WorldWideScience

Sample records for thermal storage walls

  1. Thermal Feature of a Modified Solar Phase Change Material Storage Wall System

    Directory of Open Access Journals (Sweden)

    Chenglong Luo

    2018-01-01

    Full Text Available This work is to study a novel solar PCM storage wall technology, that is, a dual-channel and thermal-insulation-in-the-middle type solar PCM storage wall (MSPCMW system. The system has the following four independent functions, passive solar heating, heat preservation, heat insulation, and passive cooling, and it can agilely cope with the requirements of climatization of buildings in different seasons throughout the year and is exactly suitable for building in regions characterized by hot summer and cold winter. The present work experimentally analyzes thermal feature of the system working in summer and winter modes, respectively.

  2. Thermal Feature of a Modified Solar Phase Change Material Storage Wall System

    OpenAIRE

    Luo, Chenglong; Xu, Lijie; Ji, Jie; Liao, Mengyin; Sun, Dan

    2018-01-01

    This work is to study a novel solar PCM storage wall technology, that is, a dual-channel and thermal-insulation-in-the-middle type solar PCM storage wall (MSPCMW) system. The system has the following four independent functions, passive solar heating, heat preservation, heat insulation, and passive cooling, and it can agilely cope with the requirements of climatization of buildings in different seasons throughout the year and is exactly suitable for building in regions characterized by hot sum...

  3. Solar energy thermalization and storage device

    Science.gov (United States)

    McClelland, J.F.

    A passive solar thermalization and thermal energy storage assembly which is visually transparent is described. The assembly consists of two substantial parallel, transparent wall members mounted in a rectangular support frame to form a liquid-tight chamber. A semitransparent thermalization plate is located in the chamber, substantially paralled to and about equidistant from the transparent wall members to thermalize solar radiation which is stored in a transparent thermal energy storage liquid which fills the chamber. A number of the devices, as modules, can be stacked together to construct a visually transparent, thermal storage wall for passive solar-heated buildings.

  4. Enhancement of heat transfer for thermal energy storage application using stearic acid nanocomposite with multi-walled carbon nanotubes

    International Nuclear Information System (INIS)

    Li, TingXian; Lee, Ju-Hyuk; Wang, RuZhu; Kang, Yong Tae

    2013-01-01

    A latent heat storage nanocomposite made of stearic acid (SA) and multi-walled carbon nanotube (MWCNT) is prepared for thermal energy storage application. The thermal properties of the SA/MWCNT nanocomposite are characterized by SEM (scanning electron microscopy) and DSC (differential scanning calorimeter) analysis techniques, and the effects of different volume fractions of MWCNT on the heat transfer enhancement and thermal performance of stearic acid are investigated during the charging and discharging phases. The SEM analysis shows that the additive of MWCNT is uniformly distributed in the phase change material of stearic acid, and the DSC analysis reveals that the melting point of SA/MWCNT nanocomposite shifts to a lower temperature during the charging phase and the freezing point shifts to a higher temperature during the discharging phase when compared with the pure stearic acid. The experimental results show that the addition of MWCNT can improve the thermal conductivity of stearic acid effectively, but it also weakens the natural convection of stearic acid in liquid state. In comparison with the pure stearic acid, the charging rate can be decreased by about 50% while the discharging rate can be improved by about 91% respectively by using the SA/5.0% MWCNT nanocomposite. It appears that the MWCNT is a promising candidate for enhancing the heat transfer performance of latent heat thermal energy storage system. - Highlights: • A nanocomposite made of stearic acid and multi-walled carbon nanotube is prepared for thermal energy storage application. • Effects of multi-walled carbon nanotube on the thermal performance of the nanocomposite are investigated. • Multi-walled carbon nanotube enhances the thermal conductivity but weakens the natural convection of stearic acid. • Discharging/charging rates of stearic acid are increased/decreased by using multi-walled carbon nanotube

  5. Thermal energy storage and losses in a room-Trombe wall system located in Mexico

    International Nuclear Information System (INIS)

    Hernández-López, I.; Xamán, J.; Chávez, Y.; Hernández-Pérez, I.; Alvarado-Juárez, R.

    2016-01-01

    A thermal evaluation of a R-TW system (room with a Trombe wall) is presented. Hourly climatic data of the coldest and the warmest days of 2014 was used to assess the behavior of the R-TW in two cities of Mexico with cold climate (Huitzilac and Toluca). The simulations were done with an in-house code based on the Finite Volume Method. It was found that thermal energy losses through the semitransparent wall are about 60% of the solar radiation incident on the system (G_s_o_l). Despite of the thermal losses, the system gets enough energy to keep the air inside the room with a temperature above 35 °C. For both cities during the coldest day, the maximum energy stored is about 109 MJ and during the warmest day is about 70 MJ. This energy is supplied from the storage wall to the air inside the room during periods without insolation. - Highlights: • Thermal performance of a Room-Trombe Wall system was evaluated under two cold cities. • Thermal energy losses through the semitransparent wall were about 60% of the solar radiation incident of the system. • The maximum energy stored by the Trombe Wall was 109 MJ during the coldest day. • The maximum energy stored by the Trombe Wall was 70 MJ during the warmest day.

  6. The roles of thermal insulation and heat storage in the energy performance of the wall materials: a simulation study.

    Science.gov (United States)

    Long, Linshuang; Ye, Hong

    2016-04-07

    A high-performance envelope is the prerequisite and foundation to a zero energy building. The thermal conductivity and volumetric heat capacity of a wall are two thermophysical properties that strongly influence the energy performance. Although many case studies have been performed, the results failed to give a big picture of the roles of these properties in the energy performance of an active building. In this work, a traversal study on the energy performance of a standard room with all potential wall materials was performed for the first time. It was revealed that both heat storage materials and insulation materials are suitable for external walls. However, the importances of those materials are distinct in different situations: the heat storage plays a primary role when the thermal conductivity of the material is relatively high, but the effect of the thermal insulation is dominant when the conductivity is relatively low. Regarding internal walls, they are less significant to the energy performance than the external ones, and they need exclusively the heat storage materials with a high thermal conductivity. These requirements for materials are consistent under various climate conditions. This study may provide a roadmap for the material scientists interested in developing high-performance wall materials.

  7. Semi-transparent solar energy thermal storage device

    Science.gov (United States)

    McClelland, John F.

    1985-06-18

    A visually transmitting solar energy absorbing thermal storage module includes a thermal storage liquid containment chamber defined by an interior solar absorber panel, an exterior transparent panel having a heat mirror surface substantially covering the exterior surface thereof and associated top, bottom and side walls, Evaporation of the thermal storage liquid is controlled by a low vapor pressure liquid layer that floats on and seals the top surface of the liquid. Porous filter plugs are placed in filler holes of the module. An algicide and a chelating compound are added to the liquid to control biological and chemical activity while retaining visual clarity. A plurality of modules may be supported in stacked relation by a support frame to form a thermal storage wall structure.

  8. Numerical analysis of a PCM thermal storage system with varying wall temperature

    International Nuclear Information System (INIS)

    Halawa, E.; Bruno, F.; Saman, W.

    2005-01-01

    Numerical analysis of melting and freezing of a PCM thermal storage unit (TSU) with varying wall temperature is presented. The TSU under analysis consists of several layers of thin slabs of a PCM subjected to convective boundary conditions where air flows between the slabs. The model employed takes into account the variations in wall temperature along the direction of air flow as well as the sensible heat. The paper discusses typical characteristics of the melting/freezing of PCM slabs in an air stream and presents some results of the numerical simulation in terms of air outlet temperatures and heat transfer rates during the whole periods of melting and freezing. Considerations in the design of the TSU are also given

  9. Thermal performance of a PCM thermal storage unit

    Energy Technology Data Exchange (ETDEWEB)

    Liu Ming; Bruno, Frank; Saman, Wasim [Sustainable Energy Centre, Inst. for Sustainable Systems and Technologies, Univ. of South Australia, Mawson Lakes, Adelaide (Australia)

    2008-07-01

    The thermal performance of a PCM thermal storage unit (TSU) is studied numerically and experimentally. The TSU under analysis consists of several flat slabs of phase change material (PCM) with melting temperature of -26.7 C. Liquid heat transfer fluid (HTF) passes between the slabs to charge and discharge the storage unit. A one dimensional mathematical model was employed to analyze the transient thermal behavior of the storage unit during the melting and freezing processes. The model takes into consideration the temperature variations in the wall along the flow direction of the HTF. The paper compares the experimental and numerical simulation results in terms of HTF outlet temperatures during the melting period. (orig.)

  10. Residential Solar-Based Seasonal Thermal Storage Systems in Cold Climates: Building Envelope and Thermal Storage

    Directory of Open Access Journals (Sweden)

    Alexandre Hugo

    2012-10-01

    Full Text Available The reduction of electricity use for heating and domestic hot water in cold climates can be achieved by: (1 reducing the heating loads through the improvement of the thermal performance of house envelopes, and (2 using solar energy through a residential solar-based thermal storage system. First, this paper presents the life cycle energy and cost analysis of a typical one-storey detached house, located in Montreal, Canada. Simulation of annual energy use is performed using the TRNSYS software. Second, several design alternatives with improved thermal resistance for walls, ceiling and windows, increased overall air tightness, and increased window-to-wall ratio of South facing windows are evaluated with respect to the life cycle energy use, life cycle emissions and life cycle cost. The solution that minimizes the energy demand is chosen as a reference house for the study of long-term thermal storage. Third, the computer simulation of a solar heating system with solar thermal collectors and long-term thermal storage capacity is presented. Finally, the life cycle cost and life cycle energy use of the solar combisystem are estimated for flat-plate solar collectors and evacuated tube solar collectors, respectively, for the economic and climatic conditions of this study.

  11. Experimental Study on Melting and Solidification of Phase Change Material Thermal Storage

    Science.gov (United States)

    Ambarita, H.; Abdullah, I.; Siregar, C. A.; Siregar, R. E. T.; Ronowikarto, A. D.

    2017-03-01

    Melting and solidification process of Phase Change Materials (PCMs) are investigated experimentally. The tested PCMs are Paraffin wax and Steric acid which typically used for solar water heater. The objective is to explore the characteristics of the PCM when it is being melted and solidified. The experiments are performed in a glass box. One side of the box wall is heated while the opposite wall is kept constant and other walls are insulated. Temperature of the heated wall are kept constant at 80°C, 85°C, and 90°C, respectively. Every experiment is carried out for 600 minutes. Temperatures are recorded and the melting and solidification processes are pictured by using camera. The results show that the melting process starts from the upper part of the thermal storage. In the solidification process, it starts from the lower part of the thermal storage. As a thermal energy storage, Paraffin wax is better than Steric acid. This is because Paraffin wax can store more energy. At heat source temperature of 90°C, thermal energy stored by Paraffin wax and Stearic acid is 61.84 kJ and 57.39 kJ, respectively. Thus it is better to used Paraffin wax in the solar water heater as thermal energy storage.

  12. Thermal energy storage based on cementitious materials: A review

    Directory of Open Access Journals (Sweden)

    Khadim Ndiaye

    2018-01-01

    Full Text Available Renewable energy storage is now essential to enhance the energy performance of buildings and to reduce their environmental impact. Many heat storage materials can be used in the building sector in order to avoid the phase shift between solar radiation and thermal energy demand. However, the use of storage material in the building sector is hampered by problems of investment cost, space requirements, mechanical performance, material stability, and high storage temperature. Cementitious material is increasingly being used as a heat storage material thanks to its low price, mechanical performance and low storage temperature (generally lower than 100 °C. In addition, cementitious materials for heat storage have the prominent advantage of being easy to incorporate into the building landscape as self-supporting structures or even supporting structures (walls, floor, etc.. Concrete solutions for thermal energy storage are usually based on sensible heat transfer and thermal inertia. Phase Change Materials (PCM incorporated in concrete wall have been widely investigated in the aim of improving building energy performance. Cementitious material with high ettringite content stores heat by a combination of physical (adsorption and chemical (chemical reaction processes usable in both the short (daily, weekly and long (seasonal term. Ettringite materials have the advantage of high energy storage density at low temperature (around 60 °C. The encouraging experimental results in the literature on heat storage using cementitious materials suggest that they could be attractive in a number of applications. This paper summarizes the investigation and analysis of the available thermal energy storage systems using cementitious materials for use in various applications.

  13. PCM thermal storage design in buildings: Experimental studies and applications to solaria in cold climates

    International Nuclear Information System (INIS)

    Guarino, Francesco; Athienitis, Andreas; Cellura, Maurizio; Bastien, Diane

    2017-01-01

    Highlights: • This paper analyzes the performance of a building-integrated thermal storage system. • A wall opposing a glazed surface serves as phase change materials thermal storage. • The study is based on both experimental and simulation studies. • Heat is stored and released up to 6–8 h after solar irradiation. • Yearly heating requirements are reduced by 17% in a cold climate. - Abstract: As energy availability and demand often do not match, thermal energy storage plays a crucial role to take advantage of solar radiation in buildings: in particular, latent heat storage via phase-change material is particularly attractive due to its ability to provide high energy storage density. This paper analyzes the performance of a building-integrated thermal storage system to increase the energy performances of solaria in a cold climate. A wall opposing a highly glazed façade (south oriented) is used as thermal storage with phase change materials embedded in the wall. The study is based on both experimental and simulation studies. The concept considered is particularly suited to retrofits in a solarium since the PCM can be added as layers facing the large window on the vertical wall directly opposite. Results indicate that this PCM thermal storage system is effective during the whole year in a cold climate. The thermal storage allows solar radiation to be stored and released up to 6–8 h after solar irradiation: this has effects on both the reduction of daily temperature swings (up to 10 °C) and heating requirements (more than 17% on a yearly base). Coupling of the thermal storage system with natural ventilation is important during mid-seasons and summer to improve the PCM charge-discharge cycles and to reduce overheating. Results also show that cooling is less important than heating, reaching up to 20% of the overall annual energy requirements for the city of Montreal, Canada. Moreover, the phase change temperature range of the material used (18–24

  14. Thermal energy storage devices, systems, and thermal energy storage device monitoring methods

    Science.gov (United States)

    Tugurlan, Maria; Tuffner, Francis K; Chassin, David P.

    2016-09-13

    Thermal energy storage devices, systems, and thermal energy storage device monitoring methods are described. According to one aspect, a thermal energy storage device includes a reservoir configured to hold a thermal energy storage medium, a temperature control system configured to adjust a temperature of the thermal energy storage medium, and a state observation system configured to provide information regarding an energy state of the thermal energy storage device at a plurality of different moments in time.

  15. Thermal energy storage apparatus, controllers and thermal energy storage control methods

    Science.gov (United States)

    Hammerstrom, Donald J.

    2016-05-03

    Thermal energy storage apparatus, controllers and thermal energy storage control methods are described. According to one aspect, a thermal energy storage apparatus controller includes processing circuitry configured to access first information which is indicative of surpluses and deficiencies of electrical energy upon an electrical power system at a plurality of moments in time, access second information which is indicative of temperature of a thermal energy storage medium at a plurality of moments in time, and use the first and second information to control an amount of electrical energy which is utilized by a heating element to heat the thermal energy storage medium at a plurality of moments in time.

  16. Transient characteristics of thermal energy storage in an enclosure packed with MEPCM particles

    International Nuclear Information System (INIS)

    Siao, Yong-Hao; Yan, Wei-Mon; Lai, Chi-Ming

    2015-01-01

    The heat transfer characteristics of phase change materials have been of continuing interest of research due to various potential technical applications, such as the latent-heat thermal energy storage, thermal protection, as well as active/passive electronic cooling. In this work, the transient characteristics of thermal energy storage in a partitioned enclosure filled with microencapsulated phase change material (MEPCM) particles were investigated experimentally and numerically. To examine the different melting temperature effects, two different MEPCM particles are tested. The core phase change materials of the MEPCM are n-octadecane with melting temperature about T M  = 28 °C and 37 °C. The enclosure is partitioned and is differentially heated by the two horizontal isothermal surfaces, while the other vertical surfaces are considered thermally insulated. The studies have been undertaken for five sets of the hot and cold wall temperatures imposed across the enclosure. The consequents show that the numerical results are in agreement with the measured data. At the initial transient, the net energy storage in enclosure, Q net , increases with the time Fo. Finally, the Q net approaches quickly the steady state for the case with a higher temperature difference of T h  − T c . Additionally, higher dimensionless accumulated energy through the hot wall Q h and cold wall Q c is found for a case with higher hot wall temperature T h

  17. Discharging process of a finned heat pipe–assisted thermal energy storage system with high temperature phase change material

    International Nuclear Information System (INIS)

    Tiari, Saeed; Qiu, Songgang; Mahdavi, Mahboobe

    2016-01-01

    Highlights: • The discharging process of a latent heat thermal energy storage system is studied. • The thermal energy storage system is assisted by finned heat pipes. • The influences of heat pipe spacing and fins geometrical features are studied. • Smaller heat pipe spacing enhances the solidification rate. • Better heat pipe and fin arrangements are determined. - Abstract: This paper presents the results of a numerical study conducted to investigate the discharging process of a latent heat thermal energy storage system assisted by finned heat pipes. A two-dimensional finite volume based numerical model along with enthalpy-porosity technique is employed to simulate the phase change of storage media during the discharging mode. The thermal energy storage system in this study consists of a square container, finned heat pipes, and potassium nitrate (KNO 3 ) as the phase change material. The charging process of the same thermal energy storage system was reported in an early paper by the authors. This paper reports the results of discharging process of the thermal energy storage system. The influences of heat pipe spacing, fin geometry and quantities as well as the effects of natural convection heat transfer on the thermal performance of the storage system were studied. The results indicate that the phase change material solidification process is hardly affected by the natural convection. Decreasing the heat pipe spacing results in faster discharging process and higher container base wall temperature. Increasing the fins length does not change the discharging time but yields higher base wall temperature. Using more fins also accelerates the discharging process and increases the container base wall temperature.

  18. Thermal storage/discharge performances of Cu-Si alloy for solar thermochemical process

    Science.gov (United States)

    Gokon, Nobuyuki; Yamaguchi, Tomoya; Cho, Hyun-seok; Bellan, Selvan; Hatamachi, Tsuyoshi; Kodama, Tatsuya

    2017-06-01

    The present authors (Niigata University, Japan) have developed a tubular reactor system using novel "double-walled" reactor/receiver tubes with carbonate molten-salt thermal storage as a phase change material (PCM) for solar reforming of natural gas and with Al-Si alloy thermal storage as a PCM for solar air receiver to produce high-temperature air. For both of the cases, the high heat capacity and large latent heat (heat of solidification) of the PCM phase circumvents the rapid temperature change of the reactor/receiver tubes at high temperatures under variable and uncontinuous characteristics of solar radiation. In this study, we examined cyclic properties of thermal storage/discharge for Cu-Si alloy in air stream in order to evaluate a potentiality of Cu-Si alloy as a PCM thermal storage material. Temperature-increasing performances of Cu-Si alloy are measured during thermal storage (or heat-charge) mode and during cooling (or heat-discharge) mode. A oxidation state of the Cu-Si alloy after the cyclic reaction was evaluated by using electron probe micro analyzer (EPMA).

  19. Thermal conductivity and latent heat thermal energy storage properties of LDPE/wax as a shape-stabilized composite phase change material

    International Nuclear Information System (INIS)

    Trigui, Abdelwaheb; Karkri, Mustapha; Krupa, Igor

    2014-01-01

    Highlights: • This study deals with the comparison of experimental results for different PCM composite to be used in passive solar walls. • This paper reports on the successful use of a specific experimental method in order to characterize the phase change effects. • The results have shown that most important thermal properties of these composites at the solid and liquid states. • Results indicate the thermal effectiveness of phase change material and significant amount of energy saving can be achieved. • Heat flux measurements are a very interesting experimental source of data which comes to complete the calorimetric device (DSC). - Abstract: Phase change material (PCM) composites based on low-density polyethylene (LDPE) with paraffin waxes were investigated in this study. The composites were prepared using a meltmixing method with a Brabender-Plastograph. The LDPE as the supporting matrix kept the molten waxes in compact shape during its phase transition from solid to liquid. Immiscibility of the PCMs (waxes) and the supporting matrix (LDPE) is a necessary property for effective energy storage. Therefore, this type paraffin can be used in a latent heat storage system without encapsulation. The objective of this research is to use PCM composite as integrated components in a passive solar wall. The proposed composite TROMBE wall allows daily storage of the solar energy in a building envelope and restitution in the evening, with a possible control of the air flux in a ventilated air layer. An experimental set-up was built to determine the thermal response of these composites to thermal solicitations. In addition, a DSC analysis was carried out. The results have shown that most important thermal properties of these composites at the solid and liquid states, like the “apparent” thermal conductivity, the heat storage capacity and the latent heat of fusion. Results indicate the performance of the proposed system is affected by the thermal effectiveness of

  20. FFTF vertical sodium storage tank preliminary thermal analysis

    International Nuclear Information System (INIS)

    Irwin, J.J.

    1995-01-01

    In the FFTF Shutdown Program, sodium from the primary and secondary heat transport loops, Interim Decay Storage (IDS), and Fuel Storage Facility (FSF) will be transferred to four large storage tanks for temporary storage. Three of the storage tanks will be cylindrical vertical tanks having a diameter of 28 feet, height of 22 feet and fabricated from carbon steel. The fourth tank is a horizontal cylindrical tank but is not the subject of this report. The storage tanks will be located near the FFTF in the 400 Area and rest on a steel-lined concrete slab in an enclosed building. The purpose of this work is to document the thermal analyses that were performed to ensure that the vertical FFTF sodium storage tank design is feasible from a thermal standpoint. The key criterion for this analysis is the time to heat up the storage tank containing frozen sodium at ambient temperature to 400 F. Normal operating conditions include an ambient temperature range of 32 F to 120 F. A key parameter in the evaluation of the sodium storage tank is the type of insulation. The baseline case assumed six inches of calcium silicate insulation. An alternate case assumed refractory fiber (Cerablanket) insulation also with a thickness of six inches. Both cases assumed a total electrical trace heat load of 60 kW, with 24 kW evenly distributed on the bottom head and 36 kW evenly distributed on the tank side wall

  1. Dynamic Exergy Analysis for the Thermal Storage Optimization of the Building Envelope

    Directory of Open Access Journals (Sweden)

    Valentina Bonetti

    2017-01-01

    Full Text Available As a measure of energy “quality”, exergy is meaningful for comparing the potential for thermal storage. Systems containing the same amount of energy could have considerably different capabilities in matching a demand profile, and exergy measures this difference. Exergy stored in the envelope of buildings is central in sustainability because the environment could be an unlimited source of energy if its interaction with the envelope is optimised for maintaining the indoor conditions within comfort ranges. Since the occurring phenomena are highly fluctuating, a dynamic exergy analysis is required; however, dynamic exergy modelling is complex and has not hitherto been implemented in building simulation tools. Simplified energy and exergy assessments are presented for a case study in which thermal storage determines the performance of seven different wall types for utilising nocturnal ventilation as a passive cooling strategy. Hourly temperatures within the walls are obtained with the ESP-r software in free-floating operation and are used to assess the envelope exergy storage capacity. The results for the most suitable wall types were different between the exergy analysis and the more traditional energy performance indicators. The exergy method is an effective technique for selecting the construction type that results in the most favourable free-floating conditions through the analysed passive strategy.

  2. Experimental investigations on the performance of a collector–storage wall system using phase change materials

    International Nuclear Information System (INIS)

    Zhou, Guobing; Pang, Mengmeng

    2015-01-01

    Highlights: • Performance of collector–storage wall using PCM was experimentally studied. • PCM surface temperature rises steep–slow–steep successively during charge. • After sharp drops, PCM surface temperature decreases slightly during discharge. • Temperatures of gap air, glazing and room vary with PCM surface temperature. • Air flow rate and heating rate fluctuate during charge but go steady after discharge. - Abstract: Experiments have been performed on the thermal behavior of a collector–storage wall system using PCM (phase change material). PCM slabs were attached on the gap-side wall surface to increase the heat storage. The test was carried out for a whole day with charging period of 6.5 h and discharging period of 17.5 h, respectively. Wall and air temperatures as well as air velocity in the gap were measured for analysis. The results showed that the PCM surface temperature increases first rapidly, then slowly and rapidly again during the charging process, which in turn corresponds with the three storage stages: sensible heat (solid), latent heat (melting) and sensible heat (liquid), respectively; while in the discharging process the PCM surface temperature decreases slightly shortly after the initial sharp drops, which suggests the long time period of solidification for PCM to release latent heat. Subject to the variations of PCM surface temperatures, similar trends were also found for the gap air temperatures, glazing temperature and indoor temperature. Both the air flow rate and heating rate by air circulation have up and down fluctuations during the charging period, and then, shortly after initial sharp drops, they keep at nearly steady values during the discharging period. The indoor temperature was found to be above 22 °C during the whole discharging period (17.5 h) under present conditions, which indicates that the indoor thermal comfort could be kept for a long time by using PCM in collector–storage wall system.

  3. Hollow porous-wall glass microspheres for hydrogen storage

    Science.gov (United States)

    Heung, Leung K.; Schumacher, Ray F.; Wicks, George G.

    2010-02-23

    A porous wall hollow glass microsphere is provided having a diameter range of between 1 to 200 microns, a density of between 1.0 to 2.0 gm/cc, a porous-wall structure having wall openings defining an average pore size of between 10 to 1000 angstroms, and which contains therein a hydrogen storage material. The porous-wall structure facilitates the introduction of a hydrogen storage material into the interior of the porous wall hollow glass microsphere. In this manner, the resulting hollow glass microsphere can provide a membrane for the selective transport of hydrogen through the porous walls of the microsphere, the small pore size preventing gaseous or liquid contaminants from entering the interior of the hollow glass microsphere.

  4. Study of Aquifer Thermal Energy Storage

    Science.gov (United States)

    Okuyama, Masaaki; Umemiya, Hiromichi; Shibuya, Ikuko; Haga, Eiji

    Yamagata University 'Aquifer Thermal Energy Storage (ATES)' is the experimental system which has been running since 1982. From the results for along terms of experiments, we obtain many important knowledge. This paper presents the accomplishments for 16 years and the characteristics of thermal energy storage in thermal energy storage well. The conclusions show as follows. 1)In recent years, the thermal recovery factor of warm energy storage well becomes almost constant at about 60%. 2) The thermal recovery factor of cool energy storage well increases gradually and becomes at about 15%. 3) Since the ferric colloidal dam is formed in aquifer, thermal recovery factor increase year after year. 4) Back wash can remove clogging for ferric colloidal dam. 5) The apparent thermal diffusivity decrease gradually due to ferric colloidal dam.

  5. Thermal performance of a multiple PCM thermal storage unit for free cooling

    International Nuclear Information System (INIS)

    Mosaffa, A.H.; Infante Ferreira, C.A.; Talati, F.; Rosen, M.A.

    2013-01-01

    Highlights: ► Numerical analysis on the performance of a thermal storages as free cooling system. ► Employing multiple PCMs to enhance heat transfer rate in thermal storages. ► Using an effective heat capacity method, the phase change parameters are determined. ► The effect of the slabs size and air channel thickness on COP is investigated. - Abstract: As demand for refrigeration and air conditioning increased during the last decade, the opportunities have expanded for using thermal energy storage (TES) systems in an economically advantageous manner in place of conventional cooling plants. Many cool storage systems use phase change materials (PCMs) and achieve peak load shifting in buildings. This work presents numerical investigations of the performance enhancement of a free cooling system using a TES unit employing multiple PCMs. The TES unit is composed of a number of rectangular channels for the flowing heat transfer fluid, separated by PCM slabs. Using the effective heat capacity method, the melting and solidification of the PCM is solved. The forced convective heat transfer inside the channels is analyzed by solving the energy equation, which is coupled with the heat conduction equation in the container wall. The effect of design parameters such as PCM slab length, thickness and fluid passage gap on the storage performance is also investigated using an energy based optimization. The results show that a system which can guarantee comfort conditions for the climate of Tabriz, Iran has an optimum COP of 7.0. This could be achieved by a combination of CaCl 2 ·6H 2 O with RT25 with the optimum air channel thickness of 3.2 mm, length of 1.3 m and PCM slab thickness of 10 mm

  6. Thermal analysis of the failed equipment storage vault system

    International Nuclear Information System (INIS)

    Jerrell, J.; Lee, S.Y.; Shadday, A.

    1995-07-01

    A storage facility for failed glass melters is required for radioactive operation of the Defense Waste Processing Facility (DWPF). It is currently proposed that the failed melters be stored in the Failed Equipment Storage Vaults (FESV's) in S area. The FESV's are underground reinforced concrete structures constructed in pairs, with adjacent vaults sharing a common wall. A failed melter is to be placed in a steel Melter Storage Box (MSB), sealed, and lowered into the vault. A concrete lid is then placed over the top of the FESV. Two melters will be placed within the FESV/MSB system, separated by the common wall. There is no forced ventilation within the vault so that the melter is passively cooled. Temperature profiles in the Failed Equipment Storage Vault Structures have been generated using the FLOW3D software to model heat conduction and convection within the FESV/MSB system. Due to complexities in modeling radiation with FLOW3D, P/THERMAL software has been used to model radiation using the conduction/convection temperature results from FLOW3D. The final conjugate model includes heat transfer by conduction, convection, and radiation to predict steady-state temperatures. Also, the FLOW3D software has been validated as required by the technical task request

  7. Thermal insulation properties of walls

    Directory of Open Access Journals (Sweden)

    Zhukov Aleksey Dmitrievich

    2014-05-01

    Full Text Available Heat-protective qualities of building structures are determined by the qualities of the used materials, adequate design solutions and construction and installation work of high quality. This rule refers both to the structures made of materials similar in their structure and nature and mixed, combined by a construction system. The necessity to ecaluate thermal conductivity is important for a product and for a construction. Methods for evaluating the thermal protection of walls are based on the methods of calculation, on full-scale tests in a laboratory or on objects. At the same time there is a reason to believe that even deep and detailed calculation may cause deviation of the values from real data. Using finite difference method can improve accuracy of the results, but it doesn’t solve all problems. The article discusses new approaches to evaluating thermal insulation properties of walls. The authors propose technique of accurate measurement of thermal insulation properties in single blocks and fragments of walls and structures.

  8. Thermal stress analysis of the fuel storage facility

    International Nuclear Information System (INIS)

    Chen, W.W.

    1991-12-01

    This paper presents the results of a nonlinear finite-element analysis to determine the structural integrity of the walls of the nuclear fuel storage room in the Radio Isotope Power System Facility of the Fuels and Materials Examination Facility (FMEF) Project. The analysis was performed to assess the effects of thermal loading on the walls that would result from a loss-of-cooling accident. The results obtained from using the same three-dimensional finite-element model with different types of elements, the eight-node brick element and the nonlinear concrete element, and the calculated results using the analytical solutions, are compared. The concrete responses in terms of octahedral normal and shearing stresses are described. The crack and crush states of the concrete were determined on the basis of multiaxial failure criteria

  9. Thermal analysis of dry concrete canister storage system for CANDU spent fuel

    International Nuclear Information System (INIS)

    Ryu, Yong Ho

    1992-02-01

    This paper presents the results of a thermal analysis of the concrete canisters for interim dry storage of spent, irradiated Canadian Deuterium Uranium(CANDU) fuel. The canisters are designed to contain 6-year-old fuel safely for periods of 50 years in stainless steel baskets sealed inside a steel-lined concrete shield. In order to assure fuel integrity during the storage, fuel rod temperature shall not exceed the temperature limit. The contents of thermal analysis include the following : 1) Steady state temperature distributions under the conservative ambient temperature and insolation load. 2) Transient temperature distributions under the changes in ambient temperature and insolation load. Accounting for the coupled heat transfer modes of conduction, convection, and radiation, the computer code HEATING5 was used to predict the thermal response of the canister storage system. As HEATING5 does not have the modeling capability to compute radiation heat transfer on a rod-to-rod basis, a separate calculating routine was developed and applied to predict temperature distribution in a fuel bundle. Thermal behavior of the canister is characterized by the large thermal mass of the concrete and radiative heat transfer within the basket. The calculated results for the worst case (steady state with maximum ambient temperature and design insolation load) indicated that the maximum temperature of the 6 year cooled fuel reached to 182.4 .deg. C, slightly above the temperature limit of 180 .deg. C. However,the thermal inertia of the thick concrete wall moderates the internal changes and prevents a rise in fuel temperature in response to ambient changes. The maximum extent of the transient zone was less than 75% of the concrete wall thickness for cyclic insolation changes. When transient nature of ambient temperature and insolation load are considered, the fuel temperature will be a function of the long term ambient temperature as opposed to daily extremes. The worst design

  10. Performance of phase change materials on storage capacity of trombe wall

    International Nuclear Information System (INIS)

    Al-Karaghouli, A.A.; Mujally, L.

    2006-01-01

    Two types of phase change materials were used as storage media in a Trombe Wall; namely paraffin wax (N-Eicoseue C 20 H 42 ) and Glaubers Salt (Na 2 SO 4 10H 2 O). To investigate the performance of these materials, a theoretical model and a simulation programme were developed. The wall temperature, the amount of heat stored, and the optimum wall thickness were calculated for both types. The study found that using two sheets of glass on the outside wall increased the surface wall temperature by around 50 degree C. It also found that Glauber salt was a much better storage material than paraffin wax. For a selected winter day at a location of 32 o N latitude, the storage capacity of the salt was more than twice that of the paraffin wax. The salt storage capacity was 32816 kJ/m 3 at an optimum wall thickness of 16 cm. this value for paraffin was 14464 kJ/m 3 at 13 cm optimum thickness. The study also concluded that according to this high heating value the wall uses, Glauber salt as a storage medium could supply its heat to the surrounding for a much longer period at night

  11. Electricity storage using a thermal storage scheme

    Energy Technology Data Exchange (ETDEWEB)

    White, Alexander, E-mail: ajw36@cam.ac.uk [Hopkinson Laboratory, Cambridge University Engineering Department, Trumpington Street, Cambridge. CB2 1PZ (United Kingdom)

    2015-01-22

    The increasing use of renewable energy technologies for electricity generation, many of which have an unpredictably intermittent nature, will inevitably lead to a greater demand for large-scale electricity storage schemes. For example, the expanding fraction of electricity produced by wind turbines will require either backup or storage capacity to cover extended periods of wind lull. This paper describes a recently proposed storage scheme, referred to here as Pumped Thermal Storage (PTS), and which is based on “sensible heat” storage in large thermal reservoirs. During the charging phase, the system effectively operates as a high temperature-ratio heat pump, extracting heat from a cold reservoir and delivering heat to a hot one. In the discharge phase the processes are reversed and it operates as a heat engine. The round-trip efficiency is limited only by process irreversibilities (as opposed to Second Law limitations on the coefficient of performance and the thermal efficiency of the heat pump and heat engine respectively). PTS is currently being developed in both France and England. In both cases, the schemes operate on the Joule-Brayton (gas turbine) cycle, using argon as the working fluid. However, the French scheme proposes the use of turbomachinery for compression and expansion, whereas for that being developed in England reciprocating devices are proposed. The current paper focuses on the impact of the various process irreversibilities on the thermodynamic round-trip efficiency of the scheme. Consideration is given to compression and expansion losses and pressure losses (in pipe-work, valves and thermal reservoirs); heat transfer related irreversibility in the thermal reservoirs is discussed but not included in the analysis. Results are presented demonstrating how the various loss parameters and operating conditions influence the overall performance.

  12. Thermal performance and heat transport in aquifer thermal energy storage

    Science.gov (United States)

    Sommer, W. T.; Doornenbal, P. J.; Drijver, B. C.; van Gaans, P. F. M.; Leusbrock, I.; Grotenhuis, J. T. C.; Rijnaarts, H. H. M.

    2014-01-01

    Aquifer thermal energy storage (ATES) is used for seasonal storage of large quantities of thermal energy. Due to the increasing demand for sustainable energy, the number of ATES systems has increased rapidly, which has raised questions on the effect of ATES systems on their surroundings as well as their thermal performance. Furthermore, the increasing density of systems generates concern regarding thermal interference between the wells of one system and between neighboring systems. An assessment is made of (1) the thermal storage performance, and (2) the heat transport around the wells of an existing ATES system in the Netherlands. Reconstruction of flow rates and injection and extraction temperatures from hourly logs of operational data from 2005 to 2012 show that the average thermal recovery is 82 % for cold storage and 68 % for heat storage. Subsurface heat transport is monitored using distributed temperature sensing. Although the measurements reveal unequal distribution of flow rate over different parts of the well screen and preferential flow due to aquifer heterogeneity, sufficient well spacing has avoided thermal interference. However, oversizing of well spacing may limit the number of systems that can be realized in an area and lower the potential of ATES.

  13. Maximizing the energy storage performance of phase change thermal storage systems

    Energy Technology Data Exchange (ETDEWEB)

    Amin, N.A.M.; Bruno, F.; Belusko, M. [South Australia Univ., Mawson Lakes, South Australia (Australia). Inst. for Sustainable Systems and Technologies

    2009-07-01

    The demand for electricity in South Australia is highly influenced by the need for refrigeration and air-conditioning. An extensive literature review has been conducted on the use of phase change materials (PCMs) in thermal storage systems. PCMs use latent heat at the solid-liquid phase transition point to store thermal energy. They are considered to be useful as a thermal energy storage (TES) material because they can provide much higher energy storage densities compared to conventional sensible thermal storage materials. This paper reviewed the main disadvantages of using PCMs for energy storage, such as low heat transfer, super cooling and system design issues. Other issues with PCMs include incongruence and corrosion of heat exchanger surfaces. The authors suggested that in order to address these problems, future research should focus on maximizing heat transfer by optimizing the configuration of the encapsulation through a parametric analysis using a PCM numerical model. The effective conductivity in encapsulated PCMs in a latent heat thermal energy storage (LHTES) system can also be increased by using conductors in the encapsulation that have high thermal conductivity. 47 refs., 1 tab., 1 fig.

  14. Cna 1 spent fuel element interim dry storage system thermal analysis

    International Nuclear Information System (INIS)

    Hilal, R. E; Garcia, J. C; Delmastro, D. F

    2006-01-01

    At the moment, the Atucha I Nuclear Power Plant (Cnea-I) located in the city of Lima, has enough room to store its spent fuel (Sf) in their two pools spent fuel until about 2015.In case of life extension a spend fuel element interim dry storage system is needed.Nucleolectrica Argentina S.A. (N A-S A) and the Comision Nacional de Energia Atomica (Cnea), have proposed different interim dry storage systems.These systems have to be evaluated in order to choose one of them.The present work's objective is the thermal analysis of one dry storage alternative for the Sf element of Cna 1.In this work a simple model was developed and used to perform the thermal calculations corresponding to the system proposed by Cnea.This system considers the store of sealed containers with 37 spent fuels in concrete modules.Each one of the containers is filled in the pool houses and transported to the module in a transference cask with lead walls.Fulfill the maximum cladding temperature requirement ( [es

  15. Thermal Response Of An Aerated Concrete Wall With Micro-Encapsulated Phase Change Material

    Science.gov (United States)

    Halúzová, Dušana

    2015-06-01

    For many years Phase Change Materials (PCM) have attracted attention due to their ability to store large amounts of thermal energy. This property makes them a candidate for the use of passive heat storage. In many applications, they are used to avoid the overheating of the temperature of an indoor environment. This paper describes the behavior of phase change materials that are inbuilt in aerated concrete blocks. Two building samples of an aerated concrete wall were measured in laboratory equipment called "twin-boxes". The first box consists of a traditional aerated concrete wall; the second one has additional PCM micro-encapsulated in the wall. The heat flux through the wall was measured and compared to simulation results modeled in the ESP-r program. This experimental measurement provides a foundation for a model that can be used to analyze further building constructions.

  16. First wall thermal hydraulic models for fusion blankets

    International Nuclear Information System (INIS)

    Fillo, J.A.

    1980-01-01

    Subject to normal and off-normal reactor conditions, thermal hydraulic models of first walls, e.g., a thermal mass barrier, a tubular shield, and a radiating liner are reviewed. Under normal operation the plasma behaves as expected in a predicted way for transient and steady-state conditions. The most severe thermal loading on the first wall occurs when the plasma becomes unstable and dumps its energy on the wall in a very short period of time (milliseconds). Depending on the plasma dump time and area over which the energy is deposited may result in melting of the first wall surface, and if the temperature is high enough, vaporization

  17. Combined Thermal Management and Power Generation Concept for the Spent Fuel Dry Storage Cask

    International Nuclear Information System (INIS)

    Kim, In Guk; Bang, In Cheol

    2017-01-01

    The management of the spent nuclear fuel generated by nuclear power plants is a major issue in Korea due to insufficient capacity of the wet storage pools. Therefore, it is considered that dry storage system is the one possible solution for storing spent fuel. A dual-purpose metal cask (transportation and storage) is currently developing in Korea. This cask has 21 of fuel assemblies and 16.8 kW of maximum decay heat. To evaluate the critical safety in normal/off normal and accident conditions, critical stabilities were conducted by using CSAS 6.0. The experimental investigation of heat removal of a concrete storage cask was also conducted under normal, off normal and accident conditions. The results of the evaluation showed a good safety of the dry storage cask. The results showed the enhanced thermal performance according to modification of flow rate. To verify combined thermal management and power generation concept, a new type of test facility for dry storage cask was designed in 1/10 scale of concrete dry storage cask. The experimental study involved the cooling methods that are an integrated system on the top of the dry cask and air flow path on the canister wall. The results showed the temperature distribution of the wall and inside of the dry cask at the normal condition. The influence of the change of the heat load and cooling system were investigated. The heat removal by the integrated system is approximately 20% of the total heat removal of the dry cask with reduced wall temperature. In these tests, economic analysis is conducted by applying the concept of the cost and efficiency. Under different decay power cases, the energy efficiency of the heat pipe and Stirling engine are determined and compared based on experimental results. The average efficiencies of the Stirling engine were the range of 2.375 to 3.247% under the power range of 35– 65W. These results showed that advanced dry storage concept had a better cooling performance in comparison with

  18. An integrated heat pipe-thermal storage design for a solar receiver

    Science.gov (United States)

    Keddy, E.; Sena, J. T.; Woloshun, K.; Merrigan, M. A.; Heidenreich, G.

    Light-weight heat pipe wall elements that incorporate a thermal storage subassembly within the vapor space are being developed as part of the Organic Rankine Cycle Solar Dynamic Power System (ORC-SDPS) receiver for the Space Station application. The operating temperature of the heat pipe elements is in the 770 to 810 K range with a design power throughput of 4.8 kW per pipe. The total heat pipe length is 1.9 M. The Rankine cycle boiler heat transfer surfaces are positioned within the heat pipe vapor space, providing a relatively constant temperature input to the vaporizer. The heat pipe design employs axial arteries and distribution wicked thermal storage units with potassium as the working fluid. Performance predictions for this configuration have been conducted and the design characterized as a function of artery geometry, distribution wick thickness, porosity, pore size, and permeability.

  19. Solar collector wall with active curtain system; Lasikatteinen massiivienen aurinkokeraeaejaeseinae

    Energy Technology Data Exchange (ETDEWEB)

    Ojanen, T.; Heimonen, I. [VTT Building Technology, Espoo (Finland). Building Physics, Building Services and Fire Technology

    1998-12-01

    Integration of solar collector into the building envelope structure brings many advantages. The disadvantage of a passive solar collector wall is that its thermal performance can not be controlled, which may cause temporary overheating and low thermal efficiency of the collector. The thermal performance of the collector wall can be improved by using controllable, active collector systems. In this paper a solar collector wall with a controllable curtain between the transparent and absorption layers is investigated. The curtain is made of several low-emissivity foil layers, which ensures low radiation heat transfer through the curtain. The curtain decreases the heat losses out from the collector wall and it improves the U-value of the wall. The curtain is used when the solar radiation intensity to the wall is not high enough or when the wall needs protection against overheating during warm weather conditions. The materials and building components used in the collector wall, except those of the curtain, are ordinary in buildings. The transparent layer can be made by using normal glazing technology and the thermal storage layer can be made out of brick or similar material. The solar energy gains through the glazing can be utilised better than in passive systems, because the curtain provides the wall with high thermal resistance outside the solar radiation periods. The thermal performance of the collector wall was studied experimentally using a Hot-Box apparatus equipped with a solar lamp. Numerical simulations were carried out to study the yearly performance of the collector wall under real climate conditions. The objectives were to determine the thermal performance of the collector wall and to study how to optimise the use of solar radiation in this system. When the curtain with high thermal resistance is used actively, the temperature level of the thermal storage layer in the wall is relatively high also during dark periods and the heat losses out from the storage

  20. Dismantling system of concrete thermal shielding walls

    International Nuclear Information System (INIS)

    Machida, Nobuhiro; Saiki, Yoshikuni; Ono, Yorimasa; Tokioka, Masatake; Ogino, Nobuyuki.

    1985-01-01

    Purpose: To enable safety and efficient dismantling of concrete thermal shielding walls in nuclear reactors. Method: Concrete thermal shielding walls are cut and dismantled into dismantled blocks by a plasma cutting tool while sealing the top opening of bioshielding structures. The dismantled blocks are gripped and conveyed. The cutting tool is remote-handled while monitoring on a television receiver. Slugs and dusts produced by cutting are removed to recover. Since the dismantling work is carried out while sealing the working circumstance and by the remote control of the cutting tool, the operators' safety can be secured. Further, since the thermal sealing walls are cut and dismantled into blocks, dismantling work can be done efficiently. (Moriyama, K.)

  1. Local Thermal Insulating Materials For Thermal Energy Storage ...

    African Journals Online (AJOL)

    Thermal insulation is one of the most important components of a thermal energy storage system. In this paper the thermal properties of selected potential local materials which can be used for high temperature insulation are presented. Thermal properties of seven different samples were measured. Samples consisted of: ...

  2. Concrete thermal energy storage for steam generation

    DEFF Research Database (Denmark)

    Singh, Shobhana; Sørensen, Kim

    2017-01-01

    Establishing enhancement methods to develop cost-effective thermal energy storage technology requires a detailed analysis. In this paper, a numerical investigation of the concrete based thermal energy storage system is carried out. The storage system consists of a heat transfer fluid flowing inside...

  3. Solar applications of thermal energy storage. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Lee, C.; Taylor, L.; DeVries, J.; Heibein, S.

    1979-01-01

    A technology assessment is presented on solar energy systems which use thermal energy storage. The study includes characterization of the current state-of-the-art of thermal energy storage, an assessment of the energy storage needs of solar energy systems, and the synthesis of this information into preliminary design criteria which would form the basis for detailed designs of thermal energy storage. (MHR)

  4. A Comprehensive Review of Thermal Energy Storage

    Directory of Open Access Journals (Sweden)

    Ioan Sarbu

    2018-01-01

    Full Text Available Thermal energy storage (TES is a technology that stocks thermal energy by heating or cooling a storage medium so that the stored energy can be used at a later time for heating and cooling applications and power generation. TES systems are used particularly in buildings and in industrial processes. This paper is focused on TES technologies that provide a way of valorizing solar heat and reducing the energy demand of buildings. The principles of several energy storage methods and calculation of storage capacities are described. Sensible heat storage technologies, including water tank, underground, and packed-bed storage methods, are briefly reviewed. Additionally, latent-heat storage systems associated with phase-change materials for use in solar heating/cooling of buildings, solar water heating, heat-pump systems, and concentrating solar power plants as well as thermo-chemical storage are discussed. Finally, cool thermal energy storage is also briefly reviewed and outstanding information on the performance and costs of TES systems are included.

  5. Thermal performance and heat transport in aquifer thermal energy storage

    NARCIS (Netherlands)

    Sommer, W.T.; Doornenbal, P.J.; Drijver, B.C.; Gaans, van P.F.M.; Leusbrock, I.; Grotenhuis, J.T.C.; Rijnaarts, H.H.M.

    2014-01-01

    Aquifer thermal energy storage (ATES) is used for seasonal storage of large quantities of thermal energy. Due to the increasing demand for sustainable energy, the number of ATES systems has increased rapidly, which has raised questions on the effect of ATES systems on their surroundings as well as

  6. Phase Change Materials for Thermal Energy Storage

    OpenAIRE

    Stiebra, L; Cabulis, U; Knite, M

    2014-01-01

    Phase change materials (PCMs) for thermal energy storage (TES) have become an important subject of research in recent years. Using PCMs for thermal energy storage provides a solution to increase the efficiency of the storage and use of energy in many domestic and industrial sectors. Phase change TES systems offer a number of advantages over other systems (e.g. chemical storage systems): particularly small temperature distance between the storage and retrieval cycles, small unit sizes and lo...

  7. Hollow ceramic block: containment of water for thermal storage in passive solar design. Final technical report

    Energy Technology Data Exchange (ETDEWEB)

    Winship, C.T.

    1983-12-27

    The project activity has been the development of designs, material compositions and production procedures to manufacture hollow ceramic blocks which contain water (or other heat absorptive liquids). The blocks are designed to serve, in plurality, a dual purpose: as an unobtrusive and efficient thermal storage element, and as a durable and aesthetically appealing surface for floors and walls of passive solar building interiors. Throughout the grant period, numerous ceramic formulas have been tested for their workabilty, thermal properties, maturing temperatures and color. Blocks have been designed to have structural integrity, and textured surfaces. Methods of slip-casting and extrusion have been developed for manufacturing of the blocks. The thermal storage capacity of the water-loaded block has been demonstrated to be 2.25 times greater than that of brick and 2.03 times greater than that of concrete (taking an average of commonly used materials). Although this represents a technical advance in thermal storage, the decorative effects provided by application of the blocks lend them a more significant advantage by reducing constraints on interior design in passive solar architecture.

  8. Heat transfer and thermal storage performance of an open thermosyphon type thermal storage unit with tubular phase change material canisters

    International Nuclear Information System (INIS)

    Wang, Ping-Yang; Hu, Bo-Wen; Liu, Zhen-Hua

    2015-01-01

    Highlights: • A novel open heat pipe thermal storage unit is design to improve its performance. • Mechanism of its operation is phase-change heat transfer. • Tubular canisters with phase change material were placed in thermal storage unit. • Experiment and analysis are carried out to investigate its operation properties. - Abstract: A novel open thermosyphon-type thermal storage unit is presented to improve design and performance of heat pipe type thermal storage unit. In the present study, tubular canisters filled with a solid–liquid phase change material are vertically placed in the middle of the thermal storage unit. The phase change material melts at 100 °C. Water is presented as the phase-change heat transfer medium of the thermal storage unit. The tubular canister is wrapped tightly with a layer of stainless steel mesh to increase the surface wettability. The heat transfer mechanism of charging/discharging is similar to that of the thermosyphon. Heat transfer between the heat resource or cold resource and the phase change material in this device occurs in the form of a cyclic phase change of the heat-transfer medium, which occurs on the surface of the copper tubes and has an extremely high heat-transfer coefficient. A series of experiments and theoretical analyses are carried out to investigate the properties of the thermal storage unit, including power distribution, start-up performance, and temperature difference between the phase change material and the surrounding vapor. The results show that the whole system has excellent heat-storage/heat-release performance

  9. Metal hydride-based thermal energy storage systems

    Science.gov (United States)

    Vajo, John J.; Fang, Zhigang

    2017-10-03

    The invention provides a thermal energy storage system comprising a metal-containing first material with a thermal energy storage density of about 1300 kJ/kg to about 2200 kJ/kg based on hydrogenation; a metal-containing second material with a thermal energy storage density of about 200 kJ/kg to about 1000 kJ/kg based on hydrogenation; and a hydrogen conduit for reversibly transporting hydrogen between the first material and the second material. At a temperature of 20.degree. C. and in 1 hour, at least 90% of the metal is converted to the hydride. At a temperature of 0.degree. C. and in 1 hour, at least 90% of the metal hydride is converted to the metal and hydrogen. The disclosed metal hydride materials have a combination of thermodynamic energy storage densities and kinetic power capabilities that previously have not been demonstrated. This performance enables practical use of thermal energy storage systems for electric vehicle heating and cooling.

  10. Basic Considerations for Dry Storage of Spent Nuclear Fuels and Revisited CFD Thermal Analysis on the Concrete Cask

    Energy Technology Data Exchange (ETDEWEB)

    Noh, Jae Soo [ACT Co. Ltd., Daejeon (Korea, Republic of); Park, Younwon; Song, Sub Lee [BEES Inc., Daejeon (Korea, Republic of); Kim, Hyeun Min [KAIST, Daejeon (Korea, Republic of)

    2016-10-15

    The integrity of storage facility and also of the spent nuclear fuel itself is considered very important. Storage casks can be located in a designated area on a site or in a designated storage building. A number of different designs for dry storage have been developed and used in different countries. Dry storage system was classified into two categories by IAEA. One is container including cask and silo, the other one is vault. However, there is various way of categorization for dry storage system. Dry silo and cask are usually classified separately, so the dry storage system can be classified into three different types. Furthermore, dry cask storage can be categorized into two types based on the type of the materials, concrete cask and metal cask. In this paper, the design characteristics of dry storage cask are introduced and computational fluid dynamics (CFD) based thermal analysis for concrete cask is revisited. Basic principles for dry storage cask design were described. Based on that, thermal analysis of concrete dry cask was introduced from the study of H. M. Kim et al. From the CFD calculation, the temperature of concrete wall was maintained under the safety criteria. From this fundamental analysis, further investigations are expected. For example, thermal analysis on the metal cask, thermal analysis on horizontally laid spent nuclear fuel assemblies for transportation concerns, and investigations on better performance of natural air circulation in dry cask can be promising candidates.

  11. Basic Considerations for Dry Storage of Spent Nuclear Fuels and Revisited CFD Thermal Analysis on the Concrete Cask

    International Nuclear Information System (INIS)

    Noh, Jae Soo; Park, Younwon; Song, Sub Lee; Kim, Hyeun Min

    2016-01-01

    The integrity of storage facility and also of the spent nuclear fuel itself is considered very important. Storage casks can be located in a designated area on a site or in a designated storage building. A number of different designs for dry storage have been developed and used in different countries. Dry storage system was classified into two categories by IAEA. One is container including cask and silo, the other one is vault. However, there is various way of categorization for dry storage system. Dry silo and cask are usually classified separately, so the dry storage system can be classified into three different types. Furthermore, dry cask storage can be categorized into two types based on the type of the materials, concrete cask and metal cask. In this paper, the design characteristics of dry storage cask are introduced and computational fluid dynamics (CFD) based thermal analysis for concrete cask is revisited. Basic principles for dry storage cask design were described. Based on that, thermal analysis of concrete dry cask was introduced from the study of H. M. Kim et al. From the CFD calculation, the temperature of concrete wall was maintained under the safety criteria. From this fundamental analysis, further investigations are expected. For example, thermal analysis on the metal cask, thermal analysis on horizontally laid spent nuclear fuel assemblies for transportation concerns, and investigations on better performance of natural air circulation in dry cask can be promising candidates

  12. Analysis of wall-packed-bed thermal interactions

    International Nuclear Information System (INIS)

    Gorbis, Z.R.; Tillack, M.S.; Tehranian, F.; Abdou, M.A.

    1995-01-01

    One of the major issues remaining for ceramic breeder blankets involves uncertainties in heat transfer and thermomechanical interactions within the breeder and multiplier regions. Particle bed forms are considered in many reactor blanket designs for both the breeder and Be multiplier. The effective thermal conductivity of beds and the wall-bed thermal conductance are still not adequately characterized, particularly under the influence of mechanical stresses. The problem is particularly serious for the wall conductance between Be and its cladding, where the uncertainty can be greater than 50%. In this work, we describe a new model for the wall-bed conductance that treats the near-wall region as a finite-width zone. The model includes an estimate of the region porosity based on the number of contact points, and the contact area for smooth surfaces. It solves the heat conduction in a near-wall unit cell. The model is verified with existing data and used to predict the range of wall conductances expected in future simulation experiments and in reactor applications. (orig.)

  13. Value and cost analyses for solar thermal-storage systems

    Energy Technology Data Exchange (ETDEWEB)

    Luft, W.; Copeland, R.J.

    1983-04-01

    Value and cost data for thermal energy storage are presented for solar thermal central receiver systems for which thermal energy storage appears to be attractive. Both solar thermal electric power and industrial process heat applications are evaluated. The value of storage is based on the cost for fossil fuel and solar thermal collector systems in 1990. The costing uses a standard lifetime methodology with the storage capacity as a parameter. Both value and costs are functions of storage capacity. However, the value function depends on the application. Value/cost analyses for first-generation storage concepts for five central receiver systems (molten salt, water/steam, organic fluid, air, and liquid metal) established the reference against which new systems were compared. Some promising second-generation energy storage concepts have been identified, and some more advanced concepts have also been evaluated.

  14. A review on energy conservation in building applications with thermal storage by latent heat using phase change materials

    International Nuclear Information System (INIS)

    Khudhair, Amar M.; Farid, Mohammed M.

    2004-01-01

    Energy storage in the walls, ceiling and floor of buildings may be enhanced by encapsulating suitable phase change materials (PCMs) within these surfaces to capture solar energy directly and increase human comfort by decreasing the frequency of internal air temperature swings and maintaining the temperature closer to the desired temperature for a longer period of time. This paper summarizes the investigation and analysis of thermal energy storage systems incorporating PCMs for use in building applications. Researches on thermal storage in which the PCM is encapsulated in concrete, gypsum wallboard, ceiling and floor have been ongoing for some time and are discussed. The problems associated with the application of PCMs with regard to the selection of materials and the methods used to contain them are also discussed

  15. Numerical study of finned heat pipe-assisted thermal energy storage system with high temperature phase change material

    International Nuclear Information System (INIS)

    Tiari, Saeed; Qiu, Songgang; Mahdavi, Mahboobe

    2015-01-01

    Highlights: • A finned heat pipe-assisted latent heat thermal energy storage system is studied. • The effects of heat pipes spacing and fins geometrical features are investigated. • Smaller heat pipes spacing and longer fins improve the melting rate. • The optimal heat pipe and fin arrangements are determined. - Abstract: In the present study, the thermal characteristics of a finned heat pipe-assisted latent heat thermal energy storage system are investigated numerically. A transient two-dimensional finite volume based model employing enthalpy-porosity technique is implemented to analyze the performance of a thermal energy storage unit with square container and high melting temperature phase change material. The effects of heat pipe spacing, fin length and numbers and the influence of natural convection on the thermal response of the thermal energy storage unit have been studied. The obtained results reveal that the natural convection has considerable effect on the melting process of the phase change material. Increasing the number of heat pipes (decreasing the heat pipe spacing) leads to the increase of melting rate and the decrease of base wall temperature. Also, the increase of fin length results in the decrease of temperature difference within the phase change material in the container, providing more uniform temperature distribution. It was also shown that number of the fins does not have a significant effect on the performance of the system

  16. Thermal Bridge Effects in Walls Separating Rowhouses

    DEFF Research Database (Denmark)

    Rose, Jørgen

    1997-01-01

    In this report the thermal bridge effects at internal wall/roof junctions in rowhouses are evaluated. The analysis is performed using a numerical calculation programme, and different solutions are evaluated with respect to extra heat loss and internal surface temperatures.......In this report the thermal bridge effects at internal wall/roof junctions in rowhouses are evaluated. The analysis is performed using a numerical calculation programme, and different solutions are evaluated with respect to extra heat loss and internal surface temperatures....

  17. Computational Fluid Dynamics Model for Solar Thermal Storage Tanks with Helical Jacket Heater and Upper Spiral Coil Heater

    Energy Technology Data Exchange (ETDEWEB)

    Baek, Seung Man [Seoul Nat' l Univ., Seoul (Korea, Republic of); Zhong, Yiming; Nam, Jin Hyun [Daegu Univ., Daegu (Korea, Republic of); Chung, Jae Dong [Sejong Univ., Seoul (Korea, Republic of); Hong, Hiki [Kyung Hee Univ., Seoul (Korea, Republic of)

    2013-04-15

    In a solar domestic hot water (Shadow) system, solar energy is collected using collector panels, transferred to a circulating heat transfer fluid (brine), and eventually stored in a thermal storage tank (Test) as hot water. In this study, a computational fluid dynamics (CAD) model was developed to predict the solar thermal energy storage in a hybrid type Test equipped with a helical jacket heater (mantle heat exchanger) and an immersed spiral coil heater. The helical jacket heater, which is the brine flow path attached to the side wall of a Test, has advantages including simple system design, low brine flow rate, and enhanced thermal stratification. In addition, the spiral coil heater further enhances the thermal performance and thermal stratification of the Test. The developed model was validated by the good agreement between the CAD results and the experimental results performed with the hybrid-type Test in Shadow settings.

  18. Computational Fluid Dynamics Model for Solar Thermal Storage Tanks with Helical Jacket Heater and Upper Spiral Coil Heater

    International Nuclear Information System (INIS)

    Baek, Seung Man; Zhong, Yiming; Nam, Jin Hyun; Chung, Jae Dong; Hong, Hiki

    2013-01-01

    In a solar domestic hot water (Shadow) system, solar energy is collected using collector panels, transferred to a circulating heat transfer fluid (brine), and eventually stored in a thermal storage tank (Test) as hot water. In this study, a computational fluid dynamics (CAD) model was developed to predict the solar thermal energy storage in a hybrid type Test equipped with a helical jacket heater (mantle heat exchanger) and an immersed spiral coil heater. The helical jacket heater, which is the brine flow path attached to the side wall of a Test, has advantages including simple system design, low brine flow rate, and enhanced thermal stratification. In addition, the spiral coil heater further enhances the thermal performance and thermal stratification of the Test. The developed model was validated by the good agreement between the CAD results and the experimental results performed with the hybrid-type Test in Shadow settings

  19. Electrically conductive carbon nanofiber/paraffin wax composites for electric thermal storage

    International Nuclear Information System (INIS)

    Zhang Kun; Han Baoguo; Yu Xun

    2012-01-01

    Highlights: ► Carbon nanofiber (CNF)/paraffin wax composite is found to be a promising electric thermal storage material. ► The thermal storage capacity of CNF/paraffin wax composite is five times of traditional electric thermal storage material. ► CNF is shown to be an effective conductive filler for the composite. - Abstract: The research of electric thermal storage (ETS) has attracted a lot of attention recently, which converts off-peak electrical energy into thermal energy and release it later at peak hours. In this study, new electric thermal storage composites are developed by employing paraffin wax as thermal storage media and carbon nanofiber (CNF) as conductive fillers. Electric heating and thermal energy release performances of the CNF/paraffin wax composites are experimentally investigated. Experimental results show that, when the composites are heated to about 70 °C, the developed electrically conductive CNF/paraffin wax composites present a thermal storage capacity of about 280 kJ/kg, which is five times of that of traditional thermal storage medium such as ceramic bricks (54 kJ/kg). The CNF/paraffin wax composites can also effectively store the thermal energy and release the thermal energy in later hours.

  20. Aquifer Thermal Energy Storage for Seasonal Thermal Energy Balance

    Science.gov (United States)

    Rostampour, Vahab; Bloemendal, Martin; Keviczky, Tamas

    2017-04-01

    Aquifer Thermal Energy Storage (ATES) systems allow storing large quantities of thermal energy in subsurface aquifers enabling significant energy savings and greenhouse gas reductions. This is achieved by injection and extraction of water into and from saturated underground aquifers, simultaneously. An ATES system consists of two wells and operates in a seasonal mode. One well is used for the storage of cold water, the other one for the storage of heat. In warm seasons, cold water is extracted from the cold well to provide cooling to a building. The temperature of the extracted cold water increases as it passes through the building climate control systems and then gets simultaneously, injected back into the warm well. This procedure is reversed during cold seasons where the flow direction is reversed such that the warmer water is extracted from the warm well to provide heating to a building. From the perspective of building climate comfort systems, an ATES system is considered as a seasonal storage system that can be a heat source or sink, or as a storage for thermal energy. This leads to an interesting and challenging optimal control problem of the building climate comfort system that can be used to develop a seasonal-based energy management strategy. In [1] we develop a control-oriented model to predict thermal energy balance in a building climate control system integrated with ATES. Such a model however cannot cope with off-nominal but realistic situations such as when the wells are completely depleted, or the start-up phase of newly installed wells, etc., leading to direct usage of aquifer ambient temperature. Building upon our previous work in [1], we here extend the mathematical model for ATES system to handle the above mentioned more realistic situations. Using our improved models, one can more precisely predict system behavior and apply optimal control strategies to manage the building climate comfort along with energy savings and greenhouse gas reductions

  1. Hydrogen storage by adsorption on activated carbon: investigation of the thermal effects during the charging process

    International Nuclear Information System (INIS)

    Hermosilla-Lara, G.

    2007-02-01

    This work presents an experimental and numerical investigation of the thermal effects occurring during the charge of adsorbent fixed bed tank. The influence of these thermal effects, which result from the exothermal character of the adsorption process and the pressure forces work, on the storage capacity is specially analysed. An experimental setup allowing the dynamic measurements of the temperature and pressure profiles has been used. Then the numerical protocol with the Fluent software, has been validated by comparison of the simulated pressure, flow rate and temperature fields in the tank with the results obtained from an experimental investigation carried out the dynamic storage. Several predictive simulations have been carried out in order to study the effect of the boundary conditions, as the wall temperature or effective thermal conductivity of the porous bed, on the storage capacity of the reservoir. We searched the optimal geometry of an interbed thermal dissipator for a given industrial tank. To do this we made vary the H/L ratio, which represents the ratio of the height of an elementary stage and the total length of the tank. We could determine an optimal geometry which corresponds to the value 1/3 of the ratio H/L. From this optimum we studied the effect of five additional cooling tubes on the tank storage capacity. The stored mass is 15 % higher than that obtained without these tubes. (author)

  2. Heat transfer efficient thermal energy storage for steam generation

    International Nuclear Information System (INIS)

    Adinberg, R.; Zvegilsky, D.; Epstein, M.

    2010-01-01

    A novel reflux heat transfer storage (RHTS) concept for producing high-temperature superheated steam in the temperature range 350-400 deg. C was developed and tested. The thermal storage medium is a metallic substance, Zinc-Tin alloy, which serves as the phase change material (PCM). A high-temperature heat transfer fluid (HTF) is added to the storage medium in order to enhance heat exchange within the storage system, which comprises PCM units and the associated heat exchangers serving for charging and discharging the storage. The applied heat transfer mechanism is based on the HTF reflux created by a combined evaporation-condensation process. It was shown that a PCM with a fraction of 70 wt.% Zn in the alloy (Zn70Sn30) is optimal to attain a storage temperature of 370 deg. C, provided the heat source such as solar-produced steam or solar-heated synthetic oil has a temperature of about 400 deg. C (typical for the parabolic troughs technology). This PCM melts gradually between temperatures 200 and 370 deg. C preserving the latent heat of fusion, mainly of the Zn-component, that later, at the stage of heat discharge, will be available for producing steam. The thermal storage concept was experimentally studied using a lab scale apparatus that enabled investigating of storage materials (the PCM-HTF system) simultaneously with carrying out thermal performance measurements and observing heat transfer effects occurring in the system. The tests produced satisfactory results in terms of thermal stability and compatibility of the utilized storage materials, alloy Zn70Sn30 and the eutectic mixture of biphenyl and diphenyl oxide, up to a working temperature of 400 deg. C. Optional schemes for integrating the developed thermal storage into a solar thermal electric plant are discussed and evaluated considering a pilot scale solar plant with thermal power output of 12 MW. The storage should enable uninterrupted operation of solar thermal electric systems during additional hours

  3. Thermal Analysis of Fluidized Bed and Fixed Bed Latent Heat Thermal Storage System

    Science.gov (United States)

    Beemkumar, N.; Karthikeyan, A.; Shiva Keshava Reddy, Kota; Rajesh, Kona; Anderson, A.

    2017-05-01

    Thermal energy storage technology is essential because its stores available energy at low cost. Objective of the work is to store the thermal energy in a most efficient method. This work is deal with thermal analysis of fluidized bed and fixed bed latent heat thermal storage (LHTS) system with different encapsulation materials (aluminium, brass and copper). D-Mannitol has been used as phase change material (PCM). Encapsulation material which is in orbicular shape with 4 inch diameter and 2 mm thickness orbicular shaped product is used. Therminol-66 is used as a heat transfer fluid (HTF). Arrangement of encapsulation material is done in two ways namely fluidized bed and fixed bed thermal storage system. Comparison was made between the performance of fixed bed and fluidized bed with different encapsulation material. It is observed that from the economical point of view aluminium in fluidized bed LHTS System has highest efficiency than copper and brass. The thermal energy storage system can be analyzed with fixed bed by varying mass flow rate of oil paves a way to find effective heat energy transfer.

  4. Thermal Insulating Concrete Wall Panel Design for Sustainable Built Environment

    Science.gov (United States)

    Zhou, Ao; Wong, Kwun-Wah

    2014-01-01

    Air-conditioning system plays a significant role in providing users a thermally comfortable indoor environment, which is a necessity in modern buildings. In order to save the vast energy consumed by air-conditioning system, the building envelopes in envelope-load dominated buildings should be well designed such that the unwanted heat gain and loss with environment can be minimized. In this paper, a new design of concrete wall panel that enhances thermal insulation of buildings by adding a gypsum layer inside concrete is presented. Experiments have been conducted for monitoring the temperature variation in both proposed sandwich wall panel and conventional concrete wall panel under a heat radiation source. For further understanding the thermal effect of such sandwich wall panel design from building scale, two three-story building models adopting different wall panel designs are constructed for evaluating the temperature distribution of entire buildings using finite element method. Both the experimental and simulation results have shown that the gypsum layer improves the thermal insulation performance by retarding the heat transfer across the building envelopes. PMID:25177718

  5. Parametric Investigation of Optimum Thermal Insulation Thickness for External Walls

    Directory of Open Access Journals (Sweden)

    Omer Kaynakli

    2011-06-01

    Full Text Available Numerous studies have estimated the optimum thickness of thermal insulation materials used in building walls for different climate conditions. The economic parameters (inflation rate, discount rate, lifetime and energy costs, the heating/cooling loads of the building, the wall structure and the properties of the insulation material all affect the optimum insulation thickness. This study focused on the investigation of these parameters that affect the optimum thermal insulation thickness for building walls. To determine the optimum thickness and payback period, an economic model based on life-cycle cost analysis was used. As a result, the optimum thermal insulation thickness increased with increasing the heating and cooling energy requirements, the lifetime of the building, the inflation rate, energy costs and thermal conductivity of insulation. However, the thickness decreased with increasing the discount rate, the insulation material cost, the total wall resistance, the coefficient of performance (COP of the cooling system and the solar radiation incident on a wall. In addition, the effects of these parameters on the total life-cycle cost, payback periods and energy savings were also investigated.

  6. Graphene Thermal Properties: Applications in Thermal Management and Energy Storage

    Directory of Open Access Journals (Sweden)

    Jackie D. Renteria

    2014-11-01

    Full Text Available We review the thermal properties of graphene, few-layer graphene and graphene nanoribbons, and discuss practical applications of graphene in thermal management and energy storage. The first part of the review describes the state-of-the-art in the graphene thermal field focusing on recently reported experimental and theoretical data for heat conduction in graphene and graphene nanoribbons. The effects of the sample size, shape, quality, strain distribution, isotope composition, and point-defect concentration are included in the summary. The second part of the review outlines thermal properties of graphene-enhanced phase change materials used in energy storage. It is shown that the use of liquid-phase-exfoliated graphene as filler material in phase change materials is promising for thermal management of high-power-density battery parks. The reported experimental and modeling results indicate that graphene has the potential to outperform metal nanoparticles, carbon nanotubes, and other carbon allotropes as filler in thermal management materials.

  7. Thermal dynamic simulation of wall for building energy efficiency under varied climate environment

    Science.gov (United States)

    Wang, Xuejin; Zhang, Yujin; Hong, Jing

    2017-08-01

    Aiming at different kind of walls in five cities of different zoning for thermal design, using thermal instantaneous response factors method, the author develops software to calculation air conditioning cooling load temperature, thermal response factors, and periodic response factors. On the basis of the data, the author gives the net work analysis about the influence of dynamic thermal of wall on air-conditioning load and thermal environment in building of different zoning for thermal design regional, and put forward the strategy how to design thermal insulation and heat preservation wall base on dynamic thermal characteristic of wall under different zoning for thermal design regional. And then provide the theory basis and the technical references for the further study on the heat preservation with the insulation are in the service of energy saving wall design. All-year thermal dynamic load simulating and energy consumption analysis for new energy-saving building is very important in building environment. This software will provide the referable scientific foundation for all-year new thermal dynamic load simulation, energy consumption analysis, building environment systems control, carrying through farther research on thermal particularity and general particularity evaluation for new energy -saving walls building. Based on which, we will not only expediently design system of building energy, but also analyze building energy consumption and carry through scientific energy management. The study will provide the referable scientific foundation for carrying through farther research on thermal particularity and general particularity evaluation for new energy saving walls building.

  8. LiH thermal energy storage device

    Science.gov (United States)

    Olszewski, M.; Morris, D.G.

    1994-06-28

    A thermal energy storage device for use in a pulsed power supply to store waste heat produced in a high-power burst operation utilizes lithium hydride as the phase change thermal energy storage material. The device includes an outer container encapsulating the lithium hydride and an inner container supporting a hydrogen sorbing sponge material such as activated carbon. The inner container is in communication with the interior of the outer container to receive hydrogen dissociated from the lithium hydride at elevated temperatures. 5 figures.

  9. Diurnal thermal analysis of microencapsulated PCM-concrete composite walls

    International Nuclear Information System (INIS)

    Thiele, Alexander M.; Sant, Gaurav; Pilon, Laurent

    2015-01-01

    Highlights: • Transient heat conduction across microencapsulated PCM-concrete walls was simulated. • Equivalent homogeneous wall with effective thermal properties was rigorously derived. • Adding PCM to the wall increases daily energy savings and delays peak thermal load. • Energy savings is maximum when PCM melting temperature equals indoor temperature. • Energy savings are limited in extreme climates but time delay can be large. - Abstract: This paper examines the benefits of adding microencapsulated phase change material (PCM) to concrete used in building envelopes to reduce energy consumption and costs. First, it establishes that the time-dependent thermal behavior of microencapsulated PCM-concrete composite walls can be accurately predicted by an equivalent homogeneous wall with appropriate effective thermal properties. The results demonstrate that adding microencapsulated PCM to concrete resulted in a reduction and a time-shift in the maximum heat flux through the composite wall subjected to diurnal sinusoidal outdoor temperature and solar radiation heat flux. The effects of the PCM volume fraction, latent heat of fusion, phase change temperature and temperature window, and outdoor temperature were evaluated. Several design rules were established including (i) increasing the PCM volume fraction and/or enthalpy of phase change increased the energy flux reduction and the time delay, (ii) the energy flux reduction was maximized when the PCM phase change temperature was close to the desired indoor temperature, (iii) the optimum phase change temperature to maximize the time delay increased with increasing average outdoor temperature, (iv) in extremely hot or cold climates, the thermal load could be delayed even though the reduction in daily energy flux was small, and (v) the choice of phase change temperature window had little effect on the energy flux reduction and on the time delay. This analysis can serve as a framework to design PCM composite walls

  10. Buffer thermal energy storage for a solar Brayton engine

    Science.gov (United States)

    Strumpf, H. J.; Barr, K. P.

    1981-01-01

    A study has been completed on the application of latent-heat buffer thermal energy storage to a point-focusing solar receiver equipped with an air Brayton engine. To aid in the study, a computer program was written for complete transient/stead-state Brayton cycle performance. The results indicated that thermal storage can afford a significant decrease in the number of engine shutdowns as compared to operating without thermal storage. However, the number of shutdowns does not continuously decrease as the storage material weight increases. In fact, there appears to be an optimum weight for minimizing the number of shutdowns.

  11. Hydrogen storage in carbon nanostruc

    NARCIS (Netherlands)

    Hirscher, M.; Becher, M.; Haluska, M.; Quintel, A.; Skakalova, V.; Choi, M.; Dettlaff-Weglikowska, U.; Roth, S.; Stepanek, I.; Bernier, P.; Leonhardt, A.; Fink, J.

    2002-01-01

    The paper gives a critical review of the literature on hydrogen storage in carbon nanostructures. Furthermore, the hydrogen storage of graphite, graphite nanofibers (GNFs), and single-walled carbon nanotubes (SWNTs) was measured by thermal desorption spectroscopy (TDS). The samples were ball milled

  12. [Study on Hollow Brick Wall's Surface Temperature with Infrared Thermal Imaging Method].

    Science.gov (United States)

    Tang, Ming-fang; Yin, Yi-hua

    2015-05-01

    To address the characteristic of uneven surface temperature of hollow brick wall, the present research adopts soft wares of both ThermaCAM P20 and ThermaCAM Reporter to test the application of infrared thermal image technique in measuring surface temperature of hollow brick wall, and further analyzes the thermal characteristics of hollow brick wall, and building material's impact on surface temperature distribution including hollow brick, masonry mortar, and so on. The research selects the construction site of a three-story-high residential, carries out the heat transfer experiment, and further examines the exterior wall constructed by 3 different hollow bricks including sintering shale hollow brick, masonry mortar and brick masonry. Infrared thermal image maps are collected, including 3 kinds of sintering shale hollow brick walls under indoor heating in winter; and temperature data of wall surface, and uniformity and frequency distribution are also collected for comparative analysis between 2 hollow bricks and 2 kinds of mortar masonry. The results show that improving heat preservation of hollow brick aid masonry mortar can effectively improve inner wall surface temperature and indoor thermal environment; non-uniformity of surface temperature decreases from 0. 6 to 0. 4 °C , and surface temperature frequency distribution changes from the asymmetric distribution into a normal distribution under the condition that energy-saving sintering shale hollow brick wall is constructed by thermal mortar replacing cement mortar masonry; frequency of average temperature increases as uniformity of surface temperature increases. This research provides a certain basis for promotion and optimization of hollow brick wall's thermal function.

  13. A comparison between CFD simulation and experimental investigation of a packed-bed thermal energy storage system

    International Nuclear Information System (INIS)

    Cascetta, Mario; Cau, Giorgio; Puddu, Pierpaolo; Serra, Fabio

    2016-01-01

    Highlights: • Thermocline formation inside a sensible type packed bed during a complete cycle. • Thermal properties of both phases must be temperature-dependent in the simulation. • Bed porosity increases from the center to the container wall. • Thermal dispersion and solid conduction must be considered in the model. • The wall influences the radial temperature profile and the amount of energy stored. - Abstract: This work presents the comparison between CFD and experimental results obtained on a sensible thermal energy storage system based on alumina beads freely poured into a carbon steel tank. Experimental investigations of charging and discharging phases were carried out at a constant mass flow rate using air as heat transfer fluid. The experimental set-up was instrumented with several thermocouples to detect axial and radial temperature distribution as well as reservoir wall temperature. The experimental results were compared with those obtained from CFD simulations carried out with the FLUENT software. The computational domain consists of an axisymmetric tank of cylindrical shape filled with a porous bed coupled with the wall. The governing equations are solved for incompressible turbulent flow and fully developed forced convection, based on the two-phase transient model equation (LTNE-local thermal non-equilibrium) to calculate the temperature of fluid and solid phases. The porosity of the bed is considered variable in the radial direction, while the thermodynamic properties of both phases are temperature-dependent. The influence of the thermal dispersion within the porous bed, as well as the effective conductivity between the beads was considered. The heat transfer coefficient was calculated according to correlation for forced convection within porous media. Numerical results show a good agreement with experimental ones if thermal properties are considered temperature-dependent and the experimental temperature profile at the inlet of the bed is

  14. Thermal Analysis Evaluation of Spent Fuel Storage Rack for Research Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Sangjin; Oh, Jinho; Kwak, Jinsung; Lee, Jongmin [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2016-10-15

    Spent fuel storage rack is to store spent fuel assemblies. The spent fuel storage rack is submerged in the designated pool for cooling. Due to the condition change of the pool water, the effect of thermal load on spent fuel storage rack must be analyzed and evaluated. In this paper, thermal stress analysis is performed and evaluated on a spent fuel storage rack. For thermal stress evaluation of the spent fuel storage rack, load combinations and allowable criteria in ASME Sec. III NB-3220 are applied. In cases of A-1 and B-1, the same temperature applied on the whole model, thermal stress doesn't occur because there is no constraint about the thermal expansion. The support frame is located on the pool bottom in free standing type and the racks are located in the support frame with enough space. Thermal expansion was considered and reflected in the design of spent fuel storage rack in advance. Thermal stress analysis is performed and evaluated on a spent fuel storage rack with consideration of pool water temperature variation. The thermal analysis including a linear heat transfer and the thermal stress analysis is performed for the racks and support frame and resulted stresses are within allowable criteria.

  15. Performance analysis of a lunar based solar thermal power system with regolith thermal storage

    International Nuclear Information System (INIS)

    Lu, Xiaochen; Ma, Rong; Wang, Chao; Yao, Wei

    2016-01-01

    The manned deep-space exploration is a hot topic of the current space activities. The continuous supply of thermal and electrical energy for the scientific equipment and human beings is a crucial issue for the lunar outposts. Since the night lasts for periods of about 350 h at most locations on the lunar surface, massive energy storage is required for continuous energy supply during the lengthy lunar night and the in-situ resource utilization is demanded. A lunar based solar thermal power system with regolith thermal storage is presented in this paper. The performance analysis is carried out by the finite-time thermodynamics to take into account major irreversible losses. The influences of some key design parameters are analyzed for system optimization. The analytical results shows that the lunar based solar thermal power system with regolith thermal storage can meet the requirement of the continuous energy supply for lunar outposts. - Highlights: • A lunar based solar thermal power system with regolith thermal storage is presented. • The performance analysis is carried out by the finite-time thermodynamics. • The influences of some key design parameters are analyzed.

  16. Heat transfer of pulsating laminar flow in pipes with wall thermal inertia

    International Nuclear Information System (INIS)

    Yuan, Hongsheng; Tan, Sichao; Wen, Jing; Zhuang, Nailiang

    2016-01-01

    The effects of wall thermal inertia on heat transfer of pulsating laminar flow with constant power density within the pipe wall are investigated theoretically. The energy equation of the fully developed flow and heat transfer is solved by separation of variables and Green's function. The effects of the pulsation amplitude and frequency, the Prandtl number and the wall heat capacity on heat transfer features characterized by temperature, heat flux and Nusselt number are analyzed. The results show that the oscillation of wall heat flux increases along with the wall thermal inertia, while the oscillation of temperature and Nusselt number is suppressed by the wall thermal inertia. The influence of pulsation on the average Nusselt number is also obtained. The pulsating laminar flow can reduce the average Nusselt number. The Nusselt number reduction of pipe flow are a little more remarkable than that of flow between parallel plates, which is mainly caused by differences in hydraulic and thermal performances of the channels. (authors)

  17. Buffer thermal energy storage for an air Brayton solar engine

    Science.gov (United States)

    Strumpf, H. J.; Barr, K. P.

    1981-01-01

    The application of latent-heat buffer thermal energy storage to a point-focusing solar receiver equipped with an air Brayton engine was studied. To demonstrate the effect of buffer thermal energy storage on engine operation, a computer program was written which models the recuperator, receiver, and thermal storage device as finite-element thermal masses. Actual operating or predicted performance data are used for all components, including the rotating equipment. Based on insolation input and a specified control scheme, the program predicts the Brayton engine operation, including flows, temperatures, and pressures for the various components, along with the engine output power. An economic parametric study indicates that the economic viability of buffer thermal energy storage is largely a function of the achievable engine life.

  18. Thermal energy storage for solar power generation - State of the art

    Science.gov (United States)

    Shukla, K. N.

    1981-12-01

    High temperature storage for applications in solar-thermal electric systems is considered. Noting that thermal storage is in either the form of latent, sensible or chemically stored heat, sensible heat storage is stressed as the most developed of the thermal storage technologies, spanning direct heating of a storage medium from 120-1250 C. Current methods involve solids, packed beds, fluidized beds, liquids, hot water, organic liquids, and inorganic liquids and molten salts. Latent heat storage comprises phase-change materials that move from solid to liquid with addition of heat and liquid to solid with the removal of heat. Metals or inorganic salts are candidates, and the energy balances are outlined. Finally, chemical heat storage is examined, showing possible high energy densities through catalytic, thermal dissociation reactions.

  19. Survey of solar thermal energy storage subsystems for thermal/electric applications

    Energy Technology Data Exchange (ETDEWEB)

    Segaser, C. L.

    1978-08-01

    A survey of the current technology and estimated costs of subsystems for storing the thermal energy produced by solar collectors is presented. The systems considered were capable of producing both electricity and space conditioning for three types of loads: a single-family detached residence, an apartment complex of 100 units, and a city of 30,000 residents, containing both single-family residences and apartments. Collector temperatures will be in four ranges: (1) 100 to 250/sup 0/F (used for space heating and single-cycle air conditioners and organic Rankine low-temperature turbines); (2) 300 to 400/sup 0/F (used for dual-cycle air conditioners and low-temperature turbines); (3) 400 to 600/sup 0/F (using fluids from parabolic trough collectors to run Rankine turbines); (4) 800 to 1000/sup 0/F (using fluids from heliostats to run closed-cycle gas turbines and steam Rankine turbines). The solar thermal energy subsystems will require from 60 to 36 x 10/sup 5/ kWhr (2.05 x 10/sup 5/ to 1.23 x 10/sup 10/ Btu) of thermal storage capacity. In addition to sensible heat and latent heat storage materials, several other media were investigated as potential thermal energy storage materials, including the clathrate and semiclathrate hydrates, various metal hydrides, and heat storage based on inorganic chemical reactions.

  20. Thermal Performance of the Storage Brick Containing Microencapsulated PCM

    International Nuclear Information System (INIS)

    Lee, Dong Gyu

    1998-02-01

    The utilization of microencapsulated phase change materials(PCMs) provides several advantages over conventional PCM application. The heat storage system, as well as heat recovery system, can be built to a smaller size than the normal systems for a given thermal cycling capacity. This microencapsulated PCM technique has not yet been commercialized, however. In this work sodium acetate trihydrate(CH 3 COONa · 3H 2 O) was selected for the PCM and was encapsulated. This microencapsulated PCM was mixed with cement mortar for utilization as a floor heating system. In this experiment performed here the main purpose was to investigate the thermal performance of a storage brick with microencapsulated PCM concentration. The thermal performance of this storage brick is dependent on PCM concentration, flow rate and cooling temperature of the heat transfer fluid, etc. The results showed that cycle time was shortened as the PCM content was increased and as the mass flow rate was increased. The same effect was obtained when the cooling temperature was decreased. For each thermal storage brick the overall heat transfer coefficient(U-value) was constant for a 0% brick, but was increased with time for the bricks containing microencapsulated PCM. For the same mass flow rate, as the cooling temperature decreased, the amount of heat withdrawn increased, and in particular a critical cooling temperature was found for each thermal storage brick. The average effectiveness of each thermal storage brick was found to be approximately 48%, 51% and 58% respectively

  1. Thermal stress and creep fatigue limitations in first wall design

    International Nuclear Information System (INIS)

    Majumdar, S.; Misra, B.; Harkness, S.D.

    1977-01-01

    The thermal-hydraulic performance of a lithium cooled cylindrical first wall module has been analyzed as a function of the incident neutron wall loading. Three criteria were established for the purpose of defining the maximum wall loading allowable for modules constructed of Type 316 stainless steel and a vanadium alloy. Of the three, the maximum structural temperature criterion of 750 0 C for vanadium resulted in the limiting wall loading value of 7 MW/m 2 . The second criterion limited thermal stress levels to the yield strength of the alloy. This led to the lowest wall loading value for the Type 316 stainless steel wall (1.7 MW/m 2 ). The third criterion required that the creep-fatigue characteristics of the module allow a lifetime of 10 MW-yr/m 2 . At wall temperatures of 600 0 C, this lifetime could be achieved in a stainless steel module for wall loadings less than 3.2 MW/m 2 , while the same lifetime could be achieved for much higher wall loadings in a vanadium module

  2. Evaluation of thermal energy storage materials for advanced compressed air energy storage systems

    Energy Technology Data Exchange (ETDEWEB)

    Zaloudek, F.R.; Wheeler, K.R.; Marksberry, L.

    1983-03-01

    Advanced Compressed-Air Energy Storage (ACAS) plants have the near-term potential to reduce the fuel consumption of compressed-air plants from 33 to 100%, depending upon their design. Fuel is saved by storing some or all of the heat of compression as sensible heat which is subsequently used to reheat the compressed air prior to expansion in the turbine generator. The thermal storage media required for this application must be low cost and durable. The objective of this project was to screen thermal store materials based on their thermal cycle durability, particulate formation and corrosion resistant characteristics. The materials investigated were iron oxide pellets, Denstone pebbles, cast-iron balls, and Dresser basalt rock. The study specifically addressed the problems of particle formation and thermal ratcheting of the materials during thermal cycling and the chemical attack on the materials by the high temperature and moist environment in an ACAS heat storage bed. The results indicate that from the durability standpoint Denstone, cast iron containing 27% or more chromium, and crushed Dresser basalt would possibly stand up to ACAS conditions. If costs are considered in addition to durability and performance, the crushed Dresser basalt would probably be the most desirable heat storage material for adiabatic and hybrid ACAS plants, and more in-depth longer term thermal cycling and materials testing of Dresser basalt is recommended. Also recommended is the redesign and costing analysis of both the hybrid and adiabatic ACAS facilities based upon the use of Dresser basalt as the thermal store material.

  3. Investigation of the Effective Thermal Conductivity in Containment Wall of OPR1000

    Energy Technology Data Exchange (ETDEWEB)

    Noh, Hyung Gyun [Pohang University, Pohang (Korea, Republic of); Lee, Jong Hwi; Kang, Hie Chan [Kunsan National University, Gunsan (Korea, Republic of)

    2016-05-15

    Many computational codes used for analyzing pressure of containment was developed such as CAP (Containment Analysis Package). These computational codes consider concrete conductivity instead of thermal conductivity of containment wall which have special geometry as heat sink. For precise analysis, effective thermal conductivity of containment wall has to be measured in individual NPPs. Thermal properties of concrete such as thermal conductivity have been investigated as function of chemical composition and temperature. Generally, containment of OPR1000 is constructed by Prestressed (PS) concrete-a composite material. Containment wall of OPR1000 is made up of steel liner, tendon, rebar and concrete as shown in Figure 1. Role of steel liner protects release of radioactive materials so called leak tightness. The effective thermal conductivity of containment wall in OPR1000 is analyzed by numerical tool (CFD) and compared with thermal conductivity models in composite solids. The effective thermal conductivity of containment wall of OPR1000 is investigated by numerical analysis (CFD). The thermal conductivity of reinforced concrete is 18.6% higher than that of concrete only. Several models were compared with CFD results. Rayleigh-Parallel liner model agrees well with CFD results. Experiment results will be compared with CFD result and models. CFD result was calculated in low steel volume fraction (0.0809) than that of OPR1000 (0.1043). The effective thermal conductivity in OPR1000 has slightly higher than CFD result because of different volume fraction.

  4. Research opportunities in salt hydrates for thermal energy storage

    Science.gov (United States)

    Braunstein, J.

    1983-11-01

    The state of the art of salt hydrates as phase change materials for low temperature thermal energy storage is reviewed. Phase equilibria, nucleation behavior and melting kinetics of the commonly used hydrate are summarized. The development of efficient, reliable inexpensive systems based on phase change materials, especially salt hydrates for the storage (and retrieval) of thermal energy for residential heating is outlined. The use of phase change material thermal energy storage systems is not yet widespread. Additional basic research is needed in the areas of crystallization and melting kinetics, prediction of phase behavior in ternary systems, thermal diffusion in salt hydrate systems, and in the physical properties pertinent to nonequilibrium and equilibrium transformations in these systems.

  5. Thermodynamic analysis of pumped thermal electricity storage

    International Nuclear Information System (INIS)

    White, Alexander; Parks, Geoff; Markides, Christos N.

    2013-01-01

    The increasing use of renewable energy technologies for electricity generation, many of which have an unpredictably intermittent nature, will inevitably lead to a greater need for electricity storage. Although there are many existing and emerging storage technologies, most have limitations in terms of geographical constraints, high capital cost or low cycle life, and few are of sufficient scale (in terms of both power and storage capacity) for integration at the transmission and distribution levels. This paper is concerned with a relatively new concept which will be referred to here as Pumped Thermal Electricity Storage (PTES), and which may be able to make a significant contribution towards future storage needs. During charge, PTES makes use of a high temperature ratio heat pump to convert electrical energy into thermal energy which is stored as ‘sensible heat’ in two thermal reservoirs, one hot and one cold. When required, the thermal energy is then converted back to electricity by effectively running the heat pump backwards as a heat engine. The paper focuses on thermodynamic aspects of PTES, including energy and power density, and the various sources of irreversibility and their impact on round-trip efficiency. It is shown that, for given compression and expansion efficiencies, the cycle performance is controlled chiefly by the ratio between the highest and lowest temperatures in each reservoir rather than by the cycle pressure ratio. The sensitivity of round-trip efficiency to various loss parameters has been analysed and indicates particular susceptibility to compression and expansion irreversibility

  6. Myo-inositol based nano-PCM for solar thermal energy storage

    International Nuclear Information System (INIS)

    Singh, D.K.; Suresh, S.; Singh, H.; Rose, B.A.J.; Tassou, S.; Anantharaman, N.

    2017-01-01

    Highlights: • Properties of Myo-Inositol laden with Al_2O_3 and CuO nanoparticles was studied. • The melting point was found to increase for MI-A and decrease for MI-C. • MI interacted only physically on addition of NPs. • Mass changes were <3% after thermal cycling of MI-A and MI-C. • MI-A is more suited for thermal energy storage than MI-C. - Abstract: The thermo-physical behavior of Myo-Inositol (MI), (a sugar alcohol), was investigated as a potential material for developing more compact solar thermal energy storage systems than those currently available. This latent heat storage medium could be utilized for commercial and industrial applications using solar thermal energy storage in the temperature range of 160–260 °C, if its thermal performance was modified. The objective of this investigation was to determine via experimentation, if Al_2O_3 and CuO nanoparticles dispersed in pure MI for mixtures of 1, 2 and 3% (by weight) improved the thermal performance of MI for solar thermal energy systems. Nanoparticles only physically interacted with MI, and not chemically, even after 50 thermal cycles. The distribution of CuO nanoparticles in the nano-PCM was found to be more uniform than alumina nanoparticles. After cycling, nano-MIs studied here suffered a lower decrease in heat of fusion than pure MI, which makes nano-MIs more suitable for solar thermal storage applications at 160–260 °C. Between CuO and Al_2O_3 nanoparticles, latter was found to be more suitable for compact solar thermal energy storage owing to an increase in melting point observed.

  7. Solid state phase change materials for thermal energy storage in passive solar heated buildings

    Science.gov (United States)

    Benson, D. K.; Christensen, C.

    1983-11-01

    A set of solid state phase change materials was evaluated for possible use in passive solar thermal energy storage systems. The most promising materials are organic solid solutions of pentaerythritol, pentaglycerine and neopentyl glycol. Solid solution mixtures of these compounds can be tailored so that they exhibit solid-to-solid phase transformations at any desired temperature within the range from less than 25 deg to 188 deg. Thermophysical properties such as thermal conductivity, density and volumetric expansion were measured. Computer simulations were used to predict the performance of various Trombe wall designs incorporating solid state phase change materials. Optimum performance was found to be sensitive to the choice of phase change temperatures and to the thermal conductivity of the phase change material. A molecular mechanism of the solid state phase transition is proposed and supported by infrared spectroscopic evidence.

  8. First wall thermal--mechanical analyses of the reference theta-pinch reactor

    International Nuclear Information System (INIS)

    Krakowski, R.A.; Hagenson, R.L.; Cort, G.E.

    1977-01-01

    The thermal-mechanical response of the Reference Theta-Pinch Reactor (RTPR) first wall was analyzed. The first wall problems anticipated for a pulsed, high-β fusion power plant can be ameliorated by either alterations in the physics operating point, materials reengineering, or blanket/first wall reconfiguration. Within the latter ''configuration'' scenario, a two-fold approach has been adopted for the thermal-mechanical portion of the RTPR first wall technology assessment. First, a number of new first wall configurations (bonded or unbonded laminated composites, all-ceramic structures, protective and/or sacrificial ''bumpers'') were considered. Second, a more quantitative failure criterion, based on the developing theories of fracture mechanics, was identified. For each first wall configuration, transient heat transfer and thermoelastic stress calculations have been made. Two-dimensional finite element structural analyses have been made for a variety of mechanical boundary conditions. Only the Al 2 O 3 /Nb - 1 Zr system has been considered. The results of this study indicated a wide range of design solutions to the pulsed thermal stress problem anticipated for the RTPR

  9. Thermal energy storage in rock chambers - a complement to nuclear power

    International Nuclear Information System (INIS)

    Margen, P.H.

    1971-01-01

    Within about a decade from now, the nuclear capacity on several generation systems will have become larger than the night load, thus increasing the incentive to exploit cheap night energy for daily storage schemes. In Sweden, energy storage schemes using rock cavities have been studied for a number of years. These include pumped storage schemes with lower magazines well below ground surface and gas turbine schemes with compressed air magazines. Recently preliminary studies have been made of a third form - that of storing hot high pressure water in rock cavities with a simple thermal insulation. One method of utilizing this water is as feed water for a nuclear power station, the water in the store being heated from about 73 ° C to 21 7°C at night, and the stored hot water being fed directly to the Nuclear Steam Supply System (NSSS) during the day. An increase in turbine output by about 25% can then be achieved at peak periods due to the elimination of the h.p. steam bleeding for unchanged reactor power. About 35 kWh of electricity can be recovered per m 3 of storage volume, i.e. 30 times as much as if one m 3 of cold water had been allowed to descend 450 m under gravity to the lower magazine of a pumped storage plant. This illustrates how much more effective hot water storage utilizes the space of a rock cavity than does cold water storage for a pumped storage plant even at very great depths. The paper describes the circuit proposed and the design of the accumulator to meet the requirements concerning thermal insulation (to avoid exposing the rock walls to daily temperature cycles), avoidance of risk of leakage of slightly active feed water to the surrounding ground water even under severe accident conditions such as pipe and tank ruptures, and water chemistry to avoid water containing impurities or dissolved gases from reaching the feed water circuit. A preliminary cost analysis is given which shows that the proposal allows the generation of additional blocks of

  10. Thermal-hydraulic analysis of spent fuel storage systems

    International Nuclear Information System (INIS)

    Rector, D.R.; Wheeler, C.L.; Lombardo, N.J.

    1987-01-01

    This paper describes the COBRA-SFS (Spent Fuel Storage) computer code, which is designed to predict flow and temperature distributions in spent nuclear fuel storage and transportation systems. The decay heat generated by spent fuel in a dry storage cask is removed through a combination of conduction, natural convection, and thermal radiation. One major advantage of COBRA-SFS is that fluid recirculation within the cask is computed directly by solving the mass and momentum conservation equations. In addition, thermal radiation heat transfer is modeled using detailed radiation exchange factors based on quarter-rod segments. The equations governing mass, momentum, and energy conservation for incompressible flows are presented, and the semi-implicit solution method is described. COBRA-SFS predictions are compared to temperature data from a spent fuel storage cask test and the effect of different fill media on the cladding temperature distribution is discussed. The effect of spent fuel consolidation on cask thermal performance is also investigated. 16 refs., 6 figs., 2 tabs

  11. Thermal effect on transverse vibrations of double-walled carbon nanotubes

    International Nuclear Information System (INIS)

    Zhang, Y Q; Liu, X; Liu, G R

    2007-01-01

    Based on the theory of thermal elasticity mechanics, a double-elastic beam model is developed for transverse vibrations of double-walled carbon nanotubes with large aspect ratios. The thermal effect is incorporated in the formulation. With this double-elastic beam model, explicit expressions are derived for natural frequencies and associated amplitude ratios of the inner to the outer tubes for the case of simply supported double-walled carbon nanotubes. The influence of temperature change on the properties of transverse vibrations is discussed. It is demonstrated that some properties of transverse vibrations of double-walled carbon nanotubes are dependent on the change of temperature

  12. Gas storage carbon with enhanced thermal conductivity

    Science.gov (United States)

    Burchell, Timothy D.; Rogers, Michael Ray; Judkins, Roddie R.

    2000-01-01

    A carbon fiber carbon matrix hybrid adsorbent monolith with enhanced thermal conductivity for storing and releasing gas through adsorption and desorption is disclosed. The heat of adsorption of the gas species being adsorbed is sufficiently large to cause hybrid monolith heating during adsorption and hybrid monolith cooling during desorption which significantly reduces the storage capacity of the hybrid monolith, or efficiency and economics of a gas separation process. The extent of this phenomenon depends, to a large extent, on the thermal conductivity of the adsorbent hybrid monolith. This invention is a hybrid version of a carbon fiber monolith, which offers significant enhancements to thermal conductivity and potential for improved gas separation and storage systems.

  13. Parametric studies and optimisation of pumped thermal electricity storage

    International Nuclear Information System (INIS)

    McTigue, Joshua D.; White, Alexander J.; Markides, Christos N.

    2015-01-01

    Highlights: • PTES is modelled by cycle analysis and a Schumann-style model of the thermal stores. • Optimised trade-off surfaces show a flat efficiency vs. energy density profile. • Overall roundtrip efficiencies of around 70% are not inconceivable. - Abstract: Several of the emerging technologies for electricity storage are based on some form of thermal energy storage (TES). Examples include liquid air energy storage, pumped heat energy storage and, at least in part, advanced adiabatic compressed air energy storage. Compared to other large-scale storage methods, TES benefits from relatively high energy densities, which should translate into a low cost per MW h of storage capacity and a small installation footprint. TES is also free from the geographic constraints that apply to hydro storage schemes. TES concepts for electricity storage rely on either a heat pump or refrigeration cycle during the charging phase to create a hot or a cold storage space (the thermal stores), or in some cases both. During discharge, the thermal stores are depleted by reversing the cycle such that it acts as a heat engine. The present paper is concerned with a form of TES that has both hot and cold packed-bed thermal stores, and for which the heat pump and heat engine are based on a reciprocating Joule cycle, with argon as the working fluid. A thermodynamic analysis is presented based on traditional cycle calculations coupled with a Schumann-style model of the packed beds. Particular attention is paid to the various loss-generating mechanisms and their effect on roundtrip efficiency and storage density. A parametric study is first presented that examines the sensitivity of results to assumed values of the various loss factors and demonstrates the rather complex influence of the numerous design variables. Results of an optimisation study are then given in the form of trade-off surfaces for roundtrip efficiency, energy density and power density. The optimised designs show a

  14. Thermal energy storage for smart grid applications

    Science.gov (United States)

    Al-Hallaj, Said; Khateeb, Siddique; Aljehani, Ahmed; Pintar, Mike

    2018-01-01

    Energy consumption for commercial building cooling accounts for 15% of all commercial building's electricity usage [1]. Electric utility companies charge their customers time of use consumption charges (/kWh) and additionally demand usage charges (/kW) to limit peak energy consumption and offset their high operating costs. Thus, there is an economic incentive to reduce both the electricity consumption charges and demand charges by developing new energy efficient technologies. Thermal energy storage (TES) systems using a phase change material (PCM) is one such technology that can reduce demand charges and shift the demand from on-peak to off-peak rates. Ice and chilled water have been used in thermal storage systems for many decades, but they have certain limitations, which include a phase change temperature of 0 degrees Celsius and relatively low thermal conductivity in comparison to other materials, which limit their applications as a storage medium. To overcome these limitations, a novel phase change composite (PCC) TES material was developed that has much higher thermal conductivity that significantly improves the charge / discharge rate and a customizable phase change temperature to allow for better integration with HVAC systems. Compared to ice storage, the PCC TES system is capable of very high heat transfer rate and has lower system and operational costs. Economic analysis was performed to compare the PCC TES system with ice system and favorable economics was proven. A 4.5 kWh PCC TES prototype system was also designed for testing and validation purpose.

  15. The electrostatic properties of Fiber-Reinforced-Plastics double wall underground storage gasoline tanks

    International Nuclear Information System (INIS)

    Li, Yipeng; Liu, Quanzhen; Meng, He; Sun, Lifu; Zhang, Yunpeng

    2013-01-01

    At present Fiber Reinforced Plastics (FRP) double wall underground storage gasoline tanks are wildly used. An FRP product with a resistance of more than 10 11 Ω is a static non-conductor, so it is difficult for the static electricity in the FRP product to decay into the earth. In this paper an experimental system was built to simulate an automobile gasoline filling station. Some electrostatic parameters of the gasoline, including volume charge density, were tested when gasoline was unloaded into a FRP double wall underground storage tank. Measurements were taken to make sure the volume charge density in the oil-outlet was similar to the volume charge density in the tank. In most cases the volume charge density of the gasoline was more than 22.7 μC m −3 , which is likely to cause electrostatic discharge in FRP double wall underground storage gasoline tanks. On the other hand, it would be hard to ignite the vapor by electrostatic discharge since the vapor pressure in the tanks is over the explosion limit. But when the tank is repaired or re-used, the operators must pay attention to the static electricity and some measurements should be taken to avoid electrostatic accident. Besides the relaxation time of charge in the FRP double wall gasoline storage tanks should be longer.

  16. Space Station thermal storage/refrigeration system research and development

    Science.gov (United States)

    Dean, W. G.; Karu, Z. S.

    1993-01-01

    Space Station thermal loading conditions represent an order of magnitude increase over current and previous spacecraft such as Skylab, Apollo, Pegasus III, Lunar Rover Vehicle, and Lockheed TRIDENT missiles. Thermal storage units (TSU's) were successfully used on these as well as many applications for ground based solar energy storage applications. It is desirable to store thermal energy during peak loading conditions as an alternative to providing increased radiator surface area which adds to the weight of the system. Basically, TSU's store heat by melting a phase change material (PCM) such as a paraffin. The physical property data for the PCM's used in the design of these TSU's is well defined in the literature. Design techniques are generally well established for the TSU's. However, the Space Station provides a new challenge in the application of these data and techniques because of three factors: the large size of the TSU required, the integration of the TSU for the Space Station thermal management concept with its diverse opportunities for storage application, and the TSU's interface with a two-phase (liquid/vapor) thermal bus/central heat rejection system. The objective in the thermal storage research and development task was to design, fabricate, and test a demonstration unit. One test article was to be a passive thermal storage unit capable of storing frozen food at -20 F for a minimum of 90 days. A second unit was to be capable of storing frozen biological samples at -94 F, again for a minimum of 90 days. The articles developed were compatible with shuttle mission conditions, including safety and handling by astronauts. Further, storage rack concepts were presented so that these units can be integrated into Space Station logistics module storage racks. The extreme sensitivity of spacecraft radiator systems design-to-heat rejection temperature requirements is well known. A large radiator area penalty is incurred if low temperatures are accommodated via a

  17. Climate Chamber Experiment-Based Thermal Analysis and Design Improvement of Traditional Huizhou Masonry Walls

    Directory of Open Access Journals (Sweden)

    Ling Dong

    2018-03-01

    Full Text Available Supported by thousands of years of history, traditional Huizhou buildings have played a vital role, both functionally and culturally, as residential buildings in China. Masonry walls are one of the key building components of a Huizhou building; however, the traditional Huizhou masonry wall structure, predominantly a hollow brick structure, cannot meet the local building energy code requirements, and thus needs to be improved. Within this context, the present research measures the actual thermal performance of traditional Huizhou masonry walls for historical buildings and new-built buildings, which results in mean thermal transmittances of 1.892 W/m2·K and 2.821 W/m2·K, respectively, while the local building energy code requires a minimum thermal transmittance of 1.500 W/m2·K. In order to improve the thermal performance of traditional Huizhou masonry walls, four design scenarios for wall insulation are proposed and tested in a climate chamber: (1 hollow brick wall with inorganic interior insulation mortar, (2 solid brick wall with inorganic interior insulation mortar, (3 hollow brick wall with foamed concrete, and (4 hollow brick wall with foamed concrete plus inorganic interior insulation mortar. The experiment results indicate that, among the four proposed design scenarios, only scenario 4 can significantly improve the thermal performance of Huizhou masonry walls and meet the building energy code requirements, with a mean thermal transmittance of 1.175 W/m2·K. This research lays the foundation for improving the thermal performance of Huizhou masonry walls with new insulation and construction technology, thereby helping to improve the quality of life of Huizhou residents while respecting the cultural significance of the traditional Huizhou building.

  18. Aquifer thermal energy (heat and chill) storage

    Energy Technology Data Exchange (ETDEWEB)

    Jenne, E.A. (ed.)

    1992-11-01

    As part of the 1992 Intersociety Conversion Engineering Conference, held in San Diego, California, August 3--7, 1992, the Seasonal Thermal Energy Storage Program coordinated five sessions dealing specifically with aquifer thermal energy storage technologies (ATES). Researchers from Sweden, The Netherlands, Germany, Switzerland, Denmark, Canada, and the United States presented papers on a variety of ATES related topics. With special permission from the Society of Automotive Engineers, host society for the 1992 IECEC, these papers are being republished here as a standalone summary of ATES technology status. Individual papers are indexed separately.

  19. Process and device for controling lateral wall of fuel assembly storage cell

    International Nuclear Information System (INIS)

    Moreau, B.

    1989-01-01

    The inspection procedure involves moving a detection system along the length of the wall of a cell in the fuel storage rack immersed in water. The detection system has at least one probe for determining the wall thickness. The probe signal is received above the pond and compared against a reference signal. This process allows to verify the presence of neutron absorbing material in the side walls of the cell [fr

  20. Low temperature desalination using solar collectors augmented by thermal energy storage

    International Nuclear Information System (INIS)

    Gude, Veera Gnaneswar; Nirmalakhandan, Nagamany; Deng, Shuguang; Maganti, Anand

    2012-01-01

    Highlights: ► A new low temperature desalination process using solar collectors was investigated. ► A thermal energy storage tank (TES) was included for continuous process operation. ► Solar collector area and TES volumes were optimized by theoretical simulations. ► Economic analysis for the entire process was compared with and without TES tank. ► Energy and emission payback periods for the solar collector system were reported. -- Abstract: A low temperature desalination process capable of producing 100 L/d freshwater was designed to utilize solar energy harvested from flat plate solar collectors. Since solar insolation is intermittent, a thermal energy storage system was incorporated to run the desalination process round the clock. The requirements for solar collector area as well as thermal energy storage volume were estimated based on the variations in solar insolation. Results from this theoretical study confirm that thermal energy storage is a useful component of the system for conserving thermal energy to meet the energy demand when direct solar energy resource is not available. Thermodynamic advantages of the low temperature desalination using thermal energy storage, as well as energy and environmental emissions payback period of the system powered by flat plate solar collectors are presented. It has been determined that a solar collector area of 18 m 2 with a thermal energy storage volume of 3 m 3 is adequate to produce 100 L/d of freshwater round the clock considering fluctuations in the weather conditions. An economic analysis on the desalination system with thermal energy storage is also presented.

  1. Retrofitted green roofs and walls and improvements in thermal comfort

    Science.gov (United States)

    Feitosa, Renato Castiglia; Wilkinson, Sara

    2017-06-01

    Increased urbanization has led to a worsening in the quality of life for many people living in large cities in respect of the urban heat island effect and increases of indoor temperatures in housing and other buildings. A solution may be to retrofit existing environments to their former conditions, with a combination of green infrastructures applied to existing walls and rooftops. Retrofitted green roofs may attenuate housing temperature. However, with tall buildings, facade areas are much larger compared to rooftop areas, the role of green walls in mitigating extreme temperatures is more pronounced. Thus, the combination of green roofs and green walls is expected to promote a better thermal performance in the building envelope. For this purpose, a modular vegetated system is adopted for covering both walls and rooftops. Rather than temperature itself, the heat index, which comprises the combined effect of temperature and relative humidity is used in the evaluation of thermal comfort in small scale experiments performed in Sydney - Australia, where identical timber framed structures prototypes (vegetated and non-vegetated) are compared. The results have shown a different understanding of thermal comfort improvement regarding heat index rather than temperature itself. The combination of green roof and walls has a valid role to play in heat index attenuation.

  2. Miscibility gap alloys with inverse microstructures and high thermal conductivity for high energy density thermal storage applications

    International Nuclear Information System (INIS)

    Sugo, Heber; Kisi, Erich; Cuskelly, Dylan

    2013-01-01

    New high energy-density thermal storage materials are proposed which use miscibility gap binary alloy systems to operate through the latent heat of fusion of one component dispersed in a thermodynamically stable matrix. Using trial systems Al–Sn and Fe–Cu, we demonstrate the development of the required inverse microstructure (low melting point phase embedded in high melting point matrix) and excellent thermal storage potential. Several other candidate systems are discussed. It is argued that such systems offer enhancement over conventional phase change thermal storage by using high thermal conductivity microstructures (50–400 W/m K); minimum volume of storage systems due to high energy density latent heat of fusion materials (0.2–2.2 MJ/L); and technical utility through adaptability to a great variety of end uses. Low (<300 °C), mid (300–400 °C) and high (600–1400 °C) temperature options exist for applications ranging from space heating and process drying to concentrated solar thermal energy conversion and waste heat recovery. -- Highlights: ► Alloys of immiscible metals are proposed as thermal storage systems. ► High latent heat of fusion per unit volume and tunable temperature are advantageous. ► Thermal storage systems with capacities of 0.2–2.2 MJ/L are identified. ► Heat delivery is via a rigid non-reactive high thermal conductivity matrix. ► The required inverse microstructures were developed for Sn–Al and Cu–Fe systems

  3. Microwavable thermal energy storage material

    Science.gov (United States)

    Salyer, I.O.

    1998-09-08

    A microwavable thermal energy storage material is provided which includes a mixture of a phase change material and silica, and a carbon black additive in the form of a conformable dry powder of phase change material/silica/carbon black, or solid pellets, films, fibers, moldings or strands of phase change material/high density polyethylene/ethylene vinyl acetate/silica/carbon black which allows the phase change material to be rapidly heated in a microwave oven. The carbon black additive, which is preferably an electrically conductive carbon black, may be added in low concentrations of from 0.5 to 15% by weight, and may be used to tailor the heating times of the phase change material as desired. The microwavable thermal energy storage material can be used in food serving applications such as tableware items or pizza warmers, and in medical wraps and garments. 3 figs.

  4. Integration of Decentralized Thermal Storages Within District Heating (DH Networks

    Directory of Open Access Journals (Sweden)

    Schuchardt Georg K.

    2016-12-01

    Full Text Available Thermal Storages and Thermal Accumulators are an important component within District Heating (DH systems, adding flexibility and offering additional business opportunities for these systems. Furthermore, these components have a major impact on the energy and exergy efficiency as well as the heat losses of the heat distribution system. Especially the integration of Thermal Storages within ill-conditioned parts of the overall DH system enhances the efficiency of the heat distribution. Regarding an illustrative and simplified example for a DH system, the interactions of different heat storage concepts (centralized and decentralized and the heat losses, energy and exergy efficiencies will be examined by considering the thermal state of the heat distribution network.

  5. Thermal energy storage for cooling of commercial buildings

    Energy Technology Data Exchange (ETDEWEB)

    Akbari, H. (Lawrence Berkeley Lab., CA (USA)); Mertol, A. (Science Applications International Corp., Los Altos, CA (USA))

    1988-07-01

    The storage of coolness'' has been in use in limited applications for more than a half century. Recently, because of high electricity costs during utilities' peak power periods, thermal storage for cooling has become a prime target for load management strategies. Systems with cool storage shift all or part of the electricity requirement from peak to off-peak hours to take advantage of reduced demand charges and/or off-peak rates. Thermal storage technology applies equally to industrial, commercial, and residential sectors. In the industrial sector, because of the lack of economic incentives and the custom design required for each application, the penetration of this technology has been limited to a few industries. The penetration rate in the residential sector has been also very limited due to the absence of economic incentives, sizing problems, and the lack of compact packaged systems. To date, the most promising applications of these systems, therefore, appear to be for commercial cooling. In this report, the current and potential use of thermal energy storage systems for cooling commercial buildings is investigated. In addition, a general overview of the technology is presented and the applicability and cost-effectiveness of this technology for developed and developing countries are discussed. 28 refs., 12 figs., 1 tab.

  6. Thermal responses of tokamak reactor first walls during cyclic plasma burns

    International Nuclear Information System (INIS)

    Smith, D.L.; Charak, I.

    1978-01-01

    The CINDA-3G computer code has been adapted to analyze the thermal responses and operating limitations of two fusion reactor first-wall concepts under normal cyclic operation. A component of an LMFBR computer code has been modified and adapted to analyze the ablative behavior of first-walls after a plasma disruption. The first-wall design concepts considered are a forced-circulation water-cooled stainless steel panel with and without a monolithic graphite liner. The thermal gradients in the metal wall and liner have been determined for several burn-cycle scenarios and the extent of surface ablation that results from a plasma disruption has been determined for stainless steel and graphite first surfaces

  7. Thermal responses of tokamak reactor first walls during cyclic plasma burns

    International Nuclear Information System (INIS)

    Smith, D.L.; Charak, I.

    1977-01-01

    The CINDA-3G computer code has been adapted to analyze the thermal responses and operating limitations of two fusion reactor first-wall concepts under normal cyclic operation. A component of an LMFBR computer has been modified and adapted to analyze the ablative behavior of first-walls after a plasma disruption. The first-wall design concepts considered are a forced-circulation water-cooled stainless steel panel with and without a monolithic graphite liner. The thermal gradients in the metal wall and liner have been determined for several burn-cycle scenarios and the extent of surface ablation that results from a plasma disruption has been determined for stainless steel and graphite first surfaces

  8. Experimental investigation of thermal storage integrated micro trigeneration system

    International Nuclear Information System (INIS)

    Johar, Dheeraj Kishor; Sharma, Dilip; Soni, Shyam Lal; Goyal, Rahul; Gupta, Pradeep K.

    2017-01-01

    Highlights: • Energy Storage System is integrated with Micro trigeneration system. • Erythritol is used as Phase Change Material. • Maximum energy saved is 15.30%. • Combined systems are feasible to increase energy efficiency. - Abstract: In this study a 4.4 kW stationary compression ignition engine is coupled with a double pipe heat exchanger, vapour absorption refrigeration system and thermal energy storage system to achieve Trigeneration i.e. power, heating and cooling. A shell and tube type heat exchanger filled with erythritol is used to store thermal energy of engine exhaust. Various combinations of thermal energy storage system integrated micro-trigeneration were investigated and results related to performance and emissions are reported in this paper. The test results show that micro capacity (4.4 kW) stationary single cylinder diesel engine can be successfully modified to simultaneously produce power, heating and cooling and also store thermal energy.

  9. Thermal Analysis of a Dry Storage Concept for Capsule Dry Storage Project

    International Nuclear Information System (INIS)

    JOSEPHSON, W.S.

    2003-01-01

    There are 1,936 cesium (Cs) and strontium (Sr) capsules stored in pools at the Waste Encapsulation and Storage Facility (WESF). These capsules will be moved to dry storage on the Hanford Site as an interim measure to reduce risk. The Cs/Sr Capsule Dry Storage Project is conducted under the assumption that the capsules will eventually be moved to the repository at Yucca Mountain, and the design criteria include requirements that will facilitate acceptance at the repository. The storage system must also permit retrieval of capsules in the event that vitrification of the capsule contents is pursued. The Capsule Advisory Panel (CAP) was created by the Project Manager for the Hanford Site Capsule Dry Storage Project (CDSP). The purpose of the CAP is to provide specific technical input to the CDSP; to identify design requirements; to ensure design requirements for the project are conservative and defensible; to identify and resolve emerging, critical technical issues, as requested; and to support technical reviews performed by regulatory organizations, as requested. The CAP will develop supporting and summary documents that can be used as part of the technical and safety bases for the CDSP. The purpose of capsule dry storage thermal analysis is to: (1) Summarize the pertinent thermal design requirements sent to vendors, (2) Summarize and address the assumptions that underlie those design requirements, (3) Demonstrate that an acceptable design exists that satisfies the requirements, (4) Identify key design features and phenomena that promote or impede design success, (5) Support other CAP analyses such as corrosion and integrity evaluations, and (6) Support the assessment of proposed designs. It is not the purpose of this report to optimize or fully analyze variations of postulated acceptable designs. The present evaluation will indicate the impact of various possible design features, but not systematically pursue design improvements obtainable through analysis

  10. Load following generation in nuclear power plants by latent thermal energy storage

    International Nuclear Information System (INIS)

    Abe, Yoshiyuki; Takahashi, Yoshio; Kamimoto, Masayuki; Sakamoto, Ryuji; Kanari, Katsuhiko; Ozawa, Takeo

    1985-01-01

    The recent increase in nuclear power plants and the growing difference between peak and off-peak demands imperatively need load following generation in nuclear power plants to meet the time-variant demands. One possible way to resolve the problem is, obviously, a prompt reaction conrol in the reactors. Alternatively, energy storage gives another sophisticated path to make load following generation in more effective manner. Latent thermal energy storage enjoys high storage density and allows thermal extraction at nearly constant temperature, i.e. phase change temperature. The present report is an attempt to evaluate the feasibility of load following electric power generation in nuclear plants (actually Pressurized Water Reactors) by latent thermal energy storage. In this concept, the excess thermal energy in the off-peak period is stored in molten salt latent thermal energy storage unit, and additional power output is generated in auxiliary generator in the peak demand duration using the stored thermal energy. The present evaluation gives encouraging results and shows the primary subject to be taken up at first is the compatibility of candidate storage materials with inexpensive structural metal materials. Chapter 1 denotes the background of the present report, and Chapter 2 reviews the previous studies on the peak load coverage by thermal energy storage. To figure out the concept of the storage systems, present power plant systems and possible constitution of storage systems are briefly shown in Chapter 3. The details of the evaluation of the candidate storage media, and the compilation of the materials' properties are presented in Chapter 4. In Chapter 5, the concept of the storage systems is depicted, and the economical feasibility of the systems is evaluated. The concluding remarks are summarized in Chapter 6. (author)

  11. Aquifer thermal energy storage. International symposium: Proceedings

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-05-01

    Aquifers have been used to store large quantities of thermal energy to supply process cooling, space cooling, space heating, and ventilation air preheating, and can be used with or without heat pumps. Aquifers are used as energy sinks and sources when supply and demand for energy do not coincide. Aquifer thermal energy storage may be used on a short-term or long-term basis; as the sole source of energy or as a partial storage; at a temperature useful for direct application or needing upgrade. The sources of energy used for aquifer storage are ambient air, usually cold winter air; waste or by-product energy; and renewable energy such as solar. The present technical, financial and environmental status of ATES is promising. Numerous projects are operating and under development in several countries. These projects are listed and results from Canada and elsewhere are used to illustrate the present status of ATES. Technical obstacles have been addressed and have largely been overcome. Cold storage in aquifers can be seen as a standard design option in the near future as it presently is in some countries. The cost-effectiveness of aquifer thermal energy storage is based on the capital cost avoidance of conventional chilling equipment and energy savings. ATES is one of many developments in energy efficient building technology and its success depends on relating it to important building market and environmental trends. This paper attempts to provide guidance for the future implementation of ATES. Individual projects have been processed separately for entry onto the Department of Energy databases.

  12. Economic impact of latent heat thermal energy storage systems within direct steam generating solar thermal power plants with parabolic troughs

    International Nuclear Information System (INIS)

    Seitz, M.; Johnson, M.; Hübner, S.

    2017-01-01

    Highlights: • Integration of a latent heat thermal energy storage system into a solar direct steam generation power cycle. • Parametric study of solar field and storage size for determination of the optimal layout. • Evaluation of storage impact on the economic performance of the solar thermal power plant. • Economic comparison of new direct steam generation plant layout with state-of-the-art oil plant layout. - Abstract: One possible way to further reduce levelized costs of electricity of concentrated solar thermal energy is to directly use water/steam as the primary heat transfer fluid within a concentrated collector field. This so-called direct steam generation offers the opportunity of higher operating temperatures and better exergy efficiency. A technical challenge of the direct steam generation technology compared to oil-driven power cycles is a competitive storage technology for heat transfer fluids with a phase change. Latent heat thermal energy storages are suitable for storing heat at a constant temperature and can be used for direct steam generation power plants. The calculation of the economic impact of an economically optimized thermal energy storage system, based on a latent heat thermal energy storage system with phase change material, is the main focus of the presented work. To reach that goal, a thermal energy storage system for a direct steam generation power plant with parabolic troughs in the solar field was thermally designed to determine the boundary conditions. This paper discusses the economic impact of the designed thermal energy storage system based on the levelized costs of electricity results, provided via a wide parametric study. A state-of-the-art power cycle with a primary and a secondary heat transfer fluid and a two-tank thermal energy storage is used as a benchmark technology for electricity generation with solar thermal energy. The benchmark and direct steam generation systems are compared to each other, based respectively

  13. Temperature dependency of the thermal conductivity of porous heat storage media

    Science.gov (United States)

    Hailemariam, Henok; Wuttke, Frank

    2018-04-01

    Analyzing the variation of thermal conductivity with temperature is vital in the design and assessment of the efficiency of sensible heat storage systems. In this study, the temperature variation of the thermal conductivity of a commercial cement-based porous heat storage material named - Füllbinder L is analyzed in saturated condition in the temperature range between 20 to 70°C (water based storage) with a steady state thermal conductivity and diffusivity meter. A considerable decrease in the thermal conductivity of the saturated sensible heat storage material upon increase in temperature is obtained, resulting in a significant loss of system efficiency and slower loading/un-loading rates, which when unaccounted for can lead to the under-designing of such systems. Furthermore, a new empirical prediction model for the estimation of thermal conductivity of cement-based porous sensible heat storage materials and naturally occurring crystalline rock formations as a function of temperature is proposed. The results of the model prediction are compared with the experimental results with satisfactory results.

  14. Experimental study on the thermal performance of a new type of thermal energy storage based on flat micro-heat pipe array

    International Nuclear Information System (INIS)

    Li, Feng-fei; Diao, Yan-hua; Zhao, Yao-hua; Zhu, Ting-ting; Liu, Jing

    2016-01-01

    Highlights: • A novel thermal energy storage based on flat micro-heat pipe array is proposed. • The thermal storage shows excellent thermal performance in the working process. • The novel thermal storage has the advantage of low flow resistance. - Abstract: The thermal performance of an air-based phase change storage unit is analyzed and discussed in this study. The thermal energy storage uses flat micro-heat pipe array (FMHPA) as the core heat transfer component and lauric acid as phase change material (PCM). An experimental system is devised to test the heat storage–release property of the storage unit under different inlet temperatures and flow rates of the heat transfer medium. The performance of the storage unit and the melting/solidification curves of the phase change material are obtained based on extensive experimental data. Experimental results indicate that the flat micro-heat pipe array exhibits excellent temperature uniformity in the heat storage–release process, and the performance of the storage unit is efficient and steady.

  15. Thermal-Responsive Polymers for Enhancing Safety of Electrochemical Storage Devices.

    Science.gov (United States)

    Yang, Hui; Leow, Wan Ru; Chen, Xiaodong

    2018-03-01

    Thermal runway constitutes the most pressing safety issue in lithium-ion batteries and supercapacitors of large-scale and high-power density due to risks of fire or explosion. However, traditional strategies for averting thermal runaway do not enable the charging-discharging rate to change according to temperature or the original performance to resume when the device is cooled to room temperature. To efficiently control thermal runaway, thermal-responsive polymers provide a feasible and reversible strategy due to their ability to sense and subsequently act according to a predetermined sequence when triggered by heat. Herein, recent research progress on the use of thermal-responsive polymers to enhance the thermal safety of electrochemical storage devices is reviewed. First, a brief discussion is provided on the methods of preventing thermal runaway in electrochemical storage devices. Subsequently, a short review is provided on the different types of thermal-responsive polymers that can efficiently avoid thermal runaway, such as phase change polymers, polymers with sol-gel transitions, and polymers with positive temperature coefficients. The results represent the important development of thermal-responsive polymers toward the prevention of thermal runaway in next-generation smart electrochemical storage devices. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  16. Thermal simulation of storage in TSS-Galleries

    International Nuclear Information System (INIS)

    Lain Huerta, R.; Martinez Santiago, T.; Ramirez Oyangueren, P.

    1993-01-01

    This report describes the experiment ''thermal simulation of storage in TSS-galleries'' what is been developed in salt mine of Asse, Germany. The report has 3 part: 1) Analysis of objectives and general description of boundary layers. 2) Geomechanics parameters of salt mine. 3) Thermal modelization, thermomechanics modelization and data acquisition

  17. Aquifer thermal energy storage in Finland

    Energy Technology Data Exchange (ETDEWEB)

    Iihola, H; Ala-Peijari, T; Seppaenen, H

    1988-01-01

    The rapid changes and crises in the field of energy during the 1970s and 1980s have forced us to examine the use of energy more critically and to look for new ideas. Seasonal aquifer thermal energy storage (T < 100/sup 0/C) on a large scale is one of the grey areas which have not yet been extensively explored. However, projects are currently underway in a dozen countries. In Finland there have been three demonstration projects from 1974 to 1987. International co-operation under the auspices of the International Energy Agency, Annex VI, 'Environmental and Chemical Aspects of Thermal Energy Storage in Aquifers and Research and Development of Water Treatment Methods' started in 1987. The research being undertaken in 8 countries includes several elements fundamental to hydrochemistry and biochemistry.

  18. Optimal control of building storage systems using both ice storage and thermal mass – Part I: Simulation environment

    International Nuclear Information System (INIS)

    Hajiah, Ali; Krarti, Moncef

    2012-01-01

    Highlights: ► A simulation environment is described to account for both passive and active thermal energy storage (TES) systems. ► Laboratory testing results have been used to validate the predictions from the simulation environment. ► Optimal control strategies for TES systems have been developed as part of the simulation environment. - Abstract: This paper presents a simulation environment that can evaluate the benefits of using simultaneously building thermal capacitance and ice storage system to reduce total operating costs including energy and demand charges while maintaining adequate occupant comfort conditions within commercial buildings. The building thermal storage is controlled through pre-cooling strategies by setting space indoor air temperatures. The ice storage system is controlled by charging the ice tank and operating the chiller during low electrical charge periods and melting the ice during on-peak periods. Optimal controls for both building thermal storage and ice storage are developed to minimize energy charges, demand charges, or combined energy and demand charges. The results obtained from the simulation environment are validated using laboratory testing for an optimal controller.

  19. Influence of geologic layering on heat transport and storage in an aquifer thermal energy storage system

    Science.gov (United States)

    Bridger, D. W.; Allen, D. M.

    2014-01-01

    A modeling study was carried out to evaluate the influence of aquifer heterogeneity, as represented by geologic layering, on heat transport and storage in an aquifer thermal energy storage (ATES) system in Agassiz, British Columbia, Canada. Two 3D heat transport models were developed and calibrated using the flow and heat transport code FEFLOW including: a "non-layered" model domain with homogeneous hydraulic and thermal properties; and, a "layered" model domain with variable hydraulic and thermal properties assigned to discrete geological units to represent aquifer heterogeneity. The base model (non-layered) shows limited sensitivity for the ranges of all thermal and hydraulic properties expected at the site; the model is most sensitive to vertical anisotropy and hydraulic gradient. Simulated and observed temperatures within the wells reflect a combination of screen placement and layering, with inconsistencies largely explained by the lateral continuity of high permeability layers represented in the model. Simulation of heat injection, storage and recovery show preferential transport along high permeability layers, resulting in longitudinal plume distortion, and overall higher short-term storage efficiencies.

  20. Multi-dimensional modeling of a thermal energy storage canister. M.S. Thesis - Cleveland State Univ., Dec. 1990

    Science.gov (United States)

    Kerslake, Thomas W.

    1991-01-01

    The Solar Dynamic Power Module being developed for Space Station Freedom uses a eutectic mixture of LiF-CaF2 phase change material (PCM) contained in toroidal canisters for thermal energy storage. Presented are the results from heat transfer analyses of a PCM containment canister. One and two dimensional finite difference computer models are developed to analyze heat transfer in the canister walls, PCM, void, and heat engine working fluid coolant. The modes of heat transfer considered include conduction in canister walls and solid PCM, conduction and pseudo-free convection in liquid PCM, conduction and radiation across PCM vapor filled void regions, and forced convection in the heat engine working fluid. Void shape, location, growth or shrinkage (due to density difference between the solid and liquid PCM phases) are prescribed based on engineering judgment. The PCM phase change process is analyzed using the enthalpy method. The discussion of the results focuses on how canister thermal performance is affected by free convection in the liquid PCM and void heat transfer. Characterizing these effects is important for interpreting the relationship between ground-based canister performance (in 1-g) and expected on-orbit performance (in micro-g). Void regions accentuate canister hot spots and temperature gradients due to their large thermal resistance. Free convection reduces the extent of PCM superheating and lowers canister temperatures during a portion of the PCM thermal charge period. Surprisingly small differences in canister thermal performance result from operation on the ground and operation on-orbit. This lack of a strong gravity dependency is attributed to the large contribution of container walls in overall canister energy redistribution by conduction.

  1. Investigation of Heat Pump Operation Strategies with Thermal Storage in Heating Conditions

    Directory of Open Access Journals (Sweden)

    Wangsik Jung

    2017-12-01

    Full Text Available A heat pump with thermal storage system is a system that operates a heat pump during nighttime using inexpensive electricity; during this time, the generated thermal energy is stored in a thermal storage tank. The stored thermal energy is used by the heat pump during daytime. Based on a model of a dual latent thermal storage tank and a heat pump, this study conducts control simulations using both conventional and advanced methods for heating in a building. Conventional methods include the thermal storage priority method and the heat pump priority method, while advanced approaches include the region control method and the dynamic programming method. The heating load required for an office building is identified using TRNSYS (Transient system simulation, used for simulations of various control methods. The thermal storage priority method shows a low coefficient of performance (COP, while the heat pump priority method leads to high electricity costs due to the low use of thermal storage. In contrast, electricity costs are lower for the region control method, which operates using the optimal part load ratio of the heat pump, and for dynamic programming, which operates the system by following the minimum cost path. According to simulation results for the winter season, the electricity costs using the dynamic programming method are 17% and 9% lower than those of the heat pump priority and thermal storage priority methods, respectively. The region control method shows results similar to the dynamic programming method with respect to electricity costs. In conclusion, advanced control methods are proven to have advantages over conventional methods in terms of power consumption and electricity costs.

  2. Rapid charging of thermal energy storage materials through plasmonic heating.

    Science.gov (United States)

    Wang, Zhongyong; Tao, Peng; Liu, Yang; Xu, Hao; Ye, Qinxian; Hu, Hang; Song, Chengyi; Chen, Zhaoping; Shang, Wen; Deng, Tao

    2014-09-01

    Direct collection, conversion and storage of solar radiation as thermal energy are crucial to the efficient utilization of renewable solar energy and the reduction of global carbon footprint. This work reports a facile approach for rapid and efficient charging of thermal energy storage materials by the instant and intense photothermal effect of uniformly distributed plasmonic nanoparticles. Upon illumination with both green laser light and sunlight, the prepared plasmonic nanocomposites with volumetric ppm level of filler concentration demonstrated a faster heating rate, a higher heating temperature and a larger heating area than the conventional thermal diffusion based approach. With controlled dispersion, we further demonstrated that the light-to-heat conversion and thermal storage properties of the plasmonic nanocomposites can be fine-tuned by engineering the composition of the nanocomposites.

  3. Modeling Pumped Thermal Energy Storage with Waste Heat Harvesting

    Science.gov (United States)

    Abarr, Miles L. Lindsey

    This work introduces a new concept for a utility scale combined energy storage and generation system. The proposed design utilizes a pumped thermal energy storage (PTES) system, which also utilizes waste heat leaving a natural gas peaker plant. This system creates a low cost utility-scale energy storage system by leveraging this dual-functionality. This dissertation first presents a review of previous work in PTES as well as the details of the proposed integrated bottoming and energy storage system. A time-domain system model was developed in Mathworks R2016a Simscape and Simulink software to analyze this system. Validation of both the fluid state model and the thermal energy storage model are provided. The experimental results showed the average error in cumulative fluid energy between simulation and measurement was +/- 0.3% per hour. Comparison to a Finite Element Analysis (FEA) model showed heat transfer. The system model was used to conduct sensitivity analysis, baseline performance, and levelized cost of energy of a recently proposed Pumped Thermal Energy Storage and Bottoming System (Bot-PTES) that uses ammonia as the working fluid. This analysis focused on the effects of hot thermal storage utilization, system pressure, and evaporator/condenser size on the system performance. This work presents the estimated performance for a proposed baseline Bot-PTES. Results of this analysis showed that all selected parameters had significant effects on efficiency, with the evaporator/condenser size having the largest effect over the selected ranges. Results for the baseline case showed stand-alone energy storage efficiencies between 51 and 66% for varying power levels and charge states, and a stand-alone bottoming efficiency of 24%. The resulting efficiencies for this case were low compared to competing technologies; however, the dual-functionality of the Bot-PTES enables it to have higher capacity factor, leading to 91-197/MWh levelized cost of energy compared to 262

  4. Influence of cultivar, cooking, and storage on cell-wall polysaccharide composition of winter squash (Cucurbita maxima).

    Science.gov (United States)

    Ratnayake, R M Sunil; Melton, Laurence D; Hurst, Paul L

    2003-03-26

    Changes in the cell-wall polysaccharides (CWP) of the edible tissues of four winter squash cultivars during storage and after cooking were investigated. A procedure for isolating cell walls of tissues containing high levels of starch was used. The starch-free CWP were sequentially fractionated using CDTA, dilute Na(2)CO(3), and 4 M KOH. Cellulose made up 40-42% of the total CWP for three cultivars (Delica, CF 2, and CF 4) at harvest but was 35% in the softer Red Warren. The pectic polysaccharides of Delica, CF 2, and CF 4 cell walls are more branched than those from Red Warren squash. The higher proportion of uronic acid in the pectic polysaccharides of Red Warren squash correlates with its lower firmness. Cooking resulted in an increase in the water-soluble pectins and a decrease in the pectins associated with cellulose. The total CWP content of the squash cultivars remained unchanged for up to 2 months of storage and then markedly decreased between 2 and 3 months of storage. The galactose content of Delica and Red Warren cell walls remained relatively constant from harvest to 2 months of storage and then decreased markedly during 2-3 months of storage.

  5. Solar-thermal conversion and thermal energy storage of graphene foam-based composite

    KAUST Repository

    Zhang, Lianbin

    2016-07-11

    Among various utilizations of solar energy, solar-thermal conversion has recently gained renewed research interest due to its extremely high energy efficiency. However, one limiting factor common to all solar-based energy conversion technologies is the intermittent nature of solar irradiation, which makes them unable to stand-alone to satisfy continuous energy need. Herein, we report a three-dimensional (3D) graphene foam and phase change material (PCM) composite for the seamlessly combined solar-thermal conversion and thermal storage for sustained energy release. The composite is obtained by infiltrating the 3D graphene foam with a commonly used PCM, paraffin wax. The high macroporosity and low density of the graphene foam allow for high weight fraction of the PCM to be incorporated, which enhances heat storage capacity of the composite. The interconnected graphene sheets in the composite provide (1) the solar-thermal conversion capability, (2) high thermal conductivity and (3) form stability of the composite. Under light irradiation, the composite effectively collects and converts the light energy into thermal energy, and the converted thermal energy is stored in the PCM and released in an elongated period of time for sustained utilization. This study provides a promising route for sustainable utilization of solar energy.

  6. Solar-thermal conversion and thermal energy storage of graphene foam-based composites.

    Science.gov (United States)

    Zhang, Lianbin; Li, Renyuan; Tang, Bo; Wang, Peng

    2016-08-14

    Among various utilizations of solar energy, solar-thermal conversion has recently gained renewed research interest due to its extremely high energy efficiency. However, one limiting factor common to all solar-based energy conversion technologies is the intermittent nature of solar irradiation, which makes them unable to stand-alone to satisfy the continuous energy need. Herein, we report a three-dimensional (3D) graphene foam and phase change material (PCM) composite for the seamlessly combined solar-thermal conversion and thermal storage for sustained energy release. The composite is obtained by infiltrating the 3D graphene foam with a commonly used PCM, paraffin wax. The high macroporosity and low density of the graphene foam allow for high weight fraction of the PCM to be incorporated, which enhances the heat storage capacity of the composite. The interconnected graphene sheets in the composite provide (1) the solar-thermal conversion capability, (2) high thermal conductivity and (3) form stability of the composite. Under light irradiation, the composite effectively collects and converts the light energy into thermal energy, and the converted thermal energy is stored in the PCM and released in an elongated period of time for sustained utilization. This study provides a promising route for sustainable utilization of solar energy.

  7. A New Model for Optimal Mechanical and Thermal Performance of Cement-Based Partition Wall.

    Science.gov (United States)

    Huang, Shiping; Hu, Mengyu; Huang, Yonghui; Cui, Nannan; Wang, Weifeng

    2018-04-17

    The prefabricated cement-based partition wall has been widely used in assembled buildings because of its high manufacturing efficiency, high-quality surface, and simple and convenient construction process. In this paper, a general porous partition wall that is made from cement-based materials was proposed to meet the optimal mechanical and thermal performance during transportation, construction and its service life. The porosity of the proposed partition wall is formed by elliptic-cylinder-type cavities. The finite element method was used to investigate the mechanical and thermal behaviour, which shows that the proposed model has distinct advantages over the current partition wall that is used in the building industry. It is found that, by controlling the eccentricity of the elliptic-cylinder cavities, the proposed wall stiffness can be adjusted to respond to the imposed loads and to improve the thermal performance, which can be used for the optimum design. Finally, design guidance is provided to obtain the optimal mechanical and thermal performance. The proposed model could be used as a promising candidate for partition wall in the building industry.

  8. A New Model for Optimal Mechanical and Thermal Performance of Cement-Based Partition Wall

    Directory of Open Access Journals (Sweden)

    Shiping Huang

    2018-04-01

    Full Text Available The prefabricated cement-based partition wall has been widely used in assembled buildings because of its high manufacturing efficiency, high-quality surface, and simple and convenient construction process. In this paper, a general porous partition wall that is made from cement-based materials was proposed to meet the optimal mechanical and thermal performance during transportation, construction and its service life. The porosity of the proposed partition wall is formed by elliptic-cylinder-type cavities. The finite element method was used to investigate the mechanical and thermal behaviour, which shows that the proposed model has distinct advantages over the current partition wall that is used in the building industry. It is found that, by controlling the eccentricity of the elliptic-cylinder cavities, the proposed wall stiffness can be adjusted to respond to the imposed loads and to improve the thermal performance, which can be used for the optimum design. Finally, design guidance is provided to obtain the optimal mechanical and thermal performance. The proposed model could be used as a promising candidate for partition wall in the building industry.

  9. Flexible composite material with phase change thermal storage

    Science.gov (United States)

    Buckley, Theresa M. (Inventor)

    2001-01-01

    A highly flexible composite material having a flexible matrix containing a phase change thermal storage material. The composite material can be made to heat or cool the body or to act as a thermal buffer to protect the wearer from changing environmental conditions. The composite may also include an external thermal insulation layer and/or an internal thermal control layer to regulate the rate of heat exchange between the composite and the skin of the wearer. Other embodiments of the PCM composite also provide 1) a path for evaporation or direct absorption of perspiration from the skin of the wearer for improved comfort and thermal control, 2) heat conductive pathways within the material for thermal equalization, 3) surface treatments for improved absorption or rejection of heat by the material, and 4) means for quickly regenerating the thermal storage capacity for reuse of the material. Applications of the composite materials are also described which take advantage of the composite's thermal characteristics. The examples described include a diver's wet suit, ski boot liners, thermal socks, ,gloves and a face mask for cold weather activities, and a metabolic heating or cooling blanket useful for treating hypothermia or fever patients in a medical setting and therapeutic heating or cooling orthopedic joint supports.

  10. Composite Materials for Thermal Energy Storage: Enhancing Performance through Microstructures

    Science.gov (United States)

    Ge, Zhiwei; Ye, Feng; Ding, Yulong

    2014-01-01

    Chemical incompatibility and low thermal conductivity issues of molten-salt-based thermal energy storage materials can be addressed by using microstructured composites. Using a eutectic mixture of lithium and sodium carbonates as molten salt, magnesium oxide as supporting material, and graphite as thermal conductivity enhancer, the microstructural development, chemical compatibility, thermal stability, thermal conductivity, and thermal energy storage performance of composite materials are investigated. The ceramic supporting material is essential for preventing salt leakage and hence provides a solution to the chemical incompatibility issue. The use of graphite gives a significant enhancement on the thermal conductivity of the composite. Analyses suggest that the experimentally observed microstructural development of the composite is associated with the wettability of the salt on the ceramic substrate and that on the thermal conduction enhancer. PMID:24591286

  11. Dynamic tuning of optical absorbers for accelerated solar-thermal energy storage.

    Science.gov (United States)

    Wang, Zhongyong; Tong, Zhen; Ye, Qinxian; Hu, Hang; Nie, Xiao; Yan, Chen; Shang, Wen; Song, Chengyi; Wu, Jianbo; Wang, Jun; Bao, Hua; Tao, Peng; Deng, Tao

    2017-11-14

    Currently, solar-thermal energy storage within phase-change materials relies on adding high thermal-conductivity fillers to improve the thermal-diffusion-based charging rate, which often leads to limited enhancement of charging speed and sacrificed energy storage capacity. Here we report the exploration of a magnetically enhanced photon-transport-based charging approach, which enables the dynamic tuning of the distribution of optical absorbers dispersed within phase-change materials, to simultaneously achieve fast charging rates, large phase-change enthalpy, and high solar-thermal energy conversion efficiency. Compared with conventional thermal charging, the optical charging strategy improves the charging rate by more than 270% and triples the amount of overall stored thermal energy. This superior performance results from the distinct step-by-step photon-transport charging mechanism and the increased latent heat storage through magnetic manipulation of the dynamic distribution of optical absorbers.

  12. Low temperature thermal energy storage: a state-of-the-art survey

    Energy Technology Data Exchange (ETDEWEB)

    Baylin, F.

    1979-07-01

    The preliminary version of an analysis of activities in research, development, and demonstration of low temperature thermal energy storage (TES) technologies having applications in renewable energy systems is presented. Three major categories of thermal storage devices are considered: sensible heat; phase change materials (PCM); and reversible thermochemical reactions. Both short-term and annual thermal energy storage technologies based on prinicples of sensible heat are discussed. Storage media considered are water, earth, and rocks. Annual storage technologies include solar ponds, aquifers, and large tanks or beds of water, earth, or rocks. PCM storage devices considered employ salt hydrates and organic compounds. The sole application of reversible chemical reactions outlined is for the chemical heat pump. All program processes from basic research through commercialization efforts are investigated. Nongovernment-funded industrial programs and foreign efforts are outlined as well. Data describing low temperature TES activities are presented also as project descriptions. Projects for all these programs are grouped into seven categories: short-term sensible heat storage; annual sensible heat storage; PCM storage; heat transfer and exchange; industrial waste heat recovery and storage; reversible chemical reaction storage; and models, economic analyses, and support studies. Summary information about yearly funding and brief descriptions of project goals and accomplishments are included.

  13. Development of a solar thermal storage system suitable for the farmhouse heating in northeast China

    Energy Technology Data Exchange (ETDEWEB)

    Jang, M.K. [Shenyang Agricultural Univ., Shenyang (China)

    2010-07-01

    This study reported on the performance of a passive solar radiant floor heating system designed for standard energy-saving farmhouses in northeast China. Weather data in the region was analyzed in terms of solar radiation, temperature, humidity and light levels. The heating characteristics of the building materials such as windows, doors, walls and roofs were also analyzed along with the indoor thermal environment of the farmhouse. The heating load was then calculated along with the size of the thermal storage element and the area of the collector element. The passive solar radiant floor heating system was designed for heating during the winter and cooling in summer. According to the results, the heating characteristics of the system have the potential to improve farming villages environment and the use of renewable energy.

  14. Measuremental analysis of thermal performance of direct gain houses in Kanto district. Effects of thermal mass and caves; Kanto chiho ni tatsu direct gain jutaku no netsuseino jissoku. Netsuyoryo to hisashi no koka

    Energy Technology Data Exchange (ETDEWEB)

    Inoue, K; Sunaga, N; Muro, K [Tokyo Metropolitan University, Tokyo (Japan)

    1996-10-27

    The thermal performance of direct gain passive solar houses was measured. Mr. M`s two-storied RC residence with double glazing windows and thermal storage floors, walls and ceilings of brick or concrete was provided for measurement. Its double eaves of the south window and both SE and SW overhanging exterior walls play a role in sunshade. Mr. I`s two-storied wooden residence with thermal storage RC floors and brick walls, and no eaves of the south window and no overhanging exterior walls was also provided. The summer and winter measurement results were in complete contrast between the residences. In summer, large thermal mass and eaves of Mr. M`s residence were effective, while in winter, small thermal mass and no eaves of Mr. I`s residence were effective. The following ideas are important in design from the viewpoint of indoor thermal environment: a movable sunshade for taking in solar radiation as much as possible in winter, well-balanced arrangement of thermal storage parts with suitable thermal mass corresponding to movement of the sun, a large screen door for cross ventilation in summer, and a night insulation shutter for reducing heat loss in winter. 2 refs., 10 figs., 1 tab.

  15. Technical and economic feasibility of thermal storage. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Shelpuk, B.; Joy, P.; Crouthamel, M.

    1977-06-01

    The technical and economic feasibility of various thermal energy storage alternatives is determined by comparing the system performance and annualized cost which result from each storage alternative operating with the same solar collector model, the same building load model, and the same heating system and controls model. Performance and cost calculations are made on the basis of an hour-by-hour time step using actual weather bureau data for Albuquerque, N. M., and New York City for a single six-month heating season. The primary approach to comparing various storage alternatives is to allow the collector area and storage mass to vary until a minimum cost combination is achieved. In the Albuquerque location collector area of 325 ft/sup 2/, water storage mass of 12.5 lb/ft/sup 2/ of collector area, and phase change mass of 6.25 lb/ft/sup 2/ of collector area results in minimum cost systems, each of which delivers about 50% of the total building demand. The primary conclusion is that, using current costs for materials and containers, water is the cheapest storage alternative for heating applications in both Albuquerque and New York City. The cost of containing or encapsulating phase change materials, coupled with their small system performance advantage, is the main reason for this conclusion. The use of desiccant materials for thermal storage is considered to be impractical due to irreversibilities in thermal cycling.

  16. Heat pipe solar receiver with thermal energy storage

    Science.gov (United States)

    Zimmerman, W. F.

    1981-01-01

    An HPSR Stirling engine generator system featuring latent heat thermal energy storge, excellent thermal stability and self regulating, effective thermal transport at low system delta T is described. The system was supported by component technology testing of heat pipes and of thermal storage and energy transport models which define the expected performance of the system. Preliminary and detailed design efforts were completed and manufacturing of HPSR components has begun.

  17. Three-Dimensional Numerical Evaluation of Thermal Performance of Uninsulated Wall Assemblies: Preprint

    Energy Technology Data Exchange (ETDEWEB)

    Ridouane, E. H.; Bianchi, M.

    2011-11-01

    This study describes a detailed three-dimensional computational fluid dynamics modeling to evaluate the thermal performance of uninsulated wall assemblies accounting for conduction through framing, convection, and radiation. The model allows for material properties variations with temperature. Parameters that were varied in the study include ambient outdoor temperature and cavity surface emissivity. Understanding the thermal performance of uninsulated wall cavities is essential for accurate prediction of energy use in residential buildings. The results can serve as input for building energy simulation tools for modeling the temperature dependent energy performance of homes with uninsulated walls.

  18. Preparation, characterization, and thermal properties of microencapsulated phase change material for thermal energy storage

    Energy Technology Data Exchange (ETDEWEB)

    Alkan, Cemil; Sari, Ahmet; Karaipekli, Ali [Department of Chemistry, Gaziosmanpasa University, 60240 Tokat (Turkey); Uzun, Orhan [Department of Physics, Gaziosmanpasa University, 60240 Tokat (Turkey)

    2009-01-15

    This study is focused on the preparation, characterization, and determination of thermal properties of microencapsulated docosane with polymethylmethacrylate (PMMA) as phase change material for thermal energy storage. Microencapsulation of docosane has been carried out by emulsion polymerization. The microencapsulated phase change material (MEPCM) was characterized using scanning electron microscopy (SEM) and Fourier transform infrared (FT-IR) spectroscopy. Thermal properties and thermal stability of MEPCM were measured by differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). DSC analysis indicated that the docosane in the microcapsules melts at 41.0 C and crystallizes at 40.6 C. It has latent heats of 54.6 and -48.7 J/g for melting and crystallization, respectively. TGA showed that the MEPCM degraded in three distinguishable steps and had good chemical stability. Accelerated thermal cycling tests also indicated that the MEPCM had good thermal reliability. Based on all these results, it can be concluded that the microencapsulated docosane as MEPCMs have good potential for thermal energy storage purposes such as solar space heating applications. (author)

  19. Numerical modelling and experimental studies of thermal behaviour of building integrated thermal energy storage unit in a form of a ceiling panel

    International Nuclear Information System (INIS)

    Jaworski, Maciej; Łapka, Piotr; Furmański, Piotr

    2014-01-01

    the proposed heat storage unit to effectively control the air temperature inside the building. However, detailed measurement of the temperature of PCM composite have shown some disadvantages of the panel used in the study, e.g. thickness of the walls and distribution of PCM should be optimized. This can be achieved with the aid of the numerical simulator developed in this research. Practical implications: The proposed ceiling panel, optimised from the point of view of thermal performance in a given environmental conditions, can be used as a part of ventilation systems in residential and office buildings

  20. Hydrogen storage behaviors of platinum-supported multi-walled carbon nanotubes

    Energy Technology Data Exchange (ETDEWEB)

    Park, Soo-Jin; Lee, Seul-Yi [Department of Chemistry, Inha University, 253 Nam-gu, Incheon 402-751 (Korea, Republic of)

    2010-12-15

    In this work, the hydrogen storage behaviors of multi-walled carbon nanotubes (MWNTs) loaded by crystalline platinum (Pt) particles were studied. The microstructure of the Pt/MWNTs was characterized by X-ray diffraction and transmission electron microscopy. The pore structure and total pore volumes of the Pt/MWNTs were analyzed by N{sub 2}/77 K adsorption isotherms. The hydrogen storage capacity of the Pt/MWNTs was evaluated at 298 K and 100 bar. From the experimental results, it was found that Pt particles were homogeneously distributed on the MWNT surfaces. The amount of hydrogen storage capacity increased in proportion to the Pt content, with Pt-5/MWNTs exhibiting the largest hydrogen storage capacity. The superior amount of hydrogen storage was linked to an increase in the number of active sites and the optimum-controlled micropore volume for hydrogen adsorption due to the well-dispersed Pt particles. Therefore, it can be concluded that Pt particles play an important role in hydrogen storage characteristics due to the hydrogen spillover effect. (author)

  1. Spent nuclear fuel storage pool thermal-hydraulic analysis

    International Nuclear Information System (INIS)

    Gay, R.R.

    1984-01-01

    Storage methods and requirements for spent nuclear fuel at U.S. commercial light water reactors are reviewed in Section 1. Methods of increasing current at-reactor storage capabilities are also outlined. In Section 2 the development of analytical methods for the thermal-hydraulic analysis of spent fuel pools is chronicled, leading up to a discussion of the GFLOW code which is described in Section 3. In Section 4 the verification of GFLOW by comparisons of the code's predictions to experimental data taken inside the fuel storage pool at the Maine Yankee nuclear power plant is presented. The predictions of GFLOW using 72, 224, and 1584 node models of the storage pool are compared to each other and to the experimental data. An example of thermal licensing analysis for Maine Yankee using the GFLOW code is given in Section 5. The GFLOW licensing analysis is compared to previous licensing analysis performed by Yankee Atomic using the RELAP-4 computer code

  2. Strategies for commercializing customer thermal-energy storage. [64 references

    Energy Technology Data Exchange (ETDEWEB)

    Nelson, S.H.

    1976-12-01

    This report presents strategies for commercializing customer thermal storage. Four storage techniques are evaluated: space heating, air conditioning, hot-water heating, and interruptible hot-water heating. The storage systems involved store off-peak electric energy for thermal applications during peak load hours. Analyses of both storage techniques and principal parties affected by storage indicate four barriers: the absence of (1) commercially available air conditioning storage devices, (2) appropriate rates, (3) information on both rates and devices, and (4) widespread utility support. Development of appropriate rates is the key to commercialization. The criteria used to evaluate rate types are: maximum combined utility and customer benefits, ease of commercialization, and practical feasibility. Four rate types--demand charges, time-of-use rates, and two forms of load management rates (a monthly credit and an off-peak discount)--plus the possibility of utility ownership are considered. The best rate types for each storage option are: for hot-water heating, a monthly credit for allowing utility interruptions or an off-peak price discount for storage; for space heating, an off-peak discount contingent upon meeting utility requirements; and for air conditioning, an off-peak discount plus monthly credit.

  3. A Facile Route to Metal Oxides/Single-Walled Carbon Nanotube Macrofilm Nanocomposites for Energy Storage

    Science.gov (United States)

    Cao, Zeyuan; Wei, Bingqing

    2015-05-01

    Nanocomposites consisting of transition-metal oxides and carbon nanomaterials with a desired size and structure are highly demanded for high performance energy storage devices. Here, a facile two-step and cost-efficient approach relying on directly thermal treatment of chemical-vapor-deposition products is developed as a general synthetic method to prepare a family of metal oxides (MxOy (M=Fe, Co, Ni))/single-walled carbon nanotube (SWNT) macrofilm nanocomposites. The MxOy nanoparticles obtained are of 3-17 nm in diameter and homogeneously anchor on the free-standing SWNT macrofilms. NiO/SWNT also exhibits a high specific capacitance of 400 F g-1 and fast charge-transfer Faradaic redox reactions to achieve asymmetric supercapacitors with a high power and energy density. All MxOy/SWNT nanocomposites could deliver a high capacity beyond 1000 mAh g-1 and show excellent cycling stability for lithium-ion batteries. The impressive results demonstrate the promise for energy storage devices and the general approach may pave the way to synthesize other functional nanocomposites.

  4. A Facile Route to Metal Oxides/Single-Walled Carbon Nanotube Macrofilm Nanocomposites for Energy Storage

    Directory of Open Access Journals (Sweden)

    Zeyuan eCao

    2015-05-01

    Full Text Available Nanocomposites consisting of transition-metal oxides and carbon nanomaterials with a desired size and structure are highly demanded for high performance energy storage devices. Here, a facile two-step and cost-efficient approach relying on directly thermal treatment of chemical-vapor-deposition products is developed as a general synthetic method to prepare a family of metal oxides (MxOy (M=Fe, Co, Ni/single-walled carbon nanotube (SWNT macrofilm nanocomposites. The MxOy nanoparticles obtained are of 3-17 nm in diameter and homogeneously anchor on the free-standing SWNT macrofilms. NiO/SWNT also exhibits a high specific capacitance of 400 F g-1 and fast charge-transfer Faradaic redox reactions to achieve asymmetric supercapacitors with a high power and energy density. All MxOy/SWNT nanocomposites could deliver a high capacity beyond 1000 mAh g-1 and show excellent cycling stability for lithium-ion batteries. The impressive results demonstrate the promise for energy storage devices and the general approach may pave the way to synthesize other functional nanocomposites.

  5. Physicochemical Properties and Storage Stability of Microencapsulated DHA-Rich Oil with Different Wall Materials.

    Science.gov (United States)

    Chen, Wuxi; Wang, Haijun; Zhang, Ke; Gao, Feng; Chen, Shulin; Li, Demao

    2016-08-01

    This study aimed to evaluate the physicochemical properties and storage stability of microencapsulated DHA-rich oil spray dried with different wall materials: model 1 (modified starch, gum arabic, and maltodextrin), model 2 (soy protein isolate, gum arabic, and maltodextrin), and model 3 (casein, glucose, and lactose). The results indicated that model 3 exhibited the highest microencapsulation efficiency (98.66 %) and emulsion stability (>99 %), with a moisture content and mean particle size of 1.663 % and 14.173 μm, respectively. Differential scanning calorimetry analysis indicated that the Tm of DHA-rich oil microcapsules was high, suggesting that the entire structure of the microcapsules remained stable during thermal processing. A thermogravimetric analysis curve showed that the product lost 5 % of its weight at 172 °C and the wall material started to degrade at 236 °C. The peroxide value of microencapsulated DHA-rich oil remained at one ninth after accelerated oxidation at 45 °C for 8 weeks to that of the unencapsulated DHA-rich oil, thus revealing the promising oxidation stability of DHA-rich oil in microcapsules.

  6. Composite materials for thermal energy storage: enhancing performance through microstructures.

    Science.gov (United States)

    Ge, Zhiwei; Ye, Feng; Ding, Yulong

    2014-05-01

    Chemical incompatibility and low thermal conductivity issues of molten-salt-based thermal energy storage materials can be addressed by using microstructured composites. Using a eutectic mixture of lithium and sodium carbonates as molten salt, magnesium oxide as supporting material, and graphite as thermal conductivity enhancer, the microstructural development, chemical compatibility, thermal stability, thermal conductivity, and thermal energy storage performance of composite materials are investigated. The ceramic supporting material is essential for preventing salt leakage and hence provides a solution to the chemical incompatibility issue. The use of graphite gives a significant enhancement on the thermal conductivity of the composite. Analyses suggest that the experimentally observed microstructural development of the composite is associated with the wettability of the salt on the ceramic substrate and that on the thermal conduction enhancer. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  7. Design Considerations of a Solid State Thermal Energy Storage

    Science.gov (United States)

    Janbozorgi, Mohammad; Houssainy, Sammy; Thacker, Ariana; Ip, Peggy; Ismail, Walid; Kavehpour, Pirouz

    2016-11-01

    With the growing governmental restrictions on carbon emission, renewable energies are becoming more prevalent. A reliable use of a renewable source however requires a built-in storage to overcome the inherent intermittent nature of the available energy. Thermal design of a solid state energy storage has been investigated for optimal performance. The impact of flow regime, laminar vs. turbulent, on the design and sizing of the system is also studied. The implications of low thermal conductivity of the storage material are discussed and a design that maximizes the round trip efficiency is presented. This study was supported by Award No. EPC-14-027 Granted by California Energy Commission (CEC).

  8. CALORSTOCK'94. Thermal energy storage. Better economy, environment, technology

    International Nuclear Information System (INIS)

    Kangas, M.T.; Lund, P.D.

    1994-01-01

    This publication is the first volume of the proceedings of CALORSTOCK'94, the sixth international conference on thermal energy storage held in Espoo, Finland on August 22-25, 1994. This volume contains 58 presentations from the following six sessions: Aquifer storage, integration into energy systems, Simulation models and design tools, IEA energy conservation through energy storage programme workshop, Earth coupled storage, District heating and utilities

  9. Partition wall structure in spent fuel storage pool and construction method for the partition wall

    International Nuclear Information System (INIS)

    Izawa, Masaaki

    1998-01-01

    A partitioning wall for forming cask pits as radiation shielding regions by partitioning inside of a spent fuel storage pool is prepared by covering both surface of a concrete body by shielding metal plates. The metal plate comprises opposed plate units integrated by welding while sandwiching a metal frame as a reinforcing material for the concrete body, the lower end of the units is connected to a floor of a pool by fastening members, and concrete is set while using the metal plate of the units as a frame to form the concrete body. The shielding metal plate has a double walled structure formed by welding a lining plate disposed on the outer surface of the partition wall and a shield plate disposed to the inner side. Then the term for construction can be shortened, and the capacity for storing spent fuels can be increased. (N.H.)

  10. Analysis of Large- Capacity Water Heaters in Electric Thermal Storage Programs

    Energy Technology Data Exchange (ETDEWEB)

    Cooke, Alan L. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Anderson, David M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Winiarski, David W. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Carmichael, Robert T. [Cadeo Group, Washington D. C. (United States); Mayhorn, Ebony T. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Fisher, Andrew R. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2015-03-17

    This report documents a national impact analysis of large tank heat pump water heaters (HPWH) in electric thermal storage (ETS) programs and conveys the findings related to concerns raised by utilities regarding the ability of large-tank heat pump water heaters to provide electric thermal storage services.

  11. Electrochemical energy storage systems for solar thermal applications

    Science.gov (United States)

    Krauthamer, S.; Frank, H.

    1980-01-01

    Existing and advanced electrochemical storage and inversion/conversion systems that may be used with terrestrial solar-thermal power systems are evaluated. The status, cost and performance of existing storage systems are assessed, and the cost, performance, and availability of advanced systems are projected. A prime consideration is the cost of delivered energy from plants utilizing electrochemical storage. Results indicate that the five most attractive electrochemical storage systems are the: iron-chromium redox (NASA LeRC), zinc-bromine (Exxon), sodium-sulfur (Ford), sodium-sulfur (Dow), and zinc-chlorine (EDA).

  12. Flexural behavior and design of steel-plate composite (SC) walls for accident thermal loading

    Energy Technology Data Exchange (ETDEWEB)

    Booth, Peter N., E-mail: boothpn@purdue.edu [Lyles School of Civil Engineering, Purdue University, West Lafayette, IN (United States); Varma, Amit H., E-mail: ahvarma@purdue.edu [Lyles School of Civil Engineering, Purdue University, West Lafayette, IN (United States); Sener, Kadir C., E-mail: ksener@purdue.edu [Lyles School of Civil Engineering, Purdue University, West Lafayette, IN (United States); Malushte, Sanjeev R. [Bechtel Corp., Frederick, MD (United States)

    2015-12-15

    Modular steel-plate composite (SC) safety-related nuclear power plant structures must be designed to resist accident thermal and mechanical loads. The design accident thermal load represents the condition where high pressure and temperature steam is released as result of a mechanical failure and applied against the surfaces of power plant structural walls. The effect of heating and pressure can have both short and long term effects on the mechanical integrity of SC structures including degradation and cracking of concrete infill, residual stresses, and out-of-plane deformations. The purpose of this research is to study the effects of thermal and mechanical loads on the out-of-plane flexural response of SC walls and to develop simplified equations that can be used to predict behavior. Four experimental beam tests are reported that represent full-scale cross-sections of SC walls subjected to combinations of mechanical and thermal loads. The study determined that thermal loads reduce the out-of-plane flexural stiffness of SC walls. For the ambient condition, the flexural stiffness closely matches a conventional elastic cracked-transformed model, and at elevated temperatures, the stiffness is reduced to a fully-cracked flexural stiffness that only takes into account the stiffness of the steel faceplates. A method is presented for estimating the thermal curvature, ϕ{sub th}, and thermal moment, M{sub th}, resulting from unequal heating of opposing faces of an SC wall. Based on the tests in this study, the application of accident thermal loads did not result in a reduction of the flexural strength of the SC section.

  13. Effective thermal conductivity and diffusivity of containment wall for nuclear power plant OPR1000

    Energy Technology Data Exchange (ETDEWEB)

    Noh, Hyung Gyun; Park, Hyun Sun [Div. of Advanced Nuclear Engineering (DANE), Pohang University of Science and Technology (POSTECH), Pohang (Korea, Republic of); Lee, Jong Hwi; Kang, Hie Chan [Mechanical Engineering Div., Kunsan National University (KNU), Gunsan (Korea, Republic of)

    2017-04-15

    The goal of this study is to evaluate the effective thermal conductivity and diffusivity of containment walls as heat sinks or passive cooling systems during nuclear power plant (NPP) accidents. Containment walls consist of steel reinforced concrete, steel liners, and tendons, and provide the main thermal resistance of the heat sinks, which varies with the volume fraction and geometric alignment of the rebar and tendons, as well as the temperature and chemical composition. The target geometry for the containment walls of this work is the standard Korean NPP OPR1000. Sample tests and numerical simulations are conducted to verify the correlations for models with different densities of concrete, volume fractions, and alignments of steel. Estimation of the effective thermal conductivity and diffusivity of the containment wall models is proposed. The Maxwell model and modified Rayleigh volume fraction model employed in the present work predict the experiment and finite volume method (FVM) results well. The effective thermal conductivity and diffusivity of the containment walls are summarized as functions of density, temperature, and the volume fraction of steel for the analysis of the NPP accidents.

  14. Evaluation of Strategies to Improve the Thermal Performance of Steel Frames in Curtain Wall Systems

    Directory of Open Access Journals (Sweden)

    Ji Hyun Oh

    2016-12-01

    Full Text Available Recently, metal curtain wall systems have been widely used in high-rise buildings due to many advantages, including being lightweight, rapid construction, and aesthetic features. Since the metal frame may lead to lower energy performance, thermal discomfort, and condensation risk due to the high thermal conductivity, its thermal performance can be important for the improvement of the overall thermal performance of the curtain wall system, as well as the energy efficiency of the building envelope. This study aims to evaluate variety of design strategies to improve the thermal performance of steel curtain wall frames. Five base cases and three further steps were selected for two different head profile shapes based on a state-of-the art technology review, and their thermal transmittances were calculated through simulations according to the ISO 12631 standard which is an international standard for calculating thermal transmittance of curtain wall system. Measured results that were obtained from hot-box tests were compared with the calculated results to validate the simulation method of this study. The shape of the head profile did not strongly influence the overall thermal transmittance, and the choice of strategies for the rabbet space was more important. More effective strategies could be decided according to the steps for variation development. This result can serve as a guideline for the design of high-performance curtain wall frames.

  15. Program definition and assessment overview. [for thermal energy storage project management

    Science.gov (United States)

    Gordon, L. H.

    1980-01-01

    The implementation of a program level assessment of thermal energy storage technology thrusts for the near and far term to assure overall coherent energy storage program is considered. The identification and definition of potential thermal energy storage applications, definition of technology requirements, and appropriate market sectors are discussed along with the necessary coordination, planning, and preparation associated with program reviews, workshops, multi-year plans and annual operating plans for the major laboratory tasks.

  16. Temperature Distribution and Thermal Performance of an Aquifer Thermal Energy Storage System

    Science.gov (United States)

    Ganguly, Sayantan

    2017-04-01

    Energy conservation and storage has become very crucial to make use of excess energy during times of future demand. Excess thermal energy can be captured and stored in aquifers and this technique is termed as Aquifer Thermal Energy Storage (ATES). Storing seasonal thermal energy in water by injecting it into subsurface and extracting in time of demand is the principle of an ATES system. Using ATES systems leads to energy savings, reduces the dependency on fossil fuels and thus leads to reduction in greenhouse gas emission. This study numerically models an ATES system to store seasonal thermal energy and evaluates the performance of it. A 3D thermo-hydrogeological numerical model for a confined ATES system is presented in this study. The model includes heat transport processes of advection, conduction and heat loss to confining rock media. The model also takes into account regional groundwater flow in the aquifer, geothermal gradient and anisotropy in the aquifer. Results show that thermal injection into the aquifer results in the generation of a thermal-front which grows in size with time. Premature thermal-breakthrough causes thermal interference in the system when the thermal-front reaches the production well and consequences in the fall of system performance and hence should be avoided. This study models the transient temperature distribution in the aquifer for different flow and geological conditions. This may be effectively used in designing an efficient ATES project by ensuring safety from thermal-breakthrough while catering to the energy demand. Based on the model results a safe well spacing is proposed. The thermal energy discharged by the system is determined and strategy to avoid the premature thermal-breakthrough in critical cases is discussed. The present numerical model is applied to simulate an experimental field study which is found to approximate the field results quite well.

  17. Thermoelectric cooling in combination with photovoltaics and thermal energy storage

    Directory of Open Access Journals (Sweden)

    Skovajsa Jan

    2017-01-01

    Full Text Available The article deals with the use of modern technologies that can improve the thermal comfort in buildings. The article describes the usage of thermal energy storage device based on the phase change material (PCM. The technology improves the thermal capacity of the building and it is possible to use it for active heating and cooling. It is designed as a “green technology” so it is able to use renewable energy sources, e.g., photovoltaic panels, solar thermal collectors, and heat pump. Moreover, an interesting possibility is the ability to use thermal energy storage in combination with a photovoltaic system and thermoelectric coolers. In the research, there were made measurements of the different operating modes and the results are presented in the text.

  18. Advanced high-temperature thermal energy storage media for industrial applications

    Science.gov (United States)

    Claar, T. D.; Waibel, R. T.

    1982-02-01

    An advanced thermal energy storage media concept based on use of carbonate salt/ceramic composite materials is being developed for industrial process and reject heat applications. The composite latent/sensible media concept and its potential advantages over state of the art latent heat systems is described. Media stability requirements, on-going materials development efforts, and planned thermal energy storage (TES) performance evaluation tests are discussed.

  19. Improved thermal storage material for portable life support systems

    Science.gov (United States)

    Kellner, J. D.

    1975-01-01

    The availability of thermal storage materials that have heat absorption capabilities substantially greater than water-ice in the same temperature range would permit significant improvements in performance of projected portable thermal storage cooling systems. A method for providing increased heat absorption by the combined use of the heat of solution of certain salts and the heat of fusion of water-ice was investigated. This work has indicated that a 30 percent solution of potassium bifluoride (KHF2) in water can absorb approximately 52 percent more heat than an equal weight of water-ice, and approximately 79 percent more heat than an equal volume of water-ice. The thermal storage material can be regenerated easily by freezing, however, a lower temperature must be used, 261 K as compared to 273 K for water-ice. This work was conducted by the United Aircraft Research Laboratories as part of a program at Hamilton Standard Division of United Aircraft Corporation under contract to NASA Ames Research Center.

  20. DNS, LES and RANS of turbulent heat transfer in boundary layer with suddenly changing wall thermal conditions

    International Nuclear Information System (INIS)

    Hattori, Hirofumi; Yamada, Shohei; Tanaka, Masahiro; Houra, Tomoya; Nagano, Yasutaka

    2013-01-01

    Highlights: • We study the turbulent boundary layer with heat transfer by DNS. • Turbulent boundary layers with suddenly changing wall thermal conditions are observed. • The detailed turbulent statistics and structures in turbulent thermal boundary layer are discussed. • Turbulence models in LES and RANS are evaluated using DNS results. • LES and RANS are almost in good agreement with DNS results. -- Abstract: The objectives of this study are to investigate a thermal field in a turbulent boundary layer with suddenly changing wall thermal conditions by means of direct numerical simulation (DNS), and to evaluate predictions of a turbulence model in such a thermal field, in which DNS of spatially developing boundary layers with heat transfer can be conducted using the generation of turbulent inflow data as a method. In this study, two types of wall thermal condition are investigated using DNS and predicted by large eddy simulation (LES) and Reynolds-averaged Navier–Stokes equation simulation (RANS). In the first case, the velocity boundary layer only develops in the entrance of simulation, and the flat plate is heated from the halfway point, i.e., the adiabatic wall condition is adopted in the entrance, and the entrance region of thermal field in turbulence is simulated. Then, the thermal boundary layer develops along a constant temperature wall followed by adiabatic wall. In the second case, velocity and thermal boundary layers simultaneously develop, and the wall thermal condition is changed from a constant temperature to an adiabatic wall in the downstream region. DNS results clearly show the statistics and structure of turbulent heat transfer in a constant temperature wall followed by an adiabatic wall. In the first case, the entrance region of thermal field in turbulence can be also observed. Thus, both the development and the entrance regions in thermal fields can be explored, and the effects upstream of the thermal field on the adiabatic region are

  1. Thermal energy storage for CSP (Concentrating Solar Power)

    Science.gov (United States)

    Py, Xavier; Sadiki, Najim; Olives, Régis; Goetz, Vincent; Falcoz, Quentin

    2017-07-01

    The major advantage of concentrating solar power before photovoltaic is the possibility to store thermal energy at large scale allowing dispatchability. Then, only CSP solar power plants including thermal storage can be operated 24 h/day using exclusively the solar resource. Nevertheless, due to a too low availability in mined nitrate salts, the actual mature technology of the two tanks molten salts cannot be applied to achieve the expected international share in the power production for 2050. Then alternative storage materials are under studies such as natural rocks and recycled ceramics made from industrial wastes. The present paper is a review of those alternative approaches.

  2. Thermal energy storage for CSP (Concentrating Solar Power

    Directory of Open Access Journals (Sweden)

    Py Xavier

    2017-01-01

    Full Text Available The major advantage of concentrating solar power before photovoltaic is the possibility to store thermal energy at large scale allowing dispatchability. Then, only CSP solar power plants including thermal storage can be operated 24 h/day using exclusively the solar resource. Nevertheless, due to a too low availability in mined nitrate salts, the actual mature technology of the two tanks molten salts cannot be applied to achieve the expected international share in the power production for 2050. Then alternative storage materials are under studies such as natural rocks and recycled ceramics made from industrial wastes. The present paper is a review of those alternative approaches.

  3. High temperature underground thermal energy storage system for solar energy

    Science.gov (United States)

    Collins, R. E.

    1980-01-01

    The activities feasibility of high temperature underground thermal storage of energy was investigated. Results indicate that salt cavern storage of hot oil is both technically and economically feasible as a method of storing huge quantities of heat at relatively low cost. One particular system identified utilizes a gravel filled cavern leached within a salt dome. Thermal losses are shown to be less than one percent of cyclically transferred heat. A system like this having a 40 MW sub t transfer rate capability and over eight hours of storage capacity is shown to cost about $13.50 per KWh sub t.

  4. Transient analysis of a thermal storage unit involving a phase change material

    Science.gov (United States)

    Griggs, E. I.; Pitts, D. R.; Humphries, W. R.

    1974-01-01

    The transient response of a single cell of a typical phase change material type thermal capacitor has been modeled using numerical conductive heat transfer techniques. The cell consists of a base plate, an insulated top, and two vertical walls (fins) forming a two-dimensional cavity filled with a phase change material. Both explicit and implicit numerical formulations are outlined. A mixed explicit-implicit scheme which treats the fin implicity while treating the phase change material explicitly is discussed. A band algorithmic scheme is used to reduce computer storage requirements for the implicit approach while retaining a relatively fine grid. All formulations are presented in dimensionless form thereby enabling application to geometrically similar problems. Typical parametric results are graphically presented for the case of melting with constant heat input to the base of the cell.

  5. Thermal energy storage in granular deposits

    Science.gov (United States)

    Ratuszny, Paweł

    2017-10-01

    Energy storage technology is crucial for the development of the use of renewable energy sources. This is a substantial constraint, however it can, to some extent, be solved by storing energy in its various forms: electrical, mechanical, chemical and thermal. This article presents the results of research in thermal properties of granular deposits. Correlation between temperature changes in the stores over a period of time and their physical properties has been studied. The results of the research have practical application in designing thermal stores based on bulk materials and ground deposits. Furthermore, the research results are significant for regeneration of the lower ground sources for heat pumps and provide data for designing ground heat exchangers for ventilation systems.

  6. COBRA-SFS thermal analysis of a sealed storage cask for the Monitored Retrievable Storage of spent fuel

    International Nuclear Information System (INIS)

    Rector, D.R.; Wheeler, C.L.

    1986-01-01

    The COBRA-SFS (Spent Fuel Storage) computer code was used to predict temperature distributions in a concrete Sealed Storage Cask (SSC). This cask was designed for the Department of Energy in the Monitored Retrievable Storage (MRS) program for storage of spent fuel from commercial power operations. Analytical results were obtained for nominal operation of the SSC with spent fuel from 36 PWR fuel assemblies consolidated in 12 cylindrical canisters. Each canister generates 1650 W of thermal power. A parametric study was performed to assess the effects on cask thermal performance of thermal conductivity of the concrete, the fin material, and the amount of radial reinforcing steel bars (rebar). Seven different cases were modeled. The results of the COBRA-SFS analysis of the current cask design predict that the peak fuel cladding temperature in the SSC will not exceed the 37 0 C design limit for the maximum spent fuel load of 19.8 kW and a maximum expected ambient temperature of 37.8 0 C (100 0 F). The results of the parametric analyses illustrate the importance of material selection and design optimization with regard to the SSC thermal performance

  7. Thermal performance analysis of a phase change thermal storage unit for space heating

    Energy Technology Data Exchange (ETDEWEB)

    Halawa, E.; Saman, W. [Institute for Sustainable Systems and Technologies School of Advanced Manufacturing and Mechanical Engineering, University of South Australia, Mawson Lakes SA 5095 (Australia)

    2011-01-15

    This paper presents the results of a comprehensive numerical study on the thermal performance of an air based phase change thermal storage unit (TSU) for space heating. The unit is designed for integration into space heating and cooling systems. The unit consists of a number of one dimensional phase change material (PCM) slabs contained in a rectangular duct where air passes between the slabs. The numerical analysis was based on an experimentally validated model. A parametric study has been carried out including the study on the effects of charge and discharge temperature differences, air mass flow rate, slab thicknesses, air gaps and slab dimensions on the air outlet temperatures and heat transfer rates of the thermal storage unit. The paper introduces and discusses quantities called charge and discharge temperature differences which play an important role in the melting and freezing processes. (author)

  8. Trial production of ceramic heat storage unit and study on thermal properties and thermal characteristics of the heat storage unit. Mixed salts of Na2CO3, MgCl2 and CaCl2 as heat storage medium

    International Nuclear Information System (INIS)

    Shiina, Yasuaki

    1998-12-01

    Heat storage technique of high temperature and high density latent heat can be applied to an accumulator of heat generated by nuclear power plant in the night and to a thermal load absorber. For the practical use of the heat storage technique, it is important to improve heat exchange characteristics between heat storage medium, such as molten salts, and heat transfer fluid because of low thermal conductivity of the molten salts, to improve durability among molten salt and structure materials and to develop the molten salt with stable thermal properties for a long period. Considering the possibility for the improvement of heat exchange characteristics of phase change heat storage system by absorbing molten salt in porous ceramics with high thermal conductivity, high temperature proof and high resistance to corrosion, several samples of the ceramics heat storage unit were made. Basic characteristics of the samples (strength, thermal properties, temperature characteristics during phase change) were measured experimentally and analytically to study the utility and applicability of the samples for the heat storage system. The results show that the heat storage unit should be used in inactive gas condition because water in the air absorbed in the molten salts would yield degeneration of properties and deterioration of strength and that operation temperature should be confined near fusion temperature because some molten salts would be vaporized and mass would be decreased in considerable high temperature. The results also show that when atmospheric temperature changes around the melting temperature, change in ceramic temperature becomes small. This result suggests the possibility that ceramic heat storage unit could be used as thermal load absorber. (J.P.N.)

  9. Molten salt thermal energy storage systems: salt selection

    Energy Technology Data Exchange (ETDEWEB)

    Maru, H.C.; Dullea, J.F.; Huang, V.S.

    1976-08-01

    A research program aimed at the development of a molten salt thermal energy storage system commenced in June 1976. This topical report describes Work performed under Task I: Salt Selection is described. A total of 31 inorganic salts and salt mixtures, including 9 alkali and alkaline earth carbonate mixtures, were evaluated for their suitability as heat-of-fusion thermal energy storage materials at temperatures of 850 to 1000/sup 0/F. Thermophysical properties, safety hazards, corrosion, and cost of these salts were compared on a common basis. We concluded that because alkali carbonate mixtures show high thermal conductivity, low volumetric expansion on melting, low corrosivity and good stability, they are attractive as heat-of-fusion storage materials in this temperature range. A 35 wt percent Li/sub 2/CO/sub 3/-65 wt percent K/sub 2/CO/sub 3/ (50 mole percent Li/sub 2/CO/sub 3/-50 mole percent K/sub 2/CO/sub 3/) mixture was selected as a model system for further experimental work. This is a eutectoid mixture having a heat of fusion of 148 Btu/lb (82 cal/g) that forms an equimolar compound, LiKCO/sub 3/. The Li/sub 2/CO/sub 3/-K/sub 2/CO/sub 3/ mixture is intended to serve as a model system to define heat transfer characteristics, potential problems, and to provide ''first-cut'' engineering data required for the prototype system. The cost of a thermal energy storage system containing this mixture cannot be predicted until system characteristics are better defined. However, our comparison of different salts indicated that alkali and alkaline earth chlorides may be more attractive from a salt cost point of view. The long-term corrosion characteristics and the effects of volume change on melting for the chlorides should be investigated to determine their overall suitability as a heat-of-fusion storage medium.

  10. Thermal energy storages analysis for high temperature in air solar systems

    International Nuclear Information System (INIS)

    Andreozzi, Assunta; Buonomo, Bernardo; Manca, Oronzio; Tamburrino, Salvatore

    2014-01-01

    In this paper a high temperature thermal storage in a honeycomb solid matrix is numerically investigated and a parametric analysis is accomplished. In the formulation of the model it is assumed that the system geometry is cylindrical, the fluid and the solid thermo physical properties are temperature independent and radiative heat transfer is taken into account whereas the effect of gravity is neglected. Air is employed as working fluid and the solid material is cordierite. The evaluation of the fluid dynamic and thermal behaviors is accomplished assuming the honeycomb as a porous medium. The Brinkman–Forchheimer–extended Darcy model is used in the governing equations and the local thermal non equilibrium is assumed. The commercial CFD Fluent code is used to solve the governing equations in transient regime. Numerical simulations are carried out with storage medium for different mass flow rates of the working fluid and different porosity values. Results in terms of temperature profiles, temperatures fields and stored thermal energy as function of time are presented. The effects of storage medium, different porosity values and mass flow rate on stored thermal energy and storage time are shown. - Highlights: • HTTES in a honeycomb solid matrix is numerically investigated. • The numerical analysis is carried out assuming the honeycomb as a porous medium. • The Brinkman–Forchheimer–extended Darcy model is used in the governing equations. • Results are carried out for different mass flow rates and porosity values. • The main effect is due to the porosity which set the thermal energy storage value

  11. Optically-controlled long-term storage and release of thermal energy in phase-change materials

    OpenAIRE

    Han, Grace G. D.; Li, Huashan; Grossman, Jeffrey C.

    2017-01-01

    Thermal energy storage offers enormous potential for a wide range of energy technologies. Phase-change materials offer state-of-the-art thermal storage due to high latent heat. However, spontaneous heat loss from thermally charged phase-change materials to cooler surroundings occurs due to the absence of a significant energy barrier for the liquid–solid transition. This prevents control over the thermal storage, and developing effective methods to address this problem has remained an elusive ...

  12. Effective Thermal Conductivity and Diffusivity of Containment Wall for Nuclear Power Plant OPR1000

    Directory of Open Access Journals (Sweden)

    Hyung Gyun Noh

    2017-04-01

    Full Text Available The goal of this study is to evaluate the effective thermal conductivity and diffusivity of containment walls as heat sinks or passive cooling systems during nuclear power plant (NPP accidents. Containment walls consist of steel reinforced concrete, steel liners, and tendons, and provide the main thermal resistance of the heat sinks, which varies with the volume fraction and geometric alignment of the rebar and tendons, as well as the temperature and chemical composition. The target geometry for the containment walls of this work is the standard Korean NPP OPR1000. Sample tests and numerical simulations are conducted to verify the correlations for models with different densities of concrete, volume fractions, and alignments of steel. Estimation of the effective thermal conductivity and diffusivity of the containment wall models is proposed. The Maxwell model and modified Rayleigh volume fraction model employed in the present work predict the experiment and finite volume method (FVM results well. The effective thermal conductivity and diffusivity of the containment walls are summarized as functions of density, temperature, and the volume fraction of steel for the analysis of the NPP accidents.

  13. Thermal Energy Storage with Phase Change Material

    Directory of Open Access Journals (Sweden)

    Lavinia Gabriela SOCACIU

    2012-08-01

    Full Text Available Thermal energy storage (TES systems provide several alternatives for efficient energy use and conservation. Phase change materials (PCMs for TES are materials supplying thermal regulation at particular phase change temperatures by absorbing and emitting the heat of the medium. TES in general and PCMs in particular, have been a main topic in research for the last 30 years, but although the information is quantitatively enormous, it is also spread widely in the literature, and difficult to find. PCMs absorb energy during the heating process as phase change takes place and release energy to the environment in the phase change range during a reverse cooling process. PCMs possesses the ability of latent thermal energy change their state with a certain temperature. PCMs for TES are generally solid-liquid phase change materials and therefore they need encapsulation. TES systems using PCMs as a storage medium offers advantages such as high TES capacity, small unit size and isothermal behaviour during charging and discharging when compared to the sensible TES.

  14. Selection of materials with potential in sensible thermal energy storage

    International Nuclear Information System (INIS)

    Fernandez, A.I.; Martinez, M.; Segarra, M.; Martorell, I.; Cabeza, L.F.

    2010-01-01

    Thermal energy storage is a technology under investigation since the early 1970s. Since then, numerous new applications have been found and much work has been done to bring this technology to the market. Nevertheless, the materials used either for latent or for sensible storage were mostly investigated 30 years ago, and the research has lead to improvement in their performance under different conditions of applications. In those years a significant number of new materials were developed in many fields other than storage and energy, but a great effort to characterize and classify these materials was done. Taking into account the fact that thousands of materials are known and a large number of new materials are developed every year, the authors use the methodology for materials selection developed by Prof. Ashby to give an overview of other materials suitable to be used in thermal energy storage. Sensible heat storage at temperatures between 150 and 200 C is defined as a case study and two different scenarios were considered: long term sensible heat storage and short term sensible heat storage. (author)

  15. Thermal reservoir sizing for adiabatic compressed air energy storage

    Energy Technology Data Exchange (ETDEWEB)

    Kere, Amelie; Goetz, Vincent; Py, Xavier; Olives, Regis; Sadiki, Najim [Perpignan Univ. (France). PROMES CNRS UPR 8521; Mercier-Allart, Eric [EDF R et D, Chatou (France)

    2012-07-01

    Despite the operation of the two existing industrial facilities to McIntosh (Alabama), and for more than thirty years, Huntorf (Germany), electricity storage in the form of compressed air in underground cavern (CAES) has not seen the development that was expected in the 80s. The efficiency of this form of storage was with the first generation CAES, less than 50%. The evolving context technique can significantly alter this situation. The new generation so-called Adiabatic CAES (A-CAES) is to retrieve the heat produced by the compression via thermal storage, thus eliminating the necessity of gas to burn and would allow consideration efficiency overall energy of the order of 70%. To date, there is no existing installation of A-CAES. Many studies describe the principal and the general working mode of storage systems by adiabatic compression of air. So, efficiencies of different configurations of adiabatic compression process were analyzed. The aim of this paper is to simulate and analyze the performances of a thermal storage reservoir integrated in the system and adapted to the working conditions of a CAES.

  16. Optimal controls of building storage systems using both ice storage and thermal mass – Part II: Parametric analysis

    International Nuclear Information System (INIS)

    Hajiah, Ali; Krarti, Moncef

    2012-01-01

    Highlights: ► A detailed analysis is presented to assess the performance of thermal energy storage (TES) systems. ► Utility rates have been found to be significant in assessing the operation of TES systems. ► Optimal control strategies for TES systems can save up to 40% of total energy cost of office buildings. - Abstract: This paper presents the results of a series of parametric analysis to investigate the factors that affect the effectiveness of using simultaneously building thermal capacitance and ice storage system to reduce total operating costs (including energy and demand costs) while maintaining adequate occupant comfort conditions in buildings. The analysis is based on a validated model-based simulation environment and includes several parameters including the optimization cost function, base chiller size, and ice storage tank capacity, and weather conditions. It found that the combined use of building thermal mass and active thermal energy storage system can save up to 40% of the total energy costs when integrated optimal control are considered to operate commercial buildings.

  17. Performance Assessment of Low-Temperature Thermal Storage with Electromagnetic Control

    Directory of Open Access Journals (Sweden)

    Ya-Wei Lee

    2014-08-01

    Full Text Available This study presents electromagnetic-controlled thermal storage (ECTS that can be directly implemented in strategies of low-temperature waste heat recovery for energy-consuming equipment. A magnetic nanofluid (MNF prepared from fine iron ferrite ferromagnetic particles is recommended as a latent heat medium (LHM. During electromagnetic induction, local flow fluctuations are generated and thermal convection in the MNF can be enhanced. The achieved results demonstrated that ECTS has a wide operational range and an optimum storage efficiency of 84.46%. Thus, a self-perturbation mode used to enhance thermal energy transportation can be designed for numerous waste heat management applications.

  18. Performance analysis of an integrated energy storage and energy upgrade thermochemical solid–gas sorption system for seasonal storage of solar thermal energy

    International Nuclear Information System (INIS)

    Li, Tingxian; Wang, Ruzhu; Kiplagat, Jeremiah K.; Kang, YongTae

    2013-01-01

    An innovative dual-mode thermochemical sorption energy storage method is proposed for seasonal storage of solar thermal energy with little heat losses. During the charging phase in summer, solar thermal energy is stored in form of chemical bonds resulting from thermochemical decomposition process, which enables the stored energy to be kept several months at ambient temperature. During the discharging phase in winter, the stored thermal energy is released in the form of chemical reaction heat resulting from thermochemical synthesis process. Thermodynamic analysis showed that the advanced dual-mode thermochemical sorption energy storage is an effective method for the long-term seasonal storage of solar energy. A coefficient of performance (COP h ) of 0.6 and energy density higher than 1000 kJ/kg of salt can be attained from the proposed system. During the discharging phase at low ambient temperatures, the stored thermal energy can be upgraded by use of a solid–gas thermochemical sorption heat transformer cycle. The proposed thermochemical sorption energy storage has distinct advantages over the conventional sensible heat and latent heat storage, such as higher energy storage density, little heat losses, integrated energy storage and energy upgrade, and thus it can contribute to improve the seasonal utilization of solar thermal energy. - Highlights: ► A dual-mode solid thermochemical sorption is proposed for seasonal solar thermal energy storage. ► Energy upgrade techniques into the energy storage system are integrated. ► Performance of the proposed seasonal energy storage system is evaluated. ► Energy density and COP h from the proposed system are as high as 1043 kJ/kg of salt and 0.60, respectively

  19. Novel Thermal Storage Technologies for Concentrating Solar Power Generation

    Energy Technology Data Exchange (ETDEWEB)

    Neti, Sudhakar [Lehigh Univ., Bethlehem, PA (United States). Mechanical Engineering and Mechanics; Oztekin, Alparslan [Lehigh Univ., Bethlehem, PA (United States); Chen, John [Lehigh Univ., Bethlehem, PA (United States); Tuzla, Kemal [Lehigh Univ., Bethlehem, PA (United States); Misiolek, Wojciech [Lehigh Univ., Bethlehem, PA (United States)

    2013-06-20

    The technologies that are to be developed in this work will enable storage of thermal energy in 100 MWe solar energy plants for 6-24 hours at temperatures around 300°C and 850°C using encapsulated phase change materials (EPCM). Several encapsulated phase change materials have been identified, fabricated and proven with calorimetry. Two of these materials have been tested in an airflow experiment. A cost analysis for these thermal energy storage systems has also been conducted that met the targets established at the initiation of the project.

  20. Identification of thermal properties distribution in building wall using infrared thermography

    Science.gov (United States)

    Brouns, Jordan; Dumoulin, Jean

    2016-04-01

    In the construction sector, most of the measurements carried out from IR camera devices are exploited in a qualitative way (e.g. observation of thermal bridges). However, unless a quantitative analysis is realized, it is not possible to assess the impact of the observed phenomena. Most of research efforts and proposed solutions to identify quantified thermal properties (e.g. U-values) have to be completed, adapted to the built environment and validated in experimental and real conditions to allow quantified assessment of materials thermal properties thanks to IR camera devices [1]. We still need several steps in terms of scientific and technical developments for such technological progress. The H2020 European Built2Spec research project (http://built2spec-project.eu/) aims at giving highlights on that. Heat transfer through the walls are generally model by 1D heat equation in the wall depth. The built is composed by a multilayer domain representing the construction process. In this context, the thermal parameters of the wall are piecewise constant space functions. We propose a methodology to recover the vector of the wall thermal properties (conductivity and capacity) from boundary measurements obtained from an IR camera. It formulates as an inverse problem where the unknown are sought as minimizers of a cost function evaluating the gap between the measures and the model response. This optimization problem is non linear, and we solve it with the Levenberg-Marquardt algorithm coupled with the conjugate gradient method [2-3]. To shorten the time of the identification process, we use the adjoint method coming from the control theory [4]. This method fasten the gradient computation by solving an associated model, named the adjoint model. We study the ability of the procedure to reconstruct internal wall constitution from different environmental conditions. Furthermore, we propose a controlled experimental test to evaluate the method in laboratory conditions. References

  1. 'Eco-house 99' - Full-scale demonstration of solar walls with building integrated heat storages

    Energy Technology Data Exchange (ETDEWEB)

    Hummelshoej, R.M.; Rahbek, J.E. [COWI Consulting Engineers and Planners AS (Denmark)

    2000-07-01

    A critical issue for solar systems in northern latitudes is the economic profitability. It is often said that the techniques for solar utilisation are expensive and unprofitable. This is, however, not always the case. A new project with 59 low energy terrace houses was carried out in Kolding, Denmark. The houses are designed as ecological buildings with emphasis on total economy based on low operation and maintenance costs, energy conservation and passive/hybrid solar utilisation. Besides direct solar gain through windows, each house has a solar wall of 6-8.5 m{sup 2} on the south facade. The solar walls are used both for heating of ventilation air and for space heating. The solar walls deliver heat to the dwellings during the heating season. To optimise the energy utilisation from the solar walls, the energy is stored internally in building integrated heat storages. Two different new types of prefabricated heat storages are built into the houses. One is an internal concrete wall with embedded ventilation pipes, and the other is a hollow concrete element with integrated stone bed. The heat storages are mainly designed to store solar energy from the day to the evening and the night. Because the solar walls and the heat storages have been a part of the design process from the start, the additional expenses are as low as 30-140 Euro/m{sup 2} solar wall compared with the alternative facade. This is far less than what it costs to add a solar wall on an existing building. Measurements over one year show that the yield of the solar walls is in the range of 115-125 kWh/m{sup 2}/year as expected. With the actual financing, the annual payment of the additional expenses for the solar systems is between 1-6 Euro/m{sup 2} solar wall, while the annual savings are about 5 Euro/year/m{sup 2} (with an energy price of 0.042 Euro/kWh). Dependent on which alternative facade construction the solar wall system is compared with, the profit of the system is in the range of 1 to +4 Euro

  2. Critical phenomena and their effect on thermal energy storage in supercritical fluids

    International Nuclear Information System (INIS)

    Hobold, Gustavo M.; Da Silva, Alexandre K.

    2017-01-01

    Highlights: •High power thermal energy storage using supercritical fluids. •Influence of property variation on energy and power density. •Multi-fluid analysis and generalization for several storage temperatures. •Cost, heat transfer and energy density evaluation for high temperature storage. -- Abstract: Large-scale implementation of concentrated solar power plants requires energy storage systems if fossil sources are to be fully replaced. While several candidates have appeared, most still face major issues such as cost, limited energy density and material compatibility. The present paper explores the influence of property variation in the proximity of the critical point on thermal energy storage using supercritical fluids (sTES) from thermodynamic and heat transfer standpoints. Influence of thermodynamic operational parameters on energy density of isobaric and isochoric sTES and their optima is discussed, showing that the energy density results from a competition between average specific heat and loaded density. Moreover, sTES is shown to be applicable to virtually any storage temperature, depending only on the fluid’s critical point. Finally, a heat transfer and energy density comparison to other existing storage mechanisms is presented and supercritical water is shown to be competitive for high temperature thermal energy storage.

  3. Thermal analysis elements of liquefied gas storage tanks

    Science.gov (United States)

    Yanvarev, I. A.; Krupnikov, A. V.

    2017-08-01

    Tasks of solving energy and resource efficient usage problems, both for oil producing companies and for companies extracting and transporting natural gas, are associated with liquefied petroleum gas technology development. Improving the operation efficiency of liquefied products storages provides for conducting structural, functional, and appropriate thermal analysis of tank parks in the general case as complex dynamic thermal systems.

  4. Adsorption thermal energy storage for cogeneration in industrial batch processes: Experiment, dynamic modeling and system analysis

    International Nuclear Information System (INIS)

    Schreiber, Heike; Graf, Stefan; Lanzerath, Franz; Bardow, André

    2015-01-01

    Adsorption thermal energy storage is investigated for heat supply with cogeneration in industrial batch processes. The feasibility of adsorption thermal energy storage is demonstrated with a lab-scale prototype. Based on these experiments, a dynamic model is developed and successfully calibrated to measurement data. Thereby, a reliable description of the dynamic behavior of the adsorption thermal energy storage unit is achieved. The model is used to study and benchmark the performance of adsorption thermal energy storage combined with cogeneration for batch process energy supply. As benchmark, we consider both a peak boiler and latent thermal energy storage based on a phase change material. Beer brewing is considered as an example of an industrial batch process. The study shows that adsorption thermal energy storage has the potential to increase energy efficiency significantly; primary energy consumption can be reduced by up to 25%. However, successful integration of adsorption thermal storage requires appropriate integration of low grade heat: Preferentially, low grade heat is available at times of discharging and in demand when charging the storage unit. Thus, adsorption thermal energy storage is most beneficial if applied to a batch process with heat demands on several temperature levels. - Highlights: • A highly efficient energy supply for industrial batch processes is presented. • Adsorption thermal energy storage (TES) is analyzed in experiment and simulation. • Adsorption TES can outperform both peak boilers and latent TES. • Performance of adsorption TES strongly depends on low grade heat temperature.

  5. Experimental and theoretic investigations of thermal behavior of a seasonal water pit heat storage

    DEFF Research Database (Denmark)

    Fan, Jianhua; Huang, Junpeng; Chatzidiakos, Angelos

    Seasonal heat storages are considered essential for district heating systems because they offer flexibility for the system to integrate different fluctuating renewable energy sources. Water pit thermal storages (PTES) have been successfully implemented in solar district heating plants in Denmark....... Thermal behavior of a 75,000 m3 water pit heat storage in Marstal solar heating plant was investigated experimentally and numerically. Temperatures at different levels of the water pit storage and temperatures at different depths of the ground around the storage were monitored and analyzed. A simulation...... model of the water pit storage is built to investigate development of temperatures in and around the storage. The calculated temperatures are compared to the monitored temperatures with an aim to validate the simulation model. Thermal stratification in the water pit heat storage and its interaction...

  6. Lauric Acid Hybridizing Fly Ash Composite for Thermal Energy Storage

    Directory of Open Access Journals (Sweden)

    Dawei Xu

    2018-04-01

    Full Text Available Fly ash includes different mineral phases. This paper reported on the preparation of a novel lauric acid (LA/fly ash (FA composite by vacuum impregnation as a form-stable phase change material (PCM for thermal energy, and especially investigated the effect of the hydrochloric acid-treated fly ash (FAh on the thermal energy storage performance of the composites. The morphology, crystalline structure, and porous textures of the samples were characterized by scanning electron microscopy (SEM, X-ray diffraction (XRD, Brunauer–Emmett–Teller (BET, X-ray fluorescence (XRF, and differential scanning calorimetry (DSC. The results indicated that hydrochloric acid treatment was beneficial to the increase of loading capacity and crystallinity of LA in the LA/FAh composite, which caused an enhanced thermal storage capacity with latent heats for melting and freezing of LA/FAh (80.94 and 77.39 J/g, higher than those of LA/FA (34.09 and 32.97 J/g, respectively. Furthermore, the mechanism of enhanced thermal storage properties was investigated in detail.

  7. Experimental investigation into a packed bed thermal storage solution for solar gas turbine systems

    CSIR Research Space (South Africa)

    Klein, P

    2013-09-01

    Full Text Available High temperature thermal storage in randomly packed beds of ceramic particles is proposed as an effective storage solution for Solar Gas Turbine (SGT) cycles in the near term. Numerical modelling of these systems allows for optimised thermal storage...

  8. The energy efficiency ratio of heat storage in one shell-and-one tube phase change thermal energy storage unit

    International Nuclear Information System (INIS)

    Wang, Wei-Wei; Wang, Liang-Bi; He, Ya-Ling

    2015-01-01

    Highlights: • A parameter to indicate the energy efficiency ratio of PCTES units is defined. • The characteristics of the energy efficiency ratio of PCTES units are reported. • A combined parameter of the physical properties of the working mediums is found. • Some implications of the energy efficiency ratio in design of PCTES units are analyzed. - Abstract: From aspect of energy consuming to pump heat transfer fluid, there is no sound basis on which to create an optimum design of a thermal energy storage unit. Thus, it is necessary to develop a parameter to indicate the energy efficiency of such unit. This paper firstly defines a parameter that indicates the ratio of heat storage of phase change thermal energy storage unit to energy consumed in pumping heat transfer fluid, which is called the energy efficiency ratio, then numerically investigates the characteristics of this parameter. The results show that the energy efficiency ratio can clearly indicate the energy efficiency of a phase change thermal energy storage unit. When the fluid flow of a heat transfer fluid is in a laminar state, the energy efficiency ratio is larger than in a turbulent state. The energy efficiency ratio of a shell-and-tube phase change thermal energy storage unit is more sensitive to the outer tube diameter. Under the same working conditions, within the heat transfer fluids studied, the heat storage property of the phase change thermal energy storage unit is best for water as heat transfer fluid. A combined parameter is found to indicate the effects of both the physical properties of phase change material and heat transfer fluid on the energy efficiency ratio

  9. Flexible operation of thermal plants with integrated energy storage technologies

    Science.gov (United States)

    Koytsoumpa, Efthymia Ioanna; Bergins, Christian; Kakaras, Emmanouil

    2017-08-01

    The energy system in the EU requires today as well as towards 2030 to 2050 significant amounts of thermal power plants in combination with the continuously increasing share of Renewables Energy Sources (RES) to assure the grid stability and to secure electricity supply as well as to provide heat. The operation of the conventional fleet should be harmonised with the fluctuating renewable energy sources and their intermittent electricity production. Flexible thermal plants should be able to reach their lowest minimum load capabilities while keeping the efficiency drop moderate as well as to increase their ramp up and down rates. A novel approach for integrating energy storage as an evolutionary measure to overcome many of the challenges, which arise from increasing RES and balancing with thermal power is presented. Energy storage technologies such as Power to Fuel, Liquid Air Energy Storage and Batteries are investigated in conjunction with flexible power plants.

  10. Performance of stratified thermal-storage system for Oliver Springs Elementary School. Progress report

    Energy Technology Data Exchange (ETDEWEB)

    Reid, R.L.; Bedinger, A.F.G.

    1981-01-01

    A progress report is given on the performance of a stratified thermal storage system coupled with a heat recovery refrigeration machine designed to provide space heating, cooling and service water heating. Water storage tanks utilizing a flexible membrane to resist temperature blending will be used as the thermal storage element. The two design goals of the heat recovery and thermal energy storage system are (1) to minimize the need to purchase energy for space heating and cooling and water heating and (2) to minimize electrical demand. An automatic data acquisition system will be used for system performance and data gathering. Data collection is expected to begin in September, 1981.

  11. Passive hygrothermal control of a museum storage building in Vejle

    DEFF Research Database (Denmark)

    Christensen, Jørgen Erik; Janssen, Hans

    2010-01-01

    and maintenance costs are currently motivating a paradigm change toward passive control. Passive control, via the thermal and hygric inertia of the building, is gaining a foothold in the museum conservation and building physical community. In this report we document the hygrothermal performance optimisation...... of a museum storage building, related to an existing storage centre in Vejle (Denmark). The current building design already incorporates passive control concepts: thermal inertia is provided by the thick walls, the ground floor and its underlying soil volume, while hygric inertia is provided by the thick...... with the thermal inertia of the ground and thus a higher temperature variation; For those reasons, more heavily insulated walls and roofs could be considered. Their effects on the interior climate and dehumidification load are however not that large. For the floor, no insulation should be added, and it could...

  12. Biogeochemical aspects of aquifer thermal energy storage

    NARCIS (Netherlands)

    Brons, H.J.

    1992-01-01

    During the process of aquifer thermal energy storage the in situ temperature of the groundwater- sediment system may fluctuate significantly. As a result the groundwater characteristics can be considerably affected by a variety of chemical, biogeochemical and microbiological

  13. Optically-controlled long-term storage and release of thermal energy in phase-change materials.

    Science.gov (United States)

    Han, Grace G D; Li, Huashan; Grossman, Jeffrey C

    2017-11-13

    Thermal energy storage offers enormous potential for a wide range of energy technologies. Phase-change materials offer state-of-the-art thermal storage due to high latent heat. However, spontaneous heat loss from thermally charged phase-change materials to cooler surroundings occurs due to the absence of a significant energy barrier for the liquid-solid transition. This prevents control over the thermal storage, and developing effective methods to address this problem has remained an elusive goal. Herein, we report a combination of photo-switching dopants and organic phase-change materials as a way to introduce an activation energy barrier for phase-change materials solidification and to conserve thermal energy in the materials, allowing them to be triggered optically to release their stored latent heat. This approach enables the retention of thermal energy (about 200 J g -1 ) in the materials for at least 10 h at temperatures lower than the original crystallization point, unlocking opportunities for portable thermal energy storage systems.

  14. Equivalent thermal conductivity of the storage basket with spent nuclear fuel of VVER-1000 reactors

    International Nuclear Information System (INIS)

    Alyokhina, Svitlana; Kostikov, Andriy

    2014-01-01

    Due to limitation of computation resources and/or computation time many thermal problems require to use simplified geometrical models with equivalent thermal properties. A new method for definition of equivalent thermal conductivity of spent nuclear fuel storage casks is proposed. It is based on solving the inverse heat conduction problem. For the proposed method two approaches for equivalent thermal conductivity definition were considered. In the first approach a simplified model in conjugate formulation is used, in the second approach a simplified model of solid body which allows an analytical solution is used. For safety ensuring during all time of spent nuclear fuel storage the equivalent thermal conductivity was calculated for different storage years. The calculated equivalent thermal conductivities can be used in thermal researches for dry spent nuclear fuel storage safety.

  15. Thermal resistances of air in cavity walls and their effect upon the thermal insulation performance

    Energy Technology Data Exchange (ETDEWEB)

    Bekkouche, S.M.A.; Cherier, M.K.; Hamdani, M.; Benamrane, N. [Application of Renewable Energies in Arid and Semi Arid Environments /Applied Research Unit on Renewable Energies/ EPST Development Center of Renewable Energies, URAER and B.P. 88, ZI, Gart Taam Ghardaia (Algeria); Benouaz, T. [University of Tlemcen, BP. 119, Tlemcen R.p. 13000 (Algeria); Yaiche, M.R. [Development Center of Renewable Energies, CDER and B.P 62, 16340, Route de l' Observatoire, Bouzareah, Algiers (Algeria)

    2013-07-01

    The optimum thickness in cavity walls in buildings is determined under steady conditions; the heat transfer has been calculated according to ISO 15099:2003. Two forms of masonry units are investigated to conclude the advantage of high thermal emissivity. The paper presents also some results from a study of the thermal insulation performance of air cavities bounded by thin reflective material layer 'eta = 0.05'. The results show that the most economical cavity configuration depends on the thermal emissivity and the insulation material used.

  16. Solar Thermal Energy Storage in a Photochromic Macrocycle.

    Science.gov (United States)

    Vlasceanu, Alexandru; Broman, Søren L; Hansen, Anne S; Skov, Anders B; Cacciarini, Martina; Kadziola, Anders; Kjaergaard, Henrik G; Mikkelsen, Kurt V; Nielsen, Mogens Brøndsted

    2016-07-25

    The conversion and efficient storage of solar energy is recognized to hold significant potential with regard to future energy solutions. Molecular solar thermal batteries based on photochromic systems exemplify one possible technology able to harness and apply this potential. Herein is described the synthesis of a macrocycle based on a dimer of the dihydroazulene/vinylheptafulvene (DHA/VHF) photo/thermal couple. By taking advantage of conformational strain, this DHA-DHA macrocycle presents an improved ability to absorb and store incident light energy in chemical bonds (VHF-VHF). A stepwise energy release over two sequential ring-closing reactions (VHF→DHA) combines the advantages of an initially fast discharge, hypothetically addressing immediate energy consumption needs, followed by a slow process for consistent, long-term use. This exemplifies another step forward in the molecular engineering and design of functional organic materials towards solar thermal energy storage and release. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  17. Radial force on the vacuum chamber wall during thermal quench in tokamaks

    Energy Technology Data Exchange (ETDEWEB)

    Pustovitov, V. D., E-mail: pustovitov-vd@nrcki.ru [National Research Centre Kurchatov Institute (Russian Federation)

    2015-12-15

    The radial force balance during a thermal quench in tokamaks is analyzed. As a rule, the duration τ{sub tp} of such events is much shorter than the resistive time τ{sub w} of the vacuum chamber wall. Therefore, the perturbations of the magnetic field B produced by the evolving plasma cannot penetrate the wall, which makes different the magnetic pressures on its inner and outer sides. The goal of this work is the analytical estimation of the resulting integral radial force on the wall. The plasma is considered axially symmetric; for the description of radial forces on the wall, the results of V.D. Shafranov’s classical work [J. Nucl. Energy C 5, 251 (1963)] are used. Developed for tokamaks, the standard equilibrium theory considers three interacting systems: plasma, poloidal field coils, and toroidal field coils. Here, the wall is additionally incorporated with currents driven by ∂B/∂t≠0 accompanying the fast loss of the plasma thermal energy. It is shown that they essentially affect the force redistribution, thereby leading to large loads on the wall. The estimates prove that these loads have to be accounted for in the disruptive scenarios in large tokamaks.

  18. Storage effects on anthocyanins, phenolics and antioxidant activity of thermally processed conventional and organic blueberries.

    Science.gov (United States)

    Syamaladevi, Roopesh M; Andrews, Preston K; Davies, Neal M; Walters, Thomas; Sablani, Shyam S

    2012-03-15

    Consumer demand for products rich in phytochemicals is increasing as a result of greater awareness of their potential health benefits. However, processed products are stored for long-term and the phytochemicals are susceptible to degradation during storage. The objective of this study was to assess the storage effects on phytochemicals in thermally processed blueberries. Thermally processed canned berries and juice/puree were analysed for phytochemicals during their long-term storage. The phytochemical retention of thermally processed blueberries during storage was not influenced by production system (conventional versus organic). During 13 months of storage, total anthocyanins, total phenolics and total antioxidant activity in canned blueberry solids decreased by up to 86, 69 and 52% respectively. In canned blueberry syrup, total anthocyanins and total antioxidant activity decreased by up to 68 and 15% respectively, while total phenolic content increased by up to 117%. Similar trends in phytochemical content were observed in juice/puree stored for 4 months. The extent of changes in phytochemicals of thermally processed blueberries during storage was significantly influenced by blanching. Long-term storage of thermally processed blueberries had varying degrees of influence on degradation of total anthocyanins, total phenolics and total antioxidant activity. Blanching before thermal processing helped to preserve the phytochemicals during storage of blueberries. Copyright © 2011 Society of Chemical Industry.

  19. High-temperature thermal storage systems for advanced solar receivers materials selections

    Science.gov (United States)

    Wilson, D. F.; Devan, J. H.; Howell, M.

    1990-01-01

    Advanced space power systems that use solar energy and Brayton or Stirling heat engines require thermal energy storage (TES) systems to operate continuously through periods of shade. The receiver storage units, key elements in both Brayton and Stirling systems, are designed to use the latent heat of fusion of phase-change materials (PCMs). The power systems under current consideration for near-future National Aeronautics and Space Administration space missions require working fluid temperatures in the 1100 to 1400 K range. The PCMs under current investigation that gave liquid temperatures within this range are the fluoride family of salts. However, these salts have low thermal conductivity, which causes large temperature gradients in the storage systems. Improvements can be obtained, however, with the use of thermal conductivity enhancements or metallic PCMs. In fact, if suitable containment materials can be found, the use of metallic PCMs would virtually eliminate the orbit associated temperature variations in TES systems. The high thermal conductivity and generally low volume change on melting of germanium and alloys based on silicon make them attractive for storage of thermal energy in space power systems. An approach to solving the containment problem, involving both chemical and physical compatibility, preparation of NiSi/NiSi2, and initial results for containment of germanium and NiSi/NiSi2, are presented.

  20. Influence of PCMs on thermal behavior of building walls: experimental study using the walls of a reduced scale room

    Directory of Open Access Journals (Sweden)

    Gounni Ayoub

    2017-01-01

    Full Text Available Using Phase-Change Materials (PCM for lightweight building applications can increase equivalent thermal mass and provide energy savings. In the present experimental work, the heat transfer performance testing of some building walls, with or without PCM, is carried out using a reduced-scale cubic room (the test-cell. The cubic cell is heated by an incandescent bulb placed on its centre, and it is housed in an air-conditioned large-scale room that allows to control the ambient air temperature. The effect of the double PCM layer and of its location relatively to the outside surface of the wall is tested and discussed in terms of overall transmitted heat flux and in terms of reduction of the inside and outside surface temperatures. Findings shows that the additional inertia introduced by the PCM leads to a reduced overall heat flux transmission by the wall and to a lesser daily temperature amplitude on the surface of the wall that enhances the thermal comfort inside the building. In the next step of this work, the case of sandwich walls with air gap, and with wood and PCM layers will be considered.

  1. Influence of PCMs on thermal behavior of building walls: experimental study using the walls of a reduced scale room

    Science.gov (United States)

    Gounni, Ayoub; Tahar Mabrouk, Mohamed; Kheiri, Abdelhamid; El alami, Mustapha

    2017-11-01

    Using Phase-Change Materials (PCM) for lightweight building applications can increase equivalent thermal mass and provide energy savings. In the present experimental work, the heat transfer performance testing of some building walls, with or without PCM, is carried out using a reduced-scale cubic room (the test-cell). The cubic cell is heated by an incandescent bulb placed on its centre, and it is housed in an air-conditioned large-scale room that allows to control the ambient air temperature. The effect of the double PCM layer and of its location relatively to the outside surface of the wall is tested and discussed in terms of overall transmitted heat flux and in terms of reduction of the inside and outside surface temperatures. Findings shows that the additional inertia introduced by the PCM leads to a reduced overall heat flux transmission by the wall and to a lesser daily temperature amplitude on the surface of the wall that enhances the thermal comfort inside the building. In the next step of this work, the case of sandwich walls with air gap, and with wood and PCM layers will be considered.

  2. Availability-based computer management of a cold thermal storage system

    International Nuclear Information System (INIS)

    Wong, K.F.V.; Ferrano, F.J.

    1990-01-01

    This paper reports on work to develop an availability-based, on-line expert system to manage a thermal energy storage air-conditioning system. The management system is designed to be used by mechanical engineers in the field of air-conditioning control and maintenance. Specifically, the expert system permits the user to easily monitor the second law of thermodynamics operating efficiencies of the major components and the system as a whole in addition to the daily scheduled operating parameters of a cold thermal storage system. Through the use of computer-generated and continually updated screen display pages, the user is permitted interaction with the expert system. The knowledge-based system is developed with a commercially available expert system shell that is resident in a personal computer. In the case studied, 130 various analog and binary inputs/outputs are used. The knowledge base for the thermal energy storage expert system included nine different display pages that are continually updated, 25 rules, three tasks, and three loops

  3. New kinds of energy-storing building composite PCMs for thermal energy storage

    International Nuclear Information System (INIS)

    Biçer, Alper; Sarı, Ahmet

    2013-01-01

    Graphical abstract: In this work, 10 new kinds of BCPCMs were prepared by blending of liquid xylitol pentalaurate (XPL) and xylitol pentamyristate (XPM) esters into gypsum, cement, diatomite, perlite and vermiculite. DSC results showed that the melting temperatures and energy storage capacities of the prepared BCPCMs are in range of about 40–55 °C and 31–126 J/g, respectively. TG investigations and thermal cycling test showed that the BCPCMs had good thermal endurance and thermal reliability. It can be also concluded that among the prepared 10 kinds materials, especially the BCPCMs including perlite, vermiculite, diatomite were found to better candidates for thermal energy storage applications in buildings due to the fact that they have relatively high heat storage ability. Highlights: ► New kinds BCPCMs were prepared by blending of liquid XPL and XPM esters with some building materials. ► The BCPCMs had suitable melting temperatures and energy storage capacities. ► Especially, the BCPCMs including perlite, vermiculite, diatomite were found to better candidates for thermal energy storage. - Abstract: Energy storing-composite phase change materials (PCMs) are significant means of thermal energy storage in buildings. Although several building composite PCMs (BCPCMs) have been developed in recent years, the additional investigations are still required to enrich the diversity of BCPCMs for solar heating and energy conservation applications in buildings. For this purpose, the present work is focused the preparation, characterization and determination of 10 new kinds of BCPCMs. The BCPCMs were prepared by blending of liquid xylitol pentalaurate (XPL) and xylitol pentamyristate (XPM) esters with gypsum, cement, diatomite, perlite and vermiculite as supporting matrices. The scanning electron microscopy (SEM) and Fourier Transform Infrared (FT-IR) analysis showed that the ester compounds were adsorbed uniformly into the building materials due to capillary forces

  4. Damage of first wall materials in fusion reactors under nonstationary thermal effects

    International Nuclear Information System (INIS)

    Maslaev, S.A.; Platonov, Yu.M.; Pimenov, V.N.

    1991-01-01

    The temperature distribution in the first wall of a fusion reactor was calculated for nonstationary thermal effects of the type of plasma destruction or the flow of 'running electrons' taking into account the melting of the surface layer of the material. The thickness of the resultant damaged layer in which thermal stresses were higher than the tensile strength of the material is estimated. The results were obtained for corrosion-resisting steel, aluminium and vanadium. Flowing down of the molten layer of the material of the first wall is calculated. (author)

  5. Storage related changes of cell wall based dietary fiber components of broccoli (Brassica oleracea var. italica) stems.

    Science.gov (United States)

    Schäfer, Judith; Stanojlovic, Luisa; Trierweiler, Bernhard; Bunzel, Mirko

    2017-03-01

    Storage related changes in the cell wall composition potentially affect the texture of plant-based foods and the physiological effects of cell wall based dietary fiber components. Therefore, a detailed characterization of cell wall polysaccharides and lignins from broccoli stems was performed. Freshly harvested broccoli and broccoli stored at 20°C and 1°C for different periods of time were analyzed. Effects on dietary fiber contents, polysaccharide composition, and on lignin contents/composition were much more pronounced during storage at 20°C than at 1°C. During storage, insoluble dietary fiber contents of broccoli stems increased up to 13%. Storage related polysaccharide modifications include an increase of the portions of cellulose, xylans, and homogalacturonans and a decrease of the neutral pectic side-chains arabinans and galactans. Broccoli stem lignins are generally rich in guaiacyl units. Lignins from freshly harvested broccoli stems contain slightly larger amounts of p-hydroxyphenyl units than syringyl units. Syringyl units are predominantly incorporated into the lignin polymers during storage, resulting in increased acetyl bromide soluble lignin contents. NMR-based analysis of the interunit linkage types of broccoli stem lignins revealed comparably large portions of resinol structures for a guaiacyl rich lignin. Incorporation of syringyl units into the polymers over storage predominantly occurs through β-O-4-linkages. Copyright © 2017 Elsevier Ltd. All rights reserved.

  6. Extremely high thermal conductivity anisotropy of double-walled carbon nanotubes

    Directory of Open Access Journals (Sweden)

    Zhaoji Ma

    2017-06-01

    Full Text Available Based on molecular dynamics simulations, we reveal that double-walled carbon nanotubes can possess an extremely high anisotropy ratio of radial to axial thermal conductivities. The mechanism is basically the same as that for the high thermal conductivity anisotropy of graphene layers - the in-plane strong sp2 bonds lead to a very high intralayer thermal conductivity while the weak van der Waals interactions to a very low interlayer thermal conductivity. However, different from flat graphene layers, the tubular structures of carbon nanotubes result in a diameter dependent thermal conductivity. The smaller the diameter, the larger the axial thermal conductivity but the smaller the radial thermal conductivity. As a result, a DWCNT with a small diameter may have an anisotropy ratio of thermal conductivity significantly higher than that for graphene layers. The extremely high thermal conductivity anisotropy allows DWCNTs to be a promising candidate for thermal management materials.

  7. Aluminum and silicon based phase change materials for high capacity thermal energy storage

    International Nuclear Information System (INIS)

    Wang, Zhengyun; Wang, Hui; Li, Xiaobo; Wang, Dezhi; Zhang, Qinyong; Chen, Gang; Ren, Zhifeng

    2015-01-01

    Six compositions of aluminum (Al) and silicon (Si) based materials: 87.8Al-12.2Si, 80Al–20Si, 70Al–30Si, 60Al–40Si, 45Al–40Si–15Fe, and 17Al–53Si–30Ni (atomic ratio), were investigated for potentially high thermal energy storage (TES) application from medium to high temperatures (550–1200 °C) through solid–liquid phase change. Thermal properties such as melting point, latent heat, specific heat, thermal diffusivity and thermal conductivity were investigated by differential scanning calorimetry and laser flash apparatus. The results reveal that the thermal storage capacity of the Al–Si materials increases with increasing Si concentration. The melting point and latent heat of 45Al–40Si–15Fe and 17Al–53Si–30Ni are ∼869 °C and ∼562 J g −1 , and ∼1079 °C and ∼960 J g −1 , respectively. The measured thermal conductivity of Al–Si binary materials depend on Si concentration and is higher than 80 W m −1  K −1 from room temperature to 500 °C, which is almost two orders of magnitude higher than those of salts that are commonly used phase change material for thermal energy storage. - Highlights: • Six kinds of materials were investigated for thermal energy storage (550–1200 °C). • Partial melting of Al–Si materials show progressively changing temperatures. • Studied materials can be used in three different working temperature ranges. • Materials are potentially good candidates for thermal energy storage applications.

  8. Detailed partial load investigation of a thermal energy storage concept for solar thermal power plants with direct steam generation

    Science.gov (United States)

    Seitz, M.; Hübner, S.; Johnson, M.

    2016-05-01

    Direct steam generation enables the implementation of a higher steam temperature for parabolic trough concentrated solar power plants. This leads to much better cycle efficiencies and lower electricity generating costs. For a flexible and more economic operation of such a power plant, it is necessary to develop thermal energy storage systems for the extension of the production time of the power plant. In the case of steam as the heat transfer fluid, it is important to use a storage material that uses latent heat for the storage process. This leads to a minimum of exergy losses during the storage process. In the case of a concentrating solar power plant, superheated steam is needed during the discharging process. This steam cannot be superheated by the latent heat storage system. Therefore, a sensible molten salt storage system is used for this task. In contrast to the state-of-the-art thermal energy storages within the concentrating solar power area of application, a storage system for a direct steam generation plant consists of a latent and a sensible storage part. Thus far, no partial load behaviors of sensible and latent heat storage systems have been analyzed in detail. In this work, an optimized fin structure was developed in order to minimize the costs of the latent heat storage. A complete system simulation of the power plant process, including the solar field, power block and sensible and latent heat energy storage calculates the interaction between the solar field, the power block and the thermal energy storage system.

  9. A hybrid solar and chemical looping combustion system for solar thermal energy storage

    International Nuclear Information System (INIS)

    Jafarian, Mehdi; Arjomandi, Maziar; Nathan, Graham J.

    2013-01-01

    Highlights: ► A novel solar–CLC hybrid system is proposed which integrates a CLC with solar thermal energy. ► The oxygen carrier particles are used as storage medium for thermal energy storage. ► A solar cavity reactor is proposed for fuel reactor. ► The absorbed solar energy is stored in the particles to produce a base heat load. -- Abstract: A novel hybrid of a solar thermal energy and a chemical looping combustion (CLC) system is proposed here, which employs the oxygen carrier particles in a CLC system to provide diurnal thermal energy storage for concentrated solar thermal energy. In taking advantage of the chemical and sensible energy storage systems that are an inherent part of a CLC system, this hybrid offers potential to achieve cost effective, base load power generation for solar energy. In the proposed system, three reservoirs have been added to a conventional CLC system to allow storage of the oxygen carrier particles, while a cavity solar receiver has been chosen for the fuel reactor. The performance of the system is evaluated using ASPEN PLUS software, with the model being validated using independent simulation result reported previously. Operating temperature, solar efficiency, solar fraction, exergy efficiency and the fraction of the solar thermal energy stored for a based load power generation application are reported.

  10. Thermal energy storage using chloride salts and their eutectics

    International Nuclear Information System (INIS)

    Myers, Philip D.; Goswami, D. Yogi

    2016-01-01

    Achieving the goals of the U.S. Department of Energy (DOE) Sunshot initiative requires (1) higher operating temperatures for concentrating solar power (CSP) plants to increase theoretical efficiency, and (2) effective thermal energy storage (TES) strategies to ensure dispatchability. Current inorganic salt-based TES systems in large-scale CSP plants generally employ molten nitrate salts for energy storage, but nitrate salts are limited in application to lower temperatures—generally, below 600 °C. These materials are sufficient for parabolic trough power plants, but they are inadequate for use at higher temperatures. At the higher operating temperatures achievable in solar power tower-type CSP plants, chloride salts are promising candidates for application as TES materials, owing to their thermal stability and generally lower cost compared to nitrate salts. In light of this, a recent study was conducted, which included a preliminary survey of chloride salts and binary eutectic systems that show promise as high temperature TES media. This study provided some basic information about the salts, including phase equilibria data and estimates of latent heat of fusion for some of the eutectics. Cost estimates were obtained through a review of bulk pricing for the pure salts among various vendors. This review paper updates that prior study, adding data for additional salt eutectic systems obtained from the literature. Where possible, data are obtained from the thermodynamic database software, FactSage. Radiative properties are presented, as well, since at higher temperatures, thermal radiation becomes a significant mode of heat transfer. Material compatibility for inorganic salts is another important consideration (e.g., with regard to piping and/or containment), so a summary of corrosion studies with various materials is also presented. Lastly, cost data for these systems are presented, allowing for meaningful comparison among these systems and other materials for TES

  11. Microencapsulated n-octacosane as phase change material for thermal energy storage

    Energy Technology Data Exchange (ETDEWEB)

    Sari, Ahmet; Alkan, Cemil; Karaipekli, Ali [Department of Chemistry, Gaziosmanpasa University, 60240 Tokat (Turkey); Uzun, Orhan [Department of Physics, Gaziosmanpasa University, 60240 Tokat (Turkey)

    2009-10-15

    This study deals with preparation and characterization of polymethylmetracrylate (PMMA) microcapsules containing n-octacosane as phase change material for thermal energy storage. The surface morphology, particle size and particle size distribution (PSD) were studied by scanning electron microscopy (SEM). The chemical characterization of PMMA/octacosane microcapsules was made by FT-IR spectroscopy method. Thermal properties and thermal stability of microencapsulated octacosane were determined using differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). The melting and freezing temperatures and the latent heats of the microencapsulated octacosane as PCM were measured as 50.6 and 53.2 C, 86.4 and -88.5 J/g, respectively, by DSC analysis. TGA analysis indicated that the microencapsulated octacosane degrade in two steps and had good chemical stability. Thermal cycling test shows that the microcapsules have good thermal reliability with respect to the accelerated thermal cycling. Based on the results, it can be considered that the microencapsulated octacosane have good energy storage potential. (author)

  12. Thermal Analysis of the SAFKEG Package for Long Term Storage

    International Nuclear Information System (INIS)

    NARENDRA, GUPTA

    2005-01-01

    Interim plutonium storage for up to 10 years in the K-reactor building is currently being planned at Savannah River Site (SRS). SAFKEG package could be used to store Pu metal and oxide (PuO2) in the K-reactor complex with other packagings like 9975. The SAFKEG is designed for carrying Type-B materials across the DOE complex and meets the 10CFR71 requirements. Thermal analyses were performed to ensure that the temperatures of the SAFKEG components will not exceed their temperature limits under the K-reactor storage conditions. Thermal analyses of the SAFKEG packaging with three content configurations using BNFL 3013 outer container (Rocky Flats, SRS bagless transfer cans, and BNFL inner containers) were performed for storage of PuO2 and plutonium metal

  13. Thermo-mechanical parametric analysis of packed-bed thermocline energy storage tanks

    International Nuclear Information System (INIS)

    González, Ignacio; Pérez-Segarra, Carlos David; Lehmkuhl, Oriol; Torras, Santiago; Oliva, Assensi

    2016-01-01

    Highlights: • A numerical model of packed-bed thermocline thermal storage for CSP is presented. • Up-to-date commercial configurations are tested both thermally and structurally. • Promising thermal performance is obtained with a temperature difference of 100 °C. • Reliable factors of safety against material yielding and ratcheting can be obtained. • Cyclic relaxation-traction elastic wall stresses arise with plant normal operation. - Abstract: A packed-bed thermocline tank represents a proved cheaper thermal energy storage for concentrated solar power plants compared with the commonly-built two-tank system. However, its implementation has been stopped mainly due to the vessel’s thermal ratcheting concern, which would compromise its structural integrity. In order to have a better understanding of the commercial viability of thermocline approach, regarding energetic effectiveness and structural reliability, a new numerical simulation platform has been developed. The model dynamically solves and couples all the significant components of the subsystem, being able to evaluate its thermal and mechanical response over plant normal operation. The filler material is considered as a cohesionless bulk solid with thermal expansion. For the stresses on the tank wall the general thermoelastic theory is used. First, the numerical model is validated with the Solar One thermocline case, and then a parametric analysis is carried out by settling this storage technology in two real plants with a temperature rise of 100 °C and 275 °C. The numerical results show a better storage performance together with the lowest temperature difference, but both options achieve suitable structural factors of safety with a proper design.

  14. Cost and performance analysis of concentrating solar power systems with integrated latent thermal energy storage

    International Nuclear Information System (INIS)

    Nithyanandam, K.; Pitchumani, R.

    2014-01-01

    Integrating TES (thermal energy storage) in a CSP (concentrating solar power) plant allows for continuous operation even during times when solar irradiation is not available, thus providing a reliable output to the grid. In the present study, the cost and performance models of an EPCM-TES (encapsulated phase change material thermal energy storage) system and HP-TES (latent thermal storage system with embedded heat pipes) are integrated with a CSP power tower system model utilizing Rankine and s-CO 2 (supercritical carbon-dioxide) power conversion cycles, to investigate the dynamic TES-integrated plant performance. The influence of design parameters of the storage system on the performance of a 200 MW e capacity power tower CSP plant is studied to establish design envelopes that satisfy the U.S. Department of Energy SunShot Initiative requirements, which include a round-trip annualized exergetic efficiency greater than 95%, storage cost less than $15/kWh t and LCE (levelized cost of electricity) less than 6 ¢/kWh. From the design windows, optimum designs of the storage system based on minimum LCE, maximum exergetic efficiency, and maximum capacity factor are reported and compared with the results of two-tank molten salt storage system. Overall, the study presents the first effort to construct and analyze LTES (latent thermal energy storage) integrated CSP plant performance that can help assess the impact, cost and performance of LTES systems on power generation from molten salt power tower CSP plant. - Highlights: • Presents technoeconomic analysis of thermal energy storage integrated concentrating solar power plants. • Presents a comparison of different storage options. • Presents optimum design of thermal energy storage system for steam Rankine and supercritical carbon dioxide cycles. • Presents designs for maximizing exergetic efficiency while minimizing storage cost and levelized cost of energy

  15. Dividing wall column: Improving thermal efficiency, energy savings and economic performance

    International Nuclear Information System (INIS)

    Aurangzeb, Md; Jana, Amiya K.

    2016-01-01

    Highlights: • A rigorous model is developed for a dividing wall column. • Heat transfer model for metal wall is proposed. • Performance improvement is quantified for a ternary system. • Thermal efficiency, energy savings and cost are three used indices. - Abstract: This work aims at investigating the performance improvement of a dividing wall column (DWC) for the separation of a ternary system. It is true that for fractionating a ternary mixture, at least a sequence of two conventional distillation columns is required. To improve energetic and economic potential, and reduce space requirement, two columns are proposed to merge into one shell with a dividing wall. For developing the mathematical model of a distillation column, we consider the effect of heat transfer through the metal wall placed at an intermediated position inside the cylindrical column. The simulated DWC model is verified using the Aspen Plus flowsheet simulator with a wide variety of phase equilibrium models. The superiority of this proposed heat integrated configuration is shown for a ternary hydrocarbon system over a conventional distillation sequence (CDS) in terms of mainly three performance indexes, namely thermal efficiency, energy savings and total annual cost (TAC). It is investigated that the dividing wall distillation scheme can secure a 37.5% energy efficiency, and a 22.6% savings in energy consumption and 23.23% in TAC. The promising performance can also be quantified in terms of a reasonably low payback period of 2.11 years.

  16. Ice thermal storage air conditioning system for electric load leveling; Denryoku heijunka to hyochikunetsu system

    Energy Technology Data Exchange (ETDEWEB)

    Shigenaga, Y. [Daikin Industries Ltd., Osaka (Japan)

    1998-08-15

    Thermal storage air conditioning system is the one to use energy stored into thermal storing materials by using night electric power and to operate effective air conditioning. Therefore, as load can be treated by the stored energy, volume of the apparatus can be reduced. And, by reduction of the consumed power at day time, it can contribute to leveling of electric power demand. In general, there are two types in the thermal storage method: one is a method to store as thermal energy, and the other is that to store as chemical energy. For conditions required for the storing materials, important elements on their actual uses are not only physical properties such as large thermal storage per unit and easy thermal in- and out-puts, but also safety, long-term reliability, and easy receiving and economics containing future. The ice thermal storage air conditioning system is classified at the viewpoint of type of ice, kind of thermal storing medium, melting method on using cooling and heating, kinds of thermal medium on cooling and heating. 3 refs., 5 figs., 2 tabs.

  17. Four-wall turbine airfoil with thermal strain control for reduced cycle fatigue

    Science.gov (United States)

    Cambell, Christian X

    2013-09-17

    A turbine airfoil (20B) with a thermal expansion control mechanism that increases the airfoil camber (60, 61) under operational heating. The airfoil has four-wall geometry, including pressure side outer and inner walls (26, 28B), and suction side outer and inner walls (32, 34B). It has near-wall cooling channels (31F, 31A, 33F, 33A) between the outer and inner walls. A cooling fluid flow pattern (50C, 50W, 50H) in the airfoil causes the pressure side inner wall (28B) to increase in curvature under operational heating. The pressure side inner wall (28B) is thicker than walls (26, 34B) that oppose it in camber deformation, so it dominates them in collaboration with the suction side outer wall (32), and the airfoil camber increases. This reduces and relocates a maximum stress area (47) from the suction side outer wall (32) to the suction side inner wall (34B, 72) and the pressure side outer wall (26).

  18. Thermal properties and thermal reliability of eutectic mixtures of some fatty acids as latent heat storage materials

    International Nuclear Information System (INIS)

    Sari, Ahmet; Sari, Hayati; Oenal, Adem

    2004-01-01

    The present study deals with two subjects. The first one is to determine the thermal properties of lauric acid (LA)-stearic acid (SA), myristic acid (MA)-palmitic acid (PA) and palmitic acid (PA)-stearic acid (SA) eutectic mixtures as latent heat storage material. The properties were measured by the differential scanning calorimetry (DSC) analysis technique. The second one is to study the thermal reliability of these materials in view of the change in their melting temperatures and latent heats of fusion with respect to repeated thermal cycles. For this aim, the eutectic mixtures were subjected to 360 repeated melt/freeze cycles, and their thermal properties were measured after 0, 90,180 and 360 thermal cycles by the technique of DSC analysis. The DSC thermal analysis results show that the binary systems of LA-SA in the ratio of 75.5:24.5 wt.%, MA-PA in the ratio of 58:42 wt.% and PA-SA in the ratio of 64.2:35.8 wt.% form eutectic mixtures with melting temperatures of 37.0, 42.60 and 52.30 deg. C and with latent heats of fusion of 182.7, 169.7 and 181.7 J g -1 , respectively. These thermal properties make them possible for heat storage in passive solar heating applications with respect to climate conditions. The accelerated thermal cycle tests indicate that the changes in the melting temperatures and latent heats of fusion of the studied eutectic mixtures are not regular with increasing number of thermal cycles. However, these materials, latent heat energy storage materials, have good thermal reliability in terms of the change in their thermal properties with respect to thermal cycling for about a one year utility period

  19. Palmitic acid/polypyrrole composites as form-stable phase change materials for thermal energy storage

    International Nuclear Information System (INIS)

    Silakhori, Mahyar; Metselaar, Hendrik Simon Cornelis; Mahlia, Teuku Meurah Indra; Fauzi, Hadi; Baradaran, Saeid; Naghavi, Mohammad Sajad

    2014-01-01

    Highlights: • A novel phase change composite of palmitic acid–polypyrrole(PA–PPy) was fabricated. • Thermal properties of PA–PPy are characterized in different mass ratios of PA–PPy. • Thermal cycling test showed that form stable PCM had a favorable thermal reliability. - Abstract: In this study a novel palmitic acid (PA)/polypyrrole (PPy) form-stable PCMs were readily prepared by in situ polymerization method. PA was used as thermal energy storage material and PPy was operated as supporting material. Form-stable PCMs were investigated by SEM (scanning electron microscopy) and FTIR (Fourier transform infrared spectrometer) analysis that illustrated PA Particles were wrapped by PPy particles. XRD (X-ray diffractometer) was used for crystalline phase of PA/PPy composites. Thermogravimetry analysis (TGA) and differential scanning calorimetry (DSC) were used for investigating Thermal stability and thermal energy storage properties of prepared form-stable PCMs. According to the obtained results the form stable PCMs exhibited favorable thermal stability in terms of their phase change temperature. The form-stable PCMs (79.9 wt% loading of PA) were considered as the highest loading PCM with desirable latent heat storage of 166.3 J/g and good thermal stability. Accelerated thermal cycling tests also showed that form stable PCM had an acceptable thermal reliability. As a consequence of acceptable thermal properties, thermal stability and chemical stability, we can consider the new kind of form stable PCMs for low temperature solar thermal energy storage applications

  20. Effect of wall thermal conductivity on the heat transfer process in annular turbulent gas flow for constant wall temperature

    International Nuclear Information System (INIS)

    Groshev, A.I.; Anisimov, V.V.; Kashcheev, V.M.; Khudasko, V.V.; Yur'ev, Yu.S.

    1987-01-01

    The effect of wall material on convective heat transfer of turbulent gas flow in an annular tube with account of longitudinal diffusion both in the wall and in the liquid is studied numerically. The conjugated problem is solved for P r =0.7 (Re=10 4 -10 6 ). Based on numerical calculations it is stated that thermal conductivity of the wall and gas essentially affects the degree of preliminary heating of liquid in the range of a non-heated section

  1. Using Nanoparticles for Enhance Thermal Conductivity of Latent Heat Thermal Energy Storage

    Directory of Open Access Journals (Sweden)

    Baydaa Jaber Nabhan

    2015-06-01

    Full Text Available Phase change materials (PCMs such as paraffin wax can be used to store or release large amount of energy at certain temperature at which their solid-liquid phase changes occurs. Paraffin wax that used in latent heat thermal energy storage (LHTES has low thermal conductivity. In this study, the thermal conductivity of paraffin wax has been enhanced by adding different mass concentration (1wt.%, 3wt.%, 5wt.% of (TiO2 nano-particles with about (10nm diameter. It is found that the phase change temperature varies with adding (TiO2 nanoparticles in to the paraffin wax. The thermal conductivity of the composites is found to decrease with increasing temperature. The increase in thermal conductivity has been found to increase by about (10% at nanoparticles loading (5wt.% and 15oC.

  2. Phonon and thermal properties of achiral single wall carbon ...

    Indian Academy of Sciences (India)

    A detailed theoretical study of the phonon and thermal properties of achiral single wall carbon nanotubes has been carried out using force constant model considering up to third nearest-neighbor interactions. We have calculated the phonon dispersions, density of states, radial breathing modes (RBM) and the specific heats ...

  3. Enhanced Thermal Management System for Spent Nuclear Fuel Dry Storage Canister with Hybrid Heat Pipes

    International Nuclear Information System (INIS)

    Jeong, Yeong Shin; Bang, In Cheol

    2016-01-01

    Dry storage uses the gas or air as coolant within sealed canister with neutron shielding materials. Dry storage system for spent fuel is regarded as relatively safe and emits little radioactive waste for the storage, but it showed that the storage capacity and overall safety of dry cask needs to be enhanced for the dry storage cask for LWR in Korea. For safety enhancement of dry cask, previous studies of our group firstly suggested the passive cooling system with heat pipes for LWR spent fuel dry storage metal cask. As an extension, enhanced thermal management systems for the spent fuel dry storage cask for LWR was suggested with hybrid heat pipe concept, and their performances were analyzed in thermal-hydraulic viewpoint in this paper. In this paper, hybrid heat pipe concept for dry storage cask is suggested for thermal management to enhance safety margin. Although current design of dry cask satisfies the design criteria, it cannot be assured to have long term storage period and designed lifetime. Introducing hybrid heat pipe concept to dry storage cask designed without disrupting structural integrity, it can enhance the overall safety characteristics with adequate thermal management to reduce overall temperature as well as criticality control. To evaluate thermal performance of hybrid heat pipe according to its design, CFD simulation was conducted and previous and revised design of hybrid heat pipe was compared in terms of temperature inside canister

  4. Thermal stratification in storage tanks of integrated collector storage solar water heaters

    International Nuclear Information System (INIS)

    Oshchepkov, M.Y.; Frid, S.E.

    2015-01-01

    To determine the influence of the shape of the tank, the installation angle, and the magnitude of the absorbed heat flux on thermal stratification in integrated collector-storage solar water heaters, numerical simulation of thermal convection in tanks of different shapes and same volume was carried out. Idealized two-dimensional models were studied; auto model stratification profiles were obtained at the constant heat flux. The shape of the tank, the pattern of the heat flux dynamics, the adiabatic mixing on the circulation rate and the degree of stratification were shown to have significant influence. (authors)

  5. Effect of Steel Framing for Securing Drywall Panels on Thermal and Humidity Parameters of the Outer Walls

    Science.gov (United States)

    Major, Maciej; Kosiń, Mariusz

    2017-12-01

    The paper analyses the effect of steel framing used to secure drywall panels on thermal and humidity properties of outer walls. In the practice of building a light structure, the most popular components are steel and wood studs. They are used to obtain framing for building a wall (an outer wall in this study). Analysis presented in this study concerned the corner of the outer wall build using the technology of light steel framing. Computer simulation was used to perform thermal and humidity analysis for the joint of the outer wall.

  6. Effect of Steel Framing for Securing Drywall Panels on Thermal and Humidity Parameters of the Outer Walls

    Directory of Open Access Journals (Sweden)

    Major Maciej

    2017-12-01

    Full Text Available The paper analyses the effect of steel framing used to secure drywall panels on thermal and humidity properties of outer walls. In the practice of building a light structure, the most popular components are steel and wood studs. They are used to obtain framing for building a wall (an outer wall in this study. Analysis presented in this study concerned the corner of the outer wall build using the technology of light steel framing. Computer simulation was used to perform thermal and humidity analysis for the joint of the outer wall.

  7. Candidate thermal energy storage technologies for solar industrial process heat applications

    Science.gov (United States)

    Furman, E. R.

    1979-01-01

    A number of candidate thermal energy storage system elements were identified as having the potential for the successful application of solar industrial process heat. These elements which include storage media, containment and heat exchange are shown.

  8. Lifetime evaluation for thermal fatigue: application at the first wall of a tokamak fusion reactor

    International Nuclear Information System (INIS)

    Merola, M.; Biggio, M.

    1989-01-01

    Thermal fatigue seems to be the most lifetime limiting phenomenon for the first wall of the next generation Tokamak fusion reactors. This work deals with the problem of the thermal fatigue in relation to the lifetime prediction of the fusion reactor first wall. The aim is to compare different lifetime methodologies among them and with experimental results. To fulfil this purpose, it has been necessary to develop a new numerical methodology, called reduced-3D, especially suitable for thermal fatigue problems

  9. Second law characterization of stratified thermal storage tanks

    Energy Technology Data Exchange (ETDEWEB)

    Fraidenraich, N [Departamento de Energia Nuclear-UFPE (Brazil)

    2000-07-01

    It is well known that fluid stratification in thermal storage tanks improves the overall performance of solar thermal systems, when compared with systems operating with uniform fluid temperature. From the point of view of the first law of thermodynamics, no difference exists between storage tanks with the same mass and average temperature, even if they have different stratified thermal structures. Nevertheless, the useful thermal energy that can be obtained from them might differ significantly. In this work, we derive an expression able to characterize the stratified configuration of thermal fluid. Using results obtained by thermodynamics of irreversible processes, the procedure adopted consists in calculating the maximum work available from the tank's thermal layer is able to develop. We arrive, then, at a dimensionless expression, the stratification parameter (SP), which depends on the mass fraction and absolute temperature of each thermal layer as well as the thermal fluid average temperature. Numerical examples for different types of tank stratification are given and it is verified that the expression obtained is sensitive to small differences in the reservoir thermal configuration. For example a thermal storage with temperatures equal to 74 Celsius degrees, 64 Celsius degrees and 54 Celsius degrees, with its mass equally distributed along the tank yields, for the parameter SP, a figure equal to 0.000294. On the other hand a storage tank with the same average temperature but with different layer's temperatures 76 Celsius degrees, 64 and 52 Celsius degrees, also with uniform mass distribution, yields for SP a value equal to quantitative evaluation of the stratification structure of thermal reservoirs. [Spanish] Es bien conocido que la estratificacion fluida en tanques de almacenamiento termico mejora el rendimiento total de los sistemas termicos solares en comparacion con sistemas que operan con temperatura uniforme del fluido. Desde el punto de vista

  10. Behavior of deep flaws in a thick-wall cylinder under thermal shock loading

    International Nuclear Information System (INIS)

    Cheverton, R.D.

    1979-01-01

    Behavior of inner-surface flaws in thick-walled vessels was studied in a 991-mm OD x 152 mm wall x 1220 mm length cylinder with toughness properties similar to those for HSST Plate. The initial temperature of 93 0 C and a thermal shock medium of liquid nitrogen (-197 0 C) were employed. The initial flaw selected was a sharp, 16 mm deep, long (1220 mm) axial crack. Crack arrest methodology was shown to be valid for deep flaws under severe thermal shock

  11. Aquifer thermal energy storage reference manual: seasonal thermal energy storage program

    Energy Technology Data Exchange (ETDEWEB)

    Prater, L.S.

    1980-01-01

    This is the reference manual of the Seasonal Thermal Energy Storage (STES) Program, and is the primary document for the transfer of technical information of the STES Program. It has been issued in preliminary form and will be updated periodically to include more technical data and results of research. As the program progresses and new technical data become available, sections of the manual will be revised to incorporate these data. This primary document contains summaries of: the TRW, incorporated demonstration project at Behtel, Alaska, Dames and Moore demonstration project at Stony Brook, New York, and the University of Minnesota demonstration project at Minneapolis-St. Paul, Minnesota; the technical support programs including legal/institutional assessment; economic assessment; environmental assessment; field test facilities; a compendia of existing information; numerical simulation; and non-aquifer STES concepts. (LCL)

  12. Feasibility of applying cathodic protection to double-wall waste storage tanks

    International Nuclear Information System (INIS)

    Moore, E.L.

    1977-01-01

    A study was conducted to determine the feasibility of applying impressed current cathodic protection to double-wall storage tanks containing terminal waste solutions. Norton Corrosion Limited concluded that such a system could be designed for installation on the tanks. Under their direction, Battelle Northwest Laboratories conducted a laboratory study to develop necessary data for design of the system. A separate study conducted by Battelle Columbus Laboratories indicated that, while terminal waste solutions by themselves do not promote stress corrosion cracking, cathodic protection may promote this type of corrosion under certain conditions. As a result of these findings, the recommendation was made not to install cathodic protection on the double-wall tanks containing terminal waste solutions

  13. Do encapsulated heat storage materials really retain their original thermal properties?

    Science.gov (United States)

    Chaiyasat, Preeyaporn; Noppalit, Sayrung; Okubo, Masayoshi; Chaiyasat, Amorn

    2015-01-14

    The encapsulation of Rubitherm®27 (RT27), which is one of the most common commercially supplied heat storage materials, by polystyrene (PS), polydivinyl benzene (PDVB) and polymethyl methacrylate (PMMA) was carried out using conventional radical microsuspension polymerization. The products were purified to remove free RT27 and free polymer particles without RT27. In the cases of PS and PDVB microcapsules, the latent heats of melting and crystallization for RT27 ( and , J/g-RT27) were clearly decreased by the encapsulation. On the other hand, those of the PMMA microcapsules were the same as pure RT27. A supercooling phenomenon was observed not only for PS and PDVB but also for the PMMA microcapsules. These results indicate that the thermal properties of the heat storage materials encapsulated depend on the type of polymer shells, i.e., encapsulation by polymer shell changes the thermal properties of RT27. This is quite different from the idea of other groups in the world, in which they discussed the thermal properties based on the ΔHm and ΔHc values expressed in J/g-capsule, assuming that the thermal properties of the heat storage materials are not changed by the encapsulation. Hereafter, this report should raise an alarm concerning the "wrong" common knowledge behind developing the encapsulation technology of heat storage materials.

  14. Eutectic mixtures of some fatty acids for latent heat storage: Thermal properties and thermal reliability with respect to thermal cycling

    International Nuclear Information System (INIS)

    Sari, Ahmet

    2006-01-01

    Accelerated thermal cycle tests have been conducted to study the change in melting temperatures and latent heats of fusion of the eutectic mixtures of lauric acid (LA)-myristic acid (MA), lauric acid (LA)-palmitic acid (PA) and myristic acid (MA)-stearic acid (SA) as latent heat storage materials. The thermal properties of these materials were determined by the differential scanning calorimetry (DSC) analysis method. The thermal reliability of the eutectic mixtures after melt/freeze cycles of 720, 1080 and 1460 was also evaluated using the DSC curves. The accelerated thermal cycle tests indicate that the melting temperatures usually tend to decrease, and the variations in the latent heats of fusion are irregular with increasing number of thermal cycles. Moreover, the probable reasons for the change in thermal properties of the eutectic mixtures after repeated thermal cycles were investigated. Fourier Transform Infrared (FT-IR) spectroscopic analysis indicates that the accelerated melt/freeze processes do not cause any degradation in the chemical structure of the mixtures. The change in thermal properties of the eutectic mixtures with increasing number of thermal cycles is only because of the presence of certain amounts of impurities in the fatty acids used in their preparation. It is concluded that the tested eutectic mixtures have reasonable thermal properties and thermal reliability as phase change materials (PCMs) for latent heat storage in any solar heating applications that include a four year utilization period

  15. Modification of single wall carbon nanotubes (SWNT) for hydrogen storage

    Energy Technology Data Exchange (ETDEWEB)

    Rashidi, A.M.; Nouralishahi, A.; Karimi, A.; Kashefi, K. [Nanotechnology Research Center, Research Institute of petroleum industry (RIPI), Tehran (Iran); Khodadadi, A.A.; Mortazavi, Y. [Chemical engineering Department, University of Tehran, Tehran (Iran)

    2010-09-15

    Due to unique structural, mechanical and electrical properties of single wall carbon nanotubes, SWNTs, they have been proposed as promising hydrogen storage materials especially in automotive industries. This research deals with investing of CNT's and some activated carbons hydrogen storage capacity. The CNT's were prepared through natural gas decomposition at a temperature of 900 C over cobalt-molybdenum nanoparticles supported by nanoporous magnesium oxide (Co-Mo/MgO) during a chemical vapor deposition (CVD) process. The effects of purity of CNT (80-95%wt.) on hydrogen storage were investigated here. The results showed an improvement in the hydrogen adsorption capacity with increasing the purity of CNT's. Maximum adsorption capacity was 0.8%wt. in case of CNT's with 95% purity and it may be raised up with some purification to 1%wt. which was far less than the target specified by DOE (6.5%wt.). Also some activated carbons were manufactured and the results compared to CNTs. There were no considerable H{sub 2}-storage for carbon nanotubes and activated carbons at room-temperature due to insufficient binding between H{sub 2} molecules carbon nanostructures. Therefore, hydrogen must be adsorbed via interaction of atomic hydrogen with the storage environment in order to achieve DOE target, because the H atoms have a very stronger interaction with carbon nanostructures. (author)

  16. Phase change thermal storage for a solar total energy system

    Science.gov (United States)

    Rice, R. E.; Cohen, B. M.

    1978-01-01

    An analytical and experimental program is being conducted on a one-tenth scale model of a high-temperature (584 K) phase-change thermal energy storage system for installation in a solar total energy test facility at Albuquerque, New Mexico, U.S.A. The thermal storage medium is anhydrous sodium hydroxide with 8% sodium nitrate. The program will produce data on the dynamic response of the system to repeated cycles of charging and discharging simulating those of the test facility. Data will be correlated with a mathematical model which will then be used in the design of the full-scale system.

  17. Advanced latent heat of fusion thermal energy storage for solar power systems

    Science.gov (United States)

    Phillips, W. M.; Stearns, J. W.

    1985-01-01

    The use of solar thermal power systems coupled with thermal energy storage (TES) is being studied for both terrestrial and space applications. In the case of terrestrial applications, it was found that one or two hours of TES could shift the insolation peak (solar noon) to coincide with user peak loads. The use of a phase change material (PCM) is attractive because of the higher energy storage density which can be achieved. However, the use of PCM has also certain disadvantages which must be addressed. Proof of concept testing was undertaken to evaluate corrosive effects and thermal ratcheting effects in a slurry system. It is concluded that the considered alkali metal/alkali salt slurry approach to TES appears to be very viable, taking into account an elimination of thermal ratcheting in storage systems and the reduction of corrosive effects. The approach appears to be useful for an employment involving temperatures applicable to Brayton or Stirling cycles.

  18. Experimental investigation on charging and discharging performance of absorption thermal energy storage system

    International Nuclear Information System (INIS)

    Zhang, Xiaoling; Li, Minzhi; Shi, Wenxing; Wang, Baolong; Li, Xianting

    2014-01-01

    Highlights: • A prototype of ATES using LiBr/H 2 O was designed and built. • Charging and discharging performances of ATES system were investigated. • ESE and ESD for cooling, domestic hot water and heating were obtained. - Abstract: Because of high thermal storage density and little heat loss, absorption thermal energy storage (ATES) is known as a potential thermal energy storage (TES) technology. To investigate the performance of the ATES system with LiBr–H 2 O, a prototype with 10 kW h cooling storage capacity was designed and built. The experiments demonstrated that charging and discharging processes are successful in producing 7 °C chilled water, 65 °C domestic hot water, or 43 °C heating water to meet the user’s requirements. Characteristics such as temperature, concentration and power variation of the ATES system during charging and discharging processes were investigated. The performance of the ATES system for supplying cooling, heating or domestic hot water was analyzed and compared. The results indicate that the energy storage efficiencies (ESE) for cooling, domestic hot water and heating are 0.51, 0.97, 1.03, respectively, and the energy storage densities (ESD) for cooling, domestic hot water and heating reach 42, 88, 110 kW h/m 3 , respectively. The performance is better than those of previous TES systems, which proves that the ATES system using LiBr–H 2 O may be a good option for thermal energy storage

  19. Thermal shock considerations for the TFCX limiter and first wall

    International Nuclear Information System (INIS)

    Haines, J.R.; Fuller, G.M.

    1983-01-01

    Resistance to thermal shock fracture of limiter and first wall surface material candidates during plasma disruption heating conditions is evaluated. A simple, figure-of-merit type thermal shock parameter which provides a mechanism to rank material candidates is derived. Combining this figure-of-merit parameter with the parameters defining specific heating conditions yields a non-dimensional thermal shock parameter. For values of this parameter below a critical value, a given material is expected to undergo thermal shock damage. Prediction of thermal shock damage with this parameter is shown to exhibit good agreement with test data. Applying this critical parameter value approach, all materials examined in this study are expected to experience thermal shock damage for nominal TFCX plasma disruption conditions. Since the extent of this damage is not clear, tests which explore the range of expected conditions for TFCX are recommended

  20. High-Temperature Thermal Energy Storage for electrification and district heating

    DEFF Research Database (Denmark)

    Pedersen, A. Schrøder; Engelbrecht, K.; Soprani, S.

    stability upon thermal cycling. The most promising material consists of basalt, diabase, and magnetite, whereas the less suited rocks contain larger proportions of quartz and mica. An HT-TES system, containing 1.5 m3 of rock pieces, was constructed. The rock bed was heated to 600 ˚C using an electric heater......The present work describes development of a High Temperature Thermal Energy Storage (HT-TES) system based on rock bed technology. A selection of rocks was investigated by thermal analysis in the range 20-800 ˚C. Subsequently, a shortlist was defined primarily based on mechanical and chemical...... to simulate thermal charging from wind energy. After complete heating of the rock bed it was left fully charged for hours to simulate actual storage conditions. Subsequently the bed discharging was performed by leading cold air through the rock bed whereby the air was heated and led to an exhaust. The results...

  1. STP-ECRTS - THERMAL AND GAS ANALYSES FOR SLUDGE TRANSPORT AND STORAGE CONTAINER (STSC) STORAGE AT T PLANT

    Energy Technology Data Exchange (ETDEWEB)

    CROWE RD; APTHORPE R; LEE SJ; PLYS MG

    2010-04-29

    The Sludge Treatment Project (STP) is responsible for the disposition of sludge contained in the six engineered containers and Settler tank within the 105-K West (KW) Basin. The STP is retrieving and transferring sludge from the Settler tank into engineered container SCS-CON-230. Then, the STP will retrieve and transfer sludge from the six engineered containers in the KW Basin directly into a Sludge Transport and Storage Containers (STSC) contained in a Sludge Transport System (STS) cask. The STSC/STS cask will be transported to T Plant for interim storage of the STSC. The STS cask will be loaded with an empty STSC and returned to the KW Basin for loading of additional sludge for transportation and interim storage at T Plant. CH2MHILL Plateau Remediation Company (CHPRC) contracted with Fauske & Associates, LLC (FAI) to perform thermal and gas generation analyses for interim storage of STP sludge in the Sludge Transport and Storage Container (STSCs) at T Plant. The sludge types considered are settler sludge and sludge originating from the floor of the KW Basin and stored in containers 210 and 220, which are bounding compositions. The conditions specified by CHPRC for analysis are provided in Section 5. The FAI report (FAI/10-83, Thermal and Gas Analyses for a Sludge Transport and Storage Container (STSC) at T Plant) (refer to Attachment 1) documents the analyses. The process considered was passive, interim storage of sludge in various cells at T Plant. The FATE{trademark} code is used for the calculation. The results are shown in terms of the peak sludge temperature and hydrogen concentrations in the STSC and the T Plant cell. In particular, the concerns addressed were the thermal stability of the sludge and the potential for flammable gas mixtures. This work was performed with preliminary design information and a preliminary software configuration.

  2. Thermal Analysis of Fission Moly Target Solid Waste Storage

    Energy Technology Data Exchange (ETDEWEB)

    Son, Hyung Min; Park, Jonghark [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2016-10-15

    There are various ways to produce Mo-99. Among them, nuclear transmutation of uranium target became the major one owing to its superior specific activity. After the fission molybdenum (FM) target is irradiated, it is transported to treatment facility to extract wanted isotope. During the process, various forms of wastes are produced including filter cake and other solid wastes. The filter cake is mostly consisted of decaying uranium compounds. The solid wastes are then packaged and moved to storage facility which will stay there for considerable amount of time. Being the continuous source of heat, the solid wastes are required to be cooled for the certain amount of time before transported to the storage area. In this study, temperature evaluation of the storage facility is carried out with pre-cooling time sensitivity to check its thermal integrity. In this study, thermal analysis on the FM target solid waste storage is performed. Finite volume method is utilized to numerically discretize and solve the geometry of interest. Analysis shows that the developed method can simulate temperature behavior during storage process, but needs to be checked against other code to see calculation accuracy. Highest temperature distribution is observed when every hole is filled with waste containers. Sensitivity results on pre-cooling time shows that at least 13 months of cooling is necessary to keep the structure integrity.

  3. Numerical thermal analysis of the vertical external partition made as the frame thin-walled steel structure

    Directory of Open Access Journals (Sweden)

    Major Maciej

    2017-01-01

    Full Text Available The article presents numerical thermal analysis of the vertical external partitions made in the lightweight steel framing technology. Steel posts that perform the structural role lead to the formation of linear thermal bridges and have a negative effect on the level of thermal transmittance U. Therefore, optimal solutions are being explored for such technologies. One of the solutions is to use perforated Thermo sections. The effect of perforated Thermo sections on energy loss was verified through comparison to the wall made of solid sections. Furthermore, the calculations analysed the effect of linear thermal bridges that are formed on wall connections in the corner. Computer simulation was employed to emphasize the significant differences in the temperature distribution in both analysed wall structures that resulted from constructional solutions.

  4. Block survey of wall covered with plant in the city of Tokyo [Japan] and evaluation of thermal environment of wall greening system

    International Nuclear Information System (INIS)

    Shibuya, K.; Soh, Y.; Satoh, S.

    2007-01-01

    There were 384 (8877 square m) walls which covered with plant on 10 square km in the city of Tokyo, and the green wall rate in the city of Tokyo was 0.88%. Vines, for example Parthenocissus tricuspidata and Hedera helix, were widely used. The factor of thinking better of the landscape in urban area was one of the easily management of plants. The three wall greening systems, a wall covered with hanging climbers and two types of self-contained living wall, mitigated the thermal environment. However its degree can be depended on the greening method and the greenery occupancy rate of wall

  5. Techno-Economic Assessment of Heat Transfer Fluid Buffering for Thermal Energy Storage in the Solar Field of Parabolic Trough Solar Thermal Power Plants

    Directory of Open Access Journals (Sweden)

    Jorge M. Llamas

    2017-08-01

    Full Text Available Currently, operating parabolic trough (PT solar thermal power plants, either solar-only or with thermal storage block, use the solar field as a heat transfer fluid (HTF thermal storage system to provide extra thermal capacity when it is needed. This is done by circulating heat transfer fluid into the solar field piping in order to create a heat fluid buffer. In the same way, by oversizing the solar field, it can work as an alternative thermal energy storage (TES system to the traditionally applied methods. This paper presents a solar field TES model for a standard solar field from a 50-MWe solar power plant. An oversized solar model is analyzed to increase the capacity storage system (HTF buffering. A mathematical model has been developed and different simulations have been carried out over a cycle of one year with six different solar multiples considered to represent the different oversized solar field configurations. Annual electricity generation and levelized cost of energy (LCOE are calculated to find the solar multiple (SM which makes the highest solar field thermal storage capacity possible within the minimum LCOE.

  6. Modelling and monitoring of Aquifer Thermal Energy Storage : impacts of soil heterogeneity, thermal interference and bioremediation

    NARCIS (Netherlands)

    Sommer, W.T.

    2015-01-01

    Modelling and monitoring of Aquifer Thermal Energy Storage

    Impacts of heterogeneity, thermal interference and bioremediation

    Wijbrand Sommer
    PhD thesis, Wageningen University, Wageningen, NL (2015)
    ISBN 978-94-6257-294-2

    Abstract

    Aquifer

  7. Experimental characterization of a solar cooker with thermal energy storage based on solar salt

    Science.gov (United States)

    Coccia, G.; Di Nicola, G.; Tomassetti, S.; Gabrielli, G.; Chieruzzi, M.; Pierantozzi, M.

    2017-11-01

    High temperature solar cooking allows to cook food fast and with good efficiency. An unavoidable drawback of this technology is that it requires nearly clear-sky conditions. In addition, evening cooking is difficult to be accomplished, particularly on the winter season during which solar radiation availability is limited to a few hours in the afternoon in most of countries. These restrictions could be overcome using a cooker thermal storage unit (TSU). In this work, a TSU based on solar salt was studied. The unit consists of two metal concentric cylindrical vessels, connected together to form a double-walled vessel. The volume between walls was filled with a certain amount of nitrate based phase change material (solar salt). In order to characterize the TSU, a test bench used to assess solar cooker performance was adopted. Experimental load tests with the TSU were carried out to evaluate the cooker performance. The obtained preliminary results show that the adoption of the solar salt TSU seems to allow both the opportunity of evening cooking and the possibility to better stabilize the cooker temperature when sky conditions are variable.

  8. Numerical investigation of a joint approach to thermal energy storage and compressed air energy storage in aquifers

    International Nuclear Information System (INIS)

    Guo, Chaobin; Zhang, Keni; Pan, Lehua; Cai, Zuansi; Li, Cai; Li, Yi

    2017-01-01

    Highlights: •One wellbore-reservoir numerical model was built to study the impact of ATES on CAESA. •With high injection temperature, the joint of ATES can improve CAESA performance. •The considerable utilization of geothermal occurs only at the beginning of operations. •Combination of CAESA and ATES can be achieved in common aquifers. -- Abstract: Different from conventional compressed air energy storage (CAES) systems, the advanced adiabatic compressed air energy storage (AA-CAES) system can store the compression heat which can be used to reheat air during the electricity generation stage. Thus, AA-CAES system can achieve a higher energy storage efficiency. Similar to the AA-CAES system, a compressed air energy storage in aquifers (CAESA) system, which is integrated with an aquifer thermal energy storage (ATES) could possibly achieve the same objective. In order to investigate the impact of ATES on the performance of CAESA, different injection air temperature schemes are designed and analyzed by using numerical simulations. Key parameters relative to energy recovery efficiencies of the different injection schemes, such as pressure distribution and temperature variation within the aquifers as well as energy flow rate in the injection well, are also investigated in this study. The simulations show that, although different injection schemes have a similar overall energy recovery efficiency (∼97%) as well as a thermal energy recovery efficiency (∼79.2%), the higher injection air temperature has a higher energy storage capability. Our results show the total energy storage for the injection air temperature at 80 °C is about 10% greater than the base model scheme at 40 °C. Sensitivity analysis reveal that permeability of the reservoir boundary could have significant impact on the system performance. However, other hydrodynamic and thermodynamic properties, such as the storage reservoir permeability, thermal conductivity, rock grain specific heat and rock

  9. Cloning single wall carbon nanotubes for hydrogen storage

    Energy Technology Data Exchange (ETDEWEB)

    Tour, James M [Rice Univ., Houston, TX (United States); Kittrell, Carter [Rice Univ., Houston, TX (United States)

    2012-08-30

    The purpose of this research is to development the technology required for producing 3-D nano-engineered frameworks for hydrogen storage based on sp2 carbon media, which will have high gravimetric and especially high volumetric uptake of hydrogen, and in an aligned fibrous array that will take advantage of the exceptionally high thermal conductivity of sp2 carbon materials to speed up the fueling process while minimizing or eliminating the need for internal cooling systems. A limitation for nearly all storage media using physisorption of the hydrogen molecule is the large amount of surface area (SA) occupied by each H2 molecule due to its large zero-point vibrational energy. This creates a conundrum that in order to maximize SA, the physisorption media is made more tenuous and the density is decreased, usually well below 1 kg/L, so that there comes a tradeoff between volumetric and gravimetric uptake. Our major goal was to develop a new type of media with high density H2 uptake, which favors volumetric storage and which, in turn, has the capability to meet the ultimate DoE H2 goals.

  10. Comparison for the interfacial and wall friction models in thermal-hydraulic system analysis codes

    International Nuclear Information System (INIS)

    Hwang, Moon Kyu; Park, Jee Won; Chung, Bub Dong; Kim, Soo Hyung; Kim, See Dal

    2007-07-01

    The average equations employed in the current thermal hydraulic analysis codes need to be closed with the appropriate models and correlations to specify the interphase phenomena along with fluid/structure interactions. This includes both thermal and mechanical interactions. Among the closure laws, an interfacial and wall frictions, which are included in the momentum equations, not only affect pressure drops along the fluid flow, but also have great effects for the numerical stability of the codes. In this study, the interfacial and wall frictions are reviewed for the commonly applied thermal-hydraulic system analysis codes, i.e. RELAP5-3D, MARS-3D, TRAC-M, and CATHARE

  11. Predictive Optimal Control of Active and Passive Building Thermal Storage Inventory

    Energy Technology Data Exchange (ETDEWEB)

    Gregor P. Henze; Moncef Krarti

    2005-09-30

    Cooling of commercial buildings contributes significantly to the peak demand placed on an electrical utility grid. Time-of-use electricity rates encourage shifting of electrical loads to off-peak periods at night and weekends. Buildings can respond to these pricing signals by shifting cooling-related thermal loads either by precooling the building's massive structure or the use of active thermal energy storage systems such as ice storage. While these two thermal batteries have been engaged separately in the past, this project investigated the merits of harnessing both storage media concurrently in the context of predictive optimal control. To pursue the analysis, modeling, and simulation research of Phase 1, two separate simulation environments were developed. Based on the new dynamic building simulation program EnergyPlus, a utility rate module, two thermal energy storage models were added. Also, a sequential optimization approach to the cost minimization problem using direct search, gradient-based, and dynamic programming methods was incorporated. The objective function was the total utility bill including the cost of reheat and a time-of-use electricity rate either with or without demand charges. An alternative simulation environment based on TRNSYS and Matlab was developed to allow for comparison and cross-validation with EnergyPlus. The initial evaluation of the theoretical potential of the combined optimal control assumed perfect weather prediction and match between the building model and the actual building counterpart. The analysis showed that the combined utilization leads to cost savings that is significantly greater than either storage but less than the sum of the individual savings. The findings reveal that the cooling-related on-peak electrical demand of commercial buildings can be considerably reduced. A subsequent analysis of the impact of forecasting uncertainty in the required short-term weather forecasts determined that it takes only very

  12. Investigation of Stratified Thermal Storage Tank Performance for Heating and Cooling Applications

    Directory of Open Access Journals (Sweden)

    Azharul Karim

    2018-04-01

    Full Text Available A large amount of energy is consumed by heating and cooling systems to provide comfort conditions for commercial building occupants, which generally contribute to peak electricity demands. Thermal storage tanks in HVAC systems, which store heating/cooling energy in the off-peak period for use in the peak period, can be used to offset peak time energy demand. In this study, a theoretical investigation on stratified thermal storage systems is performed to determine the factors that significantly influence the thermal performance of these systems for both heating and cooling applications. Five fully-insulated storage tank geometries, using water as the storage medium, were simulated to determine the effects of water inlet velocity, tank aspect ratio and temperature difference between charging (inlet and the tank water on mixing and thermocline formation. Results indicate that thermal stratification enhances with increased temperature difference, lower inlet velocities and higher aspect ratios. It was also found that mixing increased by 303% when the temperature difference between the tank and inlet water was reduced from 80 °C to 10 °C, while decreasing the aspect ratio from 3.8 to 1.0 increased mixing by 143%. On the other hand, increasing the inlet water velocity significantly increased the storage mixing. A new theoretical relationship between the inlet water velocity and thermocline formation has been developed. It was also found that inlet flow rates can be increased, without increasing the mixing, after the formation of the thermocline.

  13. High Density Thermal Energy Storage with Supercritical Fluids

    Science.gov (United States)

    Ganapathi, Gani B.; Wirz, Richard

    2012-01-01

    A novel approach to storing thermal energy with supercritical fluids is being investigated, which if successful, promises to transform the way thermal energy is captured and utilized. The use of supercritical fluids allows cost-affordable high-density storage with a combination of latent heat and sensible heat in the two-phase as well as the supercritical state. This technology will enhance penetration of several thermal power generation applications and high temperature water for commercial use if the overall cost of the technology can be demonstrated to be lower than the current state-of-the-art molten salt using sodium nitrate and potassium nitrate eutectic mixtures.

  14. Thermal energy storage for low grade heat in the organic Rankine cycle

    Science.gov (United States)

    Soda, Michael John

    Limits of efficiencies cause immense amounts of thermal energy in the form of waste heat to be vented to the atmosphere. Up to 60% of unrecovered waste heat is classified as low or ultra-low quality, making recovery difficult or inefficient. The organic Rankine cycle can be used to generate mechanical power and electricity from these low temperatures where other thermal cycles are impractical. A variety of organic working fluids are available to optimize the ORC for any target temperature range. San Diego State University has one such experimental ORC using R245fa, and has been experimenting with multiple expanders. One limitation of recovering waste heat is the sporadic or cyclical nature common to its production. This inconsistency makes sizing heat recovery ORC systems difficult for a variety of reasons including off-design-point efficiency loss, increased attrition from varying loads, unreliable outputs, and overall system costs. Thermal energy storage systems can address all of these issues by smoothing the thermal input to a constant and reliable level and providing back-up capacity for times when the thermal input is deactivated. Multiple types of thermal energy storage have been explored including sensible, latent, and thermochemical. Latent heat storage involves storing thermal energy in the reversible phase change of a phase change material, or PCM, and can have several advantages over other modalities including energy storage density, cost, simplicity, reliability, relatively constant temperature output, and temperature customizability. The largest obstacles to using latent heat storage include heat transfer rates, thermal cycling stability, and potentially corrosive PCMs. Targeting 86°C, the operating temperature of SDSU's experimental ORC, multiple potential materials were explored and tested as potential PCMs including Magnesium Chloride Hexahydrate (MgCl2˙6H2O), Magnesium Nitrate Hexahydrate (Mg(NO3)2˙6H 2O), montan wax, and carnauba wax. The

  15. An improved method for upscaling borehole thermal energy storage using inverse finite element modelling

    DEFF Research Database (Denmark)

    Tordrup, Karl Woldum; Poulsen, Søren Erbs; Bjørn, Henrik

    2017-01-01

    Dimensioning of large-scale borehole thermal energy storage (BTES) is inherently uncertain due to the natural variability of thermal conductivity and heat capacity in the storage volume. We present an improved method for upscaling a pilot BTES to full scale and apply the method to an operational...

  16. Effect of chemical treatments on hydrogen storage behaviors of multi-walled carbon nanotubes

    International Nuclear Information System (INIS)

    Lee, Seul-Yi; Park, Soo-Jin

    2010-01-01

    In this work, the hydrogen storage behaviors of chemically treated multi-walled carbon nanotubes (MWNTs) were investigated. The surface properties of the functionalized MWNTs were confirmed by Fourier transfer infrared spectroscopy, X-ray diffraction, the Boehm titration method, and zeta-potential measurements. The hydrogen storage capacity of the MWNTs was evaluated at 298 K and 100 bar. In the experimental results, it was found that the chemical treatments introduced functional groups onto the MWNT surfaces. The amount of hydrogen storage was enhanced, by acidic surface treatment, to 0.42 wt.% in the acidic-treated MWNTs compared with 0.26 wt.% in the as-received MWNTs. Meanwhile, the basic surface treatment actually reduced the hydrogen storage capacity, to 0.24 wt.% in the basic-treated MWNTs sample. Consequently, it could be concluded that hydrogen storage is greatly influenced by the acidic characteristics of MWNT surfaces, resulting in enhanced electron acceptor-donor interaction at interfaces.

  17. Summary Report for Concentrating Solar Power Thermal Storage Workshop: New Concepts and Materials for Thermal Energy Storage and Heat-Transfer Fluids, May 20, 2011

    Energy Technology Data Exchange (ETDEWEB)

    Glatzmaier, G.

    2011-08-01

    This document summarizes a workshop on thermal energy storage for concentrating solar power (CSP) that was held in Golden, Colorado, on May 20, 2011. The event was hosted by the U.S. Department of Energy (DOE), the National Renewable Energy Laboratory, and Sandia National Laboratories. The objective was to engage the university and laboratory research communities to identify and define research directions for developing new high-temperature materials and systems that advance thermal energy storage for CSP technologies. This workshop was motivated, in part, by the DOE SunShot Initiative, which sets a very aggressive cost goal for CSP technologies -- a levelized cost of energy of 6 cents per kilowatt-hour by 2020 with no incentives or credits.

  18. Thermal energy storage technologies for sustainability systems design, assessment and applications

    CERN Document Server

    Kalaiselvam, S

    2014-01-01

    Thermal Energy Storage Technologies for Sustainability is a broad-based overview describing the state-of-the-art in latent, sensible, and thermo-chemical energy storage systems and their applications across industries. Beginning with a discussion of the efficiency and conservation advantages of balancing energy demand with production, the book goes on to describe current state-of-the art technologies. Not stopping with description, the authors also discuss design, modeling, and simulation of representative systems, and end with several case studies of systems in use.Describes how thermal energ

  19. Thermal safety analysis of a dry storage cask for the Korean standard spent fuel - 16159

    International Nuclear Information System (INIS)

    Cha, Jeonghun; Kim, S.N.; Choi, K.W.

    2009-01-01

    A conceptual dry storage facility, which is based on a commercial dry storage facility, was designed for the Korea standard spent nuclear fuel (SNF) and preliminary thermal safety analysis was performed in this study. To perform the preliminary thermal analysis, a thermal analysis method was proposed. The thermal analysis method consists of 2 parts. By using the method, the surface temperature of the storage canister corresponding to the SNF clad temperature was calculated and the adequate air duct area was decided using the calculation result. The initial temperature of the facility was calculated and the fire condition and half air duct blockage were analyzed. (authors)

  20. Experiment study on the thermal properties of paraffin/kaolin thermal energy storage form-stable phase change materials

    International Nuclear Information System (INIS)

    Lv, Peizhao; Liu, Chenzhen; Rao, Zhonghao

    2016-01-01

    Highlights: • Different particle sizes of kaolin were employed to load paraffin. • The effects and reasons of particle size on thermal conductivity were studied. • Thermal property and thermal stability of the composites were investigated. • The leakage and thermal storage and release rate of the composites were studied. • The effect of vacuum impregnation method on thermal conductivity was investigated. - Abstract: In this paper, different particle sizes of kaolin were employed to incorporate paraffin via vacuum impregnation method. The paraffin/kaolin composites were characterized by Scanning Electron Microscope (SEM), X-Ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), Differential Scanning Calorimeter (DSC) and Thermogravimetry (TG). The results showed that the paraffin/kaolin composite with the largest particle size of kaolin (K4) has the highest thermal conductivity (0.413 W/(m K) at 20 °C) among the diverse composites. The latent heat capacity of paraffin/K4 is 119.49 J/g and the phase change temperature is 62.4 °C. In addition, the thermal properties and thermal conductivities of paraffin/K4 with different mass fraction of K4 (0–60%) were investigated. The thermal conductivities of the composites were explained in microcosmic field. The phonon mean free path determines the thermal conductivity, and it can be significantly affected by temperature and the contact surface area. The leaks, thermal storage and release properties of pure paraffin and paraffin/kaolin composites were investigated and the composites presented good thermal stabilities.

  1. Knudsen temperature jump and the Navier-Stokes hydrodynamics of granular gases driven by thermal walls.

    Science.gov (United States)

    Khain, Evgeniy; Meerson, Baruch; Sasorov, Pavel V

    2008-10-01

    Thermal wall is a convenient idealization of a rapidly vibrating plate used for vibrofluidization of granular materials. The objective of this work is to incorporate the Knudsen temperature jump at thermal wall in the Navier-Stokes hydrodynamic modeling of dilute granular gases of monodisperse particles that collide nearly elastically. The Knudsen temperature jump manifests itself as an additional term, proportional to the temperature gradient, in the boundary condition for the temperature. Up to a numerical prefactor O(1) , this term is known from kinetic theory of elastic gases. We determine the previously unknown numerical prefactor by measuring, in a series of molecular dynamics (MD) simulations, steady-state temperature profiles of a gas of elastically colliding hard disks, confined between two thermal walls kept at different temperatures, and comparing the results with the predictions of a hydrodynamic calculation employing the modified boundary condition. The modified boundary condition is then applied, without any adjustable parameters, to a hydrodynamic calculation of the temperature profile of a gas of inelastic hard disks driven by a thermal wall. We find the hydrodynamic prediction to be in very good agreement with MD simulations of the same system. The results of this work pave the way to a more accurate hydrodynamic modeling of driven granular gases.

  2. Nanoparticles for heat transfer and thermal energy storage

    Science.gov (United States)

    Singh, Dileep; Cingarapu, Sreeram; Timofeeva, Elena V.; Moravek, Michael

    2015-07-14

    An article of manufacture and method of preparation thereof. The article of manufacture and method of making the article includes an eutectic salt solution suspensions and a plurality of nanocrystalline phase change material particles having a coating disposed thereon and the particles capable of undergoing the phase change which provides increase in thermal energy storage. In addition, other articles of manufacture can include a nanofluid additive comprised of nanometer-sized particles consisting of copper decorated graphene particles that provide advanced thermal conductivity to heat transfer fluids.

  3. Computational Design of Non-natural Sugar Alcohols to Increase Thermal Storage Density: Beyond Existing Organic Phase Change Materials.

    Science.gov (United States)

    Inagaki, Taichi; Ishida, Toyokazu

    2016-09-14

    Thermal storage, a technology that enables us to control thermal energy, makes it possible to reuse a huge amount of waste heat, and materials with the ability to treat larger thermal energy are in high demand for energy-saving societies. Sugar alcohols are now one promising candidate for phase change materials (PCMs) because of their large thermal storage density. In this study, we computationally design experimentally unknown non-natural sugar alcohols and predict their thermal storage density as a basic step toward the development of new high performance PCMs. The non-natural sugar alcohol molecules are constructed in silico in accordance with the previously suggested molecular design guidelines: linear elongation of a carbon backbone, separated distribution of OH groups, and even numbers of carbon atoms. Their crystal structures are then predicted using the random search method and first-principles calculations. Our molecular simulation results clearly demonstrate that the non-natural sugar alcohols have potential ability to have thermal storage density up to ∼450-500 kJ/kg, which is significantly larger than the maximum thermal storage density of the present known organic PCMs (∼350 kJ/kg). This computational study suggests that, even in the case of H-bonded molecular crystals where the electrostatic energy contributes mainly to thermal storage density, the molecular distortion and van der Waals energies are also important factors to increase thermal storage density. In addition, the comparison between the three eight-carbon non-natural sugar alcohol isomers indicates that the selection of preferable isomers is also essential for large thermal storage density.

  4. Seasonal thermal energy storage in shallow geothermal systems: thermal equilibrium stage

    Directory of Open Access Journals (Sweden)

    Nowamooz Hossein

    2016-01-01

    Full Text Available This paper is dedicated to the study of seasonal heat storage in shallow geothermal installations in unsaturated soils for which hydrothermal properties such as degree of saturation and thermal conductivity vary with time throughout the profile. In the model, a semi-analytical model which estimates time-spatial thermal conductivity is coupled with a 2D cylindrical heat transfer modeling using finite difference method. The variation of temperature was obtained after 3 heating and cooling cycles for the different types of loads with maximum thermal load of qmax = 15 W.m−1 with variable angular frequency (8 months of heating and 4 months of cooling.and constant angular frequency (6 months of heating and 6 months of cooling to estimate the necessary number of cycles to reach the thermal equilibrium stage. The results show that we approach a thermal equilibrium stage where the same variation of temperature can be observed in soils after several heating and cooling cycles. Based on these simulations, the necessary number of cycles can be related to the total applied energy on the system and the minimum number of cycles is for a system with the total applied energy of 1.9qmax.

  5. David Adler Lectureship Award in the Field of Materials Physics: Racetrack Memory - a high-performance, storage class memory using magnetic domain-walls manipulated by current

    Science.gov (United States)

    Parkin, Stuart

    2012-02-01

    Racetrack Memory is a novel high-performance, non-volatile storage-class memory in which magnetic domains are used to store information in a ``magnetic racetrack'' [1]. The magnetic racetrack promises a solid state memory with storage capacities and cost rivaling that of magnetic disk drives but with much improved performance and reliability: a ``hard disk on a chip''. The magnetic racetrack is comprised of a magnetic nanowire in which a series of magnetic domain walls are shifted to and fro along the wire using nanosecond-long pulses of spin polarized current [2]. We have demonstrated the underlying physics that makes Racetrack Memory possible [3,4] and all the basic functions - creation, and manipulation of a train of domain walls and their detection. The physics underlying the current induced dynamics of domain walls will also be discussed. In particular, we show that the domain walls respond as if they have mass, leading to significant inertial driven motion of the domain walls over long times after the current pulses are switched off [3]. We also demonstrate that in perpendicularly magnetized nanowires there are two independent current driving mechanisms: one derived from bulk spin-dependent scattering that drives the domain walls in the direction of electron flow, and a second interfacial mechanism that can drive the domain walls either along or against the electron flow, depending on subtle changes in the nanowire structure. Finally, we demonstrate thermally induced spin currents are large enough that they can be used to manipulate domain walls. [4pt] [1] S.S.P. Parkin, US Patent 6,834,005 (2004); S.S.P. Parkin et al., Science 320, 190 (2008); S.S.P. Parkin, Scientific American (June 2009). [0pt] [2] M. Hayashi, L. Thomas, R. Moriya, C. Rettner and S.S.P. Parkin, Science 320, 209 (2008). [0pt] [3] L. Thomas, R. Moriya, C. Rettner and S.S.P. Parkin, Science 330, 1810 (2010). [0pt] [4] X. Jiang et al. Nat. Comm. 1:25 (2010) and Nano Lett. 11, 96 (2011).

  6. The thermal impact of aquifer thermal energy storage (ATES) systems: a case study in the Netherlands, combining monitoring and modeling

    Science.gov (United States)

    Visser, Philip W.; Kooi, Henk; Stuyfzand, Pieter J.

    2015-05-01

    Results are presented of a comprehensive thermal impact study on an aquifer thermal energy storage (ATES) system in Bilthoven, the Netherlands. The study involved monitoring of the thermal impact and modeling of the three-dimensional temperature evolution of the storage aquifer and over- and underlying units. Special attention was paid to non-uniformity of the background temperature, which varies laterally and vertically in the aquifer. Two models were applied with different levels of detail regarding initial conditions and heterogeneity of hydraulic and thermal properties: a fine-scale heterogeneity model which construed the lateral and vertical temperature distribution more realistically, and a simplified model which represented the aquifer system with only a limited number of homogeneous layers. Fine-scale heterogeneity was shown to be important to accurately model the ATES-impacted vertical temperature distribution and the maximum and minimum temperatures in the storage aquifer, and the spatial extent of the thermal plumes. The fine-scale heterogeneity model resulted in larger thermally impacted areas and larger temperature anomalies than the simplified model. The models showed that scattered and scarce monitoring data of ATES-induced temperatures can be interpreted in a useful way by groundwater and heat transport modeling, resulting in a realistic assessment of the thermal impact.

  7. Influence of nanomaterials on properties of latent heat solar thermal energy storage materials – A review

    International Nuclear Information System (INIS)

    Raam Dheep, G.; Sreekumar, A.

    2014-01-01

    Highlights: • Classification of phase change materials. • Studies on phase change properties of various phase change materials. • Influence of nanomaterials on properties of phase change materials. - Abstract: Thermal energy storage system plays a critical role in developing an efficient solar energy device. As far as solar thermal devices are concerned, there is always a mismatch between supply and demand due to intermittent and unpredictable nature of solar radiation. A well designed thermal energy storage system is capable to alleviate this demerit by providing a constant energy delivery to the load. Many research works is being carried out to determine the suitability of thermal energy storage system to integrate with solar thermal gadgets. This review paper summarizes the numerous investigations on latent heat thermal energy storage using phase change materials (PCM) and its classification, properties, selection criteria, potential research areas and studies involved to analyze the thermal–physical properties of PCM

  8. Influence of accelerated thermal charging and discharging cycles on thermo-physical properties of organic phase change materials for solar thermal energy storage applications

    International Nuclear Information System (INIS)

    Raam Dheep, G.; Sreekumar, A.

    2015-01-01

    Highlights: • Identification of organic phase change materials namely benzamide and sebacic acid. • Thermal reliability studies on identified phase change materials. • Measurement of phase transition temperature and latent heat of fusion. • Analysis of relative percentage difference (RPD%) in heat of fusion and melting temperature of benzamide and sebacic acid. - Abstract: Integration of appropriate thermal energy storage system plays a predominant role in upgrading the efficiency of solar thermal energy devices by reducing the incongruity between energy supply and demand. Latent heat thermal energy storage based on phase change materials (PCM) is found to be the most efficient and prospective method for storage of solar thermal energy. Ensuring the thermal reliability of PCM through large number of charging (melting) and discharging (solidification) cycles is a primary prerequisite to determine the suitability of PCM for a specific thermal energy storage applications. The present study explains the experimental analysis carried out on two PCM’s namely benzamide and sebacic acid to check the compatibility of the material in solar thermal energy storage applications. The selected materials were subjected to one thousand accelerated melting and solidification cycles in order to investigate the percentage of variation at different stages on latent heat of fusion, phase transition temperature, onset and peak melting temperature. Differential Scanning Calorimeter (DSC) was used to determine the phase transition temperature and heat of fusion upon completion of every 100 thermal cycles and continued up to 1000 cycles. Relative Percentage Difference (RPD%) is calculated to find out the absolute deviation of melting temperature and latent heat of fusion with respect to zeroth cycle. The experimental study recorded a melting temperatures of benzamide and sebacic acid as 125.09 °C and 135.92 °C with latent heat of fusion of 285.1 (J/g) and 374.4 (J/g). The

  9. Dynamic thermal reaction analysis of wall structures in various cooling operation conditions

    International Nuclear Information System (INIS)

    Yan, Biao; Long, Enshen; Meng, Xi

    2015-01-01

    Highlights: • Four different envelop structures are separately built in the same test building. • Cooling temperature and operation time were chosen as perturbations. • State Space Method is used to analyze the influence of wall sequence order. • The numerical models are validated by the comparisons of theory and test results. • The contrast of temperature change of different envelop structures was stark. - Abstract: This paper proposes a methodology of performance assessing of envelops under different cooling operation conditions, by focusing on indoor temperature change and dynamic thermal behavior performance of walls. To obtain a general relationship between the thermal environment change and the reaction of envelop, variously insulated walls made with the same insulation material are separately built in the same wall of a testing building with the four different structures, namely self-heat insulation (full insulation material), exterior insulation, internal insulation and intermediate insulation. The advantage of this setting is that the test targets are exposed to the same environmental variables, and the tests results are thus comparable. The target responses to two types of perturbations, cooling temperature and operation time were chosen as the important variations in the tests. Parameters of cooling set temperature of 22 °C and 18 °C, operation and restoring time 10 min and 15 min are set in the test models, and discussed with simulation results respectively. The results reveal that the exterior insulation and internal insulation are more sensitive to thermal environment change than self-heat insulation and intermediate insulation.

  10. Application of nanomaterials in solar thermal energy storage

    Science.gov (United States)

    Shamshirgaran, Seyed Reza; Khalaji Assadi, Morteza; Viswanatha Sharma, Korada

    2018-06-01

    Solar thermal conversion technology harvests the sun's energy, rather than fossil fuels, to generate low-cost, low/zero-emission energy in the form of heating, cooling or electrical form for residential, commercial, and industrial sectors. The advent of nanofluids and nanocomposites or phase change materials, is a new field of study which is adapted to enhance the efficiency of solar collectors. The concepts of thermal energy storage technologies are investigated and the role of nanomaterials in energy conversion is discussed. This review revealed that although the exploitation of nanomaterials will boost the performance of solar collectors almost in all cases, this would be accompanied by certain challenges such as production cost, instability, agglomeration and erosion. Earlier studies have dealt with the enhancement of thermal conductivity and heat capacity; however, less attention has been given to the facing challenges. Moreover, no exact criteria can be found for the selection of appropriate nanomaterials and their properties for a specific application. In most research studies, the nanoparticles' material and properties have not been selected based on estimated values so that all the aspects of desired application could be considered simultaneously. The wide spread use of nanomaterials can lead to cost effective solutions as well. Therefore, it seems there should be a sense of techno-economic optimization in exploiting nanomaterials for solar thermal energy storage applications. The optimization should cover the key parameters, particularly nanoparticle type, size, loading and shape which depends on the sort of application and also dispersion technology.

  11. Application of nanomaterials in solar thermal energy storage

    Science.gov (United States)

    Shamshirgaran, Seyed Reza; Khalaji Assadi, Morteza; Viswanatha Sharma, Korada

    2017-12-01

    Solar thermal conversion technology harvests the sun's energy, rather than fossil fuels, to generate low-cost, low/zero-emission energy in the form of heating, cooling or electrical form for residential, commercial, and industrial sectors. The advent of nanofluids and nanocomposites or phase change materials, is a new field of study which is adapted to enhance the efficiency of solar collectors. The concepts of thermal energy storage technologies are investigated and the role of nanomaterials in energy conversion is discussed. This review revealed that although the exploitation of nanomaterials will boost the performance of solar collectors almost in all cases, this would be accompanied by certain challenges such as production cost, instability, agglomeration and erosion. Earlier studies have dealt with the enhancement of thermal conductivity and heat capacity; however, less attention has been given to the facing challenges. Moreover, no exact criteria can be found for the selection of appropriate nanomaterials and their properties for a specific application. In most research studies, the nanoparticles' material and properties have not been selected based on estimated values so that all the aspects of desired application could be considered simultaneously. The wide spread use of nanomaterials can lead to cost effective solutions as well. Therefore, it seems there should be a sense of techno-economic optimization in exploiting nanomaterials for solar thermal energy storage applications. The optimization should cover the key parameters, particularly nanoparticle type, size, loading and shape which depends on the sort of application and also dispersion technology.

  12. Micro/nanoencapsulated n-nonadecane with poly(methyl methacrylate) shell for thermal energy storage

    International Nuclear Information System (INIS)

    Sarı, Ahmet; Alkan, Cemil; Biçer, Alper; Altuntaş, Ayşe; Bilgin, Cahit

    2014-01-01

    Graphical abstract: This paper was aimed to prepare, characterize and determinate of thermal energy storage properties of PMMA/C19 micro/nanocapsules as a novel encapsulated phase change material (M/N-EPCM). The chemical structure of the prepared M/N-EPCM was verified using FTIR spectroscopy method. The analysis results obtained from POM and SEM indicated that the synthesized capsules had virtually spherical-shape. The PSD analysis indicated that the M/N-EPCM capsules had mean diameter of 8.18 μm and the percentage of the capsules with nanosize was 4.90 (v/v). The DSC results showed that the synthesized M/N-PCM had a melting temperature and total latent heat value as 31.23 °C and 139.20 J/g, respectively. It can be also deduced from all results that the synthesized M/N-EPCM had promising thermal energy storage potential due to its good latent heat thermal energy storage properties, thermal durability, thermal reliability, chemical stability, thermal conductivity and phase change reversibility properties. - Highlights: • The chemical structure of the prepared M/N-EPCM was verified using FTIR spectroscopy method. • POM and SEM results indicated that the M/N-EPCM had virtually spherical shape-appearance. • The M/N-EPCM had mean diameter of 8.18 μm and the percentage of the capsules with nanosize was 4.90 (v/v). • The M/N-PCM had a melting temperature and total latent heat value as 31.23 °C and 139.20 J/g, respectively. • The M/N-EPCM had promising thermal energy storage potential. - Abstract: This paper was aimed to prepare, characterize and determine the thermal energy storage properties of poly(methyl methacrylate) (PMMA)/n-nonadecane (C19) capsules as a novel micro/nanoencapsulated phase change material (M/N-EPCM). The M/N-EPCM was fabricated via emulsion polymerization reaction of methylmethacrylate (MMA) monomer occurred around C19 used as core material. The chemical structure of the prepared M/N-EPCM was verified using Fourier transform infrared

  13. Characteristics of phase-change materials containing oxide nano-additives for thermal storage.

    Science.gov (United States)

    Teng, Tun-Ping; Yu, Chao-Chieh

    2012-11-06

    In this study, the authors report the production of nanocomposite-enhanced phase-change materials (NEPCMs) using the direct-synthesis method by mixing paraffin with alumina (Al2O3), titania (TiO2), silica (SiO2), and zinc oxide (ZnO) as the experimental samples. Al2O3, TiO2, SiO2, and ZnO were dispersed into three concentrations of 1.0, 2.0, and 3.0 wt.%. Through heat conduction and differential scanning calorimeter experiments to evaluate the effects of varying concentrations of the nano-additives on the heat conduction performance and thermal storage characteristics of NEPCMs, their feasibility for use in thermal storage was determined. The experimental results demonstrate that TiO2 is more effective than the other additives in enhancing both the heat conduction and thermal storage performance of paraffin for most of the experimental parameters. Furthermore, TiO2 reduces the melting onset temperature and increases the solidification onset temperature of paraffin. This allows the phase-change heat to be applicable to a wider temperature range, and the highest decreased ratio of phase-change heat is only 0.46%, compared to that of paraffin. Therefore, this study demonstrates that TiO2, added to paraffin to form NEPCMs, has significant potential for enhancing the thermal storage characteristics of paraffin.

  14. EVALUATION OF THERMAL INSULATION FOR THREE DIFFERENT MATERIALS USED IN CONSTRUCTION AND COMPLETION OF EXTERNAL WALLS

    Directory of Open Access Journals (Sweden)

    Marcio Carlos Navroski

    2010-05-01

    Full Text Available Summers increasingly hot are bringing large thermal problems within homes and businesses, leading to increased demand for installation of air conditioners and the consequent high energy consumption. Constructions with thermal insulation on its external walls thatcould reduce energy use or even supply the use of such equipment. Due to these factors the present study was to evaluate the insulation in three boxes built with different materials, one made of wooden boards with plain walls, and two built with plywood, wall insulation andinterior walls filled with rice husk and Styrofoam®. The boxes were built after placed in drying oven at 40 °C, then noted the temperature inside the same interval every five minutes using a digital thermometer. The box with inner Styrofoam® showed the lowest variation among the three evaluated, followed by the box of rice husk. These two materials also showed good thermal initial, unlike the box built only with wood, which showed a large interiorheating, lay in a drying oven.

  15. Experimental study on thermal storage performance of binary mixtures of fatty acids

    Science.gov (United States)

    Yan, Quanying; Zhang, Jing; Liu, Chao; Liu, Sha; Sun, Xiangyu

    2018-02-01

    We selected five kinds of fatty acids including the capric acid, stearic acid, lauric acid, palmitic acid and myristic acid and mixed them to prepare10 kinds of binary mixtures of fatty acids according to the predetermined proportion,tested the phase change temperature and latent heat of mixtures by differential scanning calorimetry(DSC). In order to find the fatty acid mixture which has suitable phase change temperature, the larger phase change latent heat and can be used for phase change wall. The results showed that the phase change temperature and latent heats of the binary mixtures of fatty acids decreased compared with the single component;The phase change temperature of the binary mixtures of fatty acids containing capric acid were lower, the range was roughly 20∼30°C,and latent heat is large,which are ideal phase change materials for phase change wall energy storage;The phase change temperature of the binary mixtures consisting of other fatty acids were still high,didn’t meet the temperature requirements of the wall energy storage.

  16. Novel “open-sorption pipe” reactor for solar thermal energy storage

    International Nuclear Information System (INIS)

    Aydin, Devrim; Casey, Sean P.; Chen, Xiangjie; Riffat, Saffa

    2016-01-01

    Highlights: • A novel ‘open sorption pipe’ heat storage was experimentally investigated. • Effect of absolute moisture levels on heat storage performance was analyzed. • Hygrothermal-cyclic performances of Zeolite 13X and vermiculite–calcium chloride were compared. • Vermiculite–calcium chloride has more durable performance than Zeolite at 80 °C regeneration temperature. • Sorption pipe system using vermiculite–calcium chloride provides energy storage density of 290 kW h/m"3. - Abstract: In the last decade sorption heat storage systems are gaining attention due to their high energy storage density and long term heat storage potential. Sorption reactor development is vital for future progress of these systems however little has done on this topic. In this study, a novel sorption pipe reactor for solar thermal energy storage is developed and experimentally investigated to fulfill this gap. The modular heat storage system consists of sorption pipe units with an internal perforated diffuser pipe network and the sorption material filled in between. Vermiculite–calcium chloride composite material was employed as the sorbent in the reactor and its thermal performance was investigated under different inlet air humidity levels. It was found that, a fourfold increase of absolute humidity difference of air led to approximately 2.3 times boost in average power output from 313 W to 730 W and an 8.8 times boost of average exergy from 4.8 W to 42.3 W. According to the testing results, each of three sorption pipes can provide an average air temperature lift of 24.1 °C over 20 h corresponding to a system total energy storage capacity of 25.5 kW h and energy storage density of 290 kW h/m"3. Within the study, vermiculite–calcium chloride performance was also compared with the widely investigated Zeolite 13X. Vermiculite–calcium chloride showed a good cyclic ability at regeneration temperature of 80 °C with a steadier thermal performance than Zeolite

  17. Heat transfer characteristics of building walls using phase change material

    Science.gov (United States)

    Irsyad, M.; Pasek, A. D.; Indartono, Y. S.; Pratomo, A. W.

    2017-03-01

    Minimizing energy consumption in air conditioning system can be done with reducing the cooling load in a room. Heat from solar radiation which passes through the wall increases the cooling load. Utilization of phase change material on walls is expected to decrease the heat rate by storing energy when the phase change process takes place. The stored energy is released when the ambient temperature is low. Temperature differences at noon and evening can be utilized as discharging and charging cycles. This study examines the characteristics of heat transfer in walls using phase change material (PCM) in the form of encapsulation and using the sleeve as well. Heat transfer of bricks containing encapsulated PCM, tested the storage and released the heat on the walls of the building models were evaluated in this study. Experiments of heat transfer on brick consist of time that is needed for heat transfer and thermal conductivity test as well. Experiments were conducted on a wall coated by PCM which was exposed on a day and night cycle to analyze the heat storage and heat release. PCM used in these experiments was coconut oil. The measured parameter is the temperature at some points in the brick, walls and ambient temperature as well. The results showed that the use of encapsulation on an empty brick can increase the time for thermal heat transfer. Thermal conductivity values of a brick containing encapsulated PCM was lower than hollow bricks, where each value was 1.3 W/m.K and 1.6 W/m.K. While the process of heat absorption takes place from 7:00 am to 06:00 pm, and the release of heat runs from 10:00 pm to 7:00 am. The use of this PCM layer can reduce the surface temperature of the walls of an average of 2°C and slows the heat into the room.

  18. Economic feasibility of thermal energy storage systems

    Energy Technology Data Exchange (ETDEWEB)

    Habeebullah, B.A. [Faculty of Engineering, King Abdulaziz University, Jeddah (Saudi Arabia)

    2007-07-01

    This paper investigates the economic feasibility of both building an ice thermal storage and structure a time of rate tariff for the unique air conditioning (A/C) plant of the Grand Holy Mosque of Makkah, Saudi Arabia. The features of the building are unique where the air-conditioned 39,300 m{sup 2} zone is open to the atmosphere and the worshippers fully occupy the building five times a day, in addition hundreds of thousands of worshippers attend the blessed weekend's prayer at noontime, which escalates the peak electricity load. For economic analysis, the objective function is the daily electricity bill that includes the operation cost and the capital investment of the ice storage system. The operation cost is function of the energy imported for operating the plant in which the tariff structure, number of operating hours and the ambient temperature are parameters. The capital recovery factor is calculated for 10% interest rate and payback period of 10 years. Full and partial load storage scenarios are considered. The results showed that with the current fixed electricity rate (0.07 $/kWh), there is no gain in introducing ice storage systems for both storage schemes. Combining energy storage and an incentive time structured rate showed reasonable daily bill savings. For base tariff of 0.07 $/kWh during daytime operation and 0.016 $/kWh for off-peak period, savings were achieved for full load storage scenario. Different tariff structure is discussed and the break-even nighttime rate was determined (varies between 0.008 and 0.03 $/kWh). Partial load storage scenario showed to be unattractive where the savings for the base structured tariff was insignificant. (author)

  19. Thermodynamic model of a thermal storage air conditioning system with dynamic behavior

    International Nuclear Information System (INIS)

    Fleming, Evan; Wen, Shaoyi; Shi, Li; Silva, Alexandre K. da

    2013-01-01

    Highlights: • We developed an automotive thermal storage air conditioning system model. • The thermal storage unit utilizes phase change materials. • We use semi-analytic solution to the coupled phase change and forced convection. • We model the airside heat exchange using the NTU method. • The system model can incorporate dynamic inputs, e.g. variable inlet airflow. - Abstract: A thermodynamic model was developed to predict transient behavior of a thermal storage system, using phase change materials (PCMs), for a novel electric vehicle climate conditioning application. The main objectives of the paper are to consider the system’s dynamic behavior, such as a dynamic air flow rate into the vehicle’s cabin, and to characterize the transient heat transfer process between the thermal storage unit and the vehicle’s cabin, while still maintaining accurate solution to the complex phase change heat transfer. The system studied consists of a heat transfer fluid circulating between either of the on-board hot and cold thermal storage units, which we refer to as thermal batteries, and a liquid–air heat exchanger that provides heat exchange with the incoming air to the vehicle cabin. Each thermal battery is a shell-and-tube configuration where a heat transfer fluid flows through parallel tubes, which are surrounded by PCM within a larger shell. The system model incorporates computationally inexpensive semi-analytic solution to the conjugated laminar forced convection and phase change problem within the battery and accounts for airside heat exchange using the Number of Transfer Units (NTUs) method for the liquid–air heat exchanger. Using this approach, we are able to obtain an accurate solution to the complex heat transfer problem within the battery while also incorporating the impact of the airside heat transfer on the overall system performance. The implemented model was benchmarked against a numerical study for a melting process and against full system

  20. Numerical model for the thermal behavior of thermocline storage tanks

    Science.gov (United States)

    Ehtiwesh, Ismael A. S.; Sousa, Antonio C. M.

    2018-03-01

    Energy storage is a critical factor in the advancement of solar thermal power systems for the sustained delivery of electricity. In addition, the incorporation of thermal energy storage into the operation of concentrated solar power systems (CSPs) offers the potential of delivering electricity without fossil-fuel backup even during peak demand, independent of weather conditions and daylight. Despite this potential, some areas of the design and performance of thermocline systems still require further attention for future incorporation in commercial CSPs, particularly, their operation and control. Therefore, the present study aims to develop a simple but efficient numerical model to allow the comprehensive analysis of thermocline storage systems aiming better understanding of their dynamic temperature response. The validation results, despite the simplifying assumptions of the numerical model, agree well with the experiments for the time evolution of the thermocline region. Three different cases are considered to test the versatility of the numerical model; for the particular type of a storage tank with top round impingement inlet, a simple analytical model was developed to take into consideration the increased turbulence level in the mixing region. The numerical predictions for the three cases are in general good agreement against the experimental results.

  1. Experimental investigation and exergy analysis on thermal storage integrated micro-cogeneration system

    International Nuclear Information System (INIS)

    Johar, Dheeraj Kishor; Sharma, Dilip; Soni, Shyam Lal; Gupta, Pradeep K.; Goyal, Rahul

    2017-01-01

    Highlights: • Energy Storage System is integrated with Micro cogeneration system. • Erythritol is used as Phase Change Material. • Maximum energy saved is 15.2%. • Maximum exergy saved is 4.22%. • Combined systems are feasible to increase energy and exergy efficiency. - Abstract: This paper describes the performance of thermal storage integrated micro-cogeneration system based on single cylinder diesel engine. In addition to electricity generated from genset, waste heat from hot exhaust of diesel engine was used to heat water in a double pipe heat exchanger of 67.70 cm length with inside tube diameter of 3.81 cm and outside tube diameter of 5.08 cm. Additionally, a latent heat thermal energy storage system was also integrated with this cogeneration system. A shell and tube type heat exchanger of 346 mm diameter and 420 mm height with 45 tubes of 18 mm diameter each was designed and fabricated, to store thermal energy, in which Erythritol (C_4H_1_0O_4) was used as phase changing material. The test results show that micro capacity (4.4 kW), stationary, single cylinder, diesel engine can be successfully utilized to simultaneously produce power as well as heating, and to also store thermal energy. Slight decrease in engine performance was observed when double pipe heat exchanger and latent heat thermal energy storage system was integrated with engine but the amount of energy which could be recovered was significant. Maximum percentage of energy saved was obtained at a load of 3.6 kW and was 15.2%.

  2. Central unresolved issues in thermal energy storage for building heating and cooling

    Energy Technology Data Exchange (ETDEWEB)

    Swet, C.J.; Baylin, F.

    1980-07-01

    This document explores the frontier of the rapidly expanding field of thermal energy storage, investigates unresolved issues, outlines research aimed at finding solutions, and suggests avenues meriting future research. Issues related to applications include value-based ranking of storage concepts, temperature constraints, consistency of assumptions, nomenclature and taxonomy, and screening criteria for materials. Issues related to technologies include assessing seasonal storage concepts, diurnal coolness storage, selection of hot-side storage concepts for cooling-only systems, phase-change storage in building materials, freeze protection for solar water heating systems, and justification of phase-change storage for active solar space heating.

  3. Conceptual assessment and thermal hydraulic analysis of MVDS system for the dry storage of reduced metal fuel

    International Nuclear Information System (INIS)

    Lee, J. C.; Bang, K. S.; Shin, H. S.; Joo, J. S.; Su, K. S.; Kim, H. D.

    2003-01-01

    Conceptual assessment and thermal hydraulic analysis of MVDS storage system have been carried out for application of reduced metal fuel. The storage concept was established considering the optimum weight, storage volume and thermal efficiency. The capacity of MVDS system for loading the reduced metal fuel has four times as compared with existing PWR fuel storage system. In the results of thermal analysis, the maximum temperature of metal fuel was estimated to be 110 .deg. C which is lower than the allowable value under normal operation condition. Therefore, it is shown that the MVDS system can feasibly accomodate the reduced metal fuel in aspect of thermal safety

  4. Effect of brine flow rate on the performance of a spiral-jacketed thermal storage tank used for SDHW systems: A computational fluid dynamics study

    International Nuclear Information System (INIS)

    Baek, Seung Man; Nam, Jin Hyun; Hong, Hiki; Kim, Charn-Jung

    2011-01-01

    This study numerically investigates the effect of the brine flow rate on the thermal performance of a spiral-jacketed thermal storage tank (TST) installed in a solar domestic hot water (SDHW) system. The spiral-jacketed TST is a TST with a mantle heat exchanger, consisting of a vertical, cylindrical water tank for energy storage and a spiral brine flow path attached to the tank wall for heat transfer. A computational fluid dynamics (CFD) model was constructed based on the actual geometry of a spiral-jacketed TST. In addition, the boundary conditions were defined by considering solar radiation and ambient temperature data that were measured during experimental operation of the SDHW system. The numerical results demonstrated that an increase in the brine flow rate enhances the thermal efficiency of the TST due to higher heat transfer coefficients in the spiral path, and also leads to reduced thermal stratification in the TST. On the other hand, a lower brine flow rate increased the heat transfer rate at the inlet of the spiral path near the top of the TST, which resulted in enhanced thermal stratification. The optimal range for the rate of brine flow rate is discussed with respect to the thermal efficiency of the TST and the required pumping power for brine circulation in the spiral flow path. - Highlights: → A CFD model was developed for a spiral-jacketed thermal storage tank (TST) installed in a solar domestic hot water (SDHW) system. → Effects of brine flow rate on the overall performance of the spiral-jacketed TST were numerically investigated. → Higher brine flow rates slightly increased the solar energy acquired by the TST, but it also increased the pump power required to circulate the brine. → Lower brine flow rates were found to be a better option for the spiral-jacketed TST, by maximizing the exergy of the SDHW system.

  5. A numerical study of external building walls containing phase change materials (PCM)

    International Nuclear Information System (INIS)

    Izquierdo-Barrientos, M.A.; Belmonte, J.F.; Rodríguez-Sánchez, D.; Molina, A.E.; Almendros-Ibáñez, J.A.

    2012-01-01

    Phase Change Materials (PCMs) have been receiving increased attention, due to their capacity to store large amounts of thermal energy in narrow temperature ranges. This property makes them ideal for passive heat storage in the envelopes of buildings. To study the influence of PCMs in external building walls, a one-dimensional transient heat transfer model has been developed and solved numerically using a finite difference technique. Different external building wall configurations were analyzed for a typical building wall by varying the location of the PCM layer, the orientation of the wall, the ambient conditions and the phase transition temperature of the PCM. The integration of a PCM layer into a building wall diminished the amplitude of the instantaneous heat flux through the wall when the melting temperature of the PCM was properly selected according to the season and wall orientation. Conversely, the results of the work show that there is no significant reduction in the total heat lost during winter regardless of the wall orientation or PCM transition temperature. Higher differences were observed in the heat gained during the summer period, due to the elevated solar radiation fluxes. The high thermal inertia of the wall implies that the inclusion of a PCM layer increases the thermal load during the day while decreasing the thermal load during the night. - Highlights: ► A comparative simulation of a building wall with and without PCMs has been conducted. ► PCM is selected according with the season, the wall orientation and the melting temperature. ► PCM in a building wall help to diminish the internal air temperature swings and to regulate the heat transfer.

  6. Gas storage cylinder formed from a composition containing thermally exfoliated graphite

    Science.gov (United States)

    Prud'Homme, Robert K. (Inventor); Aksay, Ilhan A. (Inventor)

    2012-01-01

    A gas storage cylinder or gas storage cylinder liner, formed from a polymer composite, containing at least one polymer and a modified graphite oxide material, which is a thermally exfoliated graphite oxide with a surface area of from about 300 m(exp 2)/g to 2600 m(exp 2)2/g.

  7. Gas storage materials, including hydrogen storage materials

    Science.gov (United States)

    Mohtadi, Rana F; Wicks, George G; Heung, Leung K; Nakamura, Kenji

    2013-02-19

    A material for the storage and release of gases comprises a plurality of hollow elements, each hollow element comprising a porous wall enclosing an interior cavity, the interior cavity including structures of a solid-state storage material. In particular examples, the storage material is a hydrogen storage material such as a solid state hydride. An improved method for forming such materials includes the solution diffusion of a storage material solution through a porous wall of a hollow element into an interior cavity.

  8. Design aspects of integrated compact thermal storage system for solar dryer applications

    International Nuclear Information System (INIS)

    Rajaraman, R.; Velraj, R.; Renganarayanan, S.

    2000-01-01

    Solar energy is an excellent source for drying of crops, fruits, vegetables and other agricultural and forest products. Though the availability of solar energy is plenty, it is time dependent in nature. The energy need for some applications is also time dependent, but in a different pattern and phase from the solar energy supply. This implies that the solar dryer should be integrated with an efficient thermal storage system to match the time-dependent supply and end-use requirements. Based on the studies carried out on Latent Heat Thermal Storage (LHTS) Systems, it is observed that when air is used as the heat transfer fluid in LHTS system, nearly uniform surface heat flux can be achieved. Hence the LHTS systems are most suitable for air based solar drying applications. In the present work some major conclusions arrived from the investigations on LHTS systems and the design considerations for the integrated latent heat thermal storage for the solar dryer are reported. (Author)

  9. Investigation of the charge boost technology for the efficiency increase of closed sorption thermal energy storage systems

    Science.gov (United States)

    Rohringer, C.; Engel, G.; Köll, R.; Wagner, W.; van Helden, W.

    2017-10-01

    The inclusion of solar thermal energy into energy systems requires storage possibilities to overcome the gap between supply and demand. Storage of thermal energy with closed sorption thermal energy systems has the advantage of low thermal losses and high energy density. However, the efficiency of these systems needs yet to be increased to become competitive on the market. In this paper, the so-called “charge boost technology” is developed and tested via experiments as a new concept for the efficiency increase of compact thermal energy storages. The main benefit of the charge boost technology is that it can reach a defined state of charge for sorption thermal energy storages at lower temperature levels than classic pure desorption processes. Experiments are conducted to provide a proof of principle for this concept. The results show that the charge boost technology does function as predicted and is a viable option for further improvement of sorption thermal energy storages. Subsequently, a new process application is developed by the author with strong focus on the utilization of the advantages of the charge boost technology over conventional desorption processes. After completion of the conceptual design, the theoretical calculations are validated via experiments.

  10. Study on paraffin/expanded graphite composite phase change thermal energy storage material

    International Nuclear Information System (INIS)

    Zhang Zhengguo; Fang Xiaoming

    2006-01-01

    A paraffin/expanded graphite composite phase change thermal energy storage material was prepared by absorbing the paraffin into an expanded graphite that has an excellent absorbability. In such a composite, the paraffin serves as a latent heat storage material and the expanded graphite acts as the supporting material, which prevents leakage of the melted paraffin from its porous structure due to the capillary and surface tension forces. The inherent structure of the expanded graphite did not change in the composite material. The solid-liquid phase change temperature of the composite PCM was the same as that of the paraffin, and the latent heat of the paraffin/expanded graphite composite material was equivalent to the calculated value based on the mass ratio of the paraffin in the composite. The heat transfer rate of the paraffin/expanded graphite composite was obviously higher than that of the paraffin due to the combination with the expanded graphite that had a high thermal conductivity. The prepared paraffin/expanded graphite composite phase change material had a large thermal storage capacity and improved thermal conductivity and did not experience liquid leakage during its solid-liquid phase change

  11. Low Molecular Weight Norbornadiene Derivatives for Molecular Solar-Thermal Energy Storage.

    Science.gov (United States)

    Quant, Maria; Lennartson, Anders; Dreos, Ambra; Kuisma, Mikael; Erhart, Paul; Börjesson, Karl; Moth-Poulsen, Kasper

    2016-09-05

    Molecular solar-thermal energy storage systems are based on molecular switches that reversibly convert solar energy into chemical energy. Herein, we report the synthesis, characterization, and computational evaluation of a series of low molecular weight (193-260 g mol(-1) ) norbornadiene-quadricyclane systems. The molecules feature cyano acceptor and ethynyl-substituted aromatic donor groups, leading to a good match with solar irradiation, quantitative photo-thermal conversion between the norbornadiene and quadricyclane, as well as high energy storage densities (396-629 kJ kg(-1) ). The spectroscopic properties and energy storage capability have been further evaluated through density functional theory calculations, which indicate that the ethynyl moiety plays a critical role in obtaining the high oscillator strengths seen for these molecules. © 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

  12. A coupled nuclear reactor thermal energy storage system for enhanced load following operation

    International Nuclear Information System (INIS)

    Alameri, Saeed A.; King, Jeffrey C.

    2013-01-01

    Nuclear power plants operate most economically at a constant power level, providing base load electric power. In an energy grid containing a high fraction of renewable power sources, nuclear reactors may be subject to significantly variable power demands. These variable power demands can negatively impact the effective capacity factor of the reactor and result in severe economic penalties. Coupling a nuclear reactor to a large thermal energy storage block will allow the reactor to better respond to variable power demands. In the system described in this paper, a Prismatic core Advanced High Temperature Reactor supplies constant power to a lithium chloride molten salt thermal energy storage block that provides thermal power as needed to a closed Brayton cycle energy conversion system. During normal operation, the thermal energy storage block stores thermal energy during the night for use in the times of peak demand during the day. In this case, the nuclear reactor stays at a constant thermal power level. After a loss of forced circulation, the reactor reaches a shut down state in less than half an hour and the average fuel, graphite and coolant temperatures remain well within the design limits over the duration of the transient, demonstrating the inherent safety of the coupled system. (author)

  13. Thermal enhancement of charge and discharge cycles for adsorbed natural gas storage

    KAUST Repository

    Rahman, Kazi Afzalur; Loh, Wai Soong; Chakraborty, Anutosh; Saha, Bidyut Baran; Chun, Won Gee; Ng, Kim Choon

    2011-01-01

    The usage of adsorbed natural gas (ANG) storage is hindered by the thermal management during the adsorption and desorption processes. An effective thermal enhancement is thus essential for the development of the ANG technology and the motivation

  14. Impacts of convection on high-temperature aquifer thermal energy storage

    Science.gov (United States)

    Beyer, Christof; Hintze, Meike; Bauer, Sebastian

    2016-04-01

    Seasonal subsurface heat storage is increasingly used in order to overcome the temporal disparities between heat production from renewable sources like solar thermal installations or from industrial surplus heat and the heat demand for building climatisation or hot water supply. In this context, high-temperature aquifer thermal energy storage (ATES) is a technology to efficiently store and retrieve large amounts of heat using groundwater wells in an aquifer to inject or withdraw hot or cold water. Depending on the local hydrogeology and temperature amplitudes during high-temperature ATES, density differences between the injected hot water and the ambient groundwater may induce significant convective flow components in the groundwater flow field. As a consequence, stored heat may accumulate at the top of the storage aquifer which reduces the heat recovery efficiency of the ATES system. Also, an accumulation of heat at the aquifer top will induce increased emissions of heat to overlying formations with potential impacts on groundwater quality outside of the storage. This work investigates the impacts of convective heat transport on the storage efficiency of a hypothetical high-temperature ATES system for seasonal heat storage as well as heat emissions to neighboring formations by numerical scenario simulations. The coupled groundwater flow and heat transport code OpenGeoSys is used to simulate a medium scale ATES system operating in a sandy aquifer of 20 m thickness with an average groundwater temperature of 10°C and confining aquicludes at top and bottom. Seasonal heat storage by a well doublet (i.e. one fully screened "hot" and "cold" well, respectively) is simulated over a period of 10 years with biannual injection / withdrawal cycles at pumping rates of 15 m³/h and for different scenarios of the temperature of the injected water (20, 35, 60 and 90 °C). Simulation results show, that for the simulated system significant convective heat transport sets in when

  15. Fabrication and analysis of small-scale thermal energy storage with conductivity enhancement

    International Nuclear Information System (INIS)

    Thapa, Suvhashis; Chukwu, Sam; Khaliq, Abdul; Weiss, Leland

    2014-01-01

    Highlights: • Useful thermal conductivity envelope established for small scale TES. • Paraffin conductivity enhanced from .5 to 3.8 W/m K via low-cost copper insert. • Conductivity increase beyond 5 W/m K shows diminished returns. • Storage with increased conductivity lengthened thermoelectric output up to 247 s. - Abstract: The operation and useful operating parameters of a small-scale Thermal Energy Storage (TES) device that collects and stores heat in a Phase Change Material (PCM) is explored. The PCM utilized is an icosane wax. A physical device is constructed on the millimeter scale to examine specific effects of low-cost thermal conductivity enhancements that include copper foams and other metallic inserts. Numerical methods are utilized to establish useful operating range of small-scale TES devices in general, and the limits of thermal conductivity enhancement on thermoelectric operation specifically. Specific attention is paid to the manufacturability of the various constructs as well as the resulting thermal conductivity enhancement. A maximum thermal conductivity of 3.8 W/m K is achieved in experimental testing via copper foam enhancement. A simplified copper matrix achieves conductivity of 3.7 W/m K and allows significantly reduced fabrication effort. These results compare favorably to baseline wax conductivity of .5 W/m K. Power absorption is recorded of about 900 W/m 2 . Modeling reveals diminishing returns beyond 4–6 W/m K for devices on this scale. Results show the system capable of extending thermoelectric operation several minutes through the use of thermal energy storage techniques within the effective conductivity ranges

  16. Thermal performance of a buried nuclear waste storage container storing a hybrid mix of PWR and BWR spent fuel rods

    International Nuclear Information System (INIS)

    Johnson, G.L.

    1991-11-01

    Lawrence Livermore National Laboratory will design, model, and test nuclear waste packages for use at the Nevada Nuclear Waste Storage Repository at Yucca Mountain, Nevada. On such package would store tightly packed spent fuel rods from both pressurized and boiling water reactors. The storage container provides the primary containment of the nuclear waste and the spent fuel rod cladding provides secondary containment. A series of transient conduction and radiation heat transfer analyses was run to determine for the first 1000 yr of storage if the temperature of the tuff at the borehole wall ever falls below 97 degrees C and whether the cladding of the stored spent fuel ever exceeds 350 degrees C. Limiting the borehole to temperatures of 97 degrees C or greater helps minimize corrosion by assuring that no condensed water collects on the container. The 350 degrees C cladding limit minimizes the possibility of creep- related failure in the spent fuel rod cladding. For a series of packages stored in a 8 x 30 m borehole grid where each package contains 10-yr-old spent fuel rods generating 4.74 kW or more, the borehole wall stays above 97 degrees C for the full 10000-yr analysis period. For the 4.74-kW load, the peak cladding temperature rises to just below the 350 degrees C limit about 4 years after emplacement. If the packages are stored using the spacing specified in the Site Characterization Plan (15 ft x 126 ft), a maximum of 4.1 kW per container may be stored. If the 0.05-m-thick void between the container and the borehole wall is filled with loosely packed bentonite, the peak cladding temperature rises more than 40 degrees C above the allowed cladding limit. In all cases the dominant heat transfer mode between container components is thermal radiation

  17. Energy and exergy analyses of an ice-on-coil thermal energy storage system

    International Nuclear Information System (INIS)

    Ezan, Mehmet Akif; Erek, Aytunç; Dincer, Ibrahim

    2011-01-01

    In this study, energy and exergy analyses are carried out for the charging period of an ice-on-coil thermal energy storage system. The present model is developed using a thermal resistance network technique. First, the time-dependent variations of the predicted total stored energy, mass of ice, and outlet temperature of the heat transfer fluid from a storage tank are compared with the experimental data. Afterward, performance of an ice-on-coil type latent heat thermal energy storage system is investigated for several working and design parameters. The results of a comparative study are presented in terms of the variations of the heat transfer rate, total stored energy, dimensionless energetic/exergetic effectiveness and energy/exergy efficiency. The results indicate that working and design parameters of the ice-on-coil thermal storage tank should be determined by considering both energetic and exergetic behavior of the system. For the current parameters, storage capacity and energy efficiency of the system increases with decreasing the inlet temperature of the heat transfer fluid and increasing the length of the tube. Besides, the exergy efficiency increases with increasing the inlet temperature of the heat transfer fluid and increasing the length of the tube. -- Highlights: ► A comprehensive study on energy and exergy analyses of an ice-on-coil TES system. ► Determination of irreversibilities and their potential sources. ► Evaluation of both energy and exergy efficiencies and their comparisons.

  18. Design and installation manual for thermal energy storage

    Energy Technology Data Exchange (ETDEWEB)

    Cole, R L; Nield, K J; Rohde, R R; Wolosewicz, R M

    1980-01-01

    The purpose of this manual is to provide information on the design and installation of thermal energy storage in active solar systems. It is intended for contractors, installers, solar system designers, engineers, architects, and manufacturers who intend to enter the solar energy business. The reader should have general knowledge of how solar heating and cooling systems operate and knowledge of construction methods and building codes. Knowledge of solar analysis methods such as f-Chart, SOLCOST, DOE-1, or TRNSYS would be helpful. The information contained in the manual includes sizing storage, choosing a location for the storage device, and insulation requirements. Both air-based and liquid-based systems are covered with topics on designing rock beds, tank types, pump and fan selection, installation, costs, and operation and maintenance. Topics relevant to latent heat storage include properties of phase-change materials, sizing the storage unit, insulating the storage unit, available systems, and cost. Topics relevant to heating domestic water include safety, single- and dual-tank systems, domestic water heating with air- and liquid-based space heating systems, and stand alone domestics hot water systems. Several appendices present common problems with storage systems and their solutions, heat transfer fluid properties, economic insulation thickness, heat exchanger sizing, and sample specifications for heat exchangers, wooden rock bins, steel tanks, concrete tanks, and fiberglass-reinforced plastic tanks.

  19. Peak load shifting control using different cold thermal energy storage facilities in commercial buildings: A review

    International Nuclear Information System (INIS)

    Sun, Yongjun; Wang, Shengwei; Xiao, Fu; Gao, Diance

    2013-01-01

    Highlights: • Little study reviews the load shifting control using different facilities. • This study reviews load shifting control using building thermal mass. • This study reviews load shifting control using thermal energy storage systems. • This study reviews load shifting control using phase change material. • Efforts for developing more applicable load shifting control are addressed. - Abstract: For decades, load shifting control, one of most effective peak demand management methods, has attracted increasing attentions from both researchers and engineers. Different load shifting control strategies have been developed when diverse cold thermal energy storage facilities are used in commercial buildings. The facilities include building thermal mass (BTM), thermal energy storage system (TES) and phase change material (PCM). Little study has systematically reviewed these load shifting control strategies and therefore this study presents a comprehensive review of peak load shifting control strategies using these thermal energy storage facilities in commercial buildings. The research and applications of the load shifting control strategies are presented and discussed. The further efforts needed for developing more applicable load shifting control strategies using the facilities are also addressed

  20. Development and prototype testing of MgCl 2 /graphite foam latent heat thermal energy storage system

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Dileep; Yu, Wenhua; Zhao, Weihuan; Kim, Taeil; France, David M.; Smith, Roger K.

    2018-01-01

    Composites of graphite foam infiltrated with a magnesium chloride phase-change material have been developed as high-temperature thermal energy storage media for concentrated solar power applications. This storage medium provides a high thermal energy storage density, a narrow operating temperature range, and excellent heat transfer characteristics. In this study, experimental investigations were conducted on laboratory-scale prototypes with magnesium chloride/graphite foam composite as the latent heat thermal energy storage system. Prototypes were designed and built to monitor the melt front movement during the charging/discharging tests. A test loop was built to ensure the charging/discharging of the prototypes at temperatures > 700 degrees C. Repeated thermal cycling experiments were carried out on the fabricated prototypes, and the experimental temperature profiles were compared to the predicted results from numerical simulations using COMSOL Multiphysics software. Experimental results were found to be in good agreement with the simulations to validate the thermal models.

  1. Thermal enhancement of charge and discharge cycles for adsorbed natural gas storage

    KAUST Repository

    Rahman, Kazi Afzalur

    2011-07-01

    The usage of adsorbed natural gas (ANG) storage is hindered by the thermal management during the adsorption and desorption processes. An effective thermal enhancement is thus essential for the development of the ANG technology and the motivation for this study is the investigation of a gas storage system with internal thermal control. We employed a fin-tube type heat exchanger that is placed in a pressurized cylinder. A distributed-parameter model is used for the theoretical modeling and simulations are conducted at assorted charging and discharging conditions. These studies included the transient thermal behaviours of the elements within the ANG-charged cylinder and parameters such as pressure and temperature profiles of adsorbent have been obtained during charge and discharge cycles, and results are compared with a conventional compressed methane vessel. © 2011 Elsevier Ltd. All rights reserved.

  2. Protection by high velocity thermal spraying coatings on thick walled permanent and interim store components for the diminution of repairs, corrosion and costs 'SHARK'. Overview at the end of the project

    International Nuclear Information System (INIS)

    Behrens, Sabine; Hassel, Thomas; Bach, Friedrich-Wilhelm

    2012-01-01

    The corrosion protection of the internal space of thick-walled interim and permanent storage facility components, such as Castor copyright containers, are ensured nowadays by a galvanic nickel layer. The method has proved itself and protects the base material of the containers at the underwater loading in the Nuclear power station from a corrosive attack. Although, the galvanic nickel plating is a relatively time consuming method, it lasts for several days for each container, and is with a layer thickness of 1,000 μm also expensive. To develop an alternative, faster and more economical method, a BMBF research project named - 'SHARK - protection by high velocity thermal spraying layers on thick-walled permanent and interim store components for the diminution of repairs, corrosion and costs' in cooperation between Siempelkamp Nukleartechnik GmbH and the Institute of Materials Science of the Leibniz University of Hanover was established to investigate the suitability of the high velocity oxy fuel spraying technology (HVOF) for the corrosion protective coating of thickwalled interim and permanent storage facility components. Since the permanent storage depot components are manufactured from cast iron with globular graphite, this material was exclusively used as a base material in this project. The evaluation of the economical features of the application of different nickel base spraying materials on cast iron substratum was in focus, as well as the scientific characterization of the coating systems with regard to the corrosion protective properties. Furthermore, the feasibility of the transfer of the laboratory results on a large industrial setup as well as a general suitability of the coating process for a required repair procedure was to be investigated. The preliminary examination program identified chromium containing spraying materials as successful. Results of the preliminary examination program have been used for investigations with the CASOIK demonstration

  3. Molecular solar thermal energy storage in photoswitch oligomers increases energy densities and storage times.

    Science.gov (United States)

    Mansø, Mads; Petersen, Anne Ugleholdt; Wang, Zhihang; Erhart, Paul; Nielsen, Mogens Brøndsted; Moth-Poulsen, Kasper

    2018-05-16

    Molecular photoswitches can be used for solar thermal energy storage by photoisomerization into high-energy, meta-stable isomers; we present a molecular design strategy leading to photoswitches with high energy densities and long storage times. High measured energy densities of up to 559 kJ kg -1 (155 Wh kg -1 ), long storage lifetimes up to 48.5 days, and high quantum yields of conversion of up to 94% per subunit are demonstrated in norbornadiene/quadricyclane (NBD/QC) photo-/thermoswitch couples incorporated into dimeric and trimeric structures. By changing the linker unit between the NBD units, we can at the same time fine-tune light-harvesting and energy densities of the dimers and trimers so that they exceed those of their monomeric analogs. These new oligomers thereby meet several of the criteria to be met for an optimum molecule to ultimately enter actual devices being able to undergo closed cycles of solar light-harvesting, energy storage, and heat release.

  4. Combination of aquifer thermal energy storage and enhanced bioremediation

    NARCIS (Netherlands)

    Ni, Zhuobiao; Gaans, van Pauline; Smit, Martijn; Rijnaarts, Huub; Grotenhuis, Tim

    2016-01-01

    To meet the demand for sustainable energy, aquifer thermal energy storage (ATES) is widely used in the subsurface in urban areas. However, contamination of groundwater, especially with chlorinated volatile organic compounds (CVOCs), is often being encountered. This is commonly seen as an

  5. Non-linear thermal optimization and design improvement of a new internal light concrete multi-holed brick walls by FEM

    International Nuclear Information System (INIS)

    Coz Diaz, J.J. del; Garcia Nieto, P.J.; Suarez Sierra, J.L.; Penuelas Sanchez, I.

    2008-01-01

    The aim of this work was carried out the optimization and numerical study by the finite element method of internal hollow bricks walls in order to determine the best candidate brick from the thermal point of view. With respect to the energy saving for housing and industrial structures, there is also a great interest in light building materials with good physical and thermal behaviors, which fulfills all thermal requirements of the new CTE Spanish rule. The conduction, convection and radiation phenomena are taking into account in this study for six different types of bricks varying the material conductivity obtained from five experimental tests. Mathematically, the non-linearity is due to the radiation boundary condition inside the inner recesses of the bricks. Optimization of the walls is carried out from the finite element analysis of the new hollow brick geometries by means of the average mass overall thermal efficiency and the equivalent thermal conductivity. Based on the previous thermal analysis and the optimization procedure described in this paper, the best candidate was chosen and then a full 1.22 x 0.23 x 1.05 m wall made of these bricks was simulated for fifteen different compositions. The main variables influencing the thermal conductivity of these walls are illustrated for different concrete and mortar properties and the temperature distribution is shown for some typical configurations. Finally, in order to select the appropriate wall satisfying the CTE requirements, detailed instructions are given and conclusions of this work are exposed

  6. Non-linear thermal optimization and design improvement of a new internal light concrete multi-holed brick walls by FEM

    Energy Technology Data Exchange (ETDEWEB)

    Coz Diaz, J.J. del [Edificio Departamental Viesques, No. 7-33204 Gijon, Asturias (Spain)], E-mail: juanjo@constru.uniovi.es; Garcia Nieto, P.J. [Departamento de Matematicas, Facultad de Ciencias, C/Calvo Sotelo s/n, 33007 Oviedo, Asturias (Spain); Suarez Sierra, J.L.; Penuelas Sanchez, I. [Edificio Departamental Viesques, No. 7-33204 Gijon, Asturias (Spain)

    2008-06-15

    The aim of this work was carried out the optimization and numerical study by the finite element method of internal hollow bricks walls in order to determine the best candidate brick from the thermal point of view. With respect to the energy saving for housing and industrial structures, there is also a great interest in light building materials with good physical and thermal behaviors, which fulfills all thermal requirements of the new CTE Spanish rule. The conduction, convection and radiation phenomena are taking into account in this study for six different types of bricks varying the material conductivity obtained from five experimental tests. Mathematically, the non-linearity is due to the radiation boundary condition inside the inner recesses of the bricks. Optimization of the walls is carried out from the finite element analysis of the new hollow brick geometries by means of the average mass overall thermal efficiency and the equivalent thermal conductivity. Based on the previous thermal analysis and the optimization procedure described in this paper, the best candidate was chosen and then a full 1.22 x 0.23 x 1.05 m wall made of these bricks was simulated for fifteen different compositions. The main variables influencing the thermal conductivity of these walls are illustrated for different concrete and mortar properties and the temperature distribution is shown for some typical configurations. Finally, in order to select the appropriate wall satisfying the CTE requirements, detailed instructions are given and conclusions of this work are exposed.

  7. Thermal hydraulic analyses of two fusion reactor first wall/blanket concepts

    International Nuclear Information System (INIS)

    Misra, B.; Maroni, V.A.

    1977-01-01

    A comparative study has been made of the thermal hydraulic performance of two liquid lithium blanket concepts for tokamak-type reactors. In one concept lithium is circulated through 60-cm deep cylindrical modules oriented so that the module axis is parallel to the reactor minor radius. In the other concept helium carrying channels oriented parallel to the first wall are used to cool a 60-cm thick stagnant lithium blanket. Paralleling studies were carried out wherein the thermal and structural properties of the construction materials were based on those projected for either solution-annealed 316-stainless steel or vanadium-base alloys. The effects of limitations on allowable peak structural temperature, material strength, thermal stress, coolant inlet temperature, and pumping power/thermal power ratio were evaluated. Consequences to thermal hydraulic performance resulting from the presence of or absence of a divertor were also investigated

  8. Thermal hydraulic analyses of two fusion reactor first wall/blanket concepts

    International Nuclear Information System (INIS)

    Misra, B.; Maroni, V.A.

    1978-01-01

    A comparative study has been made of the thermal hydraulic performance of two liquid lithium blanket concepts for tokamak-type reactors. In one concept lithium is circulated through 60-cm deep cylindrical modules oriented so that the module axis is parallel to the reactor minor radius. In the other concept helium carrying channels oriented parallel to the first wall are used to cool a 60-cm thick stagnant lithium blanket. Paralleling studies were carried out wherein the thermal and structural properties of the construction materials were based on those projected for either solution-annealed 316-stainless steel or vanadium-base alloys. The effects of limitations on allowable peak structural temperature, material strength, thermal stress, coolant inlet temperature, and pumping power/thermal power ratio were evaluated. Consequences to thermal hydraulic performance resulting from the presence of or absence of a divertor were also investigated

  9. Minimization of thermal insulation thickness taking into account condensation on external walls

    OpenAIRE

    Nurettin Yamankaradeniz

    2015-01-01

    Condensation occurs in the inner layers of construction materials at whatever point the partial pressure of water vapor diffuses and reaches its saturation pressure. Condensation, also called sweating, damages materials, reduces thermal resistance, and by increasing the total heat transfer coefficient, results in unwanted events such as increased heat loss. This study applied minimization of thermal insulation thickness with consideration given to condensation in the external walls. The calcu...

  10. Phase change material thermal storage for biofuel preheating in micro trigeneration application: A numerical study

    International Nuclear Information System (INIS)

    Wu, Dawei; Chen, Junlong; Roskilly, Anthony P.

    2015-01-01

    Highlights: • Engine exhaust heat driven phase change material thermal storage. • Fuel preheating for direct use of straight plant oil on diesel engine. • CFD aided design of the phase change material thermal storage. • Melting and solidification model considering natural convection. - Abstract: A biofuel micro trigeneration prototype has been developed to utilise local energy crop oils as fuel in rural areas and developing countries. Straight plant oils (SPOs) only leave behind very little carbon footprint during its simply production process compared to commercial biodiesels in refineries, but the high viscosity of SPOs causes difficulties at engine cold starts, which further results in poor fuel atomisation, compromised engine performance and fast engine deterioration. In this study, a phase change material (PCM) thermal storage is designed to recover and store engine exhaust heat to preheat SPOs at cold starts. High temperature commercial paraffin is selected as the PCM to meet the optimal preheating temperature range of 70–90 °C, in terms of the SPO property study. A numerical model of the PCM thermal storage is developed and validated by references. The PCM melting and solidification processes with the consideration of natural convection in liquid zone are simulated in ANSYS-FLUENT to verify the feasibility of the PCM thermal storage as a part of the self-contained biofuel micro trigeneration prototype

  11. Combination of aquifer thermal energy storage and enhanced bioremediation

    NARCIS (Netherlands)

    Ni, Zhuobiao; Gaans, van Pauline; Rijnaarts, Huub; Grotenhuis, Tim

    2018-01-01

    Interest in the combination concept of aquifer thermal energy storage (ATES) and enhanced bioremediation has recently risen due to the demand for both renewable energy technology and sustainable groundwater management in urban areas. However, the impact of enhanced bioremediation on ATES is not

  12. Method of making improved gas storage carbon with enhanced thermal conductivity

    Science.gov (United States)

    Burchell, Timothy D [Oak Ridge, TN; Rogers, Michael R [Knoxville, TN

    2002-11-05

    A method of making an adsorbent carbon fiber based monolith having improved methane gas storage capabilities is disclosed. Additionally, the monolithic nature of the storage carbon allows it to exhibit greater thermal conductivity than conventional granular activated carbon or powdered activated carbon storage beds. The storage of methane gas is achieved through the process of physical adsorption in the micropores that are developed in the structure of the adsorbent monolith. The disclosed monolith is capable of storing greater than 150 V/V of methane [i.e., >150 STP (101.325 KPa, 298K) volumes of methane per unit volume of storage vessel internal volume] at a pressure of 3.5 MPa (500 psi).

  13. Optimal Sizing of Energy Storage for Community Microgrids Considering Building Thermal Dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Guodong [ORNL; Li, Zhi [ORNL; Starke, Michael R. [ORNL; Ollis, Ben [ORNL; Tomsovic, Kevin [University of Tennessee, Knoxville (UTK)

    2017-07-01

    This paper proposes an optimization model for the optimal sizing of energy storage in community microgrids considering the building thermal dynamics and customer comfort preference. The proposed model minimizes the annualized cost of the community microgrid, including energy storage investment, purchased energy cost, demand charge, energy storage degradation cost, voluntary load shedding cost and the cost associated with customer discomfort due to room temperature deviation. The decision variables are the power and energy capacity of invested energy storage. In particular, we assume the heating, ventilation and air-conditioning (HVAC) systems can be scheduled intelligently by the microgrid central controller while maintaining the indoor temperature in the comfort range set by customers. For this purpose, the detailed thermal dynamic characteristics of buildings have been integrated into the optimization model. Numerical simulation shows significant cost reduction by the proposed model. The impacts of various costs on the optimal solution are investigated by sensitivity analysis.

  14. SLAC divertor channel entrance thermal stress analysis

    International Nuclear Information System (INIS)

    Johnson, G.L.; Stein, W.; Lu, S.C.; Riddle, R.A.

    1985-01-01

    X-ray beams emerging from the new SLAC electron-positron storage ring (PEP) impinge on the entrance to tangential divertor channels causing highly localized heating in the channel structure. Analyses were completed to determine the temperatures and thermally-induced stresses due to this heating. These parts are cooled with water flowing axially over them at 30 0 C. The current design and operating conditions should result in the entrance to the new divertor channel operating at a peak temperature of 123 0 C with a peak thermal stress at 91% of yield. Any micro-cracks that form due to thermally-induced stresses should not propagate to the coolant wall nor form a path for the coolant to leak into the storage ring vacuum. 34 figs., 4 tabs

  15. Commercialization of aquifer thermal energy storage technology

    Energy Technology Data Exchange (ETDEWEB)

    Hattrup, M.P.; Weijo, R.O.

    1989-09-01

    Pacific Northwest Laboratory (PNL) conducted this study for the US Department of Energy's (DOE) Office of Energy Storage and Distribution. The purpose of the study was to develop and screen a list of potential entry market applications for aquifer thermal energy storage (ATES). Several initial screening criteria were used to identify promising ATES applications. These include the existence of an energy availability/usage mismatch, the existence of many similar applications or commercial sites, the ability to utilize proven technology, the type of location, market characteristics, the size of and access to capital investment, and the number of decision makers involved. The in-depth analysis identified several additional screening criteria to consider in the selection of an entry market application. This analysis revealed that the best initial applications for ATES are those where reliability is acceptable, and relatively high temperatures are allowable. Although chill storage was the primary focus of this study, applications that are good candidates for heat ATES were also of special interest. 11 refs., 3 tabs.

  16. Low-Temperature Thermal Energy Storage Program. Annual progress report, October 1977--September 1978

    Energy Technology Data Exchange (ETDEWEB)

    Brunton, G.D.; Eissenberg, D.M.; Kedl, R.J.

    1979-05-01

    The Low-Temperature Thermal Energy Storage (LTTES) Program is part of a national effort to develop means for reducing United States dependence on oil and natural gas as primary energy sources. To this end, LTTES addresses the development of advanced sensible and latent heat storage technologies that permit substitution by solar or off-peak electrical energies or permit conservation by recovery and reuse of waste heat. Emphasis is on applying these technologies to heating and cooling of buildings. As the LTTES program continued to mature, a number of technologies were identified for development emphasis, including (1) seasonal storage of hot and cold water from waste or natural sources in aquifers, (2) short-term or daily storage of heat or coolness from solar or off-peak electrical sources in phase-change materials, and (3) recovery and reuse of rejected industrial heat through thermal storage. These areas have been further divided into three major and four minor activities; significant accomplishments are reported for each.

  17. Templated assembly of photoswitches significantly increases the energy-storage capacity of solar thermal fuels.

    Science.gov (United States)

    Kucharski, Timothy J; Ferralis, Nicola; Kolpak, Alexie M; Zheng, Jennie O; Nocera, Daniel G; Grossman, Jeffrey C

    2014-05-01

    Large-scale utilization of solar-energy resources will require considerable advances in energy-storage technologies to meet ever-increasing global energy demands. Other than liquid fuels, existing energy-storage materials do not provide the requisite combination of high energy density, high stability, easy handling, transportability and low cost. New hybrid solar thermal fuels, composed of photoswitchable molecules on rigid, low-mass nanostructures, transcend the physical limitations of molecular solar thermal fuels by introducing local sterically constrained environments in which interactions between chromophores can be tuned. We demonstrate this principle of a hybrid solar thermal fuel using azobenzene-functionalized carbon nanotubes. We show that, on composite bundling, the amount of energy stored per azobenzene more than doubles from 58 to 120 kJ mol(-1), and the material also maintains robust cyclability and stability. Our results demonstrate that solar thermal fuels composed of molecule-nanostructure hybrids can exhibit significantly enhanced energy-storage capabilities through the generation of template-enforced steric strain.

  18. Effect of carbon nanospheres on shape stabilization and thermal behavior of phase change materials for thermal energy storage

    International Nuclear Information System (INIS)

    Mehrali, Mohammad; Tahan Latibari, Sara; Mehrali, Mehdi; Mahlia, Teuku Meurah Indra; Cornelis Metselaar, Hendrik Simon

    2014-01-01

    Highlights: • Introducing novel form-stable PCM of stearic acid (SA)/carbon nanospheres (CNSs). • The highest stabilized SA content is 83 wt% in the SA/CNS composites. • Increasing thermal conductivity of composite phase change material with high amount of latent heat. - Abstract: Stearic acid (SA) is one of the main phase change materials (PCMs) for medium temperature thermal energy storage systems. In order to stabilize the shape and enhance the thermal conductivity of SA, the effects of adding carbon nanospheres (CNSs) as a carbon nanofiller were examined experimentally. The maximum mass fraction of SA retained in CNSs was found as 80 wt% without the leakage of SA in a melted state, even when it was heated over the melting point of SA. The dropping point test shows that there was clearly no liquid leakage through the phase change process at the operating temperature range of the composite PCMs. The thermal stability and thermal properties of composite PCMs were investigated with a thermogravimetric analyzer (TGA) and differential scanning calorimeter (DSC), respectively. The thermal conductivity of the SA/CNS composite was determined by the laser flash method. The thermal conductivity at 35 °C increased about 105% for the highest loading of CNS (50 wt%). The thermal cycling test proved that form-stable composite PCMs had good thermal reliability and chemical durability after 1000 cycles of melting and freezing, which is advantageous for latent heat thermal energy storage (LHTES)

  19. Thermal test and analysis of a spent fuel storage cask

    International Nuclear Information System (INIS)

    Yamakawa, H.; Gomi, Y.; Ozaki, S.; Kosaki, A.

    1993-01-01

    A thermal test simulated with full-scale cask model for the normal storage was performed to verify the storage skill of the spent fuels of the cask. The maximum temperature at each point in the test was lower than the allowable temperature. The integrity of the cask was maintained. It was observed that the safety of containment system was also kept according to the check of the seal before and after the thermal test. Therefore it was shown that using the present skill, it is possible to store spent fuels in the dry-type cask safely. Moreover, because of the good agreement between analysis and experimental results, it was shown that the analysis model was successfully established to estimate the temperature distribution of the fuel cladding and the seal portion. (J.P.N.)

  20. Development of space heating and domestic hot water systems with compact thermal energy storage. Compact thermal energy storage: Material development for System Integration

    NARCIS (Netherlands)

    Davidson, J.H.; Quinnell, J.; Burch, J.; Zondag, H.A.; Boer, R. de; Finck, C.J.; Cuypers, R.; Cabeza, L.F.; Heinz, A.; Jahnig, D.; Furbo, S.; Bertsch, F.

    2013-01-01

    Long-term, compact thermal energy storage (TES) is essential to the development of cost-effective solar and passive building-integrated space heating systems and may enhance the annual technical and economic performance of solar domestic hot water (DHW) systems. Systems should provide high energy

  1. Thermal-hydraulic assessment of concrete storage cubicle with horizontal 3013 canisters

    Energy Technology Data Exchange (ETDEWEB)

    HEARD, F.J.

    1999-04-08

    The FIDAP computer code was used to perform a series of analyses to assess the thermal-hydraulic performance characteristics of the concrete plutonium storage cubicles, as modified for the horizontal placement of 3013 canisters. Four separate models were developed ranging from a full height model of the storage cubicle to a very detailed standalone model of a horizontal 3013 canister.

  2. Thermal-hydraulic assessment of concrete storage cubicle with horizontal 3013 canisters

    International Nuclear Information System (INIS)

    Heard, F.J.

    1999-01-01

    The FIDAP computer code was used to perform a series of analyses to assess the thermal-hydraulic performance characteristics of the concrete plutonium storage cubicles, as modified for the horizontal placement of 3013 canisters. Four separate models were developed ranging from a full height model of the storage cubicle to a very detailed standalone model of a horizontal 3013 canister

  3. Selection of high temperature thermal energy storage materials for advanced solar dynamic space power systems

    Science.gov (United States)

    Lacy, Dovie E.; Coles-Hamilton, Carolyn; Juhasz, Albert

    1987-01-01

    Under the direction of NASA's Office of Aeronautics and Technology (OAST), the NASA Lewis Research Center has initiated an in-house thermal energy storage program to identify combinations of phase change thermal energy storage media for use with a Brayton and Stirling Advanced Solar Dynamic (ASD) space power system operating between 1070 and 1400 K. A study has been initiated to determine suitable combinations of thermal energy storage (TES) phase change materials (PCM) that result in the smallest and lightest weight ASD power system possible. To date the heats of fusion of several fluoride salt mixtures with melting points greater than 1025 K have been verified experimentally. The study has indicated that these salt systems produce large ASD systems because of their inherent low thermal conductivity and low density. It is desirable to have PCMs with high densities and high thermal conductivities. Therefore, alternate phase change materials based on metallic alloy systems are also being considered as possible TES candidates for future ASD space power systems.

  4. Modeling of District Heating Networks for the Purpose of Operational Optimization with Thermal Energy Storage

    Science.gov (United States)

    Leśko, Michał; Bujalski, Wojciech

    2017-12-01

    The aim of this document is to present the topic of modeling district heating systems in order to enable optimization of their operation, with special focus on thermal energy storage in the pipelines. Two mathematical models for simulation of transient behavior of district heating networks have been described, and their results have been compared in a case study. The operational optimization in a DH system, especially if this system is supplied from a combined heat and power plant, is a difficult and complicated task. Finding a global financial optimum requires considering long periods of time and including thermal energy storage possibilities into consideration. One of the most interesting options for thermal energy storage is utilization of thermal inertia of the network itself. This approach requires no additional investment, while providing significant possibilities for heat load shifting. It is not feasible to use full topological models of the networks, comprising thousands of substations and network sections, for the purpose of operational optimization with thermal energy storage, because such models require long calculation times. In order to optimize planned thermal energy storage actions, it is necessary to model the transient behavior of the network in a very simple way - allowing for fast and reliable calculations. Two approaches to building such models have been presented. Both have been tested by comparing the results of simulation of the behavior of the same network. The characteristic features, advantages and disadvantages of both kinds of models have been identified. The results can prove useful for district heating system operators in the near future.

  5. Thermal conductivity of a film of single walled carbon nanotubes measured with infrared thermal imager

    Science.gov (United States)

    Feng, Ya; Inoue, Taiki; Xiang, Rong; Chiashi, Shohei; Maruyama, Shigeo

    Heat dissipation has restricted the modern miniaturization trend with the development of electronic devices. Theoretically proven to be with high axial thermal conductivity, single walled carbon nanotubes (SWNT) have long been expected to cool down the nanoscale world. Even though the tube-tube contact resistance limits the capability of heat transfer of the bulk film, the high intrinsic thermal conductivity of SWNT still glorify the application of films of SWNT network as a thermal interface material. In this work, we proposed a new method to straightly measure the thermal conductivity of SWNT film. We bridged two cantilevered Si thin plate with SWNT film, and kept a steady state heat flow in between. With the infrared camera to record the temperature distribution, the Si plates with known thermal conductivity can work as a reference to calculate the heat flux going through the SWNT film. Further, the thermal conductivity of the SWNT film can be obtained through Fourier's law after deducting the effect of thermal radiation. The sizes of the structure, the heating temperature, the vacuum degree and other crucial impact factors are carefully considered and analyzed. The author Y. F. was supported through the Advanced Integration Science Innovation Education and Research Consortium Program by the Ministry of Education, Culture, Sport, Science and Technology.

  6. Current status of ground source heat pumps and underground thermal energy storage in Europe

    Energy Technology Data Exchange (ETDEWEB)

    Sanner, B. [Justus Liebig University, Giessen (Germany). Institute of Applied Geosciences; Karytsas, C.; Mendrinos, D. [Center for Renewable Energy Sources, Pikermi (Greece); Rybach, L. [Geowatt AG, Zurich (Switzerland)

    2003-12-01

    Geothermal Heat Pumps, or Ground Coupled Heat Pumps (GCHP), are systems combining a heat pump with a ground heat exchanger (closed loop systems), or fed by ground water from a well (open loop systems). They use the earth as a heat source when operating in heating mode, with a fluid (usually water or a water-antifreeze mixture) as the medium that transfers the heat from the earth to the evaporator of the heat pump, thus utilising geothermal energy. In cooling mode, they use the earth as a heat sink. With Borehole Heat Exchangers (BHE), geothermal heat pumps can offer both heating and cooling at virtually any location, with great flexibility to meet any demands. More than 20 years of R and D focusing on BUE in Europe has resulted in a well-established concept of sustainability for this technology, as well as sound design and installation criteria. Recent developments are the Thermal Response Test, which allows in-situ-determination of ground thermal properties for design purposes, and thermally enhanced grouting materials to reduce borehole thermal resistance. For cooling purposes, but also for the storage of solar or waste heat, the concept of underground thermal energy storage (UTES) could prove successful. Systems can be either open (aquifer storage) or can use BHE (borehole storage). Whereas cold storage is already established on the market, heat storage, and, in particular, high temperature heat storage (> 50{sup o}C) is still in the demonstration phase. Despite the fact that geothermal heat pumps have been in use for over 50 years now (the first were in the USA), market penetration of this technology is still in its infancy, with fossil fuels dominating the space heating market and air-to-air heat pumps that of space cooling. In Germany, Switzerland, Austria, Sweden, Denmark, Norway, France and the USA, large numbers of geothermal heat pumps are already operational, and installation guidelines, quality control and contractor certification are now major issues

  7. Assessing the sustainable application of Aquifer Thermal Energy Storage

    NARCIS (Netherlands)

    Jaxa-Rozen, M.; Bloemendal, J.M.; Rostampour Samarin, Vahab; Kwakkel, J.H.

    2016-01-01

    Aquifer Thermal Energy Storage (ATES) can yield significant reductions in the energy use and greenhouse gas (GHG) emissions of larger buildings, and the use of these systems has been rapidly growing in Europe – especially in the Netherlands, where over 3000 systems are currently active in urban

  8. From Molecular Electronics to Solar Thermal Energy Storage

    DEFF Research Database (Denmark)

    Olsen, Stine Tetzschner

    The Sun's signicant resource potential provides a solution for the world's increasing energy demand in a sustainable and responsible manner. However, the intrinsic property of the on-o cycles of the solar irradiation, i.e. daynight, sunny-cloudy, and summer-winter, constitutes a signicant challenge...... for the utilization of solar energy. An eective technology for storing the solar energy is required. This thesis focuses on solar thermal energy storage in molecules, since it oers a very compact and eective storage method. The rst chapter after the introduction of the thesis, chapter two, introduces the fundamental...... properties of the molecule, i.e. the electronic behaviour of the molecule in dierent environments, which is a key property for investigations of solar energy storage. The main focus of the research is on the electron transport in the Coulomb blockade regime. The third chapter goes into the challenge...

  9. Dimethyl terephthalate (DMT) as a candidate phase change material for high temperature thermal energy storage

    Energy Technology Data Exchange (ETDEWEB)

    Kuecuekaltun, Engin [Advansa Sasa Polyester San, A.S., Adana (Turkey); Paksoy, Halime; Bilgin, Ramazan; Yuecebilgic, Guezide [Cukurova Univ., Adana (Turkey). Chemistry Dept.; Evliya, Hunay [Cukurova Univ., Adana (Turkey). Center for Environmental Research

    2010-07-01

    Thermal energy storage at elevated temperatures, particularly in the range of 120-250 C is of interest with a significant potential for industrial applications that use process steam at low or intermediate pressures. At given temperature range there are few studies on thermal energy storage materials and most of them are dedicated to sensible heat. In this study, Dimethyl Terephthalate - DMT (CAS No: 120-61-6) is investigated as a candidate phase change material (PCM) for high temperature thermal energy storage. DMT is a monomer commonly used in Polyethylene terephtalate industry and has reasonable cost and availability. The Differential Scanning Calorimetry (DSC) analysis and heating cooling curves show that DMT melts at 140-146 C within a narrow window. Supercooling that was detected in DSC results was not observed in the cooling curve measurements made with a larger sample. With a latent heat of 193 J/g, DMT is a candidate PCM for high temperature storage. Potential limitations such as, low thermal conductivity and sublimation needs further investigation. (orig.)

  10. Thermal characterization of nitrates and nitrates/expanded graphite mixture phase change materials for solar energy storage

    International Nuclear Information System (INIS)

    Xiao, X.; Zhang, P.; Li, M.

    2013-01-01

    Highlights: • The addition of expanded graphite improved apparent thermal conductivity significantly. • The quadratic parallel model was used to predict the effective thermal conductivity. • The melting/freezing temperatures of mixture PCMs shifted slightly with adding of EG. - Abstract: Solar energy storage has become more attractive in recent years. In particular, latent thermal energy storage (LTES) with large energy storage density and isothermal heat storage/retrieval characteristics is a hot research topic. In the present study, sodium nitrate, potassium nitrate and their mixture were used as the base materials, and expanded graphite (EG) with high thermal conductivity and thermo-chemical stability was used as an additive to enhance the thermal conductivity. EG with various mass fractions was added to the base materials to form mixture phase change materials (PCMs), and the thermal characteristics of the mixtures were studied extensively. The transient hot-wire tests showed that the addition of EG enhanced the apparent thermal conductivity significantly, e.g. the apparent thermal conductivity of the nitrates/10 wt.% EG mixture PCM was increased by about 30–40%. The test results showed good agreement with theoretical calculations of the quadratic parallel model. Tests with differential scanning calorimeter (DSC) revealed that the melting/freezing temperatures of the mixture PCMs shifted slightly, compared with those of pure nitrates

  11. Preparation, characterization and thermal properties of PMMA/n-heptadecane microcapsules as novel solid-liquid microPCM for thermal energy storage

    International Nuclear Information System (INIS)

    Sari, Ahmet; Alkan, Cemil; Karaipekli, Ali

    2010-01-01

    This study is focused on the preparation, characterization and thermal properties of microencapsulated n-heptadecane with polymethylmethacrylate shell. The PMMA/heptadecane microcapsules were synthesized as novel solid-liquid microencapsulated phase change material (microPCMs) by emulsion polymerization method. The chemical and thermal characterization of the microPCMs were investigated using scanning electron microscopy (SEM), differential scanning calorimetry (DSC) and thermogravimetry analysis (TGA). The diameters of microPCMs were found in the narrow range (0.14-0.40 μm) under the stirring speed of 2000 rpm. The spherical surfaces of microPCMs were smooth and compact. The DSC results show that microPCMs have good energy storage capacity. Thermal cycling test showed that the microPCMs have good thermal reliability with respect to the changes in their thermal properties after repeated 5000 thermal cycling. TGA analyses also indicated that the microPCMs degraded in three steps and have good thermal stability. Based on all results, it can be considered that the PMMA/heptadecane microcapsules as novel solid-liquid microPCMs have good energy storage potential.

  12. Evaluation of in-situ thermal energy storage for lunar based solar dynamic systems

    Science.gov (United States)

    Crane, Roger A.

    1991-01-01

    A practical lunar based thermal energy storage system, based on locally available materials, could significantly reduce transportation requirements and associated costs of a continuous, solar derived power system. The concept reported here is based on a unique, in-situ approach to thermal energy storage. The proposed design is examined to assess the problems of start-up and the requirements for attainment of stable operation. The design remains, at this stage, partially conceptional in nature, but certain aspects of the design, bearing directly on feasibility, are examined in some detail. Specifically included is an engineering evaluation of the projected thermal performance of this system. Both steady state and start-up power requirements are evaluated and the associated thermal losses are evaluated as a basis for establishing potential system performance.

  13. Aquifer thermal-energy-storage modeling

    Science.gov (United States)

    Schaetzle, W. J.; Lecroy, J. E.

    1982-09-01

    A model aquifer was constructed to simulate the operation of a full size aquifer. Instrumentation to evaluate the water flow and thermal energy storage was installed in the system. Numerous runs injecting warm water into a preconditioned uniform aquifer were made. Energy recoveries were evaluated and agree with comparisons of other limited available data. The model aquifer is simulated in a swimming pool, 18 ft by 4 ft, which was filled with sand. Temperature probes were installed in the system. A 2 ft thick aquifer is confined by two layers of polyethylene. Both the aquifer and overburden are sand. Four well configurations are available. The system description and original tests, including energy recovery, are described.

  14. Thermal Storage Systems Assessment for Energy Sustainability in Housing Units

    Directory of Open Access Journals (Sweden)

    Tania I. Lagunes Vega

    2016-04-01

    Full Text Available In order to achieve greater enhancements in energy sustainability for housing, the function and efficiency of two different passive cooling systems were studied: encapsulated water in recycled bottles of Polyethylene terephthalate (PET and polystyrene plates, in comparison with standard concrete slab systems, which are customarily used in housing. Experiments were placed over a tile surface, in which temperature changes were monitored for a period of 20 days from 08:00 to 20:00. The efficiency of passive thermal storage systems was endorsed through statistical analysis using the “SPSS” software. This resulted in a 17% energy saving, thus promoting energy sustainability in housing units, which reduces the use of electrical appliances required to stabilize conditions to achieve optimum thermal comfort for the human body inside a house, therefore, reducing electrical power consumption, CO2 emissions to the atmosphere and generating savings. Due to the complexity of a system with temperature changes, a fractal analysis was performed for each experimental system, using the “Benoit” software (V.1.3 with self-compatible tools of rescaled range (R/S and a wavelets method, showing that the thermal fluctuations on the tiles with the thermal storage system adapt to the rescaled range analysis and the regular tiles adapt to the wavelets method.

  15. Non-linear thermal optimization and design improvement of a new internal light concrete multi-holed brick walls by FEM

    Energy Technology Data Exchange (ETDEWEB)

    Del Coz Diaz, J.J.; Suarez Sierra, J.L.; Penuelas Sanchez, I. [Edificio Departamental Viesques, No. 7-33204 Gijon, Asturias (Spain); Garcia Nieto, P.J. [Departamento de Matematicas, Facultad de Ciencias, C/Calvo Sotelo s/n, 33007 Oviedo, Asturias (Spain)

    2008-06-15

    The aim of this work was carried out the optimization and numerical study by the finite element method of internal hollow bricks walls in order to determine the best candidate brick from the thermal point of view. With respect to the energy saving for housing and industrial structures, there is also a great interest in light building materials with good physical and thermal behaviors, which fulfills all thermal requirements of the new CTE Spanish rule. The conduction, convection and radiation phenomena are taking into account in this study for six different types of bricks varying the material conductivity obtained from five experimental tests. Mathematically, the non-linearity is due to the radiation boundary condition inside the inner recesses of the bricks. Optimization of the walls is carried out from the finite element analysis of the new hollow brick geometries by means of the average mass overall thermal efficiency and the equivalent thermal conductivity. Based on the previous thermal analysis and the optimization procedure described in this paper, the best candidate was chosen and then a full 1.22 x 0.23 x 1.05 m wall made of these bricks was simulated for fifteen different compositions. The main variables influencing the thermal conductivity of these walls are illustrated for different concrete and mortar properties and the temperature distribution is shown for some typical configurations. Finally, in order to select the appropriate wall satisfying the CTE requirements, detailed instructions are given and conclusions of this work are exposed. (author)

  16. Flexibility of a combined heat and power system with thermal energy storage for district heating

    International Nuclear Information System (INIS)

    Nuytten, Thomas; Claessens, Bert; Paredis, Kristof; Van Bael, Johan; Six, Daan

    2013-01-01

    Highlights: ► A generic model for flexibility assessment of thermal systems is proposed. ► The model is applied to a combined heat and power system with thermal energy storage. ► A centrally located storage offers more flexibility compared to individual units. ► Increasing the flexibility requires both a more powerful CHP and a larger buffer. - Abstract: The trend towards an increased importance of distributed (renewable) energy resources characterized by intermittent operation redefines the energy landscape. The stochastic nature of the energy systems on the supply side requires increased flexibility at the demand side. We present a model that determines the theoretical maximum of flexibility of a combined heat and power system coupled to a thermal energy storage solution that can be either centralized or decentralized. Conventional central heating, to meet the heat demand at peak moments, is also available. The implications of both storage concepts are evaluated in a reference district. The amount of flexibility created in the district heating system is determined by the approach of the system through delayed or forced operation mode. It is found that the distinction between the implementation of the thermal energy storage as a central unit or as a collection of local units, has a dramatic effect on the amount of available flexibility

  17. Hydration of Magnesium Carbonate in a Thermal Energy Storage Process and Its Heating Application Design

    Directory of Open Access Journals (Sweden)

    Rickard Erlund

    2018-01-01

    Full Text Available First ideas of applications design using magnesium (hydro carbonates mixed with silica gel for day/night and seasonal thermal energy storage are presented. The application implies using solar (or another heat source for heating up the thermal energy storage (dehydration unit during daytime or summertime, of which energy can be discharged (hydration during night-time or winter. The applications can be used in small houses or bigger buildings. Experimental data are presented, determining and analysing kinetics and operating temperatures for the applications. In this paper the focus is on the hydration part of the process, which is the more challenging part, considering conversion and kinetics. Various operating temperatures for both the reactor and the water (storage tank are tested and the favourable temperatures are presented and discussed. Applications both using ground heat for water vapour generation and using water vapour from indoor air are presented. The thermal energy storage system with mixed nesquehonite (NQ and silica gel (SG can use both low (25–50% and high (75% relative humidity (RH air for hydration. The hydration at 40% RH gives a thermal storage capacity of 0.32 MJ/kg while 75% RH gives a capacity of 0.68 MJ/kg.

  18. A cooling concept of spent fuels in lag storage system

    International Nuclear Information System (INIS)

    Park, Jeong-Hwa; Yoo, Jae-Hyung; Park, Hyun-Soo

    1991-01-01

    A cooling concept of spent fuels by natural convection of hot cell air in storage pits was developed. Each storage pit was considered to be located below the hot cell floor and to accommodate only one spent fuel assembly. The aim of this study is to apply an appropriate cooling system to the design of a hot cell where considerable heat-generating fuels are handled. In such operations as disassembling, rod consolidation and packaging of spent fuels, a number of assemblies are on stand-by in the cell before and/or after the operations. A lag storage system can be used for temporary storage of spent fuels in nuclear facilities. Since the air in contact with bare fuel assemblies is potentially contaminated, it must be exhausted through high-efficiency particulate air (HEPA) filters. If the storage pit is completely isolated from the hot cell space, then it will require another separate ventilation system by forced convection of air, which will result in additional cost for the construction. In this work, however, a cooling system was proposed where natural convection of hot cell air itself is achieved by thermo-syphon. The cold air from the hot cell is supplied to the inlet provided at the bottom of each pit through the gap between the concrete pit wall and the interior thermal shield. This thermal shield is needed to form flow channels for cold and heated air, and to prevent the concrete from over-heating. The heated air exhausts from the outlet located at the top of cell wall. No additional HEPA filters are needed in this system because the heated air is routed back to the hot cell due to buoyancy-induced flow. The technical feasibility of this concept was validated by thermal analyses. As the key design constraints are the surface temperature of fuel cladding and the concrete temperature of the storage pit, the thermal analyses were focused on these parameters whether they follow within allowable limits or not. (author)

  19. Review of thermal energy storage technologies based on PCM application in buildings

    DEFF Research Database (Denmark)

    Pomianowski, Michal Zbigniew; Heiselberg, Per; Zhang, Yinping

    2013-01-01

    Thermal energy storage systems (TES), using phase change material (PCM) in buildings, are widely investigated technologies and a fast developing research area. Therefore, there is a need for regular and consistent reviews of the published studies. This review is focused on PCM technologies...... is paid to discussion and identification of proper methods to correctly determine the thermal properties of PCM materials and their composites and as well procedures to determine their energy storage and saving potential. The purpose of the paper is to highlight promising technologies for PCM application...... developed to serve the building industry. Various PCM technologies tailored for building applications are studied with respect to technological potential to improve indoor environment, increase thermal inertia and decrease energy use for building operation. What is more, in this review special attention...

  20. Analysis of regenerative thermal storage geometries for solar gas turbines

    CSIR Research Space (South Africa)

    Klein, P

    2014-08-01

    Full Text Available Ceramic heat regenerators are suited to providing thermal storage for concentrating solar power stations based on a recuperated gas turbine cycle. Randomly packed beds of spheres and saddles; honeycombs and checker bricks were identified...

  1. Energy system investment model incorporating heat pumps with thermal storage in buildings and buffer tanks

    International Nuclear Information System (INIS)

    Hedegaard, Karsten; Balyk, Olexandr

    2013-01-01

    Individual compression heat pumps constitute a potentially valuable resource in supporting wind power integration due to their economic competitiveness and possibilities for flexible operation. When analysing the system benefits of flexible heat pump operation, effects on investments should be taken into account. In this study, we present a model that facilitates analysing individual heat pumps and complementing heat storages in integration with the energy system, while optimising both investments and operation. The model incorporates thermal building dynamics and covers various heat storage options: passive heat storage in the building structure via radiator heating, active heat storage in concrete floors via floor heating, and use of thermal storage tanks for space heating and hot water. It is shown that the model is well qualified for analysing possibilities and system benefits of operating heat pumps flexibly. This includes prioritising heat pump operation for hours with low marginal electricity production costs, and peak load shaving resulting in a reduced need for peak and reserve capacity investments. - Highlights: • Model optimising heat pumps and heat storages in integration with the energy system. • Optimisation of both energy system investments and operation. • Heat storage in building structure and thermal storage tanks included. • Model well qualified for analysing system benefits of flexible heat pump operation. • Covers peak load shaving and operation prioritised for low electricity prices

  2. Numerical modeling of aquifer thermal energy storage system

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jongchan [Korea Institute of Geoscience and Mineral Resources, Geothermal Resources Department, 92 Gwahang-no, Yuseong-gu, Daejeon 305-350 (Korea, Republic of); Kongju National University, Department of Geoenvironmental Sciences, 182 Singwan-dong, Gongju-si, Chungnam 314-701 (Korea, Republic of); Lee, Youngmin [Korea Institute of Geoscience and Mineral Resources, Geothermal Resources Department, 92 Gwahang-no, Yuseong-gu, Daejeon 305-350 (Korea, Republic of); Yoon, Woon Sang; Jeon, Jae Soo [nexGeo Inc., 134-1 Garak 2-dong, Songpa-gu, Seoul 138-807 (Korea, Republic of); Koo, Min-Ho; Keehm, Youngseuk [Kongju National University, Department of Geoenvironmental Sciences, 182 Singwan-dong, Gongju-si, Chungnam 314-701 (Korea, Republic of)

    2010-12-15

    The performance of the ATES (aquifer thermal energy storage) system primarily depends on the thermal interference between warm and cold thermal energy stored in an aquifer. Additionally the thermal interference is mainly affected by the borehole distance, the hydraulic conductivity, and the pumping/injection rate. Thermo-hydraulic modeling was performed to identify the thermal interference by three parameters and to estimate the system performance change by the thermal interference. Modeling results indicate that the thermal interference grows as the borehole distance decreases, as the hydraulic conductivity increases, and as the pumping/injection rate increases. The system performance analysis indicates that if {eta} (the ratio of the length of the thermal front to the distance between two boreholes) is lower than unity, the system performance is not significantly affected, but if {eta} is equal to unity, the system performance falls up to {proportional_to}22%. Long term modeling for a factory in Anseong was conducted to test the applicability of the ATES system. When the pumping/injection rate is 100 m{sup 3}/day, system performances during the summer and winter after 3 years of operation are estimated to be {proportional_to}125 kW and {proportional_to}110 kW, respectively. Therefore, 100 m{sup 3}/day of the pumping/injection rate satisfies the energy requirements ({proportional_to}70 kW) for the factory. (author)

  3. Thermal reliability test of Al-34%Mg-6%Zn alloy as latent heat storage material and corrosion of metal with respect to thermal cycling

    International Nuclear Information System (INIS)

    Sun, J.Q.; Zhang, R.Y.; Liu, Z.P.; Lu, G.H.

    2007-01-01

    The purpose of this study is to determine the thermal reliability and corrosion of the Al-34%Mg-6%Zn alloy as a latent heat energy storage material with respect to various numbers of thermal cycles. The differential scanning calorimeter (DSC) analysis technique was applied to the alloy after 0, 50, 500 and 1000 melting/solidification cycles in order to measure the melting temperatures and the latent heats of fusion of the alloy. The containment materials were stainless steel (SS304L), carbon steel (steel C20) in the corrosion tests. The DSC results indicated that the change in melting temperature for the alloy was in the range of 3.06-5.3 K, and the latent heat of fusion decreased 10.98% after 1000 thermal cycles. The results show that the investigated Al-34%Mg-6%Zn alloy has a good thermal reliability as a latent heat energy storage material with respect to thermal cycling for thermal energy storage applications in the long term in view of the small changes in the latent heat of fusion and melting temperature. Gravimetric analysis as mass loss (mg/cm 2 ), corrosion rate (mg/day) and a microscopic or metallographic investigation were performed for corrosion tests and showed that SS304L may be considered a more suitable alloy than C20 in long term thermal storage applications

  4. Single-Walled Carbon Nanohorns for Energy Applications

    Science.gov (United States)

    Zhang, Zhichao; Han, Shuang; Wang, Chao; Li, Jianping; Xu, Guobao

    2015-01-01

    With the growth of the global economy and population, the demand for energy is increasing sharply. The development of environmentally a benign and reliable energy supply is very important and urgent. Single-walled carbon nanohorns (SWCNHs), which have a horn-shaped tip at the top of single-walled nanotube, have emerged as exceptionally promising nanomaterials due to their unique physical and chemical properties since 1999. The high purity and thermal stability, combined with microporosity and mesoporosity, high surface area, internal pore accessibility, and multiform functionalization make SWCNHs promising candidates in many applications, such as environment restoration, gas storage, catalyst support or catalyst, electrochemical biosensors, drug carrier systems, magnetic resonance analysis and so on. The aim of this review is to provide a comprehensive overview of SWCNHs in energy applications, including energy conversion and storage. The commonly adopted method to access SWCNHs, their structural modifications, and their basic properties are included, and the emphasis is on their application in different devices such as fuel cells, dye-sensitized solar cells, supercapacitors, Li-ion batteries, Li-S batteries, hydrogen storage, biofuel cells and so forth. Finally, a perspective on SWCNHs’ application in energy is presented. PMID:28347092

  5. Single-Walled Carbon Nanohorns for Energy Applications

    Directory of Open Access Journals (Sweden)

    Zhichao Zhang

    2015-10-01

    Full Text Available With the growth of the global economy and population, the demand for energy is increasing sharply. The development of environmentally a benign and reliable energy supply is very important and urgent. Single-walled carbon nanohorns (SWCNHs, which have a horn-shaped tip at the top of single-walled nanotube, have emerged as exceptionally promising nanomaterials due to their unique physical and chemical properties since 1999. The high purity and thermal stability, combined with microporosity and mesoporosity, high surface area, internal pore accessibility, and multiform functionalization make SWCNHs promising candidates in many applications, such as environment restoration, gas storage, catalyst support or catalyst, electrochemical biosensors, drug carrier systems, magnetic resonance analysis and so on. The aim of this review is to provide a comprehensive overview of SWCNHs in energy applications, including energy conversion and storage. The commonly adopted method to access SWCNHs, their structural modifications, and their basic properties are included, and the emphasis is on their application in different devices such as fuel cells, dye-sensitized solar cells, supercapacitors, Li-ion batteries, Li-S batteries, hydrogen storage, biofuel cells and so forth. Finally, a perspective on SWCNHs’ application in energy is presented.

  6. Thermal performance evaluation of a massive brick wall under real weather conditions via the Conduction Transfer function method

    Directory of Open Access Journals (Sweden)

    Emilio Sassine

    2017-12-01

    Full Text Available The reliable estimation of buildings energy needs for cooling and heating is essential for any eventual thermal improvement of the envelope or the HVAC equipment. This paper presents an interesting method to evaluate the thermal performance of a massive wall by using the frequency-domain regression (FDR method to calculate CTF coefficients by means of the Fourier transform. The method is based on the EN ISO 13786 (2007 procedure by using the Taylor expansion for the elements of the heat matrix. Numerical results were validated through an experimental heating box with stochastic boundary conditions on one side of the wall representing real weather conditions and constant temperature profile on the other side representing the inside ambiance in real cases. Finally, a frequency analysis was performed in order to assess the validity and accuracy of the method used. The results show that development to the second order is sufficient to predict the thermal behavior of the studied massive wall in the range of frequencies encountered in the building applications (one hour time step. This method is useful for thermal transfer analysis in real weather conditions where the outside temperature is stochastic; it also allows the evaluation of the thermal performance of a wall through a frequency analysis.

  7. High Efficiency and Low Cost Thermal Energy Storage System

    Energy Technology Data Exchange (ETDEWEB)

    Sienicki, James J. [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division; Lv, Qiuping [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division; Moisseytsev, Anton [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division; Bucknor, Matthew [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division

    2017-09-29

    BgtL, LLC (BgtL) is focused on developing and commercializing its proprietary compact technology for processes in the energy sector. One such application is a compact high efficiency Thermal Energy Storage (TES) system that utilizes the heat of fusion through phase change between solid and liquid to store and release energy at high temperatures and incorporate state-of-the-art insulation to minimize heat dissipation. BgtL’s TES system would greatly improve the economics of existing nuclear and coal-fired power plants by allowing the power plant to store energy when power prices are low and sell power into the grid when prices are high. Compared to existing battery storage technology, BgtL’s novel thermal energy storage solution can be significantly less costly to acquire and maintain, does not have any waste or environmental emissions, and does not deteriorate over time; it can keep constant efficiency and operates cleanly and safely. BgtL’s engineers are experienced in this field and are able to design and engineer such a system to a specific power plant’s requirements. BgtL also has a strong manufacturing partner to fabricate the system such that it qualifies for an ASME code stamp. BgtL’s vision is to be the leading provider of compact systems for various applications including energy storage. BgtL requests that all technical information about the TES designs be protected as proprietary information. To honor that request, only non-proprietay summaries are included in this report.

  8. Thermal energy storage for the Stirling engine powered automobile

    Science.gov (United States)

    Morgan, D. T. (Editor)

    1979-01-01

    A thermal energy storage (TES) system developed for use with the Stirling engine as an automotive power system has gravimetric and volumetric storage densities which are competitive with electric battery storage systems, meets all operational requirements for a practical vehicle, and can be packaged in compact sized automobiles with minimum impact on passenger and freight volume. The TES/Stirling system is the only storage approach for direct use of combustion heat from fuel sources not suitable for direct transport and use on the vehicle. The particular concept described is also useful for a dual mode TES/liquid fuel system in which the TES (recharged from an external energy source) is used for short duration trips (approximately 10 miles or less) and liquid fuel carried on board the vehicle used for long duration trips. The dual mode approach offers the potential of 50 percent savings in the consumption of premium liquid fuels for automotive propulsion in the United States.

  9. Space Evaporator Absorber Radiator (SEAR) for Thermal Storage on Manned Spacecraft

    Science.gov (United States)

    Izenson, Michael G.; Chen, Weibo; Chepko, Ariane; Bue, Grant; Quinn, Gregory

    2015-01-01

    Future manned exploration spacecraft will need to operate in challenging thermal environments. State-of-the-art technology for active thermal control relies on sublimating water ice and venting the vapor overboard in very hot environments, and or heavy phase change material heat exchangers for thermal storage. These approaches can lead to large loss of water and a significant mass penalties for the spacecraft. This paper describes an innovative thermal control system that uses a Space Evaporator Absorber Radiator (SEAR) to control spacecraft temperatures in highly variable environments without venting water. SEAR uses heat pumping and energy storage by LiCl/water absorption to enable effective cooling during hot periods and regeneration during cool periods. The LiCl absorber technology has the potential to absorb over 800 kJ per kg of system mass, compared to phase change heat sink systems that typically achieve approx. 50 kJ/kg. This paper describes analysis models to predict performance and optimize the size of the SEAR system, estimated size and mass of key components, and an assessment of potential mass savings compared with alternative thermal management approaches. We also describe a concept design for an ISS test package to demonstrate operation of a subscale system in zero gravity.

  10. Study of the valorisation of thermal storage and of power-to-heat. Study report + Study synthesis

    International Nuclear Information System (INIS)

    Canal, Patrick; Gerbaud, Manon; Mouret, Sylvain; Chammas, Maxime; Attard, Pierre; Bucy, Jacques de; Lochmann, Hugo; Le Gars, Loic; Payen, Luc; Lesueur, Herve

    2016-11-01

    This study aimed at assessing the potential of thermal storage and of power-to-heat in France, and at identifying relevant technological sectors by 2030. In order to do so, the study aimed at quantifying the value of these sectors for applications considered as relevant, this value lying in the valorisation of heat or electric power excesses, in the power arbitration, and in investment savings. Analyses have have been performed on case studies through an assessment of storage value and of P2H (Power-to-Heat) for the collectivity, a joint optimisation of fleet sizing and management, a modelling of power system fundamentals, an analysis of the profitability of storage and P2H projects, and an assessment of the technical source and of the impact on jobs. Thus, after an overview of thermal storage and power-to-heat technologies, and a presentation of the adopted methodology (definition of case studies, case study methodology, modelling hypotheses related to production and consumption, and modelling of the power system), the authors report the study of the sizing of biomass boilers in an urban heat network (determination of the storage value for the community), the study of development of an urban heat network (storage value for the community and for the operator, technological perspective by 2030), the study of the use of power-to-heat and storage for an urban heat network (value for the community, profitability and business model, perspective by 2030), the study of unavoidable heat recovery on an industrial site (value, profitability and business model, perspective by 2030), the study of co-generation and thermal storage on an industrial site (value, impact on income), the study of domestic thermal storage and of the flexibility of the French electric power system (impact of thermal water heaters on the flexibility), and the study of the impact on employment (jobs related to the domestic market and to the development of an exporting sector). Appendices propose sheets

  11. IEA SHC Task 42 / ECES Annex 29 - Working Group B: Applications of Compact Thermal Energy Storage

    NARCIS (Netherlands)

    Helden, W. van; Yamaha, M.; Rathgeber, C.; Hauer, A.; Huaylla, F.; Le Pierrès, N.; Stutz, B.; Mette, B.; Dolado, P.; Lazaro, A.; Mazo, J.; Dannemand, M.; Furbo, S.; Campos-Celador, A.; Diarce, G.; Cuypers, R.; König-Haagen, A.; Höhlein, S.; Brüggemann, D.; Fumey, B.; Weber, R.; Köll, R.; Wagner, W.; Daguenet-Frick, X.; Gantenbein, P.; Kuznik, F.

    2016-01-01

    The IEA joint Task 42 / Annex 29 is aimed at developing compact thermal energy storage materials and systems. In Working Group B, experts are working on the development of compact thermal energy storage applications, in the areas cooling, domestic heating and hot water and industry. The majority of

  12. A method to determine stratification efficiency of thermal energy storage processes independently from storage heat losses

    DEFF Research Database (Denmark)

    Haller, M.Y.; Yazdanshenas, Eshagh; Andersen, Elsa

    2010-01-01

    process is in agreement with the first law of thermodynamics. A comparison of the stratification efficiencies obtained from experimental results of charging, standby, and discharging processes gives meaningful insights into the different mixing behaviors of a storage tank that is charged and discharged......A new method for the calculation of a stratification efficiency of thermal energy storages based on the second law of thermodynamics is presented. The biasing influence of heat losses is studied theoretically and experimentally. Theoretically, it does not make a difference if the stratification...

  13. Absence of storage effects on radiation damage after thermal neutron irradiation of dry rice seeds

    Energy Technology Data Exchange (ETDEWEB)

    Kowyama, Y. [Mie Univ., Tsu (Japan); Saito, M.; Kawase, T.

    1987-09-15

    Storage effects on dry rice seeds equilibrated to 6.8% moisture content were examined after irradiation with X-rays of 5, 10, 20 and 40 kR and with thermal neutrons of 2.1, 4.2, 6.3 and 8.4×10{sup 13}N{sub th}/cm{sup 2}. Reduction in root growth was estimated from dose response curves after storage periods of 1 hr to 21 days. The longer the storage period, the greater enhancement of radiation damages in X-irradiated seeds. There were two components in the storage effect, i. e., a rapid increase of radiosensitivity within the first 24 hr and a slow increase up to 21 days. An almost complete absence of a storage effect was observed after thermal neutron exposure, in spite of considerably high radioactivities of the induced nuclides, {sup 56}Mn, {sup 42}K and {sup 24}Na, which were detected from gamma-ray spectrometry of the irradiated seeds. The present results suggest that the contributions of gamma-rays from the activated nuclides and of inherent contaminating gamma-rays are little or negligible against the neutron-induced damage, and that the main radiobiological effects of thermal neutrons are ascribed to in situ radiations, i, e., heavy particles resulting from neutron-capture reaction of atom. A mechanism underlying the absence of storage effect after thermal neutron irradiation was briefly discussed on the basis of radical formation and decay. (author)

  14. Numerical Simulation of the Thermal Performance of a Dry Storage Cask for Spent Nuclear Fuel

    Directory of Open Access Journals (Sweden)

    Heui-Yung Chang

    2018-01-01

    Full Text Available In this study, the heat flow characteristics and thermal performance of a dry storage cask were investigated via thermal flow experiments and a computational fluid dynamics (CFD simulation. The results indicate that there are many inner circulations in the flow channel of the cask (the channel width is 10 cm. These circulations affect the channel airflow efficiency, which in turn affects the heat dissipation of the dry storage cask. The daily operating temperatures at the top concrete lid and the upper locations of the concrete cask are higher than those permitted by the design specification. The installation of the salt particle collection device has a limited negative effect on the thermal dissipation performance of the dry storage cask.

  15. Thermal tests of a transport / Storage cask in buried conditions

    International Nuclear Information System (INIS)

    Yamakawa, H.; Gomi, Y.; Saegusa, T.; Ito, C.

    1998-01-01

    Thermal tests for a hypothetical accident which simulated accidents caused by building collapse in case of an earthquake were conducted using a full-scale dry type transport and storage cask (total heat load: 23 kW). The objectives of these tests were to clarify the heat transfer features of the buried cask under such accidents and the time limit for maintaining the thermal integrity of the cask. Moreover, thermal analyses of the test cask under the buried conditions were carried out on basis of experimental results to establish methodology for the thermal analysis. The characteristics of the test cask are described as well as the test method used. The heat transfer features of the buried cask under such accidents and a time for maintaining the thermal integrity of the cask have been obtained. (O.M.)

  16. Compatibility tests between Solar Salt and thermal storage ceramics from inorganic industrial wastes

    International Nuclear Information System (INIS)

    Motte, Fabrice; Falcoz, Quentin; Veron, Emmanuel; Py, Xavier

    2015-01-01

    Highlights: • ESEM and XRD characterizations have been performed. • Compatibility of these ceramics with the conventional binary Solar Salt is tested at 500 °C. • Tested ceramics have relevant properties to store thermal energy up to 1000 °C. • Feasibility of using ceramics as filler materials in thermocline is demonstrated. - Abstract: This paper demonstrates the feasibility of using several post-industrial ceramics as filler materials in a direct thermocline storage configuration. The tested ceramics, coming from several industrial processes (asbestos containing waste treatment, coal fired power plants or metallurgic furnaces) demonstrate relevant properties to store thermal energy by sensible heat up to 1000 °C. Thus, they represent at low-cost a promising, efficient and sustainable approach for thermal energy storage. In the present study, the thermo-chemical compatibility of these ceramics with the conventional binary Solar Salt is tested at medium temperature (500 °C) under steady state. In order to determine the feasibility of using such ceramics as filler material, Environmental Scanning Electron Microscopy (ESEM) and X-Ray Diffraction (XRD) characterizations have been performed to check for their chemical and structural evolution during corrosion tests. The final objective is to develop a molten salt thermocline direct storage system using low-cost shaped ceramic as structured filler material. Most of the tested ceramics present an excellent corrosion resistance in molten Solar Salt and should significantly decrease the current cost of concentrated solar thermal energy storage system

  17. Design and installation manual for thermal energy storage

    Energy Technology Data Exchange (ETDEWEB)

    Cole, R L; Nield, K J; Rohde, R R; Wolosewicz, R M [eds.

    1979-02-01

    The purpose for this manual is to provide information on the design and installation of thermal energy storage in solar heating systems. It is intended for contractors, installers, solar system designers, engineers, architects, and manufacturers who intend to enter the solar energy business. The reader should have general knowledge of how solar heating systems operate and knowledge of construction methods and building codes. Knowledge of solar analysis methods such as f-chart, SOLCOST, DOE-1, or TRNSYS would be helpful. The information contained in the manual includes sizing storage, choosing a location for the storage device, and insulation requirements. Both air-based and liquid-based systems are covered with topics on designing rock beds, tank types, pump and fan selection, installation, costs, and operation and maintenance. Topics relevant to heating domestic water include safety, single- and dual-tank systems, domestic water heating with air- and liquid-based space heating system, and stand-alone domestic hot water systems. Several appendices present common problems with storage systems and their solutions, heat transfer fluid properties, heat exchanger sizing, and sample specifications for heat exchangers, wooden rock bins, steel tanks, concrete tanks, and fiberglass-reinforced plastic tanks.

  18. The effect of thermal conductance of vertical walls on natural convection in a rectangular enclosure

    International Nuclear Information System (INIS)

    Kikuchi, Y.; Yoshino, A.; Taii, K.

    2004-01-01

    This paper deals with the experimental results of natural convective heat transfer in a rectangular water layer bounded by vertical walls of different thermal conductance. The vertical walls were made of copper or stainless steel. A minimum was observed in the horizontal distribution of temperature near the heating wall since a secondary reverse flow occurred outside the boundary layer. For copper case the experimental results of Nusselt number agreed well with calculations under an isothermal wall condition. For stainless steel case, however, the measured values were lower than the calculations since a three-dimensional effect appeared in convection due to non-uniformity in wall temperature. (author)

  19. Radiation Heat Transfer Modeling Improved for Phase-Change, Thermal Energy Storage Systems

    Science.gov (United States)

    Kerslake, Thomas W.; Jacqmin, David A.

    1998-01-01

    Spacecraft solar dynamic power systems typically use high-temperature phase-change materials to efficiently store thermal energy for heat engine operation in orbital eclipse periods. Lithium fluoride salts are particularly well suited for this application because of their high heat of fusion, long-term stability, and appropriate melting point. Considerable attention has been focused on the development of thermal energy storage (TES) canisters that employ either pure lithium fluoride (LiF), with a melting point of 1121 K, or eutectic composition lithium-fluoride/calcium-difluoride (LiF-20CaF2), with a 1040 K melting point, as the phase-change material. Primary goals of TES canister development include maximizing the phase-change material melt fraction, minimizing the canister mass per unit of energy storage, and maximizing the phase-change material thermal charge/discharge rates within the limits posed by the container structure.

  20. Characterization of Cell Wall Components and Their Modifications during Postharvest Storage of Asparagus officinalis L.: Storage-Related Changes in Dietary Fiber Composition.

    Science.gov (United States)

    Schäfer, Judith; Wagner, Steffen; Trierweiler, Bernhard; Bunzel, Mirko

    2016-01-20

    Changes in cell wall composition during storage of plant foods potentially alter the physiological effects of dietary fiber components. To investigate postharvest cell wall modifications of asparagus and their consequences in terms of insoluble dietary fiber structures, asparagus was stored at 20 and 1 °C for different periods of time. Structural analyses demonstrated postharvest changes in the polysaccharide profile, dominated by decreased portions of galactans. Increasing lignin contents correlated with compositional changes (monolignol ratios and linkage types) of the lignin polymer as demonstrated by chemical and two-dimensional nuclear magnetic resonance (2D-NMR) methods. Depending on the storage time and temperature, syringyl units were preferentially incorporated into the lignin polymer. Furthermore, a drastic increase in the level of ester-linked phenolic monomers (i.e., p-coumaric acid and ferulic acid) and polymer cross-links (di- and triferulic acids) was detected. The attachment of p-coumaric acid to lignin was demonstrated by 2D-NMR experiments. Potential consequences of postharvest modifications on physiological effects of asparagus dietary fiber are discussed.

  1. A solar air collector with integrated latent heat thermal storage

    Directory of Open Access Journals (Sweden)

    Klimes Lubomir

    2012-04-01

    Full Text Available Simulations of the behaviour of a solar air collector with integrated latent heat thermal storage were performed. The model of the collector was created with the use of coupling between TRNSYS 17 and MATLAB. Latent heat storage (Phase Change Material - PCM was integrated with the solar absorber. The model of the latent heat storage absorber was created in MATLAB and the model of the solar air collector itself was created in TRNSYS with the use of TYPE 56. The model of the latent heat storage absorber allows specification of the PCM properties as well as other parameters. The simulated air collector was the front and back pass collector with the absorber in the middle of the air cavity. Two variants were considered for comparison; the light-weight absorber made of sheet metal and the heat-storage absorber with the PCM. Simulations were performed for the climatic conditions of the Czech Republic (using TMY weather data.

  2. Plutonium storage thermal analysis (U)

    International Nuclear Information System (INIS)

    Hensel, S.J.; Lee, S.Y.; Schaade, J.B.

    1997-01-01

    Thermal modeling of plutonium metal ingots stored in food pack cans provides information useful for performing stored material safety evaluations. Four storage can geometries were modeled, and several conclusions can be made from the 14 cases analyzed. The ingot temperature increased from 7 degrees F to 12 degrees F (depending on can configuration) per additional watt of power. Including internal convection lowers computed ingot temperatures by 70 degrees F. Accounting for the heat flow through the bottom of the cans to the storage rack lowered computed ingot temperatures by an additional 70 degrees F to 80 degrees F. In the rimmed can systems storing ingots with a power of 10.35 watts, the ingot temperature varies from 190 degrees F to 213 degrees F. Including a plastic bag between the inner and outer can increases the ingot temperature by 15 degrees F. Adding a label to the outer can side reduces the outer can side temperature by 13 degrees F. Changes in ambient temperature affect the outer can temperatures more than the ingot temperature by a factor of 3. Similarly, a 5 degrees F drop in outer can temperature due to increased convection lowered the ingot temperature by only 2 degrees F

  3. Thermal fatigue crack growth on a thick wall tube containing a semi elliptical circumferential crack

    International Nuclear Information System (INIS)

    Deschanels, H.; Wakai, T.; Lacire, M.H.; Michel, B.

    2001-01-01

    In order to check the ability of the simplified assessment procedure (A16 guide) to predict fatigue crack growth, a benchmark problem was conducted. This work is carried out under the project ''agreement on the Exchange of Information and Collaboration in the field of Research and Development of Fast Breeder Reactor (FBR) between Europe (EU) and Japan''. Experimental work is conducted by PNC using Air cooled Thermal transient Test Facility (ATTF). Specimen is a thick wall tube containing a semi elliptical (3-D) circumferential crack and subjected to cyclic thermal transients. The constitutive material is the 304 austenitic stainless steel type SUS304. Due to thermal shock (650 C-300 C) the stress distribution through the wall is non-linear and well approximated using a 3 rd order polynomial. When comparing computations and tests data we observe a good agreement for the crack propagation in length. In crack depth, accurate results are obtained in the first part of the test, but on the later stage of the experiment the computations slightly underestimate the propagation (deep crack). In addition, we notice the importance of good evaluation of fracture mechanics parameters for non-linear stress distribution through the wall. At present A16 guide handbook gives stress intensity factor solutions for non-linear stress distribution through the wall. (author)

  4. Composite materials for thermal energy storage

    Science.gov (United States)

    Benson, D. K.; Burrows, R. W.; Shinton, Y. D.

    1985-01-01

    A composite material for thermal energy storage based upon polyhydric alcohols, such as pentaerythritol, trimethylol ethane (also known as pentaglycerine), neopentyl glycol and related compounds including trimethylol propane, monoaminopentaerythritol, diamino-pentaerythritol and tris(hydroxymethyl)acetic acid, separately or in combinations, which provide reversible heat storage through crystalline phase transformations are discussed. These PCM's do not become liquid during use and are in contact with at least one material selected from the group consisting of metals, carbon, siliceous, plastic, cellulosic, natural fiber, artificial fiber, concrete, gypsum, porous rock, and mixtures thereof. Particulate additions such as aluminum or graphite powders, as well as metal and carbon fibers can also be incorporated therein. Particulate and/or fibrous additions can be introduced into molten phase change materials which can then be cast into various shapes. After the phase change materials have solidified, the additions will remain dispersed throughout the matrix of the cast solid. The polyol is in contact with at least one material selected from the group consisting of metals, carbon, siliceous, plastic, cellulosic, natural fiber, artificial fiber, concrete, gypsum, and mixtures thereof.

  5. Composite materials for thermal energy storage

    Science.gov (United States)

    Benson, D.K.; Burrows, R.W.; Shinton, Y.D.

    1985-01-04

    A composite material for thermal energy storage based upon polyhydric alcohols, such as pentaerythritol, trimethylol ethane (also known as pentaglycerine), neopentyl glycol and related compounds including trimethylol propane, monoaminopentaerythritol, diamino-pentaerythritol and tris(hydroxymethyl)acetic acid, separately or in combinations, which provide reversible heat storage through crystalline phase transformations. These PCM's do not become liquid during use and are in contact with at least one material selected from the group consisting of metals, carbon, siliceous, plastic, cellulosic, natural fiber, artificial fiber, concrete, gypsum, porous rock, and mixtures thereof. Particulate additions such as aluminum or graphite powders, as well as metal and carbon fibers can also be incorporated therein. Particulate and/or fibrous additions can be introduced into molten phase change materials which can then be cast into various shapes. After the phase change materials have solidified, the additions will remain dispersed throughout the matrix of the cast solid. The polyol is in contact with at least one material selected from the group consisting of metals, carbon, siliceous, plastic, cellulosic, natural fiber, artificial fiber, concrete, gypsum, and mixtures thereof.

  6. Post-storage cell wall metabolism in two sweet cherry (Prunus avium L.) cultivars displaying different postharvest performance

    OpenAIRE

    Belge, Burcu; Comabella, Eva; Graell i Sarle, Jordi; Lara Ayala, Isabel

    2015-01-01

    The biochemical processes underlying firmness loss of sweet cherry (Prunus avium L.) fruit are poorly understood.Studies on cell wall metabolism of sweet cherry have been generally undertaken during on-tree development or at harvest maturity, while published reports on postharvest changes are scarce and fragmentary. In this work, cell wall modifications after storage at 0 ºC were studied in two cherry cultivars ('Celeste' and 'Somerset') displaying different postharvest potential. Firmness wa...

  7. Effect of p-type multi-walled carbon nanotubes for improving hydrogen storage behaviors

    International Nuclear Information System (INIS)

    Lee, Seul-Yi; Yop Rhee, Kyong; Nahm, Seung-Hoon; Park, Soo-Jin

    2014-01-01

    In this study, the hydrogen storage behaviors of p-type multi-walled carbon nanotubes (MWNTs) were investigated through the surface modification of MWNTs by immersing them in sulfuric acid (H 2 SO 4 ) and hydrogen peroxide (H 2 O 2 ) at various ratios. The presence of acceptor-functional groups on the p-type MWNT surfaces was confirmed by X-ray photoelectron spectroscopy. Measurement of the zeta-potential determined the surface charge transfer and dispersion of the p-type MWMTs, and the hydrogen storage capacity was evaluated at 77 K and 1 bar. From the results obtained, it was found that acceptor-functional groups were introduced onto the MWNT surfaces, and the dispersion of MWNTs could be improved depending on the acid-mixed treatment conditions. The hydrogen storage was increased by acid-mixed treatments of up to 0.36 wt% in the p-type MWNTs, compared with 0.18 wt% in the As-received MWNTs. Consequently, the hydrogen storage capacities were greatly influenced by the acceptor-functional groups of p-type MWNT surfaces, resulting in increased electron acceptor–donor interaction at the interfaces. - Graphical abstract: Hydrogen storage behaviors of the p-type MWNTs with the acid-mixed treatments are described. Display Omitted Display Omitted

  8. Thermal energy storage using thermo-chemical heat pump

    International Nuclear Information System (INIS)

    Hamdan, M.A.; Rossides, S.D.; Haj Khalil, R.

    2013-01-01

    Highlights: ► Understanding of the performance of thermo chemical heat pump. ► Tool for storing thermal energy. ► Parameters that affect the amount of thermal stored energy. ► Lithium chloride has better effect on storing thermal energy. - Abstract: A theoretical study was performed to investigate the potential of storing thermal energy using a heat pump which is a thermo-chemical storage system consisting of water as sorbet, and sodium chloride as the sorbent. The effect of different parameters namely; the amount of vaporized water from the evaporator, the system initial temperature and the type of salt on the increase in temperature of the salt was investigated and hence on the performance of the thermo chemical heat pump. It was found that the performance of the heat pump improves with the initial system temperature, with the amount of water vaporized and with the water remaining in the system. Finally it was also found that lithium chloride salt has higher effect on the performance of the heat pump that of sodium chloride.

  9. Effect of kinetics on the thermal performance of a sorption heat storage reactor

    NARCIS (Netherlands)

    Gaeini, M.; Zondag, H.A.; Rindt, C.C.M.

    2016-01-01

    To reach high solar fractions for solar thermal energy in the built environment, long-term heat storage is required to overcome the seasonal mismatch. A promising method for long term heat storage is to use thermochemical materials, TCMs. In this research, a lab-scale test thermochemical heat

  10. Computational Analysis on Performance of Thermal Energy Storage (TES) Diffuser

    Science.gov (United States)

    Adib, M. A. H. M.; Adnan, F.; Ismail, A. R.; Kardigama, K.; Salaam, H. A.; Ahmad, Z.; Johari, N. H.; Anuar, Z.; Azmi, N. S. N.

    2012-09-01

    Application of thermal energy storage (TES) system reduces cost and energy consumption. The performance of the overall operation is affected by diffuser design. In this study, computational analysis is used to determine the thermocline thickness. Three dimensional simulations with different tank height-to-diameter ratio (HD), diffuser opening and the effect of difference number of diffuser holes are investigated. Medium HD tanks simulations with double ring octagonal diffuser show good thermocline behavior and clear distinction between warm and cold water. The result show, the best performance of thermocline thickness during 50% time charging occur in medium tank with height-to-diameter ratio of 4.0 and double ring octagonal diffuser with 48 holes (9mm opening ~ 60%) acceptable compared to diffuser with 6mm ~ 40% and 12mm ~ 80% opening. The conclusion is computational analysis method are very useful in the study on performance of thermal energy storage (TES).

  11. Detailed energy saving performance analyses on thermal mass walls demonstrated in a zero energy house

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, L. [School of Architecture, Tianjin University, Tianjin 300072 (China); Hurt, R.; Correia, D.; Boehm, R. [Center for Energy Research, University of Nevada, Las Vegas, NV 89154 (United States)

    2009-03-15

    An insulated concrete wall system{sup 1}1 was used on exterior walls of a zero energy house. Its thermal functions were investigated using actual data in comparison to a conventional wood frame system. The internal wall temperature of massive systems changes more slowly than the conventional wall constructions, leading to a more stable indoor temperature. The Energy10 simulated equivalent R-value and DBMS of the mass walls under actual climate conditions are, respectively, 6.98 (m{sup 2} C)/W and 3.39. However, the simulated heating energy use was much lower for the massive walls while the cooling load was a little higher. Further investigation on the heat flux indicates that the heat actually is transferred inside all day and night, which results in a higher cooling energy consumption. A one-dimensional model further verified these analyses, and the calculated results are in good agreement with the actual data. We conclude that the thermal mass wall does have the ability to store heat during the daytime and release it back at night, but in desert climates with high 24-h ambient temperature and intense sunlight, more heat will be stored than can be transferred back outside at night. As a result, an increased cooling energy will be required. (author)

  12. First wall thermal stress analysis for suddenly applied heat fluxes

    International Nuclear Information System (INIS)

    Dalessandro, J.A.

    The failure criterion for a solid first wall of an inertial confinement reactor is investigated. Analytical expressions for induced thermal stresses in a plate are given. Two materials have been chosen for this investigation: grade H-451 graphite and chemically vapor deposited (CVD) β-silicon carbide. Structural failure can be related to either the maximum compressive stress produced on the surface or the maximum tensile stress developed in the interior of the plate; however, it is shown that compressive failure would predominate. A basis for the choice of the thermal shock figure of merit, k(1 - ν) sigma/E α kappa/sup 1/2/, is identified. The result is that graphite and silicon carbide rank comparably

  13. Exact solution of thermal energy storage system using PCM flat slabs configuration

    International Nuclear Information System (INIS)

    Bechiri, Mohammed; Mansouri, Kacem

    2013-01-01

    Highlights: • An exact solution of a latent heat storage unit (LHSU) consisting of several flat slabs was obtained. • The working fluid (HTF) circulating by forced convection between the slabs charges and discharges the storage unit. • The charging/discharging process is investigated for various HTF working conditions and different design parameters. - Abstract: An analytical investigation of thermal energy storage system (TESS) consisting of several flat slabs of phase change material (PCM) is presented. The working fluid (HTF) circulating on laminar forced convection between the slabs charges and discharges the storage unit. The melting and solidification of the PCM was treated as a radial one dimensional conduction problem. The forced convective heat transfer inside the channels is analyzed by solving the energy equation, which is coupled with the heat conduction equation in the PCM container. The comparison between the present exact solution with the numerical predictions and experimental data available in literature shows good agreement. The charging/discharging process is investigated in terms of liquid–solid interface position, liquid fraction, total heat transmitted to the PCM and thermal storage efficiency for various HTF working conditions and different design parameters such as PCM slab length, fluid passage gap and thickness of PCM duct container

  14. Demonstration of EnergyNest thermal energy storage (TES) technology

    Science.gov (United States)

    Hoivik, Nils; Greiner, Christopher; Tirado, Eva Bellido; Barragan, Juan; Bergan, Pâl; Skeie, Geir; Blanco, Pablo; Calvet, Nicolas

    2017-06-01

    This paper presents the experimental results from the EnergyNest 2 × 500 kWhth thermal energy storage (TES) pilot system installed at Masdar Institute of Science & Technology Solar Platform. Measured data are shown and compared to simulations using a specially developed computer program to verify the stability and performance of the TES. The TES is based on a solid-state concrete storage medium (HEATCRETE®) with integrated steel tube heat exchangers cast into the concrete. The unique concrete recipe used in the TES has been developed in collaboration with Heidelberg Cement; this material has significantly higher thermal conductivity compared to regular concrete implying very effective heat transfer, at the same time being chemically stable up to 450 °C. The demonstrated and measured performance of the TES matches the predictions based on simulations, and proves the operational feasibility of the EnergyNest concrete-based TES. A further case study is analyzed where a large-scale TES system presented in this article is compared to two-tank indirect molten salt technology.

  15. Evaluation of solar thermal storages with quantitative flow visualisation

    Energy Technology Data Exchange (ETDEWEB)

    Logie, W.; Frank, E.; Luzzi, A.

    2008-07-15

    The non-intrusive Quantitative Flow Visualisation (QFV) Techniques of Particle Imaging Velocimetry (PIV) and Laser Induced Fluorescence (LIF) have been evaluated in the context of experimental investigations on solar Thermal Energy Storages (TES). Much competence and experience has been gained in the integration of these powerful yet complex and time consuming flow analysis methods into the realm of laboratory experimentation. In addition to gathering experience in the application of QFV techniques, a number of charging and discharging variations were considered in light of exergetic evaluation for the influence they have on the ability of a TES to stratify. The contemporary awareness that poorly chosen pitch to diameter ratios by the design of immersed coil heat exchangers leads to a reduction in heat exchange and an increase in mixing phenomenon has been confirmed. The observation of two combitank (combined domestic hot water and space heating) configurations has shown that free convective heat transfer forces in the form of mixing energy play a significant role in the stratification efficiency of thermal energy storages. (author)

  16. Three-Dimensional Numerical Evaluation of Thermal Performance of Uninsulated Wall Assemblies

    Energy Technology Data Exchange (ETDEWEB)

    Ridouane, El Hassan [National Renewable Energy Lab. (NREL), Golden, CO (United States); Bianchi, Marcus V.A. [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2011-11-01

    This study describes a detailed 3D computational fluid dynamics model that evaluates the thermal performance of uninsulated wall assemblies. It accounts for conduction through framing, convection, and radiation and allows for material property variations with temperature. This research was presented at the ASME 2011 International Mechanical Engineering Congress and Exhibition; Denver, Colorado; November 11-17, 2011

  17. Thermal Analysis of a Thermal Energy Storage Unit to Enhance a Workshop Heating System Driven by Industrial Residual Water

    Directory of Open Access Journals (Sweden)

    Wenqiang Sun

    2017-02-01

    Full Text Available Various energy sources can be used for room heating, among which waste heat utilization has significantly improved in recent years. However, the majority of applicable waste heat resources are high-grade or stable thermal energy, while the low-grade or unstable waste heat resources, especially low-temperature industrial residual water (IRW, are insufficiently used. A thermal energy storage (TES unit with paraffin wax as a phase change material (PCM is designed to solve this problem in a pharmaceutical plant. The mathematical models are developed to simulate the heat storage and release processes of the TES unit. The crucial parameters in the recurrence formulae are determined: the phase change temperature range of the paraffin wax used is 47 to 56 °C, and the latent heat is 171.4 kJ/kg. Several thermal behaviors, such as the changes of melting radius, solidification radius, and fluid temperature, are simulated. In addition, the amount of heat transferred, the heat transfer rate, and the heat storage efficiency are discussed. It is presented that the medicine production unit could save 10.25% of energy consumption in the investigated application.

  18. Investigation of thermal storage and steam generator issues

    Energy Technology Data Exchange (ETDEWEB)

    1993-08-01

    A review and evaluation of steam generator and thermal storage tank designs for commercial nitrate salt technology showed that the potential exists to procure both on a competitive basis from a number of qualified vendors. The report outlines the criteria for review and the results of the review, which was intended only to assess the feasibility of each design, not to make a comparison or select the best concept.

  19. The inaccuracy of conventional one-dimensional parallel thermal resistance circuit model for two-dimensional composite walls

    International Nuclear Information System (INIS)

    Wong, K.-L.; Hsien, T.-L.; Hsiao, M.-C.; Chen, W.-L.; Lin, K.-C.

    2008-01-01

    This investigation is to show that two-dimensional steady state heat transfer problems of composite walls should not be solved by the conventionally one-dimensional parallel thermal resistance circuits (PTRC) model because the interface temperatures are not unique. Thus PTRC model cannot be used like its conventional recognized analogy, parallel electrical resistance circuits (PERC) model which has the unique node electric voltage. Two typical composite wall examples, solved by CFD software, are used to demonstrate the incorrectness. The numerical results are compared with those obtained by PTRC model, and very large differences are observed between their results. This proves that the application of conventional heat transfer PTRC model to two-dimensional composite walls, introduced in most heat transfer text book, is totally incorrect. An alternative one-dimensional separately series thermal resistance circuit (SSTRC) model is proposed and applied to the two-dimensional composite walls with isothermal boundaries. Results with acceptable accuracy can be obtained by the new model

  20. A predictive model for the chemical vapor deposition of polysilicon in a cold wall, rapid thermal system

    Energy Technology Data Exchange (ETDEWEB)

    Toprac, A.J.; Trachtenberg, I.; Edgar, T.F. (Univ. of Texas, Austin, TX (United States). Dept. of Chemical Engineering)

    1994-06-01

    The chemical vapor deposition of polysilicon from thermally activated silane in a cold wall, single-wafer rapid thermal system was studied by experimentation at a variety of low pressure conditions, including very high temperatures. The effect of diluent gas on polysilicon deposition rates was examined using hydrogen, helium, and krypton. A mass-transfer model for the chemical vapor deposition of polysilicon in a cold wall, rapid thermal system was developed. This model was used to produce an empirical rate expression for silicon deposition from silane by regressing kinetic parameters to fit experimental data. The resulting model provided accurate predictions over widely varying conditions in the experimental data.

  1. Applications of thermal energy storage to waste heat recovery in the food processing industry

    Science.gov (United States)

    Wojnar, F.; Lunberg, W. L.

    1980-01-01

    A study to assess the potential for waste heat recovery in the food industry and to evaluate prospective waste heat recovery system concepts employing thermal energy storage was conducted. The study found that the recovery of waste heat in canning facilities can be performed in significant quantities using systems involving thermal energy storage that are both practical and economical. A demonstration project is proposed to determine actual waste heat recovery costs and benefits and to encourage system implementation by the food industry.

  2. Nanoengineered Carbon Scaffolds for Hydrogen Storage

    Energy Technology Data Exchange (ETDEWEB)

    Leonard, A. D.; Hudson, J. L.; Fan, H.; Booker, R.; Simpson, L. J.; O' Neill, K. J.; Parilla, P. A.; Heben, M. J.; Pasquali, M.; Kittrell, C.; Tour, J. M.

    2009-01-01

    Single-walled carbon nanotube (SWCNT) fibers were engineered to become a scaffold for the storage of hydrogen. Carbon nanotube fibers were swollen in oleum (fuming sulfuric acid), and organic spacer groups were covalently linked between the nanotubes using diazonium functionalization chemistry to provide 3-dimensional (3-D) frameworks for the adsorption of hydrogen molecules. These 3-D nanoengineered fibers physisorb twice as much hydrogen per unit surface area as do typical macroporous carbon materials. These fiber-based systems can have high density, and combined with the outstanding thermal conductivity of carbon nanotubes, this points a way toward solving the volumetric and heat-transfer constraints that limit some other hydrogen-storage supports.

  3. Preparation, thermal properties and thermal reliabilities of microencapsulated n-octadecane with acrylic-based polymer shells for thermal energy storage

    International Nuclear Information System (INIS)

    Qiu, Xiaolin; Song, Guolin; Chu, Xiaodong; Li, Xuezhu; Tang, Guoyi

    2013-01-01

    Highlights: ► n-Octadecane was encapsulated by p(butyl methacrylate) (PBMA) and p(butyl acrylate). ► Microcapsules using divinylbenzene as crosslinking agent have better quality. ► Microcapsule with butyl methacrylate–divinylbenzene has highest latent heat. ► Microcapsule with butyl methacrylate–divinylbenzene has greatest thermal stability. ► Phase change temperatures and enthalpies of the microcapsules varied little after thermal cycle. - Abstract: Microencapsulation of n-octadecane with crosslinked p(butyl methacrylate) (PBMA) and p(butyl acrylate) (PBA) as shells for thermal energy storage was carried out by a suspension-like polymerization. Divinylbenzene (DVB) and pentaerythritol triacrylate (PETA) were employed as crosslinking agents. The surface morphologies of the microencapsulated phase change materials (microPCMs) were studied by scanning electron microscopy (SEM). Thermal properties, thermal reliabilities and thermal stabilities of the as-prepared microPCMs were investigated by differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). The microPCMs prepared by using DVB exhibit greater heat capacities and higher thermal stabilities compared with those prepared by using PETA. The thermal resistant temperature of the microPCM with BMA–DVB polymer was up to 248 °C. The phase change temperatures and latent heats of all the as-prepared microcapsules varied little after 1000 thermal cycles.

  4. Experimental investigation for the optimization of heat pipe performance in latent heat thermal storage

    Energy Technology Data Exchange (ETDEWEB)

    Ladekar, Chandrakishor; Choudhary, S. K. [RTM Nagpur University, Wardha (India); Khandare, S. S. [B. D. College of Engineering, Wardha (India)

    2017-06-15

    We investigated the optimum performance of heat pipe in Latent heat thermal energy storage (LHTES), and compared it with copper pipe. Classical plan of experimentation was used to optimize the parameters of heat pipe. Heat pipe fill ratio, evaporator section length to condenser section length ratio i.e., Heat pipe length ratio (HPLR) and heat pipe diameter, was the parameter used for optimization, as result of parametric analysis. Experiment with flow rate of 10 lit./min. was conducted for different fill ratio, HPLR and different diameter. Fill ratio of 80 %, HPLR of 0.9 and heat pipe with diameter of 18 mm showed better trend in charging and discharging. Comparison between the storage tank with optimized heat pipe and copper pipe showed almost 186 % improvement in charging and discharging time compared with the copper pipe embedded thermal storage. Heat transfer between Heat transferring fluid (HTF) and Phase change material (PCM) increased with increase in area of heat transferring media, but storage density of storage tank decreased. Storage tank with heat pipe embedded in place of copper pipe is a better option in terms of charging and discharging time as well heat storage capacity due to less heat lost. This justifies the better efficiency and effectiveness of storage tank with embedded optimized heat pipe.

  5. Experimental and Numerical Study of Effect of Thermal Management on Storage Capacity of the Adsorbed Natural Gas Vessel

    KAUST Repository

    Ybyraiymkul, Doskhan; Ng, Kim Choon; Кaltayev, Aidarkhan

    2017-01-01

    One of the main challenges in the adsorbed natural gas (ANG) storage system is the thermal effect of adsorption, which significantly lowers storage capacity. These challenges can be solved by efficient thermal management system. In this paper

  6. 1-Dimensional simulation of thermal annealing in a commercial nuclear power plant reactor pressure vessel wall section

    International Nuclear Information System (INIS)

    Nakos, J.T.; Rosinski, S.T.; Acton, R.U.

    1994-11-01

    The objective of this work was to provide experimental heat transfer boundary condition and reactor pressure vessel (RPV) section thermal response data that can be used to benchmark computer codes that simulate thermal annealing of RPVS. This specific protect was designed to provide the Electric Power Research Institute (EPRI) with experimental data that could be used to support the development of a thermal annealing model. A secondary benefit is to provide additional experimental data (e.g., thermal response of concrete reactor cavity wall) that could be of use in an annealing demonstration project. The setup comprised a heater assembly, a 1.2 in x 1.2 m x 17.1 cm thick [4 ft x 4 ft x 6.75 in] section of an RPV (A533B ferritic steel with stainless steel cladding), a mockup of the open-quotes mirrorclose quotes insulation between the RPV and the concrete reactor cavity wall, and a 25.4 cm [10 in] thick concrete wall, 2.1 in x 2.1 in [10 ft x 10 ft] square. Experiments were performed at temperature heat-up/cooldown rates of 7, 14, and 28 degrees C/hr [12.5, 25, and 50 degrees F/hr] as measured on the heated face. A peak temperature of 454 degrees C [850 degrees F] was maintained on the heated face until the concrete wall temperature reached equilibrium. Results are most representative of those RPV locations where the heat transfer would be 1-dimensional. Temperature was measured at multiple locations on the heated and unheated faces of the RPV section and the concrete wall. Incident heat flux was measured on the heated face, and absorbed heat flux estimates were generated from temperature measurements and an inverse heat conduction code. Through-wall temperature differences, concrete wall temperature response, heat flux absorbed into the RPV surface and incident on the surface are presented. All of these data are useful to modelers developing codes to simulate RPV annealing

  7. Thermal analysis of the drywell for the Nuclear Material Storage Facility

    International Nuclear Information System (INIS)

    Steinke, R.G.

    1997-01-01

    The Nuclear Materials Storage Facility Renovation Project has a conceptual design for the facility to store nuclear materials in containers inside drywells with passive cooling for long-term storage. The CFX thermal-hydraulic computer program was used to analyze internal heat-transfer processes by conduction, convection, and radiation with natural circulation of air by hydraulic buoyancy with turbulence and thermal stratification (TS) evaluated. A vertical drywell was modeled with 14 containers on support plates at 12-in. intervals. The TS of bay air outside the drywell increased the container maximum temperature by 0.728 F for each 1.0 F of bay-air TS from the bottom to the top of the drywell. The drywell outer-surface peak heat flux was shifted downward because of the effect of bay-air TS. An equivalent model was evaluated by the nodal-network conduction, convection, and radiation heat-transfer computer program (Thermal System Analysis Program) TSAP. The TSAP results are in good agreement with the CFX-model results, with the difference in results understood based on the approximations of each model

  8. Energy managemant through PCM based thermal storage system for building air-conditioning: Tidel Park, Chennai

    International Nuclear Information System (INIS)

    Nallusamy, N.; Sampath, S.; Velraj, R.

    2006-01-01

    Many modern building are designed for air-conditioning and the amount of electrical energy required for providing air-conditioning can be very significant especially in the tropics. Conservation of energy is major concern to improve the overall efficiency of the system. Integration is energy storage with the conventional system gives a lot of potential for energy saving and long-term economics. Thermal energy storage systems can improve energy management and help in matching supply and demand patterns. In the present work, a detailed study has been done on the existing thermal energy storage system used in the air-conditioning system in Tidel Park, Chennai. The present study focuses on the cool energy storage system. The modes of operation and advantages of such a system for energy management are highlighted. The reason for the adoption of combined storage system and the size of the storage medium in the air-conditioning plant are analyzed. The possibility of using this concept in other cooling and heating applications, such as storage type solar water heating system, has been explored

  9. F2-3 using the shield for thermal energy storage in PULSAR

    International Nuclear Information System (INIS)

    Sager, G.T.; Sze, D.K.; Wong, C.P.C.

    1994-01-01

    The PULSAR design study is evaluating the pulsed, inductively driven tokamak power plant to assess whether economies can be attained which-are more favorable than those of the steady-state, non-inductively driven tokamak. Considerations of market acceptance and component fatigue lead to the requirement of thermal energy storage (TES) to maintain steady-state power during the cyclic interruptions of fusion power production (open-quotes dwell phaseclose quotes). A major focus of the Study has been to identify and design technically viable TES systems for helium-cooled and liquid lithium self-cooled plants which are economically attractive, safe and environmentally benign. Several basic constraints impact the selection of the TES system. The system must be capable of discharging 2.5 GW during a dwell phase of approximately two minutes (determined by systems code analysis), thus have a capacity of at least 300 GJ. Coolant must be discharged from the TES at the static, burn phase temperature to minimize thermal stress in the steam generator. Several TES options were evaluated: Storage of heat transport working fluid, phase change media and sensible heat storage. Sensible heat storage in the outer shield was selected for PULSAR

  10. Preparation and thermal properties characterization of carbonate salt/carbon nanomaterial composite phase change material

    International Nuclear Information System (INIS)

    Tao, Y.B.; Lin, C.H.; He, Y.L.

    2015-01-01

    Highlights: • Nanocomposite phase change materials were prepared and characterized. • Larger specific surface area is more efficient to enhance specific heat. • Columnar structure is more efficient to enhance thermal conductivity. • Thermal conductivity enhancement is the key. • Single walled carbon nanotube is the optimal nanomaterial additive. - Abstract: To enhance the performance of high temperature salt phase change material, four kinds of carbon nanomaterials with different microstructures were mixed into binary carbonate eutectic salts to prepare carbonate salt/nanomaterial composite phase change material. The microstructures of the nanomaterial and composite phase change material were characterized by scanning electron microscope. The thermal properties such as melting point, melting enthalpy, specific heat, thermal conductivity and total thermal energy storage capacity were characterized. The results show that the nanomaterial microstructure has great effects on composite phase change material thermal properties. The sheet structure Graphene is the best additive to enhance specific heat, which could be enhanced up to 18.57%. The single walled carbon nanotube with columnar structure is the best additive to enhance thermal conductivity, which could be enhanced up to 56.98%. Melting point increases but melting enthalpy decreases with nanomaterial specific surface area increase. Although the additives decrease the melting enthalpy of composite phase change material, they also enhance the specific heat. As a combined result, the additives have little effects on thermal energy storage capacity. So, for phase change material performance enhancement, more emphasis should be placed on thermal conductivity enhancement and single walled carbon nanotube is the optimal nanomaterial additive

  11. Computational Analysis on Performance of Thermal Energy Storage (TES) Diffuser

    International Nuclear Information System (INIS)

    Adib, M A H M; Ismail, A R; Kardigama, K; Salaam, H A; Ahmad, Z; Johari, N H; Anuar, Z; Azmi, N S N; Adnan, F

    2012-01-01

    Application of thermal energy storage (TES) system reduces cost and energy consumption. The performance of the overall operation is affected by diffuser design. In this study, computational analysis is used to determine the thermocline thickness. Three dimensional simulations with different tank height-to-diameter ratio (HD), diffuser opening and the effect of difference number of diffuser holes are investigated. Medium HD tanks simulations with double ring octagonal diffuser show good thermocline behavior and clear distinction between warm and cold water. The result show, the best performance of thermocline thickness during 50% time charging occur in medium tank with height-to-diameter ratio of 4.0 and double ring octagonal diffuser with 48 holes (9mm opening ∼ 60%) acceptable compared to diffuser with 6mm ∼ 40% and 12mm ∼ 80% opening. The conclusion is computational analysis method are very useful in the study on performance of thermal energy storage (TES).

  12. IEA SHC Task 42/ECES Annex 29 – A Simple Tool for the Economic Evaluation of Thermal Energy Storages

    DEFF Research Database (Denmark)

    Rathgeber, Christoph; Hiebler, Stefan; Lävemann, Eberhard

    2016-01-01

    Within the framework of IEA SHC Task 42 / ECES Annex 29, a simple tool for the economic evaluation of thermal energy storages has been developed and tested on various existing storages. On that account, the storage capacity costs (costs per installed storage capacity) of thermal energy storages...... have been evaluated via a Top-down and a Bottom-up approach. The Top-down approach follows the assumption that the costs of energy supplied by the storage should not exceed the costs of energy from the market. The maximum acceptable storage capacity costs depend on the interest rate assigned...

  13. The impact of thermal bridges on the energy demand of buildings with double brick wall constructions

    Energy Technology Data Exchange (ETDEWEB)

    Theodosiou, T.G. [Department of Engineering and Management of Energy Resources, University of Western Macedonia, GR-50100 Kozani (Greece); Papadopoulos, A.M. [Laboratory of Heat Transfer and Environmental Engineering, Department of Mechanical Engineering, Aristotle University Thessaloniki, GR-54124 Thessaloniki (Greece)

    2008-07-01

    The implementation of the European Directive on the Energy Performance of Buildings (EPBD) is a milestone towards the improvement of energy efficiency in the building sector. However, even in cases where impressive measures can be implemented in the densely built urban environment, the less glamorous measure of building's envelope thermal insulation remains a prerequisite towards the improvement of the building's energy efficiency. Despite the insulation requirements specified by national regulations, thermal bridges in the building's envelope remain a weak spot in the constructions. Moreover, in many countries construction practices tend to implement only partially the insulation measures foreseen by regulations. As a result, thermal losses are in practice greater than those predicted during the design stage. This paper presents a study on representative wall thermal insulation configurations used in Greek buildings, in order to investigate the impact of the thermal bridges on the energy consumption. The double wall construction, used widely in Greece and not only there, is rather susceptible to the occurrence of thermal bridges, in contrast to a typical thermal insulating facade, like the one applied in Central Europe. The analysis of the thermal bridges' impact will in that sense also highlight the potential for energy renovation measures in older buildings. (author)

  14. Using the shield for thermal energy storage in pulsar

    International Nuclear Information System (INIS)

    Sager, G.T.; Sze, D.K.; Wong, C.P.C.; Bathke, C.G.; Blanchard, J.P.; Brimer, C.; Cheng, E.T.; El-Guebaly, L.A.; Hasan, M.Z.; Najmabadi, F.; Sharafat, S.; Sviatoslavski, I.N.; Waganer, L.

    1995-01-01

    The PULSAR pulsed tokamak power plant design utilizes the outboard shield for thermal energy storage to maintain full 1000MW(e) output during the dwell period of 200s. Thermal energy resulting from direct nuclear heating is accumulated in the shield during the 7200s fusion power production phase. The maximum shield temperature may be much higher than that for the blanket because radiation damage is significantly reduced. During the dwell period, thermal power discharged from the shield and coolant temperature are simultaneously regulated by controlling the coolant mass flow rate at the shield inlet. This is facilitated by throttled coolant bypass. Design concepts using helium and lithium coolant have been developed. Two-dimensional time-dependent thermal hydraulic calculations were performed to confirm performance capabilities required of the design concepts. The results indicate that the system design and performance can accommodate uncertainties in material limits or the length of the dwell period. (orig.)

  15. Thermal and radiation loads on the first wall and divertor plates in the KTM tokamak

    International Nuclear Information System (INIS)

    Azizov, Eh.A.; Buzhinskij, O.I.; Gladush, G.G.; Darmagraj, V.V.; Priyampol'skij, I.R.; Dvorkin, N.Ya.; Lejkin, I.N.; Tazhibaeva, I.L.; Shestakov, V.P.

    2001-01-01

    The constructing of the KTM tokamak is intended for wide scale studies of behavior both inner-chamber element materials and structures (first wall, limiters, divertor, hf-antennas, etc.) under conditions approaching to the ITER-FEAT and a future thermonuclear reactors. The KTM tokamak is designed for maintain of interaction conditions of plasma-wall, plasma flows and divertor field, stimulating conditions of ITER-FEAT; and for examination of a future tokamaks' materials. In the work the thermal loads on the first wall, divertor plates are presented

  16. Community Energy Storage Thermal Analysis and Management: Cooperative Research and Development Final Report, CRADA Number CRD-11-445

    Energy Technology Data Exchange (ETDEWEB)

    Smith, Kandler A. [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2018-01-09

    The goal of this project is to create thermal solutions and models for community energy storage devices using both purpose-designed batteries and EV or PHEV batteries. Modeling will be employed to identify major factors of a device's lifetime and performance. Simultaneously, several devices will be characterized to determine their electrical and thermal performance under controlled conditions. After the factors are identified, a variety of thermal design approaches will be evaluated to improve the performance of energy storage devices. Upon completion of this project, recommendations for community energy storage device enclosures, thermal management systems, and/or battery sourcing will be made. NREL's interest is in both new and aged batteries.

  17. Working gas temperature and pressure changes for microscale thermal creep-driven flow caused by discontinuous wall temperatures

    International Nuclear Information System (INIS)

    Han, Yen-Lin

    2010-01-01

    Microscale temperature gradient-driven (thermal creep/transpiration) gas flows have attracted significant interest during the past decade. For free molecular and transitional conditions, applying temperature gradients to a flow channel's walls induces the thermal creep effect. This results in a working gas flowing through the channel from cold to hot, which is generally accompanied by a rising pressure from cold to hot in the channel. Working gas temperature and pressure distributions can vary significantly, depending on a flow channel's configuration and wall temperature distribution. Understanding working gas temperature excursions, both increases and decreases, is essential to ensure the effective use of thermal creep flows in microscale applications. In this study, the characterizations of working gas temperature variations, due to both temperature discontinuities and more gradual changes, on a variety of flow channel walls, were systematically investigated using the direct simulation Monte Carlo (DSMC) method. A micro/meso-scale pump, the Knudsen compressor, was chosen to illustrate the importance of controlling working gas temperature in thermal creep-driven flows. Gas pressure and temperature variations, through several Knudsen compressor stage configurations, were studied to determine the most advantageous flow phenomena for the efficient operation of Knudsen compressors.

  18. High-temperature molten salt thermal energy storage systems for solar applications

    Science.gov (United States)

    Petri, R. J.; Claar, T. D.; Ong, E.

    1983-01-01

    Experimental results of compatibility screening studies of 100 salt/containment/thermal conductivity enhancement (TCE) combinations for the high temperature solar thermal application range of 704 deg to 871 C (1300 to 1600 F) are presented. Nine candidate containment/HX alloy materials and two TCE materials were tested with six candidate solar thermal alkali and alkaline earth carbonate storage salts (both reagent and technical grade of each). Compatibility tests were conducted with salt encapsulated in approx. 6.0 inch x 1 inch welded containers of test material from 300 to 3000 hours. Compatibility evaluations were end application oriented, considering the potential 30 year lifetime requirement of solar thermal power plant components. Analyses were based on depth and nature of salt side corrosion of materials, containment alloy thermal aging effects, weld integrity in salt environment, air side containment oxidation, and chemical and physical analyses of the salt. A need for more reliable, and in some cases first time determined thermophysical and transport property data was also identified for molten carbonates in the 704 to 871 C temperature range. In particular, accurate melting point (mp) measurements were performed for Li2CO3 and Na2CO3 while melting point, heat of fusion, and specific heat determinations were conducted on 81.3 weight percent Na2CO3-18.7 weight percent K2CO3 and 52.2 weight percent BaCO3-47.8 weight percent Na2CO3 to support future TES system design and ultimate scale up of solar thermal energy storage (TES) subsystems.

  19. Preparation and thermal energy storage properties of paraffin/expanded graphite composite phase change material

    International Nuclear Information System (INIS)

    Zhang, Zhengguo; Zhang, Ni; Peng, Jing; Fang, Xiaoming; Gao, Xuenong; Fang, Yutang

    2012-01-01

    Highlights: ► EG was obtained by microwave irradiation to prepare the paraffin/EG composite PCM. ► Composite PCM was characterized by XRD to investigate the chemical compatibility. ► Temperature profiles of the composite PCM were obtained during thermal energy storage. -- Abstract: The paraffin/expanded graphite (EG) composite phase change material (PCM) was prepared by absorbing liquid paraffin into EG, in which paraffin was chosen as the PCM. EG was produced by microwave irradiation performed at room temperature. It was found that the EG prepared at 800 W irradiation power for 10 s exhibited the maximum sorption capacity of 92 wt% for paraffin. Scanning electron microscopy images showed that paraffin was uniformly dispersed in the pores of EG. Differential scanning calorimeter analysis indicated that the melting temperature of the composite PCM was close to that of paraffin, and its latent heat was equivalent to the calculated value based on the mass fraction of paraffin in the composite. X-ray diffraction analysis showed that the composite PCM was just a combination of paraffin with EG, and no new substance was produced. Thermal energy storage performance of the composite PCM was tested in a latent thermal energy storage (LTES) system. Transients of axial and radial temperature profiles were obtained in the LTES for the composite PCM and paraffin. The thermal energy storage charging duration for the composite PCM was reduced obviously compared to paraffin.

  20. Conceptual thermal-mechanical design of the TFTR first wall armor against neutral beam impingement

    International Nuclear Information System (INIS)

    Chi, J.W.H.; Flaherty, R.

    1976-01-01

    The Tokamak Fusion Test Reactor (TFTR) is designed to operate in a pulsed mode with relatively low duty cycles. Each pulse consists of a short plasma heat-up period, a reaction period, followed by a relatively long cooldown period. Plasma heating is accomplished by ohmic heating by a current induced change in the magnetically linked ohmic heating coils, followed by neutral beam injection for further preheat and the initiation of fusion reactions. During normal operation, the bulk of the neutral beam energy will be absorbed by the plasma, while the remainder will impinge on the vacuum vessel wall. The amount of thermal energy deposited on an unprotected wall is expected to be excessive, limiting the frequency of pulses and requiring frequent wall replacement. A faulted condition would cause penetration of an unprotected wall. As a consequence, a wall armoring (or liner) concept was developed to protect the vacuum vessel wall and to permit ease of liner replacement

  1. New materials for thermal energy storage in concentrated solar power plants

    Science.gov (United States)

    Guerreiro, Luis; Collares-Pereira, Manuel

    2016-05-01

    Solar Thermal Electricity (STE) is an important alternative to PV electricity production, not only because it is getting more cost competitive with the continuous growth in installed capacity, engineering and associated innovations, but also, because of its unique dispatch ability advantage as a result of the already well established 2-tank energy storage using molten salts (MS). In recent years, research has been performed, on direct MS systems, to which features like modularity and combinations with other (solid) thermal storage materials are considered with the goal of achieving lower investment cost. Several alternative materials and systems have been studied. In this research, storage materials were identified with thermo-physical data being presented for different rocks (e.g. quartzite), super concrete, and other appropriate solid materials. Among the new materials being proposed like rocks from old quarries, an interesting option is the incorporation of solid waste material from old mines belonging to the Iberian Pyritic Belt. These are currently handled as byproducts of past mine activity, and can potentially constitute an environmental hazard due to their chemical (metal) content. This paper presents these materials, as part of a broad study to improve the current concept of solar energy storage for STE plants, and additionally presents a potentially valuable solution for environmental protection related to re-use of mining waste.

  2. The effect of adiabatic and conducting wall boundary conditions on LES of a thermal mixing tee

    International Nuclear Information System (INIS)

    Howard, Richard J.A.; Pasutto, Thomas

    2009-01-01

    In this paper preliminary LES simulations are carried out of the FATHERINO mixing T junction experiment. In this experiment 80degC hot water enters a lateral steel pipe which has a diameter of D=0.054m, at a speed of 1.04m/s and meets 5degC cold water which enters a perpendicular steel pipe branch that also has a diameter D=0.054m but this time at a lower speed of 0.26m/s. The modelling of the steel pipe walls is tested by comparing adiabatic and 1D conducting wall boundary conditions. The numerical grid used contains approximately 440,000 hexahedral elements. The near wall refinement is not sufficient to resolve the near wall boundary layer (y + approx. = 32) and a standard logarithmic boundary condition is used. A method known as the synthetic eddy method is used to generate the turbulent flow at the pipe inlets. Three different LES models are used (Smagorinsky, dynamic Smagorinsky and wale) to resolve the subgrid turbulent motion beyond the wall grid. An additional test is carried out where no subgrid model is used with only the wall modelling being applied. The results show that the wale model generates much less resolved turbulence than the other cases and this model shows virtually no difference between the two methods of wall thermal modelling. The dynamic Smagorinsky model shows that, downstream of the mixing T, the lower wall remains at a lower temperature for longer when the adiabatic boundary condition is applied. The Smagorinsky model is found to produce the highest level of resolved temperature fluctuation. For this model the 1D thermal modelling approach increases the unsteadiness of both the velocity and temperature fields at the onset of the mixing and in the middle of the pipe downstream of the T junction. However near the lower wall the 1D thermal modelling approach tends to reduce the unsteadiness. The case with no subgrid modelling shows higher levels of turbulence kinetic energy but lower levels of temperature fluctuation than the cases with

  3. Ice Thermal Storage Systems for LWR Supplemental Cooling and Peak Power Shifting

    Energy Technology Data Exchange (ETDEWEB)

    Haihua Zhao; Hongbin Zhang; Phil Sharpe; Blaise Hamanaka; Wei Yan; WoonSeong Jeong

    2010-06-01

    Availability of enough cooling water has been one of the major issues for the nuclear power plant site selection. Cooling water issues have frequently disrupted the normal operation at some nuclear power plants during heat waves and long draught. The issues become more severe due to the new round of nuclear power expansion and global warming. During hot summer days, cooling water leaving a power plant may become too hot to threaten aquatic life so that environmental regulations may force the plant to reduce power output or even temporarily to be shutdown. For new nuclear power plants to be built at areas without enough cooling water, dry cooling can be used to remove waste heat directly into the atmosphere. However, dry cooling will result in much lower thermal efficiency when the weather is hot. One potential solution for the above mentioned issues is to use ice thermal storage systems (ITS) that reduce cooling water requirements and boost the plant’s thermal efficiency in hot hours. ITS uses cheap off-peak electricity to make ice and uses those ice for supplemental cooling during peak demand time. ITS is suitable for supplemental cooling storage due to its very high energy storage density. ITS also provides a way to shift large amount of electricity from off peak time to peak time. Some gas turbine plants already use ITS to increase thermal efficiency during peak hours in summer. ITSs have also been widely used for building cooling to save energy cost. Among three cooling methods for LWR applications: once-through, wet cooling tower, and dry cooling tower, once-through cooling plants near a large water body like an ocean or a large lake and wet cooling plants can maintain the designed turbine backpressure (or condensation temperature) during 99% of the time; therefore, adding ITS to those plants will not generate large benefits. For once-through cooling plants near a limited water body like a river or a small lake, adding ITS can bring significant economic

  4. Hydrogen storage in single-wall carbon nano-tubes by means of laser excitation

    International Nuclear Information System (INIS)

    Oksengorn, B.

    2010-01-01

    A new mode for hydrogen adsorption and storage in single-wall carbon nano-tubes is used, on the basis of laser excitation. Remember that this method has been useful to obtain, in the case of the fullerene C 60 , many complex C 60 -atoms or C 60 -molecules, where atoms or molecular particles are trapped inside the C 60 -molecules. We think this method might be important to store many hydrogen molecules inside carbon nano-tubes. (author)

  5. Preparation, thermal properties and thermal reliabilities of microencapsulated n-octadecane with acrylic-based polymer shells for thermal energy storage

    Energy Technology Data Exchange (ETDEWEB)

    Qiu, Xiaolin [Advanced Materials Institute and Clearer Production Key Laboratory, Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055 (China); Key Laboratory of Advanced Materials, Department of Materials Science and Engineering, Tsinghua University, Haidian District, Beijing 100084 (China); Song, Guolin; Chu, Xiaodong; Li, Xuezhu [Advanced Materials Institute and Clearer Production Key Laboratory, Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055 (China); Tang, Guoyi, E-mail: tanggy@tsinghua.edu.cn [Advanced Materials Institute and Clearer Production Key Laboratory, Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055 (China); Key Laboratory of Advanced Materials, Department of Materials Science and Engineering, Tsinghua University, Haidian District, Beijing 100084 (China)

    2013-01-10

    Highlights: Black-Right-Pointing-Pointer n-Octadecane was encapsulated by p(butyl methacrylate) (PBMA) and p(butyl acrylate). Black-Right-Pointing-Pointer Microcapsules using divinylbenzene as crosslinking agent have better quality. Black-Right-Pointing-Pointer Microcapsule with butyl methacrylate-divinylbenzene has highest latent heat. Black-Right-Pointing-Pointer Microcapsule with butyl methacrylate-divinylbenzene has greatest thermal stability. Black-Right-Pointing-Pointer Phase change temperatures and enthalpies of the microcapsules varied little after thermal cycle. - Abstract: Microencapsulation of n-octadecane with crosslinked p(butyl methacrylate) (PBMA) and p(butyl acrylate) (PBA) as shells for thermal energy storage was carried out by a suspension-like polymerization. Divinylbenzene (DVB) and pentaerythritol triacrylate (PETA) were employed as crosslinking agents. The surface morphologies of the microencapsulated phase change materials (microPCMs) were studied by scanning electron microscopy (SEM). Thermal properties, thermal reliabilities and thermal stabilities of the as-prepared microPCMs were investigated by differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). The microPCMs prepared by using DVB exhibit greater heat capacities and higher thermal stabilities compared with those prepared by using PETA. The thermal resistant temperature of the microPCM with BMA-DVB polymer was up to 248 Degree-Sign C. The phase change temperatures and latent heats of all the as-prepared microcapsules varied little after 1000 thermal cycles.

  6. Fuel Assemblies Thermal Analysis in the New Spent Fuel Storage Facility at Inshass Site

    International Nuclear Information System (INIS)

    Khattab, M.; Mariy, Ahmed

    1999-01-01

    New Wet Storage Facility (NSF) is constructed at Inshass site to solve the problem of spent fuel storage capacity of ETRR-1 reactor . The Engineering Safety Heat Transfer Features t hat characterize the new facility are presented. Thermal analysis including different scenarios of pool heat load and safety limits are discussed . Cladding temperature limit during handling and storage process are specified for safe transfer of fuel

  7. Mechanical Reinforcement, Shapestabilization and Thermal Improvement of Phase-Change Energy Storage Materials Using Graphene Oxide Aerogel

    Science.gov (United States)

    Schuman, Yue Xu

    Paraffin is known as a good energy storage phase change material (PCM) because of its high energy storage capacity and low cost. However, the leakage of liquid paraffin beyond its melting point and its low thermal conductivity hinder applications of paraffin in energy storage systems. Recently, nanomaterials have been used to create PCM composites in order to enhance their thermal properties while shape stabilizing the PCMs. However, fundamental studies on the material structures and mechanical behavior of the thermally enhanced PCM composites are limited especially at the nanoscale. In this study, we developed a PCM composite using graphene oxide aerogel (GOxA) as the reinforcing 3D network. The GOxA functions thermally as a heat transfer path and mechanically as a nanofiller to reinforce the PCM matrix. We characterized the morphology, the crystal and molecular structures as well as the multiscale mechanical and thermal behavior of the GOxA-PCM composite to evaluate the role of GOxA in the PCM composite. The molecular and diffraction characterizations imply that the GOxA network may affect the paraffin's crystallization, potentially forming an interfacial phase at the surfaces of GOxA. Furthermore, the mechanical properties were studied using nanoindentation at the nano/microscale and a digital durometer at the macroscale from 25degree C to 80 degree C. The mechanical characterizations show that the GOxA-PCM composite is 3 7x harder than pure paraffin and maintains significant strength even above paraffin's melting point due to the support from the GoxA. Moreover, the composite is much less strain-rate sensitive than paraffin. The reinforcement via GOxA is much beyond the prediction by the rule of mixture, implying a strong GOxA-paraffin interfacial bonding. Finally, a thermal scanning microscopy (SThM) along with AFM was used to study the thermal properties at microscale. AFM and thermal images indicate that GOxA-PCM has a better thermal conductivity. The latent

  8. Application of elastic wave dispersion relations to estimate thermal properties of nanoscale wires and tubes of varying wall thickness and diameter

    International Nuclear Information System (INIS)

    Bifano, Michael F P; Kaul, Pankaj B; Prakash, Vikas

    2010-01-01

    This paper reports dependency of specific heat and ballistic thermal conductance on cross-sectional geometry (tube versus rod) and size (i.e., diameter and wall thickness), in free-standing isotropic non-metallic crystalline nanostructures. The analysis is performed using dispersion relations found by numerically solving the Pochhammer-Chree frequency equation for a tube. Estimates for the allowable phonon dispersion relations within the crystal lattice are obtained by modifying the elastic acoustic dispersion relations so as to account for the discrete nature of the material's crystal lattice. These phonon dispersion relations are then used to evaluate the specific heat and ballistic thermal conductance in the nanostructures as a function of the nanostructure geometry and size. Two major results are revealed in the analysis: increasing the outer diameter of a nanotube while keeping the ratio of the inner to outer tube radius (γ) fixed increases the total number of available phonon modes capable of thermal population. Secondly, decreasing the wall thickness of a nanotube (i.e., increasing γ) while keeping its outer diameter fixed, results in a drastic decrease in the available phonon mode density and a reduction in the frequency of the longitudinal and flexural acoustic phonon modes in the nanostructure. The dependency of the nanostructure's specific heat on temperature indicates 1D, 2D, and 3D geometric phonon confinement regimes. Transition temperatures for each phonon confinement regime are shown to depend on both the nanostructure's wall thickness and outer radius. Compared to nanowires (γ = 0), the frequency reduction of acoustic phonon modes in thinner walled nanotubes (γ = 0.96) is shown to elevate the ballistic thermal conductance of the thin-walled nanotube between 0.2 and 150 K. At 20 K, the ballistic thermal conductance of the thin-walled nanotube (γ = 0.96) becomes 300% greater than that of a solid nanowire. For temperatures above 150 K, the trend

  9. Experimental and numerical study of latent heat thermal energy storage systems assisted by heat pipes for concentrated solar power application

    Science.gov (United States)

    Tiari, Saeed

    A desirable feature of concentrated solar power (CSP) with integrated thermal energy storage (TES) unit is to provide electricity in a dispatchable manner during cloud transient and non-daylight hours. Latent heat thermal energy storage (LHTES) offers many advantages such as higher energy storage density, wider range of operating temperature and nearly isothermal heat transfer relative to sensible heat thermal energy storage (SHTES), which is the current standard for trough and tower CSP systems. Despite the advantages mentioned above, LHTES systems performance is often limited by low thermal conductivity of commonly used, low cost phase change materials (PCMs). Research and development of passive heat transfer devices, such as heat pipes (HPs) to enhance the heat transfer in the PCM has received considerable attention. Due to its high effective thermal conductivity, heat pipe can transport large amounts of heat with relatively small temperature difference. The objective of this research is to study the charging and discharging processes of heat pipe-assisted LHTES systems using computational fluid dynamics (CFD) and experimental testing to develop a method for more efficient energy storage system design. The results revealed that the heat pipe network configurations and the quantities of heat pipes integrated in a thermal energy storage system have a profound effect on the thermal response of the system. The optimal placement of heat pipes in the system can significantly enhance the thermal performance. It was also found that the inclusion of natural convection heat transfer in the CFD simulation of the system is necessary to have a realistic prediction of a latent heat thermal storage system performance. In addition, the effects of geometrical features and quantity of fins attached to the HPs have been studied.

  10. Thermal diffusivity measurement of erythritol and numerical analysis of heat storage performance on a fin-type heat exchanger

    International Nuclear Information System (INIS)

    Zamengo, Massimiliano; Funada, Tomohiro; Morikawa, Junko

    2017-01-01

    Highlights: • Thermal diffusivity of Erythritol was measured by temperature wave method. • Thermal diffusivity was measured in function of temperature and during phase change. • Database of temperature-dependent thermal properties is used for numerical analysis. • Heat transfer and heat storage were analyzed in a fin-type heat exchanger. • Use of temperature-dependent properties in calculations lead to longer melting time. - Abstract: Temperature dependency of thermal diffusivity of erythritol was measured by temperature wave analysis (TWA) method. This modulating technique allowed measuring thermal diffusivity continuously, even during the phase transition solid-liquid. Together with specific heat capacity and specific enthalpy measured by differential scanning calorimetry, the values of measured properties were utilized in a bi-dimensional numerical model for analysis of heat transfer and heat storage performance. The geometry of the model is representative of a cross section of a fin-type heat exchanger, in which erythritol is filling the interspaces between fins. Time-dependent temperature change and heat storage performance were analyzed by considering the variation of thermophysical properties as a function of temperature. The numerical method can be utilized for a fast parametric analysis of heat transfer and heat storage performance into heat storage systems of phase-change materials and composites.

  11. Influence of light-weight masonry mortar on the thermal insulation of walling made from hollow blocks

    Energy Technology Data Exchange (ETDEWEB)

    Kupke, C; Schuele, M

    1984-10-01

    The thermal conductivity equivalent of hollow-block masonry with different types of mortar is calculated for ten different types of blocks as a function of the thermal conductivity of the brick material. A measure is derived for determining the improved thermal conductivity of hollow-block masonry with light mortar as compared to walls with normal mortar. The findings supplement the findings already obtained for solid bricks.

  12. Thermal transfer performance of a spherical encapsulated PEG 6000-based composite for thermal energy storage

    Czech Academy of Sciences Publication Activity Database

    Anghel, E.M.; Pavel, P.M.; Constantinescu, M.; Petrescu, S.; Atkinson, I.; Buixaderas, Elena

    2017-01-01

    Roč. 208, Sep (2017), s. 1222-1231 ISSN 0306-2619 Grant - others:AV ČR(CZ) AR-17-02 Program:Bilaterální spolupráce Institutional support: RVO:68378271 Keywords : phase change materials * thermal energy storage * modeling Subject RIV: CF - Physical ; Theoretical Chemistry OBOR OECD: Physical chemistry Impact factor: 7.182, year: 2016

  13. Thermodynamic model of a thermal storage air conditioning system with dynamic behavior

    Energy Technology Data Exchange (ETDEWEB)

    Fleming, E; Wen, SY; Shi, L; da Silva, AK

    2013-12-01

    A thermodynamic model was developed to predict transient behavior of a thermal storage system, using phase change materials (PCMs), for a novel electric vehicle climate conditioning application. The main objectives of the paper are to consider the system's dynamic behavior, such as a dynamic air flow rate into the vehicle's cabin, and to characterize the transient heat transfer process between the thermal storage unit and the vehicle's cabin, while still maintaining accurate solution to the complex phase change heat transfer. The system studied consists of a heat transfer fluid circulating between either of the on-board hot and cold thermal storage units, which we refer to as thermal batteries, and a liquid-air heat exchanger that provides heat exchange with the incoming air to the vehicle cabin. Each thermal battery is a shell-and-tube configuration where a heat transfer fluid flows through parallel tubes, which are surrounded by PCM within a larger shell. The system model incorporates computationally inexpensive semianalytic solution to the conjugated laminar forced convection and phase change problem within the battery and accounts for airside heat exchange using the Number of Transfer Units (NTUs) method for the liquid-air heat exchanger. Using this approach, we are able to obtain an accurate solution to the complex heat transfer problem within the battery while also incorporating the impact of the airside heat transfer on the overall system performance. The implemented model was benchmarked against a numerical study for a melting process and against full system experimental data for solidification using paraffin wax as the PCM. Through modeling, we demonstrate the importance of capturing the airside heat exchange impact on system performance, and we investigate system response to dynamic operating conditions, e.g., air recirculation. (C) 2013 Elsevier Ltd. All rights reserved.

  14. Carbon nanotube/paraffin/montmorillonite composite phase change material for thermal energy storage.

    Science.gov (United States)

    Li, Min; Guo, Qiangang; Nutt, Steven

    2017-04-01

    A composite phase change material (PCM) comprised of organic montmorillonite (OMMT)/paraffin/grafted multi-walled nanotube (MWNT) is synthesized via ultrasonic dispersion and liquid intercalation. The microstructure of the composite PCM has been characterized to determine the phase distribution, and thermal properties (latent heat and thermal conductivity) have been measured by differential scanning calorimetry (DSC) and a thermal constant analyzer. The results show that paraffin molecules are intercalated in the montmorillonite layers and the grafted MWNTs are dispersed in the montmorillonite layers. The latent heat is 47.1 J/g, and the thermal conductivity of the OMMT/paraffin/grafted MWNT composites is 34% higher than that of the OMMT/paraffin composites and 65% higher than that of paraffin.

  15. Effect of multiple phase change materials (PCMs) slab configurations on thermal energy storage

    International Nuclear Information System (INIS)

    Shaikh, Shadab; Lafdi, Khalid

    2006-01-01

    The present work involves the use of a two dimensional control volume based numerical method to conduct a study of a combined convection-diffusion phase change heat transfer process in varied configurations of composite PCM slabs. Simulations were conducted to investigate the impact of using different configurations of multiple PCM slabs arrangements with different melting temperatures, thermophysical properties and varied sets of boundary conditions on the total energy stored as compared to using a single PCM slab. The degree of enhancement of the energy storage has been shown in terms of the total energy stored rate. The numerical results from the parametric study indicated that the total energy charged rate can be significantly enhanced by using composite PCMs as compared to the single PCM. This enhancement in the energy storage can be of great importance to improve the thermal performance of latent thermal storage systems

  16. Advanced materials for solid state hydrogen storage: “Thermal engineering issues”

    International Nuclear Information System (INIS)

    Srinivasa Murthy, S.; Anil Kumar, E.

    2014-01-01

    Hydrogen has been widely recognized as the “Energy Carrier” of the future. Efficient, reliable, economical and safe storage and delivery of hydrogen form important aspects in achieving success of the “Hydrogen Economy”. Gravimetric and volumetric storage capacities become important when one considers portable and mobile applications of hydrogen. In the case of solid state hydrogen storage, the gas is reversibly embedded (by physisorption and/or chemisorption) in a solid matrix. A wide variety of materials such as intermetallics, physisorbents, complex hydrides/alanates, metal organic frameworks, etc. have been investigated as possible storage media. This paper discusses the feasibility of lithium– and sodium–aluminum hydrides with emphasis on their thermodynamic and thermo-physical properties. Drawbacks such as poor heat transfer characteristics and poor kinetics demand special attention to the thermal design of solid state storage devices. - Highlights: • Advanced materials suitable for solid state hydrogen storage are discussed. • Issues related to thermodynamic and thermo-physical properties of hydriding materials are brought out. • Hydriding and dehydriding behavior including sorption kinetics of complex hydrides with emphasis on alanates are explained

  17. More with thermal energy storage. Report 2. Literature survey. Overview of knowledge and research questions with regard to thermal energy storage. Final report; Meer met bodemenergie. Rapport 2. Literatuuronderzoek. Overzicht van kennis en onderzoeksvragen rondom bodemenergie. Eindrapport

    Energy Technology Data Exchange (ETDEWEB)

    Lieten, S.; De Vries, E. [Bioclear, Groningen (Netherlands); Van Baaren, E.; Bakr, M.; Oude Essink, G.; Hartog, N.; Meinderstma, W.; Van Nieuwkerk, E.; Van Oostrom, N.; Woning, M. [Deltares, Delft (Netherlands); Drijver, B.; Krajenbrink, H.; Mathijssen, H.; Wennekes, R. [IF Technology, Arnhem (Netherlands)

    2012-03-30

    The project More With Thermal Energy Storage (MMB, abbreviated in Dutch) focuses on knowledge gaps and potential opportunities regarding open systems. The main questions to be answered are: (1) What effects (hydrological, thermal, microbiological and chemical) occur in the soil system by application of thermal energy storage; (2) Which technical options are available for a sustainable integration of thermal energy storage in the water and energy chain?; (3) Is it possible to achieve multiple objectives by using smart combinations? The project is organized in different work packages. In work package 2, the effects of individual and collective thermal energy storage storage systems on subsoils and the environment are determined. In work package 3 the opportunities for thermal energy storage and soil remediation are examined, while in work package 4 the focus is on new sustainable combinations of heat and cold storage. Work package 1 is the umbrella part where communication and policy of and participation in MMB are the main subjects. The aim of this literature survey is to search for knowledge that is available worldwide on the effects of heat and cold storage and the possibilities to combine this technology with controlling contaminants in soil and groundwater [Dutch] Het project Meer Met Bodemenergie (MMB) richt zich op het invullen van kennisleemtes en mogelijke kansen ten aanzien van open systemen. De belangrijkste vragen waarop het onderzoeksprogramma MMB antwoord geeft zijn: (1) Welke effecten (hydrologisch, thermisch, microbiologisch en chemisch) treden op in het bodemsysteem bij toepassing van bodemenergie?; (2) Welke technische mogelijkheden zijn er voor het duurzaam inpassen van bodem-energie in de water- en energieketen?; (3) Is het mogelijk om meerdere doelstellingen tegelijk te verwezenlijken door slimme combinaties te maken? Het project is ingericht met verschillende werkpakketten. In werkpakket 2 worden de effecten van individuele en collectieve

  18. Solar cookers with and without thermal storage - A review

    International Nuclear Information System (INIS)

    Muthusivagami, R.M.; Velraj, R.; Sethumadhavan, R.

    2010-01-01

    The continuous increase in the level of green house gas emissions and the increase in fuel prices are the main driving forces behind efforts to more effectively utilize various sources of renewable energy. In many parts of the world, direct solar radiation is considered to be one of the most prospective sources of energy. Among the different energy end uses, energy for cooking is one of the basic and dominant end uses in developing countries. Energy requirement for cooking accounts for 36% of total primary energy consumption in India. Hence, there is a critical need for the development of alternative, appropriate, affordable mode of cooking for use in developing countries. However, the large scale utilization of this form of energy is possible only if the effective technology for its storage can be developed with acceptable capital and running costs. Thermal energy storage is essential whenever there is a mismatch between the supply and consumption of energy. Latent heat storage in a phase change material is very attractive because of its high storage density with small temperature swing. The choice of PCM plays an important role in addition to heat transfer mechanism in the PCM. In this present work a review has been made to study all the research and development work carried out in the field of solar cooker in particular the storage type solar cookers. A novel concept of PCM-based storage type solar cooker is also presented which is under experimental investigation. (author)

  19. Preparation of shape-stabilized co-crystallized poly (ethylene glycol) composites as thermal energy storage materials

    International Nuclear Information System (INIS)

    Qian, Yong; Wei, Ping; Jiang, Pingkai; Li, Zhi; Yan, Yonggang; Ji, Kejian; Deng, Weihua

    2013-01-01

    Highlights: • Shape-stabilized PEG composites were prepared by sol–gel process. • The increased energy storage ability of composite was from cocrystallization effect. • Diammonium phosphate improved flame retardancy properties of PEG composite. • PEG composites had potential to be used as thermal energy storage materials. - Abstract: Shape-stabilized co-crystallized poly (ethylene glycol) (PEG) composites were prepared by sol–gel process. Tetraethoxysilane was utilized as supporting matrix precursor. The crystallization property as well as thermal energy storage properties of PEG was influenced by silica network. The combination of PEG 2k and PEG 10k with suitable ratio (3:1 by weight) led to synergistically increased fusion enthalpy attributed to cocrystallization effect. Furthermore, halogen-free flame retarded PEG composites were obtained using diammonium phosphate as flame retardant. With suitable composition, the latent heat value of flame retarded PEG composite was 96.7 kJ/kg accompanied with good thermal stability and improved flame retardancy properties. Fourier transform infrared spectrum (FT-IR), X-ray diffraction (XRD), polarized optical microscope (POM) and scanning electron microscope (SEM) were used to characterize the structure of PEG composites. Thermal stability properties of PEG composites were investigated by thermogravimetric analyzer (TGA). Char residue obtained from muffle furnace of PEG composites was analyzed by SEM and FT-IR. Flame retardancy properties of PEG composites were estimated by pyrolysis combustion flow calorimeter. Results showed that it was potential for shape-stabilized halogen-free flame retarded PEG composite to be applied in thermal energy storage field

  20. Preparation and Characterization of Modified Montmorillonite/Paraffin Phase Change Microcapsules for Energy Storage

    Directory of Open Access Journals (Sweden)

    LIN Sen

    2017-03-01

    Full Text Available The phase change microcapsules of modified montmorillonite/paraffin were prepared by Pickering emulsion method. Analytic techniques of optical microscopy, scanning electron microscopy(SEM, infrared spectroscopy(FTIR, differential scanning calorimetry(DSC and thermogravimetry(TG were utilized for characterizing chemical structure, morphology and thermal properties. Results show that modified montmorillonite as a new type wall material has excellent performance for protecting core material of paraffin. FTIR spectra of phase change of modified montmorillonite/paraffin microcapsules shows that their characteristic peaks match with corresponding peaks of pure paraffin and modified montmorillonite. DSC results indicate that modified montmorillonite/paraffin microcapsules have similar solid-liquid phase change temperature with pure paraffin. The phase transition enthalpy values of microcapsules with paraffin contents varying from 55% to 80% are 110.5-147.2J/g, indicating that microcapsules have excellent thermal storage performance and the phase change properties can be adjusted by changing contents of paraffin. TG results confirm that modified montmorillonite/paraffin microcapsules have outstanding thermal stability. The presented study indicates that modified montmorillonite is a suitable wall material for preparing paraffin microcapsule. Modified montmorillonite/paraffin microcapsules have advantages of low cost and high performance with a great application potential in the field of thermal storage.

  1. Experimental analysis of a low cost phase change material emulsion for its use as thermal storage system

    International Nuclear Information System (INIS)

    Delgado, Mónica; Lázaro, Ana; Mazo, Javier; Peñalosa, Conchita; Dolado, Pablo; Zalba, Belén

    2015-01-01

    Highlights: • A low cost PCM emulsion has been analyzed as thermal energy storage system. • Its thermophysical and rheological properties have been determined. • The system shows advantages in terms of energy density and heat transfer rate. • The PCM emulsion system has been compared to other thermal energy storage systems. - Abstract: A 46 l commercial tank with a helical coil heat exchanger and containing a low cost phase change material emulsion has been experimentally analyzed as a thermal energy storage system in terms of volumetric energy density and heat transfer rate, for its subsequent comparison with other thermal energy storage systems. This phase change material emulsion shows a phase change temperature range between 30 and 50 °C, its solids content is about 60% with an average particle size of 1 μm. The low cost phase change material emulsion shows a thermal storage capacity by mass 50% higher than water and an increase in viscosity up to 2–5 orders of magnitude. The results have shown that the global heat transfer coefficient of the phase change material emulsion tank is around 2–6 times higher than for conventional latent systems previously analyzed in literature, although 5 times lower than if it contains water. The phase change material emulsion tank presents an energy density 34% higher than the water tank, which makes it a promising solution. Measures to improve its performance are also studied in this work.

  2. Thermal properties of a novel nanoencapsulated phase change material for thermal energy storage

    Energy Technology Data Exchange (ETDEWEB)

    Fuensanta, Mónica, E-mail: monica.fuensanta@aidico.es [AIDICO, Technological Institute of Construction, Camí de Castella, 4, 03660 Novelda, Alicante (Spain); Paiphansiri, Umaporn [Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz (Germany); Romero-Sánchez, María Dolores, E-mail: md.romero@aidico.es [AIDICO, Technological Institute of Construction, Camí de Castella, 4, 03660 Novelda, Alicante (Spain); Guillem, Celia; López-Buendía, Ángel M. [AIDICO, Technological Institute of Construction, Camí de Castella, 4, 03660 Novelda, Alicante (Spain); Landfester, Katharina [Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz (Germany)

    2013-08-10

    Highlights: • A paraffin wax RT80 was encapsulated in styrene–butyl acrylate copolymer as polymer shell using miniemulsion polymerization process to obtain a novel nanoencapsulated PCM with 80 °C melting temperature. • Nano-PCMs have high compact structure, spherical morphology and thermal stability. • The nano-PCMs have potential applications as thermal energy storage materials. - Abstract: A novel nanoencapsulation of a paraffine type phase change material, RT80, in a styrene–butyl acrylate copolymer shell using the miniemulsion polymerization process was carried out. General characteristics of the RT80 nanoparticles in terms of thermal properties, morphology, chemical composition and particle size distribution were characterized by Differential Scanning Calorimetry (DSC), Thermal Gravimetric Analysis (TGA), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), Fourier Transform Infrared Spectroscopy (FT-IR) and Dynamic Light Scattering (DLS). The influence of different monomers (styrene, butyl acrylate) and the surfactant/paraffin mass ratios on nanoparticles properties such as thermal capacity, particle size and morphology were systematically investigated. In all cases studied, encapsulation efficiency was close to 80 wt% with a particle size distribution between 52 and 112 nm and regular spherical shape and uniform structure. The amount of encapsulated paraffin achieved was comprised between 8 and 20%. Melting and crystallization heats were found to be approximately 5–25 J g{sup −1}, mainly depending on surfactant/paraffin mass ratio. Melting temperature of RT80 nanoparticles slightly decreased (1–7 °C) respect to the raw RT80. In addition, the encapsulated RT80 nanoparticles show thermal stability even after 200 thermal (heat-cooling) cycles.

  3. Thermal properties of a novel nanoencapsulated phase change material for thermal energy storage

    International Nuclear Information System (INIS)

    Fuensanta, Mónica; Paiphansiri, Umaporn; Romero-Sánchez, María Dolores; Guillem, Celia; López-Buendía, Ángel M.; Landfester, Katharina

    2013-01-01

    Highlights: • A paraffin wax RT80 was encapsulated in styrene–butyl acrylate copolymer as polymer shell using miniemulsion polymerization process to obtain a novel nanoencapsulated PCM with 80 °C melting temperature. • Nano-PCMs have high compact structure, spherical morphology and thermal stability. • The nano-PCMs have potential applications as thermal energy storage materials. - Abstract: A novel nanoencapsulation of a paraffine type phase change material, RT80, in a styrene–butyl acrylate copolymer shell using the miniemulsion polymerization process was carried out. General characteristics of the RT80 nanoparticles in terms of thermal properties, morphology, chemical composition and particle size distribution were characterized by Differential Scanning Calorimetry (DSC), Thermal Gravimetric Analysis (TGA), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), Fourier Transform Infrared Spectroscopy (FT-IR) and Dynamic Light Scattering (DLS). The influence of different monomers (styrene, butyl acrylate) and the surfactant/paraffin mass ratios on nanoparticles properties such as thermal capacity, particle size and morphology were systematically investigated. In all cases studied, encapsulation efficiency was close to 80 wt% with a particle size distribution between 52 and 112 nm and regular spherical shape and uniform structure. The amount of encapsulated paraffin achieved was comprised between 8 and 20%. Melting and crystallization heats were found to be approximately 5–25 J g −1 , mainly depending on surfactant/paraffin mass ratio. Melting temperature of RT80 nanoparticles slightly decreased (1–7 °C) respect to the raw RT80. In addition, the encapsulated RT80 nanoparticles show thermal stability even after 200 thermal (heat-cooling) cycles

  4. Fatty acid esters-based composite phase change materials for thermal energy storage in buildings

    International Nuclear Information System (INIS)

    Sarı, Ahmet; Karaipekli, Ali

    2012-01-01

    In this study, fatty acid esters-based composite phase change materials (PCMs) for thermal energy storage were prepared by blending erythritol tetrapalmitate (ETP) and erythritol tetrastearate (ETS) with diatomite and expanded perlite (EP). The maximum incorporation percentage for ETP and ETS into diatomite and EP was found to be 57 wt% and 62 wt%, respectively without melted PCM seepage from the composites. The morphologies and compatibilities of the composite PCMs were structurally characterized using scanning electron microscope (SEM) and Fourier transformation infrared (FT–IR) analysis techniques. Thermal energy storage properties of the composite PCMs were determined by differential scanning calorimetry (DSC) analysis. The DSC analyses results indicated that the composite PCMs were good candidates for building applications in terms of their large latent heat values and suitable phase change temperatures. The thermal cycling test including 1000 melting and freezing cycling showed that composite PCMs had good thermal reliability and chemical stability. TG analysis revealed that the composite PCMs had good thermal durability above their working temperature ranges. Moreover, in order to improve the thermal conductivity of the composite PCMs, the expanded graphite (EG) was added to them at different mass fractions (2%, 5%, and 10%). The best results were obtained for the composite PCMs including 5wt% EG content in terms of the increase in thermal conductivity values and the decrease amount in latent heat capacity. The improvement in thermal conductivity values of ETP/Diatomite, ETS/Diatomite, ETP/EP and ETS/EP were found to be about 68%, 57%, 73% and 75%, respectively. Highlights: ► Fatty acid esters-based composite PCMs were prepared by blending ETP and ETS with diatomite and expanded perlite. ► The composite PCMs were characterized by using SEM, FT–IR, DSC and TG analysis methods. ► The DSC results indicated that the composites PCMs had good thermal

  5. Heat exchange studies on coconut oil cells as thermal energy storage for room thermal conditioning

    Science.gov (United States)

    Sutjahja, I. M.; Putri, Widya A.; Fahmi, Z.; Wonorahardjo, S.; Kurnia, D.

    2017-07-01

    As reported by many thermal environment experts, room air conditioning might be controlled by thermal mass system. In this paper we discuss the performance of coconut oil cells as room thermal energy storage. The heat exchange mechanism of coconut oil (CO) which is one of potential organic Phase Change Material (PCM) is studied based on the results of temperature measurements in the perimeter and core parts of cells. We found that the heat exchange performance, i.e. heat absorption and heat release processes of CO cells are dominated by heat conduction in the sensible solid from the higher temperature perimeter part to the lower temperature core part and heat convection during the solid-liquid phase transition and sensible liquid phase. The capability of heat absorption as measured by the reduction of air temperature is not influenced by CO cell size. Besides that, the application of CO as the thermal mass has to be accompanied by air circulation to get the cool sensation of the room’s occupants.

  6. Form-stable paraffin/high density polyethylene composites as solid-liquid phase change material for thermal energy storage: preparation and thermal properties

    International Nuclear Information System (INIS)

    Sari, Ahmet

    2004-01-01

    This paper deals with the preparation of paraffin/high density polyethylene (HDPE) composites as form-stable, solid-liquid phase change material (PCM) for thermal energy storage and with determination of their thermal properties. In such a composite, the paraffin (P) serves as a latent heat storage material and the HDPE acts as a supporting material, which prevents leakage of the melted paraffin because of providing structural strength. Therefore, it is named form-stable composite PCM. In this study, two kinds of paraffins with melting temperatures of 42-44 deg. C (type P1) and 56-58 deg. C (type P2) and latent heats of 192.8 and 212.4 J g -1 were used. The maximum weight percentage for both paraffin types in the PCM composites without any seepage of the paraffin in the melted state were found as high as 77%. It is observed that the paraffin is dispersed into the network of the solid HDPE by investigation of the structure of the composite PCMs using a scanning electronic microscope (SEM). The melting temperatures and latent heats of the form-stable P1/HDPE and P2/HDPE composite PCMs were determined as 37.8 and 55.7 deg. C, and 147.6 and 162.2 J g -1 , respectively, by the technique of differential scanning calorimetry (DSC). Furthermore, to improve the thermal conductivity of the form-stable P/HDPE composite PCMs, expanded and exfoliated graphite (EG) by heat treatment was added to the samples in the ratio of 3 wt.%. Thereby, the thermal conductivity was increased about 14% for the form-stable P1/HDPE and about 24% for the P2/HDPE composite PCMs. Based on the results, it is concluded that the prepared form-stable P/HDPE blends as composite type PCM have great potential for thermal energy storage applications in terms of their satisfactory thermal properties and improved thermal conductivity. Furthermore, these composite PCMs added with EG can be considered cost effective latent heat storage materials since they do not require encapsulation and extra cost to enhance

  7. Thermal Mode of Tanks for Storage Fuel of Thermal Power Plants and Boiler with the Influence of Engineering Facilities in the Area of their Placement

    Science.gov (United States)

    Polovnikov, V. Yu.; Makhsutbek, F. T.; Ozhikenova, Zh. F.

    2016-02-01

    This paper describes the numerical modeling of heat transfer in the area placing of the tank for storage fuel of thermal power plant and boiler with the influence of engineering construction. We have established that the presence of engineering structures in the area of placing of the tank for storage fuel of thermal power plant and boiler have little effect on the change of heat loss.

  8. Numerical study for enhancing the thermal conductivity of phase change material (PCM) storage using high thermal conductivity porous matrix

    International Nuclear Information System (INIS)

    Mesalhy, Osama; Lafdi, Khalid; Elgafy, Ahmed; Bowman, Keith

    2005-01-01

    In this paper, the melting process inside an irregular geometry filled with high thermal conductivity porous matrix saturated with phase change material PCM is investigated numerically. The numerical model is resting on solving the volume averaged conservation equations for mass, momentum and energy with phase change (melting) in the porous medium. The convection motion of the liquid phase inside the porous matrix is solved considering the Darcy, Brinkman and Forchiemer effects. A local thermal non-equilibrium assumption is considered due to the large difference in thermal properties between the solid matrix and PCM by applying a two energy equation model. The numerical code shows good agreement for pure PCM melting with another published numerical work. Through this study it is found that the presence of the porous matrix has a great effect on the heat transfer and melting rate of the PCM energy storage. Decreasing the porosity of the matrix increases the melting rate, but it also damps the convection motion. It is also found that the best technique to enhance the response of the PCM storage is to use a solid matrix with high porosity and high thermal conductivity

  9. Quantitative study of bundle size effect on thermal conductivity of single-walled carbon nanotubes

    Science.gov (United States)

    Feng, Ya; Inoue, Taiki; An, Hua; Xiang, Rong; Chiashi, Shohei; Maruyama, Shigeo

    2018-05-01

    Compared with isolated single-walled carbon nanotubes (SWNTs), thermal conductivity is greatly impeded in SWNT bundles; however, the measurement of the bundle size effect is difficult. In this study, the number of SWNTs in a bundle was determined based on the transferred horizontally aligned SWNTs on a suspended micro-thermometer to quantitatively study the effect of the bundle size on thermal conductivity. Increasing the bundle size significantly degraded the thermal conductivity. For isolated SWNTs, thermal conductivity was approximately 5000 ± 1000 W m-1 K-1 at room temperature, three times larger than that of the four-SWNT bundle. The logarithmical deterioration of thermal conductivity resulting from the increased bundle size can be attributed to the increased scattering rate with neighboring SWNTs based on the kinetic theory.

  10. Thermally responsive polymer electrolytes for inherently safe electrochemical energy storage

    Science.gov (United States)

    Kelly, Jesse C.

    Electrochemical double layer capacitors (EDLCs), supercapacitors and Li-ion batteries have emerged as premier candidates to meet the rising demands in energy storage; however, such systems are limited by thermal hazards, thermal runaway, fires and explosions, all of which become increasingly more dangerous in large-format devices. To prevent such scenarios, thermally-responsive polymer electrolytes (RPEs) that alter properties in electrochemical energy storage devices were designed and tested. These RPEs will be used to limit or halt device operation when temperatures increase beyond a predetermined threshold, therefore limiting further heating. The development of these responsive systems will offer an inherent safety mechanism in electrochemical energy storage devices, while preserving the performance, lifetimes, and versatility that large-format systems require. Initial work focused on the development of a model system that demonstrated the concept of RPEs in an electrochemical device. Aqueous electrolyte solutions of polymers exhibiting properties that change in response to temperature were developed for applications in EDLCs and supercapacitors. These "smart materials" provide a means to control electrochemical systems where polymer phase separation at high temperatures affects electrolyte properties and inhibits device performance. Aqueous RPEs were synthesized using N-isopropylacrylamide, which governs the thermal properties, and fractions of acrylic acid or vinyl sulfonic acids, which provide ions to the solution. The molecular properties of these aqueous RPEs, specifically the ionic composition, were shown to influence the temperature-dependent electrolyte properties and the extent to which these electrolytes control the energy storage characteristics of a supercapacitor device. Materials with high ionic content provided the highest room temperature conductivity and electrochemical activity; however, RPEs with low ionic content provided the highest "on

  11. Benefits of production extension and shifting with thermal storage for a 1MW CSP-ORC plant in Morocco

    Science.gov (United States)

    Bennouna, El Ghali; Mimet, Abdelaziz; Frej, Hicham

    2016-05-01

    The importance of thermal storage for commercial CSP (concentrated Solar Power) plants has now become obvious, this regardless of the solar technology used and the power cycle. The availability of a storage system to a plant operator brings a lot of possibilities for production management, cash flow optimization and grid stabilizing. In particular, and depending on plant location and local grid strategy, thermal storage can contribute, when wisely used, to control production and adapt it to the demand and / or power unbalances and varying prices. Storage systems design, sizing and configuration are proper to each power plant, hence systems that are now widely installed within large commercial solar plants are not necessarily suited for small scale decentralized production, and will not have the same effects. In this paper the benefits of thermal storage are studied for a 1MWe CSP plant with an ORC (Organic Rankine Cycle), this plant has many specific features which call for a detail analysis about the appropriate storage design and optimum operating strategies for decentralized solutions.

  12. Molten Salt-Carbon Nanotube Thermal Energy Storage for Concentrating Solar Power Systems Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Michael Schuller; Frank Little; Darren Malik; Matt Betts; Qian Shao; Jun Luo; Wan Zhong; Sandhya Shankar; Ashwin Padmanaban

    2012-03-30

    We demonstrated that adding nanoparticles to a molten salt would increase its utility as a thermal energy storage medium for a concentrating solar power system. Specifically, we demonstrated that we could increase the specific heat of nitrate and carbonate salts containing 1% or less of alumina nanoparticles. We fabricated the composite materials using both evaporative and air drying methods. We tested several thermophysical properties of the composite materials, including the specific heat, thermal conductivity, latent heat, and melting point. We also assessed the stability of the composite material with repeated thermal cycling and the effects of adding the nanoparticles on the corrosion of stainless steel by the composite salt. Our results indicate that stable, repeatable 25-50% improvements in specific heat are possible for these materials. We found that using these composite salts as the thermal energy storage material for a concentrating solar thermal power system can reduce the levelized cost of electricity by 10-20%. We conclude that these materials are worth further development and inclusion in future concentrating solar power systems.

  13. Thermal and Performance Analysis of a Photovoltaic Module with an Integrated Energy Storage System

    Directory of Open Access Journals (Sweden)

    Manel Hammami

    2017-10-01

    Full Text Available This paper is proposing and analyzing an electric energy storage system fully integrated with a photovoltaic PV module, composed by a set of lithium-iron-phosphate (LiFePO4 flat batteries, which constitutes a generation-storage PV unit. The batteries were surface-mounted on the back side of the PV module, distant from the PV backsheet, without exceeding the PV frame size. An additional low-emissivity sheet was introduced to shield the batteries from the backsheet thermal irradiance. The challenge addressed in this paper is to evaluate the PV cell temperature increase, due to the reduced thermal exchanges on the back of the module, and to estimate the temperature of the batteries, verifying their thermal constraints. Two one-dimensional (1D thermal models, numerically implemented by using the thermal library of Simulink-Matlab accounting for all the heat exchanges, are here proposed: one related to the original PV module, the other related to the portion of the area of the PV module in correspondence of the proposed energy-storage system. Convective and radiative coefficients were then calculated in relation to different configurations and ambient conditions. The model validation has been carried out considering the PV module to be at the nominal operating cell temperature (NOCT, and by specific experimental measurements with a thermographic camera. Finally, appropriate models were used to evaluate the increasing cell batteries temperature in different environmental conditions.

  14. Heat transfer enhancement in triplex-tube latent thermal energy storage system with selected arrangements of fins

    Science.gov (United States)

    Zhao, Liang; Xing, Yuming; Liu, Xin; Rui, Zhoufeng

    2018-01-01

    The use of thermal energy storage systems can effectively reduce energy consumption and improve the system performance. One of the promising ways for thermal energy storage system is application of phase change materials (PCMs). In this study, a two-dimensional numerical model is presented to investigate the heat transfer enhancement during the melting/solidification process in a triplex tube heat exchanger (TTHX) by using fluent software. The thermal conduction and natural convection are all taken into account in the simulation of the melting/solidification process. As the volume fraction of fin is kept to be a constant, the influence of proposed fin arrangement on temporal profile of liquid fraction over the melting process is studied and reported. By rotating the unit with different angle, the simulation shows that the melting time varies a little, which means that the installation error can be reduced by the selected fin arrangement. The proposed fin arrangement also can effectively reduce time of the solidification of the PCM by investigating the solidification process. To summarize, this work presents a shape optimization for the improvement of the thermal energy storage system by considering both thermal energy charging and discharging process.

  15. Gold nanoparticle-based thermal history indicator for monitoring low-temperature storage

    International Nuclear Information System (INIS)

    Wang, Yi-Cheng; Lu, Lin; Gunasekaran, Sundaram

    2015-01-01

    We describe a gold nanoparticle (AuNP)-based thermal history indicator (THI) for monitoring low-temperature storage. The THI was prepared from tetrachloroaurate using gelatin as a reducing reagent. Gelatin also acts as a stabilizer to control the growth of the AuNPs. The size and shape of the AuNPs were characterized by UV–vis spectrophotometry and transmission electron microscopy and are initially found to be spherical with an average particle size of ∼19 nm. Initially, the color of the THIs is slightly pink, but after a 90-day storage in the freezer, as both the size and shape of the AuNPs change, the color of the THIs turns to red. After 90 days the absorbance peaks of THIs held at room temperature are red-shifted from 538 to 572 nm and possessed larger amplitude compared to those stored in the freezer. The color change is a function of both storage time and temperature. The observed increase in size is mainly due to storage temperature while the change in shape is mainly due to storage time. The THIs experiencing higher temperature treatments exhibit a more intense color change which is attributed to a localized surface plasmon resonance effect. Thus, the observed visual color changes can provide information regarding the thermal history the material has experienced. Accordingly, when used in conjunction with time-temperature sensitive products, the THI may serve as a proactive system for monitoring and controlling product quality and/or safety. For example, the THI is useful in safeguarding high-value biological products such as enzymes, antibodies, plasma, stem cells and other perishables that have to be stored at low temperatures. (author)

  16. Dynamic thermal behavior of building using phase change materials for latent heat storage

    Directory of Open Access Journals (Sweden)

    Selka Ghouti

    2015-01-01

    Full Text Available This study presents a two-dimensional model with a real size home composed of two-storey (ground and first floor spaces separated by a slab, enveloped by a wall with rectangular section containing phase change material (PCM in order to minimize energy consumption in the buildings. The main objective of the PCM-wall system is to decrease the temperature change from outdoor space before it reaches the indoor space during the daytime. The numerical approach uses effective heat capacity Ceff model with realistic outdoor climatic conditions of Tlemcen city, Algeria. The numerical results showed that by using PCM in wall as energy storage components may reduce the room temperature by about 6 to 7°C of temperature depending on the floor level (first floor spaces or ground floor spaces.

  17. Thermal energy storage characteristics of bentonite-based composite PCMs with enhanced thermal conductivity as novel thermal storage building materials

    International Nuclear Information System (INIS)

    Sarı, Ahmet

    2016-01-01

    Graphical abstract: In this work, novel bentonite-based and form-stable composite phase change materials (Bb-FSPCMs) were produced for LHTES in buildings by impregnation of CA, PEG600, DD and HD with bentonite clay. The microstructures of the compatibility of the Bb-FSPCMs were by using SEM and FT-IR techniques. The DSC results indicated that the produced Bb-FSPCMs composites had suitable phase change temperature of 4–30 °C and good latent heat capacity between 38 and 74 J/g. The TG results demonstrated that all of the fabricated Bb-FSPCMs had good thermal resistance. The Bb-FSPCMs maintained their LHTES properties even after 1000 heating–cooling cycling. The total heating times of the prepared Bb-FSPCMs were reduced noticeably due to their enhanced thermal conductivity after EG (5 wt%) addition. - Highlights: • Bb-FSPCMs were produced by impregnation of CA, PEG600, DD and HD with bentonite. • DSC analysis indicated that Bb-FSPCMs had melting temperature in range of 4–30 °C. • DSC analysis also showed that Bb-FSPCMs had latent heat between 38 and 74 J/g. • The TG analysis demonstrated that Bb-FSPCMs had good thermal resistance. • Thermal conductivity of Bb-FSPCMs were enhanced noticeably with EG (5 wt%) addition. - Abstract: In this work, for latent heat thermal energy storage (LHTES) applications in buildings, bentonite-based form-stable composite phase change materials (Bb-FSPCMs) were produced by impregnation of capric acid (CA), polyethylene glycol (PEG600), dodecanol (DD) and heptadecane (HD) into bentonite clay. The morphological characterization results obtained by scanning electron microscopy (SEM) showed that the bentonite acted as good structural barrier for the organic PCMs homogenously dispersed onto its surface and interlayers. The chemical investigations made by using fourier transform infrared (FT-IR) technique revealed that the attractions between the components of the composites was physical in nature and thus the PCMs were hold

  18. Solar dryer with thermal storage and biomass-backup heater

    Energy Technology Data Exchange (ETDEWEB)

    Madhlopa, A. [Department of Physics and Biochemical Sciences, Malawi Polytechnic, P/Bag 303, Blantyre 3 (Malawi); Ngwalo, G. [Department of Mechanical Engineering, Malawi Polytechnic, P/Bag 303, Blantyre 3 (Malawi)

    2007-04-15

    An indirect type natural convection solar dryer with integrated collector-storage solar and biomass-backup heaters has been designed, constructed and evaluated. The major components of the dryer are biomass burner (with a rectangular duct and flue gas chimney), collector-storage thermal mass and drying chamber (with a conventional solar chimney). The thermal mass was placed in the top part of the biomass burner enclosure. The dryer was fabricated using simple materials, tools and skills, and it was tested in three modes of operation (solar, biomass and solar-biomass) by drying twelve batches of fresh pineapple (Ananas comosus), with each batch weighing about 20 kg. Meteorological conditions were monitored during the dehydration process. Moisture and vitamin C contents were determined in both fresh and dried samples. Results show that the thermal mass was capable of storing part of the absorbed solar energy and heat from the burner. It was possible to dry a batch of pineapples using solar energy only on clear days. Drying proceeded successfully even under unfavorable weather conditions in the solar-biomass mode of operation. In this operational mode, the dryer reduced the moisture content of pineapple slices from about 669 to 11% (db) and yielded a nutritious dried product. The average values of the final-day moisture-pickup efficiency were 15%, 11% and 13% in the solar, biomass and solar-biomass modes of operation respectively. It appears that the solar dryer is suitable for preservation of pineapples and other fresh foods. Further improvements to the system design are suggested. (author)

  19. A basic study on Thermosyphon-type thermal storage unit (TSU) using Nanofluid as the heat transfer medium

    Science.gov (United States)

    Li, Shuang-Fei; Wang, Ping-Yang; Liu, Zhen-hua

    2018-05-01

    This study proposed a novel thermosyphon-type thermal storage unit using water-based CuO nanofluid as the phase-change heat transfer medium. Seven tubular canisters containing solid-liquid phase-change material (PCM) with peak melting temperature of 100 °C were placed vertically into the center of the TSU which is a vertical cylindrical vessel made of stainless steel. Coat formed by depositing nanoparticles during the phase-change process was adopted to increase the wettability of the heat transfer surfaces of the canisters. We investigated the phase-change heat transfer, as well as the heat-storage and heat-release properties, of the TSU through experimental and computational analysis. Our results demonstrate that this thermal storage unit construction can propose good heat transfer and heat-storage/heat-release performance. The coating of nanoparticles onto the heat transfer surfaces increases the surface wettability and improves both the evaporation and condensation heat transfer. The main thermal resistance in the TSU results from the conductive heat transfer inside of the PCM. All phase-change thermal resistance of liquid film in charging and discharging processes can be ignored in this TSU.

  20. A basic study on Thermosyphon-type thermal storage unit (TSU) using Nanofluid as the heat transfer medium

    Science.gov (United States)

    Li, Shuang-Fei; Wang, Ping-Yang; Liu, Zhen-hua

    2017-11-01

    This study proposed a novel thermosyphon-type thermal storage unit using water-based CuO nanofluid as the phase-change heat transfer medium. Seven tubular canisters containing solid-liquid phase-change material (PCM) with peak melting temperature of 100 °C were placed vertically into the center of the TSU which is a vertical cylindrical vessel made of stainless steel. Coat formed by depositing nanoparticles during the phase-change process was adopted to increase the wettability of the heat transfer surfaces of the canisters. We investigated the phase-change heat transfer, as well as the heat-storage and heat-release properties, of the TSU through experimental and computational analysis. Our results demonstrate that this thermal storage unit construction can propose good heat transfer and heat-storage/heat-release performance. The coating of nanoparticles onto the heat transfer surfaces increases the surface wettability and improves both the evaporation and condensation heat transfer. The main thermal resistance in the TSU results from the conductive heat transfer inside of the PCM. All phase-change thermal resistance of liquid film in charging and discharging processes can be ignored in this TSU.

  1. Advanced Thermal Storage for Central Receivers with Supercritical Coolants

    Energy Technology Data Exchange (ETDEWEB)

    Kelly, Bruce D.

    2010-06-15

    The principal objective of the study is to determine if supercritical heat transport fluids in a central receiver power plant, in combination with ceramic thermocline storage systems, offer a reduction in levelized energy cost over a baseline nitrate salt concept. The baseline concept uses a nitrate salt receiver, two-tank (hot and cold) nitrate salt thermal storage, and a subcritical Rankine cycle. A total of 6 plant designs were analyzed, as follows: Plant Designation Receiver Fluid Thermal Storage Rankine Cycle Subcritical nitrate salt Nitrate salt Two tank nitrate salt Subcritical Supercritical nitrate salt Nitrate salt Two tank nitrate salt Supercritical Low temperature H2O Supercritical H2O Two tank nitrate salt Supercritical High temperature H2O Supercritical H2O Packed bed thermocline Supercritical Low temperature CO2 Supercritical CO2 Two tank nitrate salt Supercritical High temperature CO2 Supercritical CO2 Packed bed thermocline Supercritical Several conclusions have been drawn from the results of the study, as follows: 1) The use of supercritical H2O as the heat transport fluid in a packed bed thermocline is likely not a practical approach. The specific heat of the fluid is a strong function of the temperatures at values near 400 °C, and the temperature profile in the bed during a charging cycle is markedly different than the profile during a discharging cycle. 2) The use of supercritical CO2 as the heat transport fluid in a packed bed thermocline is judged to be technically feasible. Nonetheless, the high operating pressures for the supercritical fluid require the use of pressure vessels to contain the storage inventory. The unit cost of the two-tank nitrate salt system is approximately $24/kWht, while the unit cost of the high pressure thermocline system is nominally 10 times as high. 3) For the supercritical fluids, the outer crown temperatures of the receiver tubes are in the range of 700 to 800 °C. At temperatures of 700 °C and above

  2. UCN storage experiment for the investigation of the anomalous interaction with wall surfaces

    International Nuclear Information System (INIS)

    Kawabata, Yuji; Utsuro, Masahiko; Steyerl, A.; Malik, S.S.; Geltenbort, P.; Neumair, S.; Nesvizhevsky, V.V.

    1997-01-01

    The UCN experiment for the investigation of the anomalous interaction with wall surfaces was performed in the ILL UCN source. UCN is monochromated by the gravity and stored in the spectrometer with rectangular trap which is the Fombrin-grease coated box of 67x67cm 2 cross section and 20cm height. The measured energy distribution of stored UCN shows the indication of 'initial micro-heating'. The order of energy gain is ∼ 10 -10 eV in the initial several 100sec of storage. (author)

  3. On the Behavior of Different PCMs in a Hot Water Storage Tank against Thermal Demands.

    Science.gov (United States)

    Porteiro, Jacobo; Míguez, José Luis; Crespo, Bárbara; de Lara, José; Pousada, José María

    2016-03-21

    Advantages, such as thermal storage improvement, are found when using PCMs (Phase Change Materials) in storage tanks. The inclusion of three different types of materials in a 60 l test tank is studied. Two test methodologies were developed, and four tests were performed following each methodology. A thermal analysis is performed to check the thermal properties of each PCM. The distributions of the water temperatures inside the test tanks are evaluated by installing four Pt-100 sensors at different heights. A temperature recovery is observed after exposing the test tank to an energy demand. An energetic analysis that takes into account the energy due to the water temperature, the energy due to the PCM and the thermal loss to the ambient environment is also presented. The percentage of each PCM that remains in the liquid state after the energy demand is obtained.

  4. A central solar-industrial waste heat heating system with large scale borehole thermal storage

    NARCIS (Netherlands)

    Guo, F.; Yang, X.; Xu, L.; Torrens, I.; Hensen, J.L.M.

    2017-01-01

    In this paper, a new research of seasonal thermal storage is introduced. This study aims to maximize the utilization of renewable energy source and industrial waste heat (IWH) for urban district heating systems in both heating and non-heating seasons through the use of large-scale seasonal thermal

  5. Thermal Energy Storage for Building Load Management: Application to Electrically Heated Floor

    Directory of Open Access Journals (Sweden)

    Hélène Thieblemont

    2016-07-01

    Full Text Available In cold climates, electrical power demand for space conditioning becomes a critical issue for utility companies during certain periods of the day. Shifting a portion or all of it to off-peak periods can help reduce peak demand and reduce stress on the electrical grid. Sensible thermal energy storage (TES systems, and particularly electrically heated floors (EHF, can store thermal energy in buildings during the off-peak periods and release it during the peak periods while maintaining occupants’ thermal comfort. However, choosing the type of storage system and/or its configuration may be difficult. In this paper, the performance of an EHF for load management is studied. First, a methodology is developed to integrate EHF in TRNSYS program in order to investigate the impact of floor assembly on the EHF performance. Then, the thermal comfort (TC of the night-running EHF is studied. Finally, indicators are defined, allowing the comparison of different EHF. Results show that an EHF is able to shift 84% of building loads to the night while maintaining acceptable TC in cold climate. Moreover, this system is able to provide savings for the customer and supplier if there is a significant difference between off-peak and peak period electricity prices.

  6. Improved thermal stability of gas-phase Mg nanoparticles for hydrogen storage

    NARCIS (Netherlands)

    Krishnan, Gopi; Palasantzas, G.; Kooi, B. J.

    2010-01-01

    This work focuses on improving the thermal stability of Mg nanoparticles (NPs) for use in hydrogen storage. Three ways are investigated that can achieve this goal. (i) Addition of Cu prevents void formation during NP production and reduces the fast evaporation/voiding of Mg during annealing. (ii)

  7. Development and Performance Evaluation of High Temperature Concrete for Thermal Energy Storage for Solar Power Generation

    Energy Technology Data Exchange (ETDEWEB)

    Selvam, R. Panneer; Hale, Micah; Strasser, Matt

    2013-03-31

    Thermal energy can be stored by the mechanism of sensible or latent heat or heat from chemical reactions. Sensible heat is the means of storing energy by increasing the temperature of the solid or liquid. Since the concrete as media cost per kWhthermal is $1, this seems to be a very economical material to be used as a TES. This research is focused on extending the concrete TES system for higher temperatures (500 °C to 600 °C) and increasing the heat transfer performance using novel construction techniques. To store heat at high temperature special concretes are developed and tested for its performance. The storage capacity costs of the developed concrete is in the range of $0.91-$3.02/kWhthermal. Two different storage methods are investigated. In the first one heat is transported using molten slat through a stainless steel tube and heat is transported into concrete block through diffusion. The cost of the system is higher than the targeted DOE goal of $15/kWhthermal. The increase in cost of the system is due to stainless steel tube to transfer the heat from molten salt to the concrete blocks.The other method is a one-tank thermocline system in which both the hot and cold fluid occupy the same tank resulting in reduced storage tank volume. In this model, heated molten salt enters the top of the tank which contains a packed bed of quartzite rock and silica sand as the thermal energy storage (TES) medium. The single-tank storage system uses about half the salt that is required by the two-tank system for a required storage capacity. This amounts to a significant reduction in the cost of the storage system. The single tank alternative has also been proven to be cheaper than the option which uses large concrete modules with embedded heat exchangers. Using computer models optimum dimensions are determined to have an round trip efficiency of 84%. Additionally, the cost of the structured concrete thermocline configuration provides the TES

  8. More with thermal energy storage. Report 5. Modelling systems. Effects of thermal energy storage systems on the environment. Modelling individual projects. Final report; Meer met bodemenergie. Rapport 5. Modellering systemen. Effecten van bodemenergiesystemen op hun omgeving. Modellering individuele projecten. Eindrapport

    Energy Technology Data Exchange (ETDEWEB)

    Drijver, B.; De Jonge, H. [IF Technology, Arnhem (Netherlands)

    2012-03-30

    The project More With Thermal Energy Storage (MMB, abbreviated in Dutch) focuses on knowledge gaps and potential opportunities regarding open systems. The main questions to be answered are: (1) What effects (hydrological, thermal, microbiological and chemical) occur in the soil system by application of thermal energy storage; (2) Which technical options are available for a sustainable integration of thermal energy storage in the water and energy chain?; (3) Is it possible to achieve multiple objectives by using smart combinations? The project is organized in different work packages. In work package 2, the effects of individual and collective thermal energy storage storage systems on subsoils and the environment are determined. In work package 3 the opportunities for thermal energy storage and soil remediation are examined, while in work package 4 the focus is on new sustainable combinations of heat and cold storage. Work package 1 is the umbrella part where communication and policy of and participation in MMB are the main subjects. This report describes the results of the modeling of three existing thermal energy storage projects in the framework of the MMB project. The aim of the modeling of these projects is to gain insight in the reliability of the predicted hydrological and thermal effects, the causes of any deviations and improvements that are possible to improve the reliability of the predictions [Dutch] Het project Meer Met Bodemenergie (MMB) richt zich op het invullen van kennisleemtes en mogelijke kansen ten aanzien van open systemen. De belangrijkste vragen waarop het onderzoeksprogramma MMB antwoord geeft zijn: (1) Welke effecten (hydrologisch, thermisch, microbiologisch en chemisch) treden op in het bodemsysteem bij toepassing van bodemenergie?; (2) Welke technische mogelijkheden zijn er voor het duurzaam inpassen van bodem-energie in de water- en energieketen?; (3) Is het mogelijk om meerdere doelstellingen tegelijk te verwezenlijken door slimme

  9. Can storage reduce electricity consumption? A general equation for the grid-wide efficiency impact of using cooling thermal energy storage for load shifting

    Science.gov (United States)

    Deetjen, Thomas A.; Reimers, Andrew S.; Webber, Michael E.

    2018-02-01

    This study estimates changes in grid-wide, energy consumption caused by load shifting via cooling thermal energy storage (CTES) in the building sector. It develops a general equation for relating generator fleet fuel consumption to building cooling demand as a function of ambient temperature, relative humidity, transmission and distribution current, and baseline power plant efficiency. The results present a graphical sensitivity analysis that can be used to estimate how shifting load from cooling demand to cooling storage could affect overall, grid-wide, energy consumption. In particular, because power plants, air conditioners and transmission systems all have higher efficiencies at cooler ambient temperatures, it is possible to identify operating conditions such that CTES increases system efficiency rather than decreasing it as is typical for conventional storage approaches. A case study of the Dallas-Fort Worth metro area in Texas, USA shows that using CTES to shift daytime cooling load to nighttime cooling storage can reduce annual, system-wide, primary fuel consumption by 17.6 MWh for each MWh of installed CTES capacity. The study concludes that, under the right circumstances, cooling thermal energy storage can reduce grid-wide energy consumption, challenging the perception of energy storage as a net energy consumer.

  10. Thermal Effectiveness of Wall Indoor Fountain in Warm Humid Climate

    Science.gov (United States)

    Seputra, J. A. P.

    2018-03-01

    Nowadays, many buildings wield indoor water features such as waterfalls, fountains, and water curtains to improve their aesthetical value. Despite the provision of air cooling due to water evaporation, this feature also has adverse effect if applied in warm humid climate since evaporation might increase air humidity beyond the comfort level. Yet, there are no specific researches intended to measure water feature’s effect upon its thermal condition. In response, this research examines the influence of evaporative cooling on indoor wall fountain toward occupant’s thermal comfort in warm humid climate. To achieve this goal, case study is established in Waroeng Steak Restaurant’s dining room in Surakarta-Indonesia. In addition, SNI 03-6572-2001 with comfort range of 20.5–27.1°C and 40-60% of relative humidity is utilized as thermal criterion. Furthermore, Computational Fluid Dynamics (CFD) is employed to process the data and derive conclusions. Research variables are; feature’s height, obstructions, and fan types. As results, Two Bumps Model (ToB) is appropriate when employs natural ventilation. However, if the room is mechanically ventilated, Three Bumps Model (TeB) becomes the best choice. Moreover, application of adaptive ventilation is required to maintain thermal balance.

  11. Comparative analysis on operation strategies of CCHP system with cool thermal storage for a data center

    International Nuclear Information System (INIS)

    Song, Xu; Liu, Liuchen; Zhu, Tong; Zhang, Tao; Wu, Zhu

    2016-01-01

    Highlights: • Load characteristics of the data center make a good match with CCHP systems. • TRNSYS models was used to simulate the discussed CCHP system in a data center. • Comprehensive system performance under two operation strategies were evaluated. • Cool thermal storage was introduced to reuse the energy surplus by FEL system. • The suitable principle of equipment selection for a FEL system were proposed. - Abstract: Combined Cooling, Heating, and Power (CCHP) systems with cool thermal storage can provide an appropriate energy supply for data centers. In this work, we evaluate the CCHP system performance under two different operation strategies, i.e., following thermal load (FTL) and following electric load (FEL). The evaluation is performed through a case study by using TRNSYS software. In the FEL system, the amount of cool thermal energy generated by the absorption chillers is larger than the cooling load and it can be therefore stored and reused at the off-peak times. Results indicate that systems under both operation strategies have advantages in the fields of energy saving and environmental protection. The largest percentage of reduction of primary energy consumption, CO_2 emissions, and operation cost for the FEL system, are 18.5%, 37.4% and 46.5%, respectively. Besides, the system performance is closely dependent on the equipment selection. The relation between the amount of energy recovered through cool thermal storage and the primary energy consumption has also been taken into account. Moreover, the introduction of cool thermal storage can adjust the heat to power ratio on the energy supply side close to that on the consumer side and consequently promote system flexibility and energy efficiency.

  12. Transient forced convection with viscous dissipation to power-law fluids in thermal entrance region of circular ducts with constant wall heat flux

    International Nuclear Information System (INIS)

    Dehkordi, Asghar Molaei; Mohammadi, Ali Asghar

    2009-01-01

    A numerical investigation was conducted on the transient behavior of a hydrodynamically, fully developed, laminar flow of power-law fluids in the thermally developing entrance region of circular ducts taking into account the effect of viscous dissipation but neglecting the effect of axial conduction. In this regard, the unsteady state thermal energy equation was solved by using a finite difference method, whereas the steady state thermal energy equation without wall heat flux was solved analytically as the initial condition of the former. The effects of the power-law index and wall heat flux on the local Nusselt number and thermal entrance length were investigated. Moreover, the local Nusselt number of steady state conditions was correlated in terms of the power-law index and wall heat flux and compared with literature data, which were obtained by an analytic solution for Newtonian fluids. Furthermore, a relationship was proposed for the thermal entrance length

  13. Models comparative study for heat storage in fixed beds; Estudo comparativo de modelos para armazenamento de calor em leitos fixos

    Energy Technology Data Exchange (ETDEWEB)

    Stuginski, Junior, Rubens

    1991-07-01

    This work presents comparative results of a numerical investigation of four possible models for the prediction of thermal performance of fixed bed storage units and their thermal design. These models includes Schumann's model, the radial dispersion model, a model that include both axial heat conduction in the fluid phase and admits thermal gradient in the solids particles and finally a two dimensional single phase model. For each of these models a computer code was written and tested to evaluate the computing time of same data and analyze any other computational problems. The tests of thermal performance included particle size, porosity, particle material, flow rate, inlet temperature and heat losses form tank walls and extremities. Dynamics behaviour of the storage units due to transient variation in either flow rate or inlet temperature was also investigated. The results presented include temperature gradients, pressure drop and heat storage. The results obtained are very useful for analysis and design of fixed bed storage units. (author)

  14. Thermal-hydraulic experiment and analysis for interim dry storage of spent nuclear fuel

    International Nuclear Information System (INIS)

    Yoo, Seung Hun

    2011-02-01

    The experimental and numerical studies of interim storages for nuclear spent fuels have been performed to investigate thermal-hydraulic characteristics of the dry storage systems and to propose new methodologies for the analysis and the design. Three separate researches have been performed in the present study: (a) Development of a scaling methodology and thermal-hydraulic experiment of a single spent fuel assembly simulating a dry storage cask: (b) Full-scope simulation of a dry storage cask by the use of Computational Fluid Dynamics (CFD) code: (c) Thermal-hydraulic design of a tunnel-type interim storage facility. In the first study, a scaling methodology has been developed to design a scaled-down canister. The scaling was performed in two steps. For the first step, the height of a spent fuel assembly was reduced from full height to half height. In order to consider the effect of height reduction on the natural convection, the scaling law of Ishii and Kataoka (1984) was employed. For the second step, the quantity of spent fuel assemblies was reduced from multiple assemblies to a single assembly. The scaling methodology was validated through the comparison with the experiment of the TN24P cask. The Peak Cladding Temperature (PCT), temperature gradients, and the axial and radial temperature distribution in the nondimensional forms were in good agreement with the experimental data. Based on the developed methodology, we have performed a single assembly experiment which was designed to simulate the full scale of the TN24P cask. The experimental data was compared with the CFD calculations. It turns out that their PCTs were less than the maximum allowable temperature for the fuel cladding and that the differences of their PCTs were agreed within 3 .deg. C, which was less than measurement uncertainty. In the second study, the full-scope simulations of the TN24P cask were performed by FLUENT. In order to investigate the sensitivity of the numerical and physical

  15. More with thermal energy storage. Report 11. Area-oriented groundwater control. Fitting of thermal energy storage in area-oriented groundwater control. Chances and points of attention. Final report; Meer met bodemenergie. Rapport 11. Gebiedsgericht grond-waterbeheer. Inpassing van bodemenergie in gebiedsgrondwaterbeheer. Kansen en aandachtspunten. Eindrapport

    Energy Technology Data Exchange (ETDEWEB)

    Henssen, M. [Bioclear, Groningen (Netherlands); Hartog, N. [Deltares, Delft (Netherlands)

    2012-06-25

    The project More With Thermal Energy Storage (MMB, abbreviated in Dutch) focuses on knowledge gaps and potential opportunities regarding open systems. The main questions to be answered are: (1) What effects (hydrological, thermal, microbiological and chemical) occur in the soil system by application of thermal energy storage; (2) Which technical options are available for a sustainable integration of thermal energy storage in the water and energy chain?; (3) Is it possible to achieve multiple objectives by using smart combinations? The project is organized in different work packages. In work package 2, the effects of individual and collective thermal energy storage storage systems on subsoils and the environment are determined. In work package 3 the opportunities for thermal energy storage and soil remediation are examined, while in work package 4 the focus is on new sustainable combinations of heat and cold storage. Work package 1 is the umbrella part where communication and policy of and participation in MMB are the main subjects. In this report the following two questions are posed with regard to the use of thermal energy storage systems in contaminated areas:(1) is it realistic to expect that thermal energy storage systems can contribute to a substantial improvement of groundwater in large-scale contaminated areas?; and (2) is a thermal energy systems an option to control the burden of pollution? And which combinations with other underground or aboveground applications are possible for thermal energy storage? [Dutch] Het project Meer Met Bodemenergie (MMB) richt zich op het invullen van kennisleemtes en mogelijke kansen ten aanzien van open systemen. De belangrijkste vragen waarop het onderzoeksprogramma MMB antwoord geeft zijn: (1) Welke effecten (hydrologisch, thermisch, microbiologisch en chemisch) treden op in het bodemsysteem bij toepassing van bodemenergie?; (2) Welke technische mogelijkheden zijn er voor het duurzaam inpassen van bodem-energie in de water

  16. Thermal analysis for a spent reactor fuel storage test in granite

    International Nuclear Information System (INIS)

    Montan, D.N.

    1980-09-01

    A test is conducted in which spent fuel assemblies from an operating commercial nuclear power reactor are emplaced in the Climax granite at the US Department of Energy's Nevada Test Site. In this generic test, 11 canisters of spent PWR fuel are emplaced vertically along with 6 electrical simulator canisters on 3 m centers, 4 m below the floor of a storage drift which is 420 m below the surface. Two adjacent parallel drifts contain electrical heaters, operated to simulate (in the vicinity of the storage drift) the temperature fields of a large repository. This test, planned for up to five years duration, uses fairly young fuel (2.5 years out of core) so that the thermal peak will occur during the time frame of the test and will not exceed the peak that would not occur until about 40 years of storage had older fuel (5 to 15 years out of core) been used. This paper describes the calculational techniques and summarizes the results of a large number of thermal calculations used in the concept, basic design and final design of the spent fuel test. The results of the preliminary calculations show the effects of spacing and spent fuel age. Either radiation or convection is sufficient to make the drifts much better thermal conductors than the rock that was removed to create them. The combination of radiation and convection causes the drift surfaces to be nearly isothermal even though the heat source is below the floor. With a nominal ventilation rate of 2 m 3 /s and an ambient rock temperature of 23 0 C, the maximum calculated rock temperature (near the center of the heat source) is about 100 0 C while the maximum air temperature in the drift is around 40 0 C. This ventilation (1 m 3 /s through the main drift and 1/2 m 3 /s through each of the side drifts) will remove about 1/3 of the heat generated during the first five years of storage

  17. The SERI solar energy storage program

    Science.gov (United States)

    Copeland, R. J.; Wright, J. D.; Wyman, C. E.

    1980-01-01

    In support of the DOE thermal and chemical energy storage program, the solar energy storage program (SERI) provides research on advanced technologies, systems analyses, and assessments of thermal energy storage for solar applications in support of the Thermal and Chemical Energy Storage Program of the DOE Division of Energy Storage Systems. Currently, research is in progress on direct contact latent heat storage and thermochemical energy storage and transport. Systems analyses are being performed of thermal energy storage for solar thermal applications, and surveys and assessments are being prepared of thermal energy storage in solar applications. A ranking methodology for comparing thermal storage systems (performance and cost) is presented. Research in latent heat storage and thermochemical storage and transport is reported.

  18. Thermal-structural analysis for ITER in-wall shielding block

    International Nuclear Information System (INIS)

    Hao Junchuan; Song Yuntao; Wu Weiyue; Du Shuangsong; Wang, X.; Ioki, K.

    2012-01-01

    Highlights: ► IWS blocks shall withstand various types of mechanical loads including EM loads, inertial loads and thermal loads. ► Due to the complicated geometry, the finite element method is the suitable tool to solve the problem. ► Contact element has been selected to simulate the friction between the different components. ► At baking phase, secondary stresses due to preloading and temperature difference predominate in the total stress. ► At plasma operation phase, secondary stresses due to preloading and thermal loads were deducted from the total stresses. - Abstract: In order to verify the design strength of the in-wall shielding (IWS) blocks of the ITER, thermal-structural analyses of one IWS block under vacuum vessel (VV) baking and plasma operation conditions have been respectively performed with finite element (FE) method. Among the complicated operation scenarios of the ITER, two critical types of combined loads required by the load specification of IWS were applied on the shielding block. The stress of the block is judged by American Society of Mechanical Engineers (ASME) criterion. Results show that the structure of this block has enough safety margin, and it also supplies detailed information of the stress distribution in concerned region under certain loads.

  19. Developments in organic solid–liquid phase change materials and their applications in thermal energy storage

    International Nuclear Information System (INIS)

    Sharma, R.K.; Ganesan, P.; Tyagi, V.V.; Metselaar, H.S.C.; Sandaran, S.C.

    2015-01-01

    Highlights: • Review of organic phase change materials for thermal energy storage. • Review of the eutectic mixtures of organic PCMs. • Review of the techniques of PCM encapsulations and enhancing the thermal conductivity. • Applications of low and medium temperature organic PCMs are listed in detail. • Recommendations are made for future applications of organic PCMs. - Abstract: Thermal energy storage as sensible or latent heat is an efficient way to conserve the waste heat and excess energy available such as solar radiation. Storage of latent heat using organic phase change materials (PCMs) offers greater energy storage density over a marginal melting and freezing temperature difference in comparison to inorganic materials. These favorable characteristics of organic PCMs make them suitable in a wide range of applications. These materials and their eutectic mixtures have been successfully tested and implemented in many domestic and commercial applications such as, building, electronic devices, refrigeration and air-conditioning, solar air/water heating, textiles, automobiles, food, and space industries. This review focuses on three aspects: the materials, encapsulation and applications of organic PCMs, and provides an insight on the recent developments in applications of these materials. Organic PCMs have inherent characteristic of low thermal conductivity (0.15–0.35 W/m K), hence, a larger surface area is required to enhance the heat transfer rate. Therefore, attention is also given to the thermal conductivity enhancement of the materials, which helps to keep the area of the system to a minimum. Besides, various available techniques for material characterization have also been discussed. It has been found that a wide range of the applications of organic PCMs in buildings and other low and medium temperature solar energy applications are in abundant use but these materials are not yet popular among space applications and virtual data storage media. In

  20. Investigation of metal fluoride thermal energy storage materials: availability, cost, and chemistry. Final report, July 15, 1976--December 15, 1976

    Energy Technology Data Exchange (ETDEWEB)

    Eichelberger, J.L.

    1976-12-01

    Storage of thermal energy in the 400 to 1000/sup 0/C range is attracting increasing consideration for use in solar power, central power, vehicular, and commercial process systems. This study investigates the practicality of using metal fluorides as the heat storage medium. The projected availability of metal fluorides has been studied and is shown to be adequate for widespread thermal storage use. Costs are projected and discussed in relation to thermal energy storage applications. Phase diagrams, heats of fusion, heat capacities, vapor pressures, toxicity, stability, volume changes, thermal conductivities, fusion kinetics, corrosion, and container materials of construction for a wide range of fluorides have been examined. Analyses of these data in consideration of thermal energy storage requirements have resulted in selection of the most cost-effective fluoride mixture for each of 23 temperature increments between 400 and 1000/sup 0/C. Thermo-physical properties of these 23 materials are presented. Comparison of fluoride with non-fluoride materials shows that the fluorides are suitable candidates for high temperature applications on the bases of cost, heat capacity/unit volume, heat capacity/unit weight, corrosive properties, and availability.

  1. Thermal stress analysis of the SLAC moveable mask. Addendum 2

    International Nuclear Information System (INIS)

    Johnson, G.L.

    1985-01-01

    X-ray beams emerging from the new SLAC electron-positron storage ring (PEP) can impinge on the walls of tangential divertor channels. A moveable mask made of 6061-T6 aluminum is installed in the channel to limit wall heating. The mask is cooled with water flowing axially at 30 0 C. Beam strikes on the mask cause highly localized heating in the channel structure. Analyses were completed to determine the temperatures and thermally-induced stresses due to this heating. The current design and operating conditions should result in the entrance to the moveable mask operating at a peak temperature of 88 0 C with a peak thermal stress at 19% of the yield of 6061-T6 aluminum

  2. A thermal storage capacity market for non dispatchable renewable energies

    Science.gov (United States)

    Bennouna, El Ghali; Mouaky, Ammar; Arrad, Mouad; Ghennioui, Abdellatif; Mimet, Abdelaziz

    2017-06-01

    Due to the increasingly high capacity of wind power and solar PV in Germany and some other European countries and the high share of variable renewable energy resources in comparison to fossil and nuclear capacity, a power reserve market structured by auction systems was created to facilitate the exchange of balance power capacities between systems and even grid operators. Morocco has a large potential for both wind and solar energy and is engaged in a program to deploy 2000MW of wind capacity by 2020 and 3000 MW of solar capacity by 2030. Although the competitiveness of wind energy is very strong, it appears clearly that the wind program could be even more ambitious than what it is, especially when compared to the large exploitable potential. On the other hand, heavy investments on concentrated solar power plants equipped with thermal energy storage have triggered a few years ago including the launching of the first part of the Nour Ouarzazate complex, the goal being to reach stable, dispatchable and affordable electricity especially during evening peak hours. This paper aims to demonstrate the potential of shared thermal storage capacity between dispatchable and non dispatchable renewable energies and particularly CSP and wind power. Thus highlighting the importance of a storage capacity market in parallel to the power reserve market and the and how it could enhance the development of both wind and CSP market penetration.

  3. Energy Storage System by Means of Improved Thermal Performance of a 3 MW Grid Side Wind Power Converter

    DEFF Research Database (Denmark)

    Qin, Zian; Liserre, Marco; Blaabjerg, Frede

    2013-01-01

    method of the energy storage system. Then the conventional thermal evaluation approach is simplified for evaluation with long term wind profile. The case studies are done to address the optimal power size and capacity of the energy storage system by comparing the improvement of the thermal performance....... Also, the two promising candidates, ultracapacitors and batteries, are compared....

  4. Solidification of high temperature molten salts for thermal energy storage systems

    Science.gov (United States)

    Sheffield, J. W.

    1981-01-01

    The solidification of phase change materials for the high temperature thermal energy storage system of an advanced solar thermal power system has been examined theoretically. In light of the particular thermophysical properties of candidate phase change high temperature salts, such as the eutectic mixture of NaF - MgF2, the heat transfer characteristics of one-dimensional inward solidification for a cylindrical geometry have been studied. The Biot number for the solidified salt is shown to be the critical design parameter for constant extraction heat flux. A fin-on-fin design concept of heat transfer surface augmentation is proposed in an effort to minimize the effects of the salt's low thermal conductivity and large volume change upon fusing.

  5. Solar-thermal-energy collection/storage-pond system

    Science.gov (United States)

    Blahnik, D.E.

    1982-03-25

    A solar thermal energy collection and storage system is disclosed. Water is contained, and the water surface is exposed directly to the sun. The central part of an impermeable membrane is positioned below the water's surface and above its bottom with a first side of the membrane pointing generally upward in its central portion. The perimeter part of the membrane is placed to create a watertight boundary separating the water into a first volume which is directly exposable to the sun and which touches the membranes first side, and a second volumn which touches the membranes second side. A salt is dissolved in the first water volume.

  6. Foam/Aerogel Composite Materials for Thermal and Acoustic Insulation and Cryogen Storage

    Science.gov (United States)

    Williams, Martha K. (Inventor); Smith, Trent M. (Inventor); Fesmire, James E. (Inventor); Weiser, Erik S. (Inventor); Sass, Jared P. (Inventor)

    2011-01-01

    The invention involves composite materials containing a polymer foam and an aerogel. The composite materials have improved thermal insulation ability, good acoustic insulation, and excellent physical mechanical properties. The composite materials can be used, for instance, for heat and acoustic insulation on aircraft, spacecraft, and maritime ships in place of currently used foam panels and other foam products. The materials of the invention can also be used in building construction with their combination of light weight, strength, elasticity, ability to be formed into desired shapes, and superior thermal and acoustic insulation power. The materials have also been found to have utility for storage of cryogens. A cryogenic liquid or gas, such as N.sub.2 or H.sub.2, adsorbs to the surfaces in aerogel particles. Thus, another embodiment of the invention provides a storage vessel for a cryogen.

  7. A novel phase-change cement composite for thermal energy storage: Fabrication, thermal and mechanical properties

    International Nuclear Information System (INIS)

    Zhang, He; Xing, Feng; Cui, Hong-Zhi; Chen, Da-Zhu; Ouyang, Xing; Xu, Su-Zhen; Wang, Jia-Xin; Huang, Yi-Tian; Zuo, Jian-Dong; Tang, Jiao-Ning

    2016-01-01

    Highlights: • A novel flaky graphite-doped phase-change microcapsule (FGD-MPCM) was prepared. • FGD-MPCM has substantial latent heat storage capacity (135.8 J/g). • FGD-MPCMs/cement composite is capable of reducing indoor temperature fluctuation. • Compressive strength of cement composite with 30% FGD-MPCMs can reach to 14.2 MPa. - Abstract: Facing upon the increasingly severe energy crisis, one of the key issues for reducing the building energy consumption is to pursue high-performance thermal energy storage technologies based on phase-change materials. In this study, a novel cement composite incorporated with flaky graphite-doped microencapsulated phase-change materials (FGD-MPCMs) was developed. Various techniques, such as field emission-scanning electron microscopy (FE-SEM), optical microscopy (OM), X-ray diffraction (XRD), differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) were used to analyse the composite structure and thermal performances. The results indicate that the spherical microcapsules are well dispersed in the cement matrix. When combined within the cement, the thermal stability of the microcapsules was highly improved, and the inclusion of greater amounts of FGD-MPCMs further increased the latent heat of the composite. The mechanical properties of the cement composites were affected with the increase of FGD-MPCMs dosage and the porosity of the composites. In spite of this, the compressive strength and flexural strength of the cement composite with 30% FGD-MPCM could still reach to as high as 14.2 MPa and 4.1 MPa, respectively. Results from the infrared thermography and the model room test suggested that the composite filled with FGD-MPCMs is capable of reducing indoor temperature fluctuation and exhibits good potential for application in buildings to enhance energy savings and thermal comfort.

  8. Thermal modeling and analysis of thin-walled structures in micro milling

    Science.gov (United States)

    Zhang, J. F.; Ma, Y. H.; Feng, C.; Tang, W.; Wang, S.

    2017-11-01

    The numerical analytical model has been developed to predict the thermal effect with respect to thin walled structures by micro-milling. In order to investigate the temperature distribution around micro-edge of cutter, it is necessary to considering the friction power, the shearing power, the shear area between the tool micro-edge and materials. Due to the micro-cutting area is more difficult to be measured accurately, the minimum chip thickness as one of critical factors is also introduced. Finite element-based simulation was employed by the Advantedge, which was determined from the machining of Ti-6Al-4V over a range of the uncut chip thicknesses. Results from the proposed model have been successfully accounted for the effects of thermal softening for material.

  9. Development of graphite foam infiltrated with MgCl 2 for a latent heat based thermal energy storage (LHTES) system

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Dileep; Kim, Taeil; Zhao, Weihuan; Yu, Wenhua; France, David M.

    2016-08-01

    Thermal energy storage (TES) systems that are compatible with high temperature power cycles for concentrating solar power (CSP) require high temperature media for transporting and storing thermal energy. To that end, TES systems have been proposed based on the latent heat of fusion of the phase change materials (PCMs). However, PCMs have relatively low thermal conductivities. In this paper, use of high-thermal-conductivity graphite foam infiltrated with a PCM (MgCl2) has been investigated as a potential TES system. Graphite foams with two porosities were infiltrated with MgCl2. The infiltrated composites were evaluated for density, heat of fusion, melting/freezing temperatures, and thermal diffusivities. Estimated thermal conductivities of MgCl2/graphite foam composites were significantly higher than those of MgCl2 alone over the measured temperature range. Furthermore, heat of fusion, melting/freezing temperatures, and densities showed comparable values to those of pure MgCl2. Results of this study indicate that MgCl2/graphite foam composites show promise as storage media for a latent heat thermal energy storage system for CSP applications.

  10. Hot Thermal Storage in a Variable Power, Renewable Energy System

    Science.gov (United States)

    2014-06-01

    where cost effective, increase the utilization of distributed electric power generation through wind, solar, geothermal , and biomass renewable...characteristics and may not necessarily be available in all cases. Types of direct heat energy systems include solar thermal, waste heat, and geothermal ...of super capacitor energy storage system in microgrid,” in International Conference on Sustainable Power Generation and Supply, Janjing, China

  11. On the Behavior of Different PCMs in a Hot Water Storage Tank against Thermal Demands

    Directory of Open Access Journals (Sweden)

    Jacobo Porteiro

    2016-03-01

    Full Text Available Advantages, such as thermal storage improvement, are found when using PCMs (Phase Change Materials in storage tanks. The inclusion of three different types of materials in a 60 l test tank is studied. Two test methodologies were developed, and four tests were performed following each methodology. A thermal analysis is performed to check the thermal properties of each PCM. The distributions of the water temperatures inside the test tanks are evaluated by installing four Pt-100 sensors at different heights. A temperature recovery is observed after exposing the test tank to an energy demand. An energetic analysis that takes into account the energy due to the water temperature, the energy due to the PCM and the thermal loss to the ambient environment is also presented. The percentage of each PCM that remains in the liquid state after the energy demand is obtained.