioactive components, the waste may contain non-radioactive chemically toxic substances that can adversely affect human health and pollute the environment, especially the ground water. After an adequate decay time, the waste radioactivity will become harmless but the non-radioactive substances will persist over time. In principle, these hazardous substances may be quantified from traceability and quality controls performed during the production of the waste packages. As a consequence, a research and development program was initiated in 2007 with the aim to develop a nondestructive analytical technique for radioactive waste packages based on prompt and delayed gamma neutron activation analysis (P and DGNAA) employing a DT-neutron generator in pulsed mode. In a preliminary study it was experimentally demonstrated that P and DGNAA is suitable to determine the chemical composition of large samples. In 2010 a facility called MEDINA (Multi Element Detection based on Instrumental Neutron Activation) was developed for the qualitative and quantitative determination of nonradioactive, toxic elements and substances in 200-l steel drums. The determination of hazardous substances and elements is generally achieved measuring the prompt gamma-rays induced by thermal neutrons. Additional information about the composition of the waste matrix could be derived measuring the delayed gamma-rays from short life activation products. However a sensitive detection of these delayed gamma-rays requires that thermal neutrons have almost vanished. Therefore, the thermal neutron die-away-time has to be known in order to achieve an optimal discrimination between prompt and delayed gamma-ray spectra acquisition. Measurements Thermal neutron

  14. The design of a high-efficiency neutron counter for waste drums to provide optimized sensitivity for plutonium assay

    Energy Technology Data Exchange (ETDEWEB)

    Menlove, H.O.; Beddingfield, D.H.; Pickrell, M.M. [Los Alamos National Lab., NM (United States)] [and others

    1997-11-01

    An advanced passive neutron counter has been designed to improve the accuracy and sensitivity for the nondestructive assay of plutonium in scrap and waste containers. The High-Efficiency Neutron Counter (HENC) was developed under a Cooperative Research Development Agreement between the Los Alamos National Laboratory and Canberra Industries. The primary goal of the development was to produce a passive assay system for 200-L drums that has detectability limits and multiplicity counting features that are superior to previous systems. A detectability limit figure of merit (FOM) was defined that included the detector efficiency, the neutron die-away time, and the detector`s active volume and density that determine the cosmic-ray background. Monte Carlo neutron calculations were performed to determine the parameters to provide an optimum FOM. The system includes the {sup 252}Cf {open_quotes}add-a-source{close_quotes} feature to improve the accuracy as well as statistical filters to reduce the cosmic-ray spallation neutron background. The final decision gave an efficiency of 32% for plutonium with a detector {sup 3}He tube volume that is significantly smaller than for previous high-efficiency systems for 200-L drums. Because of the high efficiency of the HENC, we have incorporated neutron multiplicity counting for matrix corrections for those cases where the plutonium is localized in nonuniform hydrogenous materials. The paper describes the design and performance testing of the advanced system. 5 refs., 8 figs., 3 tabs.

  15. The design of a high-efficiency neutron counter for waste drums to provide optimized sensitivity for plutonium assay

    International Nuclear Information System (INIS)

    Menlove, H.O.; Beddingfield, D.H.; Pickrell, M.M.

    1997-01-01

    An advanced passive neutron counter has been designed to improve the accuracy and sensitivity for the nondestructive assay of plutonium in scrap and waste containers. The High-Efficiency Neutron Counter (HENC) was developed under a Cooperative Research Development Agreement between the Los Alamos National Laboratory and Canberra Industries. The primary goal of the development was to produce a passive assay system for 200-L drums that has detectability limits and multiplicity counting features that are superior to previous systems. A detectability limit figure of merit (FOM) was defined that included the detector efficiency, the neutron die-away time, and the detector's active volume and density that determine the cosmic-ray background. Monte Carlo neutron calculations were performed to determine the parameters to provide an optimum FOM. The system includes the 252 Cf open-quotes add-a-sourceclose quotes feature to improve the accuracy as well as statistical filters to reduce the cosmic-ray spallation neutron background. The final decision gave an efficiency of 32% for plutonium with a detector 3 He tube volume that is significantly smaller than for previous high-efficiency systems for 200-L drums. Because of the high efficiency of the HENC, we have incorporated neutron multiplicity counting for matrix corrections for those cases where the plutonium is localized in nonuniform hydrogenous materials. The paper describes the design and performance testing of the advanced system. 5 refs., 8 figs., 3 tabs

  16. Dose potential of sludge contaminated and/or TRU contaminated waste in B-25s for tornado and straight wind events

    Energy Technology Data Exchange (ETDEWEB)

    Aponte, C.I.

    2000-02-17

    F and H Tank Farms generate supernate and sludge contaminated Low-Level Waste. The waste is collected, characterized, and packaged for disposal. Before the waste can be disposed of, however, it must be properly characterized. Since the radionuclide distribution in typical supernate is well known, its characterization is relatively straight forward and requires minimal effort. Non-routine waste, including potentially sludge contaminated, requires much more effort to effectively characterize. The radionuclide distribution must be determined. In some cases the waste can be contaminated by various sludge transfers with unique radionuclide distributions. In these cases, the characterization can require an extensive effort. Even after an extensive characterization effort, the container must still be prepared for shipping. Therefore a significant amount of time may elapse from the time the waste is generated until the time of disposal. During the time it is possible for a tornado or high wind scenario to occur. The purpose of this report is to determine the effect of a tornado on potential sludge contaminated waste, or Transuranic (TRU) waste in B-25s [large storage containers], to evaluate the potential impact on F and H Tank Farms, and to help establish a B-25 control program for tornado events.

  17. Dose potential of sludge contaminated and/or TRU contaminated waste in B-25s for tornado and straight wind events

    International Nuclear Information System (INIS)

    Aponte, C.I.

    2000-01-01

    F and H Tank Farms generate supernate and sludge contaminated Low-Level Waste. The waste is collected, characterized, and packaged for disposal. Before the waste can be disposed of, however, it must be properly characterized. Since the radionuclide distribution in typical supernate is well known, its characterization is relatively straight forward and requires minimal effort. Non-routine waste, including potentially sludge contaminated, requires much more effort to effectively characterize. The radionuclide distribution must be determined. In some cases the waste can be contaminated by various sludge transfers with unique radionuclide distributions. In these cases, the characterization can require an extensive effort. Even after an extensive characterization effort, the container must still be prepared for shipping. Therefore a significant amount of time may elapse from the time the waste is generated until the time of disposal. During the time it is possible for a tornado or high wind scenario to occur. The purpose of this report is to determine the effect of a tornado on potential sludge contaminated waste, or Transuranic (TRU) waste in B-25s [large storage containers], to evaluate the potential impact on F and H Tank Farms, and to help establish a B-25 control program for tornado events

  18. TRU decontamination of high-level Purex waste by solvent extraction using a mixed octyl(phenyl)-N,N-diisobutyl-carbamoylmethylphosphine oxide/TBP/NPH (TRUEX) solvent

    International Nuclear Information System (INIS)

    Horwitz, E.P.; Kalina, D.G.; Diamond, H.; Kaplan, L.; Vandegrift, G.F.; Leonard, R.A.; Steindler, M.J.; Schulz, W.W.

    1984-01-01

    The TRUEX (transuranium extraction) process was tested on a simulated high-level dissolved sludge waste (DSW). A batch counter-current extraction mode was used for seven extraction and three scrub stages. One additional extraction stage and two scrub stages and all strip stages were performed by batch extraction. The TRUEX solvent consisted of 0.20 M octyl(phenyl)-N,N-diisobutylcarbamoyl-methylphosphine oxide-1.4 M TBP in Conoco (C 12 -C 14 ). The feed solution was 1.0 M in HNO 3 , 0.3 M in H 2 C 2 O 4 and contained mixed (stable) fission products, U, Np, Pu, and Am, and a number of inert constituents, e.g., Fe and Al. The test showed that the process is capable of reducing the TRU concentration in the DSW by a factor of 4 x 10 4 (to <100 nCi/g of disposed form) and reducing the quantity of TRU waste by two orders of magnitude

  19. ANALYSIS OF SPECIAL WASTE CONFIGURATIONS AT THE SRS WASTE MANAGEMENT FACILITIES

    International Nuclear Information System (INIS)

    Casella, V; Raymond Dewberry, R

    2007-01-01

    Job Control Waste (JCW) at the Savannah River Site (SRS) Solid Waste Management Facilities (SWMF) may be disposed of in special containers, and the analysis of these containers requires developing specific analysis methodologies. A method has been developed for the routine assay of prohibited items (liquids, etc.) contained in a 30-gallon drum that is then placed into a 55-gallon drum. Method development consisted of system calibration with a NIST standard at various drum-to-detector distances, method verification with a liquid sample containing a known amount of Pu-238, and modeling the inner container using Ortec Isotopic software. Using this method for measurement of the known standard in the drum-in-drum configuration produced excellent agreement (within 15%) with the known value. Savannah River Site Solid Waste Management also requested analysis of waste contained in large black boxes (commonly 18-feet x 12-feet x 7-feet) stored at the SWMF. These boxes are frequently stored in high background areas and background radiation must be considered for each analysis. A detection limit of less than 150 fissile-gram-equivalents (FGE) of TRU waste is required for the black-box analyses. There is usually excellent agreement for the measurements at different distances and measurement uncertainties of about 50% are obtained at distances of at least twenty feet from the box. This paper discusses the experimental setup, analysis and data evaluation for drum-in-drum and black box waste configurations at SRS

  20. The simultaneous neutron and photon interrogation method for fissile and non-fissile element separation in radioactive waste drums

    International Nuclear Information System (INIS)

    Jallu, F.; Lyoussi, A.; Passard, C.; Payan, E.; Recroix, H.; Nurdin, G.; Buisson, A.; Allano, J.

    2000-01-01

    Measuring α-emitters such as ( 234,235,236,238 U, 238,239,240,242,244 Pu, 237 Np, 241,243 Am, ...), in solid radioactive waste allows us to quantify the α-activity in a drum and then to classify it. The simultaneous photon and neutron interrogation experiment (SIMPHONIE) method dealt with in this paper, combines both active neutron interrogation and induced photofission interrogation techniques simultaneously. Its purpose is to quantify fissile ( 235 U, 239,241 Pu, ...) and non-fissile ( 236,238 U, 238,240 Pu, ...) elements separately in only one measurement. This paper presents the principle of the method, the experimental setup, and the first experimental results obtained using the DGA/ETCA Linac and MiniLinatron pulsed linear electron accelerators located at Arcueil, France. First studies were carried out with U and Pu bare samples

  1. TRU partnership-Working smarter-Not harder

    International Nuclear Information System (INIS)

    Armstrong, D.W.; Briggs, S.R.; Martin, M.R.; Turner, D.R.

    1994-01-01

    The open-quotes TRU Partnershipclose quotes was initiated and continues to function under the catch phrase philosophy of open-quotes work smarter, not harderclose quotes. The parntership participants have realized that DOE no longer has the funding available to reinvent the wheel at each site. Information and experiences from each site need to accurately and timely provided to the other sites for their use. The project teams from the different TRU waste handling sites benefit enormously from the strong network that has developed between TRU partnership participants. The partnership working interface places design manager in touch with design manager, project manager with project manager, etc. across site boundaries, and equally important, across corporate boundaries. The TRU Partnership has created a team atmosphere for the participants. The team focus is on the common challenge of managing TRU waste projects to support site needs and the needs of the national TRU waste program. Although consistency of approach for all projects at any given site is important, the TRU Partnership provides an intersite forum to establish consistency and understanding across all DOE projects managing TRU waste. The TRU Partnership has adopted the Westinghouse Electric Corporation open-quotes Savings Through Sharingclose quotes philosophy as an integral part of its organizational objectives. As applied by the group, the approach concentrates on information and experiences that can enhance development and reduce costs for (TRU) waste projects

  2. Preliminary criticality study supporting transuranic waste acceptance into the plasma hearth process

    International Nuclear Information System (INIS)

    Slate, L.J.; Santee, G.E. Jr.

    1996-01-01

    This study documents preliminary scoping calculations to address criticality issues associated with the processing of transuranic (TRU) waste and TRU mixed waste in the Plasma Hearth Process (PHP) Test Project. To assess the criticality potential associated with processing TRU waste, the process flow in the PHP is evaluated to identify the stages where criticality could occur. A criticality analysis methodology is then formulated to analyze the criticality potential. Based on these analyses, TRU acceptance criteria can be defined for the PHP. For the current level of analysis, the methodology only assesses the physical system as designed and does not address issues associated with the criticality double contingency principle. The analyses suggest that criticality within the PHP system and within the planned treatment residue (stag) containers does not pose a criticality hazard even when processing waste feed drums containing a quantity of TRU greater than would be reasonably expected. The analyses also indicate that the quantity of TRU that can be processed during each batch is controlled by moving and storage conditions for the resulting slag collection drums

  3. High-Energy X-ray imaging applied to non destructive characterization of large nuclear waste drums

    International Nuclear Information System (INIS)

    Estre, Nicolas; Eck, Daniel; Pettier, Jean-Luc; Payan, Emmanuel; Roure, Christophe; Simon, Eric

    2013-06-01

    As part of its R and D programs on non-destructive testing of nuclear waste drums, CEA is commissioning an irradiation cell named CINPHONIE, at Cadarache. This cell allows high-energy imaging (radiography and tomography) on large volumes (up to 5 m 3 ) and heavy weights (up to 5 tons). A demonstrator has been finalized, based on existing components. The X-ray source is a 9 MeV LINAC which produces Bremsstrahlung X-rays (up to 23 Gy/min at 1 meter in the beam axis). The mechanical bench is digitally controlled on three axes (translation, rotation, elevation) and can handle objects up to 2 t. This bench performs trajectories necessary for acquisition of projections (sinograms) according to different geometries: Translation-Rotation, Fan-Beam and Cone-Beam. Two detection systems both developed by CEA-Leti are available. The first one is a large GADOX scintillating screen (800*600 mm 2 ) coupled to a low-noise pixelated camera. The second one is a multi- CdTe semiconductor detector, offering measurements up to 5 decades of attenuation (equivalent to 25 cm of lead or 180 cm of standard concrete). At the end of the acquisition, a Filtered Back Projection-based algorithm is performed. Then, a density slice (fan-beam tomography) or a density volume (cone-beam tomography or helical tomography) is produced and used to examine the waste. Characterization of LINAC, associated detectors as well as the full acquisition chain, are presented. Experimental performances on phantoms and real drum are discussed and expected limits on defect detectability are evaluated by simulation. The final system, designed to handle objects up to 5 tons is then presented. (authors)

  4. JAEA thermodynamic database for performance assessment of geological disposal of high-level and TRU wastes. Selection of thermodynamic data of cobalt and nickel

    International Nuclear Information System (INIS)

    Kitamura, Akira; Yui, Mikazu; Kirishima, Akira; Saito, Takumi; Shibutani, Sanae; Tochiyama, Osamu

    2009-11-01

    Within the scope of the JAEA thermodynamic database project for performance assessment of geological disposal of high-level and TRU wastes, the selection of the thermodynamic data on the inorganic compounds and complexes of cobalt and nickel have been carried out. For cobalt, extensive literature survey has been performed and all the obtained literatures have been carefully reviewed to select the thermodynamic data. Selection of thermodynamic data of nickel has been based on a thermodynamic database published by the Nuclear Energy Agency in the Organisation for Economic Co-operation and Development (OECD/NEA), which has been carefully reviewed by the authors, and then thermodynamic data have been selected after surveying latest literatures. Based on the similarity of chemical properties between cobalt and nickel, complementary thermodynamic data of nickel and cobalt species expected under the geological disposal condition have been selected to complete the thermodynamic data set for the performance assessment of geological disposal of radioactive wastes. (author)

  5. JAEA thermodynamic database for performance assessment of geological disposal of high-level and TRU wastes. Selection of thermodynamic data of selenium

    International Nuclear Information System (INIS)

    Doi, Reisuke; Kitamura, Akira; Yui, Mikazu

    2010-02-01

    Within the scope of the JAEA thermodynamic database project for performance assessment of geological disposal of high-level and TRU radioactive wastes, the selection of the thermodynamic data on the inorganic compounds and complexes of selenium was carried out. Selection of thermodynamic data of selenium was based on a thermodynamic database of selenium published by the Nuclear Energy Agency in the Organisation for Economic Co-operation and Development (OECD/NEA). The remarks of a thermodynamic database by OECD/NEA found by the authors were noted in this report and then thermodynamic data was reviewed after surveying latest literatures. Some thermodynamic values of iron selenides were not selected by the OECD/NEA due to low reliability. But they were important for the performance assessment of geological disposal of radioactive wastes, so we selected them as a tentative value with specifying reliability and needs of the value to be determined. (author)

  6. JAEA thermodynamic database for performance assessment of geological disposal of high-level and TRU wastes. Refinement of thermodynamic data for trivalent actinoids and samarium

    International Nuclear Information System (INIS)

    Kitamura, Akira; Fujiwara, Kenso; Yui, Mikazu

    2010-01-01

    Within the scope of the JAEA thermodynamic database project for performance assessment of geological disposal of high-level radioactive and TRU wastes, the refinement of the thermodynamic data for the inorganic compounds and complexes of trivalent actinoids (actinium(III), plutonium(III), americium(III) and curium(III)) and samarium(III) was carried out. Refinement of thermodynamic data for these elements was based on the thermodynamic database for americium published by the Nuclear Energy Agency in the Organisation for Economic Co-operation and Development (OECD/NEA). Based on the similarity of chemical properties among trivalent actinoids and samarium, complementary thermodynamic data for their species expected under the geological disposal conditions were selected to complete the thermodynamic data set for the performance assessment of geological disposal of radioactive wastes. (author)

  7. Los Alamos National Laboratory transuranic waste characterization and certification program - an overview of capabilities and capacity

    International Nuclear Information System (INIS)

    Rogers, P.S.Z.; Sinkule, B.J.; Janecky, D.R.; Gavett, M.A.

    1997-01-01

    The Los Alamos National Laboratory (LANL) has full capability to characterize transuranic (TRU) waste for shipment to and disposal at the Waste Isolation Pilot Plant (WIPP) for its projected opening. LANL TRU waste management operations also include facilities to repackage both drums of waste found not to be certifiable for WIPP and oversized boxes of waste that must be size reduced for shipment to WIPP. All characterization activities and repackaging are carried out under a quality assurance program designed to meet Carlsbad Area Office (CAO) requirements. The flow of waste containers through characterization operations, the facilities used for characterization, and the electronic data management system used for data package preparation and certification of TRU waste at LANL are described

  8. Improved Hydrogen Gas Getters for TRU Waste Transuranic and Mixed Waste Focus Area - Phase 2 Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Stone, Mark Lee

    2002-04-01

    Alpha radiolysis of hydrogenous waste and packaging materials generates hydrogen gas in radioactive storage containers. For that reason, the Nuclear Regulatory Commission (NRC) limits the flammable gas (hydrogen) concentration in the Transuranic Package Transporter-II (TRUPACT-II) containers to 5 vol% of hydrogen in air, which is the lower explosion limit. Consequently, a method is needed to prevent the build up of hydrogen to 5 vol% during the storage and transport of the TRUPACT-II containers (up to 60 days). One promising option is the use of hydrogen getters. These materials scavenge hydrogen from the gas phase and irreversibly bind it in the solid phase. One proven getter is a material called 1,4-bis (phenylethynyl) benzene, or DEB. It has the needed binding rate and capacity, but some of the chemical species that might be present in the containers could interfere with its ability to remove hydrogen. This project is focused upon developing a protective polymeric membrane coating for the DEB getter material, which comes in the form of small, irregularly shaped particles. This report summarizes the experimental results of the second phase of the development of the materials.

  9. Nondestructive and quantitative characterization of TRU and LLW mixed-waste using active and passive gamma-ray spectrometry and computed tomography

    Energy Technology Data Exchange (ETDEWEB)

    Camp, D.C.; Martz, H.E.

    1991-11-12

    The technology being proposed by LLNL is an Active and Passive Computed Tomography (A P CT) Drum Scanner for contact-handled (CH) wastes. It combines the advantages offered by two well-developed nondestructive assay technologies: gamma-ray spectrometry and computed tomography (CT). Coupled together, these two technologies offer to nondestructively and quantitatively characterize mixed- wastes forms. Gamma-ray spectroscopy uses one or more external radiation detectors to passively and nondestructively measure the energy spectrum emitted from a closed container. From the resulting spectrum one can identify most radioactivities detected, be they transuranic isotopes, mixed-fission products, activation products or environmental radioactivities. Spectral libraries exist at LLNL for all four. Active (A) or transmission CT is a well-developed, nondestructive medical and industrial technique that uses an external-radiation beam to map regions of varying attenuation within a container. Passive (P) or emission CT is a technique mainly developed for medical application, e.g., single-photon emission CT. Nondestructive industrial uses of PCT are under development and just coming into use. This report discuses work on the A P CT Drum Scanner at LLNL.

  10. Nondestructive and quantitative characterization of TRU and LLW mixed-waste using active and passive gamma-ray spectrometry and computed tomography

    International Nuclear Information System (INIS)

    Camp, D.C.; Martz, H.E.

    1991-01-01

    The technology being proposed by LLNL is an Active and Passive Computed Tomography (A ampersand P CT) Drum Scanner for contact-handled (CH) wastes. It combines the advantages offered by two well-developed nondestructive assay technologies: gamma-ray spectrometry and computed tomography (CT). Coupled together, these two technologies offer to nondestructively and quantitatively characterize mixed- wastes forms. Gamma-ray spectroscopy uses one or more external radiation detectors to passively and nondestructively measure the energy spectrum emitted from a closed container. From the resulting spectrum one can identify most radioactivities detected, be they transuranic isotopes, mixed-fission products, activation products or environmental radioactivities. Spectral libraries exist at LLNL for all four. Active (A) or transmission CT is a well-developed, nondestructive medical and industrial technique that uses an external-radiation beam to map regions of varying attenuation within a container. Passive (P) or emission CT is a technique mainly developed for medical application, e.g., single-photon emission CT. Nondestructive industrial uses of PCT are under development and just coming into use. This report discuses work on the A ampersand P CT Drum Scanner at LLNL

  11. Application of molten salt oxidation for the minimization and recovery of plutonium-238 contaminated wastes

    Energy Technology Data Exchange (ETDEWEB)

    Wishau, R.

    1998-05-01

    Molten salt oxidation (MSO) is proposed as a {sup 238}Pu waste treatment technology that should be developed for volume reduction and recovery of {sup 238}Pu and as an alternative to the transport and permanent disposal of {sup 238}Pu waste to the WIPP repository. In MSO technology, molten sodium carbonate salt at 800--900 C in a reaction vessel acts as a reaction media for wastes. The waste material is destroyed when injected into the molten salt, creating harmless carbon dioxide and steam and a small amount of ash in the spent salt. The spent salt can be treated using aqueous separation methods to reuse the salt and to recover 99.9% of the precious {sup 238}Pu that was in the waste. Tests of MSO technology have shown that the volume of combustible TRU waste can be reduced by a factor of at least twenty. Using this factor the present inventory of 574 TRU drums of {sup 238}Pu contaminated wastes is reduced to 30 drums. Further {sup 238}Pu waste costs of $22 million are avoided from not having to repackage 312 of the 574 drums to a drum total of more than 4,600 drums. MSO combined with aqueous processing of salts will recover approximately 1.7 kilograms of precious {sup 238}Pu valued at 4 million dollars (at $2,500/gram). Thus, installation and use of MSO technology at LANL will result in significant cost savings compared to present plans to transport and dispose {sup 238}Pu TRU waste to the WIPP site. Using a total net present value cost for the MSO project as $4.09 million over a five-year lifetime, the project can pay for itself after either recovery of 1.6 kg of Pu or through volume reduction of 818 drums or a combination of the two. These savings show a positive return on investment.

  12. Application of molten salt oxidation for the minimization and recovery of plutonium-238 contaminated wastes

    International Nuclear Information System (INIS)

    Wishau, R.

    1998-05-01

    Molten salt oxidation (MSO) is proposed as a 238 Pu waste treatment technology that should be developed for volume reduction and recovery of 238 Pu and as an alternative to the transport and permanent disposal of 238 Pu waste to the WIPP repository. In MSO technology, molten sodium carbonate salt at 800--900 C in a reaction vessel acts as a reaction media for wastes. The waste material is destroyed when injected into the molten salt, creating harmless carbon dioxide and steam and a small amount of ash in the spent salt. The spent salt can be treated using aqueous separation methods to reuse the salt and to recover 99.9% of the precious 238 Pu that was in the waste. Tests of MSO technology have shown that the volume of combustible TRU waste can be reduced by a factor of at least twenty. Using this factor the present inventory of 574 TRU drums of 238 Pu contaminated wastes is reduced to 30 drums. Further 238 Pu waste costs of $22 million are avoided from not having to repackage 312 of the 574 drums to a drum total of more than 4,600 drums. MSO combined with aqueous processing of salts will recover approximately 1.7 kilograms of precious 238 Pu valued at 4 million dollars (at $2,500/gram). Thus, installation and use of MSO technology at LANL will result in significant cost savings compared to present plans to transport and dispose 238 Pu TRU waste to the WIPP site. Using a total net present value cost for the MSO project as $4.09 million over a five-year lifetime, the project can pay for itself after either recovery of 1.6 kg of Pu or through volume reduction of 818 drums or a combination of the two. These savings show a positive return on investment

  13. JAEA thermodynamic database for performance assessment of geological disposal of high-level and TRU wastes. Refinement of thermodynamic data for tetravalent thorium, uranium, neptunium and plutonium

    International Nuclear Information System (INIS)

    Fujiwara, Kenso; Kitamura, Akira; Yui, Mikazu

    2010-03-01

    Within the scope of the JAEA thermodynamic database project for performance assessment of geological disposal of high-level and TRU radioactive wastes, the refinement of the thermodynamic data for the inorganic compounds and complexes of Thorium(IV), Uranium(IV), Neptunium(IV) and Plutonium(IV) was carried out. Refinement of thermodynamic data for the element was performed on a basis of the thermodynamic database for actinide published by the Nuclear Energy Agency in the Organisation for Economic Co-operation and Development (OECD/NEA). Additionally, the latest data after publication of thermodynamic data by OECD/NEA were reevaluated to determine whether the data should be included in the JAEA-TDB. (author)

  14. Site health and safety plan/work plan for further characterization of waste drums at Oak Ridge National Laboratory, Oak Ridge, Tennessee

    International Nuclear Information System (INIS)

    Abston, J.P.; Burman, S.N.; Jones, D.L.

    1995-10-01

    The health and safety plan/work plan describes a strategy for characterizing the contents of 172 liquid waste and 33 solid waste drums. It also addresses the control measures that will be taken to (1) prevent or minimize any adverse impact on the environment or personnel safety and health and (2) meet standards that define acceptable management of hazardous and radioactive materials and wastes. When writing this document, the authors considered past experiences, recommendations, and best management practices to minimize possible hazards to human health or the environment from events such as fires, explosions, falls, mechanical hazards, or unplanned releases of hazardous or radioactive materials to air, soil, or surface water

  15. Components for containment enclosures - Part 3: Transfer systems such as plain doors, airlock chambers, double door transfer systems, leaktight connections for waste drums. 1. ed.

    International Nuclear Information System (INIS)

    1998-01-01

    This part of ISO 11933 specifies requirements for the selection, construction and use of the following leak tight components: doors, airlock chambers, double door transfer systems, leaktight connections for waste drums. Some of the elements, double doors or airlock chambers are described in ISO 11933-1 and ISO 11933-2 as well. Doors having bigger dimensions used for personnel od larger objects are not covered by this document

  16. Nondestructive radioassay for waste management: an assessment

    Energy Technology Data Exchange (ETDEWEB)

    Lehmkuhl, G.D.

    1981-06-01

    Nondestructive Assay (NDA) for Transuranic Waste Management is used to mean determining the amount of transuranic (TRU) isotopes in crates, drums, boxes, cans, or other containers without having to open the container. It also means determining the amount of TRU in soil, bore holes, and other environmental testing areas without having to go through extensive laboratory wet chemistry analyses. it refers to radioassay techniques used to check for contamination on objects after decontamination and to determine amounts of TRU in waste processing streams without taking samples to a laboratory. Gednerally, NDA instrumentation in this context refers to all use of radioassay which does not involve taking samples and using wet chemistry techniques. NDA instruments have been used for waste assay at some sites for over 10 years and other sites are just beginning to consider assay of wastes. The instrumentation used at several sites is discussed in this report. Almost all these instruments in use today were developed for special nuclear materials safeguards purposes and assay TRU waste down to the 500 nCi/g range. The need for instruments to assay alpha particle emitters at 10 nCi/g or less has risen from the wish to distinguish between Low Level Waste (LLW) and TRU Waste at the defined interface of 10 nCi/g. Wastes have historically been handled as TRU wastes if they were just suspected to be transuranically contaminated but their exact status was unknown. Economic and political considerations make this practice undesirable since it is easier and less costly to handle LLW. This prompted waste generators to want better instrumentation and led the Transuranic Waste Management Program to develop and test instrumentation capable of assaying many types of waste at the 10 nCi/g level. These instruments are discussed.

  17. Steam drums

    International Nuclear Information System (INIS)

    Crowder, R.

    1978-01-01

    Steam drums are described that are suitable for use in steam generating heavy water reactor power stations. They receive a steam/water mixture via riser headers from the reactor core and provide by means of separators and driers steam with typically 0.5% moisture content for driving turbines. The drums are constructed as prestressed concrete pressure vessels in which the failure of one or a few of the prestressing elements does not significantly affect the overall strength of the structure. The concrete also acts as a radiation shield. (U.K.)

  18. Innovations in the Assay of Un-Segregated Multi-Isotopic Grade TRU Waste Boxes with SuperHENC and FRAM Technology

    International Nuclear Information System (INIS)

    Simpson, A. P.; Barber, S.; Abdurrahman, N. M.

    2006-01-01

    The Super High Efficiency Neutron Coincidence Counter (SuperHENC) was originally developed by BIL Solutions Inc., Los Alamos National Laboratory (LANL) and Rocky Flats Environmental Technology Site (RFETS) for assay of transuranic (TRU) waste in Standard Waste Boxes (SWB) at Rocky Flats. This mobile system was a key component in the shipment of over 4,000 SWBs to the Waste Isolation Pilot Plant (WIPP) in Carlsbad, New Mexico. The system was WIPP certified in 2001 and operated at the site for four years. The success of this system, a passive neutron coincidence counter combined with high resolution gamma spectroscopy, led to the order of two new units, delivered to Hanford in 2004. Several new challenges were faced at Hanford: For example, the original RFETS system was calibrated for segregated waste streams such that metals, plastics, wet combustibles and dry combustibles were separated by 'Item Description Codes' prior to assay. Furthermore, the RFETS mission of handling only weapons grade plutonium, enabled the original SuperHENC to benefit from the use of known Pu isotopics. Operations at Hanford, as with most other DOE sites, generate un-segregated waste streams, with a wide diversity of Pu isotopics. Consequently, the new SuperHENCs are required to deal with new technical challenges. The neutron system's software and calibration methodology have been modified to encompass these new requirements. In addition, PC-FRAM software has been added to the gamma system, providing a robust isotopic measurement capability. Finally a new software package has been developed that integrates the neutron and gamma data to provide a final assay results and analysis report. The new system's performance has been rigorously tested and validated against WIPP quality requirements. These modifications, together with the mobile platform, make the new SuperHENC far more versatile in handling diverse waste streams and allow for rapid redeployment around the DOE complex. (authors)

  19. Drum inspection robots: Application development

    International Nuclear Information System (INIS)

    Hazen, F.B.; Warner, R.D.

    1996-01-01

    Throughout the Department of Energy (DOE), drums containing mixed and low level stored waste are inspected, as mandated by the Resource Conservation and Recovery Act (RCRA) and other regulations. The inspections are intended to prevent leaks by finding corrosion long before the drums are breached. The DOE Office of Science and Technology (OST) has sponsored efforts towards the development of robotic drum inspectors. This emerging application for mobile and remote sensing has broad applicability for DOE and commercial waste storage areas. Three full scale robot prototypes have been under development, and another project has prototyped a novel technique to analyze robotically collected drum images. In general, the robots consist of a mobile, self-navigating base vehicle, outfitted with sensor packages so that rust and other corrosion cues can be automatically identified. They promise the potential to lower radiation dose and operator effort required, while improving diligence, consistency, and documentation

  20. A neutron well counter for plutonium assay in 200 l waste drums

    International Nuclear Information System (INIS)

    Eyrich, W.; Kuechle, M.; Shafiee, M.

    1979-05-01

    A neutron well counter is briefly described which will be used for monitoring the plutonium content of 200 l barrels in the waste treatment plant of the Kernforschungszentrum Karlsruhe. Measurements on simulated waste were made to study the influence of matrix material and non-homogeneous plutonium distribution. The variation in detection efficiency could be reduced from 28% to 10% when the signals from inner and outer neutron detectors in the polyethylene annulus are counted separately and a correction is applied, using this information. This method is superior to the source addition technique. Coincidence counting shows a larger variation which could not be reduced to below 18%. (orig.) [de

  1. Defense Remote Handled Transuranic Waste Cost/Schedule Optimization Study

    International Nuclear Information System (INIS)

    Pierce, G.D.; Wolaver, R.W.; Carson, P.H.

    1986-11-01

    The purpose of this study is to provide the DOE information with which it can establish the most efficient program for the long management and disposal, in the Waste Isolation Pilot Plant (WIPP), of remote handled (RH) transuranic (TRU) waste. To fulfill this purpose, a comprehensive review of waste characteristics, existing and projected waste inventories, processing and transportation options, and WIPP requirements was made. Cost differences between waste management alternatives were analyzed and compared to an established baseline. The result of this study is an information package that DOE can use as the basis for policy decisions. As part of this study, a comprehensive list of alternatives for each element of the baseline was developed and reviewed with the sites. The principle conclusions of the study follow. A single processing facility for RH TRU waste is both necessary and sufficient. The RH TRU processing facility should be located at Oak Ridge National Laboratory (ORNL). Shielding of RH TRU to contact handled levels is not an economic alternative in general, but is an acceptable alternative for specific waste streams. Compaction is only cost effective at the ORNL processing facility, with a possible exception at Hanford for small compaction of paint cans of newly generated glovebox waste. It is more cost effective to ship certified waste to WIPP in 55-gal drums than in canisters, assuming a suitable drum cask becomes available. Some waste forms cannot be packaged in drums, a canister/shielded cask capability is also required. To achieve the desired disposal rate, the ORNL processing facility must be operational by 1996. Implementing the conclusions of this study can save approximately $110 million, compared to the baseline, in facility, transportation, and interim storage costs through the year 2013. 10 figs., 28 tabs

  2. Transuranic contaminated waste form characterization and data base

    International Nuclear Information System (INIS)

    Kniazewycz, B.G.; McArthur, W.C.

    1980-07-01

    This volume contains 5 appendices. Title listing are: technologies for recovery of transuranics; nondestructive assay of TRU contaminated wastes; miscellaneous waste characteristics; acceptance criteria for TRU waste; and TRU waste treatment technologies

  3. Utilization of metal scrap for the production of waste drums for ultimate disposal

    International Nuclear Information System (INIS)

    Janberg, K.; Rittscher, D.

    1988-01-01

    The contribution reviews the history of development of the techniques for treatment of decommissioning scrap from the beginning of the 1980's onwards (decommissioning of the Niederaichbach and Gundremmingen nuclear power stations), together with the radiological measuring methods required for regulatory purposes. The advantages of the recycling of the metal scrap by means of melting, and of materials utilization for production of waste containers for ultimate storage are discussed together with product quality assurance criteria. (RB) [de

  4. JAEA thermodynamic database for performance assessment of geological disposal of high-level and TRU wastes. Selection of thermodynamic data of molybdenum

    International Nuclear Information System (INIS)

    Kitamura, Akira; Kirishima, Akira; Saito, Takumi; Shibutani, Sanae; Tochiyama, Osamu

    2010-06-01

    Within the scope of the JAEA thermodynamic database project for performance assessment of geological disposal of high-level radioactive and TRU wastes, the selection of the thermodynamic data on the inorganic compounds and complexes of molybdenum were carried out. We focused to select thermodynamic data of aqueous species and compounds which could form under repository conditions for the disposal of radioactive wastes, i.e. relatively low concentration of molybdenum and from near neutral through alkaline conditions. Selection of thermodynamic data was based on the guidelines by the Nuclear Energy Agency in the Organisation for Economic Co-operation and Development (OECD/NEA). Extensive literature survey was performed and all the obtained articles were carefully reviewed to select the thermodynamic data for molybdenum. Thermodynamic data at 25degC and zero ionic strength were determined from accepted thermodynamic data which were considered to be reliable. We especially paid attention to select formation constant of molybdate ion (MoO 4 2- ) with hydrogen ion (H + ) in detail. This is the first report in showing selection of thermodynamic data for molybdenum with detailed reviewing process. (author)

  5. Relative performance of a TGS for the assay of drummed waste as function of collimator opening

    International Nuclear Information System (INIS)

    Kane, S.C.; Croft, S.; McClay, P.; Venkataraman, R.; Villani, M.F.

    2007-01-01

    Improving the safety, accuracy and overall cost effectiveness of the processes and methods used to characterize and handle radioactive waste is an on-going mission for the nuclear industry. An important contributor to this goal is the development of superior non-destructive assay instruments. The Tomographic Gamma Scanner (TGS) is a case in point. The TGS applies low spatial resolution experimental computed tomography (CT) linear attenuation coefficient maps with three-dimensional high-energy resolution single photon emission reconstructions. The results are presented as quantitative matrix attenuation corrected images and assay values for gamma-emitting radionuclides. Depending on a number of operational factors, this extends the diversity of waste forms that can be assayed, to a given accuracy, to items containing more heterogeneous matrix distributions and less uniform emission activity distributions. Recent advances have significantly extended the capability to a broader range of matrix density and to a wider dynamic range of surface dose rate. Automated systems sense the operational conditions, including the container type, and configure themselves accordingly. The TGS also provides a flexible data acquisition platform and can be used to perform far-field style measurements, classical segmented gamma scanner measurements, or to implement hybrid methods, such as reconstructions that use a priori knowledge to constrain the image reconstruction or the underlying energy dependence of the attenuation. A single, yet flexible, general purpose instrument of this kind adds several tiers of strategic and tactical value to facilities challenged by a diverse and difficult to assay waste streams. The TGS is still in the early phase of industrial uptake. There are only a small number of general purpose TGS systems operating worldwide, most being configured to automatically select between a few configurations appropriate for routine operations. For special investigations

  6. TRU assay system and measurements

    International Nuclear Information System (INIS)

    Brodzinski, R.L.

    1984-02-01

    The measurement of the transuranic content of nuclear products or process residues has become increasingly important for the recovery of fissionable material from spent fuel elements, the identification of commercial fuel elements which have not yet reached full burnup, the measurement and recovery of transuranics from discarded or stored waste materials, the determination of the transuranic content in high gamma activity waste material scheduled for disposal, compliance with 10CFR61 by land burial operators/shippers, and the satisfaction of accountability requirements. Active neutron interrogation techniques measure either the prompt neutrons or the beta delayed neutrons from fission products following induced fission. These techniques normally only measure fissile transuranics ( 235 U, 239 Pu, and 241 Pu) and are commonly applied only to contact handleable waste. Passive neutron interrogation techniques, on the other hand, are capable of measuring all transuranics except 235 U with adequate sensitivity and will work on both contact handleable and high gamma activity wastes. Since the passive techniques are senstitive to a wider spectrum of transuranic isotopes than the active techniques, substantially less complex and less expensive than the active systems, and they have proven techniques for measuring small quantities of TRU in high gamma activity packages, the passive neutron TRU assay technology was chosen for development into the instruments discussed in this paper

  7. Multimodality characterization of nuclear waste drums using emerging techniques for nondestructive examination and assay

    International Nuclear Information System (INIS)

    Bernardi, R.T.

    1993-01-01

    We are developing an x-ray imaging system that incorporates several inspection technologies for complete, nondestructive evaluation of containers of nuclear waste. In Phase I and Phase II SBIR programs for the DOE, we proved the feasibility of using x-ray computed tomography (CT) and digital radiography (DR)-imaging techniques using x-rays transmitted through the object-for container inspection. Now, with further funding from DOE and working with scientists at Lawrence Livermore National Lab., we are designing a mobile inspection system that will use CT and DR as well as two x-ray emission imaging techniques-single photon emission computed tomography and nondestructive assay. This system will provide much more information about the contents of containers than currently used inspection methods, and will provide archiving of digital data. In this paper, we describe inspection system and present recent results from the CT and DR evaluations

  8. Characterization of alpha low level waste in 118 litre drums by passive and active neutron measurements in the promethee assay system

    International Nuclear Information System (INIS)

    Jallu, F.; Passard, C.; Mariani, A.; Ma, J.L.; Baudry, G.; Romeyer-Dherbey, J.; Recroix, H.; Rodriguez, M.; Loridon, J.; Denis, C.; Toubon, H.

    2003-01-01

    This paper deals with the PROMETHEE (PROMpt, epithermal and THErmal interrogation experiment) waste assay system for alpha low level waste (LLW) characterization. This device, including both passive and active neutron measurement methods, is developed at the French Atomic Energy Commission (C.E.A.), Cadarache Centre, in cooperation with COGEMA. Its purpose is to reach the requirements for incinerating alpha waste (less than 50 Bq[α], i.e. about 50 μg of Pu per gram of raw waste) in 118 litre- > drums. The PROMETHEE development and progress are performed with the help of simulation based on the Monte Carlo code MCNP4 [1]. These calculations are coupled with specific experiments in order to confirm calculated results and to obtain characteristics that can not be approached by the simulation (background for example). This paper presents the PROMETHEE measurement cell, its current performances, and studies performed at the laboratory about the most limiting parameters such as the matrix of the drum - its composition (H, Cl..), its density and its heterogeneity degree -the localization and the self-shielding properties of the contaminant. (orig.)

  9. Characterization of alpha low level waste in 118 litre drums by passive and active neutron measurements in the promethee assay system

    Energy Technology Data Exchange (ETDEWEB)

    Jallu, F.; Passard, C.; Mariani, A.; Ma, J.L.; Baudry, G.; Romeyer-Dherbey, J.; Recroix, H.; Rodriguez, M.; Loridon, J.; Denis, C. [French Atomic Energy Commission (C.E.A./Cadarache), DED/SCCD/LDMN, Durance (France); Toubon, H. [COGEMA, VELIZY-VILLACOUBLAY (France)

    2003-07-01

    This paper deals with the PROMETHEE (PROMpt, epithermal and THErmal interrogation experiment) waste assay system for alpha low level waste (LLW) characterization. This device, including both passive and active neutron measurement methods, is developed at the French Atomic Energy Commission (C.E.A.), Cadarache Centre, in cooperation with COGEMA. Its purpose is to reach the requirements for incinerating alpha waste (less than 50 Bq[{alpha}], i.e. about 50 {mu}g of Pu per gram of raw waste) in 118 litre-<> drums. The PROMETHEE development and progress are performed with the help of simulation based on the Monte Carlo code MCNP4 [1]. These calculations are coupled with specific experiments in order to confirm calculated results and to obtain characteristics that can not be approached by the simulation (background for example). This paper presents the PROMETHEE measurement cell, its current performances, and studies performed at the laboratory about the most limiting parameters such as the matrix of the drum - its composition (H, Cl..), its density and its heterogeneity degree -the localization and the self-shielding properties of the contaminant. (orig.)

  10. Experimental study on the properties of drum-packed, cement solidified waste package of pre and after sea dumping test of sea depth 30m and 100m

    International Nuclear Information System (INIS)

    Maki, Yasuro; Abe, Hirotoshi; Hattori, Seiichi

    1976-01-01

    Japan Marine Science and Technology Center has been tackling with the development of the monitoring system to confirm the soundness of drum-packed, cement-solidified low level radioactive waste (the package) during falling and after reaching at sea bed when it is dumped into sea. The test was carried out at Sagami Bay of 30 m and 100 m sea depth using non-radioactive packages. The observation of the falling behaviour of packages in sea was carried out by taking photographs of the motion of packages with an underwater 16 mm movie camera and an underwater industrial TV (ITV), and the observation of the soundness and the area of packages scattered on sea bed was carried out with an underwater ITV and an underwater 70 mm snap camera which were set up on the frame. The proportion of cement-solidified waste was decided so that the uni-axial compressive strength of the cement-solidified waste satisfies the condition of ''The tentative guideline''. Prior to tests at sea, hydrostatic pressure test of packages are carried out on land. After that, core specimens were sampled to obtain the uniaxial compressive strength from packages and were tested. After sea dumping tests, 6 packages were recovered from sea bed, and the soundness were tested. As the results, the deformation and damage of drums and cement solidified waste packages did not occur at all. (Kako, I.)

  11. Defense Waste Management Plan for buried transuranic-contaminated waste, transuranic-contaminated soil, and difficult-to-certify transuranic waste

    International Nuclear Information System (INIS)

    1987-06-01

    GAO recommended that DOE provide specific plans for permanent disposal of buried TRU-contaminated waste, TRU-contaminated soil, and difficult-to-certify TRU waste; cost estimates for permanent disposal of all TRU waste, including the options for the buried TRU-contaminated waste, TRU-contaminated soil, and difficult-to-certify TRU waste; and specific discussions of environmental and safety issues for the permanent disposal of TRU waste. Purpose of this document is to respond to the GAO recommendations by providing plans and cost estimates for the long-term isolation of the buried TRU-contaminated waste, TRU-contaminated soil, and difficult-to-certify TRU waste. This report also provides cost estimates for processing and certifying stored and newly generated TRU waste, decontaminating and decommissioning TRU waste processing facilities, and interim operations

  12. Nuclear heat-load limits for above-grade storage of solid transuranium wastes

    International Nuclear Information System (INIS)

    Clontz, B.G.

    1978-06-01

    Nuclear safety and heat load limits were established for above-grade storage of transuranium (TRU) wastes. Nuclear safety limits were obtained from a study by J.L. Forstner and are summarized. Heat load limits are based on temperature calculations for TRU waste drums stored in concrete containers (hats), and results are summarized. Waste already in storage is within these limits. The limiting factors for individual drum heat load limits were (1) avoidance of temperatures in excess of 190 0 F (decomposition temperature of anion resin) when anion resin is present in a concrete hat, and (2) avoidance of temperatures in excess of 450 0 F (ignition temperature of paper) at any point inside a waste drum. The limiting factor for concrete had heat load limits was avoidance of temperatures in excess of 265 0 F (melt point of high density polyethylene) at the drum liners. A temperature profile for drums and hats filled to recommended limits is shown. Equations and assumptions used were conservative

  13. Disposal of TRU Waste from the PFP in pipe overpack containers to WIPP Including New Security Requirements

    International Nuclear Information System (INIS)

    HOPKINS, A.M.

    2003-01-01

    The Department of Energy is responsible for the safe management and cleanup of the DOE complex. As part of the cleanup and closure of the Plutonium Finishing Plant (PFP) located on the Hanford site, the nuclear material inventory was reviewed to determine the appropriate disposition path. Based on the nuclear material characteristics, the material was designated for stabilization and packaging for long term storage and transfer to the Savannah River Site, or a decision for discard was made. The discarded material was designated as waste material and slated for disposal to the Waste Isolation Pilot Plant (WIPP). Prior to preparing any residue wastes for disposal at the WIPP, several major activities need to be completed. As detailed a processing history as possible of the material including origin of the waste must be researched and documented. A technical basis for termination of safeguards on the material must be prepared and approved. Utilizing process knowledge and processing history, the material must be characterized, sampling requirements determined, acceptable knowledge package and waste designation completed prior to disposal. All of these activities involve several organizations including the contractor, DOE, state representatives and other regulators such as EPA. At PFP, a process has been developed for meeting the many, varied requirements and successfully used to prepare several residue waste streams including Rocky Flats incinerator ash, hanford incinerator ash and Sand, Slag and Crucible (SS and C) material for disposal. These waste residues are packed into Pipe Overpack Containers for shipment to the WIPP

  14. IMPROVEMENTS IN HANFORD TRANSURANIC (TRU) PROGRAM UTILIZING SYSTEMS MODELING AND ANALYSES

    International Nuclear Information System (INIS)

    UYTIOCO EM

    2007-01-01

    Hanford's Transuranic (TRU) Program is responsible for certifying contact-handled (CH) TRU waste and shipping the certified waste to the Waste Isolation Pilot Plant (WIPP). Hanford's CH TRU waste includes material that is in retrievable storage as well as above ground storage, and newly generated waste. Certifying a typical container entails retrieving and then characterizing it (Real-Time Radiography, Non-Destructive Assay, and Head Space Gas Sampling), validating records (data review and reconciliation), and designating the container for a payload. The certified payload is then shipped to WIPP. Systems modeling and analysis techniques were applied to Hanford's TRU Program to help streamline the certification process and increase shipping rates

  15. Uptake of radiocarbon from plant rhizosphere based on geological disposal of TRU waste. Root-uptake of radiocarbon carbon derived from acetic acid

    International Nuclear Information System (INIS)

    Ogiyama, Shinichi; Takeda, Hiroshi; Uchida, Shigeo; Suzuki, Hiroyuki; Inubushi, Kazuyuki

    2008-01-01

    Hydroponic experiments were conducted to examine root-uptake of 14 C in the form of acetic acid by 3 kinds of plants (marigold, tall fescue, and paddy rice) based on buried transuranic (TRU) waste disposal. Also, chamber experiment was conducted to examine loss of 14 C as vaporized carbon dioxide (CO 2 ) from the experimental tessera (spatially heterogeneous environment). The distribution of radioactivity in the plant, mediums, and carbon dioxide ( 14 CO 2 ) in the chamber were determined, and the distribution of 14 C in the plant was visualized by the autoradiography. The plants absorbed and assimilated 14 C through the roots. The amount of 14 C in marigold and tall fescue were higher than that of paddy rice. However, the amounts of 14 C-acetic acid absorbed by all the plants through their roots were considered to be very small. More so, 14 CO 2 gas was released from the culture solution to the atmosphere; however, it was not enough for the plant to perform photosynthesis. Assimilation of 14 C in the plant shoots would be because of 14 C movement of inorganic forms such as CO 2 and HCO 3 - via the roots. Thus, the results indicated that the plants absorbed 14 C through the roots and assimilated it into the shoots or edible parts not because of uptake of 14 C-acetic acid but because of uptake of 14 C in inorganic forms. (author)

  16. Volume reduction and conditioning campaigns, upon low level solid waste drums, realised in ENEA centres of Trisaia (ITREC plant) and Saluggia (EUTREX plant)

    International Nuclear Information System (INIS)

    Gili, M.

    1995-09-01

    The volume reduction and conditioning campaigns, upon low level solid waste drums, realized between 1989 and 1993 in the ENEA (Italian Agency for New Technologies, Energy and the Environment) centres of Trisaia (ITREC plant) and Saluggia (EUREX plant), by the mean of supercompactation, and cement immobilization inside over packs, are hereby described. The operational techniques and the equipments used, the whole volume reduction factors obtained and some final considerations over this solid rad wastes treatment procedure are shown. This method, where correctly operated and coupled to an accurate radiological characterization, permits to save space for the waste storage in the short period and to obtain final manufacts, certified suitable for shallow burial disposal, according to italian technical guide n. 26

  17. Enhancing TRU burning and Am transmutation in Advanced Recycling Reactor

    International Nuclear Information System (INIS)

    Ikeda, Kazumi; Kochendarfer, Richard A.; Moriwaki, Hiroyuki; Kunishima, Shigeru

    2011-01-01

    Research highlights: → This ARR is an oxide fueled sodium cooled reactor based on innovative technologies to destruct TRU. → TRU burning core is designed to burn TRU at 28 kg/TW th h, adding moderator pins of B 4 C (Enriched B-11). → Am transmutation core can transmute Am at 34 kg/TW th h, adding uranium free AmN blanket to TRU burning core. → The TRU burning core improves TRU burning by 40-50% than the previous core. → The Am transmutation core can transmute Am effectively, keeping the void reactivity acceptable. - Abstract: This paper presents about conceptual designs of Advanced Recycling Reactor (ARR) focusing on enhancement in transuranics (TRU) burning and americium (Am) transmutation. The design has been conducted in the context of the Global Nuclear Energy Partnership (GNEP) seeking to close nuclear fuel cycle in ways that reduce proliferation risks, reduce the nuclear waste in the US and further improve global energy security. This study strives to enhance the TRU burning and the Am transmutation, assuming the development of related technologies in this study, while the ARR based on mature technologies was designed in the previous study. It has followed that the provided TRU burning core is designed to burn TRU at 28 kg/TW th h, by adding moderator pins of B 4 C (Enriched B-11) and the Am transmutation core will be able to transmute Am at 34 kg/TW th h, by locating Am blanket of AmN around the TRU burning core. It indicates that these concepts improve TRU burning by 40-50% than the previous core and can transmute Am effectively, keeping the void reactivity acceptable.

  18. Crack formation in cementitious materials used for an engineering barrier system and their impact on hydraulic conductivity from the viewpoint of performance assessment of a TRU waste disposal system

    International Nuclear Information System (INIS)

    Hirano, Fumio; Mihara, Morihiro; Honda, Akira; Otani, Yoshiteru; Kyokawa, Hiroyuki; Shimizu, Hiroyuki

    2016-01-01

    The mechanical analysis code MACBECE2014 has been developed at the Japan Atomic Energy Agency (JAEA) to make realistic simulations of the physical integrity of the near field for performance assessment of the geological disposal of TRU waste in Japan. The MACBECE2014 code can be used to evaluate long-term changes in the mechanical behavior of the near field and any subsequent changes in the permeability of engineering barrier components, including crack formation in cementitious materials caused by expansion due to metal corrosion. Cracks in cementitious materials are likely to channel the flow of groundwater and so the represent preferred flow paths of any released radionuclides. Mechanical analysis was conducted using the MACBECE2014 code to investigate the concept of the TRU waste disposal system described in JAEA's Second Progress TRU Report. Simulated results of a disposal system with a bentonite buffer demonstrated that the low permeability of the engineering barrier system could be maintained for long time periods because the physical integrity of the bentonite buffer remained intact even if cracks in the cementitious components had formed locally. Simulated results of the disposal system with a concrete backfill instead of a bentonite buffer showed that crack formation leads to a significant increase in the permeability of the engineering barrier system. (author)

  19. Position for determining gas-phase volatile organic compound concentrations in transuranic waste containers. Revision 2

    Energy Technology Data Exchange (ETDEWEB)

    Connolly, M.J.; Liekhus, K.J. [Lockheed Martin Idaho Technologies Co., Idaho Falls, ID (United States). Idaho National Engineering and Environmental Lab.; Djordjevic, S.M.; Loehr, C.A.; Spangler, L.R. [Benchmark Environmental Corp. (United States)

    1998-06-01

    In the conditional no-migration determination (NMD) for the test phase of the Waste Isolation Pilot Plant (WIPP), the US Environmental Protection Agency (EPA) imposed certain conditions on the US Department of Energy (DOE) regarding gas phase volatile organic compound (VOC) concentrations in the void space of transuranic (TRU) waste containers. Specifically, the EPA required the DOE to ensure that each waste container has no layer of confinement that contains flammable mixtures of gases or mixtures of gases that could become flammable when mixed with air. The EPA also required that sampling of the headspace of waste containers outside inner layers of confinement be representative of the entire void space of the container. The EPA stated that all layers of confinement in a container would have to be sampled until DOE can demonstrate to the EPA that sampling of all layers is either unnecessary or can be safely reduced. A test program was conducted at the Idaho National Engineering and Environmental Laboratory (INEEL) to demonstrate that the gas phase VOC concentration in the void space of each layer of confinement in vented drums can be estimated from measured drum headspace using a theoretical transport model and that sampling of each layer of confinement is unnecessary. This report summarizes the studies performed in the INEEL test program and extends them for the purpose of developing a methodology for determining gas phase VOC concentrations in both vented and unvented TRU waste containers. The methodology specifies conditions under which waste drum headspace gases can be said to be representative of drum gases as a whole and describes a method for predicting drum concentrations in situations where the headspace concentration is not representative. The methodology addresses the approach for determining the drum VOC gas content for two purposes: operational period drum handling and operational period no-migration calculations.

  20. Position for determining gas phase volatile organic compound concentrations in transuranic waste containers. Revision 1

    International Nuclear Information System (INIS)

    Connolly, M.J.; Liekhus, K.J.; Djordjevic, S.M.; Loehr, C.A.; Spangler, L.R.

    1995-08-01

    In the conditional no-migration determination (NMD) for the test phase of the Waste Isolation Pilot Plant (WIPP), the US Environmental Protection Agency (EPA) imposed certain conditions on the US Department of Energy (DOE) regarding gas phase volatile organic compound (VOC) concentrations in the void space of transuranic (TRU) waste containers. Specifically, the EPA required the DOE to ensure that each waste container has no layer of confinement that contains flammable mixtures of gases or mixtures of gases that could become flammable when mixed with air. The EPA also required that sampling of the headspace of waste containers outside inner layers of confinement be representative of the entire void space of the container. The EPA stated that all layers of confinement in a container would have to be sampled until DOE can demonstrate to the EPA that sampling of all layers is either unnecessary or can be safely reduced. A test program was conducted at the Idaho National Engineering Laboratory (INEL) to demonstrate that the gas phase VOC concentration in the void space of each layer of confinement in vented drums can be estimated from measured drum headspace using a theoretical transport model and that sampling of each layer of confinement is unnecessary. This report summarizes the studies performed in the INEL test program and extends them for the purpose of developing a methodology for determining gas phase VOC concentrations in both vented and unvented TRU waste containers. The methodology specifies conditions under which waste drum headspace gases can be said to be representative of drum gases as a whole and describes a method for predicting drum concentrations in situations where the headspace concentration is not representative. The methodology addresses the approach for determining the drum VOC gas content for two purposes: operational period drum handling and operational period no-migration calculations

  1. Position for determining gas-phase volatile organic compound concentrations in transuranic waste containers. Revision 2

    International Nuclear Information System (INIS)

    Connolly, M.J.; Liekhus, K.J.

    1998-06-01

    In the conditional no-migration determination (NMD) for the test phase of the Waste Isolation Pilot Plant (WIPP), the US Environmental Protection Agency (EPA) imposed certain conditions on the US Department of Energy (DOE) regarding gas phase volatile organic compound (VOC) concentrations in the void space of transuranic (TRU) waste containers. Specifically, the EPA required the DOE to ensure that each waste container has no layer of confinement that contains flammable mixtures of gases or mixtures of gases that could become flammable when mixed with air. The EPA also required that sampling of the headspace of waste containers outside inner layers of confinement be representative of the entire void space of the container. The EPA stated that all layers of confinement in a container would have to be sampled until DOE can demonstrate to the EPA that sampling of all layers is either unnecessary or can be safely reduced. A test program was conducted at the Idaho National Engineering and Environmental Laboratory (INEEL) to demonstrate that the gas phase VOC concentration in the void space of each layer of confinement in vented drums can be estimated from measured drum headspace using a theoretical transport model and that sampling of each layer of confinement is unnecessary. This report summarizes the studies performed in the INEEL test program and extends them for the purpose of developing a methodology for determining gas phase VOC concentrations in both vented and unvented TRU waste containers. The methodology specifies conditions under which waste drum headspace gases can be said to be representative of drum gases as a whole and describes a method for predicting drum concentrations in situations where the headspace concentration is not representative. The methodology addresses the approach for determining the drum VOC gas content for two purposes: operational period drum handling and operational period no-migration calculations

  2. Department of Energy Idaho Operations Office evaluation of feasibility studies for private sector treatment of alpha and TRU mixed wastes

    International Nuclear Information System (INIS)

    1995-05-01

    The Idaho National Engineering Laboratory (INEL) is currently storing a large quantity of alpha contaminated mixed low level waste which will require treatment prior to disposal. The DOE Idaho Operations Office (DOE-ID) recognized that current knowledge and funding were insufficient to directly pursue services for the requisite treatment. Therefore, it was decided that private sector studies would be funded to clarify cost, regulatory, technology, and contractual issues associated with procuring treatment services. This report analyzes the three private sector studies procured and recommends a path forward for DOE in procuring retrieval, assay, characterization, and treatment services for INEL transuranic and alpha contaminated mixed low level waste. This report was prepared by a team of subject matter experts from the INEL referred to as the DOE-ID Evaluation Team

  3. Design of a neutron interrogation cell based on an electron accelerator and performance assessment on 220 liter nuclear waste mock-up drums

    International Nuclear Information System (INIS)

    Sari, A.; Carrel, F.; Laine, F.; Lyoussi, A.

    2013-01-01

    Radiological characterization of nuclear waste drums is an important task for the nuclear industry. The amount of actinides, such as 235 U or 239 Pu, contained in a package can be determined using non-destructive active methods based on the fission process. One of these techniques, known as neutron interrogation, uses a neutron beam to induce fission reactions on the actinides. Optimization of the neutron flux is an important step towards improving this technique. Electron accelerators enable to achieve higher neutron flux intensities than the ones delivered by deuterium-tritium generators traditionally used on neutron interrogation industrial facilities. In this paper, we design a neutron interrogation cell based on an electron accelerator by MCNPX simulation. We carry out photoneutron interrogation measurements on uranium samples placed at the center of 220 liter nuclear waste drums containing different types of matrices. We quantify impact of the matrix on the prompt neutron signal, on the ratio between the prompt and delayed neutron signals, and on the interrogative neutron half-life time. We also show that characteristics of the conversion target of the electron accelerator enable to improve significantly measurement performances. (authors)

  4. Innovative Applications of In Situ Gamma Spectroscopy for Non-destructive Assay of Transuranic Wastes

    International Nuclear Information System (INIS)

    Watters, D.J.; Weismann, J.J.; Duke, S.J.; Nicosia, W.C.

    2009-01-01

    Cabrera Services (CABRERA), under contract to National Security Technologies, LLC (NSTec), supported the transuranic (TRU) waste reduction initiative at the Radioactive Waste Management Complex of the Nevada Test Site (NTS). CABRERA developed advanced NDA techniques for oversized boxes (OSB) and drums using in situ gamma spectroscopy during several phases of the project. A more thorough characterization method was employed during the planning phase of the project to better understand the TRU content and distribution within each container, while a comprehensive NDA program was designed and implemented during the intrusive phase that guided waste segregation and re-packaging of both TRU and low-level wastes (LLW). NSTec took receipt of 58 oversized boxes of suspect TRU waste from Lawrence Livermore National Lab (LLNL). TRU waste is defined as greater than 3.7 kilobecquerels per gram [kBq/g] (100 nanocuries (nCi)/g) activity from alpha-emitting radionuclides with atomic number greater than 92 having a half-life greater than 20 years. Each box was custom-made to house a variety of suspect TRU wastes resulting from years of weapons program research, development, and testing. Since their arrival at NTS, the boxes have undergone several iterations of non-destructive assay (NDA) in preparation for the comprehensive repackaging effort. NDA has included two rounds of in situ gamma spectroscopy and real-time radiography (RTR) scans that were videotaped. Contents have been confirmed to include glove boxes, HEPA filters and their housings, and assorted process equipment and piping. TRU content was determined via directly measuring plutonium-239 (Pu-239), americium-241 (Am-241), and other radionuclides, while adding calculated results for non-measurable nuclides using reliable scaling factors developed from acceptable knowledge (AK). Advantages of CABRERA's NDA methods included: - More NDA information is available in the same amount of counting time, allowing NSTec to make more

  5. Selective cesium and strontium removal for TRU-liquid waste including fission products and concentrated nitric acids

    International Nuclear Information System (INIS)

    Mimori, T.; Miyajima, K.; Kozeki, M.; Kubota, T.; Tusa, E.; Keskinen, A.

    1996-01-01

    A nuclide removal system was designed for treatment of liquid radioactive waste at the Japan Atomic Energy Research Institute (JAERI) Tokai site. Total system will include removal of plutonium, cesium and strontium. Removal of plutonium will be carried out by a method developed by JAERI. Removal of cesium and strontium will be carried out by the methods developed in Finland. The whole project will be implemented for JAERI in cooperation between Mitsui Engineering and Shipbuilding and IVO International. This project has been carried out under the Science and Technology Agency (STA) of Japan. The liquid to be treated includes 7.4x10 9 Bq/L of cesium and 7.4x10 9 Bq/L of strontium. The amount of alpha nuclides is 3.7x10 6 Bq/L. Nitric acid concentration is 1.74 mol/L. The volume of 11,000 liters had to be treated in 200 batches of operation. Removal of cesium and strontium is based on the use of new ion exchange materials developed in Finland. These inorganic ion exchange materials have extremely good properties to separate cesium and strontium from even very difficult liquids. Ion exchange material will be used in columns, where there are materials both for cesium and strontium. According to column tests with simulated waste, one 2 liter column will effectively reach the required DF during 10 batches of operation. Purified liquid can be led to further liquid treatment at the site. After treatment of liquids, both used particle filters and used ion exchange columns will be drained and stored to wait for final treatment and disposal. The designed treatment system has a special beneficial feature as it does not produce secondary waste. Final waste is in the form of particle filters or ion exchange columns with material. Used ion exchange columns and filters will be replaced with new ones by means of remote handling. Construction of the treatment system will be scheduled to commence in FY1995 and assemblying at the site in FY1996. (J.P.N.)

  6. CT examination of radwaste drums