Nuclear materials thermo-physical property database and property analysis using the database

International Nuclear Information System (INIS)

Jeong, Yeong Seok

2002-02-01

It is necessary that thermo-physical properties and understand of nuclear materials for evaluation and analysis to steady and accident states of commercial and research reactor. In this study, development of nuclear materials thermo-properties database and home page. In application of this database, it is analyzed of thermal conductivity, heat capacity, enthalpy, and linear thermal expansion of fuel and cladding material and compared thermo-properties model in nuclear fuel performance evaluation codes with experimental data in database. Results of compare thermo-property model of UO 2 fuel and cladding major performance evaluation code, both are similar

A thermo-economic analysis of the separation process of an ethylene plant

International Nuclear Information System (INIS)

Yi, T.; Jan-Min, S.

1989-01-01

This study has established a model of thermo-economic balance for chemical processes. The general rules to form the exergy-price constraint equation and the equations of some major types of the units have been proposed. With this model, a thermo-economic analysis for the separation process of an Ethylene Plant has been studied. The paper has made an analysis for the effects of different boundary exergy prices on the process evaluation. The result shows that the thermo-economic analysis for a process, using the method advanced in here, merely depends on the process construction and the ratio of supplying exergy-prices. As soon as the ratio is well-matched, a similar analogic analysis may be set up for the same type of processes in different economic environments

Thermal stress analysis and thermo-mechanical fatigue for gas turbine blade

International Nuclear Information System (INIS)

Hyun, J. S.; Kim, B. S.; Kang, M. S.; Ha, J. S.; Lee, Y. S.

2002-01-01

The numerical analysis for gas turbine blades were carried out under several conditions by compounding temperature field, velocity field, thermal conduction of blade, and cooling heat transfer. The three types of 1,100 deg. C class 1st-stage gas turbine blades were analyzed. The analysis results are applied to the study on evaluating the remaining life for thermo-mechanical fatigue life. The thermo-mechanical fatigue experiments under out-of-phase and in-phase have been performed. The physical-based life prediction models which considered the contribution of different damage mechanisms have been applied. These models were applied to the temperature and strain rate dependences of isothermal cycling fatigue lives, and the strain-temperature history effect on the thermo-mechanical fatigue lives

Application of fast Fourier transform in thermo-magnetic convection analysis

International Nuclear Information System (INIS)

Pyrda, L

2014-01-01

Application of Fast Fourier Transform in thermo-magnetic convection is reported. Cubical enclosure filled with paramagnetic fluid heated from below and placed in the strong magnetic field gradients was investigated. The main aim of study was connected with identification of flow types, especially transition to turbulence. For this purpose the Fast Fourier Transform (FFT) analysis was applied. It was followed by the heat transfer characteristic for various values of magnetic induction gradient. The analysis was done at two Rayleigh numbers 7.89·10 5 and 1.86·10 6 with thermo-magnetic Rayleigh numbers up to 1.8·10 8 and 4.5·10 8 respectively. The presented results clearly indicate flow types and also demonstrate augmented heat transfer in dependence on magnetic induction gradient. Detailed analysis of flow transition to turbulent state was compared with transition line for natural convection reported in literature. The transition to turbulence in the case of thermo-magnetic convection of paramagnetic fluid was in very good agreement with transition in the case of natural convection.

The Comparison Of Silicon Analysis For The Uranium Silicide Fuel Using Spectrophotometrical And Gravimetrical Methods

International Nuclear Information System (INIS)

Putro, P. K.; Suripto, A.; Putra, S.; Gunanjar

1996-01-01

The analysis of silicon content in the uranium silicide fuel spectro-photometrical and gravimetrical method have been performed. The nitrous oxide-acetylene was used in the atomic absorption spectrophotometry (AAS) on the wave length of 251.6 nm, and the mixture of ammonium hepta molybdate complexes and SnC1 2 as reductor were applied during analysis by UV-VIS spectrophotometry (UV-VIS) on the wave length of 757.5 mm. The reagent of HCLO 4 and HNO 3 were used for determining Si content by gravimetrical methods. The results of this comparison is as follows: the accuracy result is around 96.37 % + 0.24 % for the Si concentration up to 300 ppm (the AAS), is 138.60 % = 0.43 % for the Si concentration range between 0.1-1.5 ppm (UV-VIS), and is 51.13 % + 0.8 % for 1 gram of Si (gravimetry). The results also show that the lowest analytical error is obtained by AAS method

Thermo-mechanical analysis of RMP coil system for EAST tokamak

International Nuclear Information System (INIS)

Wang, Songke; Ji, Xiang; Song, Yuntao; Zhang, Shanwen; Wang, Zhongwei; Sun, Youwen; Qi, Minzhong; Liu, Xufeng; Wang, Shengming; Yao, Damao

2014-01-01

Highlights: • Thermal design requirements for EAST RMP coils are summarized. • Cooling parameters based on both theoretical and numerical solutions are determined. • Compromise between thermal design and structural design is made on number of turns. • Thermo-mechanical calculations are made to validate its structural performance. - Abstract: Resonant magnetic perturbation (RMP) has been proved to be an efficient approach on edge localized modes (ELMs) control, resistive wall mode (RWM) control, and error field correction (EFC), RMP coil system under design in EAST tokamak will realize the above-mentioned multi-functions. This paper focuses on the thermo-mechanical analysis of EAST RMP coil system on the basis of sensitivity analysis, both normal and off-normal working conditions are considered. The most characteristic set of coil system is chosen with a complete modelling by means of three-dimensional (3D) finite element method, thermo-hydraulic and thermal-structural performances are investigated adequately, both locally and globally. The compromise is made between thermal performance and structural design requirements, and the results indicate that the optimized design is feasible and reasonable

Analysis of Thermo-Acoustic Emission from Damage in Composite Laminates under Thermal Cyclic Loading

International Nuclear Information System (INIS)

Kim, Young Bok; Min, Dae Hong; Lee, Deok Bo; Choi, Nak Sam

2001-01-01

An investigation on nondestructive evaluation of thermal stress-reduced damage in the composite laminates (3mm in thickness and [+45 6 /-45 6 ] S lay-up angles) has been performed using the thermo-acoustic emission technique. Reduction of thermo-AE events due to repetitive thermal load cycles showed a Kaiser effect. An analysis of the thermo-AE behavior determined the stress free temperature of composite laminates. Fiber fracture and matrix cracks were observed using the optical microscopy, scanning electron microscopy and ultrasonic C-sean. Short-Time Fourier Transform of thermo-AE signals offered the time-frequency characteristics which might classify the thermo-AE as three different types to estimate the damage processes of the composites

Heavy fuel oil pyrolysis and combustion: kinetics and evolved gases investigated by TGA-FTIR

KAUST Repository

Abdul Jameel, Abdul Gani; Han, Yunqing; Brignoli, Omar; Telalovic, Selvedin; Elbaz, Ayman M.; Im, Hong G.; Roberts, William L.; Sarathy, Mani

2017-01-01

investigated using non-isothermal thermo-gravimetric analysis (TGA) coupled with a Fourier-transform infrared (FTIR) spectrometer. TG and DTG (differential thermo-gravimetry) were used for the kinetic analysis and to study the mass loss characteristics due

Preliminary study of gravimetric anomalies in the Magallanes-Fagnano fault system, South America

Directory of Open Access Journals (Sweden)

Juan Manuel Alcacer

2018-01-01

Full Text Available The main objective of this research is to recognize several geological structures associated with the shear zones of the MFFS (Magallanes – Fagnano fault system by the analysis and interpretation of gravimetric anomalies. Besides, to compare the gravimetrical response of the cortical blocks that integrate the region under study, which is related to the different morphotectonic domains recognized in the region. This research was developed employing data obtained from World Gravity 1.0, which includes earth and satellite gravity data derived from the EGM2008 model. The study and interpretation of the MFFS from the analysis and processing of the gravimetric data, allowed appreciation of a noticeable correlation with the most superficial cortical structure.

Analysis of rocks involving the x-ray diffraction, infrared and thermal gravimetric techniques

International Nuclear Information System (INIS)

Ikram, M.; Rauf, M.A.; Munir, N.

1998-01-01

Chemical analysis of rocks and minerals are usually obtained by a number of analytical techniques. The purpose of present work is to investigate the chemical composition of the rock samples and also to find that how far the results obtained by different instrumental methods are closely related. Chemical tests wee performed before using the instrumental techniques in order to determined the nature of these rocks. The chemical analysis indicated mainly the presence of carbonate and hence the carbonate nature of these rocks. The x-ray diffraction, infrared spectroscopy and thermal gravimetric analysis techniques were used for the determination of chemical composition of these samples. The results obtained by using these techniques have shown a great deal of similarities. (author)

Thermo-hydraulic and structural analysis for finger-based concept of ITER blanket first wall

International Nuclear Information System (INIS)

Kim, Byoung-Yoon; Ahn, Hee-Jae

2011-01-01

The blanket first wall is one of the main plasma facing components in ITER tokamak. The finger-typed first wall was proposed through the current design progress by ITER organization. In this concept, each first wall module is composed of a beam and twenty fingers. The main function of the first wall is to remove efficiently the high heat flux loading from the fusion plasma during its operation. Therefore, the thermal and structural performance should be investigated for the proposed finger-based design concept of first wall. The various case studies were performed for a unit finger model considering different loading conditions. The finite element model was made for a half of a module using symmetric boundary conditions to reduce the computational effort. The thermo-hydraulic analysis was performed to obtain the pressure drop and temperature profiles. Then the structural analysis was carried out using the maximum temperature distribution obtained in thermo-hydraulic analysis. Finally, the transient thermo-hydraulic analysis was performed for the generic first wall module to obtain the temperature evolution history considering cyclic heat flux loading with nuclear heating. After that, the thermo-mechanical analysis was performed at the time step when the maximum temperature gradient was occurred. Also, the stress analysis was performed for the component with a finger and a beam to check the residual stress of the component after thermal shrinkage assembly.

Residual gravimetric method to measure nebulizer output.

Science.gov (United States)

Vecellio None, Laurent; Grimbert, Daniel; Bordenave, Joelle; Benoit, Guy; Furet, Yves; Fauroux, Brigitte; Boissinot, Eric; De Monte, Michele; Lemarié, Etienne; Diot, Patrice

2004-01-01

The aim of this study was to assess a residual gravimetric method based on weighing dry filters to measure the aerosol output of nebulizers. This residual gravimetric method was compared to assay methods based on spectrophotometric measurement of terbutaline (Bricanyl, Astra Zeneca, France), high-performance liquid chromatography (HPLC) measurement of tobramycin (Tobi, Chiron, U.S.A.), and electrochemical measurements of NaF (as defined by the European standard). Two breath-enhanced jet nebulizers, one standard jet nebulizer, and one ultrasonic nebulizer were tested. Output produced by the residual gravimetric method was calculated by weighing the filters both before and after aerosol collection and by filter drying corrected by the proportion of drug contained in total solute mass. Output produced by the electrochemical, spectrophotometric, and HPLC methods was determined after assaying the drug extraction filter. The results demonstrated a strong correlation between the residual gravimetric method (x axis) and assay methods (y axis) in terms of drug mass output (y = 1.00 x -0.02, r(2) = 0.99, n = 27). We conclude that a residual gravimetric method based on dry filters, when validated for a particular agent, is an accurate way of measuring aerosol output.

Gravimetric determination of uranium in SALE samples

International Nuclear Information System (INIS)

Anon.

1981-01-01

As a participant in the Safeguards Analytical Laboratory Evaluation (SALE) program, the Analytical Chemistry Laboratory at General Atomic routinely assays uranium dioxide and uranyl nitrate SALE samples for uranium content. Gravimetric methods are relatively easy and inexpensive to apply when the samples for uranium content. Gravimetric methods are relatively easy and inexpensive to apply when the samples are free from substantial amounts of metallic impurities. Clearly the gravimetric procedure alone is not specific for uranium and must be enhanced by the use of impurity corrections. Emission spectrography is used routinely as the technique of choice for making such corrections. In cases where it is essential to assay specifically for uranium, the modified Davies-Gray titration using a weighed titrant method is applied. In this paper some essential features of these gravimetric and titrimetric procedures are discussed

Comparison of macro-gravimetric and micro-colorimetric lipid determination methods.

Science.gov (United States)

Inouye, Laura S; Lotufo, Guiherme R

2006-10-15

In order to validate a method for lipid analysis of small tissue samples, the standard macro-gravimetric method of Bligh-Dyer (1959) [E.G. Bligh, W.J. Dyer, Can. J. Biochem. Physiol. 37 (1959) 911] and a modification of the micro-colorimetric assay developed by Van Handel (1985) [E. Van Handel, J. Am. Mosq. Control Assoc. 1 (1985) 302] were compared. No significant differences were observed for wet tissues of two species of fish. However, limited analysis of wet tissue of the amphipod, Leptocheirusplumulosus, indicated that the Bligh-Dyer gravimetric method generated higher lipid values, most likely due to the inclusion of non-lipid materials. Additionally, significant differences between the methods were observed with dry tissues, with the micro-colorimetric method consistently reporting calculated lipid values greater than as reported by the gravimetric method. This was most likely due to poor extraction of dry tissue in the standard Bligh-Dyer method, as no significant differences were found when analyzing a single composite extract. The data presented supports the conclusion that the micro-colorimetric method described in this paper is accurate, rapid, and minimizes time and solvent use.

Synthesis of a novel thermo/pH sensitive nanogel based on salep modified graphene oxide for drug release

Energy Technology Data Exchange (ETDEWEB)

Bardajee, Ghasem Rezanejade, E-mail: rezanejad@pnu.ac.ir; Hooshyar, Zari; Farsi, Maryam; Mobini, Akram; Sang, Golnaz

2017-03-01

Nanogels (NGs) are three-dimensional water soluble cross-linked hydrogel materials in the nanoscale size range with a high loading capacity for guest molecules and act as drug carrier systems. In the present work, a new type of thermo/pH sensitive NG comprising salep modified graphene oxide (SMGO) with branched N-isopropylacrylamide (NIPAM) and acrylic acid (AA) was prepared. The SMGO/P(NIPAM-co-AA) NGs exhibited nanoporous structure and spherical particles with diameters about 82 nm as characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and dynamic light scattering (DLS). The samples were also characterized by Fourier transform infrared spectroscopy (FT-IR) and thermo gravimetric analysis (TGA) to further confirm about the formation of NGs. Doxorubicin (DOX) loaded SMGO/P(NIPAM-co-AA) NGs showed thermo/pH dependent releasing behavior: slow drug release at neutral pH and lower temperature but increased significantly in acidic pH and higher temperature, without any burst release. In addition, the NGs exhibited no effect on the cell viability in the tested concentration range up to 410 μg/mL and drug release systems enhanced toxicity to HeLa cells when compared to the equivalent dose of the free drug. Overall, our results put forth NGs as potential candidates in the development of a new nanocarrier for anti-cancer drug delivery. - Highlights: • A novel thermo/pH sensitive nanogels (NGs) was successfully synthesized. • NGs showed high loading capacity for DOX drug and slow drug release at neutral pH. • NGs exhibited no effect on the cell viability in the tested concentration range.

Synthesis of a novel thermo/pH sensitive nanogel based on salep modified graphene oxide for drug release

International Nuclear Information System (INIS)

Bardajee, Ghasem Rezanejade; Hooshyar, Zari; Farsi, Maryam; Mobini, Akram; Sang, Golnaz

2017-01-01

Nanogels (NGs) are three-dimensional water soluble cross-linked hydrogel materials in the nanoscale size range with a high loading capacity for guest molecules and act as drug carrier systems. In the present work, a new type of thermo/pH sensitive NG comprising salep modified graphene oxide (SMGO) with branched N-isopropylacrylamide (NIPAM) and acrylic acid (AA) was prepared. The SMGO/P(NIPAM-co-AA) NGs exhibited nanoporous structure and spherical particles with diameters about 82 nm as characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and dynamic light scattering (DLS). The samples were also characterized by Fourier transform infrared spectroscopy (FT-IR) and thermo gravimetric analysis (TGA) to further confirm about the formation of NGs. Doxorubicin (DOX) loaded SMGO/P(NIPAM-co-AA) NGs showed thermo/pH dependent releasing behavior: slow drug release at neutral pH and lower temperature but increased significantly in acidic pH and higher temperature, without any burst release. In addition, the NGs exhibited no effect on the cell viability in the tested concentration range up to 410 μg/mL and drug release systems enhanced toxicity to HeLa cells when compared to the equivalent dose of the free drug. Overall, our results put forth NGs as potential candidates in the development of a new nanocarrier for anti-cancer drug delivery. - Highlights: • A novel thermo/pH sensitive nanogels (NGs) was successfully synthesized. • NGs showed high loading capacity for DOX drug and slow drug release at neutral pH. • NGs exhibited no effect on the cell viability in the tested concentration range.

Thermal Analysis of Braille Formed by Using Screen Printing and Inks with Thermo Powder

Directory of Open Access Journals (Sweden)

Svіtlana HAVENKO

2015-03-01

Full Text Available In order to improve the integration of blind people into society, suitable conditions should be provided for them. The expansion of Braille (BR use could serve the purpose. Depending on the materials used for Braille, it can be formed or printed in different ways: embossing, screen printing, thermoforming, digital printing. The aim of this research is to determine the effect of thermal properties of screen printing inks and inks with thermo-powder on the qualitative parameters of Braille. Screen printing inks and inks with thermo-powder were chosen for the research. Carrying out the qualitative analysis of printouts with Braille, the thermal stability was evaluated by analyzing the thermograms obtained with derivatograph Q-1500. This paper presents the findings of the thermogravimetric (TG, differential thermogravimetric (DTG and differential thermal analysis (DTA of printouts printed on paperboard Plike and using traditional screen printing inks and screen printing inks with thermo-powder. Based on the testing findings it is determined that thermal stability of printouts printed with thermo-powder ink is higher than printed with screen printing inks. It is determined that the appropriate temperature range of screen printing inks with thermo-powder drying is 98 ºC – 198 ºC because in this case better relief of Braille dots is obtained.DOI: http://dx.doi.org/10.5755/j01.ms.21.1.5702

Gravimetric method for the determination of diclofenac in pharmaceutical preparations.

Science.gov (United States)

Tubino, Matthieu; De Souza, Rafael L

2005-01-01

A gravimetric method for the determination of diclofenac in pharmaceutical preparations was developed. Diclofenac is precipitated from aqueous solution with copper(II) acetate in pH 5.3 (acetic acid/acetate buffer). Sample aliquots had approximately the same quantity of the drug content in tablets (50 mg) or in ampules (75 mg). The observed standard deviation was about +/- 2 mg; therefore, the relative standard deviation (RSD) was approximately 4% for tablet and 3% for ampule preparations. The results were compared with those obtained with the liquid chromatography method recommended in the United States Pharmacopoeia using the statistical Student's t-test. Complete agreement was observed. It is possible to obtain more precise results using higher aliquots, for example 200 mg, in which case the RSD falls to 1%. This gravimetric method, contrary to what is expected for this kind of procedure, is relatively fast and simple to perform. The main advantage is the absolute character of the gravimetric analysis.

Thermo-elastic optical coherence tomography.

Science.gov (United States)

Wang, Tianshi; Pfeiffer, Tom; Wu, Min; Wieser, Wolfgang; Amenta, Gaetano; Draxinger, Wolfgang; van der Steen, Antonius F W; Huber, Robert; Soest, Gijs van

2017-09-01

The absorption of nanosecond laser pulses induces rapid thermo-elastic deformation in tissue. A sub-micrometer scale displacement occurs within a few microseconds after the pulse arrival. In this Letter, we investigate the laser-induced thermo-elastic deformation using a 1.5 MHz phase-sensitive optical coherence tomography (OCT) system. A displacement image can be reconstructed, which enables a new modality of phase-sensitive OCT, called thermo-elastic OCT. An analysis of the results shows that the optical absorption is a dominating factor for the displacement. Thermo-elastic OCT is capable of visualizing inclusions that do not appear on the structural OCT image, providing additional tissue type information.

Thermo-economic analysis of combined power plants with changing economic parameters

International Nuclear Information System (INIS)

Bidini, G.; Desideri, U.; Facchini, B.

1991-01-01

A method of thermo-economic analysis for the choice of optimal thermodynamic parameters of steam bottoming cycles in combined cycle power plants is presented. By keeping the thermodynamic aspects separated from the economic aspects, this method allows designers to easily perform a sensitivity analysis of the change in the economic parameters

Coupled transient thermo-fluid/thermal-stress analysis approach in a VTBM setting

International Nuclear Information System (INIS)

Ying, A.; Narula, M.; Zhang, H.; Abdou, M.

2008-01-01

A virtual test blanket module (VTBM) has been envisioned as a utility to aid in streamlining and optimizing the US ITER TBM design effort by providing an integrated multi-code, multi-physics modeling environment. Within this effort, an integrated simulation approach is being developed for TBM design calculations and performance evaluation. Particularly, integrated thermo-fluid/thermal-stress analysis is important for enabling TBM design and performance calculations. In this paper, procedures involved in transient coupled thermo-fluid/thermal-stress analysis are investigated. The established procedure is applied to study the impact of pulsed operational phenomenon on the thermal-stress response of the TBM first wall. A two-way coupling between the thermal strain and temperature field is also studied, in the context of a change in thermal conductivity of the beryllium pebble bed in a solid breeder blanket TBM due to thermal strain. The temperature field determines the thermal strain in beryllium, which in turn changes the temperature field. Iterative thermo-fluid/thermal strain calculations have been applied to both steady-state and pulsed operation conditions. All calculations have been carried out in three dimensions with representative MCAD models, including all the TBM components in their entirety

Thermo-responsive polymer-functionalized mesoporous carbon for controlled drug release

Energy Technology Data Exchange (ETDEWEB)

Zhu Shenmin, E-mail: smzhu@sjtu.edu.cn [State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240 (China); Chen Chenxin [State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240 (China); Chen Zhixin [Faculty of Engineering, University of Wollongong, Wollongong, NSW 2522 (Australia); Liu Xinye; Li Yao; Shi Yang; Zhang Di [State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240 (China)

2011-03-15

Research highlights: {yields} A responsive drug delivery system based on poly(N-isopropyl acrylamide) (PNIPAM) functionalized ordered mesoporous carbon (CMK-3) is developed. {yields} A combination of surface modification of CMK-3 and in situ internal polymerization of PNIPAM was used. {yields} The system exhibited a pronounced transition at around 20-25 deg. C. - Abstract: A novel responsive drug delivery system based on poly(N-isopropyl acrylamide) (PNIPAM) functionalized ordered mesoporous carbon (CMK-3) is developed. The polymer-functionalized CMK-3 was obtained by a combination of simple surface modification of CMK-3 and in situ internal polymerization of PNIPAM. The formation of the PNIPAM inside the CMK-3 was confirmed by thermal gravimetric analysis, Fourier transform-infrared spectroscopy, scanning and transmission electron microscopy and N{sub 2} adsorption/desorption measurements. Controlled drug release tests through the porous network of the PNIPAM functionalized CMK-3 were carried out by measuring the uptake and release of ibuprofen in vitro. The release profiles exhibited a pronounced transition at around 20-25 deg. C. This thermo-sensitive release property of this delivery system was further confirmed by temperature-variable hydrogen nuclear magnetic resonance analysis. The internal PNIPAM layers acted as a storage gate as well as a release switch in response to the stimuli of environment.

Analysis of the thermal profiles and the charcoal gravimetric yield in three variations of rectangular brick

Energy Technology Data Exchange (ETDEWEB)

Oliveira, Rogerio Lima Mota de; Alves Junior, Edson; Mulina, Bruno Henrique Oliveira; Borges, Valerio Luiz; Carvalho, Solidonio Rodrigues de [Federal University of Uberlandia - UFU, MG (Brazil). School of Mechanical Engineering - FEMEC], e-mails: rogerio@mecanica.ufu.br, edson@mec.ufu.br, vlborges@mecanica.ufu.br, srcarvalho@mecanica.ufu.br

2010-07-01

Charcoal assumes a major role in Brazilian economic scenario. The procedure for obtaining charcoal consists in carbonization of wood at certain specific temperatures in kilns. This ancient process has a few joined technologies and the kilns for such practice do not have any control instruments, in their great majority, becoming dependent on the ability of its operators. However, in recent decades several studies have been developed to improve the practice as well as the equipment that involve and control the stages of charcoal production. In this sense, this work proposes the analysis of the thermal profiles and the gravimetric yield in three variations of a rectangular brick kiln called RAC220: traditional (without any type of instrumentation), instrumented with thermal sensors (RTD PT100) and adapted with gasifier. The goal is to correlate temperature, gravimetric yield and quality of the produced charcoal. Immediate analyses were performed to determine the amount of fixed carbon, volatile gases and ashes contents in charcoal. Through such measurement procedures, together with statistical analysis, the aim is to identify an important tool to reduce the time of charcoal production and also contributes to minimize losses and to increase the thermal efficiency of the production process. (author)

Characterization and Gravimetric Analysis of the Dissolved Quartz in the Conversion of Coal Fly Ash to Sodalite

International Nuclear Information System (INIS)

Mohd Hilmi Mohamed; Zainab Ramli

2012-01-01

Coal fly ash (CFA) is a waste product produced from the electrical power plant and hazardous towards the environment. However, the high composition of silica and alumina in the CFA makes it useful as raw materials in the zeolite synthesis. However, the presence of silica in the form of quartz in the CFA does not facilitate the transformation of CFA to zeolite at 100 degree Celsius and autogeneous pressure. In this study, CFA was converted to zeolites in various NaOH concentrations by microwave heating at various heating time. All synthesized product were characterized by X-ray diffraction (XRD), and gravimetric analysis. XRD has shown that quite pure sodalite in nano size has been formed as early as 15 minutes and increase with time. Prolong heating up to 45 minutes has reduced the content of quartz to ca 20 %. Gravimetric analysis performed on the liquor of the reaction showed that the dissolved silica decrease with increase of heating time indicating that most of the dissolved quartz is used up to form sodalite framework. Hence, quartz of CFA did help in enhancing the crystallinity of the formed sodalite after prolong heating. (author)

Free vibration analysis of magneto-electro-thermo-elastic nanobeams resting on a Pasternak foundation

Science.gov (United States)

Jandaghian, A. A.; Rahmani, O.

2016-03-01

In this study, free vibration analysis of magneto-electro-thermo-elastic (METE) nanobeams resting on a Pasternak foundation is investigated based on nonlocal theory and Timoshenko beam theory. Coupling effects between electric, magnetic, mechanical and thermal loading are considered to derive the equations of motion and distribution of electrical potential and magnetic potential along the thickness direction of the METE nanobeam. The governing equations and boundary conditions are obtained using the Hamilton principle and discretized via the differential quadrature method (DQM). Numerical results reveal the effects of the nonlocal parameter, magneto-electro-thermo-mechanical loading, Winkler spring coefficients, Pasternak shear coefficients and height-to-length ratio on the vibration characteristics of METE nanobeams. It is observed that the natural frequency is dependent on the magnetic, electric, temperature, elastic medium, small-scale coefficient, and height-to-length ratio. These results are useful in the mechanical analysis and design of smart nanostructures constructed from magneto-electro-thermo-elastic materials.

Free vibration analysis of magneto-electro-thermo-elastic nanobeams resting on a Pasternak foundation

International Nuclear Information System (INIS)

Jandaghian, A A; Rahmani, O

2016-01-01

In this study, free vibration analysis of magneto-electro-thermo-elastic (METE) nanobeams resting on a Pasternak foundation is investigated based on nonlocal theory and Timoshenko beam theory. Coupling effects between electric, magnetic, mechanical and thermal loading are considered to derive the equations of motion and distribution of electrical potential and magnetic potential along the thickness direction of the METE nanobeam. The governing equations and boundary conditions are obtained using the Hamilton principle and discretized via the differential quadrature method (DQM). Numerical results reveal the effects of the nonlocal parameter, magneto-electro-thermo-mechanical loading, Winkler spring coefficients, Pasternak shear coefficients and height-to-length ratio on the vibration characteristics of METE nanobeams. It is observed that the natural frequency is dependent on the magnetic, electric, temperature, elastic medium, small-scale coefficient, and height-to-length ratio. These results are useful in the mechanical analysis and design of smart nanostructures constructed from magneto-electro-thermo-elastic materials. (paper)

Steady State Thermo-Hydrodynamic Analysis of Two-Axial groove and Multilobe Hydrodynamic Bearings

Directory of Open Access Journals (Sweden)

C. Bhagat

2014-12-01

Full Text Available Steady state thermo-hydrodynamic analysis of two axial groove and multi lobe oil journal bearings is performed in this paper. To study the steady state thermo-hydrodynamic characteristics Reynolds equation is solved simultaneously along with the energy equation and heat conduction equation in bush and shaft. The effect of groove geometry, cavitation in the fluid film, the recirculation of lubricant, shaft speed has also been taken into account. Film temperature in case of three-lobe bearing is found to be high as compared to other studied bearing configurations. The data obtained from this analysis can be used conveniently in the design of such bearings, which are presented in dimensionless form.

Tunable thermo-responsive hydrogels: synthesis, structural analysis and drug release studies.

Science.gov (United States)

Cirillo, Giuseppe; Spataro, Tania; Curcio, Manuela; Spizzirri, U Gianfranco; Nicoletta, Fiore Pasquale; Picci, Nevio; Iemma, Francesca

2015-03-01

Thermo-responsive hydrogel films, synthesized by UV-initiated radical polymerization, are proposed as delivery devices for non-steroidal anti-inflammatory drugs (Diclofenac sodium and Naproxen). N-isopropylacrylamide and N,N'-ethylenebisacrylamide were chosen as thermo-sensitive monomer and crosslinker, respectively. Infrared spectroscopy was used to assess the incorporation of monomers into the network, and the network density of hydrogel films was found to strictly depend on both feed composition and film thickness. Calorimetric analyses showed negative thermo-responsive behaviour with shrinking/swelling transition values in the range 32.8-36.1°C. Equilibrium swelling studies around the LCST allowed the correlation between the structural changes and the temperature variations. The mesh size, indeed, rapidly changed from a collapsed to a swollen state, with beneficial effects in applications such as size-selective permeation or controlled drug delivery, while the crosslinking degree, the film thickness, and the loading method deeply influenced the drug release profiles at 25 and 40°C. The analysis of both 3D-network structure, release kinetics and diffusional constraints at different temperatures was evaluated by mathematical modelling. Copyright © 2014 Elsevier B.V. All rights reserved.

Influence of Thermo-Oxidative Ageing on the Thermal and Dynamical Mechanical Properties of Long Glass Fibre-Reinforced Poly(Butylene Terephthalate) Composites Filled with DOPO.

Science.gov (United States)

Zhang, Daohai; He, Min; He, Weidi; Zhou, Ying; Qin, Shuhao; Yu, Jie

2017-05-04

In this work, the long glass fibre-reinforced poly(butylene terephthalate) (PBT) composites filled with 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) were prepared by melt blending, and the influence of thermo-oxidative ageing on the static and dynamic mechanical properties, thermal behaviours and morphology of composites with different ageing time at 120 °C were investigated and analysed. The results showed that the mechanical properties decreased in the primary stage of ageing, while embrittlement occurs in the later period, and the crystallinity of PBT decreases first, and then recovers to some extent. The scanning electron microscopy (SEM) photos of the samples indicated that the obvious crack appeared on the sample surface and a deeper, broader crack occurred with a longer ageing time. The results of energy dispersive X-ray analysis (EDAX) proved the DOPO filler diffused to the sample surface by measuring the content of phosphorus. Thermal gravimetric analysis (TGA) curves showed that the thermal stabilities of composites increased with longer ageing time, as did the values of the limited oxygen index (LOI). Meanwhile, the results of dynamic mechanical analysis (DMA) indicated that the glass transition temperature shifted to a higher temperature after ageing due to the effect of crosslinking, and both the crosslinking and degradation of PBT molecular chains act as the main factors in the whole process of thermo-oxidative ageing.

Thermo Wigner operator in thermo field dynamics: its introduction and application

International Nuclear Information System (INIS)

Fan Hongyi; Jiang Nianquan

2008-01-01

Because in thermo-field dynamics (TFD) the thermo-operator has a neat expression in the thermo-entangled state representation, we need to introduce the thermo-Wigner operator (THWO) in the same representation. We derive the THWO in a direct way, which brings much conveniece to calculating the Wigner functions of thermo states in TFD. We also discuss the condition for existence of a wavefunction corresponding to a given Wigner function in the context of TFD by using the explicit form of the THWO.

Thermo-economic analysis and selection of working fluid for solar organic Rankine cycle

International Nuclear Information System (INIS)

Desai, Nishith B.; Bandyopadhyay, Santanu

2016-01-01

Highlights: • Concentrating solar power plant with organic Rankine cycle. • Thermo-economic analysis of solar organic Rankine cycle. • Performance evaluation for different working fluids. • Comparison diagram to select appropriate working fluid. - Graphical Abstract: Display Omitted - Abstract: Organic Rankine cycle (ORC), powered by line-focusing concentrating solar collectors (parabolic trough collector and linear Fresnel reflector), is a promising option for modular scale. ORC based power block, with dry working fluids, offers higher design and part-load efficiencies compared to steam Rankine cycle (SRC) in small-medium scale, with temperature sources up to 400 °C. However, the cost of ORC power block is higher compared to the SRC power block. Similarly, parabolic trough collector (PTC) system has higher optical efficiency and higher cost compared to linear Fresnel reflector (LFR) system. The thermodynamic efficiencies and power block costs also vary with working fluids of the Rankine cycle. In this paper, thermo-economic comparisons of organic Rankine and steam Rankine cycles powered by line-focusing concentrating solar collectors are reported. A simple selection methodology, based on thermo-economic analysis, and a comparison diagram for working fluids of power generating cycles are also proposed. Concentrating solar power plants with any collector technology and any power generating cycle can be compared using the proposed methodology.

Hydro-methane and methanol combined production from hydroelectricity and biomass: Thermo-economic analysis in Paraguay

International Nuclear Information System (INIS)

Rivarolo, M.; Bellotti, D.; Mendieta, A.; Massardo, A.F.

2014-01-01

Highlights: • We investigate H 2 /O 2 production from large hydraulic plant by water electrolysis. • We produce methanol and hydro-methane from H 2 /O 2 obtained. • We investigate two different configurations of the plant. • We perform a thermo-economic analysis for three scenarios in Paraguay. • We find plants optimal size using a time-dependent thermo-economic approach. - Abstract: A thermo-economic analysis regarding large scale hydro-methane and methanol production from renewable sources (biomass and renewable electricity) is performed. The study is carried out investigating hydrogen and oxygen generation by water electrolysis, mainly employing the hydraulic energy produced from the 14 GW Itaipu Binacional Plant, owned by Paraguay and Brazil. Oxygen is employed in biomass gasification to synthesize methanol; the significant amount of CO 2 separated in the process is mixed with hydrogen produced by electrolysis in chemical reactors to produce hydro-methane. Hydro-methane is employed to supply natural gas vehicles in Paraguay, methanol is sold to Brazil, that is the largest consumer in South America. The analysis is performed employing time-dependent hydraulic energy related to the water that would normally not be used by the plant, named “spilled energy”, when available; in the remaining periods, electricity is acquired at higher cost by the national grid. For the different plant lay-outs, a thermo-economic analysis has been performed employing two different software, one for the design point and one for the time-dependent one entire year optimization, since spilled energy is strongly variable throughout the year. Optimal sizes for the generation plants have been determined, investigating the influence of electricity cost, size and plant configuration

Physics of thermo-acoustic sound generation

Science.gov (United States)

Daschewski, M.; Boehm, R.; Prager, J.; Kreutzbruck, M.; Harrer, A.

2013-09-01

We present a generalized analytical model of thermo-acoustic sound generation based on the analysis of thermally induced energy density fluctuations and their propagation into the adjacent matter. The model provides exact analytical prediction of the sound pressure generated in fluids and solids; consequently, it can be applied to arbitrary thermal power sources such as thermophones, plasma firings, laser beams, and chemical reactions. Unlike existing approaches, our description also includes acoustic near-field effects and sound-field attenuation. Analytical results are compared with measurements of sound pressures generated by thermo-acoustic transducers in air for frequencies up to 1 MHz. The tested transducers consist of titanium and indium tin oxide coatings on quartz glass and polycarbonate substrates. The model reveals that thermo-acoustic efficiency increases linearly with the supplied thermal power and quadratically with thermal excitation frequency. Comparison of the efficiency of our thermo-acoustic transducers with those of piezoelectric-based airborne ultrasound transducers using impulse excitation showed comparable sound pressure values. The present results show that thermo-acoustic transducers can be applied as broadband, non-resonant, high-performance ultrasound sources.

Pyrolysis characteristics and kinetic parameters determination of biomass fuel powders by differential thermal gravimetric analysis (TGA/DTG)

International Nuclear Information System (INIS)

El-Sayed, Saad A.; Mostafa, M.E.

2014-01-01

Highlights: • The sugarcane bagasse powder has better energy value compared to the cotton stalks. • Bagasse moisture is entrained in its cell walls and its evaporation needs more energy. • The cotton stalks is more reactive and readily combustible than the bagasse powders. • A lower E and A 0 has been found for bagasse compared with cotton stalks powders. • Calculated E of bagasse and cotton stalks by direct and integral methods are different. - Abstract: The kinetics of the thermal decomposition of the two biomass materials (sugarcane bagasse and cotton stalks powders) were evaluated using a differential thermo-gravimetric analyzer under a non-isothermal condition. Two distinct reaction zones were observed for the two biomasses. The direct Arrhenius plot method and the integral method were applied for determination of kinetic parameters: activation energy, pre-exponential factor, and order of reaction. The weight loss curve showed that pyrolysis of sugarcane bagasse and cotton stalks took place mainly in the range of 200–500 °C. The activation energy of the sugarcane bagasse powder obtained by the direct Arrhenius plot method ranged between 43 and 53.5 kJ/mol. On the other side, the integral method shows larger values of activation energy (77–87.7 kJ/mol). The activation energy of the cotton stalks powder obtained by the direct Arrhenius plot method was ranged between 98.5 and 100.2 kJ/mol, but the integral method shows larger values of activation energy (72.5–127.8 kJ/mol)

Multiscale Thermo-Mechanical Design and Analysis of High Frequency and High Power Vacuum Electron Devices

Science.gov (United States)

Gamzina, Diana

Diana Gamzina March 2016 Mechanical and Aerospace Engineering Multiscale Thermo-Mechanical Design and Analysis of High Frequency and High Power Vacuum Electron Devices Abstract A methodology for performing thermo-mechanical design and analysis of high frequency and high average power vacuum electron devices is presented. This methodology results in a "first-pass" engineering design directly ready for manufacturing. The methodology includes establishment of thermal and mechanical boundary conditions, evaluation of convective film heat transfer coefficients, identification of material options, evaluation of temperature and stress field distributions, assessment of microscale effects on the stress state of the material, and fatigue analysis. The feature size of vacuum electron devices operating in the high frequency regime of 100 GHz to 1 THz is comparable to the microstructure of the materials employed for their fabrication. As a result, the thermo-mechanical performance of a device is affected by the local material microstructure. Such multiscale effects on the stress state are considered in the range of scales from about 10 microns up to a few millimeters. The design and analysis methodology is demonstrated on three separate microwave devices: a 95 GHz 10 kW cw sheet beam klystron, a 263 GHz 50 W long pulse wide-bandwidth sheet beam travelling wave tube, and a 346 GHz 1 W cw backward wave oscillator.

Tandem Gravimetric and Volumetric Apparatus for Methane Sorption Measurements

Science.gov (United States)

Burress, Jacob; Bethea, Donald

Concerns about global climate change have driven the search for alternative fuels. Natural gas (NG, methane) is a cleaner fuel than gasoline and abundantly available due to hydraulic fracturing. One hurdle to the adoption of NG vehicles is the bulky cylindrical storage vessels needed to store the NG at high pressures (3600 psi, 250 bar). The adsorption of methane in microporous materials can store large amounts of methane at low enough pressures for the allowance of conformable, ``flat'' pressure vessels. The measurement of the amount of gas stored in sorbent materials is typically done by measuring pressure differences (volumetric, manometric) or masses (gravimetric). Volumetric instruments of the Sievert type have uncertainties that compound with each additional measurement. Therefore, the highest-pressure measurement has the largest uncertainty. Gravimetric instruments don't have that drawback, but can have issues with buoyancy corrections. An instrument will be presented with which methane adsorption measurements can be performed using both volumetric and gravimetric methods in tandem. The gravimetric method presented has no buoyancy corrections and low uncertainty. Therefore, the gravimetric measurements can be performed throughout an entire isotherm or just at the extrema to verify the results from the volumetric measurements. Results from methane sorption measurements on an activated carbon (MSC-30) and a metal-organic framework (Cu-BTC, HKUST-1, MOF-199) will be shown. New recommendations for calculations of gas uptake and uncertainty measurements will be discussed.

Gravimetric determination of beryllium in the presence of transition metals

International Nuclear Information System (INIS)

Morozova, S.S.; Nikitina, L.V.; Dyatlova, N.M.; Serebryakova, G.V.; Vol'nyagina, A.N.

1976-01-01

A new organic reagent, nitrolotrimethylphosphonic acid (H 6 L), is proposed for gravimetric determination of beryllium. This complexone forms with Be hardly soluble complexes in a wide pH range. The separated complex has a composition Be 5 (HL) 2 x10H 2 O. To elucidate the possibility of determining Be in the presence of transition metals, often accompanying beryllium in alloys, interaction of cations of these metals with H 6 L at different pH has been studied potentiometrically. It has been established that at pH=1.1 in the presence of masking reagent (diethylentriaminopentacetic acid) Be can be determined when zinc, copper, chromium, cobalt, nickel, iron, manganese and cadmium are present. Gravimetric method of determining Be with the help of H 6 L has been developed. The weight form is obtained by drying the precipitate which reduces considerably the time of analysis and the error of determination

Quench characterization and thermo hydraulic analysis of SST-1 TF magnet busbar

Energy Technology Data Exchange (ETDEWEB)

Sharma, A.N., E-mail: ansharma@ipr.res.in [Institute for Plasma Research, Gandhinagar (India); Pradhan, S. [Institute for Plasma Research, Gandhinagar (India); Duchateau, J.L. [CEA Cadarache, 13108 St Paul lez Durance Cedex (France); Khristi, Y.; Prasad, U.; Doshi, K.; Varmora, P.; Tanna, V.L.; Patel, D.; Panchal, A. [Institute for Plasma Research, Gandhinagar (India)

2015-01-15

Highlights: • Details of SST-1 TF busbar quench detection. • Simulation of slow propagating normal zone. • Thermo hydraulic analyses of TF busbar in current feeder system. - Abstract: Toroidal field (TF) magnet system of steady-state superconducting tokamak-1 (SST-1) has 16 superconducting coils. TF coils are cooled with forced flow supercritical helium at 0.4 MPa, at 4.5 K and operate at nominal current of 10,000 A. Prior to TF magnet system assembly in SST-1 tokamak, each TF coil was tested individually in a test cryostat. During these tests, TF coil was connected to a pair of conventional helium vapor cooled current leads. The connecting busbar was made from the same base cable-in-conduit-conductor (CICC) of SST-1 superconducting magnet system. Quenches experimentally observed in the busbar sections of the single coil test setups have been analyzed in this paper. A steady state thermo hydraulic analysis of TF magnet busbar in actual SST-1 tokamak assembly has been done. The experimental observations of quench and results of relevant thermo hydraulic analyses have been used to predict the safe operation regime of TF magnet system busbar during actual SST-1 tokamak operational scenarios.

A Comparative Analysis of Seismological and Gravimetric Crustal Thicknesses below the Andean Region with Flat Subduction of the Nazca Plate

Directory of Open Access Journals (Sweden)

Mario E. Gimenez

2009-01-01

Full Text Available A gravimetric study was carried out in a region of the Central Andean Range between 28∘ and 32∘ south latitudes and from 72∘ and 66∘ west longitudes. The seismological and gravimetrical Moho models were compared in a sector which coincides with the seismological stations of the CHARGE project. The comparison reveals discrepancies between the gravity Moho depths and those obtained from seismological investigations (CHARGE project, the latter giving deeper values than those resulting from the gravimetric inversion. These discrepancies are attenuated when the positive gravimetric effect of the Nazca plate is considered. Nonetheless, a small residuum of about 5 km remains beneath the Cuyania terrane region, to the east of the main Andean chain. This residuum could be gravimetrically justified if the existence of a high density or eclogitized portion of the lower crust is considered. This result differed from the interpretations from Project “CHARGE” which revealed that the entire inferior crust extending from the Precordillera to the occidental “Sierras Pampeanas” could be “eclogitized”. In this same sector, we calculated the effective elastic thickness (Te of the crust. These results indicated an anomalous value of Te = 30 km below the Cuyania terrane. This is further conclusive evidence of the fact that the Cuyania terrane is allochthonous, for which also geological evidences exist.

Nuclear, thermo-mechanical and tritium release analysis of ITER breeding blanket

International Nuclear Information System (INIS)

Kosaku, Yasuo; Kuroda, Toshimasa; Enoeda, Mikio; Hatano, Toshihisa; Sato, Satoshi; Miki, Nobuharu; Akiba, Masato

2003-06-01

The design of the breeding blanket in ITER applies pebble bed breeder in tube (BIT) surrounded by multiplier pebble bed. It is assumed to use the same module support mechanism and coolant manifolds and coolant system as the shielding blankets. This work focuses on the verification of the design of the breeding blanket, from the viewpoints which is especially unique to the pebble bed type breeding blanket, such as, tritium breeding performance, tritium inventory and release behavior and thermo-mechanical performance of the ITER breeding blanket. With respect to the neutronics analysis, the detailed analyses of the distribution of the nuclear heating rate and TBR have been performed in 2D model using MCNP to clarify the input data for the tritium inventory and release rate analyses and thermo-mechanical analyses. With respect to the tritium inventory and release behavior analysis, the parametric analyses for selection of purge gas flow rate were carried out from the view point of pressure drop and the tritium inventory/release performance for Li 2 TiO 3 breeder. The analysis result concluded that purge gas flow rate can be set to conventional flow rate setting (88 l/min per module) to 1/10 of that to save the purge gas flow and minimize the size of purge gas pipe. However, it is necessary to note that more tritium is transformed to HTO (chemical form of water) in case of Li 2 TiO 3 compared to other breeder materials. With respect to the thermo-mechanical analyses of the pebble bed blanket structure, the analyses have been performed by ABAQUS with 2D model derived from one of eight facets of a blanket module, based on the reference design. Analyses were performed to identify the temperature distribution incorporating the pebble bed mechanical simulation and influence of mechanical behavior to the thermal behavior. The result showed that the maximum temperature in the breeding material was 617degC in the first row of breeding rods and the minimum temperature was 328

Comparison of gravimetric, creamatocrit and esterified fatty acid methods for determination of total fat content in human milk.

Science.gov (United States)

Du, Jian; Gay, Melvin C L; Lai, Ching Tat; Trengove, Robert D; Hartmann, Peter E; Geddes, Donna T

2017-02-15

The gravimetric method is considered the gold standard for measuring the fat content of human milk. However, it is labor intensive and requires large volumes of human milk. Other methods, such as creamatocrit and esterified fatty acid assay (EFA), have also been used widely in fat analysis. However, these methods have not been compared concurrently with the gravimetric method. Comparison of the three methods was conducted with human milk of varying fat content. Correlations between these methods were high (r(2)=0.99). Statistical differences (Pmethods. Overall, stronger correlation with lower mean (4.73g/L) and percentage differences (5.16%) was observed with the creamatocrit than the EFA method when compared to the gravimetric method. Furthermore, the ease of operation and real-time analysis make the creamatocrit method preferable. Copyright © 2016. Published by Elsevier Ltd.

Zirconium determination in refractories (gravimetric method)

International Nuclear Information System (INIS)

Capiotto, N.; Narahashi, Y.; Perish, C.G.; Souza, J.R.

1991-01-01

The zirconium determination in refractories is described, consisting in two separation methods for eliminating the interferences. The formatted product is calcined at 1100 0 C and determined gravimetrically as Zr P z 07. (author)

Analysis of unsaturated clayey materials hydration incorporating the effect of thermo-osmotic flow

International Nuclear Information System (INIS)

Sanchez, M.; Arson, C.

2012-01-01

Document available in extended abstract form only. The hydraulic gradient is the main physical phenomenon influencing the movement of water in permeable porous media. It is, however, not the only one. Figure 1 presents the main kinds of flow that can occur in a porous media alongside with the corresponding gradient responsible for the movements. The word 'law' is generally used for the diagonal terms associated with the direct flow phenomena, and the name 'effect' is reserved to the non-diagonal ones, called also 'coupled processes'. Lippmann (1907) discovered and named the phenomenon of thermo-osmosis. He discovered it experimentally by separating a volume of water into two parts by means of a membrane. Different temperatures were held in the two regions of the system. The thermal gradient caused a flow of water through the membrane from the cold to the hot side. In permeable reservoirs, the non-diagonal coefficients are relatively small and negligible compared to the diagonal terms. That is the reason why the coupled processes are generally ignored when analyzing problems in aquifers. However, in non-isothermal problems involving low permeability media and/or low hydraulic gradients thermo-osmosis may play a more influential role. Srivastava and Avasthi (1975) and Horseman and McEwen (1996) showed that water flux due to thermo-osmosis can easily exceed Darcy flux in low permeability clays. The 'phenomenological coefficient' that links each flow with the corresponding driving gradient must be measured experimentally. Accounting for thermo-osmosis is assuming that the transport of heat may modify the transport of fluids. The counterpart phenomenon of thermo-osmosis is thermo-filtration, which reflects the influence of a pressure gradient on heat flow. Thermo-osmosis and thermo-filtration are generally formulated as reciprocal relations, so that the coupled conductivity terms related to each phenomenon are set equal. Thermo-osmotic effects have been studied in the

Fuel element thermo-mechanical analysis during transient events using the FMS and FETMA codes

International Nuclear Information System (INIS)

Hernandez Lopez Hector; Hernandez Martinez Jose Luis; Ortiz Villafuerte Javier

2005-01-01

In the Instituto Nacional de Investigaciones Nucleares of Mexico, the Fuel Management System (FMS) software package has been used for long time to simulate the operation of a BWR nuclear power plant in steady state, as well as in transient events. To evaluate the fuel element thermo-mechanical performance during transient events, an interface between the FMS codes and our own Fuel Element Thermo Mechanical Analysis (FETMA) code is currently being developed and implemented. In this work, the results of the thermo-mechanical behavior of fuel rods in the hot channel during the simulation of transient events of a BWR nuclear power plant are shown. The transient events considered for this work are a load rejection and a feedwater control failure, which among the most important events that can occur in a BWR. The results showed that conditions leading to fuel rod failure at no time appeared for both events. Also, it is shown that a transient due load rejection is more demanding on terms of safety that the failure of a controller of the feedwater. (authors)

Development of microbial resistant Carbopol nanocomposite hydrogels via a green process

CSIR Research Space (South Africa)

Varaprasad, K

2014-01-01

Full Text Available transform infrared (FTIR) spectroscopy, thermo-gravimetric analysis (TGA), scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS) and transmission electron microscopy (TEM). The pure and inorganic nanocomposite hydrogels developed were tested...

Thermo Techno Modern Analytical Equipment for Research and Industrial Laboratories

Directory of Open Access Journals (Sweden)

Khokhlov, S.V.

2014-03-01

Full Text Available A brief overview of some models of Thermo Techno analytical equipment and possible areas of their application is given. Thermo Techno Company was created in 2000 as a part of representative office of international corporation Thermo Fisher Scientific — world leader in manufacturing analytical equipments. Thermo Techno is a unique company in its integrated approach in solving the problems of the user, which includes a series of steps: setting the analytical task, selection of effective analysis methods, sample delivery and preparation as well as data transmitting and archiving.

Shortened carbon nanotubes and their influence on the electrical properties of polymer nanocomposites

NARCIS (Netherlands)

Inam, F.; Reece, M.J.; Peijs, A.A.J.M.

2012-01-01

Multi-wall carbon nanotubes of medium length (mCNTs) were aggressively tip-ultrasonicated to produce shortened and damaged carbon nanotubes (xCNTs). High-resolution electron microscopic analysis was performed to measure the dimensions of carbon nanotubes (CNTs). Thermo-gravimetric analysis and Raman

DABCO CONTAINING ACIDIC POLY(IONIC LIQUID): AN EFFICIENT ...

African Journals Online (AJOL)

3Department of Medicinal Chemistry, School of Pharmacy, Ardabil University of Medical. Sciences, Ardabil, Iran ... Two basic strategies have been utilized for PILs synthesis, 1) direct .... The thermo gravimetric analysis (TGA) of the catalyst was.

Combined-cycle steam section parametric analysis by thermo-economic simulation

International Nuclear Information System (INIS)

Macor, A.; Reini, M.

1991-01-01

In the case of industrial cogeneration plants, thermal power production is, in general, strictly dependent on the technological requirements of the production cycle, whereas, the electrical power which is produced can be auto- consumed or ceded to the utility grid. In both cases, an economic worth is given to this energy which influences the overall economic feasibility of the plant. The purpose of this paper is to examine parametric inter-relationships between economic and thermodynamic performance optimization techniques. Comparisons are then made of the results obtained with the use of the thermo- economic analysis technique suggested in this paper with those obtained with the use of indicators in other exergo-economic analysis techniques

Derivative thermo analysis of the near eutectic Al-Si-Cu alloy

Directory of Open Access Journals (Sweden)

L.A. Dobrzański

2008-12-01

Full Text Available For determining of the dependence between cooling Speer, chemical composition and structure of the Al–Si–Cu aluminium cast alloy the thermo-analysis was carried out, using the UMSA device (Universal Metallurgical Simulator and Analyzer, next the optical and electron scanning microscopy was used for investigation of the structure, phase and chemical composition of the AC-AlSi7Cu3Mg grade Al cast alloy also using the EDS microanalysis as well the EBSD technique.

Novel gravimetric measurement technique for quantitative volume calibration in the sub-microliter range

International Nuclear Information System (INIS)

Liang, Dong; Zengerle, Roland; Steinert, Chris; Ernst, Andreas; Koltay, Peter; Bammesberger, Stefan; Tanguy, Laurent

2013-01-01

We present a novel measurement method based on the gravimetric principles adapted from the ASTM E542 and ISO 4787 standards for quantitative volume determination in the sub-microliter range. Such a method is particularly important for the calibration of non-contact micro dispensers as well as other microfluidic devices. The novel method is based on the linear regression analysis of continuously monitored gravimetric results and therefore is referred to as ‘gravimetric regression method (GRM)’. In this context, the regression analysis is necessary to compensate the mass loss due to evaporation that is significant for very small dispensing volumes. A full assessment of the measurement uncertainty of GRM is presented and results in a standard measurement uncertainty around 6 nl for dosage volumes in the range from 40 nl to 1 µl. The GRM has been experimentally benchmarked with a dual-dye ratiometric photometric method (Artel Inc., Westbrook, ME, USA), which can provide traceability of measurement to the International System of Units (SI) through reference standards maintained by NIST. Good precision (max. CV = 2.8%) and consistency (bias around 7 nl in the volume range from 40 to 400 nl) have been observed comparing the two methods. Based on the ASTM and ISO standards on the one hand and the benchmark with the photometric method on the other hand, two different approaches for establishing traceability for the GRM are discussed. (paper)

Providing long-term trend and gravimetric factor at Chandler period from superconducting gravimeter records by using Singular Spectrum Analysis along with its multivariate extension

Science.gov (United States)

Gruszczynska, M.; Rosat, S.; Klos, A.; Bogusz, J.

2017-12-01

In this study, Singular Spectrum Analysis (SSA) along with its multivariate extension MSSA (Multichannel SSA) were used to estimate long-term trend and gravimetric factor at the Chandler wobble frequency from superconducting gravimeter (SG) records. We have used data from seven stations located worldwide and contributing to the International Geodynamics and Earth Tides Service (IGETS). The timespan ranged from 15 to 19 years. Before applying SSA and MSSA, we had removed local tides, atmospheric (ECMWF data), hydrological (MERRA2 products) loadings and non-tidal ocean loading (ECCO2 products) effects. In the first part of analysis, we used the SSA approach in order to estimate the long-term trends from SG observations. We use the technique based on the classical Karhunen-Loève spectral decomposition of time series into long-term trend, oscillations and noise. In the second part, we present the determination of common time-varying pole tide (annual and Chandler wobble) to estimate gravimetric factor from SG time series using the MSSA approach. The presented method takes advantage over traditional methods like Least Squares Estimation by determining common modes of variability which reflect common geophysical field. We adopted a 6-year lag-window as the optimal length to extract common seasonal signals and the Chandler components of the Earth polar motion. The signals characterized by annual and Chandler wobble account for approximately 62% of the total variance of residual SG data. Then, we estimated the amplitude factors and phase lags of Chandler wobble with respect to the IERS (International Earth Rotation and Reference Systems Service) polar motion observations. The resulting gravimetric factors at the Chandler Wobble period are finally compared with previously estimates. A robust estimate of the gravimetric Earth response to the Chandlerian component of the polar motion is required to better constrain the mantle anelasticity at this frequency and hence the

Theory and modeling of cylindrical thermo-acoustic transduction

Energy Technology Data Exchange (ETDEWEB)

Tong, Lihong, E-mail: lhtong@ecjtu.edu.cn [School of Civil Engineering and Architecture, East China Jiaotong University, Nanchang, Jiangxi (China); Lim, C.W. [Department of Architecture and Civil Engineering, City University of Hong Kong, Kowloon, Hong Kong SAR (China); Zhao, Xiushao; Geng, Daxing [School of Civil Engineering and Architecture, East China Jiaotong University, Nanchang, Jiangxi (China)

2016-06-03

Models both for solid and thinfilm-solid cylindrical thermo-acoustic transductions are proposed and the corresponding acoustic pressure solutions are obtained. The acoustic pressure for an individual carbon nanotube (CNT) as a function of input power is investigated analytically and it is verified by comparing with the published experimental data. Further numerical analysis on the acoustic pressure response and characteristics for varying input frequency and distance are also examined both for solid and thinfilm-solid cylindrical thermo-acoustic transductions. Through detailed theoretical and numerical studies on the acoustic pressure solution for thinfilm-solid cylindrical transduction, it is concluded that a solid with smaller thermal conductivity favors to improve the acoustic performance. In general, the proposed models are applicable to a variety of cylindrical thermo-acoustic devices performing in different gaseous media. - Highlights: • Theory and modeling both for solid and thinfilm-solid cylindrical thermo-acoustic transductions are proposed. • The modeling is verified by comparing with the published experimental data. • Acoustic response characteristics of cylindrical thermo-acoustic transductions are predicted by the proposed model.

Thermo-hydraulic analysis of the generic equatorial port plug design

International Nuclear Information System (INIS)

Rodríguez, E.; Guirao, J.; Ordieres, J.; Cortizo, J.L.; Iglesias, S.

2012-01-01

Highlights: ► Thermo-hydraulic transient performance evaluation and optimization of the GEPP structure cooling/heating system under neutronic heating and baking conditions. ► The optimization of the GEPP box structure's cooling system includes positioning and minimization of number and size of gun drilled channels, complying with the flow and functional requirements during operating and baking conditions. - Abstract: The port-based ITER diagnostic systems are housed primarily in two locations, the equatorial and upper port plugs. The port plug structure provides confinement function, maintains ultra-high vacuum quality and the first confinement barrier for radioactive materials at the ports. The port plug structure design, from the ITER International Organisation (IO), is cooled and heated by pressurized water which flows through a series of gun-drilled water channels and water pipes. The cooling function is required to remove nuclear heating due to radiation during operation of ITER, while the heating function is intended to heat up uniformly the machine during baking condition. The work presented provides coupled thermo-hydraulic analysis and optimization of a Generic Equatorial Port Plug (GEPP) structure cooling and heating system. The optimization performed includes positioning, minimization of number and size of gun drilled channels, complying with the flow and functional requirements during operating and baking conditions.

Gravimetric gas determinations for volume calibration

International Nuclear Information System (INIS)

Gibbs, P.W.

1991-01-01

Gravimetric measurements of gases is one of the methods available for calibrating gas volumes. By inputting a known quantity of gas and measuring the resulting pressure and temperature, the system volume can be calculated using gas law principles. Historically, this method has been less accurate due to the difficulty in the mass determination. This difficulty comes from several sources. Two examples are the large tare weight of the gas container relative to the weight of gas and the external volume of the gas container relative to the standards. The application of a gravimetric gas determination to tank volume calibrations at the savannah River Site is discussed. Mass determinations on a 25,00 gram gas container were such that a 1500 gram quantity of gas was routinely determined to within ±0.2 gram at the 99% confidence level. In this paper the weighting design and the methods used to address the difficulties of the mass determination are detailed

A systematic study on the use of ultrasound energy for the synthesis of nickel-metal organic framework compounds

NARCIS (Netherlands)

Sargazi, G.; Afzali, D.; Daldosso, N.; Kazemian, H.; Chauhan, N.P.S.; Sadeghian, Z.; Tajerian, T.; Ghafarinazari, A.; Mozafari, M.

2015-01-01

A nickel metal-organic framework (Ni-MOF) was successfully synthesized using ultrasound irradiation. Further to this, X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FT-IR), Thermo-Gravimetric Analysis (TGA), Differential Scanning Calorimetry

Uncertainty Quantification and Global Sensitivity Analysis of Subsurface Flow Parameters to Gravimetric Variations During Pumping Tests in Unconfined Aquifers

Science.gov (United States)

Maina, Fadji Zaouna; Guadagnini, Alberto

2018-01-01

We study the contribution of typically uncertain subsurface flow parameters to gravity changes that can be recorded during pumping tests in unconfined aquifers. We do so in the framework of a Global Sensitivity Analysis and quantify the effects of uncertainty of such parameters on the first four statistical moments of the probability distribution of gravimetric variations induced by the operation of the well. System parameters are grouped into two main categories, respectively, governing groundwater flow in the unsaturated and saturated portions of the domain. We ground our work on the three-dimensional analytical model proposed by Mishra and Neuman (2011), which fully takes into account the richness of the physical process taking place across the unsaturated and saturated zones and storage effects in a finite radius pumping well. The relative influence of model parameter uncertainties on drawdown, moisture content, and gravity changes are quantified through (a) the Sobol' indices, derived from a classical decomposition of variance and (b) recently developed indices quantifying the relative contribution of each uncertain model parameter to the (ensemble) mean, skewness, and kurtosis of the model output. Our results document (i) the importance of the effects of the parameters governing the unsaturated flow dynamics on the mean and variance of local drawdown and gravity changes; (ii) the marked sensitivity (as expressed in terms of the statistical moments analyzed) of gravity changes to the employed water retention curve model parameter, specific yield, and storage, and (iii) the influential role of hydraulic conductivity of the unsaturated and saturated zones to the skewness and kurtosis of gravimetric variation distributions. The observed temporal dynamics of the strength of the relative contribution of system parameters to gravimetric variations suggest that gravity data have a clear potential to provide useful information for estimating the key hydraulic

Comparison of Potentiometric and Gravimetric Methods for Determination of O/U Ratio

International Nuclear Information System (INIS)

Farida; Windaryati, L; Putro Kasino, P

1998-01-01

Comparison of determination O/U ratio by using potentiometric and gravimetric methods has been done. Those methods are simple, economical and having high precision and accuracy. Determination O/U ratio for UO 2 powder using potentiometric is carried out by adopting the davies-gray method. This technique is based on the redox reaction of uranium species such as U(IV) and U(VI). In gravimetric method,the UO 2 power as a sample is calcined at temperature of 900 C, and the weight of the sample is measured after calcination process. The t-student test show that there are no different result significantly between those methods. However, for low concentration in the sample the potentiometric method has a highed precision and accuracy compare to the gravimetric method. O/U ratio obtained is 2.00768 ± 0,00170 for potentiometric method 2.01089 ± 0,02395 for gravimetric method

Radiation processed hydrogels (wound dressings) for medical applications

International Nuclear Information System (INIS)

Varshney, Lalit

2004-01-01

Thermal analysis plays an important role in study and development of hydrogel materials for medical applications. Thermal stability of the ingredients which is important from the point of manufacturing, rate of evaporation for shelf life evaluation, determination of gelation and temperature responsive temperatures, cooling behaviour, gel elasticity, radiation effects etc. can be studied using thermal analysis equipment like Differential scanning calorimetry (DSC), Thermo-gravimetric analysis (TGA) and thermo-mechanical analysis (TMA). In this use of these techniques in development, evaluation and quality control of hydrogel wound dressing is discussed

An Integrated Solution for Performing Thermo-fluid Conjugate Analysis

Science.gov (United States)

Kornberg, Oren

2009-01-01

A method has been developed which integrates a fluid flow analyzer and a thermal analyzer to produce both steady state and transient results of 1-D, 2-D, and 3-D analysis models. The Generalized Fluid System Simulation Program (GFSSP) is a one dimensional, general purpose fluid analysis code which computes pressures and flow distributions in complex fluid networks. The MSC Systems Improved Numerical Differencing Analyzer (MSC.SINDA) is a one dimensional general purpose thermal analyzer that solves network representations of thermal systems. Both GFSSP and MSC.SINDA have graphical user interfaces which are used to build the respective model and prepare it for analysis. The SINDA/GFSSP Conjugate Integrator (SGCI) is a formbase graphical integration program used to set input parameters for the conjugate analyses and run the models. The contents of this paper describes SGCI and its thermo-fluids conjugate analysis techniques and capabilities by presenting results from some example models including the cryogenic chill down of a copper pipe, a bar between two walls in a fluid stream, and a solid plate creating a phase change in a flowing fluid.

Gravimetric Analysis of Bismuth in Bismuth Subsalicylate Tablets: A Versatile Quantitative Experiment for Undergraduate Laboratories

Science.gov (United States)

Davis, Eric; Cheung, Ken; Pauls, Steve; Dick, Jonathan; Roth, Elijah; Zalewski, Nicole; Veldhuizen, Christopher; Coeler, Joel

2015-01-01

In this laboratory experiment, lower- and upper-division students dissolved bismuth subsalicylate tablets in acid and precipitated the resultant Bi[superscript 3+] in solution with sodium phosphate for a gravimetric determination of bismuth subsalicylate in the tablets. With a labeled concentration of 262 mg/tablet, the combined data from three…

Combination volumetric and gravimetric sorption instrument for high accuracy measurements of methane adsorption

Science.gov (United States)

Burress, Jacob; Bethea, Donald; Troub, Brandon

2017-05-01

The accurate measurement of adsorbed gas up to high pressures (˜100 bars) is critical for the development of new materials for adsorbed gas storage. The typical Sievert-type volumetric method introduces accumulating errors that can become large at maximum pressures. Alternatively, gravimetric methods employing microbalances require careful buoyancy corrections. In this paper, we present a combination gravimetric and volumetric system for methane sorption measurements on samples between ˜0.5 and 1 g. The gravimetric method described requires no buoyancy corrections. The tandem use of the gravimetric method allows for a check on the highest uncertainty volumetric measurements. The sources and proper calculation of uncertainties are discussed. Results from methane measurements on activated carbon MSC-30 and metal-organic framework HKUST-1 are compared across methods and within the literature.

Mycotoxin metrology: Gravimetric production of zearalenone calibration solution

Science.gov (United States)

Rego, E. C. P.; Simon, M. E.; Li, Xiuqin; Li, Xiaomin; Daireaux, A.; Choteau, T.; Westwood, S.; Josephs, R. D.; Wielgosz, R. I.; Cunha, V. S.

2018-03-01

Food safety is a major concern for countries developing metrology and quality assurance systems, including the contamination of food and feed by mycotoxins. To improve the mycotoxin analysis and ensure the metrological traceability, CRM of calibration solution should be used. The production of certified mycotoxin solutions is a major challenge due to the limited amount of standard for conducting a proper purity study and due to the cost of standards. The CBKT project was started at BIPM and Inmetro produced gravimetrically one batch of zearelenone in acetronitrile (14.708 ± 0.016 μg/g, k=2) and conducted homogeneity, stability and value assignment studies.

Improving Thermo-Oxidative Stability of Nitrile Rubber Composites by Functional Graphene Oxide.

Science.gov (United States)

Zhong, Rui; Zhang, Zhao; Zhao, Hongguo; He, Xianru; Wang, Xin; Zhang, Rui

2018-05-30

Graphene oxide (GO), modified with anti-aging agent p -phenylenediamine (PPD), was added into nitrile rubber (NBR) in order to improve the thermo-oxidative stability of NBR. The modification of GO and the transformation of functional groups were characterized by Fourier transform infrared spectroscopy (FTIR), Raman, and X-ray diffraction (XRD). Mechanical performances of NBR composites before and after the thermo-oxidative aging were recorded. The results of dynamic mechanical analysis (DMA) show an increased storage modulus (G') and a decreased value of area of tan δ peak after introducing modified GO into NBR. It indicates that filler particles show positive interaction with molecular chains. The thermo-oxidative stability of composites was investigated by thermogravimetric analysis (TG) and differential scanning calorimetry (DSC). Then, the thermo-oxidative aging kinetic parameters were obtained by the Flynn⁻Wall⁻Ozawa (FWO) equation. The results of aging tests show that the thermo-oxidative stability of rubber matrix increases obviously after introducing GO⁻PPD. In addition, mechanical properties (tensile strength and elongation at break) of both before and after aged NBR/GO⁻PPD composites were superior to that of NBR. This work provides meaningful guidance for achieving multifunction thermo-oxidative aging resistance rubber composites.

Thermo-Fluid Dynamics of Two-Phase Flow

CERN Document Server

Ishii, Mamrou

2011-01-01

"Thermo-fluid Dynamics of Two-Phase Flow, Second Edition" is focused on the fundamental physics of two-phase flow. The authors present the detailed theoretical foundation of multi-phase flow thermo-fluid dynamics as they apply to: Nuclear reactor transient and accident analysis; Energy systems; Power generation systems; Chemical reactors and process systems; Space propulsion; Transport processes. This edition features updates on two-phase flow formulation and constitutive equations and CFD simulation codes such as FLUENT and CFX, new coverage of the lift force model, which is of part

A detailed gravimetric geoid from North America to Eurasia

Science.gov (United States)

Vincent, S. F.; Strange, W. E.; Marsh, J. G.

1972-01-01

A detailed gravimetric geoid of the United States, North Atlantic, and Eurasia, which was computed from a combination of satellite derived and surface gravity data, is presented. The precision of this detailed geoid is + or - 2 to + or - 3 m in the continents but may be in the range of 5 to 7 m in those areas where data is sparse. Comparisons of the detailed gravimetric geoid with results of Rapp, Fischer, and Rice for the United States, Bomford in Europe, and Heiskanen and Fischer in India are presented. Comparisons are also presented with geoid heights from satellite solutions for geocentric station coordinates in North America, the Caribbean, and Europe.

Clinical application of transcatheter arterial thermo-chemotherapy and thermo-lipiodol embolization in treatment of hepatocellular carcinoma

International Nuclear Information System (INIS)

Wang Xuan; Chen Xiaofei; Dong Weihua

2007-01-01

Objective: To evaluate the clinical efficacy of thermo-chemotherapy and thermo-lipiodol embolization in treatment of primary hepatocellular carcinoma(PHC). Methods: One hundred and sixteen cases of PHC were divided into three groups. Group A (38 cases)was treated with normal temperature chemotherapy and normal temperature lipiodol, Group B(40 cases)with thermo-chemotherapy and normal temperature lipiodol and group C (38 cases)with thermo-chemotherapy and thermo-lipiodol. Group B and group C were called the thermotherapy group. Results: In the thermotherapy groups, the rates of tumor size reduction were significantly greater than those in the normal group. There were no significant different in the hepatic function tests among the three groups. The 6-, 12-, 18-, and 24- month survival rates of the normal group and thermotherapy groups were 97%, 58%, 39% and 18%, versus 99%, 79%, 57% and 36%, respectively. No significant differences were found in the rates of reduction of tumor size and survival rates between group B and group C. Conclusion: Thermo-chemotherapy and thermo-embolization possess significant effect on PHC but without conspicuous damage to liver function. (authors)

Combined Colorimetric and Gravimetric CMUT Sensor for Detection of Phenylacetone

DEFF Research Database (Denmark)

Mølgaard, Mathias Johannes Grøndahl; Laustsen, Milan; Thygesen, Ida Lysgaard

2017-01-01

The detection of phenylacetone is of interest as it is a common precursor for the synthesis of (meth)amphetamine. Resonant gravimetric sensors can be used to detect the mass and hereby the concentration of a gas while colorimetric arrays typically have an exceptional selectivity to the target...... analyte if the right colorimetric dyes are chosen. We present a sensor system consisting of a Capacitive Micromachined Ultrasonic Transducer (CMUT) and a colorimetric array for detection of phenylacetone. The CMUT is used as a resonant gravimetric gas sensor where the resonance frequency shift due to mass...

Generalized Fluid System Simulation Program (GFSSP) Version 6 - General Purpose Thermo-Fluid Network Analysis Software

Science.gov (United States)

Majumdar, Alok; Leclair, Andre; Moore, Ric; Schallhorn, Paul

2011-01-01

GFSSP stands for Generalized Fluid System Simulation Program. It is a general-purpose computer program to compute pressure, temperature and flow distribution in a flow network. GFSSP calculates pressure, temperature, and concentrations at nodes and calculates flow rates through branches. It was primarily developed to analyze Internal Flow Analysis of a Turbopump Transient Flow Analysis of a Propulsion System. GFSSP development started in 1994 with an objective to provide a generalized and easy to use flow analysis tool for thermo-fluid systems.

Improving Thermo-Oxidative Stability of Nitrile Rubber Composites by Functional Graphene Oxide

Directory of Open Access Journals (Sweden)

Rui Zhong

2018-05-01

Full Text Available Graphene oxide (GO, modified with anti-aging agent p-phenylenediamine (PPD, was added into nitrile rubber (NBR in order to improve the thermo-oxidative stability of NBR. The modification of GO and the transformation of functional groups were characterized by Fourier transform infrared spectroscopy (FTIR, Raman, and X-ray diffraction (XRD. Mechanical performances of NBR composites before and after the thermo-oxidative aging were recorded. The results of dynamic mechanical analysis (DMA show an increased storage modulus (G’ and a decreased value of area of tan δ peak after introducing modified GO into NBR. It indicates that filler particles show positive interaction with molecular chains. The thermo-oxidative stability of composites was investigated by thermogravimetric analysis (TG and differential scanning calorimetry (DSC. Then, the thermo-oxidative aging kinetic parameters were obtained by the Flynn–Wall–Ozawa (FWO equation. The results of aging tests show that the thermo-oxidative stability of rubber matrix increases obviously after introducing GO–PPD. In addition, mechanical properties (tensile strength and elongation at break of both before and after aged NBR/GO–PPD composites were superior to that of NBR. This work provides meaningful guidance for achieving multifunction thermo-oxidative aging resistance rubber composites.

Modified method for zirconium or hafnium gravimetric determination with glycolic acid derivatives

International Nuclear Information System (INIS)

Barbieri, R.S.; Rocha, J.C.; Terra, V.R.; Marques Neto, A.

1989-01-01

The conditions for gravimetric determination of zirconium or hafnium by glicolic acid derivatives were studied by thermogravimetric analysis. The method utilized shown that after precipitation, washing and drying of precipitates at 150 0 C, the resulting solid was weighed in the form of [M{RCH(OH)COO} 4 ] (M = Zr,Hf;R = C 6 H 5 , β-C 10 H 7 ,p-BrC 6 H 4 ). (author) [pt

Synthesis of new thermo/pH sensitive drug delivery systems based on tragacanth gum polysaccharide.

Science.gov (United States)

Hemmati, Khadijeh; Ghaemy, Mousa

2016-06-01

In this study, new pH/temperature responsive graft copolymers were synthesized based on natural Tragacanth Gum (TG) carbohydrate and their controlled drug release was investigated. Amphiphilic alkyne terminated terpolymers (mPEG-PCL-PDMAEMA-CCH)s consist of methylated poly(ethyleneglycol) (mPEG), polycaprolactone (PCL), and poly(dimethylaminoethylmethacrylate) (PDMAEMA) were synthesized by using ring opening polymerization (ROP) and atom transfer radical polymerization (ATRP), and then were grafted onto azide-functionalized TG molecules by click chemistry. Different techniques such as FT-IR, (1)H NMR, gel permeation chromatography (GPC), thermo-gravimetrical analysis (TGA) and scanning electron microscopy (SEM) were used to verify the successful synthesis of graft copolymers (TG-g-PDMAEMA-PCL-mPEG)s. The graft copolymers self-assembled to single micelles in aqueous solution and upon pH changes further assembled into micellar aggregates. These micelles were used to prepare quercetin loaded nanocarriers by probe sonication method. Size and morphology of the nanocarriers were studied by dynamic light scattering (DLS) and SEM. The in vitro release behavior of quercetin from these micelles showed pH-dependence. The results showed that release profile of quercetin best followed the first order model. Copyright © 2016 Elsevier B.V. All rights reserved.

Synthesis, characterization and behaviour to gamma radiation of the bis-L-alaninato-copper (II)

International Nuclear Information System (INIS)

Passos, B.F.T.

1985-01-01

The behaviour of coordinated compound obtained from the copper (II) and the L-(+)- alanine to gamma radiation was determined. A study of synthesis and characterization of this complex was made with elementary analysis, ultraviolet and visible electronic spectroscopy, infrared vibrational spectroscopy, proton magnetic resonance spectroscopy and thermo-gravimetric analysis. (C.G.C.)

Gravimetric and volumetric approaches adapted for hydrogen sorption measurements with in situ conditioning on small sorbent samples

International Nuclear Information System (INIS)

Poirier, E.; Chahine, R.; Tessier, A.; Bose, T.K.

2005-01-01

We present high sensitivity (0 to 1 bar, 295 K) gravimetric and volumetric hydrogen sorption measurement systems adapted for in situ sample conditioning at high temperature and high vacuum. These systems are designed especially for experiments on sorbents available in small masses (mg) and requiring thorough degassing prior to sorption measurements. Uncertainty analysis from instrumental specifications and hydrogen absorption measurements on palladium are presented. The gravimetric and volumetric systems yield cross-checkable results within about 0.05 wt % on samples weighing from (3 to 25) mg. Hydrogen storage capacities of single-walled carbon nanotubes measured at 1 bar and 295 K with both systems are presented

Measuring intestinal fluid transport in vitro: Gravimetric method versus non-absorbable marker.

Science.gov (United States)

Whittamore, Jonathan M; Genz, Janet; Grosell, Martin; Wilson, Rod W

2016-04-01

The gut sac is a long-standing, widely used in vitro preparation for studying solute and water transport, and calculation of these fluxes requires an accurate assessment of volume. This is commonly determined gravimetrically by measuring the change in mass over time. While convenient this likely under-estimates actual net water flux (Jv) due to tissue edema. We evaluated whether the popular in vivo volume marker [(14)C]-PEG 4000, offers a more representative measure of Jvin vitro. We directly compared these two methods in five teleost species (toadfish, flounder, rainbow trout, killifish and tilapia). Net fluid absorption by the toadfish intestine based on PEG was significantly higher, by almost 4-fold, compared to gravimetric measurements, compatible with the latter under-estimating Jv. Despite this, PEG proved inconsistent for all of the other species frequently resulting in calculation of net secretion, in contrast to absorption seen gravimetrically. Such poor parallelism could not be explained by the absorption of [(14)C]-PEG (typically gravimetric method therefore remains the most reliable measure of Jv and we urge caution in the use of PEG as a volume marker. Copyright © 2016 Elsevier Inc. All rights reserved.

Thermo-Hydraulic Modelling of Buffer and Backfill

International Nuclear Information System (INIS)

Pintado, X.; Rautioaho, E.

2013-09-01

The temporal evolution of saturation, liquid pressure and temperature in the components of the engineered barrier system was studied using numerical methods. A set of laboratory tests was conducted to calibrate the parameters employed in the models. The modelling consisted of thermal, hydraulic and thermo-hydraulic analysis in which the significant thermo-hydraulic processes, parameters and features were identified. CODE B RIGHT was used for the finite element modelling and supplementary calculations were conducted with analytical methods. The main objective in this report is to improve understanding of the thermo-hydraulic processes and material properties that affect buffer behaviour in the Olkiluoto repository and to determine the parametric requirements of models for the accurate prediction of this behaviour. The analyses consisted of evaluating the influence of initial canister temperature and gaps in the buffer, and the role played by fractures and the rock mass located between fractures in supplying water for buffer and backfill saturation. In the thermo-hydraulic analysis, the primary processes examined were the effects of buffer drying near the canister on temperature evolution and the manner in which heat flow affects the buffer saturation process. Uncertainties in parameters and variations in the boundary conditions, modelling geometry and thermo-hydraulic phenomena were assessed with a sensitivity analysis. The material parameters, constitutive models, and assumptions made were carefully selected for all the modelling cases. The reference parameters selected for the simulations were compared and evaluated against laboratory measurements. The modelling results highlight the importance of understanding groundwater flow through the rock mass and from fractures in the rock in order to achieve reliable predictions regarding buffer saturation, since saturation times could range from a few years to tens of thousands of years depending on the hydrogeological

Near infrared spectrometry for faecal fat measurement: comparison with conventional gravimetric and titrimetric methods.

Science.gov (United States)

Benini, L; Caliari, S; Guidi, G C; Vaona, B; Talamini, G; Vantini, I; Scuro, L A

1989-01-01

This investigation was aimed at comparing a new method for measuring faecal fat excretion, carried out with a semi-automated instrument by using near infrared analysis (NIRA), with the traditional titrimetric (Van de Kamer) and gravimetric (Sobel) methods. Near infrared analysis faecal fat was assayed on the three day stool collection from 118 patients (68 chronic pancreatitis, 19 organic diseases of the gastrointestinal tract, 19 alcoholic liver disease, 12 functional gastrointestinal disorders). A strict linear correlation was found between NIRA and both the titrimetric (r = 0.928, p less than 0.0001) and the gravimetric (r = 0.971, p less than 0.0001) methods. On homogenised faeces, a mean coefficient of variation of 2.1 (SD 1.71)% was found. Before homogenisation (where a mean coefficient of variation of 7% was found) accurate results were obtained when the mean of five measurements was considered. In conclusion, the assay of faecal fat excretion by the near infrared reflessometry appears a simple, rapid and reliable method for measuring steatorrhoea. PMID:2583563

Thermo-mechanical analysis of a user filter assembly for undulator/wiggler operations at the Advanced Photon Source

International Nuclear Information System (INIS)

Nian, H.L.T.; Kuzay, T.M.; Collins, J.; Shu, D.; Benson, C.; Dejus, R.

1996-01-01

This paper reports a thermo-mechanical study of a beamline filter (user filter) for undulator/wiggler operations. It is deployed in conjunction with the current commissioning window assembly on the APS insertion device (ID) front ends. The beamline filter at the Advanced Photon Source (APS) will eventually be used in windowless operations also. Hence survival and reasonable life expectancy of the filters under intense insertion device (ID) heat flu are crucial to the beamline operations. To accommodate various user requirements, the filter is configured to be a multi-choice type and smart to allow only those filter combinations that will be safe to operate with a given ring current and beamline insertion device gap. However, this paper addresses only the thermo-mechanical analysis of individual filter integrity and safety in all combinations possible. The current filter design is configured to have four filter frames in a cascade with each frame holding five filters. This allows a potential 625 total filter combinations. Thermal analysis for all of these combinations becomes a mammoth task considering the desired choices for filter materials (pyrolitic graphite and metallic filters), filter thicknesses, undulator gaps, and the beam currents. The paper addresses how this difficult task has been reduced to a reasonable effort and computational level. Results from thermo-mechanical analyses of the filter combinations are presented both in tabular and graphical format

Thermo-plasmonics of Irradiated Metallic Nanostructures

DEFF Research Database (Denmark)

Ma, Haiyan

Thermo-plasmonics is an emerging field in photonics which aims at harnessing the kinetic energy of light to generate nanoscopic sources of heat. Localized surface plasmons (LSP) supported by metallic nanostructures greatly enhance the interactions of light with the structure. By engineering...... delivery, nano-surgeries and thermo-transportations. Apart from generating well-controlled temperature increase in functional thermo-plasmonic devices, thermo-plasmonics can also be used in understanding complex phenomena in thermodynamics by creating drastic temperature gradients which are not accessible...... using conventional techniques. In this thesis, we present novel experimental and numerical tools to characterize thermo-plasmonic devices in a biologically relevant environment, and explore the thermodiffusion properties and measure thermophoretic forces for particles in temperature gradients ranging...

40 CFR 1065.290 - PM gravimetric balance.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 32 2010-07-01 2010-07-01 false PM gravimetric balance. 1065.290... balance. (a) Application. Use a balance to weigh net PM on a sample medium for laboratory testing. (b) Component requirements. We recommend that you use a balance that meets the specifications in Table 1 of...

A gravimetric simplified method for nucleated marrow cell counting using an injection needle.

Science.gov (United States)

Saitoh, Toshiki; Fang, Liu; Matsumoto, Kiyoshi

2005-08-01

A simplified gravimetric marrow cell counting method for rats is proposed for a regular screening method. After fresh bone marrow was aspirated by an injection needle, the marrow cells were suspended in carbonate buffered saline. The nucleated marrow cell count (NMC) was measured by an automated multi-blood cell analyzer. When this gravimetric method was applied to rats, the NMC of the left and right femurs had essentially identical values due to careful handling. The NMC at 4 to 10 weeks of age in male and female Crj:CD(SD)IGS rats was 2.72 to 1.96 and 2.75 to 1.98 (x10(6) counts/mg), respectively. More useful information for evaluation could be obtained by using this gravimetric method in addition to myelogram examination. However, some difficulties with this method include low NMC due to blood contamination and variation of NMC due to handling. Therefore, the utility of this gravimetric method for screening will be clarified by the accumulation of the data on myelotoxicity studies with this method.

Computation of improved tidal parameters at the gravimetric station of Brasimone

Directory of Open Access Journals (Sweden)

P. Baldi

1997-06-01

Full Text Available Since 1991 a GWR superconducting gravimeter has been working in a laboratory at the Brasimone ENEA Research Centre, near Bologna (Italy, in the frame of an experimental program to verify Newton's law over distances of the order of 10-100 m. Owing to the aim of the experiment, the gravimeter was moved to different laboratories in the same area, but from August 1995 to date it has been working continuously in the same laboratory in the frame of the preliminary program of the Global Geodynamics Project. The site, belonging to a building of a dismissed nuclear power plant, is free from noise due to human activities, and is thus highly suitable for recording Earth tides. Starting from a set of gravimetric and atmospheric pressure data of high quality relative to 22 months of observation, we performed the tidal analysis using Eterna 3.2 software in order to compute amplitudes, gravimetric factors and phases of the main waves of the Tamura 1987 catalogue. The accuracy of the method adopted for the calibration of the gravimeter, the values of the principal waves and the result of the computation of atmospheric pressure admittance are described.

Probabilistic thermo-chemical analysis of a pultruded composite rod

DEFF Research Database (Denmark)

Baran, Ismet; Tutum, Cem Celal; Hattel, Jesper Henri

2012-01-01

In the present study the deterministic thermo-chemical pultrusion simulation of a composite rod taken from the literature [7] is used as a validation case. The predicted centerline temperature and cure degree profiles of the rod match well with those in the literature [7]. Following the validation...

Fuel Fracture (Crumbling) Safety Impact (OCRWM)

International Nuclear Information System (INIS)

DUNCAN, D.R.

1999-01-01

The safety impact of experimentally observed N Reactor fuel sample fracture and fragmentation is evaluated using an average reaction rate enhancement derived from data from thermo-gravimetric analysis (TGA) experiments on fuel samples. The enhanced reaction rates attributed to fragmentation were within the existing safety basis

Synthesis of BiFeO 3 by carbonate precipitation

Indian Academy of Sciences (India)

Magnetoelectric multiferroic BiFeO3 (BFO) was synthesized by a simple carbonate precipitation technique of metal nitrate solutions. X-ray powder diffraction and thermo-gravimetric analysis (TGA) revealed that the precipitate consists of an intimate mixture of crystalline bismuth carbonate and an amorphous hydroxide of ...

Structural, thermal and optical behavior of 84 MeV oxygen and 120 MeV silicon ions irradiated PES

International Nuclear Information System (INIS)

Samra, Kawaljeet Singh; Thakur, Sonika; Singh, Lakhwant

2011-01-01

In order to study structural, thermal and optical behavior, thin flat samples of polyethersulfone were irradiated with oxygen and silicon ions. The changes in properties were analyzed using different techniques viz: X-ray diffraction, thermo-gravimetric analysis, Fourier transform infrared, UV-visible and photoluminescence spectroscopy. A noticeable increase in the intensity of X-ray diffraction peaks was observed after irradiation with 84 MeV oxygen ions at low and medium fluences, which may be attributed to radiation-induced cross-linking in polymer. Fourier transform infrared and thermo-gravimetric analysis corroborated the results of X-ray diffraction analysis. No noticeable change in the Fourier transform infrared spectra of oxygen ion irradiated polyethersulfone were observed even at the highest fluence of 1 x 10 13 ions cm -2 , but after irradiation with silicon ions, a reduction in intensity of almost all characteristic bands was revealed. An increase in the activation energy of decomposition of polyethersulfone was observed after irradiation with 84 MeV oxygen ions up to medium fluences but degradation was revealed at higher fluences. Similar trends were observed by photoluminescence analysis.

Thermo-economic multi-objective optimization of solar dish-Stirling engine by implementing evolutionary algorithm

International Nuclear Information System (INIS)

Ahmadi, Mohammad H.; Sayyaadi, Hoseyn; Mohammadi, Amir H.; Barranco-Jimenez, Marco A.

2013-01-01

Highlights: • Thermo-economic multi-objective optimization of solar dish-Stirling engine is studied. • Application of the evolutionary algorithm is investigated. • Error analysis is done to find out the error through investigation. - Abstract: In the recent years, remarkable attention is drawn to Stirling engine due to noticeable advantages, for instance a lot of resources such as biomass, fossil fuels and solar energy can be applied as heat source. Great number of studies are conducted on Stirling engine and finite time thermo-economic is one of them. In the present study, the dimensionless thermo-economic objective function, thermal efficiency and dimensionless power output are optimized for a dish-Stirling system using finite time thermo-economic analysis and NSGA-II algorithm. Optimized answers are chosen from the results using three decision-making methods. Error analysis is done to find out the error through investigation

Interpretation of Gravimetric and Aeromagnetic Data of the Tecoripa Chart in Southeast Sonora, Mexico.

Science.gov (United States)

Martínez-Retama, S.; Montaño-Del Cid, M. A.

2015-12-01

The Tecoripa chart H12-D64 is located southeast of the state of Sonora, México, south of Arizona. The geology is represented by sedimentary rocks of the Ordovician and Triassic, volcanic rocks of the Upper Cretaceous and Tertiary, intrusive rocks from the Upper Cretaceous- Tertiary and sedimentary rocks of the Cenozoic. In this paper a gravimetric study was conducted to determine the configuration and depth of the basement and to develop a structural model of the subsurface. For this purpose a consistent gravimetric survey in 3 profiles was conducted. To complement this study, gravimetric data obtained by INEGI (96 gravimetric stations spaced every 4000 m) that correspond to a regional survey was also used. The two sets of data were corrected and processed with the WinGLink software. The profiles were then modeled using the Talwani method. 4 Profiles corresponding to the gravimetric survey and 5 data profiles from INEGI were modeled. Aeromagnetic data from the total field of Tecoripa chart were also processed. The digital information was integrated and processed by generating a data grid. Processes applied to data consisted of reduction to the pole, regional-residual separation and upward continuations. In general, the obtained structural models show intrusive bodies associated with well-defined high gravimetric and magnetic and low gravimetric and magnetic are associated with basins and sedimentary rocks. The obtained geological models show the basement represented by volcanic rocks of the Tarahumara Formation from the Upper Cretaceous which are in contact with sedimentary rocks from the Barranca Group from Upper Cretaceous and limestones from the Middle Ordovician. Both volcanic and sedimentary rocks are intruded by granodiorite- granite with ages of the Tertiary-Oligocene. Based on the superficial geology as well as in the configuration of the basement and the obtained structural model the existence of faults with NW-SE orientation that originate Horst and

Technical support for GEIS: radioactive waste isolation in geologic formations. Volume 20. Thermo-mechanical stress analysis and development of thermal loading guidelines

International Nuclear Information System (INIS)

1978-04-01

This volume is one of a 23-volume series which supplements a Contribution to Draft Generic Environmental Impact Statement on Commercial Waste Management: Radioactive Waste Isolation in Geologic Formations, Y/OWI/TM-44. The series provides a more complete technical basis for the preconceptual designs, resource requirements, and environmental source terms associated with isolating commercial LWR wastes in underground repositories in salt, granite, shale and basalt. Wastes are considered from three fuel cycles: uranium and plutonium recycling, no recycling of spent fuel, and uranium-only recycling. The thermo-mechanical analysis of proposed preconceptual repositories in granite, shale and basalt have been undertaken. The analysis, was conducted on three different levels of scale (i) Very Near Field (canister scale), (ii) Near Field (excavation scale) and (iii) Far Field (regional scale) studies. Three numerical methods were used to undertake the thermo-mechanical calculations; namely, the finite element method for thermal stress analysis, the boundary element method for thermal and thermal stress analysis and the semi-analytical method also for thermal and thermal stresses analysis. From the thermo-mechanical studies with simplifying assumptions on rock mass behavior where applicable, recommendations for areal thermal loadings to assure retrievability of the canisters and long term safety of the repository are given

Role of thermo-analytical techniques in compositional characterization of nuclear materials

International Nuclear Information System (INIS)

Raje, Naina

2015-01-01

The study of heat effects on different materials has a long history. Extraction of metals from the ores, pottery production, glasses making etc. are the examples, where the performance of products obtained from raw materials depends on the processing temperatures. Concrete, pottery, bricks etc., are severely damaged due to uncontrolled high temperatures. Therefore, the heating of raw materials in controlled manner is of pivotal importance to get products of the desired quality. Thermo-analytical techniques provide the information on the effect of heat under controlled heating conditions. In thermo-analytical techniques, physical properties of materials are measured as a function of temperature. Simultaneous thermo-analytical techniques are beneficial in comparison to any single thermo-analytical technique. Simultaneous techniques refer to the measurement of two or more signals on the same sample at the same time in the same instrument. Nowadays, simultaneous thermo-analytical technique are extensively in use for the analysis of materials. Ammonium diuranate (ADU) and magnesium diuranate (MDU), also known as yellowcake, are intermediate precursors in fuel fabrication process, with stringent specifications along with the need to understand its thermal behavior. In the processing of lowgrade ores, higher levels of impurities are being encountered in the leach solution that affects the properties of ADU/MDU. In order to meet the fuel specifications, quality assurance of these nuclear materials is essential. Current studies describe the application of simultaneous Thermogravimetry (TG) - differential thermal analysis (DTA) - evolved gas analysis (EGA) techniques for the compositional characterization of ADU/MDU with respect to the impurities present in the matrices

Comparison of fine particle measurements from a direct-reading instrument and a gravimetric sampling method.

Science.gov (United States)

Kim, Jee Young; Magari, Shannon R; Herrick, Robert F; Smith, Thomas J; Christiani, David C

2004-11-01

Particulate air pollution, specifically the fine particle fraction (PM2.5), has been associated with increased cardiopulmonary morbidity and mortality in general population studies. Occupational exposure to fine particulate matter can exceed ambient levels by a large factor. Due to increased interest in the health effects of particulate matter, many particle sampling methods have been developed In this study, two such measurement methods were used simultaneously and compared. PM2.5 was sampled using a filter-based gravimetric sampling method and a direct-reading instrument, the TSI Inc. model 8520 DUSTTRAK aerosol monitor. Both sampling methods were used to determine the PM2.5 exposure in a group of boilermakers exposed to welding fumes and residual fuel oil ash. The geometric mean PM2.5 concentration was 0.30 mg/m3 (GSD 3.25) and 0.31 mg/m3 (GSD 2.90)from the DUSTTRAK and gravimetric method, respectively. The Spearman rank correlation coefficient for the gravimetric and DUSTTRAK PM2.5 concentrations was 0.68. Linear regression models indicated that log, DUSTTRAK PM2.5 concentrations significantly predicted loge gravimetric PM2.5 concentrations (p gravimetric PM2.5 concentrations was found to be modified by surrogate measures for seasonal variation and type of aerosol. PM2.5 measurements from the DUSTTRAK are well correlated and highly predictive of measurements from the gravimetric sampling method for the aerosols in these work environments. However, results from this study suggest that aerosol particle characteristics may affect the relationship between the gravimetric and DUSTTRAK PM2.5 measurements. Recalibration of the DUSTTRAK for the specific aerosol, as recommended by the manufacturer, may be necessary to produce valid measures of airborne particulate matter.

Inert gas narcosis has no influence on thermo-tactile sensation.

Science.gov (United States)

Jakovljević, Miroljub; Vidmar, Gaj; Mekjavic, Igor B

2012-05-01

Contribution of skin thermal sensors under inert gas narcosis to the raising hypothermia is not known. Such information is vital for understanding the impact of narcosis on behavioural thermoregulation, diver safety and judgment of thermal (dis)comfort in the hyperbaric environment. So this study aimed at establishing the effects of normoxic concentration of 30% nitrous oxide (N(2)O) on thermo-tactile threshold sensation by studying 16 subjects [eight females and eight males; eight sensitive (S) and eight non-sensitive (NS) to N(2)O]. Their mean (SD) age was 22.1 (1.8) years, weight 72.8 (15.3) kg, height 1.75 (0.10) m and body mass index 23.8 (3.8) kg m(-2). Quantitative thermo-tactile sensory testing was performed on forearm, upper arm and thigh under two experimental conditions: breathing air (air trial) and breathing normoxic mixture of 30% N(2)O (N(2)O trial) in the mixed sequence. Difference in thermo-tactile sensitivity thresholds between two groups of subjects in two experimental conditions was analysed by 3-way mixed-model analysis of covariance. There were no statistically significant differences in thermo-tactile thresholds either between the Air and N(2)O trials, or between S and NS groups, or between females and males, or with respect to body mass index. Some clinically insignificant lowering of thermo-tactile thresholds occurred only for warm thermo-tactile thresholds on upper arm and thigh. The results indicated that normoxic mixture of 30% N(2)O had no influence on thermo-tactile sensation in normothermia.

REFLA-1D/MODE3: a computer code for reflood thermo-hydrodynamic analysis during PWR-LOCA

International Nuclear Information System (INIS)

Murao, Yoshio; Okubo, Tsutomu; Sugimoto, Jun; Iguchi, Tadashi; Sudoh, Takashi.

1985-02-01

This manual describes the REFLA-1D/MODE3 reflood system analysis code. This code can solve the core thermo-hydrodynamics under forced flooding conditions and gravity feed conditions in a system similar to FLECHT-SET Phase A. This manual describes the REFLA-1D/MODE3 models and provides application information required to utilize the code. (author)

Examination of the Thermo-mechanical Properties of E-Glass/Carbon Composites

Directory of Open Access Journals (Sweden)

Hande Sezgin

2017-12-01

Full Text Available Eight-ply E-glass, carbon and E-glass/carbon fabric-reinforced polyester based hybrid composites were manufactured in this study. A vacuum infusion system was used as the production method. Dynamic mechanical analysis, thermogravimetric analysis and differential scanning calorimetry analysis were conducted to examine the thermo-mechanical properties of composite samples. The effect of reinforcement type and different stacking sequences of fabric plies on the thermo-mechanical properties of composite samples were also investigated. Results showed that the type and alignment of reinforcement material has a signifi cant effect on the dynamic mechanical properties of composite samples.

Application of InSAR and gravimetric surveys for developing construction codes in zones of land subsidence induced by groundwater extraction: case study of Aguascalientes, Mexico

Directory of Open Access Journals (Sweden)

J. Pacheco-Martínez

2015-11-01

Full Text Available Interferometric Synthetic Aperture Radar (InSAR has become a valuable tool for surface deformation monitoring, including land subsidence associated with groundwater extraction. Another useful tools for studying Earth's surface processes are geophysical methods such as Gravimetry. In this work we present the application of InSAR analysis and gravimetric surveying to generate valuable information for risk management related to land subsidence and surface faulting. Subsidence of the city of Aguascalientes, Mexico is presented as study case. Aguascalientes local governments have addressed land subsidence issues by including new requirements for new constructions projects in the State Urban Construction Code. Nevertheless, the resulting zoning proposed in the code is still subjective and not clearly defined. Our work based on gravimetric and InSAR surveys is aimed for improving the subsidence hazard zoning proposed in the State Urban Code in a more comprehensive way. The study includes a 2007–2011 ALOS InSAR time-series analysis of the Aguascalientes valley, an interpretation of the compete Bouguer gravimetric anomaly of the Aguascalientes urban area, and the application of time series and gravimetric anomaly maps for improve the subsidence hazard zoning of Aguascalientes City.

Self-standing paper based anodes prepared from siliconcarbonitride-MoS2 composite for Li-ion battery applications

Science.gov (United States)

David, Lamuel; Singh, Gurpreet

2013-03-01

We study synthesis of free-standing polymer derived SiCN/ MoS2 composite paper anode for Li-ion battery application. This was achieved following a two-step approach: First, polysilazane was interfaced with exfoliated MoS2 nanosheets which upon pyrolysis resulted in SiCN/MoS2 composite. Second, dispersion of SiCN/MoS2 in isopropanol was vacuum filtered resulting in formation of a self-standing composite paper. Physical and chemical characterization of the composite was carried out by use of electron microscopy, Fourier transform infrared spectroscopy (FT-IR) and Thermo-gravimetric analysis (TGA). FT-IR data indicated complete conversion of polysilazane precursor to SiCN ceramic, while electron microscopy confirmed layered structure of the paper. Thermo-gravimetric analysis showed enhanced thermodynamic stability of the composite paper up to 800 °C. Electrochemical analysis of SiCN/MoS2 composite paper anodes showed that Li-ion can reversible intercalate in the voltage range of 0-2.5 V with a first cycle discharge capacity of 770 mAh/g at a current density of 100 mA/g.

Reduction Of Gravimetric Data Using An Integrated Computer ...

African Journals Online (AJOL)

The rigour of gravimetric data collection, and the non-availability of comprehensive data reduction software that takes care of local peculiarities, have always constituted hindrance to the application of the gravity method of geophysical studies. However, in recent time, the importance of the gravity method in mineral ...

Thermo-mechanical interaction effects in foam cored sandwich panels-correlation between High-order models and Finite element analysis results

DEFF Research Database (Denmark)

Palleti, Hara Naga Krishna Teja; Santiuste, Carlos; Thomsen, Ole Thybo

2010-01-01

Thermo-mechanical interaction effects including thermal material degradation in polymer foam cored sandwich structures is investigated using the commercial Finite Element Analysis (FEA) package ABAQUS/Standard. Sandwich panels with different boundary conditions in the form of simply supported...

Technical note: Comparison of metal-on-metal hip simulator wear measured by gravimetric, CMM and optical profiling methods

Science.gov (United States)

Alberts, L. Russell; Martinez-Nogues, Vanesa; Baker Cook, Richard; Maul, Christian; Bills, Paul; Racasan, R.; Stolz, Martin; Wood, Robert J. K.

2018-03-01

Simulation of wear in artificial joint implants is critical for evaluating implant designs and materials. Traditional protocols employ the gravimetric method to determine the loss of material by measuring the weight of the implant components before and after various test intervals and after the completed test. However, the gravimetric method cannot identify the location, area coverage or maximum depth of the wear and it has difficulties with proportionally small weight changes in relatively heavy implants. In this study, we compare the gravimetric method with two geometric surface methods; an optical light method (RedLux) and a coordinate measuring method (CMM). We tested ten Adept hips in a simulator for 2 million cycles (MC). Gravimetric and optical methods were performed at 0.33, 0.66, 1.00, 1.33 and 2 MC. CMM measurements were done before and after the test. A high correlation was found between the gravimetric and optical methods for both heads (R 2  =  0.997) and for cups (R 2  =  0.96). Both geometric methods (optical and CMM) measured more volume loss than the gravimetric method (for the heads, p  =  0.004 (optical) and p  =  0.08 (CMM); for the cups p  =  0.01 (optical) and p  =  0.003 (CMM)). Two cups recorded negative wear at 2 MC by the gravimetric method but none did by either the optical method or by CMM. The geometric methods were prone to confounding factors such as surface deformation and the gravimetric method could be confounded by protein absorption and backside wear. Both of the geometric methods were able to show the location, area covered and depth of the wear on the bearing surfaces, and track their changes during the test run; providing significant advantages to solely using the gravimetric method.

Characterization of the structure of the Salar de Atacama Basin through gravimetric profiles and interval velocity analysis.

Science.gov (United States)

Becerra, J.; Bascunan, S. A.; Maksymowicz, A.; Martínez, F.; Arriagada, C.

2017-12-01

The structure of the basins found in the Preandean Depression in the northern Central Andes has remained elusive, partly due to a poor understanding of the structural styles and stratigraphy beneath their surface. An independent approach to the multiple interpretations of seismic lines available is the analysis of 2D gravity profiles. An E-W profile was performed across the basin, closely matching the surficial trace of previous seismic lines. The profile shows three gravimetric lows, the most relevant being one beneath the Llano de la Paciencia- Cordillera de la Sal, comprised of deformed evaporitic and terrigenous deposits of Oligocene-Early Miocene age. The structure which bounds this gravity low has a steeper dip on its eastern side, bounding the eastern side of the Cordillera de la Sal, which is at odds with previous studies that interpreted its western contact with Cretaceous outcrops as the possible basin boundary. The 3-D analyses of seismic interval velocity data around the gravimetric survey reveal a major vertical contrast in the eastern portion of the profile, interpreted as the bottom of the evaporite successions, followed to the west by a complex, narrow and deep zone of low velocities. Westward, the Cretaceous rocks record higher velocities than its post-Paleocene counterparts, and an almost uniform increase in velocity with depth. The major gravity anomaly is closely related to the Cordillera de la Sal, which consists of an array of folds and reverse faults involving Oligocene to recent deposits. We propose that the faults which generated Oligocene extension are not at the western border of the basin, but around the Cordillera de la Sal, which is the result of Miocene inversion of the same system. Strike-slip deformation was also probably a major contributor in basin formation, as shown by the narrow yet deep shape of the depocenter.

Crumpled Nitrogen-Doped Graphene for Supercapacitors with High Gravimetric and Volumetric Performances.

Science.gov (United States)

Wang, Jie; Ding, Bing; Xu, Yunling; Shen, Laifa; Dou, Hui; Zhang, Xiaogang

2015-10-14

Graphene is considered a promising electrochemical capacitors electrode material due to its high surface area and high electrical conductivity. However, restacking interactions between graphene nanosheets significantly decrease the ion-accessible surface area and impede electronic and ionic transfer. This would, in turn, severely hinder the realization of high energy density. Herein, we report a strategy for preparation of few-layer graphene material with abundant crumples and high-level nitrogen doping. The two-dimensional graphene nanosheets (CNG) feature high ion-available surface area, excellent electronic and ion transfer properties, and high packing density, permitting the CNG electrode to exhibit excellent electrochemical performance. In ionic liquid electrolyte, the CNG electrode exhibits gravimetric and volumetric capacitances of 128 F g(-1) and 98 F cm(-3), respectively, achieving gravimetric and volumetric energy densities of 56 Wh kg(-1) and 43 Wh L(-1). The preparation strategy described here provides a new approach for developing a graphene-based supercapacitor with high gravimetric and volumetric energy densities.

Derivative thermo analysis of the Al-Si cast alloy with addition of rare earths metals

Directory of Open Access Journals (Sweden)

M. Krupiński

2010-01-01

Full Text Available In this paper the dependence between chemical composition, structure and cooling rate of Al–Si aluminium cast alloy was investigated. For studying of the structure changes the thermo-analysis was carried out, using the UMSA (Universal Metallurgical Simulator and Analyzer device. For structure investigation optical and electron scanning microscopy was used, phase and chemical composition of the Al cast alloy also using qualitative point-wise EDS microanalysis.

Measurement of isotope abundance variations in nature by gravimetric spiking isotope dilution analysis (GS-IDA).

Science.gov (United States)

Chew, Gina; Walczyk, Thomas

2013-04-02

Subtle variations in the isotopic composition of elements carry unique information about physical and chemical processes in nature and are now exploited widely in diverse areas of research. Reliable measurement of natural isotope abundance variations is among the biggest challenges in inorganic mass spectrometry as they are highly sensitive to methodological bias. For decades, double spiking of the sample with a mix of two stable isotopes has been considered the reference technique for measuring such variations both by multicollector-inductively coupled plasma mass spectrometry (MC-ICPMS) and multicollector-thermal ionization mass spectrometry (MC-TIMS). However, this technique can only be applied to elements having at least four stable isotopes. Here we present a novel approach that requires measurement of three isotope signals only and which is more robust than the conventional double spiking technique. This became possible by gravimetric mixing of the sample with an isotopic spike in different proportions and by applying principles of isotope dilution for data analysis (GS-IDA). The potential and principle use of the technique is demonstrated for Mg in human urine using MC-TIMS for isotopic analysis. Mg is an element inaccessible to double spiking methods as it consists of three stable isotopes only and shows great potential for metabolically induced isotope effects waiting to be explored.

Analysis of glass fibre sizing

DEFF Research Database (Denmark)

Petersen, Helga Nørgaard; Kusano, Yukihiro; Brøndsted, Povl

2014-01-01

Glass fibre reinforced polymer composites are widely used for industrial and engineering applications which include construction, aerospace, automotive and wind energy industry. During the manufacturing glass fibres, they are surface-treated with an aqueous solution. This process and the treated...... surfaces are called sizing. The sizing influences the properties of the interface between fibres and a matrix, and subsequently affects mechanical properties of composites. In this work the sizing of commercially available glass fibres was analysed so as to study the composition and chemical structures....... Soxhlet extraction was used to extract components of the sizing from the glass fibres. The glass fibres, their extracts and coated glass plates were analysed by Thermo-Gravimetric Analysis combined with a mass spectrometer (TGA-MS), and Attenuated Total Reflectance Fourier Transform Infrared (ATR...

Thermo-mechanical stress analysis of cryopreservation in cryobags and the potential benefit of nanowarming.

Science.gov (United States)

Solanki, Prem K; Bischof, John C; Rabin, Yoed

2017-06-01

Cryopreservation by vitrification is the only promising solution for long-term organ preservation which can save tens of thousands of lives across the world every year. One of the challenges in cryopreservation of large-size tissues and organs is to prevent fracture formation due to the tendency of the material to contract with temperature. The current study focuses on a pillow-like shape of a cryobag, while exploring various strategies to reduce thermo-mechanical stress during the rewarming phase of the cryopreservation protocol, where maximum stresses are typically found. It is demonstrated in this study that while the level of stress may generally increase with the increasing amount of CPA filled in the cryobag, the ratio between width and length of the cryobag play a significant role. Counterintuitively, the overall maximum stress is not found when the bag is filled to its maximum capacity (when the filled cryobag resembles a sphere). Parametric investigation suggests that reducing the initial rewarming rate between the storage temperature and the glass transition temperature may dramatically decrease the thermo-mechanical stress. Adding a temperature hold during rewarming at the glass transition temperature may reduce the thermo-mechanical stress in some cases, but may have an adverse effect in other cases. Finally, it is demonstrated that careful incorporation of volumetric heating by means on nanoparticles in an alternating magnetic field, or nanowarming, can dramatically reduce the resulting thermo-mechanical stress. These observations display the potential benefit of a thermo-mechanical design of the cryopreservation protocols in order to prevent structural damage. Copyright © 2017 Elsevier Inc. All rights reserved.

Thermo-sensitive intelligent track membrane

International Nuclear Information System (INIS)

Pang Deling; Ren Lihua; Qian Zhilin; Huang Gang; Zhang Jinhua

1999-01-01

Using N-isopropylacryl-amide (NIP AAm) thermo-sensitive function material as monomer and nuclear track microporous membrane (NTMM) as baseline material, a thermo-sensitive intelligent track membrane (TsITM) has been prepared by the over-oxidization and pre-irradiation grafting techniques. The TsITM can be used to make a micro-switch controlled by temperature and to adjust particle screening and osmosis. To obtain sub-micron responsive grafted track pores only a very thin thermo-sensitive layer is needed. The TsITM pores are capable of swelling and shrinking rapidly and respond more sensitively to temperature

Simplified method for gravimetric determination of zirconium or hafnium with α-hydroxy carboxylic acids

International Nuclear Information System (INIS)

Barbieri, R.S.; Rocha, J.C.; Terra, V.R.; Marques Netto, A.

1989-01-01

The conditions for gravimetric determination of zirconium or hafnium by glicoloc acids derivatives were studied by thermogravimetric analysis. The method utilized shownd that after precipitation, washing and drying of precipitates at 150 o C, the resulting solid was weighed in the form of [M (RCH(OH)COO) 4 ] (M = Zr, Hf; R + C 6 H 5 , β-C 10 H 7 , p-BrC 6 H 4 ). (author)

Gravimetric and profilometric measurements of the ablation rates of photosensitive polymers at different wavelengths

International Nuclear Information System (INIS)

Dumont, Th.; Bischofberger, R.; Lippert, T.; Wokaun, A.

2005-01-01

The ablation rates of two polyimides (PMDA and DurimidTM) and one triazene polymer were studied by gravimetric (quartz microbalance) and profilometric (profilometer) methods at irradiation wavelengths of 193, 248 and 308 nm. The ablation rates determined by the two methods are discussed in the context of the absorption behavior of the materials. Furthermore, the consistence of the two experimental methods is discussed for the ablation rates of DurimidTM and the triazene polymer. The gravimetric measurements revealed a good correlation between the ablation rate and the absorption properties of the examined materials. The comparison of the gravimetric and the profilometric measurements suggest a significant mass removal, e.g. by formation of gaseous products, prior to the detection of changes in the surface morphology

A study on improvement of measurement capability for gravimetric flowmeter calibrator

International Nuclear Information System (INIS)

Lee, Dong Keun; Park, Jong Ho

2009-01-01

The calibration of flowmeter is a very important procedure to set up traceability from the national or international standards. The uncertainty of flow measurement defines reliability for measurement results. The uncertainty of gravimetric method combines uncertainties of each independent variable, including mass, time, water density, air density and the density of dead weight. In this study, it has been found that the uncertainties of mass and time measurement in the gravimetric method have dominant influence on the total measurement uncertainty. After improvements of a constant head tank and a diverter, the best measurement capability for K-water's calibration facility has been reached less than 0.1%.

Thermo-elastic optical coherence tomography

NARCIS (Netherlands)

Wang, Tianshi; Pfeiffer, Tom; Wu, Min; Wieser, Wolfgang; Amenta, Gaetano; Draxinger, Wolfgang; van der Steen, A.F.W.; Huber, Robert; Van Soest, Gijs

2017-01-01

The absorption of nanosecond laser pulses induces rapid thermo-elastic deformation in tissue. A sub-micrometer scale displacement occurs within a few microseconds after the pulse arrival. In this Letter, we investigate the laser-induced thermo-elastic deformation using a 1.5 MHz phase-sensitive

Thermo-mechanical analysis of high level nuclear wastes in granite

International Nuclear Information System (INIS)

Millard, A.; Guri, G.; Raimbault, M.

1991-01-01

In order to appraise the safety of a storage of high level nuclear wastes in rock masses, it is necessary to assess, among other features, the thermo-mechanical behaviour of the host rock for long periods (thousands of years). In France, four different media are considered as potential host rocks: granite, shale, salt, clay. The present paper is devoted to some analysis of a generic storage configuration in granite. The case of a rock mass without any major fault has been considered. The granite is modelled by means of an elastic fracturing model (no tension type). The results obtained show that some fissures, induced by the heat generation, develop mainly above the repository. The opening of the fissures, within the frame of the adopted hypothesis, have not a strong influence on the rock mass, as a geological barrier for the radionuclides. (author)

Analysis of Thermo-Elastic Fracture Problem during Aluminium Alloy MIG Welding Using the Extended Finite Element Method

Directory of Open Access Journals (Sweden)

Kuanfang He

2017-01-01

Full Text Available The thermo-elastic fracture problem and equations are established for aluminium alloy Metal Inert Gas (MIG welding, which include a moving heat source and a thermoelasticity equation with the initial and boundary conditions for a plate structure with a crack. The extended finite element method (XFEM is implemented to solve the thermo-elastic fracture problem of a plate structure with a crack under the effect of a moving heat source. The combination of the experimental measurement and simulation of the welding temperature field is done to verify the model and solution method. The numerical cases of the thermomechanical parameters and stress intensity factors (SIFs of the plate structure in the welding heating and cooling processes are investigated. The research results provide reference data and an approach for the analysis of the thermomechanical characteristics of the welding process.

Transcatheter hepatic arterial thermo-chemotherapy and thermo-lipiodol embolization for the treatment of hepatic metastases from colorectal carcinoma

International Nuclear Information System (INIS)

Wang Xuan; Chen Xiaofei

2009-01-01

Objective: To evaluate the clinical efficacy of transcatheter hepatic arterial thermo-chemotherapy and thermo-lipiodol embolization in the treatment of hepatic metastases from colorectal carcinoma. Methods: Sixty-eight cases with hepatic metastases from colorectal carcinoma were equally and randomly divided into two groups. The patients in study group were treated with transcatheter hepatic arterial thermo-chemotherapy and thermo-lipiodol embolization, while the patients in control group were treated with conventional (normal temperature) transcatheter hepatic arterial chemotherapy lipiodol embolization. Results: The effective rate of study group and control group was 65%(22/34) and 32%(11/34) respectively, the difference between two groups was statistically significant (P<0.05). No significant difference in the postoperative changes of hepatic function tests was found between the two groups. The survival rate at 6,12,18 and 24 months after the treatment was 100%, 82%, 44% and 18% respectively in study group, while it was 91%, 47%, 15% and 6% respectively in control group. Conclusion: Transcatheter hepatic arterial thermo-chemotherapy and thermo-lipiodol embolization is an effective and safe treatment for the hepatic metastases from colorectal carcinoma and has no obvious damage to the hepatic function. (authors)

Determination of the structure, morphology and complex refractive index in ZnO-nanopencils/P3HT hybrid structures

CSIR Research Space (South Africa)

Motaung, DE

2012-08-01

Full Text Available of the base of the flower-shapes. ZnO-NPs were incorporated into the nanomorphology of P3HT and two variations of P3HT:C60 and P3HT: PCBM blended films in order to facilitate charge separation and transport. Thermo-gravimetric analysis revealed that Zn...

Thermo-economic analysis of an integrated solar power generation system using nanofluids

International Nuclear Information System (INIS)

Alashkar, Adnan; Gadalla, Mohamed

2017-01-01

Highlights: • Develop a thermo-economic analysis of an integrated solar-power generation system. • A thermodynamic optimization is proposed to maximize system performance. • Select the optimum nanofluid to replace conventional heating fluids inside a PTSC. • Study the effect of thermal energy storage on performance and cost of the system. • Perform monthly and daily analyses to analyze system behavior using nanofluids. - Abstract: In this paper, a thermo-economic analysis of an Integrated Solar Regenerative Rankine Cycle (ISRRC) is performed. The ISRRC consists of a nanofluid-based Parabolic Trough Solar Collector (PTSC), and a Thermal Energy Storage System (TES) integrated with a Regenerative Rankine Cycle. The effect of dispersing metallic and non-metallic nanoparticles into conventional heating fluids on the output performance and cost of the ISRRC is studied for different volume fractions and for three modes of operation. The first mode assumes no storage, while the second and the third assume a storage system with a storage period of 7.5 h and 10 h respectively. For the modes of operation with the TES, the charging and discharging cycles are explained. The results show that the presence of the nanoparticles leads to an increase in the overall energy produced by the ISRRC for all modes of operation, causing a decrease in the Levelized Cost of Electricity (LEC), and an increase in the net savings of the ISRRC. After comparing the three modes of operation, it is established that the existence of a storage system leads to a higher power generation, and a lower LEC; however, the efficiency of the cycle drops. It is seen that the maximum increase in the annual energy output of the ISRRC caused by the addition of Cu nanoparticles to Syltherm 800 is approximately 3.1%, while the maximum increase in the net savings is about 2.4%.

Comparison of gravimetric and spectrophotometric methods for the determination of O/U ratios in uranium oxides

International Nuclear Information System (INIS)

Esteban, Adolfo; Eppis, Maria Rosa

2004-01-01

One important parameter to specify in nuclear fuels is the oxygen-metal ratio; many tests were described in literature to determine it. Possibly, gravimetric methods are the most used and usually a good precision was obtained analysing sintered materials. However, the humidity sorbed in the samples and impurities affect these methods, especially in powders. On the other hand, the spectrophotometric methods determine oxygen-uranium ratio by measuring the absorbances of different ionic species in phosphoric acid. This technique is simply and is not affected by humidity and impurities. Owing to discrepancy in the results between both methods, it was carried out in our laboratory, a study on various gravimetric and spectrophotometric methods. Several assays and analysis were performed comparing test procedures, trying to obtain better precision and accuracy. This work presents the results obtained and the recommend procedure to use with sintered and unsintered materials

Thermo-responsive methylcellulose hydrogels as temporary substrate for cell sheet biofabrication.

Science.gov (United States)

Altomare, Lina; Cochis, Andrea; Carletta, Andrea; Rimondini, Lia; Farè, Silvia

2016-05-01

Methylcellulose (MC), a water-soluble polymer derived from cellulose, was investigated as a possible temporary substrate having thermo-responsive properties favorable for cell culturing. MC-based hydrogels were prepared by a dispersion technique, mixing MC powder (2, 4, 6, 8, 10, 12 % w/v) with selected salts (sodium sulphate, Na2SO4), sodium phosphate, calcium chloride, or phosphate buffered saline, to evaluate the influence of different compositions on the thermo-responsive behavior. The inversion test was used to determine the gelation temperatures of the different hydrogel compositions; thermo-mechanical properties and thermo-reversibility of the MC hydrogels were investigated by rheological analysis. Gelation temperatures and rheological behavior depended on the MC concentration and type and concentration of salt used in hydrogel preparation. In vitro cytotoxicity tests, performed using L929 mouse fibroblasts, showed no toxic release from all the tested hydrogels. Among the investigated compositions, the hydrogel composed of 8 % w/v MC with 0.05 M Na2SO4 had a thermo-reversibility temperature at 37 °C. For that reason, this formulation was thus considered to verify the possibility of inducing in vitro spontaneous detachment of cells previously seeded on the hydrogel surface. A continuous cell layer (cell sheet) was allowed to grow and then detached from the hydrogel surface without the use of enzymes, thanks to the thermo-responsive behavior of the MC hydrogel. Immunofluorescence observation confirmed that the detached cell sheet was composed of closely interacting cells.

Gravimetric determination of hafnium through its arsenate in carbide and boride of hafnium

International Nuclear Information System (INIS)

Rasulbekova, R.A.; Mamedov, I.A.

1976-01-01

A gravimetric method of determining hafnium through hydroarsenate has been recommended. The method differs from the known ones by its simplicity and by the recalculation coefficient which is more than by 50% smaller than that used in preparing a weight form of HfO 2 . Upon development of gravimetric determination of hafnium through hydro-and pyroarsenate, an investigation has been conducted with the aim to find some physico-chemical constants of hafnium hydroarsenate. The weighed amount of hafnium hydroarsenate is dissolved in sulphuric acid (2:5). The precipitate of hafnium hydroarsenate has been studied for recording infrared absorption spectra. Thermographic analysis of the precipitate has been performed. Thermogram reveals endothermal effect at 105 deg C and exothermal at 840 deg C. Water solubility of hafnium has been determined equal to 1.75x10 6 g mol/l. The corresponding solubility product of the precipitate has been calculated which is 2.1x10 -17 . It is shown that the method possesses certain selectivity, sufficient accuracy, and is rather fast. It has been established that determination can be performed in the presence of excess amounts of ions

Electric Boiler and Heat Pump Thermo-Electrical Models for Demand Side Management Analysis in Low Voltage Grids

DEFF Research Database (Denmark)

Diaz de Cerio Mendaza, Iker; Bak-Jensen, Birgitte; Chen, Zhe

2013-01-01

The last fifteen years many European countries have integrated large percentage of renewable energy on their electricity generation mix. In Denmark the 21.3% of the electricity consumed nowadays is produced by the wind, and it has planned to be the 50% by 2025. In order to front future challenges...... on the power system control and operation, created by this unstable way of generation, Demand Side Management turns to be a promising solution. The storage capacity from thermo-electric units, like electric boilers and heat pumps, allows operating them with certain freedom. Hence they can be employed under...... certain coordination, to actively respond to the power system fluctuations. The following paper presents two simple thermo-electrical models of an electrical boiler and an air-source CO2 heat pump system. The purpose is using them in low voltage grids analysis to assess their capacity and flexibility...

Biomass thermo-conversion. Research trends

International Nuclear Information System (INIS)

Rodriguez Machin, Lizet; Perez Bermudez, Raul; Quintana Perez, Candido Enrique; Ocanna Guevara, Victor Samuel; Duffus Scott, Alejandro

2011-01-01

In this paper is studied the state of the art in order to identify the main trends of the processes of thermo conversion of biomass into fuels and other chemicals. In Cuba, from total supply of biomass, wood is the 19% and sugar cane bagasse and straw the 80%, is why research in the country, should be directed primarily toward these. The methods for energy production from biomass can be group into two classes: thermo-chemical and biological conversion routes. The technology of thermo-chemical conversion includes three subclasses: pyrolysis, gasification, and direct liquefaction. Although pyrolysis is still under development, in the current energy scenario, has received special attention, because can convert directly biomass into solid, liquid and gaseous by thermal decomposition in absence of oxygen. The gasification of biomass is a thermal treatment, where great quantities of gaseous products and small quantities of char and ash are produced. In Cuba, studies of biomass thermo-conversion studies are limited to slow pyrolysis and gasification; but gas fuels, by biomass, are mainly obtained by digestion (biogas). (author)

Insights into the Mechanism and Kinetics of Thermo-Oxidative Degradation of HFPE High Performance Polymer.

Science.gov (United States)

Kunnikuruvan, Sooraj; Parandekar, Priya V; Prakash, Om; Tsotsis, Thomas K; Nair, Nisanth N

2016-06-02

The growing requisite for materials having high thermo-oxidative stability makes the design and development of high performance materials an active area of research. Fluorination of the polymer backbone is a widely applied strategy to improve various properties of the polymer, most importantly the thermo-oxidative stability. Many of these fluorinated polymers are known to have thermo-oxidative stability up to 700 K. However, for space and aerospace applications, it is important to improve its thermo-oxidative stability beyond 700 K. Molecular-level details of the thermo-oxidative degradation of such polymers can provide vital information to improve the polymer. In this spirit, we have applied quantum mechanical and microkinetic analysis to scrutinize the mechanism and kinetics of the thermo-oxidative degradation of a fluorinated polymer with phenylethenyl end-cap, HFPE. This study gives an insight into the thermo-oxidative degradation of HFPE and explains most of the experimental observations on the thermo-oxidative degradation of this polymer. Thermolysis of C-CF3 bond in the dianhydride component (6FDA) of HFPE is found to be the rate-determining step of the degradation. Reaction pathways that are responsible for the experimentally observed weight loss of the polymer is also scrutinized. On the basis of these results, we propose a modification of HFPE polymer to improve its thermo-oxidative stability.

Influence of thermo-derivative analysis conditions on microstructure of the Al-Si-Cu alloy

Directory of Open Access Journals (Sweden)

L.A. Dobrzański

2011-04-01

Full Text Available Microstructure change of the metals and alloys as a result of variable crystallisation conditions also by mind of cooling rate changeinfluence the mechanical properties. In this work there are presented the interdependences between the cooling rate, chemical compositionand microstructure of the cast aluminium alloy Al–Si–Cu as a result of the thermo-derivative analysis, using the UMSA (UniversalMetallurgical Simulator and Analyzer device. An important tool for the microstructure evaluation of the Al type AC-AlSi7Cu3Mg alloywas the light and electron scanning microscopy technique.

Preparation of novel magnetic polyurethane foam nanocomposites by using core-shell nanoparticles

OpenAIRE

Nikje,Mir Mohammad Alavi; Moghaddam,Sahebeh Tamaddoni; Noruzian,Maede

2016-01-01

Abstract Iron oxide magnetic nanoparticles (NP's) converted to the core- shell structres by reacting with by n-(2-aminoethyl)-3-aminopropyl trimethoxysilane (AEAP) incorporated in polyurethane flexible (PUF) foam formulations. Fourier transform spectra, thermal gravimetric analysis, scanning electron images, thermo-mechanical analysis and magnetic properties of the prepared nanocomposites were studied. Obtained data shown that by the increasing of the amine modified magnetic iron oxide NP's u...

Gravimetric analysis and differential scanning calorimetric studies on glycerin-induced skin hydration.

Science.gov (United States)

Lee, Ae-Ri Cho; Moon, Hee Kyung

2007-11-01

A thermal gravimetric analysis (TGA) and a differential scanning calorimetry (DSC) were carried out to characterize the water property and an alteration of lipid phase transition of stratum corneum (SC) by glycerin. In addition, the relationship between steady state skin permeation rate and skin hydration in various concentrations of glycerin was investigated. Water vapor absorption-desorption was studied in the hairless mouse stratum corneum. Dry SC samples were exposed to different conc. of glycerin (0-50%) followed by exposure to dry air and the change in weight property was monitored over time by use of TGA. In DSC study, significant decrease in DeltaH of the lipid transition in 10% glycerin and water treated sample: the heat of lipid transition of normal, water, 10% glycerin treated SC were 6.058, 4.412 and 4.316 mJ/mg, respectively. In 10% glycerin treated SCs, the Tc of water shifts around 129 degrees C, corresponding to the weakly bound secondary water. In 40% glycerin treated SC, the Tc of water shifts to 144 degrees C corresponding to strongly bound primary water. There was a good correlation between the hydration property of the skin and the steady state skin flux with the correlation coefficient (r2=0.94). As the hydration increased, the steady state flux increased. As glycerin concentration increased, hydration property decreased. High diffusivity induced by the hydration effect of glycerin and water could be the major contributing factor for the enhanced skin permeation of nicotinic acid (NA).

Thermo-power in Brazil: diagnosis of control and monitoring of gas emissions

International Nuclear Information System (INIS)

Xavier, E.E.; Magrini, Alessandra; Rosa, L.P.; Santos, M.A. dos

2004-01-01

In parallel to Brazil's recent supply crisis, the privatization process of its power sector has drastically reshaped the nation's energy matrix. From a profile based mainly on hydro-power generation, this sector is being reshaped through a thermo-power plant construction program whose environmental repercussions will certainly be felt over the next few years. This paper offers a description of the thermo-power segment currently in operation, under construction and on the drawing board in Brazil, followed by the results of a diagnosis of the control and monitoring of the gas emissions by this segment. The methodology used for the exploratory analysis and to prepare the diagnosis consists of surveys through questionnaires completed by companies owning the thermo-power plants. After consolidating, processing and analyzing the findings reached through the replies sent in by the companies, it is concluded that thermo-power plants currently in operation lack control systems that would help reduce atmospheric pollution, and are not equipped with monitoring systems for these emissions. The thermo-power plants currently under construction and on the drawing board indicate a trend towards including these systems in their project designs, due to more stringent licensing processes

Spectrophotometric, potentiometric, and gravimetric determination of lanthanides with peri-dihydroxynaphthindenone

International Nuclear Information System (INIS)

Hassan, S.S.M.; Mahmoud, W.H.

1982-01-01

Sensitive and reasonably selective methods are described for the spectrophotometric, potentiometric, and gravimetric determination of lanthanides using peri-dihydroxynaphthindenone as a novel chromogenic and precipitating reagent. The reagent forms a stable 1:2 (metal:reagent) type of complex with light lanthanides at pH 2-7 in 1:1 ethanol-water mixture. Low metal concentrations ( 4 L mol -1 cm -1 ) which obey Beer's law. Quantitative precipitation of the complexes from metal solutions of concentrations > 100 μg/mL permits both gravimetric quantitation by igniting the precipitates to the metal oxides and potentiometric titration of the excess reagent. Results with an average recovery of 98% (standard deviation 0.7%) are obtainable for 0.1 μg to 200 mg of all light lanthanides. Many foreign ions naturally occurring or frequently associated with lanthanides do not interfere or can be tolerated

Thermo-hydrodynamic lubrication in hydrodynamic bearings

CERN Document Server

Bonneau, Dominique; Souchet, Dominique

2014-01-01

This Series provides the necessary elements to the development and validation of numerical prediction models for hydrodynamic bearings. This book describes the thermo-hydrodynamic and the thermo-elasto-hydrodynamic lubrication. The algorithms are methodically detailed and each section is thoroughly illustrated.

Accuracy criteria recommended for the certification of gravimetric coal-mine-dust samplers

International Nuclear Information System (INIS)

Bowman, J.D.; Bartley, D.L.; Breuer, G.M.; Doemeny, L.J.; Murdock, D.J.

1984-07-01

Procedures for testing bias and precision of gravimetric coal-mine-dust sampling units are reviewed. Performance criteria for NIOSH certification of personal coal-mine dust samplers are considered. The NIOSH criterion is an accuracy of 25% at the 95% confidence interval. Size distributions of coal-mine-dust are discussed. Methods for determining size distributions are described. Sampling and sizing methods are considered. Cyclone parameter estimation is discussed. Bias computations for general sampling units are noted. Recommended procedures for evaluating bias and precision of gravimetric coal mine dust personal samplers are given. The authors conclude that when cyclones are operated at lower rates, the NIOSH accuracy criteria can be met

The influence of thermo-chemotherapy on bladder tumours: an immunohistochemical analysis.

NARCIS (Netherlands)

Heijden, A.G. van der; Hulsbergen-van de Kaa, C.A.; Witjes, J.A.

2007-01-01

To study the influence of microwave induced thermo-chemotherapy on high-grade urothelial cell carcinomas. Five groups of each three patients were formed of whom initial biopsies and cystectomy samples were collected. Patients were treated 2 days prior to cystectomy with mitomycin-C (group 1),

Thermo-stimulated current and dielectric loss in composite materials

International Nuclear Information System (INIS)

Nishijima, S.; Hagihara, T.; Okada, T.

1986-01-01

Thermo-stimulated current and dielectric loss measurements have been performed on five kinds of commercially available composite materials in order to study the electric properties of composite materials at low temperatures. Thermo-stimulated current measurements have been made on the composite materials in which the matrix quality was changed intentionally. The changes in the matrices were introduced by gamma irradiation or different curing conditions. Thermo-stimulated current and dielectric loss measurements revealed the number and the molecular weight of dipolar molecules. The different features of thermo-stimulated current and dielectric losses were determined for different composite materials. The gamma irradiation and the curing conditions especially affect the thermo-stimulated current features. The changes in macroscopic mechanical properties reflect those of thermo-stimulated current. It was found that the change in quality and/or degradation of the composite materials could be detected by means of thermo-stimulated current and/or dielectric loss measurements

Gravimetric dust sampling for control purposes and occupational dust sampling.

CSIR Research Space (South Africa)

Unsted, AD

1997-02-01

Full Text Available Prior to the introduction of gravimetric dust sampling, konimeters had been used for dust sampling, which was largely for control purposes. Whether or not absolute results were achievable was not an issue since relative results were used to evaluate...

A thermal analysis study on proprietary quick-setting mixed binder system

International Nuclear Information System (INIS)

Deneanu, N.; Dulama, M.; Diaconescu, C.

2013-01-01

The present paper presents a study, by thermal analysis, of the hydration of a mixed binder system consist of Portland composite cement type CEM II/A-M(S-LL) 32,5 R and calcium aluminate cement type GORKAL 70, patented by the authors for embedding spent radioactive solvents. Cement hydration reactions are often affected by the presence of a spent radioactive solvent, usually retarded. This process can be monitored by thermal analysis and often quantified. The data are being used as a reference to compare the changes in the cement blend hydration during the solidification caused by the presence of the spent radioactive solvents itself or by emulsifier additives which are being availed. Detailed analysis of DTG (derivative thermo gravimetric) decomposition profiles of portlandite and carbonate enabled the evaluation of admixture-related parameters concerning portlandite formation and also indicated the behaviour of specific carbonates during the hydration process. (authors)

Method for the Collection, Gravimetric and Chemical Analysis of Nonvolatile Residue (NVR) on Surfaces

Science.gov (United States)

Gordon, Keith; Rutherford, Gugu; Aranda, Denisse

2017-01-01

Nonvolatile residue (NVR), sometimes referred to as molecular contamination is the term used for the total composition of the inorganic and high boiling point organic components in particulates and molecular films deposited on critical surfaces surrounding space structures, with the particulate and NVR contamination originating primarily from pre-launch operations. The "nonvolatile" suggestion from the terminology NVR implies that the collected residue will not experience much loss under ambient conditions. NVR has been shown to have a dramatic impact on the ability to perform optical measurements from platforms based in space. Such contaminants can be detected early by the controlled application of various detection techniques and contamination analyses. Contamination analyses are the techniques used to determine if materials, components, and subsystems can be expected to meet the performance requirements of a system. Of particular concern is the quantity of NVR contaminants that might be deposited on critical payload surfaces from these sources. Subsequent chemical analysis of the contaminant samples by infrared spectroscopy and gas chromatography mass spectrometry identifies the components, gives semi-quantitative estimates of contaminant thickness, indicates possible sources of the NVR, and provides guidance for effective cleanup procedures. In this report, a method for the collection and determination of the mass of NVR was generated by the authors at NASA Langley Research Center. This report describes the method developed and implemented for collecting NVR contaminants, and procedures for gravimetric and chemical analysis of the residue obtained. The result of this NVR analysis collaboration will help pave the way for Langley's ability to certify flight hardware outgassing requirements in support of flight projects such as Stratospheric Aerosol and Gas Experiment III (SAGE III), Clouds and the Earth's Radiant Energy System (CERES), Materials International

Comparison of gravimetric and gas chromatographic methods for assessing performance of textile materials against liquid pesticide penetration.

Science.gov (United States)

Shaw, Anugrah; Abbi, Ruchika

2004-01-01

Penetration of liquid pesticides through textile materials is a criterion for determining the performance of protective clothing used by pesticide handlers. The pipette method is frequently used to apply liquid pesticides onto textile materials to measure penetration. Typically, analytical techniques such as Gas Chromatography (GC) are used to measure percentage penetration. These techniques are labor intensive and costly. A simpler gravimetric method was developed, and tests were conducted to compare the gravimetric and GC methods of analysis. Three types of pesticide formulations and 4 fabrics were used for the study. Diluted pesticide formulations were pipetted onto the test specimens and percentage penetration was measured using the 2 methods. For homogeneous formulation, the results of the two methods were fairly comparable. However, due to the filtering action of the textile materials, there were differences in the percentage penetration between the 2 methods for formulations that were not homogeneous.

Thermo-electric pump

International Nuclear Information System (INIS)

Georges, J.-L.; Veyret, J.-F.

1973-01-01

Description is given of a thermo-pump for electrically conductive liquid fluids, e.g. for a liquid metal such as sodium. This pump is characterized in that the piping for the circulation of the conductive liquid is constituted by a plurality of conduits defined by two co-axial cylinders and two walls parallel to their axis. Each conduit limited outside by a magnet, inside by a mild-iron tube, and laterally by two materials forming a thermocouple. The electric current generated by that thermo-couple and the magnetic flux generated by the magnets both loop the loop through an outer cylindrical nickel shell. This can be applied to sodium circulation loops for testing nuclear fuel elements [fr

Near-field NanoThermoMechanical memory

International Nuclear Information System (INIS)

Elzouka, Mahmoud; Ndao, Sidy

2014-01-01

In this letter, we introduce the concept of NanoThermoMechanical Memory. Unlike electronic memory, a NanoThermoMechanical memory device uses heat instead of electricity to record, store, and recover data. Memory function is achieved through the coupling of near-field thermal radiation and thermal expansion resulting in negative differential thermal resistance and thermal latching. Here, we demonstrate theoretically via numerical modeling the concept of near-field thermal radiation enabled negative differential thermal resistance that achieves bistable states. Design and implementation of a practical silicon based NanoThermoMechanical memory device are proposed along with a study of its dynamic response under write/read cycles. With more than 50% of the world's energy losses being in the form of heat along with the ever increasing need to develop computer technologies which can operate in harsh environments (e.g., very high temperatures), NanoThermoMechanical memory and logic devices may hold the answer

Thermo-msf-parser: an open source Java library to parse and visualize Thermo Proteome Discoverer msf files.

Science.gov (United States)

Colaert, Niklaas; Barsnes, Harald; Vaudel, Marc; Helsens, Kenny; Timmerman, Evy; Sickmann, Albert; Gevaert, Kris; Martens, Lennart

2011-08-05

The Thermo Proteome Discoverer program integrates both peptide identification and quantification into a single workflow for peptide-centric proteomics. Furthermore, its close integration with Thermo mass spectrometers has made it increasingly popular in the field. Here, we present a Java library to parse the msf files that constitute the output of Proteome Discoverer. The parser is also implemented as a graphical user interface allowing convenient access to the information found in the msf files, and in Rover, a program to analyze and validate quantitative proteomics information. All code, binaries, and documentation is freely available at http://thermo-msf-parser.googlecode.com.

REFLA-1D/MODE 1: a computer program for reflood thermo-hydrodynamic analysis during PWR-LOCA user's manual

International Nuclear Information System (INIS)

Murao, Yoshio; Sugimoto, Jun; Okubo, Tsutomu

1981-01-01

This manual describes the REFLA-1D/MODE 1 reflood system analysis code. This code can solve the core thermo-hydrodynamics under forced flooding conditions and gravity feed conditions in a system similar to FLECHT-SET phase A. This manual describes the REFLA-1D/MODE 1 models and provides application information required to utilize REFLA-1D/MODE 1. (author)

Gravimetric determination of the iodine number of carbon black

International Nuclear Information System (INIS)

Murphy, L.J. Jr.

1991-01-01

This paper discusses a gravimetric method for the determination of the iodine adsorption number of carbon black. It comprises determining the concentration of an accurately weighed iodine blank solution by adding a standardized titrant to the iodine solution until a titration endpoint is reached and determining the concentration of the iodine solution by accurately weighing the amount of the standardized titrant necessary to reach the endpoint, accurately weighing an amount of carbon black and adding an appropriate amount of an accurately weighed portion of the iodine solution, equilibrating the carbon black-iodine solution mixture, adding the standardized titrant to an accurately weighed portion of the supernatant from the carbon black-iodine mixture until a titration endpoint is reached and determining the concentration of the supernatant by accurately weighing the amount of the standardized titrant necessary to reach the endpoint, wherein the titration endpoint of the supernatant is obtained using an indicating and a reference electrode, and calculating the iodine adsorption number of the carbon black based on the gravimetrically determined concentration of the titrant, the iodine solution, and the supernatant

Thermo-hydraulic analysis of the cool-down of the EDIPO test facility

Science.gov (United States)

Lewandowska, Monika; Bagnasco, Maurizio

2011-09-01

The first cool-down of the EDIPO (European DIPOle) test facility is foreseen to take place in 2011 by means of the existing 1.2 kW cryoplant at EPFL-CRPP Villigen. In this work, the thermo-hydraulic analysis of the EDIPO cool-down is performed in order both to assess the its duration and to optimize the procedure. The cool-down is driven by the helium flowing in both the outer cooling channel and in the windings connected hydraulically in parallel. We take into account limitations due to the pressure drop in the cooling circuit and the refrigerator capacity as well as heat conduction in the iron yoke. Two schemes of the hydraulic cooling circuit in the EDIPO windings are studied (coils connected in series and coils connected in parallel). The analysis is performed by means of an analytical model complemented by and numerical model. The results indicate that the cool-down to 5 K can be achieved in about 12 days.

Damage sensing ability of polymer nanocomposites filled with long, shortened and damaged carbon nanotubes

OpenAIRE

Inam, Fawad; Okolo, Chichi; Vo, Thuc

2016-01-01

Carbon nanotubes (CNTs) were aggressively tip-ultrasonicated to produce shortened and damaged carbon nanotubes. High-resolution scanning electron microscopic analysis was performed to measure the dimensions of CNTs. Thermo-gravimetric analysis (TGA) was used to evaluate the damage in the sonicated CNTs. Shortened CNTs, in their pristine form (undamaged), were used for comparison with damaged CNTs. Nanocomposite bars, containing CNTs, were indented using Vickers hardness testing machine to pro...

Determination of uranium in uranyl nitrate solutions of nuclear grade quality - Gravimetric method

International Nuclear Information System (INIS)

1990-01-01

This international Standard specifies a precise and accurate gravimetric method for determining the uranium content in uranyl nitrate product solutions of nuclear grade quality at concentrations above 100 g/l of uranium. Non-volatile impurities influence the accuracy of the method. Uranyl nitrate is converted into uranium octoxide (U 3 O 8 ) by ignition in air to constant mass at 900 deg. C ± 10 deg. C. Calculation of the uranium content in the sample using a gravimetric conversion factor which depends on the isotopic composition of the uranium. The isotopic composition is determined by mass spectrometry

Gravimetric study on the western edge of the Rio de La Plata craton

International Nuclear Information System (INIS)

Rame, G; Miro, R

2010-01-01

This work is about the gravimetric study on the western edge of the Rio de la Plata craton which belongs to the Gondwana fragment in the south of Brazil, Uruguay and central eastern of Argentina. The work consisted of a survey of 332 gravimetric and topographic stations extended from the western edge of the Sierra Chica de Cordoba up to 200 km east on the pampas. The gravity values observed (gobs) were obtained using a LaCoste §Rom berg gravimeter G-961 and 200T Sodin both with 0.01 mGal, referred to IGSN71 (International Gravity Standardization Net 1971) network

A gravimetric and an X-ray fluorescence method for the determination of rubidium in Rb2U(SO4)3

International Nuclear Information System (INIS)

Mudher, K.D.S.; Krishnan, K.; Jayadevan, N.C.

1993-01-01

Chemical characterization of rubidium uranium(IV) trisulfate, RB 2 U(SO 4 ) 3 , a new chemical assay standard for uranium requires accurate analysis of rubidium. A gravimetric and an X-ray fluorescence method (XRF) for the determination of rubidium in this compound are described. In the gravimetric method, rubidium is determined as Rb 2 Na[Co(NO 2 ) 6 ].H 2 O without separating uranium with a precision of the order of ±0.5%. In the XRF method, the concentration ratio of rubidium to uranium, C Rb /C U , is determined in the solid samples by the binary ratio method using calibration between intensity ratios (I Rb /I U ) and concentration ratios (C Rb /C U ). (author) 6 refs.; 2 figs.; 3 tabs

Data for effects of lanthanum complex on the thermo-oxidative aging of natural rubber

Directory of Open Access Journals (Sweden)

Wei Zheng

2015-12-01

Full Text Available Novel mixed antioxidants composed of antioxidant IPPD and lanthanum (La complex were added as a filler to form natural rubber (NR composites. By mechanical testing, Fourier transform infrared spectroscopy with attenuated total reflectance (FTIR-ATR and thermogravimetric analysis (TGA, a string of data, including the mechanical properties, the variation of internal groups and the thermal and thermo-oxidative decompositions of NR, was presented in this data article. The data accompanying its research article [1] studied the thermo-oxidative aging properties of NR in detail. The density function theoretical (DFT calculations were also used as an assistant to study the thermo-oxidative aging mechanism of NR. The data revealed that this new rare-earth antioxidant could indeed enhance the thermo-oxidative aging resistance of NR, which is associated with its different function mechanism from that of the pure antioxidant IPPD.

Data for effects of lanthanum complex on the thermo-oxidative aging of natural rubber.

Science.gov (United States)

Zheng, Wei; Liu, Li; Zhao, Xiuying; He, Jingwei; Wang, Ao; Chan, Tung W; Wu, Sizhu

2015-12-01

Novel mixed antioxidants composed of antioxidant IPPD and lanthanum (La) complex were added as a filler to form natural rubber (NR) composites. By mechanical testing, Fourier transform infrared spectroscopy with attenuated total reflectance (FTIR-ATR) and thermogravimetric analysis (TGA), a string of data, including the mechanical properties, the variation of internal groups and the thermal and thermo-oxidative decompositions of NR, was presented in this data article. The data accompanying its research article [1] studied the thermo-oxidative aging properties of NR in detail. The density function theoretical (DFT) calculations were also used as an assistant to study the thermo-oxidative aging mechanism of NR. The data revealed that this new rare-earth antioxidant could indeed enhance the thermo-oxidative aging resistance of NR, which is associated with its different function mechanism from that of the pure antioxidant IPPD.

Data for effects of lanthanum complex on the thermo-oxidative aging of natural rubber

Science.gov (United States)

Zheng, Wei; Liu, Li; Zhao, Xiuying; He, Jingwei; Wang, Ao; Chan, Tung W.; Wu, Sizhu

2015-01-01

Novel mixed antioxidants composed of antioxidant IPPD and lanthanum (La) complex were added as a filler to form natural rubber (NR) composites. By mechanical testing, Fourier transform infrared spectroscopy with attenuated total reflectance (FTIR-ATR) and thermogravimetric analysis (TGA), a string of data, including the mechanical properties, the variation of internal groups and the thermal and thermo-oxidative decompositions of NR, was presented in this data article. The data accompanying its research article [1] studied the thermo-oxidative aging properties of NR in detail. The density function theoretical (DFT) calculations were also used as an assistant to study the thermo-oxidative aging mechanism of NR. The data revealed that this new rare-earth antioxidant could indeed enhance the thermo-oxidative aging resistance of NR, which is associated with its different function mechanism from that of the pure antioxidant IPPD. PMID:26693513

The TRPM2 channel: A thermo-sensitive metabolic sensor.

Science.gov (United States)

Kashio, Makiko; Tominaga, Makoto

2017-09-03

Living organisms continually experience changes in ambient temperature. To detect such temperature changes for adaptive behavioral responses, we evolved the ability to sense temperature. Thermosensitive transient receptor potential (TRP) channels, so-called thermo-TRPs, are involved in many physiologic functions in diverse organisms and constitute important temperature sensors. One of the important roles of thermo-TRPs is detecting ambient temperature in sensory neurons. Importantly, the functional expression of thermo-TRPs is observed not only in sensory neurons but also in tissues and cells that are not exposed to drastic temperature changes, indicating that thermo-TRPs are involved in many physiologic functions within the body's normal temperature range. Among such thermo-TRPs, this review focuses on one thermo-sensitive metabolic sensor in particular, TRPM2, and summarizes recent progress to clarify the regulatory mechanisms and physiologic functions of TRPM2 at body temperature under various metabolic states.

New Techniques for Thermo-electrochemical Analysis of Lithium-ion Batteries for Space Applications

Science.gov (United States)

Walker, William; Ardebili, H.

2013-01-01

The overall goal of this study was achieved: Replicated the numerical assessment performed by Chen et. al. (2005). Displayed the ability of Thermal Desktop to be coupled with thermo-electrochemical analysis techniques. such that the local heat generated on the cells is a function of the model itself using logic blocks and arrays. Differences in the TD temperature vs. depth of discharge profiles and Chen's was most likely due to differences in two primary areas: Contact regions and conductance values. Differences in density and specific heat values. center dot The model results are highly dependent on the accuracy of the material properties with respect to the multiple layers of an individual cell.

Evaluation of thermo-mechanical properties data of carbon-based plasma facing materials

International Nuclear Information System (INIS)

Ulrickson, M.; Barabash, V.R.; Matera, R.; Roedig, M.; Smith, J.J.; Janev, R.K.

1991-03-01

This Report contains the proceedings, results and conclusions of the work done and the analysis performed during the IAEA Consultants' Meeting on ''Evaluation of thermo-mechanical properties data of carbon-based plasma facing materials'', convened on December 17-21, 1990, at the IAEA Headquarters in Vienna. Although the prime objective of the meeting was to critically assess the available thermo-mechanical properties data for certain types of carbon-based fusion relevant materials, the work of the meeting went well beyond this task. The meeting participants discussed in depth the scope and structure of the IAEA material properties database, the format of data presentation, the most appropriate computerized system for data storage, retrieval, exchange and management. The existing IAEA ALADDIN system was adopted as a convenient tool for this purpose and specific ALADDIN labelling schemes and dictionaries were established for the material properties data. An ALADDIN formatted test-file for the thermo-physical and thermo-mechanical properties of pyrolytic graphite is appended to this Report for illustrative purposes. (author)

Thermo-mechanical design of the extraction grids for RF negative ion source at HUST

Energy Technology Data Exchange (ETDEWEB)

Zuo, Chen; Liu, Kaifeng, E-mail: kfliuhust@hust.edu.cn; Li, Dong; Mei, Zhiyuan; Zhang, Zhe; Chen, Dezhi

2017-01-15

Highlights: • An extraction system with cooling channels has been designed for HUST negative ion source. • Corresponding heat loads onto three grids has been used in thermo-mechanical analysis. • The analysis results could be very useful for driving the engineering design. - Abstract: Huazhong University of Science and Technology (HUST) is developing a small radio frequency negative ion source experimental setup to promote research on neutral beam injection ion sources. The extraction system for the negative ion source is the key component to obtain the negative ions. The extraction system is composed of three grids: the plasma grid, the extraction grid and the grounded grid. Each grid is impacted by different heat loads. As the grids have to fulfil specific requirements regarding ion extraction, beam optics, and thermo-mechanical issues, grid cooling systems have been included for ensuring reliable operation. This paper focuses on the thermo-hydraulic and thermo-mechanical design of the grids. Finite element calculations have been carried out to analyse the temperature and deformation of the grids under heat loads using the fluid dynamics code CFX. Based on these results, the cooling circuit design and cooling parameters are optimised to satisfy the grid requirements.

Inkjet-Printed Biofunctional Thermo-Plasmonic Interfaces for Patterned Neuromodulation.

Science.gov (United States)

Kang, Hongki; Lee, Gu-Haeng; Jung, Hyunjun; Lee, Jee Woong; Nam, Yoonkey

2018-02-27

Localized heat generation by the thermo-plasmonic effect of metal nanoparticles has great potential in biomedical engineering research. Precise patterning of the nanoparticles using inkjet printing can enable the application of the thermo-plasmonic effect in a well-controlled way (shape and intensity). However, a universally applicable inkjet printing process that allows good control in patterning and assembly of nanoparticles with good biocompatibility is missing. Here we developed inkjet-printing-based biofunctional thermo-plasmonic interfaces that can modulate biological activities. We found that inkjet printing of plasmonic nanoparticles on a polyelectrolyte layer-by-layer substrate coating enables high-quality, biocompatible thermo-plasmonic interfaces across various substrates (rigid/flexible, hydrophobic/hydrophilic) by induced contact line pinning and electrostatically assisted nanoparticle assembly. We experimentally confirmed that the generated heat from the inkjet-printed thermo-plasmonic patterns can be applied in micrometer resolution over a large area. Lastly, we demonstrated that the patterned thermo-plasmonic effect from the inkjet-printed gold nanorods can selectively modulate neuronal network activities. This inkjet printing process therefore can be a universal method for biofunctional thermo-plasmonic interfaces in various bioengineering applications.

Precise and efficient evaluation of gravimetric quantities at arbitrarily scattered points in space

Science.gov (United States)

Ivanov, Kamen G.; Pavlis, Nikolaos K.; Petrushev, Pencho

2017-12-01

Gravimetric quantities are commonly represented in terms of high degree surface or solid spherical harmonics. After EGM2008, such expansions routinely extend to spherical harmonic degree 2190, which makes the computation of gravimetric quantities at a large number of arbitrarily scattered points in space using harmonic synthesis, a very computationally demanding process. We present here the development of an algorithm and its associated software for the efficient and precise evaluation of gravimetric quantities, represented in high degree solid spherical harmonics, at arbitrarily scattered points in the space exterior to the surface of the Earth. The new algorithm is based on representation of the quantities of interest in solid ellipsoidal harmonics and application of the tensor product trigonometric needlets. A FORTRAN implementation of this algorithm has been developed and extensively tested. The capabilities of the code are demonstrated using as examples the disturbing potential T, height anomaly ζ , gravity anomaly Δ g , gravity disturbance δ g , north-south deflection of the vertical ξ , east-west deflection of the vertical η , and the second radial derivative T_{rr} of the disturbing potential. After a pre-computational step that takes between 1 and 2 h per quantity, the current version of the software is capable of computing on a standard PC each of these quantities in the range from the surface of the Earth up to 544 km above that surface at speeds between 20,000 and 40,000 point evaluations per second, depending on the gravimetric quantity being evaluated, while the relative error does not exceed 10^{-6} and the memory (RAM) use is 9.3 GB.

Investigation research on the evaluation of a coupled thermo-hydro-mechanical-chemical phenomena. Outline report

International Nuclear Information System (INIS)

Chijimatsu, Masakazu; Amemiya, Kiyoshi; Neyama, Atsushi; Iwata, Hiroshi; Nakagawa, Koichi; Ishihara, Yoshinao; Shiozaki, Isao; Sagawa, Hiroshi

2002-02-01

In order to realize a coupling analysis in the near field of the geological disposal system, this study has been studied on the addition of the mass transport model to the coupled thermo-hydro-mechanical analysis code (THAMES) and preliminary coupling analysis by using development environmental tool (Diffpack) for numerical analysis. (1) In order to prepare the strategy on the addition of the mass transport model to the coupled thermo-hydro-mechanical analysis code (THAMES), we have studied on the requirement of THAMES-Transport and methodology of coupling analysis. After that we set out modification plan by the Eulerian-Lagrangian (EL) method. (2) Based on the document of modification plan, we have done addition of the mass transport model to the coupled thermo-hydro-mechanical analysis code (THAMES) and carried out verification analysis in order to confirm on the accuracy of THAMES-Transport. (3) In order to understand on the behavior of NaCl in the porewater under the coupled thermo-hydro-mechanical phenomena in the HLW engineered barrier system, we have calculated coupling phenomenon by using THAMES-Transport. Transportation and concentration phenomena of NaCl are calculated but precipitation of NaCl is not occurred under the analysis conditions in this report. (4) In order to confirm about feasibility of coupling analysis under the development environmental tool (Diffpack) for numerical analysis, we have carried out on the design work and writing program of the preliminary coupling system. In this study, we have adopted existing transport model (HYDROGEOCHEM) and geochemical model (phreeqe60) for preliminary coupling system. (5) In order to confirm program correctness of preliminary coupling system, we have carried out benchmarking analysis by using existing reactive-transport analysis code (HYDROGEOCHEM). (6) We have been prepared short-range development plan based on through the modification study of THAMES and writing program of the preliminary coupling

Investigation research on the evaluation of a coupled thermo-hydro-mechanical-chemical phenomena. Result report

International Nuclear Information System (INIS)

Chijimatsu, Masakazu; Amemiya, Kiyoshi; Shiozaki, Isao; Neyama, Atsushi; Iwata, Hiroshi; Nakagawa, Koichi; Ishihara, Yoshinao; Sagawa, Hiroshi

2002-02-01

In order to realize a coupling analysis in the near field of the geological disposal system, this study has been studied on the addition of the mass transport model to the coupled thermo-hydro-mechanical analysis code (THAMES) and preliminary coupling analysis by using development environmental tool (Diffpack) for numerical analysis. (1) In order to prepare the strategy on the addition of the mass transport model to the coupled thermo-hydro-mechanical analysis code (THAMES), we have studied on the requirement of THAMES-Transport and methodology of coupling analysis. After that we set out modification plan by the Eulerian-Lagrangian (EL) method. (2) Based on the document of modification plan, we have done addition of the mass transport model to the coupled thermo-hydro-mechanical analysis code (THAMES) and carried out verification analysis in order to confirm on the accuracy of THAMES-Transport. (3) In order to understand on the behavior of NaCl in the porewater under the coupled thermo-hydro-mechanical phenomena in the HLW engineered barrier system, we have calculated coupling phenomenon by using THAMES-Transport. Transportation and concentration phenomena of NaCl are calculated but precipitation of NaCl is not occurred under the analysis conditions in this report. (4) In order to confirm about feasibility of coupling analysis under the development environmental tool (Diffpack) for numerical analysis, we have carried out on the design work and writing program of the preliminary coupling system. In this study, we have adopted existing transport model (HYDROGEOCHEM) and geochemical model (phreeqe 60) for preliminary coupling system. (5) In order to confirm program correctness of preliminary coupling system, we have carried out benchmarking analysis by using existing reactive-transport analysis code (HYDROGEOCHEM). (6) We have been prepared short-range development plan based on through the modification study of THAMES and writing program of the preliminary coupling

Fabrication of thermo-responsive PNIPAAm-g-ETFE for cell culture dishes by pre-irradiation grafting

Science.gov (United States)

Yamahara, Yumi; Nagasawa, Naotsugu; Taguchi, Mitsumasa; Oshima, Akihiro; Washio, Masakazu

2018-01-01

Thermo-responsive templates for the cell cultivation based on Poly(tetrafluoroethylene-co-ethylene) (ETFE) were fabricated by pre-irradiation grafting of N-isoproplyacrylamide (NIPAAm) monomer by electron beam (EB) irradiation under nitrogen gas atmosphere at room temperature, and their characteristic properties were studied. The detachment of cultured HeLa cells from fabricated thermo-responsive templates were attempted. Furthermore, the reaction mechanism is proposed using ESR spectroscopy and FT-IR spectroscopy. It is confirmed that the cultured HeLa cells were detached from fabricated thermo-responsive templates at 20 °C. Water contact angle analysis indicated that obtained templates had thermo-response around 30 °C. It is suggested that the grafted polymer chains would mainly react with peroxy radicals (-CF2-CF(OO･)-) on tetrafluoroethylene unit in ETFE.

Some technical details concerning a new method of gravimetric-seismic inversion

DEFF Research Database (Denmark)

Strykowski, Gabriel

1999-01-01

In this paper a number of technical details related to a new method of gravimetric-seismic inversion, which is still under development, are explained. Although the present contribution aims on providing general statements on how to formulate and solve complex gravimetric-seismic modeling; problems......, the inspiration comes from the practical modeling problems in the area of Jutland peninsula (Denmark). More specifically, the methodological aspects of the proposed inversion method are illustrated on a problem of 3D modeling of the intra crustal intrusion associated with the Silkeborg Gravity High. The existing...... refraction seismic profile locates the source of the anomaly in depths 10 km - 18 km. In an earlier publication, (Strykowski, 1998), and for the same test area, a method of complex geological stripping is described. The present contribution is a continuation of this paper in the direction of inversion...

Geothermal-Related Thermo-Elastic Fracture Analysis by Numerical Manifold Method

OpenAIRE

Jun He; Quansheng Liu; Zhijun Wu; Yalong Jiang

2018-01-01

One significant factor influencing geothermal energy exploitation is the variation of the mechanical properties of rock in high temperature environments. Since rock is typically a heterogeneous granular material, thermal fracturing frequently occurs in the rock when the ambient temperature changes, which can greatly influence the geothermal energy exploitation. A numerical method based on the numerical manifold method (NMM) is developed in this study to simulate the thermo-elastic fracturing ...

Thermo-mechanical ratcheting in jointed rock masses

KAUST Repository

Pasten, C.

2015-09-01

Thermo-mechanical coupling takes place in jointed rock masses subjected to large thermal oscillations. Examples range from exposed surfaces under daily and seasonal thermal fluctuations to subsurface rock masses affected by engineered systems such as geothermal operations. Experimental, numerical and analytical results show that thermo-mechanical coupling can lead to wedging and ratcheting mechanisms that result in deformation accumulation when the rock mass is subjected to a biased static-force condition. Analytical and numerical models help in identifying the parameter domain where thermo-mechanical ratcheting can take place.

Thermo-mechanical ratcheting in jointed rock masses

KAUST Repository

Pasten, C.; Garcí a, M.; Santamarina, Carlos

2015-01-01

Thermo-mechanical coupling takes place in jointed rock masses subjected to large thermal oscillations. Examples range from exposed surfaces under daily and seasonal thermal fluctuations to subsurface rock masses affected by engineered systems such as geothermal operations. Experimental, numerical and analytical results show that thermo-mechanical coupling can lead to wedging and ratcheting mechanisms that result in deformation accumulation when the rock mass is subjected to a biased static-force condition. Analytical and numerical models help in identifying the parameter domain where thermo-mechanical ratcheting can take place.

Coupled Thermo-Electro-Magneto-Elastic Response of Smart Stiffened Panels

Science.gov (United States)

Bednarcyk, Brett A.; Yarrington, Phillip W.

2009-01-01

This report documents the procedures developed for incorporating smart laminate and panel analysis capabilities within the HyperSizer aerospace structural sizing software package. HyperSizer analyzes stiffened panels composed of arbitrary composite laminates through stiffener homogenization, or "smearing " techniques. The result is an effective constitutive equation for the stiffened panel that is suitable for use in a full vehicle-scale finite element analysis via MSC/NASTRAN. The existing thermo-elastic capabilities of HyperSizer have herein been extended to include coupled thermo-electro-magneto-elastic analysis capabilities. This represents a significant step toward realization of design tools capable of guiding the development of the next generation of smart aerospace structures. Verification results are presented that compare the developed smart HyperSizer capability with an ABAQUS piezoelectric finite element solution for a facesheet-flange combination. These results show good agreement between HyperSizer and ABAQUS, but highlight a limitation of the HyperSizer formulation in that constant electric field components are assumed.

On nonlinear thermo-electro-elasticity.

Science.gov (United States)

Mehnert, Markus; Hossain, Mokarram; Steinmann, Paul

2016-06-01

Electro-active polymers (EAPs) for large actuations are nowadays well-known and promising candidates for producing sensors, actuators and generators. In general, polymeric materials are sensitive to differential temperature histories. During experimental characterizations of EAPs under electro-mechanically coupled loads, it is difficult to maintain constant temperature not only because of an external differential temperature history but also because of the changes in internal temperature caused by the application of high electric loads. In this contribution, a thermo-electro-mechanically coupled constitutive framework is proposed based on the total energy approach. Departing from relevant laws of thermodynamics, thermodynamically consistent constitutive equations are formulated. To demonstrate the performance of the proposed thermo-electro-mechanically coupled framework, a frequently used non-homogeneous boundary-value problem, i.e. the extension and inflation of a cylindrical tube, is solved analytically. The results illustrate the influence of various thermo-electro-mechanical couplings.

Transient Thermo-Mechanical Analysis of the TPSG4 Beam Diluter

CERN Document Server

Goddard, B; Herrera-Martínez, A; Kadi, Y; Marque, S

2002-01-01

A new extraction channel is being built in the Super Proton Synchrotron (SPS) Long Straight Section 4 (LSS4) to transfer proton beams to the Large Hadron Collider (LHC) and also to the CERN Neutrino to Gran Sasso (CNGS) target. The beam is extracted in a fast mode during a single turn. For this purpose a protection of the MSE copper septum coil, in the form of a beam diluting element placed upstream, will be required to cope with the new failure modes associated with the fast extraction operation. The present analysis focuses on the thermo-mechanical behavior of the proposed TPSG4 diluter element irradiated by a fast extracted beam (up to 4.9 x 10^13 protons per 7.2 mus pulse) from the SPS. The deposited energy densities, estimated from primary and secondary particle simulations using the high-energy particle transport code FLUKA, were converted to internal heat generation rates taken as a thermal load input for the finite-element engineering analyses code ANSYS. According to the time dependence of the extrac...

Enhanced pathway efficiency of Saccharomyces cerevisiae by introducing thermo-tolerant devices.

Science.gov (United States)

Liu, Yueqin; Zhang, Genli; Sun, Huan; Sun, Xiangying; Jiang, Nisi; Rasool, Aamir; Lin, Zhanglin; Li, Chun

2014-10-01

In this study, thermo-tolerant devices consisting of heat shock genes from thermophiles were designed and introduced into Saccharomyces cerevisiae for improving its thermo-tolerance. Among ten engineered thermo-tolerant yeasts, T.te-TTE2469, T.te-GroS2 and T.te-IbpA displayed over 25% increased cell density and 1.5-4-fold cell viability compared with the control. Physiological characteristics of thermo-tolerant strains revealed that better cell wall integrity, higher trehalose content and enhanced metabolic energy were preserved by thermo-tolerant devices. Engineered thermo-tolerant strain was used to investigate the impact of thermo-tolerant device on pathway efficiency by introducing β-amyrin synthesis pathway, showed 28.1% increased β-amyrin titer, 28-35°C broadened growth temperature range and 72h shortened fermentation period. The results indicated that implanting heat shock proteins from thermophiles to S. cerevisiae would be an efficient approach to improve its thermo-tolerance. Copyright © 2014 Elsevier Ltd. All rights reserved.

Gravimetric preparation and characterization of primary reference solutions of molybdenum and rhodium.

Science.gov (United States)

Kaltenbach, Angela; Noordmann, Janine; Görlitz, Volker; Pape, Carola; Richter, Silke; Kipphardt, Heinrich; Kopp, Gernot; Jährling, Reinhard; Rienitz, Olaf; Güttler, Bernd

2015-04-01

Gravimetrically prepared mono-elemental reference solutions having a well-known mass fraction of approximately 1 g/kg (or a mass concentration of 1 g/L) define the very basis of virtually all measurements in inorganic analysis. Serving as the starting materials of all standard/calibration solutions, they link virtually all measurements of inorganic analytes (regardless of the method applied) to the purity of the solid materials (high-purity metals or salts) they were prepared from. In case these solid materials are characterized comprehensively with respect to their purity, this link also establishes direct metrological traceability to The International System of Units (SI). This, in turn, ensures the comparability of all results on the highest level achievable. Several national metrology institutes (NMIs) and designated institutes (DIs) have been working for nearly two decades in close cooperation with commercial producers on making an increasing number of traceable reference solutions available. Besides the comprehensive characterization of the solid starting materials, dissolving them both loss-free and completely under strict gravimetric control is a challenging problem in the case of several elements like molybdenum and rhodium. Within the framework of the European Metrology Research Programme (EMRP), in the Joint Research Project (JRP) called SIB09 Primary standards for challenging elements, reference solutions of molybdenum and rhodium were prepared directly from the respective metals with a relative expanded uncertainty associated with the mass fraction of U rel(w) methods required to assist with the preparation and as dissemination tools.

Characterization of materials used in the execution of historic oil paintings by XRD, SEM-EDS, TGA and LIBS analysis

OpenAIRE

Şerifaki, Kerem; Böke, Hasan; Yalçın, Şerife; İpekoğlu, Başak

2009-01-01

In this study, material characteristics of historic oil paintings in a 19th century church in Ayvali{dotless}k/Turkey were investigated to propose the treatments to be used in their conservation and protection. For this purpose, physical, chemical and mineralogical compositions and the microstructure of the paintings were determined by X-ray Diffraction, Scanning Electron Microscope, Thermo Gravimetric Analyzer, Differential Scanning Calorimeter, Infrared Spectroscopy and Laser Induced Breakd...

Uncertainty associated with assessing semen volume: are volumetric and gravimetric methods that different?

Science.gov (United States)

Woodward, Bryan; Gossen, Nicole; Meadows, Jessica; Tomlinson, Mathew

2016-12-01

The World Health Organization laboratory manual for the examination of human semen suggests that an indirect measurement of semen volume by weighing (gravimetric method) is more accurate than a direct measure using a serological pipette. A series of experiments were performed to determine the level of discrepancy between the two methods using pipettes and a balance which had been calibrated to a traceable standard. The median weights of 1.0ml and 5.0ml of semen were 1.03 g (range 1.02-1.05 g) and 5.11 g (range 4.95-5.16 g), respectively, suggesting a density for semen between 1.03g and 1.04 g/ml. When the containers were re-weighed after the removal of 5.0 ml semen using a serological pipette, the mean residual loss was 0.12 ml (120 μl) or 0.12 g (median 100 μl, range 70-300 μl). Direct comparison of the volumetric and gravimetric methods in a total of 40 samples showed a mean difference of 0.25ml (median 0.32 ± 0.67ml) representing an error of 8.5%. Residual semen left in the container by weight was on average 0.11 g (median 0.10 g, range 0.05-0.19 g). Assuming a density of 1 g/ml then the average error between volumetric and gravimetric methods was approximately 8% (p gravimetric measurement of semen volume. Laboratories may therefore prefer to provide in-house quality assurance data in order to be satisfied that 'estimating' semen volume is 'fit for purpose' as opposed to assuming a lower uncertainty associated with the WHO recommended method.

Synthesis and Characterization of pH and Thermo Dual-Responsive Hydrogels with a Semi-IPN Structure Based on N-Isopropylacrylamide and Itaconamic Acid.

Science.gov (United States)

Rwei, Syang-Peng; Tuan, Huynh Nguyen Anh; Chiang, Whe-Yi; Way, Tun-Fun

2018-04-28

A series of semi-interpenetrating polymer network (semi-IPN) hydrogels were synthesized and investigated in this study. Linear copolymer poly( N -isopropylacrylamide-co-itaconamic acid) p(NIPAM-co-IAM), which is formed by copolymerization of N -isopropylacrylamide (NIPAM) and itaconamic acid (IAM, 4-amino-2-ethylene-4-oxobutanoic acid), was introduced into a solution of NIPAM to form a series of pH and thermo dual-responsive p(NIPAM-co-IAM)/pNIPAM semi-IPN hydrogels by free radical polymerization. The structural, morphological, chemical, and physical properties of the linear copolymer and semi-IPN hydrogels were investigated. The semi-IPN hydrogel showed high thermal stability according to thermal gravimetric analyzer (TGA). Scanning electronic microscopy (SEM) images showed that the pore size was in the range of 119~297 µm and could be controlled by the addition ratio of the linear copolymer in the semi-IPN structure. The addition of linear copolymer increased the fracture strain from 57.5 ± 2.9% to 91.1 ± 4.9% depending on the added amount, while the compressive modulus decreased as the addition increased. Moreover, the pH and thermo dual-responsive properties were investigated using differential scanning calorimetry (DSC) and monitoring the swelling behavior of the hydrogels. In deionized (DI) water, the equilibrium swelling ratio of the hydrogels decreased as the temperature increased from 20 °C to 50 °C, while it varied in various pH buffer solutions. In addition, the swelling and deswelling rates of the hydrogels also significantly increased. The results indicate that the novel pH-thermo dual-responsive semi-IPN hydrogels were synthesized successfully and may be a potential material for biomedical, drug delivery, or absorption application.

Status of the LMFBR thermo- and fluid-dynamic activities at KFK

International Nuclear Information System (INIS)

Hoffmann, H.; Hofmann, F.; Rehme, K.

1979-01-01

The aim of the thermo- and fluiddynamic analysis is to determine the spatial velocity and temperature distributions in LMFBR-core elements with high accuracy. Knowledge of these data is a necessary prerequisite for determining the mechanical behavior of fuel rods and of structural material. Three cases are distinguished: Nominal geometry and steady state conditions; non-nominal geometry and quasi-steady state conditions; nominal geometry and non-steady state conditions. The present situation for the design calculations of fuel elements is based mainly on undisturbed normal operation. Most of the thermo- and fluiddynamic activities performed under the Fast Breeder Programme at KFK are related to this case. The present status of theoretical and experimental research work briefly presented in this paper, can be subdivided into the following main topics: 1. Physical and mathematical modelling of single phase rod bundle thermo- and fluiddynamics, 2. Experimental investigations on heat transfer and fluid flow in rod bundles

Comparison of Metal-on-Metal Hip Simulator Wear Measured by Gravimetric, CMM and Optical Profiling Methods

OpenAIRE

Alberts, Larry Russell; Martinez-Nogues, Vanesa; Cook, Richard; Maul, Christian; Bills, Paul J.; Racasan, Radu; Stolz, Martin; Wood, Robert J. K.

2018-01-01

Simulation of wear in artificial joint implants is critical for evaluating implant designs and materials. Traditional protocols employ the gravimetric method to determine the loss of material by measuring the weight of the implant components before and after various test intervals and after the completed test. However, the gravimetric method cannot identify the location, area coverage or maximum depth of the wear and it has difficulties with proportionally small weight changes in relatively h...

Erosion of water-based cements evaluated by volumetric and gravimetric methods.

Science.gov (United States)

Nomoto, Rie; Uchida, Keiko; Momoi, Yasuko; McCabe, John F

2003-05-01

To compare the erosion of glass ionomer, zinc phosphate and polycarboxylate cements using volumetric and gravimetric methods. For the volumetric method, the eroded depth of cement placed in a cylindrical cavity in PMMA was measured using a dial gauge after immersion in an eroding solution. For the gravimetric method, the weight of the residue of a solution in which a cylindrical specimen had been immersed was measured. 0.02 M lactic acid solution (0.02 M acid) and 0.1 M lactic acid/sodium lactate buffer solution (0.1 M buffer) were used as eroding solutions. The pH of both solutions was 2.74 and the test period was 24 h. Ranking of eroded depth and weight of residue was polycarboxylate>zinc phosphate>glass ionomers. Differences in erosion were more clearly defined by differences in eroded depth than differences in weight of residue. In 0.02 M acid, the erosion of glass ionomer using the volumetric method was effected by the hygroscopic expansion. In 0.1 M buffer, the erosion for polycarboxylate and zinc phosphate using the volumetric method was much greater than that using the gravimetric method. This is explained by cryo-SEM images which show many holes in the surface of specimens after erosion. It appears that zinc oxide is dissolved leaving a spongy matrix which easily collapses under the force applied to the dial gauge during measurement. The volumetric method that employs eroded depth of cement using a 0.1 M buffer solution is able to quantify erosion and to make material comparisons.

Thermo-controlled rheology of electro-assembled polyanionic polysaccharide (alginate) and polycationic thermo-sensitive polymers.

Science.gov (United States)

Niang, Pape Momar; Huang, Zhiwei; Dulong, Virginie; Souguir, Zied; Le Cerf, Didier; Picton, Luc

2016-03-30

Several thermo-sensitive polyelectrolyte complexes were prepared by ionic self-association between an anionic polysaccharide (alginate) and a monocationic copolymer (polyether amine, Jeffamine®-M2005) with a 'Low Critical Solubility Temperature' (LCST). We show that electro-association must be established below the aggregation temperature of the free Jeffamine®, after which the organization of the system is controlled by the thermo-association of Jeffamine® that was previously electro-associated with the alginate. Evidence for this comes primarily from the rheology in the semi-dilute region. Electro- and thermo-associative behaviours are optimal at a pH corresponding to maximum ionization of both compounds (around pH 7). High ionic strength could prevent the electro-association. The reversibility of the transition is possible only at temperatures lower than the LCST of Jeffamine®. Similar behaviour has been obtained with carboxymethyl cellulose (CMC), which suggests that this behaviour can be observed using a range of anionic polyelectrolytes. In contrast, no specific properties have been found for pullulan, which is a neutral polysaccharide. Copyright © 2015 Elsevier Ltd. All rights reserved.

Crustal thickness of Antarctica estimated using data from gravimetric satellites

Science.gov (United States)

Llubes, Muriel; Seoane, Lucia; Bruinsma, Sean; Rémy, Frédérique

2018-04-01

Computing a better crustal thickness model is still a necessary improvement in Antarctica. In this remote continent where almost all the bedrock is covered by the ice sheet, seismic investigations do not reach a sufficient spatial resolution for geological and geophysical purposes. Here, we present a global map of Antarctic crustal thickness computed from space gravity observations. The DIR5 gravity field model, built from GOCE and GRACE gravimetric data, is inverted with the Parker-Oldenburg iterative algorithm. The BEDMAP products are used to estimate the gravity effect of the ice and the rocky surface. Our result is compared to crustal thickness calculated from seismological studies and the CRUST1.0 and AN1 models. Although the CRUST1.0 model shows a very good agreement with ours, its spatial resolution is larger than the one we obtain with gravimetric data. Finally, we compute a model in which the crust-mantle density contrast is adjusted to fit the Moho depth from the CRUST1.0 model. In East Antarctica, the resulting density contrast clearly shows higher values than in West Antarctica.

A Mathematical Model of the Thermo-Anemometric Flowmeter.

Science.gov (United States)

Korobiichuk, Igor; Bezvesilna, Olena; Ilchenko, Andriі; Shadura, Valentina; Nowicki, Michał; Szewczyk, Roman

2015-09-11

A thermo-anemometric flowmeter design and the principles of its work are presented in the article. A mathematical model of the temperature field in a stream of biofuel is proposed. This model allows one to determine the fuel consumption with high accuracy. Numerical modeling of the heater heat balance in the fuel flow of a thermo-anemometric flowmeter is conducted and the results are analyzed. Methods for increasing the measurement speed and accuracy of a thermo-anemometric flowmeter are proposed.

The Thermos process heat reactor

International Nuclear Information System (INIS)

Lerouge, Bernard

1979-01-01

The THERMOS process heat reactor was born from the following idea: the hot water energy vector is widely used for heating purposes in cities, so why not save on traditional fossil fuels by simply substituting a nuclear boiler of comparable power for the classical boiler installed in the same place. The French Atomic Energy Commission has techniques for heating in the big French cities which provide better guarantees for national independence and for the environment. This THERMOS technique would result in a saving of 40,000 to 80,000 tons of oil per year [fr

Thermo-economic analysis of a solid oxide fuel cell and steam injected gas turbine plant integrated with woodchips gasification

DEFF Research Database (Denmark)

Mazzucco, Andrea; Rokni, Masoud

2014-01-01

cost on the generation cost is also presented. In order to discuss the investment cost, an economic analysis has been carried out and main parameters such as Net Present Value (NPV), internal rate of return (IRR) and Time of Return of Investment (TIR) are calculated and discussed.......% respectively which are significantly greater than conventional 10 MWe plants fed by biomass. Thermo-economic analysis provides an average cost of electricity for best performing layouts close to 6.4 and 9.4 c€/kWe which is competitive within the market. A sensitivity analysis of the influence of SOFC stack...

Use of sulfoxides for extraction-gravimetric determination of niobium and tantalum

International Nuclear Information System (INIS)

Nikolaev, A.I.; Babkin, A.G.; Tkachenko, V.G.

1977-01-01

An extraction-gravimetrical technique has been developed for determination of niobium and tantalum. The technique permits simultaneous extraction of tantalum and its concentrating in the aqueous phase; the range of Ta concentrations determined is essentially wider than in case of the routine gravimetric methods. The technique is based upon the fact, that tantalum is extracted by sulfoxides from fluorine-sulphate solutions at lower concentration of Hf and at lower ratios between the volumes of organic and aqueous phases than niobium. Two subsequent extractions by 1M sulfoxide solutions provide for practically complete transfer of tantalum into the organic phase, whereas extraction of niobium is only 3-20%. Sufficient recovery of Ta and Nb from organic phases is provided by re-extraction by NH 4 F solution. The technique is suitable for niobium and tantalum determination at the ratios of their pentoxides from 1:100 to 100:1. The disturbing influence of Fe(3) is suppressed by reductions to Fe(2)

Gravimetric determination of uranium(VI) and thorium(IV) with substituted pyrazolones

International Nuclear Information System (INIS)

Arora, H.C.; Rao, G.N.

1981-01-01

4-Acylpyrazolones like 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone (PMBP), 1-phenyl-3-methyl-4-p-nitrobenzoyl-5-pyrazolone (PMNP) and 1-phenyl-3-methyl-4-(3,5 dinitrobenzoyl)-5-pyrazolone (PMDP) have been synthesized and developed as gravimetric reagents for the determination of U(VI) and Th(IV). Uranium(VI) is almost quantitatively precipitated with PMBP, PMNP, and PMDP at pH 2.20, 1.85 and 1.70 respectively. The pH values for the complete precipitation of thorium(IV) with PMBP, PMNP and PMDP are 2.90, 2.75 and 2.50 respectively. PMBP has proved to be an efficient ligand for gravimetric determination of U(VI) by direct weighing method after drying at 100 +- 10 deg C. The percentage relative error varies from 0.4 to 1.6 in the determination of U(VI) by this method. The effect of a number of interfering ions on the precipitation of U(VI) by PMBP has been reported. (author)

Preparación y caracterización de la zeolita MCM-22 y de su precursor laminar

Directory of Open Access Journals (Sweden)

Pergher Sibele B. C.

2003-01-01

Full Text Available The layered precursor of MCM-22 was prepared with different Si/Al ratios: 15, 25, 50, 100 and ¥. Upon heat treatment these precursors form MCM-22 zeolite. Both layered precursor and MCM-22 zeolite were characterized by several techniques: Chemical Analysis by Atomic Absorption Spectroscopy (AAS, X-Ray Diffraction (XRD, Thermo-gravimetric Analysis (TGA, Pore Analysis by N2 and Ar adsorption, Scanning Electron Microscopy (SEM, Infrared Spectroscopy (IR and Temperature Programmed Desorption of ammonium (TPD.

Thermo-economic optimization of an endoreversible four-heat-reservoir absorption-refrigerator

International Nuclear Information System (INIS)

Qin Xiaoyong; Chen Lingen; Sun Fengrui; Wu Chih

2005-01-01

Based on an endoreversible four-heat-reservoir absorption-refrigeration-cycle model, the optimal thermo-economic performance of an absorption-refrigerator is analyzed and optimized assuming a linear (Newtonian) heat-transfer law applies. The optimal relation between the thermo-economic criterion and the coefficient of performance (COP), the maximum thermo-economic criterion, and the COP and specific cooling load for the maximum thermo-economic criterion of the cycle are derived using finite-time thermodynamics. Moreover, the effects of the cycle parameters on the thermo-economic performance of the cycle are studied by numerical examples

Thermo-economic analysis of proton exchange membrane fuel cell fuelled with methanol and methane

International Nuclear Information System (INIS)

Suleiman, B.; Abdulkareem, A.S.; Musa, U.; Mohammed, I.A.; Olutoye, M.A.; Abdullahi, Y.I.

2016-01-01

Highlights: • Modified proton exchange membrane fuel cell was reported. • Thermolib software was used for the simulation of PEM fuel cell configurations. • Optimal operating parameters at 50 kW output of each process were determined. • Thermo-economic analysis is the most efficient way of process selection. • Methane system configuration has been identified as the best preferred PEM fuel cell. - Abstract: Exergy and economic analysis is often used to find and identify the most efficient process configuration for proton exchange membrane fuel cell from the thermo-economic point of view. This work gives an explicit account of the synergetic effect of exergetic and economic analysis of proton exchange membrane fuel cell (PEMFC) using methanol and methane as fuel sources. This was carried out through computer simulation using Thermolib simulation toolbox. Data generated from the simulated model were subsequently used for the thermodynamic and economic analysis. Analysis of energy requirement for the two selected processes revealed that the methane fuelled system requires the lower amount of energy (4.578 kJ/s) in comparison to the methanol fuelled configuration which requires 180.719 J/s. Energy analysis of both configurations showed that the principle of energy conservation was satisfied while the result of the exergy analysis showed high exergetic efficiency around major equipment (heat exchangers, compressors and pumps) of methane fuelled configuration. Higher irreversibility rate were observed around the burner, stack, and steam reformer. These trends of exergetic efficiency and irreversibility rate were observed around equipment in the methanol fuelled system but with lower performance when compared with the methane fuelled process configuration. On the basis of overall exergetic efficiency and lost work, the methanol system was more efficient with lower irreversibility rate of 547.27 kJ/s and exergetic efficiency of 34.44% in comparison with the methane

Analysis of the Thermo-Elastic Response of Space Reflectors to Simulated Space Environment

Science.gov (United States)

Allegri, G.; Ivagnes, M. M.; Marchetti, M.; Poscente, F.

2002-01-01

The evaluation of space environment effects on materials and structures is a key matter to develop a proper design of long duration missions: since a large part of satellites operating in the earth orbital environment are employed for telecommunications, the development of space antennas and reflectors featured by high dimensional stability versus space environment interactions represents a major challenge for designers. The structural layout of state of the art space antennas and reflectors is very complex, since several different sensible elements and materials are employed: particular care must be placed in evaluating the actual geometrical configuration of the reflectors operating in the space environment, since very limited distortions of the designed layout can produce severe effects on the quality of the signal both received and transmitted, especially for antennas operating at high frequencies. The effects of thermal loads due to direct sunlight exposition and to earth and moon albedo can be easily taken into account employing the standard methods of structural analysis: on the other hand the thermal cycling and the exposition to the vacuum environment produce a long term damage accumulation which affects the whole structure. The typical effects of the just mentioned exposition are the outgassing of polymeric materials and the contamination of the exposed surface, which can affect sensibly the thermo-mechanical properties of the materials themselves and, therefore, the structural global response. The main aim of the present paper is to evaluate the synergistic effects of thermal cycling and of the exposition to high vacuum environment on an innovative antenna developed by Alenia Spazio S.p.a.: to this purpose, both an experimental and numerical research activity has been developed. A complete prototype of the antenna has been exposed to the space environment simulated by the SAS facility: this latter is constituted by an high vacuum chamber, equipped by

Effects of Microstructural Variability on Thermo-Mechanical Properties of a Woven Ceramic Matrix Composite

Science.gov (United States)

Goldsmith, Marlana B.; Sankar, Bhavani V.; Haftka, Raphael T.; Goldberg, Robert K.

2013-01-01

The objectives of this paper include identifying important architectural parameters that describe the SiC/SiC five-harness satin weave composite and characterizing the statistical distributions and correlations of those parameters from photomicrographs of various cross sections. In addition, realistic artificial cross sections of a 2D representative volume element (RVE) are generated reflecting the variability found in the photomicrographs, which are used to determine the effects of architectural variability on the thermo-mechanical properties. Lastly, preliminary information is obtained on the sensitivity of thermo-mechanical properties to architectural variations. Finite element analysis is used in combination with a response surface and it is shown that the present method is effective in determining the effects of architectural variability on thermo-mechanical properties.

Theoretical analysis and experimental investigation on performance of the thermal shield of accelerator cryomodules by thermo-siphon cooling of liquid nitrogen

Science.gov (United States)

Datta, T. S.; Kar, S.; Kumar, M.; Choudhury, A.; Chacko, J.; Antony, J.; Babu, S.; Sahu, S. K.

2015-12-01

Five beam line cryomodules with total 27 superconducting Radio Frequency (RF) cavities are installed and commissioned at IUAC to enhance the energy of heavy ion from 15 UD Pelletron. To reduce the heat load at 4.2 K, liquid nitrogen (LN2) cooled intermediate thermal shield is used for all these cryomodules. For three linac cryomodules, concept of forced flow LN2 cooling is used and for superbuncher and rebuncher, thermo-siphon cooling is incorporated. It is noticed that the shield temperature of superbuncher varies from 90 K to 110 K with respect to liquid nitrogen level. The temperature difference can't be explained by using the basic concept of thermo-siphon with the heat load on up flow line. A simple thermo-siphon experimental set up is developed to simulate the thermal shield temperature profile. Mass flow rate of liquid nitrogen is measured with different heat load on up flow line for different liquid levels. It is noticed that small amount of heat load on down flow line have a significant effect on mass flow rate. The present paper will be investigating the data generated from the thermosiphon experimental set up and a theoretical analysis will be presented here to validate the measured temperature profile of the cryomodule shield.

Three-dimensional thermo-elastic analysis of a functionally graded cylindrical shell with piezoelectric layers by differential quadrature method

Energy Technology Data Exchange (ETDEWEB)

Alashti, R. Akbari, E-mail: raalashti@nit.ac.ir [Mechanical Engineering Department, Babol University of Technology, P.O. Box 484, Shariati Avenue, Babol (Iran, Islamic Republic of); Khorsand, M. [Mechanical Engineering Department, Babol University of Technology, P.O. Box 484, Shariati Avenue, Babol (Iran, Islamic Republic of)

2011-05-15

Three-dimensional thermo-elastic analysis of a functionally graded cylindrical shell with piezoelectric layers under the effect of asymmetric thermo-electro-mechanical loads is carried out. Numerical results of displacement, stress and thermal fields are obtained using two versions of the differential quadrature methods, namely polynomial and Fourier quadrature methods. Material properties of the shell are assumed to be graded in the radial direction according to a power law but the Poisson's ratio is assumed to be constant. Shells are considered to be under the effect of the pressure loading in the form of cosine and ring pressure loads, electric potentials and temperature fields. Numerical results for various boundary conditions are obtained and the effects of the thickness of piezoelectric layers, grading index of material properties and the ratio of the thickness to the radius of the shell on these results is presented. - Highlights: > A numerical study of an FGM cylindrical shell with piezoelectric layers is made. > Governing equations are solved by two versions of differential quadrature methods. > The effect of layers thickness, grading index and geometrical ratios is presented.

Three-dimensional thermo-elastic analysis of a functionally graded cylindrical shell with piezoelectric layers by differential quadrature method

International Nuclear Information System (INIS)

Alashti, R. Akbari; Khorsand, M.

2011-01-01

Three-dimensional thermo-elastic analysis of a functionally graded cylindrical shell with piezoelectric layers under the effect of asymmetric thermo-electro-mechanical loads is carried out. Numerical results of displacement, stress and thermal fields are obtained using two versions of the differential quadrature methods, namely polynomial and Fourier quadrature methods. Material properties of the shell are assumed to be graded in the radial direction according to a power law but the Poisson's ratio is assumed to be constant. Shells are considered to be under the effect of the pressure loading in the form of cosine and ring pressure loads, electric potentials and temperature fields. Numerical results for various boundary conditions are obtained and the effects of the thickness of piezoelectric layers, grading index of material properties and the ratio of the thickness to the radius of the shell on these results is presented. - Highlights: → A numerical study of an FGM cylindrical shell with piezoelectric layers is made. → Governing equations are solved by two versions of differential quadrature methods. → The effect of layers thickness, grading index and geometrical ratios is presented.

Study on thermo-hydraulic behavior during reflood phase of a PWR-LOCA

International Nuclear Information System (INIS)

Sugimoto, Jun

1989-01-01

This paper describes thermo-hydraulic behavior during the reflood phase in a postulated large-break loss-of-coolant accident (LOCA) of a PWR. In order to better predict the reflood transient in a nuclear safety analysis specific analytical models have been developed for, saturated film boiling heat transfer in inverted slung flow, the effect of grid spacers on core thermo-hydraulics, overall system thermo-hydraulic behavior, and the thermal response similarity between nuclear fuel rods and simulated rods. A heat transfer correlation has been newly developed for saturated film boiling based on a 4 x 4-rod experiment conducted at JAERI. The correlation provides a good agreement with existing experiments except in the vicinity of grid spacer locations. An analytical model has then been developed addressing the effect of grid spacers. The thermo-hydraulic behavior near the grid spacers was found to be predicted well with this model by considering the breakup of droplets in dispersed flow and water accumulation above the grid spacers in inverted slung flow. A system analysis code has been developed which couples the one-dimensional core and multi-loop primary system component models. It provides fairly good agreement with system behavior obtained in a large-scale integral reflood experiment with active primary system components. An analytical model for the radial temperature distribution in a rod has been developed and verified with data from existing experiments. It was found that a nuclear fuel rod has a lower cladding temperature and an earlier quench time than an electrically heated rod in a typical reflood condition. (author)

Three years of high precision gravity measurements at the gravimetric station of Brasimone - Italy

Directory of Open Access Journals (Sweden)

G. Casula

1998-06-01

Full Text Available From August 1995 up to now, at the Enea Research Center of Brasimone, in the Italian Apennines between Bologna and Florence (Italy: 44º07'N, 11º.07'E, 890 m height, the superconducting gravimeter GWR model TT70 number T015 has been continuously recording the variation of the local gravity field, in the frame of the Global Geodynamics Project. The gravimetric laboratory, being a room of the disused nuclear power plant of Brasimone, is a very stable site, free from noise due to human activities. Data blocks of several months of continuous gravity records have been collected over a time span of three years, together with the meteorological data. The gravimeter has been calibrated at relative accuracy better than 0.3% with the aid of a mobile mass system, by imposed perturbations of the local gravity field and recording the gravimeter response. The results of this calibration technique were checked by two comparison experiments with absolute gravimeters performed during this period: the first, in May 1994 with the aid of the symmetrical rise and fall gravimeter of the Institute of Metrology Colonnetti of Turin, and the second in October 1997 involving an FG5 absolute gravimeter of the Institute de Physique du Globe of Strasbourg. The gravimeter signal was analysed to compute a high precision tidal model for Brasimone site. Starting from a set of gravimetric and atmospheric pressure data of high quality, relative to 46 months of observation, we performed the tidal analysis using Eterna 3.2 software to compute amplitudes, gravimetric factors and phases of the main waves of the Tamura catalogue. Finally a comparison experiment between two of the STS-1/VBB broadband seismometers of the MedNet project network and the gravity records relative to the Balleny Islands earthquake (March 25, 1998 were analysed to look for evidence of normal modes due to the free oscillations of the Earth.

Introduction to thermo-fluids systems design

CERN Document Server

Garcia McDonald, André

2012-01-01

A fully comprehensive guide to thermal systems design covering fluid dynamics, thermodynamics, heat transfer and thermodynamic power cycles Bridging the gap between the fundamental concepts of fluid mechanics, heat transfer and thermodynamics, and the practical design of thermo-fluids components and systems, this textbook focuses on the design of internal fluid flow systems, coiled heat exchangers and performance analysis of power plant systems. The topics are arranged so that each builds upon the previous chapter to convey to the reader that topics are not stand-alone i

Investigation research on the evaluation of a coupled thermo-hydro-mechanical-chemical phenomena. 2. Result report

International Nuclear Information System (INIS)

Ishihara, Yoshinao; Ito Takaya; Chijimatsu, Masakazu; Amemiya, Kiyoshi; Shiozaki, Isao; Neyama, Atsushi; Tanaka, Yumiko

2003-02-01

In order to realize a coupling analysis in the near field of the geological disposal system, the coupling analysis code on the thermo-hydro-mechanical-chemical phenomena by THAMES, Dtransu and phreeqe60, which are existing analysis code, is developed in this study. And we carried out the case analysis on the thermo-hydro-mechanical-chemical phenomena by this code. (1) We have developed coupling analysis system to manage coupling analysis and to control coupling process automatically for THAMES (thermo-hydro-mechanical analysis code), Dtransu (mass transport analysis code) and phreeqe60 (geochemical analysis code). (2) Some supporting module, which includes transfer of dissolution concentration and total concentration (dissolution + precipitation concentration), was prepared as a functional expansion. And in order to treat multi-chemical elements, we have codified mass transport analysis code. (3) We have prepared hydraulic conductivity module of buffer material depending on change of dry density due to chemical equilibrium (dissolution and precipitation of minerals), and change of concentration of NaCl solutions. After THAMES, Dtransu, phreeqe60 and hydraulic conductivity module were installed in the COUPLYS, sensitivity analysis was carried out to check basic operation. (4) In order to confirm the applicability of the developed THMC analysis code, we have carried out case analysis on 1-dimensional and 3-dimensional model which including vitrified waste, over-pack, buffer material and rock in the HLW near-field. (author)

Contrastive Numerical Investigations on Thermo-Structural Behaviors in Mass Concrete with Various Cements

Science.gov (United States)

Zhou, Wei; Feng, Chuqiao; Liu, Xinghong; Liu, Shuhua; Zhang, Chao; Yuan, Wei

2016-01-01

This work is a contrastive investigation of numerical simulations to improve the comprehension of thermo-structural coupled phenomena of mass concrete structures during construction. The finite element (FE) analysis of thermo-structural behaviors is used to investigate the applicability of supersulfated cement (SSC) in mass concrete structures. A multi-scale framework based on a homogenization scheme is adopted in the parameter studies to describe the nonlinear concrete behaviors. Based on the experimental data of hydration heat evolution rate and quantity of SSC and fly ash Portland cement, the hydration properties of various cements are studied. Simulations are run on a concrete dam section with a conventional method and a chemo-thermo-mechanical coupled method. The results show that SSC is more suitable for mass concrete structures from the standpoint of temperature control and crack prevention. PMID:28773517

Modeling and analysis of waves in a heat conducting thermo-elastic plate of elliptical shape

Directory of Open Access Journals (Sweden)

R. Selvamani

Full Text Available Wave propagation in heat conducting thermo elastic plate of elliptical cross-section is studied using the Fourier expansion collocation method based on Suhubi's generalized theory. The equations of motion based on two-dimensional theory of elasticity is applied under the plane strain assumption of generalized thermo elastic plate of elliptical cross-sections composed of homogeneous isotropic material. The frequency equations are obtained by using the boundary conditions along outer and inner surface of elliptical cross-sectional plate using Fourier expansion collocation method. The computed non-dimensional frequency, velocity and quality factor are plotted in dispersion curves for longitudinal and flexural (symmetric and antisymmetric modes of vibrations.

Preparation, optical properties and 1 Multiplication-Sign 2 polymeric thermo-optic switch of polyurethane-urea

Energy Technology Data Exchange (ETDEWEB)

Qiu, Fengxian, E-mail: fxqiuchem@163.com [School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013 (China); Cao, Zhijuan [School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013 (China); Cao, Guorong; Guan, Yijun; Shen, Qiang [Department of Physics, Jiangsu University, Zhenjiang 212013 (China); Wang, Qing; Yang, Dongya [School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013 (China)

2012-08-15

A polyurethane-urea (PUU) containing azo chromophore, polyether polyol (NJ-220) and isophorone diisocyanate (IPDI) was prepared. The structure, thermal property and mechanical properties of obtained PUU were characterized and measured by the UV-visible spectroscopy, Fourier transform infrared, Differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The refractive index (n) of PUU was determined at different temperature and wavelength (532 nm, 650 nm and 850 nm) using attenuated total reflection (ATR) technique, and the thermo-optic coefficients (dn/dT) were -5.3643 Multiplication-Sign 10{sup -4} Degree-Sign C{sup -1}, -5.2500 Multiplication-Sign 10{sup -4} Degree-Sign C{sup -1} and -4.6071 Multiplication-Sign 10{sup -4} Degree-Sign C{sup -1}, respectively. Using the Charge Coupled Device (CCD) digital imaging devices, transmission loss of PUU was measured and the value was 0.659 dB cm{sup -1}. A 1 Multiplication-Sign 2 polymeric thermo-optic switch based on the thermo-optic effect of PUU film was proposed. With branching angle of 0.143 Degree-Sign and the finite difference beam propagation method (FD-BPM), the polymeric thermo-optic switch was simulated. The result showed that the power consumption of the thermo-optic switch could be only 0.72 mW, and the response time of the switch was about 3.0 ms. The obtained PUU has a significant improvement in reducing the power consumption and response time compared with those of the normal polymeric thermo-optic switches. -- Highlights: Black-Right-Pointing-Pointer Preparation and structural characterization of a novel azo polyurethane-urea (PUU). Black-Right-Pointing-Pointer The mechanical performance and thermal property of PUU film. Black-Right-Pointing-Pointer The thermo-optic property, transmission loss and dispersion property of PUU. Black-Right-Pointing-Pointer Proposed a new 1 Multiplication-Sign 2 polymeric thermo-optic switch.

Humidity and Gravimetric Equivalency Adjustments for Nephelometer-Based Particulate Matter Measurements of Emissions from Solid Biomass Fuel Use in Cookstoves

Science.gov (United States)

Soneja, Sutyajeet; Chen, Chen; Tielsch, James M.; Katz, Joanne; Zeger, Scott L.; Checkley, William; Curriero, Frank C.; Breysse, Patrick N.

2014-01-01

Great uncertainty exists around indoor biomass burning exposure-disease relationships due to lack of detailed exposure data in large health outcome studies. Passive nephelometers can be used to estimate high particulate matter (PM) concentrations during cooking in low resource environments. Since passive nephelometers do not have a collection filter they are not subject to sampler overload. Nephelometric concentration readings can be biased due to particle growth in high humid environments and differences in compositional and size dependent aerosol characteristics. This paper explores relative humidity (RH) and gravimetric equivalency adjustment approaches to be used for the pDR-1000 used to assess indoor PM concentrations for a cookstove intervention trial in Nepal. Three approaches to humidity adjustment performed equivalently (similar root mean squared error). For gravimetric conversion, the new linear regression equation with log-transformed variables performed better than the traditional linear equation. In addition, gravimetric conversion equations utilizing a spline or quadratic term were examined. We propose a humidity adjustment equation encompassing the entire RH range instead of adjusting for RH above an arbitrary 60% threshold. Furthermore, we propose new integrated RH and gravimetric conversion methods because they have one response variable (gravimetric PM2.5 concentration), do not contain an RH threshold, and is straightforward. PMID:24950062

Humidity and gravimetric equivalency adjustments for nephelometer-based particulate matter measurements of emissions from solid biomass fuel use in cookstoves.

Science.gov (United States)

Soneja, Sutyajeet; Chen, Chen; Tielsch, James M; Katz, Joanne; Zeger, Scott L; Checkley, William; Curriero, Frank C; Breysse, Patrick N

2014-06-19

Great uncertainty exists around indoor biomass burning exposure-disease relationships due to lack of detailed exposure data in large health outcome studies. Passive nephelometers can be used to estimate high particulate matter (PM) concentrations during cooking in low resource environments. Since passive nephelometers do not have a collection filter they are not subject to sampler overload. Nephelometric concentration readings can be biased due to particle growth in high humid environments and differences in compositional and size dependent aerosol characteristics. This paper explores relative humidity (RH) and gravimetric equivalency adjustment approaches to be used for the pDR-1000 used to assess indoor PM concentrations for a cookstove intervention trial in Nepal. Three approaches to humidity adjustment performed equivalently (similar root mean squared error). For gravimetric conversion, the new linear regression equation with log-transformed variables performed better than the traditional linear equation. In addition, gravimetric conversion equations utilizing a spline or quadratic term were examined. We propose a humidity adjustment equation encompassing the entire RH range instead of adjusting for RH above an arbitrary 60% threshold. Furthermore, we propose new integrated RH and gravimetric conversion methods because they have one response variable (gravimetric PM2.5 concentration), do not contain an RH threshold, and is straightforward.

Visual estimation versus gravimetric measurement of postpartum blood loss: a prospective cohort study.

Science.gov (United States)

Al Kadri, Hanan M F; Al Anazi, Bedayah K; Tamim, Hani M

2011-06-01

One of the major problems in international literature is how to measure postpartum blood loss with accuracy. We aimed in this research to assess the accuracy of visual estimation of postpartum blood loss (by each of two main health-care providers) compared with the gravimetric calculation method. We carried out a prospective cohort study at King Abdulaziz Medical City, Riyadh, Saudi Arabia between 1 November 2009 and 31 December 2009. All women who were admitted to labor and delivery suite and delivered vaginally were included in the study. Postpartum blood loss was visually estimated by the attending physician and obstetrics nurse and then objectively calculated by a gravimetric machine. Comparison between the three methods of blood loss calculation was carried out. A total of 150 patients were included in this study. There was a significant difference between the gravimetric calculated blood loss and both health-care providers' estimation with a tendency to underestimate the loss by about 30%. The background and seniority of the assessing health-care provider did not affect the accuracy of the estimation. The corrected incidence of postpartum hemorrhage in Saudi Arabia was found to be 1.47%. Health-care providers tend to underestimate the volume of postpartum blood loss by about 30%. Training and continuous auditing of the diagnosis of postpartum hemorrhage is needed to avoid missing cases and thus preventing associated morbidity and mortality.

Library of neutron cross sections of the Thermos code; Biblioteca de secciones eficaces de neutrones del codigo Thermos

Energy Technology Data Exchange (ETDEWEB)

Alonso V, G; Hernandez L, H [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico)

1991-10-15

The present work is the complement of the IT.SN/DFR-017 report in which the structure and the generation of the library of the Thermos code is described. In this report the comparison among the values of the cross sections that has the current library of the Thermos code and those generated by means of the ENDF-B/NJOY it is shown. (Author)

On the general theory of thermo-elastic friction

NARCIS (Netherlands)

Alblas, J.B.

1961-01-01

A theory of the thermo-elastic dissipation in vibrating bodies is developed, starting from the three-dimensional thermo-elastic equations. After a discussion of the basic thermodynamical foundations, some general considerations on the problem of the conversion of mechanical energy into heat are

Thermo-physical properties of silica gel for adsorption desalination cycle

KAUST Repository

Thu, Kyaw; Chakraborty, Anutosh; Saha, Bidyut Baran; Ng, Kim Choon

2013-01-01

Thermo-physical properties, surface characteristics and water vapor uptake capacity are key parameters in the selection of adsorbent for an adsorption desalination (AD) cycle. In the AD cycles, silica gel is used as adsorbent due to their high water vapor uptake capacity, reliability, repeatability and inexpensiveness as compared to other adsorbents. Three types of commercially available silica gels (Type-RD 2560,Type-A5BW and Type-A++) are investigated using a surface characteristic analyzer and their thermo-physical properties are evaluated using several analysis methods. The instrument used in this investigation employs the static volumetric method with liquid Nitrogen at 77 K as the filing fluid. The surface area of each adsorbent is studied using Brunauer-Emmett-Teller (BET) method whilst the pore size distribution (PSD) analysis is conducted with the Non-Local Density Functional Theory (NLDFT). It is observed that the Type-A++ silica gel (granular type) possesses the highest surface area of 863.6 m2/g amongst the three parent silica gels studied. It has a two-maxima or bimodal distribution pattern where the pore diameters are distributed mostly between 10 Å and 30 Å. Water vapor uptake capacity of silica gels are studied with water vapor dosage apparatus and the results show that the Type-A++ silica gel exhibits a highest equilibrium uptake at 537 cm3/g. These thermo-physical properties are essential for the design and the numerical simulation of AD cycles. © 2012 Published by Elsevier Ltd.

Thermo-physical properties of silica gel for adsorption desalination cycle

KAUST Repository

Thu, Kyaw

2013-02-01

Thermo-physical properties, surface characteristics and water vapor uptake capacity are key parameters in the selection of adsorbent for an adsorption desalination (AD) cycle. In the AD cycles, silica gel is used as adsorbent due to their high water vapor uptake capacity, reliability, repeatability and inexpensiveness as compared to other adsorbents. Three types of commercially available silica gels (Type-RD 2560,Type-A5BW and Type-A++) are investigated using a surface characteristic analyzer and their thermo-physical properties are evaluated using several analysis methods. The instrument used in this investigation employs the static volumetric method with liquid Nitrogen at 77 K as the filing fluid. The surface area of each adsorbent is studied using Brunauer-Emmett-Teller (BET) method whilst the pore size distribution (PSD) analysis is conducted with the Non-Local Density Functional Theory (NLDFT). It is observed that the Type-A++ silica gel (granular type) possesses the highest surface area of 863.6 m2/g amongst the three parent silica gels studied. It has a two-maxima or bimodal distribution pattern where the pore diameters are distributed mostly between 10 Å and 30 Å. Water vapor uptake capacity of silica gels are studied with water vapor dosage apparatus and the results show that the Type-A++ silica gel exhibits a highest equilibrium uptake at 537 cm3/g. These thermo-physical properties are essential for the design and the numerical simulation of AD cycles. © 2012 Published by Elsevier Ltd.

Laser thermal effect on silicon nitride ceramic based on thermo-chemical reaction with temperature-dependent thermo-physical parameters

International Nuclear Information System (INIS)

Pan, A.F.; Wang, W.J.; Mei, X.S.; Wang, K.D.; Zhao, W.Q.; Li, T.Q.

2016-01-01

Highlights: • A two-dimensional thermo-chemical reaction model is creatively built. • Thermal conductivity and heat capacity of β-Si_3N_4 are computed accurately. • The appropriate thermo-chemical reaction rate is fitted and reaction element length is set to assure the constringency. • The deepest ablated position was not the center of the ablated area due to plasma absorption. • The simulation results demonstrate the thermo-chemical process cant be simplified to be physical phase transition. - Abstract: In this study, a two-dimensional thermo-chemical reaction model with temperature-dependent thermo-physical parameters on Si_3N_4 with 10 ns laser was developed to investigate the ablated size, volume and surface morphology after single pulse. For model parameters, thermal conductivity and heat capacity of β-Si_3N_4 were obtained from first-principles calculations. Thermal-chemical reaction rate was fitted by collision theory, and then, reaction element length was deduced using the relationship between reaction rate and temperature distribution. Furthermore, plasma absorption related to energy loss was approximated as a function of electron concentration in Si_3N_4. It turned out that theoretical ablated volume and radius increased and then remained constant with increasing laser energy, and the maximum ablated depth was not in the center of the ablated zone. Moreover, the surface maximum temperature of Si_3N_4 was verified to be above 3000 K within pulse duration, and it was much higher than its thermal decomposition temperature of 1800 K, which indicated that Si_3N_4 was not ablated directly above the thermal decomposition temperature. Meanwhile, the single pulse ablation of Si_3N_4 was performed at different powers using a TEM_0_0 10 ns pulse Nd:YAG laser to validate the model. The model showed a satisfactory consistence between the experimental data and numerical predictions, presenting a new modeling technology that may significantly increase the

Decomposition mechanism of melamine borate in pyrolytic and thermo-oxidative conditions

Energy Technology Data Exchange (ETDEWEB)

Hoffendahl, Carmen; Duquesne, Sophie; Fontaine, Gaëlle; Bourbigot, Serge, E-mail: serge.bourbigot@ensc-lille.fr

2014-08-20

Highlights: • Decomposition of melamine borate in pyrolytic and thermo-oxidative conditions was investigated. • With increasing temperature, orthoboric acid forms boron oxide releasing water. • Melamine decomposes evolving melamine, ammonia and other fragments. • Boron oxide is transformed into boron nitride and boron nitride-oxide structures through presence of ammonia. - Abstract: Decomposition mechanism of melamine borate (MB) in pyrolytic and thermo-oxidative conditions is investigated in the condensed and gas phases using solid state NMR ({sup 13}C and {sup 11}B), X-ray photoelectron spectroscopy (XPS), pyrolysis-gas chromatography–mass spectrometry (py-GCMS) and thermogravimetric analysis coupled with a Fourier transform infrared spectrometer (TGA–FTIR). It is evidenced that orthoboric acid dehydrates to metaboric and then to boron oxide. The melamine is partially sublimated. At the same time, melamine condensates, i.e., melem and melon are formed. Melon is only formed in thermo-oxidative conditions. At higher temperature, melem and melon decompose releasing ammonia which reacts with the boron oxide to form boron nitride (BN) and BNO structures.

Crustal thickness of Antarctica estimated using data from gravimetric satellites

Directory of Open Access Journals (Sweden)

M. Llubes

2018-04-01

Full Text Available Computing a better crustal thickness model is still a necessary improvement in Antarctica. In this remote continent where almost all the bedrock is covered by the ice sheet, seismic investigations do not reach a sufficient spatial resolution for geological and geophysical purposes. Here, we present a global map of Antarctic crustal thickness computed from space gravity observations. The DIR5 gravity field model, built from GOCE and GRACE gravimetric data, is inverted with the Parker–Oldenburg iterative algorithm. The BEDMAP products are used to estimate the gravity effect of the ice and the rocky surface. Our result is compared to crustal thickness calculated from seismological studies and the CRUST1.0 and AN1 models. Although the CRUST1.0 model shows a very good agreement with ours, its spatial resolution is larger than the one we obtain with gravimetric data. Finally, we compute a model in which the crust–mantle density contrast is adjusted to fit the Moho depth from the CRUST1.0 model. In East Antarctica, the resulting density contrast clearly shows higher values than in West Antarctica.

Wigner Function of Thermo-Invariant Coherent State

International Nuclear Information System (INIS)

Xue-Fen, Xu; Shi-Qun, Zhu

2008-01-01

By using the thermal Winger operator of thermo-field dynamics in the coherent thermal state |ξ) representation and the technique of integration within an ordered product of operators, the Wigner function of the thermo-invariant coherent state |z,ℵ> is derived. The nonclassical properties of state |z,ℵ> is discussed based on the negativity of the Wigner function. (general)

Thermo-driven microcrawlers fabricated via a microfluidic approach

International Nuclear Information System (INIS)

Wang Wei; Yao Chen; Zhang Maojie; Ju Xiaojie; Xie Rui; Chu Liangyin

2013-01-01

A novel thermo-driven microcrawler that can transform thermal stimuli into directional mechanical motion is developed by a simple microfluidic approach together with emulsion-template synthesis. The microcrawler is designed with a thermo-responsive poly(N-isopropylacrylamide) (PNIPAM) hydrogel body and a bell-like structure with an eccentric cavity. The asymmetric shrinking–swelling circulation of the microcrawlers enables a thermo-driven locomotion responding to repeated temperature changes, which provides a novel model with symmetry breaking principle for designing biomimetic soft microrobots. The microfluidic approach offers a novel and promising platform for design and fabrication of biomimetic soft microrobots. (paper)

Thermo-cleavable polymers: Materials with enhanced photochemical stability

DEFF Research Database (Denmark)

Manceau, Matthieu; Petersen, Martin Helgesen; Krebs, Frederik C

2010-01-01

Photochemical stability of three thermo-cleavable polymers was investigated as thin films under atmospheric conditions. A significant increase in lifetime was observed once the side-chain was cleaved emphasizing the detrimental effect of solubilizing groups on the photochemical stability of conju......Photochemical stability of three thermo-cleavable polymers was investigated as thin films under atmospheric conditions. A significant increase in lifetime was observed once the side-chain was cleaved emphasizing the detrimental effect of solubilizing groups on the photochemical stability...... of conjugated polymers. In addition to their ease of processing, thermo-cleavable polymers thus also offer a greater intrinsic stability under illumination....

Thermo-mechanically coupled fracture analysis of shape memory alloys using the extended finite element method

Science.gov (United States)

Hatefi Ardakani, S.; Ahmadian, H.; Mohammadi, S.

2015-04-01

In this paper, the extended finite element method is used for fracture analysis of shape memory alloys for both cases of super elastic and shape memory effects. Heat generation during the forward and reverse phase transformations can lead to temperature variation in the material because of strong thermo-mechanical coupling, which significantly influences the SMA mechanical behavior. First, the stationary crack mode is studied and the effects of loading rate on material behavior in the crack tip are examined. Then, the crack propagation analysis is performed in the presence of an initial crack by adopting a weighted averaging criterion, where the direction of crack propagation is determined by weighted averaging of effective stresses at all the integration points in the vicinity of the crack tip. Finally, several numerical examples are analyzed and the obtained results are compared with the available reference results.

Comparison of neutron scattering, gravimetric and tensiometric methods for measuring soil water content in the field

International Nuclear Information System (INIS)

Jat, R.L.; Das, D.K.; Naskar, G.C.

1975-01-01

Water content of a sandy clay loam soil was measured by neutron scattering, gravimetric and tensiometric methods. Tensiometric measurement based on laboratory moisture retention curve gave comparatively higher moisture content than those obtained by other methods. No significant differences were observed among neutron meter, gravimetric and tensiometric measurement based on field calibration curve. Though for irrigation purposes all the methods can be used equally, use of tensiometric method with field calibration curve is suggested for easy and more accurate soil water content measurement where neutron meter is not available. (author)

Thermo-mechanical behavior of retro-reflector and resulting parallelism error of laser beams for Wendelstein 7-X interferometer

International Nuclear Information System (INIS)

Peng, X.B.; Hirsch, M.; Köppen, M.; Fellinger, J.; Bykov, V.; Schauer, F.; Vliegenthart, W.

2014-01-01

Highlights: • The criterion for thermo-mechanical design of W7-X interferometer retro-reflector. • Thermo-mechanical analysis of retro-reflector with two different methods. • The most flexible part in the retro-reflector is spring washer. • Calculation of parallelism error between the incoming and reflected laser beams. • The parallelism error is much lower than the design limit 28 arcs. - Abstract: A 10 channels interferometer will be used in the Wendelstein 7-X (W7-X) for plasma density control and density profile tracking with laser beams passing through the plasma. Due to complex shape of non-planar modular coils and divertor structure, there are no large poloidally opposite ports on the plasma vessel (PV). Therefore 10 in-vessel Corner Cube Retro-reflectors (CCRs) will be used. The CCRs are integrated in the water cooled heat shield and exposed directly to thermal loads from plasma radiation. Thermo-mechanical issues are very important for the design of the CCR because deformation and flatness as well as mutual angles of the three reflecting surfaces would affect the parallelism of the laser beams and the functionality of the interferometer. Intensive work has been done to explore a suitable design for the CCR concerning thermo-mechanical behavior. Previous studies Ye et al. (2008, 2009) and Köppen et al. (2011) focused on structural optimization to decrease thermal stress in the reflecting plates under the thermal loads, and on computation and check of curvature radii of the deformed reflecting surfaces with the design criterion that the curvature radius must be bigger than 200 m. The paper presents detailed thermo-mechanical analysis of the current improved CCR under thermal loads and bolt preloads. The results of the thermo-mechanical analysis were used for the study of the resulting parallelism error of the laser beams with newly developed and more reasonable design criterion

Thermo-mechanical behavior of retro-reflector and resulting parallelism error of laser beams for Wendelstein 7-X interferometer

Energy Technology Data Exchange (ETDEWEB)

Peng, X.B., E-mail: pengxb@ipp.ac.cn [Institute of Plasma Physics, Chinese Academy of Sciences, P.O. Box 1126, 230031 Hefei Anhui (China); Max Planck Institute for Plasma Physics, EURATOM Association, Wendelsteinstr. 1, 17491 Greifswald (Germany); Hirsch, M.; Köppen, M.; Fellinger, J.; Bykov, V.; Schauer, F. [Max Planck Institute for Plasma Physics, EURATOM Association, Wendelsteinstr. 1, 17491 Greifswald (Germany); Vliegenthart, W. [TNO, Stieltjesweg 1, P.O. Box 2600, 2628 CK Delft (Netherlands)

2014-04-15

Highlights: • The criterion for thermo-mechanical design of W7-X interferometer retro-reflector. • Thermo-mechanical analysis of retro-reflector with two different methods. • The most flexible part in the retro-reflector is spring washer. • Calculation of parallelism error between the incoming and reflected laser beams. • The parallelism error is much lower than the design limit 28 arcs. - Abstract: A 10 channels interferometer will be used in the Wendelstein 7-X (W7-X) for plasma density control and density profile tracking with laser beams passing through the plasma. Due to complex shape of non-planar modular coils and divertor structure, there are no large poloidally opposite ports on the plasma vessel (PV). Therefore 10 in-vessel Corner Cube Retro-reflectors (CCRs) will be used. The CCRs are integrated in the water cooled heat shield and exposed directly to thermal loads from plasma radiation. Thermo-mechanical issues are very important for the design of the CCR because deformation and flatness as well as mutual angles of the three reflecting surfaces would affect the parallelism of the laser beams and the functionality of the interferometer. Intensive work has been done to explore a suitable design for the CCR concerning thermo-mechanical behavior. Previous studies Ye et al. (2008, 2009) and Köppen et al. (2011) focused on structural optimization to decrease thermal stress in the reflecting plates under the thermal loads, and on computation and check of curvature radii of the deformed reflecting surfaces with the design criterion that the curvature radius must be bigger than 200 m. The paper presents detailed thermo-mechanical analysis of the current improved CCR under thermal loads and bolt preloads. The results of the thermo-mechanical analysis were used for the study of the resulting parallelism error of the laser beams with newly developed and more reasonable design criterion.

Gravimetric Model of Quasigeoid in the Area of Slovakia

Directory of Open Access Journals (Sweden)

Juraj Papčo

2005-06-01

Full Text Available The gravimetric model of quasigeoid in the area of Slovakia was determined by using the revised and homogenised gravity mapping data in the scale of 1:25 000 from the area of Slovakia, and by using the mean Bouguer gravity anomalies with the resolution of 5´x7.5´ in the area 44°<φ<56° and 12°<λ<30° from abroad and by the digital terrain model DMR-2/ERTS89 with the resolution 3“ in the ellipsoidal latitude and 5“ in the ellipsoidal longitude from the area of Slovakia and the digital terrain model GTOPO30 with the resolution of 30“ in the ellipsoidal latitude and 30“ in the ellipsoidal longitude from abroad. The global part of the height anomaly was determined from the global geopotential model EGM96. The residual part of the height anomaly was determined by the Stokes integral formula. For the solution of the Stokes integra,l the Fast Fourier Transformation method in the spherical approximation was used. The gravimetric quasigeoid was tested by the GPS/levelling method using 46 points distributed on the area of Slovakia. The systematic trend of differences between height anomalies was rejected by the surface polynomial of second degree with 6 coefficients. The standard deviation after removing a systematic trend was 0.017 m

Two scale damage model and related numerical issues for thermo-mechanical high cycle fatigue

International Nuclear Information System (INIS)

Desmorat, R.; Kane, A.; Seyedi, M.; Sermage, J.P.

2007-01-01

On the idea that fatigue damage is localized at the microscopic scale, a scale smaller than the mesoscopic one of the Representative Volume Element (RVE), a three-dimensional two scale damage model has been proposed for High Cycle Fatigue applications. It is extended here to aniso-thermal cases and then to thermo-mechanical fatigue. The modeling consists in the micro-mechanics analysis of a weak micro-inclusion subjected to plasticity and damage embedded in an elastic meso-element (the RVE of continuum mechanics). The consideration of plasticity coupled with damage equations at micro-scale, altogether with Eshelby-Kroner localization law, allows to compute the value of microscopic damage up to failure for any kind of loading, 1D or 3D, cyclic or random, isothermal or aniso-thermal, mechanical, thermal or thermo-mechanical. A robust numerical scheme is proposed in order to make the computations fast. A post-processor for damage and fatigue (DAMAGE-2005) has been developed. It applies to complex thermo-mechanical loadings. Examples of the representation by the two scale damage model of physical phenomena related to High Cycle Fatigue are given such as the mean stress effect, the non-linear accumulation of damage. Examples of thermal and thermo-mechanical fatigue as well as complex applications on real size testing structure subjected to thermo-mechanical fatigue are detailed. (authors)

Thermal treatment investigation of natural lizardite at the atmospheric pressure, based on XRD and differential thermal analysis/thermal gravimetric analysis methods

International Nuclear Information System (INIS)

Dabiri, R.; Karimi Shahraki, B.; Mollaei, H.; Ghaffari, M.

2009-01-01

Determination of stability limits, mineralogical changes and thermal reaction of serpentine minerals are very important for the investigation of magmatism, mechanism and depth of plates of subduction. During the subduction process, serpentine (Lizardite) minerals will release their water due to thermal reactions. This dehydration can play an important role in volcanism processes related to the subduction, In this study, serpentine minerals (Lizardite) collected from the Neyriz Ophiolite Complex were dehydrated under the constant atmospheric pressure. These mineralogical changes were determined by X-Ray diffraction and differential thermal analysis-thermal gravimetric analyses methods. This study shows natural lizardites that heated for about one hour is stable up to 550 d eg C . Dehydration reactions on lizardite started at approximately between 100 to 150 d eg C and dehydroxylation reactions started at approximately 550-690 d eg C . As a result of thermal reaction, the decomposition of lizardite will take place and then changes in to olivine (forsterite). Crystallization of olivine (forsterite) will start at 600 d eg C . This mineral is stable up to 700 d eg C and then crystallization of enstatite will start at 700 d eg C . During this dehydration and crystallization reaction, amorphous processes will start at 600 d eg C and some amount water and silica will release.

Activated carbon from thermo-compressed wood and other lignocellulosic precursors

Directory of Open Access Journals (Sweden)

Capart, R.

2007-05-01

Full Text Available The effects of thermo-compression on the physical properties such as bulk density, mass yield, surface area, and also adsorption capacity of activated carbon were studied. The activated carbon samples were prepared from thermo-compressed and virgin fir-wood by two methods, a physical activation with CO2 and a chemical activation with KOH. A preliminary thermo-compression method seems an easy way to confer to a tender wood a bulk density almost three times larger than its initial density. Thermo-compression increased yield regardless of the mode of activation. The physical activation caused structural alteration, which enhanced the enlargement of micropores and even their degradation, leading to the formation of mesopores. Chemical activation conferred to activated carbon a heterogeneous and exclusively microporous nature. Moreover, when coupled to chemical activation, thermo-compression resulted in a satisfactory yield (23%, a high surface area (>1700 m2.g-1, and a good adsorption capacity for two model pollutants in aqueous solution: methylene blue and phenol. Activated carbon prepared from thermo-compressed wood exhibited a higher adsorption capacity for both the pollutants than did a commercial activated carbon.

Thermo-emf of cermet films based on rare earth borides

International Nuclear Information System (INIS)

Islamgaliev, R.K.; Zyrin, A.V.; Shulishova, O.I.; Shcherbak, I.A

1987-01-01

Thermo-emf and electric conductivity of granulated films which contain a solid solution of europium and praseodymium borides Eu 0.5 Pr 0.5 B 6 as a conducting phase, and glass-crystal binder on the base of alummomagnesial fluosilicates as a dielectric phase are studied within the temperature range of 100-1100 K. Thermo-emf of films has a negative sign within the temperature range of 100-500 K and does not exceed 5 μkV/K according to the absolute value which is close to the value of the conducting phase thermo-emf. A negative sign and a small value of thermo-emf are indicative of the charge transfer in granulated films by electrons. Contribution of each of the components into the general thermo-emf is different at high temperatures in different temperature ranges and depends on the individual physico-chemical properties of the used materials

Structural features of the southern Tulum Fault System, western central Argentina, through gravimetric data and geomorphologic analyses

Science.gov (United States)

Rodríguez, Aixa I.; Christiansen, Rodolfo O.; Suvires, Graciela M.; Lince Klinger, Federico; Martinez, M. Patricia

2016-12-01

A gravimetric analysis over the Tulum Valley was made. This data was used to reveal the structural setting of the Tulum Fault System situated in the southeastern part of San Juan province in the arid western part of Argentina. This system is the boundary between two geological provinces, the eastern Precordillera Oriental and the Sierras Pampeanas Occidentales. Gravity data was processed using upward continuation and vertical derivative filters and all the results were compared with the geomorphological and the drainage systems maps of the area. Our assessment confirms the presence of two structures in the Pampeano basement with positive anomalies similar to those found in Valdivia and Barboza hills, two important depocenters with low gravimetric gradients separated by a zone with higher gravity anomalies than the depocenters to the east and west. In view of this, a structural map is proposed for the area. This system is important not only because it is the boundary between two geological provinces and has significance regarding regional tectonic issues but also because it controls the surface drainage, soils distribution and groundwater flow of the Tulum basin conditioning the land use distribution.

Thermo-Chemical Conversion of Microwave Activated Biomass Mixtures

Science.gov (United States)

Barmina, I.; Kolmickovs, A.; Valdmanis, R.; Vostrikovs, S.; Zake, M.

2018-05-01

Thermo-chemical conversion of microwave activated wheat straw mixtures with wood or peat pellets is studied experimentally with the aim to provide more effective application of wheat straw for heat energy production. Microwave pre-processing of straw pellets is used to provide a partial decomposition of the main constituents of straw and to activate the thermo-chemical conversion of wheat straw mixtures with wood or peat pellets. The experimental study includes complex measurements of the elemental composition of biomass pellets (wheat straw, wood, peat), DTG analysis of their thermal degradation, FTIR analysis of the composition of combustible volatiles entering the combustor, the flame temperature, the heat output of the device and composition of the products by comparing these characteristics for mixtures with unprocessed and mw pre-treated straw pellets. The results of experimental study confirm that mw pre-processing of straw activates the thermal decomposition of mixtures providing enhanced formation of combustible volatiles. This leads to improvement of the combustion conditions in the flame reaction zone, completing thus the combustion of volatiles, increasing the flame temperature, the heat output from the device, the produced heat energy per mass of burned mixture and decreasing at the same time the mass fraction of unburned volatiles in the products.

Precision gravimetric survey at the conditions of urban agglomerations

Science.gov (United States)

Sokolova, Tatiana; Lygin, Ivan; Fadeev, Alexander

2014-05-01

Large cities growth and aging lead to the irreversible negative changes of underground. The study of these changes at the urban area mainly based on the shallow methods of Geophysics, which extensive usage restricted by technogenic noise. Among others, precision gravimetry is allocated as method with good resistance to the urban noises. The main the objects of urban gravimetric survey are the soil decompaction, leaded to the rocks strength violation and the karst formation. Their gravity effects are too small, therefore investigation requires the modern high-precision equipment and special methods of measurements. The Gravimetry division of Lomonosov Moscow State University examin of modern precision gravimeters Scintrex CG-5 Autograv since 2006. The main performance characteristics of over 20 precision gravimeters were examined in various operational modes. Stationary mode. Long-term gravimetric measurements were carried at a base station. It shows that records obtained differ by high-frequency and mid-frequency (period 5 - 12 hours) components. The high-frequency component, determined as a standard deviation of measurement, characterizes the level of the system sensitivity to external noise and varies for different devices from 2 to 5-7 μGals. Midrange component, which closely meet to the rest of nonlinearity gravimeter drifts, is partially compensated by the equipment. This factor is very important in the case of gravimetric monitoring or observations, when midrange anomalies are the target ones. For the examined gravimeters, amplitudes' deviations, associated with this parameter may reach 10 μGals. Various transportation modes - were performed by walking (softest mode), lift (vertical overload), vehicle (horizontal overloads), boat (vertical plus horizontal overloads) and helicopter. The survey quality was compared by the variance of the measurement results and internal convergence of series. The measurement results variance (from ±2 to ±4 μGals) and its

Detailed measurements and modelling of thermo active components using a room size test facility

DEFF Research Database (Denmark)

Weitzmann, Peter; Svendsen, Svend

2005-01-01

measurements in an office sized test facility with thermo active ceiling and floor as well as modelling of similar conditions in a computer program designed for analysis of building integrated heating and cooling systems. A method for characterizing the cooling capacity of thermo active components is described...... typically within 1-2K of the measured results. The simulation model, whose room model splits up the radiative and convective heat transfer between room and surfaces, can also be used to predict the dynamical conditions, where especially the temperature rise during the day is important for designing...

Fabrication of thermo-responsive cotton fabrics using poly(vinyl caprolactam-co-hydroxyethyl acrylamide) copolymer.

Science.gov (United States)

Xiao, Min; González, Edurne; Monterroza, Alexis Martell; Frey, Margaret

2017-10-15

A thermo-responsive polymer with hydrophilic to hydrophobic transition behavior, poly(vinyl caprolactam-co-hydroxyethyl acrylamide) P(VCL-co-HEAA), was prepared by copolymerization of vinyl caprolactam and N-hydroxyethyl acrylamide via free radical solution polymerization. The resulting copolymer was characterized by Fourier transform infrared spectroscopy (FTIR), 1 H nuclear magnetic resonance (NMR), gel permeation chromatography (GPC), differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). The lower critical solution temperature (LCST) of P(VCL-co-HEAA) was determined at 34.5°C. This thermo-responsive polymer was then grafted onto cotton fabrics using 1,2,3,4-butanetetracarboxylic acid (BTCA) as crosslinker and sodium hypophosphite (SHP) as catalyst. FTIR and energy dispersive X-ray spectroscopy (EDS) studies confirmed the successful grafting reaction. The modified cotton fabric exhibited thermo-responsive behavior as evidenced by water vapor permeability measurement confirming decreased permeability at elevated temperature. This is the first demonstration that a PVCL based copolymer is grafted to cotton fabrics. This study provides a new thermo-responsive polymer for fabrication of smart cotton fabrics with thermally switchable hydrophilicity. Copyright © 2017 Elsevier Ltd. All rights reserved.

Study of the corrosion behavior of magnesium alloy weddings in NaCl solutions by gravimetric tests

Energy Technology Data Exchange (ETDEWEB)

Segarra, J. A.; Calderon, B.; Portoles, A.

2015-07-01

In this article, the corrosion behavior of commercial AZ31 welded plates in aqueous chloride media was investigated by means of gravimetric techniques and Neutral Salt Spray tests (NSS). The AZ31 samples tested were welded using Gas Tugsten Arc Welding (GTAW) and different filler materials. Material microstructures were investigated by optical microscopy to stablish the influence of those microstructures in the corrosion behavior. Gravimetric and NSS tests indicate that the use of more noble filler alloys for the sample welding, preventing the reduction of aluminum content in weld beads, does not imply a better corrosion behavior. (Author)

Did Life Emerge in Thermo-Acidic Conditions?

Science.gov (United States)

Holmes, D. S.

2017-12-01

There is widespread, but not unanimous, agreement that life emerged in hot conditions by exploiting redox and pH disequilibria found on early earth. Although there are several hypotheses to explain the postulated pH disequilibria, few of these consider that life evolved at very low pH (biological evolution. This presentation will evaluate the pros and cons of the hypothesis that the early evolution of life occurred in thermo-acidic conditions. Such environments are thought to have been abundant on early earth and were probably rich in hydrogen and soluble metals including iron and sulfur that could have served as sources and sinks of electrons. Extant thermo-acidophiles thrive in such conditions. Low pH environments are rich in protons that are the major drivers of energy conservation by coupling to phosphorylation in virtually all organisms on earth; this may be a "biochemical fossil" reflecting the use of protons (low pH) in primitive energy conservation. It has also been proposed that acidic conditions favored the evolution of an RNA world with expanded catalytic activities. On the other hand, the idea that life emerged in thermo-acidic conditions can be challenged because of the proposed difficulties of folding and stabilizing proteins simultaneously exposed to high temperature and low pH. In addition, although thermo-acidophiles root to the base of the phylogenetic tree of life, consistent with the proposition that they evolved early, yet there are problems of interpretation of their subsequent evolution that cloud this simplistic phylogenetic view. We propose solutions to these problems and hypothesize that life evolved in thermo-acidic conditions.

Analogy between dynamics of thermo-rheological and piezo-rheological pendulums

International Nuclear Information System (INIS)

Hedrih, K

2008-01-01

The constitutive stress-strain relations of the standard thermo-rheological and piezo-rheological hereditary element in differential form as well as in two different integro-differential forms are defined. The considered problem of a thermo-rheological hereditary discrete system nonlinear dynamics in the form of thermo-rheological double pendulum system with coupled pendulums gets the significance of two constrained bodies in plane motion problem, as a problem important for studying a sensor dynamics or actuator dynamics in active structure dynamics. System of the averaged equations in the first approximation for amplitudes and phases are derived and qualitatively analyzed. Analogy between nonlinear dynamics of the double pendulum systems with thermo-rheological and piezo-rheological properties between pendulums is pointed out

A detailed gravimetric geoid of North America, the North Atlantic, Eurasia, and Australia

Science.gov (United States)

Marsh, J. G.

1973-01-01

A computer program was developed for the calculation of a goid based upon a combination of satellite and surface gravity data. A detailed gravimetric geoid of North America, the North Atlantic, Eurasia, and Australia was derived by using this program.

Thermo-Economic Analysis of Zeotropic Mixtures and Pure Working Fluids in Organic Rankine Cycles for Waste Heat Recovery

Directory of Open Access Journals (Sweden)

Florian Heberle

2016-03-01

Full Text Available We present a thermo-economic analysis of an Organic Rankine Cycle (ORC for waste heat recovery. A case study for a heat source temperature of 150 °C and a subcritical, saturated cycle is performed. As working fluids R245fa, isobutane, isopentane, and the mixture of isobutane and isopentane are considered. The minimal temperature difference in the evaporator and the condenser, as well as the mixture composition are chosen as variables in order to identify the most suitable working fluid in combination with optimal process parameters under thermo-economic criteria. In general, the results show that cost-effective systems have a high minimal temperature difference ΔTPP,C at the pinch-point of the condenser and a low minimal temperature difference ΔTPP,E at the pinch-point of the evaporator. Choosing isobutane as the working fluid leads to the lowest costs per unit exergy with 52.0 €/GJ (ΔTPP,E = 1.2 K; ΔTPP,C = 14 K. Considering the major components of the ORC, specific costs range between 1150 €/kW and 2250 €/kW. For the zeotropic mixture, a mole fraction of 90% isobutane leads to the lowest specific costs per unit exergy. A further analysis of the ORC system using isobutane shows high sensitivity of the costs per unit exergy for the selected cost estimation methods and for the isentropic efficiency of the turbine.

Comparison of the gravimetric, phenol red, and 14C-PEG-3350 methods to determine water absorption in the rat single-pass intestinal perfusion model.

Science.gov (United States)

Sutton, S C; Rinaldi, M T; Vukovinsky, K E

2001-01-01

This study was undertaken to determine whether the gravimetric method provided an accurate measure of water flux correction and to compare the gravimetric method with methods that employ nonabsorbed markers (eg, phenol red and 14C-PEG-3350). Phenol red,14C-PEG-3350, and 4-[2-[[2-(6-amino-3-pyridinyl)-2-hydroxyethyl]amino]ethoxy]-, methyl ester, (R)-benzene acetic acid (Compound I) were co-perfused in situ through the jejunum of 9 anesthetized rats (single-pass intestinal perfusion [SPIP]). Water absorption was determined from the phenol red,14C-PEG-3350, and gravimetric methods. The absorption rate constant (ka) for Compound I was calculated. Both phenol red and 14C-PEG-3350 were appreciably absorbed, underestimating the extent of water flux in the SPIP model. The average +/- SD water flux microg/h/cm) for the 3 methods were 68.9 +/- 28.2 (gravimetric), 26.8 +/- 49.2 (phenol red), and 34.9 +/- 21.9 (14C-PEG-3350). The (average +/- SD) ka for Compound I (uncorrected for water flux) was 0.024 +/- 0.005 min(-1). For the corrected, gravimetric method, the average +/- SD was 0.031 +/- 0.001 min(-1). The gravimetric method for correcting water flux was as accurate as the 2 "nonabsorbed" marker methods.

Solar-absorbing metamaterial microencapsulation of phase change materials for thermo-regulating textiles

Directory of Open Access Journals (Sweden)

William Tong

2015-04-01

Full Text Available This paper presents a novel concept for designing solar-absorbing metamaterial microcapsules of phase change materials (PCMs integrated with thermo-regulating smart textiles intended for coats or garments, especially for wear in space or cold weather on earth. The metamaterial is a periodically nanostructured metal-dielectric-metal thin film and can acquire surface plasmons to trap or absorb solar energy at subwavelength scales. This kind of metamaterial microencapsulation is not only able to take advantage of latent heat that can be stored or released from the PCMs over a tunable temperature range, but also has other advantages over conventional polymer microencapsulation of PCMs, such as enhanced thermal conductivity, improved flame-retardant capabilities, and usage as an extra solar power resource. The thermal analysis for this kind of microencapsulation has been done and can be used as a guideline for designing integrated thermo-regulating smart textiles in the future. These metamaterial microcapsules may open up new routes to enhancing thermo-regulating textiles with novel properties and added value.

Assessment of thermo-mechanical behavior in CLAM steel first wall structures

International Nuclear Information System (INIS)

Liu Fubin; Yao Man

2012-01-01

Highlights: ► China Low Activation Martensitic steel (CLAM) as FW the structural material. ► The thermo-mechanical behavior of the FW was analyzed under the condition of normal ITER operation combined effect of plasma heat flux and neutron heating. ► The temperature dependence of the material physical properties of CLAM is summarized. - Abstract: The temperature and strain distributions of the mockup with distinct structural material (SS316L or China Low Activation Martensitic steel (CLAM)) in two-dimensional model were calculated and analyzed, based on a high heat flux (HHF) test recently reported with heat flux of 3.2 MW/m 2 . The calculated temperature and strain results in the first wall (FW), in which SS316L is as the structural material, showed good agreement with HHF test. By substituting CLAM steel for SS316L the contrast analysis indicates that the thermo-mechanical property for CLAM steel is better than that of SS316 at the same condition. Furthermore, the thermo-mechanical behavior of the FW was analyzed under the condition of normal ITER operation combined effect of plasma heat flux and neutron heating.

Assessment of thermo-mechanical behavior in CLAM steel first wall structures

Energy Technology Data Exchange (ETDEWEB)

Liu Fubin, E-mail: liufubin_1216@126.com [School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, Liaoning (China); Yao Man, E-mail: yaoman@dlut.edu.cn [School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, Liaoning (China)

2012-01-15

Highlights: Black-Right-Pointing-Pointer China Low Activation Martensitic steel (CLAM) as FW the structural material. Black-Right-Pointing-Pointer The thermo-mechanical behavior of the FW was analyzed under the condition of normal ITER operation combined effect of plasma heat flux and neutron heating. Black-Right-Pointing-Pointer The temperature dependence of the material physical properties of CLAM is summarized. - Abstract: The temperature and strain distributions of the mockup with distinct structural material (SS316L or China Low Activation Martensitic steel (CLAM)) in two-dimensional model were calculated and analyzed, based on a high heat flux (HHF) test recently reported with heat flux of 3.2 MW/m{sup 2}. The calculated temperature and strain results in the first wall (FW), in which SS316L is as the structural material, showed good agreement with HHF test. By substituting CLAM steel for SS316L the contrast analysis indicates that the thermo-mechanical property for CLAM steel is better than that of SS316 at the same condition. Furthermore, the thermo-mechanical behavior of the FW was analyzed under the condition of normal ITER operation combined effect of plasma heat flux and neutron heating.

Thermo-mechanical assessment of full SiC/SiC composite cladding for LWR applications with sensitivity analysis

Science.gov (United States)

Singh, Gyanender; Terrani, Kurt; Katoh, Yutai

2018-02-01

SiC/SiC composites are considered among leading candidates for accident tolerant fuel cladding in light water reactors. However, when SiC-based materials are exposed to neutron irradiation, they experience significant changes in dimensions and physical properties. Under a large heat flux application (i.e. fuel cladding), the non-uniform changes in the dimensions and physical properties will lead to build-up of stresses in the structure over the course of time. To ensure reliable and safe operation of such a structure it is important to assess its thermo-mechanical performance under in-reactor conditions of irradiation and elevated temperature. In this work, the foundation for 3D thermo-mechanical analysis of SiC/SiC cladding is put in place and a set of analyses with simplified boundary conditions has been performed. The analyses were carried out with two different codes that were benchmarked against one another and prior results in the literature. A constitutive model is constructed and solved numerically to predict the stress distribution and variation in the cladding under normal operating conditions. The dependence of dimensions and physical properties variation with irradiation and temperature has been incorporated. These robust models may now be modified to take into account the axial and circumferential variation in neutron and heat flux to fully account for 3D effects. The results from the simple analyses show the development of high tensile stresses especially in the circumferential and axial directions at the inner region of the cladding. Based on the results obtained, design guidelines are recommended. For lack of certainty in or tailor-ability for the physical and mechanical properties of SiC/SiC composite material a sensitivity analysis is conducted. The analysis results establish a precedence order of the properties based on the extent to which these properties influence the temperature and the stresses.

Determination of optimum thermal debinding and sintering process parameters using Taguchi Method

CSIR Research Space (South Africa)

Seerane, M

2015-07-01

Full Text Available powder and a wax-based binder. The binder’s backbone component is a low density polyethylene (LDPE). Careful selection of thermal debinding parameters was guided by thermo- gravimetric analysis (TGA) results. The Taguchi method was used to determine... International Light Metals Technology Conference (LMT 2015), Port Elizabeth, South Africa, July 27-29 Determination of Optimum Process for Thermal Debinding and Sintering using Taguchi Method SEERANE Mandya,*, CHIKWANDA Hildab, MACHAKA Ronaldc CSIR...

Synthesis, characterization, and property studies of (La, Ag) FeO{sub 3} (0.0 {<=} x {<=} 0.3) perovskites

Energy Technology Data Exchange (ETDEWEB)

Bellakki, Manjunath B.; Kelly, Brandon J. [Department of Mechanical Engineering, Colorado State University, Fort Collins, Colorado 80523 (United States); Manivannan, V., E-mail: mani@engr.colosate.ed [Department of Mechanical Engineering, Colorado State University, Fort Collins, Colorado 80523 (United States)

2010-01-07

Applying a solution - based combustion process, Ag-doped LaFeO{sub 3} orthoferrites were synthesized. The samples were characterized by multiple techniques to establish structure - property relationships. Specifically, for structural characterization, powder X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX), Fourier transmission infrared spectroscopy (FTIR), Thermo-gravimetric analysis (TGA), and X-ray photoelectron microscopy (XPS) were carried out. For properties, squid magnetometer measurements (for magnetic properties), titrations (for chemical analysis), and diffuse reflectance (for optical band gap properties) measurements were carried out to elucidate structure-property relationship.

Gravimetric method for in vitro calibration of skin hydration measurements.

Science.gov (United States)

Martinsen, Ørjan G; Grimnes, Sverre; Nilsen, Jon K; Tronstad, Christian; Jang, Wooyoung; Kim, Hongsig; Shin, Kunsoo; Naderi, Majid; Thielmann, Frank

2008-02-01

A novel method for in vitro calibration of skin hydration measurements is presented. The method combines gravimetric and electrical measurements and reveals an exponential dependency of measured electrical susceptance to absolute water content in the epidermal stratum corneum. The results also show that absorption of water into the stratum corneum exhibits three different phases with significant differences in absorption time constant. These phases probably correspond to bound, loosely bound, and bulk water.

Separation and gravimetric determination of rare earths with N-(3-nitrobenzoyl), N-(3-tolyl) hydroxylamine

International Nuclear Information System (INIS)

Agrawal, Y.K.; Kapoor, H.L.

1977-01-01

The N-(3-nitrobenzoyl), N-(3-tolyl) hydroxylamine is used as a reagent for the separation and gravimetric determination of Ce 3+ , La 3+ , Pr 3+ , Nd 3+ , Sm 3+ and Gd 3+ . The optimum conditions of precipitation of these rare earths indicate that, by control of pH and judicious use of masking agents, these ions can be separated from, and determined gravimetrically among several other ions. Further, the stochiometric nature of the N-(3-nitrobenzoyl), N-(3-tolyl) hydroxylamine acid is advantageous for the direct determination by weighting of (C 14 H 11 N 2 O 4 ) 3 M complex without ignition to obtain oxides. These complexes are characterized by infrared spectra

Molecularly imprinted membrane extraction combined with high-performance liquid chromatography for selective analysis of cloxacillin from shrimp samples.

Science.gov (United States)

Du, Wei; Sun, Min; Guo, Pengqi; Chang, Chun; Fu, Qiang

2018-09-01

Nowadays, the abuse of antibiotics in aquaculture has generated considerable problems for food safety. Therefore, it is imperative to develop a simple and selective method for monitoring illegal use of antibiotics in aquatic products. In this study, a method combined molecularly imprinted membranes (MIMs) extraction and liquid chromatography was developed for the selective analysis of cloxacillin from shrimp samples. The MIMs was synthesized by UV photopolymerization, and characterized by scanning electron microscope, Fourier transform infrared spectra, thermo-gravimetric analysis and swelling test. The results showed that the MIMs exhibited excellent permselectivity, high adsorption capacity and fast adsorption rate for cloxacillin. Finally, the method was utilized to determine cloxacillin from shrimp samples, with good accuracies and acceptable relative standard deviation values for precision. The proposed method was a promising alternative for selective analysis of cloxacillin in shrimp samples, due to the easy-operation and excellent selectivity. Copyright © 2018. Published by Elsevier Ltd.

Thermo-economic analysis of recuperated Maisotsenko bottoming cycle using triplex air saturator: Comparative analyses

International Nuclear Information System (INIS)

Saghafifar, Mohammad; Omar, Amr; Erfanmoghaddam, Sepehr; Gadalla, Mohamed

2017-01-01

Highlights: • Proposing recuperated Maisotsenko bottoming cycle (RMBC) as a new combined cycle. • Introducing triplex air saturator for waste heat recovery application. • Conducting thermodynamic optimization to maximize RMBC thermal efficiency. • Conducting thermo-economic optimization to minimize RMBC cost of electricity. - Abstract: A recently recommended combined cycle power plant is to employ another gas turbine cycle for waste heat recovery as an air bottoming cycle (ABC). There are some studies conducted to improve ABC’s thermodynamic performance utilizing commonly power augmentation methods such as steam/water injection. In particular, it is proposed to employ Maisotsenko gas turbine cycle as a bottoming cycle, i.e. Maisotsenko bottoming cycle (MBC). Due to the promising performance of the MBC configuration, it is decided to investigate a recuperated MBC (RMBC) configuration by recommending the triplex air saturator. In this way, the air saturator consists of three sections. The first section is an indirect evaporative cooler while the other two sections are responsible for heat recovery from the topping and bottoming cycle turbines exhaust. In this paper, thermodynamic and thermo-economic analyses are carried out to study the main merits and demerits of RMBC against MBC configuration. Thermodynamic optimization results indicate that the maximum achievable efficiency for MBC and RMBC incorporation in a simple gas turbine power plant are 39.40% and 44.73%, respectively. Finally, thermo-economic optimization shows that the optimum levelized cost of electricity for MBC and RMBC power plants are 62.922 US$/MWh and 58.154 US$/MWh, respectively.

Gravimetric determination of cadmium with o-phenanthroline and iodide

International Nuclear Information System (INIS)

Yoshida, Hitoshi; Mizuno, Kazunori; Taga, Mitsuhiko; Hikime, Seiichiro

1976-01-01

Cadmium forms insoluble mixed ligand complex with o-phenanthroline and iodide ions. By using the complex a new gravimetric method for the determination of cadmium was investigated. The recommended analytical procedure is as follows: Adjust pH value of a solution containing 5 to 45 mg cadmium to 4 with 3 M acetic acid-sodium acetate buffer solution. Add over threefold moles of potassium iodide to the solution and heat to just before boiling. To the solution add 0.1% ascorbic acid solution and then 0.1 M o-phenanthroline solution drop by drop in excess with stirring, and cool the mixture to room temperature. Filter the precipitates and wash first with 0.01% potassium iodide solution and then with water. Dry the precipitates at 110 0 C for two hours and weigh as Cd(o-phen) 2 I 2 (I). The gravimetric factor of the complex for cadmium is 0.1547. Chemical composition of the precipitate is variable when o-phenanthroline is added less than twofold moles to cadmium. Adding the o-phenanthroline solution 2.4-fold moles against cadmium, the ternary complex (I) precipitates quantitatively. Though a large excess of iodide ion in the solution contaminated the precipitate, the contamination was avoided when precipitation was carryed out at high temperature and in the presence of ascorbic acid. By the presented procedure 5 to 45 mg of cadmium are determined with a standard deviation of 0 C. (JPN)

Surface enhanced thermo lithography

KAUST Repository

Coluccio, Maria Laura

2017-01-13

We used electroless deposition to fabricate clusters of silver nanoparticles (NPs) on a silicon substrate. These clusters are plasmonics devices that induce giant electromagnetic (EM) field increments. When those EM field are absorbed by the metal NPs clusters generate, in turn, severe temperature increases. Here, we used the laser radiation of a conventional Raman set-up to transfer geometrical patterns from a template of metal NPs clusters into a layer of thermo sensitive Polyphthalaldehyde (PPA) polymer. Temperature profile on the devices depends on specific arrangements of silver nanoparticles. In plane temperature variations may be controlled with (i) high nano-meter spatial precision and (ii) single Kelvin temperature resolution on varying the shape, size and spacing of metal nanostructures. This scheme can be used to generate strongly localized heat amplifications for applications in nanotechnology, surface enhanced thermo-lithography (SETL), biology and medicine (for space resolved cell ablation and treatment), nano-chemistry.

Surface enhanced thermo lithography

KAUST Repository

Coluccio, Maria Laura; Alabastri, Alessandro; Bonanni, Simon; Majewska, Roksana; Dattoli, Elisabetta; Barberio, Marianna; Candeloro, Patrizio; Perozziello, Gerardo; Mollace, Vincenzo; Di Fabrizio, Enzo M.; Gentile, Francesco

2017-01-01

We used electroless deposition to fabricate clusters of silver nanoparticles (NPs) on a silicon substrate. These clusters are plasmonics devices that induce giant electromagnetic (EM) field increments. When those EM field are absorbed by the metal NPs clusters generate, in turn, severe temperature increases. Here, we used the laser radiation of a conventional Raman set-up to transfer geometrical patterns from a template of metal NPs clusters into a layer of thermo sensitive Polyphthalaldehyde (PPA) polymer. Temperature profile on the devices depends on specific arrangements of silver nanoparticles. In plane temperature variations may be controlled with (i) high nano-meter spatial precision and (ii) single Kelvin temperature resolution on varying the shape, size and spacing of metal nanostructures. This scheme can be used to generate strongly localized heat amplifications for applications in nanotechnology, surface enhanced thermo-lithography (SETL), biology and medicine (for space resolved cell ablation and treatment), nano-chemistry.

Thermo-responsive cell culture carrier: Effects on macrophage functionality and detachment efficiency.

Science.gov (United States)

Rennert, Knut; Nitschke, Mirko; Wallert, Maria; Keune, Natalie; Raasch, Martin; Lorkowski, Stefan; Mosig, Alexander S

2017-01-01

Harvesting cultivated macrophages for tissue engineering purposes by enzymatic digestion of cell adhesion molecules can potentially result in unintended activation, altered function, or behavior of these cells. Thermo-responsive polymer is a promising tool that allows for gentle macrophage detachment without artificial activation prior to subculture within engineered tissue constructs. We therefore characterized different species of thermo-responsive polymers for their suitability as cell substrate and to mediate gentle macrophage detachment by temperature shift. Primary human monocyte- and THP-1-derived macrophages were cultured on thermo-responsive polymers and characterized for phagocytosis and cytokine secretion in response to lipopolysaccharide stimulation. We found that both cell types differentially respond in dependence of culture and stimulation on thermo-responsive polymers. In contrast to THP-1 macrophages, primary monocyte-derived macrophages showed no signs of impaired viability, artificial activation, or altered functionality due to culture on thermo-responsive polymers compared to conventional cell culture. Our study demonstrates that along with commercially available UpCell carriers, two other thermo-responsive polymers based on poly(vinyl methyl ether) blends are attractive candidates for differentiation and gentle detachment of primary monocyte-derived macrophages. In summary, we observed similar functionality and viability of primary monocyte-derived macrophages cultured on thermo-responsive polymers compared to standard cell culture surfaces. While this first generation of custom-made thermo-responsive polymers does not yet outperform standard culture approaches, our results are very promising and provide the basis for exploiting the unique advantages offered by custom-made thermo-responsive polymers to further improve macrophage culture and recovery in the future, including the covalent binding of signaling molecules and the reduction of

THERMOS, district central heating nuclear reactors

International Nuclear Information System (INIS)

Patarin, L.

1981-02-01

In order to expand the penetration of uranium in the national energy balance sheet, the C.E.A. has been studying nuclear reactors for several years now, that are capable of providing heat at favourable economic conditions. In this paper the THERMOS model is introduced. After showing the attraction of direct town heating by nuclear energy, the author describes the THERMOS project, defines the potential market, notably in France, and applies the lay-out study to the Grenoble Nuclear Study Centre site with district communal heating in mind. The economic aspects of the scheme are briefly mentioned [fr

Comprehensive nonlocal analysis of piezoelectric nanobeams with surface effects in bending, buckling and vibrations under magneto-electro-thermo-mechanical loading

Science.gov (United States)

Ebrahimi-Nejad, Salman; Boreiry, Mahya

2018-03-01

The bending, buckling and vibrational behavior of size-dependent piezoelectric nanobeams under thermo-magneto-mechano-electrical environment are investigated by performing a parametric study, in the presence of surface effects. The Gurtin-Murdoch surface elasticity and Eringen’s nonlocal elasticity theories are applied in the framework of Euler–Bernoulli beam theory to obtain a new non-classical size-dependent beam model for dynamic and static analyses of piezoelectric nanobeams. In order to satisfy the surface equilibrium equations, cubic variation of stress with beam thickness is assumed for the bulk stress component which is neglected in classical beam models. Results are obtained for clamped - simply-supported (C-S) and simply-supported - simply-supported (S-S) boundary conditions using a proposed analytical solution method. Numerical examples are presented to demonstrate the effects of length, surface effects, nonlocal parameter and environmental changes (temperature, magnetic field and external voltage) on deflection, critical buckling load and natural frequency for each boundary condition. Results of this study can serve as benchmarks for the design and analysis of nanostructures of magneto-electro-thermo-elastic materials.

A highly accurate absolute gravimetric network for Albania, Kosovo and Montenegro

Science.gov (United States)

Ullrich, Christian; Ruess, Diethard; Butta, Hubert; Qirko, Kristaq; Pavicevic, Bozidar; Murat, Meha

2016-04-01

The objective of this project is to establish a basic gravity network in Albania, Kosovo and Montenegro to enable further investigations in geodetic and geophysical issues. Therefore the first time in history absolute gravity measurements were performed in these countries. The Norwegian mapping authority Kartverket is assisting the national mapping authorities in Kosovo (KCA) (Kosovo Cadastral Agency - Agjencia Kadastrale e Kosovës), Albania (ASIG) (Autoriteti Shtetëror i Informacionit Gjeohapësinor) and in Montenegro (REA) (Real Estate Administration of Montenegro - Uprava za nekretnine Crne Gore) in improving the geodetic frameworks. The gravity measurements are funded by Kartverket. The absolute gravimetric measurements were performed from BEV (Federal Office of Metrology and Surveying) with the absolute gravimeter FG5-242. As a national metrology institute (NMI) the Metrology Service of the BEV maintains the national standards for the realisation of the legal units of measurement and ensures their international equivalence and recognition. Laser and clock of the absolute gravimeter were calibrated before and after the measurements. The absolute gravimetric survey was carried out from September to October 2015. Finally all 8 scheduled stations were successfully measured: there are three stations located in Montenegro, two stations in Kosovo and three stations in Albania. The stations are distributed over the countries to establish a gravity network for each country. The vertical gradients were measured at all 8 stations with the relative gravimeter Scintrex CG5. The high class quality of some absolute gravity stations can be used for gravity monitoring activities in future. The measurement uncertainties of the absolute gravity measurements range around 2.5 micro Gal at all stations (1 microgal = 10-8 m/s2). In Montenegro the large gravity difference of 200 MilliGal between station Zabljak and Podgorica can be even used for calibration of relative gravimeters

Fracture mechanics in new designed power module under thermo-mechanical loads

Directory of Open Access Journals (Sweden)

Durand Camille

2014-06-01

Full Text Available Thermo-mechanically induced failure is a major reliability issue in the microelectronic industry. On this account, a new type of Assembly Interconnected Technology used to connect MOSFETs in power modules has been developed. The reliability is increased by using a copper clip soldered on the top side of the chip, avoiding the use of aluminium wire bonds, often responsible for the failure of the device. Thus the new designed MOSFET package does not follow the same failure mechanisms as standard modules. Thermal and power cycling tests were performed on these new packages and resulting failures were analyzed. Thermo-mechanical simulations including cracks in the aluminium metallization and intermetallics (IMC were performed using Finite Element Analysis in order to better understand crack propagation and module behaviour.

Thermochemical production of liquid fuels from biomass: Thermo-economic modeling, process design and process integration analysis

International Nuclear Information System (INIS)

Tock, Laurence; Gassner, Martin; Marechal, Francois

2010-01-01

A detailed thermo-economic model combining thermodynamics with economic analysis and considering different technological alternatives for the thermochemical production of liquid fuels from lignocellulosic biomass is presented. Energetic and economic models for the production of Fischer-Tropsch fuel (FT), methanol (MeOH) and dimethyl ether (DME) by means of biomass drying with steam or flue gas, directly or indirectly heated fluidized bed or entrained flow gasification, hot or cold gas cleaning, fuel synthesis and upgrading are reviewed and developed. The process is integrated and the optimal utility system is computed. The competitiveness of the different process options is compared systematically with regard to energetic, economic and environmental considerations. At several examples, it is highlighted that process integration is a key element that allows for considerably increasing the performance by optimal utility integration and energy conversion. The performance computations of some exemplary technology scenarios of integrated plants yield overall energy efficiencies of 59.8% (crude FT-fuel), 52.5% (MeOH) and 53.5% (DME), and production costs of 89, 128 and 113 Euro MWh -1 on fuel basis. The applied process design approach allows to evaluate the economic competitiveness compared to fossil fuels, to study the influence of the biomass and electricity price and to project for different plant capacities. Process integration reveals in particular potential energy savings and waste heat valorization. Based on this work, the most promising options for the polygeneration of fuel, power and heat will be determined in a future thermo-economic optimization.

Analysis of the thermo-chemo-mechanical behavior of massive concrete structures oat early-age

International Nuclear Information System (INIS)

Honorio, T.; Bary, B.; Benboudjema, F.

2014-01-01

The prediction of the thermo-chemo-mechanical behavior of concrete structures at early ages is important in the context of the feasibility of massive structures. Different phenomena affecting the thermal response of the structure are studied, namely the influence of the change on convection conditions due to wind, the influence of solar radiation, the influence of ambient temperature and the influence of assembly date. A mechanical analysis accounting for autogenous shrinkage and creep strains, besides thermal strains, is performed for the latter case. The results point out the importance of considering the solar radiation and wind conditions on the thermal response of the structure. The ambient temperature impacts directly the maximum temperature reached within the structure. Finally, although the temperature profiles seem just to shift according to the assembly date, the mechanical response is less favorable to early assembly dates. (authors)

Evaluation of the gravimetric tetraphenylarsonium method for the determination of Tc(VII)

International Nuclear Information System (INIS)

Pacer, R.A.

1980-01-01

Solubility losses in the gravimetric tetraphenylarsonium method for determining pertechnetate have been evaluated. Liquid scintillation counting was used to measure the β - activity of 99 Tc in the filtrate, and indicated solubility losses of about 1% in analyses yielding 40 to 50 mg of precipitate. The solubility product of (C 6 H 5 ) 4 AsTcO 4 is estimated to be (8.6 +- 0.2) x 10 -10 at room temperature (24 to 25 0 ), and Ksub(sp) for (C 6 H 5 ) 4 AsReO 4 at approximately 21 to 23 0 is estimated at (2.6 +- 0.3) x 10 -9 . Both values are satisfactory for gravimetric purposes, but to keep solubility losses within 1% at least 40 mg of (C 6 H 5 ) 4 AsTcO 4 or 80 mg of (C 6 H 5 ) 4 AsReO 4 should be obtained (assuming 20 ml of solution, 20 to 30% excess of precipitant, and 6 or 7 washes with 5-ml portions of distilled water). (author)

ThermoData Engine: Extension to Solvent Design and Multi-component Process Stream Property Calculations with Uncertainty Analysis

DEFF Research Database (Denmark)

Diky, Vladimir; Chirico, Robert D.; Muzny, Chris

ThermoData Engine (TDE, NIST Standard Reference Databases 103a and 103b) is the first product that implements the concept of Dynamic Data Evaluation in the fields of thermophysics and thermochemistry, which includes maintaining the comprehensive and up-to-date database of experimentally measured...... property values and expert system for data analysis and generation of recommended property values at the specified conditions along with uncertainties on demand. The most recent extension of TDE covers solvent design and multi-component process stream property calculations with uncertainty analysis...... variations). Predictions can be compared to the available experimental data, and uncertainties are estimated for all efficiency criteria. Calculations of the properties of multi-component streams including composition at phase equilibria (flash calculations) are at the heart of process simulation engines...

Estimation of the internal structure of Trans-Mexican volcanic belt by gravimetric data

International Nuclear Information System (INIS)

Flores R, J.H.

1994-01-01

The regional gravimetric data of Trans-Mexican volcanic belt and surroundings, has been analyzed in order to estimate the depth of its internal structure. The short profiles with N-S orientation give a model of four shells with an average depth in the rank 24, 34, 56 and 83 kilometers. Only the profiles included between 97 West degrees to 102 West degrees give a depth of crust larger than the rest of the profiles with the same orientation. This profiles are associated with that of the Valleys of Toluca, D.F. and Puebla where the maximum crust thickness was estimated. The 3 long profiles with S-W orientation, give a model of 3 shells. The tendency of the first shell has a cortical thickness of 38 kilometers in the latitude of 18 North degrees. This tendency to increase the depth in the crust is associated with the minimum gravimetric in the map of Bouguer anomaly. (Author)

Thermo-economic analysis of integrated membrane-SMR ITM-oxy-combustion hydrogen and power production plant

International Nuclear Information System (INIS)

Sanusi, Yinka S.; Mokheimer, Esmail M.A.; Habib, Mohamed A.

2017-01-01

Highlights: •A methane reforming reactor integrated to an oxy-combustion plant is proposed. •Co-production of power and hydrogen was investigated and presented. •Optimal thermo-economic operating conditions of the system were identified and presented. •The ion transport membrane oxygen separation unit has the highest capital cost. •The combustor has the highest exergy destruction. -- Abstract: The demand for hydrogen has greatly increased in the last decade due to the stringent regulations enacted to address environmental pollution concerns. Natural gas reforming is currently the most mature technology for large-scale hydrogen production. However, it is usually associated with greenhouse gas emissions. As part of the strategies to reduce greenhouse gas emissions, new designs need to be developed to integrate hydrogen production facilities that are based on natural gas reforming with carbon capture facilities. In this study, we carried out energy, exergy and economic analysis of hydrogen production in a steam methane reforming reactor integrated with an oxy-combustion plant for co-production of power and hydrogen. The results show that the overall system efficiency and hydrogen production efficiency monotonically increase with increasing the combustor exit temperature (CET), increasing the amount of hydrogen extracted and decreasing the auxiliary fuel added to the system. The optimal thermo-economic operating conditions of the system were obtained as reformer pressure of 15 bar, auxiliary fuel factor of 0.8 and hydrogen extraction factor of 0.6. The production cost of hydrogen using the proposed system, under these optimal operating conditions, is within the range suggested by the International Energy Agency (IEA). Further analysis shows that the capital cost of the membrane-air separation unit (ITM) has the major share in the total investment cost of the system and constitutes 37% of the total capital cost of the system at the CET of 1500 K. The exergy

Magnetometric and gravimetric surveys in fault detection over Acambay System

Science.gov (United States)

García-Serrano, A.; Sanchez-Gonzalez, J.; Cifuentes-Nava, G.

2013-05-01

In commemoration of the centennial of the Acambay intraplate earthquake of November 19th 1912, we carry out gravimetric and magnetometric surveys to define the structure of faults caused by this event. The study area is located approximately 11 km south of Acambay, in the Acambay-Tixmadeje fault system, where we performed two magnetometric surveys, the first consisting of 17 lines with a spacing of 35m between lines and 5m between stations, and the second with a total of 12 lines with the same spacing, both NW. In addition to these two lines we performed gravimetric profiles located in the central part of each magnetometric survey, with a spacing of 25m between stations, in order to correlate the results of both techniques, the lengths of such profiles were of 600m and 550m respectively. This work describes the data processing including directional derivatives, analytical signal and inversion, by means of which we obtain results of magnetic variations and anomaly traits highly correlated with those faults. It is of great importance to characterize these faults given the large population growth in the area and settlement houses on them, which involves a high risk in the security of the population, considering that these are active faults and cannot be discard earthquakes associated with them, so it is necessary for the authorities and people have relevant information to these problem.

Thermo-economic evaluation and optimization of the thermo-chemical conversion of biomass into methanol

International Nuclear Information System (INIS)

Peduzzi, Emanuela; Tock, Laurence; Boissonnet, Guillaume; Maréchal, François

2013-01-01

In a carbon and resources constrained world, thermo-chemical conversion of lignocellulosic biomass into fuels and chemicals is regarded as a promising alternative to fossil resources derived products. Methanol is one potential product which can be used for the synthesis of various chemicals or as a fuel in fuel cells and internal combustion engines. This study focuses on the evaluation and optimization of the thermodynamic and economic performance of methanol production from biomass by applying process integration and optimization techniques. Results reveal the importance of the energy integration and in particular of the cogeneration of electricity for the efficient use of biomass. - Highlights: • A thermo-economic model for biomass conversion into methanol is developed. • Process integration and multi-objective optimization techniques are applied. • Results reveal the importance of energy integration for electricity co-generation

Application, advantages and limitations of high-density gravimetric surveys compared with three-dimensional geological modelling in dolomite stability investigations

OpenAIRE

Breytenbach, I J; Bosch, P J A

2011-01-01

The article discusses the nature of the gravimetric survey as applied and used in dolomite stability investigations on areas underlain by the Chuniespoort Group in South Africa. A short discussion is given on the gravimetric survey procedure along with its uses and alternative methods. Finally, two case studies illustrate the application of the method on a high-density survey grid spacing in comparison with three-dimensional geological modelling based on the lithology and karst weathering hor...

Covalent Surface Modifications of Carbon Nanotubes.

Energy Technology Data Exchange (ETDEWEB)

Pavia Sanders, Adriana [Sandia National Lab. (SNL-CA), Livermore, CA (United States); O' Bryan, Greg [Sandia National Lab. (SNL-CA), Livermore, CA (United States)

2017-07-01

A report meant to document the chemistries investigated by the author for covalent surface modification of CNTs. Oxidation, cycloaddition, and radical reactions were explored to determine their success at covalently altering the CNT surface. Characterization through infrared spectroscopy, Raman spectroscopy, and thermo gravimetric analysis was performed in order to determine the success of the chemistries employed. This report is not exhaustive and was performed for CNT surface modification exploration as it pertains to the "Next Gen" project.

Thermo-Plasmonics for Localized Graphitization and Welding of Polymeric Nanofibers

Directory of Open Access Journals (Sweden)

Ahnaf Usman Zillohu

2014-01-01

Full Text Available There is a growing interest in modulating the temperature under the illumination of light. As a heat source, metal nanoparticles (NPs have played an important role to pave the way for a new branch of plasmonics, i.e., thermo-plasmonics. While thermo-plasmonics have been well established in photo-thermal therapy, it has received comparatively less attention in materials science and chemistry. Here, we demonstrate the first proof of concept experiment of local chemistry and graphitization of metalized polymeric nanofibers through thermo-plasmonic effect. In particular, by tuning the plasmonic absorption of the nanohybrid through a change in the thickness of the deposited silver film on the fibers, the thermo-plasmonic effect can be adjusted in such a way that high enough temperature is generated enabling local welding and graphitization of the polymeric nanofibers.

Thermo-chemical pretreatment and enzymatic hydrolysis for enhancing saccharification of catalpa sawdust.

Science.gov (United States)

Jin, Shuguang; Zhang, Guangming; Zhang, Panyue; Li, Fan; Fan, Shiyang; Li, Juan

2016-04-01

To improve the reducing sugar production from catalpa sawdust, thermo-chemical pretreatments were examined and the chemicals used including NaOH, Ca(OH)2, H2SO4, and HCl. The hemicellulose solubilization and cellulose crystallinity index (CrI) were significantly increased after thermo-alkaline pretreatments, and the thermo-Ca(OH)2 pretreatment showed the best improvement for reducing sugar production comparing to other three pretreatments. The conditions of thermo-Ca(OH)2 pretreatment and enzymatic hydrolysis were systematically optimized. Under the optimal conditions, the reducing sugar yield increased by 1185.7% comparing to the control. This study indicates that the thermo-Ca(OH)2 pretreatment is ideal for the saccharification of catalpa sawdust and that catalpa sawdust is a promising raw material for biofuel. Copyright © 2016 Elsevier Ltd. All rights reserved.

Thermal and fluid dynamic analysis of partially premixed turbulent combustion driven by thermo acoustic effects

NARCIS (Netherlands)

Shahi, Mina; Kok, Jacobus B.W.; Pozarlik, Artur Krzysztof; Sponfeldner, Thomas; Malcolm, M.J.; Pawelczyk, M.; Paosawatyangyong, B.

2013-01-01

Thermo-acoustic instability can be caused by the feedback mechanism between unsteady heat release, acoustic oscillations and flow perturbations. In a gas turbine combustor limit cycles of pressure oscillations at elevated temperatures generated by the unstable combustion process enhance the

Experimental aspects of buoyancy correction in measuring reliable highpressure excess adsorption isotherms using the gravimetric method.

Science.gov (United States)

Nguyen, Huong Giang T; Horn, Jarod C; Thommes, Matthias; van Zee, Roger D; Espinal, Laura

2017-12-01

Addressing reproducibility issues in adsorption measurements is critical to accelerating the path to discovery of new industrial adsorbents and to understanding adsorption processes. A National Institute of Standards and Technology Reference Material, RM 8852 (ammonium ZSM-5 zeolite), and two gravimetric instruments with asymmetric two-beam balances were used to measure high-pressure adsorption isotherms. This work demonstrates how common approaches to buoyancy correction, a key factor in obtaining the mass change due to surface excess gas uptake from the apparent mass change, can impact the adsorption isotherm data. Three different approaches to buoyancy correction were investigated and applied to the subcritical CO 2 and supercritical N 2 adsorption isotherms at 293 K. It was observed that measuring a collective volume for all balance components for the buoyancy correction (helium method) introduces an inherent bias in temperature partition when there is a temperature gradient (i.e. analysis temperature is not equal to instrument air bath temperature). We demonstrate that a blank subtraction is effective in mitigating the biases associated with temperature partitioning, instrument calibration, and the determined volumes of the balance components. In general, the manual and subtraction methods allow for better treatment of the temperature gradient during buoyancy correction. From the study, best practices specific to asymmetric two-beam balances and more general recommendations for measuring isotherms far from critical temperatures using gravimetric instruments are offered.

Synthesis and characterization of CdO nano particles by the sol-gel method

Science.gov (United States)

Vadgama, V. S.; Vyas, R. P.; Jogiya, B. V.; Joshi, M. J.

2017-05-01

Cadmium Oxide (CdO) is an inorganic compound and one of the main precursors to other cadmium compounds. It finds applications in cadmium plating, storage batteries, in transparent conducting film, etc. Here, an attempt is made to synthesize CdO nano particles by sol-gel technique. The gel was prepared using cadmium nitrate tetra hydrate (Cd(NO3)2.4H2O) and aqueous ammonium hydroxide (NH4OH) as a precursor. The synthesized powder is further characterized by techniques like Powder X-ray diffraction (XRD), Transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR) and Thermal gravimetric analysis (TGA). Powder XRD analysis suggested the nano-crystalline nature of the sample with the cubic crystal system. Nano scaled particles of spherical morphology with the size ranging from 50-100 nm are observed from TEM images. While, FT-IR study is used to confirm the presence of different functional groups. Thermo-gravimetric analysis suggests the highly thermally stable nature of the samples. The results are discussed.

Thermo-mechanical analysis of PWR bolts susceptible to IASCC

International Nuclear Information System (INIS)

Matteoli, C.; Hannink, M.H.C.; Blom, F.J.; Marck, S.C. van der; Charpin-Jacobs, F.

2015-01-01

Irradiation Assisted Stress Corrosion Cracking (IASCC) is considered a primary ageing issue for the Reactor Pressure Vessel (RPV) internals of Pressurized Water Reactors (PWR). In particular, this complex phenomenon which develops in an environment featuring thermal and mechanical stresses, interaction with corrosive compounds and irradiation, is affecting the bolts connecting the baffles and the formers in the Nuclear Power Plants' RPVs. The baffle-former assembly is the structure that borders the fuel assemblies region, contributing to keep them in position and separating in the radial direction, the core region from the downcomer region. An evaluation of the stresses and temperatures reached in the baffle-former bolts during normal operation was performed by means of a coupled thermo-mechanical study which uses reactor physics calculations to obtain the fluence in the reactor core and as a consequence the heat deposition in the RPV internals. The heat deposition data are coupled with a finite element model of the bolts and the RPV internals in order to perform a complete analysis taking in account thermal, mechanical and radiation loadings. The study is first carried out focusing on a section of the RPV internals, showing a single row of baffle-former bolts. Then the work is extended to the full core height. The model set up in this work, includes an in-depth study of the behavior of the core internals, in particular baffle-former bolts. The model has the capability of understanding the mechanical and thermal behavior of essential internal components in a PWR. (authors)

Fabrication of cavities in low loss LTCC materials for microwave applications

International Nuclear Information System (INIS)

Malecha, Karol

2012-01-01

A method of buried cavity fabrication in low loss DP951 and new DP9K7 LTCC (low-temperature co-fired ceramic) materials is described in this paper. Laser micromachining and method based on sacrificial volume material (SVM) are studied. Cavities are fabricated in LTCC materials using two different SVMs—cetyl alcohol and carbon tape. The influence of laser system parameters on cutting quality of the LTCC materials is studied. Moreover, thermal properties of the LTCCs and used SVMs are analyzed using combined thermo-gravimetric analysis, differential thermal analysis and differential thermo-gravimetry. Geometries of the LTCC test structures fabricated using different SVMs are analyzed using a scanning electron microscope and x-ray tomography. Energy dispersive spectroscopy and surface wettability measurements are used to analyze changes in LTCC materials atomic composition after co-firing with SVMs. (paper)

Global Threat Reduction Initiative Fuel Thermo-Physical Characterization Project: Sample Management Plan

Energy Technology Data Exchange (ETDEWEB)

Casella, Amanda J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Pereira, Mario M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Steen, Franciska H. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

2013-01-01

This sample management plan provides guidelines for sectioning, preparation, acceptance criteria, analytical path, and end-of-life disposal for the fuel element segments utilized in the Global Threat Reduction Initiative (GTRI), Fuel Thermo-Physical Characterization Project. The Fuel Thermo-Physical Characterization Project is tasked with analysis of irradiated Low Enriched Uranium (LEU) Molybdenum (U-Mo) fuel element samples to support the GTRI conversion program. Sample analysis may include optical microscopy (OM), scanning electron microscopy (SEM) fuel-surface interface analysis, gas pycnometry (density) measurements, laser flash analysis (LFA), differential scanning calorimetry (DSC), thermogravimetry and differential thermal analysis with mass spectroscopy (TG /DTA-MS), Inductively Coupled Plasma Spectrophotometry (ICP), alpha spectroscopy, and Thermal Ionization Mass Spectroscopy (TIMS). The project will utilize existing Radiochemical Processing Laboratory (RPL) operating, technical, and administrative procedures for sample receipt, processing, and analyses. Test instructions (TIs), which are documents used to provide specific details regarding the implementation of an existing RPL approved technical or operational procedure, will also be used to communicate to staff project specific parameters requested by the Principal Investigator (PI). TIs will be developed, reviewed, and issued in accordance with the latest revision of the RPL-PLN-700, RPL Operations Plan. Additionally, the PI must approve all project test instructions and red-line changes to test instructions.

Electroactive polymer gels based on epoxy resin

Science.gov (United States)

Samui, A. B.; Jayakumar, S.; Jayalakshmi, C. G.; Pandey, K.; Sivaraman, P.

2007-04-01

Five types of epoxy gels have been synthesized from common epoxy resins and hardeners. Fumed silica and nanoclay, respectively, were used as fillers and butyl methacrylate/acrylamide were used as monomer(s) for making interpenetrating polymer networks (IPNs) in three compositions. Swelling study, tensile property evaluation, dynamic mechanical thermal analysis, thermo-gravimetric analysis, scanning electron microscopy and electroactive property evaluation were done. The gels have sufficient mechanical strength and the time taken for bending to 20° was found to be 22 min for forward bias whereas it was just 12 min for reverse bias.

Application of an enriched FEM technique in thermo-mechanical contact problems

Science.gov (United States)

Khoei, A. R.; Bahmani, B.

2018-02-01

In this paper, an enriched FEM technique is employed for thermo-mechanical contact problem based on the extended finite element method. A fully coupled thermo-mechanical contact formulation is presented in the framework of X-FEM technique that takes into account the deformable continuum mechanics and the transient heat transfer analysis. The Coulomb frictional law is applied for the mechanical contact problem and a pressure dependent thermal contact model is employed through an explicit formulation in the weak form of X-FEM method. The equilibrium equations are discretized by the Newmark time splitting method and the final set of non-linear equations are solved based on the Newton-Raphson method using a staggered algorithm. Finally, in order to illustrate the capability of the proposed computational model several numerical examples are solved and the results are compared with those reported in literature.

What Controls Thermo-osmosis? Molecular Simulations Show the Critical Role of Interfacial Hydrodynamics

Science.gov (United States)

Fu, Li; Merabia, Samy; Joly, Laurent

2017-11-01

Thermo-osmotic and related thermophoretic phenomena can be found in many situations from biology to colloid science, but the underlying molecular mechanisms remain largely unexplored. Using molecular dynamics simulations, we measure the thermo-osmosis coefficient by both mechanocaloric and thermo-osmotic routes, for different solid-liquid interfacial energies. The simulations reveal, in particular, the crucial role of nanoscale interfacial hydrodynamics. For nonwetting surfaces, thermo-osmotic transport is largely amplified by hydrodynamic slip at the interface. For wetting surfaces, the position of the hydrodynamic shear plane plays a key role in determining the amplitude and sign of the thermo-osmosis coefficient. Finally, we measure a giant thermo-osmotic response of the water-graphene interface, which we relate to the very low interfacial friction displayed by this system. These results open new perspectives for the design of efficient functional interfaces for, e.g., waste-heat harvesting.

What Controls Thermo-osmosis? Molecular Simulations Show the Critical Role of Interfacial Hydrodynamics.

Science.gov (United States)

Fu, Li; Merabia, Samy; Joly, Laurent

2017-11-24

Thermo-osmotic and related thermophoretic phenomena can be found in many situations from biology to colloid science, but the underlying molecular mechanisms remain largely unexplored. Using molecular dynamics simulations, we measure the thermo-osmosis coefficient by both mechanocaloric and thermo-osmotic routes, for different solid-liquid interfacial energies. The simulations reveal, in particular, the crucial role of nanoscale interfacial hydrodynamics. For nonwetting surfaces, thermo-osmotic transport is largely amplified by hydrodynamic slip at the interface. For wetting surfaces, the position of the hydrodynamic shear plane plays a key role in determining the amplitude and sign of the thermo-osmosis coefficient. Finally, we measure a giant thermo-osmotic response of the water-graphene interface, which we relate to the very low interfacial friction displayed by this system. These results open new perspectives for the design of efficient functional interfaces for, e.g., waste-heat harvesting.

Geopotential coefficient determination and the gravimetric boundary value problem: A new approach

Science.gov (United States)

Sjoeberg, Lars E.

1989-01-01

New integral formulas to determine geopotential coefficients from terrestrial gravity and satellite altimetry data are given. The formulas are based on the integration of data over the non-spherical surface of the Earth. The effect of the topography to low degrees and orders of coefficients is estimated numerically. Formulas for the solution of the gravimetric boundary value problem are derived.

Thermo-hydraulic characteristics of ship propulsion reactor in the conditions of ship motions and safety assessment

International Nuclear Information System (INIS)

Kobayashi, Michiyuki; Murata, Hiroyuki; Sawada, Kenichi; Inasaka, Fujio; Aya, Izuo; Shiozaki, Koki

1999-01-01

By inputting the experimental data, information and others on thermo-hydraulic characteristics of integrated ship propulsion reactor accumulated hitherto by the Ship Research Institute and some recent cooperation results into the nuclear ship engineering simulation system, it was conducted not only to contribute an improvement study on next ship reactor by executing general analysis and evaluation on motion characteristics under ship body motion conditions, safety at accidents, and others of the integrated ship reactor but also to investigate and prepare some measures to apply fundamental experiment results based on obtained here information to safety countermeasure of the nuclear ships. In 1997 fiscal year, on safety of the integrated ship propulsion reactor loading nuclear ship, by adding experimental data on unstable flow analysis and information on all around of the analysis to general data base fundamental program, development to intellectual data base program was intended; on effect of pulsation flow on thermo-hydraulic characteristics of ship propulsion reactor; after pulsation flow visualization experiment, experimental equipment was reconstructed into heat transfer type to conduct numerical analysis of pulsation flow by confirming validity of numerical analysis code under comparison with the visualization experiment results; and on thermo-hydraulic behavior in storage container at accident of active safety type ship propulsion reactor; a flashing vibration test using new apparatus finished on its higher pressurization at last fiscal year to examine effects of each parameter such as radius and length of exhausting nozzle and pool water temperature. (G.K.)

Effects of physical properties on thermo-fluids cavitating flows

Science.gov (United States)

Chen, T. R.; Wang, G. Y.; Huang, B.; Li, D. Q.; Ma, X. J.; Li, X. L.

2015-12-01

The aims of this paper are to study the thermo-fluid cavitating flows and to evaluate the effects of physical properties on cavitation behaviours. The Favre-averaged Navier-Stokes equations with the energy equation are applied to numerically investigate the liquid nitrogen cavitating flows around a NASA hydrofoil. Meanwhile, the thermodynamic parameter Σ is used to assess the thermodynamic effects on cavitating flows. The results indicate that the thermodynamic effects on the thermo-fluid cavitating flows significantly affect the cavitation behaviours, including pressure and temperature distribution, the variation of physical properties, and cavity structures. The thermodynamic effects can be evaluated by physical properties under the same free-stream conditions. The global sensitivity analysis of liquid nitrogen suggests that ρv, Cl and L significantly influence temperature drop and cavity structure in the existing numerical framework, while pv plays the dominant role when these properties vary with temperature. The liquid viscosity μl slightly affects the flow structure via changing the Reynolds number Re equivalently, however, it hardly affects the temperature distribution.

Thermodynamic analysis and modeling of thermo compressor; Analyse et modelisation thermodynamique du mouvement du piston d'un thermocompresseur

Energy Technology Data Exchange (ETDEWEB)

Arques, Ph. [Ecole Centrale de Lyon, 69 - Ecully (France)

1998-07-01

A thermo-compressor is a compressor that transforms directly the heat release by a source in an energy of pressure without intermediate mechanical work. It is a conversion of the Stirling engine in driven machine in order that the piston that provides the work has been suppressed. In this article, we present the analytical and numerical analyses of heat and mass transfers modeling in the different volumes of the thermo-compressor. This engine comprises a free piston displacer that separates cold and hot gas. (author)

Physical modeling and characterization of thermo-acoustic loudspeakers made of silver nano-wire films

Science.gov (United States)

La Torraca, P.; Larcher, L.; Bobinger, M.; Pavan, P.; Seeber, B.; Lugli, P.

2017-06-01

Recent developments of ultra-low heat capacity nanostructured materials revived the interest in the thermo-acoustic (TA) loudspeaker technology, which shows important advantages compared to the classical dynamic loudspeakers as they feature a lower cost and weight, flexibility, conformability to the surface of various shapes, and transparency. The development of the TA loudspeaker technology requires accurate physical models connecting the material properties to the thermal and acoustic speaker's performance. We present here a combined theoretical and experimental analysis of TA loudspeakers, where the electro-thermal and the thermo-acoustic transductions are handled separately, thus allowing an in-depth description of both the pressure and temperature dynamics. The electro-thermal transduction is analyzed by accounting for all the heat flow processes taking place between the TA loudspeaker and the surrounding environment, with focus on their frequency dependence. The thermo-acoustic conversion is studied by solving the coupled thermo-acoustic equations, derived from the Navier-Stokes equations, and by exploiting the Huygens-Fresnel principle to decompose the TA loudspeaker surface into a dense set of TA point sources. A general formulation of the 3D pressure field is derived summing up the TA point source contributions via a Rayleigh integral. The model is validated against temperature and sound pressure level measured on the TA loudspeaker sample made of a Silver Nanowire random network deposited on a polyimide substrate. A good agreement is found between measurements and simulations, demonstrating that the model is capable of connecting material properties to the thermo-acoustic performance of the device, thus providing a valuable tool for the design and optimization of TA loudspeakers.

Integration of thermo-vapor compressor with multiple-effect evaporator

International Nuclear Information System (INIS)

Sharan, Prashant; Bandyopadhyay, Santanu

2016-01-01

Highlights: • Energy integration of thermo-vapor compressor with multiple-effect evaporator. • Proposed a new methodology for optimal placement of thermo-vapor compressor. • Extended Pinch Analysis for overall energy conservation. • Obtained simultaneous reduction in evaporator area requirement and energy consumption with optimal integration. - Abstract: Thermo-vapor compressor (TVC) is used for compressing the low-pressure vapor with the help of the high-pressure motive steam, to produce the medium pressure vapor. A substantial portion of energy may be conserved by integrating TVC with the multiple-effect evaporator (MEE). The common practice in desalination industry is to compress the vapor produced in the last effect of a MEE using TVC to reduce the overall motive steam requirement. Such integration does not necessarily guarantee energy optimality. The objective of the present work is to optimally integrate TVC with a MEE system to maximize the gain output ratio (GOR). GOR is defined as the ratio of the mass flow rate of vapor produced in MEE to the mass flow rate of the motive steam supplied to TVC. GOR is the measure of the energy efficiency of MEE system. Using the principles of Pinch Analysis and techniques of mathematical optimization, a new methodology for integration of TVC with MEE is proposed in this paper. This is the first analytical methodology to optimally integrate TVC with MEE, avoiding multiple simulations of the overall system. A Theorem is proposed to directly calculate the optimal location of TVC suction position. The proposed methodology gives the designer the freedom to design an MEE-TVC with minimum energy consumption and without carrying out the detailed simulation of the entire system. The methodology is demonstrated through the illustrative case studies for concentrating corn glucose, and freshwater production through thermal desalination. In the case of corn glucose, the optimal integration of TVC with 2-effect MEE resulted in

Dynamic and biocompatible thermo-responsive magnetic hydrogels that respond to an alternating magnetic field

Energy Technology Data Exchange (ETDEWEB)

Crippa, Federica; Moore, Thomas L.; Mortato, Mariangela; Geers, Christoph; Haeni, Laetitia [Adolphe Merkle Institute, University of Fribourg, Chemin des Verdiers 4, CH-1700 Fribourg (Switzerland); Hirt, Ann M. [Institute for Geophysics, ETH Zurich, Sonneggstrasse 5, CH-8092 Zurich (Switzerland); Rothen-Rutishauser, Barbara [Adolphe Merkle Institute, University of Fribourg, Chemin des Verdiers 4, CH-1700 Fribourg (Switzerland); Petri-Fink, Alke, E-mail: alke.fink@unifr.ch [Adolphe Merkle Institute, University of Fribourg, Chemin des Verdiers 4, CH-1700 Fribourg (Switzerland); Chemistry Department, University of Fribourg, Chemin du Musée 9, CH-1700 Fribourg Switzerland (Switzerland)

2017-04-01

Magnetic thermo-responsive hydrogels are a new class of materials that have recently attracted interest in biomedicine due to their ability to change phase upon magnetic stimulation. They have been used for drug release, magnetic hyperthermia treatment, and can potentially be engineered as stimuli-responsive substrates for cell mechanobiology. In this regard, we propose a series of magnetic thermo-responsive nanocomposite substrates that undergo cyclical swelling and de-swelling phases when actuated by an alternating magnetic field in aqueous environment. The synthetized substrates are obtained with a facile and reproducible method from poly-N-isopropylacrylamide and superparamagnetic iron oxide nanoparticles. Their conformation and the temperature-related, magnetic, and biological behaviors were characterized via scanning electron microscopy, swelling ratio analysis, vibrating sample magnetometry, alternating magnetic field stimulation and indirect viability assays. The nanocomposites showed no cytotoxicity with fibroblast cells, and exhibited swelling/de-swelling behavior near physiological temperatures (around 34 °C). Therefore these magnetic thermo-responsive hydrogels are promising materials as stimuli-responsive substrates allowing the study of cell-behavior by changing the hydrogel properties in situ. - Highlights: • A magnetic thermo-responsive hydrogel for mechanobiology is proposed. • Hydrogels change phase upon magnetic stimulation near physiological temperature. • Phase changes are reversible and triggered in an aqueous environment. • The hydrogels are biocompatible for murine fibroblast cells.

Evaluation of real-time data obtained from gravimetric preparation of antineoplastic agents shows medication errors with possible critical therapeutic impact: Results of a large-scale, multicentre, multinational, retrospective study.

Science.gov (United States)

Terkola, R; Czejka, M; Bérubé, J

2017-08-01

Medication errors are a significant cause of morbidity and mortality especially with antineoplastic drugs, owing to their narrow therapeutic index. Gravimetric workflow software systems have the potential to reduce volumetric errors during intravenous antineoplastic drug preparation which may occur when verification is reliant on visual inspection. Our aim was to detect medication errors with possible critical therapeutic impact as determined by the rate of prevented medication errors in chemotherapy compounding after implementation of gravimetric measurement. A large-scale, retrospective analysis of data was carried out, related to medication errors identified during preparation of antineoplastic drugs in 10 pharmacy services ("centres") in five European countries following the introduction of an intravenous workflow software gravimetric system. Errors were defined as errors in dose volumes outside tolerance levels, identified during weighing stages of preparation of chemotherapy solutions which would not otherwise have been detected by conventional visual inspection. The gravimetric system detected that 7.89% of the 759 060 doses of antineoplastic drugs prepared at participating centres between July 2011 and October 2015 had error levels outside the accepted tolerance range set by individual centres, and prevented these doses from reaching patients. The proportion of antineoplastic preparations with deviations >10% ranged from 0.49% to 5.04% across sites, with a mean of 2.25%. The proportion of preparations with deviations >20% ranged from 0.21% to 1.27% across sites, with a mean of 0.71%. There was considerable variation in error levels for different antineoplastic agents. Introduction of a gravimetric preparation system for antineoplastic agents detected and prevented dosing errors which would not have been recognized with traditional methods and could have resulted in toxicity or suboptimal therapeutic outcomes for patients undergoing anticancer treatment. �

Thermo-responsive magnetic liposomes for hyperthermia-triggered local drug delivery.

Science.gov (United States)

Dai, Min; Wu, Cong; Fang, Hong-Ming; Li, Li; Yan, Jia-Bao; Zeng, Dan-Lin; Zou, Tao

2017-06-01

We prepared and characterised thermo-responsive magnetic liposomes, which were designed to combine features of magnetic targeting and thermo-responsive control release for hyperthermia-triggered local drug delivery. The particle size and zeta-potential of the thermo-responsive magnetic ammonium bicarbonate (MagABC) liposomes were about 210 nm and -14 mV, respectively. The MagABC liposomes showed encapsulation efficiencies of about 15% and 82% for magnetic nanoparticles (mean crystallite size 12 nm) and doxorubicin (DOX), respectively. The morphology of the MagABC liposomes was visualised using transmission electron microscope (TEM). The MagABC liposomes showed desired thermo-responsive release. The MagABC liposomes, when physically targeted to tumour cells in culture by a permanent magnetic field yielded a substantial increase in intracellular accumulation of DOX as compared to non-magnetic ammonium bicarbonate (ABC) liposomes. This resulted in a parallel increase in cytotoxicity for DOX loaded MagABC liposomes over DOX loaded ABC liposomes in tumour cells.

Construction of database server system for fuel thermo-physical properties

International Nuclear Information System (INIS)

Park, Chang Je; Kang, Kwon Ho; Song, Kee Chan

2003-12-01

To perform the evaluation of various fuels in the nuclear reactors, not only the mechanical properties but also thermo-physical properties are required as one of most important inputs for fuel performance code system. The main objective of this study is to make a database system for fuel thermo-physical properties and a PC-based hardware system has been constructed for ease use for the public with visualization such as web-based server system. This report deals with the hardware and software which are used in the database server system for nuclear fuel thermo-physical properties. It is expected to be highly useful to obtain nuclear fuel data without such a difficulty through opening the database of fuel properties to the public and is also helpful to research of development of various fuel of nuclear industry. Furthermore, the proposed models of nuclear fuel thermo-physical properties will be enough utilized to the fuel performance code system

Analytical Expressions for Thermo-Osmotic Permeability of Clays

Science.gov (United States)

Gonçalvès, J.; Ji Yu, C.; Matray, J.-M.; Tremosa, J.

2018-01-01

In this study, a new formulation for the thermo-osmotic permeability of natural pore solutions containing monovalent and divalent cations is proposed. The mathematical formulation proposed here is based on the theoretical framework supporting thermo-osmosis which relies on water structure alteration in the pore space of surface-charged materials caused by solid-fluid electrochemical interactions. The ionic content balancing the surface charge of clay minerals causes a disruption in the hydrogen bond network when more structured water is present at the clay surface. Analytical expressions based on our heuristic model are proposed and compared to the available data for NaCl solutions. It is shown that the introduction of divalent cations reduces the thermo-osmotic permeability by one third compared to the monovalent case. The analytical expressions provided here can be used to advantage for safety calculations in deep underground nuclear waste repositories.

Fiber Optic Thermo-Hygrometers for Soil Moisture Monitoring.

Science.gov (United States)

Leone, Marco; Principe, Sofia; Consales, Marco; Parente, Roberto; Laudati, Armando; Caliro, Stefano; Cutolo, Antonello; Cusano, Andrea

2017-06-20

This work deals with the fabrication, prototyping, and experimental validation of a fiber optic thermo-hygrometer-based soil moisture sensor, useful for rainfall-induced landslide prevention applications. In particular, we recently proposed a new generation of fiber Bragg grating (FBGs)-based soil moisture sensors for irrigation purposes. This device was realized by integrating, inside a customized aluminum protection package, a FBG thermo-hygrometer with a polymer micro-porous membrane. Here, we first verify the limitations, in terms of the volumetric water content (VWC) measuring range, of this first version of the soil moisture sensor for its exploitation in landslide prevention applications. Successively, we present the development, prototyping, and experimental validation of a novel, optimized version of a soil VWC sensor, still based on a FBG thermo-hygrometer, but able to reliably monitor, continuously and in real-time, VWC values up to 37% when buried in the soil.

Determination of plutonium in pure plutonium nitrate solutions - Gravimetric method

International Nuclear Information System (INIS)

1987-01-01

This International Standard specifies a precise and accurate gravimetric method for determining the concentration of plutonium in pure plutonium nitrate solutions and reference solutions, containing between 100 and 300 g of plutonium per litre, in a nitric acid medium. The weighed portion of the plutonium nitrate is treated with sulfuric acid and evaporated to dryness. The plutonium sulfate is decomposed and formed to oxide by heating in air. The oxide is ignited in air at 1200 to 1250 deg. C and weighed as stoichiometric plutonium dioxide, which is stable and non-hygroscopic

Dynamic and biocompatible thermo-responsive magnetic hydrogels that respond to an alternating magnetic field

Science.gov (United States)

Crippa, Federica; Moore, Thomas L.; Mortato, Mariangela; Geers, Christoph; Haeni, Laetitia; Hirt, Ann M.; Rothen-Rutishauser, Barbara; Petri-Fink, Alke

2017-04-01

Magnetic thermo-responsive hydrogels are a new class of materials that have recently attracted interest in biomedicine due to their ability to change phase upon magnetic stimulation. They have been used for drug release, magnetic hyperthermia treatment, and can potentially be engineered as stimuli-responsive substrates for cell mechanobiology. In this regard, we propose a series of magnetic thermo-responsive nanocomposite substrates that undergo cyclical swelling and de-swelling phases when actuated by an alternating magnetic field in aqueous environment. The synthetized substrates are obtained with a facile and reproducible method from poly-N-isopropylacrylamide and superparamagnetic iron oxide nanoparticles. Their conformation and the temperature-related, magnetic, and biological behaviors were characterized via scanning electron microscopy, swelling ratio analysis, vibrating sample magnetometry, alternating magnetic field stimulation and indirect viability assays. The nanocomposites showed no cytotoxicity with fibroblast cells, and exhibited swelling/de-swelling behavior near physiological temperatures (around 34 °C). Therefore these magnetic thermo-responsive hydrogels are promising materials as stimuli-responsive substrates allowing the study of cell-behavior by changing the hydrogel properties in situ.

Complex investigation of thermo-technical parameters of Ruskov andesite

Directory of Open Access Journals (Sweden)

František Krepelka

2006-12-01

Full Text Available The research of thermo-technical parameters of Ruskov andesite was made as a part of the complex research of its properties as well as of rock disintegration by the action of chemical flame on the rock surface, i.e. thermal spalling in particular. Thermal spalling is a process in which thermal stresses are induced in the surface layer of rock whose surface is thereby disintegrated into small parts, the so called spalls, by the brittle manner. The evaluation of thermo-technical properties of the studied rocks is necessary for the qualification and quantification of the thermal spalling process. The measured and evaluated parameters were the coefficient of linear thermal expansion, the coefficient of thermal conductivity, the specific heat capacity and the coefficient of thermal diffusivity. Andesite from the Ruskov locality was chosen as a basic experimental material for the investigation of thermal spalling upon preliminary experiments. The estimated thermo-technical parameters were analyzed regarding the application of thermal spalling for the disintegration of the Ruskov andesite. The outcome as that the values of determine thermo-technical parameters established an expectation for its successful application.

Offshore gravimetric and subsidence monitoring

Energy Technology Data Exchange (ETDEWEB)

Stenvold, Torkjell

2008-06-15

are discussed in Stenvold et al. (Chapter 2). A latitude dependence of the calibration scale factors of Scintrex gravimeters is shown for the first time. Chapter 5 contains the article 'Constraints on the in situ density of CO2 within the Utsira formation from time-lapse seafloor gravity measurements' by Nooner et al. (2007), published in the International Journal of Greenhouse Gas Control. In this article gravity measurements made on 30 seafloor stations above the CO2 bubble in 2002 and 2005 have been used to constrain the in-situ density of CO2 for models derived from seismic. The gravity responses of various numerical models are compared for the1999 to 2001 period. Note that time-lapse seismic for the 2002-2005 period was not available when this article was written. Chapter 6 contains the article 'Monitoring both gas production and CO2 injection at the Sleipner field using time-lapse gravimetry' by Alnes et al., submitted 29 February 2008 to Geophysics. This is a renewed analysis of the same gravity data as in the article by Nooner et al. (Chapter 5). Recently available 4D seismic, a more updated reservoir simulation model, and reprocessed gravity and pressure data give a new estimate of CO2 density. The observed gravity response between 2002 and 2005 from the underlying Ty Formation is shown for the first time. Chapter 7 contains the article 'Gravimetric monitoring of gas production from the Troll field' by Eiken et al., submitted 3 April 2008 to Geophysics. The gravity data is used to map and quantify water influx on Troll between 2002 and 2005. There is good agreement with well data and the amount of water influx agrees with material balance calculations. Chapter 8 contains the article 'Gravimetric monitoring of gas reservoir water influx' a combined flow- and gravity-modeling approach' by Stenvold et al., and was accepted for publication in January 2008 by Geophysics. It is to appear in an upcoming special section on

Thermo-Fluid Verification of Fuel Column with Crossflow Gap

International Nuclear Information System (INIS)

Lee, Sung Nam; Tak, Nam Il; Kim, Min Hwan; Noh, Jae Man

2013-01-01

Korea Atomic Energy Research Institute (KAERI) has been developing thermal-hydraulic code to design a safe and effective VHTR. Core reliable Optimization and Network thermo-fluid Analysis (CORONA) is a code that solves the fluid region as 1-D and the solid domain as 3-D. The postulated event is modeled to secure safety during design process. The reactor core of VHTR is piled with multi-fuel block layers. The helium gas goes through coolant channel holes after distributed from upper plenum. The fuel blocks are irradiated during operation and there might be cross gaps between blocks. These cross gaps change the passage of coolant channels and could affect the temperature of fuel compact. Therefore, two types of single fuel assembly (i. e., standard and Reserved Shutdown Control (RSC) hole fuel assemblies) were investigated in this study. The CORONA, thermo-fluid analysis code, has been developing to compute the reactor core of VHTR. Crossflow model was applied to predict temperature and flow distribution between fuel blocks in this study. The calculated results are compared with the data of commercial software, CFX. The temperature variations along the axial direction well agree for both standard / RSC fuel assemblies. The flow redistribution due to crossflow matches well. The hot spot temperature and locations might differ depending on the cross gap size. This research will be done in detail for further study

Multi-sector thermo-physiological head simulator for headgear research

Science.gov (United States)

Martinez, Natividad; Psikuta, Agnes; Corberán, José Miguel; Rossi, René M.; Annaheim, Simon

2017-02-01

A novel thermo-physiological human head simulator for headgear testing was developed by coupling a thermal head manikin with a thermo-physiological model. As the heat flux at head-site is directly measured by the head manikin, this method provides a realistic quantification of the heat transfer phenomena occurring in the headgear, such as moisture absorption-desorption cycles, condensation, or moisture migration across clothing layers. Before coupling, the opportunities of the head manikin for representing the human physiology were evaluated separately. The evaluation revealed reduced precision in forehead and face temperature predictions under extreme heterogeneous temperature distributions and no initial limitation for simulating temperature changes observed in the human physiology. The thermo-physiological model predicted higher sweat rates when applied for coupled than for pure virtual simulations. After coupling, the thermo-physiological human head simulator was validated using eight human experiments. It precisely predicted core, mean skin, and forehead temperatures with average rmsd values within the average experimental standard deviation (rmsd of 0.20 ± 0.15, 0.83 ± 0.34, and 1.04 ± 0.54 °C, respectively). However, in case of forehead, precision was lower for the exposures including activity than for the sedentary exposures. The representation of the human sweat evaporation could be affected by a reduced evaporation efficiency and the manikin sweat dynamics. The industry will benefit from this thermo-physiological human head simulator leading to the development of helmet designs with enhanced thermal comfort and, therefore, with higher acceptance by users.

Multi-sector thermo-physiological head simulator for headgear research.

Science.gov (United States)

Martinez, Natividad; Psikuta, Agnes; Corberán, José Miguel; Rossi, René M; Annaheim, Simon

2017-02-01

A novel thermo-physiological human head simulator for headgear testing was developed by coupling a thermal head manikin with a thermo-physiological model. As the heat flux at head-site is directly measured by the head manikin, this method provides a realistic quantification of the heat transfer phenomena occurring in the headgear, such as moisture absorption-desorption cycles, condensation, or moisture migration across clothing layers. Before coupling, the opportunities of the head manikin for representing the human physiology were evaluated separately. The evaluation revealed reduced precision in forehead and face temperature predictions under extreme heterogeneous temperature distributions and no initial limitation for simulating temperature changes observed in the human physiology. The thermo-physiological model predicted higher sweat rates when applied for coupled than for pure virtual simulations. After coupling, the thermo-physiological human head simulator was validated using eight human experiments. It precisely predicted core, mean skin, and forehead temperatures with average rmsd values within the average experimental standard deviation (rmsd of 0.20 ± 0.15, 0.83 ± 0.34, and 1.04 ± 0.54 °C, respectively). However, in case of forehead, precision was lower for the exposures including activity than for the sedentary exposures. The representation of the human sweat evaporation could be affected by a reduced evaporation efficiency and the manikin sweat dynamics. The industry will benefit from this thermo-physiological human head simulator leading to the development of helmet designs with enhanced thermal comfort and, therefore, with higher acceptance by users.

Experimental aspects of buoyancy correction in measuring reliable high-pressure excess adsorption isotherms using the gravimetric method

Science.gov (United States)

Nguyen, Huong Giang T.; Horn, Jarod C.; Thommes, Matthias; van Zee, Roger D.; Espinal, Laura

2017-12-01

Addressing reproducibility issues in adsorption measurements is critical to accelerating the path to discovery of new industrial adsorbents and to understanding adsorption processes. A National Institute of Standards and Technology Reference Material, RM 8852 (ammonium ZSM-5 zeolite), and two gravimetric instruments with asymmetric two-beam balances were used to measure high-pressure adsorption isotherms. This work demonstrates how common approaches to buoyancy correction, a key factor in obtaining the mass change due to surface excess gas uptake from the apparent mass change, can impact the adsorption isotherm data. Three different approaches to buoyancy correction were investigated and applied to the subcritical CO2 and supercritical N2 adsorption isotherms at 293 K. It was observed that measuring a collective volume for all balance components for the buoyancy correction (helium method) introduces an inherent bias in temperature partition when there is a temperature gradient (i.e. analysis temperature is not equal to instrument air bath temperature). We demonstrate that a blank subtraction is effective in mitigating the biases associated with temperature partitioning, instrument calibration, and the determined volumes of the balance components. In general, the manual and subtraction methods allow for better treatment of the temperature gradient during buoyancy correction. From the study, best practices specific to asymmetric two-beam balances and more general recommendations for measuring isotherms far from critical temperatures using gravimetric instruments are offered.

Library of neutron cross sections of the Thermos code

International Nuclear Information System (INIS)

Alonso V, G.; Hernandez L, H.

1991-10-01

The present work is the complement of the IT.SN/DFR-017 report in which the structure and the generation of the library of the Thermos code is described. In this report the comparison among the values of the cross sections that has the current library of the Thermos code and those generated by means of the ENDF-B/NJOY it is shown. (Author)

Thermo-hydric characterization of partially saturated porous media; Caracterisation thermo-hydrique de milieux poreux partiellement satures d'eau

Energy Technology Data Exchange (ETDEWEB)

Simon Salager; Frederic Jamin; Moulay Said El Youssoufi; Christian Saix [Laboratoire de Mecanique et Genie Civil, Universite Montpellier II, cc 048, Place Eugene Bataillon, 34095 Montpellier (France)

2005-07-01

We present a contribution to the thermo-hydric characterization of partially saturated porous media by water, through the characteristic curve. This curve defines the relation between suction and degree of saturation. Using this curve for a given temperature, a model is used to predict it for other temperatures. An experimental device called pressure cell was made in a thermo-regulated environment. The model was validated by several tests on a ceramic and silty clayey sand, at 20 and 60 C. The results obtained lead to a characteristic surface which can be considered as a generalization of the classical characteristic curve. (authors)

Study of the corrosion behavior of magnesium alloy weldings in NaCl solutions by gravimetric tests

Directory of Open Access Journals (Sweden)

Segarra, José A.

2015-09-01

Full Text Available In this article, the corrosion behavior of commercial AZ31 welded plates in aqueous chloride media was investigated by means of gravimetric techniques and Neutral Salt Spray tests (NSS. The AZ31 samples tested were welded using Gas Tugsten Arc Welding (GTAW and different filler materials. Material microstructures were investigated by optical microscopy to stablish the influence of those microstructures in the corrosion behavior. Gravimetric and NSS tests indicate that the use of more noble filler alloys for the sample welding, preventing the reduction of aluminum content in weld beads, does not imply a better corrosion behavior.En este artículo se ha investigado el comportamiento frente a la corrosión en medios acuosos salinos de chapas soldadas de aleación AZ31 mediante técnicas gravimétricas y ensayo en cámara de niebla salina. Las muestras estudiadas han sido soldadas mediante soldadura TIG (Tungsten Inert Gas y con diferentes materiales de aporte. En el estudio se ha empleado microscopía óptica para analizar la microestructura. Los ensayos de gravimetría y los ensayos de niebla salina indican que el empleo de materiales de aporte más nobles para soldar las muestras evitando la disminución del contenido en aluminio en los cordones, no implica un mejor comportamiento frente a la corrosión.

General thermo-elastic solution of radially heterogeneous, spherically isotropic rotating sphere

Energy Technology Data Exchange (ETDEWEB)

Bayat, Yahya; EkhteraeiToussi, THamid [Ferdowsi University of Mashhad, Mashhad (Iran, Islamic Republic of)

2015-06-15

A thick walled rotating spherical object made of transversely isotropic functionally graded materials (FGMs) with general types of thermo-mechanical boundary conditions is studied. The thermo-mechanical governing equations consisting of decoupled thermal and mechanical equations are represented. The centrifugal body forces of the rotation are considered in the modeling phase. The unsymmetrical thermo-mechanical boundary conditions and rotational body forces are expressed in terms of the Legendre series. The series method is also implemented in the solution of the resulting equations. The solutions are checked with the known literature and FEM based solutions of ABAQUS software. The effects of anisotropy and heterogeneity are studied through the case studies and the results are represented in different figures. The newly developed series form solution is applicable to the rotating FGM spherical transversely isotropic vessels having nonsymmetrical thermo-mechanical boundary condition.

Sensitivity analyses of biodiesel thermo-physical properties under diesel engine conditions

DEFF Research Database (Denmark)

Cheng, Xinwei; Ng, Hoon Kiat; Gan, Suyin

2016-01-01

This reported work investigates the sensitivities of spray and soot developments to the change of thermo-physical properties for coconut and soybean methyl esters, using two-dimensional computational fluid dynamics fuel spray modelling. The choice of test fuels made was due to their contrasting...... saturation-unsaturation compositions. The sensitivity analyses for non-reacting and reacting sprays were carried out against a total of 12 thermo-physical properties, at an ambient temperature of 900 K and density of 22.8 kg/m3. For the sensitivity analyses, all the thermo-physical properties were set...... as the baseline case and each property was individually replaced by that of diesel. The significance of individual thermo-physical property was determined based on the deviations found in predictions such as liquid penetration, ignition delay period and peak soot concentration when compared to those of baseline...

On three-dimensional nuclear thermo-hydraulic computation techniques for ATR

International Nuclear Information System (INIS)

1997-08-01

The three-dimensional computation code for nuclear thermo-hydraulic combination core LAYMON-2A is used for the calculation of the power distribution and the control rod reactivity value of the ATR. This code possesses various functions which are required for planning the core operation such as the search function for critical boric acid concentration, and can do various simulation calculations such as core burning calculation. Further, the three-dimensional analysis code for xenon dynamic characteristics in the core LAYMON-2C, in which the dynamic characteristic equation of xenon-samarium was incorporated into the LAYMON-2A code can take the change with time lapse of xenon-samarium concentration accompanying the change of power level and power distribution into account, and it is used for the analysis of the spatial vibration characteristics of power and the regional power control characteristics due to xenon in the core. As to the LAYMON-2A, the computation flow, power distribution and thermo-hydraulic computation models, and critical search function are explained. As to the LAYMON-2C, the computation flow is described. The comparison of the calculated values by using the LAYMON-2A code and the operation data of the Fugen is reported. (K.I.)

Athermalization of resonant optical devices via thermo-mechanical feedback

Science.gov (United States)

Rakich, Peter; Nielson, Gregory N.; Lentine, Anthony L.

2016-01-19

A passively athermal photonic system including a photonic circuit having a substrate and an optical cavity defined on the substrate, and passive temperature-responsive provisions for inducing strain in the optical cavity of the photonic circuit to compensate for a thermo-optic effect resulting from a temperature change in the optical cavity of the photonic circuit. Also disclosed is a method of passively compensating for a temperature dependent thermo-optic effect resulting on an optical cavity of a photonic circuit including the step of passively inducing strain in the optical cavity as a function of a temperature change of the optical cavity thereby producing an elasto-optic effect in the optical cavity to compensate for the thermo-optic effect resulting on an optical cavity due to the temperature change.

Thermo-hydro-mechanical behaviour of Boom clay; Comportement thermo-hydro-mecanique de l'argile de Boom

Energy Technology Data Exchange (ETDEWEB)

Le, T.T

2008-01-15

This thesis studied the thermo-hydro-mechanical properties of Boom clay, which was chosen to be the host material for the radioactive waste disposal in Mol, Belgium. Firstly, the research was concentrated on the soil water retention properties and the hydro-mechanical coupling by carrying out axial compression tests with suction monitoring. The results obtained permitted elaborating a rational experimental procedure for triaxial tests. Secondly, the systems for high pressure triaxial test at controlled temperature were developed to carry out compression, heating, and shearing tests at different temperatures. The obtained results showed clear visco-elasto-plastic behaviour of the soil. This behaviour was modelled by extending the thermo-elasto-plastic model of Cui et al. (2000) to creep effect. (author)

Comparison Of Metal Corrosion Inhibition By Gravimetric And Linear Polarization Resistance Methods

OpenAIRE

Banerji, Shankha

1992-01-01

Studies were conducted to evaluate the effectiveness of various dosages of the selected silicate and phosphate compounds applied for corrosion inhibition of cast iron, copper, lead, and galvanized steel specimens. The compounds selected for study were zinc polyphosphate (Calgon C-39), zinc orthophosphate (Virchem V-931), sodium metasilicate and glassy silicate. The effectiveness of these compounds for corrosion inhibition were studied under differing water quality conditions using gravimetric...

Thermo-ecological optimization of a solar collector

International Nuclear Information System (INIS)

Szargut, J.; Stanek, W.

2007-01-01

The depletion of non-renewable natural exergy resources (the thermo-ecological cost) has been accepted as the objective function for thermo-ecological optimization. Its general formulation has been cited. A detailed form of the objective function has been formulated for a solar collector producing hot water for household needs. The following design parameters have been accepted as the decision variables: the collector area per unit of the heat demand, the diameter of collector pipes, the distance of the pipe axes in the collector plate. The design parameters of the internal installation (the pipes, the hot water receiver) have not been taken into account, because they are very individual. The accumulation ability of hot water comprising one day has been assumed. The objective function contains the following components: the thermo-ecological cost of copper plate, copper pipes, glass plate, steel box, thermal insulation, heat transfer liquid, electricity for driving the pump of liquid, fuel for the peak boiler. The duration curves of the flux of solar radiation and absorbed heat have been elaborated according to meteorological data and used in the calculations. The objective function for economic optimization may have a similar form, only the cost values would be different

Ground source thermo-pumps for individual residential houses; Les thermopompes a capteur enterres dans les residences individuelles

Energy Technology Data Exchange (ETDEWEB)

Ossant, G. [Societe Syrec (France)

1997-12-31

The main principles, performances and constraints of the various types of ground source thermo-pumps for individual houses, i.e. ground/ground thermo-pumps, glycol water/water thermo-pumps and ground/water thermo-pumps are reviewed, and their energy consumptions are discussed. The design and operating conditions of a reverse ground source thermo-pump (Syrec) for space heating and air conditioning through a hot and cold floor system and a Syrec ground source thermo-pump for water heating, are presented

Forced synchronization and asynchronous quenching in a thermo-acoustic system

Science.gov (United States)

Mondal, Sirshendu; Pawar, Samadhan A.; Sujith, Raman

2017-11-01

Forced synchronization, which has been extensively studied in theory and experiments, occurs through two different mechanisms known as phase locking and asynchronous quenching. The latter indicates the suppression of oscillation amplitude. In most practical combustion systems such as gas turbine engines, the main concern is high amplitude pressure oscillations, known as thermo-acoustic instability. Thermo-acoustic instability is undesirable and needs to be suppressed because of its damaging consequences to an engine. In the present study, a systematic experimental investigation of forced synchronization is performed in a prototypical thermo-acoustic system, a Rijke tube, in its limit cycle operation. Further, we show a qualitatively similar behavior using a reduced order model. In the phase locking region, the simultaneous occurrence of synchronization and resonant amplification leads to high amplitude pressure oscillations. However, a reduction in the amplitude of natural oscillations by about 78% of the unforced amplitude is observed when the forcing frequency is far lower than the natural frequency. This shows the possibility of suppression of the oscillation amplitude through asynchronous quenching in thermo-acoustic systems.

A thermo-degradable hydrogel with light-tunable degradation and drug release.

Science.gov (United States)

Hu, Jingjing; Chen, Yihua; Li, Yunqi; Zhou, Zhengjie; Cheng, Yiyun

2017-01-01

The development of thermo-degradable hydrogels is of great importance in drug delivery. However, it still remains a huge challenge to prepare thermo-degradable hydrogels with inherent degradation, reproducible, repeated and tunable dosing. Here, we reported a thermo-degradable hydrogel that is rapidly degraded above 44 °C by a facile chemistry. Besides thermo-degradability, the hydrogel also undergoes rapid photolysis with ultraviolet light. By embedding photothermal nanoparticles or upconversion nanoparticles into the gel, it can release the entrapped cargoes such as dyes, enzymes and anticancer drugs in an on-demand and dose-tunable fashion upon near-infrared light exposure. The smart hydrogel works well both in vitro and in vivo without involving sophisticated syntheses, and is well suited for clinical cancer therapy due to the high transparency and non-invasiveness features of near-infrared light. Copyright © 2016 Elsevier Ltd. All rights reserved.

Thermo-siphon Mock-up Test for the HANARO-CNS

Energy Technology Data Exchange (ETDEWEB)

Choi, Jungwoon; Lee, Kye Hong; Kim, Hark Rho; Kim, Youngki; Kim, Myong Seop; Wu, Sang Ik; Kim, Bong Su

2006-04-15

In order to moderate thermal neutrons into cold neutrons, the liquid hydrogen is selected as a moderator for the HANARO CNS. By the non-nuclear heat load and nuclear heat load induced from collision of gamma-ray, beta-ray, and thermal neutrons, the liquid hydrogen in the moderator cell evaporates and flows into the heat exchanger. This evaporated hydrogen gas is liquefied by the cryogenic helium supplied from the helium refrigeration system,, then flows back to the moderator cell. This is so-called two-phase thermo-siphon. The most important point in the stable thermo-siphon is to have the good balance between the cooling capacity of the HRS and the heat load on the moderator cell so as to maintain the stable two-phase liquid level in the moderator cell. Accordingly, for not only the experience of the cryogenic two-phase thermo-siphon but also setup of the operation procedure, the full-scaled mock-up test has been performed using the liquid hydrogen. Through the test, the stable thermo-siphon establishment is confirmed at the cold normal operation; furthermore, the detail design parameter is validated. On top of the normal operation procedure setup, the abnormal operation procedure is settled based on the understanding the abnormal pressure and temperature transient dynamics in the hydrogen system.

Photometrically measured continuous personal PM(2.5) exposure: levels and correlation to a gravimetric method.

Science.gov (United States)

Lanki, Timo; Alm, Sari; Ruuskanen, Juhani; Janssen, Nicole A H; Jantunen, Matti; Pekkanen, Juha

2002-05-01

There is evidence that hourly variations in exposure to airborne particulate matter (PM) may be associated with adverse health effects. Still there are only few published data on short-term levels of personal exposure to PM in community settings. The objectives of the study were to assess hourly and shorter-term variations in personal PM(2.5) exposure in Helsinki, Finland, and to compare results from portable photometers to simultaneously measured gravimetric concentrations. The effect of relative humidity on the photometric results was also evaluated. Personal PM(2.5) exposures of elderly persons were assessed for 24 h every second week, resulting in 308 successful measurements from 47 different subjects. Large changes in concentrations in minutes after cooking or changing microenvironment were seen. The median of daily 1-h maxima was over twice the median of 24-h averages. There was a strong significant association between the two means, which was not linear. Median (95th percentile) of the photometric 24-h concentrations was 12.1 (37.7) and of the 24-h gravimetric concentrations 9.2 (21.3) microg/m3. The correlation between the photometric and the gravimetric method was quite good (R2=0.86). Participants spent 94.1% of their time indoors or in a vehicle, where relative humidity is usually low and thus not likely to cause significant effects on photometric results. Even outdoors, the relative humidity had only modest effect on concentrations. Photometers are a promising method to explore the health effects of short-term variation in personal PM(2.5) exposure.

Characterization of a Thermo-Inducible Chlorophyll-Deficient Mutant in Barley

Directory of Open Access Journals (Sweden)

Rong Wang

2017-11-01

Full Text Available Leaf color is an important trait for not only controlling crop yield but also monitoring plant status under temperature stress. In this study, a thermo-inducible chlorophyll-deficient mutant, named V-V-Y, was identified from a gamma-radiated population of the barley variety Vlamingh. The leaves of the mutant were green under normal growing temperature but turned yellowish under high temperature in the glasshouse experiment. The ratio of chlorophyll a and chlorophyll b in the mutant declined much faster in the first 7–9 days under heat treatment. The leaves of V-V-Y turned yellowish but took longer to senesce under heat stress in the field experiment. Genetic analysis indicated that a single nuclear gene controlled the mutant trait. The mutant gene (vvy was mapped to the long arm of chromosome 4H between SNP markers 1_0269 and 1_1531 with a genetic distance of 2.2 cM and a physical interval of 9.85 Mb. A QTL for grain yield was mapped to the same interval and explained 10.4% of the yield variation with a LOD score of 4. This QTL is coincident with the vvy gene interval that is responsible for the thermo-inducible chlorophyll-deficient trait. Fine mapping, based on the barley reference genome sequence, further narrowed the vvy gene to a physical interval of 0.428 Mb with 11 annotated genes. This is the first report of fine mapping a thermo-inducible chlorophyll-deficient gene in barley.

Effect of Nb2O5 doping on improving the thermo-mechanical stability of sealing interfaces for solid oxide fuel cells.

Science.gov (United States)

Zhang, Qi; Du, Xinhang; Tan, Shengwei; Tang, Dian; Chen, Kongfa; Zhang, Teng

2017-07-13

Nb 2 O 5 is added to a borosilicate sealing system to improve the thermo-mechanical stability of the sealing interface between the glass and Fe-Cr metallic interconnect (Crofer 22APU) in solid oxide fuel cells (SOFCs). The thermo-mechanical stability of the glass/metal interface is evaluated experimentally as well as by using a finite element analysis (FEA) method. The sealing glass doped with 4 mol.% Nb 2 O 5 shows the best thermo-mechanical stability, and the sealing couple of Crofer 22APU/glass/GDC (Gd 0.2 Ce 0.8 O 1.9 ) remains intact after 50 thermal cycles. In addition, all sealing couples show good joining after being held at 750 °C for 1000 h. Moreover, the possible mechanism on the thermo-mechanical stability of sealing interface is investigated in terms of stress-based and energy-based perspectives.

Degradation of polylactic acid (Pla) at different doses of gamma radiation

International Nuclear Information System (INIS)

Castillo R, Y.

2015-01-01

The excessive use of polymers such as polyethylene (PET), polystyrene (Ps) and recently the polylactic acid (Pla) that take more than 20 years to degrade, have caused great pollution in the environment. In this study the effects of gamma radiation in the Pla to different doses were studied, in order to reduce the degradation time of this polymer. The changes in physico-chemical structure of Pla during radiation were studied by thermo-gravimetric/Mass analysis; differential scanning calorimetry; scanning electron microscopy; X-ray dispersive analysis; infrared spectroscopy; X-ray diffraction and mechanical tests of hardness, elasticity and deformation. With scanning electron microscopy, the morphology of the Pla surface unirradiated was observed, in which an apparently smooth surface was observed, after changes that had the Pla when irradiated also was observed, where the effects of radiation were observed in form of scratch, agglomeration and small fractures. By X-ray dispersive analysis was determined and verified the elemental chemical composition of the Pla; as expected the tests showed only carbon, oxygen and hydrogen. With thermo-gravimetric/Mass analysis the decomposition temperatures of Pla were determined, identifying that the degradation compounds are CO, CO 2 and CH 4 . With infrared spectrometry the major peaks of Pla were observed before and after being irradiated with increasing of radiation dose the intensity of the bands decreased. Also by X-ray diffraction was observed that the polymer is an amorphous material. The mechanical tests indicate that the values of each of the tests decrease significantly with increasing the radiation dose. (Author)

Degradation of polylactic acid (Pla) at different doses of gamma radiation; Degradacion del acido polilactico (PLA) a diferentes dosis de radiacion gamma

Energy Technology Data Exchange (ETDEWEB)

Castillo R, Y.

2015-07-01

The excessive use of polymers such as polyethylene (PET), polystyrene (Ps) and recently the polylactic acid (Pla) that take more than 20 years to degrade, have caused great pollution in the environment. In this study the effects of gamma radiation in the Pla to different doses were studied, in order to reduce the degradation time of this polymer. The changes in physico-chemical structure of Pla during radiation were studied by thermo-gravimetric/Mass analysis; differential scanning calorimetry; scanning electron microscopy; X-ray dispersive analysis; infrared spectroscopy; X-ray diffraction and mechanical tests of hardness, elasticity and deformation. With scanning electron microscopy, the morphology of the Pla surface unirradiated was observed, in which an apparently smooth surface was observed, after changes that had the Pla when irradiated also was observed, where the effects of radiation were observed in form of scratch, agglomeration and small fractures. By X-ray dispersive analysis was determined and verified the elemental chemical composition of the Pla; as expected the tests showed only carbon, oxygen and hydrogen. With thermo-gravimetric/Mass analysis the decomposition temperatures of Pla were determined, identifying that the degradation compounds are CO, CO{sub 2} and CH{sub 4}. With infrared spectrometry the major peaks of Pla were observed before and after being irradiated with increasing of radiation dose the intensity of the bands decreased. Also by X-ray diffraction was observed that the polymer is an amorphous material. The mechanical tests indicate that the values of each of the tests decrease significantly with increasing the radiation dose. (Author)

Analysis of briquetting process of sewage sludge with coal to combustion process

Directory of Open Access Journals (Sweden)

Kosturkiewicz Bogdan

2016-01-01

Full Text Available Energy recovery from sewage sludge can be achieved by several thermal technologies, but before those processes sewage sludge requires special pretreatment. The paper presents the investigation of the sewage sludge with coal briquettes as a fuel for combustion process. Research is conducted at Department of Manufacturing Systems and Department of Thermal Engineering and Environmental Protection, AGH University of Science and Technology to develop a technology of briquette preparation. The obtained results showed possibility of briquetting of municipal sewage sludge with coal in roll presses, equipped with asymmetric thickening gravity feed system. The following properties were determined for the obtained briquettes: density, drop strength and compressive strength. Based on physical and chemical analysis of prepared briquettes it was confirmed that briquettes have good fuel properties to combustion process. Thermal behaviour of studied sewage sludge and prepared mixture was investigated by thermogravimetric analysis (TG. For the thermo gravimetric analysis (TG the samples were heated in an alumina crucible from an ambient temperature up to 1000 °C at a constant rates: 10 °C/min, 40 °C/min and 100 °C/min in a 40 ml/min flow of air.

Thermo-mechanical properties of SOFC components investigated by a combined method

DEFF Research Database (Denmark)

Teocoli, Francesca; Esposito, Vincenzo; Ramousse, Severine

, and differential thermo-mechanical behavior at each layer. The combination of such factors can have a critical effect on the final shape and microstructure, and on the mechanical integrity. Thermo-mechanical properties and sintering mechanisms of important SOFC materials (CGO, YSZ, ScYSZ) were systematically...

Several new thermo-hydraulic test facilities in NPIC

International Nuclear Information System (INIS)

Ye Shurong; Sun Yufa; Ji Fuyun; Zong Guifang; Guo Zhongchuan

1997-01-01

Several new thermo-hydraulic test facilities are under construction in Nuclear Power Institute of Chinese (NPIC) at Chengdu. These facilities include: 1. Nuclear Power Component Comprehensive Test Facility. 2. Reactor Hydraulic Modeling Test Facility. 3. Control Rod Drive Line Hydraulic Test Facility. 4. Large Scale Thermo-Hydraulic Test Facility. The construction of these facilities will make huge progress in the research and development capability of nuclear power technology in CHINA. The author will present a brief description of the design parameters flowchart and test program of these facilities

A new and simple gravimetric method for determination of uranium

International Nuclear Information System (INIS)

Saxena, A.K.

1994-01-01

A new and simple gravimetric method for determining uranium has been described. Using a known quantity of uranyl nitrate as the test solution, an alcoholic solution of 2-amino-2-methyl 1:3 propanediol (AMP) was added slowly. A yellow precipitate was obtained which was filtered through ashless filter paper, washed with alcohol, dried and ignited at 800 degC for 4h. It gave a black powder as a product which was shown by X-ray diffraction to be U 3 O 8 . The percentage error was found in the range -0.09 to +0.89. (author). 8 refs., 1 tab

The Metabolic Basis of Pollen Thermo-Tolerance: Perspectives for Breeding

Directory of Open Access Journals (Sweden)

Marine J. Paupière

2014-09-01

Full Text Available Crop production is highly sensitive to elevated temperatures. A rise of a few degrees above the optimum growing temperature can lead to a dramatic yield loss. A predicted increase of 1–3 degrees in the twenty first century urges breeders to develop thermo-tolerant crops which are tolerant to high temperatures. Breeding for thermo-tolerance is a challenge due to the low heritability of this trait. A better understanding of heat stress tolerance and the development of reliable methods to phenotype thermo-tolerance are key factors for a successful breeding approach. Plant reproduction is the most temperature-sensitive process in the plant life cycle. More precisely, pollen quality is strongly affected by heat stress conditions. High temperature leads to a decrease of pollen viability which is directly correlated with a loss of fruit production. The reduction in pollen viability is associated with changes in the level and composition of several (groups of metabolites, which play an important role in pollen development, for example by contributing to pollen nutrition or by providing protection to environmental stresses. This review aims to underline the importance of maintaining metabolite homeostasis during pollen development, in order to produce mature and fertile pollen under high temperature. The review will give an overview of the current state of the art on the role of various pollen metabolites in pollen homeostasis and thermo-tolerance. Their possible use as metabolic markers to assist breeding programs for plant thermo-tolerance will be discussed.

The metabolic basis of pollen thermo-tolerance: perspectives for breeding.

Science.gov (United States)

Paupière, Marine J; van Heusden, Adriaan W; Bovy, Arnaud G

2014-09-30

Crop production is highly sensitive to elevated temperatures. A rise of a few degrees above the optimum growing temperature can lead to a dramatic yield loss. A predicted increase of 1-3 degrees in the twenty first century urges breeders to develop thermo-tolerant crops which are tolerant to high temperatures. Breeding for thermo-tolerance is a challenge due to the low heritability of this trait. A better understanding of heat stress tolerance and the development of reliable methods to phenotype thermo-tolerance are key factors for a successful breeding approach. Plant reproduction is the most temperature-sensitive process in the plant life cycle. More precisely, pollen quality is strongly affected by heat stress conditions. High temperature leads to a decrease of pollen viability which is directly correlated with a loss of fruit production. The reduction in pollen viability is associated with changes in the level and composition of several (groups of) metabolites, which play an important role in pollen development, for example by contributing to pollen nutrition or by providing protection to environmental stresses. This review aims to underline the importance of maintaining metabolite homeostasis during pollen development, in order to produce mature and fertile pollen under high temperature. The review will give an overview of the current state of the art on the role of various pollen metabolites in pollen homeostasis and thermo-tolerance. Their possible use as metabolic markers to assist breeding programs for plant thermo-tolerance will be discussed.

Thermo-mechanical design of the SINGAP accelerator grids for ITER NB Injectors

International Nuclear Information System (INIS)

Agostinetti, P.; Dal Bello, S.; Palma, M.D.; Zaccaria, P.

2006-01-01

The SINGle Aperture - SINgle GAP (SINGAP) accelerator for ITER neutral beam injector foresees four grids for the extraction and acceleration of negative ions, instead of the seven grids of the Multi Aperture Multi Grid (MAMuG) reference configuration. Optimized geometry of the SINGAP grids (plasma, extraction, pre-acceleration, and grounded grid) was identified by CEA Association considering specific requirements for ions extraction and beam generation referring to experimental data and code simulations. This paper focuses on the thermo-hydraulic and thermo-mechanical design of the grids carried out by Consorzio RFX for the design of the first ITER NB Injector and the ITER NB Test Facility. The cooling circuit design (position and shape of the channels) and the cooling parameters (water coolant temperatures, pressure and velocity) were optimized with thermo-hydraulic and thermo-mechanical sensitivity analyses in order to satisfy the grid functional requirements (temperatures, in plane and out of plane deformations). A complete and detailed thermo-structural design assessment of the SINGAP grids was accomplished applying the structural design rules for ITER in-vessel components and considering both the reference load conditions and the maximum load provided by the power supplies. The design required a complete modelling of the grids and their support frames by means of 3D FE and CAD models. The grids were finally integrated with the support and cooling systems inside the beam source vessel. The main results of the thermo-hydraulic and thermo-mechanical analyses are presented. The open issues are then reported, mainly regarding the material properties characterization (static and fatigue tests) and the qualification of technologies for OFHC copper electro-deposition, brazing, and welding of heterogeneous materials. (author)

ThermoMap. Interactive analysis and information system for the area-selected evaluation of the near-surface geothermal potential; ThermoMap. Interaktives Analyse- und Auskunftssystem zur flaechenhaften Abschaetzung des oberflaechennahen geothermischen Potenzials

Energy Technology Data Exchange (ETDEWEB)

Bertemann, David [Erlangen-Nuernberg Univ., Erlangen (DE). Lehrstuhl fuer Geologie (Exogene Dynamik); Psyk, Mario [REHAU AG and CO, Erlangen-Eltersdorf (Germany)

2012-07-01

The project ThermoMap funded by the European Commission enables a comprehensive assessment of the near-surface geothermal energy potential from already existing geoscientific data sets. Currently, twelve partners from nine EU Member States are involved.

Thermo-Optic Characterization of Silicon Nitride Resonators for Cryogenic Photonic Circuits

NARCIS (Netherlands)

Elshaari, A.W.A.; Esmaeil Zadeh, I.; Jöns, K.D.; Zwiller, Val

2016-01-01

In this paper, we characterize the Thermo-optic properties of silicon nitride ring resonators between 18 and 300 K. The Thermo-optic coefficients of the silicon nitride core and the oxide cladding are measured by studying the temperature dependence of the resonance wavelengths. The resonant modes

Tectonic evolution of the Paranoá basin: New evidence from gravimetric and stratigraphic data

Science.gov (United States)

Martins-Ferreira, Marco Antonio Caçador; Campos, José Eloi Guimarães; Von Huelsen, Monica Giannoccaro

2018-06-01

Field gravimetric and stratigraphic surveys were conducted with the aim to constraint the mechanisms responsible for the initiation of the Stenian-Tonian Paranoá basin, central Brazil, a subject not yet studied in detail. The Paranoá Group crops out in the external zone of the Brasília Belt, a Neoproterozoic orogen in the western margin of the São Francisco Craton. Detailed geological mapping confirmed the existence of a regional scale fault that controlled sedimentation of the Paranoá Group during the deposition of its basal formations, revealing important details about basin initiation and early evolution. Gravimetric modeling indicates the existence of paleorift structures beneath the Paranoá sequence in the study area. Results from both stratigraphic and gravimetric surveys show strong evidence of mechanical subsidence by faulting during basin initiation. Unsorted, angular, clasts cut by quartz veins and brecciated boulders present in the basal conglomerate, support this hypothesis. Basin initiation faults coincide with deeper paleorift faults and are thus interpreted as reactivations of the older Statherian Araí Rift. The reactivations favored an initial regime of mechanical subsidence, dominated by the development of epirogenic arches subsiding at different rates. Apart from faulting activity, the post-basal sequence presents no evidence of rift environment in the strict sense. Besides, the great lateral continuity and relatively constant thickness of facies, indicate that an initial mechanic subsidence rapidly gave way to flexural subsidence during subsequent stages of basin evolution. The Paranoá Group do not present reliable characteristics that would allow its strict classification as a passive margin. Its main stratigraphic characteristics, tectonic location and basement architecture, indicate that the Paranoá Group was deposited in a cratonic margin basin, and may have been either connected to a passive margin basin at times of sea level rise

Synthesis, characterization and antifungal studies of metalloquinolone [Cd2(nal2(phen2(Cl2

Directory of Open Access Journals (Sweden)

A. Debnath

2014-12-01

Full Text Available A novel dinuclear, distorted octahedral complex of nalidixic acid (nal with Cd(II metal ion with the formula [Cd2(Nal2(Phen2(Cl2] has been synthesized in the presence of N-containing heterocyclic ligand, 1,10-phenanthroline (phen. The synthesized metal complex was characterized using CHN analysis, Fourier transformed infra-red, thermo gravimetric analysis, differential scanning chalorimetry, nuclear magnetic resonance, ultra violet-visible and single-crystal X-ray diffraction. The newly synthesized complex shows more pronounced antifungal activity compared with the parent quinolone against four fungi, namely Pythium aphanidermatum, Sclerotinia rolfsii, Rhizoctonia solani and Rhizoctonia bataticola.

Thermal energy storage using thermo-chemical heat pump

International Nuclear Information System (INIS)

Hamdan, M.A.; Rossides, S.D.; Haj Khalil, R.

2013-01-01

Highlights: ► Understanding of the performance of thermo chemical heat pump. ► Tool for storing thermal energy. ► Parameters that affect the amount of thermal stored energy. ► Lithium chloride has better effect on storing thermal energy. - Abstract: A theoretical study was performed to investigate the potential of storing thermal energy using a heat pump which is a thermo-chemical storage system consisting of water as sorbet, and sodium chloride as the sorbent. The effect of different parameters namely; the amount of vaporized water from the evaporator, the system initial temperature and the type of salt on the increase in temperature of the salt was investigated and hence on the performance of the thermo chemical heat pump. It was found that the performance of the heat pump improves with the initial system temperature, with the amount of water vaporized and with the water remaining in the system. Finally it was also found that lithium chloride salt has higher effect on the performance of the heat pump that of sodium chloride.

A cost-effective technique for integrating personal radiation dose assessment with personal gravimetric sampling

International Nuclear Information System (INIS)

Strydom, R.; Rolle, R.; Van der Linde, A.

1992-01-01

During recent years there has been an increasing awareness internationally of radiation levels in the mining and milling of radioactive ores, including those from non-uranium mines. A major aspect of radiation control is concerned with the measurement of radiation levels and the assessment of radiation doses incurred by individual workers. Current techniques available internationally for personnel monitoring of radiation exposures are expensive and there is a particular need to reduce the cost of personal radiation monitoring in South African gold mines because of the large labour force employed. In this regard the obvious benefits of integrating personal radiation monitoring with existing personal monitoring systems already in place in South African gold mines should be exploited. A system which can be utilized for this purpose is personal gravimetric sampling. A new cost-effective technique for personal radiation monitoring, which can be fully integrated with the personal gravimetric sampling strategy being implemented on mines, has been developed in South Africa. The basic principles of this technique and its potential in South African mines are described. 9 refs., 7 figs

Determination of uranium in coated fuel particle compact by potassium fluoride fusion-gravimetric method

International Nuclear Information System (INIS)

Ito, Mitsuo; Iso, Shuichi; Hoshino, Akira; Suzuki, Shuichi.

1992-03-01

Potassium fluoride-gravimetric method has been developed for the determination of uranium in TRISO type-coated fuel particle compact. Graphite matrix in the fuel compact is burned off by heating it in a platinum crucible at 850degC. The coated fuel particles thus obtained are decomposed by fusion with potassium fluoride at 900degC. The melt was dissolved with sulfuric acid. Uranium is precipitated as ammonium diuranate, by passing ammonia gas through the solution. The resulting precipitate is heated in a muffle furnace at 850degC, to convert uranium into triuranium octoxide. Uranium in the triuranium octoxide was determined gravimetrically. Ten grams of caoted fuel particles were completely decomposed by fusion with 50 g of potassium fluoride at 900degC for 3 hrs. Analytical result for uranium in the fuel compact by the proposed method was 21.04 ± 0.05 g (n = 3), and was in good agreement with that obtained by non-destructive γ-ray measurement method : 21.01 ± 0.07 g (n = 3). (author)

Temperature calibration procedure for thin film substrates for thermo-ellipsometric analysis using melting point standards

International Nuclear Information System (INIS)

Kappert, Emiel J.; Raaijmakers, Michiel J.T.; Ogieglo, Wojciech; Nijmeijer, Arian; Huiskes, Cindy; Benes, Nieck E.

2015-01-01

Highlights: • Facile temperature calibration method for thermo-ellipsometric analysis. • The melting point of thin films of indium, lead, zinc, and water can be detected by ellipsometry. • In-situ calibration of ellipsometry hot stage, without using any external equipment. • High-accuracy temperature calibration (±1.3 °C). - Abstract: Precise and accurate temperature control is pertinent to studying thermally activated processes in thin films. Here, we present a calibration method for the substrate–film interface temperature using spectroscopic ellipsometry. The method is adapted from temperature calibration methods that are well developed for thermogravimetric analysis and differential scanning calorimetry instruments, and is based on probing a transition temperature. Indium, lead, and zinc could be spread on a substrate, and the phase transition of these metals could be detected by a change in the Ψ signal of the ellipsometer. For water, the phase transition could be detected by a loss of signal intensity as a result of light scattering by the ice crystals. The combined approach allowed for construction of a linear calibration curve with an accuracy of 1.3 °C or lower over the full temperature range

ε-Polylysine-based thermo-responsive adsorbents for immunoglobulin adsorption-desorption under mild conditions.

Science.gov (United States)

Maruyama, Masashi; Shibuya, Keisuke

2017-08-22

Thermo-responsive adsorbents for immunoglobulin G (IgG) employing ε-polylysine (EPL) as a polymer backbone were developed. The introduction of mercaptoethylpyridine (MEP) as an IgG-binding ligand and hydrophobization of side chains afforded thermo-responsive IgG adsorbents, whose thermo-responsive IgG desorption ratio was up to 88% (EPL/MEP derivative 3m). The changes in surface densities of active MEP groups, which are caused by thermal conformational changes of the adsorbents, play key roles for IgG desorption. Although a trade-off of IgG adsorption capacity and IgG desorption ratio was observed, the present study offers a novel molecular design for thermo-responsive adsorbents with high synthetic accessibility and potentially low toxicity.

A highly accurate method for determination of dissolved oxygen: Gravimetric Winkler method

International Nuclear Information System (INIS)

Helm, Irja; Jalukse, Lauri; Leito, Ivo

2012-01-01

Highlights: ► Probably the most accurate method available for dissolved oxygen concentration measurement was developed. ► Careful analysis of uncertainty sources was carried out and the method was optimized for minimizing all uncertainty sources as far as practical. ► This development enables more accurate calibration of dissolved oxygen sensors for routine analysis than has been possible before. - Abstract: A high-accuracy Winkler titration method has been developed for determination of dissolved oxygen concentration. Careful analysis of uncertainty sources relevant to the Winkler method was carried out and the method was optimized for minimizing all uncertainty sources as far as practical. The most important improvements were: gravimetric measurement of all solutions, pre-titration to minimize the effect of iodine volatilization, accurate amperometric end point detection and careful accounting for dissolved oxygen in the reagents. As a result, the developed method is possibly the most accurate method of determination of dissolved oxygen available. Depending on measurement conditions and on the dissolved oxygen concentration the combined standard uncertainties of the method are in the range of 0.012–0.018 mg dm −3 corresponding to the k = 2 expanded uncertainty in the range of 0.023–0.035 mg dm −3 (0.27–0.38%, relative). This development enables more accurate calibration of electrochemical and optical dissolved oxygen sensors for routine analysis than has been possible before.

Fundamental topics for thermo-elastic stress analyses

International Nuclear Information System (INIS)

Biermann, M.

1989-01-01

This paper delivers a consistent collection of theoretical fundamentals needed to perform rather sound experimental stress analyses on thermo-elastic materials. An exposition of important concepts of symmetry and so-called peer groups, yielding the very base for a rational description of materials, goes ahead and is followed by an introduction to the constitutive theory of simple materials. Neat distinction is made between stress contributions determined by deformational and thermal impressions, on the one part, and stress constraints not accessible to strain gauging, on the other part. The mathematical formalism required for establishing constitutive equations is coherently developed from scratch and aided, albeit not subrogated, by intuition. The main intention goes to turning some of the recent advances in the nonlinear field theories of thermomechanics to practical account. A full success therein, obviously, results under the restriction to thermo-elasticity. In adverting to more particular subjects, the elementary static effects of nonlinear isotropic elasticity are pointed out. Due allowance is made for thermal effects likely to occur in heat conducting materials also beyond the isothermal or isentropic limit cases. Linearization of the constitutive equations for anisotropic thermo-elastic materials is then shown to entail the formulas of the classical theory. (orig./MM) [de

A problem in gravimetric method for the determination of rare earth elements as oxide after the fluoride separation

International Nuclear Information System (INIS)

Takada, Kunio

1979-01-01

For the gravimetric determination of lanthanum, it was precipitated as fluoride and converted to oxide by igniting (ca. 930 0 C) in a town gas flame. However, the oxidation of lanthanum fluoride by ignition was incomplete, the major part of the precipitate being converted to oxyfluoride (LaOF) and a mixture of oxide and oxyfluoride resulted. Therefore, analytical results were generally (5 -- 7)% higher than theoretically expected. The lanthanum fluoride became converted into the oxide by repeating ignition (ca. 1070 0 C) three times, each for (30 -- 40)min. However, the weight was lower than that of the corresponding sesquioxide, La 2 O 3 . Except for ytterbium and lutetium, gravimetric results as oxides for the other rare earth elements (Y, Pr, Nd, Sm, Eu and Gd) were higher than theoretical values. Therefore, the precipitation of the rare earth elements as fluoride and the subsequent determination as oxide by ignition of the fluoride could not be recommended as the gravimetric method for the rare earths. In order to obtain accurate results for major to minor amounts of the rare earth elements, an EDTA titration at pH 6 should be used after the dissolution of fluoride in acid, if the fluoride precipitation separation is involved. (author)

Enhanced Thermo-Optical Switching of Paraffin-Wax Composite Spots under Laser Heating.

Science.gov (United States)

Said, Asmaa; Salah, Abeer; Fattah, Gamal Abdel

2017-05-12

Thermo-optical switches are of particular significance in communications networks where increasingly high switching speeds are required. Phase change materials (PCMs), in particular those based on paraffin wax, provide wealth of exciting applications with unusual thermally-induced switching properties, only limited by paraffin's rather low thermal conductivity. In this paper, the use of different carbon fillers as thermal conductivity enhancers for paraffin has been investigated, and a novel structure based on spot of paraffin wax as a thermo-optic switch is presented. Thermo-optical switching parameters are enhanced with the addition of graphite and graphene, due to the extreme thermal conductivity of the carbon fillers. Differential Scanning Calorimetry (DSC) and Scanning electron microscope (SEM) are performed on paraffin wax composites, and specific heat capacities are calculated based on DSC measurements. Thermo-optical switching based on transmission is measured as a function of the host concentration under conventional electric heating and laser heating of paraffin-carbon fillers composites. Further enhancements in thermo-optical switching parameters are studied under Nd:YAG laser heating. This novel structure can be used in future networks with huge bandwidth requirements and electric noise free remote aerial laser switching applications.

The use of cerium(IV) phosphate for the gravimetric determination and separation of cerium

International Nuclear Information System (INIS)

Masin, V.; Dolezal, J.

1978-01-01

A method for the gravimetric determination of cerium as Ce 3 (PO 4 ) 4 is described. Cerium can be separated from many metals in this form, as well as from permanganate and dichromate; the cerium separated can then be titrated with iron(II) solution. The method was verified for the determination of cerium in a rare earth concentrate. (Auth.)

Design and realization of the high-precision weighing systems as the gravimetric references in PTB's national water flow standard

International Nuclear Information System (INIS)

Engel, Rainer; Beyer, Karlheinz; Baade, Hans-Joachim

2012-01-01

PTB's ‘Hydrodynamic Test Field’, which represents a high-accuracy water flow calibration facility, serves as the national primary standard for liquid flow measurands. As the core reference device of this flow facility, a gravimetric standard has been incorporated, which comprises three special-design weighing systems: 300 kg, 3 tons and 30 tons. These gravimetric references were realized as a combination of a strain-gauge-based and an electromagnetic-force-compensation load-cell-based balance, each. Special emphasis had to be placed upon the dynamics design of the whole weighing system, due to the high measurement resolution and the dynamic behavior of the weighing systems, which are dynamically affected by mechanical vibrations caused by environmental impacts, flow machinery operation, flow noise in the pipework and induced wave motions in the weigh tanks. Taking into account all the above boundary conditions, the design work for the gravimetric reference resulted in a concrete foundation ‘rock’ of some 300 tons that rests on a number of vibration isolators. In addition to these passively operating vibration isolators, the vibration damping effect is enhanced by applying an electronic level regulation device. (paper)

Resonant gravimetric immunosensing based on capacitive micromachined ultrasound transducers

KAUST Repository

Viržonis, Darius

2014-04-08

High-frequency (40 MHz) and low-frequency (7 MHz) capacitive micromachined ultrasound transducers (CMUT) were fabricated and tested for use in gravimetric detection of biomolecules. The low-frequency CMUT sensors have a gold-coated surface, while the high-frequency sensors have a silicon nitride surface. Both surfaces were functionalized with bovine leukemia virus antigen gp51 acting as the antigen. On addition of an a specific antibody labeled with horseradish peroxidase (HRP), the antigen/antibody complex is formed on the surface and quantified by HRP-catalyzed oxidation of tetramethylbenzidine. It has been found that a considerably smaller quantity of immuno complex is formed on the high frequency sensor surface. In parallel, the loading of the surface of the CMUT was determined via resonance frequency and electromechanical resistance readings. Following the formation of the immuno complexes, the resonance frequencies of the low-frequency and high-frequency sensors decrease by up to 420 and 440 kHz, respectively. Finite element analysis reveals that the loading of the (gold-coated) low frequency sensors is several times larger than that on high frequency sensors. The formation of the protein film with pronounced elasticity and stress on the gold surface case is discussed. We also discuss the adoption of this method for the detection of DNA using a hybridization assay following polymerase chain reaction.

Solar-driven thermo- and electrochemical degradation of nitrobenzene in wastewater: Adaptation and adoption of solar STEP concept.

Science.gov (United States)

Gu, Di; Shao, Nan; Zhu, Yanji; Wu, Hongjun; Wang, Baohui

2017-01-05

The STEP concept has successfully been demonstrated for driving chemical reaction by utilization of solar heat and electricity to minimize the fossil energy, meanwhile, maximize the rate of thermo- and electrochemical reactions in thermodynamics and kinetics. This pioneering investigation experimentally exhibit that the STEP concept is adapted and adopted efficiently for degradation of nitrobenzene. By employing the theoretical calculation and thermo-dependent cyclic voltammetry, the degradation potential of nitrobenzene was found to be decreased obviously, at the same time, with greatly lifting the current, while the temperature was increased. Compared with the conventional electrochemical methods, high efficiency and fast degradation rate were markedly displayed due to the co-action of thermo- and electrochemical effects and the switch of the indirect electrochemical oxidation to the direct one for oxidation of nitrobenzene. A clear conclusion on the mechanism of nitrobenzene degradation by the STEP can be schematically proposed and discussed by the combination of thermo- and electrochemistry based the analysis of the HPLC, UV-vis and degradation data. This theory and experiment provide a pilot for the treatment of nitrobenzene wastewater with high efficiency, clean operation and low carbon footprint, without any other input of energy and chemicals from solar energy. Copyright © 2016 Elsevier B.V. All rights reserved.

Thermo-mechanical response and fatigue behavior of shape memory alloy

Energy Technology Data Exchange (ETDEWEB)

Kusagawa, Masaki; Asada, Yasuhide; Nakamura, Toshiya [Tokyo Univ. (Japan). Dept. of Mechanical Engineering

1998-11-01

Mechanical, thermo-mechanical and fatigue behaviors of Ni-Ti-Nb shape memory alloy (SMA) have been studied to prepare material data for a design purpose. Presented are testing devices, testing procedure and test results of monotonic tensile, recovery of inelastic deformation due to post heating (thermo-mechanical recovery) and fatigue for future use of the SMA as a structural material of nuclear incore structures. (orig.)

Thermo-mechanical response and fatigue behavior of shape memory alloy

International Nuclear Information System (INIS)

Kusagawa, Masaki; Asada, Yasuhide; Nakamura, Toshiya

1998-01-01

Mechanical, thermo-mechanical and fatigue behaviors of Ni-Ti-Nb shape memory alloy (SMA) have been studied to prepare material data for a design purpose. Presented are testing devices, testing procedure and test results of monotonic tensile, recovery of inelastic deformation due to post heating (thermo-mechanical recovery) and fatigue for future use of the SMA as a structural material of nuclear incore structures. (orig.)

Thermal analysis of wirelessly powered thermo-pneumatic micropump based on planar LC circuit

Energy Technology Data Exchange (ETDEWEB)

Chee, Pei Song; Nafea, Marwan; Leow, Pei Ling; Ali, Mohamed Sultan Mohamed [Universiti Teknologi Malaysia, Skudai (Malaysia)

2016-06-15

This paper studies the thermal behavior of a wireless powered micropump operated using thermo-pneumatic actuation. Numerical analysis was performed to investigate the temporal conduction of the planar inductor-capacitor (LC) wireless heater and the heating chamber. The result shows that the temperature at the heating chamber reaches steady state temperature of 46.7.deg.C within 40 seconds. The finding was further verified with experimental works through the fabrication of the planar LC heater (RF sensitive actuator) and micropump device using MEMS fabrication technique. The fabricated device delivers a minimum volume of 0.096 μL at the temperature of 29.deg.C after being thermally activated for 10 s. The volume dispensed from the micropump device can precisely controlled by an increase of the electrical heating power within the cut-off input power of 0.22 W. Beyond the power, the heat transfer to the heating chamber exhibits non-linear behavior. In addition, wireless operation of the fabricated device shows successful release of color dye when the micropump is immersed in DI-water containing dish and excited by tuning the RF power.

Thermal analysis of wirelessly powered thermo-pneumatic micropump based on planar LC circuit

International Nuclear Information System (INIS)

Chee, Pei Song; Nafea, Marwan; Leow, Pei Ling; Ali, Mohamed Sultan Mohamed

2016-01-01

This paper studies the thermal behavior of a wireless powered micropump operated using thermo-pneumatic actuation. Numerical analysis was performed to investigate the temporal conduction of the planar inductor-capacitor (LC) wireless heater and the heating chamber. The result shows that the temperature at the heating chamber reaches steady state temperature of 46.7.deg.C within 40 seconds. The finding was further verified with experimental works through the fabrication of the planar LC heater (RF sensitive actuator) and micropump device using MEMS fabrication technique. The fabricated device delivers a minimum volume of 0.096 μL at the temperature of 29.deg.C after being thermally activated for 10 s. The volume dispensed from the micropump device can precisely controlled by an increase of the electrical heating power within the cut-off input power of 0.22 W. Beyond the power, the heat transfer to the heating chamber exhibits non-linear behavior. In addition, wireless operation of the fabricated device shows successful release of color dye when the micropump is immersed in DI-water containing dish and excited by tuning the RF power.

Time-Resolved Gravimetric Method To Assess Degassing of Roasted Coffee.

Science.gov (United States)

Smrke, Samo; Wellinger, Marco; Suzuki, Tomonori; Balsiger, Franz; Opitz, Sebastian E W; Yeretzian, Chahan

2018-05-30

During the roasting of coffee, thermally driven chemical reactions lead to the formation of gases, of which a large fraction is carbon dioxide (CO 2 ). Part of these gases is released during roasting while part is retained inside the porous structure of the roasted beans and is steadily released during storage or more abruptly during grinding and extraction. The release of CO 2 during the various phases from roasting to consumption is linked to many important properties and characteristics of coffee. It is an indicator for freshness, plays an important role in shelf life and in packaging, impacts the extraction process, is involved in crema formation, and may affect the sensory profile in the cup. Indeed, and in view of the multiple roles it plays, CO 2 is a much underappreciated and little examined molecule in coffee. Here, we introduce an accurate, quantitative, and time-resolved method to measure the release kinetics of gases from whole beans and ground coffee using a gravimetric approach. Samples were placed in a container with a fitted capillary to allow gases to escape. The time-resolved release of gases was measured via the weight loss of the container filled with coffee. Long-term stability was achieved using a customized design of a semimicro balance, including periodic and automatic zero value measurements and calibration procedures. The novel gravimetric methodology was applied to a range of coffee samples: (i) whole Arabica beans and (ii) ground Arabica and Robusta, roasted to different roast degrees and at different speeds (roast air temperatures). Modeling the degassing rates allowed structural and mechanistic interpretation of the degassing process.

Thermo-economic design optimization of parabolic trough solar plants for industrial process heat applications with memetic algorithms

International Nuclear Information System (INIS)

Silva, R.; Berenguel, M.; Pérez, M.; Fernández-Garcia, A.

2014-01-01

Highlights: • A thermo-economic optimization of a parabolic-trough solar plant for industrial process heat applications is developed. • An analysis of the influence of economic cost functions on optimal design point location is presented. • A multi-objective optimization approach to the design routine is proposed. • A sensitivity analysis of the optimal point location to economic, operational, and ambient conditions is developed. • Design optimization of a parabolic trough plant for a reference industrial application is developed. - Abstract: A thermo-economic design optimization of a parabolic trough solar plant for industrial processes with memetic algorithms is developed. The design domain variables considered in the optimization routine are the number of collectors in series, number of collector rows, row spacing, and storage volume. Life cycle savings, levelized cost of energy, and payback time objective functions are compared to study the influence on optimal design point location. Furthermore a multi-objective optimization approach is proposed to analyze the design problem from a multi-economic criteria point of view. An extensive set of optimization cases are performed to estimate the influence of fuel price trend, plant location, demand profile, operation conditions, solar field orientation, and radiation uncertainty on optimal design. The results allow quantifying as thermo-economic design optimization based on short term criteria as the payback time leads to smaller plants with higher solar field efficiencies and smaller solar fractions, while the consideration of optimization criteria based on long term performance of the plants, as life cycle savings based optimization, leads to the reverse conclusion. The role of plant location and future evolution of gas prices in the thermo-economic performance of the solar plant has been also analyzed. Thermo-economic optimization of a parabolic trough solar plant design for the reference industrial

Radiation-induced grafting of acrylamide onto guar gum in aqueous medium: Synthesis and characterization of grafted polymer guar-g-acrylamide

Energy Technology Data Exchange (ETDEWEB)

Biswal, Jayashree [Radiation Technology Development Section, Bhabha Atomic Research Centre, Trombay, Mumbai-400 085 (India); Kumar, Virendra [Radiation Technology Development Section, Bhabha Atomic Research Centre, Trombay, Mumbai-400 085 (India); Bhardwaj, Y.K. [Radiation Technology Development Section, Bhabha Atomic Research Centre, Trombay, Mumbai-400 085 (India)]. E-mail: ykbhard@magnum.barc.ernet.in; Goel, N.K. [Radiation Technology Development Section, Bhabha Atomic Research Centre, Trombay, Mumbai-400 085 (India); Dubey, K.A. [Radiation Technology Development Section, Bhabha Atomic Research Centre, Trombay, Mumbai-400 085 (India); Chaudhari, C.V. [Radiation Technology Development Section, Bhabha Atomic Research Centre, Trombay, Mumbai-400 085 (India); Sabharwal, S. [Radiation Technology Development Section, Bhabha Atomic Research Centre, Trombay, Mumbai-400 085 (India)

2007-10-15

Mutual radiation grafting technique has been applied to carry out grafting of acrylamide (AAm) onto guar gum (GG) using high-energy Co{sup 60} {gamma} radiation to enhance its flocculating properties for industrial effluents. The grafted product was characterized using analytical probes like elemental analysis, thermal analysis, Fourier transformed infrared (FTIR), X-ray diffraction (XRD) and scanning electron microscope (SEM). The grafting extent was observed to decrease with the dose rate and increase with the concentration of AAm. Thermo gravimetric analysis (TGA) of grafted and ungrafted samples indicated better stability of grafted product. {gamma} and microwave radiation effect on grafted and virgin GG has also been reported.

Thermogravimetric analysis of the behavior of sub-bituminous coal and cellulosic ethanol residue during co-combustion.

Science.gov (United States)

Buratti, C; Barbanera, M; Bartocci, P; Fantozzi, F

2015-06-01

The influence of the addition of cellulosic ethanol residue (CER) on the combustion of Indonesian sub-bituminous coal was analyzed by non isothermal thermo-gravimetric analysis (TGA). The effect of blends ratio (5%, 10%, 15% and 20%), interaction mechanism, and heating rate (5°C/min, 10°C/min, 15°C/min, 20°C/min) on the combustion process was studied. The results show that the increase of the blending ratio allows to achieve the increase of the combustibility index from 7.49E-08 to 5.26E-07 at the blending ratio of 20%. Two types of non-isothermal kinetic analysis methods (Ozawa-Flynn-Wall and Vyazovkin) were also applied. Results indicate that the activation energy of the blends decreases with increasing the conversion rate. In particular, the blending ratio of 20% confirms to have the better combustion performance, with the average value of the activation energy equal to 41.10 kJ/mol obtained by Ozawa-Flynn-Wall model and 31.17 kJ/mol obtained by Vyazovkin model. Copyright © 2015 Elsevier Ltd. All rights reserved.

Density Imaging of Puy de Dôme Volcano by Joint Inversion of Muographic and Gravimetric Data

Science.gov (United States)

Barnoud, A.; Niess, V.; Le Ménédeu, E.; Cayol, V.; Carloganu, C.

2016-12-01

We aim at jointly inverting high density muographic and gravimetric data to robustly infer the density structure of volcanoes. We use the puy de Dôme volcano in France as a proof of principle since high quality data sets are available for both muography and gravimetry. Gravimetric inversion and muography are independent methods that provide an estimation of density distributions. On the one hand, gravimetry allows to reconstruct 3D density variations by inversion. This process is well known to be ill-posed and intrinsically non unique, thus it requires additional constraints (eg. a priori density model). On the other hand, muography provides a direct measurement of 2D mean densities (radiographic images) from the detection of high energy atmospheric muons crossing the volcanic edifice. 3D density distributions can be computed from several radiographic images, but the number of images is generally limited by field constraints and by the limited number of available telescopes. Thus, muon tomography is also ill-posed in practice.In the case of the puy de Dôme volcano, the density structures inferred from gravimetric data (Portal et al. 2016) and from muographic data (Le Ménédeu et al. 2016) show a qualitative agreement but cannot be compared quantitatively. Because each method has different intrinsic resolutions due to the physics (Jourde et al., 2015), the joint inversion is expected to improve the robustness of the inversion. Such joint inversion has already been applied in a volcanic context (Nishiyama et al., 2013).Volcano muography requires state-of-art, high-resolution and large-scale muon detectors (Ambrosino et al., 2015). Instrumental uncertainties and systematic errors may constitute an important limitation for muography and should not be overlooked. For instance, low-energy muons are detected together with ballistic high-energy muons, decreasing the measured value of the mean density closed to the topography.Here, we jointly invert the gravimetric and

Determination of uranium by a gravimetric-volumetric titration method

International Nuclear Information System (INIS)

Krtil, J.

1998-01-01

A volumetric-gravimetric modification of a method for the determination of uranium based on the reduction of uranium to U (IV) in a phosphoric acid medium and titration with a standard potassium dichromate solution is described. More than 99% of the stoichiometric amount of the titrating solution is weighed and the remainder is added volumetrically by using the Mettler DL 40 RC Memotitrator. Computer interconnected with analytical balances collects continually the data on the analyzed samples and evaluates the results of determination. The method allows to determine uranium in samples of uranium metal, alloys, oxides, and ammonium diuranate by using aliquot portions containing 30 - 100 mg of uranium with the error of determination, expressed as the relative standard deviation, of 0.02 - 0.05%. (author)

Preparation of thermo and pH-responsive polymer@Au/Fe{sub 3}O{sub 4} core/shell nanoparticles as a carrier for delivery of anticancer agent

Energy Technology Data Exchange (ETDEWEB)

Ghorbani, Marjan [University of Tabriz, Laboratory of Polymer, Faculty of Chemistry (Iran, Islamic Republic of); Hamishehkar, Hamed, E-mail: hamishehkarh@tbzmed.ac.ir [Tabriz University of Medical Sciences, Drug Applied Research Center (Iran, Islamic Republic of); Arsalani, Naser; Entezami, Ali Akbar, E-mail: aentezami@tabrizu.ac.ir [University of Tabriz, Laboratory of Polymer, Faculty of Chemistry (Iran, Islamic Republic of)

2015-07-15

In this work, a thermo and pH-responsive poly-N-isopropylacrylamide-co-itaconic acid containing thiol side groups were successfully synthesized to prepare Doxorubicin-loaded polymer@Au/Fe{sub 3}O{sub 4} core/shell nanoparticles (DOX-NPs). Copolymer and NPs were fully characterized by FT-IR, HNMR, photo-correlation spectroscopy, SEM, X-ray diffraction, vibrating-sample magnetometer, thermal gravimetric analysis, and UV–Vis spectroscopy. The stimuli-responsive characteristics of NPs were evaluated by in vitro release study in simulated cancerous environment. The biocompatibility and cytotoxic properties of NPs and DOX-NPs are explored by MTT method. The prepared NPs with the size of 50 nm showed paramagnetic characteristics with suitable and stable dispersion at physiological medium and high loading capacity (up to 55 %) of DOX. DOX-NPs yielded a pH- and temperature-triggered release of entrapped drugs at tumor tissue environment (59 % of DOX release) compared to physiological condition (20 % of DOX release) during 48 h. In vitro cytotoxicity studies indicated that the NPs showed no cytotoxicity on A549 cells at different amounts after incubation for 72 h confirming its suitability as a drug carrier. DOX-NPs, on the other hand, caused an efficient anticancer performance as verified by MTT assay test. It was concluded that developed NPs by us in this study may open the possibilities for targeted delivery of DOX to the cancerous tissues.

Nuclear fuel technology - Determination of uranium in uranyl nitrate solutions of nuclear grade quality - Gravimetric method

International Nuclear Information System (INIS)

2003-01-01

This International Standard specifies a precise and accurate gravimetric method for determining the mass fraction of uranium in uranyl nitrate solutions of nuclear grade quality containing more than 100 g/kg of uranium. Non-volatile impurities influence the accuracy of the method

Numerical Simulation of Pressure Fluctuations in the Thermo-acoustic Transducer

Directory of Open Access Journals (Sweden)

D. A. Uglanov

2015-01-01

Full Text Available The article describes the features of numerical simulation of acoustic oscillation excitation in the resonators with a foam insert (regenerator to study the excitation of thermo-acoustic oscillations in the circuit of small-sized engine model on the pulse tube.The aim of this work is the numerical simulation of the emerging oscillations in thermoacoustic engine resonator at the standing wave. As a basis, the work takes a thermo-acoustic resonator model with the open end (without piston developed in DeltaEC software. The precalculated operation frequency of the given resonator model, as a quarter of the wave resonator, is ν = 560 Hz.The paper offers a simplified finite element resonator model and defines the harmonic law of the temperature distribution on regenerator. The time dependences of the speed and pressure amplitude for the open end of the resonator are given; the calculated value of the process operating frequency is approximately equal to the value of the frequency for a given length of the resonator. Key findings, as a result of study, are as follows:1. The paper shows a potential for using this ESI-CFD Advanced software to simulate the processes of thermal excitation of acoustic oscillations.2. Visualization of turbulent flow fluctuations in the regenerator zone extends the analysis capability of gas-dynamic processes.3. Difference between operating frequency of the process simulated by ESI-CFD Advanced and frequency value obtained by analytical methods is about 4%, which is evidence of the model applicability to study the acoustic parameters of thermo-acoustic transducers. Experimental results have proved these data.

Thermo-mechanical analysis of FG nanobeam with attached tip mass: an exact solution

Science.gov (United States)

Ghadiri, Majid; Jafari, Ali

2016-12-01

Present disquisition proposes an analytical solution method for exploring the vibration characteristics of a cantilever functionally graded nanobeam with a concentrated mass exposed to thermal loading for the first time. Thermo-mechanical properties of FGM nanobeam are supposed to change through the thickness direction of beam based on the rule of power-law (P-FGM). The small-scale effect is taken into consideration based on nonlocal elasticity theory of Eringen. Linear temperature rise (LTR) through thickness direction is studied. Existence of centralized mass in the free end of nanobeam influences the mechanical and physical properties. Timoshenko beam theory is employed to derive the nonlocal governing equations and boundary conditions of FGM beam attached with a tip mass under temperature field via Hamilton's principle. An exact solution procedure is exploited to achieve the non-dimensional frequency of FG nanobeam exposed to temperature field with a tip mass. A parametric study is led to assess the efficacy of temperature changes, tip mass, small scale, beam thickness, power-law exponent, slenderness and thermal loading on the natural frequencies of FG cantilever nanobeam with a point mass at the free end. It is concluded that these parameters play remarkable roles on the dynamic behavior of FG nanobeam subjected to LTR with a tip mass. The results for simpler states are confirmed with known data in the literature. Presented numerical results can serve as benchmarks for future thermo-mechanical analyses of FG nanobeam with tip mass.

Strain-rate dependent plasticity in thermo-mechanical transient analysis

International Nuclear Information System (INIS)

Rashid, Y.R.; Sharabi, M.N.

1980-01-01

The thermo-mechanical transient behavior of fuel element cladding and other reactor components is generally governed by the strain-rate properties of the material. Relevant constitutive modeling requires extensive material data in the form of strain-rate response as function of true-stress, temperature, time and environmental conditions, which can then be fitted within a theoretical framework of an inelastic constitutive model. In this paper, we present a constitutive formulation that deals continuously with the entire strain-rate range and has the desirable advantage of utilizing existing material data. The derivation makes use of strain-rate sensitive stress-strain curve and strain-rate dependent yield surface. By postulating a strain-rate dependent on Mises yield function and a strain-rate dependent kinematic hardening rule, we are able to derive incremental stress-strain relations that describe the strain-rate behavior in the entire deformation range spanning high strain-rate plasticity and creep. The model is sufficiently general as to apply to any materials and loading histories for which data is available. (orig.)

Study of gap conductance model for thermo mechanical fully coupled finite element model

International Nuclear Information System (INIS)

Kim, Hyo Cha; Yang, Yong Sik; Kim, Dae Ho; Bang, Je Geon; Kim, Sun Ki; Koo, Yang Hyun

2012-01-01

A light water reactor (LWR) fuel rod consists of zirconium alloy cladding and uranium dioxide pellets, with a slight gap between them. Therefore, the mechanical integrity of zirconium alloy cladding is the most critical issue, as it is an important barrier for fission products released into the environment. To evaluate the stress and strain of the cladding during operation, fuel performance codes with a one-dimensional (1D) approach have been reported since the 1970s. However, it is difficult for a 1D model to simulate the stress and strain of the cladding accurately owing to a lack of degree of freedom. A LWR fuel performance code should include thermo-mechanical coupled model owing to the existence of the fuel-cladding gap. Generally, the gap that is filled with helium gas results in temperature drop along radius direction. The gap conductance that determines temperature gradient within the gap is very sensitive to gap thickness. For instance, once the gap size increases up to several microns in certain region, difference of surface temperatures increases up to 100 Kelvin. Therefore, iterative thermo-mechanical coupled analysis is required to solve temperature distribution throughout pellet and cladding. Consequently, the Finite Element (FE) module, which can simulate a higher degree of freedom numerically, is an indispensable requirement to understand the thermomechanical behavior of cladding. FRAPCON-3, which is reliable performance code, has iterative loop for thermo-mechanical coupled calculation to solve 1D gap conductance model. In FEMAXI-III, 1D thermal analysis module and FE module for stress-strain analysis were separated. 1D thermal module includes iterative analysis between them. DIONISIO code focused on thermal contact model as function of surface roughness and contact pressure when the gap is closed. In previous works, gap conductance model has been developed only for 1D model or hybrid model (1D and FE). To simulate temperature, stress and strain

Application of CFD methods in research of SCWR thermo-hydraulics

International Nuclear Information System (INIS)

Zeng Xiaokang; Li Yongliang; Yan Xiao; Xiao Zejun; Huang Yanping

2013-01-01

The CFD method has been an important tool in the research of SCWR thermo- hydraulics. Currently, the CFD methods uses commonly the subcritical turbulence models, which can not accurately simulate the gravity and thermal expansion acceleration effect, and CFD numerical method is not applicable when the heat flux is large. The paper summarizes the application status of the CFD methods in the research of SCWR thermo-hydraulics in RETH. (authors)

Poly-Lactide/Exfoliated C30B Interactions and Influence on Thermo-Mechanical Properties Due to Artificial Weathering

Directory of Open Access Journals (Sweden)

Wendy Margarita Chávez-Montes

2016-04-01

Full Text Available Thermal stability as well as enhanced mechanical properties of poly-lactide (PLA can increase PLA applications for short-use products. The conjunction of adequate molecular weight (MW as well as satisfactory thermo-mechanical properties, together, can lead to the achievement of suitable properties. However, PLA is susceptible to thermal degradation and thus an undesired decay of MW and a decrease of its mechanical properties during processing. To avoid this PLA degradation, nanofiller is incorporated as reinforcement to increase its thermo-mechanical properties. There are many papers focusing on filler effects on the thermal stability and mechanical properties of PLA/nanocomposites; however, these investigations lack an explanation of polymer/filler interactions. We propose interactions between PLA and Cloisite30B (C30B as nanofiller. We also study the effects on the thermal and mechanical properties due to molecular weight decay after exposure to artificial weathering. PLA blank and nanocomposites were subjected to three time treatments (0, 176, and 360 h of exposure to artificial weathering in order to achieve comparable materials with different MW. MW was acquired by means of Gel Permeation Chromatography (GPC. Thermo-mechanical properties were investigated through Thermogravimetric Analysis (TGA, Differential Scanning Calorimetry (DSC, X-ray Diffraction (XRD, Dynamic Mechanical Thermal Analysis (DMTA and Fourier Transform Infrared Spectroscopy (FTIR.

Hydrophilic magnetic nanoclusters with thermo-responsive properties and their drug controlled release

International Nuclear Information System (INIS)

Meerod, Siraprapa; Rutnakornpituk, Boonjira; Wichai, Uthai; Rutnakornpituk, Metha

2015-01-01

Synthesis and drug controlled release properties of thermo-responsive magnetic nanoclusters grafted with poly(N-isopropylacrylamide) (poly(NIPAAm)) and poly(NIPAAm-co-poly(ethylene glycol) methyl ether methacrylate) (PEGMA) copolymers were described. These magnetic nanoclusters were synthesized via an in situ radical polymerization in the presence of acrylamide-grafted magnetic nanoparticles (MNPs). Poly(NIPAAm) provided thermo-responsive properties, while PEGMA played a role in good water dispersibility to the nanoclusters. The ratios of PEGMA to NIPAAm in the (co)polymerization in the presence of the MNPs were fine-tuned such that the nanoclusters with good water dispersibility, good magnetic sensitivity and thermo responsiveness were obtained. The size of the nanoclusters was in the range of 50–100 nm in diameter with about 100–200 particles/cluster. The nanoclusters were well dispersible in water at room temperature and can be suddenly agglomerated when temperature was increased beyond the lower critical solution temperature (LCST) (32 °C). The release behavior of an indomethacin model drug from the nanoclusters was also investigated. These novel magnetic nanoclusters with good dispersibility in water and reversible thermo-responsive properties might be good candidates for the targeting drug controlled release applications. - Highlights: • Nanoclusters with good water dispersibility and magnetic response were prepared. • They were grafted with thermo-responsive poly(NIPAAm) and/or poly(PEGMA). • Poly(NIPAAm) provided thermo-responsive properties to the nanoclusters. • Poly(PEGMA) provided good water dispersibilityto the nanoclusters. • Accelerated and controllable releases of a drug from the nanoclusters were shown

Exergetic analysis of a thermo-generator for automotive application: A dynamic numerical approach

Science.gov (United States)

Glavatskaya, O.; Goupil, C.; Bakkali, A. El; Shonda, O.

2012-06-01

It is well known that, when using a passenger car with an ICE (Internal Combustion Engine), only a fraction of the burnt fuel energy actually contributes to drive the vehicle. Typical passenger vehicle engines run about 25% efficiency while a great part of the remaining energy (about 40%), is lost through the exhaust gases. This latter has a significant energy conversion potential since the temperature (more than 300°C) and the mass flow rate are high enough. Thus, direct conversion of heat into electricity is a credible option if the overall system is optimized. This point is crucial since the heat conversion into work process is very sensible to any mismatching of the different parts of the system, and very sensible significant to the possible varying working conditions. All these effects constitute irreversibility sources that degrade the overall efficiency. The exergetic analysis is known to be an efficient tool for finding the root causes of theses irreversible processes. In order to investigate the performance of our automotive thermo-generator we propose an analysis of the exergy flow through the system under dynamic conditions. Taking into account the different irreversible sources such as thermal conduction and Joule effect, we are able to localize and quantify the exergy losses. Then, in order to optimize the thermoelectric converter for a given vehicle, correct actions in term of design and working conditions can be proposed.

Thermo-Mechanical Modeling of Laser-Mig Hybrid Welding (lmhw)

Science.gov (United States)

Kounde, Ludovic; Engel, Thierry; Bergheau, Jean-Michel; Boisselier, Didier

2011-01-01

Hybrid welding is a combination of two different technologies such as laser (Nd: YAG, CO2…) and electric arc welding (MIG, MAG / TIG …) developed to assemble thick metal sheets (over 3 mm) in order to reduce the required laser power. As a matter of fact, hybrid welding is a lso used in the welding of thin materials to benefit from process, deep penetration and gap limit. But the thermo-mechanical behaviour of thin parts assembled by LMHW technology for railway cars production is far from being controlled the modeling and simulation contribute to the assessment of the causes and effects of the thermo mechanical behaviour in the assembled parts. In order to reproduce the morphology of melted and heat-affected zones, two analytic functions were combined to model the heat source of LMHW. On one hand, we applied a so-called "diaboloïd" (DB) which is a modified hyperboloid, based on experimental parameters and the analysis of the macrographs of the welds. On the other hand, we used a so-called "double ellipsoïd" (DE) which takes the MIG only contribution including the bead into account. The comparison between experimental result and numerical result shows a good agreement.

Finite Element Modeling of Thermo Creep Processes Using Runge-Kutta Method

Directory of Open Access Journals (Sweden)

Yu. I. Dimitrienko

2015-01-01

Full Text Available Thermo creep deformations for most heat-resistant alloys, as a rule, nonlinearly depend on stresses and are practically non- reversible. Therefore, to calculate the properties of these materials the theory of plastic flow is most widely used. Finite-element computations of a stress-strain state of structures with account of thermo creep deformations up to now are performed using main commercial software, including ANSYS package. However, in most cases to solve nonlinear creep equations, one should apply explicit or implicit methods based on the Euler method of approximation of time-derivatives. The Euler method is sufficiently efficient in terms of random access memory in computations, however this method is cumbersome in computation time and does not always provide a required accuracy for creep deformation computations.The paper offers a finite-element algorithm to solve a three-dimensional problem of thermo creep based on the Runge-Kutta finite-difference schemes of different orders with respect to time. It shows a numerical test example to solve the problem on the thermo creep of a beam under tensile loading. The computed results demonstrate that using the Runge-Kutta method with increasing accuracy order allows us to obtain a more accurate solution (with increasing accuracy order by 1 a relative error decreases, approximately, by an order too. The developed algorithm proves to be efficient enough and can be recommended for solving the more complicated problems of thermo creep of structures.

Dosimetric characteristics of Thermo-Shield material for orthovoltage photon beams

International Nuclear Information System (INIS)

Bahmaid, Mohammad; Kim, Siyong; Liu, Chihray R.; Palta, Jatinder R.

2003-01-01

Conventionally, lead has been used for field shaping in orthovoltage radiation therapy. Recently, a compensator material named Thermo-Shield was presented for field shaping in electron beams. Thermo-Shield is composed of nontoxic, high atomic weight metal particles dispersed in a thermoplastic matrix. It is manually moldable and conforms to human anatomy or any shape at temperatures of 108-132 degree sign F. It is reusable and can be continuously reshaped to better fit the treatment field. Dosimetric characteristics of thermoplastic material were studied for Philips RT250 orthovoltage photon beams ranging from 75 to 250 kVp. It was found that Thermo-Shield should be four to five times thicker than lead to achieve the same transmission (less than 5%). However, it did not cause significant degradation in penumbra. Clinical procedures for use are discussed

Thermal Degradation of Lead Monoxide Filled Polymer Composite Radiation Shields

International Nuclear Information System (INIS)

Harish, V.; Nagaiah, N.

2011-01-01

Lead monoxide filled Isophthalate resin particulate polymer composites were prepared with different filler concentrations and investigated for physical, thermal, mechanical and gamma radiation shielding characteristics. This paper discusses about the thermo gravimetric analysis of the composites done to understand their thermal properties especially the effect of filler concentration on the thermal stability and degradation rate of composites. Pristine polymer exhibits single stage degradation whereas filled composites exhibit two stage degradation processes. Further, the IDT values as well as degradation rates decrease with the increased filler content in the composite.

Thermal properties and water repellency of cotton fabric prepared through sol-gel method

Directory of Open Access Journals (Sweden)

Gu Jia-Li

2016-01-01

Full Text Available Cotton fabrics were treated by one-step sol-gel method. The pure silica hydrosol and phosphorus-doped hydrosol were prepared with the addition of a hydrophobic hexadecyltrimethoxysilane to decrease the surface energy of cotton fabric. The thermal properties and water repellency of treated cotton fabric were characterized by thermo-gravimetric analysis, micro combustion, limiting oxygen index, and contact angle measurement. The results showed that cotton fabric treated by phosphorus-doped silica hydrosol had excellent flame retardance, and the water repellence was apparently improved with the addition of hexadecyltrimethoxysilane.

Fabrication of Mineralized Collagen from Bovine Waste Materials by Hydrothermal Method as Promised Biomaterials

DEFF Research Database (Denmark)

Sheikh, Faheem A.; Kanjwal, Muzafar Ahmed; Macossay, Javier

2011-01-01

In the present study, we aimed to produce mineralized-collagen by hydrothermal process. A simple method not depending on additional foreign chemicals has been employed to isolate the mineralized-collagen fibers from bovine waste. The process of extraction involves the use of hydrothermal method...... mineral content in the individual fibers. The X-ray diffraction showed the crystalline feature of the obtained nano-compounds. The thermo gravimetric analysis was used to differentiate between the collagen and mineral parts of obtained product. Overall, the results generously indicated production of well...

Physicochemical Study of Irradiated polypropylene/Organo :Modified Montmorillonite Composites by Using Electron Beam Irradiation Technique

International Nuclear Information System (INIS)

Hassan, M.S.

2008-01-01

Polypropylene/ Organo modified montmorillonite composites (PP/ OMMT) were prepared by melt blending with a twin screw extruder. The thermal properties by thermo gravimetric analysis (TGA), the dispersion of OMMT of macromolecules by X-ray diffraction (XRD), mechanical properties and the morphology by scanning electron microscopy (SEM) were investigated. The effect of electron beam irradiation on these properties was also studied. The results showed an intercalation between the silicate layers and the PP polymer matrix. The (PP/ OMMT) composites exhibit higher thermal stability and lower mechanical properties than pure polypropylene

Comparison of Glaciological and Gravimetric Glacier Mass Balance Measurements of Taku and Lemon Creek Glaciers, Southeast Alaska

Science.gov (United States)

Vogler, K.; McNeil, C.; Bond, M.; Getraer, B.; Huxley-Reicher, B.; McNamara, G.; Reinhardt-Ertman, T.; Silverwood, J.; Kienholz, C.; Beedle, M. J.

2017-12-01

Glacier-wide annual mass balances (Ba) have been calculated for Taku (726 km2) and Lemon Creek glaciers (10.2 km2) since 1946 and 1953 respectively. These are the longest mass balance records in North America, and the only Ba time-series available for Southeast Alaska, making them particularly valuable for the global glacier mass balance monitoring network. We compared Ba time-series from Taku and Lemon Creek glaciers to Gravity Recovery and Climate Experiment (GRACE) mascon solutions (1352 and 1353) during the 2004-2015 period to assess how well these gravimetric solutions reflect individual glaciological records. Lemon Creek Glacier is a challenging candidate for this comparison because it is small compared to the 12,100 km2 GRACE mascon solutions. Taku Glacier is equally challenging because its mass balance is stable compared to the negative balances dominating its neighboring glaciers. Challenges notwithstanding, a high correlation between the glaciological and gravimetrically-derived Ba for Taku and Lemon Creek glaciers encourage future use of GRACE to measure glacier mass balance. Additionally, we employed high frequency ground penetrating radar (GPR) to measure the variability of accumulation around glaciological sites to assess uncertainty in our glaciological measurements, and the resulting impact to Ba. Finally, we synthesize this comparison of glaciological and gravimetric mass balance solutions with a discussion of potential sources of error in both methods and their combined utility for measuring regional glacier change during the 21st century.

Thermal Analysis of Braille Formed by Using Screen Printing and Inks with Thermo Powder

OpenAIRE

Svіtlana HAVENKO; Victoria KOCHUBEI; Marta LABETSKA; Svitlana KHADZHYNOVA; Edmundas KIBIRKŠTIS; Ingrida Venytė

2015-01-01

In order to improve the integration of blind people into society, suitable conditions should be provided for them. The expansion of Braille (BR) use could serve the purpose. Depending on the materials used for Braille, it can be formed or printed in different ways: embossing, screen printing, thermoforming, digital printing. The aim of this research is to determine the effect of thermal properties of screen printing inks and inks with thermo-powder on the qualitative parameters of Braille. Sc...

Thermo-hydraulic Analysis of a Water-cooled Printed Circuit Heat Exchanger in a Small-scale Nitrogen Loop

International Nuclear Information System (INIS)

Kim, Chan Soo; Hong, Sung Deok; Kim, Min Hwan; Shim, Jaesool; Lee, Gyung Dong

2013-01-01

The development of high-temperature heat exchangers is very important because of its higher operation temperature and pressure than those of common light water reactors and industrial process plants. In particular, the intermediate heat exchanger is a key-challenged high temperature component in a Very High Temperature gas-cooled Reactor (VHTR). A printed circuit heat exchanger is one of the candidates for an intermediate heat exchanger in a VHTR. The printed circuit heat exchanger (PCHE) was developed and commercialized by HEATRIC. The compactness is better than any other heat exchanger types, because its core matrices are fabricated by diffusion bonding with photo-chemically etched micro-channels. Various tests and analysis have been performed to verify the performance of PCHE. The thermal stress analysis of the high temperature PCHE is necessary to endure the extremely operation condition of IHX. In this study, the thermo-hydraulic analysis for the laboratory-scale PCHE is performed to provide the input data for the boundary conditions of a structural analysis. The results from the first-principal calculation are compared with those from computational fluid dynamics code analysis. COMSOL 4.3a analysis is successfully performed at the uniform pressure drop condition in a set of flow channel stacks. The heat-exchanged region concentrated to the nitrogen inlet cause the uniform mass velocity distribution in the channels, therefore there is little difference between two analytical results

Study of the thermo-mechanical performances of the IFMIF-EVEDA Lithium Test Loop target assembly

Energy Technology Data Exchange (ETDEWEB)

Di Maio, P.A., E-mail: dimaio@din.unipa.it [Dipartimento dell' Energia, Universita di Palermo, Viale delle Scienze, 90128 Palermo (Italy); Arena, P.; Bongiovi, G. [Dipartimento dell' Energia, Universita di Palermo, Viale delle Scienze, 90128 Palermo (Italy); Giammusso, R.; Micciche, G.; Tincani, A. [ENEA C. R. Brasimone, 40032 Camugnano, Bologna (Italy)

2012-08-15

Highlights: Black-Right-Pointing-Pointer IFMIF-EVEDA target assembly thermo-mechanical behavior has been investigated. Black-Right-Pointing-Pointer Finite element method has been followed and a commercial code has been used. Black-Right-Pointing-Pointer Nominal, design and pressure test steady state scenarios and start-up transient conditions have been investigated. Black-Right-Pointing-Pointer Steady state results have shown that back-plate yielding may occur only under the design scenario. Black-Right-Pointing-Pointer Transient analysis has indicated that TA start-up lasts for {approx}60 h. - Abstract: Within the framework of the IFMIF R and D program and in close cooperation with ENEA-Brasimone, at the Department of Energy of the University of Palermo a research campaign has been launched to investigate the thermo-mechanical behavior of the target assembly under both steady state and start-up transient conditions. A theoretical approach based on the finite element method (FEM) has been followed and a well-known commercial code has been adopted. A realistic 3D FEM model of the target assembly has been set-up and optimized by running a mesh independency analysis. A proper set of loads and boundary conditions, mainly concerned with radiation heat transfer between the target assembly external walls and the inner walls of its containment vessel, have been considered and the target assembly thermo-mechanical behavior under nominal, design and pressure test steady state scenarios and start-up transient conditions has been investigated. Results are herewith reported and discussed.

Thermo-responsive polymeric nanoparticles for enhancing neuronal differentiation of human induced pluripotent stem cells.

Science.gov (United States)

Seo, Hye In; Cho, Ann-Na; Jang, Jiho; Kim, Dong-Wook; Cho, Seung-Woo; Chung, Bong Geun

2015-10-01

We report thermo-responsive retinoic acid (RA)-loaded poly(N-isopropylacrylamide)-co-acrylamide (PNIPAM-co-Am) nanoparticles for directing human induced pluripotent stem cell (hiPSC) fate. Fourier transform infrared spectroscopy and (1)H nuclear magnetic resonance analysis confirmed that RA was efficiently incorporated into PNIAPM-co-Am nanoparticles (PCANs). The size of PCANs dropped with increasing temperatures (300-400 nm at room temperature, 80-90 nm at 37°C) due to its phase transition from hydrophilic to hydrophobic. Due to particle shrinkage caused by this thermo-responsive property of PCANs, RA could be released from nanoparticles in the cells upon cellular uptake. Immunocytochemistry and quantitative real-time polymerase chain reaction analysis demonstrated that neuronal differentiation of hiPSC-derived neuronal precursors was enhanced after treatment with 1-2 μg/ml RA-loaded PCANs. Therefore, we propose that this PCAN could be a potentially powerful carrier for effective RA delivery to direct hiPSC fate to neuronal lineage. The use of induced pluripotent stem cells (iPSCs) has been at the forefront of research in the field of regenerative medicine, as these cells have the potential to differentiate into various terminal cell types. In this article, the authors utilized a thermo-responsive polymer, Poly(N-isopropylacrylamide) (PNIPAM), as a delivery platform for retinoic acid. It was shown that neuronal differentiation could be enhanced in hiPSC-derived neuronal precursor cells. This method may pave a way for future treatment of neuronal diseases. Copyright © 2015 Elsevier Inc. All rights reserved.

Simulation of thermo-mechanical effect in bulk-silicon FinFETs

OpenAIRE

Burenkov, Alex; Lorenz, Jürgen

2016-01-01

The thermo-mechanical effect in bulk-silicon FinFETs of the 14 nm CMOS technology node is studied by means of numerical simulation. The electrical performance of such devices is significantly enhanced by the intentional introduction of mechanical stress during the device processing. The thermo-mechanical effect modifies the mechanical stress distribution in active regions of the transistors when they are heated. This can lead to a modification of the electrical performance. Numerical simulati...

Study of Polyolefines Waste Thermo-Destruction in Large Laboratory and in Industrial Installations

Science.gov (United States)

2014-12-15

obtaining a product of performance characteristics close to those of commercially available diesel oil. Experimental Research of catalytic thermo-destruction...results were compared with parameters of diesel oil which properties were specified by specialized laboratory outside (Quality Control Laboratory Fuel...content of sulphur. The chromatographic analysis of gaseous and liquid products was conducted using Autosystem XL GC– Turbo Mass chromatograph

Gravimetric model of the Gastre trough, province of Chubut, Argentina; Modelo gravimetrico en la fosa de Gastre, provincia de Chubut, Argentina

Energy Technology Data Exchange (ETDEWEB)

Lince Klinger, F.; Nacif, S.; Martinez, M. P.; Gimenez, M. E.; Ruiz, F.; Alvarez, O.

2011-07-01

A gravimetric study of the Gastre trough in the Province of Chubut, to the southwest of the Canadon Asfalto basin, has allowed us to determine the geometry of its crystalline basement. Using filtering techniques we were able to map residual Bouguer anomalies, which show the heterogeneities situated within the upper crust, some of which are linked to recognised geological structures. The gravimetric minima in the residual Bouguer anomaly map are associated with graben-type basins, flanked by positive gravity values associated with alignments identified on the surface and with the overall topographic relief of the Gastre trough. After suitable treatment of the density values of the outcrops and seismic data we were able to construct a 2D density model, perpendicular to the trough, which indicated a depth of 3600 m. The importance of this study lies in the fact that it has been possible to arrive at a gravimetric characterization of the Gastre trough in the Canadon Asfalto basin sector, a potentially hydrocarbon-bearing area hitherto lacking in reliable data concerning its subsoil. (Author)

Solid-state reaction kinetics and optical studies of cadmium doped magnesium hydrogen phosphate crystals

Science.gov (United States)

Verma, Madhu; Gupta, Rashmi; Singh, Harjinder; Bamzai, K. K.

2018-04-01

The growth of cadmium doped magnesium hydrogen phosphate was successfully carried out by using room temperature solution technique i.e., gel encapsulation technique. Grown crystals were confirmed by single crystal X-ray diffraction (XRD). The structure of the grown crystal belongs to orthorhombic crystal system and crystallizes in centrosymmetric space group. Kinetics of the decomposition of the grown crystals were studied by non-isothermal analysis. Thermo gravimetric / differential thermo analytical (TG/DTA) studies revealed that the grown crystal is stable upto 119 °C. The various steps involved in the thermal decomposition of the material have been analysed using Horowitz-Metzger, Coats-Redfern and Piloyan-Novikova equations for evaluating various kinetic parameters. The optical studies shows that the grown crystals possess wide transmittance in the visible region and significant optical band gap of 5.5ev with cut off wavelength of 260 nm.

Gravimetric and conductometric studies of the sedimentation kinetics in aqueous dispersions of kaoline

International Nuclear Information System (INIS)

Bulavyin, L.A.; Khrapatij, S.V.; Koval'chuk, V.Yi.; Klepko, V.V.; Lebovka, M.Yi.

2006-01-01

Using gravimetric and conductometric methods, the sedimentation kinetics in aqueous suspensions of Alekseev kaoline has been studied for pH value range from 4 to 10. It has been found that pH increasing leads to the decreasing of mean radii of flocks linearly. We found that sedimentation kinetics for intermediate pH values can be described by scaling equations that crossover time defined transition from a gravitational mechanism of deposition to the diffusion one

Gravimetric water distribution assessment from geoelectrical methods (ERT and EMI) in municipal solid waste landfill.

Science.gov (United States)

Dumont, Gaël; Pilawski, Tamara; Dzaomuho-Lenieregue, Phidias; Hiligsmann, Serge; Delvigne, Frank; Thonart, Philippe; Robert, Tanguy; Nguyen, Frédéric; Hermans, Thomas

2016-09-01

The gravimetric water content of the waste material is a key parameter in waste biodegradation. Previous studies suggest a correlation between changes in water content and modification of electrical resistivity. This study, based on field work in Mont-Saint-Guibert landfill (Belgium), aimed, on one hand, at characterizing the relationship between gravimetric water content and electrical resistivity and on the other hand, at assessing geoelectrical methods as tools to characterize the gravimetric water distribution in a landfill. Using excavated waste samples obtained after drilling, we investigated the influences of the temperature, the liquid phase conductivity, the compaction and the water content on the electrical resistivity. Our results demonstrate that Archie's law and Campbell's law accurately describe these relationships in municipal solid waste (MSW). Next, we conducted a geophysical survey in situ using two techniques: borehole electromagnetics (EM) and electrical resistivity tomography (ERT). First, in order to validate the use of EM, EM values obtained in situ were compared to electrical resistivity of excavated waste samples from corresponding depths. The petrophysical laws were used to account for the change of environmental parameters (temperature and compaction). A rather good correlation was obtained between direct measurement on waste samples and borehole electromagnetic data. Second, ERT and EM were used to acquire a spatial distribution of the electrical resistivity. Then, using the petrophysical laws, this information was used to estimate the water content distribution. In summary, our results demonstrate that geoelectrical methods represent a pertinent approach to characterize spatial distribution of water content in municipal landfills when properly interpreted using ground truth data. These methods might therefore prove to be valuable tools in waste biodegradation optimization projects. Copyright © 2016 Elsevier Ltd. All rights reserved.

Evaluation by PIXE external beam-of the leaching efficiency for a thermo stated column for the sand treatment

International Nuclear Information System (INIS)

Aspiazu, J.; Vite, J.; Vivero, R.; Mendez, B.

1995-01-01

The purpose of this paper was to measure the leaching efficiency for a thermo stated column designed to extract metals in muds originated by foundry process. The results obtained were useful to contemplate different alternatives helping to solve the problem of stocking enormous volumes of polluted sand produced by industries. Samples of residual sands and muds (treated sands) coming from an engine factory and from a thermo stated column respectively, were irradiated using an external beam of 3.55 MeV energy protons. From the quantitative analysis PIXE (Proton Induced X-ray Emission), it was possible to establish the level of pollution in sands due to the foundry processes and to evaluate the leaching efficiency of the output liquid phase from the thermo stated column. For polluted sands, certain cases were observed for which the efficiency was not enough to decrease the level of pollution in, e.g., Cu, Zn, Br and Pb. (Author)

Evaluation by PIXE external beam of the leaching efficiency for a thermo stated column for the sand treatment

International Nuclear Information System (INIS)

Aspiazu, J.; Vite, J.; Vivero, R.; Mendez, B.

1995-01-01

The purpose of this paper was to measure the leaching efficiency for a thermo stated column designed to extract metals in muds originated by foundry processes. The results obtained were useful to contemplate different alternatives helping to solve the problem of stocking enormous volumes of polluted sand produced by industries. Samples of residual sands and muds (treated sands) coming from an engine factory and from a thermo stated column respectively, were irradiated using an external beam of 3.55 MeV energy protons. From the quantitative analysis PIXE (Proton Induced X-ray Emission), it was possible to establish the level of pollution in sands due to the foundry processes and to evaluate the leaching efficiency of the output liquid phase from the thermo stated column. For polluted sands, certain cases were observed for which the efficiency was not enough to decrease the level of pollution in e.g., Cu, Zn, Br y Pb. (Author)

Control of the wavelength dependent thermo-optic coefficients in structured fibres

DEFF Research Database (Denmark)

Sørensen, Henrik Rokkjær; Canning, J.; Lægsgaard, Jesper

2006-01-01

By controlling the fibre geometry, the fraction of optical field within the holes and the inserted material of a photonic crystal fibre, we demonstrate that it is possible to engineer any arbitrary wavelength-dependent thermo-optic coefficient. The possibility of making a fibre with a zero temper...... temperature dependent thermo-optic coefficient, ideal for packaging of structured fibre gratings, is proposed and explored....

Gravimetric Measurements of Filtering Facepiece Respirators Challenged With Diesel Exhaust.

Science.gov (United States)

Satish, Swathi; Swanson, Jacob J; Xiao, Kai; Viner, Andrew S; Kittelson, David B; Pui, David Y H

2017-07-01

Elevated concentrations of diesel exhaust have been linked to adverse health effects. Filtering facepiece respirators (FFRs) are widely used as a form of respiratory protection against diesel particulate matter (DPM) in occupational settings. Previous results (Penconek A, Drążyk P, Moskal A. (2013) Penetration of diesel exhaust particles through commercially available dust half masks. Ann Occup Hyg; 57: 360-73.) have suggested that common FFRs are less efficient than would be expected for this purpose based on their certification approvals. The objective of this study was to measure the penetration of DPM through NIOSH-certified R95 and P95 electret respirators to verify this result. Gravimetric-based penetration measurements conducted using polytetrafluoroethylene (PTFE) and polypropylene (PP) filters were compared with penetration measurements made with a Scanning Mobility Particle Sizer (SMPS, TSI Inc.), which measures the particle size distribution. Gravimetric measurements using PP filters were variable compared to SMPS measurements and biased high due to adsorption of gas phase organic material. Relatively inert PTFE filters adsorbed less gas phase organic material resulting in measurements that were more accurate. To attempt to correct for artifacts associated with adsorption of gas phase organic material, primary and secondary filters were used in series upstream and downstream of the FFR. Correcting for adsorption by subtracting the secondary mass from the primary mass improved the result for both PTFE and PP filters but this correction is subject to 'equilibrium' conditions that depend on sampling time and the concentration of particles and gas phase hydrocarbons. Overall, the results demonstrate that the use of filters to determine filtration efficiency of FFRs challenged with diesel exhaust produces erroneous results due to the presence of gas phase hydrocarbons in diesel exhaust and the tendency of filters to adsorb organic material. Published by

Optimization in Friction Stir Welding - With Emphasis on Thermo-mechanical Aspects

DEFF Research Database (Denmark)

Tutum, Cem Celal

combined with classical single-objective and evolutionary multi-objective optimization algorithms (i.e. SQP and NSGA-II), to find the optimum process parameters (heat input, rotational and traverse welding speeds) that would result in favorable thermo-mechanical conditions for the process.......This book deals with the challenging multidisciplinary task of combining variant thermal and thermo-mechanical simulations for the manufacturing process of friction stir welding (FSW) with numerical optimization techniques in the search for optimal process parameters. The FSW process...... is characterized by multiphysics involving solid material flow, heat transfer, thermal softening, recrystallization and the formation of residual stresses. Initially, the thermal models were addressed since they in essence constitute the basis of all other models of FSW. Following this, several integrated thermo-mechanical...

Thermo-elektrische materialen : Peltier energy harvesting

NARCIS (Netherlands)

Beurden, K.M.M. (Karin); Goselink, E.A. (Erik)

2013-01-01

Thermo-elektrische materialen zijn al sinds de 19e eeuw bekend. In 1834 ontdekte de Franse natuurkundige Jean Peltier dat er warmte wordt getransporteerd van de overgang tussen twee metalen wanneer er een elektrische stroom vloeit door het grensvlak. Het grote voordeel van Peltier elementen is dat

Investigations on vertical crustal movements in the Venezuelan Andes by gravimetric methods

Science.gov (United States)

Drewes, H.

1978-01-01

A precise gravimetric network has been installed in the Venezuelan Andes to study eventual gravity changes due to vertical tectonic movements. The design and the measurements of the network are described and the accuracy is estimated. In the center of the region a local gravity network has been reobserved three times. The detected variations are discussed. In order to obtain a genuine statement as far as possible about the significance of observed gravity changes, requirements for the procedure of monitoring precise gravity networks are pointed out.

Method of determination of thermo-acoustic coolant instability boundaries in reactor core at NPPs with WWER

International Nuclear Information System (INIS)

Skalozubov, Volodymyr; Kolykhanov, Viktor; Kovryzhkin, Yuriy

2007-01-01

The regulatory body of Ukraine, the National Atomic Energy Company and the Scientific and Production Centre have led team-works concerned with previously unstudied factors or phenomena affecting reactor safety. As a result it is determined that the thermo-acoustic coolant instability conditions can appear in the core at definite operating WWER regimes. Considerable cyclic dynamic loads affect fuel claddings over thermo-acoustic pressure oscillations. These loads can result in inadmissible cassette design damage and containment damage. Taking into account calculation and experimental research authors submit a method of on-line assessment of WWER core state concerning thermo-acoustic coolant instability. According to this method, the thermo-acoustic coolant instability appearance conditions can be estimated using normal registered parameters (pressure, temperature, heat demand etc.). At operative modes, a WWER-1000 core is stable to tracheotomies oscillations, but reduction of coolant discharge through the core for some times can result in thermo-acoustic coolant instability. Thermo-acoustic instability appears at separate transitional modes concerned with reactor scram and unloading/loading at all power units. When thermo-acoustic instability begins in transitional modes, core elements are under influence of high-frequency coolant pressure pulsations for a long time (tens of hours)

Objective and subjective measures of exercise intensity during thermo-neutral and hot yoga.

Science.gov (United States)

Boyd, Corinne N; Lannan, Stephanie M; Zuhl, Micah N; Mora-Rodriguez, Ricardo; Nelson, Rachael K

2018-04-01

While hot yoga has gained enormous popularity in recent years, owing in part to increased environmental challenge associated with exercise in the heat, it is not clear whether hot yoga is more vigorous than thermo-neutral yoga. Therefore, the aim of this study was to determine objective and subjective measures of exercise intensity during constant intensity yoga in a hot and thermo-neutral environment. Using a randomized, crossover design, 14 participants completed 2 identical ∼20-min yoga sessions in a hot (35.3 ± 0.8 °C; humidity: 20.5% ± 1.4%) and thermo-neutral (22.1 ± 0.2 °C; humidity: 27.8% ± 1.6%) environment. Oxygen consumption and heart rate (HR) were recorded as objective measures (percentage of maximal oxygen consumption and percentage of maximal HR (%HRmax)) and rating of perceived exertion (RPE) was recorded as a subjective measure of exercise intensity. There was no difference in exercise intensity based on percentage of maximal oxygen consumption during hot versus thermo-neutral yoga (30.9% ± 2.3% vs. 30.5% ± 1.8%, p = 0.68). However, exercise intensity was significantly higher during hot versus thermo-neutral yoga based on %HRmax (67.0% ± 2.3% vs. 60.8% ± 1.9%, p = 0.01) and RPE (12 ± 1 vs. 11 ± 1, p = 0.04). According to established exercise intensities, hot yoga was classified as light-intensity exercise based on percentage of maximal oxygen consumption but moderate-intensity exercise based on %HRmax and RPE while thermo-neutral yoga was classified as light-intensity exercise based on percentage of maximal oxygen uptake, %HRmax, and RPE. Despite the added hemodynamic stress and perception that yoga is more strenuous in a hot environment, we observed similar oxygen consumption during hot versus thermo-neutral yoga, classifying both exercise modalities as light-intensity exercise.

Thermo-electric transport in gauge/gravity models with momentum dissipation

Science.gov (United States)

Amoretti, Andrea; Braggio, Alessandro; Maggiore, Nicola; Magnoli, Nicodemo; Musso, Daniele

2014-09-01

We present a systematic definition and analysis of the thermo-electric linear response in gauge/gravity systems focusing especially on models with massive gravity in the bulk and therefore momentum dissipation in the dual field theory. A precise treatment of finite counter-terms proves to be essential to yield a consistent physical picture whose hydrodynamic and beyond-hydrodynamics behaviors noticeably match with field theoretical expectations. The model furnishes a possible gauge/gravity description of the crossover from the quantum-critical to the disorder-dominated Fermi-liquid behaviors, as expected in graphene.

Numerical Signal Analysis of Thermo-Cyclically Operated MOG Gas Sensor Arrays for Early Identification of Emissions from Overloaded Electric Cables

Directory of Open Access Journals (Sweden)

Rolf Seifert

2015-10-01

Full Text Available A thermo-cyclically operated multi metal oxide gas sensor (MOG array is introduced together with a novel signal analysis approach (SimSens for identifying the emissions from overheated isolation cable materials thereby detecting the fires originated in electrical cabinets at early stages. The MOG array can yield specific conductance signatures appropriate to specifically identify gases. The obtained results bear good capability for detection and identification of pyrolysis gas emissions at relatively low sample heating temperatures even before a visible color-change of the polyvinyl chloride (PVC-isolation material. The dynamic conductance signals were evaluated using SimSens, a numerical analysis tool designed for simultaneous evaluation of conductance profiles. The results show promising pyrolysis gas identification and concentration determination capabilities in relation to the conductance profile shapes of model gases like carbon monoxide (CO and propene.

Determination of sulfate in thorium salts using gravimetric technique with previous thorium separation

International Nuclear Information System (INIS)

Silva, C.M. da; Pires, M.A.F.

1994-01-01

Available as short communication only. A simple analytical method to analyze sulfates in thorium salt, is presented. The method is based on the thorium separation as hydroxide. The gravimetric technique is used to analyze the sulfate in the filtered as barium sulfate. Using this method, the sulfate separation from thorium has been reach 99,9% yield, and 0,1% precision. This method is applied to thorium salts specifically thorium sulfate, carbonate and nitrate. (author). 5 refs, 2 tabs

Investigation of cold extrusion process using coupled thermo-mechanical FEM analysis and adaptive friction modeling

Science.gov (United States)

Görtan, Mehmet Okan

2017-10-01

Cold extrusion processes are known for their excellent material usage as well as high efficiency in the production of large batches. Although the process starts at room temperature, workpiece temperatures may rise above 200°C. Moreover, contact normal stresses can exceed 2500 MPa, whereas surface enlargement values can reach up to 30. These changes affects friction coefficients in cold extrusion processes. In the current study, friction coefficients between a plain carbon steel C4C (1.0303) and a tool steel (1.2379) are determined dependent on temperature and contact pressure using the sliding compression test (SCT). In order to represent contact normal stress and temperature effects on friction coefficients, an empirical adaptive friction model has been proposed. The validity of the model has been tested with experiments and finite element simulations for a cold forward extrusion process. By using the proposed adaptive friction model together with thermo-mechanical analysis, the deviation in the process loads between numerical simulations and model experiments could be reduced from 18.6% to 3.3%.

Biological synthesis of ZnO nanoparticles using C. albicans and studying their catalytic performance in the synthesis of steroidal pyrazolines

Directory of Open Access Journals (Sweden)

Shamsuzzaman

2017-05-01

Full Text Available In this study, we describe a green and simple procedure for biosynthesis of ZnO nanoparticles using Candida albicans as eco-friendly reducing and capping agent. The synthesized ZnO nanoparticles were characterized by UV–vis spectroscopy, powder X-ray diffraction, scanning electron microscopy (SEM, transmission electron microscopy (TEM, photoluminescence (PL, thermo gravimetric analysis (TGA and differential thermal analysis (DTA. The prepared nano-particles were used as catalyst for the fast and efficient synthesis of steroidal pyrazolines (4–9 from α, β-unsaturated steroidal ketones (1–3. The target molecules were obtained in good to excellent yields applying the current method.

Synthesis, characterization and antibacterial activity of some 5-aryl-1, 3-Diphenyl 1-4, 5-dihydro-1H-Pyrazoles

International Nuclear Information System (INIS)

Al-Bahtiti, Nawal Hassan

2007-01-01

The condensation of acetophenone (I) with arylaldehyde (II) was investigated and the resulting chalcones 2-Arylidene 1-Acetophenone (III) were reacted with phenyl hydrazine and acetic acid to produce substituted 5-aryl-1, 3-diphenyl-4, 5-dihydro-1H-Pyrazoles (IV). The structures of all products were studied by H-NMR, IR, thermal and elemental analysis. Thermo-gravimetric (TG) and differential thermal analysis (DTA) was applied to investigate the thermal behavior and structure of the synthesized compounds. 2-Pyrazolines (IV) exhibited moderate activity against Streptococcus faecalis ATCC 19433, Klebsiella pneumoniae ATCC 13883, Proteus vulgaris ATCC 25922, Shigella sonnei ATCC 25931 and Peseudom oaeruginosa ATCC 27853. (author)

Dynamic of an intra-continental orogenic prism: thermo-chronologic (apatite fission tracks) and tectonic evolution of the axial zone and the piedmont of the west-central Pyrenees

International Nuclear Information System (INIS)

Meresse, F.

2013-02-01

This work illustrates the application of thermo chronology to the study of the following geologic issue: the tectonic evolution of the Pyrenean oncologic prism. Thermo-chronology gives information on the vertical movements at the scale of geological eras. Thermo-chronology is based on the following principle: the decay of a nucleus gives birth to a daughter nucleus. Above a specific temperature named closure temperature, the daughter element can diffuse outside the system while below the closure temperature, diffusion is not possible. Consequently thermo-chronology can be considered to date the moment when a mineral goes below a a specific closure temperature. Minerals have different closure temperatures and so by using a suite of thermo-chronometers on a single sample, its cooling path through the crust can be reconstructed. This work focuses on apatite fission track (AFT)analysis which is a low temperature thermo-chronometer. In apatites the temperature range between 60 and 120 Celsius degrees corresponds to the partial annealing zone. The spontaneous fission of one U 238 nucleus entails the formation of one fission track. The determination of the initial quantity of U 238 is based on the natural steady ratio U 238 /U 235 which equals 137.88. The initial quantity of U 235 is determined through the neutron irradiation of the sample. The knowledge of the initial quantity of U 238 and the number of tracks in the sample allows the dating of the sample. In this work we combine AFT thermo- chronology with a detailed structural analysis to describe vertical movements related to the thrusting system evolution, and to determine the influence of the latter on the sedimentation/burial/exhumation cycle of the syn-orogenic deposits of the southern fore-land basin

Feasibility study of a Thermo-Photo-Voltaic system for CHP application in residential buildings

International Nuclear Information System (INIS)

Bianchi, Michele; Ferrari, Claudio; Melino, Francesco; Peretto, Antonio

2012-01-01

Highlights: ► The profitability of Thermo-Photo-Voltaic generator systems for a single-family dwelling is analyzed. ► Heat and electricity load profiles depending on hour of the day are considered for an entire year. ► The effect of Thermo-Photo-Voltaic generator size is evaluated for different household utilities. ► Results allow to identify the conditions for the energetic and economic convenience of Thermo-Photo-Voltaic system. -- Abstract: The growing demand of energy coupled with an increasing attention to the environmental impact have forced, in the last decades, toward the study and the development of new strategies in order to reduce primary energy consumptions. The cogeneration (CHP) and the on-site generation (also known as distributed generation) could be the key strategy to achieve this goal; CHP systems allow to reduce the fuel consumption and pollutant emissions (in particular the greenhouse gases) compared to separate generation; moreover on-site-generation contributes to the reduction of the energy which is lost in electricity transmission, and increases the security in the energy supply. In this scenario the Thermo-Photo-Voltaic generation (TPV) is obtaining an increasing attention; TPV is a system to convert into electrical energy the radiation emitted from an artificial heat source (i.e. the combustion of fuel) by the use of photovoltaic cells. A domestic gas furnace based on this technology can provide the entire thermal need of an apartment and can also contributes to satisfy the electrical demand. The aim of this study is the understanding of the behavior of a TPV in CHP application in case of residential buildings, under both the energetic and economical point of view; in particular a parametrical analysis is developed and discussed varying the TPV electrical efficiency, the thermal request and the apartment typology.

Determination of molybdenum by the gravimetric plumbate method (with the molybdenum content from 50 % and above)

International Nuclear Information System (INIS)

Stepin, V.V.; Kurbatova, V.I.; Fedorova, N.D.

1980-01-01

A gravimetric method of molybdenum determination in ferromolybdenum (Mo content from 50% and higher) after its dissolving in HNO 3 is developed. The method is based on Mo deposition in acetic acid solution in the form of molybdenum oxide lead after separation of Fe and other interfering elements with sodium hydroxide [ru

Three-dimensional dynamo-thermo-elastic analysis of a functionally graded cylindrical shell with piezoelectric layers by DQ-FD coupled

International Nuclear Information System (INIS)

Akbari Alashti, R.; Khorsand, M.

2012-01-01

Three-dimensional elastic analysis is carried out for functionally graded cylindrical shells bonded with piezoelectric layers subjected to dynamic and thermal loads. Material properties are assumed to be graded in the radial direction obeying a simple power law with constant Poisson's ratio. Two versions of differential quadrature (DQ) method coupled with the finite difference (FD) method are employed to discretize the governing differential equations in space and time domains. The convergence is studied and results of the axisymmetric loadings are verified with reported results. Effects of the grading index of material properties, thermal gradient, boundary conditions, thickness of piezoelectric layers and electric excitation on stress, displacement, electric and temperature fields are presented. Highlights: ► Dynamo-thermo-elastic analysis of an FGM shell with piezoelectric layer is carried out. ► Governing equations are solved by DQ-FD coupled. ► Effects of grading index, temperature difference and piezoelectric thickness are presented.

Thermo-Elastic Analysis of Internally Cooled Structures Using a Higher Order Theory

Science.gov (United States)

Arnold, Steven M.; Bednarcyk, Brett A.; Aboudi, Jacob

2001-01-01

This paper presents the results of a study on the thermomechanical behavior of internally cooled silicon nitride structures. Silicon nitride is under consideration for elevated temperature aerospace engine applications. and techniques for lowering the operating temperature of structures composed of this material are under development. Lowering the operating temperature provides a large payoff in terms of fatigue life and may be accomplished through the use of thermal barrier coatings (TBC's) and the novel concept of included cooling channels. Herein, an in-depth study is performed on the behavior of a flame-impinged silicon nitride plate with a TBC and internal channels cooled by forced air. The analysis is performed using the higher order theory for functionally graded materials (HOTFGM), which has been developed through NASA Glenn Research Center funding over the past several years. HOTFGM was chosen over the traditional finite element approach as a prelude to an examination of functionally graded silicon nitride structures for which HOTFGM is ideally suited. To accommodate the analysis requirement% of the internally cooled plate problem, two crucial enhancements were made to the two-dimensional Cartesian-based version of HOTFGM. namely, incorporation of internal boundary capabilities and incorporation of convective boundary conditions. Results indicate the viability and large benefits of cooling the plate via forced air through cooling channels. Furthermore, cooling can positively impact the stress and displacement fields present in the plate, yielding an additional payoff in terms of fatigue life. Finally, a spin-off capability resulted from inclusion of internal boundaries within HOTFGM; the ability to simulate the thermo-elastic response of structures with curved surfaces. This new capability is demonstrated, and through comparison with an analytical solution, shown to be viable and accurate.

NRC wants plant-specific responses on Thermo-Lag

International Nuclear Information System (INIS)

Anon.

1994-01-01

Dissatisfied with recent industry-backed efforts to assure fire safety at nuclear power plants, the Nuclear Regulatory Commission announced on November 24 that it would direct all nuclear plant owners to specify the actions they would take to assure that the use of the Thermo-Lag 330 fire barrier material would not lead to insufficient protection of electrical cables connected to safe-shutdown systems. Previously, the NRC had been content to let the matter wait until tests sponsored by the Nuclear Management and Resources Council (Numarc) could show whether Thermo-Lag, used and installed in certain ways, would provide sufficient protection, but the NRC and Numarc have disagreed over the test methodology, and the Numarc tests are now considered to be several months behind schedule

Black Holes Versus Firewalls and Thermo-Field Dynamics

Science.gov (United States)

Chowdhury, Borun D.

2013-09-01

In this paper, we examine the implications of the ongoing black holes versus firewalls debate for the thermo-field dynamics of black holes by analyzing a conformal field theory (CFT) in a thermal state in the context of anti-de Sitter/CFT. We argue that the thermo-field doubled copy of the thermal CFT should be thought of not as a fictitious system, but as the image of the CFT in the heat bath. In case of strong coupling between the CFT and the heat bath, this image allows for free infall through the horizon and the system is described by a black hole. Conversely, firewalls are the appropriate dual description in case of weak interaction of the CFT with its heat bath.

Thermo-electrical systems for the generation of electricity

International Nuclear Information System (INIS)

Bitschi, A.; Froehlich, K.

2010-01-01

This article takes a look at theoretical models concerning thermo-electrical systems for the generation of electricity and demonstrations of technology actually realised. The potentials available and developments are discussed. The efficient use of energy along the whole generation and supply chain, as well as the use of renewable energy sources are considered as being two decisive factors in the attainment of a sustainable energy supply system. The large amount of unused waste heat available today in energy generation, industrial processes, transport systems and public buildings is commented on. Thermo-electric conversion systems are discussed and work being done on the subject at the Swiss Federal Institute of Technology in Zurich is discussed. The findings are discussed and results are presented in graphical form

Mach-Zehnder interferometer implementation for thermo-optical and Kerr effect study

Science.gov (United States)

Bundulis, Arturs; Nitiss, Edgars; Busenbergs, Janis; Rutkis, Martins

2018-04-01

In this paper, we propose the Mach-Zehnder interferometric method for third-order nonlinear optical and thermo-optical studies. Both effects manifest themselves as refractive index dependence on the incident light intensity and are widely employed for multiple opto-optical and thermo-optical applications. With the implemented method, we have measured the Kerr and thermo-optical coefficients of chloroform under CW, ns and ps laser irradiance. The application of lasers with different light wavelengths, pulse duration and energy allowed us to distinguish the processes responsible for refractive index changes in the investigated solution. Presented setup was also used for demonstration of opto-optical switching. Results from Mach-Zehnder experiment were compared to Z-scan data obtained in our previous studies. Based on this, a quality comparison of both methods was assessed and advantages and disadvantages of each method were analyzed.

Thermo-mechanical modeling of laser treatment on titanium cold-spray coatings

Science.gov (United States)

Paradiso, V.; Rubino, F.; Tucci, F.; Astarita, A.; Carlone, P.

2018-05-01

Titanium coatings are very attractive to several industrial fields, especially aeronautics, due to the enhanced corrosion resistance and wear properties as well as improved compatibility with carbon fiber reinforced plastic (CFRP) materials. Cold sprayed titanium coatings, among the others deposition processes, are finding a widespread use in high performance applications, whereas post-deposition treatments are often used to modify the microstructure of the cold-sprayed layer. Laser treatments allow one to noticeably increase the superficial properties of titanium coatings when the process parameters are properly set. On the other hand, the high heat input required to melt titanium particles may result in excessive temperature increase even in the substrate. This paper introduces a thermo-mechanical model to simulate the laser treatment effects on a cold sprayed titanium coating as well as the aluminium substrate. The proposed thermo-mechanical finite element model considers the transient temperature field due to the laser source and applied boundary conditions using them as input loads for the subsequent stress-strain analysis. Numerical outcomes highlighted the relevance of thermal gradients and thermally induced stresses and strains in promoting the damage of the coating.

Modelling the Thermo-Mechanical Behavior of Magnesium Alloys during Indirect Extrusion

International Nuclear Information System (INIS)

Steglich, D.; Ertuerk, S.; Bohlen, J.; Letzig, D.; Brocks, W.

2010-01-01

One of the basic metal forming process for semi-finished products is extrusion. Since extrusion involves complex thermo-mechanical and multiaxial loading conditions resulting in large strains, high strain rates and an increase in temperature due to deformation, a proper yield criterion and hardening law should be used in the numerical modelling of the process. A phenomenological model based on a plastic potential has been proposed that takes strain, strain rate and temperature dependency on flow behaviour into consideration. A hybrid methodology of experiment and finite element simulation has been adopted in order to obtain necessary model parameters. The anisotropy/asymmetry in yielding was quantified by tensile and compression tests of specimens prepared from different directions. The identification of the corresponding model parameters was performed by a genetic algorithm. A fully coupled thermo-mechanical analysis has been used in extrusion simulations for calculation of the temperature field by considering heat fluxes and heat generated due to plastic deformation. The results of the approach adopted in this study appeared to be successful showing promising predictions of the experiments and thus may be extended to be applicable to other magnesium alloys or even other hcp metals.

Study on properties and testing methods of thermo-responsive cementing system for well cementing in heavy oil thermal recovery

Science.gov (United States)

Li, Lianjiang

2017-08-01

In this paper, thermo-responsive cement slurry system were being developed, the properties of conventional cement slurry, compressive strength high temperature of cement sheath, mechanical properties of cement sheath and thermal properties of cement sheath were being tested. Results were being used and simulated by Well-Life Software, Thermo-responsive cement slurry system can meet the requirements of heavy oil thermal recovery production. Mechanical and thermal properties of thermo-responsive cement sheath were being tested. Tensile fracture energy of the thermo-responsive cement sheath is larger than conventional cement. The heat absorption capacity of conventional cement sheath is larger than that of thermo-responsive cement sheath, this means more heat is needed for the unit mass once increasing 1.0 °C, which also indicates that thermo-responsive cement own good heat insulating and preservation effects. The heat conductivity coefficient and thermal expansion coefficient of thermo-responsive cement is less than and conventional cement, this means that thermo-responsive cement have good heat preservation and insulation effects with good thermal expansion stabilities.

Enhanced thermo-mechanical performance and strain-induced ...

Indian Academy of Sciences (India)

Enhanced thermo-mechanical performance and strain-induced band gap reduction of TiO2@PVC nanocomposite films ... School of Chemical Engineering, Yeungnam University, Gyeongsan 712-749, Republic of Korea; School of Mechanical Engineering, Yeungnam University, Gyeongsan 712-749, Republic of Korea ...

Comparison of the gravimetric, phenol red, and 14C-PEG-3350 methods to determine water absorption in the rat single-pass intestinal perfusion model

OpenAIRE

Sutton, Steven C.; Rinaldi, M. T. S.; Vukovinsky, K. E.

2001-01-01

This study was undertaken to determine whether the gravimetric method provided an accurate measure of water flux correction and to compare the gravimetric method with methods that employ nonabsorbed markers (eg, phenol red and 14C-PEG-3350). Phenol red, 14C-PEG-3350, and 4-[2-[[2-(6-amino-3-pyridinyl)-2-hydroxyethyl]amino]ethoxy]-methyl ester, (R)-benzene acetic acid (Compound I) were co-perfused in situ through the jejunum of 9 anesthetized rats (single-pass intestinal perfusion [SPIP]). Wat...

Gross greenhouse gas fluxes from hydro-power reservoir compared to thermo-power plants

International Nuclear Information System (INIS)

Santos, Marco Aurelio dos; Pinguelli Rosa, Luiz; Sikar, Bohdan; Sikar, Elizabeth; Santos, Ednaldo Oliveira dos

2006-01-01

This paper presents the findings of gross carbon dioxide and methane emissions measurements in several Brazilian hydro-reservoirs, compared to thermo power generation. The term 'gross emissions' means gas flux measurements from the reservoir surface without natural pre-impoundment emissions by natural bodies such as the river channel, seasonal flooding and terrestrial ecosystems. The net emissions result from deducting pre-existing emissions by the reservoir. A power dam emits biogenic gases such as CO 2 and CH 4 . However, studies comparing gas emissions (gross emissions) from the reservoir surface with emissions by thermo-power generation technologies show that the hydro-based option presents better results in most cases analyzed. In this study, measurements were carried in the Miranda, Barra Bonita, Segredo, Tres Marias, Xingo, and Samuel and Tucurui reservoirs, located in two different climatological regimes. Additional data were used here from measurements taken at the Itaipu and Serra da Mesa reservoirs. Comparisons were also made between emissions from hydro-power plants and their thermo-based equivalents. Bearing in mind that the estimated values for hydro-power plants include emissions that are not totally anthropogenic, the hydro-power plants studied generally posted lower emissions than their equivalent thermo-based counterparts. Hydro-power complexes with greater power densities (capacity/area flooded-W/m 2 ), such as Itaipu, Xingo, Segredo and Miranda, have the best performance, well above thermo-power plants using state-of-the-art technology: combined cycle fueled by natural gas, with 50% efficiency. On the other hand, some hydro-power complexes with low-power density perform only slightly better or even worse than their thermo-power counterparts

Thermo-fluid behaviour of periodic cellular metals

CERN Document Server

Lu, Tian Jian; Wen, Ting

2013-01-01

Thermo-Fluid Behaviour of Periodic Cellular Metals introduces the study of coupled thermo-fluid behaviour of cellular metals with periodic structure in response to thermal loads, which is an interdisciplinary research area that requires a concurrent-engineering approach.  The book, for the first time, systematically adopts experimental, numerical, and analytical approaches, presents the fluid flow and heat transfer in periodic cellular metals under forced convection conditions, aiming to establish structure-property relationships for tailoring material structures to achieve properties and performance levels that are customized for defined multifunctional applications. The book, as a textbook and reference book, is intended for both academic and industrial people, including graduate students, researchers and engineers. Dr. Tian Jian Lu is a professor at the School of Aerospace, Xi’an Jiaotong University, Xi’an, China. Dr. Feng Xu is a professor at the Key Laboratory of Biomedical Information Engineering o...

Effective thermo-mechanical properties and shape memory effect of CNT/SMP composites

Science.gov (United States)

Yang, Qingsheng; Liu, Xia; Leng, Fangfang

2009-07-01

Shape memory polymer (SMP) has been applied in many fields as intelligent sensors and actuators. In order to improve the mechanical properties and recovery force of SMP, the addition of minor amounts of carbon nanotubes (CNT) into SMP has attracted wide attention. A micromechanical model and thermo-mechanical properties of CNT/SMP composites were studied in this paper. The thermo-mechanical constitutive relation of intellectual composites with isotropic and transversely isotropic CNT was obtained. Moreover, the shape memory effect of CNT/SMP composites and the effect of temperature and the volume fraction of CNT were discussed. The work shows that CNT/SMP composites exhibit excellent macroscopic thermo-mechanical properties and shape memory effect, while both of them can be affected remarkably by temperature and the microstructure parameters.

A binder-free NiCo2O4 nanosheet/3D elastic N-doped hollow carbon nanotube sponge electrode with high volumetric and gravimetric capacitances for asymmetric supercapacitors.

Science.gov (United States)

Tong, Hao; Yue, Shihong; Lu, Liang; Jin, Fengqiao; Han, Qiwei; Zhang, Xiaogang; Liu, Jie

2017-11-09

To increase the volumetric and gravimetric capacitances of supercapacitors, a new class of electrode materials with high electrochemical activity and favorable structures is extremely desired. In this work, a hollow novel nitrogen-doped 3D elastic single-walled carbon nanotube sponge (NSCS) which is ultra lightweight with the lowest density of 0.8 mg cm -3 , and has a high open surface structure for electrolyte accessibility and excellent compressible properties as the electrode scaffold has been successfully fabricated by the pyrolysis method which could produce the carbon nanotube sponge easily on a large scale without high-cost and time-consuming processes. Moreover, a NiCo 2 O 4 nanosheet supported on the NSCS has been successfully fabricated. The highest volumetric and gravimetric capacitance of this electrode is 790 F cm -3 at 1.43 g cm -3 and 1618 F g -1 at 0.54 g cm -3 with excellent cycling stability. The density of NiCo 2 O 4 /NSCS electrode was adjusted by mechanical compression and the most favorable density of the film for both high volumetric and gravimetric capacitances obtained was 1.21 g cm -3 . The thick NiCo 2 O 4 /NSCS film of 72 μm has been fabricated at this favorable density, presenting both high volumetric and gravimetric capacitances of 597 F cm -3 and 1074 F g -1 at 1 A g -1 , respectively, indicating that the structure of the NSCS is extremely feasible for obtaining a thick film electrode with excellent volumetric and gravimetric capacitances. Furthermore, an asymmetric supercapacitor of NiCo 2 O 4 /NSCS//NGN/CNTs was fabricated, exhibiting a high gravimetric energy density of 47.65 W h kg -1 at 536 W kg -1 and a volumetric energy density of 33.44 W h L -1 at 376.16 W L -1 .

Case-study of thermo active building systems in Japanese climate

DEFF Research Database (Denmark)

Li, Rongling; Yoshidomi, Togo; Ooka, Ryozo

2015-01-01

Thermo active building systems (TABS) have been applied in office buildings as a promising energy efficient solution in many European countries. The utilization of building thermal mass helps to provide high quality thermal environments with less energy consumption. However, the concept of TABS...... is entirely new in Japan. This paper introduces and evaluates TABS under Tokyo weather conditions to clarify the potential of use TABS in Japan. Cooling capacity of thermo active building systems used in an office building was evaluated by means of dynamic simulations. Two central rooms of the office were...

Studies on thermo-elastic heating of horns used in ultrasonic plastic welding.

Science.gov (United States)

Roopa Rani, M; Prakasan, K; Rudramoorthy, R

2015-01-01

Ultrasonic welding horn is half wavelength section or tool used to focus the ultrasonic vibrations to the components being welded. The horn is designed in such a way that it maximizes the amplitude of the sound wave passing through it. The ends of the horn represent the displacement anti-nodes and the center the 'node' of the wave. As the horns perform 20,000 cycles of expansion and contraction per second, they are highly stressed at the nodes and are heated owing to thermo-elastic effects. Considerable temperature rise may be observed in the horn, at the nodal region when working at high amplitudes indicating high stress levels leading to failure of horns due to cyclic loading. The limits for amplitude must therefore be evaluated for the safe working of the horn. Horns made of different materials have different thermo-elastic behaviors and hence different temperatures at the nodes and antinodes. This temperature field can be used as a control mechanism for setting the amplitude/weld parameters. Safe stress levels can be predicted using modal and harmonic analyses followed by a stress analysis to study the effect of cyclic loads. These are achieved using 'Ansys'. The maximum amplitude level obtained from the stress analysis is used as input for 'Comsol' to predict the temperature field. The actual temperature developed in the horn during operation is measured using infrared camera and compared with the simulated temperature. From experiments, it is observed that horn made of titanium had the lowest temperature rise at the critical region and can be expected to operate at amplitudes up to 77 μm without suffering failure due to cyclic loading. The method of predicting thermo-elastic stresses and temperature may be adopted by the industry for operating the horn within the safe stress limits thereby extending the life of the horn. Copyright © 2014 Elsevier B.V. All rights reserved.

Thermo-hydraulic-mechanical analysis of the SS-050 sodium loop during a thermal shock of 2000C/s

International Nuclear Information System (INIS)

Jesus Miranda, C.A. de; Gebrin, A.N.

1988-01-01

An analytical thermo-hydraulic model was developed to obtain the temperature of the sodium flowing between the mixing tank TM of constant volume and the drain tank of the SS-050 sodium test facility. The piping connecting these two tanks is considered in the analysis. The sodium enters in the TM through a tube with lateral holes immersed in the TM's sodium. The model and relative computer program were tested and a typical situation was studied: a thermal shock with -200 0 C/s of thermal gradient in the test section. The sodium temperature time-histories along the piping length are presented. For the thermal shock situation, the temperature field in the TM bottom and outlet nozzle was calculated and the stresses were evaluated. The final thermal stresses will allow a detailed verification of the circuit design. (author) [pt

Cyclopentadiene-functionalized polyketone as self-cross-linking thermo-reversible thermoset with increased softening temperature

NARCIS (Netherlands)

Toncelli, Claudio; Bouwhuis, Stephan; Broekhuis, Antonius Augustinus; Picchioni, Francesco

2016-01-01

Self-cross-linkable thermo-reversible thermosets were obtained by a two-steps post-functionalization of aliphatic alternating polyketones yielding two different cyclopentadiene functionalization degree of 9 and 22% (with the respect of initial 1,4-dicarbonyl units). Thermo-reversibility was verified

Effects of thermo-chemical pre-treatment on anaerobic biodegradability and hydrolysis of lignocellulosic biomass

NARCIS (Netherlands)

Fernandes, T.; Klaasse Bos, G.J.; Zeeman, G.; Sanders, J.P.M.; Lier, van J.B.

2009-01-01

The effects of different thermo-chemical pre-treatment methods were determined on the biodegradability and hydrolysis rate of lignocellulosic biomass. Three plant species, hay, straw and bracken were thermo-chemically pre-treated with calcium hydroxide, ammonium carbonate and maleic acid. After

Investigation on polyetheretherketone composite for long term storage of nuclear waste

Science.gov (United States)

Ajeesh, G.; Bhowmik, Shantanu; Sivakumar, Venugopal; Varshney, Lalit; Kumar, Virendra; Abraham, Mathew

2015-12-01

This investigation highlights the effect of radiation, chemical and thermal environments on mechanical and thermal properties of Polyetheretherketone (PEEK) composites, which could prove to be an alternative material for long term storage of nuclear wastes. The tests are conducted on specimens made from PEEK and PEEK reinforced with carbon short fiber. The specimens are subjected to radiation doses, equivalent to the cumulative dosage for 500 years followed by exposure under highly corrosive and thermal environments. Studies under optical microscopy reveal that the dispersion of carbon short fiber in the PEEK Composites is significantly uniform. Differential scanning calorimeter (DSC) and thermo gravimetric analysis (TGA) indicates that there are no significant changes in thermal properties of PEEK composite when exposed to aggressive environments. It is further observed that there are no significant changes in mechanical properties of the composite after exposure to radiation and thermo-chemical environment.

Investigation on polyetheretherketone composite for long term storage of nuclear waste

International Nuclear Information System (INIS)

Ajeesh, G.; Bhowmik, Shantanu; Sivakumar, Venugopal; Varshney, Lalit; Kumar, Virendra; Abraham, Mathew

2015-01-01

This investigation highlights the effect of radiation, chemical and thermal environments on mechanical and thermal properties of Polyetheretherketone (PEEK) composites, which could prove to be an alternative material for long term storage of nuclear wastes. The tests are conducted on specimens made from PEEK and PEEK reinforced with carbon short fiber. The specimens are subjected to radiation doses, equivalent to the cumulative dosage for 500 years followed by exposure under highly corrosive and thermal environments. Studies under optical microscopy reveal that the dispersion of carbon short fiber in the PEEK Composites is significantly uniform. Differential scanning calorimeter (DSC) and thermo gravimetric analysis (TGA) indicates that there are no significant changes in thermal properties of PEEK composite when exposed to aggressive environments. It is further observed that there are no significant changes in mechanical properties of the composite after exposure to radiation and thermo-chemical environment.

Water-cooled lithium-lead box-shaped blanket concept for Demo: thermo-mechanical optimization and manufacturing sequence proposal

International Nuclear Information System (INIS)

Baraer, L.; Dinot, N.; Giancarli, L.; Proust, E.; Salavy, J.F.; Severi, Y.; Quintric-Bossy, J.

1992-01-01

The development of the water-cooled lithium-lead box-shaped blanket concept for DEMO has now reached the stage of thermo-mechanical optimization. In the previous design phases the preliminary dimensioning of the cooling circuit has permitted to define the water proportions required in the breeder region and to demonstrate, after a minimization of steel proportion and thicknesses, that this concept could reach tritium breeding self-sufficiency. In the present analysis the location of the coolant pipes has been optimized for the whole equatorial plane cross-section of both inboard and outboard segments in order to maintain the maximum Pb-17Li/steel interface temperature below 480 deg C and to minimize the thermal gradients along the steel structures. The consequent thermo-mechanical analysis has shown that the thermal stresses always remain below the allowable limits. Segment fabricability and removal are the next design issues to be analyzed. Within this strategy, a first manufactury sequence for the outboard segment is proposed

Basic rock properties for the thermo-hydro-mechanical analysis of a high-level radioactive waste repository

Energy Technology Data Exchange (ETDEWEB)

Kim, Jhin Wung; Kang, Chul Hyung

1999-04-01

Deep geological radioactive waste disposal is generally based on the isolation of the waste from the biosphere by multiple barriers. The host rock is one of these barriers which should provide a stable mechanical and chemical environment for the engineered barriers. In the evaluation of the safety of the high-level radioactive waste disposal systems, an important part of the safety analysis is an assessment of the coupling or interaction between thermal, hydrological, and mechanical effects. In order to do this assessment, adequate data on the characteristics of different host rocks are necessary. The properties of the rock and rock discontinuity are very complex and their values vary in a wide range. The accuracy of the result of the assessment depends on the values of these properties used. The present study is an attempt to bring together and condense data for the basic properties of various rock masses, which are needed in the thermo-hydro-mechanical analysis for the deep geological radioactive waste repository. The testing and measurement methods for these basic properties are also presented. Domestic data for deep geological media should be supplemented in the future, due to the insufficiency and the lack of accuracy of the data available at present. (author). 28 refs., 21 figs.

Basic rock properties for the thermo-hydro-mechanical analysis of a high-level radioactive waste repository

International Nuclear Information System (INIS)

Kim, Jhin Wung; Kang, Chul Hyung

1999-04-01

Deep geological radioactive waste disposal is generally based on the isolation of the waste from the biosphere by multiple barriers. The host rock is one of these barriers which should provide a stable mechanical and chemical environment for the engineered barriers. In the evaluation of the safety of the high-level radioactive waste disposal systems, an important part of the safety analysis is an assessment of the coupling or interaction between thermal, hydrological, and mechanical effects. In order to do this assessment, adequate data on the characteristics of different host rocks are necessary. The properties of the rock and rock discontinuity are very complex and their values vary in a wide range. The accuracy of the result of the assessment depends on the values of these properties used. The present study is an attempt to bring together and condense data for the basic properties of various rock masses, which are needed in the thermo-hydro-mechanical analysis for the deep geological radioactive waste repository. The testing and measurement methods for these basic properties are also presented. Domestic data for deep geological media should be supplemented in the future, due to the insufficiency and the lack of accuracy of the data available at present. (author). 28 refs., 21 figs

Large thermo-erosional tunnel for a river in northeast Greenland

Science.gov (United States)

Docherty, Catherine L.; Hannah, David M.; Riis, Tenna; Rosenhøj Leth, Simon; Milner, Alexander M.

2017-12-01

Thermo-erosional river bank undercutting is caused by the combined action of thermal and mechanical erosion of the permafrost by Arctic rivers whilst the overlying sediment withstands collapse temporarily. Here, we report the discovery of a large thermo-erosional tunnel that formed in the banks of a meltwater-fed stream in northeast Greenland in summer 2015. The tunnel was observed over eight days (14-22 July), during which period the tunnel remained open but bank-side slumping increased. Stream solute load increased immediately downstream and remained high 800 m from the tunnel. Whilst this field observation was opportunistic and information somewhat limited, our study provides a rare insight into an extreme event impacting permafrost, local geomorphology and stream habitat. With accelerated climate change in Arctic regions, increased permafrost degradation and warmer stream water temperature are predicted thereby enhancing potential for thermo-erosional niche development and associated stream bank slumping. This change could have significant implications for stream physicochemical habitat and, in turn, stream benthic communities, through changes in aquatic habitat conditions.

Oxidation kinetics of reaction products formed in uranium metal corrosion.

Energy Technology Data Exchange (ETDEWEB)

Totemeier, T. C.

1998-04-22

The oxidation behavior of uranium metal ZPPR fuel corrosion products in environments of Ar-4%O{sub 2} and Ar-20%O{sub 2} were studied using thermo-gravimetric analysis (TGA). These tests were performed to extend earlier work in this area specifically, to assess plate-to-plate variations in corrosion product properties and the effect of oxygen concentration on oxidation behavior. The corrosion products from two relatively severely corroded plates were similar, while the products from a relatively intact plate were not reactive. Oxygen concentration strongly affected the burning rate of reactive products, but had little effect on low-temperature oxidation rates.

“Turn on” fluorescence enhancement of Zn octacarboxyphthaloyanine-graphene oxide conjugates by hydrogen peroxide

Energy Technology Data Exchange (ETDEWEB)

Shumba, Munyaradzi; Mashazi, Philani; Nyokong, Tebello, E-mail: t.nyokong@ru.ac.za

2016-02-15

Zn octacarboxy phthalocyanine-reduced graphene oxide or graphene oxide conjugates were characterized by absorption spectroscopy, transmission electron microscopy, fluorescence spectroscopy, X-ray diffraction, thermo gravimetric analysis and X-ray photon spectroscopy. The presence of reduced graphene oxide or graphene oxide resulted in the quenching (turn on) of Zn octacarboxy phthalocyanine fluorescence which can be explained by photoinduced electron transfer. Zn octacarboxy phthalocyanine-reduced graphene oxide or graphene oxide conjugates “turned on” fluorescence showed a linear response to hydrogen peroxide hence their potential to be used as sensors. The nanoprobe developed showed high selectivity towards hydrogen peroxide in the presence of physiological interferences.

“Turn on” fluorescence enhancement of Zn octacarboxyphthaloyanine-graphene oxide conjugates by hydrogen peroxide

International Nuclear Information System (INIS)

Shumba, Munyaradzi; Mashazi, Philani; Nyokong, Tebello

2016-01-01

Zn octacarboxy phthalocyanine-reduced graphene oxide or graphene oxide conjugates were characterized by absorption spectroscopy, transmission electron microscopy, fluorescence spectroscopy, X-ray diffraction, thermo gravimetric analysis and X-ray photon spectroscopy. The presence of reduced graphene oxide or graphene oxide resulted in the quenching (turn on) of Zn octacarboxy phthalocyanine fluorescence which can be explained by photoinduced electron transfer. Zn octacarboxy phthalocyanine-reduced graphene oxide or graphene oxide conjugates “turned on” fluorescence showed a linear response to hydrogen peroxide hence their potential to be used as sensors. The nanoprobe developed showed high selectivity towards hydrogen peroxide in the presence of physiological interferences.

Generation of drugs coated iron nanoparticles through high energy ball milling

Energy Technology Data Exchange (ETDEWEB)

Radhika Devi, A.; Murty, B. S. [Department of Metallurgical and Materials Engineering, Indian Institute of Technology Madras, Chennai 600036 (India); Chelvane, J. A. [Defence Metallurgical Research Laboratory, Hyderabad 500058 (India); Prabhakar, P. K.; Padma Priya, P. V.; Doble, Mukesh [Department of Biotechnology, Indian Institute of Technology Madras, Chennai 600036 (India)

2014-03-28

The iron nanoparticles coated with oleic acid and drugs such as folic acid/Amoxicillin were synthesized by high energy ball milling and characterized by X-ray diffraction, Transmission electron microscope, zeta potential, dynamic light scattering, Fourier Transform Infra red (FT-IR) measurements, and thermo gravimetric analysis (TGA). FT-IR and TGA measurements show good adsorption of drugs on oleic acid coated nanoparticles. Magnetic measurements indicate that saturation magnetization is larger for amoxicillin coated particles compared to folic acid coated particles. The biocompatibility of the magnetic nanoparticles prepared was evaluated by in vitro cytotoxicity assay using L929 cells as model cells.

Oxidation kinetics of reaction products formed in uranium metal corrosion

International Nuclear Information System (INIS)

Totemeier, T. C.

1998-01-01

The oxidation behavior of uranium metal ZPPR fuel corrosion products in environments of Ar-4%O 2 and Ar-20%O 2 were studied using thermo-gravimetric analysis (TGA). These tests were performed to extend earlier work in this area specifically, to assess plate-to-plate variations in corrosion product properties and the effect of oxygen concentration on oxidation behavior. The corrosion products from two relatively severely corroded plates were similar, while the products from a relatively intact plate were not reactive. Oxygen concentration strongly affected the burning rate of reactive products, but had little effect on low-temperature oxidation rates

Synthesis of C60(OH)18-20 in aqueous alkaline solution under O2-atmosphere

International Nuclear Information System (INIS)

Alves, Gustavo Catao; Ladeira, Luiz Orlando; Righi, Ariete; Krambrock, Klaus; Pinheiro, Mauricio Veloso B.; Calado, Hallen Daniel; Gil, Rossimiriam Pereira de Freitas

2006-01-01

In this work we report on an alternative synthesis of water-soluble fullerenes known as fullerols, aiming for biomedical applications. The synthesis is based on a process in which polyethylene glycol (PEG400) is used as phase-transfer catalyst between fullerene/benzene and aqueous NaOH solutions. The polyhydroxylation of the fullerenes occurs in the NaOH solution under a continuous flow of O 2 to enhance the reaction yield. The resulting compound was characterized with infrared spectroscopy, nuclear magnetic resonance, thermo-gravimetric analysis and optical absorption. The formation of C 60 (OH) 18-20 in high yields was confirmed. (author)

The Preparation and Properties of Thermo-reversibly Cross-linked Rubber Via Diels-Alder Chemistry

NARCIS (Netherlands)

Polgar, Lorenzo Massimo; van Duin, Martin; Picchioni, Francesco

2016-01-01

A method for using Diels Alder thermo-reversible chemistry as cross-linking tool for rubber products is demonstrated. In this work, a commercial ethylene-propylene rubber, grafted with maleic anhydride, is thermo-reversibly cross-linked in two steps. The pending anhydride moieties are first modified

Study of the structural integrity of thermo-wells. Application to Class I components

International Nuclear Information System (INIS)

Gavilan Moreno, C. J.

2010-01-01

This paper provides a methodology to determine a thermo-well failure. The practical application will be made on a thermo-well in Cofrentes Nuclear Power Plant. This will be designed by the existence of a spare one and it will be determined the eigenfrequencies, the vortex emission frequencies in the flow, the susceptibility to fatigue, the loads, etc.

Statistical optimization of thermo-alkali stable xylanase production from Bacillus tequilensis strain ARMATI

Directory of Open Access Journals (Sweden)

Ameer Khusro

2016-07-01

Conclusions: The cellulase-free xylanase showed an alkali-tolerant and thermo-stable property with potentially applicable nature at industrial scale. This statistical approach established a major contribution in enzyme production from the isolate by optimizing independent factors and represents a first reference on the enhanced production of thermo-alkali stable cellulase-free xylanase from B. tequilensis.

Solar-driven thermo- and electrochemical degradation of nitrobenzene in wastewater: Adaptation and adoption of solar STEP concept

International Nuclear Information System (INIS)

Gu, Di; Shao, Nan; Zhu, Yanji; Wu, Hongjun; Wang, Baohui

2017-01-01

Highlights: • STEP for NB treatment was established without input of energy and chemicals. • Treatment of NB was theoretically and experimentally studied by STEP. • The results demonstrated that STEP is more efficient than classical AOPs. • The mechanism of STEP was illustratively presented for NB wastewater. - Abstract: The STEP concept has successfully been demonstrated for driving chemical reaction by utilization of solar heat and electricity to minimize the fossil energy, meanwhile, maximize the rate of thermo- and electrochemical reactions in thermodynamics and kinetics. This pioneering investigation experimentally exhibit that the STEP concept is adapted and adopted efficiently for degradation of nitrobenzene. By employing the theoretical calculation and thermo-dependent cyclic voltammetry, the degradation potential of nitrobenzene was found to be decreased obviously, at the same time, with greatly lifting the current, while the temperature was increased. Compared with the conventional electrochemical methods, high efficiency and fast degradation rate were markedly displayed due to the co-action of thermo- and electrochemical effects and the switch of the indirect electrochemical oxidation to the direct one for oxidation of nitrobenzene. A clear conclusion on the mechanism of nitrobenzene degradation by the STEP can be schematically proposed and discussed by the combination of thermo- and electrochemistry based the analysis of the HPLC, UV–vis and degradation data. This theory and experiment provide a pilot for the treatment of nitrobenzene wastewater with high efficiency, clean operation and low carbon footprint, without any other input of energy and chemicals from solar energy.

Thermo-mechanical Modelling of Pebble Beds in Fusion Blankets and its Implementation by a Return-Mapping Algorithm

International Nuclear Information System (INIS)

Gan, Yixiang; Kamlah, Marc

2008-01-01

In this investigation, a thermo-mechanical model of pebble beds is adopted and developed based on experiments by Dr. Reimann at Forschungszentrum Karlsruhe (FZK). The framework of the present material model is composed of a non-linear elastic law, the Drucker-Prager-Cap theory, and a modified creep law. Furthermore, the volumetric inelastic strain dependent thermal conductivity of beryllium pebble beds is taken into account and full thermo-mechanical coupling is considered. Investigation showed that the Drucker-Prager-Cap model implemented in ABAQUS can not fulfill the requirements of both the prediction of large creep strains and the hardening behaviour caused by creep, which are of importance with respect to the application of pebble beds in fusion blankets. Therefore, UMAT (user defined material's mechanical behaviour) and UMATHT (user defined material's thermal behaviour) routines are used to re-implement the present thermo-mechanical model in ABAQUS. An elastic predictor radial return mapping algorithm is used to solve the non-associated plasticity iteratively, and a proper tangent stiffness matrix is obtained for cost-efficiency in the calculation. An explicit creep mechanism is adopted for the prediction of time-dependent behaviour in order to represent large creep strains in high temperature. Finally, the thermo-mechanical interactions are implemented in a UMATHT routine for the coupled analysis. The oedometric compression tests and creep tests of pebble beds at different temperatures are simulated with the help of the present UMAT and UMATHT routines, and the comparison between the simulation and the experiments is made. (authors)

Solar-driven thermo- and electrochemical degradation of nitrobenzene in wastewater: Adaptation and adoption of solar STEP concept

Energy Technology Data Exchange (ETDEWEB)

Gu, Di; Shao, Nan; Zhu, Yanji; Wu, Hongjun; Wang, Baohui, E-mail: wangbh@nepu.edu.cn

2017-01-05

Highlights: • STEP for NB treatment was established without input of energy and chemicals. • Treatment of NB was theoretically and experimentally studied by STEP. • The results demonstrated that STEP is more efficient than classical AOPs. • The mechanism of STEP was illustratively presented for NB wastewater. - Abstract: The STEP concept has successfully been demonstrated for driving chemical reaction by utilization of solar heat and electricity to minimize the fossil energy, meanwhile, maximize the rate of thermo- and electrochemical reactions in thermodynamics and kinetics. This pioneering investigation experimentally exhibit that the STEP concept is adapted and adopted efficiently for degradation of nitrobenzene. By employing the theoretical calculation and thermo-dependent cyclic voltammetry, the degradation potential of nitrobenzene was found to be decreased obviously, at the same time, with greatly lifting the current, while the temperature was increased. Compared with the conventional electrochemical methods, high efficiency and fast degradation rate were markedly displayed due to the co-action of thermo- and electrochemical effects and the switch of the indirect electrochemical oxidation to the direct one for oxidation of nitrobenzene. A clear conclusion on the mechanism of nitrobenzene degradation by the STEP can be schematically proposed and discussed by the combination of thermo- and electrochemistry based the analysis of the HPLC, UV–vis and degradation data. This theory and experiment provide a pilot for the treatment of nitrobenzene wastewater with high efficiency, clean operation and low carbon footprint, without any other input of energy and chemicals from solar energy.

Distribution of apparent activation energy counterparts during thermo - And thermo-oxidative degradation of Aronia melanocarpa (black chokeberry).

Science.gov (United States)

Janković, Bojan; Marinović-Cincović, Milena; Janković, Marija

2017-09-01

Kinetics of degradation for Aronia melanocarpa fresh fruits in argon and air atmospheres were investigated. The investigation was based on probability distributions of apparent activation energy of counterparts (ε a ). Isoconversional analysis results indicated that the degradation process in an inert atmosphere was governed by decomposition reactions of esterified compounds. Also, based on same kinetics approach, it was assumed that in an air atmosphere, the primary compound in degradation pathways could be anthocyanins, which undergo rapid chemical reactions. A new model of reactivity demonstrated that, under inert atmospheres, expectation values for ε a occured at levels of statistical probability. These values corresponded to decomposition processes in which polyphenolic compounds might be involved. ε a values obeyed laws of binomial distribution. It was established that, for thermo-oxidative degradation, Poisson distribution represented a very successful approximation for ε a values where there was additional mechanistic complexity and the binomial distribution was no longer valid. Copyright © 2017 Elsevier Ltd. All rights reserved.

GRAVIMETRIC-DETERMINATION OF THE WATER CONCENTRATION IN WHOLE-BLOOD, PLASMA AND ERYTHROCYTES AND CORRELATIONS WITH HEMATOLOGICAL AND CLINICOCHEMICAL PARAMETERS

NARCIS (Netherlands)

LIJNEMA, TH; HUIZENGA, [No Value; JAGER, J; MACKOR, AJ; GIPS, CH

1993-01-01

We have assessed gravimetric methods for determination of intravascular water, established whole blood-, plasma- and erythrocyte water reference values in a healthy volunteer group (n = 97, 48 females) and correlated these variables with 30 simultaneous hematological, clinicochemical and body

Numerical investigation on the thermo-mechanical behavior of a quadratic cross section pile heat exchanger

DEFF Research Database (Denmark)

Alberdi Pagola, Maria; Madsen, Søren; Lund Jensen, Rasmus

2017-01-01

Pile heat exchangers are traditional foundation piles with built in heat exchangers. As such, the footing of the building both serves as a structural component and a heating/cooling supply element. The existing geotechnical design standards do not consider the nature of thermo-active foundations...... and, therefore, there is a need to develop guidelines to design them properly. This paper contributes by studying the thermo-mechanical behavior of the precast piles which are 15-meter long and have a quadratic cross section and a W-shape pipe heat exchanger. This article aims to numerically assess...... the additional changes in the pile load transfer generated by its heating and cooling. In addressing this objective, a preliminary multi-physical finite element analysis is conducted which serves as a tool for exploring: i) the thermally induced mechanical stresses within the concrete and on the pile-soil axial...

Optimization of the cooling circuit and thermo-mechanical analysis for the extraction grid of ELISE

International Nuclear Information System (INIS)

Nocentini, R.; Gutser, R.; Heinemann, B.; Froeschle, M.; Riedl, R.

2011-01-01

The NNBI test facility ELISE ('Extraction from a Large Ion Source Experiment'), presently under construction at IPP, will have an extraction area with the same width and half the height of the ITER source, acceleration up to 60 kV, for 10 s, every 180 s, and plasma generation up to 1 h. Electrons are co-extracted from the ion source. Suppression magnets in the extraction grid deflect the electrons onto the extraction grid surface. For 30 mA/cm 2 extracted electron current density and 10 kV extraction voltage, localized power density is in the order of 39 MW/m 2 near the grid apertures and a total heat load of 150 kW is deposited onto each extraction grid segment. Heat removal is provided by a water circuit inside the grid. For ELISE, a new cooling circuit has been developed to provide a more reliable operation. The optimization of the cooling circuit and the thermo-mechanical analysis of the extraction grid of ELISE, considering maximum grid temperature, mechanical stresses and grid deformation, has been performed using the codes KOBRA3, TrajAn, the ANSYS finite element package and the fluid dynamics code CFX.

Understanding Fast and Robust Thermo-osmotic Flows through Carbon Nanotube Membranes: Thermodynamics Meets Hydrodynamics.

Science.gov (United States)

Fu, Li; Merabia, Samy; Joly, Laurent

2018-04-19

Following our recent theoretical prediction of the giant thermo-osmotic response of the water-graphene interface, we explore the practical implementation of waste heat harvesting with carbon-based membranes, focusing on model membranes of carbon nanotubes (CNT). To that aim, we combine molecular dynamics simulations and an analytical model considering the details of hydrodynamics in the membrane and at the tube entrances. The analytical model and the simulation results match quantitatively, highlighting the need to take into account both thermodynamics and hydrodynamics to predict thermo-osmotic flows through membranes. We show that, despite viscous entrance effects and a thermal short-circuit mechanism, CNT membranes can generate very fast thermo-osmotic flows, which can overcome the osmotic pressure of seawater. We then show that in small tubes confinement has a complex effect on the flow and can even reverse the flow direction. Beyond CNT membranes, our analytical model can guide the search for other membranes to generate fast and robust thermo-osmotic flows.

Global thermo-mechanical effects from a KBS-3 type repository

International Nuclear Information System (INIS)

Hakami, E.; Olofsson, Stig-Olof

1998-01-01

The objective of this study has been to identify the global thermo-mechanical effects in the bedrock hosting a nuclear waste repository. Numerical thermo-mechanical modeling using distinct element models was performed. The number of fracture zones, the heat intensity of the waste, the material properties of the rock mass and the boundary conditions of the models were varied. Different models for multi-level repositories were also analyzed and compared to the main single-level case. Further, the global influence from the excavation of repository tunnels and deposition holes was examined by introducing weaker rock mass material properties in the repository region of one model. The maximum compression stress obtained for the main model is 44 MPa and occurs at the repository level after about 100 years of deposition. Due to thermal expansion, the rock mass displaces upward, and the maximum heave at the ground surface after 1000 years is calculated to be 16 cm. In the area close to the ground surface the horizontal stresses reduce, causing the rock to yield in tension down to a depth of about 80 meters. The fracture zones show opening displacements at shallow depths and closing and shearing at the repository level. The maximum displacements are 0.3-2.5 cm for closing, 0.0-0.8 cm for opening and 0.2-2.2 cm for shearing. The resultant stresses and displacements depend in large part on the assumptions made concerning the heat intensity of the waste. In the main model, an initial heat intensity of 10 W/m 2 is assumed, which gives larger effects than the case with 6 W/m 2 . Another important input parameter for the analysis is the Young's modulus of the rock mass. In the main model, a value of 30 GPa is assumed. Higher values of Young's modulus give larger thermo-mechanical effects. All multi-level repository layouts give rise to higher temperatures than the single-level layout, causing the compressive stresses to increase more at the repository level. The multi

Highly Selective Polypyrrole MIP-Based Gravimetric and Electrochemical Sensors for Picomolar Detection of Glyphosate

Directory of Open Access Journals (Sweden)

Zouhour Mazouz

2017-11-01

Full Text Available There is a global debate and concern about the use of glyphosate (Gly as an herbicide. New toxicological studies will determine its use in the future under new strict conditions or its replacement by alternative synthetic or natural herbicides. In this context, we designed biomimetic polymer sensing layers for the selective molecular recognition of Gly. Towards this end, complementary surface acoustic wave (SAW and electrochemical sensors were functionalized with polypyrrole (PPy-imprinted polymer for the selective detection of Gly. Their corresponding limits of detection were on the order of 1 pM, which are among the lowest values ever reported in literature. The relevant dissociation constants between PPy and Gly were estimated at [Kd1 = (0.7 ± 0.3 pM and Kd2 = (1.6 ± 1.4 µM] and [Kd1 = (2.4 ± 0.9 pM and Kd2 = (0.3 ± 0.1 µM] for electrochemical and gravimetric measurements, respectively. Quantum chemical calculations permitted to estimate the interaction energy between Gly and PPy film: ΔE = −145 kJ/mol. Selectivity and competitivity tests were investigated with the most common pesticides. This work conclusively shows that gravimetric and electrochemical results indicate that both MIP-based sensors are perfectly able to detect and distinguish glyphosate without any ambiguity.

3D analysis of thermo-fluid dynamics of a dry storage fuel container in stationary conditions; Analisis 3D de la termo-fluidodinamica de un contenedor de almacenamiento en seco de combustible en condiciones estacionarias

Energy Technology Data Exchange (ETDEWEB)

Penalva, J.; Feria, F.; Herranz, L. E.

2012-07-01

Dry storage containers must ensure the cooling of the fuel housing. Compliance with this requirement is of huge importance to preserve the integrity of spent fuel. In this sense, the thermo-fluid dynamics of containers is a point to consider in safety studies of this storage system. The aim of this work is to achieve a three-dimensional model of thermo-fluid dynamics of the HI-STORM 100S container using Fluent code. In addition to the fundamental characterization of the device, we have studied the impact of design variations associated with the input and output channels air. In the future, the model presented here will provide a basis for analysis of transient and accidental conditions.

Quantum electron transfer processes induced by thermo-coherent ...

Indian Academy of Sciences (India)

WINTEC

Thermo-coherent state; electron transfer; quantum rate. 1. Introduction. The study ... two surfaces,16 namely, one electron two-centered exchange problem,7–10 many ... temperature classical regime for the single and the two-mode cases have ...

Preparation of thermo-responsive membranes. II.

Science.gov (United States)

Nozawa, I; Suzuki, Y; Sato, S; Sugibayashi, K; Morimoto, Y

1991-05-01

Two types of liquid crystal (LC)-immobilized membranes were prepared by a soaking method and sandwich method to control the permeation of indomethacin, as a model drug, in response to local and systemic fever. Monooxyethylene trimethylolpropane tristearate (MTTS) was used as a model LC because it has a gel-liquid crystal phase transition temperature near the body temperature, 39-40 degrees C in phosphate buffered saline (pH 7.4). Two porous polypropylene (PP) membranes were soaked into 20% MTTS chloroform solution in the soaking method, and two PP membranes were poured with the melted MTTS and pressed in the sandwich method. Thermo-response efficacy of the soaked membrane was dependent upon the content of MTTS in MTTS membrane, and the MTTS content above the void volume of PP membrane (38%) was needed for high efficacy. On the other hand, the sandwich membrane exhibited higher thermo-response efficacy than the soaked membrane, because more LC was embedded in the pores of sandwich membrane than that of the soaked membrane. The sandwich membrane permeation of indomethacin was sharply controlled by temperature changes between 32 and 38 degrees C.

The association of SNPs in Hsp90β gene 5' flanking region with thermo tolerance traits and tissue mRNA expression in two chicken breeds.

Science.gov (United States)

Chen, Zhuo-Yu; Gan, Jian-Kang; Xiao, Xiong; Jiang, Li-Yan; Zhang, Xi-Quan; Luo, Qing-Bin

2013-09-01

Thermo stress induces heat shock proteins (HSPs) expression and HSP90 family is one of them that has been reported to involve in cellular protection against heat stress. But whether there is any association of genetic variation in the Hsp90β gene in chicken with thermo tolerance is still unknown. Direct sequencing was used to detect possible SNPs in Hsp90β gene 5' flanking region in 3 chicken breeds (n = 663). Six mutations, among which 2 SNPs were chosen and genotypes were analyzed with PCR-RFLP method, were found in Hsp90β gene in these 3 chicken breeds. Association analysis indicated that SNP of C.-141G>A in the 5' flanking region of the Hsp90β gene in chicken had some effect on thermo tolerance traits, which may be a potential molecular marker of thermo tolerance, and the genotype GG was the thermo tolerance genotype. Hsp90β gene mRNA expression in different tissues detected by quantitative real-time PCR assay were demonstrated to be tissue dependent, implying that different tissues have distinct sensibilities to thermo stress. Besides, it was shown time specific and varieties differences. The expression of Hsp90β mRNA in Lingshan chickens in some tissues including heart, liver, brain and spleen were significantly higher or lower than that of White Recessive Rock (WRR). In this study, we presume that these mutations could be used in marker assisted selection for anti-heat stress chickens in our breeding program, and WRR were vulnerable to tropical thermo stress whereas Lingshan chickens were well adapted.

A thermo-mechanical benchmark calculation of an hexagonal can in the BTI accident with ABAQUS code

International Nuclear Information System (INIS)

Zucchini, A.

1988-07-01

The thermo-mechanical behaviour of an hexagonal can in a benchmark problem (simulating the conditions of a BTI accident in a fuel assembly) is examined by means of the ABAQUS code: the effects of the geometric nonlinearity are shown and the results are compared with those of a previous analysis performed with the INCA code. (author)

Thermo-cured glass ionomer cements in restorative dentistry.

Science.gov (United States)

Gorseta, Kristina; Glavina, Domagoj

2017-01-01

Numerous positive properties of glass ionomer cements including biocompatibility, bioactivity, releasing of fluoride and good adhesion to hard dental tissue even under wet conditions and easy of handling are reasons for their wide use in paediatric and restorative dentistry. Their biggest drawbacks are the weaker mechanical properties. An important step forward in improving GIC's features is thermo-curing with the dental polymerization unit during setting of the material. Due to their slow setting characteristics the GIC is vulnerable to early exposure to moisture. After thermo curing, cements retain all the benefits of GIC with developed better mechanical properties, improved marginal adaptation, increased microhardness and shear bond strength. Adding external energy through thermocuring or ultrasound during the setting of conventional GIC is crucial to achieve faster and better initial mechanical properties. Further clinical studies are needed to confirm these findings.

Alternatives to the gravimetric method for quantification of diesel particulate matter near the lower level of detection.

Science.gov (United States)

Swanson, Jacob; Kittelson, David; Pui, David; Watts, Winthrop

2010-10-01

This paper is part of the Journal of the Air & Waste Management Association's 2010 special issue on combustion aerosol measurements. The issue is a combination of papers that synthesize and evaluate ideas and perspectives that were presented by experts at a series of workshops sponsored by the Coordinating Research Council that aimed to evaluate the current and future status of diesel particulate matter (DPM) measurement. Measurement of DPM is a complex issue with many stakeholders, including air quality management and enforcement agencies, engine manufacturers, health experts, and climatologists. Adoption of the U.S. Environmental Protection Agency 2007 heavy-duty engine DPM standards posed a unique challenge to engine manufacturers. The new standards reduced DPM emissions to the point that improvements to the gravimetric method were required to increase the accuracy and the sensitivity of the measurement. Despite these improvements, the method still has shortcomings. The objectives of this paper are to review the physical and chemical properties of DPM that make gravimetric measurement difficult at very low concentrations and to review alternative metrics and methods that are potentially more accurate, sensitive, and specific. Particle volatility, size, surface area, and number metrics are considered, as well as methods to quantify them. Although the authors believe that an alternative method is required to meet the needs of engine manufacturers, the methods reviewed in the paper are applicable to other areas where the gravimetric method detection limit is approached and greater accuracy and sensitivity are required. The paper concludes by suggesting a method to measure active surface area, combined with a method to separate semi-volatile and solid fractions to further increase the specificity of the measurement, has potential for reducing the lower detection limit of DPM and enabling engine manufacturers to reduce DPM emissions in the future.

Thermo-optical Properties of Nanofluids

International Nuclear Information System (INIS)

Ortega, Maria Alejandra; Echevarria, Lorenzo; Rodriguez, Luis; Castillo, Jimmy; Fernandez, Alberto

2008-01-01

In this work, we report thermo-optical properties of nanofluids. Spherical gold nanoparticles obtained by laser ablation in condensed media were characterized using thermal lens spectroscopy in SDS-water solution pumping at 532 nm with a 10 ns pulsed laser-Nd-YAG system. Nanoparticles obtained by laser ablation were stabilized in the time by surfactants (Sodium Dodecyl-Sulfate or SDS) in different molar concentrations. The morphology and size of the gold nanoparticles were determined by transmission electron microscopy (TEM). The plasmonic resonance bands in gold nanoparticles are responsible of the light optical absorption of this wavelength. The position of the absorption maximum and width band in the UV-Visible spectra is given by the morphological characteristics of these systems. The thermo-optical constant such as thermal diffusion, thermal conductivity and dn/dT are functions of nanoparticles sizes and dielectric constant of the media. The theoretical model existents do not describe completely this relations because is not possible separate the contributions due to nanoparticles size, factor form and dielectric constant. The thermal lens signal obtained is also dependent of nanoparticles sizes. This methodology can be used in order to evaluate nanofluids and characterizing nanoparticles in different media. These results are expected to have an impact in bioimaging, biosensors and other technological applications such as cooler system

Gravimetric determination of carbon in uranium-plutonium carbide materials

International Nuclear Information System (INIS)

Kavanaugh, H.J.; Dahlby, J.W.; Lovell, A.P.

1979-12-01

A gravimetric method for determining carbon in uranium-plutonium carbide materials was developed to analyze six samples simultaneously. The samples are burned slowly in an oxygen atmosphere at approximately 900 0 C, and the gases generated are passed through Schuetze's oxidizing reagent (iodine pentoxide on silica gel) to assure quantitative oxidation of the CO to CO 2 . The CO 2 is collected on Ascarite and weighed. This method was tested using a tungsten carbide reference material (NBS-SRM-276) and a (U,Pu)C sample. For 42 analyses of the tungsten carbide, which has a certified carbon content of 6.09%, an average value of 6.09% was obtained with a standard deviation of 0.01 7 % or a relative standard deviation of 0.28%. For 17 analyses of the (U,Pu)C sample, an average carbon content of 4.97% was found with a standard deviation of 0.01 2 % or a relative standard deviation of 0.24%

Enhancement of the thermo-optical response of silver nanoparticles due to surface plasmon resonance

Science.gov (United States)

Hashemi Zadeh, Sakineh; Rashidi-Huyeh, Majid; Palpant, Bruno

2017-10-01

Owing to their remarkable optical properties, noble metals' nanoparticles are proposed for many applications. Controlling the temperature dependence of these properties may then appear to be of great relevance. In this paper, we investigate the thermo-optical properties of silver nanoparticles. Different silver nanocolloids were prepared with different surface plasmon resonance modes. The thermo-extinction spectra of the colloidal solutions were then evaluated by measuring the extinction spectra at different temperatures. This reveals a typical peak-valley profile around each surface plasmon resonance mode. Mie theory was used to study theoretically the impact of nanoparticle size on the thermo-optical properties. The results allow us to interpret properly the experimental findings.

Generation of thermo-acoustic waves from pulsed solar/IR radiation

Science.gov (United States)

Rahman, Aowabin

Acoustic waves could potentially be used in a wide range of engineering applications; however, the high energy consumption in generating acoustic waves from electrical energy and the cost associated with the process limit the use of acoustic waves in industrial processes. Acoustic waves converted from solar radiation provide a feasible way of obtaining acoustic energy, without relying on conventional nonrenewable energy sources. One of the goals of this thesis project was to experimentally study the conversion of thermal to acoustic energy using pulsed radiation. The experiments were categorized into "indoor" and "outdoor" experiments, each with a separate experimental setup. The indoor experiments used an IR heater to power the thermo-acoustic lasers and were primarily aimed at studying the effect of various experimental parameters on the amplitude of sound waves in the low frequency range (below 130 Hz). The IR radiation was modulated externally using a chopper wheel and then impinged on a porous solid, which was housed inside a thermo-acoustic (TA) converter. A microphone located at a certain distance from the porous solid inside the TA converter detected the acoustic signals. The "outdoor" experiments, which were targeted at TA conversion at comparatively higher frequencies (in 200 Hz-3 kHz range) used solar energy to power the thermo-acoustic laser. The amplitudes (in RMS) of thermo-acoustic signals obtained in experiments using IR heater as radiation source were in the 80-100 dB range. The frequency of acoustic waves corresponded to the frequency of interceptions of the radiation beam by the chopper. The amplitudes of acoustic waves were influenced by several factors, including the chopping frequency, magnitude of radiation flux, type of porous material, length of porous material, external heating of the TA converter housing, location of microphone within the air column, and design of the TA converter. The time-dependent profile of the thermo-acoustic signals

Geothermal-Related Thermo-Elastic Fracture Analysis by Numerical Manifold Method

Directory of Open Access Journals (Sweden)

Jun He

2018-05-01

Full Text Available One significant factor influencing geothermal energy exploitation is the variation of the mechanical properties of rock in high temperature environments. Since rock is typically a heterogeneous granular material, thermal fracturing frequently occurs in the rock when the ambient temperature changes, which can greatly influence the geothermal energy exploitation. A numerical method based on the numerical manifold method (NMM is developed in this study to simulate the thermo-elastic fracturing of rocklike granular materials. The Voronoi tessellation is incorporated into the pre-processor of NMM to represent the grain structure. A contact-based heat transfer model is developed to reflect heat interaction among grains. Based on the model, the transient thermal conduction algorithm for granular materials is established. To simulate the cohesion effects among grains and the fracturing process between grains, a damage-based contact fracture model is developed to improve the contact algorithm of NMM. In the developed numerical method, the heat interaction among grains as well as the heat transfer inside each solid grain are both simulated. Additionally, as damage evolution and fracturing at grain interfaces are also considered, the developed numerical method is applicable to simulate the geothermal-related thermal fracturing process.

Growth, structural, optical, thermal and laser damage threshold studies of an organic single crystal: 1,3,5 – triphenylbenzene (TPB)

International Nuclear Information System (INIS)

Raja, R. Subramaniyan; Babu, G. Anandha; Ramasamy, P.

2016-01-01

Good quality single crystals of pure hydrocarbon 1,3,5-Triphenylbenzene (TPB) have been successfully grown using toluene as a solvent using controlled slow cooling solution growth technique. TPB crystallizes in orthorhombic structure with the space group Pna2 1 . The structural perfection of the grown crystal has been analysed by high resolution X-ray diffraction measurements. The range and percentage of the optical transmission are ascertained by recording the UV-vis spectrum. Thermo gravimetric analysis (TGA) and differential thermal analysis (DTA) were used to study its thermal properties. Powder second harmonic generation studies were carried out to explore its NLO properties. Laser damage threshold value has been determined using Nd:YAG laser operating at 1064 nm.

Preparation of novel magnetic polyurethane foam nanocomposites by using core-shell nanoparticles

Directory of Open Access Journals (Sweden)

Mir Mohammad Alavi Nikje

Full Text Available Abstract Iron oxide magnetic nanoparticles (NP's converted to the core- shell structres by reacting with by n-(2-aminoethyl-3-aminopropyl trimethoxysilane (AEAP incorporated in polyurethane flexible (PUF foam formulations. Fourier transform spectra, thermal gravimetric analysis, scanning electron images, thermo-mechanical analysis and magnetic properties of the prepared nanocomposites were studied. Obtained data shown that by the increasing of the amine modified magnetic iron oxide NP's up to 3% in the polymer matrix, thermal and magnetic properties improved in comparison with pristine foams. In addition, due to the presence of functional groups on the magnetic NP's surface, hard phases formation decrease in the bulk polymer and cause decreasing of glass transition temperature.

Preparation and Characterization of Silica/Polyamide-imide Nanocomposite Thin Films

Directory of Open Access Journals (Sweden)

Hwang Jong-Sun

2010-01-01

Full Text Available Abstract The functional silica/polyamide-imide composite films were prepared via simple ultrasonic blending, after the silica nanoparticles were modified by cationic surfactant—cetyltrimethyl ammonium bromide (CTAB. The composite films were characterized by scanning electron microscope (SEM, thermo gravimetric analysis (TGA and thermomechanical analysis (TMA. CTAB-modified silica nanoparticles were well dispersed in the polyamide-imide matrix, and the amount of silica nanoparticles to PAI was investigated to be from 2 to 10 wt%. Especially, the coefficients of thermal expansion (CET continuously decreased with the amount of silica particles increasing. The high thermal stability and low coefficient of thermal expansion showed that the nanocomposite films can be widely used in the enamel wire industry.

Fruits and vegetables dehydration

International Nuclear Information System (INIS)

De Ita, A; Flores, G; Franco, F

2015-01-01

Dehydration diagrams were determined by means of Differential Thermal Analysis, DTA, and Thermo Gravimetric Analysis, TGA, curves of several simultaneous fruits and vegetables, all under the same conditions. The greater mass loss is associated with water containing in the structure of the investigated materials at low temperature. In poblano chile water is lost in a single step. The banana shows a very sharply two stages, while jicama can be observed although with a little difficulty three stages. The major mass loss occurs in the poblano chile and the lower in banana. The velocity and temperature of dehydration vary within a small range for most materials investigated, except for banana and cactus how are very different

Fruits and vegetables dehydration

Science.gov (United States)

de Ita, A.; Flores, G.; Franco, F.

2015-01-01

Dehydration diagrams were determined by means of Differential Thermal Analysis, DTA, and Thermo Gravimetric Analysis, TGA, curves of several simultaneous fruits and vegetables, all under the same conditions. The greater mass loss is associated with water containing in the structure of the investigated materials at low temperature. In poblano chile water is lost in a single step. The banana shows a very sharply two stages, while jicama can be observed although with a little difficulty three stages. The major mass loss occurs in the poblano chile and the lower in banana. The velocity and temperature of dehydration vary within a small range for most materials investigated, except for banana and cactus how are very different.

Static thermo-optic instability in double-pass fiber amplifiers

DEFF Research Database (Denmark)

Lægsgaard, Jesper

2016-01-01

A coupled-mode formalism, earlier used to describe transverse mode instabilities in single-pass optical fiber amplifiers, is extended to the case of double-pass amplifiers. Contrary to the single-pass case, it is shown that the thermo-optic nonlinearity can couple light at the same frequency...... between the LP01 and LP11 modes, leading to a static deformation of the output beam profile. This novel phenomenon is caused by the interaction of light propagating in either direction with thermo-optic index perturbations caused by light propagating in the opposite direction. The threshold power...... for the static deformation is found to be several times lower than what is typically found for the dynamic modal instabilities observed in single-pass amplifiers. (C) 2016 Optical Society of America...

Fluka and thermo-mechanical studies for the CLIC main dump

CERN Document Server

Mereghetti, Alessio; Vlachoudis, Vasilis

2011-01-01

In order to best cope with the challenge of absorbing the multi-MW beam, a water beam dump at the end of the CLIC post-collision line has been proposed. The design of the dump for the Conceptual Design Report (CDR) was checked against with a set of FLUKA Monte Carlo simulations, for the estimation of the peak and total power absorbed by the water and the vessel. Fluence spectra of escaping particles and activation rates of radio-nuclides were computed as well. Finally, the thermal transient behavior of the water bath and a thermo-mechanical analysis of the preliminary design of the window were done.

Fundamental study on thermo-hydraulic behaviors during power transient, 2

International Nuclear Information System (INIS)

Shinano, M.; Inoue, A.

1988-01-01

Thermo-hydraulic behaviors during power transient of nuclear reactors are studied. Boiling around test rod heated transiently forces to flow out liquid in the test section and generates high pressure pulse. In this study, it is investigated experimentally and analytically that magnitude of pressure pulse and energy conversion efficiency to the mechanical works in cases of fragmentation and non-fragmentation. In analysis, effects of increasing of heat transfer and of interaction area due to fragmentation is considered. Consequently, 1) magnitude of pressure pulse on fragmentation is about 10 times greater than that on non-fragmentation. 2) analytical model can show characteristics of fragmentation processes qualitatively. (author)

[Evaluation of the AOAC 985.29 enzimic gravimetric method for determination of dietary fiber in oat and corn grains].

Science.gov (United States)

da Silva, Leila Picolli; Ciocca, Maria de Lourdes Santorio; Furlong, Eliana Badiale

2003-12-01

The precision attributes and use of the enzymatic-gravimetric method of Prosky et al. (1992) (AOAC 985.29) were evaluated using corn (BR 5202 Pampa) and oat (UFRGS 15) samples. The effect of laboratory batches carried out in different days were evaluated in six laboratory batches, using for each material one duplicate for total fiber (FT) determination, one duplicate for insoluble fiber (FI) determination and blank ones for FT and for FI (both in duplicate). In order to characterize repetitive aspects, five other FT and FI determinations added to each sample were evaluated, summing up 11 data. The low coefficients of variation in the first six batches were considered acceptable as an expression of expected total intralaboratory variation. The repetitive of the method was considered good for FT determinations (CVs gravimetric corrections varies with the kind of the sample and is especially influenced by the protein content.

Thermo-sensitive polymer nanospheres as a smart plugging agent for shale gas drilling operations.

Science.gov (United States)

Wang, Wei-Ji; Qiu, Zheng-Song; Zhong, Han-Yi; Huang, Wei-An; Dai, Wen-Hao

2017-01-01

Emulsifier-free poly(methyl methacrylate-styrene) [P(MMA-St)] nanospheres with an average particle size of 100 nm were synthesized in an isopropyl alcohol-water medium by a solvothermal method. Then, through radical graft copolymerization of thermo-sensitive monomer N -isopropylacrylamide (NIPAm) and hydrophilic monomer acrylic acid (AA) onto the surface of P(MMA-St) nanospheres at 80 °C, a series of thermo-sensitive polymer nanospheres, named SD-SEAL with different lower critical solution temperatures (LCST), were prepared by adjusting the mole ratio of NIPAm to AA. The products were characterized by Fourier transform infrared spectroscopy, transmission electron microscopy, thermogravimetric analysis, particle size distribution, and specific surface area analysis. The temperature-sensitive behavior was studied by light transmittance tests, while the sealing performance was investigated by pressure transmission tests with Lungmachi Formation shales. The experimental results showed that the synthesized nanoparticles are sensitive to temperature and had apparent LCST values which increased with an increase in hydrophilic monomer AA. When the temperature was higher than its LCST value, SD-SEAL played a dual role of physical plugging and chemical inhibition, slowed down pressure transmission, and reduced shale permeability remarkably. The plugged layer of shale was changed to being hydrophobic, which greatly improved the shale stability.

First Release of Gravimetric Geoid Model over Saudi Arabia Based on Terrestrial Gravity and GOCE Satellite Data: KSAG01

Science.gov (United States)

Alothman, Abdulaziz; Elsaka, Basem

2016-04-01

A new gravimetric quasi-geoid, known as KSAG0, has been developed recently by Remove-Compute-Restore techniques (RCR), provided by the GRAVSOFT software, using gravimetric free air anomalies. The terrestrial gravity data used in this computations are: 1145 gravity field anomalies observed by ARAMCO (Saudi Arabian Oil Company) and 2470 Gravity measurements from BGI (Bureau Gravimétrique International). The computations were carried out implementing the least squares collocation method through the RCR techniques. The KSAG01 is based on merging in addition to the terrestrial gravity observations, GOCE satellite model (Eigen-6C4) and global gravity model (EGM2008) have been utilized in the computations. The long, medium and short wavelength spectrum of the height anomalies were compensated from Eigen-6C4 and EGM2008 geoid models truncated up to Degree and order (d/o) up to 2190. KSAG01 geoid covers 100 per cent of the kingdom, with geoid heights range from - 37.513 m in the southeast to 23.183 m in the northwest of the country. The accuracy of the geoid is governed by the accuracy, distribution, and spacing of the observations. The standard deviation of the predicted geoid heights is 0.115 m, with maximum errors of about 0.612 m. The RMS of geoid noise ranges from 0.019 m to 0.04 m. Comparison of the predicted gravimetric geoid with EGM, GOCE, and GPS/Levelling geoids, reveals a considerable improvements of the quasi-geoid heights over Saudi Arabia.

Magnetic resonance guided focalized ultrasound thermo-ablation: A promising oncologic local therapy

International Nuclear Information System (INIS)

Iannessi, A.; Doyen, J.; Leysalle, A.; Thyss, A.

2014-01-01

Pain management of bone metastases is usually made using systemic and local therapy. Even though radiations are nowadays the gold standard for painful metastases, innovations regarding minimally invasive treatment approaches have been developed because of the existing non-responder patients [1]. Indeed, cementoplasty and thermo-ablations like radiofrequency or cryotherapy have shown to be efficient on pain [2-4]. Among thermo-therapy, magnetic resonance guided focalized ultrasound is now a new non-invasive weapon for bone pain palliation. (authors)

A semi-analytical analysis of electro-thermo-hydrodynamic stability in dielectric nanofluids using Buongiorno's mathematical model together with more realistic boundary conditions

Science.gov (United States)

Wakif, Abderrahim; Boulahia, Zoubair; Sehaqui, Rachid

2018-06-01

The main aim of the present analysis is to examine the electroconvection phenomenon that takes place in a dielectric nanofluid under the influence of a perpendicularly applied alternating electric field. In this investigation, we assume that the nanofluid has a Newtonian rheological behavior and verifies the Buongiorno's mathematical model, in which the effects of thermophoretic and Brownian diffusions are incorporated explicitly in the governing equations. Moreover, the nanofluid layer is taken to be confined horizontally between two parallel plate electrodes, heated from below and cooled from above. In a fast pulse electric field, the onset of electroconvection is due principally to the buoyancy forces and the dielectrophoretic forces. Within the framework of the Oberbeck-Boussinesq approximation and the linear stability theory, the governing stability equations are solved semi-analytically by means of the power series method for isothermal, no-slip and non-penetrability conditions. In addition, the computational implementation with the impermeability condition implies that there exists no nanoparticles mass flux on the electrodes. On the other hand, the obtained analytical solutions are validated by comparing them to those available in the literature for the limiting case of dielectric fluids. In order to check the accuracy of our semi-analytical results obtained for the case of dielectric nanofluids, we perform further numerical and semi-analytical computations by means of the Runge-Kutta-Fehlberg method, the Chebyshev-Gauss-Lobatto spectral method, the Galerkin weighted residuals technique, the polynomial collocation method and the Wakif-Galerkin weighted residuals technique. In this analysis, the electro-thermo-hydrodynamic stability of the studied nanofluid is controlled through the critical AC electric Rayleigh number Rec , whose value depends on several physical parameters. Furthermore, the effects of various pertinent parameters on the electro-thermo

Analysis of the thermo-mechanical behaviour of the DEMO Water-Cooled Lithium Lead breeding blanket module under normal operation steady state conditions

Energy Technology Data Exchange (ETDEWEB)

Di Maio, P.A.; Arena, P. [Dipartimento di Energia, Ingegneria dell’Informazione e Modelli Matematici, Università di Palermo, Viale delle Scienze, 90128 Palermo (Italy); Aubert, J. [CEA Saclay, DEN/DANS/DM2S/SEMT, 91191 Gif sur Yvette Cedex (France); Bongiovì, G. [Dipartimento di Energia, Ingegneria dell’Informazione e Modelli Matematici, Università di Palermo, Viale delle Scienze, 90128 Palermo (Italy); Chiovaro, P., E-mail: pierluigi.chiovaro@unipa.it [Dipartimento di Energia, Ingegneria dell’Informazione e Modelli Matematici, Università di Palermo, Viale delle Scienze, 90128 Palermo (Italy); Giammusso, R. [ENEA – C.R. Brasimone, 40032 Camugnano (Italy); Li Puma, A. [CEA Saclay, DEN/DANS/DM2S/SEMT, 91191 Gif sur Yvette Cedex (France); Tincani, A. [ENEA – C.R. Brasimone, 40032 Camugnano (Italy)

2015-10-15

Highlights: • A DEMO WCLL blanket module thermo-mechanical behaviour has been investigated. • Two models of the WCLL blanket module have been set-up adopting a code based on FEM. • The water flow domain in the module has been considered. • A set of uncoupled steady state thermo-mechanical analyses has been carried out. • Critical temperature is not overcome. Safety verifications are generally satisfied. - Abstract: Within the framework of DEMO R&D activities, a research cooperation has been launched between ENEA, the University of Palermo and CEA to investigate the thermo-mechanical behaviour of the outboard equatorial module of the DEMO1 Water-Cooled Lithium Lead (WCLL) blanket under normal operation steady state scenario. The research campaign has been carried out following a theoretical–computational approach based on the Finite Element Method (FEM) and adopting a qualified commercial FEM code. In particular, two different 3D FEM models (Model 1 and Model 2), reproducing respectively the central and the lateral poloidal–radial slices of the WCLL blanket module, have been set up. A particular attention has been paid to the modelling of water flow domain, within both the segment box channels and the breeder zone tubes, to simulate realistically the coolant-box thermal coupling. Results obtained are herewith reported and critically discussed.

A geometrical multi-scale numerical method for coupled hygro-thermo-mechanical problems in photovoltaic laminates.

Science.gov (United States)

Lenarda, P; Paggi, M

A comprehensive computational framework based on the finite element method for the simulation of coupled hygro-thermo-mechanical problems in photovoltaic laminates is herein proposed. While the thermo-mechanical problem takes place in the three-dimensional space of the laminate, moisture diffusion occurs in a two-dimensional domain represented by the polymeric layers and by the vertical channel cracks in the solar cells. Therefore, a geometrical multi-scale solution strategy is pursued by solving the partial differential equations governing heat transfer and thermo-elasticity in the three-dimensional space, and the partial differential equation for moisture diffusion in the two dimensional domains. By exploiting a staggered scheme, the thermo-mechanical problem is solved first via a fully implicit solution scheme in space and time, with a specific treatment of the polymeric layers as zero-thickness interfaces whose constitutive response is governed by a novel thermo-visco-elastic cohesive zone model based on fractional calculus. Temperature and relative displacements along the domains where moisture diffusion takes place are then projected to the finite element model of diffusion, coupled with the thermo-mechanical problem by the temperature and crack opening dependent diffusion coefficient. The application of the proposed method to photovoltaic modules pinpoints two important physical aspects: (i) moisture diffusion in humidity freeze tests with a temperature dependent diffusivity is a much slower process than in the case of a constant diffusion coefficient; (ii) channel cracks through Silicon solar cells significantly enhance moisture diffusion and electric degradation, as confirmed by experimental tests.

Analysis of the hologram recording on the novel chloride photo-thermo-refractive glass

Science.gov (United States)

Ivanov, S. A.; Nikonorov, N. V.; Dubrovin, V. D.; Krykova, V. A.

2017-05-01

In this research, we present new holographic material based on fluoride photo-thermo-refractive glass(PTR) - chloride PTR glass. One of the benefit of this type of PTR glass is positive refractive index change. During this work, for the first-time volume Bragg gratings were recorded in this kind of material. The first experiments revealed that such gratings are mixed i.e. possess both absorption and phase components. Complex analysis shows that both refractive index and absorption coefficient are modulated inside the grating structure. We found out that at first there is no strict dependence of the refractive index change from dosage, but as we continue the process of thermal treatment - dependence is appear. Exposure influence on the refractive index change for this glass differs from fluoride one and shows some sort of saturation after the exposure of 4-6 J/cm2 . We distinguished refractive index change and absorption coefficient change and observed both behavior with increasing thermal treatment time. We found out that the increase of thermal treatment time results in the significant refractive index change. At the same time the absorption does `not practically change. It was found that maximum modulation of refractive index is comparable with fluoride PTR glass and achieves value of 1600 ppm. The modulation of absorption is equal to induced absorption caused by silver nanoparticles and depends from reading wavelength. Our study shows that almost all absorption is modulated inside the grating.

Lamb's plane problem in a thermo-elastic micropolar medium with stretch

Directory of Open Access Journals (Sweden)

T. K. Chadha

1987-01-01

Full Text Available A study is made of the Lamb plane problem in a thermo-elastic micropolar medium with the effect of stretch. The problem is solved for an arbitrary, normal load distribution by using the double Fourier transform. The displacement components, force stress, couple stress, vector first moment and the temperature field are determined for a half space subjected to an arbitrary normal load. Two special cases of a horizontal force and a torque which are oscillating with a frequency ω have been investigated. It is shown that results of this analysis reduce to those without stretch.

The Numerical Nuclear Reactor for High-Fidelity Integrated Simulation of Neutronic, Thermal-Hydraulic, and Thermo-Mechanical Phenomena

Energy Technology Data Exchange (ETDEWEB)

Kim, K. S.; Ju, H. G.; Jeon, T. H. and others

2005-03-15

A comprehensive high fidelity reactor core modeling capability has been developed for detailed analysis of current and advanced reactor designs as part of a US-ROK collaborative I-NERI project. High fidelity was accomplished by integrating highly refined solution modules for the coupled neutronic, thermal-hydraulic, and thermo-mechanical phenomena. Each solution module employs methods and models that are formulated faithfully to the first-principles governing the physics, real geometry, and constituents. Specifically, the critical analysis elements that are incorporated in the coupled code capability are whole-core neutron transport solution, ultra-fine-mesh computational fluid dynamics/heat transfer solution, and finite-element-based thermo-mechanics solution, all obtained with explicit (fuel pin cell level) heterogeneous representations of the components of the core. The vast computational problem resulting from such highly refined modeling is solved on massively parallel computers, and serves as the 'numerical nuclear reactor'. Relaxation of modeling parameters were also pursued to make problems run on clusters of workstations and PCs for smaller scale applications as well.

The Numerical Nuclear Reactor for High-Fidelity Integrated Simulation of Neutronic, Thermal-Hydraulic, and Thermo-Mechanical Phenomena

International Nuclear Information System (INIS)

Kim, K. S.; Ju, H. G.; Jeon, T. H. and others

2005-03-01

A comprehensive high fidelity reactor core modeling capability has been developed for detailed analysis of current and advanced reactor designs as part of a US-ROK collaborative I-NERI project. High fidelity was accomplished by integrating highly refined solution modules for the coupled neutronic, thermal-hydraulic, and thermo-mechanical phenomena. Each solution module employs methods and models that are formulated faithfully to the first-principles governing the physics, real geometry, and constituents. Specifically, the critical analysis elements that are incorporated in the coupled code capability are whole-core neutron transport solution, ultra-fine-mesh computational fluid dynamics/heat transfer solution, and finite-element-based thermo-mechanics solution, all obtained with explicit (fuel pin cell level) heterogeneous representations of the components of the core. The vast computational problem resulting from such highly refined modeling is solved on massively parallel computers, and serves as the 'numerical nuclear reactor'. Relaxation of modeling parameters were also pursued to make problems run on clusters of workstations and PCs for smaller scale applications as well

A thermo economic analysis of a PV-hydrogen system feeding the energy requests of a residential building in an isolated valley of the Alps

International Nuclear Information System (INIS)

Santarelli, M.; Macagno, S.

2004-01-01

The subject of this paper is an economic analysis of a model of a stand alone energy system based only on a renewable source (solar irradiance) integrated with a system for the production of hydrogen. The purpose of this system is to supply the complete electric and part of the heat requests of a small residential user in a remote area (an isolated building in a valley of the Alps in Italy) during a complete year of operation without integration of a traditional energy system based on fossil fuels. The system analysed is composed of a PV array integrated with an electrolyser, with a tank where the hydrogen is stored as compressed gas and with a proton exchange membrane fuel cell. Such a system has no pollutant emissions and is environmentally friendly. A simulation program has been developed to design the system and to analyse the technical and economic performance during a complete year of operation. The economic analysis is developed using thermo economic analysis. This procedure joins some aspects of exergy analysis with some economic information, such as the fuel market costs and the investment and maintenance costs of the components of the energy plant. Using this methodology, it is possible to obtain some information on the economic behaviour of the plant and to analyse in depth the process of cost formation of all system flows, in particular those of the final products. The thermo economic analysis can be performed to evaluate the different economic behaviour of the system in different operating conditions (e.g. during daylight hours or in evening hours). In this paper, the analysis has been effected considering a representative day for each month of operation and two significant hours (1:00 p.m. and 8:00 p.m.) in order to consider two opposite situations (with and without solar irradiance) with high energy demands by the user. Moreover, a sensitivity analysis has been developed to calculate the variation of the cost of the final energy products (and of the

Influence of the Lubricant Thermo-Piezo-Viscous Property on Hydrostatic Bearings in Oil Hydraulics

DEFF Research Database (Denmark)

Johansen, Per; Roemer, Daniel Beck; Andersen, Torben O.

2016-01-01

adds to the discrepancy of such simple design approach. In this paper the hydrostatic pressure force calculation is reviewed in terms of thermohydrodynamic (THD) lubrication theory, and simple analytical approximations of the hydrostatic pressure force, incorporating the piezo-viscous and thermo...... of these analytical approximations are explored in order to clarify the limits of application. In conclusion, it is found that the spatial gradient of the thermal field on the bearing surface is the significant factor in the thermo-viscous effect on the hydrostatic pressure profile, which leads to the conclusion...... that design engineers need to understand the thermodynamics of hydrostatic bearings, when using the conventional simple analytical approach, neglecting thermo-piezo-viscosity, in hydrostatic pressure force calculations....

Laser metrology for a next generation gravimetric mission

Science.gov (United States)

Mottini, Sergio; Biondetti, Giorgio; Cesare, Stefano; Castorina, Giuseppe; Musso, Fabio; Pisani, Marco; Leone, Bruno

2017-11-01

Within the ESA technology research project "Laser Interferometer High Precision tracking for LEO", Thales Alenia Space Italia is developing a laser metrology system for a Next Generation Gravimetric Mission (NGGM) based on satellite-to-satellite tracking. This technique is based on the precise measurement of the displacement between two satellites flying in formation at low altitude for monitoring the variations of Earth's gravity field at high resolution over a long time period. The laser metrology system that has been defined for this mission consists of the following elements: • an heterodyne Michelson interferometer for measuring the distance variation between retroreflectors positioned on the two satellites; • an angle metrology for measuring the orientation of the laser beam in the reference frames of the two satellites; • a lateral displacement metrology for measuring the deviations of the laser beam axis from the target retro-reflector. The laser interferometer makes use of a chopped measurement beam to avoid spurious signals and nonlinearity caused by the unbalance between the strong local beam and the weak return beam. The main results of the design, development and test activities performed on the breadboard of the metrology system are summarized in this paper.

MCTP, a code for the thermo-mechanical analysis of a fuel rod of BWR type reactors (Neutron part)

International Nuclear Information System (INIS)

Hernandez L, H.; Ortiz V, J.

2003-01-01

In the National Institute of Nuclear Research of Mexico a code for the thermo-mechanical analysis of the fuel rods of the BWR type reactors of the Nucleo electric Central of Laguna Verde is developed. The code solves the diffusion equation in cylindrical coordinates with several energy groups. The code, likewise, calculates the temperature distribution and power distribution in those fuel rods. The code is denominated Multi groups With Temperatures and Power (MCTP). In the code, the energy with which the fission neutrons are emitted it is divided in six groups. They are also considered the produced perturbations by the changes in the temperatures of the materials that constitute the fuel rods, the content of fission products, the uranium consumption and in its case the gadolinium, as well as the plutonium production. In this work there are present preliminary results obtained with the code, using data of operation of the Nucleo electric Central of Laguna Verde. (Author)

Thermo-physical properties of epoxy nanocomposites reinforced by carbon nanotubes and vapor grown carbon fibers

International Nuclear Information System (INIS)

Miyagawa, Hiroaki; Rich, Michael J.; Drzal, Lawrence T.

2006-01-01

In this study, the thermo-physical properties of epoxy nanocomposites reinforced by fluorinated single wall carbon nanotubes (FSWCNT) and vapor grown carbon fibers (VGCF) were investigated. A sonication technique using a suspension of FSWCNT and VGCF in acetone was utilized to process nanocomposites in anhydride-cured epoxy. The viscoelastic properties of the nanocomposites were measured with dynamic mechanical analysis. The glass transition temperature decreased approximately 30 deg. C with an addition of 0.14 vol.% (0.2 wt.%) FSWCNT. The depression in T g is attributed to non-stoichiometric balance of the epoxy matrix caused by the fluorine on single wall carbon nanotubes. The correct amount of the anhydride curing agent needed to achieve stoichiometry was experimentally determined by DMA measurements. After adjusting the amount of the anhydride curing agent for stoichiometry, the storage modulus of the epoxy at room temperature increased 0.63 GPa with the addition of only 0.21 vol.% (0.30 wt.%) of FSWCNT, a 20% improvement compared with the anhydride-cured neat epoxy. For VGCF, the storage modulus at room temperature increased 0.48 GPa with the addition of only 0.94 vol.% (1.5 wt.%) and then reached a plateau for larger amounts of VGCF. To understand the influence of VGCF on thermo-physical properties, the microstructure of the nanocomposites was interrogated using transmission electron microscopy (TEM). This study discusses the chemical effects of fluorine on matrix properties and the effect of stoichiometric balance on the thermo-physical properties of nanocomposites

Metal-Organic Frameworks for Resonant-Gravimetric Detection of Trace-Level Xylene Molecules.

Science.gov (United States)

Xu, Tao; Xu, Pengcheng; Zheng, Dan; Yu, Haitao; Li, Xinxin

2016-12-20

As one of typical VOCs, xylene is seriously harmful to human health. Nowadays, however, there is really lack of portable sensing method to directly detect environmental xylene that has chemical inertness. Especially when the concentration of xylene is lower than the human olfactory threshold of 470 ppb, people are indeed hard to be aware of and avoid this harmful vapor. Herein the metal-organic framework (MOF) of HKUST-1 is first explored for sensing to the nonpolar molecule of p-xylene. And the sensing mechanism is identified that is via host-guest interaction of MOF with xylene molecule. By loading MOFs on mass-gravimetric resonant-cantilevers, sensing experiments for four MOFs of MOF-5, HKUST-1, ZIF-8, and MOF-177 approve that HKUST-1 has the highest sensitivity to p-xylene. The resonant-gravimetric sensing experiments with our HKUST-1 based sensors have demonstrated that trace-level p-xylene of 400 ppb can be detected that is lower than the human olfactory threshold of 470 ppb. We analyze that the specificity of HKUST-1 to xylene comes from Cu 2+ -induced moderate Lewis acidity and the "like dissolves like" interaction of the benzene ring. In situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) is used to elucidate the adsorbing/sensing mechanism of HKUST-1 to p-xylene, where p-xylene adsorbing induced blue-shift phenomenon is observed that confirms the sensing mechanism. Our study also indicates that the sensor shows good selectivity to various kinds of common interfering gases. And the long-term repeatability and stability of the sensing material are also approved for the usage/storage period of two months. This research approves that the MOF materials exhibit potential usages for high performance chemical sensors applications.

Thermo-kinetic prediction of metastable and stable phase precipitation in Al–Zn–Mg series aluminium alloys during non-isothermal DSC analysis

International Nuclear Information System (INIS)

Lang, Peter; Wojcik, Tomasz; Povoden-Karadeniz, Erwin; Falahati, Ahmad; Kozeschnik, Ernst

2014-01-01

Highlights: • Comparison of laboratory Al–Zn–Mg alloy to industrial Al 7xxx series. • Heat flow evolution during non-isothermal DSC analysis is calculated. • TEM investigations of laboratory Al–Zn–Mg alloy at three pronounced temperatures. • Simulation and modelling of precipitation sequence. • Calculation and prediction of heat flow curves of Al 7xxx series. - Abstract: The technological properties of heat treatable Al–Zn–Mg alloys originate in the morphology and distribution of metastable particles. Starting from the solution-annealed condition, this paper describes the precipitate evolution during non-isothermal temperature changes, namely continuous heating differential scanning calorimetry (DSC) analysis. The distribution and the morphology of the metastable and stable precipitates and the heat flow accompanying the precipitation process is investigated experimentally and calculated by numerical thermo-kinetic simulations. The computer simulation results of the sizes and distributions are confirmed by transmission electron microscopy (TEM). The theoretical background and the results of the investigations are discussed

Thermo-kinetic prediction of metastable and stable phase precipitation in Al–Zn–Mg series aluminium alloys during non-isothermal DSC analysis

Energy Technology Data Exchange (ETDEWEB)

Lang, Peter, E-mail: pl404@cam.ac.uk [Department of Materials Science and Metallurgy, University of Cambridge, Charles Babbage Road 27, Cambridge CB3 0FS (United Kingdom); Wojcik, Tomasz [Institute of Materials Science and Technology, Vienna University of Technology, Favoritenstraße 9-11, Vienna 1040 (Austria); Povoden-Karadeniz, Erwin [Institute of Materials Science and Technology, Vienna University of Technology, Favoritenstraße 9-11, Vienna 1040 (Austria); Christian Doppler Laboratory “Early Stages of Precipitation”, Institute of Materials Science and Technology, Vienna University of Technology, Favoritenstraße 9-11, Vienna 1040 (Austria); Falahati, Ahmad [Institute of Materials Science and Technology, Vienna University of Technology, Favoritenstraße 9-11, Vienna 1040 (Austria); Kozeschnik, Ernst [Institute of Materials Science and Technology, Vienna University of Technology, Favoritenstraße 9-11, Vienna 1040 (Austria); Christian Doppler Laboratory “Early Stages of Precipitation”, Institute of Materials Science and Technology, Vienna University of Technology, Favoritenstraße 9-11, Vienna 1040 (Austria)

2014-10-01

Highlights: • Comparison of laboratory Al–Zn–Mg alloy to industrial Al 7xxx series. • Heat flow evolution during non-isothermal DSC analysis is calculated. • TEM investigations of laboratory Al–Zn–Mg alloy at three pronounced temperatures. • Simulation and modelling of precipitation sequence. • Calculation and prediction of heat flow curves of Al 7xxx series. - Abstract: The technological properties of heat treatable Al–Zn–Mg alloys originate in the morphology and distribution of metastable particles. Starting from the solution-annealed condition, this paper describes the precipitate evolution during non-isothermal temperature changes, namely continuous heating differential scanning calorimetry (DSC) analysis. The distribution and the morphology of the metastable and stable precipitates and the heat flow accompanying the precipitation process is investigated experimentally and calculated by numerical thermo-kinetic simulations. The computer simulation results of the sizes and distributions are confirmed by transmission electron microscopy (TEM). The theoretical background and the results of the investigations are discussed.

Thermo-mechanical analysis of an acceleration grid for the international thermonuclear experimental reactor-neutral beam injection system

International Nuclear Information System (INIS)

Fujiwara, Yukio; Hanada, Masaya; Okumura, Yoshikazu; Suzuki, Satoshi; Watanabe, Kazuhiro

2001-01-01

In the engineering design of a negative-ion beam source for a high-power neutral beam injection (NBI) system, one of the most important issues is thermo-mechanical design of acceleration grids for producing several tens of MW ion beams. An acceleration grid for the international thermonuclear experimental reactor-neutral beam injection (ITER-NBI) system will be subjected to the heat loading as high as 1.5 MW. In the present paper, thermo-mechanical characteristics of the acceleration grid for the ITER-NBI system were analyzed. Numerical simulation indicated that maximum aperture-axis displacement of the acceleration grid due to thermal expansion would be about 0.7 mm for the heat loading of 1.5 MW. From the thin lens theory of beam optics, beamlet deflection angle by the aperture-axis displacement was estimated to be about 2 mrad, which is within the requirement of the engineering design of the ITER-NBI system. Numerical simulation also indicated that no melting on the acceleration grid would occur for a heat loading of 1.5 MW, while local plastic deformation would happen. To avoid the plastic deformation, it is necessary to reduce the heat loading onto the acceleration grid to less than 1 MW

Shape distortion and thermo-mechanical properties of SOFC components from green tape to sintering body

DEFF Research Database (Denmark)

Teocoli, Francesca; Ni, De Wei; Tadesse Molla, Tesfaye

due to binder burn out, differential shrinkage behavior and to a potential interfacial reaction between the two materials. To analyze the phenomena, shrinkage of SOFC components single layers and bilayered samples were measured insitu by optical dilatometer. The densification mismatch stress, due...... to the strain rate difference between materials, was calculated using Cai’s model. Camber (curvature) development for in situ co-firing of a bi-layer ceramic green tape has been investigated. Analysis of shape evolution from green to sintered body can be carried out by the thermo-mechanical analysis techniques....

Review on Synthesis, Thermo-Physical Property, and Heat Transfer Mechanism of Nanofluids

Directory of Open Access Journals (Sweden)

Mahesh Suresh Patil

2016-10-01

Full Text Available Nanofluids are suspended nano-sized particles in a base fluid. With increasing demand for more high efficiency thermal systems, nanofluids seem to be a promising option for researchers. As a result, numerous investigations have been undertaken to understand the behaviors of nanofluids. Since their discovery, the thermo-physical properties of nanofluids have been under intense research. Inadequate understanding of the mechanisms involved in the heat transfer of nanofluids has been the major obstacle for the development of sophisticated nanofluids with the desired properties. In this comprehensive review paper, investigations on synthesis, thermo-physical properties, and heat transfer mechanisms of nanofluids have been reviewed and presented. Results show that the thermal conductivity of nanofluids increases with the increase of the operating temperature. This can potentially be used for the efficiency enhancement of thermal systems under higher operating temperatures. In addition, this paper also provides details concerning dependency of the thermo-physical properties as well as synthesis and the heat transfer mechanism of the nanofluids.

Thermo-mechanical design of the SINGAP accelerator grids for ITER NB injectors

Energy Technology Data Exchange (ETDEWEB)

Agostinetti, P. [Consorzio RFX, Euratom-ENEA Association, Corso Stati Uniti 4, I35127 Padova (Italy)], E-mail: piero.agostinetti@igi.cnr.it; Dal Bello, S.; Dalla Palma, M.; Zaccaria, P. [Consorzio RFX, Euratom-ENEA Association, Corso Stati Uniti 4, I35127 Padova (Italy)

2007-10-15

The SINGle Aperture-SINgle GAP (SINGAP) accelerator for ITER neutral beam injector foresees four grids for the extraction and acceleration of negative ions, instead of the seven grids of the Multi-Aperture Multi-Grid (MAMuG) reference configuration. The grids have to fulfil specific requirements coming from ion extraction, beam optics and thermo-mechanical issues. This paper focuses on the thermo-hydraulic and thermo-mechanical design of the grids carried out by Consorzio RFX for the design of the first ITER NB injector and the ITER NB Test Facility. The cooling circuit design (position and shape of the channels) and the cooling parameters (water coolant temperatures, pressure and velocity) were optimized with sensitivity analyses in order to satisfy the grid functional requirements (temperatures, stresses, in plane and out of plane deformations). The design required a complete modelling of the grids and their support frames by means of 3D FE and CAD models.

NIST ThermoData Engine: Extension to Solvent Design and Propagation of Uncertainties for Process Simulation

DEFF Research Database (Denmark)

Diky, Vladimir; Chirico, Robert D.; Muzny, Chris

ThermoData Engine (TDE, NIST Standard Reference Databases 103a and 103b) is the first product that implements the concept of Dynamic Data Evaluation in the fields of thermophysics and thermochemistry, which includes maintaining the comprehensive and up-to-date database of experimentally measured ...... uncertainties, curve deviations, and inadequacies of the models. Uncertainty analysis shows relative contributions to the total uncertainty from each component and pair of components....

Effect of Sr2TiMnO6 fillers on mechanical, dielectric and thermal behaviour of PMMA polymer

Directory of Open Access Journals (Sweden)

P. Thomas

2015-09-01

Full Text Available Composites of poly(methyl methacrylate (PMMA and Sr2TiMnO6 (STMO were fabricated via melt mixing followed by hot pressing technique. These were characterized using X-ray diffraction (XRD, thermo gravimetric analysis (TGA, differential scanning calorimetry (DSC, thermo mechanical analysis (TMA and impedance analyser for their structural, thermal and dielectric properties. The coefficient of thermal expansion (CTE was measured between 40°C and 100°C for pure PMMA is 115.2 ppm/°C, which was decreased to 78.58 ppm/°C when the STMO content was increased to 50 wt.% in PMMA. There was no difference in the glass transition (Tg temperature of the PMMA polymer and their composites. However, the FTIR analysis indicated possible interaction between the PMMA and STMO. The density and the hardness were increased as the STMO content increased in the PMMA matrix. Permittivity was found to be as high as 30.9 at 100 Hz for the PMMA+STMO-50 wt.% composites, indicating the possibility of using these materials for capacitor applications. The thermal stability of polymer was enhanced by incorporation of STMO fillers.

Improvement of thermo-mechanical properties of ceramic materials for nuclear applications

International Nuclear Information System (INIS)

Decroix, G.M.; Gosset, D.; Kryger, B.; Boussuge, M.; Burlet, H.

1994-01-01

In order to improve the thermo-mechanical properties of materials used as neutron absorbers in nuclear reactors, cermet or cercer have been produced with two original microstructures: micro- or macro-dispersed composites. The composites thermal shock resistance has been evaluated in an image furnace. The microstructures we obtained involve different reinforcement mechanisms, such as crack deflection, crack branching, crack bridging or microcrack toughening, and improvement of thermal conductivity. The results reveal a significant improvement of the thermo-mechanical properties of the boron base neutron absorbers whose fabrication process leads to a macro-dispersed microstructure. (authors). 8 refs., 8 figs., 2 tabs

A new formalism for non extensive physical systems: Tsallis Thermo statistics

International Nuclear Information System (INIS)

Tirnakli, U.; Bueyuekkilic, F.; Demirhan, D.

1999-01-01

Although Boltzmann-Gibbs (BG) statistics provides a suitable tool which enables us to handle a large number of physical systems satisfactorily, it has some basic restrictions. Recently a non extensive thermo statistics has been proposed by C.Tsallis to handle the non extensive physical systems and up to now, besides the generalization of some of the conventional concepts, the formalism has been prosperous in some of the physical applications. In this study, our effort is to introduce Tsallis thermo statistics in some details and to emphasize its achievements on physical systems by noting the recent developments on this line

An Explicit Approach Toward Modeling Thermo-Coupled Deformation Behaviors of SMPs

Directory of Open Access Journals (Sweden)

Hao Li

2017-03-01

Full Text Available A new elastoplastic J 2 -flow models with thermal effects is proposed toward simulating thermo-coupled finite deformation behaviors of shape memory polymers. In this new model, an elastic potential evolving with development of plastic flow is incorporated to characterize the stress-softening effect at unloading and, moreover, thermo-induced plastic flow is introduced to represent the strain recovery effect at heating. It is shown that any given test data for both effects may be accurately simulated by means of direct and explicit procedures. Numerical examples for model predictions compare well with test data in literature.

[Determination of total, soluble and insoluble dietary fiber in foods by enzymatic-gravimetric method].

Science.gov (United States)

Yang, X; Yang, Y; Zhou, R; Bian, L

2001-11-01

For studying the contents of dietary fiber in general foods and functional foods, a enzymatic-gravimetric method recommended by AOAC was established in our laboratory. The method for the determination of total, soluble and insoluble dietary fiber in foods and functional foods could be used for many other kind of foods. The relative standard deviations (RSD) of reproducibility between-run and within-run were 2.04%-7.85%, 3.42%-55.23% respectively. The repeatability of the methods was good, and the methods are suitable for many foods.

Moroccan rock phosphate solubilization during a thermo-anaerobic ...

African Journals Online (AJOL)

In order to investigate the presence of thermo-tolerant rock phosphate (RP) solubilizing anaerobic microbes during the fermentation process, we used grassland as sole organic substrate to evaluate the RP solubilization process under anaerobic thermophilic conditions. The result shows a significant decrease of pH from ...