Ion optics of a time-of-flight mass spectrometer with electrostatic sector analyzers

International Nuclear Information System (INIS)

Sakurai, T.; Ito, H.; Matsuo, T.

1995-01-01

The ion optics for a high resolution time-of-flight mass spectrometer with electrostatic sector analyzers have been investigated. The multiple focusing (triple isochronous focusing and triple spacial focusing) conditions can be achieved by using a symmetrical arrangement of the sectors in a mass spectrometer. Both high mass resolution and high ion transmission can be accomplished simultaneously. The principles of MS/MS and MS/MS/MS analyses using a TOF mass spectrometer with electrostatic sector analyzers have been proposed. Product ion spectra can be obtained by measuring the total flight times and the kinetic energy of the products without any additional separation processes, any coincidence techniques or any special timing circuits. In an experiment, MS/MS and MS/MS/MS mass spectra have been obtained. The first generation product ions have been produced by a metastable decay, and the second generation products have been produced by a sequential decay. (orig.)

Time-of-flight spectrometer for the measurement of gamma correlated neutron spectra

International Nuclear Information System (INIS)

Andryashin, A.V.; Devlein, B.V.; Lychagin, A.A.; Minko, Y.V.; Mironov, A.N.; Nesterenko, V.S.

1986-01-01

A time-of-flight spectrometer for the measurement of gamma correlated neutron spectra form (n,xnγ) reactions is described. The operation and the main parameters are discussed. The resolution in the neutron channel is 2.2 ns/m at the 150 keV neutron energy threshold. A simultaneous measurement of the time-of-flight and amplitude distributions makes it possible to study gamma correlated neutron spectra as well as the prompt gamma spectra in coincidence with selected energy neutrons. In order to test the spectrometer, measurements of the neutron spectrum in coincidence with the 846 keV gamma line of 56 Fe were carried out at an incident neutron energy of 14.1 MeV. (author). 3 figs., 6 refs

Satellite-borne time-of-flight particle spectrometer and its response to protons

International Nuclear Information System (INIS)

Shino, T.

1994-01-01

One of the purposes of the high energy particle (HEP) experiment of the GEOTAIL satellite launched in 1992 is the elucidation of plasma dynamics in the tail region of planetary magnetosphere. For that purpose, a low energy particle detector (LD) was on board, which mainly observed relatively low energy particles up to a few MeV. The LD is the particle spectrometer based on time of flight technique. In order to confirm further its sensitivity to high energy protons, the beam experiment was carried out at Waseda University using the engineering model of the LD spectrometer that is exactly the same as the launched one. The LD spectrometer is shown, and its functions are explained. The LD was designed to identify electrons of 30 - 400 keV, protons of 30 - 1500 keV, helium ions of 80 - 4000 keV, and heavy ions (mainly C, N and O) of 160 - 1500 keV. The relation of measured time of flight signals with energy signals is shown. There are several factors that determine the detection efficiency of the spectrometer, which are discussed. The experiment and the results are reported. (K.I.)

The multiple disk chopper neutron time-of-flight spectrometer at NIST

International Nuclear Information System (INIS)

Altorfer, F.B.; Cook, J.C.; Copley, J.R.D.

1995-01-01

A highly versatile multiple disk chopper neutron time-of-flight spectrometer is being installed at the Cold Neutron Research Facility of the National institute of Standards and Technology. This new instrument will fill an important gap in the portfolio of neutron inelastic scattering spectrometers in North America. It will be used for a wide variety of experiments such as studies of magnetic and vibrational excitations, tunneling spectroscopy, and quasielastic neutron scattering investigations of local and translational diffusion. The instrument uses disk choppers to monochromate and pulse the incident beam, and the energy changes of scattered neutrons are determined from their times-of-flight to a large array of detectors. The disks and the guide have been designed to make the instrument readily adaptable to the specific performance requirements of experimenters. The authors present important aspects of the design, as well as estimated values of the flux at the sample and the energy resolution for elastic scattering. The instrument should be operational in 1996

A PCI time digitizer for the new JET time-of-flight neutron spectrometer

International Nuclear Information System (INIS)

Sousa, J.; Batista, A.J.N.; Combo, A.; Pereira, R.; Cruz, N.; Carvalho, P.; Varandas, C.A.F.; Conroy, S.; Ericsson, G.; Kaellne, J.

2004-01-01

A PCI time digitizer module with eight independent time-to-digital converter (TDC) channels is being developed for the new time-of-flight spectrometer designed for optimized rate (TOFOR) which diagnoses deuterium plasmas of the EFDA-JET tokamak. The module shall measure with high accuracy the flight-times of 2.5 MeV neutrons in the 100 ns range as given by two groups of scintillation detectors operating at average event rates from the expected 500 kHz up to 5 MHz. The module stores up to 64 million hit-times with a resolution of 0.4 ns and incorporates a digital signal processor and a system-on-chip device which performs the data transfer, the device control/monitoring and may perform statistical, data reduction or control algorithms in real-time

Measurement and simulation of the inelastic resolution function of a time-of-flight spectrometer

International Nuclear Information System (INIS)

Roth, S.V.; Zirkel, A.; Neuhaus, J.; Petry, W.; Bossy, J.; Peters, J.; Schober, H.

2002-01-01

The deconvolution of inelastic neutron scattering data requires the knowledge of the inelastic resolution function. The inelastic resolution function of the time-of-flight spectrometer IN5/ILL has been measured by exploiting the sharp resonances of the roton and maxon excitations in superfluid 4 He for the two respective (q,ω) values. The calculated inelastic resolution function for three different instrumental setups is compared to the experimentally determined resolution function. The agreement between simulation and experimental data is excellent, allowing us in principle to extrapolate the simulations and thus to determine the resolution function in the whole accessible dynamic range of IN5 or any other time-of-flight spectrometer. (orig.)

Measurement and simulation of the inelastic resolution function of a time-of-flight spectrometer

CERN Document Server

Roth, S V; Neuhaus, J; Petry, W; Bossy, J; Peters, J; Schober, H

2002-01-01

The deconvolution of inelastic neutron scattering data requires the knowledge of the inelastic resolution function. The inelastic resolution function of the time-of-flight spectrometer IN5/ILL has been measured by exploiting the sharp resonances of the roton and maxon excitations in superfluid sup 4 He for the two respective (q,omega) values. The calculated inelastic resolution function for three different instrumental setups is compared to the experimentally determined resolution function. The agreement between simulation and experimental data is excellent, allowing us in principle to extrapolate the simulations and thus to determine the resolution function in the whole accessible dynamic range of IN5 or any other time-of-flight spectrometer. (orig.)

The Dubna double-arm time-of-flight spectrometer for heavy-ion reaction products

International Nuclear Information System (INIS)

Schilling, K.D.; Gippner, P.; Seidel, W.; Stary, F.; Will, E.; Heidel, K.; Lukyanov, S.M.; Penionzhkevich, Yu.E.; Salamatin, V.S.; Sodan, H.; Chubarian, G.G.

1986-05-01

The double-arm time-of-flight spectrometer DEMAS designed for the detection and identification of heavy-ion reaction products at incident energies below 10 MeV/amu is presented. Based on the kinematic coincidence method, the relevant physical information is obtained from the measurement of the two correlated velocity vectors of the binary fragments. Construction and performance of the different detector systems applied to measure the time-of-flight values, the position coordinates and the kinetic energies of both fragments are presented in detail. The description of the data acquisition and analysing procedures is followed by the discussion of some experimental examples to demonstrate the spectrometer performance. A mass resolution of typically 4 - 5 amu (fwhm) is routinely achieved. (author)

Isobar Separation in a Multiple-Reflection Time-of-Flight Mass Spectrometer by Mass-Selective Re-Trapping

Science.gov (United States)

Dickel, Timo; Plaß, Wolfgang R.; Lippert, Wayne; Lang, Johannes; Yavor, Mikhail I.; Geissel, Hans; Scheidenberger, Christoph

2017-06-01

A novel method for (ultra-)high-resolution spatial mass separation in time-of-flight mass spectrometers is presented. Ions are injected into a time-of-flight analyzer from a radio frequency (rf) trap, dispersed in time-of-flight according to their mass-to-charge ratios and then re-trapped dynamically in the same rf trap. This re-trapping technique is highly mass-selective and after sufficiently long flight times can provide even isobaric separation. A theoretical treatment of the method is presented and the conditions for optimum performance of the method are derived. The method has been implemented in a multiple-reflection time-of-flight mass spectrometer and mass separation powers (FWHM) in excess of 70,000, and re-trapping efficiencies of up to 35% have been obtained for the protonated molecular ion of caffeine. The isobars glutamine and lysine (relative mass difference of 1/4000) have been separated after a flight time of 0.2 ms only. Higher mass separation powers can be achieved using longer flight times. The method will have important applications, including isobar separation in nuclear physics and (ultra-)high-resolution precursor ion selection in multiple-stage tandem mass spectrometry. [Figure not available: see fulltext.

Miniature Time of Flight Mass Spectrometer for Space and Extraterrestrial Applications, Phase II

Data.gov (United States)

National Aeronautics and Space Administration — The PI has developed a miniature time-of-flight mass spectrometer (TOF-MS), which can be op-timized for space and extraterrestrial applications, by using a...

Design of microcomputer-based data acquisition system for the time-of-flight ion scattering spectrometer

Energy Technology Data Exchange (ETDEWEB)

Lo, H; Su, C [National Tsing Hua Univ., Hsinchu (Taiwan). Inst. of Nuclear Engineering

1981-07-15

A microcomputer-based data aquisition system used on a time-of-flight ion scattering spectrometer is described. The flight time of 90/sup 0/-scattered ions from target atom determined directly with a 30 MHz crystal-controlled oscillator and its associated circuit. The ion intensity is detected by a channel multiplier, and its output signal pulse is converted from the analog form into digital form by an ADC. Both flight time and ion intensity are stored in the microcomputer.

Design of microcomputer-based data acquisition system for the time-of-flight ion scattering spectrometer

International Nuclear Information System (INIS)

Lo, H.; Su, C.

1981-01-01

A microcomputer-based data aquisition system used on a time-of-flight ion scattering spectrometer is described. The flight time of 90 0 -scattered ions from target atom determined directly with a 30 MHz crystal-controlled oscillator and its associated circuit. The ion intensity is detected by a channel multiplier, and its output signal pulse is converted from the analog form into digital form by an ADC. Both flight time and ion intensity are stored in the microcomputer. (orig.)

Multiple-ion-beam time-of-flight mass spectrometer

International Nuclear Information System (INIS)

Rohrbacher, Andreas; Continetti, Robert E.

2001-01-01

An innovative approach to increase the throughput of mass spectrometric analyses using a multiple-ion-beam mass spectrometer is described. Two sample spots were applied onto a laser desorption/ionization target and each spot was simultaneously irradiated by a beam of quadrupled Nd:YLF laser radiation (261.75 nm) to produce ions by laser-desorption ionization. Acceleration of the ions in an electric field created parallel ion beams that were focused by two parallel einzel lens systems. After a flight path of 2.34 m, the ions were detected with a microchannel plate-phosphor screen assembly coupled with a charge coupled device camera that showed two resolved ion beams. Time-of-flight mass spectra were also obtained with this detector. Experiments were performed using both metal atom cations (Ti + and Cr + ) produced by laser desorption/ionization and the molecular ions of two different proteins (myoglobin and lysozyme), created by matrix assisted laser desorption/ionization using an excess of nicotinic acid as matrix

Experiments at the time-of-flight neutron spectrometer GNEIS in Gatchina

International Nuclear Information System (INIS)

Shcherbakov, O.A.

1990-01-01

A brief description of the Gatchina neutron time-of-flight spectrometer GNEIS at the 1 GeV proton synchrocyclotron and its main characteristics are given. Some results of the nuclear fission experiments and neutron cross section measurements are presented not only to illustrate the facility performance but to outline the basic directions of the researches as well. 28 refs.; 10 figs

Physical design of time-of-flight mass spectrometer in energetic cluster impact deposition apparatus

International Nuclear Information System (INIS)

Yu Guoqing; Shi Ying; Chen Jingsheng; Zhu Dezhang; Pan Haochang; Xu Hongjie

1999-01-01

The principle and physical design of the time-of-flight mass spectrometer equipped in the energetic cluster impact deposition apparatus are introduced. Some problems existed in experiments and their solutions are also discussed

Reflection-time-of-flight spectrometer for two-electron (e,2e) coincidence spectroscopy on surfaces

International Nuclear Information System (INIS)

Kirschner, J.; Kerherve, G.; Winkler, C.

2008-01-01

In this article, a novel time-of-flight spectrometer for two-electron-emission (e,2e/γ,2e) correlation spectroscopy from surfaces at low electron energies is presented. The spectrometer consists of electron optics that collect emitted electrons over a solid angle of approximately 1 sr and focus them onto a multichannel plate using a reflection technique. The flight time of an electron with kinetic energy of E kin ≅25 eV is around 100 ns. The corresponding time- and energy resolution are typically ≅1 ns and ≅0.65 eV, respectively. The first (e,2e) data obtained with the present setup from a LiF film are presented

The new JET 2.5-MeV neutron time-of-flight spectrometer

International Nuclear Information System (INIS)

Elevant, T.; Belle, P.v.; Grosshoeg, G.; Hoek, M.; Jarvis, O.N.; Olsson, M.; Sadler, G.

1992-01-01

A major upgrade of the JET 2.5-MeV neutron time-of-flight spectrometer has been completed. The improvement has permitted ion temperature measurements for Maxwellian deuterium plasmas with T i >4 keV to be obtained in 0.5-s intervals. By combining observations of neutron and x-ray energy spectra with studies of γ-ray emission from reactions between fast deuterons and impurities, the effects of ICRF heating on the deuterium energy distribution have been studied. The time evolution of neutron energy spectra from deuterium-beam heated deuterium plasmas is illustrated and a method for evaluating the ion temperature from such sequences is indicated. Furthermore, the spectrometer has shown stable performance during high neutron fluxes

Dual cascade time-of-flight mass spectrometer basing on electrostatic mirrors with two dimensional fields

International Nuclear Information System (INIS)

Glikman, L. G.; Goloskokov, Yu. V.; Karetskaya, S.P.; Mit', A.G.

1999-01-01

In the report [1] we have suggested the scheme of time-of-flight spectrometer containing two electrostatic mirrors with two dimensional field that doesn't depend on one of the Cartesian coordinates). In the articles [2,3] there have been found conditions for obtaining high quality of time-of-flight and spatial focusing. One of basic advantages of this scheme - is availability of intermediate stigmatic image. In the plane where this image is it's possible to place controlled diaphragm that limits ion scatter along the energy if the scatter is too large. With the help of this diaphragm at the spectrometer you can register mass spectrum with the selected energy. Good focusing quality allows reducing of initial ion energy by this increasing the time of their flight and thus analyzers resolving ability. Ion source and receiver are spaced at rather a long distances. This can be useful to solve some practical tasks

A new approach for accurate mass assignment on a multi-turn time-of-flight mass spectrometer.

Science.gov (United States)

Hondo, Toshinobu; Jensen, Kirk R; Aoki, Jun; Toyoda, Michisato

2017-12-01

A simple, effective accurate mass assignment procedure for a time-of-flight mass spectrometer is desirable. External mass calibration using a mass calibration standard together with an internal mass reference (lock mass) is a common technique for mass assignment, however, using polynomial fitting can result in mass-dependent errors. By using the multi-turn time-of-flight mass spectrometer infiTOF-UHV, we were able to obtain multiple time-of-flight data from an ion monitored under several different numbers of laps that was then used to calculate a mass calibration equation. We have developed a data acquisition system that simultaneously monitors spectra at several different lap conditions with on-the-fly centroid determination and scan law estimation, which is a function of acceleration voltage, flight path, and instrumental time delay. Less than 0.9 mDa mass errors were observed for assigned mass to charge ratios ( m/z) ranging between 4 and 134 using only 40 Ar + as a reference. It was also observed that estimating the scan law on-the-fly provides excellent mass drift compensation.

Lumbosacral Corsets Improve the Outcome of Patients with Non ...

African Journals Online (AJOL)

extreme trunk motion and offering tactile biofeedback. (5). There is paucity of data on the use of lumbosacral corset for acute low back pain. Existing literature on the use of lumbosacral corset is deficient of high quality randomized trials assessing the importance of this modality of treatment on acute low back pain with regard ...

TOPLAR: Time of Flight with Larmor Precessions - or - How to extend the dynamic range of NSE spectrometers

International Nuclear Information System (INIS)

Van Well, A.A.; Bleuel, M.; Pappas, C.

2011-01-01

Neutron Spin Echo (NSE) spectrometers typically cover a dynamic range of three orders of magnitude at a given wavelength. At long Fourier times the limits are given by the homogeneity of precession fields. At short Fourier times, the quasi-elastic approximation and the NSE formalism mark a methodological limit. We propose to overcome this limitation and by combining Time Of Flight with Larmor precession to extend the capabilities of Neutron Spin Echo spectrometers towards short Fourier times. TOFLAR should be easily implemented on NSE spectrometers equipped with a chopper system such as IN15 or the planned WASP. (authors)

Absolute calibration of a time-of-flight spectrometer and imaging plate for the characterization of laser-accelerated protons

International Nuclear Information System (INIS)

Choi, I W; Kim, C M; Sung, J H; Kim, I J; Yu, T J; Lee, S K; Jin, Y-Y; Pae, K H; Hafz, N; Lee, J

2009-01-01

A proton energy spectrometer system is composed of a time-of-flight spectrometer (TOFS) and a Thomson parabola spectrometer (TPS), and is used to characterize laser-accelerated protons. The TOFS detects protons with a plastic scintillator, and the TPS with a CR-39 or imaging plate (IP). The two spectrometers can operate simultaneously and give separate time-of-flight (TOF) and Thomson parabola (TP) data. We propose a method to calibrate the TOFS and IP by comparing the TOF data and the TP data taken with CR-39 and IP. The absolute response of the TOFS as a function of proton energy is calculated from the proton number distribution measured with CR-39. The sensitivity of IP to protons is obtained from the proton number distribution estimated with the calibrated TOFS. This method, based on the comparison of the simultaneously measured data, gives more reliable results when using laser-accelerated protons as a calibration source. The calibrated spectrometer system can be used to measure absolutely calibrated energy spectra for the optimization of laser-accelerated protons

The influence of orthopedic corsets on the incidence of pathological fractures in patients with spinal bone metastases after radiotherapy

International Nuclear Information System (INIS)

Rief, Harald; Förster, Robert; Rieken, Stefan; Bruckner, Thomas; Schlampp, Ingmar; Bostel, Tilman; Debus, Jürgen

2015-01-01

Clinical care of unstable spinal bone metastases in many centers often includes patient immobilization by means of an orthopedic corset in order to prevent pathological fractures. The aim of this retrospective analysis was to evaluate the incidence of pathological fractures after radiotherapy (RT) in patients with and without orthopedic corsets and to assess prognostic factors for pathological fractures in patients with spinal bone metastases. The incidence of pathological fractures in 915 patients with 2.195 osteolytic metastases in the thoracic and lumbar spine was evaluated retrospectively on the basis of computed tomography (CT) scans between January 2000 and January 2012 depending on prescription and wearing of patient—customized orthopedic corsets. In the corset group, 6.8 and 8.0 % in no-corset group showed pathological fractures prior to RT, no significant difference between groups was detected (p = 0.473). After 6 months, patients in the corset group showed pathological fractures in 8.6 % and in no-corset group in 9.3 % (p = 0.709). The univariate and bivariate analyses demonstrated no significant prognostic factor for incidence of pathological fractures in both groups. In this analysis, we could show for the first time in more than 900 patients, that abandoning a general corset supply in patients with spinal metastases does not significantly cause increased rates of pathological fractures. Importantly, the incidence of pathological fracture after RT was small

Novel time-of-flight spectrometer for the analysis of positron annihilation induced Auger electrons

International Nuclear Information System (INIS)

Hugenschmidt, Christoph; Legl, Stefan

2006-01-01

Positron annihilation induced Auger-electron spectroscopy (PAES) has several advantages over conventional Auger-electron spectroscopy such as extremely high surface sensitivity and outstanding signal-to-noise ratio at the Auger-transition energy. In order to benefit from these prominent features a low-energy positron beam of high intensity is required for surface sensitive PAES studies. In addition, an electron energy analyzer is required, which efficiently detects the Auger electrons with acceptable energy resolution. For this reason a novel time-of-flight (TOF) spectrometer has been developed at the intense positron source NEPOMUC that allows PAES studies within short measurement time. This TOF-PAES setup combines a trochoidal filter and a flight tube in a Faraday cage in order to achieve an improved energy resolution of about 1 eV at high electron energies up to E≅1000 eV. The electron flight time is the time between the annihilation radiation at the sample and when the electron hits a microchannel plate detector at the end of the flight tube

A method for the determination of detector channel dead time for a neutron time-of-flight spectrometer

International Nuclear Information System (INIS)

Adib, M.; Salama, M.; Abd-Kawi, A.; Sadek, S.; Hamouda, I.

1975-01-01

A new method is developed to measure the dead time of a detector channel for a neutron time-of-flight spectrometer. The method is based on the simultaneous use of two identical BF 3 detectors but with two different efficiencies, due to their different enrichment in B 10 . The measurements were performed using the T.O.F. spectrometer installed at channel No. 6 of the ET-RR-1 reactor. The main contribution to the dead time was found to be due to the time analyser and the neutron detector used. The analyser dead time has been determined using a square wave pulse generator with frequency of 1 MC/S. For channel widths of 24.4 us, 48.8 ud and 97.6 us, the weighted dead times for statistical pulse distribution were found to be 3.25 us, 1.87 us respectively. The dead time of the detector contributes mostly to the counting losses and its value was found to be (33+-3) us

A reflecting time-of-flight mass spectrometer

Energy Technology Data Exchange (ETDEWEB)

Tang, X

1991-01-01

The design, construction and operation of a reflecting time-of-flight mass spectrometer and the details of the ion mirror are discussed. The principle of velocity focusing with a single-stage ion mirror and the effect of the acceleration region are discussed. The performance of the reflecting instrument is described. Its detection limit is illustrated by observation of [M + H][sup +] ions from [approximately]5-35 femtomoles of various peptides. The factors that affect the resolution are discussed. The principle and operation of the reflecting instrument as a tandem mass spectrometer is described; this involves correlated detection of neutral and ionized fragments. The efficiency, resolution, sensitivity, and mass determination of daughter ions by this method are discussed. Methods of sample preparation are described. By using a nitrocellulose substrate, organic molecular ions as large as bovine insulin (MW 5733) were detected for the first time with low energy (keV) ion bombardment of a solid surface. Many daughter ion spectra resulting from metastable decay of parent ions have been studied. Secondary ions [(CsI)[sub n]Cs][sup +] with n up to [approximately]50 were detected; all clusters were found to be metastable, with most lifetimes <100 [mu]s, and for n>10 the daughter ions are dominant in the mass spectrum. Peptides of mass up to [approximately]2000 u have been studied with the correlated method; the daughter ion spectra were found to be strongly influenced by the identity of the bound cation (H[sup +], Na[sup +], K[sup +], or Ag[sup +]). Many daughter ions formed by known reactions yield structure and sequence information about the peptides. In addition, the [M + Na][sup +] and [M + Ag][sup +] ions decompose by a previously unreported pathway, namely, rearrangement of a C-terminal carboxyl oxygen onto the daughter ion containing the N-terminus. Both the reflected spectra and daughter ion spectra were found useful in peptide sequencing.

The corset platysma repair: a technique revisited.

Science.gov (United States)

Jacob, Carolyn I; Kaminer, Michael S

2002-03-01

Platysma banding along with excess submental adipose tissue and sagging skin can lead to an aged appearance. Several methods for improving neck and submental contours exist, including neck liposuction, bilateral platysma plication, midline platysma plication with transection of distal fibers, necklift with skin excision, and botulinum toxin injection for platysma relaxation. With the current interest in minimally invasive procedures, surgeons and patients are searching for techniques that produce maximal improvement with minimal intervention. To present a modified technique for maximizing neck contouring, discuss possible complications of the procedure, and describe appropriate candidates for the corset platysmaplasty. We performed a retrospective analysis of 10 consecutive patients who underwent neck liposuction with concomitant corset platysmaplasty at our institution. All 10 patients achieved good to excellent submental and jawline contouring, determined by both physician and patient assessment, with no visible platysma banding at 6 months follow-up. No major complications were noted. Use of corset platysmaplasty is a safe and effective method for neck rejuvenation. This variation of platysmaplasty can be used in conjunction with neck liposuction to maximize jawline and neck contour enhancement.

Polarisation analysis on the LET time-of-flight spectrometer

Science.gov (United States)

Nilsen, G. J.; Košata, J.; Devonport, M.; Galsworthy, P.; Bewley, R. I.; Voneshen, D. J.; Dalgliesh, R.; Stewart, J. R.

2017-06-01

We present a design for implementing uniaxial polarisation analysis on the LET cold neutron time-of-flight spectrometer, installed on the second target station at ISIS. The polarised neutron beam is to be produced by a transmission-based supermirror polariser with the polarising mirrors arranged in a “double-V” formation. This will be followed by a Mezei-type precession coil spin flipper, selected for its small spatial requirements, as well as a permanent magnet guide field to transport the beam polarisation to the sample position. The sample area will contain a set of holding field coils, whose purpose is to produce a highly homogenous magnetic field for the wide-angle 3He analyser cell. To facilitate fast cell changes and reduce the risk of cell failure, we intend to separate the cell and cryostat from the vacuum of the sample tank by installing both in a vessel at atmospheric pressure. When the instrument upgrade is complete, the performance of LET is expected to be commensurate with existing and planned polarised cold neutron spectrometers at other sources. Finally, we discuss the implications of performing uniaxial polarisation analysis only, and identify quasi-elastic neutron scattering (QENS) on ionic conducting materials as an interesting area to apply the technique.

HYSPEC : A CRYSTAL TIME OF FLIGHT HYBRID SPECTROMETER FOR THE SPALLATION NEUTRON SOURCE

International Nuclear Information System (INIS)

SHAPIRO, S.M.; ZALIZNYAK, I.A.

2002-01-01

This document lays out a proposal by the Instrument Development Team (IDT) composed of scientists from leading Universities and National Laboratories to design and build a conceptually new high-flux inelastic neutron spectrometer at the pulsed Spallation Neutron Source (SNS) at Oak Ridge. This instrument is intended to supply users of the SNS and scientific community, of which the IDT is an integral part, with a platform for ground-breaking investigations of the low-energy atomic-scale dynamical properties of crystalline solids. It is also planned that the proposed instrument will be equipped with a polarization analysis capability, therefore becoming the first polarized beam inelastic spectrometer in the SNS instrument suite, and the first successful polarized beam inelastic instrument at a pulsed spallation source worldwide. The proposed instrument is designed primarily for inelastic and elastic neutron spectroscopy of single crystals. In fact, the most informative neutron scattering studies of the dynamical properties of solids nearly always require single crystal samples, and they are almost invariably flux-limited. In addition, in measurements with polarization analysis the available flux is reduced through selection of the particular neutron polarization, which puts even more stringent limits on the feasibility of a particular experiment. To date, these investigations have mostly been carried out on crystal spectrometers at high-flux reactors, which usually employ focusing Bragg optics to concentrate the neutron beam on a typically small sample. Construction at Oak Ridge of the high-luminosity spallation neutron source, which will provide intense pulsed neutron beams with time-averaged fluxes equal to those at medium-flux reactors, opens entirely new opportunities for single crystal neutron spectroscopy. Drawing upon experience acquired during decades of studies with both crystal and time-of-flight (TOF) spectrometers, the IDT has developed a conceptual

HYSPEC : A CRYSTAL TIME OF FLIGHT HYBRID SPECTROMETER FOR THE SPALLATION NEUTRON SOURCE.

Energy Technology Data Exchange (ETDEWEB)

SHAPIRO,S.M.; ZALIZNYAK,I.A.

2002-12-30

This document lays out a proposal by the Instrument Development Team (IDT) composed of scientists from leading Universities and National Laboratories to design and build a conceptually new high-flux inelastic neutron spectrometer at the pulsed Spallation Neutron Source (SNS) at Oak Ridge. This instrument is intended to supply users of the SNS and scientific community, of which the IDT is an integral part, with a platform for ground-breaking investigations of the low-energy atomic-scale dynamical properties of crystalline solids. It is also planned that the proposed instrument will be equipped with a polarization analysis capability, therefore becoming the first polarized beam inelastic spectrometer in the SNS instrument suite, and the first successful polarized beam inelastic instrument at a pulsed spallation source worldwide. The proposed instrument is designed primarily for inelastic and elastic neutron spectroscopy of single crystals. In fact, the most informative neutron scattering studies of the dynamical properties of solids nearly always require single crystal samples, and they are almost invariably flux-limited. In addition, in measurements with polarization analysis the available flux is reduced through selection of the particular neutron polarization, which puts even more stringent limits on the feasibility of a particular experiment. To date, these investigations have mostly been carried out on crystal spectrometers at high-flux reactors, which usually employ focusing Bragg optics to concentrate the neutron beam on a typically small sample. Construction at Oak Ridge of the high-luminosity spallation neutron source, which will provide intense pulsed neutron beams with time-averaged fluxes equal to those at medium-flux reactors, opens entirely new opportunities for single crystal neutron spectroscopy. Drawing upon experience acquired during decades of studies with both crystal and time-of-flight (TOF) spectrometers, the IDT has developed a conceptual

Monte Carlo study of the performance of a time-of-flight multichopper spectrometer

International Nuclear Information System (INIS)

Daemen, L.L.; Eckert, J.; Pynn, R.

1995-01-01

The Monte Carlo method is a powerful technique for neutron transport studies. While it has been applied for many years to the study of nuclear systems, there are few codes available for neutron transport in the optical regime. The recent surge of interest in so-called next generation spallation neutron sources and the desire to design new and optimized instruments for these facilities has led us to develop a Monte Carlo code geared toward the simulation of neutron scattering instruments. The time-of-flight multichopper spectrometer, of which IN5 at the ILL is the prototypical example, is the first spectrometer studied with the code. Some of the results of a comparison between the IN5 performance at a reactor and at a Long Pulse Spallation Source (LPSS) are summarized here

A small sized time-of-flight mass spectrometer for simultaneous measurement of neutral and ionic species effusing from plasma, 1

International Nuclear Information System (INIS)

Horiuchi, Yukihiko

1986-01-01

A principle for simultaneous and real time measurement of neutral and ionic species effusing from plasma by using a time-of-flight mass spectrometer is proposed. A simple, small sized time-of-flight mass spectrometer combined with a dc glow discharge tube and an ion sampling electrode system for the simultaneous measurement on the basis of the proposed plinciple, has been constructed and tested. Details of the experimental setup including the geometry and the electronic hardware are described. It is shown that mass spectra of neutrals and ions from the positive column of the argon dc glow discharge are successfully observed on a single oscilloscope display. (author)

The Evaluation of Effectiviness of Conventional Corset on Walking Potential in Patients with Fibromyalgia

OpenAIRE

İnanır, Ahmet; Habiboğlu, Abdulkadir; Erkorkmaz, Ünal; İnanır, Sema

2011-01-01

Objective: It has been aimed whether the corset changes the potential to exercise in patients with fibromyalgia syndrome. Material and Methods: In this study, classified according to body mass index (BMI), 51 patients diagnosed Rehabilitation clinic with fibromyalgia and tested in walking 6 minutes with and without the corset were compared in their test results. Findings: In their walking test scores with/without the corset of the Groups 1, 2 and 3 fibromyalgia patients were identified statis...

Rocket-borne time-of-flight mass spectrometry

Science.gov (United States)

Reiter, R. F.

1976-01-01

Theoretical and numerical analyses are made of planar, cylindrical and spherical-electrode two-field time-of-flight mass spectrometers in order to optimize their operating conditions. A method is introduced which can improve the resolving power of these instruments by a factor of 7.5. Potential barrier gating in time-of-flight mass spectrometers is also analyzed. Experimental studies of a miniature cylindrical-electrode and a hemispherical-electrode time-of-flight mass spectrometer are presented. Their sensitivity and ability to operate at D-region pressures with an open source make them ideal instruments for D-region ion composition measurements. A sounding rocket experiment package carrying a cylindrical electrode time-of-flight mass spectrometer was launched. The data indicate that essentially 100% of the positive electric charge on positive ions is carried by ions with mass-to-charge ratios greater than 500 below an altitude of 92 km. These heavy charge carriers were present at altitudes up to about 100 km.

Rocket-borne time-of-flight mass spectrometry

International Nuclear Information System (INIS)

Reiter, R.F.

1976-08-01

Theoretical and numerical analyses are made of planar-, cylindrical- and spherical-electrode two-field time-of-flight mass spectrometers in order to optimize their operating conditions. A method is introduced which can improve the resolving power of these instruments by a factor of 7.5. Potential barrier gating in time-of-flight mass spectrometers is also analyzed. Experimental studies of a miniature cylindrical-electrode and a hemispherical-electrode time-of-flight mass spectrometer are presented. Their sensitivity and ability to operate at D-region pressures with an open source make them ideal instruments for D-region ion composition measurements. A sounding rocket experiment package carrying a cylindrical electrode time-of-flight mass spectrometer was launched. The data indicate that essentially 100% of the positive electric charge on positive ions is carried by ions with mass-to-charge ratios greater than 500 below an altitude of 92 km. These heavy charge carriers were present at altitudes up to about 100 km

RAMSES - Rapid Measurement and Special Environment time-of-flight Spectrometer

International Nuclear Information System (INIS)

Schober, H.; Koza, M.; Mutka, H.; Zbiri, M.; Andersen, K.

2011-01-01

Time-of-flight spectrometers are ideally suited to study the dynamics of complex materials as encountered in all domains of current scientific interest ranging from health care, biology, earth and environmental sciences, cultural heritage to energy storage and preservation. Complex materials are often available in samples of small amount, or the scientific questions to study require environments limiting the sample size (e.g., Paris-Edinburgh cells and levitation furnaces). The proposed instrument would be optimized for these conditions offering a very high neutron flux over a small beam cross-section in combination with good resolution and extended dynamical range. The later asks for a wavelength band extending slightly into the thermal region. This is achieved on a cold guide with super-mirror coating. (authors)

Design study of a time-of-flight neutron spectrometer for JT-60U

International Nuclear Information System (INIS)

Elevant, T.; Hoek, M.; Nishitani, Takeo.

1993-06-01

A time-of-flight neutron spectrometer is proposed for measurements of neutron energy spectra from deuterium-deuterium reactions in JT-60U tokamak plasmas. The sensitivity of the instrument is 2 · 10 -2 cm 2 , energy resolution is 4.5 % (FWHM) and maximum useful count-rate is 6 kHz. Analysis of neutron energy spectra will provide information on central ion temperatures larger than ∼ 4 keV with an accuracy of ± 10 %, and neutron source fraction from reactions between thermal ions with an accuracy of ± 15 %. The minimum time required for data acquisition is 0.1 s. (author)

On the use of the cold time-of-flight spectrometer in Studsvik for liquid 3He measurements

International Nuclear Information System (INIS)

Faak, Bjoern.

1989-01-01

The time-of-flight spectrometer for cold neutrons at the R2 reactor in Studsvik has been reconstructed. The design and the performance of the instrument are briefly described. Improvements required for measurement of the neutron scattering function of liquid 3 He are discussed. (author)

Laser ionization time of flight mass spectrometer for isotope mass detection and elemental analysis of materials

Science.gov (United States)

Ahmed, Nasar; Ahmed, Rizwan; Umar, Z. A.; Aslam Baig, M.

2017-08-01

In this paper we present the construction and modification of a linear time-of-flight mass spectrometer to improve its mass resolution. This system consists of a laser ablation/ionization section based on a Q-switched Nd:YAG laser (532 nm, 500 mJ, 5 ns pulse duration) integrated with a one meter linear time-of-flight mass spectrometer coupled with an electric sector and a magnetic lens and outfitted with a channeltron electron multiplier for ion detection. The resolution of the system has been improved by optimizing the accelerating potential and inserting a magnetic lens after the extraction region. The isotopes of lithium, lead and cadmium samples have been resolved and detected in accordance with their natural abundance. The capability of the system has been further exploited to determine the elemental composition of a brass alloy, having a certified composition of zinc and copper. Our results are in excellent agreement with its certified composition. This setup is found to be extremely efficient and convenient for fast analyses of any solid sample.

BATS - Backscattering And Time-of-flight Spectrometer

International Nuclear Information System (INIS)

Van Eijck, L.; Seydel, T.; Frick, B.; Schober, H.

2011-01-01

The new backscattering spectrometer IN16b will go into commissioning end 2011, providing in its final state about ten times higher count rate than its predecessor, IN16. Here we propose to increase its dynamic range by a factor of 7 with the TOF mode extension, BATS. This will make IN16b the leading high resolution backscattering spectrometer for incoherent quasi-elastic and inelastic neutron scattering; it will be competitive to the coarser resolution inverted geometry backscattering spectrometers that are being brought online at spallation sources. The increased dynamic range will extend the scope of science addressed on IN16b, generating considerable potential in fields such as the hydrogen economy (proton conduction, fuel cells, hydrogen storage), soft matter, biology and nano-science (nano-scale confinement, functionalized polymers). Such a large impact can be achieved using only a moderate investment. (authors)

Invited Article: Characterization of background sources in space-based time-of-flight mass spectrometers

International Nuclear Information System (INIS)

Gilbert, J. A.; Gershman, D. J.; Gloeckler, G.; Lundgren, R. A.; Zurbuchen, T. H.; Orlando, T. M.; McLain, J.; Steiger, R. von

2014-01-01

For instruments that use time-of-flight techniques to measure space plasma, there are common sources of background signals that evidence themselves in the data. The background from these sources may increase the complexity of data analysis and reduce the signal-to-noise response of the instrument, thereby diminishing the science value or usefulness of the data. This paper reviews several sources of background commonly found in time-of-flight mass spectrometers and illustrates their effect in actual data using examples from ACE-SWICS and MESSENGER-FIPS. Sources include penetrating particles and radiation, UV photons, energy straggling and angular scattering, electron stimulated desorption of ions, ion-induced electron emission, accidental coincidence events, and noise signatures from instrument electronics. Data signatures of these sources are shown, as well as mitigation strategies and design considerations for future instruments

Biomechanics of the immediate impact of wearing a rigid thoracolumbar corset on gait kinematics and spatiotemporal parameters

Directory of Open Access Journals (Sweden)

Taiar Redha

2018-01-01

Full Text Available The corset support is a device classified as orthosis. It compensates a functional deficiency with means of protection, recovery, correction, maintenance, and support or contention. There are two types of orthosis 1 rest orthosis and 2 corrective orthosis. Rest orthosis maintains joints in a defined position to avoid deformities or to relieve a pain at joints. Corrective orthosis adjusts joint deformity either passively or actively. Corset is used in various pathological use, thoracic-lumbar fracture, scoliosis, Scheuermann’s disease or spinal dystrophy. The purpose of this study was 1 to determine the immediate impact of wearing a semi-rigid thoracolumbar corset, the Lombax® Dorso on gait kinematics and 2 spatiotemporal parameters in 6 adults. These parameters were recorded using the optoelectronic system Vicon® on treadmill gait subjects with and without corset for the comparison. The results showed that wearing a corset significantly decrease the rotation amplitudes of the scapular and pelvic girdles (p<0.05 in the frontal plane. The movement of the pelvis and hip in this same plane was decreased also when comparing with and without a corset effects (p<0.05. The corset significantly increased the range of flexion-extension of the hip during the gait cycle. At the conclusion of this study the discriminate parameters of wearing a corset was quantified. The results and in association with manufacturer will help to improve materials for better optimization support. Comparable perspectives and after improvement of materials will aim to experiment with patients on real daily life situation.

Description of CORSET: a computer program for quantitative x-ray fluorescence analysis

International Nuclear Information System (INIS)

Stohl, F.V.

1980-08-01

Quantitative x-ray fluorescence analysis requires a method of correcting for absorption and secondary fluorescence effects due to the sample matrix. The computer program CORSET carries out these corrections without requiring a knowledge of the spectral distribution of the x-ray source, and only requires one standard per element or one standard containing all the elements. Sandia's version of CORSET has been divided into three separate programs to fit Sandia's specific requirements for on-line analysis in a melt facility. The melt facility is used to fabricate new alloys with very variable compositions and requires very rapid analyses during a run. Therefore, the standards must be analyzed several days in advance. Program DAT1 is used to set up a permanent file consisting of all the data related to the standards. Program UNINT is used to set up a permanent file with the intensities, background counts and counting times of the unknowns. Program CORSET uses the files created in UNINT and DAT1 to carry out the analysis. This report contains descriptions, listings, and sample runs for these programs. The accuracy of the analyses carried out with these three programs is about 1 to 2% relative with an elemental concentration of about 10 wt %

Data recording programme for a time-of-flight neutron spectrometer

International Nuclear Information System (INIS)

Smit, J.G.

1975-04-01

A modular program was written for the acquisition of the measurement data of a rotating crystal neutron spectrometer in a PDP-11/20 computer (16 K core memory). The modules are subroutines called by the higher-order FORTRAN programs. This program, which is carried out under the version 08/02 disk operating system, collects the data of a maximum number of 7 detectors in the core memory via interrupts in the on line mode. The detectors are connected to a time-of-flight unit which assigns the time and the detector number to the signals (minimum width of time channel 0.5 μs). From the T.O.F. unit the signals are passed on to the computer via a CAMAC input register and the CA-11 a branch driver manufactured by DEC. All the measurement data can be graphically displayed on a Tektronix visual display unit (keyboard interrupt). Relevant data are stored on disk and passed on to the central computer (S 4004) for further processing at the end of the experiment. (orig./RF) [de

Neutron time-of-flight counters and spectrometers for diagnostics of burning fusion plasmas

International Nuclear Information System (INIS)

Elevant, T.; Olsson, M.

1991-02-01

Experiment with burning fusion plasmas in tokamaks will place particular requirements on neutron measurements from radiation resistance-, physics-, burn control- and reliability considerations. The possibility to meet these needs by measurements of neutron fluxes and energy spectra by means of time-of-flight techniques are described. Reference counters and spectrometers are proposed and characterized with respect to efficiency, count-rate capabilities, energy resolution and tolerable neutron and γ-radiation background levels. The instruments can be used in a neutron camera and are capable to operate in collimated neutron fluxes up to levels corresponding to full nuclear output power in the next generation of experiments. Energy resolutions of the spectrometers enables determination of ion temperatures from 3 (keV) through analysis of the Doppler broadening. Primarily, the instruments are aimed for studies of 14 (MeV) neutrons produced in (d,t)-plasmas but can, after minor modifications, be used for analysis of 2.45 (MeV) neutrons produced in (d,d)-plasma. (au) (33 refs.)

LUMBAR CORSETS CAN DECREASE LUMBAR MOTION IN GOLF SWING

Directory of Open Access Journals (Sweden)

Koji Hashimoto

2013-03-01

Full Text Available Swinging a golf club includes the rotation and extension of the lumbar spine. Golf-related low back pain has been associated with degeneration of the lumbar facet and intervertebral discs, and with spondylolysis. Reflective markers were placed directly onto the skin of 11young male amateur golfers without a previous history of back pain. Using a VICON system (Oxford Metrics, U.K., full golf swings were monitored without a corset (WOC, with a soft corset (SC, and with a hard corset (HC, with each subject taking 3 swings. Changes in the angle between the pelvis and the thorax (maximum range of motion and angular velocity in 3 dimensions (lumbar rotation, flexion-extension, and lateral tilt were analyzed, as was rotation of the hip joint. Peak changes in lumbar extension and rotation occurred just after impact with the ball. The extension angle of the lumbar spine at finish was significantly lower under SC (38° or HC (28° than under WOC (44° conditions (p < 0.05. The maximum angular velocity after impact was significantly smaller under HC (94°/sec than under SC (177°/sec and WOC (191° /sec conditions, as were the lumbar rotation angles at top and finish. In contrast, right hip rotation angles at top showed a compensatory increase under HC conditions. Wearing a lumbar corset while swinging a golf club can effectively decrease lumbar extension and rotation angles from impact until the end of the swing. These effects were significantly enhanced while wearing an HC

Design and realization of a space-borne reflectron time of flight mass spectrometer: electronics and measuring head

International Nuclear Information System (INIS)

Devoto, P.

2006-03-01

The purpose of this thesis is the design of the electronics of a time of flight mass spectrometer, the making and the vacuum tests of a prototype which can be put onboard a satellite. A particular effort was necessary to decrease to the maximum the mass and electric consumption of the spectrometer, which led to the development of new circuits. The work completed during this thesis initially concerns the electronics of the measuring equipment which was conceived in a concern for modularity. A complete 'reflectron' type mass spectrometer was then designed, simulated and developed. The built prototype, which uses the developed electronics, was exposed to ion flows of different masses and energies in the CESR vacuum chambers. Its measured performances validate the implemented principles and show that an identical mass spectrometer can be put onboard a satellite with profit, for planetary or solar missions. (author)

Time-of-flight small-angle scattering spectrometers on pulsed neutron sources

International Nuclear Information System (INIS)

Ostanevich, Yu.M.

1987-01-01

The operation principles, constructions, advantages and shortcomings of known time-of-flight small angle neutron scattering (TOF SANS) spectrometers built up with pulsed neutron sources are reviewed. The most important characteristics of TOF SANS apparatuses are rather a high luminosity and the possibility for the measurement in an extremely wide range of scattering vector at a single exposure. This is achieved by simultaneous employment of white beam, TOF technique for wave length-scan and the commonly known angle-scan. However, the electronic equipment, data-matching programs, and the measurement procedure, necessary for accurate normalization of experimental data and their transformation into absolute cross-section scale, they all become more complex, as compared with those for SANS apparatuses operating on steady-state neutron sources, where only angle-scan is used

A multiple-orbit time-of-flight mass spectrometer based on a low energy electrostatic storage ring

Science.gov (United States)

Sullivan, M. R.; Spanjers, T. L.; Thorn, P. A.; Reddish, T. J.; Hammond, P.

2012-11-01

The results are presented for an electrostatic storage ring, consisting of two hemispherical deflector analyzers (HDA) connected by two separate sets of cylindrical lenses, used as a time-of-flight mass spectrometer. Based on the results of charged particle simulations and formal matrix model, the Ion Storage Ring is capable of operating with multiple stable orbits, for both single and multiply charged ions simultaneously.

Design of a reflex time-of-flight mass spectrometer for the study of the desorption of molecular ions

International Nuclear Information System (INIS)

Riggi, F.

1991-01-01

A reflex time-of-flight mass spectrometer for the study of the desorption and dissociation of molecular ions has been designed. A general overview of the instrument is reported, together with the different experimental aspects of the technique. These include mechanical and vacuum solutions, secondary ion optics in the electrostatic mirror, electronics, data acquisition and analysis

A Time of flight spectrometer for measurements of double differential neutron scattering cross sections

International Nuclear Information System (INIS)

Padron, I.; Dominguez, O.; Sarria, P. Sandin, C.

1996-01-01

The time -of-Flight neutron spectrometry technique by associated particle method was improved using a D-T neutron generator at Laboratory of Nuclear Analysis. This technique was implemented for double differential cross section measurements and supported by the IAEA Project CUB/01/005. An stilbene scintillation detector (dia=100 mm, length=50 mm) was used as principal neutron detector detector and was situated outside a hole in the concrete wall. This way the fligth path was extended and the scattered neutron cone accurate collimated throught the 2 m concrete wall. For the associated particle α detection a thin plastic NE-102 scint illator was used, as well as, two scintilation detectors and a long counter for the neutron flux monitoring. In this TOF neutron spectrometer (3.40 m flight path) a 1.7 nseg. temporal resolution was obtained

Investigation of the ion beam of the Titan source by the time-of-flight mass spectrometer

International Nuclear Information System (INIS)

Bugaev, A.S.; Gushenets, V.V.; Nikolaev, A.G.; Yushkov, G.Yu.

2000-01-01

The Titan ion source generates wide-aperture beams of both gaseous and metal ions of various materials. The above possibility is realized on the account of combining two types of arc discharge with cold cathodes in the source discharge system. The vacuum arc, initiated between the cathode accomplished from the ion forming material, and hollow anode, is used for obtaining the metal ions. The pinch-effect low pressure arc discharge, ignited on the same hollow anode, is used for obtaining gaseous ions. The composition of ion beams, generated by the Titan source through the specially designed time-of-flight spectrometer, is studied. The spectrometer design and principle pf operation are presented. The physical peculiarities of the source functioning, influencing the ion beam composition, are discussed [ru

A real time scintillating fiber Time of Flight spectrometer for LINAC photoproduced neutrons

Science.gov (United States)

Maspero, M.; Berra, A.; Conti, V.; Giannini, G.; Ostinelli, A.; Prest, M.; Vallazza, E.

2015-03-01

The use of high-energy (> 8 MeV) LINear ACcelerators (LINACs) for medical cancer treatments causes the photoproduction of secondary neutrons, whose unwanted dose to the patient has to be calculated. The characterization of the neutron spectra is necessary to allow the dosimetric evaluation of the neutron beam contamination. The neutron spectrum in a hospital environment is usually measured with integrating detectors such as bubble dosimeters, Thermo Luminescent Dosimeters (TLDs) or Bonner Spheres, which integrate the information over a time interval and an energy one. This paper presents the development of a neutron spectrometer based on the Time of Flight (ToF) technique in order to perform a real time characterization of the neutron contamination. The detector measures the neutron spectrum exploiting the fact that the LINAC beams are pulsed and arranged in bunches with a rate of 100-300 Hz depending on the beam type and energy. The detector consists of boron loaded scintillating fibers readout by a MultiAnode PhotoMultiplier Tube (MAPMT). A detailed description of the detector and the acquisition system together with the results in terms of ToF spectra and number of neutrons with a Varian Clinac iX are presented.

An Improvement on Space Focusing Resolution in Two-Field Time-of-Flight Mass Spectrometers

International Nuclear Information System (INIS)

Yildirim, M.; Aydin, R.; Akin, U.; Kilic, H. S.; Sise, O.; Ulu, M.; Dogan, M.

2007-01-01

Time-of-Flight Mass Spectrometer (TOFMS) is a sophisticated device for the mass selective analysis of a variety of samples. The main limitation on TOFMS technique is the obtainable resolution where the two main limiting factors are the initial space and energy spread of particles created in ionization region. Similar charged particles starting at different points will reach the detector at different times. So, this problem makes space focusing is very important subject. We have presented principles of two-fields TOFMS with second-order space focusing both using analytical methods and ray-tracing simulation. This work aims understanding of ion optical system clearly and gives hint of expectation for future developments

The 2.5-MeV neutron time-of-flight spectrometer TOFOR for experiments at JET

International Nuclear Information System (INIS)

Gatu Johnson, M.; Giacomelli, L.; Hjalmarsson, A.

2007-08-01

A time-of-flight (TOF) spectrometer for measurement of the 2.5-MeV neutron emission from fusion plasmas has been developed and put into use at the JET tokamak. It has been optimized for operation at high rates (TOFOR) for the purpose of performing advanced neutron emission spectroscopy (NES) diagnosis of deuterium plasmas with a focus on the fuel ion motional states for different auxiliary heating scenarios. This requires operation over a large dynamic range including high rates of >100 kHz with a maximum value of 0.5 MHz for the TOFOR design. This paper describes the design principles and their technical realization. The performance is illustrated with recent neutron time-of-flight spectra recorded for plasmas subjected to different heating scenarios. A data acquisition rate of 39 kHz has been achieved at about a tenth of the expected neutron yield limit of JET, giving a projected maximum of 400 kHz at peak JET plasma yield. This means that the count rate capability for NES diagnosis of D plasmas has been improved more than an order of magnitude. Another important performance factor is the spectrometer bandwidth where data have been acquired and analyzed successfully with a response function for neutrons over the energy range 1 to >5 MeV. The implications of instrumental advancement represented by TOFOR are discussed

The 2.5-MeV neutron time-of-flight spectrometer TOFOR for experiments at JET

Energy Technology Data Exchange (ETDEWEB)

Gatu Johnson, M.; Giacomelli, L.; Hjalmarsson, A. (and others)

2007-08-15

A time-of-flight (TOF) spectrometer for measurement of the 2.5-MeV neutron emission from fusion plasmas has been developed and put into use at the JET tokamak. It has been optimized for operation at high rates (TOFOR) for the purpose of performing advanced neutron emission spectroscopy (NES) diagnosis of deuterium plasmas with a focus on the fuel ion motional states for different auxiliary heating scenarios. This requires operation over a large dynamic range including high rates of >100 kHz with a maximum value of 0.5 MHz for the TOFOR design. This paper describes the design principles and their technical realization. The performance is illustrated with recent neutron time-of-flight spectra recorded for plasmas subjected to different heating scenarios. A data acquisition rate of 39 kHz has been achieved at about a tenth of the expected neutron yield limit of JET, giving a projected maximum of 400 kHz at peak JET plasma yield. This means that the count rate capability for NES diagnosis of D plasmas has been improved more than an order of magnitude. Another important performance factor is the spectrometer bandwidth where data have been acquired and analyzed successfully with a response function for neutrons over the energy range 1 to >5 MeV. The implications of instrumental advancement represented by TOFOR are discussed.

A high-efficiency spin-resolved photoemission spectrometer combining time-of-flight spectroscopy with exchange-scattering polarimetry

Energy Technology Data Exchange (ETDEWEB)

Jozwiak, Chris M.; Graff, Jeff; Lebedev, Gennadi; Andresen, Nord; Schmid, Andreas; Fedorov, Alexei; El Gabaly, Farid; Wan, Weishi; Lanzara, Alessandra; Hussain, Zahid

2010-04-13

We describe a spin-resolved electron spectrometer capable of uniquely efficient and high energy resolution measurements. Spin analysis is obtained through polarimetry based on low-energy exchange scattering from a ferromagnetic thin-film target. This approach can achieve a similar analyzing power (Sherman function) as state-of-the-art Mott scattering polarimeters, but with as much as 100 times improved efficiency due to increased reflectivity. Performance is further enhanced by integrating the polarimeter into a time-of-flight (TOF) based energy analysis scheme with a precise and flexible electrostatic lens system. The parallel acquisition of a range of electron kinetic energies afforded by the TOF approach results in an order of magnitude (or more) increase in efficiency compared to hemispherical analyzers. The lens system additionally features a 90 degrees bandpass filter, which by removing unwanted parts of the photoelectron distribution allows the TOF technique to be performed at low electron drift energy and high energy resolution within a wide range of experimental parameters. The spectrometer is ideally suited for high-resolution spin- and angle-resolved photoemission spectroscopy (spin-ARPES), and initial results are shown. The TOF approach makes the spectrometer especially ideal for time-resolved spin-ARPES experiments.

A time-of-flight spectrometer for neutron diffraction under high pressure or at high temperature

International Nuclear Information System (INIS)

Roult, G.; Buevoz, J.L.

1975-01-01

For high pressure neutron diffraction studies (40 kilobars) the sample is placed in a very thick cell. In order to allow the neutron beam to go through the cell loosing as little intensity as possible, the inner part is kept solid while the external part has some windows facing the incident and reflected beam. The window dimensions are small (a few millimeters wide and a few centimeters long). There are two alternatives: to have the window either in a perpendicular plane or in a plane parallel to the axis. In the first case a fixed wavelength spectrometer can be used but the sample is small and the contribution of the cell to the diffraction pattern is relatively great. In the second case samples can be something like ten times greater and the cell contribution can be eliminated but a fixed wavelength spectrometer cannot be used. Thus the time-of-flight method is very convenient. The second alternative was chosen

Low-pressure, multistep, multiwire proportional counter for the time-of-flight isochronous spectrometer

International Nuclear Information System (INIS)

Vieira, D.J.

1985-01-01

A low-pressure, multistep, multiwire proportional counter (MSMWPC) has been developed for the characterization and testing of the time-of-flight isochronous (TOFI) spectrometer and its associated secondary-beam transport line. This type of counter was selected because of its high sensitivity, large dynamic range, and good position (0.2 mm FWHM) and timing (180 ps FWHM) resolution. Furthermore, because the counter operates at low gas pressures (1-10 torr) and high electric-field strengths, which enable short collection times, it can be used as a transmission counter with thin gas-isolation windows and it can operate at high counting rates. Here the authors discuss the basic operating principle of the MSMWPC, describe the technical details of the detector and signal processing, and report on the performance they have measured for alpha particles and fission fragments

Modelling the line shape of very low energy peaks of positron beam induced secondary electrons measured using a time of flight spectrometer

International Nuclear Information System (INIS)

Fairchild, A J; Chirayath, V A; Gladen, R W; Chrysler, M D; Koymen, A R; Weiss, A H

2017-01-01

In this paper, we present results of numerical modelling of the University of Texas at Arlington’s time of flight positron annihilation induced Auger electron spectrometer (UTA TOF-PAES) using SIMION® 8.1 Ion and Electron Optics Simulator. The time of flight (TOF) spectrometer measures the energy of electrons emitted from the surface of a sample as a result of the interaction of low energy positrons with the sample surface. We have used SIMION® 8.1 to calculate the times of flight spectra of electrons leaving the sample surface with energies and angles dispersed according to distribution functions chosen to model the positron induced electron emission process and have thus obtained an estimate of the true electron energy distribution. The simulated TOF distribution was convolved with a Gaussian timing resolution function and compared to the experimental distribution. The broadening observed in the simulated TOF spectra was found to be consistent with that observed in the experimental secondary electron spectra of Cu generated as a result of positrons incident with energy 1.5 eV to 901 eV, when a timing resolution of 2.3 ns was assumed. (paper)

Dustbuster: a New Generation Impact-ionization Time-of-flight Mass Spectrometer for in situ Analysis of Cosmic Dust

Science.gov (United States)

Austin, D. E.; Ahrens, T. J.; Beauchamp, J. L.

2000-10-01

We have developed and tested a small impact-ionization time-of-flight mass spectrometer for analysis of cosmic dust, suitable for use on deep space missions. This mass spectrometer, named Dustbuster, incorporates a large target area and a reflectron, simultaneously optimizing mass resolution, sensitivity, and collection efficiency. Dust particles hitting the 65-cm2 target plate are partially ionized. The resulting ions are accelerated through a modified reflectron that focuses the ions in space and time to produce high-resolution spectra. The instrument, shown below, measures 10 x 10 x 20 cm, has a mass of 500 g, and consumes little power. Laser desorption ionization of metal and mineral samples (embedded in the impact plate) simulates particle impacts for instrument performance tests. Mass resolution in these experiments is near 200, permitting resolution of isotopes. The mass spectrometer can be combined with other instrument components to determine dust particle trajectories and sizes. This project was funded by NASA's Planetary Instrument Definition and Development Program.

Rapid high-resolution spin- and angle-resolved photoemission spectroscopy with pulsed laser source and time-of-flight spectrometer

Science.gov (United States)

Gotlieb, K.; Hussain, Z.; Bostwick, A.; Lanzara, A.; Jozwiak, C.

2013-09-01

A high-efficiency spin- and angle-resolved photoemission spectroscopy (spin-ARPES) spectrometer is coupled with a laboratory-based laser for rapid high-resolution measurements. The spectrometer combines time-of-flight (TOF) energy measurements with low-energy exchange scattering spin polarimetry for high detection efficiencies. Samples are irradiated with fourth harmonic photons generated from a cavity-dumped Ti:sapphire laser that provides high photon flux in a narrow bandwidth, with a pulse timing structure ideally matched to the needs of the TOF spectrometer. The overall efficiency of the combined system results in near-EF spin-resolved ARPES measurements with an unprecedented combination of energy resolution and acquisition speed. This allows high-resolution spin measurements with a large number of data points spanning multiple dimensions of interest (energy, momentum, photon polarization, etc.) and thus enables experiments not otherwise possible. The system is demonstrated with spin-resolved energy and momentum mapping of the L-gap Au(111) surface states, a prototypical Rashba system. The successful integration of the spectrometer with the pulsed laser system demonstrates its potential for simultaneous spin- and time-resolved ARPES with pump-probe based measurements.

Design of combined magnetic field system for magnetic-bottle time-of-flight spectrometer

International Nuclear Information System (INIS)

Wang Chao; Tian Jinshou; Zhang Meizhi; Kang Yifan

2011-01-01

Based on the primary requirement for the magnetic field system in magnetic-bottle time-of-flight spectrometer, an appropriate combined inhomogeneous magnetic field system is designed. The inhomogeneous higher magnetic field part, with the highest field of 1.2 T, is produced by the combination of a permanent magnet and a pole piece with optimized shape. The magnet,known as NdFeB magnet,is one of rare earth permanent magnets in N52. The guiding uniform magnetic field of 1.0 x 10 -3 T is provided by solenoid, with length of 3 m and radius of 3 cm. The pitch between the pole piece and the near end of used solenoid is determined to be 5 cm, which can satisfy the actual engineering needs. (authors)

Study of the nuclear reactions 208Pb + 58Ni and 208Pb + 64Ni with a focusing time-of-flight spectrometer

International Nuclear Information System (INIS)

Sapotta, K.

1983-01-01

In the first part of this thesis the construction of a time-of-flight spectrometer for heavy ions with magnetic focusing is described. Then ion trajectories are calculated, and the effective spatial angle and the angular resolution are determined. In the second part the study of quasielastic transfer and deep inelastic reactions of 58 Ni and 64 Ni with 208 Pb at E=265 MeV respectively 260 MeV by means of this spectrometer is described. (HSI) [de

A new time of flight mass spectrometer for absolute dissociative electron attachment cross-section measurements in gas phase

Science.gov (United States)

Chakraborty, Dipayan; Nag, Pamir; Nandi, Dhananjay

2018-02-01

A new time of flight mass spectrometer (TOFMS) has been developed to study the absolute dissociative electron attachment (DEA) cross section using a relative flow technique of a wide variety of molecules in gas phase, ranging from simple diatomic to complex biomolecules. Unlike the Wiley-McLaren type TOFMS, here the total ion collection condition has been achieved without compromising the mass resolution by introducing a field free drift region after the lensing arrangement. The field free interaction region is provided for low energy electron molecule collision studies. The spectrometer can be used to study a wide range of masses (H- ion to few hundreds atomic mass unit). The mass resolution capability of the spectrometer has been checked experimentally by measuring the mass spectra of fragment anions arising from DEA to methanol. Overall performance of the spectrometer has been tested by measuring the absolute DEA cross section of the ground state SO2 molecule, and the results are satisfactory.

Optimizing a neutron-beam focusing device for the direct geometry time-of-flight spectrometer TOFTOF at the FRM II reactor source

DEFF Research Database (Denmark)

Rasmussen, N. G.; Simeoni, G. G.; Lefmann, K.

2016-01-01

A dedicated beam-focusing device has been designed for the direct geometry thermal-cold neutron time-of-flight spectrometer TOFTOF at the neutron facility FRM II (Garching, Germany). The prototype, based on the compressed Archimedes' mirror concept, benefits from the adaptive-optics technology (a...... than 3.5 would have only marginal influence on the optimal behaviour, whereas comparable spectrometers could take advantage of longer focusing segments, with particular impact for the thermal region of the neutron spectrum....

Conceptual design of the time-of-flight backscattering spectrometer, MIRACLES, at the European Spallation Source

Energy Technology Data Exchange (ETDEWEB)

Tsapatsaris, N., E-mail: nikolaos.tsapatsaris@esss.se, E-mail: ruep.lechner@gmail.com, E-mail: bordallo@nbi.ku.dk; Bordallo, H. N., E-mail: nikolaos.tsapatsaris@esss.se, E-mail: ruep.lechner@gmail.com, E-mail: bordallo@nbi.ku.dk [Niels Bohr Institute, The University of Copenhagen, Copenhagen 2100 (Denmark); European Spallation Source ERIC, Tunavägen 24, 22100 Lund (Sweden); Lechner, R. E., E-mail: nikolaos.tsapatsaris@esss.se, E-mail: ruep.lechner@gmail.com, E-mail: bordallo@nbi.ku.dk [European Spallation Source ERIC, Tunavägen 24, 22100 Lund (Sweden); Markó, M. [Neutron Spectroscopy Department, Wigner Research Centre for Physics, H-1525 Budapest (Hungary)

2016-08-15

In this work, we present the conceptual design of the backscattering time-of-flight spectrometer MIRACLES approved for construction at the long-pulse European Spallation Source (ESS). MIRACLES’s unparalleled combination of variable resolution, high flux, extended energy, and momentum transfer (0.2–6 Å{sup −1}) ranges will open new avenues for neutron backscattering spectroscopy. Its remarkable flexibility can be attributed to 3 key elements: the long-pulse time structure and low repetition rate of the ESS neutron source, the chopper cascade that tailors the moderator pulse in the primary part of the spectrometer, and the bent Si(111) analyzer crystals arranged in a near-backscattering geometry in the secondary part of the spectrometer. Analytical calculations combined with instrument Monte-Carlo simulations show that the instrument will provide a variable elastic energy resolution, δ(ħ ω), between 2 and 32 μeV, when using a wavelength of λ ≈ 6.267 Å (Si(111)-reflection), with an energy transfer range, ħ ω, centered at the elastic line from −600 to +600 μeV. In addition, when selecting λ ≈ 2.08 Å (i.e., the Si(333)-reflection), δ(ħ ω) can be relaxed to 300 μeV and ħ ω from about 10 meV in energy gain to ca −40 meV in energy loss. Finally, the dynamic wavelength range of MIRACLES, approximately 1.8 Å, can be shifted within the interval of 2–20 Å to allow the measurement of low-energy inelastic excitations.

Conceptual design of the time-of-flight backscattering spectrometer, MIRACLES, at the European Spallation Source

International Nuclear Information System (INIS)

Tsapatsaris, N.; Bordallo, H. N.; Lechner, R. E.; Markó, M.

2016-01-01

In this work, we present the conceptual design of the backscattering time-of-flight spectrometer MIRACLES approved for construction at the long-pulse European Spallation Source (ESS). MIRACLES’s unparalleled combination of variable resolution, high flux, extended energy, and momentum transfer (0.2–6 Å"−"1) ranges will open new avenues for neutron backscattering spectroscopy. Its remarkable flexibility can be attributed to 3 key elements: the long-pulse time structure and low repetition rate of the ESS neutron source, the chopper cascade that tailors the moderator pulse in the primary part of the spectrometer, and the bent Si(111) analyzer crystals arranged in a near-backscattering geometry in the secondary part of the spectrometer. Analytical calculations combined with instrument Monte-Carlo simulations show that the instrument will provide a variable elastic energy resolution, δ(ħ ω), between 2 and 32 μeV, when using a wavelength of λ ≈ 6.267 Å (Si(111)-reflection), with an energy transfer range, ħ ω, centered at the elastic line from −600 to +600 μeV. In addition, when selecting λ ≈ 2.08 Å (i.e., the Si(333)-reflection), δ(ħ ω) can be relaxed to 300 μeV and ħ ω from about 10 meV in energy gain to ca −40 meV in energy loss. Finally, the dynamic wavelength range of MIRACLES, approximately 1.8 Å, can be shifted within the interval of 2–20 Å to allow the measurement of low-energy inelastic excitations.

A high-resolution time-of-flight spectrometer for fission fragments and ion beams

International Nuclear Information System (INIS)

Kosev, Krasimir Milchev

2007-01-01

For the purpose of fission-fragment detection a double time-of-flight (TOF) spectrometer has been developed. The key component of the TOF spectrometer is a TOF detector consisting of multichannel-plate (MCP) detectors with a position-sensitive readout, a foil for secondary electron (SE) production and an electrostatic mirror. The fission fragments are detected by measuring the SEs impinging on the position-sensitive anode after emission from the foil, acceleration and deflection by the electrostatic mirror. The functionality of the different detector components is proven in detail. Optimised schemes for the high-voltage supplies of the MCP detectors have been implemented successfully. In order to process the multichannel-plate detector signals optimally, a new state-of-the-art constant-fraction discriminator based on the amplitude and rise time compensated technique with very low threshold capabilities and optimised walk properties has been developed and incorporated into the setup. In a setup consisting of two mirror MCP detectors, we could successfully observe the TOF spectrum of a mixed ( 226 Ra, 222 Rn, 210 Po, 218 Po, 214 Po) α-source. Testing photo-fission experiments were performed at the bremsstrahlung facility at the ELBE accelerator. The setup consisted of two mirror detectors (first arm) and a 80 mm diameter MCP detector (second arm) with a 238 U target positioned in between. TOF measurements with two bremsstrahlung end-point energies of 12.9 and 16.0 MeV were carried out. A clear cut separation of the TOF peaks for the medium-mass and heavy fission fragments was observed. (orig.)

A high-resolution time-of-flight spectrometer for fission fragments and ion beams

Energy Technology Data Exchange (ETDEWEB)

Kosev, Krasimir Milchev

2007-07-01

For the purpose of fission-fragment detection a double time-of-flight (TOF) spectrometer has been developed. The key component of the TOF spectrometer is a TOF detector consisting of multichannel-plate (MCP) detectors with a position-sensitive readout, a foil for secondary electron (SE) production and an electrostatic mirror. The fission fragments are detected by measuring the SEs impinging on the position-sensitive anode after emission from the foil, acceleration and deflection by the electrostatic mirror. The functionality of the different detector components is proven in detail. Optimised schemes for the high-voltage supplies of the MCP detectors have been implemented successfully. In order to process the multichannel-plate detector signals optimally, a new state-of-the-art constant-fraction discriminator based on the amplitude and rise time compensated technique with very low threshold capabilities and optimised walk properties has been developed and incorporated into the setup. In a setup consisting of two mirror MCP detectors, we could successfully observe the TOF spectrum of a mixed ({sup 226}Ra,{sup 222}Rn,{sup 210}Po,{sup 218}Po,{sup 214}Po) {alpha}-source. Testing photo-fission experiments were performed at the bremsstrahlung facility at the ELBE accelerator. The setup consisted of two mirror detectors (first arm) and a 80 mm diameter MCP detector (second arm) with a {sup 238}U target positioned in between. TOF measurements with two bremsstrahlung end-point energies of 12.9 and 16.0 MeV were carried out. A clear cut separation of the TOF peaks for the medium-mass and heavy fission fragments was observed. (orig.)

High-performance multiple-reflection time-of-flight mass spectrometers for research with exotic nuclei and for analytical mass spectrometry

Science.gov (United States)

Plaß, Wolfgang R.; Dickel, Timo; Ayet San Andres, Samuel; Ebert, Jens; Greiner, Florian; Hornung, Christine; Jesch, Christian; Lang, Johannes; Lippert, Wayne; Majoros, Tamas; Short, Devin; Geissel, Hans; Haettner, Emma; Reiter, Moritz P.; Rink, Ann-Kathrin; Scheidenberger, Christoph; Yavor, Mikhail I.

2015-11-01

A class of multiple-reflection time-of-flight mass spectrometers (MR-TOF-MSs) has been developed for research with exotic nuclei at present and future accelerator facilities such as GSI and FAIR (Darmstadt), and TRIUMF (Vancouver). They can perform highly accurate mass measurements of exotic nuclei, serve as high-resolution, high-capacity mass separators and be employed as diagnostics devices to monitor the production, separation and manipulation of beams of exotic nuclei. In addition, a mobile high-resolution MR-TOF-MS has been developed for in situ applications in analytical mass spectrometry ranging from environmental research to medicine. Recently, the MR-TOF-MS for GSI and FAIR has been further developed. A novel RF quadrupole-based ion beam switchyard has been developed that allows merging and splitting of ion beams as well as transport of ions into different directions. It efficiently connects a test and reference ion source and an auxiliary detector to the system. Due to an increase in the kinetic energy of the ions in the time-of-flight analyzer of the MR-TOF-MS, a given mass resolving power is now achieved in less than half the time-of-flight. Conversely, depending on the time-of-flight, the mass resolving power has been increased by a factor of more than two.

Precision measurements with the multi-reflection time-of-flight mass spectrometer of ISOLTRAP at ISOLDE/CERN

Energy Technology Data Exchange (ETDEWEB)

Atanasov, Dinko; Ascher, Pauline; Borgmann, Christopher; Boehm, Christine; Eliseev, Sergey; Eronen, Tommi; George, Sebastian; Kisler, Dmitry; Naimi, Sarah [Max-Planck-Institut fuer Kernphysik, Saupfercheckweg 1, 69117 Heidelberg (Germany); Beck, Dietrich; Herfurth, Frank; Litvinov, Yuri; Minaya Ramirez, Enrique; Neidherr, Dennis [GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, Planckstr. 1, 64291 Darmstadt (Germany); Breitenfeldt, Martin [Instituut voor Kern- en Stralingsfysica, Celestijnenlaan 200d - bus 2418, 3001 Heverlee (Belgium); Cakirli, Burcu [University of Istanbul, Department of Physics, 34134 Istanbul (Turkey); Cocolios, Thomas Elias [University of Manchester, Manchester (United Kingdom); Herlert, Alexander Josef [FAIR GmbH, Planckstr. 1, D-64291 Darmstadt (Germany); Kowalska, Magdalena [CERN, Geneva 23, 1211 Geneva (Switzerland); Kreim, Susanne [Max-Planck-Institut fuer Kernphysik, Saupfercheckweg 1, 69117 Heidelberg (Germany); CERN, Geneva 23, 1211 Geneva (Switzerland); Lunney, David; Manea, Vladimir [CSNSM-IN2P3-CNRS, 91405 Orsay Campus, Bat. 104, 108 (France); Rosenbusch, Marco; Schweikhard, Lutz; Wienholtz, Frank; Wolf, Robert [Ernst-Moritz-Arndt-Universitaet, Institut fuer Physik, Felix-Hausdorff-Str. 6, 17487 Greifswald (Germany); Stanja, Juliane; Zuber, Kai [Institut fuer Kern- und Teilchenphysik, Technische Universitaet Dresden, Zellescher Weg 19, 01069 Dresden (Germany)

2014-07-01

The masses of exotic nuclides are among the most important input parameters for modern nuclear theory and astrophysical models. At the high-precision Penning-trap mass spectrometer ISOLTRAP at ISOLDE/CERN, a multi-reflection time-of-flight mass spectrometer (MR-ToF-MS) in combination with a Bradbury-Nielsen gate (BNG) can be used to achieve high-resolution isobar purification with mass-resolving powers of 105 in a few tens of milliseconds. Furthermore, the MR-ToF device can be used as a spectrometer to determine the masses of nuclides with very low yields and short half-lives, where a Penning-trap mass measurement becomes impractical due to the lower transport efficiency and decay losses during the purification and measurement cycles. Recent cross-check experiments show that the MR-ToF MS allows mass measurements with uncertainties in the sub-ppm range. In a first application the mass measurements of the nuclides 53,54Ca was performed, delivered with production rates as low as 10/s and half-lives of only 90(6) ms. The nuclides serve as important benchmarks for testing modern chiral effective theory with realistic 3-body forces. The contribution presents the on-line mass spectrometer ISOLTRAP focusing on the new applications, which became possible after the implementation of the MR-ToF MS into the current setup. In particular, the mass measurements of the neutron-rich calcium isotopes up to A=54 are discussed. In addition, measurements of the isotonic potassium isotopes are reported.

SHMS Hodoscopes and Time of Flight System

Science.gov (United States)

Craycraft, Kayla; Malace, Simona

2017-09-01

As part of the Thomas Jefferson National Accelerator Facility's (Jefferson Lab) upgrade from 6 GeV to 12 GeV, a new magnetic focusing spectrometer, the Super High Momentum Spectrometer (SHMS), was installed in experimental Hall C. The detector stack consists of horizontal drift chambers for tracking, gas Cerenkov and Aerogel detectors and a lead glass calorimeter for particle identification. A hodoscope system consisting of three planes of scintillator detectors (constructed by James Madison University) and one plane of quartz bars (built by North Carolina A&T State University) is used for triggering and time of flight measurements. This presentation consists of discussion of the installation, calibration, and characterization of the detectors used in this Time of Flight system. James Madison University, North Carolina A&T State University.

A real-time neutron-gamma discriminator based on the support vector machine method for the time-of-flight neutron spectrometer

Science.gov (United States)

Wei, ZHANG; Tongyu, WU; Bowen, ZHENG; Shiping, LI; Yipo, ZHANG; Zejie, YIN

2018-04-01

A new neutron-gamma discriminator based on the support vector machine (SVM) method is proposed to improve the performance of the time-of-flight neutron spectrometer. The neutron detector is an EJ-299-33 plastic scintillator with pulse-shape discrimination (PSD) property. The SVM algorithm is implemented in field programmable gate array (FPGA) to carry out the real-time sifting of neutrons in neutron-gamma mixed radiation fields. This study compares the ability of the pulse gradient analysis method and the SVM method. The results show that this SVM discriminator can provide a better discrimination accuracy of 99.1%. The accuracy and performance of the SVM discriminator based on FPGA have been evaluated in the experiments. It can get a figure of merit of 1.30.

Time lens for high-resolution neutron time-of-flight spectrometers

International Nuclear Information System (INIS)

Baumann, K.; Gaehler, R.; Grigoriev, P.; Kats, E.I.

2005-01-01

We examine in analytic and numeric ways the imaging effects of temporal neutron lenses created by traveling magnetic fields. For fields of parabolic shape we derive the imaging equations, investigate the time magnification, the evolution of the phase-space element, the gain factor, and the effect of finite beam size. The main aberration effects are calculated numerically. The system is technologically feasible and should convert neutron time-of-flight instruments from pinhole to imaging configuration in time, thus enhancing intensity and/or time resolution. Further fields of application for high-resolution spectrometry may be opened

Corset Usage for Gastrointestinal and Respiratory Problems in a Newborn with Prune Belly Syndrome.

Science.gov (United States)

Satar, Mehmet; Özlü, Ferda; Yapıcıoğlu, Hacer; İskit, Serdar

2016-07-01

Prune Belly syndrome (PBS), comprises a triad of anomalies that include abdominal wall flaccidity, urologic anomalies and bilateral cryptorchidism in males. The abdominal musculature hypoplasia predisposes to respiratory problems, respiratory infections secondary to impaired cough mechanism, and cause chronic constipation secondary to ineffective valsalva ability. Here, the authors present a newborn baby with Prune Belly syndrome who had respiratory and gastrointestinal problems which resolved after corset use. To the authors knowledge, this is the first case of corset usage in the treatment of PBS in a newborn infant.

A neutron spectrometer based on the combination of time-of-flight and Larmor modulation

International Nuclear Information System (INIS)

Mulder, F.M.; Kreuger, R.; Grigoriev, S.V.; Kraan, W.H.; Rekveldt, M.Th.; Van Well, A.A.

1999-01-01

A study on the feasibility of neutron beam instrumentation that applies Larmor modulation for incoming, and time-of-flight for scattered wavelength determination (or vice versa) is currently under way at IRI. The instrument resulting from this combination can in principle measure quasi elastic and inelastic scattering with a flexible resolution and dynamic range. An important difference with current spectrometers is that there is no selection of neutron wavelengths for either the incoming beam (direct geometry) or scattered beam (inverted geometry). Therefore much of the available flux is used and there is no a priory selection of the energy transfer range and resolution. This instrument will be mainly applicable for quasi-elastic scattering and complex line shapes that are extended over a broad range in energy transfer. Line shapes can be measured directly in Fourier space, which is often advantageous. Due to signal to noise considerations, this instrument will be less suitable for the determination of weak, discrete energy transfer signals. A requirement for the Larmor modulator is that it can work with a white neutron beam. This can be realised for neutrons having a wavelength above ∼ 0.1 nm by use of 'adiabatic resonance π flippers'. This type of instrument may be applied at the future ESS pulsed neutron source in order to complement current spectrometers. (author)

Rocket flight performance of a preprototype Apollo 17 UV spectrometer S-169

Science.gov (United States)

Fastie, W. G.

1971-01-01

The design, construction, testing, calibration, flight performance and flight data of an Ebert ultraviolet spectrometer are described which is an accurate representation of the conceptual design of the Apollo 17 UV spectrometer. The instrument was flown in an Aerobee 350 rocket from Wallops Island, Va., at 7:10 p.m. EDT on June 10, 1971 to an altitude of 328 km with a solar elevation angle of about 11 deg.

Linear electric field time-of-flight ion mass spectrometer

Science.gov (United States)

Funsten, Herbert O [Los Alamos, NM; Feldman, William C [Los Alamos, NM

2008-06-10

A linear electric field ion mass spectrometer having an evacuated enclosure with means for generating a linear electric field located in the evacuated enclosure and means for injecting a sample material into the linear electric field. A source of pulsed ionizing radiation injects ionizing radiation into the linear electric field to ionize atoms or molecules of the sample material, and timing means determine the time elapsed between ionization of atoms or molecules and arrival of an ion out of the ionized atoms or molecules at a predetermined position.

In-line monitoring of effluents from HTGR fuel particle preparation processes using a time-of-flight mass spectrometer

International Nuclear Information System (INIS)

Lee, D.A.; Costanzo, D.A.; Stinton, D.P.; Carpenter, J.A.; Rainey, W.T. Jr.; Canada, D.C.; Carter, J.A.

1976-08-01

The carbonization, conversion, and coating processes in the manufacture of HTGR fuel particles have been studied with the use of a time-of-flight mass spectrometer. Non-condensable effluents from these fluidized-bed processes have been monitored continuously from the beginning to the end of the process. The processes which have been monitored are these: uranium-loaded ion exchange resin carbonization, the carbothermic reduction of UO 2 to UC 2 , buffer and low temperature isotropic pyrocarbon coatings of fuel kernels, SiC coating of the kernels, and high-temperature particle annealing. Changes in concentrations of significant molecules with time and temperature have been useful in the interpretation of reaction mechanisms and optimization of process procedures

A homemade high-resolution orthogonal-injection time-of-flight mass spectrometer with a heated capillary inlet

International Nuclear Information System (INIS)

Guo Changjuan; Huang Zhengxu; Gao Wei; Nian Huiqing; Chen Huayong; Dong Junguo; Shen Guoying; Fu Jiamo; Zhou Zhen

2008-01-01

We describe a homemade high-resolution orthogonal-injection time-of-flight (O-TOF) mass spectrometer combing a heated capillary inlet. The O-TOF uses a heated capillary tube combined with a radio-frequency only quadrupole (rf-only quadrupole) as an interface to help the ion transmission from the atmospheric pressure to the low-pressure regions. The principle, configuration of the O-TOF, and the performance of the instrument are introduced in this paper. With electrospray ion source, the performances of the mass resolution, the sensitivity, the mass range, and the mass accuracy are described. We also include our results obtained by coupling atmospheric pressure matrix-assisted laser deporption ionization with this instrument

Cassini Ion Mass Spectrometer Peak Calibrations from Statistical Analysis of Flight Data

Science.gov (United States)

Woodson, A. K.; Johnson, R. E.

2017-12-01

The Cassini Ion Mass Spectrometer (IMS) is an actuating time-of-flight (TOF) instrument capable of resolving ion mass, energy, and trajectory over a field of view that captures nearly the entire sky. One of three instruments composing the Cassini Plasma Spectrometer, IMS sampled plasma throughout the Kronian magnetosphere from 2004 through 2012 when it was permanently disabled due to an electrical malfunction. Initial calibration of the flight instrument at Southwest Research Institute (SwRI) was limited to a handful of ions and energies due to time constraints, with only about 30% of planned measurements carried out prior to launch. Further calibration measurements were subsequently carried out after launch at SwRI and Goddard Space Flight Center using the instrument prototype and engineering model, respectively. However, logistical differences among the three calibration efforts raise doubts as to how accurately the post-launch calibrations describe the behavior of the flight instrument. Indeed, derived peak parameters for some ion species differ significantly from one calibration to the next. In this study we instead perform a statistical analysis on 8 years of flight data in order to extract ion peak parameters that depend only on the response of the flight instrument itself. This is accomplished by first sorting the TOF spectra based on their apparent compositional similarities (e.g. primarily water group ions, primarily hydrocarbon ions, etc.) and normalizing each spectrum. The sorted, normalized data are then binned according to TOF, energy, and counts in order to generate energy-dependent probability density maps of each ion peak contour. Finally, by using these density maps to constrain a stochastic peak fitting algorithm we extract confidence intervals for the model parameters associated with various measured ion peaks, establishing a logistics-independent calibration of the body of IMS data gathered over the course of the Cassini mission.

COMPARATIVE ANALYSIS OF THE TREATMENT OF THE EOSINOPHILIC GRANULOMA WITH VERTEBRAL INVOLVEMENT USING ORTHOPEDIC CORSET AND SURGICAL OPERATION

Directory of Open Access Journals (Sweden)

A. I. Snetkov

2010-01-01

Full Text Available The results of treatment of 72 patients with pathological fracture of vertebra bodies against eosinophilic granuloma a spine are analysed. Orthopedic corset technologies are used in treatment of 42 patients, surgical treatment was applied. Orthopedic corset may be used in patients with eosinophilic granuloma of backbone. This method of treatment was used in a case of the absence of spine secondary deformations and neurologic semiology. Orthopedic corset treatment is associated with long immobilization on the average within 1,5-2 years and never leads to a complete recovery of the damaged spine. Surgical treatment consists in use only at loss of height of a body to 30-40%, when destruction of spine more severe it is necessary to use operative treatment in two stages. Absolute indications to surgical treatment are the neurologic deficit and secondary deformations of a spine. Surgical treatment allows to reduce terms of treatment till 3-4 months and quickly to return the patient to an active life.

Tandem Mass Spectrometry on a Miniaturized Laser Desorption Time-of-Flight Mass Spectrometer

Science.gov (United States)

Li, Xiang; Cornish, Timothy; Getty, Stephanie A.; Brinckerhoff, William B.

2016-01-01

Tandem mass spectrometry (MSMS) is a powerful and widely-used technique for identifying the molecular structure of organic constituents of a complex sample. Application of MSMS to the study of unknown planetary samples on a remote space mission would contribute to our understanding of the origin, evolution, and distribution of extraterrestrial organics in our solar system. Here we report on the realization of MSMS on a miniaturized laser desorption time-of-flight mass spectrometer (LD-TOF-MS), which is one of the most promising instrument types for future planetary missions. This achievement relies on two critical components: a curved-field reflectron and a pulsed-pin ion gate. These enable use of the complementary post-source decay (PSD) and laser-assisted collision induced dissociation (L-CID) MSMS methods on diverse measurement targets with only modest investment in instrument resources such as volume and weight. MSMS spectra of selected molecular targets in various organic standards exhibit excellent agreement when compared with results from a commercial, laboratory-scale TOF instrument, demonstrating the potential of this powerful technique in space and planetary environments.

Quasielastic high-resolution time-of-flight spectrometers employing multi-disk chopper cascades for spallation sources

International Nuclear Information System (INIS)

Lechner, R.E.

2001-01-01

The design of multi-disk chopper time-of-flight (MTOF) spectrometers for high-resolution quasielastic and low-energy inelastic neutron scattering at spallation sources is discussed in some detail. A continuously variable energy resolution (1 μeV to 10 meV), and a large dynamic range (1 μeV to 100 meV), are outstanding features of this type of instrument, which are easily achieved also at a pulsed source using state-of-the-art technology. The method of intensity-resolution optimization of MTOF spectrometers at spallation sources is treated on the basis of the requirement of using (almost) 'all the neutrons of the pulse', taking into account the constant, but wavelength-dependent duration of the source pulse. It follows, that the optimization procedure (which is slightly different from that employed in the steady-state source case) should give priority to the highest resolution, whenever such a choice becomes necessary. This leads to long monochromator distances (L l2 ) of the order of 50 m, for achieving resolutions now available at reactor sources. A few examples of spectrometer layout and corresponding design parameters for large-angle and for small-angle quasielastic scattering instruments are given. In the latter case higher energy resolution than for large-angle scattering is required and achieved. The use of phase-space transformers, neutron wavelength band-pass filters and multichromatic operation for the purpose of intensity-resolution optimization are discussed. This spectrometer can be designed to make full use of the pulsed source peak flux. Therefore, and because of a number of improvements, high resolution will be available at high intensity: for any given resolution the total intensity at the detectors, when placed at one of the planned new spallation sources (SNS, JSNS, ESS, AUSTRON) will be larger by at least three orders of magnitude than the total intensity of any of the presently existing instruments of this type in routine operation at steady

Construction and simulation of a multi-reflection time-of-flight mass spectrometer at the University of Notre Dame

Energy Technology Data Exchange (ETDEWEB)

Schultz, B.E., E-mail: bschult4@nd.edu; Kelly, J.M.; Nicoloff, C.; Long, J.; Ryan, S.; Brodeur, M.

2016-06-01

One of the most significant problems in the production of rare isotopes is the simultaneous production of contaminants, often time isobaric. Thus, a high-resolution beam purification method is required which needs to be compatible with both the low yield and short half-life of the desired radionuclide. A multi-reflection time-of-flight mass spectrometer meets all these criteria, in addition to boasting a smaller footprint relative to traditional separator dipole magnets. Such a device is currently under construction at the University of Notre Dame and is intended to be coupled to the IG-ISOL source of the planned cyclotron facility. The motivation and conceptual design are presented, as well as the status of simulations to determine the feasibility of using a Bradbury–Nielsen gate for bunching ion beams during initial system testing.

The 2.5-MeV neutron time-of-flight spectrometer TOFOR for experiments at JET

International Nuclear Information System (INIS)

Gatu Johnson, M.; Giacomelli, L.; Hjalmarsson, A.; Kaellne, J.; Weiszflog, M.; Andersson Sunden, E.; Conroy, S.; Ericsson, G.; Hellesen, C.; Ronchi, E.; Sjoestrand, H.; Gorini, G.; Tardocchi, M.; Combo, A.; Cruz, N.; Sousa, J.; Popovichev, S.

2008-01-01

A time-of-flight (TOF) spectrometer for measurement of the 2.5-MeV neutron emission from fusion plasmas has been developed and put into use at the JET tokamak. It has been optimized for operation at high rates (TOFOR) for the purpose of performing advanced neutron emission spectroscopy (NES) diagnosis of deuterium plasmas with a focus on the fuel ion motional states for different auxiliary heating scenarios. This requires operation over a large dynamic range, including high rates of >100 kHz with a maximum value of 0.5 MHz for the TOFOR design. This paper describes the design principles and their technical realization. The performance is illustrated with recent neutron TOF spectra recorded for plasmas subjected to different heating scenarios. A true event count rate of 39 kHz has been achieved at about a tenth of the expected neutron yield limit of JET, giving a projected maximum of 400 kHz at peak JET plasma yield. This means that the count rate capability for NES diagnosis of D plasmas has been improved more than an order of magnitude. Another important performance factor is the spectrometer bandwidth, where data have been acquired and analyzed successfully with a response function for neutrons over the energy range 1 to >5 MeV. The implications of instrumental advancement represented by TOFOR are discussed

First spatial separation of a heavy ion isomeric beam with a multiple-reflection time-of-flight mass spectrometer

Science.gov (United States)

Dickel, T.; Plaß, W. R.; Ayet San Andres, S.; Ebert, J.; Geissel, H.; Haettner, E.; Hornung, C.; Miskun, I.; Pietri, S.; Purushothaman, S.; Reiter, M. P.; Rink, A.-K.; Scheidenberger, C.; Weick, H.; Dendooven, P.; Diwisch, M.; Greiner, F.; Heiße, F.; Knöbel, R.; Lippert, W.; Moore, I. D.; Pohjalainen, I.; Prochazka, A.; Ranjan, M.; Takechi, M.; Winfield, J. S.; Xu, X.

2015-05-01

211Po ions in the ground and isomeric states were produced via 238U projectile fragmentation at 1000 MeV/u. The 211Po ions were spatially separated in flight from the primary beam and other reaction products by the fragment separator FRS. The ions were energy-bunched, slowed-down and thermalized in a gas-filled cryogenic stopping cell (CSC). They were then extracted from the CSC and injected into a high-resolution multiple-reflection time-of-flight mass spectrometer (MR-TOF-MS). The excitation energy of the isomer and, for the first time, the isomeric-to-ground state ratio were determined from the measured mass spectrum. In the subsequent experimental step, the isomers were spatially separated from the ions in the ground state by an ion deflector and finally collected with a silicon detector for decay spectroscopy. This pioneering experimental result opens up unique perspectives for isomer-resolved studies. With this versatile experimental method new isomers with half-lives longer than a few milliseconds can be discovered and their decay properties can be measured with highest sensitivity and selectivity. These experiments can be extended to studies with isomeric beams in nuclear reactions.

Dual Source Time-of-flight Mass Spectrometer and Sample Handling System

Science.gov (United States)

Brinckerhoff, W.; Mahaffy, P.; Cornish, T.; Cheng, A.; Gorevan, S.; Niemann, H.; Harpold, D.; Rafeek, S.; Yucht, D.

We present details of an instrument under development for potential NASA missions to planets and small bodies. The instrument comprises a dual ionization source (laser and electron impact) time-of-flight mass spectrometer (TOF-MS) and a carousel sam- ple handling system for in situ analysis of solid materials acquired by, e.g., a coring drill. This DSTOF instrument could be deployed on a fixed lander or a rover, and has an open design that would accommodate measurements by additional instruments. The sample handling system (SHS) is based on a multi-well carousel, originally de- signed for Champollion/DS4. Solid samples, in the form of drill cores or as loose chips or fines, are inserted through an access port, sealed in vacuum, and transported around the carousel to a pyrolysis cell and/or directly to the TOF-MS inlet. Samples at the TOF-MS inlet are xy-addressable for laser or optical microprobe. Cups may be ejected from their holders for analyzing multiple samples or caching them for return. Samples are analyzed with laser desorption and evolved-gas/electron-impact sources. The dual ion source permits studies of elemental, isotopic, and molecular composition of unprepared samples with a single mass spectrometer. Pulsed laser desorption per- mits the measurement of abundance and isotope ratios of refractory elements, as well as the detection of high-mass organic molecules in solid samples. Evolved gas analysis permits similar measurements of the more volatile species in solids and aerosols. The TOF-MS is based on previous miniature prototypes at JHU/APL that feature high sensitivity and a wide mass range. The laser mode, in which the sample cup is directly below the TOF-MS inlet, permits both ablation and desorption measurements, to cover elemental and molecular species, respectively. In the evolved gas mode, sample cups are raised into a small pyrolysis cell and heated, producing a neutral gas that is elec- tron ionized and pulsed into the TOF-MS. (Any imaging

Investigation of the electron dynamics of Si(111) 7 x 7 and development of a time-of-flight spectrometer for time- and angle-resolved two-photon photoemission

International Nuclear Information System (INIS)

Damm, Andreas

2011-01-01

This thesis consists of two main parts. The first one reports about recent investigations of the electron dynamics on the Si(111) 7 x 7 surface employing time- and angle-resolved two-photon photoemission (2PPE). The second part describes the construction and demonstration of the capabilities of a new electron time-of-flight spectrometer. It is shown that the electron dynamics of this surface are governed by adatom and bulk states. Variation of different experimental parameters leads to the suggestion that electrons scatter from the adatom states into the conduction band of Silicon. The localization in real space can be estimated from the distribution of the photoemission intensity in momentum space to be within one 7 x 7 unit cell. The electron population in the conduction band as well as those in the adatom band show a very long-living component. In addition to recombination through defect states, these electrons can undergo radiative recombination with holes in the valence band. The second part of this thesis reports about the design, construction and demonstration of the capabilities of a new electron time-of-flight spectrometer for applications in time- and angle-resolved 2PPE experiments. The new spectrometer is designed in a flexible manner to maximize either the energy resolution or the acceptance angle, respectively. By employing a position-sensitive electron detector it is possible for the first time to measure the energy as well as all components of the parallel momentum of the photoemitted electrons and thereby to fully characterize electrons from surface states. The time-resolution can be estimated from the width of a peak induced by photons scattered from the sample to be better than 150 ps. At the minimum of about 40 mm of the adjustable drift distance this leads to a energy resolution below 5 meV for electrons with kinetic energies of 1 eV. Thereby, the parallel momentum resolution is below 5 mA -1 for parallel momentum values k parallel ≤1A -1

Design of the multi-reflection time-of-flight mass spectrometer for the RAON facility

International Nuclear Information System (INIS)

Yoon, J.W.; Park, Y.H.; Park, S.J.; Kim, G.D.; Kim, Y.K.

2014-01-01

A multi-reflection time-of-flight mass spectrometer (MR-TOF-MS) has been proposed for high precision mass measurements on the future Korean heavy ion accelerator called RAON. MR-TOF-MS will allow us to reach very high mass resolving power (> 10 5 ) with extremely short measurement times (several ms) in a compact device. The MR-TOF-MS is composed of two electrostatic ion mirrors in combination with einzel lenses. The principle is that the injected ions travel for hundreds of revolutions inside MR-TOF-MS and ions with different masses are temporally separated. When temporal separation becomes larger than the ion bunch width, ions are extracted from the MR-TOF-MS by switching off the mirror voltages, and then arrive at a detector plane located at time focus, where an MCP detector for the mass measurement or an ion gate for the isobar separation is deployed. In this paper, simulation results for the MR-TOF-MS design using SIMION code are presented. Temporal broadenings, caused by the kinetic energy spread and the transverse emittance, were minimized by optimization of the electrode potentials, and it was demonstrated that the mass resolving power of 10 5 is achievable for the condition of an energy spread of ±30 eV and an emittance of 0.75 π*mm*mrad

Angle-resolving time-of-flight electron spectrometer for near-threshold precision measurements of differential cross sections of electron-impact excitation of atoms and molecules

International Nuclear Information System (INIS)

Lange, M.; Matsumoto, J.; Setiawan, A.; Panajotovic, R.; Harrison, J.; Lower, J. C. A.; Newman, D. S.; Mondal, S.; Buckman, S. J.

2008-01-01

This article presents a new type of low-energy crossed-beam electron spectrometer for measuring angular differential cross sections of electron-impact excitation of atomic and molecular targets. Designed for investigations at energies close to excitation thresholds, the spectrometer combines a pulsed electron beam with the time-of-flight technique to distinguish between scattering channels. A large-area, position-sensitive detector is used to offset the low average scattering rate resulting from the pulsing duty cycle, without sacrificing angular resolution. A total energy resolution better than 150 meV (full width at half maximum) at scattered energies of 0.5-3 eV is achieved by monochromating the electron beam prior to pulsing it. The results of a precision measurement of the differential cross section for electron-impact excitation of helium, at an energy of 22 eV, are used to assess the sensitivity and resolution of the spectrometer

Optimized design of the chopper disks and the neutron guide in a disk chopper neutron time-of-flight spectrometer

International Nuclear Information System (INIS)

Copley, J.R.D.

1990-01-01

We consider important aspects of the performance of a disk chopper neutron time-of-flight spectrometer. The intensity at the sample position, and the contributions of the choppers to the resolution of the instrument, are evaluated as a function of the widths of the slots in the chopper disks and the width of the neutron guide between the disks. We find that there is an optimum choice of the ratios of these widths and that this choice depends on a single parameter which, for elastic scattering, is a simple ratio of distances. When pairs of counter-rotating disks are employed, the widths of the slots can be modified by grossly changing the phase relationship between the members of a chopper pair. If the slot widths are changed, the width of the guide should also be altered in order to maintain the spectrometer in an optimized state. This change in the guide width may be effectively achieved using an arrangement of nested guides. Resolution and intensity calculations demonstrate the important gains which may be realized using this approach. (orig.)

Time-of-flight detector with KBr working medium

International Nuclear Information System (INIS)

Arvanov, A.N.; Gavalyan, V.G.; Lorikyan, M.P.

1983-01-01

A detector of controlled secondary electron emission as a 3-electrode focusing electrostatic system of the photomultiplier input chamber having a microchannel electron plate herringbone assembly with the total gain of approXimately 10 7 is described. A controlled secondary emission emitter based on MgO or KBr is installed as a cathode. The detector is designed for time-of-flight spectrometers. The time resolution is < or approximately equal to 0.5 ns. The time-of-flight system realized on the base of such two detectors has 100% detection efficiency and it is ''transparent'' for an identified particle. Its characteristics for α particle, deuteron and proton detection are estimated

Compact Two-step Laser Time-of-Flight Mass Spectrometer for in Situ Analyses of Aromatic Organics on Planetary Missions

Science.gov (United States)

Getty, Stephanie; Brickerhoff, William; Cornish, Timothy; Ecelberger, Scott; Floyd, Melissa

2012-01-01

RATIONALE A miniature time-of-flight mass spectrometer has been adapted to demonstrate two-step laser desorption-ionization (LOI) in a compact instrument package for enhanced organics detection. Two-step LDI decouples the desorption and ionization processes, relative to traditional laser ionization-desorption, in order to produce low-fragmentation conditions for complex organic analytes. Tuning UV ionization laser energy allowed control ofthe degree of fragmentation, which may enable better identification of constituent species. METHODS A reflectron time-of-flight mass spectrometer prototype measuring 20 cm in length was adapted to a two-laser configuration, with IR (1064 nm) desorption followed by UV (266 nm) postionization. A relatively low ion extraction voltage of 5 kV was applied at the sample inlet. Instrument capabilities and performance were demonstrated with analysis of a model polycyclic aromatic hydrocarbon, representing a class of compounds important to the fields of Earth and planetary science. RESULTS L2MS analysis of a model PAH standard, pyrene, has been demonstrated, including parent mass identification and the onset o(tunable fragmentation as a function of ionizing laser energy. Mass resolution m/llm = 380 at full width at half-maximum was achieved which is notable for gas-phase ionization of desorbed neutrals in a highly-compact mass analyzer. CONCLUSIONS Achieving two-step laser mass spectrometry (L2MS) in a highly-miniature instrument enables a powerful approach to the detection and characterization of aromatic organics in remote terrestrial and planetary applications. Tunable detection of parent and fragment ions with high mass resolution, diagnostic of molecular structure, is possible on such a compact L2MS instrument. Selectivity of L2MS against low-mass inorganic salt interferences is a key advantage when working with unprocessed, natural samples, and a mechanism for the observed selectivity is presented.

Performance optimisation of a new-generation orthogonal-acceleration quadrupole-time-of-flight mass spectrometer.

Science.gov (United States)

Bristow, Tony; Constantine, Jill; Harrison, Mark; Cavoit, Fabien

2008-04-01

Orthogonal-acceleration quadrupole time-of-flight (oa-QTOF) mass spectrometers, employed for accurate mass measurement, have been commercially available for well over a decade. A limitation of the early instruments of this type was the narrow ion abundance range over which accurate mass measurements could be made with a high degree of certainty. Recently, a new generation of oa-QTOF mass spectrometers has been developed and these allow accurate mass measurements to be recorded over a much greater range of ion abundances. This development has resulted from new ion detection technology and improved electronic stability or by accurate control of the number of ions reaching the detector. In this report we describe the results from experiments performed to evaluate the mass measurement performance of the Bruker micrOTOF-Q, a member of the new-generation oa-QTOFs. The relationship between mass accuracy and ion abundance has been extensively evaluated and mass measurement accuracy remained stable (+/-1.5 m m/z units) over approximately 3-4 orders of magnitude of ion abundance. The second feature of the Bruker micrOTOF-Q that was evaluated was the SigmaFit function of the software. This isotope pattern-matching algorithm provides an exact numerical comparison of the theoretical and measured isotope patterns as an additional identification tool to accurate mass measurement. The smaller the value, the closer the match between theoretical and measured isotope patterns. This information is then employed to reduce the number of potential elemental formulae produced from the mass measurements. A relationship between the SigmaFit value and ion abundance has been established. The results from the study for both mass accuracy and SigmaFit were employed to define the performance criteria for the micrOTOF-Q. This provided increased confidence in the selection of elemental formulae resulting from accurate mass measurements.

Sensitivity of peak positions to flight-path parameters in a deep-inelastic scattering neutron TOF spectrometer

International Nuclear Information System (INIS)

Gray, E.MacA.; Chatzidimitriou-Dreismann, C.A.; Blach, T.P.

2012-01-01

The effects of small changes in flight-path parameters (primary and secondary flight paths, detector angles), and of displacement of the sample along the beam axis away from its ideal position, are examined for an inelastic time-of-flight (TOF) neutron spectrometer, emphasising the deep-inelastic regime. The aim was to develop a rational basis for deciding what measured shifts in the positions of spectral peaks could be regarded as reliable in the light of the uncertainties in the calibrated flight-path parameters. Uncertainty in the length of the primary or secondary flight path has the least effect on the positions of the peaks of H, D and He, which are dominated by the accuracy of the calibration of the detector angles. This aspect of the calibration of a TOF spectrometer therefore demands close attention to achieve reliable outcomes where the position of the peaks is of significant scientific interest and is discussed in detail. The corresponding sensitivities of the position of peak of the Compton profile, J(y), to flight-path parameters and sample position are also examined, focusing on the comparability across experiments of results for H, D and He. We show that positioning the sample to within a few mm of the ideal position is required to ensure good comparability between experiments if data from detectors at high forward angles are to be reliably interpreted.

The fusion-fission process in the reaction {sup 34}S+{sup 186}W near the interaction barrier

Energy Technology Data Exchange (ETDEWEB)

Harca, I. M. [Flerov Laboratory of Nuclear Reactions, Joint Institute for Nuclear Research, (FLNR JINR) Dubna, Russia and Faculty of Physics, University of Bucharest - P.O. Box MG 11, RO 77125, Bucharest-Magurele (Romania); Dmitriev, S.; Itkis, J.; Kozulin, E. M.; Knyazheva, G.; Loktev, T.; Novikov, K. [Flerov Laboratory of Nuclear Reactions, Joint Institute for Nuclear Research, (FLNR JINR) Dubna (Russian Federation); Azaiez, F.; Gottardo, A.; Matea, I.; Verney, D. [IPN, CNRS/IN2P3, Univ. Paris-Sud, 91405 Orsay (France); Chubarian, G. [Cyclotron Institute, Texas A and M University, College Station, TX 77843-3366 (United States); Hanappe, F. [Universite Libre de Bruxelles (ULB), Bruxelles (Belgium); Piot, J.; Schmitt, C. [GANIL, CEA/DSM-CNRS/IN2P3, Bd Henri Becquerel, BP 55027, F-14076 Caen Cedex 5 (France); Trzaska, W. H. [Accelerator Laboratory of University of Jyväskylä (JYFL), Jyväskylä (Finland); Vardaci, E. [Dipartamento di Scienze Fisiche and INFN (INFN-Na), Napoli (Italy)

2015-02-24

The reaction {sup 34}S+{sup 186}W at E{sub lab}=160 MeV was investigated with the aim of diving into the features of the fusion-fission process. Gamma rays in coincidence with binary reaction fragments were measured using the high efficiency gamma-ray spectrometer ORGAM at the TANDEM Accelerator facility of I.P.N., Orsay, and the time-of-flight spectrometer for fission fragments (FF) registration CORSET of the Flerov Laboratory of Nuclear Reactions (FLNR), Dubna. The coupling of the ORGAM and CORSET setups offers the unique opportunity of extracting details for characterizing the fusion-fission process and gives information regarding production of neutron-rich heavy nuclei. The FF–γ coincidence method is of better use then the γ – γ coincidence method when dealing with low statistic measurements and also offers the opportunity to precisely correct the Dopler shift for in-flight emitted gamma rays. Evidence of symmetric and asymmetric fission modes were observed in the mass and TKE distributions, occurring due to shell effects in the fragments. Coincident measurements allow for discrimination between the gamma rays by accepting a specific range within the mass distribution of the reaction products. Details regarding the experimental setup, methods of processing the acquisitioned data and preliminary results are presented.

An integrated ion trap and time-of-flight mass spectrometer for chemical and photo- reaction dynamics studies

International Nuclear Information System (INIS)

Schowalter, Steven J.; Chen Kuang; Rellergert, Wade G.; Sullivan, Scott T.; Hudson, Eric R.

2012-01-01

We demonstrate the integration of a linear quadrupole trap with a simple time-of-flight mass spectrometer with medium-mass resolution (m/Δm∼ 50) geared towards the demands of atomic, molecular, and chemical physics experiments. By utilizing a novel radial ion extraction scheme from the linear quadrupole trap into the mass analyzer, a device with large trap capacity and high optical access is realized without sacrificing mass resolution. This provides the ability to address trapped ions with laser light and facilitates interactions with neutral background gases prior to analyzing the trapped ions. Here, we describe the construction and implementation of the device as well as present representative ToF spectra. We conclude by demonstrating the flexibility of the device with proof-of-principle experiments that include the observation of molecular-ion photodissociation and the measurement of trapped-ion chemical reaction rates.

Development of a Portable Single Photon Ionization-Photoelectron Ionization Time-of-Flight Mass Spectrometer

Directory of Open Access Journals (Sweden)

Yunguang Huang

2015-01-01

Full Text Available A vacuum ultraviolet lamp based single photon ionization- (SPI- photoelectron ionization (PEI portable reflecting time-of-flight mass spectrometer (TOFMS was designed for online monitoring gas samples. It has a dual mode ionization source: SPI for analyte with ionization energy (IE below 10.6 eV and PEI for IE higher than 10.6 eV. Two kinds of sampling inlets, a capillary inlet and a membrane inlet, are utilized for high concentration and trace volatile organic compounds, respectively. A mass resolution of 1100 at m/z 64 has been obtained with a total size of 40 × 31 × 29 cm, the weight is 27 kg, and the power consumption is only 70 W. A mixture of benzene, toluene, and xylene (BTX, SO2, and discharging products of SF6 were used to test its performance, and the result showed that the limit of quantitation for BTX is as low as 5 ppbv (S/N = 10 : 1 with linear dynamic ranges greater than four orders of magnitude. The portable TOFMS was also evaluated by analyzing volatile organic compounds from wine and decomposition products of SF6 inside of a gas-insulated switchgear.

An integrated ion trap and time-of-flight mass spectrometer for chemical and photo- reaction dynamics studies.

Science.gov (United States)

Schowalter, Steven J; Chen, Kuang; Rellergert, Wade G; Sullivan, Scott T; Hudson, Eric R

2012-04-01

We demonstrate the integration of a linear quadrupole trap with a simple time-of-flight mass spectrometer with medium-mass resolution (m/Δm ∼ 50) geared towards the demands of atomic, molecular, and chemical physics experiments. By utilizing a novel radial ion extraction scheme from the linear quadrupole trap into the mass analyzer, a device with large trap capacity and high optical access is realized without sacrificing mass resolution. This provides the ability to address trapped ions with laser light and facilitates interactions with neutral background gases prior to analyzing the trapped ions. Here, we describe the construction and implementation of the device as well as present representative ToF spectra. We conclude by demonstrating the flexibility of the device with proof-of-principle experiments that include the observation of molecular-ion photodissociation and the measurement of trapped-ion chemical reaction rates. © 2012 American Institute of Physics

Action spectroscopy of SrCl{sup +} using an integrated ion trap time-of-flight mass spectrometer

Energy Technology Data Exchange (ETDEWEB)

Puri, Prateek, E-mail: teek24@ucla.edu; Schowalter, Steven J.; Hudson, Eric R. [Department of Physics and Astronomy, University of California, Los Angeles, California 90095 (United States); Kotochigova, Svetlana; Petrov, Alexander [Department of Physics, Temple University, Philadelphia, Pennsylvania 19122 (United States)

2014-07-07

The photodissociation cross-section of SrCl{sup +} is measured in the spectral range of 36 000–46 000 cm{sup −1} using a modular time-of-flight mass spectrometer (TOF-MS). By irradiating a sample of trapped SrCl{sup +} molecular ions with a pulsed dye laser, X{sup 1}Σ{sup +} state molecular ions are electronically excited to the repulsive wall of the A{sup 1}Π state, resulting in dissociation. Using the TOF-MS, the product fragments are detected and the photodissociation cross-section is determined for a broad range of photon energies. Detailed ab initio calculations of the SrCl{sup +} molecular potentials and spectroscopic constants are also performed and are found to be in good agreement with experiment. The spectroscopic constants for SrCl{sup +} are also compared to those of another alkaline earth halogen, BaCl{sup +}, in order to highlight structural differences between the two molecular ions. This work represents the first spectroscopy and ab initio calculations of SrCl{sup +}.

Development of the STEFF detector for the neutron Time Of Flight facility (n_TOF), CERN

CERN Document Server

AUTHOR|(CDS)2092031

Signicant work has been performed on the development of STEFF (SpecTrometer for Exotic Fission Fragments), a 2E2V (2-Energy 2-Velocity) spectrometer built by the University of Manchester Fission Group. The majority of this work was in the development of the time-of-flight systems, in particular the stop detector; with the main goals of improving the timing resolution and the detection eciency of the ssion fragments. Further development of the STEFF spectrometer was done to enable 2E2V measurements of the $^{235}$U(n,f) reaction with coincident measurements using a white neutron spectra of energies ranging from 10 meV to 200 MeV provided by the n_TOF (neutron Time Of Flight) facility, CERN. The STEFF spectrometer was successfully operated twice on the Experimental Area-2 high flux pulsed neutron beam line resulting in 2E2V measurements for ssion events with neutron energies ranging from 20 meV to 10 MeV. The first experiment received 1.36 X 10$^{18}$ POT (Protons On Target) with stable conditions and the seco...

Time-of-flight data acquisition unit (DAU) for neutron scattering experiments. Specification of the requirements and design concept. Version 3.1

International Nuclear Information System (INIS)

Herdam, G.; Klessmann, H.; Wawer, W.; Adebayo, J.; David, G.; Szatmari, F.

1989-12-01

This specification describes the requirements for the Data Acquisition Unit (DAU) and defines the design concept for the functional units involved. The Data Acquisition Unit will be used in the following neutron scattering experiments: Time-of-Flight Spectrometer NEAT, Time-of-Flight Spectrometer SPAN. In addition, the data of the SPAN spectrometer in Spin Echo experiments will be accumulated. The Data Acquisition Unit can be characterised by the following requirements: Time-of-flight measurement with high time resolution (125 ns), sorting the time-of-flight in up to 4096 time channels (channel width ≥ 1 μs), selection of different time channel widths for peak and background, on-line time-of-flight correction for neutron flight paths of different lengths, sorting the detector position information in up to 4096 position channels, accumulation of two-dimensional spectra in a 32 Mbyte RAM memory (4 K time channels*4 K position channels*16 bits). Because of the stringent timing requirements the functional units of the DAU are hardware controlled via tables. The DAU is part of a process control system which has access to the functional units via the VMEbus in order to initialise, to load tables and control information, and to read status information and spectra. (orig.) With 18 figs

HYSPEC: A crystal time-of-flight hybrid spectrometer for the spallation neutron source with polarization capabilities

International Nuclear Information System (INIS)

Shapiro, S.M.; Zaliznyak, I.A.; Passell, L.; Ghosh, V.J.; Leonhardt, W.J.; Hagen, M.E.

2006-01-01

The hybrid spectrometer (HYSPEC) is a unique direct geometry inelastic scattering instrument under construction at the spallation neutron source (SNS). It combines the intensity enhancement features of focusing Bragg crystals with time-of-flight energy analysis. It will be located at beam-line 14B, which views a coupled liquid hydrogen moderator. A neutron beam from the moderator will travel along a curved guide, through a Fermi chopper and will then be focused onto a sample in an external building, 39 m from the source. In this configuration the intensity at the sample position is more than an order of magnitude larger than for other planned inelastic instrument. A movable detector bank 4.5 m from the sample will cover an angular range of 60 deg. in the horizontal plane and 15 deg. in the vertical direction. An important feature of HYSPEC is the ability to do neutron polarization analysis experiments. A Heusler crystal, which polarizes the neutron beam, can be used as the focusing crystal and a series of bender analyzers will analyze the polarization of the scattered beam

Digitizing data acquisition and time-of-flight pulse processing for ToF-ERDA

Energy Technology Data Exchange (ETDEWEB)

Julin, Jaakko, E-mail: jaakko.julin@jyu.fi; Sajavaara, Timo

2016-01-01

A versatile system to capture and analyze signals from multi channel plate (MCP) based time-of-flight detectors and ionization based energy detectors such as silicon diodes and gas ionization chambers (GIC) is introduced. The system is based on commercial digitizers and custom software. It forms a part of a ToF-ERDA spectrometer, which has to be able to detect recoil atoms of many different species and energies. Compared to the currently used analogue electronics the digitizing system provides comparable time-of-flight resolution and improved hydrogen detection efficiency, while allowing the operation of the spectrometer be studied and optimized after the measurement. The hardware, data acquisition software and digital pulse processing algorithms to suit this application are described in detail.

LVGEMS Time-of-Flight Mass Spectrometry on Satellites

Science.gov (United States)

Herrero, Federico

2013-01-01

NASA fs investigations of the upper atmosphere and ionosphere require measurements of composition of the neutral air and ions. NASA is able to undertake these observations, but the instruments currently in use have their limitations. NASA has extended the scope of its research in the atmosphere and now requires more measurements covering more of the atmosphere. Out of this need, NASA developed multipoint measurements using miniaturized satellites, also called nanosatellites (e.g., CubeSats), that require a new generation of spectrometers that can fit into a 4 4 in. (.10 10 cm) cross-section in the upgraded satellites. Overall, the new mass spectrometer required for the new depth of atmospheric research must fulfill a new level of low-voltage/low-power requirements, smaller size, and less risk of magnetic contamination. The Low-Voltage Gated Electrostatic Mass Spectrometer (LVGEMS) was developed to fulfill these requirements. The LVGEMS offers a new spectrometer that eliminates magnetic field issues associated with magnetic sector mass spectrometers, reduces power, and is about 1/10 the size of previous instruments. LVGEMS employs the time of flight (TOF) technique in the GEMS mass spectrometer previously developed. However, like any TOF mass spectrometer, GEMS requires a rectangular waveform of large voltage amplitude, exceeding 100 V -- that means that the voltage applied to one of the GEMS electrodes has to change from 0 to 100 V in a time of only a few nanoseconds. Such electronic speed requires more power than can be provided in a CubeSat. In the LVGEMS, the amplitude of the rectangular waveform is reduced to about 1 V, compatible with digital electronics supplies and requiring little power.

Development of a hand-portable photoionization time-of-flight mass spectrometer

International Nuclear Information System (INIS)

Dieckman, S.L.; Bostrom, G.A.; Waterfield, L.G.; Jendrzejczyk, J.A.; Raptis, A.C.

1996-01-01

ANL is currently developing a portable chemical sensor system based on laser desorption photoionization time-of-flight mass spectrometry. It will incorporate direct sampling, a cryocooler base sample adsorption and concentration, and direct surface multiphoton ionization. All components will be in a package 9 x 11 x 4 in., weighing 15-18 lbs. A sample spectrum is given for a NaCl sample

Position sensitive detection coupled to high-resolution time-of-flight mass spectrometry: Imaging for molecular beam deflection experiments

International Nuclear Information System (INIS)

Abd El Rahim, M.; Antoine, R.; Arnaud, L.; Barbaire, M.; Broyer, M.; Clavier, Ch.; Compagnon, I.; Dugourd, Ph.; Maurelli, J.; Rayane, D.

2004-01-01

We have developed and tested a high-resolution time-of-flight mass spectrometer coupled to a position sensitive detector for molecular beam deflection experiments. The major achievement of this new spectrometer is to provide a three-dimensional imaging (X and Y positions and time-of-flight) of the ion packet on the detector, with a high acquisition rate and a high resolution on both the mass and the position. The calibration of the experimental setup and its application to molecular beam deflection experiments are discussed

High precision mass measurements of thermalized relativistic uranium projectile and fission fragments with a multiple-reflection time-of-flight mass spectrometer

Energy Technology Data Exchange (ETDEWEB)

Ayet San Andres, Samuel [GSI Helmholtzzentrum fuer Schwerionenforschung, Darmstadt (Germany); Justus Liebig Universitaet, Giessen (Germany); Collaboration: FRS Ion Catcher-Collaboration

2016-07-01

At the FRS Ion Catcher at GSI, a relativistic beam of {sup 238}U at 1GeV/u was used to produce fission and projectile fragments on a beryllium target. The ions were separated in-flight at the FRS, thermalized in a cryogenic stopping cell and transferred to a multiple-reflection time-of-flight mass spectrometer (MR-TOF-MS) where high precision mass measurements were performed. The masses of several fission and projectile fragments were measured (including short-lived nuclei with half-lives down to 18 ms) and the possibility of tailoring an isomerically clean beam for other experiments was demonstrated. With the demonstrated performance of the MR-TOF-MS and the expected production rates of exotic nuclei far from stability at the next-generation facilities such as FAIR, novel mass measurements of nuclei close to the neutron drip line will be possible and key information for understanding the r-process will be available. The results from the last experiment and an outlook of possible future mass measurements close to the neutron drip line at FAIR with the MR-TOF-MS are presented.

Applicability of a two-step laser desorption-ionization aerosol time-of-flight mass spectrometer for determination of chemical composition of ultrafine aerosol particles

Energy Technology Data Exchange (ETDEWEB)

Laitinen, T.

2013-11-01

This thesis is based on the construction of a two-step laser desorption-ionization aerosol time-of-flight mass spectrometer (laser AMS), which is capable of measuring 10 to 50 nm aerosol particles collected from urban and rural air at-site and in near real time. The operation and applicability of the instrument was tested with various laboratory measurements, including parallel measurements with filter collection/chromatographic analysis, and then in field experiments in urban environment and boreal forest. Ambient ultrafine aerosol particles are collected on a metal surface by electrostatic precipitation and introduced to the time-of-flight mass spectrometer (TOF-MS) with a sampling valve. Before MS analysis particles are desorbed from the sampling surface with an infrared laser and ionized with a UV laser. The formed ions are guided to the TOF-MS by ion transfer optics, separated according to their m/z ratios, and detected with a micro channel plate detector. The laser AMS was used in urban air studies to quantify the carbon cluster content in 50 nm aerosol particles. Standards for the study were produced from 50 nm graphite particles, suspended in toluene, with 72 hours of high power sonication. The results showed the average amount of carbon clusters (winter 2012, Helsinki, Finland) in 50 nm particles to be 7.2% per sample. Several fullerenes/fullerene fragments were detected during the measurements. In boreal forest measurements, the laser AMS was capable of detecting several different organic species in 10 to 50 nm particles. These included nitrogen-containing compounds, carbon clusters, aromatics, aliphatic hydrocarbons, and oxygenated hydrocarbons. A most interesting event occurred during the boreal forest measurements in spring 2011 when the chemistry of the atmosphere clearly changed during snow melt. On that time concentrations of laser AMS ions m/z 143 and 185 (10 nm particles) increased dramatically. Exactly at the same time, quinoline concentrations

Antimatter search with AMS (Alpha Magnetic Spectrometer) during STS-91 precursor flight

International Nuclear Information System (INIS)

Alpat, Behcet

2000-01-01

The Alpha Magnetic Spectrometer (AMS) is designed to study the antimatter, matter and dark matter in space. AMS successfully flown on space shuttle Discovery during precursor flight STS-91 in a 51.7 degree sign orbit at altitudes between 320 and 390 km. No antimatter nuclei with Z ≥ 2 were detected. In this report we present the AMS performances during shuttle flight and we give new limits on antimatter/matter flux ratio

Charged particle scintillation mass spectrometer

International Nuclear Information System (INIS)

Baranov, P.S.; Zhuravlev, E.E.; Nafikov, A.A.; Osadchi , A.I.; Raevskij, V.G.; Smirnov, P.A.; Cherepnya, S.N.; Yanulis, Yu.P.

1982-01-01

A scintillation mass-spectrometer for charged particle identification by the measured values of time-of-flight and energy operating on line with the D-116 computer is described. Original time detectors with 100x100x2 mm 3 and 200x2 mm 2 scintillators located on the 1- or 2 m path length are used in the spectrometer. The 200x200x200 mm 3 scintillation unit is used as a E-counter. Time-of-flight spectra of the detected particles on the 2 m path length obtained in spectrometer test in the beam of charged particles escaping from the carbon target at the angle of 130 deg under 1.2 GeV bremsstrahlung beam of the ''Pakhra'' PIAS synchrotron are presented. Proton and deuteron energy spectra as well as mass spectrum of all the particles detected by the spectrometer are given. Mass resolution obtained on the 2 m path length for π-mesons is +-25%, for protons is +-5%, for deuterons is +-3%

The advantages of orthogonal acceleration in ICP time-of-flight mass spectrometry

International Nuclear Information System (INIS)

Gaal, Andrew

2004-01-01

The OptiMass 8000 incorporates an orthogonal acceleration time-of-flight mass spectrometer. A general schematic of the instrument is given. The continuous ion beam is chopped by an orthogonal accelerator. A push out pulse supply is coupled to the accelerator for providing repetitive push-out voltages at a frequency of 30 kHz. The ion packets that are sliced out of the beam then travel within the field free space towards the SMARTGATE ion blanker. Orthogonal accelerator parameters are set to enable temporal-spatial focusing at the SMARTGATE ion blanker, so that iso-mass ion packets are resolved in time. Any ion packets of unwanted specie are ejected from the direction of travel by supplying pulsed voltages onto the deflection plates of the SMARTGATE. The ions to be measured are let through SMARTGATE and travel further down the field free space, to enter the ion reflectron. The ion reflectron increases the resolution of the mass spectrometer by means of temporal-energy focussing. After reflection, the ions travel within the field free space towards the discrete-dynode detector. In comparison to other acceleration geometries used in elemental time-of-flight mass spectrometry the OptiMass 8000 orthogonal acceleration geometry ultimately leads to superior resolution. As the energy spread is about 3 orders of magnitude lower in the time-of-flight direction for an oaTOFMS in comparison to an on-axis system, aberration acquired in the initial stages of acceleration are much lower. As a result the orthogonal acceleration scheme provides superior resolution at the first spatial focus point and the detector. The orthogonal acceleration time-of-flight analyzer of the OptiMass 8000 is able to provide resolution of at least 1800 at mass 238. (author)

Characterization of a time-of-flight mass spectrometer and its applications in the study of solid surfaces; Charakterisierung eines Flugzeitmassenspektrometers und seine Anwendungen in der Festkoerperoberflaechenuntersuchung

Energy Technology Data Exchange (ETDEWEB)

Mazarov, P.

2006-12-21

The object and the purpose of the present work was to develop, to assemble and to start running a new TOF (time of flight) mass spectrometer for imaging SNMS analytic which is optimized for the analysis of highly molecular secondary ions. The most important purpose was the characterization of the TOF mass spectrometer. The obtained mass spectra of indium, tantalum and silver clusters reflect the excellent properties of the TOF mass spectrometer for the detection of large clusters with good detection efficiency up to masses of 16000 amu. The possibility of the deflection of selected saturated atom and cluster peaks serves for further improvement of the detection efficiency for large molecules. The accessible mass resolution was determined to be of the order of m/{delta}m=1000 in the high mass region. Numerous measurements were carried out to characterize the useful yield of this spectrometer. For a best possible adaptation of the TOF mass spectrometer for the detection of highly molecular particles, a device for post-acceleration of the detected particles by up to 10 keV were inserted directly before the MCP detector. The detection efficiency of positive secondary ions was determined for different post-acceleration voltages for the example of sputtered indium cluster ions. In addition, a new method was developed for the quantitative determination of the spectral ionization probability {alpha}{sup +}({nu}) of sputtered particles as a function of the emission velocity. The next application of the TOF mass spectrometer is the analysis of complicated organic molecules in solid state surfaces. During measurements of the photo-ionization behaviour of neutral tryptophan molecules, it was found out that a stable molecular ion signal is generated in the SNMS spectrum with h{nu}=7.9 eV can only be observed by the use of a continuous ion beam or very long (ms range) ion pulses. (orig.)

High-throughput shotgun lipidomics by quadrupole time-of-flight mass spectrometry

DEFF Research Database (Denmark)

Ståhlman, Marcus; Ejsing, Christer S.; Tarasov, Kirill

2009-01-01

Technological advances in mass spectrometry and meticulous method development have produced several shotgun lipidomic approaches capable of characterizing lipid species by direct analysis of total lipid extracts. Shotgun lipidomics by hybrid quadrupole time-of-flight mass spectrometry allows...... the absolute quantification of hundreds of molecular glycerophospholipid species, glycerolipid species, sphingolipid species and sterol lipids. Future applications in clinical cohort studies demand detailed lipid molecule information and the application of high-throughput lipidomics platforms. In this review...... we describe a novel high-throughput shotgun lipidomic platform based on 96-well robot-assisted lipid extraction, automated sample infusion by mircofluidic-based nanoelectrospray ionization, and quantitative multiple precursor ion scanning analysis on a quadrupole time-of-flight mass spectrometer...

Residual stress analysis by neutron time-of-flight at a reactor source

International Nuclear Information System (INIS)

Priesmeyer, H.G.; Schroder, J.

1990-01-01

Non-destructive neutron diffractometry for stress analysis will be a powerful experimental tool in material science research performed at the GKSS 5 MW reactor FRG-1. Arguments which show the advantages of the time-of-flight method are given and a suitable high-resolution neutron-efficient type of spectrometer is introduced. First results derived from this method are presented

Optimizing a neutron-beam focusing device for the direct geometry time-of-flight spectrometer TOFTOF at the FRM II reactor source

Energy Technology Data Exchange (ETDEWEB)

Rasmussen, N.G. [Nanoscience Center, Niels Bohr Institute, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen Ø (Denmark); Simeoni, G.G., E-mail: ggsimeoni@outlook.com [Heinz Maier-Leibnitz Zentrum (MLZ) and Physics Department, Technical University of Munich, D-85748 Garching (Germany); Lefmann, K. [Nanoscience Center, Niels Bohr Institute, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen Ø (Denmark)

2016-04-21

A dedicated beam-focusing device has been designed for the direct geometry thermal-cold neutron time-of-flight spectrometer TOFTOF at the neutron facility FRM II (Garching, Germany). The prototype, based on the compressed Archimedes' mirror concept, benefits from the adaptive-optics technology (adjustable supermirror curvature) and the compact size (only 0.5 m long). We have simulated the neutron transport across the entire guide system. We present a detailed computer characterization of the existing device, along with the study of the factors mostly influencing the future improvement. We have optimized the simulated prototype as a function of the neutron wavelength, accounting also for all relevant features of a real instrument like the non-reflecting side edges. The results confirm the “chromatic” displacement of the focal point (flux density maximum) at fixed supermirror curvature, and the ability of a variable curvature to keep the focal point at the sample position. Our simulations are in excellent agreement with theoretical predictions and the experimentally measured beam profile. With respect to the possibility of a further upgrade, we find that supermirror coatings with m-values higher than 3.5 would have only marginal influence on the optimal behaviour, whereas comparable spectrometers could take advantage of longer focusing segments, with particular impact for the thermal region of the neutron spectrum.

COINTOF mass spectrometry: design of a time-of-flight analyzer and development of the analysis method

International Nuclear Information System (INIS)

Teyssier, C.

2012-01-01

DIAM (Device for the irradiation of molecular clusters) is a newly designed experimental setup to investigate processes resulting from the irradiation of molecular nano-systems by 20-150 keV protons. One of its specificities relies on the original technique of mass spectrometry named COINTOF (Correlated Ion and Neutral Time Of Flight) consisting in correlated measurements of the time of flight of charged and neutral fragments produced by the dissociation of a single molecular ion parent. A strategy of treatment and analysis of the detection signals was developed to distinguish two fragments close in time ( 3 O + and two water molecules. The distribution of the time of flight difference between the two neutral fragments is measured providing an estimate of the kinetic energy release of a few eV. In parallel, a second time-of-flight mass spectrometer was designed. It associates a linear time-of-flight and an orthogonal time-of-flight and integrates position detectors (delay line anode). Simulations demonstrate the potentials of the new analyzer. Finally, research works were led at the laboratory R.-J. A. Levesque (Universite de Montreal) on the imaging capabilities of the multi-pixel detectors of the MPX-ATLAS collaboration. (author)

Fusion-fission of superheavy nuclei at low excitation energies

International Nuclear Information System (INIS)

Itkis, M.G.; Oganesyan, Yu.Ts.; Kozulin, E.M.

2000-01-01

The process of fusion-fission of superheavy nuclei with Z = 102 -122 formed in the reactions with 22 Ne, 26 Mg, 48 Ca, 58 Fe and 86 Kr ions at energies near and below the Coulomb barrier has been studied. The experiments were carried out at the U-400 accelerator of the Flerov Laboratory of Nuclear Reactions (JINR) using a time-of-flight spectrometer of fission fragments CORSET and a neutron multi-detector DEMON. As a result of the experiments, mass and energy distributions of fission fragments, fission and quasi-fission cross sections, multiplicities of neutrons and gamma-rays and their dependence on the mechanism of formation and decay of compound superheavy systems have been studied

ICF implosion hotspot ion temperature diagnostic techniques based on neutron time-of-flight method

International Nuclear Information System (INIS)

Tang Qi; Song Zifeng; Chen Jiabin; Zhan Xiayu

2013-01-01

Ion temperature of implosion hotspot is a very important parameter for inertial confinement fusion. It reflects the energy level of the hotspot, and it is very sensitive to implosion symmetry and implosion speed. ICF implosion hotspot ion temperature diagnostic techniques based on neutron time-of-flight method were described. A neutron TOF spectrometer was developed using a ultrafast plastic scintillator as the neutron detector. Time response of the spectrometer has 1.1 ns FWHM and 0.5 ns rising time. TOF spectrum resolving method based on deconvolution and low pass filter was illuminated. Implosion hotspot ion temperature in low neutron yield and low ion temperature condition at Shenguang-Ⅲ facility was acquired using the diagnostic techniques. (authors)

Electrostatic mirror of time-of-flight focusing of charged particles and its application to mass spectrometry

International Nuclear Information System (INIS)

Berger, C.

1985-01-01

This invention is more particularly aimed at the electrostatic devices used in time-of-flight mass spectrometers. To obtain a better resolution and a maximum transmission, the mirror is characterized by three annular electrodes with same radius R: - having at least an inner conductor surface related to an electric source, - delimiting by their facing ends cross-sections, - spaced successively with coaxial arrangement, - having an axial length for the center electrode equal to 0,9 R and for the end electrodes a length enough to give to them a behaviour equivalent to a infinite length tube cylinder. Ion beams are reflected by the mirror which in the same time realizes the time-of-flight unicity for ion. TOF unicity means that time of flight will be the same for equal mass ions [fr

Optimization of time-correlated single photon counting spectrometer

International Nuclear Information System (INIS)

Zhang Xiufeng; Du Haiying; Sun Jinsheng

2011-01-01

The paper proposes a performance improving scheme for the conventional time-correlated single photon counting spectrometer and develops a high speed data acquisition card based on PCI bus and FPGA technologies. The card is used to replace the multi-channel analyzer to improve the capability and decrease the volume of the spectrometer. The process of operation is introduced along with the integration of the spectrometer system. Many standard samples are measured. The experimental results show that the sensitivity of the spectrometer is single photon counting, and the time resolution of fluorescence lifetime measurement can be picosecond level. The instrument could measure the time-resolved spectroscopy. (authors)

Control of Strobilurin Fungicides in Wheat Using Direct Analysis in Real Time Accurate Time-of-Flight and Desorption Electrospray Ionization Linear Ion Trap Mass Spectrometry

NARCIS (Netherlands)

Schurek, J.; Vaclavik, L.; Hooijerink, H.; Lacina, O.; Poustka, J.; Sharman, M.; Caldow, M.; Nielen, M.W.F.; Hajslova, J.

2008-01-01

Ambient mass spectrometry has been used for the analysis of strobilurin residues in wheat. The use of this novel, challenging technique, employing a direct analysis in a real time (DART) ion-source coupled with a time-of-flight mass spectrometer (TOF MS) and a desorption electrospray ionization

In-beam test of the Boron-10 Multi-Grid neutron detector at the IN6 time-of-flight spectrometer at the ILL

Energy Technology Data Exchange (ETDEWEB)

Birch, J; Hultman, L; Höglund, C [Linköping University, Thin Film Physics Division, IFM, SE-581 83 Linköping (Sweden); Buffet, J-C; Clergeau, J-F; Correa, J; Van Esch, P; Ferraton, M; Guerard, B; Halbwachs, J; Khaplanov, A; Koza, M; Piscitelli, F; Zbiri, M [Institute Laue Langevin, Rue Jules Horowitz, FR-38000 Grenoble (France); Hall-Wilton, R [European Spallation Source ESS AB, P.O Box 176, SE-221 00 Lund (Sweden)

2014-07-24

A neutron detector concept based on solid layers of boron carbide enriched in {sup 10}B has been in development for the last few years as an alternative for {sup 3}He by collaboration between the ILL, ESS and Linköping University. This Multi-Grid detector uses layers of aluminum substrates coated with {sup 10}B{sub 4}C on both sides that are traversed by the incoming neutrons. Detection is achieved using a gas counter readout principle. By segmenting the substrate and using multiple anode wires, the detector is made inherently position sensitive. This development is aimed primarily at neutron scattering instruments with large detector areas, such as time-of-flight chopper spectrometers. The most recent prototype has been built to be interchangeable with the {sup 3}He detectors of IN6 at ILL. The {sup 10}B detector has an active area of 32 x 48cm{sup 2}. It was installed at the IN6 instrument and operated for several weeks, collecting data in parallel with the regularly scheduled experiments, thus providing the first side-by-side comparison with the conventional {sup 3}He detectors. Results include an efficiency comparison, assessment of the in-detector scattering contribution, sensitivity to gamma-rays and the signal-to-noise ratio in time-of-flight spectra. The good expected performance has been confirmed with the exception of an unexpected background count rate. This has been identified as natural alpha activity in aluminum. New convertor substrates are under study to eliminate this source of background.

Implementation of dipolar direct current (DDC) collision-induced dissociation in storage and transmission modes on a quadrupole/time-of-flight tandem mass spectrometer.

Science.gov (United States)

Webb, Ian K; Londry, Frank A; McLuckey, Scott A

2011-09-15

Means for effecting dipolar direct current collision-induced dissociation (DDC CID) on a quadrupole/time-of-flight in a mass spectrometer have been implemented for the broadband dissociation of a wide range of analyte ions. The DDC fragmentation method in electrodynamic storage and transmission devices provides a means for inducing fragmentation of ions over a large mass-to-charge range simultaneously. It can be effected within an ion storage step in a quadrupole collision cell that is operated as a linear ion trap or as ions are continuously transmitted through the collision cell. A DDC potential is applied across one pair of rods in the quadrupole collision cell of a QqTOF hybrid mass spectrometer to effect fragmentation. In this study, ions derived from a small drug molecule, a model peptide, a small protein, and an oligonucleotide were subjected to the DDC CID method in either an ion trapping or an ion transmission mode (or both). Several key experimental parameters that affect DDC CID results, such as time, voltage, low mass cutoff, and bath gas pressure, are illustrated with protonated leucine enkephalin. The DDC CID dissociation method gives a readily tunable, broadband tool for probing the primary structures of a wide range of analyte ions. The method provides an alternative to the narrow resonance conditions of conventional ion trap CID and it can access more extensive sequential fragmentation, depending upon conditions. The DDC CID approach constitutes a collision analog to infrared multiphoton dissociation (IRMPD). Copyright © 2011 John Wiley & Sons, Ltd.

IN5 Polarisation Option (IPOP) and HIgh FIeld Magnet Option (HIFIMO) for the IN5 time-of-flight spectrometer

International Nuclear Information System (INIS)

Ollivier, J.; Mutka, H.

2011-01-01

The new secondary spectrometer for the cold neutron time-of-flight (ToF) instrument IN5 was built with non-magnetic material, keeping in mind the upgrade option of polarisation analysis (PA) and the possibility of applying high continuous magnetic fields. The refurbished instrument has a high incident flux and elevated count-rate and offers a unique opportunity for applying polarised neutron methods for high resolution inelastic scattering, including single crystal investigations. On IN5 the polarised option would use the PASTIS concept of three sets of compact perpendicular coils (see the PANTHER proposal) allowing XYZPA and a 3 He analyser banana. As for high magnetic fields: a magnet suitable for ToF instruments must place a minimal amount of material in the incoming and outgoing beams and provide a large asymmetric view towards the detectors. An homogeneous field area of about 20 mm diameter over 30 mm height is also required. There is a size constraint set by the 800 mm diameter sample chamber and the optimal angular acceptance towards the detectors is -12 degrees / +135 degrees in the equatorial plane and +/- 22 degrees in the vertical direction

Combined Raman/LIBS spectrometer elegant breadboard: built and tested - and flight model spectrometer unit

Science.gov (United States)

Ahlers, B.; Hutchinson, I.; Ingley, R.

2017-11-01

A spectrometer for combined Raman and Laser Induced Breakdown Spectroscopy (LIBS) is amongst the different instruments that have been pre-selected for the Pasteur payload of the ExoMars rover. It is regarded as a fundamental, next-generation instrument for organic, mineralogical and elemental characterisation of Martian soil, rock samples and organic molecules. Raman spectroscopy and LIBS will be integrated into a single instrument sharing many hardware commonalities [1]. The combined Raman / LIBS instrument has been recommended as the highest priority mineralogy instrument to be included in the rover's analytical laboratory for the following tasks: Analyse surface and sub-surface soil and rocks on Mars, identify organics in the search for life and determine soil origin & toxicity. The synergy of the system is evident: the Raman spectrometer is dedicated to molecular analysis of organics and minerals; the LIBS provides information on the sample's elemental composition. An international team, under ESA contract and with the leadership of TNO Science and Industry, has built and tested an Elegant Bread Board (EBB) of the combined Raman / LIBS instrument. The EBB comprises a specifically designed, extremely compact, spectrometer with high resolution over a large wavelength range, suitable for both Raman spectroscopy and LIBS measurements. The EBB also includes lasers, illumination and imaging optics as well as fibre optics for light transfer. A summary of the functional and environmental requirements together with a description of the optical design and its expected performance are described in [2]. The EBB was developed and constructed to verify the instruments' end-to-end functional performance with natural samples. The combined Raman / LIBS EBB realisation and test results of natural samples will be presented. For the Flight Model (FM) instrument, currently in the design phase, the Netherlands will be responsible for the design, development and verification of the

GEANT4 simulation and evaluation of a time-of-flight spectrometer for nuclear cross section measurements in particle therapy

International Nuclear Information System (INIS)

Gruenwald, Oxana

2011-01-01

In 2007 a new project has been launched in a cooperation between the RWTH Aachen Physics Department, the University Hospital Aachen and the Philips Research Laboratories. The project aim is to validate and improve GEANT4 nuclear interaction models for use in proton and ion therapy. The method chosen here is the measurement of nuclear reaction cross sections which will not only provide a comparison to the simulation but will also allow to improve some of the parameters in the nuclear models. In the first phase of the project 200 MeV protons are used as a projectile in combination with a thin graphite target. For use in particle therapy the excitation functions of the most frequently produced isotopes need to be measured with an accuracy of 10% or less. For this purpose a dedicated detector system has been designed and implemented in GEANT4. The detection of target fragments produced by protons in graphite is achieved via time-of-flight spectrometry. In the setup presented here the primary beam first hits the Start detector and initiates the time-of-flight measurement before it passes through the apertures of two Veto detectors and impinges on the target. Successively, the secondary particles emanating from the target travel a short distance of 70/80 cm through vacuum (0.1 mbar) before they hit one of the 20 Stop detectors which end the time-of-flight measurement and record the energy deposited by the particle. The dissertation at hand describes the underlying detector concept and presents a detailed GEANT4 simulation of the setup which allows to evaluate the detector performance with respect to target fragment identification at a projectile energy of 200 MeV. At first, correlations of time-of-flight and energy deposition are built from simulated data and are subsequently used to reconstruct mass spectra of the detected fragments. Such influences on the detection performance as the target thickness, the residual pressure within the detector chamber, the Veto system

GEANT4 simulation and evaluation of a time-of-flight spectrometer for nuclear cross section measurements in particle therapy

Energy Technology Data Exchange (ETDEWEB)

Gruenwald, Oxana

2011-06-08

In 2007 a new project has been launched in a cooperation between the RWTH Aachen Physics Department, the University Hospital Aachen and the Philips Research Laboratories. The project aim is to validate and improve GEANT4 nuclear interaction models for use in proton and ion therapy. The method chosen here is the measurement of nuclear reaction cross sections which will not only provide a comparison to the simulation but will also allow to improve some of the parameters in the nuclear models. In the first phase of the project 200 MeV protons are used as a projectile in combination with a thin graphite target. For use in particle therapy the excitation functions of the most frequently produced isotopes need to be measured with an accuracy of 10% or less. For this purpose a dedicated detector system has been designed and implemented in GEANT4. The detection of target fragments produced by protons in graphite is achieved via time-of-flight spectrometry. In the setup presented here the primary beam first hits the Start detector and initiates the time-of-flight measurement before it passes through the apertures of two Veto detectors and impinges on the target. Successively, the secondary particles emanating from the target travel a short distance of 70/80 cm through vacuum (0.1 mbar) before they hit one of the 20 Stop detectors which end the time-of-flight measurement and record the energy deposited by the particle. The dissertation at hand describes the underlying detector concept and presents a detailed GEANT4 simulation of the setup which allows to evaluate the detector performance with respect to target fragment identification at a projectile energy of 200 MeV. At first, correlations of time-of-flight and energy deposition are built from simulated data and are subsequently used to reconstruct mass spectra of the detected fragments. Such influences on the detection performance as the target thickness, the residual pressure within the detector chamber, the Veto system

In-Flight Spectral Calibration of the APEX Imaging Spectrometer Using Fraunhofer Lines

Science.gov (United States)

Kuhlmann, Gerrit; Hueni, Andreas; Damm, Aalexander; Brunner, Dominik

2015-11-01

The Airborne Prism EXperiment (APEX) is an imaging spectrometer which allows to observe atmospheric trace gases such as nitrogen dioxide (NO2). Using a high resolution spectrum of solar Fraunhofer lines, APEX measurements collected during flight have been spectrally calibrated for centre wavelength positions (CW) and instrument slit function (ISF) and compared to the laboratory calibration. We find that CWs depend strongly on both across- and along-track position due to spectral smile and CWs dependency on ambient pressure. The width of the ISF is larger than estimated from the laboratory calibration but can be described by a linear scaling of the laboratory values. The ISF width depends on across- but not on along-track direction. The results demonstrate the importance of characterizing and monitoring the instrument performance during flight and will be used to improve the Empa APEX NO2 retrieval algorithm.

Calibration of time of flight detectors using laser-driven neutron source

Energy Technology Data Exchange (ETDEWEB)

Mirfayzi, S. R.; Kar, S., E-mail: s.kar@qub.ac.uk; Ahmed, H.; Green, A.; Alejo, A.; Jung, D. [Centre for Plasma Physics, School of Mathematics and Physics, Queen’s University Belfast, Belfast BT7 1NN (United Kingdom); Krygier, A. G.; Freeman, R. R. [Department of Physics, The Ohio State University, Columbus, Ohio 43210 (United States); Clarke, R. [Central Laser Facility, Rutherford Appleton Laboratory, Didcot, Oxfordshire OX11 0QX (United Kingdom); Fuchs, J.; Vassura, L. [LULI, Ecole Polytechnique, CNRS, Route de Saclay, 91128 Palaiseau Cedex (France); Kleinschmidt, A.; Roth, M. [Institut für Kernphysik, Technische Universität Darmstadt, Schloßgartenstrasse 9, D-64289 Darmstadt,Germany (Germany); Morrison, J. T. [Propulsion Systems Directorate, Air Force Research Lab, Wright Patterson Air Force Base, Ohio 45433 (United States); Najmudin, Z.; Nakamura, H. [Blackett Laboratory, Department of Physics, Imperial College, London SW7 2AZ (United Kingdom); Norreys, P. [Central Laser Facility, Rutherford Appleton Laboratory, Didcot, Oxfordshire OX11 0QX (United Kingdom); Department of Physics, University of Oxford, Oxford OX1 3PU (United Kingdom); Oliver, M. [Department of Physics, University of Oxford, Oxford OX1 3PU (United Kingdom); Zepf, M. [Centre for Plasma Physics, School of Mathematics and Physics, Queen’s University Belfast, Belfast BT7 1NN (United Kingdom); Helmholtz Institut Jena, D-07743 Jena (Germany); Borghesi, M. [Centre for Plasma Physics, School of Mathematics and Physics, Queen’s University Belfast, Belfast BT7 1NN (United Kingdom); Institute of Physics of the ASCR, ELI-Beamlines Project, Na Slovance 2, 18221 Prague (Czech Republic)

2015-07-15

Calibration of three scintillators (EJ232Q, BC422Q, and EJ410) in a time-of-flight arrangement using a laser drive-neutron source is presented. The three plastic scintillator detectors were calibrated with gamma insensitive bubble detector spectrometers, which were absolutely calibrated over a wide range of neutron energies ranging from sub-MeV to 20 MeV. A typical set of data obtained simultaneously by the detectors is shown, measuring the neutron spectrum emitted from a petawatt laser irradiated thin foil.

Calibration of time of flight detectors using laser-driven neutron source

Science.gov (United States)

Mirfayzi, S. R.; Kar, S.; Ahmed, H.; Krygier, A. G.; Green, A.; Alejo, A.; Clarke, R.; Freeman, R. R.; Fuchs, J.; Jung, D.; Kleinschmidt, A.; Morrison, J. T.; Najmudin, Z.; Nakamura, H.; Norreys, P.; Oliver, M.; Roth, M.; Vassura, L.; Zepf, M.; Borghesi, M.

2015-07-01

Calibration of three scintillators (EJ232Q, BC422Q, and EJ410) in a time-of-flight arrangement using a laser drive-neutron source is presented. The three plastic scintillator detectors were calibrated with gamma insensitive bubble detector spectrometers, which were absolutely calibrated over a wide range of neutron energies ranging from sub-MeV to 20 MeV. A typical set of data obtained simultaneously by the detectors is shown, measuring the neutron spectrum emitted from a petawatt laser irradiated thin foil.

Calibration of time of flight detectors using laser-driven neutron source

International Nuclear Information System (INIS)

Mirfayzi, S. R.; Kar, S.; Ahmed, H.; Green, A.; Alejo, A.; Jung, D.; Krygier, A. G.; Freeman, R. R.; Clarke, R.; Fuchs, J.; Vassura, L.; Kleinschmidt, A.; Roth, M.; Morrison, J. T.; Najmudin, Z.; Nakamura, H.; Norreys, P.; Oliver, M.; Zepf, M.; Borghesi, M.

2015-01-01

Calibration of three scintillators (EJ232Q, BC422Q, and EJ410) in a time-of-flight arrangement using a laser drive-neutron source is presented. The three plastic scintillator detectors were calibrated with gamma insensitive bubble detector spectrometers, which were absolutely calibrated over a wide range of neutron energies ranging from sub-MeV to 20 MeV. A typical set of data obtained simultaneously by the detectors is shown, measuring the neutron spectrum emitted from a petawatt laser irradiated thin foil

Depth profiling of Al{sub 2}O{sub 3} + TiO{sub 2} nanolaminates by means of a time-of-flight energy spectrometer

Energy Technology Data Exchange (ETDEWEB)

Laitinen, M., E-mail: mikko.i.laitinen@jyu.fi [Dept. of Physics, P.O. Box 35, 40014 University of Jyvaeskylae (Finland); Sajavaara, T., E-mail: timo.sajavaara@jyu.fi [Dept. of Physics, P.O. Box 35, 40014 University of Jyvaeskylae (Finland); Rossi, M., E-mail: mikko.rossi@jyu.fi [Dept. of Physics, P.O. Box 35, 40014 University of Jyvaeskylae (Finland); Julin, J., E-mail: jaakko.julin@jyu.fi [Dept. of Physics, P.O. Box 35, 40014 University of Jyvaeskylae (Finland); Puurunen, R.L., E-mail: riikka.puurunen@vtt.fi [VTT Technical Research Centre of Finland, Tietotie 3, FI-02150 Espoo (Finland); Suni, T., E-mail: tommi.suni@vtt.fi [VTT Technical Research Centre of Finland, Tietotie 3, FI-02150 Espoo (Finland); Institute of Industrial Science, University of Tokyo, ew304, 4-6-1 Komaba, Meguro-ku, 153-8505 Tokyo (Japan); Ishida, T., E-mail: tadashii@iis.u-tokyo.ac.jp [Institute of Industrial Science, University of Tokyo, ew304, 4-6-1 Komaba, Meguro-ku, 153-8505 Tokyo (Japan); Fujita, H., E-mail: fujita@iis.u-tokyo.ac.jp [Institute of Industrial Science, University of Tokyo, ew304, 4-6-1 Komaba, Meguro-ku, 153-8505 Tokyo (Japan); Arstila, K., E-mail: kai.arstila@imec.be [Imec, Kapeldreef 75, Leuven 3001 (Belgium); Brijs, B., E-mail: bert.brijs@imec.be [Imec, Kapeldreef 75, Leuven 3001 (Belgium); Whitlow, H.J., E-mail: harry.j.whitlow@jyu.fi [Dept. of Physics, P.O. Box 35, 40014 University of Jyvaeskylae (Finland)

2011-12-15

Atomic layer deposition (ALD) is currently a widespread method to grow conformal thin films with a sub-nm thickness control. By using ALD for nanolaminate oxides, it is possible to fine tune the electrical, optical and mechanical properties of thin films. In this study the elemental depth profiles and surface roughnesses were determined for Al{sub 2}O{sub 3} + TiO{sub 2} nanolaminates with nominal single-layer thicknesses of 1, 2, 5, 10 and 20 nm and total thickness between 40 nm and 60 nm. The depth profiles were measured by means of a time-of-flight elastic recoil detection analysis (ToF-ERDA) spectrometer recently installed at the University of Jyvaeskylae. In TOF-E measurements {sup 63}Cu, {sup 35}Cl, {sup 12}C and {sup 4}He ions with energies ranging from 0.5 to 10 MeV, were used and depth profiles of the whole nanolaminate film could be analyzed down to 5 nm individual layer thickness.

IPNS-I chopper spectrometers

International Nuclear Information System (INIS)

Price, D.L.; Carpenter, J.M.; Pelizzari, C.A.; Sinha, S.K.; Bresof, I.; Ostrowski, G.E.

1982-01-01

We briefly describe the layout and operation of the two chopper experiments at IPNS-I. The recent measurement on solid 4 He by Hilleke et al. provides examples of time-of-flight data from the Low Resolution Chopper Spectrometer

Picosecond resolution on relativistic heavy ions' time-of-flight measurement

International Nuclear Information System (INIS)

Ebran, A.; Taieb, J.; Belier, G.; Chatillon, A.; Laurent, B.; Martin, J.-F.; Pellereau, E.

2013-01-01

We developed a time-of-flight measurement system for relativistic heavy ions with a requested resolution of 40 ps Full Width Half Maximum. Such a resolution is mandatory to assign the correct mass number to every fission fragment, identified using the Bρ-ToF-ΔE method with the recoil spectrometer designed for the SOFIA experiment—which hold very recently at GSI. To achieve such a performance, fast plastic scintillators read-out by dedicated photomultiplier tubes were chosen among other possible options. We have led several test-measurements from 2009 to 2011, in order to investigate: the effect of the addition of a quenching molecule in the scintillator's matrix, the influence of the detector's size and the impact of the photomultiplier tube. The contribution of the dedicated electronics is also characterized. Time-of-flight measurements were performed realized with electron pulses and relativistic heavy ions, respectively provided by the LASER driven electron–accelerator (ELSA) at CEA–DAM Ile-de-France and by the SIS18/FRS facility at GSI. The reported results exhibit a time resolution better than 20 ps Full Width Half Maximum reached with the last prototype at GSI with an Uranium beam. These results confirm that the SOFIA experiment should enable the measurement of the relativistic fission fragments' time-of-flight with the requested resolution

Photoelectron spectrometer for attosecond spectroscopy of liquids and gases

Energy Technology Data Exchange (ETDEWEB)

Jordan, I.; Huppert, M.; Wörner, H. J., E-mail: hwoerner@ethz.ch [Laboratory of Physical Chemistry, ETH Zurich, Vladimir-Prelog-Weg 2, 8093 Zurich (Switzerland); Brown, M. A. [Laboratory for Surface Science and Technology, Department of Materials, ETH Zurich, Vladimir-Prelog-Weg 5, 8093 Zurich (Switzerland); Bokhoven, J. A. van [Institute for Chemical and Bioengineering, ETH Zurich, Vladimir-Prelog-Weg 1, 8093 Zurich (Switzerland); Laboratory for Catalysis and Sustainable Chemistry, Paul Scherrer Institute, 5232 Villigen (Switzerland)

2015-12-15

A new apparatus for attosecond time-resolved photoelectron spectroscopy of liquids and gases is described. It combines a liquid microjet source with a magnetic-bottle photoelectron spectrometer and an actively stabilized attosecond beamline. The photoelectron spectrometer permits venting and pumping of the interaction chamber without affecting the low pressure in the flight tube. This pressure separation has been realized through a sliding skimmer plate, which effectively seals the flight tube in its closed position and functions as a differential pumping stage in its open position. A high-harmonic photon spectrometer, attached to the photoelectron spectrometer, exit port is used to acquire photon spectra for calibration purposes. Attosecond pulse trains have been used to record photoelectron spectra of noble gases, water in the gas and liquid states as well as solvated species. RABBIT scans demonstrate the attosecond resolution of this setup.

Photoelectron spectrometer for attosecond spectroscopy of liquids and gases

International Nuclear Information System (INIS)

Jordan, I.; Huppert, M.; Wörner, H. J.; Brown, M. A.; Bokhoven, J. A. van

2015-01-01

A new apparatus for attosecond time-resolved photoelectron spectroscopy of liquids and gases is described. It combines a liquid microjet source with a magnetic-bottle photoelectron spectrometer and an actively stabilized attosecond beamline. The photoelectron spectrometer permits venting and pumping of the interaction chamber without affecting the low pressure in the flight tube. This pressure separation has been realized through a sliding skimmer plate, which effectively seals the flight tube in its closed position and functions as a differential pumping stage in its open position. A high-harmonic photon spectrometer, attached to the photoelectron spectrometer, exit port is used to acquire photon spectra for calibration purposes. Attosecond pulse trains have been used to record photoelectron spectra of noble gases, water in the gas and liquid states as well as solvated species. RABBIT scans demonstrate the attosecond resolution of this setup

Photoelectron spectrometer for attosecond spectroscopy of liquids and gases

Science.gov (United States)

Jordan, I.; Huppert, M.; Brown, M. A.; van Bokhoven, J. A.; Wörner, H. J.

2015-12-01

A new apparatus for attosecond time-resolved photoelectron spectroscopy of liquids and gases is described. It combines a liquid microjet source with a magnetic-bottle photoelectron spectrometer and an actively stabilized attosecond beamline. The photoelectron spectrometer permits venting and pumping of the interaction chamber without affecting the low pressure in the flight tube. This pressure separation has been realized through a sliding skimmer plate, which effectively seals the flight tube in its closed position and functions as a differential pumping stage in its open position. A high-harmonic photon spectrometer, attached to the photoelectron spectrometer, exit port is used to acquire photon spectra for calibration purposes. Attosecond pulse trains have been used to record photoelectron spectra of noble gases, water in the gas and liquid states as well as solvated species. RABBIT scans demonstrate the attosecond resolution of this setup.

Combined proton-recoil and neutron time-of-flight spectrometer for 14 MeV neutrons

International Nuclear Information System (INIS)

Grosshoeg, G.; Aronsson, D.; Arvidsson, E.; Beimer, K.-H.; Pekkari, L.-O.; Rydz, R.; Sjoestrand, N.G.

1983-05-01

The main effort put into this work is the foundation of a reliable physical basis for a 12-16 MeV neutron-spectrometer at JET. The essential problem is the amount of scatterer that can be incorporated without losing resolution. We have found two possible methods, the use of a pure hydrogen scatterer and the use of a polyethylene foil scatterer. The pure hydrogen solution gives a very complicated spectrometer with large detectors. The polyethylene solution is limited by the thickness and the width of the foil. We judge the solution with the polyethylene foil to be the most promising one for a reliable spectrometer. However, a large foil area is needed. This gives a spectrometer design with an annular foil, an annular neutron detection system, and a central proton-detector. An efficiency of 10 - 6 counts/s per n/cm 2 ,s at the foil can be obtained with a resolution in the order of 100 keV for 14 MeV neutrons. Following the General Requirements given in the contract of this work, we concluded that an instrument with the desired properties can be made. The instruments is able to give useful information about the plasma from plasma temperatures of about 5 keV. (Authors)

Rotation stability of high speed neutron time-of-flight mechanical chopper

International Nuclear Information System (INIS)

Habib, N.; Adib, M.

1998-01-01

A modified rotation stabilization system has been designed to maintain the stability of a neutron time-of-flight (TOF) mechanical chopper rates from 460 rpm to 16000 rpm. The main principle of the system is based on comparing the chopper's rotation period with the preselected one from a quartz timer. The result of comparison is used to control the current driver of the chopper's motor. A 600 Hz three phase generator controlled by a magnetic amplifier was used as a current driver. The stability of the chopper's rotation rate at 16000 rpm was 0.02%. An improved method precise time scale calibration of the TOF spectrometer is applied

Application of a digital data acquisition system for time of flight Positron annihilation-induced Auger Electron Spectroscopy

Science.gov (United States)

Gladen, R. W.; Chirayath, V. A.; McDonald, A. D.; Fairchild, A. J.; Chrysler, M. D.; Imam, S. K.; Koymen, A. R.; Weiss, A. H.

We describe herein a digital data acquisition system for a time-of-flight Positron annihilation-induced Auger Electron Spectrometer. This data acquisition system consists of a high-speed digitizer collecting signals induced by Auger electrons and annihilation gammas in a multi-channel plate electron detector and a BaF2 gamma detector, respectively. The time intervals between these two signals is used to determine the times of flight of the Auger electrons, which are analyzed by algorithms based on traditional nuclear electronics methods. Ultimately, this digital data acquisition system will be expanded to incorporate the first coincidence measurements of Auger electron and annihilation gamma energies.

Identification of molecules in graphite furnace by laser ionization time-of-flight mass spectrometry: sulfur and chlorine containing compounds

CSIR Research Space (South Africa)

Raseleka, RM

2004-01-01

Full Text Available An electro thermal vaporizer (ETV) coupled to a time-of-flight mass spectrometer (TOF-MS) with laser ionization (LI) was applied to the identification of molecules from sulphur and chlorine matrices in the furnace. An interface was developed...

A time-of-flight system for precise measurements of a relativistic charged particle beam momentum

International Nuclear Information System (INIS)

Avramenko, S.A.; Belikov, Yu.A.; Golokhvastov, A.I.; Lukstin'sh, Yu.; Man'yakov, P.K.; Rukoyatkin, P.A.; Khorozov, S.A.

1996-01-01

A time-of-flight system with a time resolution (σ) about 100 ps is described. The methods for the calibration, stability verification and the method for the time resolution evaluation in conditions of a nonmonochromatic beam are discussed especially. The system was applied in charge exchange ( 3 H, 3 He) experiments with the GIBS spectrometer for a measurement of 3 H-nuclei momenta at 2 GeV/c per nucleon with a precision about 0.2%. (author). 4 refs., 7 figs., 1 tab

Low power ion spectrometer for high counting rates

International Nuclear Information System (INIS)

Klein, J.W.; Dullenkopf, P.; Glasmachers, A.; Melbert, J.; Winkelnkemper, W.

1980-01-01

This report describes in detail the electronic concept for a time-of-flight (TOF) ion spectrometer for high counting rates and high dynamic range which can be used as a satellite instrument. The detection principle of the spectrometer is based on a time-of-flight and energy measurement for each incident ion. The ionmass is related to these two quantities by a simple equation. The described approach for the mass identification systems is using an analog fast-slow concept: The fast TOF-signal preselects the gainstep in the much slower energy channel. The conversion time of the mass identifier is approximately 10 -6 s and the dynamic range of the energy channel is better than 10 3 (20 keV to 25 MeV). The purpose of this study was to demonstrate the feasibility of a TOF-spectrometer capable to measure the ion composition in planetary magnetospheres. (orig.) [de

Gamma rays as probe of fission and quasi-fission dynamics in the reaction 32S + 197Au near the Coulomb barrier

Science.gov (United States)

Pulcini, A.; Vardaci, E.; Kozulin, E.; Ashaduzzaman, M.; Borcea, C.; Bracco, A.; Brambilla, S.; Calinescu, S.; Camera, F.; Ciemala, M.; de Canditiis, B.; Dorvaux, O.; Harca, I. M.; Itkis, I.; Kirakosyan, V. V.; Knyazheva, G.; Kozulina, N.; Kolesov, I. V.; La Rana, G.; Maj, A.; Matea, I.; Novikov, K.; Petrone, C.; Quero, D.; Rath, P.; Saveleva, E.; Schmitt, C.; Sposito, G.; Stezowski, O.; Trzaska, W. H.; Wilson, J.

2018-05-01

Compound nucleus fission and quasi-fission are both binary decay channels whose common properties make the experimental separation between them difficult. A way to achieve this separation could be to probe the angular momentum of the binary fragments. This can be done detecting gamma rays in coincidence with the two fragments. As a case study, the reaction 32S + 197Au near the Coulomb barrier has been performed at the Tandem ALTO facility at IPN ORSAY. ORGAM and PARIS, two different gamma detectors arrays, are coupled with the CORSET detector, a two-arm time-of-flight spectrometer. TOF-TOF data were analyzed to reconstruct the mass-energy distribution of the primary fragments coupled with gamma multiplicity and spectroscopic analysis. Preliminary results of will be shown.

Gas chromatography interfaced with atmospheric pressure ionization-quadrupole time-of-flight-mass spectrometry by low-temperature plasma ionization

DEFF Research Database (Denmark)

Norgaard, Asger W.; Kofoed-Sorensen, Vivi; Svensmark, Bo

2013-01-01

A low temperature plasma (LTP) ionization interface between a gas chromatograph (GC) and an atmospheric pressure inlet mass spectrometer, was constructed. This enabled time-of-flight mass spectrometric detection of GC-eluting compounds. The performance of the setup was evaluated by injection...

Introduction of a 20 kHz Nd:YVO4 laser into a hybrid quadrupole time-of-flight mass spectrometer for MALDI-MS imaging.

Science.gov (United States)

Trim, Paul J; Djidja, Marie-Claude; Atkinson, Sally J; Oakes, Keith; Cole, Laura M; Anderson, David M G; Hart, Philippa J; Francese, Simona; Clench, Malcolm R

2010-08-01

A commercial hybrid quadrupole time-of-flight mass spectrometer has been modified for high-speed matrix-assisted laser desorption ionisation (MALDI) imaging using a short-pulse optical technology Nd:YVO(4) laser. The laser operating in frequency-tripled mode (lambda = 355 nm) is capable of delivering 1.5-ns pulses of energy at up to 8 microJ at 5-10 kHz and 3 microJ at 20 kHz. Experiments to improve beam homogeneity and reduce laser speckle by mechanical vibration of the fibre-optic laser delivery system are reported along with data from trial and tissue imaging experiments using the modified instrument. The laser appeared to yield best results for MALDI-MS imaging experiments when operating at repetition rates 5-10 kHz. Combining this with raster imaging allowed images of rat brain sections to be recorded in 37 min. Similarly, images of the distribution of peptides in "on-tissue" digest experiments from tumour tissues were recorded in 1 h and 30 min rather than the 8-h acquisition time previously used. A brief investigation of targeted protein analysis/imaging by multiple reaction monitoring experiments "on-tissue" is reported. A total of 26 transitions were recorded over a 3-s cycle time and images of abundant proteins were successfully recorded.

Design and realization of a space-borne reflectron time of flight mass spectrometer: electronics and measuring head; Conception et realisation d'un spectrometre de masse a temps de vol spatialisable de type 'reflectron' electronique et tete de mesure

Energy Technology Data Exchange (ETDEWEB)

Devoto, P

2006-03-15

The purpose of this thesis is the design of the electronics of a time of flight mass spectrometer, the making and the vacuum tests of a prototype which can be put onboard a satellite. A particular effort was necessary to decrease to the maximum the mass and electric consumption of the spectrometer, which led to the development of new circuits. The work completed during this thesis initially concerns the electronics of the measuring equipment which was conceived in a concern for modularity. A complete 'reflectron' type mass spectrometer was then designed, simulated and developed. The built prototype, which uses the developed electronics, was exposed to ion flows of different masses and energies in the CESR vacuum chambers. Its measured performances validate the implemented principles and show that an identical mass spectrometer can be put onboard a satellite with profit, for planetary or solar missions. (author)

Evaluation of the ROTAX spectrometer

International Nuclear Information System (INIS)

Tietze-Jaensch, H.; Schmidt, W.; Geick, R.

1997-01-01

After installation of the new-type rotating crystal analyser spectrometer ROTAX at ISIS, we report on practical experience and describe its current status. The rotating analyser technique works feasibly and reliably and provides an ultimate scan flexibility on a pulsed time-of-flight neutron spectrometer. The spinning analyser achieves a mulitplex advantage factor of ca. 50 without compromising the resolution of the instrument. Despite these instrument merits its individual beam position at ISIS has only an unsatisfactorily weak flux, thus hindering this instrument yet to become fully competitive with other high-performance neutron spectrometers based at high-flux reactors. However, we strongly recommend a ROTAX-type instrument to be emphasized when the instrumentation suite of the future European spallation source ESS will come under scrutiny. (orig.)

Picosecond resolution on relativistic heavy ions' time-of-flight measurement

Energy Technology Data Exchange (ETDEWEB)

Ebran, A., E-mail: adeline.ebran@cea.fr; Taieb, J., E-mail: julien.taieb@cea.fr; Belier, G.; Chatillon, A.; Laurent, B.; Martin, J.-F.; Pellereau, E.

2013-11-11

We developed a time-of-flight measurement system for relativistic heavy ions with a requested resolution of 40 ps Full Width Half Maximum. Such a resolution is mandatory to assign the correct mass number to every fission fragment, identified using the Bρ-ToF-ΔE method with the recoil spectrometer designed for the SOFIA experiment—which hold very recently at GSI. To achieve such a performance, fast plastic scintillators read-out by dedicated photomultiplier tubes were chosen among other possible options. We have led several test-measurements from 2009 to 2011, in order to investigate: the effect of the addition of a quenching molecule in the scintillator's matrix, the influence of the detector's size and the impact of the photomultiplier tube. The contribution of the dedicated electronics is also characterized. Time-of-flight measurements were performed realized with electron pulses and relativistic heavy ions, respectively provided by the LASER driven electron–accelerator (ELSA) at CEA–DAM Ile-de-France and by the SIS18/FRS facility at GSI. The reported results exhibit a time resolution better than 20 ps Full Width Half Maximum reached with the last prototype at GSI with an Uranium beam. These results confirm that the SOFIA experiment should enable the measurement of the relativistic fission fragments' time-of-flight with the requested resolution.

Multiple-reflection time-of-flight mass spectrometry for in situ applications

Science.gov (United States)

Dickel, T.; Plaß, W. R.; Lang, J.; Ebert, J.; Geissel, H.; Haettner, E.; Jesch, C.; Lippert, W.; Petrick, M.; Scheidenberger, C.; Yavor, M. I.

2013-12-01

Multiple-reflection time-of-flight mass spectrometers (MR-TOF-MS) have recently been installed at different low-energy radioactive ion beam facilities. They are used as isobar separators with high ion capacity and as mass spectrometers with high mass resolving power and accuracy for short-lived nuclei. Furthermore, MR-TOF-MS have a huge potential for applications in other fields, such as chemistry, biology, medicine, space science, and homeland security. The development, commissioning and results of an MR-TOF-MS is presented, which serves as proof-of-principle to show that very high mass resolving powers (∼105) can be achieved in a compact device (length ∼30 cm). Based on this work, an MR-TOF-MS for in situ application has been designed. For the first time, this device combines very high mass resolving power (>105), mobility, and an atmospheric pressure inlet in one instrument. It will enable in situ measurements without sample preparation at very high mass accuracy. Envisaged applications of this mobile MR-TOF-MS are discussed.

Analysis of sample composition using resonant ionization and time-of-flight techniques

International Nuclear Information System (INIS)

Cruz, A. de la; Ortiz, M.; Campos, J.

1995-01-01

This paper describes the setting up of a linear time-of-flight mass spectrometer that uses a tunable laser to produce resonant ionization of atoms and molecules in a pulsed supersonic beam. The ability of this kind of systems to produce time resolved signals for each species present in the sample allows quantitative analysis of its composition. By using a tunable laser beam of high spectral resolution to produce ionization, studies based on the structure of the photoionization spectra obtained are possible. In the present work several isotopic species of ordinary and deuterated benzene have been studied. Special care has been dedicated to the influence of the presence of a 13C in the ring. In this way values for spectroscopic constants and isotopic shifts have been obtained. Another system based in a homemade proportional counter has been designed and used is an auxiliary system. The results obtained with it are independent of these mentioned above and compatible with them. This system is of great utility for laser wavelength tuning to produce ionization in the mass spectrometer. (Author) 98 refs

Analysis of sample composition using resonant ionization and time-of-flight techniques

International Nuclear Information System (INIS)

Luz, A. de la; Ortiz, M.; Campos, J.

1995-01-01

This paper describes the setting up of a linear time-of-flight mass spectrometer that uses a tunable laser to produce resonant ionization of atoms and molecules in a pulsed supersonic beam. The ability of this kind of systems to produce time resolved signals for each species present in the samples allows quantitative analysis of its composition. By using a tunable laser beam of high spectral resolution to produce ionization, studies based on the structure of the photoionization spectra obtained are possible. In the present work several isotopic species of ordinary and deuterated benzene have been studies. special care has been dedicated to the influence of the presence of a ''13 C in the ring. In this way values for spectroscopic constants and isotopic shifts have been obtained. Another system based in a homemade proportional counter has been designed and used as an auxiliary system. The results obtained with it are independent of these mentioned above and compatible with them. This system is of great utility for laser wavelength tuning to produce ionization in the mass spectrometer

Fully automatic and precise data analysis developed for time-of-flight mass spectrometry.

Science.gov (United States)

Meyer, Stefan; Riedo, Andreas; Neuland, Maike B; Tulej, Marek; Wurz, Peter

2017-09-01

Scientific objectives of current and future space missions are focused on the investigation of the origin and evolution of the solar system with the particular emphasis on habitability and signatures of past and present life. For in situ measurements of the chemical composition of solid samples on planetary surfaces, the neutral atmospheric gas and the thermal plasma of planetary atmospheres, the application of mass spectrometers making use of time-of-flight mass analysers is a technique widely used. However, such investigations imply measurements with good statistics and, thus, a large amount of data to be analysed. Therefore, faster and especially robust automated data analysis with enhanced accuracy is required. In this contribution, an automatic data analysis software, which allows fast and precise quantitative data analysis of time-of-flight mass spectrometric data, is presented and discussed in detail. A crucial part of this software is a robust and fast peak finding algorithm with a consecutive numerical integration method allowing precise data analysis. We tested our analysis software with data from different time-of-flight mass spectrometers and different measurement campaigns thereof. The quantitative analysis of isotopes, using automatic data analysis, yields results with an accuracy of isotope ratios up to 100 ppm for a signal-to-noise ratio (SNR) of 10 4 . We show that the accuracy of isotope ratios is in fact proportional to SNR -1 . Furthermore, we observe that the accuracy of isotope ratios is inversely proportional to the mass resolution. Additionally, we show that the accuracy of isotope ratios is depending on the sample width T s by T s 0.5 . Copyright © 2017 John Wiley & Sons, Ltd. Copyright © 2017 John Wiley & Sons, Ltd.

The role of vacuum in the quality of TOF mass spectrometer

International Nuclear Information System (INIS)

Bhowmick, A.; Gadkari, S.C.; Yakhmi, J.V.; Sahni, V.C.

2005-01-01

The art in the designing of time-of-flight mass spectrometers has come across a long course of development. The present day state-of-the-art machines are essentially the outcome of knowledge from the advances in different other areas of technology. This article discusses exclusively the role of UHV to enhance the quality of the TOF mass spectrometers and its application to the recently developed high resolution TOF mass spectrometer at TP and PED-BARC. (author)

Airborne testing and demonstration of a new flight system based on an Aerodyne N2O-CO2-CO-H2O mini-spectrometer

Science.gov (United States)

Gvakharia, A.; Kort, E. A.; Smith, M. L.; Conley, S.

2017-12-01

Nitrous oxide (N2O) is a powerful greenhouse gas and ozone depleting substance. With high atmospheric backgrounds and small relative signals, N2O emissions have been challenging to observe and understand on regional scales with traditional instrumentation. Fast-response airborne measurements with high precision and accuracy can potentially bridge this observational gap. Here we present flight assessments of a new flight system based on an Aerodyne mini-spectrometer as well as a Los Gatos N2O/CO analyzer during the Fertilizer Emissions Airborne Study (FEAST). With the Scientific Aviation Mooney aircraft, we conducted test flights for both analyzers where a known calibration gas was sampled throughout the flight (`null' tests). Clear altitude/cabin-pressure dependencies were observed for both analyzers if operated in an "off-the-shelf' manner. For the remainder of test flights and the FEAST campaign we used a new flight system based on an Aerodyne mini-spectrometer with the addition of a custom pressure control/calibration system. Instead of using traditional approaches with spectral-zeros and infrequent in-flight calibrations, we employ a high-flow system with stable flow control to enable high frequency (2 minutes), short duration (15 seconds) sampling of a known calibration gas. This approach, supported by the null test, enables correction for spectral drift caused by a variety of factors while maintaining a 90% duty cycle for 1Hz sampling from an aircraft. Preliminary in-flight precisions are estimated at 0.05 ppb, 0.1 ppm, 1 ppb, and 10 ppm for N2O, CO2, CO, and H2O respectively. We also present a further 40 hours of inter-comparison in flight with a Picarro 2301-f ring-down spectrometer demonstrating consistency between CO2 and H2O measurements and no altitude dependent error.

Mass measurements of {sup 238}U-projectile fragments for the first time with a multiple-reflection time-of-flight mass spectrometer

Energy Technology Data Exchange (ETDEWEB)

Ebert, Jens

2016-07-01

Mass measurements of short-lived uranium projectile fragments were performed for the first time with a Multiple-Reflexion-Time-of-Flight Mass Spectrometer (MR-TOF-MS). A major part of this doctoral work was a novel development of a data analysis method for the MR-TOF-MS mass measurements of exotic nuclei at the fragment separator FRS at GSI. The developed method was successfully applied to the data obtained from two pilot experiments with the MR-TOF-MS at the FRS in 2012 and 2014. A substantial upgrade of the experimental setup of the MR-TOF-MS was also performed in the frame work of this doctoral thesis after the first run. In the experiments projectile fragments were created with 1000 MeV/u {sup 238}U ions in a Be/Nb target at the entrance of the in-flight separator FRS. The exotic nuclei were spatially separated, energy bunched and slowed down with the ion-optical system of the FRS combined with monoenergetic and homogeneous degraders. At the final focal plane of the FRS the fragments were completely slowed down and thermalized in a cryogenic stopping cell (CSC) filled with 3-5 mg/cm{sup 2} pure helium gas. The exotic nuclei were fast extracted from the CSC to enable mass measurements of very short-lived fragments with the MR-TOF-MS. The achievement of this goal was successfully demonstrated with the mass measurement of {sup 220}Ra ions with a half-life of 17.9 ms and 11 detected events. The mass measurements of the isobars {sup 211}Fr, {sup 211}Po and {sup 211}Rn have clearly demonstrated the scientific potential of the MR-TOF-MS for the investigation of exotic nuclei and the power of the data analysis system. Difficult measurements with overlapping mass distributions with only a few counts in the measured spectra were the challenge for the new data analysis method based on the maximum likelihood method. The drifts during the measurements were corrected with the developed time-resolved calibration method. After the improvements of the setup as a consequence of

Comprehensive Two-dimensional Liquid Chromatography coupled to High Resolution Time of Flight Mass Spectrometry for Chemical Characterization of Sewage Treatment Plant Effluents

NARCIS (Netherlands)

Ouyang, X.; Leonards, P.E.G.; Legler, J.; van der Oost, R.; de Boer, J.; Lamoree, M.H.

2015-01-01

For the first time a comprehensive two-dimensional liquid chromatography (LC. ×. LC) system coupled with a high resolution time-of-flight mass spectrometer (HR-ToF MS) was developed and applied for analysis of emerging toxicants in wastewater effluent. The system was optimized and validated using

A Time of flight spectrometer for measurements of double differential neutron scattering cross sections; Montaje de un espectrometro por tiempo de vuelo para la medicion de secciones doble diferenciales de dispersion de neutrones

Energy Technology Data Exchange (ETDEWEB)

Padron, I; Dominguez, O; Sarria, P. Sandin, C. [Centro de Estudios Aplicados al Desarrollo Nuclear (CEADEN), La Habana (Cuba)

1996-05-01

The time -of-Flight neutron spectrometry technique by associated particle method was improved using a D-T neutron generator at Laboratory of Nuclear Analysis. This technique was implemented for double differential cross section measurements and supported by the IAEA Project CUB/01/005. An stilbene scintillation detector (dia=100 mm, length=50 mm) was used as principal neutron detector detector and was situated outside a hole in the concrete wall. This way the fligth path was extended and the scattered neutron cone accurate collimated throught the 2 m concrete wall. For the associated particle {alpha} detection a thin plastic NE-102 scint illator was used, as well as, two scintilation detectors and a long counter for the neutron flux monitoring. In this TOF neutron spectrometer (3.40 m flight path) a 1.7 nseg. temporal resolution was obtained.

New design for a time-of-flight mass spectrometer with a liquid beam laser desorption ion source for the analysis of biomolecules

International Nuclear Information System (INIS)

Charvat, A.; Lugovoj, E.; Faubel, M.; Abel, B.

2004-01-01

We describe a novel liquid beam mass spectrometer, based on a recently discovered nanosecond laser desorption phenomenon, [W. Kleinekofort, J. Avdiev, and B. Brutschy, Int. J. Mass Ion. Processes 152, 135 (1996)] which allows the liquid-to-vacuum transfer, and subsequent mass analysis of pre-existing ions and ionic associates from liquid microjets of aqueous solutions. The goal of our novel technical approach is to establish a system with good mass resolution that implements improvements on critical components that make the system more reliable and easier to operate. For laser desorption pulsed dye-laser difference frequency mixing is used that provides tunable infrared light near the absorption maximum of liquid water around 3 μm. Different types of liquid beam glass nozzles (convergent capillary and aperture plate nozzles) are investigated and characterized. Starting from theoretical considerations of hydrodynamic drag forces on micrometer size droplets in supersonic rarefied gas flows we succeeded in capturing efficiently the liquid beam in a liquid beam recycling trap operating at the vapor pressure of liquid water. For improving the pollution resistance, the liquid jet high vacuum ion source region is spatially separated from the reflectron time-of-flight mass spectrometer (TOF-MS) working behind a gate valve in an ultrahigh vacuum environment. A simple (simulation optimized) ion optics is employed for the ion transfer from the source to the high vacuum region. This new feature is also mostly responsible for the improved mass resolution. With the present tandem-TOF-MS setup a resolution of m/Δm≅1800 for the low and m/Δm≅700 in the high mass region has been obtained for several biomolecules of different mass and complexity (amino acids, insulin, and cytochrome c)

Laser ablation aerosol particle time-of-flight mass spectrometer (LAAPTOF): performance, reference spectra and classification of atmospheric samples

Science.gov (United States)

Shen, Xiaoli; Ramisetty, Ramakrishna; Mohr, Claudia; Huang, Wei; Leisner, Thomas; Saathoff, Harald

2018-04-01

The laser ablation aerosol particle time-of-flight mass spectrometer (LAAPTOF, AeroMegt GmbH) is able to identify the chemical composition and mixing state of individual aerosol particles, and thus is a tool for elucidating their impacts on human health, visibility, ecosystem, and climate. The overall detection efficiency (ODE) of the instrument we use was determined to range from ˜ (0.01 ± 0.01) to ˜ (4.23 ± 2.36) % for polystyrene latex (PSL) in the size range of 200 to 2000 nm, ˜ (0.44 ± 0.19) to ˜ (6.57 ± 2.38) % for ammonium nitrate (NH4NO3), and ˜ (0.14 ± 0.02) to ˜ (1.46 ± 0.08) % for sodium chloride (NaCl) particles in the size range of 300 to 1000 nm. Reference mass spectra of 32 different particle types relevant for atmospheric aerosol (e.g. pure compounds NH4NO3, K2SO4, NaCl, oxalic acid, pinic acid, and pinonic acid; internal mixtures of e.g. salts, secondary organic aerosol, and metallic core-organic shell particles; more complex particles such as soot and dust particles) were determined. Our results show that internally mixed aerosol particles can result in spectra with new clusters of ions, rather than simply a combination of the spectra from the single components. An exemplary 1-day ambient data set was analysed by both classical fuzzy clustering and a reference-spectra-based classification method. Resulting identified particle types were generally well correlated. We show how a combination of both methods can greatly improve the interpretation of single-particle data in field measurements.

Development of a Robust, High Current, Low Power Field Emission Electron Gun for a Spaceflight Reflectron Time-of-Flight Mass Spectrometer

Science.gov (United States)

Southard, Adrian E.; Getty, Stephanie A.; Feng, Steven; Glavin, Daniel P.; Auciello, Orlando; Sumant, Anirudha

2012-01-01

Carbon materials, including carbon nanotubes (CNTs) and nitrogen-incorporated ultrananocrystalline diamond (N-UNCD), have been of considerable interest for field emission applications for over a decade. In particular, robust field emission materials are compelling for space applications due to the low power consumption and potential for miniaturization. A reflectron time-of-flight mass spectrometer (TOF-MS) under development for in situ measurements on the Moon and other Solar System bodies uses a field emitter to generate ions from gaseous samples, using electron ionization. For these unusual environments, robustness, reliability, and long life are of paramount importance, and to this end, we have explored the field emission properties and lifetime of carbon nanotubes and nitrogen-incorporated ultrananocrystalline diamond (N-UNCD) thin films, the latter developed and patented by Argonne National Laboratory. We will present recent investigations of N-UNCD as a robust field emitter, revealing that this material offers stable performance in high vacuum for up to 1000 hours with threshold voltage for emission of about 3-4 V/lJm and current densities in the range of tens of microA. Optimizing the mass resolution and sensitivity of such a mass spectrometer has also been enabled by a parallel effort to scale up a CNT emitter to an array measuring 2 mm x 40 mm. Through simulation and experiment of the new extended format emitter, we have determined that focusing the electron beam is limited due to the angular spread of the emitted electrons. This dispersion effect can be reduced through modification of the electron gun geometry, but this reduces the current reaching the ionization region. By increasing the transmission efficiency of the electron beam to the anode, we have increased the anode current by two orders of magnitude to realize a corresponding enhancement in instrument sensitivity, at a moderate cost to mass resolution. We will report recent experimental and

A Shuttle Upper Atmosphere Mass Spectrometer /SUMS/ experiment

Science.gov (United States)

Blanchard, R. C.; Duckett, R. J.; Hinson, E. W.

1982-01-01

A magnetic mass spectrometer is currently being adapted to the Space Shuttle Orbiter to provide repeated high altitude atmosphere data to support in situ rarefied flow aerodynamics research, i.e., in the high velocity, low density flight regime. The experiment, called Shuttle Upper Atmosphere Mass Spectrometer (SUMS), is the first attempt to design mass spectrometer equipment for flight vehicle aerodynamic data extraction. The SUMS experiment will provide total freestream atmospheric quantitites, principally total mass density, above altitudes at which conventional pressure measurements are valid. Experiment concepts, the expected flight profile, tradeoffs in the design of the total system and flight data reduction plans are discussed. Development plans are based upon a SUMS first flight after the Orbiter initial development flights.

Time of flight spectra of electrons emitted from graphite after positron annihilation

International Nuclear Information System (INIS)

Gladen, R W; Chirayath, V A; Chrysler, M D; Mcdonald, A D; Fairchild, A J; Shastry, K; Koymen, A R; Weiss, A H

2017-01-01

Low energy (∼2 eV) positrons were deposited onto the surface of highly oriented pyrolytic graphite (HOPG) using a positron beam equipped with a time of flight (TOF) spectrometer. The energy of the electrons emitted as a result of various secondary processes due to positron annihilation was measured using the University of Texas at Arlington’s (UTA) TOF spectrometer. The positron annihilation-induced electron spectra show the presence of a carbon KLL Auger peak at ∼263 eV. The use of a very low energy beam allowed us to observe a new feature not previously seen: a broad peak which reached to a maximum intensity at ∼4 eV and extended up to a maximum energy of ∼15 eV. The low energy nature of the peak was confirmed by the finding that the peak was eliminated when a tube in front of the sample was biased at -15 V. The determination that the electrons in the peak are leaving the surface with energies up to 7 times the incoming positron energy indicates that the electrons under the broad peak were emitted as a result of a positron annihilation related process. (paper)

Comparison of linear intrascan and interscan dynamic ranges of Orbitrap and ion-mobility time-of-flight mass spectrometers.

Science.gov (United States)

Kaufmann, Anton; Walker, Stephan

2017-11-30

The linear intrascan and interscan dynamic ranges of mass spectrometers are important in metabolome and residue analysis. A large linear dynamic range is mandatory if both low- and high-abundance ions have to be detected and quantitated in heavy matrix samples. These performance criteria, as provided by modern high-resolution mass spectrometry (HRMS), were systematically investigated. The comparison included two generations of Orbitraps, and an ion mobility quadrupole time-of-flight (QTOF) system In addition, different scan modes, as provided by the utilized instruments, were investigated. Calibration curves of different compounds covering a concentration range of five orders of magnitude were measured to evaluate the linear interscan dynamic range. The linear intrascan dynamic range and the resulting mass accuracy were evaluated by repeating these measurements in the presence of a very intense background. Modern HRMS instruments can show linear dynamic ranges of five orders of magnitude. Often, however, the linear dynamic range is limited by the detection capability (sensitivity and selectivity) and by the electrospray ionization. Orbitraps, as opposed to TOF instruments, show a reduced intrascan dynamic range. This is due to the limited C-trap and Orbitrap capacity. The tested TOF instrument shows poorer mass accuracies than the Orbitraps. In contrast, hyphenation with an ion-mobility device seems not to affect the linear dynamic range. The linear dynamic range of modern HRMS instrumentation has been significantly improved. This also refers to the virtual absence of systematic mass shifts at high ion abundances. The intrascan dynamic range of the current Orbitrap technology may still be a limitation when analyzing complex matrix extracts. On the other hand, the linear dynamic range is not only limited by the detector technology, but can also be shortened by peripheral devices, where the ionization and transfer of ions take place. Copyright © 2017 John Wiley

The SPEDE spectrometer

Science.gov (United States)

Papadakis, P.; Cox, D. M.; O'Neill, G. G.; Borge, M. J. G.; Butler, P. A.; Gaffney, L. P.; Greenlees, P. T.; Herzberg, R.-D.; Illana, A.; Joss, D. T.; Konki, J.; Kröll, T.; Ojala, J.; Page, R. D.; Rahkila, P.; Ranttila, K.; Thornhill, J.; Tuunanen, J.; Van Duppen, P.; Warr, N.; Pakarinen, J.

2018-03-01

The electron spectrometer, SPEDE, has been developed and will be employed in conjunction with the Miniball spectrometer at the HIE-ISOLDE facility, CERN. SPEDE allows for direct measurement of internal conversion electrons emitted in-flight, without employing magnetic fields to transport or momentum filter the electrons. Together with the Miniball spectrometer, it enables simultaneous observation of γ rays and conversion electrons in Coulomb excitation experiments using radioactive ion beams.

High resolution fast neutron spectrometry without time-of-flight

International Nuclear Information System (INIS)

Evans, A.E.; Brandenberger, J.D.

1978-01-01

Performance tests of a spectrometer tube of the type developed by Cuttler and Shalev show that the measurement of fast neutron spectra with this device can be made with an energy resolution previously obtainable only in large time-of-flight facilities. In preliminary tests, resolutions of 16.4 keV for thermal neutrons and 30.9 keV for 1-MeV neutrons were obtained. A broad-window pulse-shape discrimination (PSD) system is used to remove from pulse-height distributions most of the continua due to 3 He-recoil events, noise, and wall effect. Use of PSD improved the energy resolution to 12.9 keV for thermal neutrons and 29.2 keV for 1-MeV neutrons. The detector is a viable tool for neutron research at nominally equipped accelerator laboratories

Real-time monitoring of trace-level VOCs by an ultrasensitive compact lamp-based VUV photoionization mass spectrometer

Science.gov (United States)

Sun, W. Q.; Shu, J. N.; Zhang, P.; Li, Z.; Li, N. N.; Liang, M.; Yang, B.

2015-06-01

In this study, we report on the development of a compact lamp-based vacuum ultraviolet (VUV) photoionization mass spectrometer (PIMS; hereafter referred to as VUV-PIMS) in our laboratory; it is composed of a radio frequency-powered VUV lamp, a VUV photoionizer, an ion-immigration region, and a reflection time-of-flight mass spectrometer. By utilizing the novel photoionizer consisting of a photoionization cavity and a VUV light baffle, extremely low background noise was obtained. An ultrasensitive detection limit (2σ) of 3 pptv was achieved for benzene after an acquisition time of 10 s. To examine its potential for application in real-time sample monitoring, the developed VUV-PIMS was employed for the continuous measurement of urban air for six days in Beijing, China. Strong signals of trace-level volatile organic compounds such as benzene and its alkylated derivatives were observed in the mass spectra. These initial experimental results reveal that the instrument can be used for the online monitoring of trace-level species in the atmosphere.

Two Dual Ion Spectrometer Flight Units of the Fast Plasma Instrument Suite (FPI) for the Magnetospheric Multiscale Mission (MMS)

Science.gov (United States)

Adams, Mitzi

2014-01-01

Two Dual Ion Spectrometer flight units of the Fast Plasma Instrument Suite (FPI) for the Magnetospheric Multiscale Mission (MMS) have returned to MSFC for flight testing. Anticipated to begin on June 30, tests will ensue in the Low Energy Electron and Ion Facility of the Heliophysics and Planetary Science Office (ZP13), managed by Dr. Victoria Coffey of the Natural Environments Branch of the Engineering Directorate (EV44). The MMS mission consists of four identical spacecraft, whose purpose is to study magnetic reconnection in the boundary regions of Earth's magnetosphere.

Laser ablation aerosol particle time-of-flight mass spectrometer (LAAPTOF: performance, reference spectra and classification of atmospheric samples

Directory of Open Access Journals (Sweden)

X. Shen

2018-04-01

Full Text Available The laser ablation aerosol particle time-of-flight mass spectrometer (LAAPTOF, AeroMegt GmbH is able to identify the chemical composition and mixing state of individual aerosol particles, and thus is a tool for elucidating their impacts on human health, visibility, ecosystem, and climate. The overall detection efficiency (ODE of the instrument we use was determined to range from  ∼  (0.01 ± 0.01 to  ∼  (4.23 ± 2.36 % for polystyrene latex (PSL in the size range of 200 to 2000 nm,  ∼  (0.44 ± 0.19 to  ∼  (6.57 ± 2.38 % for ammonium nitrate (NH4NO3, and  ∼  (0.14 ± 0.02 to  ∼  (1.46 ± 0.08 % for sodium chloride (NaCl particles in the size range of 300 to 1000 nm. Reference mass spectra of 32 different particle types relevant for atmospheric aerosol (e.g. pure compounds NH4NO3, K2SO4, NaCl, oxalic acid, pinic acid, and pinonic acid; internal mixtures of e.g. salts, secondary organic aerosol, and metallic core–organic shell particles; more complex particles such as soot and dust particles were determined. Our results show that internally mixed aerosol particles can result in spectra with new clusters of ions, rather than simply a combination of the spectra from the single components. An exemplary 1-day ambient data set was analysed by both classical fuzzy clustering and a reference-spectra-based classification method. Resulting identified particle types were generally well correlated. We show how a combination of both methods can greatly improve the interpretation of single-particle data in field measurements.

High intensity TOF spectrometer for cold neutrons

International Nuclear Information System (INIS)

Maayouf, R.M.; Abd El-Kawy, A.; Habib, N.; Adib, M.; Hamouda, I.

1984-01-01

This work presents a neutron time-of-flight (TOF) spectrometer developed specially for total neutron cross-section measurements at neutron energies below 5 MeV and sample's temperature varying from the liquid nitrogen one and up to 500 0 K. The spectrometer is equipped by remote control unit, designed especially, in order to move the sample in and out of the beam during the experimental measurements. The spectrometer has proved to be useful for transmission measurements at neutron energies below 5 MeV. It has a reasonable energy resolution (4.4%) and high effect to background ratio (11.1) at 5 MeV

Application of MSS-neutron spin echo spectrometer to pulsed neutron sources

International Nuclear Information System (INIS)

Tasaki, S.; Ebisawa, T.; Hino, M.; Kawai, T.

2001-01-01

A multilayer spin splitter (MSS) is a neutron device that gives phase difference between field-parallel and -antiparallel spin component of a superposing state. Since the phase difference is equivalent to the Larmor precession angle, MSS enables us to construct a new type of neutron spin echo (NSE) spectrometer. The new NSE spectrometer has its properties that 1. since the phase shift is neutron flight path length, the spectrometer can be drastically small, 2. the neutron spin echo time is proportional to the neutron wavelength. (author)

Sensitivity and response time improvements in millimeter-wave spectrometers

International Nuclear Information System (INIS)

Kolbe, W.F.; Leskovar, B.

1980-09-01

A new version of a microwave spectrometer for the detection of gaseous pollutants and other atmospheric constituents is described. The spectrometer, which operates in the vicinity of 70 GHz, employs a Fabry-Perot resonator as a sample cell and uses superhetrodyne detection for high sensitivity. The spectrometer has been modified to incorporate a frequency doubler modulated at 30 MHz to permit operation with a single Gunn oscillator source. As a result, faster response time and somewhat greater sensitivity are obtained. The spectrometer is capable of detecting a minimum concentration of 1 ppM of SO 2 diluted in air with a 1 second time constant. For OCS diluted in air, the minimum detectable concentration is 800 ppB and with a 10 second time constant 300 ppB

Indigenously built resonance ionization mass spectrometer

International Nuclear Information System (INIS)

Razvi, M.A.N.; Jayasekharan, T.; Thankarajan, K.; Guhagarkar, M.B.; Dixit, M.N.; Bhale, G.L.

2000-04-01

Design, fabrication and performance testing of an indigenously built Resonance Ionization Mass Spectrometer (RIMS) is presented in this report. The instrument is totally indigenous, but for the laser components consisting of the excimer laser and tunable dye lasers. Constructional details of atomic beam source and linear time-of-flight mass spectrometer are included. Finally, commissioning and performance testing of the instrument is described. Mass resolving power of 400 and a detection limit of 100 atoms has been achieved using this RIMS set-up. (author)

High resolution time-of-flight spectrometer for crossed molecular beam study of elementary chemical reactions

International Nuclear Information System (INIS)

Qiu Minghui; Che Li; Ren Zefeng; Dai Dongxu; Wang Xiuyan; Yang Xueming

2005-01-01

In this article, we describe an apparatus in our laboratory for investigating elementary chemical reactions using the high resolution time-of-flight Rydberg tagging method. In this apparatus, we have adopted a rotating source design so that collision energy can be changed for crossed beam studies of chemical reactions. Preliminary results on the HI photodissociation and the F atom reaction with H 2 are reported here. These results suggest that the experimental apparatus is potentially a powerful tool for investigating state-to-state dynamics of elementary chemical reactions

Eddy covariance emission and deposition flux measurements using proton transfer reaction – time of flight – mass spectrometry (PTR-TOF-MS): comparison with PTR-MS measured vertical gradients and fluxes

NARCIS (Netherlands)

Park, J.H.; Goldstein, A.H.; Timkovsky, J|info:eu-repo/dai/nl/330541676; Fares, S.; Weber, R.; Karlik, J.; Holzinger, R.|info:eu-repo/dai/nl/337989338

2013-01-01

During summer 2010, a proton transfer reaction – time of flight – mass spectrometer (PTR-TOF-MS) and a quadrupole proton transfer reaction mass spectrometer (PTR-MS) were deployed simultaneously for one month in an orange orchard in the Central Valley of California to collect continuous data

Rapid Quadrupole-Time-of-Flight Mass Spectrometry Method Quantifies Oxygen-Rich Lignin Compound in Complex Mixtures

Science.gov (United States)

Boes, Kelsey S.; Roberts, Michael S.; Vinueza, Nelson R.

2018-03-01

Complex mixture analysis is a costly and time-consuming task facing researchers with foci as varied as food science and fuel analysis. When faced with the task of quantifying oxygen-rich bio-oil molecules in a complex diesel mixture, we asked whether complex mixtures could be qualitatively and quantitatively analyzed on a single mass spectrometer with mid-range resolving power without the use of lengthy separations. To answer this question, we developed and evaluated a quantitation method that eliminated chromatography steps and expanded the use of quadrupole-time-of-flight mass spectrometry from primarily qualitative to quantitative as well. To account for mixture complexity, the method employed an ionization dopant, targeted tandem mass spectrometry, and an internal standard. This combination of three techniques achieved reliable quantitation of oxygen-rich eugenol in diesel from 300 to 2500 ng/mL with sufficient linearity (R2 = 0.97 ± 0.01) and excellent accuracy (percent error = 0% ± 5). To understand the limitations of the method, it was compared to quantitation attained on a triple quadrupole mass spectrometer, the gold standard for quantitation. The triple quadrupole quantified eugenol from 50 to 2500 ng/mL with stronger linearity (R2 = 0.996 ± 0.003) than the quadrupole-time-of-flight and comparable accuracy (percent error = 4% ± 5). This demonstrates that a quadrupole-time-of-flight can be used for not only qualitative analysis but also targeted quantitation of oxygen-rich lignin molecules in complex mixtures without extensive sample preparation. The rapid and cost-effective method presented here offers new possibilities for bio-oil research, including: (1) allowing for bio-oil studies that demand repetitive analysis as process parameters are changed and (2) making this research accessible to more laboratories. [Figure not available: see fulltext.

Development of cold neutron spectrometers

International Nuclear Information System (INIS)

Lee, Changhee; Lee, C. H.; So, J. Y.; Park, S.; Han, Y. S.; Cho, S. J.; Moon, M. K.; Choi, Y. H.; Sun, G. M.

2012-03-01

□ Cold Neutron Triple Axsis Spectrometer (Cold-TAS) Development Ο Fabrication and Installation of the Major Cold-TAS Components Ο Performance Test of the Cold-TAS □ Cold Neutron Time-of-Flight Spectrometer(DC-TOF) Development Ο Fabrication of the Major DC-TOF Components Ο Development DC-TOF Data Reduction Software □ Expected Contribution The two world-class inelastic neutron scattering instruments measure atomic or molecular scale dynamics of meV energy range. This unprecedented measurement capability in the country will enable domestic and international scientists to observe new phenomena in their materials research to obtain world class results. Especially those who work in the fields of magnetic properties of superconductors and multiferroics, molecular dynamics, etc. will get more benefit from these two instruments

Time-of-flight mass spectrometer using an imaging detector and a rotating electric field

International Nuclear Information System (INIS)

Katayama, Atsushi; Kameo, Yutaka; Nakashima, Mikio

2008-01-01

A new technique for minor isotope analysis that uses a rotating electric field and an imaging detector is described. The rotating electric field is generated by six cylindrically arranged plane electrodes with multi-phase sinusoidal wave voltage. When ion packets that are discriminated by time-of-flight enter the rotating electric field, they are circularly deflected, rendering a spiral image on the fluorescent screen of the detector. This spiral image represents m/z values of ions as the position and abundance of ions as brightness. For minor isotopes analyses, the micro channel plate detector under gate control operation is used to eliminate the influence of high intensity of major isotopes. (author)

Ion optics of a new time-of-flight mass spectrometer for quantitative surface analysis

International Nuclear Information System (INIS)

Veryovkin, Igor V.; Calaway, Wallis F.; Pellin, Michael J.

2004-01-01

A new time-of-flight instrument for quantitative surface analysis was developed and constructed at Argonne National Laboratory. It implements ion sputtering and laser desorption for probing analyzed samples and can operate in regimes of secondary neutral mass spectrometry with laser post-ionization and secondary ion mass spectrometry. The instrument incorporates two new ion optics developments: (1) 'push-pull' front end ion optics and (2) focusing and deflecting lens. Implementing these novel elements significantly enhance analytical capabilities of the instrument. Extensive three-dimensional computer simulations of the instrument were conducted in SIMION 3D (c) to perfect its ion optics. The operating principles of the new ion optical systems are described, and a scheme of the new instrument is outlined together with its operating modes

Angle-resolved ion TOF spectrometer with a position sensitive detector

Energy Technology Data Exchange (ETDEWEB)

Saito, Norio [Electrotechnical Lab., Tsukuba, Ibaraki (Japan); Heiser, F; Wieliczec, K; Becker, U

1996-07-01

A angle-resolved ion time-of-flight mass spectrometer with a position sensitive anode has been investigated. Performance of this spectrometer has been demonstrated by measuring an angular distribution of a fragment ion pair, C{sup +} + O{sup +}, from CO at the photon energy of 287.4 eV. The obtained angular distribution is very close to the theoretically expected one. (author)

Wide-range scintillation spectrometer of fast neutrons

International Nuclear Information System (INIS)

Blinov, M.V.; Gavrilov, B.P.; Ivannikova, L.L.; Kozulin, Eh.M.; Mozhaev, A.N.; Saidgareev, V.M.; Tyurin, G.P.

1984-01-01

A spectrometer of fast neutrons developed on the base of stilbene crystas and permitting to detect neutrons simultaneously by time-of-flight and recoil protons with analysis of pulse shape in the 0.5-50 MeV energy range is described. The detecting part is performed in the CAMAC standard. The ''Minsk-32'' computer was used for data storage and preliminary processing

Spectrometry using the PTB neutron multisphere spectrometer (NEMUS) at flight altitudes and at ground level

CERN Document Server

Wiegel, B; Matzke, M; Schrewe, U J; Wittstock, J

2002-01-01

Bonner sphere measurements are presented for flights at altitudes of up to 12 km and geomagnetic latitudes between 26 deg.N and 86 deg.N and compared with results obtained by several survey meters. As an example of the natural neutron background near sea level, results from a recent longterm measurement campaign performed at the PTB site using an extended spectrometer are presented. The dependence of neutron fluence and ambient dose equivalent on the atmospheric pressure is demonstrated.

Spherical neutron polarimetry applied to spin-echo and time-of-flight spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Lelievre-Berna, E., E-mail: lelievre@ill.e [Institut Laue Langevin (ILL), 6 rue Jules Horowitz, 38042 Grenoble Cedex 9 (France); Bentley, P.; Bourgeat-Lami, E.; Thomas, M. [Institut Laue Langevin (ILL), 6 rue Jules Horowitz, 38042 Grenoble Cedex 9 (France); Pappas, C. [Helmholtz Centre Berlin for Materials and Energy (HCB), Glienickerstr. 100, 14109 Berlin (Germany); Faculty of Applied Sciences, Delft University of Technology, Mekelweg 15, 2629 JB Delft (Netherlands); Kischnik, R.; Moskvin, E. [Helmholtz Centre Berlin for Materials and Energy (HCB), Glienickerstr. 100, 14109 Berlin (Germany)

2009-09-01

The changes in direction of the neutron spin that take place on scattering by a magnetic interaction vector are highly dependent on their relative directions. In some circumstances, without zero-field polarimeter, it is impossible to distinguish between a simple depolarisation and a rotation of the polarisation vector. Motivated by the investigation of chiral magnetic fluctuations, we have implemented the third-generation zero-field polarimeter Cryopad on the neutron spin-echo spectrometer SPAN at the Helmholtz Centre Berlin (HCB). We present the method and the limitations of this novel technique that is now available on IN15 at the ILL. The huge progress accomplished with {sup 3}He neutron spin filters/flippers are going to facilitate the exploitation of polarised beams at spallation sources. Zero-field polarimeters like Cryopad are used routinely at several steady-state sources but their design would be inefficient at a pulse source. We have investigated the possibility to implement a zero-field polarimeter on a time-of-flight spectrometer. We propose a design that would lead to a better efficiency and present the finite element calculations.

High mass resolution time of flight mass spectrometer for measuring products in heterogeneous catalysis in highly sensitive microreactors

DEFF Research Database (Denmark)

Andersen, Thomas; Jensen, Robert; Christensen, M. K.

2012-01-01

We demonstrate a combined microreactor and time of flight system for testing and characterization of heterogeneous catalysts with high resolution mass spectrometry and high sensitivity. Catalyst testing is performed in silicon-based microreactors which have high sensitivity and fast thermal...

Multiple-reflection time-of-flight mass spectrometry for in situ applications

International Nuclear Information System (INIS)

Dickel, T.; Plaß, W.R.; Lang, J.; Ebert, J.; Geissel, H.; Haettner, E.; Jesch, C.; Lippert, W.; Petrick, M.; Scheidenberger, C.; Yavor, M.I.

2013-01-01

Highlights: • MR-TOF-MS: huge potential in chemistry, medicine, space science, homeland security. • Compact MR-TOF-MS (length ∼30 cm) with very high mass resolving powers (10 5 ). • Combination of high resolving power (>10 5 ), mobility, API for in situ measurements. • Envisaged applications of mobile MR-TOF-MS. -- Abstract: Multiple-reflection time-of-flight mass spectrometers (MR-TOF-MS) have recently been installed at different low-energy radioactive ion beam facilities. They are used as isobar separators with high ion capacity and as mass spectrometers with high mass resolving power and accuracy for short-lived nuclei. Furthermore, MR-TOF-MS have a huge potential for applications in other fields, such as chemistry, biology, medicine, space science, and homeland security. The development, commissioning and results of an MR-TOF-MS is presented, which serves as proof-of-principle to show that very high mass resolving powers (∼10 5 ) can be achieved in a compact device (length ∼30 cm). Based on this work, an MR-TOF-MS for in situ application has been designed. For the first time, this device combines very high mass resolving power (>10 5 ), mobility, and an atmospheric pressure inlet in one instrument. It will enable in situ measurements without sample preparation at very high mass accuracy. Envisaged applications of this mobile MR-TOF-MS are discussed

Multiple-reflection time-of-flight mass spectrometry for in situ applications

Energy Technology Data Exchange (ETDEWEB)

Dickel, T., E-mail: t.dickel@gsi.de [II. Physikalisches Institut, Justus-Liebig-Universität Gießen, 35392 Gießen (Germany); GSI Helmholtzzentrum für Schwerionenforschung GmbH, Planckstraße 1, 64291 Darmstadt (Germany); Plaß, W.R. [II. Physikalisches Institut, Justus-Liebig-Universität Gießen, 35392 Gießen (Germany); GSI Helmholtzzentrum für Schwerionenforschung GmbH, Planckstraße 1, 64291 Darmstadt (Germany); Lang, J.; Ebert, J. [II. Physikalisches Institut, Justus-Liebig-Universität Gießen, 35392 Gießen (Germany); Geissel, H.; Haettner, E. [II. Physikalisches Institut, Justus-Liebig-Universität Gießen, 35392 Gießen (Germany); GSI Helmholtzzentrum für Schwerionenforschung GmbH, Planckstraße 1, 64291 Darmstadt (Germany); Jesch, C.; Lippert, W.; Petrick, M. [II. Physikalisches Institut, Justus-Liebig-Universität Gießen, 35392 Gießen (Germany); Scheidenberger, C. [II. Physikalisches Institut, Justus-Liebig-Universität Gießen, 35392 Gießen (Germany); GSI Helmholtzzentrum für Schwerionenforschung GmbH, Planckstraße 1, 64291 Darmstadt (Germany); Yavor, M.I. [Institute for Analytical Instrumentation, Russian Academy of Sciences, 190103 St. Petersburg (Russian Federation)

2013-12-15

Highlights: • MR-TOF-MS: huge potential in chemistry, medicine, space science, homeland security. • Compact MR-TOF-MS (length ∼30 cm) with very high mass resolving powers (10{sup 5}). • Combination of high resolving power (>10{sup 5}), mobility, API for in situ measurements. • Envisaged applications of mobile MR-TOF-MS. -- Abstract: Multiple-reflection time-of-flight mass spectrometers (MR-TOF-MS) have recently been installed at different low-energy radioactive ion beam facilities. They are used as isobar separators with high ion capacity and as mass spectrometers with high mass resolving power and accuracy for short-lived nuclei. Furthermore, MR-TOF-MS have a huge potential for applications in other fields, such as chemistry, biology, medicine, space science, and homeland security. The development, commissioning and results of an MR-TOF-MS is presented, which serves as proof-of-principle to show that very high mass resolving powers (∼10{sup 5}) can be achieved in a compact device (length ∼30 cm). Based on this work, an MR-TOF-MS for in situ application has been designed. For the first time, this device combines very high mass resolving power (>10{sup 5}), mobility, and an atmospheric pressure inlet in one instrument. It will enable in situ measurements without sample preparation at very high mass accuracy. Envisaged applications of this mobile MR-TOF-MS are discussed.

A new Time-of-Flight mass measurement project for exotic nuclei and ultra-high precision detector development

Directory of Open Access Journals (Sweden)

Sun Bao-Hua

2016-01-01

Full Text Available The time-of-flight (TOF mass spectrometry (MS, a high-resolution magnetic spectrometer equipped with a fast particle tracking system, is well recognized by its ability in weighing the most exotic nuclei. Currently such TOF-MS can achieve a mass resolution power of about 2×10−4. We show that the mass resolution can be further improved by one order of magnitude with augmented timing and position detectors. We report the progress in developing ultra-fast detectors to be used in TOF-MS.

A multi-analyzer crystal spectrometer (MAX) for pulsed neutron sources

International Nuclear Information System (INIS)

Tajima, K.; Ishikawa, Y.; Kanai, K.; Windsor, C.G.; Tomiyoshi, S.

1982-03-01

The paper describes the principle and initial performance of a multi-analyzer crystal spectrometer (MAX) recently installed at the KENS spallation neutron source at Tsukuba. The spectrometer is able to make time of flight scans along a desired direction in reciprocal space, covering a wide range of the energy transfers corresponding to the fifteen analyzer crystals. The constant Q or constant E modes of operation can be performed. The spectrometer is particularly suited for studying collective excitations such as phonons and magnons to high energy transfers using single crystal samples. (author)

Fast neutron scintillation spectrometer in a heavy ion accelerator

International Nuclear Information System (INIS)

Blinov, M.V.; Gavrilov, B.P.; Ivannikova, L.L.; Kozulin, Eh.M.; Mozhaev, A.N.; Tyurin, G.P.

1984-01-01

Scintillation fast neutron spectrometer in a heavy ion accelerator is described in short. The spectrometer is used to measure characteristics of neutrons emitted in heavy ion interaction with different nuclei. Experiment was performed on the base of particle flight from 0.7 up to 2 m. Within the angle range of 0-150 deg. The technique is based on recording of two-dimensional neutron spectra obtained due to combination of the time-of-flight method and the method of recoil proton energy detection. Two measuring channels were used in the spectrometer. Each channel comprise both amplitude and time tracks. Detector on the base microchannel plates (MCP) generated a signal in passing the next ion bunch was used in order to obtain the time mark. Data from the scintillation block are recorded with respect to three parameters: recoil proton amplitude, time of neutron or γ-quantum arrival in respect of MCP-sensor pulse. Apparatus is carried out within the CAMAC standard. The spectrometer calibration within the 1-20 MeV neutron range was conducted in the Van-de-Graaf accelerator, and for higher energies - with the use of lightguides. Spectrometer time resolution for neutron energies of 0.5-50 MeV constituted 1.5-1.8 ns. The above measuring of neutron spectra from 1 /H2C+ 181 Ta and sup(20, 22)Ne+sup(181)Ta reaction have revealed a possibility of the experiment organization in heavy ion accelerators in the presence of strong neutron and γ-fields. Organization of multi-dimensional analysis combining two methods allows one to separate accelerator cycle, a region of the most reliable information, free of a low-energy gamma background and limited both by a dynamic threshold and a region of permissible energy values

Elements of Tiny Plasma Spectrometers

Data.gov (United States)

National Aeronautics and Space Administration — We propose to advance major elements of a miniaturized plasma spectrometer for flight on future missions. This type of instrument has been developed and successfully...

Parametric evaluation of laser ablation and ionization time-of-flight mass spectrometry with ion guide cooling cell

International Nuclear Information System (INIS)

Peng Ding; He Jian; Yu Quan; Chen Lizhi; Hang Wei; Huang Benli

2008-01-01

A novel laser ablation and ionization time-of-flight mass spectrometer has been used for direct elemental analysis of alloys. The system was incorporated with an ion guide cooling cell to reduce the kinetic energy distribution for the purpose of better resolution. Parametric studies have been conducted on the system with respect to the buffer gas pressure and the distance from sample to the nozzle to obtain the maximal signal intensities. In order to obtain satisfactory relative sensitivity coefficients (RSC) for different elements, the influence of the laser irradiance, nozzle voltage, rf frequency and voltage of the hexapole were also investigated. Under the optimized conditions, the RSC of different elements were available for direct semi-quantitative analysis. The mass resolving power (FWHM) of the spectrometer was approximately 7000 (m/Δm) and the limit of detection (LOD) was 10 -6 g/g

Principles of time-of-flight tomography

International Nuclear Information System (INIS)

Campagnolo, R.; Garderet, P.; Lecomte, J.L.; Bouvier, A.; Darier, P.; Soussaline, F.

1983-03-01

After a short introduction to the physics of time-of-flight positron tomography, the various aspects of this technique are presented. The characteristics including data acquisition and image reconstruction system of a positron tomograph (TTV01) which uses time-of-flight information, are described. The preliminary results obtained with TTV01, such as resolution and sensitivity, as well as phantom images, are presented [fr

Construction of a time-of-flight neutron spectrometer for reaction angles 000 and study of the reaction 65Cu(p,xn) 65Zn for Esub(p)=26.7 MeV

International Nuclear Information System (INIS)

Holler, Y.

1984-01-01

At the Hamburg Isochronous Cyclotron a novel time-of-flight neutron spectrometer was designed, constructed, and tested by means of a for the planned application typical nuclear reaction. The apparature was optimized for the measurement of continuous, structure-deficient neutron spectra in a wide angular range at a reproducible, as low as possible scattering neutron background. Such a facility is fitted to the strengths of the Hamburg cyclotron and allows to study questions on the precompound emission and on the inelastic projectile ( 3 He) breakup. The final test was performed with the reaction 65 Cu(p,xn) 65 Zn at Esub(p)=26.7 MeV for which already comparable data over a smaller angular range were present. In the analysis of the measurement results performed regarding the precompound effects the hybrid-exciton model calculations let recognize essential deviations at high neutron energies in the range of the extreme reaction angles. (orig./HSI) [de

Shock tube/time-of-flight mass spectrometer for high temperature kinetic studies

International Nuclear Information System (INIS)

Tranter, Robert S.; Giri, Binod R.; Kiefer, John H.

2007-01-01

A shock tube (ST) with online, time-of-flight mass spectrometric (TOF-MS) detection has been constructed for the study of elementary reactions at high temperature. The ST and TOF-MS are coupled by a differentially pumped molecular beam sampling interface, which ensures that the samples entering the TOF-MS are not contaminated by gases drawn from the cold end wall thermal boundary layer in the ST. Additionally, the interface allows a large range of postshock pressures to be used in the shock tube while maintaining high vacuum in the TOF-MS. The apparatus and the details of the sampling system are described along with an analysis in which cooling of the sampled gases and minimization of thermal boundary layer effects are discussed. The accuracy of kinetic measurements made with the apparatus has been tested by investigating the thermal unimolecular dissociation of cyclohexene to ethylene and 1,3-butadiene, a well characterized reaction for which considerable literature data that are in good agreement exist. The experiments were performed at nominal reflected shock wave pressures of 600 and 1300 Torr, and temperatures ranging from 1260 to 1430 K. The rate coefficients obtained are compared with the earlier shock tube studies and are found to be in very good agreement. As expected no significant difference is observed in the rate constant between pressures of 600 and 1300 Torr

Time-of-flight electron energy loss spectroscopy using TM110 deflection cavities

Directory of Open Access Journals (Sweden)

W. Verhoeven

2016-09-01

Full Text Available We demonstrate the use of two TM110 resonant cavities to generate ultrashort electron pulses and subsequently measure electron energy losses in a time-of-flight type of setup. The method utilizes two synchronized microwave cavities separated by a drift space of 1.45 m. The setup has an energy resolution of 12 ± 2 eV FWHM at 30 keV, with an upper limit for the temporal resolution of 2.7 ± 0.4 ps. Both the time and energy resolution are currently limited by the brightness of the tungsten filament electron gun used. Through simulations, it is shown that an energy resolution of 0.95 eV and a temporal resolution of 110 fs can be achieved using an electron gun with a higher brightness. With this, a new method is provided for time-resolved electron spectroscopy without the need for elaborate laser setups or expensive magnetic spectrometers.

Metrology for terahertz time-domain spectrometers

Science.gov (United States)

Molloy, John F.; Naftaly, Mira

2015-12-01

In recent years the terahertz time-domain spectrometer (THz TDS) [1] has emerged as a key measurement device for spectroscopic investigations in the frequency range of 0.1-5 THz. To date, almost every type of material has been studied using THz TDS, including semiconductors, ceramics, polymers, metal films, liquid crystals, glasses, pharmaceuticals, DNA molecules, proteins, gases, composites, foams, oils, and many others. Measurements with a TDS are made in the time domain; conversion from the time domain data to a frequency spectrum is achieved by applying the Fourier Transform, calculated numerically using the Fast Fourier Transform (FFT) algorithm. As in many other types of spectrometer, THz TDS requires that the sample data be referenced to similarly acquired data with no sample present. Unlike frequency-domain spectrometers which detect light intensity and measure absorption spectra, a TDS records both amplitude and phase information, and therefore yields both the absorption coefficient and the refractive index of the sample material. The analysis of the data from THz TDS relies on the assumptions that: a) the frequency scale is accurate; b) the measurement of THz field amplitude is linear; and c) that the presence of the sample does not affect the performance characteristics of the instrument. The frequency scale of a THz TDS is derived from the displacement of the delay line; via FFT, positioning errors may give rise to frequency errors that are difficult to quantify. The measurement of the field amplitude in a THz TDS is required to be linear with a dynamic range of the order of 10 000. And attention must be given to the sample positioning and handling in order to avoid sample-related errors.

Users guide to the inelastic rotor spectrometer (IRS)

International Nuclear Information System (INIS)

Bunce, L.J.

1987-11-01

The paper is a users guide to the inelastic rotor spectrometer installed on the Harwell 136 Mev electron linear accelerator HELIOS. The spectrometer is designed to measure neutron inelastic scattering for energy transfers from 50 meV to 400 meV and covering a range of Q values from 1 to 15 A 0-1 . The guide contains a description of:- time-of-flight scales, run and sample changer control units, sample environment, detectors, rotor system, 600 Hz operation of rotor, a run, and data processing. (U.K.)

Testing flight software on the ground: Introducing the hardware-in-the-loop simulation method to the Alpha Magnetic Spectrometer on the International Space Station

Energy Technology Data Exchange (ETDEWEB)

Sun, Wenhao, E-mail: wenhao_sun@126.com [Southeast University, Nanjing 210096 (China); Cai, Xudong [Massachusetts Institute of Technology, MA 02139-4307 (United States); Meng, Qiao [Southeast University, Nanjing 210096 (China)

2016-04-11

Complex automatic protection functions are being added to the onboard software of the Alpha Magnetic Spectrometer. A hardware-in-the-loop simulation method has been introduced to overcome the difficulties of ground testing that are brought by hardware and environmental limitations. We invented a time-saving approach by reusing the flight data as the data source of the simulation system instead of mathematical models. This is easy to implement and it works efficiently. This paper presents the system framework, implementation details and some application examples.

Neutral particle time-of-flight analyzer for the Tandem Mirror Experiment Upgrade (TMX-U)

International Nuclear Information System (INIS)

Hibbs, S.M.; Carter, M.R.; Coutts, G.W.

1985-01-01

We describe the design and performance of a time-of-flight (ToF) analyzer being built for installation on the east end cell of the Tandem Mirror Experiment Upgrade (TMX-U). Its primary purpose is to measure the velocity distribution of escaping charge exchange neutral particles having energies between 20 and 5000 electron volts (eV). It also enables direct determination of the thermal barrier potential when used in conjunction with the plasma potential diagnostic and the end loss ion spectrometer. In addition, it can measure the velocity distribution of passing ions leaving the central cell and of ions trapped in the thermal barrier

Performance comparison and selection criteria: an assessment for choosing the best flight detector for the SIR-2 NIR-spectrometer on Chandrayaan-1

Science.gov (United States)

Sitek, P.; Vilenius, E.; Mall, U.

2008-01-01

We describe the performance evaluation of a sample of InGaAs detectors from which the best unit had to be selected for the flight model of the SIR-2 NIR-spectrometer to be flown on the Chandrayaan-1 mission in 2008.

Laser desorption and time-of-flight mass spectrometry. Fundamentals .Applications

International Nuclear Information System (INIS)

Chaurand, P.

1994-11-01

Time-of-flight mass spectrometry is a very powerful technique for the analysis of heavy molecular ions (100 000 u and more). The ejection in the gas phase and the ionization of these molecules is now possible through the MALDI technique (Matrix Assisted Laser Desorption Ionization). This technique consists in mixing the heavy molecules to be analysed with a organic matrix which absorbs at the wavelength of the laser. The necessary irradiance are of the order of 10 6 W/cm 2 . In these conditions we have shown that the mass resolutions are optimum and that the relative mass accuracies are of the order of 10 -4 . We have also demonstrated that the emission angle of the molecular ions in MALDI depends on the incident angle of the laser light. During the desorption process, the molecular ions are emitted in the opposite direction of the incident laser light. This effect is particularly important for the design of the accelerating stage of the time-of-flight spectrometers. Problems relative to the detection of these heavy molecular ions have been studied in details between 0.5 10 4 m/s and 10 5 m/s. The velocity threshold of the electronic emission is lower than the value of 0.5 10 4 m/s. The relation between the electronic emission and the projectile velocity is complex. Finally, examples on mass identification of C 60 molecules and derivated C 60 are presented. Desorption methods are compared. (author). 32 refs., 34 figs

ISLA: An Isochronous Spectrometer with Large Acceptances

Energy Technology Data Exchange (ETDEWEB)

Bazin, D., E-mail: bazin@nscl.msu.edu; Mittig, W.

2013-12-15

A novel type of recoil mass spectrometer and separator is proposed for the future secondary radioactive beams of the ReA12 accelerator at NSCL/FRIB, inspired from the TOFI spectrometer developed at the Los Alamos National Laboratory for online mass measurements. The Isochronous Spectrometer with Large Acceptances (ISLA) is able to achieve superior characteristics without the compromises that usually plague the design of large acceptance spectrometers. ISLA can provide mass-to-charge ratio (m/q) measurements to better than 1 part in 1000 by using an optically isochronous time-of-flight independent of the momentum vector of the recoiling ions, despite large acceptances of 20% in momentum and 64 msr in solid angle. The characteristics of this unique design are shown, including requirements for auxiliary detectors around the target and the various types of reactions to be used with the re-accelerated radioactive beams of the future ReA12 accelerator.

Prismatic analyzer concept for neutron spectrometers

DEFF Research Database (Denmark)

Birk, Jonas O.; Marko, M.; Freeman, P.G.

2014-01-01

readily be combined with advanced focussing geometries and with multiplexing instrument designs. We present a combination of simulations and data showing three different energies simultaneously reflected from one analyser. Experiments were performed on a cold triple axis instrument and on a prototype...... inverse geometry Time-of-flight spectrometer installed at PSI, Switzerland, and shows excellent agreement with the predictions. Typical improvements will be 2.0 times finer resolution and a factor of 1.9 in flux gain compared to a focussing Rowland geometry, or of 3.3 times finer resolution and a factor...

Development of a new corona discharge based ion source for high resolution time-of-flight chemical ionization mass spectrometer to measure gaseous H2SO4 and aerosol sulfate

Science.gov (United States)

Zheng, Jun; Yang, Dongsen; Ma, Yan; Chen, Mindong; Cheng, Jin; Li, Shizheng; Wang, Ming

2015-10-01

A new corona discharge (CD) based ion source was developed for a commercial high-resolution time-of-flight chemical ionization mass spectrometer (HRToF-CIMS) (Aerodyne Research Inc.) to measure both gaseous sulfuric acid (H2SO4) and aerosol sulfate after thermal desorption. Nitrate core ions (NO3-) were used as reagent ions and were generated by a negative discharge in zero air followed by addition of excess nitrogen dioxide (NO2) to convert primary ions and hydroxyl radicals (OH) into NO3- ions and nitric acid (HNO3). The CD-HRToF-CIMS showed no detectable interference from hundreds parts per billion by volume (ppbv) of sulfur dioxide (SO2). Unlike the atmospheric pressure ionization (API) ToF-CIMS, the CD ion source was integrated onto the ion-molecule reaction (IMR) chamber and which made it possible to measure aerosol sulfate by coupling to a filter inlet for gases and aerosols (FIGAERO). Moreover, compared with a quadrupole-based mass spectrometer, the desired HSO4- signal was detected by its exact mass of m/z 96.960, which was well resolved from the potential interferences of HCO3-ṡ(H2O)2 (m/z 97.014) and O-ṡH2OṡHNO3 (m/z 97.002). In this work, using laboratory-generated standards the CD-HRToF-CIMS was demonstrated to be able to detect as low as 3.1 × 105 molecules cm-3 gaseous H2SO4 and 0.5 μg m-3 ammonium sulfate based on 10-s integration time and two times of the baseline noise. The CD ion source had the advantages of low cost and a simple but robust structure. Since the system was non-radioactive and did not require corrosive HNO3 gas, it can be readily field deployed. The CD-HRToF-CIMS can be a powerful tool for both field and laboratory studies of aerosol formation mechanism and the chemical processes that were critical to understand the evolution of aerosols in the atmosphere.

A proposed neutron spectrometer system for JET

International Nuclear Information System (INIS)

Elevant, T.; Hellbom, G.; Scheffel, J.; Malmskog, S.

1979-12-01

A neutron spectrometer system is proposed primarily for measurements of ion temperature and density and ion beam energy distribution in extended fusion plasmas like e.g. in JET. Three different spectrometers are involved: time of flight, proton recoil and 3 He. Energy resolutions of a few percent both for DD and DT neutrons are provided. Six order of magnitudes in flux ranges will be covered by the system when employing multi-target systems. A neutron collimator and shielding system will be desirable in order to obtain relevant information. Due to the entire differences in energy and fluxes for DD and DT plasmas a flexible collimator-shielding system is recommended

Multi-Grid detector for neutron spectroscopy: results obtained on time-of-flight spectrometer CNCS

Science.gov (United States)

Anastasopoulos, M.; Bebb, R.; Berry, K.; Birch, J.; Bryś, T.; Buffet, J.-C.; Clergeau, J.-F.; Deen, P. P.; Ehlers, G.; van Esch, P.; Everett, S. M.; Guerard, B.; Hall-Wilton, R.; Herwig, K.; Hultman, L.; Höglund, C.; Iruretagoiena, I.; Issa, F.; Jensen, J.; Khaplanov, A.; Kirstein, O.; Lopez Higuera, I.; Piscitelli, F.; Robinson, L.; Schmidt, S.; Stefanescu, I.

2017-04-01

The Multi-Grid detector technology has evolved from the proof-of-principle and characterisation stages. Here we report on the performance of the Multi-Grid detector, the MG.CNCS prototype, which has been installed and tested at the Cold Neutron Chopper Spectrometer, CNCS at SNS. This has allowed a side-by-side comparison to the performance of 3He detectors on an operational instrument. The demonstrator has an active area of 0.2 m2. It is specifically tailored to the specifications of CNCS. The detector was installed in June 2016 and has operated since then, collecting neutron scattering data in parallel to the He-3 detectors of CNCS. In this paper, we present a comprehensive analysis of this data, in particular on instrument energy resolution, rate capability, background and relative efficiency. Stability, gamma-ray and fast neutron sensitivity have also been investigated. The effect of scattering in the detector components has been measured and provides input to comparison for Monte Carlo simulations. All data is presented in comparison to that measured by the 3He detectors simultaneously, showing that all features recorded by one detector are also recorded by the other. The energy resolution matches closely. We find that the Multi-Grid is able to match the data collected by 3He, and see an indication of a considerable advantage in the count rate capability. Based on these results, we are confident that the Multi-Grid detector will be capable of producing high quality scientific data on chopper spectrometers utilising the unprecedented neutron flux of the ESS.

The VERDI fission fragment spectrometer

Directory of Open Access Journals (Sweden)

Frégeau M.O.

2013-12-01

Full Text Available The VERDI time-of-flight spectrometer is dedicated to measurements of fission product yields and of prompt neutron emission data. Pre-neutron fission-fragment masses will be determined by the double time-of-flight (TOF technique. For this purpose an excellent time resolution is required. The time of flight of the fragments will be measured by electrostatic mirrors located near the target and the time signal coming from silicon detectors located at 50 cm on both sides of the target. This configuration, where the stop detector will provide us simultaneously with the kinetic energy of the fragment and timing information, significantly limits energy straggling in comparison to legacy experimental setup where a thin foil was usually used as a stop detector. In order to improve timing resolution, neutron transmutation doped silicon will be used. The high resistivity homogeneity of this material should significantly improve resolution in comparison to standard silicon detectors. Post-neutron fission fragment masses are obtained form the time-of-flight and the energy signal in the silicon detector. As an intermediary step a diamond detector will also be used as start detector located very close to the target. Previous tests have shown that poly-crystalline chemical vapour deposition (pCVD diamonds provides a coincidence time resolution of 150 ps not allowing complete separation between very low-energy fission fragments, alpha particles and noise. New results from using artificial single-crystal diamonds (sCVD show similar time resolution as from pCVD diamonds but also sufficiently good energy resolution.

A novel particle time of flight diagnostic for measurements of shock- and compression-bang times in D3He and DT implosions at the NIF.

Science.gov (United States)

Rinderknecht, H G; Johnson, M Gatu; Zylstra, A B; Sinenian, N; Rosenberg, M J; Frenje, J A; Waugh, C J; Li, C K; Sèguin, F H; Petrasso, R D; Rygg, J R; Kimbrough, J R; MacPhee, A; Collins, G W; Hicks, D; Mackinnon, A; Bell, P; Bionta, R; Clancy, T; Zacharias, R; Döppner, T; Park, H S; LePape, S; Landen, O; Meezan, N; Moses, E I; Glebov, V U; Stoeckl, C; Sangster, T C; Olson, R; Kline, J; Kilkenny, J

2012-10-01

The particle-time-of-flight (pTOF) diagnostic, fielded alongside a wedge range-filter (WRF) proton spectrometer, will provide an absolute timing for the shock-burn weighted ρR measurements that will validate the modeling of implosion dynamics at the National Ignition Facility (NIF). In the first phase of the project, pTOF has recorded accurate bang times in cryogenic DT, DT exploding pusher, and D(3)He implosions using DD or DT neutrons with an accuracy better than ±70 ps. In the second phase of the project, a deflecting magnet will be incorporated into the pTOF design for simultaneous measurements of shock- and compression-bang times in D(3)He-filled surrogate implosions using D(3)He protons and DD-neutrons, respectively.

Doppler time-of-flight imaging

KAUST Repository

Heidrich, Wolfgang; Heide, Felix; Wetzstein, Gordon; Hullin, Matthias

2017-01-01

Systems and methods for imaging object velocity are provided. In an embodiment, at least one Time-of-Flight camera is used to capture a signal representative of an object in motion over an exposure time. Illumination and modulation frequency

In-flight calibration of Hitomi Soft X-ray Spectrometer. (3) Effective area

Science.gov (United States)

Tsujimoto, Masahiro; Okajima, Takashi; Eckart, Megan E.; Hayashi, Takayuki; Hoshino, Akio; Iizuka, Ryo; Kelley, Richard L.; Kilbourne, Caroline A.; Leutenegger, Maurice A.; Maeda, Yoshitomo; Mori, Hideyuki; Porter, Frederick S.; Sato, Kosuke; Sato, Toshiki; Serlemitsos, Peter J.; Szymkowiak, Andrew; Yaqoob, Tahir

2018-03-01

We present the result of the in-flight calibration of the effective area of the Soft X-ray Spectrometer (SXS) on board the Hitomi X-ray satellite using an observation of the Crab nebula. We corrected for artifacts when observing high count rate sources with the X-ray microcalorimeter. We then constructed a spectrum in the 0.5-20 keV band, which we modeled with a single power-law continuum attenuated by interstellar extinction. We evaluated the systematic uncertainty of the spectral parameters by various calibration items. In the 2-12 keV band, the SXS result is consistent with the literature values in flux (2.20 ± 0.08 × 10-8 erg s-1 cm-2 with a 1 σ statistical uncertainty) but is softer in the power-law index (2.19 ± 0.11). The discrepancy is attributable to the systematic uncertainty of about +6%/-7% and +2%/-5% respectively for the flux and the power-law index. The softer spectrum is affected primarily by the systematic uncertainty of the Dewar gate valve transmission and the event screening.

Focusing procedures in time-of-flight mass spectrometry

International Nuclear Information System (INIS)

Ioanoviciu, D.

2002-01-01

Time-of-flight mass spectrometry is a fast growing field due to its ability to handle very fast processes and due to its theoretically unlimited mass range. The performances of the time-of-flight mass analysers are heavily dependent on the progress in ion optics, a periodically reviewed field. In this presentation the various focusing procedures in time-of-flight mass spectrometry are reviewed. For ions of the same charge and mass flight time differences result from different potentials at the location of formation and from the initial velocity spread. There is no simultaneous space and velocity focusing in time-of-flight mass spectrometry. Space focusing of first and second order can be reached in time-of-flight mass analysers having two homogeneous electric field ion sources followed by a field free space in front of the detector. Single and double stage homogeneous electric field mirrors can focus in time ions of different energies. These different energies result when ions leaving different initial sites and arriving simultaneously to an intermediate space focus. Convenient mass dispersion can be obtained by including a mirror. Initial velocity focusing is obtained by the delayed extraction procedure in drift space and mirror time-of-flight mass analysers. Post source pulse focusing aims at the same purpose. Ion source electrodes of hyperbolic shape, operated by high voltage pulses can bring major improvements of the resolution, especially at high masses. For each focusing procedure the geometric and/or electric conditions are given as well as the aberrations allowing the mass resolution determination. The various focusing procedures are compared and a prediction of their future performances was tempted. (author)

Single particle characterization using a light scattering module coupled to a time-of-flight aerosol mass spectrometer

Science.gov (United States)

Cross, E. S.; Onasch, T. B.; Canagaratna, M.; Jayne, J. T.; Kimmel, J.; Yu, X.-Y.; Alexander, M. L.; Worsnop, D. R.; Davidovits, P.

2008-12-01

We present the first single particle results obtained using an Aerodyne time-of-flight aerosol mass spectrometer coupled with a light scattering module (LS-ToF-AMS). The instrument was deployed at the T1 ground site approximately 40 km northeast of the Mexico City Metropolitan Area (MCMA) as part of the MILAGRO field study in March of 2006. The instrument was operated as a standard AMS from 12-30 March, acquiring average chemical composition and size distributions for the ambient aerosol, and in single particle mode from 27-30 March. Over a 75-h sampling period, 12 853 single particle mass spectra were optically triggered, saved, and analyzed. The correlated optical and chemical detection allowed detailed examination of single particle collection and quantification within the LS-ToF-AMS. The single particle data enabled the mixing states of the ambient aerosol to be characterized within the context of the size-resolved ensemble chemical information. The particulate mixing states were examined as a function of sampling time and most of the particles were found to be internal mixtures containing many of the organic and inorganic species identified in the ensemble analysis. The single particle mass spectra were deconvolved, using techniques developed for ensemble AMS data analysis, into HOA, OOA, NH4NO3, (NH4)2SO4, and NH4Cl fractions. Average single particle mass and chemistry measurements are shown to be in agreement with ensemble MS and PTOF measurements. While a significant fraction of ambient particles were internal mixtures of varying degrees, single particle measurements of chemical composition allowed the identification of time periods during which the ambient ensemble was externally mixed. In some cases the chemical composition of the particles suggested a likely source. Throughout the full sampling period, the ambient ensemble was an external mixture of combustion-generated HOA particles from local sources (e.g. traffic), with number concentrations peaking

Time Manager Software for a Flight Processor

Science.gov (United States)

Zoerne, Roger

2012-01-01

Data analysis is a process of inspecting, cleaning, transforming, and modeling data to highlight useful information and suggest conclusions. Accurate timestamps and a timeline of vehicle events are needed to analyze flight data. By moving the timekeeping to the flight processor, there is no longer a need for a redundant time source. If each flight processor is initially synchronized to GPS, they can freewheel and maintain a fairly accurate time throughout the flight with no additional GPS time messages received. How ever, additional GPS time messages will ensure an even greater accuracy. When a timestamp is required, a gettime function is called that immediately reads the time-base register.

Time-Resolved Hard X-Ray Spectrometer

International Nuclear Information System (INIS)

Kenneth Moya; Ian McKennaa; Thomas Keenana; Michael Cuneob

2007-01-01

Wired array studies are being conducted at the SNL Z accelerator to maximize the x-ray generation for inertial confinement fusion targets and high energy density physics experiments. An integral component of these studies is the characterization of the time-resolved spectral content of the x-rays. Due to potential spatial anisotropy in the emitted radiation, it is also critical to diagnose the time-evolved spectral content in a space-resolved manner. To accomplish these two measurement goals, we developed an x-ray spectrometer using a set of high-speed detectors (silicon PIN diodes) with a collimated field-of-view that converged on a 1-cm-diameter spot at the pinch axis. Spectral discrimination is achieved by placing high Z absorbers in front of these detectors. We built two spectrometers to permit simultaneous different angular views of the emitted radiation. Spectral data have been acquired from recent Z shots for the radial and polar views. UNSPEC1 has been adapted to analyze and unfold the measured data to reconstruct the x-ray spectrum. The unfold operator code, UFO2, is being adapted for a more comprehensive spectral unfolding treatment

ALICE Time of Flight Module

CERN Multimedia

The Time-Of-Flight system of ALICE consists of 90 such modules, each containing 15 or 19 Multigap Resistive Plate Chamber (MRPC) strips. This detector is used for identification of charged particles. It measures with high precision (50 ps) the time of flight of charged particles and therefore their velocity. The curvature of the particle trajectory inside the magnetic field gives the momentum, thus the particle mass is calculated and the particle is identified The MRPC is a stack of resistive glass plates, separated from each other by nylon fishing line. The mass production of the chambers (~1600, covering a surface of 150 m2) was done at INFN Bologna, while the first prototypes were bult at CERN.

Time-of-flight laser spectrometer

International Nuclear Information System (INIS)

Izosimov, I.N.; Naumov, Yu.V.; Shishunov, N.A.

1982-01-01

A new method of laser spectroscopy with a multichannel way of recording is proposed. In the above method the beam of laser carrying out resonance excitation of studied atoms at the first stage, is directed along the atom beam. It the generation line width of this laser is much less than doppler broadening of spectral line caused by the atom velocities scattering in the beam, the selection of atoms according to velocities will take place, i. e. only atoms, having a definite projection of velocity on laser beam direction, will be excited. If laser line has several components, concealed in doppler circuit, the spectrum of velocities of excited atoms will also include several components. Spectrum of ion velocities obtained as a result of photoionization of excited atoms, reproduces within the limits of doppler circuit the structure of spectral line, corresponding to atom transition into the given excited state, as laser frequency at the dye is fixed in the process, of measurement. The method, proposed, is characterized not only by the property of multichannel but by a new way of atomic beam collimation. Analysis of ion velocities permits to carry out the regime of non-doppler spectroscopy at weakly collima-- ted atomic beams with collimation degree of 1:3. It gives a gain in sensitivity of about one order in comparison with one-channel methods while operating with high resolution (of 30 MHz order) [ru

Development of grazing incidence devices for space-borne time of flight mass spectrometry

Science.gov (United States)

Cadu, A.; Devoto, P.; Louarn, P.; Sauvaud, J.-A.

2012-04-01

Time of flight mass spectrometer is widely used to study space plasmas in planetary and solar missions. This space-borne instrument selects ions in function of their energy through an electrostatic analyzer. Particles are then post-accelerated to energies in the range of 20 keV to cross a carbon foil. At the foil exit, electrons are emitted and separated from ion beam in the time of flight section. A first detector (a Micro-Channel Plate or MCP) emits a start signal at electron arrival and a second one emits a stop signal at incident ion end of path. The time difference gives the speed of the particle and its mass can be calculated, knowing its initial energy. However, current instruments suffer from strong limitations. The post acceleration needs very high voltage power supplies which are heavy, have a high power consumption and imply technical constraints for the development. A typical instrument weighs from 5 to 6 kg, includes a 20 kV power supply, consumes a least 5 W and encounters corona effect and electrical breakdown problems. Moreover, despite the particle high energy range, scattering and straggling phenomena in the carbon foil significantly reduce the instrument overall resolution. Some methods, such as electrostatic focus lenses or reflectrons, really improve mass separation but global system efficiency remains very low because of the charge state dependence of such devices. The main purpose of our work is to replace carbon foil by grazing incidence MCP's - also known as MPO's, for Micro Pore Optics - for electron emission. Thus, incident particles would back-scatter onto the channel inner surface with an angle of a few degrees. With this solution, we can decrease dispersion sources and lower the power supplies to post accelerate ions. The result would be a lighter and simpler instrument with a substantial resolution improvement. We have first simulated MPO's behavior with TRIM and MARLOWE Monte-Carlo codes. Energy scattering and output angle computed

ALICE Time Of Flight Detector

CERN Multimedia

Alici, A

2013-01-01

Charged particles in the intermediate momentum range are identified in ALICE by the Time Of Flight (TOF) detector. The time measurement with the TOF, in conjunction with the momentum and track length measured by the tracking detector, is used to calculate the particle mass.

Study of preshower in the PANDA target spectrometer

International Nuclear Information System (INIS)

Dutta, Kamal; Kalita, Kushal; Suzuki, K.; Steinschaden, D.; Roy, B.J.

2015-01-01

PANDA (antiProton ANnihilation at DArmstdt) is one of the major projects at FAIR, GSI, Germany. The main objective of this experiment is to study the fundamental questions of hadron physics and QCD in pp¯ annihilation using high intensity cooled anti-proton beams with momenta between 1.5 GeV/c and 15 GeV/c. To achieve high momentum resolution and full solid angle coverage, the PANDA detector is split in to two parts: target spectrometer and forward spectrometer. The target spectrometer is a complex detector consisting of several subsystems surrounding the interaction point. It is surrounded by a 2 T superconducting solenoid magnet. A Micro Vertex Detector (MVD), close to interaction point, detects secondary vertices of D and Hyperon decays. The Straw Tube Tracker (STT) is the central tracking system around the MVD. A cherenkov counter named DIRC (Detection of Internally Reflected Cherenkov light), provides π/K separation for particle momenta up to 3.5 GeV/c. The barrel Time-of-Flight (TOF) detector, consists of plastic scintillator tiles with a time resolution of 100 ps. It is used to identify particles of momentum below cherenkov threshold

Implementation of a new data acquisition and exclusive measurement of the reaction vector pp → ppπ+π- at the time of flight spectrometer COSY-TOF

International Nuclear Information System (INIS)

Erhardt, Arthur

2009-01-01

The two-pion production pp ppπ + π - was measured exclusively at T p =793 MeV using the short version of the COSY-TOF spectrometer. In this measurement both the new EMS-based data acquisition system and a delayed pulse technique have been used, which, in addition to particle identification, energy, time of flight, and angle determination provides pi+ identification for pions in the theta lab range from 2 to 28 degrees. The measured total cross section for this reaction is σ=4.1(4) μb at T p =793 MeV. Due to an improved efficiency correction, the earlier measured total cross section has been corrected to σ=1.6 μb at T p =747 MeV. This value agrees nicely with the results from WASA/PROMICE. The data are compared to previous data and theoretical models which have been developed to understand the results from WASA/PROMICE measurements. The measurements have been carried out with transversally polarized proton beam which made it possible to determine analyzing powers for different subsystems of the two pion production reaction. In contrast to predictions we find significant analyzing power values up to A y =0.3. The data in the range of Roper excitation confirm that the dominating π π decay channel is N * →Nσ. (orig.)

Fission physics experiments at the time-of-flight spectrometer GNEIS in Gatchina (PNPI)

International Nuclear Information System (INIS)

Shcherbakov, O.A.

1994-01-01

The outline of and fission physics experiments at the Gatchina neutron spectrometer GNEIS based on the 1 GeV PNPI proton synchrotron are presented. The prefission gamma-ray spectrum of the (n, gamma f) reaction were investigated. The capture gamma-ray spectra for 721.6 eV and 1211.4 eV resonances in U-238 were measured and the nature of the 721.6 eV resonance in U-238 were examined. The forward-backward asymmetry in slow neutron fission of U-235 and energy dependence of the forward-backward and instrumental asymmetry coefficients were obtained. Fission cross section ratios for Th-232 to U-235 and for U-238 to U-235 in the energy range up to 200 MeV were measured. The results of the cross section ratios agreed well with those of Behrens et al. and Difilippo et al. (T.H.)

MONSTER: a TOF Spectrometer for beta-delayed Neutron Spetroscopy

CERN Document Server

Martinez, T; Castilla, J; Garcia, A R; Marin, J; Martinez, G; Mendoza, E; Santos, C; Tera, F; Jordan, M D; Rubio, B; Tain, J L; Bhattacharya, C; Banerjee, K; Bhattacharya, S; Roy, P; Meena, J K; Kundu, S; Mukherjee, G; Ghosh, T K; Rana, T K; Pandey, R; Saxena, A; Behera, B; Penttila, H; Jokinen, A; Rinta-Antila, S; Guerrero, C; Ovejero, M C; Villamarin, D; Agramunt, J; Algora, A

2014-01-01

Beta-delayed neutron (DN) data, including emission probabilities, P-n, and energy spectrum, play an important role in our understanding of nuclear structure, nuclear astrophysics and nuclear technologies. A MOdular Neutron time-of-flight SpectromeTER (MONSTER) is being built for the measurement of the neutron energy spectra and branching ratios. The TOF spectrometer will consist of one hundred liquid scintillator cells covering a significant solid angle. The MONSTER design has been optimized by using Monte Carlo (MC) techniques. The response function of the MONSTER cell has been characterized with mono-energetic neutron beams and compared to dedicated MC simulations.

Photoionization mass spectrometer for studies of flame chemistry with a synchrotron light source

International Nuclear Information System (INIS)

Cool, Terrill A.; McIlroy, Andrew; Qi, Fei; Westmoreland, Phillip R.; Poisson, Lionel; Peterka, Darcy S.; Ahmed, Musahid

2005-01-01

A flame-sampling molecular-beam photoionization mass spectrometer, recently designed and constructed for use with a synchrotron-radiation light source, provides significant improvements over previous molecular-beam mass spectrometers that have employed either electron-impact ionization or vacuum ultraviolet laser photoionization. These include superior signal-to-noise ratio, soft ionization, and photon energies easily and precisely tunable [E/ΔE(FWHM)≅250-400] over the 7.8-17-eV range required for quantitative measurements of the concentrations and isomeric compositions of flame species. Mass resolution of the time-of-flight mass spectrometer is m/Δm=400 and sensitivity reaches ppm levels. The design of the instrument and its advantages for studies of flame chemistry are discussed

Concept design of a time-of-flight spectrometer for the measurement of the energy of alpha particles.

Science.gov (United States)

García-Toraño, E

2018-04-01

The knowledge of the energies of the alpha particles emitted in the radioactive decay of a nuclide is a key factor in the construction of its decay scheme. Virtually all existing data are based on a few absolute measurements made by magnetic spectrometry (MS), to which most other MS measurements are traced. An alternative solution would be the use of time-of-flight detectors. This paper discusses the main aspects to be considered in the design of such detectors, and the performances that could be reasonably expected. Based on the concepts discussed here, it is estimated that an energy resolution about 2.5keV may be attainable with a good quality source. Copyright © 2017 Elsevier Ltd. All rights reserved.

The Harwell back-scattering spectrometer

International Nuclear Information System (INIS)

Windsor, C.G.; Bunce, L.J.; Borcherds, P.H.; Cole, I.; Fitzmaurice, M.; Johnson, D.A.G.; Sinclair, R.N.

1976-01-01

Neutron diffraction spectra in which both high resolution (Δ Q/Q approximately equal to 0.003) and high intensity are maintained up to scattering vectors as high as 30A -1 (sin theta/lambda = 2.5) have been obtained with the back-scattering spectrometer (BSS) recently installed on the Harwell electron linac. The theory behind the spectrometer design is described, and it is shown how the above resolution requirement leads to its basic features of a 12m incident flight path, a 2m scattering flight path and a scattering angle (2theta) acceptance from 165 0 to 175 0 . Examples of the resolution, intensity and background are given. It is shown that the problem of frame overlap may be overcome by using an absorbing filter. (author)

The TORCH time-of-flight detector

Energy Technology Data Exchange (ETDEWEB)

Harnew, N., E-mail: Neville.Harnew@physics.ox.ac.uk [University of Oxford, Denys Wilkinson Building, 1 Keble Road, Oxford OX1 3RH (United Kingdom); Brook, N. [University College London, Department of Physics & Astronomy, Gower Street, London WC1E 6BT (United Kingdom); Castillo García, L. [CERN, PH Department, CH-1211 Geneva 23 (Switzerland); Laboratory for High Energy Physics, Ecole Polytechnique Fédérale de Lausanne, CH-1015 Lausanne (Switzerland); Cussans, D. [H.H. Wills Physics Laboratory, University of Bristol, Bristol BS8 1TL (United Kingdom); Föhl, K.; Forty, R.; Frei, C. [CERN, PH Department, CH-1211 Geneva 23 (Switzerland); Gao, R. [University of Oxford, Denys Wilkinson Building, 1 Keble Road, Oxford OX1 3RH (United Kingdom); Gys, T.; Piedigrossi, D. [CERN, PH Department, CH-1211 Geneva 23 (Switzerland); Rademacker, J.; Ros Garcia, A.; Dijk, M. van [H.H. Wills Physics Laboratory, University of Bristol, Bristol BS8 1TL (United Kingdom)

2016-07-11

The TORCH time-of-flight detector is being developed to provide particle identification between 2 and 10 GeV/c momentum over a flight distance of 10 m. TORCH is designed for large-area coverage, up to 30 m{sup 2}, and has a DIRC-like construction. The goal is to achieve a 15 ps time-of-flight resolution per incident particle by combining arrival times from multiple Cherenkov photons produced within quartz radiator plates of 10 mm thickness. A four-year R&D programme is underway with an industrial partner (Photek, UK) to produce 53×53 mm{sup 2} Micro-Channel Plate (MCP) detectors for the TORCH application. The MCP-PMT will provide a timing accuracy of 40 ps per photon and it will have a lifetime of up to at least 5 Ccm{sup −2} of integrated anode charge by utilizing an Atomic Layer Deposition (ALD) coating. The MCP will be read out using charge division with customised electronics incorporating the NINO chipset. Laboratory results on prototype MCPs are presented. The construction of a prototype TORCH module and its simulated performance are also described.

Magnetic spectrometer of the DEUTERON-2 set-up

International Nuclear Information System (INIS)

Ajvazyan, R.V.; Alanakyan, K.V.; Amaryan, M.J.

1989-01-01

A magnetic spectrometer of the two-arm DEUTERON-2 set-up of the Erevan Physical Institute is described. It is shown that the rejection factor for electrons and pions is 10 -2 - 10 -3 . The positively charged particles in the momentum range up to 1.5 GeV/c are identified by momentum and time-of-flight measurements. The main characteristics of the spectrometer are: momentum and angular acceptance δp/p = 46%, Δθ = 4 deg, solid angle ΔΩ = 2.75 msr, momentum resolution δp/p = 1.5%, angular resolutions δθ = 0.6 deg, δφ = 2 deg. The intervals of measured momentum and the polar scattering anlge are 0.5-3 GeV/c and 10-30 deg, 68-90 deg respectively. 7 refs.; 11 figs

Simulations of chopper jitter at the LET neutron spectrometer at the ISIS TS2

DEFF Research Database (Denmark)

Klenø, Kaspar Hewitt; Lefmann, Kim; Willendrup, Peter Kjær

2014-01-01

The effect of uncertainty in chopper phasing (jitter) has been investigated for the high-resolution time-of-flight spectrometer LET at the ISIS second target station. The investigation is carried out using virtual experiments, with the neutron simulation package McStas, where the chopper jitter i...

Integrated intensities in inverse time-of-flight technique

International Nuclear Information System (INIS)

Dorner, Bruno

2006-01-01

In traditional data analysis a model function, convoluted with the resolution, is fitted to the measured data. In case that integrated intensities of signals are of main interest, one can use an approach which does not require a model function for the signal nor detailed knowledge of the resolution. For inverse TOF technique, this approach consists of two steps: (i) Normalisation of the measured spectrum with the help of a monitor, with 1/k sensitivity, which is positioned in front of the sample. This means at the same time a conversion of the data from time of flight to energy transfer. (ii) A Jacobian [I. Waller, P.O. Froeman, Ark. Phys. 4 (1952) 183] transforms data collected at constant scattering angle into data as if measured at constant momentum transfer Q. This Jacobian works correctly for signals which have a constant width at different Q along the trajectory of constant scattering angle. The approach has been tested on spectra of Compton scattering with neutrons, having epithermal energies, obtained on the inverse TOF spectrometer VESUVIO/ISIS. In this case the width of the signal is increasing proportional to Q and in consequence the application of the Jacobian leads to integrated intensities slightly too high. The resulting integrated intensities agree very well with results derived in the traditional way. Thus this completely different approach confirms the observation that signals from recoil by H-atoms at large momentum transfers are weaker than expected

A neutron spectrometer for studying giant resonances with (p,n) reactions in inverse kinematics

International Nuclear Information System (INIS)

Stuhl, L.; Krasznahorkay, A.; Csatlós, M.; Algora, A.; Gulyás, J.; Kalinka, G.; Timár, J.; Kalantar-Nayestanaki, N.; Rigollet, C.; Bagchi, S.; Najafi, M.A.

2014-01-01

A neutron spectrometer, the European Low-Energy Neutron Spectrometer (ELENS), has been constructed to study exotic nuclei in inverse-kinematics experiments. The spectrometer, which consists of plastic scintillator bars, can be operated in the neutron energy range of 100 keV–10 MeV. The neutron energy is determined using the time-of-flight technique, while the position of the neutron detection is deduced from the time-difference information from photomultipliers attached to both ends of each bar. A novel wrapping method has been developed for the plastic scintillators. The array has a larger than 25% detection efficiency for neutrons of approximately 500 keV in kinetic energy and an angular resolution of less than 1°. Details of the design, construction and experimental tests of the spectrometer will be presented

Users guide to the HELIOS backscattering spectrometer (BSS)

International Nuclear Information System (INIS)

Bunce, L.J.

1986-10-01

The BSS is a backscattering spectrometer installed on the Harwell 136 Mev electron linear accelerator, HELIOS. A general description of the instrument is given, along with the time of flight scales, and the run and sample changer control units. The sample environment, vacuum system and detectors of the BSS are described, as well as the preparation, starting and running of an experiment using the BSS. (UK)

Analytical properties of time-of-flight PET data

Energy Technology Data Exchange (ETDEWEB)

Cho, Sanghee; Ahn, Sangtae; Quanzheng, Li; Leahy, Richard M [Signal and Image Processing Institute, University of Southern California, Los Angeles, CA 90089 (United States)], E-mail: leahy@sipi.usc.edu

2008-06-07

We investigate the analytical properties of time-of-flight (TOF) positron emission tomography (PET) sinograms, where the data are modeled as line integrals weighted by a spatially invariant TOF kernel. First, we investigate the Fourier transform properties of 2D TOF data and extend the 'bow-tie' property of the 2D Radon transform to the time-of-flight case. Second, we describe a new exact Fourier rebinning method, TOF-FOREX, based on the Fourier transform in the time-of-flight variable. We then combine TOF-FOREX rebinning with a direct extension of the projection slice theorem to TOF data, to perform fast 3D TOF PET image reconstruction. Finally, we illustrate these properties using simulated data.

Analytical properties of time-of-flight PET data

Science.gov (United States)

Cho, Sanghee; Ahn, Sangtae; Li, Quanzheng; Leahy, Richard M.

2008-06-01

We investigate the analytical properties of time-of-flight (TOF) positron emission tomography (PET) sinograms, where the data are modeled as line integrals weighted by a spatially invariant TOF kernel. First, we investigate the Fourier transform properties of 2D TOF data and extend the 'bow-tie' property of the 2D Radon transform to the time-of-flight case. Second, we describe a new exact Fourier rebinning method, TOF-FOREX, based on the Fourier transform in the time-of-flight variable. We then combine TOF-FOREX rebinning with a direct extension of the projection slice theorem to TOF data, to perform fast 3D TOF PET image reconstruction. Finally, we illustrate these properties using simulated data.

Analytical properties of time-of-flight PET data

International Nuclear Information System (INIS)

Cho, Sanghee; Ahn, Sangtae; Li Quanzheng; Leahy, Richard M

2008-01-01

We investigate the analytical properties of time-of-flight (TOF) positron emission tomography (PET) sinograms, where the data are modeled as line integrals weighted by a spatially invariant TOF kernel. First, we investigate the Fourier transform properties of 2D TOF data and extend the 'bow-tie' property of the 2D Radon transform to the time-of-flight case. Second, we describe a new exact Fourier rebinning method, TOF-FOREX, based on the Fourier transform in the time-of-flight variable. We then combine TOF-FOREX rebinning with a direct extension of the projection slice theorem to TOF data, to perform fast 3D TOF PET image reconstruction. Finally, we illustrate these properties using simulated data

Analytical properties of time-of-flight PET data

Energy Technology Data Exchange (ETDEWEB)

Cho, Sanghee; Ahn, Sangtae; Li Quanzheng; Leahy, Richard M [Signal and Image Processing Institute, University of Southern California, Los Angeles, CA 90089 (United States)], E-mail: leahy@sipi.usc.edu

2008-06-07

We investigate the analytical properties of time-of-flight (TOF) positron emission tomography (PET) sinograms, where the data are modeled as line integrals weighted by a spatially invariant TOF kernel. First, we investigate the Fourier transform properties of 2D TOF data and extend the 'bow-tie' property of the 2D Radon transform to the time-of-flight case. Second, we describe a new exact Fourier rebinning method, TOF-FOREX, based on the Fourier transform in the time-of-flight variable. We then combine TOF-FOREX rebinning with a direct extension of the projection slice theorem to TOF data, to perform fast 3D TOF PET image reconstruction. Finally, we illustrate these properties using simulated data.

Timing properties of a time-of-flight detector

International Nuclear Information System (INIS)

Nakagawa, Takahide; Yuasa-Nakagawa, Keiko.

1989-01-01

The time resolution of a time-of-flight (T.O.F.) detector which consists of a channel plate detector (CPD) with a central hole and a surface barrier detector (SBD) was measured. A time resolution of 80 psec fwhm was obtained for 8.78 MeV alpha particles. The influence on fast timing of the SBD of alpha particles was carefully studied. The plasma delay time and time resolution of the SBD were found to strongly depend on the electric field strength and properties of the SBD. (author)

Contribution to the study of 14 MeV neutron scattering by {sup 12}C using a time-of-flight spectrometer (1963); Contribution a l'etude de la diffusion des neutrons de 14 MeV par {sup 12}C, a l'aide d'un spectrometre a temps de vol (1963)

Energy Technology Data Exchange (ETDEWEB)

Perrin, P [Commisariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

1963-07-15

Experimental measurements of 14 MeV fast neutrons scattering by {sup 12}C by time-flight spectrometer, with a 1.7 n. sec over-all resolution. The excitation of the 7.65 MeV level is observed. (author) [French] Etude experimentate de la diffusion par {sup 12}C des neutrons rapides de 14 MeV a l'aide d'un spectrometre de resolution totale de 17 n/s. Observation de l'excitation du niveau 0+ de 7,65 MeV. (auteur)

Emission and chemistry of organic compounds from biomass burning: measurements from an iodide time-of-flight chemical ionization mass spectrometer (I- ToF-CIMS) during the FIREX FireLab 2016 intensive

Science.gov (United States)

Yuan, B.; Krechmer, J. E.; Warneke, C.; Coggon, M.; Koss, A.; Lim, C. Y.; Selimovic, V.; Gilman, J.; Lerner, B. M.; Stark, H.; Kang, H.; Jimenez, J. L.; Yokelson, R. J.; Liggio, J.; Roberts, J. M.; Kroll, J. H.; De Gouw, J. A.

2017-12-01

Biomass burning can emit large amounts of many different organic compounds to the atmosphere. The emission strengths of these emitted organic compounds and their subsequent atmospheric chemistry are not well known. In this study, we deployed a time-of-flight chemical ionization mass spectrometer using iodide as reagent ions (Iodide ToF-CIMS) to measure direct emissions of organic compounds during the FIREX laboratory 2016 intensive in the USDA Fire Sciences Lab in Missoula, MT. An interpretation of the I­- TOF-CIMS mass spectra from biomass burning emissions will be presented. The dependence of the emissions of selected organic compounds with fuel types, combustion efficiency and fuel chemical compositions will be discussed. The I- TOF-CIMS also measured aged biomass burning smoke from a small smog chamber and an oxidative flow reactor (OFR). The I- TOF-CIMS consistently observed much higher signals of highly oxygenated organic compounds in the aged biomass burning smoke than in fresh emissions, indicative of strong secondary formation of these organic compounds in biomass burning plumes.

Energy and angle resolved studies of double photo-ionisation of helium by electron time-of-flight coincidence spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Viefhaus, J.; Avaldi, L.; Heiser, F.; Hentges, R.; Gessner, O.; Ruedel, A.; Wiedenhoeft, M.; Wieliczek, K.; Becker, U. [Fritz-Haber-Institut der Max-Planck-Gesellschaft, Berlin (Germany)

1996-10-28

Helium double photo-ionization is studied by a novel coincidence technique which employs time-of-flight spectrometers. Using this technique it is possible to collect simultaneously all the electron pairs, with different energy sharing, emitted by the absorption of a single energetic incident photon. The measurements, in a configuration where the two electrons emerge at 180{sup o} relative angle, provide the more complete information on the contribution of the ungerade amplitude to the triple differential cross section and allow the establishment of a relative scale for the full coincidence angular distribution measured by other experiments at the same photon energies, but only for a few selected energy-sharing conditions. (author).

A new beam profile monitor and time of flight system for CologneAMS

Energy Technology Data Exchange (ETDEWEB)

Pascovici, G. [CologneAMS, University of Cologne (Germany); Dewald, A., E-mail: dewald@ikp.uni-koeln.de [CologneAMS, University of Cologne (Germany); Institute of Nuclear Physics, University of Cologne (Germany); Heinze, S., E-mail: heinze@ikp.uni-koeln.de [CologneAMS, University of Cologne (Germany); Fink, L.; Mueller-Gatermann, C.; Schiffer, M.; Feuerstein, C. [CologneAMS, University of Cologne (Germany); Pfeiffer, M.; Jolie, J.; Thiel, S.; Zell, K.O.; Arnopolina, O. [Institute of Nuclear Physics, University of Cologne (Germany); Blanckenburg, F. von [GFZ, German Research Centre for Geosciences, Potsdam (Germany)

2013-01-15

A complex beam detector consisting of a high-resolution beam profile monitor (BPM) and a time of flight (TOF) spectrometer with tracking capabilities was designed especially for the special needs of the Cologne center for accelerator mass spectrometry (CologneAMS). The beam detector assembly is designed to match the beam specifications of the 6 MV Tandetron AMS setup and its data acquisition system. It will have a reconfigurable structure, either as a fast TOF subsystem with a ca. 10 cm{sup 2} equivalent active area, or as a more complex BPM-TOF detector with beam tracking capabilities and a larger active area (16 cm{sup 2}). The purpose of this detector is to suppress background during spectrometry of heavy ions (U, Cm, Pu, Am etc.) and to suppress isobaric interferences such as {sup 36}S in {sup 36}Cl spectra.

High-effective position time spectrometer in actual measurements of low intensity region of electron spectra

International Nuclear Information System (INIS)

Babenkov, M.I.; Zhdanov, V.S.

2002-01-01

Magnetic position-time spectrometer was proposed in previous work, where not only electron coordinates in focal plane are measured by position sensitive detector (PSD) but places of their birth in beta source plane of a large area are fixed using another PSD, situated behind it, by quick effects, accompanying radioactive decay. PSD on the basis of macro-channel plates are used. It is succeeded in position-time spectrometer to combine beta sources of a large area with multichannel registration for a wide energy interval, that efficiency of measurements was two orders of magnitude increase d in comparison magnetic apparatus having PSD only in focal plane. Owing to two detectors' switching on coincidence the relation effect/background in increased minimum on two orders of magnitude in comparison with the same apparatus. At some complication of mathematical analysis it was obtained, that high characteristics of position-time spectrometer are kept during the use the magnetic field, providing double focusing. Owning to this focusing the gain the efficiency of measurements will make one more order of magnitude. Presented high-effective position-time spectrometer is supposed to use in the measurements of low-intensity region of electron spectra, which are important for development of fundamental physics. This is the first of all estimation of electron anti-neutrino mass by the form of beta spectrum of tritium in the region of boundary energy. Recently here there was problem of non physical negative values. This problem can be solved by using in measurement of different in principle high-effective spectrometers, which possess improved background properties. A position-time spectrometers belongs to these apparatus, which provides the best background conditions at very large effectiveness of the measurements of tritium beta spectrum in the region of boundary energy with acceptable high resolution. An important advantage of position-time spectrometer is the possibility of

The design and performance of a velocity map imaging spectrometer for the study of molecular photoionisation dynamics

Energy Technology Data Exchange (ETDEWEB)

Holland, D.M.P., E-mail: david.holland@stfc.ac.uk [Daresbury Laboratory, Daresbury, Warrington, Cheshire WA4 4AD (United Kingdom); Shaw, D.A. [Daresbury Laboratory, Daresbury, Warrington, Cheshire WA4 4AD (United Kingdom)

2012-12-10

Highlights: Black-Right-Pointing-Pointer Velocity map imaging spectrometer optimised for molecular photoionisation dynamics. Black-Right-Pointing-Pointer Kinetic energy distribution of O{sup +} fragments measured. Black-Right-Pointing-Pointer Effect of autoionisation on photoelectron vibrational populations studied. -- Abstract: The design, construction and performance of a velocity map imaging spectrometer for the study of molecular photoionisation dynamics is described. The spectrometer has been optimised for the efficient collection and detection of particles (electrons or positively charged ions) generated through the interaction of gas phase molecules with synchrotron radiation. A double Einzel lens, incorporated into the flight tube, enhances the collection efficiency of energetic particles. Computer modelling has been used to trace the trajectories of charged particles through the spectrometer and to assess the image quality. A time and position sensitive delay-line detector is used to record the images. Results from two experimental studies are presented to illustrate the capabilities of the spectrometer. In the first, the effect of electronic autoionisation on the vibrationally resolved photoelectron branching ratios of the N{sub 2}{sup +} X {sup 2}{Sigma}{sub g}{sup +} state has been investigated in an excitation range where prominent structure due to Rydberg states occurs in the ion yield curve. The results show that autoionisation leads to rotational branch populations that differ from those observed in direct, non-resonant, photoionisation. In the second, the kinetic energy distribution and the angular distribution of O{sup +} fragments formed in the dissociative photoionisation of molecular oxygen have been measured. The timing properties of the detector have allowed O{sup +} fragments to be separated from O{sub 2}{sup +} parent ions using time-of-flight techniques.

Rocket studies of solar corona and transition region. [X-Ray spectrometer/spectrograph telescope

Science.gov (United States)

Acton, L. W.; Bruner, E. C., Jr.; Brown, W. A.; Nobles, R. A.

1979-01-01

The XSST (X-Ray Spectrometer/Spectrograph Telescope) rocket payload launched by a Nike Boosted Black Brant was designed to provide high spectral resolution coronal soft X-ray line information on a spectrographic plate, as well as time resolved photo-electric records of pre-selected lines and spectral regions. This spectral data is obtained from a 1 x 10 arc second solar region defined by the paraboloidal telescope of the XSST. The transition region camera provided full disc images in selected spectral intervals originating in lower temperature zones than the emitting regions accessible to the XSST. A H-alpha camera system allowed referencing the measurements to the chromospheric temperatures and altitudes. Payload flight and recovery information is provided along with X-ray photoelectric and UV flight data, transition camera results and a summary of the anomalies encountered. Instrument mechanical stability and spectrometer pointing direction are also examined.

Time-of-flight experiments using a pseudo-statistical chopper

International Nuclear Information System (INIS)

Aizawa, Otohiko; Kanda, Keiji

1975-01-01

A ''pseudo-statistical'' chopper was manufactured and used for the experiments on neutron transmission and scattering. The characteristics of the chopper and the experimental results are discussed in comparison with those in the time-of-flight technique using a conventional chopper. Which of the two methods is superior depends on the form of the time-of-flight distribution to be measured. Pseudo-statistical pulsing may be especially advantageous for scattering experiments with single or a few-line time-of-flight spectrum. (auth.)

Detection of atmospheric gaseous amines and amides by a high-resolution time-of-flight chemical ionization mass spectrometer with protonated ethanol reagent ions

Directory of Open Access Journals (Sweden)

L. Yao

2016-11-01

Full Text Available Amines and amides are important atmospheric organic-nitrogen compounds but high time resolution, highly sensitive, and simultaneous ambient measurements of these species are rather sparse. Here, we present the development of a high-resolution time-of-flight chemical ionization mass spectrometer (HR-ToF-CIMS method, utilizing protonated ethanol as reagent ions to simultaneously detect atmospheric gaseous amines (C1 to C6 and amides (C1 to C6. This method possesses sensitivities of 5.6–19.4 Hz pptv−1 for amines and 3.8–38.0 Hz pptv−1 for amides under total reagent ion signals of  ∼  0.32 MHz. Meanwhile, the detection limits were 0.10–0.50 pptv for amines and 0.29–1.95 pptv for amides at 3σ of the background signal for a 1 min integration time. Controlled characterization in the laboratory indicates that relative humidity has significant influences on the detection of amines and amides, whereas the presence of organics has no obvious effects. Ambient measurements of amines and amides utilizing this method were conducted from 25 July to 25 August 2015 in urban Shanghai, China. While the concentrations of amines ranged from a few parts per trillion by volume to hundreds of parts per trillion by volume, concentrations of amides varied from tens of parts per trillion by volume to a few parts per billion by volume. Among the C1- to C6-amines, the C2-amines were the dominant species with concentrations up to 130 pptv. For amides, the C3-amides (up to 8.7 ppb were the most abundant species. The diurnal and backward trajectory analysis profiles of amides suggest that in addition to the secondary formation of amides in the atmosphere, industrial emissions could be important sources of amides in urban Shanghai. During the campaign, photo-oxidation of amines and amides might be a main loss pathway for them in daytime, and wet deposition was also an important sink.

Current instrument status of the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS)

Science.gov (United States)

Eastwood, Michael L.; Sarture, Charles M.; Chrien, Thomas G.; Green, Robert O.; Porter, Wallace M.

1991-01-01

An upgraded version of AVIRIS, an airborne imaging spectrometer based on a whiskbroom-type scanner coupled via optical fibers to four dispersive spectrometers, that has been in operation since 1987 is described. Emphasis is placed on specific AVIRIS subsystems including foreoptics, fiber optics, and an in-flight reference source; spectrometers and detector dewars; a scan drive mechanism; a signal chain; digital electronics; a tape recorder; calibration systems; and ground support requirements.

First records of thermal neutrons with the spectrometer for time of flight (TOF) in the RP-10 Nuclear Reactor

International Nuclear Information System (INIS)

Munive, M.; Baltuano, O; Soto, C; Ravello, Y

2002-01-01

To obtain the first spectrum of an emergent beam of neutrons of a nuclear reactor is the main parameter of the characterization in the use of this reactor; one of ways to get this spectrum is for the technique of time of flight, TOF, which registers the time that a neutron need to cover a certain distance, associating this time then to the kinetic energy of the neutron. The kinetic study of the beam of neutrons is carried out on neutron pulses that are generated by a revolving choke called Chopper; and the analysis in the time of the detected pulses is carried out for a system MCS. Using this technique it is achieved the record of the spectra in energy, or in wavelength , of the irradiation facilities No 2 and 4, and of the exit N o 5 of the thermal column of the Nuclear Reactor RP-10 of the Nuclear Center Oscar de la Guerra RACSO, Peru (au)

Analysis of Marine Aerosol Polysaccharides by Pyrolysis Time-of-Flight Mass Spectrometry

Science.gov (United States)

Lawler, M. J.; Grieman, M. M.; Sengur, I.; Saltzman, E. S.

2017-12-01

The relationship between surface ocean biological productivity and marine cloud formation and properties has been explored for decades, but the impacts of marine biogenic emissions on cloudiness and climate remain highly uncertain. This is in part due to the challenge of directly linking biogenic materials in the surface ocean with cloud-forming aerosol. It has been shown that polysaccharide gel-forming materials, also known as transparent exopolymers, may be mechanically ejected from the sea surface during air bubble bursting (Leck and Bigg, 2005). Existing analysis methods for such aerosols require considerable sample mass and sample preparation. As part of the multi-year seasonal North Atlantic Aerosols and Marine Ecosystems Study (NAAMES), ambient submicron marine aerosol was collected in November 2015 and May 2016 from the R/V Atlantis at using a Particle into Liquid Sampler (PILS). These samples of roughly 15 minute time resolution were frozen and returned to UC Irvine for analysis. A new technique has been developed to attempt to quantify polysaccharide material in these ambient samples. A small subsample (1- 5 µL) is taken from the PILS vial samples and allowed to dry on a Pt ribbon filament in the chemical ionization source region of a time-of-flight mass spectrometer. The sample then undergoes a two-step heating process, in which volatilizable molecules are first desorbed and then non-volatilizable large molecules such as polysaccharides are pyrolyzed. These desorbed molecules and decomposition products are ionized using either O2- or H3O+ reagent ion and are directly sampled into the mass spectrometer. The resulting spectra can then be compared to standards of known polysaccharide materials for quantification and potentially structural and/or compositional information.

Design and Test of Portable Hyperspectral Imaging Spectrometer

Directory of Open Access Journals (Sweden)

Chunbo Zou

2017-01-01

Full Text Available We design and implement a portable hyperspectral imaging spectrometer, which has high spectral resolution, high spatial resolution, small volume, and low weight. The flight test has been conducted, and the hyperspectral images are acquired successfully. To achieve high performance, small volume, and regular appearance, an improved Dyson structure is designed and used in the hyperspectral imaging spectrometer. The hyperspectral imaging spectrometer is suitable for the small platform such as CubeSat and UAV (unmanned aerial vehicle, and it is also convenient to use for hyperspectral imaging acquiring in the laboratory and the field.

On the design of the NIF Continuum Spectrometer

Science.gov (United States)

Thorn, D. B.; MacPhee, A.; Ayers, J.; Galbraith, J.; Hardy, C. M.; Izumi, N.; Bradley, D. K.; Pickworth, L. A.; Bachmann, B.; Kozioziemski, B.; Landen, O.; Clark, D.; Schneider, M. B.; Hill, K. W.; Bitter, M.; Nagel, S.; Bell, P. M.; Person, S.; Khater, H. Y.; Smith, C.; Kilkenny, J.

2017-08-01

In inertial confinement fusion (ICF) experiments on the National Ignition Facility (NIF), measurements of average ion temperature using DT neutron time of flight broadening and of DD neutrons do not show the same apparent temperature. Some of this may be due to time and space dependent temperature profiles in the imploding capsule which are not taken into account in the analysis. As such, we are attempting to measure the electron temperature by recording the free-free electron-ion scattering-spectrum from the tail of the Maxwellian temperature distribution. This will be accomplished with the new NIF Continuum Spectrometer (ConSpec) which spans the x-ray range of 20 keV to 30 keV (where any opacity corrections from the remaining mass of the ablator shell are negligible) and will be sensitive to temperatures between ˜ 3 keV and 6 keV. The optical design of the ConSpec is designed to be adaptable to an x-ray streak camera to record time resolved free-free electron continuum spectra for direct measurement of the dT/dt evolution across the burn width of a DT plasma. The spectrometer is a conically bent Bragg crystal in a focusing geometry that allows for the dispersion plane to be perpendicular to the spectrometer axis. Additionally, to address the spatial temperature dependence, both time integrated and time resolved pinhole and penumbral imaging will be provided along the same polar angle. The optical and mechanical design of the instrument is presented along with estimates for the dispersion, solid angle, photometric sensitivity, and performance.

The feasibility of using a Fourier RTOF spectrometer at a low-power research reactor

International Nuclear Information System (INIS)

Maayouf, R.M.A.; Priesmeyer, H.G.; Kudryashev, V.A.

1991-01-01

The present situation of Fourier time-of-flight (TOF) spectrometry is discussed using the FSS spectrometer as example. The use of the Fourier reverse TOF spectrometry, as an efficient tool for studying condensed matter, at a 2 MW (WWR-S type) reactor is also assessed. The arrangement of the RTOF spectrometer, which could be successfully used at such type of reactor, is introduced. The suggested arrangement applies a neutron guide tube of 24 m length and allows for effective luminosity 2.4.10 6 at a flight path distance of 3.6 m. The number of neutrons scattered from a sample (5 cm 3 in volume) and incident on the detector system, as estimated for the suggested arrangement, is ∝1.6.10 3 n/sec. Such high counting rate allows to measure a diffraction spectrum within less than an hour. (orig.) With 12 figs [de

Simple flight time calibration generator in PLL technique

International Nuclear Information System (INIS)

Lauch, J.

1975-01-01

Calibration and routine check-ups of flight time measuring systems can be carried out with the aid of defined flight time calibration spectra. This paper describes a simple flight time calibration generator capable of generating such calibration spectra in the form of line spectra or of a white spectrum. The flight time of the generator is adjustable in steps from 100 to 3,200 ns. The number of calibration lines can be set to 10 or to 20, resulting in line spacings ranging from 5 to 320 ns. The stop signals are generated by a crystal oscillator, the start signals are generated by a voltage-controlled oscillator locked in a phase control circuit. The start and stop rates can be adjusted in steps. (orig.) [de

Implement of a magnetic spectrometer at the CERN intersecting stockage rings (900 spectrometer in the R608 experiment)

International Nuclear Information System (INIS)

Reyrolle, M.

1985-01-01

By adding a new spectrometer at 90 0 in the R608 experiment at CERN (ISR) we can search correlations between some systems of particles fully measured in the forward and transverse directions. The corresponding new electronic trigger, which selects events with momentum above a chosen threshold, is mixed or not to the forward trigger, in order to record correlated or inclusive data from the collisions p-p, p-anti-p, α-α. In the 90 0 spectrometer, we build drift chambers, set before the dipolar magnet. We studied the spatial resolution and the methods to associate tracks before and after this magnet. We developed the method to determine the momenta, by taking account of the variations of the deflecting power: the accuracy of this method is better than O.3%, and the global resolution is about 0.01 P 2 . We proposed also how to identify the particles from time of flight measurements and aerogel cerenkov counters [fr

Study and realization of a parallel plate avalanche counter used for time of flight and localization measurements

International Nuclear Information System (INIS)

Pellegrin, P.O.

1985-01-01

A parallel Plates Avalanche Counter (P.P.A.C.) allowing high resolution training and localization is studied. It is designed to be placed on the beam trajectory-including the magnetic spectrometer of SARA accelerator at ISN Grenoble. Two purposes are searched: firstly to improve the time-of-flight measurement due to the very high intrinsic time resolution (it can be less than 150 ps), secondly to measure with accuracy the scattering angle of the particle on the target, due to its localization. The detector thickness has been reduced to set aside as unimportant the disturbance produced on the particle trajectory. The theoretical aspect of the detector operation and a quantitative study of the disturbances it causes on particle energy are presented. The set-up and its necessary surroundings are described with experimental results of its characteristics [fr

Programmable ion mobility spectrometer: Time resolution improvement and ion counter comparison

International Nuclear Information System (INIS)

Harrison, R.G.; Wilding, R.J.

2005-01-01

Atmospheric ion mobility spectrometers operating on the aspirated electrode principle require switching of a bias voltage to select ions of different mobility. The ion spectrum can be obtained by sweeping across a set of bias voltages. If rapid temporal changes in atmospheric ion spectra are to be measured, however, such as for a balloon-carried instrument, the sweep time across the ion spectrum must be kept short. As bias voltage steps can generate saturation in the mobility spectrometer's electrometer amplifier, the electrometer recovery time limits the ion mobility spectrum sweep rate. Here, active compensation of the charge injected at a bias voltage step is used to reduce the saturation time. Further, the optimal setting of the charge compensation circuitry provides a determination of the system capacitance, a necessary calibration parameter for absolute measurements. Using laboratory air, hourly variations in ion concentrations and air conductivity found using the voltage switching system were similar to those obtained with a traditional ion counter operating at a single mobility: ion growth, however, could only be detected using the ion spectrometer

Effect of the size of experimental channels of the lead slowing-down spectrometer SVZ-100 (Institute for Nuclear Research, Moscow) on the moderation constant

Energy Technology Data Exchange (ETDEWEB)

Latysheva, L. N.; Bergman, A. A.; Sobolevsky, N. M., E-mail: sobolevs@inr.ru [Russian Academy of Sciences, Institute for Nuclear Research (Russian Federation); Ilic, R. D. [Vinca Institute of Nuclear Sciences (Serbia)

2013-04-15

Lead slowing-down (LSD) spectrometers have a low energy resolution (about 30%), but their luminosity is 10{sup 3} to 10{sup 4} times higher than that of time-of-flight (TOF) spectrometers. A high luminosity of LSD spectrometers makes it possible to use them to measure neutron cross section for samples of mass about several micrograms. These features specify a niche for the application of LSD spectrometers in measuring neutron cross sections for elements hardly available in macroscopic amounts-in particular, for actinides. A mathematical simulation of the parameters of SVZ-100 LSD spectrometer of the Institute for Nuclear Research (INR, Moscow) is performed in the present study on the basis of the MCNPX code. It is found that the moderation constant, which is the main parameter of LSD spectrometers, is highly sensitive to the size and shape of detecting volumes in calculations and, hence, to the real size of experimental channels of the LSD spectrometer.

Effect of the size of experimental channels of the lead slowing-down spectrometer SVZ-100 (Institute for Nuclear Research, Moscow) on the moderation constant

International Nuclear Information System (INIS)

Latysheva, L. N.; Bergman, A. A.; Sobolevsky, N. M.; Ilić, R. D.

2013-01-01

Lead slowing-down (LSD) spectrometers have a low energy resolution (about 30%), but their luminosity is 10 3 to 10 4 times higher than that of time-of-flight (TOF) spectrometers. A high luminosity of LSD spectrometers makes it possible to use them to measure neutron cross section for samples of mass about several micrograms. These features specify a niche for the application of LSD spectrometers in measuring neutron cross sections for elements hardly available in macroscopic amounts—in particular, for actinides. A mathematical simulation of the parameters of SVZ-100 LSD spectrometer of the Institute for Nuclear Research (INR, Moscow) is performed in the present study on the basis of the MCNPX code. It is found that the moderation constant, which is the main parameter of LSD spectrometers, is highly sensitive to the size and shape of detecting volumes in calculations and, hence, to the real size of experimental channels of the LSD spectrometer.

Flight-time spread of uniform field sector magnet system for use in nuclear life-time measurements

International Nuclear Information System (INIS)

Sakata, Akihiko; Mamei, Masayuki; Yamada, Yoshihiro; Ohira, Kyozo

1984-01-01

A nuclear life-time measurement apparatus incorporating a deflecting β-ray spectrometer with electron pre-accelerator has been constructed. A new arrangement consisting of two double angular focusing sector magnets based on the principle of symmetry has been devised so as to reduce the time spread in the spectrometer, which up till now has been the weak point of such systems. The time spread in the spectrometer was estimated to be asymptotically equals 0.1 ns by a simulation method, and good agreement was obtained between this estimated value and the experimental value. A prompt time resolution of 1.25 ns (FWHM) was obtained. The half-lives of the 199 and 401 keV levels in 75 As were measured with an acceleration voltage up to 30 kV to check the reliability of the apparatus. The values were found to be 0.87+-0.04 ns and 1.74+-0.05 ns, respectively, in good agreement with previous measurements. (author)

Time-frequency energy density precipitation method for time-of-flight extraction of narrowband Lamb wave detection signals

Energy Technology Data Exchange (ETDEWEB)

Zhang, Y., E-mail: thuzhangyu@foxmail.com; Huang, S. L., E-mail: huangsling@tsinghua.edu.cn; Wang, S.; Zhao, W. [State Key Laboratory of Power Systems, Department of Electrical Engineering, Tsinghua University, Beijing 100084 (China)

2016-05-15

The time-of-flight of the Lamb wave provides an important basis for defect evaluation in metal plates and is the input signal for Lamb wave tomographic imaging. However, the time-of-flight can be difficult to acquire because of the Lamb wave dispersion characteristics. This work proposes a time-frequency energy density precipitation method to accurately extract the time-of-flight of narrowband Lamb wave detection signals in metal plates. In the proposed method, a discrete short-time Fourier transform is performed on the narrowband Lamb wave detection signals to obtain the corresponding discrete time-frequency energy density distribution. The energy density values at the center frequency for all discrete time points are then calculated by linear interpolation. Next, the time-domain energy density curve focused on that center frequency is precipitated by least squares fitting of the calculated energy density values. Finally, the peak times of the energy density curve obtained relative to the initial pulse signal are extracted as the time-of-flight for the narrowband Lamb wave detection signals. An experimental platform is established for time-of-flight extraction of narrowband Lamb wave detection signals, and sensitivity analysis of the proposed time-frequency energy density precipitation method is performed in terms of propagation distance, dispersion characteristics, center frequency, and plate thickness. For comparison, the widely used Hilbert–Huang transform method is also implemented for time-of-flight extraction. The results show that the time-frequency energy density precipitation method can accurately extract the time-of-flight with relative error of <1% and thus can act as a universal time-of-flight extraction method for narrowband Lamb wave detection signals.

Time-frequency energy density precipitation method for time-of-flight extraction of narrowband Lamb wave detection signals

International Nuclear Information System (INIS)

Zhang, Y.; Huang, S. L.; Wang, S.; Zhao, W.

2016-01-01

The time-of-flight of the Lamb wave provides an important basis for defect evaluation in metal plates and is the input signal for Lamb wave tomographic imaging. However, the time-of-flight can be difficult to acquire because of the Lamb wave dispersion characteristics. This work proposes a time-frequency energy density precipitation method to accurately extract the time-of-flight of narrowband Lamb wave detection signals in metal plates. In the proposed method, a discrete short-time Fourier transform is performed on the narrowband Lamb wave detection signals to obtain the corresponding discrete time-frequency energy density distribution. The energy density values at the center frequency for all discrete time points are then calculated by linear interpolation. Next, the time-domain energy density curve focused on that center frequency is precipitated by least squares fitting of the calculated energy density values. Finally, the peak times of the energy density curve obtained relative to the initial pulse signal are extracted as the time-of-flight for the narrowband Lamb wave detection signals. An experimental platform is established for time-of-flight extraction of narrowband Lamb wave detection signals, and sensitivity analysis of the proposed time-frequency energy density precipitation method is performed in terms of propagation distance, dispersion characteristics, center frequency, and plate thickness. For comparison, the widely used Hilbert–Huang transform method is also implemented for time-of-flight extraction. The results show that the time-frequency energy density precipitation method can accurately extract the time-of-flight with relative error of <1% and thus can act as a universal time-of-flight extraction method for narrowband Lamb wave detection signals.

Characterization of a Carbon Nanotube Field Emission Electron Gun for the VAPoR Miniaturized Pyrolysis-Time-of-Flight Mass Spectrometer

Science.gov (United States)

Getty, Stephanie; Li, Mary; Costen, Nicholas; Hess, Larry; Feng, Steve; King, Todd; Brinckerhoff, William; Mahaffy, Paul; Glavin, Daniel

2009-01-01

We are developing the VAPoR (Volatile Analysis by Pyrolysis of Regolith) instrument towards studying soil composition, volatiles, and trapped noble gases in the polar regions of the Moon. VAPOR will ingest a soil sample and conduct analysis by pyrolysis and time-of-flight mass spectrometry (ToF-MS). Here, we describe miniaturization efforts within this development, including a carbon nanotube (CNT) field emission electron gun that is under consideration for use as the electron impact ionization source for the ToF-MS.

Calibration of scintillation-light filters for neutron time-of-flight spectrometers at the National Ignition Facility

Energy Technology Data Exchange (ETDEWEB)

Sayre, D. B., E-mail: sayre4@llnl.gov; Barbosa, F.; Caggiano, J. A.; Eckart, M. J.; Grim, G. P.; Hartouni, E. P.; Hatarik, R. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); DiPuccio, V. N.; Weber, F. A. [National Security Technologies, Livermore, California 94551 (United States)

2016-11-15

Sixty-four neutral density filters constructed of metal plates with 88 apertures of varying diameter have been radiographed with a soft x-ray source and CCD camera at National Security Technologies, Livermore. An analysis of the radiographs fits the radial dependence of the apertures’ image intensities to sigmoid functions, which can describe the rapidly decreasing intensity towards the apertures’ edges. The fitted image intensities determine the relative attenuation value of each filter. Absolute attenuation values of several imaged filters, measured in situ during calibration experiments, normalize the relative quantities which are now used in analyses of neutron spectrometer data at the National Ignition Facility.

Time domain optical spectrometry with fiber optic waveguides

International Nuclear Information System (INIS)

Whitten, W.B.

1983-01-01

Spectrometers which use optical fibers to obtain time domain spectral dispersion are reviewed. Pulse transmission through fiber optic waveguides is discussed and the basic requirements for sources and detectors are given. Multiplex spectrometry and time-of-flight spectrometry are then discussed. Resolution, fiber requirements, instrumentation and specific spectrometers are presented

Structural calculations and experimental detection of small Ga mS n clusters using time-of-flight mass spectrometry

Science.gov (United States)

BelBruno, J. J.; Sanville, E.; Burnin, A.; Muhangi, A. K.; Malyutin, A.

2009-08-01

Ga mS n clusters were generated by laser ablation of a solid sample of Ga 2S 3. The resulting molecules were analyzed in a time-of-flight mass spectrometer. In addition to atomic species, the spectra exhibited evidence for the existence of GaS3+, GaS4+, GaS5+, and GaS6+ clusters. The potential neutral and cationic structures of the observed Ga mS n clusters were computationally investigated using a density-functional approach. Reference is made to the kinetic pathways required for production of clusters from the starting point of the stoichiometric molecule or molecular ion. Cluster atomization enthalpies are compared with bulk values from the literature.

Time-resolved photoemission micro-spectrometer using higher-order harmonics of Ti:sapphire laser

International Nuclear Information System (INIS)

Azuma, J.; Kamada, M.; Kondo, Y.

2004-01-01

Full text: A new photoemission spectrometer is under construction for the photoemission microscopy and the time-resolved pump- probe experiment. The higher order harmonics of the Ti:sapphire laser is used as the light source of the VUV region in this system. Because the fundamental laser is focused tightly into the rare gas jet to generate the higher order harmonics, the spot size of the laser, in other words, the spot size of the VUV light source is smaller than a few tens of micrometer. This smallness of the spot size has advantage for the microscopy. In order to compensate the low flux of the laser harmonics, a multilayer-coated schwaltzshild optics was designed. The multilayers play also as the monochromatic filter. The spatial resolution of this schwaltzshild system is found to be less than 1 micrometer by the ray-tracing calculations. A main chamber of the system is equipped with a time-of-flight energy analyzer to improve the efficiency of the electron detection. The main chamber and the gas chamber are separated by a differential pumping chamber and a thin Al foil. The system is designed for the study of the clean surface. It will be capable to perform the sub-micron photoemission microscopy and the femto-second pump-probe photoemission study for the various photo-excited dynamics on clean surfaces

In-flight spectral performance monitoring of the Airborne Prism Experiment

NARCIS (Netherlands)

Odorico, D' P.; Alberti, E.; Schaepman, M.E.

2010-01-01

Spectral performance of an airborne dispersive pushbroom imaging spectrometer cannot be assumed to be stable over a whole flight season given the environmental stresses present during flight. Spectral performance monitoring during flight is commonly accomplished by looking at selected absorption

The ARGUS time-of-flight system

International Nuclear Information System (INIS)

Heller, R.; Klinger, T.; Salomon, R.; Schubert, K.R.; Stiewe, J.; Waldi, R.; Weseler, S.

1985-01-01

The time-of-flight system of the ARGUS detector at the DORIS e + e - storage ring consists of 64 barrel scintillation counters covering 75% of 4π, and 2x48 end cap counters, covering 17% of 4π. The barrel counters are viewed by two phototubes each, while the end cap counters have one tube only. The time-of-flight system serves as a part of the fast trigger and identifies charged particles. The time resolution achieved during the first year of ARGUS operation is 210 ps for Bhabhas (which are used for the off-line monitoring of the system), and 220 ps for hadrons, both in barrel and end cap counters. This converts into a three standard deviation mass separation up to 700 MeV/c between pions and kaons and 1200 MeV/c between kaons and protons. Electrons can be separated from heavier particles up to 230 MeV/c. (orig.)

A new FPGA-based time-over-threshold system for the time of flight detectors at the BGO-OD experiment

Energy Technology Data Exchange (ETDEWEB)

Freyermuth, Oliver [Physikalisches Institut, Nussallee 12, D-53115 Bonn (Germany); Collaboration: BGO-OD-Collaboration

2015-07-01

The BGO-OD experiment at the ELSA accelerator facility at Bonn is built for the systematic investigation of meson photoproduction in the GeV region. It features the unique combination of a central, highly segmented BGO crystal calorimeter covering almost 4π in acceptance and a forward magnetic spectrometer complemented by time of flight walls. The readout of the ToF scintillator bars was upgraded to an FPGA-based VME-board equipped with discriminator mezzanines including per-channel remotely adjustable thresholds. A firmware was developed combining a time-over-threshold (ToT) measurement by implementing a dual-edge TDC, a configurable meantimer trigger logic including a special cosmics trigger, adjustable input delays and gateable scalers, all inside a single electronics module. An experimentally obtained relation between ToT and slope of a PMT signal can be used for a time walk correction to achieve time resolutions comparable to a classical chain of CFD and standard TDC. Additionally, the time-over-threshold information can be exploited for gain matching and allows to monitor online the gain-stability and check for electronics problems such as pulse reflections or baseline jitter. The system is well-suited for a wide range of PMT-based fast detectors with many channels and further applications foreseen.

Deployment of the FIGAERO Iodide Time of flight (ToF)-Chemical ionisation mass spectrometer (CIMS) using X-ray ionisation in Manaus

Science.gov (United States)

Bannan, T.; Bacak, A.; Priestley, M.; Adelstein, E.; Worrall, S.; Artaxo, P.; Carbone, S.; Topping, D. O.; Allan, J. D.; Coe, H.; Percival, C.

2017-12-01

Here the deployment of the The Filter Inlet for Gases and AEROsols (FIGAERO) coupled with the Aerodyne High Resolution (HR)-Time of flight (ToF)-Chemical ionisation mass spectrometer (CIMS) in Manaus is presented. This project utilised the Tofwerk X-ray ionisation source in the tropical rainforest in close proximity to Manaus, Brazil, at the ZF2 measurement site. The FIGAERO is a filter based technique that provides simultaneous molecular information of both the gas and particle phase. When analysing particles that have been collected the evolution of the MS signals from different compounds change independently as a function of temperature; creating a thermogram that is m/z specific. The temperature for which the desorbed signal shows a maximum for each compound has been used previously to extract vapour pressure information in laboratory characterisatio. Krieger et al. (2017) defined the homologous series of polyethylene glycols as a series of compounds that showed a very good agreement over a wide range of atmospherically relevant vapour pressures between different experimental setups. PEG samples therefore provide an ideal bench mark for characterising individual FIGAERO inlets to give vapour pressure information essential for partitioning characterisation. The PEG calibration curve has been used to validate vapour pressure measurements in a well-defined single component bases and in simple chamber experiments, results of which are presented. With a high reactivity and large ubiquitous global source, isoprene has a profound effect upon atmospheric chemistry and composition. Despite this there are still significant gaps in the understanding of the processes that lead to isoprene derived secondary organic aerosol (SOA). This project aims to provide insights into the role of isoprene in the mechanisms of production of SOA and its importance in the particulate mass budgets in the tropics and the fundamental chemical processes. The volatility and composition of

TOF plotter - a program to perform routine analysis time-of-flight mass spectral data

International Nuclear Information System (INIS)

Knippel, Brad C.; Padgett, Clifford W.; Marcus, R. Kenneth

2004-01-01

The main article discusses the operation and application of the program to mass spectral data files. This laboratory has recently reported the construction and characterization of a linear time-of-flight mass spectrometer (ToF-MS) utilizing a radio frequency glow discharge ionization source. Data acquisition and analysis was performed using a digital oscilloscope and Microsoft Excel, respectively. Presently, no software package is available that is specifically designed for time-of-flight mass spectral analysis that is not instrument dependent. While spreadsheet applications such as Excel offer tremendous utility, they can be cumbersome when repeatedly performing tasks which are too complex or too user intensive for macros to be viable. To address this situation and make data analysis a faster, simpler task, our laboratory has developed a Microsoft Windows-based software program coded in Microsoft Visual Basic. This program enables the user to rapidly perform routine data analysis tasks such as mass calibration, plotting and smoothing on x-y data sets. In addition to a suite of tools for data analysis, a number of calculators are built into the software to simplify routine calculations pertaining to linear ToF-MS. These include mass resolution, ion kinetic energy and single peak identification calculators. A detailed description of the software and its associated functions is presented followed by a characterization of its performance in the analysis of several representative ToF-MS spectra obtained from different GD-ToF-MS systems

Time-frequency energy density precipitation method for time-of-flight extraction of narrowband Lamb wave detection signals.

Science.gov (United States)

Zhang, Y; Huang, S L; Wang, S; Zhao, W

2016-05-01

The time-of-flight of the Lamb wave provides an important basis for defect evaluation in metal plates and is the input signal for Lamb wave tomographic imaging. However, the time-of-flight can be difficult to acquire because of the Lamb wave dispersion characteristics. This work proposes a time-frequency energy density precipitation method to accurately extract the time-of-flight of narrowband Lamb wave detection signals in metal plates. In the proposed method, a discrete short-time Fourier transform is performed on the narrowband Lamb wave detection signals to obtain the corresponding discrete time-frequency energy density distribution. The energy density values at the center frequency for all discrete time points are then calculated by linear interpolation. Next, the time-domain energy density curve focused on that center frequency is precipitated by least squares fitting of the calculated energy density values. Finally, the peak times of the energy density curve obtained relative to the initial pulse signal are extracted as the time-of-flight for the narrowband Lamb wave detection signals. An experimental platform is established for time-of-flight extraction of narrowband Lamb wave detection signals, and sensitivity analysis of the proposed time-frequency energy density precipitation method is performed in terms of propagation distance, dispersion characteristics, center frequency, and plate thickness. For comparison, the widely used Hilbert-Huang transform method is also implemented for time-of-flight extraction. The results show that the time-frequency energy density precipitation method can accurately extract the time-of-flight with relative error of wave detection signals.

Time-of-flight spectrometer for slow neutrons in use at the reactor in Saclay. Its application for the study of the inelastic diffusion of cold neutrons; L'appareillage de spectrometrie a temps-de-vol pour neutrons lents en service a la pile de Saclay. Son application a l'etude de la diffusion inelastique des neutrons froids

Energy Technology Data Exchange (ETDEWEB)

Jacsot, B; Netter, F [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires; Galula, M [Centre National de la Recherche Scientifique (CNRS), 91 - Gif-sur-Yvette (France)

1955-07-01

The time-of-flight spectrometers is constituted of a mechanic swivel obturator which absorbs neutrons until energies above 1 KeV, a mechanic filter which allow to retain only high wave length components and a delayed pulses selector with 100 channels. Its main application field is the thermic region where it allowed to measure the inelastic scattering of neutrons using various materials as H{sub 2}O, D{sub 2}O, Be, BeO, etc... (M.P.)

Neutron Time-Of-Flight (n_TOF) experiment

CERN Multimedia

Brugger, M; Kaeppeler, F K; Jericha, E; Cortes rossell, G P; Riego perez, A; Baccomi, R; Laurent, B G; Griesmayer, E; Leeb, H; Dressler, M; Cano ott, D; Variale, V; Ventura, A; Carrillo de albornoz trillo, A; Andrzejewski, J J; Pavlik, A F; Kadi, Y; Zanni vlastou, R; Krticka, M; Kokkoris, M; Praena rodriguez, A J; Cortes giraldo, M A; Perkowski, J; Losito, R; Audouin, L; Weiss, C; Tagliente, G; Wallner, A; Woods, P J; Mengoni, A; Guerrero sanchez, C G; Tain enriquez, J L; Vlachoudis, V; Calviani, M; Junghans, A R; Reifarth, R; Mendoza cembranos, E; Quesada molina, J M; Babiano suarez, V; Schumann, M D; Tsinganis, A; Rauscher, T; Calvino tavares, F; Mingrone, F; Gonzalez romero, E M; Colonna, N; Negret, A L; Chiaveri, E; Milazzo, P M; De almeida carrapico, C A; Castelluccio, D M

The neutron time-of-flight facility n_TOF at CERN, Switzerland, operational since 2001, delivers neutrons using the Proton Synchrotron (PS) 20 GeV/c proton beam impinging on a lead spallation target. The facility combines a very high instantaneous neutron flux, an excellent time of flight resolution due to the distance between the experimental area and the production target (185 meters), a low intrinsic background and a wide range of neutron energies, from thermal to GeV neutrons. These characteristics provide a unique possibility to perform neutron-induced capture and fission cross-section measurements for applications in nuclear astrophysics and in nuclear reactor technology.

Trace metal analysis in arctic aerosols by an inductively coupled plasma-time of flight-mass spectrometer combined with an inductively heated vaporizer

International Nuclear Information System (INIS)

Luedke, Christian; Skole, Jochen; Taubner, Kerstin; Kriews, Michael

2005-01-01

Two newly developed instruments were combined to analyze the trace metal content in size separated arctic aerosols during the measurement campaign ASTAR 2004 (Arctic Study of Tropospheric Aerosols, Clouds and Radiation 2004) at Spitsbergen in May-June 2004. The aim of this extensive aerosol measurement campaign was to obtain a database for model-calculations of arctic aerosol, which play an important role in the global climate change. The ASTAR project was centered on two aircraft measurement campaigns, scheduled from 2004 to 2005, addressing both aerosol and cloud measurements, combined with ground-based and satellite observations. In the present paper one example for the analysis of ground-based aerosol particles is described. The sampling of aerosol particles was performed in a well-known manner by impaction of the particles on cleaned graphite targets. By means of a cascade impactor eight size classes between 0.35 and 16.6 μm aerodynamic diameters were separated. To analyze the metal content in the aerosol particles the targets were rapidly heated up to 2700 deg. C in an inductively heated vaporizer system (IHVS). An argon flow transports the vaporized sample material into the inductively coupled plasma (ICP) used as ionization source for the time of flight-mass spectrometer (TOF-MS). The simultaneous extraction of the ions from the plasma, as realized in the TOF instrument, allows to obtain the full mass spectrum of the sample during the vaporization pulse without any limitation in the number of elements detected. With optimized experimental parameters the element content in arctic aerosol particles was determined in a mass range between 7 Li and 209 Bi. Comparing the size distribution of the elemental content of the aerosol particles, two different meteorological situations were verified. For calibration acidified reference solutions were placed on the cleaned target inside the IHVS. The limits of detection (LOD) for the element mass on the target range

The performance and the characterization of laser ablation aerosol particle time-of-flight mass spectrometry (LAAP-ToF-MS)

Science.gov (United States)

Gemayel, Rachel; Hellebust, Stig; Temime-Roussel, Brice; Hayeck, Nathalie; Van Elteren, Johannes T.; Wortham, Henri; Gligorovski, Sasho

2016-05-01

Hyphenated laser ablation-mass spectrometry instruments have been recognized as useful analytical tools for the detection and chemical characterization of aerosol particles. Here we describe the performances of a laser ablation aerosol particle time-of-flight mass spectrometer (LAAP-ToF-MS) which was designed for aerodynamic particle sizing using two 405 nm scattering lasers and characterization of the chemical composition of single aerosol particle via ablation/ionization by a 193 nm excimer laser and detection in a bipolar time-of-flight mass spectrometer with a mass resolving power of m/Δm > 600.We describe a laboratory based optimization strategy for the development of an analytical methodology for characterization of atmospheric particles using the LAAP-ToF-MS instrument in combination with a particle generator, a differential mobility analyzer and an optical particle counter. We investigated the influence of particle number concentration, particle size and particle composition on the detection efficiency. The detection efficiency is a product of the scattering efficiency of the laser diodes and the ionization efficiency or hit rate of the excimer laser. The scattering efficiency was found to vary between 0.6 and 1.9 % with an average of 1.1 %; the relative standard deviation (RSD) was 17.0 %. The hit rate exhibited good repeatability with an average value of 63 % and an RSD of 18 %. In addition to laboratory tests, the LAAP-ToF-MS was used to sample ambient air during a period of 6 days at the campus of Aix-Marseille University, situated in the city center of Marseille, France. The optimized LAAP-ToF-MS methodology enables high temporal resolution measurements of the chemical composition of ambient particles, provides new insights into environmental science, and a new investigative tool for atmospheric chemistry and physics, aerosol science and health impact studies.

In-flight calibration of Hitomi Soft X-ray Spectrometer. (1) Background

Science.gov (United States)

Kilbourne, Caroline A.; Sawada, Makoto; Tsujimoto, Masahiro; Angellini, Lorella; Boyce, Kevin R.; Eckart, Megan E.; Fujimoto, Ryuichi; Ishisaki, Yoshitaka; Kelley, Richard L.; Koyama, Shu; Leutenegger, Maurice A.; Loewenstein, Michael; McCammon, Dan; Mitsuda, Kazuhisa; Nakashima, Shinya; Porter, Frederick S.; Seta, Hiromi; Takei, Yoh; Tashiro, Makoto S.; Terada, Yukikatsu; Yamada, Shinya; Yamasaki, Noriko Y.

2018-03-01

The X-Ray Spectrometer (XRS) instrument of Suzaku provided the first measurement of the non-X-ray background (NXB) of an X-ray calorimeter spectrometer, but the data set was limited. The Soft X-ray Spectrometer (SXS) instrument of Hitomi was able to provide a more detailed picture of X-ray calorimeter background, with more than 360 ks of data while pointed at the Earth, and a comparable amount of blank-sky data. These data are important not only for analyzing SXS science data, but also for categorizing the contributions to the NXB in X-ray calorimeters as a class. In this paper, we present the contributions to the SXS NXB, the types and effectiveness of the screening, the interaction of the screening with the broad-band redistribution, and the residual background spectrum as a function of magnetic cut-off rigidity. The orbit-averaged SXS NXB in the range 0.3-12 keV was 4 × 10-2 counts s-1 cm-2. This very low background in combination with groundbreaking spectral resolution gave SXS unprecedented sensitivity to weak spectral lines.

TORCH—a Cherenkov based time-of-flight detector

Energy Technology Data Exchange (ETDEWEB)

Dijk, M.W.U. van, E-mail: m.vandijk@bristol.ac.uk [H.H. Wills Physics Laboratory, University of Bristol, Tyndall Avenue, Bristol BS8 1TL (United Kingdom); Brook, N.H. [H.H. Wills Physics Laboratory, University of Bristol, Tyndall Avenue, Bristol BS8 1TL (United Kingdom); Castillo García, L. [European Organisation for Nuclear Research (CERN), CH-1211 Geneva 23 (Switzerland); Laboratory for High Energy Physics, Ecole Polytechnique Fédérale de Lausanne, CH-1015 Lausanne (Switzerland); Cowie, E.N.; Cussans, D. [H.H. Wills Physics Laboratory, University of Bristol, Tyndall Avenue, Bristol BS8 1TL (United Kingdom); D' Ambrosio, C. [European Organisation for Nuclear Research (CERN), CH-1211 Geneva 23 (Switzerland); Fopma, J. [Denys Wilkinson Laboratory, University of Oxford, Keble Road, Oxford OX1 3RH (United Kingdom); Forty, R.; Frei, C. [European Organisation for Nuclear Research (CERN), CH-1211 Geneva 23 (Switzerland); Gao, R. [Denys Wilkinson Laboratory, University of Oxford, Keble Road, Oxford OX1 3RH (United Kingdom); Gys, T. [European Organisation for Nuclear Research (CERN), CH-1211 Geneva 23 (Switzerland); Harnew, N.; Keri, T. [Denys Wilkinson Laboratory, University of Oxford, Keble Road, Oxford OX1 3RH (United Kingdom); Piedigrossi, D. [European Organisation for Nuclear Research (CERN), CH-1211 Geneva 23 (Switzerland)

2014-12-01

TORCH is an innovative high-precision time-of-flight system to provide particle identification in the difficult intermediate momentum region up to 10 GeV/c. It is also suitable for large-area applications. The detector provides a time-of-flight measurement from the imaging of Cherenkov photons emitted in a 1 cm thick quartz radiator. The photons propagate by total internal reflection to the edge of the quartz plate and are then focused onto an array of photon detectors at the periphery. A time-of-flight resolution of about 10–15 ps per incident charged particle needs to be achieved to allow a three sigma kaon-pion separation up to 10 GeV/c momentum for the TORCH located 9.5 m from the interaction point. Given ∼30 detected photons per incident charged particle, this requires measuring the time-of-arrival of individual photons to about 70 ps. This paper will describe the design of a TORCH prototype involving a number of ground-breaking and challenging techniques.

Ion microtomography using ion time-of-flight

International Nuclear Information System (INIS)

Roberts, M.L.; Heikkinen, D.W.; Proctor, I.D.; Pontau, A.E.; Olona, G.T.; Felter, T.E.; Morse, D.H.; Hess, B.V.

1992-01-01

We have developed and are in the process of testing an ion time-of-flight (TOF) detector system for use in our ion microtomography measurements. Using TOF, ion energy is determined by measurement of the ion's flight time over a certain path length. For ion microtomography, the principle advantage of TOF analysis is that ion count rates of several hundred thousand counts per second can be achieved as compared to a limit of about ten thousand ions per second when using a solid-state silicon surface barrier detector and associated electronics. This greater than 10 fold increase in count rate correspondingly shortens sample analysis time or increases the amount of data that can be collected on a given sample. Details of the system and progress to date are described

Recent progress in the chopper spectrometer, INC

International Nuclear Information System (INIS)

Itoh, Shinichi; Arai, Masatoshi; Kawai, Masayoshi

2001-01-01

A guide tube comprising supermirrors, of which the critical wavenumber is three times as large as that of natural nickel, was installed in the primary flight path of the chopper spectrometer, INC, at KENS. Also, the characteristics of the ambient-temperature H 2 O moderator, which INC is facing, was changed by renewal construction of the neutron source at KENS. We discuss here an improvement in the performance of INC by a comparison with the previous performance. We also report on the development on a goniometer for single-crystal experiments at low temperatures. (author)

TOF spectrometer with improved sensitivity for ERDA of light isotopes

International Nuclear Information System (INIS)

Siketic, Z.; Bogdanovic Radovic, I.; Jaksic, M.

2009-01-01

Time-of-Flight Elastic Recoil Detection Analysis (TOF ERDA) is a well established and powerful ion beam analytical technique. It is used for simultaneous and quantitative analysis of elemental depth distributions of light and medium mass elements in both light and heavy matrices. Contrary to silicon particle detectors, the efficiency of the carbon-foil MCP time detectors in TOF system depends on energy and electronic stopping power of analyzing recoil atoms in the C foil and it is often less than 100% for light elements (H, He, Li). This is particularly critical for hydrogen isotopes where detection efficiency can be drastically reduced (∼ 10%). Therefore, TOF ERDA spectrometers were so far not the best choice for depth profiling and quantification of light elements. To improve the detection efficiency of TOF ERDA, the electron emission of C foils (∼ 0.3 μg/cm 2 ) has been enhanced by evaporating a thin LiF layer on the foil. That procedure improved significantly detection efficiency of hydrogen and other light elements, making TOF ERDA spectrometer more suitable for multielemental analysis applications. The capabilities of upgraded spectrometer were demonstrated on samples with well known as well as unknown concentration and depth distribution of H and D.(author)

Design of a pulsed angular selective electron gun for the KATRIN main spectrometer

Energy Technology Data Exchange (ETDEWEB)

Winzen, Daniel; Hannen, Volker; Ortjohann, Hans-Werner; Zacher, Michael; Weinheimer, Christian [Institut fuer Kernphysik, Westfaelische Wilhelms-Universitaet, Muenster (Germany); Collaboration: KATRIN-Collaboration

2012-07-01

The KATRIN (KArlsruhe TRItium Neutrino mass) experiment will study the tritium {beta}-spectrum near the endpoint of 18.6 keV, aiming to measure the mass of the electron antineutrino. Using an electrostatic retarding spectrometer (MAC-E-Filter), the projected sensitivity for m{sub ve} is 200 meV/c{sup 2} at 90% C.L. In order to map out the electric and magnetic fields in the main spectrometer, an angular selective electron gun is currently being developed. The e-gun uses an UV-Laser to produce electrons via the photo-electric effect from a copper substrate which are then accelerated electrostatically. It features a small energy spread of approx. 0.1 eV, a sharp emission angle and will be able to cover the whole magnetic flux tube of KATRIN. Using a pulsed laser it is also possible to investigate the time of flight (TOF) of electrons through the spectrometer, offering enhanced sensitivity to spectrometer properties far away from the analysing plane. By comparing information from transmission function measurements and TOF data with Monte Carlo simulations of the setup, one will be able to achieve a detailed understanding of the spectrometer properties.

Development of hard X-ray spectrometer with high time resolution on the J-TEXT tokamak

Energy Technology Data Exchange (ETDEWEB)

Ma, T.K.; Chen, Z.Y., E-mail: zychen@hust.edu.cn; Huang, D.W.; Tong, R.H.; Yan, W.; Wang, S.Y.; Dai, A.J.; Wang, X.L.

2017-06-01

A hard X-ray (HXR) spectrometer has been developed to study the runaway electrons during the sawtooth activities and during the runaway current plateau phase on the J-TEXT tokamak. The spectrometer system contains four NaI scintillator detectors and a multi-channel analyzer (MCA) with 0.5 ms time resolution. The dedicated peak detection circuit embedded in the MCA provides a pulse height analysis at count rate up to 1.2 million counts per second (Mcps), which is the key to reach the high time resolution. The accuracy and reliability of the system have been verified by comparing with the hardware integrator of HXR flux. The temporal evolution of HXR flux in different energy ranges can be obtained with high time resolution by this dedicated HXR spectrometer. The response of runaway electron transport with different energy during the sawtooth activities can be studied. The energy evolution of runaway electrons during the plateau phase of runaway current can be obtained. - Highlights: • A HXR spectrometer with high time resolution has been developed on J-TEXT tokamak. • The response of REs transport during the sawtooth activities can be investigated. • The energy evolution of REs following the disruptions can be monitored.

HORACE: Software for the analysis of data from single crystal spectroscopy experiments at time-of-flight neutron instruments

International Nuclear Information System (INIS)

Ewings, R.A.; Buts, A.; Le, M.D.; Duijn, J. van; Bustinduy, I.; Perring, T.G.

2016-01-01

The HORACE suite of programs has been developed to work with large multiple-measurement data sets collected from time-of-flight neutron spectrometers equipped with arrays of position-sensitive detectors. The software allows exploratory studies of the four dimensions of reciprocal space and excitation energy to be undertaken, enabling multi-dimensional subsets to be visualized, algebraically manipulated, and models for the scattering to simulated or fitted to the data. The software is designed to be an extensible framework, thus allowing user-customized operations to be performed on the data. Examples of the use of its features are given for measurements exploring the spin waves of the simple antiferromagnet RbMnF_3 and ferromagnetic iron, and the phonons in URu_2Si_2.

HORACE: Software for the analysis of data from single crystal spectroscopy experiments at time-of-flight neutron instruments

Energy Technology Data Exchange (ETDEWEB)

Ewings, R.A.; Buts, A.; Le, M.D. [ISIS Facility, STFC Rutherford Appleton Laboratory, Harwell Campus, Didcot OX11 0QX (United Kingdom); Duijn, J. van [Departamento de Mecánica, Universidad de Córdoba, 14071 Córdoba (Spain); Bustinduy, I. [ESS Bilbao, Poligono Ugaldeguren III, Pol. A, 7B - 48170 Zamudio, Bizkaia – País Vasco (Spain); Perring, T.G., E-mail: toby.perring@stfc.ac.uk [ISIS Facility, STFC Rutherford Appleton Laboratory, Harwell Campus, Didcot OX11 0QX (United Kingdom); London Centre for Nanotechnology and Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT (United Kingdom)

2016-10-21

The HORACE suite of programs has been developed to work with large multiple-measurement data sets collected from time-of-flight neutron spectrometers equipped with arrays of position-sensitive detectors. The software allows exploratory studies of the four dimensions of reciprocal space and excitation energy to be undertaken, enabling multi-dimensional subsets to be visualized, algebraically manipulated, and models for the scattering to simulated or fitted to the data. The software is designed to be an extensible framework, thus allowing user-customized operations to be performed on the data. Examples of the use of its features are given for measurements exploring the spin waves of the simple antiferromagnet RbMnF{sub 3} and ferromagnetic iron, and the phonons in URu{sub 2}Si{sub 2}.

New components for the neutron spectrometer SV5c at the 10H channel of the research reactor FRJ2

International Nuclear Information System (INIS)

Stockmeyer, R.

1991-02-01

The following new components have been installed at the neutron time-of-flight spectrometer SV5c: 1. Monochromator with devices for tilting and rotating 10 crystal. The fine-adjustment of the crystal orientation can be done with a computer program which maximizes the neutron intensity at the sample position. 2. 128 x 512 multi-channel time-of-flight electronic 3. Computerized equipment for measuring thermal properties of a sample (adsorption isotherm, sample transmission) 4. Data aquisition, data handling and experiment control software coded in ASYST. (orig.)

Near shot-noise limited time-resolved circular dichroism pump-probe spectrometer

Science.gov (United States)

Stadnytskyi, Valentyn; Orf, Gregory S.; Blankenship, Robert E.; Savikhin, Sergei

2018-03-01

We describe an optical near shot-noise limited time-resolved circular dichroism (TRCD) pump-probe spectrometer capable of reliably measuring circular dichroism signals in the order of μdeg with nanosecond time resolution. Such sensitivity is achieved through a modification of existing TRCD designs and introduction of a new data processing protocol that eliminates approximations that have caused substantial nonlinearities in past measurements and allows the measurement of absorption and circular dichroism transients simultaneously with a single pump pulse. The exceptional signal-to-noise ratio of the described setup makes the TRCD technique applicable to a large range of non-biological and biological systems. The spectrometer was used to record, for the first time, weak TRCD kinetics associated with the triplet state energy transfer in the photosynthetic Fenna-Matthews-Olson antenna pigment-protein complex.

Quadrupole Time-of-Flight Mass Spectrometer

Data.gov (United States)

Federal Laboratory Consortium — FUNCTION: The system generates superior quality mass spectrometry (MS) and tandem mass spectrometry (MS/MS) data from both atmospheric pressure ionization (API) and...

Time-of-flight mass spectrographs—From ions to neutral atoms

Science.gov (United States)

Möbius, E.; Galvin, A. B.; Kistler, L. M.; Kucharek, H.; Popecki, M. A.

2016-12-01

After their introduction to space physics in the mid 1980s time-of-flight (TOF) spectrographs have become a main staple in spaceborne mass spectrometry. They have largely replaced magnetic spectrometers, except when extremely high mass resolution is required to identify complex molecules, for example, in the vicinity of comets or in planetary atmospheres. In combination with electrostatic analyzers and often solid state detectors, TOF spectrographs have become key instruments to diagnose space plasma velocity distributions, mass, and ionic charge composition. With a variety of implementation schemes that also include isochronous electric field configurations, TOF spectrographs can respond to diverse science requirements. This includes a wide range in mass resolution to allow the separation of medium heavy isotopes or to simply provide distributions of the major species, such as H, He, and O, to obtain information on source tracers or mass fluxes. With a top-hat analyzer at the front end, or in combination with deflectors for three-axis stabilized spacecraft, the distribution function of ions can be obtained with good time resolution. Most recently, the reach of TOF ion mass spectrographs has been extended to include energetic neutral atoms. After selecting the arrival direction with mechanical collimation, followed by conversion to ions, adapted TOF sensors form a new branch of the spectrograph family tree. We review the requirements, challenges, and implementation schemes for ion and neutral atom spectrographs, including potential directions for the future, while largely avoiding overlap with complementary contributions in this special issue.

Assessing and minimizing contamination in time of flight based validation data

Science.gov (United States)

Lennox, Kristin P.; Rosenfield, Paul; Blair, Brenton; Kaplan, Alan; Ruz, Jaime; Glenn, Andrew; Wurtz, Ronald

2017-10-01

Time of flight experiments are the gold standard method for generating labeled training and testing data for the neutron/gamma pulse shape discrimination problem. As the popularity of supervised classification methods increases in this field, there will also be increasing reliance on time of flight data for algorithm development and evaluation. However, time of flight experiments are subject to various sources of contamination that lead to neutron and gamma pulses being mislabeled. Such labeling errors have a detrimental effect on classification algorithm training and testing, and should therefore be minimized. This paper presents a method for identifying minimally contaminated data sets from time of flight experiments and estimating the residual contamination rate. This method leverages statistical models describing neutron and gamma travel time distributions and is easily implemented using existing statistical software. The method produces a set of optimal intervals that balance the trade-off between interval size and nuisance particle contamination, and its use is demonstrated on a time of flight data set for Cf-252. The particular properties of the optimal intervals for the demonstration data are explored in detail.

Third generation of lead slowing-down spectrometers: First results and prospects

International Nuclear Information System (INIS)

Alexeev, A.A.; Belousov, Yu.V.; Bergman, A.A.; Volkov, A.N.; Goncharenko, O.N.; Grachev, M.N.; Kazarnovsky, M.V.; Matushkov, V.L.; Mostovoy, V.I.; Novikov, A.V.; Novoselov, S.A.; Ryabov, Yu.V.; Stavissky, Yu.Ya.; Gledenov, Yu.M.; Parzhitski, S.S.; Popov, Yu.P.

1999-01-01

At the same neutron-source intensity S, lead slowing-down spectrometers (LSDS) for neutrons possess luminosity 10 3 -10 4 times as great as that of time-of-flight spectrometers with the same energy resolution ΔE/E(bar sign) (for the former, ΔE/E(bar sign)≅35-45% at a mean energy E(bar sign) less than 50 keV). In combination with high-current proton accelerators, third-generation LSDSs can operate at S values exceeding those acceptable for second-generation LSDSs coupled to electron accelerators by a factor of 10 2 to 10 3 . At the Institute for Nuclear Research (Russian Academy of Sciences, Moscow), the first third-generation LSDS facility called PITON (about 15 tons of lead) has been operating successfully and a large LSDS (more than 100 tons of lead) is now under construction. The results of the first experiments at the PITON facility are presented, and the experimental programs for both facilities is outlined

Improvement of the intrinsic time resolving power of the Cologne iron-free orange type electron spectrometers

Energy Technology Data Exchange (ETDEWEB)

Regis, J.-M.; Materna, Th.; Pascovici, G.; Christen, S.; Dewald, A.; Fransen, C.; Jolie, J.; Petkov, P.; Zell, K. O. [Institut fuer Kernphysik (IKP), Universitaet zu Koeln, Zuelpicher Str. 77, 50937 Koeln (Germany)

2010-11-15

Conversion electron spectroscopy represents an important tool for nuclear structure analysis of medium and heavy nuclei. Two iron-free magnetic electron spectrometers of the orange type have been installed at the Institute for Nuclear Physics of the University of Cologne. The very large transmission of 15% and the very good energy resolution of 1% makes the iron-free orange spectrometer a powerful instrument. By means of fast timing techniques, lifetimes of nuclear excited states can be measured with an accuracy better than 20 ps. For the first time, the energy dependent centroid position of prompt events yielding the time-walk characteristics (the prompt curve) of the orange spectrometer fast timing setup has been measured using prompt secondary {delta}-electrons generated in a pulsed beam experiment. The prompt curve calibrated as a function of energy allows precise lifetime determination down to a few tens of picoseconds by the use of the centroid shift method.

Resolution of the VESUVIO spectrometer for High-energy Inelastic Neutron Scattering experiments

Science.gov (United States)

Imberti, S.; Andreani, C.; Garbuio, V.; Gorini, G.; Pietropaolo, A.; Senesi, R.; Tardocchi, M.

2005-11-01

New perspectives for epithermal neutron spectroscopy have been opened up as a result of the development of the Resonance Detector and its use on inverse geometry time-of-flight spectrometers at spallation sources. A special application of the Resonance Detector is the Very Low Angle Detector Bank (VLAD) for the VESUVIO spectrometer at ISIS, operating in the angular range 1∘500 meV, a regime so far inaccessible to experimental studies on condensed matter systems. The HINS measurements complement the Deep Inelastic Neutron Scattering (DINS) measurements performed on VESUVIO in the high wavevector q(20 Å-11 eV), where the short-time single-particle dynamics can be sampled. This paper will revise the main components of the resolution for HINS measurements of VESUVIO. Instrument performances and examples of applications for neutron scattering processes at high energy and at low wavevector transfer are discussed.

Time-of-flight scattering and recoiling spectrometry

International Nuclear Information System (INIS)

Rabalais, J.W.

1991-01-01

Ion scattering and recoiling spectrometry consists of directing a collimated beam of monoenergetic ions towards a surface and measuring the flux of scattered and recoiled particles from this surface. When the neutral plus ion flux is velocity selected by measuring the flight times from the sample to the detector, the technique is called time-of-flight scattering and recoiling spectrometry (TOF-SARS). TOF-SARS is capable of (1) surface elemental analysis by applying classical mechanics to the velocities of the particles, (2) surface structural analysis by monitoring the angular anisotropies in the particle flux, and (3) ion-surface electron exchange probabilities by analysis of the ion/neutral fractions in the particle flux. Examples of these three areas are presented herein

Cosmic radiation algorithm utilizing flight time tables

International Nuclear Information System (INIS)

Katja Kojo, M.Sc.; Mika Helminen, M.Sc.; Anssi Auvinen, M.D.Ph.D.; Katja Kojo, M.Sc.; Anssi Auvinen, M.D.Ph.D.; Gerhard Leuthold, D.Sc.

2006-01-01

Cosmic radiation is considerably higher on cruising altitudes used in aviation than at ground level. Exposure to cosmic radiation may increase cancer risk among pilots and cabin crew. The International Commission on Radiation Protection (ICRP) has recommended that air crew should be classified as radiation workers. Quantification of cosmic radiation doses is necessary for assessment of potential health effects of such occupational exposure. For Finnair cabin crew (cabin attendants and stewards), flight history is not available for years prior to 1991 and therefore, other sources of information on number and type of flights have to be used. The lack of systematically recorded information is a problem for dose estimation for many other flight companies personnel as well. Several cosmic radiation dose estimations for cabin crew have been performed using different methods (e.g. 2-5), but they have suffered from various shortcomings. Retrospective exposure estimation is not possible with personal portable dosimeters. Methods that employ survey data for occupational dose assessment are prone to non-differential measurement error i.e. the cabin attendants do not remember correctly the number of past flights. Assessment procedures that utilize surrogate measurement methods i.e. the duration of employment, lack precision. The aim of the present study was to develop an assessment method for individual occupational exposure to cosmic radiation based on flight time tables. Our method provides an assessment method that does not require survey data or systematic recording of flight history, and it is rather quick, inexpensive, and possible to carry out in all other flight companies whose past time tables for the past periods exist. Dose assessment methods that employ survey data are prone to random error i.e. the cabin attendants do not remember correctly the number or types of routes that they have flown during the past. Our method avoids this since survey data are not needed

Comparison of detector materials for time-of-flight positron tomography

International Nuclear Information System (INIS)

Derenzo, S.E.

1982-06-01

Knowledge of detection efficiency and timing resolution is essential when comparing detector materials for time-of-flight positron tomography. We present results of Monte Carlo calculations of the detection efficiency of plastic, lead loaded plastic, NaI(T1), liquid xenon, bismuth germanate (BGO), CsF, BaF 2 , Ge, and HgI 2 for 511 keV photons. We also use recently published values of timing resolution for these detector materials to tabulate the quantity (efficiency) 2 /(time resolution) which is a measure of the relative sensitivity for time of flight positron tomography

Time-of-flight position-sensitive x-ray detection

International Nuclear Information System (INIS)

Mowat, J.W.

1981-01-01

A new method for recording beam-foil time-of-flight data is described. A stationary, side-window, position-senstive proportional counter, oriented with anode wire parallel to the ion beam, views the decay in flight of excited ions through a Soller slit x-ray collimator. In contrast to the standard method, the exciter foil, placed within or upstream from the field of view, is not moved during the acquisition of a decay curve. Each point on the anode acts like an independent detector seeing a unique segment of the ion beam. The correspondence between the downstream distance at which an ion decays and the position along the anode at which the x-ray is detected makes a pulse-height spectrum of position pulses equivalent to a time-of-flight decay curve. Thus an entire decay curve can now be acquired without moving the foil. Increased efficiency is the most significant improvement over the standard method in which the radiation detector views only a small segment of the flight path at any one time. Experiments using translating foils are subject to a spurious dependence of x-ray intensity on foil position if the foil is non-uniform (or non-uniformly aged) and wobbles as it moves. This effect is eliminated here. Foil aging effects which influence excitation rates and introduce a slowly varying time dependence of the x-ray intensity are automatically normalized by this multichannel technique. The application of this method to metastable x-ray emitting states of low-Z ions are discussed

Doppler time-of-flight imaging

KAUST Repository

Heide, Felix

2015-07-30

Over the last few years, depth cameras have become increasingly popular for a range of applications, including human-computer interaction and gaming, augmented reality, machine vision, and medical imaging. Many of the commercially-available devices use the time-of-flight principle, where active illumination is temporally coded and analyzed on the camera to estimate a per-pixel depth map of the scene. In this paper, we propose a fundamentally new imaging modality for all time-of-flight (ToF) cameras: per-pixel velocity measurement. The proposed technique exploits the Doppler effect of objects in motion, which shifts the temporal frequency of the illumination before it reaches the camera. Using carefully coded illumination and modulation frequencies of the ToF camera, object velocities directly map to measured pixel intensities. We show that a slight modification of our imaging system allows for color, depth, and velocity information to be captured simultaneously. Combining the optical flow computed on the RGB frames with the measured metric axial velocity allows us to further estimate the full 3D metric velocity field of the scene. We believe that the proposed technique has applications in many computer graphics and vision problems, for example motion tracking, segmentation, recognition, and motion deblurring.

Atom-probe field-ion-microscope mass spectrometer

International Nuclear Information System (INIS)

Nishikawa, Osamu

1983-01-01

The titled analyzer, called simply atom-probe, has been developed by combining a field ion microscope (FIM) and a mass spectrometer, and is divided into the time-of-flight type, magnetic sector type, and quadrupole type depending on the types of mass spectrometers. In this paper, the author first describes on the principle and construction of a high resolution, time-of-flight atom-probe developed and fabricated in his laboratory. The feature of the atom-probe lies in the analysis of atoms and molecules in hyper-fine structure region one by one utilizing the high resolution of FIM. It also has the advantages of directly determining the composition by a ratio of the numbers of respective ions because of a constant detection sensitivity regardless of mass numbers, of the resolution as high as single atom layer in depth direction, and of detecting the positional relationship among detected ions by the order of detection in a sample. To determine the composition in a hyperfine structure region, the limited small number of atoms and molecules in the region must be identified distinctly one by one. In the analyzed result of Ni-silicide formed by heating Si evaporated on a Ni tip at 1000 K for 5 minutes, each isotope was not only clearly separated, but also their abundance ratio was very close to the natural abundance ratio. The second half of the paper reports on the analysis of TiC promising for a cold cathode material, adsorption of CO and alcohol, and the composition and structure of silicides, as a few application examples. (Wakatsuki, Y.)

Time-resolved optical spectrometer based on a monolithic array of high-precision TDCs and SPADs

Science.gov (United States)

Tamborini, Davide; Markovic, Bojan; Di Sieno, Laura; Contini, Davide; Bassi, Andrea; Tisa, Simone; Tosi, Alberto; Zappa, Franco

2013-12-01

We present a compact time-resolved spectrometer suitable for optical spectroscopy from 400 nm to 1 μm wavelengths. The detector consists of a monolithic array of 16 high-precision Time-to-Digital Converters (TDC) and Single-Photon Avalanche Diodes (SPAD). The instrument has 10 ps resolution and reaches 70 ps (FWHM) timing precision over a 160 ns full-scale range with a Differential Non-Linearity (DNL) better than 1.5 % LSB. The core of the spectrometer is the application-specific integrated chip composed of 16 pixels with 250 μm pitch, containing a 20 μm diameter SPAD and an independent TDC each, fabricated in a 0.35 μm CMOS technology. In front of this array a monochromator is used to focus different wavelengths into different pixels. The spectrometer has been used for fluorescence lifetime spectroscopy: 5 nm spectral resolution over an 80 nm bandwidth is achieved. Lifetime spectroscopy of Nile blue is demonstrated.