Thermodynamics of Radiation Modes
Pina, Eduardo; de la Selva, Sara Maria Teresa
2010-01-01
We study the equilibrium thermodynamics of the electromagnetic radiation in a cavity of a given volume and temperature. We found three levels of description, the thermodynamics of one mode, the thermodynamics of the distribution of frequencies in a band by summing over the frequencies in it and the global thermodynamics by summing over all the…
Co-C and Pd-C Eutectic Fixed Points for Radiation Thermometry and Thermocouple Thermometry
Wang, L.
2017-12-01
Two Co-C and Pd-C eutectic fixed point cells for both radiation thermometry and thermocouple thermometry were constructed at NMC. This paper describes details of the cell design, materials used, and fabrication of the cells. The melting curves of the Co-C and Pd-C cells were measured with a reference radiation thermometer realized in both a single-zone furnace and a three-zone furnace in order to investigate furnace effect. The transition temperatures in terms of ITS-90 were determined to be 1324.18 {°}C and 1491.61 {°}C with the corresponding combined standard uncertainty of 0.44 {°}C and 0.31 {°}C for Co-C and Pd-C, respectively, taking into account of the differences of two different types of furnaces used. The determined ITS-90 temperatures are also compared with that of INRIM cells obtained using the same reference radiation thermometer and the same furnaces with the same settings during a previous bilateral comparison exercise (Battuello et al. in Int J Thermophys 35:535-546, 2014). The agreements are within k=1 uncertainty for Co-C cell and k = 2 uncertainty for Pd-C cell. Shapes of the plateaus of NMC cells and INRIM cells are compared too and furnace effects are analyzed as well. The melting curves of the Co-C and Pd-C cells realized in the single-zone furnace are also measured by a Pt/Pd thermocouple, and the preliminary results are presented as well.
User's Manual: Routines for Radiative Heat Transfer and Thermometry
Risch, Timothy K.
2016-01-01
Determining the intensity and spectral distribution of radiation emanating from a heated surface has applications in many areas of science and engineering. Areas of research in which the quantification of spectral radiation is used routinely include thermal radiation heat transfer, infrared signature analysis, and radiation thermometry. In the analysis of radiation, it is helpful to be able to predict the radiative intensity and the spectral distribution of the emitted energy. Presented in this report is a set of routines written in Microsoft Visual Basic for Applications (VBA) (Microsoft Corporation, Redmond, Washington) and incorporating functions specific to Microsoft Excel (Microsoft Corporation, Redmond, Washington) that are useful for predicting the radiative behavior of heated surfaces. These routines include functions for calculating quantities of primary importance to engineers and scientists. In addition, the routines also provide the capability to use such information to determine surface temperatures from spectral intensities and for calculating the sensitivity of the surface temperature measurements to unknowns in the input parameters.
Radiation thermometry for semiconductor crystal growing furnaces
International Nuclear Information System (INIS)
Helgeland, W.
1985-01-01
Single crystals of silicon produced by the Czochralski process are used widely in the production of integrated circuits and other electronic devices. Recent advances in automation of industrial equipment for this process have led to the application of a dual wave band radiation thermometer. The instrument system automatically performs certain critical temperature measurements. In nonautomated equipment, these measurements require the judgement of a trained human operator. The difficulties of measuring and controlling the temperature at the critical location are discussed, especially with regard to detecting the meltdown end point and to initially establishing the correct temperature for seeding. A description is given of the customized temperature measurement system, which is based upon an existing ratio radiation thermometer. Thermometer output characteristics are described
Thermodynamic Geometry and Hawking Radiation
Bellucci, S
2010-01-01
This work explores the role of thermodynamic fluctuations in the two parameter Hawking radiating black hole configurations. The system is characterized by an ensemble of arbitrary mass and radiation frequency of the black holes. In the due course of the Hawking radiations, we find that the intrinsic geometric description exhibits an intriguing set of exact pair correction functions and global correlation lengths. We investigate the nature of the constant amplitude radiation and find that it's not stable under fluctuations of the mass and frequency. Subsequently, the consideration of the York model decreasing amplitude radiation demonstrates that thermodynamic fluctuations are globally stable in the small frequency region. In connection with quantum gravity refinements, we take an account of the logarithmic correction into the constant amplitude and York amplitude over the Hawking radiation. In both considerations, we notice that the nature of the possible parametric fluctuations may precisely be ascertained w...
Zeng, Hui; Ou, Dongbin; Chen, Lianzhong; Li, Fei; Yu, Xilong
2018-02-01
Nonintrusive temperature measurements for a real ammonium dinitramide (ADN)-based thruster by using tunable diode laser absorption spectroscopy and monochromatic radiation thermometry are proposed. The ADN-based thruster represents a promising future space propulsion employing green, nontoxic propellant. Temperature measurements in the chamber enable quantitative thermal analysis for the thruster, providing access to evaluate thermal properties of the thruster and optimize thruster design. A laser-based sensor measures temperature of combustion gas in the chamber, while a monochromatic thermometry system based on thermal radiation is utilized to monitor inner wall temperature in the chamber. Additional temperature measurements of the outer wall temperature are conducted on the injector, catalyst bed, and combustion chamber of the thruster by using thermocouple, respectively. An experimental ADN thruster is redesigned with optimizing catalyst bed length of 14 mm and steady-state firing tests are conducted under various feed pressures over the range from 5 to 12 bar at a typical ignition temperature of 200°C. A threshold of feed pressure higher than 8 bar is required for the thruster's normal operation and upstream movement of the heat release zone is revealed in the combustion chamber out of temperature evolution in the chamber.
Fermi, Enrico
1956-01-01
Indisputably, this is a modern classic of science. Based on a course of lectures delivered by the author at Columbia University, the text is elementary in treatment and remarkable for its clarity and organization. Although it is assumed that the reader is familiar with the fundamental facts of thermometry and calorimetry, no advanced mathematics beyond calculus is assumed.Partial contents: thermodynamic systems, the first law of thermodynamics (application, adiabatic transformations), the second law of thermodynamics (Carnot cycle, absolute thermodynamic temperature, thermal engines), the entr
Energy Technology Data Exchange (ETDEWEB)
Hollandt, J. [Physikalisch-Technische Bundesanstalt (PTB), Braunschweig (Germany). Fachbereich Hochtemperatur- und Vakuumphysik; Hartmann, J. [Physikalisch-Technische Bundesanstalt (PTB), Braunschweig (Germany). Arbeitsgruppe Hochtemperaturskala; Gutschwager, B. [Physikalisch-Technische Bundesanstalt (PTB), Braunschweig (Germany). Arbeitsgruppe Infrarot-Strahlungsthermometrie; Struss, O. [HEITRONICS Infrarot Messtechnik GmbH (Germany)
2007-09-15
The temperature is one of the measurands most frequently determined, as it decisively influences physical, chemical and biological processes. To be able to evaluate, optimize, repeat and compare industrial procedures, temperatures must be measured with sufficient accuracy and worldwide uniformity. This is done with the aid of the regulations and instructions of the international temperature scale. Today, non-contact measurements of surface temperatures can be performed without problems with radiation thermometers over a temperature range from -100 C up to 3000 C. Compared to contacting measurements, radiation-thermometric temperature measurement offers a series of advantages. Radiation thermometers react very fast and the measurement is not influenced by heat supply or dissipation. This allows objects to be measured which move very fast, are energized or may experience fast temperature changes. Consequently, radiation thermometry is increasingly used for the monitoring and control of thermal processes, for maintenance and in building services engineering. The present contribution shall inform of the fundamentals of radiation-thermometric temperature measurement as well as of the construction and popular types of radiation thermometers. It will be explained how exact and worldwide uniform temperature measurement is guaranteed via the international temperature scale and the calibration of radiation thermometers. The emissivity of surfaces which is important in practical temperature measurements and some examples of industrial applications of radiation thermometers will be described. (orig.)
Energy Technology Data Exchange (ETDEWEB)
Hollandt, J.; Hartmann, J.; Gutschwager, B. [Physikalisch-Technische Bundesanstalt, Berlin (Germany); Struss, O. [HEITRONICS Infrarot Messtechnik GmbH, Wiesbaden (Germany)
2006-07-01
The temperature is one of the measurands most frequently determined, as it decisively influences physical, chemical and biological processes. To be able to evaluate, optimize, repeat and compare industrial procedures, temperatures must be measured with sufficient accuracy and worldwide uniformity. This is done with the aid of the regulations and instructions of the international temperature scale. Today, non-contact measurements of surface temperatures can be performed without problems with radiation thermometers over a temperature range from -100 C up to 3000 C. Compared to contacting measurements, radiation-thermometric temperature measurement offers a series of advantages. Radiation thermometers react very fast and the measurement is not influenced by heat supply or dissipation. This allows objects to be measured which move very fast, are energized or may experience fast temperature changes. Consequently, radiation thermometry is increasingly used for the monitoring and control of thermal processes, for maintenance and in building services engineering. The present contribution shall inform of the fundamentals of radiation-thermometric temperature measurement as well as of the construction and popular types of radiation thermometers. It will be explained how exact and worldwide uniform temperature measurement is guaranteed via the international temperature scale and the calibration of radiation thermometers. The emissivity of surfaces which is important in practical temperature measurements and some examples of industrial applications of radiation thermometers will be described. (orig.)
De Lucas, Javier; Segovia, José Juan
2018-05-01
Blackbody cavities are the standard radiation sources widely used in the fields of radiometry and radiation thermometry. Its effective emissivity and uncertainty depend to a large extent on the temperature gradient. An experimental procedure based on the radiometric method for measuring the gradient is followed. Results are applied to particular blackbody configurations where gradients can be thermometrically estimated by contact thermometers and where the relationship between both basic methods can be established. The proposed procedure may be applied to commercial blackbodies if they are modified allowing secondary contact temperature measurement. In addition, the established systematic may be incorporated as part of the actions for quality assurance in routine calibrations of radiation thermometers, by using the secondary contact temperature measurement for detecting departures from the real radiometrically obtained gradient and the effect on the uncertainty. On the other hand, a theoretical model is proposed to evaluate the effect of temperature variations on effective emissivity and associated uncertainty. This model is based on a gradient sample chosen following plausible criteria. The model is consistent with the Monte Carlo method for calculating the uncertainty of effective emissivity and complements others published in the literature where uncertainty is calculated taking into account only geometrical variables and intrinsic emissivity. The mathematical model and experimental procedure are applied and validated using a commercial type three-zone furnace, with a blackbody cavity modified to enable a secondary contact temperature measurement, in the range between 400 °C and 1000 °C.
Willmott, Jon R.; Lowe, David; Broughton, Mick; White, Ben S.; Machin, Graham
2016-09-01
A primary temperature scale requires realising a unit in terms of its definition. For high temperature radiation thermometry in terms of the International Temperature Scale of 1990 this means extrapolating from the signal measured at the freezing temperature of gold, silver or copper using Planck’s radiation law. The difficulty in doing this means that primary scales above 1000 °C require specialist equipment and careful characterisation in order to achieve the extrapolation with sufficient accuracy. As such, maintenance of the scale at high temperatures is usually only practicable for National Metrology Institutes, and calibration laboratories have to rely on a scale calibrated against transfer standards. At lower temperatures it is practicable for an industrial calibration laboratory to have its own primary temperature scale, which reduces the number of steps between the primary scale and end user. Proposed changes to the SI that will introduce internationally accepted high temperature reference standards might make it practicable to have a primary high temperature scale in a calibration laboratory. In this study such a scale was established by calibrating radiation thermometers directly to high temperature reference standards. The possible reduction in uncertainty to an end user as a result of the reduced calibration chain was evaluated.
Evaluation of phase sensitive detection method and Si avalanche photodiode for radiation thermometry
International Nuclear Information System (INIS)
Hobbs, M J; Tan, C H; Willmott, J R
2013-01-01
We report the evaluation of Si avalanche photodiodes (APDs) for use in radiation thermometry as an alternative to Si photodiodes. We compared their performance when operated under phase sensitive detection (PSD), where the signal is modulated, and direct detection (DD) methods. A Si APD was compared with a Si photodiode with reference black body temperatures of 275 to 600°C, in terms of the mean output voltage and signal-to-noise ratio (SNR), measured at different APD gain values. We found that using both PSD and DD methods, the high internal gain of the Si APD achieved a lower minimum detection temperature in order to satisfy a specific minimum output voltage of the detector-preamplifier combination employed. The use of PSD over DD for the Si APD allowed for improved performance of the thermometer, with a lower minimum measurable temperature, as well as improvement in the SNR. For instance we found that at 350°C, the Si APD biased at 150 V using PSD can provide ∼ 88 times enhancement in the system SNR over that of a Si photodiode using DD. A corresponding temperature error of ±0.05°C was achieved using the APD with PSD compared to an error of ±2.75°C measured using the Si photodiode with DD.
Operational methods of thermodynamics. Volume 1 - Temperature measurement
Eder, F. X.
The principles of thermometry are examined, taking into account the concept of temperature, the Kelvin scale, the statistical theory of heat, negative absolute temperatures, the thermodynamic temperature scale, the thermodynamic temperature scale below 1 K, noise thermometry, temperature scales based on black-body radiation, acoustical thermometry, and the International Practical Temperature Scale 1968. Aspects of practical temperature measurement are discussed, giving attention to thermometers based on the expansion of a gas or a liquid, instruments utilizing the relative thermal expansion of two different metals, devices measuring the vapor pressure of a liquid, thermocouples, resistance thermometers, radiation pyrometers of various types, instruments utilizing the temperature dependence of a number of material characteristics, devices for temperature control, thermometer calibration, and aspects of thermometer installation and inertia. A description is presented of the approaches employed for the measurement of low temperatures.
The effect of clear sky radiation on crop surface temperature determined by thermal thermometry
International Nuclear Information System (INIS)
Svendsen, H.; Jensen, H.E.; Jensen, S.E.; Mogensen, V.O.
1990-01-01
By numerical integration of Planck's radiation function, a relationship between emitted radiation from a black body in the wavelength band 8–14 μm and the corresponding surface temperature was obtained. Using this relationship, an equation was developed relating the temperature error at different temperatures to the crop surface emissivity and clear sky radiation. It is concluded that the temperature error to be expected from neglect of clear sky radiation in the wavelength band 8–14μm in radiometric crop surface temperature determination is < 0.2 and 0.1 °C for crops with an emissivity > 0.96 and 0.98, respectively, for a leaf temperature range from 0 to 30°C
Manara, J.; Zipf, M.; Stark, T.; Arduini, M.; Ebert, H.-P.; Tutschke, A.; Hallam, A.; Hanspal, J.; Langley, M.; Hodge, D.; Hartmann, J.
2017-01-01
The objective of the EU project "Sensors Towards Advanced Monitoring and Control of Gas Turbine Engines (acronym STARGATE)" is the development of a suite of advanced sensors, instrumentation and related systems in order to contribute to the developing of the next generation of green and efficient gas turbine engines. One work package of the project deals with the design and development of a long wavelength infrared (LWIR) radiation thermometer for the non-contact measurement of the surface temperature of thermal barrier coatings (TBCs) during the operation of gas turbine engines. For opaque surfaces (e.g. metals or superalloys) radiation thermometers which are sensitive in the near or short wavelength infrared are used as state-of-the-art method for non-contact temperature measurements. But this is not suitable for oxide ceramic based TBCs (e.g. partially yttria stabilized zirconia) as oxide ceramics are semi-transparent in the near and short wavelength infrared spectral region. Fortunately the applied ceramic materials are non-transparent in the long wavelength infrared and additionally exhibit a high emittance in this wavelength region. Therefore, a LWIR pyrometer can be used for non-contact temperature measurements of the surfaces of TBCs as such pyrometers overcome the described limitation of existing techniques. For performing non-contact temperature measurements in gas turbines one has to know the infrared-optical properties of the applied TBCs as well as of the hot combustion gas in order to properly analyse the measurement data. For reaching a low uncertainty on the one hand the emittance of the TBC should be high (>0.9) in order to reduce reflections from the hot surrounding and on the other hand the absorbance of the hot combustion gas should be low (<0.1) in order to decrease the influence of the gas on the measured signal. This paper presents the results of the work performed by the authors with focus on the implementation of the LWIR pyrometer and the
Towards the development of high temperature comparison artifacts for radiation thermometry
Energy Technology Data Exchange (ETDEWEB)
Teixeira, R. N. [Inmetro, Duque de Caxias, RJ (Brazil); Machin, G. [NPL, Teddington (United Kingdom); Orlando, A. [PUC-Rio, Rio de Janeiro, RJ (Brazil)
2013-09-11
This paper describes the methodology and first results of the development of high temperature fixed point artifacts of unknown temperature suitable for scale comparison purposes. This study is being undertaken at the Thermal Metrology Division of Inmetro, Brazil, as part of PhD studies. In this initial phase of the study two identical cobalt carbon eutectic cells were constructed and one doped with a known amount of copper. This was an attempt to achieve a controlled change in the transition temperature of the alloy during melting. Copper was chosen due to the relatively simple phase diagram it forms with carbon and cobalt. The cobalt, in powder form, was supplied by Alfa Aesar at 99.998 % purity, and was mixed with carbon powder (1,9 % by weight) of 99.9999 % purity. Complete filling of the crucible took 6 steps and was performed in a vertical furnace with graphite heating elements, in an inert gas atmosphere. The temperature measurements were performed using a KE LP3 radiation thermometer, which was previously evaluated for spectral responsivity, linearity and size-of-source effect (SSE). During these measurements, the thermometer stability was periodically checked using a silver fixed point blackbody maintained in a three zone furnace. The main purpose of the first part of this study is to dope a series of Co-C blackbody with differing amounts of copper, in order to alter their temperatures whilst still retaining good melting plateau performance. The long-term stability of the adjusted transition temperatures will also be investigated. Other dopants will be studied as the research progresses, and thermo chemical modeling will be performed in an attempt to understand the change in temperature with dopant concentration and so help select suitable dopants in the future. The overall objective is to construct comparison artifacts that have good performance, in terms of plateau shape and long-term temperature stability, but with unknown temperatures. These can then be
Thermodynamic limits of energy harvesting from outgoing thermal radiation.
Buddhiraju, Siddharth; Santhanam, Parthiban; Fan, Shanhui
2018-04-17
We derive the thermodynamic limits of harvesting power from the outgoing thermal radiation from the ambient to the cold outer space. The derivations are based on a duality relation between thermal engines that harvest solar radiation and those that harvest outgoing thermal radiation. In particular, we derive the ultimate limit for harvesting outgoing thermal radiation, which is analogous to the Landsberg limit for solar energy harvesting, and show that the ultimate limit far exceeds what was previously thought to be possible. As an extension of our work, we also derive the ultimate limit of efficiency of thermophotovoltaic systems.
Johnson Noise Thermometry in the range 505 K to 933 K
Tew, Weston; Labenski, John; Nam, Sae Woo; Benz, Samuel; Dresselhaus, Paul; Martinis, John
2006-03-01
The International Temperature Scale of 1990 (ITS-90) is an artifact-based temperature scale, T90, designed to approximate thermodynamic temperature T. The thermodynamic errors of the ITS-90, characterized as the value of T-T90, only recently have been quantified by primary thermodynamic methods. Johnson Noise Thermometry (JNT) is a primary method which can be applied over wide temperature ranges, and NIST is currently using JNT to determine T-T90 in the range 505 K to 933 K, overlapping both acoustic gas-based and radiation-based thermometry. Advances in digital electronics have now made the computationally intensive processing required for JNT viable using noise voltage correlation in the frequency domain. We have also optimized the design of the 5-wire JNT temperature probes to minimize electromagnetic interference and transmission line effects. Statistical uncertainties under 50 μK/K are achievable using relatively modest bandwidths of ˜100 kHz. The NIST JNT system will provide critical data for T-T90 linking together the highly accurate acoustic gas-based data at lower temperatures with the higher-temperature radiation-based data, forming the basis for a new International Temperature Scale with greatly improved thermodynamic accuracy.
High Repetition Rate Thermometry System And Method
Chrystie, Robin
2015-05-14
A system and method for rapid thermometry using intrapulse spectroscopy can include a laser for propagating pulses of electromagnetic radiation to a region. Each of the pulses can be chirped. The pulses from the region can be detected. An intrapulse absorbance spectrum can be determined from the pulses. An instantaneous temperature of the region based on the intrapulse absorbance spectrum can be determined.
High Repetition Rate Thermometry System And Method
Chrystie, Robin; Farooq, Aamir
2015-01-01
A system and method for rapid thermometry using intrapulse spectroscopy can include a laser for propagating pulses of electromagnetic radiation to a region. Each of the pulses can be chirped. The pulses from the region can be detected. An intrapulse absorbance spectrum can be determined from the pulses. An instantaneous temperature of the region based on the intrapulse absorbance spectrum can be determined.
QED corrections to Planck's radiation law and photon thermodynamics
International Nuclear Information System (INIS)
Partovi, M.H.
1994-01-01
Leading corrections to Planck's radiation formula and other photon thermodynamic functions arising from the pair-mediated photon-photon interaction are calculated. This interaction is found to be attractive and to cause a small increase in occupation number for all modes and a corresponding correction to the equation of state. The results are valid for the range of temperatures well below T e =5.9 GK, the temperature equivalent to the electron mass, a range for which the photon gas is essentially free of pair-produced electrons and positrons. An interesting effect of these corrections is the behavior of the photon gas as an elastic medium and its ability to propagate density perturbations. It is found that the cosmic photon gas subsequent to electron-positron annihilation would have manifested these elastic properties were it not for the presence of the free electrons and their dominance of the photon thermodynamics
Fisenko, Anatoliy I.; Lemberg, Vladimir
2014-07-01
Using the explicit form of the functions to describe the monopole and dipole spectra of the Cosmic Microwave Background (CMB) radiation, the exact expressions for the temperature dependences of the radiative and thermodynamic functions, such as the total radiation power per unit area, total energy density, number density of photons, Helmholtz free energy density, entropy density, heat capacity at constant volume, and pressure in the finite range of frequencies v 1≤ v≤ v 2 are obtained. Since the dependence of temperature upon the redshift z is known, the obtained expressions can be simply presented in z representation. Utilizing experimental data for the monopole and dipole spectra measured by the COBE FIRAS instrument in the 60-600 GHz frequency interval at the temperature T=2.72548 K, the values of the radiative and thermodynamic functions, as well as the radiation density constant a and the Stefan-Boltzmann constant σ are calculated. In the case of the dipole spectrum, the constants a and σ, and the radiative and thermodynamic properties of the CMB radiation are obtained using the mean amplitude T amp=3.358 mK. It is shown that the Doppler shift leads to a renormalization of the radiation density constant a, the Stefan-Boltzmann constant σ, and the corresponding constants for the thermodynamic functions. The expressions for new astrophysical parameters, such as the entropy density/Boltzmann constant, and number density of CMB photons are obtained. The radiative and thermodynamic properties of the Cosmic Microwave Background radiation for the monopole and dipole spectra at redshift z≈1089 are calculated.
Primary Tunnel Junction Thermometry
International Nuclear Information System (INIS)
Pekola, Jukka P.; Holmqvist, Tommy; Meschke, Matthias
2008-01-01
We describe the concept and experimental demonstration of primary thermometry based on a four-probe measurement of a single tunnel junction embedded within four arrays of junctions. We show that in this configuration random sample specific and environment-related errors can be avoided. This method relates temperature directly to Boltzmann constant, which will form the basis of the definition of temperature and realization of official temperature scales in the future
Battuello, M.; Girard, F.; Florio, M.
2009-02-01
Four independent radiation temperature scales approximating the ITS-90 at 900 nm, 950 nm and 1.6 µm have been realized from the indium point (429.7485 K) to the copper point (1357.77 K) which were used to derive by extrapolation the transition temperature T90(Co-C) of the cobalt-carbon eutectic fixed point. An INRIM cell was investigated and an average value T90(Co-C) = 1597.20 K was found with the four values lying within 0.25 K. Alternatively, thermodynamic approximated scales were realized by assigning to the fixed points the best presently available thermodynamic values and deriving T(Co-C). An average value of 1597.27 K was found (four values lying within 0.25 K). The standard uncertainties associated with T90(Co-C) and T(Co-C) were 0.16 K and 0.17 K, respectively. INRIM determinations are compatible with recent thermodynamic determinations on three different cells (values lying between 1597.11 K and 1597.25 K) and with the result of a comparison on the same cell by an absolute radiation thermometer and an irradiance measurement with filter radiometers which give values of 1597.11 K and 1597.43 K, respectively (Anhalt et al 2006 Metrologia 43 S78-83). The INRIM approach allows the determination of both ITS-90 and thermodynamic temperature of a fixed point in a simple way and can provide valuable support to absolute radiometric methods in defining the transition temperature of new high-temperature fixed points.
International Nuclear Information System (INIS)
Zanchini, E.
1988-01-01
The definition of energy, in thermodynamics, is dependent by starting operative definitions of the basic concepts of physics on which it rests, such as those of isolated systems, ambient of a system, separable system and set of separable states. Then the definition of energy is rigorously extended to open systems. The extension gives a clear physical meaning to the concept of energy difference between two states with arbitrary different compositions
Wähmer, M.; Anhalt, K.; Hollandt, J.; Klein, R.; Taubert, R. D.; Thornagel, R.; Ulm, G.; Gavrilov, V.; Grigoryeva, I.; Khlevnoy, B.; Sapritsky, V.
2017-10-01
Absolute spectral radiometry is currently the only established primary thermometric method for the temperature range above 1300 K. Up to now, the ongoing improvements of high-temperature fixed points and their formal implementation into an improved temperature scale with the mise en pratique for the definition of the kelvin, rely solely on single-wavelength absolute radiometry traceable to the cryogenic radiometer. Two alternative primary thermometric methods, yielding comparable or possibly even smaller uncertainties, have been proposed in the literature. They use ratios of irradiances to determine the thermodynamic temperature traceable to blackbody radiation and synchrotron radiation. At PTB, a project has been established in cooperation with VNIIOFI to use, for the first time, all three methods simultaneously for the determination of the phase transition temperatures of high-temperature fixed points. For this, a dedicated four-wavelengths ratio filter radiometer was developed. With all three thermometric methods performed independently and in parallel, we aim to compare the potential and practical limitations of all three methods, disclose possibly undetected systematic effects of each method and thereby confirm or improve the previous measurements traceable to the cryogenic radiometer. This will give further and independent confidence in the thermodynamic temperature determination of the high-temperature fixed point's phase transitions.
Hawking radiation and thermodynamics of a Vaidya-Bonner black hole
International Nuclear Information System (INIS)
Niu Zhenfeng; Liu Wenbiao
2010-01-01
Using Parikh's tunneling method, the Hawking radiation on the apparent horizon of a Vaidya-Bonner black hole is calculated. When the back-reaction of particles is neglected, the thermal spectrum can be precisely obtained. Then, the black hole thermodynamics can be calculated successfully on the apparent horizon. When a relativistic perturbation is applied to the apparent horizon, a similar calculation can also lead to a purely thermal spectrum. The first law of thermodynamics can also be derived successfully at the new supersurface near the apparent horizon. When the event horizon is thought of as a deviation from the apparent horizon, the expressions of the characteristic position and temperature are consistent with the previous viewpoint which asserts that the thermodynamics should be based on the event horizon. It is concluded that the thermodynamics should be constructed exactly on the apparent horizon while the event horizon thermodynamics is just one of the perturbations near the apparent horizon.
Energy Technology Data Exchange (ETDEWEB)
Barbosa Junior, Wellington; Queiroga, Renan Nobrega Gadelha; Nascimento, Mairon Antonio Hosannah do; Souza, Carlson Pereira de; Chiavone-Filho, Osvaldo [Rio Grande do Norte Univ., Natal, RN (Brazil). Programa de Pos-graduacao em Engenharia Quimica]. E-mail: wbjunior@eq.ufrn.br
2003-07-01
In the petroleum industry a great problem found is the formation of solids during the production, transport and the storage, which are mainly paraffins. It was mainly used the thermometry for determination of paraffin formation, or the solubility of paraffin in the other hydrocarbon solvent as function of the composition. The gas chromatography was used to determine if the system light hydrocarbon and paraffin form solid solution, applying a simplified analytical method with thermostatized filtration and glass syringe. The experimental data obtained was used with the aid of the modified UNIFAC model for representing both the liquid and solid solution phases in equilibrium. (author)
Investigation of uncertainty components in Coulomb blockade thermometry
International Nuclear Information System (INIS)
Hahtela, O. M.; Heinonen, M.; Manninen, A.; Meschke, M.; Savin, A.; Pekola, J. P.; Gunnarsson, D.; Prunnila, M.; Penttilä, J. S.; Roschier, L.
2013-01-01
Coulomb blockade thermometry (CBT) has proven to be a feasible method for primary thermometry in every day laboratory use at cryogenic temperatures from ca. 10 mK to a few tens of kelvins. The operation of CBT is based on single electron charging effects in normal metal tunnel junctions. In this paper, we discuss the typical error sources and uncertainty components that limit the present absolute accuracy of the CBT measurements to the level of about 1 % in the optimum temperature range. Identifying the influence of different uncertainty sources is a good starting point for improving the measurement accuracy to the level that would allow the CBT to be more widely used in high-precision low temperature metrological applications and for realizing thermodynamic temperature in accordance to the upcoming new definition of kelvin
Investigation of uncertainty components in Coulomb blockade thermometry
Energy Technology Data Exchange (ETDEWEB)
Hahtela, O. M.; Heinonen, M.; Manninen, A. [MIKES Centre for Metrology and Accreditation, Tekniikantie 1, 02150 Espoo (Finland); Meschke, M.; Savin, A.; Pekola, J. P. [Low Temperature Laboratory, Aalto University, Tietotie 3, 02150 Espoo (Finland); Gunnarsson, D.; Prunnila, M. [VTT Technical Research Centre of Finland, Tietotie 3, 02150 Espoo (Finland); Penttilä, J. S.; Roschier, L. [Aivon Oy, Tietotie 3, 02150 Espoo (Finland)
2013-09-11
Coulomb blockade thermometry (CBT) has proven to be a feasible method for primary thermometry in every day laboratory use at cryogenic temperatures from ca. 10 mK to a few tens of kelvins. The operation of CBT is based on single electron charging effects in normal metal tunnel junctions. In this paper, we discuss the typical error sources and uncertainty components that limit the present absolute accuracy of the CBT measurements to the level of about 1 % in the optimum temperature range. Identifying the influence of different uncertainty sources is a good starting point for improving the measurement accuracy to the level that would allow the CBT to be more widely used in high-precision low temperature metrological applications and for realizing thermodynamic temperature in accordance to the upcoming new definition of kelvin.
Negative energy radiation and the second law of thermodynamics
International Nuclear Information System (INIS)
Deutsch, D.; Ottewill, A.C.; Sciama, D.W.
1982-01-01
It has been suggested that the second law of thermodynamics can be violated by processes involving the absorption by a hot body of negative energy fluxes of quantum origin. We show that this suggestion is false in the case of the process recently proposed by Davies, at least for a simple model of the hot body involved. Such a model body would not in fact be able to absorb the negative energy flux incident on it. We suggest that our argument can be generalized, and that there is no reason to doubt the second law. (orig.)
Directory of Open Access Journals (Sweden)
A.Y. Klimenko
2017-05-01
Full Text Available This work investigates the influence of directional properties of decoherence on kinetics rate equations. The physical reality is understood as a chain of unitary and decoherence events. The former are quantum-deterministic, while the latter introduce uncertainty and increase entropy. For interactions of matter and antimatter, two approaches are considered: symmetric decoherence, which corresponds to conventional symmetric (CP-invariant thermodynamics, and antisymmetric decoherence, which corresponds to antisymmetric (CPT-invariant thermodynamics. Radiation, in its interactions with matter and antimatter, is shown to be decoherence-neutral. The symmetric and antisymmetric assumptions result in different interactions of radiation with matter and antimatter. The theoretical predictions for these differences are testable by comparing absorption (emission of light by thermodynamic systems made of matter and antimatter. Canonical typicality for quantum mixtures is briefly discussed in Appendix A.
A new technique for direct traceability of contact thermometry Co-C eutectic cells to the ITS-90
Energy Technology Data Exchange (ETDEWEB)
Failleau, G.; Deuzé, T.; Bourson, F.; Briaudeau, S.; Sadli, M. [Laboratoire Commun de Métrologie LNE-Cnam, 61 rue du Landy 93210 La Plaine Saint Denis (France)
2013-09-11
The eutectic Co-C melting point is a promising system to serve as a thermometric fixed-point in the temperature range above 1084.62 °C (copper freezing point). During the last decade, LNE-Cnam has developed and characterized some fixed-point devices, based on eutectic Co-C alloy, for applications to contact and radiation thermometry. Above 962 °C, the ITS-90 is realized by radiation thermometry by the extrapolation from a Ag, Au or Cu fixed point using the Planck law for radiation. So the only way for assigning a temperature in the scale to a Co-C cell (∼1324 °C) is by radiation thermometry. An indirect method is commonly used to assign a temperature to a high-temperature fixed point (HTFP) cell designed for contact thermometry is to fill a pyrometric cell with the same mixture as the contact thermometry cell. In this case, the temperature assigned to the pyrometric cell is attributed to the contact cell. This paper describes a direct method allowing the determination of the melting temperature realized by a 'contact thermometry' Co-C cell by comparison to a 'radiation thermometry' Co-C cell whose melting temperature was assigned in accordance to the scale by extrapolation from the Cu point. In addition, the same Co-C cell is studied with a standard Pt/Pd thermocouple.
Matter-antimatter accounting, thermodynamics, and black-hole radiation
International Nuclear Information System (INIS)
Toussaint, D.; Treiman, S.B.; Wilczek, F.; Zee, A.
1979-01-01
We discuss several issues bearing on the observed asymmetry between matter and antimatter in the content of the universe, in particular, the possible role in this of Hawking radiation from black holes, with allowance for weak C- and T-violating interactions. We show that the radiation, species by species, can be asymmetric between baryons and antibaryons. However, if baryon number is microscopically conserved there cannot be a net flux of baryon number in the radiation. Black-hole absorption from a medium with net baryon number zero can drive the medium to an asymmetric state. On the other hand, if baryon conservation is violated, a net asymmetry can develop. This can arise through asymmetric gravitational interactions of the radiated particles, and conceivably, by radiation of long-lived particles which decay asymmetrically. In the absence of microscopic baryon conservation, asymmetries can also arise from collision processes generally,say in the early stages of the universe as a whole. However, no asymmetries can develop (indeed any ''initial'' ones are erased) insofar as the baryon-violating interactions are in thermal equilibrium, as they might well be in the dense, high-temperature stages of the very early universe. Thus particle collisions can generate asymmetries only when nonequilibrium effects driven by cosmological expansion come into play. A scenario for baryon-number generation suggested by superunified theories is discussed in some detail. Black-hole radiation is another highly nonequilibrium process which is very efficient in producing asymmetry, given microscopic C, T, and baryon-number violation
Radioactivity induced by neutrons: Enrico Fermi and a thermodynamic approach to radiative capture
De Gregorio, Alberto
2006-07-01
When Fermi learned that slow neutrons are much more effective than fast ones in inducing radioactivity, he explained this phenomenon by mentioning the well-known scattering cross section between neutrons and protons. At this early stage, he did not refer to the capture cross section by target nuclei. At the same time a thermodynamic approach to neutron-proton capture was being discussed by physicists: neutron capture was interpretated as the reverse of deuteron photodissociation and detailed balance among neutrons, protons, deuterons, and radiation was invoked. This thermodynamic approach might underlie Fermi's early explanation of the great efficiency of slow neutrons. Fermi repeatedly used a thermodynamic approach that had been used in describing some of the physical properties of conductors by Richardson and had been influential in Fermi's youth.
Energy and thermodynamic considerations involving electromagnetic zero-point radiation
International Nuclear Information System (INIS)
Cole, Daniel C.
1999-01-01
There has been recent speculation and controversy regarding whether electromagnetic zero-point radiation might be the next candidate in the progression of plentiful energy sources, ranging, for example, from hydrodynamic, chemical, and nuclear energy sources. Certainly, however, extracting energy from the vacuum seems counter intuitive to most people. Here, these ideas are clarified, drawing on simple and common examples. Known properties of electromagnetic zero-point energy are qualitatively discussed. An outlook on the success of utilizing this energy source is then discussed
Noise Thermometry with Two Weakly Coupled Bose-Einstein Condensates
International Nuclear Information System (INIS)
Gati, Rudolf; Hemmerling, Boerge; Foelling, Jonas; Albiez, Michael; Oberthaler, Markus K.
2006-01-01
Here we report on the experimental investigation of thermally induced fluctuations of the relative phase between two Bose-Einstein condensates which are coupled via tunneling. The experimental control over the coupling strength and the temperature of the thermal background allows for the quantitative analysis of the phase fluctuations. Furthermore, we demonstrate the application of these measurements for thermometry in a regime where standard methods fail. With this we confirm that the heat capacity of an ideal Bose gas deviates from that of a classical gas as predicted by the third law of thermodynamics
Noise thermometry with two weakly coupled Bose-Einstein condensates.
Gati, Rudolf; Hemmerling, Börge; Fölling, Jonas; Albiez, Michael; Oberthaler, Markus K
2006-04-07
Here we report on the experimental investigation of thermally induced fluctuations of the relative phase between two Bose-Einstein condensates which are coupled via tunneling. The experimental control over the coupling strength and the temperature of the thermal background allows for the quantitative analysis of the phase fluctuations. Furthermore, we demonstrate the application of these measurements for thermometry in a regime where standard methods fail. With this we confirm that the heat capacity of an ideal Bose gas deviates from that of a classical gas as predicted by the third law of thermodynamics.
Thermodynamics and Hawking radiation of five-dimensional rotating charged Goedel black holes
International Nuclear Information System (INIS)
Wu Shuangqing; Peng Junjin
2011-01-01
We study the thermodynamics of Goedel-type rotating charged black holes in five-dimensional minimal supergravity. These black holes exhibit some peculiar features such as the presence of closed timelike curves and the absence of a globally spatial-like Cauchy surface. We explicitly compute their energies, angular momenta, and electric charges that are consistent with the first law of thermodynamics. Besides, we extend the covariant anomaly cancellation method, as well as the approach of the effective action, to derive their Hawking fluxes. Both the methods of the anomaly cancellation and the effective action give the same Hawking fluxes as those from the Planck distribution for blackbody radiation in the background of the charged rotating Goedel black holes. Our results further support that Hawking radiation is a quantum phenomenon arising at the event horizon.
NRC Microwave Refractive Index Gas Thermometry Implementation Between 24.5 K and 84 K
Rourke, P. M. C.
2017-07-01
The implementation of microwave refractive index gas thermometry at the National Research Council between 24.5 K and 84 K is reported. A new gas-handling system for accurate control and measurement of experimental gas pressure has been constructed, and primary thermometry measurements have been taken using a quasi-spherical copper resonator and helium gas at temperatures corresponding to three defining fixed points of the International Temperature Scale of 1990 (ITS-90). These measurements indicate differences between the thermodynamic temperature T and ITS-90 temperature T_{90} of ( T - T_{90} ) = -0.60 ± 0.56 mK at T_{90} = 24.5561 K, ( T - T_{90} ) = -2.0 ± 1.3 mK at T_{90} = 54.3584 K, and ( T - T_{90} ) = -4.0 ± 2.9 mK at T_{90} = 83.8058 K. The present results at T_{90} = 24.5561 K and T_{90} = 83.8058 K agree with previously reported measurements from other primary thermometry techniques of acoustic gas thermometry and dielectric constant gas thermometry, and the result at T_{90} = 54.3584 K provides new information in a temperature region where there is a gap in other recent data sets.
Survey, applications, and prospects of Johnson noise thermometry
International Nuclear Information System (INIS)
Blalock, T.V.; Shepard, R.L.
1981-01-01
Significant progress in the field of Johnson noise thermometry has occurred since the 1971 survey of Kamper. This paper will review the foundation work of Johnson noise thermometry, survey the basic methods which do not utilize quantum devices for noise thermometry for industrial temperatures, and present some applications of noise thermometry in temperature scale metrology and process temperature instrumentation. 35 references
International Nuclear Information System (INIS)
Buhler, S.; Junquera, T.; Thermeau, J.P.
1999-01-01
The LHC project will use about 8000 thermometers to control the temperature of magnets. These thermometers will be operated at a temperature ranging from 1.6 K to 300 K and their calibration should be better than 0.25%. A small cryogenic thermometer calibration facility has been designed and tested. To select the cryogenic temperature sensors, an irradiation program is being performed to expose at high neutron fluences (>10 15 n/cm 2 ) the following thermometers: carbon resistors, Ge, thin film, RhFe and Pt. The resistance shifts under radiation of the different sensors at liquid helium are presented. (authors)
Single-cell photoacoustic thermometry
Gao, Liang; Wang, Lidai; Li, Chiye; Liu, Yan; Ke, Haixin; Zhang, Chi
2013-01-01
Abstract. A novel photoacoustic thermometric method is presented for simultaneously imaging cells and sensing their temperature. With three-seconds-per-frame imaging speed, a temperature resolution of 0.2°C was achieved in a photo-thermal cell heating experiment. Compared to other approaches, the photoacoustic thermometric method has the advantage of not requiring custom-developed temperature-sensitive biosensors. This feature should facilitate the conversion of single-cell thermometry into a routine lab tool and make it accessible to a much broader biological research community. PMID:23377004
Energy Technology Data Exchange (ETDEWEB)
Edler, F.; Kuhne, M.; Tegeler, E. [Bundesanstalt Physikalisch-Technische, Berlin (Germany)
2004-02-01
The thermodynamic temperature of the melting point of palladium in air was measured by noise thermometric methods. The temperature measurement was based on noise comparison using a two-channel arrangement to eliminate parasitic noises of electronic components by cross correlation. Three miniature fixed points filled with pure palladium (purity: {approx}99.99%, mass: {approx}90 g) were used to realize the melts of the fixed point metal. The measured melting temperature of palladium in air amounted to 1552.95 deg C {+-} 0.21 K (k = 2). This temperature is 0.45 K lower than the temperature of the melting point of palladium measured by radiation thermometry. (authors)
Thermodynamics and Cloud Radiative Effect from the First Year of GoAmazon
Collow, Allie Marquardt; Miller, Mark; Trabachino, Lynne
2015-01-01
Deforestation is an ongoing concern for the Amazon Rainforest of Brazil and associated changes to the land surface have been hypothesized to alter the climate in the region. A comprehensive set of meteorological observations at the surface and within the lower troposphere above Manacapuru, Brazil and data from the Modern Era Retrospective Analysis for Research and Applications Version 2 (MERRA-2) are used to evaluate the seasonal cycle of cloudiness, thermodynamics, and the radiation budget. While ample moisture is present in the Amazon Rainforest year round, the northward progression of the Hadley circulation during the dry season contributes to a drying of the middle troposphere and inhibits the formation of deep convection. This results in a reduction in cloudiness and precipitation as well as an increase in the height of the lifting condensation level, which is shown to have a negative correlation to the fraction of low clouds. Frequent cloudiness prevents solar radiation from reaching the surface and clouds are often reflective with high values of shortwave cloud radiative effect at the surface and top of the atmosphere. Cloud radiative effect is reduced during the dry season however the dry season surface shortwave cloud radiative effect is still double what is observed during the wet season in other tropical locations. Within the column, the impact of clouds on the radiation budget is more prevalent in the longwave part of the spectrum, with a net warming in the wet season.
Indirect Determination of the Thermodynamic Temperature of a Gold Fixed-Point Cell
Battuello, M.; Girard, F.; Florio, M.
2010-09-01
Since the value T 90(Au) was fixed on the ITS-90, some determinations of the thermodynamic temperature of the gold point have been performed which form, with other renormalized results of previous measurements by radiation thermometry, the basis for the current best estimates of ( T - T 90)Au = 39.9 mK as elaborated by the CCT-WG4. Such a value, even if consistent with the behavior of T - T 90 differences at lower temperatures, is quite influenced by the low values of T Au as determined with few radiometric measurements. At INRIM, an independent indirect determination of the thermodynamic temperature of gold was performed by means of a radiation thermometry approach. A fixed-point technique was used to realize approximated thermodynamic scales from the Zn point up to the Cu point. A Si-based standard radiation thermometer working at 900 nm and 950 nm was used. The low uncertainty presently associated to the thermodynamic temperature of fixed points and the accuracy of INRIM realizations, allowed scales with an uncertainty lower than 0.03 K in terms of the thermodynamic temperature to be realized. A fixed-point cell filled with gold, 99.999 % in purity, was measured, and its freezing temperature was determined by both interpolation and extrapolation. An average T Au = 1337.395 K was found with a combined standard uncertainty of 23 mK. Such a value is 25 mK higher than the presently available value as derived by the CCT-WG4 value of ( T - T 90)Au = 39.9 mK.
Single-contact tunneling thermometry
Maksymovych, Petro
2016-02-23
A single-contact tunneling thermometry circuit includes a tunnel junction formed between two objects. Junction temperature gradient information is determined based on a mathematical relationship between a target alternating voltage applied across the junction and the junction temperature gradient. Total voltage measured across the junction indicates the magnitude of the target alternating voltage. A thermal gradient is induced across the junction. A reference thermovoltage is measured when zero alternating voltage is applied across the junction. An increasing alternating voltage is applied while measuring a thermovoltage component and a DC rectification voltage component created by the applied alternating voltage. The target alternating voltage is reached when the thermovoltage is nullified or doubled by the DC rectification voltage depending on the sign of the reference thermovoltage. Thermoelectric current and current measurements may be utilized in place of the thermovoltage and voltage measurements. The system may be automated with a feedback loop.
Local thermodynamic equilibrium in a laser-induced plasma evidenced by blackbody radiation
Hermann, Jörg; Grojo, David; Axente, Emanuel; Craciun, Valentin
2018-06-01
We show that the plasma produced by laser ablation of solid materials in specific conditions has an emission spectrum that is characterized by the saturation of the most intense spectral lines at the blackbody radiance. The blackbody temperature equals the excitation temperature of atoms and ions, proving directly and unambiguously a plasma in local thermodynamic equilibrium. The present investigations take benefit from the very rich and intense emission spectrum generated by ablation of a nickel-chromium-molybdenum alloy. This alternative and direct proof of the plasma equilibrium state re-opens the perspectives of quantitative material analyses via calibration-free laser-induced breakdown spectroscopy. Moreover, the unique properties of this laser-produced plasma promote its use as radiation standard for intensity calibration of spectroscopic instruments.
Trade-off between information and disturbance in qubit thermometry
Seveso, Luigi; Paris, Matteo G. A.
2018-03-01
We address the trade-off between information and disturbance in qubit thermometry from the perspective of quantum estimation theory. Given a quantum measurement, we quantify information via the Fisher information of the measurement and disturbance via four different figures of merit, which capture different aspects (statistical, thermodynamical, geometrical) of the trade-off. For each disturbance measure, the efficient measurements, i.e., the measurements that introduce a disturbance not greater than any other measurement extracting the same amount of information, are determined explicitly. The family of efficient measurements varies with the choice of the disturbance measure. On the other hand, commutativity between the elements of the probability operator-valued measure (POVM) and the equilibrium state of the thermometer is a necessary condition for efficiency with respect to any figure of disturbance.
Buoncristiani, A. M.; Smith, B. T.; Byvik, C. E.
1982-01-01
Using general thermodynamic arguments, we analyze the conversion of the energy contained in the radiation from a blackbody to useful work by a quantum system. We show that the energy available for conversion is bounded above by the change in free energy in the incident and reradiated fields and that this free energy change depends upon the temperature of the receiving device. Universal efficiency curves giving the ultimate thermodynamic conversion efficiency of the quantum system are presented in terms of the blackbody temperature and the temperature and threshold energy of the quantum system. Application of these results is made to a variety of systems including biological photosynthetic, photovoltaic, and photoelectrochemical systems.
Energy Technology Data Exchange (ETDEWEB)
Ghate, Virendra P. [Argonne National Lab. (ANL), Argonne, IL (United States); Miller, Mark [Rutgers Univ., New Brunswick, NJ (United States)
2016-11-01
The overall goal of this project was to improve the understanding of marine boundary clouds by using data collected at the Atmospheric Radiation Measurement (ARM) sites, so that they can be better represented in global climate models (GCMs). Marine boundary clouds are observed regularly over the tropical and subtropical oceans. They are an important element of the Earth’s climate system because they have substantial impact on the radiation budget together with the boundary layer moisture, and energy transports. These clouds also have an impact on large-scale precipitation features like the Inter Tropical Convergence Zone (ITCZ). Because these clouds occur at temporal and spatial scales much smaller than those relevant to GCMs, their effects and the associated processes need to be parameterized in GCM simulations aimed at predicting future climate and energy needs. Specifically, this project’s objectives were to (1) characterize the surface turbulent fluxes, boundary layer thermodynamics, radiation field, and cloudiness associated with cumulus-topped marine boundary layers; (2) explore the similarities and differences in cloudiness and boundary layer conditions observed in the tropical and trade-wind regions; and (3) understand similarities and differences by using a simple bulk boundary layer model. In addition to working toward achieving the project’s three objectives, we also worked on understanding the role played by different forcing mechanisms in maintaining turbulence within cloud-topped boundary layers We focused our research on stratocumulus clouds during the first phase of the project, and cumulus clouds during the rest of the project. Below is a brief description of manuscripts published in peer-reviewed journals that describe results from our analyses.
Thermodynamics of post-growth annealing of cadmium zinc telluride nuclear radiation detectors
Adams, Aaron Lee
Nuclear Radiation Detectors are used for detecting, tracking, and identifying radioactive materials which emit high-energy gamma and X-rays. The use of Cadmium Zinc Telluride (CdZnTe) detectors is particularly attractive because of the detector's ability to operate at room temperature and measure the energy spectra of gamma-ray sources with a high resolution, typically less than 1% at 662 keV. While CdZnTe detectors are acceptable imperfections in the crystals limit their full market potential. One of the major imperfections are Tellurium inclusions generated during the crystal growth process by the retrograde solubility of Tellurium and Tellurium-rich melt trapped at the growth interface. Tellurium inclusions trap charge carriers generated by gamma and X-ray photons and thus reduce the portion of generated charge carriers that reach the electrodes for collection and conversion into a readable signal which is representative of the ionizing radiation's energy and intensity. One approach in resolving this problem is post-growth annealing which has the potential of removing the Tellurium inclusions and associated impurities. The goal of this project is to use experimental techniques to study the thermodynamics of Tellurium inclusion migration in post-growth annealing of CdZnTe nuclear detectors with the temperature gradient zone migration (TGZM) technique. Systematic experiments will be carried out to provide adequate thermodynamic data that will inform the engineering community of the optimum annealing parameters. Additionally, multivariable correlations that involve the Tellurium diffusion coefficient, annealing parameters, and CdZnTe properties will be analyzed. The experimental approach will involve systematic annealing experiments (in Cd vapor overpressure) on different sizes of CdZnTe crystals at varying temperature gradients ranging from 0 to 60°C/mm (used to migrate the Tellurium inclusion to one side of the crystal), and at annealing temperatures ranging
Wu, S. Q.; Cai, X.
2000-01-01
Four classical laws of black hole thermodynamics are extended from exterior (event) horizon to interior (Cauchy) horizon. Especially, the first law of classical thermodynamics for Kerr-Newman black hole (KNBH) is generalized to those in quantum form. Then five quantum conservation laws on the KNBH evaporation effect are derived in virtue of thermodynamical equilibrium conditions. As a by-product, Bekenstein-Hawking's relation $ S=A/4 $ is exactly recovered.
International Nuclear Information System (INIS)
Wu, S.Q.; Cai, X.
2000-01-01
Four classical laws of black-hole thermodynamics are extended from exterior (event) horizon to interior (Cauchy) horizon. Especially, the first law of classical thermodynamics for Kerr-Newman black hole (KNBH) is generalized to those in quantum form. Then five quantum conservation laws on the KNBH evaporation effect are derived in virtue of thermodynamical equilibrium conditions. As a by-product, Bekenstein-Haw king's relation S=A/4 is exactly recovered
Czech Academy of Sciences Publication Activity Database
Adineh, V.R.; Coufal, O.; Živný, Oldřich
2012-01-01
Roč. 40, č. 10 (2012), s. 2723-2735 ISSN 0093-3813 R&D Projects: GA ČR GAP205/11/2070 Institutional research plan: CEZ:AV0Z20430508 Keywords : Electrical discharge machining * net emission coefficient * nitrogen-iron reaction products * plasma modeling, radiative heat transfer * thermodynamic properties Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 0.868, year: 2012
International Nuclear Information System (INIS)
Hartmann, Juergen
2009-01-01
Well characterised sources of thermal radiation are essential for photometry, radiometry, and thermometry. They serve as reference radiators for the calibration of detectors and radiance sources. Thermal radiation sources are advantageous for this purpose compared to other radiance sources such as lamps or LEDs because they possess a continuous spectrum of the emitted spectral radiance, which, for blackbody sources, can be calculated analytically using Planck's law of radiation. For application in thermometry, blackbody sources starting from temperatures near absolute zero to temperatures up to 3000 deg. C are needed for the calibration of radiation thermometers. For application in photometry and radiometry high intensity sources of radiation in the visible and UV region of the optical spectrum were required. This latter requirement is met by blackbody sources at temperatures well above 2000 deg. C. An ideal reference source should always emit the same amount of radiation at any time of use. This is realised by fixed-point radiators. Such radiators are based on a phase transition of a substance, at high temperatures the melting and freezing points of metals. However, current metal fixed-points are limited to relatively low temperatures. In the present work innovative techniques necessary for research into high-temperature thermal radiation sources are developed and thoroughly described. Starting with variable temperature blackbody sources the techniques required are: Precise apertures determination and detailed characterisation of the applied optical detectors. The described techniques are then used to undertake research into the development of high-temperature fixed-points above the copper fixed-point for application in photometry, radiometry, and thermometry. Applying these sophisticated techniques it was shown that these new high-temperature fixed-points are reproducible and repeatable to better than 100 mK at temperatures up to nearly 3200 K. Finally, a forward
Progress in Noise Thermometry at 505 K and 693 K Using Quantized Voltage Noise Ratio Spectra
Tew, W. L.; Benz, S. P.; Dresselhaus, P. D.; Coakley, K. J.; Rogalla, H.; White, D. R.; Labenski, J. R.
2010-09-01
Technical advances and new results in noise thermometry at temperatures near the tin freezing point and the zinc freezing point using a quantized voltage noise source (QVNS) are reported. The temperatures are derived by comparing the power spectral density of QVNS synthesized noise with that of Johnson noise from a known resistance at both 505 K and 693 K. Reference noise is digitally synthesized so that the average power spectra of the QVNS match those of the thermal noise, resulting in ratios of power spectra close to unity in the low-frequency limit. Three-parameter models are used to account for differences in impedance-related time constants in the spectra. Direct comparison of noise temperatures to the International Temperature Scale of 1990 (ITS-90) is achieved in a comparison furnace with standard platinum resistance thermometers. The observed noise temperatures determined by operating the noise thermometer in both absolute and relative modes, and related statistics together with estimated uncertainties are reported. The relative noise thermometry results are combined with results from other thermodynamic determinations at temperatures near the tin freezing point to calculate a value of T - T 90 = +4(18) mK for temperatures near the zinc freezing point. These latest results achieve a lower uncertainty than that of our earlier efforts. The present value of T - T 90 is compared to other published determinations from noise thermometry and other methods.
International Nuclear Information System (INIS)
Casa, G.; Castrillo, A.; Galzerano, G.; Wehr, R.; Merlone, A.; Di Serafino, D.; Laporta, P.; Gianfrani, L.
2008-01-01
We report on a new optical implementation of primary gas thermometry based on laser-absorption spectrometry in the near infrared. The method consists in retrieving the Doppler broadening from highly accurate observations of the line shape of the R(12) ν 1 +2ν 2 0 +ν 3 transition in CO 2 gas at thermodynamic equilibrium. Doppler width measurements as a function of gas temperature, ranging between the triple point of water and the gallium melting point, allowed for a spectroscopic determination of the Boltzmann constant with a relative accuracy of ∼1.6x10 -4
Casa, G.; Castrillo, A.; Galzerano, G.; Wehr, R.; Merlone, A.; di Serafino, D.; Laporta, P.; Gianfrani, L.
2008-05-01
We report on a new optical implementation of primary gas thermometry based on laser-absorption spectrometry in the near infrared. The method consists in retrieving the Doppler broadening from highly accurate observations of the line shape of the R(12) ν1+2ν20+ν3 transition in CO2 gas at thermodynamic equilibrium. Doppler width measurements as a function of gas temperature, ranging between the triple point of water and the gallium melting point, allowed for a spectroscopic determination of the Boltzmann constant with a relative accuracy of ˜1.6×10-4.
Non-equilibrium thermodynamics of radiation-induced processes in solids
International Nuclear Information System (INIS)
Yurov, V.M.; Eshchanov, A.N.; Kuketaev, A.T.; Sidorenya, Yu.S.
2005-01-01
In the paper an item about a defect system response in solids on external action (temperature, pressure, light, etc.) from the point of view of non-equilibrium statistical thermodynamics is considered
Fast thermometry for superconducting rf cavity testing
International Nuclear Information System (INIS)
Orris, Darryl; Bellantoni, Leo; Carcagno, Ruben H.; Edwards, Helen; Harms, Elvin Robert; Khabiboulline, Timergali N.; Kotelnikov, Sergey; Makulski, Andrzej; Nehring, Roger; Pischalnikov, Yuriy; Fermilab
2007-01-01
Fast readout of strategically placed low heat capacity thermometry can provide valuable information of Superconducting RF (SRF) cavity performance. Such a system has proven very effective for the development and testing of new cavity designs. Recently, several resistance temperature detectors (RTDs) were installed in key regions of interest on a new 9 cell 3.9 GHz SRF cavity with integrated HOM design at FNAL. A data acquisition system was developed to read out these sensors with enough time and temperature resolution to measure temperature changes on the cavity due to heat generated from multipacting or quenching within power pulses. The design and performance of the fast thermometry system will be discussed along with results from tests of the 9 cell 3.9GHz SRF cavity
Fast thermometry for superconducting rf cavity testing
Energy Technology Data Exchange (ETDEWEB)
Orris, Darryl; Bellantoni, Leo; Carcagno, Ruben H.; Edwards, Helen; Harms, Elvin Robert; Khabiboulline, Timergali N.; Kotelnikov, Sergey; Makulski, Andrzej; Nehring, Roger; Pischalnikov, Yuriy; /Fermilab
2007-06-01
Fast readout of strategically placed low heat capacity thermometry can provide valuable information of Superconducting RF (SRF) cavity performance. Such a system has proven very effective for the development and testing of new cavity designs. Recently, several resistance temperature detectors (RTDs) were installed in key regions of interest on a new 9 cell 3.9 GHz SRF cavity with integrated HOM design at FNAL. A data acquisition system was developed to read out these sensors with enough time and temperature resolution to measure temperature changes on the cavity due to heat generated from multipacting or quenching within power pulses. The design and performance of the fast thermometry system will be discussed along with results from tests of the 9 cell 3.9GHz SRF cavity.
Signal processing method for Johnson noise thermometry
International Nuclear Information System (INIS)
Hwang, I. G.; Moon, B. S.; Kinser, Rpger
2003-01-01
The development of Johnson Noise Thermometry requires a high sensitive preamplifier circuit to pick up the temperature-related noise on the sensing element. However, the random noise generated in this amplification circuit causes a significant erroneous influence to the measurement. This paper describes signal processing mechanism of the Johnson Noise Thermometry system which is underway of development in collaboration between KAERI and ORNL. It adopts two identical amplifier channels and utilizes a digital signal processing technique to remove the independent noise of each channel. The CPSD(Cross Power Spectral Density) function is used to cancel the independent noise and the differentiation of narrow or single frequency peak from the CPSD data separates the common mode electromagnetic interference noise
Schrödinger, Erwin
1952-01-01
Nobel Laureate's brilliant attempt to develop a simple, unified standard method of dealing with all cases of statistical thermodynamics - classical, quantum, Bose-Einstein, Fermi-Dirac, and more.The work also includes discussions of Nernst theorem, Planck's oscillator, fluctuations, the n-particle problem, problem of radiation, much more.
Energy Technology Data Exchange (ETDEWEB)
Feng, Y.; Kotamarthi, V. R.; Coulter, R.; Zhao, C.; Cadeddu, M.
2016-01-01
Aerosol radiative effects and thermodynamic responses over South Asia are examined with the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) for March 2012. Model results of aerosol optical depths (AODs) and extinction profiles are analyzed and compared to satellite retrievals and two ground-based lidars located in northern India. The WRF-Chem model is found to heavily underestimate the AOD during the simulated pre-monsoon month and about 83 % of the model's low bias is due to aerosol extinctions below ~2 km. Doubling the calculated aerosol extinctions below 850 hPa generates much better agreement with the observed AOD and extinction profiles averaged over South Asia. To separate the effect of absorption and scattering properties, two runs were conducted: in one run (Case I), the calculated scattering and absorption coefficients were increased proportionally, while in the second run (Case II) only the calculated aerosol scattering coefficient was increased. With the same AOD and extinction profiles, the two runs produce significantly different radiative effects over land and oceans. On the regional mean basis, Case I generates 48 % more heating in the atmosphere and 21 % more dimming at the surface than Case II. Case I also produces stronger cooling responses over the land from the longwave radiation adjustment and boundary layer mixing. These rapid adjustments offset the stronger radiative heating in Case I and lead to an overall lower-troposphere cooling up to -0.7 K day^{−1}, which is smaller than that in Case II. Over the ocean, direct radiative effects dominate the heating rate changes in the lower atmosphere lacking such surface and lower atmosphere adjustments due to fixed sea surface temperature, and the strongest atmospheric warming is obtained in Case I. Consequently, atmospheric dynamics (boundary layer heights and meridional circulation) and thermodynamic processes (water vapor and cloudiness) are shown to
Directory of Open Access Journals (Sweden)
Y. Feng
2016-01-01
Full Text Available Aerosol radiative effects and thermodynamic responses over South Asia are examined with the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem for March 2012. Model results of aerosol optical depths (AODs and extinction profiles are analyzed and compared to satellite retrievals and two ground-based lidars located in northern India. The WRF-Chem model is found to heavily underestimate the AOD during the simulated pre-monsoon month and about 83 % of the model's low bias is due to aerosol extinctions below ∼ 2 km. Doubling the calculated aerosol extinctions below 850 hPa generates much better agreement with the observed AOD and extinction profiles averaged over South Asia. To separate the effect of absorption and scattering properties, two runs were conducted: in one run (Case I, the calculated scattering and absorption coefficients were increased proportionally, while in the second run (Case II only the calculated aerosol scattering coefficient was increased. With the same AOD and extinction profiles, the two runs produce significantly different radiative effects over land and oceans. On the regional mean basis, Case I generates 48 % more heating in the atmosphere and 21 % more dimming at the surface than Case II. Case I also produces stronger cooling responses over the land from the longwave radiation adjustment and boundary layer mixing. These rapid adjustments offset the stronger radiative heating in Case I and lead to an overall lower-troposphere cooling up to −0.7 K day−1, which is smaller than that in Case II. Over the ocean, direct radiative effects dominate the heating rate changes in the lower atmosphere lacking such surface and lower atmosphere adjustments due to fixed sea surface temperature, and the strongest atmospheric warming is obtained in Case I. Consequently, atmospheric dynamics (boundary layer heights and meridional circulation and thermodynamic processes (water vapor and
Saxena, A K
2014-01-01
Heat and thermodynamics aims to serve as a textbook for Physics, Chemistry and Engineering students. The book covers basic ideas of Heat and Thermodynamics, Kinetic Theory and Transport Phenomena, Real Gases, Liquafaction and Production and Measurement of very Low Temperatures, The First Law of Thermodynamics, The Second and Third Laws of Thermodynamics and Heat Engines and Black Body Radiation. KEY FEATURES Emphasis on concepts Contains 145 illustrations (drawings), 9 Tables and 48 solved examples At the end of chapter exercises and objective questions
Energy Technology Data Exchange (ETDEWEB)
Savchuk, Ol.A. [Física i Cristallografia de Materials i Nanomaterials (FiCMA-FiCNA) and EMaS, Universitat Rovira i Virgili (URV), c/Marcellí Domingo s/n E-43007, Tarragona (Spain); Carvajal, J.J., E-mail: joanjosep.carvajal@urv.cat [Física i Cristallografia de Materials i Nanomaterials (FiCMA-FiCNA) and EMaS, Universitat Rovira i Virgili (URV), c/Marcellí Domingo s/n E-43007, Tarragona (Spain); Pujol, M.C.; Massons, J. [Física i Cristallografia de Materials i Nanomaterials (FiCMA-FiCNA) and EMaS, Universitat Rovira i Virgili (URV), c/Marcellí Domingo s/n E-43007, Tarragona (Spain); Haro-González, P. [Fluorescence Imaging Group, Departamento de Física de Materiales, Facultad de Ciencias, Universidad Autónoma de Madrid, C/Francisco Tomás y Valiente 7, E-28049 Madrid (Spain); Martínez, O.; Jiménez, J. [GdS-Optronlab, Departamento Física Materia Condensada, Universidad de Valladolid, Edificio I+D, Paseo de Belén 11, 47011 Valladolid (Spain); Aguiló, M.; Díaz, F. [Física i Cristallografia de Materials i Nanomaterials (FiCMA-FiCNA) and EMaS, Universitat Rovira i Virgili (URV), c/Marcellí Domingo s/n E-43007, Tarragona (Spain)
2016-01-15
Here we analyze alternative luminescence thermometry techniques to FIR, such as intensity ratio luminescence thermometry between the emission arising from two electronic levels that are not necessarily thermally coupled, but that show different evolutions with temperature, and lifetime luminescence nanothermometry in (Ho,Tm,Yb):KLu(WO{sub 4}){sub 2} and (Er,Yb):NaY{sub 2}F{sub 5}O nanoparticles. (Ho,Tm,Yb):KLu(WO{sub 4}){sub 2} nanoparticles exhibited a maximum relative sensitivity of 0.61% K{sup −1}, similar to that achievable in Er-doped systems, which are the upconverting systems presenting the highest sensitivity. From another side, (Er,Yb):NaY{sub 2}F{sub 5}O nanocrystals show great potentiality as thermal sensors at the nanoscale for moderate temperatures due to the incorporation of additional non-radiative relaxation mechanisms that shorten the emission lifetime generated by the oxygen present in the structure when compared to (Er,Yb):NaYF{sub 4} nanoparticles exhibiting the highest upconversion efficiency. We used those nanoparticles for ex-vivo temperature determination by laser induced heating in chicken breast using lifetime-based thermometry. The results obtained indicate that these techniques might constitute alternatives to FIR with potential applications for the determination of moderate temperatures, with sensitivities comparable to those that can be achieved by FIR or even higher. - Highlights: • Other nanothermometry techniques than FIR proposed with upconversion nanoparticles. • Energy transfer between different lanthanide ions can be used for thermometry. • Lifetime measurements can constitute also a tool for temperature determination.
Two Fiber Optical Fiber Thermometry
Jones, Mathew R.; Farmer, Jeffery T.; Breeding, Shawn P.
2000-01-01
An optical fiber thermometer consists of an optical fiber whose sensing tip is given a metallic coating. The sensing tip of the fiber is essentially an isothermal cavity, so the emission from this cavity will be approximately equal to the emission from a blackbody. Temperature readings are obtained by measuring the spectral radiative heat flux at the end of the fiber at two wavelengths. The ratio of these measurements and Planck's Law are used to infer the temperature at the sensing tip. Optical fiber thermometers have high accuracy, excellent long-term stability and are immune to electromagnetic interference. In addition, they can be operated for extended periods without requiring re-calibration. For these reasons. it is desirable to use optical fiber thermometers in environments such as the International Space Station. However, it has recently been shown that temperature readings are corrupted by emission from the fiber when extended portions of the probe are exposed to elevated temperatures. This paper will describe several ways in which the reading from a second fiber can be used to correct the corrupted temperature measurements. The accuracy and sensitivity to measurement uncertainty will be presented for each method.
Nanometer scale thermometry in a living cell
Kucsko, G.; Maurer, P. C.; Yao, N. Y.; Kubo, M.; Noh, H. J.; Lo, P. K.; Park, H.; Lukin, M. D.
2014-01-01
Sensitive probing of temperature variations on nanometer scales represents an outstanding challenge in many areas of modern science and technology1. In particular, a thermometer capable of sub-degree temperature resolution over a large range of temperatures as well as integration within a living system could provide a powerful new tool for many areas of biological, physical and chemical research; possibilities range from the temperature-induced control of gene expression2–5 and tumor metabolism6 to the cell-selective treatment of disease7,8 and the study of heat dissipation in integrated circuits1. By combining local light-induced heat sources with sensitive nanoscale thermometry, it may also be possible to engineer biological processes at the sub-cellular level2–5. Here, we demonstrate a new approach to nanoscale thermometry that utilizes coherent manipulation of the electronic spin associated with nitrogen-vacancy (NV) color centers in diamond. We show the ability to detect temperature variations down to 1.8 mK (sensitivity of 9mK/Hz) in an ultra-pure bulk diamond sample. Using NV centers in diamond nanocrystals (nanodiamonds, NDs), we directly measure the local thermal environment at length scales down to 200 nm. Finally, by introducing both nanodiamonds and gold nanoparticles into a single human embryonic fibroblast, we demonstrate temperature-gradient control and mapping at the sub-cellular level, enabling unique potential applications in life sciences. PMID:23903748
Velocity navigator for motion compensated thermometry.
Maier, Florian; Krafft, Axel J; Yung, Joshua P; Stafford, R Jason; Elliott, Andrew; Dillmann, Rüdiger; Semmler, Wolfhard; Bock, Michael
2012-02-01
Proton resonance frequency shift thermometry is sensitive to breathing motion that leads to incorrect phase differences. In this work, a novel velocity-sensitive navigator technique for triggering MR thermometry image acquisition is presented. A segmented echo planar imaging pulse sequence was modified for velocity-triggered temperature mapping. Trigger events were generated when the estimated velocity value was less than 0.2 cm/s during the slowdown phase in parallel to the velocity-encoding direction. To remove remaining high-frequency spikes from pulsation in real time, a Kalman filter was applied to the velocity navigator data. A phantom experiment with heating and an initial volunteer experiment without heating were performed to show the applicability of this technique. Additionally, a breath-hold experiment was conducted for comparison. A temperature rise of ΔT = +37.3°C was seen in the phantom experiment, and a root mean square error (RMSE) outside the heated region of 2.3°C could be obtained for periodic motion. In the volunteer experiment, a RMSE of 2.7°C/2.9°C (triggered vs. breath hold) was measured. A novel velocity navigator with Kalman filter postprocessing in real time significantly improves the temperature accuracy over non-triggered acquisitions and suggests being comparable to a breath-held acquisition. The proposed technique might be clinically applied for monitoring of thermal ablations in abdominal organs.
MR thermometry for monitoring tumor ablation
International Nuclear Information System (INIS)
Senneville, Baudouin D. de; Quesson, Bruno; Dragonu, Iulius; Moonen, Chrit T.W.; Mougenot, Charles; Grenier, Nicolas
2007-01-01
Local thermal therapies are increasingly used in the clinic for tissue ablation. During energy deposition, the actual tissue temperature is difficult to estimate since physiological processes may modify local heat conduction and energy absorption. Blood flow may increase during temperature increase and thus change heat conduction. In order to improve the therapeutic efficiency and the safety of the intervention, mapping of temperature and thermal dose appear to offer the best strategy to optimize such interventions and to provide therapy endpoints. MRI can be used to monitor local temperature changes during thermal therapies. On-line availability of dynamic temperature mapping allows prediction of tissue death during the intervention based on semi-empirical thermal dose calculations. Much progress has been made recently in MR thermometry research, and some applications are appearing in the clinic. In this paper, the principles of MRI temperature mapping are described with special emphasis on methods employing the temperature dependency of the water proton resonance frequency. Then, the prospects and requirements for widespread applications of MR thermometry in the clinic are evaluated. (orig.)
Institute of Scientific and Technical Information of China (English)
无
2009-01-01
Chen et al.proposed the concepts of effective temperature of photon and entropy constant of photon in a recent paper [Chen Z S,Mo S P,Hu P.Recent progress in thermodynamics of radiation―exergy of radiation,effective temperature of photon and entropy constant of photon.Sci China Ser E-Tech Sci,2008,51(8):1096―1109] by enduing a single photon with macroscale thermodynamic parameters such as exergy and entropy.This paper argues that applying these concepts and their inferences to macro-scale thermodynamic system will lead to the results which conflict with macroscale thermodynamic laws.This means that the concepts of effective temperature of photon and entropy constant of photon are not correct.
Action of radiation and serotin on DNA and satellite DNA of thermodynamic parameters
International Nuclear Information System (INIS)
Sanaya, T.V.
1987-01-01
A study was made on the effect of X-rays on thermal denaturation of DNA and satellite DNA of cattle spleen against the background of 10 -3 M serotonin influence. The minimal dose at which the damage of satellite DNA is observed, is equal to 38 Gy; similar damage of DNA requires the double dose. Serotonin with 10 -3 M concentration doesn't change thermodynamic DNA characteristics, but its presence in the moment of irradiation even at 152 Gy dose reveals the clearly pronounced protection effect on satellite DNA damage
International Nuclear Information System (INIS)
Tomic, Simonida L.J.; Micic, Maja M.; Filipovic, Jovanka M.; Suljovrujic, Edin H.
2007-01-01
The copolymeric hydrogels based on 2-hydroxyethyl methacrylate (HEMA) and itaconic acid (IA) were synthesized by gamma radiation induced radical polymerization. Swelling and thermodynamic properties of PHEMA and copolymeric P(HEMA/IA) hydrogels with different IA contents (2, 3.5 and 5 mol%) were studied in a wide pH and temperature range. Initial studies of so-prepared hydrogels show interesting pH and temperature sensitivity in swelling and drug release behavior. Special attention was devoted to temperature investigations around physiological temperature (37 deg. C), where small changes in temperature significantly influence swelling and drug release of these hydrogels. Due to maximum swelling of hydrogels around 40 deg. C, the P(HEMA/IA) hydrogel containing 5 mol% of IA without and with drug-antibiotic (gentamicin) were investigated at pH 7.40 and in the temperature range 25-42 deg. C, in order to evaluate their potential for medical applications
International Nuclear Information System (INIS)
Giangrande, Scott E.; Feng, Zhe; Jensen, Michael P.; Comstock, Jennifer M.; Johnson, Karen L.
2017-01-01
Routine cloud, precipitation and thermodynamic observations collected by the Atmospheric Radiation Measurement (ARM) Mobile Facility (AMF) and Aerial Facility (AAF) during the 2-year US Department of Energy (DOE) ARM Observations and Modeling of the Green Ocean Amazon (GoAmazon2014/5) campaign are summarized. These observations quantify the diurnal to large-scale thermodynamic regime controls on the clouds and precipitation over the undersampled, climatically important Amazon basin region. The extended ground deployment of cloud-profiling instrumentation enabled a unique look at multiple cloud regimes at high temporal and vertical resolution. This longer-term ground deployment, coupled with two short-term aircraft intensive observing periods, allowed new opportunities to better characterize cloud and thermodynamic observational constraints as well as cloud radiative impacts for modeling efforts within typical Amazon wet and dry seasons.
Survey on Johnson noise thermometry for temperature instrumentation
International Nuclear Information System (INIS)
Hwang, I. K.; Kim, Y. K.; Kim, J. S.; Moon, B. S.
2002-01-01
Johnson Noise Thermometry is an drift-free temperature measurement method which is able to maintain the best accuracy without calibration for a long period. Resistance Temperature Detectors (RTDs) and Thermocouples used widely in power plants have the drift problem which causes a measurement error. Despite the advantage of Johnson Noise thermometry, it has not been used because it is very sensitive to electromagnetic noise and environment. It also requires more complicated signal processing methods. This paper presents the characteristics of Johnson Noise thermometry and various implementation method proposed over the past decades time period. The key factor in development of a noise thermometer is how to extract the tiny noise signal from the sensor and discriminate out the unnecessary noise interference from the environments. The new digital technology of fast signal processing skill will useful to challenge the existing problems fir commercialization of noise thermometry
A Comparison of Surface Infrared with Rectal Thermometry in Dogs.
Omóbòwálé, T O; Ogunro, B N; Odigie, E A; Otuh, P I; Olugasa, B O
2017-12-30
Accurate determination of temperature is crucial in the diagnosis of febrile conditions. Although fewer techniques have proven as useful and reliable a predictor of core body temperature as the rectal thermometry, the process of obtaining the rectal temperature could be stressful in dogs. The infrared thermometry is a noncontact device used for measuring body temperature, with advantages which include speed, convenience, and reduced stress to the animals and reduced occupational risks to the animal handler. Therefore, there is the need to assess the consistency and agreement between non-contact infrared thermometry and traditional rectal thermometry in body temperature estimation. This study compared and assessed the sensitivity of non-contact infrared thermometer used on the forehead and nasal regions respectively with that of a rectal thermometer in dogs for body temperature estimation. One hundred and thirty (130) dogs presented for veterinary attention at the Veterinary Teaching Hospital (VTH), University of Ibadan, Nigeria were enrolled in this study during August to September 2014, irrespective of sex, age, breed or health status. Temperatures of dogs presented at the clinic were obtained using both multiple non-contact infrared thermometric measures obtained in the nasal and frontal head regions; and by rectal temperature. A multivariate cross-matrix analysis was used to assess the difference in measurements between the rectal thermometry and non-contact infrared thermometry. Descriptive statistics was used to compare variation and trend regularity of the nasal and fore-head infrared thermometry. A logistic regression of the difference in measurements was computed at 95% confidence interval and P<0.05. The mean difference revealed that the rectal temperature was 5.330C higher than the non-contact infrared forehead-based temperature and 7.570C higher than nasal-based temperature measurements respectively. The Bland-Altman (B-A) plot showed that the 95% limits
International Nuclear Information System (INIS)
Gil, J.M.; Rodriguez, R.; Martel, P.; Florido, R.; Rubiano, J.G.; Mendoza, M.A.; Minguez, E.
2013-01-01
In this work the spectrally resolved, multigroup and mean radiative opacities of carbon plasmas are calculated for a wide range of plasma conditions which cover situations where corona, local thermodynamic and non-local thermodynamic equilibrium regimes are found. An analysis of the influence of the thermodynamic regime on these magnitudes is also carried out by means of comparisons of the results obtained from collisional-radiative, corona or Saha–Boltzmann equations. All the calculations presented in this work were performed using ABAKO/RAPCAL code. -- Highlights: ► Spectrally resolved, multigroup and mean radiative opacities of carbon plasmas are calculated. ► Corona, local thermodynamic and non-local thermodynamic equilibrium regimes are analyzed. ► Simulations performed using the computational package ABAKO/RAPCAL. ► A criterion for the establishment of the thermodynamic regime is proposed.
Electronic thermometry in tunable tunnel junction
Maksymovych, Petro
2016-03-15
A tunable tunnel junction thermometry circuit includes a variable width tunnel junction between a test object and a probe. The junction width is varied and a change in thermovoltage across the junction with respect to the change in distance across the junction is determined. Also, a change in biased current with respect to a change in distance across the junction is determined. A temperature gradient across the junction is determined based on a mathematical relationship between the temperature gradient, the change in thermovoltage with respect to distance and the change in biased current with respect to distance. Thermovoltage may be measured by nullifying a thermoelectric tunneling current with an applied voltage supply level. A piezoelectric actuator may modulate the probe, and thus the junction width, to vary thermovoltage and biased current across the junction. Lock-in amplifiers measure the derivatives of the thermovoltage and biased current modulated by varying junction width.
Refractiry metal monocrystals in high temperature thermometry
International Nuclear Information System (INIS)
Kuritnyk, I.P.
1988-01-01
The regularities of changes in thermoelectric properties of refractory metals in a wide temperature range (300-2300 K) depending on their structural state and impurities, are generalized. It is found that the main reasons for changes in thermo-e.m.f. of refractory metals during their operation in various media are diffusion processes and local microvoltages appearing in nonhomogeneous thermoelectrodes. It is shown that microstructure formation and control of impurities in thermometric materials permit to improve considerably the metrologic parameters of thermal transformers. Tungsten and molybdenum with monocrystalline structure with their high stability of properties, easy to manufacture and opening new possibilities in high-temperature contact measurement are used in thermometry for the first time
Noise thermometry - a new temperature measuring method
International Nuclear Information System (INIS)
Brixy, H.; Hecker, R.; Rittinghaus, K.F.
1975-01-01
The thermal Johnson-Niquist noise is the basis of noise thermometry. This temperature measuring method is, e.g., of interest insofar as the noise thermometer gives absolute values as a primary thermometer and is in principle extensively independent of environmental influences and material properties. The resistance values of the measuring probe are about 10 Ohm to a few kOhm. The demands of electronics are high, the self-noise of the measuring apparatus must be as small as possible; a comparative measuring method is advantageous. 1 to 2,500 K are given as a possible temperature range. An accuracy of 0.1% could be achieved in laboratory measurements. Temperature measurements to be used in operation in a few nuclear reactors are mentioned. (HP/LH) [de
International Nuclear Information System (INIS)
Ke-Xia, Jiang; Dan-Tao, Peng; Jun, Feng; San-Min, Ke
2009-01-01
Relations between the tunneling rate and the unified first law of thermodynamics at the apparent horizon of the FRW universe are investigated. The tunneling rate arises as a consequence of the unified first law of thermodynamics in such a dynamical system. Analysis shows how the tunneling is intimately connected with the unified first law of thermodynamics through the principle of conservation of energy. (general)
The thermodynamic solar energy
International Nuclear Information System (INIS)
Rivoire, B.
2002-04-01
The thermodynamic solar energy is the technic in the whole aiming to transform the solar radiation energy in high temperature heat and then in mechanical energy by a thermodynamic cycle. These technic are most often at an experimental scale. This paper describes and analyzes the research programs developed in the advanced countries, since 1980. (A.L.B.)
International Nuclear Information System (INIS)
Hwang, Jeong Ui; Jang, Jong Jae; Jee, Jong Gi
1987-01-01
The contents of this book are thermodynamics on the law of thermodynamics, classical thermodynamics and molecule thermodynamics, basics of molecule thermodynamics, molecule and assembly partition function, molecule partition function, classical molecule partition function, thermodynamics function for ideal assembly in fixed system, thermodynamics function for ideal assembly in running system, Maxwell-Boltzmann's law of distribution, chemical equilibrium like calculation of equilibrium constant and theory of absolute reaction rate.
Polymer coated fiber Bragg grating thermometry for microwave hyperthermia.
Saxena, Indu Fiesler; Hui, Kaleo; Astrahan, Melvin
2010-09-01
Measuring tissue temperature distribution during electromagnetically induced hyperthermia (HT) is challenging. High resistance thermistors with nonmetallic leads have been used successfully in commercial HT systems for about three decades. The single 1 mm thick temperature sensing element is mechanically moved to measure tissue temperature distributions. By employing a single thermometry probe containing a fixed linear sensor array temperature, distributions during therapy can be measured with greater ease. While the first attempts to use fiber Bragg grating (FBG) technology to obtain multiple temperature points along a single fiber have been reported, improvement in the detection system's stability were needed for clinical applications. The FBG temperature sensing system described here has a very high temporal stability detection system and an order of magnitude faster readout than commercial systems. It is shown to be suitable for multiple point fiber thermometry during microwave hyperthermia when compared to conventional mechanically scanning probe HT thermometry. A polymer coated fiber Bragg grating (PFBG) technology is described that provides a number of FBG thermometry locations along the length of a single optical fiber. The PFBG probe developed is tested under simulated microwave hyperthermia treatment to a tissue equivalent phantom. Two temperature probes, the multiple PFBG sensor and the Bowman probe, placed symmetrically with respect to a microwave antenna in a tissue phantom are subjected to microwave hyperthermia. Measurements are made at start of HT and 85 min later, when a 6 degrees C increase in temperature is registered by both probes, as is typical in clinical HT therapy. The optical fiber multipoint thermometry probe performs highly stable, real-time thermometry updating each multipoint thermometry scan over a 5 cm length every 2 s. Bowman probe measurements are acquired simultaneously for comparison. In addition, the PFBG sensor's detection
International Nuclear Information System (INIS)
Travaille, G.; Peyrusse, O.; Bousquet, B.; Canioni, L.; Pierres, K. Michel-Le; Roy, S.
2009-01-01
We present a collisional-radiative approach of the theoretical analysis of laser-induced breakdown spectroscopy (LIBS) plasmas. This model, which relies on an optimized effective potential atomic structure code, was used to simulate a pure aluminum plasma. The description of aluminum involved a set of 220 atomic levels representative of three different stages of ionization (Al 0 , Al + and Al ++ ). The calculations were carried for stationary plasmas, with input parameters (n e and T e ) ranging respectively between 10 13-18 cm -3 and 0.3-2 eV. A comparison of our atomic data with some existing databases is made. The code was mainly developed to address the validity of the local thermodynamic equilibrium (LTE) assumption. For usual LIBS plasma parameters, we did not reveal a sizeable discrepancy of the radiative equilibrium of the plasma towards LTE. For cases where LTE was firmly believed to stand, the Boltzmann plot outputs of this code were used to check the physical accuracy of the Boltzmann temperature, as it is currently exploited in several calibration-free laser-induced breakdown spectroscopy (CF-LIBS) studies. In this paper, a deviation ranging between 10 and 30% of the measured Boltzmann temperature to the real excitation temperature is reported. This may be due to the huge dispersion induced on the line emissivities, on which the Boltzmann plots are based to extract this parameter. Consequences of this fact on the CF-LIBS procedure are discussed and further insights to be considered for the future are introduced.
Directory of Open Access Journals (Sweden)
Paolo Ruzza
2015-05-01
Full Text Available Many neurodegenerative diseases, including Huntington’s, Alzheimer’s and Parkinson’s diseases, are characterized by protein misfolding and aggregation. The capability of trehalose to interfere with protein misfolding and aggregation has been recently evaluated by several research groups. In the present work, we studied, by means of synchrotron radiation circular dichroism (SRCD spectroscopy, the dose-effect of trehalose on α-synuclein conformation and/or stability to probe the capability of this osmolyte to interfere with α-synuclein’s aggregation. Our study indicated that a low trehalose concentration stabilized α-synuclein folding much better than at high concentration by blocking in vitro α-synuclein’s polymerisation. These results suggested that trehalose could be associated with other drugs leading to a new approach for treating Parkinson’s and other brain-related diseases.
Hayat, T.; Khan, M. Ijaz; Qayyum, Sumaira; Alsaedi, A.; Khan, M. Imran
2018-03-01
This research addressed entropy generation for MHD stagnation point flow of viscous nanofluid over a stretching surface. Characteristics of heat transport are analyzed through nonlinear radiation and heat generation/absorption. Nanoliquid features for Brownian moment and thermophoresis have been considered. Fluid in the presence of constant applied inclined magnetic field is considered. Flow problem is mathematically modeled and governing expressions are changed into nonlinear ordinary ones by utilizing appropriate transformations. The effects of pertinent variables on velocity, nanoparticle concentration and temperature are discussed graphically. Furthermore Brownian motion and thermophoresis effects on entropy generation and Bejan number have been examined. Total entropy generation is inspected through various flow variables. Consideration is mainly given to the convergence process. Velocity, temperature and mass gradients at the surface of sheet are calculated numerically.
Dhara, Chirag; Renner, Maik; Kleidon, Axel
2015-04-01
The convective transport of heat and moisture plays a key role in the climate system, but the transport is typically parameterized in models. Here, we aim at the simplest possible physical representation and treat convective heat fluxes as the result of a heat engine. We combine the well-known Carnot limit of this heat engine with the energy balances of the surface-atmosphere system that describe how the temperature difference is affected by convective heat transport, yielding a maximum power limit of convection. This results in a simple analytic expression for convective strength that depends primarily on surface solar absorption. We compare this expression with an idealized grey atmosphere radiative-convective (RC) model as well as Global Circulation Model (GCM) simulations at the grid scale. We find that our simple expression as well as the RC model can explain much of the geographic variation of the GCM output, resulting in strong linear correlations among the three approaches. The RC model, however, shows a lower bias than our simple expression. We identify the use of the prescribed convective adjustment in RC-like models as the reason for the lower bias. The strength of our model lies in its ability to capture the geographic variation of convective strength with a parameter-free expression. On the other hand, the comparison with the RC model indicates a method for improving the formulation of radiative transfer in our simple approach. We also find that the latent heat fluxes compare very well among the approaches, as well as their sensitivity to surface warming. What our comparison suggests is that the strength of convection and their sensitivity in the climatic mean can be estimated relatively robustly by rather simple approaches.
International Nuclear Information System (INIS)
Yoo, W. J.; Jang, K. W.; Seo, J. K.; Moon, J.; Han, K. T.; Lee, B.; Park, B. G.
2011-01-01
Any warm object by measuring the emitted infrared (IR) radiation. The radiometers using infrared optical fibers are based on the relationship between the temperature of a heat source and the quality and the quantity of an IR radiation. To measure physical properties including a temperature, optical fiber-based sensor has many advantages, such as small size, low cost, high resolution, remote sensing and immunity to electromagnetic radiation over conventional electrical sensors. In this study, we carried out the feasibility study on the development of an embedded IR fiber-optic sensor for thermometry of the secondary water system in a nuclear power plant. The 2-channel embedded fiberoptic temperature sensor was fabricated using two identical IR optical fibers for accurate thermometry without complicated calibration processes. To decide accurate temperature of the water, we measured the difference between the IR radiations emitted from the two temperature sensing probes according to the temperature variation of the water
High temperature measurement by noise thermometry
International Nuclear Information System (INIS)
Decreton, M.C.
1982-06-01
Noise thermometry has received a lot of attention for measurements of temperatures in the high range around 1000-2000 deg. K. For these measurements, laboratory type experiments have been mostly performed. These have shown the interest of the technique when long term stability, high precision and insensibility to external conditions are concerned. This is particularly true for measurements in nuclear reactors where important drifts due to irradiation effects are experienced with other measurement techniques, as thermocouple for instance. Industrial noise thermometer experiments have not been performed extensively up to now. The subject of the present study is the development of a 1800 deg. K noise thermometer for nuclear applications. The measurement method is based on a generalized noise power approach. The rms noise voltage (Vsub(s)) and noise current (Isub(s)) are successively measured on the resistive sensor. The same quantities are also measured on a dummy short circuited probe (Vsub(d) and Isub(d)). The temperature is then deduced from these measured values by the following formula: cTsub(s) = (Vsub(s) 2 - Vsub(d) 2 )(Vsub(s)/Isub(s) - Vsub(d)/Isub(d)) - 1 , where c is a constant and Tsub(s) the absolute temperature of the sensor. This approach has the particular advantage of greatly reducing the sensibility to environmental perturbations on the leads and to the influence of amplifier noise sources. It also eliminates the necessity of resistance measurement and keeps the electronic circuits as simple as possible
A thermocouple thermometry system for ultrasound hyperthermia
International Nuclear Information System (INIS)
Ozarka, M.; Gharakhani, A.; Magin, R.; Cain, C.
1984-01-01
A thermometry system designed to be used in the treatment of cancer by ultrasound hyperthermia is described. The system monitors tumor temperatures using 16 type T (copper-constantan) thermocouples and is controlled by a 12 MHz Intel 8031 microcomputer. An analog circuit board contains the thermocouple amplifiers, an analog multiplexer, scaling circuitry, and an analog to digital converter. A digital board contains the Intel 8031, program memory, data memory, as well as circuitry for control and data communications. Communication with the hyperthermia system control computer is serially by RS-232 with selectable baud rate. Since the thermocouple amplifiers may have slight differences in gain and offset, a calibrated offset is added to a lookup table value to obtain the proper display temperature to within +- 0.1 0 C. The calibration routine, implemented in software, loads a nonvolatile random access memory chip with the proper offset values based on the outputs of each thermocouple channel at known temperatures which bracket a range of interest
Ultrasonic thermometry for nuclear power plants
International Nuclear Information System (INIS)
Saravana Kumar, S.; Arunraj, A.L.R.; Swaminathan, K.
2013-01-01
Ultrasonic transducer provides a method of measurement of temperature in industrial tanks and boilers containing different liquids with varied salt content. This method is used to measure the average temperature continuously where other traditional methods available do not offer. Traditional methods used for temperature measurement like infrared thermometers, thermocouples, measures temperature at a single location. Numerous thermocouples are to be fixed at various part of the boiler in order to measure the temperature of the entire boiler, which incurs high cost. Reliability of the system decreases, with increasing number of thermocouples. When they fail at a point, the time incurred in finding the faulty part or faulty thermocouple is high. Ultrasonic transducer provides continuous measurement for all different characteristic liquids with higher accuracy and lesser response time. Fault location and clearance time is also less in ultrasonic measurement method, since only a couple of transducers used for the entire boiler structure. Additionally ultrasonic thermometry along support measuring electronic system can be built of low cost. (author)
International Nuclear Information System (INIS)
Alp, E. Ercan; Sturhahn, Wolfgang; Toellner, Thomas S.; Zhao, Jiyong; Leu, Bogdan M.
2012-01-01
Discovery of Moessbauer effect in a nuclear transition was a remarkable development. It revealed how long-lived nuclear states with relatively low energies in the kiloelectron volt (keV) region can be excited without recoil. This new effect had a unique feature involving a coupling between nuclear physics and solid-state physics, both in terms of physics and sociology. Physics coupling originates from the fact that recoilless emission and absorption or resonance is only possible if the requirement that nuclei have to be bound in a lattice with quantized vibrational states is fulfilled, and that the finite electron density on the nucleus couples to nuclear degrees of freedom leading to hyperfine interactions. thus, Moessbauer spectroscopy allows peering into solid-state effects using unique nuclear transitions. Sociological aspects of this coupling had been equally startling and fruitful. The interaction between diverse scientific communities, who learned to use Moessbauer spectroscopy proved to be very valuable. For example, biologists, geologists, chemists, physics, materials scientists, and archeologists, all sharing a common spectroscopic technique, also learned to appreciate the beauty and intricacies of each other's fields. As a laboratory-based technique, Moessbauer spectroscopy matured by the end of the 1970s. Further exciting developments took place when accelerator-based techniques were employed, like synchrotron radiation or 'in-beam'Moessbauer experiments with implanted radioactive ions. More recently, two Moessbauer spectrometers on the surface of the Mars kept the technique vibrant and viable up until present time. In this chapter, the authors look into some of the unique aspects of nuclear resonance excited with synchrotron radiation as a probe of condensed matter, including magnetism, valence, vibrations, and lattice dynamics, and review the development of nuclear resonance inelastic x-ray scattering (NRIXS) and synchrotron Moessbauer spectroscopy
Saïd, F.; Corsmeier, U.; Kalthoff, N.; Kottmeier, C.; Lothon, M.; Wieser, A.; Hofherr, T.; Perros, P.
2005-03-01
Among seven airplanes involved in the Experience sur Site pour COntraindre les Modèles de Pollution atmosphérique et de Transport d'Emission (ESCOMPTE) experiment in 2001, four measured classical meteorological parameters, radiation fluxes, trace gases and turbulence (for three among four): the Dornier 128 from the Institut für Meteorologie und Klimaforschung, the Fokker 27 ARAT from the Institut National des Sciences de l'Univers, the Merlin 4 and Piper Aztec 23 from Météo France. This paper presents the results of intercomparison flights between three pairs of aircraft. The results are very similar for mean parameters except for the horizontal wind measurements provided by the Merlin that showed a problem that is probably linked to the measurement of the aircraft velocity. Further investigation is required to know whether corrections are possible or not for these wind measurements. Turbulence is studied along two legs over a flat and homogeneous area: in spite of the heterogeneity of the measured functions (one leg is close to the top of the boundary layer), the comparison is rather good. The relative accuracy of the data provided to the data base is given. It easily allows to use the huge amount of aircraft data collected during the experiment with very few restrictions. We underline some points where efforts should be borne for future experiments: wind coupling between Inertial Navigation System data and Global Positioning System (GPS) data, CO and NO x measurements.
Guichard, F.; Kergoat, L.; Mougin, E.; Timouk, F.; Bock, O.; Hiernaux, P.
2009-04-01
A good knowledge of surface fluxes and atmospheric low levels is central to improving our understanding of the West African monsoon. This study provides a quantitative analysis of the peculiar seasonal and diurnal cycles of surface thermodynamics and radiative fluxes encountered in Central Sahel. It is based on a multi-year dataset collected in the Malian Gourma over a sandy soil at 1.5°W-15.3°N (a site referred to as Agoufou) with an automated weather station and a sunphotometer (AERONET), complemented by observations from the AMMA field campaign. The seasonal cycle of this Tropical region is characterized by a broad maximum of temperature in May, following the first minimum of the solar zenith angle by a few weeks, when Agoufou lies within the West African Heat-Low, and a late summer maximum of equivalent potential temperature within the core of the monsoon season, around the second yearly maximum of solar zenith angle, as the temperature reaches its Summer minimum. More broadly, subtle balances between surface air temperature and moisture fields are found on a range of scales. For instance, during the monsoon, apart from August, their opposite daytime fluctuations (warming, drying) lead to an almost flat diurnal cycle of the equivalent potential temperature at the surface. This feature stands out in contrast to other more humid continental regions. Here, the strong dynamics associated with the transition from a drier hot Spring to a brief cooler wet tropical Summer climate involves very large transformations of the diurnal cycles. The Summer increase of surface net radiation, Rnet, is also strong; typically 10-day mean Rnet reaches about 5 times its Winter minimum (~30 W.m-2) in August (~150 W.m-2). A major feature revealed by observations is that this increase is mostly driven by modifications of the surface upwelling fluxes shaped by rainfall events and vegetation phenology (surface cooling and darkening), while the direct impact of atmospheric changes on
Performance of Different Light Sources for the Absolute Calibration of Radiation Thermometers
Martín, M. J.; Mantilla, J. M.; del Campo, D.; Hernanz, M. L.; Pons, A.; Campos, J.
2017-09-01
The evolving mise en pratique for the definition of the kelvin (MeP-K) [1, 2] will, in its forthcoming edition, encourage the realization and dissemination of the thermodynamic temperature either directly (primary thermometry) or indirectly (relative primary thermometry) via fixed points with assigned reference thermodynamic temperatures. In the last years, the Centro Español de Metrología (CEM), in collaboration with the Instituto de Óptica of Consejo Superior de Investigaciones Científicas (IO-CSIC), has developed several setups for absolute calibration of standard radiation thermometers using the radiance method to allow CEM the direct dissemination of the thermodynamic temperature and the assignment of the thermodynamic temperatures to several fixed points. Different calibration facilities based on a monochromator and/or a laser and an integrating sphere have been developed to calibrate CEM's standard radiation thermometers (KE-LP2 and KE-LP4) and filter radiometer (FIRA2). This system is based on the one described in [3] placed in IO-CSIC. Different light sources have been tried and tested for measuring absolute spectral radiance responsivity: a Xe-Hg 500 W lamp, a supercontinuum laser NKT SuperK-EXR20 and a diode laser emitting at 6473 nm with a typical maximum power of 120 mW. Their advantages and disadvantages have been studied such as sensitivity to interferences generated by the laser inside the filter, flux stability generated by the radiant sources and so forth. This paper describes the setups used, the uncertainty budgets and the results obtained for the absolute temperatures of Cu, Co-C, Pt-C and Re-C fixed points, measured with the three thermometers with central wavelengths around 650 nm.
International Nuclear Information System (INIS)
Duthil, P
2014-01-01
The goal of this paper is to present a general thermodynamic basis that is useable in the context of superconductivity and particle accelerators. The first part recalls the purpose of thermodynamics and summarizes its important concepts. Some applications, from cryogenics to magnetic systems, are covered. In the context of basic thermodynamics, only thermodynamic equilibrium is considered
Energy Technology Data Exchange (ETDEWEB)
Duthil, P [Orsay, IPN (France)
2014-07-01
The goal of this paper is to present a general thermodynamic basis that is useable in the context of superconductivity and particle accelerators. The first part recalls the purpose of thermodynamics and summarizes its important concepts. Some applications, from cryogenics to magnetic systems, are covered. In the context of basic thermodynamics, only thermodynamic equilibrium is considered.
Measurement of Two-Phase Flow and Heat Transfer Parameters using Infrared Thermometry
Kim, Tae-Hoon; Kommer, Eric; Dessiatoun, Serguei; Kim, Jungho
2012-01-01
A novel technique to measure heat transfer and liquid film thickness distributions over relatively large areas for two-phase flow and heat transfer phenomena using infrared (IR)thermometry is described. IR thermometry is an established technology that can be used to measure temperatures when optical access to the surface is available in the wavelengths of interest. In this work, a midwave IR camera (3.6-5.1 microns) is used to determine the temperature distribution within a multilayer consisting of a silicon substrate coated with a thin insulator. Since silicon is largely transparent to IR radiation, the temperature of the inner and outer walls of the multilayer can be measured by coating selected areas with a thin, IR opaque film. If the fluid used is also partially transparent to IR, the flow can be visualized and the liquid film thickness can be measured. The theoretical basis for the technique is given along with a description of the test apparatus and data reduction procedure. The technique is demonstrated by determining the heat transfer coefficient distributions produced by droplet evaporation and flow boiling heat transfer.
Multiwavelength Thermometry at High Temperature: Why It is Advantageous to Work in the Ultraviolet
Girard, F.; Battuello, M.; Florio, M.
2014-07-01
In principle, multiwavelength radiation thermometry allows one to correctly measure the temperature of surfaces of unknown and varying surface emissivity. Unfortunately, none of the practical realizations proposed in the past proved to be sufficiently reliable because of a strong influence of the errors arising from incorrect modeling of the emissivity and of the limited number of operating wavelengths. The use of array detectors allows a high degree of flexibility both in terms of number and spectral position of the working wavelength bands. In the case of applications at high temperatures, i.e., near 2000 C or above, an analysis of the theoretical measuring principles of multiwavelength thermometry, suggests the opportunity of investigating the possible advantages in extending the operating wavelengths toward the ultraviolet region. To this purpose, a simulation program was developed which allows investigation of the effect of different influencing parameters. This paper presents a brief theoretical introduction and practical analysis of the method. The best choices are derived in terms of the different influencing parameters and data relative to the simulation of both real materials and fictitious emissivity curves and have been studied and analyzed with different emissivity models to check the robustness of the method.
International Nuclear Information System (INIS)
Lim, Gyeong Hui
2008-03-01
This book consists of 15 chapters, which are basic conception and meaning of statistical thermodynamics, Maxwell-Boltzmann's statistics, ensemble, thermodynamics function and fluctuation, statistical dynamics with independent particle system, ideal molecular system, chemical equilibrium and chemical reaction rate in ideal gas mixture, classical statistical thermodynamics, ideal lattice model, lattice statistics and nonideal lattice model, imperfect gas theory on liquid, theory on solution, statistical thermodynamics of interface, statistical thermodynamics of a high molecule system and quantum statistics
Rodrigue, Kamiko Kouemeni Jean; Saleh, Mahamat; Thomas, Bouetou Bouetou; Kofane, Timoleon Crepin
2018-05-01
In this paper, we investigate the thermodynamics and Hawking radiation of Schwarzschild black hole with quintessence-like matter and deficit solid angle. From the metric of the black hole, we derive the expressions of temperature and specific heat using the laws of black hole thermodynamics. Using the null geodesics method and Parikh-Wilczeck tunneling method, we derive the expressions of Boltzmann factor and the change of Bekenstein-Hawking entropy for the black hole. The behaviors of the temperature, specific heat, Boltzmann factor and the change of Bekenstein entropy versus the deficit solid angle (ɛ 2) and the density of static spherically symmetric quintessence-like matter (ρ 0) were explicitly plotted. The results show that, when the deficit solid angle (ɛ 2) and the density of static spherically symmetric quintessence-like matter at r=1 (ρ 0) vanish (ρ 0=ɛ =0), these four thermodynamics quantities are reduced to those obtained for the simple case of Schwarzschild black hole. For low entropies, the presence of quintessence-like matter induces a first order phase transition of the black hole and for the higher values of the entropies, we observe the second order phase transition. When increasing ρ 0, the transition points are shifted to lower entropies. The same thing is observed when increasing ɛ 2. In the absence of quintessence-like matter (ρ 0=0), these transition phenomena disappear. Moreover the rate of radiation decreases when increasing ρ 0 or (ɛ ^2).
Jara, Amanda L; Hanson, Jarod M; Gabbard, Jon D; Johnson, Scott K; Register, Emery T; He, Biao
2016-01-01
During disease outbreaks, core temperature is a useful health metric in swine, due to the presence of pyrexia especially during the acute phase of infection. Despite technologic advances in other facets of swine production and health management, rectal thermometry continues to be the ‘gold standard’ for measuring core body temperature. However, for various reasons, collecting rectal temperatures can be difficult and unsafe depending on the housing modality. In addition, the delay between insertion of the rectal thermometer and obtaining a reading can affect measurement accuracy, especially when the pig requires physical restraint. Clearly safer, faster, and more accurate and precise temperature acquisition methods that necessitate minimal or no handling of swine are needed. We therefore compared rectal thermometers, subcutaneous microchips, and an inexpensive handheld infrared thermometer by measuring the core body temperature of 24 male castrated piglets at random intervals over a 5-wk period. The core body temperature (mean ± 1 SD) was 39.3 ± 0.5 °C by rectal thermometry, 39.0 ± 0.7 °C by microchip transponder, and 34.3 ± 1.0 °C by infrared thermometry; these 3 values differed significantly. Although the readings obtain by using infrared thermometry were numerically lower than those from the other methods, it is arguably the safest method for assessing the core temperature of swine and showed strong relative correlation with rectal temperature. PMID:27657715
Vasil'chenko, Zh V.; Azharonok, V. V.; Filatova, I. I.; Shimanovich, V. D.; Golubev, V. S.; Zabelin, A. M.
1996-09-01
Emission spectroscopy methods were used in an investigation of thermodynamic parameters of a surface plasma formed by the action of cw CO2 laser radiation of (2-5)×106 W cm-2 intensity on stainless steel in a protective He or Ar atmosphere. The spatiotemporal structure and pulsation characteristics of the plasma plume were used to determine the fields of the plasma electron density and temperature.
Thermodynamics of nuclear materials
International Nuclear Information System (INIS)
1979-01-01
Full text: The science of chemical thermodynamics has substantially contributed to the understanding of the many problems encountered in nuclear and reactor technology. These problems include reaction of materials with their surroundings and chemical and physical changes of fuels. Modern reactor technology, by its very nature, has offered new fields of investigations for the scientists and engineers concerned with the design of nuclear fuel elements. Moreover, thermodynamics has been vital in predicting the behaviour of new materials for fission as well as fusion reactors. In this regard, the Symposium was organized to provide a mechanism for review and discussion of recent thermodynamic investigations of nuclear materials. The Symposium was held in the Juelich Nuclear Research Centre, at the invitation of the Government of the Federal Republic of Germany. The International Atomic Energy Agency has given much attention to the thermodynamics of nuclear materials, as is evidenced by its sponsorship of four international symposia in 1962, 1965, 1967, and 1974. The first three meetings were primarily concerned with the fundamental thermodynamics of nuclear materials; as with the 1974 meeting, this last Symposium was primarily aimed at the thermodynamic behaviour of nuclear materials in actual practice, i.e., applied thermodynamics. Many advances have been made since the 1974 meeting, both in fundamental and applied thermodynamics of nuclear materials, and this meeting provided opportunities for an exchange of new information on this topic. The Symposium dealt in part with the thermodynamic analysis of nuclear materials under conditions of high temperatures and a severe radiation environment. Several sessions were devoted to the thermodynamic studies of nuclear fuels and fission and fusion reactor materials under adverse conditions. These papers and ensuing discussions provided a better understanding of the chemical behaviour of fuels and materials under these
International Nuclear Information System (INIS)
Garcia-Moliner, F.
1975-01-01
Basic thermodynamics of a system consisting of two bulk phases with an interface. Solid surfaces: general. Discussion of experimental data on surface tension and related concepts. Adsorption thermodynamics in the Gibbsian scheme. Adsorption on inert solid adsorbents. Systems with electrical charges: chemistry and thermodynamics of imperfect crystals. Thermodynamics of charged surfaces. Simple models of charge transfer chemisorption. Adsorption heat and related concepts. Surface phase transitions
Directory of Open Access Journals (Sweden)
Yuriy Puzachenko
2013-09-01
Full Text Available The paper discusses methods of evaluating thermodynamic properties of landscape cover based on multi-spectral measurements by the Landsat satellites. Authors demonstrate how these methods could be used for studying functionality of landscapes and for spatial interpolation of Flux NET system measurements.
Live-cell thermometry with nitrogen vacancy centers in nanodiamonds
Jayakumar, Harishankar; Fedder, Helmut; Chen, Andrew; Yang, Liudi; Li, Chenghai; Wrachtrup, Joerg; Wang, Sihong; Meriles, Carlos
The ability to measure temperature is typically affected by a tradeoff between sensitivity and spatial resolution. Good thermometers tend to be bulky systems and hence are ill-suited for thermal sensing with high spatial localization. Conversely, the signal resulting from nanoscale temperature probes is often impacted by noise to a level where the measurement precision becomes poor. Adding to the microscopist toolbox, the nitrogen vacancy (NV) center in diamond has recently emerged as a promising platform for high-sensitivity nanoscale thermometry. Of particular interest are applications in living cells because diamond nanocrystals are biocompatible and can be chemically functionalized to target specific organelles. Here we report progress on the ability to probe and compare temperature within and between living cells using nanodiamond-hosted NV thermometry. We focus our study on cancerous cells, where atypical metabolic pathways arguably lead to changes in the way a cell generates heat, and thus on its temperature profile.
Thermometry of ultracold atoms by electromagnetically induced transparency
Peters, Thorsten; Wittrock, Benjamin; Blatt, Frank; Halfmann, Thomas; Yatsenko, Leonid P.
2012-06-01
We report on systematic numerical and experimental investigations of electromagnetically induced transparency (EIT) to determine temperatures in an ultracold atomic gas. The technique relies on the strong dependence of EIT on atomic motion (i.e., Doppler shifts), when the relevant atomic transitions are driven with counterpropagating probe and control laser beams. Electromagnetically induced transparency permits thermometry with satisfactory precision over a large temperature range, which can be addressed by the appropriate choice of Rabi frequency in the control beam. In contrast to time-of-flight techniques, thermometry by EIT is fast and nondestructive, i.e., essentially it does not affect the ultracold medium. In an experimental demonstration we apply both EIT and time-of-flight measurements to determine temperatures along different symmetry axes of an anisotropic ultracold gas. As an interesting feature we find that the temperatures in the anisotropic atom cloud vary in different directions.
Thermometry system development for thermoradiotherapy of deep-seated tumours
Fadeev, A. M.; Ivanov, S. M.; Perelstein, E. A.; Polozov, S. M.
2017-12-01
Therapeutic hyperthermia (including RF hyperthermia) in combination with radiotherapy (called thermoradiotherapy) is one of widely used contemporary cancer treatment methods. The independent electron linac and RF system or their combinations are necessary for effective therapy. Whole-body hyperthermia is used for treatment of metastatic cancer that was spread throughout the body, regional one is used for treatment of part of the body (for instance leg or abdominal cavity). Local hyperthermia with characteristic size of heating volume of 20-100 mm permits to heat tumour without overheating of healthy tissues. The thermometry of deep suited tissues during the hyperthermia process is an important and complex task. Invasive methods as thermistors, optical sensors or thermo-couples can not be widely used because all of them are able to transport tumor cells to the healthy region of the patient body. Distant methods of the temperature measurement such, as radiothermometry and acoustic thermometry can not be used for tissues seated deeper than 5-7 cm. One of possible ways to solve the problem of temperature measurement of the deep suited tissues is discussed in this article: it was proposed to use the same electrodes for RF hyperthermia and thermometry. As known electrodynamics characteristics of tissues are sufficiently depends on temperature. It was proposed to use this effect for active radiothermometry in local hyperthermia. Two opposite RF dipoles can be used as generator and receiver of pick-up signal.
Müller, Ingo
1993-01-01
Physicists firmly believe that the differential equations of nature should be hyperbolic so as to exclude action at a distance; yet the equations of irreversible thermodynamics - those of Navier-Stokes and Fourier - are parabolic. This incompatibility between the expectation of physicists and the classical laws of thermodynamics has prompted the formulation of extended thermodynamics. After describing the motifs and early evolution of this new branch of irreversible thermodynamics, the authors apply the theory to mon-atomic gases, mixtures of gases, relativistic gases, and "gases" of phonons and photons. The discussion brings into perspective the various phenomena called second sound, such as heat propagation, propagation of shear stress and concentration, and the second sound in liquid helium. The formal mathematical structure of extended thermodynamics is exposed and the theory is shown to be fully compatible with the kinetic theory of gases. The study closes with the testing of extended thermodynamics thro...
Thermodynamics of Accelerating Black Holes.
Appels, Michael; Gregory, Ruth; Kubizňák, David
2016-09-23
We address a long-standing problem of describing the thermodynamics of an accelerating black hole. We derive a standard first law of black hole thermodynamics, with the usual identification of entropy proportional to the area of the event horizon-even though the event horizon contains a conical singularity. This result not only extends the applicability of black hole thermodynamics to realms previously not anticipated, it also opens a possibility for studying novel properties of an important class of exact radiative solutions of Einstein equations describing accelerated objects. We discuss the thermodynamic volume, stability, and phase structure of these black holes.
A Ratiometric Method for Johnson Noise Thermometry Using a Quantized Voltage Noise Source
Nam, S. W.; Benz, S. P.; Martinis, J. M.; Dresselhaus, P.; Tew, W. L.; White, D. R.
2003-09-01
Johnson Noise Thermometry (JNT) involves the measurement of the statistical variance of a fluctuating voltage across a resistor in thermal equilibrium. Modern digital techniques make it now possible to perform many functions required for JNT in highly efficient and predictable ways. We describe the operational characteristics of a prototype JNT system which uses digital signal processing for filtering, real-time spectral cross-correlation for noise power measurement, and a digitally synthesized Quantized Voltage Noise Source (QVNS) as an AC voltage reference. The QVNS emulates noise with a constant spectral density that is stable, programmable, and calculable in terms of known parameters using digital synthesis techniques. Changes in analog gain are accounted for by alternating the inputs between the Johnson noise sensor and the QVNS. The Johnson noise power at a known temperature is first balanced with a synthesized noise power from the QVNS. The process is then repeated by balancing the noise power from the same resistor at an unknown temperature. When the two noise power ratios are combined, a thermodynamic temperature is derived using the ratio of the two QVNS spectral densities. We present preliminary results where the ratio between the gallium triple point and the water triple point is used to demonstrate the accuracy of the measurement system with a standard uncertainty of 0.04 %.
Olander, Donald
2007-01-01
The book’s methodology is unified, concise, and multidisciplinary, allowing students to understand how the principles of thermodynamics apply to all technical fields that touch upon this most fundamental of scientific theories. It also offers a rigorous approach to the quantitative aspects of thermodynamics, accompanied by clear explanations to help students transition smoothly from the physical concepts to their mathematical representations
Energy Technology Data Exchange (ETDEWEB)
Chu, William, E-mail: William.Chu@sunnybrook.ca [Department of Radiation Oncology, Sunnybrook Health Sciences Centre and the University of Toronto, Toronto, Ontario (Canada); Physical Sciences, Sunnybrook Research Institute, Toronto, Ontario (Canada); Staruch, Robert M. [Clinical Sites Research Program, Philips Research, Cambridge, Massachusetts (United States); Pichardo, Samuel [Thunder Bay Regional Research Institute, Thunder Bay, Ontario (Canada); Physics and Electrical Engineering, Lakehead University, Thunder Bay, Ontario (Canada); Tillander, Matti; Köhler, Max O. [MR Therapy, Philips Healthcare, Vantaa (Finland); Huang, Yuexi [Physical Sciences, Sunnybrook Research Institute, Toronto, Ontario (Canada); Ylihautala, Mika [MR Therapy, Philips Healthcare, Vantaa (Finland); McGuffin, Merrylee [Department of Radiation Oncology, Sunnybrook Health Sciences Centre and the University of Toronto, Toronto, Ontario (Canada); Czarnota, Gregory [Department of Radiation Oncology, Sunnybrook Health Sciences Centre and the University of Toronto, Toronto, Ontario (Canada); Physical Sciences, Sunnybrook Research Institute, Toronto, Ontario (Canada); Hynynen, Kullervo [Physical Sciences, Sunnybrook Research Institute, Toronto, Ontario (Canada)
2016-07-15
Purpose: To evaluate the feasibility of magnetic resonance–guided high-intensity focused ultrasound (MR-HIFU) mild hyperthermia in deep tissue targets for enhancing radiation therapy and chemotherapy in the context of recurrent rectal cancer. A preclinical study was performed to evaluate the safety and performance of MR-HIFU mild hyperthermia. A prospective imaging study was performed in volunteers with rectal cancer to evaluate MR thermometry quality near the rectum and accessibility of rectal tumors using MR-HIFU. Methods and Materials: Mild hyperthermia was performed in pig thigh (9 sonications, 6 pigs) using a clinical MR-HIFU system. Targets near the rectal wall and deep thigh were evaluated. Thermal maps obtained in 6 planes every 3.2 seconds were used to control sonications in 18-mm diameter treatment regions at temperatures of 42°C to 42.5°C for 10 to 60 minutes. Volunteer imaging-only studies to assess the quality of MR thermometry (without heating) were approved by the institutional research ethics board. Anatomic and MR thermometry images were acquired in consenting volunteers with rectal cancer. In 3 of 6 study participants, rectal filling with saline was used to reduce motion-related MR thermometry artifacts near the tumor. Results: In pigs, mean target temperature matched the desired hyperthermia temperature within 0.2°C; temporal standard deviation ≤0.5°C. With optimized control thresholds, no undesired tissue damage was observed. In human volunteers, MR temperature measurements had adequate precision and stability, especially when rectal filling was used to reduce bowel motion. Conclusions: In pigs, MR-HIFU can safely deliver mild hyperthermia (41°C-43°C) to a targeted volume for 30 minutes. In humans, careful patient selection and preparation will enable adequate targeting for recurrent rectal cancers and sufficient MR temperature mapping stability to control mild hyperthermia. These results enable human trials of MR-HIFU hyperthermia.
International Nuclear Information System (INIS)
Chu, William; Staruch, Robert M.; Pichardo, Samuel; Tillander, Matti; Köhler, Max O.; Huang, Yuexi; Ylihautala, Mika; McGuffin, Merrylee; Czarnota, Gregory; Hynynen, Kullervo
2016-01-01
Purpose: To evaluate the feasibility of magnetic resonance–guided high-intensity focused ultrasound (MR-HIFU) mild hyperthermia in deep tissue targets for enhancing radiation therapy and chemotherapy in the context of recurrent rectal cancer. A preclinical study was performed to evaluate the safety and performance of MR-HIFU mild hyperthermia. A prospective imaging study was performed in volunteers with rectal cancer to evaluate MR thermometry quality near the rectum and accessibility of rectal tumors using MR-HIFU. Methods and Materials: Mild hyperthermia was performed in pig thigh (9 sonications, 6 pigs) using a clinical MR-HIFU system. Targets near the rectal wall and deep thigh were evaluated. Thermal maps obtained in 6 planes every 3.2 seconds were used to control sonications in 18-mm diameter treatment regions at temperatures of 42°C to 42.5°C for 10 to 60 minutes. Volunteer imaging-only studies to assess the quality of MR thermometry (without heating) were approved by the institutional research ethics board. Anatomic and MR thermometry images were acquired in consenting volunteers with rectal cancer. In 3 of 6 study participants, rectal filling with saline was used to reduce motion-related MR thermometry artifacts near the tumor. Results: In pigs, mean target temperature matched the desired hyperthermia temperature within 0.2°C; temporal standard deviation ≤0.5°C. With optimized control thresholds, no undesired tissue damage was observed. In human volunteers, MR temperature measurements had adequate precision and stability, especially when rectal filling was used to reduce bowel motion. Conclusions: In pigs, MR-HIFU can safely deliver mild hyperthermia (41°C-43°C) to a targeted volume for 30 minutes. In humans, careful patient selection and preparation will enable adequate targeting for recurrent rectal cancers and sufficient MR temperature mapping stability to control mild hyperthermia. These results enable human trials of MR-HIFU hyperthermia.
Vortex Thermometry for Turbulent Two-Dimensional Fluids.
Groszek, Andrew J; Davis, Matthew J; Paganin, David M; Helmerson, Kristian; Simula, Tapio P
2018-01-19
We introduce a new method of statistical analysis to characterize the dynamics of turbulent fluids in two dimensions. We establish that, in equilibrium, the vortex distributions can be uniquely connected to the temperature of the vortex gas, and we apply this vortex thermometry to characterize simulations of decaying superfluid turbulence. We confirm the hypothesis of vortex evaporative heating leading to Onsager vortices proposed in Phys. Rev. Lett. 113, 165302 (2014)PRLTAO0031-900710.1103/PhysRevLett.113.165302, and we find previously unidentified vortex power-law distributions that emerge from the dynamics.
Iribarne, J V
1973-01-01
The thermodynamics of the atmosphere is the subject of several chapters in most textbooks on dynamic meteorology, but there is no work in English to give the subject a specific and more extensive treatment. In writing the present textbook, we have tried to fill this rather remarkable gap in the literature related to atmospheric sciences. Our aim has been to provide students of meteorology with a book that can playa role similar to the textbooks on chemical thermodynamics for the chemists. This implies a previous knowledge of general thermodynamics, such as students acquire in general physics courses; therefore, although the basic principles are reviewed (in the first four chapters), they are only briefly discussed, and emphasis is laid on those topics that will be useful in later chapters, through their application to atmospheric problems. No attempt has been made to introduce the thermodynamics of irreversible processes; on the other hand, consideration of heterogeneous and open homogeneous systems permits a...
Wei, Bo-Bo; Jiang, Zhan-Feng; Liu, Ren-Bao
2015-01-01
The holographic principle states that the information about a volume of a system is encoded on the boundary surface of the volume. Holography appears in many branches of physics, such as optics, electromagnetism, many-body physics, quantum gravity, and string theory. Here we show that holography is also an underlying principle in thermodynamics, a most important foundation of physics. The thermodynamics of a system is fully determined by its partition function. We prove that the partition function of a finite but arbitrarily large system is an analytic function on the complex plane of physical parameters, and therefore the partition function in a region on the complex plane is uniquely determined by its values along the boundary. The thermodynamic holography has applications in studying thermodynamics of nano-scale systems (such as molecule engines, nano-generators and macromolecules) and provides a new approach to many-body physics. PMID:26478214
Fiber Optic Based Thermometry System for Superconducting RF Cavities
Energy Technology Data Exchange (ETDEWEB)
Kochergin, Vladimir [Microxact Inc.
2013-05-06
Thermometry is recognized as the best technique to identify and characterize losses in SRF cavities. The most widely used and reliable apparatus for temperature mapping at cryogenic temperatures is based on carbon resistors (RTDs). The use of this technology on multi-cell cavities is inconvenient due to the very large number of sensors required to obtain sufficient spatial resolution. Recent developments make feasible the use of multiplexible fiber optic sensors for highly distributed temperature measurements. However, sensitivity of multiplexible cryogenic temperature sensors was found extending only to 12K at best and thus was not sufficient for SRF cavity thermometry. During the course of the project the team of MicroXact, JLab and Virginia Tech developed and demonstrated the multiplexible fiber optic sensor with adequate response below 20K. The demonstrated temperature resolution is by at least a factor of 60 better than that of the best multiplexible fiber optic temperature sensors reported to date. The clear path toward at least 10times better temperature resolution is shown. The first to date temperature distribution measurements with ~2.5mm spatial resolution was done with fiber optic sensors at 2K to4K temperatures. The repeatability and accuracy of the sensors were verified only at 183K, but at this temperature both parameters significantly exceeded the state of the art. The results of this work are expected to find a wide range of applications, since the results are enabling the whole new testing capabilities, not accessible before.
Directory of Open Access Journals (Sweden)
Lilian Govone
2017-12-01
Full Text Available This paper presents a theoretical investigation of the second law performance of double diffusive forced convection in microreactors with the inclusion of nanofluid and radiation effects. The investigated microreactors consist of a single microchannel, fully filled by a porous medium. The transport of heat and mass are analysed by including the thick walls and a first order, catalytic chemical reaction on the internal surfaces of the microchannel. Two sets of thermal boundary conditions are considered on the external surfaces of the microchannel; (1 constant temperature and (2 constant heat flux boundary condition on the lower wall and convective boundary condition on the upper wall. The local thermal non-equilibrium approach is taken to thermally analyse the porous section of the system. The mass dispersion equation is coupled with the transport of heat in the nanofluid flow through consideration of Soret effect. The problem is analytically solved and illustrations of the temperature fields, Nusselt number, total entropy generation rate and performance evaluation criterion (PEC are provided. It is shown that the radiation effect tends to modify the thermal behaviour within the porous section of the system. The radiation parameter also reduces the overall temperature of the system. It is further demonstrated that, expectedly, the nanoparticles reduce the temperature of the system and increase the Nusselt number. The total entropy generation rate and consequently PEC shows a strong relation with radiation parameter and volumetric concentration of nanoparticles.
International Nuclear Information System (INIS)
Fechner, H.
1988-12-01
The aim was to determine the achievable accuracy of the noise thermometer developed at the KFA in the range from 0 to 1000 0 C under laboratory conditions. Precision noise temperature measurements at fixed temperature points (triple point of water, freezing point of zinc and silver) were carried out. The fixed point technique and the conventional precision resistance thermometry, which is required to operate the fixed points, were established in accordance with the requirements of accurate (and thus longer lasting) noise temperature measurements. The analysis of all possible sources of error ensured that all systematic or random errors were in the range of a few 10 -5 . The further developed KFA noise thermometers, which can be used under industrial conditions, achieve under laboratory conditions a measuring error of about ±2.5 10 -4 - relative to the thermodynamic temperature scale - in the temperature range from 273.16 K (0.01 0 C) to 1234.894 K (961.744 0 C). Assuming that the individual measured values display a normal distribution, the noise measurements at the zinc and silver point are combined to a mean value, it becomes apparent that the average noise temperatures only deviate by +2 10 -5 (zinc) or +4 10 -5 (silver) from the respective thermodynamic temperature. (orig./HP) [de
International Nuclear Information System (INIS)
Torabi, Mohsen; Zhang, Kaili
2015-01-01
Highlights: • First and second laws of thermodynamics have been investigated in a composite wall. • Convective–radiative heat transfer is assumed on both surfaces. • Optimum interface location is calculated to minimize the total entropy generation rate. • Thermal conductivities ratio has great effects on the temperature and entropy generation. - Abstract: Composite geometries have numerous applications in industry and scientific researches. This work investigates the temperature distribution, and local and total entropy generation rates within two-layer composite walls using conjugate convection and radiation boundary conditions. Thermal conductivities of the materials of walls are assumed temperature-dependent. Temperature-dependent internal heat generations are also incorporated into the modeling. The differential transformation method (DTM) is used as an analytical technique to tackle the highly nonlinear system of ordinary differential equations. Thereafter, the local and total entropy generation rates are calculated using the DTM formulated temperature distribution. An exact analytical solution, for the temperature-independent model without radiation effect, is also derived. The correctness and accuracy of the DTM solution are checked against the exact solution. After verification, effects of thermophysical parameters such as location of the interface, convection–conduction parameters, radiation–conduction parameters, and internal heat generations, on the temperature distribution, and both local and total entropy generation rates are examined. To deliver the minimum total entropy generation rate, optimum values for some parameters are also found. Since composite walls are widely used in many fields, the abovementioned investigation is a beneficial tool for many engineering industries and scientific fields to minimize the entropy generation, which is the exergy destruction, of the system
Eichhorn, Ralf; Aurell, Erik
2014-04-01
'Stochastic thermodynamics as a conceptual framework combines the stochastic energetics approach introduced a decade ago by Sekimoto [1] with the idea that entropy can consistently be assigned to a single fluctuating trajectory [2]'. This quote, taken from Udo Seifert's [3] 2008 review, nicely summarizes the basic ideas behind stochastic thermodynamics: for small systems, driven by external forces and in contact with a heat bath at a well-defined temperature, stochastic energetics [4] defines the exchanged work and heat along a single fluctuating trajectory and connects them to changes in the internal (system) energy by an energy balance analogous to the first law of thermodynamics. Additionally, providing a consistent definition of trajectory-wise entropy production gives rise to second-law-like relations and forms the basis for a 'stochastic thermodynamics' along individual fluctuating trajectories. In order to construct meaningful concepts of work, heat and entropy production for single trajectories, their definitions are based on the stochastic equations of motion modeling the physical system of interest. Because of this, they are valid even for systems that are prevented from equilibrating with the thermal environment by external driving forces (or other sources of non-equilibrium). In that way, the central notions of equilibrium thermodynamics, such as heat, work and entropy, are consistently extended to the non-equilibrium realm. In the (non-equilibrium) ensemble, the trajectory-wise quantities acquire distributions. General statements derived within stochastic thermodynamics typically refer to properties of these distributions, and are valid in the non-equilibrium regime even beyond the linear response. The extension of statistical mechanics and of exact thermodynamic statements to the non-equilibrium realm has been discussed from the early days of statistical mechanics more than 100 years ago. This debate culminated in the development of linear response
Ben-Naim, Arieh
2017-01-01
This textbook introduces thermodynamics with a modern approach, starting from four fundamental physical facts (the atomic nature of matter, the indistinguishability of atoms and molecules of the same species, the uncertainty principle, and the existence of equilibrium states) and analyzing the behavior of complex systems with the tools of information theory, in particular with Shannon's measure of information (or SMI), which can be defined on any probability distribution. SMI is defined and its properties and time evolution are illustrated, and it is shown that the entropy is a particular type of SMI, i.e. the SMI related to the phase-space distribution for a macroscopic system at equilibrium. The connection to SMI allows the reader to understand what entropy is and why isolated systems follow the Second Law of Thermodynamics. The Second Llaw is also formulated for other systems, not thermally isolated and even open with respect to the transfer of particles. All the fundamental aspects of thermodynamics are d...
Casa, G.; Castrillo, A.; Galzerano, G.; Wehr, R.; Merlone, A.; Di Serafino, D.; Laporta, P.; Gianfrani, L.
2008-01-01
We report on a new optical implementation of primary gas thermometry based on laser absorption spectrometry in the near infrared. The method consists in retrieving the Doppler broadening from highly accurate observations of the line shape of the R(12) $\
Sub-picowatt/kelvin resistive thermometry for probing nanoscale thermal transport.
Zheng, Jianlin; Wingert, Matthew C; Dechaumphai, Edward; Chen, Renkun
2013-11-01
Advanced instrumentation in thermometry holds the key for experimentally probing fundamental heat transfer physics. However, instrumentation with simultaneously high thermometry resolution and low parasitic heat conduction is still not available today. Here we report a resistive thermometry scheme with ~50 μK temperature resolution and ~0.25 pW/K thermal conductance resolution, which is achieved through schemes using both modulated heating and common mode noise rejection. The suspended devices used herein have been specifically designed to possess short thermal time constants and minimal attenuation effects associated with the modulated heating current. Furthermore, we have systematically characterized the parasitic background heat conductance, which is shown to be significantly reduced using the new device design and can be effectively eliminated using a "canceling" scheme. Our results pave the way for probing fundamental nanoscale thermal transport processes using a general scheme based on resistive thermometry.
Classical or equilibrium thermodynamics: basic conceptual aspects
Directory of Open Access Journals (Sweden)
Luiz Augusto Calvo Tiritan
2008-08-01
Full Text Available The Classical or Equilibrium Thermodynamics is one of the most consolidated fields of Physics. It is synthesized by a well-known and self coherent knowledge structure. The essence of the Classical Thermodynamics theoretical structure consists of a set of natural laws that rule the macroscopic physical systems behavior. These laws were formulated based on observations generalizations and are mostly independent of any hypotheses concerning the microscopic nature of the matter. In general, the approaches established for the Classical Thermodynamics follow one of the following alternatives: the historical approach that describes chronologically the evolution of ideas, concepts and facts, and the postulational approach in which postulates are formulated but are not demonstrated a priori but can be confirmed a posteriori. In this work, a brief review of the pre-classical historical approach conceptual evolution is elaborated, from the beginning of the seventeenth century to the middle of the nineteenth century. As for this, the following themes are dealt with in an evolutionary and phenomenological way: heat nature, thermometry, calorimetry, Carnot’s heat engine, heat mechanical equivalent and the first and second laws. The Zeroth law that was formulated afterwards is included in the discussion.
Effect of frost on phosphorescence for thermographic phosphor thermometry
Kim, Dong; Kim, Mirae; Kim, Kyung Chun
2017-12-01
In this study, we analyzed phosphorescence lifetime and its accuracy by growing frost for thermographic phosphor thermometry in a low-temperature environment. Mg4FGeO6:Mn particles were coated on an aluminum plate and excited with a UV-LED to obtain phosphorescence signals. The surface temperature was maintained at -20, -15, -10 °C, and the phosphorescence signal was acquired as the frost grew for 3700 s. The lifetime was calculated and compared with the calibration curve under no-frost conditions. The error of the measured lifetime was within 0.7% of that in the no-frost conditions. A 2D surface temperature profile of the target plate was successfully obtained with the frost formation.
Zirconium metal-water oxidation kinetics. I. Thermometry
International Nuclear Information System (INIS)
Cathcart, J.V.; McElroy, D.L.; Pawel, R.E.; Perkins, R.A.; Williams, R.K.; Yurek, G.J.
1976-02-01
A description is given of the thermometry techniques used in the Zirconium Metal--Water Oxidation Kinetics Program. Temperature measurements in the range 900 to 1500 0 C are made in three experimental systems: two oxidation apparatuses and the annealing furnace used in a corollary study of the diffusion of oxygen in β-Zircaloy. Carefully calibrated Pt vs Pt--10 percent Rh thermocouples are employed in all three apparatuses, while a Pt--6 percent Rh vs Pt-- 30 percent Rh thermocouple and an optical pyrometer are used in addition in the annealing furnace. Features of the experimental systems pertaining to thermocouple installation, temperature control, emf measurements, etc. are described, and potential temperature-measurement error sources are discussed in detail. The accuracy of the temperature measurements is analyzed
Magnon and phonon thermometry with inelastic light scattering
Olsson, Kevin S.; An, Kyongmo; Li, Xiaoqin
2018-04-01
Spin caloritronics investigates the interplay between the transport of spin and heat. In the spin Seebeck effect, a thermal gradient across a magnetic material generates a spin current. A temperature difference between the energy carriers of the spin and lattice subsystems, namely the magnons and phonons, is necessary for such thermal nonequilibrium generation of spin current. Inelastic light scattering is a powerful method that can resolve the individual temperatures of magnons and phonons. In this review, we discuss the thermometry capabilities of inelastic light scattering for measuring optical and acoustic phonons, as well as magnons. A scattering spectrum offers three temperature sensitive parameters: frequency shift, linewidth, and integrated intensity. We discuss the temperatures measured via each of these parameters for both phonon and magnons. Finally, we discuss inelastic light scattering experiments that have examined the magnon and phonon temperatures in thermal nonequilibrium which are particularly relevant to spin caloritronic phenomena.
Development of high frequency and wide bandwidth Johnson noise thermometry
International Nuclear Information System (INIS)
Crossno, Jesse; Liu, Xiaomeng; Kim, Philip; Ohki, Thomas A.; Fong, Kin Chung
2015-01-01
We develop a high frequency, wide bandwidth radiometer operating at room temperature, which augments the traditional technique of Johnson noise thermometry for nanoscale thermal transport studies. Employing low noise amplifiers and an analog multiplier operating at 2 GHz, auto- and cross-correlated Johnson noise measurements are performed in the temperature range of 3 to 300 K, achieving a sensitivity of 5.5 mK (110 ppm) in 1 s of integration time. This setup allows us to measure the thermal conductance of a boron nitride encapsulated monolayer graphene device over a wide temperature range. Our data show a high power law (T ∼ 4) deviation from the Wiedemann-Franz law above T ∼ 100 K
Raman Thermometry Measurements of Free Evaporation from Liquid Water Droplets
International Nuclear Information System (INIS)
Smith, Jared D.; Cappa, Christopher D.; Drisdell, Walter S.; Cohen, Ronald C.; Saykally, Richard J.
2006-01-01
Recent theoretical and experimental studies of evaporation have suggested that on average, molecules in the higher-energy tail of the Boltzmann distribution are more readily transferred into the vapor during evaporation. To test these conclusions, the evaporative cooling rates of a droplet train of liquid water injected into vacuum have been studied via Raman thermometry. The resulting cooling rates are fit to an evaporative cooling model based on Knudsen's maximum rate of evaporation, in which we explicitly account for surface cooling. We have determined that the value of the evaporation coefficient (γ e ) of liquid water is 0.62 ± 0.09, confirming that a rate-limiting barrier impedes the evaporation rate. Such insight will facilitate the formulation of a microscopic mechanism for the evaporation of liquid water
Application of ultrasonic thermometry in LMFBR safety research
International Nuclear Information System (INIS)
Carlson, G.A.; Sullivan, W.H.; Plein, H.G.
1977-01-01
Ultrasonic thermometry has many potential applications in reactor safety research, where extremely high temperatures and lack of visual access may preclude the use of conventional diagnostics. An application (the in-core molten fuel pool experiment) will be described in which thoriated tungsten ultrasonic thermometers were used to measure temperatures in UO 2 to incipient melt (2860 0 ). Each thermometer included five sensor elements 10 mm long, providing five temperatures within the UO 2 at various axial locations. The 10 mm spatial resolution is about five times better than previous applications of the technique. Temperature resolution of +-10 0 C was indicated by calibration data. Besides providing temperature data approximately 1000 0 C higher than were obtained with thermocouples, the thermometer yielded valuable axial temperature profile data. Details of the sensors, exciting coils, and signal conditioning electronics will be given
Digital particle image thermometry/velocimetry: a review
Energy Technology Data Exchange (ETDEWEB)
Dabiri, Dana [University of Washington, Department of Aeronautics and Astronautics, Seattle, WA (United States)
2009-02-15
Digital particle image thermometry/velocimetry (DPIT/V) is a relatively new methodology that allows for measurements of simultaneous temperature and velocity within a two-dimensional domain, using thermochromic liquid crystal tracer particles as the temperature and velocity sensors. Extensive research has been carried out over recent years that have allowed the methodology and its implementation to grow and evolve. While there have been several reviews on the topic of liquid crystal thermometry (Moffat in Exp Therm Fluid Sci 3:14-32, 1990; Baughn in Int J Heat Fluid Flow 16:365-375, 1995; Roberts and East in J Spacecr Rockets 33:761-768, 1996; Wozniak et al. in Appl Sci Res 56:145-156, 1996; Behle et al. in Appl Sci Res 56:113-143, 1996; Stasiek in Heat Mass Transf 33:27-39, 1997; Stasiek and Kowalewski in Opto Electron Rev 10:1-10, 2002; Stasiek et al. in Opt Laser Technol 38:243-256, 2006; Smith et al. in Exp Fluids 30:190-201, 2001; Kowalewski et al. in Springer handbook of experimental fluid mechanics, 1st edn. Springer, Berlin, pp 487-561, 2007), the focus of the present review is to provide a relevant discussion of liquid crystals pertinent to DPIT/V. This includes a background on liquid crystals and color theory, a discussion of experimental setup parameters, a description of the methodology's most recent advances and processing methods affecting temperature measurements, and finally an explanation of its various implementations and applications. (orig.)
International Nuclear Information System (INIS)
Li, D.J.; Luk, K.H.; Jiang, H.B.; Chou, C.K.; Hwang, G.Z.
1984-01-01
The construction of a modified coaxial cable as an intracavitary microwave applicator suitable for use in some vaginal and rectal cancers is presented. Thermometry is performed for microwave frequencies of 300, 400, 650, and 915 MHz. Temperature profiles in tissue phantoms were obtained with Vitek 101 temperature probes and thermography, and the data were compared with those obtained in dogs. The temperature profiles are dependent on the frequency of the microwaves and the insertion depth of the applicator. In addition, a lucite cylindrical spacer external to the applicator also altered the heating pattern. Therefore, with proper combinations of frequency, insertion depth, and spacer, the applicator can be used for heating tumors in some clinical situations. Two patients were treated with this intracavitary microwave applicator in conjunction with interstitial radiation therapy. Tolerance to such combined therapy was satisfactory in these preliminary trial treatments
Infrared thermometry and the crop water stress index. II. Sampling procedures and interpretation
Energy Technology Data Exchange (ETDEWEB)
Gardner, B. R. [BP Research, Cleveland, OH (United States); Nielsen, D. C.; Shock, C. C.
1992-10-15
Infrared thermometry can be a valuable research and production tool for detecting and quantifying water stress in plants, as shown by a large volume of published research. Users of infrared thermometers (IRT) should be aware of the many equipment, environmental, and plant factors influencing canopy temperature measured by an IRT. The purpose of this paper is to describe factors influencing measured plant temperature, outline sampling procedures that will produce reliable Crop Water Stress Index (CWSI) values, and offer interpretations of CWSI and plant temperatures relative to crop production and other water stress parameters by reviewing previously conducted research. Factors that are considered are IRT condition, configuration, and position; psychrometer location; wind speed; solar radiation; time of day; leaf area and orientation; and appropriate non-water-stressed baseline equation. Standard sampling and CWSI calculation procedures are proposed. Use of CWSI with crops varying in type of response to water stress is described. Previously conducted research on plant temperatures or CWSI is tabulated by crop and water stress parameters measured. The paper provides valuable information to assist interested users of IRTs in making reliable water stress measurements. (author)
Infrared thermometry and the crop water stress index. II. Sampling procedures and interpretation
International Nuclear Information System (INIS)
Gardner, B.R.; Nielsen, D.C.; Shock, C.C.
1992-01-01
Infrared thermometry can be a valuable research and production tool for detecting and quantifying water stress in plants, as shown by a large volume of published research. Users of infrared thermometers (IRT) should be aware of the many equipment, environmental, and plant factors influencing canopy temperature measured by an IRT. The purpose of this paper is to describe factors influencing measured plant temperature, outline sampling procedures that will produce reliable Crop Water Stress Index (CWSI) values, and offer interpretations of CWSI and plant temperatures relative to crop production and other water stress parameters by reviewing previously conducted research. Factors that are considered are IRT condition, configuration, and position; psychrometer location; wind speed; solar radiation; time of day; leaf area and orientation; and appropriate non-water-stressed baseline equation. Standard sampling and CWSI calculation procedures are proposed. Use of CWSI with crops varying in type of response to water stress is described. Previously conducted research on plant temperatures or CWSI is tabulated by crop and water stress parameters measured. The paper provides valuable information to assist interested users of IRTs in making reliable water stress measurements. (author)
Strange, Nicholas; Arnold, Thomas; Forster, Matthew; Parker, Julia; Larese, J. Z.; Diamond Light Source Collaboration; University of Tennessee Team
2014-03-01
Hexagonal boron nitride (hBN) has a lattice structure similar to that of graphite with a slightly larger lattice parameter in the basal plane. This, among other properties, makes it an excellent substrate in place of graphite, eliciting some important differences. This work is part of a larger effort to examine the interaction of alkanes with magnesium oxide, graphite, and boron nitride surfaces. In our current presentation, we will discuss the interaction of decane with these surfaces. Decane exhibits a fully commensurate structure on graphite and hBN at monolayer coverages. In this particular experiment, we have examined the monolayer structure of decane adsorbed on the basal plane of hBN using synchrotron x-ray radiation at Diamond Light Source. Additionally, we have examined the system experimentally with volumetric isotherms as well as computationally using molecular dynamics simulations. The volumetric isotherms allow us to calculate properties which provide important information about the adsorbate's interaction with not only neighboring molecules, but also the interaction with the adsorbent boron nitride.
Thermal physics kinetic theory and thermodynamics
Singh, Devraj; Yadav, Raja Ram
2016-01-01
THERMAL PHYSICS: Kinetic Theory and Thermodynamics is designed for undergraduate course in Thermal Physics and Thermodynamics. The book provides thorough understanding of the fundamental principles of the concepts in Thermal Physics. The book begins with kinetic theory, then moves on liquefaction, transport phenomena, the zeroth, first, second and third laws, thermodynamics relations and thermal conduction. The book concluded with radiation phenomenon. KEY FEATURES: * Include exercises * Short Answer Type Questions * Long Answer Type Questions * Numerical Problems * Multiple Choice Questions
Ben-Naim, Arieh
1987-01-01
This book deals with a subject that has been studied since the beginning of physical chemistry. Despite the thousands of articles and scores of books devoted to solvation thermodynamics, I feel that some fundamen tal and well-established concepts underlying the traditional approach to this subject are not satisfactory and need revision. The main reason for this need is that solvation thermodynamics has traditionally been treated in the context of classical (macroscopic) ther modynamics alone. However, solvation is inherently a molecular pro cess, dependent upon local rather than macroscopic properties of the system. Therefore, the starting point should be based on statistical mechanical methods. For many years it has been believed that certain thermodynamic quantities, such as the standard free energy (or enthalpy or entropy) of solution, may be used as measures of the corresponding functions of solvation of a given solute in a given solvent. I first challenged this notion in a paper published in 1978 b...
Blackbody-radiation correction to the polarizability of helium
International Nuclear Information System (INIS)
Puchalski, M.; Jentschura, U. D.; Mohr, P. J.
2011-01-01
The correction to the polarizability of helium due to blackbody radiation is calculated near room temperature. A precise theoretical determination of the blackbody radiation correction to the polarizability of helium is essential for dielectric gas thermometry and for the determination of the Boltzmann constant. We find that the correction, for not too high temperature, is roughly proportional to a modified hyperpolarizability (two-color hyperpolarizability), which is different from the ordinary hyperpolarizability of helium. Our explicit calculations provide a definite numerical result for the effect and indicate that the effect of blackbody radiation can be excluded as a limiting factor for dielectric gas thermometry using helium or argon.
The thermodynamic solar energy; Le solaire thermodynamique
Energy Technology Data Exchange (ETDEWEB)
Rivoire, B. [Centre National de la Recherche Scientifique (CNRS-IMP), 66 - Perpignan (France)
2002-04-01
The thermodynamic solar energy is the technic in the whole aiming to transform the solar radiation energy in high temperature heat and then in mechanical energy by a thermodynamic cycle. These technic are most often at an experimental scale. This paper describes and analyzes the research programs developed in the advanced countries, since 1980. (A.L.B.)
International Nuclear Information System (INIS)
Gomez Palacio, German Rau
1998-01-01
Ecology is no more a descriptive and self-sufficient science. Many viewpoints are needed simultaneously to give a full coverage of such complex systems: ecosystems. These viewpoints come from physics, chemistry, and nuclear physics, without a new far from equilibrium thermodynamics and without new mathematical tools such as catastrophe theory, fractal theory, cybernetics and network theory, the development of ecosystem science would never have reached the point of today. Some ideas are presented about the importance that concept such as energy, entropy, exergy information and none equilibrium have in the analysis of processes taking place in ecosystems
Thermometry in dielectrophoresis chips for contact-free cell handling
International Nuclear Information System (INIS)
Jaeger, M S; Mueller, T; Schnelle, T
2007-01-01
Cell biology applications, protocols in immunology and stem cell research, require that individual cells are handled under strict control of their contacts to other cells or synthetic surfaces. Dielectrophoresis (DEP) in microfluidic chips is an established technique to investigate, group, wash, cultivate and sort cells contact-free under physiological conditions: microelectrode octode cages, versatile dielectrophoretic elements energized with radio frequency electric fields, stably trap single cells or cellular aggregates. For medical applications and cell cultivation, possible side effects of the dielectrophoretic manipulation, such as membrane polarization and Joule heating, have to be quantified. Therefore, we characterized the electric field-induced warming in dielectrophoretic cages using ohmic resistance measurements, fluorometry, liquid crystal beads, infra-red thermography and bubble size thermometry. We compare the results of these techniques with respect to the influences of voltage, electric conductivity of buffer, frequency, cage size and electrode surface. We conclude that in the culture medium thermal effects may be neglected if low voltages and an electric field-reducing phase pattern are used. Our experimental results provide explicit values for estimating the thermal effect on dielectrophoretically caged cells and show that Joule heating is best minimized by optimizing the cage geometry and reducing the buffer conductivity. The results may additionally serve to evaluate and improve theoretical predictions on field-induced effects. Based on present-day chip processing possibilities, DEP is well suited for the manipulation of cells
Structural disorder of graphite and implications for graphite thermometry
Kirilova, Martina; Toy, Virginia; Rooney, Jeremy S.; Giorgetti, Carolina; Gordon, Keith C.; Collettini, Cristiano; Takeshita, Toru
2018-02-01
Graphitization, or the progressive maturation of carbonaceous material, is considered an irreversible process. Thus, the degree of graphite crystallinity, or its structural order, has been calibrated as an indicator of the peak metamorphic temperatures experienced by the host rocks. However, discrepancies between temperatures indicated by graphite crystallinity versus other thermometers have been documented in deformed rocks. To examine the possibility of mechanical modifications of graphite structure and the potential impacts on graphite thermometry, we performed laboratory deformation experiments. We sheared highly crystalline graphite powder at normal stresses of 5 and 25 megapascal (MPa) and aseismic velocities of 1, 10 and 100 µm s-1. The degree of structural order both in the starting and resulting materials was analyzed by Raman microspectroscopy. Our results demonstrate structural disorder of graphite, manifested as changes in the Raman spectra. Microstructural observations show that brittle processes caused the documented mechanical modifications of the aggregate graphite crystallinity. We conclude that the calibrated graphite thermometer is ambiguous in active tectonic settings.
Structural disorder of graphite and implications for graphite thermometry
Directory of Open Access Journals (Sweden)
M. Kirilova
2018-02-01
Full Text Available Graphitization, or the progressive maturation of carbonaceous material, is considered an irreversible process. Thus, the degree of graphite crystallinity, or its structural order, has been calibrated as an indicator of the peak metamorphic temperatures experienced by the host rocks. However, discrepancies between temperatures indicated by graphite crystallinity versus other thermometers have been documented in deformed rocks. To examine the possibility of mechanical modifications of graphite structure and the potential impacts on graphite thermometry, we performed laboratory deformation experiments. We sheared highly crystalline graphite powder at normal stresses of 5 and 25 megapascal (MPa and aseismic velocities of 1, 10 and 100 µm s−1. The degree of structural order both in the starting and resulting materials was analyzed by Raman microspectroscopy. Our results demonstrate structural disorder of graphite, manifested as changes in the Raman spectra. Microstructural observations show that brittle processes caused the documented mechanical modifications of the aggregate graphite crystallinity. We conclude that the calibrated graphite thermometer is ambiguous in active tectonic settings.
Ultrasonic thermometry system for measuring very high temperatures in reactor safety experiments
International Nuclear Information System (INIS)
Carlson, G.A.; Sullivan, W.H.; Plein, H.G.; Kerley, T.M.
1979-06-01
Ultrasonic thermometry has many potential applications in reactor safety experiments, where extremely high temperatures and lack of visual access may preclude the use of conventional diagnostics. This report details ultrasonic thermometry requirements for one such experiment, the molten fuel pool experiment. Sensors, transducers, and signal processing electronics are described in detail. Axial heat transfer in the sensors is modelled and found acceptably small. Measurement errors, calculations of their effect, and ways to minimize them are given. A rotating sensor concept is discussed which holds promise of alleviating sticking problems at high temperature. Applications of ultrasonic thermometry to three in-core experiments are described. In them, five 10-mm-length sensor elements were used to measure axial temperatures in a UO 2 or UO 2 -steel system fission-heated to about 2860 0 C
de Oliveira, Mário J
2017-01-01
This textbook provides an exposition of equilibrium thermodynamics and its applications to several areas of physics with particular attention to phase transitions and critical phenomena. The applications include several areas of condensed matter physics and include also a chapter on thermochemistry. Phase transitions and critical phenomena are treated according to the modern development of the field, based on the ideas of universality and on the Widom scaling theory. For each topic, a mean-field or Landau theory is presented to describe qualitatively the phase transitions. These theories include the van der Waals theory of the liquid-vapor transition, the Hildebrand-Heitler theory of regular mixtures, the Griffiths-Landau theory for multicritical points in multicomponent systems, the Bragg-Williams theory of order-disorder in alloys, the Weiss theory of ferromagnetism, the Néel theory of antiferromagnetism, the Devonshire theory for ferroelectrics and Landau-de Gennes theory of liquid crystals. This new edit...
Petryshyn, V A; Lim, D; Laval, B L; Brady, A; Slater, G; Tripati, A K
2015-01-01
Quantitative tools for deciphering the environment of microbialite formation are relatively limited. For example, the oxygen isotope carbonate-water geothermometer requires assumptions about the isotopic composition of the water of formation. We explored the utility of using 'clumped' isotope thermometry as a tool to study the temperatures of microbialite formation. We studied microbialites recovered from water depths of 10-55 m in Pavilion Lake, and 10-25 m in Kelly Lake, spanning the thermocline in both lakes. We determined the temperature of carbonate growth and the (18)O/(16)O ratio of the waters that microbialites grew in. Results were then compared to current limnological data from the lakes to reconstruct the history of microbialite formation. Modern microbialites collected at shallow depths (11.7 m) in both lakes yield clumped isotope-based temperatures of formation that are within error of summer water temperatures, suggesting that clumped isotope analyses may be used to reconstruct past climates and to probe the environments in which microbialites formed. The deepest microbialites (21.7-55 m) were recovered from below the present-day thermoclines in both lakes and yield radioisotope ages indicating they primarily formed earlier in the Holocene. During this time, pollen data and our reconstructed water (18)O/(16)O ratios indicate a period of aridity, with lower lake levels. At present, there is a close association between both photosynthetic and heterotrophic communities, and carbonate precipitation/microbialite formation, with biosignatures of photosynthetic influences on carbonate detected in microbialites from the photic zone and above the thermocline (i.e., depths of generally <20 m). Given the deeper microbialites are receiving <1% of photosynthetically active radiation (PAR), it is likely these microbialites primarily formed when lower lake levels resulted in microbialites being located higher in the photic zone, in warm surface waters. © 2014 John
Henkes, Gregory A.; Passey, Benjamin H.; Grossman, Ethan L.; Shenton, Brock J.; Yancey, Thomas E.; Pérez-Huerta, Alberto
2018-05-01
Surface temperature is among the most important parameters describing planetary climate and habitability, and yet there remains considerable debate about the temperature evolution of the Earth's oceans during the Phanerozoic Eon (541 million years ago to present), the time during which complex metazoan life radiated on Earth. Here we critically assess the emerging record of Phanerozoic ocean temperatures based on carbonate clumped isotope thermometry of fossil brachiopod and mollusk shells, and we present new data that fill important gaps in the Late Paleozoic record. We evaluate and reject the hypothesis that solid-state reordering of 13C-18O bonds has destroyed the primary clumped isotope temperature signal of most fossils during sedimentary burial at elevated temperatures. The resulting Phanerozoic record, which shows a general coupling between tropical seawater temperatures and atmospheric carbon dioxide (CO2) levels since the Paleozoic, indicates that tropical temperatures during the icehouse climate of the Carboniferous period were broadly similar to present (∼25-30 °C), and suggests that benthic metazoans were able to thrive at temperatures of 35-40 °C during intervals of the early and possibly the latest Paleozoic when CO2 levels were likely 5-10× higher than present-day values. Equally important, there is no resolvable trend in seawater oxygen isotope ratios (δ18 O) over the past ∼500 million years, indicating that the average temperature of oxygen exchange between seawater and the oceanic crust has been high (∼270 °C) since at least the early Paleozoic, which points to mid-ocean ridges as the dominant locus of water-rock interaction over the past half-billion years.
Elimination of noise peak for signal processing in Johnson noise thermometry development
International Nuclear Information System (INIS)
Hwang, I. G.; Moon, B. S.; Jeong, J. E.; Jeo, Y. H.; Kisner, Roger A.
2003-01-01
The internal and external noise is the most considering obstacle in development of Johnson Noise Thermometry system. This paper addresses an external noise elimination issue of the Johnson Noise Thermometry system which is underway of development in collaboration between KAERI and ORNL. Although internal random noise is canceled by Cross Power Spectral Density function, a continuous wave penetrating into the electronic circuit is eliminated by the difference of peaks between Johnson signal and external noise. The elimination logic using standard deviation of CPSD and energy leakage problem in discrete CPSD function are discussed in this paper
CT thermometry for cone-beam CT guided ablation
DeStefano, Zachary; Abi-Jaoudeh, Nadine; Li, Ming; Wood, Bradford J.; Summers, Ronald M.; Yao, Jianhua
2016-03-01
Monitoring temperature during a cone-beam CT (CBCT) guided ablation procedure is important for prevention of over-treatment and under-treatment. In order to accomplish ideal temperature monitoring, a thermometry map must be generated. Previously, this was attempted using CBCT scans of a pig shoulder undergoing ablation.1 We are extending this work by using CBCT scans of real patients and incorporating more processing steps. We register the scans before comparing them due to the movement and deformation of organs. We then automatically locate the needle tip and the ablation zone. We employ a robust change metric due to image noise and artifacts. This change metric takes windows around each pixel and uses an equation inspired by Time Delay Analysis to calculate the error between windows with the assumption that there is an ideal spatial offset. Once the change map is generated, we correlate change data with measured temperature data at the key points in the region. This allows us to transform our change map into a thermal map. This thermal map is then able to provide an estimate as to the size and temperature of the ablation zone. We evaluated our procedure on a data set of 12 patients who had a total of 24 ablation procedures performed. We were able to generate reasonable thermal maps with varying degrees of accuracy. The average error ranged from 2.7 to 16.2 degrees Celsius. In addition to providing estimates of the size of the ablation zone for surgical guidance, 3D visualizations of the ablation zone and needle are also produced.
Thermometry, calorimetry, and mean body temperature during heat stress.
Kenny, Glen P; Jay, Ollie
2013-10-01
Heat balance in humans is maintained at near constant levels through the adjustment of physiological mechanisms that attain a balance between the heat produced within the body and the heat lost to the environment. Heat balance is easily disturbed during changes in metabolic heat production due to physical activity and/or exposure to a warmer environment. Under such conditions, elevations of skin blood flow and sweating occur via a hypothalamic negative feedback loop to maintain an enhanced rate of dry and evaporative heat loss. Body heat storage and changes in core temperature are a direct result of a thermal imbalance between the rate of heat production and the rate of total heat dissipation to the surrounding environment. The derivation of the change in body heat content is of fundamental importance to the physiologist assessing the exposure of the human body to environmental conditions that result in thermal imbalance. It is generally accepted that the concurrent measurement of the total heat generated by the body and the total heat dissipated to the ambient environment is the most accurate means whereby the change in body heat content can be attained. However, in the absence of calorimetric methods, thermometry is often used to estimate the change in body heat content. This review examines heat exchange during challenges to heat balance associated with progressive elevations in environmental heat load and metabolic rate during exercise. Further, we evaluate the physiological responses associated with heat stress and discuss the thermal and nonthermal influences on the body's ability to dissipate heat from a heat balance perspective.
Transrectal ultrasound applicator for prostate heating monitored using MRI thermometry
International Nuclear Information System (INIS)
Smith, Nadine Barrie; Buchanan, Mark T.; Hynynen, Kullervo
1999-01-01
Purpose: For potential localized hyperthermia treatment of tumors within the prostate, an ultrasound applicator consisting entirely of nonmagnetic materials for use with magnetic resonance imaging (MRI) has been developed and tested on muscle tissue ex vivo and in vivo. Methods and Materials: A partial-cylindrical intracavitary transducer consisting of 16 elements in a 4 x 4 pattern was constructed. It produced a radially propagating acoustic pressure field. Each element of this array (1.5 x 0.75 cm), operating at 1.5 MHz, could be separately powered to produce a desired energy deposition pattern within a target volume. Spatial and temporal temperature elevations were determined using the temperature-dependent proton resonant frequency (PRF) shift and phase subtraction of MR images acquired during ultrasonic heating. Four rabbits were exposed to the ultrasound to raise the local tissue temperature to 45 deg. C for 25 minutes. Six experiments compared thermocouple temperature results to PRF shift temperature results. Results: The tests showed that the multi-element ultrasound applicator was MRI-compatible and allowed imaging during sonication. The induced temperature distribution could be controlled by monitoring the RF power to each transducer element. Therapeutic temperature elevations were easily achieved in vivo at power levels that were about 16% of the maximum system power. From the six thermocouple experiments, comparison between the thermocouple temperature and the PRF temperature yielded an average error of 0.34 ± 0.36 deg. C. Conclusions: The MRI-compatible intracavitary applicator and driving system was able to control the ultrasound field and temperature pattern in vivo. MRI thermometry using the PRF shift can provide adequate temperature accuracy and stability for controlling the temperature distribution
Thermodynamics a complete undergraduate course
Steane, Andrew M
2016-01-01
This is an undergraduate textbook in thermodynamics—the science of heat, work, temperature, and entropy. The text presents thermodynamics in and of itself, as an elegant and powerful set of ideas and methods. These methods open the way to understanding a very wide range of phenomena in physics, chemistry, engineering, and biology. Starting out from an introduction of concepts at first year undergraduate level, the roles of temperature, internal energy, and entropy are explained via the laws of thermodynamics. The text employs a combination of examples, exercises, and careful discussion, with a view to conveying the feel of the subject as well as avoiding common misunderstandings. The Feynman–Smuluchowski ratchet, Szilard’s engine, and Maxwell’s daemon are used to elucidate entropy and the second law. Free energy and thermodynamic potentials are discussed at length, with applications to solids as well as fluids and flow processes. Thermal radiation is discussed, and the main ideas significant to global...
DEFF Research Database (Denmark)
De Poorter, J; De Wagter, C; De Deene, Y
1995-01-01
The noninvasive thermometry method is based on the temperature dependence of the proton resonance frequency (PRF). High-quality temperature images can be obtained from phase information of standard gradient-echo sequences with an accuracy of 0.2 degrees C in phantoms. This work was focused on the...
Infrared thermometry of water-stressed crops - emerging methods and technologies
Infrared thermometry has shown potential to quantify water stress in crop canopy. This presentation will outline the limited irrigation experiments by the USDA-ARS in northern Colorado, which is used for a framework to evaluate canopy temperature. Recent methods have been introduced that may be accu...
A self-reference PRF-shift MR thermometry method utilizing the phase gradient
International Nuclear Information System (INIS)
Langley, Jason; Potter, William; Phipps, Corey; Zhao Qun; Huang Feng
2011-01-01
In magnetic resonance (MR) imaging, the most widely used and accurate method for measuring temperature is based on the shift in proton resonance frequency (PRF). However, inter-scan motion and bulk magnetic field shifts can lead to inaccurate temperature measurements in the PRF-shift MR thermometry method. The self-reference PRF-shift MR thermometry method was introduced to overcome such problems by deriving a reference image from the heated or treated image, and approximates the reference phase map with low-order polynomial functions. In this note, a new approach is presented to calculate the baseline phase map in self-reference PRF-shift MR thermometry. The proposed method utilizes the phase gradient to remove the phase unwrapping step inherent to other self-reference PRF-shift MR thermometry methods. The performance of the proposed method was evaluated using numerical simulations with temperature distributions following a two-dimensional Gaussian function as well as phantom and in vivo experimental data sets. The results from both the numerical simulations and experimental data show that the proposed method is a promising technique for measuring temperature. (note)
Mathematical foundations of thermodynamics
Giles, R; Stark, M; Ulam, S
2013-01-01
Mathematical Foundations of Thermodynamics details the core concepts of the mathematical principles employed in thermodynamics. The book discusses the topics in a way that physical meanings are assigned to the theoretical terms. The coverage of the text includes the mechanical systems and adiabatic processes; topological considerations; and equilibrium states and potentials. The book also covers Galilean thermodynamics; symmetry in thermodynamics; and special relativistic thermodynamics. The book will be of great interest to practitioners and researchers of disciplines that deal with thermodyn
Noncontact surface thermometry for microsystems: LDRD final report.
Energy Technology Data Exchange (ETDEWEB)
Abel, Mark (Georgia Institute of Technology, Atlanta, GA); Beecham, Thomas (Georgia Institute of Technology, Atlanta, GA); Graham, Samuel (Georgia Institute of Technology, Atlanta, GA); Kearney, Sean Patrick; Serrano, Justin Raymond; Phinney, Leslie Mary
2006-10-01
We describe a Laboratory Directed Research and Development (LDRD) effort to develop and apply laser-based thermometry diagnostics for obtaining spatially resolved temperature maps on working microelectromechanical systems (MEMS). The goal of the effort was to cultivate diagnostic approaches that could adequately resolve the extremely fine MEMS device features, required no modifications to MEMS device design, and which did not perturb the delicate operation of these extremely small devices. Two optical diagnostics were used in this study: microscale Raman spectroscopy and microscale thermoreflectance. Both methods use a low-energy, nonperturbing probe laser beam, whose arbitrary wavelength can be selected for a diffraction-limited focus that meets the need for micron-scale spatial resolution. Raman is exploited most frequently, as this technique provides a simple and unambiguous measure of the absolute device temperature for most any MEMS semiconductor or insulator material under steady state operation. Temperatures are obtained from the spectral position and width of readily isolated peaks in the measured Raman spectra with a maximum uncertainty near {+-}10 K and a spatial resolution of about 1 micron. Application of the Raman technique is demonstrated for V-shaped and flexure-style polycrystalline silicon electrothermal actuators, and for a GaN high-electron-mobility transistor. The potential of the Raman technique for simultaneous measurement of temperature and in-plane stress in silicon MEMS is also demonstrated and future Raman-variant diagnostics for ultra spatio-temporal resolution probing are discussed. Microscale thermoreflectance has been developed as a complement for the primary Raman diagnostic. Thermoreflectance exploits the small-but-measurable temperature dependence of surface optical reflectivity for diagnostic purposes. The temperature-dependent reflectance behavior of bulk silicon, SUMMiT-V polycrystalline silicon films and metal surfaces is
International Nuclear Information System (INIS)
2013-01-01
The chapter one presents the composition of matter and atomic theory; matter structure; transitions; origin of radiation; radioactivity; nuclear radiation; interactions in decay processes; radiation produced by the interaction of radiation with matter
Thermodynamic tables to accompany Modern engineering thermodynamics
Balmer, Robert T
2011-01-01
This booklet is provided at no extra charge with new copies of Balmer's Modern Engineering Thermodynamics. It contains two appendices. Appendix C contains 40 thermodynamic tables, and Appendix D consists of 6 thermodynamic charts. These charts and tables are provided in a separate booklet to give instructors the flexibility of allowing students to bring the tables into exams. The booklet may be purchased separately if needed.
Classical and statistical thermodynamics
Rizk, Hanna A
2016-01-01
This is a text book of thermodynamics for the student who seeks thorough training in science or engineering. Systematic and thorough treatment of the fundamental principles rather than presenting the large mass of facts has been stressed. The book includes some of the historical and humanistic background of thermodynamics, but without affecting the continuity of the analytical treatment. For a clearer and more profound understanding of thermodynamics this book is highly recommended. In this respect, the author believes that a sound grounding in classical thermodynamics is an essential prerequisite for the understanding of statistical thermodynamics. Such a book comprising the two wide branches of thermodynamics is in fact unprecedented. Being a written work dealing systematically with the two main branches of thermodynamics, namely classical thermodynamics and statistical thermodynamics, together with some important indexes under only one cover, this treatise is so eminently useful.
International Nuclear Information System (INIS)
Lojpur, Vesna; Ćulubrk, Sanja; Dramićanin, Miroslav D.
2016-01-01
Herein, Eu 3+ doped Gd 2 Ti 2 O 7 nanoparticles were tested for application in ratiometric luminescence thermometry. It is shown that two combinations of emissions: one that uses two emissions of Eu 3+ ions and one that uses one emission of Eu 3+ ions and trap emission of Gd 2 Ti 2 O 7 provide thermometry over the 303–423 K temperature range with relative sensitivities between 0.14% K −1 and 0.95% K −1 . Thermometry based on two Eu 3+ emissions from 5 D 0 to 5 D 1 levels has a higher relative sensitivity, but lower absolute sensitivity than thermometry based on one Eu 3+ emission and trap emission of Gd 2 Ti 2 O 7 . The tested material is prepared by Pechini-type polymerized complex route and is composed of agglomerated nanoparticles of ~30–50 nm in size with pure-phase cubic structure (space group Fd-3m) as evidenced from electron microscopy and X-ray diffraction measurements. - Highlights: • Eu 3+ doped Gd 2 Ti 2 O 7 nanoparticles can serve as probes for luminescence thermometry. • Gd 2 Ti 2 O 7 trap emission is an excellent internal standard for luminescence thermometry. • Temperature is measured over 303–423 K range with sensitivity ranging 0.14–0.95% K −1 .
Eldridge, Jeffrey I.; Shyam, Vikram; Wroblewski, Adam C.; Zhu, Dongming; Cuy, Michael D.; Wolfe, Douglas E.
2016-01-01
While the effects of thermal barrier coating (TBC) thermal protection and air film cooling effectiveness are usually studied separately, their contributions to combined cooling effectiveness are interdependent and are not simply additive. Therefore, combined cooling effectiveness must be measured to achieve an optimum balance between TBC thermal protection and air film cooling. In this investigation, surface temperature mapping was performed using recently developed Cr-doped GdAlO3 phosphor thermometry. Measurements were performed in the NASA GRC Mach 0.3 burner rig on a TBC-coated plate using a scaled up cooling hole geometry where both the mainstream hot gas temperature and the blowing ratio were varied. Procedures for surface temperature and cooling effectiveness mapping of the air film-cooled TBC-coated surface are described. Applications are also shown for an engine component in both the burner rig test environment as well as an engine afterburner environment. The effects of thermal background radiation and flame chemiluminescence on the measurements are investigated, and advantages of this method over infrared thermography as well as the limitations of this method for studying air film cooling are discussed.
Ultrasonic Thermometry for In-Pile Temperature Detection
International Nuclear Information System (INIS)
Daw, J.E.; Rempe, J.L.; Wilkins, S.C.
2002-01-01
The Idaho National Laboratory has recently initiated a new effort to evaluate the viability of using ultrasonic thermometry technology as an improved sensor for detecting temperature during irradiation testing. Ultrasonic thermometers (UTs) work on the principle that the speed at which sound travels through a material (acoustic velocity) is dependant on the temperature of the material. By introducing an acoustic pulse to the sensor and measuring the time delay of echoes, temperature may be derived. UTs have several advantages over other sensor types. UTs can be made very small, as the sensor consists only of a small diameter rod which may or may not require a sheath. Measurements may be made near the melting point of the sensor material, as no electrical insulation is required; and shunting effects are avoided. Most attractive, however, is the ability to introduce acoustic discontinuities to the sensor, as this enables temperature measurements at several points along the sensor length (allowing temperature profiling with a single sensor). A typical multi-sensor UT system, with key components identified, is shown in Figure 1. As indicated in this figure, a narrow ultrasonic pulse is generated in a magnetostrictive rod by an excitation coil. The ultrasonic pulse propagates to the sensor wire, where a fraction of the pulse energy is reflected at each discontinuity (notches or diameter change). Each reflected pulse is received by the excitation coil, transformed into an electrical signal, amplified and evaluated in a start/stop counter system. The time interval between two adjacent echoes is evaluated and compared to a calibration curve to give the average temperature in the corresponding sensor segment. When a number of notches are available on the wire sensor, the various measurements give access to a temperature profile along the probe. UTs have been used successfully for several applications; however, several problems have limited the success of these sensors. For
Energy Technology Data Exchange (ETDEWEB)
Meister, D.; Huebner, F.; Mack, M.; Vogl, T.J. [Frankfurt Univ. (Germany). Inst. fuer Diagnostische und Interventionelle Radiologie
2007-05-15
Purpose: Evaluation of thermometry with fast MR sequences for laser-induced interstitial laser therapy (LITT) and verification of the thermometric results with a fiber-optic thermometer. Method and Materials: In vitro experiments were conducted using an agarose gel mixture and pig liver lobes. MR-guided LITT was performed using a laser power between 3 and 15?watts. Thermometry was performed using longitudinal relaxation time T1 and proton resonance frequency shift (PRF) methods under acquisition of amplitude and phase shift images. PRF was measured with a fast spoiled GRE sequence. Four different sequences were used for T1 thermometry: gradient echo (GE), TrueFISP (TRUFI), Saturation Recovery Turbo-FLASH (SRTF) and Inversion Recovery Turbo-FLASH (IRTF) sequences. The temperature was controlled using a fiber-optic Luxtron device and correlated with the MR temperature. The range of applied and monitored temperatures exceeded 80 degrees Celsius. Results: The temperature dependence showed a good linear relationship up to 60 degrees Celsius. Calibration experiments for the T1 method delivered coefficients of determination from 0.977 to 0.997 for agarose and from 0.958 to 0.995 for the pig liver samples. The IRTF sequence had the highest temperature sensitivity (agarose 0.99, liver 1.19). During LITT the TRUE-FISP sequence exhibited a strong nonlinear relationship. R{sup 2} of this sequence was 0.809 in the agarose experiments. The average temperature errors when heated up to 80 degrees Celsius were 3.86 - 11.38 degrees Celsius for Agarose gel and 5.7 - 12.16 degrees Celsius for the liver tissue. SRTF and IRTF sequences exhibited the most linear relationship with temperature but were more dependent on tissue differences. (orig.)
Thermodynamics in Einstein's thought
International Nuclear Information System (INIS)
Klein, M.J.
1983-01-01
The role of the thermodynamical approach in the Einstein's scientific work is analyzed. The Einstein's development of a notion about statistical fluctuations of thermodynamical systems that leads him to discovery of corpuscular-wave dualism is retraced
Thermodynamic theory of black holes
Energy Technology Data Exchange (ETDEWEB)
Davies, P C.W. [King' s Coll., London (UK). Dept. of Mathematics
1977-04-21
The thermodynamic theory underlying black hole processes is developed in detail and applied to model systems. It is found that Kerr-Newman black holes undergo a phase transition at a = 0.68M or Q = 0.86M, where the heat capacity has an infinite discontinuity. Above the transition values the specific heat is positive, permitting isothermal equilibrium with a surrounding heat bath. Simple processes and stability criteria for various black hole situations are investigated. The limits for entropically favoured black hole formation are found. The Nernst conditions for the third law of thermodynamics are not satisfied fully for black holes. There is no obvious thermodynamic reason why a black hole may not be cooled down below absolute zero and converted into a naked singularity. Quantum energy-momentum tensor calculations for uncharged black holes are extended to the Reissner-Nordstrom case, and found to be fully consistent with the thermodynamic picture for Q < M. For Q < M the model predicts that 'naked' collapse also produces radiation, with such intensity that the collapsing matter is entirely evaporated away before a naked singularity can form.
One Antimatter— Two Possible Thermodynamics
Directory of Open Access Journals (Sweden)
Alexander Y. Klimenko
2014-02-01
Full Text Available Conventional thermodynamics, which is formulated for our world populated by radiation and matter, can be extended to describe physical properties of antimatter in two mutually exclusive ways: CP-invariant or CPT-invariant. Here we refer to invariance of physical laws under charge (C, parity (P and time reversal (T transformations. While in quantum field theory CPT invariance is a theorem confirmed by experiments, the symmetry principles applied to macroscopic phenomena or to the whole of the Universe represent only hypotheses. Since both versions of thermodynamics are different only in their treatment of antimatter, but are the same in describing our world dominated by matter, making a clear experimentally justified choice between CP invariance and CPT invariance in context of thermodynamics is not possible at present. This work investigates the comparative properties of the CP- and CPT-invariant extensions of thermodynamics (focusing on the latter, which is less conventional than the former and examines conditions under which these extensions can be experimentally tested.
Advanced classical thermodynamics
International Nuclear Information System (INIS)
Emanuel, G.
1987-01-01
The theoretical and mathematical foundations of thermodynamics are presented in an advanced text intended for graduate engineering students. Chapters are devoted to definitions and postulates, the fundamental equation, equilibrium, the application of Jacobian theory to thermodynamics, the Maxwell equations, stability, the theory of real gases, critical-point theory, and chemical thermodynamics. Diagrams, graphs, tables, and sample problems are provided. 38 references
Mei, Jie; Riedel, Nico; Grittner, Ulrike; Endres, Matthias; Banneke, Stefanie; Emmrich, Julius Valentin
2018-02-23
Body temperature is a valuable parameter in determining the wellbeing of laboratory animals. However, using body temperature to refine humane endpoints during acute illness generally lacks comprehensiveness and exposes to inter-observer bias. Here we compared two methods to assess body temperature in mice, namely implanted radio frequency identification (RFID) temperature transponders (method 1) to non-contact infrared thermometry (method 2) in 435 mice for up to 7 days during normothermia and lipopolysaccharide (LPS) endotoxin-induced hypothermia. There was excellent agreement between core and surface temperature as determined by method 1 and 2, respectively, whereas the intra- and inter-subject variation was higher for method 2. Nevertheless, using machine learning algorithms to determine temperature-based endpoints both methods had excellent accuracy in predicting death as an outcome event. Therefore, less expensive and cumbersome non-contact infrared thermometry can serve as a reliable alternative for implantable transponder-based systems for hypothermic responses, although requiring standardization between experimenters.
Feasibility of Johnson Noise Thermometry based on Digital Signal Processing Techniques
International Nuclear Information System (INIS)
Hwang, In Koo; Kim, Yang Mo
2014-01-01
This paper presents an implementation strategy of noise thermometry based on a digital signal processing technique and demonstrates its feasibilities. A key factor in its development is how to extract the small thermal noise signal from other noises, for example, random noise from amplifiers and continuous electromagnetic interference from the environment. The proposed system consists of two identical amplifiers and uses a cross correlation function to cancel the random noise of the amplifiers. Then, the external interference noises are eliminated by discriminating the difference in the peaks between the thermal signal and external noise. The gain of the amplifiers is estimated by injecting an already known pilot signal. The experimental simulation results of signal processing methods have demonstrated that the proposed approach is an effective method in eliminating an external noise signal and performing gain correction for development of the thermometry
Luminescence thermometry with Eu{sup 3+} doped GdAlO{sub 3}
Energy Technology Data Exchange (ETDEWEB)
Lojpur, Vesna, E-mail: vesna.lojpur@yahoo.com; Ćulubrk, Sanja; Medić, Mina; Dramicanin, Miroslav
2016-02-15
Eu{sup 3+} doped GdAlO{sub 3} powder synthesized by solid state reaction was investigated for application in luminescence thermometry. Phase composition of material was confirmed by X-ray powder diffraction analysis. The photoluminescence emission spectra were collected under excitation of 399 nm, while elevating the temperature of the sample from the room temperature to 793 K. Emissions from {sup 5}D{sub 1}→{sup 7}F{sub 1} and {sup 5}D{sub 0}→{sup 7}F{sub 2} characteristic transitions of Eu{sup 3+} ions are selected for the temperature-dependence study using the fluorescence intensity ratio method. Emission decay curves measured at the strongest emission peak centered at 614 nm were recorded in a same temperature range. Data analysis showed that thermometry by fluorescence intensity ratio method can be used over the temperature region 293–793 K with the maximal relative sensitivity of 2.96% K{sup −1} (at 293 K). Temporal dependence of emission (lifetime) provides temperature sensing from 620 to 793 K with the maximal relative sensitivity of 2.28% K{sup −1}. - Highlights: • GdAlO{sub 3}: 4 at% of Eu{sup 3+} can be used for luminescence thermometry in the 293–793 K range. • Combined FIR and lifetime thermometry provide >0.5% K{sup −1} relative sensitivity. • Temperature dependence of lifetime is well described energy gap law model.
Statistical black-hole thermodynamics
International Nuclear Information System (INIS)
Bekenstein, J.D.
1975-01-01
Traditional methods from statistical thermodynamics, with appropriate modifications, are used to study several problems in black-hole thermodynamics. Jaynes's maximum-uncertainty method for computing probabilities is used to show that the earlier-formulated generalized second law is respected in statistically averaged form in the process of spontaneous radiation by a Kerr black hole discovered by Hawking, and also in the case of a Schwarzschild hole immersed in a bath of black-body radiation, however cold. The generalized second law is used to motivate a maximum-entropy principle for determining the equilibrium probability distribution for a system containing a black hole. As an application we derive the distribution for the radiation in equilibrium with a Kerr hole (it is found to agree with what would be expected from Hawking's results) and the form of the associated distribution among Kerr black-hole solution states of definite mass. The same results are shown to follow from a statistical interpretation of the concept of black-hole entropy as the natural logarithm of the number of possible interior configurations that are compatible with the given exterior black-hole state. We also formulate a Jaynes-type maximum-uncertainty principle for black holes, and apply it to obtain the probability distribution among Kerr solution states for an isolated radiating Kerr hole
Introduction to applied thermodynamics
Helsdon, R M; Walker, G E
1965-01-01
Introduction to Applied Thermodynamics is an introductory text on applied thermodynamics and covers topics ranging from energy and temperature to reversibility and entropy, the first and second laws of thermodynamics, and the properties of ideal gases. Standard air cycles and the thermodynamic properties of pure substances are also discussed, together with gas compressors, combustion, and psychrometry. This volume is comprised of 16 chapters and begins with an overview of the concept of energy as well as the macroscopic and molecular approaches to thermodynamics. The following chapters focus o
Twenty lectures on thermodynamics
Buchdahl, H A
2013-01-01
Twenty Lectures on Thermodynamics is a course of lectures, parts of which the author has given various times over the last few years. The book gives the readers a bird's eye view of phenomenological and statistical thermodynamics. The book covers many areas in thermodynamics such as states and transition; adiabatic isolation; irreversibility; the first, second, third and Zeroth laws of thermodynamics; entropy and entropy law; the idea of the application of thermodynamics; pseudo-states; the quantum-static al canonical and grand canonical ensembles; and semi-classical gaseous systems. The text
International Nuclear Information System (INIS)
Pandeya, G.D.; Klaessens, J.H.G.M.; Greuter, M.J.W.; Oudkerk, M.; Schmidt, B.; Flohr, T.; Hillegersberg, R. van
2011-01-01
To assess the feasibility of computed tomography (CT) based thermometry during interstitial laser heating in the bovine liver. Four freshly exercised cylindrical blocks of bovine tissue were heated using a continuous laser of Nd:YAG (wavelength: 1064 nm, active length: 30 mm, power: 10-30 W). All tissues were imaged at least once before and 7 times during laser heating using CT and temperatures were simultaneously measured with 5 calibrated thermal sensors. The dependency of the average CT numbers as a function of temperature was analysed with regression analysis and a CT thermal sensitivity was derived. During laser heating, the growing hypodense area was observed around the laser source and that area showed an increase as a function of time. The formation of hypodense area was caused by declining in CT numbers at increasing temperatures. The regression analysis showed an inverse linear dependency between temperature and average CT number with -0.65 ± 0.048 HU/ C (R 2 = 0.75) for the range of 18-85 C in bovine liver. The non-invasive CT based thermometry during interstitial laser heating is feasible in the bovine liver. CT based thermometry could be further developed and may be of potential use during clinical LITT of the liver. (orig.)
Thermodynamical properties of dark energy
International Nuclear Information System (INIS)
Gong Yungui; Wang Bin; Wang Anzhong
2007-01-01
We have investigated the thermodynamical properties of dark energy. Assuming that the dark energy temperature T∼a -n and considering that the volume of the Universe enveloped by the apparent horizon relates to the temperature, we have derived the dark energy entropy. For dark energy with constant equation of state w>-1 and the generalized Chaplygin gas, the derived entropy can be positive and satisfy the entropy bound. The total entropy, including those of dark energy, the thermal radiation, and the apparent horizon, satisfies the generalized second law of thermodynamics. However, for the phantom with constant equation of state, the positivity of entropy, the entropy bound, and the generalized second law cannot be satisfied simultaneously
Rational extended thermodynamics
Müller, Ingo
1998-01-01
Ordinary thermodynamics provides reliable results when the thermodynamic fields are smooth, in the sense that there are no steep gradients and no rapid changes. In fluids and gases this is the domain of the equations of Navier-Stokes and Fourier. Extended thermodynamics becomes relevant for rapidly varying and strongly inhomogeneous processes. Thus the propagation of high frequency waves, and the shape of shock waves, and the regression of small-scale fluctuation are governed by extended thermodynamics. The field equations of ordinary thermodynamics are parabolic while extended thermodynamics is governed by hyperbolic systems. The main ingredients of extended thermodynamics are • field equations of balance type, • constitutive quantities depending on the present local state and • entropy as a concave function of the state variables. This set of assumptions leads to first order quasi-linear symmetric hyperbolic systems of field equations; it guarantees the well-posedness of initial value problems and f...
Wang, Peng; Hu, Zhenwei; Xie, Zhi; Yan, Ming
2018-05-01
An experimental apparatus has been designed for measuring the emissivity of a steel surface in both vacuum and oxidation atmosphere. The sample is heated with the method of electromagnetic induction in order to ensure the temperature uniformity. The radiance emitted from a sample is measured using a fiber-optic Fourier transform infrared spectrometer. Using this unique apparatus, we investigated the spectral (2-6 μm) and directional (0°-86°) emissivity of stainless steel 304 with different degrees of surface oxidation at temperatures ranging from 800 to 1100 °C. The experimental results show that the emissivity increases slightly with increasing temperature, which accords with the Hagen-Rubens relation. The emissivity increases rapidly at the initial stage of oxidation, but gradually reaches to a constant value after 20 min. In addition, the directional emissivity has a maximum value at the measuring angle of about 75°. The maximum uncertainty of emissivity is only 3.0% over all the measuring ranges, indicating that this experimental apparatus has a high reliability. In order to measure the surface temperature of casting billets based on multi-wavelength thermometry, the bivariate emissivity function with the two variables, wavelength and temperature, is determined. Temperature measurement results based on our technique are compared with those from common dual-wavelength radiation thermometry. Our approach reduces the measured temperature fluctuation from ±20.7 °C to ±2.8 °C and reflects the temperature variation with the changes of production parameters in real time.
An introduction to equilibrium thermodynamics
Morrill, Bernard; Hartnett, James P; Hughes, William F
1973-01-01
An Introduction to Equilibrium Thermodynamics discusses classical thermodynamics and irreversible thermodynamics. It introduces the laws of thermodynamics and the connection between statistical concepts and observable macroscopic properties of a thermodynamic system. Chapter 1 discusses the first law of thermodynamics while Chapters 2 through 4 deal with statistical concepts. The succeeding chapters describe the link between entropy and the reversible heat process concept of entropy; the second law of thermodynamics; Legendre transformations and Jacobian algebra. Finally, Chapter 10 provides a
Thermodynamics for scientists and engineers
International Nuclear Information System (INIS)
Lim, Gyeong Hui
2011-02-01
This book deals with thermodynamics for scientists and engineers. It consists of 11 chapters, which are concept and background of thermodynamics, the first law of thermodynamics, the second law of thermodynamics and entropy, mathematics related thermodynamics, properties of thermodynamics on pure material, equilibrium, stability of thermodynamics, the basic of compound, phase equilibrium of compound, excess gibbs energy model of compound and activity coefficient model and chemical equilibrium. It has four appendixes on properties of pure materials and thermal mass.
Thermodynamics of Bioreactions.
Held, Christoph; Sadowski, Gabriele
2016-06-07
Thermodynamic principles have been applied to enzyme-catalyzed reactions since the beginning of the 1930s in an attempt to understand metabolic pathways. Currently, thermodynamics is also applied to the design and analysis of biotechnological processes. The key thermodynamic quantity is the Gibbs energy of reaction, which must be negative for a reaction to occur spontaneously. However, the application of thermodynamic feasibility studies sometimes yields positive Gibbs energies of reaction even for reactions that are known to occur spontaneously, such as glycolysis. This article reviews the application of thermodynamics in enzyme-catalyzed reactions. It summarizes the basic thermodynamic relationships used for describing the Gibbs energy of reaction and also refers to the nonuniform application of these relationships in the literature. The review summarizes state-of-the-art approaches that describe the influence of temperature, pH, electrolytes, solvents, and concentrations of reacting agents on the Gibbs energy of reaction and, therefore, on the feasibility and yield of biological reactions.
Thermodynamically efficient solar concentrators
Winston, Roland
2012-10-01
Non-imaging Optics is the theory of thermodynamically efficient optics and as such depends more on thermodynamics than on optics. Hence in this paper a condition for the "best" design is proposed based on purely thermodynamic arguments, which we believe has profound consequences for design of thermal and even photovoltaic systems. This new way of looking at the problem of efficient concentration depends on probabilities, the ingredients of entropy and information theory while "optics" in the conventional sense recedes into the background.
Black Holes and Thermodynamics
Wald, Robert M.
1997-01-01
We review the remarkable relationship between the laws of black hole mechanics and the ordinary laws of thermodynamics. It is emphasized that - in analogy with the laws of thermodynamics - the validity the laws of black hole mechanics does not appear to depend upon the details of the underlying dynamical theory (i.e., upon the particular field equations of general relativity). It also is emphasized that a number of unresolved issues arise in ``ordinary thermodynamics'' in the context of gener...
Cryogenic engineering and thermometry for an in-core apparatus
International Nuclear Information System (INIS)
Clark, D.D.; Spern, S.A.; Atwood, A.G.; Ouellet, C.G.; Decker, F.H.
1996-01-01
During the design, construction, and testing of the final model of the cold neutron source for the cold neutron beam facility of the Cornell TRIGA reactor, several interesting cryogenic and thermometric problems were encountered. This paper summarizes some of those problems and their solutions. The goal is to maintain an aluminum chamber containing 110cm 3 of mesitylene at 30 K or below in the presence of radiation fields of 1 x 10 12 thermal n/cm 2 · s, 3.8 x 10 10 fast n/cm 2 · s, and 1.4 x 10 3 rad/s of gamma rays known to exist at 500 kW within the beam port 17 cm from the core edge. Cooling is accomplished by conduction through a 1.85-cm-diam, 261-cm-long copper rod connecting the chamber to a two-stage Gifford-McMahon cryorefrigerator located outside the reactor bulk shield. It is desirable to measure the temperatures of the chamber, the refrigerator, and a number of other system components for monitoring and diagnostic purposes. The principal concerns are the heat loads and radiation effects caused by the nuclear radiation
Reiss, Howard
1997-01-01
Since there is no shortage of excellent general books on elementary thermodynamics, this book takes a different approach, focusing attention on the problem areas of understanding of concept and especially on the overwhelming but usually hidden role of ""constraints"" in thermodynamics, as well as on the lucid exposition of the significance, construction, and use (in the case of arbitrary systems) of the thermodynamic potential. It will be especially useful as an auxiliary text to be used along with any standard treatment.Unlike some texts, Methods of Thermodynamics does not use statistical m
Thermodynamics of nuclear materials
International Nuclear Information System (INIS)
Rand, M.H.
1975-01-01
A report is presented of the Fourth International Symposium on Thermodynamics of Nuclear Materials held in Vienna, 21-25 October 1974. The technological theme of the Symposium was the application of thermodynamics to the understanding of the chemistry of irradiated nuclear fuels and to safety assessments for hypothetical accident conditions in reactors. The first four sessions were devoted to these topics and they were followed by four more sessions on the more basic thermodynamics, phase diagrams and the thermodynamic properties of a wide range of nuclear materials. Sixty-seven papers were presented
Thermodynamic and Quantum Thermodynamic Analyses of Brownian Movement
Gyftopoulos, Elias P.
2006-01-01
Thermodynamic and quantum thermodynamic analyses of Brownian movement of a solvent and a colloid passing through neutral thermodynamic equilibrium states only. It is shown that Brownian motors and E. coli do not represent Brownian movement.
Energy Technology Data Exchange (ETDEWEB)
Tatebe, Ken, E-mail: Ken.Tatebe@gmail.com [Department of Radiology, University of Texas Southwestern Medical Center, 5323 Harry Hines Boulevard, Dallas, Texas 75390 (United States); Ramsay, Elizabeth; Kazem, Mohammad; Peikari, Hamed [Physical Sciences, Sunnybrook Research Institute, 2075 Bayview Avenue, Toronto, Ontario M4N3M5 (Canada); Mougenot, Charles [Philips Healthcare, 281 Hillmount Road, Markham, Ontario L6C 2S3 (Canada); Bronskill, Michael [Physical Sciences, Sunnybrook Research Institute, 2075 Bayview Avenue, Toronto, Ontario M4N3M5, Canada and Department of Medical Biophysics, University of Toronto, 610 University Avenue, Toronto, Ontario M5G2M9 (Canada); Chopra, Rajiv [Department of Radiology, University of Texas Southwestern Medical Center, 5323 Harry Hines Boulevard, Dallas, Texas 75390 (United States); Advanced Imaging Research Center, University of Texas Southwestern Medical Center, 5323 Harry Hines Boulevard, Dallas, Texas 75390 (United States); Physical Sciences, Sunnybrook Research Institute, 2075 Bayview Avenue, Toronto, Ontario M4N3M5 (Canada); Department of Medical Biophysics, University of Toronto, 610 University Avenue, Toronto, Ontario M5G2M9 (Canada)
2016-01-15
Purpose: Magnetic resonance imaging (MRI) is capable of providing valuable real-time feedback during medical procedures, partly due to the excellent soft-tissue contrast available. Several technical hurdles still exist to seamless integration of medical devices with MRI due to incompatibility of most conventional devices with this imaging modality. In this study, the effect of local perturbations in the magnetic field caused by the magnetization of medical devices was examined using finite element analysis modeling. As an example, the influence of the geometric and material characteristics of a transurethral high-intensity ultrasound applicator on temperature measurements using proton resonance frequency (PRF)-shift thermometry was investigated. Methods: The effect of local perturbations in the magnetic field, caused by the magnetization of medical device components, was examined using finite element analysis modeling. The thermometry artifact generated by a transurethral ultrasound applicator was simulated, and these results were validated against analytic models and scans of an applicator in a phantom. Several parameters were then varied to identify which most strongly impacted the level of simulated thermometry artifact, which varies as the applicator moves over the course of an ablative high-intensity ultrasound treatment. Results: Key design parameters identified as having a strong influence on the magnitude of thermometry artifact included the susceptibility of materials and their volume. The location of components was also important, particularly when positioned to maximize symmetry of the device. Finally, the location of component edges and the inclination of the device relative to the magnetic field were also found to be important factors. Conclusions: Previous design strategies to minimize thermometry artifact were validated, and novel design strategies were identified that substantially reduce PRF-shift thermometry artifacts for a variety of device
International Nuclear Information System (INIS)
Tatebe, Ken; Ramsay, Elizabeth; Kazem, Mohammad; Peikari, Hamed; Mougenot, Charles; Bronskill, Michael; Chopra, Rajiv
2016-01-01
Purpose: Magnetic resonance imaging (MRI) is capable of providing valuable real-time feedback during medical procedures, partly due to the excellent soft-tissue contrast available. Several technical hurdles still exist to seamless integration of medical devices with MRI due to incompatibility of most conventional devices with this imaging modality. In this study, the effect of local perturbations in the magnetic field caused by the magnetization of medical devices was examined using finite element analysis modeling. As an example, the influence of the geometric and material characteristics of a transurethral high-intensity ultrasound applicator on temperature measurements using proton resonance frequency (PRF)-shift thermometry was investigated. Methods: The effect of local perturbations in the magnetic field, caused by the magnetization of medical device components, was examined using finite element analysis modeling. The thermometry artifact generated by a transurethral ultrasound applicator was simulated, and these results were validated against analytic models and scans of an applicator in a phantom. Several parameters were then varied to identify which most strongly impacted the level of simulated thermometry artifact, which varies as the applicator moves over the course of an ablative high-intensity ultrasound treatment. Results: Key design parameters identified as having a strong influence on the magnitude of thermometry artifact included the susceptibility of materials and their volume. The location of components was also important, particularly when positioned to maximize symmetry of the device. Finally, the location of component edges and the inclination of the device relative to the magnetic field were also found to be important factors. Conclusions: Previous design strategies to minimize thermometry artifact were validated, and novel design strategies were identified that substantially reduce PRF-shift thermometry artifacts for a variety of device
Black-Body Radiation Correction to the Polarizability of Helium
Puchalski, M.; Jentschura, U. D.; Mohr, P. J.
2011-01-01
The correction to the polarizability of helium due to black-body radiation is calculated near room temperature. A precise theoretical determination of the black-body radiation correction to the polarizability of helium is essential for dielectric gas thermometry and for the determination of the Boltzmann constant. We find that the correction, for not too high temperature, is roughly proportional to a modified hyperpolarizability (two-color hyperpolarizability), which is different from the ord...
Lazo-Porras, Maria; Bernabe-Ortiz, Antonio; Sacksteder, Katherine A; Gilman, Robert H; Malaga, German; Armstrong, David G; Miranda, J Jaime
2016-04-19
Diabetic foot neuropathy (DFN) is one of the most important complications of diabetes mellitus; its early diagnosis and intervention can prevent foot ulcers and the need for amputation. Thermometry, measuring the temperature of the feet, is a promising emerging modality for diabetic foot ulcer prevention. However, patient compliance with at-home monitoring is concerning. Delivering messages to remind patients to perform thermometry and foot care might be helpful to guarantee regular foot monitoring. This trial was designed to compare the incidence of diabetic foot ulcers (DFUs) between participants who receive thermometry alone and those who receive thermometry as well as mHealth (SMS and voice messaging) over a year-long study period. This is an evaluator-blinded, randomized, 12-month trial. Individuals with a diagnosis of type 2 diabetes mellitus, aged between 18-80 years, having a present dorsalis pedis pulse in both feet, are in risk group 2 or 3 using the diabetic foot risk classification system (as specified by the International Working Group on the Diabetic Foot), have an operating cell phone or a caregiver with an operating cell phone, and have the ability to provide informed consent will be eligible to participate in the study. Recruitment will be performed in diabetes outpatient clinics at two Ministry of Health tertiary hospitals in Lima, Peru. participants in both groups will receive education about foot care at the beginning of the study and they will be provided with a thermometry device (TempStat™). TempStat™ is a tool that captures a thermal image of the feet, which, depending on the temperature of the feet, shows different colors. In this study, if a participant notes a single yellow image or variance between one foot and the contralateral foot, they will be prompted to notify a nurse to evaluate their activity within the previous 2 weeks and make appropriate recommendations. In addition to thermometry, participants in the intervention arm
Dangarembizi, Rachael; Erlwanger, Kennedy H; Mitchell, Duncan; Hetem, Robyn S; Madziva, Michael T; Harden, Lois M
2017-10-01
Stress-induced hyperthermia following rectal thermometry is reported in normothermic rats, but appears to be muted or even absent in febrile rats. We therefore investigated whether the use of rectal thermometry affects the accuracy of temperature responses recorded in normothermic and febrile rats. Using intra-abdominally implanted temperature-sensitive radiotelemeters we measured the temperature response to rectal temperature measurement in male Sprague Dawley rats (~200g) injected subcutaneously with Brewer's yeast (20ml/kg of a 20% Brewer's yeast solution=4000mg/kg) or saline (20ml/kg of 0.9% saline). Rats had been pre-exposed to, or were naive to rectal temperature measurement before the injection. The first rectal temperature measurement was taken in the plateau phase of the fever (18h after injection) and at hourly intervals thereafter. In normothermic rats, rectal temperature measurement was associated with an increase in abdominal temperature (0.66±0.27°C) that had a rapid onset (5-10min), peaked at 15-20min and lasted for 35-50min. The hyperthermic response to rectal temperature measurement was absent in febrile rats. Exposure to rectal temperature measurement on two previous occasions did not reduce the hyperthermia. There was a significant positive linear association between temperatures recorded using the two methods, but the agreement interval identified that rectal temperature measured with a thermocouple probe could either be 0.7°C greater or 0.5°C lower than abdominal temperature measured with radiotelemeter. Thus, due to stress-induced hyperthermia, rectal thermometry does not ensure accurate recording of body temperature in short-spaced, intermittent intervals in normothermic and febrile rats. Copyright © 2017 Elsevier Inc. All rights reserved.
Robust adaptive extended Kalman filtering for real time MR-thermometry guided HIFU interventions.
Roujol, Sébastien; de Senneville, Baudouin Denis; Hey, Silke; Moonen, Chrit; Ries, Mario
2012-03-01
Real time magnetic resonance (MR) thermometry is gaining clinical importance for monitoring and guiding high intensity focused ultrasound (HIFU) ablations of tumorous tissue. The temperature information can be employed to adjust the position and the power of the HIFU system in real time and to determine the therapy endpoint. The requirement to resolve both physiological motion of mobile organs and the rapid temperature variations induced by state-of-the-art high-power HIFU systems require fast MRI-acquisition schemes, which are generally hampered by low signal-to-noise ratios (SNRs). This directly limits the precision of real time MR-thermometry and thus in many cases the feasibility of sophisticated control algorithms. To overcome these limitations, temporal filtering of the temperature has been suggested in the past, which has generally an adverse impact on the accuracy and latency of the filtered data. Here, we propose a novel filter that aims to improve the precision of MR-thermometry while monitoring and adapting its impact on the accuracy. For this, an adaptive extended Kalman filter using a model describing the heat transfer for acoustic heating in biological tissues was employed together with an additional outlier rejection to address the problem of sparse artifacted temperature points. The filter was compared to an efficient matched FIR filter and outperformed the latter in all tested cases. The filter was first evaluated on simulated data and provided in the worst case (with an approximate configuration of the model) a substantial improvement of the accuracy by a factor 3 and 15 during heat up and cool down periods, respectively. The robustness of the filter was then evaluated during HIFU experiments on a phantom and in vivo in porcine kidney. The presence of strong temperature artifacts did not affect the thermal dose measurement using our filter whereas a high measurement variation of 70% was observed with the FIR filter.
Kalman Filtered Bio Heat Transfer Model Based Self-adaptive Hybrid Magnetic Resonance Thermometry.
Zhang, Yuxin; Chen, Shuo; Deng, Kexin; Chen, Bingyao; Wei, Xing; Yang, Jiafei; Wang, Shi; Ying, Kui
2017-01-01
To develop a self-adaptive and fast thermometry method by combining the original hybrid magnetic resonance thermometry method and the bio heat transfer equation (BHTE) model. The proposed Kalman filtered Bio Heat Transfer Model Based Self-adaptive Hybrid Magnetic Resonance Thermometry, abbreviated as KalBHT hybrid method, introduced the BHTE model to synthesize a window on the regularization term of the hybrid algorithm, which leads to a self-adaptive regularization both spatially and temporally with change of temperature. Further, to decrease the sensitivity to accuracy of the BHTE model, Kalman filter is utilized to update the window at each iteration time. To investigate the effect of the proposed model, computer heating simulation, phantom microwave heating experiment and dynamic in-vivo model validation of liver and thoracic tumor were conducted in this study. The heating simulation indicates that the KalBHT hybrid algorithm achieves more accurate results without adjusting λ to a proper value in comparison to the hybrid algorithm. The results of the phantom heating experiment illustrate that the proposed model is able to follow temperature changes in the presence of motion and the temperature estimated also shows less noise in the background and surrounding the hot spot. The dynamic in-vivo model validation with heating simulation demonstrates that the proposed model has a higher convergence rate, more robustness to susceptibility problem surrounding the hot spot and more accuracy of temperature estimation. In the healthy liver experiment with heating simulation, the RMSE of the hot spot of the proposed model is reduced to about 50% compared to the RMSE of the original hybrid model and the convergence time becomes only about one fifth of the hybrid model. The proposed model is able to improve the accuracy of the original hybrid algorithm and accelerate the convergence rate of MR temperature estimation.
Granet, Irving
2014-01-01
Fundamental ConceptsIntroductionThermodynamic SystemsTemperatureForce and MassElementary Kinetic Theory of GasesPressureReviewKey TermsEquations Developed in This ChapterQuestionsProblemsWork, Energy, and HeatIntroductionWorkEnergyInternal EnergyPotential EnergyKinetic EnergyHeatFlow WorkNonflow WorkReviewKey TermsEquations Developed in This ChapterQuestionsProblemsFirst Law of ThermodynamicsIntroductionFirst Law of ThermodynamicsNonflow SystemSteady-Flow SystemApplications of First Law of ThermodynamicsReviewKey TermsEquations Developed in This ChapterQuestionsProblemsThe Second Law of ThermodynamicsIntroductionReversibility-Second Law of ThermodynamicsThe Carnot CycleEntropyReviewKey TermsEquations Developed in This ChapterQuestionsProblemsProperties of Liquids and GasesIntroductionLiquids and VaporsThermodynamic Properties of SteamComputerized PropertiesThermodynamic DiagramsProcessesReviewKey TermsEquations Developed in This ChapterQuestionsProblemsThe Ideal GasIntroductionBasic ConsiderationsSpecific Hea...
Quasiparticles and thermodynamical consistency
International Nuclear Information System (INIS)
Shanenko, A.A.; Biro, T.S.; Toneev, V.D.
2003-01-01
A brief and simple introduction into the problem of the thermodynamical consistency is given. The thermodynamical consistency relations, which should be taken into account under constructing a quasiparticle model, are found in a general manner from the finite-temperature extension of the Hellmann-Feynman theorem. Restrictions following from these relations are illustrated by simple physical examples. (author)
All-Optical Nanoscale Thermometry using Silicon-Vacancy Centers in Diamond
Nguyen, Christian; Evans, Ruffin; Sipahigil, Alp; Bhaskar, Mihir; Sukachev, Denis; Lukin, Mikhail
2017-04-01
Accurate thermometry at the nanoscale is a difficult challenge, but building such a thermometer would be a powerful tool for discovering and understanding new processes in biology, chemistry and physics. Applications include cell-selective treatment of disease, engineering of more efficient integrated circuits, or even the development of new chemical and biological reactions. In this work, we study how the bulk properties of the Silicon Vacancy center (SiV) in diamond depend on temperature, and use them to measure temperature with 100mK accuracy. Using SiVs in 200 nm nanodiamonds, we measure the temperature with 100 nm spatial resolution over a 10 μm area.
Two-dimensional thermometry by using neutron resonance absorption spectrometer DOG
International Nuclear Information System (INIS)
Kamiyama, T.; Noda, H.; Kiyanagi, Y.; Ikeda, S.
2001-01-01
We applied the neutron resonance absorption spectroscopy to thermometry of a bulk object. The measurement was done by using the neutron resonance absorption spectrometer, DOG, installed at KENS, High Energy Accelerator Research Organization Neutron Source, which enables us to investigate effective temperature of a particular element by analyzing line width of resonance absorption spectrum. The effective temperature becomes consistence with the sample temperature above room temperature. For the analysis we applied the computed tomography method to reconstruct the temperature distribution on the object cross section. The results and the calculated distribution by the heat conducting equation are well agreed on the temperature difference inside the object. (author)
A new method of liquid crystal thermometry excluding human color sensation
International Nuclear Information System (INIS)
Kunugi, Tomoaki; Akino, Norio; Ueda, Masaharu.
1987-01-01
Some choresteric liquid crystals can be used as a thermometer because of their color changes with varying temperatures. However, it is impossible to employ human color sensation for precise quantitative evaluation of temperature from their color. Therefore, a new method of liquid crystal thermometry is developed using narrow band optical filters and an image processor to exclude the employment of human color sensation. Relations between filter wavelength and temperature were determined by calibration tests. Two dimensional temperature distributions on a heated plate were successfully measured by the present method. (author)
International Nuclear Information System (INIS)
Gillies, G.T.; Dowell, L.J.; Lutz, W.N.; Allison, S.W.; Cates, M.R.; Noel, B.W.; Franks, L.A.; Borella, H.M.
1987-10-01
There are a growing number of industrial measurement situations that call for a high precision, noncontact method of thermometry. Our collaboration has been successful in developing one such method based on the laser-induced fluorescence of rare-earth-doped ceramic phosphors like Y 2 O 3 :Eu. In this paper, we summarize the results of characterization studies aimed at identifying the sources of systematic error in a laboratory-grade version of the method. We then go on to present data from measurements made in the afterburner plume of a jet turbine and inside an operating permanent magnet motor. 12 refs., 6 figs
Equilibrium thermodynamics - Callen's postulational approach
Jongschaap, R.J.J.; Öttinger, Hans Christian
2001-01-01
In order to provide the background for nonequilibrium thermodynamics, we outline the fundamentals of equilibrium thermodynamics. Equilibrium thermodynamics must not only be obtained as a special case of any acceptable nonequilibrium generalization but, through its shining example, it also elucidates
Applied chemical engineering thermodynamics
Tassios, Dimitrios P
1993-01-01
Applied Chemical Engineering Thermodynamics provides the undergraduate and graduate student of chemical engineering with the basic knowledge, the methodology and the references he needs to apply it in industrial practice. Thus, in addition to the classical topics of the laws of thermodynamics,pure component and mixture thermodynamic properties as well as phase and chemical equilibria the reader will find: - history of thermodynamics - energy conservation - internmolecular forces and molecular thermodynamics - cubic equations of state - statistical mechanics. A great number of calculated problems with solutions and an appendix with numerous tables of numbers of practical importance are extremely helpful for applied calculations. The computer programs on the included disk help the student to become familiar with the typical methods used in industry for volumetric and vapor-liquid equilibria calculations.
Thermodynamics an engineering approach
Cengel, Yunus A
2014-01-01
Thermodynamics, An Engineering Approach, eighth edition, covers the basic principles of thermodynamics while presenting a wealth of real-world engineering examples so students get a feel for how thermodynamics is applied in engineering practice. This text helps students develop an intuitive understanding by emphasizing the physics and physical arguments. Cengel and Boles explore the various facets of thermodynamics through careful explanations of concepts and use of numerous practical examples and figures, having students develop necessary skills to bridge the gap between knowledge and the confidence to properly apply their knowledge. McGraw-Hill is proud to offer Connect with the eighth edition of Cengel/Boles, Thermodynamics, An Engineering Approach. This innovative and powerful new system helps your students learn more efficiently and gives you the ability to assign homework problems simply and easily. Problems are graded automatically, and the results are recorded immediately. Track individual stude...
Thermodynamic estimation: Ionic materials
International Nuclear Information System (INIS)
Glasser, Leslie
2013-01-01
Thermodynamics establishes equilibrium relations among thermodynamic parameters (“properties”) and delineates the effects of variation of the thermodynamic functions (typically temperature and pressure) on those parameters. However, classical thermodynamics does not provide values for the necessary thermodynamic properties, which must be established by extra-thermodynamic means such as experiment, theoretical calculation, or empirical estimation. While many values may be found in the numerous collected tables in the literature, these are necessarily incomplete because either the experimental measurements have not been made or the materials may be hypothetical. The current paper presents a number of simple and relible estimation methods for thermodynamic properties, principally for ionic materials. The results may also be used as a check for obvious errors in published values. The estimation methods described are typically based on addition of properties of individual ions, or sums of properties of neutral ion groups (such as “double” salts, in the Simple Salt Approximation), or based upon correlations such as with formula unit volumes (Volume-Based Thermodynamics). - Graphical abstract: Thermodynamic properties of ionic materials may be readily estimated by summation of the properties of individual ions, by summation of the properties of ‘double salts’, and by correlation with formula volume. Such estimates may fill gaps in the literature, and may also be used as checks of published values. This simplicity arises from exploitation of the fact that repulsive energy terms are of short range and very similar across materials, while coulombic interactions provide a very large component of the attractive energy in ionic systems. Display Omitted - Highlights: • Estimation methods for thermodynamic properties of ionic materials are introduced. • Methods are based on summation of single ions, multiple salts, and correlations. • Heat capacity, entropy
On the thermodynamics of hairy black holes
Energy Technology Data Exchange (ETDEWEB)
Anabalón, Andrés [Departamento de Ciencias, Facultad de Artes Liberales y Facultad de Ingeniería y Ciencias, Universidad Adolfo Ibáñez, Viña del Mar (Chile); Astefanesei, Dumitru [Instituto de Física, Pontificia Universidad Católica de Valparaíso, Casilla 4059, Valparaíso (Chile); Choque, David, E-mail: brst1010123@gmail.com [Universidad Técnica Federico Santa María, Av. España 1680, Valparaiso (Chile)
2015-04-09
We investigate the thermodynamics of a general class of exact 4-dimensional asymptotically Anti-de Sitter hairy black hole solutions and show that, for a fixed temperature, there are small and large hairy black holes similar to the Schwarzschild–AdS black hole. The large black holes have positive specific heat and so they can be in equilibrium with a thermal bath of radiation at the Hawking temperature. The relevant thermodynamic quantities are computed by using the Hamiltonian formalism and counterterm method. We explicitly show that there are first order phase transitions similar to the Hawking–Page phase transition.
International Nuclear Information System (INIS)
Mansson, B.A.
1990-01-01
Economics, as the social science most concerned with the use and distribution of natural resources, must start to make use of the knowledge at hand in the natural sciences about such resources. In this, thermodynamics is an essential part. In a physicists terminology, human economic activity may be described as a dissipative system which flourishes by transforming and exchanging resources, goods and services. All this involves complex networks of flows of energy and materials. This implies that thermodynamics, the physical theory of energy and materials flows, must have implications for economics. On another level, thermodynamics has been recognized as a physical theory of value, with value concepts similar to those of economic theory. This paper discusses some general aspects of the significance of non-equilibrium thermodynamics for economics. The role of exergy, probably the most important of the physical measures of value, is elucidated. Two examples of integration of thermodynamics with economic theory are reviewed. First, a simple model of a steady-state production system is sued to illustrate the effects of thermodynamic process constraints. Second, the framework of a simple macroeconomic growth model is used to illustrate how some thermodynamic limitations may be integrated in macroeconomic theory
Precise Thermometry for Next Generation LHC Superconducting Magnet Prototypes
Datskov, V; Bottura, L; Perez, J C; Borgnolutti, F; Jenninger, B; Ryan, P
2013-01-01
The next generation of LHC superconducting magnets is very challenging and must operate in harsh conditions: high radiation doses in a range between 10 and 50 MGy, high voltage environment of 1 to 5 kV during the quench, dynamic high magnetic field up to 12 T, dynamic temperature range 1.8 K to 300 K in 0.6 sec. For magnet performance and long term reliability it is important to study dynamic thermal effects, such as the heat flux through the magnet structure, or measuring hot spot in conductors during a magnet quench with high sampling rates above 200 Hz. Available on the market cryogenic temperature sensors comparison is given. An analytical model for special electrically insulating thermal anchor (Kapton pad) with high voltage insulation is described. A set of instrumentation is proposed for fast monitoring of thermal processes during normal operation, quenches and failure situations. This paper presents the technology applicable for mounting temperature sensors on high voltage superconducting (SC) cables....
Directory of Open Access Journals (Sweden)
C. Tomaz
2003-07-01
Full Text Available Recent studies have employed tympanic thermometry to assess lateralization of cognitive and emotional functions in primates. However, no studies using this technique have investigated the possibility of hemispheric specialization in New World monkeys. Therefore, the aim of the present study was to investigate tympanic membrane (TM temperature asymmetries and their possible correlation with stress responses in marmosets (Callithrix penicillata. Infrared TM thermometry was completed bilaterally in 24 animals (14 males and 10 females during a stressful situation of capture and restraint. There were no significant differences between gender. A significant negative correlation was observed between TM temperature of the right ear and the number of captures (r = -0.633; P<0.001. Subjects with a more frequent previous history of captures (5 to 9 captures; N = 11 showed lower TM temperature when compared to those with fewer previous captures (1 to 4 captures; N = 13. No differences were observed for the left TM temperature. These results suggest that under intense emotional challenge (capture and restraint there is a stronger activation of the neural structures situated in the right brain hemisphere. Taken together, the data reveal for the first time evidence of hemispheric specialization in emotional physiological processing in a New World monkey.
Practical acoustic thermometry with twin-tube and single-tube sensors
Energy Technology Data Exchange (ETDEWEB)
De Podesta, M.; Sutton, G.; Edwards, G.; Stanger, L.; Preece, H. [National Physical Laboratory, Teddington, (United Kingdom)
2015-07-01
Accurate measurement of high temperatures in a nuclear environment presents unique challenges. All secondary techniques inevitably drift because the thermometric materials in thermocouples and resistance sensors are sensitive not just to temperature, but also their own chemical and physical composition. The solution is to use primary methods that rely on fundamental links between measurable physical properties and temperature. In the nuclear field the best known technique is the measurement of Johnson Noise in a resistor (See Paper 80 at this conference). In this paper we describe the measurement of temperature in terms of the speed of sound in a gas confined in a tube - an acoustic waveguide. Acoustic thermometry is the most accurate technique of primary thermometry ever devised with the best uncertainty of measurement below 0.001 C. In contrast, the acoustic technique described in this work has a much larger uncertainty, approximately 1 deg. C. But the cost and ease of use are improved by several orders of magnitude, making implementation eminently practical. We first describe the basic construction and method of operation of thermometers using twin-tubes and single tubes. We then present results using a twin-tube design showing that showing long term stability (i.e. no detectable drift) at 700 deg. C over periods of several weeks. We then outline how the technique may be developed for different nuclear applications. (authors)
Energy Technology Data Exchange (ETDEWEB)
Streitparth, Florian; Walter, Thula; Bucourt, Maximilian de; Freyhardt, Patrick; Maurer, Martin; Renz, Diane; Gebauer, Bernhard; Hamm, Bernd; Teichgraeber, Ulf K.M. [Charite, Humboldt-University Medical School, Department of Radiology, Berlin (Germany); Hartwig, Tony; Putzier, Michael; Strube, Patrick [Charite, Humboldt-University, Center for Musculoskeletal Surgery, Berlin (Germany); Bretschneider, Tina [University of Magdeburg, Department of Radiology, Magdeburg (Germany)
2013-10-15
To assess the feasibility, safety and efficacy of real-time MR guidance and thermometry of percutaneous laser disc decompression (PLDD). Twenty-four discs in 22 patients with chronic low-back and radicular pain were treated by PLDD using open 1.0-T magnetic-resonance imaging (MRI). A fluoroscopic proton-density-weighted turbo spin-echo (PDw TSE) sequence was used to position the laser fibre. Non-spoiled gradient-echo (GRE) sequences were employed for real-time thermal monitoring based on proton resonance frequency (PRF). Radicular pain was assessed over 6 months with a numerical rating scale (NRS). PLDD was technically successful in all cases, with adequate image quality for laser positioning. The PRF-based real-time temperature monitoring was found to be feasible in practice. After 6 months, 21 % reported complete remission of radicular pain, 63 % at least great pain relief and 74 % at least mild relief. We found a significant decrease in the NRS score between the pre-intervention and the 6-month follow-up assessment (P < 0.001). No major complications occurred; the single adverse event recorded, moderate motor impairment, resolved. Real-time MR guidance and PRF-based thermometry of PLDD in the lumbar spine under open 1.0-T MRI appears feasible, safe and effective and may pave the way to more precise operating procedures. (orig.)
International Nuclear Information System (INIS)
Streitparth, Florian; Walter, Thula; Bucourt, Maximilian de; Freyhardt, Patrick; Maurer, Martin; Renz, Diane; Gebauer, Bernhard; Hamm, Bernd; Teichgraeber, Ulf K.M.; Hartwig, Tony; Putzier, Michael; Strube, Patrick; Bretschneider, Tina
2013-01-01
To assess the feasibility, safety and efficacy of real-time MR guidance and thermometry of percutaneous laser disc decompression (PLDD). Twenty-four discs in 22 patients with chronic low-back and radicular pain were treated by PLDD using open 1.0-T magnetic-resonance imaging (MRI). A fluoroscopic proton-density-weighted turbo spin-echo (PDw TSE) sequence was used to position the laser fibre. Non-spoiled gradient-echo (GRE) sequences were employed for real-time thermal monitoring based on proton resonance frequency (PRF). Radicular pain was assessed over 6 months with a numerical rating scale (NRS). PLDD was technically successful in all cases, with adequate image quality for laser positioning. The PRF-based real-time temperature monitoring was found to be feasible in practice. After 6 months, 21 % reported complete remission of radicular pain, 63 % at least great pain relief and 74 % at least mild relief. We found a significant decrease in the NRS score between the pre-intervention and the 6-month follow-up assessment (P < 0.001). No major complications occurred; the single adverse event recorded, moderate motor impairment, resolved. Real-time MR guidance and PRF-based thermometry of PLDD in the lumbar spine under open 1.0-T MRI appears feasible, safe and effective and may pave the way to more precise operating procedures. (orig.)
Advanced thermodynamics engineering
Annamalai, Kalyan; Jog, Milind A
2011-01-01
Thermolab Excel-Based Software for Thermodynamic Properties and Flame Temperatures of Fuels IntroductionImportance, Significance and LimitationsReview of ThermodynamicsMathematical BackgroundOverview of Microscopic/NanothermodynamicsSummaryAppendix: Stokes and Gauss Theorems First Law of ThermodynamicsZeroth LawFirst Law for a Closed SystemQuasi Equilibrium (QE) and Nonquasi-equilibrium (NQE) ProcessesEnthalpy and First LawAdiabatic Reversible Process for Ideal Gas with Constant Specific HeatsFirst Law for an Open SystemApplications of First Law for an Open SystemIntegral and Differential Form
REA, The Editors of
2012-01-01
REA's Essentials provide quick and easy access to critical information in a variety of different fields, ranging from the most basic to the most advanced. As its name implies, these concise, comprehensive study guides summarize the essentials of the field covered. Essentials are helpful when preparing for exams, doing homework and will remain a lasting reference source for students, teachers, and professionals. Thermodynamics I includes review of properties and states of a pure substance, work and heat, energy and the first law of thermodynamics, entropy and the second law of thermodynamics
Non-equilibrium thermodynamics
De Groot, Sybren Ruurds
1984-01-01
The study of thermodynamics is especially timely today, as its concepts are being applied to problems in biology, biochemistry, electrochemistry, and engineering. This book treats irreversible processes and phenomena - non-equilibrium thermodynamics.S. R. de Groot and P. Mazur, Professors of Theoretical Physics, present a comprehensive and insightful survey of the foundations of the field, providing the only complete discussion of the fluctuating linear theory of irreversible thermodynamics. The application covers a wide range of topics: the theory of diffusion and heat conduction, fluid dyn
Thermodynamics of quantum strings
Morgan, M J
1994-01-01
A statistical mechanical analysis of an ideal gas of non-relativistic quantum strings is presented, in which the thermodynamic properties of the string gas are calculated from a canonical partition function. This toy model enables students to gain insight into the thermodynamics of a simple 'quantum field' theory, and provides a useful pedagogical introduction to the more complicated relativistic string theories. A review is also given of the thermodynamics of the open bosonic string gas and the type I (open) superstring gas. (author)
Modern engineering thermodynamics
Balmer, Robert T
2010-01-01
Designed for use in a standard two-semester engineering thermodynamics course sequence. The first half of the text contains material suitable for a basic Thermodynamics course taken by engineers from all majors. The second half of the text is suitable for an Applied Thermodynamics course in mechanical engineering programs. The text has numerous features that are unique among engineering textbooks, including historical vignettes, critical thinking boxes, and case studies. All are designed to bring real engineering applications into a subject that can be somewhat abstract and mathematica
International Nuclear Information System (INIS)
Pujol Mora, J.
1999-01-01
The exposition to ionizing radiations is a constant fact in the life of the human being and its utilization as diagnostic and therapeutic method is generalized. However, it is notorious how as years go on, the fear to the ionizing radiation seems to persist too, and this fact is not limited to the common individual, but to the technical personnel and professional personnel that labors with them same. (S. Grainger) [es
International Nuclear Information System (INIS)
Davidson, J.H.
1986-01-01
The basic facts about radiation are explained, along with some simple and natural ways of combating its ill-effects, based on ancient healing wisdom as well as the latest biochemical and technological research. Details are also given of the diet that saved thousands of lives in Nagasaki after the Atomic bomb attack. Special comment is made on the use of radiation for food processing. (U.K.)
Theoretical physics 5 thermodynamics
Nolting, Wolfgang
2017-01-01
This concise textbook offers a clear and comprehensive introduction to thermodynamics, one of the core components of undergraduate physics courses. It follows on naturally from the previous volumes in this series, defining macroscopic variables, such as internal energy, entropy and pressure,together with thermodynamic principles. The first part of the book introduces the laws of thermodynamics and thermodynamic potentials. More complex themes are covered in the second part of the book, which describes phases and phase transitions in depth. Ideally suited to undergraduate students with some grounding in classical mechanics, the book is enhanced throughout with learning features such as boxed inserts and chapter summaries, with key mathematical derivations highlighted to aid understanding. The text is supported by numerous worked examples and end of chapter problem sets. About the Theoretical Physics series Translated from the renowned and highly successful German editions, the eight volumes of this series cove...
Elements of chemical thermodynamics
Nash, Leonard K
2005-01-01
This survey of purely thermal data in calculating the position of equilibrium in a chemical reaction highlights the physical content of thermodynamics, as distinct from purely mathematical aspects. 1970 edition.
Elements of statistical thermodynamics
Nash, Leonard K
2006-01-01
Encompassing essentially all aspects of statistical mechanics that appear in undergraduate texts, this concise, elementary treatment shows how an atomic-molecular perspective yields new insights into macroscopic thermodynamics. 1974 edition.
Electrochemical thermodynamic measurement system
Reynier, Yvan [Meylan, FR; Yazami, Rachid [Los Angeles, CA; Fultz, Brent T [Pasadena, CA
2009-09-29
The present invention provides systems and methods for accurately characterizing thermodynamic and materials properties of electrodes and electrochemical energy storage and conversion systems. Systems and methods of the present invention are configured for simultaneously collecting a suite of measurements characterizing a plurality of interconnected electrochemical and thermodynamic parameters relating to the electrode reaction state of advancement, voltage and temperature. Enhanced sensitivity provided by the present methods and systems combined with measurement conditions that reflect thermodynamically stabilized electrode conditions allow very accurate measurement of thermodynamic parameters, including state functions such as the Gibbs free energy, enthalpy and entropy of electrode/electrochemical cell reactions, that enable prediction of important performance attributes of electrode materials and electrochemical systems, such as the energy, power density, current rate and the cycle life of an electrochemical cell.
Workshop on Teaching Thermodynamics
1985-01-01
It seemed appropriate to arrange a meeting of teachers of thermodynamics in the United Kingdom, a meeting held in the pleasant surroundings of Emmanuel College, Cambridge, in Sept~mber, 1984. This volume records the ideas put forward by authors, the discussion generated and an account of the action that discussion has initiated. Emphasis was placed on the Teaching of Thermodynamics to degree-level students in their first and second years. The meeting, a workshop for practitioners in which all were expected to take part, was remarkably well supported. This was notable in the representation of essentially every UK university and polytechnic engaged in teaching engineering thermodynamics and has led to a stimulating spread of ideas. By intention, the emphasis for attendance was put on teachers of engineering concerned with thermodynamics, both mechanical and chemical engineering disciplines. Attendance from others was encouraged but limited as follows: non-engineering acad emics, 10%, industrialists, 10%. The ...
International Nuclear Information System (INIS)
Bekenstein, J.D.
1980-01-01
Including black holes in the scheme of thermodynamics has disclosed a deep-seated connection between gravitation, heat and the quantum that may lead us to a synthesis of the corresponding branches of physics
Polyelectrolytes thermodynamics and rheology
P M, Visakh; Picó, Guillermo Alfredo
2014-01-01
This book discusses current development of theoretical models and experimental findings on the thermodynamics of polyelectrolytes. Particular emphasis is placed on the rheological description of polyelectrolyte solutions and hydrogels.
International Nuclear Information System (INIS)
Winther, J.F.; Ulbak, K.; Dreyer, L.; Pukkala, E.; Oesterlind, A.
1997-01-01
Exposure to solar and ionizing radiation increases the risk for cancer in humans. Some 5% of solar radiation is within the ultraviolet spectrum and may cause both malignant melanoma and non-melanocytic skin cancer; the latter is regarded as a benign disease and is accordingly not included in our estimation of avoidable cancers. Under the assumption that the rate of occurrence of malignant melanoma of the buttocks of both men and women and of the scalp of women would apply to all parts of the body in people completely unexposed to solar radiation, it was estimated that approximately 95% of all malignant melanomas arising in the Nordic populations around the year 2000 will be due to exposure to natural ultraviolet radiation, equivalent to an annual number of about 4700 cases, with 2100 in men and 2600 in women, or some 4% of all cancers notified. Exposure to ionizing radiation in the Nordic countries occurs at an average effective dose per capita per year of about 3 mSv (Iceland, 1.1 mSv) from natural sources, and about 1 mSv from man-made sources. While the natural sources are primarily radon in indoor air, natural radionuclides in food, cosmic radiation and gamma radiation from soil and building materials, the man-made sources are dominated by the diagnostic and therapeutic use of ionizing radiation. On the basis of measured levels of radon in Nordic dwellings and associated risk estimates for lung cancer derived from well-conducted epidemiological studies, we estimated that about 180 cases of lung cancer (1% of all lung cancer cases) per year could be avoided in the Nordic countries around the year 2000 if indoor exposure to radon were eliminated, and that an additional 720 cases (6%) could be avoided annually if either radon or tobacco smoking were eliminated. Similarly, it was estimated that the exposure of the Nordic populations to natural sources of ionizing radiation other than radon and to medical sources will each give rise to an annual total of 2120
A New Perspective on Thermodynamics
Lavenda, Bernard H
2010-01-01
Dr. Bernard H. Lavenda has written A New Perspective on Thermodynamics to combine an old look at thermodynamics with a new foundation. The book presents a historical perspective, which unravels the current presentation of thermodynamics found in standard texts, and which emphasizes the fundamental role that Carnot played in the development of thermodynamics. A New Perspective on Thermodynamics will: Chronologically unravel the development of the principles of thermodynamics and how they were conceived by their discoverers Bring the theory of thermodynamics up to the present time and indicate areas of further development with the union of information theory and the theory of means and their inequalities. New areas include nonextensive thermodynamics, the thermodynamics of coding theory, multifractals, and strange attractors. Reintroduce important, yet nearly forgotten, teachings of N.L. Sardi Carnot Highlight conceptual flaws in timely topics such as endoreversible engines, finite-time thermodynamics, geometri...
Gravity as a thermodynamic phenomenon
Moustos, Dimitris
2017-01-01
The analogy between the laws of black hole mechanics and the laws of thermodynamics led Bekenstein and Hawking to argue that black holes should be considered as real thermodynamic systems that are characterised by entropy and temperature. Black hole thermodynamics indicates a deeper connection between thermodynamics and gravity. We review and examine in detail the arguments that suggest an interpretation of gravity itself as a thermodynamic theory.
Ruppeiner theory of black hole thermodynamics
International Nuclear Information System (INIS)
Aman, Jan E; Bedford, James; Grumiller, Daniel; Pidokrajt, Narit; Ward, John
2007-01-01
The Ruppeiner metric as determined by the Hessian of the Gibbs surface provides a geometric description of thermodynamic systems in equilibrium. An interesting example is a black hole in equilibrium with its own Hawking radiation. In this article, we present results from the Ruppeiner study of various black hole families from different gravity theories e.g. 2D dilaton gravity, BTZ, general relativity and higher-dimensional Einstein-Maxwell gravity
Thermodynamics of nuclear materials
International Nuclear Information System (INIS)
1962-01-01
The first session of the symposium discussed in general the thermodynamic properties of actinides, including thorium, uranium and Plutonium which provide reactor fuel. The second session was devoted to applications of thermodynamic theory to the study of nuclear materials, while the experimental techniques for the determination of thermodynamic data were examined at the next session. The thermodynamic properties of alloys were considered at a separate session, and another session was concerned with solids other than alloys. Vaporization processes, which are of special interest in the development of high-temperature reactors, were discussed at a separate session. The discussions on the methods of developing the data and ascertaining their accuracy were especially useful in highlighting the importance of determining whether any given data are reliable before they can be put to practical application. Many alloys and refractory materials (i. e. materials which evaporate only at very high temperatures) are of great importance in nuclear technology, and some of these substances are extremely complex in their chemical composition. For example, until recently the phase composition of the oxides of thorium, uranium and plutonium had been only very imperfectly understood, and the same was true of the carbides of these elements. Recent developments in experimental techniques have made it possible to investigate the phase composition of these complex materials as well as the chemical species of these materials in the gaseous phase. Recent developments in measuring techniques, such as fluorine bomb calorimetry and Knudsen effusion technique, have greatly increased the accuracy of thermodynamic data
Real-time control of focused ultrasound heating based on rapid MR thermometry.
Vimeux, F C; De Zwart, J A; Palussiére, J; Fawaz, R; Delalande, C; Canioni, P; Grenier, N; Moonen, C T
1999-03-01
Real-time control of the heating procedure is essential for hyperthermia applications of focused ultrasound (FUS). The objective of this study is to demonstrate the feasibility of MRI-controlled FUS. An automatic control system was developed using a dedicated interface between the MR system control computer and the FUS wave generator. Two algorithms were used to regulate FUS power to maintain the focal point temperature at a desired level. Automatic control of FUS power level was demonstrated ex vivo at three target temperature levels (increase of 5 degrees C, 10 degrees C, and 30 degrees C above room temperature) during 30-minute hyperthermic periods. Preliminary in vivo results on rat leg muscle confirm that necrosis estimate, calculated on-line during FUS sonication, allows prediction of tissue damage. CONCLUSIONS. The feasibility of fully automatic FUS control based on MRI thermometry has been demonstrated.
A high-resolution mK-calorimeter applying SQUID-thermometry
Energy Technology Data Exchange (ETDEWEB)
Reifenberger, Andreas; Leps, Norman; Fleischmann, Andreas; Pies, Christian; Enss, Christian; Klingeler, Ruediger [Kirchhoff-Institut fuer Physik, Universitaet Heidelberg, INF 227,69120 Heidelberg (Germany)
2012-07-01
A new calorimeter for measuring single-crystalline samples of mg-size at ultra-low temperatures is described. Thermometry is done by means of a paramagnetic sensor material (Er-doped Au) in a low magnetic field. A temperature change results in a magnetization change which can be read out as change in magnetic flux by a superconducting quantum interference device (SQUID). This enables measurements in a wide temperature range (theoretically from 1 mK-1 K) with very high sensitivities. The bolometric design exhibits low addenda heat capacity and allows measurements of heat capacities from nJ/K to {mu}J/K by means of a temperature-relaxation method. The performance of the device is compared to a commercially available Quantum Design calorimeter in elsewise unchanged experimental settings in the temperature range from 15 mK to 500 mK.
NMR imaging of cell phone radiation absorption in brain tissue
Gultekin, David H.; Moeller, Lothar
2013-01-01
A method is described for measuring absorbed electromagnetic energy radiated from cell phone antennae into ex vivo brain tissue. NMR images the 3D thermal dynamics inside ex vivo bovine brain tissue and equivalent gel under exposure to power and irradiation time-varying radio frequency (RF) fields. The absorbed RF energy in brain tissue converts into Joule heat and affects the nuclear magnetic shielding and the Larmor precession. The resultant temperature increase is measured by the resonance frequency shift of hydrogen protons in brain tissue. This proposed application of NMR thermometry offers sufficient spatial and temporal resolution to characterize the hot spots from absorbed cell phone radiation in aqueous media and biological tissues. Specific absorption rate measurements averaged over 1 mg and 10 s in the brain tissue cover the total absorption volume. Reference measurements with fiber optic temperature sensors confirm the accuracy of the NMR thermometry. PMID:23248293
DEFF Research Database (Denmark)
Westerhoff, Hans V.; Jensen, Peter Ruhdal; Snoep, Jacky L.
1998-01-01
-called emergent properties. Tendency towards increased entropy is an essential determinant for the behaviour of ideal gas mixtures, showing that even in the simplest physical/chemical systems, (dys)organisation of components is crucial for the behaviour of systems. This presentation aims at illustrating...... that the behaviour of two functionally interacting biological components (molecules, protein domains, pathways, organelles) differs from the behaviour these components would exhibit in isolation from one another, where the difference should be essential for the maintenance and growth of the living state, For a true...... understanding of this BioComplexity, modem thermodynamic concepts and methods (nonequilibrium thermodynamics, metabolic and hierarchical control analysis) will be needed. We shall propose to redefine nonequilibrium thermodynamics as: The science that aims at understanding the behaviour of nonequilibrium systems...
Extended Irreversible Thermodynamics
Jou, David
2010-01-01
This is the 4th edition of the highly acclaimed monograph on Extended Irreversible Thermodynamics, a theory that goes beyond the classical theory of irreversible processes. In contrast to the classical approach, the basic variables describing the system are complemented by non-equilibrium quantities. The claims made for extended thermodynamics are confirmed by the kinetic theory of gases and statistical mechanics. The book covers a wide spectrum of applications, and also contains a thorough discussion of the foundations and the scope of the current theories on non-equilibrium thermodynamics. For this new edition, the authors critically revised existing material while taking into account the most recent developments in fast moving fields such as heat transport in micro- and nanosystems or fast solidification fronts in materials sciences. Several fundamental chapters have been revisited emphasizing physics and applications over mathematical derivations. Also, fundamental questions on the definition of non-equil...
Statistical thermodynamics of alloys
Gokcen, N A
1986-01-01
This book is intended for scientists, researchers, and graduate students interested in solutions in general, and solutions of metals in particular. Readers are assumed to have a good background in thermodynamics, presented in such books as those cited at the end of Chapter 1, "Thermo dynamic Background." The contents of the book are limited to the solutions of metals + metals, and metals + metalloids, but the results are also appli cable to numerous other types of solutions encountered by metallurgists, materials scientists, geologists, ceramists, and chemists. Attempts have been made to cover each topic in depth with numerical examples whenever necessary. Chapter 2 presents phase equilibria and phase diagrams as related to the thermodynamics of solutions. The emphasis is on the binary diagrams since the ternary diagrams can be understood in terms of the binary diagrams coupled with the phase rule, and the Gibbs energies of mixing. The cal culation of thermodynamic properties from the phase diagrams is ...
Thermodynamics of Crystalline States
Fujimoto, Minoru
2010-01-01
Thermodynamics is a well-established discipline of physics for properties of matter in thermal equilibrium surroundings. Applying to crystals, however, the laws encounter undefined properties of crystal lattices, which therefore need to be determined for a clear and well-defined description of crystalline states. Thermodynamics of Crystalline States explores the roles played by order variables and dynamic lattices in crystals in a wholly new way. This book is divided into three parts. The book begins by clarifying basic concepts for stable crystals. Next, binary phase transitions are discussed to study collective motion of order variables, as described mostly as classical phenomena. In the third part, the multi-electron system is discussed theoretically, as a quantum-mechanical example, for the superconducting state in metallic crystals. Throughout the book, the role played by the lattice is emphasized and examined in-depth. Thermodynamics of Crystalline States is an introductory treatise and textbook on meso...
Concise chemical thermodynamics
Peters, APH
2010-01-01
EnergyThe Realm of ThermodynamicsEnergy BookkeepingNature's Driving ForcesSetting the Scene: Basic IdeasSystem and SurroundingsFunctions of StateMechanical Work and Expanding GasesThe Absolute Temperature Scale Forms of Energy and Their Interconversion Forms of Renewable Energy Solar Energy Wind Energy Hydroelectric Power Geothermal Energy Biomass Energy References ProblemsThe First Law of Thermodynamics Statement of the First Law Reversible Expansion of an Ideal GasConstant-Volume ProcessesConstant-Pressure ProcessesA New Function: EnthalpyRelationship between ?H and ?UUses and Conventions of
REA, The Editors of
2013-01-01
REA's Essentials provide quick and easy access to critical information in a variety of different fields, ranging from the most basic to the most advanced. As its name implies, these concise, comprehensive study guides summarize the essentials of the field covered. Essentials are helpful when preparing for exams, doing homework and will remain a lasting reference source for students, teachers, and professionals. Thermodynamics II includes review of thermodynamic relations, power and refrigeration cycles, mixtures and solutions, chemical reactions, chemical equilibrium, and flow through nozzl
Wong, Kaufui Vincent
2011-01-01
Praise for the First Edition from Students: "It is a great thermodynamics text…I loved it!-Mathew Walters "The book is comprehensive and easy to understand. I love the real world examples and problems, they make you feel like you are learning something very practical."-Craig Paxton"I would recommend the book to friends."-Faure J. Malo-Molina"The clear diction, as well as informative illustrations and diagrams, help convey the material clearly to the reader."-Paul C. Start"An inspiring and effective tool for any aspiring scientist or engineer. Definitely the best book on Classical Thermodynamics out."-Seth Marini.
Mechanics, Waves and Thermodynamics
Ranjan Jain, Sudhir
2016-05-01
Figures; Preface; Acknowledgement; 1. Energy, mass, momentum; 2. Kinematics, Newton's laws of motion; 3. Circular motion; 4. The principle of least action; 5. Work and energy; 6. Mechanics of a system of particles; 7. Friction; 8. Impulse and collisions; 9. Central forces; 10. Dimensional analysis; 11. Oscillations; 12. Waves; 13. Sound of music; 14. Fluid mechanics; 15. Water waves; 16. The kinetic theory of gases; 17. Concepts and laws of thermodynamics; 18. Some applications of thermodynamics; 19. Basic ideas of statistical mechanics; Bibliography; Index.
Statistical thermodynamics of alloys
International Nuclear Information System (INIS)
Gokcen, N.A.
1986-01-01
This book presents information on the following topics: consequences of laws of thermodynamics; Helmholtz and Gibbs energies; analytical forms of excess partial molar properties; single-component and multicomponent equilibria; phase rules and diagrams; lever rule; fermions, bosons, and Boltzons; approximate equations; enthalpy and heat capacity; Pd-H system; hydrogen-metal systems; limitations of Wagner model; energy of electrons and hols; dopants in semiconductors; derived thermodynamic properties; simple equivalent circuit; calculation procedure; multicompoent diagrams re; Engel-Brewer theories; p-n junctions; and solar cells
Radiation amorphization of materials
International Nuclear Information System (INIS)
Neklyudov, I.M.; Chernyaeva, T.P.
1993-01-01
The results of experimental and theoretical research on radiation amorphization are presented in this analytical review. Mechanism and driving forces of radiation amorphization are described, kinetic and thermodynamic conditions of amorphization are formulated. Compositional criteria of radiation amorphization are presented, that allow to predict irradiation behaviour of materials, their tendency to radiation amorphization. Mechanism of transition from crystalline state to amorphous state are considered depending on dose, temperature, structure of primary radiation damage and flux level. (author). 134 refs., 4 tab., 25 fig
Experimental thermodynamics experimental thermodynamics of non-reacting fluids
Neindre, B Le
2013-01-01
Experimental Thermodynamics, Volume II: Experimental Thermodynamics of Non-reacting Fluids focuses on experimental methods and procedures in the study of thermophysical properties of fluids. The selection first offers information on methods used in measuring thermodynamic properties and tests, including physical quantities and symbols for physical quantities, thermodynamic definitions, and definition of activities and related quantities. The text also describes reference materials for thermometric fixed points, temperature measurement under pressures, and pressure measurements. The publicatio
Black Hole Thermodynamics in an Undergraduate Thermodynamics Course.
Parker, Barry R.; McLeod, Robert J.
1980-01-01
An analogy, which has been drawn between black hole physics and thermodynamics, is mathematically broadened in this article. Equations similar to the standard partial differential relations of thermodynamics are found for black holes. The results can be used to supplement an undergraduate thermodynamics course. (Author/SK)
Correct thermodynamic forces in Tsallis thermodynamics: connection with Hill nanothermodynamics
International Nuclear Information System (INIS)
Garcia-Morales, Vladimir; Cervera, Javier; Pellicer, Julio
2005-01-01
The equivalence between Tsallis thermodynamics and Hill's nanothermodynamics is established. The correct thermodynamic forces in Tsallis thermodynamics are pointed out. Through this connection we also find a general expression for the entropic index q which we illustrate with two physical examples, allowing in both cases to relate q to the underlying dynamics of the Hamiltonian systems
Fluctuating Thermodynamics for Biological Processes
Ham, Sihyun
Because biomolecular processes are largely under thermodynamic control, dynamic extension of thermodynamics is necessary to uncover the mechanisms and driving factors of fluctuating processes. The fluctuating thermodynamics technology presented in this talk offers a practical means for the thermodynamic characterization of conformational dynamics in biomolecules. The use of fluctuating thermodynamics has the potential to provide a comprehensive picture of fluctuating phenomena in diverse biological processes. Through the application of fluctuating thermodynamics, we provide a thermodynamic perspective on the misfolding and aggregation of the various proteins associated with human diseases. In this talk, I will present the detailed concepts and applications of the fluctuating thermodynamics technology for elucidating biological processes. This work was supported by Samsung Science and Technology Foundation under Project Number SSTF-BA1401-13.
A Hamiltonian approach to Thermodynamics
Energy Technology Data Exchange (ETDEWEB)
Baldiotti, M.C., E-mail: baldiotti@uel.br [Departamento de Física, Universidade Estadual de Londrina, 86051-990, Londrina-PR (Brazil); Fresneda, R., E-mail: rodrigo.fresneda@ufabc.edu.br [Universidade Federal do ABC, Av. dos Estados 5001, 09210-580, Santo André-SP (Brazil); Molina, C., E-mail: cmolina@usp.br [Escola de Artes, Ciências e Humanidades, Universidade de São Paulo, Av. Arlindo Bettio 1000, CEP 03828-000, São Paulo-SP (Brazil)
2016-10-15
In the present work we develop a strictly Hamiltonian approach to Thermodynamics. A thermodynamic description based on symplectic geometry is introduced, where all thermodynamic processes can be described within the framework of Analytic Mechanics. Our proposal is constructed on top of a usual symplectic manifold, where phase space is even dimensional and one has well-defined Poisson brackets. The main idea is the introduction of an extended phase space where thermodynamic equations of state are realized as constraints. We are then able to apply the canonical transformation toolkit to thermodynamic problems. Throughout this development, Dirac’s theory of constrained systems is extensively used. To illustrate the formalism, we consider paradigmatic examples, namely, the ideal, van der Waals and Clausius gases. - Highlights: • A strictly Hamiltonian approach to Thermodynamics is proposed. • Dirac’s theory of constrained systems is extensively used. • Thermodynamic equations of state are realized as constraints. • Thermodynamic potentials are related by canonical transformations.
A Hamiltonian approach to Thermodynamics
International Nuclear Information System (INIS)
Baldiotti, M.C.; Fresneda, R.; Molina, C.
2016-01-01
In the present work we develop a strictly Hamiltonian approach to Thermodynamics. A thermodynamic description based on symplectic geometry is introduced, where all thermodynamic processes can be described within the framework of Analytic Mechanics. Our proposal is constructed on top of a usual symplectic manifold, where phase space is even dimensional and one has well-defined Poisson brackets. The main idea is the introduction of an extended phase space where thermodynamic equations of state are realized as constraints. We are then able to apply the canonical transformation toolkit to thermodynamic problems. Throughout this development, Dirac’s theory of constrained systems is extensively used. To illustrate the formalism, we consider paradigmatic examples, namely, the ideal, van der Waals and Clausius gases. - Highlights: • A strictly Hamiltonian approach to Thermodynamics is proposed. • Dirac’s theory of constrained systems is extensively used. • Thermodynamic equations of state are realized as constraints. • Thermodynamic potentials are related by canonical transformations.
New perspectives in thermodynamics
International Nuclear Information System (INIS)
Serrin, J.
1986-01-01
The last decade has seen a unity of method and approach in the foundations of thermodynamics and continuum mechanics, in which rigorous laws of thermodynamics have been combined with invariance notions of mechanics to produce new and deep understanding. Real progress has been made in finding a set of appropriate concepts for classical thermodynamics, by which energy conservation and the Clausius inequality can be given well-defined meanings for arbitrary processes and which allow an approach to the entropy concept which is free of traditional ambiguities. There has been, moreover, a careful scrutiny of long established but nevertheless not sharply defined concepts such as the Maxwell equal-area rule, the famous Gibbs phase rule, and the equivalence of work and heat. The thirteen papers in this volume accordingly gather together for the first time the many ideas and concepts which have raised classical thermodynamics from a heuristic and intuitive science to the level of precision presently demanded of other branches of mathematical physics
Thermodynamics and statistical mechanics
Landsberg, Peter T
1990-01-01
Exceptionally articulate treatment combines precise mathematical style with strong physical intuition. Wide range of applications includes negative temperatures, negative heat capacities, special and general relativistic effects, black hole thermodynamics, gravitational collapse, more. Over 100 problems with worked solutions. Advanced undergraduate, graduate level. Table of applications. Useful formulas and other data.
Thermodynamic stabilization of colloids
Stol, R.J.; Bruyn, P.L. de
An analysis is given of the conditions necessary for obtaining a thermodynamically stable dispersion (TSD) of solid particles in a continuous aqueous solution phase. The role of the adsorption of potential-determining ions at the planar interface in lowering the interfacial free energy (γ) to
Chemical thermodynamics. An introduction
Energy Technology Data Exchange (ETDEWEB)
Keszei, Ernoe [Budapest Univ. (Hungary). Dept. of Physical Chemistry
2012-07-01
Eminently suitable as a required textbook comprising complete material for or an undergraduate chemistry major course in chemical thermodynamics. Clearly explains details of formal derivations that students can easily follow and so master applied mathematical operations. Offers problems and solutions at the end of each chapter for self-test and self- or group study. This course-derived undergraduate textbook provides a concise explanation of the key concepts and calculations of chemical thermodynamics. Instead of the usual 'classical' introduction, this text adopts a straightforward postulatory approach that introduces thermodynamic potentials such as entropy and energy more directly and transparently. Structured around several features to assist students' understanding, Chemical Thermodynamics: - Develops applications and methods for the ready treatment of equilibria on a sound quantitative basis. - Requires minimal background in calculus to understand the text and presents formal derivations to the student in a detailed but understandable way. - Offers end-of-chapter problems (and answers) for self-testing and review and reinforcement, of use for self- or group study. This book is suitable as essential reading for courses in a bachelor and master chemistry program and is also valuable as a reference or textbook for students of physics, biochemistry and materials science.
Thermodynamics applied. Where? Why?
Hirs, Gerard
2003-01-01
In recent years, thermodynamics has been applied in a number of new fields leading to a greater societal impact. This paper gives a survey of these new fields and the reasons why these applications are important. In addition, it is shown that the number of fields could be even greater in the future
Thermodynamics, applied. : Where? why?
Hirs, Gerard
1999-01-01
In recent years thermodynamics has been applied in a number of new fields leading to a greater societal impact. The paper gives a survey of these new fields and the reasons why these applications are important. In addition it is shown that the number of fields could be even greater in the future and
Nonequilibrium thermodynamics of nucleation
Schweizer, M.; Sagis, L.M.C.
2014-01-01
We present a novel approach to nucleation processes based on the GENERIC framework (general equation for the nonequilibrium reversible-irreversible coupling). Solely based on the GENERIC structure of time-evolution equations and thermodynamic consistency arguments of exchange processes between a
Debbasch, F.
2011-01-01
The logical structure of classical thermodynamics is presented in a modern, geometrical manner. The first and second law receive clear, operatively oriented statements and the Gibbs free energy extremum principle is fully discussed. Applications relevant to chemistry, such as phase transitions, dilute solutions theory and, in particular, the law…
Black hole thermodynamical entropy
International Nuclear Information System (INIS)
Tsallis, Constantino; Cirto, Leonardo J.L.
2013-01-01
As early as 1902, Gibbs pointed out that systems whose partition function diverges, e.g. gravitation, lie outside the validity of the Boltzmann-Gibbs (BG) theory. Consistently, since the pioneering Bekenstein-Hawking results, physically meaningful evidence (e.g., the holographic principle) has accumulated that the BG entropy S BG of a (3+1) black hole is proportional to its area L 2 (L being a characteristic linear length), and not to its volume L 3 . Similarly it exists the area law, so named because, for a wide class of strongly quantum-entangled d-dimensional systems, S BG is proportional to lnL if d=1, and to L d-1 if d>1, instead of being proportional to L d (d ≥ 1). These results violate the extensivity of the thermodynamical entropy of a d-dimensional system. This thermodynamical inconsistency disappears if we realize that the thermodynamical entropy of such nonstandard systems is not to be identified with the BG additive entropy but with appropriately generalized nonadditive entropies. Indeed, the celebrated usefulness of the BG entropy is founded on hypothesis such as relatively weak probabilistic correlations (and their connections to ergodicity, which by no means can be assumed as a general rule of nature). Here we introduce a generalized entropy which, for the Schwarzschild black hole and the area law, can solve the thermodynamic puzzle. (orig.)
Thermodynamics Far from the Thermodynamic Limit.
de Miguel, Rodrigo; Rubí, J Miguel
2017-11-16
Understanding how small systems exchange energy with a heat bath is important to describe how their unique properties can be affected by the environment. In this contribution, we apply Landsberg's theory of temperature-dependent energy levels to describe the progressive thermalization of small systems as their spectrum is perturbed by a heat bath. We propose a mechanism whereby the small system undergoes a discrete series of excitations and isentropic spectrum adjustments leading to a final state of thermal equilibrium. This produces standard thermodynamic results without invoking system size. The thermal relaxation of a single harmonic oscillator is analyzed as a model example of a system with a quantized spectrum than can be embedded in a thermal environment. A description of how the thermal environment affects the spectrum of a small system can be the first step in using environmental factors, such as temperature, as parameters in the design and operation of nanosystem properties.
Thermodynamics for the practicing engineer
Theodore, Louis; Vanvliet, Timothy
2009-01-01
This book concentrates specifically on the applications of thermodynamics, rather than the theory. It addresses both technical and pragmatic problems in the field, and covers such topics as enthalpy effects, equilibrium thermodynamics, non-ideal thermodynamics and energy conversion applications. Providing the reader with a working knowledge of the principles of thermodynamics, as well as experience in their application, it stands alone as an easy-to-follow self-teaching aid to practical applications and contains worked examples.
Low-temperature thermometry. Use of a gas thermometer as a calibration standard between 4 and 300 K
International Nuclear Information System (INIS)
Combarieu, A. de
1978-01-01
A constant volume gas thermometer was built to calibrate the various secondary thermometers used at low temperature. This gas thermometer is placed in a cryostat where any stable temperature between 4 and 300 K may be obtained. After some words about low temperature thermometry, the gas thermometer and its auxiliary equipment are described briefly; the corrections to be applied to the results are given and the article ends with a table showing the values obtained [fr
Choice of the thermodynamic variables
International Nuclear Information System (INIS)
Balian, R.
1985-09-01
Some basic ideas of thermodynamics and statistical mechanics, both at equilibrium and off equilibrium, are recalled. In particular, the selection of relevant variables which underlies any macroscopic description is discussed, together with the meaning of the various thermodynamic quantities, in order to set the thermodynamic approaches used in nuclear physics in a general prospect [fr
Contact symmetries and Hamiltonian thermodynamics
International Nuclear Information System (INIS)
Bravetti, A.; Lopez-Monsalvo, C.S.; Nettel, F.
2015-01-01
It has been shown that contact geometry is the proper framework underlying classical thermodynamics and that thermodynamic fluctuations are captured by an additional metric structure related to Fisher’s Information Matrix. In this work we analyse several unaddressed aspects about the application of contact and metric geometry to thermodynamics. We consider here the Thermodynamic Phase Space and start by investigating the role of gauge transformations and Legendre symmetries for metric contact manifolds and their significance in thermodynamics. Then we present a novel mathematical characterization of first order phase transitions as equilibrium processes on the Thermodynamic Phase Space for which the Legendre symmetry is broken. Moreover, we use contact Hamiltonian dynamics to represent thermodynamic processes in a way that resembles the classical Hamiltonian formulation of conservative mechanics and we show that the relevant Hamiltonian coincides with the irreversible entropy production along thermodynamic processes. Therefore, we use such property to give a geometric definition of thermodynamically admissible fluctuations according to the Second Law of thermodynamics. Finally, we show that the length of a curve describing a thermodynamic process measures its entropy production
Statistical Thermodynamics and Microscale Thermophysics
Carey, Van P.
1999-08-01
Many exciting new developments in microscale engineering are based on the application of traditional principles of statistical thermodynamics. In this text Van Carey offers a modern view of thermodynamics, interweaving classical and statistical thermodynamic principles and applying them to current engineering systems. He begins with coverage of microscale energy storage mechanisms from a quantum mechanics perspective and then develops the fundamental elements of classical and statistical thermodynamics. Subsequent chapters discuss applications of equilibrium statistical thermodynamics to solid, liquid, and gas phase systems. The remainder of the book is devoted to nonequilibrium thermodynamics of transport phenomena and to nonequilibrium effects and noncontinuum behavior at the microscale. Although the text emphasizes mathematical development, Carey includes many examples and exercises to illustrate how the theoretical concepts are applied to systems of scientific and engineering interest. In the process he offers a fresh view of statistical thermodynamics for advanced undergraduate and graduate students, as well as practitioners, in mechanical, chemical, and materials engineering.
International Nuclear Information System (INIS)
Bernhoeft, N.; Lander, G.H.; Colineau, E.
2003-01-01
An asymmetric shift in the position of the magnetic Bragg peak with respect to the fiducial lattice has been observed by resonant X-ray scattering in a diverse series of antiferromagnetic compounds. This apparent violation of Bragg's law is interpreted in terms of a dynamically phased order parameter. We demonstrate the use of this effect as a novel probe of fragile or dynamic thermodynamic order in strongly correlated electronic systems. In particular, fresh light is shed on the paradoxical situation encountered in URu 2 Si 2 where the measured entropy gain on passing through T Neel is incompatible with the ground state moment estimated by neutron diffraction. The intrinsic space-time averaging of the probe used to characterise the thermodynamic macroscopic state may play a crucial and previously neglected role. In turn, this suggests the further use of resonant X-ray scattering in investigations of systems dominated by quantum fluctuations. (author)
Demtröder, Wolfgang
2017-01-01
This introduction to classical mechanics and thermodynamics provides an accessible and clear treatment of the fundamentals. Starting with particle mechanics and an early introduction to special relativity this textbooks enables the reader to understand the basics in mechanics. The text is written from the experimental physics point of view, giving numerous real life examples and applications of classical mechanics in technology. This highly motivating presentation deepens the knowledge in a very accessible way. The second part of the text gives a concise introduction to rotational motion, an expansion to rigid bodies, fluids and gases. Finally, an extensive chapter on thermodynamics and a short introduction to nonlinear dynamics with some instructive examples intensify the knowledge of more advanced topics. Numerous problems with detailed solutions are perfect for self study.
Thermodynamical quantum information sharing
International Nuclear Information System (INIS)
Wiesniak, M.; Vedral, V.; Brukner, C.
2005-01-01
Full text: Thermodynamical properties fully originate from classical physics and can be easily measured for macroscopic systems. On the other hand, entanglement is a widely spoken feature of quantum physics, which allows to perform certain task with efficiency unavailable with any classical resource. Therefore an interesting question is whether we can witness entanglement in a state of a macroscopic sample. We show, that some macroscopic properties, in particular magnetic susceptibility, can serve as an entanglement witnesses. We also study a mutual relation between magnetic susceptibility and magnetisation. Such a complementarity exhibits quantum information sharing between these two thermodynamical quantities. Magnetization expresses properties of individual spins, while susceptibility might reveal non-classical correlations as a witness. Therefore, a rapid change of one of these two quantities may mean a phase transition also in terms of entanglement. The complementarity relation is demonstrated by an analytical solution of an exemplary model. (author)
A commentary on thermodynamics
Day, William Alan
1988-01-01
The aim of this book is to comment on, and clarify, the mathematical aspects of the theory of thermodynamics. The standard presentations of the subject are often beset by a number of obscurities associated with the words "state", "reversible", "irreversible", and "quasi-static". This book is written in the belief that such obscurities are best removed not by the formal axiomatization of thermodynamics, but by setting the theory in the wider context of a genuine field theory which incorporates the effects of heat conduction and intertia, and proving appropriate results about the governing differential equations of this field theory. Even in the simplest one-dimensional case it is a nontrivial task to carry through the details of this program, and many challenging problems remain open.
Thermodynamics of Crystalline States
Fujimoto, Minoru
2013-01-01
Thermodynamics is a well-established discipline of physics for properties of matter in thermal equilibrium with the surroundings. Applying to crystals, however, the laws encounter undefined properties of crystal lattice, which therefore need to be determined for a clear and well-defined description of crystalline states. Thermodynamics of Crystalline States explores the roles played by order variables and dynamic lattices in crystals in a wholly new way. The book begins by clarifying basic concepts for stable crystals. Next, binary phase transitions are discussed to study collective motion of order variables, as described mostly as classical phenomena. New to this edition is the examination of magnetic crystals, where magnetic symmetry is essential for magnetic phase transitions. The multi-electron system is also discussed theoretically, as a quantum-mechanical example, for superconductivity in metallic crystals. Throughout the book, the role played by the lattice is emphasized and studied in-depth. Thermod...
Gaetani, G.A.; Cohen, A.L.; Wang, Z.; Crusius, John
2011-01-01
This study presents a new approach to coral thermometry that deconvolves the influence of water temperature on skeleton composition from that of “vital effects”, and has the potential to provide estimates of growth temperatures that are accurate to within a few tenths of a degree Celsius from both tropical and cold-water corals. Our results provide support for a physico-chemical model of coral biomineralization, and imply that Mg2+ substitutes directly for Ca2+ in biogenic aragonite. Recent studies have identified Rayleigh fractionation as an important influence on the elemental composition of coral skeletons. Daily, seasonal and interannual variations in the amount of aragonite precipitated by corals from each “batch” of calcifying fluid can explain why the temperature dependencies of elemental ratios in coral skeleton differ from those of abiogenic aragonites, and are highly variable among individual corals. On the basis of this new insight into the origin of “vital effects” in coral skeleton, we developed a Rayleigh-based, multi-element approach to coral thermometry. Temperature is resolved from the Rayleigh fractionation signal by combining information from multiple element ratios (e.g., Mg/Ca, Sr/Ca, Ba/Ca) to produce a mathematically over-constrained system of Rayleigh equations. Unlike conventional coral thermometers, this approach does not rely on an initial calibration of coral skeletal composition to an instrumental temperature record. Rather, considering coral skeletogenesis as a biologically mediated, physico-chemical process provides a means to extract temperature information from the skeleton composition using the Rayleigh equation and a set of experimentally determined partition coefficients. Because this approach is based on a quantitative understanding of the mechanism that produces the “vital effect” it should be possible to apply it both across scleractinian species and to corals growing in vastly different environments. Where
Thermodynamics of clan production
International Nuclear Information System (INIS)
Giovannini, Alberto; Lupia, Sergio; Ugoccioni, Roberto
2002-01-01
Scenarios for particle production in the GeV and TeV regions are reviewed. The expected increase with the c.m. energy of the average number of clans for the soft component and the decrease for the semihard one indicate possible classical and quantum behavior of gluons, respectively. Clan thermodynamics, discussed in the paper, appears as the natural framework to deal with such phenomena
Work reservoirs in thermodynamics
International Nuclear Information System (INIS)
Anacleto, Joaquim
2010-01-01
We stress the usefulness of the work reservoir in the formalism of thermodynamics, in particular in the context of the first law. To elucidate its usefulness, the formalism is then applied to the Joule expansion and other peculiar and instructive experimental situations, clarifying the concepts of configuration and dissipative work. The ideas and discussions presented in this study are primarily intended for undergraduate students, but they might also be useful to graduate students, researchers and teachers.
Work reservoirs in thermodynamics
Anacleto, Joaquim
2010-05-01
We stress the usefulness of the work reservoir in the formalism of thermodynamics, in particular in the context of the first law. To elucidate its usefulness, the formalism is then applied to the Joule expansion and other peculiar and instructive experimental situations, clarifying the concepts of configuration and dissipative work. The ideas and discussions presented in this study are primarily intended for undergraduate students, but they might also be useful to graduate students, researchers and teachers.
International Nuclear Information System (INIS)
Bonasera, A.; Latora, V.; Ploszajczak, M.
1996-07-01
The maximal Lyapunov exponents (LE) are calculated, starting from concepts of hydrodynamics. Analytical expressions for the LE can be found in ergodic limit by using results of the classical thermodynamics for a Boltzmann gas and for systems undergoing a second order phase transition. A recipe is given to measure LE in systems which might have a critical behavior, such as a Bose-Einstein condensation or a transition to a quark-gluon plasma. (author)
Advanced thermodynamic (exergetic) analysis
International Nuclear Information System (INIS)
Tsatsaronis, G; Morosuk, T
2012-01-01
Exergy analysis is a powerful tool for developing, evaluating and improving an energy conversion system. However, the lack of a formal procedure in using the results obtained by an exergy analysis is one of the reasons for exergy analysis not being very popular among energy practitioners. Such a formal procedure cannot be developed as long as the interactions among components of the overall system are not being taken properly into account. Splitting the exergy destruction into unavoidable and avoidable parts in a component provides a realistic measure of the potential for improving the thermodynamic efficiency of this component. Alternatively splitting the exergy destruction into endogenous and exogenous parts provides information on the interactions among system components. Distinctions between avoidable and unavoidable exergy destruction on one side and endogenous and exogenous exergy destruction on the other side allow the engineer to focus on the thermodynamic inefficiencies that can be avoided and to consider the interactions among system components. The avoidable endogenous and the avoidable exogenous exergy destruction provide the best guidance for improving the thermodynamic performance of energy conversion systems.
The discovery of thermodynamics
Weinberger, Peter
2013-07-01
Based on the idea that a scientific journal is also an "agora" (Greek: market place) for the exchange of ideas and scientific concepts, the history of thermodynamics between 1800 and 1910 as documented in the Philosophical Magazine Archives is uncovered. Famous scientists such as Joule, Thomson (Lord Kelvin), Clausius, Maxwell or Boltzmann shared this forum. Not always in the most friendly manner. It is interesting to find out, how difficult it was to describe in a scientific (mathematical) language a phenomenon like "heat", to see, how long it took to arrive at one of the fundamental principles in physics: entropy. Scientific progress started from the simple rule of Boyle and Mariotte dating from the late eighteenth century and arrived in the twentieth century with the concept of probabilities. Thermodynamics was the driving intellectual force behind the industrial revolution, behind the enormous social changes caused by this revolution. The history of thermodynamics is a fascinating story, which also gives insights into the mechanism that seem to govern science.
Campbell, Anne A.; Porter, Wallace D.; Katoh, Yutai; Snead, Lance L.
2016-03-01
Silicon carbide is used as a passive post-irradiation temperature monitor because the irradiation defects will anneal out above the irradiation temperature. The irradiation temperature is determined by measuring a property change after isochronal annealing, i.e., lattice spacing, dimensions, electrical resistivity, thermal diffusivity, or bulk density. However, such methods are time-consuming since the steps involved must be performed in a serial manner. This work presents the use of thermal expansion from continuous dilatometry to calculate the SiC irradiation temperature, which is an automated process requiring minimal setup time. Analysis software was written that performs the calculations to obtain the irradiation temperature and removes possible user-introduced error while standardizing the analysis. This method has been compared to an electrical resistivity and isochronal annealing investigation, and the results revealed agreement of the calculated temperatures. These results show that dilatometry is a reliable and less time-intensive process for determining irradiation temperature from passive SiC thermometry.
Thermometry of levitated nanoparticles in a hybrid electro-optical trap
Aranas, E. B.; Fonseca, P. Z. G.; Barker, P. F.; Monteiro, T. S.
2017-03-01
There have been recent rapid developments in stable trapping of levitated nanoparticles in high vacuum. Cooling of nanoparticles, from phonon occupancies of 107 down to ≃ 100{--}1000 phonons, have already been achieved by several groups. Prospects for quantum ground-state cooling seem extremely promising. Cavity-cooling without added stabilisation by feedback cooling remains challenging, but trapping at high vacuum in a cavity is now possible through the addition of a Paul trap. However, the Paul trap has been found to qualitatively modify the cavity output spectrum, with the latter acquiring an atypical ‘split-sideband’ structure, of different form from the displacement spectrum, and which depends on N, the optical well at which the particle localises. In the present work we investigate the N-dependence of the dynamics, in particular with respect to thermometry: we show that in strong cooling regions N≳ 100, the temperature may still be reliably inferred from the cavity output spectra. We also explain the N-dependence of the mechanical frequencies and optomechanical coupling showing that these may be accurately estimated. We present a simple ‘fast-cavity’ model for the cavity output and test all our findings against full numerical solutions of the nonlinear stochastic equations of motion for the system.
Directory of Open Access Journals (Sweden)
Jun Du
2013-01-01
Full Text Available A scour monitoring system for subsea pipeline based on active thermometry is proposed in this paper. The temperature reading of the proposed system is based on a distributed Brillouin optical fiber sensing technique. A thermal cable acts as the main component of the system, which consists of a heating belt, armored optical fibers and heat-shrinkable tubes which run parallel to the pipeline. The scour-induced free span can be monitored through different heat transfer behaviors of in-water and in-sediment scenarios during heating and cooling processes. Two sets of experiments, including exposing different lengths of the upper surface of the pipeline to water and creating free spans of various lengths, were carried out in laboratory. In both cases, the scour condition was immediately detected by the proposed monitoring system, which confirmed the system is robust and very sensitive. Numerical study of the method was also investigated by using the finite element method (FEM with ANSYS, resulting in reasonable agreement with the test data. This brand new system provides a promising, low cost, highly precise and flexible approach for scour monitoring of subsea pipelines.
Flame thermometry using laser-induced-grating spectroscopy of nitric oxide
Luers, Andrew; Salhlberg, Anna-Lena; Hochgreb, Simone; Ewart, Paul
2018-03-01
A systematic study of laser-induced thermal-grating scattering (LITGS) using nitric oxide as an absorbing species is presented as a means of thermometry in air-fed combustion. The relative contributions to the scattered signal from degenerate four-wave mixing, DFWM, and from laser-induced thermal-grating scattering, LITGS, are studied in the time domain for NO in N2 buffer gas up to 4 bar, using a pulsed laser system to excite the (0,0) γ-bands of NO at 226.21 nm. LITGS signals from combustion-generated NO in a laminar, pre-mixed CH4/O2/N2 flame on an in-house constructed slot burner were used to derive temperature values as a function of O2 concentration and position in the flame at 1 and 2.5 bar total pressure. Temperature values consistent with the calculated adiabatic flame temperature were derived from averaged LITGS signals over 50-100 single shots at 10 Hz repetition rate in the range 1600-2400 K with a pressure-dependent uncertainty of ± 1.8% at 1 bar to ± 1.4% at 2.5 bar. Based on observed signal-to-noise ratios, the minimum detectable concentration of NO in the flame is estimated to be 80 ppm for a 5 s measurement time at 10 Hz repetition rate.
Planar measurements of spray-induced wall cooling using phosphor thermometry
Dragomirov, Plamen; Mendieta, Aldo; Abram, Christopher; Fond, Benoît; Beyrau, Frank
2018-03-01
The wall cooling induced by spray impingement is investigated using phosphor thermometry. Thin coatings of zinc oxide (ZnO) phosphor were applied with a transparent chemical binder onto a steel surface. Instantaneous spatially resolved temperatures were determined using the spectral intensity ratio method directly after the injection of UV-grade hexane onto the surface using a commercial gasoline injector. The investigations showed that 2D temperature measurements with high spatial and shot-to-shot precision of, respectively, 0.5 and 0.6 K can be achieved, allowing the accurate resolution of the cooling induced by the spray. The presence of a liquid film over the phosphor coating during measurements showed no noticeable influence on the measured temperatures. However, in some cases a change in the intensity ratio at the spray impingement area, in the form of a permanent "stain", could be observed after multiple injections. The formation of this stain was less likely with increasing annealing time of the coating as well as lower plate operating temperatures during the injection experiments. Finally, the experimental results indicate a noticeable influence of the thickness of the phosphor coating on the measured spray-induced wall cooling history. Hence, for quantitative analysis, a compromise between coating thickness and measurement accuracy needs to be considered for similar applications where the heat transfer rates are very high.
Sensitivity Modulation of Upconverting Thermometry through Engineering Phonon Energy of a Matrix.
Suo, Hao; Guo, Chongfeng; Zheng, Jiming; Zhou, Bo; Ma, Chonggeng; Zhao, Xiaoqi; Li, Ting; Guo, Ping; Goldys, Ewa M
2016-11-09
Investigation of the unclear influential factors to thermal sensing capability is the only way to achieve highly sensitive thermometry, which is greatly needed to meet the growing demand for potential sensing applications. Here, the effect from the phonon energy of a matrix on the sensitivity of upconversion (UC) microthermometers is elaborately discussed using a controllable method. Uniform truncated octahedral YF 3 :Er 3+ /Yb 3+ microcrystals were prepared by a hydrothermal approach, and phase transformation from YF 3 to YOF and Y 2 O 3 with nearly unchanged morphology and size was successfully realized by controlling the annealing temperature. The phonon energies of blank matrixes were determined by FT-IR spectra and Raman scattering. Upon 980 nm excitation, phonon energy-dependent UC emitting color was finely tuned from green to yellow for three samples, and the mechanisms were proposed. Thermal sensing behaviors based on the TCLs ( 2 H 11/2 / 4 S 3/2 ) were evaluated, and the sensitivities gradually grew with the increase in the matrix's phonon energy. According to chemical bond theory and first-principle calculations, the most intrinsic factors associated with thermometric ability were qualitatively demonstrated through analyzing the inner relation between the phonon energy and bond covalency. The exciting results provide guiding insights into employing appropriate host materials with desired thermometric ability while offering the possibility of highly accurate measurement of temperature.
Urano, C.; Yamazawa, K.; Kaneko, N.-H.
2017-12-01
We report on our measurement of the Boltzmann constant by Johnson noise thermometry (JNT) using an integrated quantum voltage noise source (IQVNS) that is fully implemented with superconducting integrated circuit technology. The IQVNS generates calculable pseudo white noise voltages to calibrate the JNT system. The thermal noise of a sensing resistor placed at the temperature of the triple point of water was measured precisely by the IQVNS-based JNT. We accumulated data of more than 429 200 s in total (over 6 d) and used the Akaike information criterion to estimate the fitting frequency range for the quadratic model to calculate the Boltzmann constant. Upon detailed evaluation of the uncertainty components, the experimentally obtained Boltzmann constant was k=1.380 6436× {{10}-23} J K-1 with a relative combined uncertainty of 10.22× {{10}-6} . The value of k is relatively -3.56× {{10}-6} lower than the CODATA 2014 value (Mohr et al 2016 Rev. Mod. Phys. 88 035009).
International Nuclear Information System (INIS)
Moon, Byung Soo; Hwang, In Koo; Chung, Chong Eun; Kwon, Kee Choon; David, E. H.; Kisner, R.A.
2004-06-01
In this report, we first proved that a random signal obtained by taking the sum of a set of signal frequency signals generates a continuous Markov process. We used this random signal to simulate the Johnson noise and verified that the Johnson noise thermometry can be used to improve the measurements of the reactor coolant temperature within an accuracy of below 0.14%. Secondly, by using this random signal we determined the optimal sampling rate when the frequency band of the Johnson noise signal is given. Also the results of our examination on how good the linearity of the Johnson noise is and how large the relative error of the temperature could become when the temperature increases are described. Thirdly, the results of our analysis on a set of the Johnson noise signal blocks taken from a simple electric circuit are described. We showed that the properties of the continuous Markov process are satisfied even when some channel noises are present. Finally, we describe the algorithm we devised to handle the problem of the time lag in the long-term average or the moving average in a transient state. The algorithm is based on the Haar wavelet and is to estimate the transient temperature that has much smaller time delay. We have shown that the algorithm can track the transient temperature successfully
Improving Agricultural Water Resources Management Using Ground-based Infrared Thermometry
Taghvaeian, S.
2014-12-01
Irrigated agriculture is the largest user of freshwater resources in arid/semi-arid parts of the world. Meeting rapidly growing demands in food, feed, fiber, and fuel while minimizing environmental pollution under a changing climate requires significant improvements in agricultural water management and irrigation scheduling. Although recent advances in remote sensing techniques and hydrological modeling has provided valuable information on agricultural water resources and their management, real improvements will only occur if farmers, the decision makers on the ground, are provided with simple, affordable, and practical tools to schedule irrigation events. This presentation reviews efforts in developing methods based on ground-based infrared thermometry and thermography for day-to-day management of irrigation systems. The results of research studies conducted in Colorado and Oklahoma show that ground-based remote sensing methods can be used effectively in quantifying water stress and consequently triggering irrigation events. Crop water use estimates based on stress indices have also showed to be in good agreement with estimates based on other methods (e.g. surface energy balance, root zone soil water balance, etc.). Major challenges toward the adoption of this approach by agricultural producers include the reduced accuracy under cloudy and humid conditions and its inability to forecast irrigation date, which is a critical knowledge since many irrigators need to decide about irrigations a few days in advance.
Estimation of wetland evapotranspiration in northern New York using infrared thermometry
Hwang, K.; Chandler, D. G.
2016-12-01
Evapotranspiration (ET) is an important component of the water budget and often regarded as a major water loss. In freshwater wetlands, cumulative annual ET can equal precipitation under well-watered conditions. Wetland ET is therefore an important control on contaminant and nutrient transport. Yet, quantification of wetland ET is challenged by complex surface characteristics, diverse plant species and density, and variations in wetland shape and size. As handheld infrared (IR) cameras have become available, studies exploiting the new technology have increased, especially in agriculture and hydrology. The benefits of IR cameras include (1) high spatial resolution, (2) high sample rates, (3) real-time imaging, (4) a constant viewing geometry, and (5) no need for atmosphere and cloud corrections. Compared with traditional methods, infrared thermometer is capable of monitoring at the scale of a small pond or localized plant community. This enables finer scale survey of heterogeneous land surfaces rather than strict dependence on atmospheric variables. Despite this potential, there has been a limited number of studies of ET and drought stress with IR cameras. In this study, the infrared thermometry-based method was applied to estimate ET over wetland plant species in St. Lawrence River Valley, NY. The results are evaluated with traditional methods to test applicability over multiple vegetation species in a same area.
Fluorescent Molecular Rotor-in-Paraffin Waxes for Thermometry and Biometric Identification.
Jin, Young-Jae; Dogra, Rubal; Cheong, In Woo; Kwak, Giseop
2015-07-08
Novel thermoresponsive sensor systems consisting of a molecular rotor (MR) and paraffin wax (PW) were developed for various thermometric and biometric identification applications. Polydiphenylacetylenes (PDPAs) coupled with long alkyl chains were used as MRs, and PWs of hydrocarbons having 16-20 carbons were utilized as phase-change materials. The PDPAs were successfully dissolved in the molten PWs and did not act as an impurity that prevents phase transition of the PWs. These PDPA-in-PW hybrids had almost the same enthalpies and phase-transition temperatures as the corresponding pure PWs. The hybrids exhibited highly reversible fluorescence (FL) changes at the critical temperatures during phase transition of the PWs. These hybrids were impregnated into common filter paper in the molten state by absorption or were encapsulated into urea resin to enhance their mechanical integrity and cyclic stability during repeated use. The wax papers could be utilized in highly advanced applications including FL image writing/erasing, an array-type thermo-indicator, and fingerprint/palmprint identification. The present findings should facilitate the development of novel fluorescent sensor systems for biometric identification and are potentially applicable for biological and biomedical thermometry.
Infrared thermometry and the crop water stress index. I. History, theory, and baselines
International Nuclear Information System (INIS)
Gardner, B.R.; Nielsen, D.C.; Shock, C.C.
1992-01-01
Development of portable infrared thermometers and the definition of the Crop Water Stress Index (CWSI) have led to widespread interest in infrared thermometry to monitor water stress and schedule irrigations. But the CWSI concept is still new and poorly understood by many. The purpose of this paper is to review the definition of CWSI, and the determination and interpretation of the non-water-stressed baselines used to compute CWSI. The non-water-stressed baseline equation normalizes the canopy minus air temperature differential for variations in vapor pressure deficit. Non-water-stressed baselines can be determined empirically from measurements of canopy and air temperatures and vapor pressure deficit, made diurnally on a single day, or at a single time of day over many days, on well-watered plants. The value of the maximum canopy minus air temperature differential under maximum water stress should also be determined empirically. Causes for CWSI values falling outside of the defined 0 to 10 unit range are reviewed. Non-water-stressed baselines may shift with plant growth stage. Effective use of CWSI is dependent on understanding the definition of CWSI, and the proper determination and use of non-water-stressed baselines. (author)
Microchip transponder thermometry for monitoring core body temperature of antelope during capture.
Rey, Benjamin; Fuller, Andrea; Hetem, Robyn S; Lease, Hilary M; Mitchell, Duncan; Meyer, Leith C R
2016-01-01
Hyperthermia is described as the major cause of morbidity and mortality associated with capture, immobilization and restraint of wild animals. Therefore, accurately determining the core body temperature of wild animals during capture is crucial for monitoring hyperthermia and the efficacy of cooling procedures. We investigated if microchip thermometry can accurately reflect core body temperature changes during capture and cooling interventions in the springbok (Antidorcas marsupialis), a medium-sized antelope. Subcutaneous temperature measured with a temperature-sensitive microchip was a weak predictor of core body temperature measured by temperature-sensitive data loggers in the abdominal cavity (R(2)=0.32, bias >2 °C). Temperature-sensitive microchips in the gluteus muscle, however, provided an accurate estimate of core body temperature (R(2)=0.76, bias=0.012 °C). Microchips inserted into muscle therefore provide a convenient and accurate method to measure body temperature continuously in captured antelope, allowing detection of hyperthermia and the efficacy of cooling procedures. Copyright © 2015 Elsevier Ltd. All rights reserved.
Thermodynamics: The Unique Universal Science
Directory of Open Access Journals (Sweden)
Wassim M. Haddad
2017-11-01
Full Text Available Thermodynamics is a physical branch of science that governs the thermal behavior of dynamical systems from those as simple as refrigerators to those as complex as our expanding universe. The laws of thermodynamics involving conservation of energy and nonconservation of entropy are, without a doubt, two of the most useful and general laws in all sciences. The first law of thermodynamics, according to which energy cannot be created or destroyed, merely transformed from one form to another, and the second law of thermodynamics, according to which the usable energy in an adiabatically isolated dynamical system is always diminishing in spite of the fact that energy is conserved, have had an impact far beyond science and engineering. In this paper, we trace the history of thermodynamics from its classical to its postmodern forms, and present a tutorial and didactic exposition of thermodynamics as it pertains to some of the deepest secrets of the universe.
Thermodynamics of adaptive molecular resolution.
Delgado-Buscalioni, R
2016-11-13
A relatively general thermodynamic formalism for adaptive molecular resolution (AMR) is presented. The description is based on the approximation of local thermodynamic equilibrium and considers the alchemic parameter λ as the conjugate variable of the potential energy difference between the atomistic and coarse-grained model Φ=U (1) -U (0) The thermodynamic formalism recovers the relations obtained from statistical mechanics of H-AdResS (Español et al, J. Chem. Phys. 142, 064115, 2015 (doi:10.1063/1.4907006)) and provides relations between the free energy compensation and thermodynamic potentials. Inspired by this thermodynamic analogy, several generalizations of AMR are proposed, such as the exploration of new Maxwell relations and how to treat λ and Φ as 'real' thermodynamic variablesThis article is part of the themed issue 'Multiscale modelling at the physics-chemistry-biology interface'. © 2016 The Author(s).
RNA Thermodynamic Structural Entropy.
Garcia-Martin, Juan Antonio; Clote, Peter
2015-01-01
Conformational entropy for atomic-level, three dimensional biomolecules is known experimentally to play an important role in protein-ligand discrimination, yet reliable computation of entropy remains a difficult problem. Here we describe the first two accurate and efficient algorithms to compute the conformational entropy for RNA secondary structures, with respect to the Turner energy model, where free energy parameters are determined from UV absorption experiments. An algorithm to compute the derivational entropy for RNA secondary structures had previously been introduced, using stochastic context free grammars (SCFGs). However, the numerical value of derivational entropy depends heavily on the chosen context free grammar and on the training set used to estimate rule probabilities. Using data from the Rfam database, we determine that both of our thermodynamic methods, which agree in numerical value, are substantially faster than the SCFG method. Thermodynamic structural entropy is much smaller than derivational entropy, and the correlation between length-normalized thermodynamic entropy and derivational entropy is moderately weak to poor. In applications, we plot the structural entropy as a function of temperature for known thermoswitches, such as the repression of heat shock gene expression (ROSE) element, we determine that the correlation between hammerhead ribozyme cleavage activity and total free energy is improved by including an additional free energy term arising from conformational entropy, and we plot the structural entropy of windows of the HIV-1 genome. Our software RNAentropy can compute structural entropy for any user-specified temperature, and supports both the Turner'99 and Turner'04 energy parameters. It follows that RNAentropy is state-of-the-art software to compute RNA secondary structure conformational entropy. Source code is available at https://github.com/clotelab/RNAentropy/; a full web server is available at http
RNA Thermodynamic Structural Entropy.
Directory of Open Access Journals (Sweden)
Juan Antonio Garcia-Martin
Full Text Available Conformational entropy for atomic-level, three dimensional biomolecules is known experimentally to play an important role in protein-ligand discrimination, yet reliable computation of entropy remains a difficult problem. Here we describe the first two accurate and efficient algorithms to compute the conformational entropy for RNA secondary structures, with respect to the Turner energy model, where free energy parameters are determined from UV absorption experiments. An algorithm to compute the derivational entropy for RNA secondary structures had previously been introduced, using stochastic context free grammars (SCFGs. However, the numerical value of derivational entropy depends heavily on the chosen context free grammar and on the training set used to estimate rule probabilities. Using data from the Rfam database, we determine that both of our thermodynamic methods, which agree in numerical value, are substantially faster than the SCFG method. Thermodynamic structural entropy is much smaller than derivational entropy, and the correlation between length-normalized thermodynamic entropy and derivational entropy is moderately weak to poor. In applications, we plot the structural entropy as a function of temperature for known thermoswitches, such as the repression of heat shock gene expression (ROSE element, we determine that the correlation between hammerhead ribozyme cleavage activity and total free energy is improved by including an additional free energy term arising from conformational entropy, and we plot the structural entropy of windows of the HIV-1 genome. Our software RNAentropy can compute structural entropy for any user-specified temperature, and supports both the Turner'99 and Turner'04 energy parameters. It follows that RNAentropy is state-of-the-art software to compute RNA secondary structure conformational entropy. Source code is available at https://github.com/clotelab/RNAentropy/; a full web server is available at http
Chemical thermodynamics of uranium
International Nuclear Information System (INIS)
Grenthe, I.; Fuger, J.; Lemire, R.J.; Muller, A.B.; Nguyen-Trung Cregu, C.; Wanner, H.
1992-01-01
A comprehensive overview on the chemical thermodynamics of those elements that are of particular importance in the safety assessment of radioactive waste disposal systems is provided. This is the first volume in a series of critical reviews to be published on this subject. The book provides an extensive compilation of chemical thermodynamic data for uranium. A description of procedures for activity corrections and uncertainty estimates is given. A critical discussion of data needed for nuclear waste management assessments, including areas where significant gaps of knowledge exist is presented. A detailed inventory of chemical thermodynamic data for inorganic compounds and complexes of uranium is listed. Data and their uncertainty limits are recommended for 74 aqueous complexes and 199 solid and 31 gaseous compounds containing uranium, and on 52 aqueous and 17 solid auxiliary species containing no uranium. The data are internally consistent and compatible with the CODATA Key Values. The book contains a detailed discussion of procedures used for activity factor corrections in aqueous solution, as well as including methods for making uncertainty estimates. The recommended data have been prepared for use in environmental geochemistry. Containing contributions written by experts the chapters cover various subject areas such a s: oxide and hydroxide compounds and complexes, the uranium nitrides, the solid uranium nitrates and the arsenic-containing uranium compounds, uranates, procedures for consistent estimation of entropies, gaseous and solid uranium halides, gaseous uranium oxides, solid phosphorous-containing uranium compounds, alkali metal uranates, uncertainties, standards and conventions, aqueous complexes, uranium minerals dealing with solubility products and ionic strength corrections. The book is intended for nuclear research establishments and consulting firms dealing with uranium mining and nuclear waste disposal, as well as academic and research institutes
Quantum and thermodynamical aspects of black holes
International Nuclear Information System (INIS)
Sande e Lemos, J.P. de.
1982-08-01
The collapse of a spherically symmetric matter distribution resulting in Schwarzschild's black holes (BH) is discussed. Using Kerr metric, some dynamical results envolving test particles orbiting around BH with rotation are obtained. Quantum field theory is used to discuss the results obtained by Hawking in which one BH can emit a stationary flux of particles working a BH in a given temperature. Then, thermodynamics is introduced, some properties are verified and some phenomena of BH-radiation and BH-BH interaction are studied. (L.C.) [pt
Thermodynamics and phases in quantum gravity
International Nuclear Information System (INIS)
Husain, Viqar; Mann, R B
2009-01-01
We give an approach for studying quantum gravity effects on black hole thermodynamics. This combines a quantum framework for gravitational collapse with quasi-local definitions of energy and surface gravity. Our arguments suggest that (i) the specific heat of a black hole becomes positive after a phase transition near the Planck scale,(ii) its entropy acquires a logarithmic correction and (iii) the mass loss rate is modified such that Hawking radiation stops near the Planck scale. These results are due essentially to a realization of fundamental discreteness in quantum gravity, and are in this sense potentially theory independent.
Thermodynamics of phase transitions
International Nuclear Information System (INIS)
Cofta, H.
1972-01-01
The phenomenology of the phase transitions has been considered. The definitions of thermodynamic functions and parameters, as well as those of the phase transitions, are given and some of the relations between those quantities are discussed. The phase transitions classification proposed by Ehrenfest has been described. The most important features of phase transitions are discussed using the selected physical examples including the critical behaviour of ferromagnetic materials at the Curie temperature and antiferromagnetic materials at the Neel temperature. Some aspects of the Ehrenfest's equations, that have been derived, for the interfacial lines and surfaces are considered as well as the role the notion of interfaces. (S.B.)
Energy Technology Data Exchange (ETDEWEB)
Biswas, S. N.
1980-07-01
The application of quantum statistical mechanics to a system of particles consisting of quarks is considered. Realistic theoretical investigations have been underway to understand highly dense objects such as white dwarfs and neutron stars. The various possibilities in the case of very high densities such as 10/sup 15/ or 10/sup 16/ g/cm/sup 3/ are enumerated. The thermodynamics of a phase transition from neutron matter phase to quark matter phase is analysed. Preliminary results based on quantum chromodynamics and other phenomenological models are reported.
Kirkland, Kyle
2007-01-01
Temperature is vital to the health and welfare of all living beings, and Earth's temperature varies considerably from place to place. Early humans could only live in warm areas such as the tropics. Although modern humans have the technology to keep their houses and offices warm even in cold environments, the growth and development of civilization has created unintentional effects. Cities are warmer than their surrounding regions, and on a global scale, Earth is experiencing rising temperatures. Thus, the science of thermodynamics offers an important tool to study these effects. "Time and
Navrotsky, Alexandra
Thermodynamics of Crystals is a gold mine of a references bargain with more derivations of useful equations per dollar, or per page, than almost any other book I know. Useful to whom? To the solid state physicist, the solid state chemist working the geophysicist, the rock mechanic, the mineral physicist. Useful for what? For lattice dynamics, crystal potentials, band structure. For elegant, rigorous, and concise derivations of fundamental equations. For comparison of levels of approximation. For some data and physical insights, especially for metals and simple halides. This book is a reissue, with some changes and additions, of a 1970 treatise. It ages well, since the fundamentals do not change.
Interfacial solvation thermodynamics
International Nuclear Information System (INIS)
Ben-Amotz, Dor
2016-01-01
Previous studies have reached conflicting conclusions regarding the interplay of cavity formation, polarizability, desolvation, and surface capillary waves in driving the interfacial adsorptions of ions and molecules at air–water interfaces. Here we revisit these questions by combining exact potential distribution results with linear response theory and other physically motivated approximations. The results highlight both exact and approximate compensation relations pertaining to direct (solute–solvent) and indirect (solvent–solvent) contributions to adsorption thermodynamics, of relevance to solvation at air–water interfaces, as well as a broader class of processes linked to the mean force potential between ions, molecules, nanoparticles, proteins, and biological assemblies. (paper)
Kaufman, Myron
2002-01-01
Ideal for one- or two-semester courses that assume elementary knowledge of calculus, This text presents the fundamental concepts of thermodynamics and applies these to problems dealing with properties of materials, phase transformations, chemical reactions, solutions and surfaces. The author utilizes principles of statistical mechanics to illustrate key concepts from a microscopic perspective, as well as develop equations of kinetic theory. The book provides end-of-chapter question and problem sets, some using Mathcad™ and Mathematica™; a useful glossary containing important symbols, definitions, and units; and appendices covering multivariable calculus and valuable numerical methods.
Gravitation, Thermodynamics, and Quantum Theory
Wald, Robert M.
1999-01-01
During the past 30 years, research in general relativity has brought to light strong hints of a very deep and fundamental relationship between gravitation, thermodynamics, and quantum theory. The most striking indication of such a relationship comes from black hole thermodynamics, where it appears that certain laws of black hole mechanics are, in fact, simply the ordinary laws of thermodynamics applied to a system containing a black hole. This article will review the present status of black h...
On thermodynamic and microscopic reversibility
International Nuclear Information System (INIS)
Crooks, Gavin E
2011-01-01
The word 'reversible' has two (apparently) distinct applications in statistical thermodynamics. A thermodynamically reversible process indicates an experimental protocol for which the entropy change is zero, whereas the principle of microscopic reversibility asserts that the probability of any trajectory of a system through phase space equals that of the time reversed trajectory. However, these two terms are actually synonymous: a thermodynamically reversible process is microscopically reversible, and vice versa
Quantum Thermodynamics at Strong Coupling: Operator Thermodynamic Functions and Relations
Directory of Open Access Journals (Sweden)
Jen-Tsung Hsiang
2018-05-01
Full Text Available Identifying or constructing a fine-grained microscopic theory that will emerge under specific conditions to a known macroscopic theory is always a formidable challenge. Thermodynamics is perhaps one of the most powerful theories and best understood examples of emergence in physical sciences, which can be used for understanding the characteristics and mechanisms of emergent processes, both in terms of emergent structures and the emergent laws governing the effective or collective variables. Viewing quantum mechanics as an emergent theory requires a better understanding of all this. In this work we aim at a very modest goal, not quantum mechanics as thermodynamics, not yet, but the thermodynamics of quantum systems, or quantum thermodynamics. We will show why even with this minimal demand, there are many new issues which need be addressed and new rules formulated. The thermodynamics of small quantum many-body systems strongly coupled to a heat bath at low temperatures with non-Markovian behavior contains elements, such as quantum coherence, correlations, entanglement and fluctuations, that are not well recognized in traditional thermodynamics, built on large systems vanishingly weakly coupled to a non-dynamical reservoir. For quantum thermodynamics at strong coupling, one needs to reexamine the meaning of the thermodynamic functions, the viability of the thermodynamic relations and the validity of the thermodynamic laws anew. After a brief motivation, this paper starts with a short overview of the quantum formulation based on Gelin & Thoss and Seifert. We then provide a quantum formulation of Jarzynski’s two representations. We show how to construct the operator thermodynamic potentials, the expectation values of which provide the familiar thermodynamic variables. Constructing the operator thermodynamic functions and verifying or modifying their relations is a necessary first step in the establishment of a viable thermodynamics theory for
Experimental approaches to membrane thermodynamics
DEFF Research Database (Denmark)
Westh, Peter
2009-01-01
Thermodynamics describes a system on the macroscopic scale, yet it is becoming an important tool for the elucidation of many specific molecular aspects of membrane properties. In this note we discuss this application of thermodynamics, and give a number of examples on how thermodynamic measurements...... have contributed to the understanding of specific membrane phenomena. We mainly focus on non-specific interactions of bilayers and small molecules (water and solutes) in the surrounding solvent, and the changes in membrane properties they bring about. Differences between thermodynamic...
Molecular thermodynamics of nonideal fluids
Lee, Lloyd L
2013-01-01
Molecular Thermodynamics of Nonideal Fluids serves as an introductory presentation for engineers to the concepts and principles behind and the advances in molecular thermodynamics of nonideal fluids. The book covers related topics such as the laws of thermodynamics; entropy; its ensembles; the different properties of the ideal gas; and the structure of liquids. Also covered in the book are topics such as integral equation theories; theories for polar fluids; solution thermodynamics; and molecular dynamics. The text is recommended for engineers who would like to be familiarized with the concept
Viallon, Magalie; Terraz, Sylvain; Roland, Joerg; Dumont, Erik; Becker, Christoph D; Salomir, Rares
2010-04-01
MR thermometry based on the proton resonance frequency shift (PRFS) is the most commonly used method for the monitoring of thermal therapies. As the chemical shift of water protons is temperature dependent, the local temperature variation (relative to an initial baseline) may be calculated from time-dependent phase changes in gradient-echo (GRE) MR images. Dynamic phase shift in GRE images is also produced by time-dependent changes in the magnetic bulk susceptibility of tissue. Gas bubbles (known as "white cavitation") are frequently visualized near the RF electrode in ultrasonography-guided radio frequency ablation (RFA). This study aimed to investigate RFA-induced cavitation's effects by using simultaneous ultrasonography and MRI, to both visualize the cavitation and quantify the subsequent magnetic susceptibility-mediated errors in concurrent PRFS MR-thermometry (MRT) as well as to propose a first-order correction for the latter errors. RF heating in saline gels and in ex vivo tissues was performed with MR-compatible bipolar and monopolar electrodes inside a 1.5 T MR clinical scanner. Ultrasonography simultaneous to PRFS MRT was achieved using a MR-compatible phased-array ultrasonic transducer. PRFS MRT was performed interleaved in three orthogonal planes and compared to measurements from fluoroptic sensors, under low and, respectively, high RFA power levels. Control experiments were performed to isolate the main source of errors in standard PRFS thermometry. Ultrasonography, MRI and digital camera pictures clearly demonstrated generation of bubbles every time when operating the radio frequency equipment at therapeutic powers (> or = 30 W). Simultaneous bimodal (ultrasonography and MRI) monitoring of high power RF heating demonstrated a correlation between the onset of the PRFS-thermometry errors and the appearance of bubbles around the applicator. In an ex vivo study using a bipolar RF electrode under low power level (5 W), the MR measured temperature curves
Thermodynamics of geothermal fluids
Energy Technology Data Exchange (ETDEWEB)
Rogers, P.S.Z.
1981-03-01
A model to predict the thermodynamic properties of geothermal brines, based on a minimum amount of experimental data on a few key systems, is tested. Volumetric properties of aqueous sodium chloride, taken from the literature, are represented by a parametric equation over the range 0 to 300{sup 0}C and 1 bar to 1 kbar. Density measurements at 20 bar needed to complete the volumetric description also are presented. The pressure dependence of activity and thermal properties, derived from the volumetric equation, can be used to complete an equation of state for sodium chloride solutions. A flow calorimeter, used to obtain heat capacity data at high temperatures and pressures, is described. Heat capacity measurements, from 30 to 200{sup 0}C and 1 bar to 200 bar, are used to derive values for the activity coefficient and other thermodynamic properties of sodium sulfate solutions as a function of temperature. Literature data on the solubility of gypsum in mixed electrolyte solutions have been used to evaluate model parameters for calculating gypsum solubility in seawater and natural brines. Predictions of strontium and barium sulfate solubility in seawater also are given.
Thermodynamics of Error Correction
Directory of Open Access Journals (Sweden)
Pablo Sartori
2015-12-01
Full Text Available Information processing at the molecular scale is limited by thermal fluctuations. This can cause undesired consequences in copying information since thermal noise can lead to errors that can compromise the functionality of the copy. For example, a high error rate during DNA duplication can lead to cell death. Given the importance of accurate copying at the molecular scale, it is fundamental to understand its thermodynamic features. In this paper, we derive a universal expression for the copy error as a function of entropy production and work dissipated by the system during wrong incorporations. Its derivation is based on the second law of thermodynamics; hence, its validity is independent of the details of the molecular machinery, be it any polymerase or artificial copying device. Using this expression, we find that information can be copied in three different regimes. In two of them, work is dissipated to either increase or decrease the error. In the third regime, the protocol extracts work while correcting errors, reminiscent of a Maxwell demon. As a case study, we apply our framework to study a copy protocol assisted by kinetic proofreading, and show that it can operate in any of these three regimes. We finally show that, for any effective proofreading scheme, error reduction is limited by the chemical driving of the proofreading reaction.
Chemical thermodynamic representation of
International Nuclear Information System (INIS)
Lindemer, T.B.; Besmann, T.M.
1984-01-01
The entire data base for the dependence of the nonstoichiometry, x, on temperature and chemical potential of oxygen (oxygen potential) was retrieved from the literature and represented. This data base was interpreted by least-squares analysis using equations derived from the classical thermodynamic theory for the solid solution of a solute in a solvent. For hyperstoichiometric oxide at oxygen potentials more positive than -266700 + 16.5T kJ/mol, the data were best represented by a [UO 2 ]-[U 3 O 7 ] solution. For O/U ratios above 2 and oxygen potentials below this boundary, a [UO 2 ]-[U 2 O 4 . 5 ] solution represented the data. The data were represented by a [UO 2 ]-[U 1 / 3 ] solution. The resulting equations represent the experimental ln(PO 2 ) - ln(x) behavior and can be used in thermodynamic calculations to predict phase boundary compositions consistent with the literature. Collectively, the present analysis permits a mathematical representation of the behavior of the total data base
De Lorenzo, Tommaso; Perez, Alejandro
2018-02-01
We show that null surfaces defined by the outgoing and infalling wave fronts emanating from and arriving at a sphere in Minkowski spacetime have thermodynamical properties that are in strict formal correspondence with those of black hole horizons in curved spacetimes. Such null surfaces, made of pieces of light cones, are bifurcate conformal Killing horizons for suitable conformally stationary observers. They can be extremal and nonextremal depending on the radius of the shining sphere. Such conformal Killing horizons have a constant light cone (conformal) temperature, given by the standard expression in terms of the generalization of surface gravity for conformal Killing horizons. Exchanges of conformally invariant energy across the horizon are described by a first law where entropy changes are given by 1 /(4 ℓp2) of the changes of a geometric quantity with the meaning of horizon area in a suitable conformal frame. These conformal horizons satisfy the zeroth to the third laws of thermodynamics in an appropriate way. In the extremal case they become light cones associated with a single event; these have vanishing temperature as well as vanishing entropy.
Thermodynamics and statistical physics. 2. rev. ed.
International Nuclear Information System (INIS)
Schnakenberg, J.
2002-01-01
This textbook covers tthe following topics: Thermodynamic systems and equilibrium, irreversible thermodynamics, thermodynamic potentials, stability, thermodynamic processes, ideal systems, real gases and phase transformations, magnetic systems and Landau model, low temperature thermodynamics, canonical ensembles, statistical theory, quantum statistics, fermions and bosons, kinetic theory, Bose-Einstein condensation, photon gas
Thermodynamic Properties and Thermodynamic Geometries of Black p-Branes
International Nuclear Information System (INIS)
Yi-Huan Wei; Xiao Cui; Jia-Xin Zhao
2016-01-01
The heat capacity and the electric capacitance of the black p-branes (BPB) are generally defined, then they are calculated for some special processes. It is found that the Ruppeiner thermodynamic geometry of BPB is flat. Finally, we give some discussions for the flatness of the Ruppeiner thermodynamic geometry of BPB and some black holes. (paper)
Zentgraf, Florian; Stephan, Michael; Berrocal, Edouard; Albert, Barbara; Böhm, Benjamin; Dreizler, Andreas
2017-07-01
Structured laser illumination planar imaging (SLIPI) is combined with gas phase thermometry measurements using thermographic phosphor (TGP) particles. The technique is applied to a heated jet surrounded by a coflow which is operated at ambient temperature. The respective air flows are seeded with a powder of BaMgAl10O17:Eu2+ (BAM) which is used as temperature-sensitive gas phase tracer. Upon pulsed excitation in the ultraviolet spectral range, the temperature is extracted based on the two-color ratio method combined with SLIPI. The main advantage of applying the SLIPI approach to phosphor thermometry is the reduction of particle-to-particle multiple light scattering and diffuse wall reflections, yielding a more robust calibration procedure as well as improving the measurement accuracy, precision, and sensitivity. For demonstration, this paper focuses on sample-averaged measurements of temperature fields in a jet-in-coflow configuration. Using the conventional approach, which in contrast to SLIPI is based on imaging with an unmodulated laser light sheet, we show that for the present setup typically 40% of the recorded signal is affected by the contribution of multiply scattered photons. At locations close to walls even up to 75% of the apparent signal is due to diffuse reflection and wall luminescence of BAM sticking at the surface. Those contributions lead to erroneous temperature fields. Using SLIPI, an unbiased two-color ratio field is recovered allowing for two-dimensional mean temperature reconstructions which exhibit a more realistic physical behavior. This is in contrast to results deduced by the conventional approach. Furthermore, using the SLIPI approach it is shown that the temperature sensitivity is enhanced by a factor of up to 2 at 270 °C. Finally, an outlook towards instantaneous SLIPI phosphorescence thermometry is provided.
Crake, Calum; Meral, F. Can; Burgess, Mark T.; Papademetriou, Iason T.; McDannold, Nathan J.; Porter, Tyrone M.
2017-08-01
Focused ultrasound (FUS) has the potential to enable precise, image-guided noninvasive surgery for the treatment of cancer in which tumors are identified and destroyed in a single integrated procedure. However, success of the method in highly vascular organs has been limited due to heat losses to perfusion, requiring development of techniques to locally enhance energy absorption and heating. In addition, FUS procedures are conventionally monitored using MRI, which provides excellent anatomical images and can map temperature, but is not capable of capturing the full gamut of available data such as the acoustic emissions generated during this inherently acoustically-driven procedure. Here, we employed phase-shift nanoemulsions (PSNE) embedded in tissue phantoms to promote cavitation and hence temperature rise induced by FUS. In addition, we incorporated passive acoustic mapping (PAM) alongside simultaneous MR thermometry in order to visualize both acoustic emissions and temperature rise, within the bore of a full scale clinical MRI scanner. Focal cavitation of PSNE could be resolved using PAM and resulted in accelerated heating and increased the maximum elevated temperature measured via MR thermometry compared to experiments without nanoemulsions. Over time, the simultaneously acquired acoustic and temperature maps show translation of the focus of activity towards the FUS transducer, and the magnitude of the increase in cavitation and focal shift both increased with nanoemulsion concentration. PAM results were well correlated with MRI thermometry and demonstrated greater sensitivity, with the ability to detect cavitation before enhanced heating was observed. The results suggest that PSNE could be beneficial for enhancement of thermal focused ultrasound therapies and that PAM could be a critical tool for monitoring this process.
van Beeck, Jeronimus Petrus Antonius Johannes; Grosges, Thomas; De Giorgi, Maria Grazia
2003-07-01
Global rainbow thermometry (GRT) measures the mean size and temperature of an ensemble of spray droplets. The domain of validity of the Airy theory for this technique is established through comparison with Lorenz-Mie theory. The temperature derivation from the inflection points of the Airy rainbow pattern appears to be independent of the type of spray dispersion. Measurements in a water spray are reported. The mean diameter obtained from the rainbow pattern lies between the arithmetic and the Sauter mean diameters measured by phase Doppler anemometry. The temperature measurement by GRT is shown to be accurate within a few degrees Celsius.
Energy Technology Data Exchange (ETDEWEB)
Strack, J.; Leung, K.; Walker, A., E-mail: strackj@mcmaster.ca [McMaster Univ., Hamilton, ON (Canada)
2014-07-01
Laser induced fluorescence (LIF) is an experimental technique whereby a scalar field in a fluid system is measured optically from the fluorescence intensity of a tracer dye following excitation by laser light. For laser induced fluorescence thermometry (LIF-T), a temperature sensitive dye is used. Through the use of a temperature sensitive tracer dye, sheet laser optics, optical filters, and photography, a 2D temperature field can be measured non-invasively. An experiment to test the viability of using LIF-T for macroscopic thermal hydraulic experiments was developed and tested. A reference calibration curve to relate fluorescence measurements to temperature is presented. (author)
Thiagarajan, N.; Tripati, A.; Eiler, J.
2007-12-01
fine fraction of 5.6 Ma sediments show calcification temperatures of 20.4°C ± 2.3°C and seawater δ18O values of -1.4‰ ± 0.6‰. G. sacculifer (with sac) and mixed coccoliths from 1.4 Ma sediments yield calcification temperatures of 22.3°C ± 2.5°C and seawater δ18O values of 1.7‰ ± 0.7‰, and 19.4°C ± 1.8°C and seawater δ18O values of 0.4‰ ± 0.5‰, respectively. Our preliminary findings are consistent with the 'dynamical ocean thermostat' model. [1] Clement, A., et al., 1996, An Ocean Dynamical Thermostat, J. of Clim., 9, 2190-2196. [2] Cane, M., et al., 1997, Twentieth-Century Sea Surface Temperature Trends, Science, 957-960. [3] Fedorov, A., et al., 2006, The Pliocene Paradox (Mechanisms for a permanent El Nino), Science, 312, 1437-1443. [4] Rickaby, R. and Halloran, P., 2005, Cool La Nina during the warmth of the Pliocene?, Science, 307, 1948-1953. [5] Wara, M., et al. ,2005, Permanent El Nino-like conditions during the Pliocene Warm Period, Science, 309, 758-761. [6] Ghosh, P., et al., 2006, 13C-18O bonds in carbonate minerals: A new kind of paleothermometer, GCA, 70, 1439-1456. [7] Eiler, J. and Tripati, A., 2007, 'Clumped isotope' thermometry in benthic foraminifera and ostracods: A novel tool for reconstructing deep-ocean temperatures. Fall AGU. [8] Tripati, A., et al. 2007, 'Carbonate `clumped isotope' thermometry in planktonic foraminifera and coccoliths. Fall AGU.
Odéen, Henrik; Todd, Nick; Diakite, Mahamadou; Minalga, Emilee; Payne, Allison; Parker, Dennis L.
2014-01-01
Purpose: To investigate k-space subsampling strategies to achieve fast, large field-of-view (FOV) temperature monitoring using segmented echo planar imaging (EPI) proton resonance frequency shift thermometry for MR guided high intensity focused ultrasound (MRgHIFU) applications. Methods: Five different k-space sampling approaches were investigated, varying sample spacing (equally vs nonequally spaced within the echo train), sampling density (variable sampling density in zero, one, and two dimensions), and utilizing sequential or centric sampling. Three of the schemes utilized sequential sampling with the sampling density varied in zero, one, and two dimensions, to investigate sampling the k-space center more frequently. Two of the schemes utilized centric sampling to acquire the k-space center with a longer echo time for improved phase measurements, and vary the sampling density in zero and two dimensions, respectively. Phantom experiments and a theoretical point spread function analysis were performed to investigate their performance. Variable density sampling in zero and two dimensions was also implemented in a non-EPI GRE pulse sequence for comparison. All subsampled data were reconstructed with a previously described temporally constrained reconstruction (TCR) algorithm. Results: The accuracy of each sampling strategy in measuring the temperature rise in the HIFU focal spot was measured in terms of the root-mean-square-error (RMSE) compared to fully sampled “truth.” For the schemes utilizing sequential sampling, the accuracy was found to improve with the dimensionality of the variable density sampling, giving values of 0.65 °C, 0.49 °C, and 0.35 °C for density variation in zero, one, and two dimensions, respectively. The schemes utilizing centric sampling were found to underestimate the temperature rise, with RMSE values of 1.05 °C and 1.31 °C, for variable density sampling in zero and two dimensions, respectively. Similar subsampling schemes
Kocken, I.; Ziegler, M.
2017-12-01
Clumped isotope measurements on carbonates are a quickly developing and promising palaeothermometry proxy1-3. Developments in the field have brought down the necessary sample amount and improved the precision and accuracy of the measurements. The developments have included inter-laboratory comparison and the introduction of an absolute reference frame4, determination of acid fractionation effects5, correction for the pressure baseline6, as well as improved temperature calibrations2, and most recently new approaches to improve efficiency in terms of sample gas usage7. However, a large-scale application of clumped isotope thermometry is still hampered by required large sample amounts, but also the time-consuming analysis. In general, a lot of time is goes into the measurement of standards. Here we present a study on the optimal ratio between standard- and sample measurements using the Kiel Carbonate Device method. We also consider the optimal initial signal intensity. We analyse ETH-standard measurements from several months to determine the measurement regime with the highest precision and optimised measurement time management.References 1. Eiler, J. M. Earth Planet. Sci. Lett. 262, 309-327 (2007).2. Kelson, J. R., et al. Geochim. Cosmochim. Acta 197, 104-131 (2017).3. Kele, S. et al. Geochim. Cosmochim. Acta 168, 172-192 (2015).4. Dennis, K. J. et al. Geochim. Cosmochim. Acta 75, 7117-7131 (2011).5. Müller, I. A. et al. Chem. Geol. 449, 1-14 (2017).6. Meckler, A. N. et al. Rapid Commun. Mass Spectrom. 28, 1705-1715 (2014).7. Hu, B. et al. Rapid Commun. Mass Spectrom. 28, 1413-1425 (2014).
International Nuclear Information System (INIS)
Stacey, Frank D
2010-01-01
Applications of elementary thermodynamic principles to the dynamics of the Earth lead to robust, quantitative conclusions about the tectonic effects that arise from convection. The grand pattern of motion conveys deep heat to the surface, generating mechanical energy with a thermodynamic efficiency corresponding to that of a Carnot engine operating over the adiabatic temperature gradient between the heat source and sink. Referred to the total heat flux derived from the Earth's silicate mantle, the efficiency is 24% and the power generated, 7.7 x 10 12 W, causes all the material deformation apparent as plate tectonics and the consequent geological processes. About 3.5% of this is released in seismic zones but little more than 0.2% as seismic waves. Even major earthquakes are only localized hiccups in this motion. Complications that arise from mineral phase transitions can be used to illuminate details of the motion. There are two superimposed patterns of convection, plate subduction and deep mantle plumes, driven by sources of buoyancy, negative and positive respectively, at the top and bottom of the mantle. The patterns of motion are controlled by the viscosity contrasts (>10 4 : 1) at these boundaries and are self-selected as the least dissipative mechanisms of heat transfer for convection in a body with very strong viscosity variation. Both are subjects of the thermodynamic efficiency argument. Convection also drives the motion in the fluid outer core that generates the geomagnetic field, although in that case there is an important energy contribution by compositional separation, as light solute is rejected by the solidifying inner core and mixed into the outer core, a process referred to as compositional convection. Uncertainty persists over the core energy balance because thermal conduction is a drain on core energy that has been a subject of diverse estimates, with attendant debate over the need for radiogenic heat in the core. The geophysical approach to
Fundamental functions in equilibrium thermodynamics
Horst, H.J. ter
In the standard presentations of the principles of Gibbsian equilibrium thermodynamics one can find several gaps in the logic. For a subject that is as widely used as equilibrium thermodynamics, it is of interest to clear up such questions of mathematical rigor. In this paper it is shown that using
Thermodynamics of negative absolute pressures
International Nuclear Information System (INIS)
Lukacs, B.; Martinas, K.
1984-03-01
The authors show that the possibility of negative absolute pressure can be incorporated into the axiomatic thermodynamics, analogously to the negative absolute temperature. There are examples for such systems (GUT, QCD) processing negative absolute pressure in such domains where it can be expected from thermodynamical considerations. (author)
Thermodynamic study of selected monoterpenes
Czech Academy of Sciences Publication Activity Database
Štejfa, V.; Fulem, Michal; Růžička, K.; Červinka, C.; Rocha, M.A.A.; Santos, L.M.N.B.F.; Schröder, B.
2013-01-01
Roč. 60, MAY (2013), 117-125 ISSN 0021-9614 Institutional support: RVO:68378271 Keywords : monoterpenes * pinene * vapor pressure * heat capacity * vaporization and sublimation enthalpy * ideal - gas thermodynamic Subject RIV: BJ - Thermodynamics Impact factor: 2.423, year: 2013
Thermodynamic optimization of power plants
Haseli, Y.
2011-01-01
Thermodynamic Optimization of Power Plants aims to establish and illustrate comparative multi-criteria optimization of various models and configurations of power plants. It intends to show what optimization objectives one may define on the basis of the thermodynamic laws, and how they can be applied
Ch. 33 Modeling: Computational Thermodynamics
International Nuclear Information System (INIS)
Besmann, Theodore M.
2012-01-01
This chapter considers methods and techniques for computational modeling for nuclear materials with a focus on fuels. The basic concepts for chemical thermodynamics are described and various current models for complex crystalline and liquid phases are illustrated. Also included are descriptions of available databases for use in chemical thermodynamic studies and commercial codes for performing complex equilibrium calculations.
Thermodynamics of urban population flows.
Hernando, A; Plastino, A
2012-12-01
Orderliness, reflected via mathematical laws, is encountered in different frameworks involving social groups. Here we show that a thermodynamics can be constructed that macroscopically describes urban population flows. Microscopic dynamic equations and simulations with random walkers underlie the macroscopic approach. Our results might be regarded, via suitable analogies, as a step towards building an explicit social thermodynamics.
Thermodynamics from Car to Kitchen
Auty, Geoff
2014-01-01
The historical background to the laws of thermodynamics is explained using examples we can all observe in the world around us, focusing on motorised transport, refrigeration and solar heating. This is not to be considered as an academic article. The purpose is to improve understanding of thermodynamics rather than impart new knowledge, and for…
Applied thermodynamics: A new frontier for biotechnology
DEFF Research Database (Denmark)
Mollerup, Jørgen
2006-01-01
The scientific career of one of the most outstanding scientists in molecular thermodynamics, Professor John M. Prausnitz at Berkeley, reflects the change in the agenda of molecular thermodynamics, from hydrocarbon chemistry to biotechnology. To make thermodynamics a frontier for biotechnology...
Energy Technology Data Exchange (ETDEWEB)
Vient, E
2006-12-15
This work deals with the calorimetry and thermometry of hot nuclei produced in collisions Xe + Sn between 25 and 100 MeV/u. The apparatus for hot nucleus physical characterization is the 4{pi} detector array Indra. This study was made by using the event generators Gemini, Simon and Hipse and a data-processing filter simulating the complete operation of the multi-detector. The first chapter presents the different ways of producing hot nuclei. In the second and third chapters, the author presents a critical methodological study of calorimetry and thermometry applied to hot nuclei, different methods are reviewed, their accuracy and application range are assessed. All the calorimetry methods rely on the assumption that we are able to discriminate decay products of the hot nucleus from evaporated particles. In the fourth chapter, the author gives some ways of improving calorimetry characterization of the hot nucleus. An alternative method of calorimetry is proposed in the fifth chapter, this method is based on the experimental determination of an evaporation probability that is deduced from the physical characteristics of the particles present in a restricted domain of the space of velocities.
Thermodynamics in Loop Quantum Cosmology
International Nuclear Information System (INIS)
Li, L.F.; Zhu, J.Y.
2009-01-01
Loop quantum cosmology (LQC) is very powerful to deal with the behavior of early universe. Moreover, the effective loop quantum cosmology gives a successful description of the universe in the semiclassical region. We consider the apparent horizon of the Friedmann-Robertson-Walker universe as a thermodynamical system and investigate the thermodynamics of LQC in the semiclassical region. The effective density and effective pressure in the modified Friedmann equation from LQC not only determine the evolution of the universe in LQC scenario but also are actually found to be the thermodynamic quantities. This result comes from the energy definition in cosmology (the Misner-Sharp gravitational energy) and is consistent with thermodynamic laws. We prove that within the framework of loop quantum cosmology, the elementary equation of equilibrium thermodynamics is still valid.
Thermodynamic properties of cryogenic fluids
Leachman, Jacob; Lemmon, Eric; Penoncello, Steven
2017-01-01
This update to a classic reference text provides practising engineers and scientists with accurate thermophysical property data for cryogenic fluids. The equations for fifteen important cryogenic fluids are presented in a basic format, accompanied by pressure-enthalpy and temperature-entropy charts and tables of thermodynamic properties. It begins with a chapter introducing the thermodynamic relations and functional forms for equations of state, and goes on to describe the requirements for thermodynamic property formulations, needed for the complete definition of the thermodynamic properties of a fluid. The core of the book comprises extensive data tables and charts for the most commonly-encountered cryogenic fluids. This new edition sees significant updates to the data presented for air, argon, carbon monoxide, deuterium, ethane, helium, hydrogen, krypton, nitrogen and xenon. The book supports and complements NIST’s REFPROP - an interactive database and tool for the calculation of thermodynamic propertie...
Applied statistical thermodynamics
Lucas, Klaus
1991-01-01
The book guides the reader from the foundations of statisti- cal thermodynamics including the theory of intermolecular forces to modern computer-aided applications in chemical en- gineering and physical chemistry. The approach is new. The foundations of quantum and statistical mechanics are presen- ted in a simple way and their applications to the prediction of fluid phase behavior of real systems are demonstrated. A particular effort is made to introduce the reader to expli- cit formulations of intermolecular interaction models and to show how these models influence the properties of fluid sy- stems. The established methods of statistical mechanics - computer simulation, perturbation theory, and numerical in- tegration - are discussed in a style appropriate for newcom- ers and are extensively applied. Numerous worked examples illustrate how practical calculations should be carried out.
Thermodynamic properties of vanadium
International Nuclear Information System (INIS)
Desai, P.D.
1986-01-01
This work reviews and discusses the data and information on the various thermodynamic properties of vanadium available through March 1985. These include the heat capacity and enthalpy, enthalpy of melting, vapor pressure, and enthalpy of vaporization. The existing data have been critically evaluated and analyzed, and the recommended values for heat capacity, enthalpy, entropy, and Gibbs energy function covering the temperature range from 1 to 3800 K have been generated. These values are referred to tempertures based on IPTS-1968. The units used for various properties are joules per mole (J. mol - 1 ). The estimated uncertainties in the heat capacity are +/-3% below 15 K, +/-10% from 15 to 150 K, +/-3% from 150 to 298.15 K, +/-2% from 298.15 to 1000 K, +/-3% from 1000 to the melting point (2202 K), and +/-5% in the liquid region
Thermodynamics and energy conversion
Struchtrup, Henning
2014-01-01
This textbook gives a thorough treatment of engineering thermodynamics with applications to classical and modern energy conversion devices. Some emphasis lies on the description of irreversible processes, such as friction, heat transfer and mixing, and the evaluation of the related work losses. Better use of resources requires high efficiencies, therefore the reduction of irreversible losses should be seen as one of the main goals of a thermal engineer. This book provides the necessary tools. Topics include: car and aircraft engines, including Otto, Diesel and Atkinson cycles, by-pass turbofan engines, ramjet and scramjet; steam and gas power plants, including advanced regenerative systems, solar tower, and compressed air energy storage; mixing and separation, including reverse osmosis, osmotic powerplants, and carbon sequestration; phase equilibrium and chemical equilibrium, distillation, chemical reactors, combustion processes, and fuel cells; the microscopic definition of entropy. The book i...
Cosmological event horizons, thermodynamics, and particle creation
International Nuclear Information System (INIS)
Gibbons, G.W.; Hawking, S.W.
1977-01-01
It is shown that the close connection between event horizons and thermodynamics which has been found in the case of black holes can be extended to cosmological models with a repulsive cosmological constant. An observer in these models will have an event horizon whose area can be interpreted as the entropy or lack of information of the observer about the regions which he cannot see. Associated with the event horizon is a surface gravity kappa which enters a classical ''first law of event horizons'' in a manner similar to that in which temperature occurs in the first law of thermodynamics. It is shown that this similarity is more than an analogy: An observer with a particle detector will indeed observe a background of thermal radiation coming apparently from the cosmological event horizon. If the observer absorbs some of this radiation, he will gain energy and entropy at the expense of the region beyond his ken and the event horizon will shrink. The derivation of these results involves abandoning the idea that particles should be defined in an observer-independent manner. They also suggest that one has to use something like the Everett-Wheeler interpretation of quantum mechanics because the back reaction and hence the spacetime metric itself appear to be observer-dependent, if one assumes, as seems reasonable, that the detection of a particle is accompanied by a change in the gravitational field
Thermodynamics of Fluid Polyamorphism
Directory of Open Access Journals (Sweden)
Mikhail A. Anisimov
2018-01-01
Full Text Available Fluid polyamorphism is the existence of different condensed amorphous states in a single-component fluid. It is either found or predicted, usually at extreme conditions, for a broad group of very different substances, including helium, carbon, silicon, phosphorous, sulfur, tellurium, cerium, hydrogen, and tin tetraiodide. This phenomenon is also hypothesized for metastable and deeply supercooled water, presumably located a few degrees below the experimental limit of homogeneous ice formation. We present a generic phenomenological approach to describe polyamorphism in a single-component fluid, which is completely independent of the molecular origin of the phenomenon. We show that fluid polyamorphism may occur either in the presence or in the absence of fluid phase separation depending on the symmetry of the order parameter. In the latter case, it is associated with a second-order transition, such as in liquid helium or liquid sulfur. To specify the phenomenology, we consider a fluid with thermodynamic equilibrium between two distinct interconvertible states or molecular structures. A fundamental signature of this concept is the identification of the equilibrium fraction of molecules involved in each of these alternative states. However, the existence of the alternative structures may result in polyamorphic fluid phase separation only if mixing of these structures is not ideal. The two-state thermodynamics unifies all the debated scenarios of fluid polyamorphism in different areas of condensed-matter physics, with or without phase separation, and even goes beyond the phenomenon of polyamorphism by generically describing the anomalous properties of fluids exhibiting interconversion of alternative molecular states.
New astrophysical school of thermodynamics. Space dynamics and gravitism
Energy Technology Data Exchange (ETDEWEB)
Gal-Or, B [Technion-Israel Inst. of Tech., Haifa. Dept. of Aeronautical Engineering
1978-07-01
Much verified information has been accumulated in recent years which shows that many fundamental concepts involving classical physics, thermodynamics, astrophysics and the general theory of relativity are strongly coupled together. This evidence is employed in this paper to explain principles of the astrophysical school of thermodynamics; a growing revolutionary school which deduces thermodynamics, energy dissipation, and time anisotropies from the Newtonian and Einsteinian theories of gravitation and from the dynamics of radiation in 'unsaturable' (intercluster) space. Accordingly, the density of radiation and the dynamics of ('unsaturable') outer space affect all processes in the galactic media, in the solar system, in the magnetosphere and on Earth. The origin of all observed irreversibilities in nature - of time, of all time anisotropics, of energy dissipation, of T-violations in 'elementary particles', of retarded potentials in electrodynamics, of the biological clocks, and of biological arrows of time - is one; it is the radiation unsaturability of space. But, since this unsaturability and gravitation are interconnected, the origin of asymmetries, structure, and thermodynamics is explained within the framework of the Newtonian and Einsteinian theories of gravitation. The theory presented here forms a part of a general approach called gravitism, which unifies some other disciplinary studies in the natural sciences with a unified approach to gravitation and the theory of time.
Thermodynamics of string black hole with hyperscaling violation
International Nuclear Information System (INIS)
Sadeghi, J.; Pourhassan, B.; Asadi, A.
2014-01-01
In this paper, we start with a black brane and construct a specific space-time which violates hyperscaling. To obtain the string solution, we apply the Null-Melvin Twist and KK reduction. Using the difference action method, we study the thermodynamics of the system to obtain a Hawking-Page phase transition. To have hyperscaling violation, we need to consider θ = (d)/(2). In this case, the free energy F is always negative and our solution is thermal radiation without a black hole. Therefore, we find that there is no Hawking-Page transition. Also, we discuss the stability of the system and all thermodynamical quantities. (orig.)
Quantum thermodynamic cycles and quantum heat engines. II.
Quan, H T
2009-04-01
We study the quantum-mechanical generalization of force or pressure, and then we extend the classical thermodynamic isobaric process to quantum-mechanical systems. Based on these efforts, we are able to study the quantum version of thermodynamic cycles that consist of quantum isobaric processes, such as the quantum Brayton cycle and quantum Diesel cycle. We also consider the implementation of the quantum Brayton cycle and quantum Diesel cycle with some model systems, such as single particle in a one-dimensional box and single-mode radiation field in a cavity. These studies lay the microscopic (quantum-mechanical) foundation for Szilard-Zurek single-molecule engine.
Development of a thermodynamic data base for selected heavy metals
International Nuclear Information System (INIS)
Hageman, Sven; Scharge, Tina; Willms, Thomas
2015-07-01
The report on the development of a thermodynamic data base for selected heavy metals covers the description of experimental methods, the thermodynamic model for chromate, the thermodynamic model for dichromate, the thermodynamic model for manganese (II), the thermodynamic model for cobalt, the thermodynamic model for nickel, the thermodynamic model for copper (I), the thermodynamic model for copper(II), the thermodynamic model for mercury (0) and mercury (I), the thermodynamic model for mercury (III), the thermodynamic model for arsenate.
Kim, Daehee; Kim, Hanul; Yun, Wan Soo; Watanabe, Kenji; Taniguchi, Takashi; Rho, Heesuk; Bae, Myung-Ho
2018-04-01
Understanding the energy transport by charge carriers and phonons in two-dimensional (2D) van der Waals heterostructures is essential for the development of future energy-efficient 2D nanoelectronics. Here, we performed in situ spatially resolved Raman thermometry on an electrically biased graphene channel and its hBN substrate to study the energy dissipation mechanism in graphene/hBN heterostructures. By comparing the temperature profile along the biased graphene channel with that along the hBN substrate, we found that the thermal boundary resistance between the graphene and hBN was in the range of (1-2) ~ × 10-7 m2 K W-1 from ~100 °C to the onset of graphene break-down at ~600 °C in air. Consideration of an electro-thermal transport model together with the Raman thermometry conducted in air showed that a doping effect occurred under a strong electric field played a crucial role in the energy dissipation of the graphene/hBN device up to T ~ 600 °C.
All Fiber-Coupled OH Planar Laser-Induced-Fluorescence (OH-PLIF)-Based Two-Dimensional Thermometry.
Hsu, Paul S; Jiang, Naibo; Patnaik, Anil K; Katta, Vish; Roy, Sukesh; Gord, James R
2018-04-01
Two-color, planar laser-induced fluorescence (PLIF)-based two-dimensional (2D) thermometry techniques for reacting flows, which are typically developed in the laboratory conditions, face a stiff challenge in their practical implementation in harsh environments such as combustion rigs. In addition to limited optical access, the critical experimental conditions (i.e., uncontrolled humidity, vibration, and large thermal gradients) often restrict sensitive laser system operation and cause difficulties maintaining beam-overlap. Thus, an all fiber-coupled, two-color OH-PLIF system has been developed, employing two long optical fibers allowing isolation of the laser and signal-collection systems. Two OH-excitation laser beams (∼283 nm and ∼286 nm) are delivered through a common 6 m long, 400 µm core, deep ultraviolet (UV)-enhanced multimode fiber. The fluorescence signal (∼310 nm) is collected by a 3 m long, UV-grade imaging fiber. Proof-of-principle temperature measurements are demonstrated in atmospheric pressure, near adiabatic, CH 4 /O 2 /N 2 jet flames. The effects of the excitation pulse interval on fiber transmission are investigated. The proof-of-principle measurements show significant promise for thermometry in harsh environments such as gas turbine engine tests.
International Nuclear Information System (INIS)
Ohwada, Hiroshi; Ishihara, Yasutoshi
2010-01-01
To improve the efficacy of hyperthermia treatment, a novel method of noninvasive measurement of body temperature change is proposed. The proposed technology, thermometry, is based on changes in the electromagnetic field distribution inside the heating applicator with temperature changes and the temperature dependence of the dielectric constant. In addition, an image of the temperature change distribution inside a body is reconstructed by applying a computed tomography (CT) algorithm. The proposed thermometry method can serve as a possible noninvasive method to monitor the temperature change distribution inside the body without the use of enormous thermometers such as in the case of magnetic resonance imaging (MRI). Furthermore, this temperature monitoring method can be easily combined with a heating applicator based on a cavity resonator, and the novel integrated treatment system can possibly be used to treat cancer effectively while noninvasively monitoring the heating effect. In this paper, the phase change distributions of the electromagnetic field with temperature changes are simulated by numerical analysis using the finite difference time domain (FDTD) method. Moreover, to estimate the phase change distributions inside a target body, the phase change distributions with temperature changes are reconstructed by a filtered back-projection. In addition, the reconstruction accuracy of the converted temperature change distribution from the phase change is evaluated. (author)
Life, hierarchy, and the thermodynamic machinery of planet Earth.
Kleidon, Axel
2010-12-01
Throughout Earth's history, life has increased greatly in abundance, complexity, and diversity. At the same time, it has substantially altered the Earth's environment, evolving some of its variables to states further and further away from thermodynamic equilibrium. For instance, concentrations in atmospheric oxygen have increased throughout Earth's history, resulting in an increased chemical disequilibrium in the atmosphere as well as an increased redox gradient between the atmosphere and the Earth's reducing crust. These trends seem to contradict the second law of thermodynamics, which states for isolated systems that gradients and free energy are dissipated over time, resulting in a state of thermodynamic equilibrium. This seeming contradiction is resolved by considering planet Earth as a coupled, hierarchical and evolving non-equilibrium thermodynamic system that has been substantially altered by the input of free energy generated by photosynthetic life. Here, I present this hierarchical thermodynamic theory of the Earth system. I first present simple considerations to show that thermodynamic variables are driven away from a state of thermodynamic equilibrium by the transfer of power from some other process and that the resulting state of disequilibrium reflects the past net work done on the variable. This is applied to the processes of planet Earth to characterize the generation and transfer of free energy and its dissipation, from radiative gradients to temperature and chemical potential gradients that result in chemical, kinetic, and potential free energy and associated dynamics of the climate system and geochemical cycles. The maximization of power transfer among the processes within this hierarchy yields thermodynamic efficiencies much lower than the Carnot efficiency of equilibrium thermodynamics and is closely related to the proposed principle of Maximum Entropy Production (MEP). The role of life is then discussed as a photochemical process that generates
Energy Technology Data Exchange (ETDEWEB)
Britton Jr, Charles L. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
2015-09-14
This memorandum constitutes our September 2015 level 4 milestone for the project entitled “Johnson Noise Thermometry for Drift-free Temperature Measurements” and satisfies the Milestone/Activity (Conclude HFIR field demonstration of JNT prototype). The progress summary describes the work performed to complete the subject milestone.
Lam, Mie K; Huisman, Merel; Nijenhuis, Robbert J; van den Bosch, Maurice; Viergever, Max A; Moonen, Chrit Tw; Bartels, LW
2015-01-01
BACKGROUND: Magnetic resonance (MR)-guided high-intensity focused ultrasound has emerged as a clinical option for palliative treatment of painful bone metastases, with MR thermometry (MRT) used for treatment monitoring. In this study, the general image quality of the MRT was assessed in terms of
Statistical Thermodynamics of Disperse Systems
DEFF Research Database (Denmark)
Shapiro, Alexander
1996-01-01
Principles of statistical physics are applied for the description of thermodynamic equilibrium in disperse systems. The cells of disperse systems are shown to possess a number of non-standard thermodynamic parameters. A random distribution of these parameters in the system is determined....... On the basis of this distribution, it is established that the disperse system has an additional degree of freedom called the macro-entropy. A large set of bounded ideal disperse systems allows exact evaluation of thermodynamic characteristics. The theory developed is applied to the description of equilibrium...
Thermodynamic light on black holes
International Nuclear Information System (INIS)
Davies, P.
1977-01-01
The existence of black holes and their relevance to our understanding of the nature of space and time are considered, with especial reference to the application of thermodynamic arguments which can reveal their energy-transfer processes in a new light. The application of thermodynamics to strongly gravitating systems promises some fascinating new insights into the nature of gravity. Situations can occur during gravitational collapse in which existing physics breaks down. Under these circumstances, the application of universal thermodynamical principles might be our only guide. (U.K.)
Thermodynamic metrics and optimal paths.
Sivak, David A; Crooks, Gavin E
2012-05-11
A fundamental problem in modern thermodynamics is how a molecular-scale machine performs useful work, while operating away from thermal equilibrium without excessive dissipation. To this end, we derive a friction tensor that induces a Riemannian manifold on the space of thermodynamic states. Within the linear-response regime, this metric structure controls the dissipation of finite-time transformations, and bestows optimal protocols with many useful properties. We discuss the connection to the existing thermodynamic length formalism, and demonstrate the utility of this metric by solving for optimal control parameter protocols in a simple nonequilibrium model.
Some aspects of plasma thermodynamics
International Nuclear Information System (INIS)
Gorgoraki, V.I.
1986-01-01
The objective reasons which have inhibited the development of a plasma-thermodynamics theory are discussed and the authors formulate the fundamental principles which can be the basis of a common plasma-thermodynamics theory. Two kinds of thermodynamic equilibrium plasmas are discussed, an isothermal plasma and a nonisothermal plasma. An isothermal plasma is a high-temperature plasma; the Saha-Eggert equation describes its behavior. A nonisothermal plasma is a low-temperature plasma, and the reactions taking place therein are purely plasma-chemical. The ionization equilibrium and the composition of such a plasma can be found with the aid of the equations presented in this paper
Practical chemical thermodynamics for geoscientists
Fegley, Bruce, Jr
2012-01-01
Practical Chemical Thermodynamics for Geoscientists covers classical chemical thermodynamics and focuses on applications to practical problems in the geosciences, environmental sciences, and planetary sciences. This book will provide a strong theoretical foundation for students, while also proving beneficial for earth and planetary scientists seeking a review of thermodynamic principles and their application to a specific problem. Strong theoretical foundation and emphasis on applications Numerous worked examples in each chapter Brief historical summaries and biographies of key thermodynamicists-including their fundamental research and discoveries Extensive references to relevant literature.
Thermodynamic analysis of biochemical systems
International Nuclear Information System (INIS)
Yuan, Y.; Fan, L.T.; Shieh, J.H.
1989-01-01
Introduction of the concepts of the availability (or exergy), datum level materials, and the dead state has been regarded as some of the most significant recent developments in classical thermodynamics. Not only the available energy balance but also the material and energy balances of a biological system may be established in reference to the datum level materials in the dead state or environment. In this paper these concepts are illustrated with two examples of fermentation and are shown to be useful in identifying sources of thermodynamic inefficiency, thereby leading naturally to the rational definition of thermodynamic efficiency of a biochemical process
Thermodynamic phase transition of a black hole in rainbow gravity
Directory of Open Access Journals (Sweden)
Zhong-Wen Feng
2017-09-01
Full Text Available In this letter, using the rainbow functions that were proposed by Magueijo and Smolin, we investigate the thermodynamics and the phase transition of rainbow Schwarzschild black hole. First, we calculate the rainbow gravity corrected Hawking temperature. From this modification, we then derive the local temperature, free energy, and other thermodynamic quantities in an isothermal cavity. Finally, we analyze the critical behavior, thermodynamic stability, and phase transition of the rainbow Schwarzschild black hole. The results show that the rainbow gravity can stop the Hawking radiation in the final stages of black holes' evolution and lead to the remnants of black holes. Furthermore, one can observe that the rainbow Schwarzschild black hole has one first-order phase transition, two second-order phase transitions, and three Hawking–Page-type phase transitions in the framework of rainbow gravity theory.
Development of a quantum dot mediated thermometry for minimally invasive thermal therapy
Hanson, Willard L.
Thermally-related, minimally invasive therapies are designed to treat tumors while minimizing damage to the surrounding tissues. Adjacent tissues become susceptible to thermal injury to ensure the cancer is completely destroyed. Destroying tumor cells, while minimizing collateral damage to the surrounding tissue, requires the capacity to control and monitor tissue temperatures both spatially and temporally. Current devices measure the tumor's tissue temperature at a specific location leaving the majority unmonitored. A point-wise application can not substantiate complete tumor destruction. This type of surgery would be more effective if volumetric tissue temperature measurement were available. On this premise, the feasibility of a quantum dot (QD) assembly to measure the tissue temperature volumetrically was tested in the experiments described in this dissertation. QDs are fluorescence semiconductor nanoparticles having various superior optical properties. This new QD-mediated thermometry is capable of monitoring the thermal features of tissues non-invasively by measuring the aggregate fluorescence intensity of the QDs accumulated at the target tissues prior to and during the surgical procedure. Thus, such a modality would allow evaluation of tissue destruction by measuring the fluorescence intensity of the QD as a function of temperature. The present study also quantified the photoluminescence intensity and attenuation of the QD as a function of depth and wavelength using a tissue phantom. A prototype system was developed to measure the illumination through a tissue phantom as a proof of concept of the feasibility of a noninvasive thermal therapy. This prototype includes experimental hardware, software and working methods to perform image acquisition, and data reduction strategic to quantify the intensity and transport characteristics of the QD. The significance of this work is that real-time volumetric temperature information will prove a more robust tool for use
A method for atomic-level noncontact thermometry with electron energy distribution
Kinoshita, Ikuo; Tsukada, Chiharu; Ouchi, Kohei; Kobayashi, Eiichi; Ishii, Juntaro
2017-04-01
We devised a new method of determining the temperatures of materials with their electron-energy distributions. The Fermi-Dirac distribution convoluted with a linear combination of Gaussian and Lorentzian distributions was fitted to the photoelectron spectrum measured for the Au(110) single-crystal surface at liquid N2-cooled temperature. The fitting successfully determined the surface-local thermodynamic temperature and the energy resolution simultaneously from the photoelectron spectrum, without any preliminary results of other measurements. The determined thermodynamic temperature was 99 ± 2.1 K, which was in good agreement with the reference temperature of 98.5 ± 0.5 K measured using a silicon diode sensor attached to the sample holder.
Thermodynamical string fragmentation
Energy Technology Data Exchange (ETDEWEB)
Fischer, Nadine [Theoretical Particle Physics, Department of Astronomy and Theoretical Physics, Lund University,Sölvegatan 14A, Lund, SE-223 62 (Sweden); School of Physics and Astronomy, Monash University,Wellington Road, Clayton, VIC-3800 (Australia); Sjöstrand, Torbjörn [Theoretical Particle Physics, Department of Astronomy and Theoretical Physics, Lund University,Sölvegatan 14A, Lund, SE-223 62 (Sweden)
2017-01-31
The observation of heavy-ion-like behaviour in pp collisions at the LHC suggests that more physics mechanisms are at play than traditionally assumed. The introduction e.g. of quark-gluon plasma or colour rope formation can describe several of the observations, but as of yet there is no established paradigm. In this article we study a few possible modifications to the Pythia event generator, which describes a wealth of data but fails for a number of recent observations. Firstly, we present a new model for generating the transverse momentum of hadrons during the string fragmentation process, inspired by thermodynamics, where heavier hadrons naturally are suppressed in rate but obtain a higher average transverse momentum. Secondly, close-packing of strings is taken into account by making the temperature or string tension environment-dependent. Thirdly, a simple model for hadron rescattering is added. The effect of these modifications is studied, individually and taken together, and compared with data mainly from the LHC. While some improvements can be noted, it turns out to be nontrivial to obtain effects as big as required, and further work is called for.
Regularities of radiation heredity
International Nuclear Information System (INIS)
Skakov, M.K.; Melikhov, V.D.
2001-01-01
One analyzed regularities of radiation heredity in metals and alloys. One made conclusion about thermodynamically irreversible changes in structure of materials under irradiation. One offers possible ways of heredity transmittance of radiation effects at high-temperature transformations in the materials. Phenomenon of radiation heredity may be turned to practical use to control structure of liquid metal and, respectively, structure of ingot via preliminary radiation treatment of charge. Concentration microheterogeneities in material defect structure induced by preliminary irradiation represent the genetic factor of radiation heredity [ru
Progress in Primary Acoustic Thermometry at NIST: 273 K to 505 K
Strouse, G. F.; Defibaugh, D. R.; Moldover, M. R.; Ripple, D. C.
2003-09-01
The NIST Acoustic Thermometer determines the thermodynamic temperature by measuring the speed of sound of argon in a spherical cavity. We obtained the thermodynamic temperature of three fixed points on the International Temperature Scale of 1990: the melting point of gallium [T(Ga) = 302.9146 K] and the freezing points of indium [T(In) = 429.7485 K] and tin [T(Sn) = 505.078 K]. The deviations of thermodynamic temperature from the ITS-90 defined temperatures are T - T90 = (4.7 ± 0.6) mK at T(Ga) , T - T90 = (8.8 ± 1.5) mK at T(In) , and T - T90 = (10.7 ± 3.0) mK at T(Sn) , where the uncertainties are for a coverage factor of k = 1. Our results at T(In) and T(Sn) reduce the uncertainty of T - T90 by a factor of two in this range. Both T - T90 at T(Ga) and the measured thermal expansion of the resonator between the triple point of water and T(Ga) are in excellent agreement with the 1992 determination at NIST. The dominant uncertainties in the present data come from frequency-dependent and time-dependent crosstalk between the electroacoustic transducers. We plan to reduce these uncertainties and extend this work to 800 K.
Thermodynamic Calculations for Systems Biocatalysis
DEFF Research Database (Denmark)
Abu, Rohana; Gundersen, Maria T.; Woodley, John M.
2015-01-01
the transamination of a pro-chiral ketone into a chiral amine (interesting in many pharmaceutical applications). Here, the products are often less energetically stable than the reactants, meaning that the reaction may be thermodynamically unfavourable. As in nature, such thermodynamically-challenged reactions can...... on the basis of kinetics. However, many of the most interesting non-natural chemical reactions which could potentially be catalysed by enzymes, are thermodynamically unfavourable and are thus limited by the equilibrium position of the reaction. A good example is the enzyme ω-transaminase, which catalyses...... be altered by coupling with other reactions. For instance, in the case of ω-transaminase, such a coupling could be with alanine dehydrogenase. Herein, the aim of this work is to identify thermodynamic bottlenecks within a multi-enzyme process, using group contribution method to calculate the Gibbs free...
Shock Thermodynamic Applied Research Facility
Federal Laboratory Consortium — The Shock Thermodynamic Applied Research Facility (STAR) facility, within Sandia’s Solid Dynamic Physics Department, is one of a few institutions in the world with a...
Thermodynamic analysis of PBMR plant
International Nuclear Information System (INIS)
Sen, S.; Kadiroglu, O.K.
2002-01-01
The thermodynamic analysis of a PBMR is presented for various pressures and temperatures values. The design parameters of the components of the power plant are calculated and an optimum cycle for the maximum thermal efficiency is sought for. (author)
Thermodynamic efficiency of solar concentrators.
Shatz, Narkis; Bortz, John; Winston, Roland
2010-04-26
The optical thermodynamic efficiency is a comprehensive metric that takes into account all loss mechanisms associated with transferring flux from the source to the target phase space, which may include losses due to inadequate design, non-ideal materials, fabrication errors, and less than maximal concentration. We discuss consequences of Fermat's principle of geometrical optics and review étendue dilution and optical loss mechanisms associated with nonimaging concentrators. We develop an expression for the optical thermodynamic efficiency which combines the first and second laws of thermodynamics. As such, this metric is a gold standard for evaluating the performance of nonimaging concentrators. We provide examples illustrating the use of this new metric for concentrating photovoltaic systems for solar power applications, and in particular show how skewness mismatch limits the attainable optical thermodynamic efficiency.
Thermodynamic origin of nonimaging optics
Jiang, Lun; Winston, Roland
2016-10-01
Nonimaging optics is the theory of thermodynamically efficient optics and as such depends more on thermodynamics than on optics. Hence, in this paper, a condition for the "best" design is proposed based on purely thermodynamic arguments, which we believe has profound consequences for the designs of thermal and even photovoltaic systems. This way of looking at the problem of efficient concentration depends on probabilities, the ingredients of entropy and information theory, while "optics" in the conventional sense recedes into the background. Much of the paper is pedagogical and retrospective. Some of the development of flowline designs will be introduced at the end and the connection between the thermodynamics and flowline design will be graphically presented. We will conclude with some speculative directions of where the ideas might lead.
First principles thermodynamics of alloys
International Nuclear Information System (INIS)
Ducastelle, F.
1993-01-01
We present a brief report on the methods of solid state physics (electronic structure, statistical thermodynamics) that allow us to discuss the phase stability of alloys and to determine their phase diagrams. (orig.)
Thermodynamic approach to biomass gasification
International Nuclear Information System (INIS)
Boissonnet, G.; Seiler, J.M.
2003-01-01
The document presents an approach of biomass transformation in presence of steam, hydrogen or oxygen. Calculation results based on thermodynamic equilibrium are discussed. The objective of gasification techniques is to increase the gas content in CO and H 2 . The maximum content in these gases is obtained when thermodynamic equilibrium is approached. Any optimisation action of a process. will, thus, tend to approach thermodynamic equilibrium conditions. On the other hand, such calculations can be used to determine the conditions which lead to an increase in the production of CO and H 2 . An objective is also to determine transformation enthalpies that are an important input for process calculations. Various existing processes are assessed, and associated thermodynamic limitations are evidenced. (author)
Thermodynamics from concepts to applications
Shavit, Arthur
2008-01-01
The book presents a logical methodology for solving problems in the context of conservation laws and property tables or equations. The authors elucidate the terms around which thermodynamics has historically developed, such as work, heat, temperature, energy, and entropy. Using a pedagogical approach that builds from basic principles to laws and eventually corollaries of the laws, the text enables students to think in clear and correct thermodynamic terms as well as solve real engineering problems.
Generalization of Gibbs Entropy and Thermodynamic Relation
Park, Jun Chul
2010-01-01
In this paper, we extend Gibbs's approach of quasi-equilibrium thermodynamic processes, and calculate the microscopic expression of entropy for general non-equilibrium thermodynamic processes. Also, we analyze the formal structure of thermodynamic relation in non-equilibrium thermodynamic processes.
Thermodynamic implications of the gravitationally induced particle creation scenario
Energy Technology Data Exchange (ETDEWEB)
Saha, Subhajit [Indian Institute of Science Education and Research Kolkata, Department of Physical Sciences, Mohanpur, West Bengal (India); Mondal, Anindita [S N Bose National Centre for Basic Sciences, Department of Astrophysics and Cosmology, Kolkata, West Bengal (India)
2017-03-15
A rigorous thermodynamic analysis has been done as regards the apparent horizon of a spatially flat Friedmann-Lemaitre-Robertson-Walker universe for the gravitationally induced particle creation scenario with constant specific entropy and an arbitrary particle creation rate Γ. Assuming a perfect fluid equation of state p = (γ - 1)ρ with (2)/(3) ≤ γ ≤ 2, the first law, the generalized second law (GSL), and thermodynamic equilibrium have been studied, and an expression for the total entropy (i.e., horizon entropy plus fluid entropy) has been obtained which does not contain Γ explicitly. Moreover, a lower bound for the fluid temperature T{sub f} has also been found which is given by T{sub f} ≥ 8 (((3γ)/(2)-1)/((2)/(γ)-1)) H{sup 2}. It has been shown that the GSL is satisfied for (Γ)/(3H) ≤ 1. Further, when Γ is constant, thermodynamic equilibrium is always possible for (1)/(2) < (Γ)/(3H) < 1, while for (Γ)/(3H) ≤ min {(1)/(2), (2γ-2)/(3γ-2)} and (Γ)/(3H) ≥ 1, equilibrium can never be attained. Thermodynamic arguments also lead us to believe that during the radiation phase, Γ ≤ H. When Γ is not a constant, thermodynamic equilibrium holds if H ≥ (27)/(4) γ{sup 2}H{sup 3} (1-(Γ)/(3H)){sup 2}, however, such a condition is by no means necessary for the attainment of equilibrium. (orig.)
Geometro-thermodynamics of tidal charged black holes
International Nuclear Information System (INIS)
Gergely, Laszlo Arpad; Pidokrajt, Narit; Winitzki, Sergei
2011-01-01
Tidal charged spherically symmetric vacuum brane black holes are characterized by their mass m and tidal charge q, an imprint of the five-dimensional Weyl curvature. For q>0 they are formally identical to the Reissner-Nordstroem black hole of general relativity. We study the thermodynamics and thermodynamic geometries of tidal charged black holes and discuss similarities and differences as compared to the Reissner-Nordstroe m black hole. As a similarity, we show that (for q>0) the heat capacity of the tidal charged black hole diverges on a set of measure zero of the parameter space, nevertheless both the regularity of the Ruppeiner metric and a Poincare stability analysis show no phase transition at those points. The thermodynamic state spaces being different indicates that the underlying statistical models could be different. We find that the q<0 parameter range, which enhances the localization of gravity on the brane, is thermodynamically preferred. Finally we constrain for the first time the possible range of the tidal charge from the thermodynamic limit on gravitational radiation efficiency at black hole mergers. (orig.)
Thermodynamic implications of the gravitationally induced particle creation scenario
International Nuclear Information System (INIS)
Saha, Subhajit; Mondal, Anindita
2017-01-01
A rigorous thermodynamic analysis has been done as regards the apparent horizon of a spatially flat Friedmann-Lemaitre-Robertson-Walker universe for the gravitationally induced particle creation scenario with constant specific entropy and an arbitrary particle creation rate Γ. Assuming a perfect fluid equation of state p = (γ - 1)ρ with (2)/(3) ≤ γ ≤ 2, the first law, the generalized second law (GSL), and thermodynamic equilibrium have been studied, and an expression for the total entropy (i.e., horizon entropy plus fluid entropy) has been obtained which does not contain Γ explicitly. Moreover, a lower bound for the fluid temperature T f has also been found which is given by T f ≥ 8 (((3γ)/(2)-1)/((2)/(γ)-1)) H 2 . It has been shown that the GSL is satisfied for (Γ)/(3H) ≤ 1. Further, when Γ is constant, thermodynamic equilibrium is always possible for (1)/(2) < (Γ)/(3H) < 1, while for (Γ)/(3H) ≤ min {(1)/(2), (2γ-2)/(3γ-2)} and (Γ)/(3H) ≥ 1, equilibrium can never be attained. Thermodynamic arguments also lead us to believe that during the radiation phase, Γ ≤ H. When Γ is not a constant, thermodynamic equilibrium holds if H ≥ (27)/(4) γ 2 H 3 (1-(Γ)/(3H)) 2 , however, such a condition is by no means necessary for the attainment of equilibrium. (orig.)
Thermodynamics of firms' growth
Zambrano, Eduardo; Hernando, Alberto; Hernando, Ricardo; Plastino, Angelo
2015-01-01
The distribution of firms' growth and firms' sizes is a topic under intense scrutiny. In this paper, we show that a thermodynamic model based on the maximum entropy principle, with dynamical prior information, can be constructed that adequately describes the dynamics and distribution of firms' growth. Our theoretical framework is tested against a comprehensive database of Spanish firms, which covers, to a very large extent, Spain's economic activity, with a total of 1 155 142 firms evolving along a full decade. We show that the empirical exponent of Pareto's law, a rule often observed in the rank distribution of large-size firms, is explained by the capacity of economic system for creating/destroying firms, and that can be used to measure the health of a capitalist-based economy. Indeed, our model predicts that when the exponent is larger than 1, creation of firms is favoured; when it is smaller than 1, destruction of firms is favoured instead; and when it equals 1 (matching Zipf's law), the system is in a full macroeconomic equilibrium, entailing ‘free’ creation and/or destruction of firms. For medium and smaller firm sizes, the dynamical regime changes, the whole distribution can no longer be fitted to a single simple analytical form and numerical prediction is required. Our model constitutes the basis for a full predictive framework regarding the economic evolution of an ensemble of firms. Such a structure can be potentially used to develop simulations and test hypothetical scenarios, such as economic crisis or the response to specific policy measures. PMID:26510828
Design of thermodynamic experiments and analyses of thermodynamic relationships
International Nuclear Information System (INIS)
Oezer Arnas, A.
2009-01-01
In teaching of thermodynamics, a certain textbook is followed internationally whatever language it is written in. However, although some do a very good job, most are not correct and precise and furthermore NONE discuss at all the need for and importance of designing thermodynamic experiments although experimentation in engineering is considered to be the back bone of analyses, not pursued much these days, or numerical studies, so very predominant these days. Here some thermodynamic experiments along with physical interpretation of phenomena through simple mathematics will be discussed that are straightforward, meaningful and which can be performed by any undergraduate/graduate student. Another important topic for discussion is the fact that the thermodynamic state principle demands uniqueness of results. It has been found in literature that this fact is not well understood by those who attempt to apply it loosely and end up with questionable results. Thermodynamics is the fundamental science that clarifies all these issues if well understood, applied and interpreted. The attempt of this paper is to clarify these situations and offer alternative methods for analyses. (author)
Yamada, Takahiro; Maezawa, Masaaki; Urano, Chiharu
2015-11-01
We present design and testing of a pseudo-random number generator (PRNG) and a variable pulse number multiplier (VPNM) which are digital circuit subsystems in an integrated quantum voltage noise source for Jonson noise thermometry. Well-defined, calculable pseudo-random patterns of single flux quantum pulses are synthesized with the PRNG and multiplied digitally with the VPNM. The circuit implementation on rapid single flux quantum technology required practical circuit scales and bias currents, 279 junctions and 33 mA for the PRNG, and 1677 junctions and 218 mA for the VPNM. We confirmed the circuit operation with sufficiently wide margins, 80-120%, with respect to the designed bias currents.
Synthesis of Er(III)/Yb(III)-doped BiF3 upconversion nanoparticles for use in optical thermometry.
Du, Peng; Yu, Jae Su
2018-03-23
The authors describe an ethylene glycol assisted precipitation method for synthesis of Er(III)/Yb(III)-doped BiF 3 nanoparticles (NPs) at room temperature. Under 980-nm light irradiation, the NPs emit upconversion (UC) emission of Er(III) ions as a result of a two-photon absorption process. The temperature-dependent green emissions (peaking at 525 and 545 nm) are used to establish an unambiguous relationship between the ratio of fluorescence intensities and temperature. The NPs have a maximum sensitivity of 6.5 × 10 -3 K -1 at 619 K and can be applied over the 291-691 K temperature range. The results indicate that these NPs are a promising candidate for optical thermometry. Graphical abstract Schematic of the room-temperature preparation of Er(III)/Yb(III)-doped BiF 3 nanoparticles with strongly temperature-dependent upconversion emission.
Strategy for thermometry via Tm³⁺-doped NaYF₄ core-shell nanoparticles.
Zhou, Shaoshuai; Jiang, Guicheng; Li, Xinyue; Jiang, Sha; Wei, Xiantao; Chen, Yonghu; Yin, Min; Duan, Changkui
2014-12-01
Optical thermometers usually make use of the fluorescence intensity ratio of two thermally coupled energy levels, with the relative sensitivity constrained by the limited energy gap. Here we develop a strategy by using the upconversion (UC) emissions originating from two multiplets with opposite temperature dependences to achieve higher relative temperature sensitivity. We show that the intensity ratio of the two UC emissions, ³F(2,3) and ¹G₄, of Tm³⁺ in β-NaYF₄:20%Yb³⁺, 0.5%Tm³⁺/NaYF₄:1%Pr³⁺ core-shell nanoparticles under 980 nm laser excitation exhibits high relative temperature sensitivity between 350 and 510 K, with a maximum of 1.53% K⁻¹ at 417 K. This demonstrates the validity of the strategy, and that the studied material has the potential for high-performance optical thermometry.
Blakley, Sean Michael
Nitrogen--vacancy diamond (NVD) quantum sensors are an emerging technology that has shown great promise in areas like high-resolution thermometry and magnetometry. Optical fibers provide attractive new application paradigms for NVD technology. A detailed description of the fabrication processes associated with the development of novel fiber-optic NVD probes are presented in this work. The demonstrated probes are tested on paradigmatic model systems designed to ascertain their suitability for use in challenging biological environments. Methods employing optically detected magnetic resonance (ODMR) are used to accurately measure and map temperature distributions of small objects and to demonstrate emergent temperature-dependent phenomena in genetically modified living organisms. These methods are also used to create detailed high resolution spatial maps of both magnetic scalar and magnetic vector field distributions of spatially localized weak field features in the presence of a noisy, high-field background.
Knobloch, Jens; Muller, Henry; Padamsee, Hasan
1994-11-01
Presented in this paper are the description and the test results of a new stationary thermometry system used to map the temperature of the outer surface of 1.5 GHz superconducting single-cell cavities during operation at 1.6 K. The system comprises 764 removable carbon thermometers whose signals are multiplexed and scanned by a Macintosh computer. A complete temperature map can be obtained in as little as 0.1 s at a temperature resolution of about 0.2 mK. Alternatively, it has been demonstrated that if the acquisition time is increased to several seconds, then a temperature resolution on the order of 30 μK is possible. To our knowledge, these are the fastest acquisition times so far achieved with L-band cavities at these resolutions.
Inman, Kristopher; Wang, Xia; Sangeorzan, Brian
Internal temperatures in a proton exchange membrane (PEM) fuel cell govern the ionic conductivities of the polymer electrolyte, influence the reaction rate at the electrodes, and control the water vapor pressure inside the cell. It is vital to fully understand thermal behavior in a PEM fuel cell if performance and durability are to be optimized. The objective of this research was to design, construct, and implement thermal sensors based on the principles of the lifetime-decay method of phosphor thermometry to measure temperatures inside a PEM fuel cell. Five sensors were designed and calibrated with a maximum uncertainty of ±0.6 °C. Using these sensors, surface temperatures were measured on the cathode gas diffusion layer of a 25 cm 2 PEM fuel cell. The test results demonstrate the utility of the optical temperature sensor design and provide insight into the thermal behavior found in a PEM fuel cell.
Chemical Thermodynamics Vol. 12 - Chemical Thermodynamics of tin
International Nuclear Information System (INIS)
Gamsjaeger, Heinz; GAJDA, Tamas; Sangster, James; Saxena, Surendra K.; Voigt, Wolfgang; Perrone, Jane
2012-01-01
This is the 12th volume of a series of expert reviews of the chemical thermodynamics of key chemical elements in nuclear technology and waste management. This volume is devoted to the inorganic species and compounds of tin. The tables contained in Chapters III and IV list the currently selected thermodynamic values within the NEA TDB Project. The database system developed at the NEA Data Bank, see Section II.6, assures consistency among all the selected and auxiliary data sets. The recommended thermodynamic data are the result of a critical assessment of published information. The values in the auxiliary data set, see Tables IV-1 and IV-2, have been adopted from CODATA key values or have been critically reviewed in this or earlier volumes of the series
Labenski, J. R.; Tew, W. L.; Benz, S. P.; Nam, S. W.; Dresselhaus, P.
2008-02-01
A Johnson-noise thermometer (JNT) has been used with a quantized voltage noise source (QVNS), as a calculable reference to determine the ratio of temperatures near the Zn freezing point to those near the Sn freezing point. The temperatures are derived in a series of separate measurements comparing the synthesized noise power from the QVNS with that of Johnson noise from a known resistance. The synthesized noise power is digitally programed to match the thermal noise powers at both temperatures and provides the principle means of scaling the temperatures. This produces a relatively flat spectrum for the ratio of spectral noise densities, which is close to unity in the low-frequency limit. The data are analyzed as relative spectral ratios over the 4.8 to 450 kHz range averaged over a 3.2 kHz bandwidth. A three-parameter model is used to account for differences in time constants that are inherently temperature dependent. A drift effect of approximately -6 μK·K-1 per day is observed in the results, and an empirical correction is applied to yield a relative difference in temperature ratios of -11.5 ± 43 μK·K-1 with respect to the ratio of temperatures assigned on the International Temperature Scale of 1990 (ITS-90). When these noise thermometry results are combined with results from acoustic gas thermometry at temperatures near the Sn freezing point, a value of T - T 90 = 7 ± 30 mK for the Zn freezing point is derived.
Thermodynamic Database for Zirconium Alloys
International Nuclear Information System (INIS)
Jerlerud Perez, Rosa
2003-05-01
For many decades zirconium alloys have been commonly used in the nuclear power industry as fuel cladding material. Besides their good corrosion resistance and acceptable mechanical properties the main reason of using these alloys is the low neutron absorption. Zirconium alloys are exposed to a very severe environment during the nuclear fission process and there is a demand for better design of this material. To meet this requirement a thermodynamic database is developed to support material designers. In this thesis some aspects about the development of a thermodynamic database for zirconium alloys are presented. A thermodynamic database represents an important facility in applying thermodynamic equilibrium calculations for a given material providing: 1) relevant information about the thermodynamic properties of the alloys e.g. enthalpies, activities, heat capacity, and 2) significant information for the manufacturing process e.g. heat treatment temperature. The basic information in the database is first the unary data, i.e. pure elements; those are taken from the compilation of the Scientific Group Thermodata Europe (SGTE) and then the binary and ternary systems. All phases present in those binary and ternary systems are described by means of the Gibbs energy dependence on composition and temperature. Many of those binary systems have been taken from published or unpublished works and others have been assessed in the present work. All the calculations have been made using Thermo C alc software and the representation of the Gibbs energy obtained by applying Calphad technique
A noise thermometry investigation of the melting point of gallium at the NIM
Zhang, J. T.; Xue, S.
2006-06-01
This paper describes a study of the melting point of gallium with the new NIM Johnson noise thermometer (JNT). The new thermometer adopts the structure of switching correlator and commutator with the reference resistor maintained at the triple point of water. The electronic system of the new thermometer is basically the same as the current JNT, but the preamplifiers have been improved slightly. This study demonstrates that examining the characteristics of the noise signals in the frequency domain is of critical importance in constructing an improved new thermometer, where a power spectral analysis is found to be critical in establishing appropriate grounding for the new thermometer. The new JNT is tested on measurements of the thermodynamic temperature of the melting point of gallium, which give the thermodynamic temperature of 302.9160 K, with an overall integration time of 190 h and a combined standard uncertainty of 9.4 mK. The uncertainty analysis indicates that a standard combined uncertainty of 3 mK could be achieved with the new thermometer over an integration period of 1750 h.
International Nuclear Information System (INIS)
Shchukina, N.G.
1980-01-01
The methodology of the problem of deviation from local thermodynamical equilibrium in the solar atmosphere is presented. The difficulties of solution and methods of realization are systematized. The processes of line formation are considered which take into account velocity fields, structural inhomogeneity, radiation non-coherence etc. as applied to a quiet solar atmosphere. The conclusion is made on the regularity of deviation of the local thermodynamic equilibrium in upper layers of the solar atmosphere
The Thermodynamic Machinery of Life
Kurzynski, Michal
2006-01-01
Living organisms are open thermodynamic systems whose functional structure has developed and been kinetically frozen during the historical process of biological evolution. A thermodynamics of both nonequilibrium and complex systems is needed for their description. In this book, the foundations of such a thermodynamics are presented. Biological processes at the cellular level are considered as coupled chemical reactions and transport processes across internal and the cytoplasmic membrane. All these processes are catalyzed by specific enzymes hence the kinetics of enzymatic catalysis and its control are described here in detail. The coupling of several processes through a common enzyme is considered in the context of free energy or signal transduction. Special attention is paid to evidence for a rich stochastic internal dynamics of native proteins and its possible role in the control of enzyme activity and in the action of biological molecular machines.
Complexation thermodynamics of modified cyclodextrins
DEFF Research Database (Denmark)
Schönbeck, Jens Christian Sidney; Westh, Peter; Holm, Rene
2014-01-01
Inclusion complexes between two bile salts and a range of differently methylated β-cyclodextrins were studied in an attempt to rationalize the complexation thermodynamics of modified cyclodextrins. Calorimetric titrations at a range of temperatures provided precise values of the enthalpies (ΔH......°), entropies (ΔS°), and heat capacities (ΔCp) of complexation, while molecular dynamics simulations assisted the interpretation of the obtained thermodynamic parameters. As previously observed for several types of modified cyclodextrins, the substituents at the rims of the cyclodextrin induced large changes......° and then a strong decrease when the degree of substitution exceeded some threshold. Exactly the same trend was observed for ΔCp. The dehydration of nonpolar surface, as quantified by the simulations, can to a large extent explain the variation in the thermodynamic parameters. The methyl substituents form additional...
Nanofluidics thermodynamic and transport properties
Michaelides, Efstathios E (Stathis)
2014-01-01
This volume offers a comprehensive examination of the subject of heat and mass transfer with nanofluids as well as a critical review of the past and recent research projects in this area. Emphasis is placed on the fundamentals of the transport processes using particle-fluid suspensions, such as nanofluids. The nanofluid research is examined and presented in a holistic way using a great deal of our experience with the subjects of continuum mechanics, statistical thermodynamics, and non-equilibrium thermodynamics of transport processes. Using a thorough database, the experimental, analytical, and numerical advances of recent research in nanofluids are critically examined and connected to past research with medium and fine particles as well as to functional engineering systems. Promising applications and technological issues of heat/mass transfer system design with nanofluids are also discussed. This book also: Provides a deep scientific analysis of nanofluids using classical thermodynamics and statistical therm...
Development of Thermodynamic Conceptual Evaluation
Talaeb, P.; Wattanakasiwich, P.
2010-07-01
This research aims to develop a test for assessing student understanding of fundamental principles in thermodynamics. Misconceptions found from previous physics education research were used to develop the test. Its topics include heat and temperature, the zeroth and the first law of thermodynamics, and the thermodynamics processes. The content validity was analyzed by three physics experts. Then the test was administered to freshmen, sophomores and juniors majored in physics in order to determine item difficulties and item discrimination of the test. A few items were eliminated from the test. Finally, the test will be administered to students taking Physics I course in order to evaluate the effectiveness of Interactive Lecture Demonstrations that will be used for the first time at Chiang Mai University.
Statistical thermodynamics of clustered populations.
Matsoukas, Themis
2014-08-01
We present a thermodynamic theory for a generic population of M individuals distributed into N groups (clusters). We construct the ensemble of all distributions with fixed M and N, introduce a selection functional that embodies the physics that governs the population, and obtain the distribution that emerges in the scaling limit as the most probable among all distributions consistent with the given physics. We develop the thermodynamics of the ensemble and establish a rigorous mapping to regular thermodynamics. We treat the emergence of a so-called giant component as a formal phase transition and show that the criteria for its emergence are entirely analogous to the equilibrium conditions in molecular systems. We demonstrate the theory by an analytic model and confirm the predictions by Monte Carlo simulation.
Thermodynamics of nuclear power systems
International Nuclear Information System (INIS)
Anno, J.
1983-01-01
The conversion of nuclear energy to useful work follows essentially the same course as the conversion of thermal energy from fossil fuel to work. The thermal energy released in the reactor core is first transferred to the primary coolant which then generally transfers its heat to a secondary fluid. The secondary fluid serves as the working fluid in a heat engine. In this chapter the authors briefly examine the thermodynamic principles governing the operation of such engines, the major thermodynamic cycles used, and their application to nuclear power plants
Thermodynamics of nuclear power systems
International Nuclear Information System (INIS)
Anno, J.
1977-01-01
The conversion of nuclear energy to useful work follows essentially the same course as the conversion of thermal energy from fossil fuel to work. The thermal energy released in the reactor core is first transferred to the primary coolant which then generally transfers its heat to a secondary fluid. The secondary fluid serves as the working fluid in a heat engine. The author briefly examines the thermodynamic principles governing the operation of such engines, the major thermodynamic cycles used, and their application to nuclear power plants. (Auth.)
Placement by thermodynamic simulated annealing
International Nuclear Information System (INIS)
Vicente, Juan de; Lanchares, Juan; Hermida, Roman
2003-01-01
Combinatorial optimization problems arise in different fields of science and engineering. There exist some general techniques coping with these problems such as simulated annealing (SA). In spite of SA success, it usually requires costly experimental studies in fine tuning the most suitable annealing schedule. In this Letter, the classical integrated circuit placement problem is faced by Thermodynamic Simulated Annealing (TSA). TSA provides a new annealing schedule derived from thermodynamic laws. Unlike SA, temperature in TSA is free to evolve and its value is continuously updated from the variation of state functions as the internal energy and entropy. Thereby, TSA achieves the high quality results of SA while providing interesting adaptive features
Thermodynamics of Dipolar Chain Systems
DEFF Research Database (Denmark)
R. Armstrong, J.; Zinner, Nikolaj Thomas; V. Fedorov, D.
2012-01-01
The thermodynamics of a quantum system of layers containing perpendicularly oriented dipolar molecules is studied within an oscillator approximation for both bosonic and fermionic species. The system is assumed to be built from chains with one molecule in each layer. We consider the effects...... numerically. Our findings indicate that thermodynamic observables, such as the heat capacity, can be used to probe the signatures of the intralayer interaction between chains. This should be relevant for near future experiments on polar molecules with strong dipole moments....
Applied Thermodynamics: Grain Boundary Segregation
Directory of Open Access Journals (Sweden)
Pavel Lejček
2014-03-01
Full Text Available Chemical composition of interfaces—free surfaces and grain boundaries—is generally described by the Langmuir–McLean segregation isotherm controlled by Gibbs energy of segregation. Various components of the Gibbs energy of segregation, the standard and the excess ones as well as other thermodynamic state functions—enthalpy, entropy and volume—of interfacial segregation are derived and their physical meaning is elucidated. The importance of the thermodynamic state functions of grain boundary segregation, their dependence on volume solid solubility, mutual solute–solute interaction and pressure effect in ferrous alloys is demonstrated.
Thermodynamics of de Sitter universes
International Nuclear Information System (INIS)
Huang Chaoguang; Liu Liao; Wang Bobo
2002-01-01
It is shown that the first law of thermodynamics can be applied to the de Sitter universe to relate its vacuum energy, pressure, entropy of horizon, chemical potential, etc., when the cosmological constant changes due to the fluctuation of the vacuum or other reasons. The second law should be reformulated in the form that the spontaneous decay of the vacuum never makes the entropy of the de Sitter universe decrease. The third law of thermodynamics, applying to the de Sitter universe, implies that the cosmological constant cannot reach zero by finite physical processes. The relation to the holographic principle is also briefly discussed
Nuclear thermodynamics below particle threshold
International Nuclear Information System (INIS)
Schiller, A.; Agvaanluvsan, U.; Algin, E.; Bagheri, A.; Chankova, R.; Guttormsen, M.; Hjorth-Jensen, M.; Rekstad, J.; Siem, S.; Sunde, A. C.; Voinov, A.
2005-01-01
From a starting point of experimentally measured nuclear level densities, we discuss thermodynamical properties of nuclei below the particle emission threshold. Since nuclei are essentially mesoscopic systems, a straightforward generalization of macroscopic ensemble theory often yields unphysical results. A careful critique of traditional thermodynamical concepts reveals problems commonly encountered in mesoscopic systems. One of which is the fact that microcanonical and canonical ensemble theory yield different results, another concerns the introduction of temperature for small, closed systems. Finally, the concept of phase transitions is investigated for mesoscopic systems
Peaceful nuclear explosions and thermodynamics
International Nuclear Information System (INIS)
Prieto, F.E.
1975-01-01
Some theoretical advances in the thermodynamics of very high pressures are reviewed. A universal (system-independent) formulation of the thermodynamics is sketched, and some of the equations more frequently used are written in system-independent form. Among these equations are: Hugoniot pressure and temperature as functions of volume; the Mie-Gruneisen equation; and an explicit form for the equation of state. It is also shown that this formalism can be used to interpret and predict results from peaceful nuclear explosions. (author)
Multi-pressure boiler thermodynamics analysis code
International Nuclear Information System (INIS)
Lorenzoni, G.
1992-01-01
A new method and the relative FORTRAN program for the thermodynamics design analysis of a multipressure boiler are reported. This method permits the thermodynamics design optimization with regard to total exergy production and a preliminary costs
THERMODYNAMIC STUDIES ON THE CHARGE-TRANSFER ...
African Journals Online (AJOL)
... technique was employed to investigate thermodynamic parameters associated with the interaction ... KEY WORDS: Amitriptyline , chloranilic acid, thermodynamic parameters. Global Jnl Pure & Applied Sciences Vol.10(1) 2004: 147-153 ...
On thermodynamic limits of entropy densities
Moriya, H; Van Enter, A
We give some sufficient conditions which guarantee that the entropy density in the thermodynamic limit is equal to the thermodynamic limit of the entropy densities of finite-volume (local) Gibbs states.
Quantum and thermodynamic aspects of Black Holes
International Nuclear Information System (INIS)
Sande e Lemos, J.P. de; Videira, A.L.L.
1983-01-01
The main results originating from the attempts of trying to incorporate quantum and thermodynamic properties and concepts to the gravitational system black hole, essentially the Hawking effect and the four laws of thermodynamics are reviewed. (Author) [pt
Thermodynamic theory of equilibrium fluctuations
International Nuclear Information System (INIS)
Mishin, Y.
2015-01-01
The postulational basis of classical thermodynamics has been expanded to incorporate equilibrium fluctuations. The main additional elements of the proposed thermodynamic theory are the concept of quasi-equilibrium states, a definition of non-equilibrium entropy, a fundamental equation of state in the entropy representation, and a fluctuation postulate describing the probability distribution of macroscopic parameters of an isolated system. Although these elements introduce a statistical component that does not exist in classical thermodynamics, the logical structure of the theory is different from that of statistical mechanics and represents an expanded version of thermodynamics. Based on this theory, we present a regular procedure for calculations of equilibrium fluctuations of extensive parameters, intensive parameters and densities in systems with any number of fluctuating parameters. The proposed fluctuation formalism is demonstrated by four applications: (1) derivation of the complete set of fluctuation relations for a simple fluid in three different ensembles; (2) fluctuations in finite-reservoir systems interpolating between the canonical and micro-canonical ensembles; (3) derivation of fluctuation relations for excess properties of grain boundaries in binary solid solutions, and (4) derivation of the grain boundary width distribution for pre-melted grain boundaries in alloys. The last two applications offer an efficient fluctuation-based approach to calculations of interface excess properties and extraction of the disjoining potential in pre-melted grain boundaries. Possible future extensions of the theory are outlined.
Thermodynamic efficiency of nonimaging concentrators
Shatz, Narkis; Bortz, John; Winston, Roland
2009-08-01
The purpose of a nonimaging concentrator is to transfer maximal flux from the phase space of a source to that of a target. A concentrator's performance can be expressed relative to a thermodynamic reference. We discuss consequences of Fermat's principle of geometrical optics. We review étendue dilution and optical loss mechanisms associated with nonimaging concentrators, especially for the photovoltaic (PV) role. We introduce the concept of optical thermodynamic efficiency which is a performance metric combining the first and second laws of thermodynamics. The optical thermodynamic efficiency is a comprehensive metric that takes into account all loss mechanisms associated with transferring flux from the source to the target phase space, which may include losses due to inadequate design, non-ideal materials, fabrication errors, and less than maximal concentration. As such, this metric is a gold standard for evaluating the performance of nonimaging concentrators. Examples are provided to illustrate the use of this new metric. In particular we discuss concentrating PV systems for solar power applications.
Thermodynamics of asymptotically safe theories
DEFF Research Database (Denmark)
Rischke, Dirk H.; Sannino, Francesco
2015-01-01
We investigate the thermodynamic properties of a novel class of gauge-Yukawa theories that have recently been shown to be completely asymptotically safe, because their short-distance behaviour is determined by the presence of an interacting fixed point. Not only do all the coupling constants freeze...
Thermodynamics of freezing and melting
DEFF Research Database (Denmark)
Pedersen, Ulf Rørbæk; Costigliola, Lorenzo; Bailey, Nicholas
2016-01-01
phases at a single thermodynamic state point provide the basis for calculating the pressure, density and entropy of fusion as functions of temperature along the melting line, as well as the variation along this line of the reduced crystalline vibrational mean-square displacement (the Lindemann ratio...
Thermodynamical aspects of pulse tubes
Waele, de A.T.A.M.; Steijaert, P.P.; Gijzen, J.
1997-01-01
The cooling power of cryocoolers is determined by the work done by the compressor and the entropy produced by the irreversible processes in the various components of the system. In this paper we discuss the thermodynamics of pulse tubes, but many of the relationships are equally valid for other
Thermodynamics of Oligonucleotide Duplex Melting
Schreiber-Gosche, Sherrie; Edwards, Robert A.
2009-01-01
Melting temperatures of oligonucleotides are useful for a number of molecular biology applications, such as the polymerase chain reaction (PCR). Although melting temperatures are often calculated with simplistic empirical equations, application of thermodynamics provides more accurate melting temperatures and an opportunity for students to apply…
Simulating metabolism with statistical thermodynamics.
Cannon, William R
2014-01-01
New methods are needed for large scale modeling of metabolism that predict metabolite levels and characterize the thermodynamics of individual reactions and pathways. Current approaches use either kinetic simulations, which are difficult to extend to large networks of reactions because of the need for rate constants, or flux-based methods, which have a large number of feasible solutions because they are unconstrained by the law of mass action. This report presents an alternative modeling approach based on statistical thermodynamics. The principles of this approach are demonstrated using a simple set of coupled reactions, and then the system is characterized with respect to the changes in energy, entropy, free energy, and entropy production. Finally, the physical and biochemical insights that this approach can provide for metabolism are demonstrated by application to the tricarboxylic acid (TCA) cycle of Escherichia coli. The reaction and pathway thermodynamics are evaluated and predictions are made regarding changes in concentration of TCA cycle intermediates due to 10- and 100-fold changes in the ratio of NAD+:NADH concentrations. Finally, the assumptions and caveats regarding the use of statistical thermodynamics to model non-equilibrium reactions are discussed.
THERMODYNAMICS USED IN ENVIRONMENTAL ENGINEERING
Thermodynamics is a science in which energy transformations are studied as well as their relationships to the changes in the chemical properties of a system. It is the fundamental basis of many engineering fields. The profession of environmental engineering is no exception. In pa...
Thermodynamics on the Molality Scale
Canagaratna, Sebastian G.; Maheswaran, M.
2013-01-01
For physical measurements, the compositions of solutions, especially electrolyte solutions, are expressed in terms of molality rather than mole fractions. The development of the necessary thermodynamic equations directly in terms of molality is not common in textbooks, and the treatment in the literature is not very systematic. We develop a…
A Simple Statistical Thermodynamics Experiment
LoPresto, Michael C.
2010-01-01
Comparing the predicted and actual rolls of combinations of both two and three dice can help to introduce many of the basic concepts of statistical thermodynamics, including multiplicity, probability, microstates, and macrostates, and demonstrate that entropy is indeed a measure of randomness, that disordered states (those of higher entropy) are…
Optical radiation measurements II; Proceedings of the Meeting, Orlando, FL, Mar. 27, 28, 1989
Palmer, James M.
1989-09-01
The present conference discusses topics in the characterization of imaging radiometers, laboratory instrumentation, field and spacecraft instrumentation, and quantum and thermal standard detectors. Attention is given to UV radiometric imaging, dual-color radiometer imagery, a novel diode-array radiometer, a novel reference spectrophotometer, radiance calibration of spherical integrators, instrumentation for measurement of spectral goniometric reflectance, and a real-time IR background discrimination radiometer. Also discussed are a multichannel radiometer for atmosphere optical property measurements, the UV spectroradiometric output of a turbojet, characterizations of the Earth Radiation Budget Experiment scanning radiometers, total-radiation thermometry, future directions in Si photodiode self-calibration, and radiometric quality Ge photodiodes.
Thermodynamics of Acoustic Black Holes in Two Dimensions
Directory of Open Access Journals (Sweden)
Baocheng Zhang
2016-01-01
Full Text Available It is well-known that the thermal Hawking-like radiation can be emitted from the acoustic horizon, but the thermodynamic-like understanding for acoustic black holes was rarely made. In this paper, we will show that the kinematic connection can lead to the dynamic connection at the horizon between the fluid and gravitational models in two dimensions, which implies that there exists the thermodynamic-like description for acoustic black holes. Then, we discuss the first law of thermodynamics for the acoustic black hole via an intriguing connection between the gravitational-like dynamics of the acoustic horizon and thermodynamics. We obtain a universal form for the entropy of acoustic black holes, which has an interpretation similar to the entropic gravity. We also discuss the specific heat and find that the derivative of the velocity of background fluid can be regarded as a novel acoustic analogue of the two-dimensional dilaton potential, which interprets why the two-dimensional fluid dynamics can be connected to the gravitational dynamics but it is difficult for four-dimensional case. In particular, when a constraint is added for the fluid, the analogue of a Schwarzschild black hole can be realized.
Possible extended forms of thermodynamic entropy
International Nuclear Information System (INIS)
Sasa, Shin-ichi
2014-01-01
Thermodynamic entropy is determined by a heat measurement through the Clausius equality. The entropy then formalizes a fundamental limitation of operations by the second law of thermodynamics. The entropy is also expressed as the Shannon entropy of the microscopic degrees of freedom. Whenever an extension of thermodynamic entropy is attempted, we must pay special attention to how its three different aspects just mentioned are altered. In this paper, we discuss possible extensions of the thermodynamic entropy. (paper)
Chemical Thermodynamics and Information Theory with Applications
Graham, Daniel J
2011-01-01
Thermodynamics and information touch theory every facet of chemistry. However, the physical chemistry curriculum digested by students worldwide is still heavily skewed toward heat/work principles established more than a century ago. Rectifying this situation, Chemical Thermodynamics and Information Theory with Applications explores applications drawn from the intersection of thermodynamics and information theory--two mature and far-reaching fields. In an approach that intertwines information science and chemistry, this book covers: The informational aspects of thermodynamic state equations The
Contact Geometry of Mesoscopic Thermodynamics and Dynamics
Directory of Open Access Journals (Sweden)
Miroslav Grmela
2014-03-01
Full Text Available The time evolution during which macroscopic systems reach thermodynamic equilibrium states proceeds as a continuous sequence of contact structure preserving transformations maximizing the entropy. This viewpoint of mesoscopic thermodynamics and dynamics provides a unified setting for the classical equilibrium and nonequilibrium thermodynamics, kinetic theory, and statistical mechanics. One of the illustrations presented in the paper is a new version of extended nonequilibrium thermodynamics with fluxes as extra state variables.
Thermodynamics of statistical inference by cells.
Lang, Alex H; Fisher, Charles K; Mora, Thierry; Mehta, Pankaj
2014-10-03
The deep connection between thermodynamics, computation, and information is now well established both theoretically and experimentally. Here, we extend these ideas to show that thermodynamics also places fundamental constraints on statistical estimation and learning. To do so, we investigate the constraints placed by (nonequilibrium) thermodynamics on the ability of biochemical signaling networks to estimate the concentration of an external signal. We show that accuracy is limited by energy consumption, suggesting that there are fundamental thermodynamic constraints on statistical inference.
A mathematical model for radiation hydrodynamics
Directory of Open Access Journals (Sweden)
Sebastiano Pennisi
1990-11-01
Full Text Available We adopt here the idea of describing a radiation field by means of the radiation energy density E and the radiative flux vector F which must satisfy a set of evolution equations; in these equations an unknown tensorial function P(E,F appears that is determined by the methods of extended thermodynamics.
Radiation resistance of polymer materials for space
International Nuclear Information System (INIS)
Miyauchi, Masahiko; Iwata, Minoru; Yokota, Rikio
2011-01-01
The thin film of thermoplastic polyimide with a new asymmetric structure is used in the solar sail 'IKAROS'. Here, the relation of its chemical structure to its thermodynamic properties and radiation resistance is introduced. (M.H.)
Casimir effect and thermodynamics of horizon instabilities
International Nuclear Information System (INIS)
Hartnoll, Sean A.
2004-01-01
We propose a dual thermodynamic description of a classical instability of generalized black hole spacetimes. From a thermodynamic perspective, the instability is due to negative compressibility in regions where the Casimir pressure is large. The argument indicates how the correspondence between thermodynamic and classical instability for horizons may be extended to cases without translational invariance
Thermodynamics and statistical mechanics. [thermodynamic properties of gases
1976-01-01
The basic thermodynamic properties of gases are reviewed and the relations between them are derived from the first and second laws. The elements of statistical mechanics are then formulated and the partition function is derived. The classical form of the partition function is used to obtain the Maxwell-Boltzmann distribution of kinetic energies in the gas phase and the equipartition of energy theorem is given in its most general form. The thermodynamic properties are all derived as functions of the partition function. Quantum statistics are reviewed briefly and the differences between the Boltzmann distribution function for classical particles and the Fermi-Dirac and Bose-Einstein distributions for quantum particles are discussed.
Nonequilibrium thermodynamic models and applications to hydrogen plasma
International Nuclear Information System (INIS)
Cho, K.Y.
1988-01-01
A generalized multithermal equilibrium (GMTE) thermodynamic model is developed and presented with applications to hydrogen. A new chemical equilibrium equation for GMTE is obtained without the ensemble temperature concept, used by a previous MTE model. The effects of the GMTE model on the derivation and calculation of the thermodynamic, transport, and radiative properties are presented and significant differences from local thermal equilibrium (LTE) and two temperature model are discussed. When the electron translational temperature (T e ) is higher than the translational temperature of the heavy particles, the effects of hydrogen molecular species to the properties are significant at high T e compared with LTE results. The density variations of minor species are orders of magnitude with kinetic nonequilibrium at a constant electron temperature. A collisional-radiative model is also developed with the GMTE chemical equilibrium equation to study the effects of radiative transfer and the ambipolar diffusion on the population distribution of the excited atoms. The nonlocal radiative transfer effect is parameterized by an absorption factor, which is defined as a ratio of the absorbed intensity to the spontaneous emission coefficient
Quantitative MR thermometry based on phase-drift correction PRF shift method at 0.35 T.
Chen, Yuping; Ge, Mengke; Ali, Rizwan; Jiang, Hejun; Huang, Xiaoyan; Qiu, Bensheng
2018-04-10
Noninvasive magnetic resonance thermometry (MRT) at low-field using proton resonance frequency shift (PRFS) is a promising technique for monitoring ablation temperature, since low-field MR scanners with open-configuration are more suitable for interventional procedures than closed systems. In this study, phase-drift correction PRFS with first-order polynomial fitting method was proposed to investigate the feasibility and accuracy of quantitative MR thermography during hyperthermia procedures in a 0.35 T open MR scanner. Unheated phantom and ex vivo porcine liver experiments were performed to evaluate the optimal polynomial order for phase-drift correction PRFS. The temperature estimation approach was tested in brain temperature experiments of three healthy volunteers at room temperature, and in ex vivo porcine liver microwave ablation experiments. The output power of the microwave generator was set at 40 W for 330 s. In the unheated experiments, the temperature root mean square error (RMSE) in the inner region of interest was calculated to assess the best-fitting order for polynomial fit. For ablation experiments, relative temperature difference profile measured by the phase-drift correction PRFS was compared with the temperature changes recorded by fiber optic temperature probe around the microwave ablation antenna within the target thermal region. The phase-drift correction PRFS using first-order polynomial fitting could achieve the smallest temperature RMSE in unheated phantom, ex vivo porcine liver and in vivo human brain experiments. In the ex vivo porcine liver microwave ablation procedure, the temperature error between MRT and fiber optic probe of all but six temperature points were less than 2 °C. Overall, the RMSE of all temperature points was 1.49 °C. Both in vivo and ex vivo experiments showed that MR thermometry based on the phase-drift correction PRFS with first-order polynomial fitting could be applied to monitor temperature changes during
The thermodynamic-buffer enzymes.
Stucki, J W
1980-08-01
Oxidative phosphorylation operates at optimal efficiency if and only if the condition of conductance matching L33/L11 = square root 1-q2 is fulfilled. In this relation L11 is the phenomenological conductance of phosphorylation, L33 the phenomenological conductance of the load, i.e. the irreversible ATP-utilizing processes in the cell, and q the degree of coupling of oxidative phosphorylation driven by respiration. Since during short time intervals L11 and q are constant whereas L33 fluctuates in the cell, oxidative phosphorylation would only rarely operate at optimal efficiency due to violation of conductance matching. This paper demonstrates that the reversible ATP-utilizing reaction catalyzed by adenylate kinase can effectively compensate deviations from conductance matching in the presence of a fluctuating L33 and hence allows oxidative phosphorylation to operate at optimal efficiency in the cell. Since the adenylate kinase reaction was found to buffer a thermodynamic potential, i.e. the phosphate potential, this finding was generalized to the concept of thermodynamic buffering. The thermodynamic buffering ability of the adenylate kinase reaction was demonstrated by experiments with incubated rat-liver mitochondria. Considerations of changes introduced in the entropy production by the adenylate kinase reaction allowed to establish the theoretical framework for thermodynamic buffering. The ability of thermodynamic buffering to compensate deviations from conductance matching in the presence of fluctuating loads was demonstrated by computer simulations. The possibility of other reversible ATP-utilizing reactions, like the ones catalyzed by creatine kinase and arginine kinase, to contribute to thermodynamic buffering is discussed. Finally, the comparison of the theoretically calculated steady-stae cytosolic adenine nucleotide concentrations with experimental data from perfused livers demonstrated that in livers from fed rats conductance matching is fulfilled on a
Thermodynamic Relations for Kiselev and Dilaton Black Hole
International Nuclear Information System (INIS)
Jamil, Mubasher; Pradhan, Parthapratim; Majeed, Bushra
2015-01-01
We investigate the thermodynamics and phase transition for Kiselev black hole and dilaton black hole. Specifically we consider Reissner-Nordström black hole surrounded by radiation and dust and Schwarzschild black hole surrounded by quintessence, as special cases of Kiselev solution. We have calculated the products relating the surface gravities, surface temperatures, Komar energies, areas, entropies, horizon radii, and the irreducible masses at the Cauchy and the event horizons. It is observed that the product of surface gravities, product of surface temperature, and product of Komar energies at the horizons are not universal quantities for the Kiselev solutions while products of areas and entropies at both the horizons are independent of mass of the above-mentioned black holes (except for Schwarzschild black hole surrounded by quintessence). For charged dilaton black hole, all the products vanish. The first law of thermodynamics is also verified for Kiselev solutions. Heat capacities are calculated and phase transitions are observed, under certain conditions
The OpenCalphad thermodynamic software interface
Sundman, Bo; Kattner, Ursula R; Sigli, Christophe; Stratmann, Matthias; Le Tellier, Romain; Palumbo, Mauro; Fries, Suzana G
2017-01-01
Thermodynamic data are needed for all kinds of simulations of materials processes. Thermodynamics determines the set of stable phases and also provides chemical potentials, compositions and driving forces for nucleation of new phases and phase transformations. Software to simulate materials properties needs accurate and consistent thermodynamic data to predict metastable states that occur during phase transformations. Due to long calculation times thermodynamic data are frequently pre-calculated into “lookup tables” to speed up calculations. This creates additional uncertainties as data must be interpolated or extrapolated and conditions may differ from those assumed for creating the lookup table. Speed and accuracy requires that thermodynamic software is fully parallelized and the Open-Calphad (OC) software is the first thermodynamic software supporting this feature. This paper gives a brief introduction to computational thermodynamics and introduces the basic features of the OC software and presents four different application examples to demonstrate its versatility. PMID:28260838
Thermodynamic Model of Spatial Memory
Kaufman, Miron; Allen, P.
1998-03-01
We develop and test a thermodynamic model of spatial memory. Our model is an application of statistical thermodynamics to cognitive science. It is related to applications of the statistical mechanics framework in parallel distributed processes research. Our macroscopic model allows us to evaluate an entropy associated with spatial memory tasks. We find that older adults exhibit higher levels of entropy than younger adults. Thurstone's Law of Categorical Judgment, according to which the discriminal processes along the psychological continuum produced by presentations of a single stimulus are normally distributed, is explained by using a Hooke spring model of spatial memory. We have also analyzed a nonlinear modification of the ideal spring model of spatial memory. This work is supported by NIH/NIA grant AG09282-06.
The 4th Thermodynamic Principle?
International Nuclear Information System (INIS)
Montero Garcia, Jose de la Luz; Novoa Blanco, Jesus Francisco
2007-01-01
It should be emphasized that the 4th Principle above formulated is a thermodynamic principle and, at the same time, is mechanical-quantum and relativist, as it should inevitably be and its absence has been one of main the theoretical limitations of the physical theory until today.We show that the theoretical discovery of Dimensional Primitive Octet of Matter, the 4th Thermodynamic Principle, the Quantum Hexet of Matter, the Global Hexagonal Subsystem of Fundamental Constants of Energy and the Measurement or Connected Global Scale or Universal Existential Interval of the Matter is that it is possible to be arrived at a global formulation of the four 'forces' or fundamental interactions of nature. The Einstein's golden dream is possible
Statistical thermodynamics of nonequilibrium processes
Keizer, Joel
1987-01-01
The structure of the theory ofthermodynamics has changed enormously since its inception in the middle of the nineteenth century. Shortly after Thomson and Clausius enunciated their versions of the Second Law, Clausius, Maxwell, and Boltzmann began actively pursuing the molecular basis of thermo dynamics, work that culminated in the Boltzmann equation and the theory of transport processes in dilute gases. Much later, Onsager undertook the elucidation of the symmetry oftransport coefficients and, thereby, established himself as the father of the theory of nonequilibrium thermodynamics. Com bining the statistical ideas of Gibbs and Langevin with the phenomenological transport equations, Onsager and others went on to develop a consistent statistical theory of irreversible processes. The power of that theory is in its ability to relate measurable quantities, such as transport coefficients and thermodynamic derivatives, to the results of experimental measurements. As powerful as that theory is, it is linear and...
Modern Thermodynamics with Statistical Mechanics
Helrich, Carl S
2009-01-01
With the aim of presenting thermodynamics in as simple and as unified a form as possible, this textbook starts with an introduction to the first and second laws and then promptly addresses the complete set of the potentials in a subsequent chapter and as a central theme throughout. Before discussing modern laboratory measurements, the book shows that the fundamental quantities sought in the laboratory are those which are required for determining the potentials. Since the subjects of thermodynamics and statistical mechanics are a seamless whole, statistical mechanics is treated as integral part of the text. Other key topics such as irreversibility, the ideas of Ilya Prigogine, chemical reaction rates, equilibrium of heterogeneous systems, and transition-state theory serve to round out this modern treatment. An additional chapter covers quantum statistical mechanics due to active current research in Bose-Einstein condensation. End-of-chapter exercises, chapter summaries, and an appendix reviewing fundamental pr...
Thermodynamics of Dipolar Chain Systems
International Nuclear Information System (INIS)
Armstrong, J.R.; Zinner, N.T.; Fedorov, D.V.; Jensen, A.S.
2013-01-01
The thermodynamics of a quantum system of layers containing perpendicularly oriented dipolar molecules is studied within an oscillator approximation for both bosonic and fermionic species. The system is assumed to be built from chains with one molecule in each layer. We consider the effects of the intralayer repulsion and quantum statistical requirements in systems with more than one chain. Specifically, we consider the case of two chains and solve the problem analytically within the harmonic Hamiltonian approach which is accurate for large dipole moments. The case of three chains is calculated numerically. Our findings indicate that thermodynamic observables, such as the heat capacity, can be used to probe the signatures of the intralayer interaction between chains. This should be relevant for near future experiments on polar molecules with strong dipole moments. (author)
Association theories for complex thermodynamics
DEFF Research Database (Denmark)
Kontogeorgis, Georgios; Rafiqul Gani
2013-01-01
of this review is two-fold: first to illustrate some of the significant capabilities of these association theories and why indeed they have already been extensively used and are expected to find even more applications in the future. The second and most important aspect of this review is to outline many...... applications. While specialized models can handle different cases, even complex ones, with the advent of powerful theories and computers there is the hope that a single or a few models could be suitable for a general modeling of complex thermodynamics. After more than 100 years with active use of thermodynamic...... models, we have now come to the understanding that simple one-fluid theories like the cubic equations of state or the various forms of local composition models will never be able to model a wide range of complex systems with sufficient accuracy. While various modern approaches have appeared, one very...
Chiral thermodynamics of nuclear matter
Energy Technology Data Exchange (ETDEWEB)
Fiorilla, Salvatore
2012-10-23
The equation of state of nuclear matter is calculated at finite temperature in the framework of in-medium chiral perturbation theory up to three-loop order. The dependence of its thermodynamic properties on the isospin-asymmetry is investigated. The chiral quark condensate is evaluated for symmetric nuclear matter. Its behaviour as a function of density and temperature sets important nuclear physics constraints for the QCD phase diagram.
Thermodynamic properties of sea air
Directory of Open Access Journals (Sweden)
R. Feistel
2010-02-01
Full Text Available Very accurate thermodynamic potential functions are available for fluid water, ice, seawater and humid air covering wide ranges of temperature and pressure conditions. They permit the consistent computation of all equilibrium properties as, for example, required for coupled atmosphere-ocean models or the analysis of observational or experimental data. With the exception of humid air, these potential functions are already formulated as international standards released by the International Association for the Properties of Water and Steam (IAPWS, and have been adopted in 2009 for oceanography by IOC/UNESCO.
In this paper, we derive a collection of formulas for important quantities expressed in terms of the thermodynamic potentials, valid for typical phase transitions and composite systems of humid air and water/ice/seawater. Particular attention is given to equilibria between seawater and humid air, referred to as "sea air" here. In a related initiative, these formulas will soon be implemented in a source-code library for easy practical use. The library is primarily aimed at oceanographic applications but will be relevant to air-sea interaction and meteorology as well.
The formulas provided are valid for any consistent set of suitable thermodynamic potential functions. Here we adopt potential functions from previous publications in which they are constructed from theoretical laws and empirical data; they are briefly summarized in the appendix. The formulas make use of the full accuracy of these thermodynamic potentials, without additional approximations or empirical coefficients. They are expressed in the temperature scale ITS-90 and the 2008 Reference-Composition Salinity Scale.
Improved Estimates of Thermodynamic Parameters
Lawson, D. D.
1982-01-01
Techniques refined for estimating heat of vaporization and other parameters from molecular structure. Using parabolic equation with three adjustable parameters, heat of vaporization can be used to estimate boiling point, and vice versa. Boiling points and vapor pressures for some nonpolar liquids were estimated by improved method and compared with previously reported values. Technique for estimating thermodynamic parameters should make it easier for engineers to choose among candidate heat-exchange fluids for thermochemical cycles.
Statistics and thermodynamics of fracture
Chudnovsky, A.
1984-01-01
A probabilistic model of the fracture processes unifying the phenomenological study of long term strength of materials, fracture mechanics and statistical approaches to fracture is briefly outlined. The general framework of irreversible thermodynamics is employed to model the deterministic side of the failure phenomenon. The stochastic calculus is used to account for thg failure mechanisms controlled by chance; particularly, the random roughness of fracture surfaces.
Thermodynamic data for uranium fluorides
International Nuclear Information System (INIS)
Leitnaker, J.M.
1983-03-01
Self-consistent thermodynamic data have been tabulated for uranium fluorides between UF 4 and UF 6 , including UF 4 (solid and gas), U 4 F 17 (solid), U 2 F 9 (solid), UF 5 (solid and gas), U 2 F 10 (gas), and UF 6 (solid, liquid, and gas). Included are thermal function - the heat capacity, enthalpy, and free energy function, heats of formation, and vaporization behavior
THERMODYNAMIC MODEL OF GAS HYDRATES
Недоступ, В. И.; Недоступ, О. В.
2015-01-01
The interest to gas hydrates grows last years. Therefore working out of reliable settlement-theoretical methods of definition of their properties is necessary. The thermodynamic model of gas hydrates in which the central place occupies a behaviour of guest molecule in cell is described. The equations of interaction of molecule hydrate formative gas with cell are received, and also an enthalpy and energy of output of molecule from a cell are determined. The equation for calculation of thermody...
Chiral thermodynamics of nuclear matter
International Nuclear Information System (INIS)
Fiorilla, Salvatore
2012-01-01
The equation of state of nuclear matter is calculated at finite temperature in the framework of in-medium chiral perturbation theory up to three-loop order. The dependence of its thermodynamic properties on the isospin-asymmetry is investigated. The chiral quark condensate is evaluated for symmetric nuclear matter. Its behaviour as a function of density and temperature sets important nuclear physics constraints for the QCD phase diagram.
Thermodynamic evolution far from equilibrium
Khantuleva, Tatiana A.
2018-05-01
The presented model of thermodynamic evolution of an open system far from equilibrium is based on the modern results of nonequilibrium statistical mechanics, the nonlocal theory of nonequilibrium transport developed by the author and the Speed Gradient principle introduced in the theory of adaptive control. Transition to a description of the system internal structure evolution at the mesoscopic level allows a new insight at the stability problem of non-equilibrium processes. The new model is used in a number of specific tasks.
Foundations of radiation hydrodynamics
Mihalas, Dimitri
1999-01-01
Radiation hydrodynamics is a broad subject that cuts across many disciplines in physics and astronomy: fluid dynamics, thermodynamics, statistical mechanics, kinetic theory, and radiative transfer, among others. The theory developed in this book by two specialists in the field can be applied to the study of such diverse astrophysical phenomena as stellar winds, supernova explosions, and the initial phases of cosmic expansion, as well as the physics of laser fusion and reentry vehicles. As such, it provides students with the basic tools for research on radiating flows.Largely self-contained,
Foundations of radiation hydrodynamics
Mihalas, D.; Mihalas, B. W.
This book is the result of an attempt, over the past few years, to gather the basic tools required to do research on radiating flows in astrophysics. The microphysics of gases is discussed, taking into account the equation of state of a perfect gas, the first and second law of thermodynamics, the thermal properties of a perfect gas, the distribution function and Boltzmann's equation, the collision integral, the Maxwellian velocity distribution, Boltzmann's H-theorem, the time of relaxation, and aspects of classical statistical mechanics. Other subjects explored are related to the dynamics of ideal fluids, the dynamics of viscous and heat-conducting fluids, relativistic fluid flow, waves, shocks, winds, radiation and radiative transfer, the equations of radiation hydrodynamics, and radiating flows. Attention is given to small-amplitude disturbances, nonlinear flows, the interaction of radiation and matter, the solution of the transfer equation, acoustic waves, acoustic-gravity waves, basic concepts of special relativity, and equations of motion and energy.
Metal Carbon Eutectics to Extend the Use of the Fixed-Point Technique in Precision IR Thermometry
Battuello, M.; Girard, F.; Florio, M.
2008-06-01
The high-temperature extension of the fixed-point technique for primary calibration of precision infrared (IR) thermometers was investigated both through mathematical simulations and laboratory investigations. Simulations were performed with Co C (1,324°C) and Pd C (1, 492°C) eutectic fixed points, and a precision IR thermometer was calibrated from the In point (156.5985°C) up to the Co C point. Mathematical simulations suggested the possibility of directly deriving the transition temperature of the Co C and Pd C points by extrapolating the calibration derived from fixed-point measurements from In to the Cu point. Both temperatures, as a result of the low uncertainty associated with the In Cu calibration and the high number of fixed points involved in the calibration process, can be derived with an uncertainty of 0.11°C for Co C and 0.18°C for Pd C. A transition temperature of 1,324.3°C for Co C was determined from the experimental verification, a value higher than, but compatible with, the one proposed by the thermometry community for inclusion as a secondary reference point for ITS-90 dissemination, i.e., 1,324.0°C.
International Nuclear Information System (INIS)
Yamada, Takahiro; Maezawa, Masaaki; Urano, Chiharu
2015-01-01
Highlights: • We demonstrated RSFQ digital components of a new quantum voltage noise source. • A pseudo-random number generator and variable pulse number multiplier are designed. • Fabrication process is based on four Nb wiring layers and Nb/AlOx/Nb junctions. • The circuits successfully operated with wide dc bias current margins, 80–120%. - Abstract: We present design and testing of a pseudo-random number generator (PRNG) and a variable pulse number multiplier (VPNM) which are digital circuit subsystems in an integrated quantum voltage noise source for Jonson noise thermometry. Well-defined, calculable pseudo-random patterns of single flux quantum pulses are synthesized with the PRNG and multiplied digitally with the VPNM. The circuit implementation on rapid single flux quantum technology required practical circuit scales and bias currents, 279 junctions and 33 mA for the PRNG, and 1677 junctions and 218 mA for the VPNM. We confirmed the circuit operation with sufficiently wide margins, 80–120%, with respect to the designed bias currents.
Energy Technology Data Exchange (ETDEWEB)
Yamada, Takahiro, E-mail: yamada-takahiro@aist.go.jp [Nanoelectronics Research Institute, National Institute of Advanced Industrial Science and Technology, Central 2, Umezono 1-1-1, Tsukuba, Ibaraki 305-8568 (Japan); Maezawa, Masaaki [Nanoelectronics Research Institute, National Institute of Advanced Industrial Science and Technology, Central 2, Umezono 1-1-1, Tsukuba, Ibaraki 305-8568 (Japan); Urano, Chiharu [National Metrology Institute of Japan, National Institute of Advanced Industrial Science and Technology, Central 3, Umezono 1-1-1, Tsukuba, Ibaraki 305-8563 (Japan)
2015-11-15
Highlights: • We demonstrated RSFQ digital components of a new quantum voltage noise source. • A pseudo-random number generator and variable pulse number multiplier are designed. • Fabrication process is based on four Nb wiring layers and Nb/AlOx/Nb junctions. • The circuits successfully operated with wide dc bias current margins, 80–120%. - Abstract: We present design and testing of a pseudo-random number generator (PRNG) and a variable pulse number multiplier (VPNM) which are digital circuit subsystems in an integrated quantum voltage noise source for Jonson noise thermometry. Well-defined, calculable pseudo-random patterns of single flux quantum pulses are synthesized with the PRNG and multiplied digitally with the VPNM. The circuit implementation on rapid single flux quantum technology required practical circuit scales and bias currents, 279 junctions and 33 mA for the PRNG, and 1677 junctions and 218 mA for the VPNM. We confirmed the circuit operation with sufficiently wide margins, 80–120%, with respect to the designed bias currents.
Arunachalam, Kavitha; Maccarini, Paolo F; Stauffer, Paul R
2008-10-01
This paper presents a complete thermal analysis of a novel conformal surface thermometer design with directional sensitivity for real-time temperature monitoring during hyperthermia treatments of large superficial cancer. The thermal monitoring sheet (TMS) discussed in this paper consists of a 2-D array of fiberoptic sensors embedded between two layers of flexible, low-loss, and thermally conductive printed circuit board (PCB) film. Heat transfer across all interfaces from the tissue surface through multiple layers of insulating dielectrics surrounding the small buried temperature sensor and into an adjacent temperature-regulated water coupling bolus was studied using 3-D thermal simulation software. Theoretical analyses were carried out to identify the most effective differential TMS probe configuration possible with commercially available flexible PCB materials and to compare their thermal responses with omnidirectional probes commonly used in clinical hyperthermia. A TMS sensor design that employs 0.0508-mm Kapton MTB and 0.2032-mm Kapton HN flexible polyimide films is proposed for tissue surface thermometry with low influence from the adjacent waterbolus. Comparison of the thermal simulations with clinical probes indicates the new differential TMS probe design to outperform in terms of both transient response and steady-state accuracy in selectively reading the tissue surface temperature, while decreasing the overall thermal barrier of the probe between the coupling waterbolus and tissue surface.
Gu, Mingming
2018-01-08
The effects of moderate levels of chirp in the pump and Stokes pulses on chirped-probe-pulse femtosecond coherent anti-Stokes Raman scattering (CPP fs CARS) were investigated. The frequency chirp in the pump and Stokes pulses was introduced by placing SF11 glass disks with thicknesses of 10 mm or 20 mm in the optical path for these beams. The magnitude of the chirp in the probe beam was much greater and was induced by placing a 30-cm rod of SF10 glass in the beam path. The temperature measurements were performed in hydrogen/air non-premixed flames stabilized on a Hencken burner at equivalence ratios of 0.3, 0.5, 0.7, and 1.0. We performed measurements with no disks in pump and Stokes beam paths, and then with disks of 10 mm and 20 mm placed in both beam paths. The spectrum of the nonresonant background four-wave mixing signal narrowed considerably with increasing pump and Stokes chirp, while the resonant CARS signal was relatively unaffected. Consequently, the interference of the nonresonant background with the resonant CARS signal in the frequency-spread dephasing region of the spectrum was minimized. The increased rate of decay of the resonant CARS signal with increasing temperature was thus readily apparent. We have started to analyze the CPP fs CARS thermometry data and initial results indicate improved accuracy and precision are obtained due to moderate chirp in the pump and Stokes laser pulses.
Modulation infrared thermometry of caloric effects at up to kHz frequencies
Döntgen, Jago; Rudolph, Jörg; Waske, Anja; Hägele, Daniel
2018-03-01
We present a novel non-contact method for the direct measurement of caloric effects in low volume samples. The adiabatic temperature change ΔT of a magnetocaloric sample is very sensitively determined from thermal radiation. Rapid modulation of ΔT is induced by an oscillating external magnetic field. Detection of thermal radiation with a mercury-cadmium-telluride detector allows for measurements at field frequencies exceeding 1 kHz. In contrast to thermoacoustic methods, our method can be employed in vacuum which enhances adiabatic conditions especially in the case of small volume samples. Systematic measurements of the magnetocaloric effect as a function of temperature, magnetic field amplitude, and modulation frequency give a detailed picture of the thermal behavior of the sample. Highly sensitive measurements of the magnetocaloric effect are demonstrated on a 2 mm thick sample of gadolinium and a 60 μm thick Fe80B12Nb8 ribbon.
Biochemical thermodynamics: applications of Mathematica.
Alberty, Robert A
2006-01-01
The most efficient way to store thermodynamic data on enzyme-catalyzed reactions is to use matrices of species properties. Since equilibrium in enzyme-catalyzed reactions is reached at specified pH values, the thermodynamics of the reactions is discussed in terms of transformed thermodynamic properties. These transformed thermodynamic properties are complicated functions of temperature, pH, and ionic strength that can be calculated from the matrices of species values. The most important of these transformed thermodynamic properties is the standard transformed Gibbs energy of formation of a reactant (sum of species). It is the most important because when this function of temperature, pH, and ionic strength is known, all the other standard transformed properties can be calculated by taking partial derivatives. The species database in this package contains data matrices for 199 reactants. For 94 of these reactants, standard enthalpies of formation of species are known, and so standard transformed Gibbs energies, standard transformed enthalpies, standard transformed entropies, and average numbers of hydrogen atoms can be calculated as functions of temperature, pH, and ionic strength. For reactions between these 94 reactants, the changes in these properties can be calculated over a range of temperatures, pHs, and ionic strengths, and so can apparent equilibrium constants. For the other 105 reactants, only standard transformed Gibbs energies of formation and average numbers of hydrogen atoms at 298.15 K can be calculated. The loading of this package provides functions of pH and ionic strength at 298.15 K for standard transformed Gibbs energies of formation and average numbers of hydrogen atoms for 199 reactants. It also provides functions of temperature, pH, and ionic strength for the standard transformed Gibbs energies of formation, standard transformed enthalpies of formation, standard transformed entropies of formation, and average numbers of hydrogen atoms for 94
Thermodynamic Studies for Drug Design and Screening
Garbett, Nichola C.; Chaires, Jonathan B.
2012-01-01
Introduction A key part of drug design and development is the optimization of molecular interactions between an engineered drug candidate and its binding target. Thermodynamic characterization provides information about the balance of energetic forces driving binding interactions and is essential for understanding and optimizing molecular interactions. Areas covered This review discusses the information that can be obtained from thermodynamic measurements and how this can be applied to the drug development process. Current approaches for the measurement and optimization of thermodynamic parameters are presented, specifically higher throughput and calorimetric methods. Relevant literature for this review was identified in part by bibliographic searches for the period 2004 – 2011 using the Science Citation Index and PUBMED and the keywords listed below. Expert opinion The most effective drug design and development platform comes from an integrated process utilizing all available information from structural, thermodynamic and biological studies. Continuing evolution in our understanding of the energetic basis of molecular interactions and advances in thermodynamic methods for widespread application are essential to realize the goal of thermodynamically-driven drug design. Comprehensive thermodynamic evaluation is vital early in the drug development process to speed drug development towards an optimal energetic interaction profile while retaining good pharmacological properties. Practical thermodynamic approaches, such as enthalpic optimization, thermodynamic optimization plots and the enthalpic efficiency index, have now matured to provide proven utility in design process. Improved throughput in calorimetric methods remains essential for even greater integration of thermodynamics into drug design. PMID:22458502
Thermodynamic studies for drug design and screening.
Garbett, Nichola C; Chaires, Jonathan B
2012-04-01
A key part of drug design and development is the optimization of molecular interactions between an engineered drug candidate and its binding target. Thermodynamic characterization provides information about the balance of energetic forces driving binding interactions and is essential for understanding and optimizing molecular interactions. This review discusses the information that can be obtained from thermodynamic measurements and how this can be applied to the drug development process. Current approaches for the measurement and optimization of thermodynamic parameters are presented, specifically higher throughput and calorimetric methods. Relevant literature for this review was identified in part by bibliographic searches for the period 2004 - 2011 using the Science Citation Index and PUBMED and the keywords listed below. The most effective drug design and development platform comes from an integrated process utilizing all available information from structural, thermodynamic and biological studies. Continuing evolution in our understanding of the energetic basis of molecular interactions and advances in thermodynamic methods for widespread application are essential to realize the goal of thermodynamically driven drug design. Comprehensive thermodynamic evaluation is vital early in the drug development process to speed drug development toward an optimal energetic interaction profile while retaining good pharmacological properties. Practical thermodynamic approaches, such as enthalpic optimization, thermodynamic optimization plots and the enthalpic efficiency index, have now matured to provide proven utility in the design process. Improved throughput in calorimetric methods remains essential for even greater integration of thermodynamics into drug design. © 2012 Informa UK, Ltd.
Directory of Open Access Journals (Sweden)
Martin Adámek
2016-12-01
Full Text Available The characterization and monitoring of thermal processes in thermodynamic systems can be performed using the thermodynamic sensors (TDS. The basic idea of thermodynamic sensor is possible to use in many various applications (eq. monitoring of frictional heat, thermal radiation, pollution of cleaning fluid, etc.. One of application areas, where the thermodynamic sensor can find the new area for a using, is a production of milk products - cheese, yogurt, kefir, etc. This paper describes the estimated possibilities, advantages and disadvantages of the use of thermodynamic sensors in diary productions and simple experiments for characterization and monitoring of basic operations in milk production process by thermodynamic sensors. The milk products are often realized by fermenting or renneting process. Final stages of fermentation and renneting processes are often determined on the base of sensory evaluation, pH measurement or by analytical method. The exact time of the fermentation process completion is dependent on various parameters and is often the company know-how. The fast, clean and simple non-analytical non-contact method for monitoring and for the determination of process final stages does not exist in this time. Tests of fermentation process, renneting process and yoghurt process by thermodynamic sensors were characterized and measured in this work. Measurement of activity yeasts was tested in first series of experiments. In second series of experiments, measurement of processes in milk production was tested. First results of simple experiments show that the thermodynamic sensors might be used for determination of time behaviour of these processes. Therefore, the milk products (cheese, yogurt, kefir, etc. is opened as a one of new application areas, where the thermodynamic sensor can be used.
Thermodynamics for Chemists, Physicists and Engineers
Hołyst, Robert
2012-01-01
Thermodynamics is an essential part of chemical physics and is of fundamental importance in physics, chemistry and engineering courses. This textbook takes an interdisciplinary approach to the subject and is therefore suitable for undergraduates in all those courses. The book is an introduction to phenomenological thermodynamics and its applications to phase transitions and chemical reactions, with some references to statistical mechanics. It strikes the balance between the rigorousness of the Callen text and phenomenological approach of the Atkins text. The book is divided in three parts. The first introduces the postulates and laws of thermodynamics and complements these initial explanations with practical examples. The second part is devoted to applications of thermodynamics to phase transitions in pure substances and mixtures. The third part covers thermodynamic systems in which chemical reactions take place. There are some sections on more advanced topics such as thermodynamic potentials, natural variabl...
Geometric description of BTZ black hole thermodynamics
International Nuclear Information System (INIS)
Quevedo, Hernando; Sanchez, Alberto
2009-01-01
We study the properties of the space of thermodynamic equilibrium states of the Banados-Teitelboim-Zanelli (BTZ) black hole in (2+1) gravity. We use the formalism of geometrothermodynamics to introduce in the space of equilibrium states a two-dimensional thermodynamic metric whose curvature is nonvanishing, indicating the presence of thermodynamic interaction, and free of singularities, indicating the absence of phase transitions. Similar results are obtained for generalizations of the BTZ black hole which include a Chern-Simons term and a dilatonic field. Small logarithmic corrections of the entropy turn out to be represented by small corrections of the thermodynamic curvature, reinforcing the idea that thermodynamic curvature is a measure of thermodynamic interaction.
Microbial diversity arising from thermodynamic constraints
Großkopf, Tobias; Soyer, Orkun S
2016-01-01
The microbial world displays an immense taxonomic diversity. This diversity is manifested also in a multitude of metabolic pathways that can utilise different substrates and produce different products. Here, we propose that these observations directly link to thermodynamic constraints that inherently arise from the metabolic basis of microbial growth. We show that thermodynamic constraints can enable coexistence of microbes that utilise the same substrate but produce different end products. We find that this thermodynamics-driven emergence of diversity is most relevant for metabolic conversions with low free energy as seen for example under anaerobic conditions, where population dynamics is governed by thermodynamic effects rather than kinetic factors such as substrate uptake rates. These findings provide a general understanding of the microbial diversity based on the first principles of thermodynamics. As such they provide a thermodynamics-based framework for explaining the observed microbial diversity in different natural and synthetic environments. PMID:27035705
Microbial diversity arising from thermodynamic constraints.
Großkopf, Tobias; Soyer, Orkun S
2016-11-01
The microbial world displays an immense taxonomic diversity. This diversity is manifested also in a multitude of metabolic pathways that can utilise different substrates and produce different products. Here, we propose that these observations directly link to thermodynamic constraints that inherently arise from the metabolic basis of microbial growth. We show that thermodynamic constraints can enable coexistence of microbes that utilise the same substrate but produce different end products. We find that this thermodynamics-driven emergence of diversity is most relevant for metabolic conversions with low free energy as seen for example under anaerobic conditions, where population dynamics is governed by thermodynamic effects rather than kinetic factors such as substrate uptake rates. These findings provide a general understanding of the microbial diversity based on the first principles of thermodynamics. As such they provide a thermodynamics-based framework for explaining the observed microbial diversity in different natural and synthetic environments.
Thermodynamic study of selected monoterpenes III
International Nuclear Information System (INIS)
Štejfa, Vojtěch; Fulem, Michal; Růžička, Květoslav; Červinka, Ctirad
2014-01-01
Highlights: • (−)-trans-Pinane, (+)-Δ-carene, eucalyptol, and limonene were studied. • New thermodynamic data were measured and calculated. • Many of thermodynamic data are reported for the first time. - Abstract: A thermodynamic study of selected monoterpenes, (−)-trans-pinane, (+)-Δ-carene, eucalyptol, (+)-limonene, and (−)-limonene, is presented in this work. The vapor pressure measurements were performed using the static method over the environmentally important temperature range (238 to 308) K. Liquid heat capacities were measured by Tian–Calvet calorimetry in the temperature interval (258 to 355) K. The phase behavior was investigated by differential scanning calorimetry (DSC) from T = 183 K. The thermodynamic properties in the ideal-gas state were calculated by combining statistical thermodynamic and density functional theory (DFT) calculations. Calculated ideal-gas heat capacities and experimental data for vapor pressures and condensed phase heat capacities were treated simultaneously to obtain a consistent thermodynamic description
Thermodynamics of random reaction networks.
Directory of Open Access Journals (Sweden)
Jakob Fischer
Full Text Available Reaction networks are useful for analyzing reaction systems occurring in chemistry, systems biology, or Earth system science. Despite the importance of thermodynamic disequilibrium for many of those systems, the general thermodynamic properties of reaction networks are poorly understood. To circumvent the problem of sparse thermodynamic data, we generate artificial reaction networks and investigate their non-equilibrium steady state for various boundary fluxes. We generate linear and nonlinear networks using four different complex network models (Erdős-Rényi, Barabási-Albert, Watts-Strogatz, Pan-Sinha and compare their topological properties with real reaction networks. For similar boundary conditions the steady state flow through the linear networks is about one order of magnitude higher than the flow through comparable nonlinear networks. In all networks, the flow decreases with the distance between the inflow and outflow boundary species, with Watts-Strogatz networks showing a significantly smaller slope compared to the three other network types. The distribution of entropy production of the individual reactions inside the network follows a power law in the intermediate region with an exponent of circa -1.5 for linear and -1.66 for nonlinear networks. An elevated entropy production rate is found in reactions associated with weakly connected species. This effect is stronger in nonlinear networks than in the linear ones. Increasing the flow through the nonlinear networks also increases the number of cycles and leads to a narrower distribution of chemical potentials. We conclude that the relation between distribution of dissipation, network topology and strength of disequilibrium is nontrivial and can be studied systematically by artificial reaction networks.
Thermodynamics of random reaction networks.
Fischer, Jakob; Kleidon, Axel; Dittrich, Peter
2015-01-01
Reaction networks are useful for analyzing reaction systems occurring in chemistry, systems biology, or Earth system science. Despite the importance of thermodynamic disequilibrium for many of those systems, the general thermodynamic properties of reaction networks are poorly understood. To circumvent the problem of sparse thermodynamic data, we generate artificial reaction networks and investigate their non-equilibrium steady state for various boundary fluxes. We generate linear and nonlinear networks using four different complex network models (Erdős-Rényi, Barabási-Albert, Watts-Strogatz, Pan-Sinha) and compare their topological properties with real reaction networks. For similar boundary conditions the steady state flow through the linear networks is about one order of magnitude higher than the flow through comparable nonlinear networks. In all networks, the flow decreases with the distance between the inflow and outflow boundary species, with Watts-Strogatz networks showing a significantly smaller slope compared to the three other network types. The distribution of entropy production of the individual reactions inside the network follows a power law in the intermediate region with an exponent of circa -1.5 for linear and -1.66 for nonlinear networks. An elevated entropy production rate is found in reactions associated with weakly connected species. This effect is stronger in nonlinear networks than in the linear ones. Increasing the flow through the nonlinear networks also increases the number of cycles and leads to a narrower distribution of chemical potentials. We conclude that the relation between distribution of dissipation, network topology and strength of disequilibrium is nontrivial and can be studied systematically by artificial reaction networks.
Thermodynamics and life span estimation
International Nuclear Information System (INIS)
Kuddusi, Lütfullah
2015-01-01
In this study, the life span of people living in seven regions of Turkey is estimated by applying the first and second laws of thermodynamics to the human body. The people living in different regions of Turkey have different food habits. The first and second laws of thermodynamics are used to calculate the entropy generation rate per unit mass of a human due to the food habits. The lifetime entropy generation per unit mass of a human was previously found statistically. The two entropy generations, lifetime entropy generation and entropy generation rate, enable one to determine the life span of people living in seven regions of Turkey with different food habits. In order to estimate the life span, some statistics of Turkish Statistical Institute regarding the food habits of the people living in seven regions of Turkey are used. The life spans of people that live in Central Anatolia and Eastern Anatolia regions are the longest and shortest, respectively. Generally, the following inequality regarding the life span of people living in seven regions of Turkey is found: Eastern Anatolia < Southeast Anatolia < Black Sea < Mediterranean < Marmara < Aegean < Central Anatolia. - Highlights: • The first and second laws of thermodynamics are applied to the human body. • The entropy generation of a human due to his food habits is determined. • The life span of Turks is estimated by using the entropy generation method. • Food habits of a human have effect on his life span
Relativistic thermodynamics of Fluids. l
International Nuclear Information System (INIS)
Havas, P.; Swenson, R.J.
1979-01-01
In 1953, Stueckelberg and Wanders derived the basic laws of relativistic linear nonequilibrium thermodynamics for chemically reacting fluids from the relativistic local conservation laws for energy-momentum and the local laws of production of substances and of nonnegative entropy production by the requirement that the corresponding currents (assumed to depend linearly on the derivatives of the state variables) should not be independent. Generalizing their method, we determine the most general allowed form of the energy-momentum tensor T/sup alphabeta/ and of the corresponding rate of entropy production under the same restriction on the currents. The problem of expressing this rate in terms of thermodynamic forces and fluxes is discussed in detail; it is shown that the number of independent forces is not uniquely determined by the theory, and seven possibilities are explored. A number of possible new cross effects are found, all of which persist in the Newtonian (low-velocity) limit. The treatment of chemical reactions is incorporated into the formalism in a consistent manner, resulting in a derivation of the law for rate of production, and in relating this law to transport processes differently than suggested previously. The Newtonian limit is discussed in detail to establish the physical interpretation of the various terms of T/sup alphabeta/. In this limit, the interpretation hinges on that of the velocity field characterizing the fluid. If it is identified with the average matter velocity following from a consideration of the number densities, the usual local conservation laws of Newtonian nonequilibrium thermodynamics are obtained, including that of mass. However, a slightly different identification allows conversion of mass into energy even in this limit, and thus a macroscopic treatment of nuclear or elementary particle reactions. The relation of our results to previous work is discussed in some detail
Thermodynamic control of anvil cloud amount
Bony, Sandrine; Stevens, Bjorn; Coppin, David; Becker, Tobias; Reed, Kevin A.; Voigt, Aiko
2016-01-01
General circulation models show that as the surface temperature increases, the convective anvil clouds shrink. By analyzing radiative–convective equilibrium simulations, we show that this behavior is rooted in basic energetic and thermodynamic properties of the atmosphere: As the climate warms, the clouds rise and remain at nearly the same temperature, but find themselves in a more stable atmosphere; this enhanced stability reduces the convective outflow in the upper troposphere and decreases the anvil cloud fraction. By warming the troposphere and increasing the upper-tropospheric stability, the clustering of deep convection also reduces the convective outflow and the anvil cloud fraction. When clouds are radiatively active, this robust coupling between temperature, high clouds, and circulation exerts a positive feedback on convective aggregation and favors the maintenance of strongly aggregated atmospheric states at high temperatures. This stability iris mechanism likely contributes to the narrowing of rainy areas as the climate warms. Whether or not it influences climate sensitivity requires further investigation. PMID:27412863
Thermodynamic Upper Bound on Broadband Light Coupling with Photonic Structures
Yu, Zongfu
2012-10-01
The coupling between free space radiation and optical media critically influences the performance of optical devices. We show that, for any given photonic structure, the sum of the external coupling rates for all its optical modes are subject to an upper bound dictated by the second law of thermodynamics. Such bound limits how efficient light can be coupled to any photonic structure. As one example of application, we use this upper bound to derive the limit of light absorption in broadband solar absorbers. © 2012 American Physical Society.
Thermodynamic Studies to Support Actinide/Lanthanide Separations
Energy Technology Data Exchange (ETDEWEB)
Rao, Linfeng [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
2016-09-04
Thermodynamic data on the complexation of Np(V) with HEDTA in a wide pH region were re-modeled by including a dimeric complex species, (NpO_{2})_{2}(OH)_{2}L_{2}^{6-} where L^{3-} stands for the fully deprotonated HEDTA ligand and better fits were achieved for the spectrophotometric data. The presence of the dimeric complex species in high pH region was verified for the first time by the EXAFS experiments at Stanford Synchrotron Radiation Laboratory (SSRL).
Thermodynamic limit for coherence-limited solar power conversion
Mashaal, Heylal; Gordon, Jeffrey M.
2014-09-01
The spatial coherence of solar beam radiation is a key constraint in solar rectenna conversion. Here, we present a derivation of the thermodynamic limit for coherence-limited solar power conversion - an expansion of Landsberg's elegant basic bound, originally limited to incoherent converters at maximum flux concentration. First, we generalize Landsberg's work to arbitrary concentration and angular confinement. Then we derive how the values are further lowered for coherence-limited converters. The results do not depend on a particular conversion strategy. As such, they pertain to systems that span geometric to physical optics, as well as classical to quantum physics. Our findings indicate promising potential for solar rectenna conversion.
Semiclassical Loop Quantum Gravity and Black Hole Thermodynamics
Directory of Open Access Journals (Sweden)
Arundhati Dasgupta
2013-02-01
Full Text Available In this article we explore the origin of black hole thermodynamics using semiclassical states in loop quantum gravity. We re-examine the case of entropy using a density matrix for a coherent state and describe correlations across the horizon due to SU(2 intertwiners. We further show that Hawking radiation is a consequence of a non-Hermitian term in the evolution operator, which is necessary for entropy production or depletion at the horizon. This non-unitary evolution is also rooted in formulations of irreversible physics.
Thermodynamic Studies to Support Actinide/Lanthanide Separations
International Nuclear Information System (INIS)
Rao, Linfeng
2016-01-01
Thermodynamic data on the complexation of Np(V) with HEDTA in a wide pH region were re-modeled by including a dimeric complex species, (NpO 2 ) 2 (OH) 2 L 2 ^{6-} where L 3- stands for the fully deprotonated HEDTA ligand and better fits were achieved for the spectrophotometric data. The presence of the dimeric complex species in high pH region was verified for the first time by the EXAFS experiments at Stanford Synchrotron Radiation Laboratory (SSRL).
Thermodynamics inducing massive particles' tunneling and cosmic censorship
International Nuclear Information System (INIS)
Zhang, Baocheng; Cai, Qing-yu; Zhan, Ming-sheng
2010-01-01
By calculating the change of entropy, we prove that the first law of black hole thermodynamics leads to the tunneling probability of massive particles through the horizon, including the tunneling probability of massive charged particles from the Reissner-Nordstroem black hole and the Kerr-Newman black hole. Novelly, we find the trajectories of massive particles are close to that of massless particles near the horizon, although the trajectories of massive charged particles may be affected by electromagnetic forces. We show that Hawking radiation as massive particles tunneling does not lead to violation of the weak cosmic-censorship conjecture. (orig.)
Thermodynamics inducing massive particles' tunneling and cosmic censorship
Energy Technology Data Exchange (ETDEWEB)
Zhang, Baocheng [Chinese Academy of Sciences, State Key Laboratory of Magnetic Resonances and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, Wuhan (China); Graduate University of Chinese Academy of Sciences, Beijing (China); Cai, Qing-yu [Chinese Academy of Sciences, State Key Laboratory of Magnetic Resonances and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, Wuhan (China); Zhan, Ming-sheng [Chinese Academy of Sciences, State Key Laboratory of Magnetic Resonances and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, Wuhan (China); Chinese Academy of Sciences, Center for Cold Atom Physics, Wuhan (China)
2010-08-15
By calculating the change of entropy, we prove that the first law of black hole thermodynamics leads to the tunneling probability of massive particles through the horizon, including the tunneling probability of massive charged particles from the Reissner-Nordstroem black hole and the Kerr-Newman black hole. Novelly, we find the trajectories of massive particles are close to that of massless particles near the horizon, although the trajectories of massive charged particles may be affected by electromagnetic forces. We show that Hawking radiation as massive particles tunneling does not lead to violation of the weak cosmic-censorship conjecture. (orig.)
An introduction to statistical thermodynamics
Hill, Terrell L
1987-01-01
""A large number of exercises of a broad range of difficulty make this book even more useful…a good addition to the literature on thermodynamics at the undergraduate level."" - Philosophical MagazineAlthough written on an introductory level, this wide-ranging text provides extensive coverage of topics of current interest in equilibrium statistical mechanics. Indeed, certain traditional topics are given somewhat condensed treatment to allow room for a survey of more recent advances.The book is divided into four major sections. Part I deals with the principles of quantum statistical mechanics a
Thermodynamic basis for cluster kinetics
DEFF Research Database (Denmark)
Hu, Lina; Bian, Xiufang; Qin, Xubo
2006-01-01
Due to the inaccessibility of the supercooled region of marginal metallic glasses (MMGs) within the experimental time window, we study the cluster kinetics above the liquidus temperature, Tl, to acquire information on the fragility of the MMG systems. Thermodynamic basis for the stability...... of locally ordered structure in the MMG liquids is discussed in terms of the two-order-parameter model. It is found that the Arrhenius activation energy of clusters, h, is proportional to the chemical mixing enthalpy of alloys, Hchem. Fragility of the MMG forming liquids can be described by the ratio...
Thermodynamics of the hot BIon
DEFF Research Database (Denmark)
Grignani, Gianluca; Harmark, Troels; Marini, Andrea
2011-01-01
We investigate the thermodynamics of the recently obtained nite temperature BIon solution of arXiv:1012.1494, focusing on two aspects. The first concerns comparison of the free energy of the three available phases for the finite temperature brane-antibrane wormhole configuration. Based on this we...... propose a heuristic picture for the dynamics of the phases that involves a critical temperature below which a stable phase exists. This stable phase is the finite temperature analogue of the thin throat branch of the extremal brane anti-brane wormhole configuration. The second aspect that we consider...
Thermodynamic data for uranium fluorides
Energy Technology Data Exchange (ETDEWEB)
Leitnaker, J.M.
1983-03-01
Self-consistent thermodynamic data have been tabulated for uranium fluorides between UF/sub 4/ and UF/sub 6/, including UF/sub 4/ (solid and gas), U/sub 4/F/sub 17/ (solid), U/sub 2/F/sub 9/ (solid), UF/sub 5/ (solid and gas), U/sub 2/F/sub 10/ (gas), and UF/sub 6/ (solid, liquid, and gas). Included are thermal function - the heat capacity, enthalpy, and free energy function, heats of formation, and vaporization behavior.
Some problems in relativistic thermodynamics
International Nuclear Information System (INIS)
Veitsman, E. V.
2007-01-01
The relativistic equations of state for ideal and real gases, as well as for various interface regions, have been derived. These dependences help to eliminate some controversies in the relativistic thermodynamics based on the special theory of relativity. It is shown, in particular, that the temperature of system whose velocity tends to the velocity of light in vacuum varies in accordance with the Ott law T = T 0 /√1 - v 2 /c 2 . Relativistic dependences for heat and mass transfer, for Ohm's law, and for a viscous flow of a liquid have also been derived
Thermodynamic laws in isolated systems.
Hilbert, Stefan; Hänggi, Peter; Dunkel, Jörn
2014-12-01
The recent experimental realization of exotic matter states in isolated quantum systems and the ensuing controversy about the existence of negative absolute temperatures demand a careful analysis of the conceptual foundations underlying microcanonical thermostatistics. Here we provide a detailed comparison of the most commonly considered microcanonical entropy definitions, focusing specifically on whether they satisfy or violate the zeroth, first, and second laws of thermodynamics. Our analysis shows that, for a broad class of systems that includes all standard classical Hamiltonian systems, only the Gibbs volume entropy fulfills all three laws simultaneously. To avoid ambiguities, the discussion is restricted to exact results and analytically tractable examples.
Unified geometric description of black hole thermodynamics
International Nuclear Information System (INIS)
Alvarez, Jose L.; Quevedo, Hernando; Sanchez, Alberto
2008-01-01
In the space of thermodynamic equilibrium states we introduce a Legendre invariant metric which contains all the information about the thermodynamics of black holes. The curvature of this thermodynamic metric becomes singular at those points where, according to the analysis of the heat capacities, phase transitions occur. This result is valid for the Kerr-Newman black hole and all its special cases and, therefore, provides a unified description of black hole phase transitions in terms of curvature singularities.
Stochastic deformation of a thermodynamic symplectic structure
Kazinski, P. O.
2008-01-01
A stochastic deformation of a thermodynamic symplectic structure is studied. The stochastic deformation procedure is analogous to the deformation of an algebra of observables like deformation quantization, but for an imaginary deformation parameter (the Planck constant). Gauge symmetries of thermodynamics and corresponding stochastic mechanics, which describes fluctuations of a thermodynamic system, are revealed and gauge fields are introduced. A physical interpretation to the gauge transform...
Irreversible thermodynamics of Poisson processes with reaction.
Méndez, V; Fort, J
1999-11-01
A kinetic model is derived to study the successive movements of particles, described by a Poisson process, as well as their generation. The irreversible thermodynamics of this system is also studied from the kinetic model. This makes it possible to evaluate the differences between thermodynamical quantities computed exactly and up to second-order. Such differences determine the range of validity of the second-order approximation to extended irreversible thermodynamics.
Thermodynamics of Enzyme-Catalyzed Reactions Database
SRD 74 Thermodynamics of Enzyme-Catalyzed Reactions Database (Web, free access) The Thermodynamics of Enzyme-Catalyzed Reactions Database contains thermodynamic data on enzyme-catalyzed reactions that have been recently published in the Journal of Physical and Chemical Reference Data (JPCRD). For each reaction the following information is provided: the reference for the data, the reaction studied, the name of the enzyme used and its Enzyme Commission number, the method of measurement, the data and an evaluation thereof.
Thermodynamically consistent model calibration in chemical kinetics
Directory of Open Access Journals (Sweden)
Goutsias John
2011-05-01
Full Text Available Abstract Background The dynamics of biochemical reaction systems are constrained by the fundamental laws of thermodynamics, which impose well-defined relationships among the reaction rate constants characterizing these systems. Constructing biochemical reaction systems from experimental observations often leads to parameter values that do not satisfy the necessary thermodynamic constraints. This can result in models that are not physically realizable and may lead to inaccurate, or even erroneous, descriptions of cellular function. Results We introduce a thermodynamically consistent model calibration (TCMC method that can be effectively used to provide thermodynamically feasible values for the parameters of an open biochemical reaction system. The proposed method formulates the model calibration problem as a constrained optimization problem that takes thermodynamic constraints (and, if desired, additional non-thermodynamic constraints into account. By calculating thermodynamically feasible values for the kinetic parameters of a well-known model of the EGF/ERK signaling cascade, we demonstrate the qualitative and quantitative significance of imposing thermodynamic constraints on these parameters and the effectiveness of our method for accomplishing this important task. MATLAB software, using the Systems Biology Toolbox 2.1, can be accessed from http://www.cis.jhu.edu/~goutsias/CSS lab/software.html. An SBML file containing the thermodynamically feasible EGF/ERK signaling cascade model can be found in the BioModels database. Conclusions TCMC is a simple and flexible method for obtaining physically plausible values for the kinetic parameters of open biochemical reaction systems. It can be effectively used to recalculate a thermodynamically consistent set of parameter values for existing thermodynamically infeasible biochemical reaction models of cellular function as well as to estimate thermodynamically feasible values for the parameters of new
Quantum thermodynamics: a nonequilibrium Green's function approach.
Esposito, Massimiliano; Ochoa, Maicol A; Galperin, Michael
2015-02-27
We establish the foundations of a nonequilibrium theory of quantum thermodynamics for noninteracting open quantum systems strongly coupled to their reservoirs within the framework of the nonequilibrium Green's functions. The energy of the system and its coupling to the reservoirs are controlled by a slow external time-dependent force treated to first order beyond the quasistatic limit. We derive the four basic laws of thermodynamics and characterize reversible transformations. Stochastic thermodynamics is recovered in the weak coupling limit.
The energy balance of a plasma in partial local thermodynamic equilibrium
Kroesen, G.M.W.; Schram, D.C.; Timmermans, C.J.; de Haas, J.C.M.
1990-01-01
The energy balance for electrons and heavy particles constituting a plasma in partial local thermodynamic equilibrium is derived. The formulation of the energy balance used allows for evaluation of the source terms without knowledge of the particle and radiation transport situation, since most of
Yourgrau, Wolfgang; Raw, Gough
2002-01-01
Extensively revised edition of a much-respected work examines thermodynamics of irreversible processes, general principles of statistical thermodynamics, assemblies of noninteracting structureless particles, and statistical theory. 1966 edition.
Exergy of partially coherent thermal radiation
International Nuclear Information System (INIS)
Wijewardane, S.; Goswami, Yogi
2012-01-01
Exergy of electromagnetic radiation has been studied by a number of researchers for well over four decades in order to estimate the maximum conversion efficiencies of thermal radiation. As these researchers primarily dealt with solar and blackbody radiation, which have a low degree of coherence, they did not consider the partial coherence properties of thermal radiation. With the recent development of surface structures, which can emit radiation with high degree of coherence, the importance of considering the partial coherent properties in exergy calculation has become a necessity as the coherence properties directly influence the entropy of the wave field. Here in this paper we derive an expression for the exergy of quasi-monochromatic radiation using statistical thermodynamics and show that it is identical with the expressions derived using classical thermodynamics. We also present a method to calculate the entropy, thereby the exergy of partially coherent radiation using statistical thermodynamics and a method called matrix treatment of wave field. -- Highlights: ► Considered partial coherence of radiation for the first time to calculate exergy. ► The importance of this method is emphasized with energy conversion examples. ► Derived an expression for the exergy of radiation using statistical thermodynamics. ► Adopted a method to calculate intensity of statistically independent principle wave.
Surface dependency in thermodynamics of ideal gases
International Nuclear Information System (INIS)
Sisman, Altug
2004-01-01
The Casimir-like size effect rises in ideal gases confined in a finite domain due to the wave character of atoms. By considering this effect, thermodynamic properties of an ideal gas confined in spherical and cylindrical geometries are derived and compared with those in rectangular geometry. It is seen that an ideal gas exhibits an unavoidable quantum surface free energy and surface over volume ratio becomes a control variable on thermodynamic state functions in microscale. Thermodynamics turns into non-extensive thermodynamics and geometry difference becomes a driving force since the surface over volume ratio depends on the geometry
Coherence and measurement in quantum thermodynamics.
Kammerlander, P; Anders, J
2016-02-26
Thermodynamics is a highly successful macroscopic theory widely used across the natural sciences and for the construction of everyday devices, from car engines to solar cells. With thermodynamics predating quantum theory, research now aims to uncover the thermodynamic laws that govern finite size systems which may in addition host quantum effects. Recent theoretical breakthroughs include the characterisation of the efficiency of quantum thermal engines, the extension of classical non-equilibrium fluctuation theorems to the quantum regime and a new thermodynamic resource theory has led to the discovery of a set of second laws for finite size systems. These results have substantially advanced our understanding of nanoscale thermodynamics, however putting a finger on what is genuinely quantum in quantum thermodynamics has remained a challenge. Here we identify information processing tasks, the so-called projections, that can only be formulated within the framework of quantum mechanics. We show that the physical realisation of such projections can come with a non-trivial thermodynamic work only for quantum states with coherences. This contrasts with information erasure, first investigated by Landauer, for which a thermodynamic work cost applies for classical and quantum erasure alike. Repercussions on quantum work fluctuation relations and thermodynamic single-shot approaches are also discussed.
Radiative relativistic shock adiabate
International Nuclear Information System (INIS)
Tsintsadze, L.N.; Nishikawa, K.
1997-01-01
The influences of thermal radiation on the state equation of shock waves, derived in the previous paper [L. N. Tsintsadze, Phys. Plasmas 2, 4462 (1995)], are studied and a series of relations of thermodynamic quantities that hold for shock waves are derived. It is shown that the presence of radiation can strongly change the compressibility of the plasma. It is well known that for polytropic gases the compressibility cannot change more than four times the initial value in the case of nonrelativistic temperatures. The numerical calculations show that there are no such restrictions, when the radiation energy exceeds the kinetic energy of the plasma. The ultrarelativistic temperature range is also covered in our numerical calculations. Also studied are the influences of the radiation on the PT and the TV diagrams. A significant modification due to radiation is found in every case studied. copyright 1997 American Institute of Physics
Thermodynamic studies on charge-coupled substituted synthetic monazite
Energy Technology Data Exchange (ETDEWEB)
Rawat, D. [Product Development Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400085 (India); Phapale, S. [Chemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400085 (India); Mishra, R., E-mail: mishrar@barc.gov.in [Chemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400085 (India); Dash, S. [Product Development Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400085 (India)
2017-04-15
Phosphate-based monazite ceramic is considered worldwide as a potential crystalline host matrix for immobilization of long-lived tri- and tetra-valent actinides present in high-level nuclear waste. Monazite is chemically stable with respect to the leaching processes and has high radiation stability. The present paper describes the influence of charged coupled (Ca{sup 2+}, Th{sup 4+}) substitution in place of La{sup 3+} on thermodynamic stability of synthetic monazite ceramics. XRD-analysis of Ca, Th substituted LaPO{sub 4} viz., La{sub 1-x}Ca{sub x/2}Th{sub x/2}PO{sub 4} (0 ≤ x ≤ 1) points to the formation of ideal solid-solution in the entire range of composition. However, thermodynamic analysis indicates deviation from ideal solid-solution with a minima at x = 0.25. The substituted La{sub 1-x}Ca{sub x/2}Th{sub x/2}PO{sub 4} system is found to be iso-entropic and stabilized mainly by enthalpy. Enthalpies of formation as a function of Ca{sup 2+}, Th{sup 4+} substitution were analysed to provide insights into the development of thermodynamically stable nuclear waste matrix.
Determining Cloud Thermodynamic Phase from Micropulse Lidar Network Data
Lewis, Jasper R.; Campbell, James; Lolli, Simone; Tan, Ivy; Welton, Ellsworth J.
2017-01-01
Determining cloud thermodynamic phase is a critical factor in studies of Earth's radiation budget. Here we use observations from the NASA Micro Pulse Lidar Network (MPLNET) and thermodynamic profiles from the Goddard Earth Observing System, version 5 (GEOS-5) to distinguish liquid water, mixed-phase, and ice water clouds. The MPLNET provides sparse global, autonomous, and continuous measurements of clouds and aerosols which have been used in a number of scientific investigations to date. The use of a standardized instrument and a common suite of data processing algorithms with thorough uncertainty characterization allows for straightforward comparisons between sites. Lidars with polarization capabilities have recently been incorporated into the MPLNET project which allows, for the first time, the ability to infer a cloud thermodynamic phase. This presentation will look specifically at the occurrence of ice and mixed phase clouds in the temperature region of -10 C to -40 C for different climatological regions and seasons. We compare MPLNET occurrences of mixed-phase clouds to an historical climatology based on observations from the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) instrument aboard the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) spacecraft.
Liu, Lei; Xiao, Yilin; Wörner, G.; Kronz, A.; Simon, K.; Hou, Zhenhui
2014-08-01
This study explores the potential of detrital rutile geochemistry and thermometry as a provenance tracer in rocks from the Central Dabie ultrahigh-pressure metamorphic (UHPM) zone in east-central China that formed during Triassic continental collision. Trace element data of 176 detrital rutile grains selected from local river sediments and 91 rutile grains from distinct bedrocks in the Shuanghe and Bixiling areas, obtained by both electron microprobe (EMP) and in situ LA-ICP-MS analyses, suggest that geochemical compositions and thermometry of detrital rutiles are comparable to those from their potential source rocks. After certification of the Cr-Nb discrimination method for the Central Dabie UHPM zone, we show that 29% of the detrital rutiles in the Shuanghe area were derived from metamafic sources whereas in the Bixiling area that it is up to 76%. Furthermore, the proportion of distinct types of detrital rutiles combined with modal abundances of rutile in metapelites and metamafic bedrocks can be used to estimate the proportion of different source lithologies. Based on this method the proportion of mafic source rocks was estimated to ∼10% at Shuanghe and >60% at Bixiling, respectively, which is consistent with the proportions of eclogite (the major rutile-bearing metamafic rock) distribution in the field. Therefore, the investigation of detrital rutiles is a potential way to evaluate the proportion of metamafic rocks and even to prospect for metamafic bodies in UHPM terranes. Zr-in-rutile temperatures were calculated at different pressures and compared with temperatures derived from rock-in rutiles and garnet-clinopyroxene Fe-Mg thermometers. Temperatures calculated for detrital rutiles range from 606 °C to 707 °C and 566 °C to 752 °C in Shuanghe and Bixiling, respectively, at P = 3 GPa with an average temperatures of ca. 630 °C for both areas. These temperature averages and ranges are similar to those calculated for rutiles from surrounding source rocks
Thermodynamic features of dioxins’ adsorption
Energy Technology Data Exchange (ETDEWEB)
Prisciandaro, Marina [Department of Industrial and Information Engineering and of Economics, University of L’Aquila, Viale Giovanni Gronchi 18, L’Aquila 67100 (Italy); Piemonte, Vincenzo, E-mail: v.piemonte@unicampus.it [Faculty of Engineering, University Campus Biomedico of Rome, Via Alvaro del Portillo 21, Rome 00128 (Italy); Mazziotti di Celso, Giuseppe [Faculty of Bioscience, University of Teramo, Via R. Balzarini, 1, 64100 Teramo (Italy); Ronconi, Silvia [Arta Abruzzo, Department of L’Aquila, Bazzano (AQ), 67100 L’Aquila (Italy); Capocelli, Mauro [Faculty of Engineering, University Campus Biomedico of Rome, Via Alvaro del Portillo 21, Rome 00128 (Italy)
2017-02-15
Highlights: • We develop the P-T diagram for six PCDD. • We derive theoretical adsorption isotherms according to the Langmuir’s model. • We calculate K and w{sub max} values for several temperatures. • We estimate the adsorption heat with a good agreement with literature data. - Abstract: In this paper, the six more poisonous species among all congeners of dioxin group are taken into account, and the P-T diagram for each of them is developed. Starting from the knowledge of vapour tensions and thermodynamic parameters, the theoretical adsorption isotherms are calculated according to the Langmuir’s model. In particular, the Langmuir isotherm parameters (K and w{sub max}) have been validated through the estimation of the adsorption heat (ΔH{sub ads}), which varies in the range 20–24 kJ/mol, in agreement with literature values. This result will allow to put the thermodynamical basis for a rational design of different process units devoted to dioxins removal.
Bioengineering thermodynamics of biological cells.
Lucia, Umberto
2015-12-01
Cells are open complex thermodynamic systems. They can be also regarded as complex engines that execute a series of chemical reactions. Energy transformations, thermo-electro-chemical processes and transports phenomena can occur across the cells membranes. Moreover, cells can also actively modify their behaviours in relation to changes in their environment. Different thermo-electro-biochemical behaviours occur between health and disease states. But, all the living systems waste heat, which is no more than the result of their internal irreversibility. This heat is dissipated into the environment. But, this wasted heat represent also a sort of information, which outflows from the cell toward its environment, completely accessible to any observer. The analysis of irreversibility related to this wasted heat can represent a new approach to study the behaviour of the cells themselves and to control their behaviours. So, this approach allows us to consider the living systems as black boxes and analyze only the inflows and outflows and their changes in relation to the modification of the environment. Therefore, information on the systems can be obtained by analyzing the changes in the cell heat wasted in relation to external perturbations. The bioengineering thermodynamics bases are summarized and used to analyse possible controls of the calls behaviours based on the control of the ions fluxes across the cells membranes.
Thermodynamical description of excited nuclei
International Nuclear Information System (INIS)
Bonche, P.
1989-01-01
In heavy ion collisions it has been possible to obtain composite systems at rather high excitation energies corresponding to temperatures of several MeV. The theoretical studies of these systems are based on concepts borrowed from thermodynamics or statistical physics, such as the temperature. In these lectures, we present the concepts of statistical physics which are involved in the physics of heavy ion as they are produced nowadays in the laboratory and also during the final stage of a supernova collapse. We do not attempt to describe the reaction mechanisms which yield such nuclear systems nor their decay by evaporation or fragmentation. We shall only study their static properties. The content of these lectures is organized in four main sections. The first one gives the basic features of statistical physics and thermodynamics necessary to understand quantum mechanics at finite temperature. In the second one, we present a study of the liquid-gas phase transition in nuclear physics. A phenomenological approach of the stability of hot nuclei follows. The microscopic point of view is proposed in the third part. Starting from the basic concepts derived in the first part, it provides a description of excited or hot nuclei which confirms the qualitative results of the second part. Furthermore it gives a full description of most properties of these nuclei as a function of temperature. Finally in the last part, a microscopic derivation of the equation of state of nuclear matter is proposed to study the collapse of a supernova core