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Sample records for thick alluvial deposits

  1. Alluvial Deposits in Iowa

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    Iowa State University GIS Support and Research Facility — This coverage maps alluvial deposits throughout Iowa. This generally would include areas of alluvial soils associated with modern streams that are identified on...

  2. Correlation of alluvial deposits at the Nevada Test Site

    International Nuclear Information System (INIS)

    Grothaus, B.; Howard, N.

    1977-01-01

    Because characteristics of rock layers and problems in drilling must be studied before radioactive waste can be safely contained, an evaluation was made of methods for correlating alluvial deposits at Yucca Flat of the Nevada Test Site (NTS). Although correlation of Tertiary volcanic tuff beds at the NTS has been successfully achieved, correlation of stratigraphic zones in the overlying alluvium has posed technical difficulties. We have evaluated several methods for correlating alluvial deposits from drillholes, including electric resistivity logs (E logs), visual examination of sidewall samples and comparison of their carbonate (CO 2 ) content, downhole stereo photography for identifying debris flow deposits, caliche age-dating, and specific yield and permeability measurements of deposits. For predicting the thickness of zones having similar physical properties in the alluvium, E log measurements were found to be the most useful of these methods

  3. The Influence of Syndepositional Macropores on the Hydraulic Integrity of Thick Alluvial Clay Aquitards

    Science.gov (United States)

    Timms, Wendy A.; Acworth, R. Ian; Crane, Richard A.; Arns, Christoph H.; Arns, Ji-Youn; McGeeney, Dayna E.; Rau, Gabriel C.; Cuthbert, Mark O.

    2018-04-01

    Clay-rich deposits are commonly assumed to be aquitards which act as natural hydraulic barriers due to their low hydraulic connectivity. Postdepositional weathering processes are known to increase the permeability of aquitards in the near surface but not impact on deeper parts of relatively thick formations. However, syndepositional processes affecting the hydraulic properties of aquitards have previously received little attention in the literature. Here, we analyze a 31 m deep sediment core recovered from an inland clay-rich sedimentary sequence using a combination of techniques including particle size distribution and microscopy, centrifuge dye tracer testing and micro X-ray CT imaging. Subaerial deposition of soils within these fine grained alluvial deposits has led to the preservation of considerable macropores (root channels or animal burrows). Connected pores and macropores thus account for vertical hydraulic conductivity (K) of 4.2×10-9 m/s (geometric mean of 13 samples) throughout the thick aquitard, compared to a matrix K that is likely sediment was deposited must be considered when aquitards are investigated as potential natural hydraulic barriers and illustrate the value of combining multiple investigation techniques for characterizing clay-rich deposits.

  4. Depositional Architecture of Late Pleistocene-Holocene Coastal Alluvial-fan System in the Coastal Range, Taiwan

    Science.gov (United States)

    Chen, S. T.; Chen, W. S.

    2016-12-01

    Since late Pleistocene, the Coastal Range (Philippine Sea plate) collided and overridden on the Central Range (Eurasian Plate) along the Longitudinal Valley Fault. Therefore, the Coastal Range is exposed widely the late Pleistocene-Holocene marine and fluvial terraces caused by the tectonic uplift. Based on the estimation of paleosea-level elevations (Δh), depositional paleodepth, altitude distribution of Holocene deposits (D), altitude of outcrops (H), and 14C dating of marine deposits (t), the uplift rate (=(Δh+H +d-D)/t) is about 5-10 mm/yr in the southern Coastal Range. In this study, we suggest through field logging that the deposits can be divided into alluvial, foreshore (intertidal), shoreface, and offshore environments. In Dulan area in the southern Coastal Range, the uplift rate was 6-7 mm/yr during 16,380-10,000 cal yr BP and 3-4 mm/yr after 7,000 cal yr BP. Results from the Dulan Coastal alluvial-fan system can be divided into five depositional stages: (1) 16,380-14,300 cal yr BP: The rate of global sea level rise (SLR) has averaged about 6-7 mm/yr, similar to the tectonic uplift rate. In this stage, the bedrock was eroded and formed a wide wave-cut platform. (2) 14,300-10,000 cal yr BP: SLR of about 14 mm/yr that was faster than tectonic uplift rate of 6-7 mm/yr. As a result of transgression, the beach-lagoon deposits about 5 m thick were unconformably overlain on the wave-cut platform. (3) 10,000-8,200 cal yr BP: The ongoing sea level rise (SLR: 11 mm/yr), the lagoon deposits were overlain by an offshore slump deposits representing a gradual deepening of the depositional environment. (4) 8,200-7,930 cal yr BP (SLR: 6-7 mm/yr): The tectonic uplift rate may occur at similar SLR. The alluvial-fan deposits have prograded over the shallow marine deposits. (5) After 7,000 cal yr BP (SLR: 1-0 mm/yr): SLR was much slower than tectonic uplift rate of 3-4 mm/yr. Thus, Holocene marine terraces are extensively developed in the coastal region, showing that the

  5. MIDDLE MIOCENE DEPOSITIONAL MODEL IN THE DRAVA DEPRESSION DESCRIBED BY GEOSTATISTICAL POROSITY AND THICKNESS MAPS (CASE STUDY: STARI GRADAC-BARCS NYUGAT FIELD

    Directory of Open Access Journals (Sweden)

    Tomislav Malvić

    2006-12-01

    Full Text Available Neogene depositional environments in the Drava depression can be classified in two groups. One group is of local alluvial fans, which were active during the period of Middle Miocene (Badenian extension through the entire Pannonian Basin. The second group is represented by continuous Pannonian and Pontian sedimentation starting with lacustrine environment of partly deep water and partly prodelta (turbidity fans and terminating at the delta plain sedimentation. The coarse-grained sediments of alluvial fans have the great hydrocarbon potential, because they often comprise reservoir rocks. Reservoir deposits are mostly overlain (as result of fan migration by pelitic seal deposits and sometimes including organic rich source facies. That Badenian sequences are often characterised by complete petroleum systems, what is confirmed by large number of oil and gas discoveries in such sediments in the Drava and other Croatian depressions. Alluvial environments are characterised by frequent changes of petrophysical properties, due to local character of depositional mechanism and material sources. In the presented paper, Stari Gradac-Barcs Nyugat field is selected as a case study for demonstrating the above mentioned heterogenic features of the Badenian sequences. Structural solutions are compared by maps of parameters related to depositional environment, i.e. porosity and thickness maps. Geostatistics were used for spatial extension of input dataset. The spatial variability of porosity values, i.e. reservoir quality, is interpreted by transition among different sub-environments (facies in the alluvial fan system.

  6. Continental Environment of Triassic Alluvial Beds in the Northern North Sea Area: Core Examples from the Lunde Formation, Snorre Field

    Energy Technology Data Exchange (ETDEWEB)

    Nystuen, Johan Petter; Bergan, Morten

    1999-07-01

    Alluvial processes transport and deposit gravel, sand and mud in a series of depositional systems such as alluvial fans, fluvial channels, floodplain and lacustrine basins. In the northernmost part of the North Sea alluvial sandstones form major reservoir rocks in several oil fields in the Tampen Spur area. In the Snorre Field, the Norian- Early Rhaetian Lunde Formation has given a great database from exploration and production wells, seismic studies, reservoir modelling, production experience and comparative analogue studies on facies distribution, alluvial architecture, heterogeneities and reservoir properties of alluvial successions. The Lunde Formation is subdivided in three members, the lower, middle and upper Lunde members, with the upper member being the main part of the Lunde reservoir rocks. The scope of presenting core samples from the upper Lunde member is to demonstrate main alluvial facies and facies associations, how facies analysis proceeds into construction of conceptual fluvial models that in turn are fundamental in evaluation of reservoir heterogeneities and reservoir modelling. The upper Lunde member consists of repeated units of red and grey sandstone and mudstone. Sandstones are dominantly medium-grained with common range from coarse- to very fine-grained. A basic building stone of the alluvial succession consists of a thick single- or multi-storey sandstone body overlain by a thick mudstone unit. Such couplets form allostratigraphic units and define the main reservoir zones.

  7. An alluvial record of El Niño events from northern coastal Peru

    Science.gov (United States)

    Wells, Lisa E.

    1987-12-01

    Overbank flood deposits of northern coastal Peru provide the potential for the development of a late Quaternary chronology of El Niño events. Alluvial deposits from the 1982-1983 El Niño event are the basis for establishing a type El Niño deposit. Sedimentary structures suggesting depositional processes range from sheet flows to debris flows, with sheet flood deposits being the most common. The 1982-1983 deposits are characterized by a 50- to 100-cm- thick basal gravel, overlain by a 10- to 100-cm-thick sand bed, grading into a 1- to 10-cm-thick silty sand bed and capped by a very thin layer of silt or clay. The surface of the deposit commonly displays the original shear flow lines crosscut by postdepositional mud cracks and footprints (human and animal). Stacked sequences of flood deposits are present in Pleistocene and Holocene alluvial fill, suggesting that El Niño type events likely occurred throughout the late Quaternary. A relative chronology of the deposits is developed based on terrace and soil stratigraphy and on the degree of preservation of surficial features. A minimum of 15 El Niño events occurred during the Holocene; a minimum of 21 events occurred during the late Pleistocene. Timing of the Holocene events is bracketed by isochrons derived from the archaeologic stratigraphy. Corrected radiocarbon ages from included detrital wood provide the following absolute dates for El Niño events: 1720 ± 60 A.D., 1460 ± 20 A.D., 1380 ± 140 A.D. (error overlaps with the A.D. 1460 event; these may represent a single event), and 1230 ± 60 B.C.

  8. Characteristics of ejecta and alluvial deposits at Meteor Crater, Arizona and Odessa Craters, Texas: Results from ground penetrating radar

    Science.gov (United States)

    Grant, J. A.; Schultz, P. H.

    1991-01-01

    Previous ground penetrating radar (GRP) studies around 50,000 year old Meteor Crater revealed the potential for rapid, inexpensive, and non-destructive sub-surface investigations for deep reflectors (generally greater than 10 m). New GRP results are summarized focusing the shallow sub-surfaces (1-2 m) around Meteor Crater and the main crater at Odessa. The following subject areas are covered: (1) the thickness, distribution, and nature of the contact between surrounding alluvial deposits and distal ejecta; and (2) stratigraphic relationships between both the ejecta and alluvium derived from both pre and post crater drainages. These results support previous conclusions indicating limited vertical lowering (less than 1 m) of the distal ejecta at Meteor Crater and allow initial assessment of the gradational state if the Odessa craters.

  9. Geological aspects of paleoseismicity and archaeosismology in the fluvial alluvial Rimac valley

    OpenAIRE

    Jacay, Javier

    2017-01-01

    The sedimentary fill of the Rimac River fluvial-alluvial plain (Upper Miocene-Quaternary) consists of a thick sequence of unconsolidated material that corresponds to fluvial deposits. A record of seismotectonic activity is presentedin the sedimentary levels of fine facie within numerous paleoseismic structures such as contoured layers, pseudonodules, load figures, and material injections. Additionally, wall inclination and collapse, as well as displacement and partialfracturing, and pavement ...

  10. Reconnaissance investigation of the alluvial gold deposits in the North Takhar Area of Interest, Takhar Province, Afghanistan

    Science.gov (United States)

    Chirico, Peter G.; Malpeli, Katherine C.; Moran, Thomas W.

    2013-01-01

    This study is a reconnaissance assessment of the alluvial gold deposits of the North Takhar Area of Interest (AOI) in Takhar Province, Afghanistan. Soviet and Afghan geologists collected data and calculated the gold deposit reserves in Takhar Province in the 1970s, prior to the development of satellite-based remote-sensing platforms and new methods of geomorphic mapping. The purpose of this study was to integrate new mapping techniques with previously collected borehole sampling and concentration sampling data and geomorphologic interpretations to reassess the alluvial gold placer deposits in the North Takhar AOI. Through a combination of historical borehole and cross-section data and digital terrain modeling, the Samti, Nooraba-Khasar-Anjir, and Kocha River placer deposits were reassessed. Resource estimates were calculated to be 20,927 kilograms (kg) for Samti, 7,626 kg for Nooraba-Khasar-Anjir, 160 kg for the mouth of the Kocha, 1,047 kg for the lower Kocha, 113 kg for the middle Kocha, and 168 kg for the upper Kocha. Previous resource estimates conducted by the Soviets for the Samti and Nooraba-Khasar-Anjir deposits estimated 30,062 kg and 802 kg of gold, respectively. This difference between the new estimates and previous estimates results from the higher resolution geomorphic model and the interpretation of areas outside of the initial work zone studied by Soviet and Afghan geologists.

  11. Rome in its setting. Post-glacial aggradation history of the Tiber River alluvial deposits and tectonic origin of the Tiber Island

    Science.gov (United States)

    Motta, Laura; Brock, Andrea L.; Macrì, Patrizia; Florindo, Fabio; Sadori, Laura; Terrenato, Nicola

    2018-01-01

    The Tiber valley is a prominent feature in the landscape of ancient Rome and an important element for understanding its urban development. However, little is known about the city’s original setting. Our research provides new data on the Holocene sedimentary history and human-environment interactions in the Forum Boarium, the location of the earliest harbor of the city. Since the Last Glacial Maximum, when the fluvial valley was incised to a depth of tens of meters below the present sea level, 14C and ceramic ages coupled with paleomagnetic analysis show the occurrence of three distinct aggradational phases until the establishment of a relatively stable alluvial plain at 6–8 m a.s.l. during the late 3rd century BCE. Moreover, we report evidence of a sudden and anomalous increase in sedimentation rate around 2600 yr BP, leading to the deposition of a 4-6m thick package of alluvial deposits in approximately one century. We discuss this datum in the light of possible tectonic activity along a morpho-structural lineament, revealed by the digital elevation model of this area, crossing the Forum Boarium and aligned with the Tiber Island. We formulate the hypothesis that fault displacement along this structural lineament may be responsible for the sudden collapse of the investigated area, which provided new space for the observed unusually large accumulation of sediments. We also posit that, as a consequence of the diversion of the Tiber course and the loss in capacity of transport by the river, this faulting activity triggered the origin of the Tiber Island. PMID:29590208

  12. Preparation and characterization of thick metastable sputter deposits

    International Nuclear Information System (INIS)

    Allen, R.P.; Dahlgren, S.D.; Merz, M.D.

    1975-01-01

    High-rate dc supported-discharge sputtering techniques were developed and used to prepare 0.1 mm to 5.0 mm-thick deposits of a variety of metastable materials including amorphous alloys representing more than 15 different rare-earth-transition metal systems and a wide range of compositions and deposition conditions. The ability to prepare thick, homogeneous deposits has made it possible for the first time to investigate the structure, properties, and annealing behavior of these unique sputtered alloys using neutron diffraction, ultrasonic, and other experimental techniques that are difficult or impractical for thin films. More importantly, these characterization studies show that the structure and properties of the massive sputter deposits are independent of thickness and can be reproduced from deposit to deposit. Other advantages and applications of this metastable materials preparation technique include the possibility of varying structure and properties by control of the deposition parameters and the ability to deposit even reactive alloys with a very low impurity content

  13. Late Pleistocene dune-sourced alluvial fans in coastal settings: Sedimentary facies and related processes (Mallorca, Western Mediterranean)

    Science.gov (United States)

    Pomar, F.; del Valle, L.; Fornós, J. J.; Gómez-Pujol, L.

    2018-05-01

    Aeolian-alluvial sedimentary interaction results in the formation of deposits characterized by typical alluvial sedimentary structures, but is composed of conspicuous amounts of aeolian sediments. The literature on this topic is limited and most works relate more with continental aeolian dunes or fluvial dune interference with fan bodies. Furthermore, there is a lack of examples of aeolian-alluvial sedimentary interference in coastal settings. In the western Mediterranean, there are many Pleistocene alluvial fan deposits built up partly by sediment originating from coastal dunes dismantled by alluvial streams. Very often, these deposits show a continuous sedimentary sequence through which we can derive the contribution and predominance of coastal, alluvial-colluvial and aeolian processes and their controls on landscape formation. This is an outstanding feature within coastal systems since it shows marine sediments reworked and integrated within coastal dune fields by aeolian transport, and the latter built up into alluvial fan bodies. In this sense, aeolian-alluvial interaction is the geomorphic-sedimentary expression of the coexistence and overlapping of alluvial and aeolian environments resulting in deposits sharing sedimentary features from both environments. The aim of this paper is to unravel the contribution of coastal dunes in the construction of alluvial fans bodies and identify the main sedimentary facies that constitute these deposits, as well as their climatic controls. For this reason, Es Caló fan (northern Mallorca) has been selected due to its well-exposed deposits exhibiting the alternation of aeolian, alluvial and colluvial deposits. Sedimentological and stratigraphic analyses based on 33 logs and complementary analyses demonstrate that most of the facies constituting the fan body are made up completely of marine bioclastic sands. These deposits record an alluvial fan sedimentary environment characterized by sediments inputs that do not proceed

  14. Laboratory alluvial fans in one dimension.

    Science.gov (United States)

    Guerit, L; Métivier, F; Devauchelle, O; Lajeunesse, E; Barrier, L

    2014-08-01

    When they reach a flat plain, rivers often deposit their sediment load into a cone-shaped structure called alluvial fan. We present a simplified experimental setup that reproduces, in one dimension, basic features of alluvial fans. A mixture of water and glycerol transports and deposits glass beads between two transparent panels separated by a narrow gap. As the beads, which mimic natural sediments, get deposited in this gap, they form an almost one-dimensional fan. At a moderate sediment discharge, the fan grows quasistatically and maintains its slope just above the threshold for sediment transport. The water discharge determines this critical slope. At leading order, the sediment discharge only controls the velocity at which the fan grows. A more detailed analysis reveals a slight curvature of the fan profile, which relates directly to the rate at which sediments are transported.

  15. ALLUVIAL DEPOSITS AS A SUBSOIL AND MATERIAL FOR BASIC HYDRO-TECHNICAL CONSTRUCTIONS

    Directory of Open Access Journals (Sweden)

    Jędrzej Wierzbicki

    2015-11-01

    Full Text Available The article presents an analysis of geotechnical parameters of the alluvial deposit (the areas of the Vistula and Warta river valleys with a view to using the soil as an earth construction material and as a foundation for buildings constructed on the grounds tested. Strength and deformation parameters of the subsoil tested were identified by the CPTU (cone penetration test and DMT (flat dilatometer test methods, as well as by the vane test (VT. The article includes the analysis of overconsolidation process of the soil tested and a formula for the identification of the overconsolidation ratio OCR. Equation 4 reflects the relation between the undrained shear strength and plasticity of the silts analyzed and the OCR value. The analysis resulted in the determination of the Nkt coefficient, which might be used to identify the undrained shear strength of both sediments tested. On the basis of a detailed analysis of changes in terms of the constrained oedometric modulus M0, the relations between the said modulus, the liquidity index and the OCR value were identified. Mayne’s formula (1995 was used to determine the M0 modulus from the CPTU test. The usefulness of the alluvial deposit as an earth construction material was analysed after their structure had been destroyed and compacted with a Proctor apparatus. In cases of samples characterized by different water content and soil particle density, the analysis of changes in terms of cohesion and the internal friction angle proved that these parameters are influenced by the soil phase composition. On the basis of the tests, it was concluded that the most desirable shear strength parameters are achieved when the silt is compacted below the optimum water content.

  16. Distribution of technogenic radionuclides in alluvial deposits and fractions of soils in neighboring zone of Krasnoyarsk GKhK

    International Nuclear Information System (INIS)

    Linnik, V.G.; Volosov, A.G.; Korobova, E.M.; Borisov, A.P.; Potapov, V.N.; Surkov, V.V.; Borguis, A.P.; Braun, Dzh.; Alekseeva, T.A.

    2004-01-01

    Distribution of synthetic radionuclides using landscape-radiation profile of Berezovyj island. Difference in density of contamination deals with heterogeneous lithological composition of soil-forming rocks and so with different duration of flooding. Radionuclide distribution in alluvial deposits and soil fractions near Balchug village is considered, the role of thin fraction in radionuclides accumulation is determined [ru

  17. Coal depositional models in some tertiary and cretaceous coal fields in the US western interior

    Energy Technology Data Exchange (ETDEWEB)

    Flores, R M

    1979-12-01

    Detailed stratigraphic and sedimentological studies of the Tertiary Tongue River Member of the Fort Union Formation in the Powder River Basin, Wyoming, and the Cretaceous Blackhawk Formation and Star Point Sandstone in the Wasatch Plateau, Utah, indicate that the depositional environments of coal played a major role in controlling coal thickness, lateral continuity, potential minability, and type of floor and roof rocks. The potentially minable, thick coal beds of the Tongue River Member were primarily formed in long-lived floodbasin backswamps of upper alluvial plain environment. Avulsion of meandering fluvial channels contributed to the erratic lateral extent of coals in this environment. Laterally extensive coals formed in floodbasin backswamps of a lower alluvial plain environment; however, interruption by overbank and crevasse-splay sedimentation produced highly split and merging coal beds. Lacustrine sedimentation common to the lower alluvial plain, similar to the lake-covered lower alluvial valley of the Atchafalaya River Basin, is related to a high-constructive delta. In contrast to these alluvial coals are the deltaic coal deposits of the Blackhawk Formation. The formation consists of three coal populations: upper delta plain, lower delta plain, and back-barrier. Coals of the lower delta plain are thick and laterally extensive, in contrast to those of the upper delta plain and back-barrier, which contain abundant, very thin and laterally discontinuous carbonaceous shale partings. The reworking of the delta-front sediments of the Star Point Sandstone suggests that the Blackhawk-Star Point delta was a high-destructive system. 1 figure, 1 table.

  18. Thorium prospect of placer deposits in Koba area and its surroundings

    International Nuclear Information System (INIS)

    Ngadenin; Fd Dian Indrastomo; Widodo

    2012-01-01

    The objective of the present study of the thorium in placer of Koba, Central Bangka District. Bangka Belitung Province and its surrounding is to find out thorium prospect in alluvial deposits. The study method are geological and radiometrical mapping, grain counting and thorium grade analysis of pan concentrated. Result of the research reveals that lithology of the investigation area compose of meta sandstone unit with radiometric value of 35 c/s - 200 c/s, granite intrusion with radiometric value of 140-550 c/s and alluvial with radiometric value of 40-300 c/s SPP2NF. Content of monazite in the pan concentrated is approximately 7.54 %, content of thorium in pan concentrated of 1410 ppm, covered alluvial deposits of about 400 kilometers square with average thickness 3.77 meters. According to the study thorium prospect in Koba area is feasible to be Based on the type of deposit (placer) which are relatively easy to be mined at low cost, high content of monazite and thorium so that the prospect thorium Koba feasible to develop. (author)

  19. Quantifying relief on alluvial fans using airborne lidar to reveal patterns of sediment accumulation

    Science.gov (United States)

    Morelan, A. E., III; Oskin, M. E.

    2017-12-01

    We present a method of quantifying detailed surface relief on alluvial fans from high-resolution topography. Average slope and curvature of the fan are used together to empirically derive an idealized, radially symmetric fan surface, from which we compute residual topography. Maps produced using this technique highlight spatial patterns of fan deposition and avulsion. Regions of high residual topography reveal active and abandoned sediment lobes accumulated from recent depositional events, often with well-defined channels at their apex. Preliminary observations suggest that surface relief is uniform across a collection of fans in a given region and source lithology. Alluvial fans with granitic catchment lithologies in eastern California (n=12), each with varying source catchment size and mean fan slope, all show relief of around 4 meters. A collection of fans from the Carrizo Plain in central California (n=12), with source catchments set within Miocene marine and nonmarine sedimentary rocks, show significantly lower relief values around 2 meters. We hypothesize that particle grain size determines this contrasting relief through its control on the thickness of fan-building debris flows. In both settings we find that sediment lobes tend to extend toward the fan toe. This pattern supports a process, observed in analog experiments, of fan deposition dominated by back-filling and overtopping of distributary channels by debris-flows.

  20. Morphodynamic simulation of sediment deposition patterns on a recently stripped bedrock anastomosed channel

    Directory of Open Access Journals (Sweden)

    D. Milan

    2018-04-01

    Full Text Available Some mixed bedrock-alluvial dryland rivers are known to undergo cycles of alluvial building during low flow periods, punctuated by stripping events during rare high magnitude flows. We focus on the Olifants River, Kruger National Park, South Africa, and present 2-D morphodynamic simulations of hydraulics and sediment deposition patterns over an exposed bedrock anastomosed pavement. We examine the assumptions underlying a previous conceptual model, namely that sedimentation occurs preferentially on bedrock highs. Our modelling results and local field observations in fact show that sediment thicknesses are greater over bedrock lows, suggesting these are the key loci for deposition, barform initiation and island building. During peak flows, velocities in the topographic lows tend to be lower than in intermediate topographic areas. It is likely that intermediate topographic areas supply sediment to the topographic lows at this flow stage, which is then deposited in the lows on the falling limb of the hydrograph as velocities reduce. Subsequent vegetation establishment on deposits in the topographic lows is likely to play a key role in additional sedimentation and vegetation succession, both through increasing the cohesive strength of alluvial units and by capturing new sediments and propagules.

  1. Morphodynamic simulation of sediment deposition patterns on a recently stripped bedrock anastomosed channel

    Science.gov (United States)

    Milan, David; Heritage, George; Entwistle, Neil; Tooth, Stephen

    2018-04-01

    Some mixed bedrock-alluvial dryland rivers are known to undergo cycles of alluvial building during low flow periods, punctuated by stripping events during rare high magnitude flows. We focus on the Olifants River, Kruger National Park, South Africa, and present 2-D morphodynamic simulations of hydraulics and sediment deposition patterns over an exposed bedrock anastomosed pavement. We examine the assumptions underlying a previous conceptual model, namely that sedimentation occurs preferentially on bedrock highs. Our modelling results and local field observations in fact show that sediment thicknesses are greater over bedrock lows, suggesting these are the key loci for deposition, barform initiation and island building. During peak flows, velocities in the topographic lows tend to be lower than in intermediate topographic areas. It is likely that intermediate topographic areas supply sediment to the topographic lows at this flow stage, which is then deposited in the lows on the falling limb of the hydrograph as velocities reduce. Subsequent vegetation establishment on deposits in the topographic lows is likely to play a key role in additional sedimentation and vegetation succession, both through increasing the cohesive strength of alluvial units and by capturing new sediments and propagules.

  2. Numerical simulation of sediment deposition thickness at Beidaihe International Yacht Club

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    Cheng-gang Lu

    2010-09-01

    Full Text Available The finite element method (FEM was used to simulate sediment hydrodynamics at the Beidaihe International Yacht Club, and a two-dimensional model was established. The sediment movement and deposition were analyzed under many tidal conditions in conjunction with the hydrological regime of the Daihe River. The peak value of the sediment deposition thickness appears in the main channel and around the estuary. The sediment deposition thickness is essentially constant and relatively small in the project area. The sediment deposition thickness in the main channel, in the yachting area, and around the hotel is greater than the other areas in the project. Regular excavation and dredging of the channel is the best measure for mitigating the sedimentation.

  3. Obtaining Thickness-Limited Electrospray Deposition for 3D Coating.

    Science.gov (United States)

    Lei, Lin; Kovacevich, Dylan A; Nitzsche, Michael P; Ryu, Jihyun; Al-Marzoki, Kutaiba; Rodriguez, Gabriela; Klein, Lisa C; Jitianu, Andrei; Singer, Jonathan P

    2018-04-04

    Electrospray processing utilizes the balance of electrostatic forces and surface tension within a charged spray to produce charged microdroplets with a narrow dispersion in size. In electrospray deposition, each droplet carries a small quantity of suspended material to a target substrate. Past electrospray deposition results fall into two major categories: (1) continuous spray of films onto conducting substrates and (2) spray of isolated droplets onto insulating substrates. A crossover regime, or a self-limited spray, has only been limitedly observed in the spray of insulating materials onto conductive substrates. In such sprays, a limiting thickness emerges, where the accumulation of charge repels further spray. In this study, we examined the parametric spray of several glassy polymers to both categorize past electrospray deposition results and uncover the critical parameters for thickness-limited sprays. The key parameters for determining the limiting thickness were (1) field strength and (2) spray temperature, related to (i) the necessary repulsive field and (ii) the ability for the deposited materials to swell in the carrier solvent vapor and redistribute charge. These control mechanisms can be applied to the uniform or controllably-varied microscale coating of complex three-dimensional objects.

  4. Topographic and hydraulic controls over alluviation on a bedrock template

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    Milan, David; Heritage, George; Entwistle, Neil; Tooth, Stephen

    2017-04-01

    Bedrock-alluvial anastomosed channels found in dryland rivers are characterised by an over-wide channel cut into the host rock containing a network of interconnecting bedrock sub-channels separated by bedrock influenced interfluve areas. Whilst the channels remain largely free of sediment the interfluves display varying levels of alluviation ranging from bare rock, sand sheets and silt drapes through to consolidated bedrock core bars, islands and lateral deposits. Examination of the sedimentary units associated with the bedrock anastomosed reaches of the Sabie river in the Kruger National Park, South Africa reveal a repeating sequence of coarse sand / fine gravel grading through to silt representing successive flood related depositional units. Unit development in relation to the bedrock template was investigated using pre-flood aerial imagery of bedrock core bar locations and post flood LiDAR data of bedrock anastomosed sites stripped during the 2000 and 2012 extreme flood events. This revealed a propensity for bar development associated with bedrock hollows disconnected from the principal high-energy sub-channels. 2-D morpho-dynamic modelling was used to further investigate spatial patterns of deposition over the bedrock template. Although topographic lows displayed mid-range velocities during peak flow events, these are likely to be preferential routing areas, with sediments stalling in low energy areas on the falling limb of floods. It is also likely that vegetation development plays a fundamental role in the development of alluviated zones, through increasing strength of alluvial units and capturing new sediments. With these results in mind we present a conceptual model for the development of bedrock-core bars, the fundamental unit in bedrock-alluvial anastomosed channels.

  5. Delineation of groundwater development potential zones in parts of marginal Ganga Alluvial Plain in South Bihar, Eastern India.

    Science.gov (United States)

    Saha, Dipankar; Dhar, Y R; Vittala, S S

    2010-06-01

    A part of the Gangetic Alluvial Plain covering 2,228 km(2), in the state of Bihar, is studied for demarcating groundwater development potential zones. The area is mainly agrarian and experiencing intensive groundwater draft to the tune of 0.12 million cubic metre per square kilometres per year from the Quaternary marginal alluvial deposits, unconformably overlain northerly sloping Precambrian bedrock. Multiparametric data on groundwater comprising water level, hydraulic gradient (pre- and post-monsoon), aquifer thickness, permeability, suitability of groundwater for drinking and irrigation and groundwater resources vs. draft are spatially analysed and integrated on a Geographical Information System platform to generate thematic layers. By integrating these layers, three zones have been delineated based on groundwater development potential. It is inferred that about 48% of the area covering northern part has high development potential, while medium and low development potential category covers 41% of the area. Further increase in groundwater extraction is not recommended for an area of 173 km(2), affected by over-exploitation. The replenishable groundwater resource available for further extraction has been estimated. The development potential enhances towards north with increase in thickness of sediments. Local deviations are due to variation of-(1) cumulative thickness of aquifers, (2) deeper water level resulting from localised heavy groundwater extraction and (3) aquifer permeability.

  6. Distribution of monazite in granite and alluvial of South Bangka

    International Nuclear Information System (INIS)

    Ngadenin

    2011-01-01

    Monazite is one source of thorium (Th), which has significant economic value and potential as an alternative fuel of nuclear power plants. The aims of research is to find out the distribution monazite alternative fuel of nuclear power plants. The aims of research is to find out the distribution monazite and its potential as a resource of radioactive minerals on the Bangka Island, then the data will be used and its potential as a resource of radioactive minerals on the Bangka Island, then the data will be used as a reference in the development of radioactive minerals exploration areas in the coming year. The research location is in the Bencah and Gadung villages, South Bangka Regency. The method used is the geological mapping, sampling of rock for petrographic, mineragraphic and autoradiographic analysis and heavy mineral for grains counting analysis. The results showed that lithologic area of Bencah Village composed of clay stone and alluvial deposits, while the Gadung Village composed by granite and alluvial deposits. Granite Gadung is predicted as the ilmenite series granite and tend to be of S type, while the material of Bencah alluvial is predicted come from the Klabat granite groups. In general, distribution of monazite in the alluvial slightly more potent of monazite than in the granite so that the development of radioactive minerals exploration will be prioritized in the alluvial areas. (author)

  7. 75 FR 62137 - Notice of Public Meeting; Proposed Alluvial Valley Floor Coal Exchange Public Interest Factors...

    Science.gov (United States)

    2010-10-07

    ... exchange Federal coal deposits for Alluvial Valley Floor (AVF) fee coal pursuant to the Federal Land Policy...; MTM-99236] Notice of Public Meeting; Proposed Alluvial Valley Floor Coal Exchange Public Interest... Alluvial Valley Floor Environmental Assessment can be viewed on the BLM's Miles City Field Office Web page...

  8. Alluvial aquifers in the Mzingwane catchment: Their distribution, properties, current usage and potential expansion

    Science.gov (United States)

    Moyce, William; Mangeya, Pride; Owen, Richard; Love, David

    The Mzingwane River is a sand filled channel, with extensive alluvial aquifers distributed along its banks and bed in the lower catchment. LandSat TM imagery was used to identify alluvial deposits for potential groundwater resources for irrigation development. On the false colour composite band 3, band 4 and band 5 (FCC 345) the alluvial deposits stand out as white and dense actively growing vegetation stands out as green making it possible to mark out the lateral extent of the saturated alluvial plain deposits using the riverine fringe and vegetation . The alluvial aquifers form ribbon shaped aquifers extending along the channel and reaching over 20 km in length in some localities and are enhanced at lithological boundaries. These alluvial aquifers extend laterally outside the active channel, and individual alluvial aquifers have been measured with area ranging from 45 ha to 723 ha in the channels and 75 ha to 2196 ha on the plains. The alluvial aquifers are more pronounced in the Lower Mzingwane, where the slopes are gentler and allow for more sediment accumulation. Estimated water resources potential ranges between 175,000 m 3 and 5,430,000 m 3 in the channels and between 80,000 m 3 and 6,920,000 m 3 in the plains. Such a water resource potential can support irrigation ranging from 18 ha to 543 ha for channels alluvial aquifers and 8 ha to 692 ha for plain alluvial aquifers. Currently, some of these aquifers are being used to provide water for domestic use, livestock watering and dip tanks, commercial irrigation and market gardening. The water quality of the aquifers in general is fairly good due to regular recharge and flushing out of the aquifers by annual river flows and floodwater. Water salinity was found to increase significantly in the end of the dry season, and this effect was more pronounced in water abstracted from wells on the alluvial plains. During drought years, recharge is expected to be less and if the drought is extended water levels in the

  9. Diagenesis of Permian alluvial fan deposits of Northern Switzerland

    International Nuclear Information System (INIS)

    Bluem, W.

    1987-01-01

    Fine-grained sandstones of Permian alluvial fan deposits from three Nagra boreholes (Weiach, Riniken, Kaisten) and an exploration well, drilled at Wintersingen are clast supported, moderately sorted arkosic greywackes containing typically 2-20 % clayey matrix. Petrographic studies indicate that the origin of this clayey matrix is postdepositional. Mechanical infiltration of fines and diagenetic reddening of detrital and authigenic iron oxides are the earliest recorded events. Additionally, nodular calcites of calcrete origin and fibrous illitic clays are also ascribed to the eogenetic environment. The present strong compaction fabric results from general lack of eogenetic framework supporting cements. During mesogenesis, secondary porosity was generated through partial removal of early calcite. At the same time, a first generation of syntaxial quartz cementation and a subsequent fibrous illite authigenesis took place. Leaching of detrital K-feldspars post-dating compaction is recorded throughout the studied boreholes. The following burial diagenetic events differ between the various boreholes: in Weiach and Wintersingen kaolinite, illite, prismatic quartz and ankerite/siderite are recorded; in Riniken K-feldspar, illite, prismatic quartz and dolomite developed; whilst in Kaisten K-feldspar and microcrystalline quartz-cement dominate. These differences reflect the chemistry, pH and ionic strength of the pore fluids. Filling of veins by dolomite/ankerite, iron-rich and subsequent iron-poor calcite is the latest recorded event. (author) 21 refs., 10 figs., 1 tab

  10. Alluvial architecture of the Holocene Rhine-Meuse delta (The Netherlands) and the Lower Mississippi Valley (U.S.A.)

    NARCIS (Netherlands)

    Gouw, M.J.P.

    2007-01-01

    Alluvial architecture describes the geometry, proportion, and spatial distribution of different types of fluvial deposits in an alluvial succession. Alluvial architecture is frequently subject of study, because natural resources commonly occur in ancient fluvial sequences. The ability of models to

  11. Alluvial architecture of the Holocene Rhine-Meuse delta (The Netherlands) and the Lower Mississippi Valley (U.S.A.)

    OpenAIRE

    Gouw, M.J.P.

    2007-01-01

    Alluvial architecture describes the geometry, proportion, and spatial distribution of different types of fluvial deposits in an alluvial succession. Alluvial architecture is frequently subject of study, because natural resources commonly occur in ancient fluvial sequences. The ability of models to simulate alluvial architecture realistically is largely unknown due to a lack of natural data to test the models. Generating high-resolution datasets describing alluvial architecture of natural fluv...

  12. Deposition and early hydrologic evolution of Westwater Canyon wet alluvial-fan system

    International Nuclear Information System (INIS)

    Galloway, W.E.

    1980-01-01

    The Westwater Canyon Member is one of several large, low-gradient alluvial fans that compose the Morrison Formation in the Four Corners area. Morrison fans were deposited by major laterally migrating streams entering a broad basin bounded by highlands to the west and south. The Westwater Canyon sand framework consists of a downfan succession of 1) proximal braided channel, 2) straight bed-load channel, 3) sinuous mixed-load channel, and 4) distributary mixed-load-channel sand bodies. Regional sand distribution and facies patterns are highly digitate and radiate from a point source located northwest of Gallup, New Mexico. Early ground-water flow evolution within the Westwater Canyon fan aquifer system can be inferred by analogy with Quaternary wet-fan deposits and by the interpreted paragenetic sequence of diagenetic features present. Syndepositional flow was controlled by the downfan hydrodynamic gradient and the high horizontal and vertical transmissivity of the sand-rich fan aquifer. Dissolution and transport of soluble humate would be likely in earliest ground water, which was abundant, fresh, and slightly alkaline. With increasing confinement of the aquifer below less permeable tuffaceous Brushy Basin deposits and release of soluble constituents from volcanic ash, flow patterns stabilized, and relatively more saline, uranium-rich ground water permeated the aquifer. Uranium mineralization occurred during this early postdepositional, semiconfined flow phase. Development of overlying Dakota swamps suggests a shallow water table indicative of regional dischare or stagnation. In either event, only limited downward flux of acidic water is recorded by local, bleached, kaolinized zones where the Westwater Canyon directly underlies the Dakota swamps. Subsequent ground-water flow phases have further obscured primary alteration patterns and caused local oxidation and redistribution of uranium

  13. Fault-sourced alluvial fans and their interaction with axial fluvial drainage: An example from the Plio-Pleistocene Upper Valdarno Basin (Tuscany, Italy)

    Science.gov (United States)

    Fidolini, Francesco; Ghinassi, Massimiliano; Aldinucci, Mauro; Billi, Paolo; Boaga, Jacopo; Deiana, Rita; Brivio, Lara

    2013-05-01

    The present study deals with the fault-sourced, alluvial-fan deposits of the Plio-Pleistocene Upper Valdarno Basin (Northern Apennines, Italy). Different phases of alluvial fan aggradation, progradation and backstep are discussed as possible effects of the interaction among fault-generated accommodation space, sediment supply and discharge variations affecting the axial fluvial drainage. The Upper Valdarno Basin, located about 35 km SE of Florence, is filled with 550 m palustrine, lacustrine and alluvial deposits forming four main unconformity-bounded units (i.e. synthems). The study alluvial-fan deposits belong to the two uppermost synthems (Montevarchi and Torrente Ciuffenna synthems) and are Early to Middle Pleistocene in age. These deposits are sourced from the fault-bounded, NE margin of the basin and interfinger with axial fluvial deposits. Alluvial fan deposits of the Montevarchi Synthem consist of three main intervals: i) a lower interval, which lacks any evidence of a depositional trend and testify balance between the subsidence rate (i.e. fault activity) and the amount of sediment provided from the margin; ii) a coarsening-upward middle interval, pointing to a decrease in subsidence rate associated with an augment in sediment supply; iii) a fining-upward, upper interval (locally preserved), documenting a phase of tectonic quiescence associated with a progressive re-equilibration of the tectonically-induced morphological profile. The basin-scale unconformity, which separates the Montevarchi and Torrente Ciuffenna synthems was due to the entrance of the Arno River into the basin as consequence of a piracy. This event caused a dramatic increase in water discharge of the axial fluvial system, and its consequent embanking. Such an erosional surface started to develop in the axial areas, and propagated along the main tributaries, triggering erosion of the alluvial fan deposits. Alluvial-fan deposits of the Torrente Ciuffenna Synthem accumulated above the

  14. 30 CFR 785.19 - Surface coal mining and reclamation operations on areas or adjacent to areas including alluvial...

    Science.gov (United States)

    2010-07-01

    ... alluvial valley floor exists if it finds that— (i) Unconsolidated streamlaid deposits holding streams are... on areas or adjacent to areas including alluvial valley floors in the arid and semiarid areas west of....19 Surface coal mining and reclamation operations on areas or adjacent to areas including alluvial...

  15. Case studies of groundwater- surface water interactions and scale relationships in small alluvial aquifers

    NARCIS (Netherlands)

    Love, Dave; de Hamer, Wouter; Owen, Richard J.S.; Booij, Martijn J.; Uhlenbrook, Stefan; Hoekstra, Arjen Ysbert; van der Zaag, Pieter

    2007-01-01

    An alluvial aquifer can be described as a groundwater system, generally unconfined, that is hosted in laterally discontinuous layers of gravel, sand, silt and clay, deposited by a river in a river channel, banks or flood plain. In semi-arid regions, streams that are associated with alluvial aquifers

  16. Measuring Paleolandscape Relief in Alluvial River Systems from the Stratigraphic Record

    Science.gov (United States)

    Hajek, E. A.; Trampush, S. M.; Chamberlin, E.; Greenberg, E.

    2017-12-01

    Aggradational alluvial river systems sometimes generate relief in the vicinity of their channel belts (i.e. alluvial ridges) and it has been proposed that this process may define important thresholds in river avulsion. The compensation scale can be used to estimate the maximum relief across a landscape and can be connected to the maximum scale of autogenic organization in experimental and numerical systems. Here we use the compensation scale - measured from outcrops of Upper Cretaceous and Paleogene fluvial deposits - to estimate the maximum relief that characterized ancient fluvial landscapes. In some cases, the compensation scale significantly exceeds the maximum channel depth observed in a deposit, suggesting that aggradational alluvial systems organize to sustain more relief than might be expected by looking only in the immediate vicinity of the active channel belt. Instead, these results indicate that in some systems, positive topographic relief generated by multiple alluvial ridge complexes and/or large-scale fan features may be associated with landscape-scale autogenic organization of channel networks that spans multiple cycles of channel avulsion. We compare channel and floodplain sedimentation patterns among the studied ancient fluvial systems in an effort to determine whether avulsion style, channel migration, or floodplain conditions influenced the maximum autogenic relief of ancient landscapes. Our results emphasize that alluvial channel networks may be organized at much larger spatial and temporal scales than previously realized and provide an avenue for understanding which types of river systems are likely to exhibit the largest range of autogenic dynamics.

  17. Field, Laboratory and Imaging spectroscopic Analysis of Landslide, Debris Flow and Flood Hazards in Lacustrine, Aeolian and Alluvial Fan Deposits Surrounding the Salton Sea, Southern California

    Science.gov (United States)

    Hubbard, B. E.; Hooper, D. M.; Mars, J. C.

    2015-12-01

    High resolution satellite imagery, field spectral measurements using a portable ASD spectrometer, and 2013 hyperspectral AVIRIS imagery were used to evaluate the age of the Martinez Mountain Landslide (MML) near the Salton Sea, in order to determine the relative ages of adjacent alluvial fan surfaces and the potential for additional landslides, debris flows, and floods. The Salton Sea (SS) occupies a pluvial lake basin, with ancient shorelines ranging from 81 meters to 113 meters above the modern lake level. The highest shoreline overlaps the toe of the 0.24 - 0.38 km3 MML deposit derived from hydrothermally altered granites exposed near the summit of Martinez Mountain. The MML was originally believed to be of early Holocene age. However, AVIRIS mineral maps show abundant desert varnish on the top and toe of the landslide. Desert varnish can provide a means of relative dating of alluvial fan (AF) or landslide surfaces, as it accumulates at determinable rates over time. Based on the 1) highest levels of desert varnish accumulation mapped within the basin, 2) abundant evaporite playa minerals on top of the toe of the landslide, and 3) the highest shoreline of the ancestral lake overtopping the toe of the landslide with gastropod and bivalve shells, we conclude that the MML predates the oldest alluvial fan terraces and lake sediments exposed in the Coachella and Imperial valleys and must be older than early Holocene (i.e. Late Pleistocene?). Thus, the MML landslide has the potential to be used as a spectral endmember for desert varnish thickness and thus proxy for age discrimination of active AF washes versus desert pavements. Given the older age of the MML landslide and low water levels in the modern SS, the risk from future rockslides of this size and related seiches is rather low. However, catastrophic floods and debris flows do occur along the most active AF channels; and the aftermath of such flows can be identified spectrally by montmorillonite crusts forming in

  18. Clogging of water supply wells in alluvial aquifers by mineral incrustations, central Serbia

    Directory of Open Access Journals (Sweden)

    Majkić-Dursun Brankica

    2015-01-01

    Full Text Available The formation of incrustations on public water supply well screens reduces their performance considerably. The incrustations increase hydraulic losses, reduce the capacity of the well and screen, affect the quality of the pumped water and increase maintenance costs. In alluvial environments, the most common deposits are iron and manganese hydroxides. However, the rates of formation, compositions and levels of crystallization vary, depending on the geochemical characteristics of the alluvial environment, the microbiological characteristics of the groundwater and the abstraction method. Samples of 15 incrustations were collected from wells that tap shallow alluvial aquifers and were found to be dominated by iron. XRD analyses detected low-crystalline ferrihydrite and manganese hydroxide in the samples collected from the water supply source at Trnovče (Velika Morava alluvial. The incrustations from the Belgrade Groundwater Source revealed the presence of ferrihydrite and a substantial amount of goethite α-FeOOH. Apart from goethite, greigite (Fe3S4 was detected in three samples, while one sample additionally contained bernalite Fe(OH3 and monoclinic sulfur S8. Among carbonates, only siderite was detected. Iron oxidizing bacteria generally catalyze deposition processes in wells, while sulfate reducing bacteria (SRB play a role in the biogenic formation of greigite. Determining the nature of the deposited material allows better selection of rehabilitation chemicals and procedure. [Projekat Ministarstva nauke Republike Srbije, br. TR37014

  19. Geohydrologic units and water-level conditions in the Terrace alluvial aquifer and Paluxy Aquifer, May 1993 and February 1994, near Air Force Plant 4, Fort Worth area, Texas

    Science.gov (United States)

    Rivers, Glen A.; Baker, Ernest T.; Coplin, L.S.

    1996-01-01

    The terrace alluvial aquifer underlying Air Force Plant 4 and the adjacent Naval Air Station (formerly Carswell Air Force Base) in the Fort Worth area, Texas, is contaminated locally with organic and metal compounds. Residents south and west of Air Force Plant 4 and the Naval Air Station are concerned that contaminants might enter the underlying Paluxy aquifer, which provides water to the city of White Settlement, south of Air Force Plant 4, and to residents west of Air Force Plant 4. The U.S. Environmental Protection Agency has qualified Air Force Plant 4 for Superfund cleanup. The pertinent geologic units include -A~rom oldest to youngest the Glen Rose, Paluxy, and Walnut Formations, Goodland Limestone, and terrace alluvial deposits. Except for the Glen Rose Formation, all units crop out at or near Air Force Plant 4 and the Naval Air Station. The terrace alluvial deposits, which nearly everywhere form the land surface, range from 0 to about 60 feet thick. These deposits comprise a mostly unconsolidated mixture of gravel, sand, silt, and clay. Mudstone and sandstone of the Paluxy Formation crop out north, west, and southwest of Lake Worth and total between about 130 and about 175 feet thick. The terrace alluvial deposits and the Paluxy Formation comprise the terrace alluvial aquifer and the Paluxy aquifer, respectively. These aquifers are separated by the Goodland-Walnut confining unit, composed of the Goodland Limestone and (or) Walnut Formation. Below the Paluxy aquifer, the Glen Rose Formation forms the Glen Rose confining unit. Water-level measurements during May 1993 and February 1994 from wells in the terrace alluvial aquifer indicate that, regionally, ground water flows toward the east-southeast beneath Air Force Plant 4 and the Naval Air Station. Locally, water appears to flow outward from ground-water mounds maintained by the localized infiltration of precipitation and reportedly by leaking water pipes and sanitary and (or) storm sewer lines beneath the

  20. Terrestrial Cosmogenic-Nuclide Dating of Alluvial Fans in Death Valley, California

    Science.gov (United States)

    Machette, Michael N.; Slate, Janet L.; Phillips, Fred M.

    2008-01-01

    We have used terrestrial cosmogenic nuclides (TCN) to establish the age of some of the most extensive Quaternary alluvial fans in Death Valley, California. These intermediate-age alluvial fans are most extensive on the western side of the valley, where tectonic deformation is considerably less pronounced than on the eastern side of the valley. These fans are characterized by a relatively smooth, densely packed desert pavement formed by well-varnished (blackened) clasts. These surfaces have been mapped as the Q2 gravel by previous workers and as unit Qai (intermediate age) by us. However, the intermediate-age gravels probably contain multiple subunits, as evidenced by slight differences in morphologic expression, soil formation, and inset geomorphic relations. The TCN technique used herein sums the cosmogenic 36Cl in approximately 2.5-meter-deep profiles through soil and host alluvium, thus avoiding some of the problems associated with the more typical surface-exposure dating of boulders or smaller clasts. Our TCN 36Cl dating of 12 depth profiles indicates that these intermediate-age (Qai) alluvial fans range from about 100 to 40 kilo-annum (ka), with a mean age of about 70 ka. An alternative interpretation is that alluvial unit Qai was deposited in two discrete episodes from 90 to 80 ka and from 60 to 50 ka, before and after MIS (marine oxygen-isotope stage) 4 (respectively). Without an intermediate-age unit, such as MIS 4 lake deposits, we can neither disprove nor prove that Qai was deposited in two discrete intervals or over a longer range of time. Thus, in Death Valley, alluvial unit Qai largely brackets MIS 4, which is not associated with a deep phase of Lake Manly. These Qai fans extend to elevations of about -46 meters (150 feet below sea level) and have not been transgressed by Lake Manly, suggesting that MIS 4 or MIS 2 lakes were rather shallow in Death Valley, perhaps because they lacked inflow from surface runoff of the Sierra Nevada drainages through

  1. Interaction of fine sediment with alluvial streambeds

    Science.gov (United States)

    Jobson, Harvey E.; Carey, William P.

    1989-01-01

    More knowledge is needed about the physical processes that control the transport of fine sediment moving over an alluvial bed. The knowledge is needed to design rational sampling and monitoring programs that assess the transport and fate of toxic substances in surface waters because the toxics are often associated with silt- and clay-sized particles. This technical note reviews some of the past research in areas that may contribute to an increased understanding of the processes involved. An alluvial streambed can have a large capacity to store fine sediments that are extracted from the flow when instream concentrations are high and it can gradually release fine sediment to the flow when the instream concentrations are low. Several types of storage mechanisms are available depending on the relative size distribution of the suspended load and bed material, as well as the flow hydraulics. Alluvial flow tends to segregate the deposited material according to size and density. Some of the storage locations are temporary, but some can store the fine sediment for very long periods of time.

  2. Alluvial Aquifer

    Data.gov (United States)

    Kansas Data Access and Support Center — This coverage shows the extents of the alluvial aquifers in Kansas. The alluvial aquifers consist of unconsolidated Quaternary alluvium and contiguous terrace...

  3. Persistence of exponential bed thickness distributions in the stratigraphic record: Experiments and theory

    Science.gov (United States)

    Straub, K. M.; Ganti, V. K.; Paola, C.; Foufoula-Georgiou, E.

    2010-12-01

    Stratigraphy preserved in alluvial basins houses the most complete record of information necessary to reconstruct past environmental conditions. Indeed, the character of the sedimentary record is inextricably related to the surface processes that formed it. In this presentation we explore how the signals of surface processes are recorded in stratigraphy through the use of physical and numerical experiments. We focus on linking surface processes to stratigraphy in 1D by quantifying the probability distributions of processes that govern the evolution of depositional systems to the probability distribution of preserved bed thicknesses. In this study we define a bed as a package of sediment bounded above and below by erosional surfaces. In a companion presentation we document heavy-tailed statistics of erosion and deposition from high-resolution temporal elevation data recorded during a controlled physical experiment. However, the heavy tails in the magnitudes of erosional and depositional events are not preserved in the experimental stratigraphy. Similar to many bed thickness distributions reported in field studies we find that an exponential distribution adequately describes the thicknesses of beds preserved in our experiment. We explore the generation of exponential bed thickness distributions from heavy-tailed surface statistics using 1D numerical models. These models indicate that when the full distribution of elevation fluctuations (both erosional and depositional events) is symmetrical, the resulting distribution of bed thicknesses is exponential in form. Finally, we illustrate that a predictable relationship exists between the coefficient of variation of surface elevation fluctuations and the scale-parameter of the resulting exponential distribution of bed thicknesses.

  4. Outlook for Mississippi Alluvial Valley forests: a subregional report from the Southern Forest Futures Project

    Science.gov (United States)

    Emile S. Gardiner

    2015-01-01

    The Mississippi Alluvial Valley, which can be broadly subdivided into the Holocene Deposits section and the Deltaic Plain section, is a 24.9-million-acre area generally approximating the alluvial floodplain and delta of the lower Mississippi River. Its robust agricultural economy is maintained by a largely rural population, and recreational resources draw high...

  5. State of the art in thin film thickness and deposition rate monitoring sensors

    International Nuclear Information System (INIS)

    Buzea, Cristina; Robbie, Kevin

    2005-01-01

    In situ monitoring parameters are indispensable for thin film fabrication. Among them, thickness and deposition rate control are often the most important in achieving the reproducibility necessary for technological exploitation of physical phenomena dependent on film microstructure. This review describes the types of thickness and deposition rate sensors and their theoretical and phenomenological background, underlining their performances, as well as advantages and disadvantages

  6. Thickness control in electrophoretic deposition of WO3 nanofiber thin films for solar water splitting

    International Nuclear Information System (INIS)

    Fang, Yuanxing; Lee, Wei Cheat; Canciani, Giacomo E.; Draper, Thomas C.; Al-Bawi, Zainab F.; Bedi, Jasbir S.; Perry, Christopher C.; Chen, Qiao

    2015-01-01

    Graphical abstract: - Highlights: • A novel method combining electrospinning and electrophoretic deposition was established for the creation of nanostructured semiconductor thin films. • The created thin films displayed a high chemical stability with a controllable thickness. • The PEC water splitting performance of the thin films was optimized by fine-tuning the thickness of the films. • A maximum photoconversion efficiency was achieved by 18 μm nanofibrous thin films. - Abstract: Electrophoretic deposition (EPD) of ground electrospun WO 3 nanofibers was applied to create photoanodes with controlled morphology for the application of photoelectrochemical (PEC) water splitting. The correlations between deposition parameters and film thicknesses were investigated with theoretical models to precisely control the morphology of the nanostructured porous thin film. The photoconversion efficiency was further optimized as a function of film thickness. A maximum photoconversion efficiency of 0.924% from electrospun WO 3 nanofibers that EPD deposited on a substrate was achieved at a film thickness of 18 μm.

  7. Experiment study on the thick GEM-like multiplier for X-ray photoelectrons energy deposition gaining

    International Nuclear Information System (INIS)

    Zhu Pengfei; Ye Yan; Long Yan; Cao Ningxiang; Jia Xing; Li Jianfeng

    2009-01-01

    The GEM is a novel detector with high gain,high time and location resolution. Imitating the structure of the GEM, a thick GEM-like multiplier which has the similar function with that of the GEM is designed and manufactured. The characteristics of the thick GEM-like multiplier increasing electron energy deposition in absorbing medium has been experimentally studied. The results indicate that the energy deposition gain of x-ray photoelectron in medium is apparent, and the maximum energy deposition can increase by more than 40%. Some suggestions of further increasing the energy deposition are given, and the future application of the way of increasing the x-ray photoelectron energy deposition by the thick GEM-like multiplier in hard x-ray imaging is prospected. (authors)

  8. Thickness of surficial sediment at and near the Idaho National Engineering Laboratory, Idaho

    International Nuclear Information System (INIS)

    Anderson, S.R.; Liszewski, M.J.; Ackerman, D.J.

    1996-06-01

    Thickness of surficial sediment was determined from natural-gamma logs in 333 wells at and near the Idaho National Engineering Laboratory in eastern Idaho to provide reconnaissance data for future site-characterization studies. Surficial sediment, which is defined as the unconsolidated clay, silt, sand, and gravel that overlie the uppermost basalt flow at each well, ranges in thickness from 0 feet in seven wells drilled through basalt outcrops east of the Idaho Chemical Processing Plant to 313 feet in well Site 14 southeast of the Big Lost River sinks. Surficial sediment includes alluvial, lacustrine, eolian, and colluvial deposits that generally accumulated during the past 200 thousand years. Additional thickness data, not included in this report, are available from numerous auger holes and foundation borings at and near most facilities

  9. Analysis and assessment on heavy metal sources in the coastal soils developed from alluvial deposits using multivariate statistical methods.

    Science.gov (United States)

    Li, Jinling; He, Ming; Han, Wei; Gu, Yifan

    2009-05-30

    An investigation on heavy metal sources, i.e., Cu, Zn, Ni, Pb, Cr, and Cd in the coastal soils of Shanghai, China, was conducted using multivariate statistical methods (principal component analysis, clustering analysis, and correlation analysis). All the results of the multivariate analysis showed that: (i) Cu, Ni, Pb, and Cd had anthropogenic sources (e.g., overuse of chemical fertilizers and pesticides, industrial and municipal discharges, animal wastes, sewage irrigation, etc.); (ii) Zn and Cr were associated with parent materials and therefore had natural sources (e.g., the weathering process of parent materials and subsequent pedo-genesis due to the alluvial deposits). The effect of heavy metals in the soils was greatly affected by soil formation, atmospheric deposition, and human activities. These findings provided essential information on the possible sources of heavy metals, which would contribute to the monitoring and assessment process of agricultural soils in worldwide regions.

  10. Vapor deposition on doublet airfoil substrates: Control of coating thickness and microstructure

    Energy Technology Data Exchange (ETDEWEB)

    Rodgers, Theron M.; Zhao, Hengbei; Wadley, Haydn N. G., E-mail: haydn@virginia.edu [Department of Materials Science and Engineering, University of Virginia, 395 McCormick Rd., P.O. Box 400745, Charlottesville, Virginia 22904 (United States)

    2015-11-15

    Gas jet assisted vapor deposition processes for depositing coatings are conducted at higher pressures than conventional physical vapor deposition methods, and have shown promise for coating complex shaped substrates including those with non-line-of-sight (NLS) regions on their surface. These regions typically receive vapor atoms at a lower rate and with a wider incident angular distribution than substrate regions in line-of-sight (LS) of the vapor source. To investigate the coating of such substrates, the thickness and microstructure variation along the inner (curved) surfaces of a model doublet airfoil containing both LS and NLS regions has been investigated. Results from atomistic simulations and experiments confirm that the coating's thickness is thinner in flux-shadowed regions than in other regions for all the coating processes investigated. They also indicated that the coatings columnar microstructure and pore volume fraction vary with surface location through the LS to NLS transition zone. A substrate rotation strategy for optimizing the thickness over the entire doublet airfoil surface was investigated, and led to the identification of a process that resulted in only small variation of coating thickness, columnar growth angle, and pore volume fraction on all doublet airfoil surfaces.

  11. The “Alluvial Mesovoid Shallow Substratum”, a New Subterranean Habitat

    Science.gov (United States)

    Ortuño, Vicente M.; Gilgado, José D.; Jiménez-Valverde, Alberto; Sendra, Alberto; Pérez-Suárez, Gonzalo; Herrero-Borgoñón, Juan J.

    2013-01-01

    In this paper we describe a new type of subterranean habitat associated with dry watercourses in the Eastern Iberian Peninsula, the “Alluvial Mesovoid Shallow Substratum” (alluvial MSS). Historical observations and data from field sampling specially designed to study MSS fauna in the streambeds of temporary watercourses support the description of this new habitat. To conduct the sampling, 16 subterranean sampling devices were placed in a region of Eastern Spain. The traps were operated for 12 months and temperature and relative humidity data were recorded to characterise the habitat. A large number of species was captured, many of which belonged to the arthropod group, with marked hygrophilous, geophilic, lucifugous and mesothermal habits. In addition, there was also a substantial number of species showing markedly ripicolous traits. The results confirm that the network of spaces which forms in alluvial deposits of temporary watercourses merits the category of habitat, and here we propose the name of “alluvial MSS”. The “alluvial MSS” may be covered or not by a layer of soil, is extremely damp, provides a buffer against above ground temperatures and is aphotic. In addition, compared to other types of MSS, it is a very unstable habitat. It is possible that the “alluvial MSS” may be found in other areas of the world with strongly seasonal climatic regimes, and could play an important role as a biogeographic corridor and as a refuge from climatic changes. PMID:24124544

  12. Preliminary results of chronostratigraphic field work, OSL-dating and morphogenetic reconstruction of an alluvial apron at Alborz southern foothill, Damghan basin, Iran

    Science.gov (United States)

    Büdel, Christian; Fuchs, Markus; Majid Padashi, Seyed; Baumhauer, Roland

    2014-05-01

    Here we present preliminary results of a chronostratigraphic study of an alluvial fan in the Damghan Basin, northern Iran. The basin sediments date back to the Mio- and Pliocene and therefore represent the starting point of alluvial fan aggradation. Today, the still active alluvial fans prograde from the Albors Mountain ranges and sit on the older sediment bodies. In this study, our focus is on the late Pleistocene to Holocene alluvial fan sedimentation history. The upper stratigraphy of the alluvial fans and intercalated lake deposits is characterized by six individual layers of gravels and fines, representing six different stratigraphic units. These units are described and classified by detailed geomorphological and stratigraphic mapping. To establish an alluvial fan chronology, six profiles were sampled for OSL dating. As expected, due to the high-energy transport system of alluvial fan aggradation in semi-desert environments, OSL dating of these sediments is challenging due to the problem of insufficient bleaching. Consequently, most of the samples are interpreted as maximum ages. However, the measurements show a consistent internal age structure and the overall OSL-based chronology is in agreement with the age model derived from our geomorphological analysis. As a first interpretation, based on surveyed geomorphological features and chronological analysis, we could identify seven morphodynamic phases, leading to a genetic model of alluvial fan aggradation. The oldest Pleistocene age estimate is derived from a former lake terrace. The following ages represent ongoing lake sediment deposition and the development of a proximal and mid-fan gravel cover. After the youngest lake deposits were accumulated within the Holocene, the lake starts to retreat and small alluvial fans are filling up the former lake bottom. This last sedimentation phase can be divided in at least two sub-phases, probably coupled to a lateral shifting of the active depositional lobe and to the

  13. Sedimentological analysis of the Estefaniense de Tineo basin (Asturias): example of coal deposits in alluvial fans. Analisis sedimentologico de la cuenca Estefaniense de Tineo (Asturias): ejemplo de depositos de carbon en abanicos aluviales

    Energy Technology Data Exchange (ETDEWEB)

    Santos Garcia, J.A. (Empresa Nacional ADARO, Madrid (Spain))

    1991-01-01

    A sedimentological analysis of the Stephanian deposits of Tineo Basin is carried out. Three unities are established (Basal Breachs, Intermediate Unit and Conglomerate Unit) by means of lithological, mining and sedimentological criteria, which represent larger episodes in the filling of the basin. The first episode corresponds to the initial configuration of the basin, with coarse grained breccia deposits related to steep slopes (Basal Breccia). The second and more complex (Intermediate Unit), is represented by four larger sequences (stages from UI-1 to UI-4, La Prohida Zone) which show secondary tectonic pulsations. At this moment the sedimentation is carried out in several subbasins separated by palaeoreliefs or thresholds. The third episode corresponds to a strong reactivation of the northern edge of the basin, with deposition of the Conglomeratic Unit. The filling of the basin is assimilated to a pattern of alluvial fans in a tectonically-active basin, in which the coal deposition look place during calm (tranquil) periods when a large alluvial fan flanked by coalescent smaller sized fans developed along the northern margin of the basin. 24 refs., 9 figs.

  14. Controls on alluvial fans morphology

    Science.gov (United States)

    Delorme, P.; Devauchelle, O.; Lajeunesse, E.; Barrier, L.; Métivier, F.

    2017-12-01

    Using laboratory experiments, we investigate the influence of water and sediment discharges on the morphology of an alluvial fan. In our flume, a single-thread laminar river deposits corundum sand (0.4 mm) into a conical fan. We record the fan progradation with top-view images, and measure its shape using the deformation of a Moiré pattern. The fan remains virtually self-affine as it grows, with a nearly constant slope. We find that, when the sediment discharge is small, the longitudinal slope of the fan remains close to that of a river at the threshold for sediment transport. A higher sediment discharge causes the fan's slope to depart from the threshold value. Due to the downstream decrease of the sediment load, this slope gets shallower towards the fan's toe. This mechanism generates a slightly concave fan profile. This suggests that the proximal slope of an alluvial fan could be a proxy for the sediment flux that feeds the fan.Finally, we discuss the applicability of these results to natural systems.

  15. Liquefaction analysis of alluvial soil deposits in Bedsa south west of Cairo

    Directory of Open Access Journals (Sweden)

    Kamal Mohamed Hafez Ismail Ibrahim

    2014-09-01

    Full Text Available Bedsa is one of the districts in Dahshour that lays south west of Cairo and suffered from liquefaction during October 1992 earthquake, Egypt. The soil profile consists of alluvial river Nile deposits mainly sandy mud with low plasticity; the ground water is shallow. The earthquake hypocenter was 18 km far away with local magnitude 5.8; the fault length was 13.8 km, as recorded by the Egyptian national seismological network (ENSN at Helwan. The analysis used the empirical method introduced by the national center for earthquake engineering research (NCEER based on field standard penetration of soil. It is found that the studied area can liquefy since there are saturated loose sandy silt layers at depth ranges from 7 to 14 m. The settlement is about 26 cm. The probability of liquefaction ranges between 40% and 100%. The presence of impermeable surface from medium cohesive silty clay acts as a plug resisting and trapping the upward flow of water during liquefaction, so fountain and spouts at weak points occurs. It is wise to use point bearing piles with foundation level deeper than 14 m beyond the liquefiable depth away from ground slopes, otherwise liquefaction improving techniques have to be applied in the area.

  16. Thickness control in electrophoretic deposition of WO{sub 3} nanofiber thin films for solar water splitting

    Energy Technology Data Exchange (ETDEWEB)

    Fang, Yuanxing; Lee, Wei Cheat; Canciani, Giacomo E.; Draper, Thomas C.; Al-Bawi, Zainab F. [Department of Chemistry, School of Life Sciences, University of Sussex, Brighton BN1 9QJ (United Kingdom); Bedi, Jasbir S. [School of Public Health & Zoonoses, Guru Angad Dev Veterinary and Animal Sciences University, Ludhiana 141004 Punjab (India); Perry, Christopher C. [Division of Biochemistry, School of Medicine, Loma Linda University, Loma Linda, CA 92350 (United States); Chen, Qiao, E-mail: qiao.chen@sussex.ac.uk [Department of Chemistry, School of Life Sciences, University of Sussex, Brighton BN1 9QJ (United Kingdom)

    2015-12-15

    Graphical abstract: - Highlights: • A novel method combining electrospinning and electrophoretic deposition was established for the creation of nanostructured semiconductor thin films. • The created thin films displayed a high chemical stability with a controllable thickness. • The PEC water splitting performance of the thin films was optimized by fine-tuning the thickness of the films. • A maximum photoconversion efficiency was achieved by 18 μm nanofibrous thin films. - Abstract: Electrophoretic deposition (EPD) of ground electrospun WO{sub 3} nanofibers was applied to create photoanodes with controlled morphology for the application of photoelectrochemical (PEC) water splitting. The correlations between deposition parameters and film thicknesses were investigated with theoretical models to precisely control the morphology of the nanostructured porous thin film. The photoconversion efficiency was further optimized as a function of film thickness. A maximum photoconversion efficiency of 0.924% from electrospun WO{sub 3} nanofibers that EPD deposited on a substrate was achieved at a film thickness of 18 μm.

  17. Turkana Grits - a Cretaceous braided alluvial system in northern Kenya

    Energy Technology Data Exchange (ETDEWEB)

    Handford, C.R.

    1987-05-01

    Rather spotty but excellent exposures of the Cretaceous-age Turkana Grits occur near the western shore of Lake Turkana, northern Kenya. These very coarse to pebbly arkosic sandstones and sandy conglomerates were derived from and rest unconformably upon Precambrian metamorphic basement; they are overlain by late Tertiary basaltic flows that comprise much of the volcanics in the East African Rift Zone. The formation ranges up to 2000 ft thick in the Laburr Range. Several outcrops contain sauropod, crocodile, and tortoise remains as well as abundant trunks of petrified wood (Dryoxylon). Five major facies make up the Turkana Grits and record a major episode of continental fluvial deposition in basins flanked by Precambrian basement. Facies 1 is crudely stratified, cobble and boulder conglomerate (clast-supported); Facies 2 is crudely stratified pebble-cobble conglomerate and pebbly sandstone; Facies 3 is trough cross-bedded, very coarse sandstones containing fossils wood and vertebrate remains; Facies 4 is crudely stratified to massive sandstones with ironstone nodules; and Facies 5 is red, purple, and gray mudstone and mud shale with carbonate nodules. Facies 1 through 3 record deposition in proximal to medial braided-stream channel, longitudinal bar and dune complexes. Facies 4 is a lowland, hydromorphic paleosol, and Facies 5 represents overbank and abandoned channel-fill sedimentation in an alluvial plain.

  18. The role of discharge variability in the formation and preservation of alluvial sediment bodies

    Science.gov (United States)

    Fielding, Christopher R.; Alexander, Jan; Allen, Jonathan P.

    2018-03-01

    Extant, planform-based facies models for alluvial deposits are not fully fit for purpose, because they over-emphasise plan form whereas there is little in the alluvial rock record that is distinctive of any particular planform, and because the planform of individual rivers vary in both time and space. Accordingly, existing facies models have limited predictive capability. In this paper, we explore the role of inter-annual peak discharge variability as a possible control on the character of the preserved alluvial record. Data from a suite of modern rivers, for which long-term gauging records are available, and for which there are published descriptions of subsurface sedimentary architecture, are analysed. The selected rivers are categorized according to their variance in peak discharge or the coefficient of variation (CVQp = standard deviation of the annual peak flood discharge over the mean annual peak flood discharge). This parameter ranges over the rivers studied between 0.18 and 1.22, allowing classification of rivers as having very low ( 0.90) annual peak discharge variance. Deposits of rivers with very low and low peak discharge variability are dominated by cross-bedding on various scales and preserve macroform bedding structure, allowing the interpretation of bar construction processes. Rivers with moderate values preserve mostly cross-bedding, but records of macroform processes are in places muted and considerably modified by reworking. Rivers with high and very high values of annual peak discharge variability show a wide range of bedding structures commonly including critical and supercritical flow structures, abundant in situ trees and transported large, woody debris, and their deposits contain pedogenically modified mud partings and generally lack macroform structure. Such a facies assemblage is distinctively different from the conventional fluvial style recorded in published facies models but is widely developed both in modern and ancient alluvial

  19. A simple semi-empirical approach to model thickness of ash-deposits for different eruption scenarios

    Directory of Open Access Journals (Sweden)

    A. O. González-Mellado

    2010-11-01

    Full Text Available The impact of ash-fall on people, buildings, crops, water resources, and infrastructure depends on several factors such as the thickness of the deposits, grain size distribution and others. Preparedness against tephra falls over large regions around an active volcano requires an understanding of all processes controlling those factors, and a working model capable of predicting at least some of them. However, the complexity of tephra dispersion and sedimentation makes the search of an integral solution an almost unapproachable problem in the absence of highly efficient computing facilities due to the large number of equations and unknown parameters that control the process. An alternative attempt is made here to address the problem of modeling the thickness of ash deposits as a primary impact factor that can be easily communicated to the public and decision-makers. We develop a semi-empirical inversion model to estimate the thickness of non-compacted deposits produced by an explosive eruption around a volcano in the distance range 4–150 km from the eruptive source.

    The model was elaborated from the analysis of the geometric distribution of deposit thickness of 14 world-wide well-documented eruptions. The model was initially developed to depict deposits of potential eruptions of Popocatépetl and Colima volcanoes in México, but it can be applied to any volcano. It has been designed to provide planners and Civil Protection authorities of an accurate perception of the ash-fall deposit thickness that may be expected for different eruption scenarios. The model needs to be fed with a few easy-to-obtain parameters, namely, height of the eruptive column, duration of the explosive phase, and wind speed and direction, and its simplicity allows it to run in any platform, including a personal computers and even a notebook. The results may be represented as tables, two dimensional thickness-distance plots, or isopach maps using any available

  20. Potential building sand deposits in Songkhla province area

    Directory of Open Access Journals (Sweden)

    Kooptarnond, K.

    2002-10-01

    Full Text Available An investigation of potential building sand deposits in Songkhla province area subdivided them into four regions according to their accumulation in various alluvial plains, meanders throughout alluvial deposits and residual soils. Four selected deposits, were Rattaphum-Khuan Niang, U-Taphao river, Na Mom, and Chana-Thepha regions. Information obtained from these deposits revealed a good correlation between the geomorphological features as interpreted from aerial photographs and those identified from vertical electrical resistivity sounding results. Sand samples were analysed for their physical and chemical properties. Petrographic studies were also undertaken to characterize the composition types, texture and shapes. An overview of the sand properties was used them to be within the acceptable limits for building sand. However, relatively high organic impurities and soundness were found in sand from Khuan Niang and Na Mom deposits. The result indicated a potential reconnaissance mineral resource of about 46 square kilometres.A reserve evaluation for natural building sand was carried out by using Geographic Information System (GIS. Maps of the various parameters considered were constructed in digital database format with the aid of Arc/Info and ArcView software. Overlay mapping and buffer zone modules were performed to evaluate inferred resources of building sand. The key parameters of analysis included the distance from transportation, distance from streams, lithology and thickness of sand layers. The remaining inferred sand total was of about 386 million cubic metres or about 1,021 million metric tons was therefore estimated, of which 60 percent lies in the Rattaphum-Khuan Niang region and 40 percent in the other regions.

  1. Reservoir Characterization, Production Characteristics, and Research Needs for Fluvial/Alluvial Reservoirs in the United States

    Energy Technology Data Exchange (ETDEWEB)

    Cole, E.L.; Fowler, M.L.; Jackson, S.R.; Madden, M.P.; Raw-Schatzinger, V.; Salamy, S.P.; Sarathi, P.; Young, M.A.

    1999-04-28

    The Department of Energy's (DOE's) Oil Recovery Field Demonstration Program was initiated in 1992 to maximize the economically and environmentally sound recovery of oil from known domestic reservoirs and to preserve access to this resource. Cost-shared field demonstration projects are being initiated in geology defined reservoir classes which have been prioritized by their potential for incremental recovery and their risk of abandonment. This document defines the characteristics of the fifth geological reservoir class in the series, fluvial/alluvial reservoirs. The reservoirs of Class 5 include deposits of alluvial fans, braided streams, and meandering streams. Deposit morphologies vary as a complex function of climate and tectonics and are characterized by a high degree of heterogeneity to fluid flow as a result of extreme variations in water energy as the deposits formed.

  2. Geostatistical and GIS analysis of the spatial variability of alluvial gold content in Ngoura-Colomines area, Eastern Cameroon: Implications for the exploration of primary gold deposit

    Science.gov (United States)

    Takodjou Wambo, Jonas Didero; Ganno, Sylvestre; Djonthu Lahe, Yannick Sthopira; Kouankap Nono, Gus Djibril; Fossi, Donald Hermann; Tchouatcha, Milan Stafford; Nzenti, Jean Paul

    2018-06-01

    Linear and nonlinear geostatistic is commonly used in ore grade estimation and seldom used in Geographical Information System (GIS) technology. In this study, we suggest an approach based on geostatistic linear ordinary kriging (OK) and Geographical Information System (GIS) techniques to investigate the spatial distribution of alluvial gold content, mineralized and gangue layers thicknesses from 73 pits at the Ngoura-Colomines area with the aim to determine controlling factors for the spatial distribution of mineralization and delineate the most prospective area for primary gold mineralization. Gold content varies between 0.1 and 4.6 g/m3 and has been broadly grouped into three statistical classes. These classes have been spatially subdivided into nine zones using ordinary kriging model based on physical and topographical characteristics. Both mineralized and barren layer thicknesses show randomly spatial distribution, and there is no correlation between these parameters and the gold content. This approach has shown that the Ngoura-Colomines area is located in a large shear zone compatible with the Riedel fault system composed of P and P‧ fractures oriented NE-SW and NNE-SSW respectively; E-W trending R fractures and R‧ fractures with NW-SE trends that could have contributed significantly to the establishment of this gold mineralization. The combined OK model and GIS analysis have led to the delineation of Colomines, Tissongo, Madubal and Boutou villages as the most prospective areas for the exploration of primary gold deposit in the study area.

  3. FUTURE STUDIES AT PENA BLANCA: RADIONUCLIDE MIGRATION IN THE VADOSE ZONE OF AN ALLUVIAL FAN

    Energy Technology Data Exchange (ETDEWEB)

    P. Goodell; J. Walton; P.J. Rodriguez

    2005-07-11

    The pathway to the accessible environment at Yucca Mountain contains volcanic rocks and alluvial fill. Transport properties in alluvial fill, specifically retardation and dispersivity, may be significant in determining the overall performance of the repository. Prior relevant studies, with the exception of the Nye County Tracer Test, are almost entirely in bedrock material. The proposed study will provide field data on radionuclide migration in alluvial material. High grade uranium ore was mined at the Nopal I deposit. This mined ore (60,000 tons) was moved in 1994 to its present site as open piles on an alluvial fan in the Boquilla Colorada Microbasin. Precipitation is approximately 20 cm/year, and has caused migration of radionuclides into the subsurface. We propose partial removal of an ore pile, excavation into the alluvial fan, sampling, and determination of radionuclide mobilities from the uranium decay chain. The proposed research would be taking advantage of a unique opportunity with a known time frame for migration.

  4. FUTURE STUDIES AT PENA BLANCA: RADIONUCLIDE MIGRATION IN THE VADOSE ZONE OF AN ALLUVIAL FAN

    International Nuclear Information System (INIS)

    Goodell, P.; Walton, J.; Rodriguez, P.J.

    2005-01-01

    The pathway to the accessible environment at Yucca Mountain contains volcanic rocks and alluvial fill. Transport properties in alluvial fill, specifically retardation and dispersivity, may be significant in determining the overall performance of the repository. Prior relevant studies, with the exception of the Nye County Tracer Test, are almost entirely in bedrock material. The proposed study will provide field data on radionuclide migration in alluvial material. High grade uranium ore was mined at the Nopal I deposit. This mined ore (60,000 tons) was moved in 1994 to its present site as open piles on an alluvial fan in the Boquilla Colorada Microbasin. Precipitation is approximately 20 cm/year, and has caused migration of radionuclides into the subsurface. We propose partial removal of an ore pile, excavation into the alluvial fan, sampling, and determination of radionuclide mobilities from the uranium decay chain. The proposed research would be taking advantage of a unique opportunity with a known time frame for migration

  5. Thickness of Lipid Deposition on Oral Surfaces Depending on Oil Content and Its Influence on Mouthfeel Perception

    Directory of Open Access Journals (Sweden)

    Urška Pivk Kupirovič

    2012-01-01

    Full Text Available Lipid content in food strongly influences food perception on the level of textural properties. Lipids in contact with the tongue and palate are substantially responsible for the sensory impact of a product. The aim of this study is to investigate the impact of oil content on the thickness of lipid deposition on oral surface as well as on the mouthfeel perception. The fluorescent probe method was used to study the thickness of lipid deposition on oral surface. We observed an increase in the thickness of lipid deposition depending on the increase of oil content in oil/water dispersions. Clear correlation was shown between the thickness of lipid deposition on oral surfaces and the perception of mouthfeel. A direct measure of undisrupted deposition of food components on oral surface contributes to the understanding of the behaviour of food components in the mouth and their influence on mouthfeel perception.

  6. Distribution and Aggregate Thickness of Salt Deposits of the United States

    Data.gov (United States)

    U.S. Environmental Protection Agency — The map shows the distribution and aggregate thickness of salt deposits of the United States. This information is from contour map sheets, scanned and processed for...

  7. Radioactive Contamination of Alluvial Soils in the Taiga Landscapes of Yakutia with 137Cs, 226Ra, and 238U

    Science.gov (United States)

    Chevychelov, A. P.; Sobakin, P. I.

    2017-12-01

    The concentrations and distribution of 137Cs in alluvial soils (Fluvisols) of the upper and middle reaches of the Markha River in the northwest of Yakutia and 226Ra and 238U in alluvial soils within the El'kon uranium ore deposit in the south of Yakutia have been studied. It is shown that the migration of radiocesium in the permafrost-affected soils of Yakutia owing to alluviation processes extends to more than 600 km from the source of the radioactive contamination. The migration of 137Cs with water flows is accompanied by its deposition in the buried horizons of alluvial soils during extremely high floods caused by ice jams. In the technogenic landscapes of southern Yakutia, active water migration of 238U and 226Ra from radioactive dump rocks. The leaching of 238U with surface waters from the rocks is more intense than the leaching of 226Ra. The vertical distribution patterns of 238U and 226Ra in the profiles of alluvial soils are complex. Uranium tends to accumulate in the surface humus horizon and in the buried soil horizons, whereas radium does not display any definite regularities of its distribution in the soil profiles. At present, the migration of 238U and 226Ra with river water and their accumulation in the alluvial soils extend to about 30 km from the source.

  8. An Alluvial Fan at Apollinaris Patera, Mars

    OpenAIRE

    Ghail, RC; Hutchison, JE

    2003-01-01

    Apollinaris Patera, Mars (7?S,173?E), is an intermediate sized volcano (~6 km high, 150 km diameter) with a large (200-km long) fan-like deposit on its southern flank. This fan is deeply incised and originates from a single breach in the rim of the summit caldera. New topographic and multispectral image data reveal that this fan is alluvial, implying a long-lived source of (volcaniclastic) sediment and water (probably from a caldera lake).

  9. Map showing thickness of saturated Quaternary deposits, Sugar House quadrangle, Salt Lake County, Utah, February 1972

    Science.gov (United States)

    Mower, R.W.

    1973-01-01

    Saturated Quaternary deposits in the Sugar Horse quadrangle supply significant quantities of water to wells from which water is withdrawn for domestic, municipal, industrial, and irrigation uses. The deposits consist of clay, silt, sand, and gravel; individual beds range from a few inches to several tens of feet thick. The principal aquifer, which is almost completely within the Quaternary deposits, supplied about 4 percent, or 9,000 acre-feet, of the municipal and industrial water used annually in Salt Lake County during 1964-68.As a general rule, more water is stored and more water will be yielded to a well where aquifers are thicker. This map can be used as a general guide to those areas where greatest amounts of water are stored in the aquifer, and where yields to wells may be greater. Local variations in the ability of saturated deposits to transmit water can alter the general relationship between aquifer thickness and yield of wells.The thickness of saturated Quaternary deposits within the area of the Sugar Horse quadrangle ranges from zero to about 650 feet, as shown on the map. The thickest section of these deposits is near the southwestern corner of the quadrangle, and the thinnest section is along the mountain front adjacent to the approximate eastern limit of saturated Quaternary deposits.The thickness of saturated Quaternary deposits shown on this map is based on drillers’ logs for 55 deep wells (which show the thickness of the Quaternary deposits) and on water-level measurements made in February 1972 in wells in unconfined shallow aquifers.Reports in the following list of selected references contain other information about the saturated Quaternary deposits in this and adjacent parts of Jordan Valley, Utah. The basic-data reports and releases contain well logs, water-level measurements, and other types of basic ground-water data. The interpretive repots contain discussions of the occurrence of ground water, tests to determine hydraulic properties of

  10. Remote sensing analysis of depositional landforms in alluvial settings: Method development and application to the Taquari megafan, Pantanal (Brazil)

    Science.gov (United States)

    Zani, Hiran; Assine, Mario Luis; McGlue, Michael Matthew

    2012-08-01

    Traditional Shuttle Radar Topography Mission (SRTM) topographic datasets hold limited value in the geomorphic analysis of low-relief terrains. To address this shortcoming, this paper presents a series of techniques designed to enhance digital elevation models (DEMs) of environments dominated by low-amplitude landforms, such as a fluvial megafan system. These techniques were validated through the study of a wide depositional tract composed of several megafans located within the Brazilian Pantanal. The Taquari megafan is the most remarkable of these features, covering an area of approximately 49,000 km2. To enhance the SRTM-DEM, the megafan global topography was calculated and found to be accurately represented by a second order polynomial. Simple subtraction of the global topography from altitude produced a new DEM product, which greatly enhanced low amplitude landforms within the Taquari megafan. A field campaign and optical satellite images were used to ground-truth features on the enhanced DEM, which consisted of both depositional (constructional) and erosional features. The results demonstrate that depositional lobes are the dominant landforms on the megafan. A model linking baselevel change, avulsion, clastic sedimentation, and erosion is proposed to explain the microtopographic features on the Taquari megafan surface. The study confirms the potential promise of enhanced DEMs for geomorphological research in alluvial settings.

  11. Depositional characteristics of cretaceous cover in Xiangyangshan area of Heilongjiang province and analysis on prospect for sandstone hosted interlayer oxidation zone type uranium deposits

    International Nuclear Information System (INIS)

    Cai Yuqi; Li Shengxiang; Dong Wenming

    2003-01-01

    The depositional systems and characteristics of Cretaceous Cover depositional facies are discussed. In combination with logging curves in Xiangyangshan area, two depositional systems (namely, alluvial fan depositional system and alluvial plain depositional system) and five types of depositional facies are distinguished. Results of detailed research are given for each depositional facies in aspects of lithology, depositional structure, logging curve and grain size distribution pattern. Temporal and spatial distribution features of the depositional facies and the development features of interlayer oxidation zones of the second member of Quantou Formation are analyzed. Finally, conclusions on prospects for sandstone-hosted interlayer oxidation zone type uranium deposits in the study area are given in the aspect of depositional facies. (authors)

  12. Groundwater quality in alluvial and prolluvial areas under the influence of irrigated agriculture activities.

    Science.gov (United States)

    Kovacevik, Biljana; Boev, Blazo; Panova, Vesna Zajkova; Mitrev, Sasa

    2016-12-05

    The aim of this study was to investigate the groundwater pollution from alluvial aquifers lying under surface agriculture activities in two geologically different areas: alluvial and prolluvial. The groundwater in investigated areas is neutral to alkaline (pH 7.05-8.45), and the major dissolved ions are bicarbonate and calcium. Groundwater samples from the alluvial area are characterized by nitrate concentration above the national maximum concentration limit (MCL) at 20.5% of samples [mean value (Me) 6.31 mg/L], arsenic concentrations greater than national MCL at 35.6% of investigated samples (Me 12.12 µg/L) and elevated concentrations of iron (Me 202.37 µg/L) and manganese (Me 355.22 µg/L) at 22.7% and 81% of investigated samples, respectively. Groundwater samples from the prolluvial area did not show significantly elevated concentrations of heavy metals, but the concentration of nitrate was considerably higher (Me 65.06 mg/L). Factor analysis positively correlates As with Mn and Fe, suggesting its natural origin. Nitrate was found in positive correlation with SO 4 2- and Ni but in negative with NH 4 + , suggesting its anthropogenic origin and the relationship of these ions in the process of denitrification. The t-test analysis showed a significant difference between nitrate pollution of groundwater from alluvial and prolluvial areas. According to the chemical composition of groundwater, the process of denitrification is considered to be the main reason for the reduced presence of nitrate in the groundwater lying under alluvial deposits represented by chalk and sandstones. Denitrification in groundwater lying under prolluvial deposits represented by magmatic and metamorphic rock formations was not observed.

  13. Evolution of depositional system and uraniferous characteristics of Damoguaihe formation in Kelulun sag

    International Nuclear Information System (INIS)

    Zhang Zhijie; Yu Xinghe; Zhang Chuanheng; Chen Zhankun

    2005-01-01

    Damoguaihe Formation, which is mainly of alluvial fan, fan delta and lacustrine depositional systems, is the target horizon for the prospecting of sandstone-type uranium deposit in Kelulun sag, Hailaer basin. According to the depositional environment and sediment characteristics, alluvial fan facies is subdivided into upper fan, middle fan and lower fan subfacies; the fan delta facies is subadivided into upper fan delta plain, lower fan delta plain, fan delta front and fan prodelta subfacies. At the northern edge of the sag occurred one fan delta and one alluvial fan, which can mutually transform one into another. The terrigenous coarse-grained clastic deposits in the study area provide favorable condition for the concentration of uranium and especially the main channels and distributary channels on the fan delta and alluvial fan are the most favorable sites for uranium concentration. (authors)

  14. Summary of Available Hydrogeologic Data for the Northeast Portion of the Alluvial Aquifer at Louisville, Kentucky

    National Research Council Canada - National Science Library

    Unthank, Michael D; Nelson, Jr., Hugh L

    2006-01-01

    The hydrogeologic characteristics of the unconsolidated glacial outwash sand and gravel deposits that compose the northeast portion of the alluvial aquifer at Louisville, Kentucky, indicate a prolific...

  15. The Isopach Mapping of Volcanic Deposits of Mount Samalas 1257 AD Based on the Values of Resistivity and Physical Properties

    Directory of Open Access Journals (Sweden)

    Hiden Hiden

    2017-08-01

    Full Text Available A detailed study had been conducted on the sediment of Mount Samalas’ volcanic eruption in 1257 AD. Using the framework of the reconstruction of the ancient eruption of Mount Samalas, the first step was to map and analyze the deposits of volcanic sediment. Secondly, we analyzed the effect of geomorphology and the distance function to the isopach thickness. The results show that a combination of methods allowed to provide a high resolution map of the distribution of the thickness of the volcanic deposits, both on the slope and in alluvial areas. Geo-electric survey results (both Vertical Electric Sound (VES and 2D mapping show consistent changes in the pattern of contrast resistivity layer interface, for all areas. The pattern changes in a row of the top layer, the high resistivity turned into the low. Furthermore, the second and third layer interface changes from low to the high resistivity. High resistivity on the top layer is interpreted as a layer of unconsolidated volcanic sediment. High resistivity values are range from 736 to 2000 Ohm.m on the top layer in the area of the slopes while in the area of alluvial, the resistivity values range from 20 to 958 Ohm.m. Generally, the volcanic deposits in the area of the slopes have a higher value of isopach (>17 m than in areas of alluvial (<25 m. The geomorphology seemed to have no significant effect on the isopach value, particularly pyroclastic fallout. Such is the case with distance from the source to the site, which is not linear. The value of isopach increases westward from 21 to 31 km, in contrast to the East, which began to occur at a distance of 14 km to 21 km.

  16. The Effect of Film Thickness on the Gas Sensing Properties of Ultra-Thin TiO₂ Films Deposited by Atomic Layer Deposition.

    Science.gov (United States)

    Wilson, Rachel L; Simion, Cristian Eugen; Blackman, Christopher S; Carmalt, Claire J; Stanoiu, Adelina; Di Maggio, Francesco; Covington, James A

    2018-03-01

    Analyte sensitivity for gas sensors based on semiconducting metal oxides should be highly dependent on the film thickness, particularly when that thickness is on the order of the Debye length. This thickness dependence has previously been demonstrated for SnO₂ and inferred for TiO₂. In this paper, TiO₂ thin films have been prepared by Atomic Layer Deposition (ALD) using titanium isopropoxide and water as precursors. The deposition process was performed on standard alumina gas sensor platforms and microscope slides (for analysis purposes), at a temperature of 200 °C. The TiO₂ films were exposed to different concentrations of CO, CH₄, NO₂, NH₃ and SO₂ to evaluate their gas sensitivities. These experiments showed that the TiO₂ film thickness played a dominant role within the conduction mechanism and the pattern of response for the electrical resistance towards CH₄ and NH₃ exposure indicated typical n -type semiconducting behavior. The effect of relative humidity on the gas sensitivity has also been demonstrated.

  17. Measurement of thickness of film deposited on the plasma-facing wall in the QUEST tokamak by colorimetry.

    Science.gov (United States)

    Wang, Z; Hanada, K; Yoshida, N; Shimoji, T; Miyamoto, M; Oya, Y; Zushi, H; Idei, H; Nakamura, K; Fujisawa, A; Nagashima, Y; Hasegawa, M; Kawasaki, S; Higashijima, A; Nakashima, H; Nagata, T; Kawaguchi, A; Fujiwara, T; Araki, K; Mitarai, O; Fukuyama, A; Takase, Y; Matsumoto, K

    2017-09-01

    After several experimental campaigns in the Kyushu University Experiment with Steady-state Spherical Tokamak (QUEST), the originally stainless steel plasma-facing wall (PFW) becomes completely covered with a deposited film composed of mixture materials, such as iron, chromium, carbon, and tungsten. In this work, an innovative colorimetry-based method was developed to measure the thickness of the deposited film on the actual QUEST wall. Because the optical constants of the deposited film on the PFW were position-dependent and the extinction coefficient k 1 was about 1.0-2.0, which made the probing light not penetrate through some thick deposited films, the colorimetry method developed can only provide a rough value range of thickness of the metal-containing film deposited on the actual PFW in QUEST. However, the use of colorimetry is of great benefit to large-area inspections and to radioactive materials in future fusion devices that will be strictly prohibited from being taken out of the limited area.

  18. Anastomosing river deposits: palaeoenvironmental control on coal quality and distribution, Northern Karoo Basin

    Energy Technology Data Exchange (ETDEWEB)

    Cairncross, B

    1980-01-01

    Borehole data from an area close to the northern margin of the Karoo Basin 110 m thick coal reveal a bearing succession of the Vryheid Formation overlying Dwyka tillite. The lowermost sediments reflect processes of deglaciation with a complex array of glaciolacustrine, glaciofluvial and alluvial-outwash fan deposits. Above this paraglacial milieu, tundra-type peat bogs developed in inactive areas and account for the two thick basal coal seams (No. 1 and 2 seams). During accumulation of peat which was later to form the extensive No. 2 coal seam, active clastic sedimentation was confined to laterally restricted river channels which incised into the underlying peat. Lateral migration was inhibited by vegetation stabilized river banks and channel deposits are characterized by vertically accreted upward-fining cycles. Channel fill consists of coarse-grinder bedload sediment deposited in anastomosing streams. Flood episodes are marked by widespread, but thin (< 1 m), shale zones that intercalate with the channel sandstones. Both sandstone and shale units are completely enveloped by No. 2 coal seams. This clastic parting influences No. 2 coal seam distribution and ash content. 23 references

  19. The Effects of Two Thick Film Deposition Methods on Tin Dioxide Gas Sensor Performance

    OpenAIRE

    Bakrania, Smitesh D.; Wooldridge, Margaret S.

    2009-01-01

    This work demonstrates the variability in performance between SnO2 thick film gas sensors prepared using two types of film deposition methods. SnO2 powders were deposited on sensor platforms with and without the use of binders. Three commonly utilized binder recipes were investigated, and a new binder-less deposition procedure was developed and characterized. The binder recipes yielded sensors with poor film uniformity and poor structural integrity, compared to the binder-less deposition meth...

  20. Tracing the Source of Borneo's Cempaka Diamond Deposit

    Science.gov (United States)

    White, L. T.; Graham, I.; Armstrong, R. A.; Hall, R.

    2014-12-01

    Several gem quality diamond deposits are found in paleo-alluvial deposits across Borneo. The source of the diamonds and their origin are enigmatic. They could have formed in Borneo and be derived from local sources, or they could be related to diamond deposits in NW Australia, and carried with the Southwest Borneo Block after it rifted from Australia in the Late Jurassic. We collected U-Pb isotopic data from detrital zircons from the Cempaka alluvial diamond deposit in southeast Borneo. Two thirds of the zircons that were dated crystallized between 75 Ma and 110 Ma. The other third are Triassic or older (223 Ma, 314-319 Ma, 353-367 Ma, 402-414 Ma, 474 Ma, 521 Ma, 549 Ma, 1135-1176 Ma, 1535 Ma, 2716 Ma). All of the Cretaceous zircons are angular, euhedral grains with minor evidence of mechanical abrasion. Considering their age and morphology they were likely derived from the nearby Schwaner Granites. The Triassic and older grains are rounded to semi-rounded and were likely derived from Australia before Borneo rifted from Gondwana. Some of the zircons have ages that resemble those of the Merlin and Argyle diamond deposits of Australia. The diamonds themselves have delicate resorption features and overgrowths that would potentially be destroyed with prolonged transport. Geochemical data collected from the diamonds implies they were associated with lamproite intrusions. Deep seismic lines and zircons from igneous rocks suggest SE Borneo, the East Java Sea and East Java are largely underlain by thick lithosphere rifted from NW Australia. Based on several lines of evidence, we propose that diamond-bearing lamproites intruded before rifting of SW Borneo from Australia, or after collision with Sundaland of SW Borneo and the East Java-West Sulawesi Blocks during the Cretaceous. Exposure of the source after the Late Cretaceous led to diamond accumulation in river systems that flowed from the Schwaner Mountains.

  1. Direct fabrication of integrated 3D Au nanobox arrays by sidewall deposition with controllable heights and thicknesses

    Energy Technology Data Exchange (ETDEWEB)

    Cha, Nam-Goo; Lee, Bong Kuk; Kanki, Teruo; Lee, Hea Yeon; Kawai, Tomoji; Tanaka, Hidekazu, E-mail: h-tanaka@sanken.osaka-u.ac.j [Institute of Scientific and Industrial Research, Osaka University, 8-1 Mihogaoka, Ibaraki, Osaka 567-0047 (Japan)

    2009-09-30

    This paper provides a unique strategy for controlling integrated hollow nanostructure arrays such as boxes or pillars at the nanometer scale. The key merit of this technique is that it can overcome resolution limits by sidewall deposition and deposit various materials using a sputtering method. The sputtering method can be replaced by other dry deposition techniques such as pulsed laser deposition (PLD) for complex functional materials. Furthermore, it can produce low-cost large-area fabrication and high reproducibility using the NIL (nanoimprint lithograph) process. The fabrication method consists of a sequence of bilayer spin-coating, UV-NIL, RIE (reactive ion etching), sputtering, ion milling and piranha cleaning processes. By changing the deposition time and molds, various thicknesses and shapes can be fabricated, respectively. Furthermore, the fabricated Au box nanostructure has a bending zone of the top layer and a {approx}17 nm undercut of the bottom layer as observed by SEM (scanning electron microscope). The sidewall thickness was changed from 12 to 61 nm by controlling the deposition time, and was investigated to understand the relationship with blanket thicknesses and geometric effects. The calculated sidewall thickness matched well with experimental results. Using smaller hole-patterned molds, integrated nanobox arrays, with inner squares measuring {approx}160 nm, and nanopillar arrays, with inside pores measuring {approx}65 nm, were fabricated under the same conditions.

  2. Chronostratigraphic study of the Grottaperfetta alluvial valley in the city of Rome (Italy: investigating possible interaction between sedimentary and tectonic processes

    Directory of Open Access Journals (Sweden)

    G. Di Giulio

    2008-06-01

    Full Text Available We carried out geomorphologic and geological investigations in a south-eastern tributary valley of the Tiber River in Rome, the Grottaperfetta valley, aimed to reconstruct its buried geometry. Since results of the geomorphologic study evidenced anomalies of the stream beds, we performed geoelectric and boreholes prospecting to check whether recent faulting, rather than an inherited structural control, possibly contributed to the evolution of the alluvial valley. Vertical offsets of the stratigraphic horizons across adjacent boreholes were evidenced within the Late Pleistocene-Holocene alluvium and its substratum. In order to rule out the effects of irregular geometry of the alluvial deposits, we focussed on sectors where vertical offsets affected all the stratigraphic horizons (alluvium and pre-Holocene substratum, showing an increasing displacement with depth. We identified a site where repeated displacements occur coupled with a lateral variation of soil resistivity, and we drilled an oblique borehole aimed to cross and sample the possible fault zone affecting the terrain. A 7 cm thick granular layer, inclined 50°÷70° on the horizontal, was recovered 5 m b.g., and it was interpreted as the filling material of a fracture. The convergence of the reported features with independent evidence from geoelectric and geomorphologic investigations leads to hypothesize the presence of a faulting zone within the Holocene alluvial terrains and to propose the excavation of a trench to verify this hypothesis.

  3. Storage in alluvial deposits controls the timing of particle delivery from large watersheds, filtering upland erosional signals and delaying benefits from watershed best management practices

    Science.gov (United States)

    Pizzuto, J. E.; Skalak, K.; Karwan, D. L.

    2017-12-01

    Transport of suspended sediment and sediment-borne constituents (here termed fluvial particles) through large river systems can be significantly influenced by episodic storage in floodplains and other alluvial deposits. Geomorphologists quantify the importance of storage using sediment budgets, but these data alone are insufficient to determine how storage influences the routing of fluvial particles through river corridors across large spatial scales. For steady state systems, models that combine sediment budget data with "waiting time distributions" (to define how long deposited particles remain stored until being remobilized) and velocities during transport events can provide useful predictions. Limited field data suggest that waiting time distributions are well represented by power laws, extending from 104 years, while the probability of storage defined by sediment budgets varies from 0.1 km-1 for small drainage basins to 0.001 km-1 for the world's largest watersheds. Timescales of particle delivery from large watersheds are determined by storage rather than by transport processes, with most particles requiring 102 -104 years to reach the basin outlet. These predictions suggest that erosional "signals" induced by climate change, tectonics, or anthropogenic activity will be transformed by storage before delivery to the outlets of large watersheds. In particular, best management practices (BMPs) implemented in upland source areas, designed to reduce the loading of fluvial particles to estuarine receiving waters, will not achieve their intended benefits for centuries (or longer). For transient systems, waiting time distributions cannot be constant, but will vary as portions of transient sediment "pulses" enter and are later released from storage. The delivery of sediment pulses under transient conditions can be predicted by adopting the hypothesis that the probability of erosion of stored particles will decrease with increasing "age" (where age is defined as the

  4. Thickness dependent growth of low temperature atomic layer deposited zinc oxide films

    International Nuclear Information System (INIS)

    Montiel-González, Z.; Castelo-González, O.A.; Aguilar-Gama, M.T.; Ramírez-Morales, E.; Hu, H.

    2017-01-01

    Highlights: • Polycrystalline columnar ZnO thin films deposited by ALD at low temperatures. • Higher deposition temperature leads to a greater surface roughness in the ALD ZnO films. • Higher temperature originates larger refractive index values of the ALD ZnO films. • ZnO thin films were denser as the numbers of ALD deposition cycles were larger. • XPS analysis revels mayor extent of the DEZ reaction during the ALD process. - Abstract: Zinc oxide films are promising to improve the performance of electronic devices, including those based on organic materials. However, the dependence of the ZnO properties on the preparation conditions represents a challenge to obtain homogeneous thin films that satisfy specific applications. Here, we prepared ZnO films of a wide range of thicknesses by atomic layer deposition (ALD) at relatively low temperatures, 150 and 175 °C. From the results of X-ray photoelectron spectroscopy, X-ray diffraction and Spectroscopic Ellipsometry it is concluded that the polycrystalline structure of the wurtzite is the main phase of the ALD samples, with OH groups on their surface. Ellipsometry revealed that the temperature and the deposition cycles have a strong effect on the films roughness. Scanning electron micrographs evidenced such effect, through the large pyramids developed at the surface of the films. It is concluded that crystalline ZnO thin films within a broad range of thickness and roughness can be obtained for optic or optoelectronic applications.

  5. Growth of BaTiO3-PVDF composite thick films by using aerosol deposition

    Science.gov (United States)

    Cho, Sung Hwan; Yoon, Young Joon

    2016-01-01

    Barium titanate (BaTiO3)-polyvinylidene fluoride (PVDF) composite thick films were grown by using aerosol deposition at room temperature with BaTiO3 and PVDF powders. To produce a uniform composition in ceramic and polymer composite films, which show a substantial difference in specific gravity, we used PVDF-coated BaTiO3 powders as the starting materials. An examination of the microstructure confirmed that the BaTiO3 were well distributed in the PVDF matrix in the form of a 0 - 3 compound. The crystallite size in the BaTiO3-PVDF composite thick films was 5 ˜ 50 times higher than that in pure BaTiO3 thick films. PVDF plays a role in suppressing the fragmentation of BaTiO3 powder during the aerosol deposition process and in controlling the relative permittivity.

  6. Obsidian from volcanic sequences and rent alluvial deposits, Erzurum district, north-eastern Anatolia: Chemical characterisation and archaeological implications

    International Nuclear Information System (INIS)

    Brennan, P.; Sagona, T.

    1997-01-01

    Full text: Recent geoarchaeological research in the Erzurum district, north-eastern Anatolia, has revealed an abundance of obsidian at numerous neolithic and Bronze Age sites. Geochemical characterisation using neutron activation analysis indicates that the obsidian was obtained from several sources that are chemically distinct from the major sources already known from Central Anatolia an the Lake Van area. Multiple sources are represented in the samples collected from at least two of the sites, namely the sites of Sos and Pulur. The primary source of some of the obsidian utilised at the site of Sos has been located in the volcanic sequence outcropping tot he north-west of Pasinler. Field survey however has shown that the alluvial deposits along the main rivers and some of their tributaries were the main sources of the obsidian utilised at the sites near Erzurum. Trade or exchange of obsidian with sites outside the Erzurum area seems to have been limited

  7. Stability of radioactive minerals in an oxidizing hydrogeological environment: new results from an alluvial placer deposit, Naegi district, central Japan

    International Nuclear Information System (INIS)

    Sasao, Eiji; Komuro, Kosei; Nakata, Masataka

    2009-01-01

    Study of the stability of radioactive minerals in a placer deposit in the Naegi District, southeastern Gifu Prefecture, Central Japan contributes to understanding the modes of nuclide migration under various hydrogeological environments in the tectonically active Japanese Island Arc system. The placer deposit is embedded in basal conglomerates of the lower-most alluvial sequences, exposed to a near-surface, oxidizing hydrogeological environment. The mineral samples, ranging in mesh size from 120 to 250, were identified after sieving and magnetic separation to be mainly cassiterite, thorite, monazite, and topaz, with subordinate amounts of zircon, fergusonite-(Y), xenotime and wolframite. Observations using optical and scanning microscopy indicated that many grains of zircon have well-preserved crystal faces. Most monazite and fergusonite-(Y) grains are partly abraded and corroded whereas thorite grains are highly abraded and corroded. This indicates that under an oxidizing hydrogeological environment, the mechanical durability and geological stability decrease from zircon to monazite/fergusonite-(Y) to thorite, which correlates well with the Mohs's hardness scale. Cut and polished thorite grains display a high degree of alteration. The altered portions have higher Th, Fe and Y contents, and lower U and Si contents in comparison with the unaltered portions, indicating leaching of U and Si. In the fergusonite-(Y) grains, the altered portions have higher Th, Nb and Ta contents, and lower U and Y contents in comparison with the unaltered portions, indicate leaching of U and Y. Thus it is determined that uranium is strongly leached in an oxidizing hydrogeological environment. The leaching behaviour is dependent on mineralogy and is consistent with thermodynamic estimates. The alteration rate of fergusonite-(Y) was calculated to range from 0.05 to 0.000025 μm/year based on the thickness of the external alteration film and the duration of exposure to the oxidizing

  8. Nucleation of Waterfalls at Fault Scarps Temporarily Shielded By Alluvial Fan Aggradation.

    Science.gov (United States)

    Malatesta, L. C.; Lamb, M. P.

    2014-12-01

    Waterfalls are important components of mountain river systems and they can serve as an agent to transfer tectonic, climatic, or authigenic signals upstream through a catchment. Retreating waterfalls lower the local base level of the adjacent hillslopes, and temporarily increase sediment delivery to the fluvial system. Their creation is often attributed to seismic ruptures, lithological boundaries, or the coalescence of multiple smaller steps. We explore here a mechanism for the nucleation of waterfalls that does not rely on sudden seismic slip but on the build-up of accumulated slip during periods of fault burial by fluvial aggradation. Alluvial fans are common features at the front of mountain ranges bound by normal or thrust faults. Climate change or internal forcing in the mountain catchment modifies the equilibrium slope of alluvial fans. When alluvial fans aggrade, they shield the active fault scarp from fluvial erosion allowing the scarp to grow undisturbed. The scarp may then be exposed when the channel incises into the fan exposing a new bedrock waterfall. We explore this mechanism analytically and using a numerical model for bedrock river incision and sediment deposition. We find that the creation of waterfalls by scarp burial is limited by three distinct timescales: 1) the critical timescale for the scarp to grow to the burial height, 2) the timescale of alluvial re-grading of the fan, and 3) the timescale of the external or internal forcing, such as climate change. The height of the waterfall is controlled by i) the difference in equilibrium alluvial-fan slopes, ii) the ratio of the respective fan and catchment sizes, iii) the catchment wide denudation rate, and iv) the fault slip rate. We test whether an individual waterfall could be produced by alluvial shielding of a scarp, and identify the tectonic, climatic, or authigenic nature of waterfalls using example field sites in the southwest United States.

  9. Effect of layer thickness on the thermal release from Be-D co-deposited layers

    Science.gov (United States)

    Baldwin, M. J.; Doerner, R. P.

    2014-08-01

    The results of previous work (Baldwin et al 2013 J. Nucl. Mater. 438 S967-70 and Baldwin et al 2014 Nucl. Fusion 54 073005) are extended to explore the influence of layer thickness on the thermal D2 release from co-deposited Be-(0.05)D layers produced at ˜323 K. Bake desorption of layers of thickness 0.2-0.7 µm are explored with a view to examine the influence of layer thickness on the efficacy of the proposed ITER bake procedure, to be carried out at the fixed temperatures of 513 K on the first wall and 623 K in the divertor. The results of experiment and modelling with the TMAP-7 hydrogen transport code, show that thicker Be-D co-deposited layers are relatively more difficult to desorb (time-wise) than thinner layers with the same concentrations of intrinsic traps and retained hydrogen isotope fraction.

  10. [Effects of the grain size and thickness of dust deposits on soil water and salt movement in the hinterland of the Taklimakan Desert].

    Science.gov (United States)

    Sun, Yan-Wei; Li, Sheng-Yu; Xu, Xin-Wen; Zhang, Jian-Guo; Li, Ying

    2009-08-01

    By using mcirolysimeter, a laboratory simulation experiment was conducted to study the effects of the grain size and thickness of dust deposits on the soil water evaporation and salt movement in the hinterland of the Taklimakan Desert. Under the same initial soil water content and deposition thickness condition, finer-textured (grain size of dust deposits on soil water evaporation had an inflection point at the grain size 0.20 mm, i. e., increased with increasing grain size when the grain size was 0.063-0.20 mm but decreased with increasing grain size when the grain size was > 0.20 mm. With the increasing thickness of dust deposits, its inhibition effect on soil water evaporation increased, and there existed a logarithmic relationship between the dust deposits thickness and water evaporation. Surface soil salt accumulation had a negative correlation with dust deposits thickness. In sum, the dust deposits in study area could affect the stability of arid desert ecosystem.

  11. Effects of the thickness of gold deposited on a source backing film in the 4πβ-counting

    International Nuclear Information System (INIS)

    Miyahara, Hiroshi; Yoshida, Makoto; Watanabe, Tamaki

    1976-01-01

    A gold deposited VYNS film as a source backing in the 4πβ-counting has generally been used for reducing the absorption of β-rays. The thickness of the film with the gold is usually a few times thicker than the VYNS film itself. However, Because the appropriate thickness of gold has not yet been determined, the effects of gold thickness on electrical resistivity, plateau characteristics and β-ray counting efficiency were studied. 198 Au (960 keV), 60 Co(315 keV), 59 Fe(273 keV) and 95 Nb(160 keV), which were prepared as sources by the aluminium chloride treatment method, were used. Gold was evaporated under a deposition rate of 1 - 5 μg/cm 2 /min at a pressure less than 1 x 10 -5 Torr. Results show that the gold deposition on the side opposite the source after source preparation is essential. In this case, a maximum counting efficiency is obtained at the mean thickness of 2 μg/cm 2 . When gold is deposited only on the same side as the source, a maximum counting efficiency, which is less than that in the former case, is obtained at the mean thickness of 20 μg/cm 2 . (Evans, J.)

  12. Measuring the thickness of austenitic weld deposits on carbon steel walls using a magnetic method

    International Nuclear Information System (INIS)

    Wagner, K.

    1988-01-01

    The theoretical background is described of a magnetic method characterized by a marked compensation of the undesirable effect of δ-ferrite content in the deposit, on the accuracy of measuring deposit thickness. A description is also given of the basic types of sensors and the results are summarized of comparing measurements performed on weld deposits of WWER-type reactor pressure vessels. (author). 7 figs., 5 refs

  13. Effect of thickness on electrical properties of SILAR deposited SnS thin films

    Science.gov (United States)

    Akaltun, Yunus; Astam, Aykut; Cerhan, Asena; ćayir, Tuba

    2016-03-01

    Tin sulfide (SnS) thin films of different thickness were prepared on glass substrates by successive ionic layer adsorption and reaction (SILAR) method at room temperature using tin (II) chloride and sodium sulfide aqueous solutions. The thicknesses of the films were determined using spectroscopic ellipsometry measurements and found to be 47.2, 65.8, 111.0, and 128.7nm for 20, 25, 30 and 35 deposition cycles respectively. The electrical properties of the films were investigated using d.c. two-point probe method at room temperature and the results showed that the resistivity was found to decrease with increasing film thickness.

  14. Textural parameters distribution in sediments surface of the Uruguay river background between km 221 and 254

    International Nuclear Information System (INIS)

    Capeluto, W.; Campos, T. de los

    2010-01-01

    The aim of this paper is to analyze the distribution of textural statistical parameters and spatial variation in the morphology of the sediment areas. The geology of the area comprises alluvial and alluvial deposits of variable thicknesses overlying deposits of Fray Bent os, Salto and Guichon formations that occasionally emerge in the river bed

  15. The Effect of Film Thickness on the Gas Sensing Properties of Ultra-Thin TiO2 Films Deposited by Atomic Layer Deposition

    Directory of Open Access Journals (Sweden)

    Rachel L. Wilson

    2018-03-01

    Full Text Available Analyte sensitivity for gas sensors based on semiconducting metal oxides should be highly dependent on the film thickness, particularly when that thickness is on the order of the Debye length. This thickness dependence has previously been demonstrated for SnO2 and inferred for TiO2. In this paper, TiO2 thin films have been prepared by Atomic Layer Deposition (ALD using titanium isopropoxide and water as precursors. The deposition process was performed on standard alumina gas sensor platforms and microscope slides (for analysis purposes, at a temperature of 200 °C. The TiO2 films were exposed to different concentrations of CO, CH4, NO2, NH3 and SO2 to evaluate their gas sensitivities. These experiments showed that the TiO2 film thickness played a dominant role within the conduction mechanism and the pattern of response for the electrical resistance towards CH4 and NH3 exposure indicated typical n-type semiconducting behavior. The effect of relative humidity on the gas sensitivity has also been demonstrated.

  16. Holocene alluvial stratigraphy and response to climate change in the Roaring River valley, Front Range, Colorado, USA

    Science.gov (United States)

    Madole, Richard F.

    2012-09-01

    Stratigraphic analyses and radiocarbon geochronology of alluvial deposits exposed along the Roaring River, Colorado, lead to three principal conclusions: (1) the opinion that stream channels in the higher parts of the Front Range are relics of the Pleistocene and nonalluvial under the present climate, as argued in a water-rights trial USA v. Colorado, is untenable, (2) beds of clast-supported gravel alternate in vertical succession with beds of fine-grained sediment (sand, mud, and peat) in response to centennial-scale changes in snowmelt-driven peak discharges, and (3) alluvial strata provide information about Holocene climate history that complements the history provided by cirque moraines, periglacial deposits, and paleontological data. Most alluvial strata are of late Holocene age and record, among other things, that: (1) the largest peak flows since the end of the Pleistocene occurred during the late Holocene; (2) the occurrence of a mid- to late Holocene interval (~ 2450-1630(?) cal yr BP) of warmer climate, which is not clearly identified in palynological records; and (3) the Little Ice Age climate seems to have had little impact on stream channels, except perhaps for minor (~ 1 m) incision.

  17. Effect of layer thickness on the thermal release from Be–D co-deposited layers

    International Nuclear Information System (INIS)

    Baldwin, M.J.; Doerner, R.P.

    2014-01-01

    The results of previous work (Baldwin et al 2013 J. Nucl. Mater. 438 S967–70 and Baldwin et al 2014 Nucl. Fusion 54 073005) are extended to explore the influence of layer thickness on the thermal D 2 release from co-deposited Be–(0.05)D layers produced at ∼323 K. Bake desorption of layers of thickness 0.2–0.7 µm are explored with a view to examine the influence of layer thickness on the efficacy of the proposed ITER bake procedure, to be carried out at the fixed temperatures of 513 K on the first wall and 623 K in the divertor. The results of experiment and modelling with the TMAP-7 hydrogen transport code, show that thicker Be–D co-deposited layers are relatively more difficult to desorb (time-wise) than thinner layers with the same concentrations of intrinsic traps and retained hydrogen isotope fraction. (paper)

  18. Thickness determination of large-area films of yttria-stabilized zirconia produced by pulsed laser deposition

    Energy Technology Data Exchange (ETDEWEB)

    Pryds, N. [Materials Research Department, Riso National Laboratory, DK-4000 Roskilde (Denmark)]. E-mail: nini.pryds@risoe.dk; Toftmann, B. [Department of Optics and Plasma Research, Riso National Laboratory, DK-4000 Roskilde (Denmark); Bilde-Sorensen, J.B. [Materials Research Department, Riso National Laboratory, DK-4000 Roskilde (Denmark); Schou, J. [Department of Optics and Plasma Research, Riso National Laboratory, DK-4000 Roskilde (Denmark); Linderoth, S. [Materials Research Department, Riso National Laboratory, DK-4000 Roskilde (Denmark)

    2006-04-30

    Films of yttria-stabilized zirconia (YSZ) on a polished silicon substrate of diameter up to 125 mm have been produced in a large-area pulsed laser deposition (PLD) setup under typical PLD conditions. The film thickness over the full film area has been determined by energy-dispersive X-ray spectrometry in a scanning electron microscope (SEM) with use of a method similar to one described by Bishop and Poole. The attenuation of the electron-induced X-rays from the Si wafer by the film was monitored at a number of points along a diameter and the thickness was determined by Monte Carlo simulations of the attenuation for various values of film thickness with the program CASINO. These results have been compared with direct measurements in the SEM of the film thickness on a cross-section on one of the wafers. The results of these measurements demonstrate the ability of this technique to accurately determine the thickness of a large film, i.e. up to diameters of 125 mm, in a relatively short time, without destroying the substrate, without the need of a standard sample and without the need of a flat substrate. We have also demonstrated that by controlling the deposition parameters large-area YSZ films with uniform thickness can be produced.

  19. Thickness determination of large-area films of yttria-stabilized zirconia produced by pulsed laser deposition

    International Nuclear Information System (INIS)

    Pryds, N.; Toftmann, B.; Bilde-Sorensen, J.B.; Schou, J.; Linderoth, S.

    2006-01-01

    Films of yttria-stabilized zirconia (YSZ) on a polished silicon substrate of diameter up to 125 mm have been produced in a large-area pulsed laser deposition (PLD) setup under typical PLD conditions. The film thickness over the full film area has been determined by energy-dispersive X-ray spectrometry in a scanning electron microscope (SEM) with use of a method similar to one described by Bishop and Poole. The attenuation of the electron-induced X-rays from the Si wafer by the film was monitored at a number of points along a diameter and the thickness was determined by Monte Carlo simulations of the attenuation for various values of film thickness with the program CASINO. These results have been compared with direct measurements in the SEM of the film thickness on a cross-section on one of the wafers. The results of these measurements demonstrate the ability of this technique to accurately determine the thickness of a large film, i.e. up to diameters of 125 mm, in a relatively short time, without destroying the substrate, without the need of a standard sample and without the need of a flat substrate. We have also demonstrated that by controlling the deposition parameters large-area YSZ films with uniform thickness can be produced

  20. In situ, real-time thickness measurement techniques for bath-deposited CdS thin films on Cu(In,Ga)Se2

    International Nuclear Information System (INIS)

    Mann, Jonathan R.; Noufi, Rommel

    2012-01-01

    A technique has been developed that can measure the thickness of a 30–70 nm thin film of cadmium sulfide on a Cu(In,Ga)Se 2 substrate, in real time, as it grows in a chemical bath. The technique does not damage the film, and can be used to monitor batch depositions and roll-to-roll depositions with equal accuracy. The technique is based on reflectance spectroscopy through the chemical bath. - Highlights: ► Reflection spectra were collected during the chemical bath deposition of CdS. ► Two algorithms were generated to extract film thickness from each spectrum. ► Two conventional techniques were used to independently verify CdS film thicknesses. ► The accuracies of the algorithms are within 7% of the actual thicknesses. ► The algorithms offer in situ, real time thicknesses through the chemical bath.

  1. Detailed gravity survey to help seismic microzonation: Mapping the thickness of unconsolidated deposits in Ottawa, Canada

    Science.gov (United States)

    Lamontagne, M.; Thomas, M.; Silliker, J.; Jobin, D.

    2011-11-01

    In this study, measurements of gravity were made to map and model the thickness of Quaternary deposits (sand and clay) overlying Ordovician limestones in a suburb of Ottawa (Orléans, Ontario). Because ground motion amplification is partly related to the thickness of unconsolidated deposits, this work helps refine the assessment of the earthquake damage potential of the area. It also helps the mapping of clay basins, which can locally exceed 100 m in thickness, where ground motion amplification can occur. Previous work, including well log data and seismic methods, have yielded a wealth of information on near-surface geology in Orléans, thereby providing the necessary constraints to test the applicability of gravity modeling in other locations where other methods cannot always be used. Some 104 gravity stations were occupied in an 8 × 12 km test area in the Orléans. Stations were accurately located with differential GPS that provided centimetric accuracy in elevation. Densities of the unconsolidated Quaternary deposits (Champlain Sea clay) determined on core samples and densities determined on limestone samples from outcrops were used to constrain models of the clay layer overlying the higher density bedrock formations (limestone). The gravity anomaly map delineates areas where clay basins attain > 100 m depth. Assuming a realistic density for the Champlain Sea clays (1.9-2.1 g/cm 3), the thickness over the higher density bedrock formations (Ordovician carbonate rocks) was modeled and compared with well logs and two seismic reflection profiles. The models match quite well with the information determined from well logs and seismic methods. It was found that gravity and the thickness of unconsolidated deposits are correlated but the uncertainties in both data sets preclude the definition of a direct correlation between the two. We propose that gravity measurements at a local scale be used as an inexpensive means of mapping the thickness of unconsolidated deposits

  2. Age and origin of the Gezira alluvial fan between the Blue and White Nile rivers

    Science.gov (United States)

    Williams, martin

    2014-05-01

    The Gezira is a low-angle alluvial fan bounded by the Blue Nile to the east and the White Nile to the west. It is the main agricultural region of Sudan and produces high quality long-staple cotton for export. Dark cracking clays (vertisols) cover much of the Gezira and range in age from 50 kyr to Holocene. The Gezira is traversed by a series of defunct sandy channels that originate between Sennar and Wad Medani on the present-day Blue Nile. With a radius of 300 km and an area of 40,000 km2 the Gezira is a mega-fan. The younger channels range in age from early Holocene to 100 kyr, while near surface channels filled with rolled quartz and carbonate gravels have ages back to >250 kyr. Boreholes in the Gezira reveal coarse alluvial sands and gravels in now buried channels overlain by alluvial clays, forming a repetitive sequence of fining-upwards alluvial units. that probably extend back to Pliocene times. The fan is up to 180 m thick with a volume of ~1,800 km3. The sandy or gravelly bed-load channels coincide with colder drier climates and sparse vegetation in the Ethiopian headwaters of the Blue Nile and the alluvial clays denote widespread flooding during times of stronger summer monsoon. The early stages of such flood events were often accompanied by mass burial of Nile oyster (Etheria elliptica) beds, such as the 45-50 kyr floods that deposited up to 5 m of clay in the northern Gezira. A unique feature of the eastern Gezira is a former Blue Nile channel at least 80 km long running parallel to the present river and entirely filled with volcanic ash. The channel was only 3-4 m deep and 20-30 m wide. Very fine laminations and cross-beds, together with locally abundant phytoliths and sponge spicules, suggest slow-moving water, with flow dispersed across many distributary channels. The ash geochemistry is similar to that in the lower part of the Kibish Formation in the lower Omo valley of southern Ethiopia and points to a minimum age of 100 kyr and a maximum age of

  3. Potential impacts of damming the Juba Valley, western Somalia: Insights from geomorphology and alluvial history

    Science.gov (United States)

    Williams, Martin

    2014-05-01

    In 1988 plans were well advanced to dam the Juba River in western Somalia. The aims of the Baardheere Dam Project were to generate hydroelectric power for the capital Mogadishu, and to provide water for irrigation in the Juba Valley. A reconnaissance survey on foot along 500 km of the river upstream of the proposed dam site at Baardheere and detailed geomorphic mapping from air photos provided a basis for reconstructing the late Quaternary alluvial history of the river and for assessing the potential impact of the proposed dam. The Juba River rises in the Ethiopian Highlands and is the only river in Somalia that flows to the sea. Its history reflects climatic events in Ethiopia, where the Rift Valley lakes were very low during the LGM (21±2 ka), and high for about 5, 000 years before and after then. Cave deposits in Somalia indicate wetter conditions at 13, 10, 7.5 and 1.5 ka. Alluvial terraces in the Juba Valley range in age from late Pleistocene to late Holocene but only attain a few metres above the present floodplain. This is because the dry tributary valleys contain limestone caves and fissures that divert any high flows from the parent river underground, a process not known when the project was first approved. The oldest preserved terrace was cemented by calcrete by 40 ka. Alluvial gravels were deposited at the outlet of dry tributary valleys during times of episodic high-energy flow between 26 ka and 28 ka. Finely laminated shelly sands accumulated at 10 ka to form the 5 m terrace. The 2 m terrace was laid down 3.2 ka ago as a slackwater deposit. The lack of high-level alluvial terraces raises doubts over plans to dam the river, since rapid leakage would occur from side valleys and the reservoir would not attain the height needed to generate hydroelectric power. It would submerge all existing arable land along the river. Finally, the presence in the late Holocene alluvium of the sub-fossil gastropods Bulinus truncatus and Biomphalaria pfeifferi, which are

  4. Clay Mineralogy of AN Alluvial Aquifer in a Mountainous, Semiarid Terrain, AN Example from Rifle, Colorado

    Science.gov (United States)

    Elliott, W. C.; Lim, D.; Zaunbrecher, L. K.; Pickering, R. A.; Williams, K. H.; Navarre-Sitchler, A.; Long, P. E.; Noel, V.; Bargar, J.; Qafoku, N. P.

    2015-12-01

    Alluvial sediments deposited along the Colorado River corridor in the semi-arid regions of central to western Colorado can be important hosts for legacy contamination including U, V, As and Se. These alluvial sediments host aquifers which are thought to provide important "hot spots" and "hot moments" for microbiological activity controlling organic carbon processing and fluxes in the subsurface. Relatively little is known about the clay mineralogy of these alluvial aquifers and the parent alluvial sediments in spite of the fact that they commonly include lenses of silt-clay materials. These lenses are typically more reduced than coarser grained materials, but zones of reduced and more oxidized materials are present in these alluvial aquifer sediments. The clay mineralogy of the non-reduced parent alluvial sediments of the alluvial aquifer located in Rifle, CO (USA) is composed of chlorite, smectite, illite, kaolinite and quartz. The clay mineralogy of non-reduced fine-grained materials at Rifle are composed of the same suite of minerals found in the sediments plus a vermiculite-smectite intergrade that occurs near the bottom of the aquifer near the top of the Wasatch Formation. The clay mineral assemblages of the system reflect the mineralogically immature character of the source sediments. These assemblages are consistent with sediments and soils that formed in a moderately low rainfall climate and suggestive of minimal transport of the alluvial sediments from their source areas. Chlorite, smectite, smectite-vermiculite intergrade, and illite are the likely phases involved in the sorption of organic carbon and related microbial redox transformations of metals in these sediments. Both the occurrence and abundance of chlorite, smectite-vermiculite, illite and smectite can therefore exert an important control on the contaminant fluxes and are important determinants of biogeofacies in mountainous, semiarid terrains.

  5. Nanostructured MgTiO{sub 3} thick films obtained by electrophoretic deposition from nanopowders prepared by solar PVD

    Energy Technology Data Exchange (ETDEWEB)

    Apostol, Irina [S.C. IPEE Amiral Trading Impex S.A., 115300 Curtea de Arges (Romania); Mahajan, Amit [Department of Materials and Ceramics Engineering, Centre for Research in Ceramics and Composite Materials, CICECO, University of Aveiro, 3810-093 Aveiro (Portugal); Monty, Claude J.A. [CNRS-PROMES Laboratory, 66120 Font Romeu Odeillo (France); Venkata Saravanan, K., E-mail: venketvs@cutn.ac.in [Department of Materials and Ceramics Engineering, Centre for Research in Ceramics and Composite Materials, CICECO, University of Aveiro, 3810-093 Aveiro (Portugal); Department of Physics, School of Basic and Applied Science, Central University of Tamil Nadu, Thiruvarur 61010 (India)

    2015-12-15

    Highlights: • Obtaining nano-crystalline magnesium titanium oxide powders by solar physical vapor deposition (SPVD) process. And using these nano-powders to obtain thick films on conducting substrates by electrophoretic deposition (EPD). • SPVD is a core innovative, original and environmentally friendly process to prepare nano-materials in a powder form. • Sintered thick films exhibited dielectric constant, ε{sub r} ∼18.3 and dielectric loss, tan δ ∼0.0012 at 1 MHz, which is comparable to the values reported earlier. • New contributions to the pool of information on the preparation of nano-structured MgTiO{sub 3} thick films at low temperatures. • A considerable decrease in synthesis temperature of pure MgTiO{sub 3} thick film was observed by the combination of SPVD and EPD. - Abstract: A novel combination of solar physical vapor deposition (SPVD) and electrophoretic deposition (EPD) that was developed to grow MgTiO{sub 3} nanostructured thick films is presented. Obtaining nanostructured MgTiO{sub 3} thick films, which can replace bulk ceramic components, a major trend in electronic industry, is the main objective of this work. The advantage of SPVD is direct synthesis of nanopowders, while EPD is simple, fast and inexpensive technique for preparing thick films. SPVD technique was developed at CNRS-PROMES Laboratory, Odeillo-Font Romeu, France, while the EPD was performed at University of Aveiro – DeMAC/CICECO, Portugal. The nanopowders with an average crystallite size of about 30 nm prepared by SPVD were dispersed in 50 ml of acetone in basic media with addition of triethanolamine. The obtained well-dispersed and stable suspensions were used for carrying out EPD on 25 μm thick platinum foils. After deposition, films with thickness of about 22–25 μm were sintered in air for 15 min at 800, 900 and 1000 °C. The structural and microstructural characterization of the sintered thick films was carried out using XRD and SEM, respectively. The

  6. Investigation of the electrochemical deposition of thick layers of cadmium telluride

    International Nuclear Information System (INIS)

    Rousset, J.

    2007-04-01

    This research thesis deals with the problem of electrochemical deposition of thick layers of cadmium telluride (CdTe) meeting the requirements of high energy radiation detection. The author first recalls the physicochemical properties of CdTe and the basic principles of radiology. He details the different criteria which define a material for X ray detection. He describes the experimental conditions, the nature and preparation of substrates, and the different electrochemical systems used in this research. He studies the impact of the applied potential on the material properties, and compares previously obtained results available in the literature with those obtained in the chosen pool conditions. He discusses the synthesis of CdTe thick layers for which different methods are tested: static in potential, static in intensity, pulsed. The coatings obtained with a given potential and then with a given current are investigated. Finally, the influence of a thermal treatment in presence or absence of a sintering agent on the morphology, the chemical composition, and the crystalline and electric properties of the deposited material is discussed, and the results of the behaviour under X rays of a electrodeposited layer are presented

  7. Measurement of the thickness of a target deposited in a substrate

    International Nuclear Information System (INIS)

    Martinez Q, E.; Aguilera, E.F.

    1990-12-01

    Being based on the Elastic scattering and in the Energy losses that suffer a projectile to the interacting with the matter, a method that allows to determine the thickness of a target deposited in a more heavy substrate is presented. The obtained results are consistent with that waited and the derived errors of the method are small. The used technique allows to reduce in considerable form the systematic errors coming from the calibration of the equipment. It is considered that this method is applicable in an interval of thickness quite wide and for many materials since it is only necessary to choose the projectile type and the energy of the same one appropriately. (Author)

  8. Thick film laser induced forward transfer for deposition of thermally and mechanically sensitive materials

    International Nuclear Information System (INIS)

    Kattamis, Nicholas T.; Purnick, Priscilla E.; Weiss, Ron; Arnold, Craig B.

    2007-01-01

    Laser forward transfer processes incorporating thin absorbing films can be used to deposit robust organic and inorganic materials but the deposition of more delicate materials has remained elusive due to contamination and stress induced during the transfer process. Here, we present the approach to high resolution patterning of sensitive materials by incorporating a thick film polymer absorbing layer that is able to dissipate shock energy through mechanical deformation. Multiple mechanisms for transfer as a function of incident laser energy are observed and we show viable and contamination-free deposition of living mammalian embryonic stem cells

  9. Depositional environment and provenance of Middle Siwalik ...

    Indian Academy of Sciences (India)

    The sedimentary facies and facies associations within the lithostratigraphic column of the Middle Siwalik rocks show temporal repetition of sedimentary facies associations suggesting oscillation between proximal-, mid- and distal fan setups within a palaeo-alluvial fan depositional environment similar to the depositional ...

  10. Thick CrN/NbN multilayer coating deposited by cathodic arc technique

    Energy Technology Data Exchange (ETDEWEB)

    Araujo, Juliano Avelar; Tschiptschin, Andre Paulo; Souza, Roberto Martins, E-mail: antschip@usp.br [Universidade de Sao Paulo (USP), SP (Brazil); Lima, Nelson Batista de [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2017-01-15

    The production of tribological nanoscale multilayer CrN/NbN coatings up to 6 μm thick by Sputtering/HIPIMS has been reported in literature. However, high demanding applications, such as internal combustion engine parts, need thicker coatings (>30 μm). The production of such parts by sputtering would be economically restrictive due to low deposition rates. In this work, nanoscale multilayer CrN/NbN coatings were produced in a high-deposition rate, industrial-size, Cathodic Arc Physical Vapor Deposition (ARC-PVD) chamber, containing three cathodes in alternate positions (Cr/ Nb/Cr). Four 30 μm thick NbN/CrN multilayer coatings with different periodicities (20, 10, 7.5 and 4 nm) were produced. The coatings were characterized by X-Ray Diffraction (XRD) and Transmission Electron Microscopy (TEM). The multilayer coating system was composed of alternate cubic rock salt CrN and NbN layers, coherently strained due to lattice mismatch. The film grew with columnar morphology through the entire stratified structure. The periodicities adopted were maintained throughout the entire coating. The 20 nm periodicity coating showed separate NbN and CrN peaks in the XRD patterns, while for the lower periodicity (≤10nm) coatings, just one intermediate lattice (d-spacing) was detected. An almost linear increase of hardness with decreasing bilayer period indicates that interfacial effects can dominate the hardening mechanisms. (author)

  11. Distal alluvial fan sediments in early Proterozoic red beds of the Wilgerivier formation, Waterberg Group, South Africa

    Science.gov (United States)

    Van Der Neut, M.; Eriksson, P. G.; Callaghan, C. C.

    The 1900 - 1700 M.a. Waterberg Group belongs to a series of southern African cratonic cover sequences of roughly equivalent age. Red beds of the Wilgerivier Formation comprise sandstones, interbedded with subordinate conglomerates and minor mudrocks. These immature sedimentary rocks exhibit lenticular bedding, radial palaeocurrent patterns and features indicative of both streamflow and gravity-flow deposition. A distal wet alluvial fan palaeoenvironmental setting is envisaged, with fan-deltas forming where alluvial lobes prograded into a lacustrine basin. Intrastratal, diagenetic alteration of ferromagnesian detrital grains and ferruginous grain coatings led to the red colouration of the Wilgerivier sediments.

  12. Facies analysis, depositional environments and paleoclimate of the Cretaceous Bima Formation in the Gongola Sub - Basin, Northern Benue Trough, NE Nigeria

    Science.gov (United States)

    Shettima, B.; Abubakar, M. B.; Kuku, A.; Haruna, A. I.

    2018-01-01

    Facies analysis of the Cretaceous Bima Formation in the Gongola Sub -basin of the Northern Benue Trough northeastern Nigeria indicated that the Lower Bima Member is composed of alluvial fan and braided river facies associations. The alluvial fan depositional environment dominantly consists of debris flow facies that commonly occur as matrix supported conglomerate. This facies is locally associated with grain supported conglomerate and mudstone facies, representing sieve channel and mud flow deposits respectively, and these deposits may account for the proximal alluvial fan region of the Lower Bima Member. The distal fan facies were represented by gravel-bed braided river system of probably Scot - type model. This grade into sandy braided river systems with well developed floodplains facies, forming probably at the lowermost portion of the alluvial fan depositional gradient, where it inter-fingers with basinal facies. In the Middle Bima Member, the facies architecture is dominantly suggestive of deep perennial sand-bed braided river system with thickly developed amalgamated trough crossbedded sandstone facies fining to mudstone. Couplets of shallow channels are also locally common, attesting to the varying topography of the basin. The Upper Bima Member is characterized by shallow perennial sand-bed braided river system composed of successive succession of planar and trough crossbedded sandstone facies associations, and shallower channels of the flashy ephemeral sheetflood sand - bed river systems defined by interbedded succession of small scale trough crossbedded sandstone facies and parallel laminated sandstone facies. The overall stacking pattern of the facies succession of the Bima Formation in the Gongola Sub - basin is generally thinning and fining upwards cycles, indicating scarp retreat and deposition in a relatively passive margin setting. Dominance of kaolinite in the clay mineral fraction of the Bima Formation points to predominance of humid sub - tropical

  13. Effect of Coating Thickness on the Properties of TiN Coatings Deposited on Tool Steels Using Cathodic Arc Pvd Technique

    Science.gov (United States)

    Mubarak, A.; Akhter, Parvez; Hamzah, Esah; Mohd Toff, Mohd Radzi Hj.; Qazi, Ishtiaq A.

    Titanium nitride (TiN) widely used as hard coating material, was coated on tool steels, namely on high-speed steel (HSS) and D2 tool steel by physical vapor deposition method. The study concentrated on cathodic arc physical vapor deposition (CAPVD), a technique used for the deposition of hard coatings for tooling applications, and which has many advantages. The main drawback of this technique, however, is the formation of macrodroplets (MDs) during deposition, resulting in films with rougher morphology. Various standard characterization techniques and equipment, such as electron microscopy, atomic force microscopy, hardness testing machine, scratch tester, and pin-on-disc machine, were used to analyze and quantify the following properties and parameters: surface morphology, thickness, hardness, adhesion, and coefficient of friction (COF) of the deposited coatings. Surface morphology revealed that the MDs produced during the etching stage, protruded through the TiN film, resulting in film with deteriorated surface features. Both coating thickness and indentation loads influenced the hardness of the deposited coatings. The coatings deposited on HSS exhibit better adhesion compared to those on D2 tool steel. Standard deviation indicates that the coating deposited with thickness around 6.7 μm showed the most stable trend of COF versus sliding distance.

  14. A row-charge nuclear cratering explosion in alluvial rocks

    International Nuclear Information System (INIS)

    Kireev, V.V.; Kedrovskij, O.L.; Valentinov, Yu.A.; Myasnikov, K.V.; Nikiforov, G.A.; Prozorov, L.B.; Potapov, V.K.

    1975-01-01

    A brief description is given of the first row-charge nuclear cratering explosion in alluvial rocks carried out on the route of the Pechora-Kolva canal. The authors explain the purposes of the explosion, describe the geological conditions, indicate the emplacement parameters and yields of the charges, present data on the dynamics of development of the explosion and report on its seismic effects. The parameters of the resulting trench cut and the characteristics of the rock ejecta are also given. The possibility of using nuclear explosions for hydrotechnological projects requiring large excavations in a thick stratum of weak water-bearing rocks is considered

  15. Thickness Dependence of Optoelectrical Properties of Mo-Doped In2O3 Films Deposited on Polyethersulfone Substrates by Ion-Beam-Assisted Evaporation

    Directory of Open Access Journals (Sweden)

    Chin-Chiuan Kuo

    2010-01-01

    Full Text Available Indium molybdenum oxide (IMO films were deposited onto the polyethersulfone (PES substrates by ion-beam-assisted evaporation (IBAE deposition at low temperature in this study. The effects of film thickness on their optical and electrical properties were investigated. The results show that the deposited IMO films exhibit a preferred orientation of B(222. The electrical resistivity of the deposited film initially reduces then subsequently increases with film thickness. The IMO film with the lowest resistivity of 7.61 × 10−4 ohm-cm has been achieved when the film thickness is 120 nm. It exhibits a satisfactory surface roughness pv of 8.75 nm and an average visible transmittance of 78.7%.

  16. Magnetic properties of Pr-Fe-B thick-film magnets deposited on Si substrates with glass buffer layer

    Science.gov (United States)

    Nakano, M.; Kurosaki, A.; Kondo, H.; Shimizu, D.; Yamaguchi, Y.; Yamashita, A.; Yanai, T.; Fukunaga, H.

    2018-05-01

    In order to improve the magnetic properties of PLD-made Pr-Fe-B thick-film magnets deposited on Si substrates, an adoption of a glass buffer layer was carried out. The glass layer could be fabricated under the deposition rate of approximately 70 μm/h on a Si substrate using a Nd-YAG pulse laser in the vacuum atmosphere. The use of the layer enabled us to reduce the Pr content without a mechanical destruction and enhance (BH)max value by approximately 20 kJ/m3 compared with the average value of non-buffer layered Pr-Fe-B films with almost the same thickness. It is also considered that the layer is also effective to apply a micro magnetization to the films deposited on Si ones.

  17. Synthesis of thick diamond films by direct current hot-cathode plasma chemical vapour deposition

    CERN Document Server

    Jin Zeng Sun; Bai Yi Zhen; Lu Xian Yi

    2002-01-01

    The method of direct current hot-cathode plasma chemical vapour deposition has been established. A long-time stable glow discharge at large discharge current and high gas pressure has been achieved by using a hot cathode in the temperature range from 1100 degree C to 1500 degree C and non-symmetrical configuration of the poles, in which the diameter of the cathode is larger than that of anode. High-quality thick diamond films, with a diameter of 40-50 mm and thickness of 0.5-4.2 mm, have been synthesized by this method. Transparent thick diamond films were grown over a range of growth rates between 5-10 mu m/h. Most of the thick diamond films have thermal conductivities of 10-12 W/K centre dot cm. The thick diamond films with high thermal conductivity can be used as a heat sink of semiconducting laser diode array and as a heat spreading and isolation substrate of multichip modules. The performance can be obviously improved

  18. Estimation of soft sediment thickness in Kuala Lumpur based on microtremor observation data

    Science.gov (United States)

    Chiew, Chang Chyau; Cheah, Yi Ben; Tan, Chin Guan; Lau, Tze Liang

    2017-10-01

    Seismic site effect is one of the major concerns in earthquake engineering. Soft ground tends to amplify the seismic wave in surficial geological layers. The determination of soft ground thickness on the surface layers of the earth is an important input for seismic hazard assessment. This paper presents an easy and convenient approach to estimate the soft sediment thickness at the site using microtremor observation technique. A total number of 133 survey points were conducted in selected sites around Kuala Lumpur area using a microtremor measuring instrument, but only 103 survey points contributed to the seismic microzonation and sediment thickness plots. The bedrock of Kuala Lumpur area is formed by Kenny Hill Formation, limestone, granite, and the Hawthornden Schist; however, the thickness of surface soft ground formed by alluvial deposits, mine tailings, and residual soils remains unknown. Hence, the predominant frequency of the ground in each site was determined based on Nakamura method. A total number of 14 sites with known depth to bedrock from the supply of geotechnical reports in the study area were determined. An empirical correlation was developed to relate the ground predominant frequency and soft ground thickness. This correlation may contribute to local soil underlying the subsurface of Kuala Lumpur area. The finding provides an important relationship for engineers to estimate the soft ground thickness in Kuala Lumpur area based on the dynamic characteristics of the ground measured from microtremor observation.

  19. Process-structure-property relationships of micron thick gadolinium oxide films deposited by reactive electron beam-physical vapor deposition (EB-PVD)

    Science.gov (United States)

    Grave, Daniel A.

    Gadolinium oxide (Gd2O3) is an attractive material for solid state neutron detection due to gadolinium's high thermal neutron capture cross section. Development of neutron detectors based on Gd2 O3 requires sufficiently thick films to ensure neutron absorption. In this dissertation work, the process-structure-property relationships of micron thick Gd2O3 films deposited by reactive electron-beam physical vapor deposition (EB-PVD) were studied. Through a systematic design of experiments, fundamental studies were conducted to determine the effects of processing conditions such as deposition temperature, oxygen flow rate, deposition rate, and substrate material on Gd2O3 film crystallographic phase, texture, morphology, grain size, density, and surface roughness. Films deposited at high rates (> 5 A/s) were examined via x-ray diffraction (XRD) and Raman spectroscopy. Quantitative phase volume calculations were performed via a Rietveld refinement technique. All films deposited at high rates were found to be fully monoclinic or mixed cubic/monoclinic phase. Generally, increased deposition temperature and increased oxygen flow resulted in increased cubic phase volume. As film thickness increased, monoclinic phase volume increased. Grazing incidence x-ray diffraction (GIXRD) depth profiling analysis showed that cubic phase was only present under large incidence angle (large penetration depth) measurements, and after a certain point, only monoclinic phase was grown. This was confirmed by transmission electron microscopy (TEM) analysis with selected area diffraction (SAD). Based on this information, a large compressive stress was hypothesized to cause the formation of the monoclinic phase and this hypothesis was confirmed by demonstrating the existence of a stress induced phase transition. An experiment was designed to introduce compressive stress into the Gd2O 3 films via ion beam assisted deposition (IBAD). This allowed for systematic increase in compressive stress while

  20. Model, prediction, and experimental verification of composition and thickness in continuous spread thin film combinatorial libraries grown by pulsed laser deposition

    International Nuclear Information System (INIS)

    Bassim, N. D.; Schenck, P. K.; Otani, M.; Oguchi, H.

    2007-01-01

    Pulsed laser deposition was used to grow continuous spread thin film libraries of continuously varying composition as a function of position on a substrate. The thickness of each component that contributes to a library can be empirically modeled to a bimodal cosine power distribution. We deposited ternary continuous spread thin film libraries from Al 2 O 3 , HfO 2 , and Y 2 O 3 targets, at two different background pressures of O 2 : 1.3 and 13.3 Pa. Prior to library deposition, we deposited single component calibration films at both pressures in order to measure and fit the thickness distribution. Following the deposition and fitting of the single component films, we predict both the compositional coverage and the thickness of the libraries. Then, we map the thickness of the continuous spread libraries using spectroscopic reflectometry and measure the composition of the libraries as a function of position using mapping wavelength-dispersive spectrometry (WDS). We then compare the compositional coverage of the libraries and observe that compositional coverage is enhanced in the case of 13.3 Pa library. Our models demonstrate linear correlation coefficients of 0.98 for 1.3 Pa and 0.98 for 13.3 Pa with the WDS

  1. Temperature-dependent evolution of the wetting layer thickness during Ge deposition on Si(001).

    Science.gov (United States)

    Bergamaschini, R; Brehm, M; Grydlik, M; Fromherz, T; Bauer, G; Montalenti, F

    2011-07-15

    The evolution of the wetting layer (WL) thickness during Ge deposition on Si(001) is analyzed with the help of a rate-equation approach. The combined role of thickness, island volume and shape-dependent chemical potentials is considered. Several experimental observations, such as WL thinning following the pyramid-to-dome transformation, are captured by the model, as directly demonstrated by a close comparison with photoluminescence measurements (PL) on samples grown at three different temperatures. The limitations of the model in describing late stages of growth are critically addressed.

  2. Effect of thickness on structural, electrical, optical and magnetic properties of Co and Al doped ZnO films deposited by sol-gel route

    Energy Technology Data Exchange (ETDEWEB)

    Sharma, Mamta [Department of Electronic Science, University of Delhi South Campus, New Delhi 110021 (India); Mehra, R.M. [Department of Electronic Science, University of Delhi South Campus, New Delhi 110021 (India)], E-mail: rammehra2003@yahoo.com

    2008-12-30

    This paper reports deposition and characterization of Zn{sub 0.94}Co{sub 0.05}Al{sub 0.01}O films of thickness ranging from 70 nm to 400 nm. These films were deposited on a glass (Corning, 7059) substrate using sol-gel route. The films have been characterized to study their structural, electrical, optical and magnetic properties. X-ray diffraction (XRD) and atomic force microscopy (AFM) were used to study the crystallinity and growth mode of the films. The films deposited up to a thickness of 200 nm showed improvement in crystallinity and preferential c-axis orientation. A transition in the growth mode from vertical (c-axis) to lateral (a and b-axis) was observed with further increase in the thickness of the film. The average transmittance of the films for thickness less than 200 nm was above 80% in the visible region which decreased at higher thickness of the film. The resistivity of the film was found to decrease with increase in thickness up to 200 nm. Ferromagnetism, at room temperature, was confirmed for 200 nm and 400 nm thick films.

  3. Effect of thickness on structural, electrical, optical and magnetic properties of Co and Al doped ZnO films deposited by sol-gel route

    International Nuclear Information System (INIS)

    Sharma, Mamta; Mehra, R.M.

    2008-01-01

    This paper reports deposition and characterization of Zn 0.94 Co 0.05 Al 0.01 O films of thickness ranging from 70 nm to 400 nm. These films were deposited on a glass (Corning, 7059) substrate using sol-gel route. The films have been characterized to study their structural, electrical, optical and magnetic properties. X-ray diffraction (XRD) and atomic force microscopy (AFM) were used to study the crystallinity and growth mode of the films. The films deposited up to a thickness of 200 nm showed improvement in crystallinity and preferential c-axis orientation. A transition in the growth mode from vertical (c-axis) to lateral (a and b-axis) was observed with further increase in the thickness of the film. The average transmittance of the films for thickness less than 200 nm was above 80% in the visible region which decreased at higher thickness of the film. The resistivity of the film was found to decrease with increase in thickness up to 200 nm. Ferromagnetism, at room temperature, was confirmed for 200 nm and 400 nm thick films.

  4. Potentiometric Surface of the Alluvial Aquifer and Hydrologic Conditions in the Juana Diaz area, Puerto Rico, June 29 - July 1, 2005

    Science.gov (United States)

    Rodriguez, Jose M.; Santigo-Rivera, Luis; Gómez-Gómez, Fernando

    2006-01-01

    A synoptic survey of the hydrologic conditions in the Juana Diaz area, Puerto Rico, was conducted between June 29 and July 1, 2005, to define the spatial distribution of the potentiometric surface of the alluvial aquifer. The study area encompasses 21 square miles of the more extensive South Coastal Plain Alluvial Aquifer system and is bounded along the north by foothills of the Cordillera Central mountain chain, to the south by the Caribbean Sea, the east by the Rio Descalabrado and to the west by the Rio Inabon. Ground water in the Juana Diaz area is in the Quaternary-age alluvial deposits and the middle-Tertiary age Ponce Limestone and Juana Diaz Formation (Giusti, 1968). The hydraulic properties of the Ponce Limestone in the Juana Diaz area are unknown, and the Juana Diaz Formation is a unit of poor permeability due to its high clay content. Consequently, the Ponce Limestone and the Juana Diaz Formation are generally considered to be the base of the alluvial aquifer in the Juana Diaz area with ground-water flow occurring primarily within the alluvial deposits. The potentiometric-surface map of the alluvial aquifer was delineated using ground-water level measurements taken at existing wells. The water-level measurements were taken at wells that were either not pumping during the survey or were shut down for a brief period. In the latter case, a recovery period of 30 minutes was allowed for the drawdown in the wellbore to achieve a near static level position representative of the aquifer at the measurement point. Land-surface altitude from U.S. Geological Survey (USGS) 1:20,000 scale topographic maps (Playa de Ponce, Ponce, Rio Descalabrado, and Santa Isabel) were used to refer ground-water levels to mean sea level datum (National Geodetic Vertical Datum of 1929). In addition to the ground-water level measurements, the potentiometricsurface contours were delineated using hydrologic features, such as drainage ditches and saturated intermittent streams that were

  5. Reconnaissance map showing thickness of volcanic ash deposits in the greater Hilo area, Hawaii

    Science.gov (United States)

    Buchanan-Banks, Jane M.

    1983-01-01

    This study was undertaken to determine the thickness and distribution of volcanic ash deposits in the greater Hilo area, Hawaii, as a step toward evaluating their susceptibility to failure during earthquake shaking. On several occasions their instability has resulted in serious damage. For example, the 1868 earthquake (m=7+), following a prolonged rainy period, caused a debris flow of hillside ash deposits that killed 31 people in Wood Valley (Bringham, 1869). The 1973 Honomu earthquake (m=6.2) resulted in more damage from shaking to areas underlain by ash deposits in the older part of Hilo than in other areas, and soil slips in ash, as well as rockfalls, were common along the roads north of town (Nielsen and others, 1977). 

  6. Basement and climate controls on proximal depositional systems in continental settings

    NARCIS (Netherlands)

    Ventra, D.

    2011-01-01

    This doctoral dissertation discusses the sedimentology and dynamics of selected, modern and ancient clastic depositional systems (alluvial fans and colluvial aprons) at continental basin margins. The focus on single depositional systems gave the opportunity to devote particular attention to

  7. Growth of thick La2Zr2O7 buffer layers for coated conductors by polymer-assisted chemical solution deposition

    International Nuclear Information System (INIS)

    Zhang, Xin; Zhao, Yong; Xia, Yudong; Guo, Chunsheng; Cheng, C.H.; Zhang, Yong; Zhang, Han

    2015-01-01

    Highlights: • We develops a low-cost and high-efficient technology of fabricating LZO buffer layers. • Sufficient thickness LZO buffer layers have been obtained on NiW (2 0 0) alloy substrate. • Highly biaxially textured YBCO thin film has been deposited on LZO/NiW. - Abstract: La 2 Zr 2 O 7 (LZO) epitaxial films have been deposited on LaAlO 3 (LAO) (1 0 0) single-crystal surface and bi-axially textured NiW (2 0 0) alloy substrate by polymer-assisted chemical solution deposition, and afterwards studied with XRD, SEM and AFM approaches. Highly in-plane and out-of-plane oriented, dense, smooth, crack free and with a sufficient thickness (>240 nm) LZO buffer layers have been obtained on LAO (1 0 0) single-crystal surface; The films deposited on NiW (2 0 0) alloy substrate are also found with high degree in-plane and out-of-plane texturing, good density with pin-hole-free, micro-crack-free nature and a thickness of 300 nm. Highly epitaxial 500 nm thick YBa 2 Cu 3 O 7−x (YBCO) thin film exhibits the self-field critical current density (Jc) reached 1.3 MA/cm 2 at 77 K .These results demonstrate the LZO epi-films obtained with current techniques have potential to be a buffer layer for REBCO coated conductors

  8. Capturing and modelling high-complex alluvial topography with UAS-borne laser scanning

    Science.gov (United States)

    Mandlburger, Gottfried; Wieser, Martin; Pfennigbauer, Martin

    2015-04-01

    Due to fluvial activity alluvial forests are zones of highest complexity and relief energy. Alluvial forests are dominated by new and pristine channels in consequence of current and historic flood events. Apart from topographic features, the vegetation structure is typically very complex featuring, both, dense under story as well as high trees. Furthermore, deadwood and debris carried from upstream during periods of high discharge within the river channel are deposited in these areas. Therefore, precise modelling of the micro relief of alluvial forests using standard tools like Airborne Laser Scanning (ALS) is hardly feasible. Terrestrial Laser Scanning (TLS), in turn, is very time consuming for capturing larger areas as many scan positions are necessary for obtaining complete coverage due to view occlusions in the forest. In the recent past, the technological development of Unmanned Arial Systems (UAS) has reached a level that light-weight survey-grade laser scanners can be operated from these platforms. For capturing alluvial topography this could bridge the gap between ALS and TLS in terms of providing a very detailed description of the topography and the vegetation structure due to the achievable very high point density of >100 points per m2. In our contribution we demonstrate the feasibility to apply UAS-borne laser scanning for capturing and modelling the complex topography of the study area Neubacher Au, an alluvial forest at the pre-alpine River Pielach (Lower Austria). The area was captured with Riegl's VUX-1 compact time-of-flight laser scanner mounted on a RiCopter (X-8 array octocopter). The scanner features an effective scan rate of 500 kHz and was flown in 50-100 m above ground. At this flying height the laser footprint is 25-50 mm allowing mapping of very small surface details. Furthermore, online waveform processing of the backscattered laser energy enables the retrieval of multiple targets for single laser shots resulting in a dense point cloud of

  9. Depositional conditions on an alluvial fan at the turn of the Weichselian to the Holocene – a case study in the Żmigród Basin, southwest Poland

    Directory of Open Access Journals (Sweden)

    Zieliński Paweł

    2016-06-01

    Full Text Available Presented are the results of research into the fluvio-aeolian sedimentary succession at the site of Postolin in the Żmigród Basin, southwest Poland. Based on lithofacies analysis, textural analysis, Thermoluminescence and Infrared-Optical Stimulated Luminescence dating and GIS analysis, three lithofacies units were recognised and their stratigraphic succession identified: 1 the lower unit was deposited during the Pleni-Weichselian within a sand-bed braided river functioning under permafrost conditions within the central part of the alluvial fan; 2 the middle unit is the result of aeolian deposition and fluvial redeposition on the surface of the fan during long-term permafrost and progressive decrease of humidity of the climate at the turn of the Pleni- to the Late Weichselian; 3 the upper unit accumulated following the development of longitudinal dunes at the turn of the Late Weichselian to the Holocene; the development of dunes was interrupted twice by the form being stabilised by vegetation and soil development.

  10. Geologic structure of the Yucaipa area inferred from gravity data, San Bernardino and Riverside Counties, California

    Science.gov (United States)

    Mendez, Gregory O.; Langenheim, V.E.; Morita, Andrew; Danskin, Wesley R.

    2016-09-30

    In the spring of 2009, the U.S. Geological Survey, in cooperation with the San Bernardino Valley Municipal Water District, began working on a gravity survey in the Yucaipa area to explore the three-dimensional shape of the sedimentary fill (alluvial deposits) and the surface of the underlying crystalline basement rocks. As water use has increased in pace with rapid urbanization, water managers have need for better information about the subsurface geometry and the boundaries of groundwater subbasins in the Yucaipa area. The large density contrast between alluvial deposits and the crystalline basement complex permits using modeling of gravity data to estimate the thickness of alluvial deposits. The bottom of the alluvial deposits is considered to be the top of crystalline basement rocks. The gravity data, integrated with geologic information from surface outcrops and 51 subsurface borings (15 of which penetrated basement rock), indicated a complex basin configuration where steep slopes coincide with mapped faults―such as the Crafton Hills Fault and the eastern section of the Banning Fault―and concealed ridges separate hydrologically defined subbasins.Gravity measurements and well logs were the primary data sets used to define the thickness and structure of the groundwater basin. Gravity measurements were collected at 256 new locations along profiles that totaled approximately 104.6 km (65 mi) in length; these data supplemented previously collected gravity measurements. Gravity data were reduced to isostatic anomalies and separated into an anomaly field representing the valley fill. The ‘valley-fill-deposits gravity anomaly’ was converted to thickness by using an assumed, depth-varying density contrast between the alluvial deposits and the underlying bedrock.To help visualize the basin geometry, an animation of the elevation of the top of the basement-rocks was prepared. The animation “flies over” the Yucaipa groundwater basin, viewing the land surface

  11. Controls on sediment cover in bedrock-alluvial channels of the Henry Mountains, Utah

    Science.gov (United States)

    Hodge, R. A.; Yager, E.; Johnson, J. P.; Tranmer, A.

    2017-12-01

    The location and extent of sediment cover in bedrock-alluvial channels influences sediment transport rates, channel incision and instream ecology. However, factors affecting sediment cover and how it responds to changes in relative sediment supply have rarely been quantitatively evaluated in field settings. Using field surveys and SFM analysis of channel reach topography, we quantified sediment cover and channel properties including slope, width, grain size distributions, and bedrock and alluvial roughness in North Wash and Chelada Creek in the Henry Mountains, Utah. Along reaches where upstream sediment supply does not appear to be restricted, we find that the fraction of local bedrock exposure increases as a function of local relative transport capacity . In a downstream section of Chelada Creek, decadal-scale sediment supply has been restricted by an upstream culvert that has caused a backwater effect and corresponding upstream deposition. In this section, alluvial cover is uncorrelated with local stream power. To test the impact of relative sediment supply on sediment cover, a 1D sediment transport model was used to predict the equilibrium sediment cover in Chelada Creek under varying flow and sediment supply conditions. Sediment transport in each model section was predicted using the partial cover model of Johnson (2015), which accounts for differences in bedrock and alluvial roughness on critical shear stress and flow resistance. Model runs in which sediment supply was approximately equal to mean transport capacity produced a pattern of sediment cover which best matched the field observations upstream of the culvert. However, runs where sediment supply was under-capacity produced the pattern most similar to field observations downstream of the culvert, consistent with our field-based interpretations. Model results were insensitive to initial sediment cover, and equilibrium was relatively quickly reached, suggesting that the channel is responsive to changes in

  12. Quaternary alluvial fans of Ciudad Juárez, Chihuahua, northern México: OSL ages and implications for climatic history of the region

    Science.gov (United States)

    Zúñiga de León, David; Kershaw, Stephen; Mahan, Shannon

    2016-01-01

    Alluvial fans formed from sediments derived from erosion of the Juárez Mountains in northernmost México have a significant flood impact on the Ciudad Juárez, which is built on the fan system. The northern part of Ciudad Juárez is the most active; further south, older parts of the fan, upon which the rest of the city is built, were largely eroded by natural processes prior to human habitation and subsequently modified only recently by human construction. Three aeolian sand samples, collected from the uppermost (youngest) parts of the fan system in the city area, in places where human intervention has not disturbed the sediment, and constrain the latest dates of fan building. Depositional ages of the Quaternary alluvial fans were measured using Optically Stimulated Luminescence (OSL) on aeolian sands that have inter-fingered with alluvial fan material. These dates are: a) sample P1, 31 ka; b) sample P2, 41 ka; c) sample P3, 74 ka, between Oxygen Isotope Stages (OIS) 3 to 5. They demonstrate that fan development, in the area now occupied by the city, terminated in the Late Pleistocene, immediately after what we interpret to have been an extended period of erosion without further deposition, lasting from the Late Pleistocene to Holocene. The three dates broadly correspond to global glacial periods, implying that the cool, dry periods may reflect periods of aeolian transport in northern México in between phases that were wetter to form the alluvial fans. Alluvial fan margins inter-finger with fluvial terrace sediments derived from the Río Bravo, indicating an additional component of fan dissection by Río Bravo lateral erosion, presumed to be active during earlier times than our OSL ages, but these are not yet dated. Further dating is required to ascertain the controls on the fan and fluvial system.

  13. Sedimentology of Fraser River delta peat deposits: a modern analogue for some deltaic coals

    Energy Technology Data Exchange (ETDEWEB)

    Styan, W B; Bustin, R M

    1984-01-01

    On the Recent lobe of the Fraser River delta, peat accumulation has actively occurred on the distal lower delta plain, the transition between upper and lower delta plains, and the alluvial plain. Distal lower delta plain peats developed from widespread salt and brackish marshes and were not influenced appreciably by fluvial activity. Lateral development of the marsh facies were controlled by compaction and eustatic sea-level rise. The resulting thin, discontinuous peat network contains numerous silty clay partings and high concentrations of sulphur. Freshwater marsh facies formed but were later in part eroded and altered by transgressing marine waters. Peats overlie a thin, fluvial, fining-upward sequence which in turn overlies a thick, coarsening-upward, prodelta-delta front succession. Lower- upper delta plain peats initially developed from interdistributary brackish marshes and were later fluvially influenced as the delta prograded. Thickest peats occur in areas where distributary channels were abandoned earliest. Sphagnum biofacies replace sedge-grass-dominated communities except along active channel margins, where the sedge-grass facies is intercalated with overbank and splay deposits. Peats are underlain by a relatively thin sequence of fluvial deposits which in turn is underlain by a major coarsening-upward delta front and pro-delta sequence. Alluvial plain peats accumulated in back swamp environments of the flood plain. Earliest sedge-clay and gyttja peats developed over thin fining-upward fluvial cycles or are interlaminated with fine-grained flood deposits. Thickest accumulations occur where peat fills small avulsed flood channels. Overlying sedge-grass and sphagnum biofacies are horizontally stratified and commonly have sharp boundaries with fine-grained flood sediments. At active channel margins, however, sedge-grass peats are intercalated with natural levee deposits consisting of silty clay.

  14. Room temperature synthesis of indium tin oxide nanotubes with high precision wall thickness by electroless deposition

    Directory of Open Access Journals (Sweden)

    Mario Boehme

    2011-02-01

    Full Text Available Conductive nanotubes consisting of indium tin oxide (ITO were fabricated by electroless deposition using ion track etched polycarbonate templates. To produce nanotubes (NTs with thin walls and small surface roughness, the tubes were generated by a multi-step procedure under aqueous conditions. The approach reported below yields open end nanotubes with well defined outer diameter and wall thickness. In the past, zinc oxide films were mostly preferred and were synthesized using electroless deposition based on aqueous solutions. All these methods previously developed, are not adaptable in the case of ITO nanotubes, even with modifications. In the present work, therefore, we investigated the necessary conditions for the growth of ITO-NTs to achieve a wall thickness of around 10 nm. In addition, the effects of pH and reductive concentrations for the formation of ITO-NTs are also discussed.

  15. Residence times and alluvial architecture of a sediment superslug in response to different flow regimes

    Science.gov (United States)

    Moody, John A.

    2017-10-01

    A superslug was deposited in a basin in the Colorado Front Range Mountains as a consequence of an extreme flood following a wildfire disturbance in 1996. The subsequent evolution of this superslug was measured by repeat topographic surveys (31 surveys from 1996 through 2014) of 18 cross sections approximately uniformly spaced over 1500 m immediately above the basin outlet. These surveys allowed the identification within the superslug of chronostratigraphic units deposited and eroded by different geomorphic processes in response to different flow regimes. Over the time period of the study, the superslug went through aggradation, incision, and stabilization phases that were controlled by a shift in geomorphic processes from generally short-duration, episodic, large-magnitude floods that deposited new chronostratigraphic units to long-duration processes that eroded units. These phases were not contemporaneous at each channel cross section, which resulted in a complex response that preserved different chronostratigraphic units at each channel cross section having, in general, two dominant types of alluvial architecture-laminar and fragmented. Age and transit-time distributions for these two alluvial architectures evolved with time since the extreme flood. Because of the complex shape of the distributions they were best modeled by two-parameter Weibull functions. The Weibull scale parameter approximated the median age of the distributions, and the Weibull shape parameter generally had a linear relation that increased with time since the extreme flood. Additional results indicated that deposition of new chronostratigraphic units can be represented by a power-law frequency distribution, and that the erosion of units decreases with depth of burial to a limiting depth. These relations can be used to model other situations with different flow regimes where vertical aggradation and incision are dominant processes, to predict the residence time of possible contaminated

  16. Heat deposition, damage, and tritium breeding characteristics in thick liquid wall blanket concepts

    International Nuclear Information System (INIS)

    Youssef, M.Z.; Abdou, M.A.

    2000-01-01

    The advanced power extraction (APEX) study aims at exploring new and innovative blanket concepts that can efficiently extract power from fusion devices with high neutron wall load. Among the concepts under investigation is the free liquid FW/liquid blanket concept in which a fast flowing liquid FW (∼2-3 cm) is followed by thick flowing blanket (B) of ∼40-50 cm thickness with minimal amount of structure. The liquid FW/B are contained inside the vacuum vessel (VV) with a shielding zone (S) located either behind the VV and outside the vacuum boundary (case A) or placed after the FW/B and inside the VV (case B). In this paper we investigate the nuclear characteristics of this concept in terms of: (1) attenuation capability of the liquid FW/B/S and protection of the VV and magnet against radiation damage; (2) profiles of tritium production rate and tritium breeding ratio (TBR) for several liquid candidates; and (3) profiles of heat deposition rate and power multiplication. The candidate liquid breeders considered are Li, Flibe, Li-Sn, and Li-Pb. Parameters varied are (1) FW/B thickness, L, (2) Li-6 enrichment and (3) thickness of the shield

  17. Sources, lability and solubility of Pb in alluvial soils of the River Trent catchment, U.K

    International Nuclear Information System (INIS)

    Izquierdo, M.; Tye, A.M.; Chenery, S.R.

    2012-01-01

    Alluvial soils are reservoirs of metal contaminants such as Pb that originate from many different sources and are integrated temporally and spatially through erosional and depositional processes. In this study the source, lability and solubility of Pb were examined in a range of alluvial soils from the middle and lower River Trent and its tributary the River Dove using Pb isotope apportionment and isotopic dilution. All samples were collected within 10 m of the river bank to represent the soil that is most likely to be remobilised during bank erosion. Paired samples were taken from the topsoil (0–15 cm) and subsoil (35–50 cm) to assess differences with depth. Lead concentrations in soil ranged from 43 to 1282 mg/kg. The lability of soil Pb varied between 9 and 56% of total metal concentration whilst Pb concentrations in pore water varied between 0.2 and 6.5 μg/L. There was little difference in the % Pb lability between paired top and sub soils, possibly because soil characteristics such as pH, iron oxides and clay content were generally similar; a result of the recycling of eroded and deposited soils within the river system. Soil pH was found to be negatively correlated with % Pb lability. Source apportionment using 206 Pb/ 207 Pb and 208 Pb/ 207 Pb ratios showed that the isotopic ratios of Pb in the total, labile and solution pools fitted along a mixing line between Broken Hill Type (‘BHT’) Pb, used as an additive in UK petrol, and the local coal/Southern Pennine ore Pb. Various anomalies were found in the Pb isotopes of the bankside alluvial soils which were explained by point source pollution. Statistically significant differences were found between (i) the isotopic composition of Pb in the total soil pool and the labile/solution pools and (ii) the isotopic composition of Pb in the labile and solution pools, suggesting an enrichment of recent non-Pennine sources of Pb entering the soils in the labile and solution pools. -- Highlights: ► The labile

  18. Morphometric Analysis and Delineation of Debris Flow Susceptible Alluvial Fans in the Philippines after the 2015 Koppu and Melor Typhoon Events

    Science.gov (United States)

    Llanes, F.; Rodolfo, K. S.; Lagmay, A. M. A.

    2017-12-01

    On 17 October 2015, Typhoon Koppu brought heavy rains that generated debris flows in the municipalities of Bongabon, Laur, and Gabaldon in Nueva Ecija province. Roughly two months later on 15 December, Typhoon Melor made landfall in the province of Oriental Mindoro, bringing heavy rains that also generated debris flows in multiple watersheds in the municipality of Baco. Despite not being in the direct path of the typhoon, debris flows were triggered in Bongabon, Gabaldon, and Laur, whereas old debris-flow deposits were remobilized in Dingalan, a coastal town in Aurora province adjacent to Gabaldon. During the onslaught of Typhoons Koppu and Melor, landslides of rock, soil, and debris converged in the mountain stream networks where they were remobilized into debris flows that destroyed numerous houses and structures situated on alluvial fans. Satellite images before and after the two typhoons were compared to calculate the deposit extents on the fans and to determine the number and extent of landslides on each watershed. The affected alluvial fans were investigated in the field to determine whether they are debris flow or flood-prone, using a set of established geomorphic and sedimentary characteristics that differentiate deposits of the two processes. Melton ratio, watershed length, and other significant morphometric indices were calculated and analyzed for the affected watersheds using geographic information system (GIS) and high-resolution digital terrain models. A GIS model that can delineate debris flow susceptible alluvial fans in the Philippines was derived and developed from the analysis. Limitations of the model are discussed, as well as recommendations to improve and refine it.

  19. Constraining the thickness of polar ice deposits on Mercury using the Mercury Laser Altimeter and small craters in permanently shadowed regions

    Science.gov (United States)

    Deutsch, Ariel N.; Head, James W.; Chabot, Nancy L.; Neumann, Gregory A.

    2018-05-01

    Radar-bright deposits at the poles of Mercury are located in permanently shadowed regions, which provide thermally stable environments for hosting and retaining water ice on the surface or in the near subsurface for geologic timescales. While the areal distribution of these radar-bright deposits is well characterized, their thickness, and thus their total mass and volume, remain poorly constrained. Here we derive thickness estimates for selected water-ice deposits using small, simple craters visible within the permanently shadowed, radar-bright deposits. We examine two endmember scenarios: in Case I, these craters predate the emplacement of the ice, and in Case II, these craters postdate the emplacement of the ice. In Case I, we find the difference between estimated depths of the original unfilled craters and the measured depths of the craters to find the estimated infill of material. The average estimated infilled material for 9 craters assumed to be overlain with water ice is ∼ 41-14+30 m, where 1-σ standard error of the mean is reported as uncertainty. Reported uncertainties are for statistical errors only. Additional systematic uncertainty may stem from georeferencing the images and topographic datasets, from the radial accuracy of the altimeter measurements, or from assumptions in our models including (1) ice is flat in the bowl-shaped crater and (2) there is negligible ice at the crater rims. In Case II, we derive crater excavation depths to investigate the thickness of the ice layer that may have been penetrated by the impact. While the absence of excavated regolith associated with the small craters observed suggests that impacts generally do not penetrate through the ice deposit, the spatial resolution and complex illumination geometry of images may limit the observations. Therefore, it is not possible to conclude whether the small craters in this study penetrate through the ice deposit, and thus Case II does not provide a constraint on the ice thickness

  20. Adhesion-enhanced thick copper film deposition on aluminum oxide by an ion-beam-mixed Al seed layer

    International Nuclear Information System (INIS)

    Kim, Hyung-Jin; Park, Jae-Won

    2012-01-01

    We report a highly-adherent 30-μm Cu conductive-path coating on an aluminum-oxide layer anodized on an aluminum-alloy substrate for a metal-printed circuit-board application. A 50-nm Al layer was first coated with an e-beam evaporative deposition method on the anodized oxide, followed by ion bombardment to mix the interfacial region. Subsequently, a Cu coating was deposited onto the mixed seed layer to the designed thickness. Adhesions of the interface were tested by using tape adhesion test, and pull-off tests and showed commercially acceptable adhesions for such thick coating layers. The ion beam mixing (IBM) plays the role of fastening the thin seed coating layer to the substrate and enhancing the adhesion of the Cu conductive path on the anodized aluminum surface.

  1. Residual stress in thick low-pressure chemical-vapor deposited polycrystalline SiC coatings on Si substrates

    Science.gov (United States)

    Choi, D.; Shinavski, R. J.; Steffier, W. S.; Spearing, S. M.

    2005-04-01

    Residual stress in thick coatings of polycrystalline chemical-vapor deposited SiC on Si substrates is a key variable that must be controlled if SiC is to be used in microelectromechanical systems. Studies have been conducted to characterize the residual stress level as a function of deposition temperature, Si wafer and SiC coating thickness, and the ratios of methyltrichlorosilane to hydrogen and hydrogen chloride. Wafer curvature was used to monitor residual stress in combination with a laminated plate analysis. Compressive intrinsic (growth) stresses were measured with magnitudes in the range of 200-300MPa; however, these can be balanced with the tensile stress due to the thermal-expansion mismatch to leave near-zero stress at room temperature. The magnitude of the compressive intrinsic stress is consistent with previously reported values of surface stress in combination with the competition between grain-boundary energy and elastic strain energy.

  2. Structure and corrosion behavior of sputter deposited cerium oxide based coatings with various thickness on Al 2024-T3 alloy substrates

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Yuanyuan [College of Materials Science and Engineering, Chongqing University, Chongqing 400045 (China); Materials Research Center, Department of Materials Science and Engineering, Missouri University of Science and Technology, Rolla, MO 65409 (United States); Huang, Jiamu, E-mail: huangjiamu@cqu.edu.cn [College of Materials Science and Engineering, Chongqing University, Chongqing 400045 (China); Claypool, James B.; Castano, Carlos E. [Materials Research Center, Department of Materials Science and Engineering, Missouri University of Science and Technology, Rolla, MO 65409 (United States); O’Keefe, Matthew J., E-mail: mjokeefe@mst.edu [Materials Research Center, Department of Materials Science and Engineering, Missouri University of Science and Technology, Rolla, MO 65409 (United States)

    2015-11-15

    Highlights: • Crystalline CeO{sub 2} coatings are deposited on Al 2024-T3 alloys by magnetron sputtering. • The crystal size and internal stress both increased with the thickness of CeO{sub 2} coating. • The ∼210 nm thick coating has the highest adhesion strength to the Al alloy substrate. • The ∼900 nm thick coating increased the corrosion resistance two orders of magnitude. • CeO{sub 2} coatings provide good cathodic inhibition for Al alloys by acting as physical barriers. - Abstract: Cerium oxide based coatings from ∼100 to ∼1400 nm in thickness were deposited onto Al 2024-T3 alloy substrates by magnetron sputtering of a 99.99% pure CeO{sub 2} target. The crystallite size of CeO{sub 2} coatings increased from 15 nm to 46 nm as the coating thickness increased from ∼100 nm to ∼1400 nm. The inhomogeneous lattice strain increased from 0.36% to 0.91% for the ∼100 nm to ∼900 nm thick coatings and slightly decreased to 0.89% for the ∼1400 nm thick coating. The highest adhesion strength to Al alloy substrates was for the ∼210 nm thick coating, due to a continuous film coverage and low internal stress. Electrochemical measurements indicated that sputter deposited crystalline CeO{sub 2} coatings acted as physical barriers that provide good cathodic inhibition for Al alloys in saline solution. The ∼900 nm thick CeO{sub 2} coated sample had the best corrosion performance that increased the corrosion resistance by two orders magnitude and lowered the cathodic current density 30 times compared to bare Al 2024-T3 substrates. The reduced defects and exposed surface, along with suppressed charge mobility, likely accounts for the improved corrosion performance as coating thickness increased from ∼100 nm to ∼900 nm. The corrosion performance decreased for ∼1400 nm thick coatings due in part to an increase in coating defects and porosity along with a decrease in adhesion strength.

  3. Low-temperature plasma-enhanced atomic layer deposition of 2-D MoS2 : Large area, thickness control and tuneable morphology

    NARCIS (Netherlands)

    Sharma, A.; Verheijen, M.A.; Wu, L.; Karwal, S.; Vandalon, V.; Knoops, H.C.M.; Sundaram, R.S.; Hofmann, J.P.; Kessels, W.M.M.; Bol, A.A.

    2018-01-01

    Low-temperature controllable synthesis of monolayer-to-multilayer thick MoS2 with tuneable morphology is demonstrated by using plasma enhanced atomic layer deposition (PEALD). The characteristic self-limiting ALD growth with a growth-per-cycle of 0.1 nm per cycle and digital thickness control down

  4. Robust TaNx diffusion barrier for Cu-interconnect technology with subnanometer thickness by metal-organic plasma-enhanced atomic layer deposition

    International Nuclear Information System (INIS)

    Kim, H.; Detavenier, C.; Straten, O. van der; Rossnagel, S.M.; Kellock, A.J.; Park, D.-G.

    2005-01-01

    TaN x diffusion barriers with good barrier properties at subnanometer thickness were deposited by plasma-enhanced atomic layer deposition (PE-ALD) from pentakis(dimethylamino)Ta. Hydrogen and/or nitrogen plasma was used as reactants to produce TaN x thin films with a different nitrogen content. The film properties including the carbon and oxygen impurity content were affected by the nitrogen flow during the process. The deposited film has nanocrystalline grains with hydrogen-only plasma, while the amorphous structure was obtained for nitrogen plasma. The diffusion barrier properties of deposited TaN films for Cu interconnects have been studied by thermal stress test based on synchrotron x-ray diffraction. The results indicate that the PE-ALD TaN films are good diffusion barriers even at a small thickness as 0.6 nm. Better diffusion barrier properties were obtained for higher nitrogen content. Based on a diffusion kinetics analysis, the nanocrystalline microstructure of the films was responsible for the better diffusion barrier properties compared to polycrystalline PE-ALD TaN films deposited from TaCl 5

  5. Influence of the thickness of electrochemically deposited polyaniline used as hole transporting layer on the behaviour of polymer light-emitting diodes

    Energy Technology Data Exchange (ETDEWEB)

    Alonso, J.L. [Dpto. de Fisica y Arquitectura de Computadores, Universidad Miguel Hernandez, Av. de la Universidad s/n, Ed. Torrepinet, 03202, Elche, Alicante (Spain)], E-mail: j.l.alonso@umh.es; Ferrer, J.C. [Dpto. de Fisica y Arquitectura de Computadores, Universidad Miguel Hernandez, Av. de la Universidad s/n, Ed. Torrepinet, 03202, Elche, Alicante (Spain); Cotarelo, M.A.; Montilla, F. [Dpto. de Quimica Fisica e Instituto Universitario de Materiales de Alicante, Apdo. de Correos 99, E-03080, Alicante (Spain); Fernandez de Avila, S. [Dpto. de Fisica y Arquitectura de Computadores, Universidad Miguel Hernandez, Av. de la Universidad s/n, Ed. Torrepinet, 03202, Elche, Alicante (Spain)

    2009-02-27

    An experimental study about the influence of the thickness of electrochemically deposited polyaniline (PANI), used as hole-transporting layer, on the behaviour of polymer light emitting diodes is presented. Two sets of devices with a different conjugated polymer used as active layer were prepared. Poly(9-vinylcarbazole) was used for the first type of devices, whereas Poly[2-methoxy-5-(3',7'-dimethyloctyloxy)-1,4-phenylene-vinylene] was used for the second type. Each set consists of five polymeric diodes in which the hole-transporting layer has been varied. In one case of each set no layer was deposited, in other one a Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) layer was deposited, and in the rest of the diodes a different thickness of electrochemically deposited PANI was employed. The optic and electronic characterization of the devices show that controlling the thickness of the PANI hole transporting layer, both the maximum emission peak of the electroluminescence curves and the driving voltage could be tuned. Furthermore, an exponential behaviour has been demonstrated for the maximum intensity of the electroluminescence curves as a function of the applied excitation voltage between anode and cathode.

  6. Influence of the thickness of electrochemically deposited polyaniline used as hole transporting layer on the behaviour of polymer light-emitting diodes

    International Nuclear Information System (INIS)

    Alonso, J.L.; Ferrer, J.C.; Cotarelo, M.A.; Montilla, F.; Fernandez de Avila, S.

    2009-01-01

    An experimental study about the influence of the thickness of electrochemically deposited polyaniline (PANI), used as hole-transporting layer, on the behaviour of polymer light emitting diodes is presented. Two sets of devices with a different conjugated polymer used as active layer were prepared. Poly(9-vinylcarbazole) was used for the first type of devices, whereas Poly[2-methoxy-5-(3',7'-dimethyloctyloxy)-1,4-phenylene-vinylene] was used for the second type. Each set consists of five polymeric diodes in which the hole-transporting layer has been varied. In one case of each set no layer was deposited, in other one a Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) layer was deposited, and in the rest of the diodes a different thickness of electrochemically deposited PANI was employed. The optic and electronic characterization of the devices show that controlling the thickness of the PANI hole transporting layer, both the maximum emission peak of the electroluminescence curves and the driving voltage could be tuned. Furthermore, an exponential behaviour has been demonstrated for the maximum intensity of the electroluminescence curves as a function of the applied excitation voltage between anode and cathode

  7. Analysis on sequence stratigraphy and depositional systems of Mangbang formation, upper tertiary in Longchuanjiang basin

    International Nuclear Information System (INIS)

    Sun Zexuan; Yao Yifeng; Chen Yong; Li Guoxin

    2004-01-01

    Longchuanjiang basin is a small Cenozoic intramontane down-faulted basin. This paper, combining the Pliocene structure, the volcanic activities and the sedimentation of the basin, analyses the sequence stratigraphy and the depositional systems of Mangbang formation (the cover of the basin). Based on the analysis of depositional systems of Mangbang formation, the depositional pattern of Pliocene in Longchuanjiang basin is set up. It is suggested that because of the fast accumulation in early down-faulted zone during Pliocene time, the alluvial fan depositional system was dominated at that time. During the middle-late period, the alluvial fan entered the lake forming a combination of fan-fandelta-lacustrine depositional systems. Authors propose a view point that the formation of Mangbang formation sequence was constrained by multistage tectonic movement, and three structural sequences were established, and system tracts were divided. (authors)

  8. Online estimation of wax deposition thickness in single-phase sub-sea pipelines based on acoustic chemometrics: A feasibility study

    OpenAIRE

    Halstensen, Maths; Arvoh, Benjamin Kaku; Amundsen, Lene; Hoffmann, Rainer

    2012-01-01

    Wax deposition in sub-sea oil producing pipelines is a concern to the oil producing companies. The deposition of wax in pipelines can cause serious economic implications if not monitored and controlled. Several researchers have developed models and investigated the deposition of wax in crude oil pipelines. As of today, there is no off the shelf instrument available for reliable online estimation of the wax depo- sition thickness in sub-sea pipelines. Acoustic chemometrics was applied to inves...

  9. Enhancement in (BHmax of PLD-made isotropic Nd-Fe-B thick film magnets deposited on Si substrates

    Directory of Open Access Journals (Sweden)

    M. Nakano

    2017-05-01

    Full Text Available Increase in Nd contents of a PLD-made isotropic Nd-Fe-B thick-film magnet enabled us to enhance the thickness of the film magnet deposited on a Si substrate because the linear expansion coefficient of Nd is an intermediate value between Nd2Fe14B and Si. The large amount of Nd, however, degraded the residual magnetic polarization and (BHmax. In the study, we reduced the Nd contents of each Nd-Fe-B film by inserting a Nd or a Nd-rich Nd-Fe-B buffer layer between a Nd-Fe-B film and a Si substrate in order to suppress the mechanical destruction together with the improvement in magnetic properties. It was found that the mechanical property of a Nd-Fe-B film comprising the Nd-Fe-B buffer layer in the thickness range from 10 to 60 μm was superior than that of a sample with the Nd buffer layer. Resultantly, an average (BHmax value of Nd-Fe-B films with each Nd-Fe-B buffer layer deposited on Si substrates could be enhanced by approximately 15 kJ/m3 compared to that of non-buffer-layered films.

  10. Effect of precursor concentration and film thickness deposited by layer on nanostructured TiO2 thin films

    Science.gov (United States)

    Affendi, I. H. H.; Sarah, M. S. P.; Alrokayan, Salman A. H.; Khan, Haseeb A.; Rusop, M.

    2018-05-01

    Sol-gel spin coating method is used in the production of nanostructured TiO2 thin film. The surface topology and morphology was observed using the Atomic Force Microscopy (AFM) and Field Emission Scanning Electron Microscopy (FESEM). The electrical properties were investigated by using two probe current-voltage (I-V) measurements to study the electrical resistivity behavior, hence the conductivity of the thin film. The solution concentration will be varied from 14.0 to 0.01wt% with 0.02wt% interval where the last concentration of 0.02 to 0.01wt% have 0.01wt% interval to find which concentrations have the highest conductivity then the optimized concentration's sample were chosen for the thickness parameter based on layer by layer deposition from 1 to 6 layer. Based on the result, the lowest concentration of TiO2, the surface becomes more uniform and the conductivity will increase. As the result, sample of 0.01wt% concentration have conductivity value of 1.77E-10 S/m and will be advanced in thickness parameter. Whereas in thickness parameter, the 3layer deposition were chosen as its conductivity is the highest at 3.9098E9 S/m.

  11. Fluvial to Lacustrine Facies Transitions in Gale Crater, Mars

    Science.gov (United States)

    Sumner, Dawn Y.; Williams, Rebecca M. E.; Schieber, Juergen; Palucis, Marisa C.; Oehler, Dorothy Z.; Mangold, Nicolas; Kah, Linda C.; Gupta, Sanjeev; Grotzinger, John P.; Grant, John A., III; hide

    2015-01-01

    NASA's Curiosity rover has documented predominantly fluvial sedimentary rocks along its path from the landing site to the toe of the Peace Vallis alluvial fan (0.5 km to the east) and then along its 8 km traverse across Aeolis Palus to the base of Aeolis Mons (Mount Sharp). Lacustrine facies have been identified at the toe of the Peace Vallis fan and in the lowermost geological unit exposed on Aeolis Mons. These two depositional systems provide end members for martian fluvial/alluvial-lacustrine facies models. The Peace Vallis system consisted of an 80 square kilometers alluvial fan with decimeter-thick, laterally continuous fluvial sandstones with few sedimentary structures. The thin lacustrine unit associated with the fan is interpreted as deposited in a small lake associated with fan runoff. In contrast, fluvial facies exposed over most of Curiosity's traverse to Aeolis Mons consist of sandstones with common dune-scale cross stratification (including trough cross stratification), interbedded conglomerates, and rare paleochannels. Along the southwest portion of the traverse, sandstone facies include south-dipping meter-scale clinoforms that are interbedded with finer-grained mudstone facies, interpreted as lacustrine. Sedimentary structures in these deposits are consistent with deltaic deposits. Deltaic deposition is also suggested by the scale of fluvial to lacustrine facies transitions, which occur over greater than 100 m laterally and greater than 10 m vertically. The large scale of the transitions and the predicted thickness of lacustrine deposits based on orbital mapping require deposition in a substantial river-lake system over an extended interval of time. Thus, the lowermost, and oldest, sedimentary rocks in Gale Crater suggest the presence of substantial fluvial flow into a long-lived lake. In contrast, the Peace Vallis alluvial fan onlaps these older deposits and overlies a major unconformity. It is one of the youngest deposits in the crater, and

  12. The analyzing stratum formation and sediment environment using TEM for finding sandstone type uranium deposits in Mahuangquan area

    International Nuclear Information System (INIS)

    Zhao Xigang; He Jianguo; Zhao Cuiping; Lou Hansheng

    2010-01-01

    Transient electromagnetic method (TEM) is used to detect deep geological information for insidious sandstone type uranium deposits in Mahuangquan area. TEM surveying data is processed to build the relation between resistance rate and different petrology, to ensure three large electronic strata, and to explain the space position of sediment center and alluvial fan. Combining with ore control factors of sandstone type uranium deposit, it can conclude that the slope area and the alluvial fan are the key areas for further exploration work. (authors)

  13. The effects of two thick film deposition methods on tin dioxide gas sensor performance.

    Science.gov (United States)

    Bakrania, Smitesh D; Wooldridge, Margaret S

    2009-01-01

    This work demonstrates the variability in performance between SnO(2) thick film gas sensors prepared using two types of film deposition methods. SnO(2) powders were deposited on sensor platforms with and without the use of binders. Three commonly utilized binder recipes were investigated, and a new binder-less deposition procedure was developed and characterized. The binder recipes yielded sensors with poor film uniformity and poor structural integrity, compared to the binder-less deposition method. Sensor performance at a fixed operating temperature of 330 °C for the different film deposition methods was evaluated by exposure to 500 ppm of the target gas carbon monoxide. A consequence of the poor film structure, large variability and poor signal properties were observed with the sensors fabricated using binders. Specifically, the sensors created using the binder recipes yielded sensor responses that varied widely (e.g., S = 5 - 20), often with hysteresis in the sensor signal. Repeatable and high quality performance was observed for the sensors prepared using the binder-less dispersion-drop method with good sensor response upon exposure to 500 ppm CO (S = 4.0) at an operating temperature of 330 °C, low standard deviation to the sensor response (±0.35) and no signal hysteresis.

  14. The Effects of Two Thick Film Deposition Methods on Tin Dioxide Gas Sensor Performance

    Directory of Open Access Journals (Sweden)

    Smitesh D. Bakrania

    2009-08-01

    Full Text Available This work demonstrates the variability in performance between SnO2 thick film gas sensors prepared using two types of film deposition methods. SnO2 powders were deposited on sensor platforms with and without the use of binders. Three commonly utilized binder recipes were investigated, and a new binder-less deposition procedure was developed and characterized. The binder recipes yielded sensors with poor film uniformity and poor structural integrity, compared to the binder-less deposition method. Sensor performance at a fixed operating temperature of 330 ºC for the different film deposition methods was evaluated by exposure to 500 ppm of the target gas carbon monoxide. A consequence of the poor film structure, large variability and poor signal properties were observed with the sensors fabricated using binders. Specifically, the sensors created using the binder recipes yielded sensor responses that varied widely (e.g., S = 5 – 20, often with hysteresis in the sensor signal. Repeatable and high quality performance was observed for the sensors prepared using the binder-less dispersion-drop method with good sensor response upon exposure to 500 ppm CO (S = 4.0 at an operating temperature of 330 ºC, low standard deviation to the sensor response (±0.35 and no signal hysteresis.

  15. Pb(Zr,Ti)O3-Pb(Mn1/3Nb2/3)O3 piezoelectric thick films by aerosol deposition

    International Nuclear Information System (INIS)

    Ryu, Jungho; Choi, Jong-Jin; Hahn, Byung-Dong; Yoon, Woon-Ha; Lee, Byoung-Kuk; Choi, Joon Hwan; Park, Dong-Soo

    2010-01-01

    Piezoelectric thick films of Pb(Zr,Ti)O 3 -Pb(Mn 1/3 Nb 2/3 )O 3 (PZT-PMnN) with Zr:Ti ratios ranging from 0.45:0.55 to 0.60:0.40 were fabricated on a platinized silicon wafer by aerosol deposition (AD). All the films were deposited with a thickness of 10 μm with high density. By adding PMnN to 57:43 PZT, a dielectric constant as low as ∼660 was achieved while the effective piezoelectric constant was over 140 pC/N. PZT-PMnN with a Zr:Ti ratio of 57:43 thus showed a maximum piezoelectric voltage constant (g 33 ) of 23.8 x 10 -3 Vm/N and is a good candidate for high quality thick films for application to high-energy density or high sensitivity, piezoelectric energy harvesters and sensors.

  16. Preliminary Groundwater Simulations To Compare Different Reconstruction Methods of 3-d Alluvial Heterogeneity

    Science.gov (United States)

    Teles, V.; de Marsily, G.; Delay, F.; Perrier, E.

    Alluvial floodplains are extremely heterogeneous aquifers, whose three-dimensional structures are quite difficult to model. In general, when representing such structures, the medium heterogeneity is modeled with classical geostatistical or Boolean meth- ods. Another approach, still in its infancy, is called the genetic method because it simulates the generation of the medium by reproducing sedimentary processes. We developed a new genetic model to obtain a realistic three-dimensional image of allu- vial media. It does not simulate the hydrodynamics of sedimentation but uses semi- empirical and statistical rules to roughly reproduce fluvial deposition and erosion. The main processes, either at the stream scale or at the plain scale, are modeled by simple rules applied to "sediment" entities or to conceptual "erosion" entities. The model was applied to a several kilometer long portion of the Aube River floodplain (France) and reproduced the deposition and erosion cycles that occurred during the inferred climate periods (15 000 BP to present). A three-dimensional image of the aquifer was gener- ated, by extrapolating the two-dimensional information collected on a cross-section of the floodplain. Unlike geostatistical methods, this extrapolation does not use a statis- tical spatial analysis of the data, but a genetic analysis, which leads to a more realistic structure. Groundwater flow and transport simulations in the alluvium were carried out with a three-dimensional flow code or simulator (MODFLOW), using different rep- resentations of the alluvial reservoir of the Aube River floodplain: first an equivalent homogeneous medium, and then different heterogeneous media built either with the traditional geostatistical approach simulating the permeability distribution, or with the new genetic model presented here simulating sediment facies. In the latter case, each deposited entity of a given lithology was assigned a constant hydraulic conductivity value. Results of these

  17. Upstream effects of dams on alluvial channels: state-of-the-art and future challenges

    Science.gov (United States)

    Liro, Maciej

    2017-04-01

    More than 50,000 large dams (with the height above 15 m) operate all over the world and, thus, they significantly disturb water and sediment transport in river systems. These disturbances are recognized as one of the most important factors shaping river morphology in the Anthropocene. Downstream effects of dams have been well documented in numerous case studies and supported by predictions from existing models. In contrast, little is known on the upstream effects of dams on alluvial channels. This review highlights the lack of studies on sedimentological, hydromorphological and biogeomorphological adjustments of alluvial rivers in the base-level raised zones of backwater upstream of dam reservoirs where water level fluctuations occur. Up to date, it has been documented that backwater effects may facilitate fine and coarse sediment deposition, increase groundwater level, provide higher and more frequent channel and floodplain inundation and lead to significant morphological changes. But there have been no studies quantifying short- and long-term consequences of these disturbances for the hydromorphological and biogeomorphological feedbacks that control development of alluvial channels. Some recent studies carried out on gravel-bed and fine-grained bed rivers show that the above mentioned disturbances facilitate vegetation expansion on exposed channel sediments and floodplain influencing river morphology, which suggests that backwater area of alluvial rivers may be treated as the hotspot of bio-geomorphological changes in a fluvial system. To set the stage for future research on upstream effects of dams, this work presents the existing state-of-art and proposes some hypotheses which may be tested in future studies. This study was carried out within the scope of the Research Project 2015/19/N/ST10/01526 financed by the National Science Centre of Poland

  18. Timing and nature of alluvial fan and strath terrace formation in the Eastern Precordillera of Argentina

    Science.gov (United States)

    Hedrick, Kathryn; Owen, Lewis A.; Rockwell, Thomas K.; Meigs, Andrew; Costa, Carlos; Caffee, Marc W.; Masana, Eulalia; Ahumada, Emilio

    2013-11-01

    Sixty-eight 10Be terrestrial cosmogenic nuclide (TCN) surface exposure ages are presented to define the timing of alluvial fan and strath terrace formation in the hyper-arid San Juan region of the Argentine Precordillera. This region is tectonically active, and numerous fault scarps traverse Quaternary landforms. The three study sites, Marquesado strath complex, Loma Negra alluvial fan and Carpintería strath complex reveal a history of alluvial fan and strath terrace development over the past ˜225 ka. The Marquesado complex Q3m surface dates to ˜17 ± 3 ka, whereas the Loma Negra Q1ln, Q2ln, Q3ln, Q4ln, and Q5ln surfaces date to ˜24 ± 3 ka, ˜48 ± 2 ka, ˜65 ± 13 ka, ˜105 ± 21 ka, and ˜181 ± 29 ka, respectively. The Carpintería complex comprises eight surfaces that have been dated and include the Q1c (˜23 ± 3 ka), Q2c (˜5 ± 5 ka), Q3ac (˜25 ± 12 ka), Q3bc (˜29 ± 15 ka), Q4c (˜61 ± 12 ka), Q5c (˜98 ± 18 ka), Q6c (˜93 ± 18 ka), and Q7c (˜212 ± 37 ka). 10Be TCN depth profile data for the Loma Negra alluvial fan complex and Carpintería strath terrace complex, as well as OSL ages on some Carpintería deposits, aid in refining surface ages for comparison with local and global climate proxies, and additionally offer insights into inheritance and erosion rate values for TCNs (˜10 × 10410Be atoms/g of SiO2 and ˜5 m Ma-1, respectively). Comparison with other alluvial fan studies in the region show that less dynamic and older preserved surfaces occur in the Carpintería and Loma Negra areas with only younger alluvial fan surfaces preserved both to the north and south. These data in combination with that of other studies illustrate broad regional agreement between alluvial fan and strath terrace ages, which suggests that climate is the dominant forcing agent in the timing of terrace formation in this region.

  19. Residence times and alluvial architecture of a sediment superslug in response to different flow regimes

    Science.gov (United States)

    Moody, John A.

    2017-01-01

    A superslug was deposited in a basin in the Colorado Front Range Mountains as a consequence of an extreme flood following a wildfire disturbance in 1996. The subsequent evolution of this superslug was measured by repeat topographic surveys (31 surveys from 1996 through 2014) of 18 cross sections approximately uniformly spaced over 1500 m immediately above the basin outlet. These surveys allowed the identification within the superslug of chronostratigraphic units deposited and eroded by different geomorphic processes in response to different flow regimes.Over the time period of the study, the superslug went through aggradation, incision, and stabilization phases that were controlled by a shift in geomorphic processes from generally short-duration, episodic, large-magnitude floods that deposited new chronostratigraphic units to long-duration processes that eroded units. These phases were not contemporaneous at each channel cross section, which resulted in a complex response that preserved different chronostratigraphic units at each channel cross section having, in general, two dominant types of alluvial architecture—laminar and fragmented. Age and transit-time distributions for these two alluvial architectures evolved with time since the extreme flood. Because of the complex shape of the distributions they were best modeled by two-parameter Weibull functions. The Weibull scale parameter approximated the median age of the distributions, and the Weibull shape parameter generally had a linear relation that increased with time since the extreme flood. Additional results indicated that deposition of new chronostratigraphic units can be represented by a power-law frequency distribution, and that the erosion of units decreases with depth of burial to a limiting depth. These relations can be used to model other situations with different flow regimes where vertical aggradation and incision are dominant processes, to predict the residence time of possible contaminated

  20. Depositional system of the Bayangobi formation, lower cretaceous and its control over in-situ leachable sandstone-type uranium deposits in Chagandelesu area, Inner Mongolia

    International Nuclear Information System (INIS)

    Zhang Wanliang

    2002-01-01

    Chagandelesu area is situated in the eastern part of Bayangobi basin, Inner Mongolia. In the Early Cretaceous, a detrital rock series (Bayangobi Formation) with a thickness of about 1000 m was formed within a down-faulted basin under the extensional tectonic regime. The Bayangobi Formation is the prospecting target for interlayer oxidation zone sandstone-type uranium deposits, and is divided into three lithologic members: the lower member-- proluvial (alluvial), subaqueous fan or fan-delta facies sediments; the middle member-shallow lacustrine-semi-deep lacustrine-deep lacustrine facies sediments; the upper member-littoral shallow lacustrine or delta facies sediments. The facies order of Bayangobi Formation represents the evolution process of basin water from the shallow (early period) to the deep (middle period) then again to the shallow (late period) level. The Bayangobi Formation composed of a third sequence order reflects respectively a lowstand system tract (LST), a transgressive system tract (TST) and a highstand system tract (HST). The author also makes an analysis on physical properties of psammites of Bayangobi Formation, and proposes that psammites of delta and littoral shallow lacustrine facies are favourable for the formation of interlayer oxidation zone sandstone-type uranium deposits

  1. Large landslides, composed of megabreccia, interbedded in Miocene basin deposits, southeastern Arizona

    Science.gov (United States)

    Krieger, Medora Louise Hooper

    1977-01-01

    The landslides in the Kearny and El Capitan Mountain quadrangles, Pinal and Gila Counties, Ariz., are tabular or lens like masses of megabreccia enclosed in Miocene basin deposits. The megabreccias within individual slide blocks are composed of pervasively brecciated Precambrian and younger formations that remain in normal stratigraphic sequence, indicating that each landslide moved as a fairly coherent mass. The megabreccias consist of fresh, mostly angular rock fragments in a comminuted matrix of the same composition as the fragments. The matrix ranges in amount from sparse to abundant. Where the matrix is sparse, the fragments fit tightly with little or no rotation. Locally fragments are rotated but not moved far; most units within a slide block are lithologically homogeneous. The Kearny landslides are conformably interbedded in steeply east-dipping playa and alluvial deposits. They form map units from a few tens of meters to nearly 4 km long and from less than 1 to 270 m wide. Narrow ridges expose sections through the landslides at about right angles to the direction of movement. The upper (proximal) ends have been eroded; the lower (distal) ends are buried. The El Capitan landslide dips very gently southward. Although partly dissected during erosion of the enclosing alluvial and lakebed deposits, its approximate original outline is still preserved. It forms a thin sheet, 5-15 m thick and at least 3.8 km long; the maximum outcrop width, near its distal end, is about 1.5 km. The Kearny landslides show little evidence of having exerted differential pressure on the underlying soft playa and alluvial deposits, and the contacts with the underlying sediments have little relief. The distal end of the El Capitan landslide, on the other hand, has considerable relief. As the landslide came to an abrupt stop, the end plowed into the underlying sediments, compressing them into fol9.s and forming sandstone dikes. The source of the El Capitan landslide is a well

  2. Effects of alluvial knickpoint migration on floodplain ecology and geomorphology

    Science.gov (United States)

    Larsen, Annegret; May, Jan-Hendrick

    2016-04-01

    Alluvial knickpoints are well described as erosional mechanism within discontinuous ephemeral streams in the semi-arid SW USA. However, alluvial knickpoints occur globally in a wide range of settings and of climate zones, including temperate SE Australia, subtropical Africa, and tropical Australia. Much attention has been given in the scientific literature to the trigger mechanisms of alluvial knickpoints, which can be summarized as: i) threshold phenomena, ii) climate variability and iii) land-use change, or to a combination of these factors. Recently, studies have focused on the timescale of alluvial knickpoint retreat, and the processes, mechanisms and feedbacks with ecology, geomorphology and hydrology. In this study, we compile data from a global literature review with a case study on a tropical river system in Australia affected by re-occurring, fast migrating (140 myr-1) alluvial knickpoint. We highlight the importance of potential water table declines due to channel incision following knickpoint migration, which in turn leads to the destabilization of river banks, and a shift in floodplain vegetation and fire incursion. We hypothesize that the observed feedbacks might also help to understand the broader impacts of alluvial knickpoint migration in other regions, and might explain the drastic effects of knickpoint migration on land cover and land-use in semi-arid areas.

  3. Tensile test of a silicon microstructure fully coated with submicrometer-thick diamond like carbon film using plasma enhanced chemical vapor deposition method

    Science.gov (United States)

    Zhang, Wenlei; Uesugi, Akio; Hirai, Yoshikazu; Tsuchiya, Toshiyuki; Tabata, Osamu

    2017-06-01

    This paper reports the tensile properties of single-crystal silicon (SCS) microstructures fully coated with sub-micrometer thick diamond like carbon (DLC) film using plasma enhanced chemical vapor deposition (PECVD). To minimize the deformations or damages caused by non-uniform coating of DLC, which has high compression residual stress, released SCS specimens with the dimensions of 120 µm long, 4 µm wide, and 5 µm thick were coated from the top and bottom side simultaneously. The thickness of DLC coating is around 150 nm and three different bias voltages were used for deposition. The tensile strength improved from 13.4 to 53.5% with the increasing of negative bias voltage. In addition, the deviation in strength also reduced significantly compared to bare SCS sample.

  4. Influence of film thickness on structural, optical, and electrical properties of spray deposited antimony doped SnO{sub 2} thin films

    Energy Technology Data Exchange (ETDEWEB)

    Yadav, Abhijit A., E-mail: aay_physics@yahoo.co.in

    2015-09-30

    Transparent conducting antimony doped SnO{sub 2} thin films with varying thickness were deposited by chemical spray pyrolysis technique from non-aqueous solvent Propan-2-ol. The effect of film thickness on the properties of antimony doped SnO{sub 2} thin films have been studied. X-ray diffraction measurements showed tetragonal crystal structure of as-deposited antimony doped SnO{sub 2} films irrespective of film thickness. The surface morphology of antimony doped SnO{sub 2} thin film is spherical with the continuous distribution of grains. Electrical and optical properties were investigated by Hall Effect and optical measurements. The average optical transmittance of films decreased from 89% to 73% within the visible range (350–850 nm) with increase in film thickness. The minimum value of sheet resistance observed is 4.81 Ω/cm{sup 2}. The lowest resistivity found is 3.76 × 10{sup −4} Ω cm at 660 nm film thickness. - Highlights: • Effect of film thickness on the properties of antimony doped SnO{sub 2} thin films • Crystalline size in the range of 34–37 nm • Average transmittance decreased from 89% to 73% in the visible region. • Minimum sheet resistance of 4.81 Ω/cm{sup 2} • Lowest resistivity is found to be 3.76 × 10{sup −4} Ω cm at 660 nm film thickness.

  5. Deposition of SrTiO3 films by electrophoresis with thickness and particle size control

    International Nuclear Information System (INIS)

    Junior, W.D.M.; Pena, A.F.V.; Souza, A.E.; Santos, G.T.A.; Teixeira, S.R.; Senos, A.M.R.; Longo, E.

    2012-01-01

    The SrTiO3 (ST) is a material that exhibits semiconducting characteristics and interesting electrical properties. In room temperature has a structure of high cubic symmetry. The size of the crystallites of this material directly influences this symmetry, changing its network parameters. ST nanoparticles are obtained by hydrothermal method assisted by microwave (MAH). ST films are prepared by electrophoretic deposition (EPD). Approximately 1 g of the powder is dissolved in 100 ml of acetone and 1.5 ml of triethanolamine. The stainless steel substrates are arranged horizontally in the solution. The depositions are performed for 1-10 min and subjected to a potential difference of 20-100 V. The films were characterized by x-ray diffraction (XRD) and atomic force microscopy (AFM). The characterizations show that it is possible to control both the thickness and size of the crystallites of the film depending on the deposition parameters adopted. (author)

  6. Characterization of Natural Organic Matter in Alluvial Aquifer Sediments: Approaches and Implications for Reactivity

    Science.gov (United States)

    Fox, P. M.; Nico, P. S.; Hao, Z.; Gilbert, B.; Tfaily, M. M.; Devadoss, J.

    2015-12-01

    Sediment-associated natural organic matter (NOM) is an extremely complex assemblage of organic molecules with a wide range of sizes, functional groups, and structures, which is intricately associated with mineral particles. The chemical nature of NOM may control its' reactivity towards metals, minerals, enzymes, and bacteria. Organic carbon concentrations in subsurface sediments are typically much lower than in surface soils, posing a distinct challenge for characterization. In this study, we investigated NOM associated with shallow alluvial aquifer sediments in a floodplain of the Colorado River. Total organic carbon (TOC) contents in these subsurface sediments are typically around 0.1%, but can range from 0.03% up to approximately 1.5%. Even at the typical TOC values of 0.1%, the mass of sediment-associated OC is approximately 5000 times higher than the mass of dissolved OC, representing a large pool of carbon that may potentially be mobilized or degraded under changing environmental conditions. Sediment-associated OC is much older than both the depositional age of the alluvial sediments and dissolved OC in the groundwater, indicating that the vast majority of NOM was sequestered by the sediment long before it was deposited in the floodplain. We have characterized the sediment-bound NOM from two locations within the floodplain with differing physical and geochemical properties. One location has relatively low organic carbon (mineral association across different biogeochemical regimes and assess the potential reactivity of various NOM pools.

  7. Robotic complex for the development of thick steeply-inclined coal seams and ore deposits

    Science.gov (United States)

    Nikitenko, M. S.; Malakhov, Yu V.; Neogi, Biswarup; Chakraborty, Pritam; Banerjee, Dipesu

    2017-09-01

    Proposal for the formulation of robotic complexes for steeply inclined coal seams as a basis of the supportive-enclosing walking module and power support with a controlled outlet for mining industry has been represented in this literature. In mining industry, the available resource base reserves and mineral deposits are concentrated deep down the earth crust leading towards a complicated geological condition i.e. abrupt ore bedding and steeply inclined strata with the high gas content and fire hazard of thick coal stratum, heading against an unfavorable and sometimes human labor life risk during subversive mining. Prevailing towards the development of effective robotic complexes based on the means of “unmanned technologies” for extraction of minerals from hard-to-reach deposits and make sure the safety of underground staff during sublevel mining technology.

  8. TiN films by Atomic Layer Deposition: Growth and electrical characterization down to sub-nm thickness

    NARCIS (Netherlands)

    Van Hao, B.; Wolters, Robertus A.M.; Kovalgin, Alexeij Y.

    2012-01-01

    This study reports on the growth and characterization of TiN thib films obtained by atomic layer deposition at 350-425 ◦C. We observe a growth of the continuous layers from the very beginning of the process, i.e. for a thickness of 0.65 nm, which is equivalent to 3 monolayers of TiN. The film growth

  9. Quaternary allostratigraphy of surficial deposit map units at Yucca Mountain, Nevada: A progress report

    International Nuclear Information System (INIS)

    Lundstrom, S.C.; Wesling, J.R.; Swan, F.H.; Taylor, E.M.; Whitney, J.W.

    1993-01-01

    Surficial geologic mapping at Yucca Mountain, Nevada, is relevant to site characterization studies of paleoclimate, tectonics, erosion, flood hazards, and water infiltration. Alluvial, colluvial, and eolian allostratigraphic map units are defined on the basis of age-related surface characteristics and soil development, as well as lithology and sedimentology indicative of provenance and depositional mode. In gravelly alluvial units, which include interbedded debris flows, the authors observe a useful qualitative correlation between surface and soil properties. Map units of estimated middle Pleistocene age typically have a well-developed, varnished desert pavement, and minimal erosional and preserved depositional microrelief, associated with a soil with a reddened Bt horizon and stage 3 carbonate and silica morphology. Older units have greater erosional relief, an eroded argillic horizon and stage 4 carbonate morphology, whereas younger units have greater preservation of depositional morphology, but lack well-developed pavements, rock varnish, and Bt and Kqm soil horizons. Trench and gully-wall exposures show that alluvial, colluvial and eolian dominated surface units are underlain by multiple buried soils separating sedimentologically similar deposits; this stratigraphy increases the potential for understanding the long-term Quaternary paleoenvironmental history of Yucca Mountain. Age estimates for allostratigraphic units, presently based on uranium-trend dating and regional correlation using soil development, will be further constrained by ongoing dating studies that include tephra identification, uranium-series disequilibrium, and thermoluminescence methods

  10. Estimation of alluvial recharge in the semiarid

    OpenAIRE

    Andrade,Tafnes S.; Montenegro,Suzana M. G. L.; Montenegro,Abelardo A. de A.; Rodrigues,Diogo F. B.

    2014-01-01

    In areas where there is irrigated agriculture, the recuperation of water reserves in alluvial aquifers may occur preferentially due to precipitation. Recharging can be evaluated from variation information of water depth measured in piezometers or observation wells. Thus, the aim of this research is to study the recharge in the alluvial aquifer formed by the Mimoso temporary stream in the semiarid region of Pernambuco (PE), Brazil, using the method of the fluctuation of the water level. This s...

  11. Optimization of the thickness of a conducting polymer, polyaniline, deposited on the surface of poly(vinyl chloride) membranes: a new way to improve their potentiometric response.

    Science.gov (United States)

    Shishkanova, T V; Matejka, P; Král, V; Sedenková, I; Trchová, M; Stejskal, J

    2008-08-29

    Repeated depositions of polyaniline (PANI) have been used to control the thickness of the polymeric film deposited on poly(vinyl chloride) (PVC) membrane surface. The oxidation of aniline was carried out in a dispersion mode, i.e. in the presence of poly(N-vinylpyrrolidone) (PVP). Two kinds of PVC were used for this purpose: a non-plasticized PVC for the study of PANI deposition and PVC, plasticized with nitrophenyl octyl ether (NPOE), as a prototype of a liquid membrane electrode. The results of UV-visible and FTIR spectroscopies and electron microscopy showed that (1) the film thickness increased by about equal increments of approximately 40 nm after each polymerization, and (2) the interface with PVC was constituted by PANI film and adhering PANI-PVP colloidal particles. The various thicknesses of the deposited PANI films affected the potentiometric response of the NPOE/PVC membrane with and without an anion-exchanger. The potentiometric anionic response was observed with a minimal thickness of PANI film on the blank NPOE/PVC membrane. Sensitivity of the PANI film to pH occurred only with a blank NPOE/PVC membrane coated with a thick polymeric film, while it was strongly suppressed by the presence of a lipophilic anion-exchanger, tridodecylmethylammonium chloride (TDDMACl), in the membrane, regardless of the thickness of the polymer film. The thickness of the PANI film did not affect the anionic selectivity pattern of TDDMACl-based membranes to any great extent, but its presence improved and stabilized their potentiometric characteristics (sensitivity, linear-response range).

  12. Revised stratigraphy of the Permian Bainmedart coal measures, northern Prince Charles Mountains, east Antarctica

    Energy Technology Data Exchange (ETDEWEB)

    McLoughlin, S.; Drinnan, A.N. [University of Melbourne, Parkville, Vic. (Australia). School of Botany

    1997-05-01

    The Bainmedart Coal Measures constitute the middle portion of the Permian-Triassic Amery Group, which represents the only substantial Palaeozoic-Mesozoic sedimentary succession exposed in eastern Antarctica outside the Transantarctic Mountains. The coal measures overlie alluvial fan deposits of the Radok Conglomerate and are conformably overlain by the dominantly fluviatile Flagstone Bench Formation. The coal measures were deposited within alluvial settings dominated by north to northeasterly flowing, low-sinuosity rivers chiefly confined to broad, fault-bounded, valleys of the Lambert Graben, a major late Palaeozoic to early Mesozoic failed rift system. Both climatic and local tectonic factors are considered to have been the major influences on the pattern of coal measure sedimentation. Recent mapping has identified a much greater thickness of sediments within the coal measures than had been inferred previously. The Bainmedart Coal Measures are formally subdivided into six members. In ascending stratigraphic order these are: Dart Fields Conglomerate Member ({lt} 3m thick), Toploje Member (300 m thick), Dragons Teeth Member (15-25 m thick), Glossopteris Gully Member (670 m thick), Grainer Member (350 m thick), acid McKinnon Member (530 m thick).

  13. Growth of thick La{sub 2}Zr{sub 2}O{sub 7} buffer layers for coated conductors by polymer-assisted chemical solution deposition

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Xin, E-mail: xzhang@my.swjtu.edu.cn [Key Laboratory of Magnetic Levitation Technologies and Maglev Trains, Ministry of Education of China, Superconductivity and New Energy Center (SNEC), Southwest Jiaotong University, Chengdu, Sichuan 610031 (China); School of Electrical Engineering, Southwest Jiaotong University, Chengdu, Sichuan 610031 (China); Zhao, Yong, E-mail: yzhao@swjtu.edu.cn [Key Laboratory of Magnetic Levitation Technologies and Maglev Trains, Ministry of Education of China, Superconductivity and New Energy Center (SNEC), Southwest Jiaotong University, Chengdu, Sichuan 610031 (China); School of Materials Science and Engineering, University of New South Wales, Sydney, 2052 NSW (Australia); Xia, Yudong [State Key Lab of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 610054 (China); Guo, Chunsheng [Key Laboratory of Magnetic Levitation Technologies and Maglev Trains, Ministry of Education of China, Superconductivity and New Energy Center (SNEC), Southwest Jiaotong University, Chengdu, Sichuan 610031 (China); Cheng, C.H. [School of Materials Science and Engineering, University of New South Wales, Sydney, 2052 NSW (Australia); Zhang, Yong [Key Laboratory of Magnetic Levitation Technologies and Maglev Trains, Ministry of Education of China, Superconductivity and New Energy Center (SNEC), Southwest Jiaotong University, Chengdu, Sichuan 610031 (China); Zhang, Han [Department of Physics, Peking University, Beijing 100871 (China)

    2015-06-15

    Highlights: • We develops a low-cost and high-efficient technology of fabricating LZO buffer layers. • Sufficient thickness LZO buffer layers have been obtained on NiW (2 0 0) alloy substrate. • Highly biaxially textured YBCO thin film has been deposited on LZO/NiW. - Abstract: La{sub 2}Zr{sub 2}O{sub 7} (LZO) epitaxial films have been deposited on LaAlO{sub 3} (LAO) (1 0 0) single-crystal surface and bi-axially textured NiW (2 0 0) alloy substrate by polymer-assisted chemical solution deposition, and afterwards studied with XRD, SEM and AFM approaches. Highly in-plane and out-of-plane oriented, dense, smooth, crack free and with a sufficient thickness (>240 nm) LZO buffer layers have been obtained on LAO (1 0 0) single-crystal surface; The films deposited on NiW (2 0 0) alloy substrate are also found with high degree in-plane and out-of-plane texturing, good density with pin-hole-free, micro-crack-free nature and a thickness of 300 nm. Highly epitaxial 500 nm thick YBa{sub 2}Cu{sub 3}O{sub 7−x} (YBCO) thin film exhibits the self-field critical current density (Jc) reached 1.3 MA/cm{sup 2} at 77 K .These results demonstrate the LZO epi-films obtained with current techniques have potential to be a buffer layer for REBCO coated conductors.

  14. Major Brazilian gold deposits - 1982 to 1999

    Science.gov (United States)

    Thorman, Charles H.; DeWitt, Ed; Maron, Marcos A.; Ladeira, Eduardo A.

    2001-07-01

    Brazil has been a major but intermittent producer of gold since its discovery in 1500. Brazil led the world in gold production during the 18th and early 19th centuries. From the late 19th century to the late 20th century, total mining company and garimpeiro production was small and relatively constant at about 5 to 8 t/year. The discovery of alluvial deposits in the Amazon by garimpeiros in the 1970s and the opening of eight mines by mining companies from 1983 to 1990 fueled a major boom in Brazil's gold production, exceeding 100 t/year in 1988 and 1989. However, garimpeiro alluvial production decreased rapidly in the 1990s, to about 10 t/year by 1999. Company production increased about tenfold from about 4 t/year in 1982 to 40 t in 1992. Production from 1992 to the present remained relatively stable, even though several mines were closed or were in the process of closing and no new major mines were put into production during that period. Based on their production history from 1982-1999, 17 gold mines are ranked as major (>20 t) and minor (3-8 t) mines. From 1982-1999, deposits hosted in Archean rocks produced 66% of the gold in Brazil, whereas deposits in Paleoproterozoic and Neoproterozoic rocks accounted for 19% and 15%, respectively. Deposits in metamorphosed sedimentary rocks, especially carbonate-rich rocks and carbonate iron-formation, yielded the great bulk of the gold. Deposits in igneous rocks were of much less importance. The Archean and Paleoproterozoic terranes of Brazil largely lack base-metal-rich volcanogenic massive sulfide deposits, porphyry deposits, and polymetallic veins and sedimentary exhalative deposits. An exception to this is in the Carajás Mineral Province.

  15. Major brazilian gold deposits - 1982 to 1999

    Science.gov (United States)

    Thorman, C.H.; Dewitt, E.; Maron, M.A.; Ladeira, E.A.

    2001-01-01

    Brazil has been a major but intermittent producer of gold since its discovery in 1500. Brazil led the world in gold production during the 18th and early 19th centuries. From the late 19th century to the late 20th century, total mining company and garimpeiro production was small and relatively constant at about 5 to 8 t/year. The discovery of alluvial deposits in the Amazon by garimpeiros in the 1970s and the opening of eight mines by mining companies from 1983 to 1990 fueled a major boom in Brazil's gold production, exceeding 100 t/year in 1988 and 1989. However, garimpeiro alluvial production decreased 'rapidly in the 1990s, to about 10 t/year by 1999. Company production increased about tenfold from about 4 t/year in 1982 to 40 t in 1992. Production from 1992 to the present remained relatively stable, even though several mines were closed or were in the process of closing and no new major mines were put into production during that period. Based on their production history from 1982-1999, 17 gold mines are ranked as major (> 20 t) and minor (3-8 t) mines. From 1982-1999, deposits hosted in Archean rocks produced 66% of the gold in Brazil, whereas deposits in Paleoproterozoic and Neoproterozoic rocks accounted for 19% and 15%, respectively. Deposits in metamorphosed sedimentary rocks, especially carbonate-rich rocks and carbonate iron-formation, yielded the great bulk of the gold. Deposits in igneous rocks were of much less importance. The Archean and Paleoproterozoic terranes of Brazil largely lack base-metal-rich volcanogenic massive sulfide deposits, porphyry deposits, and polymetallic veins and sedimentary exhalative deposits. An exception to this is in the Caraja??s Mineral Province.

  16. Degradation of the Mitchell River fluvial megafan by alluvial gully erosion increased by post-European land use change, Queensland, Australia

    Science.gov (United States)

    Shellberg, J. G.; Spencer, J.; Brooks, A. P.; Pietsch, T. J.

    2016-08-01

    Along low gradient rivers in northern Australia, there is widespread gully erosion into unconfined alluvial deposits of active and inactive floodplains. On the Mitchell River fluvial megafan in northern Queensland, river incision and fan-head trenching into Pleistocene and Holocene megafan units with sodic soils created the potential energy for a secondary cycle of erosion. In this study, rates of alluvial gully erosion into incipiently-unstable channel banks and/or pre-existing floodplain features were quantified to assess the influence of land use change following European settlement. Alluvial gully scarp retreat rates were quantified at 18 sites across the megafan using recent GPS surveys and historic air photos, demonstrating rapid increases in gully area of 1.2 to 10 times their 1949 values. Extrapolation of gully area growth trends backward in time suggested that the current widespread phase of gullying initiated between 1880 and 1950, which is post-European settlement. This is supported by young optically stimulated luminescence (OSL) dates of gully inset-floodplain deposits, LiDAR terrain analysis, historic explorer accounts of earlier gully types, and archival records of cattle numbers and land management. It is deduced that intense cattle grazing and associated disturbance concentrated in the riparian zones during the dry season promoted gully erosion in the wet season along steep banks, adjacent floodplain hollows and precursor gullies. This is a result of reduced native grass cover, increased physical disturbance of soils, and the concentration of water runoff along cattle tracks, in addition to fire regime modifications, episodic drought, and the establishment of exotic weed and grass species. Geomorphic processes operating over geologic time across the fluvial megafan predisposed the landscape to being pushed by land used change across an intrinsically close geomorphic threshold towards instability. The evolution of these alluvial gullies is discussed

  17. Adsorption behavior of endosulfan on alluvial soil

    International Nuclear Information System (INIS)

    Ashraf, M.; Sherazi, S.T.H.; Nizamani, S.M.; Bhanger, M.I.

    2012-01-01

    The present study was carried out to assess the behavior of endosulfan pesticide in alluvial soil under laboratory conditions. Sandy loam soil was studied to evaluate the fate of applied endosulfan with respect to soil properties. Known amount of endosulfan was added on alluvial soil in PVC column and eluted with 1000 ml of water. Eluents were collected in 10 parts, each of 100 ml. The soil in the column was divided in to three equal parts, each of 10 cm. Each part of the soil and eluents were analyzed for the determination of Endosulfan level using GC- mu ECD and GC-MS techniques. The kinetic and equilibrium adsorption characteristics of endosulfan on sandy loam soil was also studied and found that it follows Ho's pseudo second order and Freundlich isotherm. The present study revealed that a-and beta-Endosulfan was determined efficiently with their degraded products in alluvial soil under laboratory conditions with above mentioned instruments. (author)

  18. Alluvial Diamond Resource Potential and Production Capacity Assessment of Ghana

    Science.gov (United States)

    Chirico, Peter G.; Malpeli, Katherine C.; Anum, Solomon; Phillips, Emily C.

    2010-01-01

    In May of 2000, a meeting was convened in Kimberley, South Africa, and attended by representatives of the diamond industry and leaders of African governments to develop a certification process intended to assure that rough, exported diamonds were free of conflictual concerns. This meeting was supported later in 2000 by the United Nations in a resolution adopted by the General Assembly. By 2002, the Kimberley Process Certification Scheme (KPCS) was ratified and signed by both diamond-producing and diamond-importing countries. Over 70 countries were included as members at the end of 2007. To prevent trade in 'conflict' diamonds while protecting legitimate trade, the KPCS requires that each country set up an internal system of controls to prevent conflict diamonds from entering any imported or exported shipments of rough diamonds. Every diamond or diamond shipment must be accompanied by a Kimberley Process (KP) certificate and be contained in tamper-proof packaging. The objective of this study was to assess the alluvial diamond resource endowment and current production capacity of the alluvial diamond-mining sector in Ghana. A modified volume and grade methodology was used to estimate the remaining diamond reserves within the Birim and Bonsa diamond fields. The production capacity of the sector was estimated using a formulaic expression of the number of workers reported in the sector, their productivity, and the average grade of deposits mined. This study estimates that there are approximately 91,600,000 carats of alluvial diamonds remaining in both the Birim and Bonsa diamond fields: 89,000,000 carats in the Birim and 2,600,000 carats in the Bonsa. Production capacity is calculated to be 765,000 carats per year, based on the formula used and available data on the number of workers and worker productivity. Annual production is highly dependent on the international diamond market and prices, the numbers of seasonal workers actively mining in the sector, and

  19. Radon concentration in the springs of the alluvial fan

    International Nuclear Information System (INIS)

    Horiuchi, Kimiko; Ishii, Tadashi; Kobayashi, Masao

    2003-01-01

    Rokugo alluvial fan is one of the typical stratified alluvial fans which have grown in the east edge of Yokote basin in Akita Prefecture. Many of Rokugo's springs are gushing out from 45 m to 50 m above the sea level where city town have been developed. Mechanism of gushing out of spring is closely bound up with the landform of this area. There is nearly no radon existing in the surface water, but in groundwater, radon concentrations are stable in every stratums and infiltration of groundwater to surface water. We would like to obtain some hydrological information by measuring radon concentration in water samples of Rokugo alluvial fan. (author)

  20. Thick Fe2O3, Fe3O4 films prepared by the chemical solution deposition method

    Czech Academy of Sciences Publication Activity Database

    Buršík, Josef; Košovan, P.; Šubrt, Jan

    2006-01-01

    Roč. 39, č. 2 (2006), s. 85-94 ISSN 0928-0707 R&D Projects: GA ČR GA203/01/0408 Institutional research plan: CEZ:AV0Z40320502 Keywords : chemical solution deposition * thick films * alpha-Fe2O3 Subject RIV: CA - Inorganic Chemistry Impact factor: 1.009, year: 2006

  1. Quaternary alluvial stratigraphy and palaeoclimatic reconstruction at the Thar margin

    DEFF Research Database (Denmark)

    Jain, M.; Tandon, S.K.

    2003-01-01

    Quaternary alluvial record at the Thar desert margin has been examined using the exposed succession along Mahudi, Sabarmati river, Western India. Different alluvial facies, their associations and granulometry have been studied for palaeoenvironmental reconstruction. Clay mineral indices smectite/...

  2. Optimization of laser energy deposition for single-shot high aspect-ratio microstructuring of thick BK7 glass

    Energy Technology Data Exchange (ETDEWEB)

    Garzillo, Valerio; Grigutis, Robertas [Dipartimento di Scienza e Alta Tecnologia, University of Insubria, Via Valleggio 11, I-22100 Como (Italy); Jukna, Vytautas [Centre de Physique Theorique, CNRS, Ecole Polytechnique, Université Paris-Saclay, F-91128 Palaiseau (France); LOA, ENSTA-ParisTech, CNRS, Ecole Polytechnique, Université Paris Saclay, F-91762 Palaiseau (France); Couairon, Arnaud [Centre de Physique Theorique, CNRS, Ecole Polytechnique, Université Paris-Saclay, F-91128 Palaiseau (France); Di Trapani, Paolo [Dipartimento di Scienza e Alta Tecnologia, University of Insubria and CNISM UdR Como, Via Valleggio 11, I-22100 Como (Italy); Jedrkiewicz, Ottavia, E-mail: ottavia.jedrkiewicz@ifn.cnr.it [Istituto di Fotonica e Nanotecnologie, CNR and CNISM UdR Como, Via Valleggio 11, I-22100 Como (Italy)

    2016-07-07

    We investigate the generation of high aspect ratio microstructures across 0.7 mm thick glass by means of single shot Bessel beam laser direct writing. We study the effect on the photoinscription of the cone angle, as well as of the energy and duration of the ultrashort laser pulse. The aim of the study is to optimize the parameters for the writing of a regular microstructure due to index modification along the whole sample thickness. By using a spectrally resolved single pulse transmission diagnostics at the output surface of the glass, we correlate the single shot material modification with observations of the absorption in different portions of the retrieved spectra, and with the absence or presence of spectral modulation. Numerical simulations of the evolution of the Bessel pulse intensity and of the energy deposition inside the sample help us interpret the experimental results that suggest to use picosecond pulses for an efficient and more regular energy deposition. Picosecond pulses take advantage of nonlinear plasma absorption and avoid temporal dynamics effects which can compromise the stationarity of the Bessel beam propagation.

  3. Optical dating using feldspar from Quaternary alluvial and colluvial sediments from SE Brazilian Plateau, Brazil

    International Nuclear Information System (INIS)

    Tatumi, Sonia H.; Peixoto, Maria Naise O.; Moura, Josilda R.S.; Mello, Claudio L.; Carmo, Isabela O.; Kowata, Emilia A.; Yee, Marcio; Brito, Silvio Luiz M.; Gozzi, Giuiliano; Kassab, Luciana R.P.

    2003-01-01

    Opticallly stimulated luminescence (OSL) dating has been applied to a wide variety of materials such as loess, sand dunes, colluvium, alluvium, volcanic products, etc., helping geologic geomorphologic studies. OSL dating results using feldspar crystals extracted from alluvial and colluvial deposits of SE Brazilian Plateau will be presented in this work. The methodology used is based on the regeneration method, with multiple aliquot protocol. A total of 23 sample ages were obtained spanning 6.5-97.2 kyr. Results of radioactive contents and comparison with radiocarbon ages will be discussed

  4. VARIATION IN CROSION/DEPOSITION RATES OVER THE LAST FIFTTY YEARS ON ALLUVIAL FAN SURFACES OF L. PLEISTOCENE-MID HOLOCENE AGE, ESTIMATIONS USING 137CS SOIL PROFILE DATA, AMARGOSA VALLEY, NEVADA

    International Nuclear Information System (INIS)

    C. Harrington; R. Kelly; K.T. Ebert

    2005-01-01

    Variations in erosion and deposition for the last fifty years (based on estimates from 137Cs profiles) on surfaces (Late Pleistocene to Late Holocene in age) making up the Fortymile Wash alluvial fan south of Yucca Mountain, is a function of surface age and of desert pavement development or absence. For purposes of comparing erosion and deposition, the surfaces can be examined as three groups: (1) Late Pleistocene surfaces possess areas of desert pavement development with thin Av or sandy A horizons, formed by the trapping capabilities of the pavements. These zones of deposition are complemented by coppice dune formation on similar parts of the surface. Areas on the surface where no pavement development has occurred are erosional in nature with 0.0 +/- 0.0 cm to 1.5 +/- 0.5 cm of erosion occurring primarily by winds blowing across the surface. Overall these surfaces may show either a small net depositional gain or small erosional loss. (2) Early Holocene surfaces have no well-developed desert pavements, but may have residual gravel deposits in small areas on the surfaces. These surfaces show the most consistent erosional surface areas on which it ranges from 1.0 +/-.01 cm to 2.0+/- .01 cm. Fewer depositional forms are found on this age of surface so there is probably a net loss of 1.5 cm across these surfaces. (3) The Late Holocene surfaces show the greatest variability in erosion and deposition. Overbank deposition during floods cover many edges of these surfaces and coppice dune formation also creates depositional features. Erosion rates are highly variable and range from 0.0 +/- 0.0 to a maximum of 2.0+/-.01. Erosion occurs because of the lack of protection of the surface. However, the common areas of deposition probably result in the surface having a small net depositional gain across these surfaces. Thus, the interchannel surfaces of the Fortymile Wash fan show a variety of erosional styles as well as areas of deposition. The fan, therefore, is a dynamic

  5. Magnetic properties of alluvial soils contaminated with lead, zinc and cadmium

    Science.gov (United States)

    Petrovský, E.; Kapička, A.; Jordanova, N.; Borůvka, L.

    2001-09-01

    Several proxy methods have been used recently to outline increased levels of pollution. One of them is based on measurements of the concentration of (ferri)magnetic minerals of anthropogenic origin. This method has been used recently in the mapping of both polluted and unpolluted areas. In order to validate this method, a more detailed study of links between magnetic parameters characterising the physical shape of magnetic minerals and concentrations of heavy metals is needed. In this study, we analysed the magnetic characteristics of alluvial soils, formed as a result of several breakdowns of wet deposit sink of ashes from a lead ore smelter. The soils were previously analysed for concentration of lead, zinc and cadmium. Our results show that in this case of a shared source of heavy metals and magnetic minerals, simple measurements of magnetic susceptibility discriminate well between polluted and clean areas. In addition, the concentration pattern agrees with the concentrations of the heavy metals studied in deeper soil layers that were not affected by post-depositional changes due to climate and remediation efforts.

  6. Design of flood protection for transportation alignments on alluvial fans

    International Nuclear Information System (INIS)

    French, R.H.

    1991-01-01

    The method of floodplain delineation on alluvial fans developed for the national flood insurance program is modified to provide estimates of peak flood flows at transportation alignments crossing an alluvial fan. The modified methodology divides the total alignment length into drainage design segments and estimates the peak flows that drainage structures would be required to convey as a function of the length of the drainage design segment, the return period of the event, and the location of the alignment on the alluvial fan. An example of the application of the methodology is provided. 16 refs., 5 figs

  7. Enhanced Self-Biased Magnetoelectric Coupling in Laser-Annealed Pb(Zr,Ti)O3 Thick Film Deposited on Ni Foil.

    Science.gov (United States)

    Palneedi, Haribabu; Maurya, Deepam; Geng, Liwei D; Song, Hyun-Cheol; Hwang, Geon-Tae; Peddigari, Mahesh; Annapureddy, Venkateswarlu; Song, Kyung; Oh, Yoon Seok; Yang, Su-Chul; Wang, Yu U; Priya, Shashank; Ryu, Jungho

    2018-04-04

    Enhanced and self-biased magnetoelectric (ME) coupling is demonstrated in a laminate heterostructure comprising 4 μm-thick Pb(Zr,Ti)O 3 (PZT) film deposited on 50 μm-thick flexible nickel (Ni) foil. A unique fabrication approach, combining room temperature deposition of PZT film by granule spray in vacuum (GSV) process and localized thermal treatment of the film by laser radiation, is utilized. This approach addresses the challenges in integrating ceramic films on metal substrates, which is often limited by the interfacial chemical reactions occurring at high processing temperatures. Laser-induced crystallinity improvement in the PZT thick film led to enhanced dielectric, ferroelectric, and magnetoelectric properties of the PZT/Ni composite. A high self-biased ME response on the order of 3.15 V/cm·Oe was obtained from the laser-annealed PZT/Ni film heterostructure. This value corresponds to a ∼2000% increment from the ME response (0.16 V/cm·Oe) measured from the as-deposited PZT/Ni sample. This result is also one of the highest reported values among similar ME composite systems. The tunability of self-biased ME coupling in PZT/Ni composite has been found to be related to the demagnetization field in Ni, strain mismatch between PZT and Ni, and flexural moment of the laminate structure. The phase-field model provides quantitative insight into these factors and illustrates their contributions toward the observed self-biased ME response. The results present a viable pathway toward designing and integrating ME components for a new generation of miniaturized tunable electronic devices.

  8. Essential application of depositional analysis and interpretation in hydrogeologic assessments of contaminated sites

    International Nuclear Information System (INIS)

    Sciacca, J.

    1991-01-01

    In most hydrogeologic studies of contaminated sites, little attention is given to analysis of depositional environments and associated depositional patterns. This analysis is essential for sedimentary deposits present at a majority of these sites. The depositional processes associated with alluvial, fluvial and deltaic environments yield heterogeneity ranging from large to small scale. These processes also yield preferential grain orientations in coarse grained units which result in preferential directions of increased permeability. Studies conducted in fluvial and deltaic petroleum reservoirs have shown varying permeabilities resulting from deposition that strongly control the flow of fluids. The marked heterogeneity evident in the sandy portion of a single 3 to 30-foot thick fluvial point bar deposit can exert significant differences in porous flow. Preferential permeability has been shown parallel to the long axis of fluvial channel sand units while barrier beach sands exhibit preferential permeability perpendicular to the long axis of the sand body. Such controls influence natural flow and transport of contaminants in groundwater. Hydrogeologic studies should: determine the depositional environment and facies present at the site; determine the propensity for heterogeneity within the entire vertical sequence investigated and within the different facies present; assess the potential for preferential permeability within sand bodies; and provide a predictive depositional model to assess potential connections between major high permeability units. Sand unit connections are commonly forced during cross section generation and subsequent aquifer analysis. Failure to incorporate the above objectives in hydrogeologic investigations ignores the basic precept that process controls the distribution of permeability and will result in poor prediction of natural and remedial transport of contaminants in groundwater

  9. Response of alluvial systems to Late Pleistocene climate changes recorded by environmental magnetism in the Añavieja Basin (Iberian Range, NE Spain)

    Energy Technology Data Exchange (ETDEWEB)

    Oliva-Urcia, B.; Muñoz, A.; Larrasoaña, J.C.; Luzon, A.; Perez, A.; Gonzalez, A.; Jiang, Z.; Liu, Q.; Roman-Berdi, T.

    2016-07-01

    Environmental magnetic proxies were analyzed in a relatively monotonous, ~25.3m thick alluvial sedimentary sequence drilled in the Añavieja Basin (NE Spain). Results from the core AÑ2 suggest that the concentrationdependent magnetic parameters mainly reflect variations in the content of detrital magnetite, sourced in the catchment rocks and soils of the basin, via changes in the dynamics of alluvial fans due to temperature changes in the northern hemisphere during the Late Pleistocene. The correspondence between the magnetic proxies and the temperature variations in the North Atlantic region (NGRIP curve) indicates that higher (lower) concentrations and finer (coarser) magnetite grains coincide with warm (cold) periods. We propose that during cold periods, a sparser vegetation cover favored the incoming of higher energy runoff bearing coarser sediments to the basin that are relatively impoverished in magnetite. In contrast, during warm periods, the wider distribution of the vegetation cover associated with the lower runoff energy lead to finer, magnetite-richer sediment input to the basin. Maghemite, presumably of pedogenic origin, appears to be present also in the studied alluvial sediments. Further studies are necessary to unravel its palaeoclimatic significance. (Author)

  10. Length scale hierarchy and spatiotemporal change of alluvial morphologies over the Selenga River delta, Russia

    Science.gov (United States)

    Dong, T. Y.; Nittrouer, J.; McElroy, B. J.; Ma, H.; Czapiga, M. J.; Il'icheva, E.; Pavlov, M.; Parker, G.

    2017-12-01

    The movement of water and sediment in natural channels creates various types of alluvial morphologies that span length scales from dunes to deltas. The behavior of these morphologies is controlled microscopically by hydrodynamic conditions and bed material size, and macroscopically by hydrologic and geological settings. Alluvial morphologies can be modeled as either diffusive or kinematic waves, in accordance with their respective boundary conditions. Recently, it has been shown that the difference between these two dynamic behaviors of alluvial morphologies can be characterized by the backwater number, which is a dimensionless value normalizing the length scale of a morphological feature to its local hydrodynamic condition. Application of the backwater number has proven useful for evaluating the size of morphologies, including deltas (e.g., by assessing the preferential avulsion location of a lobe), and for comparing bedform types across different fluvial systems. Yet two critical questions emerge when applying the backwater number: First, how do different types of alluvial morphologies compare within a single deltaic system, where there is a hydrodynamic transition from uniform to non-uniform flow? Second, how do different types of morphologies evolve temporally within a system as a function of changing water discharge? This study addresses these questions by compiling and analyzing field data from the Selenga River delta, Russia, which include measurements of flow velocity, channel geometry, bed material grain size, and channel slope, as well as length scales of various morphologies, including dunes, island bars, meanders, bifurcations, and delta lobes. Data analyses reveal that the length scale of morphologies decrease and the backwater number increases as flow transitions from uniform to non-uniform conditions progressing downstream. It is shown that the evaluated length scale hierarchy and planform distribution of different morphologies can be used to

  11. Transport and deposition of carbon at catchment scale: stabilization mechanisms approach

    Science.gov (United States)

    Martínez-Mena, María; Almagro, María; Díaz-Pereira, Elvira; García-Franco, Noelia; Boix-Fayos, Carolina

    2016-04-01

    Terrestrial sedimentation buries large amounts of organic carbon (OC) annually, contributing to the terrestrial carbon sink. The temporal significance of this sink will strongly depend on the attributes of the depositional environment, but also on the characteristics of the OC reaching these sites and its stability upon deposition. The fate of the redistributed OC will ultimately depend on the mechanisms of its physical and chemical protection against decomposition, its turnover rates and the conditions under which the OC is stored in sedimentary settings. This framework is more complex in Mediterranean river basins where sediments are often redistributed under a range of environmental conditions in ephemeral, intermittent and perennial fluvial courses, sometimes within the same catchment. The OC stabilization mechanisms and their relations with aggregation at different transport and sedimentary deposits is under those conditions highly uncertain. The main objective of this work was to characterize the stabilization and mineralization of OC in sediments in transit (suspended load), at a range of depositional settings (alluvial bars, reservoir sediments) and soils from the source areas in a sub-catchment (111 km2) at the headwaters of the Segura catchment in South East Spain. In order to obtain a deeper knowledge on the predominant stabilization mechanism corresponding to each erosional phase, the following organic carbon fractionation method was carried out: Four aggregate size classes were distinguished by sieving (large and small macroaggregates, free microaggregates, and free silt plus clay fraction), and the microaggregates occluded within macroaggregates (SMm) were isolated. As a further step, an oxidation of the OC occluded in silt plus clay fraction and that of the free silt plus clay fraction was performed to estimate the oxidant resistant OC pool. Measured OC in these fractions can be related to three functional pools: active (free particulate organic

  12. Hydrocarbon Status of Alluvial Soils in the Istra Morphostructural Node (Moscow Oblast)

    Science.gov (United States)

    Pikovskiy, Yu. I.; Gennadiev, A. N.; Kovach, R. G.; Khlynina, N. I.; Khlynina, A. V.

    2017-12-01

    The effect of the current block structure of the earth's crust and its most active sites (morphostructural nodes) on the natural hydrocarbon status of alluvial soils has been considered. Studies have been performed in the Istra district of Moscow oblast within the Istra morphostructural node. The node represents an area of increased geodynamic activity of the earth's crust located at the convergence or intersection of block boundaries: mobile linear zones following large river valleys with alluvial soils. Soil cover mainly consists of alluvial humic-gley soils (Eutric Gleyic Fluvisols) of different depths and alluvial mucky-gley soils (Eutric Gleyic Histic Fluvisols). Some soils manifest stratification. Two factors forming the hydrocarbon status of soils are considered: soil processes and the effect of geodynamic activity, which is manifested within the morphostructural node. The contents of bitumoids and retained methane and butanes in alluvial soils appreciably increase at the entry of river valley into the node. The occurrence frequency of 5-6-ring polycyclic aromatic hydrocarbons (perylene and benzo[ghi]perylene) in mineral horizons increases. It has been concluded that alluvial soils within the Istra morphostructural node are characterized by the biogeochemical type of hydrocarbon status with signs of emanation type at sites with the highest geodynamic activity.

  13. Temporal correlation of fluvial and alluvial sequences in the Makran Range, SE-Iran

    Science.gov (United States)

    Kober, F.; Zeilinger, G.; Ivy-Ochs, S.; Dolati, A.; Smit, J.; Burg, J.-P.; Bahroudi, A.; Kubik, P. W.; Baur, H.; Wieler, R.; Haghipour, N.

    2009-04-01

    The Makran region of southeastern Iran is an active accretionary wedge with a partially subaerial component. New investigations have revealed a rather complex geodynamic evolution of the Makran active accretionary wedge that is not yet fully understood in its entity. Ongoing convergence between the Arabian and Eurasian plates and tectonic activity since the late Mesozoic has extended all trough the Quaternary. We focus here on fluvial and alluvial sequences in tectonically separated basins that have been deposited probably in the Pliocene/Quaternary, based on stratigraphic classification in official geological maps, in order to understand the climatic and tectonic forces occurring during the ongoing accretionary wegde formation. Specifically, we investigate the influence of Quaternary climate variations (Pleistocene cold period, monsoonal variations) on erosional and depositional processes in the (semi)arid Makran as well as local and regional tectonic forces in the Coastal and Central Makran Range region. Necessary for such an analysis is a temporal calibration of alluvial and fluvial terrace sequences that will allow an inter-basin correlation. We utilize the exposure age dating method using terrestrial cosmogenic nuclides (TCN) due to the lack of otherwise datatable material in the arid Makran region. Limited radiocarbon data are only available for marine terraces (wave-cut platforms). Our preliminary 21Ne and 10Be TCN-ages of amalgamated clast samples from (un)deformed terrace and alluvial sequences range from ~250 ky to present day (modern wash). These ages agree in relative terms with sequences previously assigned by other investigations through correlation of Quaternary sequences from Central and Western Iran regions. However, our minimum ages suggest that all age sequences are of middle to late Pleistocene age, compared to Pliocene age estimates previously assigned for the oldest units. Although often suggested, a genetical relation and connection of those

  14. A Pleistocene coastal alluvial fan complex produced by Middle Pleistocene glacio-fluvial processes

    Science.gov (United States)

    Adamson, Kathryn; Woodward, Jamie; Hughes, Philip; Giglio, Federico; Del Bianco, Fabrizio

    2014-05-01

    A coarse-grained alluvial fan sequence at Lipci, Kotor Bay, in western Montenegro, provides a sedimentary record of meltwater streams draining from the Orjen Massif (1,894 m a.s.l.) to the coastal zone. At Lipci sedimentary evidence and U-series ages have been used alongside offshore bathymetric imagery and seismic profiles to establish the size of the fan and constrain the nature and timing of its formation. Establishing the depositional history of such coastal fans is important for our understanding of cold stage sediment flux from glaciated uplands to the offshore zone, and for exploring the impact of sea level change on fan reworking. There is evidence of at least four phases of Pleistocene glaciation on the Orjen massif, which have been U-series dated and correlated to MIS 12, MIS 6, MIS 5d-2 and the Younger Dryas. A series of meltwater channels delivered large volumes of coarse- and fine-grained limestone sediment from the glaciated uplands into the Bay of Kotor. At the southern margin of the Orjen massif, a series of large (>700 m long) alluvial fans has developed. Some of these extend offshore for up to 600 m. Lipci fan lies downstream of end moraines in the valley immediately above, which were formed by an extensive outlet glacier of the Orjen ice cap during MIS 12. The terrestrial deposits are part of the fan apex (50 m a.s.l.) that lies at the foot of a steep bedrock channel, but the majority of the fan is now more than 25 m below sea level. The terrestrial fan sediments are strongly cemented by multiple generations of calcite precipitates: the oldest U-series ages are infinite indicating that the fan is >350 ka in age. These ages are in agreement with alluvial sedimentary evidence and U-series ages from other fluvial units on Mount Orjen. The terrestrial portion of the Lipci fan surface contains several channels. These are well preserved due to cementation with calcium carbonate. Submarine imagery indicates that the now submerged portion of the fan also

  15. Comparison of stress in single and multiple layer depositions of plasma-deposited amorphous silicon dioxide

    International Nuclear Information System (INIS)

    Au, V; Charles, C; Boswell, R W

    2006-01-01

    The stress in a single-layer continuous deposition of amorphous silicon dioxide (SiO 2 ) film is compared with the stress within multiple-layer intermittent or 'stop-start' depositions. The films were deposited by helicon activated reactive evaporation (plasma assisted deposition with electron beam evaporation source) to a 1 μm total film thickness. The relationships for stress as a function of film thickness for single, two, four and eight layer depositions have been obtained by employing the substrate curvature technique on a post-deposition etch-back of the SiO 2 film. At film thicknesses of less than 300 nm, the stress-thickness relationships clearly show an increase in stress in the multiple-layer samples compared with the relationship for the single-layer film. By comparison, there is little variation in the film stress between the samples when it is measured at 1 μm film thickness. Localized variations in stress were not observed in the regions where the 'stop-start' depositions occurred. The experimental results are interpreted as a possible indication of the presence of unstable, strained Si-O-Si bonds in the amorphous SiO 2 film. It is proposed that the subsequent introduction of a 'stop-start' deposition process places additional strain on these bonds to affect the film structure. The experimental stress-thickness relationships were reproduced independently by assuming a linear relationship between the measured bow and film thickness. The constants of the linear model are interpreted as an indication of the density of the amorphous film structure

  16. Planar structured perovskite solar cells by hybrid physical chemical vapor deposition with optimized perovskite film thickness

    Science.gov (United States)

    Wei, Xiangyang; Peng, Yanke; Jing, Gaoshan; Cui, Tianhong

    2018-05-01

    The thickness of perovskite absorber layer is a critical parameter to determine a planar structured perovskite solar cell’s performance. By modifying the spin coating speed and PbI2/N,N-dimethylformamide (DMF) solution concentration, the thickness of perovskite absorber layer was optimized to obtain high-performance solar cells. Using a PbI2/DMF solution of 1.3 mol/L, maximum power conversion efficiency (PCE) of a perovskite solar cell is 15.5% with a perovskite film of 413 nm at 5000 rpm, and PCE of 14.3% was also obtained for a solar cell with a perovskite film of 182 nm thick. It is derived that higher concentration of PbI2/DMF will result in better perovskite solar cells. Additionally, these perovskite solar cells are highly uniform. In 14 sets of solar cells, standard deviations of 11 sets of solar cells were less than 0.50% and the smallest standard deviation was 0.25%, which demonstrates the reliability and effectiveness of hybrid physical chemical vapor deposition (HPCVD) method.

  17. Numerical model of the lowermost Mississippi River as an alluvial-bedrock reach: preliminary results

    Science.gov (United States)

    Viparelli, E.; Nittrouer, J. A.; Mohrig, D. C.; Parker, G.

    2012-12-01

    Recent field studies reveal that the river bed of the Lower Mississippi River is characterized by a transition from alluvium (upstream) to bedrock (downstream). In particular, in the downstream 250 km of the river, fields of actively migrating bedforms alternate with deep zones where a consolidated substratum is exposed. Here we present a first version of a one-dimensional numerical model able to capture the alluvial-bedrock transition in the lowermost Mississippi River, defined herein as the 500-km reach between the Old River Control Structure and the Gulf of Mexico. The flow is assumed to be steady, and the cross-section is divided in two regions, the river channel and the floodplain. The streamwise variation of channel and floodplain geometry is described with synthetic relations derived from field observations. Flow resistance in the river channel is computed with the formulation for low-slope, large sand bed rivers due to Wright and Parker, while a Chezy-type formulation is implemented on the floodplain. Sediment is modeled in terms of bed material and wash load. Suspended load is computed with the Wright-Parker formulation. This treatment allows either uniform sediment or a mixture of different grain sizes, and accounts for stratification effects. Bedload transport rates are estimated with the relation for sediment mixtures of Ashida and Michiue. Previous work documents reasonable agreement between these load relations and field measurements. Washload is routed through the system solving the equation of mass conservation of sediment in suspension in the water column. The gradual transition from the alluvial reach to the bedrock reach is modeled in terms of a "mushy" layer of specified thickness overlying the non-erodible substrate. In the case of a fully alluvial reach, the channel bed elevation is above this mushy layer, while in the case of partial alluvial cover of the substratum, the channel bed elevation is within the mushy layer. Variations in base

  18. Flood deposits characterization in Matraca community, Guainia Department in Colombia

    International Nuclear Information System (INIS)

    Cramer, T.; Molano, J.; Bonilla, A.; Amaya, Z.; Franco, J.; Iregui, I.

    2010-01-01

    The characterization of alluvial deposits found in the indigenous community of Matraca is a study that requires mineralogical, petrographic, sedimentological, geochemical and physical analyzes.The results obtained from these analyzes bring the certainty to be in the presence of economically exploitable mineral columbite-tantalite of the series field

  19. Film thickness determination by grazing incidence diffraction

    Energy Technology Data Exchange (ETDEWEB)

    Battiston, G A; Gerbasi, R [CNR, Padua (Italy). Istituto di Chimica e Tecnologie Inorganiche e dei Materiali Avanzati

    1996-09-01

    Thin films deposited via MOCVD (Metal Organic Chemical Vapour Deposition) are layers in the thickness range of a few manometers to about ten micrometers. An understanding of the physics and chemistry of films is necessary for a better comprehension of the phenomena involved in the film deposition procedure and its optimisation. Together with the crystalline phase a parameter that must be determined is the thickness of the layer. In this work the authors present a method for the measurement of the film thickness. This procedure, based on diffraction intensity absorption of the X-rays, both incident and diffracted in passing through the layers, resulted quite simple, rapid and non-destructive.

  20. Film thickness determination by grazing incidence diffraction

    International Nuclear Information System (INIS)

    Battiston, G. A.; Gerbasi, R.

    1996-01-01

    Thin films deposited via MOCVD (Metal Organic Chemical Vapour Deposition) are layers in the thickness range of a few manometers to about ten micrometers. An understanding of the physics and chemistry of films is necessary for a better comprehension of the phenomena involved in the film deposition procedure and its optimisation. Together with the crystalline phase a parameter that must be determined is the thickness of the layer. In this work the authors present a method for the measurement of the film thickness. This procedure, based on diffraction intensity absorption of the X-rays, both incident and diffracted in passing through the layers, resulted quite simple, rapid and non-destructive

  1. The Lower Cretaceous Way Group of northern Chile: An alluvial fan-fan delta complex

    Science.gov (United States)

    Flint, S.; Clemmey, H.; Turner, P.

    1986-01-01

    Alluvial fan sediments of the Lower Cretaceous Coloso Basin in northern Chile were deposited in a half-graben and derived from andesitic volcanics of a former island arc. Transport directions were towards the east, away from the present-day Peru-Chile trench. Grain flow, density modified grain flow and sheetflow processes were responsible for most of the sediment deposition with cohesive debris flows playing only a minor part. An early phase of conglomerate deposition (Coloso Formation) into a restricted basin records the transition from proximal fan facies with abundant grain flows and remobilized screes to mid-fan facies dominated by sheetflows. Stratiform copper mineralization near the top of the lower conglomerates is related to the unroofing of the Jurassic island arc. This mineralization comprises copper sulphide-cemented sands and gravels and formed by the reaction of mineralized detritus with diagenetic and hydrothermal solutions. A later phase of deposition (Lombriz Formation) includes sandstones, siltstones and conglomerates with a source area different from the Coloso Formation. This change in source may be related to strike-slip tectonics as the basin extended. The Lombriz conglomerates pass distally (eastwards) into red sandstones and purple siltstones with thin limestones deposited under marine conditions. This sequence is interpreted as a major fan delta complex. It passes conformably into marine carbonates of the Tableado Formation signifying the complete drowning of the basin in lower Cretaceous times.

  2. Regression Methods for Virtual Metrology of Layer Thickness in Chemical Vapor Deposition

    DEFF Research Database (Denmark)

    Purwins, Hendrik; Barak, Bernd; Nagi, Ahmed

    2014-01-01

    The quality of wafer production in semiconductor manufacturing cannot always be monitored by a costly physical measurement. Instead of measuring a quantity directly, it can be predicted by a regression method (Virtual Metrology). In this paper, a survey on regression methods is given to predict...... average Silicon Nitride cap layer thickness for the Plasma Enhanced Chemical Vapor Deposition (PECVD) dual-layer metal passivation stack process. Process and production equipment Fault Detection and Classification (FDC) data are used as predictor variables. Various variable sets are compared: one most...... algorithm, and Support Vector Regression (SVR). On a test set, SVR outperforms the other methods by a large margin, being more robust towards changes in the production conditions. The method performs better on high-dimensional multivariate input data than on the most predictive variables alone. Process...

  3. Gold deposits in the western sector of the Central Spanish System

    International Nuclear Information System (INIS)

    Barrios, S.; Florido, P.; Reguilon, R.

    2010-01-01

    The gold deposits in the western sector of the Central Spanish System can be grouped in: (1) gold quartz veins type (El Chivote, La Pedrera), (2) paleoplacers: gold nuggets in tertiary alluvial deposits (Las Cavenes, Sierro de Coria), (3) quaternary placers (Rio Erjas), (4) gold nuggets in a regolith developed on the Schist and Graywacke Complex (CEG) (Casillas de Coria). The morphological study of gold nuggets will provide physical, chemical, bacteriological and climatic characteristics. Mining works are located on these deposits from roman time to the present day. (Author)

  4. Effect of laser beam parameters on magnetic properties of Nd-Fe-B thick-film magnets fabricated by pulsed laser deposition

    International Nuclear Information System (INIS)

    Fukunaga, H.; Nakano, M.; Yanai, T.; Kamikawatoko, T.; Yamashita, F.

    2011-01-01

    The effects of varying the laser power and the spot diameter of a laser beam on the magnetic properties, morphology, and deposition rate of Nd-Fe-B thick-film magnets fabricated by pulsed laser deposition (PLD) were investigated. Reducing the laser fluence on the target reduces the remanence and increases the Nd content and consequently the coercivity of the prepared films. The spot size of the laser beam was found to affect the film surface morphology, the deposition rate, and the reproducibility of the magnetic properties of the prepared films. Reducing the spot size reduces the number of droplets and the reproducibility of the magnetic properties and increases the droplet size. Controlling the spot size of the laser beam enabled us to maximize the deposition rate. Consequently, a coercivity of 1210 kA/m and a remanence of 0.51 T were obtained at a deposition rate of 11.8 μm/(h·W). This deposition rate is 30% greater than the highest previously reported deposition rate by PLD.

  5. Braidplain, floodplain and playa lake, alluvial-fan, aeolian and palaeosol facies composing a diversified lithogenetical sequence in the permian and triassic of South Devon (England)

    Science.gov (United States)

    Mader, Detlef

    The Permian and Triassic of South Devon (England) are a continental red bed sequence of very diversified lithogenetical composition. Within the thick series, the distribution of the main depositional environments being fluvial braidplain, fluvial floodplain and playa lake, alluvial fan, aeolian dune and calcrete palaeosol changes repeatedly in both horizontal and vertical direction. Significant sedimentary milieus such as aeolian dunes and calcrete palaeosols occur repeatedly within the succession, but are also lacking in several parts of the sequence. Fluvial braidplain deposits comprise conglomerates, sandstones, intraformational reworking horizons and mudstones and originate in channels and overbank plains of a braided river system. Conglomerates and sandstones are formed by migration of bars and spreading out of sheets during infilling of streams and aggradation of flats. Gravel is often enriched as lag pockets or veneers within steeper scour holes and kolk pots or on the plane floor of the watercourse. Finer-grained sandstones and mudstones are laid down by suspension settling in stagnant water bodies such as small lakes in the overbank area and residual pools in interbar depressions during low-stage or waning-flow in active channels or in abandoned streams. Spectacular bioturbation features in some sandstones with both horizontal tubes and vertical burrows testify to the colonization of the sediments at the bottom of the rivers with declining discharge and transport capacity. Intraformational reworking horizons with ghost-like remnants of degraded sandstones, mudstones and pedogenic carbonates document partially severe condensation of the sequence by removal of some facies elements from the depositional record. The occasionally occurring gravel-bearing mudstones or silty-clayey sandstones represent products of high-energy water surges overspilling the channel banks and transporting sandy and gravelly bed-load in limited amounts beyond the levee wall. The

  6. Single and Double Infrared Transitions in Rapid Vapor Deposited Parahydrogen Solids: Application to Sample Thickness Determination and Quantitative Infrared Absorption Spectroscopy

    National Research Council Canada - National Science Library

    Tam, Simon

    2001-01-01

    ...) solid from its infrared (IR) absorption spectrum. Millimeters-thick pH2 solids of exceptional optical clarity can be produced by the rapid vapor deposition method M.E. Fajardo and S. Tam, J. Chem. Phys. 108, 4237 (1998...

  7. Controlled growth of carbon nanofibers using plasma enhanced chemical vapor deposition: Effect of catalyst thickness and gas ratio

    International Nuclear Information System (INIS)

    Saidin, M.A.R.; Ismail, A.F.; Sanip, S.M.; Goh, P.S.; Aziz, M.; Tanemura, M.

    2012-01-01

    The characteristics of carbon nanofibers (CNFs) grown, using direct current plasma enhanced chemical vapor deposition system reactor under various acetylene to ammonia gas ratios and different catalyst thicknesses were studied. Nickel/Chromium-glass (Ni/Cr-glass) thin film catalyst was employed for the growth of CNF. The grown CNFs were then characterized using Raman spectroscopy, field emission scanning electron microscopy and transmission electron microscopy (TEM). Raman spectroscopy showed that the Ni/Cr-glass with thickness of 15 nm and gas ratio acetylene to ammonia of 1:3 produced CNFs with the lowest I D /I G value (the relative intensity of D-band to G-band). This indicated that this catalyst thickness and gas ratio value is the optimum combination for the synthesis of CNFs under the conditions studied. TEM observation pointed out that the CNFs produced have 104 concentric walls and the residual catalyst particles were located inside the tubes of CNFs. It was also observed that structural morphology of the grown CNFs was influenced by acetylene to ammonia gas ratio and catalyst thickness.

  8. Controlled growth of carbon nanofibers using plasma enhanced chemical vapor deposition: Effect of catalyst thickness and gas ratio

    Energy Technology Data Exchange (ETDEWEB)

    Saidin, M.A.R. [Advanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi Malaysia, 81310 Skudai, Johor Bahru (Malaysia); Ismail, A.F., E-mail: afauzi@utm.my [Advanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi Malaysia, 81310 Skudai, Johor Bahru (Malaysia); Sanip, S.M.; Goh, P.S.; Aziz, M. [Advanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi Malaysia, 81310 Skudai, Johor Bahru (Malaysia); Tanemura, M. [Department of Frontier Material, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555 (Japan)

    2012-01-31

    The characteristics of carbon nanofibers (CNFs) grown, using direct current plasma enhanced chemical vapor deposition system reactor under various acetylene to ammonia gas ratios and different catalyst thicknesses were studied. Nickel/Chromium-glass (Ni/Cr-glass) thin film catalyst was employed for the growth of CNF. The grown CNFs were then characterized using Raman spectroscopy, field emission scanning electron microscopy and transmission electron microscopy (TEM). Raman spectroscopy showed that the Ni/Cr-glass with thickness of 15 nm and gas ratio acetylene to ammonia of 1:3 produced CNFs with the lowest I{sub D}/I{sub G} value (the relative intensity of D-band to G-band). This indicated that this catalyst thickness and gas ratio value is the optimum combination for the synthesis of CNFs under the conditions studied. TEM observation pointed out that the CNFs produced have 104 concentric walls and the residual catalyst particles were located inside the tubes of CNFs. It was also observed that structural morphology of the grown CNFs was influenced by acetylene to ammonia gas ratio and catalyst thickness.

  9. Structural Properties Characterized by the Film Thickness and Annealing Temperature for La2O3 Films Grown by Atomic Layer Deposition.

    Science.gov (United States)

    Wang, Xing; Liu, Hongxia; Zhao, Lu; Fei, Chenxi; Feng, Xingyao; Chen, Shupeng; Wang, Yongte

    2017-12-01

    La 2 O 3 films were grown on Si substrates by atomic layer deposition technique with different thickness. Crystallization characteristics of the La 2 O 3 films were analyzed by grazing incidence X-ray diffraction after post-deposition rapid thermal annealing treatments at several annealing temperatures. It was found that the crystallization behaviors of the La 2 O 3 films are affected by the film thickness and annealing temperatures as a relationship with the diffusion of Si substrate. Compared with the amorphous La 2 O 3 films, the crystallized films were observed to be more unstable due to the hygroscopicity of La 2 O 3 . Besides, the impacts of crystallization characteristics on the bandgap and refractive index of the La 2 O 3 films were also investigated by X-ray photoelectron spectroscopy and spectroscopic ellipsometry, respectively.

  10. Development and evaluation of a long-term deposit probe for on-line monitoring of deposit growth

    Energy Technology Data Exchange (ETDEWEB)

    Brink, Anders; Lauren, Tor; Yrjas, Patrik; Hupa, Mikko [Process Chemistry Centre, Aabo Akademi University, Biskopsgatan 8, FI-20540 Turku (Finland); Friesenbichler, Joachim [Institute for Resource Efficient and Sustainable Systems, Technical University Graz Inffeldg. 21b, A-8010 Graz (Austria)

    2007-12-15

    A newly designed air-cooled probe for on-line monitoring of deposition growth has been tested in a boiler firing three woody fuels. Thermocouples are mounted on both sides of the tube wall enabling measurements of the heat flux through the probe wall. Knowing the heat flux through the probe wall, it is possible to measure the additional heat transfer resistance caused by the deposit and to estimate the properties of the deposit. Calculating the deposit thickness using the collected temperature data indicated the thinnest deposit when wood was fired, followed by bark and waste wood. The calculated deposit thickness was larger than those found when analysing the deposit thickness after the probe had been removed. Nevertheless, the ranking of fuels by deposit build-up rate was the same. (author)

  11. The impact of medium architecture of alluvial settings on non-Fickian transport

    Science.gov (United States)

    Zhang, Yong; Green, Christopher T.; Fogg, Graham E.

    2013-01-01

    The influence of heterogeneous architecture of alluvial aquifers on non-Fickian transport is explored using the Monte Carlo approach. More than two thousand high-resolution hydrofacies models representing seven groups of alluvial settings are built to test the effects of varying facies proportions, mean length and its anisotropy ratio, juxtapositional tendencies, and sub-facies heterogeneity. Results show that the volumetric fraction (P(Z)) of floodplain layers classified by their thicknesses Z controls the non-Fickian tailing of tracer transport at late times. A simple quantitative relationship SBTC≈SP(Z)/2-1 is built based on a multi-rate mass transfer analysis, where SBTC is the slope of the power-law portion of tracer breakthrough curve, and SP(Z) denotes the slope of the power-law portion of the distribution of P(Z) which can be measured, e.g., in core logs. At early times, the mean length of hydrofacies affects the non-Fickian tailing by controlling the channeling of flow in high-permeability non-floodplain materials and the sequestration in surrounding low-permeability floodplain layers. The competition between channeling and sequestration generates complex pre-asymptotic features, including sublinear growth of plume mean displacement, superlinear growth of plume variance, and skewed mass distribution. Those observations of the influence of medium heterogeneity on tracer transport at early and late times may lead to development of nonlocal transport models that can be parameterized using measurable aquifer characteristics.

  12. Enhanced Performance of Nanowire-Based All-TiO2 Solar Cells using Subnanometer-Thick Atomic Layer Deposited ZnO Embedded Layer

    International Nuclear Information System (INIS)

    Ghobadi, Amir; Yavuz, Halil I.; Ulusoy, T. Gamze; Icli, K. Cagatay; Ozenbas, Macit; Okyay, Ali K.

    2015-01-01

    In this paper, the effect of angstrom-thick atomic layer deposited (ALD) ZnO embedded layer on photovoltaic (PV) performance of Nanowire-Based All-TiO 2 solar cells has been systematically investigated. Our results indicate that by varying the thickness of ZnO layer the efficiency of the solar cell can be significantly changed. It is shown that the efficiency has its maximum for optimal thickness of 1 ALD cycle in which this ultrathin ZnO layer improves device performance through passivation of surface traps without hampering injection efficiency of photogenerated electrons. The mechanisms contributing to this unprecedented change in PV performance of the cell have been scrutinized and discussed

  13. Investigating selective transport and abrasion on an alluvial fan using quantitative grain size and shape analysis

    Science.gov (United States)

    Litwin, K. L.; Jerolmack, D. J.

    2011-12-01

    Selective sorting and abrasion are the two major fluvial processes that are attributed to the downstream fining of sediments in rivers and alluvial fans. Selective transport is the process by which smaller grains are preferentially transported downstream while larger grains are deposited closer to the source. Abrasion is defined by the production of fine sediments and sand that occurs by saltation of gravel, where particle-to-particle collisions supply the energy required to break apart grains. We hypothesize that abrasion results in the gradual fining of large grains and the production of fine sands and silts, while sorting accounts for the differences in transport of these two grain-size fractions produced from abrasion, thereby creating the abrupt gravel-sand transition observed in many channel systems. In this research, we explore both selective transport and abrasion processes on the Dog Canyon alluvial fan near Alamogordo, New Mexico. We complete an extensive grain size analysis down the main channel of the fan employing an image-based technique that utilizes an autocorrelation process. We also characterize changes in grain shape using standard shape parameters, as well as Fourier analysis, which allows the study of contributions of grain roughness on a variety of length scales. Sorting appears to dominate the upper portion of the fan; the grain-size distribution narrows moving downstream until reaching a point of equal mobility, at which point sorting ceases. Abrasion exerts a subtle but persistent effect on grains during transport down the fan. Shape analysis reveals that particles become more rounded by the removal of small-scale textural features, a process that is expected to only modestly influence grain size of gravel, but should produce significant quantities of sand. This study provides a better understanding of the importance of grain abrasion and sorting on the downstream fining of channel grains in an alluvial fan, as well as an improved knowledge

  14. Sources, lability and solubility of Pb in alluvial soils of the River Trent catchment, U.K.

    Science.gov (United States)

    Izquierdo, M; Tye, A M; Chenery, S R

    2012-09-01

    Alluvial soils are reservoirs of metal contaminants such as Pb that originate from many different sources and are integrated temporally and spatially through erosional and depositional processes. In this study the source, lability and solubility of Pb were examined in a range of alluvial soils from the middle and lower River Trent and its tributary the River Dove using Pb isotope apportionment and isotopic dilution. All samples were collected within 10 m of the river bank to represent the soil that is most likely to be remobilised during bank erosion. Paired samples were taken from the topsoil (0-15 cm) and subsoil (35-50 cm) to assess differences with depth. Lead concentrations in soil ranged from 43 to 1282 mg/kg. The lability of soil Pb varied between 9 and 56% of total metal concentration whilst Pb concentrations in pore water varied between 0.2 and 6.5 μg/L. There was little difference in the % Pb lability between paired top and sub soils, possibly because soil characteristics such as pH, iron oxides and clay content were generally similar; a result of the recycling of eroded and deposited soils within the river system. Soil pH was found to be negatively correlated with % Pb lability. Source apportionment using (206)Pb/(207)Pb and (208)Pb/(207)Pb ratios showed that the isotopic ratios of Pb in the total, labile and solution pools fitted along a mixing line between Broken Hill Type ('BHT') Pb, used as an additive in UK petrol, and the local coal/Southern Pennine ore Pb. Various anomalies were found in the Pb isotopes of the bankside alluvial soils which were explained by point source pollution. Statistically significant differences were found between (i) the isotopic composition of Pb in the total soil pool and the labile/solution pools and (ii) the isotopic composition of Pb in the labile and solution pools, suggesting an enrichment of recent non-Pennine sources of Pb entering the soils in the labile and solution pools. Copyright © 2012 Natural Environment

  15. Sandstone-type uranium deposits

    International Nuclear Information System (INIS)

    Austin, S.R.; D'Andrea, R.F. Jr.

    1978-01-01

    Three overall factors are necessary for formation of uranium deposits in sandstone: a source of uranium, host rocks capable of transmitting uranium-bearing solutions, and a precipitant. Possible sources of uranium in sandstone-type deposits include groundwaters emanating from granitic highlands, arkosic sediments, tuffaceous material within or overlying the host rocks, connate fluids, and overlying black shales. The first three sources are considered the most likely. Host rocks are generally immature sandstones deposited in alluvial-fan, intermontane-basin or marginal-marine environments, but uranium deposits do occur in well-winnowed barrier-bar or eolian sands. Host rocks for uranium deposits generally show coefficients of permeability on the order of 1 to 100 gal/day/ft 2 . Precipitants are normally agents capable of reducing uranium from the uranyl to the uranous state. The association of uranium with organic matter is unequivocal; H 2 S, a powerful reductant, may have been present at the time of formation of some deposits but may go unnoticed today. Vanadium can serve to preserve the tabular characteristics of some deposits in the near-surface environment, but is considered an unlikely primary precipitant for uranium. Uranium deposits in sandstone are divided into two overall types: peneconcordant deposits, which occur in locally reducing environments in otherwise oxidized sandstones; and roll-type deposits, which occur at the margin of an area where an oxidized groundwater has permeated an otherwise reduced sandstone. Uranium deposits are further broken down into four subclasses; these are described

  16. Response spectra in alluvial soils

    International Nuclear Information System (INIS)

    Chandrasekharan, A.R.; Paul, D.K.

    1975-01-01

    For aseismic design of structures, the ground motion data is assumed either in the form of ground acceleration as a function of time or indirectly in the form of response spectra. Though the response spectra approach has limitations like not being applicable for nonlinear problems, it is usually used for structures like nuclear power plants. Fifty accelerograms recorded at alluvial sites have been processed. Since different empirical formulas relating acceleration with magnitude and distance give a wide scatter of values, peak ground acceleration alone cannot be the parameter as is assumed by a number of authors. The spectra corresponding to 5% damping have been normalised with respect to three parameters, namely, peak ground acceleration, peak ground velocity and a nondimensional quantity ad/v 2 . Envelopee of maxima and minima as well as average response spectra has been obtained. A comparison with the USAEC spectra has been made. A relation between ground acceleration, ground velocity and ad/v 2 has been obtained which would nearly give the same magnification of the response. A design response spectra for alluvial soils has been recommended. (author)

  17. 44 CFR 65.13 - Mapping and map revisions for areas subject to alluvial fan flooding.

    Science.gov (United States)

    2010-10-01

    ... areas subject to alluvial fan flooding. 65.13 Section 65.13 Emergency Management and Assistance FEDERAL... areas subject to alluvial fan flooding. This section describes the procedures to be followed and the... provides protection from the base flood in an area subject to alluvial fan flooding. This information must...

  18. Development of Budenovskoye Deposit in South Kazakhstan

    International Nuclear Information System (INIS)

    Matunov, A.; Niyetbayev, M.

    2014-01-01

    Budenovskoye deposit was discovered in 1979 in permeable alluvial deposits of the Upper Cretaceous and is the world largest sandstone type deposit. The prospecting and exploration works were started there in 1987 with inferred resources of the southern flank only estimated at about 200,000 tU. Key geology features of the deposit are: • The deposit is located in the maximum submerged part of the depression formed in the Upper Cretaceous period by channel facies; a very complex morphology of mineralisation in plan, large vertical area, multilayer structure, relatively high productivity of the deposits. • High-pressure nature of groundwaters with positive occurrence of piezometric level, very high water conductivity, permeability of horizons and their water abundance, lack of consistent confining layers, and location of the deposit in the artesian basin at the junction with hydrogeological massif of B Karatau Range. • Relatively low concentration of main syngenetic genesis reducing agents in ore-bearing rocks in combination with other factors causes the insufficiently contrastive reducing barrier and extraordinary stretched profile of epigenetic zonation with fuzzy boundaries between separate zones and subzones.

  19. Trace elements in deposits of Jurassic paleovalleys of the Chulym-Yenisei depression - (Malinovskoe uranium deposit)

    Energy Technology Data Exchange (ETDEWEB)

    Potseluev, A.A.; Rikhvanov, L.P.; Arbuzov, S.I.; Lyapunov, P.I.; Rubinov, I.M.; Bazhenov, M.I.; Zadorin, L.I. [Tomsk Polytechnic University, Tomsk (Russian Federation)

    2001-07-01

    The REE composition of uraniferous alluvial deposits in the Malinovskaya paleovalley of the Chulym-Yenisei depression is studied. The contents of elements are determined by the INAA and X-ray fluorescent methods and by emission and X-ray spectroscopies. The minerals are identified by X-ray, luminescent, and laser analyses. The ore-bearing zone shows three types of elevated concentrations of elements: primary clastogene (W, Ge), primary sorption-biogenic (U, Se, Mo, V, As), and secondary redeposited infiltrogenic (elements of the first two types plus Hf, Sc, and REE). The high content of W is explained by its supply from primary deposits of the Altai-Sayan region, and the high content of Ge is due to the presence of fragments of Ge-bearing coals.

  20. Thick film hydrogen sensor

    Science.gov (United States)

    Hoffheins, Barbara S.; Lauf, Robert J.

    1995-01-01

    A thick film hydrogen sensor element includes an essentially inert, electrically-insulating substrate having deposited thereon a thick film metallization forming at least two resistors. The metallization is a sintered composition of Pd and a sinterable binder such as glass frit. An essentially inert, electrically insulating, hydrogen impermeable passivation layer covers at least one of the resistors.

  1. Dust deposition in southern Nevada and California, 1984-1989: Relations to climate, source area, and source lithology

    Science.gov (United States)

    Reheis, Marith C.; Kihl, Rolf

    1995-05-01

    Dust samples collected annually for 5 years from 55 sites in southern Nevada and California provide the first regional source of information on modern rates of dust deposition, grain size, and mineralogical and chemical composition relative to climate and to type and lithology of dust source. The average silt and clay flux (rate of deposition) in southern Nevada and southeastern California ranges from 4.3 to 15.7 g/m2/yr, but in southwestern California the average silt and clay flux is as high as 30 g/m2/yr. The climatic factors that affect dust flux interact with each other and with the factors of source type (playas versus alluvium), source lithology, geographic area, and human disturbance. Average dust flux increases with mean annual temperature but is not correlated to decreases in mean annual precipitation because the regional winds bring dust to relatively wet areas. In contrast, annual dust flux mostly reflects changes in annual precipitation (relative drought) rather than temperature. Although playa and alluvial sources produce about the same amount of dust per unit area, the total volume of dust from the more extensive alluvial sources is much larger. In addition, playa and alluvial sources respond differently to annual changes in precipitation. Most playas produce dust that is richer in soluble salts and carbonate than that from alluvial sources (except carbonate-rich alluvium). Gypsum dust may be produced by the interaction of carbonate dust and anthropogenic or marine sulfates. The dust flux in an arid urbanizing area may be as much as twice that before disturbance but decreases when construction stops. The mineralogic and major-oxide composition of the dust samples indicates that sand and some silt is locally derived and deposited, whereas clay and some silt from different sources can be far-traveled. Dust deposited in the Transverse Ranges of California by the Santa Ana winds appears to be mainly derived from sources to the north and east.

  2. Interpretation of massive sandstones in ephemeral fluvial settings: A case study from the Upper Candelária Sequence (Upper Triassic, Paraná Basin, Brazil)

    Science.gov (United States)

    Horn, Bruno Ludovico Dihl; Goldberg, Karin; Schultz, Cesar Leandro

    2018-01-01

    Ephemeral rivers display a wide range of upper- and lower-flow regime structures due to great flow-velocity changes during the floods. The development of flow structures in these setting is yet to be understood, especially in the formation of thick, massive sandstones. The Upper Triassic of Southern Gondwana was marked by a climate with great seasonal changes, yet there is no description of river systems with seasonal characteristics in Southern Gondwana. This work aims to characterize a ephemeral alluvial system of the Upper Triassic of the Paraná Basin. The characteristics of the deposits are discussed in terms of depositional processes through comparison with similar deposits from literature, flow characteristics and depositional signatures compared to flume experiments. The alluvial system is divided in four facies associations: (1) channels with wanning fill, characterized by low width/thickness ratio, tabular bodies, scour-and-fill structures with upper- and lower-flow regime bedforms; (2) channels with massive fill, characterized by low w/t ratio, sheet-like bodies, scour-and-fill structures with massive sandstones; (3) proximal sheetfloods, characterized by moderate w/t ratio, sheet-like bodies with upper- and lower-flow regime bedforms and (4) distal sheetfloods, characterized by high w/t ratio, sheet-like bodies with lower-flow regime bedforms. Evidence for the seasonal reactivation of the riverine system includes the scarcity of well-developed macroforms and presence of in-channel mudstones, thick intraformational conglomerates, and the occurrence of well- and poorly-preserved vertebrate bones in the same beds. The predominantly massive sandstones indicate deposition from a hyperconcentrated flow during abrupt changes in flow speed, caused by de-confinement or channel avulsion, whereas turbulent portions of the flow formed the upper- and lower-flow regime bedforms after the deposition of the massive layers. The upper portion of the Candelária Sequence

  3. The role of post-ore processes in the alteration of infiltrational uranium deposits

    International Nuclear Information System (INIS)

    Kondrat'eva, I.A.; Bobrova, L.L.; Nesterova, M.V.

    1992-01-01

    Ore-bearing rocks and ores of uranium deposits that are associated with gray alluvial deposits and formed through oxidation of sedimentary beds at the end of the Jurassic, have undergone intensive alterations. The impact of hot carbonic acid solutions on infiltrational uranium deposits, along with calcite and hematite, resulted in partial dissolution of and redeposition of uranium. Uranium concentrates with newly formed Fe-bisulfides and hydroxides in the reducing stage of epigenetic alterations within a hydrochemical sulfide-gley medium, leading to changes in ore morphology. 20 refs., 7 figs., 3 tabs

  4. Calculation of Al2O3 contents in Al2O3-PTFE composite thick films fabricated by using the aerosol deposition

    International Nuclear Information System (INIS)

    Kim, Hyung-Jun; Kim, Yoon-Hyun; Nam, Song-Min; Yoon, Young-Joon; Kim, Jong-Hee

    2010-01-01

    Low-temperature fabrication of Al 2 O 3 -PTFE (poly tetra fluoro ethylene) composite thick films for flexible integrated substrates was attempted by using the aerosol deposition method. For optimization of composite thick films, a novel calculation method for the ceramic contents in the composites was attempted. Generally, a thermogravimetry (TG) analysis is used to calculate the ceramic contents in the ceramic-polymer composites. However, the TG analysis requires a long measurement time in each analysis, so we studied a novel calculation method that used a simple dielectric measurement. We used Hashin-Shtrikman bounds to obtain numerical results for the relationship between the dielectric constant of the composites and the contents of Al 2 O 3 . A 3-D electrostatic simulation model similar to the deposited Al 2 O 3 -PTFE composite thick films was prepared, and the simulation result was around the lower bound of the Hashin-Shtrikman bounds. As a result, we could calculate the Al 2 O 3 contents in the composites with a low error of below 5 vol.% from convenient dielectric measurements, and the Al 2 O 3 contents ranged from 51 vol.% to 54 vol.%.

  5. Channel layer thickness dependence of In-Ti-Zn-O thin-film transistors fabricated using pulsed laser deposition

    International Nuclear Information System (INIS)

    Zhang, Q.; Shan, F. K.; Liu, G. X.; Liu, A.; Lee, W. J.; Shin, B. C.

    2014-01-01

    Amorphous indium-titanium-zinc-oxide (ITZO) thin-film transistors (TFTs) with various channel thicknesses were fabricated at room temperature by using pulsed laser deposition. The channel layer thickness (CLT) dependence of the TFTs was investigated. All the ITZO thin films were amorphous, and the surface roughnesses decreased slightly first and then increased with increasing CLT. With increasing CLT from 35 to 140 nm, the on/off current ratio and the field-effect mobility increased, and the subthreshold swing decreased. The TFT with a CLT of 210 nm exhibited the worst performance, while the ITZO TFT with a CLT of 140 nm exhibited the best performance with a subthreshold voltage of 2.86 V, a mobility of 53.9 cm 2 V -1 s -1 , a subthreshold swing of 0.29 V/decade and an on/off current ratio of 10 9 .

  6. Effect of substrates and thickness on optical properties in atomic layer deposition grown ZnO thin films

    Science.gov (United States)

    Pal, Dipayan; Singhal, Jaya; Mathur, Aakash; Singh, Ajaib; Dutta, Surjendu; Zollner, Stefan; Chattopadhyay, Sudeshna

    2017-11-01

    Atomic Layer Deposition technique was used to grow high quality, very low roughness, crystalline, Zinc Oxide (ZnO) thin films on silicon (Si) and fused quartz (SiO2) substrates to study the optical properties. Spectroscopic ellipsometry results of ZnO/Si system, staggered type-II quantum well, demonstrate that there is a significant drop in the magnitudes of both the real and imaginary parts of complex dielectric constants and in near-band gap absorption along with a blue shift of the absorption edge with decreasing film thickness at and below ∼20 nm. Conversely, UV-vis absorption spectroscopy of ZnO/SiO2, thin type-I quantum well, consisting of a narrower-band gap semiconductor grown on a wider-band gap (insulator) substrate, shows the similar thickness dependent blue-shift of the absorption edge but with an increase in the magnitude of near-band gap absorption with decreasing film thickness. Thickness dependent blue shift, energy vs. 1/d2, in two different systems, ZnO/Si and ZnO/SiO2, show a difference in their slopes. The observed phenomena can be consistently explained by the corresponding exciton (or carrier/s) deconfinement and confinement effects at the ZnO/Si and ZnO/SiO2 interface respectively, where Tanguy-Elliott amplitude pre-factor plays the key role through the electron-hole overlap factor at the interface.

  7. Biometric estimation of chest wall thickness of females

    International Nuclear Information System (INIS)

    Berger, C.D.; Lane, B.H.

    1985-01-01

    Optimal use of whole-body counting data to estimate pulmonary deposition of many of the actinides is dependent upon accurate measurement of the thickness of the chest wall because of severe attenuation of low-energy x rays and photons associated with the decay of these radionuclides. An algorithm for estimation of female chest wall thicknesses, verified by real-time ultrasonic measurements, has been derived based on the correlation of measured chest wall thickness and other common biometric quantities. Use of this algorithm will reduce the error generally associated with estimation of internal actinide deposition previously resulting from assuming an average chest wall thickness for all female subjects

  8. Lower Cretaceous paleo-Vertisols and sedimentary interrelationships in stacked alluvial sequences, Utah, USA

    Science.gov (United States)

    Joeckel, R. M.; Ludvigson, G. A.; Kirkland, J. I.

    2017-11-01

    The Yellow Cat Member of the Cedar Mountain Formation in Poison Strip, Utah, USA, consists of stacked, erosionally bounded alluvial sequences dominated by massive mudstones (lithofacies Fm) with paleo-Vertisols. Sediment bodies within these sequences grade vertically and laterally into each other at pedogenic boundaries, across which color, texture, and structures (sedimentary vs. pedogenic) change. Slickensides, unfilled (sealed) cracks, carbonate-filled cracks, and deeper cracks filled with sandstone; the latter features suggest thorough desiccation during aridification. Thin sandstones (Sms) in some sequences, typically as well as laminated to massive mudstones (Flm) with which they are interbedded in some cases, are interpreted as avulsion deposits. The termini of many beds of these lithofacies curve upward, parallel to nearby pedogenic slickensides, as the features we call ;turnups.; Turnups are overlain or surrounded by paleosols, but strata sheltered underneath beds with turnups retain primary sedimentary fabrics. Turnups were produced by movement along slickensides during pedogenesis, by differential compaction alongside pre-existing gilgai microhighs, or by a combination of both. Palustrine carbonates (lithofacies C) appear only in the highest or next-highest alluvial sequences, along with a deep paleo-Vertisol that exhibits partially preserved microrelief at the base of the overlying Poison Strip Member. The attributes of the Yellow Cat Member suggest comparatively low accommodation, slow accumulation, long hiatuses in clastic sedimentation, and substantial time intervals of subaerial exposure and pedogenesis; it appears to be distinct among the members of the Cedar Mountain Formation in these respects.

  9. Thickness dependence of magnetic properties and giant magneto-impedance effect in amorphous Co{sub 73}Si{sub 12}B{sub 15} thin films prepared by Dual-Ion beam assisted deposition

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Yu [School of Physics and Nuclear Energy Engineering, Beihang University, Beijing 100191 (China); BISSE/BUAA-SPNEE joint Laboratory Magnetism and Sperconducting technology on Spacecraft, Beihang University, Beijing 100191 (China); Wang, San-sheng, E-mail: wangssh@buaa.edu.cn [School of Physics and Nuclear Energy Engineering, Beihang University, Beijing 100191 (China); BISSE/BUAA-SPNEE joint Laboratory Magnetism and Sperconducting technology on Spacecraft, Beihang University, Beijing 100191 (China); Hu, Teng [School of Physics and Nuclear Energy Engineering, Beihang University, Beijing 100191 (China); He, Tong-fu [School of Instrumentation Science and Opto-electronics Engineering, Beihang University, Beijing 100191 (China); Chen, Zi-yu [School of Physics and Nuclear Energy Engineering, Beihang University, Beijing 100191 (China); Yi, Zhong; Meng, Li-Fei [Science and Technology on Reliability and Environmental Engineering Laboratory, Beijing Institute of Spacecraft Environment Engineering, Beijing 100094 (China); BISSE/BUAA-SPNEE joint Laboratory Magnetism and Sperconducting technology on Spacecraft, Beihang University, Beijing 100191 (China)

    2017-03-15

    Dual-Ion Beam Assisted Deposition is a suitable method for the preparation of giant magneto-impedance (GMI) materials. In this paper, Co{sub 73}Si{sub 12}B{sub 15} thin films with different thicknesses were prepared by Dual-Ion Beam Assisted Deposition, and the influences of film thickness on magnetic properties and GMI effect were investigated. It was found that the asymmetric magnetic hysteresis loop in the prepared Co{sub 73}Si{sub 12}B{sub 15} thin films occurs at ambient temperature, and the shift behavior of hysteresis loop associated with film thickness. With the film thickness increasing, the values of shift field and coercive field and other parameters such as remanence and shift ratio appeared complex variation. At a certain frequency, the large GMI effect is only observed in some films, which have good magnetic properties including low coercivity, low remanence ratio and high shift ratio. The results indicated that the thickness dependence of magnetic properties nonlinearly determined the GMI effect in Co{sub 73}Si{sub 12}B{sub 15} thin films. - Highlights: • The relationship between film thickness and ΔZ/Z, ΔR/R, ΔX/X ratio of CoSiB film exhibits a complex behavior as the film thickness increases from 1.33 to 7.34 µm. The maximum value of GMI ratio is observed when the film thickness was 1.56, 2.48, 3.81 or 7.34 µm. • With the increase of film thickness, the peak frequency shifts to lower frequency, but does not decrease following the t-power law. • The above thickness phenomenon is due to the different magnetic properties of thin films. • The Dual-Ion Beam Assisted Deposition is introduced to prepare the GMI materials.

  10. Effect of Ga2O3 buffer layer thickness on the properties of Cu/ITO thin films deposited on flexible substrates

    International Nuclear Information System (INIS)

    Zhuang Huihui; Yan Jinliang; Xu Chengyang; Meng Delan

    2014-01-01

    Cu and Cu/ITO films were prepared on polyethylene terephthalate (PET) substrates with a Ga 2 O 3 buffer layer using radio frequency (RF) and direct current (DC) magnetron sputtering. The effect of Cu layer thickness on the optical and electrical properties of the Cu film deposited on a PET substrate with a Ga 2 O 3 buffer layer was studied, and an appropriate Cu layer thickness of 4.2 nm was obtained. Changes in the optoelectrical properties of Cu(4.2 nm)/ITO(30 nm) films were investigated with respect to the Ga 2 O 3 buffer layer thickness. The optical and electrical properties of the Cu/ITO films were significantly influenced by the thickness of the Ga 2 O 3 buffer layer. A maximum transmission of 86%, sheet resistance of 45 Ω/□ and figure of merit of 3.96 × 10 −3 Ω −1 were achieved for Cu(4.2 nm)/ITO(30 nm) films with a Ga 2 O 3 layer thickness of 15 nm. (semiconductor materials)

  11. Arboreous vegetation of an alluvial riparian forest and their soil relations: Porto Rico island, Paraná river, Brazil

    Directory of Open Access Journals (Sweden)

    Campos João Batista

    2002-01-01

    Full Text Available The dynamics of alluvial deposits in floodplains forms islands and sandbanks. Deposits frequently accumulate at the river margins and on islands with consequent side growths. One of these sandbanks which started to form in 1952 annexed an area of 12.4ha to the Porto Rico island (53masculine15?W and 22masculine45?S. At present a forest fragment of approximately 2.0 ha exists in this place. The structural analysis of arboreous vegetation of this fragment showed a floristic gradient related to the physical and chemical variations of the substratum. High density of pioneer species associated to the absence of recruitment of new individuals of these and other successional categories indicated that the forest was impaired in its succession process. This fact could be associated with constant disturbances caused by cattle in the area.

  12. Thermal release of D2 from new Be-D co-deposits on previously baked co-deposits

    Science.gov (United States)

    Baldwin, M. J.; Doerner, R. P.

    2015-12-01

    Past experiments and modeling with the TMAP code in [1, 2] indicated that Be-D co-deposited layers are less (time-wise) efficiently desorbed of retained D in a fixed low-temperature bake, as the layer grows in thickness. In ITER, beryllium rich co-deposited layers will grow in thickness over the life of the machine. Although, compared with the analyses in [1, 2], ITER presents a slightly different bake efficiency problem because of instances of prior tritium recover/control baking. More relevant to ITER, is the thermal release from a new and saturated co-deposit layer in contact with a thickness of previously-baked, less-saturated, co-deposit. Experiments that examine the desorption of saturated co-deposited over-layers in contact with previously baked under-layers are reported and comparison is made to layers of the same combined thickness. Deposition temperatures of ∼323 K and ∼373 K are explored. It is found that an instance of prior bake leads to a subtle effect on the under-layer. The effect causes the thermal desorption of the new saturated over-layer to deviate from the prediction of the validated TMAP model in [2]. Instead of the D thermal release reflecting the combined thickness and levels of D saturation in the over and under layer, experiment differs in that, i) the desorption is a fractional superposition of desorption from the saturated over-layer, with ii) that of the combined over and under -layer thickness. The result is not easily modeled by TMAP without the incorporation of a thin BeO inter-layer which is confirmed experimentally on baked Be-D co-deposits using X-ray micro-analysis.

  13. Thermal release of D_2 from new Be-D co-deposits on previously baked co-deposits

    International Nuclear Information System (INIS)

    Baldwin, M.J.; Doerner, R.P.

    2015-01-01

    Past experiments and modeling with the TMAP code in [1, 2] indicated that Be-D co-deposited layers are less (time-wise) efficiently desorbed of retained D in a fixed low-temperature bake, as the layer grows in thickness. In ITER, beryllium rich co-deposited layers will grow in thickness over the life of the machine. Although, compared with the analyses in [1, 2], ITER presents a slightly different bake efficiency problem because of instances of prior tritium recover/control baking. More relevant to ITER, is the thermal release from a new and saturated co-deposit layer in contact with a thickness of previously-baked, less-saturated, co-deposit. Experiments that examine the desorption of saturated co-deposited over-layers in contact with previously baked under-layers are reported and comparison is made to layers of the same combined thickness. Deposition temperatures of ∼323 K and ∼373 K are explored. It is found that an instance of prior bake leads to a subtle effect on the under-layer. The effect causes the thermal desorption of the new saturated over-layer to deviate from the prediction of the validated TMAP model in [2]. Instead of the D thermal release reflecting the combined thickness and levels of D saturation in the over and under layer, experiment differs in that, i) the desorption is a fractional superposition of desorption from the saturated over-layer, with ii) that of the combined over and under -layer thickness. The result is not easily modeled by TMAP without the incorporation of a thin BeO inter-layer which is confirmed experimentally on baked Be-D co-deposits using X-ray micro-analysis.

  14. Characterization of 13 and 30 mum thick hydrogenated amorphous silicon diodes deposited over CMOS integrated circuits for particle detection application

    CERN Document Server

    Despeisse, M; Commichau, S C; Dissertori, G; Garrigos, A; Jarron, P; Miazza, C; Moraes, D; Shah, A; Wyrsch, N; Viertel, Gert M; 10.1016/j.nima.2003.11.022

    2004-01-01

    We present the experimental results obtained with a novel monolithic silicon pixel detector which consists in depositing a n-i-p hydrogenated amorphous silicon (a-Si:H) diode straight above the readout ASIC (this technology is called Thin Film on ASIC, TFA). The characterization has been performed on 13 and 30mum thick a-Si:H films deposited on top of an ASIC containing a linear array of high- speed low-noise transimpedance amplifiers designed in a 0.25mum CMOS technology. Experimental results presented have been obtained with a 600nm pulsed laser. The results of charge collection efficiency and charge collection speed of these structures are discussed.

  15. Level III Ecoregions of the Mississippi Alluvial Plain

    Data.gov (United States)

    U.S. Environmental Protection Agency — Ecoregions for the Mississippi Alluvial Plain were extracted from the seamless national shapefile. Ecoregions denote areas of general similarity in ecosystems and in...

  16. Level IV Ecoregions of the Mississippi Alluvial Plain

    Data.gov (United States)

    U.S. Environmental Protection Agency — Ecoregions for the Mississippi Alluvial Plain were extracted from the seamless national shapefile. Ecoregions denote areas of general similarity in ecosystems and in...

  17. Coeval gravity-driven and thick-skinned extensional tectonics in the mid-Cretaceous of the western Pyrenees

    Science.gov (United States)

    Bodego, Arantxa; Agirrezabala, Luis M.

    2010-05-01

    The Mesozoic Basque-Cantabrian Basin in the western Pyrenees constitutes a peri-cratonic basin originated by rifting related to the Cretaceous opening of the Bay of Biscay. During the mid-Cretaceous the basin experienced important extensional/transtensional tectonics, which controlled the deposition of thick sedimentary successions. Many extensional structures have been documented in the basin but their thin-skinned/thick-skinned character is an unresolved question. In this field-based study, we characterize contemporaneous thin-skinned and thick-skinned deformations that took place during the filling of the mid-Cretaceous Lasarte sub-basin, located in the northeastern margin of the Basque-Cantabrian Basin (western Pyrenees). Most of these extensional structures and associated growth strata are preserved and allow us to characterize and date different deformation phases. Moreover, verticalization and overturning of the successions during Tertiary compression allow mapping the geometry of the extensional structures at depth. The Lasarte sub-basin constitutes a triangular sag bordered by three major basement-involved faults, which trend N, E and NE, respectively. These trends, common in the Variscan fault pattern of Pyrenees, suggest that they are old faults reactivated during the mid-Cretaceous extension. Stratigraphy of the area shows very thin to absent Aptian-Albian (and older) deposits above the upward border blocks, whereas on the downward blocks (sub-basin interior) contemporaneous thick successions were deposited (up to 1500 m). The sub-basin fill is composed of different sedimentary systems (from alluvial to siliciclastic and carbonate platforms) affected by syndepositional extensional faults (and related folds). These faults die out in a southwestward dipping (~4°) detachment layer composed of Triassic evaporites and clays. A NE-SW cross-section of the sub-basin shows NW- to N-trending six planar and two listric extensional faults and associated folds

  18. Residual stress analysis in thick uranium films

    International Nuclear Information System (INIS)

    Hodge, A.M.; Foreman, R.J.; Gallegos, G.F.

    2005-01-01

    Residual stress analysis was performed on thick, 1-25 μm, depleted uranium (DU) films deposited on an Al substrate by magnetron sputtering. Two distinct characterization techniques were used to measure substrate curvature before and after deposition. Stress evaluation was performed using the Benabdi/Roche equation, which is based on beam theory of a bi-layer material. The residual stress evolution was studied as a function of coating thickness and applied negative bias voltage (0, -200, -300 V). The stresses developed were always compressive; however, increasing the coating thickness and applying a bias voltage presented a trend towards more tensile stresses and thus an overall reduction of residual stresses

  19. Geology and mineral deposits of Churchill County, Nevada

    Science.gov (United States)

    Willden, Ronald; Speed, Robert C.

    1974-01-01

    Churchill County, in west-central Nevada, is an area of varied topography and geology that has had a rather small total mineral production. The western part of the county is dominated by the broad low valley of the Carson Sink, which is underlain by deposits of Lake Lahontan. The bordering mountain ranges to the west and south are of low relief and underlain largely by Tertiary volcanic and sedimentary units. Pre-Tertiary rocks are extensively exposed east of the Carson Sink in the Stillwater Range, Clan Alpine Mountains, Augusta Mountains, and New Pass Mountains. The eastern valleys are underlain by Quaternary alluvial and lacustrine deposits contemporaneous with the western deposits of Lake Lahontan. The eastern mountain ranges are more rugged than the western ranges and have higher relief; the eastern valleys are generally narrower.

  20. Thermal release of D{sub 2} from new Be-D co-deposits on previously baked co-deposits

    Energy Technology Data Exchange (ETDEWEB)

    Baldwin, M.J., E-mail: m1baldwin@ucsd.edu; Doerner, R.P.

    2015-12-15

    Past experiments and modeling with the TMAP code in [1, 2] indicated that Be-D co-deposited layers are less (time-wise) efficiently desorbed of retained D in a fixed low-temperature bake, as the layer grows in thickness. In ITER, beryllium rich co-deposited layers will grow in thickness over the life of the machine. Although, compared with the analyses in [1, 2], ITER presents a slightly different bake efficiency problem because of instances of prior tritium recover/control baking. More relevant to ITER, is the thermal release from a new and saturated co-deposit layer in contact with a thickness of previously-baked, less-saturated, co-deposit. Experiments that examine the desorption of saturated co-deposited over-layers in contact with previously baked under-layers are reported and comparison is made to layers of the same combined thickness. Deposition temperatures of ∼323 K and ∼373 K are explored. It is found that an instance of prior bake leads to a subtle effect on the under-layer. The effect causes the thermal desorption of the new saturated over-layer to deviate from the prediction of the validated TMAP model in [2]. Instead of the D thermal release reflecting the combined thickness and levels of D saturation in the over and under layer, experiment differs in that, i) the desorption is a fractional superposition of desorption from the saturated over-layer, with ii) that of the combined over and under -layer thickness. The result is not easily modeled by TMAP without the incorporation of a thin BeO inter-layer which is confirmed experimentally on baked Be-D co-deposits using X-ray micro-analysis.

  1. Preliminary description of quaternary and late pliocene surficial deposits at Yucca Mountain and vicinity, Nye County, Nevada

    International Nuclear Information System (INIS)

    Hoover, D.L.

    1989-01-01

    The Yucca Mountain area, in the south-central part of the Great Basin, is in the drainage basin of the Amargosa River. The mountain consists of several fault blocks of volcanic rocks that are typical of the Basin and Range province. Yucca Mountain is dissected by steep-sided valleys of consequent drainage systems that are tributary on the east side to Fortymile Wash and on the west side to an unnamed wash that drains Crater Flat. Most of the major washes near Yucca Mountain are not integrated with the Amargosa River, but have distributary channels on the piedmont above the river. Landforms in the Yucca Mountain area include rock pediments, ballenas, alluvial pediments, alluvial fans, stream terraces, and playas. Early Holocene and older alluvial fan deposits have been smoothed by pedimentation. The semiconical shape of alluvial fans is apparent at the junction of tributaries with major washes and where washes cross fault and terrace scarps. Playas are present in the eastern and southern ends of the Amargosa Desert. 39 refs., 9 figs., 1 tab

  2. Breakthrough to Non-Vacuum Deposition of Single-Crystal, Ultra-Thin, Homogeneous Nanoparticle Layers: A Better Alternative to Chemical Bath Deposition and Atomic Layer Deposition

    Directory of Open Access Journals (Sweden)

    Yu-Kuang Liao

    2017-04-01

    Full Text Available Most thin-film techniques require a multiple vacuum process, and cannot produce high-coverage continuous thin films with the thickness of a few nanometers on rough surfaces. We present a new ”paradigm shift” non-vacuum process to deposit high-quality, ultra-thin, single-crystal layers of coalesced sulfide nanoparticles (NPs with controllable thickness down to a few nanometers, based on thermal decomposition. This provides high-coverage, homogeneous thickness, and large-area deposition over a rough surface, with little material loss or liquid chemical waste, and deposition rates of 10 nm/min. This technique can potentially replace conventional thin-film deposition methods, such as atomic layer deposition (ALD and chemical bath deposition (CBD as used by the Cu(In,GaSe2 (CIGS thin-film solar cell industry for decades. We demonstrate 32% improvement of CIGS thin-film solar cell efficiency in comparison to reference devices prepared by conventional CBD deposition method by depositing the ZnS NPs buffer layer using the new process. The new ZnS NPs layer allows reduction of an intrinsic ZnO layer, which can lead to severe shunt leakage in case of a CBD buffer layer. This leads to a 65% relative efficiency increase.

  3. Geology and climatic indicators in the Westphalian A New Glasgow formation, Nova Scotia, Canada: implications for the genesis of coal and of sandstone-hosted lead deposits

    Energy Technology Data Exchange (ETDEWEB)

    Chandler, F.W. [Geological Survey of Canada, Ottawa, ON (Canada)

    1998-03-01

    Disagreement exists on whether the early Pennsylvanian climate of the Euramerican coal province was everwet or seasonal. Abundant paleopedological evidence, including calcrete-bearing vertisols, shows that during formation of Westphalian C to Stephanian coals in Nova Scotia, the climate was tropical and seasonal with a pronounced by dry season; but interpretation of Westphalian A-B coal-bearing sequences lacks this form of evidence. Development of calcrete-bearing vertisols in alluvial fan deposits of the Westphalian A New Glasgow formation indicate that a tropical climate with a pronounced dry season was already in force by early Westphalian time. During the dry season, the coal swamps of the early Westphalian Joggins and Springhill Mines formations were fed by groundwater from coeval alluvial fan deposits of the Polly Brook Formation at the basin margin. Sedimentological evidence indicates that, similarly, groundwater flowed northward from the toe of the New Glasgow alluvial fan, but correlative palustrine sediments have not been found on land in the New Glasgow area. The possibility remains of an early Westphalian coalfield associated with the New Glasgow formation to the north under the Northumberland Strait and Gulf of St. Lawrence. Formation of the Yava sandstone-hosted lead deposit in the fluvial Silver Mine Formation of Cape Breton Island, a stratigraphic equivalent of the Cumberland Basin coal swamps, indicates that such deposits can form in fluvial strata deposited under a tropical seasonal climate with a pronounced dry season.

  4. The geology and chronology of the Acheulean deposits in the Mieso area (East-Central Ethiopia).

    Science.gov (United States)

    Benito-Calvo, Alfonso; Barfod, Dan N; McHenry, Lindsay J; de la Torre, Ignacio

    2014-11-01

    This paper presents the Quaternary sequence of the Mieso area of Central-East Ethiopia, located in the piedmont between the SE Ethiopian Escarpment and the Main Ethiopian Rift-Afar Rift transition sector.In this region, a piedmont alluvial plain is terraced at þ25 m above the two main fluvial courses, the Mieso and Yabdo Rivers. The piedmont sedimentary sequence is divided into three stratigraphic units separated by unconformities. Mieso Units I and II contain late Acheulean assemblages and a weakly consolidated alluvial sequence, consisting mainly of fine sediments with buried soils and, to a lesser degree, conglomerates. Palaeo-wetland areas were common in the alluvial plain, represented by patches of tufas, stromatolites and clays. At present, the piedmont alluvial surface is preserved mainly on a dark brown soil formed at the top of Unit II. Unit III corresponds to a fluvial deposit overlying Unit II, and is defined by sands, silty clays and gravels, including several Later Stone Age (LSA) occurrences. Three fine-grained tephra levels are interbedded in Unit I (tuffs TBI and TA) and II (tuff CB), and are usually spatially-constrained and reworked. Argon/argon (40Ar/39Ar) dating from tuff TA, an ash deposit preserved in a palustrine environment, yielded an age of 0.212 ± 0.016 Ma (millions of years ago). This date places thetop of Unit I in the late Middle Pleistocene, with Acheulean sites below and above tuff TA. Regional correlations tentatively place the base of Unit I around the Early-Middle Pleistocene boundary, Unit II inthe late Middle Pleistocene and within the Late Pleistocene, and the LSA occurrences of Unit III in the LatePleistoceneeHolocene.

  5. Geomorphologic and sedimentologic controls on records of flood-induced alluviation in Las Cajas National Park, Ecuador

    Science.gov (United States)

    Rodbell, D. T.; Bustamante, M. G.; Marks, S.; Abbott, M. B.; Moy, C. M.

    2017-12-01

    The sediment record from Laguna Pallcacocha in Las Cajas National Park, southern Ecuador (4060 masl; 2°46'S; 79°14'W) has been interpreted to record El Niño floods spanning the Holocene (Rodbell et al., 1999; Moy et al., 2002). The sediment record is unusual for the nearly continuous dark- and light-colored laminations (0.1-2.0 cm thick) that comprise the Holocene. Light laminae typically have erosive basal contacts and fine-upwards, whereas dark laminae possess abrupt or gradational lower contacts and reveal no grain size trends. Light laminae contain 7%), and contain 3-10% biogenic silica. Light laminae represent deposition during periods of increased precipitation, mobilization of unvegetated sediment above the lake, and increased stream discharge, all of which generate density-driven undercurrents. Conversely, dark laminae are deposited relatively slowly by sedimentation of organic matter, some derived from surface soil horizons. Time series analysis of light laminae reveal the ENSO spectral signature (2-8 yr) that evolves through the Holocene. However, none of the sediment cores taken from many nearby lakes reveal an alluvial record comparable in terms of frequency and magnitude to that preserved in Pallcacocha thus raising questions as to the factors responsible for the rich stratigraphy preserved in Pallcacocha, and, moreover, the regional paleoclimatic significance of the Pallcacocha record. A review of lacustrine sediment cores obtained from Las Cajas National Park suggests that drainage basin factors are the primary control on the sedimentologic signal recorded. These factors include bedrock geology, presence of unvegetated sediment exposed on slopes, connectivity of exposed sediment to primary inflow streams, drainage basin slope, drainage basin:lake surface area ratio, and position of lake in paternoster sequence of lakes. Bedrock is comprised of Quaternary silicic ignimbrite, rhyolite, and andesite of the Tarqui Formation. Ignimibrite provides the

  6. Alluvial architecture of fluvio-deltaic successions: a review with special reference to Holocene settings

    NARCIS (Netherlands)

    Gouw, M.J.P.

    2007-01-01

    Alluvial architecture has been subject of many studies because of the occurrence of natural resources in ancient fluvial successions. This paperprovides an overview of the current state of research on alluvial architecture with special reference to Holocene fluvio-deltaic settings. Severalexamples

  7. Influence of PECVD deposited SiNx passivation layer thickness on In0.18Al0.82N/GaN/Si HEMT

    International Nuclear Information System (INIS)

    Singh, Sarab Preet; Liu, Yi; Ngoo, Yi Jie; Kyaw, Lwin Min; Bera, Milan Kumar; Chor, Eng Fong; Dolmanan, S B; Tripathy, Sudhiranjan

    2015-01-01

    The influence of plasma enhanced chemical vapour deposited (PECVD) silicon nitride (SiN x ) passivation film thickness on In 0.18 Al 0.82 N/GaN/Si heterostructures and HEMTs has been investigated. The formation of Si 3 N 4 was confirmed by x-ray photoelectron spectroscopy (XPS) measurements. X-ray reflectivity (XRR) measurements reveal that both the density and roughness of the SiN x film increase with increasing film thickness. With an increase in SiN x film thickness, a significant increase in two-dimensional electron gas (2DEG) density, drain current, extrinsic transconductance and negative threshold voltage shift of the In 0.18 Al 0.82 /GaN/Si HEMTs are observed. An optimal thickness of SiN x is ∼100 nm and it yields a substantial increase in 2DEG density (∼30%) with a minimum sheet resistance for In 0.18 Al 0.82 N/GaN/Si heterostructures. Furthermore, we correlate the observed SiN x film thickness-dependent electrical characteristics of In 0.18 Al 0.82 /GaN/Si HEMTs with the density of the SiN x film. (paper)

  8. Morphometric measurement of submucosal thickness in areas of fat deposition in the terminal ileum and colonic sections, with correlation with body mass index, weight and age: a male autopsy study.

    Science.gov (United States)

    Mesa, Hector; Drawz, Sarah; Dykoski, Richard; Manivel, Juan Carlos

    2015-10-01

    An increased amount of submucosal (SM) fat in the colon on imaging is considered to be characteristic of inflammatory bowel disease (IBD); however, a recent study in patients without IBD reported a correlation between colonic SM fat deposition and body weight (BW). The aim of this study was to perform a morphometric investigation of SM thickness in areas of fat deposition in the terminal ileum (TI), ileocaecal valve (ICV), and colonic sections, to determine whether there are variations by site, and whether it shows a correlation with BW, body mass index (BMI), or age. Representative samples of TI, ICV and colonic sections were collected prospectively from 115 autopsy cases without IBD. All of the study subjects were male (Veterans Hospital). SM thickness was measured in areas of fat deposition. Correlation analysis was performed between SM thickness and BW, BMI, and age. Fat deposition was common; however, with the exception of the ICV, it was neither consistent nor prominent, and it did not show a statistical correlation with BW, BMI, or age. SM fat deposition is common but not uniform or conspicuous in the TI or colon. In contrast to extravisceral intra-abdominal fat, it does not show a correlation with BW or BMI, and is not associated with ageing. As all study subjects were male, gender-dependent variability cannot be excluded. © 2015 John Wiley & Sons Ltd.

  9. Aerial Transient Electromagnetic Surveys of Alluvial Aquifers in Rural Watersheds of Arizona

    Science.gov (United States)

    Pool, D. R.; Callegary, J. B.; Groom, R. W.

    2006-12-01

    Development in rural areas of Arizona has led the State of Arizona (Arizona Department of Water Resources), in cooperation with the Arizona Water Science Center of the U.S. Geological Survey, to sponsor investigations of the hydrogeologic framework of several alluvial-basin aquifers. An efficient method for mapping the aquifer extent and lithology was needed due to sparse subsurface information. Aerial Transient Electro-Magnetic (ATEM) methods were selected because they can be used to quickly survey large areas and with a great depth of investigation. Both helicopter and fixed-wing ATEM methods are available. A fixed-wing method (GEOTEM) was selected because of the potential for a depth of investigation of 300 m or more and because previous surveys indicated the method is useful in alluvial basins in southeastern Arizona. About 2,900 km of data along flight lines were surveyed across five alluvial basins, including the Middle San Pedro and Willcox Basins in southeastern Arizona, and Detrital, Hualapai, and Sacramento Basins in northwestern Arizona. Data initially were analyzed by the contractor (FUGRO Airborne Surveys) to produce conductivity-depth-transforms, which approximate the general subsurface electrical-property distribution along profiles. Physically based two-dimensional physical models of the profile data were then developed by PetRos- Eikon by using EMIGMA software. Hydrologically important lithologies can have different electrical properties. Several types of crystalline and sedimentary rocks generally are poor aquifers that have low porosity and high electrical resistivity. Good alluvial aquifers of sand and gravel generally have an intermediate electrical resistivity. Poor aquifer materials, such as silt and clay, and areas of poor quality water have low electrical resistivity values. Several types of control data were available to constrain the models including drill logs, electrical logs, water levels , and water quality information from wells; and

  10. Characterization of 13 and 30 μm thick hydrogenated amorphous silicon diodes deposited over CMOS integrated circuits for particle detection application

    International Nuclear Information System (INIS)

    Despeisse, M.; Anelli, G.; Commichau, S.; Dissertori, G.; Garrigos, A.; Jarron, P.; Miazza, C.; Moraes, D.; Shah, A.; Wyrsch, N.; Viertel, G.

    2004-01-01

    We present the experimental results obtained with a novel monolithic silicon pixel detector which consists in depositing a n-i-p hydrogenated amorphous silicon (a-Si:H) diode straight above the readout ASIC (this technology is called Thin Film on ASIC, TFA). The characterization has been performed on 13 and 30 μm thick a-Si:H films deposited on top of an ASIC containing a linear array of high-speed low-noise transimpedance amplifiers designed in a 0.25 μm CMOS technology. Experimental results presented have been obtained with a 600 nm pulsed laser. The results of charge collection efficiency and charge collection speed of these structures are discussed

  11. Ways of distinguishing epigenetic types of gray-colored rocks in sheet-infiltration deposits

    International Nuclear Information System (INIS)

    Rasulova, S.D.; Yashunskii, Yu.V.

    1994-01-01

    At an infiltration deposit of uranium in Upper-Cretaceous sandy-clay alluvial deposits (Central Kyzylkum), six stages of postsedimentation epigenetic transformations were distinguished. The genesis of altered rocks was determined mostly by mineralogical methods. A new methodological technique is suggested, which calls for analysis of the textural, structural, and mineral correspondence of ferruginous components of gray-colored and oxidized rocks in the region of their contact and makes it possible to typify epigenetic changes in conditions of repeated change in the direction of geochemical processes

  12. Photoluminescence properties of poly (p-phenylene vinylene) films deposited by chemical vapor deposition

    International Nuclear Information System (INIS)

    Gedelian, Cynthia A.; Rajanna, K.C.; Premerlani, Brian; Lu, Toh-Ming

    2014-01-01

    Photoluminescence spectra of PPV at varying thicknesses and temperatures have been studied. A study of the quenching of the polymer film using a modified version of fluorescence spectroscopy reveals interface effects dominating at thicknesses below about 600 Å, while bulk effects dominate at higher thicknesses. The application of the Stern–Volmer equation to solid film is discussed. Stern–Volmer plots were nonlinear with downward deviations at higher thickness of the film which was explained due to self-quenching in films and larger conformational change and increased restriction from change in electron density due to electron transition during excitation in bulk polymer films over 60 nm thick. PPV deposited into porous (∼4 nm in diameter) nanostructured substrate shows a larger 0–0 than 0–1 transition peak intensity and decreased disorder in the films due to structure imposed by substrate matrix. Temperature dependent effects are measured for a film at 500 Å, right on the border between the two areas. PPV films deposited on porous methyl silsesquioxane (MSQ) were also examined in order to compare the flat film to a substrate that allows for the domination of interface effects. The enthalpies of the first two peaks are very similar, but the third peak demonstrates a lower enthalpy and a larger wavelength shift with temperature. Films deposited inside pores show a smaller amount of disorder than flat films. Calculation of the Huang–Rhys factor at varying temperatures for the flat film and film in porous MSQ shows large temperature dependence for the flat film but a smaller amount of disorder in the nanostructured film. -- Highlights: • Poly (p-phenylene vinylene) films deposited by chemical vapor deposition exhibited photoluminescence properties. • Fluorescence spectra of the polymer films revealed interface effects dominating at thicknesses below about 600 Å, while bulk effects dominate at higher thicknesses. • Stern–Volmer plots were

  13. Geomorphic and hydraulic controls on large-scale riverbank failure on a mixed bedrock-alluvial river system, the River Murray, South Australia: a bathymetric analysis.

    Science.gov (United States)

    De Carli, E.; Hubble, T.

    2014-12-01

    During the peak of the Millennium Drought (1997-2010) pool-levels in the lower River Murray in South Australia dropped 1.5 metres below sea level, resulting in large-scale mass failure of the alluvial banks. The largest of these failures occurred without signs of prior instability at Long Island Marina whereby a 270 metre length of populated and vegetated riverbank collapsed in a series of rotational failures. Analysis of long-reach bathymetric surveys of the river channel revealed a strong relationship between geomorphic and hydraulic controls on channel width and downstream alluvial failure. As the entrenched channel planform meanders within and encroaches upon its bedrock valley confines the channel width is 'pinched' and decreases by up to half, resulting in a deepening thalweg and channel bed incision. The authors posit that flow and shear velocities increase at these geomorphically controlled 'pinch-points' resulting in complex and variable hydraulic patterns such as erosional scour eddies, which act to scour the toe of the slope over-steepening and destabilising the alluvial margins. Analysis of bathymetric datasets between 2009 and 2014 revealed signs of active incision and erosional scour of the channel bed. This is counter to conceptual models which deem the backwater zone of a river to be one of decelerating flow and thus sediment deposition. Complex and variable flow patterns have been observed in other mixed alluvial-bedrock river systems, and signs of active incision observed in the backwater zone of the Mississippi River, United States. The incision and widening of the lower Murray River suggests the channel is in an erosional phase of channel readjustment which has implications for riverbank collapse on the alluvial margins. The prevention of seawater ingress due to barrage construction at the Murray mouth and Southern Ocean confluence, allowed pool-levels to drop significantly during the Millennium Drought reducing lateral confining support to the

  14. Deposition and diagenesis of the Brushy Basin Member and upper part of the Westwater Canyon member of the Morrison Formation, San Juan Basin, New Mexico

    International Nuclear Information System (INIS)

    Bell, T.E.

    1986-01-01

    The Brushy Basin Member and the upper part of the Westwater Canyon Member of the Morrison Formation in northwest New Mexico are nonmarine sedimentary rocks of Late Jurassic age. This stratigraphic interval consists of as many as four lithofacies deposited in fluvial and playa-lake environments. Lithofacies A is composed of crossbed feldspathic sandstone and was deposited by braided streams on an alluvial plain. Lithofacies B is composed of crossbedded feldspathic sandstone and tuffaceous mudstone, and was deposited by braided and anastomosing streams at the distal end of the alluvial plain. Lithofacies C is composed of calcareous, tuffaceous mudstone and was deposited on a mudflat between the alluvial plain and a playa lake. Lithofacies D is composed of zeolitic, tuffaceous mudstone and was deposited in a playa lake. The distribution of diagenetic facies in mudstones and tuffs in the Brushy Basin Member and upper part of the Westwater Canyon Member reflects the pH and salinity gradients common to fluvial/playa-lake systems. The abundant vitric ash in the sediments reacted to form montmorillonite in the fluvial facies. Calcite and montmorillonite were the reaction products where the fluvial and outermost playa facies met. Vitric ash reacted to form clinoptilolite and heulandite along the playa margins. In the center of the playa facies, analcime replaced clinoptilolite, an early zeolite. These early diagenetic minerals were replaced by albite, quartz, and mixed-layer illitemontmorillonite where the Brushy Basin Member and upper part of the Westwater Canyon Member have been deeply buried in the San Juan basin

  15. The Thickness Dependence of Optical Constants of Ultrathin Iron Films

    International Nuclear Information System (INIS)

    Gao Shang; Lian Jie; Wang Xiao; Li Ping; Sun Xiao-Fen; Li Qing-Hao

    2013-01-01

    Ultrathin iron films with different thicknesses from 7.1 to 51.7 nm are deposited by magnetron sputtering and covered by tantalum layers protecting them from being oxidized. These ultrathin iron films are studied by spectroscopic ellipsometry and transmittance measurement. An extra tantalum film is deposited under the same sputtering conditions and its optical constants and film thickness are obtained by a combination of ellipsometry and transmission measurement. After introducing these obtained optical constants and film thickness into the tantalum-iron film, the optical constants and film thicknesses of ultrathin iron films with different thicknesses are obtained. The results show that combining ellipsometry and transmission measurement improves the uniqueness of the obtained film thickness. The optical constants of ultrathin iron films depend strongly on film thicknesses. There is a broad absorption peak at about 370 nm and it shifts to 410 nm with film thickness decreasing

  16. The role of episodic fire-related debris flows on long-term (103-104) sediment yields in the Middle Fork Salmon River Watershed, in central Idaho

    Science.gov (United States)

    Riley, K. E.; Pierce, J. L.; Hopkins, A.

    2010-12-01

    Episodic fire-related debris flows contribute large amounts of sediment and large woody debris to streams. This study evaluates fire-related sedimentation from small steep tributaries of the Middle Fork Salmon River (MFSR) in central Idaho to evaluate the timing, frequency, and magnitude of episodic fire-related sedimentation on long-term (10 3-10 4) sediment yields. The MFSR lies within the Northern Rocky Mountains and encompasses a range of ecosystems including high elevation (~3,000 -1,700 m) subalpine pine and spruce forests, mid-elevation (2650 - 1130 m) montane Douglas-fir and ponderosa pine-dominated forests and low elevation (~ 1,800 - 900 m) sagebrush steppe. Recent debris flow events in tributaries of the MFSR appear to primarily result from increased surface runoff, rilling, and progressive sediment bulking following high severity fires. This study estimates: 1) the volume of sediment delivered by four recent (1997-2008) fire-related debris flow events using real time kinematic GPS surveys, and 2) the timing of Holocene fire-related debris flow events determined by 14C dating charcoal fragments preserved in buried burned soils and within fire-related deposits. Our measured volumes of the four recent debris flow events are compared to two empirically derived volume estimates based on remotely sensed spatial data (burn severity and slope), measured geometric data (longitudinal profile, cross sectional area, flow banking angle), and precipitation records. Preliminary stratigraphic profiles in incised alluvial fans suggest that a large percentage of alluvial fan thickness is composed of fire-related deposits suggesting fire-related hillslope erosion is a major process delivering sediment to alluvial fans and to the MFSR. Fire-related deposits from upper basins compose ~71% of total alluvial fan thickness, while fire-related deposits from lower basins make up 36% of alluvial fan thickness. However, lower basins are less densely vegetated with small diameter

  17. 78 FR 10449 - Endangered and Threatened Wildlife and Plants; Designation of Critical Habitat for Astragalus...

    Science.gov (United States)

    2013-02-13

    ... Creek and Morongo Wash (Unit 3), and unnamed channels through the alluvial valley floor deposits... ephemeral washes that carry substrates from alluvial deposits to alluvial fan areas where they can be... alluvial sand deposits that support the fluvial and aeolian sand transport processes crucial to the...

  18. Measurement of the thickness of a target deposited in a substrate; Medicion del grosor de un blanco depositado en un substrato

    Energy Technology Data Exchange (ETDEWEB)

    Martinez Q, E.; Aguilera, E.F

    1990-12-15

    Being based on the Elastic scattering and in the Energy losses that suffer a projectile to the interacting with the matter, a method that allows to determine the thickness of a target deposited in a more heavy substrate is presented. The obtained results are consistent with that waited and the derived errors of the method are small. The used technique allows to reduce in considerable form the systematic errors coming from the calibration of the equipment. It is considered that this method is applicable in an interval of thickness quite wide and for many materials since it is only necessary to choose the projectile type and the energy of the same one appropriately. (Author)

  19. The Neogene molasse deposits of the Zagros Mountains in central Dezful Embayment: facies, sedimentary environments and controls

    Directory of Open Access Journals (Sweden)

    Ali Hossein Jalilian

    2016-03-01

    Full Text Available The upper part of Neogene sequence of the Zagros Mountains consists of a clastic succession which is identified as Aghajari and Bakhtyari formations. The sequence is an excellent example of synorogenic sedimentation or molasse deposited in northern portion of the Zagros foreland basin. Sedimentological analysis of an outcrop section representing Miocene-Pliocene sediments in central Dezful Embayment resulted in recognizing 9 lithofacies and 4 architectural elements. These lithofacies include conglometate (Gt, Gh, Gmm, sandstone (Sp, Sh, Sr, St and mudstone (Fm, Fl that were deposited in meandering stream, braided river and alluvial fan environments. Paleocurrent analysis of cross-beds, channels and asymmetric ripple marks indicate that these Neogene clastics were mainly drived from Cretaceous to Paleogene highlands in the Zagros Mountains on the north. This stratigraphic record is coarsening-upward and formed by a regressive depositional megacycle under arid climate. Facies and depositional history analysis show that sedimentation of the Zagros molasse was primarily controlled by base-level changes rather than catchment lithology or climate. The sedimentary record of this regressive megacycle reveales the base-level was constantly falling down on one hand and the provenance was uplifting on the other hand. Tectonic activities and Zagros Mountains rising in the Late Miocene resulted in deposition of fining-upward point-bar and floodplain sequences of the Aghajari Formation in low-gradient meandering streams. The Lahbari Member of the Aghajari Formation represents deposition in braided rivers that composed predominantly of flood-plain deposits in the Early Pliocene. Finally, the sedimentary cycle of the Zagros molasse deposits terminated with massive conglomerates of the Bakhtyari Formation deposited in large alluvial fans near the source area.

  20. Control of Alq3 wetting layer thickness via substrate surface functionalization.

    Science.gov (United States)

    Tsoi, Shufen; Szeto, Bryan; Fleischauer, Michael D; Veinot, Jonathan G C; Brett, Michael J

    2007-06-05

    The effects of substrate surface energy and vapor deposition rate on the initial growth of porous columnar tris(8-hydroxyquinoline)aluminum (Alq3) nanostructures were investigated. Alq3 nanostructures thermally evaporated onto as-supplied Si substrates bearing an oxide were observed to form a solid wetting layer, likely caused by an interfacial energy mismatch between the substrate and Alq3. Wetting layer thickness control is important for potential optoelectronic applications. A dramatic decrease in wetting layer thickness was achieved by depositing Alq3 onto alkyltrichlorosilane-derivatized Si/oxide substrates. Similar effects were noted with increasing deposition rates. These two effects enable tailoring of the wetting layer thickness.

  1. Thickness effect on the microstructure, morphology and optoelectronic properties of ZnS films

    International Nuclear Information System (INIS)

    Prathap, P; Revathi, N; Subbaiah, Y P Venkata; Reddy, K T Ramakrishna

    2008-01-01

    Thin films of ZnS with thicknesses ranging from 100 to 600 nm have been deposited on glass substrates by close spaced thermal evaporation. All the films were grown at the same deposition conditions except the deposition time. The effect of thickness on the physical properties of ZnS films has been studied. The experimental results indicated that the thickness affects the structure, lattice strain, surface morphology and optoelectronic properties of ZnS films significantly. The films deposited at a thickness of 100 nm showed hexagonal structure whereas films of thickness 300 nm or more showed cubic structure. However, coexistence of both cubic and hexagonal structures was observed in the films of 200 nm thickness. The surface roughness of the films showed an increasing trend at higher thicknesses of the films. A blue-shift in the energy band gap along with an intense UV emission band was observed with the decrease of film thickness, which are ascribed to the quantum confinement effect. The behaviour of optical constants such as refractive index and extinction coefficient were analysed. The variation of refractive index and extinction coefficient with thickness was explained on the basis of the contribution from the packing density of the layers. The electrical resistivity as well as the activation energy were evaluated and found to decrease with the increase of film thickness. The thickness had a significant influence on the optical band gap as well as the luminescence intensity

  2. The use of O, H and Sr isotopes and carbamazepine to identify the origin of water bodies supplying a shallow alluvial aquifer

    Science.gov (United States)

    Sassine, Lara; Le Gal La Salle, Corinne; Lancelot, Joël; Verdoux, Patrick

    2014-05-01

    Alluvial aquifers are of great socio-economic importance in France since they supply 82% of drinking water production, though they reveal to be very vulnerable to pesticides and emerging organic contaminants. The aim of this work is to identify the origin of water bodies which contribute to the recharge of an alluvial aquifer for a better understanding of its hydrochemistry and transfer of contaminants therein. The study is based on an isotopic and geochemical tracers approach, including major elements, trace elements (Br, Sr),and isotopes (δ18O, δ2H, 87Sr/86Sr), as well as organic molecules. Indeed, organic molecules such as pharmaceutical compounds, more precisely carbamazepine and caffeine, have shown their use as indicators of surface water in groundwater. The study area is a partially-confined shallow alluvial aquifer, the so-called Vistrenque aquifer, located at 15 km from the Mediterranean Sea, in the Quaternary alluviums deposited by an ancient arm of the Rhône River, in Southern France. This aquifer constitutes a shallow alluvial layer in a NE-SW graben structure. It is situated between a karst aquifer in lower Cretaceous limestones, on the NW border, and the Costières Plateau, on the SE border, having a similar geology as the Vistrenque. The alluvial plain is crossed by a surface water network with the Vistre as the main stream, and a canal used for irrigation essentially, the BRL canal, which is fed by the Rhône River. δ18O and δ2H allowed to differentiate the BRL canal water, depleted in heavy isotopes (δ2H = -71.5o vs V-SMOW), and the more enriched local rainwater (δ2H = -35.5o vs V-SMOW). In the Vistre surface water a binary mixing were evidenced with the BRL canal water and the rainwater, as end members. Then, in the Vistrenque groundwater both the BRL and the Vistre contributions could be identified, as they still show contrasting signature with local recharge. This allows to highlight the surface water contribution to a heavily exploited

  3. The red bed-type and sandstone-type uranium deposits in the inland basins of the northwest China

    International Nuclear Information System (INIS)

    Wang Zhilong.

    1988-01-01

    On the basis of the study on the relationship between the red bed-type and sandstone-type uranium deposits in the inland basins of the northwest China, a classification of red beds based on sedimentary facies and redding origin is presented. Red beds in the inland badins can be divided into six types: 1. alluvial plain and 2. shallow lake red beds formed at the stage of continental disintegration; 3. fluvial alluvial red bed, 4. delta plain and 5. desert red beds formed at the diagenetic-epigenetic stage; 6. spattered red (secondaty red beds) formed at the hypergenic weathering stage. According to the characteristics, structural environments of these six types of red beds, and changes of various geochemical characteristic values (Eh, pH, Th/U, Fe 3+ /Fe 2+ , Sr/Ba, etc.) from host rocks to different kinds of red beds , the relationship between these values and sandstone-type uranium deposits was determined. it is an open system, the mobile uranium is easily leached, thus it is unfavoutable for mineralization; but when the rock reddens at the diagenetic epigenetic stage (closed system) that is favourable for mineraizaltion, the mobile uranium can be concentrated to form uranium deposits

  4. Influence of deposition rate on the properties of tin coatings deposited on tool steels using arc method

    International Nuclear Information System (INIS)

    Akhtar, P.; Abbas, M.

    2007-01-01

    Titanium nitride (TiN) widely used as hard coating material, was coated on tool steels, namely on high-speed steel (HSS) and D2 tool steel by physical vapour deposition method. The study concentrated on cathodic arc physical vapour deposition (CAPVD), a technique used for the deposition of hard coatings for tooling applications, and which has many advantages. The main drawback of this technique, however, is the formation of macrodroplets (MD's) during deposition, resulting in films with rougher morphology. Various standard characterization techniques and equipment, such as electron microscopy, atomic force microscopy, hardness testing machine, scratch tester and pin-on-disc machine, were used to analyze and quantify the following properties and parameters, surface morphology, thickness, hardness, adhesion and coefficient of friction (COF) of the deposited coatings. Surface morphology revealed that the MD's produced during the etching stage, protruded through the thin film, resulting in film with deteriorated surface features. Both coating thickness and indentation loads influenced the hardness of the deposited coatings. The coatings deposited on HSS exhibit better adhesion compared to those on D2 tool steel. Standard deviation indicates that the coating deposited with thickness around 6.7 macro m showed the most stable trend of COF versus sliding distance. (author)

  5. Stratigraphy, age, and depositional setting of the Miocene Barstow Formation at Harvard Hill, central Mojave Desert, California

    Science.gov (United States)

    Leslie, Shannon R.; Miller, David M.; Wooden, Joseph L.; Vazquez, Jorge A.

    2010-01-01

    New detailed geologic mapping and geochronology of the Barstow Formation at Harvard Hill, 30 km east of Barstow, CA, help to constrain Miocene paleogeography and tectonics of the central Mojave Desert. A northern strand of the Quaternary ENE-striking, sinistral Manix fault divides the Barstow Formation at Harvard Hill into two distinct lithologic assemblages. Strata north of the fault consist of: a green rhyolitic tuff, informally named the Shamrock tuff; lacustrine sandstone; partially silicified thin-bedded to massive limestone; and alluvial sandstone to pebble conglomerate. Strata south of the fault consist of: lacustrine siltstone and sandstone; a rhyolitic tuff dated at 19.1 Ma (U-Pb); rock-avalanche breccia deposits; partially silicified well-bedded to massive limestone; and alluvial sandstone and conglomerate. Our U-Pb zircon dating of the Shamrock tuff by SHRIMP-RG yields a peak probability age of 18.7 ± 0.1 Ma. Distinctive outcrop characteristics, mineralogy, remanent magnetization, and zircon geochemistry (Th/U) suggest that the Shamrock tuff represents a lacustrine facies of the regionally extensive Peach Spring Tuff (PST). Here we compare zircon age and geochemical analyses from the Shamrock tuff with those of the PST at Stoddard Wash and provide new insight into the age of zircon crystallization in the PST rhyolite. Results of our field studies show that Miocene strata at Harvard Hill mostly accumulated in a lacustrine environment, although depositional environments varied from a relatively deep lake to a very shallow lake or even onshore setting. Rock-avalanche breccias and alluvial deposits near the base of the exposed section indicate proximity to a steep basin margin and detrital studies suggest a southern source for coarse-grained deposits; therefore, we may infer a southern basin-margin setting at Harvard Hill during the early Miocene. Our geochronology demonstrates that deposition of the Barstow Formation at Harvard Hill extended from before

  6. Excess erosion and deposition in the catchments of Kamenichka and Radanjska river, Republic of Macedonia

    Directory of Open Access Journals (Sweden)

    Milevski Ivica

    2009-01-01

    Full Text Available One of the greatest environmental problems in the Republic of Macedonia is accelerated soil erosion caused by high human impact during last centuries on to the susceptible landscape. Natural factors itself are very suitable for development of such erosion: from mostly erodible rocks and soils on the mountainous slopes around the depressions, to the generally continental, semi-arid climate and slight vegetation cover. Because of that, there are sites with severe erosion and deposition like those in the catchments of Kamenichka River and Radanjska River, two torrential tributaries of Bregalnica. In these catchments there are varieties of erosion-related landforms: rills, gullies, badlands, landslides, as well as valley-type alluvial fans and huge alluvial plains. Such devastating accelerated erosion and deposition largely transformed original landscape, and represent significant environmental, social, and economic problem in local areas. Because of that, some measures of protection and conservation were taken from 1950-ties in both catchments. But it is obvious that the final effect of these measures is far of enough, so new efforts must be implemented to revitalizing these abandoned lands.

  7. Hydrogeology and simulation of groundwater flow and analysis of projected water use for the Canadian River alluvial aquifer, western and central Oklahoma

    Science.gov (United States)

    Ellis, John H.; Mashburn, Shana L.; Graves, Grant M.; Peterson, Steven M.; Smith, S. Jerrod; Fuhrig, Leland T.; Wagner, Derrick L.; Sanford, Jon E.

    2017-02-13

    aquifer materials. The aquifer areal extent ranged from less than 0.2 to 8.5 miles wide. The maximum aquifer thickness was 120 feet (ft), and the average aquifer thickness was 50 ft. Average horizontal hydraulic conductivity for the Canadian River alluvial aquifer was calculated to be 39 feet per day, and the maximum horizontal hydraulic conductivity was calculated to be 100 feet per day.Recharge rates to the Canadian River alluvial aquifer were estimated by using a soil-water-balance code to estimate the spatial distribution of groundwater recharge and a water-table fluctuation method to estimate localized recharge rates. By using daily precipitation and temperature data from 39 climate stations, recharge was estimated to average 3.4 in/yr, which corresponds to 8.7 percent of precipitation as recharge for the Canadian River alluvial aquifer from 1981 to 2013. The water-table fluctuation method was used at one site where continuous water-level observation data were available to estimate the percentage of precipitation that becomes groundwater recharge. Estimated annual recharge at that site was 9.7 in/yr during 2014.Groundwater flow in the Canadian River alluvial aquifer was identified and quantified by a conceptual flow model for the period 1981–2013. Inflows to the Canadian River alluvial aquifer include recharge to the water table from precipitation, lateral flow from the surrounding bedrock, and flow from the Canadian River, whereas outflows include flow to the Canadian River (base-flow gain), evapotranspiration, and groundwater use. Total annual recharge inflows estimated by the soil-water-balance code were multiplied by the area of each reach and then averaged over the simulated period to produce an annual average of 28,919 acre-feet per year (acre-ft/yr) for Reach I and 82,006 acre-ft/yr for Reach II. Stream base flow to the Canadian River was estimated to be the largest outflow of groundwater from the aquifer, measured at four streamgages, along with

  8. Microstructure of vapor deposited coatings on curved substrates

    Energy Technology Data Exchange (ETDEWEB)

    Rodgers, Theron M.; Zhao, Hengbei; Wadley, Haydn N. G., E-mail: haydn@virginia.edu [Department of Materials Science and Engineering, University of Virginia, 395 McCormick Rd., P.O. Box 400745, Charlottesville, Virginia 22904 (United States)

    2015-09-15

    Thermal barrier coating systems consisting of a metallic bond coat and ceramic over layer are widely used to extend the life of gas turbine engine components. They are applied using either high-vacuum physical vapor deposition techniques in which vapor atoms rarely experience scattering collisions during propagation to a substrate, or by gas jet assisted (low-vacuum) vapor deposition techniques that utilize scattering from streamlines to enable non-line-of-sight deposition. Both approaches require substrate motion to coat a substrate of complex shape. Here, direct simulation Monte Carlo and kinetic Monte Carlo simulation methods are combined to simulate the deposition of a nickel coating over the concave and convex surfaces of a model airfoil, and the simulation results are compared with those from experimental depositions. The simulation method successfully predicted variations in coating thickness, columnar growth angle, and porosity during both stationary and substrate rotated deposition. It was then used to investigate a wide range of vapor deposition conditions spanning high-vacuum physical vapor deposition to low-vacuum gas jet assisted vapor deposition. The average coating thickness was found to increase initially with gas pressure reaching a maximum at a chamber pressure of 8–10 Pa, but the best coating thickness uniformity was achieved under high vacuum deposition conditions. However, high vacuum conditions increased the variation in the coatings pore volume fraction over the surface of the airfoil. The simulation approach was combined with an optimization algorithm and used to investigate novel deposition concepts to tailor the local coating thickness.

  9. Microstructure of vapor deposited coatings on curved substrates

    International Nuclear Information System (INIS)

    Rodgers, Theron M.; Zhao, Hengbei; Wadley, Haydn N. G.

    2015-01-01

    Thermal barrier coating systems consisting of a metallic bond coat and ceramic over layer are widely used to extend the life of gas turbine engine components. They are applied using either high-vacuum physical vapor deposition techniques in which vapor atoms rarely experience scattering collisions during propagation to a substrate, or by gas jet assisted (low-vacuum) vapor deposition techniques that utilize scattering from streamlines to enable non-line-of-sight deposition. Both approaches require substrate motion to coat a substrate of complex shape. Here, direct simulation Monte Carlo and kinetic Monte Carlo simulation methods are combined to simulate the deposition of a nickel coating over the concave and convex surfaces of a model airfoil, and the simulation results are compared with those from experimental depositions. The simulation method successfully predicted variations in coating thickness, columnar growth angle, and porosity during both stationary and substrate rotated deposition. It was then used to investigate a wide range of vapor deposition conditions spanning high-vacuum physical vapor deposition to low-vacuum gas jet assisted vapor deposition. The average coating thickness was found to increase initially with gas pressure reaching a maximum at a chamber pressure of 8–10 Pa, but the best coating thickness uniformity was achieved under high vacuum deposition conditions. However, high vacuum conditions increased the variation in the coatings pore volume fraction over the surface of the airfoil. The simulation approach was combined with an optimization algorithm and used to investigate novel deposition concepts to tailor the local coating thickness

  10. Geology of the Pennsylvanian and Permian Culter Group and Permian Kaibab Limestone in the Paradox Basin, southeastern Utah and southwestern Colorado

    Science.gov (United States)

    Condon, Steven M.

    1997-01-01

    The Cutler Formation is composed of thick, arkosic, alluvial sandstones shed southwestward from the Uncompahgre highlands into the Paradox Basin. Salt tectonism played an important role in deposition of the Cutler in some areas. In the northeast part of the basin, more than 8,000 ft, and as much as 15,000 ft, of arkose was trapped between rising salt anticlines - this arkose is thin to absent over the crests of some anticlines. In the western and southern parts of the basin, the Cutler is recognized as a Group consisting of, in ascending order: the lower Cutler beds, Cedar Mesa Sandstone, Organ Rock Formation, White Rim Sandstone, and De Chelly Sandstone. The aggregate thickness of these formations is less than 2,000 ft. The formations of the Cutler Group were deposited in a complex system of alluvial, eolian, and marine environments characterized by abrupt vertical and lateral lithologic changes. The basal Cutler is Pennsylvanian in age, but the bulk of the Group was deposited during the Permian. The Cutler is conformably underlain by the Pennsylvanian Hermosa Group across most of the basin. It is overlain unconformably by the Permian Kaibab Limestone in the western part of the Paradox Basin. The Cutler or Kaibab are overlain unconformably by the Triassic Moenkopi or Chinle Formations.

  11. Fluvial landscape development in the southwestern Kalahari during the Holocene - Chronology and provenance of fluvial deposits in the Molopo Canyon

    DEFF Research Database (Denmark)

    Ramisch, Arne; Bens, Oliver; Buylaert, Jan-Pieter

    2017-01-01

    are sparse and often discontinuous. Hence, little is known about Holocene environmental change in this region. This study focuses on reconstructing paleoenvironmental change from the timing and provenance of fluvial deposits located within the Molopo Canyon, which connects the southern Kalahari drainage...... to the deposition of alluvial fills. These results suggest that the southern Kalahari Drainage remained endorheic and therefore disconnected from the Orange River throughout the Holocene....

  12. The Quaternary alluvial systems tract of the Pantanal Basin, Brazil

    Directory of Open Access Journals (Sweden)

    Mario Luis Assine

    Full Text Available ABSTRACT The Pantanal Basin is an active sedimentary basin in central-west Brazil that consists of a complex alluvial systems tract characterized by the interaction between different river systems developed in one of the largest wetlands in the world. The Paraguay River is the trunk river system that drains the water and part of the sediment load received from areas outside of the basin. Depositional styles vary considerably along the river profiles throughout the basin, with the development of entrenched meandering belts, anastomosing reaches, and floodplain ponds. Paleodrainage patterns are preserved on the surface of abandoned lobes of fluvial fans, which also exhibit many degradational channels. Here, we propose a novel classification scheme according to which the geomorphology, hydrological regime and sedimentary dynamics of these fluvial systems are determined by the geology and geomorphology of the source areas. In this way, the following systems are recognized and described: (I the Paraguay trunk-river plains; (II fluvial fans sourced by the tablelands catchment area; (III fluvial fans sourced by lowlands; and (IV fluvial interfans. We highlight the importance of considering the influences of source areas when interpreting contrasting styles of fluvial architectures in the rock record.

  13. Influence of the film thickness on the structure, optical and electrical properties of ITO coatings deposited by sputtering at room temperature on glass and plastic substrates

    International Nuclear Information System (INIS)

    Guillén, C; Herrero, J

    2008-01-01

    Transparent and conductive indium tin oxide (ITO) films with thickness between 0.2 and 0.7 µm were deposited by sputtering at room temperature on glass and polyethylene terephthalate (PET) substrates. All films were polycrystalline, with crystallite size increasing and lattice distortion decreasing when the film thickness was increased. Besides, transmission in the near-infrared region is found to be decreasing and carrier concentration increasing when the film thickness was increased. For the same thickness, the lattice distortion is slightly lower and the carrier concentration higher for the layers grown on PET substrates. A direct relationship between the lattice distortion and the free carrier concentration has been established, applying to the films grown on glass and plastic substrates. By adjusting ITO coating thickness, sheet resistance below 15 Ω sq −1 and average visible transmittance about 90% have been achieved by sputtering at room temperature

  14. The anthracite of Nazar-Aylok Deposit

    International Nuclear Information System (INIS)

    Pachadzhanov, D.N.; Valiev, Yu.Ya.

    2013-01-01

    Present article is devoted to anthracite of Nazar-Aylok Deposit. The ash content, composition of coals of Nazar-Aylok Deposit and thickness of deposit were considered. The coal samples were studied by means of neutron activation analysis.

  15. Geomorphic Characterization of the FortyMile Wash Alluvial Fan, Nye County, Nevada, In Support of the Yucca Mountain Project

    International Nuclear Information System (INIS)

    Cline; De Long; Pelletier; Harrington

    2005-01-01

    In the event of an unlikely volcanic eruption through the proposed high-level radioactive waste repository at Yucca Mountain, contaminated ash would be deposited in portions of the Fortymile Wash drainage basin and would subsequently be redistributed to the Fortymile Wash alluvial fan by fluvial processes. As part of an effort to quantify the transport of contaminated ash throughout the fluvial system, characterization of the Fortymile Wash alluvial fan is required, especially the spatial distribution of fluvial activity over time scales of repository operation, and the rates of radionuclide migration into different soils on the fan. The Fortymile Wash alluvial fan consists of extremely low relief terraces as old as 70 ka. By conducting soils-geomorphic mapping and correlating relative surface ages with available geochronology from the Fortymile Wash fan and adjacent piedmonts, we identified 4 distinct surfaces on the fan. Surface ages are used to predict the relative stability of different areas of the fan to fluvial activity. Pleistocene-aged surfaces are assumed to be fluvially inactive over the 10 kyr time scale, for example. Our mapping and correlation provides a map of the depozone for contaminated ash that takes into account long-term channel migration the time scales of repository operation, and it provides a geomorphic framework for predicting radionuclide dispersion rates into different soils across the fan. The standard model for vertical migration of radionuclides in soil is diffusion; therefore we used diffusion profiles derived from 137 Cs fallout to determine infiltration rates on the various geomorphic surfaces. The results show a strong inverse correlation of the geomorphic surface age and diffusivity values inferred from the 137 Cs profiles collected on the different surfaces of the fan

  16. Strontium isotope geochemistry of alluvial groundwater: a tracer for groundwater resources characterisation

    Directory of Open Access Journals (Sweden)

    P. Négrel

    2004-01-01

    Full Text Available This study presents strontium isotope and major ion data of shallow groundwater and river water from the Ile du Chambon catchment, located on the Allier river in the Massif Central (France. There are large variations in the major-element contents in the surface- and groundwater. Plotting of Na vs. Cl contents and Ca, Mg, NO3, K, SO4, HCO3, Sr concentrations reflect water–rock interaction (carbonate dissolution for Ca, Mg, HCO3 and Sr because the bedrock contains marly limestones, agricultural input (farming and fertilising and sewage effluents (for NO3, K, SO4, although some water samples are unpolluted. Sr contents and isotope ratios (87Sr/86Sr vary from 0.70892 to 0.71180 along the hydrological cycle in the groundwater agree with previous work on groundwater in alluvial aquifers in the Loire catchment. The data plot along three directions in a 87Sr/86Sr v. 1/Sr diagram as a result of mixing, involving at least three geochemical signatures–Allier river water, and two distinct signatures that might be related to different water-rock interactions in the catchment. Mixing proportions are calculated and discussed. The alluvial aquifer of the Ile du Chambon catchment is considered, within the Sr isotope systematic, in a larger scheme that includes several alluvial aquifers of the Loire Allier catchment. Keywords: : Loire river, major and trace elements, Sr isotopic ratio, alluvial aquifer, hydrology

  17. Dependences of microstructure and critical current density on the thickness of YBa2Cu3O7-x film prepared by pulsed laser deposition on buffered Ni–W tape

    International Nuclear Information System (INIS)

    Xu, Da; Wang, Ying; Liu, Linfei; Li, Yijie

    2013-01-01

    YBa 2 Cu 3 O 7−x (YBCO) films with different thicknesses were fabricated on buffered Ni–W tapes by pulsed laser deposition. The thickness dependences of microstructure and critical current density (J c ) of YBCO film were systematically investigated. The microstructure and surface morphology of YBCO film were characterized by X-ray diffraction, optical microscopy, field emission scanning electron microscopy and atomic force microscopy. And the critical current (I c ) of YBCO film was measured by the conventional four-probe method. We found that the full width at half maximum values of both omega and phi scan rocking curves, the content of a-axis oriented grain, and surface roughness of YBCO film all increased with augmenting the thickness of YBCO film. It was also found that with increasing the thickness of YBCO film from 0.3 μm to 1.5 μm, the I c of YBCO film increased from 72 A/cm to 248 A/cm and yet J c of YBCO film decreased from 2.1 × 10 6 A/cm 2 to 1.6 × 10 6 A/cm 2 . Our results indicated that the microstructure and J c of YBCO film were largely dependent on the thickness of YBCO film under the optimized deposition condition of substrate temperature. - Highlights: ► YBa 2 Cu 3 O 7−x (YBCO) films with different thicknesses were grown on metallic tapes. ► The texture and critical current were dependent on the thickness of YBCO film. ► Thickness effect was weakened by fabricating YBCO film layer by layer

  18. Electrophoretic Deposition of Gallium with High Deposition Rate

    Directory of Open Access Journals (Sweden)

    Hanfei Zhang

    2014-12-01

    Full Text Available In this work, electrophoretic deposition (EPD is reported to form gallium thin film with high deposition rate and low cost while avoiding the highly toxic chemicals typically used in electroplating. A maximum deposition rate of ~0.6 μm/min, almost one order of magnitude higher than the typical value reported for electroplating, is obtained when employing a set of proper deposition parameters. The thickness of the film is shown to increase with deposition time when sequential deposition is employed. The concentration of Mg(NO32, the charging salt, is also found to be a critical factor to control the deposition rate. Various gallium micropatterns are obtained by masking the substrate during the process, demonstrating process compatibility with microfabrication. The reported novel approach can potentially be employed in a broad range of applications with Ga as a raw material, including microelectronics, photovoltaic cells, and flexible liquid metal microelectrodes.

  19. A genome wide association study for backfat thickness in Italian Large White pigs highlights new regions affecting fat deposition including neuronal genes

    Directory of Open Access Journals (Sweden)

    Fontanesi Luca

    2012-11-01

    Full Text Available Abstract Background Carcass fatness is an important trait in most pig breeding programs. Following market requests, breeding plans for fresh pork consumption are usually designed to reduce carcass fat content and increase lean meat deposition. However, the Italian pig industry is mainly devoted to the production of Protected Designation of Origin dry cured hams: pigs are slaughtered at around 160 kg of live weight and the breeding goal aims at maintaining fat coverage, measured as backfat thickness to avoid excessive desiccation of the hams. This objective has shaped the genetic pool of Italian heavy pig breeds for a few decades. In this study we applied a selective genotyping approach within a population of ~ 12,000 performance tested Italian Large White pigs. Within this population, we selectively genotyped 304 pigs with extreme and divergent backfat thickness estimated breeding value by the Illumina PorcineSNP60 BeadChip and performed a genome wide association study to identify loci associated to this trait. Results We identified 4 single nucleotide polymorphisms with P≤5.0E-07 and additional 119 ones with 5.0E-07 Conclusions Further investigations are needed to evaluate the effects of the identified single nucleotide polymorphisms associated with backfat thickness on other traits as a pre-requisite for practical applications in breeding programs. Reported results could improve our understanding of the biology of fat metabolism and deposition that could also be relevant for other mammalian species including humans, confirming the role of neuronal genes on obesity.

  20. NAA of the 'Minoan pumice' at Thera and comparison to alluvial pumice deposits in the Eastern Mediterranean region

    International Nuclear Information System (INIS)

    Bichler, M.; Egger, H.; Preisinger, A.; Ritter, D.; Stastny, P.

    1997-01-01

    Neutron activation analysis was used to determine up to 30 elements in the pumice layers from the 'Minoan eruption' at Thera (Santorini, Greece). Mt Pilato (Lipari, Italy) and in alluvial pumice from coasts of the Eastern Mediterranean region. The morphologically well distinguishable layers of the 'Minoan pumice' were found to be of nearly similar composition in respect to the elements determined and their distribution patterns could therefore be used to identify a sample as Santorinian or not. Additionally, this method was applied to pumice lumps found during archaeological excavations in the Nile delta, Egypt. The results showed that two of the three Egyptian samples are products of the Minoan eruption at Thera and therefore chronologically useful. A second group of pumices collected at Antalya (Turkey), Crete (Greece) and also in Egypt was found to have a distinctly different composition and is therefore related to another volcanic event. (author)

  1. Indium-Nitrogen Codoped Zinc Oxide Thin Film Deposited by Ultrasonic Spray Pyrolysis on n-(111 Si Substrate: The Effect of Film Thickness

    Directory of Open Access Journals (Sweden)

    Cheng-Chang Yu

    2014-01-01

    Full Text Available Indium-nitrogen codoped zinc oxide (INZO thin films were fabricated by spray pyrolysis deposition technique on n-(111 Si substrate with different film thicknesses at 450°C using a precursor containing zinc acetate, ammonium acetate, and indium nitrate with 1 : 3 : 0.05 at.% concentration. The morphology and structure studies were carried out by scanning electron microscopy (SEM and X-ray diffraction (XRD. The grain size of the films increased when increasing the film thickness. From XRD spectra, polycrystalline ZnO structure can be observed and the preferred orientation behavior varied from (002 to (101 as the film thickness increased. The concentration and mobility were investigated by Hall effect measurement. the p-type films with a hole mobility around 3 cm2V−1s−1 and hole concentration around 3×1019 cm−3 can be achieved with film thickness less than 385 nm. The n-type conduction with concentration 1×1020 cm−3 is observed for film with thickness 1089 nm. The defect states were characterized by photoluminescence. With temperature-dependent conductivity analysis, acceptor state with activation energy 0.139 eV dominate the p type conduction for thin INZO film. And the Zn-related shallow donors with activation energy 0.029 eV dominate the n-type conduction for the thick INZO film.

  2. Direct current magnetron sputter-deposited ZnO thin films

    International Nuclear Information System (INIS)

    Hoon, Jian-Wei; Chan, Kah-Yoong; Krishnasamy, Jegenathan; Tou, Teck-Yong; Knipp, Dietmar

    2011-01-01

    Zinc oxide (ZnO) is a very promising electronic material for emerging transparent large-area electronic applications including thin-film sensors, transistors and solar cells. We fabricated ZnO thin films by employing direct current (DC) magnetron sputtering deposition technique. ZnO films with different thicknesses ranging from 150 nm to 750 nm were deposited on glass substrates. The deposition pressure and the substrate temperature were varied from 12 mTorr to 25 mTorr, and from room temperature to 450 deg. C, respectively. The influence of the film thickness, deposition pressure and the substrate temperature on structural and optical properties of the ZnO films was investigated using atomic force microscopy (AFM) and ultraviolet-visible (UV-Vis) spectrometer. The experimental results reveal that the film thickness, deposition pressure and the substrate temperature play significant role in the structural formation and the optical properties of the deposited ZnO thin films.

  3. Inhalation of nanoplatelets - Theoretical deposition simulations.

    Science.gov (United States)

    Sturm, Robert

    2017-12-01

    Primary objective of the contribution was the theoretical prediction of nanoplatelet deposition in the human respiratory tract. Modeling was founded on the hypothetical inhalation of graphene nanoplatelets (GNP) measuring 0.01 and 0.1μm in thickness and adopting a projected area diameter of 1-30μm. Particle uptake was assumed to take place with inhalation flow rates of 250, 500, 750, and 1000cm 3 s -1 , respectively. For an appropriate description of pulmonary particle behavior, transport of GNP in a stochastic lung structure and deposition formulae based on analytical and numerical studies were presupposed. The results obtained from the theoretical approach clearly demonstrate that GNP with a thickness of 0.01μm deposit in the respiratory tract by 20-50%, whereas GNP with a thickness of 0.1μm exhibit a deposition of 20-90%. Larger platelets deposit with higher probability than small ones. Increase of inhalation flow rate is accompanied by decreased deposition in the case of thin GNP, whilst thicker GNP are preferably accumulated in the extrathoracic region. Generation-specific deposition ranges from 0.05 to 7% (0.01μm) and from 0.05 to 9%, with maximum values being obtained in airway generation 20. In proximal airway generations (0-10), deposition is increased with inhalation flow rate, whereas in intermediate to distal generations a reverse effect may be observed. Health consequences of GNP deposition in different lung compartments are subjected to an intense debate. Copyright © 2017. Published by Elsevier GmbH.

  4. Formation and physical properties of YBCO thick films grown by using the electrophoretic deposition method

    CERN Document Server

    Kim, U J; Kim, Y C; Han, S K; Kang, K Y

    1999-01-01

    Thick films of the YBa sub 2 Cu sub 3 O subgamma sub - subdelta (YBCO) superconductor were prepared by using the electrophoretic deposition technique and a flexible wire as the substrate. The transition temperature of the wires was 91 K, the intragranular magnetic critical current density J sub c sub g sup m sup a sup g was about 10 sup 5 A/cm sup 2 at 77 K in a weak field, and the transport J sub c sup t sup r sup a sup n sup s was about 365 A/cm sup 2 at 77 K. We calculated the intergranular magnetic critical current J sub c sub J sup m sup a sup g and the activation energy from the AC-susceptibility measurements, and their values were about 444 A/cm sup 2 at 77 K and 2.02 eV, respectively.

  5. Low temperature perovskite crystallization of highly tunable dielectric Ba0.7Sr0.3TiO3 thick films deposited by ion beam sputtering on platinized silicon substrates

    Science.gov (United States)

    Zhu, X. H.; Guigues, B.; Defaÿ, E.; Dubarry, C.; Aïd, M.

    2009-02-01

    Ba0.7Sr0.3TiO3 (BST) thick films with thickness up to 1 μm were deposited on Pt-coated silicon substrates by ion beam sputtering, followed by an annealing treatment. It is demonstrated that pure well-crystallized perovskite phase could be obtained in thick BST films by a low temperature process (535 °C). The BST thick films show highly tunable dielectric properties with tunability (at 800 kV/cm) up to 51.0% and 66.2%, respectively, for the 0.5 and 1 μm thick films. The relationship between strains and dielectric properties was systematically investigated in the thick films. The results suggest that a comparatively larger tensile thermal in-plane strain (0.15%) leads to the degradation in dielectric properties of the 0.5 μm thick film; besides, strong defect-related inhomogeneous strains (˜0.3%) make the dielectric peaks smearing and broadening in the thick films, which, however, preferably results in high figure-of-merit factors over a wide operating temperature range. Moreover, the leakage current behavior in the BST thick films was found to be dominated by the space-charge-limited-current mechanism, irrespective of the film thickness.

  6. Low temperature perovskite crystallization of highly tunable dielectric Ba0.7Sr0.3TiO3 thick films deposited by ion beam sputtering on platinized silicon substrates

    International Nuclear Information System (INIS)

    Zhu, X. H.; Defaye, E.; Aied, M.; Guigues, B.; Dubarry, C.

    2009-01-01

    Ba 0.7 Sr 0.3 TiO 3 (BST) thick films with thickness up to 1 μm were deposited on Pt-coated silicon substrates by ion beam sputtering, followed by an annealing treatment. It is demonstrated that pure well-crystallized perovskite phase could be obtained in thick BST films by a low temperature process (535 deg. C). The BST thick films show highly tunable dielectric properties with tunability (at 800 kV/cm) up to 51.0% and 66.2%, respectively, for the 0.5 and 1 μm thick films. The relationship between strains and dielectric properties was systematically investigated in the thick films. The results suggest that a comparatively larger tensile thermal in-plane strain (0.15%) leads to the degradation in dielectric properties of the 0.5 μm thick film; besides, strong defect-related inhomogeneous strains (∼0.3%) make the dielectric peaks smearing and broadening in the thick films, which, however, preferably results in high figure-of-merit factors over a wide operating temperature range. Moreover, the leakage current behavior in the BST thick films was found to be dominated by the space-charge-limited-current mechanism, irrespective of the film thickness

  7. Natural hazards on alluvial fans: the debris flow and flash flood disaster of December 1999, Vargas state, Venezuela

    Science.gov (United States)

    Larsen, Matthew C.; Wieczorek, Gerald F.; Eaton, L.S.; Torres-Sierra, Heriberto; Sylva, Walter F.

    2001-01-01

    Large populations live on or near alluvial fans in locations such as Los Angeles, California, Salt Lake City, Utah, Denver, Colorado, and lesser known areas such as Sarno, Italy, and Vargas, Venezuela. Debris flows and flash floods occur episodically in these alluvial fan environments, and place many communities at high risk during intense and prolonged rainfall. In December 1999, rainstorms induced thousands of landslides along the Cordillera de la Costa, Vargas, Venezuela. Rainfall accumulation of 293 mm during the first 2 weeks of December was followed by an additional 911 mm of rainfall on December 14 through 16. Debris flows and floods inundated coastal communities resulting in a catastrophic death toll of as many as 30,000 people. Flash floods and debris flows caused severe property destruction on alluvial fans at the mouths of the coastal mountain drainage network. In time scales spanning thousands of years, the alluvial fans along this Caribbean coastline are dynamic zones of high geomorphic activity. Because most of the coastal zone in Vargas consists of steep mountain fronts that rise abruptly from the Caribbean Sea, the alluvial fans provide practically the only flat areas upon which to build. Rebuilding and reoccupation of these areas requires careful determination of hazard zones to avoid future loss of life and property. KEY TERMS: Debris flows, flash floods, alluvial fans, natural hazards, landslides, Venezuela

  8. Temporal-spatial variation and source apportionment of soil heavy metals in the representative river-alluviation depositional system.

    Science.gov (United States)

    Wang, Cheng; Yang, Zhongfang; Zhong, Cong; Ji, Junfeng

    2016-09-01

    The contributions of major driving forces on temporal changes of heavy metals in the soil in a representative river-alluviation area at the lower of Yangtze River were successfully quantified by combining geostatistics analysis with the modified principal component scores & multiple linear regressions approach (PCS-MLR). The results showed that the temporal (2003-2014) changes of Cu, Zn, Ni and Cr presented a similar spatial distribution pattern, whereas the Cd and Hg showed the distinctive patterns. The temporal changes of soil Cu, Zn, Ni and Cr may be predominated by the emission of the shipbuilding industry, whereas the significant changes of Cd and Hg were possibly predominated by the geochemical and geographical processes, such as the erosion of the Yangtze River water and leaching because of soil acidification. The emission of metal-bearing shipbuilding industry contributed an estimated 74%-83% of the changes in concentrations of Cu, Zn, Ni and Cr, whereas the geochemical and geographical processes may contribute 58% of change of Cd in the soil and 59% of decrease of Hg. Copyright © 2016 Elsevier Ltd. All rights reserved.

  9. Textural and Compositional Characterization of Wadi Feiran Deposits, Sinai Peninsula, Egypt, Using Radarsat-1, PALSAR, SRTM and ETM+ Data

    Directory of Open Access Journals (Sweden)

    Ahmed Gaber

    2009-12-01

    Full Text Available The present work aims at identifying favorable locations for groundwater resources harvesting and extraction along the Wadi Feiran basin, SW Sinai Peninsula, Egypt, in an effort to facilitate new development projects in this area. Landsat ETM+, Radarsat-1 and PALSAR images of Wadi Feiran basin were used in this work to perform multisource data fusion and texture analysis, in order to classify the wadi deposits based on grain size distribution and predominant rock composition as this information may lead to the location of new groundwater resources. An unsupervised classification was first performed on two sets of fused images (i.e., ETM+/Radarsat-1 and ETM+/PALSAR resulting in five classes (hybrid classes describing the main alluvial sediments in the wadi system. Some variations in the spatial distribution of individual classes were observed, due to the different spectral and spatial resolutions of Radarsat-1 (C-band, 12.5 m and PALSAR (L-band, 6.25 m data. Alluvial deposits are mixtures of parent rocks located further upstream often at a great distance. In order to classify the alluvial deposits in terms of individual rock types (endmembers, a spectral linear unmixing of the optical ETM+ image was performed. Subsequently, each class of the fused (hybrid images was correlated with (1 individual rock type fractions (endmembers obtained from spectrally unmixing the ETM+ image, (2 the geocoded and calibrated radar images (Radarsat-1 and PALSAR and, (3 the slope map generated from the SRTM data. The goal was to determine predominant rock composition, mean backscatter and slope values for each of the five hybrid classes. Backscatter coefficient values extracted from both radar data (C- and L-band were correlated and checked in the field, confirming that both wavelengths produced more or less similar textural classes that correspond to specific grain or fragment sizes of alluvial deposits. However, comparison of the spatial distribution of matching

  10. Thickness-modulated tungsten-carbon superconducting nanostructures grown by focused ion beam induced deposition for vortex pinning up to high magnetic fields.

    Science.gov (United States)

    Serrano, Ismael García; Sesé, Javier; Guillamón, Isabel; Suderow, Hermann; Vieira, Sebastián; Ibarra, Manuel Ricardo; De Teresa, José María

    2016-01-01

    We report efficient vortex pinning in thickness-modulated tungsten-carbon-based (W-C) nanostructures grown by focused ion beam induced deposition (FIBID). By using FIBID, W-C superconducting films have been created with thickness modulation properties exhibiting periodicity from 60 to 140 nm, leading to a strong pinning potential for the vortex lattice. This produces local minima in the resistivity up to high magnetic fields (2.2 T) in a broad temperature range due to commensurability effects between the pinning potential and the vortex lattice. The results show that the combination of single-step FIBID fabrication of superconducting nanostructures with built-in artificial pinning landscapes and the small intrinsic random pinning potential of this material produces strong periodic pinning potentials, maximizing the opportunities for the investigation of fundamental aspects in vortex science under changing external stimuli (e.g., temperature, magnetic field, electrical current).

  11. Loess Thickness Variations Across the Loess Plateau of China

    Science.gov (United States)

    Zhu, Yuanjun; Jia, Xiaoxu; Shao, Mingan

    2018-01-01

    The soil thickness is very important for investigating and modeling soil-water processes, especially on the Loess Plateau of China with its deep loess deposit and limited water resources. A digital elevation map (DEM) of the Loess Plateau and neighborhood analysis in ArcGIS software were used to generate a map of loess thickness, which was then validated by 162 observations across the plateau. The generated loess thickness map has a high resolution of 100 m × 100 m. The map indicates that loess is thick in the central part of the plateau and becomes gradually shallower in the southeast and northwest directions. The areas near mountains and river basins have the shallowest loess deposit. The mean loess thickness is the deepest in the zones with 400-600-mm precipitation and decreases gradually as precipitation varies beyond this range. Our validation indicates that the map just slightly overestimates loess thickness and is reliable. The loess thickness is mostly between 0 and 350 m in the Loess Plateau region. The calculated mean loess thickness is 105.7 m, with the calibrated value being 92.2 m over the plateau exclusive of the mountain areas. Our findings provide very basic data of loess thickness and demonstrate great progress in mapping the loess thickness distribution for the plateau, which are valuable for a better study of soil-water processes and for more accurate estimations of soil water, carbon, and solute reservoirs in the Loess Plateau of China.

  12. Large Area Deposition of MoS2 by Pulsed Laser Deposition with In-Situ Thickness Control

    KAUST Repository

    Serna, Martha I.

    2016-05-24

    A scalable and catalyst-free method to deposit stoichiometric Molybdenum Disulfide (MoS2) films over large areas is reported with the maximum area limited by the size of the substrate holder. The method allows deposition of MoS2 layers on a wide range of substrates without any additional surface preparation including single crystals (sapphire and quartz), polycrystalline (HfO2), and amorphous (SiO2). The films are deposited using carefully designed MoS2 targets fabricated with excess of sulfur (S) and variable MoS2 and S particle size. Uniform and layered MoS2 films as thin as two monolayers, with an electrical resistivity of 1.54 × 104 Ω cm-1 were achieved. The MoS2 stoichiometry was as confirmed by High Resolution Rutherford Backscattering Spectrometry (HRRBS). With the method reported here, in situ graded MoS2 films ranging from ~1 to 10 monolayers can also be deposited.

  13. Large Area Deposition of MoS2 by Pulsed Laser Deposition with In-Situ Thickness Control

    KAUST Repository

    Serna, Martha I.; Yoo, Seong H.; Moreno, Salvador; Xi, Yang; Oviedo, Juan Pablo; Choi, Hyunjoo; Alshareef, Husam N.; Kim, Moon J.; Minary-Jolandan, Majid; Quevedo-Lopez, Manuel A.

    2016-01-01

    A scalable and catalyst-free method to deposit stoichiometric Molybdenum Disulfide (MoS2) films over large areas is reported with the maximum area limited by the size of the substrate holder. The method allows deposition of MoS2 layers on a wide range of substrates without any additional surface preparation including single crystals (sapphire and quartz), polycrystalline (HfO2), and amorphous (SiO2). The films are deposited using carefully designed MoS2 targets fabricated with excess of sulfur (S) and variable MoS2 and S particle size. Uniform and layered MoS2 films as thin as two monolayers, with an electrical resistivity of 1.54 × 104 Ω cm-1 were achieved. The MoS2 stoichiometry was as confirmed by High Resolution Rutherford Backscattering Spectrometry (HRRBS). With the method reported here, in situ graded MoS2 films ranging from ~1 to 10 monolayers can also be deposited.

  14. Fertilizers mobilization in alluvial aquifer: laboratory experiments

    Science.gov (United States)

    Mastrocicco, M.; Colombani, N.; Palpacelli, S.

    2009-02-01

    In alluvial plains, intensive farming with conspicuous use of agrochemicals, can cause land pollution and groundwater contamination. In central Po River plain, paleo-channels are important links between arable lands and the underlaying aquifer, since the latter is often confined by clay sediments that act as a barrier against contaminants migration. Therefore, paleo-channels are recharge zones of particular interest that have to be protected from pollution as they are commonly used for water supply. This paper focuses on fertilizer mobilization next to a sand pit excavated in a paleo-channel near Ferrara (Italy). The problem is approached via batch test leaking and columns elution of alluvial sediments. Results from batch experiments showed fast increase in all major cations and anions, suggesting equilibrium control of dissolution reactions, limited availability of solid phases and geochemical homogeneity of samples. In column experiments, early elution and tailing of all ions breakthrough was recorded due to preferential flow paths. For sediments investigated in this study, dispersion, dilution and chemical reactions can reduce fertilizers at concentration below drinking standards in a reasonable time frame, provided fertilizer loading is halted or, at least, reduced. Thus, the definition of a corridor along paleo-channels is recommended to preserve groundwater quality.

  15. Metabolism of 14C-lindane in flooded alluvial soil

    International Nuclear Information System (INIS)

    Siddaramappa, R.; Sethunathan, N.

    1975-01-01

    The effect of rice straw on the persistence of uniformly ring labelled 14 C-lindane in an alluvial soil was investigated under flooded conditions. The residues in the soil were extracted with chloroform-diethyl ether and the radioactivity was measured by liquid scintillation. The radioactivity in the solvent phase decreased more rapidly in amended soil than in unamended soil. Radioautograph of thin layer chromatograms of solvent phase indicated that lindane was readily converted to a breakdown product in both amended and unamended soils. This breakdown product was also formed in both autoclaved and nonautoclaved soils. Rice straw amendment enhanced further decomposition of lindane and its breakdown product. Heat treatment retarded further decomposition of lindane and its breakdown product whereas they were rapidly decomposed in nonautoclaved soil. These studies indicated that in flooded alluvial soil tested, lindane was initially decomposed by a chemical reaction and soil microorganisms appeared to attack the products of the chemical reaction. (author)

  16. Peclet number as affected by molecular diffusion controls transient anomalous transport in alluvial aquifer-aquitard complexes

    Science.gov (United States)

    Zhang, Yong; Green, Christopher T.; Tick, Geoffrey R.

    2015-01-01

    This study evaluates the role of the Peclet number as affected by molecular diffusion in transient anomalous transport, which is one of the major knowledge gaps in anomalous transport, by combining Monte Carlo simulations and stochastic model analysis. Two alluvial settings containing either short- or long-connected hydrofacies are generated and used as media for flow and transport modeling. Numerical experiments show that 1) the Peclet number affects both the duration of the power-law segment of tracer breakthrough curves (BTCs) and the transition rate from anomalous to Fickian transport by determining the solute residence time for a given low-permeability layer, 2) mechanical dispersion has a limited contribution to the anomalous characteristics of late-time transport as compared to molecular diffusion due to an almost negligible velocity in floodplain deposits, and 3) the initial source dimensions only enhance the power-law tail of the BTCs at short travel distances. A tempered stable stochastic (TSS) model is then applied to analyze the modeled transport. Applications show that the time-nonlocal parameters in the TSS model relate to the Peclet number, Pe. In particular, the truncation parameter in the TSS model increases nonlinearly with a decrease in Pe due to the decrease of the mean residence time, and the capacity coefficient increases with an increase in molecular diffusion which is probably due to the increase in the number of immobile particles. The above numerical experiments and stochastic analysis therefore reveal that the Peclet number as affected by molecular diffusion controls transient anomalous transport in alluvial aquifer–aquitard complexes.

  17. Potency of Thorium and Uranium in West Bangka Region

    International Nuclear Information System (INIS)

    Ngadenin; Heri Syaeful; Kurnia Setiawan Widana; Muhammad Nurdin

    2014-01-01

    Thorium and uranium in Bangka Island are mainly found in monazite mineral. In the geological point of view the monazite formed in S type granite, sandstones and alluvial deposits. In Bangka Barat where several S types granite and also alluvial deposits and this area considered as a potential area for monazite placer. S type granites are predicted as a source of monazite while alluvial deposits are considered as a dispersion place for deposition of monazite. The purpose of this study is to determine the geological information and to know the hypothetical potency of thorium and uranium resources in alluvial deposits. The methods used in this study are geological mapping, measurement of thorium and uranium contents in the rock, sampling of granite for petrographic analysis, sampling of heavy mineral in alluvial deposits for grain size analysis. Results of the research show that the lithology of West Bangka region composed of schist unit, meta-sandstone unit, granite intrusion, diabase intrusion, sandstone unit and alluvial deposits. Monazite is found in granite intrusion, sandstone unit and alluvial deposits. Evolving fault strand to northwest-southeast, northeast-southwest and west-east. The results of the grain size analysis of heavy mineral shows the average percentage of monazite in the heavy mineral is 6.34%. Other potential minerals contained in placer deposits are zircon 36.65%, ilmenite 19.67% and cassiterite 14.75%. (author)

  18. Enhancing flood hazard estimation methods on alluvial fans using an integrated hydraulic, geological and geomorphological approach

    Science.gov (United States)

    Mollaei, Zeinab; Davary, Kamran; Majid Hasheminia, Seyed; Faridhosseini, Alireza; Pourmohamad, Yavar

    2018-04-01

    Due to the uncertainty concerning the location of flow paths on active alluvial fans, alluvial fan floods could be more dangerous than riverine floods. The United States Federal Emergency Management Agency (FEMA) used a simple stochastic model named FAN for this purpose, which has been practiced for many years. In the last decade, this model has been criticized as a consequence of development of more complex computer models. This study was conducted on three alluvial fans located in northeast and southeast Iran using a combination of the FAN model, the hydraulic portion of the FLO-2D model, and geomorphological information. Initial stages included three steps: (a) identifying the alluvial fans' landforms, (b) determining the active and inactive areas of alluvial fans, and (c) delineating 100-year flood within these selected areas. This information was used as an input in the mentioned three approaches of the (i) FLO-2D model, (ii) geomorphological method, and (iii) FAN model. Thereafter, the results of each model were obtained and geographical information system (GIS) layers were created and overlaid. Afterwards, using a scoring system, the results were evaluated and compared. The goal of this research was to introduce a simple but effective solution to estimate the flood hazards. It was concluded that the integrated method proposed in this study is superior at projecting alluvial fan flood hazards with minimum required input data, simplicity, and affordability, which are considered the primary goals of such comprehensive studies. These advantages are more highlighted in underdeveloped and developing countries, which may well lack detailed data and financially cannot support such costly projects. Furthermore, such a highly cost-effective method could be greatly advantageous and pragmatic for developed countries.

  19. Geomorphological and cryostratigraphical analyses of the Zackenberg Valley, NE Greenland and significance of Holocene alluvial fans

    Science.gov (United States)

    Cable, Stefanie; Christiansen, Hanne H.; Westergaard-Nielsen, Andreas; Kroon, Aart; Elberling, Bo

    2018-02-01

    In High Arctic northern Greenland, future responses to climatic changes are poorly understood on a landscape scale. Here, we present a study of the geomorphology and cryostratigraphy in the Zackenberg Valley in NE Greenland (74°N) containing a geomorphological map and a simplified geocryological map, combined with analyses of 13 permafrost cores and two exposures. Cores from a solifluction sheet, alluvial fans, and an emerged delta were studied with regards to cryostructures, ice and total carbon contents, grain size distribution, and pore water electrical conductivity; and the samples were AMS 14C dated. The near-surface permafrost on slopes and alluvial fans is ice rich, as opposed to the ice-poor epigenetic permafrost in the emerged delta. Ground ice and carbon distribution are closely linked to sediment transport processes, which largely depend on lithology and topography. Holocene alluvial fans on the lowermost hillslopes, covering 12% of the study area, represent paleoenvironmental archives. During the contrasting climates of the Holocene, the alluvial fans continued to aggrade - through the warmer early Holocene Optimum, the colder late Holocene, and the following climate warming - and by 0.45 mm a- 1, on average. This is caused by three factors: sedimentation, ground ice aggradation, and vegetation growth and is reflected by AMS 14C dating and continuously alternating cryostructures. Highly variable sedimentation rates in space and time at the alluvial fans have been detected. This is also reflected by alternating lenticular and microlenticular cryostructures indicating syngenetic permafrost aggradation during sedimentation with suspended and organic-matrix cryostructures indicating quasi-syngenetic permafrost aggradation in response to vegetation growth in periods with reduced or no sedimentation. Over time, this causes organic matter to become buried, indicating that alluvial fans represent effective carbon sinks that have previously been overlooked.

  20. An X-ray fluorescence method for the determination of metals thicknesses

    International Nuclear Information System (INIS)

    Vazquez, Cristina; Leyt, D.V. de; Riveros, J.A.

    1987-01-01

    An absolute method for the determination of the thickness of a metal film deposited on a metallic substrate is described. The method is based on the measurement of fluorescent intensity ratios for two lines from the substrate element. Additionally, the proposed method can be employed to determine the density of the deposited material or the incident angle of primary radiation and take off angle, if the metal film thickness is known. (Author) [es

  1. Effect of thickness on structural, corrosion and mechanical properties of a thin ZrN film deposited by medium frequency (MF) reactive sputtering

    Energy Technology Data Exchange (ETDEWEB)

    Kavitha, Ayyalu; Kannan, Raman [Anna Univ., Dindigul (India). Dept. of Physics; Loganathan, Subramani [Titan Industries, Hosur, Tamilnadu (India). Ion Plating Dept.

    2016-07-01

    Zirconium nitride (ZrN) thin films were prepared on stainless steel (SS) substrates by medium frequency (MF) reactive sputtering with gas ion source (GIS) by varying the deposition time and obtained thickness (t{sub ZrN}) in the range of 1.25 to 3.24 μm. The effect of thickness on the structural and microstructural properties was studied using XRD and AFM. XRD characterization revealed that the texture of the ZrN thin films changes as a function of thickness. Both, the (111) and (200) peak, appear initially and (111) becomes more intense with increasing t{sub ZrN}. AFM imaging revealed that the ZrN thin film coated with t{sub ZrN} ∼ 3.24 μm shows larger grains that are uniformly distributed over the surface. An average hardness value of 19.79 GPa was observed for ZrN thin films having t{sub ZrN} ∼ 3.24 μm. The ZrN thin films having t{sub ZrN} ∼ 3.24 μm exhibits better adhesion strength up to 20 N. The electrochemical polarization studies indicated that the ZrN thin film having larger thickness shows improved corrosion resistance compared to SS in 3.5 % NaCl solution.

  2. Controlling the resistivity gradient in chemical vapor deposition-deposited aluminum-doped zinc oxide

    NARCIS (Netherlands)

    Ponomarev, M. V.; Verheijen, M. A.; Keuning, W.; M. C. M. van de Sanden,; Creatore, M.

    2012-01-01

    Aluminum-doped ZnO (ZnO:Al) grown by chemical vapor deposition (CVD) generally exhibit a major drawback, i.e., a gradient in resistivity extending over a large range of film thickness. The present contribution addresses the plasma-enhanced CVD deposition of ZnO: Al layers by focusing on the control

  3. Thick and low-stress PECVD amorphous silicon for MEMS applications

    International Nuclear Information System (INIS)

    Iliescu, Ciprian; Chen Bangtao

    2008-01-01

    This paper presents a solution for the deposition of thick amorphous silicon (α-Si:H) in PECVD reactors for MEMS applications, such as sacrificial layer or mask layer for dry or wet etching of glass. This achievement was possible by tuning the deposition parameters to a 'zero' value of the residual stress in the α-Si:H layer. The influence of the process parameters, such as power, frequency mode, temperature, pressure and SiH 4 /Ar flow rates for tuning the residual stress and for a good deposition rate is analyzed. The deposition of low-stress and thick (more than 12 µm in our case) α-Si:H layers was possible without generation of hillock defects (previously reported in literature for layers thicker then 2 µm). Finally, the paper presents some MEMS applications of such a deposited α-Si:H layer: masking layer for deep wet etching as well as dry etching of glass, and sacrificial layer for dry or wet release

  4. Numerical simulation of the internal stresses of thick tungsten coating deposited by vacuum plasma spraying on copper substrate

    International Nuclear Information System (INIS)

    Salito, A.; Tului, M.; Casadei, F.

    1998-01-01

    Several Divertor components in the new generation of nuclear fusion reactors need to be protected against ion sputtering. Particularly copper based (Cu) material is very sensitive to this sputtering process. A solution to overcome such component wear and plasma contamination is to protect the copper substrate with a thick tungsten (W) functional coating. The main difficulty to produce such components is the significant difference in the coating thermomechanical properties between W and Cu. The Vacuum Plasma Spraying coating process (VPS) is a very flexible new economical way to find a solution to the above problem. To optimise the adhesion and stress release properties between the Cu-alloy substrate and the W coating, it is possible to deposit an interlayer as a bond coat between both materials. The aim of this study is to determine the maximum of the residual stresses located between the Cu substrate and the W coating using finite element analysis. The results have been used to select different types of bond coat for the experimental development of thick W coating (>3 mm) on to mock-ups for the Divertor Channel of the ITER project. (author)

  5. Fluvial sedimentary styles and associated depositional environments in the buntsandstein west of river rhine in saar area and pfalz (F.R. Germany) and vosges (France)

    Science.gov (United States)

    Dachroth, Wolfgang

    The Buntsandstein west of river Rhine in Saar area, Pfalz and Vosges consists of three fluvial magnacycles which are characterized by different associated non-alluvial environments. The stratigraphic sequence is divided by several unconformities reflecting tectonic movements which were connected with periods of extension of the depositional area. Two major phases and two minor events are recognized by the evaluation of the Pfalz unconformity and the Lothringen unconformity, and the Leuter unconformity and the Saar unconformity, respectively. The Lower Buntsandstein (including Zechstein) compries the first magnacycle and is built up of alluvial-fan deposits, fluvial braidplain sediments and marine to lagoonal deposits. Some aeolian sands as well as several palaeosols are also present. The palaeolandscape consists of alluvial fans seaming the margin of the basin and fluvial braidplains reaching from the toes of the fan belt to the centre of the depositional area which is occupied by a lagoonal sea that partially evolves into a playa-lake with progressive refreshment. The Middle Buntsandstein comprises the second magnacycle and is composed of an alternation of aeolian Dünnschichten and fluvial Felsbänke. The third facies are alluvial-fan deposits of palaeogeographically restricted distribution along the margins of the basin. The aeolian Dünnschichten originate in the marginal parts of chott-type depressions (in comparison with the recent Chott Djerid in Tunesia) where rising ground water moistens the dry sediments that are laid down on the playa floor and thus allows their enhanced preservation. In dry periods, wind-blown sand is spread out as plane sheets or as migrating wind ripple trains, or accumulates to barchanoid-type dunes that advance across the flat. Depending on supply of sand, all stages of transition between dune fields with only narrow interdune corridors between the ridges and interdune playas with isolated widely-spaced dunes are developed. The

  6. Alluvial diamond resource potential and production capacity assessment of Mali

    Science.gov (United States)

    Chirico, Peter G.; Barthelemy, Francis; Kone, Fatiaga

    2010-01-01

    In May of 2000, a meeting was convened in Kimberley, South Africa, and attended by representatives of the diamond industry and leaders of African governments to develop a certification process intended to assure that rough, exported diamonds were free of conflictual concerns. This meeting was supported later in 2000 by the United Nations in a resolution adopted by the General Assembly. By 2002, the Kimberley Process Certification Scheme (KPCS) was ratified and signed by diamond-producing and diamond-importing countries. Over 70 countries were included as members of the KPCS at the end of 2007. To prevent trade in "conflict diamonds" while protecting legitimate trade, the KPCS requires that each country set up an internal system of controls to prevent conflict diamonds from entering any imported or exported shipments of rough diamonds. Every diamond or diamond shipment must be accompanied by a Kimberley Process (KP) certificate and be contained in tamper-proof packaging. The objective of this study was (1) to assess the naturally occurring endowment of diamonds in Mali (potential resources) based on geological evidence, previous studies, and recent field data and (2) to assess the diamond-production capacity and measure the intensity of mining activity. Several possible methods can be used to estimate the potential diamond resource. However, because there is generally a lack of sufficient and consistent data recording all diamond mining in Mali and because time to conduct fieldwork and accessibility to the diamond mining areas are limited, four different methodologies were used: the cylindrical calculation of the primary kimberlitic deposits, the surface area methodology, the volume and grade approach, and the content per kilometer approach. Approximately 700,000 carats are estimated to be in the alluvial deposits of the Kenieba region, with 540,000 carats calculated to lie within the concentration grade deposits. Additionally, 580,000 carats are estimated to have

  7. The paradigm of paraglacial megafans of the San Juan river basin, Central Andes, Argentina

    Science.gov (United States)

    Suvires, Graciela M.

    2014-11-01

    The spatial distribution and several morphometric characteristics of the Quaternary alluvial fans of the San Juan River, in the province of San Juan, at the Central and Western part of Argentina, have been studied to classify them as paraglacial megafans, as well to ratify its depositional environmental conditions. The high sedimentary load exported by San Juan river from the Central Andes to the foreland depressions is estimated about 3,682,200 hm3. The large alluvial fans of Ullum-Zonda and Tulum valleys were deposited into deep tectonic depressions, during the Upper Pleistocene deglaciation stages. The outcome of collecting remotely sensed data, map and DEM data, geophysical data and much fieldwork gave access to morphometric, morphographic and morphogenetic data of these alluvial fans. The main drainage network was mapped on processed images using QGis (vers.2.0.1). Several fan morphometric parameters were measured, such as the size, the shape, the thickness, the surface areas and the sedimentary volume of exported load. The analyzed fans were accumulated in deep tectonic depressions, where the alluvium fill reaches 700 to 1200 m thick. Such fans do not reach the large size that other world megafans have, and this is due to tectonic obstacles, although the sedimentary fill average volume surpasses 514,000 hm3. The author proposes to consider Ullum-Zonda and Tulum alluvial fans as paraglacial megafans. According to the stratigraphic relationships of the tropical South American Rivers, the author considers that the San Juan paraglacial megafans would have occurred in the period before 24 ka BP , possibly corresponding to Middle Pleniglacial (ca 65-24ka BP). They record colder and more humid conditions compared with the present arid and dry conditions.

  8. Hydrochemical Processes in the Alluvial Aquifer of the Gwydir River (Northern New South Wales, Australia)

    OpenAIRE

    Menció, Anna; Mas-Pla, Josep; Korbel, Kathryn; Hose, Grant C.

    2013-01-01

    The hydrochemistry of the Narrabri Formation, the shallow aquifer system of the alluvial fan of the Gwydir River (NSW, Australia), is analyzed to better understand the hydrogeological processes involved in aquifer recharge, and to set up future management options that preserve the quantity and quality of water resources. Results show that groundwater hydrochemistry in this alluvial aquifer is mainly controlled by silicate weathering and cation exchange. However, salt remobilization in specifi...

  9. Impacts of hydroelectric dams on alluvial riparian plant communities in Eastern Brazilian Amazonian.

    Science.gov (United States)

    Ferreira, Leandro Valle; Cunha, Denise A; Chaves, Priscilla P; Matos, Darley C L; Parolin, Pia

    2013-09-01

    The major rivers of the Amazon River basin and their biota are threatened by the planned construction of large hydroelectric dams that are expected to have strong impacts on floodplain plant communities. The present study presents forest inventories from three floodplain sites colonized by alluvial riparian vegetation in the Tapajós, Xingu and Tocantins River basins in eastern Amazonian. Results indicate that tree species of the highly specialized alluvial riparian vegetation are clearly distinct among the three river basins, although they are not very distinct from each other and environmental constraints are very similar. With only 6 of 74 species occurring in all three inventories, most tree and shrub species are restricted to only one of the rivers, indicating a high degree of local distribution. Different species occupy similar environmental niches, making these fragile riparian formations highly valuable. Conservation plans must consider species complementarily when decisions are made on where to place floodplain forest conservation units to avoid the irreversible loss of unique alluvial riparian vegetation biodiversity.

  10. Impacts of hydroelectric dams on alluvial riparian plant communities in eastern Brazilian Amazonian

    Directory of Open Access Journals (Sweden)

    LEANDRO VALLE FERREIRA

    2013-09-01

    Full Text Available The major rivers of the Amazon River basin and their biota are threatened by the planned construction of large hydroelectric dams that are expected to have strong impacts on floodplain plant communities. The present study presents forest inventories from three floodplain sites colonized by alluvial riparian vegetation in the Tapajós, Xingu and Tocantins River basins in eastern Amazonian. Results indicate that tree species of the highly specialized alluvial riparian vegetation are clearly distinct among the three river basins, although they are not very distinct from each other and environmental constraints are very similar. With only 6 of 74 species occurring in all three inventories, most tree and shrub species are restricted to only one of the rivers, indicating a high degree of local distribution. Different species occupy similar environmental niches, making these fragile riparian formations highly valuable. Conservation plans must consider species complementarily when decisions are made on where to place floodplain forest conservation units to avoid the irreversible loss of unique alluvial riparian vegetation biodiversity.

  11. The evaluation of in-situ leaching hydrological-geologic condition in a sandstone-type uranium deposits of a low-grade and thick ledge

    International Nuclear Information System (INIS)

    Jiang Yan

    2014-01-01

    The ore aquifer of a sandstone-type uranium deposits is thick, the grade, and uranium amount per square meter is low. To demonstrate the economic rationality of the in-situ leaching deposit, the Pumping test on the spot, recovery of water levels test, Pumping test and Injection test, Injection test in a Drilling hole, the pumping and injection balance test are carried out. And the hydro geological parameters of mineral aquifer are acquired. The parameters includes coefficient of transmissibility, Coefficient of permeability, Specific discharge of a well and Water injection. Radius of influence etc. The relation between discharge of drilling and Drawdown is researched. The capability of pumping and injection by a drilling hole is determined. The Hydraulic between the aquifer with mineral and the upper and lower aquifer is researched. The reasonable Mining drawdown is testified, the hydrogeological conditions of in-Situ leaching of the mining deposit is found out, this provides necessary parameters and basis for this kind of Situ-leach uranium mining wells, the designing of Spacing of wells, and the economic evaluation of In-situ leaching technology. (author)

  12. Buried paleoindian-age landscapes in stream valleys of the central plains, USA

    Science.gov (United States)

    Mandel, R.D.

    2008-01-01

    A systematic study of late-Quaternary landscape evolution in the Central Plains documented widespread, deeply buried paleosols that represent Paleoindian-age landscapes in terrace fills of large streams (> 5th order), in alluvial fans, and in draws in areas of western Kansas with a thick loess mantle. Alluvial stratigraphic sections were investigated along a steep bio-climatic gradient extending from the moist-subhumid forest-prairie border of the east-central Plains to the dry-subhumid and semi-arid shortgrass prairie of the west-central Plains. Radiocarbon ages indicate that most large streams were characterized by slow aggradation accompanied by cumulic soil development from ca. 11,500 to 10,000??14C yr B.P. In the valleys of some large streams, such as the Ninnescah and Saline rivers, these processes continued into the early Holocene. The soil-stratigraphic record in the draws of western Kansas indicates slow aggradation punctuated by episodes of landscape stability and pedogenesis beginning as early as ca. 13,300??14C yr B.P. and spanning the Pleistocene-Holocene boundary. The development record of alluvial fans in western Kansas is similar to the record in the draws; slow aggradation was punctuated by multiple episodes of soil development between ca. 13,000 and 9000??14C yr B.P. In eastern Kansas and Nebraska, development of alluvial fans was common during the early and middle Holocene, but evidence shows fan development as early as ca. 11,300??14C yr B.P. Buried soils dating between ca. 12,600 and 9000??14C yr B.P. were documented in fans throughout the region. In stream valleys across the Central Plains, rapid alluviation after ca. 9000??14C yr B.P. resulted in deeply buried soils that may harbor Paleoindian cultural deposits. Hence, the paucity of recorded stratified Paleoindian sites in the Central Plains is probably related to poor visibility (i.e., deep burial in alluvial deposits) instead of limited human occupation in the region during the terminal

  13. Sedimentology and paleoecology of an Eocene Oligocene alluvial lacustrine arid system, Southern Mexico

    Science.gov (United States)

    Beraldi-Campesi, Hugo; Cevallos-Ferriz, Sergio R. S.; Centeno-García, Elena; Arenas-Abad, Concepción; Fernández, Luis Pedro

    2006-10-01

    A depositional model of the Eocene-Oligocene Coatzingo Formation in Tepexi de Rodríguez (Puebla, Mexico) is proposed, based on facies analysis of one of the best-preserved sections, the Axamilpa Section. The sedimentary evolution is interpreted as the retrogradation of an alluvial system, followed by the progressive expansion of an alkaline lake system, with deltaic, palustrine, and evaporitic environments. The analysis suggests a change towards more arid conditions with time. Fossils from this region, such as fossil tracks of artiodactyls, aquatic birds and cat-like mammals, suggest that these animals traversed the area, ostracods populated the lake waters, and plants grew on incipient soils and riparian environments many times throughout the history of the basin. The inferred habitat for some fossil plants coincides with the sedimentological interpretation of an arid to semiarid climate for that epoch. This combined sedimentological-paleontological study of the Axamilpa Section provides an environmental context in which fossils can be placed and brings into attention important biotic episodes, like bird and camelid migrations or the origin of endemic but extinct plants in this area.

  14. Isotope studies on mechanisms of groundwater recharge to an alluvial aquifer in Gatton, Queensland, Australia

    International Nuclear Information System (INIS)

    Dharmasiri, J.K.; Morawska, L.

    1997-01-01

    Gatton is an important agricultural area for Queensland where about 40% of its vegetables needs are produced using groundwater as the main source. An alluvial Aquifer is located about 30m beneath the layers of alluvial sediments ranging from black soils of volcanic origin on top, layers of alluvial sands, clays and beds of sand and gravel. The leakage of creek flows has been considered to be the main source of recharge to this aquifer. A number of weirs have been built across the Lockyer and Laidley creeks to allow surface water to infiltrate through the beds when the creeks flow. Water levels in bores in a section located in the middle of the alluvial plain (Crowley Vale) have been declining for the last 20 years with little or no success in recharging from the creeks. Acute water shortages have been experienced in the Gatton area during the droughts of 1980-81, 1986-87 and 1994-97. Naturally occurring stable isotopes, 2 H, 18 0 and 13 C as well as radioisotopes 3 H and 14 C have been used to delineate sources of recharge and active recharge areas. Tritium tracing of soil moisture in the unsaturated soil was also used to determine direct infiltration rates

  15. The role of surface preparation in corrosion protection of copper with nanometer-thick ALD alumina coatings

    Energy Technology Data Exchange (ETDEWEB)

    Mirhashemihaghighi, Shadi; Światowska, Jolanta [PSL Research University, CNRS – Chimie ParisTech, Institut de Recherche de Chimie Paris (IRCP), 11 rue Pierre et Marie Curie, 75005 Paris (France); Maurice, Vincent, E-mail: vincent.maurice@chimie-paristech.fr [PSL Research University, CNRS – Chimie ParisTech, Institut de Recherche de Chimie Paris (IRCP), 11 rue Pierre et Marie Curie, 75005 Paris (France); Seyeux, Antoine; Klein, Lorena H. [PSL Research University, CNRS – Chimie ParisTech, Institut de Recherche de Chimie Paris (IRCP), 11 rue Pierre et Marie Curie, 75005 Paris (France); Salmi, Emma; Ritala, Mikko [Laboratory of Inorganic Chemistry, Department of Chemistry, University of Helsinki, P.O. Box 55, FIN-00014 Helsinki (Finland); Marcus, Philippe [PSL Research University, CNRS – Chimie ParisTech, Institut de Recherche de Chimie Paris (IRCP), 11 rue Pierre et Marie Curie, 75005 Paris (France)

    2016-11-30

    Highlights: • 10–50 nm thick alumina coatings were grown on copper by atomic layer deposition. • Surface smoothening by substrate annealing was studied as pre-deposition treatment. • Corrosion protection is promoted by pre-treatment for 10 nm but not for thicker films. • Local adhesion failure is assigned to the stresses accumulated in the thicker films. • Surface smoothening decreases the interfacial strength bearing the film stresses. - Abstract: Surface smoothening by substrate annealing was studied as a pre-treatment for improving the corrosion protection provided to copper by 10, 20 and 50 nm thick alumina coatings deposited by atomic layer deposition. The interplay between substrate surface state and deposited film thickness for controlling the corrosion protection provided by ultrathin barrier films is demonstrated. Pre-annealing at 750 °C heals out the dispersed surface heterogeneities left by electropolishing and reduces the surface roughness to less than 2 nm independently of the deposited film thickness. For 10 nm coatings, substrate surface smoothening promotes the corrosion resistance. However, for 20 and 50 nm coatings, it is detrimental to the corrosion protection due to local detachment of the deposited films. The weaker adherence of the thicker coatings is assigned to the stresses accumulated in the films with increasing deposited thickness. Healing out the local heterogeneities on the substrate surface diminishes the interfacial strength that is bearing the stresses of the deposited films, thereby increasing adhesion failure for the thicker films. Pitting corrosion occurs at the local sites of adhesion failure. Intergranular corrosion occurs at the initially well coated substrate grain boundaries because of the growth of a more defective and permeable coating at grain boundaries.

  16. Hydrologic modeling of flood conveyance and impacts of historic overbank sedimentation on West Fork Black's Fork, Uinta Mountains, northeastern Utah, USA

    Science.gov (United States)

    Carson, Eric C.

    2006-05-01

    This study assesses historic overbank alluvial sedimentation along a low-gradient reach of West Fork Black's Fork in the northern Uinta Mountains, Utah. In this previously glaciated setting, an alluvial floodplain that is approximately 400 m wide by 1500 m long has been modified by the combined effects of valley morphometry and the recent history of clear-cut logging during the late 19th and early 20th Centuries. To quantify the effects on sedimentation and flow conveyance, three natural streambank exposures were sampled and analyzed for nuclear bomb fallout 137Cs. The distribution of 137Cs within the three profiles suggests that a remnant outwash terrace exerts a first-order control over the deposition of overbank alluvium. Upstream from a constriction in the floodplain caused by the terrace remnant, as much as 40 cm of overbank alluvium has been deposited since the beginning of clear-cut logging. Immediately downstream of that constriction, no evidence exists for any overbank sedimentation during that same period. Vibracore samples and Oakfield soil probe sampling throughout the study reach quantified the geographic extent and thicknesses of the historic alluvial package. Flood conveyance through the study area was modeled using the U.S. Army Corps of Engineers HEC-RAS modeling program. Model simulations were run for modern conditions (using surveyed topography) and for prehistoric conditions (using the modern topography less the historic alluvial package determined by 137Cs analyses). Model results indicate that the floodplain constriction caused a significant impediment to flood conveyance at even modest discharges during prehistoric conditions. This promoted ponding of floodwaters upstream of the constriction and deposition of alluvium. This has increased bank heights upstream of the constriction, to the point that under modern conditions 1- to 5-year recurrence interval floods are largely confined within the channel. These results confirm the validity of this

  17. Atomic layer deposition of a MoS₂ film.

    Science.gov (United States)

    Tan, Lee Kheng; Liu, Bo; Teng, Jing Hua; Guo, Shifeng; Low, Hong Yee; Tan, Hui Ru; Chong, Christy Yuen Tung; Yang, Ren Bin; Loh, Kian Ping

    2014-09-21

    A mono- to multilayer thick MoS₂ film has been grown by using the atomic layer deposition (ALD) technique at 300 °C on a sapphire wafer. ALD provides precise control of the MoS₂ film thickness due to pulsed introduction of the reactants and self-limiting reactions of MoCl₅ and H₂S. A post-deposition annealing of the ALD-deposited monolayer film improves the crystallinity of the film, which is evident from the presence of triangle-shaped crystals that exhibit strong photoluminescence in the visible range.

  18. One-step aerosol synthesis of nanoparticle agglomerate films: simulation of film porosity and thickness

    International Nuclear Information System (INIS)

    Maedler, Lutz; Lall, Anshuman A; Friedlander, Sheldon K

    2006-01-01

    A method is described for designing nanoparticle agglomerate films with desired film porosity and film thickness. Nanoparticle agglomerates generated in aerosol reactors can be directly deposited on substrates to form uniform porous films in one step, a significant advance over existing technologies. The effect of agglomerate morphology and deposition mechanism on film porosity and thickness are discussed. Film porosity was calculated for a given number and size of primary particles that compose the agglomerates, and fractal dimension. Agglomerate transport was described by the Langevin equation of motion. Deposition enhancing forces such as thermophoresis are incorporated in the model. The method was validated for single spherical particles using previous theoretical studies. An S-shape film porosity dependence on the particle Peclet number typical for spherical particles was also observed for agglomerates, but films formed from agglomerates had much higher porosities than films from spherical particles. Predicted film porosities compared well with measurements reported in the literature. Film porosities increased with the number of primary particles that compose an agglomerate and higher fractal dimension agglomerates resulted in denser films. Film thickness as a function of agglomerate deposition time was calculated from the agglomerate deposition flux in the presence of thermophoresis. The calculated film thickness was in good agreement with measured literature values. Thermophoresis can be used to reduce deposition time without affecting the film porosity

  19. ELLIPSOMETRIC STUDY OF SEMITRANSPARENT SILVER LAYERS DEPOSITED ON GLASS

    Directory of Open Access Journals (Sweden)

    Víctor Toranzos

    2014-12-01

    Full Text Available Using ellipsometry, the film structure is characterized by optical indices n, k (visible region, 450 nm <  < 580 nm and the thickness (15 < d < 35 nm. The optical indices change with the quantity of silver deposited, obtaining effective indices of 1.0 < n < 1.8 and 1.6 < k < 2.6 to the smaller deposits that belong to a volumetric fraction between 0.35 and 0.5 of silver in the air. An effective optical thickness film decrease is observed when the silver volumetric fraction increases, and a thickness increase with close indices to solid silver when the deposited silver increases. Optical and effective medium theory indices are compared.

  20. Electroplated thick-film cobalt platinum permanent magnets

    International Nuclear Information System (INIS)

    Oniku, Ololade D.; Qi, Bin; Arnold, David P.

    2016-01-01

    The material and magnetic properties of multi-micron-thick (up to 6 μm) L1 0 CoPt magnetic films electroplated onto silicon substrates are investigated as candidate materials for integration in silicon-based microsystems. The influence of various process conditions on the structure and magnetic properties of electroplated CoPt thick-films is studied in order to better understand the complex process/structure/property relationships associated with the electroplated films. Process variables studied here include different seed layers, electroplating current densities (ranging from 25–200 mA/cm 2 ), deposition times (up to 60 min), and post-deposition annealing times and temperatures. Analyses include film morphology, film thickness, composition, surface roughness, grain size, phase volume fractions, and L1 0 ordering parameter. Key correlations are found relating process and structure variations to the extrinsic magnetic properties (remanence, coercivity, squareness, and energy product). Strong hard magnetic properties (B r ~0.8 T, H ci ~800 kA/m, squareness close to 0.9, and BH max of 100 kJ/m 3 ) are obtained for films deposited on Si/TiN/Ti/Cu at current densities of 100 mA/cm 2 , pH of 7, and subsequently annealed at 675 °C for 30 min. - Highlights: • CoPt films plated up to 6 μm thick on silicon substrates. • A1 to L1 0 phase transformation by annealing in forming gas. • Various process–structure–property relationships explored. • Key results: B r ~0.8 T, H ci ~800 kA/m, squareness 0.9, and BH max ~100 kJ/m 3 .

  1. Development of A Mississippi River Alluvial Aquifer Groundwater Model

    Science.gov (United States)

    Karakullukcu, R. E.; Tsai, F. T. C.; Bhatta, D.; Paudel, K.; Kao, S. C.

    2017-12-01

    The Mississippi River Alluvial Aquifer (MRAA) underlies the Mississippi River Valley of the northeastern Louisiana, extending from the north border of Louisiana and Arkansas to south central of Louisiana. The MRAA has direct contact with the Mississippi River. However, the interaction between the Mississippi River and the alluvial aquifer is largely unknown. The MRAA is the second most used groundwater source in Louisiana's aquifers with about 390 million gallons per day, which is about 25% of all groundwater withdrawals in Louisiana. MRAA is the major water source to agriculture in the northeastern Louisiana. The groundwater withdrawals from the MRAA increases annually for irrigation. High groundwater pumping has caused significant groundwater level decline and elevated salinity in the aquifer. Therefore, dealing with agricultural irrigation is the primary purpose for managing the MRAA. The main objective of this study is to develop a groundwater model as a tool for the MRAA groundwater management. To do so, a hydrostratigraphy model of the MRAA was constructed by using nearly 8,000 drillers' logs and electric logs collected from Louisiana Department of Natural Resources. The hydrostratigraphy model clearly shows that the Mississippi River cuts into the alluvial aquifer. A grid generation technique was developed to convert the hydrostratigraphy model into a MODFLOW model with 12 layers. A GIS-based method was used to estimate groundwater withdrawals for irrigation wells based on the crop location and acreage from the USDACropScape - Cropland Data Layer. Results from the Variable Infiltration Capacity (VIC) model were used to determine potential recharge. NHDPlusV2 data was used to determine water level for major streams for the MODFLOW River Package. The groundwater model was calibrated using groundwater data between 2004 and 2015 to estimate aquifer hydraulic conductivity, specific yield, specific storage, river conductance, and surficial recharge.

  2. Gluteal fat thickness in pelvic CT

    International Nuclear Information System (INIS)

    Park, Jeong Mi; Jung, Se Young; Lee, Jae Mun; Park, Seog Hee; Kim, Choon Yul; Bahk, Yong Whee

    1986-01-01

    Many calcifications due to fat necrosis in the buttocks detected on the pelvis roentgenograms suggest that the majority of injections intended to be intramuscular actually are delivered into fat. We measured thickness of adult gluteal fat to decide whether the injection using needle of usual length is done into fat or muscle. We measured the vertical thickness of the subcutaneous fat at a point of 2-3cm above the femoral head cut slice with randomly collected 116 cases of adults in the department of Radiology, St. Mary's Hospital, Catholic Medical College. We found that 32% female cases might actually receive on intra adipose injection when a needle of maximum 3.8cm length is inserted into the buttock. If deposition into muscle is desirable, we need to choose needle whose length is appropriate for the site of injection and the patient's deposits of fat.

  3. Equilibrium helium film in the thick film limit

    International Nuclear Information System (INIS)

    Klier, J.; Schletterer, F.; Leiderer, P.; Shikin, V.

    2003-01-01

    For the thickness of a liquid or solid quantum film, like liquid helium or solid hydrogen, there exist still open questions about how the film thickness develops in certain limits. One of these is the thick film limit, i.e., the crossover from the thick film to bulk. We have performed measurements in this range using the surface plasmon resonance technique and an evaporated Ag film deposited on glass as substrate. The thickness of the adsorbed helium film is varied by changing the distance h of the bulk reservoir to the surface of the substrate. In the limiting case, when h > 0, the film thickness approaches about 100 nm following the van der Waals law in the retarded regime. The film thickness and its dependence on h is precisely determined and theoretically modeled. The equilibrium film thickness behaviour is discussed in detail. The agreement between theory and experiment is very good

  4. Morphological Characteristics of Au Films Deposited on Ti: A Combined SEM-AFM Study

    Directory of Open Access Journals (Sweden)

    Francesco Ruffino

    2018-03-01

    Full Text Available Deposited Au films and coatings are, nowadays, routinely used as active or passive elements in several innovative electronic, optoelectronic, sensing, and energy devices. In these devices, the physical properties of the Au films are strongly determined by the films nanoscale structure. In addition, in these devices, often, a layer of Ti is employed to promote adhesion and, so, influencing the nanoscale structure of the deposited Au film. In this work, we present experimental analysis on the nanoscale cross-section and surface morphology of Au films deposited on Ti. In particular, we sputter-deposited thick (>100 nm thickness Au films on Ti foils and we used Scanning Electron Microscopy to analyze the films cross-sectional and surface morphology as a function of the Au film thickness and deposition angle. In addition, we analyzed the Au films surface morphology by Atomic Force Microscopy which allowed quantifying the films surface roughness versus the film thickness and deposition angle. The results establish a relation between the Au films cross-sectional and surface morphologies and surface roughness to the film thickness and deposition angle. These results allow setting a general working framework to obtain Au films on Ti with specific morphological and topographic properties for desired applications in which the Ti adhesion layer is needed for Au.

  5. A methodological toolkit for field assessments of artisanally mined alluvial diamond deposits

    Science.gov (United States)

    Chirico, Peter G.; Malpeli, Katherine C.

    2014-01-01

    This toolkit provides a standardized checklist of critical issues relevant to artisanal mining-related field research. An integrated sociophysical geographic approach to collecting data at artisanal mine sites is outlined. The implementation and results of a multistakeholder approach to data collection, carried out in the assessment of Guinea’s artisanally mined diamond deposits, also are summarized. This toolkit, based on recent and successful field campaigns in West Africa, has been developed as a reference document to assist other government agencies or organizations in collecting the data necessary for artisanal diamond mining or similar natural resource assessments.

  6. Counter diffusion of zinc and iron in alluvial soil

    International Nuclear Information System (INIS)

    Rattan, R.K.; Deb, D.L.

    1980-01-01

    Half cell technique showed that an increase in moisture tension and CaCO 3 content caused reduction in the counter diffusion coefficients of zinc and iron in an alluvial soil. Increases in bulk density, ambient temperature and concentration of synthetic chelating agents e.g. EDTA and DTPA increased the counter diffusion coefficients of both zinc and iron. (author)

  7. Versatile technique for assessing thickness of 2D layered materials by XPS

    Science.gov (United States)

    Zemlyanov, Dmitry Y.; Jespersen, Michael; Zakharov, Dmitry N.; Hu, Jianjun; Paul, Rajib; Kumar, Anurag; Pacley, Shanee; Glavin, Nicholas; Saenz, David; Smith, Kyle C.; Fisher, Timothy S.; Voevodin, Andrey A.

    2018-03-01

    X-ray photoelectron spectroscopy (XPS) has been utilized as a versatile method for thickness characterization of various two-dimensional (2D) films. Accurate thickness can be measured simultaneously while acquiring XPS data for chemical characterization of 2D films having thickness up to approximately 10 nm. For validating the developed technique, thicknesses of few-layer graphene (FLG), MoS2 and amorphous boron nitride (a-BN) layer, produced by microwave plasma chemical vapor deposition (MPCVD), plasma enhanced chemical vapor deposition (PECVD), and pulsed laser deposition (PLD) respectively, were accurately measured. The intensity ratio between photoemission peaks recorded for the films (C 1s, Mo 3d, B 1s) and the substrates (Cu 2p, Al 2p, Si 2p) is the primary input parameter for thickness calculation, in addition to the atomic densities of the substrate and the film, and the corresponding electron attenuation length (EAL). The XPS data was used with a proposed model for thickness calculations, which was verified by cross-sectional transmission electron microscope (TEM) measurement of thickness for all the films. The XPS method determines thickness values averaged over an analysis area which is orders of magnitude larger than the typical area in cross-sectional TEM imaging, hence provides an advanced approach for thickness measurement over large areas of 2D materials. The study confirms that the versatile XPS method allows rapid and reliable assessment of the 2D material thickness and this method can facilitate in tailoring growth conditions for producing very thin 2D materials effectively over a large area. Furthermore, the XPS measurement for a typical 2D material is non-destructive and does not require special sample preparation. Therefore, after XPS analysis, exactly the same sample can undergo further processing or utilization.

  8. Lithostratigraphy and depositional environments in the Waterberg-Erongo area, central Namibia, and correlation with the main Karoo Basin, South Africa

    Science.gov (United States)

    Holzförster, Frank; Stollhofen, Harald; Stanistreet, Ian G.

    1999-07-01

    The dissected landscape of the Waterberg-Erongo area, central Namibia, exposes Karoo-equivalent strata deposited in basins that occur throughout sub-Saharan Africa. Although many are of economic interest, including coal-bearing strata, their depositional history is not well understood. This study of the Waterberg-Erongo area provides detailed lithostratigraphical data, which suggest sedimentation from the late Early Triassic to the Early Jurassic in a fault-bounded depository. Subsidence and sediment supply were controlled predominantly by the northeast-southwest trending Waterberg-Omaruru Fault Zone, which defines the northwestern margin of the depository. Facies development and thickness distribution of the Karoo strata in the Waterberg-Erongo area, perhaps the most continuous of any of the Karoo basins, indicate a northeastwardly-migrating depocentre alongside that fault, in response to major extensional movements in the early pre-South Atlantic rift zone. Periodic fault movements repeatedly caused basinward progradation of the alluvial facies, which are reflected by stacked fining-upward cycles in the lithological record. On a broader scale, the results of this study suggest that the northward propagation of the rift zone between Southern Africa and South America, was partially accommodated by transfer lineaments. Local depocentres developed along these lineaments, such as those in the Waterberg-Erongo area, with localised enhanced subsidence greater than that revealed in other Namibian onshore exposures, dominated by the rifting itself.

  9. Depositional environment and sedimentary of the basinal sediments in the Eibiswalder Bucht (Radl Formation and Lower Eibiswald Beds), Miocene Western Styrian Basin, Austria

    Science.gov (United States)

    Stingl, K.

    1994-12-01

    The Eibiswald Bucht is a small subbasin of the Western Styrian Basin exposing sediments of Lower Miocene age. In the past the entire sequence exposed in the Eibiswalder Bucht has been interpreted as being of fluvial/lacustrine origin; here, results are presented of detailed sedimentological investigations that lead to a revision of this concept. The lowermost siliciclastic sedimentary unit of the Eibiswalder Bucht sequence is the Radl Formation. It is overlain by the Eibiswald Beds, which are subdivided into the Lower, Middle and Upper Eibiswald Beds. The Radl Formation and the Lower Eibiswald Beds are interpreted as a fan delta complex deposited along NNW-SSE striking faults. Based on the sedimentary facies this fan delta can be subdivided into a subaerial alluvial fan facies group, a proximal delta facies group and a distal delta/prodelta facies group. The Radl Formation comprises the alluvial fan and proximal delta facies groups, the Lower Eibiswald Beds the distal delta/prodelta facies group. The alluvial fan and the proximal delta consist of diverse deposits of gravelly flows. The distal delta/prodelta consists of wave-reworked, bioturbated, low density turbidites intercalated with minor gravelly mass flows. The prodelta can be regarded as as the basin facies of the small and shallow Eibiswalder Bucht, where marine conditions prevailed. The basin was probably in part connected with the Eastern Styrian Basin, the contemporary depositional environment of the Styrian Schlier (mainly turbiditic marine offshore sediments in the Eastern Styrian Basin). Analysis of the clast composition, in conjunction with the paleotransport direction of the coarse delta mass flows of the Radl Formation, shows that the source rocks were exclusively crystalline rocks ranging from greenschists to eclogites.

  10. Matrix shaped pulsed laser deposition: New approach to large area and homogeneous deposition

    Energy Technology Data Exchange (ETDEWEB)

    Akkan, C.K.; May, A. [INM – Leibniz Institute for New Materials, CVD/Biosurfaces Group, Campus D2 2, 66123 Saarbrücken (Germany); Hammadeh, M. [Department for Obstetrics, Gynecology and Reproductive Medicine, IVF Laboratory, Saarland University Medical Center and Faculty of Medicine, Building 9, 66421 Homburg, Saar (Germany); Abdul-Khaliq, H. [Clinic for Pediatric Cardiology, Saarland University Medical Center and Faculty of Medicine, Building 9, 66421 Homburg, Saar (Germany); Aktas, O.C., E-mail: cenk.aktas@inm-gmbh.de [INM – Leibniz Institute for New Materials, CVD/Biosurfaces Group, Campus D2 2, 66123 Saarbrücken (Germany)

    2014-05-01

    Pulsed laser deposition (PLD) is one of the well-established physical vapor deposition methods used for synthesis of ultra-thin layers. Especially PLD is suitable for the preparation of thin films of complex alloys and ceramics where the conservation of the stoichiometry is critical. Beside several advantages of PLD, inhomogeneity in thickness limits use of PLD in some applications. There are several approaches such as rotation of the substrate or scanning of the laser beam over the target to achieve homogenous layers. On the other hand movement and transition create further complexity in process parameters. Here we present a new approach which we call Matrix Shaped PLD to control the thickness and homogeneity of deposited layers precisely. This new approach is based on shaping of the incoming laser beam by a microlens array and a Fourier lens. The beam is split into much smaller multi-beam array over the target and this leads to a homogenous plasma formation. The uniform intensity distribution over the target yields a very uniform deposit on the substrate. This approach is used to deposit carbide and oxide thin films for biomedical applications. As a case study coating of a stent which has a complex geometry is presented briefly.

  11. Spacer Thickness-Dependent Electron Transport Performance of Titanium Dioxide Thick Film for Dye-Sensitized Solar Cells

    Directory of Open Access Journals (Sweden)

    Reda E. El-Shater

    2015-01-01

    Full Text Available A titanium dioxide (P25 film was deposited by cast coating as conductive photoelectrode and subsequently immersed in dye solution (N719 to fabricate the photoanode of dye-sensitized solar cells (DSSCs. A plastic spacer was used as a separation and sealant layer between the photoanode and the counter electrode. The effect of the thickness of this spacer on the transfer of electrons in the liquid electrolyte of the DSSCs was studied by means of both IV curves and electrochemical impedance. Using a spacer thickness range of 20 μm to 50 μm, efficiency ranges from 3.73% to 7.22%. The highest efficiency of 7.22% was obtained with an optimal spacer thickness of 40 μm.

  12. Cadmium accumulation and growth responses of a poplar (Populus deltoids x Populus nigra) in cadmium contaminated purple soil and alluvial soil

    Energy Technology Data Exchange (ETDEWEB)

    Wu Fuzhong [Faculty of Forestry, Sichuan Agricultural University, 625014, Ya' an (China); Yang Wanqin, E-mail: scyangwq@163.com [Faculty of Forestry, Sichuan Agricultural University, 625014, Ya' an (China); Zhang Jian; Zhou Liqiang [Faculty of Forestry, Sichuan Agricultural University, 625014, Ya' an (China)

    2010-05-15

    To characterize the phytoextraction efficiency of a hybrid poplar (Populus deltoids x Populus nigra) in cadmium contaminated purple soil and alluvial soil, a pot experiment in field was carried out in Sichuan basin, western China. After one growing period, the poplar accumulated the highest of 541.98 {+-} 19.22 and 576.75 {+-} 40.55 {mu}g cadmium per plant with 110.77 {+-} 12.68 and 202.54 {+-} 19.12 g dry mass in these contaminated purple soil and alluvial soil, respectively. Higher phytoextraction efficiency with higher cadmium concentration in tissues was observed in poplar growing in purple soil than that in alluvial soil at relative lower soil cadmium concentration. The poplar growing in alluvial soil had relative higher tolerance ability with lower reduction rates of morphological and growth characters than that in purple soil, suggesting that the poplar growing in alluvial soil might display the higher phytoextraction ability when cadmium contamination level increased. Even so, the poplars exhibited obvious cadmium transport from root to shoot in both soils regardless of cadmium contamination levels. It implies that this examined poplar can extract more cadmium than some hyperaccumulators. The results indicated that metal phytoextraction using the poplar can be applied to clean up soils moderately contaminated by cadmium in these purple soil and alluvial soil.

  13. Effect of thermal processing on silver thin films of varying thickness deposited on zinc oxide and indium tin oxide

    International Nuclear Information System (INIS)

    Sivaramakrishnan, K.; Ngo, A. T.; Alford, T. L.; Iyer, S.

    2009-01-01

    Silver films of varying thicknesses (25, 45, and 60 nm) were deposited on indium tin oxide (ITO) on silicon and zinc oxide (ZnO) on silicon. The films were annealed in vacuum for 1 h at different temperatures (300-650 deg. C). Four-point-probe measurements were used to determine the resistivity of the films. All films showed an abrupt change in resistivity beyond an onset temperature that varied with thickness. Rutherford backscattering spectrometry measurements revealed agglomeration of the Ag films upon annealing as being responsible for the resistivity change. X-ray pole figure analysis determined that the annealed films took on a preferential texturing; however, the degree of texturing was significantly higher in Ag/ZnO/Si than in Ag/ITO/Si samples. This observation was accounted for by interface energy minimization. Atomic force microscopy (AFM) measurements revealed an increasing surface roughness of the annealed films with temperature. The resistivity behavior was explained by the counterbalancing effects of increasing crystallinity and surface roughness. Average surface roughness obtained from the AFM measurements were also used to model the agglomeration of Ag based on Ostwald ripening theory

  14. Deposition Measurements in NSTX

    Science.gov (United States)

    Skinner, C. H.; Kugel, H. W.; Hogan, J. T.; Wampler, W. R.

    2004-11-01

    Two quartz microbalances have been used to record deposition on the National Spherical Torus Experiment. The experimental configuration mimics a typical diagnostic window or mirror. An RS232 link was used to acquire the quartz crystal frequency and the deposited thickness was recorded continuously with 0.01 nm resolution. Nuclear Reaction Analysis of the deposit was consistent with the measurement of the total deposited mass from the change in crystal frequency. We will present measurements of the variation of deposition with plasma conditions. The transport of carbon impurities in NSTX has been modelled with the BBQ code. Preliminary calculations indicated a negligible fraction of carbon generated at the divertor plates in quiescent discharges directly reaches the outer wall, and that transient events are responsible for the deposition.

  15. A study of local site effects in Benevento(Southern Italy by the analysis of seismic records of explosions

    Directory of Open Access Journals (Sweden)

    L. Mirabile

    1995-06-01

    Full Text Available In this paper we evalllate the seismic amplification effects in the town of Benevento llsing records of an explo- sion of 500 kg fired at abollt 7 km. Seismic records were obtained at 43 selected sites in the city by digital three-component stations. A data selection performed on the signal-to-noise ratio reduced the available data to 26 stations. We used the spectral ratio techniques to evaluate the amplification effects of each recording site compared both to the average spectrum calculated over 26 stations and to a reference seismic station. The shapes of the spectral ratios were classified according to the geological characteristics of the site. A characteristic shape of the spectral ratio was observed to be related to the specific structure of the subsoil. In particular, the sites on basin sediments (Lagonegro Unit and Middle Pleistocene conglomerates failed to show amplification effects; the sites on thick alluvial deposits showed amplification in the 5-9 Hz range; finally, sites on alluvial-lacustrine deposits amplified the seismic signal at frequencies depending on the characteristics and the thickness of the deposit. In addition, damage distribution caused by the 1688 earthquake in Benevento was related to the thickness of the surface layers in the ancient built-up area of the town. The study of the spectral ra- tios showed that these deposits amplify ground motion at frequencies between 9 and 12 Hz, i.e. frequencies close to the natural period of the most widespread buildings at that time in Benevento. Geological and seismic data were jointly used to carry out a zonation of the urban area of Benevento on the basis of homogeneous seismic responses. The validity of this analysis is limited to the main frequency band and amplitude of ground motion produced by the explosions.

  16. Plasma deposition by discharge in powder

    International Nuclear Information System (INIS)

    El-Gamal, H.A.; El-Tayeb, H.A.; Abd El-Moniem, M.; Masoud, M.M.

    2000-01-01

    Different types of material powders have been fed to the breach of a coaxial discharge. The coaxial discharge is powered from a 46.26 mu F, 24 KV capacitor bank. When the discharge takes place at the breach, the powder is heated and ionized to form a sheath of its material. The plasma sheath is ejected from the discharge zone with high velocity. The plasma sheath material is deposited on a glass substrate. It has been found from scanning electron microscope (SEM) analysis that the deposited material is almost homogenous for ceramic and graphite powders. The grain size is estimated to be the order of few microns. To measure the deposited material thickness the microdensitometer and a suitable arrangement of a laser interferometer and an optical microscope are used. It has also been found that deposited material thickness depends on the discharge number of shots and the capacitor bank energy

  17. Complex utilization of the useful components of the andreye-yulyevskoe kyanite tecnogenic deposit (Southern Urals

    Directory of Open Access Journals (Sweden)

    Viktor Alekseyevich Koroteyev

    2013-03-01

    Full Text Available Utilization of sillimanite group’s minerals (kyanite, sillimanite, andalusite in high-aluminiferousrefractory industry with a purpose of following utilization in metallurgy to obtain silumine and aluminium by elctrothermic method is impossible without new resources. A one of them is the Andree-Yulyevskaya group of kyanite-bearing technogenic objects. Technogenic deposits formed as a result of alluvial gold deposits’ exploitation at the Southern Urals is an additional source of the complex mineral products. A concentration of minerals of the technogenic objects is higher than initial alluvial placers’ one in n10-n1000 times. During the valuation of industrial potential of the Andree-Yulyevskayakya tetechnogenic deposit, (Southern Urals a concentrate method of technogenicsands’ sampling has been used which permitsestimating a gold placers’ potential of thetechnogenic objects with poor gold and rutile as a useful additional mineral has been distinguished. As a result of researches a principal technological scheme of technogenic sands’ concentration permitting to obtain kyanite concentrates with content of Al2O3 of 55.5 (% to 60.2 (% — the main product and gold-bearing and rutile concentrates as additional products. Complex extraction of kyanite, gold, and rutile from technogenic objects has a commercial attraction of this type deposits’ exploitation.

  18. DEPOSITS AND MINING POTENTIAL OF BENTONITE IN CROATIA

    Directory of Open Access Journals (Sweden)

    Mario Klanfar

    2012-07-01

    Full Text Available Bentonite is one of the materials that is planed to be used for buffering and backfilling in spent nuclear fuel repositories, within deep crystalline rock. There are several locations in Croatia that bentonite deposits and occurrences are found on. Some were exploited in past, and others were more or less explored. This paper presents overview of bentonite deposits, basic properties and potential resources, and mining practices in Croatia. Largest exploited deposits are found in area of Poljanska luka, Gornja Jelenska and Bednja. Surface and underground methods (drift and fill, sublevel caving were used during exploitation. In the area of Svilaja and Lika are found potentially valuable deposits that were never exploited. Montmorilonite content ranges form 20-50% to 57-89%. Most deposits contain bentonite beds with thickness 0,4-1,6 m, and have plunge 10°-30°. Few exceptions are nearly horizontal and thick more than 5 m and even 12 m. One is declined at 70° and up to 40m thick. Proven reserves are about 2,3 Mt with some level of uncertainty. Average production per mine during exploitation period can be assumed to be several thousands t/y.

  19. Soils on raised marine terraces in the Metaponto area, S Italy: not a simple chronosequence

    Science.gov (United States)

    Sauer, Daniela; Al-Sharif, Riyad; Wagner, Stephen; Scarciglia, Fabio; Deffontaines, Benoît; Benvenuti, Marco; Carnicelli, Stefano; Brückner, Helmut

    2015-04-01

    A sequence of Middle and Late Pleistocene raised marine terraces stretches along the Gulf of Taranto, S Italy, for more than 65 km from Rocca Imperiale, Calabria, in the SW to Taranto, Apulia, in the NE, in an approximately 25 km wide belt. The terraces formed as a result of the interplay between sea-level fluctuations and regional tectonic uplift over a time-span of ca. 780 ka. They were selected for establishing a soil chronosequence, in order to analyse rates of soil-forming processes in the central Mediterranean region. Indeed, several general trends of soil formation with terrace age were identified. For example, soil thickness and Fed/Fet ratios increase, while the weathering ratio (Ca+Mg+K+Na)/Al decreases with assumed terrace age. These changes could be best described by power functions (R2 = 0.88 for soil thickness, R2 = 0.87 for Fed/Fet, and R2 = 0.96 for (Ca+Mg+K+Na)/Al). However, closer examination revealed that the soils did not simply form in the marine gravel bodies but in various kinds of sediments. The development of the landscape along the Gulf of Taranto turned out to be much more complex than previously expected. Sediment-soil successions exposed in several gravel quarries reveal that each terrace, after its original formation, was exposed to changing conditions in terms of climate, vegetation, level of erosion base (related to sea-level oscillations and/or tectonics), and other environmental factors during the Pleistocene and Holocene periods. As a result, it was subject to (i) further geomorphological and sedimentological evolution, including incision, denudation, deposition of alluvial sediments, and accumulation of colluvial deposits, in parts due to natural processes and in parts due to human activity; (ii) various directions and rates of soil development, corresponding to changing environmental conditions during glacial and interglacial periods. In some cases, there is evidence for a period of soil formation in the marine deposits prior to

  20. Characterising alluvial aquifers in a remote ephemeral catchment (Flinders River, Queensland) using a direct push tracer approach

    Science.gov (United States)

    Taylor, Andrew R.; Smith, Stanley D.; Lamontagne, Sébastien; Suckow, Axel

    2018-01-01

    The availability of reliable water supplies is a key factor limiting development in northern Australia. However, characterising groundwater resources in this remote part of Australia is challenging due to a lack of existing infrastructure and data. Here, direct push technology (DPT) was used to characterise shallow alluvial aquifers at two locations in the semiarid Flinders River catchment. DPT was used to evaluate the saturated thickness of the aquifer and estimate recharge rates by sampling for environmental tracers in groundwater (major ions, 2H, 18O, 3H and 14C). The alluvium at Fifteen Mile Reserve and Glendalough Station consisted of a mixture of permeable coarse sandy and gravely sediments and less permeable clays and silts. The alluvium was relatively thin (i.e. < 20 m) and, at the time of the investigation, was only partially saturated. Tritium (3H) concentrations in groundwater was ∼1 Tritium Unit (TU), corresponding to a mean residence time for groundwater of about 12 years. The lack of an evaporation signal for the 2H and 18O of groundwater suggests rapid localised recharge from overbank flood events as the primary recharge mechanism. Using the chloride mass balance technique (CMB) and lumped parameter models to interpret patterns in 3H in the aquifer, the mean annual recharge rate varied between 21 and 240 mm/yr. Whilst this recharge rate is relatively high for a semiarid climate, the alluvium is thin and heterogeneous hosting numerous alluvial aquifers with varied connectivity and limited storage capacity. Combining DPT and environmental tracers is a cost-effective strategy to characterise shallow groundwater resources in unconsolidated sedimentary aquifers in remote data sparse areas.

  1. Fabrication and characterization of vacuum deposited fluorescein thin films

    Energy Technology Data Exchange (ETDEWEB)

    Jalkanen, Pasi, E-mail: pasi.jalkanen@gmail.co [University of Jyvaeskylae, Department of Physics, Nanoscience center (NSC), P.O. Box 35, FI-40014 Jyvaeskylae (Finland); Kulju, Sampo, E-mail: sampo.j.kulju@jyu.f [University of Jyvaeskylae, Department of Physics, Nanoscience center (NSC), P.O. Box 35, FI-40014 Jyvaeskylae (Finland); Arutyunov, Konstantin, E-mail: konstantin.arutyunov@jyu.f [University of Jyvaeskylae, Department of Physics, Nanoscience center (NSC), P.O. Box 35, FI-40014 Jyvaeskylae (Finland); Antila, Liisa, E-mail: liisa.j.antila@jyu.f [University of Jyvaeskylae, Department of Chemistry, Nanoscience center (NSC) P.O. Box 35, FI-40014 Jyvaeskylae (Finland); Myllyperkioe, Pasi, E-mail: pasi.myllyperkio@jyu.f [University of Jyvaeskylae, Department of Chemistry, Nanoscience center (NSC) P.O. Box 35, FI-40014 Jyvaeskylae (Finland); Ihalainen, Teemu, E-mail: teemu.o.ihalainen@jyu.f [University of Jyvaeskylae, Department of Biology, Nanoscience center (NSC), P.O. Box 35, FI-40014 Jyvaeskylae (Finland); Kaeaeriaeinen, Tommi, E-mail: tommi.kaariainen@lut.f [Lappeenranta University of Technology, ASTRal, P.O. Box 181, FI-50101 Mikkeli (Finland); Kaeaeriaeinen, Marja-Leena, E-mail: marja-leena.kaariainen@lut.f [Lappeenranta University of Technology, ASTRal, P.O. Box 181, FI-50101 Mikkeli (Finland); Korppi-Tommola, Jouko, E-mail: jouko.korppi-tommola@jyu.f [University of Jyvaeskylae, Department of Biology, Nanoscience center (NSC), P.O. Box 35, FI-40014 Jyvaeskylae (Finland)

    2011-03-31

    Simple vacuum evaporation technique for deposition of dyes on various solid surfaces has been developed. The method is compatible with conventional solvent-free nanofabrication processing enabling fabrication of nanoscale optoelectronic devices. Thin films of fluorescein were deposited on glass, fluorine-tin-oxide (FTO) coated glass with and without atomically layer deposited (ALD) nanocrystalline 20 nm thick anatase TiO{sub 2} coating. Surface topology, absorption and emission spectra of the films depend on their thickness and the material of supporting substrate. On a smooth glass surface the dye initially forms islands before merging into a uniform layer after 5 to 10 monolayers. On FTO covered glass the absorption spectra are similar to fluorescein solution in ethanol. Absorption spectra on ALD-TiO{sub 2} is red shifted compared to the film deposited on bare FTO. The corresponding emission spectra at {lambda} = 458 nm excitation show various thickness and substrate dependent features, while the emission of films deposited on TiO{sub 2} is quenched due to the effective electron transfer to the semiconductor conduction band.

  2. Design and spectroscopic reflectometry characterization of pulsed laser deposition combinatorial libraries

    International Nuclear Information System (INIS)

    Schenck, Peter K.; Bassim, Nabil D.; Otani, Makoto; Oguchi, Hiroyuki; Green, Martin L.

    2007-01-01

    The goal of the design of pulsed laser deposition (PLD) combinatorial library films is to optimize the compositional coverage of the films while maintaining a uniform thickness. The deposition pattern of excimer laser PLD films can be modeled with a bimodal cos n distribution. Deposited films were characterized using a spectroscopic reflectometer (250-1000 nm) to map the thickness of both single composition calibration films and combinatorial library films. These distribution functions were used to simulate the composition and thickness of multiple target combinatorial library films. The simulations were correlated with electron-probe microanalysis wavelength-dispersive spectroscopy (EPMA-WDS) composition maps. The composition and thickness of the library films can be fine-tuned by adjusting the laser spot size, fluence, background gas pressure, target geometry and other processing parameters which affect the deposition pattern. Results from compositionally graded combinatorial library films of the ternary system Al 2 O 3 -HfO 2 -Y 2 O 3 are discussed

  3. Electroplated thick-film cobalt platinum permanent magnets

    Energy Technology Data Exchange (ETDEWEB)

    Oniku, Ololade D.; Qi, Bin; Arnold, David P., E-mail: darnold@ufl.edu

    2016-10-15

    The material and magnetic properties of multi-micron-thick (up to 6 μm) L1{sub 0} CoPt magnetic films electroplated onto silicon substrates are investigated as candidate materials for integration in silicon-based microsystems. The influence of various process conditions on the structure and magnetic properties of electroplated CoPt thick-films is studied in order to better understand the complex process/structure/property relationships associated with the electroplated films. Process variables studied here include different seed layers, electroplating current densities (ranging from 25–200 mA/cm{sup 2}), deposition times (up to 60 min), and post-deposition annealing times and temperatures. Analyses include film morphology, film thickness, composition, surface roughness, grain size, phase volume fractions, and L1{sub 0} ordering parameter. Key correlations are found relating process and structure variations to the extrinsic magnetic properties (remanence, coercivity, squareness, and energy product). Strong hard magnetic properties (B{sub r} ~0.8 T, H{sub ci} ~800 kA/m, squareness close to 0.9, and BH{sub max} of 100 kJ/m{sup 3}) are obtained for films deposited on Si/TiN/Ti/Cu at current densities of 100 mA/cm{sup 2}, pH of 7, and subsequently annealed at 675 °C for 30 min. - Highlights: • CoPt films plated up to 6 μm thick on silicon substrates. • A1 to L1{sub 0} phase transformation by annealing in forming gas. • Various process–structure–property relationships explored. • Key results: B{sub r} ~0.8 T, H{sub ci} ~800 kA/m, squareness 0.9, and BH{sub max} ~100 kJ/m{sup 3}.

  4. Electrochemical Sensor Coating Based on Electrophoretic Deposition of Au-Doped Self-Assembled Nanoparticles.

    Science.gov (United States)

    Zhang, Rongli; Zhu, Ye; Huang, Jing; Xu, Sheng; Luo, Jing; Liu, Xiaoya

    2018-02-14

    The electrophoretic deposition (EPD) of self-assembled nanoparticles (NPs) on the surface of an electrode is a new strategy for preparing sensor coating. By simply changing the deposition conditions, the electrochemical response for an analyte of deposited NPs-based coating can be controlled. This advantage can decrease the difference between different batches of sensor coating and ensure the reproducibility of each sensor. This work investigated the effects of deposition conditions (including deposition voltage, pH value of suspension, and deposition time) on the structure and the electrochemical response for l-tryptophan of sensor coating formed from Au-doped poly(sodium γ-glutamate) with pendant dopamine units nanohybrids (Au/γ-PGA-DA NBs) via the EPD method. The structure and thickness of the deposited sensor coating were measured by atomic force microscopy, which demonstrated that the structure and thickness of coating can be affected by the deposition voltage, the pH value of the suspension, and the deposition time. The responsive current for l-tryptophan of the deposited sensor coating were measured by differential pulse voltammetry, which showed that the responsive current value was affected by the structure and thickness of the deposited coating. These arguments suggested that a rich design-space for tuning the electrochemical response for analyte and a source of variability in the structure of sensor coating can be provided by the deposition conditions. When Au/γ-PGA-DA NBs were deposited on the electrode surface and formed a continuous coating with particle morphology and thinner thickness, the deposited sensor coating exhibited optimal electrochemical response for l-tryptophan.

  5. Uranium-series comminution ages of continental sediments: Case study of a Pleistocene alluvial fan

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Victoria E.; DePaolo, Donald J.; Christensen, John N.

    2010-04-30

    Obtaining quantitative information about the timescales associated with sediment transport, storage, and deposition in continental settings is important but challenging. The uranium-series comminution age method potentially provides a universal approach for direct dating of Quaternary detrital sediments, and can also provide estimates of the sediment transport and storage timescales. (The word"comminution" means"to reduce to powder," reflecting the start of the comminution age clock as reduction of lithic parent material below a critical grain size threshold of ~;;50 mu m.) To test the comminution age method as a means to date continental sediments, we applied the method to drill-core samples of the glacially-derived Kings River Fan alluvial deposits in central California. Sediments from the 45 m core have independently-estimated depositional ages of up to ~;;800 ka, based on paleomagnetism and correlations to nearby dated sediments. We characterized sequentially-leached core samples (both bulk sediment and grain size separates) for U, Nd, and Sr isotopes, grain size, surface texture, and mineralogy. In accordance with the comminution age model, where 234U is partially lost from small sediment grains due to alpha recoil, we found that (234U/238U) activity ratios generally decrease with age, depth, and specific surface area, with depletions of up to 9percent relative to radioactive equilibrium. The resulting calculated comminution ages are reasonable, although they do not exactly match age estimates from previous studies and also depend on assumptions about 234U loss rates. The results indicate that the method may be a significant addition to the sparse set of available tools for dating detrital continental sediments, following further refinement. Improving the accuracy of the method requires more advanced models or measurements for both the recoil loss factor fa and weathering effects. We discuss several independent methods for obtaining fa on individual samples

  6. Magnetic properties and microstructure investigation of electrodeposited FeNi/ITO films with different thickness

    International Nuclear Information System (INIS)

    Cao, Derang; Wang, Zhenkun; Feng, Erxi; Wei, Jinwu; Wang, Jianbo; Liu, Qingfang

    2013-01-01

    Highlights: •FeNi alloy thin films with different thickness deposited on Indium Tin Oxides (ITOs) conductive glass substrates by electrodeposition method. •A columnar crystalline microstructure and domain structure were obtained in FeNi thin films. •Particular FMR spectra of FeNi alloy with different thickness were studied. -- Abstract: FeNi alloy thin films with different thickness deposited on Indium Tin Oxides (ITOs) conductive glass substrates from the electrolytes by electrodeposition method have been studied by magnetic force microscopy (MFM), scanning electron microscopy (SEM) and ferromagnetic resonance (FMR) technique. For these films possessing an in-plane isotropy, the remanence decreases with the increasing of film thickness and the critical thickness that a stripe domain structure emerges is about 116 nm. Characteristic differences of the FMR spectra of different thickness are also observed. The results show that the resonance field at high measured angle increases firstly then decreases with increasing thickness, which may be related to the striped domain structure

  7. CHANNEL EVOLUTION IN MODIFIED ALLUVIAL STREAMS.

    Science.gov (United States)

    Simon, Andrew; Hupp, Cliff R.

    1987-01-01

    This study (a) assesses the channel changes and network trends of bed level response after modifications between 1959 and 1972 of alluvial channels in western Tennessee and (b) develops a conceptual model of bank slope development to qualitatively assess bank stability and potential channel widening. A six-step, semiquantitative model of channel evolution in disturbed channels was developed by quantifying bed level trends and recognizing qualitative stages of bank slope development. Development of the bank profile is defined in terms of three dynamic and observable surfaces: (a) vertical face (70 to 90 degrees), (b) upper bank (25 to 50 degrees), and (c) slough line (20 to 25 degrees).

  8. End-Pleistocene to Holocene paleoenvironmental record from piston corer samples and the challenge of stratigraphic correlation of playa sediment data with a connected alluvial apron from Damghan Basin, Iran

    Science.gov (United States)

    Büdel, Christian; Hoelzmann, Philipp; Wennrich, Volker; Majid Padashi, Sajed; Baumhauer, Roland

    2015-04-01

    The study yields a first characterization and correlation of the end-Pleistocene to Holocene sediment archive of playa and playa lake deposits in the Damghan Basin, northern Iran. The Basin sediments are deposited since Mio- and Pliocene, which is valid for the connected alluvial fans, too. These are covering the area between the playa and mountains and while prograding from the mountain ranges they deliver gravels and fine-sediments to the basins sink. The processes on the studied alluvial apron are described and dated already and can be explained in seven morphodynamic phases, which are linked to a general lake level high-stand in north-east Iran at about 8000-9000 years ago. If and how these phases are passed on from the alluvial record down to the playa sediment record is aim of this study. Today the salt pans margins are highly affected by salt tectonic drifting and access was suboptimal. Only here drilling could be performed through about 280 centimeters of salt-crust unfrequently intercalated with loamy layers. For yielding undisturbed playa sediment records sampling was performed with inliner-tubes deployed in a piston corer (Kullenberg type). Thus at two different drilling sites in summation seven cores could be taken, down to a maximum depth of 129 cm and 1000 cm. Back in Germany the cores had been opened and initially described, photographed and optically scanned with a core logger. Regarding future studies, the aim was a best possible comprehensive documentation of the cores. Therefore basically grainsize measurements (laser diffraction), multi element analyses (XRF, ICP-OES, titrimetry) and mineralogical measurements (XRD) had been deployed on samples taken from every single previously identified layer. Continuous elemental data was secured by use of a XRF-scanning core logger. The sedimentological description together with laboratory element analyses shows saline conditions in the first three meters coincide with general coarser grain sizes. The next

  9. Cadmium accumulation and growth responses of a poplar (Populus deltoids x Populus nigra) in cadmium contaminated purple soil and alluvial soil

    International Nuclear Information System (INIS)

    Wu Fuzhong; Yang Wanqin; Zhang Jian; Zhou Liqiang

    2010-01-01

    To characterize the phytoextraction efficiency of a hybrid poplar (Populus deltoids x Populus nigra) in cadmium contaminated purple soil and alluvial soil, a pot experiment in field was carried out in Sichuan basin, western China. After one growing period, the poplar accumulated the highest of 541.98 ± 19.22 and 576.75 ± 40.55 μg cadmium per plant with 110.77 ± 12.68 and 202.54 ± 19.12 g dry mass in these contaminated purple soil and alluvial soil, respectively. Higher phytoextraction efficiency with higher cadmium concentration in tissues was observed in poplar growing in purple soil than that in alluvial soil at relative lower soil cadmium concentration. The poplar growing in alluvial soil had relative higher tolerance ability with lower reduction rates of morphological and growth characters than that in purple soil, suggesting that the poplar growing in alluvial soil might display the higher phytoextraction ability when cadmium contamination level increased. Even so, the poplars exhibited obvious cadmium transport from root to shoot in both soils regardless of cadmium contamination levels. It implies that this examined poplar can extract more cadmium than some hyperaccumulators. The results indicated that metal phytoextraction using the poplar can be applied to clean up soils moderately contaminated by cadmium in these purple soil and alluvial soil.

  10. Nearshore sediment thickness, Fire Island, New York

    Science.gov (United States)

    Locker, Stanley D.; Miselis, Jennifer L.; Buster, Noreen A.; Hapke, Cheryl J.; Wadman, Heidi M.; McNinch, Jesse E.; Forde, Arnell S.; Stalk, Chelsea A.

    2017-04-03

    Investigations of coastal change at Fire Island, New York (N.Y.), sought to characterize sediment budgets and determine geologic framework controls on coastal processes. Nearshore sediment thickness is critical for assessing coastal system sediment availability, but it is largely unquantified due to the difficulty of conducting geological or geophysical surveys across the nearshore. This study used an amphibious vessel to acquire chirp subbottom profiles. These profiles were used to characterize nearshore geology and provide an assessment of nearshore sediment volume. Two resulting sediment-thickness maps are provided: total Holocene sediment thickness and the thickness of the active shoreface. The Holocene sediment section represents deposition above the maximum flooding surface that is related to the most recent marine transgression. The active shoreface section is the uppermost Holocene sediment, which is interpreted to represent the portion of the shoreface thought to contribute to present and future coastal behavior. The sediment distribution patterns correspond to previously defined zones of erosion, accretion, and stability along the island, demonstrating the importance of sediment availability in the coastal response to storms and seasonal variability. The eastern zone has a thin nearshore sediment thickness, except for an ebb-tidal deposit at the wilderness breach caused by Hurricane Sandy. Thicker sediment is found along a central zone that includes shoreface-attached sand ridges, which is consistent with a stable or accretional coastline in this area. The thickest overall Holocene section is found in the western zone of the study, where a thicker lower section of Holocene sediment appears related to the westward migration of Fire Island Inlet over several hundred years.

  11. The influence of fiber thickness, wall thickness and gap distance on the spiral nanofibrous scaffolds for bone tissue engineering

    International Nuclear Information System (INIS)

    Wang Junping; Shah, Ami; Yu Xiaojun

    2011-01-01

    We have developed a 3D nanofibrous spiral scaffold for bone tissue engineering which has shown enhanced cell attachment, proliferation and differentiation compared to traditional cylindrical scaffolds due to the spiral structures and the nanofiber incorporation. Some important parameters of these spiral scaffolds including gap distance, wall thickness and especially fiber thickness are crucial to the performance of the spiral structured scaffolds. In this study, we investigated the fiber thickness, gap distance and wall thickness of the spiral structure on the behavior of osteoblast cells. The human osteoblast cells are seeded on spiral structured scaffolds with various fiber thickness, gap distance and wall thickness and cell attachment, proliferation, differentiation and mineralized matrix deposition on the scaffolds are evaluated. It was found that increasing the thickness of nanofiber layer not only limited the cell infiltration into the scaffolds, but also restrained the osteoblastic cell phenotype development. Moreover, the geometric effect studies indicated that scaffolds with the thinner wall and gap distance 0.2 mm show the best bioactivity for osteoblasts.

  12. Genesis endapan aluvium Dataran Purworejo Jawa Tengah; Implikasinya terhadap sumber daya geologi

    Directory of Open Access Journals (Sweden)

    Sutikno Bronto

    2014-06-01

    Full Text Available http://dx.doi.org/10.17014/ijog.vol2no4.20072Purworejo is part of the Southern Central Jawa alluvial plain that is bordered by the South Sera- yu Mountains and Sumbing Volcano in the north, West Progo Mountains in the east, Indian Ocean in the south, and Kebumen-Banyumas plain in the west. This Purworejo plain comprises reworked allu- vial deposits, particularly from Tertiary volcanic rocks of the South Serayu and West Progo Mount- ains, and the Sumbing Quaternary Volcano. In the northern part older reworked material has formed Purworejo alluvial fan in the east and Kutoarjo alluvial fan in the west. Those alluvial fans developed from northeast side of studied area. The central part of Purworejo plain consists of older coastal alluvial deposits which have been covered by recent fluvial deposits that transported by Wawar River in the west, Jali River in the middle, and Bogowonto River in the east. The southern part of Purworejo plain, starting from the Lereng River until present coastal line is composed of younger alluvial coast- al deposits. It is suggested that groundwater resources are abundant under the Purworejo plain, and the young alluvial coastal deposits contain highly potential iron sand and associated minerals.  

  13. Deposition of selenium coatings on beryllium foils. Revision 1

    International Nuclear Information System (INIS)

    Erikson, E.D.; Tassano, P.L.; Reiss, R.H.; Griggs, G.E.

    1984-01-01

    A technique for preparing selenium films on 50.8 micrometers thick beryllium foils is described. The selenium was deposited in vacuum from a resistance heated evaporation source. A water-cooled enclosure was used to minimize contamination of the vacuum system and to reduce the exposure of personnel to toxic and obnoxious materials. Profilometry measurements of the coatings indicated selenium thicknesses of 5.5, 12.9, 37.5, 49.8 and 74.5 micrometers. The control of deposition rate and of coating thickness was facilitated using a commercially available closed-loop programmable deposition controller. The x-ray transmission of the coated substrates was measured using a tritiated zirconium source. The transmissivities of the film/substrate combination are presented for the range of energies from 4 to 20 keV

  14. Reference conditions for old-growth redwood restoration on alluvial flats

    Science.gov (United States)

    Christa M. Dagley; John-Pascal. Berrill

    2012-01-01

    We quantified structural attributes in three alluvial flat old-growth coast redwood stands. Tree size parameters and occurrences of distinctive features (e.g., burls, goose pens) were similar between stands. Occurrence of distinctive features was greater among larger trees. Tree sizefrequency distributions conformed to a reverse-J diameter distribution. The range of...

  15. Quaternary continental deposits in north of Uruguay: stratigraphy and paleontology

    International Nuclear Information System (INIS)

    Goso Aguilar, C.; Ubilla, M.

    2004-01-01

    Conglomeradic and sandstones lithofacies corresponding to fluvial and alluvial environments were recognized. These sediments partially belong to the quaternary Mataojos Formation. A discordant contact with the upper pelitic deposits identified with the Sopas Formation was detected. This paper deals with sedimentological and stratigraphical considerations in order to explain the sedimentary processes during the genesis of these stratigraphic sections as well as to begin a lithostratigraphical discussion about the operability of those units. In turn, chronologic and paleoenvironment comments are provided taken into account vertebrates fossils and tools to perform chronocorrelation with southern sedimentological units of Uruguay [es

  16. Evolution of optical constants of silicon dioxide on silicon from ultrathin films to thick films

    Energy Technology Data Exchange (ETDEWEB)

    Cai Qingyuan; Zheng Yuxiang; Mao Penghui; Zhang Rongjun; Zhang Dongxu; Liu Minghui; Chen Liangyao, E-mail: yxzheng@fudan.edu.c [Key Laboratory of Micro and Nano Photonic Structures, Ministry of Education, Department of Optical Science and Engineering, Fudan University, Shanghai 200433 (China)

    2010-11-10

    A series of SiO{sub 2} films with thickness range 1-600 nm have been deposited on crystal silicon (c-Si) substrates by electron beam evaporation (EBE) method. Variable-angle spectroscopic ellipsometry (VASE) in combination with a two-film model (ambient-oxide-interlayer substrate) was used to determine the optical constants and thicknesses of the investigated films. The refractive indices of SiO{sub 2} films thicker than 60 nm are close to those of bulk SiO{sub 2}. For the thin films deposited at the rate of {approx}1.0 nm s{sup -1}, the refractive indices increase with decreasing thickness from {approx}60 to {approx}10 nm and then drop sharply with decreasing thickness below {approx}10 nm. However, for thin films deposited at the rates of {approx}0.4 and {approx}0.2 nm s{sup -1}, the refractive indices monotonically increase with decreasing thickness below 60 nm. The optical constants of the ultrathin film depend on the morphology of the film, the stress exerted on the film, as well as the stoichiometry of the oxide film.

  17. Evolution of optical constants of silicon dioxide on silicon from ultrathin films to thick films

    International Nuclear Information System (INIS)

    Cai Qingyuan; Zheng Yuxiang; Mao Penghui; Zhang Rongjun; Zhang Dongxu; Liu Minghui; Chen Liangyao

    2010-01-01

    A series of SiO 2 films with thickness range 1-600 nm have been deposited on crystal silicon (c-Si) substrates by electron beam evaporation (EBE) method. Variable-angle spectroscopic ellipsometry (VASE) in combination with a two-film model (ambient-oxide-interlayer substrate) was used to determine the optical constants and thicknesses of the investigated films. The refractive indices of SiO 2 films thicker than 60 nm are close to those of bulk SiO 2 . For the thin films deposited at the rate of ∼1.0 nm s -1 , the refractive indices increase with decreasing thickness from ∼60 to ∼10 nm and then drop sharply with decreasing thickness below ∼10 nm. However, for thin films deposited at the rates of ∼0.4 and ∼0.2 nm s -1 , the refractive indices monotonically increase with decreasing thickness below 60 nm. The optical constants of the ultrathin film depend on the morphology of the film, the stress exerted on the film, as well as the stoichiometry of the oxide film.

  18. Oxygen Barrier Coating Deposited by Novel Plasma-enhanced Chemical Vapor Deposition

    DEFF Research Database (Denmark)

    Jiang, Juan; Benter, M.; Taboryski, Rafael Jozef

    2010-01-01

    We report the use of a novel plasma-enhanced chemical vapor deposition chamber with coaxial electrode geometry for the SiOx deposition. This novel plasma setup exploits the diffusion of electrons through the inner most electrode to the interior samples space as the major energy source. This confi......We report the use of a novel plasma-enhanced chemical vapor deposition chamber with coaxial electrode geometry for the SiOx deposition. This novel plasma setup exploits the diffusion of electrons through the inner most electrode to the interior samples space as the major energy source...... effect of single-layer coatings deposited under different reaction conditions was studied. The coating thickness and the carbon content in the coatings were found to be the critical parameters for the barrier property. The novel barrier coating was applied on different polymeric materials...

  19. Feasibility study of thermal water illumination in the area of Calnu sugar, Colonia Spain, Artigas department

    International Nuclear Information System (INIS)

    Carrion, R.; Pena, S.; Cicalese, H.; Pacheco, A.

    1999-01-01

    This work is about the hydrogeological study carried in Artigas department (Calnu sugar) with the proposal to determine the lighting chance on thermal water. By geophysical methods is possible to estimate the thickness and alluvial characteristics, sedimentary deposits, failures or alteration mantles. The results obtained allowed to determine the geometry, magnitude and relative depth of the body studied. The measured parameter is the apparent resistivity. This resistivity variation is measured by vertical electrical soundings

  20. Thermal plasma chemical vapor deposition

    International Nuclear Information System (INIS)

    Heberlein, J.; Pfender, E.

    1993-01-01

    Thermal plasmas, with temperatures up to and even exceeding 10 4 K, are capable of producing high density vapor phase precursors for the deposition of relatively thick films. Although this technology is still in its infancy, it will fill the void between the relatively slow deposition processes such as physical vapor deposition and the high rate thermal spray deposition processes. In this chapter, the present state-of-the-art of this field is reviewed with emphasis on the various types of reactors proposed for this emerging technology. Only applications which attracted particular attention, namely diamond and high T c superconducting film deposition, are discussed in greater detail. (orig.)

  1. The Miocene Roof Mapping Using Microtremor Recording and Electrical Survey Method in Blida City, Algeria

    Science.gov (United States)

    Bouchelouh, Assia; Bensalem, Rabah; Zaourar, Naima; Machane, Djamel; Moulouel, Hakim; Oubaiche, El Hadi

    2018-01-01

    Bedrock depths in the Mitidja basin in general and in the Blida region in particular are still poorly known despite, the existence of some relatively deep hydraulic boreholes that intersect only superficial alluvial formations. To assess the seismic risk of Blida town, knowledge of soil amplification requires the thickness and properties of sedimentary formations that cover the substratum. For the purposes of our study, the thicknesses obtained by the vertical electric soundings, carried out in the hydrogeological study of the basin, were combined with horizontal-to-vertical spectral ratio (HVSR) microtremor recordings. This combination made it possible to determine an empirical relationship between frequency and thickness specific to the Blida site area, which enabled the roof of the Miocene to be mapped and shows slight undulations with directions compatible with the tectonic constraints of the region. The boundaries between the low and high frequencies obtained by HVSR are well materialized, at south by Sidi El Kebir river, at west by Chiffa river and in the central part by a line of direction SE-NW corresponding to the old passage of Sidi El Kebir river. The presence of low frequencies attributed to the old alluvial deposits with significant thicknesses that originate just after Sidi El Kebir river confirms that the South Mitidjian contact is subvertical.

  2. Litterfall in the hardwood forest of a minor alluvial-floodplain

    Science.gov (United States)

    Calvin E. Meier; John A. Stanturf; Emile S. Gardiner

    2006-01-01

    within mature deciduous forests, annual development of foliar biomass is a major component of aboveground net primary production and nutrient demand. As litterfall, this same foliage becomes a dominant annual transfer of biomass and nutrients to the detritus pathway. We report litterfall transfers of a mature bottomland hardwood forest in a minor alluvial-floodplain...

  3. Studies of gamma emitters in the alluvial deposit and in water of the Bug River

    International Nuclear Information System (INIS)

    Chibowski, S.; Pawlik, M.

    1995-01-01

    Studies of the contents of gamma emitters in samples of water and deposit taken from the Bug River (in Poland only) are presented. The total γ-activity of deposits ranges from 120-650 Bq/kg and the average value is 350 Bq/kg. The elevated activity is chiefly due to the presence of natural radionuclides. The main artificial radionuclides are Cs-137 and Cs-134, whose contribution to the total activity ranges from 0.2 to 6%. The activity of waters samples is low, namely, 1.7-3.5 Bq/kg and is due to the presence of natural radionuclides. The heterogeneity of the distribution of natural and artificial radionuclides in the studies samples reveals the effect of economical and industrial activities on contamination of the Bug. (author). 7 refs, 1 fig., 4 tabs

  4. ITO thin films deposited by advanced pulsed laser deposition

    International Nuclear Information System (INIS)

    Viespe, Cristian; Nicolae, Ionut; Sima, Cornelia; Grigoriu, Constantin; Medianu, Rares

    2007-01-01

    Indium tin oxide thin films were deposited by computer assisted advanced PLD method in order to obtain transparent, conductive and homogeneous films on a large area. The films were deposited on glass substrates. We studied the influence of the temperature (room temperature (RT)-180 deg. C), pressure (1-6 x 10 -2 Torr), laser fluence (1-4 J/cm 2 ) and wavelength (266-355 nm) on the film properties. The deposition rate, roughness, film structure, optical transmission, electrical conductivity measurements were done. We deposited uniform ITO thin films (thickness 100-600 nm, roughness 5-10 nm) between RT and 180 deg. C on a large area (5 x 5 cm 2 ). The films have electrical resistivity of 8 x 10 -4 Ω cm at RT, 5 x 10 -4 Ω cm at 180 deg. C and an optical transmission in the visible range, around 89%

  5. Age of depositional and weathering events in Central Amazonia

    Science.gov (United States)

    Sant'Anna, Lucy Gomes; Soares, Emílio Alberto do Amaral; Riccomini, Claudio; Tatumi, Sonia Hatsue; Yee, Marcio

    2017-08-01

    In the last three decades, several studies have been devoted to understanding the role of Late Pleistocene-Holocene climate changes in the Amazonia lowlands environment. However, most of these studies used data obtained from sedimentary deposits (lakes, swamps, and colluvium) located away from the central plain or on the edges of the Amazonia region. This article integrates optically stimulated luminescence and accelerated mass spectrometry 14C ages with sedimentological and geomorphological data obtained during this study or compiled from the literature for fluvial and lacustrine deposits of the central alluvial plain of the Solimões-Amazon River. The age data allow us to present a chronological framework for the Late Pleistocene-Holocene deposits and conclude that (i) the dryness of the LGM in central Amazonia lowlands is recorded by the formation of fluvial terraces and their weathering to pedogenic hematite between 25.3 ka and 17.7 ka; (ii) floodplain deposition was contemporaneous with terrace weathering and occurred in a context of decreased water volume in fluvial channels, lowering of river base level and sea level, and isostatic rebound of the continent; and (iii) lateral and mid-channel fluvial bars in the Solimões-Amazon River have a minimum age of 11.5 ± 1.5 ka, and their deposition responded to increased precipitation at the beginning of the Holocene.

  6. A remote coal deposit revisited

    DEFF Research Database (Denmark)

    Bojesen-Kofoed, Jørgen A.; Kalkreuth, Wolfgang; Petersen, Henrik I.

    2012-01-01

    discovery. The outcrops found in 2009 amount to approximately 8 m of sediment including a coal seam of 2 m thickness. More outcrops and additional coal deposits most certainly are to be found, pending further fieldwork. The deposits are Middle Jurassic, Callovian, in age and were deposited in a floodplain...... environment related to meandering river channels. Spores and pollen in the lower fluvial deposits reflect abundant vegetation of ferns along the river banks. In contrast, a sparse spore and pollen flora in the coals show a mixed vegetation of ferns and gymnosperms. Based on proximate and petrographic analyses...

  7. Nano-crystalline thin and nano-particulate thick TiO2 layer: Cost effective sequential deposition and study on dye sensitized solar cell characteristics

    International Nuclear Information System (INIS)

    Das, P.; Sengupta, D.; Kasinadhuni, U.; Mondal, B.; Mukherjee, K.

    2015-01-01

    Highlights: • Thin TiO 2 layer is deposited on conducting substrate using sol–gel based dip coating. • TiO 2 nano-particles are synthesized using hydrothermal route. • Thick TiO 2 particulate layer is deposited on prepared thin layer. • Dye sensitized solar cells are made using thin and thick layer based photo-anode. • Introduction of thin layer in particulate photo-anode improves the cell efficiency. - Abstract: A compact thin TiO 2 passivation layer is introduced between the mesoporous TiO 2 nano-particulate layer and the conducting glass substrate to prepare photo-anode for dye-sensitized solar cell (DSSC). In order to understand the effect of passivation layer, other two DSSCs are also developed separately using TiO 2 nano-particulate and compact thin film based photo-anodes. Nano-particles are prepared using hydrothermal synthesis route and the compact passivation layer is prepared by simply dip coating the precursor sol prepared through wet chemical route. The TiO 2 compact layer and the nano-particles are characterised in terms of their micro-structural features and phase formation behavior. It is found that introduction of a compact TiO 2 layer in between the mesoporous TiO 2 nano-particulate layer and the conducting substrate improves the solar to electric conversion efficiency of the fabricated cell. The dense thin passivation layer is supposed to enhance the photo-excited electron transfer and prevent the recombination of photo-excited electrons

  8. Studies Concerning Water-Surface Deposits in Recovery Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Strandberg, O; Arvesen, J; Dahl, L

    1971-11-15

    The Feed-water Committee of the Stiftelsen Svensk Cellulosaforskning (Foundation for Swedish Cellulose Research) has initiated research and investigations which aim to increase knowledge about water-surface deposits in boiler tubes, and the resulting risks of gas-surface corrosion in chemical recovery boilers (sulphate pulp industry). The Committee has arranged with AB Atomenergi, Studsvik, for investigations into the water-surface deposits on tubes from six Scandinavian boilers. These investigations have included direct measurements of the thermal conductivity of the deposits, and determinations of their quantity, thickness and structure have been carried out. Previous investigations have shown that gas-surface corrosion can occur at tube temperatures above 330 deg C. The measured values for the thermal conductivity of the deposits indicate that even with small quantities of deposit (c. 1 g/dm2 ) and a moderate boiler pressure (40 atm), certain types of deposit can give rise to the above-mentioned surface temperature, at which the risk of gas-surface corrosion becomes appreciable. For higher boiler pressures the risk is great even with a minimal layer of deposit. The critical deposit thickness can be as low as 0.1 mm

  9. Influence of ni thickness on oscillation coupling in Cu/Ni multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Gagorowska, B; Dus-Sitek, M [Institute of Physics, Czestochowa University of Technology, Al. Armii Krajowej 19, 42-200 Czestochowa (Poland)

    2007-08-15

    The results of investigation of magnetic properties of [Cu/Ni]x100 were presented. Samples were deposited by face-to-face sputtering method onto the silicon substrate, the thickness of Cu layer was constant (d{sub Cu} = 2 nm) and the thickness of Ni layer - variable (1 nm {<=} d{sub Ni} {<=} 6 nm). In Cu/Ni multilayers, for the thickness of Ni layer bigger than 2 nm antiferromagnetic coupling (A-F) were observed, for the thickness of Ni smaller than 2 nm A-F coupling is absent.

  10. Influence of ni thickness on oscillation coupling in Cu/Ni multilayers

    International Nuclear Information System (INIS)

    Gagorowska, B; Dus-Sitek, M

    2007-01-01

    The results of investigation of magnetic properties of [Cu/Ni]x100 were presented. Samples were deposited by face-to-face sputtering method onto the silicon substrate, the thickness of Cu layer was constant (d Cu = 2 nm) and the thickness of Ni layer - variable (1 nm ≤ d Ni ≤ 6 nm). In Cu/Ni multilayers, for the thickness of Ni layer bigger than 2 nm antiferromagnetic coupling (A-F) were observed, for the thickness of Ni smaller than 2 nm A-F coupling is absent

  11. Dynamic-speckle profilometer for online measurements of coating thickness

    Energy Technology Data Exchange (ETDEWEB)

    Kamshilin, A A [Laboratory of Optical Sensor Technology, Department of Physics, University of Kuopio, PO Box 1627, FIN-70211 Kuopio (Finland); Semenov, D V [Laboratory of Optical Sensor Technology, Department of Physics, University of Kuopio, PO Box 1627, FIN-70211 Kuopio (Finland); Nippolainen, E [Laboratory of Optical Sensor Technology, Department of Physics, University of Kuopio, PO Box 1627, FIN-70211 Kuopio (Finland); Miridonov, S [Optics Department, CICESE, Carr. Tijuana-Ensenada km 107, C.P. 22860, A.P. 360, Ensenada, B.C. (Mexico)

    2007-10-15

    Online control of thickness of as-deposited coatings is of great importance because it directly affects the quality of protective coatings. We present a novel approach that enables online, real-time and non-contact measurements thickness of thermally sprayed coatings. The proposed technique uses dynamic speckles generated by rapidly deflecting laser beam. Within 10 ms the system can scan 500 times a small area of the deposited layer thus resulting in measurement accuracy of 5 microns irrespectively of the layer roughness. In comparison with traditional optical triangulation technique of distance measurements, our system has following advantages: (i) much simpler optical scheme that includes conventional photodiode to measure the scattered light, (ii) much simpler electronics for real-time data processing, (iii) much higher speed of measurements.

  12. Dynamic-speckle profilometer for online measurements of coating thickness

    International Nuclear Information System (INIS)

    Kamshilin, A A; Semenov, D V; Nippolainen, E; Miridonov, S

    2007-01-01

    Online control of thickness of as-deposited coatings is of great importance because it directly affects the quality of protective coatings. We present a novel approach that enables online, real-time and non-contact measurements thickness of thermally sprayed coatings. The proposed technique uses dynamic speckles generated by rapidly deflecting laser beam. Within 10 ms the system can scan 500 times a small area of the deposited layer thus resulting in measurement accuracy of 5 microns irrespectively of the layer roughness. In comparison with traditional optical triangulation technique of distance measurements, our system has following advantages: (i) much simpler optical scheme that includes conventional photodiode to measure the scattered light, (ii) much simpler electronics for real-time data processing, (iii) much higher speed of measurements

  13. Sedimentary facies and depositional environments of early Mesozoic Newark Supergroup basins, eastern North America

    Science.gov (United States)

    Smoot, J.P.

    1991-01-01

    The early Mesozoic Newark Supergroup consists of continental sedimentary rocks and basalt flows that occupy a NE-trending belt of elongate basins exposed in eastern North America. The basins were filled over a period of 30-40 m.y. spanning the Late Triassic to Early Jurassic, prior to the opening of the north Atlantic Ocean. The sedimentary rocks are here divided into four principal lithofacies. The alluvial-fan facies includes deposits dominated by: (1) debris flows; (2) shallow braided streams; (3) deeper braided streams (with trough crossbeds); or (4) intense bioturbation or hyperconcentrated flows (tabular, unstratified muddy sandstone). The fluvial facies include deposits of: (1) shallow, ephemeral braided streams; (2) deeper, flashflooding, braided streams (with poor sorting and crossbeds); (3) perennial braided rivers; (4) meandering rivers; (5) meandering streams (with high suspended loads); (6) overbank areas or local flood-plain lakes; or (7) local streams and/or colluvium. The lacustrine facies includes deposits of: (1) deep perennial lakes; (2) shallow perennial lakes; (3) shallow ephemeral lakes; (4) playa dry mudflats; (5) salt-encrusted saline mudflats; or (6) vegetated mudflats. The lake margin clastic facies includes deposits of: (1) birdfoot deltas; (2) stacked Gilbert-type deltas; (3) sheet deltas; (4) wave-reworked alluvial fans; or (5) wave-sorted sand sheets. Coal deposits are present in the lake margin clastic and the lacustrine facies of Carnian age (Late Triassic) only in basins of south-central Virginia and North and South Carolina. Eolian deposits are known only from the basins in Nova Scotia and Connecticut. Evaporites (and their pseudomorphs) occur mainly in the northern basins as deposits of saline soils and less commonly of saline lakes, and some evaporite and alkaline minerals present in the Mesozoic rocks may be a result of later diagenesis. These relationships suggest climatic variations across paleolatitudes, more humid to the

  14. Deposition of plasmon gold-fluoropolymer nanocomposites

    Science.gov (United States)

    Safonov, Alexey I.; Sulyaeva, Veronica S.; Timoshenko, Nikolay I.; Kubrak, Konstantin V.; Starinskiy, Sergey V.

    2016-12-01

    Degradation-resistant two-dimensional metal-fluoropolymer composites consisting of gold nanoparticles coated with a thin fluoropolymer film were deposited on a substrate by hot wire chemical vapour deposition (HWCVD) and ion sputtering. The morphology and optical properties of the obtained coatings were determined. The thickness of the thin fluoropolymer film was found to influence the position of the surface plasmon resonance peak. Numerical calculations of the optical properties of the deposited materials were performed using Mie theory and the finite-difference time-domain (FDTD) method. The calculation results are consistent with the experimental data. The study shows that the position of the resonance peak can be controlled by changing the surface concentration of particles and the thickness of the fluoropolymer coating. The protective coating was found to prevent the plasmonic properties of the nanoparticles from changing for several months.

  15. Growth and characterization of thick cBN coatings on silicon and tool substrates

    International Nuclear Information System (INIS)

    Bewilogua, K.; Keunecke, M.; Weigel, K.; Wiemann, E.

    2004-01-01

    Recently some research groups have achieved progress in the deposition of cubic boron nitride (cBN) coatings with a thickness of 2 μm and more, which is necessary for cutting tool applications. In our laboratory, thick cBN coatings were sputter deposited on silicon substrates using a boron carbide target. Following a boron carbide interlayer (few 100 nm thick), a gradient layer with continuously increasing nitrogen content was prepared. After the cBN nucleation, the process parameters were modified for the cBN film growth to a thickness of more than 2 μm. However, the transfer of this technology to technically relevant substrates, like cemented carbide cutting inserts, required some further process modifications. At first, a titanium interlayer had to be deposited followed by a more than 1-μm-thick boron carbide layer. The next steps were identical to those on silicon substrates. The total coating thickness was in the range of 3 μm with a 0.5- to nearly 1-μm-thick cBN top layer. In spite of the enormous intrinsic stress, both the coatings on silicon and on cemented carbide exhibited a good adhesion and a prolonged stability in humid air. Oxidation experiments revealed a stability of the coating system on cemented carbide up to 700 deg. C and higher. Coated cutting inserts were tested in turning operations with different metallic workpiece materials. The test results will be compared to those of well-established cutting materials, like polycrystalline cubic boron nitride (PCBN) and oxide ceramics, considering the wear of coated tools

  16. Design of alluvial Egyptian irrigation canals using artificial neural networks method

    Directory of Open Access Journals (Sweden)

    Hassan Ibrahim Mohamed

    2013-06-01

    Full Text Available In the present study, artificial neural networks method (ANNs is used to estimate the main parameters which used in design of stable alluvial channels. The capability of ANN models to predict the stable alluvial channels dimensions is investigated, where the flow rate and sediment mean grain size were considered as input variables and wetted perimeter, hydraulic radius, and water surface slope were considered as output variables. The used ANN models are based on a back propagation algorithm to train a multi-layer feed-forward network (Levenberg Marquardt algorithm. The proposed models were verified using 311 data sets of field data collected from 61 manmade canals and drains. Several statistical measures and graphical representation are used to check the accuracy of the models in comparison with previous empirical equations. The results of the developed ANN model proved that this technique is reliable in such field compared with previously developed methods.

  17. BaF2 POST-DEPOSITION REACTION PROCESS FOR THICK YBCO FILMS

    International Nuclear Information System (INIS)

    SUENAGA, M.; SOLOVYOV, V.F.; WU, L.; WIESMANN, H.J.; ZHU, Y.

    2001-01-01

    The basic processes of the so-called BaF 2 process for the formation of YBa 2 Cu 3 O 7 , YBCO, films as well as its advantages over the in situ formation processes are discussed in the previous chapter. The process and the properties of YBCO films by this process were also nicely described in earlier articles by R. Feenstra, (et al.) Here, we will discuss two pertinent subjects related to fabrication of technologically viable YBCO conductors using this process. These are (1) the growth of thick (>> 1 microm) c-axis-oriented YBCO films and (2) their growth rates. Before the detail discussions of these subjects are given, we first briefly discuss what geometrical structure a YBCO-coated conductor should be. Then, we will provide examples of simple arguments for how thick the YBCO films and how fast their growth rates need to be. Then, the discussions in the following two sections are devoted to: (1) the present understanding of the nucleation and the growth process for YBCO, and why it is so difficult to grow thick c-axis-oriented films (> 3 microm), and (2) our present understanding of the YBCO growth-limiting mechanism and methods to increase the growth rates. The values of critical-current densities J c in these films are of primary importance for the applications,. and the above two subjects are intimately related to the control of J c of the films. In general, the lower the temperatures of the YBCO formation are the higher the values of J c of the films. Thus, the present discussion is limited to those films which are reacted at ∼735 C. This is the lowest temperature at which c-axis-oriented YBCO films (1-3 microm thick) are comfortably grown. It is also well known that the non-c-axis oriented YBCO platelets are extremely detrimental to the values of J c such that their effects on J c dwarf essentially all of other microstructural effects which control J c . Hence, the discussion given below is mainly focused on how to avoid the growth of these crystallites

  18. Deposition of plasmon gold–fluoropolymer nanocomposites

    Energy Technology Data Exchange (ETDEWEB)

    Safonov, Alexey I., E-mail: safonov@itp.nsc.ru [Kutateladze Institute of Thermophysics SB RAS, Lavrentyev Ave. 1, 630090, Novosibirsk (Russian Federation); Sulyaeva, Veronica S. [Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentyev Ave. 3, 630090, Novosibirsk (Russian Federation); Timoshenko, Nikolay I.; Kubrak, Konstantin V.; Starinskiy, Sergey V. [Kutateladze Institute of Thermophysics SB RAS, Lavrentyev Ave. 1, 630090, Novosibirsk (Russian Federation)

    2016-12-01

    Degradation-resistant two-dimensional metal–fluoropolymer composites consisting of gold nanoparticles coated with a thin fluoropolymer film were deposited on a substrate by hot wire chemical vapour deposition (HWCVD) and ion sputtering. The morphology and optical properties of the obtained coatings were determined. The thickness of the thin fluoropolymer film was found to influence the position of the surface plasmon resonance peak. Numerical calculations of the optical properties of the deposited materials were performed using Mie theory and the finite-difference time-domain (FDTD) method. The calculation results are consistent with the experimental data. The study shows that the position of the resonance peak can be controlled by changing the surface concentration of particles and the thickness of the fluoropolymer coating. The protective coating was found to prevent the plasmonic properties of the nanoparticles from changing for several months. - Highlights: • The gold–fluoropolymer composites are obtained by a combination of GJD and HWCVD. • The optical properties of composites were determined by experiments and calculation. • The dependence of SPR position on filling, NPs size and FP thickness were analyzed. • The plasmonic properties of the Au NPs are saved in the fluoropolymer matrix.

  19. Miniaturized, Planar Ion-selective Electrodes Fabricated by Means of Thick-film Technology

    Directory of Open Access Journals (Sweden)

    Robert Koncki

    2006-04-01

    Full Text Available Various planar technologies are employed for developing solid-state sensorshaving low cost, small size and high reproducibility; thin- and thick-film technologies aremost suitable for such productions. Screen-printing is especially suitable due to itssimplicity, low-cost, high reproducibility and efficiency in large-scale production. Thistechnology enables the deposition of a thick layer and allows precise pattern control.Moreover, this is a highly economic technology, saving large amounts of the used inks. Inthe course of repetitions of the film-deposition procedure there is no waste of material dueto additivity of this thick-film technology. Finally, the thick films can be easily and quicklydeposited on inexpensive substrates. In this contribution, thick-film ion-selective electrodesbased on ionophores as well as crystalline ion-selective materials dedicated forpotentiometric measurements are demonstrated. Analytical parameters of these sensors arecomparable with those reported for conventional potentiometric electrodes. All mentionedthick-film strip electrodes have been totally fabricated in only one, fully automated thick-film technology, without any additional manual, chemical or electrochemical steps. In allcases simple, inexpensive, commercially available materials, i.e. flexible, plastic substratesand easily cured polymer-based pastes were used.

  20. Electroless atomic layer deposition

    Science.gov (United States)

    Robinson, David Bruce; Cappillino, Patrick J.; Sheridan, Leah B.; Stickney, John L.; Benson, David M.

    2017-10-31

    A method of electroless atomic layer deposition is described. The method electrolessly generates a layer of sacrificial material on a surface of a first material. The method adds doses of a solution of a second material to the substrate. The method performs a galvanic exchange reaction to oxidize away the layer of the sacrificial material and deposit a layer of the second material on the surface of the first material. The method can be repeated for a plurality of iterations in order to deposit a desired thickness of the second material on the surface of the first material.

  1. Scale Thickness Measurement of Steam Generator Tubing Using Eddy Current Signal of Bobbin Coil

    International Nuclear Information System (INIS)

    Kim, Chang Soo; Um, Ki Soo; Kim, Jae Dong

    2012-01-01

    Steam generator is one of the major components of nuclear power plant and steam generator tubes are the pressure boundary between primary and secondary side, which makes them critical for nuclear safety. As the operating time of nuclear power plant increases, not only damage mechanisms but also scaled deposits on steam generator tubes are known to be problematic causing tube support flow hole blockage and heat fouling. The ability to assess the extent and location of scaled deposits on tubes became essential for management and maintenance of steam generator and eddy current bobbin data can be utilized to measure thickness of scale on tubes. In this paper, tube reference standards with various thickness of scaled deposit has been set up to provide information about the overall deposit condition of steam generator tubes, providing essential tool for steam generator management and maintenance to predict and prevent future damages. Also, methodology to automatically measure scale thickness on tubes has been developed and applied to field data to estimate overall scale amount.

  2. Electrical resistivity tomography investigations in the ufita Valley (southern Italy.

    Directory of Open Access Journals (Sweden)

    C. Basso

    2008-06-01

    Full Text Available Several Electrical Resistivity Tomography (ERT surveys have been carried out to study the subsurface structural and sedimentary settings of the upper Ufita River valley, and to evaluate their efficiency to distinguish the geological boundary between shallow Quaternary sedimentary deposits and clayey bedrock characterized by moderate resistivity contrast. Five shallow ERTs were carried out across a morphological scarp running at the foot of the northeastern slope of the valley. This valley shoulder is characterized by a set of triangular facets, that some authors associated to the presence of a SW-dipping normal fault. The geological studies allow us to interpret the shallow ERTs results obtaining a resistivity range for each Quaternary sedimentary deposit. The tomographies showed the geometrical relationships of alluvial and slope deposits, having a maximum thickness of 30-40 m, and the morphology of the bedrock. The resistivity range obtained for each sedimentary body has been used for calibrating the tomographic results of one 3560m-long deep ERT carried out across the deeper part of the intramountain depression with an investigation depth of about 170 m. The deep resistivity result highlighted the complex alluvial setting, characterized by alternating fine grained lacustrine deposits and coarser gravelly fluvial sediments.

  3. Historical trajectories and restoration strategies for the Mississippi River alluvial valley

    Science.gov (United States)

    Brice B. Hanberry; John M. Kabrick; Hong S. He; Brian J. Palik

    2012-01-01

    Unlike upland forests in the eastern United States, little research is available about the composition and structure of bottomland forests before Euro-American settlement. To provide a historical reference encompassing spatial variation for the Lower Mississippi River Alluvial Valley, we quantified forest types, species distributions, densities, and stocking of...

  4. Thickness effects of yttria-doped ceria interlayers on solid oxide fuel cells

    Science.gov (United States)

    Fan, Zeng; An, Jihwan; Iancu, Andrei; Prinz, Fritz B.

    2012-11-01

    Determining the optimal thickness range of the interlayed yttria-doped ceria (YDC) films promises to further enhance the performance of solid oxide fuel cells (SOFCs) at low operating temperatures. The YDC interlayers are fabricated by the atomic layer deposition (ALD) method with one super cycle of the YDC deposition consisting of 6 ceria deposition cycles and one yttria deposition cycle. YDC films of various numbers of ALD super cycles, ranging from 2 to 35, are interlayered into bulk fuel cells with a 200 um thick yttria-stabilized zirconia (YSZ) electrolyte. Measurements and analysis of the linear sweep voltammetry of these fuel cells reveal that the performance of the given cells is maximized at 10 super cycles. Auger elemental mapping and X-ray photoelectron spectroscopy (XPS) techniques are employed to determine the film completeness, and they verify 10 super cycles of YDC to be the critical thickness point. This optimal YDC interlayer condition (6Ce1Y × 10 super cycles) is applied to the case of micro fuel cells as well, and the average performance enhancement factor is 1.4 at operating temperatures of 400 and 450 °C. A power density of 1.04 W cm-2 at 500 °C is also achieved with the optimal YDC recipe.

  5. Quality of water in alluvial aquifers in eastern Iowa

    Science.gov (United States)

    Savoca, Mark E.; Sadorf, Eric M.; Linhart, S. Michael; Barnes, Kimberlee K.

    2001-01-01

    The goal of the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Program is to assess the status and trends in the quality of the Nation's surface and ground water, and to better understand the natural and human factors affecting water quality. The Eastern Iowa Basins study unit encompasses an area of about 50,500 square kilometers (19,500 square miles) in eastern Iowa and southern Minnesota and is one of 59 study units in the NAWQA program. Land-use studies are an important component of the NAWQA program, and are designed to assess the concentration and distribution of water-quality constituents in recently recharged ground water associated with the most significant land use and hydrogeologic settings within a study unit. The focus of the land-use study in the Eastern Iowa Basins study unit is agricultural and urban land uses and alluvial aquifers. Agriculture is the dominant land use in the study unit. Urban areas, although not extensive, represent important potential source areas of contaminants associated with residential, commercial, and industrial activities. Alluvial aquifers are present throughout much of the study unit, and constitute a major ground-water supply that is susceptible to contamination from land-use activities.

  6. Ice-Rich Yedoma Permafrost: A Synthesis of Circum-Arctic Distribution and Thickness

    Science.gov (United States)

    Strauss, J.; Fedorov, A. N.; Fortier, D.; Froese, D. G.; Fuchs, M.; Grosse, G.; Günther, F.; Harden, J. W.; Hugelius, G.; Kanevskiy, M. Z.; Kholodov, A. L.; Kunitsky, V.; Laboor, S.; Lapointe Elmrabti, L.; Rivkina, E.; Robinson, J. E.; Schirrmeister, L.; Shmelev, D.; Shur, Y.; Spektor, V.; Ulrich, M.; Veremeeva, A.; Walter Anthony, K. M.; Zimov, S. A.

    2015-12-01

    Vast portions of Arctic and sub-Arctic Siberia, Alaska and the Yukon Territory are covered by ice-rich silts that are penetrated by large ice wedges, resulting from syngenetic sedimentation and freezing. Accompanied by wedge-ice growth, the sedimentation process was driven by cold continental climatic and environmental conditions in unglaciated regions during the late Pleistocene, inducing the accumulation of the unique Yedoma permafrost deposits up to 50 meter thick. Because of fast incorporation of organic material into permafrost during formation, Yedoma deposits include low-decomposed organic matter. Moreover, ice-rich permafrost deposits like Yedoma are especially prone to degradation triggered by climate changes or human activity. When Yedoma deposits degrade, large amounts of sequestered organic carbon as well as other nutrients are released and become part of active biogeochemical cycling. This could be of global significance for the climate warming, as increased permafrost thaw is likely to cause a positive feedback loop. Therefore, a detailed assessment of the Yedoma deposit volume is of importance to estimate its potential future climate response. Moreover, as a step beyond the objectives of this synthesis study, our coverage (see figure for the Yedoma domain) and thickness estimation will provide critical data to refine the Yedoma permafrost organic carbon inventory, which is assumed to have freeze-locked between 83±12 and 129±30 gigatonnes (Gt) of organic carbon. Hence, we here synthesize data on the circum-Arctic and sub-Arctic distribution and thickness of Yedoma permafrost (see figure for the Yedoma domain) in the framework of an Action Group funded by the International Permafrost Association (IPA). The quantification of the Yedoma coverage is conducted by the digitization of geomorphological and Quaternary geological maps. Further data on Yedoma thickness is contributed from boreholes and exposures reported in the scientific literature.

  7. Barium titanate thick films prepared by screen printing technique

    Directory of Open Access Journals (Sweden)

    Mirjana M. Vijatović

    2010-06-01

    Full Text Available The barium titanate (BaTiO3 thick films were prepared by screen printing technique using powders obtained by soft chemical route, modified Pechini process. Three different barium titanate powders were prepared: i pure, ii doped with lanthanum and iii doped with antimony. Pastes for screen printing were prepared using previously obtained powders. The thick films were deposited onto Al2O3 substrates and fired at 850°C together with electrode material (silver/palladium in the moving belt furnace in the air atmosphere. Measurements of thickness and roughness of barium titanate thick films were performed. The electrical properties of thick films such as dielectric constant, dielectric losses, Curie temperature, hysteresis loop were reported. The influence of different factors on electrical properties values was analyzed.

  8. Magnetic properties of alluvial soils contaminated with lead, zinc and cadmium

    Czech Academy of Sciences Publication Activity Database

    Petrovský, Eduard; Kapička, Aleš; Jordanova, Neli; Borůvka, L.

    2001-01-01

    Roč. 48, č. 2 (2001), s. 12-136 ISSN 0926-9851 R&D Projects: GA ČR GA205/96/0260 Institutional research plan: CEZ:AV0Z3012916 Keywords : magnetic properties * alluvial soil * heavy metals Subject RIV: DE - Earth Magnetism, Geodesy, Geography Impact factor: 0.390, year: 2001

  9. Precambrian fluvial deposits: Enigmatic palaeohydrological data from the c. 2 1.9 Ga Waterberg Group, South Africa

    Science.gov (United States)

    Eriksson, Patrick G.; Bumby, Adam J.; Brümer, Jacobus J.; van der Neut, Markus

    2006-08-01

    Precambrian fluvial systems, lacking the influence of rooted vegetation, probably were characterised by flashy surface runoff, low bank stability, broad channels with abundant bedload, and faster rates of channel migration; consequently, a braided fluvial style is generally accepted. Pre-vegetational braided river systems, active under highly variable palaeoclimatic conditions, may have been more widespread than are modern, ephemeral dry-land braided systems. Aeolian deflation of fine fluvial detritus does not appear to have been prevalent. With the onset of large cratons by the Neoarchaean-Palaeoproterozoic, very large, perennial braided river systems became typical. The c. 2.06-1.88 Ga Waterberg Group, preserved within a Main and a smaller Middelburg basin on the Kaapvaal craton, was deposited largely by alluvial/braided-fluvial and subordinate palaeo-desert environments, within fault-bounded, possibly pull-apart type depositories. Palaeohydrological data obtained from earlier work in the Middelburg basin (Wilgerivier Formation) are compared to such data derived from the correlated Blouberg Formation, situated along the NE margin of the Main basin. Within the preserved Blouberg depository, palaeohydrological parameters estimated from clast size and cross-bed set thickness data, exhibit rational changes in their values, either in a down-palaeocurrent direction, or from inferred basin margin to palaeo-basin centre. In both the Wilgerivier and Blouberg Formations, calculated palaeoslope values (derived from two separate formulae) plot within the gap separating typical alluvial fan gradients from those which characterise rivers (cf. [Blair, T.C., McPherson, J.G., 1994. Alluvial fans and their natural distinction from rivers based on morphology, hydraulic processes, sedimentary processes, and facies assemblages. J. Sediment. Res. A64, 450-489.]). Although it may be argued that such data support possibly unique fluvial styles within the Precambrian, perhaps related to

  10. Carbonate deposition, Pyramid Lake subbasin, Nevada: 1. Sequence of formation and elevational distribution of carbonate deposits (Tufas)

    Science.gov (United States)

    Benson, L.

    1994-01-01

    During the late Quarternary, the elevation of terrace cutting and carbonate deposition in the Pyramid Lake subbasin were controlled by constancy of lake level imposed by spill to adjoining subbasins. Sill elevations are 1177-1183 m (Mud Lake Slough Sill), 1207 m (Emerson Pass Sill), and 1265 m (Darwin Pass Sill). Carbonate deposition was favored by: (1) hydrologic closure, (2) proximity to a source of calcium, (3) elevated water temperature, and (4) a solid substrate. The thickness and aspect of tufa are a function oflake-level dynamics. Relatively thin sheets and pendant sheets were deposited during a rising or falling lake. The upper parts of thick reef-form tufas have a horizontal aspect and were deposited in a lake which was stabilized by spill to the Carson Desert subbasin. The lower parts of the reef-form tufas are thinner and their outer surface has a vertical aspect, indicating that the lower part formed in a receding lake. The thickest and most complete sequences of tufa are mounds that border the Pyramid Lake shore. The tops of the tallest mounds reach the elevation of the Darwin Pass Sill and many mounds have been eroded to the elevations of the Mud Lake Slough Sill of the Emerson Pass Sill. The sequence of tufa formation (from oldest to youngest) displayed in these mounds is: (1) a beachrock containing carbonate-cemented volcanic cobbles, (2) broken and eroded old spheroids that contain thinolitic tufa and an outer rind of dense laminated tufa, (3) large cylindrical (tubular) tufas capped by (4) coatings of old dense tufas, and (5) several generations of old branching tufa commonly associated with thin, platy tufas and coatings of thinolitic tufa, (6) young spheroids that contain poorly oriented young thinolitic tufa in the center and several generations of radially oriented young thinolitic tufas near the outer edge, (7) a transitional thinolite-to-branching tufa, (8) two or more layers of young branching tufa, (9) a 0.5-cm-thick layer of fine

  11. Modeling of Thickness and Profile Uniformity of Thermally Sprayed Coatings Deposited on Cylinders

    Science.gov (United States)

    Yanjun, Zhang; Wenbo, Li; Dayu, Li; Jinkun, Xiao; Chao, Zhang

    2018-02-01

    In thermal spraying processes, kinematic parameters of the robot play a decisive role in the coating thickness and profile. In this regard, some achievements have been made to optimize the spray trajectory on flat surfaces. However, few reports have focused on nonholonomic or variable-curvature cylindrical surfaces. The aim of this study is to investigate the correlation between the coating profile, coating thickness, and scanning step, which is determined by the radius of curvature and scanning angle. A mathematical simulation model was developed to predict the thickness of thermally sprayed coatings. Experiments were performed on cylinders with different radiuses of curvature to evaluate the predictive ability of the model.

  12. Thermal shock resistance of thick boron-doped diamond under extreme heat loads

    NARCIS (Netherlands)

    De Temmerman, G.; Dodson, J.; Linke, J.; Lisgo, S.; Pintsuk, G.; Porro, S.; Scarsbrook, G.

    2011-01-01

    Thick free-standing boron-doped diamonds were prepared by microwave plasma assisted chemical vapour deposition. Samples with a final thickness close to 5 mm and with lateral dimensions 25 x 25 mm were produced. The thermal shock resistance of the material was tested by exposure in the JUDITH

  13. Radiocarbon dating of floodplain and young terraces alluvial sediments of Latvia rivers

    International Nuclear Information System (INIS)

    Eberhards, G.; Saltupe, B.

    2000-01-01

    This paper include new information about alluvial sediments structure and radiocarbon data of some Latvia free-meandering rivers (Gauja, Ogre, Liela and Maza Jugla, Daugava) floodplains and first terraces. In this present study we examined Gauja river floodplains in the different geomorphological and geological areas. Radiocarbon dating add the fact that the high level floodplain (4-5 m) formation and sediment accumulation take place 3000-5000 years before present (BP) middle level floodplains formed 1500-2100 years BP. Investigations show that one river terraces and floodplains with same relative height have a several absolute age. The rivers crossed same hypsometrical regions (highlands, lowlands) downstream in lowlands alluvial terraces performed as floodplains or from from floodplains to terraces with same height. On the highest, middle and in the lower parts of the rivers with free - meandering channel to - day the dynamic balance of the channel processes exits 4000-5000 years. (author)

  14. Microfaunal evidence of age and depositional environments of the Cerro Prieto section (Plio-Pleistocene), Baja California, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Ingle, J.C. Jr.

    1982-01-01

    Microfossils including benthic and planktic foraminifera, ostracodes, calcareous algae, fish skeletal material, and fragments of pelecypods were found in 14 core samples from depths of 185 to 1952 m in the Cerro Prieto geothermal field, providing evidence of both the age and depositional history of sediments comprising the 3000-m-thick Pliocene and Pleistocene section in this area. Ostracodes of brackish water and marine origin constitute the most common microfossils present in this sequence occurring in 8 samples; in situ littoral and neritic species of benthic foraminifera occur in 5 samples with planktic species present in 2 samples. Distributional patterns of ostracodes and foraminifera together with previously analyzed lithofacies (Lyons and van de Kamp, 1980) indicate that the Cerro Prieto section represents an intertonguing complex of alluvial, deltaic, estuarine, and shallow marine environments deposited along the front of the Colorado River delta as it prograded across the Salton Trough during Pliocene and Pleistocene time. Foraminiferal evidence indicates that a sand and shale unit commonly present at depths between 700 and 1100 m represents a significant mid-Pleistocene marine incursion in the Cerro Prieto area. Tentative correlation of the Cerro Prieto section with the well dated Palm Springs Formation of the Imperial Valley, California area suggests that the Pliocene/Pleistocene boundary occurs at a depth of approximately 2000 m in the area of well M-93. Reworked specimens of Cretaceous foraminifera and fragments of the Cretaceous pelecypod Inoceramus were found in five samples further substantiating the Colorado Plateau provenance of a significant portion of the Colorado River deltaic sediments in the Cerro Prieto area.

  15. Effect of thickness on optical properties of thermally evaporated SnS films

    International Nuclear Information System (INIS)

    Selim, M.S.; Gouda, M.E.; El-Shaarawy, M.G.; Salem, A.M.; Abd El-Ghany, W.A.

    2013-01-01

    The effect of film thickness on the structure and optical properties of thermally evaporated SnS film has been studied. SnS films with different thicknesses in the range 152–585 nm were deposited onto clean glass substrates at room temperature. X-ray diffraction study revealed that SnS films of thickness ≥ 283 nm are crystalline, whereas films of lower thickness exhibit poor crystalline with more amorphous background. The crystalline nature of the lower film thickness has been confirmed using transmission electron microscope and the corresponding electron diffraction pattern. The thicker film samples showed nearly stoichiometric chemical composition; however, thinner samples are deficient in S and rich in Sn. The optical property of the deposited films has been investigated in the wavelength range 350–2500 nm. The refractive index increases notably with increasing film thickness. The refractive index for the investigated film thicknesses are adequately described by the effective-single-oscillator model. The static refractive index and the static dielectric constant have been calculated. Analysis of the optical absorption coefficient revealed the presence of direct optical transition and the corresponding band gap values were found to decrease as the film thickness increases. - Highlights: ► X-ray diffraction was used to study the structure of SnS films. ► Transmission electron microscope confirms the crystalline state of SnS films. ► The refractive index increases notably with increasing the film thickness. ► The optical band gap of SnS films decreases with increasing film thickness

  16. The application of microtextural and heavy mineral analysis to discriminate between storm and tsunami deposits

    Science.gov (United States)

    Costa, Pedro J.M.; Gelfenbaum, Guy R.; Dawson, Sue; La selle, Seanpaul; Milne, F; Cascalho, J.; Ponte Lira, C.; Andrade, C.; Freitas, M. C.; Jaffe, Bruce E.

    2017-01-01

    Recent work has applied microtextural and heavy mineral analyses to sandy storm and tsunami deposits from Portugal, Scotland, Indonesia and the USA. We looked at the interpretation of microtextural imagery (scanning electron microscopy) of quartz grains and heavy mineral compositions. We consider inundation events of different chronologies and sources (the AD 1755 Lisbon and 2004 Indian Ocean tsunamis, the Great Storm of 11 January 2005 in Scotland, and Hurricane Sandy in 2012) that affected contrasting coastal and hinterland settings with different regional oceanographic conditions. Storm and tsunami deposits were examined along with potential source sediments (alluvial, beach, dune and nearshore sediments) to determine provenance.Results suggest that tsunami deposits typically exhibit a significant spatial variation in grain sizes, microtextures and heavy minerals. Storm deposits show less variability, especially in vertical profiles. Tsunami and storm quartz grains had more percussion marks and fresh surfaces compared to potential source material. Moreover, in the studied cases, tsunami samples had fewer fresh surfaces than storm deposits.Heavy mineral assemblages are typically site-specific. The concentration of heavy minerals decreases upwards in tsunamigenic units, whereas storm sediments show cyclic concentrations of heavy minerals, reflected in the laminations observed macroscopically in the deposits.

  17. Hideout in steam generator tube deposits

    International Nuclear Information System (INIS)

    Balakrishnan, P.V.; Franklin, K.J.; Turner, C.W.

    1998-05-01

    Hideout in deposits on steam generator tubes was studied using tubes coated with magnetite. Hideout from sodium chloride solutions at 279 degrees C was followed using an on-line high-temperature conductivity probe, as well as by chemical analysis of solution samples from the autoclave in which the studies were done. Significant hideout was observed only at a heat flux greater than 200 kW/m 2 , corresponding to a temperature drop greater than 2 degrees C across the deposits. The concentration factor resulting from the hideout increased highly non-linearly with the heat flux (varying as high as the fourth power of the heat flux). The decrease in the apparent concentration factor with increasing deposit thickness suggested that the pores in the deposit were occupied by a mixture of steam and water, which is consistent with the conclusion from the thermal conductivity measurements on deposits in a separate study. Analyses of the deposits after the hideout tests showed no evidence of any hidden-out solute species, probably due to the concentrations being very near the detection limits and to their escape from the deposit as the tests were being ended. This study showed that hideout in deposits may concentrate solutes in the steam generator bulk water by a factor as high as 2 x 10 3 . Corrosion was evident under the deposit in some tests, with some chromium enrichment on the surface of the tube. Chromium enrichment usually indicates an acidic environment, but the mobility required of chromium to become incorporated into the thick magnetite deposit may indicate corrosion under an alkaline environment. An alkaline environment could result from preferential accumulation of sodium in the solution in the deposit during the hideout process. (author)

  18. Thickness Measurement of V2O5 Nanometric Thin Films Using a Portable XRF

    Directory of Open Access Journals (Sweden)

    Fabio Lopes

    2016-01-01

    Full Text Available Nanometric thin films have always been chiefly used for decoration; however they are now being widely used as the basis of high technology. Among the various physical qualities that characterize them, the thickness strongly influences their properties. Thus, a new procedure is hereby proposed and developed for determining the thickness of V2O5 nanometric thin films deposited on the glass surface using Portable X-Ray Fluorescence (PXRF equipment and the attenuation of the radiation intensity Kα of calcium present in the glass. It is shown through the present paper that the radiation intensity of calcium Kα rays is proportional to film thickness in nanometric films of vanadium deposited on the glass surface.

  19. Assessment of multiple geophysical techniques for the characterization of municipal waste deposit sites

    Science.gov (United States)

    Gaël, Dumont; Tanguy, Robert; Nicolas, Marck; Frédéric, Nguyen

    2017-10-01

    In this study, we tested the ability of geophysical methods to characterize a large technical landfill installed in a former sand quarry. The geophysical surveys specifically aimed at delimitating the deposit site horizontal extension, at estimating its thickness and at characterizing the waste material composition (the moisture content in the present case). The site delimitation was conducted with electromagnetic (in-phase and out-of-phase) and magnetic (vertical gradient and total field) methods that clearly showed the transition between the waste deposit and the host formation. Regarding waste deposit thickness evaluation, electrical resistivity tomography appeared inefficient on this particularly thick deposit site. Thus, we propose a combination of horizontal to vertical noise spectral ratio (HVNSR) and multichannel analysis of the surface waves (MASW), which successfully determined the approximate waste deposit thickness in our test landfill. However, ERT appeared to be an appropriate tool to characterize the moisture content of the waste, which is of prior information for the organic waste biodegradation process. The global multi-scale and multi-method geophysical survey offers precious information for site rehabilitation studies, water content mitigation processes for enhanced biodegradation or landfill mining operation planning.

  20. Analysis of the Carmel Valley alluvial ground-water basin, Monterey County, California

    Science.gov (United States)

    Kapple, Glenn W.; Mitten, Hugh T.; Durbin, Timothy J.; Johnson, Michael J.

    1984-01-01

    A two-dimensional, finite-element, digital model was developed for the Carmel Valley alluvial ground-water basin using measured, computed, and estimated discharge and recharge data for the basin. Discharge data included evapotranspiration by phreatophytes and agricultural, municipal, and domestic pumpage. Recharge data included river leakage, tributary runoff, and pumping return flow. Recharge from subsurface boundary flow and rainfall infiltration was assumed to be insignificant. From 1974 through 1978, the annual pumping rate ranged from 5,900 to 9,100 acre-feet per year with 55 percent allotted to municipal use principally exported out of the valley, 44 percent to agricultural use, and 1 percent to domestic use. The pumpage return flow within the valley ranged from 900 to 1,500 acre-feet per year. The aquifer properties of transmissivity (about 5,900 feet squared per day) and of the storage coefficient (0.19) were estimated from an average alluvial thickness of 75 feet and from less well-defined data on specific capacity and grain-size distribution. During calibration the values estimated for hydraulic conductivity and storage coefficient for the lower valley were reduced because of the smaller grain size there. The river characteristics were based on field and laboratory analyses of hydraulic conductivity and on altitude survey data. The model is intended principally for simulation of flow conditions using monthly time steps. Time variations in transmissivity and short-term, highrecharge potential are included in the model. The years 1974 through 1978 (including "pre-" and "post-" drought) were selected because of the extreme fluctuation in water levels between the low levels measured during dry years and the above-normal water levels measured during the preceding and following wet years. Also, during this time more hydrologic information was available. Significantly, computed water levels were generally within a few feet of the measured levels, and computed

  1. Deposition of titanium coating on SiC fiber by chemical vapor deposition with Ti-I{sub 2} system

    Energy Technology Data Exchange (ETDEWEB)

    Luo, Xian, E-mail: luo_shenfan@hotmail.com; Wu, Shuai; Yang, Yan-qing; Jin, Na; Liu, Shuai; Huang, Bin

    2017-06-01

    Highlights: • The transformation paths of (Ti + I{sub 2}) powder to Ti coating is: Ti + I{sub 2} → (TiI{sub 2}, TiI{sub 3}) → Ti. • Uniform coating was obtained on SiC fiber, but it contained Si and C elements. • Deposition rate of the coating increased with the increase of temperature. • Deposition thickness increased with time and achieved the maximum at 90 min. - Abstract: Titanium coating was prepared on SiC fiber using titanium-iodine (Ti-I{sub 2}) mixture by hot-wall chemical vapor deposition. Thermodynamic analysis and experimental observation were carried out in this work. The thermodynamic analysis of the reactions in the Ti-I{sub 2} system indicates that Ti and I{sub 2} raw powder materials transform to titanium coating as follows: Ti + I{sub 2} → (TiI{sub 2}, TiI{sub 3}), and (TiI{sub 2}, TiI{sub 3}) → Ti. In theory, the conversions of TiI{sub 3} and TiI{sub 2} reach the maximum when Ti:I{sub 2} is 1:1.5, while in actual experiment that reached the maximum when Ti:I{sub 2} was 1:2, as there existed the waste of I{sub 2} due to sublimation. Typical deposited coating is relatively flat and uniform. However, as SiC is prone to react with Ti at high temperatures, the obtained coating contained some Si and C elements except for Ti. So the coating was not a pure Ti coating but contained some carbides and silicides. Deposition rate of the coating increased with the increase of temperature. The deposited thickness increased with the increase of heat preservation time, and achieved the maximum thickness at 90 min.

  2. The ichthyofauna of limnic systems in Quaternary deposits of extreme southern Brazil

    Directory of Open Access Journals (Sweden)

    Cindy Marques

    2016-12-01

    Full Text Available The Quaternary in the state of Rio Grande do Sul (RS, southern Brazil, is geologically represented by the coastal plain and was originated by successive events of Pleistocene-Holocene marine transgressions and the occurrence of alluvial deposits. This paper aimed to characterize the fish assemblage occurring in a swampy Quaternary area adjacent to Lagoa Pequena, a lacustrine system connected to the west margin of the Laguna dos Patos estuary. A checklist is also provided of the ichthyofauna so far recorded in limnic systems of Quaternary deposits in the state of Rio Grande do Sul. A total of 42 species was recorded, distributed in nine orders, 18 families and 31 genera. Characidae and Cichlidae were the most representative families, comprising 15 and 4 species respectively. A bibliographic revision associated to our sample data revealed the occurrence of 156 species in limnic systems inserted in RS Quaternary deposits (114 limnic, 15 marine/estuarine/limnic, ten marine/estuarine, nine estuarine/limnic and eight marine. Characiformes and Siluriformes are the most diverse orders, corroborating the Neotropical pattern. Seven species can be considered endemic to RS Quaternary deposits.

  3. Magnetic properties of permalloy films with different thicknesses deposited onto obliquely sputtered Cu underlayers

    International Nuclear Information System (INIS)

    Li, Xiaoyu; Sun, Xiaojun; Wang, Jianbo; Liu, Qingfang

    2015-01-01

    In this work, the influence of obliquely sputtered Cu underlayer of 10 nm on the magnetic properties of normally sputtered Permalloy thin films with different thicknesses from 10 nm to 150 nm has been investigated. It has been found that the samples with the Permalloy layer thickness ranging from 10 nm to 70 nm exhibit a good in-plane uniaxial magnetic anisotropy, and the increase of the film thickness leads to a decrease of the anisotropy field and the natural resonance frequency. The critical Permalloy layer thickness for stripe domain initiation of these films is about 80 nm, which is thinner than that of obliquely sputtered Permalloy thin films without an underlayer. The characteristic shapes of hysteresis loops which can be called ''transcritical'' are observed above the critical thickness. The condition and mechanism of appearing stripe domain structure were discussed and it has been found that the frequency response of permeability of the anisotropic films shows the characteristics of multi-peak resonance. - Highlights: • Py films were fabricated on obliquely sputtered Cu underlayers by RF magnetron sputtering. • Effects of Py layer thickness on anisotropy, ferromagnetic resonance frequency have been studied. • Samples with Py layer (<70 nm) show a good in-plane uniaxial magnetic anisotropy. • Samples with Py layer (>80 nm) show stripe domains and multi-peaks in permeability spectra

  4. Stress anisotropy and stress gradient in magnetron sputtered films with different deposition geometries

    International Nuclear Information System (INIS)

    Zhao, Z.B.; Yalisove, S.M.; Bilello, J.C.

    2006-01-01

    Mo films were deposited via magnetron sputtering with two different deposition geometries: dynamic deposition (moving substrate) and static deposition (fixed substrate). The residual stress and structural morphologies of these films were investigated, with particular focus on in-plane anisotropy of the biaxial stress and stress gradient across the film thickness. The results revealed that the Mo films developed distinct states of residual stress, which depended on both deposition geometry and film thickness. With the dynamic geometry, the Mo films generally exhibited anisotropic stress. Both the degree of anisotropy and the magnitude of stress varied as functions of film thickness. The variation of stress was linked to the evolution of anisotropic microstructures in the films. The Mo films from the static geometry developed isotropic residual stress, which was more compressive and noticeably larger in magnitude than that of the Mo films from the dynamic geometry. Aside from these disparities, the two types of Mo films (i.e., anisotropic and isotropic) exhibited notably similar trends of stress variation with film thickness. Depth profiling indicated the presence of large stress gradients for the Mo films, irrespective of the deposition geometries. This observation seems to be consistent with the premise that Mo films develop a zone T structure, which is inherently inhomogeneous along the film thickness. Moreover, the largest stress gradient for both types of deposition geometries arises at roughly the same film depth (∼240 nm from substrate), where the stresses sharply transits from highly compressive to less compressive or even tensile. This appears to correspond to the boundary region that separates two distinct stages of microstructural evolution, a feature unique to zone T-type structure

  5. Effect of Different Catalyst Deposition Technique on Aligned Multiwalled Carbon Nanotubes Grown by Thermal Chemical Vapor Deposition

    Directory of Open Access Journals (Sweden)

    Mohamed Shuaib Mohamed Saheed

    2014-01-01

    Full Text Available The paper reported the investigation of the substrate preparation technique involving deposition of iron catalyst by electron beam evaporation and ferrocene vaporization in order to produce vertically aligned multiwalled carbon nanotubes array needed for fabrication of tailored devices. Prior to the growth at 700°C in ethylene, silicon dioxide coated silicon substrate was prepared by depositing alumina followed by iron using two different methods as described earlier. Characterization analysis revealed that aligned multiwalled carbon nanotubes array of 107.9 µm thickness grown by thermal chemical vapor deposition technique can only be achieved for the sample with iron deposited using ferrocene vaporization. The thick layer of partially oxidized iron film can prevent the deactivation of catalyst and thus is able to sustain the growth. It also increases the rate of permeation of the hydrocarbon gas into the catalyst particles and prevents agglomeration at the growth temperature. Combination of alumina-iron layer provides an efficient growth of high density multiwalled carbon nanotubes array with the steady growth rate of 3.6 µm per minute for the first 12 minutes and dropped by half after 40 minutes. Thicker and uniform iron catalyst film obtained from ferrocene vaporization is attributed to the multidirectional deposition of particles in the gaseous form.

  6. Realistic reflectance spectrum of thin films covering a transparent optically thick substrate

    Energy Technology Data Exchange (ETDEWEB)

    Cesaria, M., E-mail: maura.cesaria@le.infn.it; Caricato, A. P.; Martino, M. [Department of Mathematics and Physics “Ennio De Giorgi,” University of Salento, Via Arnesano, I-73100 Lecce (Italy)

    2014-07-21

    A spectrophotometric strategy is presented and discussed for calculating realistically the reflectance spectrum of an absorbing film deposited over a thick transparent or semi-transparent substrate. The developed route exploits simple mathematics, has wide range of applicability (high-to-weak absorption regions and thick-to-ultrathin films), rules out numerical and curve-fitting procedures as well as model-functions, inherently accounts for the non-measurable contribution of the film-substrate interface as well as substrate backside, and describes the film reflectance spectrum as determined by the experimental situation (deposition approach and parameters). The reliability of the method is tested on films of a well-known material (indium tin oxide) by deliberately changing film thickness and structural quality through doping. Results are found consistent with usual information yielded by reflectance, its inherent relationship with scattering processes and contributions to the measured total reflectance.

  7. Size dependent optical characteristics of chemically deposited

    Indian Academy of Sciences (India)

    Keywords. Thin film; ZnS; CBD method; optical properties. Abstract. ZnS thin films of different thicknesses were prepared by chemical bath deposition using thiourea and zinc acetate as S2- and Zn2+ source. The effect of film thickness on the optical and structural properties was studied. The optical absorption studies in the ...

  8. Use of morphometric analysis and self-organizing maps for alluvial fan classification: case study on Ostorankooh altitudes, Iran

    International Nuclear Information System (INIS)

    Mokarram, Marzieh; Seif, Abdollah; Sathyamoorthy, Dinesh

    2014-01-01

    The aim of this study is to classify alluvial fans formed by high-gradient braided streams and torrents that discharge into the Oshtorankook altitudes in the Lorestan province, Iran. The morphology of the fans and their watershed is quantitatively described through estimated morphometric parameters. For relationships between geomorphological features of the fans and their drainage basins, self-organizingmaps (SOM) were used. In SOM, according to both qualitative data and morphometric variables, the clustering tendency of alluvial fans was investigated using 15 alluvial fans parameters. The results of the analysis showed that several morphologically different fan types were recognizedbased on their geomorphological characteristics in the study area. A strong positive relationship was found between the drainage basin area and size of the fan with a simple power function. In addition, the relationship between fan slope and drainage area was found to be negative and moderately strong with a simple power function

  9. Optimization of Si–C reaction temperature and Ge thickness in C-mediated Ge dot formation

    Energy Technology Data Exchange (ETDEWEB)

    Satoh, Yuhki, E-mail: yu-ki@ecei.tohoku.ac.jp; Itoh, Yuhki; Kawashima, Tomoyuki; Washio, Katsuyoshi

    2016-03-01

    To form Ge dots on a Si substrate, the effect of thermal reaction temperature of sub-monolayer C with Si (100) was investigated and the deposited Ge thickness was optimized. The samples were prepared by solid-source molecular beam epitaxy with an electron-beam gun for C sublimation and a Knudsen cell for Ge evaporation. C of 0.25 ML was deposited on Si (100) at a substrate temperature of 200 °C, followed by a high-temperature treatment at the reaction temperature (T{sub R}) of 650–1000 °C to create Si–C bonds. Ge equivalent to 2 to 5 nm thick was subsequently deposited at 550 °C. Small and dense dots were obtained for T{sub R} = 750 °C but the dot density decreased and the dot diameter varied widely in the case of lower and higher T{sub R}. A dot density of about 2 × 10{sup 10} cm{sup −2} was achieved for Ge deposition equivalent to 3 to 5 nm thick and a standard deviation of dot diameter was the lowest of 10 nm for 5 nm thick Ge. These results mean that C-mediated Ge dot formation was strongly influenced not only by the c(4 × 4) reconstruction condition through the Si–C reaction but also the relationship between the Ge deposition thickness and the exposed Si (100)-(2 × 1) surface area. - Highlights: • The effect of Si–C reaction temperature on Ge dot formation was investigated. • Small and dense dots were obtained for T{sub R} = 750 °C. • The dot density of about 2 × 10{sup 10} cm{sup −2} was achieved for Ge = 3 to 5 nm. • The standard deviation of dot diameter was the lowest of 10 nm at Ge = 5 nm.

  10. Deposition and Characterization of HVOF Thermal Sprayed Functionally Graded Coatings Deposited onto a Lightweight Material

    Science.gov (United States)

    Hasan, M.; Stokes, J.; Looney, L.; Hashmi, M. S. J.

    2009-02-01

    There is a significant interest in lightweight materials (like aluminum, magnesium, titanium, and so on) containing a wear resistance coating, in such industries as the automotive industry, to replace heavy components with lighter parts in order to decrease vehicle weight and increase fuel efficiency. Functionally graded coatings, in which the composition, microstructure, and/or properties vary gradually from the bond coat to the top coat, may be applied to lightweight materials, not only to decrease weight, but also to enhance components mechanical properties by ensuring gradual microstructural (changes) together with lower residual stress. In the current work, aluminum/tool-steel functionally graded coatings were deposited onto lightweight aluminum substrates. The graded coatings were then characterized in terms of residual stress and hardness. Results show that residual stress increased with an increase in deposition thickness and a decrease in number of layers. However, the hardness also increased with an increase in deposition thickness and decrease in number of layers. Therefore, an engineer must compromise between the hardness and stress values while designing a functionally graded coating-substrate system.

  11. Using Lead Concentrations and Stable Lead Isotope Ratios to Identify Contamination Events in Alluvial Soils

    International Nuclear Information System (INIS)

    Saint-Laurent, D.; St-Laurent, J.; Hahni, M.; Chapados, C.; Ghaleb, B.

    2010-01-01

    Soils contaminated with hydrocarbons (C10,C50), polycyclic aromatic hydrocarbons (PAHs), and other contaminants (e.g., As, Cd, Cu, Pb) were recently discovered on the banks of the Saint-Francois and Massawippi rivers. Alluvial soils are contaminated over a distance of 100 kilometers, and the level of the contaminated-hydrocarbon layer in the soil profiles is among the highest at the Windsor and Richmond sites. Concentrations of lead and stable lead isotope ratios ( 204 Pb/ 206 Pb, 206 Pb/ 207 Pb, 208 Pb/ 20 '6Pb) are also used to identify contamination events. The maximum and minimum values detected in soil profiles for arsenic, cadmium, and lead vary from 3.01 to 37.88?mg kg -1 (As), 0.11 to 0.81?mg kg-1 (Cd) 12.32 to 149.13?mg kg -1 (Pb), respectively, while the 207 Pb/ 206 Pb isotopic ratio values are between 0.8545 and 0.8724 for all the profiles. The highest values of trace elements (As, Pb and Zn) were detected in the hydrocarbon layer (C10,C50), most often located at the bottom of the profiles (160, 200, and 220 cm in depth). The various peaks recorded in the soils and the position of the profiles suggest that various contaminants were transported by the river on several occasions and infiltrated the soil matrix or deposited on flood plains during successive floods. Atmospheric particles which entered the river or deposited on riverbanks must also be considered as another source of pollution recorded in soils

  12. Using Lead Concentrations and Stable Lead Isotope Ratios to Identify Contamination Events in Alluvial Soils

    Directory of Open Access Journals (Sweden)

    Diane Saint-Laurent

    2010-01-01

    Full Text Available Soils contaminated with hydrocarbons (C10–C50, polycyclic aromatic hydrocarbons (PAHs, and other contaminants (e.g., As, Cd, Cu, Pb were recently discovered on the banks of the Saint-François and Massawippi rivers. Alluvial soils are contaminated over a distance of 100 kilometers, and the level of the contaminated-hydrocarbon layer in the soil profiles is among the highest at the Windsor and Richmond sites. Concentrations of lead and stable lead isotope ratios (204Pb/206Pb, 207Pb/206Pb, 208Pb/206Pb are also used to identify contamination events. The maximum and minimum values detected in soil profiles for arsenic, cadmium, and lead vary from 3.01 to 37.88 mg kg-1 (As, 0.11 to 0.81 mg kg-1 (Cd 12.32 to 149.13 mg kg-1 (Pb, respectively, while the 207Pb/206Pb isotopic ratio values are between 0.8545 and 0.8724 for all the profiles. The highest values of trace elements (As, Pb and Zn were detected in the hydrocarbon layer (C10–C50, most often located at the bottom of the profiles (160, 200, and 220 cm in depth. The various peaks recorded in the soils and the position of the profiles suggest that various contaminants were transported by the river on several occasions and infiltrated the soil matrix or deposited on floodplains during successive floods. Atmospheric particles which entered the river or deposited on riverbanks must also be considered as another source of pollution recorded in soils.

  13. Origin, Extent, and Thickness of Quaternary Geologic Units in the Willamette Valley, Oregon

    Science.gov (United States)

    O'Connor, Jim E.; Sarna-Wojcicki, Andrei M.; Wozniak, Karl C.; Polette, Danial J.; Fleck, Robert J.

    2001-01-01

    Stratigraphic and chronologic information collected for Quaternary deposits in the Willamette Valley, Oregon, provides a revised stratigraphic framework that serves as a basis for a 1:250,000-scale map, as well as for thickness estimates of widespread Quaternary geologic units. We have mapped 11 separate Quaternary units that are differentiated on the basis of stratigraphic, topographic, pedogenic, and hydrogeologic properties. In summation, these units reflect four distinct episodes in the Quaternary geologic development of the Willamette Valley: 1) Fluvial sands and gravels that underlie terraces flanking lowland margins and tributary valleys were probably deposited between 2.5 and 0.5 million years ago. They are the oldest widespread surficial Quaternary deposits in the valley. Their present positions and preservation are undoubtedly due to postdepositional tectonic deformation - either by direct tectonic uplift of valley margins, or by regional tectonic controls on local base level. 2) Tertiary and Quaternary excavation or tectonic lowering of the Willamette Valley accommodated as much as 500 m (meters) of lacustrine and fluvial fill. Beneath the lowland floor, much of the upper 10 to 50 m of fill is Quaternary sand and gravel deposited by braided channel systems in subhorizontal sheets 2 to 10 m thick. These deposits grade to gravel fans 40 to 100 m thick where major Cascade Range rivers enter the valley and are traced farther upstream as much thinner valley trains of coarse gravel. The sand and gravel deposits have ages that range from greater than 420,000 to about 12,000 years old. A widely distributed layer of sand and gravel deposited at about 12 ka (kiloannum, thousands of years before the present) is looser and probably more permeable than older sand and gravel. Stratigraphic exposures and drillers' logs indicate that this late Pleistocene unit is mostly between 5 and 20 m thick where it has not been subsequently eroded by the Willamette River and its

  14. Electrospark deposition for die repair

    Directory of Open Access Journals (Sweden)

    J. Tušek

    2012-01-01

    Full Text Available The electrospark deposition is a process for surfacing of hard metal alloys, e.g. carbides and stellites, on the surfaces of new or old machine elements. In this process, a high current is conducted through an oscillating electrode and a substrate for a very short period of time. In the paper, the process is described and the thickness of deposited layer, chemical composition, dilution rate and the layer roughness are determined.

  15. Geology and recognition criteria for uraniferous humate deposits, Grants Uranium Region, New Mexico. Final report

    International Nuclear Information System (INIS)

    Adams, S.S.; Saucier, A.E.

    1981-01-01

    The geology of the uraniferous humate uranium deposits of the Grants Uranium Region, northwestern New Mexico, is summarized. The most important conclusions of this study are enumerated. Although the geologic characteristics of the uraniferous humate deposits of the Grants Uranium Region are obviously not common in the world, neither are they bizarre or coincidental. The source of the uranium in the deposits of the Grants Uranium Region is not known with certainty. The depositional environment of the host sediments was apparently the mid and distal portions of a wet alluvial fan system. The influence of structural control on the location and accumulation of the host sediments is now supported by considerable data. The host sediments possess numerous important characteristics which influenced the formation of uraniferous humate deposits. Ilmenite-magnetite distribution within potential host sandstones is believed to be the simplest and most useful regional alteration pattern related to this type of uranium deposit. A method is presented for organizing geologic observations into what is referred to as recognition criteria. The potential of the United States for new districts similar to the Grants Uranium Region is judged to be low based upon presently available geologic information. Continuing studies on uraniferous humate deposits are desirable in three particular areas

  16. Tuning the mechanical properties of vertical graphene sheets through atomic layer deposition

    International Nuclear Information System (INIS)

    Davami, Keivan; Jiang, Yijie; Cortes, John; Lin, Chen; Turner, Kevin T; Bargatin, Igor; Shaygan, Mehrdad

    2016-01-01

    We report the fabrication and characterization of graphene nanostructures with mechanical properties that are tuned by conformal deposition of alumina. Vertical graphene (VG) sheets, also called carbon nanowalls (CNWs), were grown on copper foil substrates using a radio-frequency plasma-enhanced chemical vapor deposition (RF-PECVD) technique and conformally coated with different thicknesses of alumina (Al_2O_3) using atomic layer deposition (ALD). Nanoindentation was used to characterize the mechanical properties of pristine and alumina-coated VG sheets. Results show a significant increase in the effective Young’s modulus of the VG sheets with increasing thickness of deposited alumina. Deposition of only a 5 nm thick alumina layer on the VG sheets nearly triples the effective Young’s modulus of the VG structures. Both energy absorption and strain recovery were lower in VG sheets coated with alumina than in pure VG sheets (for the same peak force). This may be attributed to the increase in bending stiffness of the VG sheets and the creation of connections between the sheets after ALD deposition. These results demonstrate that the mechanical properties of VG sheets can be tuned over a wide range through conformal atomic layer deposition, facilitating the use of VG sheets in applications where specific mechanical properties are needed. (paper)

  17. The spatial thickness distribution of metal films produced by large area pulsed laser deposition

    DEFF Research Database (Denmark)

    Pryds, Nini; Schou, Jørgen; Linderoth, Søren

    2007-01-01

    Thin films of metals have been deposited in the large-area Pulsed Laser Deposition (PLD) Facility at Riso National Laboratory. Thin films of Ag and Ni were deposited with laser pulses from an excimer laser at 248 nm with a rectangular beam spot at a fluence of 10 J/cm(2) on glass substrates of 127...

  18. The NSLS-II Multilayer Laue Lens Deposition System

    International Nuclear Information System (INIS)

    Conley, R.; Bouet, N.; Biancarosa, J.; Shen, Q.; Boas, L.; Feraca, J.; Rosenbaum, L.

    2009-01-01

    The NSLS-II(1) program has a requirement for an unprecedented level of x-ray nanofocusing and has selected the wedged multilayer Laue lens(2,3) (MLL) as the optic of choice to meet this goal. In order to fabricate the MLL a deposition system is required that is capable of depositing depth-graded and laterally-graded multilayers with precise thickness control over many thousands of layers, with total film growth in one run up to 100 m thick or greater. This machine design expounds on the positive features of a rotary deposition system(4) constructed previously for MLLs and will contain multiple stationary, horizontally-oriented magnetron sources where a transport will move a substrate back and forth in a linear fashion over shaped apertures at well-defined velocities to affect a multilayer coating.

  19. Sputter deposition system for controlled fabrication of multilayers

    International Nuclear Information System (INIS)

    Di Nardo, R.P.; Takacs, P.Z.; Majkrzak, C.F.; Stefan, P.M.

    1985-06-01

    A detailed description of a sputter deposition system constructed specifically for the fabrication of x-ray and neutron multilayer monochromators and supermirrors is given. One of the principal design criteria is to maintain precise control of film thickness and uniformity over large substrate areas. Regulation of critical system parameters is fully automated so that response to feedback control information is rapid and complicated layer thickness sequences can be deposited accurately and efficiently. The use of either dc or rf magnetron sources makes it possible to satisfy the diverse material requirements of both x-ray and neutron optics

  20. Bacterial biomass and DNA diversity in an alluvial meadow soil upon long-term fertilization

    NARCIS (Netherlands)

    Naumova, N.B.; Kuikman, P.J.

    2001-01-01

    The denaturing gradient gel-electrophoresis of bacterial DNA fragments and the assessment of bacterial biomass revealed changes in the diversity of the bacterial community in a meadow alluvial soil upon long-term fertilization.

  1. Properties of electrophoretically deposited single wall carbon nanotube films

    International Nuclear Information System (INIS)

    Lim, Junyoung; Jalali, Maryam; Campbell, Stephen A.

    2015-01-01

    This paper describes techniques for rapidly producing a carbon nanotube thin film by electrophoretic deposition at room temperature and determines the film mass density and electrical/mechanical properties of such films. The mechanism of electrophoretic deposition of thin layers is explained with experimental data. Also, film thickness is measured as a function of time, electrical field and suspension concentration. We use Rutherford backscattering spectroscopy to determine the film mass density. Films created in this manner have a resistivity of 2.14 × 10 −3 Ω·cm, a mass density that varies with thickness from 0.12 to 0.54 g/cm 3 , and a Young's modulus between 4.72 and 5.67 GPa. The latter was found to be independent of thickness from 77 to 134 nm. We also report on fabricating free-standing films by removing the metal seed layer under the CNT film, and selectively etching a sacrificial layer. This method could be extended to flexible photovoltaic devices or high frequency RF MEMS devices. - Highlights: • We explain the electrophoretic deposition process and mechanism of thin SWCNT film deposition. • Characterization of the SWCNT film properties including density, resistivity, transmittance, and Young's modulus. • The film density and resistivity are found to be a function of the film thickness. • Techniques developed to create free standing layers of SW-CNTs for flexible electronics and mechanical actuators

  2. Mining of sedimentary-type ore deposits

    International Nuclear Information System (INIS)

    Bruha, J.; Slovacek, T.; Berka, J.; Sadilek, P.

    1992-01-01

    A procedure is proposed for mining sedimentary-type ore deposits, particularly uranium deposits, using the stope-pillar technique. The stope having been mined out, the free room is filled with hydro-setting gob from the surface. A precondition for the application of this technique is horizontal ore mineralization in sediments where the total thickness of the mineralized ore layer is at least 3 to 5 m. Mining losses do not exceed 5%. For thicknesses greater than 5 m, the roof is reinforced and the walls are secured with netting. The assets of the technique include higher labor productivity of the driving, lower material demands in reinforcing and filling, lower power consumption, and reduced use of explosives. (Z.S.). 3 figs

  3. Optimum thickness evaluation of ZrO2 coating on type 304L stainless steel for corrosion protection

    International Nuclear Information System (INIS)

    Garg, Nidhi; Bera, Santanu; Velmurugan, S.; Tripathi, V.S.; Karki, Vijay

    2015-01-01

    Nano-crystalline ZrO 2 coatings of different thickness have been grown on pre-oxidized stainless steel (SS) surface by hydrothermal method in an autoclave. Thickness of the coating has been enhanced by repeating the deposition process several times using same precursor concentration. Several cycles of the deposition process lead to the increase of the coating thickness from 200 nm to ∼1 μm after the fourth round of deposition. The samples after different rounds of the coating have been extensively characterized by SEM-EDS technique to find the surface topography, coating thickness and composition. Corrosion resistance properties of the plain SS, pre-oxidized SS and all the ZrO 2 coated samples were studied by potentiodynamic polarization technique and electrochemical impedance spectroscopy (EIS). Corrosion current densities (I corr /cm 2 ) of the coated samples are found to reduce significantly with the increase in thickness. After a certain critical thickness, the corrosion resistance properties found to deteriorate due to the formation of coating defects caused by lattice strain. The coating was found to be continuous but porous after the first cycle but porosity of zirconia coating have been reduced drastically after the second cycle itself. EIS analysis confirms that the zirconia coated samples show insulating, barrier like characteristics in terms of high charge transfer resistance after the second cycle of zirconia deposition. The role of pre-oxidized surface composition and the interface between the pre-oxidized surface and the coating has been discussed in details by showing the depth distribution of Zr in the coating. (author)

  4. Nano-crystalline thin and nano-particulate thick TiO{sub 2} layer: Cost effective sequential deposition and study on dye sensitized solar cell characteristics

    Energy Technology Data Exchange (ETDEWEB)

    Das, P.; Sengupta, D. [Centre for Advanced Materials Processing, CSIR-Central Mechanical Engineering Research Institute, Durgapur, 713209 West Bengal (India); CSIR-Central Mechanical Engineering Research Institute, Academy of Scientific and Innovative Research (AcSIR), Durgapur, 713209 West Bengal (India); Kasinadhuni, U. [Department of Engineering Physics, Bengal College of Engineering and Technology, Durgapur, West Bengal (India); Mondal, B. [Centre for Advanced Materials Processing, CSIR-Central Mechanical Engineering Research Institute, Durgapur, 713209 West Bengal (India); Mukherjee, K., E-mail: kalisadhanm@yahoo.com [Centre for Advanced Materials Processing, CSIR-Central Mechanical Engineering Research Institute, Durgapur, 713209 West Bengal (India)

    2015-06-15

    Highlights: • Thin TiO{sub 2} layer is deposited on conducting substrate using sol–gel based dip coating. • TiO{sub 2} nano-particles are synthesized using hydrothermal route. • Thick TiO{sub 2} particulate layer is deposited on prepared thin layer. • Dye sensitized solar cells are made using thin and thick layer based photo-anode. • Introduction of thin layer in particulate photo-anode improves the cell efficiency. - Abstract: A compact thin TiO{sub 2} passivation layer is introduced between the mesoporous TiO{sub 2} nano-particulate layer and the conducting glass substrate to prepare photo-anode for dye-sensitized solar cell (DSSC). In order to understand the effect of passivation layer, other two DSSCs are also developed separately using TiO{sub 2} nano-particulate and compact thin film based photo-anodes. Nano-particles are prepared using hydrothermal synthesis route and the compact passivation layer is prepared by simply dip coating the precursor sol prepared through wet chemical route. The TiO{sub 2} compact layer and the nano-particles are characterised in terms of their micro-structural features and phase formation behavior. It is found that introduction of a compact TiO{sub 2} layer in between the mesoporous TiO{sub 2} nano-particulate layer and the conducting substrate improves the solar to electric conversion efficiency of the fabricated cell. The dense thin passivation layer is supposed to enhance the photo-excited electron transfer and prevent the recombination of photo-excited electrons.

  5. Influence of geologic structure on alluvial sedimentation in northwestern Yucca Flat, Nye County, Nevada

    International Nuclear Information System (INIS)

    Wagoner, J.L.

    1983-01-01

    Using downhole photography, alluvial sediments are described in 5 emplacement holes in northwestern Yucca Flat. The holes are located on or near the Grouse Canyon fan. The 3 most proximally located holes contain the coarsest sediments and display a general decrease in grain size in the downfan direction. The 2 most distally located holes contain fine-grained distal facies sediment in the upper parts of the holes and coarse-grained proximal facies gravels lower in the holes. The proximal gravels in the lower half of the sections were derived from the gravity high, a north-south-trending horst which was exposed early during the history of Yucca Flat basin. Alluvial sedimentation eventually exceeded uplift of the horst, which was buried by distal facies sediments, derived from the western basin margin

  6. Characteristics of electroplated Ni thick film on the PN junction semiconductor for beta-voltaic battery

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jin Joo; Uhm, Young Rang; Park, Keun Young; Son, Kwang Jae [Radioisotope Research Division, Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2014-12-15

    Nickel (Ni) electroplating was implemented by using a metal Ni powder in order to establish a {sup 63}Ni plating condition on the PN junction semiconductor needed for production of betavoltaic battery. PN junction semiconductors with a Ni seed layer of 500 and 1000 Å were coated with Ni at current density from 10 to 50 mA cm{sup -2}. The surface roughness and average grain size of Ni deposits were investigated by XRD and SEM techniques. The roughness of Ni deposit was increased as the current density was increased, and decreased as the thickness of Ni seed layer was increased. The results showed that the optimum surface shape was obtained at a current density of 10 mA cm{sup -2} in seed layer with thickness of 500 Å, 20 mA cm{sup -2} of 1000 Å. Also, pure Ni deposit was well coated on a PN junction semiconductor without any oxide forms. Using the line width of (111) in XRD peak, the average grain size of the Ni thick firm was measured. The results showed that the average grain size was increased as the thickness of seed layer was increased.

  7. Characteristics of electroplated Ni thick film on the PN junction semiconductor for beta-voltaic battery

    International Nuclear Information System (INIS)

    Kim, Jin Joo; Uhm, Young Rang; Park, Keun Young; Son, Kwang Jae

    2014-01-01

    Nickel (Ni) electroplating was implemented by using a metal Ni powder in order to establish a 63 Ni plating condition on the PN junction semiconductor needed for production of betavoltaic battery. PN junction semiconductors with a Ni seed layer of 500 and 1000 Å were coated with Ni at current density from 10 to 50 mA cm -2 . The surface roughness and average grain size of Ni deposits were investigated by XRD and SEM techniques. The roughness of Ni deposit was increased as the current density was increased, and decreased as the thickness of Ni seed layer was increased. The results showed that the optimum surface shape was obtained at a current density of 10 mA cm -2 in seed layer with thickness of 500 Å, 20 mA cm -2 of 1000 Å. Also, pure Ni deposit was well coated on a PN junction semiconductor without any oxide forms. Using the line width of (111) in XRD peak, the average grain size of the Ni thick firm was measured. The results showed that the average grain size was increased as the thickness of seed layer was increased

  8. Biostratigraphy and biofacies of the Devonian deposits of the Kuh-e-Shorab section (southwest Damghan based on conodont fauna

    Directory of Open Access Journals (Sweden)

    Mehdi Hoveida

    2016-09-01

    Full Text Available The studied section located in the Djam-Semnan area 55 kms south west Damghan, at the vicinity of the Amrovan rail way station, in the northern flank of Shorab unassymetric anticline. The section is 440 meters thick, including limestone, dolomitic limestone and sandstone with rich fossils contents (e.g.: trilobite, coral, brachiopod, crinoid segments and vertebrate remains. The lower boundary is covered with the recent alluvial and the upper boundary disconformably overlain by the red marls and sandstones of the Permian Dorud formation. In order to determine biostratigraphy and bifacies of the deposits of Bahram formation in Shorab section, twenty five samples (4-6 kgs were collected and processed with conventional actic/formic acid. Nineteen samples were prolific and totally yielded 340 conodont elements. The extracted conodont elements mainly separated out of the carbonate units. Thirty-one species belong to four genera (Polygnathus, Icriodus, Pelecysgnathus and Ancyrodella were discriminated as: Icriodus excavatus, I. expansus, I. cedarensis, I. subterminus, I. iowaensis, I. alternatus, I. tafilaltensis, I. brevis, I. cf. expansus, I. sp., Polygnathus brevilaminus, Poly. angustidiscus, Poly. pollocki, Poly. cf. webbi, Poly. aspelundi, Poly. politus, Poly. alatus, Poly. webbi, Poly. cf. olgae, Poly. dubius, Poly. xylus, Poly. zinaidae, Poly. sp., Pelekeygnathus inclinathus, Pele. serradentatus, Pele. sp., Ancyrodella pristina, Acny. cf. pristina, Ancy. aff. binodosa, Ancy. sp. Based on the frequency and distribution of the collected elements Late Givetian to Early Famennian age were suggested to the studied interval. Conodonts biofacies (icriodid-polygnathid confirm the deposition of the Bahram formation of the Shorab section in the shallow carbonate condition.

  9. Synthesis of LSM films deposited by dip-coating on YSZ substrate

    International Nuclear Information System (INIS)

    Conceicao, Leandro da; Souza, Mariana M.V.M.; Ribeiro, Nielson F.P.

    2010-01-01

    The dip-coating process was used to deposit films of La 0.7 Sr 0. 3MnO 3 (LSM) used as cathode in solid oxide fuel cells (SOFC). In this study we evaluated the relationship between the deposition parameters such as speed of withdrawal and number of deposited layers of LSM film on a substrate of 8% YSZ commercial, and structural properties, such as thickness and formation of cracks. The structure and morphology of the films were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). With parameters set the film had good adhesion to the substrate with a thickness around 10 μm, showing possible adherence problems when more than one layer is deposited on the substrate. (author)

  10. Resputtering effect during MgO buffer layer deposition by magnetron sputtering for superconducting coated conductors

    Energy Technology Data Exchange (ETDEWEB)

    Xiao, Shaozhu; Shi, Kai; Deng, Shutong; Han, Zhenghe [Applied Superconductivity Research Center, Department of Physics, Tsinghua University, Beijing 100084 (China); Feng, Feng, E-mail: feng.feng@sz.tsinghua.edu.cn; Lu, Hongyuan [Division of Advanced Manufacturing, Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055 (China); Qu, Timing; Zhu, Yuping [Department of Mechanical Engineering, Tsinghua University, Beijing 100084 (China); Huang, Rongxia [School of Electromechanical Engineering, Guangdong University of Technology, Guangzhou 510006 (China)

    2015-07-15

    In this study, MgO thin films were deposited by radio-frequency magnetron sputtering. The film thickness in the deposition area directly facing the target center obviously decreased compared with that in other areas. This reduction in thickness could be attributed to the resputtering effect resulting from bombardment by energetic particles mainly comprising oxygen atoms and negative oxygen ions. The influences of deposition position and sputtering pressure on the deposition rate were investigated. Resputtering altered the orientation of the MgO film from (111) to (001) when the film was deposited on a single crystal yttria-stabilized zirconia substrate. The density distribution of energetic particles was calculated on the basis of the measured thicknesses of the MgO films deposited at different positions. The divergence angle of the energetic particle flux was estimated to be approximately 15°. The energetic particle flux might be similar to the assisting ion flux in the ion beam assisted deposition process and could affect the orientation of the MgO film growth.

  11. Method for deposition of a conductor in integrated circuits

    Science.gov (United States)

    Creighton, J. Randall; Dominguez, Frank; Johnson, A. Wayne; Omstead, Thomas R.

    1997-01-01

    A method is described for fabricating integrated semiconductor circuits and, more particularly, for the selective deposition of a conductor onto a substrate employing a chemical vapor deposition process. By way of example, tungsten can be selectively deposited onto a silicon substrate. At the onset of loss of selectivity of deposition of tungsten onto the silicon substrate, the deposition process is interrupted and unwanted tungsten which has deposited on a mask layer with the silicon substrate can be removed employing a halogen etchant. Thereafter, a plurality of deposition/etch back cycles can be carried out to achieve a predetermined thickness of tungsten.

  12. Diamond-like carbon films deposited on polycarbonates by plasma-enhanced chemical vapor deposition

    Energy Technology Data Exchange (ETDEWEB)

    Guo, C.T. [Department of Computer and Communication, Diwan College of Management, 72141 Taiwan (China)], E-mail: ctguo@dwu.edu.tw

    2008-04-30

    Diamond-like carbon films were coated on optical polycarbonate using plasma-enhanced chemical vapor deposition. A mixture of SiH{sub 4} and CH{sub 4}/H{sub 2} gases was utilized to reduce the internal compressive stress of the deposited films. The structure of the DLC films was characterized as a function of film thickness using Raman spectroscopy. The dependence of G peak positions and the intensity ratio of I{sub D}/I{sub G} on the DLC film thicknesses was analyzed in detail. Other studies involving atomic force microscopy, ultraviolet visible spectrometry, and three adhesion tests were conducted. Good transparency in the visible region, and good adhesion between diamond-like carbon films and polycarbonate were demonstrated. One-time recordings before and after a DLC film was coated on compact rewritable disc substrates were analyzed as a case study. The results reveal that the diamond-like carbon film overcoating the optical polycarbonates effectively protects the storage media.

  13. Cracking and delamination of vapor-deposited tantalum films

    International Nuclear Information System (INIS)

    Fisher, R.M.; Duan, J.Z.; Liu, J.B.

    1990-01-01

    This paper reports on tantalum films which begin to crack and spall during vapor deposition on glass at a thickness of 180 nm. Islands and ribbons, 10 - 30 μm in size, delaminate by crack growth along the Ta/glass interface for several μm after which the crack penetrates into the glass to a depth of 0.5 - 1 μm and complete spalling occurs. X-ray diffraction showed that about 50% of the original bct, β-tantalum, phase had transformed to the bcc α-Ta phase. When Ta was deposited on glass that was first covered with 52 nm of copper, spalling was observed to begin at a thickness of 105 nm. In this case, the film first cracks and then peels along the Cu/glass interface and curls into scrolls indicating the presence of a small stress gradient. X-ray diffraction of the as-deposited film, and electron diffraction of ion-milled flakes, showed that the Ta films deposited on Cu-coated glass almost completely transform to bcc α-Ta. The critical thickness for delamination along the Cu/glass interface is about 1/2 that for cracking in the glass substrate when an intermediate layer of Cu is not present. All of the above findings are in good agreement with previous observations on Cr films

  14. Sedimentological analysis and bed thickness statistics from a Carboniferous deep-water channel-levee complex: Myall Trough, SE Australia

    Science.gov (United States)

    Palozzi, Jason; Pantopoulos, George; Maravelis, Angelos G.; Nordsvan, Adam; Zelilidis, Avraam

    2018-02-01

    This investigation presents an outcrop-based integrated study of internal division analysis and statistical treatment of turbidite bed thickness applied to a Carboniferous deep-water channel-levee complex in the Myall Trough, southeast Australia. Turbidite beds of the studied succession are characterized by a range of sedimentary structures grouped into two main associations, a thick-bedded and a thin-bedded one, that reflect channel-fill and overbank/levee deposits, respectively. Three vertically stacked channel-levee cycles have been identified. Results of statistical analysis of bed thickness, grain-size and internal division patterns applied on the studied channel-levee succession, indicate that turbidite bed thickness data seem to be well characterized by a bimodal lognormal distribution, which is possibly reflecting the difference between deposition from lower-density flows (in a levee/overbank setting) and very high-density flows (in a channel fill setting). Power law and exponential distributions were observed to hold only for the thick-bedded parts of the succession and cannot characterize the whole bed thickness range of the studied sediments. The succession also exhibits non-random clustering of bed thickness and grain-size measurements. The studied sediments are also characterized by the presence of statistically detected fining-upward sandstone packets. A novel quantitative approach (change-point analysis) is proposed for the detection of those packets. Markov permutation statistics also revealed the existence of order in the alternation of internal divisions in the succession expressed by an optimal internal division cycle reflecting two main types of gravity flow events deposited within both thick-bedded conglomeratic and thin-bedded sandstone associations. The analytical methods presented in this study can be used as additional tools for quantitative analysis and recognition of depositional environments in hydrocarbon-bearing research of ancient

  15. Preliminary study of favorability for uranium of the Sangre de Cristo Formation in the Las Vegas basin, northeastern New Mexico

    International Nuclear Information System (INIS)

    May, R.T.; Strand, J.R.; Reid, B.E.; Phillips, W.R.

    1977-12-01

    Uranium favorability of the Sangre de Cristo Formation (Pennsylvanian-Permian) in the Las Vegas basin has been evaluated. The Las Vegas basin project area, located in Colfax, Mora, and San Miguel Counties, New Mexico, comprises about 3,489 sq mi. The formation contains sedimentologic and stratigraphic characteristics that are considered favorable for uranium deposition. Field investigations consisted of section measuring, rock sampling, and ground radiometric reconnaissance. North-south and east-west cross sections of the basin were prepared from well logs and measured sections. Petrographic, chemical, and spectrographic analyses were conducted on selected samples. Stratigraphic and sedimentologic information were used to determine depositional environments. The most favorable potential host rocks include red to pink, coarse-grained, poorly sorted, feldspathic to arkosic lenticular sandstones with stacked sandstone thicknesses of more than 20 ft and sandstone-to-shale ratios between 1:1 and 2:1. The sandstone is interbedded with mudstone and contains carbonaceous debris and anomalous concentrations of uranium locally. Areas of maximum favorability are found in a braided-stream, alluvial-plain depositional environment in the north-central part of the Las Vegas basin. There, carbonaceous material is well preserved, probably due to rapid subsidence and burial. Furthermore, uranium favorability is highest in the lower half of the formation because carbonaceous wood and plant fragments, as well as known uranium deposits, are concentrated in this zone. Piedmont deposits in the north and east, and meander-belt, alluvial-plain deposits in the south, are not considered favorable because of the paucity of uranium deposits and a minimum of carbonaceous material

  16. Contrasting morphodynamics in alluvial fans and fan deltas: effect of the downstream boundary

    NARCIS (Netherlands)

    Dijk, M. van; Kleinhans, M.G.; Postma, G.; Kraal, E.

    2012-01-01

    Alluvial fans and fan deltas can, in principle, have exactly the same upstream conditions, but fan deltas by definition have ponding water at their downstream boundary. This ponding creates effects on the autogenic behaviour of fan deltas, such as backwater adaptation, mouth bars and backward

  17. Mechanical Properties of Additively Manufactured Thick Honeycombs

    Directory of Open Access Journals (Sweden)

    Reza Hedayati

    2016-07-01

    Full Text Available Honeycombs resemble the structure of a number of natural and biological materials such as cancellous bone, wood, and cork. Thick honeycomb could be also used for energy absorption applications. Moreover, studying the mechanical behavior of honeycombs under in-plane loading could help understanding the mechanical behavior of more complex 3D tessellated structures such as porous biomaterials. In this paper, we study the mechanical behavior of thick honeycombs made using additive manufacturing techniques that allow for fabrication of honeycombs with arbitrary and precisely controlled thickness. Thick honeycombs with different wall thicknesses were produced from polylactic acid (PLA using fused deposition modelling, i.e., an additive manufacturing technique. The samples were mechanically tested in-plane under compression to determine their mechanical properties. We also obtained exact analytical solutions for the stiffness matrix of thick hexagonal honeycombs using both Euler-Bernoulli and Timoshenko beam theories. The stiffness matrix was then used to derive analytical relationships that describe the elastic modulus, yield stress, and Poisson’s ratio of thick honeycombs. Finite element models were also built for computational analysis of the mechanical behavior of thick honeycombs under compression. The mechanical properties obtained using our analytical relationships were compared with experimental observations and computational results as well as with analytical solutions available in the literature. It was found that the analytical solutions presented here are in good agreement with experimental and computational results even for very thick honeycombs, whereas the analytical solutions available in the literature show a large deviation from experimental observation, computational results, and our analytical solutions.

  18. Interactions between fauna and environment in recent alluvial soils (Dunajec River, SE Poland)

    Science.gov (United States)

    Mikuś, Paweł; Uchman, Alfred

    2017-04-01

    Recent riverine system is a particular place for interactions between fauna and the deposited sediments containing young and old alluvial soils. It is characterized by large energy gradients in relatively short time, which forces special adaptations of burrowing animals recorded in bioturbation structures. Predators produce mainly shelter burrows (interpreted as domichnia), and saprofags, especially earthworms, produce locomotion and feeding structures (pascichnia). Such structures have been studied in non- or poorly vegetated, sandy or muddy Holocene alluvia in the lower reach of the Dunajec River flowing through the Carpathian Foredeep in SE Poland. The observed burrows are mostly produced by a variety of organisms, including the European mole (Talpa europaea), common earthworm (Lumbricus terrestris), ground beetles (Carabidae), solitary bees (Ammophila), red fox (Vulpes vulpes), European beaver (Castor fiber), shrews (Soricidae), European otter (Lutra lutra), several species of mice (Muridae), voles (Myodae, Microtae), and the swallow sand martin (Riparia riparia). Burrows of a few species of ground beetles have been subjected to more detailed studies. Fertile deposits of older (early to middle Holocene) terraces, formed with many long-term interruptions in sedimentation processes, have a well-developed soil levels, more vulnerable to burrowing than recently deposited sediments. The terraces contain layers of sands and muds, which primary sedimentary structures and layer boundaries are completely or partly disturbed by bioturbation. Organic-rich muds have been moved up and down and mixed with sand. Moreover, sediments have been leached into open burrows during floods or rainfalls. In the natural levee sediments, mostly fine to medium sands, are horizontally burrowed, foremost by earthworms (Lumbricidae). Vertical, long (over 2 m deep) burrows of larger earthworms cross cut the natural levee sediments and enter buried soils. They were formed during a long period

  19. Effect of thickness on structure, microstructure, residual stress and soft magnetic properties of DC sputtered Fe65Co35 soft magnetic thin films

    International Nuclear Information System (INIS)

    Prasanna Kumari, T.; Manivel Raja, M.; Kumar, Atul; Srinath, S.; Kamat, S.V.

    2014-01-01

    The effect of film thickness on structure, microstructure, residual stress and soft magnetic properties of Fe 65 Co 35 thin films deposited on Si(001) and MgO(001) substrates was investigated by varying film thickness from 30 to 600 nm. X-ray diffraction studies showed that the FeCo films are polycrystalline in the as-deposited condition irrespective of deposition on Si or MgO substrate. The microstructure of films consisted of spherical grains for 30 nm film thickness and columnar grains for all other film thicknesses. The grain size for the films was found to increase from 15 to 50 nm with increasing film thickness. The sputtered films also exhibited tensile residual stresses with the magnitude of stress decreasing with increasing film thickness. The Fe 65 Co 35 films deposited on both substrates also exhibited very good in-plane soft magnetic properties with a saturation magnetization 4πM s of ∼23.6–23.8 kG and coercivity of ∼27–30 Oe without any under-layer only for films with thickness of 30 nm. For all other thicknesses, these films exhibited a significantly higher coercivity. The observed variations in soft magnetic properties with film thickness were explained in terms of residual stress and microstructure of the films. - Highlights: • Spherical grain morphology transformed to columnar above 30 nm film thickness. • Sputtered films exhibited tensile residual stresses decreasing with film thickness. • An in-plane coercivity of ∼27–30 Oe was achieved without any under-layer

  20. Thickness dependence of electro-optical properties of WO{sub 3} films as an electrochromic functional material for energy-efficient applications

    Energy Technology Data Exchange (ETDEWEB)

    Esmail, Ayat; Hashem, Hany; Soltan, Soltan; Hammam, Mahmoud; Ramadan, Ahmed [Faculty of Science, Department of Physics, Helwan University, Cairo (Egypt)

    2017-01-15

    WO{sub 3} films of different thicknesses (100, 200, and 300 nm) were prepared by two vacuum physical vapor deposition (PVD) methods (thermal evaporation and an electron gun). Electrophysical measurements (cyclic voltammetry and chronoamperometry) were carried out using a potentiostat in an electrochromic cell (liquid device) that consists of a substrate coated with double layers of F: SnO{sub 2} and WO{sub 3} served as working electrodes. X-ray diffraction showed an amorphous structure for all the deposited WO{sub 3} thin films. While the transmission in the bleached state does not change and it is close to the as-deposited state, it is slightly less at larger thickness. The cyclic voltammogram was more open (more current flow) for thicker films due to the less dense structure with many channels. Also, the coloration efficiency was higher at low thickness. The response time was of the order of seconds and decreased for coloration, while it increased for the bleaching process as the film thickness increases. According to the proposed figure of merit, the electrochromic performance deteriorates as the WO{sub 3} film thickness decreases. However, the thickness is more effective in the case of an electron gun. Generally, continuous films but thinner than 200 nm, are recommended for deposition methods. (copyright 2016 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  1. Plasma Spray-Physical Vapor Deposition (PS-PVD) of Ceramics for Protective Coatings

    Science.gov (United States)

    Harder, Bryan J.; Zhu, Dongming

    2011-01-01

    In order to generate advanced multilayer thermal and environmental protection systems, a new deposition process is needed to bridge the gap between conventional plasma spray, which produces relatively thick coatings on the order of 125-250 microns, and conventional vapor phase processes such as electron beam physical vapor deposition (EB-PVD) which are limited by relatively slow deposition rates, high investment costs, and coating material vapor pressure requirements. The use of Plasma Spray - Physical Vapor Deposition (PS-PVD) processing fills this gap and allows thin (deposited and multilayer coatings of less than 100 microns to be generated with the flexibility to tailor microstructures by changing processing conditions. Coatings of yttria-stabilized zirconia (YSZ) were applied to NiCrAlY bond coated superalloy substrates using the PS-PVD coater at NASA Glenn Research Center. A design-of-experiments was used to examine the effects of process variables (Ar/He plasma gas ratio, the total plasma gas flow, and the torch current) on chamber pressure and torch power. Coating thickness, phase and microstructure were evaluated for each set of deposition conditions. Low chamber pressures and high power were shown to increase coating thickness and create columnar-like structures. Likewise, high chamber pressures and low power had lower growth rates, but resulted in flatter, more homogeneous layers

  2. Geological 3-D modelling and resources estimation of the Budenovskoye uranium deposit (Kazakhstan)

    International Nuclear Information System (INIS)

    Boytsov, A.; Heyns, M.; Seredkin, M.

    2014-01-01

    The Budenovskoye deposit is the biggest sandstone-hosted, roll front type uranium deposit in Kazakhstan and in the world. Uranium mineralization occurs in the unconsolidated lacustrine-alluvial sediments of Late Cretaceous Mynkuduk and Inkuduk horizons. The Budenovskoye deposit was split into four areas for development with the present Karatau ISL Mine operating No. 2 area and Akbastau ISL Mine Nos. 1, 3 and 4 areas. Mines are owned by Kazatomprom and Uranium One in equal shares. CSA Global was retained by Uranium One to update in accordance with NI 43-101 the Mineral Resource estimates for the Karatau and Akbastau Mines. The modelling Reports shows a significant increase in total uranium resources tonnage at both mines when compared to the March 2012 NI 43-101 resource estimate: at Karartau measured and indicated resources increased by 586% while at Akbastau by 286%. It has also added a 55,766 tonnes U to the Karatau Inferred Mineral Resource category.The new estimates result from the application of 3-D modelling techniques to the extensive database of drilling information, new exploration activities.

  3. Quality of Shallow Groundwater and Drinking Water in the Mississippi Embayment-Texas Coastal Uplands Aquifer System and the Mississippi River Valley Alluvial Aquifer, South-Central United States, 1994-2004

    Science.gov (United States)

    Welch, Heather L.; Kingsbury, James A.; Tollett, Roland W.; Seanor, Ronald C.

    2009-01-01

    The Mississippi embayment-Texas coastal uplands aquifer system is an important source of drinking water, providing about 724 million gallons per day to about 8.9 million people in Texas, Louisiana, Mississippi, Arkansas, Missouri, Tennessee, Kentucky, Illinois, and Alabama. The Mississippi River Valley alluvial aquifer ranks third in the Nation for total withdrawals of which more than 98 percent is used for irrigation. From 1994 through 2004, water-quality samples were collected from 169 domestic, monitoring, irrigation, and public-supply wells in the Mississippi embayment-Texas coastal uplands aquifer system and the Mississippi River Valley alluvial aquifer in various land-use settings and of varying well capacities as part of the U.S. Geological Survey's National Water-Quality Assessment Program. Groundwater samples were analyzed for physical properties and about 200 water-quality constituents, including total dissolved solids, major inorganic ions, trace elements, radon, nutrients, dissolved organic carbon, pesticides, pesticide degradates, and volatile organic compounds. The occurrence of nutrients and pesticides differed among four groups of the 114 shallow wells (less than or equal to 200 feet deep) in the study area. Tritium concentrations in samples from the Holocene alluvium, Pleistocene valley trains, and shallow Tertiary wells indicated a smaller component of recent groundwater than samples from the Pleistocene terrace deposits. Although the amount of agricultural land overlying the Mississippi River Valley alluvial aquifer was considerably greater than areas overlying parts of the shallow Tertiary and Pleistocene terrace deposits wells, nitrate was rarely detected and the number of pesticides detected was lower than other shallow wells. Nearly all samples from the Holocene alluvium and Pleistocene valley trains were anoxic, and the reducing conditions in these aquifers likely result in denitrification of nitrate. In contrast, most samples from the

  4. Thickness Dependent on Photocatalytic Activity of Hematite Thin Films

    Directory of Open Access Journals (Sweden)

    Yen-Hua Chen

    2012-01-01

    Full Text Available Hematite (Fe2O3 thin films with different thicknesses are fabricated by the rf magnetron sputtering deposition. The effects of film thicknesses on the photocatalytic activity of hematite films have been investigated. Hematite films possess a polycrystalline hexagonal structure, and the band gap decreases with an increase of film thickness. Moreover, all hematite films exhibit good photocatalytic ability under visible-light irradiation; the photocatalytic activity of hematite films increases with the increasing film thickness. This is because the hematite film with a thicker thickness has a rougher surface, providing more reaction sites for photocatalysis. Another reason is a lower band gap of a hematite film would generate more electron-hole pairs under visible-light illumination to enhance photocatalytic efficiency. Experimental data are well fitted with Langmuir-Hinshelwood kinetic model. The photocatalytic rate constant of hematite films ranges from 0.052 to 0.068 min-1. This suggests that the hematite film is a superior photocatalyst under visible-light irradiation.

  5. Influence of processing parameters on PZT thick films

    International Nuclear Information System (INIS)

    Huang, Oliver; Bandyopadhyay, Amit; Bose, Susmita

    2005-01-01

    We have studied influence of processing parameters on the microstructure and ferroelectric properties of lead zirconate titanate (PZT)-based thick films in the range of 5-25 μm. PZT and 2% La-doped PZT thick films were processed using a modified sol-gel process. In this process, PZT- and La-doped PZT powders were first prepared via sol-gel. These powders were calcined and then used with respective sols to form a slurry. Slurry composition was optimized to spin-coat thick films on platinized Si substrate (Si/SiO 2 /Ti/Pt). Spinning rate, acceleration and slurry deposition techniques were optimized to form thick films with uniform thickness and without any cracking. Increasing solids loading was found to enhance the surface smoothness of the film and decrease porosity. Films were tested for their electrical properties and ferroelectric fatigue response. The maximum polarization obtained was 40 μC/cm 2 at 250 kV/cm for PZT thick film and 30 μC/cm 2 at 450 kV/cm for La-doped PZT thick film. After 10 9 cycles of fatiguing at 35 kHz, La-doped PZT showed better resistance for ferroelectric fatigue compared with un-doped PZT films

  6. Morphological and microstructural characterization of nanostructured pure α-phase W coatings on a wide thickness range

    Energy Technology Data Exchange (ETDEWEB)

    Gordillo, N., E-mail: nuri.gordillo@gmail.com [Instituto de Fusión Nuclear, ETSI de Industriales, Universidad Politécnica de Madrid, C/José Gutierrez Abascal, 2, E-28006 Madrid (Spain); CEI Campus Moncloa, UCM-UPM, Madrid (Spain); Panizo-Laiz, M. [Instituto de Fusión Nuclear, ETSI de Industriales, Universidad Politécnica de Madrid, C/José Gutierrez Abascal, 2, E-28006 Madrid (Spain); Tejado, E. [Department of Materials Science, Research Centre on Safety and Durability of Structures and Materials (CISDEM), UPM-CSIC, C/Profesor Aranguren s/n, E-28040 Madrid (Spain); Centro Nacional de Investigaciones Metalúrgicas, CENIM-CSIC, Madrid (Spain); Fernandez-Martinez, I. [Instituto de Energía Solar (IES), Universidad Politécnica de Madrid, Avenida Complutense s/n, E-28040 Madrid (Spain); Instituto de Microelectrónica de Madrid, IMM-CNM-CSIC, Isaac Newton 8 PTM, Tres Cantos, E-28760 Madrid (Spain); Rivera, A. [Instituto de Fusión Nuclear, ETSI de Industriales, Universidad Politécnica de Madrid, C/José Gutierrez Abascal, 2, E-28006 Madrid (Spain); Pastor, J.Y. [Department of Materials Science, Research Centre on Safety and Durability of Structures and Materials (CISDEM), UPM-CSIC, C/Profesor Aranguren s/n, E-28040 Madrid (Spain); Castro, C. Gómez de [Departamento de Física de Materiales, Facultad de CC. Químicas, Universidad Complutense de Madrid, Ciudad Universitaria s/n, E-28040 Madrid (Spain); and others

    2014-10-15

    Highlights: • Pure α-phase tungsten nanostructures were deposited by DC-magnetron sputtering. • Non-delaminated coatings were achieved at powers ≤50 W. • The coating thicknesses vary from 30 nm up to ∼4.0 μm. • The influence of the substrate on the coating properties was investigated. • We report on the morphological, microstructural and mechanical properties. - Abstract: Nanostructured tungsten (nanoW) coatings have been deposited by DC magnetron sputtering. First, the influence of the sputtering power on the adhesion of the coatings to the substrate was investigated by depositing coatings at powers varying from 30 up to 220 W. Non-delaminated coatings were achieved at powers ≤50 W. Second, the influence of coating thickness on the morphological, microstructural and mechanical properties was investigated for films deposited at 50 W with thicknesses varying from 30 nm up to ∼4.0 μm. SEM images reveal that all the films are highly compact, consisting of nanometer sized columns that grow perpendicular to the substrate. XRD data evidence that films are monophasic, being made of pure α-phase. All coatings show compressive stress and low micro-strain. Nanoindentation tests show that coatings have a hardness higher than that reported for coarse grained W. No significant dependence of the previous properties on coating thickness was observed. Finally, the influence of the substrate on coatings properties was studied, by depositing a W coating at a power of 50 W on a commercial steel substrate: no significant dependence was found.

  7. Groundwater movement, recharge, and perchlorate occurrence in a faulted alluvial aquifer in California (USA)

    Science.gov (United States)

    Izbicki, John A.; Teague, Nicholas F.; Hatzinger, Paul B.; Böhlke, John Karl; Sturchio, Neil C.

    2015-01-01

    Perchlorate from military, industrial, and legacy agricultural sources is present within an alluvial aquifer in the Rialto-Colton groundwater subbasin, 80 km east of Los Angeles, California (USA). The area is extensively faulted, with water-level differences exceeding 60 m across parts of the Rialto-Colton Fault separating the Rialto-Colton and Chino groundwater subbasins. Coupled well-bore flow and depth-dependent water-quality data show decreases in well yield and changes in water chemistry and isotopic composition, reflecting changing aquifer properties and groundwater recharge sources with depth. Perchlorate movement through some wells under unpumped conditions from shallower to deeper layers underlying mapped plumes was as high as 13 kg/year. Water-level maps suggest potential groundwater movement across the Rialto-Colton Fault through an overlying perched aquifer. Upward flow through a well in the Chino subbasin near the Rialto-Colton Fault suggests potential groundwater movement across the fault through permeable layers within partly consolidated deposits at depth. Although potentially important locally, movement of groundwater from the Rialto-Colton subbasin has not resulted in widespread occurrence of perchlorate within the Chino subbasin. Nitrate and perchlorate concentrations at the water table, associated with legacy agricultural fertilizer use, may be underestimated by data from long-screened wells that mix water from different depths within the aquifer.

  8. The Temporal-Spatial Distribution of Shule River Alluvial Fan Units in China Based on SAR Data and OSL Dating

    Directory of Open Access Journals (Sweden)

    Lu Zhang

    2013-12-01

    Full Text Available Alluvial fans in arid and semi-arid regions can provide important evidence of geomorphic and climatic changes, which reveal the evolution of the regional tectonic activity and environment. Synthetic aperture radar (SAR remote sensing technology, which is sensitive to geomorphic features, plays an important role in quickly mapping alluvial fan units of different ages. In this paper, RADARSAT-2 (Canada’s C-band new-generation radar satellite and ALOS-PALSAR (Japan’s advanced land observing satellite, phased array type L-band SAR sensor data, acquired over the Shule River Alluvial Fan (SRAF, are used to extract backscattering coefficients, scattering mechanism-related information, and polarimetric characteristic parameters. The correlation between these SAR characteristic parameters and fan units of the SRAF of different ages was studied, and the spatial distribution of fan units, since the Late Pleistocene, was extracted based on the Maximum Likelihood classification method. The results prove that (1 some C-band SAR parameters can describe the geomorphic characteristics of alluvial fan units of different ages in the SRAF; (2 SAR data can be used to map the SRAF’s surface between the Late Pleistocene and the Holocene and to extract the spatial distribution of fan units; and (3 the time-spatial distribution of the SRAF can provide valuable information for tectonic and paleoenvironmental research of the study area.

  9. Peat-accumulating depositional systems of Sarawak, East Malaysia

    Science.gov (United States)

    Staub, James R.; Esterle, Joan S.

    1994-02-01

    Many coal deposits originate in deltaic, estuarine, and coastal plain settings and a knowledge of interrelationships between the tectonic and depositional elements active at the time of sediment deposition is necessary to formulate basin scale models. The prograding coastal depositional systems of Sarawak all contain domed peat-accumulating environments in which low-ash, low-sulfur peats are being deposited in areas of active clastic siliciclastic sedimentation. These depositional systems are as large as 11,400 km 2 and individual peat deposits within systems are in excess of 20 m thick and 1000 km 2 in area. The geographic positions and drainage basin areas of each depositional system are controlled by fault and fold systems. Although prograding into the same receiving basin, individual system geomorphology is variable and ranges from a wave-dominated microtidal delta, to a wave-dominated meso- to macro-tidal delta/coastal plain system, to a tide-dominated macrotidal estuarine embayment along a 450 km stretch of coastline. System variation is a function of sediment supply, shelf and embayment geometry, wave climate, and tidal range. These factors, which control depositional system geomorphology, also control the resulting long axis orientation of the thick, domed peat deposits. The surface vegetation and internal characteristics of most domed peat deposits, however, are similar. Internal characteristics consist of basal high-ash, high-sulfur, degraded peats overlain by low-ash, low-sulfur, well preserved peats in vertical profile. These systems demonstrate variable responses to late Pleistocene/Holocene sea-level rise and, in these instances, the variation is most attributable to local differences in siliciclastic sediment supply, which is a function of the drainage basin area.

  10. Modeling and measuring the relationships between sediment transport processes, alluvial bedforms and channel-scale morphodynamics in sandy braided rivers.

    Science.gov (United States)

    Nicholas, A. P.; Ashworth, P. J.; Best, J.; Lane, S. N.; Parsons, D. R.; Sambrook Smith, G.; Simpson, C.; Strick, R. J. P.; Unsworth, C. A.

    2017-12-01

    Recent years have seen significant advances in the development and application of morphodynamic models to simulate river evolution. Despite this progress, significant challenges remain to be overcome before such models can provide realistic simulations of river response to environmental change, or be used to determine the controls on alluvial channel patterns and deposits with confidence. This impasse reflects a wide range of factors, not least the fact that many of the processes that control river behaviour operate at spatial scales that cannot be resolved by such models. For example, sand-bed rivers are characterised by multiple scales of topography (e.g., dunes, bars, channels), the finest of which must often by parameterized, rather than represented explicitly in morphodynamic models. We examine these issues using a combination of numerical modeling and field observations. High-resolution aerial imagery and Digital Elevation Models obtained for the sandy braided South Saskatchewan River in Canada are used to quantify dune, bar and channel morphology and their response to changing flow discharge. Numerical simulations are carried out using an existing morphodynamic model based on the 2D shallow water equations, coupled with new parameterisations of the evolution and influence of alluvial bedforms. We quantify the spatial patterns of sediment flux using repeat images of dune migration and bar evolution. These data are used to evaluate model predictions of sediment transport and morphological change, and to assess the degree to which model performance is controlled by the parametrization of roughness and sediment transport phenomena linked to subgrid-scale bedforms (dunes). The capacity of such models to replicate the characteristic multi-scale morphology of bars in sand-bed rivers, and the contrasting morphodynamic signatures of braiding during low and high flow conditions, is also assessed.

  11. Factors influencing the deposition of hydroxyapatite coating onto hollow glass microspheres

    International Nuclear Information System (INIS)

    Jiao, Yan; Xiao, Gui-Yong; Xu, Wen-Hua; Zhu, Rui-Fu; Lu, Yu-Peng

    2013-01-01

    Hydroxyapatite (HA) and HA coated microcarriers for cell culture and delivery have attracted more attention recently, owing to the rapid progress in the field of tissue engineering. In this research, a dense and uniform HA coating with the thickness of about 2 μm was successfully deposited on hollow glass microspheres (HGM) by biomimetic process. The influences of SBF concentration, immersion time, solid/liquid ratio and activation of HGM on the deposition rate and coating characteristics were discussed. X-ray diffraction (XRD) and Fourier transform infrared spectrum (FTIR) analyses revealed that the deposited HA is poorly crystalline. The thickness of HA coating showed almost no increase after immersion in 1.5SBF for more than 15 days with the solid/liquid ratio of 1:150. At the same time, SBF concentration, solid/liquid ratio and activation treatment played vital roles in the formation of HA coating on HGM. This poorly crystallized HA coated HGM could have potential use as microcarrier for cell culture. Highlights: • HA coatings were deposited on hollow glass microspheres by biomimetic process. • The obtained HA coating was poorly crystalline and carbonated. • The influencing factors of deposition rate and coating characteristics were studied. • The thickness of HA coating showed almost no increase after immersion for 15 days

  12. Geology and ground-water conditions of Clark County Washington, with a description of a major alluvial aquifer along the Columbia River

    Science.gov (United States)

    Mundorff, Maurice John

    1964-01-01

    , unconsolidated rocks in the lowlands to the west At most places small to moderate quantities of water can be obtained from fractures in the older consolidated rocks. However, in the populated parts of the county, these rocks generally are overlain by considerable thicknesses of more permeable materials, and few wells have been drilled in them. Springs and dug wells yield an ample domestic supply at a number of outlying farms in the foothills. The younger (Pliocene to Recent) unconsolidated materials were deposited chiefly by streams in the basin formed by downwarping of the older rocks. However, some lake deposits and glacial drift also are included. The oldest unit of this group, the lower member of the Troutdale formation of Pliocene age, consists chiefly of clay, silt, and fine sand but includes lenses of coarser sand and, rarely, gravel. The maximum known thickness of the lower member of the Troutdale formation is about 660 feet. This unit is not a good aquifer because most of the strata are fine grained. However, at a few places drilled wells have penetrated lenses of coarser grained materials in these deposits and have obtained small to moderate amounts of water from them. The upper member of the Troutdale formation consists almost entirely of lightly to moderately cemented gravel, of which the most striking feature is the presence of a considerable percentage of quartzite pebbles. The average thickness of the upper member of the Troutdale may originally have been 300 to 400 feet. The member crops out over considerable areas in the county and, where conditions of topography and exposure are optimum, has beer very deeply weathered. It is suggested that the upper member of the Troutdale formation may prove to be of early Pleistocene age. This member is one of the best aquifers in the county; here, more drilled wells have been completed in this unit than in any other--most i

  13. Aerial gamma ray and magnetic survey: Mississippi and Florida airborne survey, Russellville quadrangle, Arkansas

    International Nuclear Information System (INIS)

    1980-09-01

    The Russellville quadrangle in north central Arkansas overlies thick Paleozoic sediments of the Arkoma Basin. These Paleozoics dominate surface exposure except where covered by Quaternary alluvial materials. Examination of available literature shows no known uranium deposits (or occurrences) within the quadrangle. Eighty-eight groups of uranium samples were defined as anomalies and are discussed briefly. None were considered significant, and most appeared to be of cultural origin. Magnetic data show character that suggest structural and/or lithologic complexity, but imply relatively deep-seated sources

  14. Aerial gamma ray and magnetic survey: Mississippi and Florida airborne survey, Fort Smith quadrangle, Oklahoma, and Arkansas. Final report

    International Nuclear Information System (INIS)

    1980-09-01

    The Fort Smith quadrangle in western Arkansas and eastern Oklahoma overlies thick Paleozoic sediments of the Arkoma Basin. These Paleozoics dominate surface exposure except where covered by Quaternary Alluvial materials. Examination of available literature shows no known uranium deposits (or occurrences) within the quadrangle. Seventy-five groups of uranium samples were defined as anomalies and are discussed briefly. None were considered significant, and most appeared to be of cultural origin. Magnetic data show character that suggest structural and/or lithologic complexity, but imply relatively deep-seated sources

  15. Age, distribution, and significance within a sediment budget, of in-channel depositional surfaces in the Normanby River, Queensland, Australia

    Science.gov (United States)

    Pietsch, T. J.; Brooks, A. P.; Spencer, J.; Olley, J. M.; Borombovits, D.

    2015-06-01

    We present the results of investigations into alluvial deposition in the catchment of the Normanby River, which flows into Princess Charlotte Bay (PCB) in the northern part of the Great Barrier Reef Lagoon. Our focus is on the fine fraction (bank attached bars or inset or inner floodplains, these more or less flat-lying surfaces within the macro-channel have hitherto received little attention in sediment budgeting models. We use high resolution LiDAR based mapping combined with optical dating of exposures cut into these in-channel deposits to compare their aggradation rates with those found in other depositional zones in the catchment, namely the floodplain and coastal plain. In total 59 single grain OSL dates were produced across 21 stratigraphic profiles at 14 sites distributed though the 24 226 km2 catchment. In-channel storage in these inset features is a significant component of the contemporary fine sediment budget (i.e. recent decades/last century), annually equivalent to more than 50% of the volume entering the channel network from hillslopes and subsoil sources. Therefore, at the very least, in-channel storage of fine material needs to be incorporated into sediment budgeting exercises. Furthermore, deposition within the channel has occurred in multiple locations coincident in time with accelerated sediment production following European settlement. Generally, this has occurred on a subset of the features we have examined here, namely linear bench features low in the channel. This suggests that accelerated aggradation on in-channel depositional surfaces has been in part a response to accelerated erosion within the catchment. The entire contribution of ~ 370 kilotonnes per annum of fine sediment estimated to have been produced by alluvial gully erosion over the last ~ 100 years can be accounted for by that stored as in-channel alluvium. These features therefore can play an important role in mitigating the impact on the receiving water of accelerated erosion.

  16. Hardness Enhancement of STS304 Deposited with Yttria Stabilized Zirconia by Aerosol Deposition Method

    Energy Technology Data Exchange (ETDEWEB)

    Lim, Il-Ho; Park, Chun-Kil; Kim, Hyung Sun; Jeong, Dea-Yong [Inha University, Incheon (Korea, Republic of); Lee, Yong-Seok [Sodoyeon Co., Yeoju (Korea, Republic of); Kong, Young-Min [University of Ulsan, Ulsan (Korea, Republic of); Kang, Kweon Ho [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2016-03-15

    To improve the surface hardness of the STS304, Yttria stabilized zirconia (YSZ) films with nano-sized grain were deposited by an aerosol-deposition (AD) method. Coating layers showed dense structure and had -5µm thickness. When 3 mol% YSZ powders with tetragonal phase were deposited on STS304 substrate, tetragonal structure was transformed to cubic structure due to the high impact energy during the AD process. At the same time, strong impact by YSZ particles allowed the austenite phase in STS304 to be transformed into martensite phase. Surface hardness measured with nano indentor showed that YSZ coated film had 11.5 GPa, which is larger value than 7 GPa of STS304.

  17. Thickness and structure of the water film deposited from vapour on calcite surfaces

    DEFF Research Database (Denmark)

    Bohr, Jakob; Wogelius, Roy A.; Morris, Peter M.

    2010-01-01

    Synchrotron X-ray reflectivity (SXR) was used to measure the thickness of the water film that adsorbs on a {10¯14} cleavage surface of calcite (CaCO3) in a sample chamber where relative humidity could be controlled within the range from......Synchrotron X-ray reflectivity (SXR) was used to measure the thickness of the water film that adsorbs on a {10¯14} cleavage surface of calcite (CaCO3) in a sample chamber where relative humidity could be controlled within the range from...

  18. Potential of direct metal deposition technology for manufacturing thick functionally graded coatings and parts for reactors components

    International Nuclear Information System (INIS)

    Thivillon, L.; Bertrand, Ph.; Laget, B.; Smurov, I.

    2009-01-01

    Direct metal deposition (DMD) is an automated 3D deposition process arising from laser cladding technology with co-axial powder injection to refine or refurbish parts. Recently DMD has been extended to manufacture large-size near-net-shape components. When applied for manufacturing new parts (or their refinement), DMD can provide tailored thermal properties, high corrosion resistance, tailored tribology, multifunctional performance and cost savings due to smart material combinations. In repair (refurbishment) operations, DMD can be applied for parts with a wide variety of geometries and sizes. In contrast to the current tool repair techniques such as tungsten inert gas (TIG), metal inert gas (MIG) and plasma welding, laser cladding technology by DMD offers a well-controlled heat-treated zone due to the high energy density of the laser beam. In addition, this technology may be used for preventative maintenance and design changes/up-grading. One of the advantages of DMD is the possibility to build functionally graded coatings (from 1 mm thickness and higher) and 3D multi-material objects (for example, 100 mm-sized monolithic rectangular) in a single-step manufacturing cycle by using up to 4-channel powder feeder. Approved materials are: Fe (including stainless steel), Ni and Co alloys, (Cu,Ni 10%), WC compounds, TiC compounds. The developed coatings/parts are characterized by low porosity (<1%), fine microstructure, and their microhardness is close to the benchmark value of wrought alloys after thermal treatment (Co-based alloy Stellite, Inox 316L, stainless steel 17-4PH). The intended applications concern cooling elements with complex geometry, friction joints under high temperature and load, light-weight mechanical support structures, hermetic joints, tubes with complex geometry, and tailored inside and outside surface properties, etc

  19. Potential of direct metal deposition technology for manufacturing thick functionally graded coatings and parts for reactors components

    Science.gov (United States)

    Thivillon, L.; Bertrand, Ph.; Laget, B.; Smurov, I.

    2009-03-01

    Direct metal deposition (DMD) is an automated 3D deposition process arising from laser cladding technology with co-axial powder injection to refine or refurbish parts. Recently DMD has been extended to manufacture large-size near-net-shape components. When applied for manufacturing new parts (or their refinement), DMD can provide tailored thermal properties, high corrosion resistance, tailored tribology, multifunctional performance and cost savings due to smart material combinations. In repair (refurbishment) operations, DMD can be applied for parts with a wide variety of geometries and sizes. In contrast to the current tool repair techniques such as tungsten inert gas (TIG), metal inert gas (MIG) and plasma welding, laser cladding technology by DMD offers a well-controlled heat-treated zone due to the high energy density of the laser beam. In addition, this technology may be used for preventative maintenance and design changes/up-grading. One of the advantages of DMD is the possibility to build functionally graded coatings (from 1 mm thickness and higher) and 3D multi-material objects (for example, 100 mm-sized monolithic rectangular) in a single-step manufacturing cycle by using up to 4-channel powder feeder. Approved materials are: Fe (including stainless steel), Ni and Co alloys, (Cu,Ni 10%), WC compounds, TiC compounds. The developed coatings/parts are characterized by low porosity (<1%), fine microstructure, and their microhardness is close to the benchmark value of wrought alloys after thermal treatment (Co-based alloy Stellite, Inox 316L, stainless steel 17-4PH). The intended applications concern cooling elements with complex geometry, friction joints under high temperature and load, light-weight mechanical support structures, hermetic joints, tubes with complex geometry, and tailored inside and outside surface properties, etc.

  20. Potential of direct metal deposition technology for manufacturing thick functionally graded coatings and parts for reactors components

    Energy Technology Data Exchange (ETDEWEB)

    Thivillon, L.; Bertrand, Ph.; Laget, B. [Ecole Nationale d' Ingenieurs de Saint-Etienne (ENISE), DIPI Laboratory, 58 rue Jean Parot, 42023 Saint-Etienne cedex 2 (France); Smurov, I. [Ecole Nationale d' Ingenieurs de Saint-Etienne (ENISE), DIPI Laboratory, 58 rue Jean Parot, 42023 Saint-Etienne cedex 2 (France)], E-mail: smurov@enise.fr

    2009-03-31

    Direct metal deposition (DMD) is an automated 3D deposition process arising from laser cladding technology with co-axial powder injection to refine or refurbish parts. Recently DMD has been extended to manufacture large-size near-net-shape components. When applied for manufacturing new parts (or their refinement), DMD can provide tailored thermal properties, high corrosion resistance, tailored tribology, multifunctional performance and cost savings due to smart material combinations. In repair (refurbishment) operations, DMD can be applied for parts with a wide variety of geometries and sizes. In contrast to the current tool repair techniques such as tungsten inert gas (TIG), metal inert gas (MIG) and plasma welding, laser cladding technology by DMD offers a well-controlled heat-treated zone due to the high energy density of the laser beam. In addition, this technology may be used for preventative maintenance and design changes/up-grading. One of the advantages of DMD is the possibility to build functionally graded coatings (from 1 mm thickness and higher) and 3D multi-material objects (for example, 100 mm-sized monolithic rectangular) in a single-step manufacturing cycle by using up to 4-channel powder feeder. Approved materials are: Fe (including stainless steel), Ni and Co alloys, (Cu,Ni 10%), WC compounds, TiC compounds. The developed coatings/parts are characterized by low porosity (<1%), fine microstructure, and their microhardness is close to the benchmark value of wrought alloys after thermal treatment (Co-based alloy Stellite, Inox 316L, stainless steel 17-4PH). The intended applications concern cooling elements with complex geometry, friction joints under high temperature and load, light-weight mechanical support structures, hermetic joints, tubes with complex geometry, and tailored inside and outside surface properties, etc.

  1. Application of geoecological concept of the alluvial landscape in the creation of nature reserve (case study from Czech Republic

    Directory of Open Access Journals (Sweden)

    Ivo Machar

    2011-01-01

    Full Text Available The geoecological concept of the alluvial landscape describes the variability and consecutive character of alluvial ecotopes and biocenoses, which are interrelated in terms of their homeorhetic development, in their dynamic ecological stability. This article deals with application of this landscape concept in the frame of creation of nature reserve as core zone of the Litovelské Pomoraví Protected Landscape Area (Czech Republic. Complex protection of the whole floodplain ecosystem, which comprised all components of the fluvial succession series of alluvial habitats, was proposed on the basis of determination of geomorphological type of the river system. Analyses of the floodplain forest stands status within the study area were performed using methods that are normally used in the elaboration of management plans of protected areas within forest land on the basis of data from Forest Management Plan. The area of the proposed NNR was created by the overlay of the special map layers using method gap-analysis in the frame of GIS.

  2. Locating underground uranium deposits

    International Nuclear Information System (INIS)

    Felice, P.E.

    1979-01-01

    Underground uranium deposits are located by placing wires of dosimeters each about 5 to 18 mg/cm 2 thick underground in a grid pattern. Each dosimeter contains a phosphor which is capable of storing the energy of alpha particles. In each pair one dosimeter is shielded from alpha particles with more than 18 mg/cm 2 thick opaque material but not gamma and beta rays and the other dosimeter is shielded with less than 1 mg/cm 2 thick opaque material to exclude dust. After a period underground the dosimeters are heated which releases the stored energy as light. The amount of light produced from the heavily shielded dosimeter is subtracted from the amount of light produced from the thinly shielded dosimeter to give an indication of the location and quantity of uranium underground

  3. Geophysical Characterization of the Quaternary-Cretaceous Contact Using Surface Resistivity Methods in Franklin and Webster Counties, South-Central Nebraska

    Science.gov (United States)

    Teeple, Andrew; Kress, Wade H.; Cannia, James C.; Ball, Lyndsay B.

    2009-01-01

    Formation made accurate interpretation of the resistivity profile sections difficult and less confident because of similar resistivity of this formation and that of the coarser-grained sediment of the Quaternary-age deposits. However, distinct conductive features were identified within the resistivity profile sections that aided in delineating the contact between the resistive Quaternary-age deposits and the resistive Niobrara Formation. Using this information, an interpretive boundary was drawn on the resistivity profile sections to represent the contact between the Quaternary-age alluvial deposits and the Cretaceous-age Niobrara Formation. A digital elevation model (DEM) of the top of the Niobrara Formation was constructed using the altitudes from the interpreted contact lines. This DEM showed that the general trend of top of the Niobrara Formation dips to the southeast. At the north edge of the study site, the Niobrara Formation topographic high trends east-west with an altitude range of 559 meters in the west to 543 meters in the east. Based on the land-surface elevation and the Niobrara Formation DEM, the estimated thickness of the Quaternary-age alluvial deposits throughout the study area was mapped and showed a thinning of the Quaternary-age alluvial deposits to the north, approximately where the topographic high of the Niobrara Formation is located. This topographic high in the Niobrara Formation has the potential to act as a barrier to ground-water flow from the uplands alluvial aquifer to the Republican River alluvial aquifer as shown in the resistivity profile sections. The Quaternary-age alluvial deposits in the uplands and those in the Republican River Valley are not fully represented as disconnected because it is possible that there are ground-water flow paths that were not mapped during this study.

  4. Influence of deposition time on the properties of chemical bath deposited manganese sulfide thin films

    Directory of Open Access Journals (Sweden)

    Anuar Kassim

    2010-12-01

    Full Text Available Manganese sulfide thin films were chemically deposited from an aqueous solution containing manganese sulfate, sodium thiosulfate and sodium tartrate. The influence of deposition time (2, 3, 6 and 8 days on the properties of thin films was investigated. The structure and surface morphology of the thin films were studied by X-ray diffraction and atomic force microscopy, respectively. In addition, in order to investigate the optical properties of the thin films, the UV-visible spectrophotometry was used. The XRD results indicated that the deposited MnS2 thin films exhibited a polycrystalline cubic structure. The number of MnS2 peaks on the XRD patterns initially increased from three to six peaks and then decreased to five peaks, as the deposition time was increased from 2 to 8 days. From the AFM measurements, the film thickness and surface roughness were found to be dependent on the deposition time.

  5. High-performance piezoelectric thick film based energy harvesting micro-generators for MEMS

    DEFF Research Database (Denmark)

    Zawada, Tomasz; Hansen, Karsten; Lou-Moeller, Rasmus

    2010-01-01

    and are transformed by the energy harvesting micro-generator into usable electrical signal. The micro-generator comprises a silicon cantilever with integrated InSensor® TF2100 PZT thick film deposited using screen-printing. The output power versus frequency and electrical load h