WorldWideScience

Sample records for transferring secondary gas

  1. Gas transfer system

    International Nuclear Information System (INIS)

    Oberlin, J.C.; Frick, G.; Kempfer, C.; North, C.

    1988-09-01

    The state of work on the Vivitron gas transfer system and the system functions are summarized. The system has to: evacuate the Vivitron reservoir; transfer gas from storage tanks to the Vivitron; recirculate gas during operation; transfer gas from the Vivitron to storage tanks; and assure air input. The system is now being installed. Leak alarms are given by SF6 detectors, which set off a system of forced ventilation. Another system continuously monitors the amount of SF6 in the tanks [fr

  2. A Secondary Flow Effect on the Heat and Mass Transfer Processes in the Finned Rod Bundles of Gas-cooled Reactors

    Directory of Open Access Journals (Sweden)

    A. A. Dunaitsev

    2017-01-01

    Full Text Available In nuclear power engineering a need to justify an operability of products and their components is of great importance. In high-temperature gas reactors, the critical element affecting the facility reliability is the fuel rod cladding, which in turn leads to the need to gain knowledge in the field of gas dynamics and heat transfer in the reactor core and to increase the detail of the calculation results. For the time being, calculations of reactor core are performed using the proven techniques of per-channel calculations, which show good representativeness and count rate. However, these techniques require additional experimental studies to describe correctly the inter-channel exchange, which, being taken into account, largely affects the pattern of the temperature fields in the region under consideration. Increasingly more relevant and demandable are numerical simulation methods of fluid and gas dynamics, as well as of heat exchange, which consist in the direct solution of the system of differential equations of mass balance, kinetic moment, and energy. Calculation of reactor cores or rod bundles according these techniques does not require additional experimental studies and allows us to obtain the local distributions of flow characteristics in the bundle and the flow characteristics that are hard to measure in the physical experiment.The article shows the calculation results and their analysis for an infinite rod lattice of the reactor core. The results were obtained by the technique of modelling one rod of a regular lattice using the periodic boundary conditions, followed by translating the results to the neighbouring rods. In channels of complex shape, there are secondary flows caused by changes in the channel geometry along the flow and directed across the main front of the flow. These secondary flows in the reactor cores with rods spaced by the winding wire lead to a redistribution of the coolant along the channel section, which in turn

  3. Chemical composition, secondary metabolites, in vitro gas ...

    African Journals Online (AJOL)

    Chemical composition, secondary metabolites, in vitro gas production characteristics and acceptability study of some forage for ruminant feeding in South-Western Nigeria. ... Chemical composition and qualitative analysis of saponins, phenol and steroids of the plants were determined. In vitro gas production (IVGP) was ...

  4. Gas transfer velocities in small forested ponds

    Science.gov (United States)

    Holgerson, Meredith A.; Farr, Emily R.; Raymond, Peter A.

    2017-05-01

    Inland waters actively exchange gases with the atmosphere, and the gas exchange rate informs system biogeochemistry, ecology, and global carbon budgets. Gas exchange in medium- to large-sized lakes is largely regulated by wind; yet less is known about processes regulating gas transfer in small ponds where wind speeds are low. In this study, we determined the gas transfer velocity, k600, in four small (water temperature; however, the explanatory power was weak (R2 water bodies, we compiled direct measurements of k600 from 67 ponds and lakes worldwide. Our k600 estimates were within the range of estimates for other small ponds, and variability in k600 increased with lake size. However, the majority of studies were conducted on medium-sized lakes (0.01 to 1 km2), leaving small ponds and large lakes understudied. Overall, this study adds four small ponds to the existing body of research on gas transfer velocities from inland waters and highlights uncertainty in k600, with implications for calculating metabolism and carbon emissions in inland waters.

  5. Heat transfer to accelerating gas flows

    International Nuclear Information System (INIS)

    Kennedy, T.D.A.

    1978-01-01

    The development of fuels for gas-cooled reactors has resulted in a number of 'gas loop' experiments in materials-testing research reactors. In these experiments, efforts are made to reproduce the conditions expected in gas-cooled power reactors. Constant surface temperatures are sought over a short (300 mm) fuelled length, and because of entrance effects, an accelerating flow is required to increase the heat transfer down-stream from the entrance. Strong acceleration of a gas stream will laminarise the flow even at Reynolds Numbers up to 50000, far above values normally associated with laminar flow. A method of predicting heat transfer in this situation is presented here. An integral method is used to find the velocity profile; this profile is then used in an explicit finite-difference solution of the energy equation to give a temperature profile and resultant heat-transfer coefficient values. The Kline criterion, which compares viscous and disruptive forces, is used to predict whether the flow will be laminar. Experimental results are compared with predictions, and good agreement is found to exist. (author)

  6. Penning transfer in argon-based gas mixtures

    CERN Document Server

    Sahin, O; Tapan, I; Ozmutlu, E N

    2010-01-01

    Penning transfers, a group of processes by which excitation energy is used to ionise the gas, increase the gas gain in some detectors. Both the probability that such transfers occur and the mechanism by which the transfer takes place, vary with the gas composition and pressure. With a view to developing a microscopic electron transport model that takes Penning transfers into account, we use this dependence to identify the transfer mechanisms at play. We do this for a number of argon-based gas mixtures, using gain curves from the literature.

  7. Mass transfer in gas-liquid slurry reactors

    NARCIS (Netherlands)

    Beenackers, A.A.C.M.; van Swaaij, Willibrordus Petrus Maria

    1993-01-01

    A critical review is presented on the mass transfer characteristics of gas¿liquid slurry reactors. The recent findings on the influence of the presence of solid particles on the following mass transfer parameters in slurry reactors are discussed: volumetric gas¿liquid mass transfer coefficients

  8. Gas turbine heat transfer and cooling technology

    CERN Document Server

    Han, Je-Chin; Ekkad, Srinath

    2012-01-01

    FundamentalsNeed for Turbine Blade CoolingTurbine-Cooling TechnologyTurbine Heat Transfer and Cooling IssuesStructure of the BookReview Articles and Book Chapters on Turbine Cooling and Heat TransferNew Information from 2000 to 2010ReferencesTurbine Heat TransferIntroductionTurbine-Stage Heat TransferCascade Vane Heat-Transfer ExperimentsCascade Blade Heat TransferAirfoil Endwall Heat TransferTurbine Rotor Blade Tip Heat TransferLeading-Edge Region Heat TransferFlat-Surface Heat TransferNew Information from 2000 to 20102.10 ClosureReferencesTurbine Film CoolingIntroductionFilm Cooling on Rotat

  9. A windowless gas target for secondary beam production

    CERN Document Server

    Kishida, T; Shibata, M; Watanabe, H; Tsutsumi, T; Motomura, S; Ideguchi, E; Zhou, X H; Morikawa, T; Kubo, T; Ishihara, M

    1999-01-01

    A windowless gas target was developed for the production of secondary high-spin isomer beams (HSIB). An sup 1 sup 6 O target in the compound form of CO sub 2 gas was used to produce a sup 1 sup 4 sup 5 sup m Sm beam by using an sup 1 sup 6 O( sup 1 sup 3 sup 6 Xe, 7n) sup 1 sup 4 sup 5 sup m Sm reaction. The target gas pressure was kept constant at 50 Torr. A target thickness of about 1 mg/cm sup 2 was achieved with a 10 cm target length. Gas was recirculated and the consumption was very little.

  10. Secondary origin of negative carbon isotopic series in natural gas

    Directory of Open Access Journals (Sweden)

    Jinxing Dai

    2016-02-01

    Full Text Available The carbon isotopic series of alkane gases were divided into three types: (1 positive carbon isotopic series: δ13C values increased with increasing carbon numbers among the C1–C4 alkanes, which is a typical characteristic for primary alkane gases; (2 negative carbon isotopic series: δ13C values decreased with increasing carbon numbers among the C1–C4 alkanes; and (3 partial carbon isotopic reversal, which had no increasing or decreasing relationship between the δ13C values and carbon numbers. Negative carbon isotopic series were further divided into primary and secondary origins. The primary is a typical characteristic of abiogenic gases, while the secondary is a result of the secondary alteration imposed on biogenic gases usually observed in over-mature shale gas and coal-derived gas. Previous research has proposed several possible explanations for negative carbon isotopic series of secondary origin, such as secondary cracking, diffusion, and the Rayleigh fractionation of ethane and propane through redox reaction with the participation of transition metal and water at 250–300 °C. After a comparative study, the authors found that the negative carbon isotopic series of secondary origin for both shale gas and coal-derived gas appeared in areas where source rocks (shales were at an over-mature stage, but not in areas where source rocks (shales were only at a high-maturity stage. As a result, high maturity (>200 °C was the main controlling factor for the occurrence of negative carbon isotopic series of secondary origin in thermogenic gases. Within this maturity interval, secondary cracking, diffusion, and Rayleigh fractionation of ethane and propane could happen separately or together.

  11. Review of RSG-GAS secondary cooling pump performance

    International Nuclear Information System (INIS)

    Marsahala, Y.B.

    1999-01-01

    The control system of RSG-GAS secondary pump is the study for the operation existence of RSG-GAS secondary pump. The research is about characteristic of the secondary pump and its control system. The measuring of characteristic parameter of secondary cooling pump was being done while the pump running. The pump was loading with capacity 1950 m3/hr. with ambient temperature 28.5 oC. The fault effect of public grid (PLN) such as the fluctuation of both voltage and frequency likes voltage drops (dip). Supply block out that effect of the electric motor performances directly will be analyzed. How far those faults will effect the overall performance of secondary cooling system. Analyzing. Will be done according to the control system was installed. Has be done to find the direct effects of the motor performances against the motor rotation fluctuation which run from 1450 rpm to 1475 rpm. The using of start-delta starting method with delay time about 6 seconds, is enough or not to reduce the inrush starting current also analyzed in this paper. From the research can be obtained that in the steady state condition , the electric motor runs with both power and current are still under tolerances permitted. According to the analyzed data above, it will be consider that the control system of secondary pump would be modified or not. Therefore the analyzed data can show the characteristic curve of the secondary cooling system performance

  12. Calibration transfer in temperature modulated gas sensor arrays

    OpenAIRE

    Fernández Romero, Luis; Güney, Selda; Gutiérrez Gálvez, Agustín; Marco Colás, Santiago

    2016-01-01

    Shifts in working temperature are an important issue that prevents the successful transfer of calibration models from one chemical instrument to another. This effect is of special relevance when working with gas sensor arrays modulated in temperature. In this paper, we study the use of multivariate techniques to transfer the calibration model from a temperature modulated gas sensor array to another when a global change of temperature occurs. To do so, we built 12 identical master sensor array...

  13. Property transfer assessments should include radon gas testing

    International Nuclear Information System (INIS)

    Nardi, M.A.

    1992-01-01

    There are two emerging influences that will require radon gas testing as part of many property transfers and most environmental assessments. These requirements come from lending regulators and state legislatures and affect single family, multifamily, and commercial properties. Fannie Mae and others have developed environmental investigation guidelines for protection from long term legal liabilities in the purchase of environmentally contaminated real estate. These guidelines include radon gas testing for many properties. Several states have enacted laws that require environmental disclosure forms be prepared to ensure that the parties involved in certain real estate transactions are aware of the environmental liabilities that may come with the transfer of property. Indiana has recently enacted legislation that would require the disclosure of the presence of radon gas on many commercial real estate transactions. With more banks and state governments following this trend, radon gas testing should be performed during all property transfers and environmental assessments to protect the parties involved from any long term legal liabilities

  14. Modeling of Aerobrake Ballute Stagnation Point Temperature and Heat Transfer to Inflation Gas

    Science.gov (United States)

    Bahrami, Parviz A.

    2012-01-01

    A trailing Ballute drag device concept for spacecraft aerocapture is considered. A thermal model for calculation of the Ballute membrane temperature and the inflation gas temperature is developed. An algorithm capturing the most salient features of the concept is implemented. In conjunction with the thermal model, trajectory calculations for two candidate missions, Titan Explorer and Neptune Orbiter missions, are used to estimate the stagnation point temperature and the inflation gas temperature. Radiation from both sides of the membrane at the stagnation point and conduction to the inflating gas is included. The results showed that the radiation from the membrane and to a much lesser extent conduction to the inflating gas, are likely to be the controlling heat transfer mechanisms and that the increase in gas temperature due to aerodynamic heating is of secondary importance.

  15. Effect of flue gas recirculation on heat transfer in a supercritical circulating fluidized bed combustor

    Directory of Open Access Journals (Sweden)

    Błaszczuk Artur

    2015-09-01

    Full Text Available This paper focuses on assessment of the effect of flue gas recirculation (FGR on heat transfer behavior in 1296t/h supercritical coal-fired circulating fluidized bed (CFB combustor. The performance test in supercritical CFB combustor with capacity 966 MWth was performed with the low level of flue gas recirculation rate 6.9% into furnace chamber, for 80% unit load at the bed pressure of 7.7 kPa and the ratio of secondary air to the primary air SA/PA = 0.33. Heat transfer behavior in a supercritical CFB furnace between the active heat transfer surfaces (membrane wall and superheater and bed material has been analyzed for Geldart B particle with Sauter mean diameters of 0.219 and 0.246 mm. Bed material used in the heat transfer experiments had particle density of 2700 kg/m3. A mechanistic heat transfer model based on cluster renewal approach was used in this work. A heat transfer analysis of CFB combustion system with detailed consideration of bed-to-wall heat transfer coefficient distributions along furnace height is investigated. Heat transfer data for FGR test were compared with the data obtained for representative conditions without recycled flue gases back to the furnace through star-up burners.

  16. Transient heat transfer for forced convection flow of helium gas

    International Nuclear Information System (INIS)

    Liu, Qiusheng; Fukuda, Katsuya; Sasaki, Kenji; Yamamoto, Manabu

    1999-01-01

    Transient heat transfer coefficients for forced convection flow of helium gas over a horizontal cylinder were measured using a forced convection test loop. The platinum heater with a diameter of 1.0 mm was heated by electric current with an exponential increase of Q 0 exp(t/τ). It was clarified that the heat transfer coefficient approaches the steady-state one for the period τ over 1 s, and it becomes higher for the period of τ shorter than 1 s. The transient heat transfer shows less dependent on the gas flowing velocity when the period becomes very shorter. Semi-empirical correlations for steady-state and transient heat transfer were developed based on the experimental data. (author)

  17. Control Decisions for Flammable Gas Hazards in Waste Transfer Systems

    International Nuclear Information System (INIS)

    KRIPPS, L.J.

    2000-01-01

    This report describes the control decisions for flammable gas hazards in waste transfer systems (i.e., waste transfer piping and waste transfer-associated structures) made at control decision meetings on November 30, 1999a and April 19, 2000, and their basis. These control decisions, and the analyses that support them, will be documented in an amendment to the Final Safety Analysis Report (FSAR) (CHG 2000a) and Technical Safety Requirements (TSR) (CHG 2000b) to close the Flammable Gas Unreviewed Safety Question (USQ) (Bacon 1996 and Wagoner 1996). Following the Contractor Tier I review of the FSAR and TSR amendment, it will be submitted to the US. Department of Energy (DOE), Office of River Protection (ORP) for review and approval. The control decision meeting on November 30, 1999 to address flammable gas hazards in waste transfer systems followed the control decision process and the criteria for control decisions described in Section 3.3.1.5 of the FSAR. The control decision meeting agenda, attendance list, and introductory and background presentations are included in Attachments 1 through 4. The control decision discussions on existing and other possible controls for flammable gas hazards in waste transfer systems and the basis for selecting or not selecting specific controls are summarized in this report

  18. Heat transfer across the interface between nanoscale solids and gas.

    Science.gov (United States)

    Cheng, Chun; Fan, Wen; Cao, Jinbo; Ryu, Sang-Gil; Ji, Jie; Grigoropoulos, Costas P; Wu, Junqiao

    2011-12-27

    When solid materials and devices scale down in size, heat transfer from the active region to the gas environment becomes increasingly significant. We show that the heat transfer coefficient across the solid-gas interface behaves very differently when the size of the solid is reduced to the nanoscale, such as that of a single nanowire. Unlike for macroscopic solids, the coefficient is strongly pressure dependent above ∼10 Torr, and at lower pressures it is much higher than predictions of the kinetic gas theory. The heat transfer coefficient was measured between a single, free-standing VO(2) nanowire and surrounding air using laser thermography, where the temperature distribution along the VO(2) nanowire was determined by imaging its domain structure of metal-insulator phase transition. The one-dimensional domain structure along the nanowire results from the balance between heat generation by the focused laser and heat dissipation to the substrate as well as to the surrounding gas, and thus serves as a nanoscale power-meter and thermometer. We quantified the heat loss rate across the nanowire-air interface, and found that it dominates over all other heat dissipation channels for small-diameter nanowires near ambient pressure. As the heat transfer across the solid-gas interface is nearly independent of the chemical identity of the solid, the results reveal a general scaling relationship for gaseous heat dissipation from nanostructures of all solid materials, which is applicable to nanoscale electronic and thermal devices exposed to gaseous environments.

  19. Transient forced convection heat transfer in helium gas

    International Nuclear Information System (INIS)

    Liu, Qiusheng; Fukuda, Katsuya

    2002-01-01

    The knowledge of transient forced convection heat transfer at various periods of exponential increase of heat input to a heater is important as a database for understanding the transient heat transfer process in a high temperature gas cooled reactor (HTGR) due to an accident in excess reactivity. The transient heat transfer coefficients for forced convection flow of helium gas over a horizontal cylinder were measured using a forced convection test loop. The platinum heater with a diameter of 1.0 mm was heated by electric current with an exponential increase of Q 0 exp(t/τ). It was clarified that the heat transfer coefficient approaches the quasi-steady-state one for the period τ over 1 s, and it becomes higher for the period of τ shorter than 1 s. The transient heat transfer shows less dependent on the gas flowing velocity when the period becomes very shorter. Semi-empirical correlations for quasi-steady-state and transient heat transfer were developed based on the experimental data. (author)

  20. Transient heat transfer for forced convection flow of helium gas

    International Nuclear Information System (INIS)

    Liu, Qiusheng; Fukuda, Katsuya

    2002-01-01

    The knowledge of forced convection transient heat transfer at various periods of exponential increase of heat input to a heater is important as a database for understanding the transient heat transfer process in a high temperature gas cooled reactor (HTGR) due to an accident in excess reactivity. The transient heat transfer coefficients for forced convection flow of helium gas over a horizontal cylinder were measured using a forced convection test loop. The platinum heater with a diameter of 1.0 mm was heated by electric current with an exponential increase of Q 0 exp(t/τ). It was clarified that the heat transfer coefficient approaches the quasi-steady-state one for the period τ over 1 s, and it becomes higher for the period of τ shorter than 1 s. The transient heat transfer shows less dependent on the gas flowing velocity when the period becomes very shorter. Semi-empirical correlations for quasi-steady-state and transient heat transfer were developed based on the experimental data. (author)

  1. Electron transfer in gas surface collisions

    International Nuclear Information System (INIS)

    Wunnik, J.N.M. van.

    1983-01-01

    In this thesis electron transfer between atoms and metal surfaces in general is discussed and the negative ionization of hydrogen by scattering protons at a cesiated crystalline tungsten (110) surface in particular. Experimental results and a novel theoretical analysis are presented. In Chapter I a theoretical overview of resonant electron transitions between atoms and metals is given. In the first part of chapter II atom-metal electron transitions at a fixed atom-metal distance are described on the basis of a model developed by Gadzuk. In the second part the influence of the motion of the atom on the atomic charge state is incorporated. Measurements presented in chapter III show a strong dependence of the fraction of negatively charged H atoms scattered at cesiated tungsten, on the normal as well as the parallel velocity component. In chapter IV the proposed mechanism for the parallel velocity effect is incorporated in the amplitude method. The scattering process of protons incident under grazing angles on a cesium covered surface is studied in chapter V. (Auth.)

  2. Gas-liquid mass transfer coefficient in stirred tank reactors

    NARCIS (Netherlands)

    Yawalkar, Archis A.; Heesink, Albertus B.M.; Versteeg, Geert; Pangarkar, Vishwas G.

    2003-01-01

    Volumetric gas—liquid mass transfer coefficient (kLa) data available in the literature for larger tanks (T = 0.39 m to 2.7 m) have been analyzed on the basis of relative dispersion parameter, N/Ncd. It was observed that at a given superficial gas velocity (VG), kLa values were approximately the same

  3. Gas Requirements in Pressurized Transfer of Liquid Hydrogen

    Science.gov (United States)

    Gluck, D. F.; Kline, J. F.

    1961-01-01

    Of late, liquid hydrogen has become a very popular fuel for space missions. It is being used in such programs as Centaur and Saturn. Furthermore, hydrogen is the ideal working fluid for nuclear powered space vehicles currently under development. In these applications, liquid hydrogen fuel is generally transferred to the combustion chamber by a combination of pumping and pressurization. The pump forces the liquid propellant from the fuel tank to the combustion chamber; gaseous pressurant holds tank pressure sufficiently high to prevent cavitation at the pump inlet and to maintain the structural rigidity of the tank. The pressurizing system, composed of pressurant, tankage, and associated hardware can be a large portion of the total vehicle weight. Pressurant weight can be reduced by introducing the pressurizing gas at temperatures substantially greater than those of liquid hydrogen. Heat and mass transfer processes thereby induced complicate gas requirements during discharge. These requirements must be known to insure proper design of the pressurizing system. The aim of this paper is to develop from basic mass and energy transfer processes a general method to predict helium and hydrogen gas usage for the pressurized transfer of liquid hydrogen. This required an analytical and experimental investigation, the results of which are described in this paper.

  4. Gas Transfer Velocity in the Presence of Wave Breaking

    Science.gov (United States)

    Li, S.

    2016-02-01

    Wave breaking is known to intensify the gas exchange across the air-sea interface through air entrainment and enhancement of the near-surface turbulence. We proposed a composite model for the gas transfer velocity by examining the near-surface turbulence induced by wave breaking, which was determined based on the combination of the vertical distribution of the turbulence in the wave-affected layer and the breaking wave energy dissipation rate in the wave-breaking layer. The gas transfer velocity was calculated as a function of the air frictional velocity, wave age, and whitecap coverage. The model was validated for both the wind and wave-age dependence against field and laboratory measurements. The results supported the hypothesis that the large uncertainties in the traditional wind speed-based gas transfer velocities at moderate to high wind speeds can be ascribed to the neglect of the wind-wave effect, which is mainly attributed to the whitecap coverage as a function of the wind-wave Reynolds number.

  5. Heat transfer between immiscible liquids enhanced by gas bubbling

    International Nuclear Information System (INIS)

    Greene, G.A.; Schwarz, C.E.; Klages, J.; Klein, J.

    1982-08-01

    The phenomena of core-concrete interactions impact upon containment integrity of light water reactors (LWR) following postulated complete meltdown of the core by containment pressurization, production of combustible gases, and basemat penetration. Experiments have been performed with non-reactor materials to investigate one aspect of this problem, heat transfer between overlying immiscible liquids whose interface is disturbed by a transverse non-condensable gas flux emanating from below. Hydrodynamic studies have been performed to test a criterion for onset of entrainment due to bubbling through the interface and subsequent heat transfer studies were performed to assess the effect of bubbling on interfacial heat transfer rates, both with and without bubble induced entrainment. Non-entraining interfacial heat transfer data with mercury-water/oil fluid pairs were observed to be bounded from below within a factor of two to three by the Szekeley surface renewal heat transfer model. However heat transfer data for fluid pairs which are found to entrain (water-oil), believed to be characteristic of molten reactor core-concrete conditions, were measured to be up to two orders of magnitude greater than surface renewal predictions and are calculated by a simple entrainment heat transfer model

  6. Heat transfer characteristics around a single heated rod immersed in sodium pool with gas jet injection

    International Nuclear Information System (INIS)

    Hideto Niikura; Kazuo Soga; Ken-ichiro Sugiyama; Akira Yamaguchi

    2005-01-01

    In a steam generator using liquid sodium, water intensely reacts with sodium when it leaks out from a heat transfer tube. It is important to evaluate the influence of sodium-water reaction to surrounding tubes and the shell. Hence, it has been desired to develop the simulation code for the evaluation of sodium-water reaction. From this viewpoint, the Japan Nuclear Cycle is now developing the SERAPHIM code. We reported a preliminary study to establish an experimental method for a single heated rod immersed in sodium pool with steam jet impingement planned in the near future as well as to obtain a preliminary data to verify the adequacy of SERAPHIM code. We first measured local and mean heat transfer coefficients around a horizontal single heated rod immersed in a water pool and a sodium pool with a limited volume in the experimental apparatus. It was confirmed that the mean heat transfer coefficients fairly agreed with the existing data for natural convection in water and sodium. Secondary we measured local and mean heat transfer coefficients around a horizontal single heated rod with Ar gas jet impingement immersed in the limited water pool and in the limited sodium pool. It was clearly observed that the local heat transfer coefficients in the sodium pool keep almost the same values in every angle regardless of increase in Ar gas jet velocity varied from about 8.7m/s to about 78m/s. On the other hand, it was confirmed in the water pool that local heat transfer coefficients on the forward stagnation side exposed in the Ar gas jet impingement increase with increasing the jet velocity while the local heat transfer coefficients on the opposite surface keep almost same values regardless of increase in the velocity. (authors)

  7. Charge Transfer Properties Through Graphene Layers in Gas Detectors

    CERN Document Server

    Thuiner, P.; Jackman, R.B.; Müller, H.; Nguyen, T.T.; Oliveri, E.; Pfeiffer, D.; Resnati, F.; Ropelewski, L.; Smith, J.A.; van Stenis, M.; Veenhof, R.

    2016-01-01

    Graphene is a single layer of carbon atoms arranged in a honeycomb lattice with remarkable mechanical, electrical and optical properties. For the first time graphene layers suspended on copper meshes were installed into a gas detector equipped with a gaseous electron multiplier. Measurements of low energy electron and ion transfer through graphene were conducted. In this paper we describe the sample preparation for suspended graphene layers, the testing procedures and we discuss the preliminary results followed by a prospect of further applications.

  8. Fluid dynamics and mass transfer in a gas centrifuge

    International Nuclear Information System (INIS)

    Conlisk, A.T.; Foster, M.R.; Walker, J.D.A.

    1982-01-01

    The fluid motion, temperature distribution and the mass-transfer problem of a binary gas mixture in a rapidly rotating centrifuge are investigated. Solutions for the velocity, temperature and mass-fraction fields within the centrifuge are obtained for mechanically or thermally driven centrifuges. For the mass-transfer problem, a detailed analysis of the fluid-mechanical boundary layers is required, and, in particular, mass fluxes within the boundary layers are obtained for a wide range of source-sink geometries. Solutions to the mass-transfer problem are obtained for moderately and strongly forced flows in the container; the dependence of the separation (or enrichment) factor on centrifuge configuration, rotational speed and fraction of the volumetric flow rate extracted at the product port (the cut) are predicted. (author)

  9. Could Secondary DNA Transfer Falsely Place Someone at the Scene of a Crime?

    Science.gov (United States)

    Cale, Cynthia M; Earll, Madison E; Latham, Krista E; Bush, Gay L

    2016-01-01

    The occurrence of secondary DNA transfer has been previously established. However, the transfer of DNA through an intermediary has not been revisited with more sensitive current technologies implemented to increase the likelihood of obtaining results from low-template/low-quality samples. This study evaluated whether this increased sensitivity could lead to the detection of interpretable secondary DNA transfer profiles. After two minutes of hand to hand contact, participants immediately handled assigned knives. Swabbings of the knives with detectable amounts of DNA were amplified with the Identifiler(®) Plus Amplification Kit and injected on a 3130xl. DNA typing results indicated that secondary DNA transfer was detected in 85% of the samples. In five samples, the secondary contributor was either the only contributor or the major contributor identified despite never coming into direct contact with the knife. This study demonstrates the risk of assuming that DNA recovered from an object resulted from direct contact. © 2015 American Academy of Forensic Sciences.

  10. Exhaust gas heat recovery through secondary expansion cylinder and water injection in an internal combustion engine

    Directory of Open Access Journals (Sweden)

    Nassiri Toosi Ali

    2017-01-01

    Full Text Available To enhance thermal efficiency and increase performance of an internal combustion engine, a novel concept of coupling a conventional engine with a secondary 4-stroke cylinder and direct water injection process is proposed. The burned gases after working in a traditional 4-stroke combustion cylinder are transferred to a secondary cylinder and expanded even more. After re-compression of the exhaust gases, pre-heated water is injected at top dead center. The evaporation of injected water not only recovers heat from exhaust gases, but also increases the mass of working gas inside the cylinder, therefore improves the overall thermal efficiency. A 0-D/1-D model is used to numerically simulate the idea. The simulations outputs showed that the bottoming cycle will be more efficient at higher engines speeds, specifically in a supercharged/turbocharged engine, which have higher exhaust gas pressure that can reproduce more positive work. In the modeled supercharged engine, results showed that brake thermal efficiency can be improved by about 17%, and brake power by about 17.4%.

  11. Charge-transfer properties in the gas electron multiplier

    International Nuclear Information System (INIS)

    Han, Sanghyo; Kim, Yongkyun; Cho, Hyosung

    2004-01-01

    The charge transfer properties of a gas electron multiplier (GEM) were systematically investigated over a broad range of electric field configurations. The electron collection efficiency and the charge sharing were found to depend on the external fields, as well as on the GEM voltage. The electron collection efficiency increased with the collection field up to 90%, but was essentially independent of the drift field strength. A double conical GEM has a 10% gain increase with time due to surface charging by avalanche ions whereas this effect was eliminated with the cylindrical GEM. The positive-ion feedback is also estimated. (author)

  12. An inverse gas chromatographic methodology for studying gas-liquid mass transfer.

    Science.gov (United States)

    Paloglou, A; Martakidis, K; Gavril, D

    2017-01-13

    A novel methodology of reversed flow inverse gas chromatography (RF-IGC) is presented. It permits the simultaneous determination of mass transfer coefficients across the gas liquid interface as well as the respective solubility parameters and thermodynamic functions of dissolution of gases into liquids. The standard deviation of the experimentally determined parameters is estimated for first time, which combined with the successful comparison of the values of the present parameters with other literature ones ascertain the reliability of the methodology. Another novelty of the present work is that the chromatographic sampling of the physicochemical phenomena is done without performing the usual flow reversals procedure. Vinyl chloride monomer's (VCM) interaction with various composition liquid foods: orange juice, milk and olive oil was used as model system. The present transfer rates are controlled by the gas film at lower temperatures, but at higher temperatures the resistances in both films tend to become equal. The found liquid diffusivity values express the total mass transfer from the gas phase into the liquid's bulk and they decrease with rising temperature, as the solubilities of gases in liquids do. Solubility, expressed by Henry's law constant and the mean values of interfacial thickness are of the same order of magnitude to literature ones. From the thermodynamic point of view, VCM dissolution in all liquids is accompanied by significant heat release and it is a slightly non-spontaneous process, near equilibrium, while the entropy change values are negative. Copyright © 2016 Elsevier B.V. All rights reserved.

  13. Leadership for Effective Teacher Training Transfer in Kuwaiti Secondary Schools

    Science.gov (United States)

    Winokur, Ilene K.; Sperandio, Jill

    2017-01-01

    This article reports on the findings of a study undertaken to examine the links between leadership practices of a transformational nature and the transfer of teacher training in the public high schools in Kuwait. The participants in the study were teachers who had undergone mandated professional development (PD) aimed at improving teaching…

  14. Horizontal transfer of bait in the German cockroach: indoxacarb causes secondary and tertiary mortality.

    Science.gov (United States)

    Buczkowski, Grzegorz; Scherer, Clay W; Bennett, Gary W

    2008-06-01

    Horizontal transfer of indoxacarb in the German cockroach, Blattella germanica (L.), was examined under laboratory conditions. Results show that a single bait-fed adult cockroach (i.e., the donor) transferred indoxacarb to numerous primary recipients (secondary mortality),which then became secondary donors. These recipients subsequently became donors to other cockroaches and caused significant mortality in other members of the aggregation, resulting in tertiary kill. Indoxacarb was effectively transferred among adult cockroaches and resulted in significant secondary mortality. When adult males served as donors and vectored the insecticide to adult males, the donor:recipient ratio affected the mortality of the recipients and the rate of secondary mortality increased with increasing the ratio of donors to recipients. Furthermore, secondary mortality in the untreated cockroaches was significantly affected by the freshness of excretions from the donors, the presence of alternative food, and the duration of contact between the donors and the recipients. Ingested indoxacarb was most effectively translocated when the recipients interacted with freshly symptomatic donors in the absence of alternative food. The transfer of indoxacarb continued beyond secondary mortality and resulted in significant tertiary mortality. Excretions from a single bait-fed adult killed 38/50 (76%) nymphs within 72 h. The dead nymphs then vectored indoxacarb to 20 adult males and killed 16/20 (81%) recipients within 72 h. Behavioral mechanisms involved in the horizontal transfer of indoxacarb may include: contact with excretions, necrophagy, emetophagy, and ingestion of other excretions that originate from the donors.

  15. Air-sea gas transfer for gases of varying solubility

    Science.gov (United States)

    Rutgersson, Anna; Sahlee, Erik; Andersson, Andreas; Podgrajsek, Eva

    2014-05-01

    CombiCombination of surface water cooling and a deep ocean mixed layer generates convective eddies scaling with the depth of a mixed layer that enhances the efficiency of the air-sea gas transfer. This enhancement is explained by the convective eddies disturbing the molecular diffusion layer and inducing increased turbulent mixing in the water (Rutgersson et al 2011). The enhancement can be introduced into existing formulations for calculating the air-sea exchange of gases by using an additional resistance, due to large-scale convection acting in parallel with other processes. The additional resistance is expressed by the convective velocity scale of the water and the friction velocity and characterizes the relative role of surface shear and buoyancy forces. We use direct flux measurements by the Eddy-Covariance method (EC), we use gases of varying solubility (carbon dioxide, methane and water vapor). New methodology allows also to introduce EC measurements of oxygen (Andersson et al., 2014). Water-side convection is of particular interest for the low to moderate wind-speed regime, when spray and bubbles have less dominance of the efficiency of the transfer. It is also possible that gases of different solubility shows a different response to various forcing mechanisms. Lake data of methane fluxes exhibits a stronger diurnal cycle than CO2 as a response to the strong diurnal cycle of water-side convection (Podgrajsek et al., 2014). Calculated fluxes from the Baltic Sea basin shows an altered diurnal cycle when introducing the convection. The potential need of taking processes into account generating turbulence of a larger scale, such as water-side convection or Langmuir circulation introduced larger requirements on the remote sensing products used for air-sea gas flux climatologies. Andersson, A. Rutgersson A. and Sahlee, E. Using a high frequency fluorescent oxygen probe in atmospheric eddy covariance applications. Submitted 2014. Podgrajsek, E., E. Sahlée and A

  16. Heat transfer problems in gas-cooled solid blankets

    International Nuclear Information System (INIS)

    Fillo, J.A.; Powell, J.R.

    1976-01-01

    In all fusion reactors using the deuterium-tritium fuel cycle, a large fraction approximately 80 percent of the fusion energy will be released as approximately 14 MeV neutrons which must be slowed down in a relatively thick blanket surrounding the plasma, thereby, converting their kinetic energy to high temperature heat which can be continuously removed by a coolant stream and converted in part to electricity in a conventional power turbine. Because of the primary goal of achieving minimum radioactivity, to date Brookhaven blanket concepts have been restricted to the use of some form of solid lithium, with inert gas-cooling and in some design cases, water-cooling of the shell structure. Aluminum and graphite have been identified as very promising structural materials for fusion blankets, and conceptual designs based on these materials have been made. Depending on the thermal loading on the ''first'' wall which surrounds the plasma as well as blanket design, heat transfer problems may be noticeably different in gas-cooled solid blankets. Approaches to solution of heat removal problems as well as explanation of: (a) the after-heat problems in blankets; (b) tritium breeding in solids; and (c) materials selection for radiation shields relative to the minimum activity blanket efforts at Brookhaven are discussed

  17. Primary and secondary organic aerosol origin by combined gas-particle phase source apportionment

    Directory of Open Access Journals (Sweden)

    M. Crippa

    2013-08-01

    Full Text Available Secondary organic aerosol (SOA, a prominent fraction of particulate organic mass (OA, remains poorly constrained. Its formation involves several unknown precursors, formation and evolution pathways and multiple natural and anthropogenic sources. Here a combined gas-particle phase source apportionment is applied to wintertime and summertime data collected in the megacity of Paris in order to investigate SOA origin during both seasons. This was possible by combining the information provided by an aerosol mass spectrometer (AMS and a proton transfer reaction mass spectrometer (PTR-MS. A better constrained apportionment of primary OA (POA sources is also achieved using this methodology, making use of gas-phase tracers. These tracers made possible the discrimination between biogenic and continental/anthropogenic sources of SOA. We found that continental SOA was dominant during both seasons (24–50% of total OA, while contributions from photochemistry-driven SOA (9% of total OA and marine emissions (13% of total OA were also observed during summertime. A semi-volatile nighttime component was also identified (up to 18% of total OA during wintertime. This approach was successfully applied here and implemented in a new source apportionment toolkit.

  18. Experience transfer in Norwegian oil and gas industry: Approaches and organizational mechanisms

    Energy Technology Data Exchange (ETDEWEB)

    Aase, Karina

    1997-12-31

    The main objective of this thesis has been to explore how experience transfer works in Norwegian oil and gas industry. This includes how the concept of experience transfer is defined, what the barriers to achieve experience transfer are, how the oil and gas companies address experience transfer, and how these approaches work. The thesis is organized in five papers: (1) describes how organizational members perceive experience transfer and then specifies the organizational and structural barriers that must be overcome to achieve efficient transfer. (2) discusses the organizational means an oil company implements to address experience transfer. (3) describes a process of improving and using requirement and procedure handbooks for experience transfer. (4) explores how the use of information technology influences experience transfer. (5) compares organizational members` perceptions of experience transfer means in an oil company and an engineering company involved in offshore development projects. 277 refs., 3 figs., 29 tabs.

  19. Charge amplification and transfer processes in the gas electron multiplier

    International Nuclear Information System (INIS)

    Bachmann, S.; Bressan, A.; Ropelewski, L.; Sauli, F.; Sharma, A.; Moermann, D.

    1999-01-01

    We report the results of systematic investigations on the operating properties of detectors based on the gas electron multiplier (GEM). The dependence of gain and charge collection efficiency on the external fields has been studied in a range of values for the hole diameter and pitch. The collection efficiency of ionization electrons into the multiplier, after an initial increase, reaches a plateau extending to higher values of drift field the larger the GEM voltage and its optical transparency. The effective gain, fraction of electrons collected by an electrode following the multiplier, increases almost linearly with the collection field, until entering a steeper parallel plate multiplication regime. The maximum effective gain attainable increases with the reduction in the hole diameter, stabilizing to a constant value at a diameter approximately corresponding to the foil thickness. Charge transfer properties appear to depend only on ratios of fields outside and within the channels, with no interaction between the external fields. With proper design, GEM detectors can be optimized to satisfy a wide range of experimental requirements: tracking of minimum ionizing particles, good electron collection with small distortions in high magnetic fields, improved multi-track resolution and strong ion feedback suppression in large volume and time-projection chambers

  20. Catalytic tar removal from biomass producer gas with secondary air

    Energy Technology Data Exchange (ETDEWEB)

    Lammers, G.; Beenackers, A.A.C.M. [University of Groningen (Netherlands). Dept. of Chemical Engineering; Corella, J. [Universidad Complutense, Madrid (Spain)

    1997-12-31

    The effect of air addition on biomass tar conversion in catalytic packed bed crackers was studied using both an isothermal micro reactor and a fluidised bed bench scale biomass gasification set up with down stream tar crackers. The micro reactor was applied for experiments with artificial biomass producer gas containing naphthalene as a model tar compound. Experiments were carried out with inert silica and catalytically active calcined dolomite bed material both with and without air addition. Experimental results with real tar from the fluidised bed bench scale gasification set up were in qualitative agreement with results from the micro reactor experiments. (author)

  1. Gas transfer through the air-water interface in LES of Langmuir circulation in shallow water

    Science.gov (United States)

    Akan, Cigdem; Tejada-Martínez, Andrés E.

    2008-11-01

    Over the past century the study of gas exchange rates between the atmosphere and the ocean has received increased attention because of concern about the fate of slightly soluble, greenhouse gases such as CO2 released into the atmosphere. Of recent interest is the oceanic uptake of CO2 along US shallow water coastal regions (e.g. see http://www.nacarbon.org). We present surface gas transfer results from large-eddy simulation (LES) of wind-driven shallow water flow with and without wave effects. Wave effects, parameterized by the well-known Craik-Leibovich vortex force, lead to the generation of Langmuir circulation (LC), serving as a mechanism for surface renewal of low concentration fluid. Our computations are motivated by the infrared imagery of Marmorino et al. (2004) suggesting that LC can affect gas transfer across the surface through straining and stretching of the gas concentration boundary layer. Preliminary LES shows that shallow water LC can increase the surface gas transfer rate by about 30 percent. Here we will focus on the accuracy of surface renewal models in predicting gas transfer velocity, a measure of gas transfer efficiency, in the presence of LC. Gas transfer velocity predicted by the surface renewal models will be compared to the prediction obtained directly from the LES.

  2. LOCAL HEAT TRANSFER AT THE END FACES CHANNEL PROFILES OF TURBINE NOZZLES FOR INTENSE SECONDARY FLOWS

    Directory of Open Access Journals (Sweden)

    A. Kashchenko

    2015-07-01

    Full Text Available Results of experimental study of local heat transfer at the end surfaces of channel profiles of turbine nozzles in secondary currents, the intensity of which was varied by reducing the height of the profiles are presented. The thickness of the boundary layer on the inlet in the channel profiles was reduced to the minimum possible in the experiment. The data characterizing the distribution of local heat transfer coefficients on the end surface in a wide range of characteristic parameters change is obtained.

  3. Steady Secondary Flows Generated by Periodic Compression and Expansion of an Ideal Gas in a Pulse Tube

    Science.gov (United States)

    Lee, Jeffrey M.

    1999-01-01

    This study establishes a consistent set of differential equations for use in describing the steady secondary flows generated by periodic compression and expansion of an ideal gas in pulse tubes. Also considered is heat transfer between the gas and the tube wall of finite thickness. A small-amplitude series expansion solution in the inverse Strouhal number is proposed for the two-dimensional axisymmetric mass, momentum and energy equations. The anelastic approach applies when shock and acoustic energies are small compared with the energy needed to compress and expand the gas. An analytic solution to the ordered series is obtained in the strong temperature limit where the zeroth-order temperature is constant. The solution shows steady velocities increase linearly for small Valensi number and can be of order I for large Valensi number. A conversion of steady work flow to heat flow occurs whenever temperature, velocity or phase angle gradients are present. Steady enthalpy flow is reduced by heat transfer and is scaled by the Prandtl times Valensi numbers. Particle velocities from a smoke-wire experiment were compared with predictions for the basic and orifice pulse tube configurations. The theory accurately predicted the observed steady streaming.

  4. Assessing the Risk of Secondary Transfer Via Fingerprint Brush Contamination Using Enhanced Sensitivity DNA Analysis Methods.

    Science.gov (United States)

    Bolivar, Paula-Andrea; Tracey, Martin; McCord, Bruce

    2016-01-01

    Experiments were performed to determine the extent of cross-contamination of DNA resulting from secondary transfer due to fingerprint brushes used on multiple items of evidence. Analysis of both standard and low copy number (LCN) STR was performed. Two different procedures were used to enhance sensitivity, post-PCR cleanup and increased cycle number. Under standard STR typing procedures, some additional alleles were produced that were not present in the controls or blanks; however, there was insufficient data to include the contaminant donor as a contributor. Inclusion of the contaminant donor did occur for one sample using post-PCR cleanup. Detection of the contaminant donor occurred for every replicate of the 31 cycle amplifications; however, using LCN interpretation recommendations for consensus profiles, only one sample would include the contaminant donor. Our results indicate that detection of secondary transfer of DNA can occur through fingerprint brush contamination and is enhanced using LCN-DNA methods. © 2015 American Academy of Forensic Sciences.

  5. Numerical Methodology for Coupled Time-Accurate Simulations of Primary and Secondary Flowpaths in Gas Turbines

    Science.gov (United States)

    Przekwas, A. J.; Athavale, M. M.; Hendricks, R. C.; Steinetz, B. M.

    2006-01-01

    Detailed information of the flow-fields in the secondary flowpaths and their interaction with the primary flows in gas turbine engines is necessary for successful designs with optimized secondary flow streams. Present work is focused on the development of a simulation methodology for coupled time-accurate solutions of the two flowpaths. The secondary flowstream is treated using SCISEAL, an unstructured adaptive Cartesian grid code developed for secondary flows and seals, while the mainpath flow is solved using TURBO, a density based code with capability of resolving rotor-stator interaction in multi-stage machines. An interface is being tested that links the two codes at the rim seal to allow data exchange between the two codes for parallel, coupled execution. A description of the coupling methodology and the current status of the interface development is presented. Representative steady-state solutions of the secondary flow in the UTRC HP Rig disc cavity are also presented.

  6. The Fusarium graminearum genome reveals more secondary metabolite gene clusters and hints of horizontal gene transfer.

    Directory of Open Access Journals (Sweden)

    Christian M K Sieber

    Full Text Available Fungal secondary metabolite biosynthesis genes are of major interest due to the pharmacological properties of their products (like mycotoxins and antibiotics. The genome of the plant pathogenic fungus Fusarium graminearum codes for a large number of candidate enzymes involved in secondary metabolite biosynthesis. However, the chemical nature of most enzymatic products of proteins encoded by putative secondary metabolism biosynthetic genes is largely unknown. Based on our analysis we present 67 gene clusters with significant enrichment of predicted secondary metabolism related enzymatic functions. 20 gene clusters with unknown metabolites exhibit strong gene expression correlation in planta and presumably play a role in virulence. Furthermore, the identification of conserved and over-represented putative transcription factor binding sites serves as additional evidence for cluster co-regulation. Orthologous cluster search provided insight into the evolution of secondary metabolism clusters. Some clusters are characteristic for the Fusarium phylum while others show evidence of horizontal gene transfer as orthologs can be found in representatives of the Botrytis or Cochliobolus lineage. The presented candidate clusters provide valuable targets for experimental examination.

  7. Mass transfer accompanied with complete reversible chemical reactions in gas-liquid systems: an overview

    NARCIS (Netherlands)

    van Swaaij, Willibrordus Petrus Maria; Versteeg, Geert

    1992-01-01

    In many processes in the chemical industry mass transfer accompanied with reversible, complex chemical reactions in gas-liquid systems are frequently encountered. In point of view of design purposes it is very important that the absorption rates of the transferred reactants can estimated

  8. Economics of secondary energy from GTL regarding natural gas reserves of Bolivia

    Energy Technology Data Exchange (ETDEWEB)

    Udaeta, Miguel Edgar Morales; Burani, Geraldo Francisco; Arzabe Maure, Jose Omar; Oliva, Cidar Ramon [Instituto de Eletrotecnica e Energia da Universidade de Sao Paulo, Sao Paulo-SP (Brazil)

    2007-08-15

    This work aims the economics and the viability of Natural Gas Industrialization in Bolivia, by producing secondary fuels like gas to liquid (GTL)-diesel from natural gas (cleaner than the oil by-product), looking for a clean development with that environmentally well energy using this GTL process. Bolivia has resources that could fulfill these secondary energy resources from GTL. It is possible to process 30 MCMpd of gas obtaining profits from the gas and also from the liquid hydrocarbons that are found in it. Then the Bolivian GTL would present the following advantages: it would export diesel and/or gasoline and would not have to import it anymore.; the exportations of GTL-FT would reach 35 Mbpy, acquiring competitive prices; it would increase productive jobs not only due to the GTL itself, but also from secondary economy linked to GTL market; the use of GTL-FT diesel would bring a ''cleaner'' environment especially in the urban areas; finally, from the macroeconomic perspective, the investment in the plant construction and supporting works would generate a great amount of job offers. (author)

  9. Economics of secondary energy from GTL regarding natural gas reserves of Bolivia

    International Nuclear Information System (INIS)

    Udaeta, Miguel Edgar Morales; Burani, Geraldo Francisco; Arzabe Maure, Jose Omar; Oliva, Cidar Ramon

    2007-01-01

    This work aims the economics and the viability of Natural Gas Industrialization in Bolivia, by producing secondary fuels like gas to liquid (GTL)-diesel from natural gas (cleaner than the oil by-product), looking for a clean development with that environmentally well energy using this GTL process. Bolivia has resources that could fulfill these secondary energy resources from GTL. It is possible to process 30 MCMpd of gas obtaining profits from the gas and also from the liquid hydrocarbons that are found in it. Then the Bolivian GTL would present the following advantages: it would export diesel and/or gasoline and would not have to import it anymore.; the exportations of GTL-FT would reach 35 Mbpy, acquiring competitive prices; it would increase productive jobs not only due to the GTL itself, but also from secondary economy linked to GTL market; the use of GTL-FT diesel would bring a 'cleaner' environment especially in the urban areas; finally, from the macroeconomic perspective, the investment in the plant construction and supporting works would generate a great amount of job offers

  10. Quantifying the loss of methane through secondary gas mass transport (or 'slip') from a micro-porous membrane contactor applied to biogas upgrading.

    Science.gov (United States)

    McLeod, Andrew; Jefferson, Bruce; McAdam, Ewan J

    2013-07-01

    Secondary gas transport during the separation of a binary gas with a micro-porous hollow fibre membrane contactor (HMFC) has been studied for biogas upgrading. In this application, the loss or 'slip' of the secondary gas (methane) during separation is a known concern, specifically since methane possesses the intrinsic calorific value. Deionised (DI) water was initially used as the physical solvent. Under these conditions, carbon dioxide (CO2) and methane (CH4) absorption were dependent upon liquid velocity (V(L)). Whilst the highest CO2 flux was recorded at high V(L), selectivity towards CO2 declined due to low residence times and a diminished gas-side partial pressure, and resulted in slip of approximately 5.2% of the inlet methane. Sodium hydroxide was subsequently used as a comparative chemical absorption solvent. Under these conditions, CO2 mass transfer increased by increasing gas velocity (VG) which is attributed to the excess of reactive hydroxide ions present in the solvent, and the fast conversion of dissolved CO2 to carbonate species reinitiating the concentration gradient at the gas-liquid interface. At high gas velocities, CH4 slip was reduced to 0.1% under chemical conditions. Methane slip is therefore dependent upon whether the process is gas phase or liquid phase controlled, since methane mass transport can be adequately described by Henry's law within both physical and chemical solvents. The addition of an electrolyte was found to further retard CH4 absorption via the salting out effect. However, their applicability to physical solvents is limited since electrolytic concentration similarly impinges upon the solvents' capacity for CO2. This study illustrates the significance of secondary gas mass transport, and furthermore demonstrates that gas-phase controlled systems are recommended where greater selectivity is required. Copyright © 2013 Elsevier Ltd. All rights reserved.

  11. Gas-liquid transfer of aroma compounds during winemaking fermentations

    OpenAIRE

    Mouret, J. R.; Morakul, S.; Nicolle, P.; Athes, V.; Sablayrolles, J. M.

    2012-01-01

    We precisely monitored the production kinetics of 16 volatile carbon compounds corresponding to the predominant higher alcohols and esters produced during the alcoholic fermentation of wine using an online GC system. We studied the gas-liquid partitioning of isobutanol, isoamyl acetate and ethyl hexanoate and showed that CO2 stripping had no impact on the partition coefficient (k(i)). We formulated a predictive model for k(i) changes during the fermentation and calculated the gas-liquid balan...

  12. Thermal Battery Operating Gas Atmosphere Control and Heat Transfer Optimization

    Science.gov (United States)

    2012-09-01

    previously (2, 5), using an Agilent 34970A Data Acquisition/Switch Unit (typically 10 readings/s), MKS Baratron dual capacitance manometer pressure ...confirmed experimentally to an accuracy of better than ±0.1% using a dual capacitance manometer to measure the gas pressure while the tube furnace heated...gas pressures in absolute atmospheres. Three of the four curves that include data above 60 °C are quasi- steady-state data from two operating LCCM

  13. Mass transfer processes across the Capillary Fringe: Quantification of gas-water interface and bubble mediated mass transfer

    Science.gov (United States)

    Geistlinger, Helmut; Mohammadian, Sadjad; Schlüter, Steffen; Karimzadeh, Lotfollah; Vogel, Hans-Jörg

    2013-04-01

    The Capillary Fringe (CF) is a highly dynamic zone at the interface between the water-saturated aquifer and the vadose zone, where steep biogeochemical gradients and thus high bioactivities are expected. Mass transfer processes between the unsaturated zone and the atmosphere, like Greenhouse gas emissions and evaporation, are controlled by the highly temporal and spatial variable gas-water interface across the capillary fringe. Due to water table fluctuations, gas phase may be entrapped or released at/from the CF, which extremely affects the hydraulic properties of the porous medium as well as the mass transfer processes in the partially saturated zone. Most of these processes (gas entrapment and bubble mediated mass transfer (BMT)) are governed by the interactions between the interfaces of gas, water and soil phases. Quantification of these parameters requires a pore-scale approach, which can determine the phase volumes and interfaces with high accuracy. For the understanding and prediction of the involved processes, experiments and modeling at the pore scale are the necessary prerequisites for upscaled, effective modeling approaches. To achieve this aim, we conducted a set of column experiments using X-Ray Computed Tomography (CT). Using this technique, we are able to quantitatively analyze the desired variables in 3D inside the actual bulk volume of the porous media. Water table (WT) elevation was raised at different velocities in the column filled with 1mm-glass beads. After each rise, the column was scanned with CT. We used an intelligent multi-phase segmentation method, considering grey value frequency and voxel neighboring, to separate gas, water, and solid phases in the CT images. The saturation of the gas phase, distribution of the trapped gas bubbles and clusters, and their size, shape, and area are quantified and analyzed at pore-scale. We developed a new segmentation algorithm to distinguish the gas/water interface from the gas/solid interface. Only the

  14. Surface shear stress dependence of gas transfer velocity parameterizations using DNS

    Science.gov (United States)

    Fredriksson, S. T.; Arneborg, L.; Nilsson, H.; Handler, R. A.

    2016-10-01

    Air-water gas-exchange is studied in direct numerical simulations (DNS) of free-surface flows driven by natural convection and weak winds. The wind is modeled as a constant surface-shear-stress and the gas-transfer is modeled via a passive scalar. The simulations are characterized via a Richardson number Ri=Bν/u*4 where B, ν, and u* are the buoyancy flux, kinematic viscosity, and friction velocity respectively. The simulations comprise 0water gas-exchange, (ii) determine, for a given buoyancy flux, the wind speed at which gas transfer becomes primarily shear driven, and (iii) find an expression for the gas-transfer velocity for flows driven by both convection and shear. The evaluated gas transfer-velocity parametrizations are based on either the rate of turbulent kinetic energy dissipation, the surface flow-divergence, the surface heat-flux, or the wind-speed. The parametrizations based on dissipation or divergence show an unfavorable Ri dependence for flows with combined forcing whereas the parametrization based on heat-flux only shows a limited Ri dependence. The two parametrizations based on wind speed give reasonable estimates for the transfer-velocity, depending however on the surface heat-flux. The transition from convection- to shear-dominated gas-transfer-velocity is shown to be at Ri≈0.004. Furthermore, the gas-transfer is shown to be well represented by two different approaches: (i) additive forcing expressed as kg,sum =AShearu*|Ri/Ric+1| 1/4Sc-n where Ric=|AShear/ABuoy|4, and (ii) either buoyancy or shear dominated expressed as, kg=ABuoy|Bν| 1/4Sc-n, Ri>Ric or kg=AShearu*Sc-n, Riwater surface-characteristics.

  15. Gas Turbine/Solar Parabolic Trough Hybrid Design Using Molten Salt Heat Transfer Fluid: Preprint

    Energy Technology Data Exchange (ETDEWEB)

    Turchi, C. S.; Ma, Z.

    2011-08-01

    Parabolic trough power plants can provide reliable power by incorporating either thermal energy storage (TES) or backup heat from fossil fuels. This paper describes a gas turbine / parabolic trough hybrid design that combines a solar contribution greater than 50% with gas heat rates that rival those of natural gas combined-cycle plants. Previous work illustrated benefits of integrating gas turbines with conventional oil heat-transfer-fluid (HTF) troughs running at 390?C. This work extends that analysis to examine the integration of gas turbines with salt-HTF troughs running at 450 degrees C and including TES. Using gas turbine waste heat to supplement the TES system provides greater operating flexibility while enhancing the efficiency of gas utilization. The analysis indicates that the hybrid plant design produces solar-derived electricity and gas-derived electricity at lower cost than either system operating alone.

  16. Microporous hollow fibre membrane modules as gas-liquid contactors. Part 1: Physical mass transfer processes. A specific application: mass transfer in highly viscous liquids

    NARCIS (Netherlands)

    Kreulen, H.; Kreulen, H.; Versteeg, Geert; Smolders, C.A.; Smolders, C.A.; van Swaaij, Willibrordus Petrus Maria

    1993-01-01

    Gas-liquid mass transfer has been studied in a membrane module with non-wetted microporous fibres in the laminar flow regime. This new type of gas/liquid contactor can be operated stabily over a large range of gas and liquid flows because gas and liquid phase do not influence each other directly.

  17. Wireless Power Transfer Technology Applied to an Autonomous Electric UAV with a Small Secondary Coil

    Directory of Open Access Journals (Sweden)

    Tommaso Campi

    2018-02-01

    Full Text Available This study deals with the design and the optimization of a wireless power transfer (WPT charging system based on magnetic resonant coupling applied to an electric vertical take-off and landing Unmanned Aerial Vehicle (UAV. In this study, a procedure for primary and secondary coil design is proposed. The primary circuit in the ground station consists of an array of coils in order to mitigate the negative effects on the coupling factor produced by the possible misalignment between the coils due to an imperfect landing. Key aspects for the design of the secondary coil onboard the UAV are the lightness and compactness of the WPT system components. A demonstrative prototype of the WPT system is applied to a commercial drone. The WPT electrical performances are calculated and measured. Finally, an automatic battery recharge station is built where the drone can autonomously land, recharge the battery and take off to continue its flight mission.

  18. DNA fingerprinting secondary transfer from different skin areas: Morphological and genetic studies.

    Science.gov (United States)

    Zoppis, Silvia; Muciaccia, Barbara; D'Alessio, Alessio; Ziparo, Elio; Vecchiotti, Carla; Filippini, Antonio

    2014-07-01

    The correct identification of the biological samples under analysis is crucial in forensic investigation in that it represents the pivotal issue attesting that the resulting genetic profiles are fully reliable in terms of weight of the evidence. The study reported herein shows that "touch DNA" secondary transfer is indeed possible from person to person and, in turn, from person to object depending on the specific sebaceous or non-sebaceous skin area previously touched. In addition, we demonstrate the presence of fragmented single stranded DNA specifically immunodetected in the vast majority of cells forming the sebaceous gland but not in the epidermis layers, strongly indicating that sebaceous fluid represents an important vector responsible for DNA transfer. In view of our results, forensic investigations need to take into account that the propensity to leave behind genetic material through contact could depend from the individual ability to shed sebaceous fluid on the skin surface. Copyright © 2014 Elsevier Ireland Ltd. All rights reserved.

  19. Heat transfer intensification within tube recuperator by inserting secondary emitters inside air channels

    International Nuclear Information System (INIS)

    Sandor, P.; Soroka, B.; Kudryavtsev, V.; Zgurskyy, V.

    2009-01-01

    The research program was stipulated by reduction the service life of the tube recuperators of reheating furnaces at DUNAFERR metallurgical works in Dunaujvaros (Hungary) while replacement the natural gas by coke - oven gas as a furnace fuel took place and air preheating temperature was increased. The tests procedure consists in comparison of temperature and pressure distributions by air flows preheating under air moving inside the tube loops. Advantages of new recuperator design compared to ordinary one have been proven by validation of concept for adequacy to the testing results. The first tests have demonstrated enhancement of local specific and total heat fluxes transferred from flue gases to air flow within the MD tube loops in comparison with those for BD loops by 25 to 45% - dependence on temperature level within the heating (furnace) chamber and on preheated air flow rate. (author)

  20. Liquid-gas mass transfer at drop structures

    DEFF Research Database (Denmark)

    Matias, Natércia; Nielsen, Asbjørn Haaning; Vollertsen, Jes

    2017-01-01

    established. Then, by applying the two-film theory with two-reference substances, the relation to hydrogen sulfide release was defined. The experiments confirmed that the choice of the type of drop structure is critical to determine the uptake/emission rates. By quantifying the air-water mass transfer rates...... between free-fall and backdrop types of drop, the latter resulted in considerably lower oxygen uptake rates....

  1. Gas Temperature and Radiative Heat Transfer in Oxy-fuel Flames

    DEFF Research Database (Denmark)

    Bäckström, Daniel; Johansson, Robert; Andersson, Klas

    This work presents measurements of the gas temperature, including fluctuations, and its influence on the radiative heat transfer in oxy-fuel flames. The measurements were carried out in the Chalmers 100 kW oxy-fuel test unit. The in-furnace gas temperature was measured by a suction pyrometer...... temperature than the suction pyrometer in the low velocity regions of the furnace, a difference which is likely to be an effect of the purge gas added in the optical probe. The measured temperature fluctuations were evaluated by modeling of the gas radiation. The influence from the measured fluctuations...

  2. Thermal Analysis of the Divertor Primary Heat Transfer System Piping During the Gas Baking Process

    Energy Technology Data Exchange (ETDEWEB)

    Yoder Jr, Graydon L [ORNL; Harvey, Karen [ORNL; Ferrada, Juan J [ORNL

    2011-02-01

    A preliminary analysis has been performed examining the temperature distribution in the Divertor Primary Heat Transfer System (PHTS) piping and the divertor itself during the gas baking process. During gas baking, it is required that the divertor reach a temperature of 350 C. Thermal losses in the piping and from the divertor itself require that the gas supply temperature be maintained above that temperature in order to ensure that all of the divertor components reach the required temperature. The analysis described in this report was conducted in order to estimate the required supply temperature from the gas heater.

  3. Modelling mass transfer during venting/soil vapour extraction: Non-aqueous phase liquid/gas mass transfer coefficient estimation

    Science.gov (United States)

    Esrael, D.; Kacem, M.; Benadda, B.

    2017-07-01

    We investigate how the simulation of the venting/soil vapour extraction (SVE) process is affected by the mass transfer coefficient, using a model comprising five partial differential equations describing gas flow and mass conservation of phases and including an expression accounting for soil saturation conditions. In doing so, we test five previously reported quations for estimating the non-aqueous phase liquid (NAPL)/gas initial mass transfer coefficient and evaluate an expression that uses a reference NAPL saturation. Four venting/SVE experiments utilizing a sand column are performed with dry and non-saturated sand at low and high flow rates, and the obtained experimental results are subsequently simulated, revealing that hydrodynamic dispersion cannot be neglected in the estimation of the mass transfer coefficient, particularly in the case of low velocities. Among the tested models, only the analytical solution of a convection-dispersion equation and the equation proposed herein are suitable for correctly modelling the experimental results, with the developed model representing the best choice for correctly simulating the experimental results and the tailing part of the extracted gas concentration curve.

  4. Choice stepping response and transfer times: effects of age, fall risk, and secondary tasks.

    Science.gov (United States)

    St George, Rebecca J; Fitzpatrick, Richard C; Rogers, Mark W; Lord, Stephen R

    2007-05-01

    Deterioration with age of physiological components of balance control increases fall risk. Avoiding a fall can also require higher level cognitive processing to select correct motor and stepping responses. Here we investigate how a competing cognitive task and an obstacle to stepping affect the initiation and execution phases of choice stepping reaction times in young and older people. Three groups were studied: young persons (YOUNG: 23-40 years, n = 20), older persons with a low risk of falls (OLR: 75-86 years, n = 18), and older persons with a high risk of falls (OHR: 78-88 years, n = 22). Four conditions were examined: choice stepping, choice stepping + obstacle, choice stepping + working memory task, and choice stepping + working memory task + obstacle. Step response and transfer times were measured for each condition, in addition to hesitant stepping, contacts with the obstacle and errors made in the memory test. Older participant groups had significantly longer response and transfer times than the young group had, and the OHR group had significantly longer response and transfer times than the OLR group had. There was a significant Group x Secondary task interaction for response time (F(2,215) = 12.6, p age and fall risk. Compared with young people, older people, and more so those at risk of falling, have an impaired ability to initiate and execute quick, accurate voluntary steps, particularly in situations where attention is divided.

  5. Experience Transfer in Norwegian Oil and Gas Industry: Approaches and Organizational Mechanisms

    International Nuclear Information System (INIS)

    Aase, Karina

    1997-01-01

    The core aim of the study is to explore the concept of experience transfer in oil and gas industry, and how an oil company approaches this concept. The thesis consists of five papers which are combined in a general description entitled 'Experience transfer in Norwegian oil and gas industry: approaches and organizational mechanisms'. The first paper describes how organizational members perceive experience transfer, and then specifies the many organizational and structural barriers that have to be overcome to achieve efficient experience transfer. The second paper elaborates and assesses the organizational means an oil company implements to address experience transfer. The third paper describes a process of improving and using requirement and procedure handbooks for experience transfer. The fourth paper explores in more detail how the use of information technology influences experience transfer. And the fifth paper compares organizational members' perceptions of experience transfer means in an oil company and an engineering company involved in offshore development projects. Some of the papers are based upon the same data material. Therefore there are reiterations in parts of the contents, especially in the methodological sections

  6. Experience Transfer in Norwegian Oil and Gas Industry: Approaches and Organizational Mechanisms

    Energy Technology Data Exchange (ETDEWEB)

    Aase, Karina

    1997-07-01

    The core aim of the study is to explore the concept of experience transfer in oil and gas industry, and how an oil company approaches this concept. The thesis consists of five papers which are combined in a general description entitled 'Experience transfer in Norwegian oil and gas industry: approaches and organizational mechanisms'. The first paper describes how organizational members perceive experience transfer, and then specifies the many organizational and structural barriers that have to be overcome to achieve efficient experience transfer. The second paper elaborates and assesses the organizational means an oil company implements to address experience transfer. The third paper describes a process of improving and using requirement and procedure handbooks for experience transfer. The fourth paper explores in more detail how the use of information technology influences experience transfer. And the fifth paper compares organizational members' perceptions of experience transfer means in an oil company and an engineering company involved in offshore development projects. Some of the papers are based upon the same data material. Therefore there are reiterations in parts of the contents, especially in the methodological sections.

  7. High-precision gas gain and energy transfer measurements in Ar–CO{sub 2} mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Şahin, Özkan, E-mail: osahin@uludag.edu.tr [Department of Physics, Uludağ University, 16059 Bursa (Turkey); Kowalski, Tadeusz Z. [Faculty of Physics and Applied Computer Science, AGH University of Science and Technology, Kraków (Poland); Veenhof, Rob [Department of Physics, Uludağ University, 16059 Bursa (Turkey); RD51 collaboration, CERN, Genève (Switzerland)

    2014-12-21

    Ar–CO{sub 2} is a Penning mixture since a fraction of the energy stored in Ar 3p{sup 5}3d and higher excited states can be transferred to ionize CO{sub 2} molecules. In the present work, concentration and pressure dependence of Penning transfer rate and photon feedback parameter in Ar–CO{sub 2} mixtures have been investigated with recent systematic high-precision gas gain measurements which cover the range 1–50% CO{sub 2} at 400, 800, 1200, 1800 hPa and gas gain from 1 to 5×10{sup 5}.

  8. A mechanistic model of heat transfer for gas-liquid flow in vertical wellbore annuli.

    Science.gov (United States)

    Yin, Bang-Tang; Li, Xiang-Fang; Liu, Gang

    2018-01-01

    The most prominent aspect of multiphase flow is the variation in the physical distribution of the phases in the flow conduit known as the flow pattern. Several different flow patterns can exist under different flow conditions which have significant effects on liquid holdup, pressure gradient and heat transfer. Gas-liquid two-phase flow in an annulus can be found in a variety of practical situations. In high rate oil and gas production, it may be beneficial to flow fluids vertically through the annulus configuration between well tubing and casing. The flow patterns in annuli are different from pipe flow. There are both casing and tubing liquid films in slug flow and annular flow in the annulus. Multiphase heat transfer depends on the hydrodynamic behavior of the flow. There are very limited research results that can be found in the open literature for multiphase heat transfer in wellbore annuli. A mechanistic model of multiphase heat transfer is developed for different flow patterns of upward gas-liquid flow in vertical annuli. The required local flow parameters are predicted by use of the hydraulic model of steady-state multiphase flow in wellbore annuli recently developed by Yin et al. The modified heat-transfer model for single gas or liquid flow is verified by comparison with Manabe's experimental results. For different flow patterns, it is compared with modified unified Zhang et al. model based on representative diameters.

  9. Heat transfer by liquids in suspension in a turbulent gas stream (1960)

    International Nuclear Information System (INIS)

    Grison, E.; Commissariat a l'Energie Atomique, Saclay

    1960-01-01

    The introduction of a small volume of liquid into a turbulent gas stream used as cooling agent improves considerably the heat transfer coefficient of the gas. When the turbulent regime is established, one observes in a cylindrical tube two types of flow whether the liquid wets or does not wet the wall. In the first case, one gets on the wall an annular liquid film and droplets in suspension are in the gas stream. In the second case, a fog of droplets is formed without any liquid film on the wall. Experiments were performed with the following mixtures: water-hydrogen, water-nitrogen, ethanol-nitrogen (wetting liquids) introduced into a stainless steel tube of 4 mm ID, electrically heated on 320 mm of length. We varied the gas flow rate (Reynolds until 50000), the rate of the liquid flow rate to gas flow rate (until 15), the pressure (until 10 kg/cm 2 ), the temperature (until the boiling point) and the heat flux (until 250 W/cm 2 ). Two types of burnout were observed. A formula of correlation of the burnout heat flux is given. Making use of the analogy between mass transfer and heat transfer, a dimensionless formula of correlation of the local heat transfer coefficients is established. (author) [fr

  10. Gas-phase products and secondary organic aerosol formation from the ozonolysis and photooxidation of myrcene

    Science.gov (United States)

    Böge, Olaf; Mutzel, Anke; Iinuma, Yoshiteru; Yli-Pirilä, Pasi; Kahnt, Ariane; Joutsensaari, Jorma; Herrmann, Hartmut

    2013-11-01

    In this study, the ozone and OH-radical reactions of myrcene were investigated in an aerosol chamber (at 292-295 K and 50% relative humidity) to examine the gas-phase oxidation products and secondary organic aerosol (SOA) formation. The ozone reaction studies were performed in the presence and absence of CO, which serves as an OH radical scavenger. In the photooxidation experiments OH radicals were generated by photolysis of methyl nitrite. The ozonolysis of myrcene in the presence of CO resulted in a substantial yield of 4-vinyl-4-pentenal (55.3%), measured as m/z 111 plus m/z 93 using proton transfer reaction-mass spectrometry (PTR-MS) and confirmed unambiguously as C7H10O by denuder measurements and HPLC/ESI-TOFMS analysis of its 2,4-dinitrophenylhydrazine (DNPH) derivative. Additionally, the formation of two different organic dicarbonyls with m/z 113 and a molecular formula of C6H8O2 were observed (2.1%). The yields of these dicarbonyls were higher in the ozonolysis experiments without an OH scavenger (5.4%) and even higher (13.8%) in the myrcene OH radical reaction. The formation of hydroxyacetone as a direct product of the myrcene reaction with ozone with a molar yield of 17.6% was also observed. The particle size distribution and volume concentrations were monitored and facilitated the calculation of SOA yields, which ranged from 0 to 0.01 (ozonolysis in the presence of CO) to 0.39 (myrcene OH radical reaction). Terpenylic acid was found in the SOA samples collected from the ozonolysis of myrcene in the absence of an OH scavenger and the OH radical-initiated reaction of myrcene but not in samples collected from the ozonolysis in the presence of CO as an OH radical scavenger, suggesting that terpenylic acid formation involves the reaction of myrcene with an OH radical. A reaction mechanism describing the formation of terpenylic acid is proposed.

  11. Microporous hollow fibre membrane modules as gas-liquid contactors. Part 1. Physical mass transfer processes : A specific application

    NARCIS (Netherlands)

    Kreulen, H.; Versteeg, G.F.; Swaaij, W.P.M. van

    1993-01-01

    Gas-liquid mass transfer has been studied in a membrane module with non-wetted microporous fibres in the laminar flow regime. This new type of gas/liquid contactor can be operated stabily over a large range of gas and liquid flows because gas and liquid phase do not influence each other directly.

  12. Molecular theory of mass transfer kinetics and dynamics at gas-water interface

    International Nuclear Information System (INIS)

    Morita, Akihiro; Garrett, Bruce C

    2008-01-01

    The mass transfer mechanism across gas-water interface is studied with molecular dynamics (MD) simulation. The MD results provide a robust and qualitatively consistent picture to previous studies about microscopic aspects of mass transfer, including interface structure, free energy profiles for the uptake, scattering dynamics and energy relaxation of impinging molecules. These MD results are quantitatively compared with experimental uptake measurements, and we find that the apparent inconsistency between MD and experiment could be partly resolved by precise decomposition of the observed kinetics into elemental steps. Remaining issues and future perspectives toward constructing a comprehensive multi-scale description of interfacial mass transfer are summarized.

  13. The influence of polymeric membrane gas spargers on hydrodynamics and mass transfer in bubble column bioreactors

    DEFF Research Database (Denmark)

    Tirunehe, Gossay; Norddahl, B.

    2016-01-01

    Gas sparging performances of a flat sheet and tubular polymeric membranes were investigated in 3.1 m bubble column bioreactor operated in a semi batch mode. Air–water and air–CMC (Carboxymethyl cellulose) solutions of 0.5, 0.75 and 1.0 % w/w were used as interacting gas–liquid mediums. CMC...... solutions were employed in the study to simulate rheological properties of bioreactor broth. Gas holdup, bubble size distribution, interfacial area and gas–liquid mass transfer were studied in the homogeneous bubbly flow hydrodynamic regime with superficial gas velocity (UG) range of 0.0004–0.0025 m...

  14. Numerical simulation study of gas-liquid reactive mass transfer along corrugated sheets with interface tracking

    International Nuclear Information System (INIS)

    Haroun, Y.

    2008-11-01

    This work is done within the framework of gas treatment and CO 2 capture process development. The main objective of the present work is to fill the gap between classical experiments and industrial conditions by the use of Computational Fluid Dynamics (CFD). The physical problem considered corresponds to the liquid film flow down a corrugate surface under gravity in present of a gas phase. The chemical species in the gas phase absorb in the liquid phase and react. Numerical calculations are carried out in order to determine the impact of physical and geometrical properties on reactive mass transfer in industrial operating conditions. (author)

  15. Variability in the primary emissions and secondary gas and particle formation from vehicles using bioethanol mixtures.

    Science.gov (United States)

    Gramsch, E; Papapostolou, V; Reyes, F; Vásquez, Y; Castillo, M; Oyola, P; López, G; Cádiz, A; Ferguson, S; Wolfson, M; Lawrence, J; Koutrakis, P

    2018-04-01

    Bioethanol for use in vehicles is becoming a substantial part of global energy infrastructure because it is renewable and some emissions are reduced. Carbon monoxide (CO) emissions and total hydrocarbons (THC) are reduced, but there is still controversy regarding emissions of nitrogen oxides (NO x ), aldehydes, and ethanol; this may be a concern because all these compounds are precursors of ozone and secondary organic aerosol (SOA). The amount of emissions depends on the ethanol content, but it also may depend on the engine quality and ethanol origin. Thus, a photochemical chamber was used to study secondary gas and aerosol formation from two flex-fueled vehicles using different ethanol blends in gasoline. One vehicle and the fuel used were made in the United States, and the others were made in Brazil. Primary emissions of THC, CO, carbon dioxide (CO 2 ), and nonmethane hydrocarbons (NMHC) from both vehicles decreased as the amount of ethanol in gasoline increased. NO x emissions in the U.S. and Brazilian cars decreased with ethanol content. However, emissions of THC, CO, and NO x from the Brazilian car were markedly higher than those from the U.S. car, showing high variability between vehicle technologies. In the Brazilian car, formation of secondary nitrogen dioxide (NO 2 ) and ozone (O 3 ) was lower for higher ethanol content in the fuel. In the U.S. car, NO 2 and O 3 had a small increase. Secondary particle (particulate matter [PM]) formation in the chamber decreased for both vehicles as the fraction of ethanol in fuel increased, consistent with previous studies. Secondary to primary PM ratios for pure gasoline is 11, also consistent with previous studies. In addition, the time required to form secondary PM is longer for higher ethanol blends. These results indicate that using higher ethanol blends may have a positive impact on air quality. The use of bioethanol can significantly reduce petroleum use and greenhouse gas emissions worldwide. Given the extent of

  16. Gas phase emissions from cooking processes and their secondary aerosol production potential

    Science.gov (United States)

    Klein, Felix; Platt, Stephen; Bruns, Emily; Termime-roussel, Brice; Detournay, Anais; Mohr, Claudia; Crippa, Monica; Slowik, Jay; Marchand, Nicolas; Baltensperger, Urs; Prevot, Andre; El Haddad, Imad

    2014-05-01

    Long before the industrial evolution and the era of fossil fuels, high concentrations of aerosol particles were alluded to in heavily populated areas, including ancient Rome and medieval London. Recent radiocarbon measurements (14C) conducted in modern megacities came as a surprise: carbonaceous aerosol (mainly organic aerosol, OA), a predominant fraction of particulate matter (PM), remains overwhelmingly non-fossil despite extensive fossil fuel combustion. Such particles are directly emitted (primary OA, POA) or formed in-situ in the atmosphere (secondary OA, SOA) via photochemical reactions of volatile organic compounds (VOCs). Urban levels of non-fossil OA greatly exceed the levels measured in pristine environments strongly impacted by biogenic emissions, suggesting a contribution from unidentified anthropogenic non-fossil sources to urban OA. Positive matrix factorization (PMF) techniques applied to ambient aerosol mass spectrometer (AMS, Aerodyne) data identify primary cooking emissions (COA) as one of the main sources of primary non-fossil OA in major cities like London (Allan et al., 2010), New York (Sun et al., 2011) and Beijing (Huang et al., 2010). Cooking processes can also emit VOCs that can act as SOA precursors, potentially explaining in part the high levels of oxygenated OA (OOA) identified by the AMS in urban areas. However, at present, the chemical nature of these VOCs and their secondary aerosol production potential (SAPP) remain virtually unknown. The approach adopted here involves laboratory quantification of PM and VOC emission factors from the main primary COA emitting processes and their SAPP. Primary emissions from deep-fat frying, vegetable boiling, vegetable frying and meat cooking for different oils, meats and vegetables were analysed under controlled conditions after ~100 times dilution. A high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) and a high resolution proton transfer time-of-flight mass spectrometer (PTR

  17. NACOWA experiments on LMFBR cover gas aerosols, heat transfer, and fission product enrichment

    International Nuclear Information System (INIS)

    Minges, J.; Schuetz, W.

    1993-12-01

    Fifteen different NACOWA test series were carried out. The following items were investigated: sodium mass concentration in the cover gas, sodium aerosol particle size, radiative heat transfer across the cover gas, total heat transfer across the cover gas, sodium deposition on the cover plate, temperature profiles across the cover gas, phenomena if the argon cover gas is replaced by helium, enrichment of cesium, iodine, and zinc in the aerosol and in the deposits. The conditions were mainly related to the design parameters of the EFR. According to the first consistent design, a pool temperature of 545 C and a roof temperature of only 120 C were foreseen at a cover gas height of 85 cm. The experiments were carried out in a stainless steel test vessel of 0.6 m diameter and 1.14 m height. Pool temperature (up to 545 C), cover gas height (12.5 cm, 33 cm, and others), and roof temperature (from 110 C to 450 C) were the main parameters. (orig./HP) [de

  18. Secondary flow and heat transfer coefficient distributions in the developing flow region of ribbed turbine blade cooling passages

    Science.gov (United States)

    Forsyth, Peter; McGilvray, Matthew; Gillespie, David R. H.

    2017-01-01

    This paper reports an experimental and numerical study of the development and coupling of aerodynamic flows and heat transfer within a model ribbed internal cooling passage to provide insight into the development of secondary flows. Static instrumentation was installed at the end of a long smooth passage and used to measure local flow features in a series of experiments where ribs were incrementally added upstream. This improves test turnaround time and allows higher-resolution heat transfer coefficient distributions to be captured, using a hybrid transient liquid crystal technique. A composite heat transfer coefficient distribution for a 12-rib-pitch passage is reported: notably the behaviour is dominated by the development of the secondary flow in the passage throughout. Both the aerodynamic and heat transfer test data were compared to numerical simulations developed using a commercial computational fluid dynamics solver. By conducting a number of simulations it was possible to interrogate the validity of the underlying assumptions of the experimental strategy; their validity is discussed. The results capture the developing size and strength of the vortical structures in secondary flow. The local flow field was shown to be strongly coupled to the enhancement of heat transfer coefficient. Comparison of the experimental and numerical data generally shows excellent agreement in the level of heat transfer coefficient predicted, though the numerical simulations fail to capture some local enhancement on both the ribbed and smooth surfaces. Where this was the case, the coupled flow and heat transfer measurements were able to identify missing velocity field characteristics.

  19. Heat transfer to a particle exposed to a rarefield ionized-gas flow

    International Nuclear Information System (INIS)

    Chen, X.; He, P.

    1986-01-01

    Analytical results are presented concerning the heat transfer to a spherical particle exposed to a high temperature, ionized- gas flow for the extreme case of free-molecule flow regime. It has been shown that the presence of relative velocity between the particle and the ionized gas reduces the floating potential on the particle, enhances the heat flux and causes appreciably non-uniform distribution of the local heat flux. Pronounced difference is found between metallic and non-metallic particles in the floating potential and the local heat flux distributions, in particular for the case with high gas-flow temperature. Relative contribution of atoms to the total heat flux is dominant for the case of low gas-flow temperature, while the heat flux is mainly caused by ions and electrons for the case of high gas-flow temperature

  20. Carbon dioxide stripping in aquaculture -- part II: development of gas transfer models

    Science.gov (United States)

    Colt, John; Watten, Barnaby; Pfeiffer, Tim

    2012-01-01

    The basic mass transfer equation for gases such as oxygen and carbon dioxide can be derived from integration of the driving force equation. Because of the physical characteristics of the gas transfer processes, slightly different models are used for aerators tested under the non steady-state procedures, than for packed columns, or weirs. It is suggested that the standard condition for carbon dioxide should be 20 °C, 1 atm, CCO2=20 mg/kg, and XCO2=0.000285. The selection of the standard condition for carbon dioxide based on a fixed mole fraction ensures that standardized carbon dioxide transfer rates will be comparable even though the value of C*CO2 in the atmosphere is increasing with time. The computation of mass transfer for carbon dioxide is complicated by the impact of water depth and gas phase enrichment on the saturation concentration within the unit, although the importance of either factor depends strongly on the specific type of aerator. For some types of aerators, the most accurate gas phase model remains to be determined for carbon dioxide. The assumption that carbon dioxide can be treated as a non-reactive gas in packed columns may apply for cold acidic waters but not for warm alkaline waters.

  1. Hexachlorophene. Secondary microorganism resistance to hexachlorophene. Conjugative transfer inhibition by the R-plasmid-coded resistance by hexachlorophene.

    Science.gov (United States)

    Volná, F

    1982-01-01

    Strain resistance of the genus Escherichia, Salmonella, and Pseudomonas to hexachlorophene is inducible. Secondary resistance of the Gram-negative microorganisms to hexachlorophene is an inherited property of these strains. There are not any explicit differences of primary sensitivity to hexachlorophene between sensitive strains and those resistant to antibiotics. The secondary resistance level of Gram-negative microorganisms to hexachlorophene is also not dependent on the natural resistance (or sensitivity) of strains to antibiotics. Hexachlorophene, in concentration of 10 micrograms/ml of conjugation mixture, causes 100% inhibition of the conjugation transfer of the resistance determinants to antibiotics from tested strains with conjugative R-plasmid. The indirect secondary resistance conjugation transfer to hexachlorophene was verified in two cases. The resistance to hexachlorophene was transferred, coupled with resistance to chloramphenicol, tetracycline, and streptomycin, from the Escherichia coli strains (No. 8) and Salmonella typhimurium (No. 4) to the recipient Escherichia coli strain K 12, SZK-Ec-329/74 (No. 2).

  2. Application of 'Hydration Model' to evaluate gas phase transfer of ruthenium and technetium from reprocessing solutions

    International Nuclear Information System (INIS)

    Sasahira, Akira; Hoshikawa, Tadahiro; Kamoshida, Mamoru; Kawamura, Fumio

    1994-01-01

    In order to evaluate the amounts of gas phase transferred ruthenium (Ru), and technetium (Tc), simulations were made for the continuous evaporator used in a reprocessing plant to concentrate high level liquid waste. The concentrations and activities of nitric acid and water, which controlled the reaction rate and gas-liquid equilibrium in the evaporator solution, were evaluated using the previously developed 'Hydration Model'. When the feed solution contained 2.7 M (=mol/dm 3 ) of nitric acid, the nitric acid concentration in the evaporator solution reached its maximum at the concentration factor (CF) of 6 (CF: concentration ratio of FPs in evaporator and feed solutions). The activities of nitric acid and water were saturated at values of 0.01 and 0.43, respectively, after the CF reached 6. The simulation predicted decontamination factors DFs of 2x10 5 and 8x10 3 for Ru and Tc, respectively, for a typical evaporation conditions with an operational pressure of 6,700 Pa, and FPs of 0.02 to 1.4 M. The simulation results agreed with the verification experiment within a factor of 2 for the amount of gas-phase transferred Ru during evaporation. The factor for the amount of gas-phase transferred Tc was estimated as 5 from the measurement error in the gas-liquid equilibrium constant. (author)

  3. Light-induced heat and mass transfer in a single-component gas in a capillary

    International Nuclear Information System (INIS)

    Chermyaninov, I. V.; Chernyak, V. G.; Vilisova, E. A.

    2007-01-01

    A theoretical analysis is presented of light-induced heat and mass transfer in a single-component gas in a capillary tube at arbitrary Knudsen numbers. Surface and collisional mechanisms of transfer are analyzed, due to differences in accommodation coefficient and collision cross section between excited-and ground-state particles, respectively. Analytical expressions for kinetic coefficients characterizing the gas drift and heat transfer in a capillary tube are obtained in the limits of low and high Knudsen numbers. Numerical computations are performed for intermediate Knudsen numbers. Both drift and heat fluxes are determined as functions of the light beam frequency. In the case of an inhomogeneously broadened absorption line, the light-induced fluxes are found to depend not only on the sign, but also on the amount, of light beam detuning from the absorption line center frequency

  4. Gas-liquid mass transfer coefficient of methane in bubble column reactor

    International Nuclear Information System (INIS)

    Lee, Jaewon; Ha, Kyoung-Su; Lee, Jinwon; Kim, Choongik; Yasin, Muhammad; Park, Shinyoung; Chang, In Seop; Lee, Eun Yeol

    2015-01-01

    Biological conversion of methane gas has been attracting considerable recent interest. However, methanotropic bioreactor is limited by low solubility of methane gas in aqueous solution. Although a large mass transfer coefficient of methane in water could possibly overcome this limitation, no dissolved methane probe in aqueous environment is commercially available. We have developed a reactor enabling the measurement of aqueous phase methane concentration and mass transfer coefficient (k L a). The feasibility of the new reactor was demonstrated by measuring k L a values as a function of spinning rate of impeller and flow rate of methane gas. Especially, at spinning rate of 300 rpm and flow rate of 3.0 L/min, a large k L a value of 102.9 h -1 was obtained

  5. Secondary transfer of adult mantled howlers (Alouatta palliata) on Hacienda La Pacifica, Costa Rica: 1975-2009.

    Science.gov (United States)

    Clarke, Margaret R; Glander, Kenneth E

    2010-07-01

    Natal emigration by male and female mantled howlers (Alouatta palliata), and subsequent immigration into breeding groups, is well documented for the free-ranging population on Hacienda La Pacifica, Costa Rica, but secondary transfer was considered rare (Glander in Int J Primatol 3:415-436, 1992). Population surveys in 1998 and 2006 caused us to question our assumptions and to re-evaluate our long-term data set from a post hoc perspective. We first identified all animals observed or captured as adults in more than one non-natal group anywhere in the population. We then systematically analyzed joining or leaving by adults in seven groups tracked for various times from 1975 to 2005 for patterns suggesting secondary transfer. Fourteen adults (nine females, five males) were found in two different non-natal groups as adults. In addition, one male and one female that became dominant and reproduced in their natal group later transferred to a second group, and one female was known to be a tertiary transfer. Data from the seven tracked social groups indicate that 35% of all the males and 29% of all the females were potential secondary transfers. In these groups, males leaving or joining was not associated with group size or absolute number of females. Females leaving or joining was not associated with group size or absolute number of males, but females left groups with more females and joined groups with fewer females. Both sexes left groups with unfavorable sex ratios for their sex and joined groups with sex ratios more favorable for their sex. Since a favorable sex ratio is associated with reproductive success in other howler populations, this suggests secondary transfer as a reproductive strategy. Other factors could also influence secondary transfer.

  6. Test beam results of a low-pressure micro-strip gas chamber with a secondary-electron emitter

    International Nuclear Information System (INIS)

    Kwan, S.; Anderson, D.F.; Zimmerman, J.; Sbarra, C.; Salomon, M.

    1994-10-01

    We present recent results, from a beam test, on the angular dependence of the efficiency and the distribution of the signals on the anode strips of a low-pressure microstrip gas chamber with a thick CsI layer as a secondary-electron emitter. New results of CVD diamond films as secondary-electron emitters are discussed

  7. Numerical simulation of compressible gas flow and heat transfer in a microchannel surrounded by solid media

    International Nuclear Information System (INIS)

    Zhou Jianhua; Zhang Yuwen; Chen, J.K.

    2007-01-01

    In this study, a numerical model is developed to investigate the coupled compressible gas flow and heat transfer in a microchannel surrounded by solid media. To accommodate the varying flow cross-section, the compressible gas flow model is established in a non-orthogonal curvilinear coordinate system. An iterative numerical procedure is employed to solve the coupled heat transfer and gas flow equations. The computer code for the compressible gas flow is first validated against two test problems, and then extended by including the heat conduction in the solid media. The effect of the inlet Mach number on the Nusselt number is examined. It is found that the pressure difference from the pyrolysis front to the heated surface is induced essentially by the gas addition from the channel wall, instead from the pyrolysis front. The necessity of accounting for the gas compressibility is clearly demonstrated when severe heating is applied. The pressure distribution obtained along the channel axial direction is useful for further structural analysis of composite materials

  8. Fluorescence resonance energy transfer of gas-phase ions under ultra high vacuum and ambient conditions.

    Science.gov (United States)

    Frankevich, Vladimir; Chagovets, Vitaliy; Widjaja, Fanny; Barylyuk, Konstantin; Yang, Zhiyi; Zenobi, Renato

    2014-05-21

    We report evidence for fluorescence resonance energy transfer (FRET) of gas-phase ions under ultra high vacuum conditions (10(-9) mbar) inside a mass spectrometer as well as under ambient conditions inside an electrospray plume. Two different FRET pairs based on carboxyrhodamine 6G (donor) and ATTO590 or Bodipy TR (acceptor) dyes were examined and their gas-phase optical properties were studied. Our measurements indicate a different behavior for the two FRET pairs, which can be attributed to their different conformations in the gas phase. Upon desolvation via electrospray ionization, one of the FRET pairs undergoes a conformational change that leads to disappearance of FRET. This study shows the promise of FRET to obtain a direct correlation between solution and gas-phase structures.

  9. Mountain scale modeling of transient, coupled gas flow, heat transfer and carbon-14 migration

    International Nuclear Information System (INIS)

    Lu, Ning; Ross, B.

    1993-01-01

    We simulate mountain-scale coupled heat transfer and gas flow at Yucca Mountain. A coupled rock-gas flow and heat transfer model, TGIF2, is used to simulate mountain-scale two-dimensional transient heat transfer and gas flow. The model is first verified against an analytical solution for the problem of an infinite horizontal layer of fluid heated from below. Our numerical results match very well with the analytical solution. Then, we obtain transient temperature and gas flow distributions inside the mountain. These distributions are used by a transient semianalytical particle tracker to obtain carbon-14 travel times for particles starting at different locations within the repository. Assuming that the repository is filled with 30-year-old waste at an initial areal power density of 57 kw/acre, we find that repository temperatures remain above 60 degrees C for more than 10,000 years. Carbon-14 travel times to the surface are mostly less than 1000 years, for particles starting at any time within the first 10,000 years

  10. Heat transfer characteristics of liquid-gas Taylor flows incorporating microencapsulated phase change materials

    International Nuclear Information System (INIS)

    Howard, J A; Walsh, P A

    2014-01-01

    This paper presents an investigation on the heat transfer characteristics associated with liquid-gas Taylor flows in mini channels incorporating microencapsulated phase change materials (MPCM). Taylor flows have been shown to result in heat transfer enhancements due to the fluid recirculation experienced within liquid slugs which is attributable to the alternating liquid slug and gas bubble flow structure. Microencapsulated phase change materials (MPCM) also offer significant potential with increased thermal capacity due to the latent heat required to cause phase change. The primary aim of this work was to examine the overall heat transfer potential associated with combining these two novel liquid cooling technologies. By investigating the local heat transfer characteristics, the augmentation/degradation over single phase liquid cooling was quantified while examining the effects of dimensionless variables, including Reynolds number, liquid slug length and gas void fraction. An experimental test facility was developed which had a heated test section and allowed MPCM-air Taylor flows to be subjected to a constant heat flux boundary condition. Infrared thermography was used to record high resolution experimental wall temperature measurements and determine local heat transfer coefficients from the thermal entrance point. 30.2% mass particle concentration of the MPCM suspension fluid was examined as it provided the maximum latent heat for absorption. Results demonstrate a significant reduction in experimental wall temperatures associated with MPCM-air Taylor flows when compared with the Graetz solution for conventional single phase coolants. Total enhancement in the thermally developed region is observed to be a combination of the individual contributions due to recirculation within the liquid slugs and also absorption of latent heat. Overall, the study highlights the potential heat transfer enhancements that are attainable within heat exchange devices employing MPCM

  11. Oil and gas technology transfer activities and potential in eight major producing states. Volume 1

    Energy Technology Data Exchange (ETDEWEB)

    1993-07-01

    In 1990, the Interstate Oil and Gas Compact Commission (the Compact) performed a study that identified the structure and deficiencies of the system by which oil and gas producers receive information about the potential of new technologies and communicate their problems and technology needs back to the research community. The conclusions of that work were that major integrated companies have significantly more and better sources of technology information than independent producers. The majors also have significantly better mechanisms for communicating problems to the research and development (R&D) community. As a consequence, the Compact recommended analyzing potential mechanisms to improve technology transfer channels for independents and to accelerate independents acceptance and use of existing and emerging technologies. Building on this work, the Compact, with a grant from the US Department Energy, has reviewed specific technology transfer organizations in each of eight major oil producing states to identify specific R&D and technology transfer organizations, characterize their existing activities, and identify potential future activities that could be performed to enhance technology transfer to oil and gas producers. The profiles were developed based on information received from organizations,follow-up interviews, site visit and conversations, and participation in their sponsored technology transfer activities. The results of this effort are reported in this volume. In addition, the Compact has also developed a framework for the development of evaluation methodologies to determine the effectiveness of technology transfer programs in performing their intended functions and in achieving desired impacts impacts in the producing community. The results of that work are provided in a separate volume.

  12. 40 CFR 63.984 - Fuel gas systems and processes to which storage vessel, transfer rack, or equipment leak...

    Science.gov (United States)

    2010-07-01

    ...) National Emission Standards for Closed Vent Systems, Control Devices, Recovery Devices and Routing to a Fuel Gas System or a Process § 63.984 Fuel gas systems and processes to which storage vessel, transfer... 40 Protection of Environment 10 2010-07-01 2010-07-01 false Fuel gas systems and processes to...

  13. Wireless transfer of measured data. Continuous measurement of natural gas consumption in a liberalized market

    International Nuclear Information System (INIS)

    De Buisonje, B.

    2000-01-01

    In a deregulated market it is very important to be able to measure gas consumption per hour, or even every 5 minutes, on site and reliably transfer the data measured to the trader. It is common practice in the gas industry to make forecasts for each customer taking off more than 10 million m 3 . This requires the preparation of load profiles based on gas consumption during five minutes. For both the consumer and the trader it is important to be informed (semi-)continuously of the actual gas consumption, which can then be directly compared with the expected load profile, after which adjustments can be made. One of the gas distribution companies in the Netherlands, Essent, transfers wireless data in the case of remote metering. Essent uses Ferranti Computer Systems and the Mobitex network of RAM Mobile Data. Consumers also have access to the data measured through the Internet. They can use the actual load profile for billing purposes. Moreover, they can immediately adjust their energy consumption to stick to the offtake forecast as long as possible and thus save costs

  14. Continuous modeling of internal-energy transfers in rarefied-gas flows

    Science.gov (United States)

    Choquet, I.; Marmignon, C.

    A relationship between the mean probability and the instantaneous probability for energy transfer on the molecular scale in rarefied-gas flows is obtained, assuming that the effective collision cross section depends only on the relative velocity. A method for the exact solution of this equation is introduced which leads to Boyd's expressions for rotational-translation transfer and which extends the validity domain of the vibration-translation model. The results obtained demonstrate that it is necessary to take into account the internal-energy dependence of the effective collision cross section if a suitable equilibrium temperature is to be obtained.

  15. Mathematical modeling of heat transfer in production premises heated by gas infrared emitters

    Directory of Open Access Journals (Sweden)

    Maksimov Vyacheslav I.

    2017-01-01

    Full Text Available The results of numerical modeling of the process of free convective heat transfer in the regime of turbulent convection in a closed rectangular region heated by an infrared radiator are presented. The system of Navier-Stokes equations in the Boussinesq approximation is solved, the energy equation for the gas and the heat conduction equations for the enclosing vertical and horizontal walls. A comparative analysis of the heat transfer regimes in the considered region for different Grashof numbers is carried out. The features of the formation of heated air flows relative to the infrared emitter located at some distance from the upper horizontal boundary of the region are singled out.

  16. [Clinical study on treatment of secondary keratoconus with special designed rigid gas permeable contact lens].

    Science.gov (United States)

    Wang, Dan; Xie, Pei-ying; Zhou, Jian-lan

    2013-04-01

    To investigate the clinical effects of special designed rigid gas permeable contact lens (RGPCL) in the treatment of secondary keratoconus. Retrospective study. The results of correction of secondary keratoconus by the RGPCL in 89 cases (102 eyes) at the Optometry & Ophthalmology Center were analyzed, including history, slit lamp microscope, computer assisted corneal topography, phoropter, corneal endothelial cell examinations and A-scan corneal thickness measurements. We selected and designed the contact lens with different materials for refractive correction according to different corneal deformations. Visual stability and corneal changes were regularly observed. We compared corrected vision, corneal curvature and corneal topography before and after wearing spectacles and RGPCL by using a paired-t test. Secondary keratoconus after keratorefractive operation in 56 cases (67 eyes), including post-LASIK in 53 eyes, post-PRK in 4 eyes and post-RK in 10 eyes were observed. The cornea thickness in the lesion region was less than 0.4 mm, with nebula or macula. Corneal topography showed different local protrusions, Steep K ranged 47.56 D to 69.72 D, corneal astigmatism ranged 4.00 D to 14.00 D, with irregular deformations, visible different degrees matrix strips pattern changes and Fleischer ring. Secondary keratoconus in 31 cases (31 eyes) was developed after corneal injury. The lesions included opaque scar, decrease of corneal endothelial density, multi-deformations and aphakia in 15 eyes. In addition, there were different degrees of damage in pupil, iris, vitreous and retina. Secondary keratoconus in one case (2 eyes) was developed after anti-glaucoma and pediatric cataract extraction operations (with intraocular lens implantation). Another case was secondary to repeated bilateral keratitis episodes, with large macula, mild thinning of cornea, neovascularization and roughness of corneal surface. The uncorrected visual acuity in these eyes was poor. After wearing the

  17. Formation of secondary aerosols: impact of the gas-phase chemical mechanism

    Science.gov (United States)

    Kim, Y.; Sartelet, K.; Seigneur, C.

    2010-08-01

    The impact of two recent gas-phase chemical kinetic mechanisms (CB05 and RACM2) on the formation of secondary inorganic and organic aerosols is compared for simulations of PM2.5 over Europe between 15 July and 15 August 2001. The host chemistry transport model is Polair3D of the Polyphemus air-quality platform. Particulate matter is modeled with SIREAM, which is coupled to the thermodynamic model ISORROPIA and to the secondary organic aerosol module MAEC. Model performance is satisfactory with both mechanisms for speciated PM2.5. The monthly-mean difference of the concentration of PM2.5 is less than 1 μg/m3 (6%) over the entire domain. Secondary chemical components of PM2.5 include sulfate, nitrate, ammonium and organic aerosols, and the chemical composition of PM2.5 is not significantly different between the two mechanisms. Monthly-mean concentrations of inorganic aerosol are higher with RACM2 than with CB05 (+16% for sulfate, +11% for nitrate, and +12% for ammonium), whereas the concentrations of organic aerosols are slightly higher with CB05 than with RACM2 (+26% for anthropogenic SOA and +1% for biogenic SOA). Differences in the inorganic and organic aerosols result primarily from differences in oxidant concentrations (OH, O3 and NO3). Nitrate formation tends to be HNO3-limited over land and differences in the concentrations of nitrate are due to differences in concentration of HNO3. Differences in aerosols formed from aromatics SVOC are due to different aromatics oxidation between CB05 and RACM2. The aromatics oxidation in CB05 leads to more cresol formation, which then leads to more SOA. Differences in the aromatics aerosols would be significantly reduced with the recent CB05-TU mechanism for toluene oxidation. Differences in the biogenic aerosols are due to different oxidant concentrations (monoterpenes) and different particulate organic mass concentrations affecting the gas-particle partitioning of SOA (isoprene).

  18. Simulation Of The Secondary Cooling System Failed For One Line Mode Of RSG-GAS

    International Nuclear Information System (INIS)

    Dibyo, Sukmanto; Susyadi; Sembiring, Tagor M; Isnaeni, Darwis

    2003-01-01

    Recently, an assessment of 15 MW power reactor RSG-GAS operated using one line cooling mode is under carried out, in which is in the same manner as BA TAN policy. At the power above mentioned, requirement for the research as well as isotop production has been fulfilled. To obtain the transient condition of 1 line-cooling mode, the simulation using RELAP5.MOD3.2 code was carried out. The simulation parameters interesting known are the inlet of primary coolant temperature after failed the secondary cooling system. At the first, reactor is operated at 15 MW steady state condition using 1 line-cooling mode. Primary coolant flow rate of 430 kg/s and secondary of 550 kg/s respectively. After that the decreasing is occurred due to stop of secondary cooling pump. Therefore the primary cooling inlet temperature to the core increase cause scram reactor by inserted control rod. During the transient occur, the characteristic of primary cooling temperature pattern change were obtained. The simulation result shows that the temperature increase (ΔT) temperature to the reactor is 5,1 o C at the second of 85.5. Here is lower than ΔT for the two cooling mode of 10 o C. That temperature characteristic still tolerable against acceptable safety margin to the flow instability

  19. Feedback model of secondary electron emission in DC gas discharge plasmas

    Science.gov (United States)

    Saravanan, ARUMUGAM; Prince, ALEX; Suraj, Kumar SINHA

    2018-01-01

    Feedback is said to exist in any amplifier when the fraction of output power in fed back as an input. Similarly, in gaseous discharge ions that incident on the cathode act as a natural feedback element to stabilize and self sustain the discharge. The present investigation is intended to emphasize the feedback nature of ions that emits secondary electrons (SEs) from the cathode surface in DC gas discharges. The average number of SEs emitted per incident ion and non ionic species (energetic neutrals, metastables and photons) which results from ion is defined as effective secondary electron emission coefficient (ESEEC,{γ }{{E}}). In this study, we derive an analytic expression that corroborates the relation between {γ }{{E}} and power influx by ion to the cathode based on the feedback theory of an amplifier. In addition, experimentally, we confirmed the typical positive feedback nature of SEE from the cathode in argon DC glow discharges. The experiment is done for three different cathode material of same dimension (tungsten (W), copper (Cu) and brass) under identical discharge conditions (pressure: 0.45 mbar, cathode bias: ‑600 V, discharge gab: 15 cm and operating gas: argon). Further, we found that the {γ }{{E}} value of these cathode material controls the amount of feedback power given by ions. The difference in feedback leads different final output i.e the power carried by ion at cathode ({P}{{i}}{\\prime }{| }{{C}}). The experimentally obtained value of {P}{{i}}{\\prime }{| }{{C}} is 4.28 W, 6.87 W and 9.26 W respectively for W, Cu and brass. In addition, the present investigation reveals that the amount of feedback power in a DC gas discharges not only affect the fraction of power fed back to the cathode but also the entire characteristics of the discharge.

  20. Microporous hollow fibre membrane modules as gas-liquid contactors. Part 1: Physical mass transfer processes. A specific application: mass transfer in highly viscous liquids

    OpenAIRE

    Kreulen, H.; Kreulen, H.; Versteeg, Geert; Smolders, C.A.; Smolders, C.A.; van Swaaij, Willibrordus Petrus Maria

    1993-01-01

    Gas-liquid mass transfer has been studied in a membrane module with non-wetted microporous fibres in the laminar flow regime. This new type of gas/liquid contactor can be operated stabily over a large range of gas and liquid flows because gas and liquid phase do not influence each other directly. Therefore foam is not formed in the module, gas bubbles are not entrained in the liquid flowing out of the reactor and the separation of both phases can be achieved very easily. These phenomena often...

  1. Saclay Reactor: acquired knowledge by two years experience in heat transfer using compressed gas

    International Nuclear Information System (INIS)

    Yvon, J.

    1955-01-01

    Describes the conception and functioning of a new reactor (EL-2) using compressed gas as primary coolant. The aim of the use of compressed gas as primary coolant is to reduce the quantity of heavy water used in the functioning of the reactor. Description of the reactor vessel (dimensions, materials, reflector and protection). Description of the cells and the circulation of the gas within the cells. A complete explanation of the control and regulating of the reaction by the ionization chamber is given. Heavy water is used as modulator: it describes the heavy water system and its recombination system. The fuel slugs are cooled by compressed gas: its system is described as well as the blower and the heat exchanger system. Water is supplied by a cooling tower which means the reactor power is dependant of the atmospheric conditions. Particular attention has been given to the tightness of the different systems used. The relation between neutron flow and the thermal output is discussed: the thermal output can be calculated by measuring the gas flow and its heating or by measuring the neutron flow within the reactor, both methods gives closed results. Reactivity study: determination of the different factors which induce a variation of reactivity. Heat transfer: discussion on the use of different heat transfer systems, determination of the required chemical and physical properties of the primary coolant as well as the discussion of the nuclear and thermal requirements for the choice of it. A comparison between the use of nitrogen and carbon dioxide gas shows an advantage in using nitrogen with the existing knowledge. Reflexion on the relevance of this work and the future perspectives of the use of compressed gas as primary coolant. (M.P.)

  2. Numerical investigation of heat transfer in high-temperature gas-cooled reactors

    Energy Technology Data Exchange (ETDEWEB)

    Chen, g.; Anghaie, S. [Univ. of Florida, Gainesville, FL (United States)

    1995-09-01

    This paper proposes a computational model for analysis of flow and heat transfer in high-temperature gas-cooled reactors. The formulation of the problem is based on using the axisymmetric, thin layer Navier-Stokes equations. A hybrid implicit-explicit method based on finite volume approach is used to numerically solve the governing equations. A fast converging scheme is developed to accelerate the Gauss-Siedel iterative method for problems involving the wall heat flux boundary condition. Several cases are simulated and results of temperature and pressure distribution in the core are presented. Results of a parametric analysis for the assessment of the impact of power density on the convective heat transfer rate and wall temperature are discussed. A comparative analysis is conducted to identify the Nusselt number correlation that best fits the physical conditions of the high-temperature gas-cooled reactors.

  3. Determination of heat transfer coefficient for an interaction of sub-cooled gas and metal

    International Nuclear Information System (INIS)

    Sidek, Mohd Zaidi; Kamarudin, Muhammad Syahidan

    2016-01-01

    Heat transfer coefficient (HTC) for a hot metal surface and their surrounding is one of the need be defined parameter in hot forming process. This study has been conducted to determine the HTC for an interaction between sub-cooled gas sprayed on a hot metal surface. Both experiments and finite element have been adopted in this work. Initially, the designated experiment was conducted to obtain temperature history of spray cooling process. Then, an inverse method was adopted to calculate the HTC value before we validate in a finite element simulation model. The result shows that the heat transfer coefficient for interaction of subcooled gas and hot metal surface is 1000 W/m 2 K. (paper)

  4. Fluctuation theorem for entropy production during effusion of an ideal gas with momentum transfer.

    Science.gov (United States)

    Wood, Kevin; Van den Broeck, C; Kawai, R; Lindenberg, Katja

    2007-06-01

    We derive an exact expression for entropy production during effusion of an ideal gas driven by momentum transfer in addition to energy and particle flux. Following the treatment in Cleuren [Phys. Rev. E 74, 021117 (2006)], we construct a master equation formulation of the process and explicitly verify the thermodynamic fluctuation theorem, thereby directly exhibiting its extended applicability to particle flows and hence to hydrodynamic systems.

  5. Heat transfer from a spherical particle in a rarefied monatomic gas

    Science.gov (United States)

    Pazooki, N.; Loyalka, S. K.

    1988-10-01

    The problem of heat transfer from a spherical particle situated in an infinite expanse of a monatomic gas is considered. The Bhatnagar, Gross, and Krook (BGK) model of the linearized Boltzmann equation is used. The boundary-value problem is converted to a system of linear integral equations, which is solved numerically. Results for radial heat flux, gaseous density, and temperature for all degrees of rarefaction, and arbitrary thermal accommodation coefficient, are obtained.

  6. Simulation of Heat Transfer to the Gas Coolant with Low Prandtl Number Value

    Directory of Open Access Journals (Sweden)

    T. N. Kulikova

    2015-01-01

    Full Text Available The work concerns the simulating peculiarities of heat transfer to the gas coolants with low values of the Prandtl number, in particular, to the binary mixtures of inert gases.The paper presents simulation results of heat transfer to the fully established flow of a helium-xenon mixture in the round tube of 6 mm in diameter with the boundary condition of the second kind. It considers a flow of three helium-xenon mixtures with different helium content and molecular Prandtl numbers within the range 0.239–0.322 and with Reynolds numbers ranged from 10000 to 50000. During numerical simulation a temperature factor changed from 1.034 to 1.061. CFD-code STAR-CCM+ that is designed for solving a wide range of problems of hydrodynamics, heat transfer and stress was used as the primary software.The applicability of the five models for the turbulent Prandtl number is examined. It is shown that the choice of the model has a significant influence on the heat transfer coefficient. The paper presents structural characteristics of the flow in the wall region. It estimates a thermal stabilization section to be approximately as long as 30 diameters of tube.Simulation results are compared with the known data on heat transfer to gas coolants with low values of the Prandtl number. It is shown that V2F low-Reynolds number -ε turbulence model with an approximation for the turbulent Prandtl number used according Kays-CrawfordWeigand gives the best compliance with the results predicted by relationships of Kays W.M. and Petukhov B.S. The approximating correlation summarizes a set of simulation results.Application of the work results is reasonable when conducting the numerical simulation of heat transfer to binary gas mixtures in channels of different forms. The presented approximating correlation allows rapid estimate of heat transfer coefficients to the gas coolants with a low value of the molecular Prandl number within the investigated range with a flow through the

  7. Installation design of pump motor control systems for supplied of the RSG-GAS secondary raw water cooling system

    International Nuclear Information System (INIS)

    Kiswanto; Teguh Sulistyo; M-Taufik

    2013-01-01

    It has designed already of an installation of the pump motor control system for supplied of raw water to fulfil the RSG-GAS secondary cooling system. The installation design of this plant is used to supply electrical energy from PLN and 3 phase generator to operate the pump motor embedded multilevel type, capacity, Q = 30 m 3 /h; electric power, PN = 4 kW; voltage, 380V/3-/50Hz, and Y connections that can be operated manually or automatically by using the automatic transfer switch. The results obtained recapitulation total load of 4 kW, the magnitude of the nominal current of 9.5 A; kind of safety and capacity are used NFB 16 A, use of this type of cable to the control panel is PLN NYY 6 mm 2 diameter maximum current capacity of 25 A cable and use the control panel to the pump motor cable type NYY 4 mm 2 diameter maximum current capacity of 20 A. The design of the pump motor control system installation is ready to be implemented. (author)

  8. Formation of secondary aerosols over Europe: comparison of two gas-phase chemical mechanisms

    Science.gov (United States)

    Kim, Y.; Sartelet, K.; Seigneur, C.

    2011-01-01

    The impact of two recent gas-phase chemical kinetic mechanisms (CB05 and RACM2) on the formation of secondary inorganic and organic aerosols is compared for simulations of PM2.5 over Europe between 15 July and 15 August 2001. The host chemistry transport model is Polair3D of the Polyphemus air-quality platform. Particulate matter is modeled with a sectional aerosol model (SIREAM), which is coupled to the thermodynamic model ISORROPIA for inorganic species and to a module (MAEC) that treats both hydrophobic and hydrophilic species for secondary organic aerosol (SOA). Modifications are made to the gas-phase chemical mechanisms to handle the formation of SOA. In order to isolate the effect of the original chemical mechanisms on PM formation, the addition of reactions and chemical species needed for SOA formation was harmonized to the extent possible between the two gas-phase chemical mechanisms. Model performance is satisfactory with both mechanisms for speciated PM2.5. The monthly-mean difference of the concentration of PM2.5 is less than 1 μg m-3 (6%) over the entire domain. Secondary chemical components of PM2.5 include sulfate, nitrate, ammonium and organic aerosols, and the chemical composition of PM2.5 is not significantly different between the two mechanisms. Monthly-mean concentrations of inorganic aerosol are higher with RACM2 than with CB05 (+16% for sulfate, +11% for nitrate, and +10% for ammonium), whereas the concentrations of organic aerosols are slightly higher with CB05 than with RACM2 (+22% for anthropogenic SOA and +1% for biogenic SOA). Differences in the inorganic and organic aerosols result primarily from differences in oxidant concentrations (OH, O3 and NO3). Nitrate formation tends to be HNO3-limited over land and differences in the concentrations of nitrate are due to differences in concentration of HNO3. Differences in aerosols formed from aromatic SVOC are due to different aromatic oxidation between CB05 and RACM2. The aromatic oxidation in

  9. The performance of a new gas to gas heat exchanger with strip fin

    NARCIS (Netherlands)

    Wang, J.; Hirs, Gerard; Rollmann, P.

    1999-01-01

    A compact gas to gas heat exchanger needs large heat transfer areas on both fluid sides. This can be realised by adding secondary surfaces. The secondary surfaces are plate fin, strip fin, and louvered fin, etc. The fins extend the heat transfer surfaces and promote turbulence. This paper presents a

  10. A simple technique for continuous measurement of time-variable gas transfer in surface waters

    Science.gov (United States)

    Tobias, Craig R.; Bohlke, John Karl; Harvey, Judson W.; Busenberg, Eurybiades

    2009-01-01

    Mass balance models of dissolved gases in streams, lakes, and rivers serve as the basis for estimating wholeecosystem rates for various biogeochemical processes. Rates of gas exchange between water and the atmosphere are important and error-prone components of these models. Here we present a simple and efficient modification of the SF6 gas tracer approach that can be used concurrently while collecting other dissolved gas samples for dissolved gas mass balance studies in streams. It consists of continuously metering SF6-saturated water directly into the stream at a low rate of flow. This approach has advantages over pulse injection of aqueous solutions or bubbling large amounts of SF6 into the stream. By adding the SF6 as a saturated solution, we minimize the possibility that other dissolved gas measurements are affected by sparging and/or bubble injecta. Because the SF6 is added continuously we have a record of changing gas transfer velocity (GTV) that is contemporaneous with the sampling of other nonconservative ambient dissolved gases. Over a single diel period, a 30% variation in GTV was observed in a second-order stream (Sugar Creek, Indiana, USA). The changing GTV could be attributed in part to changes in temperature and windspeed that occurred on hourly to diel timescales.

  11. Theoretical studies on membrane-based gas separation using computational fluid dynamics (CFD) of mass transfer

    International Nuclear Information System (INIS)

    Sohrabi, M.R.; Marjani, A.; Davallo, M.; Moradi, S.; Shirazian, S.

    2011-01-01

    A 2D mass transfer model was developed to study carbon dioxide removal by absorption in membrane contactors. The model predicts the steady state absorbent and carbon dioxide concentrations in the membrane by solving the conservation equations. The continuity equations for three sub domains of the membrane contactor involving the tube; membrane and shell were obtained and solved by finite element method (FEM). The model was based on 'non-wetted mode' in which the gas phase filled the membrane pores. Laminar parabolic velocity profile was used for the liquid flow in the tube side; whereas, the gas flow in the shell side was characterized by Happel's free surface model. Axial and radial diffusion transport inside the shell, through the membrane, and within the tube side of the contactor was considered in the mass transfer model. The predictions of percent CO/sub 2/ removal obtained by modeling were compared with the experimental values obtained from literature. They were the experimental results for CO/sub 2/ removal from CO/sub 2//N/sub 2/ gas mixture with amines aqueous solutions as the liquid solvent using polypropylene membrane contactor. The modeling predictions were in good agreement with the experimental values for different values of gas and liquid flow rates. (author)

  12. Oil and gas property transfers: Analyzing the environmental risk through the environmental site assessment process

    International Nuclear Information System (INIS)

    Bratberg, D.; Hocker, S.

    1994-01-01

    The Superfund Act made anyone buying contaminated real estate liable for cleanup costs whether they know about the contamination or contributed to the contamination. In 1986, SARA amended the Superfund Act to include a provision known as the ''Innocent Landowner Defense.'' This provision created a defense for purchasers of contaminated property who did not contribute to the contamination and had no reason to believe that the property was contaminated at the time of the real estate transfer. SARA allows the purchasers and lenders to perform an environmental assessment using ''due diligence'' to identify contamination problems existing at a site. Since the passing of SARA, the environmental site assessment (ESA) process has become commonplace during the transfer of commercial real estate. Since the introduction of SARA, many professional associations, governmental agencies, and proposed federal legislation have struggled to produce a standard for conducting Phase 1 ESAs. Only recently has a standard been produced. Until recently, the domestic oil and gas industry has been relatively unconcerned about the Superfund liability issues. This approach was created by Congress's decision in 1980 to temporarily exempt the majority of oil and gas exploration and production wastes from federal hazardous waste rulings. However, new stringent rules governing oil and gas waste management practices are being considered by federal and state regulatory agencies. Based upon this knowledge and the awakening of public awareness, the use of ESAs for oil and gas transactions is increasing

  13. The gas-liquid mass transfer coefficient (k(L)a) in the gas-liquid Multi-stage Agitated Contactor (MAC)

    NARCIS (Netherlands)

    Breman, B.B; Beenackers, A.A C M; Bouma, M.J; VanderWerf, M.H.

    1996-01-01

    Data on the volumetric liquid-side gas-liquid mass transfer coefficient, k(L)a, in a Multi-stage Agitated Contractor (MAC) are reported for three gas-liquid systems (air-water, helium-n-octane, and air-Monoethylene Glycol (MEG)). k(L)a (s(-1)) was determined using a dynamic method with moderately

  14. Experimental study on secondary depressurization action for PWR vessel bottom small break LOCA with HPI failure and gas inflow (ROSA-V/LSTF test SB-PV-03)

    International Nuclear Information System (INIS)

    Suzuki, Mitsuhiro; Takeda, Takeshi; Asaka, Hideaki; Nakamura, Hideo

    2005-06-01

    A small break loss-of-coolant accident (SBLOCA) experiment was conducted at the Large Scale Test Facility (LSTF) of ROSA-V program to study effects of accident management (AM) measures on core cooling, which is important in case of high pressure injection (HPI) system failure during an SBLOCA at a pressurized water reactor (PWR). The LSTF is a full-height and 1/48 volume-scaled facility simulating 4-loop Westinghouse-type PWR (3423 MWt). The experiment, SB-PV-03, simulated a PWR vessel bottom SBLOCA with a rupture of ten instrument-tubes which is equivalent to 0.2% cold leg break. Total HPI failure, non-condensable gas inflow from accumulator injection system (AIS) and operator AM actions on steam generator (SG) secondary depressurization at a rate of -55 K/h and auxiliary feedwater (AFW) supply for 30 minutes were assumed as experiment conditions. It is clarified that the AM actions are effective on primary system depressurization until the end of AIS injection at 1.6 MPa, but thereafter become less effective due to inflow of the non-condensable gas, resulting in delay of low pressure injection (LPI) actuation and whole core heatup under continuous water discharge through the bottom break. The report describes these thermohydraulic phenomena related with transient primary coolant mass and AM actions in addition to estimation of non-condensable gas behavior which affected primary-to-secondary heat transfer. (author)

  15. Increasing Gas Hydrate Formation Temperature for Desalination of High Salinity Produced Water with Secondary Guests

    Energy Technology Data Exchange (ETDEWEB)

    Cha, Jong-Ho; Seol, Yongkoo

    2013-10-07

    We suggest a new gas hydrate-based desalination process using water-immiscible hydrate formers; cyclopentane (CP) and cyclohexane (CH) as secondary hydrate guests to alleviate temperature requirements for hydrate formation. The hydrate formation reactions were carried out in an isobaric condition of 3.1 MPa to find the upper temperature limit of CO2 hydrate formation. Simulated produced water (8.95 wt % salinity) mixed with the hydrate formers shows an increased upper temperature limit from -2 °C for simple CO2 hydrate to 16 and 7 °C for double (CO2 + CP) and (CO2 + CH) hydrates, respectively. The resulting conversion rate to double hydrate turned out to be similar to that with simple CO2 hydrate at the upper temperature limit. Hydrate formation rates (Rf) for the double hydrates with CP and CH are shown to be 22 and 16 times higher, respectively, than that of the simple CO2 hydrate at the upper temperature limit. Such mild hydrate formation temperature and fast formation kinetics indicate increased energy efficiency of the double hydrate system for the desalination process. Dissociated water from the hydrates shows greater than 90% salt removal efficiency for the hydrates with the secondary guests, which is also improved from about 70% salt removal efficiency for the simple hydrates.

  16. Peptide secondary structures in the gas phase: consensus motif of N-linked glycoproteins.

    Science.gov (United States)

    Cocinero, Emilio J; Stanca-Kaposta, E Cristina; Gamblin, David P; Davis, Benjamin G; Simons, John P

    2009-01-28

    The possibility of secondary structure acting as a primary determinant in nature's choice of the consensus sequon, NXS/T in all N-linked glycoproteins, has been addressed by determining the intrinsic secondary structures of the capped oligopeptide, Ac-NGS-NHBn, and two "mutants", Ac-QGS-NHBn and Ac-NPS-NHBn, by use of infrared laser ion dip spectroscopy in the gas phase coupled with ab initio and density functional theory calculation. Their global minimum energy conformations, exclusively or preferentially populated in all three peptides, display marked differences. NGS adopts an open, S-shaped backbone conformation rather than the C(10) "Asx" turn structure that all previous measurements have identified in solution; the difference can be related to the high dipole moment of the "Asx" conformation and structural selection in a polar environment. QGS adopts a similar but more rigid backbone structure, supported by markedly stronger hydrogen bonds. NPS adopts an Asx turn coupled with a C(10) beta-turn backbone conformation, a structure also adopted in a crystal environment. These and other more subtle structural differences, particularly those involving interactions with the carboxamide side chain, provide strong evidence for the operation of structural constraints, and a potential insight into the unique reactivity of the asparagine side chain toward enzymatic glycosylation.

  17. Impact of transcranial direct current stimulation on somatosensory transfer learning: when the secondary somatosensory cortex comes into play.

    Science.gov (United States)

    Hirtz, Raphael; Weiss, Thomas; Huonker, Ralph; Witte, Otto W

    2018-04-03

    Transfer learning is an immanent feature of perceptual learning. Yet, despite the increasingly widespread application of transcranial direct current stimulation (tDCS) to study learning, transfer effects in response to tDCS have not been studied. Therefore, the present study investigated the transfer of tactile acuity evoked by repeatedly applied anodal tDCS over the left primary somatosensory cortex (S1) over the course of five days from the dominant (right) to the non-dominant (left) index finger (IF). There was a complete transfer of improvement of the right IF to its contralateral homologue by follow-up four weeks later. Changes in tactile acuity of the left IF in the tDCS anodal condition were accompanied by a significant longitudinal change in functional connectivity between the left S1 and the right secondary somatosensory cortex (S2) assessed at day five of tDCS delivery and four week later. Moreover, we observed a close link between tactile acuity and (changes of) functional connectivity of the right S2 in the tDCS anodal condition identifying the S2 as neural correlate to mediate the transfer of tDCS effects in the somatosensory domain. These findings provide unprecedented evidence of transfer effects evoked by tDCS, implicate the S2 in somatosensory transfer learning and provide evidence in support of models of perceptual learning allocating learning to the reweighting of connections between different levels of processing. Copyright © 2018. Published by Elsevier B.V.

  18. Pneumatosis intestinalis and portal venous gas secondary to Gefitinib therapy for lung adenocarcinoma

    Directory of Open Access Journals (Sweden)

    Lee Joo

    2012-03-01

    Full Text Available Abstract Background Pneumatosis intestinalis (PI, defined as the presence of gas in the bowel wall, and portal venous gas (PVG are relatively rare radiological findings. Although several chemotherapeutic agents and anti-vascular endothelial growth factor agents are reported to be associated with PI and PVG, an association with anti-epidermal growth factor receptor (EGFR agents has not been described previously. Case presentation The present report describes a case of PI and PVG secondary to treatment with an EGFR tyrosine kinase inhibitor. A 66-year-old woman who had been diagnosed with metastatic lung adenocarcinoma presented with nausea, vomiting and abdominal distension after commencing gefitinib. A computed tomography (CT scan of the abdomen revealed PI extending from the ascending colon to the rectum, hepatic PVG, and infarction of the liver. Gefitinib therapy was discontinued immediately and the patient was managed conservatively. A follow-up CT scan 2 weeks later revealed that the PI and hepatic PVG had completely resolved. Conclusion This is the first report of PI and PVG caused by EGFR tyrosine kinase inhibitor. Although these complications are extremely rare, clinicians should be aware of the risk of PI and PVG in patients undergoing targeted molecular therapy.

  19. Gas transfer under breaking waves: experiments and an improved vorticity-based model

    Directory of Open Access Journals (Sweden)

    V. K. Tsoukala

    2008-07-01

    Full Text Available In the present paper a modified vorticity-based model for gas transfer under breaking waves in the absence of significant wind forcing is presented. A theoretically valid and practically applicable mathematical expression is suggested for the assessment of the oxygen transfer coefficient in the area of wave-breaking. The proposed model is based on the theory of surface renewal that expresses the oxygen transfer coefficient as a function of both the wave vorticity and the Reynolds wave number for breaking waves. Experimental data were collected in wave flumes of various scales: a small-scale experiments were carried out using both a sloping beach and a rubble-mound breakwater in the wave flume of the Laboratory of Harbor Works, NTUA, Greece; b large-scale experiments were carried out with a sloping beach in the wind-wave flume of Delft Hydraulics, the Netherlands, and with a three-layer rubble mound breakwater in the Schneideberg Wave Flume of the Franzius Institute, University of Hannover, Germany. The experimental data acquired from both the small- and large-scale experiments were in good agreement with the proposed model. Although the apparent transfer coefficients from the large-scale experiments were lower than those determined from the small-scale experiments, the actual oxygen transfer coefficients, as calculated using a discretized form of the transport equation, are in the same order of magnitude for both the small- and large-scale experiments. The validity of the proposed model is compared to experimental results from other researchers. Although the results are encouraging, additional research is needed, to incorporate the influence of bubble mediated gas exchange, before these results are used for an environmental friendly design of harbor works, or for projects involving waste disposal at sea.

  20. Investigation of secondary formation of formic acid: urban environment vs. oil and gas producing region

    Science.gov (United States)

    Yuan, B.; Veres, P. R.; Warneke, C.; Roberts, J. M.; Gilman, J. B.; Koss, A.; Edwards, P. M.; Graus, M.; Kuster, W. C.; Li, S.-M.; Wild, R. J.; Brown, S. S.; Dubé, W. P.; Lerner, B. M.; Williams, E. J.; Johnson, J. E.; Quinn, P. K.; Bates, T. S.; Lefer, B.; Hayes, P. L.; Jimenez, J. L.; Weber, R. J.; Zamora, R.; Ervens, B.; Millet, D. B.; Rappenglück, B.; de Gouw, J. A.

    2015-02-01

    Formic acid (HCOOH) is one of the most abundant carboxylic acids in the atmosphere. However, current photochemical models cannot fully explain observed concentrations and in particular secondary formation of formic acid across various environments. In this work, formic acid measurements made at an urban receptor site (Pasadena) in June-July 2010 during CalNex (California Research at the Nexus of Air Quality and Climate Change) and a site in an oil and gas producing region (Uintah Basin) in January-February 2013 during UBWOS 2013 (Uintah Basin Winter Ozone Studies) will be discussed. Although the VOC (volatile organic compounds) compositions differed dramatically at the two sites, measured formic acid concentrations were comparable: 2.3 ± 1.3 in UBWOS 2013 and 2.0 ± 1.0 ppb in CalNex. We determine that concentrations of formic acid at both sites were dominated by secondary formation (> 99%). A constrained box model using the Master Chemical Mechanism (MCM v3.2) underestimates the measured formic acid concentrations drastically at both sites (by a factor of > 10). Compared to the original MCM model that includes only ozonolysis of unsaturated organic compounds and OH oxidation of acetylene, when we updated yields of ozonolysis of alkenes and included OH oxidation of isoprene, vinyl alcohol chemistry, reaction of formaldehyde with HO2, oxidation of aromatics, and reaction of CH3O2 with OH, the model predictions for formic acid were improved by a factor of 6.4 in UBWOS 2013 and 4.5 in CalNex, respectively. A comparison of measured and modeled HCOOH/acetone ratios is used to evaluate the model performance for formic acid. We conclude that the modified chemical mechanism can explain 19 and 45% of secondary formation of formic acid in UBWOS 2013 and CalNex, respectively. The contributions from aqueous reactions in aerosol and heterogeneous reactions on aerosol surface to formic acid are estimated to be 0-6 and 0-5% in UBWOS 2013 and CalNex, respectively. We observe that

  1. Characterization of carbon dioxide transfer in a hollow fiber membrane module as a solution for gas-liquid transfer in microgravity conditions.

    Science.gov (United States)

    Farges, Berangere; Duchez, David; Dussap, Claude-Gilles; Cornet, Jean-F.

    In microgravity, one of the major difficulties encountered in closed photosynthetic reactors is the gas-liquid transfer with the necessity to provide CO2 (carbon source, pH control) and to recover the produced O2 . Indeed, reduced gravity is expected to modify gas liquid transfer and liquid phase mixing characteristics inside photobioreactors conceived to regenerate atmosphere of closed life-support systems. To obtain efficient mass transfer conditions and mixing of phases, several solutions are possible: use of rotating reactor (centrifugal field), use of forced, co-current convective reactor with gas-liquid separator and use of membrane modules. In terms of space process engineering, the membrane reactor can be a valuable alternative in which the gas and liquid phases are separated with a selectively permeable membrane. The rate-limiting factors in this reactor were demonstrated to be the surface of membrane A needed for diffusion of gases and the CO2 and O2 mass transfer coefficients in the liquid phase kL. How-ever, the major advantages of the membrane reactor are that it is composed of a hydrophobic membrane (here PTFE) which showed a high hydrophobicity, an important chemical resis-tance, a very long term stability and overall which is favourable to gas transfer. Moreover, the volumetric mass transfer coefficients are sufficiently high to build compact systems with small footprints, no complex rotating devices and lighter weights. This paper describes first the development of a system enabling the accurate characterization of the mass transfer limiting step for a PTFE membrane module. This original technical apparatus, together with a technical assessment of membrane permeability to different gases, is associated with a balance model, determining thus completely the CO2 mass transfer problem between phases. First results are given and discussed for the CO2 mass transfer coefficient CO kL 2 obtained in case of an absorption experiment at pH = 8 using the

  2. Effect of secondary air supply rate on the combustion of volatile gas in a controlled-air incinerator

    International Nuclear Information System (INIS)

    Jangsawang, W.; Vallikul, P.; Kerdsuwan, S.; Fungtammasan, B.

    2005-01-01

    Experiments have been carried out to study the effect of secondary air supply rate on the combustion of volatile gas in a controlled-air incinerator. The secondary air supply was varied at flow rates of 0.56, 1.026, 1.73 Nm 3 /min. The waste in this study was categorized into three types: namely those containing low, medium and high combustible matter. The significant results of the experimental investigation showed that increasing secondary air supply rate reduces the chamber temperature in both chambers and strong effect on CO reduction for waste with high combustible content. NO formation increases slightly as secondary air supply increases and SO 2 formation depends on the sulfur content in the waste and is insensitive to secondary air for the range of flow rate tested. (Author)

  3. A new method of heat transfer augmentation by means of foreign gas jet impingement in liquid bath

    International Nuclear Information System (INIS)

    Ma, C.F.; Gan, Y.P.; Tang, F.J.; Bergles, A.E.

    1987-01-01

    The authors discuss a two-phase two-component experimental system developed to study enhancement of heat transfer from a vertical chip size heater to surrounding liquid (Freon 113 or Ethanol) due to air jet impingement. Heat transfer coefficient was measured as function of jet velocity, heat flux and the distance between exit of jet tube and heated surface. The injector was placed very close to the hot surface. It was found that the heat transfer was notably enhanced with foreign gas impingement, especially in the cases of small temperature differences between wall and coolant. In fact for higher jet velocities the heat transfer coefficients tended to infinite while the temperature differences between wall and coolant were zero. The heat transfer coefficients decreased with the increasing of heat flux. High-speed camera was used to study the behaviour of the gas bubbles which play very important role in the heat transfer process. A physical model of simultaneous heat and mass transfer was presented to explain the special heat transfer characteristics in this system. It was suggested by the experimental and analytical investigations that the heat transmission was enhanced not only by agitation of the liquid by the gas bubbles but also by evaporative cooling of the liquid film beneath the gas bubble. Based on this model a semiempirical method was developed and can be used to correlate the non-boiling data

  4. Microporous hollow fibre membrane modules as gas-liquid contactors. Part 1. Physical mass transfer processes: A specific application

    OpenAIRE

    Kreulen, H.; Versteeg, G.F.; Swaaij, W.P.M. van

    1993-01-01

    Gas-liquid mass transfer has been studied in a membrane module with non-wetted microporous fibres in the laminar flow regime. This new type of gas/liquid contactor can be operated stabily over a large range of gas and liquid flows because gas and liquid phase do not influence each other directly. Therefore foam is not formed in the module, gas bubbles are not entrained in the liquid flowing out of the reactor and the separation of both phases can be achieved very easily. These phenomena often...

  5. TECHNOLOGY TRANSFER TO U.S. INDEPENDENT OIL AND NATURAL GAS PRODUCERS

    Energy Technology Data Exchange (ETDEWEB)

    Donald Duttlinger

    1999-12-01

    During FY99, the Petroleum Technology Transfer Council (PTTC) continued pursuing its mission of helping U.S. independent oil and gas producers make timely, informed technology decisions. PTfC's national organization has active grassroots programs that connect with independents through its 10 Regional Lead Organizations (RLOs). These activities--including technology workshops, resource centers, websites, newsletters, and other outreach efforts--are guided by regional Producer Advisory Groups (PAGs). The role of the national headquarters (HQ) staff includes planning and managing the PTTC program, conducting nation-wide technology transfer activities, and implementing a comprehensive communications effort. This technical progress report summarizes PTTC's accomplishments during FY99, which lay the groundwork for further growth in the future.

  6. Mathematical Simulation of Convective Heat Transfer in the Low-Temperature Storage of Liquefied Natural Gas

    Directory of Open Access Journals (Sweden)

    Shestakov Igor A.

    2015-01-01

    Full Text Available The article shows the results of mathematical modeling of convective heat transfer in the low-temperature storage of liquefied natural gas. Regime of natural convection in an enclosure with different intensity of the heat flux at the external borders are investigated. Was examined two-dimensional nonstationary problem within the model of Navier-Stokes in dimensionless variables “vorticity - stream function - temperature”. Distributions of hydrodynamic parameters and temperatures that characterize the basic regularities of the processes are obtained. Circulating flows are determined and carried out the analysis of vortices formation mechanism and the temperature distribution in solution at conditions of natural convection when the Grashof number (Gr = 106. A significant influence of heat transfer rate on solutions boundary on flow structure and temperature field in LNG storage tanks.

  7. TECHNOLOGY TRANSFER TO U.S. INDEPENDENT OIL AND NATURAL GAS PRODUCERS

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    2000-05-01

    During FY00, the Petroleum Technology Transfer Council (PTTC) continued pursuing its mission of helping U.S. independent oil and gas producers make timely, informed technology decisions. PTTC's national organization has active grassroots programs that connect with independents through its 10 Regional Lead Organizations (RLOs). These activities--including technology workshops, resource centers, websites, newsletters, and other outreach efforts--are guided by regional Producer Advisory Groups (PAGs). The role of the national headquarters (HQ) staff includes planning and managing the PTTC program, conducting nation-wide technology transfer activities, and implementing a comprehensive communications effort. This technical progress report summarizes PTTC's accomplishments during FY00, which lay the groundwork for further growth in the future.

  8. Gas-liquid mass transfer in a cross-flow hollow fiber module : Analytical model and experimental validation

    NARCIS (Netherlands)

    Dindore, V. Y.; Versteeg, G. F.

    2005-01-01

    The cross-flow operation of hollow fiber membrane contactors offers many advantages and is preferred over the parallel-flow contactors for gas-liquid mass transfer operations. However, the analysis of such a cross-flow membrane gas-liquid contactor is complicated due to the change in concentrations

  9. Experimental Investigation on Acoustic Control Droplet Transfer in Ultrasonic-Wave-Assisted Gas Metal Arc Welding

    Science.gov (United States)

    Weifeng, Xie; Chenglei, Fan; Chunli, Yang; Sanbao, Lin

    2018-02-01

    Ultrasonic-wave-assisted gas metal arc welding (U-GMAW) is a new, advanced arc welding method that uses an ultrasonic wave emitted from an ultrasonic radiator above the arc. However, it remains unclear how the ultrasonic wave affects the metal droplet, hindering further application of U-GMAW. In this paper, an improved U-GMAW system was used and its superiority was experimentally demonstrated. Then a series of experiments were designed and performed to study how the ultrasonic wave affects droplet transfer, including droplet size, velocity, and motion trajectory. The behavior of droplet transfer was observed in high-speed images. The droplet transfer is closely related to the distribution of the acoustic field, determined by the ultrasonic current. Moreover, by analyzing the variably accelerated motion of the droplet, the acoustic control of the droplet transfer was intuitively demonstrated. Finally, U-GMAW was successfully used in vertical-up and overhead welding experiments, showing that U-GMAW is promising for use in welding in all positions.

  10. Computational prediction of heat transfer to gas turbine nozzle guide vanes with roughened surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Guo, S.M.; Jones, T.V. [Univ. of Oxford (United Kingdom). Dept. of Engineering Science; Lock, G.D. [Univ. of Bath (United Kingdom). Dept. of Mechanical Engineering; Dancer, S.N. [Rolls-Royce PLC, Derby (United Kingdom)

    1998-04-01

    The local Mach number and heat transfer coefficient over the aerofoil surfaces and endwalls of a transonic gas turbine nozzle guide vane have been calculated. the computations were performed by solving the time-averaged Navier-Stokes equations using a fully three-dimensional computational code (CFDS), which is well established at Rolls-Royce. A model to predict the effects of roughness has been incorporated into CFDS and heat transfer levels have been calculated for both hydraulically smooth and transitionally rough surfaces. The roughness influences the calculations in two ways; first the mixing length at a certain height above the surface is increased; second the wall function used to reconcile the wall condition with the first grid point above the wall is also altered. The first involves a relatively straightforward shift of the origin in the van Driest damping function description, the second requires an integration of the momentum equation across the wall layer. A similar treatment applies to the energy equation. The calculations are compared with experimental contours of heat transfer coefficient obtained using both thin-film gages and the transient liquid crystal technique. Measurements were performed using both hydraulically smooth and roughened surfaces, and at engine-representative Mach and Reynolds numbers. The heat transfer results are discussed and interpreted in terms of surface-shear flow visualization using oil and dye techniques.

  11. Dynamics of pulsed expansion of polyatomic gas cloud: Internal-translational energy transfer contribution

    International Nuclear Information System (INIS)

    Morozov, A. A.

    2007-01-01

    Polyatomic gas cloud expansion under pulsed laser evaporation is studied on the basis of one-dimensional direct Monte Carlo simulation. The effect of rotational-translational (RT) and vibrational-translational (VT) energy transfer on dynamics of the cloud expansion is considered. Efficiency of VT energy transfer dependence on the amount of evaporated matter is discussed. To analyze VT energy transfer impact, the number of collisions per molecule during the expansion is calculated. The data are generally in good agreement with available analytical and numerical predictions. Dependencies of the effective number of vibrational degrees of freedom on the number of vibrationally inelastic collisions are obtained and generalized. The importance of the consideration of energy transfer from the internal degrees of freedom to the translational ones is illustrated by an example of pulsed laser evaporation of polytetrafluoroethylene (PTFE). Based on the obtained regularities, analysis of experimental data on pulsed laser evaporation of aniline is performed. The calculated aniline vibrational temperature correlates well with the experimentally measured one

  12. TECHNOLOGY TRANSFER TO U.S. INDEPENDENT OIL AND NATURAL GAS PRODUCERS

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    2003-04-30

    The Petroleum Technology Transfer Council (PTTC) continued pursuing its mission of helping U.S. independent oil and natural gas producers make timely, informed technology decisions. Networking opportunities that occur with a Houston Headquarters (HQ) location are increasing name awareness. Focused efforts by Executive Director Don Duttlinger to interact with large independents, national service companies and some majors are continuing to supplement the support base of the medium to smaller industry participants around the country. PTTC is now involved in many of the technology-related activities that occur in high oil and natural gas activity areas. Access to technology remains the driving force for those who do not have in-house research and development capabilities and look to the PTTC to provide services and options for increased efficiency.

  13. Unsteady heat transfer of a monatomic gas between two coaxial circular cylinders

    Directory of Open Access Journals (Sweden)

    A. M. Abourabia

    2002-01-01

    Full Text Available We consider a kinetic-theory treatment of the cylindrical unsteady heat transfer. A model kinetic equation of the BGK (Bhatnager-Gross-Krook type is solved using the method of moments with a two-sided distribution function. We study the relations between the different macroscopic properties of the gas as the temperature, density, and heat flux with both the radial distance r and the time t. Also we study the problem from the viewpoint of irreversible thermodynamics and estimate the entropy, entropy production, entropy flux, thermodynamic forces, kinetic coefficients, the change in internal energy, and verify Onsager′s relation for nonequilibrium thermodynamic properties of the system.

  14. Experimental and numerical investigations of heat transfer and thermal efficiency of an infrared gas stove

    Science.gov (United States)

    Charoenlerdchanya, A.; Rattanadecho, P.; Keangin, P.

    2018-01-01

    An infrared gas stove is a low-pressure gas stove type and it has higher thermal efficiency than the other domestic cooking stoves. This study considers the computationally determine water and air temperature distributions, water and air velocity distributions and thermal efficiency of the infrared gas stove. The goal of this work is to investigate the effect of various pot diameters i.e. 220 mm, 240 mm and 260 mm on the water and air temperature distributions, water and air velocity distributions and thermal efficiency of the infrared gas stove. The time-dependent heat transfer equation involving diffusion and convection coupled with the time-dependent fluid dynamic equation is implemented and is solved by using the finite element method (FEM). The computer simulation study is validated with an experimental study, which is use standard experiment by LPG test for low-pressure gas stove in households (TIS No. 2312-2549). The findings revealed that the water and air temperature distributions increase with greater heating time, which varies with the three different pot diameters (220 mm, 240 mm and 260 mm). Similarly, the greater heating time, the water and air velocity distributions increase that vary by pot diameters (220, 240 and 260 mm). The maximum water temperature in the case of pot diameter of 220 mm is higher than the maximum water velocity in the case of pot diameters of 240 mm and 260 mm, respectively. However, the maximum air temperature in the case of pot diameter of 260 mm is higher than the maximum water velocity in the case of pot diameters of 240 mm and 220 mm, respectively. The obtained results may provide a basis for improving the energy efficiency of infrared gas stoves and other equipment, including helping to reduce energy consumption.

  15. Gas-grain energy transfer in solar nebula shock waves: Implications for the origin of chondrules

    Science.gov (United States)

    Hood, L. L.; Horanyi, M.

    1993-01-01

    Meteoritic chondrules provide evidence for the occurrence of rapid transient heating events in the protoplanetary nebula. Astronomical evidence suggests that gas dynamic shock waves are likely to be excited in protostellar accretion disks by processes such as protosolar mass ejections, nonaxisymmetric structures in an evolving disk, and impact on the nebula surface of infalling 'clumps' of circumstellar gas. Previous detailed calculations of gas-grain energy and momentum transfer have supported the possibility that such shock waves could have melted pre-existing chondrule-sized grains. The main requirement for grains to reach melting temperatures in shock waves with plausibly low Mach numbers is that grains existed in dust-rich zones (optical depth greater than 1) where radiative cooling of a given grain can be nearly balanced by radiation from surrounding grains. Localized dust-rich zones also provide a means of explaining the apparent small spatial scale of heating events. For example, the scale size of at least some optically thick dust-rich zones must have been relatively small (less than 10 kilometers) to be consistent with petrologic evidence for accretion of hot material onto cold chondrules. The implied number density of mm-sized grains for these zones would be greater than 30 m(exp -3). In this paper, we make several improvements of our earlier calculations to include radiation self-consistently in the shock jump conditions, and we include heating of grains due to radiation from the shocked gas. In addition, we estimate the importance of momentum feedback of dust concentrations onto the shocked gas which would tend to reduce the efficiency of gas dynamic heating of grains in the center of the dust cloud.

  16. Radiative transfer calculations of the diffuse ionised gas in disc galaxies with cosmic ray feedback.

    Science.gov (United States)

    Vandenbroucke, Bert; Wood, Kenneth; Girichidis, Philipp; Hill, Alex; Peters, Thomas

    2018-03-01

    The large vertical scale heights of the diffuse ionised gas (DIG) in disc galaxies are challenging to model, as hydrodynamical models including only thermal feedback seem to be unable to support gas at these heights. In this paper, we use a three dimensional Monte Carlo radiation transfer code to post-process disc simulations of the Simulating the Life-Cycle of Molecular Clouds (SILCC) project that include feedback by cosmic rays. We show that the more extended discs in simulations including cosmic ray feedback naturally lead to larger scale heights for the DIG which are more in line with observed scale heights. We also show that including a fiducial cosmic ray heating term in our model can help to increase the temperature as a function of disc scale height, but fails to reproduce observed DIG nitrogen and sulphur forbidden line intensities. We show that, to reproduce these line emissions, we require a heating mechanism that affects gas over a larger density range than is achieved by cosmic ray heating, which can be achieved by fine tuning the total luminosity of ionising sources to get an apropriate ionising spectrum as a function of scale height. This result sheds a new light on the relation between forbidden line emissions and temperature profiles for realistic DIG gas distributions.

  17. Humidity independent mass spectrometry for gas phase chemical analysis via ambient proton transfer reaction.

    Science.gov (United States)

    Zhu, Hongying; Huang, Guangming

    2015-03-31

    In this work, a humidity independent mass spectrometric method was developed for rapid analysis of gas phase chemicals. This method is based upon ambient proton transfer reaction between gas phase chemicals and charged water droplets, in a reaction chamber with nearly saturate humidity under atmospheric pressure. The humidity independent nature enables direct and rapid analysis of raw gas phase samples, avoiding time- and sample-consuming sample pretreatments in conventional mass spectrometry methods to control sample humidity. Acetone, benzene, toluene, ethylbenzene and meta-xylene were used to evaluate the analytical performance of present method. The limits of detection for benzene, toluene, ethylbenzene and meta-xylene are in the range of ∼0.1 to ∼0.3 ppbV; that of benzene is well below the present European Union permissible exposure limit for benzene vapor (5 μg m(-3), ∼1.44 ppbV), with linear ranges of approximately two orders of magnitude. The majority of the homemade device contains a stainless steel tube as reaction chamber and an ultrasonic humidifier as the source of charged water droplets, which makes this cheap device easy to assemble and facile to operate. In addition, potential application of this method was illustrated by the real time identification of raw gas phase chemicals released from plants at different physiological stages. Copyright © 2015 Elsevier B.V. All rights reserved.

  18. Radiative transfer calculations of the diffuse ionized gas in disc galaxies with cosmic ray feedback

    Science.gov (United States)

    Vandenbroucke, Bert; Wood, Kenneth; Girichidis, Philipp; Hill, Alex S.; Peters, Thomas

    2018-05-01

    The large vertical scale heights of the diffuse ionized gas (DIG) in disc galaxies are challenging to model, as hydrodynamical models including only thermal feedback seem to be unable to support gas at these heights. In this paper, we use a three-dimensional Monte Carlo radiation transfer code to post-process disc simulations of the Simulating the Life-Cycle of Molecular Clouds project that include feedback by cosmic rays. We show that the more extended discs in simulations including cosmic ray feedback naturally lead to larger scale heights for the DIG which are more in line with observed scale heights. We also show that including a fiducial cosmic ray heating term in our model can help to increase the temperature as a function of disc scale height, but fails to reproduce observed DIG nitrogen and sulphur forbidden line intensities. We show that, to reproduce these line emissions, we require a heating mechanism that affects gas over a larger density range than is achieved by cosmic ray heating, which can be achieved by fine tuning the total luminosity of ionizing sources to get an appropriate ionizing spectrum as a function of scale height. This result sheds a new light on the relation between forbidden line emissions and temperature profiles for realistic DIG gas distributions.

  19. Regio-Selective Intramolecular Hydrogen/Deuterium Exchange in Gas-Phase Electron Transfer Dissociation

    Science.gov (United States)

    Hamuro, Yoshitomo

    2017-05-01

    Protein backbone amide hydrogen/deuterium exchange mass spectrometry (HDX-MS) typically utilizes enzymatic digestion after the exchange reaction and before MS analysis to improve data resolution. Gas-phase fragmentation of a peptic fragment prior to MS analysis is a promising technique to further increase the resolution. The biggest technical challenge for this method is elimination of intramolecular hydrogen/deuterium exchange (scrambling) in the gas phase. The scrambling obscures the location of deuterium. Jørgensen's group pioneered a method to minimize the scrambling in gas-phase electron capture/transfer dissociation. Despite active investigation, the mechanism of hydrogen scrambling is not well-understood. The difficulty stems from the fact that the degree of hydrogen scrambling depends on instruments, various parameters of mass analysis, and peptide analyzed. In most hydrogen scrambling investigations, the hydrogen scrambling is measured by the percentage of scrambling in a whole molecule. This paper demonstrates that the degree of intramolecular hydrogen/deuterium exchange depends on the nature of exchangeable hydrogen sites. The deuterium on Tyr amide of neurotensin (9-13), Arg-Pro-Tyr-Ile-Leu, migrated significantly faster than that on Ile or Leu amides, indicating the loss of deuterium from the original sites is not mere randomization of hydrogen and deuterium but more site-specific phenomena. This more precise approach may help understand the mechanism of intramolecular hydrogen exchange and provide higher confidence for the parameter optimization to eliminate intramolecular hydrogen/deuterium exchange during gas-phase fragmentation.

  20. Preliminary characterization of carbon dioxide transfer in a hollow fiber membrane module as a possible solution for gas-liquid transfer in microgravity conditions

    Science.gov (United States)

    Farges, Bérangère; Duchez, David; Dussap, Claude-Gilles; Cornet, Jean-François

    2012-01-01

    In microgravity, one of the major challenge encountered in biological life support systems (BLSS) is the gas-liquid transfer with, for instance, the necessity to provide CO2 (carbon source, pH control) and to recover the evolved O2 in photobioreactors used as atmosphere bioregenerative systems.This paper describes first the development of a system enabling the accurate characterization of the mass transfer limiting step for a PTFE membrane module used as a possible efficient solution to the microgravity gas-liquid transfer. This original technical apparatus, together with a technical assessment of membrane permeability to different gases, is associated with a balance model, determining thus completely the CO2 mass transfer problem between phases. First results are given and discussed for the CO2 mass transfer coefficient kLCO obtained in case of absorption experiments at pH 8 using the hollow fiber membrane module. The consistency of the proposed method, based on a gas and liquid phase balances verifying carbon conservation enables a very accurate determination of the kLCO value as a main limiting step of the whole process. Nevertheless, further experiments are still needed to demonstrate that the proposed method could serve in the future as reference method for mass transfer coefficient determination if using membrane modules for BLSS in reduced or microgravity conditions.

  1. Conjugated heat transfer and temperature distributions in a gas turbine combustion liner under base-load operation

    International Nuclear Information System (INIS)

    Kim, Kyung Min; Yun, Nam Geon; Jeon, Yun Heung; Lee, Dong Hyun; Cho, Yung Hee

    2010-01-01

    Prediction of temperature distributions on hot components is important in development of a gas turbine combustion liner. The present study investigated conjugated heat transfer to obtain temperature distributions in a combustion liner with six combustion nozzles. 3D numerical simulations using FVM commercial codes, Fluent and CFX were performed to calculate combustion and heat transfer distributions. The temperature distributions in the combustor liner were calculated by conjugation of conduction and convection (heat transfer coefficients) obtained by combustion and cooling flow analysis. The wall temperature was the highest on the attachment points of the combustion gas from combustion nozzles, but the temperature gradient was high at the after shell section with low wall temperature

  2. Comparison Study on Empirical Correlation for Mass Transfer Coefficient with Gas Hold-up and Input Power of Aeration Process

    Energy Technology Data Exchange (ETDEWEB)

    Park, Sang Kyoo; Yang, Hei Cheon [Chonnam Nat’l Univ., Gwangju (Korea, Republic of)

    2017-06-15

    As stricter environmental regulation have led to an increase in the water treatment cost, it is necessary to quantitatively study the input power of the aeration process to improve the energy efficiency of the water treatment processes. The objective of this study is to propose the empirical correlations for the mass transfer coefficient with the gas hold-up and input power in order to investigate the mass transfer characteristics of the aeration process. It was found that as the input power increases, the mass transfer coefficient increases because of the decrease of gas hold-up and increase of Reynolds number, the penetration length, and dispersion of mixed flow. The correlations for the volumetric mass transfer coefficients with gas hold-up and input power were consistent with the experimental data, with the maximum deviation less than approximately ±10.0%.

  3. A two-dimensional position sensitive gas chamber with scanned charge transfer readout

    Energy Technology Data Exchange (ETDEWEB)

    Gomez, F. E-mail: faustgr@usc.es; Iglesias, A.; Lobato, R.; Mosquera, J.; Pardo, J.; Pena, J.; Pazos, A.; Pombar, M.; Rodriguez, A

    2003-10-21

    We have constructed and tested a two-dimensional position sensitive parallel-plate gas ionization chamber with scanned charge transfer readout. The scan readout method described here is based on the development of a new position-dependent charge transfer technique. It has been implemented by using gate strips perpendicularly oriented to the collector strips. This solution reduces considerably the number of electronic readout channels needed to cover large detector areas. The use of a 25 {mu}m thick kapton etched circuit allows high charge transfer efficiency with a low gating voltage, consequently needing a very simple commutating circuit. The present prototype covers 8x8 cm{sup 2} with a pixel size of 1.27x1.27 mm{sup 2}. Depending on the intended use and beam characteristics a smaller effective pixel is feasible and larger active areas are possible. This detector can be used for X-ray or other continuous beam intensity profile monitoring.

  4. Contribution of heat transfer to turbine blades and vanes for high temperature industrial gas turbines. Part 2: Heat transfer on serpentine flow passage.

    Science.gov (United States)

    Takeishi, K; Aoki, S

    2001-05-01

    The improvement of the heat transfer coefficient of the 1st row blades in high temperature industrial gas turbines is one of the most important issues to ensure reliable performance of these components and to attain high thermal efficiency of the facility. This paper deals with the contribution of heat transfer to increase the turbine inlet temperature of such gas turbines in order to attain efficient and environmentally benign engines. Following the experiments described in Part 1, a set of trials was conducted to clarify the influence of the blade's rotating motion on the heat transfer coefficient for internal serpentine flow passages with turbulence promoters. Test results are shown and discussed in this second part of the contribution.

  5. Optimization techniques for the secondary development of old gas fields in the Sichuan Basin and their application

    Directory of Open Access Journals (Sweden)

    Chongshuang Xia

    2016-12-01

    Full Text Available After nearly 60 years of development, many old gas fields in the Sichuan Basin have come to middle–late development stages with low pressure and low yield, and some are even on the verge of abandonment, but there are plenty remaining gas resources still undeveloped. Analysis shows that gas fields which have the conditions for the secondary development are faced with many difficulties. For example, it is difficult to produce low permeable reserves and to unset the hydraulic seal which is formed by active formation water. In this paper, therefore, the technical route and selection conditions of old gas fields for the secondary development were comprehensively elaborated with its definition as the beginning. Firstly, geological model forward modeling and production performance inversion characteristic curve diagnosis are performed by using the pressure normalization curve and the identification and quantitative description method for multiple sets of storage–seepage body of complex karst fracture–cavity systems is put forward, after the multiple storage–seepage body mode of fracture–cavity systems is established. Combined with the new occurrence mode of gas and water in U-shape pipes, a new calculation technology for natural gas reserves of multiple fracture–cavity systems with strong water invasion is developed. Secondly, a numerical model of pore–cavity–fracture triple media is built, and simulation and result evaluation technology for the production pattern of “drainage by horizontal wells + gas production by vertical wells” in bottom-water fracture and cavity gas reservoirs with strong water invasion is developed. Thirdly, the geological model of gas reservoirs is reconstructed with the support of the integration technologies which are formed based on fine gas reservoir description. Low permeable reserves of gas reservoirs are evaluated based on each classification. The effective producing ratio is increased further by

  6. Heat transfer to immersed horizontal tubes in gas fluidized bed dryers

    Energy Technology Data Exchange (ETDEWEB)

    Jonassen, Ola

    1999-10-01

    The main objective of this study was to construct heat pump fluidized bed dryers of the FHT type with improved dewatering capacity for a given size of the dryer. The use of heat exchangers immersed in the fluidized bed drying chambers is an important part of the FHT (Fluidized Bed High Temperature Heat Pump Dryer) concept. A pilot plant FHT dryer was built and successfully tested on fish meal raw material and seaweed. The plant included two fluidized bed drying chambers with immersed heat exchangers. The gain in water vapor of the drying air through the chambers was increased up to four times that of adiabatic drying. The energy saving concept was retained as a SMER ratio of 3.5 to 4.7 was measured in the same tests. Therefore optimization of the immersed heat exchangers was considered the most important single objective for this work. The optimization study of the heat exchangers was confined to the actual operating conditions for the dryers using: (1) Bubbling gas fluidized beds were used, (2) air as the only type of fluidising gas, (3) beds at atmospheric pressure, (4) bed temperatures below 100 {sup o}C, (5) fluidized particles of Geldart classes B and D, (6) horizontal tube banks for the immersed heat exchanger, and the influence of radiation heat transfer was ignored. The heat transfer study was confined to the fluidized bed side of the heat exchanger surface. It was concluded early in this work that the bubbles play a major role in generating the particle circulation inside the bed and hence also in heat transfer. Publications describing the most important bubble induced mechanisms contributing to high rates of heat transfer were found to be limited. Therefore the first part of this study was aimed at establishing a method for locating and measuring the size and rise velocity of bubbles inside the bed. The method established through this work using differential pressure measurements from two static pressure probes was used later in the study of heat transfer

  7. Heat transfer to immersed horizontal tubes in gas fluidized bed dryers

    Energy Technology Data Exchange (ETDEWEB)

    Jonassen, Ola

    1999-07-01

    The main objective of this study was to construct heat pump fluidized bed dryers of the FHT type with improved dewatering capacity for a given size of the dryer. The use of heat exchangers immersed in the fluidized bed drying chambers is an important part of the FHT (Fluidized Bed High Temperature Heat Pump Dryer) concept. A pilot plant FHT dryer was built and successfully tested on fish meal raw material and seaweed. The plant included two fluidized bed drying chambers with immersed heat exchangers. The gain in water vapor of the drying air through the chambers was increased up to four times that of adiabatic drying. The energy saving concept was retained as a SMER ratio of 3.5 to 4.7 was measured in the same tests. Therefore optimization of the immersed heat exchangers was considered the most important single objective for this work. The optimization study of the heat exchangers was confined to the actual operating conditions for the dryers using: (1) Bubbling gas fluidized beds were used, (2) air as the only type of fluidizing gas,(3) beds at atmospheric pressure, (4) bed temperatures below 100 {sup o}C, (5) fluidized particles of Geldart classes B and D, (6) horizontal tube banks for the immersed heat exchanger and the influence of radiation heat transfer was ignored. The heat transfer study was confined to the fluidized bed side of the heat exchanger surface. It was concluded early in this work that the bubbles play a major role in generating the particle circulation inside the bed and hence also in heat transfer. Publications describing the most important bubble induced mechanisms contributing to high rates of heat transfer were found to be limited. Therefore the first part of this study was aimed at establishing a method for locating and measuring the size and rise velocity of bubbles inside the bed. The method established through this work using differential pressure measurements from two static pressure probes was used later in the study of heat transfer

  8. Study of the influence of surfactants on the transfer of gases into liquids by inverse gas chromatography.

    Science.gov (United States)

    Atta, Khan Rashid; Gavril, Dimitrios; Loukopoulos, Vassilios; Karaiskakis, George

    2004-01-16

    The experimental technique of the reversed-flow version of inverse gas chromatography was applied for the study of effects of surfactants in reducing air-water exchange rates. The vinyl chloride (VC)-water system was used as a model, which is of great importance in environmental chemistry. Using suitable mathematical analysis, various physicochemical quantities were calculated, among which the most significant are: Partition coefficients of the VC gas between the surfactant interface and the carrier gas nitrogen, as well as between the bulk of the water + surfactant solution and the carrier gas nitrogen, overall mass transfer coefficients of VC in the liquid (water + surfactant) and the gas (nitrogen) phases, water and surfactant film transfer coefficients, nitrogen, water and surfactant phase resistances for the transfer of VC into the water solution, relative resistance of surfactant in the transfer of VC into the bulk of solution, exchange velocity of VC between nitrogen and the liquid solution, and finally the thickness of the surfactant stagnant film in the liquid phase, according to the three phase resistance model. From the variation of the above parameters with the surfactant's concentration, important conclusions concerning the effects of surfactants on the transfer of a gas at the air-liquid interface, as well as to the bulk of the liquid were extracted. An interesting finding of this work was also that by successive addition of surfactant, the critical micelle concentration of surfactant was obtained, after which follows a steady-state for the transfer of the gas into the water body, which could be attributed to the transition from mono- to multi-layer state.

  9. Pulsatile flow and mass transport over an array of cylinders: gas transfer in a cardiac-driven artificial lung.

    Science.gov (United States)

    Chan, Kit Yan; Fujioka, Hideki; Bartlett, Robert H; Hirschl, Ronald B; Grotberg, James B

    2006-02-01

    The pulsatile flow and gas transport of a Newtonian passive fluid across an array of cylindrical microfibers are numerically investigated. It is related to an implantable, artificial lung where the blood flow is driven by the right heart. The fibers are modeled as either squared or staggered arrays. The pulsatile flow inputs considered in this study are a steady flow with a sinusoidal perturbation and a cardiac flow. The aims of this study are twofold: identifying favorable array geometry/spacing and system conditions that enhance gas transport; and providing pressure drop data that indicate the degree of flow resistance or the demand on the right heart in driving the flow through the fiber bundle. The results show that pulsatile flow improves the gas transfer to the fluid compared to steady flow. The degree of enhancement is found to be significant when the oscillation frequency is large, when the void fraction of the fiber bundle is decreased, and when the Reynolds number is increased; the use of a cardiac flow input can also improve gas transfer. In terms of array geometry, the staggered array gives both a better gas transfer per fiber (for relatively large void fraction) and a smaller pressure drop (for all cases). For most cases shown, an increase in gas transfer is accompanied by a higher pressure drop required to power the flow through the device.

  10. Comparison of primary and secondary particle formation from natural gas engine exhaust and of their volatility characteristics

    Directory of Open Access Journals (Sweden)

    J. Alanen

    2017-07-01

    Full Text Available Natural gas usage in the traffic and energy production sectors is a growing trend worldwide; thus, an assessment of its effects on air quality, human health and climate is required. Engine exhaust is a source of primary particulate emissions and secondary aerosol precursors, which both contribute to air quality and can cause adverse health effects. Technologies, such as cleaner engines or fuels, that produce less primary and secondary aerosols could potentially significantly decrease atmospheric particle concentrations and their adverse effects. In this study, we used a potential aerosol mass (PAM chamber to investigate the secondary aerosol formation potential of natural gas engine exhaust. The PAM chamber was used with a constant UV-light voltage, which resulted in relatively long equivalent atmospheric ages of 11 days at most. The studied retro-fitted natural gas engine exhaust was observed to form secondary aerosol. The mass of the total aged particles, i.e., particle mass measured downstream of the PAM chamber, was 6–268 times as high as the mass of the emitted primary exhaust particles. The secondary organic aerosol (SOA formation potential was measured to be 9–20 mg kgfuel−1. The total aged particles mainly consisted of organic matter, nitrate, sulfate and ammonium, with the fractions depending on exhaust after-treatment and the engine parameters used. Also, the volatility, composition and concentration of the total aged particles were found to depend on the engine operating mode, catalyst temperature and catalyst type. For example, a high catalyst temperature promoted the formation of sulfate particles, whereas a low catalyst temperature promoted nitrate formation. However, in particular, the concentration of nitrate needed a long time to stabilize – more than half an hour – which complicated the conclusions but also indicates the sensitivity of nitrate measurements on experimental parameters such as emission

  11. Wind Speed and Sea State Dependencies of Air-Sea Gas Transfer: Results From the High Wind Speed Gas Exchange Study (HiWinGS)

    Science.gov (United States)

    Blomquist, B. W.; Brumer, S. E.; Fairall, C. W.; Huebert, B. J.; Zappa, C. J.; Brooks, I. M.; Yang, M.; Bariteau, L.; Prytherch, J.; Hare, J. E.; Czerski, H.; Matei, A.; Pascal, R. W.

    2017-10-01

    A variety of physical mechanisms are jointly responsible for facilitating air-sea gas transfer through turbulent processes at the atmosphere-ocean interface. The nature and relative importance of these mechanisms evolves with increasing wind speed. Theoretical and modeling approaches are advancing, but the limited quantity of observational data at high wind speeds hinders the assessment of these efforts. The HiWinGS project successfully measured gas transfer coefficients (k660) with coincident wave statistics under conditions with hourly mean wind speeds up to 24 m s-1 and significant wave heights to 8 m. Measurements of k660 for carbon dioxide (CO2) and dimethylsulfide (DMS) show an increasing trend with respect to 10 m neutral wind speed (U10N), following a power law relationship of the form: k660 CO2˜U10N1.68 and k660 dms˜U10N1.33. Among seven high wind speed events, CO2 transfer responded to the intensity of wave breaking, which depended on both wind speed and sea state in a complex manner, with k660 CO2 increasing as the wind sea approaches full development. A similar response is not observed for DMS. These results confirm the importance of breaking waves and bubble injection mechanisms in facilitating CO2 transfer. A modified version of the Coupled Ocean-Atmosphere Response Experiment Gas transfer algorithm (COAREG ver. 3.5), incorporating a sea state-dependent calculation of bubble-mediated transfer, successfully reproduces the mean trend in observed k660 with wind speed for both gases. Significant suppression of gas transfer by large waves was not observed during HiWinGS, in contrast to results from two prior field programs.

  12. Formation of secondary organic aerosols from gas-phase emissions of heated cooking oils

    Science.gov (United States)

    Liu, Tengyu; Li, Zijun; Chan, ManNin; Chan, Chak K.

    2017-06-01

    Cooking emissions can potentially contribute to secondary organic aerosol (SOA) but remain poorly understood. In this study, formation of SOA from gas-phase emissions of five heated vegetable oils (i.e., corn, canola, sunflower, peanut and olive oils) was investigated in a potential aerosol mass (PAM) chamber. Experiments were conducted at 19-20 °C and 65-70 % relative humidity (RH). The characterization instruments included a scanning mobility particle sizer (SMPS) and a high-resolution time-of-flight aerosol mass spectrometer (HR-TOF-AMS). The efficiency of SOA production, in ascending order, was peanut oil, olive oil, canola oil, corn oil and sunflower oil. The major SOA precursors from heated cooking oils were related to the content of monounsaturated fat and omega-6 fatty acids in cooking oils. The average production rate of SOA, after aging at an OH exposure of 1. 7 × 1011 molecules cm-3 s, was 1. 35 ± 0. 30 µg min-1, 3 orders of magnitude lower compared with emission rates of fine particulate matter (PM2. 5) from heated cooking oils in previous studies. The mass spectra of cooking SOA highly resemble field-derived COA (cooking-related organic aerosol) in ambient air, with R2 ranging from 0.74 to 0.88. The average carbon oxidation state (OSc) of SOA was -1.51 to -0.81, falling in the range between ambient hydrocarbon-like organic aerosol (HOA) and semi-volatile oxygenated organic aerosol (SV-OOA), indicating that SOA in these experiments was lightly oxidized.

  13. Formation of secondary organic aerosols from gas-phase emissions of heated cooking oils

    Directory of Open Access Journals (Sweden)

    T. Liu

    2017-06-01

    Full Text Available Cooking emissions can potentially contribute to secondary organic aerosol (SOA but remain poorly understood. In this study, formation of SOA from gas-phase emissions of five heated vegetable oils (i.e., corn, canola, sunflower, peanut and olive oils was investigated in a potential aerosol mass (PAM chamber. Experiments were conducted at 19–20 °C and 65–70 % relative humidity (RH. The characterization instruments included a scanning mobility particle sizer (SMPS and a high-resolution time-of-flight aerosol mass spectrometer (HR-TOF-AMS. The efficiency of SOA production, in ascending order, was peanut oil, olive oil, canola oil, corn oil and sunflower oil. The major SOA precursors from heated cooking oils were related to the content of monounsaturated fat and omega-6 fatty acids in cooking oils. The average production rate of SOA, after aging at an OH exposure of 1. 7 × 1011 molecules cm−3 s, was 1. 35 ± 0. 30 µg min−1, 3 orders of magnitude lower compared with emission rates of fine particulate matter (PM2. 5 from heated cooking oils in previous studies. The mass spectra of cooking SOA highly resemble field-derived COA (cooking-related organic aerosol in ambient air, with R2 ranging from 0.74 to 0.88. The average carbon oxidation state (OSc of SOA was −1.51 to −0.81, falling in the range between ambient hydrocarbon-like organic aerosol (HOA and semi-volatile oxygenated organic aerosol (SV-OOA, indicating that SOA in these experiments was lightly oxidized.

  14. Carbon isotope evidence for the latitudinal distribution and wind speed dependence of the air-sea gas transfer velocity

    International Nuclear Information System (INIS)

    Krakauer, Nir Y.

    2006-01-01

    The air-sea gas transfer velocity is an important determinant of the exchange of gases, including CO 2 , between the atmosphere and ocean, but the magnitude of the transfer velocity and what factors control it remains poorly known. Here, we use oceanic and atmospheric observations of 14 C and 13 C to constrain the global mean gas transfer velocity as well as the exponent of its wind speed dependence, utilizing the distinct signatures left by the air-sea exchange of 14 CO 2 and 13 CO 2 . While the atmosphere and ocean inventories of 14 CO 2 and 13 CO 2 constrain the mean gas transfer velocity, the latitudinal pattern in the atmospheric and oceanic 14 C and 13 C distributions contain information about the wind speed dependence. We computed the uptake of bomb 14 C by the ocean for different transfer velocity patterns using pulse response functions from an ocean general circulation model, and evaluated the match between the predicted bomb 14 C concentrations and observationally based estimates for the 1970s-1990s. Using a wind speed climatology based on satellite measurements, we solved either for the best-fit global relationship between gas exchange and mean wind speed or for the mean gas transfer velocity over each of 11 ocean regions. We also compared the predicted consequences of different gas exchange relationships on the rate of change and interhemisphere gradient of 14 C in atmospheric CO 2 with tree-ring and atmospheric measurements. Our results suggest that globally, the dependence of the air-sea gas transfer velocity on wind speed is close to linear, with an exponent of 0.5 ± 0.4, and that the global mean gas transfer velocity at a Schmidt number of 660 is 20 ± 3 cm/hr, similar to the results of previous analyses. We find that the air-sea flux of 13 C estimated from atmosphere and ocean observations also suggests a lower than quadratic dependence of gas exchange on wind speed

  15. Gas-liquid mass transfer and flow phenomena in the Peirce-Smith converter: a water model study

    Science.gov (United States)

    Zhao, Xing; Zhao, Hong-liang; Zhang, Li-feng; Yang, Li-qiang

    2018-01-01

    A water model with a geometric similarity ratio of 1:5 was developed to investigate the gas-liquid mass transfer and flow characteristics in a Peirce-Smith converter. A gas mixture of CO2 and Ar was injected into a NaOH solution bath. The flow field, volumetric mass transfer coefficient per unit volume ( Ak/V; where A is the contact area between phases, V is the volume, and k is the mass transfer coefficient), and gas utilization ratio ( η) were then measured at different gas flow rates and blow angles. The results showed that the flow field could be divided into five regions, i.e., injection, strong loop, weak loop, splashing, and dead zone. Whereas the Ak/V of the bath increased and then decreased with increasing gas flow rate, and η steadily increased. When the converter was rotated clockwise, both Ak/V and η increased. However, the flow condition deteriorated when the gas flow rate and blow angle were drastically increased. Therefore, these parameters must be controlled to optimal conditions. In the proposed model, the optimal gas flow rate and blow angle were 7.5 m3·h-1 and 10°, respectively.

  16. TECHNOLOGY TRANSFER TO U.S. INDEPENDENT OIL AND NATURAL GAS PRODUCERS

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    2002-11-01

    The Petroleum Technology Transfer Council (PTTC) continued pursuing its mission of assisting U.S. independent oil and gas producers make timely, informed technology decisions by providing access to information during Fiscal Year 2002 (FY02). Functioning as a cohesive national organization, PTTC has active grassroots programs through its ten Regional Lead Organizations (RLOs) and three satellite offices that efficiently extend the program reach. They bring research and academia to the table via their association with geological surveys and engineering departments. The regional directors interact with independent oil and gas producers through technology workshops, resource centers, websites, newsletters, various technical publications and other outreach efforts. These are guided by regional Producer Advisory Groups (PAGs), who are area operators and service companies working with the regional networks. The role of the national Headquarters (HQ) staff includes planning and managing the PTTC program, conducting nation wide technology transfer activities, and implementing a comprehensive communications effort. The organization effectively combines federal funding through the Department of Energy's (DOE) Office of Fossil Energy with state and industry funding to achieve important goals for all of these sectors. This integrated funding base is combined with industry volunteers guiding PTTC's activities and the dedication of national and regional staff to achieve notable results. PTTC is increasingly recognized as a critical resource for information and access to technologies, especially for smaller companies without direct contact with R&D efforts. The DOE participation is managed through the National Energy Technology Laboratory (NETL), which deploys a national natural gas program via the Strategic Center for Natural Gas (SCNG) and a national oil program through the National Petroleum Technology Office (NTPO). This technical progress report summarizes PTTC

  17. Natural gas large volumes measurement: going for on-line custody transfer; Medicao de grandes volumes de gas natural: rumo a transferencia de custodia on-line

    Energy Technology Data Exchange (ETDEWEB)

    Mercon, Eduardo G.; Frisoli, Caetano [PETROBRAS Transporte S.A. (TRANSPETRO), Rio de Janeiro, RJ (Brazil)

    2005-07-01

    This paper describes the structure of the natural gas flow measurement process in TRANSPETRO, and comments features and performance of existing or under-implantation equipment and systems, reviewing best practices and technology in use. This process runs through three interrelated segments: data flow measurement, strictly speaking; data transfer and acquisition; and data flow measurement certification (data consolidation to invoice). Initially, the work makes an approach to the data flow measurement segment, evaluating technical features of flow meters, and describing configurations and functions of the operating gas flow computers in TRANSPETRO's custody transfer stations. In this part it will also be presented the implantation of TRANSPETRO's system for gas chromatography data input on-line to flow computers. Further, in data transfer and acquisition, SCADA system technical aspects will be evaluated, considering communications protocols and programmable logic controllers functions in remote terminal units, and discussing their places in the measurement process. Additionally, TRANSPETRO's experience in data measurement certification tools is in discussion, as well as new upcoming tools and their potential features, from what new practices will be suggested. Finally, all the work has been conceived and carried out always aiming to the state-of-the-art technology in gas flow measurement: on-line custody transfer. (author)

  18. A gas dynamics scheme for a two moments model of radiative transfer

    International Nuclear Information System (INIS)

    Buet, Ch.; Despres, B.

    2007-01-01

    We address the discretization of the Levermore's two moments and entropy model of the radiative transfer equation. We present a new approach for the discretization of this model: first we rewrite the moment equations as a Compressible Gas Dynamics equation by introducing an additional quantity that plays the role of a density. After that we discretize using a Lagrange-projection scheme. The Lagrange-projection scheme permits us to incorporate the source terms in the fluxes of an acoustic solver in the Lagrange step, using the well-known piecewise steady approximation and thus to capture correctly the diffusion regime. Moreover we show that the discretization is entropic and preserve the flux-limited property of the moment model. Numerical examples illustrate the feasibility of our approach. (authors)

  19. Numerical computations of fluid flow and heat transfer in a gas-stirred liquid bath

    Science.gov (United States)

    Türkoğlu, Haşmet; Farouk, Bakhtier

    1990-08-01

    The flow and temperature fields due to bottom air injection in a cylindrical vessel containing water were numerically analyzed. The Eulerian approach was used for the formulation of both the continuous and the dispersed phases. The computational domain was extended beyond the undisturbed height of the liquid in the bath to accommodate practical gas injection systems. Turbulence in the liquid phase was modeled using a two-equation k- ɛ model. Interphase friction and heat transfer coefficients were calculated by using correlations available in the literature. The general-purpose computer program PHOENICS was employed to predict the velocity, vol-ume fraction, and the temperature fields of each phase. Turbulent dispersion of the phases was modeled by introducing a “dispersion Prandtl number.” The predicted flow fields were com-pared with experimental measurements available in the literature. The results are of interest in the design and operation of a wide variety of material processing operations.

  20. TECHNOLOGY TRANSFER TO U.S. INDEPENDENT OIL AND NATURAL GAS PRODUCERS

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    2001-05-01

    The Petroleum Technology Transfer Council (PTTC) continued pursuing its mission of helping U.S. independent oil and natural gas producers make timely, informed technology decisions. PTTC's Board made a strategic decision to relocate the Headquarters (HQ) office from Washington, DC to Houston, Texas. Driving force behind relocation was to better connect with independent producers, but cost savings could also be realized. Relocation was accomplished in late December 2000, with the HQ office being fully operational by January 2001. Early indications are that the HQ relocation is, in fact, enabling better networking with senior executives of independents in the Houston oil community. New Board leadership, elected in March 2001, will continue to effectively guide PTTC.

  1. Proposal for data acquisition system of gas chromatograph and natural gas transfer custody via web; Proposta para um sistema de aquisicao de dados de cromatografia e medicao fiscal de gas natural via web

    Energy Technology Data Exchange (ETDEWEB)

    Santana, Jose Paulo C.; Guimaraes, Marcelo F.; Zeitoune, Rafael J. [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2005-07-01

    In this paper, is presented a proposal of a Chromatograph and Transfer Custody Measurement Data Acquisition System through Web, complementary to the SCADA System, responsible for control and monitoring PETROBRAS Gas Pipelines, intended to comply with the requirements of the Gerencias de Qualidade e Medicao (MQD) and Planejamento Integrado da Logistica (PCL) from PETROBRAS Gas e Energia, regarding the evaluation of the quality of the natural gas that is being commercialized, as well as its billing. (author)

  2. A numerical scheme to calculate temperature and salinity dependent air-water transfer velocities for any gas

    Science.gov (United States)

    Johnson, M. T.

    2010-10-01

    The ocean-atmosphere flux of a gas can be calculated from its measured or estimated concentration gradient across the air-sea interface and the transfer velocity (a term representing the conductivity of the layers either side of the interface with respect to the gas of interest). Traditionally the transfer velocity has been estimated from empirical relationships with wind speed, and then scaled by the Schmidt number of the gas being transferred. Complex, physically based models of transfer velocity (based on more physical forcings than wind speed alone), such as the NOAA COARE algorithm, have more recently been applied to well-studied gases such as carbon dioxide and DMS (although many studies still use the simpler approach for these gases), but there is a lack of validation of such schemes for other, more poorly studied gases. The aim of this paper is to provide a flexible numerical scheme which will allow the estimation of transfer velocity for any gas as a function of wind speed, temperature and salinity, given data on the solubility and liquid molar volume of the particular gas. New and existing parameterizations (including a novel empirical parameterization of the salinity-dependence of Henry's law solubility) are brought together into a scheme implemented as a modular, extensible program in the R computing environment which is available in the supplementary online material accompanying this paper; along with input files containing solubility and structural data for ~90 gases of general interest, enabling the calculation of their total transfer velocities and component parameters. Comparison of the scheme presented here with alternative schemes and methods for calculating air-sea flux parameters shows good agreement in general. It is intended that the various components of this numerical scheme should be applied only in the absence of experimental data providing robust values for parameters for a particular gas of interest.

  3. A numerical scheme to calculate temperature and salinity dependent air-water transfer velocities for any gas

    Directory of Open Access Journals (Sweden)

    M. T. Johnson

    2010-10-01

    Full Text Available The ocean-atmosphere flux of a gas can be calculated from its measured or estimated concentration gradient across the air-sea interface and the transfer velocity (a term representing the conductivity of the layers either side of the interface with respect to the gas of interest. Traditionally the transfer velocity has been estimated from empirical relationships with wind speed, and then scaled by the Schmidt number of the gas being transferred. Complex, physically based models of transfer velocity (based on more physical forcings than wind speed alone, such as the NOAA COARE algorithm, have more recently been applied to well-studied gases such as carbon dioxide and DMS (although many studies still use the simpler approach for these gases, but there is a lack of validation of such schemes for other, more poorly studied gases. The aim of this paper is to provide a flexible numerical scheme which will allow the estimation of transfer velocity for any gas as a function of wind speed, temperature and salinity, given data on the solubility and liquid molar volume of the particular gas. New and existing parameterizations (including a novel empirical parameterization of the salinity-dependence of Henry's law solubility are brought together into a scheme implemented as a modular, extensible program in the R computing environment which is available in the supplementary online material accompanying this paper; along with input files containing solubility and structural data for ~90 gases of general interest, enabling the calculation of their total transfer velocities and component parameters. Comparison of the scheme presented here with alternative schemes and methods for calculating air-sea flux parameters shows good agreement in general. It is intended that the various components of this numerical scheme should be applied only in the absence of experimental data providing robust values for parameters for a particular gas of interest.

  4. The Application of Discontinuous Galerkin Methods in Conjugate Heat Transfer Simulations of Gas Turbines

    Directory of Open Access Journals (Sweden)

    Zeng-Rong Hao

    2014-11-01

    Full Text Available The performance of modern heavy-duty gas turbines is greatly determined by the accurate numerical predictions of thermal loading on the hot-end components. The purpose of this paper is: (1 to present an approach applying a novel numerical technique—the discontinuous Galerkin (DG method—to conjugate heat transfer (CHT simulations, develop the engineering-oriented numerical platform, and validate the feasibility of the methodology and tool preliminarily; and (2 to utilize the constructed platform to investigate the aerothermodynamic features of a typical transonic turbine vane with convection cooling. Fluid dynamic and solid heat conductive equations are discretized into explicit DG formulations. A centroid-expanded Taylor basis is adopted for various types of elements. The Bassi-Rebay method is used in the computation of gradients. A coupled strategy based on a data exchange process via numerical flux on interface quadrature points is simply devised. Additionally, various turbulence Reynolds-Averaged-Navier-Stokes (RANS models and the local-variable-based transition model γ-Reθ are assimilated into the integral framework, combining sophisticated modelling with the innovative algorithm. Numerical tests exhibit good consistency between computational and analytical or experimental results, demonstrating that the presented approach and tool can handle well general CHT simulations. Application and analysis in the turbine vane, focusing on features around where there in cluster exist shock, separation and transition, illustrate the effects of Bradshaw’s shear stress limitation and separation-induced-transition modelling. The general overestimation of heat transfer intensity behind shock is conjectured to be associated with compressibility effects on transition modeling. This work presents an unconventional formulation in CHT problems and achieves its engineering applications in gas turbines.

  5. TECHNOLOGY TRANSFER TO U.S. INDEPENDENT OIL AND NATURAL GAS PRODUCERS

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    2000-11-01

    The Petroleum Technology Transfer Council (PTTC) continued pursuing its mission of helping U.S. independent oil and gas producers make timely, informed technology decisions during Fiscal Year 2000 (FY00). Functioning as a cohesive national organization, PTTC has active grassroots programs through its ten Regional Lead Organizations (RLOs) who bring research and academia to the table via their association with geological surveys and engineering departments. The regional directors connect with independent oil and gas producers through technology workshops, resource centers, websites, newsletters, various technical publications and other outreach efforts. These are guided by regional Producer Advisory Groups (PAGs), who are area operators and service companies working with the Regional Lead Organizations. The role of the national headquarters (HQ) staff includes planning and managing the PTTC program, conducting nation-wide technology transfer activities, and implementing a comprehensive communications effort. The organization effectively combines federal, state, and industry funding to achieve important goals for all of these sectors. This integrated funding base, combined with industry volunteers guiding PTTC's activities and the dedication of national and regional staff, are achieving notable results. PTTC is increasingly recognized as a critical resource for information and access to technologies, especially for smaller companies. This technical progress report summarizes PTTC's accomplishments during FY00, which lays the groundwork for further growth in the future. At a time of many industry changes and market movements, the organization has built a reputation and expectation to address industry needs of getting information distributed quickly which can impact the bottom line immediately.

  6. TECHNOLOGY TRANSFER TO U.S. INDEPENDENT OIL AND NATURAL GAS PRODUCERS

    Energy Technology Data Exchange (ETDEWEB)

    Donald Duttlinger

    2001-11-01

    The Petroleum Technology Transfer Council (PTTC) continued pursuing its mission of helping U.S. independent oil and gas producers make timely, informed technology decisions during Fiscal Year 2001 (FY01). Functioning as a cohesive national organization, PTTC has active grassroots programs through its ten Regional Lead Organizations (RLOs). They bring research and academia to the table via their association with geological surveys and engineering departments. The regional directors interact with independent oil and gas producers through technology workshops, resource centers, websites, newsletters, various technical publications and other outreach efforts. These are guided by regional Producer Advisory Groups (PAGs), who are area operators and service companies working with the regional networks. The role of the national Headquarters (HQ) staff includes planning and managing the PTTC program, conducting nation wide technology transfer activities, and implementing a comprehensive communications effort. The organization effectively combines federal funding through the Department of Energy's (DOE) Office of Fossil Energy, state, and industry funding to achieve important goals for all of these sectors. This integrated funding base, combined with industry volunteers guiding PTTC's activities and the dedication of national and regional staff, are achieving notable results. PTTC is increasingly recognized as a critical resource for information and access to technologies, especially for smaller companies without direct contact to R&D efforts. This technical progress report summarizes PTTC's accomplishments during FY01, which lays the groundwork for further growth in the future. At a time of many industry changes and wide market movements, the organization itself is adapting to change. PTTC has built a reputation and expectation among producers and other industry participants to quickly distribute information addressing technical needs. The organization

  7. Analytical linear energy transfer model including secondary particles: calculations along the central axis of the proton pencil beam

    International Nuclear Information System (INIS)

    Marsolat, F; De Marzi, L; Mazal, A; Pouzoulet, F

    2016-01-01

    In proton therapy, the relative biological effectiveness (RBE) depends on various types of parameters such as linear energy transfer (LET). An analytical model for LET calculation exists (Wilkens’ model), but secondary particles are not included in this model. In the present study, we propose a correction factor, L sec , for Wilkens’ model in order to take into account the LET contributions of certain secondary particles. This study includes secondary protons and deuterons, since the effects of these two types of particles can be described by the same RBE-LET relationship. L sec was evaluated by Monte Carlo (MC) simulations using the GATE/GEANT4 platform and was defined by the ratio of the LET d distributions of all protons and deuterons and only primary protons. This method was applied to the innovative Pencil Beam Scanning (PBS) delivery systems and L sec was evaluated along the beam axis. This correction factor indicates the high contribution of secondary particles in the entrance region, with L sec values higher than 1.6 for a 220 MeV clinical pencil beam. MC simulations showed the impact of pencil beam parameters, such as mean initial energy, spot size, and depth in water, on L sec . The variation of L sec with these different parameters was integrated in a polynomial function of the L sec factor in order to obtain a model universally applicable to all PBS delivery systems. The validity of this correction factor applied to Wilkens’ model was verified along the beam axis of various pencil beams in comparison with MC simulations. A good agreement was obtained between the corrected analytical model and the MC calculations, with mean-LET deviations along the beam axis less than 0.05 keV μm −1 . These results demonstrate the efficacy of our new correction of the existing LET model in order to take into account secondary protons and deuterons along the pencil beam axis. (paper)

  8. Magnetic Emissions Reduction by Varying Secondary Side Capacitor for Ferrite Geometry based Series-Parallel Topology Wireless Power Transfer to Vehicles

    DEFF Research Database (Denmark)

    Batra, Tushar; Schaltz, Erik

    2014-01-01

    Magnetic fields in surroundings of wireless power transfer system depends upon the two coil currents, distance from the coils and space angle between the two coil fields in steady state conditions. Increase in value of the secondary capacitor leads to a phase shift between the two currents...... of series-parallel topology wireless power transfer to vehicles without compromising with the power transfer capability of the system....

  9. Contribution of heat transfer to turbine blades and vanes for high temperature industrial gas turbines. Part 1: Film cooling.

    Science.gov (United States)

    Takeishi, K; Aoki, S

    2001-05-01

    This paper deals with the contribution of heat transfer to increase the turbine inlet temperature of industrial gas turbines in order to attain efficient and environmentally benign engines. High efficiency film cooling, in the form of shaped film cooling and full coverage film cooling, is one of the most important cooling technologies. Corresponding heat transfer tests to optimize the film cooling effectiveness are shown and discussed in this first part of the contribution.

  10. Effect of wall thermal conductivity on the heat transfer process in annular turbulent gas flow for constant wall temperature

    International Nuclear Information System (INIS)

    Groshev, A.I.; Anisimov, V.V.; Kashcheev, V.M.; Khudasko, V.V.; Yur'ev, Yu.S.

    1987-01-01

    The effect of wall material on convective heat transfer of turbulent gas flow in an annular tube with account of longitudinal diffusion both in the wall and in the liquid is studied numerically. The conjugated problem is solved for P r =0.7 (Re=10 4 -10 6 ). Based on numerical calculations it is stated that thermal conductivity of the wall and gas essentially affects the degree of preliminary heating of liquid in the range of a non-heated section

  11. Effect of carrier gas composition on transferred arc metal nanoparticle synthesis

    International Nuclear Information System (INIS)

    Stein, Matthias; Kiesler, Dennis; Kruis, Frank Einar

    2013-01-01

    Metal nanoparticles are used in a great number of applications; an effective and economical production scaling-up is hence desirable. A simple and cost-effective transferred arc process is developed, which produces pure metal (Zn, Cu, and Ag) nanoparticles with high production rates, while allowing fast optimization based on energy efficiency. Different carrier gas compositions, as well as the electrode arrangements and the power input are investigated to improve the production and its efficiency and to understand the arc production behavior. The production rates are determined by a novel process monitoring method, which combines an online microbalance method with a scanning mobility particle sizer for fast production rate and size distribution measurement. Particle characterization is performed via scanning electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray diffraction measurements. It is found that the carrier gas composition has the largest impact on the particle production rate and can increase it with orders of magnitude. This appears to be not only a result of the increased heat flux and melt temperature but also of the formation of tiny nitrogen (hydrogen) bubbles in the molten feedstock, which impacts feedstock evaporation significantly in bi-atomic gases. A production rate of sub 200 nm particles from 20 up to 2,500 mg/h has been realized for the different metals. In this production range, specific power consumptions as low as 0.08 kWh/g have been reached.

  12. Heat-transfer regimes in nuclear-reactor-pumped gas lasers

    Energy Technology Data Exchange (ETDEWEB)

    Torczynski, J.R.

    1990-01-01

    The flow induced in nuclear-reactor-pumped gas lasers by the competing effects of spatially nonuniform fission-fragment heating (pumping) and heat transfer to the walls is examined. The equations of motion are acoustically filtered (low Mach number approximation), and the resulting equations are seen to have three timescales: the duration of the heating, the time required by the heating to produce a pressure rise comparable to the initial pressure, and the time for the thermal boundary layer to grow into the center of the laser cell. Three distinct regimes emerge from consideration of the relative magnitudes of these timescales. In the negligible-conduction regime, thermal-conduction effects are small, and the motion is determined by the spatial nonuniformity of the heating. In the dominant-conduction regime, thermal-conduction effects govern the motion. In the mixed regime, the effects of thermal conduction and heating nonuniformity are comparable, but since they are oppositely directed, a complex gas motion results. Analytical solutions to the equations of motion are presented for the negligible-conduction and dominant-conduction regimes, and examples are given for all three regimes. Plots of the second spatial derivative of the density field (a quantity often used in optical analyses) are given for the negligible-conduction and the dominant-conduction regimes as functions of the appropriate similarity parameters. 26 refs., 14 figs.

  13. UK-China review of opportunities for landfill gas (LFG) technology transfer

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-07-01

    This report presents the results of a project to identify opportunities to transfer UK skills with regard to landfill gas (LFG) technologies to China and other countries looking to develop LFG as a commercially viable clean energy source. The aim of the project was to develop all aspects of LFG extraction and utilisation techniques. The project involved: examining current Chinese waste disposal practices; identifying key technologies and methods for maximising LFG recovery; considering end use options and methods to optimise gas use; assessing the environmental benefits; and identifying potential opportunities for UK industry. The report consider: barriers to the development of LFG; waste disposal and landfill design in China; China's experience of LFG use; UN Development Programme (UNDP) and Global Environmental Forum (GEF) LFG demonstration projects in China; environmental regulation and controls in China; LFG technology in the UK; support for renewable energy in China and the UK; design and operational needs in China from a UK perspective; technology needs, barriers and opportunities; and recommendations for action and future work.

  14. TECHNOLOGY TRANSFER TO U.S. INDEPENDENT OIL AND NATURAL GAS PRODUCERS

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    2002-05-31

    The Petroleum Technology Transfer Council (PTTC) continued pursuing its mission of helping U.S. independent oil and natural gas producers make timely, informed technology decisions. Networking opportunities that occur with a Houston Headquarters (HQ) location are increasing name awareness. Focused efforts by Executive Director Don Duttlinger to interact with large independents, national service companies and some majors are continuing to supplement the support base of the medium to smaller industry participants around the country. PTTC is now involved in many of the technology-related activities that occur in high oil and natural gas activity areas. Access to technology remains the driving force for those who do not have in-house research and development capabilities and look to the PTTC to provide services and options for increased efficiency. Looking forward to the future, the Board, Regional Lead Organization (RLO) Directors and HQ staff developed a 10-year vision outlining what PTTC needs to accomplish in supporting a national energy plan. This vision has been communicated to Department of Energy (DOE) staff and PTTC looks forward to continuing this successful federal-state-industry partnership. As part of this effort, several more examples of industry using information gained through PTTC activities to impact their bottom line were identified. Securing the industry pull on technology acceptance was the cornerstone of this directional plan.

  15. Kinetics and dynamics of near-resonant vibrational energy transfer in gas ensembles of atmospheric interest

    Science.gov (United States)

    McCaffery, Anthony J.

    2018-03-01

    This study of near-resonant, vibration-vibration (V-V) gas-phase energy transfer in diatomic molecules uses the theoretical/computational method, of Marsh & McCaffery (Marsh & McCaffery 2002 J. Chem. Phys. 117, 503 (doi:10.1063/1.1489998)) The method uses the angular momentum (AM) theoretical formalism to compute quantum-state populations within the component molecules of large, non-equilibrium, gas mixtures as the component species proceed to equilibration. Computed quantum-state populations are displayed in a number of formats that reveal the detailed mechanism of the near-resonant V-V process. Further, the evolution of quantum-state populations, for each species present, may be followed as the number of collision cycles increases, displaying the kinetics of evolution for each quantum state of the ensemble's molecules. These features are illustrated for ensembles containing vibrationally excited N2 in H2, O2 and N2 initially in their ground states. This article is part of the theme issue `Modern theoretical chemistry'.

  16. A two-stage biological gas to liquid transfer process to convert carbon dioxide into bioplastic

    KAUST Repository

    Al Rowaihi, Israa

    2018-03-06

    The fermentation of carbon dioxide (CO2) with hydrogen (H2) uses available low-cost gases to synthesis acetic acid. Here, we present a two-stage biological process that allows the gas to liquid transfer (Bio-GTL) of CO2 into the biopolymer polyhydroxybutyrate (PHB). Using the same medium in both stages, first, acetic acid is produced (3.2 g L−1) by Acetobacterium woodii from 5.2 L gas-mixture of CO2:H2 (15:85 v/v) under elevated pressure (≥2.0 bar) to increase H2-solubility in water. Second, acetic acid is converted to PHB (3 g L−1 acetate into 0.5 g L−1 PHB) by Ralstonia eutropha H16. The efficiencies and space-time yields were evaluated, and our data show the conversion of CO2 into PHB with a 33.3% microbial cell content (percentage of the ratio of PHB concentration to cell concentration) after 217 h. Collectively, our results provide a resourceful platform for future optimization and commercialization of a Bio-GTL for PHB production.

  17. Learning transfer of geospatial technologies in secondary science and mathematics core areas

    Science.gov (United States)

    Nielsen, Curtis P.

    The purpose of this study was to investigate the transfer of geospatial technology knowledge and skill presented in a social sciences course context to other core areas of the curriculum. Specifically, this study explored the transfer of geospatial technology knowledge and skill to the STEM-related core areas of science and mathematics among ninth-grade students. Haskell's (2001) research on "levels of transfer" provided the theoretical framework for this study, which sought to demonstrate the experimental group's higher ability to transfer geospatial skills, higher mean assignment scores, higher post-test scores, higher geospatial skill application and deeper levels of transfer application than the control group. The participants of the study consisted of thirty ninth-graders enrolled in U.S. History, Earth Science and Integrated Mathematics 1 courses. The primary investigator of this study had no previous classroom experiences with this group of students. The participants who were enrolled in the school's existing two-section class configuration were assigned to experimental and control groups. The experimental group had ready access to Macintosh MacBook laptop computers, and the control group had ready access to Macintosh iPads. All participants in U.S. History received instruction with and were required to use ArcGIS Explorer Online during a Westward Expansion project. All participants were given the ArcGIS Explorer Online content assessment following the completion of the U.S. History project. Once the project in U.S. History was completed, Earth Science and Integrated Mathematics 1 began units of instruction beginning with a multiple-choice content pre-test created by the classroom teachers. Experimental participants received the same unit of instruction without the use or influence of ArcGIS Explorer Online. At the end of the Earth Science and Integrated Math 1 units, the same multiple-choice test was administered as the content post-test. Following the

  18. Effects of entrance configuration on pressure loss and heat transfer of transitional gas flow in a circular tube

    International Nuclear Information System (INIS)

    Ogawa, Masuro; Kawamura, Hiroshi

    1986-01-01

    Pressure loss and heat transfer of a transitional gas flow are affected significantly by the entrance configuration. The friction factor and the heat transfer coefficient were measured using a circular tube with four different kinds of entrance configurations. The Reynolds number at the transition from laminar to intermittent flow was varied from about 1,940 to 9,120. The intermittency factor was measured for heated and unheated flows ; and the relation between the intermittency and the friction factor or heat transfer coefficient was examined. Several existing correlations were tested and found to correlate with the experimental results fairly well. (author)

  19. Gas transfer between the atmosphere and irrigated sugarcane plantation sites under different rainfall in Hawai'i

    Science.gov (United States)

    Miyazawa, Y.; Giambelluca, T. W.; Crow, S. E.; Mudd, R. G.; Youkhana, A.; Nullet, M.; Nakahata, M.

    2015-12-01

    Sugarcane plantation land cover is increasing in area in Brazil, South Asia and the Pacific Islands because of the growing demand for sugar and biofuel production. While a large portion of sugarcane cultivated in Brazil is rain-fed and experiences drought influences on gas exchange, sugarcane in Hawai'i is thought to be buffered from drought effects because it is drip irrigated. Knowledge about carbon sequestration and evapotranspiration rates is fundamental both for the prediction of sugar and biofuel production and for water resource management for the large plantations. To understand gas transfer under spatially and temporally heterogeneous environments, we investigated the leaf- soil- and stand-scale gas transfer processes at two irrigated sugarcane plantation study sites in Hawai'i with contrasting rainfall. Gas and energy transfers were monitored using eddy covariance systems for a full- and later half- crop cycle. Leaf ecophysiological traits were measured for stands of different ages to evaluate the effects of stand age on gas transfer. Carbon sequestration rates (Fc) showed a strong relationship with solar radiation with small differences between sites. Latent heat flux expressed as the evapotranspiration rates (ET) also had a strong relationship with solar radiation, but showed seasonality due to variations in biological control (surface conductance) and atmospheric evaporative demand. The difference in ET and its responses to environments was less clear partly buffered by the differences in the stand age and seasons. The stable Fc-solar radiation relationship despite the variation in surface conductance was partly due to the saturation of net photosynthetic rates with intercellular CO2 concentration and the low sensitivity of net photosynthesis to variations in surface conductance in sugarcane with the C4 photosynthesis pathway. The response of gas transfer to periodic irrigation, rainfall and age-related changes in leaf ecophysiological traits will be

  20. A numerical scheme to calculate temperature and salinity dependent air-water transfer velocities for any gas

    Science.gov (United States)

    Johnson, M. T.

    2010-02-01

    The transfer velocity determines the rate of exchange of a gas across the air-water interface for a given deviation from Henry's law equilibrium between the two phases. In the thin film model of gas exchange, which is commonly used for calculating gas exchange rates from measured concentrations of trace gases in the atmosphere and ocean/freshwaters, the overall transfer is controlled by diffusion-mediated films on either side of the air-water interface. Calculating the total transfer velocity (i.e. including the influence from both molecular layers) requires the Henry's law constant and the Schmidt number of the gas in question, the latter being the ratio of the viscosity of the medium and the molecular diffusivity of the gas in the medium. All of these properties are both temperature and (on the water side) salinity dependent and extensive calculation is required to estimate these properties where not otherwise available. The aim of this work is to standardize the application of the thin film approach to flux calculation from measured and modelled data, to improve comparability, and to provide a numerical framework into which future parameter improvements can be integrated. A detailed numerical scheme is presented for the calculation of the gas and liquid phase transfer velocities (ka and kw respectively) and the total transfer velocity, K. The scheme requires only basic physical chemistry data for any gas of interest and calculates K over the full range of temperatures, salinities and wind-speeds observed in and over the ocean. Improved relationships for the wind-speed dependence of ka and for the salinity-dependence of the gas solubility (Henry's law) are derived. Comparison with alternative schemes and methods for calculating air-sea flux parameters shows good agreement in general but significant improvements under certain conditions. The scheme is provided as a downloadable program in the supplementary material, along with input files containing molecular

  1. Gas transfer velocities of methane and carbon dioxide in a subtropical shallow pond

    Science.gov (United States)

    Xiao, Shangbin

    2015-04-01

    Two diel field campaigns under different weather patterns were carried out in the summer and autumn of 2013 to measure CO2 and CH4 fluxes and to probe the rates of gas exchange across the air-water interface in a subtropical eutrophic pond in China. Bubble emissions of CH4 accounted for 99.7% and 91.67% of the total CH4 emission measured at two sites in the summer; however, no bubble was observed in the autumn. The pond was supersaturated with CO2 and CH4 during the monitoring period, and the saturation ratios (i.e., observed concentration / equilibrium concentration) of CH4 were much higher than that of CO2. Although the concentration of dissolved CO2 in the surface water collected in the autumn was 1.24 times of that in the summer, the mean diffusive CO2 flux across the water-air interface measured in the summer is almost twice compared with that in the autumn. The mean concentration of dissolved CH4 in the surface water in the autumn was around half of that in the summer, but the mean diffusive CH4 flux in the summer is 4-5 times of that in the autumn. Our data showed that the variation in gas exchange rate was dominated by differences in weather patterns and primary production. Averaged k600-CO2 and k600-CH4 (the gas transfer velocity normalized to a Schmidt number of 600) were 0.65 and 0.55 cm/h in the autumn, and 2.83 and 1.64 cm/h in the summer respectively. No statistically significant correlation was found between k600 and U10 (wind speed at 10 m height) in the summer at low wind speeds in clear weather. Diffusive gas fluxes increased during the nights, which resulted from the nighttime cooling effect of water surface and stronger turbulent mixing in the water column. The chemical enhancements for CO2 was estimated up to 1.94-fold in the hot and clear summer with low wind speeds, which might have been resulted from the increasing hydration reactions in water due to the high water temperature and active metabolism in planktonic algae. However, both the air

  2. Gas transfer velocities for quantifying methane, oxygen and other gas fluxes through the air-water interface of wetlands with emergent vegetation

    Science.gov (United States)

    Poindexter, C.; Variano, E. A.

    2012-12-01

    Empirical models for the gas transfer velocity, k, in the ocean, lakes and rivers are fairly well established, but there are few data to predict k for wetlands. We have conducted experiments in a simulated emergent marsh in the laboratory to explore the relationship between k, wind shear and thermal convection. Now we identify the implications of these results for gas transfer in actual wetlands by (1) quantifying the range of wind conditions in emergent vegetation canopies and the range of thermal convection intensities in wetland water columns, and (2) describing the non-linear interaction of these two stirring forces over their relevant ranges in wetlands. We measured mean wind speeds and wind speed variance within the shearless region of a Schoenoplectus-Typha marsh canopy in the Sacramento-San Joaquin Delta (Northern California, USA). The mean wind speed within this region, , is significantly smaller than wind above the canopy. Based on our laboratory experiments, for calm or even average wind conditions in this emergent marsh k600 is only on the order 0.1 cm hr-1 (for neutrally or stably stratified water columns). We parameterize unstable thermal stratification and the resulting thermal convection using the heat flux through the air-water interface, q. We analyzed a water temperature record for the Schoenoplectus-Typha marsh to obtain a long-term heat flux record. We used these heat flux data along with short-term heat flux data from other wetlands in the literature to identify the range of the gas transfer velocity associated with thermal convection in wetlands. The typical range of heat fluxes through water columns shaded by closed emergent canopies (-200 W m-2 to +200 W m-2) yields k600 values of 0.5 - 2.5 cm hr-1 according to the model we developed in the laboratory. Thus for calm or average wind conditions, the gas transfer velocity associated with thermal convection is significantly larger than the gas transfer velocity associated with wind shear

  3. Effect of wind waves on air-sea gas exchange: proposal of an overall CO2 transfer velocity formula as a function of breaking-wave parameter

    International Nuclear Information System (INIS)

    Zhao, D.; Suzuki, Y.; Komori, S.

    2003-01-01

    A new formula for gas transfer velocity as a function of the breaking-wave parameter is proposed based on correlating gas transfer with whitecap coverage. The new formula for gas transfer across an air-sea interface depends not only on wind speed but also on wind-wave state. At the same wind speed, a higher gas transfer velocity will be obtained for a more developed wind-sea, which is represented by a smaller spectral peak frequency of wind waves. We suggest that the large uncertainties in the traditional relationship of gas transfer velocity with wind speed be ascribed to the neglect of the effect of wind waves. The breaking-wave parameter can be regarded as a Reynolds number that characterizes the intensity of turbulence associated with wind waves in the downward-bursting boundary layer (DBBL). DBBL provides an effective way to exchange gas across the air-sea interface, which might be related to the surface renewal

  4. Site-specific analysis of gas-phase hydrogen/deuterium exchange of peptides and proteins by electron transfer dissociation.

    Science.gov (United States)

    Rand, Kasper D; Pringle, Steven D; Morris, Michael; Brown, Jeffery M

    2012-02-21

    To interpret the wealth of information contained in the hydrogen/deuterium exchange (HDX) behavior of peptides and proteins in the gas-phase, analytical tools are needed to resolve the HDX of individual exchanging sites. Here we show that ETD can be combined with fast gas-phase HDX in ND(3) gas and used to monitor the exchange of side-chain hydrogens of individual residues in both small peptide ions and larger protein ions a few milliseconds after electrospray. By employing consecutive traveling wave ion guides in a mass spectrometer, peptide and protein ions were labeled on-the-fly (0.1-10 ms) in ND(3) gas and subsequently fragmented by ETD. Fragment ions were separated using ion mobility and mass analysis enabled the determination of the gas-phase deuterium uptake of individual side-chain sites in a range of model peptides of different size and sequence as well as two proteins; cytochrome C and ubiquitin. Gas-phase HDX-ETD experiments on ubiquitin ions ionized from both denaturing and native solution conditions suggest that residue-specific HDX of side-chain hydrogens is sensitive to secondary and tertiary structural features occurring in both near-native and unfolded gas-phase conformers present shortly after electrospray. The described approach for online gas-phase HDX and ETD paves the way for making mass spectrometry techniques based on gas-phase HDX more applicable in bioanalytical research.

  5. Experimental evaluation of enthalpy efficiency and gas-phase contaminant transfer in an enthalpy recovery unit with polymer membrane foils

    DEFF Research Database (Denmark)

    Nie, Jinzhe; Yang, Jianrong; Fang, Lei

    2015-01-01

    Experimental studies were conducted in a laboratory setting to investigate the enthalpy efficiency and gas-phase contaminant transfer in a polymer membrane enthalpy recovery unit. One commercially available polymer membrane enthalpy recovery unit was used as a reference unit. Simulated indoor air...

  6. Application of the penetration theory for gas - Liquid mass transfer without liquid bulk : Differences with system with a bulk

    NARCIS (Netherlands)

    van Elk, E. P.; Knaap, M. C.; Versteeg, G. F.

    2007-01-01

    Frequently applied micro models for gas-liquid mass transfer all assume the presence of a liquid bulk. However, some systems are characterized by the absence of a liquid bulk, a very thin layer of liquid flows over a solid surface. An example of such a process is absorption in a column equipped with

  7. Mass transfer with complex chemical reaction in gas-liquid systems - I. Consecutive reversible reactions with equal diffusivities

    NARCIS (Netherlands)

    Vas bhat, R.D.; van Swaaij, Willibrordus Petrus Maria; Kuipers, J.A.M.; Versteeg, Geert

    1999-01-01

    A fundamental description of gas¿liquid mass transfer with reversible consecutive reaction has been derived. The Higbie penetration theory has been used and numerical simulations were carried out for isothermal absorption. Although the model can be adapted to reactions of general stoichiometric and

  8. Quantification of diesel exhaust gas phase organics by a thermal desorption proton transfer reaction mass spectrometer

    Science.gov (United States)

    Erickson, M. H.; Wallace, H. W.; Jobson, B. T.

    2012-02-01

    A new approach was developed to measure the total abundance of long chain alkanes (C12 and above) in urban air using thermal desorption with a proton transfer reaction mass spectrometer (PTR-MS). These species are emitted in diesel exhaust and may be important precursors to secondary organic aerosol production in urban areas. Long chain alkanes undergo dissociative proton transfer reactions forming a series of fragment ions with formula CnH2n+1. The yield of the fragment ions is a function of drift conditions. At a drift field strength of 80 Townsends, the most abundant ion fragments from C10 to C16 n-alkanes were m/z 57, 71 and 85. The PTR-MS is insensitive to n-alkanes less than C8 but displays an increasing sensitivity for larger alkanes. Higher drift field strengths yield greater normalized sensitivity implying that the proton affinity of the long chain n-alkanes is less than H2O. Analysis of diesel fuel shows the mass spectrum was dominated by alkanes (CnH2n+1), monocyclic aromatics, and an ion group with formula CnH2n-1 (m/z 97, 111, 125, 139). The PTR-MS was deployed in Sacramento, CA during the Carbonaceous Aerosols and Radiative Effects Study field experiment in June 2010. The ratio of the m/z 97 to 85 ion intensities in ambient air matched that found in diesel fuel. Total diesel exhaust alkane concentrations calculated from the measured abundance of m/z 85 ranged from the method detection limit of ~1 μg m-3 to 100 μg m-3 in several air pollution episodes. The total diesel exhaust alkane concentration determined by this method was on average a factor of 10 greater than the sum of alkylbenzenes associated with spark ignition vehicle exhaust.

  9. Heat transfer during condensation of steam from steam-gas mixtures in the passive safety systems of nuclear power plants

    Science.gov (United States)

    Portnova, N. M.; Smirnov, Yu B.

    2017-11-01

    A theoretical model for calculation of heat transfer during condensation of multicomponent vapor-gas mixtures on vertical surfaces, based on film theory and heat and mass transfer analogy is proposed. Calculations were performed for the conditions implemented in experimental studies of heat transfer during condensation of steam-gas mixtures in the passive safety systems of PWR-type reactors of different designs. Calculated values of heat transfer coefficients for condensation of steam-air, steam-air-helium and steam-air-hydrogen mixtures at pressures of 0.2 to 0.6 MPa and of steam-nitrogen mixture at the pressures of 0.4 to 2.6 MPa were obtained. The composition of mixtures and vapor-to-surface temperature difference were varied within wide limits. Tube length ranged from 0.65 to 9.79m. The condensation of all steam-gas mixtures took place in a laminar-wave flow mode of condensate film and turbulent free convection in the diffusion boundary layer. The heat transfer coefficients obtained by calculation using the proposed model are in good agreement with the considered experimental data for both the binary and ternary mixtures.

  10. Heat transfer analysis of porous media receiver with different transport and thermophysical models using mixture as feeding gas

    International Nuclear Information System (INIS)

    Wang, Fuqiang; Tan, Jianyu; Wang, Zhiqiang

    2014-01-01

    Highlights: • Using local thermal non-equilibrium model to solve heat transfer of porous media. • CH 4 /H 2 O mixture is adopted as feeding gas of porous media receiver. • Radiative transfer equation between porous strut is solved by Rosseland approximation. • Transport and thermophysical models not included in Fluent are programmed by UDFs. • Variations of model on thermal performance of porous media receiver are studied. - Abstract: The local thermal non-equilibrium model is adopted to solve the steady state heat and mass transfer problems of porous media solar receiver. The fluid entrance surface is subjected to concentrated solar radiation, and CH 4 /H 2 O mixture is adopted as feeding gas. The radiative heat transfer equation between porous strut is solved by Rosseland approximation. The impacts of variation in transport and thermophysical characteristics model of gas mixture on thermal performance of porous media receiver are investigated. The transport and thermophysical characteristics models which are not included in software Fluent are programmed by user defined functions (UDFs). The numerical results indicate that models of momentum source term for porous media receiver have significant impact on pressure drop and static pressure distribution, and the radiative heat transfer cannot be omitted during the thermal performance analysis of porous media receiver

  11. Application of the direct simulation Monte Carlo method to nanoscale heat transfer between a soot particle and the surrounding gas

    International Nuclear Information System (INIS)

    Yang, M.; Liu, F.; Smallwood, G.J.

    2004-01-01

    Laser-Induced Incandescence (LII) technique has been widely used to measure soot volume fraction and primary particle size in flames and engine exhaust. Currently there is lack of quantitative understanding of the shielding effect of aggregated soot particles on its conduction heat loss rate to the surrounding gas. The conventional approach for this problem would be the application of the Monte Carlo (MC) method. This method is based on simulation of the trajectories of individual molecules and calculation of the heat transfer at each of the molecule/molecule collisions and the molecule/particle collisions. As the first step toward calculating the heat transfer between a soot aggregate and the surrounding gas, the Direct Simulation Monte Carlo (DSMC) method was used in this study to calculate the heat transfer rate between a single spherical aerosol particle and its cooler surrounding gas under different conditions of temperature, pressure, and the accommodation coefficient. A well-defined and simple hard sphere model was adopted to describe molecule/molecule elastic collisions. A combination of the specular reflection and completely diffuse reflection model was used to consider molecule/particle collisions. The results obtained by DSMC are in good agreement with the known analytical solution of heat transfer rate for an isolated, motionless sphere in the free-molecular regime. Further the DSMC method was applied to calculate the heat transfer in the transition regime. Our present DSMC results agree very well with published DSMC data. (author)

  12. A Lattice Gas Automata Model for the Coupled Heat Transfer and Chemical Reaction of Gas Flow Around and Through a Porous Circular Cylinder

    Directory of Open Access Journals (Sweden)

    Hongsheng Chen

    2015-12-01

    Full Text Available Coupled heat transfer and chemical reaction of fluid flow in complex boundaries are explored by introducing two additional properties, i.e. particle type and energy state into the Lattice gas automata (LGA Frisch–Hasslacher–Pomeau (FHP-II model. A mix-redistribute of energy and type of particles is also applied on top of collision rules to ensure randomness while maintaining the conservation of mass, momentum and energy. Simulations of heat transfer and heterogeneous reaction of gas flow passing a circular porous cylinder in a channel are presented. The effects of porosity of cylinder, gas inlet velocity, and reaction probability on the reaction process are further analyzed with respect to the characteristics of solid morphology, product concentration, and temperature profile. Numerical results indicate that the reaction rate increases with increasing reaction probability as well as gas inlet velocity. Cylinders with a higher value of porosity and more homogeneous structure also react with gas particles faster. These results agree well with the basic theories of gas–solid reactions, indicating the present model provides a method for describing gas–solid reactions in complex boundaries at mesoscopic level.

  13. A Mathematical Model of Membrane Gas Separation with Energy Transfer by Molecules of Gas Flowing in a Channel to Molecules Penetrating this Channel from the Adjacent Channel

    Directory of Open Access Journals (Sweden)

    Szwast Maciej

    2015-06-01

    Full Text Available The paper presents the mathematical modelling of selected isothermal separation processes of gaseous mixtures, taking place in plants using membranes, in particular nonporous polymer membranes. The modelling concerns membrane modules consisting of two channels - the feeding and the permeate channels. Different shapes of the channels cross-section were taken into account. Consideration was given to co-current and counter-current flows, for feeding and permeate streams, respectively, flowing together with the inert gas receiving permeate. In the proposed mathematical model it was considered that pressure of gas changes along the length of flow channels was the result of both - the drop of pressure connected with flow resistance, and energy transfer by molecules of gas flowing in a given channel to molecules which penetrate this channel from the adjacent channel. The literature on membrane technology takes into account only the drop of pressure connected with flow resistance. Consideration given to energy transfer by molecules of gas flowing in a given channel to molecules which penetrate this channel from the adjacent channel constitute the essential novelty in the current study. The paper also presents results of calculations obtained by means of a computer program which used equations of the derived model. Physicochemical data concerning separation of the CO2/CH4 mixture with He as the sweep gas and data concerning properties of the membrane made of PDMS were assumed for calculations.

  14. Analysis of transient heat flow to thick-walled plates and cylinders. [to determine gas heat transfer coefficient

    Science.gov (United States)

    Powell, W. B.

    1973-01-01

    A methodology is described for the analysis of a transient temperature measurement made in a flat or curved plate subjected to convective heat transfer, such that the surface heat flux, the hot-gas temperture, and the gas heat transfer coefficient can be determined. It is shown that if the transient temperature measurement is made at a particular point located nearly midway in the thickness of the plate there is an important simplification in the data analysis process, in that the factor relating the surface heat flux to the measured rate of rise of temperature becomes invariant for a Fourier Number above 0.60 and for all values of the Biot Number. Parameters are derived, tabulated, and plotted which enable straightforward determination of the surface heat flux, the hot-gas temperature, of the plate, the rate of rise of temperature, the plate thickness and curvature, and the mean thermal properties of the plate material at the test temperature.

  15. Conditional cash transfer impact evaluation: an evaluation of the costa rican secondary education program Avancemos

    Directory of Open Access Journals (Sweden)

    Catherine Mata

    2015-07-01

    Full Text Available This paper evaluates the impact of Avancemos, a conditional cash transfer program in Costa Rica. Specifically, this paper measures the impact on student desertion for the first year of the program using a panel created with the Household Surveys for Multiple Purposes for the years 2006 and 2007, elaborated by the National Institute of Statistics and Census. Using econometric tools and quasi-experimental methodologies such as Propensity Score Matching and difference-in-differences, we find a positive impact associated to the program for desertion and reinsertion. Specifically, for between 10 and 16 percent of the students who did not leave high school, it was only due to Avancemos, meaning that without the program they would have abandoned their studies. This is why we can conclude that Avancemos had a positive impact according to its planned objectives of preventing dropouts and ensuring their reinsertion.

  16. Heat Transfer Augmentation in Gas Turbine Blade Rectangular Passages Using Circular Ribs with Fins

    Directory of Open Access Journals (Sweden)

    Mohammed W. Al-Jibory

    2017-11-01

    Full Text Available In this paper, an experimental system  was designed and built to simulate conditions in the gas turbine blade cooling and run the experimental part. Boundary conditions are: inlet coolant air temperature is 300K with Reynolds numbers (Re=7901 .The surrounding constant hot air temperatures was (673 K.The numerical simulations were done by using software FLUENT version (14.5, in this part, it was presented the effect of using circular ribs having middle fin fitted in rectangular passage channel on fluid flow and heat transfer characteristics.  Ribs used with pitch-rib height of 10, rectangular channel of (30x60 mm cross section, 1.5 mm duct thickness and 0.5 m long. The temperature, velocity distribution contours, cooling air temperature distribution at the duct centerline, the inner wall surface temperature of the duct, and thermal performance factor are presented in this paper. it can be seen that the duct with all ribs with middle fins was the better case which leads to increase the coolant air temperature by (10.22 % and decrease the inner wall temperature by (6.15 % . The coolant air flow velocity seems to be accelerated and decelerated through the channel in the presence of ribs, so it was shown that the thermal performance factor along the duct is larger than 1, this is due to the fact that the ribs create turbulent conditions and increasing thermal surface area, and thus increasing heat transfer coefficient than the smooth channel.

  17. Aging of biogenic secondary organic aerosol via gas-phase OH radical reactions

    DEFF Research Database (Denmark)

    Donahue, Neil M.; Henry, Kaytlin M.; Mentel, Thomas F.

    2012-01-01

    The Multiple Chamber Aerosol Chemical Aging Study (MUCHACHAS) tested the hypothesis that hydroxyl radical (OH) aging significantly increases the concentration of first-generation biogenic secondary organic aerosol (SOA). OH is the dominant atmospheric oxidant, and MUCHACHAS employed environmental...

  18. Hot-gas-side heat transfer characteristics of subscale, plug-nozzle rocket calorimeter chamber

    Science.gov (United States)

    Quentmeyer, Richard J.; Roncace, Elizabeth A.

    1993-01-01

    An experimental investigation was conducted to determine the hot-gas-side heat transfer characteristics for a liquid-hydrogen-cooled, subscale, plug-nozzle rocket test apparatus. This apparatus has been used since 1975 to evaluate rocket engine advanced cooling concepts and fabrication techniques, to screen candidate combustion chamber liner materials, and to provide data for model development. In order to obtain the data, a water-cooled calorimeter chamber having the same geometric configuration as the plug-nozzle test apparatus was tested. It also used the same two showerhead injector types that were used on the test apparatus: one having a Rigimesh faceplate and the other having a platelet faceplate. The tests were conducted using liquid oxygen and gaseous hydrogen as the propellants over a mixture ratio range of 5.8 to 6.3 at a nominal chamber pressure of 4.14 MPa abs (600 psia). The two injectors showed similar performance characteristics with the Rigimesh faceplate having a slightly higher average characteristic-exhaust-velocity efficiency of 96 percent versus 94.4 percent for the platelet faceplate. The throat heat flux was 54 MW/m(sup 2) (33 Btu/in.(sup 2)-sec) at the nominal operating condition, which was a chamber pressure of 4.14 MPa abs (600 psia), a hot-gas-side wall temperature of 730 K (1314 R), and a mixture ratio of 6.0. The chamber throat region correlation coefficient C(sub g) for a Nusselt number correlation of the form Nu =C(sub g)Re(sup 0.8)Pr(sup 0.3) averaged 0.023 for the Rigimesh faceplate and 0.026 for the platelet faceplate.

  19. Detection of nerve agents using proton transfer reaction mass spectrometry with ammonia as reagent gas.

    Science.gov (United States)

    Ringer, Joachim M

    2013-01-01

    The chemical warfare agents (CWA) Sarin, Soman, Cyclosarin and Tabun were characterised by proton transfer mass spectrometry (PTRMS). It was found that PTRMS is a suitable technique to detect nerve agents highly sensitively, highly selectively and in near real-time. Methods were found to suppress molecule fragmentation which is significant under PTRMS hollow cathode ionisation conditions. In this context, the drift voltage (as one of the most important system parameters) was varied and ammonia was introduced as an additional chemical reagent gas. Auxiliary chemicals such as ammonia affect ionisation processes and are quite common in context with detectors for CWAs based on ion mobility spectrometry (IMS). With both, variation of drift voltage and ammonia as the reagent gas, fragmentation can be suppressed effectively. Suppression of fragmentation is crucial particularly concerning the implementation of an algorithm for automated agent identification in field applications. On the other hand, appearance of particular fragments might deliver additional information. Degradation and rearrangement products of nerve agents are not distinctive for the particular agent but for the chemical class they belong to. It was found that switching between ammonia doped and ordinary water ionisation chemistry can easily be performed within a few seconds. Making use of this effect it is possible to switch between fragment and molecular ion peak spectra. Thus, targeted fragmentation can be used to confirm identification based only on single peak detection. PTRMS turned out to be a promising technique for future CWA detectors. In terms of sensitivity, response time and selectivity (or confidence of identification, respectively) PTRMS performs as a bridging technique between IMS and GC-MS.

  20. Mixed convection heat transfer between a steam/non-condensable gas mixture and an inclined finned tube bundle

    Energy Technology Data Exchange (ETDEWEB)

    De Cachard, F.; Lompersky, S.; Monauni, G.R. [Paul Scherrer Institute, Villigen (Switzerland). Thermal Hydraulic Lab.

    1999-07-01

    An experimental and analytical program was performed at PSI (Paul Scherrer Institute) to study the performance of a finned-tube condenser in the presence of non-condensable gases at low gas mass fluxes. The model developed for this application includes mixed convection heat transfer between the vapour/non-condensable mixture and the finned tubes, heat conduction through the fins and tubes, and evaporative heat transfer inside the tubes. On the gas, heat transfer correlations are used, and the condensation rate is calculated using the heat/mass transfer analogy. A combination of various available correlations for forced convection in staggered finned tube bundles is used, together with a correction accounting for superimposed natural convection. For the condensate heat transfer resistance, the beatty and Katz model for gravity driven liquid films on the tubes is used. The fine efficiency is accounted for using classical iterative calculations. Evaporative heat transfer inside the tubes is predicted using the Chen correlation. The finned tube condenser model has been assessed against data obtained at the PSI LINX facility with two test condensers. For the 62 LINX experiments performed, the model predictions are very good, i.e., less then 10% standard deviation between experimental and predicted results.

  1. Large eddy simulation for predicting turbulent heat transfer in gas turbines.

    Science.gov (United States)

    Tafti, Danesh K; He, Long; Nagendra, K

    2014-08-13

    Blade cooling technology will play a critical role in the next generation of propulsion and power generation gas turbines. Accurate prediction of blade metal temperature can avoid the use of excessive compressed bypass air and allow higher turbine inlet temperature, increasing fuel efficiency and decreasing emissions. Large eddy simulation (LES) has been established to predict heat transfer coefficients with good accuracy under various non-canonical flows, but is still limited to relatively simple geometries and low Reynolds numbers. It is envisioned that the projected increase in computational power combined with a drop in price-to-performance ratio will make system-level simulations using LES in complex blade geometries at engine conditions accessible to the design process in the coming one to two decades. In making this possible, two key challenges are addressed in this paper: working with complex intricate blade geometries and simulating high-Reynolds-number (Re) flows. It is proposed to use the immersed boundary method (IBM) combined with LES wall functions. A ribbed duct at Re=20 000 is simulated using the IBM, and a two-pass ribbed duct is simulated at Re=100 000 with and without rotation (rotation number Ro=0.2) using LES with wall functions. The results validate that the IBM is a viable alternative to body-conforming grids and that LES with wall functions reproduces experimental results at a much lower computational cost. © 2014 The Author(s) Published by the Royal Society. All rights reserved.

  2. Production of secondary particles and nuclei in cosmic rays collisions with the interstellar gas using the FLUKA code

    CERN Document Server

    Mazziotta, M N; Ferrari, A; Gaggero, D; Loparco, F; Sala, P R

    2016-01-01

    The measured fluxes of secondary particles produced by the interactions of Cosmic Rays (CRs) with the astronomical environment play a crucial role in understanding the physics of CR transport. In this work we present a comprehensive calculation of the secondary hadron, lepton, gamma-ray and neutrino yields produced by the inelastic interactions between several species of stable or long-lived cosmic rays projectiles (p, D, T, 3He, 4He, 6Li, 7Li, 9Be, 10Be, 10B, 11B, 12C, 13C, 14C, 14N, 15N, 16O, 17O, 18O, 20Ne, 24Mg and 28Si) and different target gas nuclei (p, 4He, 12C, 14N, 16O, 20Ne, 24Mg, 28Si and 40Ar). The yields are calculated using FLUKA, a simulation package designed to compute the energy distributions of secondary products with large accuracy in a wide energy range. The present results provide, for the first time, a complete and self-consistent set of all the relevant inclusive cross sections regarding the whole spectrum of secondary products in nuclear collisions. We cover, for the projectiles, a ki...

  3. Gas tax/public transit annual expenditure report pursuant to the agreement on the transfer of federal gas tax revenue and the agreement on the transfer of public transit funds for the period April 1, 2006 to March 31, 2007

    International Nuclear Information System (INIS)

    Binnie, B.; Taylor, R.; Gibson, B.

    2007-09-01

    Federal funding initiatives for local infrastructure and capacity building was discussed with particular reference to the unique partnerships between the Canada-British Columbia Agreement on the transfer of federal gas tax revenues and the Canada-British Columbia agreement on the transfer of funds for public transit. The agreements reflect the nature of intergovernmental relations in British Columbia where the Union of British Columbia Municipalities (UBCM) works together with both federal and provincial governments to promote sustainable communities. This report identified the initiatives that are underway in communities across British Columbia as they begin to implement Gas Tax and Public Transit funded projects. These projects span a broad range of eligible project categories. The leadership role taken by local governments in the province to reduce greenhouse gas emissions was highlighted. Some of the 141 projects reported in 2007 were highlighted in this report, including improvement to public transit in the District of Saanich; TransLink bus replacement and expansion; cycling and pedestrian infrastructure; improvements to local roads and bridges; alternative energy retrofits; collection of solid waste; improvement to water systems; stormwater and wastewater treatment; capacity building; watershed protection; and water acquisition strategies. Of the projects reported, 33 per cent anticipated gas tax spending in more than 1 year, indicating either payment of capital costs as they are incurred during a construction period that spans beyond a single year, or use of gas tax funding towards the debt servicing costs related to the eligible project. tabs., figs

  4. Duration and urgency of transfer in births planned at home and in freestanding midwifery units in England: secondary analysis of the Birthplace national prospective cohort study

    Science.gov (United States)

    2013-01-01

    Background In England, there is a policy of offering healthy women with straightforward pregnancies a choice of birth setting. Options may include home or a freestanding midwifery unit (FMU). Transfer rates from these settings are around 20%, and higher for nulliparous women. The duration of transfer is of interest because of the potential for delay in access to specialist care and is also of concern to women. We aimed to estimate the duration of transfer in births planned at home and in FMUs and explore the effects of distance and urgency on duration. Methods This was a secondary analysis of data collected in a national prospective cohort study including 27,842 ‘low risk’ women with singleton, term, ‘booked’ pregnancies, planning birth in FMUs or at home in England from April 2008 to April 2010. We described transfer duration using the median and interquartile range, for all transfers and those for reasons defined as potentially urgent or non-urgent, and used cumulative distribution curves to compare transfer duration by urgency. We explored the effect of distance for transfers from FMUs and described outcomes in women giving birth within 60 minutes of transfer. Results The median overall transfer time, from decision to transfer to first OU assessment, was shorter in transfers from home compared with transfers from FMUs (49 vs 60 minutes; p < 0.001). The median duration of transfers before birth for potentially urgent reasons (home 42 minutes, FMU 50 minutes) was 8–10 minutes shorter compared with transfers for non-urgent reasons. In transfers for potentially urgent reasons, the median overall transfer time from FMUs within 20 km of an OU was 47 minutes, increasing to 55 minutes from FMUs 20-40 km away and 61 minutes in more remote FMUs. In women who gave birth within 60 minutes after transfer, adverse neonatal outcomes occurred in 1-2% of transfers. Conclusions Transfers from home or FMU commonly take up to 60 minutes from decision to

  5. Third party access pricing to the network, secondary capacity market and economic optimum: the case of natural gas

    Energy Technology Data Exchange (ETDEWEB)

    David, L.; Percebois, J

    2002-09-01

    The gas deregulation process implies crucial choices concerning access to transportation networks. These choices deal with the nature, the structure and the level of access fees. This paper proposes an evaluation of different systems implemented both in Europe and North America, in relation to normative pricing references. The rules according to which shippers can buy or sell capacity represent another kind of choice that Regulators have to make. This paper proposes a simple model which demonstrates that secondary market prices should not be subject to a cap and emphasizes the need of a 'use-it-or-lose-it' rule on this market. (authors)

  6. Third party access pricing to the network, secondary capacity market and economic optimum: the case of natural gas

    International Nuclear Information System (INIS)

    David, L.; Percebois, J.

    2002-09-01

    The gas deregulation process implies crucial choices concerning access to transportation networks. These choices deal with the nature, the structure and the level of access fees. This paper proposes an evaluation of different systems implemented both in Europe and North America, in relation to normative pricing references. The rules according to which shippers can buy or sell capacity represent another kind of choice that Regulators have to make. This paper proposes a simple model which demonstrates that secondary market prices should not be subject to a cap and emphasizes the need of a 'use-it-or-lose-it' rule on this market. (authors)

  7. Angular dependence of secondary ion emission from silicon bombarded with inert gas ions

    International Nuclear Information System (INIS)

    Wittmaack, K.

    1984-01-01

    The emission of positive and negative, atomic and molecular secondary ions sputtered from silicon has been studied under ultrahigh vacuum conditions. The sample was bombarded with 2-12 keV Ar + and Xe + ions at angles of incidence between 0 0 and 60 0 to the surface normal. The angular dependence of the secondary ion intensity as well as the energy spectra of Si + and Si - were found to differ significantly. The effect is attributed mostly do differences in the rate of neutralization. The stability of molecular ions appears to be independent of the charge state. Supporting evidence is provided for the idea that multiply charged secondary ions are due to Auger de-excitation of sputtered atoms in vacuum. (orig.)

  8. Surface wave observations during CoOP experiments and their relation to air-sea gas transfer

    Science.gov (United States)

    Hara, Tetsu; Uz, B. Mete; Wei, Hua; Edson, James B.; Frew, Nelson M.; McGillis, Wade R.; McKenna, Sean P.; Bock, Erik J.; Haußecker, Horst; Schimpf, Uwe

    Gas exchange between the ocean and the atmosphere is strongly influenced by physical processes in the near-surface waters. Surface waves are particularly important for gas fluxes because they enable faster transfer of gases across the diffusive sublayer by causing more frequent renewal of the skin layer. During the CoOP air-sea gas exchange experiments (1995; 1997), we obtained one of the most comprehensive data sets of physical processes at the air-sea interface in both near-shore and off-shore waters. During these experiments simultaneous measurements of short wind waves, surface films, wind stress, and transfer velocity were made from a towed or self-propelled catamaran with a wide range of wind stress and with varying surface film conditions. The results show that the wave spectra at higher wavenumbers are significantly reduced by surfactant at wind friction velocities below 0.2 m s-1. The surfactant effect may be quantified using the surface enrichment (difference between the CDOM fluorescence in microlayers and that in bulk water) with reasonable accuracy. During rain events the wave spectra are raised at higher wavenumbers (above 200 rad m-1) but are not affected at 100 rad m-1. The surfactant effect is also reduced during rain. The air-sea gas transfer velocity is roughly proportional to the wave spectra at higher wavenumbers but appears to be less sensitive to spectra of longer waves.

  9. Specialists' meeting on heat and mass transfer in the reactor cover gas, Harwell, England, 8-10 October 1985

    International Nuclear Information System (INIS)

    1986-07-01

    The specialists' meeting on ''Heat and Mass Transfer in the Reactor Cover Gas'' was held at Harwell, the United Kingdom, on 8-10 October 1985. It was attended by 24 participants from all IWGFR member-countries: France, the Federal Republic of Germany, India, Italy, Japan, the Union of Soviet Socialist Republics, the United Kingdom and the United States. The meeting was presided over by Dr K. Eickhoff of the United Kingdom. The following topical areas were reviewed and discussed during the meeting: 1. National review presentations on the status of activities on heat and mass transfer in the reactor cover gas - 2 papers; 2. Aerosol dynamics - 4 papers; 3. Aerosol trapping - 2 papers; 4. Heat and mass transfer through cover gas in annuli - 3 papers; 5. Radiative properties - 4 papers; 6. Modelling of cover gas - 4 papers. A separate abstract was prepared for each of these papers. On the basis of papers presented and discussed by participants, session summaries and conclusions were drafted on the above topical areas. These summaries, as well as general conclusions and recommendations of the meeting were reviewed and agreed upon by consensus at the end of the meeting

  10. Evaluation of radiation heat transfer in porous medial: Application for a pebble bed modular reactor cooled by CO2 gas

    Directory of Open Access Journals (Sweden)

    Sidi-Ali Kamel

    2013-01-01

    Full Text Available This work analyses the contribution of radiation heat transfer in the cooling of a pebble bed modular reactor. The mathematical model, developed for a porous medium, is based on a set of equations applied to an annular geometry. Previous major works dealing with the subject have considered the forced convection mode and often did not take into account the radiation heat transfer. In this work, only free convection and radiation heat transfer are considered. This can occur during the removal of residual heat after shutdown or during an emergency situation. In order to derive the governing equations of radiation heat transfer, a steady-state in an isotropic and emissive porous medium (CO2 is considered. The obtained system of equations is written in a dimensionless form and then solved. In order to evaluate the effect of radiation heat transfer on the total heat removed, an analytical method for solving the system of equations is used. The results allow quantifying both radiation and free convection heat transfer. For the studied situation, they show that, in a pebble bed modular reactor, more than 70% of heat is removed by radiation heat transfer when CO2 is used as the coolant gas.

  11. The effect of microbubbles on gas-liquid mass transfer coefficient and degradation rate of COD in wastewater treatment.

    Science.gov (United States)

    Yao, Kangning; Chi, Yong; Wang, Fei; Yan, Jianhua; Ni, Mingjiang; Cen, Kefa

    2016-01-01

    A commonly used aeration device at present has the disadvantages of low mass transfer rate because the generated bubbles are several millimeters in diameter which are much bigger than microbubbles. Therefore, the effect of a microbubble on gas-liquid mass transfer and wastewater treatment process was investigated. To evaluate the effect of each bubble type, the volumetric mass transfer coefficients for microbubbles and conventional bubbles were determined. The volumetric mass transfer coefficient was 0.02905 s(-1) and 0.02191 s(-1) at a gas flow rate of 0.67 L min(-1) in tap water for microbubbles and conventional bubbles, respectively. The degradation rate of simulated municipal wastewater was also investigated, using aerobic activated sludge and ozone. Compared with the conventional bubble generator, the chemical oxygen demand (COD) removal rate was 2.04, 5.9, 3.26 times higher than those of the conventional bubble contactor at the same initial COD concentration of COD 200 mg L(-1), 400 mg L(-1), and 600 mg L(-1), while aerobic activated sludge was used. For the ozonation process, the rate of COD removal using microbubble generator was 2.38, 2.51, 2.89 times of those of the conventional bubble generator. Based on the results, the effect of initial COD concentration on the specific COD degradation rate were discussed in different systems. Thus, the results revealed that microbubbles could enhance mass transfer in wastewater treatment and be an effective method to improve the degradation of wastewater.

  12. TECHNOLOGY TRANSFER TO U.S. INDEPENDENT OIL AND NATURAL GAS PRODUCERS

    Energy Technology Data Exchange (ETDEWEB)

    Donald F. Duttlinger; E. Lance Cole

    2003-12-15

    The Petroleum Technology Transfer Council (PTTC) continued pursuing its mission of assisting U.S. independent oil and gas producers to make timely, informed technology decisions. Functioning as a cohesive national organization, PTTC has active grassroots programs through its 10 Regional Lead Organizations (RLOs) and 3 Satellite Offices that encompass all of the oil- and natural gas-producing regions in the U.S. Active volunteer leadership from the Board and regional Producer Advisory Groups keeps activities focused on producer's needs. Technical expertise and personal networks of national and regional staff enable PTTC to deliver focused, technology-related information in a manner that is cost and time effective for independents. The organization effectively combines federal funding through the Department of Energy's (DOE) Office of Fossil Energy with matching state and industry funding, forming a unique partnership. This final report summarizes PTTC's accomplishments. In this final fiscal year of the contract, activities exceeded prior annual activity levels by significant percentages. Strategic planning implemented during the year is focusing PTTC's attention on changes that will bear fruit in the future. Networking and connections are increasing PTTC's sphere of influence with both producers and the service sector. PTTC's reputation for unbiased bottom-line information stimulates cooperative ventures. In FY03 PTTC's regions held 169 workshops, drawing 8,616 attendees. There were nearly 25,000 reported contacts. This represents a 38% increase in attendance and 34% increase in contacts as compared to FY02 activity. Repeat attendance at regional workshops, a measure of customer satisfaction and value received, remained strong at 50%. 39% of participants in regional workshops respond ''Yes'' on feedback forms when asked if they are applying technologies based on knowledge gained through PTTC. This feedback

  13. Gas Desorption Behavior of Graphite Anodes in Lithium Ion Secondary Batteries After Adsorption of Electrolytes

    Science.gov (United States)

    Watanabe, Toshinori; Nobuta, Yuji; Yamauchi, Yuji; Hino, Tomoaki; Kubota, Yoshihiro; Ohzeki, Katsutomo

    When it was soaked, more were desorbed In this study, gas desorption behaviors of graphite anode samples after various surface treatments and electrolyte solvent adsorption properties were investigated. The total amount of desorbed gases for the natural graphite samples increased after soaking in propylene carbonate, and increased even further with Raman R value, suggesting that surface defects act as an effective adsorption site for the electrolyte. These findings indicate that surface treatment such as a coating might be an effective remedy to reduce the amount of desorption gases in natural graphite samples. It was also found that the total amount of gas desorption largely decreased with the coating with polymer resin and subsequent heat treatment at 423 K for 12 hours in a medium of air. It is likely that the dominant gas species present in the natural graphite after the electrolyte soaking are dependent on the binding energy and the molecular structure of the electrolyte solvent.

  14. The historical development of heat transfer surfaces for gas-cooled reactors analysed with a simple criterion

    International Nuclear Information System (INIS)

    Leslie, D.C.

    1980-01-01

    The evolution of finned heat transfer surfaces for gas-cooled reactors, from longitudinal through transverse to the sophisticated helical polyzonal and herring-bone fins, is described, and their merits are compared using a simple criterion of heat transfer efficiency. These fins cannot be used in AGR's because of the high neutron absorption and low thermal conductivity of stainless steel, and artificial roughening in the form of ribbing is used instead; the same criterion can be applied to this type of surface. The interest of the material is largely historical. (author)

  15. Effects of wettability on forced convective and gas-liquid two-phase flow heat transfer of mercury

    International Nuclear Information System (INIS)

    Nakagawa, Yusuke; Kawakita, Keisuke; Takenaka, Nobuyuki

    2003-01-01

    High-energy proton beam is irradiated to a target made of high atomic number materials to initiate nuclear spallation reaction to obtain neutron source. A mercury target is now a candidate of the target for the intense proton beam. It is important to study thermal hydraulics of the mercury target. In this study, mercury was used as a working fluid in a stainless steel tube heated by direct electrical current in similar thermal hydraulic situation to the actual target. The effects of mercury wettability on forced convective heat transfer and gas-liquid two-phase flow heat transfer were verified. (author)

  16. UV laser induced proton-transfer of protein molecule in the gas phase produced by droplet-beam laser ablation

    Science.gov (United States)

    Kohno, Jun-ya; Kondow, Tamotsu

    2008-09-01

    Droplet-beam laser-ablation mass-spectrometry was applied for a study of the UV-laser induced proton-transfer reaction of protonated lysozyme hydrated clusters in the gas phase. Protonated lysozyme hydrated clusters were produced by irradiation of an IR laser onto a droplet-beam of an aqueous solution of lysozyme and were subsequently irradiated by a UV laser. It is found that H + and H 3O + are produced through photodissociation of protonated lysozyme hydrated clusters. The mechanism of the proton-transfer reaction is discussed.

  17. Heat transfer in hybrid fibre reinforced concrete-steel composite column exposed to a gas-fired radiant heater

    Science.gov (United States)

    Štefan, R.; Procházka, J.; Novák, J.; Fládr, J.; Wald, F.; Kohoutková, A.; Scheinherrová, L.; Čáchová, M.

    2017-09-01

    In the paper, a gas-fired radiant heater system for testing of structural elements and materials at elevated temperatures is described. The applicability of the system is illustrated on an example of the heat transfer experiment on a hybrid fibre reinforced concrete-steel composite column specimen. The results obtained during the test are closely analysed by common data visualization techniques. The experiment is simulated by a mathematical model of heat transfer, assuming the material data of the concrete determined by in-house measurements. The measured and calculated data are compared and discussed.

  18. Scaling analysis of the coupled heat transfer process in the high-temperature gas-cooled reactor core

    International Nuclear Information System (INIS)

    Conklin, J.C.

    1986-08-01

    The differential equations representing the coupled heat transfer from the solid nuclear core components to the helium in the coolant channels are scaled in terms of representative quantities. This scaling process identifies the relative importance of the various terms of the coupled differential equations. The relative importance of these terms is then used to simplify the numerical solution of the coupled heat transfer for two bounding cases of full-power operation and depressurization from full-system operating pressure for the Fort St. Vrain High-Temperature Gas-Cooled Reactor. This analysis rigorously justifies the simplified system of equations used in the nuclear safety analysis effort at Oak Ridge National Laboratory

  19. Heat transfer technology for internal passages of air-cooled blades for heavy-duty gas turbines.

    Science.gov (United States)

    Weigand, B; Semmler, K; von Wolfersdorf, J

    2001-05-01

    The present review paper, although far from being complete, aims to give an overview about the present state of the art in the field of heat transfer technology for internal cooling of gas turbine blades. After showing some typical modern cooled blades, the different methods to enhance heat transfer in the internal passages of air-cooled blades are discussed. The complicated flows occurring in bends are described in detail, because of their increasing importance for modern cooling designs. A short review about testing of cooling design elements is given, showing the interaction of the different cooling features as well. The special focus of the present review has been put on the cooling of blades for heavy-duty gas turbines, which show several differences compared to aero-engine blades.

  20. Microbial keratitis secondary to unintended poor compliance with scleral gas-permeable contact lenses.

    Science.gov (United States)

    Zimmerman, Aaron B; Marks, Amanda

    2014-01-01

    To report a case of neurotrophic keratitis in which scleral contact lenses improved vision from 20/100 to 20/20, however, due to poor lens care, an incident of microbial keratitis developed. A 64-year-old man with an ocular history of neurotrophic keratitis secondary to herpes simplex in each eye was successfully fit with scleral lenses. He subsequently developed microbial keratitis due to a number of risk factors. The lesion was culture negative, yet was very responsive to treatment with moxifloxacin. The lesion fully healed, and the patient did not suffer additional vision loss. This case demonstrates the ability of scleral lenses to correct visual impairments secondary to poor epithelial integrity and illustrates the importance of the practitioner providing detailed lens care instruction.

  1. Evaluation of Pentachlorophenol Residues in Some Hygienic Papers Prepared from Virgin and Secondary Pulp by Electron Capture Gas Chromatographic Method

    Directory of Open Access Journals (Sweden)

    Behrouz Akbari-adergani

    2016-01-01

    Full Text Available In this study, residual amount of pentachlorophenol (PCP as the most important paper preservative, which is extremely hazardous pollutant, was determined in some tissue papers and napkins. Twenty-five samples of two producing hygienic paper factories prepared from virgin and secondary pulp were analyzed for the presence of trace amount of PCP. The analytical procedure involved direct extraction of PCP from hygienic paper and its determination by gas chromatography with electron capture detection. The statistical results for the analysis of all samples revealed that there were significant differences between mean of PCP in hygienic papers prepared from virgin and secondary pulp (P<0.05. This method gave recoveries of 86-98% for hygienic paper made from virgin pulp and 79-92% for hygienic paper made from secondary pulp. The limit of detection (LOD and limit of quantification (LOQ for PCP were 6.3 and 21.0 mg/kg, respectively. The analytical method has the requisite sensitivity, accuracy, precision and specificity to assay PCP in hygienic papers. This study demonstrates a concern with exposition to PCP considering that hygienic paper is largely consumed in the society.

  2. A how-to approach for a 3D simulation of charge transfer characteristics in a gas electron multiplier (GEM)

    CERN Document Server

    Sharma, A

    1999-01-01

    In this paper a detailed description of how to simulate charge transfer processes in a gaseous device is presented, taking the gas electron multiplier (GEM) as an example. A 3-dimensional simulation of the electric field and avalanche is performed. Results on charge transport are compared to experiment and agree within experimental errors; the avalanche mechanism and positive ion feedback are studied. The procedures used in the simulation are described in detail, and program scripts are appended. (15 refs).

  3. The effects of geometry and operational conditions on gas holdup, liquid circulation and mass transfer in an airlift reactor

    Directory of Open Access Journals (Sweden)

    Gouveia E.R.

    2003-01-01

    Full Text Available In airlift reactors transport phenomena are achieved by pneumatic agitation and circulation occurs in a defined cyclic pattern through a loop. In the present work, the effect of geometrical relations on gas holdup and liquid velocity, and consequently on the gas-liquid mass transfer coefficient, was studied in a 6-liter airlift bioreactor with A D/A R = 0.63; A D, downcomer cross-sectional area, and A R, riser cross-sectional area. Measurements of the volumetric oxygen transfer coefficient (kLa were taken in a water-air system using a modified sulfite oxidation method. Different conditions were examined by varying parameters such as superficial air velocity in the riser (U GR, bottom clearance (d1 and top clearance (d2. It was observed from the experimental results that d1 and d2 have a remarkable effect on kLa values. The effect is due to their influence on gas holdup and liquid velocity, consequently affecting kLa. Superficial air velocity in the riser (U GR ranged from 0.0126 to 0.0440 m.s-1 and kLa varied between 40 to 250 h-1, whereas gas holdup (e reached values up to 0.2. The volumetric oxygen transfer coefficient (kLa, gas holdup in the riser (eR and downcomer (eD and superficial liquid velocity in the riser (U LR for all the geometrical relations were successfully correlated with dimensionless numbers, namely, the Sherwood number (Sh and the Froude number (Fr as well as with geometrical relations such as the bottom space ratio (B = d1/D D and top space ratio (T = (d2 + D D/D D.

  4. Numerical prediction on turbulent heat transfer of a spacer ribbed fuel rod for high temperature gas-cooled reactors

    International Nuclear Information System (INIS)

    Takase, Kazuyuki

    1994-11-01

    The turbulent heat transfer of a fuel rod with three-dimensional trapezoidal spacer ribs for high temperature gas-cooled reactors was analyzed numerically using the k-ε turbulence model, and investigated experimentally using a simulated fuel rod under the helium gas condition of a maximum outlet temperature of 1000degC and pressure of 4MPa. From the experimental results, it found that the turbulent heat transfer coefficients of the fuel rod were 18 to 80% higher than those of a concentric smooth annulus at a region of Reynolds number exceeding 2000. On the other hand, the predicted average Nusselt number of the fuel rod agreed well with the heat transfer correlation obtained from the experimental data within a relative error of 10% with Reynolds number of more than 5000. It was verified that the numerical analysis results had sufficient accuracy. Furthermore, the numerical prediction could clarify quantitatively the effects of the heat transfer augmentation by the spacer rib and the axial velocity increase due to a reduction in the annular channel cross-section. (author)

  5. Experimental and analytical studies of iodine mass transfer from xenon-iodine mixed gas bubble to liquid sodium pool

    International Nuclear Information System (INIS)

    Miyahara, S.; Sagawa, N.; Shimoyama, K.

    1996-01-01

    In the fuel pin failure accident of a liquid metal fast reactor, volatile fission products play an important role in the assessment of radiological consequences. Especially the radioisotopes of elemental iodine are important because of their high volatility and of the low permissible dose to human thyroid. The released iodines are known to be retained in the coolant sodium as sodium iodide due to the chemical affinity between alkali metals and halogens. However, the xenon and krypton released with iodines into the sodium pool as bubbles may influence the reaction rate of iodine with sodium during the bubble rising. So far, the only few experimental results have been available concerning the decontamination factor (DF: the ratio of the initial iodine mass in the mixed gas bubble to the released mass into the cover gas) of iodine in this phenomenon. Therefore, experimental and analytical studies were carried out to study the mass transfer of iodine from a xenon-iodine mixed gas bubble to the liquid sodium pool. In the experiments, the bubble was generated in the sodium pool by cracking a quartz ball which contains the xenon-iodine mixed gas and then, the mixed gas released into the argon cover gas was collected to determine the transferred iodine mass into the pool. A rising velocity of the bubble was measured by Chen-type void sensors arranged vertically in the pool. From the measured rising velocity and another observation of bubble behavior in simulated water experiments, it is found that the generated bubble breaks up into several smaller bubbles of spherical cap type during the rising period. Transferred iodine mass per unit initial bubble volume from the bubble to the sodium pool shows increases with increasing time and the initial iodine concentration. A mass transfer rate obtained by differentiating the transferred iodine mass with respect to the time indicates a rapid decrease just after the bubble generation and a slow decrease for the successive period

  6. Near-surface physics during convection affecting air-water gas transfer

    Science.gov (United States)

    Fredriksson, S. T.; Arneborg, L.; Nilsson, H.; Handler, R. A.

    2016-05-01

    The gas flux at the water surface is affected by physical processes including turbulence from wind shear, microscale wave breaking, large-scale breaking, and convection due to heat loss at the surface. The main route in the parameterizations of the gas flux has been to use the wind speed as a proxy for the gas flux velocity, indirectly taking into account the dependency of the wind shear and the wave processes. The interest in the contributions from convection processes has increased as the gas flux from inland waters (with typically lower wind and sheltered conditions) now is believed to play a substantial role in the air-water gas flux budget. The gas flux is enhanced by convection through the mixing of the mixed layer as well as by decreasing the diffusive boundary layer thickness. The direct numerical simulations performed in this study are shown to be a valuable tool to enhance the understanding of this flow configuration often present in nature.

  7. Gas hold-up and oxygen mass transfer in three pneumatic bioreactors operating with sugarcane bagasse suspensions.

    Science.gov (United States)

    Esperança, M N; Cunha, F M; Cerri, M O; Zangirolami, T C; Farinas, C S; Badino, A C

    2014-05-01

    Sugarcane bagasse is a low-cost and abundant by-product generated by the bioethanol industry, and is a potential substrate for cellulolytic enzyme production. The aim of this work was to evaluate the effects of air flow rate (QAIR), solids loading (%S), sugarcane bagasse type, and particle size on the gas hold-up (εG) and volumetric oxygen transfer coefficient (kLa) in three different pneumatic bioreactors, using response surface methodology. Concentric tube airlift (CTA), split-cylinder airlift (SCA), and bubble column (BC) bioreactor types were tested. QAIR and %S affected oxygen mass transfer positively and negatively, respectively, while sugarcane bagasse type and particle size (within the range studied) did not influence kLa. Using large particles of untreated sugarcane bagasse, the loop-type bioreactors (CTA and SCA) exhibited higher mass transfer, compared to the BC reactor. At higher %S, SCA presented a higher kLa value (0.0448 s−1) than CTA, and the best operational conditions in terms of oxygen mass transfer were achieved for %S 27.0 L min−1. These results demonstrated that pneumatic bioreactors can provide elevated oxygen transfer in the presence of vegetal biomass, making them an excellent option for use in three-phase systems for cellulolytic enzyme production by filamentous fungi.

  8. The missing dimension of knowledge transfer from subsidiaries to headquarters: The case of Oil and Gas companies in CEE region

    Directory of Open Access Journals (Sweden)

    Emil Velinov

    2016-12-01

    Full Text Available The paper identifies knowledge management determinants of knowledge transfer from subsidiaries to headquarters in the top Oil & Gas companies in Central and Eastern Europe as their level of innovations, internationalization and economic importance are emerging. The paper sheds a light not only on the process of knowledge transfer parent-subsidiary but via versa as it is critical in the 21st century for better adapting to specific business needs in certain geographical regions. Thus, this reversed knowledge from subsidiaries to headquarters is critical for the given business sector where the level of innovation and amount of R&D investments are enormous. The study argues that the reversed process of knowledge transfers from subsidiary to parent company is positively related to company performance and business diversification. Nowadays the knowledge formed in the subsidiaries of Multinational Corporations (MNCs is transferred to headquarters by investing in R&D centres, building new exploration and testing sites abroad. In the reversed knowledge transfer process we can identify main challenges, which are very critical to analyse and determine the exact process.

  9. Numerical modelling of methane oxidation efficiency and coupled water-gas-heat reactive transfer in a sloping landfill cover.

    Science.gov (United States)

    Feng, S; Ng, C W W; Leung, A K; Liu, H W

    2017-10-01

    Microbial aerobic methane oxidation in unsaturated landfill cover involves coupled water, gas and heat reactive transfer. The coupled process is complex and its influence on methane oxidation efficiency is not clear, especially in steep covers where spatial variations of water, gas and heat are significant. In this study, two-dimensional finite element numerical simulations were carried out to evaluate the performance of unsaturated sloping cover. The numerical model was calibrated using a set of flume model test data, and was then subsequently used for parametric study. A new method that considers transient changes of methane concentration during the estimation of the methane oxidation efficiency was proposed and compared against existing methods. It was found that a steeper cover had a lower oxidation efficiency due to enhanced downslope water flow, during which desaturation of soil promoted gas transport and hence landfill gas emission. This effect was magnified as the cover angle and landfill gas generation rate at the bottom of the cover increased. Assuming the steady-state methane concentration in a cover would result in a non-conservative overestimation of oxidation efficiency, especially when a steep cover was subjected to rainfall infiltration. By considering the transient methane concentration, the newly-modified method can give a more accurate oxidation efficiency. Copyright © 2017. Published by Elsevier Ltd.

  10. Advanced fingerprinting of high-quality cocoa: Challenges in transferring methods from thermal to differential-flow modulated comprehensive two dimensional gas chromatography.

    Science.gov (United States)

    Magagna, Federico; Liberto, Erica; Reichenbach, Stephen E; Tao, Qingping; Carretta, Andrea; Cobelli, Luigi; Giardina, Matthew; Bicchi, Carlo; Cordero, Chiara

    2018-02-09

    The possibility to transfer methods from thermal to differential-flow modulated comprehensive two-dimensional gas chromatographic (GC×GC) platforms opens interesting perspectives for routine analysis of complex samples. Flow modulated platforms avoid the use of cryogenics, thereby simplifying laboratory operations and analyst supervision during intensive analytical sessions. This study evaluates the feasibility of transferring a fingerprinting method capable of classifying and discriminating cocoa samples based on the volatiles fraction composition according to their origin and processing steps. Previously developed principles of GC×GC method translation are applied to an original fingerprinting method, developed for a loop-type thermal modulated GC×GC-MS system, to engineer a method for a reverse-injection differential flow modulated platform (GC×2GC-MS/FID) with a dual-parallel secondary column and dual detection. Effective method translation preserves analytes elution order, 1 D resolution, and 2D pattern coherence. The experimental results confirm the feasibility of translating fingerprinting method conditions while preserving the informative power of 2D peak patterns for sample classification and discrimination. Correct translation enables effective transfer of metadata (e.g., compound names and MS fragmentation patterns) by automatic template transformation and matching from the original/reference method to its translated counterpart. Although the adoption of a narrow bore (i.e. 0.1mm d c ) column in the first-dimension enabled operation under close-to-optimal conditions with the differential-flow modulation platform, due to the dual-parallel columns in the second-dimension, it resulted in lower overall method sensitivity. Nevertheless, fingerprinting accuracy was preserved and most of the key-aroma compounds and technological markers were effectively mapped, thus limiting the loss of fingerprinting information. Copyright © 2017 Elsevier B.V. All rights

  11. Simulating progressive social transfers. Gas subsidies and solidarity bonds in Ecuador

    International Nuclear Information System (INIS)

    Cuesta, J.; Ponce, J.; Leon, M.

    2004-02-01

    After two decades of neglect, social expending has become a cornerstone in the current fight against poverty in Ecuador. Ecuador is presently considering the elimination of regressive gas subsidies and the shift of these resources into pro-poor targeted Solidarity Bonds. Great distributive gains are expected from this reform. There are, however, a number of considerations that may prevent this policy shift from obtaining substantial poverty and equality gains. Despite their regressivity, implicit gas subsidies still represent a considerable proportion of total household consumption among poor households. Also, solidarity bonds siphon off a substantial share of their total benefits to middle income groups. This paper estimates the redistributive consequences of policy reforms on gas subsidies and solidarity bonds in Ecuador. A simulation methodology estimates both direct and indirect (labour-driven) distributive effects of four alternative scenarios: (1) total elimination of gas subsidies; (2) selective elimination of gas subsidies among non-poor households; (3) total elimination of gas subsidies and shift of resources to solidarity bonds targeted to the poor; (4) selective elimination of gas subsidies and shift of resources to solidarity bonds targeted to the poor. Estimates confirm that the redistributive gains from these reforms are rather small both for poverty and inequality. Incentives to work following the elimination of subsidies compensate, or even outdo, immediate poverty rises. Also, the elimination of gas subsidies without further expansion of subsidy bonds will unambiguously increase poverty in Ecuador between one and one and a half percent points

  12. Oscillatory conductive heat transfer for a fiber in an ideal gas

    Science.gov (United States)

    Kuntz, H. L.; Perreira, N. D.

    1985-01-01

    A description of the thermal effects created by placing a cylindrical fiber in an inviscid, ideal gas, through which an acoustic wave propagates, is presented. The fibers and the gas have finite heat capacities and thermal conductivities. Expressions for the temperature distribution in the gas and in the material are determined. The temperature distribution is caused by pressure oscillations in the gas which, in turn, are caused by the passage of an acoustic wave. The relative value of a dimensionless parameter is found to be indicative of whether the exact or approximate equations should be used in the solution. This parameter is a function of the thermal conductivities and heat capacities of the fiber and gas, the acoustic frequency, and the fiber diameter.

  13. Synthesis of highly c-oriented ZIF-69 membranes by secondary growth and their gas permeation properties

    KAUST Repository

    Liu, Yunyang

    2011-09-01

    A seeded growth procedure was successfully developed to synthesize highly c-oriented and well-intergrown zeolitic imidazolate framework-69 (ZIF-69) membranes on porous α-alumina substrates. The synthesis conditions were optimized both for seed preparation and for secondary growth. For seeding, a facile method was developed to prepare smaller and flat ZIF-69 microcrystals in order to make thin and c-oriented seed layers. While for secondary growth, a synthesis condition that favored the growth along the c-direction was chosen in order to form highly c-oriented ZIF-69 membranes after growth. As a result, the majority of ZIF-69 grains inside the membrane have their straight channels along the crystallographic c-axis aligned perpendicularly to the substrate surface. Such alignment was confirmed by both XRD and pole figure analysis. The mixture-gas separation studies that were carried out at room temperature and 1atm gave separation factors of 6.3, 5.0, 4.6 for CO2/N2, CO2/CO and CO2/CH4 respectively, and a permeance of ∼1.0×10-7molm-2s-1Pa-1 for CO2 in almost all mixtures. Both the separation factor and permeance were better than the performance of the ZIF-69 membranes prepared by the in situ solvothermal method due to improvement in the membrane microstructure by the seeded growth method. © 2011 Elsevier B.V.

  14. Validation of ANSYS CFX for gas and liquid metal flows with conjugate heat transfer within the European project THINS

    Energy Technology Data Exchange (ETDEWEB)

    Papukchiev, A., E-mail: angel.papukchiev@grs.de; Buchholz, S.

    2017-02-15

    Highlights: • ANSYS CFX is validated for gas and liquid metal flows. • L-STAR and TALL-3D experiments are simulated. • Complex flow and heat transfer phenomena are modelled. • Conjugate heat transfer has to be considered in CFD analyses. - Abstract: Within the FP7 European project THINS (Thermal Hydraulics of Innovative Nuclear Systems), numerical tools for the simulation of the thermal-hydraulics of next generation rector systems were developed, applied and validated for innovative coolants. The Gesellschaft fuer Anlagen- und Reaktorsicherheit (GRS) gGmbH participated in THINS with activities related to the development and validation of computational fluid dynamics (CFD) and coupled System Thermal Hydraulics (STH) – CFD codes. High quality measurements from the L-STAR and TALL-3D experiments were used to assess the numerical results. Two-equation eddy viscosity and scale resolving turbulence models were used in the validation process of ANSYS CFX for gas and liquid metal flows with conjugate heat transfer. This paper provides a brief overview on the main results achieved at GRS within the project.

  15. Observing Proton Transfer Reactions Inside the MALDI Plume: Experimental and Theoretical Insight into MALDI Gas-Phase Reactions

    Science.gov (United States)

    Mirabelli, Mario F.; Zenobi, Renato

    2017-08-01

    We evaluated the contribution of gas-phase in-plume proton transfer reactions to the formation of protonated and deprotonated molecules in the MALDI process. A split sample holder was used to separately deposit two different samples, which avoids any mixing during sample preparation. The two samples were brought very close to each other and desorbed/ionized by the same laser pulse. By using a combination of deuterated and non-deuterated matrices, it was possible to observe exclusively in-plume proton transfer processes. The hydrogen/deuterium exchange (HDX) kinetics were evaluated by varying the delayed extraction (DE) time, allowing the desorbed ions and neutrals to interact inside the plume for a variable period of time before being extracted and detected. Quantum mechanical calculations showed that the HDX energy barriers are relatively low for such reactions, corroborating the importance of gas-phase proton transfer in the MALDI plume. The experimental results, supported by theoretical simulations, confirm that the plume is a very reactive environment, where HDX reactions could be observed from 0 ns up to 400 ns after the laser pulse. These results could be used to evaluate the relevance of previously proposed (and partially conflicting) ionization models for MALDI.

  16. Investigations of the gas-side heat transfer and flow characteristics of steam generators in AGR stations

    International Nuclear Information System (INIS)

    Lis, J.

    1984-01-01

    This paper describes the experimental and analytical investigations of the gas-side heat transfer and flow characteristics of steam generators in the AGR stations carried out by CERL. The majority of the experimental work on heat transfer and flow characteristics of close-packed tube arrangements in cross-flow of gases is carried out in a pressurised heat exchanger rig. The rig is operated on-line by a dedicated PDP 11/40 computer over the range of Reynolds number 10 4 to 3x10 5 . Atmospheric wind tunnels employing either small or large scale models of the specific sections of steam generators are used for a variety of supplementary and development studies. Various measurements techniques and, in particular, LDA and hot wire anemometry employed in these studies are described. The more important aspects of various investigations are illustrated by typical results. In order to ensure the efficient operation and integrity of steam generators under asymmetric boundary conditions a MIX suite of 2-dimensional codes has been developed. The codes calculate the gas and water/steam flow and temperature distributions in each channel of the steam generator taking into account thermal mixing in the gas as it passes through the generator. Application of the MIX codes to the solution of various operational problems is illustrated by typical examples and the continuing exercise of validating the codes against plant operational data is discussed. (author)

  17. Influence analysis of secondary O-ring seals in dynamic behavior of spiral groove gas face seals

    Science.gov (United States)

    Hu, Songtao; Huang, Weifeng; Liu, Xiangfeng; Wang, Yuming

    2016-05-01

    The current research on secondary O-ring seals used in mechanical seals has begun to focus on their dynamic properties. However, detailed analysis of the dynamic properties of O-ring seals in spiral groove gas face seals is lacking. In particular a transient study and a difference analysis of steady-state and transient performance are imperative. In this paper, a case study is performed to gauge the effect of secondary O-ring seals on the dynamic behavior (steady-state performance and transient performance) of face seals. A numerical finite element method (FEM) model is developed for the dynamic analysis of spiral groove gas face seals with a flexibly mounted stator in the axial and angular modes. The rotor tilt angle, static stator tilt angle and O-ring damping are selected to investigate the effect of O-ring seals on face seals during stable running operation. The results show that the angular factor can be ignored to save time in the simulation under small damping or undamped conditions. However, large O-ring damping has an enormous effect on the angular phase difference of mated rings, affecting the steady-state performance of face seals and largely increasing the possibility of face contact that reduces the service life of face seals. A pressure drop fluctuation is carried out to analyze the effect of O-ring seals on the transient performance of face seals. The results show that face seals could remain stable without support stiffness and O-ring damping during normal stable operation but may enter a large-leakage state when confronting instantaneous fluctuations. The oscillation-amplitude shortening effect of O-ring damping on the axial mode is much greater than that on the angular modes and O-ring damping prefers to cater for axial motion at the cost of angular motion. This research proposes a detailed dynamic-property study of O-ring seals in spiral groove gas face seals, to assist in the design of face seals.

  18. Product distributions for some thermal energy charge transfer reactions of rare gas ions

    Science.gov (United States)

    Anicich, V. G.; Laudenslager, J. B.; Huntress, W. T., Jr.; Futrell, J. H.

    1977-01-01

    Ion cyclotron resonance methods were used to measure the product distributions for thermal-energy charge-transfer reactions of He(+), Ne(+), and Ar(+) ions with N2, O2, CO, NO, CO2, and N2O. Except for the He(+)-N2 reaction, no molecular ions were formed by thermal-energy charge transfer from He(+) and Ne(+) with these target molecules. The propensity for dissociative ionization channels in these highly exothermic charge-transfer reactions at thermal energies contrasts with the propensity for formation of parent molecular ions observed in photoionization experiments and in high-energy charge-transfer processes. This difference is explained in terms of more stringent requirements for energy resonance and favorable Franck-Condon factors at thermal ion velocities.

  19. Estimating of gas transfer velocity using triple isotopes of dissolved oxygen.

    Digital Repository Service at National Institute of Oceanography (India)

    Sarma, V.V.S.S.; Abe, O.; Honda, M.; Saino, T.

    The atmosphere-ocean exchange of climatically important gases is determined by the transfer velocity (k) and concentration gradient across the interface. Based on observations in the northwestern subarctic Pacific and Sagami Bay, we report here...

  20. Rotational Energy Transfer of N2 Gas Determined Using a New Ab Initio Potential Energy Surface

    Science.gov (United States)

    Huo, Winifred M.; Stallcop, James R.; Partridge, Harry; Langhoff, Stephen R. (Technical Monitor)

    1997-01-01

    Rotational energy transfer between two N2 molecules is a fundamental process of some importance. Exchange is expected to play a role, but its importance is somewhat uncertain. Rotational energy transfer cross sections of N2 also have applications in many other fields including modeling of aerodynamic flows, laser operations, and linewidth analysis in nonintrusive laser diagnostics. A number of N2-N2 rigid rotor potential energy surface (PES) has been reported in the literature.

  1. Heat transfer by a mixture of a liquid and a gas in forced turbulent convection with slight vaporisation of the liquid phase (1961)

    International Nuclear Information System (INIS)

    Huyghe, J.; Mondin, H.; Villeneuve, J.

    1961-01-01

    The vaporisation of an appreciable quantity of a liquid in a turbulent gas stream explains the increase in the heat capacity of the fluid and the improvement in the heat-transfer coefficient. The present study makes it clear that even with a very slight vaporisation, the transfer coefficient can be much increased, the pressure drop remaining nearly constant. (authors) [fr

  2. Mass transfer with complex chemical reactions in gas-liquid systems: two-step reversible reactions with unit stoichiometric and kinetic orders

    NARCIS (Netherlands)

    Vas bhat, R.D.; Kuipers, J.A.M.; Versteeg, Geert

    2000-01-01

    An absorption model to study gas¿liquid mass transfer accompanied by reversible two-step reactions in the liquid phase has been presented. This model has been used to determine mass transfer rates, enhancement factors and concentration profiles over a wide range of process conditions. Although

  3. Heat transfer efficiency evaluation for outward and inward multi-flame-hole gas burner

    Science.gov (United States)

    Morita, Shin-ichi; Hayamizu, Yasutaka; Katayama, Takashi; Inaba, Hideo

    2012-04-01

    The purpose of this study is to understand the factor that influence the heating efficiency of the outward and inward multi-hole gas burner. The flame-hole angle and the distance from flame hole to heating object are chosen as the experimental parameters. The measurement of the flame temperature distribution is carried out on each experimental condition. The observation of combustion flame, by the Schlieren method, is done from the purpose to understand the combustion phenomenon on the heating efficiency. LPG (Liquefied petroleum gas) is used for the test fuel gas. The compositions of LPG are propane 97.5vol%, butane 0.2vol% and methane + ethylene 2.3vol%. The optimum ranges of the flame-hole angle and the distance from flame hole to heating object are clarified. The experimental correlation equations for the outward and inward multi-flame-hole gas burner are proposed.

  4. Mass transfer and chemical reaction in gas-liquid-liquid systems

    NARCIS (Netherlands)

    Brilman, Derk Willem Frederik

    1998-01-01

    Gas-liquid-liquid reaction systems may be encountered in several important fields of application as e.g. hydroformylation, alkylation, carboxylation, polymerisation, hydrometallurgy, biochemical processes and fine chemicals manufacturing. However, the reaction engineering aspects of these systems

  5. Mixed convection heat transfer between a steam / non-condensable gas mixture and an inclined finned tube bundle

    Energy Technology Data Exchange (ETDEWEB)

    Cachard, F. de; Lomperski, S.; Monauni, G.R. [Paul Scherrer Inst. (PSI), Villigen (Switzerland). Lab. for Thermal-Hydraulics

    1999-07-01

    An experimental and analytical program was performed at PSI to study the performance of a finned-tube condenser in the presence of non-condensable gases at low gas mass fluxes. The model developed for this application includes mixed convection heat transfer between the vapour/non-condensable mixture and the finned-tubes, heat conduction through the fins and tubes, and evaporative heat transfer inside the tubes. The finned-tubes condenser model has been assessed against data obtained at the PSI LINX facility with two test condensers. For the 62 LINX experiments performed, the model predictions are very good, i.e., less than 10 % standard deviation between experimental and predicted results. (authors)

  6. Numerical analysis of gas transfer by natural convection in a fluid saturated porous medium

    International Nuclear Information System (INIS)

    Akbal, S.; Filiz Baytas, A.

    2005-01-01

    The concentration distribution of a radioactive gas in a square porous cavity is investigated in this study. The decay of the radioactive gas is taken into account in the concentration equation. The governing equations are solved using alternating direction implicit method (ADI) and Finite volume method. Numerical results for velocity and concentration profiles are presented for an extensive range of parameter like Grashof number (Gr c ), Schmidt number (Sc) and the non-dimensional constant of radioactive decay. (authors)

  7. Numerical analysis of gas transfer by natural convection in a fluid saturated porous medium

    Energy Technology Data Exchange (ETDEWEB)

    Akbal, S. [Cekmece Nuclear Research and Training Center (Turkey); Filiz Baytas, A. [Istanbul Technical Univ. (Turkey). Inst. for Energy

    2005-07-01

    The concentration distribution of a radioactive gas in a square porous cavity is investigated in this study. The decay of the radioactive gas is taken into account in the concentration equation. The governing equations are solved using alternating direction implicit method (ADI) and Finite volume method. Numerical results for velocity and concentration profiles are presented for an extensive range of parameter like Grashof number (Gr{sub c}), Schmidt number (Sc) and the non-dimensional constant of radioactive decay. (authors)

  8. Wintertime Air-Sea Gas Transfer Rates and Air Injection Fluxes at Station Papa in the NE Pacific

    Science.gov (United States)

    McNeil, C.; Steiner, N.; Vagle, S.

    2008-12-01

    In recent studies of air-sea fluxes of N2 and O2 in hurricanes, McNeil and D'Asaro (2007) used a simplified model formulation of air-sea gas flux to estimate simultaneous values of gas transfer rate, KT, and air injection flux, VT. The model assumes air-sea gas fluxes at high to extreme wind speeds can be explained by a combination of two processes: 1) air injection, by complete dissolution of small bubbles drawn down into the ocean boundary layer by turbulent currents, and 2) near-surface equilibration processes, such as occurs within whitecaps. This analysis technique relies on air-sea gas flux estimates for two gases, N2 and O2, to solve for the two model parameters, KT and VT. We present preliminary results of similar analysis of time series data collected during winter storms at Station Papa in the NE Pacific during 2003/2004. The data show a clear increase in KT and VT with increasing NCEP derived wind speeds and acoustically measured bubble penetration depth.

  9. Magnetic Emissions Reduction by Varying Secondary Side Capacitor for Ferrite Geometry based Series-Parallel Topology Wireless Power Transfer to Vehicles

    DEFF Research Database (Denmark)

    Batra, Tushar; Schaltz, Erik

    2014-01-01

    power at unity power factor at expense of higher primary current and bigger capacitors on both sides. This reduction increases with increase in the secondary capacitor till a certain maximum point and then decreases. Hence this new design method can be very useful in reducing the magnetic emissions......Magnetic fields in surroundings of wireless power transfer system depends upon the two coil currents, distance from the coils and space angle between the two coil fields in steady state conditions. Increase in value of the secondary capacitor leads to a phase shift between the two currents...... and as a result magnetic emissions are reduced. But the side effect of this phase shift is reduction in the power transfer capability of the system. This paper proposes a new design method with help of theory and simulations which shows that it is possible to reduce the magnetic emissions and transmit the same...

  10. Single Electron Transfer-Promoted Photochemical Reactions of Secondary N-Trimethylsilylmethyl-N-benzylamines Leading to Aminomethylation of Fullerene C60.

    Science.gov (United States)

    Lim, Suk Hyun; Jeong, Ho Cheol; Sohn, Youngku; Kim, Young-Il; Cho, Dae Won; Woo, Hee-Jae; Shin, Ik-Soo; Yoon, Ung Chan; Mariano, Patrick S

    2016-03-18

    Photoreactions between C60 and secondary N-trimethylsilylmethyl-N-benzylamines were explored to evaluate the feasibility of a new method for secondary aminomethylation of electron acceptors. The results show that photoreactions of C60 with these secondary amines in 10% EtOH-toluene occur to form aminomethyl-1,2-dihydrofullerenes predominantly through a pathway involving single electron transfer (SET)-promoted formation of secondary aminium radicals followed by preferential loss of the α-trimethylsilyl group. The aminomethyl radicals formed in this manner then couple with C60 or C60(•-) to form radical or anion precursors of the aminomethyl-1,2-dihydrofullerenes. In contrast to thermal and photochemical strategies developed previously, the new SET photochemical approach using α-trimethylsilyl-substituted secondary amines is both mild and efficient, and as a result, it should be useful in broadening the library of substituted fullerenes. Moreover, the results should have an impact on the design of SET-promoted C-C bond forming reactions. Specifically, introduction of an α-trimethylsilyl group leads to a change in the chemoselectivity of SET-promoted reactions of secondary amines with acceptors that typically favor aminium radical N-H deprotonation, leading to N-C bond formation. Finally, symmetric and unsymmetric fulleropyrrolidines are also generated in yields that are highly dependent on the electronic properties of arene ring substituents in amines, irradiation time, and solvent.

  11. Dose and linear energy transfer distributions of primary and secondary particles in carbon ion radiation therapy: A Monte Carlo simulation study in water.

    Science.gov (United States)

    Johnson, Daniel; Chen, Yong; Ahmad, Salahuddin

    2015-01-01

    The factors influencing carbon ion therapy can be predicted from accurate knowledge about the production of secondary particles from the interaction of carbon ions in water/tissue-like materials, and subsequently the interaction of the secondary particles in the same materials. The secondary particles may have linear energy transfer (LET) values that potentially increase the relative biological effectiveness of the beam. Our primary objective in this study was to classify and quantify the secondary particles produced, their dose averaged LETs, and their dose contributions in the absorbing material. A 1 mm diameter carbon ion pencil beam with energies per nucleon of 155, 262, and 369 MeV was used in a geometry and tracking 4 Monte Carlo simulation to interact in a 27 L water phantom containing 3000 rectangular detector voxels. The dose-averaged LET and the dose contributions of primary and secondary particles were calculated from the simulation. The results of the simulations show that the secondary particles that contributed a major dose component had LETs 600 keV/µm contributed only <0.3% of the dose.

  12. Dose and linear energy transfer distributions of primary and secondary particles in carbon ion radiation therapy: A Monte Carlo simulation study in water

    Directory of Open Access Journals (Sweden)

    Daniel Johnson

    2015-01-01

    Full Text Available The factors influencing carbon ion therapy can be predicted from accurate knowledge about the production of secondary particles from the interaction of carbon ions in water/tissue-like materials, and subsequently the interaction of the secondary particles in the same materials. The secondary particles may have linear energy transfer (LET values that potentially increase the relative biological effectiveness of the beam. Our primary objective in this study was to classify and quantify the secondary particles produced, their dose averaged LETs, and their dose contributions in the absorbing material. A 1 mm diameter carbon ion pencil beam with energies per nucleon of 155, 262, and 369 MeV was used in a geometry and tracking 4 Monte Carlo simulation to interact in a 27 L water phantom containing 3000 rectangular detector voxels. The dose-averaged LET and the dose contributions of primary and secondary particles were calculated from the simulation. The results of the simulations show that the secondary particles that contributed a major dose component had LETs 600 keV/µm contributed only <0.3% of the dose.

  13. Analysing the Distribution of Questions in the Gas Law Chapters of Secondary and Introductory College Chemistry Textbooks from the United States

    Science.gov (United States)

    Gillette, Gabriel; Sanger, Michael J.

    2014-01-01

    This study analysed the distribution of questions from the gas law chapters of four high school and four college chemistry textbooks based on six variables--Book Type (secondary "versus" introductory college), Cognitive Skill (lower-order "versus" higher-order), Question Format (calculation "versus" multiple-choice…

  14. Modeling the gas-particle partitioning of secondary organic aerosol: the importance of liquid-liquid phase separation

    Directory of Open Access Journals (Sweden)

    A. Zuend

    2012-05-01

    Full Text Available The partitioning of semivolatile organic compounds between the gas phase and aerosol particles is an important source of secondary organic aerosol (SOA. Gas-particle partitioning of organic and inorganic species is influenced by the physical state and water content of aerosols, and therefore ambient relative humidity (RH, as well as temperature and organic loading levels. We introduce a novel combination of the thermodynamic models AIOMFAC (for liquid mixture non-ideality and EVAPORATION (for pure compound vapor pressures with oxidation product information from the Master Chemical Mechanism (MCM for the computation of gas-particle partitioning of organic compounds and water. The presence and impact of a liquid-liquid phase separation in the condensed phase is calculated as a function of variations in relative humidity, organic loading levels, and associated changes in aerosol composition. We show that a complex system of water, ammonium sulfate, and SOA from the ozonolysis of α-pinene exhibits liquid-liquid phase separation over a wide range of relative humidities (simulated from 30% to 99% RH. Since fully coupled phase separation and gas-particle partitioning calculations are computationally expensive, several simplified model approaches are tested with regard to computational costs and accuracy of predictions compared to the benchmark calculation. It is shown that forcing a liquid one-phase aerosol with or without consideration of non-ideal mixing bears the potential for vastly incorrect partitioning predictions. Assuming an ideal mixture leads to substantial overestimation of the particulate organic mass, by more than 100% at RH values of 80% and by more than 200% at RH values of 95%. Moreover, the simplified one-phase cases stress two key points for accurate gas-particle partitioning calculations: (1 non-ideality in the condensed phase needs to be considered and (2 liquid-liquid phase separation is a consequence of considerable deviations

  15. Primary gas- and particle-phase emissions and secondary organic aerosol production from gasoline and diesel off-road engines.

    Science.gov (United States)

    Gordon, Timothy D; Tkacik, Daniel S; Presto, Albert A; Zhang, Mang; Jathar, Shantanu H; Nguyen, Ngoc T; Massetti, John; Truong, Tin; Cicero-Fernandez, Pablo; Maddox, Christine; Rieger, Paul; Chattopadhyay, Sulekha; Maldonado, Hector; Maricq, M Matti; Robinson, Allen L

    2013-12-17

    Dilution and smog chamber experiments were performed to characterize the primary emissions and secondary organic aerosol (SOA) formation from gasoline and diesel small off-road engines (SOREs). These engines are high emitters of primary gas- and particle-phase pollutants relative to their fuel consumption. Two- and 4-stroke gasoline SOREs emit much more (up to 3 orders of magnitude more) nonmethane organic gases (NMOGs), primary PM and organic carbon than newer on-road gasoline vehicles (per kg of fuel burned). The primary emissions from a diesel transportation refrigeration unit were similar to those of older, uncontrolled diesel engines used in on-road vehicles (e.g., premodel year 2007 heavy-duty diesel trucks). Two-strokes emitted the largest fractional (and absolute) amount of SOA precursors compared to diesel and 4-stroke gasoline SOREs; however, 35-80% of the NMOG emissions from the engines could not be speciated using traditional gas chromatography or high-performance liquid chromatography. After 3 h of photo-oxidation in a smog chamber, dilute emissions from both 2- and 4-stroke gasoline SOREs produced large amounts of semivolatile SOA. The effective SOA yield (defined as the ratio of SOA mass to estimated mass of reacted precursors) was 2-4% for 2- and 4-stroke SOREs, which is comparable to yields from dilute exhaust from older passenger cars and unburned gasoline. This suggests that much of the SOA production was due to unburned fuel and/or lubrication oil. The total PM contribution of different mobile source categories to the ambient PM burden was calculated by combining primary emission, SOA production and fuel consumption data. Relative to their fuel consumption, SOREs are disproportionately high total PM sources; however, the vastly greater fuel consumption of on-road vehicles renders them (on-road vehicles) the dominant mobile source of ambient PM in the Los Angeles area.

  16. The effect of gas-phase polycyclic aromatic hydrocarbons on the formation and properties of biogenic secondary organic aerosol particles

    Energy Technology Data Exchange (ETDEWEB)

    Zelenyuk, Alla [Pacific Northwest National Laboratory; USA; Imre, Dan G. [Imre Consulting; USA; Wilson, Jacqueline [Pacific Northwest National Laboratory; USA; Bell, David M. [Pacific Northwest National Laboratory; USA; Suski, Kaitlyn J. [Pacific Northwest National Laboratory; USA; Shrivastava, Manish [Pacific Northwest National Laboratory; USA; Beránek, Josef [Pacific Northwest National Laboratory; USA; Alexander, M. Lizabeth [Pacific Northwest National Laboratory; USA; Kramer, Amber L. [Department of Chemistry; Oregon State University; USA; Massey Simonich, Staci L. [Department of Chemistry; Oregon State University; USA; Environmental and Molecular Toxicology; Oregon State University

    2017-01-01

    When secondary organic aerosol (SOA) particles are formed by ozonolysis in the presence of gas-phase polycyclic aromatic hydrocarbons (PAHs), their formation and properties are significantly different from SOA particles formed without PAHs. For all SOA precursors and all PAHs, discussed in this study, the presence of the gas-phase PAHs during SOA formation significantly affects particle mass loadings, composition, growth, evaporation kinetics, and viscosity. SOA particles formed in the presence of PAHs have, as part of their compositions, trapped unreacted PAHs and products of heterogeneous reactions between PAHs and ozone. Compared to ‘pure’ SOA particles, these particles exhibit slower evaporation kinetics, have higher fractions of non-volatile components, like oligomers, and higher viscosities, assuring their longer atmospheric lifetimes. In turn, the increased viscosity and decreased volatility provide a shield that protects PAHs from chemical degradation and evaporation, allowing for the long-range transport of these toxic pollutants. The magnitude of the effect of PAHs on SOA formation is surprisingly large. The presence of PAHs during SOA formation increases mass loadings by factors of two to five, and particle number concentrations, in some cases, by more than a factor of 100. Increases in SOA mass, particle number concentrations, and lifetime have important implications to many atmospheric processes related to climate, weather, visibility, and human health, all of which relate to the interactions between biogenic SOA and anthropogenic PAHs. The synergistic relationship between SOA and PAHs presented here are clearly complex and call for future research to elucidate further the underlying processes and their exact atmospheric implications.

  17. Multi-generation gas-phase oxidation, equilibrium partitioning, and the formation and evolution of secondary organic aerosol

    Directory of Open Access Journals (Sweden)

    C. D. Cappa

    2012-10-01

    Full Text Available A new model of secondary organic aerosol (SOA formation is developed that explicitly takes into account multi-generational oxidation as well as fragmentation of gas-phase compounds, and assumes equilibrium gas-particle partitioning. The model framework requires specification of a limited number of tunable parameters to describe the kinetic evolution of SOA mass, the average oxygen-to-carbon atomic ratio and the mean particle volatility as oxidation proceeds. These parameters describe (1 the relationship between oxygen content and volatility, (2 the probability of fragmentation and (3 the amount of oxygen added per reaction. The time-evolution and absolute value of the simulated SOA mass depends sensitively on all tunable parameters. Of the tunable parameters, the mean O : C is most sensitive to the oxygen/volatility relationship, exhibiting only a weak dependence on the other relationships. The model mean particle O : C produced from a given compound is primarily controlled by the number of carbon atoms comprising the SOA precursor, with some sensitivity to the specified oxygen/volatility relationship. The model is tested against laboratory measurements of time-dependent SOA formation from the photooxidation of α-pinene and n-pentadecane and performs well (after tuning. The model can also accurately simulate the carbon-number dependence of aerosol yields previously observed for oxidation of straight-chain alkanes. This model may provide a generalized framework for the interpretation of laboratory SOA formation experiments in which explicit consideration of multiple-generations of products is required, which is true for all photo-oxidation experiments.

  18. TRACE assessment on local condensation heat transfer in presence of non-condensable gas inside a vertical tube

    Energy Technology Data Exchange (ETDEWEB)

    Cho, Yong Jin; Ahn, Seung Hoon; Kim, Kap; Kim, Hho Jung [Korea Institute of Nuclear Safety, Daejeon (Korea, Republic of)

    2009-07-01

    TRACE assessment was performed to investigate local condensation heat transfer coefficients in the presence of a noncondensable gas inside a vertical tube. The data obtained from pure steam and steam/nitrogen mixture condensation experiments were compared to study the effects of noncondensable nitrogen gas on the annular film condensation phenomena. The condenser tube had a small inner diameter of 13mm (about 1/2-in.) and this experiment had been performed to prove the effectiveness of the a Passive Residual Heat Removal System (PRHRS) of SMART (System-integrated Modular Advanced ReacTor), which is a small modular integral-type pressurized water reactor that is developed for the dual purposes of seawater desalination and small-scaled power generation. In the case of nitrogen presence, TRACE results show the converged results but the prediction is different from experimental data. The candidate reasons can be focused on several models, such as the film thickness calculation, surface area, and condensation heat transfer correlations, etc. In the case of pure steam condensation case, TRACE results shows large oscillations and do not converge. This should be investigated in detail to identify the reason. Until now, the oscillation in thermal hydraulic parameters results from the film thickness calculation and surface area calculation. For future works, the whole sets of the experiment will be assessed and the improvement of TRACE will be performed.

  19. Method translation and full metadata transfer from thermal to differential flow modulated comprehensive two dimensional gas chromatography: Profiling of suspected fragrance allergens.

    Science.gov (United States)

    Cordero, Chiara; Rubiolo, Patrizia; Reichenbach, Stephen E; Carretta, Andrea; Cobelli, Luigi; Giardina, Matthew; Bicchi, Carlo

    2017-01-13

    The possibility to transfer methods from thermal to differential-flow modulated comprehensive two-dimensional gas chromatographic (GC×GC) platforms is of high interest to improve GC×GC flexibility and increase the compatibility of results from different platforms. The principles of method translation are here applied to an original method, developed for a loop-type thermal modulated GC×GC-MS/FID system, suitable for quali-quantitative screening of suspected fragrance allergens. The analysis conditions were translated to a reverse-injection differential flow modulated platform (GC×2GC-MS/FID) with a dual-parallel secondary column and dual detection. The experimental results, for a model mixture of suspected volatile allergens and for raw fragrance mixtures of different composition, confirmed the feasibility of translating methods by preserving 1 D elution order, as well as the relative alignment of resulting 2D peak patterns. A correct translation produced several benefits including an effective transfer of metadata (compound names, MS fragmentation pattern, response factors) by automatic template transformation and matching from the original/reference method to its translated counterpart. The correct translation provided: (a) 2D pattern repeatability, (b) MS fragmentation pattern reliability for identity confirmation, and (c) comparable response factors and quantitation accuracy within a concentration range of three orders of magnitude. The adoption of a narrow bore (i.e. 0.1mm d c ) first-dimension column to operate under close-to-optimal conditions with the differential-flow modulation GC×GC platform was also advantageous in halving the total analysis under the translated conditions. Copyright © 2016 Elsevier B.V. All rights reserved.

  20. Study of the effect of noncondensable gas on heat transfer phenomena in horizontal steam generator of pactel facility with CATHARE2 V1.5a

    International Nuclear Information System (INIS)

    Sarrette, C.; Puustinen, M.; Bestion, D.

    2001-01-01

    Lappeenranta University of Technology (LTKK) and VTT Energy carried out a series of preliminary tests in 1999 to study the behavior of noncondensable (NC) gases in VVER geometry. The tests aimed at studying the effect of NC gases on system thermal-hydraulics and on heat transfer in a horizontal steam generator (HSG). The system behavior can be affected by hydrogen produced in the core in case of a severe accident, by nitrogen from hydro-accumulators released into the primary circuit in case of a loss-of-coolant accident (LOCA) and more generally by any NC gas in all cases where cooling is ensured by natural circulation. A secondary objective of the tests - the first series of tests ever performed with NC gas with PACTEL - was to find out, if the instrumentation of PACTEL was adequate for this type of tests and if it was functioning properly. This paper presents the measured and calculated (CATHARE code version V15a mod 2.1) results of the test NCg-l. It was carried out in natural circulation (one loop in operation) and at about 50 % of primary mass inventory. Compressed air, simulating nitrogen gas was injected in the vertical part of the hot leg below the HSG. Clearly, the initial conditions in calculation and test are quite different. Before NC gas injection, the system is probably in a two-phase mode. At the measured inventory, the calculation predicts single-phase vapor mode. However, CATHARE predicts some qualitative trends of the test: (1) primary pressure increase after each air injection, and (2) existence of passive zones in steam generator tubes. Some quantitative disagreements have to be better understood by investigating the reasons for differences in the initial state: power level, heat losses, coolant repartition and flow rate in the primary circuit, uncertainty of measured pressures and temperatures, improvement of the CATHARE nodalization. The possible occurrence of reverse flow in some steam generator tubes must be also studied in more detail

  1. Modelling non-equilibrium secondary organic aerosol formation and evaporation with the aerosol dynamics, gas- and particle-phase chemistry kinetic multilayer model ADCHAM

    Science.gov (United States)

    Roldin, P.; Eriksson, A. C.; Nordin, E. Z.; Hermansson, E.; Mogensen, D.; Rusanen, A.; Boy, M.; Swietlicki, E.; Svenningsson, B.; Zelenyuk, A.; Pagels, J.

    2014-08-01

    We have developed the novel Aerosol Dynamics, gas- and particle-phase chemistry model for laboratory CHAMber studies (ADCHAM). The model combines the detailed gas-phase Master Chemical Mechanism version 3.2 (MCMv3.2), an aerosol dynamics and particle-phase chemistry module (which considers acid-catalysed oligomerization, heterogeneous oxidation reactions in the particle phase and non-ideal interactions between organic compounds, water and inorganic ions) and a kinetic multilayer module for diffusion-limited transport of compounds between the gas phase, particle surface and particle bulk phase. In this article we describe and use ADCHAM to study (1) the evaporation of liquid dioctyl phthalate (DOP) particles, (2) the slow and almost particle-size-independent evaporation of α-pinene ozonolysis secondary organic aerosol (SOA) particles, (3) the mass-transfer-limited uptake of ammonia (NH3) and formation of organic salts between ammonium (NH4+) and carboxylic acids (RCOOH), and (4) the influence of chamber wall effects on the observed SOA formation in smog chambers. ADCHAM is able to capture the observed α-pinene SOA mass increase in the presence of NH3(g). Organic salts of ammonium and carboxylic acids predominantly form during the early stage of SOA formation. In the smog chamber experiments, these salts contribute substantially to the initial growth of the homogeneously nucleated particles. The model simulations of evaporating α-pinene SOA particles support the recent experimental findings that these particles have a semi-solid tar-like amorphous-phase state. ADCHAM is able to reproduce the main features of the observed slow evaporation rates if the concentration of low-volatility and viscous oligomerized SOA material at the particle surface increases upon evaporation. The evaporation rate is mainly governed by the reversible decomposition of oligomers back to monomers. Finally, we demonstrate that the mass-transfer-limited uptake of condensable organic compounds

  2. Simulating gas-liquid mass transfer in a spin filter bioreactor

    OpenAIRE

    Niño López, Lilibeth Caridad; Gelves Zambrano, Germán Ricardo

    2015-01-01

    Computational fluid dynamics (CFD) and population balance model (PBM) model have been used to simulate hydrodynamics and mass transfer in a 0.014 m3 Spin Filter Bioreactor. The operating conditions chosen were defined by typical settings used for culturing plant cells. Turbulence, rotating flow, bubbles breakage and coalescence were simulated by using the k-e, MRF (Multiple Reference Frame) and PBM approaches, respectively. The numerical results from different operational conditions are compa...

  3. Theoretical approach for enhanced mass transfer effects in-duct flue gas desulfurization processes

    Energy Technology Data Exchange (ETDEWEB)

    1990-10-24

    During the reporting of July 1 to September 30, 1990, bench- and pilot-scale experiments were conducted to measure mass transfer and kinetic rates under simulated duct-injection conditions. This report describes the results of stirred-tank modelling experiments; experiments with moist solids in a short-time differential reactor in order to study and compare SO{sub 2} conversions; an investigation of the agglomeration of damp Ca(OH)-based solids; and evaluation of speciality sorbents.

  4. Transient heat transfer in viscous rarefied gas between concentric cylinders. Effect of curvature

    Science.gov (United States)

    Gospodinov, P.; Roussinov, V.; Dankov, D.

    2015-10-01

    The thermoacoustic waves arising in cylindrical or planar Couette rarefied gas flow between rotating cylinders is studied in the cases of suddenly cylinder (active) wall velocity direction turn on. An unlimited increase in the radius of the inner cylinder flow can be interpreted as Couette flow between the two flat plates. Based on the developed in previous publications Navier-Stockes-Fourier (NSF) model and Direct Simulation Monte Carlo (DSMC) method and their numerical solutions, are considered transient processes in the gas phase. Macroscopic flow characteristics (velocity, density, temperature) are received. The cylindrical flow cases for fixed velocity and temperature of the both walls are considered. The curvature effects over the wave's distribution and attenuation are studied numerically.

  5. The potential for buoyant displacement gas release events in Tank 241-SY-102 after waste transfer from Tank 241-SY-101

    International Nuclear Information System (INIS)

    Wells, BE; Meyer, P.E.; Chen, G.

    2000-01-01

    Tank 241-SY-101 (SY-101) is a double-shell, radioactive waste storage tank with waste that, before the recent transfer and water back-dilution operations, was capable of retaining gas and producing buoyant displacement (BD) gas release events (GREs). Some BD GREs caused gas concentrations in the tank headspace to exceed the lower flammability limit (LFL). A BD GRE occurs when a portion of the nonconvective layer retains enough gas to become buoyant, rises to the waste surface, breaks up, and releases some of its stored gas. The installation of a mixer pump in 1993 successfully mitigated gas retention in the settled solids layer in SY-101 and has since prevented BD GREs. However, operation of the mixer pump over the years caused gas retention in the floating crust layer and a corresponding accelerated waste level growth. The accelerating crust growth trend observed in 1997--98 led to initiation of sequences of waste removal and water back-dilutions in December 1999. Waste is removed from the mixed slurry layer in Tank SY-101 and transferred into Tank 241-Sy-102 (SY-102). Water is then added back to dissolve soluble solids that retain gas. The initial transfer of 89,500 gallons of SY-101 waste, diluted in-line at 0.94:1 by volume with water, to SY-102 was conducted in December 1999. The second transfer of 230,000 gallons of original SY-101 waste, diluted approximately 0.9:1, was completed in January 2000, and the third transfer of 205,500 gallons of original SY-101 waste diluted at 0.9:1 was completed in March 2000

  6. Tibial rotational osteotomy and distal tuberosity transfer for patella subluxation secondary to excessive external tibial torsion: surgical technique and clinical outcome.

    Science.gov (United States)

    Drexler, M; Dwyer, T; Dolkart, O; Goldstein, Y; Steinberg, E L; Chakravertty, R; Cameron, J C

    2014-11-01

    Recurrent patella subluxation may be secondary to excessive external tibial torsion. The purpose of this study is to evaluate the clinical and radiographic outcome of patients undergoing tibial derotation osteotomy and tibial tuberosity transfer for recurrent patella subluxation in association with excessive external tibial torsion. A combined tibial derotation osteotomy and tibial tuberosity transfer was performed in 15 knees (12 patients) with recurrent patella subluxation secondary to excessive external tibial torsion. Clinical evaluation was carried out using preoperative and post-operative Knee Society Score (KSS), Kujala Patellofemoral score, the Western Ontario and McMaster Universities Osteoarthritis Index (WOMAC) questionnaire, the short form-12 (SF-12) and a visual analogue score (VAS) pain scale. The median follow-up period was 84 months (range 15-156) and median patient age was 34 years (range 19-57 years). The median preoperative external tibial torsion was 62° (range 55°-70°), with a median rotational correction of 36° (range 30°-45°) after surgery. Significant improvement (p 45° who underwent tibial derotation osteotomy and tibial tuberosity transfer achieved a satisfactory outcome in terms of pain relief and improved function. A significant complication was seen in 2/15 patients. Case series, Level IV.

  7. The Effect of a Serious Digital Game on Students’ Ability to Transfer Knowledge in Secondary Agricultural Education: An Exploratory Study

    Directory of Open Access Journals (Sweden)

    J. C. Bunch

    2016-06-01

    Full Text Available This study’s purpose was to compare the effectiveness of the traditional, lecture and discussion method to a digital game-based learning (DGBL approach on students’ near and far knowledge transfer abilities in agriculture and mathematics regarding a unit on swine diseases in animal science courses. Two research questions guided the study, which employed a quasi-experimental, between-groups design. No statistically significant differences (p > .05 were found between the counterfactual group and the treatment group regarding students’ near and far knowledge transfer. Based on this result, it can be recommended that professional development opportunities be created with an emphasis on using serious games to teach course content for in-service teachers without diminishing students’ knowledge transfer. Specifically, the creators of this professional development should consider emphasizing Technological Pedagogical Content Knowledge development in teachers. In addition, future investigations should focus on the kind of transfer that occurred, whether positive, negative, or zero.

  8. Computational-fluid-dynamics (CFD) analysis of mixing and gas-liquid mass transfer in shake flasks.

    Science.gov (United States)

    Zhang, Hu; Williams-Dalson, Wellae; Keshavarz-Moore, Eli; Shamlou, Parviz Ayazi

    2005-02-01

    CFD (computational fluid dynamics) techniques were used to predict mixing and gas-liquid mass transfer in a 250 ml shake flask operating over a range of shaking frequencies between 100 and 300 rev./min, shaking diameters between 20 and 60 mm, and fill volumes between 25 and 100 ml. Interfacial area, a, volumetric mass-transfer coeffcient, kLa, and the power input per unit volume, epsilonv, of the liquid were predicted to be 300bioreactors used in the fermentation of bacterial and fungal micro-organisms (100bioreactors. Bacterial and fungal micro-organisms require dissolved oxygen concentrations typically in the range 50-250 mmol of O2 . h(-1) . litre(-1), corresponding to volumetric mass-transfer coefficients, kLa, in the range of 250-400 h(-1). Poor mixing and dissolved-oxygen limitation in shake flasks may limit their use in process design and media optimization in fermentation. In contrast, mammalian cells have relatively low demand for oxygen and consequently require a lower specific power input, this being typically between 1 and 10 W . m(-3), allowing efficient operation in shake flasks. Experimental data presented as part of the present study showed that mammalian cell growth in shake flasks was essentially independent of the specific power input, the maximum specific cell growth rate being 0.056 h(-1). The corresponding maximum oxygen-uptake rate was 0.74 mmol of O2 . h(-1) . litre(-1) for a viable cell count of 1.3 x 10(6) cells . ml(-1). These values are comparable with reported values for laboratory and pilotscale bioreactors. This analysis suggests that growth of mammalian cells in shake flasks (and hence in laboratory bioreactors) is not limited by the gas-liquid mass-transfer rate. In mammalian cell cultures, the requirement for good mixing is driven by other considerations, including the need for good cell suspension and reduction in heterogeneity, for example, in pH, temperature, nutrient concentration, osmolality and lactate/glucose ratio.

  9. Heat Transfer Augmentation Technologies for Internal Cooling of Turbine Components of Gas Turbine Engines

    Directory of Open Access Journals (Sweden)

    Phil Ligrani

    2013-01-01

    Full Text Available To provide an overview of the current state of the art of heat transfer augmentation schemes employed for internal cooling of turbine blades and components, results from an extensive literature review are presented with data from internal cooling channels, both with and without rotation. According to this survey, a very small number of existing investigations consider the use of combination devices for internal passage heat transfer augmentation. Examples are rib turbulators, pin fins, and dimples together, a combination of pin fins and dimples, and rib turbulators and pin fins in combination. The results of such studies are compared with data obtained prior to 2003 without rotation influences. Those data are comprised of heat transfer augmentation results for internal cooling channels, with rib turbulators, pin fins, dimpled surfaces, surfaces with protrusions, swirl chambers, or surface roughness. This comparison reveals that all of the new data, obtained since 2003, collect within the distribution of globally averaged data obtained from investigations conducted prior to 2003 (without rotation influences. The same conclusion in regard to data distributions is also reached in regard to globally averaged thermal performance parameters as they vary with friction factor ratio. These comparisons, made on the basis of such judgment criteria, lead to the conclusion that improvements in our ability to provide better spatially-averaged thermal protection have been minimal since 2003. When rotation is present, existing investigations provide little evidence of overall increases or decreases in overall thermal performance characteristics with rotation, at any value of rotation number, buoyancy parameter, density ratio, or Reynolds number. Comparisons between existing rotating channel experimental data and the results obtained prior to 2003, without rotation influences, also show that rotation has little effect on overall spatially-averaged thermal

  10. Heat transfer from rarefied ionized argon gas to a biased wall

    International Nuclear Information System (INIS)

    Kanzawa, A.; Honda, T.; Hayashi, T.

    1979-01-01

    The heat transfer rates from an argon plasma jet at 507 Pa to a 0.15-mm-i.d. tungsten wire to which various potentials are applied against the plasma jet were measured and compared with the theoretical calculation. The heat flow rate was obtained from the electric resistance change of the wire. When the wire is biased, the probe current obstructs the accurate measurement. Therefore, the current was cut off by a switching circuit. And, the accommodation coefficients of argon atoms and ions were determined 0.62 and 0.48. (author)

  11. Turbulent heat transfer on a permeable surface in the range of supercritical gas injections

    International Nuclear Information System (INIS)

    Kichatov, B.V.; Polyaev, V.M.

    1997-01-01

    Gas injection in a permeable surface is used as one of the most perspective ways of thermal protection. Forcing back of the boundary layer from the surface takes place by injection, whereby the friction coefficients and heat exchange are decreased. By certain injection parameter, which is called critical, there takes place the complete forcing back of the boundary layer from the surface. However the process of friction and heat exchange degeneration proceeds nonuniformly. This article is devoted to explanation of the above notice. Analysis of the problem is based on the limiting relative law of heat exchange and friction for a turbulent boundary layer

  12. Secondary natural gas recovery: Targeted applications for infield reserve growth in midcontinent reservoirs, Boonsville Field, Fort Worth Basin, Texas. Topical report, May 1993--June 1995

    Energy Technology Data Exchange (ETDEWEB)

    Hardage, B.A.; Carr, D.L.; Finley, R.J.; Tyler, N.; Lancaster, D.E.; Elphick, R.Y.; Ballard, J.R.

    1995-07-01

    The objectives of this project are to define undrained or incompletely drained reservoir compartments controlled primarily by depositional heterogeneity in a low-accommodation, cratonic Midcontinent depositional setting, and, afterwards, to develop and transfer to producers strategies for infield reserve growth of natural gas. Integrated geologic, geophysical, reservoir engineering, and petrophysical evaluations are described in complex difficult-to-characterize fluvial and deltaic reservoirs in Boonsville (Bend Conglomerate Gas) field, a large, mature gas field located in the Fort Worth Basin of North Texas. The purpose of this project is to demonstrate approaches to overcoming the reservoir complexity, targeting the gas resource, and doing so using state-of-the-art technologies being applied by a large cross section of Midcontinent operators.

  13. Photonic quantum state transfer between a cold atomic gas and a crystal

    Science.gov (United States)

    Maring, Nicolas; Farrera, Pau; Kutluer, Kutlu; Mazzera, Margherita; Heinze, Georg; de Riedmatten, Hugues

    2017-11-01

    Interfacing fundamentally different quantum systems is key to building future hybrid quantum networks. Such heterogeneous networks offer capabilities superior to those of their homogeneous counterparts, as they merge the individual advantages of disparate quantum nodes in a single network architecture. However, few investigations of optical hybrid interconnections have been carried out, owing to fundamental and technological challenges such as wavelength and bandwidth matching of the interfacing photons. Here we report optical quantum interconnection of two disparate matter quantum systems with photon storage capabilities. We show that a quantum state can be transferred faithfully between a cold atomic ensemble and a rare-earth-doped crystal by means of a single photon at 1,552  nanometre telecommunication wavelength, using cascaded quantum frequency conversion. We demonstrate that quantum correlations between a photon and a single collective spin excitation in the cold atomic ensemble can be transferred to the solid-state system. We also show that single-photon time-bin qubits generated in the cold atomic ensemble can be converted, stored and retrieved from the crystal with a conditional qubit fidelity of more than 85 per cent. Our results open up the prospect of optically connecting quantum nodes with different capabilities and represent an important step towards the realization of large-scale hybrid quantum networks.

  14. Photonic quantum state transfer between a cold atomic gas and a crystal.

    Science.gov (United States)

    Maring, Nicolas; Farrera, Pau; Kutluer, Kutlu; Mazzera, Margherita; Heinze, Georg; de Riedmatten, Hugues

    2017-11-22

    Interfacing fundamentally different quantum systems is key to building future hybrid quantum networks. Such heterogeneous networks offer capabilities superior to those of their homogeneous counterparts, as they merge the individual advantages of disparate quantum nodes in a single network architecture. However, few investigations of optical hybrid interconnections have been carried out, owing to fundamental and technological challenges such as wavelength and bandwidth matching of the interfacing photons. Here we report optical quantum interconnection of two disparate matter quantum systems with photon storage capabilities. We show that a quantum state can be transferred faithfully between a cold atomic ensemble and a rare-earth-doped crystal by means of a single photon at 1,552  nanometre telecommunication wavelength, using cascaded quantum frequency conversion. We demonstrate that quantum correlations between a photon and a single collective spin excitation in the cold atomic ensemble can be transferred to the solid-state system. We also show that single-photon time-bin qubits generated in the cold atomic ensemble can be converted, stored and retrieved from the crystal with a conditional qubit fidelity of more than 85 per cent. Our results open up the prospect of optically connecting quantum nodes with different capabilities and represent an important step towards the realization of large-scale hybrid quantum networks.

  15. Soil Microbial Communities and Gas Dynamics Contribute to Arbuscular Mycorrhizal Nitrogen Uptake and Transfer to Plants

    Science.gov (United States)

    Hestrin, R.; Harrison, M. J.; Lehmann, J.

    2016-12-01

    Arbuscular mycorrhizal fungi (AMF) associate with most terrestrial plants and influence ecosystem ecology and biogeochemistry. There is evidence that AMF play a role in soil nitrogen cycling, in part by taking up nitrogen and transferring it to plants. However, many aspects of this process are poorly understood, including the factors that control fungal access to nitrogen stored in soil organic matter. In this study, we used stable isotopes and root exclusion to track nitrogen movement from organic matter into AMF and host plants. AMF significantly increased total plant biomass and nitrogen content, but both AMF and other soil microbes seemed to compete with plants for nitrogen. Surprisingly, gaseous nitrogen species also contributed significantly to plant nitrogen content under alkaline soil conditions. Our current experiments investigate whether free-living microbial communities that have evolved under a soil nitrogen gradient influence AMF access to soil organic nitrogen and subsequent nitrogen transfer to plants. This research links interactions between plants, mycorrhizal symbionts, and free-living microbes with terrestrial carbon and nitrogen dynamics.

  16. Air–Sea CO2 Gas Transfer Velocity in a Shallow Estuary

    DEFF Research Database (Denmark)

    Mørk, Eva Thorborg; Sørensen, Lise Lotte; Jensen, Bjarne

    2014-01-01

    The air–sea transfer velocity of CO2(kCO2) was investigated in a shallow estuary in March to July 2012, using eddy-covariance measurements of CO2 fluxes and measured air–sea CO2 partial-pressure differences. A data evaluation method that eliminates data by nine rejection criteria in order...... to heighten parametrization certainty is proposed. We tested the data evaluation method by comparing two datasets: one derived using quality criteria related solely to the eddy-covariance method, and the other derived using quality criteria based on both eddy-covariance and cospectral peak methods. The best...... parametrization of transfer velocity normalized to a Schmidt number of 600 (k600) was determined to be: k600=0.3U102.5 where U10 is the wind speed in m s−1 at 10 m; k600 is based on CO2 fluxes calculated by the eddy-covariance method and including the cospectral peak method criteria. At low wind speeds...

  17. Novel method for investigation and evaluation of heat transfer in fixed bed tubular reactors with gas flow

    Science.gov (United States)

    Bauer, M.; Adler, R.

    2002-08-01

    A novel concept for the investigation and evaluation of radial heat transfer in fixed bed tubular reactors in absence of a chemical reaction based on instationary measurements is presented in this work. Compared to known stationary investigational concepts one is able to get an increased informational yield from the experimental data especially for low tube-to-particle diameter ratios and small gas mass flow rates to be found typically in heterogeneous catalysis. The question discussed contrary in literature which boundary condition should be applied to the inner reactor wall is answered. A empirical correlation of the parameters for the two dimensional pseudohomogeneous model was found which allows a more accurate description of the experimental findings than known approaches from literature. The experiments were conducted for spherical particles and hollow cylinders made from steatite.

  18. Secondary acidification: Changes in gas-aerosol partitioning of semivolatile nitric acid and enhancement of its deposition due to increased emission and concentration of SOx

    Science.gov (United States)

    Kajino, Mizuo; Ueda, Hiromasa; Nakayama, Shinji

    2008-02-01

    Secondary acidification, or the indirect enhancement of semivolatile air pollutant deposition associated with increased SO42- concentrations, is shown to occur in general air pollution using data collected from six stations of the Acid Deposition Monitoring Network in East Asia (EANET) in Japan. This effect was first detected as a result of volcanic SO2 plumes in our previous studies. Results indicate that as SO42- concentration increases, gas-aerosol partitioning of nitric acid shifts to the gas phase, increasing the HNO3 gas concentration. Since the dry and wet deposition rates of HNO3 gas are very high, deposition can be enhanced even when the emission of NOx remains unchanged. In western Japan, the indirect effect for wet deposition is most apparent from spring to autumn, when the Asian continental outflow carries sulfate-rich contaminated air masses. However, it is not pronounced in air masses containing abundant sea-salt particles and related cation components in aerosols. In areas such as forests or farmlands with low surface resistance, dry deposition of nitric acid is more pronounced than wet deposition as the dry deposition velocity of HNO3 gas is high. Increased dry deposition of t-NO3 due to the indirect effect and consequent vegetation damage is thus of considerable concern in such regions. The deposition of other semivolatile components, such as hydrochloric acid and ammonia, can be altered and can also induce secondary acidification.

  19. Gas

    International Nuclear Information System (INIS)

    1996-01-01

    The French government has decided to modify the conditions of extension of local natural gas authorities to neighbouring districts. The European Union is studying the conditions of internal gas market with the objective of more open markets although considering public service requirements

  20. Estimation of bubble-mediated air–sea gas exchange from concurrent DMS and CO2 transfer velocities at intermediate–high wind speeds

    Directory of Open Access Journals (Sweden)

    T. G. Bell

    2017-07-01

    Full Text Available Simultaneous air–sea fluxes and concentration differences of dimethylsulfide (DMS and carbon dioxide (CO2 were measured during a summertime North Atlantic cruise in 2011. This data set reveals significant differences between the gas transfer velocities of these two gases (Δkw over a range of wind speeds up to 21 m s−1. These differences occur at and above the approximate wind speed threshold when waves begin breaking. Whitecap fraction (a proxy for bubbles was also measured and has a positive relationship with Δkw, consistent with enhanced bubble-mediated transfer of the less soluble CO2 relative to that of the more soluble DMS. However, the correlation of Δkw with whitecap fraction is no stronger than with wind speed. Models used to estimate bubble-mediated transfer from in situ whitecap fraction underpredict the observations, particularly at intermediate wind speeds. Examining the differences between gas transfer velocities of gases with different solubilities is a useful way to detect the impact of bubble-mediated exchange. More simultaneous gas transfer measurements of different solubility gases across a wide range of oceanic conditions are needed to understand the factors controlling the magnitude and scaling of bubble-mediated gas exchange.

  1. Sensitivity of secondary production and export flux to choice of trophic transfer formulation in marine ecosystem models

    Science.gov (United States)

    Anderson, Thomas R.; Hessen, Dag O.; Mitra, Aditee; Mayor, Daniel J.; Yool, Andrew

    2013-09-01

    The performance of four contemporary formulations describing trophic transfer, which have strongly contrasting assumptions as regards the way that consumer growth is calculated as a function of food C:N ratio and in the fate of non-limiting substrates, was compared in two settings: a simple steady-state ecosystem model and a 3D biogeochemical general circulation model. Considerable variation was seen in predictions for primary production, transfer to higher trophic levels and export to the ocean interior. The physiological basis of the various assumptions underpinning the chosen formulations is open to question. Assumptions include Liebig-style limitation of growth, strict homeostasis in zooplankton biomass, and whether excess C and N are released by voiding in faecal pellets or via respiration/excretion post-absorption by the gut. Deciding upon the most appropriate means of formulating trophic transfer is not straightforward because, despite advances in ecological stoichiometry, the physiological mechanisms underlying these phenomena remain incompletely understood. Nevertheless, worrying inconsistencies are evident in the way in which fundamental transfer processes are justified and parameterised in the current generation of marine ecosystem models, manifested in the resulting simulations of ocean biogeochemistry. Our work highlights the need for modellers to revisit and appraise the equations and parameter values used to describe trophic transfer in marine ecosystem models.

  2. Influence of Metal Transfer Stability and Shielding Gas Composition on CO and CO2 Emissions during Short-circuiting MIG/MAG Welding

    Directory of Open Access Journals (Sweden)

    Valter Alves de Meneses

    Full Text Available Abstract: Several studies have demonstrated the influence of parameters and shielding gas on metal transfer stability or on the generation of fumes in MIG/MAG welding, but little or nothing has been discussed regarding the emission of toxic and asphyxiating gases, particularly as it pertains to parameterization of the process. The purpose of this study was to analyze and evaluate the effect of manufacturing aspects of welding processes (short-circuit metal transfer stability and shielding gas composition on the gas emission levels during MIG/MAG welding (occupational health and environmental aspects. Using mixtures of Argon with CO2 and O2 and maintaining the same average current and the same weld bead volume, short-circuit welding was performed with carbon steel welding wire in open (welder’s breathing zone and confined environments. The welding voltage was adjusted to gradually vary the transfer stability. It was found that the richer the composition of the shielding gas is in CO2, the more CO and CO2 are generated by the arc. However, unlike fume emission, voltage and transfer stability had no effect on the generation of these gases. It was also found that despite the large quantity of CO and CO2 emitted by the arc, especially when using pure CO2 shielding gas, there was no high level residual concentration of CO and CO2 in or near the worker’s breathing zone, even in confined work cells.

  3. The influence of adsorption coating on molecular heat transfer in the system `rarefied gas — metal'

    Science.gov (United States)

    Ukhov, A. I.; Borisov, S. F.; Porodnov, B. T.

    2010-03-01

    Based on the classical concept of atomic motion and the Goodman and Wachman lattice theory, we have developed a computer program to model the equilibrium and non-equilibrium scattering of helium atoms by 3D tungsten crystal lattice with allowance for adsorption surface coating. Within the concept of energy accommodation coefficient, we have calculated the rate of molecular heat transfer of helium to clean tungsten surface or to tungsten surface partially covered with an adsorbate. The calculations were performed for various surface temperatures. The calculated dependences were compared to test data obtained in experiments with surfaces controlled in terms of their chemical composition. Within the developed approach, the simulations proved capable of providing an adequate description to experimental data obtained for the equilibrium energy accommodation coefficient on the clean surface, and also for the non-equilibrium energy accommodation coefficient for the surface partially covered with adsorbate.

  4. Combining UV photodissociation action spectroscopy with electron transfer dissociation for structure analysis of gas-phase peptide cation-radicals.

    Science.gov (United States)

    Shaffer, Christopher J; Pepin, Robert; Tureček, František

    2015-12-01

    We report the first example of using ultraviolet (UV) photodissociation action spectroscopy for the investigation of gas-phase peptide cation-radicals produced by electron transfer dissociation. z-Type fragment ions (●) Gly-Gly-Lys(+), coordinated to 18-crown-6-ether (CE), are generated, selected by mass and photodissociated in the 200-400 nm region. The UVPD action spectra indicate the presence of valence-bond isomers differing in the position of the Cα radical defect, (α-Gly)-Gly-Lys(+) (CE), Gly-(α-Gly)-Lys(+) (CE) and Gly-Gly-(α-Lys(+))(CE). The isomers are readily distinguishable by UV absorption spectra obtained by time-dependent density functional theory (TD-DFT) calculations. In contrast, conformational isomers of these radical types are calculated to have similar UV spectra. UV photodissociation action spectroscopy represents a new tool for the investigation of transient intermediates of ion-electron reactions. Specifically, z-type cation radicals are shown to undergo spontaneous hydrogen atom migrations upon electron transfer dissociation. Copyright © 2015 John Wiley & Sons, Ltd.

  5. Experimental Study of Heat Transfer to Small Cylinders in a Subsonic, High-temperature Gas Stream

    Science.gov (United States)

    Glawe, George E; Johnson, Robert C

    1957-01-01

    A Nusselt-Reynolds number relation for cylindrical thermocouple wires in crossflow was obtained from the experimental determination of time constants. Tests were conducted in exhaust gas over a temperature range of 2000 to 3400 R, a Mach number range of 0.3 to 0.8, and a static-pressure range from 2/3 to 1-1/3 atmospheres, yielding a Reynolds number range of 450 to 3000. The correlation obtained is Nu=(0.428 plus or minus 0.003) times the square root of Re* with average deviations of a single observation of 8.5 percent. This relation is the same as one previously reported for room-temperature conditions.

  6. Role of technology transfer in abating greenhouse gas emissions: the case of Sri Lanka

    Energy Technology Data Exchange (ETDEWEB)

    Gnanalingam, K.; Siyambalapitiya, T. [Sri Lanka Energy Managers Association, Colombo (Sri Lanka)

    1994-12-31

    Measures introduced by the Sri Lanka government to reduce energy consumption are outlined. These include introduction of improved cookstoves, promotion of gas use in place of electricity, introduction of efficient lighting, energy management programs in industry, and research into more appropriate agricultural machinery. Self-reliance in energy planning is advocated. Foreign expertise may be needed to initiate a process but emphasis is put on eventual transition to national staffing. The article outlines Sri Lanka`s foreign investment policy. It then describes the efforts made so far to improve the efficiency of lighting systems in households, together with details of costs and benefits of a possible state sponsored or private sector funded popularization programme for efficient lighting systems. 1 fig.

  7. Validation of a predictive model coupling gas transfer and microbial growth in fresh food packed under modified atmosphere.

    Science.gov (United States)

    Guillard, V; Couvert, O; Stahl, V; Hanin, A; Denis, C; Huchet, V; Chaix, E; Loriot, C; Vincelot, T; Thuault, D

    2016-09-01

    Predicting microbial safety of fresh products in modified atmosphere packaging implies to take into account the dynamic of O2, CO2 and N2 exchanges in the system and its effect on microbial growth. In this paper a mechanistic model coupling gas transfer and predictive microbiology was validated using dedicated challenge-tests performed on poultry meat, fresh salmon and processed cheese, inoculated with either Listeria monocytogenes or Pseudomonas fluorescens and packed in commercially used packaging materials (tray + lid films). The model succeeded in predicting the relative variation of O2, CO2 and N2 partial pressure in headspace and the growth of the studied microorganisms without any parameter identification. This work highlighted that the respiration of the targeted microorganism itself and/or that of the naturally present microflora could not be neglected in most of the cases, and could, in the particular case of aerobic microbes contribute to limit the growth by removing all residual O2 in the package. This work also confirmed the low sensitivity of L. monocytogenes toward CO2 while that of P. fluorescens permitted to efficiently prevent its growth by choosing the right combination of packaging gas permeability value and initial % of CO2 initially flushed in the pack. Copyright © 2016 Elsevier Ltd. All rights reserved.

  8. Charge transfer processes during ion scattering and stimulated desorption of secondary ions from gas-condensed dielectric surfaces

    International Nuclear Information System (INIS)

    Souda, Ryutaro

    2002-01-01

    The ion emission mechanism from weakly-interacting solid surfaces has been investigated. The H + ion captures a valence electron via transient chemisorption, so that the ion neutralization probability is related to the nature of bonding of adsorbates. The H + ion is scattered from physisorbed Ar at any coverage whereas the H + yield from solid H 2 O decays considerably due to covalency in the hydrogen bond. In electron- and ion-stimulated desorption, the ion ejection probability is correlated intimately with the physisorption/chemisorption of parent atoms or molecules. The emission of F + ions is rather exceptional because they arise from the screened F 2s core-hole state followed by the ionization via the intra-atomic Auger decay after bond breakage. In electron-stimulated desorption of H 2 O, hydrated protons are emitted effectively from nanoclusters formed on a solid Ar substrate due to Coulomb repulsion between confined valence holes

  9. Charge transfer processes during ion scattering and stimulated desorption of secondary ions from gas-condensed dielectric surfaces

    CERN Document Server

    Souda, R

    2002-01-01

    The ion emission mechanism from weakly-interacting solid surfaces has been investigated. The H sup + ion captures a valence electron via transient chemisorption, so that the ion neutralization probability is related to the nature of bonding of adsorbates. The H sup + ion is scattered from physisorbed Ar at any coverage whereas the H sup + yield from solid H sub 2 O decays considerably due to covalency in the hydrogen bond. In electron- and ion-stimulated desorption, the ion ejection probability is correlated intimately with the physisorption/chemisorption of parent atoms or molecules. The emission of F sup + ions is rather exceptional because they arise from the screened F 2s core-hole state followed by the ionization via the intra-atomic Auger decay after bond breakage. In electron-stimulated desorption of H sub 2 O, hydrated protons are emitted effectively from nanoclusters formed on a solid Ar substrate due to Coulomb repulsion between confined valence holes.

  10. Heat transfer in gas-cooled piles; Echanges thermiques dans les piles a gaz

    Energy Technology Data Exchange (ETDEWEB)

    Le Foll, J.; Gelin, P.; Robert, E. de [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    Measurements under steady flow conditions gave the distribution of the local heat transfer coefficient along the cross section perimeter of a longitudinally finned can. The distribution is generally affected by strong irregularities which make the elementary theory of heat transfer along the fins inapplicable. We studied systematically the above mentioned distribution and established however that heat transfer properties were rendered similar to those of an annular channel cross-section with isotherms heat exchange perimeter by application of two non-dimensional parameters. These parameters may be calculated by integration on the specific channel cross section and will generally permit to reach a sufficient approximation. Although the computation is rather difficult the evaluation of the parameters is more easily done by electrical analogy measurements and there even exits a possibility to learn directly about the effect of slight changes of the can outer perimeter. Now, the channel as a whole is rated to such performances as are apt to keep the can temperature below a given limiting value, generally by making the assumption that the properties of the cross section remain identical through-out the channel. Usually, however, there are many separate fuel elements along the channel and consequently flux and heat transfer coefficient distribution and local temperature values on the can may be significantly disturbed compared to the simpler case above mentioned. We must therefore bear in mind to design the fuel elements to avoid end caps becoming in turn overheated. Moreover, fuel end caps may be more heavily stressed than the other parts of the can which results in a lower value of the temperature limit and it must be remembered they lie nearer fuel hotter parts on the rod axis, precisely where fuel discontinuity, to make matters worse, may cause the flux to show a rise. The flux rise was computed on an electronic machine and subsequently measured directly

  11. Keto-enol tautomerization and intermolecular proton transfer in photoionized cyclopentanone dimer in the gas phase

    Energy Technology Data Exchange (ETDEWEB)

    Ghosh, Arup K.; Chatterjee, Piyali; Chakraborty, Tapas, E-mail: pctc@iacs.res.in [Department of Physical Chemistry, Indian Association for the Cultivation of Science, 2A Raja S. C. Mullick Road, Jadavpur, Kolkata 700032 (India)

    2014-07-28

    Time-of-flight mass spectra of cyclopentanone and its clusters cooled in a supersonic jet expansion have been measured following 4-, 3-, and 2-photon ionizations by the 2nd, 3rd, and 4th harmonic wavelengths, respectively, of a Q-switched Nd:YAG laser. The mass spectra reveal signatures of energetically favored keto to enol tautomerization of the molecular ion leading to intermolecular proton transfer, and this observation is found sharply dependent on the ionization wavelengths used. Electronic structure calculation predicts that in spite of the energetic preference, keto-enol conversion barrier of isolated molecular ion is high. However, the barrier is significantly reduced in a CH⋯O hydrogen-bonded dimer of the molecule. The transition states associated with tautomeric conversion of both cyclopentanone monomer and dimer cations have been identified by means of intrinsic reaction co-ordinate calculation. In a supersonic jet expansion, although a weakly bound dimer is readily generated, the corresponding cation and also the protonated counterpart are observed only for ionization by 532 nm. For other two ionization wavelengths, these species do not register in the mass spectra, where the competing reaction channels via α-cleavage of the ring become dominant. In contrast to the report of a recent study, we notice that the intact molecular ion largely survives fragmentations when ionized from the 2-photon resonant 3p Rydberg state as intermediate using nanosecond laser pulses, and the corresponding resonant 3-photon ionization spectrum has been recorded probing the intact molecular ion.

  12. Italian position paper on heat and mass transfer in the reactor cover gas

    International Nuclear Information System (INIS)

    Caponetti, R.; Olivieri, P.; Petrazzuolo, F.

    1986-01-01

    The major effort being made in Italy with regard to the development of fast nuclear reactors is concentrated, as is known, in the construction of the PEC reactor, whose mechanical completion is expected early in 1988. The 116MWt PEC (Prova Elementi di Combustibile; i.e. Fuel Element Testing) reactor is sodium cooled. It is being built to study the behavior of fuel elements under thermal and neutronic conditions similar to those of fast nuclear power stations. Particular attention is being dedicated to safety aspects. This document furnishes a number of construction solutions with regard to that reactor and preparatory approaches to its operation, namely: a brief description of the construction solutions as far as concerns the Closure Head Assembly and the cover gas circuit together with its main components; the description of some test facilities arranged for abatement and measurement of sodium aerosol concentration; a number of preliminary evaluation results obtained thus far with regard to the formation, transport and depositing of sodium aerosols

  13. Heat transfer in a compact heat exchanger containing rectangular channels and using helium gas

    Science.gov (United States)

    Olson, D. A.

    1991-01-01

    Development of a National Aerospace Plane (NASP), which will fly at hypersonic speeds, require novel cooling techniques to manage the anticipated high heat fluxes on various components. A compact heat exchanger was constructed consisting of 12 parallel, rectangular channels in a flat piece of commercially pure nickel. The channel specimen was radiatively heated on the top side at heat fluxes of up to 77 W/sq cm, insulated on the back side, and cooled with helium gas flowing in the channels at 3.5 to 7.0 MPa and Reynolds numbers of 1400 to 28,000. The measured friction factor was lower than that of the accepted correlation for fully developed turbulent flow, although the uncertainty was high due to uncertainty in the channel height and a high ratio of dynamic pressure to pressure drop. The measured Nusselt number, when modified to account for differences in fluid properties between the wall and the cooling fluid, agreed with past correlations for fully developed turbulent flow in channels. Flow nonuniformity from channel-to-channel was as high as 12 pct above and 19 pct below the mean flow.

  14. Radiant and convective heat transfer for flow of a transparent gas in a short tube with prescribed sinusoidal wall heat flux

    International Nuclear Information System (INIS)

    de Lemos, M.J.S.

    1982-01-01

    The present analysis accounts for radiant and convective heat transfer for a transparent fluid flowing in a short tube with prescribed wall heat flux. The heat flux distribution used was of sine shape with maximum at the middle of the tube. Such a solution is the approximate one for axial power in a nuclear reactor. The solutions for the tube wall and gas bulk temperatures were obtained by successive substitutions for the wall and gas balance energy equations. The results show a decrease of 30% for the maximum wall temperature using black surface (e = 1). In this same case, the increasing in the gas temperature shows a decrease of 58%

  15. Targeted technology applications for infield reserve growth: A synopsis of the Secondary Natural Gas Recovery project, Gulf Coast Basin. Topical report, September 1988--April 1993

    Energy Technology Data Exchange (ETDEWEB)

    Levey, R.A.; Finley, R.J.; Hardage, B.A.

    1994-06-01

    The Secondary Natural Gas Recovery (SGR): Targeted Technology Applications for Infield Reserve Growth is a joint venture research project sponsored by the Gas Research Institute (GRI), the US Department of Energy (DOE), the State of Texas through the Bureau of Economic Geology at The University of Texas at Austin, with the cofunding and cooperation of the natural gas industry. The SGR project is a field-based program using an integrated multidisciplinary approach that integrates geology, geophysics, engineering, and petrophysics. A major objective of this research project is to develop, test, and verify those technologies and methodologies that have near- to mid-term potential for maximizing recovery of gas from conventional reservoirs in known fields. Natural gas reservoirs in the Gulf Coast Basin are targeted as data-rich, field-based models for evaluating infield development. The SGR research program focuses on sandstone-dominated reservoirs in fluvial-deltaic plays within the onshore Gulf Coast Basin of Texas. The primary project research objectives are: To establish how depositional and diagenetic heterogeneities cause, even in reservoirs of conventional permeability, reservoir compartmentalization and hence incomplete recovery of natural gas. To document examples of reserve growth occurrence and potential from fluvial and deltaic sandstones of the Texas Gulf Coast Basin as a natural laboratory for developing concepts and testing applications. To demonstrate how the integration of geology, reservoir engineering, geophysics, and well log analysis/petrophysics leads to strategic recompletion and well placement opportunities for reserve growth in mature fields.

  16. The impact of changing wind speeds on gas transfer and its effect on global air-sea CO2 fluxes

    Science.gov (United States)

    Wanninkhof, R.; Triñanes, J.

    2017-06-01

    An increase in global wind speeds over time is affecting the global uptake of CO2 by the ocean. We determine the impact of changing winds on gas transfer and CO2 uptake by using the recently updated, global high-resolution, cross-calibrated multiplatform wind product (CCMP-V2) and a fixed monthly pCO2 climatology. In particular, we assess global changes in the context of regional wind speed changes that are attributed to large-scale climate reorganizations. The impact of wind on global CO2 gas fluxes as determined by the bulk formula is dependent on several factors, including the functionality of the gas exchange-wind speed relationship and the regional and seasonal differences in the air-water partial pressure of CO2 gradient (ΔpCO2). The latter also controls the direction of the flux. Fluxes out of the ocean are influenced more by changes in the low-to-intermediate wind speed range, while ingassing is impacted more by changes in higher winds because of the regional correlations between wind and ΔpCO2. Gas exchange-wind speed parameterizations with a quadratic and third-order polynomial dependency on wind, each of which meets global constraints, are compared. The changes in air-sea CO2 fluxes resulting from wind speed trends are greatest in the equatorial Pacific and cause a 0.03-0.04 Pg C decade-1 increase in outgassing over the 27 year time span. This leads to a small overall decrease of 0.00 to 0.02 Pg C decade-1 in global net CO2 uptake, contrary to expectations that increasing winds increase net CO2 uptake.Plain Language SummaryThe effects of changing winds are isolated from the total change in trends in global air-sea CO2 fluxes over the last 27 years. The overall effect of increasing winds over time has a smaller impact than expected as the impact in regions of outgassing is greater than for the regions acting as a CO2 sink.

  17. Dynamic transfer applied to secondary ion imaging over large scanned fields with the nanoSIMS 50 at high mass resolution

    Science.gov (United States)

    Slodzian, Georges; Wu, Ting-Di; Duprat, Jean; Engrand, Cécile; Guerquin-Kern, Jean-Luc

    2017-12-01

    Dynamic transfer is an adaptive optical approach used for coupling a scanning ion probe with the mass spectrometer designed for analyzing sputtered ions emanating from the probe impact. Its tuning is of crucial importance for getting uniform signal collection over large scanning fields and therefore scanning images free of vignetting in a context of high mass resolution. Revisiting the optical design of the NanoSIMS 50 instrument, where the same set of lenses focuses the primary ion probe on the sample and collects secondary ions from the sample, led us to develop novel experimental procedures to achieve dynamic transfer tuning and overcome instrumental imperfections. It is the case for scanning distortion that may be induced by the octopole used for correcting probe astigmatism and may cause irreducible vignetting on scanning images. We show that it is possible to develop complete tuning procedures by compromising temporarily on the sharpness of the probe focus. Most importantly, we show that, in a context of high mass resolution, the transfer does not significantly disturb isotopic ratios over large scanned fields provided external coils are properly adjusted to compensate ambient magnetic fields. Deepening the procedures led us to demonstrate that the scanning center of the probe may not coincide with the imaging center of COOL, Coaxial Objective Lenses forming the probe and extracting secondary ions. We have checked that bringing those two centers into coincidence resulted in a better image quality over large fields. In the present work, we show how to handle the secondary beam in order to position it before it enters the spectrometer. That capability is essential for optimizing transmission at high mass resolution by aligning the secondary beam axis on a given entrance axis of the spectrometer. These results led us to propose several instrumental improvements including the crucial interest of an additional octopole upstream in the primary ion probe column to

  18. Primary emissions and secondary formation of volatile organic compounds from natural gas production in five major U.S. shale plays

    Science.gov (United States)

    Gilman, J.; Lerner, B. M.; Warneke, C.; Graus, M.; Lui, R.; Koss, A.; Yuan, B.; Murphy, S. M.; Alvarez, S. L.; Lefer, B. L.; Min, K. E.; Brown, S. S.; Roberts, J. M.; Osthoff, H. D.; Hatch, C. D.; Peischl, J.; Ryerson, T. B.; De Gouw, J. A.

    2014-12-01

    According to the U.S. Energy and Information Administration (EIA), domestic production of natural gas from shale formations is currently at the highest levels in U.S. history. Shale gas production may also result in the production of natural gas plant liquids (NGPLs) such as ethane and propane as well as natural gas condensate composed of a complex mixture of non-methane hydrocarbons containing more than ~5 carbon atoms (e.g., hexane, cyclohexane, and benzene). The amounts of natural gas liquids and condensate produced depends on the particular reservoir. The source signature of primary emissions of hydrocarbons to the atmosphere within each shale play will therefore depend on the composition of the raw natural gas as well as the industrial processes and equipment used to extract, separate, store, and transport the raw materials. Characterizing the primary emissions of VOCs from natural gas production is critical to assessing the local and regional atmospheric impacts such as the photochemical formation of ozone and secondary formation of organic aerosol. This study utilizes ground-based measurements of a full suite of volatile organic compounds (VOCs) in two western U.S. basins, the Uintah (2012-2014 winter measurements only) and Denver-Julesburg (winter 2011 and summer 2012), and airborne measurements over the Haynesville, Fayetteville, and Marcellus shale basins (summer 2013). By comparing the observed VOC to propane enhancement ratios, we show that each basin has a unique VOC source signature associated with oil and natural gas operations. Of the shale basins studied, the Uintah basin had the largest overall VOC to propane enhancement ratios while the Marcellus had the lowest. For the western basins, we will compare the composition of oxygenated VOCs produced from photochemical oxidation of VOC precursors and contrast the oxygenated VOC mixture to a "typical" summertime urban VOC mixture. The relative roles of alkanes, alkenes, aromatics, and cycloalkanes as

  19. Submm Observations of Massive Star Formation in the Giant Molecular Cloud NGC 6334 : Gas Kinematics with Radiative Transfer Models

    Science.gov (United States)

    Zernickel, A.

    2015-05-01

    Context. How massive stars (M>8 Ms) form and how they accrete gas is still an open research field, but it is known that their influence on the interstellar medium (ISM) is immense. Star formation involves the gravitational collapse of gas from scales of giant molecular clouds (GMCs) down to dense hot molecular cores (HMCs). Thus, it is important to understand the mass flows and kinematics in the ISM. Aims. This dissertation focuses on the detailed study of the region NGC 6334, located in the Galaxy at a distance of 1.7 kpc. It is aimed to trace the gas velocities in the filamentary, massive star-forming region NGC 6334 at several scales and to explain its dynamics. For that purpose, different scales are examined from 0.01-10 pc to collect information about the density, molecular abundance, temperature and velocity, and consequently to gain insights about the physio-chemical conditions of molecular clouds. The two embedded massive protostellar clusters NGC 6334I and I(N), which are at different stages of development, were selected to determine their infall velocities and mass accretion rates. Methods. This astronomical source was surveyed by a combination of different observatories, namely with the Submillimeter Array (SMA), the single-dish telescope Atacama Pathfinder Experiment (APEX), and the Herschel Space Observatory (HSO). It was mapped with APEX in carbon monoxide (13CO and C18O, J=2-1) at 220.4 GHz to study the filamentary structure and turbulent kinematics on the largest scales of 10 pc. The spectral line profiles are decomposed by Gaussian fitting and a dendrogram algorithm is applied to distinguish velocity-coherent structures and to derive statistical properties. The velocity gradient method is used to derive mass flow rates. The main filament was mapped with APEX in hydrogen cyanide (HCN) and oxomethylium (HCO+, J=3-2) at 267.6 GHz to trace the dense gas. To reproduce the position- velocity diagram (PVD), a cylindrical model with the radiative transfer

  20. Heat transfer modelling in the vertical tubes of a natural circulation passive containment loop with noncondensable gas

    International Nuclear Information System (INIS)

    Herranz, L.E.; Munoz-Cobo, J.L.; Tachenko, I.; Sancho, J.; Escriva, A.; Verdu, G.

    1994-01-01

    One of the key safety systems of the Simplified Boiling Water Reactor (SBWR) of General Electric is the Passive Containment Cooling System (PCCS). This system is designed to behave as a heat sink without need of operator actions in case of a reactor accident. Such a function relies on setting up a natural circulation loop between drywell and wetwell. Along this loop heat is removed by condensing the steam coming from the drywell onto the inner surface of externally cooled vertical tubes. Therefore, a successful design of the condenser requires a good knowledge of the local heat transmission coefficients. In this paper a model of steam condensation into vertical tubes is presented. Based on a modified diffusion boundary layer approach for noncondensables, this model accounts for the effect of shear stress caused by the cocurrent steam-gas mixture on the liquid film thickness. An approximate method to calculate film thickness, avoiding iterative algorithms, has been proposed. At present, this model has been implemented in HTCPIPE code and its results are being checked in terms of local heat transfer coefficients against the experimental data available. A good agreement between measurements and predictions is being observed for tests at atmospheric pressure. Further development and validation of the model is needed to consider aspects such as mist formation, wavy flow and high pressure. (author)

  1. Pharmacologically increasing collateral perfusion during acute stroke using a carboxyhemoglobin gas transfer agent (Sanguinate™) in spontaneously hypertensive rats.

    Science.gov (United States)

    Cipolla, Marilyn J; Linfante, Italo; Abuchowski, Abe; Jubin, Ronald; Chan, Siu-Lung

    2018-05-01

    Similar to patients with chronic hypertension, spontaneously hypertensive rats (SHR) develop fast core progression during middle cerebral artery occlusion (MCAO) resulting in large final infarct volumes. We investigated the effect of Sanguinate™ (SG), a PEGylated carboxyhemoglobin (COHb) gas transfer agent, on changes in collateral and reperfusion cerebral blood flow and brain injury in SHR during 2 h of MCAO. SG (8 mL/kg) or vehicle ( n = 6-8/group) was infused i.v. after 30 or 90 min of ischemia with 2 h reperfusion. Multi-site laser Doppler probes simultaneously measured changes in core MCA and collateral flow during ischemia and reperfusion using a validated method. Brain injury was measured using TTC. Animals were anesthetized with choral hydrate. Collateral flow changed little in vehicle-treated SHR during ischemia (-8 ± 9% vs. prior to infusion) whereas flow increased in SG-treated animals (29 ± 10%; p collateral flow in SHR during MCAO is consistent with small penumbra and large infarction. The ability to increase collateral flow in SHR with SG suggests that this compound may be useful as an adjunct to endovascular therapy and extend the time window for treatment.

  2. Investigation of beam non-uniformity after cross-beam energy transfer in a gas filled hohlraum

    Science.gov (United States)

    Schneider, M. B.; Hinkel, D. E.; Rosen, M. D.; Callahan, D. A.; Michel, P. A.; Moore, A. S.; Moody, J. D.

    2015-11-01

    Control of hotspot symmetry in an ignition capsule imploded by the x-ray drive in a high gas-filled cylindrical hohlraum at the NIF currently requires cross-beam energy transfer (CBET) from the outer beams to the inner beams. CBET occurs in the central region of the laser entrance hole (LEH) where the laser beams overlap. Linear gain models applied to individual rays indicate that CBET is not uniform across the beam profile, producing a non-uniform spatial distribution on the beams that varies in time. This changing spatial distribution could introduce asymmetries in the x-ray drive applied to the ignition capsule and should be quantified. We are investigating the effects of CBET using the Quartraum experimental platform. This platform uses an LEH-only target designed to isolate the effect of CBET on the spatial-intensity distribution of the inner beams by minimizing the effect of absorption and backscatter. A time resolved image of two inner beams is captured on a high Z witness plate. Experimental results showing how the beam's x-ray foot print on the witness plate changes as a function of Δλ will be shown and compared to models.

  3. SIMS of Organic Materials—Interface Location in Argon Gas Cluster Depth Profiles Using Negative Secondary Ions

    Science.gov (United States)

    Havelund, R.; Seah, M. P.; Tiddia, M.; Gilmore, I. S.

    2018-02-01

    A procedure has been established to define the interface position in depth profiles accurately when using secondary ion mass spectrometry and the negative secondary ions. The interface position varies strongly with the extent of the matrix effect and so depends on the secondary ion measured. Intensity profiles have been measured at both fluorenylmethyloxycarbonyl-uc(l)-pentafluorophenylalanine (FMOC) to Irganox 1010 and Irganox 1010 to FMOC interfaces for many secondary ions. These profiles show separations of the two interfaces that vary over some 10 nm depending on the secondary ion selected. The shapes of these profiles are strongly governed by matrix effects, slightly weakened by a long wavelength roughening. The matrix effects are separately measured using homogeneous, known mixtures of these two materials. Removal of the matrix and roughening effects give consistent compositional profiles for all ions that are described by an integrated exponentially modified Gaussian (EMG) profile. Use of a simple integrated Gaussian may lead to significant errors. The average interface positions in the compositional profiles are determined to standard uncertainties of 0.19 and 0.14 nm, respectively, using the integrated EMG function. Alternatively, and more simply, it is shown that interface positions and profiles may be deduced from data for several secondary ions with measured matrix factors by simply extrapolating the result to Ξ = 0. Care must be taken in quoting interface resolutions since those measured for predominantly Gaussian interfaces with Ξ above or below zero, without correction, appear significantly better than the true resolution.

  4. The Influence of Flow and Bed Slope on Gas Transfer in Steep Streams and Their Implications for Evasion of CO2

    Science.gov (United States)

    Maurice, L.; Rawlins, B. G.; Farr, G.; Bell, R.; Gooddy, D. C.

    2017-11-01

    The evasion of greenhouse gases (including CO2, CH4, and N2O) from streams and rivers to the atmosphere is an important process in global biogeochemical cycles, but our understanding of gas transfer in steep (>10%) streams, and under varying flows, is limited. We investigated gas transfer using combined tracer injections of SF6 and salt. We used a novel experimental design in which we compared four very steep (18.4-29.4%) and four moderately steep (3.7-7.6%) streams and conducted tests in each stream under low flow conditions and during a high-discharge event. Most dissolved gas evaded over short distances ( 100 and 200-400 m, respectively), so accurate estimates of evasion fluxes will require sampling of dissolved gases at these scales to account for local sources. We calculated CO2 gas transfer coefficients (KCO2) and found statistically significant differences between larger KCO2 values for steeper (mean 0.465 min-1) streams compared to those with shallower slopes (mean 0.109 min-1). Variations in flow had an even greater influence. KCO2 was substantially larger under high (mean 0.497 min-1) compared to low flow conditions (mean 0.077 min-1). We developed a statistical model to predict KCO2 using values of streambed slope × discharge which accounted for 94% of the variation. We show that two models using slope and velocity developed by Raymond et al. (2012) for streams and rivers with shallower slopes also provide reasonable estimates of our CO2 gas transfer velocities (kCO2; m d-1). We developed a robust field protocol which could be applied in future studies.

  5. Heat Transfer and Observation of Droplet-Surface Interactions During Air-Mist Cooling at CSP Secondary System Temperatures

    Science.gov (United States)

    Huerta L., Mario E.; Mejía G., M. Esther; Castillejos E., A. Humberto

    2016-04-01

    Air-mists are key elements in the secondary cooling of modern thin steel slab continuous casters. The selection of water, W, and air, A, flow rates, and pressures in pneumatic nozzles open up a wide spectrum of cooling possibilities by their influence on droplet diameter, d, droplet velocity, v, and water impact flux, w. Nonetheless, due to the harsh environment resulting from the high temperatures and dense mists involved, there is very little information about the correlation between heat flux extracted, - q, and mist characteristics, and none about the dynamics of drop-wall interactions. For obtaining both kinds of information, this work combines a steady-state heat flux measuring method with a visualization technique based on a high-speed camera and a laser illumination system. For wall temperatures, T w, between ~723 K and ~1453 K (~450 °C and ~1180 °C), which correspond to film boiling regime, it was confirmed that - q increases with increase in v, w, and T w and with decrease in d. It should be noticed, however, that the increase in w generally decreases the spray cooling effectiveness because striking drops do not evaporate efficiently due to the interference by liquid remains from previous drops. Visualization of the events happening close to the surface also reveals that the contact time of the liquid with the surface is very brief and that rebounding, splashing, sliding, and levitation of drops lead to ineffective contact with the surface. At the center of the mist footprint, where drops impinge nearly normal to the surface those with enough momentum establish intimate contact with it before forming a vapor layer that pushes away the remaining liquid. Also, some drops are observed sliding upon the surface or levitating close to it; these are drops with low momentum which are influenced by the deflecting air stream. At footprint positions where oblique impingement occurs, frequently drops are spotted sliding or levitating and liquid films flowing in

  6. Analysis of expiration gas in intensive care patients with SIRS/sepsis using proton-transfer-reaction-mass-spectrometry

    International Nuclear Information System (INIS)

    Bodrogi, F.B.M.

    2003-11-01

    In 1971, Pauling and co-workers were the first to detect volatile organic compounds (VOC) in human breath. Since then, a number of technical applications for breath gas analyses have been designed and processed, among them gas chromatography and proton transfer reaction-mass spectrometry (PTR-MS). Due to this technical progress it is meanwhile possible to correlate different kinds and stages of diseases with measurable changes in the patient's VOC profile. The aim of the present study was to investigate the composition of VOC in exhaled air of patients with sepsis via PTR-MS. To isolate distinct volatile organic compounds that may serve as clinical markers for the onset, the progress, as well as the outcome of the disease, the results obtained from septic patients were compared with two different control groups: 25 healthy, non-smoking volunteers enrolled in the day-case-surgery and 25 post-operative in-patients residing in post-anaesthetic care units (PACU). PTR-MS is capable to analyze VOC according to their molecular weight with a range between 21-230 Da. A total of 210 different masses has been detected in the present study. 54 masses were significantly different in exhaled air of septic patients as compared to healthy controls as well as post-operative patients. Among them, mass 69 representing isoprene might be of special interest for the diagnosis of sepsis. Although no exact biochemical properties of isoprene have been described to date, it is known that isoprene synthesis is increased in plants following exposure to oxidative stress. Chronic, systemic infectious diseases like sepsis are accompanied by the production of reactive oxygen species, indicating that isoprene might be increased in the course of sepsis, too. In the present study, isoprene values were markedly higher in septic patients as compared to PACU residents (3.3-fold increase in mean value) and to healthy volunteers (2.2-fold increase in mean value). In addition (and in contrast to other VOC

  7. Interaction of chemical reactions and radiant heat transfer with temperature turbulent pulsations and its effect on heat traner in high-temperature gas flows

    International Nuclear Information System (INIS)

    Petukhov, B.S.; Zal'tsman, I.G.; Shikov, V.K.

    1980-01-01

    Methods of taking account of mutual effect of chemical transformations, radiation and turbulence in the calculations of heat transfer in gas flows are considered. Exponential functions of medium parameters are used to describe chemical sources and optical properties of media. It is shown using as an example the dissociation reaction C 2 reversible 2C that the effect of temperature and composition pulsations on recombination rates is negligibly small. It is also shown on the example of turbulent flow of hot molecular gas in a flat channel with cold walls that at moderate temperatures the effect of temperature pulsations on heat radiation flow can be significant (30-40%). The calculational results also show that there is a region in a turbulent boundary layer where the radiation greatly affects the coefficient of turbulent heat transfer

  8. 75 FR 39680 - Houston Pipe Line Company LP, Worsham-Steed Gas Storage, L.P., Energy Transfer Fuel, LP, Mid...

    Science.gov (United States)

    2010-07-12

    ... DEPARTMENT OF ENERGY Federal Energy Regulatory Commission [Docket No. PR10-44-000; Docket No. PR10-46-000; Docket No. PR10-48- 000; Docket No. PR10-49-000; Docket No. PR10-50-000] Houston Pipe Line Company LP, Worsham-Steed Gas Storage, L.P., Energy Transfer Fuel, LP, Mid Continent Market Center, L.L.C...

  9. The relationship between vapour pressure, vaporization enthalpy, and enthalpy of transfer from solution to gas: An extension of the Martin equation

    International Nuclear Information System (INIS)

    Srisaipet, A.; Aryusuk, K.; Lilitchan, S.; Krisnangkura, K.

    2007-01-01

    Martin's equation, Δ sln g G=Δ sln g G o +zδ sln g G, is extended to cover vaporization free energy (Δ l g G). The extended equation is further expanded in terms of enthalpy and entropy and then used to correlate vaporization enthalpy (Δ l g H) and enthalpy of transfer from solution to gas (Δ sln g H). Data available in the literatures are used to validate and support the speculations derived from the proposed equation

  10. Investigation on the performance and emission parameters of dual fuel diesel engine with mixture combination of hydrogen and producer gas as secondary fuel

    Directory of Open Access Journals (Sweden)

    A. E. Dhole

    2016-06-01

    Full Text Available This study presents experimental investigation in to the effects of using mixture of producer gas and hydrogen in five different proportions as a secondary fuel with diesel as pilot fuel at wide range of load conditions in dual fuel operation of a 4 cylinder turbocharged and intercooled 62.5 kW gen-set diesel engine at constant speed of 1500 RPM. Secondary fuel Substitution is in different percentage of diesel at each load. To generate producer gas, the rice husk was used as source in the downdraft gasifier. The performance and emission characteristics of the dual fuel engine are compared with that of diesel engine at different load conditions. It was found that of all the combinations tested, mixture combination of PG:H2=(60:40% is the most suited one at which the brake thermal efficiency is in good comparison to that of diesel operation. Decreased NOx emissions and increased CO emissions were observed for dual fuel mode for all the fuel combinations compared to diesel fuel operation.

  11. Enhancement of Leaf Gas Exchange and Primary Metabolites under Carbon Dioxide Enrichment Up-Regulates the Production of Secondary Metabolites in Labisia pumila Seedlings

    Directory of Open Access Journals (Sweden)

    Mohd Hafiz Ibrahim

    2011-05-01

    Full Text Available A split plot 3 by 3 experiment was designed to investigate and distinguish the relationships among production of primary metabolites (soluble sugar and starch, secondary metabolites (total phenolics, TP; total flavonoids, TF and leaf gas exchange of three varieties of the Malaysian medicinal herb Labisia pumila Blume, namely the varieties alata, pumila and lanceolata, under three levels of CO2 enrichment (400, 800 and 1,200 µmol mol−1 for 15 weeks. The treatment effects were solely contributed by CO2 enrichment levels; no varietal differences were observed. As CO2 levels increased from 400 to 1,200 µmol mol−1, the production of carbohydrates also increased steadily, especially for starch more than soluble sugar (sucrose. TF and TP content, simultaneously, reached their peaks under 1,200 µmol exposure, followed by 800 and 400 µmol mol−1. Net photosynthesis (A and quantum efficiency of photosystem II (fv/fm were also enhanced as CO2 increased from 400 to 1,200 µmol mol−1. Leaf gas exchange characteristics displayed a significant positive relationship with the production of secondary metabolites and carbohydrate contents. The increase in production of TP and TFs were manifested by high C/N ratio and low protein content in L. pumila seedlings, and accompanied by reduction in cholorophyll content that exhibited very significant negative relationships with total soluble sugar, starch and total non structural carbohydrate.

  12. Flow pattern-based mass and heat transfer and frictional drag of gas-non-Newtonian liquid flow in helical coil: two- and three-phase systems

    Science.gov (United States)

    Thandlam, Anil Kumar; Das, Chiranjib; Majumder, Subrata Kumar

    2017-04-01

    Investigation of wall-liquid mass transfer and heat transfer phenomena with gas-Newtonian and non-Newtonian fluids in vertically helical coil reactor have been reported in this article. Experiments were conducted to investigate the effect of various dynamic and geometric parameters on mass and heat transfer coefficients in the helical coil reactor. The flow pattern-based heat and mass transfer phenomena in the helical coil reactor are highlighted at different operating conditions. The study covered a wide range of geometric parameters such as diameter of the tube ( d t ), diameter of the coil ( D c ), diameter of the particle ( d p ), pitch difference ( p/D c ) and concentrations of non-Newtonian liquid. The correlation models for the heat and mass transfer coefficient based on the flow pattern are developed which may be useful in process scale-up of the helical coil reactor for industrial application. The frictional drag coefficient was also estimated and analyzed by mass transfer phenomena based on the electrochemical method.

  13. An Evaluation of Gas Law Webquest Based on Active Learning Style in a Secondary School in Malaysia

    Science.gov (United States)

    Alias, Norlidah; DeWitt, Dorothy; Siraj, Saedah

    2014-01-01

    In this study, the PTEchLS WebQuest on Gas Laws was evaluated. It was designed for Form Four students with active learning styles. The focus of the evaluation was on the usability and effectiveness of the PTechLS WebQuest. Data were collected from interviews and students' achievement scores. Two teachers and eight students volunteered to…

  14. Mass transfer of reacting chemical species: an example from the radiation chemistry of AGR coolant gas mixtures (CO2/CO/CH4/H2O)

    International Nuclear Information System (INIS)

    Burns, W.G.; Barton, R.A.; Goodall, J.A.B.; Mardon, T.

    1988-01-01

    Advanced gas-cooled reactor (AGR) coolant gas is predominantly carbon dioxide with additions of carbon monoxide and methane to minimize the attack of the graphite moderator by irradiated carbon dioxide. The presence of the additives, especially methane, causes a range of reactive gas phase species to be formed. Some of these react with fuel element and other surfaces to form a carbonaceous deposit which inhibits heat transfer and is therefore deleterious to reactor performance. The mass transfer of a reactive intermediate from a flowing gas stream to a surface is an essential part of the mechanism of deposition and is considered here in principle using an existing complex reaction mechanism for AGR gas chemistry. The normal approximation for dealing with mass transfer of stable species is equivalent to assuming a bulk region with high diffusion constants and a thin boundary layer with normal diffusion constants where diffusion to the wall occurs. When considering reacting species it is found that a logical extension of this approximation shows that the approximation is useful only if there are no reactions in the boundary layer. If reactions occur in the boundary layer the removal reaction competes with other chemical reactions and gives a higher flux to the wall than would be calculated for a stable species. It is shown that an appreciable proportion of the added methane could be transformed to carbon deposit and that the removal of radicals in wall reactions appreciably affects the chemistry of the system and the concentrations of species which otherwise would be formed in reactions of the removed radicals. (author)

  15. Influence of fluid-mechanical characteristics of the system on the volumetric mass transfer coefficient and gas dispersion in three-phase system

    Directory of Open Access Journals (Sweden)

    Knežević Milena M.

    2014-01-01

    Full Text Available Distribution of gas bubbles and volumetric mass transfer coefficient, Kla, in a three phase system, with different types of solid particles at different operation conditions were studied in this paper. The ranges of superficial gas and liquid velocities used in this study were 0,03-0,09 m/s and 0-0,1 m/s, respectively. The three different types of solid particles were used as a bed in the column (glass dp=3 mm, dp=6 mm; ceramic dp=6 mm. The experiments were carried out in a 2D plexiglas column, 278 x 20,4 x 500 mm and in a cylindrical plexiglas column, with a diameter of 64 mm and a hight of 2000 mm. The Kla coefficient increased with gas and liquid velocities. Results showed that the volumetric mass transfer coefficient has a higher values in three phase system, with solid particles, compared with two phase system. The particles properties (diameter and density have a major impact on oxygen mass transfer in three phase systems.

  16. Experimental investigation of the liquid volumetric mass transfer coefficient for upward gas-liquid two-phase flow in rectangular microchannels

    Directory of Open Access Journals (Sweden)

    X. Y. Ji

    2010-12-01

    Full Text Available The gas-liquid two-phase mass transfer process in microchannels is complicated due to the special dynamical characteristics. In this work, a novel method was explored to measure the liquid side volumetric mass transfer coefficient kLa. Pressure transducers were utilized to measure the pressure variation of upward gas-liquid two-phase flow in three vertical rectangular microchannels and the liquid side volumetric mass transfer coefficient kLa was calculated through the Pressure-Volume-Temperature correlation of the gas phase. Carbon dioxide-water, carbon dioxide-ethanol and carbon dioxide-n-propanol were used as working fluids, respectively. The dimensions of the microchannels were 40 µm×240 µm (depth×width, 100 µm×800 µm and 100 µm×2000 µm, respectively. Results showed that the channel diameter and the capillary number influence kLa remarkably and that the maximum value of kLa occurs in the annular flow regime. A new correlation of kLa was proposed based on the Sherwood number, Schmidt number and the capillary number. The predicted values of kLa agreed well with the experimental data.

  17. Sensitivity of Global Sea-Air CO2 Flux to Gas Transfer Algorithms, Climatological Wind Speeds, and Variability of Sea Surface Temperature and Salinity

    Science.gov (United States)

    McClain, Charles R.; Signorini, Sergio

    2002-01-01

    Sensitivity analyses of sea-air CO2 flux to gas transfer algorithms, climatological wind speeds, sea surface temperatures (SST) and salinity (SSS) were conducted for the global oceans and selected regional domains. Large uncertainties in the global sea-air flux estimates are identified due to different gas transfer algorithms, global climatological wind speeds, and seasonal SST and SSS data. The global sea-air flux ranges from -0.57 to -2.27 Gt/yr, depending on the combination of gas transfer algorithms and global climatological wind speeds used. Different combinations of SST and SSS global fields resulted in changes as large as 35% on the oceans global sea-air flux. An error as small as plus or minus 0.2 in SSS translates into a plus or minus 43% deviation on the mean global CO2 flux. This result emphasizes the need for highly accurate satellite SSS observations for the development of remote sensing sea-air flux algorithms.

  18. Flow prediction and heat transfer in a cooling square duch of a gas turbine blade using CFD; Predicciones de flujo y transferencia de calor en un conductor de alabe enfriado de turbina de gas utilizando CFD

    Energy Technology Data Exchange (ETDEWEB)

    Urquiza B, Gustavo [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico); Sierra E, Fernando [Universidad Nacional Autonoma de Mexico, Mexico D.F. (Mexico); Kubiak S, Janusz; Campos A, Rafael [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)

    2003-10-15

    A numerical investigation has been conducted to study the turbulent flow and the heat transfer in a blade turbine coolant passage involving a 180 degrees turn. The study provides a comparison test for two turbulence models. The numerical solution was conducted employing two models for turbulence, the renormalization Group Theory (RNG) and the Reynolds Stress Model (RSM), using a refined grid to model with detail the recirculating flow. Computations are performed with a commercial finite volume code which solves three dimensional, incompressible, Navier-Stokes and Energy equations. At the passage turn, significant secondary flows are present, formed by a pair of symmetrical vortices. Results have been compared against published experimental data for Re = 53 000. Very good agreement is achieved for the prediction of the local static pressure distribution along the passage. A strong effect of rotation has been observed mainly in the flow field as described in detail in the paper. [Spanish] En este trabajo se presenta una investigacion numerica para estudiar el flujo turbulento y la transferencia de calor en un conducto de enfriamiento de un alabes de turbina de gas con giro de 180 grados. El estudio proporciona una comparacion de resultados para dos modelos de turbulencia. La solucion numerica emplea dos modelos de turbulencia: el modelo de esfuerzos de Reynolds (RSM) y el modelo de la teoria del grupo de renormalizacion (RNG), utilizando una malla refinada para modelar con detalle el flujo de recirculacion. Los calculos fueron realizados con un codigo comercial de volumenes finitos el cual resuelve las ecuaciones tridimensionales de Navier-Stoke y de energia para flujo incompresible. En la seccion de giro del conductor, aparecen flujos secundarios significativos, formados por un par de celulas simetricas. Los resultados han sido comparados contra datos experimentales de la literatura para Re = 53 000. se obtuvo un buen acuerdo para la prediccion de la distribucion de

  19. The secondary release of mercury in coal fly ash-based flue-gas mercury removal technology.

    Science.gov (United States)

    He, Jingfeng; Duan, Chenlong; Lei, Mingzhe; Zhu, Xuemei

    2016-01-01

    The secondary release of mercury from coal fly ash is a negative by-product from coal-fired power plants, and requires effective control to reduce environmental pollution. Analysing particle size distribution and composition of the coal fly ash produced by different mercury removing technologies indicates that the particles are generally less than 0.5 mm in size and are composed mainly of SiO2, Al2O3, and Fe2O3. The relationships between mercury concentration in the coal fly ash, its particle size, and loss of ignition were studied using different mercury removing approaches. The research indicates that the coal fly ash's mercury levels are significantly higher after injecting activated carbon or brominating activated carbon when compared to regular cooperating-pollution control technology. This is particularly true for particle size ranges of >0.125, 0.075-0.125, and 0.05-0.075 mm. Leaching experiments revealed the secondary release of mercury in discarded coal fly ash. The concentration of mercury in the coal fly ash increases as the quantity of injecting activated carbon or brominating activated carbon increases. The leached concentrations of mercury increase as the particle size of the coal fly ash increases. Therefore, the secondary release of mercury can be controlled by adding suitable activated carbon or brominating activated carbon when disposing of coal fly ash. Adding CaBr2 before coal combustion in the boiler also helps control the secondary release of mercury, by increasing the Hg(2+) concentration in the leachate. This work provides a theoretical foundation for controlling and removing mercury in coal fly ash disposal.

  20. Physisorption-Based Charge Transfer in Two-Dimensional SnS2 for Selective and Reversible NO2 Gas Sensing.

    Science.gov (United States)

    Ou, Jian Zhen; Ge, Wanyin; Carey, Benjamin; Daeneke, Torben; Rotbart, Asaf; Shan, Wei; Wang, Yichao; Fu, Zhengqian; Chrimes, Adam F; Wlodarski, Wojtek; Russo, Salvy P; Li, Yong Xiang; Kalantar-Zadeh, Kourosh

    2015-10-27

    Nitrogen dioxide (NO2) is a gas species that plays an important role in certain industrial, farming, and healthcare sectors. However, there are still significant challenges for NO2 sensing at low detection limits, especially in the presence of other interfering gases. The NO2 selectivity of current gas-sensing technologies is significantly traded-off with their sensitivity and reversibility as well as fabrication and operating costs. In this work, we present an important progress for selective and reversible NO2 sensing by demonstrating an economical sensing platform based on the charge transfer between physisorbed NO2 gas molecules and two-dimensional (2D) tin disulfide (SnS2) flakes at low operating temperatures. The device shows high sensitivity and superior selectivity to NO2 at operating temperatures of less than 160 °C, which are well below those of chemisorptive and ion conductive NO2 sensors with much poorer selectivity. At the same time, excellent reversibility of the sensor is demonstrated, which has rarely been observed in other 2D material counterparts. Such impressive features originate from the planar morphology of 2D SnS2 as well as unique physical affinity and favorable electronic band positions of this material that facilitate the NO2 physisorption and charge transfer at parts per billion levels. The 2D SnS2-based sensor provides a real solution for low-cost and selective NO2 gas sensing.

  1. Active Site Dynamical Effects in the Hydrogen Transfer Rate-limiting Step in the Catalysis of Linoleic Acid by Soybean Lipoxygenase-1 (SLO-1): Primary and Secondary Isotope Contributions.

    Science.gov (United States)

    Phatak, Prasad; Venderley, Jordan; Debrota, John; Li, Junjie; Iyengar, Srinivasan S

    2015-07-30

    Using ab initio molecular dynamics (AIMD) simulations that facilitate the treatment of rare events, we probe the active site participation in the rate-determining hydrogen transfer step in the catalytic oxidation of linoleic acid by soybean lipoxygenase-1 (SLO-1). The role of two different active site components is probed. (a) On the hydrogen atom acceptor side of the active site, the hydrogen bonding propensity between the acceptor side hydroxyl group, which is bound to the iron cofactor, and the backbone carboxyl group of isoleucine (residue number 839) is studied toward its role in promoting the hydrogen transfer event. Primary and secondary (H/D) isotope effects are also probed and a definite correlation with subtle secondary H/D isotope effects is found. With increasing average nuclear kinetic energy, the increase in transfer probability is enhanced due to the presence of the hydrogen bond between the backbone carbonyl of I839 and the acceptor oxygen. Further increase in average nuclear kinetic energy reduces the strength of this secondary hydrogen bond which leads to a deterioration in hydrogen transfer rates and finally embrances an Arrhenius-like behavior. (b) On the hydrogen atom donor side, the coupling between vibrational modes predominantly localized on the donor-side linoleic acid group and the reactive mode is probed. There appears to be a qualitative difference in the coupling between modes that belong to linoleic acid and the hydrogen transfer mode, for hydrogen and deuterium transfer. For example, the donor side secondary hydrogen atom is much more labile (by nearly a factor of 5) during deuterium transfer as compared to the case for hydrogen transfer. This appears to indicate a greater coupling between the modes belonging to the linoleic acid scaffold and the deuterium transfer mode and also provides a new rationalization for the abnormal (nonclassical) secondary isotope effect results obtained by Knapp, Rickert, and Klinman in J. Am. Chem. Soc

  2. Homogenization and two scales convergence of some stationary and non-stationary heat transfer problems, application to gas cooled nuclear rectors

    International Nuclear Information System (INIS)

    Habibi, Z.

    2011-01-01

    We are interested in the homogenization of heat transfer in periodic porous media modelling the geometry of a gas cooled nuclear reactor. This geometry is made of a solid media perforated by several long thin parallel cylinders, the diameter of which is of the same order than the period. The heat is transported by conduction in the solid part of the domain and by conduction, convection and radiative transfer in the fluid part (the cylinders). A non-local boundary condition models the radiative heat transfer on the cylinder walls. It is a stationary analysis corresponding to a nominal performance of the reactor core, and also non-stationary corresponding to a normal shut-down of the core. To obtain the homogenized problem we first use a formal two-scale asymptotic expansion method. The mathematical justification of our results is based on the notion of two-scale convergence. One feature of this work in dimension 3 is that it combines homogenization with a 3D to 2D asymptotic analysis since the radiative transfer in the limit cell problem is purely two-dimensional. A second feature of this work is the study of this heat transfer when it contains an oscillating thermal source at the microscopic level and a thermal exchange with the perforations. In this context, our numerical analysis shows a non-negligible contribution of the second order corrector which helps us to model the gradients appearing between the source area and the perforations. (author) [fr

  3. A comparison of fuzzy logic and cluster renewal approaches for heat transfer modeling in a 1296 t/h CFB boiler with low level of flue gas recirculation

    Science.gov (United States)

    Błaszczuk, Artur; Krzywański, Jarosław

    2017-03-01

    The interrelation between fuzzy logic and cluster renewal approaches for heat transfer modeling in a circulating fluidized bed (CFB) has been established based on a local furnace data. The furnace data have been measured in a 1296 t/h CFB boiler with low level of flue gas recirculation. In the present study, the bed temperature and suspension density were treated as experimental variables along the furnace height. The measured bed temperature and suspension density were varied in the range of 1131-1156 K and 1.93-6.32 kg/m3, respectively. Using the heat transfer coefficient for commercial CFB combustor, two empirical heat transfer correlation were developed in terms of important operating parameters including bed temperature and also suspension density. The fuzzy logic results were found to be in good agreement with the corresponding experimental heat transfer data obtained based on cluster renewal approach. The predicted bed-to-wall heat transfer coefficient covered a range of 109-241 W/(m2K) and 111-240 W/(m2K), for fuzzy logic and cluster renewal approach respectively. The divergence in calculated heat flux recovery along the furnace height between fuzzy logic and cluster renewal approach did not exceeded ±2%.

  4. A comparison of fuzzy logic and cluster renewal approaches for heat transfer modeling in a 1296 t/h CFB boiler with low level of flue gas recirculation

    Directory of Open Access Journals (Sweden)

    Błaszczuk Artur

    2017-03-01

    Full Text Available The interrelation between fuzzy logic and cluster renewal approaches for heat transfer modeling in a circulating fluidized bed (CFB has been established based on a local furnace data. The furnace data have been measured in a 1296 t/h CFB boiler with low level of flue gas recirculation. In the present study, the bed temperature and suspension density were treated as experimental variables along the furnace height. The measured bed temperature and suspension density were varied in the range of 1131-1156 K and 1.93-6.32 kg/m3, respectively. Using the heat transfer coefficient for commercial CFB combustor, two empirical heat transfer correlation were developed in terms of important operating parameters including bed temperature and also suspension density. The fuzzy logic results were found to be in good agreement with the corresponding experimental heat transfer data obtained based on cluster renewal approach. The predicted bed-to-wall heat transfer coefficient covered a range of 109-241 W/(m2K and 111-240 W/(m2K, for fuzzy logic and cluster renewal approach respectively. The divergence in calculated heat flux recovery along the furnace height between fuzzy logic and cluster renewal approach did not exceeded ±2%.

  5. Physical Therapy Intervention to Augment Outcomes Of Lymph Node Transfer Surgery for a Breast Cancer Survivor with Secondary Upper Extremity Lymphedema: A Case Report.

    Science.gov (United States)

    McKey, Katelyn P; Alappattu, Meryl J

    Lymphedema is an incurable complication of breast cancer treatment that affects roughly 20 percent of women. It is often managed via complete decongestive therapy, which includes manual lymph drainage, therapeutic compression, skin care, and exercise. Lymph node transfer is a new and expensive surgical intervention that uses one's own lymph nodes and implants them in the affected upper extremity. Previous research has investigated augmenting lymph node transfer surgery with complete decongestive therapy, but there is a lack of evidence regarding the success of focusing lymph drainage against the normal pressure gradient toward a surgical flap located on the wrist. The patient's main motivation for the surgical intervention was to alleviate her daily burden of complete decongestive therapy. The purpose of this case report was to compare the methods and results of pre-surgical complete decongestive physical therapy to a post-operation modified approach that directed lymph fluid away from the major lymphatic ducts and instead toward a surgical flap on the wrist of a patient with lymphedema. A 65-year-old female presented with secondary upper extremity lymphedema following breast cancer treatment. Her circumferential measurements and L-Dex score corroborated this diagnosis, and she had functional deficits in upper extremity range of motion. She was seen for 10 visits of traditional complete decongestive therapy prior to her lymph node transfer surgery and 24 treatments of modified complete decongestive therapy over the course of six months following surgery. At six months, the patient had minor improvements in the Functional Assessment of Chronic Illness Therapy-Fatigue, Disabilities of the Arm, Shoulder and Hand questionnaire, range of motion, and upper extremity strength. However, her circumferential measurements and L-Dex scores showed a meaningful increase in limb girth. The patient's smallest upper extremity volumes were documented before the operation after two

  6. Enhancement of Oxygen Mass Transfer and Gas Holdup Using Palm Oil in Stirred Tank Bioreactors with Xanthan Solutions as Simulated Viscous Fermentation Broths

    Directory of Open Access Journals (Sweden)

    Suhaila Mohd Sauid

    2013-01-01

    Full Text Available Volumetric mass transfer coefficient (kLa is an important parameter in bioreactors handling viscous fermentations such as xanthan gum production, as it affects the reactor performance and productivity. Published literatures showed that adding an organic phase such as hydrocarbons or vegetable oil could increase the kLa. The present study opted for palm oil as the organic phase as it is plentiful in Malaysia. Experiments were carried out to study the effect of viscosity, gas holdup, and kLa on the xanthan solution with different palm oil fractions by varying the agitation rate and aeration rate in a 5 L bench-top bioreactor fitted with twin Rushton turbines. Results showed that 10% (v/v of palm oil raised the kLa of xanthan solution by 1.5 to 3 folds with the highest kLa value of 84.44 h−1. It was also found that palm oil increased the gas holdup and viscosity of the xanthan solution. The kLa values obtained as a function of power input, superficial gas velocity, and palm oil fraction were validated by two different empirical equations. Similarly, the gas holdup obtained as a function of power input and superficial gas velocity was validated by another empirical equation. All correlations were found to fit well with higher determination coefficients.

  7. The gas/stream ratio as indicator of heat transfer at the Solfatara fumaroles, Phlegraean Fields (Italy)

    Energy Technology Data Exchange (ETDEWEB)

    Cioni, R.; Corazza, E. (C.N.R., Pisa (Italy)); Marini, L. (Geotermica Italiana, Pisa (Italy))

    1984-01-01

    A simple geochemical model of Solfatara, Phlegraean Fields (Italy), is proposed on the basis of gas composition and temperature at the surface. Data on the Solfatara fumaroles have been collected since 1979 within the framework of a geochemical monitoring for the surveillance of the Phlegraean volcanic system. Surface manifestations of Solfatara are likely to be fed through isoenthalpic expansion of dry steam, which separates from a geothermal liquid in an intensively fractured zone at about 236{degree}C. This value is consistent both with gas composition and surface temperature. The gas/steam ratio appears to be the most effective parameter to detect changes of heat flow at depth. Actually a remarkable decrease in the gas/steam ratio has been observed since 1981, while the gas composition and the temperature did not change significantly. These facts suggest increased heat flow at depth.

  8. Investigation of the effects of pressure gradient, temperature and wall temperature ratio on the stagnation point heat transfer for circular cylinders and gas turbine vanes

    Science.gov (United States)

    Nagamatsu, H. T.; Duffy, R. E.

    1984-01-01

    Low and high pressure shock tubes were designed and constructed for the purpose of obtaining heat transfer data over a temperature range of 390 to 2500 K, pressures of 0.3 to 42 atm, and Mach numbers of 0.15 to 1.5 with and without pressure gradient. A square test section with adjustable top and bottom walls was constructed to produce the favorable and adverse pressure gradient over the flat plate with heat gages. A water cooled gas turbine nozzle cascade which is attached to the high pressure shock tube was obtained to measuse the heat flux over pressure and suction surfaces. Thin-film platinum heat gages with a response time of a few microseconds were developed and used to measure the heat flux for laminar, transition, and turbulent boundary layers. The laminar boundary heat flux on the shock tube wall agreed with Mirel's flat plate theory. Stagnation point heat transfer for circular cylinders at low temperature compared with the theoretical prediction, but for a gas temperature of 922 K the heat fluxes were higher than the predicted values. Preliminary flat plate heat transfer data were measured for laminar, transition, and turbulent boundary layers with and without pressure gradients for free-stream temperatures of 350 to 2575 K and flow Mach numbers of 0.11 to 1.9. The experimental heat flux data were correlated with the laminar and turbulent theories and the agreement was good at low temperatures which was not the case for higher temperatures.

  9. Electrochemical characteristics of silver- and nickel-coated synthetic graphite prepared by a gas suspension spray coating method for the anode of lithium secondary batteries

    International Nuclear Information System (INIS)

    Choi, Won Chang; Byun, Dongjin; Lee, Joong Kee; Cho, Byung won

    2004-01-01

    Four kinds of synthetic graphite coated with silver and nickel for the anodes of lithium secondary batteries were prepared by a gas suspension spray coating method. The electrode coated with silver showed higher charge-discharge capacities due to a Ag-Li alloy, but rate capability decreased at higher charge-discharge rate. This result can be explained by the formation of an artificial Ag oxidation film with higher impedance, this lowered the rate capability at high charge-discharge rate due to its low electrical conductivity. Rate capability is improved, however, by coating nickel and silver together on the surface of synthetic graphite. The nickel which is inactive with oxidation reaction plays an important role as a conducting agent which enhanced the conductivity of the electrode

  10. Transfer of preheat-treated SnO 2 via a sacrificial bridge-type ZnO layer for ethanol gas sensor

    KAUST Repository

    Lee, Da Hoon

    2017-08-05

    The progress in developing the microelectromechanical system (MEMS) heater-based SnO2 gas sensors was hindered by the subsequent heat treatment of the tin oxide (SnO2), nevertheless it is required to obtain excellent sensor characteristics. During the sintering process, the MEMS heater and the contact electrodes can be degraded at such a high temperature, which could reduce the sensor response and reliability. In this research, we presented a process of preheating the printed SnO2 sensing layer on top of a sacrificial bridge-type ZnO layer at such a high temperature, followed by transferring it onto the contact electrodes of sensor device by selective etching of the sacrificial ZnO layer. Therefore, the sensor device was not exposed to the high sintering temperature. The SnO2 gas sensor fabricated by the transfer process exhibited a rectangular sensing curve behavior with a rapid response of 52 s at 20 ppm ethanol concentration. In addition, reliable and repeatable sensing characteristics were obtained even at an ethanol gas concentration of 5 ppm.

  11. Ultrasonic nebulization extraction-heating gas flow transfer-headspace single drop microextraction of essential oil from pericarp of Zanthoxylum bungeanum Maxim.

    Science.gov (United States)

    Wei, Shigang; Zhang, Huihui; Wang, Yeqiang; Wang, Lu; Li, Xueyuan; Wang, Yinghua; Zhang, Hanqi; Xu, Xu; Shi, Yuhua

    2011-07-22

    The ultrasonic nebulization extraction-heating gas flow transfer coupled with headspace single drop microextraction (UNE-HGFT-HS-SDME) was developed for the extraction of essential oil from Zanthoxylum bungeanum Maxim. The gas chromatography-mass spectrometry was applied to the determination of the constituents in the essential oil. The contents of the constituents from essential oil obtained by the proposed method were found to be more similar to those obtained by hydro-distillation (HD) than those obtained by ultrasonic nebulization extraction coupled with headspace single drop microextraction (UNE-HS-SDME). The heating gas flow was firstly used in the analysis of the essential oil to transfer the analytes from the headspace to the solvent microdrop. The relative standard deviations for determining the five major constituents were in the range from 1.5 to 6.7%. The proposed method is a fast, sensitive, low cost and small sample consumption method for the determination of the volatile and semivolatile constituents in the plant materials. Copyright © 2011 Elsevier B.V. All rights reserved.

  12. Net sea–air CO2 flux uncertainties in the Bay of Biscay based on the choice of wind speed products and gas transfer parameterizations

    Directory of Open Access Journals (Sweden)

    P. Otero

    2013-05-01

    Full Text Available The estimation of sea–air CO2 fluxes is largely dependent on wind speed through the gas transfer velocity parameterization. In this paper, we quantify uncertainties in the estimation of the CO2 uptake in the Bay of Biscay resulting from the use of different sources of wind speed such as three different global reanalysis meteorological models (NCEP/NCAR 1, NCEP/DOE 2 and ERA-Interim, one high-resolution regional forecast model (HIRLAM-AEMet, winds derived under the Cross-Calibrated Multi-Platform (CCMP project, and QuikSCAT winds in combination with some of the most widely used gas transfer velocity parameterizations. Results show that net CO2 flux estimations during an entire seasonal cycle (September 2002–September 2003 may vary by a factor of ~ 3 depending on the selected wind speed product and the gas exchange parameterization, with the highest impact due to the last one. The comparison of satellite- and model-derived winds with observations at buoys advises against the systematic overestimation of NCEP-2 and the underestimation of NCEP-1. In the coastal region, the presence of land and the time resolution are the main constraints of QuikSCAT, which turns CCMP and ERA-Interim in the preferred options.

  13. 77 FR 2293 - AmeriGas Propane, L.P., AmeriGas Propane, Inc., Energy Transfer Partners, L.P., and Energy...

    Science.gov (United States)

    2012-01-17

    ... of these changes in demand, refilling cylinders does not provide a competitive constraint on the... selling portable cylinders prefilled with propane commonly used for barbeque grills (referred to herein as ``propane exchange cylinders''). The AmeriGas Cylinder Exchange or ``ACE'' division is also engaged in the...

  14. [Gas-permeable scleral lens for management of severe keratoconjunctivitis sicca secondary to chronic graft-versus-host disease].

    Science.gov (United States)

    Rossi, P; Delcampe, A; Gueudry, J; Duncombe, A; Gabison, E; Doan, S; Muraine, M

    2015-11-01

    Graft-versus-host disease is a major complication of allogeneic hematopoietic stem cell transplantation. Severe keratoconjunctivitis sicca is common in patients with chronic GVH disease. The goal of this study was to evaluate the safety and efficacy of a gas-permeable scleral lens in the management of severe dry eye disease associated with chronic GVH. This is a retrospective study from June 2009 to November 2013. Patients fitted with scleral lenses for severe keratoconjunctivitis sicca associated with chronic GVH were included. The main outcomes measured were best-corrected visual acuity and quality of life (OSDI and NEI-VFQ25) composite scores before and six months after scleral lens fitting. Sixteen patients were included. The mean age was 52 years (19-69 years). Mean follow-up was 20 months (3-48 months). All patients reported improvement of their ocular symptoms. Best corrected visual acuity improved from 0.21 ± 0.26 to 0.1 ± 0.14 logMAR (P = 0.002), OSDI score improved from 92.1 ± 11.3 to 23.5 ± 11.2 (P = 0.002) and NEI-VFQ25 improved from 41.3 ± 7 to 83.1 ± 15.9 (P = 0.003), 6 months after scleral lens fitting. No serious adverse events, infectious, hypoxemic or allergic complications attributable to the scleral lens occurred. Gas-permeable scleral lens use appears to be safe and effective in patients with severe dry eye related to chronic GVH. Copyright © 2015 Elsevier Masson SAS. All rights reserved.

  15. Heat Transfer in a Gas Mixture Between Two Parallel Plates: Finite-difference Analysis of the Boltzmann Equation

    National Research Council Canada - National Science Library

    Kosuge, Shingo

    2000-01-01

    The problem of heat transfer and temperature distribution in a binary mixture of rarefied gases between two parallel plates with different temperatures is investigated on the basis of kinetic theory...

  16. Dimethylamine as a Replacement for Ammonia Dosing in the Secondary Circuit of an Advanced Gas-Cooled Reactor (AGR) Power Station

    International Nuclear Information System (INIS)

    Armstrong, C.; Mitchell, M.; Bull, A.; Quirk, G.P.; Rudge, A.

    2012-09-01

    Increasing flow resistance observed over recent years within the helical once-through boilers in the four Advanced Gas-Cooled Reactors (AGRs) at Hartlepool and Heysham 1 Power stations have reduced boiler performance, resulting in reductions in feedwater flow, steam temperatures, power output and the need to carry out periodic chemical cleaning. The root cause is believed to be the development of magnetite deposits with high flow impedance in the 9%Cr evaporator section of the boiler tubing. To prevent continued increases in boiler flow resistance, dimethylamine is being trialled, in one of the four affected units, as a replacement to the conventional ammonia dosing. Dimethylamine increases the pH at temperature around the secondary circuit and, based on full scale boiler rig simulations, is expected to reduce iron transport and prevent flow resistance increases within the evaporator section of the boiler. The dimethylamine plant trial commenced in January 2011 and is ongoing. The feedwater concentration of dimethylamine has been increased progressively towards a final target value of 900 μg kg -1 and its effect on iron transport and boiler pressure loss is being closely monitored. The high steam temperatures (>500 deg. C) of the secondary circuit lead to some decomposition of dimethylamine, which is being carefully monitored at various locations around the circuit. The decomposition products identified with dimethylamine dosing include ammonia, methylamine, formic acid, carbon dioxide and, as yet, unidentified neutral organic species. The effect of dimethylamine dosing on iron transport, boiler pressure drops and its decomposition behaviour around the secondary circuit during the plant trial will be presented in this paper. (authors)

  17. Chromatographic fingerprint analysis of secondary metabolites in citrus fruits peels using gas chromatography-mass spectrometry combined with advanced chemometric methods.

    Science.gov (United States)

    Parastar, Hadi; Jalali-Heravi, Mehdi; Sereshti, Hassan; Mani-Varnosfaderani, Ahmad

    2012-08-17

    Multivariate curve resolution (MCR) and multivariate clustering methods along with other chemometric methods are proposed to improve the analysis of gas chromatography-mass spectrometry (GC-MS) fingerprints of secondary metabolites in citrus fruits peels. In this way, chromatographic problems such as baseline/background contribution, low S/N peaks, asymmetric peaks, retention time shifts, and co-elution (overlapped and embedded peaks) occurred during GC-MS analysis of chromatographic fingerprints are solved using the proposed strategy. In this study, first, informative GC-MS fingerprints of citrus secondary metabolites are generated and then, whole data sets are segmented to some chromatographic regions. Each chromatographic segment for eighteen samples is column-wise augmented with m/z values as common mode to preserve bilinear model assumption needed for MCR analysis. Extended multivariate curve resolution alternating least squares (MCR-ALS) is used to obtain pure elution and mass spectral profiles for the components present in each chromatographic segment as well as their relative concentrations. After finding the best MCR-ALS model, the relative concentrations for resolved components are examined using principal component analysis (PCA) and k-nearest neighbor (KNN) clustering methods to explore similarities and dissimilarities among different citrus samples according to their secondary metabolites. In general, four clear-cut clusters are determined and the chemical markers (chemotypes) responsible to this differentiation are characterized by subsequent discriminate analysis using counter-propagation artificial neural network (CPANN) method. It is concluded that the use of proposed strategy is a more reliable and faster way for the analysis of large data sets like chromatographic fingerprints of natural products compared to conventional methods. Copyright © 2012 Elsevier B.V. All rights reserved.

  18. Multiscale study of hydrodynamics, mixing and gas-liquid mass transfer in a stirred-tank bioreactor

    OpenAIRE

    de Lamotte, Anne

    2018-01-01

    The growth of industrial biotechnology has created a pull for advancing bioreactor design. The requirements of the culture system have led to a variety of technical issues that generally involve transfer of mass and energy. Predicting bioreactor performance has proved to be complex as it requires not only a deep knowledge of all the biological aspects, but also a proper characterization of transport and transfer phenomena within the bioreactor which are equipment design and scale dependent. I...

  19. Transferência de massa gás-líquido em coluna de aeração Mass transfer gas-liquid in column of aeration

    Directory of Open Access Journals (Sweden)

    Marcio Ricardo Salla

    2008-06-01

    Full Text Available Neste trabalho estuda-se a transferência de massa gás-líquido a partir de bolhas de ar para a água, geradas por um difusor de ar, em uma coluna de aeração, mudando a vazão de ar de 400 L/h a 2000 L/h, o nível de água de 0,50 m a 1,80 m, cujas taxas de aplicação superficial de ar variaram de 3,1 L/m².s a 15,4 L/m².s. Várias características hidrodinâmicas foram medidas, tal como a velocidade ascensional das bolhas de ar e seus diâmetros, fundamentais para verificar o coeficiente de transferência de massa que estão na literatura, usando um equipamento laser para velocimetria não-intrusiva. Após os estudos da transferência de massa, foi concluído que a vazão de ar entre 400 L/h e 800 L/h e o nível de água de 1,80 m apresentou a maior eficiência de transferência de massa, garantindo para estas medidas, dentro da coluna em estudo, maior quantidade de oxigênio dissolvido.The present work is a study of the mass transfer gas-liquid from air bubbles into water, generated by a diffuser of air, in a column of aeration, changing the air flow from 400 L/h to 2000 L/h, the level of water from 0.50 m to 1.80 m, whose taxes of superficial application of air had varied of 3.1 L/m².s to 15.4 L/m².s. Several hydrodynamics characteristics were measured, such as the velocity range of the air bubbles and their diameter, fundamental to check the mass transfer coefficient that are in literature, by using a laser equipment for non-intrusive velocimetry. After of the study of the mass transfer, it was concluded that the air flow between 400 L/h and 800 L/h and the level of water of 1.80 m was the most efficient of mass transfer, guaranteeing for these measure, into of the column in study, most quantity of dissolved oxygen.

  20. Heat and mass transfer in a gas in a capillary induced by light with nonuniform intensity distribution over the beam cross section

    International Nuclear Information System (INIS)

    Chernyak, V. G.; Polikarpov, A. P.

    2011-01-01

    An analysis is presented of the heat and drift fluxes induced by velocity-selective light absorption in a single-component gas in a capillary tube. The light intensity distribution across the beam is assumed to have a Gaussian profile. Kinetic equations are solved numerically to calculate flux profiles and kinetic coefficients quantifying the contributions of surface and collisional mechanisms to light-induced transfer as functions of the Knudsen number, the ratio of the rate of radiative decay of the exited level and intermolecular collision frequency, accommodation coefficient, and the ratio of the tube radius to the light beam radius.

  1. Modeling of permeate flux and mass transfer resistances in the reclamation of molasses wastewater by a novel gas-sparged nanofiltration

    International Nuclear Information System (INIS)

    Patel, Tejal Manish; Nath, Kaushik

    2014-01-01

    A semi-empirical model has been applied to predict the permeate flux and mass transfer resistances during the cross flow nanofiltration of molasses wastewater in flat-sheet module. The model includes laminar flow regime as well as flow in presence of gas sparging at two different gas velocities. Membrane hydraulic resistance (R m ), osmotic pressure resistance (R osm ) and the concentration polarization resistance (R cp ) were considered in series. The concentration polarization resistance was correlated to the operating conditions, namely, the feed concentration, the trans-membrane pressure difference and the cross flow velocity for a selected range of experiments. There was an appreciable reduction of concentration polarization resistance R cp spar in presence of gas sparging. Both the concentration polarization resistance R cp lam and osmotic pressure resistance R osm decreased with cross-flow velocity, but increased with feed concentration and the operating pressure. Experimental and theoretical permeate flux values as a function of cross flow velocity for both the cases, in the presence and absence of gas sparging, were also compared

  2. Status of the development of hot gas ducts for HTRs

    International Nuclear Information System (INIS)

    Stehle, H.; Klas, E.

    1984-01-01

    In the PNP nuclear process heat system the heat generated in the helium cooled core is transferred to the steam reformer and to the successive steam generator or to the intermediate heat exchanger by the primary helium via suitable hot gas ducts. The heat is carried over to the steam gasifier by the intermediate heat exchanger and a secondary helium loop. In both the primary and the secondary loop, the hot gas ducts are internally insulated by a ceramic fibre insulation to protect the support tube and the pressure housing from the high helium temperatures. A graphite hot gas liner will be used for the coaxial primary duct with an annular gap between support tube and pressure shell for the cold gas counterflow. A metallic hot gas liner will be installed in the secondary duct

  3. Transference and natural gas distribution system analysis utilizing hybrid modelling; Analise de sistemas de transferencia e distribuicao de gas natural utilizando modelagem hibrida

    Energy Technology Data Exchange (ETDEWEB)

    Calvo, Robson A.; Martinkoski, Ricardo [Centro Federal de Educacao Tecnologica do Parana (CEFET), Curitiba, PR (Brazil); Neves Junior, Flavio [Centro Federal de Educacao Tecnologica do Parana (CEFET), Curitiba, PR (Brazil). Programa de Pos-Graduacao em Engenharia Eletrica e Informatica Industrial

    2003-07-01

    The objective of this article is to apply techniques of formal specification in modelling of natural gas transmission and distribution systems. In this case the formal models are characterized by using hybrid automata. Initially the existent components in the net are modeled and represented by independent hybrid automata. The global dynamics is obtained through the product hybrid automata. Languages representing the desirable states of the system are obtained from the hybrid automata, allowing a hybrid control procedure. An automatic tool as SHIFT must be used to modelling and simulation. (author)

  4. Obtaining the cumulative k-distribution of a gas mixture from those of its components. [radiative transfer in stratosphere

    Science.gov (United States)

    Gerstell, M. F.

    1993-01-01

    A review of the convolution theorem for obtaining the cumulative k-distribution of a gas mixture proven in Goody et al. (1989) and a discussion of its application to natural spectra are presented. Computational optimizations for use in analyzing high-altitude gas mixtures are introduced. Comparisons of the results of the optimizations, and criteria for deciding what altitudes are 'high' in this context are given. A few relevant features of the testing support software are examined. Some spectrally integrated results, and the circumstances the might permit substituting the method of principal absorbers are examined.

  5. Gasification of coal-derived chars in synthesis gas mixtures under intraparticle mass-transfer-controlled conditions

    NARCIS (Netherlands)

    Bliek, A.; Lont, J.C.; van Swaaij, Willibrordus Petrus Maria

    1986-01-01

    A model has been formulated to describe the quasi-steady-state gasification of coal-derived chars in gas mixtures where both the reactants carbon dioxide and steam, and the gasification products carbon monoxide and hydrogen are present. As such, these conditions reflect the situation found in most

  6. CFD Study of Full-Scale Aerobic Bioreactors: Evaluation of Dynamic O2 Distribution, Gas-Liquid Mass Transfer and Reaction

    Energy Technology Data Exchange (ETDEWEB)

    Humbird, David; Sitaraman, Hariswaran; Stickel, Jonathan; Sprague, Michael A.; McMillan, Jim

    2016-11-18

    If advanced biofuels are to measurably displace fossil fuels in the near term, they will have to operate at levels of scale, efficiency, and margin unprecedented in the current biotech industry. For aerobically-grown products in particular, scale-up is complex and the practical size, cost, and operability of extremely large reactors is not well understood. Put simply, the problem of how to attain fuel-class production scales comes down to cost-effective delivery of oxygen at high mass transfer rates and low capital and operating costs. To that end, very large reactor vessels (>500 m3) are proposed in order to achieve favorable economies of scale. Additionally, techno-economic evaluation indicates that bubble-column reactors are more cost-effective than stirred-tank reactors in many low-viscosity cultures. In order to advance the design of extremely large aerobic bioreactors, we have performed computational fluid dynamics (CFD) simulations of bubble-column reactors. A multiphase Euler-Euler model is used to explicitly account for the spatial distribution of air (i.e., gas bubbles) in the reactor. Expanding on the existing bioreactor CFD literature (typically focused on the hydrodynamics of bubbly flows), our simulations include interphase mass transfer of oxygen and a simple phenomenological reaction representing the uptake and consumption of dissolved oxygen by submerged cells. The simulations reproduce the expected flow profiles, with net upward flow in the center of column and downward flow near the wall. At high simulated oxygen uptake rates (OUR), oxygen-depleted regions can be observed in the reactor. By increasing the gas flow to enhance mixing and eliminate depleted areas, a maximum oxygen transfer (OTR) rate is obtained as a function of superficial velocity. These insights regarding minimum superficial velocity and maximum reactor size are incorporated into NREL's larger techno-economic models to supplement standard reactor design equations.

  7. Study of the influence of surfactants on the activity coefficients and mass transfer coefficients of methanol in aqueous mixtures by reversed-flow gas chromatography.

    Science.gov (United States)

    Kotsalos, Efthimios; Brezovska, Boryana; Sevastos, Dimitrios; Vagena, Artemis; Koliadima, Athanasia; Kapolos, John; Karaiskakis, George

    2017-11-17

    This work focuses on the influences of surfactants on the activity coefficients, γ, of methanol in binary mixtures with water, as well as on the mass transfer coefficients, k c , for the evaporation of methanol, which is a ubiquitous component in the troposphere, from mixtures of methanol with water at various surfactant's and methanol's concentrations. The technique used is the Reversed-Flow Gas Chromatography (R.F.G.C.), a version of Inverse Gas Chromatography, which allows determining both parameters by performing only one experiment for the k c parameter and two experiments for the γ parameter. The k c and γ values decrease in the presence of the three surfactants used (CTAB, SDS, TRITON X-100) at all methanol's and surfactant's concentrations. The decrease in the methanol's molar fraction, at constant number of surfactant films leads to a decrease in the k c and γ values, while the decrease in the surfactant's concentration, at constant methanol's molar fraction leads to an increase in both the k c and γ parameters. Mass transfer coefficients for the evaporation of methanol at the surfactant films, are also calculated which are approximately between 4 and 5 orders of magnitude larger than the corresponding mass transfer coefficients at the liquid films. Finally, thicknesses of the boundary layer of methanol in the mixtures of methanol with water were determined. The quantities found are compared with those given in the literature or calculated theoretically using various empirical equations. The precision of the R.F.G.C. method for measuring γ and k c parameters is approximately high (94.3-98.0%), showing that R.F.G.C. can be used with success not only for the thermodynamic study of solutions, but also for the interphase transport. Copyright © 2017 Elsevier B.V. All rights reserved.

  8. Combustion-driven oscillation in a furnace with multispud-type gas burners. 4th Report. Effects of position of secondary air guide sleeve and openness of secondary air guide vane on combustion oscillation condition; Multispud gata gas turner ni okeru nensho shindo. 4. Nijigen kuki sleeve ichi oyobi nijigen kuki vane kaido no shindo reiki ni oyobosu eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Akiyama, I.; Okiura, K.; Baba, A.; Orimoto, M. [Babcock-Hitachi K.K., Tokyo (Japan)

    1994-07-25

    Effects of the position of a secondary air guide sleeve and the openness of a secondary air guide vane on combustion oscillation conditions were studied experimentally for multispud-type gas burners. Pressure fluctuation in furnaces was analyzed with the previously reported resonance factor which was proposed as an index to represent the degree of combustion oscillation. As a result, the combustion oscillation region was largely affected by both position of a guide sleeve and openness of a guide vane. As the openness having large effect on the ratio of primary and secondary air/tertiary air and the position hardly having effect on the ratio were adjusted skillfully, the burner with no combustion oscillation region was achieved in its normal operation range. In addition, as the effect of preheating combustion air was arranged with a standard flow rate or mass flow flux of air, it was suggested the combustion oscillation region due to preheating can be described with the same manner as that due to no preheating. 5 refs., 8 figs.

  9. Investigation of heat transfer and flow using ribs within gas turbine blade cooling passage: Experimental and hybrid LES/RANS modeling

    Science.gov (United States)

    Kumar, Sourabh

    Gas turbines are extensively used for aircraft propulsion, land based power generation and various industrial applications. Developments in innovative gas turbine cooling technology enhance the efficiency and power output, with an increase in turbine rotor inlet temperatures. These advancements of turbine cooling have allowed engine design to exceed normal material temperature limits. For internal cooling design, techniques for heat extraction from the surfaces exposed to hot stream are based on the increase of heat transfer areas and on promotion of turbulence of the cooling flow. In this study, it is obtained by casting repeated continuous V and broken V shaped ribs on one side of the two pass square channel into the core of blade. Despite extensive research on ribs, only few papers have validated the numerical data with experimental results in two pass channel. In the present study, detailed experimental investigation is carried out for two pass square channels with 180° turn. Detailed heat transfer distribution occurring in the ribbed passage is reported for steady state experiment. Four different combinations of 60° and Broken 60° V ribs in channel are considered. Thermocouples are used to obtain the temperature on the channel surface and local heat transfer coefficients are obtained for various Reynolds numbers, within the turbulent flow regime. Area averaged data are calculated in order to compare the overall performance of the tested ribbed surface and to evaluate the degree of heat transfer enhancement induced by the ribs with. Flow within the channels is characterized by heat transfer enhancing ribs, bends, rotation and buoyancy effects. Computational Fluid Dynamics (CFD) simulations were carried out for the same geometries using different turbulence models such as k-o Shear stress transport (SST) and Reynolds stress model (RSM). These CFD simulations were based on advanced computing in order to improve the accuracy of three dimensional metal

  10. A systematic comparison of two empirical gas-liquid mass transfer determination methodologies to characterize methane biodegradation in stirred tank bioreactors.

    Science.gov (United States)

    Muñoz, Raul; Soto, Cenit; Zuñiga, Cristal; Revah, Sergio

    2018-03-29

    This study aimed at systematically comparing the potential of two empirical methods for the estimation of the volumetric CH 4 mass transfer coefficient (k l a CH4 ), namely gassing-out and oxygen transfer rate (OTR), to describe CH 4 biodegradation in a fermenter operated with a methanotrophic consortium at 400, 600 and 800 rpm. The k l a CH4 estimated from the OTR methodology accurately predicted the CH 4 elimination capacity (EC) under CH 4 mass transfer limiting conditions regardless of the stirring rate (∼9% of average error between empirical and estimated ECs). Thus, empirical CH 4 -ECs of 37.8 ± 5.8, 42.5 ± 5.4 and 62.3 ± 5.2 g CH 4 m -3 h -1 vs predicted CH 4 -ECs of 35.6 ± 2.2, 50.1 ± 2.3 and 59.6 ± 3.4 g CH 4 m -3 h -1 were recorded at 400, 600 and 800 rpm, respectively. The rapid Co 2+ -catalyzed reaction of O 2 with SO 3 -2 in the vicinity of the gas-liquid interphase during OTR determinations, mimicking microbial CH 4 uptake in the biotic experiments, was central to accurately describe the k l a CH4 . Copyright © 2018 Elsevier Ltd. All rights reserved.

  11. Modeling of gas-liquid mass transfer in a stirred tank bioreactor agitated by a Rushton turbine or a new pitched blade impeller.

    Science.gov (United States)

    Gelves, Ricardo; Dietrich, A; Takors, Ralf

    2014-03-01

    A combined computational fluid dynamics (CFD) and population balance model (PBM) approach has been applied to simulate hydrodynamics and mass transfer in a 0.18 m(3) gas-liquid stirred bioreactor agitated by (1) a Rushton turbine, and (2) a new pitched blade geometry with rotating cartridges. The operating conditions chosen were motivated by typical settings used for culturing mammalian cells. The effects of turbulence, rotating flow, bubbles breakage and coalescence were simulated using the k-ε, multiple reference frame (MRF), Sliding mesh (SM) and PBM approaches, respectively. Considering the new pitched blade geometry with rotating aeration microspargers, [Formula: see text] mass transfer was estimated to be 34 times higher than the conventional Rushton turbine set-up. Notably, the impeller power consumption was modeled to be about 50 % lower. Independent [Formula: see text] measurements applying the same operational conditions confirmed this finding. Motivated by these simulated and experimental results, the new aeration and stirring device is qualified as a very promising tool especially useful for cell culture applications which are characterized by the challenging problem of achieving relatively high mass transfer conditions while inserting only low stirrer energy.

  12. Flow and heat and mass transfer in laminar and turbulent mist gas-droplets stream over a flat plate

    CERN Document Server

    Terekhov, Victor I

    2014-01-01

    In this book the author presents selected challenges of thermal-hydraulics modeling of two-phase flows in minichannels with change of phase. These encompass the common modeling of flow boiling and flow condensation using the same expression. Approaches to model these two respective cases show, however, that experimental data show different results to those obtained by methods of calculation of heat transfer coefficient for respective cases. Partially that can be devoted to the fact that there are non-adiabatic effects present in both types of phase change phenomena which modify the pressure drop due to friction, responsible for appropriate modelling. The modification of interface shear stresses between flow boiling and flow condensation in case of annular flow structure may be considered through incorporation of the so called blowing parameter, which differentiates between these two modes of heat transfer. On the other hand, in case of bubbly flows, the generation of bubbles also modifies the friction pressur...

  13. DNA transfer and cell killing in epidermoid cells by diagnostic ultrasound activation of contrast agent gas bodies in vitro.

    Science.gov (United States)

    Miller, Douglas L; Dou, Chunyan; Song, Jianming

    2003-04-01

    DNA transfer by sonoporation and cell killing in monolayer cells were examined by contrast-aided low-power diagnostic ultrasound (US). Culture chambers with epidermoid cell monolayers were scanned at about 1 mm/s with a 1.5-MHz scan head aimed upward at the chamber in a 37 degrees C water bath. For DNA transfer tests, plasmids coding for green fluorescent protein (GFP) were added to the medium, and GFP expression was assessed by flow cytometry after 2 days. In separate tests, cell killing was determined immediately after treatment. GFP-positive cell counts were 0.4% (0.7% SD) for shams and 3.7% (1.2% SD) of cells for exposure at 2.3 MPa with 2% Optison contrast agent. The fraction of dead cells was 3.4% (1.7% SD) in shams and 28.6% (6.3% SD) in exposed chambers. Both effects increased for increasing Optison concentration and increasing peak rarefactional pressure amplitude. Contrast-aided diagnostic US has a potential therapeutic application for gene transfer, but a trade-off appears to exist with cell killing.

  14. Heat Transfer and Flow on the First Stage Blade Tip of a Power Generation Gas Turbine. Part 1; Experimental Results

    Science.gov (United States)

    Bunker, Ronald S.; Bailey, Jeremy C.; Ameri, Ali A.

    1999-01-01

    A combined computational and experimental study has been performed to investigate the detailed distribution of convective heat transfer coefficients on the first stage blade tip surface for a geometry typical of large power generation turbines(>100MW). This paper is concerned with the design and execution of the experimental portion of the study. A stationary blade cascade experiment has been run consisting of three airfoils, the center airfoil having a variable tip gap clearance. The airfoil models the aerodynamic tip section of a high pressure turbine blade with inlet Mach number of 0.30, exit Mach number of 0.75, pressure ratio of 1.45, exit Reynolds number based on axial chord of 2.57 x 10(exp 6), and total turning of about 110 degrees. A hue detection based liquid crystal method is used to obtain the detailed heat transfer coefficient distribution on the blade tip surface for flat, smooth tip surfaces with both sharp and rounded edges. The cascade inlet turbulence intensity level took on values of either 5% or 9%. The cascade also models the casing recess in the shroud surface ahead of the blade. Experimental results are shown for the pressure distribution measurements on the airfoil near the tip gap, on the blade tip surface, and on the opposite shroud surface. Tip surface heat transfer coefficient distributions are shown for sharp-edge and rounded-edge tip geometries at each of the inlet turbulence intensity levels.

  15. Research and development of asymmetrical heat transfer augmentation method in radial channels of blades for high temperature gas turbines

    Science.gov (United States)

    Shevchenko, I. V.; Rogalev, A. N.; Garanin, I. V.; Vegera, A. N.; Kindra, V. O.

    2017-11-01

    The serpentine-like one and half-pass cooling channel systems are primarily used in blades fabricated by the lost-wax casting process. The heat transfer turbulators like cross-sectional or angled ribs used in channels of the midchord region failed to eliminate the temperature irregularity from the suction and pressure sides, which is reaching 200°C for a first stage blade of the high-pressure turbine for an aircraft engine. This paper presents the results of a numerical and experimental test of an advanced heat transfer augmentation system in radial channels developed for alignment of the temperature field from the suction and pressure sides. A numerical simulation of three-dimensional coolant flow for a wide range of Reynolds numbers was carried out using ANSYS CFX software. Effect of geometrical parameters on the heat removal asymmetry was determined. The test results of a blade with the proposed intensification system conducted in a liquid-metal thermostat confirmed the accuracy of calculations. Based on the experimental data, the dependencies for calculation of heat transfer coefficients to the cooling air in the blade studied were obtained.

  16. Three-dimensional simulation of beam propagation and heat transfer in static gas Cs DPALs using wave optics and fluid dynamics models

    Science.gov (United States)

    Waichman, Karol; Barmashenko, Boris D.; Rosenwaks, Salman

    2017-10-01

    Analysis of beam propagation, kinetic and fluid dynamic processes in Cs diode pumped alkali lasers (DPALs), using wave optics model and gasdynamic code, is reported. The analysis is based on a three-dimensional, time-dependent computational fluid dynamics (3D CFD) model. The Navier-Stokes equations for momentum, heat and mass transfer are solved by a commercial Ansys FLUENT solver based on the finite volume discretization technique. The CFD code which solves the gas conservation equations includes effects of natural convection and temperature diffusion of the species in the DPAL mixture. The DPAL kinetic processes in the Cs/He/C2H6 gas mixture dealt with in this paper involve the three lowest energy levels of Cs, (1) 62S1/2, (2) 62P1/2 and (3) 62P3/2. The kinetic processes include absorption due to the 1->3 D2 transition followed by relaxation the 3 to 2 fine structure levels and stimulated emission due to the 2->1 D1 transition. Collisional quenching of levels 2 and 3 and spontaneous emission from these levels are also considered. The gas flow conservation equations are coupled to fast-Fourier-transform algorithm for transverse mode propagation to obtain a solution of the scalar paraxial propagation equation for the laser beam. The wave propagation equation is solved by the split-step beam propagation method where the gain and refractive index in the DPAL medium affect the wave amplitude and phase. Using the CFD and beam propagation models, the gas flow pattern and spatial distributions of the pump and laser intensities in the resonator were calculated for end-pumped Cs DPAL. The laser power, DPAL medium temperature and the laser beam quality were calculated as a function of pump power. The results of the theoretical model for laser power were compared to experimental results of Cs DPAL.

  17. From Elitism to Inclusive Education: Development of Outcomes-Based Learning and Post-Secondary Credit Accumulation and Transfer Systems in England and Wales.

    Science.gov (United States)

    Faris, Ron

    This report provides observations and lessons learned by a study-visit team from the Centre for Curriculum, Transfer and Technology (Canada) and the British Columbian Council on Admissions and Transfer. The study-visit was a reconnaissance of the reform of the post-school education and training system in the United Kingdom (UK), chiefly in England…

  18. A gas dynamics scheme for a two moments model of radiative transfer; Un schema de type dynamique des gaz pour un modele a deux moments en transfert radiatif

    Energy Technology Data Exchange (ETDEWEB)

    Buet, Ch.; Despres, B

    2007-07-01

    We address the discretization of the Levermore's two moments and entropy model of the radiative transfer equation. We present a new approach for the discretization of this model: first we rewrite the moment equations as a Compressible Gas Dynamics equation by introducing an additional quantity that plays the role of a density. After that we discretize using a Lagrange-projection scheme. The Lagrange-projection scheme permits us to incorporate the source terms in the fluxes of an acoustic solver in the Lagrange step, using the well-known piecewise steady approximation and thus to capture correctly the diffusion regime. Moreover we show that the discretization is entropic and preserve the flux-limited property of the moment model. Numerical examples illustrate the feasibility of our approach. (authors)

  19. Loss of ammonia during electron-transfer dissociation of deuterated peptides as an inherent gauge of gas-phase hydrogen scrambling

    DEFF Research Database (Denmark)

    Rand, Kasper D; Zehl, Martin; Jensen, Ole Nørregaard

    2010-01-01

    we utilize the abundant loss of ammonia upon ETD of peptide ions as a universal reporter of positional randomization of the exchangeable hydrogens (hydrogen scrambling) during HX-ETD experiments. We show that the loss of ammonia from peptide ions proceeds without depletion of deuterium when employing......The application of electron-transfer dissociation (ETD) to obtain single-residue resolution in hydrogen exchange-mass spectrometry (HX-MS) experiments has recently been demonstrated. For such measurements, it is critical to ensure that the level of gas-phase hydrogen scrambling is negligible. Here...... detected by a depletion of deuterium when deuterated ammonia is lost from peptides during ETD. This straightforward method requires no modifications to the experimental workflow and has the great advantage that the occurrence of hydrogen scrambling can be directly detected in the actual peptides analyzed...

  20. The modeling of coating thickness, heat transfer, and fluid flow and its correlation with the thermal barrier coating microstructure for a plasma sprayed gas turbine application

    Science.gov (United States)

    Nylén, P.; Wigren, J.; Pejryd, L.; Hansson, M.-O.

    1999-09-01

    The plasma sprya deposition of a zirconia thermal barrier coating (TBC) on a gas turbine component was examined using analytical and experimental techniques. The coating thickness was simulated by the use of commercial off-line software. The impinging jet was modeled by means of a finite difference elliptic code using a simplified turbulence model. Powder particle velocity, temperature history, and trajectory were calculated using a stochastic discrete particle model. The heat transfer and fluid flow model were then used to calculate transient coating and substrate temperatures using the finite element method. The predicted thickness, temperature, and velocity of the particles and the coating temperatures were compared with these measurements, and good correlations were obtained. The coating microstructure was evaluated by optical and scanning microscopy techniques. Special attention was paid to the crack structures within the top coating. Finally, the correlation between the modeled parameters and the deposit microstructure was studied.

  1. Particle Size Dependence of Biogenic Secondary Organic Aerosol Molecular Composition

    OpenAIRE

    Tu, Peijun; Johnston, Murray V.

    2017-01-01

    Formation of secondary organic aerosol (SOA) is initiated by the oxidation of volatile organic compounds (VOCs) in the gas phase. Mass transfer to the particle phase is thought to occur primarily by a combination of condensation of non-volatile products and partitioning of semi-volatile products, though particle phase chemistry may also play a role if it transforms semi-volatile reactants into non-volatile products. In principle, changes in particle composition as a function of particle size...

  2. Hematopoiesis stimulation test by interleukin 1α gene transfer in the Cynomolgus macaque: application to secondary medullary aplasia from an accidental irradiation

    International Nuclear Information System (INIS)

    De Revel, Th.

    2002-12-01

    After a description of the context of medullary aplasia (haematological radiobiology, radiation acute syndrome, therapeutic care), and an overview of knowledge about the interleukin-1 and medullary stroma cells, this research thesis aims at investigating therapeutic alternatives for radio-accidental aplasia. More precisely, it aims at defining means to get cytokines which are efficient for haematopoiesis. Interleukin-1 is chosen for its properties and tests are performed on a macaque with two approaches for gene transfer: an ex vivo transfer by retroviral vector enabling an integration in the target cell genome, and an in situ transfer by adeno-viral vector directly applied in the animal osseous medulla

  3. CORTAP: a coupled neutron kinetics-heat transfer digital computer program for the dynamic simulation of the high temperature gas cooled reactor core

    International Nuclear Information System (INIS)

    Cleveland, J.C.

    1977-01-01

    CORTAP (Core Transient Analysis Program) was developed to predict the dynamic behavior of the High Temperature Gas Cooled Reactor (HTGR) core under normal operational transients and postulated accident conditions. CORTAP is used both as a stand-alone component simulation and as part of the HTGR nuclear steam supply (NSS) system simulation code ORTAP. The core thermal neutronic response is determined by solving the heat transfer equations for the fuel, moderator and coolant in an average powered region of the reactor core. The space independent neutron kinetics equations are coupled to the heat transfer equations through a rapidly converging iterative technique. The code has the capability to determine conservative fuel, moderator, and coolant temperatures in the ''hot'' fuel region. For transients involving a reactor trip, the core heat generation rate is determined from an expression for decay heat following a scram. Nonlinear effects introduced by temperature dependent fuel, moderator, and coolant properties are included in the model. CORTAP predictions will be compared with dynamic test results obtained from the Fort St. Vrain reactor owned by Public Service of Colorado, and, based on these comparisons, appropriate improvements will be made in CORTAP

  4. Numerical Investigation on the Flow and Heat Transfer Characteristics of Supercritical Liquefied Natural Gas in an Airfoil Fin Printed Circuit Heat Exchanger

    Directory of Open Access Journals (Sweden)

    Zhongchao Zhao

    2017-11-01

    Full Text Available As a new kind of highly compact and efficient micro-channel heat exchanger, the printed circuit heat exchanger (PCHE is a promising candidate satisfying the heat exchange requirements of liquefied natural gas (LNG vaporization at low and high pressure. The effects of airfoil fin arrangement on heat transfer and flow resistance were numerically investigated using supercritical liquefied natural gas (LNG as working fluid. The thermal properties of supercritical LNG were tested by utilizing the REFPROF software database. Numerical simulations were performed using FLUENT. The inlet temperature of supercritical LNG was 121 K, and its pressure was 10.5 MPa. The reference mass flow rate of LNG was set as 1.22 g/s for the vertical pitch Lv = 1.67 mm and the staggered pitch Ls = 0 mm, with the Reynolds number of about 3750. The SST k-ω model was selected and verified by comparing with the experimental data using supercritical liquid nitrogen as cold fluid. The airfoil fin PCHE had better thermal-hydraulic performance than that of the straight channel PCHE. Moreover, the airfoil fins with staggered arrangement displayed better thermal performance than that of the fins with parallel arrangement. The thermal-hydraulic performance of airfoil fin PCHE was improved with increasing Ls and Lv. Moreover, Lv affected the Nusselt number and pressure drop of airfoil fin PCHE more obviously. In conclusion, a sparser staggered arrangement of fins showed a better thermal-hydraulic performance in airfoil fin PCHE.

  5. Analysis of conjugated heat transfer, in transient state of the first stage of a gas turbine; Analisis de transferencia de calor conjugada, en estado transitorio, de la primera etapa de una turbina de gas

    Energy Technology Data Exchange (ETDEWEB)

    Campos Amezcua, Alfonso; Mazur C, Zdzislaw [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico); Gallegos Munoz, Armando [Facultad de Ingenieria Mecanica, Electrica y Electronica (FIMEE), Universidad de Guanajuato, Guanajuato (Mexico)

    2007-11-15

    This article presents an analysis of conjugated heat transfer in the first stage of movable blades during the starting of a gas turbine, covering a period of 1,012 seconds. The developed computer model is in 3D and uses as initial and border conditions typical starting curves for stack gases, the cooling air and the angular velocity of the blades. As a result of the numerical predictions, the temperature distributions in stack gases, the trowel of the blade and the cooling air are included, doing emphasis in the results obtained in the solid (body of the blade), since these are used for thermo-mechanical stress analysis and later estimation of the blade residual life. [Spanish] Este articulo presenta un analisis de transferencia de calor conjugada en la primera etapa de alabes moviles, durante el arranque de una turbina de gas, cubriendo un periodo de 1.012 segundos. El modelo computacional desarrollado es en tres dimensiones y utiliza como condiciones iniciales y de frontera curvas de arranque tipicas para los gases de combustion, el aire de enfriamiento y la velocidad angular de los alabes. Como resultado de las predicciones numericas, se incluyen las distribuciones de temperatura en los gases de combustion, la paleta del alabe y el aire de enfriamiento, haciendo enfasis en los resultados obtenidos en el solido (cuerpo del alabe), ya que estos se utilizan para analisis de esfuerzos termomecanicos y posterior estimacion de vida residual del alabe.

  6. Weighted Domain Transfer Extreme Learning Machine and Its Online Version for Gas Sensor Drift Compensation in E-Nose Systems

    Directory of Open Access Journals (Sweden)

    Zhiyuan Ma

    2018-01-01

    Full Text Available Machine learning approaches have been widely used to tackle the problem of sensor array drift in E-Nose systems. However, labeled data are rare in practice, which makes supervised learning methods hard to be applied. Meanwhile, current solutions require updating the analytical model in an offline manner, which hampers their uses for online scenarios. In this paper, we extended Target Domain Adaptation Extreme Learning Machine (DAELM_T to achieve high accuracy with less labeled samples by proposing a Weighted Domain Transfer Extreme Learning Machine, which uses clustering information as prior knowledge to help select proper labeled samples and calculate sensitive matrix for weighted learning. Furthermore, we converted DAELM_T and the proposed method into their online learning versions under which scenario the labeled data are selected beforehand. Experimental results show that, for batch learning version, the proposed method uses around 20% less labeled samples while achieving approximately equivalent or better accuracy. As for the online versions, the methods maintain almost the same accuracies as their offline counterparts do, but the time cost remains around a constant value while that of offline versions grows with the number of samples.

  7. Development of a membrane-assisted fluidized bed reactor - 1 - Gas phase back-mixing and bubble-to-emulsion phase mass transfer using tracer injection and ultrasound experiments

    NARCIS (Netherlands)

    Deshmukh, S.A.R.K.; Laverman, J.A.; Cents, A.H.G.; van Sint Annaland, M.; Kuipers, J.A.M.

    2005-01-01

    A small laboratory-scale membrane-assisted fluidized bed reactor (MAFBR) was constructed in order to experimentally demonstrate the benefits of this reactor concept, especially the enhanced bubble-to-emulsion phase mass transfer and the reduced overall axial gas phase back-mixing, due to the

  8. Immersion, Relevance and Transferability: The Motivational Preferences of Lower Secondary Students towards a Newly Created Praxis-Based Class Music Program

    Science.gov (United States)

    Lowe, Geoffrey; Coy, Neil

    2016-01-01

    The purpose of this study was to gather information on measures of motivation among year 7, 8 and 9 students enrolled in class music in a major Australian secondary school. The rationale for the study was to gain insights into why retention in the class music program had dramatically increased since the introduction of a new teaching program. A…

  9. Synthesis of enantiomerically pure C2-symmetric 4-pyrrolidinopyridine derivative as a chiral acyl transfer catalyst for the kinetic resolution of secondary alcohols

    Science.gov (United States)

    Naraku; Shimomoto; Hanamoto; Inanaga

    2000-01-01

    The first chiral C2-symmetric 4-pyrrolidinopyridine (PPY) derivative was synthesized in an enantiomerically pure form and successfully utilized as a chiral nucleophilic catalyst for the kinetic resolution of secondary alcohols leaving one enantiomer with high selectivity factors (up to s = 13.5).

  10. On the influence of waves on air-sea CO2 gas transfer in the coastal zone

    Science.gov (United States)

    Ocampo-Torres, Francisco Javier; Gutiérrez-Loza, Lucía

    2017-04-01

    As part of the "Sea Surface Roughness as Air-Sea Interaction Control" project, we study the influence of wave-associated processes controlling turbulent CO2 fluxes through the air-sea interface in a coastal region, at the Northwest of Baja California, México. The conducted field campaign allowed us with a full year dataset (May 2014-April 2015) of high quality data of CO2 fluxes (FCO2) estimated through Eddy Covariance (EC). Ocean surface waves were also recorded using an Acoustic Doppler Current Profiler (Workhorse Sentinel, Teledyne RD Instruments) located at 10 m depth about 350 m away from the shore were the EC tower was located. The study area was found to be a sink of CO2 under moderate wind and wave conditions with a mean flux of -1.32 μmol/m2s [1]. The linear correlation between the wind speed and FCO2 was found rather weak, suggesting that other physical processes besides wind may also be important for the gas exchange modulation at coastal waters at these temporal scales. Recent results on the other hand, through quantile regression analysis computed between FCO2 and a) wind speed, b) significant wave height, c) wave steepness and d) water temperature, allowed us to identify the significant wave height as the best correlated variable. However, the correlation varied with the probability distribution characteristics of FCO2, with the regression slope presenting both positive and negative values. The latter implies that in the coastal areas, the presence of swell is the key factor that promotes the intensification of the fluxes into and from the ocean. In fact, making use of the water temperature as indicator of the CO2 concentration in the water phase, the behavior of the relationship between the FCO2 and the significant wave height might be partially explained. Further analysis showed that the characteristics of wind speed and water temperature determine the direction in which the FCO2 occur. This work is a contribution from RugDiSMar project (CONACYT

  11. Flue gas condensation in oxyfuel power plants. Heat- and mass transfer measurements and experimental validation of an efficient condensation concept; Rauchgaskondensation in Oxyfuel-Kraftwerken. Waerme- und Stoffuebergangsmessungen sowie experimentelle Validierung eines effizienten Kondensationskonzepts

    Energy Technology Data Exchange (ETDEWEB)

    Raindl, Markus

    2010-12-06

    Condensation of a steam-inert gas mixture in an Oxyfuel condenser differs significantly from condensation of pure steam: condenser pressure and rest gas content increase dramatically, heat- and mass transfer coefficients are lower and oversaturation of the steam-inert gas mixture yields to fog formation. In the context of this thesis, therefore, at first the optimal ranges of working parameters for Oxyfuel processes calculated. In the following some heat flux measurements were carried out on a horizontal, crossflow pipe to validate various heat- and mass transfer theories. Building on these results a new, efficient condensation concept was developed to reduce fog formation. The final results of the measurements with a laboratory model show great performance regarding fog reduction and condensation efficiency. (orig.)

  12. Effect of gas-transfer velocity parameterization choice on air-sea CO2 fluxes in the North Atlantic Ocean and the European Arctic

    Science.gov (United States)

    Wrobel, Iwona; Piskozub, Jacek

    2016-09-01

    The oceanic sink of carbon dioxide (CO2) is an important part of the global carbon budget. Understanding uncertainties in the calculation of this net flux into the ocean is crucial for climate research. One of the sources of the uncertainty within this calculation is the parameterization chosen for the CO2 gas-transfer velocity. We used a recently developed software toolbox, called the FluxEngine (Shutler et al., 2016), to estimate the monthly air-sea CO2 fluxes for the extratropical North Atlantic Ocean, including the European Arctic, and for the global ocean using several published quadratic and cubic wind speed parameterizations of the gas-transfer velocity. The aim of the study is to constrain the uncertainty caused by the choice of parameterization in the North Atlantic Ocean. This region is a large oceanic sink of CO2, and it is also a region characterized by strong winds, especially in winter but with good in situ data coverage. We show that the uncertainty in the parameterization is smaller in the North Atlantic Ocean and the Arctic than in the global ocean. It is as little as 5 % in the North Atlantic and 4 % in the European Arctic, in comparison to 9 % for the global ocean when restricted to parameterizations with quadratic wind dependence. This uncertainty becomes 46, 44, and 65 %, respectively, when all parameterizations are considered. We suggest that this smaller uncertainty (5 and 4 %) is caused by a combination of higher than global average wind speeds in the North Atlantic (> 7 ms-1) and lack of any seasonal changes in the direction of the flux direction within most of the region. We also compare the impact of using two different in situ pCO2 data sets (Takahashi et al. (2009) and Surface Ocean CO2 Atlas (SOCAT) v1.5 and v2.0, for the flux calculation. The annual fluxes using the two data sets differ by 8 % in the North Atlantic and 19 % in the European Arctic. The seasonal fluxes in the Arctic computed from the two data sets disagree with each

  13. Reduction of magnetic emission by increasing secondary side capacitor for ferrite geometry based series-series topology for wireless power transfer to vehicles

    DEFF Research Database (Denmark)

    Batra, Tushar; Schaltz, Erik; Ahn, Seungyoung

    2014-01-01

    shielding methods are used for screening of the magnetic fields of this system. In this paper, a new active shielding design method for series-series topology of this technology has been presented. In this method, the secondary capacitor value is increased to reduce phase angle between the primary...... of analytical expressions and later substantiated with simulations. At the end, it is also shown that resonance in the system is still intact with this new design methodology....

  14. Secondary coordination sphere accelerates hole transfer for enhanced hydrogen photogeneration from [FeFe]-hydrogenase mimic and CdSe QDs in water.

    Science.gov (United States)

    Wen, Min; Li, Xu-Bing; Jian, Jing-Xin; Wang, Xu-Zhe; Wu, Hao-Lin; Chen, Bin; Tung, Chen-Ho; Wu, Li-Zhu

    2016-07-15

    Achieving highly efficient hydrogen (H2) evolution via artificial photosynthesis is a great ambition pursued by scientists in recent decades because H2 has high specific enthalpy of combustion and benign combustion product. [FeFe]-Hydrogenase ([FeFe]-H2ase) mimics have been demonstrated to be promising catalysts for H2 photoproduction. However, the efficient photocatalytic H2 generation system, consisting of PAA-g-Fe2S2, CdSe QDs and H2A, suffered from low stability, probably due to the hole accumulation induced photooxidation of CdSe QDs and the subsequent crash of [FeFe]-H2ase mimics. In this work, we take advantage of supramolecular interaction for the first time to construct the secondary coordination sphere of electron donors (HA(-)) to CdSe QDs. The generated secondary coordination sphere helps realize much faster hole removal with a ~30-fold increase, thus leading to higher stability and activity for H2 evolution. The unique photocatalytic H2 evolution system features a great increase of turnover number to 83600, which is the highest one obtained so far for photocatalytic H2 production by using [FeFe]-H2ase mimics as catalysts.

  15. Proceedings of the natural gas research and development contractors review meeting

    Energy Technology Data Exchange (ETDEWEB)

    Malone, R.D.; Shoemaker, H.D.; Byrer, C.W. (eds.)

    1990-11-01

    The purpose of this meeting was to present results of the research in the DOE-sponsored Natural Gas Program, and simultaneously to provide a forum for real-time technology transfer, to the active research community, to the interested public, and to the natural gas industry, who are the primary users of this technology. The current research focus is to expand the base of near-term and mid-term economic gas resources through research activities in Eastern Tight Gas, Western Tight Gas, Secondary Gas Recovery (increased recovery of gas from mature fields); to enhance utilization, particularly of remote gas resources through research in Natural Gas to Liquids Conversion; and to develop additional, long term, potential gas resources through research in Gas Hydrates and Deep Gas. With the increased national emphasis on the use of natural gas, this forum has been expanded to include summaries of DOE-sponsored research in energy-related programs and perspectives on the importance of gas to future world energy. Thirty-two papers and fourteen poster presentations were given in seven formal, and one informal, sessions: Three general sessions (4 papers); Western Tight Gas (6 papers); Eastern Tight Gas (8 papers); Conventional/Speculative Resources (8 papers); and Gas to Liquids (6 papers). Individual reports are processed separately on the data bases.

  16. Binary Gas Mixtures of Light Helium to Intensify Laminar Forced Convection in Round Tubes

    Science.gov (United States)

    Campo, Antonio; Chikh, Salah; Papari, Mohammad; Mobinipouya, Mahammad

    2007-11-01

    This paper addresses potential heat transfer enhancement of laminar gaseous flows inside tubes with constant wall temperatures. The goal is to investigate the capabilities of certain binary gas mixtures of light helium as the primary gas with nitrogen, oxygen, carbon dioxide, methane, sulfur hexafluoride and tetrafluoromethane as the secondary heavier gases. The velocity of the binary gas mixtures is fully established and the temperature develops from a uniform value. The thermophysical properties of the binary gas mixtures depend on the molar gas composition in the w-domain [0, 1]. The two case studies involve a low mean bulk temperature of 300 K and the other a high mean bulk temperature of 600 K, both sharing 1 atm. The two target parameters for analysis and design are the maximum heat transfer rate and the pressure drop at the optimal molar gas composition.

  17. Agreement between Autorita per l'energia elettrica e il gas and commission de regulation de l'electricite on transfer capacity allocation over the grid interconnecting Italy and France for the year 2002

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-07-01

    The present document contains the general outlines adopted by the Autorita per l'energia elettrica e il gas (hereafter AEEG) and the Commission de Regulation de l'Electricite (hereafter CRE) with respect to terms and conditions for allocating the transfer capacity over the interconnected grid between Italy, France and, with reference to a technically-coupled portion of the interconnection, Switzerland for the year 2002. Same conditions will be applied by AEEG, to a possible extent, to the transfer capacity allocation over the interconnected grid between Italy. Austria and Slovenia for the year 2002.

  18. Mass Transfer Correlations for Multiple-Impeller Gas-Liquid Contactors. Analysis of the Effect of a Axial Dispersion in Gas and Liquid Phase on “Local” kLa Values Measured by the Dynamic Pressure Method in Individual Stages of the Vessel.

    Czech Academy of Sciences Publication Activity Database

    Zedníková, Mária; Linek, V.; Moucha, T.

    2007-01-01

    Roč. 62, 6 (2007) , s. 1650-1669 ISSN 0009-2509 Institutional research plan: CEZ:AV0Z40720504 Keywords : mass transfer * multiple-impeller vessel * gas liquid axial dispersion Subject RIV: CI - Industrial Chemistry, Chemical Engineering Impact factor: 1.775, year: 2007

  19. The energy, transferred to secondary charged pions in pion-nucleon and pion-carbon interactions at momentum 40 GeV/s

    International Nuclear Information System (INIS)

    Boos, E.G.; Izbasarov, M.; Temiraliyev, T.; Samoilov, V.V.; Tursunov, R.A.

    2005-01-01

    Full text: The analysis has been undertaken for the energy ratio K π ± (partial coefficient of inelasticity) taken away by charged pions at laboratory coordinate system in pion-nucleon and pion-carbon interactions at momentum 40 GeV/s. It is shown that distribution of partial inelasticity coefficients for elementary act is more narrow than the same distribution for carbon nucleus. The mean number of charged mesons (n π ± t) grows with enlarging of partial inelasticity coefficient, being larger for interactions of π - -mesons with carbon nuclei in comparison with corresponding distribution in elementary act. The similar picture is observed for one-nucleon and multi-nucleon events selected from π - - C -interactions by the value of total electric charge of all secondary particles (except for the identified protons) and by the value of target mass

  20. Buoyancy-Driven Heat Transfer During Application of a Thermal Gradient for the Study of Vapor Deposition at Low Pressure Using and Ideal Gas

    Science.gov (United States)

    Frazier, D. O.; Hung, R. J.; Paley, M. S.; Penn, B. G.; Long, Y. T.

    1996-01-01

    A mathematical model has been developed to determine heat transfer during vapor deposition of source materials under a variety of orientations relative to gravitational accelerations. The model demonstrates that convection can occur at total pressures as low as 10-2 mm Hg. Through numerical computation, using physical material parameters of air, a series of time steps demonstrates the development of flow and temperature profiles during the course of vapor deposition. These computations show that in unit gravity vapor deposition occurs by transport through a fairly complicated circulating flow pattern when applying heat to the bottom of the vessel with parallel orientation with respect to the gravity vector. The model material parameters for air predict the effect of kinematic viscosity to be of the same order as thermal diffusivity, which is the case for Prandtl number approx. 1 fluids. Qualitative agreement between experiment and the model indicates that 6-(2-methyl-4-nitroanilino)-2,4-hexadiyn-l-ol (DAMNA) at these pressures indeed approximates an ideal gas at the experiment temperatures, and may validate the use of air physical constants. It is apparent that complicated nonuniform temperature distribution in the vapor could dramatically affect the homogeneity, orientation, and quality of deposited films. The experimental test i's a qualitative comparison of film thickness using ultraviolet-visible spectroscopy on films generated in appropriately oriented vapor deposition cells. In the case where heating of the reaction vessel occurs from the top, deposition of vapor does not normally occur by convection due to a stable stratified medium. When vapor deposition occurs in vessels heated at the bottom, but oriented relative to the gravity vector between these two extremes, horizontal thermal gradients induce a complex flow pattern. In the plane parallel to the tilt axis, the flow pattern is symmetrical and opposite in direction from that where the vessel is

  1. Energetics of primary and secondary electron transfer in Photosystem II membrane particles of spinach revisited on basis of recombination-fluorescence measurements.

    Science.gov (United States)

    Grabolle, Markus; Dau, Holger

    2005-06-30

    Photon absorption by one of the roughly 200 chlorophylls of the plant Photosystem II (PSII) results in formation of an equilibrated excited state (Chl200*) and is followed by chlorophyll oxidation (formation of P680+) coupled to reduction of a specific pheophytin (Phe), then electron transfer from Phe- to a firmly bound quinone (QA), and subsequently reduction of P680+ by a redox-active tyrosine residue denoted as Z. The involved free-energy differences (DeltaG) and redox potentials are of prime interest. Oxygen-evolving PSII membrane particles of spinach were studied at 5 degrees C. By analyzing the delayed and prompt Chl fluorescence, we determined the equilibrium constant and thus free-energy difference between Chl200* and the [Z+,QA-] radical pair to be -0.43+/-0.025 eV, at 10 mus after the photon absorption event for PSII in its S(3)-state. On basis of this value and previously published results, the free-energy difference between P680* and [P680+,QA-] is calculated to be -0.50+/-0.04 eV; the free-energy loss associated with electron transfer from Phe to QA is found to be 0.34+/-0.04 eV. The given uncertainty ranges do not represent a standard deviation or likely error, but an estimate of the maximal error. Assuming a QA-/QA redox potential of -0.08 V, the following redox-potential estimates are obtained: +1.25 V for P680/P680+; +1.21 V for Z/Z+ (at 10 mus); -0.42 V for Phe-/Phe; -0.58 V for P680*/P680+.

  2. Oxygen transfer in liquids.

    Science.gov (United States)

    Stejskal, J; Potůcek, F

    1985-04-01

    In the laboratory-type airlift tower reactor oxygen transfer from air in tap water and/or polyacrylamide solutions (Neuperm WF) was studied. In order to characterize the system, volumetric coefficient of oxygen transfer was determined by the gassing-out method. Two arrangements of the airlift tower reactor were compared, namely the reactor with and without motionless mixer. In addition, mean relative gas holdup and gas power output were determined for both arrangements.

  3. Electron transfer reactions

    CERN Document Server

    Cannon, R D

    2013-01-01

    Electron Transfer Reactions deals with the mechanisms of electron transfer reactions between metal ions in solution, as well as the electron exchange between atoms or molecules in either the gaseous or solid state. The book is divided into three parts. Part 1 covers the electron transfer between atoms and molecules in the gas state. Part 2 tackles the reaction paths of oxidation states and binuclear intermediates, as well as the mechanisms of electron transfer. Part 3 discusses the theories and models of the electron transfer process; theories and experiments involving bridged electron transfe

  4. Homogenization of some radiative heat transfer models: application to gas-cooled reactor cores; Homogeneisation de modeles de transferts thermiques et radiatifs: application au coeur des reacteurs a caloporteur gaz

    Energy Technology Data Exchange (ETDEWEB)

    El Ganaoui, K

    2006-09-15

    In the context of homogenization theory we treat some heat transfer problems involving unusual (according to the homogenization) boundary conditions. These problems are defined in a solid periodic perforated domain where two scales (macroscopic and microscopic) are to be taken into account and describe heat transfer by conduction in the solid and by radiation on the wall of each hole. Two kinds of radiation are considered: radiation in an infinite medium (non-linear problem) and radiation in cavity with grey-diffuse walls (non-linear and non-local problem). The derived homogenized models are conduction problems with an effective conductivity which depend on the considered radiation. Thus we introduce a framework (homogenization and validation) based on mathematical justification using the two-scale convergence method and numerical validation by simulations using the computer code CAST3M. This study, performed for gas cooled reactors cores, can be extended to other perforated domains involving the considered heat transfer phenomena. (author)

  5. A Web-based, computer-tailored smoking prevention program to prevent children from starting to smoke after transferring to secondary school: randomized controlled trial.

    Science.gov (United States)

    Cremers, Henricus-Paul; Mercken, Liesbeth; Candel, Math; de Vries, Hein; Oenema, Anke

    2015-03-09

    Smoking prevalence rates among Dutch children increase rapidly after they transit to secondary school, in particular among children with a low socioeconomic status (SES). Web-based, computer-tailored programs supplemented with prompt messages may be able to empower children to prevent them from starting to smoke when they transit to secondary school. The main aim of this study is to evaluate whether computer-tailored feedback messages, with and without prompt messages, are effective in decreasing children's smoking intentions and smoking behavior after 12 and 25 months of follow-up. Data were gathered at baseline (T0), and after 12 months (T1) and 25 months (T2) of follow-up of a smoking prevention intervention program called Fun without Smokes. A total of 162 schools were randomly allocated to a no-intervention control group, an intervention prompt group, or an intervention no-prompt group. A total of 3213 children aged 10 to 12 years old participated in the study and completed a Web-based questionnaire assessing their smoking intention, smoking behavior, and sociocognitive factors, such as attitude, social influence, and self-efficacy, related to smoking. After completion, children in the intervention groups received computer-tailored feedback messages in their own email inbox and those messages could be accessed on the intervention website. Children in the prompt group received prompt messages, via email and short message service (SMS) text messaging, to stimulate them to reuse the intervention website with nonsmoking content. Multilevel logistic regression analyses were performed using multiple imputations to assess the program effects on smoking intention and smoking behavior at T1 and T2. A total of 3213 children participated in the Fun without Smokes study at T0. Between T0 and T1 a total of 1067 children out of the original 3213 (33.21%) dropped out of the study. Between T0 and T2 the number of children that did not participate in the final measurement was

  6. Heat transfer measurements for Stirling machine cylinders

    Science.gov (United States)

    Kornhauser, Alan A.; Kafka, B. C.; Finkbeiner, D. L.; Cantelmi, F. C.

    1994-01-01

    The primary purpose of this study was to measure the effects of inflow-produced heat turbulence on heat transfer in Stirling machine cylinders. A secondary purpose was to provide new experimental information on heat transfer in gas springs without inflow. The apparatus for the experiment consisted of a varying-volume piston-cylinder space connected to a fixed volume space by an orifice. The orifice size could be varied to adjust the level of inflow-produced turbulence, or the orifice plate could be removed completely so as to merge the two spaces into a single gas spring space. Speed, cycle mean pressure, overall volume ratio, and varying volume space clearance ratio could also be adjusted. Volume, pressure in both spaces, and local heat flux at two locations were measured. The pressure and volume measurements were used to calculate area averaged heat flux, heat transfer hysteresis loss, and other heat transfer-related effects. Experiments in the one space arrangement extended the range of previous gas spring tests to lower volume ratio and higher nondimensional speed. The tests corroborated previous results and showed that analytic models for heat transfer and loss based on volume ratio approaching 1 were valid for volume ratios ranging from 1 to 2, a range covering most gas springs in Stirling machines. Data from experiments in the two space arrangement were first analyzed based on lumping the two spaces together and examining total loss and averaged heat transfer as a function of overall nondimensional parameter. Heat transfer and loss were found to be significantly increased by inflow-produced turbulence. These increases could be modeled by appropriate adjustment of empirical coefficients in an existing semi-analytic model. An attempt was made to use an inverse, parameter optimization procedure to find the heat transfer in each of the two spaces. This procedure was successful in retrieving this information from simulated pressure-volume data with artificially

  7. Hydrodynamique, transfert de chaleur et combustion de gaz naturel en lit fluidisé circulant Hydrodynamics, Heat Transfer and Combustion of Natural Gas in a Circulating Fluidized Bed

    Directory of Open Access Journals (Sweden)

    Feugier A.

    2006-11-01

    Full Text Available L'hydrodynamique, les transferts de chaleur et la combustion du gaz naturel ont été étudiés dans un réacteur à lit circulant de 15 cm de diamètre et de 7 m de haut. Ce réacteur peut opérer avec des vitesses de gaz allant jusqu'à 15 m/s, jusqu'à des températures de 880-900°C et avec des débits de solides compris entre 0 et 15t/h. Les charges utilisées sont des sables de granulométrie allant de 95 à 625 microns. Le profil de concentration en solides dans le réacteur est déterminé à partir du profil de pression. Une corrélation reliant la vitesse de glissement des particules aux principaux paramètres opératoires, rend compte de façon très satisfaisante de l'ensemble des résultats expérimentaux. La mise en place d'un échangeur en paroi dans la partie supérieure du réacteur a permis la détermination de coefficients d'échange thermique. Ces derniers sont essentiellement fonction de la, concentration en particules au droit de l'échangeur et de la granulométrie des particules. Des valeurs allant jusqu'à 200 W/m2 K peuvent, être obtenues. Enfin, la combustion du méthane s'avère très sensible à la présence de particules dans le réacteur. Ces particules ont un effet inhibiteur. Hydrodynamics, heat transfer and combustion of natural gas have been investigated in a circulating-bed reactor 15 cm in diameter and 7 m high. This reactor can operate with gas velocities up to 15 m/s, at temperature up to 880-900°C and with solids flow rates of between 0 and 15 t/h. The solids used are sands with a particle size ranging from 95 to 625 microns. The solids concentration profile in the reactor is determined from the pressure profile. A correlation linking the slippage velocity of particles to the principal operating parameters very satisfactorily takes into consideration the overall experimental results. The installation of a wall heat exchanger in the upper part of the reactor enabled the heat exchange coefficients to be

  8. Generalized radiative transfer theory for scattering by particles in an absorbing gas: Addressing both spatial and spectral integration in multi-angle remote sensing of optically thin aerosol layers

    Science.gov (United States)

    Davis, Anthony B.; Xu, Feng; Diner, David J.

    2018-01-01

    We demonstrate the computational advantage gained by introducing non-exponential transmission laws into radiative transfer theory for two specific situations. One is the problem of spatial integration over a large domain where the scattering particles cluster randomly in a medium uniformly filled with an absorbing gas, and only a probabilistic description of the variability is available. The increasingly important application here is passive atmospheric profiling using oxygen absorption in the visible/near-IR spectrum. The other scenario is spectral integration over a region where the absorption cross-section of a spatially uniform gas varies rapidly and widely and, moreover, there are scattering particles embedded in the gas that are distributed uniformly, or not. This comes up in many applications, O2 A-band profiling being just one instance. We bring a common framework to solve these problems both efficiently and accurately that is grounded in the recently developed theory of Generalized Radiative Transfer (GRT). In GRT, the classic exponential law of transmission is replaced by one with a slower power-law decay that accounts for the unresolved spectral or spatial variability. Analytical results are derived in the single-scattering limit that applies to optically thin aerosol layers. In spectral integration, a modest gain in accuracy is obtained. As for spatial integration of near-monochromatic radiance, we find that, although both continuum and in-band radiances are affected by moderate levels of sub-pixel variability, only extreme variability will affect in-band/continuum ratios.

  9. Monthly dynamics of carbon dioxide exchange across the sea surface of the Arctic Ocean in response to changes in gas transfer velocity and partial pressure of CO2 in 2010

    Directory of Open Access Journals (Sweden)

    Iwona Wrobel

    2017-10-01

    Full Text Available The Arctic Ocean (AO is an important basin for global oceanic carbon dioxide (CO2 uptake, but the mechanisms controlling air–sea gas fluxes are not fully understood, especially over short and long timescales. The oceanic sink of CO2 is an important part of the global carbon budget. Previous studies have shown that in the AO differences in the partial pressure of CO2 (ΔpCO2 and gas transfer velocity (k both contribute significantly to interannual air–sea CO2 flux variability, but that k is unimportant for multidecadal variability. This study combined Earth Observation (EO data collected in 2010 with the in situ pCO2 dataset from Takahashi et al. (2009 (T09 using a recently developed software toolbox called FluxEngine to determine the importance of k and ΔpCO2 on CO2 budgets in two regions of the AO – the Greenland Sea (GS and the Barents Sea (BS with their continental margins. Results from the study indicate that the variability in wind speed and, hence, the gas transfer velocity, generally play a major role in determining the temporal variability of CO2 uptake, while variability in monthly ΔpCO2 plays a major role spatially, with some exceptions.

  10. A-few-second synthesis of silicon nanoparticles by gas-evaporation and their self-supporting electrodes based on carbon nanotube matrix for lithium secondary battery anodes

    Science.gov (United States)

    Kowase, Takayuki; Hori, Keisuke; Hasegawa, Kei; Momma, Toshiyuki; Noda, Suguru

    2017-09-01

    Rapid gas-evaporation method is proposed and developed, which yields Si nanoparticles (SiNPs) in a few seconds at high yields of 20%-60% from inexpensive and safe bulk Si. Such rapid process is realized by heating the Si source to a temperature ≥2000 °C, much higher than the melting point of Si (1414 °C). The size of SiNPs is controlled at tens to hundreds nanometers simply by the Ar gas pressure during the evaporation process. Self-supporting films are fabricated simply by co-dispersion and filtration of the SiNPs and carbon nanotubes (CNTs) without using binders nor metal foils. The half-cell tests showed the improved performances of the SiNP-CNT composite films as anode when coated with graphitic carbon layer. Their performances are evaluated with various SiNP sizes and Si/CNT ratios systematically. The SiNP-CNT film with a Si/CNT mass ratio of 4 realizes the balanced film-based capacities of 618 mAh/gfilm, 230 mAh/cm3, and 0.644 mAh/cm2 with a moderate Si-based performance of 863 mAh/gSi at the 100th cycle.

  11. Gas phase ion chemistry

    CERN Document Server

    Bowers, Michael T

    1979-01-01

    Gas Phase Ion Chemistry, Volume 2 covers the advances in gas phase ion chemistry. The book discusses the stabilities of positive ions from equilibrium gas-phase basicity measurements; the experimental methods used to determine molecular electron affinities, specifically photoelectron spectroscopy, photodetachment spectroscopy, charge transfer, and collisional ionization; and the gas-phase acidity scale. The text also describes the basis of the technique of chemical ionization mass spectrometry; the energetics and mechanisms of unimolecular reactions of positive ions; and the photodissociation

  12. Air-sea gas transfer in a shallow, flowing and coastal environment estimated by dissolved inorganic carbon and dissolved oxygen analyses

    Digital Repository Service at National Institute of Oceanography (India)

    Abe, O.; Watanabe, A.; Sarma, V.V.S.S.; Matsu, Y.; Yamano, H.; Yoshida, N.; Saino, T.

    We estimated gas exchange rates in Kabira Reef at Ishigaki Island, southwest Japan, using a mass balance calculation with dual ‘biological’ tracers: dissolved inorganic carbon (DIC) and dissolved oxygen (DO). The nighttime results allowed us...

  13. Thermalization of secondary electrons under AMSGEMP conditions

    International Nuclear Information System (INIS)

    Bloomberg, H.W.; Pine, V.W.

    1984-01-01

    A Monte Carlo algorithm is used to determine the time behavior of source secondary electrons for ranges of the electric field to pressure ratio E/p of interest in AMSGEMP. The algorithm contains a very detailed cross section set describing electron interactions with the background gas. The authors show that the delay in the attainment of the peak time independent ionization frequency (or ionization coefficient) may result in negligible ionization over times of interest. In any case the behavior is shown to behave much differently than in examples where limited cross section sets, common in currently employed predictive codes, are employed. In particular, the importance of momentum transfer is indicated. A critique of the scaling implications of the phenomena is made

  14. Secondary Trauma in Children and School Personnel

    Science.gov (United States)

    Motta, Robert W.

    2012-01-01

    A review of childhood secondary trauma is presented. Secondary trauma involves the transfer and acquisition of negative affective and dysfunctional cognitive states due to prolonged and extended contact with others, such as family members, who have been traumatized. As such, secondary trauma refers to a spread of trauma reactions from the victim…

  15. Programmed temperature vaporizing injector to filter off disturbing high boiling and involatile material for on-line high performance liquid chromatography gas chromatography with on-column transfer.

    Science.gov (United States)

    Biedermann, Maurus; Grob, Koni

    2013-03-15

    Insertion of a programmed temperature vaporizing (PTV) injector under conditions of concurrent solvent recondensation (CSR) into the on-line HPLC-GC interface for on-column transfer (such as the retention gap technique with partially concurrent eluent evaporation) enables filtering off high boiling or involatile sample constituents by a desorption temperature adjusted to the required cut-off. Details of this technique were investigated and optimized. Memory effects, observed when transferred liquid was sucked backwards between the transfer line and the wall of the injector liner, can be kept low by a small purge flow rate through the transfer line at the end of the transfer and the release of the liquid through a narrow bore capillary kept away from the liner wall. The column entrance should be within the well heated zone of the injector to prevent losses of solute material retained on the liner wall during the splitless period. The desorption temperature must be maintained until an elevated oven temperature is reached to prevent peak broadening resulting of a cool inlet section in the bottom part of the injector. Copyright © 2013 Elsevier B.V. All rights reserved.

  16. Organic nitrate and secondary organic aerosol yield from NO3 oxidation of β-pinene evaluated using a gas-phase kinetics/aerosol partitioning model

    Directory of Open Access Journals (Sweden)

    H.-P. Dorn

    2009-02-01

    Full Text Available The yields of organic nitrates and of secondary organic aerosol (SOA particle formation were measured for the reaction NO3+β-pinene under dry and humid conditions in the atmosphere simulation chamber SAPHIR at Research Center Jülich. These experiments were conducted at low concentrations of NO3 (NO3+N2O5pvap~5×10−6 Torr (6.67×10−4 Pa, which constrains speculation about the oxidation mechanism and chemical identity of the organic nitrate. Once formed the SOA in this system continues to evolve, resulting in measurable aerosol volume decrease with time. The observations of high aerosol yield from NOx-dependent oxidation of monoterpenes provide an example of a significant anthropogenic source of SOA from biogenic hydrocarbon precursors. Estimates of the NO3+β-pinene SOA source strength for California and the globe indicate that NO3 reactions with monoterpenes are likely an important source (0.5–8% of the global total of organic aerosol on regional and global scales.

  17. Report of study group 10.3 ''gas market development in developing countries: technology transfer and financing''; Rapport du groupe d'etudes 10.3 ''l'evolution du marche gazier dans les pays en voie de developpement. Transfert des tehnologies et financement''

    Energy Technology Data Exchange (ETDEWEB)

    Okimi, H.

    2000-07-01

    The study of SG10.3 in this triennium focuses on the gas downstream in developing countries. Discussions on gas developments have flourished in the international gas community often with more emphasis on production and transmission. This may be because that gas distribution is an every day activity for gas enterprises in many member countries and is thought not new. When we look at developments in developing countries, however, the gas downstream development is more important than we normally think. Upstream gas cannot be developed without confidence in gas market; then this affects the whole gas development which may not be achieved without a guaranteed market. A gas market is not simply there but has to be developed. When a gas field is found, people may simply think that there is a market for the gas somewhere. But gas is not a commodity in the countries where there is no distribution networks. Market development is an infrastructure development there, and it often requires complicated processes including financing, technology transfer, implementation of gas networks, marketing, and operation and maintenance. (author)

  18. Development of local heat transfer and pressure drop models for pebble bed high temperature gas-cooled reactor cores - HTR2008-58296

    International Nuclear Information System (INIS)

    McLaughlin, B.; Worsley, M.; Stainsby, R.; Grief, A.; Dennier, A.; Macintosh, S.; Van Heerden, E.

    2008-01-01

    This paper describes pressure drop and heat transfer coefficient predictions for a typical coolant flow within the core of a pebble bed reactor (PBR) by examining a representative group of pebbles remote from the reflector region. The three- dimensional steady state flow and heat transfer predictions utilized in this work are obtained from a computational fluid dynamics (CFD) model created in the commercial software ANSYS FLUENT TM . This work utilizes three RANS turbulence models and the Chilton-Colburn analogy for heat transfer. A methodology is included in this paper for creating a quality unstructured mesh with prismatic surface layers on a random arrangement of touching pebbles. The results of the model are validated by comparing them with the correlations of the German KTA rules for a PBR. (authors)

  19. R + D work on gas-cooled breeder development

    International Nuclear Information System (INIS)

    Dalle Donne, M.; Dorner, S.; Jacobs, G.; Meyer, L.; Rehme, K.; Schumacher, G.; Wilhelm, D.

    1978-01-01

    The development work for the gas-cooled breeder in the Karlsruhe Nuclear Research Center may be assigned to two different groups: a) Investigations on fuel elements. b) Studies concerning the safety of gas-cooled fast breeder reactors. To the first group there belongs the work related to the: - heat transfer between fuel elements and coolant gas, - influence of increased content of water vapor in helium or the fuel rods. The second group concerns: - establishing a computer code for transient calculations in the primary and secondary circuit of a gas-cooled fast breeder reactor, - steam reactivity coefficients, - the core destruction phase of hypothetical accidents, - the core-catcher using borax. (orig./RW) [de

  20. Natural Gas Market Hubs

    Data.gov (United States)

    Department of Homeland Security — A hub is a physical transfer point for natural gas where several pipelines are connected. A market center is a hub where the operator offers services that facilitate...

  1. Technologies for the management of MSW incineration ashes from gas cleaning: New perspectives on recovery of secondary raw materials and circular economy.

    Science.gov (United States)

    Quina, Margarida J; Bontempi, Elza; Bogush, Anna; Schlumberger, Stefan; Weibel, Gisela; Braga, Roberto; Funari, Valerio; Hyks, Jiri; Rasmussen, Erik; Lederer, Jakob

    2018-04-17

    Environmental policies in the European Union focus on the prevention of hazardous waste and aim to mitigate its impact on human health and ecosystems. However, progress is promoting a shift in perspective from environmental impacts to resource recovery. Municipal solid waste incineration (MSWI) has been increasing in developed countries, thus the amount of air pollution control residues (APCr) and fly ashes (FA) have followed the same upward trend. APCr from MSWI is classified as hazardous waste in the List of Waste (LoW) and as an absolute entry (19 01 07*), but FA may be classified as a mirror entry (19 0 13*/19 01 14). These properties arise mainly from their content in soluble salts, potentially toxic metals, trace organic pollutants and high pH in contact with water. Since these residues have been mostly disposed of in underground and landfills, other possibilities must be investigated to recover secondary raw materials and products. According to the literature, four additional routes of recovery have been found: detoxification (e.g. washing), product manufacturing (e.g. ceramic products and cement), practical applications (e.g. CO 2 sequestration) and recovery of materials (e.g. Zn and salts). This work aims to identify the best available technologies for material recovery in order to avoid landfill solutions. Within this scope, six case studies are presented and discussed: recycling in lightweight aggregates, glass-ceramics, cement, recovery of zinc, rare metals and salts. Finally, future perspectives are provided to advance understanding of this anthropogenic waste as a source of resources, yet tied to safeguards for the environment. Copyright © 2018 The Authors. Published by Elsevier B.V. All rights reserved.

  2. Absent menstrual periods - secondary

    Science.gov (United States)

    Amenorrhea - secondary; No periods - secondary; Absent periods - secondary; Absent menses - secondary; Absence of periods - secondary ... Secondary amenorrhea can occur due to natural changes in the body. For example, the most common cause of secondary ...

  3. SECONDARY NATURAL GAS RECOVERY IN THE APPALACHIAN BASIN: APPLICATION OF ADVANCED TECHNOLOGIES IN A FIELD DEMONSTRATION SITE, HENDERSON DOME, WESTERN PENNSYLVANIA

    Energy Technology Data Exchange (ETDEWEB)

    BOB A. HARDAGE; ELOISE DOHERTY; STEPHEN E. LAUBACH; TUCKER F. HENTZ

    1998-08-14

    The principal objectives of this project were to test and evaluate technologies that would result in improved characterization of fractured natural-gas reservoirs in the Appalachian Basin. The Bureau of Economic Geology (Bureau) worked jointly with industry partner Atlas Resources, Inc. to design, execute, and evaluate several experimental tests toward this end. The experimental tests were of two types: (1) tests leading to a low-cost methodology whereby small-scale microfractures observed in matrix grains of sidewall cores can be used to deduce critical properties of large-scale fractures that control natural-gas production and (2) tests that verify methods whereby robust seismic shear (S) waves can be generated to detect and map fractured reservoir facies. The grain-scale microfracture approach to characterizing rock facies was developed in an ongoing Bureau research program that started before this Appalachian Basin study began. However, the method had not been tested in a wide variety of fracture systems, and the tectonic setting of rocks in the Appalachian Basin composed an ideal laboratory for perfecting the methodology. As a result of this Appalachian study, a low-cost commercial procedure now exists that will allow Appalachian operators to use scanning electron microscope (SEM) images of thin sections extracted from oriented sidewall cores to infer the spatial orientation, relative geologic timing, and population density of large-scale fracture systems in reservoir sandstones. These attributes are difficult to assess using conventional techniques. In the Henderson Dome area, large quartz-lined regional fractures having N20E strikes, and a subsidiary set of fractures having N70W strikes, are prevalent. An innovative method was also developed for obtaining the stratigraphic and geographic tops of sidewall cores. With currently deployed sidewall coring devices, no markings from which top orientation can be obtained are made on the sidewall core itself during

  4. Gas and Gas Pains

    Science.gov (United States)

    ... to produce gas. Often, relatively simple changes in eating habits can lessen bothersome gas. Certain digestive system disorders, ... such as soda and beer, increase stomach gas. Eating habits, such as eating too quickly, drinking through a ...

  5. Laboratory Determination of Gas-Side Mass Transfer Coefficients Applicable to Soil Venting Systems for Removing Petroleum Hydrocarbons from Vadose Zone Soils

    Science.gov (United States)

    1991-01-01

    monolayers situated on either side of this interface (Treybal, 1980; Henley and Seader , 1981). This equilibrium condition may be used to describe mass transfer...W.F. Reehl and D.H. Rosenblatt, eds., Handbook of Chemical Property Estimation Methods, American Chemical Society, 1990. Henley, E.J. and J.D. Seader

  6. Combining Experiments and Simulation of Gas Absorption for Teaching Mass Transfer Fundamentals: Removing CO2 from Air Using Water and NaOH

    Science.gov (United States)

    Clark, William M.; Jackson, Yaminah Z.; Morin, Michael T.; Ferraro, Giacomo P.

    2011-01-01

    Laboratory experiments and computer models for studying the mass transfer process of removing CO2 from air using water or dilute NaOH solution as absorbent are presented. Models tie experiment to theory and give a visual representation of concentration profiles and also illustrate the two-film theory and the relative importance of various…

  7. Heat transfer in cryogenic helium gas by turbulent Rayleigh-Bénard convection in a cylindrical cell of aspect ratio 1

    Czech Academy of Sciences Publication Activity Database

    Urban, Pavel; Hanzelka, Pavel; Musilová, Věra; Králík, Tomáš; La Mantia, M.; Srnka, Aleš; Skrbek, L.

    2014-01-01

    Roč. 16, č. 5 (2014), 053042: 1-40 ISSN 1367-2630 R&D Projects: GA ČR GPP203/12/P897 Institutional support: RVO:68081731 Keywords : Rayleigh-Bénard convection * heat transfer efficiency * cryogenic helium Subject RIV: BK - Fluid Dynamics Impact factor: 3.558, year: 2014

  8. Molecularly Defined Manganese Pincer Complexes for Selective Transfer Hydrogenation of Ketones.

    Science.gov (United States)

    Perez, Marc; Elangovan, Saravanakumar; Spannenberg, Anke; Junge, Kathrin; Beller, Matthias

    2017-01-10

    For the first time an easily accessible and well-defined manganese N,N,N-pincer complex catalyzes the transfer hydrogenation of a broad range of ketones with good to excellent yields. This cheap earth abundant-metal based catalyst provides access to useful secondary alcohols without the need of hydrogen gas. Preliminary investigations to explore the mechanism of this transformation are also reported. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  9. Chemical characterization of latent fingerprints by matrix-assisted laser desorption ionization, time-of-flight secondary ion mass spectrometry, mega electron volt secondary mass spectrometry, gas chromatography/mass spectrometry, X-ray photoelectron spectroscopy, and attenuated total reflection Fourier transform infrared spectroscopic imaging: an intercomparison.

    Science.gov (United States)

    Bailey, Melanie J; Bright, Nicholas J; Croxton, Ruth S; Francese, Simona; Ferguson, Leesa S; Hinder, Stephen; Jickells, Sue; Jones, Benjamin J; Jones, Brian N; Kazarian, Sergei G; Ojeda, Jesus J; Webb, Roger P; Wolstenholme, Rosalind; Bleay, Stephen

    2012-10-16

    The first analytical intercomparison of fingerprint residue using equivalent samples of latent fingerprint residue and characterized by a suite of relevant techniques is presented. This work has never been undertaken, presumably due to the perishable nature of fingerprint residue, the lack of fingerprint standards, and the intradonor variability, which impacts sample reproducibility. For the first time, time-of-flight secondary ion mass spectrometry, high-energy secondary ion mass spectrometry, and X-ray photoelectron spectroscopy are used to target endogenous compounds in fingerprints and a method is presented for establishing their relative abundance in fingerprint residue. Comparison of the newer techniques with the more established gas chromatography/mass spectrometry and attenuated total reflection Fourier transform infrared spectroscopic imaging shows good agreement between the methods, with each method detecting repeatable differences between the donors, with the exception of matrix-assisted laser desorption ionization, for which quantitative analysis has not yet been established. We further comment on the sensitivity, selectivity, and practicability of each of the methods for use in future police casework or academic research.

  10. Flow laminarization and heat transfer crisis in tubes while intense heating of turbulent flow of a gas endothermically dissociating on a wall

    International Nuclear Information System (INIS)

    Kurganov, V.A.; Gladuntsov, A.I.

    1977-01-01

    Analysed are the experimental data obtained for heat transfer to gaseous dissociating ammonium (NH 3 ) under heating in round pipes (steel Kh18N10T) at developed eddying input flow and marginal condition of heat supply gsub(c) approximately equal to const in the ranges of the following parameters: p=3-10 atm; Tsub(input)=310-720 K; Tsub(c) ( 3 ; gsub(c)/-anti rho W 8.8 kJ/kg; gsub(c)/(anti rho WCsub(p) sub(input)Tsub(input)) (<=) 0.0104; 1/d (<=) 150 (where Tsub(c) is the wall temperature, gsub(c) the heat flow density on wall, and anti rho W velocity). The discussion involves phenomena of worsened heat transfer at high heat loads. The authors show the basic relationship between these phenomena and laminarization of the near-wall flow at the input site of the pipe. The regularities of heat transfer were noted to undergo substantial transformation under laminarized flow

  11. Photochemical Aging of α-pinene and β-pinene Secondary Organic Aerosol formed from Nitrate Radical Oxidation: New Insights into the Formation and Fates of Highly Oxygenated Gas- and Particle-phase Organic Nitrates

    Science.gov (United States)

    Nah, T.; Sanchez, J.; Boyd, C.; Ng, N. L.

    2015-12-01

    The nitrate radical (NO3), one of the most important oxidants in the nocturnal atmosphere, can react rapidly with a variety of biogenic volatile organic compounds (BVOCs) to form high mass concentrations of secondary organic aerosol (SOA) and organic nitrates (ON). Despite its critical importance in aerosol formation, the mechanisms and products from the NO3 oxidation of BVOCs have been largely unexplored, and the fates of their SOA and ON after formation are not well characterized. In this work, we studied the formation of SOA and ON from the NO3 oxidation of α-pinene and β-pinene and investigated for the first time how they evolve during dark and photochemical aging through a series of chamber experiments performed at the Georgia Tech Environmental Chamber (GTEC) facility. The α-pinene and β-pinene SOA are characterized using real-time gas- and particle-phase measurements, which are used to propose mechanisms for SOA and organic nitrate formation and aging. Highly oxygenated gas- and particle-phase ON (containing as many as 9 oxygen atoms) are detected during the NO3 reaction. In addition, the β-pinene SOA and α-pinene SOA exhibited drastically different behavior during photochemical aging. Our results indicate that nighttime ON formed by NO3+monoterpene chemistry can serve as either NOx reservoirs or sinks depending on the monoterpene precursor. Results from this study provide fundamental data for evaluating the contributions of NO3+monoterpene reactions to ambient OA measured in the Southeastern U.S.

  12. TTF stirs market for natural gas

    International Nuclear Information System (INIS)

    Meyboom, W.

    2007-01-01

    Recently, the Dutch company Air Products switched from Gasterra to the virtual gas market place TTF, taking along several of its own clients. Gasterra thus lost a major client for high calorific gas. The gas market is in full motion. TitleTransfer Facility is a virtual market place of the operator of the Dutch natural gas transport grid, Gas Transport Services. [mk] [nl

  13. 30 CFR 250.1203 - Gas measurement.

    Science.gov (United States)

    2010-07-01

    ... base pressure of 14.73 psia and reflect the same degree of water saturation as in the gas volume. (8... gas meter. Show whether gas volumes and gross Btu heating values are reported at saturated or... are the requirements when natural gas from a Federal lease on the OCS is transferred to a gas plant...

  14. Development of a supercritical fluid extraction-gas chromatography-mass spectrometry method for the identification of highly polar compounds in secondary organic aerosols formed from biogenic hydrocarbons in smog chamber experiments.

    Science.gov (United States)

    Chiappini, L; Perraudin, E; Durand-Jolibois, R; Doussin, J F

    2006-11-01

    A new one-step method for the analysis of highly polar components of secondary organic aerosols (SOA) has been developed. This method should lead to a better understanding of SOA formation and evolution since it enables the compounds responsible for SOA formation to be identified. Since it is based on supercritical fluid extraction coupled to gas chromatography-mass spectrometry, it minimizes the analysis time and significantly enhances sensitivity, which makes it suitable for trace-level compounds, which are constituents of SOA. One of the key features of this method is the in situ derivatisation step: an online silylation allowing the measurement of highly polar, polyfunctional compounds, which is a prerequisite for the elucidation of chemical mechanisms. This paper presents the development of this analytical method and highlights its ability to address this major atmospheric issue through the analysis of SOA formed from the ozonolysis of a biogenic hydrocarbon (sabinene). Ozonolysis of sabinene was performed in a 6 m3 Teflon chamber. The aerosol components were derivatised in situ. More than thirty products, such as sabinaketone, sabinic acid and other multifunctional compounds including dicarboxylic acids and oxoacids, were measured. Nine of them were identified and quantified. The sensitivity and the linearity (0.91

  15. Natural gas; Gas Natural

    Energy Technology Data Exchange (ETDEWEB)

    Lopes, Carlos A.; Moraes, Claudia C.D. [Eletricidade de Sao Paulo S.A. (ELETROPAULO), Sao Paulo, SP (Brazil); Fonseca, Carlos H.F. [Centrais Eletricas de Santa Catarina S.A., Florianopolis, SC (Brazil); Silva, Clecio Fabricio da; Alves, Ricardo P. [Companhia Paranaense de Energia (COPEL), Curitiba, PR (Brazil); Sposito, Edivaldo Soares; Hulle, Lutero [Espirito Santo Centrais Eletricas S.A. (ESCELSA), Vitoria, ES (Brazil); S. Martins, Icaro da [Centrais Eletricas do Norte do Brasil S.A. (ELETRONORTE), Belem, PA (Brazil); Vilhena, Joao Luiz S. de [Companhia Energetica de Minas Gerais (CEMIG), Belo Horizonte, MG (Brazil); Fagundes, Zaluar Aquino [Companhia Estadual de Energia Eletrica do Estado do Rio Grande do Sul, Porto Alegre, RS (Brazil)

    1996-12-31

    An increase in the consumption of natural gas in Brazil is an expected fact in what concerns energetic planning. This work presents the existing situation in what concerns natural gas utilization in the main world economies, as well as an analysis of the participation of this fuel among the energy final consumption per sources. The Brazilian consumption of natural gas is also analysed as well as the international agreement between Brazil and Bolivia for natural gas commercialization. Some legal, institutional and political aspects related to natural gas commercialization are also discussed. Finally, several benefits to be brought by the utilization of natural gas are presented 10 refs., 3 tabs.

  16. Solid phase characterization and gas transfers through unsaturated porous media: experimental study and modeling applied diffusion of hydrogen through cement-based materials

    International Nuclear Information System (INIS)

    Vu, T.H.

    2009-10-01

    This thesis documents the relationship between the porous microstructure of cement based materials and theirs gaseous diffusivity properties relative to the aqueous phase location and the global saturation level of the material. The materials studied are cement pastes and mortars. To meet the thesis objective, the materials are characterized in detail by means of several experimental methods: mercury intrusion porosimetry, water porosimetry, thermo-poro-metry, nitrogen sorption and water desorption. In addition, diffusion tests realized on materials maintained in controlled humidity chambers allow obtaining the effective hydrogen diffusivity as function of the microstructure and the saturation state of material with a gas chromatography. The experimental results are then used as a data base that is compared to a modeling approach. The model developed consists of a combination of ordinary diffusion (Fick regime) and Knudsen diffusion of hydrogen. The model also accounts for the effects of the liquid curtains, the impact of tortuosity on gas diffusion, and the saturation level of the porous system. (author)

  17. 13 CFR 120.601 - SBA Secondary Market.

    Science.gov (United States)

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false SBA Secondary Market. 120.601... Market Fiscal and Transfer Agent (fta) § 120.601 SBA Secondary Market. The SBA secondary market (“Secondary Market”) consists of the sale of Certificates, representing either the entire guaranteed portion...

  18. Secondary dyslipidaemia

    African Journals Online (AJOL)

    Repro

    metabolism of lipoprotein particles, most often the triglyceride (TG)-rich particles. Under normal metabolic conditions these patients may be entirely normal, but when exposed to one of the secondary causes this 'excessive metabolic load' precipitates an ever-worsening cycle of impairment in lipoprotein metabolism.

  19. Gas-Phase Mass-Transfer Resistances at Polymeric Electrolyte Membrane Fuel Cells Electrodes: Theoretical Analysis on the Effectiveness of Interdigitated and Serpentine Flow Arrangements

    Directory of Open Access Journals (Sweden)

    Elisabetta Arato

    2016-03-01

    Full Text Available Mass transfer phenomena in polymeric electrolyte membrane fuel cells (PEMFC electrodes has already been analyzed in terms of the interactions between diffusive and forced flows. It was demonstrated that the whole phenomenon could be summarized by expressing the Sherwood number as a function of the Peclet number. The dependence of Sherwood number on Peclet one Sh(Pe function, which was initially deduced by determining three different flow regimes, has now been given a more accurate description. A comparison between the approximate and the accurate results for a reference condition of diluted reactant and limit current has shown that the former are useful for rapid, preliminary calculations. However, a more precise and reliable estimation of the Sherwood number is worth attention, as it provides a detailed description of the electrochemical kinetics and allows a reliable comparison of the various geometrical arrangements used for the distribution of the reactants.

  20. Generation of inclined protoplanetary discs and misaligned planets through mass accretion - I. Coplanar secondary discs

    Science.gov (United States)

    Xiang-Gruess, M.; Kroupa, P.

    2017-10-01

    We study the three-dimensional (3D) evolution of a viscous protoplanetary disc that accretes gas material from a second protoplanetary disc during a close encounter in an embedded star cluster. The aim is to investigate the capability of the mass accretion scenario to generate strongly inclined gaseous discs that could later form misaligned planets. We use smoothed particle hydrodynamics to study mass transfer and disc inclination for passing stars and circumstellar discs with different masses. We explore different orbital configurations to find the parameter space that allows significant disc inclination generation. Thies et al. suggested that significant disc inclination and disc or planetary system shrinkage can generally be produced by the accretion of external gas material with a different angular momentum. We found that this condition can be fulfilled for a large range of gas mass and angular momentum. For all encounters, mass accretion from the secondary disc increases with decreasing mass of the secondary proto-star. Thus, higher disc inclinations can be attained for lower secondary stellar masses. Variations of the secondary disc's orientation relative to the orbital plane can alter the disc evolution significantly. The results taken together show that mass accretion can change the 3D disc orientation significantly resulting in strongly inclined discs. In combination with the gravitational interaction between the two star-disc systems, this scenario is relevant for explaining the formation of highly inclined discs that could later form misaligned planets.

  1. Gas and Gas Pains

    Science.gov (United States)

    ... Gas and gas pains Symptoms & causes Diagnosis & treatment Advertisement Mayo Clinic does not endorse companies or products. ... a Job Site Map About This Site Twitter Facebook Google YouTube Pinterest Mayo Clinic is a not- ...

  2. Multiple automated headspace in-tube extraction for the accurate analysis of relevant wine aroma compounds and for the estimation of their relative liquid-gas transfer rates.

    Science.gov (United States)

    Zapata, Julián; Lopez, Ricardo; Herrero, Paula; Ferreira, Vicente

    2012-11-30

    An automated headspace in-tube extraction (ITEX) method combined with multiple headspace extraction (MHE) has been developed to provide simultaneously information about the accurate wine content in 20 relevant aroma compounds and about their relative transfer rates to the headspace and hence about the relative strength of their interactions with the matrix. In the method, 5 μL (for alcohols, acetates and carbonyl alcohols) or 200 μL (for ethyl esters) of wine sample were introduced in a 2 mL vial, heated at 35°C and extracted with 32 (for alcohols, acetates and carbonyl alcohols) or 16 (for ethyl esters) 0.5 mL pumping strokes in four consecutive extraction and analysis cycles. The application of the classical theory of Multiple Extractions makes it possible to obtain a highly reliable estimate of the total amount of volatile compound present in the sample and a second parameter, β, which is simply the proportion of volatile not transferred to the trap in one extraction cycle, but that seems to be a reliable indicator of the actual volatility of the compound in that particular wine. A study with 20 wines of different types and 1 synthetic sample has revealed the existence of significant differences in the relative volatility of 15 out of 20 odorants. Differences are particularly intense for acetaldehyde and other carbonyls, but are also notable for alcohols and long chain fatty acid ethyl esters. It is expected that these differences, linked likely to sulphur dioxide and some unknown specific compositional aspects of the wine matrix, can be responsible for relevant sensory changes, and may even be the cause explaining why the same aroma composition can produce different aroma perceptions in two different wines. Copyright © 2012 Elsevier B.V. All rights reserved.

  3. Gas and particulate phase products from the ozonolysis of acenaphthylene

    Science.gov (United States)

    Riva, Matthieu; Healy, Robert M.; Tomaz, Sophie; Flaud, Pierre-Marie; Perraudin, Emilie; Wenger, John C.; Villenave, Eric

    2016-10-01

    Polycyclic aromatic hydrocarbons (PAHs) are recognized as important secondary organic aerosol (SOA) precursors in the urban atmosphere. In this work, the gas-phase ozonolysis of acenaphthylene was investigated in an atmospheric simulation chamber using a proton transfer reaction time-of-flight-mass spectrometer (PTR-TOF-MS) and an aerosol time-of-flight-mass spectrometer (ATOFMS) for on-line characterization of the oxidation products in the gas and particle phases, respectively. SOA samples were also collected on filters and analyzed by ultra performance liquid chromatography/electrospray ionization high-resolution quadrupole time-of-flight mass spectrometry (UPLC/ESI-HR-QTOFMS) and gas chromatography/electron impact ionization-mass spectrometry (GC/EI-MS). The major gas-phase products included a range of oxygenated naphthalene derivatives such as 1,8-naphthalic anhydride, naphthalene 1,8-dicarbaldehyde and naphthaldehyde, as well as a secondary ozonide. Possible reaction mechanisms are proposed for the formation of these products and favoured pathways have been suggested. Many of these products were also found in the particle phase along with a range of oligomeric compounds. The same range of gas and particle phase products was observed in the presence and absence of excess cyclohexane, an OH scavenger, indicating that OH radical production from the ozonolysis of acenaphthylene is negligible. SOA yields in the range 23-37% were determined and indicate that acenaphthylene ozonolysis may contribute to part of the SOA observed in urban areas.

  4. PTAC 2003 annual report : creating value through innovation : facilitating innovation, technology transfer, and collaborative research and development in the upstream oil and gas industry

    International Nuclear Information System (INIS)

    2004-01-01

    Petroleum Technology Alliance Canada (PTAC) is Canada's leading organization that helps in the development and transfer of petroleum technology. This annual report listed the key achievements in 2003, and presented an outlook for 2004. PTAC hosted 16 forums, workshops and conferences in 2003 which focused on specific needs or technical areas. The organization also facilitated 18 Technology Information Sessions in 2003 for members to promote interest, feedback and participation or funding for new research and development projects and to find industry partners. The projects launched in 2003 focused on the following issues: driving safety, e-business, emission reduction, eco-efficiency, environment, heavy oil, and innovation. In 2003, PTAC conducted a web survey and sent out two questionnaires to gain industry feedback on various topics. This annual report includes an auditor's report of PTAC's financial statements. The report includes summarized balance sheet of assets, liabilities/surplus and net assets. It also includes summarized statements of revenues, expenses and surplus for the year ended December 31, 2003 with comparative figures for 2002. 1 tab

  5. Column imprints: a secondary index structure

    NARCIS (Netherlands)

    Sidirourgos, L.; Kersten, M.

    2013-01-01

    Large scale data warehouses rely heavily on secondary indexes, such as bitmaps and b-trees, to limit access to slow IO devices. However, with the advent of large main memory systems, cache conscious secondary indexes are needed to improve also the transfer bandwidth between memory and cpu. In this

  6. Gas development plan - Lithuania

    International Nuclear Information System (INIS)

    1993-10-01

    A detailed description of the plan for the development of gas utilization in Lithuania is presented. The plan is subdivided under the headings of gas supply, gas demand, gas transmission and distribution, economy and the organization of the gas sector in the country. The first phase of the project has been undertaken by a Danish firm in cooperation with the Lithuanian firm Lietuvos Dujos. The first aim was to clarify the problems that will arise in connection with this joint venture on developing the use of gas in Lithuania, focusing on existing gas supply and market conditions, the current flow control and metering and economic constraints. The organization of the gas sector in the country as it stands today is described and possible models for its future organization are discussed in addition to a strategy of implementation. Possible development trends are outlined and maximum/minimum demand scenarios are suggested. Subjects and areas related to the gas sector in Lithuania are identified for further investigation in the next phase. It is stated that Lithuania is at present undergoing a fast transformation towards a market economy and that the transfer of foreign currency has been liberalized. Only the pipeline from Minsk to Vilnius is open at present and provides the total supply of natural gas to Lithuania and Kalingrad, controlled by the Russian gas company, Lentransgas, on the basis of a gas purchase agreement regulated on a yearly basis. Other possible supply sources are the Danish part of the North Sea and the Norwegian offshore fields. (AB)

  7. Technology Transfer Report

    Science.gov (United States)

    2000-01-01

    Since its inception, Goddard has pursued a commitment to technology transfer and commercialization. For every space technology developed, Goddard strives to identify secondary applications. Goddard then provides the technologies, as well as NASA expertise and facilities, to U.S. companies, universities, and government agencies. These efforts are based in Goddard's Technology Commercialization Office. This report presents new technologies, commercialization success stories, and other Technology Commercialization Office activities in 1999.

  8. On the deposition of volatiles and semivolatiles from cigarette smoke aerosols: relative rates of transfer of nicotine and ammonia from particles to the gas phase.

    Science.gov (United States)

    Seeman, Jeffrey I; Lipowicz, Peter J; Piadé, Jean-Jacques; Poget, Laurent; Sanders, Edward B; Snyder, James P; Trowbridge, Clarence G

    2004-08-01

    The hypothesis that elevated levels of ammonia-releasing compounds in tobacco and ammonia in mainstream (MS) smoke increase the rate and amount of nicotine evaporation from the particles of MS smoke aerosol was examined by kinetic modeling and experiments with MS cigarette smoke. Computational simulation of a kinetic mechanism describing volatile loss of nicotine, ammonia, and acetic acid from an aqueous solution was used to compute the time-dependent concentration of all species in the model. Because of the high volatility of ammonia relative to that of nicotine, variation over a wide range of initial ammonia concentration had no significant effect upon the rate of loss of nicotine from the model system. The effects of a variation in the volatile loss rate constant for ammonia and for the acid were examined. The simulations show that ammonia is lost from the model solution at a greater rate than nicotine and acid, and the loss of volatile acid has a significant role in the rate and amount of nicotine loss. Simulations with a model system undergoing a continuous steady addition of ammonia showed that high rates of ammonia addition could significantly increase the rate of nicotine volatile loss from the model solution. A series of smoking experiments was performed using blended cigarettes connected to a denuder tube. Deposition of smoke constituents can occur directly from the gas phase and by the deposition of smoke aerosol particles themselves. As nicotine exists >99% in the particle phase of MS smoke, in the absence of particle deposition, denuder tube deposition of nicotine occurs via the evaporation-deposition pathway. Solanesol, a nonvolatile tobacco and smoke terpene, was used to quantify the amount of particle deposition onto the denuder tube. The amount of ammonia deposited on the denuder tube was an order of magnitude greater than that of nicotine, showing that ammonia evaporates from the MS smoke particles much faster than does nicotine. The experimental

  9. Secondary Craters

    Science.gov (United States)

    2005-01-01

    7 October 2005 This Mars Global Surveyor (MGS) Mars Orbiter Camera (MOC) image shows a cluster of craters in far western Arabia Terra. The crater cluster is oriented along a line that runs nearly east-west (left-right) across the scene. Clusters of craters positioned along a line like this are secondary craters -- that is, they formed as the result of a much larger meteor, asteroid, or cometary impact somewhere else in the region. These craters do not form from the object that impacted Mars to form the larger, primary crater; these are the product of the impact of the rocks and debris thrown out by the larger impact. Location near: 14.9oN, 19.3oW Image width: width: 3 km (1.9 mi) Illumination from: lower left Season: Northern Autumn

  10. Energy imparted, energy transferred, and net energy transferred

    International Nuclear Information System (INIS)

    Attix, F.H.

    1983-01-01

    The ICRU-defined non-stochastic quantity absorbed dose is related to the stochastic quantity energy imparted. In the present paper the corresponding stochastic quantities energy transferred and net energy transferred are defined as precursors for kerma and collision kerma, respectively. This forms a rational fundamental framework for radiation dosimetry which facilitates its teaching and understanding. For neutrons collision kerma coincides with kerma, because the heavy secondaries do not lose significant energy by radiative processes (e.g., bremsstrahlung)

  11. Mesure et modélisation multidimensionnelle des transferts thermiques gaz-paroi dans le cas des moteurs à allumage commandé Measurement and Multidimensional Modeling of Gas-Wall Heat Transfers in Spark-Ignition Engines

    Directory of Open Access Journals (Sweden)

    Gilaber P.

    2006-11-01

    formulation k-epsilon de la turbulence a été adoptée. La sensibilité du modèle aux effets de densité et de turbulence a été testée par l'intermédiaire de variations de l'avance à l'allumage et du régime. La comparaison entre mesure et simulation a montré un bon accord, tant en termes de flux thermiques locaux et instantanés, qu'en termes de bilan global. The computational fluid dynamics codes, which help to predict the behaviour of combusting gas in reciprocating engines, need, as boundary conditions for the momentum and energy equations, to approximate wall frictions and heat transfer between gas and walls. The purpose of this work is to validate a heat transfer model for spark ignited engines. Two steps of research have been worked on to meet this objective: an experimental phase and a computational phase. In the experimental phase, measurements were made on a test-engine instrumented with fast-response surface heat flux gages. Each gage consisted of a steel cylinder, containing two thermocouples. To analyze the influence of fluid dynamics on heat transfer, a Laser Doppler Velocimeter was used, by means of a spacer placed between the engine head and cylinder. The spacer was equiped with two windows and two heat-flux gages permitting simultaneous measurements of the heat flux and of the fluid dynamics outside the boundary layer. Two other gages were present in the head of the engine and up to ten data inputs could be simultaneously recorded at each crank-angle, including two velocity components and the cylinder pressure. A parametric analysis was carried out revealing the following trends:- the global heat transfer rate for a thermodynamic cycle of the engine decreases as the speed of the engine is increased, but the peak value of the wall heat-flux increases because of the increase of the turbulence level. - the volumetric efficiency appeared to have little effect on the turbulence level, and its influence on the heat transfer is mainly due to the increase of

  12. Secondary combustion system for wood burning stove

    Energy Technology Data Exchange (ETDEWEB)

    von Conta, P.E.W.

    1986-12-16

    This patent describes an improved secondary combustion system for combusting the exhaust gases exiting from a fire box in a wood burning stove comprising: an insulated conduit defining an exhaust passageway leading from an intake opening to an exit opening; screen means interposed across the exhaust passageway in the vicinity of the intake opening to impart a rapid acceleration to a gas stream entering the exhaust passageway; rotation means to impart a rotation to the gas stream in a first portion of the exhaust passageway; counter-rotation means to impart a counter-rotation to the gas stream in a second portion of the exhaust passageway; deceleration means to decelerate the gas stream in the second portion of the exhaust passageway; and secondary air means to inject a source of secondary air into the exhaust passageway.

  13. Gas-phase chemical dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Weston, R.E. Jr.; Sears, T.J.; Preses, J.M. [Brookhaven National Laboratory, Upton, NY (United States)

    1993-12-01

    Research in this program is directed towards the spectroscopy of small free radicals and reactive molecules and the state-to-state dynamics of gas phase collision, energy transfer, and photodissociation phenomena. Work on several systems is summarized here.

  14. Selective exhaust gas recirculation in combined cycle gas turbine power plants with post-combustion carbon capture

    OpenAIRE

    Herraiz Palomino, Laura

    2017-01-01

    Selective Exhaust Gas Recirculation (S-EGR) consists of selectively transferring CO2 from the exhaust gas stream of a gas-fired power plant into the air stream entering the gas turbine compressor. Unlike in “non-selective” Exhaust Gas Recirculation (EGR) technology, recirculation of, principally, nitrogen does not occur, and the gas turbine still operates with a large excess of air. Two configurations are proposed: one with the CO2 transfer system operating in parallel to th...

  15. Transfer Pricing

    OpenAIRE

    Larsen, Mads Grenaa; Nørgaard, Mads Frid; Hansen, Manjarita

    2013-01-01

    This project seeks to highlight some of the criticisms given towards the OECD Transfer Pricing Guidelines and the challenges Danish companies experience by pricing their goods and the problems this causes for trade. The project is based on a series of interviews that represent the different agents who are operating in Transfer Pricing business. These interviews, combined with the Transfer Pricing Guidelines, gives us the basis to analyse the challenges we want to clarify based on the hypothes...

  16. Natural gas in Mexico

    International Nuclear Information System (INIS)

    Ramirez, M.

    1999-01-01

    A series of overhead viewgraphs accompanied this presentation which focused on various aspects of the natural gas industry in Mexico. Some of the viewgraphs depicted statistics from 1998 regarding natural gas throughput from various companies in North America, natural gas reserves around the world, and natural gas reserves in Mexico. Other viewgraphs depicted associated and non-associated natural gas production from 1988 to 1998 in million cubic feet per day. The Burgos Basin and the Cantarell Basin gas production from 1997 to 2004 was also depicted. Other viewgraphs were entitled: (1) gas processing infrastructure for 1999, (2) cryogenic plant at Cd. PEMEX, (3) average annual growth of dry natural gas production for 1997-2004 is estimated at 5.2 per cent, (4) gas flows for December 1998, (5) PGPB- interconnect points, (6) U.S. Mexico gas trade for 1994-1998, (7) PGPB's interconnect projects with U.S., and (8) natural gas storage areas. Technological innovations in the industry include more efficient gas turbines which allow for cogeneration, heat recovery steam generators which reduce pollutant emissions by 21 per cent, cold boxes which increase heat transfer efficiency, and lateral reboilers which reduce energy consumption and total costs. A pie chart depicting natural gas demand by sector shows that natural gas for power generation will increase from 16 per cent in 1997 to 31 per cent in 2004. The opportunities for cogeneration projects were also reviewed. The Comision Federal de Electricidad and independent power producers represent the largest opportunity. The 1997-2001 investment program proposes an 85 per cent sulphur dioxide emission reduction compared to 1997 levels. This presentation also noted that during the 1998-2001 period, total ethane production will grow by 58 tbd. 31 figs

  17. Transfer Pricing

    DEFF Research Database (Denmark)

    Rohde, Carsten; Rossing, Christian Plesner

    trade internally as the units have to decide what prices should be paid for such inter-unit transfers. One important challenge is to uncover the consequences that different transfer prices have on the willingness in the organizational units to coordinate activities and trade internally. At the same time...... the determination of transfer price will affect the size of the profit or loss in the organizational units and thus have an impact on the evaluation of managers‟ performance. In some instances the determination of transfer prices may lead to a disagreement between coordination of the organizational units...

  18. Methods of natural gas liquefaction and natural gas liquefaction plants utilizing multiple and varying gas streams

    Science.gov (United States)

    Wilding, Bruce M; Turner, Terry D

    2014-12-02

    A method of natural gas liquefaction may include cooling a gaseous NG process stream to form a liquid NG process stream. The method may further include directing the first tail gas stream out of a plant at a first pressure and directing a second tail gas stream out of the plant at a second pressure. An additional method of natural gas liquefaction may include separating CO.sub.2 from a liquid NG process stream and processing the CO.sub.2 to provide a CO.sub.2 product stream. Another method of natural gas liquefaction may include combining a marginal gaseous NG process stream with a secondary substantially pure NG stream to provide an improved gaseous NG process stream. Additionally, a NG liquefaction plant may include a first tail gas outlet, and at least a second tail gas outlet, the at least a second tail gas outlet separate from the first tail gas outlet.

  19. Delayed transfer of care from NHS secondary care to primary care in England: its determinants, effect on hospital bed days, prevalence of acute medical conditions and deaths during delay, in older adults aged 65 years and over

    Directory of Open Access Journals (Sweden)

    McGourty John C

    2009-01-01

    Full Text Available Abstract Background The delay in discharge or transfer of care back to the community following an acute admission to the hospital in older adults has long been a recognized challenge in the UK. We examined the determinants and outcomes of delayed transfer of care in older adults. Methods A prospective observational study was conducted in a district general hospital with a catchment population of 250,000 in England, UK. Those >= 65 years admitted to two care of the elderly wards during February 2007 were identified and prospectively followed-up till their discharge. Data was presented descriptively. Results 36.7% (58/158 of patients had a delay in transfer of care. They tended to be older, had poorer pre-morbid mobility, and were more likely to be confused at the time of admission. Compared to the 2003 National Audit Report, a significantly higher percentage (29.3%vs.17% awaited therapist assessments or (27.6%vs.9% domiciliary care, with a lower percentage ( Conclusion Awaiting therapy and domiciliary care input were significant contributing factors in delayed transfer of care. Similar local assessments could provide valuable information in identifying areas for improvement. Based on available current evidence, efficacy driven changes to the organisation and provision of support, for example rapid response delayed discharge services at the time of "fit to discharge" may help to improve the situation.

  20. Gas proportional scintillation counter

    International Nuclear Information System (INIS)

    Iguchi, Tetsuo; Nakazawa, Masaharu; Sekiguchi, Akira

    1980-01-01

    As the trial in the first stage of utilizing recoil helium for the measurement of 2 - 14 MeV neutron spectra in the simulated blanket for a nuclear fusion reactor, the He-Xe system gas proportional scintillation counter (GPSC) has been manufactured for trial, giving consideration to the advantages of gas scintillators and further to improve the energy resolution. In GPSC, delayed secondary scintillation pulses are produced, and its amplitude gives the energy resolution the adverse effect. Thus, in order to improve the energy resolution, it is desirable to realize such geometry of proportional counters that the electric field in the vicinity of center wire is sufficiently intense to induce the secondary excitation or ionization. The counters of such construction are called GPSC, in which the actual energy resolution can be improved according to the secondary scintillation pulses without losing the fast primary scintillation pulses useful for fast coincidence technique. The experimental results and the consideration on them are described. As compared with proportional counters, GPSC can give large output pulses even at low voltage, improve the energy resolution greatly as compared with ordinary gas scintillators, and measure the time data by the primary scintillation and the energy data based on the secondary scintillation simultaneously. However, it is likely to be affected by gas impurities more than proportional counters, and inferior in the reproducibility and stability of measurement. (Wakatsuki, Y.)

  1. Creep collapse of thick-walled heat transfer tube subjected to external pressure at high temperature

    International Nuclear Information System (INIS)

    Ioka, Ikuo; Kaji, Yoshiyuki; Terunuma, Isao; Nekoya, Shin-ichi; Miyamoto, Yoshiaki

    1994-09-01

    A series of creep collapse tests of thick-walled heat transfer tube were examined experimentally and analytically to confirm an analytical method for creep deformation behavior of a heat transfer tube of an intermediate heat exchanger (IHX) at a depressurization accident of secondary cooling system of HTTR (High Temperature Engineering Test Reactor). The tests were carried out using thick-walled heat transfer tubes made of Hastelloy XR at 950degC in helium gas environment. The predictions of creep collapse time obtained by a general purpose FEM-code ABAQUS were in good agreement with the experimental results. A lot of cracks were observed on the outer surface of the test tubes after the creep collapse. However, the cracks did not pass through the tube wall and, therefore, the leak tightness was maintained regardless of a collapse deformation for all tubes tested. (author)

  2. Transfer Pricing

    DEFF Research Database (Denmark)

    Rohde, Carsten; Rossing, Christian Plesner

    trade internally as the units have to decide what prices should be paid for such inter-unit transfers. One important challenge is to uncover the consequences that different transfer prices have on the willingness in the organizational units to coordinate activities and trade internally. At the same time...

  3. Transfer Pricing

    DEFF Research Database (Denmark)

    Nielsen, Søren Bo

    2014-01-01

    Against a background of rather mixed evidence about transfer pricing practices in multinational enterprises (MNEs) and varying attitudes on the part of tax authorities, this paper explores how multiple aims in transfer pricing can be pursued across four different transfer pricing regimes. A MNE has...... a production subsidiary in one country, from where it sells the produced good locally as well as to a sales subsidiary in a second country. The latter subsidiary is engaged in duopolistic competition with a local competitor. The MNE has two aims in setting the transfer price: strategic delegation and tax...... minimization. We examine the extent to which the four transfer pricing regimes we set up allow the MNE to pursue these aims. While neither strategic delegation nor tax minimization will be eliminated, trade-offs are inevitable, albeit to varying degree....

  4. Transfer Pricing

    DEFF Research Database (Denmark)

    Nielsen, Søren Bo

    2014-01-01

    a production subsidiary in one country, from where it sells the produced good locally as well as to a sales subsidiary in a second country. The latter subsidiary is engaged in duopolistic competition with a local competitor. The MNE has two aims in setting the transfer price: strategic delegation and tax......Against a background of rather mixed evidence about transfer pricing practices in multinational enterprises (MNEs) and varying attitudes on the part of tax authorities, this paper explores how multiple aims in transfer pricing can be pursued across four different transfer pricing regimes. A MNE has...... minimization. We examine the extent to which the four transfer pricing regimes we set up allow the MNE to pursue these aims. While neither strategic delegation nor tax minimization will be eliminated, trade-offs are inevitable, albeit to varying degree....

  5. Transfers in multiphase environment; Transferts en milieu multiphasique

    Energy Technology Data Exchange (ETDEWEB)

    Marinhas, S.; Delahaye, A.; Fournaison, L. [Cemagref - GPAN, 92 - Antony (France); Dalmazzone, D.; Furst, W. [Ecole Nationale Superieure de Techniques Avancees (ENSTA), 75 - Paris (France); Petitet, J.P. [Laboratoire d' Ingenierie des Materiaux et des Hautes Pressions (LIMHP), CNRS, 93 - Villetaneuse (France); Trinquet, F.; Royon, L.; Kayossi, H.; Guiffant, G. [Laboratoire Matiere Systeme Complexe, CNRS UMR 7057, 75 - Paris (France); El Omari, L.; Baonga, J.B.; Louahlia-Gualous, H.; Panday, P.K. [Institut FEMTO, Dept. C.R.E.S.T.-UTBM-UFC, UMR CNRS 6174, 90 - Belfort (France); Asbik, M.; Ansari, O. [UFR de Modelisation, Optimisation et Ingenierie des Systemes Energetiques, Faculte des Sciences et Techniques, Errachidia (Morocco); Zeghmati, B. [Perpignan Univ., Laboratoire de Mathematiques et Physique des Systemes, Groupe de Mecanique Energetique (M.E.P.S.-G.M.E.), EA 3086, 66 (France); Jamil, A.; Zeraouli, Y.; Dumas, J.P. [Pau Univ. et des Pays de l' Adour, Lab. de Thermique, Energetique et Procedes (LaTEP), 64 (France); Roux, P.; Fichot, F. [CEA Cadarache, Institut de Radioprotection et de Surete Nucleaire (IRSN), 13 - Saint-Paul-lez-Durance (France); Gobin, D.; Goyeau, B. [Laboratoire FAST, 91 - Orsay (France); Quintard, M. [Institut de Mecanique des Fluides, 31 - Toulouse (France); Barthes, M.; Reynard, Ch.; Santini, R.; Tadrist, L. [Laboratoire IUSTI CNRS UMR 6595, 13 - Marseille (France)

    2005-07-01

    This session about heat and mass transfers in multiphase flows gathers 17 papers dealing with: dynamic study of gas hydrate slurry applied to secondary refrigeration; ice melting inside an agitated reactor: experiment and phenomenological approach; experimental and numerical investigation of the local thickness change of a liquid film dripping around an horizontal tube; evaporation of a liquid film dripping around the external wall of an horizontal tube: laminar-turbulent transition phenomenon; coldness distribution by stabilized ice slurries, study of the behaviour under thermal cycling; study of phases disequilibria of two-phase refrigerating fluids; solidification of binary mixtures, influence of the local chemical non-equilibrium and of the effective transport properties; analysis of heat transfers during the growth of a vapor bubble; forecasting of micro-porosity inside Al-Si alloy smelting parts; estimation of a source term in a 2D transient problem: application to electron beam welding; mesoscopic approach of thermal flows; experimental and numerical study of the impact of a circular jet on a heated disc; inverse conduction method for a jet impacting a rotating cylinder: feasibility study; experimental follow up of a fusion-solidification front with and without transfer promoter; parametric study of a latent heat storage tank during horizontal drainage; stability between two layers of a same supercritical fluid; numerical modeling of the heat transfer inside a stainless steel slab. (J.S.)

  6. Gas hydrate and humans

    Science.gov (United States)

    Kvenvolden, K.A.

    2000-01-01

    The potential effects of naturally occurring gas hydrate on humans are not understood with certainty, but enough information has been acquired over the past 30 years to make preliminary assessments possible. Three major issues are gas hydrate as (1) a potential energy resource, (2) a factor in global climate change, and (3) a submarine geohazard. The methane content is estimated to be between 1015 to 1017 m3 at STP and the worldwide distribution in outer continental margins of oceans and in polar regions are significant features of gas hydrate. However, its immediate development as an energy resource is not likely because there are various geological constraints and difficult technological problems that must be solved before economic recovery of methane from hydrate can be achieved. The role of gas hydrate in global climate change is uncertain. For hydrate methane to be an effective greenhouse gas, it must reach the atmosphere. Yet there are many obstacles to the transfer of methane from hydrate to the atmosphere. Rates of gas hydrate dissociation and the integrated rates of release and destruction of the methane in the geo/hydro/atmosphere are not adequately understood. Gas hydrate as a submarine geohazard, however, is of immediate and increasing importance to humans as our industrial society moves to exploit seabed resources at ever-greater depths in the waters of our coastal oceans. Human activities and installations in regions of gas-hydrate occurrence must take into account the presence of gas hydrate and deal with the consequences of its presence.

  7. Heat Transfer and Cooling in Gas Turbines

    Science.gov (United States)

    1985-09-01

    des gradients longitudinaux et transversaux - effacement des sillages provenant de l’amont. Le tableau ci-dessous traduit on temp~rature de ...aubes et des pointe vta~a our V’aube, . La figure 4 donne tin oscillograaae reprisentgnt le champ des luminances eu bord de fuits de quelquen aubeo...temips de r4t)onse. .𔃿. • i A: Fig. 3 PyrolrMVP opfiqiie povr ta Mee des tetiIraiti it wrface suralabt, Fig. 4 - ftelevd des luminan,

  8. Facility Configuration Study of the High Temperature Gas-Cooled Reactor Component Test Facility

    Energy Technology Data Exchange (ETDEWEB)

    S. L. Austad; L. E. Guillen; D. S. Ferguson; B. L. Blakely; D. M. Pace; D. Lopez; J. D. Zolynski; B. L. Cowley; V. J. Balls; E.A. Harvego, P.E.; C.W. McKnight, P.E.; R.S. Stewart; B.D. Christensen

    2008-04-01

    A test facility, referred to as the High Temperature Gas-Cooled Reactor Component Test Facility or CTF, will be sited at Idaho National Laboratory for the purposes of supporting development of high temperature gas thermal-hydraulic technologies (helium, helium-Nitrogen, CO2, etc.) as applied in heat transport and heat transfer applications in High Temperature Gas-Cooled Reactors. Such applications include, but are not limited to: primary coolant; secondary coolant; intermediate, secondary, and tertiary heat transfer; and demonstration of processes requiring high temperatures such as hydrogen production. The facility will initially support completion of the Next Generation Nuclear Plant. It will secondarily be open for use by the full range of suppliers, end-users, facilitators, government laboratories, and others in the domestic and international community supporting the development and application of High Temperature Gas-Cooled Reactor technology. This pre-conceptual facility configuration study, which forms the basis for a cost estimate to support CTF scoping and planning, accomplishes the following objectives: • Identifies pre-conceptual design requirements • Develops test loop equipment schematics and layout • Identifies space allocations for each of the facility functions, as required • Develops a pre-conceptual site layout including transportation, parking and support structures, and railway systems • Identifies pre-conceptual utility and support system needs • Establishes pre-conceptual electrical one-line drawings and schedule for development of power needs.

  9. Nonlinear analysis of thermal stresses of a of first stage nozzle of a gas turbine at full load from the results of an analysis of conjugated heat transference; Analisis no lineal de esfuerzos termicos de una tobera de primera etapa de turbina de gas a plena carga a partir de resultados de un analisis de transferencia de calor conjugado

    Energy Technology Data Exchange (ETDEWEB)

    Perez Hernandez, Efrain [Centro Nacional de Investigacion y Desarrollo Tecnologico (Cenidet), Cuernavaca, Morelos (Mexico); Mazur C, Zdzislaw; Garcia Illescas, R; Hernandez Rossette, Alejandro [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)

    2007-11-15

    The gas turbines operate at extremely high temperatures, at high thermal and mechanical stresses, causing that the useful life of the involved components be reduced. In the present article the results realized by previous investigations of temperatures obtained from analysis of heat transfer and flow of fluids of the nozzle by means of the Star-CD program based on finite volumes is presented. Later, the NISA program of finite elements was used to realize the analysis of thermal stresses considering the material plasticity. The methodology employed to determine the material properties variable with the temperature of the super-alloy FSX-414 and the plasticity model used in the structural analysis in the finite element program. The result will be later used in the fatigue analysis for the useful life assessment. [Spanish] Las turbinas de gas operan a temperatura extremadamente altas, a elevados esfuerzos termicos y mecanicos, ocasionando que la vida de los componentes involucrados se reduzca. En el presente articulo se presentan los resultados realizados por previas investigaciones de temperaturas obtenidas a partir de analisis de transferencia de calor y flujo de fluidos de la tobera mediante el programa Star-CD basado en volumenes finitos. Posteriormente, se utilizo el programa NISA de elementos finitos para realizar el analisis de esfuerzos termicos considerando plasticidad del material. Se muestra la metodologia empleada para determinar las propiedades del material variables con la temperatura de la superaleacion FSX-414 y el modelo de plasticidad utilizado en el analisis estructural en el programa de elemento finito. Los resultados seran empleados posteriormente en el analisis de fatiga para la estimacion de vida util.

  10. Hanford Site Secondary Waste Roadmap

    Energy Technology Data Exchange (ETDEWEB)

    Westsik, Joseph H.

    2009-01-29

    Summary The U.S. Department of Energy (DOE) is making plans to dispose of 54 million gallons of radioactive tank wastes at the Hanford Site near Richland, Washington. The high-level wastes and low-activity wastes will be vitrified and placed in permanent disposal sites. Processing of the tank wastes will generate secondary wastes, including routine solid wastes and liquid process effluents, and these need to be processed and disposed of also. The Department of Energy Office of Waste Processing sponsored a meeting to develop a roadmap to outline the steps necessary to design the secondary waste forms. Representatives from DOE, the U.S. Environmental Protection Agency, the Washington State Department of Ecology, the Oregon Department of Energy, Nuclear Regulatory Commission, technical experts from the DOE national laboratories, academia, and private consultants convened in Richland, Washington, during the week of July 21-23, 2008, to participate in a workshop to identify the risks and uncertainties associated with the treatment and disposal of the secondary wastes and to develop a roadmap for addressing those risks and uncertainties. This report describes the results of the roadmap meeting in Richland. Processing of the tank wastes will generate secondary wastes, including routine solid wastes and liquid process effluents. The secondary waste roadmap workshop focused on the waste streams that contained the largest fractions of the 129I and 99Tc that the Integrated Disposal Facility risk assessment analyses were showing to have the largest contribution to the estimated IDF disposal impacts to groundwater. Thus, the roadmapping effort was to focus on the scrubber/off-gas treatment liquids with 99Tc to be sent to the Effluent Treatment Facility for treatment and solidification and the silver mordenite and carbon beds with the captured 129I to be packaged and sent to the IDF. At the highest level, the secondary waste roadmap includes elements addressing regulatory and

  11. Station Transfers

    Data.gov (United States)

    Department of Homeland Security — ixed rail transit external system transfers for systems within the Continental United States, Alaska, Hawaii, the District of Columbia, and Puerto Rico. The modes of...

  12. 微通道内气-液弹状流动及传质特性研究进展 (Review on flow and mass transfer characteristics of gas-liquid slug flow in microchannels)

    NARCIS (Netherlands)

    Yao, Chaoqun; Yue, Jun; Zhao, Yuchao; Chen, Guangwen; Yuan, Quan

    2015-01-01

    Gas-liquid slug flow (also termed as Taylor flow) is a flow pattern characterized by the alternate movement of elongated bubbles and liquid slugs. Gas-liquid slug flow operation in microchannels has been found important implications in the enhancement of gas-liquid reactions due to its advantages

  13. Radical Generation from the Gas-Phase Activation of Ionized Lipid Ozonides

    Science.gov (United States)

    Ellis, Shane R.; Pham, Huong T.; in het Panhuis, Marc; Trevitt, Adam J.; Mitchell, Todd W.; Blanksby, Stephen J.

    2017-07-01

    Reaction products from the ozonolysis of unsaturated lipids at gas-liquid interfaces have the potential to significantly influence the chemical and physical properties of organic aerosols in the atmosphere. In this study, the gas-phase dissociation behavior of lipid secondary ozonides is investigated using ion-trap mass spectrometry. Secondary ozonides were formed by reaction between a thin film of unsaturated lipids (fatty acid methyl esters or phospholipids) with ozone before being transferred to the gas phase as [M + Na]+ ions by electrospray ionization. Activation of the ionized ozonides was performed by either energetic collisions with helium buffer-gas or laser photolysis, with both processes yielding similar product distributions. Products arising from the decomposition of the ozonides were characterized by their mass-to-charge ratio and subsequent ion-molecule reactions. Product assignments were rationalized as arising from initial homolysis of the ozonide oxygen-oxygen bond with subsequent decomposition of the nascent biradical intermediate. In addition to classic aldehyde and carbonyl oxide-type fragments, carbon-centered radicals were identified with a number of decomposition pathways that indicated facile unimolecular radical migration. These findings reveal that photoactivation of secondary ozonides formed by the reaction of aerosol-bound lipids with tropospheric ozone may initiate radical-mediated chemistry within the particle resulting in surface modification.

  14. Storage and transmission of secondary energy

    International Nuclear Information System (INIS)

    Taube, M.

    1979-09-01

    In the area of the total energy flow, possibilities and limits of shifts in time (storage) and in space (transfer) of secondary energy, i.e. electrical, chemical and thermal energy are examined and formulated. These shifts are linked to the qualitative conversions of secondary energy. The multiple technological possibilities, the spectrum of governing factors and the numerous technical and economical parameters show that only a complex optimization is possible. (Auth.)

  15. Simple setup for gas-phase h/d exchange mass spectrometry coupled to electron transfer dissociation and ion mobility for analysis of polypeptide structure on a liquid chromatographic time scale

    DEFF Research Database (Denmark)

    Mistarz, Ulrik Hvid; Brown, Jeffery M; Haselmann, Kim F

    2014-01-01

    Gas-phase hydrogen/deuterium exchange (HDX) is a fast and sensitive, yet unharnessed analytical approach for providing information on the structural properties of biomolecules, in a complementary manner to mass analysis. Here, we describe a simple setup for ND3-mediated millisecond gas-phase HDX...... gas immediately upstream or downstream of the primary skimmer cone. The approach was implemented on three commercially available mass spectrometers and required no or minor fully reversible reconfiguration of gas-inlets of the ion source. Results from gas-phase HDX-MS of peptides using the aqueous ND3...

  16. Secondary organic aerosol formation and transport

    Science.gov (United States)

    Pandis, Spyros N.; Harley, Robert A.; Cass, Glen R.; Seinfeld, John H.

    A Lagrangian trajectory model simulating the formation, transport and deposition of secondary organic aerosol is developed and applied to the Los Angeles area, for the air pollution episode of 27-28 August 1987. The predicted secondary organic aerosol on 28 August 1987 represents 15-22% of the measured particulate organic carbon at inland locations in the base case simulations, and 5-8% of that at coastal locations. A maximum secondary organic aerosol concentration of 6.8 μg m -3 is predicted for Claremont, CA, during this episode. On a daily average basis at Claremont about 46% of this secondary organic aerosol is predicted to be a result of the oxidation of non-toluene aromatics (xylenes, alkylbenzenes, etc.), 19% from toluene, 16% from biogenic hydrocarbons (α-pinene, ß-pinene, etc.), 15% from alkanes and 4% from alkenes. The major uncertainties in predicting secondary organic aerosol concentrations are the reactive organic gas emissions, the aerosol yields and the partitioning of the condensable gases between the two phases. Doubling the reactive organic gas (ROG) emissions results in an increase of the secondary organic aerosol predicted at Claremont by a factor of 2.3. Predicted secondary organic aerosol levels are less sensitive to changes in secondary organic aerosol deposition and NO x emissions than to ROG emissions.

  17. Paralysis: Secondary Conditions

    Science.gov (United States)

    ... 5pm ET. 1-800-539-7309 ☰ Living with Paralysis Get Support Get Involved Research Events Blog & Forum About Us Donate Living with Paralysis > Health > Secondary conditions Secondary conditions Secondary conditions refer ...

  18. Mass Transfer Method and Apparatus

    DEFF Research Database (Denmark)

    1995-01-01

    .g. polytetrafluoroethylene (PTFE, Teflon $m(3)) membranes, in the form of hollow fibres having gas-containing pores and contacting the second fluid with the inner surface of the membranes. Useful membranes are characterized in that they e.g. have a porosity ($g(e)) of at least 0.50, a mass transfer coefficient of e...

  19. Proton transfer and complex formation of angiotensin I ions with gaseous molecules at various temperature

    Energy Technology Data Exchange (ETDEWEB)

    Nonose, Shinji, E-mail: nonose@yokohama-cu.ac.jp; Yamashita, Kazuki; Sudo, Ayako; Kawashima, Minami

    2013-09-23

    Highlights: • Proton transfer from angiotensin I ions (z = 2, 3) to gaseous molecules was studied. • Temperature dependence of absolute reaction rate constants was measured. • Remarkable changes were obtained for distribution of product ions and reaction rate constants. • Proton transfer reaction was enhanced and reduced by complex formation. • Conformation changes are induced by complex formation and or by thermal collision with He. - Abstract: Proton transfer reactions of angiotensin I ions for +2 charge state, [M + 2H]{sup 2+}, to primary, secondary and aromatic amines were examined in the gas phase. Absolute reaction rate constants for proton transfer were determined from intensities of parent and product ions in the mass spectra. Temperature dependence of the reaction rate constants was measured. Remarkable change was observed for distribution of product ions and reaction rate constants. Proton transfer reaction was enhanced or reduced by complex formation of [M + 2H]{sup 2+} with gaseous molecules. The results relate to conformation changes of [M + 2H]{sup 2+} with change of temperature, which are induced by complex formation and or by thermal collision with He. Proton transfer reactions of angiotensin I ions for +3 charge state, [M + 3H]{sup 3+}, were also studied. The reaction rates did not depend on temperature so definitely.

  20. Proton transfer and complex formation of angiotensin I ions with gaseous molecules at various temperature

    International Nuclear Information System (INIS)

    Nonose, Shinji; Yamashita, Kazuki; Sudo, Ayako; Kawashima, Minami

    2013-01-01

    Highlights: • Proton transfer from angiotensin I ions (z = 2, 3) to gaseous molecules was studied. • Temperature dependence of absolute reaction rate constants was measured. • Remarkable changes were obtained for distribution of product ions and reaction rate constants. • Proton transfer reaction was enhanced and reduced by complex formation. • Conformation changes are induced by complex formation and or by thermal collision with He. - Abstract: Proton transfer reactions of angiotensin I ions for +2 charge state, [M + 2H] 2+ , to primary, secondary and aromatic amines were examined in the gas phase. Absolute reaction rate constants for proton transfer were determined from intensities of parent and product ions in the mass spectra. Temperature dependence of the reaction rate constants was measured. Remarkable change was observed for distribution of product ions and reaction rate constants. Proton transfer reaction was enhanced or reduced by complex formation of [M + 2H] 2+ with gaseous molecules. The results relate to conformation changes of [M + 2H] 2+ with change of temperature, which are induced by complex formation and or by thermal collision with He. Proton transfer reactions of angiotensin I ions for +3 charge state, [M + 3H] 3+ , were also studied. The reaction rates did not depend on temperature so definitely

  1. Elements of heat transfer

    CERN Document Server

    Rathakrishnan, Ethirajan

    2012-01-01

    1 Basic Concepts and Definitions1.1 Introduction1.1.1 Driving Potential1.2 Dimensions and Units1.2.1 Dimensional Homogeneity1.3 Closed and Open Systems1.3.1 Closed System (ControlMass)1.3.2 Isolated System1.3.3 Open System (ControlVolume)1.4 Forms of Energy1.4.1 Internal Energy1.5 Properties of a System1.5.1 Intensive and Extensive Properties1.6 State and Equilibrium1.7 Thermal and Calorical Properties1.7.1 Specific Heat of an Incompressible Substance1.7.2 Thermally Perfect Gas 1.8 The Perfect Gas1.9 Summary1.10 Exercise ProblemsConduction Heat Transfer2.1 Introduction2.2 Conduction Heat Trans

  2. Effects of Chamber Pressure and Partial Pressure of Water Vapor on Secondary Drying in Lyophilization.

    Science.gov (United States)

    Searles, James A; Aravapalli, Sridhar; Hodge, Cody

    2017-10-01

    Secondary drying is the final step of lyophilization before stoppering, during which water is desorbed from the product to yield the final moisture content. We studied how chamber pressure and partial pressure of water vapor during this step affected the time course of water content of aqueous solutions of polyvinylpyrrolidone (PVP) in glass vials. The total chamber pressure had no effect when the partial pressure of water vapor was very low. However, when the vapor phase contained a substantial fraction of water vapor, the PVP moisture content was much higher. We carried out dynamic vapor sorption experiments (DVS) to demonstrate that the higher PVP moisture content was a straightforward result of the higher water vapor content in the lyophilizer. The results highlight that the partial pressure of water vapor is extremely important during secondary drying in lyophilization, and that lower chamber pressure set points for secondary drying may sometimes be justified as a strategy for ensuring low partial pressure of water vapor, especially for lyophilizers that do not inject dry gas to control pressure. These findings have direct application for process transfers/scale ups from freeze-dryers that do not inject dry gas for pressure control to those that do, and vice versa.

  3. Technology Transfer

    Science.gov (United States)

    Smith, Nanette R.

    1995-01-01

    The objective of this summer's work was to attempt to enhance Technology Application Group (TAG) ability to measure the outcomes of its efforts to transfer NASA technology. By reviewing existing literature, by explaining the economic principles involved in evaluating the economic impact of technology transfer, and by investigating the LaRC processes our William & Mary team has been able to lead this important discussion. In reviewing the existing literature, we identified many of the metrics that are currently being used in the area of technology transfer. Learning about the LaRC technology transfer processes and the metrics currently used to track the transfer process enabled us to compare other R&D facilities to LaRC. We discuss and diagram impacts of technology transfer in the short run and the long run. Significantly, it serves as the basis for analysis and provides guidance in thinking about what the measurement objectives ought to be. By focusing on the SBIR Program, valuable information regarding the strengths and weaknesses of this LaRC program are to be gained. A survey was developed to ask probing questions regarding SBIR contractors' experience with the program. Specifically we are interested in finding out whether the SBIR Program is accomplishing its mission, if the SBIR companies are providing the needed innovations specified by NASA and to what extent those innovations have led to commercial success. We also developed a survey to ask COTR's, who are NASA employees acting as technical advisors to the SBIR contractors, the same type of questions, evaluating the successes and problems with the SBIR Program as they see it. This survey was developed to be implemented interactively on computer. It is our hope that the statistical and econometric studies that can be done on the data collected from all of these sources will provide insight regarding the direction to take in developing systematic evaluations of programs like the SBIR Program so that they can

  4. Gas Sensor

    KAUST Repository

    Luebke, Ryan

    2015-01-22

    A gas sensor using a metal organic framework material can be fully integrated with related circuitry on a single substrate. In an on-chip application, the gas sensor can result in an area-efficient fully integrated gas sensor solution. In one aspect, a gas sensor can include a first gas sensing region including a first pair of electrodes, and a first gas sensitive material proximate to the first pair of electrodes, wherein the first gas sensitive material includes a first metal organic framework material.

  5. Gas Hydrate Storage of Natural Gas

    Energy Technology Data Exchange (ETDEWEB)

    Rudy Rogers; John Etheridge

    2006-03-31

    lower heat transfer rate in the internal heat exchanger than was designed. It is believed that the fins on the heat-exchanger tubes did not make proper contact with the tubes transporting the chilled glycol, and pairs of fins were too close for interior areas of fins to serve as hydrate collection sites. A correction of the fabrication fault in the heat exchanger fin attachments could be easily made to provide faster formation rates. The storage success with the POC process provides valuable information for making the process an economically viable process for safe, aboveground natural-gas storage.

  6. Fundamentals of gas particle flow

    CERN Document Server

    Rudinger, G

    1980-01-01

    Fundamentals of Gas-Particle Flow is an edited, updated, and expanded version of a number of lectures presented on the "Gas-Solid Suspensions” course organized by the von Karman Institute for Fluid Dynamics. Materials presented in this book are mostly analytical in nature, but some experimental techniques are included. The book focuses on relaxation processes, including the viscous drag of single particles, drag in gas-particles flow, gas-particle heat transfer, equilibrium, and frozen flow. It also discusses the dynamics of single particles, such as particles in an arbitrary flow, in a r

  7. Visualization of gas dissolution following upward gas migration in porous media: Technique and implications for stray gas

    Science.gov (United States)

    Van De Ven, C. J. C.; Mumford, Kevin G.

    2018-05-01

    The study of gas-water mass transfer in porous media is important in many applications, including unconventional resource extraction, carbon storage, deep geological waste storage, and remediation of contaminated groundwater, all of which rely on an understanding of the fate and transport of free and dissolved gas. The novel visual technique developed in this study provided both quantitative and qualitative observations of gas-water mass transfer. Findings included interaction between free gas architecture and dissolved plume migration, plume geometry and longevity. The technique was applied to the injection of CO2 in source patterns expected for stray gas originating from oil and gas operations to measure dissolved phase concentrations of CO2 at high spatial and temporal resolutions. The data set is the first of its kind to provide high resolution quantification of gas-water dissolution, and will facilitate an improved understanding of the fundamental processes of gas movement and fate in these complex systems.

  8. Technology transfer

    International Nuclear Information System (INIS)

    Boury, C.

    1986-01-01

    This paper emphasizes in the specific areas of design, engineering and component production. This paper presents what Framatome has to offer in these areas and its export oriented philosophy. Then, a typical example of this technology transfer philosophy is the collaboration with the South Korean firm, Korea Heavy Industries Corporation (KHIC) for the supply of KNU 9 and KNU 10 power stations

  9. Modeling microscale heat transfer using Calore

    International Nuclear Information System (INIS)

    Gallis, Michail A.; Rader, Daniel John; Wong, Chung-Nin Channy; Bainbridge, Bruce L.; Torczynski, John Robert; Piekos, Edward Stanley

    2005-01-01

    Modeling microscale heat transfer with the computational-heat-transfer code Calore is discussed. Microscale heat transfer problems differ from their macroscopic counterparts in that conductive heat transfer in both solid and gaseous materials may have important noncontinuum effects. In a solid material, three noncontinuum effects are considered: ballistic transport of phonons across a thin film, scattering of phonons from surface roughness at a gas-solid interface, and scattering of phonons from grain boundaries within the solid material. These processes are modeled for polycrystalline silicon, and the thermal-conductivity values predicted by these models are compared to experimental data. In a gaseous material, two noncontinuum effects are considered: ballistic transport of gas molecules across a thin gap and accommodation of gas molecules to solid conditions when reflecting from a solid surface. These processes are modeled for arbitrary gases by allowing the gas and solid temperatures across a gas-solid interface to differ: a finite heat transfer coefficient (contact conductance) is imposed at the gas-solid interface so that the temperature difference is proportional to the normal heat flux. In this approach, the behavior of gas in the bulk is not changed from behavior observed under macroscopic conditions. These models are implemented in Calore as user subroutines. The user subroutines reside within Sandia's Source Forge server, where they undergo version control and regression testing and are available to analysts needing these capabilities. A Calore simulation is presented that exercises these models for a heated microbeam separated from an ambient-temperature substrate by a thin gas-filled gap. Failure to use the noncontinuum heat transfer models for the solid and the gas causes the maximum temperature of the microbeam to be significantly underpredicted

  10. Modeling microscale heat transfer using Calore.

    Energy Technology Data Exchange (ETDEWEB)

    Gallis, Michail A.; Rader, Daniel John; Wong, Chung-Nin Channy; Bainbridge, Bruce L.; Torczynski, John Robert; Piekos, Edward Stanley

    2005-09-01

    Modeling microscale heat transfer with the computational-heat-transfer code Calore is discussed. Microscale heat transfer problems differ from their macroscopic counterparts in that conductive heat transfer in both solid and gaseous materials may have important noncontinuum effects. In a solid material, three noncontinuum effects are considered: ballistic transport of phonons across a thin film, scattering of phonons from surface roughness at a gas-solid interface, and scattering of phonons from grain boundaries within the solid material. These processes are modeled for polycrystalline silicon, and the thermal-conductivity values predicted by these models are compared to experimental data. In a gaseous material, two noncontinuum effects are considered: ballistic transport of gas molecules across a thin gap and accommodation of gas molecules to solid conditions when reflecting from a solid surface. These processes are modeled for arbitrary gases by allowing the gas and solid temperatures across a gas-solid interface to differ: a finite heat transfer coefficient (contact conductance) is imposed at the gas-solid interface so that the temperature difference is proportional to the normal heat flux. In this approach, the behavior of gas in the bulk is not changed from behavior observed under macroscopic conditions. These models are implemented in Calore as user subroutines. The user subroutines reside within Sandia's Source Forge server, where they undergo version control and regression testing and are available to analysts needing these capabilities. A Calore simulation is presented that exercises these models for a heated microbeam separated from an ambient-temperature substrate by a thin gas-filled gap. Failure to use the noncontinuum heat transfer models for the solid and the gas causes the maximum temperature of the microbeam to be significantly underpredicted.

  11. Experimental studies on thermohydraulics in packed beds in a comparison to computer program THERMIX-2D: the examination of dispersive heat transfer using a cold gas stream as an example

    International Nuclear Information System (INIS)

    Schuerenkraemer, M.; Barthels, H.

    1985-01-01

    The computer program THERMIX-2D is being examined with regard to the expression for effective thermal conductivity with predominantly dispersive fraction as compared to the experimental data. A locally introduced cold gas stream (strand) is superposed on a stationary hot gas stream within a steel ball packing, and the thermal compensating processes are measured and computed. 12 refs., 16 figs., 2 tabs

  12. Carbon monoxide transfer in pig lungs during mechanical ventilation

    NARCIS (Netherlands)

    F.C.A.M. te Nijenhuis (Frances)

    1996-01-01

    textabstractThis thesis comprises studies of gas transfer in the lungs during mechanical ventilation, which have been obtained in healthy pigs. The objectives of this thesis were: I) to adapt the breath-holding teclmique, as used during spontaneous breathing for estimation of gas transfer, to

  13. Heat transfer system

    International Nuclear Information System (INIS)

    McGuire, J.C.

    1983-01-01

    An intermediate heat exchanger that provides the required physical isolation between the primary reactor coolant loops and a secondary liquid loop in which steam is generated was developed. The intermediate heat exchanger is contained within a sealed vapor chamber that includes a bottom interior portion and an adjacent upper interior portion in vertical communication with one another. The chamber is exhausted of all noncondensible gases at ambient temperature. A heat transfer medium within the chamber maintains a two phase liquid-vapor-liquid system at the design heat transfer temperature. A first set of tubes in the bottom portion of the vapor chamber is supplied with primary reactor coolant. A second set of tubes in the upper portion of the chamber is supplied with water or steam. A thermal linkage is provided between the two sets of tubes by the heat transfer medium, which is evaporated in the vicinity of the first set and is condensed in the vicinity of the second set. This results in a latent heat transport system, condensate return being accomplished by gravity

  14. 17 CFR 229.1204 - (Item 1204) Oil and gas production, production prices and production costs.

    Science.gov (United States)

    2010-04-01

    ... price (including transfers) per unit of oil, gas and other products produced; and (2) The average... conversion to synthetic oil or gas, the product's production, transfer prices, and production costs should be disclosed separately from all other products. Instruction 4 to Item 1204: The transfer price of oil and gas...

  15. senior secondary students' performance in selectd aspects

    African Journals Online (AJOL)

    Temechegn

    Rivers State University of Science & Technology, Port Harcourt, Nigeria. Email: mcsahia@yahoo.com. ABSTRACT. The purpose of the study was to investigate students' performance in chemical calculations involving gas equation, mole concept and chemical equations. 100 Senior Secondary. (SS) students from 10 schools ...

  16. A Study on the Mixed Convection Heat Transfer in a Vertical Cylinder Using Electroplating System

    International Nuclear Information System (INIS)

    Ko, Bong Jin

    2008-02-01

    Hydrogen economy has drawn public attentions as a promising future energy source. Hydrogen is a non-petroleum-based, non-toxic, renewable and clean burning energy source. Hydrogen is the secondary energy, which means that it is produced by consuming the first energy such as coal, gas, petroleum etc. This again means that it is clean so long as it is produced by clean methods. One of the promising production methods of hydrogen is to use the heat from an HTGR(High Temperature Gas-cooled Reactor), a next generation nuclear reactor for a safe and reliable operation as well as for efficient and economic generation of energy. The knowledge of detailed heat transfer phenomena in gaseous phase emerges as an important factor for HTGR, where buoyancy effect plays a significant role. Large and expensive test facilities are to be constructed to assess the detailed mixed convection phenomena. However, using analogy concept, heat transfer system can be transformed to mass transfer system and vice versa. If a simple mass transfer system could be devised, and the experimental solution from that system could be obtained, then this could theoretically lead to a solution for a similar heat transfer system. In this study, a copper electroplating system was selected as the mass transfer system. A copper electroplating system with limiting current technique has a good advantage to simulate heat transfer system as mass transfer coefficient, analogous with heat transfer coefficient, can be directly obtained from the information of the bulk concentration and electric current between electrodes. This study simulated the mixed convective heat transfer phenomena in a vertical cylinder using copper electroplating system. The mixed convection phenomenon is observed when the forced and natural convections are of comparable magnitudes in one system. The mixed convection is classified as laminar and turbulent flows depending on the exchange mechanism and also as buoyancy aided and buoyancy

  17. Technology transfer

    International Nuclear Information System (INIS)

    Anon.

    1977-01-01

    Illustrated by the example of the FRG's nuclear energy exports, it is shown that the nuclear technology transfer leads to new dimensions of intergovernmental relations, which hold within themselves on account of multiple state-to-state, scientific, industrial and - last but not least - personal contacts the chance of far-reaching friendships between countries and people. If the chance is taken, this can also be seen as an important contribution towards maintaining the peace. (orig.) [de

  18. Anatomy Transfer

    OpenAIRE

    Dicko, Ali Hamadi; Liu, Tiantian; Gilles, Benjamin; Kavan, Ladislav; Faure, François; Palombi, Olivier; Cani, Marie-Paule

    2013-01-01

    International audience; Characters with precise internal anatomy are important in film and visual effects, as well as in medical applications. We propose the first semi-automatic method for creating anatomical structures, such as bones, muscles, viscera and fat tissues. This is done by transferring a reference anatomical model from an input template to an arbitrary target character, only defined by its boundary representation (skin). The fat distribution of the target character needs to be sp...

  19. Transfer Zymography.

    Science.gov (United States)

    Pan, Daniel; Wilson, Karl A; Tan-Wilson, Anna

    2017-01-01

    The technique described here, transfer zymography, was developed to overcome two limitations of conventional zymography. When proteolytic enzymes are resolved by nonreducing SDS-PAGE into a polyacrylamide gel with copolymerized protein substrate, the presence of the protein substrate can result in anomalous, often slower, migration of the protease and an estimated mass higher than its actual mass. A further drawback is that the presence of a high background of substrate protein interferes with proteomic analysis of the protease band by excision, tryptic digestion, and LC-MS/MS analysis. In transfer zymography, the proteolytic enzymes are resolved by conventional nonreducing SDS-PAGE, without protein substrate in the gel. The proteins in the resolving gel are then electrophoretically transferred to a receiving gel that contains the protein substrate, by a process similar to western blotting. The receiving gel is then processed in a manner similar to conventional zymography. SDS is removed by Triton X-100 and incubated in conditions suitable for the proteolytic activity. After protein staining, followed by destaining, bands representing regions with active protease are visualized as clear bands in a darkly stained background. For proteomic analysis, electrophoresis is carried out simultaneously on a second resolving gel, and the bands corresponding to the clear regions in the receiving gel after zymogram development are excised for proteomic analysis.

  20. Gas gangrene

    Science.gov (United States)

    Tissue infection - Clostridial; Gangrene - gas; Myonecrosis; Clostridial infection of tissues; Necrotizing soft tissue infection ... Gas gangrene is most often caused by bacteria called Clostridium perfringens. It also can be caused by ...

  1. Laser induced energy transfer

    International Nuclear Information System (INIS)

    Falcone, R.W.

    1979-01-01

    Two related methods of rapidly transferring stored energy from one excited chemical species to another are described. The first of these, called a laser induced collision, involves a reaction in which the energy balance is met by photons from an intense laser beam. A collision cross section of ca 10 - 17 cm 2 was induced in an experiment which demonstrated the predicted dependence of the cross section on wavelength and power density of the applied laser. A second type of laser induced energy transfer involves the inelastic scattering of laser radiation from energetically excited atoms, and subsequent absorption of the scattered light by a second species. The technique of producing the light, ''anti-Stokes Raman'' scattering of visible and infrared wavelength laser photons, is shown to be an efficient source of narrow bandwidth, high brightness, tunable radiation at vacuum ultraviolet wavelengths by using it to excite a rare gas transition at 583.7 A. In addition, this light source was used to make the first measurement of the isotopic shift of the helium metastable level at 601 A. Applications in laser controlled chemistry and spectroscopy, and proposals for new types of lasers using these two energy transfer methods are discussed

  2. Gas separating

    Science.gov (United States)

    Gollan, Arye Z.

    1990-12-25

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing.

  3. Gas treating absorption theory and practice

    CERN Document Server

    Eimer, Dag

    2014-01-01

    Gas Treating: Absorption Theory and Practice provides an introduction to the treatment of natural gas, synthesis gas and flue gas, addressing why it is necessary and the challenges involved.  The book concentrates in particular on the absorption-desorption process and mass transfer coupled with chemical reaction. Following a general introduction to gas treatment, the chemistry of CO2, H2S and amine systems is described, and selected topics from physical chemistry with relevance to gas treating are presented. Thereafter the absorption process is discussed in detail, column hardware is explain

  4. Bed-To-Wall Heat Transfer in a Supercritical Circulating Fluidised Bed Boiler

    Directory of Open Access Journals (Sweden)

    Błaszczuk Artur

    2014-06-01

    Full Text Available The purpose of this work is to find a correlation for heat transfer to walls in a 1296 t/h supercritical circulating fluidised bed (CFB boiler. The effect of bed-to-wall heat transfer coefficient in a long active heat transfer surface was discussed, excluding the radiation component. Experiments for four different unit loads (i.e. 100% MCR, 80% MCR, 60% MCR and 40% MCR were conducted at a constant excess air ratio and high level of bed pressure (ca. 6 kPa in each test run. The empirical correlation of the heat transfer coefficient in a large-scale CFB boiler was mainly determined by two key operating parameters, suspension density and bed temperature. Furthermore, data processing was used in order to develop empirical correlation ranges between 3.05 to 5.35 m·s-1 for gas superficial velocity, 0.25 to 0.51 for the ratio of the secondary to the primary air, 1028 to 1137K for bed temperature inside the furnace chamber of a commercial CFB boiler, and 1.20 to 553 kg·m-3 for suspension density. The suspension density was specified on the base of pressure measurements inside the boiler’s combustion chamber using pressure sensors. Pressure measurements were collected at the measuring ports situated on the front wall of the combustion chamber. The obtained correlation of the heat transfer coefficient is in agreement with the data obtained from typical industrial CFB boilers.

  5. Ruslands Gas

    OpenAIRE

    Elkjær, Jonas Bondegaard

    2008-01-01

    This paper is about Russian natural gas and the possibility for Russia to use its reserves of natural gas politically towards the European Union to obtain some political power. Russia owns 32,1 % of the world gas reserves, and The European Union is getting 50 % of its gas import from Russia. I will use John Mearsheimer’s theory ”The Tragedy of Great Power Politics” to explain how Russia can use its big reserves of gas on The European Union to get political influence. This paper is about Ru...

  6. Ruslands Gas

    OpenAIRE

    Elkjær, Jonas Bondegaard

    2008-01-01

    This paper is about Russian natural gas and the possibility for Russia to use its reserves of natural gas politically towards the European Union to obtain some political power. Russia owns 32,1 % of the world gas reserves, and The European Union is getting 50 % of its gas import from Russia. I will use John Mearsheimer’s theory ”The Tragedy of Great Power Politics” to explain how Russia can use its big reserves of gas on The European Union to get political influence.

  7. Harnessing gas

    International Nuclear Information System (INIS)

    1998-01-01

    Nigeria produces almost two million barrels of oil a day from its oil fields in the Niger Delta area. Most of the oil comes from reservoirs containing gas, which is produced with the oil. This associated gas is separated from the oil at flow stations and more than 95 per cent of it is flared-currently a total of some two billion standard cubic feet per day (scf/d), which is estimated to be about a quarter of the gas the world flares and vents. The energy available from Nigeria's flared gas is prodigious, equivalent to one quarter of France's gas requirements. The company recognises that flaring wastes a valuable resource and is environmentally damaging. It aims to stop necessary flaring as soon as possible through a series of projects to harness or conserve this gas. Several gas gathering and conservation projects are already underway in response to emerging markets while other plans await new markets. The company is committed to reduce gas flaring as soon as is feasible to the minimum needed to maintain safe operations. But why are solutions being found only now? why has Nigeria been flaring gas for so long? These question lie at the crux of the debate about Nigeria and gas flaring and the answers, which continue to have a major impact on associated gas development today, are rooted in history, economics and geography

  8. Gas Storage Technology Consortium

    Energy Technology Data Exchange (ETDEWEB)

    Joel Morrison; Elizabeth Wood; Barbara Robuck

    2010-09-30

    The EMS Energy Institute at The Pennsylvania State University (Penn State) has managed the Gas Storage Technology Consortium (GSTC) since its inception in 2003. The GSTC infrastructure provided a means to accomplish industry-driven research and development designed to enhance the operational flexibility and deliverability of the nation's gas storage system, and provide a cost-effective, safe, and reliable supply of natural gas to meet domestic demand. The GSTC received base funding from the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL) Oil & Natural Gas Supply Program. The GSTC base funds were highly leveraged with industry funding for individual projects. Since its inception, the GSTC has engaged 67 members. The GSTC membership base was diverse, coming from 19 states, the District of Columbia, and Canada. The membership was comprised of natural gas storage field operators, service companies, industry consultants, industry trade organizations, and academia. The GSTC organized and hosted a total of 18 meetings since 2003. Of these, 8 meetings were held to review, discuss, and select proposals submitted for funding consideration. The GSTC reviewed a total of 75 proposals and committed co-funding to support 31 industry-driven projects. The GSTC committed co-funding to 41.3% of the proposals that it received and reviewed. The 31 projects had a total project value of $6,203,071 of which the GSTC committed $3,205,978 in co-funding. The committed GSTC project funding represented an average program cost share of 51.7%. Project applicants provided an average program cost share of 48.3%. In addition to the GSTC co-funding, the consortium provided the domestic natural gas storage industry with a technology transfer and outreach infrastructure. The technology transfer and outreach were conducted by having project mentoring teams and a GSTC website, and by working closely with the Pipeline Research Council International (PRCI) to

  9. Mass transfer apparatus and method for separation of gases

    Energy Technology Data Exchange (ETDEWEB)

    Blount, Gerald C.; Gorensek, Maximilian Boris; Hamm, Luther L.

    2018-01-16

    A process and apparatus for separating components of a source gas is provided in which more soluble components of the source gas are dissolved in an aqueous solvent at high pressure. The system can utilize hydrostatic pressure to increase solubility of the components of the source gas. The apparatus includes gas recycle throughout multiple mass transfer stages to improve mass transfer of the targeted components from the liquid to gas phase. Separated components can be recovered for use in a value added application or can be processed for long-term storage, for instance in an underwater reservoir.

  10. Deep Sludge Gas Release Event Analytical Evaluation

    International Nuclear Information System (INIS)

    Sams, Terry L.

    2013-01-01

    Long Abstract. Full Text. The purpose of the Deep Sludge Gas Release Event Analytical Evaluation (DSGRE-AE) is to evaluate the postulated hypothesis that a hydrogen GRE may occur in Hanford tanks containing waste sludges at levels greater than previously experienced. There is a need to understand gas retention and release hazards in sludge beds which are 200 -300 inches deep. These sludge beds are deeper than historical Hanford sludge waste beds, and are created when waste is retrieved from older single-shell tanks (SST) and transferred to newer double-shell tanks (DST).Retrieval of waste from SSTs reduces the risk to the environment from leakage or potential leakage of waste into the ground from these tanks. However, the possibility of an energetic event (flammable gas accident) in the retrieval receiver DST is worse than slow leakage. Lines of inquiry, therefore, are (1) can sludge waste be stored safely in deep beds; (2) can gas release events (GRE) be prevented by periodically degassing the sludge (e.g., mixer pump); or (3) does the retrieval strategy need to be altered to limit sludge bed height by retrieving into additional DSTs? The scope of this effort is to provide expert advice on whether or not to move forward with the generation of deep beds of sludge through retrieval of C-Farm tanks. Evaluation of possible mitigation methods (e.g., using mixer pumps to release gas, retrieving into an additional DST) are being evaluated by a second team and are not discussed in this report. While available data and engineering judgment indicate that increased gas retention (retained gas fraction) in DST sludge at depths resulting from the completion of SST 241-C Tank Farm retrievals is not expected and, even if gas releases were to occur, they would be small and local, a positive USQ was declared (Occurrence Report EM-RP--WRPS-TANKFARM-2012-0014, 'Potential Exists for a Large Spontaneous Gas Release Event in Deep Settled Waste Sludge'). The purpose of this technical

  11. Some Metapsychological Considerations about Transference

    Directory of Open Access Journals (Sweden)

    Sergio Guillermo Castellanos-Urrego**

    2009-12-01

    Full Text Available This paper shows a metapsychological re-creation of transference from a conceptualization of representations as the units of psychism. Transferences have their origins in the effort of an unsatisfied libidinal investiture that continues to be active in the Unconscious, and which allows the primary process to inadvertently filter into the secondary process through a “false link”. Therefore, a current perception becomes identified with the expectative representation, which makes the individual believe that this new person will satisfy the aforementioned investiture. Transference neurosis is a psychoanalytic pillar, since only through it may one consciously and currently have access the repressed unconscious drives, a feature of childhood sexuality, and restart the psychosexual development.

  12. Engineering of Secondary Metabolism.

    Science.gov (United States)

    O'Connor, Sarah E

    2015-01-01

    Secondary (specialized) metabolites, produced by bacteria, fungi, plants, and other organisms, exhibit enormous structural variation, and consequently display a wide range of biological activities. Secondary metabolism improves and modulates the phenotype of the host producer. Furthermore, these biological activities have resulted in the use of secondary metabolites in a variety of industrial and pharmaceutical applications. Metabolic engineering presents a powerful strategy to improve access to these valuable molecules. A critical overview of engineering approaches in secondary metabolism is presented, both in heterologous and native hosts. The recognition of the increasing role of compartmentalization in metabolic engineering is highlighted. Engineering approaches to modify the structure of key secondary metabolite classes are also critically evaluated.

  13. One-nucleon transfer reactions induced by secondary beam of {sup 11}Be: study of the nuclear structure of the exotic nuclei {sup 11}Be and {sup 10}Li; Reactions de transfert d'un nucleon induites par un faisceau secondaire de {sup 11}Be: etude de la structure des noyaux exotiques {sup 11}Be et {sup 10}Li

    Energy Technology Data Exchange (ETDEWEB)

    Pita, S

    2000-09-01

    The structure of the neutron rich light nuclei {sup 11}Be and {sup 10}Li has been investigated by means of one nucleon transfer reactions. The experiments have been carried out at GANIL in inverse kinematics using {sup 11}Be secondary beams. The {sup 11}Be(p,d){sup 10}Be reaction bas been studied at 35.3 MeV/u. The {sup 10}Be ejectiles were analyzed by the spectrometer SPEG, and coincident deuterons were detected in the position sensitive silicon detector CHARISSA. Transfer cross sections to 0{sup +}{sub 1} and 2{sup +}{sub 1}, states in {sup 10}Be were measured up to {theta}{sub CM} = 16 deg. and compared to DWBA and CRC predictions. The effects of neutron-cure couplings on reaction form factors have been studied by solving coupled equations in the framework of a vibrational model. It is shown that the rate of core excitation {sup 10}Be{sub 2+} in the {sup 11}Be{sub gs} wave function is overestimated by a standard analysis with form factors given by the usual Separation Energy prescription. The former model predicts a rate of core excitation of 16% and leads to theoretical cross sections which are in good agreement with the experimental data. The aim of the {sup 11}Be(d,{sup 3}He){sup 10}Li experiment, realized at 37 MeV/u, was to measure the distribution of the 2s neutron strength in the unbound nucleus {sup 10}Li. The energy spectrum was deduced from the {sup 3}He energy and angle measured by the silicon strip detector array MUST. An asymmetric peak is clearly observed near the threshold, with a maximum at -S{sub n} = 130 keV. This constitutes a direct proof of the inversion of 2s and 1p{sub 1/2} shells in {sup 10}Li, which was until now a controversial question in spite of many experimental efforts. On the other band the analysis of the {sup 11}Be(d,t){sup 10}Be reaction studied in the same experiment confirms the results obtained in the {sup 11}Be(p,d){sup 10}Be reaction concerning the {sup 11}Be{sub gs} structure. This work shows the interest and feasibility

  14. GAS BEARING

    Science.gov (United States)

    Skarstrom, C.W.

    1960-09-01

    A gas lubricated bearing for a rotating shaft is described. The assembly comprises a stationary collar having an annular member resiliently supported thereon. The collar and annular member are provided with cooperating gas passages arranged for admission of pressurized gas which supports and lubricates a bearing block fixed to the rotatable shaft. The resilient means for the annular member support the latter against movement away from the bearing block when the assembly is in operation.

  15. Requirements for gas quality and gas appliances

    NARCIS (Netherlands)

    Levinsky, Howard; Gersen, Sander; Kiewiet, Bert

    2015-01-01

    Introduction The gas transmission network in the Netherlands transports two different qualities of gas, low-calorific gas known as G-gas or L-gas and, high calorific gas (H-gas). These two gas qualities are transported in separate networks, and are connected by means of five blending and conversion

  16. Heat transfer from rough surfaces

    International Nuclear Information System (INIS)

    Dalle Donne, M.

    1977-01-01

    Artificial roughness is often used in nuclear reactors to improve the thermal performance of the fuel elements. Although these are made up of clusters of rods, the experiments to measure the heat transfer and friction coefficients of roughness are performed with single rods contained in smooth tubes. This work illustrated a new transformation method to obtain data applicable to reactor fuel elements from these annulus experiments. New experimental friction data are presented for ten rods, each with a different artificial roughness made up of two-dimensional rectangular ribs. For each rod four tests have been performed, each in a different outer smooth tube. For two of these rods, each for two different outer tubes, heat transfer data are also given. The friction and heat transfer data, transformed with the present method, are correlated by simple equations. In the paper, these equations are applied to a case typical for a Gas Cooled Fast Reactor fuel element. (orig.) [de

  17. Gas separating

    Science.gov (United States)

    Gollan, A.

    1988-03-29

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing. 3 figs.

  18. Competition of proton and electron transfers in gas-phase reactions of hydrogen-containing dications CHX.sup.2+./sup. (X = F, Cl, Br, I) with atoms, nonpolar and polar molecules

    Czech Academy of Sciences Publication Activity Database

    Roithová, Jana; Herman, Zdeněk; Schröder, D.; Schwarz, H.

    2006-01-01

    Roč. 12, č. 9 (2006), s. 2465-2471 ISSN 0947-6539 R&D Projects: GA AV ČR KJB4040302 Institutional research plan: CEZ:AV0Z40400503 Keywords : ab initio calculations * dications * electron transfer * proton transport * superelectrophiles Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 5.015, year: 2006

  19. Hollow fiber gas-liquid membrane contactors for acid gas capture: a review.

    Science.gov (United States)

    Mansourizadeh, A; Ismail, A F

    2009-11-15

    Membrane contactors using microporous membranes for acid gas removal have been extensively reviewed and discussed. The microporous membrane acts as a fixed interface between the gas and the liquid phase without dispersing one phase into another that offers a flexible modular and energy efficient device. The gas absorption process can offer a high selectivity and a high driving force for transport even at low concentrations. Using hollow fiber gas-liquid membrane contactors is a promising alternative to conventional gas absorption systems for acid gas capture from gas streams. Important aspects of membrane contactor as an efficient energy devise for acid gas removal including liquid absorbents, membrane characteristics, combination of membrane and absorbent, mass transfer, membrane modules, model development, advantages and disadvantages were critically discussed. In addition, current status and future potential in research and development of gas-liquid membrane contactors for acid gas removal were also briefly discussed.

  20. ADVANCED GAS TURBINE SYSTEMS RESEARCH

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    2000-01-01

    The activities of the Advanced Gas Turbine Systems Research (AGRSR) program are described in the quarterly report. The report is divided into discussions of Membership, Administration, Technology Transfer (Workshop/Education) and Research. Items worthy of note are presented in extended bullet format following the appropriate heading.