WorldWideScience

Sample records for thermal phase transitions

  1. Thermal equilibrium during the electroweak phase transition

    International Nuclear Information System (INIS)

    Tetradis, N.

    1991-12-01

    The effective potential for the standard model develops a barrier, at temperatures around the electroweak scale, which separates the minimum at zero field and a deeper non-zero minimum. This could create out of equilibrium conditions by inducing the localization of the Higgs field in a metastable state around zero. In this picture vacuum decay would occur through bubble nucleation. I show that there is an upper bound on the Higgs mass for the above scenario to be realized. The barrier must be high enough to prevent thermal fluctuations of the Higgs expectation value from establishing thermal equilibrium between the two minima. The upper bound is estimated to be lower than the experimental lower limit. This is also imposes constraints on extensions of the standard model constructed in order to generate a strongly first order phase transition. (orig.)

  2. Negative thermal expansion near two structural quantum phase transitions

    Science.gov (United States)

    Occhialini, Connor A.; Handunkanda, Sahan U.; Said, Ayman; Trivedi, Sudhir; Guzmán-Verri, G. G.; Hancock, Jason N.

    2017-12-01

    Recent experimental work has revealed that the unusually strong, isotropic structural negative thermal expansion in cubic perovskite ionic insulator ScF3 occurs in excited states above a ground state tuned very near a structural quantum phase transition, posing a question of fundamental interest as to whether this special circumstance is related to the anomalous behavior. To test this hypothesis, we report an elastic and inelastic x-ray scattering study of a second system Hg2I2 also tuned near a structural quantum phase transition while retaining stoichiometric composition and high crystallinity. We find similar behavior and significant negative thermal expansion below 100 K for dimensions along the body-centered-tetragonal c axis, bolstering the connection between negative thermal expansion and zero-temperature structural transitions. We identify the common traits between these systems and propose a set of materials design principles that can guide discovery of new materials exhibiting negative thermal expansion.

  3. Negative thermal expansion near two structural quantum phase transitions

    Energy Technology Data Exchange (ETDEWEB)

    Occhialini, Connor A.; Handunkanda, Sahan U.; Said, Ayman; Trivedi, Sudhir; Guzmán-Verri, G. G.; Hancock, Jason N.

    2017-12-01

    Recent experimental work has revealed that the unusually strong, isotropic structural negative thermal expansion in cubic perovskite ionic insulator ScF3 occurs in excited states above a ground state tuned very near a structural quantum phase transition, posing a question of fundamental interest as to whether this special circumstance is related to the anomalous behavior. To test this hypothesis, we report an elastic and inelastic x-ray scattering study of a second system Hg2I2 also tuned near a structural quantum phase transition while retaining stoichiometric composition and high crystallinity. We find similar behavior and significant negative thermal expansion below 100 K for dimensions along the body-centered-tetragonal c axis, bolstering the connection between negative thermal expansion and zero-temperature structural transitions.We identify the common traits between these systems and propose a set of materials design principles that can guide discovery of newmaterials exhibiting negative thermal expansion

  4. Superradiant Phase Transition in a Superconducting Circuit in Thermal Equilibrium.

    Science.gov (United States)

    Bamba, Motoaki; Inomata, Kunihiro; Nakamura, Yasunobu

    2016-10-21

    We propose a superconducting circuit that shows a superradiant phase transition (SRPT) in thermal equilibrium. The existence of the SRPT is confirmed analytically in the limit of an infinite number of artificial atoms. We also perform a numerical diagonalization of the Hamiltonian with a finite number of atoms and observe an asymptotic behavior approaching the infinite limit as the number of atoms increases. The SRPT can also be interpreted intuitively in a classical analysis.

  5. Do phase transitions survive binomial reducibility and thermal scaling?

    International Nuclear Information System (INIS)

    Moretto, L.G.; Phair, L.; Wozniak, G.J.

    1996-05-01

    First order phase transitions are described in terms of the microcanonical and canonical ensemble, with special attention to finite size effects. Difficulties in interpreting a 'caloric curve' are discussed. A robust parameter indicating phase coexistence (univariance) or single phase (bivariance) is extracted for charge distributions. 9 refs., 4 figs

  6. Do phase transitions survive binomial reducibility and thermal scaling?

    Energy Technology Data Exchange (ETDEWEB)

    Moretto, L.G.; Phair, L.; Wozniak, G.J.

    1996-05-01

    First order phase transitions are described in terms of the microcanonical and canonical ensemble, with special attention to finite size effects. Difficulties in interpreting a `caloric curve` are discussed. A robust parameter indicating phase coexistence (univariance) or single phase (bivariance) is extracted for charge distributions. 9 refs., 4 figs.

  7. Thermal phase transition with full 2-loop effective potential

    Science.gov (United States)

    Laine, M.; Meyer, M.; Nardini, G.

    2017-07-01

    Theories with extended Higgs sectors constructed in view of cosmological ramifications (gravitational wave signal, baryogenesis, dark matter) are often faced with conflicting requirements for their couplings; in particular those influencing the strength of a phase transition may be large. Large couplings compromise perturbative studies, as well as the high-temperature expansion that is invoked in dimensionally reduced lattice investigations. With the example of the inert doublet extension of the Standard Model (IDM), we show how a resummed 2-loop effective potential can be computed without a high-T expansion, and use the result to scrutinize its accuracy. With the exception of Tc, which is sensitive to contributions from heavy modes, the high-T expansion is found to perform well. 2-loop corrections weaken the transition in IDM, but they are moderate, whereby a strong transition remains an option.

  8. Thermal phase transition with full 2-loop effective potential

    Directory of Open Access Journals (Sweden)

    M. Laine

    2017-07-01

    Full Text Available Theories with extended Higgs sectors constructed in view of cosmological ramifications (gravitational wave signal, baryogenesis, dark matter are often faced with conflicting requirements for their couplings; in particular those influencing the strength of a phase transition may be large. Large couplings compromise perturbative studies, as well as the high-temperature expansion that is invoked in dimensionally reduced lattice investigations. With the example of the inert doublet extension of the Standard Model (IDM, we show how a resummed 2-loop effective potential can be computed without a high-T expansion, and use the result to scrutinize its accuracy. With the exception of Tc, which is sensitive to contributions from heavy modes, the high-T expansion is found to perform well. 2-loop corrections weaken the transition in IDM, but they are moderate, whereby a strong transition remains an option.

  9. Unsaturated deformable porous media flow with thermal phase transition

    Czech Academy of Sciences Publication Activity Database

    Krejčí, Pavel; Rocca, E.; Sprekels, J.

    2017-01-01

    Roč. 27, č. 14 (2017), s. 2675-2710 ISSN 0218-2025 R&D Projects: GA ČR(CZ) GA15-12227S Institutional support: RVO:67985840 Keywords : porous media * phase transitions * existence of solutions Subject RIV: BA - General Mathematics OBOR OECD: Applied mathematics Impact factor: 2.860, year: 2016 http://www.worldscientific.com/doi/abs/10.1142/S0218202517500555

  10. Dynamic Off-Equilibrium Transition in Systems Slowly Driven across Thermal First-Order Phase Transitions.

    Science.gov (United States)

    Pelissetto, Andrea; Vicari, Ettore

    2017-01-20

    We study the off-equilibrium behavior of systems with short-range interactions, slowly driven across a thermal first-order transition, where the equilibrium dynamics is exponentially slow. We consider a dynamics that starts in the high-T phase at time t=t_{i}0 in the low-T phase, with a time-dependent temperature T(t)/T_{c}≈1-t/t_{s}, where t_{s} is the protocol time scale. A general off-equilibrium scaling (OS) behavior emerges in the limit of large t_{s}. We check it at the first-order transition of the two-dimensional q-state Potts model with q=20 and 10. The numerical results show evidence of a dynamic transition, where the OS functions show a spinodal-like singularity. Therefore, the general mean-field picture valid for systems with long-range interactions is qualitatively recovered, provided the time dependence is appropriately (logarithmically) rescaled.

  11. A non-destructive method to measure the thermal properties of frozen soils during phase transition

    Directory of Open Access Journals (Sweden)

    Bin Zhang

    2015-04-01

    Full Text Available Frozen soils cover about 40% of the land surface on the earth and are responsible for the global energy balances affecting the climate. Measurement of the thermal properties of frozen soils during phase transition is important for analyzing the thermal transport process. Due to the involvement of phase transition, the thermal properties of frozen soils are rather complex. This paper introduces the uses of a multifunctional instrument that integrates time domain reflectometry (TDR sensor and thermal pulse technology (TPT to measure the thermal properties of soil during phase transition. With this method, the extent of phase transition (freezing/thawing was measured with the TDR module; and the corresponding thermal properties were measured with the TPT module. Therefore, the variation of thermal properties with the extent of freezing/thawing can be obtained. Wet soils were used to demonstrate the performance of this measurement method. The performance of individual modules was first validated with designed experiments. The new sensor was then used to monitor the properties of soils during freezing–thawing process, from which the freezing/thawing degree and thermal properties were simultaneously measured. The results are consistent with documented trends of thermal properties variations.

  12. Elastic modulus, thermal expansion, and specific heat at a phase transition

    International Nuclear Information System (INIS)

    Testardi, L.R.

    1975-01-01

    The interrelation of the elastic modulus, thermal-expansion coefficient, and specific heat of a transformed phase relative to the untransformed phase is calculated assuming a particular but useful form of the thermodynamic potential. For second-order phase transitions where this potential applies, measurements of modulus, expansion, and specific heat can yield the general (longitudinal as well as shear) first- and second-order stress (or strain) dependences of the transition temperature and of the order parameter at absolute zero. An exemplary application to one type of phase transition is given

  13. Variation of thermal conductivity of DPPC lipid bilayer membranes around the phase transition temperature.

    Science.gov (United States)

    Youssefian, Sina; Rahbar, Nima; Lambert, Christopher R; Van Dessel, Steven

    2017-05-01

    Given their amphiphilic nature and chemical structure, phospholipids exhibit a strong thermotropic and lyotropic phase behaviour in an aqueous environment. Around the phase transition temperature, phospholipids transform from a gel-like state to a fluid crystalline structure. In this transition, many key characteristics of the lipid bilayers such as structure and thermal properties alter. In this study, we employed atomistic simulation techniques to study the structure and underlying mechanisms of heat transfer in dipalmitoylphosphatidylcholine (DPPC) lipid bilayers around the fluid-gel phase transformation. To investigate this phenomenon, we performed non-equilibrium molecular dynamics simulations for a range of different temperature gradients. The results show that the thermal properties of the DPPC bilayer are highly dependent on the temperature gradient. Higher temperature gradients cause an increase in the thermal conductivity of the DPPC lipid bilayer. We also found that the thermal conductivity of DPPC is lowest at the transition temperature whereby one lipid leaflet is in the gel phase and the other is in the liquid crystalline phase. This is essentially related to a growth in thermal resistance between the two leaflets of lipid at the transition temperature. These results provide significant new insights into developing new thermal insulation for engineering applications. © 2017 The Authors.

  14. Pressure-dependence of the phase transitions and thermal expansion in zirconium and hafnium pyrovanadate

    Energy Technology Data Exchange (ETDEWEB)

    Gallington, Leighanne C.; Hester, Brett R.; Kaplan, Benjamin S. [School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332‐0400 (United States); Wilkinson, Angus P., E-mail: angus.wilkinson@chemistry.gatech.edu [School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332‐0400 (United States); School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332‐0245 (United States)

    2017-05-15

    Low or negative thermal expansion (NTE) has been previously observed in members of the ZrP{sub 2}O{sub 7} family at temperatures higher than their order-disorder phase transitions. The thermoelastic properties and phase behavior of the low temperature superstructure and high temperature negative thermal expansion phases of ZrV{sub 2}O{sub 7} and HfV{sub 2}O{sub 7} were explored via in situ variable temperature/pressure powder x-ray diffraction measurements. The phase transition temperatures of ZrV{sub 2}O{sub 7} and HfV{sub 2}O{sub 7} exhibited a very strong dependence on pressure (∼700 K GPa), with moderate compression suppressing the formation of their NTE phases below 513 K. Compression also reduced the magnitude of the coefficients of thermal expansion in both the positive and negative thermal expansion phases. Additionally, the high temperature NTE phase of ZrV{sub 2}O{sub 7} was found to be twice as stiff as the low temperature positive thermal expansion superstructure (24 and 12 GPa respectively). - Graphical abstract: The temperature at which ZrV{sub 2}O{sub 7} transforms to a phase displaying negative thermal expansion is strongly pressure dependent. The high temperature form of ZrV{sub 2}O{sub 7} is elastically stiffer than the low temperature form. - Highlights: • The order-disorder phase transition temperatures in ZrV{sub 2}O{sub 7} and HfV{sub 2}O{sub 7} are strongly pressure dependent (∼700 K.GPa). • The high temperature (disordered) phase of ZrV{sub 2}O{sub 7} is much stiffer than the ambient temperature (ordered) phase. • Compression reduces the magnitude of the negative thermal expansion in the high temperature phase of ZrV{sub 2}O{sub 7}.

  15. Pressure-dependence of the phase transitions and thermal expansion in zirconium and hafnium pyrovanadate

    Science.gov (United States)

    Gallington, Leighanne C.; Hester, Brett R.; Kaplan, Benjamin S.; Wilkinson, Angus P.

    2017-05-01

    Low or negative thermal expansion (NTE) has been previously observed in members of the ZrP2O7 family at temperatures higher than their order-disorder phase transitions. The thermoelastic properties and phase behavior of the low temperature superstructure and high temperature negative thermal expansion phases of ZrV2O7 and HfV2O7 were explored via in situ variable temperature/pressure powder x-ray diffraction measurements. The phase transition temperatures of ZrV2O7 and HfV2O7 exhibited a very strong dependence on pressure (∼700 K GPa), with moderate compression suppressing the formation of their NTE phases below 513 K. Compression also reduced the magnitude of the coefficients of thermal expansion in both the positive and negative thermal expansion phases. Additionally, the high temperature NTE phase of ZrV2O7 was found to be twice as stiff as the low temperature positive thermal expansion superstructure (24 and 12 GPa respectively).

  16. Pressure-dependence of the phase transitions and thermal expansion in zirconium and hafnium pyrovanadate

    Energy Technology Data Exchange (ETDEWEB)

    Gallington, Leighanne C.; Hester, Brett R.; Kaplan, Benjamin S.; Wilkinson, Angus P. (GIT)

    2017-05-01

    Low or negative thermal expansion (NTE) has been previously observed in members of the ZrP2O7 family at temperatures higher than their order-disorder phase transitions. The thermoelastic properties and phase behavior of the low temperature superstructure and high temperature negative thermal expansion phases of ZrV2O7 and HfV2O7 were explored via in situ variable temperature/pressure powder x-ray diffraction measurements. The phase transition temperatures of ZrV2O7 and HfV2O7 exhibited a very strong dependence on pressure (~700 K GPa), with moderate compression suppressing the formation of their NTE phases below 513 K. Compression also reduced the magnitude of the coefficients of thermal expansion in both the positive and negative thermal expansion phases. Additionally, the high temperature NTE phase of ZrV2O7 was found to be twice as stiff as the low temperature positive thermal expansion superstructure (24 and 12 GPa respectively).

  17. Thermal battery. [solid metal halide electrolytes with enhanced electrical conductance after a phase transition

    Science.gov (United States)

    Carlsten, R.W.; Nissen, D.A.

    1973-03-06

    The patent describes an improved thermal battery whose novel design eliminates various disadvantages of previous such devices. Its major features include a halide cathode, a solid metal halide electrolyte which has a substantially greater electrical conductance after a phase transition at some temperature, and a means for heating its electrochemical cells to activation temperature.

  18. Numerical Modelling of Tailings Dam Thermal-Seepage Regime Considering Phase Transitions

    Directory of Open Access Journals (Sweden)

    Aniskin Nikolay Alekseevich

    2017-01-01

    Full Text Available Statement of the Problem. The article describes the problem of combined thermal-seepage regime for earth dams and those operated in the permafrost conditions. This problem can be solved using the finite elements method based on the local variational formulation. Results. A thermal-seepage regime numerical model has been developed for the “dam-foundation” system in terms of the tailings dam. The effect of heat-and-mass transfer and liquid phase transition in soil interstices on the dam state is estimated. The study with subsequent consideration of these factors has been undertaken. Conclusions. The results of studying the temperature-filtration conditions of the structure based on the factors of heat-and-mass transfer and liquid phase transition have shown that the calculation results comply with the field data. Ignoring these factors or one of them distorts the real situation of the dam thermal-seepage conditions.

  19. Phase transitions

    CERN Document Server

    Sole, Ricard V; Solé, Ricard V; Solé, Ricard V; Sol, Ricard V; Solé, Ricard V

    2011-01-01

    Phase transitions--changes between different states of organization in a complex system--have long helped to explain physics concepts, such as why water freezes into a solid or boils to become a gas. How might phase transitions shed light on important problems in biological and ecological complex systems? Exploring the origins and implications of sudden changes in nature and society, Phase Transitions examines different dynamical behaviors in a broad range of complex systems. Using a compelling set of examples, from gene networks and ant colonies to human language and the degradation of diverse ecosystems, the book illustrates the power of simple models to reveal how phase transitions occur. Introductory chapters provide the critical concepts and the simplest mathematical techniques required to study phase transitions. In a series of example-driven chapters, Ricard Solé shows how such concepts and techniques can be applied to the analysis and prediction of complex system behavior, including the origins of ...

  20. Study on Stress Development in the Phase Transition Layer of Thermal Barrier Coatings

    Directory of Open Access Journals (Sweden)

    Yijun Chai

    2016-09-01

    Full Text Available Stress development is one of the significant factors leading to the failure of thermal barrier coating (TBC systems. In this work, stress development in the two phase mixed zone named phase transition layer (PTL, which grows between the thermally grown oxide (TGO and the bond coat (BC, is investigated by using two different homogenization models. A constitutive equation of the PTL based on the Reuss model is proposed to study the stresses in the PTL. The stresses computed with the proposed constitutive equation are compared with those obtained with Voigt model-based equation in detail. The stresses based on the Voigt model are slightly higher than those based on the Reuss model. Finally, a further study is carried out to explore the influence of phase transition proportions on the stress difference caused by homogenization models. Results show that the stress difference becomes more evident with the increase of the PTL thickness ratio in the TGO.

  1. Exploration of Doubly Thermal Phase Transition Process of PDEGA-b-PDMA-b-PVCL in Water.

    Science.gov (United States)

    Ye, Zhangxin; Li, Youcheng; An, Zesheng; Wu, Peiyi

    2016-07-05

    Understanding of phase transition mechanism of thermoresponsive polymers is the basis for the rational design of smart materials with predictable properties. Linear ABC triblock terpolymer poly(di(ethylene glycol)ethyl ether acrylate)-b-poly(N,N-dimethylacrylamide)-b-poly(N-vinylcaprolactam) (PDEGA-b-PDMA-b-PVCL) was synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization. The doubly thermal phase transition of PDEGA-b-PDMA-b-PVCL in aqueous solution was investigated by a combination of nuclear magnetic resonance (NMR), differential scanning calorimetry (DSC), turbidimetry, and dynamic light scattering (DLS). The terpolymer self-assembles into micelles with PDEGA being the core-forming block during the first lower critical solution temperature (LCST) transition corresponding to PDEGA, which is followed by a second LCST transition corresponding to PVCL, resulting in the formation of micellar aggregates. The PDMA middle segment plays an important role as an isolation zone to prevent cooperative dehydration of the PDEGA and PVCL segments, and therefore, two independent LCST transitions corresponding to PDEGA and PVCL were observed. Furthermore, FT-IR with perturbation correlation moving window (PCMW) and two-dimensional spectroscopy (2DCOS) was applied to elucidate the two-step phase transition mechanism of this terpolymer. It was observed that the CH, ester carbonyl, and ether groups of PDEGA change prior to the CH and amide carbonyl groups of PVCL, further supporting that the two phase transitions corresponding to PDEGA and PVCL indeed occur without mutual interferences.

  2. Phase transition of neopentyl glycol in nanopores for thermal energy storage

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Chao; Li, Qifeng; Wang, Liping; Lan, Xiaozheng, E-mail: lanxzh@sdau.edu.cn

    2016-05-20

    Highlights: • NPG nanocomposites in porous glass (d = 11.5–300 nm) are prepared. • Solid transition temperature of the nanocomposites can be tuned to ∼11 °C below the bulk. • Latent heat of the pore NPG varies in the range of 65.5–99.6% of the bulk value. • Nanoconfinement provides a way of reusing those ideal heat storage materials. - Abstract: Size-dependent thermal properties of neopentyl glycol (NPG) embedded in controlled porous glasses (CPGs) are investigated using differential scanning calorimetry (DSC), infrared spectroscopy (FT-IR), and powder X-ray diffraction (XRD). In the nanopores of CPGs (diameter d = 11.5–300 nm), NPG shows depressed solid–solid and solid–liquid phase transition temperatures and latent heats, which decrease as the pore size becomes smaller. In thermal cycling around the solid transition, the nano-sized NPG display stable transition temperature and enthalpy change as the bulk. Supercooling in the solid transition increases with the decreasing pore diameter (d > 25 nm). From FT-IR and XRD analysis, NPG in the nanopores maintains the same structure as the bulk. The nanoencapsulated NPG is analogous to a series of new phase change materials (PCMs), through which the ideal heat storage performance of the bulk may be handed down.

  3. Phase transitions and thermal expansion in Ni51- x Mn36 + x Sn13 alloys

    Science.gov (United States)

    Kaletina, Yu. V.; Gerasimov, E. G.; Kazantsev, V. A.; Kaletin, A. Yu.

    2017-10-01

    Thermal expansion and structural and magnetic phase transitions in alloys of the Ni-Mn-Sn system have been investigated. The spontaneous martensitic transformation in Ni51-xMn36 + xSn13 (0 ≤ x ≤ 3) alloys is found to be accompanied by high jumps in the temperature dependences of the linear thermal expansion. The relative change in the linear sizes of these alloys at the martensitic transformation is 1.5 × 10-3. There are no anomalies in the magnetic-ordering temperature range in the temperature dependences of the coefficient of linear thermal expansion. The differences in the behavior of linear thermal expansion at the martensitic transformation in Ni51-xMn36 + xSn13 (0 ≤ x ≤ 3) and Ni47Mn40Sn13( x = 4) alloys have been established.

  4. Thermal study of monovalent-divalent phase transition in npBifc-F1TCNQ System

    International Nuclear Information System (INIS)

    Sato, Michiko; Nishio, Yutaka; Kajita, Koji; Mochida, Tomoyuki

    2009-01-01

    In a new molecular solid composed of di-neopentyl-biferrocene (npBifc) and fluorotetracyanoquinodimethane (F 1 TCNQ) 3 , Mochida reported the discovery of a reversible valence transfer that can be regarded as an 'ionic(I)-ionic(II)' phase transfer between the monovalent state (D + A - ) and the divalent state (D 2+ A 2- ). We have studied thermo-dynamical properties of this transformation for this complex using the differential thermal analyses (DTA). We observed a broad excess specific heat with multi-peaks attributed to micro-domain structure over the corresponding temperature range (100-150K) accompanied by temperature hysteresis of 7K. The transition entropy (ΔS) was determined to be 22 ± 2 J/mol-K and almost satisfied a Clausius-Clapeyron relation. These experimental results provide an experimental confirmation of the first order phase transition for the monovalent-divalent transfer. At the transition, we observe that the electronic degrees of freedom remained constant values, while large entropy absorbed crossing from low temperature phase to high temperature one is contributed by the lattice one. We finally estimated the internal energy and concluded that delicate energy valance between Madelung, ionization and affinity energies enable this system to exhibit a temperature induce monovalent-divalent phase transition.

  5. Quantum phase transitions

    International Nuclear Information System (INIS)

    Sachdev, S.

    1999-01-01

    Phase transitions are normally associated with changes of temperature but a new type of transition - caused by quantum fluctuations near absolute zero - is possible, and can tell us more about the properties of a wide range of systems in condensed-matter physics. Nature abounds with phase transitions. The boiling and freezing of water are everyday examples of phase transitions, as are more exotic processes such as superconductivity and superfluidity. The universe itself is thought to have passed through several phase transitions as the high-temperature plasma formed by the big bang cooled to form the world as we know it today. Phase transitions are traditionally classified as first or second order. In first-order transitions the two phases co-exist at the transition temperature - e.g. ice and water at 0 deg., or water and steam at 100 deg. In second-order transitions the two phases do not co-exist. In the last decade, attention has focused on phase transitions that are qualitatively different from the examples noted above: these are quantum phase transitions and they occur only at the absolute zero of temperature. The transition takes place at the ''quantum critical'' value of some other parameter such as pressure, composition or magnetic field strength. A quantum phase transition takes place when co-operative ordering of the system disappears, but this loss of order is driven solely by the quantum fluctuations demanded by Heisenberg's uncertainty principle. The physical properties of these quantum fluctuations are quite distinct from those of the thermal fluctuations responsible for traditional, finite-temperature phase transitions. In particular, the quantum system is described by a complex-valued wavefunction, and the dynamics of its phase near the quantum critical point requires novel theories that have no analogue in the traditional framework of phase transitions. In this article the author describes the history of quantum phase transitions. (UK)

  6. Thermally enhanced optical nonlinearity in nematic liquid crystal close to phase transition temperature

    Science.gov (United States)

    Shih, Chia-Chi; Chen, Yu-Jen; Hung, Wen-Chi; Jiang, I.-Min; Tsai, Ming-Shan

    2010-09-01

    This study investigates the beam profile and the liquid crystal (LC) arrangement affected by an optical field on LC thin films at a temperature close to nematic-isotropic phase transition temperature ( TNI). A combined microscopic and conoscopic technique was used in experiments as a convenient way to analyze the optical nonlinearity that is associated with the molecular configuration of nematic liquid crystal (NLC). An optical field combined with thermal enhancement enhances molecular reorientation and causes additional molecular excitation along the axis of propagation of the beam. The reorientational nonlinearity yields an undulating structure with multi-foci; the length between each pair of foci increases with time, as described.

  7. Critical linear thermal expansion in the smectic-A phase near the nematic-smectic phase transition.

    Science.gov (United States)

    Anesta, E; Iannacchione, G S; Garland, C W

    2004-10-01

    Recent high-resolution x-ray investigations of the smectic- A (SmA) phase near the nematic-to-SmA transition provide information about the critical behavior of the linear thermal expansion coefficient alpha// parallel to the director. Combining such data with available volume thermal expansion alpha(V) data yields the in-plane linear expansion coefficient alpha(perpendicular) . The critical behaviors of alpha// and alpha(perpendicular) are the same as those for alpha(V) and the heat capacity Cp. However, for any given liquid crystal, alpha//(crit) and alpha(perpendicular)(crit) differ in sign. Furthermore, the quantity alpha// (crit) is positive for SmAd partial bilayer smectics, while it is negative for nonpolar SmAm monomeric smectics. This feature is discussed in terms of the molecular structural aspects of these smectic phases.

  8. Statistical physics of non-thermal phase transitions from foundations to applications

    CERN Document Server

    Abaimov, Sergey G

    2015-01-01

    Statistical physics can be used to better understand non-thermal complex systems—phenomena such as stock-market crashes, revolutions in society and in science, fractures in engineered materials and in the Earth’s crust, catastrophes, traffic jams, petroleum clusters, polymerization, self-organized criticality and many others exhibit behaviors resembling those of thermodynamic systems. In particular, many of these systems possess phase transitions identical to critical or spinodal phenomena in statistical physics. The application of the well-developed formalism of statistical physics to non-thermal complex systems may help to predict and prevent such catastrophes as earthquakes, snow-avalanches and landslides, failure of engineering structures, or economical crises. This book addresses the issue step-by-step, from phenomenological analogies between complex systems and statistical physics to more complex aspects, such as correlations, fluctuation-dissipation theorem, susceptibility, the concept of free ener...

  9. Transition phases of zeolite Faujasite type to Sodalite by thermal treatment

    Directory of Open Access Journals (Sweden)

    Katia K. Kaminishikawahara

    2015-10-01

    Full Text Available The zeolites can have several functions as catalysts (biofuel production and molecular sieves (treatment of contaminated areas. This study aims to characterize the zeolites obtained in the transition of a Faujasite like zeolite into a Sodalite, when submitted to different thermal treatment times. The synthesized zeolites were characterized by X-ray diffraction where the crystalline phases were identified: Faujasite, Sodalite, SiO2 and amorphous material. The 4 hours heat treatment produces zeolite crystal structure similar to Faujasite, having basic sites, surface area of 552.7 m2 g-1 , and pore volume of 0.3391 cm3 g-1. With increasing time of heat treatment was observed the transition to the Sodalite phase witch containing 0.277 mmol g-1 of basic active sites with surface area of 11.38 m2 g-1 and pore volume of 0.0651 cm3 g-1. By the Rietveld method was identified and quantified the presence of Sodalite and Hidrossodalite in samples with 24 and 30 hours of reaction times.

  10. Glycolipid-based nanostructures with thermal-phase transition behavior functioning as solubilizers and refolding accelerators for protein aggregates.

    Science.gov (United States)

    Kameta, N; Matsuzawa, T; Yaoi, K; Fukuda, J; Masuda, M

    2017-05-03

    The self-assembly of synthetic glycolipids produced nanostructures such as vesicles and nanotubes consisting of bilayer membranes, which underwent a gel-to-liquid crystalline thermal phase transition. Vesicles formed at temperatures above the thermal phase transition temperatures (T g-l ) could solubilize aggregates of denatured proteins by trapping them in the fluid bilayer membranes. Cooling to temperatures below T g-l caused a morphological transformation into nanotubes that accompanied the thermal phase transition from the fluid to the solid state. This phenomenon allowed the trapped proteins to be quickly released into the bulk solution and simultaneously facilitated the refolding of the proteins. The refolding efficiency strongly depended on the electrostatic attraction between the bilayer membranes of the nanostructures and the proteins. Because of the long shape (>400 nm) of the nanotubes, simple membrane filtration through a pore size of 200 nm led to complete separation and recovery of the refolded proteins (3-9 nm sizes).

  11. Thermal conductivity at the amorphous-nanocrystalline phase transition in beech wood biocarbon

    Science.gov (United States)

    Parfen'eva, L. S.; Orlova, T. S.; Smirnov, B. I.; Smirnov, I. A.; Misiorek, H.; Jezowski, A.; Ramirez-Rico, J.

    2014-05-01

    High-porosity samples of beech wood biocarbon (BE-C) were prepared by pyrolysis at carbonization temperatures T carb = 650, 1300, and 1600°C, and their resistivity ρ and thermal conductivity κ were studied in the 5-300 and 80-300 K temperature intervals. The experimental results obtained were evaluated by invoking X-ray diffraction data and information on the temperature dependences ρ( T) and κ( T) for BE-C samples prepared at T carb = 800, 1000, and 2400°C, which were collected by the authors earlier. An analysis of the κ( T carb) behavior led to the conclusion that the samples under study undergo an amorphous-nanocrystalline phase transition in the interval 800°C < T carb < 1000°C. Evaluation of the electronic component of the thermal conductivity revealed that the Lorentz number of the sample prepared at T carb = 2400°C exceeds by far the classical Sommerfeld value, which is characteristic of metals and highly degenerate semiconductors.

  12. Thermal Properties of the Mixed n-Octadecane/Cu Nanoparticle Nanofluids during Phase Transition: A Molecular Dynamics Study

    Directory of Open Access Journals (Sweden)

    Qibin Li

    2017-01-01

    Full Text Available Paraffin based nanofluids are widely used as thermal energy storage materials and hold many applications in the energy industry. In this work, equilibrium and nonequilibrium molecular dynamics simulations are employed to study the thermal properties of the mixed nanofluids of n-octadecane and Cu nanoparticles during phase transition. Four different nanofluids systems with different mass ratios between the n-octadecane and Cu nanoparticles have been studied and the results show that Cu nanoparticles can improve the thermal properties of n-octadecane. The melting point, heat capacity and thermal conductivity of the mixed systems are decreased with the increasing of the mass ratio of n-octadecane.

  13. Thermal Properties of the Mixed n-Octadecane/Cu Nanoparticle Nanofluids during Phase Transition: A Molecular Dynamics Study.

    Science.gov (United States)

    Li, Qibin; Yu, Yinsheng; Liu, Yilun; Liu, Chao; Lin, Liyang

    2017-01-05

    Paraffin based nanofluids are widely used as thermal energy storage materials and hold many applications in the energy industry. In this work, equilibrium and nonequilibrium molecular dynamics simulations are employed to study the thermal properties of the mixed nanofluids of n -octadecane and Cu nanoparticles during phase transition. Four different nanofluids systems with different mass ratios between the n -octadecane and Cu nanoparticles have been studied and the results show that Cu nanoparticles can improve the thermal properties of n -octadecane. The melting point, heat capacity and thermal conductivity of the mixed systems are decreased with the increasing of the mass ratio of n -octadecane.

  14. Optical, thermal and phase transition studies in Sn1–xGexTe

    Indian Academy of Sciences (India)

    Unknown

    or TG/DTA studies cannot give the exact transition tem- perature when the material undergoes a phase transition and photoacoustics is the best tool for such studies. This we have demonstrated in our recent paper on L-alaninium oxalate (Sivabharathy et al 2004). The photoacoustic (PA) technique is one of the simplest and ...

  15. Constitutive model for a stress- and thermal-induced phase transition in a shape memory polymer

    International Nuclear Information System (INIS)

    Guo, Xiaogang; Liu, Liwu; Liu, Yanju; Zhou, Bo; Leng, Jinsong

    2014-01-01

    Recently, increasing applications of shape memory polymers have pushed forward the development of appropriate constitutive models for smart materials such as the shape memory polymer. During the heating process, the phase transition, which is a continuous time-dependent process, happens in the shape memory polymer, and various individual phases will form at different configuration temperatures. In addition, these phases can generally be divided into two parts: the frozen and active phase (Liu Y et al 2006 Int. J. Plast. 22 279–313). During the heating or cooling process, the strain will be stored or released with the occurring phase transition between these two parts. Therefore, a shape memory effect emerges. In this paper, a new type of model was developed to characterize the variation of the volume fraction in a shape memory polymer during the phase transition. In addition to the temperature variation, the applied stress was also taken as a significant influence factor on the phase transition. Based on the experimental results, an exponential equation was proposed to describe the relationship between the stress and phase transition temperature. For the sake of describing the mechanical behaviors of the shape memory polymer, a three-dimensional constitutive model was established. Also, the storage strain, which was the key factor of the shape memory effect, was also discussed in detail. Similar to previous works, we first explored the effect of applied stress on storage strain. Through comparisons with the DMA and the creep experimental results, the rationality and accuracy of the new phase transition and constitutive model were finally verified. (paper)

  16. Magnetic resonance in transverse-field Ising magnet LiHoF4 through quantum and thermal phase transitions

    Energy Technology Data Exchange (ETDEWEB)

    Kovacevic, Ivan; Babkevich, Peter; Chung, Mingee; Boero, Giovanni; Ronnow, Henrik [Ecole Polytechnique Federale de Lausanne (EPFL), Lausanne (Switzerland)

    2015-07-01

    Coplanar resonators and vector network analyzer (VNA) were used to measure the susceptibility in wide frequency range up to 6 GHz. The investigated temperatures from 0.2 K to 4.2 K and field range from 0 to 9 T cover the thermal transition into a ferromagnetically ordered phase below 1.53 K in zero-field as well as the quantum phase transition into a quantum-disordered paramagnetic phase above critical field 4.95 T at zero temperature. Entangled electro-nuclear states in LiHoF4 were probed by excitation field matching the hyperfine transitions at resonant frequencies. Absorption line was obtained by sweeping the transverse field at different frequencies. The model calculations within the mean-field approximation enable to track the evolution of the hyperfine levels as a function of field and temperature through quantum and thermal transitions, and show indeed excellent agreement with the experimental results. The presented methodology may find immediate applications to other important rare-earth containing materials such as spin ice, particularly close to the quantum phase transitions.

  17. TRANSITION AND DECOMPOSITION TEMPERATURES OF CEMENT PHASES - A COLLECTION OF THERMAL ANALYSIS DATA

    Directory of Open Access Journals (Sweden)

    Nick C. Collier

    2016-10-01

    Full Text Available Thermal analysis techniques provide the cement chemist with valuable tools to qualify and quantify the products formed during the hydration of cementitious materials. These techniques are commonly used alongside complimentary techniques such as X-ray diffraction and electron microscopy/energy dispersive spectroscopy to confirm the composition of phases present and identify amorphous material unidentified by other techniques. The most common thermal analysis techniques used by cement chemists are thermogravimetry, differential thermal analysis and differential scanning calorimetry. In order to provide a useful reference tool to the cement chemist, this paper provides a brief summary of the temperatures at which phase changes occur in the most common cement hydrates in the range 0-800°C in order to aid phase identification.

  18. Thermally Reversible and Irreversible Phase Transition Behaviors in Poly(ethylene oxide)/Ionic Liquid Mixtures.

    Science.gov (United States)

    Chen, Yunlei; Niu, Yanhua; Gong, Pengjian; Xiao, Zhilin; Li, Guangxian

    2017-12-01

    The irreversible and reversible phase transition behaviors during phase separation-recovery (heating-cooling) cycles for poly(ethylene oxide)/1-ethyl-3-methylimidazolium tetrafluoroborate ionic liquid (PEO/[EMIM][BF 4 ]) mixtures with a lower critical solution temperature phase diagram are reported for the first time. The evident differential scanning calorimetry endothermic and exothermic peaks are observed during the heating-cooling scan cycles near the phase boundary, in which the large heat loss for samples below the critical composition (60 wt% PEO) and obvious downward shift of phase transition temperature for all the compositions between the first and second cycles are particularly attractive. After the first recovery process, a reversible behavior during the next cycles is expected. These interesting phenomena are further confirmed by optical microscopy and Fourier-transform infrared measurements. It is demonstrated that the disruption and partial recovery of the hydrogen bonds, combined with the conformational change of PEO chains, can contribute to this irreversible behavior as well as a conversion to reversible phase transition behavior. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  19. Experimental Research on the Thermal Performance of Composite PCM Hollow Block Walls and Validation of Phase Transition Heat Transfer Models

    Directory of Open Access Journals (Sweden)

    Yuan Zhang

    2016-01-01

    Full Text Available A type of concrete hollow block with typical structure and a common phase change material (PCM were adopted. The PCM was filled into the hollow blocks by which the multiform composite PCM hollow blocks were made. The temperature-changing hot chamber method was used to test the thermal performance of block walls. The enthalpy method and the effective heat capacity method were used to calculate the heat transfer process. The results of the two methods can both reach the reasonable agreement with the experimental data. The unsteady-state thermal performance of the PCM hollow block walls is markedly higher than that of the wall without PCM. Furthermore, if the temperature of the PCM in the wall does not exceed its phase transition temperature range, the PCM wall can reach high thermal performance.

  20. Determination of thermal diffusivity at low temperature using the two-beam phase-lag photoacoustic method with observation of phase-transitions

    International Nuclear Information System (INIS)

    Jorge, M.P.P.

    1992-01-01

    This study consists of the determination of thermal diffusivity int he temperature range from 77 K to 300 K by the two-beam phase-lag photoacoustic method. Room temperature measurements of NTD (neutron transmutation doping) silicon suggest that the doping process does not affect its thermal properties. For the superconductor Y Ba 2 Cu 3 O 7 - x it has been verified that the sample density affects its thermal diffusivity. The validity of the experimental method on the Li K SO 4 crystal has been examined by using the thermal diffusivity of a Li F crystal and an Y 2 O 3 ceramic, at room temperature. The behavior of the thermal diffusivity as a function of the temperature for the Li K SO 4 crystal shows two anomalies which correspond at phase-transitions of this crystal in the studied temperature range. (author)

  1. Use of solid-state phase transitions for thermal energy storage. Final report, June 1, 1977--August 31, 1978

    Energy Technology Data Exchange (ETDEWEB)

    Leffler, A.J.; Myers, J.; Weinstein, D.

    1978-01-01

    A study has been carried out on the feasibility of using solid-state phase transitions for thermal energy storage. As part of this study a literature search was made to identify the most promising types of compounds and a synthesis program was carried out to prepare certain of these substances. In addition a large number of compounds for testing were obtained from commercial sources. All of the compounds were screened for transitions using a Perkin Elmer DSC-1B differential scanning calorimeter. From this program seven compounds were found that have transition energies from 20-30 cal/g in the temperatre range of 335-405 K. The most promising compound found is 5-norbornene-2,3-dicarboxylic acid anhydride having a transition of 22.6 cal/g at 366 K and an estimated cost of peparation of $0.40/lb..

  2. Understanding quantum phase transitions

    CERN Document Server

    Carr, Lincoln

    2010-01-01

    Quantum phase transitions (QPTs) offer wonderful examples of the radical macroscopic effects inherent in quantum physics: phase changes between different forms of matter driven by quantum rather than thermal fluctuations, typically at very low temperatures. QPTs provide new insight into outstanding problems such as high-temperature superconductivity and display fundamental aspects of quantum theory, such as strong correlations and entanglement. Over the last two decades, our understanding of QPTs has increased tremendously due to a plethora of experimental examples, powerful new numerical meth

  3. Thermal study of monovalent-divalent phase transition in npBifc-F{sub 1}TCNQ System

    Energy Technology Data Exchange (ETDEWEB)

    Sato, Michiko; Nishio, Yutaka; Kajita, Koji [Department of Physics, Faculty of Science, Toho University, Miyama 2-2-1, Funabashi, Chiba, 274-8510 (Japan); Mochida, Tomoyuki, E-mail: nishio@ph.sci.toho-u.ac.j [Department of Chemistry, Faculty of Science, Kobe University, Rokkodai, Nada, Kobe 657-8501 (Japan)

    2009-03-01

    In a new molecular solid composed of di-neopentyl-biferrocene (npBifc) and fluorotetracyanoquinodimethane (F{sub 1}TCNQ){sub 3}, Mochida reported the discovery of a reversible valence transfer that can be regarded as an 'ionic(I)-ionic(II)' phase transfer between the monovalent state (D{sup +}A{sup -}) and the divalent state (D{sup 2+}A{sup 2-}). We have studied thermo-dynamical properties of this transformation for this complex using the differential thermal analyses (DTA). We observed a broad excess specific heat with multi-peaks attributed to micro-domain structure over the corresponding temperature range (100-150K) accompanied by temperature hysteresis of 7K. The transition entropy (DELTAS) was determined to be 22 +- 2 J/mol-K and almost satisfied a Clausius-Clapeyron relation. These experimental results provide an experimental confirmation of the first order phase transition for the monovalent-divalent transfer. At the transition, we observe that the electronic degrees of freedom remained constant values, while large entropy absorbed crossing from low temperature phase to high temperature one is contributed by the lattice one. We finally estimated the internal energy and concluded that delicate energy valance between Madelung, ionization and affinity energies enable this system to exhibit a temperature induce monovalent-divalent phase transition.

  4. Thermal properties and phase transition in the fluoride, (NH{sub 4}){sub 3}SnF{sub 7}

    Energy Technology Data Exchange (ETDEWEB)

    Kartashev, A.V. [Kirensky Institute of Physics, Siberian Department of the Russian Academy of Sciences, 660036 Krasnoyarsk (Russian Federation); Astafijev Krasnoyarsk State Pedagogical University, 660049 Krasnoyarsk (Russian Federation); Gorev, M.V. [Kirensky Institute of Physics, Siberian Department of the Russian Academy of Sciences, 660036 Krasnoyarsk (Russian Federation); Institute of Engineering Physics and Radio Electronics, Siberian State University, 660074 Krasnoyarsk (Russian Federation); Bogdanov, E.V. [Kirensky Institute of Physics, Siberian Department of the Russian Academy of Sciences, 660036 Krasnoyarsk (Russian Federation); Krasnoyarsk State Agrarian University, 660049 Krasnoyarsk (Russian Federation); Flerov, I.N. [Kirensky Institute of Physics, Siberian Department of the Russian Academy of Sciences, 660036 Krasnoyarsk (Russian Federation); Institute of Engineering Physics and Radio Electronics, Siberian State University, 660074 Krasnoyarsk (Russian Federation); Laptash, N.M. [Institute of Chemistry, Far Eastern Department of the Russian Academy of Sciences, 690022 Vladivostok (Russian Federation)

    2016-05-15

    Calorimetric, dilatometric and differential thermal analysis studies were performed on (NH{sub 4}){sub 3}SnF{sub 7} for a wide range of temperatures and pressures. Large entropy (δS{sub 0}=22 J/mol K) and elastic deformation (δ(ΔV/V){sub 0}=0.89%) jumps have proven that the Pa-3↔Pm-3m phase transition is a strong first order structural transformation. A total entropy change of ΔS{sub 0}=32.5 J/mol K is characteristic for the order–disorder phase transition, and is equal to the sum of entropy changes in the related material, (NH{sub 4}){sub 3}TiF{sub 7}, undergoing transformation between the two cubic phases through the intermediate phases. Hydrostatic pressure decreases the stability of the high temperature Pm-3m phase in (NH{sub 4}){sub 3}SnF{sub 7}, contrary to (NH{sub 4}){sub 3}TiF{sub 7}, characterised by a negative baric coefficient. The effect of experimental conditions on the chemical stability of (NH{sub 4}){sub 3}SnF{sub 7} was observed. - Graphical abstract: Strong first order structural transformation Pa-3↔Pm-3m in (NH{sub 4}){sub 3}SnF{sub 7} is associated with very large total entropy change of ΔS{sub 0}=32.5 J/mol K characteristic for the ordering processes and equal to the sum of entropy changes in the related (NH{sub 4}){sub 3}TiF{sub 7} undergoing transformation between the same two cubic phases through the intermediate phases. - Highlights: • (NH{sub 4}){sub 3}SnF{sub 7} undergoes strong first order Pa-3↔Pm-3m phase transition. • Anomalous behaviour of ΔC{sub p} and ΔV/V exists far below phase transition temperature. • Structural distortions are accompanied by huge total entropy change ΔS≈Rln50. • High pressure strongly increases the stability of Pa-3 phase in (NH{sub 4}){sub 3}SnF{sub 7}. • Entropy of the Pa-3↔Pm-3m phase transition does not depend on pressure.

  5. Composition dependent phase transition and its induced hysteretic effect in the thermal conductivity of WxMo1-xTe2

    Science.gov (United States)

    Yan, Xue-Jun; Lv, Yang-Yang; Li, Lei; Li, Xiao; Yao, Shu-Hua; Chen, Yan-Bin; Liu, Xiao-Ping; Lu, Hong; Lu, Ming-Hui; Chen, Yan-Feng

    2017-05-01

    Recently, transition metal dichalcogenide (TMD) materials have shown promise in electronics and optoelectronics applications. Most of their properties are closely related to their abundant structural phases and phase transitions. For more practical applications in the future, it is necessary to tune the phase transitions in this material system. Here, we demonstrate the modulation of phase transitions in miscible WxMo1-xTe2 samples by appropriate alloying. The temperature dependent thermal conductivity along the c-axis, which strongly relates to the phase structures and the defect level, has been measured using the time-domain thermoreflectance method. In addition, a tunable hysteretic effect, induced by phase transitions, is observed in both thermal and electrical transport properties and confirmed by the consistent hysteresis in the Raman spectroscopic study. This hysteretic effect can be applied to realize phase-change storage devices. Furthermore, we provide a phase diagram to illustrate the composition dependent phase transition in WxMo1-xTe2. This work demonstrates an approach to modulate phase transition and thermal hysteresis in such a TMD material system by alloying engineering.

  6. Effects of B2/B19′ phase boundary on thermally induced phase transition in NiTi: An atomistic study

    Energy Technology Data Exchange (ETDEWEB)

    Qin, Sheng-Jian [School of Materials Science and Engineering, Beihang University, Beijing 100191 (China); Shang, Jia-Xiang, E-mail: shangjx@buaa.edu.cn [School of Materials Science and Engineering, Beihang University, Beijing 100191 (China); Wang, Xu [School of Materials Science and Engineering, Beihang University, Beijing 100191 (China); Wang, Fu-He [Department of Physics, Capital Normal University, Beijing 100048 (China)

    2015-10-30

    Highlights: • A new order parameter is created to characterize the local atom structure. • Heterogeneous nucleation of B2 phase occurs at high temperatures in B2/B19′ phase boundary system. • B2/B19′ phase boundary provides the sites for heterogeneous B2 nucleation at high temperatures. • Homogeneous nucleation of B19′ phase occurs at low temperatures in B2/B19′ phase boundary system. • B2 and B19′ phases coexist at medium temperatures. - Abstract: Molecular dynamics simulations are performed to study the thermally induced phase transition in NiTi B19′ single crystal at high temperatures (400, 500, 600 and 700 K), B2 single crystal at low temperatures (50, 100, 150 and 200 K) and the system containing a B2/B19′ phase boundary at high, medium (300, 320 and 340 K) and low temperatures. Homogeneous nucleation and growth of the B2 and the B19′ phases are observed in B19′ and B2 single crystal systems, respectively. In B2/B19′ system, heterogeneous nucleation and growth of the B2 phase are observed at high temperatures, which results in forming a B2/B2 grain boundary and a new B2/B19′ phase boundary; the B2 phase transforms homogeneously to B19′ phase at low temperatures; the B2 and B19′ phases coexist without heterogeneous nucleation of any phase at medium temperatures. Compared with the single crystal, the B2/B19′ phase boundary provides the sites for heterogeneous B2 nucleation at high temperatures and has little effect on the phase transition at low temperatures.

  7. MIIGe(PO 4) 2 ( M=Ca, Sr, Ba): Crystal structure, phase transitions and thermal expansion

    Science.gov (United States)

    Popa, Karin; Wallez, Gilles; Bregiroux, Damien; Loiseau, Pascal

    2011-10-01

    Three earth alkali-germanium monophosphates MIIGe(PO 4) 2 ( M=Ca, Sr, Ba) were prepared by solid state reaction and their structures, previously unknown, studied by Rietveld analysis. BaGe(PO 4) 2 and high-temperature β-SrGe(PO 4) 2 (space group C2/ m, Z=2) are fully isotypic with yavapaiite, whereas CaGe(PO 4) 2 and low-temperature α-SrGe(PO 4) 2 ( C2/ c, Z=4) are distorted derivatives. The phase transition between the two forms is observed for the first time. The thermal expansion, resulting from several structural mechanisms, is very anisotropic.

  8. Phase transition and thermal expansion studies of alumina thin films prepared by reactive pulsed laser deposition.

    Science.gov (United States)

    Balakrishnan, G; Thirumurugesan, R; Mohandas, E; Sastikumar, D; Kuppusami, P; Songl, J I

    2014-10-01

    Aluminium oxide (Al2O3) thin films were deposited on Si (100) substrates at an optimized oxygen partial pressure of 3 x 10(-3) mbar at room temperature by pulsed laser deposition (PLD). The films were characterized by high temperature X-ray diffraction (HTXRD), field emission scanning electron microscopy (FESEM) and atomic force microscopy (AFM). The HTXRD pattern showed the cubic y-Al2O3 phase in the temperature range 300-973 K. At temperatures ≥ 1073 K, the δ and θ-phases of Al2O3 were observed. The mean linear thermal expansion coefficient and volume thermal expansion coefficient of γ-Al2O3 was found to be 12.66 x 10(-6) K(-1) and 38.87 x 10(-6) K(-1) in the temperature range 300 K-1073 K. The field emission scanning electron microscopy revealed a smooth and structureless morphology of the films deposited on Si (100). The atomic force microscopy study indicated the increased crystallinity and surface roughness of the films after annealing at high temperature.

  9. The formation of α-phase SnS nanorods by PVP assisted polyol synthesis: Phase stability, micro structure, thermal stability and defects induced energy band transitions

    Energy Technology Data Exchange (ETDEWEB)

    Baby, Benjamin Hudson; Mohan, D. Bharathi, E-mail: d.bharathimohan@gmail.com

    2017-05-01

    We report the formation of single phase of SnS nanostructure through PVP assisted polyol synthesis by varying the source concentration ratio (Sn:S) from 1:1M to 1:12M. The effect of PVP concentration and reaction medium towards the preparation of SnS nanostructure is systematically studied through confocal Raman spectrometer, X-ray diffraction, thermogravimetry analysis, scanning electron microscope, transmission electron microscopy, X-ray photoelectron spectroscopy, UV–Vis–NIR absorption and fluorescence spectrophotometers. The surface morphology of SnS nanostructure changes from nanorods to spherical shape with increasing PVP concentration from 0.15M to 0.5M. Raman analysis corroborates that Raman active modes of different phases of Sn-S are highly active when Raman excitation energy is slightly greater than the energy band gap of the material. The presence of intrinsic defects and large number of grain boundaries resulted in an improved thermal stability of 20 °C during the phase transition of α-SnS. Band gap calculation from tauc plot showed the direct band gap of 1.5 eV which is attributed to the single phase of SnS, could directly meet the requirement of an absorber layer in thin film solar cells. Finally, we proposed an energy band diagram for as synthesized single phase SnS nanostructure based on the experimental results obtained from optical studies showing the energy transitions attributed to band edge transition and also due to the presence of intrinsic defects. - Highlights: • PVP stabilizes the orthorhombic (α) phase of SnS. • Optical band gap of P type SnS tuned by PVP for photovoltaic applications. • The formation of Sn rich SnS phase is investigated through XPS analysis. • Intrinsic defects enhance the thermal stability of α-SnS. • The feasibility of energy transition liable to point defects is discussed.

  10. Emergence and seismological implications of phase transition and universality in a system with interaction between thermal pressurization and dilatancy.

    Science.gov (United States)

    Suzuki, Takehito

    2017-08-01

    A dynamic earthquake source process is modeled by assuming interaction among frictional heat, fluid pressure, and inelastic porosity. In particular, fluid pressure increase due to frictional heating (thermal pressurization effect) and fluid pressure decrease due to inelastic porosity increase (dilatancy effect) play important roles in this process. Two nullclines become exactly the same in the system of governing equations, which generates non-isolated fixed points in the phase space. These lead to a type of phase transition, which produces a universality described by the power law between the initial value of one variable and the final value of the other variable. The universal critical exponent is found to be 1/2, which is independent of the details of the porosity evolution law. We can regard the dynamic earthquake slip process as a phase transition by considering the final porosity or slip as the order parameter. Physical prediction of phase emergence is difficult because the porosity evolution law has uncertainties, and the final slip amount is difficult to predict because of the universality. Finally, nonlinear mathematical application of the result is also discussed.

  11. Selective crystal growth of polymorphs and crystal-to-crystal thermal phase transition of non-peripherally alkyl-substituted phthalocyanine and tetrabenzotriazaporphyrin

    Science.gov (United States)

    Ohmori, Masashi; Nakano, Chika; Fujii, Akihiko; Shimizu, Yo; Ozaki, Masanori

    2017-06-01

    Selective crystal growth of polymorphs and crystal-to-crystal thermal phase transition of non-peripherally alkyl-substituted macrocycle molecules, such as octapentylphthalocyanine (C5PcH2), octahexylphthalocyanine (C6PcH2), and octahexyltetrabenzotriazaporphyrin (C6TBTAPH2) have been investigated. Two types of single crystals, called α-type and β-type, were separately grown by controlling the recrystallization conditions, and the crystal structures were determined by single-crystal X-ray structure analysis. The irreversible crystal-to-crystal thermal phase transition from α-type to β-type were observed by the differential scanning calorimetry and temperature-controlled X-ray structure analysis. The selective crystal growth of the α-type or β-type and the irreversible crystal-to-crystal thermal phase transition have been discussed by taking the alkyl-substituent distribution into consideration.

  12. Thermal Phase Transitions of Strongly Correlated Bosons with Spin-Orbit Coupling

    Science.gov (United States)

    Hickey, Ciarán; Paramekanti, Arun

    2014-12-01

    Experiments on ultracold atoms have started to explore lattice effects and thermal fluctuations for two-component bosons with spin-orbit coupling (SOC). Motivated by this, we derive and study a t J model for lattice bosons with equal Rashba-Dresselhaus SOC and strong Hubbard repulsion in a uniform Zeeman magnetic field. Using the Gutzwiller ansatz, we find strongly correlated ground states with stripe superfluid (SF) order. We formulate a finite temperature generalization of the Gutzwiller method, and show that thermal fluctuations in the doped Mott insulator drive a two-step melting of the stripe SF, revealing a wide regime of a stripe normal fluid.

  13. Learning phase transitions by confusion

    Science.gov (United States)

    van Nieuwenburg, Evert P. L.; Liu, Ye-Hua; Huber, Sebastian D.

    2017-02-01

    Classifying phases of matter is key to our understanding of many problems in physics. For quantum-mechanical systems in particular, the task can be daunting due to the exponentially large Hilbert space. With modern computing power and access to ever-larger data sets, classification problems are now routinely solved using machine-learning techniques. Here, we propose a neural-network approach to finding phase transitions, based on the performance of a neural network after it is trained with data that are deliberately labelled incorrectly. We demonstrate the success of this method on the topological phase transition in the Kitaev chain, the thermal phase transition in the classical Ising model, and the many-body-localization transition in a disordered quantum spin chain. Our method does not depend on order parameters, knowledge of the topological content of the phases, or any other specifics of the transition at hand. It therefore paves the way to the development of a generic tool for identifying unexplored phase transitions.

  14. Martensitic phase transitions

    Energy Technology Data Exchange (ETDEWEB)

    Petry, W.; Neuhaus, J. [Techn. Universitaet Muenchen, Physik Department E13, Munich (Germany)

    1996-11-01

    Many elements transform from a high temperature bcc phase to a more dense packed temperature phase. The great majority of these transitions are of 1st order, displacive and reconstructive. The lattice potentials which govern these martensitic transitions can be probed by inelastic neutron scattering, thereby answering fundamental questions like : Will the transition be announced by dynamical or static fluctuations? What are the trajectories for the displacements needed for the transformation? Does the vibrational entropy stabilize the high temperature phase? Are the unusual transport properties in these materials related to their ability to transform? (author) 17 figs., 1 tab., 46 refs.

  15. Cosmological phase transitions

    International Nuclear Information System (INIS)

    Kolb, E.W.

    1987-01-01

    If the universe stated from conditions of high temperature and density, there should have been a series of phase transitions associated with spontaneous symmetry breaking. The cosmological phase transitions could have observable consequences in the present Universe. Some of the consequences including the formation of topological defects and cosmological inflation are reviewed here. One of the most important tools in building particle physics models is the use of spontaneous symmetry breaking (SSB). The proposal that there are underlying symmetries of nature that are not manifest in the vacuum is a crucial link in the unification of forces. Of particular interest for cosmology is the expectation that are the high temperatures of the big bang symmetries broken today will be restored, and that there are phase transitions to the broken state. The possibility that topological defects will be produced in the transition is the subject of this section. The possibility that the Universe will undergo inflation in a phase transition will be the subject of the next section. Before discussing the creation of topological defects in the phase transition, some general aspects of high-temperature restoration of symmetry and the development of the phase transition will be reviewed. 29 references, 1 figure, 1 table

  16. Phase transitions modern applications

    CERN Document Server

    Gitterman, Moshe

    2014-01-01

    This book provides a comprehensive review of the theory of phase transitions and its modern applications, based on the five pillars of the modern theory of phase transitions i.e. the Ising model, mean field, scaling, renormalization group and universality. This expanded second edition includes, along with a description of vortices and high temperature superconductivity, a discussion of phase transitions in chemical reaction and moving systems. The book covers a close connection between phase transitions and small world phenomena as well as scale-free systems such as the stock market and the Internet. Readership: Scientists working in different fields of physics, chemistry, biology and economics as well as teaching material for undergraduate and graduate courses.

  17. Non-linear thermal evolution of the crystal structure and phase transitions of LaFeO{sub 3} investigated by high temperature X-ray diffraction

    Energy Technology Data Exchange (ETDEWEB)

    Selbach, Sverre M.; Tolchard, Julian R.; Fossdal, Anita [Department of Materials Science and Engineering, Norwegian University of Science and Technology, NO-7491 Trondheim (Norway); Grande, Tor, E-mail: grande@ntnu.no [Department of Materials Science and Engineering, Norwegian University of Science and Technology, NO-7491 Trondheim (Norway)

    2012-12-15

    The crystal structure, anisotropic thermal expansion and structural phase transition of the perovskite LaFeO{sub 3} has been studied by high-temperature X-ray diffraction from room temperature to 1533 K. The structural evolution of the orthorhombic phase with space group Pbnm and the rhombohedral phase with R3{sup Macron }c structure of LaFeO{sub 3} is reported in terms of lattice parameters, thermal expansion coefficients, atomic positions, octahedral rotations and polyhedral volumes. Non-linear lattice expansion across the antiferromagnetic to paramagnetic transition of LaFeO{sub 3} at T{sub N}=735 K was compared to the corresponding behavior of the ferroelectric antiferromagnet BiFeO{sub 3} to gain insight to the magnetoelectric coupling in BiFeO{sub 3}, which is also multiferroic. The first order phase transition of LaFeO{sub 3} from Pbnm to R3{sup Macron }c was observed at 1228{+-}9 K, and a subsequent transition to Pm3{sup Macron }m was extrapolated to occur at 2140{+-}30 K. The stability of the Pbnm and R3{sup Macron }c polymorphs of LaFeO{sub 3} is discussed in terms of the competing enthalpy and entropy of the two crystal polymorphs and the thermal evolution of the polyhedral volume ratio V{sub A}/V{sub B}. - Graphical abstract: Aniostropic thermal evolution of the lattice parameters and phase transition of LaFeO{sub 3}. Highlights: Black-Right-Pointing-Pointer The crystal structure of LaFeO{sub 3} is studied by HTXRD from RT to 1533 K. Black-Right-Pointing-Pointer A non-linear expansion across the Neel temperature is observed for LaFeO{sub 3}. Black-Right-Pointing-Pointer The ratio V{sub A}/V{sub B} is used to rationalize the thermal evolution of the structure.

  18. Non-linear thermal evolution of the crystal structure and phase transitions of LaFeO3 investigated by high temperature X-ray diffraction

    International Nuclear Information System (INIS)

    Selbach, Sverre M.; Tolchard, Julian R.; Fossdal, Anita; Grande, Tor

    2012-01-01

    The crystal structure, anisotropic thermal expansion and structural phase transition of the perovskite LaFeO 3 has been studied by high-temperature X-ray diffraction from room temperature to 1533 K. The structural evolution of the orthorhombic phase with space group Pbnm and the rhombohedral phase with R3 ¯ c structure of LaFeO 3 is reported in terms of lattice parameters, thermal expansion coefficients, atomic positions, octahedral rotations and polyhedral volumes. Non-linear lattice expansion across the antiferromagnetic to paramagnetic transition of LaFeO 3 at T N =735 K was compared to the corresponding behavior of the ferroelectric antiferromagnet BiFeO 3 to gain insight to the magnetoelectric coupling in BiFeO 3 , which is also multiferroic. The first order phase transition of LaFeO 3 from Pbnm to R3 ¯ c was observed at 1228±9 K, and a subsequent transition to Pm3 ¯ m was extrapolated to occur at 2140±30 K. The stability of the Pbnm and R3 ¯ c polymorphs of LaFeO 3 is discussed in terms of the competing enthalpy and entropy of the two crystal polymorphs and the thermal evolution of the polyhedral volume ratio V A /V B . - Graphical abstract: Aniostropic thermal evolution of the lattice parameters and phase transition of LaFeO 3 . Highlights: ► The crystal structure of LaFeO 3 is studied by HTXRD from RT to 1533 K. ► A non-linear expansion across the Néel temperature is observed for LaFeO 3 . ► The ratio V A /V B is used to rationalize the thermal evolution of the structure.

  19. Anisotropic thermal properties and ferroelectric phase transitions in layered CuInP2S6 and CuInP2Se6 crystals

    Science.gov (United States)

    Liubachko, V.; Shvalya, V.; Oleaga, A.; Salazar, A.; Kohutych, A.; Pogodin, A.; Vysochanskii, Yu. M.

    2017-12-01

    Thermal diffusivity and thermal conductivity have been studied for the layered crystals CuInP2S6, CuInP2Se6 from 30 K to 350 K, showing a relevant thermal anisotropy. Heat is much more efficiently transferred within the layers than perpendicular to them. The ferrielectric transition in CuInP2S6 is proven to be clearly first order while the ferroelectric one in CuInP2Se6 has a weak first order character. The behavior of the thermal conductivity as a function of temperature in the ferroelectric phases shows that heat conduction is phonon driven. Disorder in the paraelectric phases due to hopping motions of Cu ions significantly reduces the thermal conductivity to extremely low values.

  20. Thermoanalytical studies of carbamazepine: hydration/dehydration, thermal decomposition, and solid phase transitions

    Directory of Open Access Journals (Sweden)

    Mônia Aparecida Lemos Pinto

    2014-12-01

    Full Text Available Carbamazepine (CBZ, a widely used anticonvulsant drug, can crystallize and exhibits four polymorphic forms and one dihydrate. Anhydrous CBZ can spontaneously absorb water and convert to the hydrate form whose different crystallinity leads to lower biological activity. The present study was concerned to the possibility of recovering the hydrated form by heating. The thermal behavior of spontaneously hydrated carbamazepine was investigated by TG/DTG-DTA and DSC in dynamic atmospheres of air and nitrogen, which revealed that the spontaneous hydration of this pharmaceutical resulted in a Form III hydrate with 1.5 water molecules. After dehydration, this anhydrous Form III converted to Form I, which melted and decomposed in a single event, releasing isocyanic acid, as shown by evolved gas analysis using TG-FTIR. Differential scanning calorimetry analyses revealed that Form III melted and crystallized as Form I, and that subsequent cooling cycles only generated Form I by crystallization. Solid state decomposition kinetic studies showed that there was no change in the substance after the elimination of water by heating to 120 °C. Activation energies of 98 ± 2 and 93 ± 2 kJ mol-1 were found for the hydrated and dried samples, respectively, and similar profiles of activation energy as a function of conversion factor were observed for these samples.

  1. paraelectric phase transition

    Indian Academy of Sciences (India)

    at% of La, x = 3, 5, 6, 10 and 12] have been measured in the frequency range 1 Hz–1 MHz using the vector impedance ... The ferroelectric phase transition is diffuse in nature and broadening of the peak increases with La content. Keywords. PLZT ..... formation from rhombohedral–tetragonal–cubic phase with increase in ...

  2. On the theory of dynamical scattering of thermal neutrons by nearly perfect α-Fe2O3 crystals near the Morine phase transition

    International Nuclear Information System (INIS)

    Chukhovskij, F.N.; Nosik, V.L.

    1994-01-01

    On the base of an exact solution of the dynamic problem of scattering is analyzed the thermal neutron diffraction due to magnetic interaction by the reorientational transition (Morine transition) in a nearly perfect crystal of hematite. It is shown that in dependence on the value and direction of an external magnetic field the diffraction scattering character is changed substantially. Formulae are obtained and calculations are fulfilled of the diffraction integral intensity (DII) as a temperature function near the Morine phase transition. DII calculation results are compared with experimental data

  3. Phase transitions in nuclear physics

    Energy Technology Data Exchange (ETDEWEB)

    Moretto, L.G.; Phair, L.; Wozniak, G.J.

    1997-08-01

    A critical overview of the low energy phase transitions in nuclei is presented with particular attention to the 2nd (1st) order pairing phase transitions, and to the 1st order liquid-vapor phase transition. The role of fluctuations in washing out these transitions is discussed and illustrated with examples. A robust indicator of phase coexistence in multifragmentation is presented.

  4. Electronic phase transitions

    CERN Document Server

    Kopaev, YuV

    1992-01-01

    Electronic Phase Transitions deals with topics, which are presently at the forefront of scientific research in modern solid-state theory. Anderson localization, which has fundamental implications in many areas of solid-state physics as well as spin glasses, with its influence on quite different research activities such as neural networks, are two examples that are reviewed in this book. The ab initio statistical mechanics of structural phase transitions is another prime example, where the interplay and connection of two unrelated disciplines of solid-state theory - first principle ele

  5. Photoinduced phase transitions

    CERN Document Server

    Nasu, K

    2004-01-01

    A new class of insulating solids was recently discovered. Whenirradiated by a few visible photons, these solids give rise to amacroscopic excited domain that has new structural and electronicorders quite different from the starting ground state. This occurrenceis called "photoinduced phase transition", and this multi-authoredbook reviews recent theoretical and experimental studies of this newphenomenon.

  6. Phase transitions and electrical conduction in thermal energy storage compound (n-C12H25NH3)2CdCl4

    Science.gov (United States)

    Mahmoud Abdelkader, Mohamed; Aboud, Aboud Ibrahim; Gamal, Wafia Mohamed

    2015-05-01

    Differential scanning calorimetry (DSC) and differential thermal analysis (DTA) are performed for the compound (n-C12H25NH3)2CdCl4. The ac conductivity σ(ω,T), and the complex dielectric permittivity ɛ*(ω,T) are measured as a function of temperature (100 K < T < 375 K) and at some selected frequencies (3 → 100 kHz). Two structural phase transitions are detected at T = (330 ± 1) K and T = (343 ± 1) K as minor and major transitions, respectively. The analysis of the measured electrical parameters reveals that the frequency-dependent conductivity obeys the power law, and the quantum mechanical tunneling (QMT) model is the main conduction mechanism in the low-temperature phase (LTP; phase III). The role of hydrogen bond N-H…Cl as a trigger force for phase transitions has been discussed. While the LTP is of the order-disorder type, the high-temperature phase (HTP) or phase I seems to be conformational and represents the main transition.

  7. Determination of Thermal Expansion Coefficients and Locating the Temperature-Induced Phase Transition in Methylammonium Lead Perovskites Using X-ray Diffraction.

    Science.gov (United States)

    Jacobsson, T Jesper; Schwan, L Josef; Ottosson, Mikael; Hagfeldt, Anders; Edvinsson, Tomas

    2015-11-16

    Lead halogen perovskites, and particularly methylammonium lead iodine, CH3NH3PbI3, have recently attracted considerable interest as alternative solar cell materials, and record solar cell efficiencies have now surpassed 20%. Concerns have, however, been raised about the thermal stability of methylammonium lead iodine, and a phase transformation from a tetragonal to a cubic phase has been reported at elevated temperature. Here, this phase transition has been investigated in detail using temperature-dependent X-ray diffraction measurements. The phase transformation is pinpointed to 54 °C, which is well within the normal operating range of a typical solar cell. The cell parameters were extracted as a function of the temperature, from which the thermal expansion coefficient was calculated. The latter was found to be rather high (αv = 1.57 × 10(-4) K(-1)) for both the tetragonal and cubic phases. This is 6 times higher than the thermal expansion coefficient for soda lime glass and CIGS and 11 times larger than that of CdTe. This could potentially be of importance for the mechanical stability of perovskite solar cells in the temperature cycling experienced under normal day-night operation. The experimental knowledge of the thermal expansion coefficients and precise determination of the cell parameters can potentially also be valuable while conducting density functional theory simulations on these systems in order to deliver more accurate band structure calculations.

  8. Effect of Si additions on thermal stability and the phase transition sequence of sputtered amorphous alumina thin films

    Energy Technology Data Exchange (ETDEWEB)

    Bolvardi, H.; Baben, M. to; Nahif, F.; Music, D., E-mail: music@mch.rwth-aachen.de; Schnabel, V.; Shaha, K. P.; Mráz, S.; Schneider, J. M. [Materials Chemistry, RWTH Aachen University, Kopernikusstr. 10, D-52074 Aachen (Germany); Bednarcik, J.; Michalikova, J. [Deutsches Elektronen Synchrotron DESY, FS-PE group, Notkestrasse 85, D-22607 Hamburg (Germany)

    2015-01-14

    Si-alloyed amorphous alumina coatings having a silicon concentration of 0 to 2.7 at. % were deposited by combinatorial reactive pulsed DC magnetron sputtering of Al and Al-Si (90-10 at. %) split segments in Ar/O{sub 2} atmosphere. The effect of Si alloying on thermal stability of the as-deposited amorphous alumina thin films and the phase formation sequence was evaluated by using differential scanning calorimetry and X-ray diffraction. The thermal stability window of the amorphous phase containing 2.7 at. % of Si was increased by more than 100 °C compared to that of the unalloyed phase. A similar retarding effect of Si alloying was also observed for the α-Al{sub 2}O{sub 3} formation temperature, which increased by more than 120 °C. While for the latter retardation, the evidence for the presence of SiO{sub 2} at the grain boundaries was presented previously, this obviously cannot explain the stability enhancement reported here for the amorphous phase. Based on density functional theory molecular dynamics simulations and synchrotron X-ray diffraction experiments for amorphous Al{sub 2}O{sub 3} with and without Si incorporation, we suggest that the experimentally identified enhanced thermal stability of amorphous alumina with addition of Si is due to the formation of shorter and stronger Si–O bonds as compared to Al–O bonds.

  9. Assessing the Thermal Conductivity of Cu2-xSe Alloys Undergoing a Phase Transition via the Simultaneous Measurement of Thermoelectric Parameters by a Harman-Based Setup

    Science.gov (United States)

    Vasilevskiy, D.; Keshavarz, M. K.; Simard, J.-M.; Masut, R. A.; Turenne, S.; Snyder, G. J.

    2018-01-01

    Some materials such as Cu2-xSe, Cu1.97Ag0.03Se, and SnSe have attracted attention by demonstrating a significant enhancement of their thermoelectric performance, which is associated with a phase transition. This phenomenon, observed in a limited temperature (T) interval, results in sharp changes of the Seebeck coefficient (S), the electrical resistivity (ρ), and the thermal conductivity (κ), which may render the correct evaluation of the dimensionless figure of merit (ZT) difficult. We report the thermoelectric properties of a polycrystalline Cu2-xSe sample which is known to undergo a phase transition near 410 K, containing a mixture of α- and β-phases at room temperature, as determined by x-ray diffraction measurements. We have used a Harman-based setup (TEMTE Inc.), which assures the direct measurement of ZT at all temperatures, including the phase transition region. This approach ensures that κ(T) is determined under steady-state conditions at any given temperature, including points arbitrarily close to the transition temperature which cannot be guaranteed by previously used techniques such as laser flash. We have observed a sharp maximum for κ(T) near 410 K, similar to the reported specific heat variation, with a ZT peak value of 0.2 at 400 K. The expected gain in ZT related to the phase transition is reduced because the increase in S is counterbalanced by the increase in κ(T). Thus, our detailed assessment of the temperature variation of the individual thermoelectric properties accurately evaluates the performance enhancement associated to a structural phase transition and helps to elucidate this complex phenomenon.

  10. Thermally activated proton hopping in lawsonite, the ferroelectric transition at 125 K, and the co-elastic phase transition at 270 K

    International Nuclear Information System (INIS)

    Salje, E K H; Carpenter, M A

    2011-01-01

    Lawsonite, CaAl 2 Si 2 O 7 (OH) 2 H 2 O, is a novel ferroelectric material which is dominated by ordering and disordering of protons. We report related elastic anomalies in lawsonite. A new approach to extracting acoustic data from resonant ultrasonic spectroscopy has been applied to investigate the ordering and disordering of protons. This approach is based on analysis of entire spectra, rather than the more conventional fitting of individual resonance peaks and captures three features of the transitions. Firstly, structural disorder of protons persists down to low temperatures. Secondly, the structural transition between two paraelectric phases near 270 K is mainly of the order/disorder type but is not directly coupled to the proton mobility. Thirdly, the ferroelectric transition at 125 K shows a direct link with the proton mobility with an activation energy of 0.03 eV. The latter transition occurs in the large class of ferroelectric crystals where the molecular groups are linked by hydrogen and its thermodynamic potential is almost identical to that of KDP (KH 2 PO 4 ), albeit with a smaller isotope effect. While some damping is seen in small temperature intervals below the transition points, these anomalies are much smaller than those that occur at ferroelastic phase transitions. (fast track communication)

  11. Anomalous thermal expansion, negative linear compressibility, and high-pressure phase transition in ZnAu2(CN) 4 : Neutron inelastic scattering and lattice dynamics studies

    Science.gov (United States)

    Gupta, Mayanak K.; Singh, Baltej; Mittal, Ranjan; Zbiri, Mohamed; Cairns, Andrew B.; Goodwin, Andrew L.; Schober, Helmut; Chaplot, Samrath L.

    2017-12-01

    We present temperature-dependent inelastic-neutron-scattering measurements, accompanied by ab initio calculations of the phonon spectra and elastic properties as a function of pressure to quantitatively explain an unusual combination of negative thermal expansion and negative linear compressibility behavior of ZnAu2(CN) 4 . The mechanism of the negative thermal expansion is identified in terms of specific anharmonic phonon modes that involve bending of the -Zn-NC-Au-CN-Zn- linkage. The soft phonon at the L point at the Brillouin zone boundary quantitatively relates to the high-pressure phase transition at about 2 GPa. The ambient pressure structure is also found to be close to an elastic instability that leads to a weakly first-order transition.

  12. Stearic-acid/carbon-nanotube composites with tailored shape-stabilized phase transitions and light–heat conversion for thermal energy storage

    International Nuclear Information System (INIS)

    Li, Benxia; Nie, Shibin; Hao, Yonggan; Liu, Tongxuan; Zhu, Jinbo; Yan, Shilong

    2015-01-01

    Highlights: • A facile preparation of shape-stabilized composite PCMs for thermal energy storage. • The composite PCMs present tunable phase change temperatures and enthalpy. • Sunlight-driven phase change for photothermal conversion and storage. - Abstract: The development of functional materials with both light–heat conversion and thermal energy storage properties is of crucial importance for efficient utilization of sunlight to meet the growing demand for sustainable energy. In this work, the shape-stabilized phase change composites were designed and prepared by integration of stearic acid (SA) and acid-treated carbon nanotubes (a-CNTs). The a-CNTs not only acted as a flexible matrix but also endowed the composites high light–heat conversion ability. The reversible phase transitions shifted from high temperatures (T m = 74 °C, T f = 57 °C) of pure SA to near room temperature (T m = ∼30 °C, T f = ∼22 °C) of SA/a-CNTs composites, probably resulting from the strong interface confinement effect. The phase change enthalpy of the SA/a-CNTs composite could also be tailored by changing the mass ratio of SA and a-CNTs. The composites containing SA of 54.2 wt.%, 67.8 wt.% and 79.5 wt.% presented the melting enthalpy of 76.3 J/g, 98.8 J/g and 111.8 J/g, respectively. Moreover, the phase transition of SA/a-CNTs composite could be driven by sunlight for the energy storage/release. Therefore, this research provides a new platform for improving solar utilization, and understanding the phase transition behaviors of organic PCMs in dimensionally confined environments as well

  13. Silicide induced surface defects in FePt nanoparticle fcc-to-fct thermally activated phase transition

    International Nuclear Information System (INIS)

    Chen, Shu; Lee, Stephen L.; André, Pascal

    2016-01-01

    Magnetic nanoparticles (MnPs) are relevant to a wide range of applications including high density information storage and magnetic resonance imaging to name but a few. Among the materials available to prepare MnPs, FePt is attracting growing attention. However, to harvest the strongest magnetic properties of FePt MnPs, a thermal annealing is often required to convert face-centered cubic as synthesized nPs into its tetragonal phase. Rarely addressed are the potential side effects of such treatments on the magnetic properties. In this study, we focus on the impact of silica shells often used in strategies aiming at overcoming MnP coalescence during the thermal annealing. While we show that this shell does prevent sintering, and that fcc-to-fct conversion does occur, we also reveal the formation of silicide, which can prevent the stronger magnetic properties of fct-FePt MnPs from being fully realised. This report therefore sheds lights on poorly investigated and understood interfacial phenomena occurring during the thermal annealing of MnPs and, by doing so, also highlights the benefits of developing new strategies to avoid silicide formation.

  14. Neutron Diffraction Measurements and First Principles Study of Thermal Motion of Atoms in Select M_{n+1}AX_n and Binary MX Transition Metal Carbide Phases

    OpenAIRE

    Lane, Nina J.; Vogel, Sven C.; Hug, Gilles; Togo, Atsushi; Chaput, Laurent; Hultman, Lars; Barsoum, Michel W.

    2012-01-01

    Herein, we compare the thermal vibrations of atoms in select ternary carbides with the formula Mn+1AXn ("MAX phases," M = Ti, Cr; A = Al, Si, Ge; X = C, N) as determined from first principles phonon calculations to those obtained from high-temperature neutron powder diffraction studies. The transition metal carbides TiC, TaC, and WC are also studied to test our methodology on simpler carbides. Good qualitative and quantitative agreement is found between predicted and experimental values for t...

  15. Continuous quantum phase transitions

    Energy Technology Data Exchange (ETDEWEB)

    Sondhi, S.L. [Department of Physics, Princeton University, Princeton, New Jersey 08544 (United States); Girvin, S.M.; Carini, J.P. [Department of Physics, Indiana University, Bloomington, Indiana 47405 (United States); Shahar, D. [Department of Electrical Engineering, Princeton University, Princeton, New Jersey 08544 (United States)

    1997-01-01

    A quantum system can undergo a continuous phase transition at the absolute zero of temperature as some parameter entering its Hamiltonian is varied. These transitions are particularly interesting for, in contrast to their classical finite-temperature counterparts, their dynamic and static critical behaviors are intimately intertwined. Considerable insight is gained by considering the path-integral description of the quantum statistical mechanics of such systems, which takes the form of the {ital classical} statistical mechanics of a system in which time appears as an extra dimension. In particular, this allows the deduction of scaling forms for the finite-temperature behavior, which turns out to be described by the theory of finite-size scaling. It also leads naturally to the notion of a temperature-dependent dephasing length that governs the crossover between quantum and classical fluctuations. Using these ideas, a scaling analysis of experiments on Josephson-junction arrays and quantum-Hall-effect systems is presented. {copyright} {ital 1997} {ital The American Physical Society}

  16. Enhancement in magnetocaloric properties of NiMnGa alloy through stoichiometric tuned phase transformation and magneto-thermal transitions

    Science.gov (United States)

    Dey, Sushmita; Roy, R. K.; Ghosh, M.; Basu Mallick, A.; Mitra, A.; Panda, A. K.

    2017-10-01

    The investigation is focussed on phase generation and magnetocaloric properties of a series of Ni77-XMnXGa23 (x = 22, 23, 24, 25, 27) alloys prepared through arc melting furnace. With increase in Mn content, the alloys showed systematic transition from a non-modulated martensite (NM) to a fully austenitic parent phase through an appearance and coexistence of modulated (M) structure. Intermediate Mn containing alloy (#Mn24) not only displayed high magnetic entropy change (ΔSM) of -7.7 J/kg-1K-1 but also large Refrigerant Capacity (RC) of 169 J.Kg-1 at magnetic field change of 3 T compared to other alloys. The coexisting martensite (NM, M) and parent austenite as well as overlapping thermomagnetic and structural transformation was deliverable through tuning of alloy chemistry wherein Ni was systematically substituted by Mn. Transmission electron microscopy (TEM) supported the proposition with existence of martensite plates of different morphology in Mn24 alloy exhibiting superior magnetocaloric properties.

  17. Organic, cross-linking, and shape-stabilized solar thermal energy storage materials: A reversible phase transition driven by broadband visible light

    International Nuclear Information System (INIS)

    Wang, Yunming; Tang, Bingtao; Zhang, Shufen

    2014-01-01

    Graphical abstract: Organic shape-stabilized solar thermal energy storage materials (OCSPCMs) with broadband harvesting for visible light were obtained by crosslinking and color matching, which provided a new platform for improving the efficiency of solar radiation utilization. - Highlights: • Novel phase change materials (OCSPCMs) were obtained by crosslinking and color matching. • The η of the OCSPCM was higher than 0.74 (visible light from 400 nm to 700 nm). • The phase change latent heats of the OCSPCMs were more than 120 J/g. • The OCSPCM has excellent form-stable effect during phase change process. - Abstract: Broadband visible sunlight usage and shape-stabilized effect were achieved using organic, cross-linking, and shape-stabilized phase-changed materials (OCSPCMs) with broadband visible light absorption, which were obtained by cross-linking reticulation and color matching (yellow, red, and blue) according to solar irradiation energy density. The obtained OCSPCMs exhibited excellent form-stable phase-change energy storage and broadband visible light-harvesting. Under broadband irradiation (from 400 nm to 700 nm), the light-to-heat conversion and the thermal energy storage efficiency (η > 0.74) of the OCSPCMs were significantly improved upon solar irradiation by color matching compared with those of OCSPCMs with single-band selective absorption of visible light (yellow, red, or blue). Differential scanning calorimetric results indicated that the phase change temperatures and latent heats of OCSPCMs ranged from 32.6 °C to 60.2 °C and from 120.1 J/g to 132.7 J/g, respectively. The novel materials show a reversible (more than 200 cycles) phase transition via ON/OFF switching of visible light irradiation

  18. Phase transition in finite systems

    International Nuclear Information System (INIS)

    Chomaz, Ph.; Duflot, V.; Duflot, V.; Gulminelli, F.

    2000-01-01

    In this paper we present a review of selected aspects of Phase transitions in finite systems applied in particular to the liquid-gas phase transition in nuclei. We show that the problem of the non existence of boundary conditions can be solved by introducing a statistical ensemble with an averaged constrained volume. In such an ensemble the microcanonical heat capacity becomes negative in the transition region. We show that the caloric curve explicitly depends on the considered transformation of the volume with the excitation energy and so does not bear direct informations on the characteristics of the phase transition. Conversely, partial energy fluctuations are demonstrated to be a direct measure of the equation of state. Since the heat capacity has a negative branch in the phase transition region, the presence of abnormally large kinetic energy fluctuations is a signal of the liquid gas phase transition. (author)

  19. Phase transitions and thermal entanglement of the distorted Ising-Heisenberg spin chain: topology of multiple-spin exchange interactions in spin ladders

    Science.gov (United States)

    Arian Zad, Hamid; Ananikian, Nerses

    2017-11-01

    We consider a symmetric spin-1/2 Ising-XXZ double sawtooth spin ladder obtained from distorting a spin chain, with the XXZ interaction between the interstitial Heisenberg dimers (which are connected to the spins based on the legs via an Ising-type interaction), the Ising coupling between nearest-neighbor spins of the legs and rungs spins, respectively, and additional cyclic four-spin exchange (ring exchange) in the square plaquette of each block. The presented analysis supplemented by results of the exact solution of the model with infinite periodic boundary implies a rich ground state phase diagram. As well as the quantum phase transitions, the characteristics of some of the thermodynamic parameters such as heat capacity, magnetization and magnetic susceptibility are investigated. We prove here that among the considered thermodynamic and thermal parameters, solely heat capacity is sensitive versus the changes of the cyclic four-spin exchange interaction. By using the heat capacity function, we obtain a singularity relation between the cyclic four-spin exchange interaction and the exchange coupling between pair spins on each rung of the spin ladder. All thermal and thermodynamic quantities under consideration should be investigated by regarding those points which satisfy the singularity relation. The thermal entanglement within the Heisenberg spin dimers is investigated by using the concurrence, which is calculated from a relevant reduced density operator in the thermodynamic limit.

  20. Generalized definitions of phase transitions

    International Nuclear Information System (INIS)

    Chomaz, Ph.; Gulminelli, F.

    2001-09-01

    We define a first order phase transition as a bimodality of the event distribution in the space of observations and we show that this is equivalent to a curvature anomaly of the thermodynamical potential and that it implies the Yang Lee behavior of the zeros of the partition sum. Moreover, it allows to study phase transitions out of equilibrium. (authors)

  1. Excited-state quantum phase transitions in systems with two degrees of freedom: Level density, level dynamics, thermal properties

    International Nuclear Information System (INIS)

    Stránský, Pavel; Macek, Michal; Cejnar, Pavel

    2014-01-01

    Quantum systems with a finite number of freedom degrees f develop robust singularities in the energy spectrum of excited states as the system’s size increases to infinity. We analyze the general form of these singularities for low f, particularly f=2, clarifying the relation to classical stationary points of the corresponding potential. Signatures in the smoothed energy dependence of the quantum state density and in the flow of energy levels with an arbitrary control parameter are described along with the relevant thermodynamical consequences. The general analysis is illustrated with specific examples of excited-state singularities accompanying the first-order quantum phase transition. -- Highlights: •ESQPTs found in infinite-size limit of systems with low numbers of freedom degrees f. •ESQPTs related to non-analytical evolutions of classical phase–space properties. •ESQPT signatures analyzed for general f, particularly f=2, extending known case f=1. •ESQPT signatures identified in smoothened density and flow of energy spectrum. •ESQPTs shown to induce a new type of thermodynamic anomalies

  2. Thermal switching of the electrical conductivity of Si(111)(√3x√3)Ag due to a surface phase transition

    International Nuclear Information System (INIS)

    Wells, J W; Kallehauge, J F; Hofmann, Ph

    2007-01-01

    The temperature-dependent surface conductivity of the Si(111)(√3x√3)Ag surface was measured using a microscopic four-point probe. The conductivity was found to undergo a sharp increase of about three orders of magnitude when the system was heated above about 220 K. This strong conductivity change is reversible and attributed to the phase transition which is generally believed to occur on this surface. It is also shown that, in order to find the true surface conductivity, it is necessary to separate it from the contribution of the bulk and space charge layer. In this work, this is achieved by using a finite-element model. A percolating network of Ag islands on Si(111) was also studied and a much simpler behaviour (compared to that of Si(111))(√3x√3)Ag) was found. The temperature-dependent conductivity of this system was found to display typical metallic behaviour. The absolute value of the conductivity is comparable to the value expected by modelling the Ag film as exhibiting the bulk Ag transport properties

  3. Magnetic resonance of phase transitions

    CERN Document Server

    Owens, Frank J; Farach, Horacio A

    1979-01-01

    Magnetic Resonance of Phase Transitions shows how the effects of phase transitions are manifested in the magnetic resonance data. The book discusses the basic concepts of structural phase and magnetic resonance; various types of magnetic resonances and their underlying principles; and the radiofrequency methods of nuclear magnetic resonance. The text also describes quadrupole methods; the microwave technique of electron spin resonance; and the Mössbauer effect. Phase transitions in various systems such as fluids, liquid crystals, and crystals, including paramagnets and ferroelectrics, are also

  4. Thermal study of dipalmitoyl 1,2 diglyceride transitions

    International Nuclear Information System (INIS)

    Albon, N.; Craievich, A.F.

    1984-01-01

    The enthalpy of the phase transitions of purified dipalmitoyl 1,2 glyceride, including the melting of two of the phases, have been measured by differencial thermal analysis. The special procedures required for measurement of some of the phases are described. The results of measurements of similar transitions of nonadecane of lower purity are also given. Values obtained are discussed in relation to the structures of the phases and the study of phospholipids. (Author) [pt

  5. Microgravity Two-Phase Flow Transition

    Science.gov (United States)

    Parang, M.; Chao, D.

    1999-01-01

    Two-phase flows under microgravity condition find a large number of important applications in fluid handling and storage, and spacecraft thermal management. Specifically, under microgravity condition heat transfer between heat exchanger surfaces and fluids depend critically on the distribution and interaction between different fluid phases which are often qualitatively different from the gravity-based systems. Heat transfer and flow analysis in two-phase flows under these conditions require a clear understanding of the flow pattern transition and development of appropriate dimensionless scales for its modeling and prediction. The physics of this flow is however very complex and remains poorly understood. This has led to various inadequacies in flow and heat transfer modeling and has made prediction of flow transition difficult in engineering design of efficient thermal and flow systems. In the present study the available published data for flow transition under microgravity condition are considered for mapping. The transition from slug to annular flow and from bubbly to slug flow are mapped using dimensionless variable combination developed in a previous study by the authors. The result indicate that the new maps describe the flow transitions reasonably well over the range of the data available. The transition maps are examined and the results are discussed in relation to the presumed balance of forces and flow dynamics. It is suggested that further evaluation of the proposed flow and transition mapping will require a wider range of microgravity data expected to be made available in future studies.

  6. Heat capacity characterization at phase transition temperature of Agl superionic

    International Nuclear Information System (INIS)

    Widowati, Arie

    2000-01-01

    The phase transition of Agl superionic conductor was investigated by calorometric. A single phase transition was found at (153±5) o C which corresponds to the α - β transition. Calorimetric measurement showed an anomalously high heat capacity with a large discontinues change in the Arrhenius plot, was found above the transition temperature of β - α phase. The maximum heat capacity was found to be ±19.7 cal/gmol. Key words : superionic conductor, thermal capacity

  7. Non-equilibrium phase transitions

    CERN Document Server

    Henkel, Malte; Lübeck, Sven

    2009-01-01

    This book describes two main classes of non-equilibrium phase-transitions: (a) static and dynamics of transitions into an absorbing state, and (b) dynamical scaling in far-from-equilibrium relaxation behaviour and ageing. The first volume begins with an introductory chapter which recalls the main concepts of phase-transitions, set for the convenience of the reader in an equilibrium context. The extension to non-equilibrium systems is made by using directed percolation as the main paradigm of absorbing phase transitions and in view of the richness of the known results an entire chapter is devoted to it, including a discussion of recent experimental results. Scaling theories and a large set of both numerical and analytical methods for the study of non-equilibrium phase transitions are thoroughly discussed. The techniques used for directed percolation are then extended to other universality classes and many important results on model parameters are provided for easy reference.

  8. Phase transitions in surfactant monolayers

    International Nuclear Information System (INIS)

    Casson, B.D.

    1998-01-01

    Two-dimensional phase transitions have been studied in surfactant monolayers at the air/water interface by sum-frequency spectroscopy and ellipsometry. In equilibrium monolayers of medium-chain alcohols C n H 2n+1 OH (n = 9-14) a transition from a two-dimensional crystalline phase to a liquid was observed at temperatures above the bulk melting point. The small population of gauche defects in the solid phase increased only slightly at the phase transition. A model of the hydrocarbon chains as freely rotating rigid rods allowed the area per molecule and chain tilt in the liquid phase to be determined. The area per molecule, chain tilt and density of the liquid phase all increased with increasing chain length, but for each chain length the density was higher than in a bulk liquid hydrocarbon. In a monolayer of decanol adsorbed at the air/water interface a transition from a two-dimensional liquid to a gas was observed. A clear discontinuity in the coefficient of ellipticity as a function of temperature showed that the transition is first-order. This result suggests that liquid-gas phase transitions in surfactant monolayers may be more widespread than once thought. A solid-liquid phase transition has also been studied in mixed monolayers of dodecanol with an anionic surfactant (sodium dodecyl sulphate) and with a homologous series of cationic surfactants (alkyltrimethylammonium bromides: C n TABs, n = 12, 14, 16). The composition and structure of the mixed monolayers was studied above and below the phase transition. At low temperatures the mixed monolayers were as densely packed as a monolayer of pure dodecanol in its solid phase. At a fixed temperature the monolayers under-went a first-order phase transition to form a phase that was less dense and more conformationally disordered. The proportion of ionic surfactant in the mixed monolayer was greatest in the high temperature phase. As the chain length of the C n TAB increased the number of conformational defects

  9. A novel method for simultaneous and continuous determination of thermal properties during phase transition applied to Calanus finmarchicus.

    Science.gov (United States)

    Bantle, Michael; Eikevik, Trygve Magne; Brennvall, Jon Eirik

    2010-08-01

    The thermal properties of a product are the most important parameters for practical engineering purposes and models in food science. Calanus finmarchicus is currently being examined as a marine resource for uncommon aquatic lipids and proteins. Thermal conductivity, specific heat, enthalpy and density were measured over the temperature range from -40 to +20 degrees C. The initial freezing point was determined to be -2.3 degrees C. The thermal properties were recorded continuously on 4 samples using a new method, and the results were compared with predictive models. The accuracy of the new method is demonstrated by different calibration runs. Significant differences in the thermal conductivity of the frozen material were found between the parallel-series model and the data, whereas the model of Pham and Willix (1989) or the Maxwell-Euken adaption showed better agreement. The measured data for specific heat, enthalpy, and density agreed well with the model. Practical Application: The thermal data obtained can be used directly in food engineering and technology applications, for example, in a thin layer model for freezing food for which precise thermal data for each layer are now available, enabling the more accurate prediction of freezing times and temperature profiles. Dimensionless numbers (such as the Biot number) can also be based on measured data with minor deviations compared to more general modeled thermal properties. Future activities will include the generation of a comprehensive database for different products.

  10. Phase-change radiative thermal diode

    OpenAIRE

    Ben-Abdallah, Philippe; Biehs, Svend-Age

    2013-01-01

    A thermal diode transports heat mainly in one preferential direction rather than in the opposite direction. This behavior is generally due to the non-linear dependence of certain physical properties with respect to the temperature. Here we introduce a radiative thermal diode which rectifies heat transport thanks to the phase transitions of materials. Rectification coefficients greater than 70% and up to 90% are shown, even for small temperature differences. This result could have important ap...

  11. Phase change thermal energy storage material

    Science.gov (United States)

    Benson, David K.; Burrows, Richard W.

    1987-01-01

    A thermal energy storge composition is disclosed. The composition comprises a non-chloride hydrate having a phase change transition temperature in the range of 70.degree.-95.degree. F. and a latent heat of transformation of at least about 35 calories/gram.

  12. Phase transitions and quantum entropy

    International Nuclear Information System (INIS)

    Arrachea, L.; Canosa, N.; Plastino, A.; Portesi, M.; Rossignoli, R.

    1990-01-01

    An examination is made of the possibility to predict phase transitions of the fundamental state of finite quantum system, knowing the quantum entropy of these states, defined on the basis of the information theory. (Author). 7 refs., 3 figs

  13. Phase transition in finite systems

    International Nuclear Information System (INIS)

    Chomaz, Ph.; Duflot, V.; Duflot, V.; Gulminelli, F.

    2000-01-01

    The general problem of the definition of a phase transition without employing the thermodynamical limit is addressed. Different necessary conditions are considered and illustrated with examples from different nuclear and general physics phenomenologies. (authors)

  14. Phase transition in finite systems

    Energy Technology Data Exchange (ETDEWEB)

    Chomaz, Ph.; Duflot, V. [Grand Accelerateur National d' Ions Lourds (GANIL), 14 - Caen (France); Duflot, V.; Gulminelli, F. [Laboratoire de Physique Corpusculaire, LPC-ISMRa, CNRS-IN2P3, 14 - Caen (France)

    2000-07-01

    The general problem of the definition of a phase transition without employing the thermodynamical limit is addressed. Different necessary conditions are considered and illustrated with examples from different nuclear and general physics phenomenologies. (authors)

  15. Phase transitions in field theory

    International Nuclear Information System (INIS)

    Carvalho, C.A.A. de; Bollini, C.G.; Giambiagi, J.J.

    1984-01-01

    By means of an example for which the effective potential is explicitly calculable (up to the one loop approximation), it is discussed how a phase transition takes place as the temperature is increased and pass from spontaneously broken symmetry to a phase in which the symmetry is restored. (Author) [pt

  16. Phase transitions and neutron scattering

    International Nuclear Information System (INIS)

    Shirane, G.

    1993-01-01

    A review is given of recent advances in neutron scattering studies of solid state physics. I have selected the study of a structural phase transition as the best example to demonstrate the power of neutron scattering techniques. Since energy analysis is relatively easy, the dynamical aspects of a transition can be elucidated by the neutron probe. I shall discuss in some detail current experiments on the 100 K transition in SrTiO 3 , the crystal which has been the paradigm of neutron studies of phase transitions for many years. This new experiment attempts to clarify the relation between the neutron central peak, observed in energy scans, and the two length scales observed in recent x-ray diffraction studies where only scans in momentum space are possible. (author)

  17. Phase transitions and neutron scattering

    International Nuclear Information System (INIS)

    Shirane, G.

    1993-01-01

    A review is given of recent advances in neutron scattering studies of solid state physics. The author has selected the study of a structural phase transition as the best example to demonstrate the power of neutron scattering techniques. Since energy analysis is relatively easy, the dynamical aspects of a transition can be elucidated by the neutron probe. He will discuss in some detail current experiments on the 100K transition in SrTiO 3 , the crystal which has been the paradigm of neutron studies of phase transitions for many years. This new experiment attempts to clarify the relation between the neutron central peak, observed in energy scans, and the two length scales observed in recent x-ray diffraction studies where only scans in momentum space are possible

  18. Incommensurate phase transitions

    Energy Technology Data Exchange (ETDEWEB)

    Currat, R. [Institut Max von Laue - Paul Langevin (ILL), 38 - Grenoble (France)

    1996-11-01

    We review the characteristic aspects of modulated crystals from the point of view of inelastic neutron scattering. We discuss the phenomenological Landau theory of the normal-to-incommensurate displacive instability and its predictions concerning the fluctuation spectrum of the modulated phase. General results on the form of the normal-mode eigenvectors and on the inelastic scattering channels through which they couple to the probe are established using the superspace approach. We illustrate these results on a simple discrete model symmetry and we review available inelastic neutron scattering data on several displacively modulated compounds. (author) 21 figs., 73 refs.

  19. Phase transitions in operational risk.

    Science.gov (United States)

    Anand, Kartik; Kühn, Reimer

    2007-01-01

    In this paper we explore the functional correlation approach to operational risk. We consider networks with heterogeneous a priori conditional and unconditional failure probability. In the limit of sparse connectivity, self-consistent expressions for the dynamical evolution of order parameters are obtained. Under equilibrium conditions, expressions for the stationary states are also obtained. Consequences of the analytical theory developed are analyzed using phase diagrams. We find coexistence of operational and nonoperational phases, much as in liquid-gas systems. Such systems are susceptible to discontinuous phase transitions from the operational to nonoperational phase via catastrophic breakdown. We find this feature to be robust against variation of the microscopic modeling assumptions.

  20. Detailed Investigation of the Structural, Thermal, and Electronic Properties of Gold Isocyanide Complexes with Mechano-Triggered Single-Crystal-to-Single-Crystal Phase Transitions.

    Science.gov (United States)

    Seki, Tomohiro; Sakurada, Kenta; Muromoto, Mai; Seki, Shu; Ito, Hajime

    2016-02-01

    Mechano-induced phase transitions in organic crystalline materials, which can alter their properties, have received much attention. However, most mechano-responsive molecular crystals exhibit crystal-to-amorphous phase transitions, and the intermolecular interaction patterns in the daughter phase are difficult to characterize. We have investigated phenyl(phenylisocyanide)gold(I) (1) and phenyl(3,5-dimethylphenylisocyanide)gold(I) (2) complexes, which exhibit a mechano-triggered single-crystal-to-single-crystal phase transition. Previous reports of complexes 1 and 2 have focused on the relationships between the crystalline structures and photoluminescence properties; in this work we have focused on other aspects. The face index measurements of complexes 1 and 2 before and after the mechano-induced phase transitions have indicated that they undergo non-epitaxial phase transitions without a rigorous orientational relationship between the mother and daughter phases. Differential scanning calorimetry analyses revealed the phase transition of complex 1 to be enthalpically driven by the formation of new aurophilic interactions. In contrast, the phase transition of complex 2 was found to be entropically driven, with the closure of an empty void in the mother phase. Scanning electron microscopy observation showed that the degree of the charging effect of both complexes 1 and 2 was changed by the phase transitions, which suggests that the formation of the aurophilic interactions affords more effective conductive pathways. Moreover, flash-photolysis time-resolved microwave conductivity measurements revealed that complex 1 increased in conductivity after the phase change, whereas the conductivity of complex 2 decreased. These contrasting results were explained by the different patterns in the aurophilic interactions. Finally, an intriguing disappearing polymorphism of complex 2 has been reported, in which a polymorph form could not be obtained again after some period of time

  1. Heavy ion seeks phase transition

    International Nuclear Information System (INIS)

    Ducomet, B.

    1987-11-01

    The emergence of the phase transition language in the context of heavy ion collisions at the so called ''GANIL energies'' (typically 10 - 100 MeV/u) has led us to make more precise some current definitions adopted in statistical mechanics, and used in a much less clear way in the nuclear physics context [fr

  2. Van der Waals phase transition in the framework of holography

    Directory of Open Access Journals (Sweden)

    Xiao-Xiong Zeng

    2017-01-01

    Full Text Available Phase structure of the quintessence Reissner–Nordström–AdS black hole is probed by the nonlocal observables such as holographic entanglement entropy and two point correlation function. Our result shows that, as the case of the thermal entropy, both the observables exhibit the Van der Waals-like phase transition. To reinforce this conclusion, we further check the equal area law for the first order phase transition and critical exponent of the heat capacity for the second order phase transition. We also discuss the effect of the state parameter on the phase structure of the nonlocal observables.

  3. Van der Waals phase transition in the framework of holography

    Energy Technology Data Exchange (ETDEWEB)

    Zeng, Xiao-Xiong, E-mail: xxzeng@itp.ac.cn [State School of Material Science and Engineering, Chongqing Jiaotong University, Chongqing 400074 (China); Institute of Theoretical Physics, Chinese Academy of Sciences, Beijing 100190 (China); Li, Li-Fang, E-mail: lilf@itp.ac.cn [State Key Laboratory of Space Weather, National Space Science Center, Chinese Academy of Sciences, Beijing 100190 (China)

    2017-01-10

    Phase structure of the quintessence Reissner–Nordström–AdS black hole is probed by the nonlocal observables such as holographic entanglement entropy and two point correlation function. Our result shows that, as the case of the thermal entropy, both the observables exhibit the Van der Waals-like phase transition. To reinforce this conclusion, we further check the equal area law for the first order phase transition and critical exponent of the heat capacity for the second order phase transition. We also discuss the effect of the state parameter on the phase structure of the nonlocal observables.

  4. The influence of the relative thermal expansion and electric permittivity on phase transitions in the perovskite-type bidimensional layered NH3(CH2)3NH3CdBr4 compound

    Science.gov (United States)

    Staśkiewicz, Beata; Staśkiewicz, Anna

    2017-07-01

    Hydrothermal method has been used to synthesized the layered hybrid compound NH3(CH2)3NH3CdBr4 of perovskite architecture. Structural, dielectric and dilatometric properties of the compound have been analyzed. Negative thermal expansion (NTE) effect in the direction perpendicular to the perovskite plane as well as an unusual phase sequence have been reported based on X-ray diffraction analysis. Electric permittivity measurements evidenced the phase transitions at Tc1=326/328 K and Tc2=368/369 K. Relative linear expansion measurements almost confirmed these temperatures of phase transitions. Anomalies of electric permittivity and expansion behavior connected with the phase transitions are detected at practically the same temperatures as those observed earlier in differential scanning calorimetry (DSC), infrared (IR), far infrared (FIR) and Raman spectroscopy studies. Mechanism of the phase transitions is explained. Relative linear expansion study was prototype to estimate critical exponent value β for continuous phase transition at Tc1. It has been inferred that there is a strong interplay between the distortion of the inorganic network, those hydrogen bonds and the intermolecular interactions of the organic component.

  5. Quantum phase transitions of strongly correlated electron systems

    International Nuclear Information System (INIS)

    Imada, Masatoshi

    1998-01-01

    Interacting electrons in solids undergo various quantum phase transitions driven by quantum fluctuations. The quantum transitions take place at zero temperature by changing a parameter to control quantum fluctuations rather than thermal fluctuations. In contrast to classical phase transitions driven by thermal fluctuations, the quantum transitions have many different features where quantum dynamics introduces a source of intrinsic fluctuations tightly connected with spatial correlations and they have been a subject of recent intensive studies as we see below. Interacting electron systems cannot be fully understood without deep analyses of the quantum phase transitions themselves, because they are widely seen and play essential roles in many phenomena. Typical and important examples of the quantum phase transitions include metal-insulator transitions, (2, 3, 4, 5, 6, 7, 8, 9) metal-superconductor transitions, superconductor-insulator transitions, magnetic transitions to antiferromagnetic or ferromagnetic phases in metals as well as in Mott insulators, and charge ordering transitions. Here, we focus on three different types of transitions

  6. Phase transitions and critical phenomena

    CERN Document Server

    Domb, Cyril

    2001-01-01

    The field of phase transitions and critical phenomena continues to be active in research, producing a steady stream of interesting and fruitful results. It has moved into a central place in condensed matter studies.Statistical physics, and more specifically, the theory of transitions between states of matter, more or less defines what we know about 'everyday' matter and its transformations.The major aim of this serial is to provide review articles that can serve as standard references for research workers in the field, and for graduate students and others wishing to obtain reliable in

  7. Transitional Phenomena on Phase Change Materials

    Directory of Open Access Journals (Sweden)

    Wójcik Tadeusz M.

    2014-03-01

    Full Text Available One of the most significant problem with technology development is transferring of large heat fluxes, which requires constant heat transfer temperature (in the specified temperature range. This problem concern mainly the nuclear energetics, space technologies, military technologies and most of all electronics containing integrated circuits with very large scale of integrations. Intensive heat transfer and thermal energy storage are possible by the use of phase change materials (PCMs. In the paper there are presented preliminary results of research on the use of liquid-gas (L-G PCMs and solid-solid phase change materials (S-S PCMs. For L-G PCMs the boiling characteristics were determined by increasing and decreasing the heat flux, which for certain sets of structural parameters of the heating surface and the physical properties of the liquid induce a variety of forms of transitional phenomena. Thermal energy storage is much more effective when using PCMs than sensible heat.

  8. Passive thermal management using phase change materials

    Science.gov (United States)

    Ganatra, Yash Yogesh

    The trend of enhanced functionality and reducing thickness of mobile devices has. led to a rapid increase in power density and a potential thermal bottleneck since. thermal limits of components remain unchanged. Active cooling mechanisms are not. feasible due to size, weight and cost constraints. This work explores the feasibility. of a passive cooling system based on Phase Change Materials (PCMs) for thermal. management of mobile devices. PCMs stabilize temperatures due to the latent heat. of phase change thus increasing the operating time of the device before threshold. temperatures are exceeded. The primary contribution of this work is the identification. of key parameters which influence the design of a PCM based thermal management. system from both the experiments and the numerical models. This work first identifies strategies for integrating PCMs in an electronic device. A. detailed review of past research, including experimental techniques and computational. models, yields key material properties and metrics to evaluate the performance of. PCMs. Subsequently, a miniaturized version of a conventional thermal conductivity. measurement technique is developed to characterize thermal resistance of PCMs. Further, latent heat and transition temperatures are also characterized for a wide. range of PCMs. In-situ measurements with PCMs placed on the processor indicate that some. PCMs can extend the operating time of the device by as much as a factor of 2.48. relative to baseline tests (with no PCMs). This increase in operating time is investigated. by computational thermal models that explore various integration locations, both at the package and device level.

  9. Phase transitions in dense matter

    Science.gov (United States)

    Dexheimer, Veronica; Hempel, Matthias; Iosilevskiy, Igor; Schramm, Stefan

    2017-11-01

    As the density of matter increases, atomic nuclei disintegrate into nucleons and, eventually, the nucleons themselves disintegrate into quarks. The phase transitions (PT's) between these phases can vary from steep first order to smooth crossovers, depending on certain conditions. First-order PT's with more than one globally conserved charge, so-called non-congruent PT's, have characteristic differences compared to congruent PT's. In this conference proceeding we discuss the non-congruence of the quark deconfinement PT at high densities and/or temperatures relevant for heavy-ion collisions, neutron stars, proto-neutron stars, supernova explosions, and compact-star mergers.

  10. Phase Transitions and Free Boundaries

    Science.gov (United States)

    1991-10-31

    V PHASE TRANSITIONS AND FREE BOUNDARIES FINAL REPORT AD -A243 412 DECO 3 1991 WILLARD MILLER, JR. U October 31, 1991 OFFICE OF NAVAL RESEARCH N0014-91...Einstein- University of Michigan Yang/Mills equations Abstract: The only static solution to the vacuum Einstein equations is the celebrated Schwarzschild ...equations to Maxwell’s equations, the only static solution is the Reissner- Nordstr6m metric which is again singular at the origin. Finally, for any gauge

  11. Signatures of Quantum Phase Transitions via Quantum Information Theoretic Measures

    Science.gov (United States)

    Bose, I.; Tribedi, A.

    Quantum phase transitions (QPTs) in many body systems occur at T = 0 brought about by tuning a non-thermal parameter, e.g. pressure, chemical composition or external magnetic field [1, 2]. In a QPT, the ground state wave function undergoes qualitative changes at the transition point. The transition is driven by quantum fluctuations whereas ordinary phase transitions occurring at nonzero temperatures are driven by thermal fluctuations. Like a thermal phase transition, a QPT can be first order, second order or higher order. The thermal critical point, associated with a second-order phase transition, is characterized by the presence of thermal fluctuations on all length scales resulting in a divergent correlation length. The free energy and the thermodynamic functions develop singularities as temperature Trightarrow T_{textrm{c}} , the critical temperature. At the quantum critical point (QCP), quantum fluctuations occur on all length scales leading to a divergent correlation length. The ground state and related physical quantities become non-analytic as the tuning parameter g tends to the critical value g c . The influence of QPTs extends into the finite T part of the phase diagram so that experimental detection of QPTs is possible.

  12. No Hawking-Page phase transition in three dimensions

    International Nuclear Information System (INIS)

    Myung, Y.S.

    2005-01-01

    We investigate whether or not the Hawking-Page phase transition is possible to occur in three dimensions. Starting with the simplest class of Lanczos-Lovelock action, thermodynamic behavior of all AdS-type black holes without charge falls into two classes: Schwarzschild-AdS black holes in even dimensions and Chern-Simons black holes in odd dimensions. The former class can provide the Hawking-Page transition between Schwarzschild-AdS black holes and thermal AdS space. On the other hand, the latter class is exceptional and thus the Hawking-Page transition is hard to occur. In three dimensions, a second-order phase transition might occur between the non-rotating BTZ black hole and the massless BTZ black hole (thermal AdS space), instead of the first-order Hawking-Page transition between the non-rotating BTZ black hole and thermal AdS space

  13. Scale invariance from phase transitions to turbulence

    CERN Document Server

    Lesne, Annick

    2012-01-01

    During a century, from the Van der Waals mean field description (1874) of gases to the introduction of renormalization group (RG techniques 1970), thermodynamics and statistical physics were just unable to account for the incredible universality which was observed in numerous critical phenomena. The great success of RG techniques is not only to solve perfectly this challenge of critical behaviour in thermal transitions but to introduce extremely useful tools in a wide field of daily situations where a system exhibits scale invariance. The introduction of scaling, scale invariance and universality concepts has been a significant turn in modern physics and more generally in natural sciences. Since then, a new "physics of scaling laws and critical exponents", rooted in scaling approaches, allows quantitative descriptions of numerous phenomena, ranging from phase transitions to earthquakes, polymer conformations, heartbeat rhythm, diffusion, interface growth and roughening, DNA sequence, dynamical systems, chaos ...

  14. Chiral phase transitions in quantum chromodynamics at finite ...

    Indian Academy of Sciences (India)

    cedure the phase structure of gauge theories. At finite temperature/density, however, we should seriously ask whether the preceding results [1] of the DS equation analysis on the chiral phase transition could be relied on being the real consequences of thermal gauge theories. This is because in previous analyses the ...

  15. Gibbs measures and phase transitions

    CERN Document Server

    Georgii, Hans-Otto

    2011-01-01

    From a review of the first edition: ""This book […] covers in depth a broad range of topics in the mathematical theory of phase transition in statistical mechanics. […] It is in fact one of the author's stated aims that this comprehensive monograph should serve both as an introductory text and as a reference for the expert."" (F. Papangelou, Zentralblatt MATH) The second edition has been extended by a new section on large deviations and some comments on the more recent developments in the area.

  16. Phase transitions and critical phenomena

    CERN Document Server

    Domb, Cyril

    2000-01-01

    The field of phase transitions and critical phenomena continues to be active in research, producing a steady stream of interesting and fruitful results. No longer an area of specialist interest, it has acquired a central focus in condensed matter studies. The major aim of this serial is to provide review articles that can serve as standard references for research workers in the field, and for graduate students and others wishing to obtain reliable information on important recent developments.The two review articles in this volume complement each other in a remarkable way. Both deal with what m

  17. Light scattering near phase transitions

    CERN Document Server

    Cummins, HZ

    1983-01-01

    Since the development of the laser in the early 1960's, light scattering has played an increasingly crucial role in the investigation of many types of phase transitions and the published work in this field is now widely dispersed in a large number of books and journals.A comprehensive overview of contemporary theoretical and experimental research in this field is presented here. The reviews are written by authors who have actively contributed to the developments that have taken place in both Eastern and Western countries.

  18. Phase transition in tensor models

    Energy Technology Data Exchange (ETDEWEB)

    Delepouve, Thibault [Laboratoire de Physique Théorique, CNRS UMR 8627, Université Paris Sud,91405 Orsay Cedex (France); Centre de Physique Théorique, CNRS UMR 7644, École Polytechnique,91128 Palaiseau Cedex (France); Gurau, Razvan [Centre de Physique Théorique, CNRS UMR 7644, École Polytechnique,91128 Palaiseau Cedex (France); Perimeter Institute for Theoretical Physics,31 Caroline St. N, N2L 2Y5, Waterloo, ON (Canada)

    2015-06-25

    Generalizing matrix models, tensor models generate dynamical triangulations in any dimension and support a 1/N expansion. Using the intermediate field representation we explicitly rewrite a quartic tensor model as a field theory for a fluctuation field around a vacuum state corresponding to the resummation of the entire leading order in 1/N (a resummation of the melonic family). We then prove that the critical regime in which the continuum limit in the sense of dynamical triangulations is reached is precisely a phase transition in the field theory sense for the fluctuation field.

  19. Thermal comfort in urban transitional spaces

    Energy Technology Data Exchange (ETDEWEB)

    Chungyoon Chun [Yonsei University, Seoul (Korea). College of Human Ecology, Department of Housing and Interior Design; Tamura, A. [Yokohama National University (Japan). Department of Architecture and Building Science

    2005-05-15

    This paper deals with thermal comfort in urban transitional spaces. This topic investigates thermal comfort during walking activities through transitional spaces-urban corridors, shopping streets, and open-ended passageways. The study involves a field study and a laboratory study with a sequenced walk through an environmental control chamber. Subjects in both studies wore the same clothing ensembles, walked the same speed, and evaluated their thermal comfort at 20 designated point in the field and in specific rooms in the control chamber. Air temperature, relative humidity, and air velocity were measured concurrently as the thermal comfort votes completed. Findings revealed that the previously experienced temperatures determined thermal comfort at the following point in the sequence. Because thermal comfort at a point can be influenced widely by relative placement of temperatures in sequence, thermal comfort in transitional spaces can be adapted very widely compared to comfort inside of buildings. Thermal comfort along the experimental courses was evaluated by averaging the temperature of a course. (author)

  20. Baryogenesis via leptonic CP-violating phase transition

    Science.gov (United States)

    Pascoli, Silvia; Turner, Jessica; Zhou, Ye-Ling

    2018-05-01

    We propose a new mechanism to generate a lepton asymmetry based on the vacuum CP-violating phase transition (CPPT). This approach differs from classical thermal leptogenesis as a specific seesaw model, and its UV completion, need not be specified. The lepton asymmetry is generated via the dynamically realised coupling of the Weinberg operator during the phase transition. This mechanism provides a connection with low-energy neutrino observables.

  1. Dynamical constraints on phase transitions

    Energy Technology Data Exchange (ETDEWEB)

    Morawetz, K. [Grand Accelerateur National d' Ions Lourds (GANIL), 14 - Caen (France); Laboratoire de Physique Corpusculaire, IN2P3-CNRS, ISMRA et Universite, 14 - Caen (France)

    2000-07-01

    The numerical solutions of nonlocal and local Boltzmann kinetic equations for the simulation of central heavy ion reactions are parameterized in terms of time dependent thermodynamical variables in the Fermi liquid sense. This allows to discuss dynamical trajectories in phase space. The nonequilibrium state is characterized by non-isobaric, non-isochoric etc conditions, called iso-nothing conditions. Therefore a combination of thermodynamical observables is constructed which allows to locate instabilities and points of possible phase transition in a dynamical sense. We find two different mechanisms of instability, a short time surface - dominated instability and later a spinodal - dominated volume instability. The latter one occurs only if the incident energies are not exceeding much the Fermi energy and might be attributed to spinodal decomposition. Oppositely the fast surface explosion occurs far outside the spinodal and pertains also in the cases where the system develops too fast for suffering the spinodal decomposition and where the system approaches equilibrium outside the spinodal. (author)

  2. Dynamical constraints on phase transitions

    International Nuclear Information System (INIS)

    Morawetz, K.

    2000-01-01

    The numerical solutions of nonlocal and local Boltzmann kinetic equations for the simulation of central heavy ion reactions are parameterized in terms of time dependent thermodynamical variables in the Fermi liquid sense. This allows to discuss dynamical trajectories in phase space. The nonequilibrium state is characterized by non-isobaric, non-isochoric etc conditions, called iso-nothing conditions. Therefore a combination of thermodynamical observables is constructed which allows to locate instabilities and points of possible phase transition in a dynamical sense. We find two different mechanisms of instability, a short time surface - dominated instability and later a spinodal - dominated volume instability. The latter one occurs only if the incident energies are not exceeding much the Fermi energy and might be attributed to spinodal decomposition. Oppositely the fast surface explosion occurs far outside the spinodal and pertains also in the cases where the system develops too fast for suffering the spinodal decomposition and where the system approaches equilibrium outside the spinodal. (author)

  3. Symmetry and Phase Transitions in Nuclei

    International Nuclear Information System (INIS)

    Iachello, F.

    2009-01-01

    Phase transitions in nuclei have received considerable attention in recent years, especially after the discovery that, contrary to expectations, systems at the critical point of a phase transition display a simple structure. In this talk, quantum phase transitions (QPT), i.e. phase transitions that occur as a function of a coupling constant that appears in the quantum Hamiltonian, H, describing the system, will be reviewed and experimental evidence for their occurrence in nuclei will be presented. The phase transitions discussed in the talk will be shape phase transitions. Different shapes have different symmetries, classified by the dynamic symmetries of the Interacting Boson Model, U(5), SU(3) and SO(6). Very recently, the concept of Quantum Phase Transitions has been extended to Excited State Quantum Phase Transitions (ESQPT). This extension will be discussed and some evidence for incipient ESQPT in nuclei will be presented. Systems at the critical point of a phase transition are called 'critical systems'. Approximate analytic formulas for energy spectra and other properties of 'critical nuclei', in particular for nuclei at the critical point of the second order U(5)-SO(6) transition, called E(5), and along the line of first order U(5)-SU(3) transitions, called X(5), will be presented. Experimental evidence for 'critical nuclei' will be also shown. Finally, the microscopic derivation of shape phase transitions in nuclei within the framework of density functional methods will be briefly discussed.(author)

  4. On the chiral phase transition in the linear sigma model

    International Nuclear Information System (INIS)

    Tran Huu Phat; Nguyen Tuan Anh; Le Viet Hoa

    2003-01-01

    The Cornwall- Jackiw-Tomboulis (CJT) effective action for composite operators at finite temperature is used to investigate the chiral phase transition within the framework of the linear sigma model as the low-energy effective model of quantum chromodynamics (QCD). A new renormalization prescription for the CJT effective action in the Hartree-Fock (HF) approximation is proposed. A numerical study, which incorporates both thermal and quantum effect, shows that in this approximation the phase transition is of first order. However, taking into account the higher-loop diagrams contribution the order of phase transition is unchanged. (author)

  5. Thermal expansion accompanying the glass-liquid transition and crystallization

    Directory of Open Access Journals (Sweden)

    M. Q. Jiang

    2015-12-01

    Full Text Available We report the linear thermal expansion behaviors of a Zr-based (Vitreloy 1 bulk metallic glass in its as-cast, annealed and crystallized states. Accompanying the glass-liquid transition, the as-cast Vitreloy 1 shows a continuous decrease in the thermal expansivity, whereas the annealed glass shows a sudden increase. The crystallized Vitreloy 1 exhibits an almost unchanged thermal expansivity prior to its melting. Furthermore, it is demonstrated that the nucleation of crystalline phases can induce a significant thermal shrinkage of the supercooled liquid, but with the growth of these nuclei, the thermal expansion again dominates. These results are explained in the framework of the potential energy landscape, advocating that the configurational and vibrational contributions to the thermal expansion of the glass depend on both, structure and temperature.

  6. The electroweak phase transition in the Inert Doublet Model

    Energy Technology Data Exchange (ETDEWEB)

    Blinov, Nikita [Department of Physics, University of California Santa Cruz,1156 High St, Santa Cruz, CA 95064 (United States); Santa Cruz Institute for Particle Physics,1156 High St, Santa Cruz, CA 95064 (United States); Theory Department, TRIUMF,4004 Wesbrook Mall, Vancouver, BC V6T 2A3 (Canada); Department of Physics and Astronomy, University of British Columbia,Vancouver, BC V6T 1Z1 (Canada); Profumo, Stefano; Stefaniak, Tim [Department of Physics, University of California Santa Cruz,1156 High St, Santa Cruz, CA 95064 (United States); Santa Cruz Institute for Particle Physics,1156 High St, Santa Cruz, CA 95064 (United States)

    2015-07-21

    We study the strength of a first-order electroweak phase transition in the Inert Doublet Model (IDM), where particle dark matter (DM) is comprised of the lightest neutral inert Higgs boson. We improve over previous studies in the description and treatment of the finite-temperature effective potential and of the electroweak phase transition. We focus on a set of benchmark models inspired by the key mechanisms in the IDM leading to a viable dark matter particle candidate, and illustrate how to enhance the strength of the electroweak phase transition by adjusting the masses of the yet undiscovered IDM Higgs states. We argue that across a variety of DM masses, obtaining a strong enough first-order phase transition is a generic possibility in the IDM. We find that due to direct dark matter searches and collider constraints, a sufficiently strong transition and a thermal relic density matching the universal DM abundance is possible only in the Higgs funnel regime.

  7. The electroweak phase transition in the Inert Doublet Model

    Energy Technology Data Exchange (ETDEWEB)

    Blinov, Nikita; Profumo, Stefano; Stefaniak, Tim, E-mail: nblinov@triumf.ca, E-mail: profumo@ucsc.edu, E-mail: tistefan@ucsc.edu [Department of Physics, University of California Santa Cruz, 1156 High St, Santa Cruz, CA 95064 (United States)

    2015-07-01

    We study the strength of a first-order electroweak phase transition in the Inert Doublet Model (IDM), where particle dark matter (DM) is comprised of the lightest neutral inert Higgs boson. We improve over previous studies in the description and treatment of the finite-temperature effective potential and of the electroweak phase transition. We focus on a set of benchmark models inspired by the key mechanisms in the IDM leading to a viable dark matter particle candidate, and illustrate how to enhance the strength of the electroweak phase transition by adjusting the masses of the yet undiscovered IDM Higgs states. We argue that across a variety of DM masses, obtaining a strong enough first-order phase transition is a generic possibility in the IDM. We find that due to direct dark matter searches and collider constraints, a sufficiently strong transition and a thermal relic density matching the universal DM abundance is possible only in the Higgs funnel regime.

  8. QCD Phase Transitions, Volume 15

    Energy Technology Data Exchange (ETDEWEB)

    Schaefer, T.; Shuryak, E.

    1999-03-20

    The title of the workshop, ''The QCD Phase Transitions'', in fact happened to be too narrow for its real contents. It would be more accurate to say that it was devoted to different phases of QCD and QCD-related gauge theories, with strong emphasis on discussion of the underlying non-perturbative mechanisms which manifest themselves as all those phases. Before we go to specifics, let us emphasize one important aspect of the present status of non-perturbative Quantum Field Theory in general. It remains true that its studies do not get attention proportional to the intellectual challenge they deserve, and that the theorists working on it remain very fragmented. The efforts to create Theory of Everything including Quantum Gravity have attracted the lion share of attention and young talent. Nevertheless, in the last few years there was also a tremendous progress and even some shift of attention toward emphasis on the unity of non-perturbative phenomena. For example, we have seen some efforts to connect the lessons from recent progress in Supersymmetric theories with that in QCD, as derived from phenomenology and lattice. Another example is Maldacena conjecture and related development, which connect three things together, string theory, super-gravity and the (N=4) supersymmetric gauge theory. Although the progress mentioned is remarkable by itself, if we would listen to each other more we may have chance to strengthen the field and reach better understanding of the spectacular non-perturbative physics.

  9. Thermally induced morphological transition of silver fractals

    DEFF Research Database (Denmark)

    Solov'yov, Ilia; Solov'yov, Andrey; Kébaili, Nouari

    2014-01-01

    We present both experimental and theoretical study of thermally induced morphological transition of silver nanofractals. Experimentally, those nanofractals formed from deposition and diffusion of preformed silver clusters on cleaved graphite surfaces exhibit dendritic morphologies that are highly...... sensitive to any perturbation, particularly caused by temperature. We analyze and characterize the morphological transition both in time and temperature using the recently developed Monte Carlo simulation approach for the description of nanofractal dynamics and compare the obtained results...

  10. Li-ion batteries: Phase transition

    International Nuclear Information System (INIS)

    Hou Peiyu; Zhang Yantao; Zhang Lianqi; Chu Geng; Gao Jian

    2016-01-01

    Progress in the research on phase transitions during Li + extraction/insertion processes in typical battery materials is summarized as examples to illustrate the significance of understanding phase transition phenomena in Li-ion batteries. Physical phenomena such as phase transitions (and resultant phase diagrams) are often observed in Li-ion battery research and already play an important role in promoting Li-ion battery technology. For example, the phase transitions during Li + insertion/extraction are highly relevant to the thermodynamics and kinetics of Li-ion batteries, and even physical characteristics such as specific energy, power density, volume variation, and safety-related properties. (topical review)

  11. Thermal physics of transition edge sensor arrays

    International Nuclear Information System (INIS)

    Hoevers, H.F.C.

    2006-01-01

    Thermal transport in transition edge sensor (TES)-based microcalorimeter arrays is reviewed. The fundamentals of thermal conductance in Si 3 N 4 membranes are discussed and the magnitude of the electron-phonon coupling and Kapitza coupling in practical devices is summarized. Next, the thermal transport in high-stopping power and low-heat capacity absorbers, required for arrays of TES microcalorimeters, is discussed in combination with a performance analysis of detectors with mushroom-absorbers. Finally, the phenomenology of unexplained excess noise, observed in both Mo- and Ti-based TESs, is briefly summarized and related with the coupling of the TES to the heat bath

  12. Sound speed during the QCD phase transition

    International Nuclear Information System (INIS)

    Nagasawa, Michiyasu; Yokoyama, Jun'ichi

    1998-01-01

    The Jeans scale is estimated during the coexistence epoch of quark-gluon and hadron phases in the first-order QCD phase transition. It is shown that, contrary to previous claims, reduction of the sound speed is so little that the phase transition does not affect evolution of cosmological density fluctuations appreciably. (author)

  13. Hawking–Page phase transition in new massive gravity

    Directory of Open Access Journals (Sweden)

    Shao-Jun Zhang

    2015-07-01

    Full Text Available We consider Hawking–Page phase transition between the BTZ black hole with M≥0 and the thermal soliton with M=−1 in new massive gravity. By comparing the on-shell free energies, we can see that there exists a critical temperature. The thermal soliton is more probable than the black hole below the critical temperature while the black hole is more probable than the thermal soliton above the critical temperature. By consistently constructing the off-shell free energies taking into account the conical singularity, we show that there exist infinite non-equilibrium states connecting the BTZ black hole and the thermal soliton, so that they provide a picture of continuous evolution of the phase transition.

  14. The Structural Phase Transition in Solid DCN

    DEFF Research Database (Denmark)

    Dietrich, O. W.; Mackenzie, Gordon A.; Pawley, G. S.

    1976-01-01

    Neutron scattering measurements on deuterated hydrogen cyanide have shown that the structural phase transition from a tetragonal to an orthorhombic form at 160 K is a first order transition. A transverse acoustic phonon mode, which has the symmetry of the transition was observed at very low...

  15. Locating phase transitions in computationally hard problems

    Indian Academy of Sciences (India)

    automatic planning and models of associative memory among others, all indicate the widespread prevalence of phase transitions in a computational context. It has also been .... depicted by the colour; number of nodes N = 250. Note the sharp inflection corresponding to a phase transition. is an evolution of the system to ...

  16. Late time phase transition as dark energy

    Indian Academy of Sciences (India)

    Abstract. We show that the dark energy field can naturally be described by the scalar condensates of a non-abelian gauge group. This gauge group is unified with the standard model gauge groups and it has a late time phase transition. The small phase transition explains why the positive acceleration of the universe is ...

  17. Scaling Concepts in Describing Continuous Phase Transitions

    Indian Academy of Sciences (India)

    Advanced Scientific. Research, Bengaluru. His research addresses the behaviour of liquids and disordered soft matter, including glassy dynamics and the glass transition, glasses, jamming, and phase transformations in liquids. Phase transitions, like the boiling of water upon increasing temperature, are a part of everyday ...

  18. Phases and phase transitions of S=1 bosons

    Indian Academy of Sciences (India)

    smukerjee

    Quantum phases and phase transitions of bosons. Subroto Mukerjee. Dept. of Physics & Centre for Quantum. Information and Quantum Computing (CQIQC). Indian Institute of Science, Bangalore. 77th annual meeting of the IAS, Nov. 20 2011, PRL Ahmedabad ...

  19. Thermodynamics of pairing phase transition in nuclei

    International Nuclear Information System (INIS)

    Karim, Afaque; Ahmad, Shakeb

    2014-01-01

    The pairing gaps, pairing energy, heat capacity and entropy are calculated within BCS (Bardeen- Cooper-Schrieffer) based quasi particle approach, including thermal fluctuations on pairing field within pairing model for all nuclei (light, medium, heavy and super heavy nuclei). Quasi particles approach in BCS theory was introduced and reformulated to study various properties. For thermodynamic behavior of nuclei at finite temperatures, the anomalous averages of creation and annihilation operators are introduced. It is solved self consistently at finite temperatures to obtain BCS Hamiltonian. After doing unitary transformation, we obtained the Hamiltonian in the diagonal form. Thus, one gets temperature dependence gap parameter and pairing energy for nuclei. Moreover, the energy at finite temperatures is the sum of the condensation energy and the thermal energy of fermionic quasi particles. With the help of BCS Hamiltonian, specific heat, entropy and free energy are calculated for different nuclei. In this paper the gap parameter occupation number and pairing energy as a function of temperature which is important for all the light, medium, heavy and super heavy nuclei is calculated. Moreover, the various thermo dynamical quantities like specific heat, entropy and free energy is also obtained for different nuclei. Thus, the thermodynamics of pairing phase transition in nuclei is studied

  20. Transitional Thermal Creep of Early Age Concrete

    DEFF Research Database (Denmark)

    Hauggaard, A. B.; Damkilde, L.; Hansen, Per Freiesleben

    1999-01-01

    Couplings between creep of hardened concrete and temperature/water effects are well-known. Both the level and the gradients in time of temperature or water content influence the creep properties. In early age concrete the internal drying and the heat development due to hydration increase the effect...... of these couplings. The purpose of this work is to set up a mathematical model for creep of concrete that includes the transitional thermal effect. The model governs both early age concrete and hardened concrete. The development of the material properties in the model is assumed to depend on the hydration process...... and the thermal activation of water in the microstructure. The thermal activation is assumed to be governed by the Arrhenius principle, and the activation energy of the viscosity of water is found applicable in the analysis of the experimental data. Changes in temperature create an imbalance in the microstructure...

  1. Transitional Thermal Creep of Early Age Concrete

    DEFF Research Database (Denmark)

    Hauggaard-Nielsen, Anders Boe; Damkilde, Lars; Freiesleben Hansen, Per

    1999-01-01

    of these couplings. The purpose of this work is to set up a mathematical model for creep of concrete which includes the transitional thermal effect. The model govern both early age concrete and hardened concrete. The development of the material properties in the model are assumed to depend on the hydration process......Couplings between creep of hardened concrete and temperature/water effects are well-known. Both the level and the gradients in time of temperature or water content influence the creep properties. In early age concrete the internal drying and the heat development due to hydration increase the effect...... and the thermal activation of the water in the microstructure. The thermal activation is assumed to be governed by the Arrhenius principle and the activation energy of the viscosity of water is found applicable in the analysis of experimental data. Changes in temperature create an imbalance in the microstructure...

  2. Phase transitions in solids under high pressure

    CERN Document Server

    Blank, Vladimir Davydovich

    2013-01-01

    Phase equilibria and kinetics of phase transformations under high pressureEquipment and methods for the study of phase transformations in solids at high pressuresPhase transformations of carbon and boron nitride at high pressure and deformation under pressurePhase transitions in Si and Ge at high pressure and deformation under pressurePolymorphic α-ω transformation in titanium, zirconium and zirconium-titanium alloys Phase transformations in iron and its alloys at high pressure Phase transformations in gallium and ceriumOn the possible polymorphic transformations in transition metals under pressurePressure-induced polymorphic transformations in АIBVII compoundsPhase transformations in AIIBVI and AIIIBV semiconductor compoundsEffect of pressure on the kinetics of phase transformations in iron alloysTransformations during deformation at high pressure Effects due to phase transformations at high pressureKinetics and hysteresis in high-temperature polymorphic transformations under pressureHysteresis and kineti...

  3. Phase transitions and critical behaviour for charged black holes

    International Nuclear Information System (INIS)

    Carlip, S; Vaidya, S

    2003-01-01

    We investigate the thermodynamics of a four-dimensional charged black hole in a finite cavity in asymptotically flat and asymptotically de Sitter spaces. In each case, we find a Hawking-Page-like phase transition between a black hole and a thermal gas very much like the known transition in asymptotically anti-de Sitter space. For a 'supercooled' black hole - a thermodynamically unstable black hole below the critical temperature for the Hawking-Page phase transition - the phase diagram has a line of first-order phase transitions that terminates in a second-order point. For the asymptotically flat case, we calculate the critical exponents at the second-order phase transition and find that they exactly match the known results for a charged black hole in anti-de Sitter space. We find strong evidence for similar phase transitions for the de Sitter black hole as well. Thus many of the thermodynamic features of charged anti-de Sitter black holes do not really depend on asymptotically anti-de Sitter boundary conditions; the thermodynamics of charged black holes is surprisingly universal

  4. Quantum phase transition with dissipative frustration

    Science.gov (United States)

    Maile, D.; Andergassen, S.; Belzig, W.; Rastelli, G.

    2018-04-01

    We study the quantum phase transition of the one-dimensional phase model in the presence of dissipative frustration, provided by an interaction of the system with the environment through two noncommuting operators. Such a model can be realized in Josephson junction chains with shunt resistances and resistances between the chain and the ground. Using a self-consistent harmonic approximation, we determine the phase diagram at zero temperature which exhibits a quantum phase transition between an ordered phase, corresponding to the superconducting state, and a disordered phase, corresponding to the insulating state with localized superconducting charge. Interestingly, we find that the critical line separating the two phases has a nonmonotonic behavior as a function of the dissipative coupling strength. This result is a consequence of the frustration between (i) one dissipative coupling that quenches the quantum phase fluctuations favoring the ordered phase and (ii) one that quenches the quantum momentum (charge) fluctuations leading to a vanishing phase coherence. Moreover, within the self-consistent harmonic approximation, we analyze the dissipation induced crossover between a first and second order phase transition, showing that quantum frustration increases the range in which the phase transition is second order. The nonmonotonic behavior is reflected also in the purity of the system that quantifies the degree of correlation between the system and the environment, and in the logarithmic negativity as an entanglement measure that encodes the internal quantum correlations in the chain.

  5. Phase transitions in glassy systems via convolutional neural networks

    Science.gov (United States)

    Fang, Chao

    Machine learning is a powerful approach commonplace in industry to tackle large data sets. Most recently, it has found its way into condensed matter physics, allowing for the first time the study of, e.g., topological phase transitions and strongly-correlated electron systems. The study of spin glasses is plagued by finite-size effects due to the long thermalization times needed. Here we use convolutional neural networks in an attempt to detect a phase transition in three-dimensional Ising spin glasses. Our results are compared to traditional approaches.

  6. The liquid to vapor phase transition in excited nuclei

    Energy Technology Data Exchange (ETDEWEB)

    Elliott, J.B.; Moretto, L.G.; Phair, L.; Wozniak, G.J.; Beaulieu, L.; Breuer, H.; Korteling, R.G.; Kwiatkowski, K.; Lefort, T.; Pienkowski, L.; Ruangma, A.; Viola, V.E.; Yennello, S.J.

    2001-05-08

    For many years it has been speculated that excited nuclei would undergo a liquid to vapor phase transition. For even longer, it has been known that clusterization in a vapor carries direct information on the liquid-vapor equilibrium according to Fisher's droplet model. Now the thermal component of the 8 GeV/c pion + 197 Au multifragmentation data of the ISiS Collaboration is shown to follow the scaling predicted by Fisher's model, thus providing the strongest evidence yet of the liquid to vapor phase transition.

  7. Techniques for detection of transition phases in calcined alumina

    International Nuclear Information System (INIS)

    Pandolfelli, V.C.; Folgueras-Dominguez, S.

    1987-01-01

    Detection of transition phases in alumina, is very important in the receiving control and calcination of aluminium hydroxide. The non alfa or transition phases difficults the processability and causes localized shrinkage on sintering compromising the dimensional and mechanical aspects of the product. In this research using refraction index, absorption of dyes, specific density, X-ray diffraction and scanning electron microscopy, analyses, are done in calcined hydroxides submited to different thermal treatments. The limits and facilities of each technique are discussed and compared. (Author) [pt

  8. The quantum phase-transitions of water

    Science.gov (United States)

    Fillaux, François

    2017-08-01

    It is shown that hexagonal ices and steam are macroscopically quantum condensates, with continuous spacetime-translation symmetry, whereas liquid water is a quantum fluid with broken time-translation symmetry. Fusion and vaporization are quantum phase-transitions. The heat capacities, the latent heats, the phase-transition temperatures, the critical temperature, the molar volume expansion of ice relative to water, as well as neutron scattering data and dielectric measurements are explained. The phase-transition mechanisms along with the key role of quantum interferences and that of Hartley-Shannon's entropy are enlightened. The notions of chemical bond and force-field are questioned.

  9. Phase transition phenomenon: A compound measure analysis

    Science.gov (United States)

    Kang, Bo Soo; Park, Chanhi; Ryu, Doojin; Song, Wonho

    2015-06-01

    This study investigates the well-documented phenomenon of phase transition in financial markets using combined information from both return and volume changes within short time intervals. We suggest a new measure for the phase transition behaviour of markets, calculated as a return distribution conditional on local variance in volume imbalance, and show that this measure successfully captures phase transition behaviour under various conditions. We analyse the intraday trade and quote dataset from the KOSPI 200 index futures, which includes detailed information on the original order size and the type of each initiating investor. We find that among these two competing factors, the submitted order size yields more explanatory power on the phenomenon of market phase transition than the investor type.

  10. Phase transition in the hadron gas model

    International Nuclear Information System (INIS)

    Gorenstein, M.I.; Petrov, V.K.; Zinov'ev, G.M.

    1981-01-01

    A class of statistical models of hadron gas allowing an analytical solution is considered. A mechanism of a possible phase transition in such a system is found and conditions for its occurence are determined [ru

  11. Phase Transitions, Diffraction Studies and Marginal Dimensionality

    DEFF Research Database (Denmark)

    Als-Nielsen, Jens Aage

    1985-01-01

    Continuous phase transitions and the associated critical phenomena have been one of the most active areas of research in condensed matter physics for several decades. This short review is only one cut through this huge subject and the author has chosen to emphasize diffraction studies as a basic...... experimental method and illustrate how diffraction experiments have revealed the role of dimensionality in the general classification of phase transitions...

  12. Phase transitions with four-spin interactions

    OpenAIRE

    Lebowitz, Joel L.; Ruelle, David

    2010-01-01

    Using an extended Lee-Yang theorem and GKS correlation inequalities, we prove, for a class of ferromagnetic multi-spin interactions, that they will have a phase transition(and spontaneous magnetization) if, and only if, the external field $h=0$ (and the temperature is low enough). We also show the absence of phase transitions for some nonferromagnetic interactions. The FKG inequalities are shown to hold for a larger class of multi-spin interactions.

  13. Instanton transition in thermal and moduli deformed de Sitter cosmology

    International Nuclear Information System (INIS)

    Kounnas, Costas; Partouche, Herve

    2008-01-01

    We consider the de Sitter cosmology deformed by the presence of a thermal bath of radiation and/or time-dependent moduli fields. Depending on the parameters, either a first or second-order phase transition can occur. In the first case, an instanton allows a double analytic continuation. It induces a probability to enter the inflationary evolution by tunnel effect from another cosmological solution. The latter starts with a big bang and, in the case the transition does not occur, ends with a big crunch. A temperature duality exchanges the two cosmological branches. In the limit where the pure de Sitter universe is recovered, the tunnel effect reduces to a 'creation from nothing', due to the vanishing of the big bang branch. However, the latter may be viable in some range of the deformation parameter. In the second case, there is a smooth evolution from a big bang to the inflationary phase

  14. A MATLAB GUI to study Ising model phase transition

    Science.gov (United States)

    Thornton, Curtislee; Datta, Trinanjan

    We have created a MATLAB based graphical user interface (GUI) that simulates the single spin flip Metropolis Monte Carlo algorithm. The GUI has the capability to study temperature and external magnetic field dependence of magnetization, susceptibility, and equilibration behavior of the nearest-neighbor square lattice Ising model. Since the Ising model is a canonical system to study phase transition, the GUI can be used both for teaching and research purposes. The presence of a Monte Carlo code in a GUI format allows easy visualization of the simulation in real time and provides an attractive way to teach the concept of thermal phase transition and critical phenomena. We will also discuss the GUI implementation to study phase transition in a classical spin ice model on the pyrochlore lattice.

  15. Transitions in the computational power of thermal states for measurement-based quantum computation

    International Nuclear Information System (INIS)

    Barrett, Sean D.; Bartlett, Stephen D.; Jennings, David; Doherty, Andrew C.; Rudolph, Terry

    2009-01-01

    We show that the usefulness of the thermal state of a specific spin-lattice model for measurement-based quantum computing exhibits a transition between two distinct 'phases' - one in which every state is a universal resource for quantum computation, and another in which any local measurement sequence can be simulated efficiently on a classical computer. Remarkably, this transition in computational power does not coincide with any phase transition, classical, or quantum in the underlying spin-lattice model.

  16. Phase transitions in two dimensions

    International Nuclear Information System (INIS)

    Henderson, D.

    1980-01-01

    Although a two-dimensional solid with long-range translational order cannot existin the thermodynamic limit (N → ∞, V →∞, N/V finite) macroscopic samples of two-dimensional solids can exist. In this work, stability of the phase was determined by the usuar method of equating the pressure and chemical potential of the phases. (A.C.A.S.) [pt

  17. Thermal transitions of the amorphous polymers in wheat straw

    Science.gov (United States)

    Wolfgang Stelte; Craig Clemons; Jens K. Holm; Jesper Ahrenfeldt; Ulrik B. Henriksen; Anand R. Sanadi

    2011-01-01

    The thermal transitions of the amorphous polymers in wheat straw were investigated using dynamic mechanical thermal analysis (DMTA). The study included both natural and solvent extracted wheat straw, in moist (8–9% water content) and dry conditions, and was compared to spruce samples. Under these conditions two transitions arising from the glass transition of lignin...

  18. Phase transitions in crystalline solids 1

    International Nuclear Information System (INIS)

    Walker, J.R.

    1993-09-01

    Many crystalline materials of interest to the Canadian Nuclear Program have the potential to undergo phase transitions in their range of application. During such phase transitions, a representation of the space group of the higher symmetry polymorph softens to induce the transition. This report is the first in a series of reports concerned with the group-theoretic properties of phase transitions in crystalline materials. The object of the research is to identify all spectroscopically-active soft modes for the 230 three-dimensional space groups. Identification of these soft modes will enable a detailed examination of phase transitions in materials of interest to the Canadian Nuclear Program and aid in the optimization of material properties. In this report, the group-theoretic properties of crystal structures and phase transitions are reviewed. It is demonstrated that the problem of extending a group reduces to that of determining its automorphisms. The automorphism groups of the crystallographic and icosahedral point groups are derived using a consistent presentation

  19. An absorbing phase transition from a structured active particle phase

    Energy Technology Data Exchange (ETDEWEB)

    Lopez, Cristobal [Instituto Mediterraneo de Estudios Avanzados IMEDEA (CSIC-UIB), Campus de la Universidad de las Islas Baleares, E-07122 Palma de Mallorca (Spain); Ramos, Francisco [Departamento de Electromagnetismo y Fisica de la Materia and Instituto de Fisica Teorica y Computacional Carlos I, Facultad de Ciencias, Universidad de Granada, 18071 Granada (Spain); Hernandez-GarcIa, Emilio [Instituto Mediterraneo de Estudios Avanzados IMEDEA (CSIC-UIB), Campus de la Universidad de las Islas Baleares, E-07122 Palma de Mallorca (Spain)

    2007-02-14

    In this work we study the absorbing state phase transition of a recently introduced model for interacting particles with neighbourhood-dependent reproduction rates. The novelty of the transition is that as soon as the active phase is reached by increasing a control parameter a periodically arranged structure of particle clusters appears. A numerical study in one and two dimensions shows that the system falls into the directed percolation universality class.

  20. The Structural Phase Transition in Solid DCN

    DEFF Research Database (Denmark)

    Dietrich, O. W.; Mackenzie, Gordon A.; Pawley, G. S.

    1975-01-01

    Neutron scattering measurements on deuterated hydrogen cyanide have shown that the structural phase change from a tetragonal to an orthorhombic form at 160K is a first-order transition. A transverse acoustic phonon mode, which has the symmetry of the phase change, was observed at very low energies...

  1. Symmetry structure and phase transitions

    Indian Academy of Sciences (India)

    Spontaneous symmetry breaking is one of the most important concepts of all unified gauge theories. The idea that ... stable configurations of gauge and Higgs fields in the form of domain walls, cosmic strings and monopoles on the ..... pressure to balance the surface tension and the pressure of the hadron phase. The quark.

  2. Linear Thermal Expansion Measurements with Sub-Atomic Resolution for the Study of Phase Transitions in Novel Condensed Matter Systems. Final Report

    International Nuclear Information System (INIS)

    Neumeier, John J.

    2010-01-01

    This grant has involved numerous projects focusing on further development of thermal expansion measurement technology. Significant improvements to our novel quartz thermal expansion cell have been realized. We have developed an absolute method for measuring the thermal expansion of materials under consideration for use in thermal expansion cell construction. The work associated with this grant has significantly expanded the capabilities and infrastructure for the measurement of the thermal expansion of solids at Montana State University. The techniques we develop have been transferred to students and postdocs through the training they receive. The National High Magnetic Field Laboratory (NHMFL) in Los Alamos has collaborated with the PI to import our quartz thermal expansion cells for measurements in pulsed-magnetic field as part of their user program. The significant progress made with our technology is expected to impact important problems in materials physics. Collaborations with LANL, ANL, BNL and ORNL formed a significant portion of the scientific work. Numerous scientific investigations associated with this grant have already appeared in the archival literature, or have been submitted. Some other work is still in progress, and will be the subject of future grant proposals and publications.

  3. Ultrafast dynamics during the photoinduced phase transition in VO2

    Science.gov (United States)

    Wegkamp, Daniel; Stähler, Julia

    2015-12-01

    The phase transition of VO2 from a monoclinic insulator to a rutile metal, which occurs thermally at TC = 340 K, can also be driven by strong photoexcitation. The ultrafast dynamics during this photoinduced phase transition (PIPT) have attracted great scientific attention for decades, as this approach promises to answer the question of whether the insulator-to-metal (IMT) transition is caused by electronic or crystallographic processes through disentanglement of the different contributions in the time domain. We review our recent results achieved by femtosecond time-resolved photoelectron, optical, and coherent phonon spectroscopy and discuss them within the framework of a selection of latest, complementary studies of the ultrafast PIPT in VO2. We show that the population change of electrons and holes caused by photoexcitation launches a highly non-equilibrium plasma phase characterized by enhanced screening due to quasi-free carriers and followed by two branches of non-equilibrium dynamics: (i) an instantaneous (within the time resolution) collapse of the insulating gap that precedes charge carrier relaxation and significant ionic motion and (ii) an instantaneous lattice potential symmetry change that represents the onset of the crystallographic phase transition through ionic motion on longer timescales. We discuss the interconnection between these two non-thermal pathways with particular focus on the meaning of the critical fluence of the PIPT in different types of experiments. Based on this, we conclude that the PIPT threshold identified in optical experiments is most probably determined by the excitation density required to drive the lattice potential change rather than the IMT. These considerations suggest that the IMT can be driven by weaker excitation, predicting a transiently metallic, monoclinic state of VO2 that is not stabilized by the non-thermal structural transition and, thus, decays on ultrafast timescales.

  4. Search for electronic phase separation at quantum phase transitions

    NARCIS (Netherlands)

    Pfleiderer, C.; Böni, P.; Franz, C.; Keller, T.; Neubauer, A.; Niklowitz, P.G.; Schmakat, P.; Schulz, M.; Huang, Y.; Mydosh, J.A.; Vojta, M.; Duncan, W.; Grosche, F.M.; Brando, M.; Deppe, M.; Geibel, C.; Steglich, F.; Krimmel, A.; Loidl, A.

    2010-01-01

    Phase separation and extreme sensitivity to disorder and defects are key features of electronic order near quantum phase transitions. Neutron depolarization imaging and neutron Larmor diffraction are new experimental techniques capable of providing detailed real-space and reciprocal-space

  5. Pairing phase transition in 106,107,108Pd

    International Nuclear Information System (INIS)

    Kadi, H.; Benhamouda, N.

    2015-01-01

    The pairing phase transition is investigated in hot even–even and even–odd Pd isotopes such as 106 ≤ A ≤ 108 in a framework of a microscopic approach that takes into account the statistical fluctuations. In this aim, one considers the Modified BCS method (MBCS). The latter is extended to the odd system case, where the blocking effect is included. The model was applied to the evaluation of the thermal properties such as the excitation energy, entropy and heat capacity. The obtained results are compared on one hand to the usual finite temperature BCS (FTBCS) method and on the other hand to the experimental data. The obtained results allow to show that the thermal fluctuations smooth out the superfluid-normal (SN) phase transition observed in the usual FTBCS results. Moreover, in the region where the pairing phase transition occurs, the experimental data of thermal properties are better reproduced when statistical fluctuations are considered in MBCS method instead of the FTBCS approach. (author)

  6. Phase transitions in methyl parben doped dipalmitoyl phosphatidylethanolamine vesicles

    Science.gov (United States)

    Panicker, Lata

    2013-02-01

    Influence of the preservative, methyl paraben (MPB), on the thermal properties of dipalmitoyl phosphatidylethanolamine (DPPE) vesicles was investigated using DSC. DSC measurement of the lipid acyl chain melting transition in DPPE membrane doped with MPB, showed MPB concentration dependant modifications in the membrane thermal properties. The interesting findings are: (1) the presence of parabens increases the membrane fluidity. (2) the MPB molecules seem to be present in the aqueous bilayer interfacial region intercalated between the neighboring lipid polar headgroup (3) high concentration of MPB favored formation of crystalline and glassy phases.

  7. Infinite cascades of phase transitions in the classical Ising chain

    Science.gov (United States)

    Timonin, P. N.; Chitov, Gennady Y.

    2017-12-01

    We report exact results on one of the best studied models in statistical physics: the classical antiferromagnetic Ising chain in a magnetic field. We show that the model possesses an infinite cascade of thermal phase transitions (also known as disorder lines or geometric phase transitions). The phase transition is signaled by a change of asymptotic behavior of the nonlocal string-string correlation functions when their monotonic decay becomes modulated by incommensurate oscillations. The transitions occur for rarefied (m -periodic) strings with arbitrary odd m . We propose a duality transformation which maps the Ising chain onto the m -leg Ising tube with nearest-neighbor couplings along the legs and the plaquette four-spin interactions of adjacent legs. Then the m -string correlation functions of the Ising chain are mapped onto the two-point spin-spin correlation functions along the legs of the m -leg tube. We trace the origin of these cascades of phase transitions to the lines of the Lee-Yang zeros of the Ising chain in m -periodic complex magnetic field, allowing us to relate these zeros to the observable (and potentially measurable) quantities.

  8. Titanium Heat Pipe Thermal Plane, Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — The objective of the Phase II program is to complete the development of the titanium heat pipe thermal plane and establish all necessary steps for production of this...

  9. Phase transitions in multiplicative competitive processes

    International Nuclear Information System (INIS)

    Shimazaki, Hideaki; Niebur, Ernst

    2005-01-01

    We introduce a discrete multiplicative process as a generic model of competition. Players with different abilities successively join the game and compete for finite resources. Emergence of dominant players and evolutionary development occur as a phase transition. The competitive dynamics underlying this transition is understood from a formal analogy to statistical mechanics. The theory is applicable to bacterial competition, predicting novel population dynamics near criticality

  10. Supersymmetric electroweak phase transition beyond perturbation theory

    CERN Document Server

    Cline, J M; Cline, James M; Kainulainen, Kimmo

    1996-01-01

    We compute the three-dimensional effective action for the minimal supersymmetric standard model, which describes the light modes of the theory near the finite-temperature electroweak phase transition, keeping the one-loop corrections from the third generation quarks and squarks. Using the lattice results of Kajantie et al. for the phase transition in the same class of 3-D models, we find that the strength of the phase transition is sufficient for electroweak baryogenesis, in much broader regions of parameter space than have been indicated by purely perturbative analyses. In particular we find that, while small values of \\tan\\beta are favored, positive results persist even for arbitrarily large values of \\tan\\beta if the mass of the A^0 boson is between 40 and 100 GeV, a region of parameters which has not been previously identified as being favorable for electroweak baryogenesis.

  11. Late-time cosmological phase transitions

    International Nuclear Information System (INIS)

    Schramm, D.N.

    1990-11-01

    It is shown that the potential galaxy formation and large-scale structure problems of objects existing at high redshifts (Z approx-gt 5), structures existing on scales of 100M pc as well as velocity flows on such scales, and minimal microwave anisotropies (ΔT/T) approx-lt 10 -5 can be solved if the seeds needed to generate structure form in a vacuum phase transition after decoupling. It is argued that the basic physics of such a phase transition is no more exotic than that utilized in the more traditional GUT scale phase transitions, and that, just as in the GUT case, significant random gaussian fluctuations and/or topological defects can form. Scale lengths of ∼100M pc for large-scale structure as well as ∼1 M pc for galaxy formation occur naturally. Possible support for new physics that might be associated with such a late-time transition comes from the preliminary results of the SAGE solar neutrino experiment, implying neutrino flavor mixing with values similar to those required for a late-time transition. It is also noted that a see-saw model for the neutrino masses might also imply a tau neutrino mass that is an ideal hot dark matter candidate. However, in general either hot or cold dark matter can be consistent with a late-time transition. 47 refs., 2 figs

  12. Thermal transistor utilizing gas-liquid transition

    KAUST Repository

    Komatsu, Teruhisa S.

    2011-01-25

    We propose a simple thermal transistor, a device to control heat current. In order to effectively change the current, we utilize the gas-liquid transition of the heat-conducting medium (fluid) because the gas region can act as a good thermal insulator. The three terminals of the transistor are located at both ends and the center of the system, and are put into contact with distinct heat baths. The key idea is a special arrangement of the three terminals. The temperature at one end (the gate temperature) is used as an input signal to control the heat current between the center (source, hot) and another end (drain, cold). Simulating the nanoscale systems of this transistor, control of heat current is demonstrated. The heat current is effectively cut off when the gate temperature is cold and it flows normally when it is hot. By using an extended version of this transistor, we also simulate a primitive application for an inverter. © 2011 American Physical Society.

  13. Network traffic behaviour near phase transition point

    Science.gov (United States)

    Lawniczak, A. T.; Tang, X.

    2006-03-01

    We explore packet traffic dynamics in a data network model near phase transition point from free flow to congestion. The model of data network is an abstraction of the Network Layer of the OSI (Open Systems Interconnect) Reference Model of packet switching networks. The Network Layer is responsible for routing packets across the network from their sources to their destinations and for control of congestion in data networks. Using the model we investigate spatio-temporal packets traffic dynamics near the phase transition point for various network connection topologies, and static and adaptive routing algorithms. We present selected simulation results and analyze them.

  14. Exceptional Points and Dynamical Phase Transitions

    Directory of Open Access Journals (Sweden)

    I. Rotter

    2010-01-01

    Full Text Available In the framework of non-Hermitian quantum physics, the relation between exceptional points,dynamical phase transitions and the counter intuitive behavior of quantum systems at high level density is considered. The theoretical results obtained for open quantum systems and proven experimentally some years ago on a microwave cavity, may explain environmentally induce deffects (including dynamical phase transitions, which have been observed in various experimental studies. They also agree(qualitatively with the experimental results reported recently in PT symmetric optical lattices.

  15. Dimension changing phase transitions in instanton crystals

    International Nuclear Information System (INIS)

    Kaplunovsky, Vadim; Sonnenschein, Jacob

    2014-01-01

    We investigate lattices of instantons and the dimension-changing transitions between them. Our ultimate goal is the 3D→4D transition, which is holographically dual to the phase transition between the baryonic and the quarkyonic phases of cold nuclear matter. However, in this paper (just as in http://dx.doi.org/10.1007/JHEP11(2012)047) we focus on lower dimensions — the 1D lattice of instantons in a harmonic potential V∝M 2 2 x 2 2 +M 3 2 x 2 2 +M 4 2 x 4 2 , and the zigzag-shaped lattice as a first stage of the 1D→2D transition. We prove that in the low- and moderate-density regimes, interactions between the instantons are dominated by two-body forces. This drastically simplifies finding the ground state of the instantons’ orientations, so we made a numeric scan of the whole orientation space instead of assuming any particular ansatz. We find that depending on the M 2 /M 3 /M 4 ratios, the ground state of instanton orientations can follow a wide variety of patterns. For the straight 1D lattices, we found orientations periodically running over elements of a ℤ 2 , Klein, prismatic, or dihedral subgroup of the SU(2)/ℤ 2 , as well as irrational but link-periodic patterns. For the zigzag-shaped lattices, we detected 4 distinct orientation phases — the anti-ferromagnet, another abelian phase, and two non-abelian phases. Allowing the zigzag amplitude to vary as a function of increasing compression force, we obtained the phase diagrams for the straight and zigzag-shaped lattices in the (force,M 3 /M 4 ), (chemical potential,M 3 /M 4 ), and (density,M 3 /M 4 ) planes. Some of the transitions between these phases are second-order while others are first-order. Our techniques can be applied to other types of non-abelian crystals

  16. Low-temperature structural phase transition in deuterated and protonated lithium acetate dihydrate

    Energy Technology Data Exchange (ETDEWEB)

    Schroeder, F., E-mail: schroeder@kristall.uni-frankfurt.d [Goethe-Universitaet Frankfurt am Main, Institut fuer Geowissenschaften, Abt. Kristallographie, Altenhoeferallee 1, 60438 Frankfurt am Main (Germany); Winkler, B.; Haussuehl, E. [Goethe-Universitaet Frankfurt am Main, Institut fuer Geowissenschaften, Abt. Kristallographie, Altenhoeferallee 1, 60438 Frankfurt am Main (Germany); Cong, P.T.; Wolf, B. [Goethe-Universitaet Frankfurt am Main, Physikalisches Institut, Max-von-Laue-Strasse 1, 60438 Frankfurt am Main (Germany); Avalos-Borja, M. [Instituto Potosino de Investigacion Cientifica y Tecnologica, A.C. Camino a la Presa San Jose 2055, Col. Lomas 4 seccion CP 78216, San Luis Potosi (Mexico); Quilichini, M.; Hennion, B. [Laboratoire Leon Brillouin, CEN Saclay, 91191 Gif-sur-Yvette (France)

    2010-08-15

    Heat capacity measurements of protonated lithium acetate dihydrate show a structural phase transition at T = 12 K. This finding is in contrast to earlier work, where it was thought that only the deuterated compound undergoes a low temperature structural phase transition. This finding is confirmed by low temperature ultrasound spectroscopy, where the structural phase transition is associated with a velocity decrease of the ultrasonic waves, i.e. with an elastic softening. We compare the thermodynamic properties of the protonated and deuterated compounds and discuss two alternatives for the mechanism of the phase transition based on the thermal expansion measurements.

  17. Space Storm as a Dynamical Phase Transition

    Science.gov (United States)

    Wanliss, J. A.

    2006-12-01

    Fluctuations of the DST index were analyzed for several magnetic storms preceded by more than a week of extremely quiet conditions to establish that there is a rapid and unidirectional change in the Hurst scaling exponent at the time of storm onset. That is, the transition is accompanied by the specific signature of a rapid unidirectional change in the temporal fractal scaling of fluctuations in DST, signaling the formation of a new dynamical phase (or mode) which is considerably more organized than the background state. We compare these results to a model of multifractional Brownian motion and suggest that the relatively sudden change from a less correlated to a more correlated pattern of multiscale fluctuations at storm onset can be characterized in terms of nonequilibrium dynamical phase transitions. Initial results show that a dynamical transition in solar wind VBs is correlated with the storm onset for intense storms, suggesting that the transition observed in DST is of external solar wind origin, rather than internal magnetospheric origin. On the other hand, some results show a dynamical transition in solar wind scaling exponents not matched in DST. As well, we also present results for small storms where there is a strong dynamical transition in DST without a similar changes in the VBs scaling statistics. The results for small storms seem to reduce the importance of the solar wind fluctuations but the evidence for the intense storms seems to point to the solar wind as being responsible for providing the scale free properties in the DST fluctuations.

  18. Dynamical quantum phase transitions: a review

    Science.gov (United States)

    Heyl, Markus

    2018-05-01

    Quantum theory provides an extensive framework for the description of the equilibrium properties of quantum matter. Yet experiments in quantum simulators have now opened up a route towards the generation of quantum states beyond this equilibrium paradigm. While these states promise to show properties not constrained by equilibrium principles, such as the equal a priori probability of the microcanonical ensemble, identifying the general properties of nonequilibrium quantum dynamics remains a major challenge, especially in view of the lack of conventional concepts such as free energies. The theory of dynamical quantum phase transitions attempts to identify such general principles by lifting the concept of phase transitions to coherent quantum real-time evolution. This review provides a pedagogical introduction to this field. Starting from the general setting of nonequilibrium dynamics in closed quantum many-body systems, we give the definition of dynamical quantum phase transitions as phase transitions in time with physical quantities becoming nonanalytic at critical times. We summarize the achieved theoretical advances as well as the first experimental observations, and furthermore provide an outlook to major open questions as well as future directions of research.

  19. Scattering theory of topological phase transitions

    NARCIS (Netherlands)

    Fulga, Ion Cosma

    2013-01-01

    This thesis deals with characterizing topological phases as well as the transitions between them, focusing on transport properties and the effects of disorder. In Chapters 2 and 3 we derived scattering matrix expressions for the topological invariants of systems. This approach is oftentimes

  20. Locating phase transitions in computationally hard problems

    Indian Academy of Sciences (India)

    - ity does not seem to justify the .... Although phase transitions occur only in the thermodynamic limit, in the limit of infinitely large systems, as .... composition) for a system in the stochastic theory of adiabatic explosion [17]. In that thermodynamic ...

  1. Magnesium hydrides and their phase transitions

    Czech Academy of Sciences Publication Activity Database

    Paidar, Václav

    2016-01-01

    Roč. 41, č. 23 (2016), s. 9769-9773 ISSN 0360-3199 R&D Projects: GA MŠk(CZ) LD13069 Institutional support: RVO:68378271 Keywords : hydrogen * magnesium and transition metal hydrides * crystal structure stability * displacive phase transformations Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 3.582, year: 2016

  2. Vol. 3: Statistical Physics and Phase Transitions

    International Nuclear Information System (INIS)

    Sitenko, A.

    1993-01-01

    Problems of modern physics and the situation with physical research in Ukraine are considered. Programme of the conference includes scientific and general problems. Its proceedings are published in 6 volumes. The papers presented in this volume refer to statistical physics and phase transition theory

  3. Monte Carlo Simulation of Phase Transitions

    OpenAIRE

    村井, 信行; N., MURAI; 中京大学教養部

    1983-01-01

    In the Monte Carlo simulation of phase transition, a simple heat bath method is applied to the classical Heisenberg model in two dimensions. It reproduces the correlation length predicted by the Monte Carlo renor-malization group and also computed in the non-linear σ model

  4. Dynamical quantum phase transitions: a review.

    Science.gov (United States)

    Heyl, Markus

    2018-02-15

    Quantum theory provides an extensive framework for the description of the equilibrium properties of quantum matter. Yet experiments in quantum simulators have now opened up a route towards the generation of quantum states beyond this equilibrium paradigm. While these states promise to show properties not constrained by equilibrium principles, such as the equal a priori probability of the microcanonical ensemble, identifying the general properties of nonequilibrium quantum dynamics remains a major challenge, especially in view of the lack of conventional concepts such as free energies. The theory of dynamical quantum phase transitions attempts to identify such general principles by lifting the concept of phase transitions to coherent quantum real-time evolution. This review provides a pedagogical introduction to this field. Starting from the general setting of nonequilibrium dynamics in closed quantum many-body systems, we give the definition of dynamical quantum phase transitions as phase transitions in time with physical quantities becoming nonanalytic at critical times. We summarize the achieved theoretical advances as well as the first experimental observations, and furthermore provide an outlook to major open questions as well as future directions of research.

  5. Hysteresis in the phase transition of chocolate

    Science.gov (United States)

    Ren, Ruilong; Lu, Qunfeng; Lin, Sihua; Dong, Xiaoyan; Fu, Hao; Wu, Shaoyi; Wu, Minghe; Teng, Baohua

    2016-01-01

    We designed an experiment to reproduce the hysteresis phenomenon of chocolate appearing in the heating and cooling process, and then established a model to relate the solidification degree to the order parameter. Based on the Landau-Devonshire theory, our model gave a description of the hysteresis phenomenon in chocolate, which lays the foundations for the study of the phase transition behavior of chocolate.

  6. Scaling Concepts in Describing Continuous Phase Transitions

    Indian Academy of Sciences (India)

    these relations was among the main motivations that lead to scal- ing descriptions of behaviour near critical points. Phase Transitions: Preliminaries. The theoretical analyses of critical points, as well as their exposi- tion, have employed simplified models of interacting systems. We follow the same practice here, and define ...

  7. Two phase transitions in Nuclear Physics

    International Nuclear Information System (INIS)

    Bes, D.R.

    1985-01-01

    The status of the art of the problem associated with two phase transitions in the nuclear matter, viz.: the disappearance of the nuclear superfluiditiy with the raising of the rotation velocity and the appearance of an octupolar deformation in the actinide zone, is presented. (L.C.) [pt

  8. Phase transition to QGP matter : confined vs deconfined matter

    CERN Multimedia

    Maire, Antonin

    2015-01-01

    Simplified phase diagram of the nuclear phase transition, from the regular hadronic matter to the QGP phase. The sketch is meant to describe the transition foreseen along the temperature axis, at low baryochemical potential, µB.

  9. The Physics of Structural Phase Transitions

    CERN Document Server

    Fujimoto, Minoru

    2005-01-01

    Phase transitions in which crystalline solids undergo structural changes present an interesting problem in the interplay between the crystal structure and the ordering process that is typically nonlinear. Intended for readers with prior knowledge of basic condensed-matter physics, this book emphasizes the physics behind spontaneous structural changes in crystals. Starting with the relevant thermodynamic principles, the text discusses the nature of order variables in collective motion in structural phase transitions, where a singularity in such a collective mode is responsible for lattice instability as revealed by soft phonons. In this book, critical anomalies at second-order structural transitions are first analyzed with the condensate model. Discussions on the nonlinear ordering mechanism are followed with the soliton theory, thereby interpreting the role of long-range order. Relevant details for nonlinear mathematics are therefore given for minimum necessity. The text also discusses experimental methods fo...

  10. Magnetocaloric materials and first order phase transitions

    DEFF Research Database (Denmark)

    Neves Bez, Henrique

    of the properties of such materials.The experimental characterization of these materials is done through various different methods, such as X-ray diffraction, magnetometry, calorimetry, direct measurements of entropy change, capacitance dilatometry, scanning electron microscopy,energy-dispersive X-ray spectrometry...... shows a paradoxical behavior; the material shows features of both a first order phase transition and of a second order one. Identities as shift of the heat capacity peak and an asymmetric growth of of the entropy change with magnetic field would describe this material transition as a first order one...... temperature and field independent is exaggerated and perhaps cannot be taken.A series of La(Fe,Mn,Si)13Hz with slightly changes in the composition is also evaluated here. This material may present a second order phase transition for large content of Mn and Si, which will become a first order one as the Mn...

  11. Optical characterization of phase transitions in pure polymers and blends

    Energy Technology Data Exchange (ETDEWEB)

    Mannella, Gianluca A.; Brucato, Valerio; La Carrubba, Vincenzo, E-mail: vincenzo.lacarrubba@unipa.it [Department of Civil, Environmental, Aerospace and Materials Engineering (DICAM), University of Palermo, Viale delle Scienze, Ed. 8, 90128 Palermo (Italy)

    2015-12-17

    To study the optical properties of polymeric samples, an experimental apparatus was designed on purpose and set up. The sample is a thin film enclosed between two glass slides and a PTFE frame, with a very thin thermocouple placed on sample for direct temperature measurement. This sample holder was placed between two aluminum slabs, equipped with a narrow slit for optical measurements and with electrical resistances for temperature control. Sample was enlightened by a laser diode, whereas transmitted light was detected with a photodiode. Measurements were carried out on polyethylene-terephtalate (PET) and two different polyamides, tested as pure polymers and blends. The thermal history imposed to the sample consisted in a rapid heating from ambient temperature to a certain temperature below the melting point, a stabilization period, and then a heating at constant rate. After a second stabilization period, the sample was cooled. The data obtained were compared with DSC measurements performed with the same thermal history. In correspondence with transitions detected via DSC (e.g. melting, crystallization and cold crystallization), the optical signal showed a steep variation. In particular, crystallization resulted in a rapid decrease of transmitted light, whereas melting gave up an increase of light transmitted by the sample. Further variations in transmitted light were recorded for blends, after melting: those results may be related to other phase transitions, e.g. liquid-liquid phase separation. All things considered, the apparatus can be used to get reliable data on phase transitions in polymeric systems.

  12. Computational advances in transition phase analysis

    International Nuclear Information System (INIS)

    Morita, K.; Kondo, S.; Tobita, Y.; Shirakawa, N.; Brear, D.J.; Fischer, E.A.

    1994-01-01

    In this paper, historical perspective and recent advances are reviewed on computational technologies to evaluate a transition phase of core disruptive accidents in liquid-metal fast reactors. An analysis of the transition phase requires treatment of multi-phase multi-component thermohydraulics coupled with space- and energy-dependent neutron kinetics. Such a comprehensive modeling effort was initiated when the program of SIMMER-series computer code development was initiated in the late 1970s in the USA. Successful application of the latest SIMMER-II in USA, western Europe and Japan have proved its effectiveness, but, at the same time, several areas that require further research have been identified. Based on the experience and lessons learned during the SIMMER-II application through 1980s, a new project of SIMMER-III development is underway at the Power Reactor and Nuclear Fuel Development Corporation (PNC), Japan. The models and methods of SIMMER-III are briefly described with emphasis on recent advances in multi-phase multi-component fluid dynamics technologies and their expected implication on a future reliable transition phase analysis. (author)

  13. Structural Phase Transition in Adipic Acid

    Science.gov (United States)

    Srinivasa Gopalan, R.; Kumaradhas, P.; Kulkarni, G. U.

    1999-11-01

    The structure of adipic acid undergoing phase transition at ∼136 K has been investigated using single-crystal x-ray diffraction. On lowering the temperature, the a parameter of the room temperature monoclinic cell decreases by ∼0.25 Å. Accompanying the transition, the b parameter nearly triples while a reverts back to the room temperature value. Two-thirds of the molecules in the structure loses center of symmetry. Packing diagrams of the high- and low-temperature phases on superposition reveal that there exist alternating domains perpendicular to the b direction, which contain molecules with and without symmetry. Unsymmetric molecules show displacements along the ac diagonal. Intermolecular hydrogen contacts involving carboxylic oxygens and the methylene hydrogens seem to increase interchain interactions in the low-temperature phase.

  14. Non-linear elastic thermal stress analysis with phase changes

    International Nuclear Information System (INIS)

    Amada, S.; Yang, W.H.

    1978-01-01

    The non-linear elastic, thermal stress analysis with temperature induced phase changes in the materials is presented. An infinite plate (or body) with a circular hole (or tunnel) is subjected to a thermal loading on its inner surface. The peak temperature around the hole reaches beyond the melting point of the material. The non-linear diffusion equation is solved numerically using the finite difference method. The material properties change rapidly at temperatures where the change of crystal structures and solid-liquid transition occur. The elastic stresses induced by the transient non-homogeneous temperature distribution are calculated. The stresses change remarkably when the phase changes occur and there are residual stresses remaining in the plate after one cycle of thermal loading. (Auth.)

  15. Thermal transitions of the amorphous polymers in wheat straw

    DEFF Research Database (Denmark)

    Stelte, Wolfgang; Clemons, Craig; Holm, Jens K.

    2011-01-01

    The thermal transitions of the amorphous polymers in wheat straw were investigated using dynamic mechanical thermal analysis (DMTA). The study included both natural and solvent extracted wheat straw, in moist (8–9% water content) and dry conditions, and was compared to spruce samples. Under...... these conditions two transitions arising from the glass transition of lignin and hemicelluloses have been identified. Key transitions attributed to softening of lignin were found at 53, 63 and 91 °C for moist samples of wheat straw, extracted straw and spruce, respectively. Transitions for hemicelluloses were...

  16. Multilevel radiative thermal memory realized by the hysteretic metal-insulator transition of vanadium dioxide

    International Nuclear Information System (INIS)

    Ito, Kota; Nishikawa, Kazutaka; Iizuka, Hideo

    2016-01-01

    Thermal information processing is attracting much interest as an analog of electronic computing. We experimentally demonstrated a radiative thermal memory utilizing a phase change material. The hysteretic metal-insulator transition of vanadium dioxide (VO 2 ) allows us to obtain a multilevel memory. We developed a Preisach model to explain the hysteretic radiative heat transfer between a VO 2 film and a fused quartz substrate. The transient response of our memory predicted by the Preisach model agrees well with the measured response. Our multilevel thermal memory paves the way for thermal information processing as well as contactless thermal management

  17. Energy transition and phasing out nuclear

    International Nuclear Information System (INIS)

    Laponche, Bernard

    2013-05-01

    In the first part of this report, the author outlines and comments the need of an energy transition in the world: overview of world challenges (world energy consumption and its constraints, a necessary energy transition, new actors and new responsibilities), and describes the German example of an energy transition policy. In the second part, he presents and discusses the main reasons for phasing out nuclear: description of a nuclear plant operation (fission and chain reaction, heat production, production of radioactive elements, how to stop a nuclear reactor), safety and risk issues (protection arrangements, risk and consequence of a nuclear accident), issue of radioactive wastes, relationship between civil techniques and proliferation of nuclear weapons. In a third part, the author proposes an overview of the energy issue in France: final energy consumption, electricity production and consumption, primary energy consumption, characteristics of the French energy system (oil dependency, electricity consumption, and high share of nuclear energy in electricity production). In a last part, the author addresses the issue of energy transition in a perspective of phasing out nuclear: presentation of the Negawatt scenario, assessments made by Global Chance, main programmes of energy transition

  18. Phase transition signals of finite systems

    International Nuclear Information System (INIS)

    Duflot-Flandrois, Veronique

    2001-01-01

    Phase transitions are universal properties of interacting matter. They are well described if the considered system is infinite, by using standard thermodynamics. But in the case of small systems like atomic nuclei, this formalism cannot be applied anymore. Our aim is to propose a statistical mechanics approach in order to define the thermodynamical features of small open systems subject to non-saturating forces. We concentrate in particular on the definition and characterization for such systems of phase transitions belonging to the liquid gas universality class. Theoretical and experimental observables are defined to signal the occurrence and the order of this transition without any ambiguity. One of the most relevant and experimentally accessible observables consists in the study of kinetic energy fluctuations for a fixed value of the total deposited energy. In a first order phase transition such fluctuations become anomaly high and at the same time the size distribution appears to behave critically. All our results are obtained within numerical simulations of the lattice gas model with a nearest neighbors attractive interaction. Finally we check the influence of non-saturating forces, developing the specific example of the Coulomb interaction in the nucleus. Future improvements and perspectives at this work consist in the analysis of specific effects occurring in nuclei: isospin and quantum mechanics. (author) [fr

  19. Sprayable Phase Change Coating Thermal Protection Material

    Science.gov (United States)

    Richardson, Rod W.; Hayes, Paul W.; Kaul, Raj

    2005-01-01

    NASA has expressed a need for reusable, environmentally friendly, phase change coating that is capable of withstanding the heat loads that have historically required an ablative thermal insulation. The Space Shuttle Program currently relies on ablative materials for thermal protection. The problem with an ablative insulation is that, by design, the material ablates away, in fulfilling its function of cooling the underlying substrate, thus preventing the insulation from being reused from flight to flight. The present generation of environmentally friendly, sprayable, ablative thermal insulation (MCC-l); currently use on the Space Shuttle SRBs, is very close to being a reusable insulation system. In actual flight conditions, as confirmed by the post-flight inspections of the SRBs, very little of the material ablates. Multi-flight thermal insulation use has not been qualified for the Space Shuttle. The gap that would have to be overcome in order to implement a reusable Phase Change Coating (PCC) is not unmanageable. PCC could be applied robotically with a spray process utilizing phase change material as filler to yield material of even higher strength and reliability as compared to MCC-1. The PCC filled coatings have also demonstrated potential as cryogenic thermal coatings. In experimental thermal tests, a thin application of PCC has provided the same thermal protection as a much thicker and heavier application of a traditional ablative thermal insulation. In addition, tests have shown that the structural integrity of the coating has been maintained and phase change performance after several aero-thermal cycles was not affected. Experimental tests have also shown that, unlike traditional ablative thermal insulations, PCC would not require an environmental seal coat, which has historically been required to prevent moisture absorption by the thermal insulation, prevent environmental degradation, and to improve the optical and aerodynamic properties. In order to reduce

  20. Adaptive phase estimation with squeezed thermal light

    DEFF Research Database (Denmark)

    Berni, A. A.; Madsen, Lars Skovgaard; Lassen, Mikael Østergaard

    2013-01-01

    a squeezed vacuum into an interferometer . However, this approach leads to enhanced sensitivity only for small phase shifts. In this work we aim for ab initio sub-shot noise estimation of an unknown phase shift using a pre-determined squeezed probe and an adaptive measurement approach. We experimentally...... investigate the performances of such protocol under the realistic assumption of thermalization of the probe state. Indeed, adaptive phase estimation schemes with squeezed states and Bayesian processing of homodyne data have been shown to be asymptotically optimal in the pure case, thus approaching the quantum...... Cramér-Rao bound. In our protocol we take advantage of the enhanced sensitivity of homodyne detection in proximity of the optimal phase which maximizes the homodyne Fisher information. A squeezed thermal probe state (signal) undergoes an unknown phase shift. The first estimation step involves...

  1. Cubic to tetragonal phase transition of Tm3+ doped nanocrystals in oxyfluoride glass ceramics

    International Nuclear Information System (INIS)

    Li, Yiming; Fu, Yuting; Shi, Yahui; Zhang, Xiaoyu; Yu, Hua; Zhao, Lijuan

    2016-01-01

    Tm 3+ ions doped β-PbF 2 nanocrystals in oxyfluoride glass ceramics with different doping concentrations and thermal temperatures are prepared by a traditional melt-quenching and thermal treatment method to investigate the structure and the phase transition of Tm 3+ doped nanocrystals. The structures are characterized by X-ray diffraction Rietveld analysis and confirmed with numerical simulation. The phase transitions are proved further by the emission spectra. Both of the doping concentration and thermal temperature can induce an O h to D 4h site symmetry distortion and a cubic to tetragonal phase transition. The luminescence of Tm 3+ doped nanocrystals at 800 nm was modulated by the phase transition of the surrounding crystal field

  2. Space storm as a phase transition

    Science.gov (United States)

    Wanliss, J. A.; Dobias, P.

    2007-04-01

    Fluctuations of the SYM-H index were analyzed for several space storms preceded by more than a week of extremely quiet conditions to establish that there was a rapid and unidirectional change in the Hurst scaling exponent at the time of storm onset. That is, the transition was accompanied by the specific signature of a rapid unidirectional change in the temporal fractal scaling of fluctuations in SYM-H, signaling the formation of a new dynamical phase (or mode) which was considerably more organized than the background state. We compare these results to a model of multifractional Brownian motion and suggest that the relatively sudden change from a less correlated to a more correlated pattern of multiscale fluctuations at storm onset can be characterized in terms of nonequilibrium dynamical phase transitions. The results show that a dynamical transition in solar wind VB is correlated with the storm onset for intense storms, suggesting that the dynamical transition observed in SYM-H is of external solar wind origin, rather than internal magnetospheric origin. However, some results showed a dynamical transition in solar wind scaling exponents not matched by similar transitions in SYM-H. In other instances, we observed some small storms where there was a strong dynamical transition in SYM-H without similar changes in the VB scaling statistics, suggesting that changes were due to internal magnetospheric processes. In summary, the results for intense storms points to the solar wind as being responsible for providing the scale free properties in the SYM-H fluctuations but the evidence for small storms clearly limit the importance of the solar wind fluctuations; their interaction is more complex than simple causality.

  3. About the dynamics of structural phase transitions

    International Nuclear Information System (INIS)

    Medeiros, J.T.N.

    1975-01-01

    The dynamics of structural phase transitions with a fourth order interaction between the soft phonon fields is studied in the 1/n approximation, using many body methods at finite temperatures. Two limits are considered: high transition temperature T sub(c) (classical limit) and T sub(c) = 0 (quantum limit). The dynamical contribution to the critical coefficient eta of the correlation function is calculated in these limits. It is found that there is no dynamical contribution to eta in the classical limit, whereas in the quantum limit eta is non-zero only for dimensions of the system d [pt

  4. Phase transitions in Pareto optimal complex networks.

    Science.gov (United States)

    Seoane, Luís F; Solé, Ricard

    2015-09-01

    The organization of interactions in complex systems can be described by networks connecting different units. These graphs are useful representations of the local and global complexity of the underlying systems. The origin of their topological structure can be diverse, resulting from different mechanisms including multiplicative processes and optimization. In spatial networks or in graphs where cost constraints are at work, as it occurs in a plethora of situations from power grids to the wiring of neurons in the brain, optimization plays an important part in shaping their organization. In this paper we study network designs resulting from a Pareto optimization process, where different simultaneous constraints are the targets of selection. We analyze three variations on a problem, finding phase transitions of different kinds. Distinct phases are associated with different arrangements of the connections, but the need of drastic topological changes does not determine the presence or the nature of the phase transitions encountered. Instead, the functions under optimization do play a determinant role. This reinforces the view that phase transitions do not arise from intrinsic properties of a system alone, but from the interplay of that system with its external constraints.

  5. Synthesis and nanoscale thermal encoding of phase-change nanowires

    International Nuclear Information System (INIS)

    Sun Xuhui; Yu Bin; Meyyappan, M.

    2007-01-01

    Low-dimensional phase-change nanostructures provide a valuable research platform for understanding the phase-transition behavior and thermal properties at nanoscale and their potential in achieving superdense data storage. Ge 2 Sb 2 Te 5 nanowires have been grown using a vapor-liquid-solid technique and shown to exhibit distinctive properties that may overcome the present data storage scaling barrier. Local heating of an individual nanowire with a focused electron beam was used to shape a nano-bar-code on a Ge 2 Sb 2 Te 5 nanowire. The data encoding on Ge 2 Sb 2 Te 5 nanowire may promote novel device concepts to implement ultrahigh density, low energy, high speed data storage using phase-change nanomaterials with diverse thermal-programing strategies

  6. Phase change material thermal capacitor clothing

    Science.gov (United States)

    Buckley, Theresa M. (Inventor)

    2005-01-01

    An apparatus and method for metabolic cooling and insulation of a user in a cold environment. In its preferred embodiment the apparatus is a highly flexible composite material having a flexible matrix containing a phase change thermal storage material. The apparatus can be made to heat or cool the body or to act as a thermal buffer to protect the wearer from changing environmental conditions. The apparatus may also include an external thermal insulation layer and/or an internal thermal control layer to regulate the rate of heat exchange between the composite and the skin of the wearer. Other embodiments of the apparatus also provide 1) a path for evaporation or direct absorption of perspiration from the skin of the wearer for improved comfort and thermal control, 2) heat conductive pathways within the material for thermal equalization, 3) surface treatments for improved absorption or rejection of heat by the material, and 4) means for quickly regenerating the thermal storage capacity for reuse of the material. Applications of the composite materials are also described which take advantage of the composite's thermal characteristics. The examples described include a diver's wet suit, ski boot liners, thermal socks, gloves and a face mask for cold weather activities, and a metabolic heating or cooling blanket useful for treating hypothermia or fever patients in a medical setting and therapeutic heating or cooling orthopedic joint supports.

  7. Comparing two tetraalkylammonium ionic liquids. II. Phase transitions

    Energy Technology Data Exchange (ETDEWEB)

    Lima, Thamires A.; Paschoal, Vitor H.; Faria, Luiz F. O.; Ribeiro, Mauro C. C., E-mail: mccribei@iq.usp.br [Laboratório de Espectroscopia Molecular, Departamento de Química Fundamental, Instituto de Química, Universidade de São Paulo, CP 26077, CEP 05513-970 São Paulo, SP (Brazil); Ferreira, Fabio F.; Costa, Fanny N. [Centro de Ciências Naturais e Humanas, Universidade Federal do ABC, Santo André, SP (Brazil); Giles, Carlos [Depto. de Física da Matéria Condensada, Instituto de Física Gleb Wataghin, Universidade Estadual de Campinas, 13083-859 Campinas, SP (Brazil)

    2016-06-14

    Phase transitions of the ionic liquids n-butyl-trimethylammonium bis(trifluoromethanesulfonyl)imide, [N{sub 1114}][NTf{sub 2}], and methyl-tributylammonium bis(trifluoromethanesulfonyl)imide, [N{sub 1444}][NTf{sub 2}], were investigated by differential scanning calorimetry (DSC), X-ray diffraction (XRD) measurements, and Raman spectroscopy. XRD and Raman spectra were obtained as a function of temperature at atmospheric pressure, and also under high pressure at room temperature using a diamond anvil cell (DAC). [N{sub 1444}][NTf{sub 2}] experiences glass transition at low temperature, whereas [N{sub 1114}][NTf{sub 2}] crystallizes or not depending on the cooling rate. Both the ionic liquids exhibit glass transition under high pressure. XRD and low-frequency Raman spectra provide a consistent physical picture of structural ordering-disordering accompanying the thermal events of crystallization, glass transition, cold crystallization, pre-melting, and melting. Raman spectra in the high-frequency range of some specific cation and anion normal modes reveal conformational changes of the molecular structures along phase transitions.

  8. Transition phase in LMFBR hypothetical accidents

    International Nuclear Information System (INIS)

    Ostensen, R.W.; Henninger, R.J.; Jackson, J.F.

    1976-01-01

    Mechanistic analyses of transient-under-cooling accidents have led in some cases to a mild initiating phase instead of a direct hydrodynamic disassembly of the core. The fuel is then trapped in the core by the strong mechanical surroundings and blockages formed by refrozen cladding steel and/or fuel. The formation of fuel blockages has been verified experimentally. The bottled-up core will boil on fission and decay heat, with steel as the working fluid. Boil-up in a churn turbulent flow regime may prevent recriticality due to fuel recompaction. Ultimate fuel removal from the core is probably by a two-phase blow-down after permanent leakage paths are opened. However, a vigorous recriticality can not be precluded. Reactors with void coefficients larger than that in CRBR are more likely to disassemble in the initiating phase, so the transition phase may be unique to small cores

  9. Thermalization calorimetry: A simple method for investigating glass transition and crystallization of supercooled liquids

    DEFF Research Database (Denmark)

    Jakobsen, Bo; Sanz, Alejandro; Niss, Kristine

    2016-01-01

    and their crystallization, e.g., for locating the glass transition and melting point(s), as well as for investigating the stability against crystallization and estimating the relative change in specific heat between the solid and liquid phases at the glass transition......We present a simple method for fast and cheap thermal analysis on supercooled glass-forming liquids. This “Thermalization Calorimetry” technique is based on monitoring the temperature and its rate of change during heating or cooling of a sample for which the thermal power input comes from heat...

  10. Gravitational Waves from a Dark Phase Transition.

    Science.gov (United States)

    Schwaller, Pedro

    2015-10-30

    In this work, we show that a large class of models with a composite dark sector undergo a strong first order phase transition in the early Universe, which could lead to a detectable gravitational wave signal. We summarize the basic conditions for a strong first order phase transition for SU(N) dark sectors with n_{f} flavors, calculate the gravitational wave spectrum and show that, depending on the dark confinement scale, it can be detected at eLISA or in pulsar timing array experiments. The gravitational wave signal provides a unique test of the gravitational interactions of a dark sector, and we discuss the complementarity with conventional searches for new dark sectors. The discussion includes the twin Higgs and strongly interacting massive particle models as well as symmetric and asymmetric composite dark matter scenarios.

  11. Electroweak monopoles and the electroweak phase transition

    Energy Technology Data Exchange (ETDEWEB)

    Arunasalam, Suntharan; Kobakhidze, Archil [The University of Sydney, ARC Centre of Excellence for Particle Physics at the Terascale, School of Physics, Sydney, NSW (Australia)

    2017-07-15

    We consider an isolated electroweak monopole solution within the Standard Model with a nonlinear Born-Infeld extension of the hypercharge gauge field. Monopole (and dyon) solutions in such an extension are regular and their masses are predicted to be proportional to the Born-Infeld mass parameter. We argue that cosmological production of electroweak monopoles may delay the electroweak phase transition and make it more strongly first order for monopole masses M >or similar 9.3 . 10{sup 3} TeV, while the nucleosynthesis constraints on the abundance of relic monopoles impose the bound M phase transition. (orig.)

  12. Phase transitions and elementary-particle physics

    International Nuclear Information System (INIS)

    Creutz, M.

    1981-01-01

    The reason physicists have recently taken an intense interest in the statistical mechanics of certain lattice models is reviewed. Phase transitions in these systems are of direct relevance to whether the gauge theory of interacting quarks and gluons can prevent the quark as appearing as a free isolated object. Monte Carlo simulation techniques have given the strongest evidence for the confinement phenomenon and are beginning to make numerical predictions in strong interaction physics

  13. Gravitation, phase transitions, and the big bang

    International Nuclear Information System (INIS)

    Krauss, L.M.

    1982-01-01

    Introduced here is a model of the early universe based on the possibility of a first-order phase transition involving gravity, and arrived at by a consideration of instabilities in the semiclassical theory. The evolution of the system is very different from the standard Friedmann-Robertson-Walker big-bang scenario, indicating the potential importance of semiclassical finite-temperature gravitational effects. Baryosynthesis and monopole production in this scenario are also outlined

  14. The use of lipids as phase change materials for thermal energy storage

    Science.gov (United States)

    Phase change materials (PCMs) are substances capable of absorbing and releasing large 2 amounts of thermal energy (heat or cold) as latent heat over constant temperature as they 3 undergo a change in state of matter (phase transition), commonly, between solid and 4 liquid phases. Since the late 194...

  15. Phase transitions of ε-HNIW in compound systems

    Directory of Open Access Journals (Sweden)

    Jing-yuan Zhang

    2016-05-01

    Full Text Available The heat-induced phase transitions of ε-HNIW, both neat and coated with various additives used in plastic bonded explosives, were investigated using powder X-ray diffraction and differential scanning calorimetry. It was found that ε-HNIW, after being held at 70°C for 60h, remained in the ε-phase. Applying other conditions, various phase transition parameters were determined, including Tc (the critical phase transition temperature, T50 (the temperature at which 50% of the phase transition is complete and T180 (the percentage of γ-HNIW present in samples heated to 180°C. According to the above three parameters, additives were divided into three categories: those that delay phase transition, those that raise the critical temperature and the transition rate, and those that promote the phase transition. Based on the above data, a phase transition mechanism is proposed.

  16. Compact Stars with Sequential QCD Phase Transitions.

    Science.gov (United States)

    Alford, Mark; Sedrakian, Armen

    2017-10-20

    Compact stars may contain quark matter in their interiors at densities exceeding several times the nuclear saturation density. We explore models of such compact stars where there are two first-order phase transitions: the first from nuclear matter to a quark-matter phase, followed at a higher density by another first-order transition to a different quark-matter phase [e.g., from the two-flavor color-superconducting (2SC) to the color-flavor-locked (CFL) phase]. We show that this can give rise to two separate branches of hybrid stars, separated from each other and from the nuclear branch by instability regions, and, therefore, to a new family of compact stars, denser than the ordinary hybrid stars. In a range of parameters, one may obtain twin hybrid stars (hybrid stars with the same masses but different radii) and even triplets where three stars, with inner cores of nuclear matter, 2SC matter, and CFL matter, respectively, all have the same mass but different radii.

  17. Second-order phase transitions of pure substances

    NARCIS (Netherlands)

    Schaftenaar, H.P.C.

    2009-01-01

    In this report we are dealing with the thermodynamic theory of second-order phase transitions or continuous transitions of unary systems. The first classification of these phase transitions is due to Ehrenfest (1933), based on chemical potentials. First-order transitions are changes in which the

  18. Thermal Energy Storage with Phase Change Material

    Directory of Open Access Journals (Sweden)

    Lavinia Gabriela SOCACIU

    2012-08-01

    Full Text Available Thermal energy storage (TES systems provide several alternatives for efficient energy use and conservation. Phase change materials (PCMs for TES are materials supplying thermal regulation at particular phase change temperatures by absorbing and emitting the heat of the medium. TES in general and PCMs in particular, have been a main topic in research for the last 30 years, but although the information is quantitatively enormous, it is also spread widely in the literature, and difficult to find. PCMs absorb energy during the heating process as phase change takes place and release energy to the environment in the phase change range during a reverse cooling process. PCMs possesses the ability of latent thermal energy change their state with a certain temperature. PCMs for TES are generally solid-liquid phase change materials and therefore they need encapsulation. TES systems using PCMs as a storage medium offers advantages such as high TES capacity, small unit size and isothermal behaviour during charging and discharging when compared to the sensible TES.

  19. Phase transitions in shocked porous quartz

    Science.gov (United States)

    Akin, M. C.; Crum, R. S.; Lind, J.; Pagan, D. C.; Homel, M. A.; Hurley, R. C.; Herbold, E. B.

    2017-06-01

    The presence of porosity in granular media provides the means to probe regions of the phase diagram that do not coincide with the principal Hugoniot. In particular, the potential for increased heating is likely to lead to observable changes in phase boundaries. 55% dense quartz and forsterite were prepared by tap filling. These samples were shock compressed using the two stage light gas gun at DCS-APS to examine the impact of the increased porosity on the phase boundary. Here we discuss the observed changes to phase in quartz and forsterite compared to the fully dense materials, the effects of porosity upon compaction and phase transitions, and the implications for constructing the phase diagram. This work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. Work was supported by LLNL's LDRD program under Grant 16-ERD-010. The Dynamic Compression Sector (35) is supported by Department of Energy / National Nuclear Security Administration under Award Number DE-NA0002442. This research used resources of the Advanced Photon Source, a U.S. Department of Energy (DOE) Office of Science User Facility operated for the DOE Office of Science by Argonne National Laboratory under Contract No. DE-AC02-06CH11357.

  20. Structural phase transition in monolayer MoTe2 driven by electrostatic doping

    Science.gov (United States)

    Wang, Ying; Xiao, Jun; Zhu, Hanyu; Li, Yao; Alsaid, Yousif; Fong, King Yan; Zhou, Yao; Wang, Siqi; Shi, Wu; Wang, Yuan; Zettl, Alex; Reed, Evan J.; Zhang, Xiang

    2017-10-01

    Monolayers of transition-metal dichalcogenides (TMDs) exhibit numerous crystal phases with distinct structures, symmetries and physical properties. Exploring the physics of transitions between these different structural phases in two dimensions may provide a means of switching material properties, with implications for potential applications. Structural phase transitions in TMDs have so far been induced by thermal or chemical means; purely electrostatic control over crystal phases through electrostatic doping was recently proposed as a theoretical possibility, but has not yet been realized. Here we report the experimental demonstration of an electrostatic-doping-driven phase transition between the hexagonal and monoclinic phases of monolayer molybdenum ditelluride (MoTe2). We find that the phase transition shows a hysteretic loop in Raman spectra, and can be reversed by increasing or decreasing the gate voltage. We also combine second-harmonic generation spectroscopy with polarization-resolved Raman spectroscopy to show that the induced monoclinic phase preserves the crystal orientation of the original hexagonal phase. Moreover, this structural phase transition occurs simultaneously across the whole sample. This electrostatic-doping control of structural phase transition opens up new possibilities for developing phase-change devices based on atomically thin membranes.

  1. The transition to chaotic phase synchronization

    Science.gov (United States)

    Mosekilde, E.; Laugesen, J. L.; Zhusubaliyev, Zh. T.

    2012-08-01

    The transition to chaotic phase synchronization for a periodically driven spiral-type chaotic oscillator is known to involve a dense set of saddle-node bifurcations. By following the synchronization transition through the cascade of period-doubling bifurcations in a forced Rössler system, this paper describes how these saddle-node bifurcations arise and how their characteristic cyclic organisation develops. We identify the cycles that are involved in the various saddle-node bifurcations and descibe how the formation of multi-layered resonance cycles in the synchronization domain is related to the torus doubling bifurcations that take place outside this domain. By examining a physiology-based model of the blood flow regulation to the individual functional unit (nephron) of the kidney we demonstrate how a similar bifurcation structure may arise in this system as a response to a periodically varying arterial blood pressure. The paper finally discusses how an alternative transition to chaotic phase synchronization may occur in the mutual synchronization of two chaotically oscillating period-doubling systems.

  2. Casimir amplitudes in topological quantum phase transitions.

    Science.gov (United States)

    Griffith, M A; Continentino, M A

    2018-01-01

    Topological phase transitions constitute a new class of quantum critical phenomena. They cannot be described within the usual framework of the Landau theory since, in general, the different phases cannot be distinguished by an order parameter, neither can they be related to different symmetries. In most cases, however, one can identify a diverging length at these topological transitions. This allows us to describe them using a scaling approach and to introduce a set of critical exponents that characterize their universality class. Here we consider some relevant models of quantum topological transitions associated with well-defined critical exponents that are related by a quantum hyperscaling relation. We extend to these models a finite-size scaling approach based on techniques for calculating the Casimir force in electromagnetism. This procedure allows us to obtain universal Casimir amplitudes at their quantum critical points. Our results verify the validity of finite-size scaling in these systems and confirm the values of the critical exponents obtained previously.

  3. Casimir amplitudes in topological quantum phase transitions

    Science.gov (United States)

    Griffith, M. A.; Continentino, M. A.

    2018-01-01

    Topological phase transitions constitute a new class of quantum critical phenomena. They cannot be described within the usual framework of the Landau theory since, in general, the different phases cannot be distinguished by an order parameter, neither can they be related to different symmetries. In most cases, however, one can identify a diverging length at these topological transitions. This allows us to describe them using a scaling approach and to introduce a set of critical exponents that characterize their universality class. Here we consider some relevant models of quantum topological transitions associated with well-defined critical exponents that are related by a quantum hyperscaling relation. We extend to these models a finite-size scaling approach based on techniques for calculating the Casimir force in electromagnetism. This procedure allows us to obtain universal Casimir amplitudes at their quantum critical points. Our results verify the validity of finite-size scaling in these systems and confirm the values of the critical exponents obtained previously.

  4. PHASE CHANGE MATERIALS IN FLOOR TILES FOR THERMAL ENERGY STORAGE

    Energy Technology Data Exchange (ETDEWEB)

    Douglas C. Hittle

    2002-10-01

    Passive solar systems integrated into residential structures significantly reduce heating energy consumption. Taking advantage of latent heat storage has further increased energy savings. This is accomplished by the incorporation of phase change materials into building materials used in passive applications. Trombe walls, ceilings and floors can all be enhanced with phase change materials. Increasing the thermal storage of floor tile by the addition of encapsulated paraffin wax is the proposed topic of research. Latent heat storage of a phase change material (PCM) is obtained during a change in phase. Typical materials use the latent heat released when the material changes from a liquid to a solid. Paraffin wax and salt hydrates are examples of such materials. Other PCMs that have been recently investigated undergo a phase transition from one solid form to another. During this process they will release heat. These are known as solid-state phase change materials. All have large latent heats, which makes them ideal for passive solar applications. Easy incorporation into various building materials is must for these materials. This proposal will address the advantages and disadvantages of using these materials in floor tile. Prototype tile will be made from a mixture of quartz, binder and phase change material. The thermal and structural properties of the prototype tiles will be tested fully. It is expected that with the addition of the phase change material the structural properties will be compromised to some extent. The ratio of phase change material in the tile will have to be varied to determine the best mixture to provide significant thermal storage, while maintaining structural properties that meet the industry standards for floor tile.

  5. Study of the deconfinement phase transition in a finite volume with massive particles: Hydrodynamics of the system near the transition

    Energy Technology Data Exchange (ETDEWEB)

    Ghenam, L.; Djoudi, A. Ait El [Laboratoire de Physique des Particules et Physique Statistique, Ecole Normale Superieure - Kouba, B.P. 92, 16050, Vieux Kouba, Algiers (Algeria)

    2012-06-27

    We study the finite size and finite mass effects for the thermal deconfinement phase transition in Quantum Chromodynamics (QCD), using a simple model of coexistence of hadronic (H) gas and quark-gluon plasma (QGP) phases in a finite volume. We consider the equations of state of the two phases with the QGP containing two massless u and d quarks and massive s quarks, and a hadronic gas of massive pions, and we probe the system near the transition. For this, we examine the behavior of the most important hydrodynamical quantities describing the system, at a vanishing chemical potential ({mu}= 0), with temperature and energy density.

  6. Phase stability of transition metals and alloys

    International Nuclear Information System (INIS)

    Hixson, R.S.; Schiferl, D.; Wills, J.M.; Hill, M.A.

    1997-01-01

    This is the final report of a three-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). This project was focused on resolving unexplained differences in calculated and measured phase transition pressures in transition metals. Part of the approach was to do new, higher accuracy calculations of transmission pressures for group 4B and group 6B metals. Theory indicates that the transition pressures for these baseline metals should change if alloyed with a d-electron donor metal, and calculations done using the Local Density Approximation (LDA) and the Virtual Crystal Approximation (VCA) indicate that this is true. Alloy systems were calculated for Ti, Zr and Hf based alloys with various solute concentrations. The second part of the program was to do new Diamond Anvil Cell (DAC) measurements to experimentally verify calculational results. Alloys were prepared for these systems with grain size suitable for Diamond Anvil Cell experiments. Experiments were done on pure Ti as well as Ti-V and Ti-Ta alloys. Measuring unambiguous transition pressures for these systems proved difficult, but a new technique developed yielded good results

  7. Quantum phase transitions in matrix product states

    International Nuclear Information System (INIS)

    Zhu Jingmin

    2008-01-01

    We present a new general and much simpler scheme to construct various quantum phase transitions (QPTs) in spin chain systems with matrix product ground states. By use of the scheme we take into account one kind of matrix product state (MPS) QPT and provide a concrete model. We also study the properties of the concrete example and show that a kind of QPT appears, accompanied by the appearance of the discontinuity of the parity absent block physical observable, diverging correlation length only for the parity absent block operator, and other properties which are that the fixed point of the transition point is an isolated intermediate-coupling fixed point of renormalization flow and the entanglement entropy of a half-infinite chain is discontinuous. (authors)

  8. Quantum Phase Transitions in Matrix Product States

    International Nuclear Information System (INIS)

    Jing-Min, Zhu

    2008-01-01

    We present a new general and much simpler scheme to construct various quantum phase transitions (QPTs) in spin chain systems with matrix product ground states. By use of the scheme we take into account one kind of matrix product state (MPS) QPT and provide a concrete model. We also study the properties of the concrete example and show that a kind of QPT appears, accompanied by the appearance of the discontinuity of the parity absent block physical observable, diverging correlation length only for the parity absent block operator, and other properties which are that the fixed point of the transition point is an isolated intermediate-coupling fixed point of renormalization flow and the entanglement entropy of a half-infinite chain is discontinuous

  9. Band Jahn-Teller structural phase transition in Y2In

    Science.gov (United States)

    Svanidze, E.; Georgen, C.; Hallas, A. M.; Huang, Q.; Santiago, J. M.; Lynn, J. W.; Morosan, E.

    2018-02-01

    The number of paramagnetic materials that undergo a structural phase transition is rather small, which can perhaps explain the limited understanding of the band Jahn-Teller mechanism responsible for this effect. Here we present a structural phase transition observed in paramagnetic Y2In at temperature T0=250 ±5 K. Below T0, the high-temperature hexagonal P 63/m m c phase transforms into the low-temperature orthorhombic P n m a phase. This transition is accompanied by an unambiguous thermal hysteresis of about 10 K, observed in both magnetic susceptibility M /H (T ) and resistivity ρ (T ) , indicating a first-order transition. Band structure calculations suggest a band Jahn-Teller mechanism, during which the degeneracy of electron bands close to the Fermi energy is broken. We establish that this structural phase transition does not have a magnetic component; however, the possibility of a charge density wave formation has not been eliminated.

  10. Phases and phase transitions in the algebraic microscopic shell model

    Directory of Open Access Journals (Sweden)

    Georgieva A. I.

    2016-01-01

    Full Text Available We explore the dynamical symmetries of the shell model number conserving algebra, which define three types of pairing and quadrupole phases, with the aim to obtain the prevailing phase or phase transition for the real nuclear systems in a single shell. This is achieved by establishing a correspondence between each of the pairing bases with the Elliott’s SU(3 basis that describes collective rotation of nuclear systems. This allows for a complete classification of the basis states of different number of particles in all the limiting cases. The probability distribution of the SU(3 basis states within theirs corresponding pairing states is also obtained. The relative strengths of dynamically symmetric quadrupole-quadrupole interaction in respect to the isoscalar, isovector and total pairing interactions define a control parameter, which estimates the importance of each term of the Hamiltonian in the correct reproduction of the experimental data for the considered nuclei.

  11. Thermal property prediction and measurement of organic phase change materials in the liquid phase near the melting point

    International Nuclear Information System (INIS)

    O’Connor, William E.; Warzoha, Ronald; Weigand, Rebecca; Fleischer, Amy S.; Wemhoff, Aaron P.

    2014-01-01

    Highlights: • Liquid-phase thermal properties for five phase change materials were estimated. • Various liquid phase and phase transition thermal properties were measured. • The thermal diffusivity was found using a best path to prediction approach. • The thermal diffusivity predictive method shows 15% agreement for organic PCMs. - Abstract: Organic phase change materials (PCMs) are a popular choice for many thermal energy storage applications including solar energy, building envelope thermal barriers, and passive cooling of portable electronics. Since the extent of phase change during a heating or cooling process is dependent upon rapid thermal penetration into the PCM, accurate knowledge of the thermal diffusivity of the PCM in both solid and liquid phases is crucial. This study addresses the existing gaps in information for liquid-phase PCM properties by examining an approach that determines the best path to prediction (BPP) for the thermal diffusivity of both alkanes and unsaturated acids. Knowledge of the BPP will enable researchers to explore the influence of PCM molecular structure on bulk thermophysical properties, thereby allowing the fabrication of optimized PCMs. The BPP method determines which of the tens of thousands of combinations of 22 different available theoretical techniques provides best agreement with thermal diffusivity values based on reported or measured density, heat capacity, and thermal conductivity for each of five PCMs (heneicosane, tricosane, tetracosane, oleic acid, and linoleic acid) in the liquid phase near the melting point. Separate BPPs were calibrated for alkanes based on heneicosane and tetracosane, and for the unsaturated acids. The alkane and unsaturated acid BPPs were then tested on a variety of similar materials, showing agreement with reported/measured thermal diffusivity within ∼15% for all materials. The alkane BPP was then applied to find that increasing the length of alkane chains decreases the PCM thermal

  12. Double thermal transitions of type I collagen in acidic solution.

    Science.gov (United States)

    Liu, Yan; Liu, Lingrong; Chen, Mingmao; Zhang, Qiqing

    2013-01-01

    Contributed equally to this work. To further understand the origin of the double thermal transitions of collagen in acidic solution induced by heating, the denaturation of acidic soluble collagen was investigated by micro-differential scanning calorimeter (micro-DSC), circular dichroism (CD), dynamic laser light scattering (DLLS), transmission electron microscopy (TEM), and two-dimensional (2D) synchronous fluorescence spectrum. Micro-DSC experiments revealed that the collagen exhibited double thermal transitions, which were located within 31-37 °C (minor thermal transition, T(s) ∼ 33 °C) and 37-55 °C (major thermal transition, T(m) ∼ 40 °C), respectively. The CD spectra suggested that the thermal denaturation of collagen resulted in transition from polyproline II type structure to unordered structure. The DLLS results showed that there were mainly two kinds of collagen fibrillar aggregates with different sizes in acidic solution and the larger fibrillar aggregates (T(p2) = 40 °C) had better heat resistance than the smaller one (T(p1) = 33 °C). TEM revealed that the depolymerization of collagen fibrils occurred and the periodic cross-striations of collagen gradually disappeared with increasing temperature. The 2D fluorescence correlation spectra were also applied to investigate the thermal responses of tyrosine and phenylalanine residues at the molecular level. Finally, we could draw the conclusion that (1) the minor thermal transition was mainly due to the defibrillation of the smaller collagen fibrillar aggregates and the unfolding of a little part of triple helices; (2) the major thermal transition primarily arose from the defibrillation of the larger collagen fibrillar aggregates and the complete denaturation of the majority part of triple helices.

  13. Phase transitions in de Sitter space

    Directory of Open Access Journals (Sweden)

    Alexander Vilenkin

    1983-10-01

    Full Text Available An effective potential in de Sitter space is calculated for a model of two interacting scalar fields in one-loop approximation and in a self-consistent approximation which takes into account an infinite set of diagrams. Various approaches to renormalization in de Sitter space are discussed. The results are applied to analyze the phase transition in the Hawking-Moss version of the inflationary universe scenario. Requiring that inflation is sufficiently large, we derive constraints on the parameters of the model.

  14. Chiral phase transition from string theory.

    Science.gov (United States)

    Parnachev, Andrei; Sahakyan, David A

    2006-09-15

    The low energy dynamics of a certain D-brane configuration in string theory is described at weak t'Hooft coupling by a nonlocal version of the Nambu-Jona-Lasinio model. We study this system at finite temperature and strong t'Hooft coupling, using the string theory dual. We show that for sufficiently low temperatures chiral symmetry is broken, while for temperatures larger then the critical value, it gets restored. We compute the latent heat and observe that the phase transition is of the first order.

  15. Traders' behavioral coupling and market phase transition

    Science.gov (United States)

    Ma, Rong; Zhang, Yin; Li, Honggang

    2017-11-01

    Traditional economic theory is based on the assumption that traders are completely independent and rational; however, trading behavior in the real market is often coupled by various factors. This paper discusses behavioral coupling based on the stock index in the stock market, focusing on the convergence of traders' behavior, its effect on the correlation of stock returns and market volatility. We find that the behavioral consensus in the stock market, the correlation degree of stock returns, and the market volatility all exhibit significant phase transitions with stronger coupling.

  16. Phase Transitions of Thermoelectric TAGS-85

    OpenAIRE

    Kumar, Anil; Vermeulen, Paul A.; Kooi, Bart J.; Rao, Jiancun; van Eijck, Lambert; Schwarzmueller, Stefan; Oeckler, Oliver; Blake, Graeme R.

    2017-01-01

    The alloys (GeTe)x(AgSbTe2)100–x, commonly known as TAGS-x, are among the best performing p-type thermoelectric materials for the composition range 80 ≤ x ≤ 90 and in the temperature range 200–500 °C. They adopt a rhombohedrally distorted rocksalt structure at room temperature and are reported to undergo a reversible phase transition to a cubic structure at ∼250 °C. However, we show that, for the optimal x = 85 composition (TAGS-85), both the structural and thermoelectric properties are highl...

  17. A Note on Holography and Phase Transitions

    Directory of Open Access Journals (Sweden)

    Marc Bellon

    2011-01-01

    Full Text Available Focusing on the connection between the Landau theory of second-order phase transitions and the holographic approach to critical phenomena, we study diverse field theories in an anti de Sitter black hole background. Through simple analytical approximations, solutions to the equations of motion can be obtained in closed form which give rather good approximations of the results obtained using more involved numerical methods. The agreement we find stems from rather elementary considerations on perturbation of Schrödinger equations.

  18. Miscellaneous results on the electroweak phase transition

    International Nuclear Information System (INIS)

    Ilgenfritz, E.M.; Schiller, A.

    1994-12-01

    We present new 4-D Monte Carlo results characterizing the strength of the finite temperature phase transition for Higgs/W mass ratios 1.0 and 0.6, obtained on isotropic lattices mainly with N s = 16, N t = 2. We discuss the distribution of a gauge invariant block spin order parameter, estimating the Higgs condensate Φ c at T c . We use the Potvin/Rebbi method in order to find the interface tension α/T c 3 . We demonstrate how the multi-histogram method (giving free energy differences) can be used to avoid the limiting procedure δ K → 0. From pure-phase histograms at K c , extrapolated with the help of this method, we estimate the latent heat Δε/T c 4 . Actual time series at lower Higgs mass require blocking in order to determine the jump of the lattice observables. (orig.)

  19. Phase Change Material Thermal Power Generator

    Science.gov (United States)

    Jones, Jack A.

    2013-01-01

    An innovative modification has been made to a previously patented design for the Phase Change Material (PCM) Thermal Generator, which works in water where ocean temperature alternatively melts wax in canisters, or allows the wax to re-solidify, causing high-pressure oil to flow through a hydraulic generator, thus creating electricity to charge a battery that powers the vehicle. In this modification, a similar thermal PCM device has been created that is heated and cooled by the air and solar radiation instead of using ocean temperature differences to change the PCM from solid to liquid. This innovation allows the device to use thermal energy to generate electricity on land, instead of just in the ocean.

  20. Molecular Origins of Thermal Transitions in Polyelectrolyte Assemblies

    Science.gov (United States)

    Yildirim, Erol; Zhang, Yanpu; Antila, Hanne S.; Lutkenhaus, Jodie L.; Sammalkorpi, Maria; Aalto Team; Texas A&M Team

    2015-03-01

    Polyelectrolyte (PE) multilayers and complexes formed from oppositely charged polymers can exhibit extraordinary superhydrophobicity, mechanical strength and responsiveness resulting in applications ranging functional membranes, optics, sensors and drug delivery. Depending on the assembly conditions, PE assemblies may undergo a thermal transition from glassy to soft behavior under heating. Our earlier work using thermal analysis measurements shows a distinct thermal transition for PE layer-by-layer (LbL) systems assembled with added salt but no analogous transition in films assembled without added salt or dry systems. These findings raise interesting questions on the nature of the thermal transition; here, we explore its molecular origins through characterization of the PE aggregates by temperature-controlled all-atom molecular dynamics simulations. We show via molecular simulations the thermal transition results from the existence of an LCST (lower critical solution temperature) in the PE systems: the diffusion behavior, hydrogen bond formation, and bridging capacity of water molecules plasticizing the complex changes at the transition temperature. We quantify the behavior, map its chemistry specificity through comparison of strongly and weakly charged PE complexes, and connect the findings to our interrelated QCM-D experiments.

  1. Influence of dimensionality on phase transition in VO2 nanocrystals

    Directory of Open Access Journals (Sweden)

    Blagojević V.A.

    2013-01-01

    Full Text Available Hydrothermally synthesized one-dimensional and two-dimensional nanocrystals of VO2 undergo phase transition around 65°C, where temperature and mechanism of phase transition are dependent on dimensionality of nanocrystals. Both nanocrystalline samples exhibit depression of phase transition temperature compared to the bulk material, the magnitude of which depends on the dimensionality of the nanocrystal. One-dimensional nanoribbons exhibit lower phase transition temperature and higher values of apparent activation energy than two-dimensional nanosheets. The phase transition exhibits as a complex process with somewhat lower value of enthalpy than the phase transition in the bulk, probably due to higher proportion of surface atoms in the nanocrystals. High values of apparent activation energy indicate that individual steps of the phase transition involve simultaneous movement of large groups of atoms, as expected for single-domain nanocrystalline materials. [Projekat Ministarstva nauke Republike Srbije, br. 142015

  2. Glass transition and thermal expansivity of polystyrene thin films

    International Nuclear Information System (INIS)

    Inoue, R.; Kanaya, T.; Miyazaki, T.; Nishida, K.; Tsukushi, I.; Shibata, K.

    2006-01-01

    We have studied glass transition temperature and thermal expansivity of polystyrene thin films supported on silicon substrate using X-ray reflectivity and inelastic neutron scattering techniques. In annealing experiments, we have found that the reported apparent negative expansivity of polymer thin films is caused by unrelaxed structure due to insufficient annealing. Using well-annealed films, we have evaluated glass transition temperature T g and thermal expansivity as a function of film thickness. The glass transition temperature decreases with film thickness and is constant below about 10 nm, suggesting the surface glass transition temperature of 355 K, which is lower than that in bulk. We have also found that the thermal expansivity in the glassy state decreases with film thickness even after annealing. The decrease has been attributed to hardening of harmonic force constant arising from chain confinement in a thin film. This idea has been confirmed in the inelastic neutron scattering measurements

  3. Glass transition and thermal expansivity of polystyrene thin films

    Energy Technology Data Exchange (ETDEWEB)

    Inoue, R. [Institute for Chemical Research, Kyoto University, Uji, Kyoto-fu 611-0011 (Japan); Kanaya, T. [Institute for Chemical Research, Kyoto University, Uji, Kyoto-fu 611-0011 (Japan)]. E-mail: kanaya@scl.kyoto-u.ac.jp; Miyazaki, T. [Nitto Denko Corporation, 1-1-2 Shimohozumi, Ibaraki, Osaka-fu 567-8680 (Japan); Nishida, K. [Institute for Chemical Research, Kyoto University, Uji, Kyoto-fu 611-0011 (Japan); Tsukushi, I. [Chiba Institute of Technology, Narashino, Chiba-ken 275-0023 (Japan); Shibata, K. [Japan Atomic Energy Research Institute, Tokai, Ibaraki-ken 319-1195 (Japan)

    2006-12-20

    We have studied glass transition temperature and thermal expansivity of polystyrene thin films supported on silicon substrate using X-ray reflectivity and inelastic neutron scattering techniques. In annealing experiments, we have found that the reported apparent negative expansivity of polymer thin films is caused by unrelaxed structure due to insufficient annealing. Using well-annealed films, we have evaluated glass transition temperature T {sub g} and thermal expansivity as a function of film thickness. The glass transition temperature decreases with film thickness and is constant below about 10 nm, suggesting the surface glass transition temperature of 355 K, which is lower than that in bulk. We have also found that the thermal expansivity in the glassy state decreases with film thickness even after annealing. The decrease has been attributed to hardening of harmonic force constant arising from chain confinement in a thin film. This idea has been confirmed in the inelastic neutron scattering measurements.

  4. Phase transitions and doping in semiconductor nanocrystals

    Science.gov (United States)

    Sahu, Ayaskanta

    impurities (or doping) allows further control over the electrical and optical properties of nanocrystals. However, while impurity doping in bulk semiconductors is now routine, doping of nanocrystals remains challenging. In particular, evidence for electronic doping, in which additional electrical carriers are introduced into the nanocrystals, has been very limited. Here, we adopt a new approach to electronic doping of nanocrystals. We utilize a partial cation exchange to introduce silver impurities into cadmium selenide (CdSe) and lead selenide (PbSe) nanocrystals. Results indicate that the silver-doped CdSe nanocrystals show a significant increase in fluorescence intensity, as compared to pure CdSe nanocrystals. We also observe a switching from n- to p-type doping in the silver-doped CdSe nanocrystals with increased silver amounts. Moreover, the silver-doping results in a change in the conductance of both PbSe and CdSe nanocrystals and the magnitude of this change depends on the amount of silver incorporated into the nanocrystals. In the bulk, silver chalcogenides (Ag2E, E=S, Se, and Te) possess a wide array of intriguing properties, including superionic conductivity. In addition, they undergo a reversible temperature-dependent phase transition which induces significant changes in their electronic and ionic properties. While most of these properties have been examined extensively in bulk, very few studies have been conducted at the nanoscale. We have recently developed a versatile synthesis that yields colloidal silver chalcogenide nanocrystals. Here, we study the size dependence of their phase-transition temperatures. We utilize differential scanning calorimetry and in-situ X-ray diffraction analyses to observe the phase transition in nanocrystal assemblies. We observe a significant deviation from the bulk alpha (low-temperature) to beta (high-temperature) phase-transition temperature when we reduce their size to a few nanometers. Hence, these nanocrystals provide great

  5. Phase transitions of natural corals monitored by ESR spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Vongsavat, V. [Department of Chemistry, Faculty of Science, Mahidol University, Rama VI Road, Rajathevi, Bangkok 10400 (Thailand); Winotai, P. [Department of Chemistry, Faculty of Science, Mahidol University, Rama VI Road, Rajathevi, Bangkok 10400 (Thailand); Meejoo, S. [Department of Chemistry, Faculty of Science, Mahidol University, Rama VI Road, Rajathevi, Bangkok 10400 (Thailand)]. E-mail: scsmj@mahidol.ac.th

    2006-01-15

    The main purpose of this work is to present a systematic study of structure of marine exoskeletons, Acropora coral and its structural transformation upon heat treatments. The coralline sample was ground and characterized as powder throughout this work. Structural identifications of all samples have been confirmed using X-ray diffraction and IR spectroscopy. It was clearly found that the fresh specimen is made of aragonite, a common phase of the mineral CaCO{sub 3}. Thermal analyses, DSC and TGA were used to monitor structural and thermal decompositions and an irreversible solid-state phase transition from aragonite to calcite of the marine carbonate. Next, the coral powder was annealed at specific temperatures over the range 350-900 deg. C, and the effects of heat treatment on the structure of coralline samples were carefully studied by Rietveld refinement method. In addition, we have examined Mn{sup 2+} paramagnetic ions and free radicals present in the coral and changes of those upon heating by using ESR spectroscopy. The local environments of Mn{sup 2+} ions were verified from the calculated ESR spectra using appropriate spin Hamiltonian parameters, i.e. gyromagnetic tensor g , zero-field splitting D and hyperfine tensor A . This work reported structures and compositions as well as physical, chemical and thermal properties of the coralline material upon heat treatments qualitatively and quantitatively.

  6. Phase transition and gravitational wave phenomenology of scalar conformal extensions of the Standard Model

    Energy Technology Data Exchange (ETDEWEB)

    Marzola, Luca; Racioppi, Antonio; Vaskonen, Ville [National Institute of Chemical Physics and Biophysics, Tallinn (Estonia)

    2017-07-15

    Thermal corrections in classically conformal models typically induce a strong first-order electroweak phase transition, thereby resulting in a stochastic gravitational background that could be detectable at gravitational wave observatories. After reviewing the basics of classically conformal scenarios, in this paper we investigate the phase transition dynamics in a thermal environment and the related gravitational wave phenomenology within the framework of scalar conformal extensions of the Standard Model. We find that minimal extensions involving only one additional scalar field struggle to reproduce the correct phase transition dynamics once thermal corrections are accounted for. Next-to-minimal models, instead, yield the desired electroweak symmetry breaking and typically result in a very strong gravitational wave signal. (orig.)

  7. Dynamic Phase Transitions In The Spin-2 Ising System Under An Oscillating Magnetic Field Within The Effective-Field Theory

    International Nuclear Information System (INIS)

    Ertas, Mehmet; Keskin, Mustafa; Deviren, Bayram

    2010-01-01

    The dynamic phase transitions are studied in the spin-2 Ising model under a time-dependent oscillating magnetic field by using the effective-field theory with correlations. The effective-field dynamic equation is derived by employing the Glauber transition rates and the phases in the system are obtained by solving this dynamic equation. The nature (first- or second-order) of the dynamic phase transition is characterized by investigating the thermal behavior of the dynamic order parameter and the dynamic phase transition temperatures are obtained. The dynamic phase diagrams are presented in (T/zJ, h/zJ) plane.

  8. Thermal characteristics of shape-stabilized phase change material wallboard with periodical outside temperature waves

    International Nuclear Information System (INIS)

    Zhou, Guobing; Yang, Yongping; Wang, Xin; Cheng, Jinming

    2010-01-01

    Thermal characteristics of shape-stabilized phase change material (SSPCM) wallboard with sinusoidal temperature wave on the outer surface were investigated numerically and compared with traditional building materials such as brick, foam concrete and expanded polystyrene (EPS). One-dimensional enthalpy equation under convective boundary conditions was solved using fully implicit finite-difference scheme. The simulation results showed that the SSPCM wallboard presents distinct characteristics from other ordinary building materials. Phase transition keeping time of inner surface and decrement factor were applied to analyze the effects of PCM thermophysical properties (melting temperature, heat of fusion, phase transition zone and thermal conductivity), inner surface convective heat transfer coefficient and thickness of SSPCM wallboard. It was found that melting temperature is one important factor which influences both the phase transition keeping time and the decrement factor; for a certain outside temperature wave, there exist critical values of latent heat of fusion and thickness of SSPCM above which the phase transition keeping time or the decrement factor are scarcely influenced; thermal conductivity of PCM and inner surface convective coefficient have little effect on the phase transition keeping time but significantly influence the decrement factor; and the phase transition zone leads to small fluctuations of the original flat segment of inner surface temperature line. The results aim to be useful for the selection of SSPCMs and their applications in passive solar buildings.

  9. Thermal duality and Hagedorn transition from p-adic strings.

    Science.gov (United States)

    Biswas, Tirthabir; Cembranos, Jose A R; Kapusta, Joseph I

    2010-01-15

    We develop the finite temperature theory of p-adic string models. We find that the thermal properties of these nonlocal field theories can be interpreted either as contributions of standard thermal modes with energies proportional to the temperature, or inverse thermal modes with energies proportional to the inverse of the temperature, leading to a thermal duality at leading order (genus one) analogous to the well-known T duality of string theory. The p-adic strings also recover the asymptotic limits (high and low temperature) for arbitrary genus that purely stringy calculations have yielded. We also discuss our findings surrounding the nature of the Hagedorn transition.

  10. Theoretical potential for low energy consumption phase change memory utilizing electrostatically-induced structural phase transitions in 2D materials

    Science.gov (United States)

    Rehn, Daniel A.; Li, Yao; Pop, Eric; Reed, Evan J.

    2018-01-01

    Structural phase-change materials are of great importance for applications in information storage devices. Thermally driven structural phase transitions are employed in phase-change memory to achieve lower programming voltages and potentially lower energy consumption than mainstream nonvolatile memory technologies. However, the waste heat generated by such thermal mechanisms is often not optimized, and could present a limiting factor to widespread use. The potential for electrostatically driven structural phase transitions has recently been predicted and subsequently reported in some two-dimensional materials, providing an athermal mechanism to dynamically control properties of these materials in a nonvolatile fashion while achieving potentially lower energy consumption. In this work, we employ DFT-based calculations to make theoretical comparisons of the energy required to drive electrostatically-induced and thermally-induced phase transitions. Determining theoretical limits in monolayer MoTe2 and thin films of Ge2Sb2Te5, we find that the energy consumption per unit volume of the electrostatically driven phase transition in monolayer MoTe2 at room temperature is 9% of the adiabatic lower limit of the thermally driven phase transition in Ge2Sb2Te5. Furthermore, experimentally reported phase change energy consumption of Ge2Sb2Te5 is 100-10,000 times larger than the adiabatic lower limit due to waste heat flow out of the material, leaving the possibility for energy consumption in monolayer MoTe2-based devices to be orders of magnitude smaller than Ge2Sb2Te5-based devices.

  11. QCD PHASE TRANSITIONS-VOLUME 15.

    Energy Technology Data Exchange (ETDEWEB)

    SCHAFER,T.

    1998-11-04

    The title of the workshop, ''The QCD Phase Transitions'', in fact happened to be too narrow for its real contents. It would be more accurate to say that it was devoted to different phases of QCD and QCD-related gauge theories, with strong emphasis on discussion of the underlying non-perturbative mechanisms which manifest themselves as all those phases. Before we go to specifics, let us emphasize one important aspect of the present status of non-perturbative Quantum Field Theory in general. It remains true that its studies do not get attention proportional to the intellectual challenge they deserve, and that the theorists working on it remain very fragmented. The efforts to create Theory of Everything including Quantum Gravity have attracted the lion share of attention and young talent. Nevertheless, in the last few years there was also a tremendous progress and even some shift of attention toward emphasis on the unity of non-perturbative phenomena. For example, we have seen some. efforts to connect the lessons from recent progress in Supersymmetric theories with that in QCD, as derived from phenomenology and lattice. Another example is Maldacena conjecture and related development, which connect three things together, string theory, super-gravity and the (N=4) supersymmetric gauge theory. Although the progress mentioned is remarkable by itself, if we would listen to each other more we may have chance to strengthen the field and reach better understanding of the spectacular non-perturbative physics.

  12. Phase transitions in Ge-Sb phase change materials

    International Nuclear Information System (INIS)

    Raoux, Simone; Virwani, Kumar; Cabral, Cyril Jr.; Krusin-Elbaum, Lia; Jordan-Sweet, Jean L.; Hitzbleck, Martina; Salinga, Martin; Madan, Anita; Pinto, Teresa L.

    2009-01-01

    Thin films of the phase change material Ge-Sb with Ge concentrations between 7.3 and 81.1 at. % were deposited by cosputtering from elemental targets. Their crystallization behavior was studied using time-resolved x-ray diffraction, Auger electron spectroscopy, differential scanning calorimetry, x-ray reflectivity, profilometry, optical reflectivity, and resistivity versus temperature measurements. It was found that the crystallization temperature increases with Ge content. Calculations of the glass transition temperature (which is a lower limit for the crystallization temperature T x ) also show an increase with Ge concentration closely tracking the measured values of T x . For low Ge content samples, Sb x-ray diffraction peaks occurred during a heating ramp at lower temperature than Ge diffraction peaks. The appearance of Ge peaks is related to Ge precipitation and agglomeration. For Ge concentrations of 59.3 at. % and higher, Sb and Ge peaks occurred at the same temperature. Upon crystallization, film mass density and optical reflectivity increase as well as electrical contrast (ratio of resistivity in amorphous phase to crystalline phase) all showed a maximum for the eutectic alloy (14.5 at. % Ge). For the alloy with 59.3 at. % Ge there was very little change in any of these parameters, while the alloy with 81.1 at. % Ge behaved opposite to a typical phase change alloy and showed reduced mass density and reflectivity and increased resistivity

  13. Wilson loop's phase transition probed by non-local observable

    Directory of Open Access Journals (Sweden)

    Hui-Ling Li

    2018-04-01

    Full Text Available In order to give further insights into the holographic Van der Waals phase transition, it would be of great interest to investigate the behavior of Wilson loop across the holographic phase transition for a higher dimensional hairy black hole. We offer a possibility to proceed with a numerical calculation in order to discussion on the hairy black hole's phase transition, and show that Wilson loop can serve as a probe to detect a phase structure of the black hole. Furthermore, for a first order phase transition, we calculate numerically the Maxwell's equal area construction; and for a second order phase transition, we also study the critical exponent in order to characterize the Wilson loop's phase transition.

  14. Chiral phase transitions in quantum chromodynamics at finite ...

    Indian Academy of Sciences (India)

    DS equation, showing the importance of properly taking into account the essential thermal effects, namely the Landau damping and the unstable nature of thermal quasiparticles. Keywords. Chiral transition; finite temperature; quantum chromodynamics; Dyson–Schwinger equation; hard thermal loops; real time formalism.

  15. Observables of non-equilibrium phase transition

    Energy Technology Data Exchange (ETDEWEB)

    Tomasik, Boris [Univerzita Mateja Bela, FPV, Banska Bystrica (Slovakia); Ceske vysoke uceni technicke v Praze, FJFI, Prague (Czech Republic); Schulc, Martin; Kopecna, Renata [Ceske vysoke uceni technicke v Praze, FJFI, Prague (Czech Republic); Melo, Ivan [Univerzita Mateja Bela, FPV, Banska Bystrica (Slovakia); Zilinska univerzita, Elektrotechnicka fakulta, Zilina (Slovakia)

    2016-08-15

    A rapidly expanding fireball which undergoes first-order phase transition will supercool and proceed via spinodal decomposition. Hadrons are produced from the individual fragments as well as the left-over matter filling the space between them. Emission from fragments should be visible in rapidity correlations, particularly of protons. In addition to that, even within narrow centrality classes, rapidity distributions will be fluctuating from one event to another in case of fragmentation. This can be identified with the help of the Kolmogorov-Smirnov test. Finally, we present a method which allows to sort events with varying rapidity distributions, in such a way that events with similar rapidity histograms are grouped together. (orig.)

  16. Deep Neural Network Detects Quantum Phase Transition

    Science.gov (United States)

    Arai, Shunta; Ohzeki, Masayuki; Tanaka, Kazuyuki

    2018-03-01

    We detect the quantum phase transition of a quantum many-body system by mapping the observed results of the quantum state onto a neural network. In the present study, we utilized the simplest case of a quantum many-body system, namely a one-dimensional chain of Ising spins with the transverse Ising model. We prepared several spin configurations, which were obtained using repeated observations of the model for a particular strength of the transverse field, as input data for the neural network. Although the proposed method can be employed using experimental observations of quantum many-body systems, we tested our technique with spin configurations generated by a quantum Monte Carlo simulation without initial relaxation. The neural network successfully identified the strength of transverse field only from the spin configurations, leading to consistent estimations of the critical point of our model Γc = J.

  17. Kinetics of the chiral phase transition

    Energy Technology Data Exchange (ETDEWEB)

    Hees, Hendrik van [Johann-Wolfgang-Goethe-Universitaet Frankfurt, Institut fuer Theoretische Physik, Frankfurt (Germany); Frankfurt Institute for Advanced Studies (FIAS), Frankfurt (Germany); Wesp, Christian; Meistrenko, Alex; Greiner, Carsten [Johann-Wolfgang-Goethe-Universitaet Frankfurt, Institut fuer Theoretische Physik, Frankfurt (Germany)

    2016-07-01

    We simulate the kinetics of the chiral phase transition in hot and dense strongly interacting matter within a novel kinetic-theory approach. Employing an effective linear σ model for quarks, σ mesons, and pions we treat the quarks within a test-particle ansatz for solving the Boltzmann transport equation and the mesons in terms of classical fields. The decay-recombination processes like σ <-> anti q+q are treated using a kind of wave-particle dualism using the exact conservation of energy and momentum. After demonstrating the correct thermodynamic limit for particles and fields in a ''box calculation'' we apply the simulation to the dynamics of an expanding fireball similar to the medium created in ultrarelativistic heavy-ion collisions.

  18. Roles of strain and domain boundaries on the phase transition stability of VO2 thin films

    Science.gov (United States)

    Jian, Jie; Chen, Aiping; Chen, Youxing; Zhang, Xinghang; Wang, Haiyan

    2017-10-01

    The fundamental phase transition mechanism and the stability of the semiconductor-to-metal phase transition properties during multiple thermal cycles have been investigated on epitaxial vanadium dioxide (VO2) thin films via both ex situ heating and in situ heating by transmission electron microscopy (TEM). VO2 thin films were deposited on c-cut sapphire substrates by pulsed laser deposition. Ex situ studies show the broadening of transition sharpness (ΔT) and the width of thermal hysteresis (ΔH) after 60 cycles. In situ TEM heating studies reveal that during thermal cycles, large strain was accumulated around the domain boundaries, which was correlated with the phase transition induced lattice constant change and the thermal expansion. It suggests that the degradation of domain boundary structures in the VO2 films not only caused the transition property reduction (e.g., the decrease in ΔT and ΔH) but also played an important role in preventing the film from fracture during thermal cycles.

  19. Quantum phase transitions in Bose-Fermi systems

    International Nuclear Information System (INIS)

    Petrellis, D.; Leviatan, A.; Iachello, F.

    2011-01-01

    Research highlights: → We study quantum phase transitions in a system of N bosons and a single-j fermion. → Classical order parameters and correlation diagrams of quantum levels are determined. → The odd fermion strongly influences the location and nature of the phase transition. → Experimental evidence for the U(5)-SU(3) transition in odd-even nuclei is presented. - Abstract: Quantum phase transitions in a system of N bosons with angular momentum L = 0, 2 (s, d) and a single fermion with angular momentum j are investigated both classically and quantum mechanically. It is shown that the presence of the odd fermion strongly influences the location and nature of the phase transition, especially the critical value of the control parameter at which the phase transition occurs. Experimental evidence for the U(5)-SU(3) (spherical to axially-deformed) transition in odd-even nuclei is presented.

  20. Magnetically ordered phase near transition to Bose-glass phase

    Science.gov (United States)

    Syromyatnikov, A. V.; Sizanov, A. V.

    2017-01-01

    We discuss a magnetically ordered ("superfluid") phase near quantum transition to the Bose-glass phase in a simple modeling system, a Heisenberg antiferromagnet with spatial dimension d >2 in an external magnetic field with disorder in exchange coupling constants. Our analytical consideration is based on hydrodynamic description of long-wavelength excitations. Results obtained are valid in the entire critical region near the quantum critical point (QCP), allowing us to describe a possible crossover from one critical behavior to another. We demonstrate that the system behaves in full agreement with predictions by M. P. Fisher et al. [Phys. Rev. B 40, 546 (1989), 10.1103/PhysRevB.40.546] in close vicinity to the QCP. We find as an extension to that analysis that the anomalous dimension η =2 -d and β =ν d /2 , where β and ν are critical exponents of the order parameter and the correlation length, respectively. The density of states per spin of low-energy localized excitations is found to be independent of d ("superuniversal"). We show that many recent experimental and numerical results obtained in various three-dimensional (3D) systems can be described by our formulas using percolation critical exponents. Then, it is a possibility that a percolation critical regime arises in the ordered phase in some 3D systems not very close to the QCP.

  1. Multiple phase transitions in palmitoleic acid under the pressure

    Energy Technology Data Exchange (ETDEWEB)

    Kos, A; Siegoczynski, R M; Rostocki, A J; Tefelski, D B; Kosciesza, R; Wieja, K [Faculty of Physics, Warsaw University of Technology, Koszykowa 75, 00-662 Warsaw (Poland)], E-mail: aldona@if.pw.edu.pl

    2008-07-15

    Long unsaturated carbon chain liquids exhibit a phase transition under a high pressure. We have investigated the phase transition in palmitoleic acid as a representative of this group not researched yet. A temperature, a relative permittivity and a dissipation factor have been measured, while the pressure was applied. We have also observed the transmitted and the scattered IR light. These parameters allowed us to find phase transitions that occurred due to the pressure. Especially the behavior of the temperature indicates several phase transitions during compression. Above certain pressure the liquid becomes opaque, it is connected with most significant phase transition that occurs around 177 MPa. We have observed asymmetry of intensity of the scattered light, which is much stronger during decompression. Observed multiple phase transitions are not present in other acids investigated by us.

  2. Characteristics of the chiral phase transition in nonlocal quark models

    International Nuclear Information System (INIS)

    Gomez Dumm, D. Gomez; Scoccola, N.N.

    2005-01-01

    The characteristics of the chiral phase transition are analyzed within the framework of chiral quark models with nonlocal interactions in the mean-field approximation. In the chiral limit, we develop a semianalytic framework that allows us to explicitly determine the phase transition curve, the position of the critical points, some relevant critical exponents, etc. For the case of finite current quark masses, we show the behavior of various thermodynamical and chiral response functions across the phase transition

  3. Gravitational waves from global second order phase transitions

    Energy Technology Data Exchange (ETDEWEB)

    Jr, John T. Giblin [Department of Physics, Kenyon College, 201 North College Rd, Gambier, OH 43022 (United States); Price, Larry R.; Siemens, Xavier; Vlcek, Brian, E-mail: giblinj@kenyon.edu, E-mail: larryp@caltech.edu, E-mail: siemens@gravity.phys.uwm.edu, E-mail: bvlcek@uwm.edu [Center for Gravitation and Cosmology, Department of Physics, University of Wisconsin-Milwaukee, P.O. Box 413, Milwaukee, WI 53201 (United States)

    2012-11-01

    Global second-order phase transitions are expected to produce scale-invariant gravitational wave spectra. In this manuscript we explore the dynamics of a symmetry-breaking phase transition using lattice simulations. We explicitly calculate the stochastic gravitational wave background produced during the transition and subsequent self-ordering phase. We comment on this signal as it compares to the scale-invariant spectrum produced during inflation.

  4. The phase transition of RDX under hydrostatic and ramp compression

    Science.gov (United States)

    Zheng, Xianxu; Zhang, Zhaohui; Zhao, Jun; Zeng, Daipeng; Zeng, Yangyang; Zhang, Xu

    2017-06-01

    The thermodynamic state of explosive was highly dependent on the phase transition structure and phase transition of explosive crystal. However, the phase transition details of explosive have never been characterized sufficiently under different compression conditions. In this study, both the hydrostatic and ramp compression were performed to examine the phase transition of RDX crystal. Based on our experimental results, we confirmed the α- γ phase transition onset around 4 GPa under hydrostatic compression, which agree with the published literature very well. In the ramp compression experiment, a 260 ns ramp compression up to 30 GPa was generated to compress the RDX single crystal along 020 crystal axis, the PDV signal indicated that the phase transition was induced around 2.8 GPa, and the phase transition induction time was about several tens nanoseconds. Our preliminary experiments suggest that the phase transition pressure of RDX have great relation with the compression history, that probably means the phase transition mechanism were quite different between the hydrostatic and ramp compression.

  5. Does zero temperature decide on the nature of the electroweak phase transition?

    International Nuclear Information System (INIS)

    Harman, Christopher P.D.; Huber, Stephan J.

    2016-01-01

    Taking on a new perspective of the electroweak phase transition, we investigate in detail the role played by the depth of the electroweak minimum (“vacuum energy difference”). We find a strong correlation between the vacuum energy difference and the strength of the phase transition. This correlation only breaks down if a negative eigenvalue develops upon thermal corrections in the squared scalar mass matrix in the broken vacuum before the critical temperature. As a result the scalar fields slide across field space toward the symmetric vacuum, often causing a significantly weakened phase transition. Phenomenological constraints are found to strongly disfavour such sliding scalar scenarios. For several popular models, we suggest numerical bounds that guarantee a strong first order electroweak phase transition. The zero temperature phenomenology can then be studied in these parameter regions without the need for any finite temperature calculations. For almost all non-supersymmetric models with phenomenologically viable parameter points, we find a strong phase transition is guaranteed if the vacuum energy difference is greater than −8.8×10 7 GeV 4 . For the GNMSSM, we guarantee a strong phase transition for phenomenologically viable parameter points if the vacuum energy difference is greater than −6.9×10 7 GeV 4 . Alternatively, we capture more of the parameter space exhibiting a strong phase transition if we impose a simultaneous bound on the vacuum energy difference and the singlet mass.

  6. Pressure induced phase transitions in ceramic compounds containing tetragonal zirconia

    Energy Technology Data Exchange (ETDEWEB)

    Sparks, R.G.; Pfeiffer, G.; Paesler, M.A.

    1988-12-01

    Stabilized tetragonal zirconia compounds exhibit a transformation toughening process in which stress applied to the material induces a crystallographic phase transition. The phase transition is accompanied by a volume expansion in the stressed region thereby dissipating stress and increasing the fracture strength of the material. The hydrostatic component of the stress required to induce the phase transition can be investigated by the use of a high pressure technique in combination with Micro-Raman spectroscopy. The intensity of Raman lines characteristic for the crystallographic phases can be used to calculate the amount of material that has undergone the transition as a function of pressure. It was found that pressures on the order of 2-5 kBar were sufficient to produce an almost complete transition from the original tetragonal to the less dense monoclinic phase; while a further increase in pressure caused a gradual reversal of the transition back to the original tetragonal structure.

  7. Highly birefringent crystal for Raman transitions with phase modulators

    Science.gov (United States)

    Arias, Nieves; Abediyeh, Vahide; Hamzeloui, Saeed; Jeronimo-Moreno, Yasser; Gomez, Eduardo

    2016-05-01

    We present a system to excite Raman transitions with minimum phase noise. The system uses a phase modulator to generate the phase locked beams required for the transition. We use a long calcite crystal to filter out one of the sidebands, avoiding the cancellation that appears at high detunings for phase modulation. The measured phase noise is limited by the quality of the microwave synthesizer. We use the calcite crystal a second time to produce a co-propagating Raman pair with perpendicular polarizations to drive velocity insensitive Raman transitions. Support from CONACYT and Fundacion Marcos Moshinsky.

  8. Phase transitions in a gas of anyons

    International Nuclear Information System (INIS)

    MacKenzie, R.; Nebia-Rahal, F.; Paranjape, M. B.; Richer, J.

    2010-01-01

    We continue our numerical Monte Carlo simulation of a gas of closed loops on a 3 dimensional lattice, however, now in the presence of a topological term added to the action which corresponds to the total linking number between the loops. We compute the linking number using a novel approach employing certain notions from knot theory. Adding the topological term converts the particles into anyons. Interpreting the model as an effective theory that describes the 2+1-dimensional Abelian Higgs model in the asymptotic strong-coupling regime, the topological linking number simply corresponds to the addition to the action of the Chern-Simons term. The system continues to exhibit a phase transition as a function of the vortex mass as it becomes small. We find the following new results. The Chern-Simons term has no effect on the Wilson loop. On the other hand, it does effect the 't Hooft loop of a given configuration, adding the linking number of the 't Hooft loop with all of the dynamical vortex loops. We find the unexpected result that both the Wilson loop and the 't Hooft loop exhibit a perimeter law even though there are no massless particles in the theory, in both phases of the theory. It should be noted that our method suffers from numerical instabilities if the coefficient of the Chern-Simons term is too large; thus, we have restricted our results to small values of this parameter. Furthermore, interpreting the lattice loop gas as an effective theory describing the Abelian Higgs model is only known to be true in the infinite coupling limit; for strong but finite coupling this correspondence is only a conjecture, the validity of which is beyond the scope of this article.

  9. Unconventional phase transitions in a constrained single polymer chain

    International Nuclear Information System (INIS)

    Klushin, L I; Skvortsov, A M

    2011-01-01

    Phase transitions were recognized among the most fascinating phenomena in physics. Exactly solved models are especially important in the theory of phase transitions. A number of exactly solved models of phase transitions in a single polymer chain are discussed in this review. These are three models demonstrating the second order phase transitions with some unusual features: two-dimensional model of β-structure formation, the model of coil–globule transition and adsorption of a polymer chain grafted on the solid surface. We also discuss models with first order phase transitions in a single macromolecule which admit not only exact analytical solutions for the partition function with explicit finite-size effects but also the non-equilibrium free energy as a function of the order parameter (Landau function) in closed analytical form. One of them is a model of mechanical desorption of a macromolecule, which demonstrates an unusual first order phase transition with phase coexistence within a single chain. Features of first and second order transitions become mixed here due to phase coexistence which is not accompanied by additional interfacial free energy. Apart from that, there exist several single-chain models belonging to the same class (adsorption of a polymer chain tethered near the solid surface or liquid–liquid interface, and escape transition upon compressing a polymer between small pistons) that represent examples of a highly unconventional first order phase transition with several inter-related unusual features: no simultaneous phase coexistence, and hence no phase boundary, non-concave thermodynamic potential and non-equivalence of conjugate ensembles. An analysis of complex zeros of partition functions upon approaching the thermodynamic limit is presented for models with and without phase coexistence. (topical review)

  10. Soft x-ray induced femtosecond solid-to-solid phase transition

    Czech Academy of Sciences Publication Activity Database

    Tavella, F.; Höppner, H.; Tkachenko, V.; Medvedev, Nikita; Capotondi, F.; Golz, T.; Kai, Y.; Manfredda, M.; Pedersoli, E.; Prandolini, M.J.; Stojanovic, N.; Tanikawa, T.; Teubner, U.; Toleikis, S.; Ziaja, B.

    2017-01-01

    Roč. 24, Sep (2017), s. 22-27 ISSN 1574-1818 Institutional support: RVO:68378271 Keywords : soft x-ray * ultrashort x-ray pulses * grafitization of diamond * non-thermal phase transition Subject RIV: BL - Plasma and Gas Discharge Physics OBOR OECD: Fluids and plasma physics (including surface physics) Impact factor: 0.908, year: 2016

  11. Spin-Hall effect and emergent antiferromagnetic phase transition in n-Si

    Science.gov (United States)

    Lou, Paul C.; Kumar, Sandeep

    2018-04-01

    Spin current experiences minimal dephasing and scattering in Si due to small spin-orbit coupling and spin-lattice interactions is the primary source of spin relaxation. We hypothesize that if the specimen dimension is of the same order as the spin diffusion length then spin polarization will lead to non-equilibrium spin accumulation and emergent phase transition. In n-Si, spin diffusion length has been reported up to 6 μm. The spin accumulation in Si will modify the thermal transport behavior of Si, which can be detected with thermal characterization. In this study, we report observation of spin-Hall effect and emergent antiferromagnetic phase transition behavior using magneto-electro-thermal transport characterization. The freestanding Pd (1 nm)/Ni80Fe20 (75 nm)/MgO (1 nm)/n-Si (2 μm) thin film specimen exhibits a magnetic field dependent thermal transport and spin-Hall magnetoresistance behavior attributed to Rashba effect. An emergent phase transition is discovered using self-heating 3ω method, which shows a diverging behavior at 270 K as a function of temperature similar to a second order phase transition. We propose that spin-Hall effect leads to the spin accumulation and resulting emergent antiferromagnetic phase transition. We propose that the length scale for Rashba effect can be equal to the spin diffusion length and two-dimensional electron gas is not essential for it. The emergent antiferromagnetic phase transition is attributed to the site inversion asymmetry in diamond cubic Si lattice.

  12. Phase transition in L-alaninium oxalate by photoacoustics

    Indian Academy of Sciences (India)

    Unknown

    TG and DTA mea- surements were first carried out to identify any transitions. The calorimetric techniques such as DSC, TG and DTA are generally used to study the phase transition. But,. Ganguly and Rao (1981) reported from their PA study on. La2CuO4 that there would be a weak transition at 553 K but they could not see ...

  13. Thermal lens and interferometric method for glass transition and thermo physical properties measurements in Nd2O3 doped sodium zincborate glass.

    Science.gov (United States)

    Astrath, N G C; Steimacher, A; Rohling, J H; Medina, A N; Bento, A C; Baesso, M L; Jacinto, C; Catunda, T; Lima, S M; Karthikeyan, B

    2008-12-22

    In this work the time resolved thermal lens method is combined with interferometric technique, the thermal relaxation calorimetry, photoluminescence and lifetime measurements to determine the thermo physical properties of Nd(2)O(3) doped sodium zincborate glass as a function of temperature up to the glass transition region. Thermal diffusivity, thermal conductivity, fluorescence quantum efficiency, linear thermal expansion coefficient and thermal coefficient of electronic polarizability were determined. In conclusion, the results showed the ability of thermal lens and interferometric methods to perform measurements very close to the phase transition region. These techniques provide absolute values for the measured physical quantities and are advantageous when low scan rates are required.

  14. A grain boundary phase transition in Si–Au

    International Nuclear Information System (INIS)

    Ma, Shuailei; Meshinchi Asl, Kaveh; Tansarawiput, Chookiat; Cantwell, Patrick R.; Qi, Minghao; Harmer, Martin P.; Luo, Jian

    2012-01-01

    A grain boundary transition from a bilayer to an intrinsic (nominally clean) boundary is observed in Si–Au. An atomically abrupt transition between the two complexions (grain boundary stabilized phases) implies the occurrence of a first-order interfacial phase transition associated with a discontinuity in the interfacial excess. This observation supports a grain-boundary complexion theory with broad applications. This transition is atypical in that the monolayer complexion is absent. A model is proposed to explain the bilayer stabilization and the origin of this complexion transition.

  15. On the theory of phase transitions in polypeptides

    DEFF Research Database (Denmark)

    Yakubovich, Alexander V.; Solov'yov, Ilia; Solov'yov, Andrey V.

    2008-01-01

    We suggest a theoretical method based on the statistical mechanics for treating the alpha-helix random coil transition in polypeptides. This process is considered as a first-order-like phase transition. The developed theory is free of model parameters and is based solely on fundamental physical...... principles. We apply the developed formalism for the description of thermodynamical properties of alanine polypeptides of different length. We analyze the essential thermodynamical properties of the system such as heat capacity, phase transition temperature and latent heat of the phase transition...

  16. Molecular simulation of the pressure-induced crystallographic phase transition of p-terphenyl.

    Science.gov (United States)

    Schatschneider, Bohdan; Chronister, Eric L

    2011-01-27

    The pressure- and temperature-induced polymorphic crystal phase transitions of p-terphenyl (PTP) have been modeled using a modified PCFF interaction force field. Modifications of the interaction potential were necessary to simultaneously model both the temperature-induced phase transition at ambient pressure and the pressure-induced phase transition at low temperature. Although the high-temperature and high-pressure phases are both characterized by flattening of the PTP molecule, the mechanisms of the temperature- and pressure-induced phase transitions are different. At high temperature thermal energy exceeds the torsional barrier, resulting in a bimodal phenyl ring twist angle distribution that averages to zero. In contrast, compression of PTP at high pressure results in a static planar structure. At high pressure the compression of the unit cell is also characterized by large compression of the a lattice parameter and weak compression of c, but some expansion of the b lattice parameter. The expansion of the b lattice parameter is likely associated with pressure-induced soft mode behavior of some lattice vibrations as well as soft mode behavior of pseudolocal phonons associated with impurities in PTP. The crystallographic angles α, β, and γ also indicate a triclinic crystal phase above the critical phase transition pressure of P(c) ~ 0.5 GPa at low temperature, suggesting a distinct phase separate from the monoclinic high-pressure phase at high temperature.

  17. Role of multistability in the transition to chaotic phase synchronization

    DEFF Research Database (Denmark)

    Postnov, D.E.; Vadivasova, T.E.; Sosnovtseva, Olga

    1999-01-01

    In this paper we describe the transition to phase synchronization for systems of coupled nonlinear oscillators that individually follow the Feigenbaum route to chaos. A nested structure of phase synchronized regions of different attractor families is observed. With this structure, the transition...... using Rössler systems and model maps are given. ©1999 American Institute of Physics....

  18. Local discontinuous Galerkin methods for phase transition problems

    NARCIS (Netherlands)

    Tian, Lulu

    2015-01-01

    In this thesis we develop a local discontinuous Galerkin (LDG) finite element method to solve mathematical models for phase transitions in solids and fluids. The first model we study is called a viscosity-capillarity (VC) system associated with phase transitions in elastic bars and Van der Waals

  19. Structural phase transitions and piezoelectric anomalies in ordered ...

    Indian Academy of Sciences (India)

    Home; Journals; Bulletin of Materials Science; Volume 30; Issue 4. Structural phase transitions and piezoelectric anomalies in ordered Sc0.5Ga0.5N alloys ... This alloy is found to exhibit a tremendous piezoelectric response, associated with a phase transition from nonpolar 63/(6h) space group to a polar ...

  20. Phase transitions in liquids with directed intermolecular bonding

    OpenAIRE

    Son, L.; Ryltcev, R.

    2005-01-01

    Liquids with quasi - chemical bonding between molecules are described in terms of vertex model. It is shown that this bonding results in liquid - liquid phase transition, which occurs between phases with different mean density of intermolecular bonds. The transition may be suggested to be a universal phenomena for those liquids.

  1. Supercooling across first-order phase transitions in vortex matter

    Indian Academy of Sciences (India)

    Hysteresis in cycling through first-order phase transitions in vortex matter, akin to the well-studied phenomenon of supercooling of water, has been discussed in literature. Hysteresis can be seen while varying either temperature or magnetic field (and thus the density of vortices). Our recent work on phase transitions with ...

  2. High-density QCD phase transitions inside neutron stars: Glitches ...

    Indian Academy of Sciences (India)

    2017-10-09

    Oct 9, 2017 ... ... of different high-density phases and associated phase transitions. We study effectsof density fluctuations during transitions with and without topological defect production and study the effect on pulsar timings due to changing moment of inertia of the star. We also discuss gravitational wave production due ...

  3. Electroweak phase transition and some related phenomena–a brief

    Indian Academy of Sciences (India)

    In this article, we give a bird's eye view of the research on electroweak phase transition and some related phenomena, viz., cosmological baryogenesis, electroweak bubble dynamics and generation of gravitationalwaves. Our presentation revolves around the observation that a strong first-order electroweak phase transition ...

  4. Model for pairing phase transition in atomic nuclei

    International Nuclear Information System (INIS)

    Schiller, A.; Guttormsen, M.; Hjorth-Jensen, M.; Rekstad, J.; Siem, S.

    2002-01-01

    A model is developed which allows the investigation and classification of the pairing phase transition in atomic nuclei. The regions of the parameter space are discussed for which a pairing phase transition can be observed. The model parameters include number of particles, attenuation of pairing correlations with increasing seniority, single-particle level spacing, and pairing gap parameter

  5. Thermalization calorimetry: A simple method for investigating glass transition and crystallization of supercooled liquids

    Directory of Open Access Journals (Sweden)

    Bo Jakobsen

    2016-05-01

    Full Text Available We present a simple method for fast and cheap thermal analysis on supercooled glass-forming liquids. This “Thermalization Calorimetry” technique is based on monitoring the temperature and its rate of change during heating or cooling of a sample for which the thermal power input comes from heat conduction through an insulating material, i.e., is proportional to the temperature difference between sample and surroundings. The monitored signal reflects the sample’s specific heat and is sensitive to exo- and endothermic processes. The technique is useful for studying supercooled liquids and their crystallization, e.g., for locating the glass transition and melting point(s, as well as for investigating the stability against crystallization and estimating the relative change in specific heat between the solid and liquid phases at the glass transition.

  6. Thermodynamic phase transition of a black hole in rainbow gravity

    Directory of Open Access Journals (Sweden)

    Zhong-Wen Feng

    2017-09-01

    Full Text Available In this letter, using the rainbow functions that were proposed by Magueijo and Smolin, we investigate the thermodynamics and the phase transition of rainbow Schwarzschild black hole. First, we calculate the rainbow gravity corrected Hawking temperature. From this modification, we then derive the local temperature, free energy, and other thermodynamic quantities in an isothermal cavity. Finally, we analyze the critical behavior, thermodynamic stability, and phase transition of the rainbow Schwarzschild black hole. The results show that the rainbow gravity can stop the Hawking radiation in the final stages of black holes' evolution and lead to the remnants of black holes. Furthermore, one can observe that the rainbow Schwarzschild black hole has one first-order phase transition, two second-order phase transitions, and three Hawking–Page-type phase transitions in the framework of rainbow gravity theory.

  7. Thermodynamic phase transition of a black hole in rainbow gravity

    Science.gov (United States)

    Feng, Zhong-Wen; Yang, Shu-Zheng

    2017-09-01

    In this letter, using the rainbow functions that were proposed by Magueijo and Smolin, we investigate the thermodynamics and the phase transition of rainbow Schwarzschild black hole. First, we calculate the rainbow gravity corrected Hawking temperature. From this modification, we then derive the local temperature, free energy, and other thermodynamic quantities in an isothermal cavity. Finally, we analyze the critical behavior, thermodynamic stability, and phase transition of the rainbow Schwarzschild black hole. The results show that the rainbow gravity can stop the Hawking radiation in the final stages of black holes' evolution and lead to the remnants of black holes. Furthermore, one can observe that the rainbow Schwarzschild black hole has one first-order phase transition, two second-order phase transitions, and three Hawking-Page-type phase transitions in the framework of rainbow gravity theory.

  8. Baryon inhomogeneity from the cosmic quark-hadron phase transition

    International Nuclear Information System (INIS)

    Kurki-Suonio, H.

    1991-01-01

    We discuss the generation of inhomogeneity in the baryon-number density during the cosmic quark-hadron phase transition. We use a simple model with thin-wall phase boundaries and ideal-gas equations of state. The nucleation of the phase transition introduces a new distance scale into the universe which will be the scale of the generated inhomogeneity. We review the estimate of this scale. During the transition baryon number is likely to collect onto a layer at the phase boundary. These layers may in the end be deposited as small regions of very high baryon density. 21 refs., 1 fig

  9. Activity induced phase transition in mixtures of active and passive agents

    Science.gov (United States)

    Sinha Mahapatra, Pallab; Kulkarni, Ajinkya

    2017-11-01

    Collective behaviors of self-propelling agents are ubiquitous in nature that produces interesting patterns. The objective of this study is to investigate the phase transition in mixtures of active and inert agents suspended in a liquid. A modified version of the Vicsek Model has been used (see Ref.), where the particles are modeled as soft disks with finite mass, confined in a square domain. The particles are required to align their local motion to their immediate neighborhood, similar to the Vicsek model. We identified the transition from disorganized thermal-like motion to an organized vortical motion. We analyzed the nature of the transition by using different order parameters. Furthermore the switching between the phases has been investigated via artificial nucleation of randomly picked active agents spanning the entire domain. Finally the motivation for this phase transition has been explained via average dissipation and the mean square displacement (MSD) of the agents.

  10. CO2 Capture from Flue Gas by Phase Transitional Absorption

    Energy Technology Data Exchange (ETDEWEB)

    Liang Hu

    2009-06-30

    A novel absorption process called Phase Transitional Absorption was invented. What is the Phase Transitional Absorption? Phase Transitional Absorption is a two or multi phase absorption system, CO{sub 2} rich phase and CO{sub 2} lean phase. During Absorption, CO{sub 2} is accumulated in CO{sub 2} rich phase. After separating the two phases, CO{sub 2} rich phase is forward to regeneration. After regeneration, the regenerated CO{sub 2} rich phase combines CO{sub 2} lean phase to form absorbent again to complete the cycle. The advantage for Phase Transitional Absorption is obvious, significantly saving on regeneration energy. Because CO{sub 2} lean phase was separated before regeneration, only CO{sub 2} rich phase was forward to regeneration. The absorption system we developed has the features of high absorption rate, high loading and working capacity, low corrosion, low regeneration heat, no toxic to environment, etc. The process evaluation shows that our process is able to save 80% energy cost by comparing with MEA process.

  11. Isospin and momentum dependence of liquid-gas phase transition in hot asymmetric nuclear matter

    International Nuclear Information System (INIS)

    Xu, Jun; Ma, Hongru; Chen, Liewen; Li, Baoan

    2008-01-01

    The liquid-gas phase transition in hot neutron-rich nuclear matter is investigated within a self-consistent thermal model using different interactions with or without isospin and/or momentum dependence. The boundary of the phase-coexistence region is shown to be sensitive to the density dependence of the nuclear symmetry energy as well as the isospin and momentum dependence of the nuclear interaction. (author)

  12. Quantum phase transitions in highly crystalline two-dimensional superconductors.

    Science.gov (United States)

    Saito, Yu; Nojima, Tsutomu; Iwasa, Yoshihiro

    2018-02-22

    Superconductor-insulator transition is one of the remarkable phenomena driven by quantum fluctuation in two-dimensional (2D) systems. Such a quantum phase transition (QPT) was investigated predominantly on highly disordered thin films with amorphous or granular structures using scaling law with constant exponents. Here, we provide a totally different view of QPT in highly crystalline 2D superconductors. According to the magneto-transport measurements in 2D superconducting ZrNCl and MoS 2 , we found that the quantum metallic state commonly observed at low magnetic fields is converted via the quantum Griffiths state to the weakly localized metal at high magnetic fields. The scaling behavior, characterized by the diverging dynamical critical exponent (Griffiths singularity), indicates that the quantum fluctuation manifests itself as superconducting puddles, in marked contrast to the thermal fluctuation. We suggest that an evolution from the quantum metallic to the quantum Griffiths state is generic nature in highly crystalline 2D superconductors with weak pinning potentials.

  13. Phase Transitions In M-Theory And F-Theory

    OpenAIRE

    Witten, Edward

    1996-01-01

    Phase transitions are studied in $M$-theory and $F$-theory. In $M$-theory compactification to five dimensions on a Calabi-Yau, there are topology-changing transitions similar to those seen in conformal field theory, but the non-geometrical phases known in conformal field theory are absent. At boundaries of moduli space where such phases might have been expected, the moduli space ends, by a conventional or unconventional physical mechanism. The unconventional mechanisms, which roughly involve ...

  14. Superionic phase transition in silver chalcogenide nanocrystals realizing optimized thermoelectric performance.

    Science.gov (United States)

    Xiao, Chong; Xu, Jie; Li, Kun; Feng, Jun; Yang, Jinlong; Xie, Yi

    2012-03-07

    Thermoelectric has long been recognized as a potentially transformative energy conversion technology due to its ability to convert heat directly into electricity. However, how to optimize the three interdependent thermoelectric parameters (i.e., electrical conductivity σ, Seebeck coefficient S, and thermal conductivity κ) for improving thermoelectric properties is still challenging. Here, we put forward for the first time the semiconductor-superionic conductor phase transition as a new and effective way to selectively optimize the thermoelectric power factor based on the modulation of the electric transport property across the phase transition. Ultra low value of thermal conductivity was successfully retained over the whole investigated temperature range through the reduction of grain size. As a result, taking monodisperse Ag(2)Se nanocrystals for an example, the maximized ZT value can be achieved around the temperature of phase transition. Furthermore, along with the effective scattering of short-wavelength phonons by atomic defects created by alloying, the alloyed ternary silver chalcogenide compounds, monodisperse Ag(4)SeS nanocrystals, show better ZT value around phase transition temperature, which is cooperatively contributed by superionic phase transition and alloying at nanoscale. © 2012 American Chemical Society

  15. The thickness dependence of the phase transition temperature in PVDF

    Energy Technology Data Exchange (ETDEWEB)

    Mai, M. [Institute of Electrical Engineering Physics, Saarland University, D-66123 Saarbruecken (Germany); Fridkin, V. [Institute of Crystallography of Russian Academy of Sciences, 119333 Moscow (Russian Federation); Martin, B., E-mail: b.martin@mx.uni-saarland.de [Institute of Electrical Engineering Physics, Saarland University, D-66123 Saarbruecken (Germany); Leschhorn, A.; Kliem, H. [Institute of Electrical Engineering Physics, Saarland University, D-66123 Saarbruecken (Germany)

    2013-07-15

    It was found recently that in the Langmuir–Blodgett ultrathin vinylidene fluoride (PVDF) films there is ferroelectric phase transition of the first order. Earlier in the bulk PVDF this phase transition was not observed because the melting temperature of this ferroelectric polymer (∼170 °C) is lower than the point of the possible phase transition. Therefore this polymer was treated for a long time as pyroelectric. In the present work we investigate PVDF Langmuir–Blodgett films at the nanoscale and the film thickness interval, where ferroelectric phase transition disappears and transition from ferroelectric to pyroelectric state takes place. This phenomenon is explained by the finite-size effect at the nanoscale using Landau–Ginzburg–Devonshire (LGD) theory and by the Weiss mean field model.

  16. Reclaimable Thermally Reversible Polymers for AM Feedstock, Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — CRG proposes to continue efforts from the 2016 NASA SBIR Phase I topic H5.04 Reclaimable Thermally Reversible Polymers for AM Feedstock. In Phase II, CRG will refine...

  17. Nonequilibrium topological phase transitions in two-dimensional optical lattices

    Science.gov (United States)

    Nakagawa, Masaya; Kawakami, Norio

    2014-01-01

    Recently, concepts of topological phases of matter are extended to nonequilibrium systems, especially periodically driven systems. In this paper, we construct an example which shows nonequilibrium topological phase transitions using ultracold fermions in optical lattices. We show that the Rabi oscillation has the possibility to induce nonequilibrium topological phases which are classified into time-reversal-invariant topological insulators for a two-orbital model of alkaline-earth-metal atoms. Furthermore, we study the nonequilibrium topological phases using time-dependent Schrieffer-Wolff-type perturbation theory, and we obtain an analytical expression to describe the topological phase transitions from a high-frequency limit of external driving fields.

  18. Calculation of Heat Exchange and Changing Phase Ratio in Extended Flowing Heat Accumulators on Phase Transitions with Rectangular Inserts

    Directory of Open Access Journals (Sweden)

    I. G. Zorina

    2016-01-01

    Full Text Available To use the renewable power sources such as solar, wind, biogas, and others is complicated because of their sporadic supply. Thus and so, energy accumulation makes the user independent on the operating mode of the power source.Some of the heat accumulation methods can be realized with accumulators using phase transitions and based on the heat storage materials that change their state of aggregation during storage and rejection of thermal energy. In comparison with the gravel or liquid heat accumulators these devices are compact and provide high density of stored energy. To intensify heat exchange in such devices, are used highly heat-conductive metallic inсlusions of different shape, capsular laying or heat storage materials placed in the form of inserts, extended heat exchange surfaces, etc.Heat transfer of accumulator using phase transitions is calculated through solving a nonlinear Stefan problem. For calculation, are, usually, used various sufficiently time-consuming methods.The paper presents a heat transfer calculation when changing the aggregation state of substance. Its recommendation is to use the analytical dependences that allow calculation of heat exchange characteristics with charging phase transition accumulators of a capsular type in which a heat storage material is in cross-inserts.It is assumed that heat transfer in the coolant flow is one-dimensional, thermal and physical properties of heat storage material and coolant are constant, and heat transfer in the accumulator using phase transitions is quasi-stationary.

  19. Polarons and Mobile Impurities Near a Quantum Phase Transition

    Science.gov (United States)

    Shadkhoo, Shahriar

    derives the effective Euclidean action from the classical equation of motion. We calculate the effective mass of the polaron in the model polar liquid at zero and finite temperatures. The self-trapping transition of this polaron turns out to be discontinuous in certain regions of the phase diagram. In order to systematically investigate the role of quantum fluctuations on the polaron properties, we adopt a quantum field theory which supports nearly-critical local modes: the quantum Landau-Brazovskii (QLB) model, which exhibits fluctuation-induced first order transition (weak crystallization). In the vicinity of the phase transition, the quantum fluctuations are strongly correlated; one can in principle tune the strength of these fluctuations, by adjusting the parameters close to or away from the transition point. Furthermore, sufficiently close to the transition, the theory accommodates "soliton'' solutions, signaling the nonlinear response of the system. Therefore, the model seems to be a promising candidate for studying the effects of strong quantum fluctuations and also failure of linear response theory, in the polaron problem. We observe that at zero temperature, and away from the Brazovskii transition where the linear response approximation is valid, the localization transition of the polaron is discontinuous. Upon enhancing fluctuations---of either thermal or quantum nature---the gap of the effective mass closes at distinct second-order critical points. Sufficiently close to the Brazovskii transition where the nonlinear contributions of the field are significantly large, a new state appears in addition to extended and self-trapped polarons: an impurity-induced soliton. We interpret this as the break-down of linear response, reminiscent of what we observe in a polar liquid. Quantum LB model has been proposed to be realizable in ultracold Bose gases in cavities. We thus discuss the experimental feasibility, and propose a setup which is believed to exhibit the

  20. Axially engineered metal-insulator phase transition by graded doping VO2 nanowires.

    Science.gov (United States)

    Lee, Sangwook; Cheng, Chun; Guo, Hua; Hippalgaonkar, Kedar; Wang, Kevin; Suh, Joonki; Liu, Kai; Wu, Junqiao

    2013-03-27

    The abrupt first-order metal-insulator phase transition in single-crystal vanadium dioxide nanowires (NWs) is engineered to be a gradual transition by axially grading the doping level of tungsten. We also demonstrate the potential of these NWs for thermal sensing and actuation applications. At room temperature, the graded-doped NWs show metal phase on the tips and insulator phase near the center of the NW, and the metal phase grows progressively toward the center when the temperature rises. As such, each individual NW acts as a microthermometer that can be simply read out with an optical microscope. The NW resistance decreases gradually with the temperature rise, eventually reaching 2 orders of magnitude drop, in stark contrast to the abrupt resistance change in undoped VO2 wires. This novel phase transition yields an extremely high temperature coefficient of resistivity ~10%/K, simultaneously with a very low resistivity down to 0.001 Ω·cm, making these NWs promising infrared sensing materials for uncooled microbolometers. Lastly, they form bimorph thermal actuators that bend with an unusually high curvature, ~900 m(-1)·K(-1) over a wide temperature range (35-80 °C), significantly broadening the response temperature range of previous VO2 bimorph actuators. Given that the phase transition responds to a diverse range of stimuli-heat, electric current, strain, focused light, and electric field-the graded-doped NWs may find wide applications in thermo-opto-electro-mechanical sensing and energy conversion.

  1. Discontinuity of maximum entropy inference and quantum phase transitions

    International Nuclear Information System (INIS)

    Chen, Jianxin; Ji, Zhengfeng; Yu, Nengkun; Zeng, Bei; Li, Chi-Kwong; Poon, Yiu-Tung; Shen, Yi; Zhou, Duanlu

    2015-01-01

    In this paper, we discuss the connection between two genuinely quantum phenomena—the discontinuity of quantum maximum entropy inference and quantum phase transitions at zero temperature. It is shown that the discontinuity of the maximum entropy inference of local observable measurements signals the non-local type of transitions, where local density matrices of the ground state change smoothly at the transition point. We then propose to use the quantum conditional mutual information of the ground state as an indicator to detect the discontinuity and the non-local type of quantum phase transitions in the thermodynamic limit. (paper)

  2. Superfluid phase transition with activated velocity fluctuations: Renormalization group approach

    Science.gov (United States)

    Dančo, Michal; Hnatič, Michal; Komarova, Marina V.; Lučivjanský, Tomáš; Nalimov, Mikhail Yu.

    2016-01-01

    A quantum field model that incorporates Bose-condensed systems near their phase transition into a superfluid phase and velocity fluctuations is proposed. The stochastic Navier-Stokes equation is used for a generation of the velocity fluctuations. As such this model generalizes model F of critical dynamics. The field-theoretic action is derived using the Martin-Siggia-Rose formalism and path integral approach. The regime of equilibrium fluctuations is analyzed within the perturbative renormalization group method. The double (ɛ ,δ ) -expansion scheme is employed, where ɛ is a deviation from space dimension 4 and δ describes scaling of velocity fluctuations. The renormalization procedure is performed to the leading order. The main corollary gained from the analysis of the thermal equilibrium regime suggests that one-loop calculations of the presented models are not sufficient to make a definite conclusion about the stability of fixed points. We also show that critical exponents are drastically changed as a result of the turbulent background and critical fluctuations are in fact destroyed by the developed turbulence fluctuations. The scaling exponent of effective viscosity is calculated and agrees with expected value 4 /3 .

  3. Superfluid phase transition with activated velocity fluctuations: Renormalization group approach.

    Science.gov (United States)

    Dančo, Michal; Hnatič, Michal; Komarova, Marina V; Lučivjanský, Tomáš; Nalimov, Mikhail Yu

    2016-01-01

    A quantum field model that incorporates Bose-condensed systems near their phase transition into a superfluid phase and velocity fluctuations is proposed. The stochastic Navier-Stokes equation is used for a generation of the velocity fluctuations. As such this model generalizes model F of critical dynamics. The field-theoretic action is derived using the Martin-Siggia-Rose formalism and path integral approach. The regime of equilibrium fluctuations is analyzed within the perturbative renormalization group method. The double (ε,δ)-expansion scheme is employed, where ε is a deviation from space dimension 4 and δ describes scaling of velocity fluctuations. The renormalization procedure is performed to the leading order. The main corollary gained from the analysis of the thermal equilibrium regime suggests that one-loop calculations of the presented models are not sufficient to make a definite conclusion about the stability of fixed points. We also show that critical exponents are drastically changed as a result of the turbulent background and critical fluctuations are in fact destroyed by the developed turbulence fluctuations. The scaling exponent of effective viscosity is calculated and agrees with expected value 4/3.

  4. Phase transition of pure zirconia under irradiation: A textbook example

    Energy Technology Data Exchange (ETDEWEB)

    Simeone, D. [CEA/Saclay, DEN/DMN/SRMA/LA2M, F-91191 Gif sur Yvette (France)]. E-mail: david.simeone@cea.fr; Baldinozzi, G. [Laboratoire de Structures, Proprietes et Modelisation des Solides, UMR CNRS 8580 Ecole Centrale Paris, F-92295 Chatenay Malabry (France); Gosset, D. [CEA/Saclay, DEN/DMN/SRMA/LA2M, F-91191 Gif sur Yvette (France); Le Caer, S. [CEA/Saclay, DSM/DRECAM/SCM/URA 331 CNRS, F-91191 Gif sur Yvette (France)

    2006-09-15

    One of the most important goals in ceramic and materials science is to be able to design materials with specific properties. Irradiation seems to be a powerful tool for the design of advanced ceramics because of its ability to modify over different scales the microstructure of solids. Nowadays, it is clearly proved that irradiation induces order-disorder phase transitions in metallic alloys and in some ceramics. In this paper, we show that a displacive phase transition can also be induced by irradiation. Based on many experimental facts, a microscopic model is proposed to explain the displacive phase transition observed in this material after irradiation. Defects, produced in the oxygen sublattice, induce important strain fields on a nanometric scale. This strain field can be handled as a secondary order parameter within the Landau theory approach, leading to a decrease of the phase transition temperature and thus quenching the high temperature tetragonal phase.

  5. Thermodynamic model of nonequilibrium phase transitions.

    Science.gov (United States)

    Martyushev, L M; Konovalov, M S

    2011-07-01

    Within the scope of a thermodynamic description using the maximum entropy production principle, transitions from one nonequilibrium (kinetic) regime to another are considered. It is shown that in the case when power-law dependencies of thermodynamic flux on force are similar for two regimes, only a transition accompanied by a positive jump of thermodynamic flux is possible between them. It is found that the difference in powers of the dependencies of thermodynamic fluxes on forces results in a number of interesting nonequilibrium transitions between kinetic regimes, including the reentrant one with a negative jump of thermodynamic flux.

  6. Evidence for a Cosmological Phase Transition on the TeVScale

    Energy Technology Data Exchange (ETDEWEB)

    Lindesay, James V.; Noyes, H.Pierre; /SLAC

    2005-08-23

    Examining the reverse evolution of the universe from the present, long before reaching Planck density dynamics one expects major modifications from the de-coherent thermal equations of state, suggesting a prior phase that has macroscopic coherence properties. The assumption that the phase transition occurs during the radiation dominated epoch, and that zero-point motions drive the fluctuations associated with this transition, specifies a class of cosmological models in which the cosmic microwave background fluctuation amplitude at last scattering is approximately 10{sup -5}. Quantum measurability constraints (e.g. uncertainly relations) define cosmological scales whose expansion rates can be at most luminal.

  7. Phase transition in a modified square Josephson-junction array

    CERN Document Server

    Han, J

    1999-01-01

    We study the phase transition in a modified square proximity-coupled Josephson-junction array with small superconducting islands at the center of each plaquette. We find that the modified square array undergoes a Kosterlitz-Thouless-Berezinskii-like phase transition, but at a lower temperature than the simple square array with the same single-junction critical current. The IV characteristics, as well as the phase transition, resemble qualitatively those of a disordered simple square array. The effects of the presence of the center islands in the modified square array are discussed.

  8. Novel phase transitions in B-site doped manganites

    International Nuclear Information System (INIS)

    Popovic, Z.V.; Cantarero, A.; Thijssen, W.H.A.; Paunovic, N.; Dohcevic-Mitrovic, Z.; Sapina, F.

    2005-01-01

    We have examined the infrared reflectivity and the electrical resistivity of La 1- x [Sr(Ba)] x Mn 1- z [Cu(Zn)] z O 3 samples in ferromagnetic metallic and insulator regime. Several phase transitions are observed, the most obvious being the transition from a ferromagnetic metallic to a ferromagnetic insulator phase that is related to the formation of short-range orbitally ordered domains. The temperature T 1 of the phase transition is dependent on doping concentration and for optimally doped samples (∼32% of Mn 4+ ions) we have found T 1 ∼0.93 T C

  9. Quantum phase transitional patterns of nuclei

    International Nuclear Information System (INIS)

    Dai Lianrong; Wang Lixing; Pan Feng; Zhong Weiwei; Liu Qi

    2013-01-01

    With the framework of Interacting Boson Model (IBM), transitional patterns from the spherical to the axially deformed limit of the IBM with a schematic Hamiltonian are studied by replacing the SU (3) quadrupole-quadrupole term with O (6) cubic interaction. But, we use the two schemes to investigate some energy ratios and B (E2) ratios for different bosons N = 8 and N = 20. The results show that with the increasing of the numbers of bosons, the transitional behaviors can be enhanced; the transitional behaviors are very similar in the two schemes. However, there are some distinctive differences for some quantities across the entire transitional region, such as energy levels and ratios, B (E2) values and ratios, and expectation values of the shape variables. Generally speaking, the transition is smoother and the nuclear shape is less well defined in the new scheme. Then we apply the two schemes to the critical point symmetry candidate, such as 152 Sm, and find the overall fitting quality of the UQ scheme is better than that of the U (5)-SU (3) scheme, especially for the inter-band E2 transitions in 152 Sm. (authors)

  10. Multi-Cell Thermal Battery, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — The multi-cell thermal battery (MCTB) is a device that can recover a large fraction of the thermal energy from heated regolith and subsequently apply this energy to...

  11. Titanium Heat Pipe Thermal Plane, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — Thermacore Inc. proposes an innovative titanium heat pipe thermal plane for passive thermal control of individual cells within a fuel cell stack. The proposed...

  12. Multi-Cell Thermal Battery, Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — The multi-cell thermal battery (MCTB) is a device that can recover a large fraction of the thermal energy from heated regolith and subsequently apply this energy to...

  13. Quantum phase transitions in random XY spin chains

    International Nuclear Information System (INIS)

    Bunder, J.E.; McKenzie, R.H.

    2000-01-01

    Full text: The XY spin chain in a transverse field is one of the simplest quantum spin models. It is a reasonable model for heavy fermion materials such as CeCu 6-x Au x . It has two quantum phase transitions: the Ising transition and the anisotropic transition. Quantum phase transitions occur at zero temperature. We are investigating what effect the introduction of randomness has on these quantum phase transitions. Disordered systems which undergo quantum phase transitions can exhibit new universality classes. The universality class of a phase transition is defined by the set of critical exponents. In a random system with quantum phase transitions we can observe Griffiths-McCoy singularities. Such singularities are observed in regions which have no long range order, so they are not classified as critical regions, yet they display phenomena normally associated with critical points, such as a diverging susceptibility. Griffiths-McCoy phases are due to rare regions with stronger than! average interactions and may be present far from the quantum critical point. We show how the random XY spin chain may be mapped onto a random Dirac equation. This allows us to calculate the density of states without making any approximations. From the density of states we can describe the conditions which should allow a Griffiths-McCoy phase. We find that for the Ising transition the dynamic critical exponent, z, is not universal. It is proportional to the disorder strength and inversely proportional to the energy gap, hence z becomes infinite at the critical point where the energy gap vanishes

  14. Pressure-induced phase transition in a ternary microemulsion system

    International Nuclear Information System (INIS)

    Nagao, Michihiro; Seto, Hideki

    2002-01-01

    Static and dynamic structure of a ternary microemulsion system including AOT (Aerosol-OT; dioctyl sulfosuccinate sodium salt) were investigated in order to clarify the mechanism of the structural phase transition induced by pressure. From the static measurement by means of small-angle x-ray and neutron scattering (SAXS and SANS), it was observed that the dense water-in-oil droplet structure at ambient temperature and pressure transformed to two-phase coexistence with the lamellar phase and the bicontinuous phase with increasing pressure as the case of increasing temperature. The characteristic features of pressure-induced phase transition were quite similar to the temperature-induced one below the phase transition temperature and pressure, however, above the transition temperature and pressure, they were different. From the dynamical measurement by means of the neutron spin echo (NSE), membrane dynamics at high-pressure phase was observed completely different from the high temperature phase. The result showed that with increasing temperature the membrane became flexible and, on the other hand, it became rigid with increasing pressure. These differences suggested the different mechanism of the pressure-induced phase transition from the temperature-induced one. (author)

  15. Holographic Van der Waals-like phase transition in the Gauss–Bonnet gravity

    Energy Technology Data Exchange (ETDEWEB)

    He, Song, E-mail: hesong17@gmail.com [Max Planck Institute for Gravitational Physics (Albert Einstein Institute), Am Mühlenberg 1, 14476 Golm (Germany); State Key Laboratory of Theoretical Physics, Institute of Theoretical Physics, Chinese Academy of Sciences, Beijing 100190 (China); Li, Li-Fang, E-mail: lilf@itp.ac.cn [Center for Space Science and Applied Research, Chinese Academy of Sciences, Beijing 100190 (China); Zeng, Xiao-Xiong, E-mail: xxzeng@itp.ac.cn [State Key Laboratory of Theoretical Physics, Institute of Theoretical Physics, Chinese Academy of Sciences, Beijing 100190 (China); School of Material Science and Engineering, Chongqing Jiaotong University, Chongqing 400074 (China)

    2017-02-15

    The Van der Waals-like phase transition is observed in temperature–thermal entropy plane in spherically symmetric charged Gauss–Bonnet–AdS black hole background. In terms of AdS/CFT, the non-local observables such as holographic entanglement entropy, Wilson loop, and two point correlation function of very heavy operators in the field theory dual to spherically symmetric charged Gauss–Bonnet–AdS black hole have been investigated. All of them exhibit the Van der Waals-like phase transition for a fixed charge parameter or Gauss–Bonnet parameter in such gravity background. Further, with choosing various values of charge or Gauss–Bonnet parameter, the equal area law and the critical exponent of the heat capacity are found to be consistent with phase structures in temperature–thermal entropy plane.

  16. Multifragmentation of heavy systems: partitions and phase transition signals; Multifragmentation de systemes lourds: partitions et signaux de transition de phases

    Energy Technology Data Exchange (ETDEWEB)

    Bonnet, E

    2006-09-15

    This work studies mononuclear systems produced in heavy ion collisions with large (peripheral: Au+Au) and small (central: Xe+Sn et Gd+U) impact parameters. These two classes of collisions need specific selections in order to isolate sources in thermal equilibrium (quasi-projectiles and quasi-fusion sources). We perform analyses on the statistical ensembles of events obtained after those selections to evidence phase transition signatures. First, a bimodal behaviour of the biggest fragment (Z{sub 1}) distribution, in peripheral collisions, is related to an order parameter using a renormalisation with an equiprobable excitation energy (E{sup *}) distribution constraint. A comparison with a canonical ensemble gives us information on the coexistence region location. Then, we compare static and dynamical properties of fragments produced by these sources in peripheral and central collisions. Differences on fragment multiplicities and charge asymmetry of partitions are observed. They find their origins in the presence or not of a velocity field mostly related to collective radial expansion during fragment formation. Analyses of the signal related to abnormal fluctuations of configurational energies and of the fossil signal related to spinodal decomposition for Au quasi-projectiles are performed to establish a link with the same signals already observed for central collisions. Finally, the location of events of the two types of sources in the E{sup *} - Z{sub 1} plane, are compared with a phase diagram, particularly the boundaries of the coexistence region deduced from the previous signals. (author)

  17. QCD phase transition in Brans-Dicke cosmology

    Energy Technology Data Exchange (ETDEWEB)

    Atazadeh, K. [Shahid Beheshti University G. C., Evin, Department of Physics, Tehran (Iran, Islamic Republic of)

    2011-04-15

    In the standard picture of cosmology, when the universe was about 10 {mu}sec old it underwent a transition from quark phase to hadron one, being associated with a chiral symmetry breaking after the electro weak transition. We assume that this transition was of crossover and study the evolution of the Universe in the context of Brans-Dicke theory. The evolution of physical quantities relevant to the physical description of the early Universe, namely, the energy density, temperature and the scale factor, are studied within an effective model of lattice QCD for high temperature and also we consider in the context of hadronic resonance gas model those parameters at low temperature. We show that for different values of Brans-Dicke coupling, {omega}, a phase transition occurs and results in decreasing of the effective temperature of the quark-gluon plasma during the process of quark-hadron phase transition. (orig.)

  18. Five-dimensional visualization of phase transition in BiNiO3 under high pressure

    Science.gov (United States)

    Liu, Yijin; Wang, Junyue; Azuma, Masaki; Mao, Wendy L.; Yang, Wenge

    2014-01-01

    Colossal negative thermal expansion was recently discovered in BiNiO3 associated with a low density to high density phase transition under high pressure. The varying proportion of co-existing phases plays a key role in the macroscopic behavior of this material. Here, we utilize a recently developed X-ray Absorption Near Edge Spectroscopy Tomography method and resolve the mixture of high/low pressure phases as a function of pressure at tens of nanometer resolution taking advantage of the charge transfer during the transition. This five-dimensional (X, Y, Z, energy, and pressure) visualization of the phase boundary provides a high resolution method to study the interface dynamics of high/low pressure phase.

  19. Augmentation of Solar Thermal Propulsion Systems Via Phase Change Thermal Energy Storage and Thermal Electric Conversion

    Science.gov (United States)

    2012-04-01

    system can be devised with a less than 50% propulsion mass fraction (including propel- lant) and a 1.5 km/s velocity increment (ΔV ) capability...Geosynchronous Transfer Or- bit (GTO) to Geosynchronous Earth Orbit (GEO), insertion into lunar orbit, LaGrange point insertion, highly eccentric ...container so that the phase transition process dom - inates. Current experimental scales are limited in size due to the low power delivery of the Fresnel

  20. Dynamical Symmetries and Causality in Non-Equilibrium Phase Transitions

    Directory of Open Access Journals (Sweden)

    Malte Henkel

    2015-11-01

    Full Text Available Dynamical symmetries are of considerable importance in elucidating the complex behaviour of strongly interacting systems with many degrees of freedom. Paradigmatic examples are cooperative phenomena as they arise in phase transitions, where conformal invariance has led to enormous progress in equilibrium phase transitions, especially in two dimensions. Non-equilibrium phase transitions can arise in much larger portions of the parameter space than equilibrium phase transitions. The state of the art of recent attempts to generalise conformal invariance to a new generic symmetry, taking into account the different scaling behaviour of space and time, will be reviewed. Particular attention will be given to the causality properties as they follow for co-variant n-point functions. These are important for the physical identification of n-point functions as responses or correlators.

  1. Research for the energy turnaround. Phase transitions actively shape. Contributions

    International Nuclear Information System (INIS)

    Szczepanski, Petra; Wunschick, Franziska; Martin, Niklas

    2015-01-01

    The Annual Conference 2014 of the Renewable Energy Research Association was held in Berlin on 6 and 7 November 2014. This book documents the contributions of the conference on research for the energy turnaround, phase transitions actively shape. After an introduction and two contributions to the political framework, the contributions to the economic phases of the energy transition, the phase of the current turn, the phases of social energy revolution, the stages of heat turnaround (Waermewende), and the stages of the mobility turn deal with the stages of development of the energy system. Finally, the Research Association Renewable Energy is briefly presented. [de

  2. Electroweak phase transition in a model with gauged lepton number

    International Nuclear Information System (INIS)

    Aranda, Alfredo; Jiménez, Enrique; Vaquera-Araujo, Carlos A.

    2015-01-01

    In this work we study the electroweak phase transition in a model with gauged lepton number. Here, a family of vector-like leptons is required in order to cancel the gauge anomalies. Furthermore, these leptons can play an important role in the transition process. We find that this framework is able to provide a strong transition, but only for a very limited number of cases.

  3. Phase transition of bismuth telluride thin films grown by MBE

    DEFF Research Database (Denmark)

    Fülöp, Attila; Song, Yuxin; Charpentier, Sophie

    2014-01-01

    A previously unreported phase transition between Bi2Te3 and Bi4Te3 in bismuth telluride grown by molecular beam epitaxy is recorded via XRD, AFM, and SIMS observations. This transition is found to be related to the Te/Bi beam equivalent pressure (BEP) ratio. BEP ratios below 17 favor the formation...

  4. Phase transition in L-alaninium oxalate by photoacoustics

    Indian Academy of Sciences (India)

    Phase transition in L-alaninium oxalate is studied by using TG, DTA and photoacoustic spectroscopy. A sharp transition at 378 K by photoacoustics is observed whereas at the same temperature the endothermic energy change observed by TG and DTA is not very sharp. This is discussed in detail with reference to the other ...

  5. Phase transitions, interfacial fluctuations and hidden symmetries for ...

    Indian Academy of Sciences (India)

    Fluids adsorbed at micro-patterned and geometrically structured substrates can exhibit novel phase transitions and interfacial fluctuation effects distinct from those characteristic of wetting at planar, homogeneous walls. We review recent theoretical progress in this area paying particular attention to filling transitions pertinent ...

  6. Quantum Shape-Phase Transitions in Finite Nuclei

    International Nuclear Information System (INIS)

    Leviatan, A.

    2007-01-01

    Quantum shape-phase transitions in finite nuclei are considered in the framework of the interacting boson model. Critical-point Hamiltonians for first- and second-order transitions are identified by resolving them into intrinsic and collective parts. Suitable wave functions and finite-N estimates for observables at the critical-points are derived

  7. Quantum Shape-Phase Transitions in Finite Nuclei

    Energy Technology Data Exchange (ETDEWEB)

    Leviatan, A. [Racah Institute of Physics, Hebrew University, Jerusalem 91904 (Israel)

    2007-05-15

    Quantum shape-phase transitions in finite nuclei are considered in the framework of the interacting boson model. Critical-point Hamiltonians for first- and second-order transitions are identified by resolving them into intrinsic and collective parts. Suitable wave functions and finite-N estimates for observables at the critical-points are derived.

  8. The QCD phase transitions: From mechanism to observables

    Energy Technology Data Exchange (ETDEWEB)

    Shuryak, E.V.

    1997-09-22

    This paper contains viewgraphs on quantum chromodynamic phase transformations during heavy ion collisions. Some topics briefly described are: finite T transitions of I molecule pairs; finite density transitions of diquarks polymers; and the softtest point of the equation of state as a source of discontinuous behavior as a function of collision energy or centrality.

  9. Signals of a phase transition in nuclear breakup

    International Nuclear Information System (INIS)

    Campi, X.

    1987-01-01

    We show that nuclei break up like finite systems that exhibit a clean phase transition in infinite size. This is done by studying conditional moments of the fragment multiplicities, the largest fragment size produced by event and its fluctuations. The nature of this smooth phase transition cannot be determined from the available experimental data. The ''critical point'' is reached when the energy deposited in the nucleus is 90% of its binding energy

  10. Partial dynamical symmetry at critical points of quantum phase transitions.

    Science.gov (United States)

    Leviatan, A

    2007-06-15

    We show that partial dynamical symmetries can occur at critical points of quantum phase transitions, in which case underlying competing symmetries are conserved exactly by a subset of states, and mix strongly in other states. Several types of partial dynamical symmetries are demonstrated with the example of critical-point Hamiltonians for first- and second-order transitions in the framework of the interacting boson model, whose dynamical symmetries correspond to different shape phases in nuclei.

  11. Partial Dynamical Symmetry at Critical Points of Quantum Phase Transitions

    International Nuclear Information System (INIS)

    Leviatan, A.

    2007-01-01

    We show that partial dynamical symmetries can occur at critical points of quantum phase transitions, in which case underlying competing symmetries are conserved exactly by a subset of states, and mix strongly in other states. Several types of partial dynamical symmetries are demonstrated with the example of critical-point Hamiltonians for first- and second-order transitions in the framework of the interacting boson model, whose dynamical symmetries correspond to different shape phases in nuclei

  12. Hadronization during quark-gluon plasma phase transition

    International Nuclear Information System (INIS)

    Mohanty, A.K.; Kataria, S.K.

    1996-01-01

    The hadron multiplicity distributions and factorial moments are studied in the framework of Landau theory of phase transitions. The factorial moments show a scaling law with a scaling exponent ν which characterizes the intermittency properties of the hadron phase for T c (or T t ) where T c (or T t ) is the transition temperature for second (or first) order transition. The scaling exponent ν is weakly dependent on the free energy parameters as well as on temperature. It is shown that ν remains practically constant in the hadron phase for which T c or T t whether the transition is second order or first order of second kind where the free energy expansion includes cubic term. This universality in the scaling exponent is also maintained above T c over a wide range of temperature even if the transition is strongly first order of first kind where the free energy expansion has only even order coefficients, except around the critical temperature T t where T t approx-gt T c . Therefore, the scaling exponent ν is rather more universal and only indicates the presence of a possible phase transition. It is further shown that the hadron multiplicity distribution is quite sensitive to the free energy parameters. The study of hadron multiplicity distribution at various resolution or bin size reveals more information about the dynamics of the phase transition. The calculated hadron multiplicity distributions are also compared with the negative binomial distribution, often used to explain the experimental multiplicity distributions. copyright 1996 The American Physical Society

  13. The cosmic QCD phase transition with dense matter and its gravitational waves from holography

    Science.gov (United States)

    Ahmadvand, M.; Bitaghsir Fadafan, K.

    2018-04-01

    Consistent with cosmological constraints, there are scenarios with the large lepton asymmetry which can lead to the finite baryochemical potential at the cosmic QCD phase transition scale. In this paper, we investigate this possibility in the holographic models. Using the holographic renormalization method, we find the first order Hawking-Page phase transition, between the Reissner-Nordström AdS black hole and thermal charged AdS space, corresponding to the de/confinement phase transition. We obtain the gravitational wave spectra generated during the evolution of bubbles for a range of the bubble wall velocity and examine the reliability of the scenarios and consequent calculations by gravitational wave experiments.

  14. Liquid-liquid phase transition and glass transition in a monoatomic model system.

    Science.gov (United States)

    Xu, Limei; Buldyrev, Sergey V; Giovambattista, Nicolas; Stanley, H Eugene

    2010-01-01

    We review our recent study on the polyamorphism of the liquid and glass states in a monatomic system, a two-scale spherical-symmetric Jagla model with both attractive and repulsive interactions. This potential with a parametrization for which crystallization can be avoided and both the glass transition and the liquid-liquid phase transition are clearly separated, displays water-like anomalies as well as polyamorphism in both liquid and glassy states, providing a unique opportunity to study the interplay between the liquid-liquid phase transition and the glass transition. Our study on a simple model may be useful in understanding recent studies of polyamorphism in metallic glasses.

  15. Experimental study of the magnetic phase transition in the MnSi itinerant helimagnet

    International Nuclear Information System (INIS)

    Stishov, S. M.; Petrova, A. E.; Khasanov, S.; Panova, G. Kh.; Shikov, A. A.; Lashley, J. C.; Wu, D.; Lograsso, T. A.

    2008-01-01

    Magnetic susceptibility, heat capacity, thermal expansion, and resistivity of a high-quality single crystal of MnSi were carefully studied at ambient pressure. The calculated change in magnetic entropy in the temperature range 0-30 K is less than 0.1R, a low value that emphasizes the itinerant nature of magnetism in MnSi. A linear temperature term dominates the behavior of the thermal expansion coefficient in the range 30-150 K, which correlates to a large enhancement of the linear electronic term in the heat capacity. A surprising similarity between variation of the heat capacity, the thermal expansion coefficient, and the temperature derivative of resistivity through the phase transition in MnSi is observed. Specific forms of the heat capacity, thermal expansion coefficient, and temperature derivative of resistivity at the phase transition to a helical magnetic state near 29 K are interpreted as a combination of sharp first-order features and broad peaks or shallow valleys of yet unknown origin. The appearance of these broad satellites probably hints at a frustrated magnetic state in MnSi slightly above the transition temperature. Present experimental findings bring the current views on the phase diagram of MnSi into question

  16. Problem-solving phase transitions during team collaboration

    DEFF Research Database (Denmark)

    Wiltshire, Travis; Butner, Jonathan E.; Fiore, Stephen M.

    2017-01-01

    ) with dynamical systems theory suggesting that when a system is undergoing a phase transition it should exhibit a peak in entropy and that entropy levels should also relate to team performance. Communications from 40 teams that collaborated on a complex problem were coded for occurrence of problem......-solving processes. We applied a sliding window entropy technique to each team's communications and specified criteria for (a) identifying data points that qualify as peaks and (b) determining which peaks were robust. We used multilevel modeling, and provide a qualitative example, to evaluate whether phases exhibit...... phases. Peaks in entropy thus corresponded to qualitative shifts in teams’ CPS communications, providing empirical evidence that teams exhibit phase transitions during CPS. Also, lower average levels of entropy at the phase transition points predicted better CPS performance. We specify future directions...

  17. Entropy and baryon number conservation in the deconfinement phase transition

    International Nuclear Information System (INIS)

    Leonidov, A.; Redlich, K.; Satz, H.; Suhonen, E.; Weber, G.

    1994-01-01

    The conservation of entropy and baryon number in the deconfinement phase transition is studied in the framework of the bag model. In the standard construction of the equilibrium phase transition from a quark-gluon plasma into a hadron gas a subsequent dilution and reheating of the system on the phase boundary is necessary to preserve the entropy and baryon number conservation. We propose modifying the bag pressure to depend explicitly on temperature and baryon chemical potential. It is shown that this modification is sufficient to construct a model in agreement with the Gibbs equilibrium criteria for a phase transition, while simultaneously assuring entropy and baryon number conservation on the phase boundary. Within this model the quark-gluon plasma hadronizes at a fixed temperature and chemical potential

  18. Density Functional Theory for Phase-Ordering Transitions

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Jianzhong [Univ. of California, Riverside, CA (United States)

    2016-03-30

    Colloids display astonishing structural and dynamic properties that can be dramatically altered by modest changes in the solution condition or an external field. This complex behavior stems from a subtle balance of colloidal forces and intriguing mesoscopic and macroscopic phase transitions that are sensitive to the processing conditions and the dispersing environment. Whereas the knowledge on the microscopic structure and phase behavior of colloidal systems at equilibrium is now well-advanced, quantitative predictions of the dynamic properties and the kinetics of phase-ordering transitions in colloids are not always realized. Many important mesoscopic and off-equilibrium colloidal states remain poorly understood. The proposed research aims to develop a new, unifying approach to describe colloidal dynamics and the kinetics of phase-ordering transitions based on accomplishments from previous work for the equilibrium properties of both uniform and inhomogeneous systems and on novel concepts from the state-of-the-art dynamic density functional theory. In addition to theoretical developments, computational research is designed to address a number of fundamental questions on phase-ordering transitions in colloids, in particular those pertinent to a competition of the dynamic pathways leading to various mesoscopic structures, off-equilibrium states, and crystalline phases. By providing a generic theoretical framework to describe equilibrium, metastable as well as non-ergodic phase transitions concurrent with the colloidal self-assembly processes, accomplishments from this work will have major impacts on both fundamental research and technological applications.

  19. Polymer Semiflexibility Induces Nonuniversal Phase Transitions in Diblock Copolymers

    Science.gov (United States)

    Mao, Shifan; MacPherson, Quinn; Spakowitz, Andrew J.

    2018-02-01

    The order-disorder phase transition and the associated phase diagrams of semiflexible diblock copolymers are investigated using the wormlike chain model, incorporating concentration fluctuations. The free energy up to quartic order in concentration fluctuations is developed with chain-rigidity-dependent coefficients, evaluated using our exact results for the wormlike chain model, and a one-loop renormalization treatment is used to account for fluctuation effects. The chain length N and the monomer aspect ratio α directly control the strength of immiscibility (defined by the Flory-Huggins parameter χ ) at the order-disorder transition and the resulting microstructures at different chemical compositions fA. When monomers are infinitely thin (i.e., large aspect ratio α ), the finite chain length N lowers the χ N at the phase transition. However, fluctuation effects become important when chains have a finite radius, and a decrease in the chain length N elevates the χ N at the phase transition. Phase diagrams of diblock copolymers over a wide range of N and α are calculated based on our fluctuation theory. We find that both finite N and α enhance the stability of the lamellar phase above the order-disorder transition. Our results demonstrate that polymer semiflexibility plays a dramatic role in the phase behavior, even for large chain lengths (e.g., N ≈100 ).

  20. Ab initio theory of helix <-> coil phase transition

    DEFF Research Database (Denmark)

    Yakubovich, Alexander V.; Solov'yov, Ilia; Solov'yov, Andrey V.

    2008-01-01

    In this paper, we suggest a theoretical method based on the statistical mechanics for treating the alpha-helix random coil transition in alanine polypeptides. We consider this process as a first-order phase transition and develop a theory which is free of model parameters and is based solely...... on fundamental physical principles. It describes essential thermodynamical properties of the system such as heat capacity, the phase transition temperature and others from the analysis of the polypeptide potential energy surface calculated as a function of two dihedral angles, responsible for the polypeptide...

  1. Phase transitions and spin excitations of spin-1 bosons in optical lattice

    Science.gov (United States)

    Zhu, Min-Jie; Zhao, Bo

    2018-03-01

    For spin-1 bosonic system trapped in optical lattice, we investigate two main problems, including MI-SF phase transition and magnetic phase separations in MI phase, with extended standard basis operator (SBO) method. For both ferromagnetic (U2 0) systems, we analytically figure out the symmetry properties in Mott-insulator and superfluid phases, which would provide a deeper insight into the MI-SF phase transition process. Then by applying self-consistent approach to the method, we include the effect of quantum and thermal fluctuations and derive the MI-SF transition phase diagram, which is in quantitative agreement with recent Monte-Carlo simulation at zero temperature, and at finite temperature, we find the underestimation of finite-temperature-effect in the mean-field approximation method. If we further consider the spin excitations in the insulating states of spin-1 system in external field, distinct spin phases are expected. Therefore, in the Mott lobes with n = 1 and n = 2 atoms per site, we give analytical and numerical boundaries of the singlet, nematic, partially magnetic and ferromagnetic phases in the magnetic phase diagrams.

  2. Martensitic phase transition in Cu–14%Al–4%Ni shape memory alloys studied by Brillouin light scattering

    International Nuclear Information System (INIS)

    Graczykowski, B; Mielcarek, S; Mroz, B; Breczewski, T; No, M L; San-Juan, J

    2013-01-01

    The paper presents the influence of the martensitic phase transition on hypersonic thermally excited surface acoustic waves propagating in Cu–14%Al–4%Ni (wt%) shape memory alloy. Non-destructive and non-contact testing using Brillouin light scattering spectroscopy permitted determination of the elastic constants of austenite versus temperature. Experimental results obtained for martensite were interpreted using the proposed model of the cubic to orthorhombic martensitic phase transition based on the Landau model of a first-order phase transition. Additionally we adopted the approximation of the domain structure of martensite by a polycrystalline sample using the Voigt–Reuss–Hill procedure of averaging the elastic constants. (paper)

  3. Magnetic and Structural Phase Transitions in Thulium under High Pressures and Low Temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Vohra, Yogesh K.; Tsoi, Georgiy M.; Samudrala, Gopi K. [UAB

    2017-10-01

    The nature of 4f electrons in many rare earth metals and compounds may be broadly characterized as being either "localized" or "itinerant", and is held responsible for a wide range of physical and chemical properties. The pressure variable has a very dramatic effect on the electronic structure of rare earth metals which in turn drives a sequence of structural and magnetic transitions. We have carried out four-probe electrical resistance measurements on rare earth metal Thulium (Tm) under high pressures to 33 GPa and low temperatures to 10 K to monitor the magnetic ordering transition. These studies are complemented by angle dispersive x-ray diffraction studies to monitor crystallographic phase transitions at high pressures and low temperatures. We observe an abrupt increase in magnetic ordering temperature in Tm at a pressure of 17 GPa on phase transition from ambient pressure hcp-phase to α-Sm phase transition. In addition, measured equation of state (EOS) at low temperatures show anomalously low thermal expansion coefficients likely linked to magnetic transitions.

  4. An objective indicator for two-phase flow pattern transition

    International Nuclear Information System (INIS)

    Hervieua, E.; Seleghim, P. Jr.

    1998-01-01

    This work concerns the development of a methodology the objective of which is to characterize and diagnose two-phase flow regime transitions. The approach is based on the fundamental assumption that a transition flow is less stationary than a flow with an established regime. During the first time, the efforts focused on: (1) the design and construction of an experimental loop, allowing to reproduce the main horizontal two-phase flow patterns, in a stable and controlled way; (2) the design and construction of an electrical impedance probe, providing an imaged information of the spatial phase distribution in the pipe; and (3) the systematic study of the joint time-frequency and time-scale analysis methods, which permitted to define an adequate parameter quantifying the unstationarity degree. During the second time, in order to verify the fundamental assumption, a series of experiments were conducted, the objective of which was to demonstrate the correlation between unstationarity and regime transition. The unstationarity degree was quantified by calculating the Gabor's transform time-frequency covariance of the impedance probe signals. Furthermore, the phenomenology of each transition was characterized by the joint moments and entropy. The results clearly show that the regime transitions are correlated with local time-frequency covariance peaks, which demonstrates that these regime transitions are characterized by a loss of stationarity. Consequently, the time-frequency covariance constitutes an objective two-phase flow regime transition indicator. (orig.)

  5. An objective indicator for two-phase flow pattern transition

    International Nuclear Information System (INIS)

    Hervieu, E.; Seleghim, P. Jr.

    1998-01-01

    This work concerns the development of a methodology which objective is to characterize and diagnose two-phase flow regime transitions. The approach is based on the fundamental assumption that a transition flow is less stationary than a flow with an established regime. In a first time, the efforts focused on: the design and construction of an experimental loop, allowing to reproduce the main horizontal two-phase flow patterns, in a stable and controlled way; the design and construction of an electrical impedance probe, providing an imaged information of the spatial phase distribution in the pipe; the systematic study of the joint time-frequency and time-scale analysis methods, which permitted to define an adequate parameter quantifying the unstationarity degree. In a second time, in order to verify the fundamental assumption, a series of experiments were conducted, which objective was to demonstrate the correlation between unstationarity and regime transition. The unstationarity degree was quantified by calculating the Gabor's transform time-frequency covariance of the impedance probe signals. Furthermore, the phenomenology of each transition was characterized by the joint moments and entropy. The results clearly show that the regime transitions are correlated with local time-frequency covariance peaks, which demonstrates that these regime transitions are characterized by a loss of stationarity. Consequently, the time-frequency covariance constitutes an objective two-phase flow regime transition indicator. (author)

  6. The Phase Transitions between H 0.27V 0.27W 0.73O 3· {1}/{3} H 2O and V 0.27W 0.73O 2.865: An X-Ray, Thermal Analysis, and HREM Study

    Science.gov (United States)

    Dupont, L.; Sundberg, M.

    1998-03-01

    A mixed vanadium-tungsten oxide hydrate (H 0.27V 0.27W 0.73O 3· {1}/{3}H 2O) has been synthesized by a soft chemistry method, and the phase transitions from the hydrate (precursor) to the final product V 0.27W 0.73O 2.865have been studied by thermal analysis, X-ray powder diffraction, and high-resolution electron microscopy (HREM) techniques. Supermetastable, metastable, and stable oxides have been observed. H 0.27V 0.27W 0.73O 3· {1}/{3}H 2O possesses a structure related to WO 3· {1}/{3}H 2O. Dehydration of the precursor leads to a supermetastable phase, H 0.27V 0.27W 0.73O 3, with a structure similar to that of the hydrate. At 350°C this phase transforms to the metastable H 0.27V 0.27W 0.73O 3, with a structure isotypic with WO 3(hex). The phase transition between the hydrate and H 0.27V 0.27W 0.73O 3is both pseudomorphous and topotactic. Removal of hydrogen and oxygen from the metastable oxide induces a second phase transition at 500°C to a more stable phase, V 0.27W 0.73O 2.865, with an oxygen-deficient WO 3-type structure. The monoclinic symmetry of the latter oxide increases at higher temperature, first to orthorhombic and then to tetragonal. This transition is not pseudomorphous but of a topotactic nature. The obtained results suggest that the hydrogen content stabilizes the WO 3(hex)-related structure of the metastable phase. A hypothetical model based on HREM observations is proposed for the structural transformation H 0.27V 0.27W 0.73O 3→V 0.27W 0.73O 2.865.

  7. Five-dimensional visualization of phase transition in BiNiO3 under high pressure

    OpenAIRE

    Liu, Yijin; Wang, Junyue; Azuma, Masaki; Mao, Wendy L.; Yang, Wenge

    2014-01-01

    Colossal negative thermal expansion was recently discovered in BiNiO3 associated with a low density to high density phase transition under high pressure. The varying proportion of co-existing phases plays a key role in the macroscopic behavior of this material. Here, we utilize a recently developed X-ray Absorption Near Edge Spectroscopy Tomography method and resolve the mixture of high/low pressure phases as a function of pressure at tens of nanometer resolution taking advantage of the charg...

  8. New numerical method to study phase transitions and its applications

    International Nuclear Information System (INIS)

    Lee, Jooyoung; Kosterlitz, J.M.

    1991-11-01

    We present a powerful method of identifying the nature of transitions by numerical simulation of finite systems. By studying the finite size scaling properties of free energy barrier between competing states, we can identify unambiguously a weak first order transition even when accessible system sizes are L/ξ < 0.05 as in the five state Potts model in two dimensions. When studying a continuous phase transition we obtain quite accurate estimates of critical exponents by treating it as a field driven first order transition. The method has been successfully applied to various systems

  9. Gas phase thermal diffusion of stable isotopes

    International Nuclear Information System (INIS)

    Eck, C.F.

    1979-01-01

    The separation of stable isotopes at Mound Facility is reviewed from a historical perspective. The historical development of thermal diffusion from a laboratory process to a separation facility that handles all the noble gases is described. In addition, elementary thermal diffusion theory and elementary cascade theory are presented along with a brief review of the uses of stable isotopes

  10. Thermal Energy Storage in Phase Change Material.

    Science.gov (United States)

    1982-03-01

    Graphs of the exnerimental results follow: tney are groupea in the tree categories: tube cross flow, ricked bed, and tube parallel flow. A. Tube Cross... Riordan , Michael, "Thermal Storage: A Rtsic Guile to the Ptate of the Art", Solar Age, Aril, 1978, P. 10. 5. Telkes, Maria, "Thermal Lner y Storage in

  11. Dark Matter Decay between Phase Transitions at the Weak Scale.

    Science.gov (United States)

    Baker, Michael J; Kopp, Joachim

    2017-08-11

    We propose a new alternative to the weakly interacting massive particle paradigm for dark matter. Rather than being determined by thermal freeze-out, the dark matter abundance in this scenario is set by dark matter decay, which is allowed for a limited amount of time just before the electroweak phase transition. More specifically, we consider fermionic singlet dark matter particles coupled weakly to a scalar mediator S_{3} and to auxiliary dark sector fields, charged under the standard model gauge groups. Dark matter freezes out while still relativistic, so its abundance is initially very large. As the Universe cools down, the scalar mediator develops a vacuum expectation value (VEV), which breaks the symmetry that stabilizes dark matter. This allows dark matter to mix with charged fermions and decay. During this epoch, the dark matter abundance is reduced to give the value observed today. Later, the SM Higgs field also develops a VEV, which feeds back into the S_{3} potential and restores the dark sector symmetry. In a concrete model we show that this "VEV flip-flop" scenario is phenomenologically successful in the most interesting regions of its parameter space. We also comment on detection prospects at the LHC and elsewhere.

  12. On the phase transition nature in compressible Ising models

    International Nuclear Information System (INIS)

    Ota, A.T.

    1985-01-01

    The phase transition phenomenon is analysed in a compressible ferromagnetic Ising model at null field, through the mean-field approximation. The model studied is d-dimensional under the magnetic point of view and one-dimensional under the elastic point of view. This is achieved keeping the compressive interactions among the ions and rejecting annealing forces completely. The exchange parameter J is linear and the elastic potential quadratic in relation to the microscopic shifts of the lattice. In the one-dimensional case, this model shows no phase transition. In the two-dimensional case, the role of the S i spin of the i-the ion is crucial: a) for spin 1/2 the transitions are of second order; b) for spin 1, desides the second order transitions there is a three-critical point and a first-order transitions line. (L.C.) [pt

  13. Complexity and phase transitions in a holographic QCD model

    Science.gov (United States)

    Zhang, Shao-Jun

    2018-04-01

    Applying the "Complexity = Action" conjecture, we study the holographic complexity close to crossover/phase transition in a holographic QCD model proposed by Gubser et al. This model can realize three types of phase transition, crossover or first and second order, depending on the parameters of the dilaton potential. The re-scaled late-time growth rate of holographic complexity density for the three cases is calculated. Our results show that it experiences a fast drop/jump close to the critical point while approaching constants far beyond the critical temperature. Moreover, close to the critical temperature, it shows a behavior characterizing the type of the transition. These features suggest that the growth rate of the holographic complexity may be used as a good parameter to characterize the phase transition. The Lloyd's bound is always satisfied for the cases we considered but only saturated for the conformal case.

  14. Structural phase transitions and topological defects in ion Coulomb crystals

    Energy Technology Data Exchange (ETDEWEB)

    Partner, Heather L. [Physikalisch-Technische Bundesanstalt, Braunschweig (Germany); Nigmatullin, Ramil [Institute of Quantum Physics, Ulm Univ., Ulm (Germany); Burgermeister, Tobias [Physikalisch-Technische Bundesanstalt, Braunschweig (Germany); Keller, Jonas [Physikalisch-Technische Bundesanstalt, Braunschweig (Germany); Pyka, Karsten [Physikalisch-Technische Bundesanstalt, Braunschweig (Germany); Plenio, Martin B. [Center for Integrated Quantum Science and Technology, Ulm Univ., Ulm, (Germany):Institute for Theoretical Physics, Ulm Univ.,Ulm, (Germany); Retzker, Alex [Racah Institute of Physics, The Hebrew University of Jerusalem, Givat Ram (Israel); Zurek, Wojciech Hubert [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); del Campo, Adolfo [Univ. of Massachusetts, Amherst, MA (United States). Dept. of Physics; Mehlstaubler, Tanja E. [Physikalisch-Technische Bundesanstalt, Braunschweig (Germany)

    2014-11-19

    We use laser-cooled ion Coulomb crystals in the well-controlled environment of a harmonic radiofrequency ion trap to investigate phase transitions and defect formation. Topological defects in ion Coulomb crystals (kinks) have been recently proposed for studies of nonlinear physics with solitons and as carriers of quantum information. Defects form when a symmetry breaking phase transition is crossed non-adiabatically. For a second order phase transition, the Kibble-Zurek mechanism predicts that the formation of these defects follows a power law scaling in the rate of the transition. We demonstrate a scaling of defect density and describe kink dynamics and stability. We further discuss the implementation of mass defects and electric fields as first steps toward controlled kink preparation and manipulation.

  15. The Physics of Phase Transitions Concepts and Applications

    CERN Document Server

    Papon, Pierre; Meijer, Paul H.E

    2006-01-01

    The physics of phase transitions is an important area at the crossroads of several fields that play central roles in materials sciences. In this second edition, new developments had been included which came up in the states of matter physics, in particular in the domain of nanomaterials and atomic Bose-Einstein condensates where progress is accelerating. The presentation of several chapters had been improved by bringing better information on some phase transition mechanisms and by illustrating them with new application examples. This work deals with all classes of phase transitions in fluids and solids. It contains chapters on evaporation, melting, solidification, magnetic transitions, critical phenomena, superconductivity, etc., and is intended for graduate students in physics and engineering; for scientists it will serve both as an introduction and an overview. End-of-chapter problems and complete answers are included.

  16. Phase transitions in nuclear matter and consequences for neutron stars

    International Nuclear Information System (INIS)

    Kaempfer, B.

    1983-04-01

    Estimates of the minimal bombarding energy necessary to reach the quark gluon phase in heavy ion collisions are presented within a hydrodynamical scenario. Further, the consequences of first-order phase transitions from nuclear/neutron matter to pion-condensed matter or quark matter are discussed for neutron stars. (author)

  17. Observation of phase transitions in spreading activation networks.

    Science.gov (United States)

    Shrager, J; Hogg, T; Huberman, B A

    1987-05-29

    Phase transitions, similar to those seen in physical systems, are observed in spreading activation networks. Such networks are used both in theories of cognition and in artificial intelligence applications. This result confirms a predicted abrupt behavioral change as either the topology of the network or the activation parameters are varied across phase boundaries.

  18. Supercooling across first-order phase transitions in vortex matter

    Indian Academy of Sciences (India)

    Abstract. Hysteresis in cycling through first-order phase transitions in vortex matter, akin to the well-studied phenomenon of supercooling of water, has been discussed in literature. Hysteresis can be seen while varying either temperature T or magnetic field H (and thus the density of vortices). Our recent work on phase ...

  19. Commensurate-incommensurate phase transition in the deformed crystal

    International Nuclear Information System (INIS)

    Parlinski, K.; Watanabe, Y.; Ohno, K.; Kawazoe, Y.

    1995-01-01

    Using simple orthorhombic microscopic model the commensurate-incommensurate phase transition has been studied. Coupling of the order parameter with spontaneous strain may lead to process which uses the ferroelastic domain walls to introduce the discommensurations to the incommensurate phase. (author). 4 refs, 1 fig

  20. Phase transitions and topological excitations in hypergauge theories

    International Nuclear Information System (INIS)

    Nencka-Ficek, H.

    1985-01-01

    The problems connected with the phase structure of antisymmetric tensor gauge fields are investigated. (s+1)-dimensional hyperloops cannot be constructed in (s+1)-dimensional lattices. This is the cause of a lack of phase transitions in the U(1) theories with fields being sth-kind gauge invariant in the (s+1)-dimensional lattice

  1. The Physics of Weldpool Formation: Phase Transition Process In ...

    African Journals Online (AJOL)

    ... phase transition took place but did not significantly alter the microstructure of the weldment. This study also supports the claims made by different investigators about the different heat treatments given to metals to determine a particular hardenability level. This heat treatment process is an indicator of phase change.

  2. Non-Fourier heat conduction and phase transition in laser ablation of polytetrafluoroethylene (PTFE)

    Science.gov (United States)

    Zhang, Yu; Zhang, Daixian; Wu, Jianjun; Li, Jian; He, Zhaofu

    2017-11-01

    The phase transition in heat conduction of polytetrafluoroethylene-like polymers was investigated and applied in many fields of science and engineering. Considering more details including internal absorption of laser radiation, reflectivity of material and non-Fourier effect etc., the combined heat conduction and phase transition in laser ablation of polytetrafluoroethylene were modeled and investigated numerically. The thermal and mechanic issues in laser ablation were illustrated and analyzed. Especially, the phenomenon of temperature discontinuity formed in the combined phase transition and non-Fourier heat conduction was discussed. Comparisons of target temperature profiles between Fourier and non-Fourier heat conduction in melting process were implemented. It was indicated that the effect of non-Fourier plays an important role in the temperature evolvement. The effect of laser fluence was proven to be significant and the thermal wave propagation was independent on the laser intensity for the non-Fourier heat conduction. Besides, the effect of absorption coefficients on temperature evolvements was studied. For different ranges of absorption coefficients, different temperature evolvements can be achieved. The above numerical simulation provided insight into physical processes of combined non-Fourier heat conduction and phase transition in laser ablation.

  3. Phase transitions in the urea/n-nonadecane system by calorimetric techniques

    International Nuclear Information System (INIS)

    Lopez-Echarri, A; Ruiz-Larrea, I; Fraile-RodrIguez, A; Diaz-Hernandez, J; Breczewski, T; Bocanegra, E H

    2007-01-01

    A calorimetric study of urea/n-nonadecane, CO(NH 2 ) 2 /C 19 H 40 , and the deuterated derivatives, CO(ND 2 ) 2 /C 19 D 40 and CO(NH 2 ) 2 /C 19 D 40 , around the structural phase transition temperature is presented. For this purpose differential scanning (DSC), temperature-modulated (AC) and adiabatic calorimetry have been used and the obtained results are compared. Leaving apart the noticeable peak associated with the main phase transition at 158.5, 149.4 and 154 K respectively, small anomalies of the specific heat are found at lower temperatures and their corresponding entropic and enthalpic changes are reported. Heating and cooling experiments show the influence of the temperature rate and the thermal history on the detailed profile of the specific heat traces. The presence of thermal hysteresis and latent heat as a way to characterize the order of the phase transitions is discussed. Finally, a tentative approach to the urea and the alkyl chain contributions to the specific heat and their influence on the phase transition mechanisms is presented

  4. THERMAL ENERGY STORAGE PROPERTIES OF FORMSTABLE PARAFFIN/RECYCLE BLOCK CONCRETE COMPOSITE PHASE CHANGE MATERIAL

    Directory of Open Access Journals (Sweden)

    PATTARAPORN SUTTAPHAKDEE

    2017-01-01

    Full Text Available In this research, the form-stable composite phase change material was developed by incorporating paraffin on recycle block concrete (RB through the vacuum impregnation method. The compatibility and thermal properties of RB impregnated with paraffin ranging from 0-35 wt% were characterized by Fourier transform infrared spectroscopy (FTIR and differential scanning calorimetry (DSC. Results revealed that paraffin was uniformly absorbed in RB with a good physical compatibility. The optimum adsorption ratio of paraffin in RB was 25 wt% which produced phase transition temperature of 52.85 OC and latent heat of 30.98 J/g. The obtained form-stable paraffin/RB composite PCM had proper latent heat and phase transition temperature and can be applied for thermal energy storage applications such as solar heating and cooling in buildings.

  5. The crystal structure and the phase transitions of pyridinium trifluoromethanesulfonate

    International Nuclear Information System (INIS)

    Jesariew, Dominik; Ilczyszyn, Maria M; Pietraszko, Adam

    2014-01-01

    The calorimetric and optical studies and the structural properties of pyridinium trifluoromethanesulfonate (abbreviated as PyHOTf) are reported. A sequence of four fully reversible solid–solid phase transitions, at 223.0, 309.0, 359.9 and 394.3 K, has been discovered. The phase transition sequence was confirmed by x-ray diffraction data. The crystal structures of three phases (V, IV and III) have been determined from the single crystal x-ray diffraction data. Structural properties of the high temperature phases are characterized using powder x-ray diffraction data measured in the 290–425 K temperature range. The structural changes triggered by the temperature change are discussed in relation to the phase transitions. Two low temperature phases (V and IV) belong to the P4 3 2 1 2 space group of the tetragonal system. The intermediate phases (III and II) are monoclinic and the prototype high temperature phase (I) is a pseudo-cubic (tetragonal) one. The low temperature phases (V and IV) are well ordered. The crystal structure of intermediate (III and II) and prototype (I) phases are characterized by high disorder of the pyridinium cations and triflate anions. (papers)

  6. Phase transitions in biogenic amorphous calcium carbonate.

    Science.gov (United States)

    Gong, Yutao U T; Killian, Christopher E; Olson, Ian C; Appathurai, Narayana P; Amasino, Audra L; Martin, Michael C; Holt, Liam J; Wilt, Fred H; Gilbert, P U P A

    2012-04-17

    Crystalline biominerals do not resemble faceted crystals. Current explanations for this property involve formation via amorphous phases. Using X-ray absorption near-edge structure (XANES) spectroscopy and photoelectron emission microscopy (PEEM), here we examine forming spicules in embryos of Strongylocentrotus purpuratus sea urchins, and observe a sequence of three mineral phases: hydrated amorphous calcium carbonate (ACC · H(2)O) → dehydrated amorphous calcium carbonate (ACC) → calcite. Unexpectedly, we find ACC · H(2)O-rich nanoparticles that persist after the surrounding mineral has dehydrated and crystallized. Protein matrix components occluded within the mineral must inhibit ACC · H(2)O dehydration. We devised an in vitro, also using XANES-PEEM, assay to identify spicule proteins that may play a role in stabilizing various mineral phases, and found that the most abundant occluded matrix protein in the sea urchin spicules, SM50, stabilizes ACC · H(2)O in vitro.

  7. Theoretical Predictions of Phase Transitions at Ultra-high Pressures

    Science.gov (United States)

    Boates, Brian

    2013-06-01

    We present ab initio calculations of the high-pressure phase diagrams of important planetary materials such as CO2, MgSiO3, and MgO. For CO2, we predict a series of distinct liquid phases over a wide pressure (P) and temperature (T) range, including a first-order transition to a dense polymer liquid. We have computed finite-temperature free energies of liquid and solid CO2 phases to determine the melting curve beyond existing measurements and investigate possible phase separation transitions. The interaction of these phase boundaries with the mantle geotherm will also be discussed. Furthermore, we find evidence for a vast pressure-temperature regime where molten MgSiO3 decomposes into liquid SiO2 and solid MgO, with a volume change of approximately 1.2 percent. The demixing transition is driven by the crystallization of MgO ? the reaction only occurs below the high-pressure MgO melting curve. The predicted transition pressure at 10,000 K is in close proximity to an anomaly reported in recent laser-driven shock experiments of MgSiO3. We also present new results for the high-pressure melting curve of MgO and its B1-B2 solid phase transition, with a triple point near 364 GPa and 12,000 K.

  8. Quantum phase transitions of a disordered antiferromagnetic topological insulator

    Science.gov (United States)

    Baireuther, P.; Edge, J. M.; Fulga, I. C.; Beenakker, C. W. J.; Tworzydło, J.

    2014-01-01

    We study the effect of electrostatic disorder on the conductivity of a three-dimensional antiferromagnetic insulator (a stack of quantum anomalous Hall layers with staggered magnetization). The phase diagram contains regions where the increase of disorder first causes the appearance of surface conduction (via a topological phase transition), followed by the appearance of bulk conduction (via a metal-insulator transition). The conducting surface states are stabilized by an effective time-reversal symmetry that is broken locally by the disorder but restored on long length scales. A simple self-consistent Born approximation reliably locates the boundaries of this so-called "statistical" topological phase.

  9. High pressure structural phase transition of neodymium mono pnictides

    International Nuclear Information System (INIS)

    Pagare, Gitanjali; Ojha, P.; Sanyal, S.P.; Aynyas, Mahendra

    2007-01-01

    We have investigated theoretically the high-pressure structural phase transition of two neodymium mono NdX (X=As, Sb) using an interionic potential theory with necessary modification to include the effect of Coulomb screening by the delocalized f electrons of Nd ion. These compounds exhibits first order crystallographic phase transition from their NaCl (B 1 ) phase to body centered tetragonal (BCT) at 27 GPa and 15.3 GPa respectively. We also calculated the Nd-Nd distance as a function of pressure. (author)

  10. Green material composites from renewable resources: Polymorphic transitions and phase diagram of beeswax/rosin resin

    Energy Technology Data Exchange (ETDEWEB)

    Gaillard, Yves [Mines-ParisTech., CEMEF, UMR CNRS 7635, 1 rue Claude Daunesse 06904 Sophia Antipolis cedex (France); Mija, Alice [University of Nice-Sophia Antipolis, Thermokinetic Group, Laboratory of Chemistry of Organic and Metallic Materials C.M.O.M., 06108 Nice Cedex 2 (France); Burr, Alain; Darque-Ceretti, Evelyne; Felder, Eric [Mines-ParisTech., CEMEF, UMR CNRS 7635, 1 rue Claude Daunesse 06904 Sophia Antipolis cedex (France); Sbirrazzuoli, Nicolas, E-mail: sbirrazz@unice.fr [University of Nice-Sophia Antipolis, Thermokinetic Group, Laboratory of Chemistry of Organic and Metallic Materials C.M.O.M., 06108 Nice Cedex 2 (France)

    2011-07-10

    Highlights: {yields} Blends of Rosin and beeswax are studied by DSC, XRD, and optical microscopy. {yields} The first phase diagram beeswax/rosin is established. {yields} Polymorphic transitions are identified and appear to be highly related to rosin content. - Abstract: Rosin and beeswax are two complex natural materials presenting numerous applications in paints, adhesives, varnishes or inks. Melted, they are particularly interesting for their adhesion properties. This paper establishes the first phase diagram beeswax/rosin blends. A systematic approach using X-ray diffraction (XRD), differential scanning calorimetry (DSC) and polarised optical microscopy (POM) has been performed in order to describe the crystallographic structure and the thermal properties of two materials, beeswax and rosin, and their blends. Indeed, melting, softening and crystallisation temperatures, polymorphic transitions but also crystalline index has been investigated. The resulting phase diagram reveals a complex behaviour in terms of phase transformation and time-dependent phenomenon mainly representative of the complex composition of beeswax.

  11. Shear induced phase transitions induced in edible fats

    Science.gov (United States)

    Mazzanti, Gianfranco; Welch, Sarah E.; Marangoni, Alejandro G.; Sirota, Eric B.; Idziak, Stefan H. J.

    2003-03-01

    The food industry crystallizes fats under different conditions of temperature and shear to obtain products with desired crystalline phases. Milk fat, palm oil, cocoa butter and chocolate were crystallized from the melt in a temperature controlled Couette cell. Synchrotron x-ray diffraction studies were conducted to examine the role of shear on the phase transitions seen in edible fats. The shear forces on the crystals induced acceleration of the alpha to beta-prime phase transition with increasing shear rate in milk fat and palm oil. The increase was slow at low shear rates and became very strong above 360 s-1. In cocoa butter the acceleration between beta-prime-III and beta-V phase transition increased until a maximum of at 360 s-1, and then decreased, showing competition between enhanced heat transfer and viscous heat generation.

  12. Generalized transport model for phase transition with memory

    International Nuclear Information System (INIS)

    Chen, Chi; Ciucci, Francesco

    2013-01-01

    A general model for phenomenological transport in phase transition is derived, which extends Jäckle and Frisch model of phase transition with memory and the Cahn–Hilliard model. In addition to including interfacial energy to account for the presence of interfaces, we introduce viscosity and relaxation contributions, which result from incorporating memory effect into the driving potential. Our simulation results show that even without interfacial energy term, the viscous term can lead to transient diffuse interfaces. From the phase transition induced hysteresis, we discover different energy dissipation mechanism for the interfacial energy and the viscosity effect. In addition, by combining viscosity and interfacial energy, we find that if the former dominates, then the concentration difference across the phase boundary is reduced; conversely, if the interfacial energy is greater then this difference is enlarged.

  13. Magnetism and Microstructure Characterization of Phase Transitions in a Steel

    Directory of Open Access Journals (Sweden)

    M. Güler

    2014-01-01

    Full Text Available We present phase transitions in a low carbon steel according to existing phases and their magnetism. Scanning electron microscope employed research to clarify and evaluate the microstructural details. Additionally, we utilized from Mössbauer spectroscopy for magnetic characteristics of different existed phases. Scanning electron microscope examinations showed that the pure state of the steel was fully in the ferrite phase with equiaxed grains. Moreover, subsequent heat treatments on the studied steel also ensured the first austenite and then pearlite phase formation. Mössbauer spectroscopy of these phases appeared as a paramagnetic single-line absorption peak for the austenite phase and ferromagnetic six-line spectra for both ferrite and pearlite phases. From Mössbauer data, we determined that the internal magnetic fields of ferrite and pearlite phases were as 32.2 Tesla and 31.3 Tesla, respectively.

  14. Shape change as entropic phase transition: A study using Jarzynski ...

    Indian Academy of Sciences (India)

    Abstract. A Brownian particle in a confined space with varying cross-section, experiences an effective entropic potential in reduced dimension. We modulate the shape of the confinement and examine the nature of dynamical transition between two distinct thermalized entropic states corresponding to different shapes of the.

  15. Monte Carlo simulations of phase transitions and lattice dynamics in an atom-phonon model for spin transition compounds

    International Nuclear Information System (INIS)

    Apetrei, Alin Marian; Enachescu, Cristian; Tanasa, Radu; Stoleriu, Laurentiu; Stancu, Alexandru

    2010-01-01

    We apply here the Monte Carlo Metropolis method to a known atom-phonon coupling model for 1D spin transition compounds (STC). These inorganic molecular systems can switch under thermal or optical excitation, between two states in thermodynamical competition, i.e. high spin (HS) and low spin (LS). In the model, the ST units (molecules) are linked by springs, whose elastic constants depend on the spin states of the neighboring atoms, and can only have three possible values. Several previous analytical papers considered a unique average value for the elastic constants (mean-field approximation) and obtained phase diagrams and thermal hysteresis loops. Recently, Monte Carlo simulation papers, taking into account all three values of the elastic constants, obtained thermal hysteresis loops, but no phase diagrams. Employing Monte Carlo simulation, in this work we obtain the phase diagram at T=0 K, which is fully consistent with earlier analytical work; however it is more complex. The main difference is the existence of two supplementary critical curves that mark a hysteresis zone in the phase diagram. This explains the pressure hysteresis curves at low temperature observed experimentally and predicts a 'chemical' hysteresis in STC at very low temperatures. The formation and the dynamics of the domains are also discussed.

  16. Effects of single particle on shape phase transitions and phase coexistence in odd-even nuclei

    Science.gov (United States)

    Yu, Xiang-Ru; Hu, Jing; Li, Xiao-Xue; An, Si-Yu; Zhang, Yu

    2018-02-01

    A classical analysis of shape phase transitions and phase coexistence in odd-even nuclei has been performed in the framework of the interacting boson-fermion model. The results indicate that the effects of a single particle may influence different types of transitions in different ways. Especially, it is revealed that phase coexistence can clearly emerge in the critical region and thus be taken as a indicator of the shape phase transitions in odd-even nuclei. Supported by National Natural Science Foundation of China (11375005)

  17. Phase transitions: the lattice QCD approach

    International Nuclear Information System (INIS)

    Gavai, R.V.

    1986-01-01

    Recent results in the field of finite temperature lattice quantum chromodynamics (QCD) are presented with special emphasis on comparison of the different methods used to incorporate the dynamical fermions. Attempts to obtain a nonperturbative estimate of the velocity of sound in both the hadronic and quark-gluon phase are summarized along with the results. 15 refs., 7 figs

  18. Kinetics of silica-phase transitions

    Energy Technology Data Exchange (ETDEWEB)

    Duffy, C.J.

    1993-07-01

    In addition to the stable silica polymorph quartz, several metastable silica phases are present in Yucca Mountain. The conversion of these phases to quartz is accompanied by volume reduction and a decrease in the aqueous silica activity, which may destabilize clinoptilolite and mordenite. The primary reaction sequence for the silica phases is from opal or glass to disordered opal-CT, followed by ordering of the opal-CT and finally by the crystallization of quartz. The ordering of opal-CT takes place in the solid state, whereas the conversion of opal-CT takes place through dissolution-reprecipitation involving the aqueous phase. It is proposed that the rate of conversion of opal-CT to quartz is controlled by diffusion of defects out of a disordered surface layer formed on the crystallizing quartz. The reaction rates are observed to be dependent on temperature, pressure, degree of supersaturation, and pH. Rate equations selected from the literature appear to be consistent with observations at Yucca Mountain.

  19. Integrated thermal treatment system sudy: Phase 2, Results

    Energy Technology Data Exchange (ETDEWEB)

    Feizollahi, F.; Quapp, W.J.

    1995-08-01

    This report presents the second phase of a study on thermal treatment technologies. The study consists of a systematic assessment of nineteen thermal treatment alternatives for the contact-handled mixed low-level waste (MLLW) currently stored in the US Department of Energy complex. The treatment alternatives consist of widely varying technologies for safely destroying the hazardous organic components, reducing the volume, and preparing for final disposal of the MLLW. The alternatives considered in Phase 2 were innovative thermal treatments with nine types of primary processing units. Other variations in the study examined the effect of combustion gas, air pollution control system design, and stabilization technology for the treatment residues. The Phase 1 study, the results of which have been published as an interim report, examined ten initial thermal treatment alternatives. The Phase 2 systems were evaluated in essentially the same manner as the Phase 2 systems. The assumptions and methods were the same as for the Phase 1 study. The quantities, and physical and chemical compositions, of the input waste used in he Phase 2 systems differ from those in the Phase 1 systems, which were based on a preliminary waste input database developed at the onset of the Integrated Thermal Treatment System study. The inventory database used in the Phase 2 study incorporates the latest US Department of Energy information. All systems, both primary treatment systems and subsystem inputs, have now been evaluated using the same waste input (2,927 lb/hr).

  20. Integrated thermal treatment system sudy: Phase 2, Results

    International Nuclear Information System (INIS)

    Feizollahi, F.; Quapp, W.J.

    1995-08-01

    This report presents the second phase of a study on thermal treatment technologies. The study consists of a systematic assessment of nineteen thermal treatment alternatives for the contact-handled mixed low-level waste (MLLW) currently stored in the US Department of Energy complex. The treatment alternatives consist of widely varying technologies for safely destroying the hazardous organic components, reducing the volume, and preparing for final disposal of the MLLW. The alternatives considered in Phase 2 were innovative thermal treatments with nine types of primary processing units. Other variations in the study examined the effect of combustion gas, air pollution control system design, and stabilization technology for the treatment residues. The Phase 1 study, the results of which have been published as an interim report, examined ten initial thermal treatment alternatives. The Phase 2 systems were evaluated in essentially the same manner as the Phase 2 systems. The assumptions and methods were the same as for the Phase 1 study. The quantities, and physical and chemical compositions, of the input waste used in he Phase 2 systems differ from those in the Phase 1 systems, which were based on a preliminary waste input database developed at the onset of the Integrated Thermal Treatment System study. The inventory database used in the Phase 2 study incorporates the latest US Department of Energy information. All systems, both primary treatment systems and subsystem inputs, have now been evaluated using the same waste input (2,927 lb/hr)

  1. Crystal structures, phase relationships, and magnetic phase transitions of R5M4 compounds (R = rare earths, M = Si, Ge)

    Science.gov (United States)

    Ouyang, Zhong-Wen; Rao, Guang-Hui

    2013-09-01

    Our recent studies of the crystal structures, phase transitions, and magnetic properties of intermetallic compounds R5M4 (R = rare earths; M = Si, Ge) are reviewed briefly. First, crystal structures, phase relationships, and magnetic properties of several 5:4 compounds, including Nd5Si4-xGex, Pr5Si4-xGex, Gd5-xLaxGe4, La5Si4, and Gd5Sn4, are presented. In particular, the canted spin structures as well as the magnetic phase transitions in Pr5Si2Ge2 and Pr5Ge4 investigated by neutron powder diffractions and small-angle neutron scattering are reviewed. Second, the crystal structures and magnetic properties of the most studied compounds Gd5(Si,Ge)4 are summarized. The focus is on the parent compound Gd5Ge4, which is an amazing material exhibiting magnetic anisotropy, angular dependent spin-flop transition, metastable magnetic response, Griffiths-like phase, thermal effect under pulsed fields, antiferromagnetic and ferromagnetic resonances, pronounced effects of impurities, and high-field induced magnetic transitions.

  2. Aluminum-centered tetrahedron-octahedron transition in advancing Al-Sb-Te phase change properties.

    Science.gov (United States)

    Xia, Mengjiao; Ding, Keyuan; Rao, Feng; Li, Xianbin; Wu, Liangcai; Song, Zhitang

    2015-02-24

    Group IIIA elements, Al, Ga, or In, etc., doped Sb-Te materials have proven good phase change properties, especially the superior data retention ability over popular Ge2Sb2Te5, while their phase transition mechanisms are rarely investigated. In this paper, aiming at the phase transition of Al-Sb-Te materials, we reveal a dominant rule of local structure changes around the Al atoms based on ab initio simulations and nuclear magnetic resonance evidences. By comparing the local chemical environments around Al atoms in respective amorphous and crystalline Al-Sb-Te phases, we believe that Al-centered motifs undergo reversible tetrahedron-octahedron reconfigurations in phase transition process. Such Al-centered local structure rearrangements significantly enhance thermal stability of amorphous phase compared to that of undoped Sb-Te materials, and facilitate a low-energy amorphization due to the weak links among Al-centered and Sb-centered octahedrons. Our studies may provide a useful reference to further understand the underlying physics and optimize performances of all IIIA metal doped Sb-Te phase change materials, prompting the development of NOR/NAND Flash-like phase change memory technology.

  3. interThermalPhaseChangeFoam—A framework for two-phase flow simulations with thermally driven phase change

    Directory of Open Access Journals (Sweden)

    Mahdi Nabil

    2016-01-01

    Full Text Available The volume-of-fluid (VOF approach is a mature technique for simulating two-phase flows. However, VOF simulation of phase-change heat transfer is still in its infancy. Multiple closure formulations have been proposed in the literature, each suited to different applications. While these have enabled significant research advances, few implementations are publicly available, actively maintained, or inter-operable. Here, a VOF solver is presented (interThermalPhaseChangeFoam, which incorporates an extensible framework for phase-change heat transfer modeling, enabling simulation of diverse phenomena in a single environment. The solver employs object oriented OpenFOAM library features, including Run-Time-Type-Identification to enable rapid implementation and run-time selection of phase change and surface tension force models. The solver is packaged with multiple phase change and surface tension closure models, adapted and refined from earlier studies. This code has previously been applied to study wavy film condensation, Taylor flow evaporation, nucleate boiling, and dropwise condensation. Tutorial cases are provided for simulation of horizontal film condensation, smooth and wavy falling film condensation, nucleate boiling, and bubble condensation. Validation and grid sensitivity studies, interfacial transport models, effects of spurious currents from surface tension models, effects of artificial heat transfer due to numerical factors, and parallel scaling performance are described in detail in the Supplemental Material (see Appendix A. By incorporating the framework and demonstration cases into a single environment, users can rapidly apply the solver to study phase-change processes of interest.

  4. Deconfinement phase transition in the Hamiltonian approach to Yang–Mills theory in Coulomb gauge

    Directory of Open Access Journals (Sweden)

    Reinhardt H.

    2014-04-01

    Full Text Available Recent results obtained for the deconfinement phase transition within the Hamiltonian approach to Yang–Mills theory are reviewed. Assuming a quasiparticle picture for the grand canonical gluon ensemble the thermal equilibrium state is found by minimizing the free energy with respect to the quasi-gluon energy. The deconfinement phase transition is accompanied by a drastic change of the infrared exponents of the ghost and gluon propagators. Above the phase transition the ghost form factor remains infrared divergent but its infrared exponent is approximately halved. The gluon energy being infrared divergent in the confined phase becomes infrared finite in the deconfined phase. Furthermore, the effective potential of the order parameter for confinement is calculated for SU(N Yang–Mills theory in the Hamiltonian approach by compactifying one spatial dimension and using a background gauge fixing. In the simplest truncation, neglecting the ghost and using the ultraviolet form of the gluon energy, we recover the Weiss potential. From the full non-perturbative potential (with the ghost included we extract a critical temperature of the deconfinement phase transition of 269 MeV for the gauge group SU(2 and 283 MeV for SU(3.

  5. Low temperature thermal diffusivity of LiKSO4 obtained using the photoacoustic phase lag method

    Directory of Open Access Journals (Sweden)

    Jorge M.P.P.M.

    1999-01-01

    Full Text Available This paper describes the determination of the thermal diffusivity of LiKSO4 crystals using the photoacoustic phase lag method, in the 77 K to 300 K temperature interval. This method is quite simple and fast and when it is coupled to a specially designed apparatus, that includes a resonant photoacoustic cell, allows for the determination of the thermal diffusivity at low temperatures. The thermal diffusivity is an important parameter that depends on the temperature, and no values of this parameter for LiKSO4, at low temperature, have yet been reported. The LiKSO4 is a crystal with many phase transitions which can be detected via the anomalies in the variation of the thermal diffusivity as a function of the temperature.

  6. Quick Spacecraft Thermal Analysis Tool, Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — For spacecraft design and development teams concerned with cost and schedule, the Quick Spacecraft Thermal Analysis Tool (QuickSTAT) is an innovative software suite...

  7. Lightweight Thermal Storage Heat Exchangers, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — This SBIR proposal aims to develop thermal energy storage heat exchangers that are significantly lighter and higher conductance than the present art which involves...

  8. Non-thermal soot denuder, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose to develop a non-thermal soot denuder for measuring chemical components of the nucleation mode particulate matter emissions from gas turbine engines, in...

  9. Variable Surface Area Thermal Radiator, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — Due to increased complexity of spacecraft and longer expected life, more sophisticated and complex thermal management schemes are needed that will be capable of...

  10. Alternate Propellant Thermal Rocket, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — The Alternate Propellant Thermal Rocket (APTR) is a novel concept for propulsion of space exploration or orbit transfer vehicles. APTR propulsion is provided by...

  11. Advanced Spacecraft Thermal Modeling, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — For spacecraft developers who spend millions to billions of dollars per unit and require 3 to 7 years to deploy, the LoadPath reduced-order (RO) modeling thermal...

  12. Study of the phase transition dynamics of the L to H transition

    International Nuclear Information System (INIS)

    Moyer, R.A.; Rhodes, T.L.; Rettig, C.L.

    1997-12-01

    A highly radiating zone (MARFE) just above the divertor X-point has been used to access the marginal transition regime P sep ∼ P thres to study the existence of a critical point for the L to H transition. Phase transition models predict that at the critical point, the transition duration increases and the plasma parameters vary continuously between L-mode and H-mode. In these experiments, the L to H transition duration increased 50--100 times over fast transitions. However, the evolution of E r shear, edge density gradient, H-mode pedestal, and fluctuations is essentially unchanged from that in fast transitions. The only difference is in the speed with which and the degree to which the fluctuation amplitudes are transiently reduced. This difference is understandable in terms of the time scales for fluctuation amplitude reduction (≤ 100 micros) and edge pressure gradient increase (several ms), provided the edge fluctuations are pressure-gradient driven

  13. Quantum Phase Transition and Entanglement in Topological Quantum Wires.

    Science.gov (United States)

    Cho, Jaeyoon; Kim, Kun Woo

    2017-06-05

    We investigate the quantum phase transition of the Su-Schrieffer-Heeger (SSH) model by inspecting the two-site entanglements in the ground state. It is shown that the topological phase transition of the SSH model is signified by a nonanalyticity of local entanglement, which becomes discontinuous for finite even system sizes, and that this nonanalyticity has a topological origin. Such a peculiar singularity has a universal nature in one-dimensional topological phase transitions of noninteracting fermions. We make this clearer by pointing out that an analogous quantity in the Kitaev chain exhibiting the identical nonanalyticity is the local electron density. As a byproduct, we show that there exists a different type of phase transition, whereby the pattern of the two-site entanglements undergoes a sudden change. This transition is characterised solely by quantum information theory and does not accompany the closure of the spectral gap. We analyse the scaling behaviours of the entanglement in the vicinities of the transition points.

  14. Continuous solid-state phase transitions in energy storage materials with orientational disorder – Computational and experimental approach

    International Nuclear Information System (INIS)

    Singh, Harpreet; Talekar, Anjali; Chien, Wen-Ming; Shi, Renhai; Chandra, Dhanesh; Mishra, Amrita; Tirumala, Muralidhar; Nelson, Daryl J.

    2015-01-01

    We report on TES (thermal energy storage) in new CT (continuous phase transitions) in multicomponent tetrahederally configured (orientationally disordered) crystals of NPG-neopentylglycol-C 5 H 12 O 2 , PG-pentaglycerine-C 5 H 12 O 3 , and PE-pentaerythritol-C 5 H 12 O 4 . This discovery is applicable in thermal energy storage in many systems which do not require conventional isothermal first-order phase transition energy storage. The above compounds exhibit polymorphs of orientationally disordered phases in which O–H…O bond rotation around the C–C bond stores significant amount of energy; for example, in PE 41.26 kJ/mol are absorbed isothermally during solid–solid transitions. In this paper we show, anisothermal continuous phase transitions (CT), due to compositional changes with changes in temperature, associated with a measurable amount of energy, not reported earlier. The correlation of phase stability regions in pseudo-binaries, calculated from ternary NPG–PG–PE phase diagrams, is validated by experimental ternary DSC (differential scanning calorimetry) and in-situ x-ray diffraction data. We established equations for determining the CT in a temperature range, and their respective enthalpies of transitions for any composition of the ternaries. Thermodynamic calculations of the Gibbs energies of the solution phases are modeled as substitutional solid solutions, in which the excess Gibbs energies are expressed by the Redlich–Kister–Muggianu polynomial. There is excellent agreement between the experimental and CALPHAD calculated data. - Highlights: • Continuous phase transition (CT) thermal energy storage in organic ternary system. • Anisothermal temperature ramping leads to CT transitions as per lever rule. • Orientationally disordered phases store energy in O–H…O bond rotation/oscillation. • Validated calculated data with measured thermodynamic properties in ternary system. • Used CALPHAD methodology to calculate Gibbs energies of

  15. Enthalpy of phase transition and prediction of phase Equilibria in systems of glycols and glycol ethers

    OpenAIRE

    Esina, Zoya; Miroshnikov, Aleksandr; Korchuganova, Margarita

    2014-01-01

    The PCEAS model was used to study the liquid-solid and liquid-vapor phase transitions at constant pressure in systems containing glycols and glycol ethers. This method is based on minimizing the excess Gibbs energy over the solvation parameter, which takes into account the processes of association of molecules in various phases. To compute the diagrams, the data on enthalpy and phase transition temperatures of pure components are required, while the information about the interactions in the b...

  16. Phase Equilibria in the Bi-In-Sn-Zn System. Thermal Analysis vs. Calculations

    Directory of Open Access Journals (Sweden)

    Dębski A.

    2017-12-01

    Full Text Available With the use of the differential thermal analysis (DTA, studies of the phase transitions were conducted for 90 of alloys from the quaternary Bi-In-Sn-Zn system and for the constant ratio of Bi:In and Bi:Sn. The studies were conducted for the alloys prepared from the purity metals (Bi, In, Sn, Zn = 99.999 mas. % by way of melting in a graphite crucible in a glove-box filled with Ar, in which the impurities level was less than 0.1 ppm. After melting and thorough mixing, the liquid alloys were poured out into a graphite test mold. The phase transition temperature data obtained from the DTA investigations were next confronted with those determined from the calculations based on the binary and ternary optimized thermodynamic parameters available in the literature. It was found that the experimental and the calculated phase transition temperatures were in good agreement.

  17. Thermal Performance of Microencapsulated Phase Change Material Survey

    National Research Council Canada - National Science Library

    Alvarado, Jorge L; Jones, Barclay G; Marsh, Charles P; Kessler, David A; Sohn, Chang W; Feickert, Carl A; Phetteplace, Gary E; Crowley, Eric D; Franks, Ryan J; Carlson, Thomas A

    2008-01-01

    ...). Because PCMs have greater thermal capacity than the carrier fluid, owing to their latent heat of phase change, they can increase the amount of heat transfer at equivalent volumetric flow in a heat...

  18. Thermal effects in quantum phase-space distributions

    International Nuclear Information System (INIS)

    Pennini, F.; Plastino, A.

    2010-01-01

    Thermal properties derived from quantal phase-space distributions are studied with a view to compare first order in h effects to second order ones. The discussion is given in information theoretic terms.

  19. High Temperature Fiberoptic Thermal Imaging System, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — The proposed Phase 1 program will fabricate and demonstrate a small diameter single fiber endoscope that can perform high temperature thermal imaging in a jet engine...

  20. New data on the phase transition in SrAlF5

    International Nuclear Information System (INIS)

    Bondarev, V. S.; Vasil’ev, A. D.; Gorev, M. V.; Mel’nikova, S. V.; Isaenko, L. I.

    2011-01-01

    The thermophysical characteristics of the SrAlF 5 crystal have been investigated on samples differing in quality. The results of studying the thermal expansion and birefringence in heating-cooling cycles in the temperature range of 100–800 K have been analyzed. Specific heat anomalies are found whose position on the temperature scale depends on the sample quality and thermal history. An X-ray diffraction analysis of SrAlF 5 showed the absence of structural phase transitions in the temperature range under study. It is suggested that the specific heat anomalies are related to the peculiarity of transport properties of this crystal.

  1. Crystal structure and phase transitions in perovskite-like C(NH2)(3)SnCl3

    DEFF Research Database (Denmark)

    Szafranski, M.; Ståhl, Kenny

    2007-01-01

    X-ray single-crystal diffraction, high-temperature powder diffraction and differential thermal analysis at ambient and high pressure have been employed to study the crystal structure and phase transitions of guanidinium trichlorostannate, C(NH2)(3)SnCl3. At 295 K the crystal structure is orthorho......X-ray single-crystal diffraction, high-temperature powder diffraction and differential thermal analysis at ambient and high pressure have been employed to study the crystal structure and phase transitions of guanidinium trichlorostannate, C(NH2)(3)SnCl3. At 295 K the crystal structure...

  2. Uncatalyzed thermal gas phase aziridination of alkenes by organic ...

    Indian Academy of Sciences (India)

    Alkene aziridination by azides through uncatalyzed thermal gas phase routes has been studiedusing the DFT B3LYP/6-31G(d,p) method, where the possible role of discrete nitrene intermediates is emphasized.The thermal decomposition of azides is studied using the MP2/aug-cc-pVDZ strategy as well. The MP2(but not the ...

  3. Antiferrodistortive phase transitions and ground state of PZT ceramics

    International Nuclear Information System (INIS)

    Pandey, Dhananjai

    2013-01-01

    The ground state of the technologically important Pb(Zr x Ti (1-x) )O 3 , commonly known as PZT, ceramics is currently under intense debate. The phase diagram of this material shows a morphotropic phase boundary (MPB) for x∼0.52 at 300K, across which a composition induced structural phase transition occurs leading to maximization of the piezoelectric properties. In search for the true ground state of the PZT in the MPB region, Beatrix Noheda and coworkers first discovered a phase transition from tetragonal (space group P4mm) to an M A type monoclinic phase (space group Cm) at low temperatures for x=0.52. Soon afterwards, we discovered yet another low temperature phase transition for the same composition in which the M A type (Cm) monoclinic phase transforms to another monoclinic phase with Cc space group. We have shown that the Cm to Cc phase transition is an antiferrodistortive (AFD) transition involving tilting of oxygen octahedra leading to unit cell doubling and causing appearance of superlattice reflections which are observable in the electron and neutron diffraction patterns only and not in the XRD patterns, as a result of which Noheda and coworkers missed the Cc phase in their synchrotron XRD studies at low temperatures. Our findings were confirmed by leading groups using neutron, TEM, Raman and high pressure diffraction studies. The first principles calculations also confirmed that the true ground state of PZT in the MPB region has Cc space group. However, in the last couple of years, the Cc space group of the ground state has become controversial with an alternative proposal of R3c as the space group of the ground state phase which is proposed to coexist with the metastable Cm phase. In order to resolve this controversy, we recently revisited the issue using pure PZT and 6% Sr 2+ substituted PZT, the latter samples show larger tilt angle on account of the reduction in the average cationic radius at the Pb 2+ site. Using high wavelength neutrons and high

  4. A new phase transition phenomenon in gallium-lanthanide binary alloys

    International Nuclear Information System (INIS)

    Kimmel, G.; Kaplan, W.D.

    1991-01-01

    The existence of an enthalpy gap during heating or cooling indicates a first order phase transition. The difference in entropy can be directly found from the enthalpy change and the transition temperature. The increase in entropy in heating is linked to the type of phase transformation; for melting (solid-liquid transformations) it is roughly an order of magnitude greater than in solid-solid first order transformations. The observation of unusually large enthalpy gaps received as endothermic peaks in differential thermal analyses (DTA) of Lanthanides-Gallium without any known first order phase transition called our attention to this phenomenon. The regime of the phenomenon is limited to gallium alloyed by light Lanthanides (La-Gd) in atomic concentration from 66 to 80 atomic percent Ga. a common feature of these alloys is the unique Pair Wise Substitution (PWS) effect, where Lanthanide atoms are replaced by Ga-Ga pairs. This is due to the tendency of gallium to bond in pairs. Hence, a single formula R 1-x Ga 2+2x (0 ≤ x ≤ 0.333) is used to define the alloys or compounds in these systems. In this paper, the authors deduce from their experiments that this transition is related solely to the sub-unit cell configuration of Ga-Ga pairs, and is a new phase transition phenomenon

  5. Phase-Change Thermal Energy Storage

    Science.gov (United States)

    1989-11-01

    The goal of this program is to advance the engineering and scientific understanding of solar thermal technology and to establish the technology base from which private industry can develop solar thermal power production options for introduction into the competitive energy market. Solar thermal technology concentrates the solar flux using tracking mirrors or lenses onto a receiver where the solar energy is absorbed as heat and converted into electricity or incorporated into products as process heat. The two primary solar thermal technologies, central receivers and distributed receivers, employ various point and line-focus optics to concentrate sunlight. Current central receiver systems use fields of heliostats (two-axes tracking mirrors) to focus the sun's radiant energy onto a single, tower-mounted receiver. Point focus concentrators up to 17 meters in diameter track the sun in two axes and use parabolic dish mirrors or Fresnel lenses to focus radiant energy onto a receiver. Troughs and bowls are line-focus tracking reflectors that concentrate sunlight onto receiver tubes along their focal lines. Concentrating collector modules can be used alone or in a multimodule system. The concentrated radiant energy absorbed by the solar thermal receiver is transported to the conversion process by a circulating working fluid. Receiver temperatures range from 100 C in low-temperature troughs to over 1500 C in dish and central receiver systems.

  6. Topological phases and phase transitions in magnets and ice

    NARCIS (Netherlands)

    Keesman, R.

    2017-01-01

    The main focus of this Thesis is the behaviour of two-dimensional materials, namely (anti)-ferromagnetic materials in the first two chapters, which show topological phases, and energetic square ice in the third and fourth chapter. The magnetic materials are of interest in part due to foreseen

  7. Experimental First Order Pairing Phase Transition in Atomic Nuclei

    International Nuclear Information System (INIS)

    Moretto, L G; Larsen, A C; Giacoppo, F; Guttormsen, M; Siem, S

    2015-01-01

    The natural log of experimental nuclear level densities at low energy is linear with energy. This can be interpreted in terms of a nearly 1st order phase transition from a superfluid to an ideal gas of quasi particles. The transition temperature coincides with the BCS critical temperature and yields gap parameters in good agreement with the values extracted from even- odd mass differences from rotational states. This converging evidence supports the relevance of the BCS theory to atomic nuclei

  8. Gravitational radiation from first-order phase transitions

    International Nuclear Information System (INIS)

    Child, Hillary L.; Giblin, John T. Jr.

    2012-01-01

    It is believed that first-order phase transitions at or around the GUT scale will produce high-frequency gravitational radiation. This radiation is a consequence of the collisions and coalescence of multiple bubbles during the transition. We employ high-resolution lattice simulations to numerically evolve a system of bubbles using only scalar fields, track the anisotropic stress during the process and evolve the metric perturbations associated with gravitational radiation. Although the radiation produced during the bubble collisions has previously been estimated, we find that the coalescence phase enhances this radiation even in the absence of a coupled fluid or turbulence. We comment on how these simulations scale and propose that the same enhancement should be found at the Electroweak scale; this modification should make direct detection of a first-order electroweak phase transition easier

  9. Chirality Quantum Phase Transition in Noncommutative Dirac Oscillator

    International Nuclear Information System (INIS)

    Wang Shao-Hua; Hou Yu-Long; Jing Jian; Wang Qing; Long Zheng-Wen

    2014-01-01

    The charged Dirac oscillator on a noncommutative plane coupling to a uniform perpendicular magnetic held is studied in this paper. We map the noncommutative plane to a commutative one by means of Bopp shift and study this problem on the commutative plane. We find that this model can be mapped onto a quantum optics model which contains Anti—Jaynes—Cummings (AJC) or Jaynes—Cummings (JC) interactions when a dimensionless parameter ζ (which is the function of the intensity of the magnetic held) takes values in different regimes. Furthermore, this model behaves as experiencing a chirality quantum phase transition when the dimensionless parameter ζ approaches the critical point. Several evidences of the chirality quantum phase transition are presented. We also study the non-relativistic limit of this model and find that a similar chirality quantum phase transition takes place in its non-relativistic limit. (physics of elementary particles and fields)

  10. Novel phase transitions in B-site doped manganites

    Energy Technology Data Exchange (ETDEWEB)

    Popovic, Z.V. [Institute of Physics, P.O. Box 68, 11080 Belgrade/Zemun (Serbia and Montenegro)]. E-mail: zoran.popovic@phy.bg.ac.yu; Cantarero, A. [Materials Science Institute, University of Valencia, P.O. Box 22085, 46071 Valencia (Spain); Thijssen, W.H.A. [Kamerlingh Onnes Laboratorium, Leiden University, Postbus 9504, 2300 RA Leiden (Netherlands); Paunovic, N. [Institute of Physics, P.O. Box 68, 11080 Belgrade/Zemun (Serbia and Montenegro); Dohcevic-Mitrovic, Z. [Institute of Physics, P.O. Box 68, 11080 Belgrade/Zemun (Serbia and Montenegro); Sapina, F. [Materials Science Institute, University of Valencia, P.O. Box 22085, 46071 Valencia (Spain)

    2005-04-30

    We have examined the infrared reflectivity and the electrical resistivity of La{sub 1-} {sub x} [Sr(Ba)] {sub x} Mn{sub 1-} {sub z} [Cu(Zn)] {sub z} O{sub 3} samples in ferromagnetic metallic and insulator regime. Several phase transitions are observed, the most obvious being the transition from a ferromagnetic metallic to a ferromagnetic insulator phase that is related to the formation of short-range orbitally ordered domains. The temperature T {sub 1} of the phase transition is dependent on doping concentration and for optimally doped samples ({approx}32% of Mn{sup 4+} ions) we have found T {sub 1}{approx}0.93 T {sub C}.

  11. Non-equilibrium physics at a holographic chiral phase transition

    International Nuclear Information System (INIS)

    Evans, Nick; Kim, Keun-young; Kalaydzhyan, Tigran; Kirsch, Ingo

    2010-11-01

    The D3/D7 system holographically describes an N=2 gauge theory which spontaneously breaks a chiral symmetry by the formation of a quark condensate in the presence of a magnetic field. At finite temperature it displays a first order phase transition. We study out of equilibrium dynamics associated with this transition by placing probe D7 branes in a geometry describing a boost-invariant expanding or contracting plasma. We use an adiabatic approximation to track the evolution of the quark condensate in a heated system and reproduce the phase structure expected from equilibrium dynamics. We then study solutions of the full partial differential equation that describes the evolution of out of equilibrium configurations to provide a complete description of the phase transition including describing aspects of bubble formation. (orig.)

  12. Non-equilibrium physics at a holographic chiral phase transition

    Energy Technology Data Exchange (ETDEWEB)

    Evans, Nick; Kim, Keun-young [Southampton Univ. (United Kingdom). School of Physics and Astronomy; Kavli Institute for Theoretical Physics China, Beijing (China); Kalaydzhyan, Tigran; Kirsch, Ingo [Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany)

    2010-11-15

    The D3/D7 system holographically describes an N=2 gauge theory which spontaneously breaks a chiral symmetry by the formation of a quark condensate in the presence of a magnetic field. At finite temperature it displays a first order phase transition. We study out of equilibrium dynamics associated with this transition by placing probe D7 branes in a geometry describing a boost-invariant expanding or contracting plasma. We use an adiabatic approximation to track the evolution of the quark condensate in a heated system and reproduce the phase structure expected from equilibrium dynamics. We then study solutions of the full partial differential equation that describes the evolution of out of equilibrium configurations to provide a complete description of the phase transition including describing aspects of bubble formation. (orig.)

  13. Phase-transition-like behaviour of quantum games

    CERN Document Server

    Du Jiang Feng; Xu Xiao Dong; Zhou Xian Yi; Han Rong Dian

    2003-01-01

    The discontinuous dependence of the properties of a quantum game on its entanglement has been shown to be very much like phase transitions viewed in the entanglement-payoff diagram (J Du et al 2002 Phys. Rev. Lett. 88 137902). In this paper we investigate such phase-transition-like behaviour of quantum games, by suggesting a method which would help to illuminate the origin of such a kind of behaviour. For the particular case of the generalized Prisoners' Dilemma, we find that, for different settings of the numerical values in the payoff table, even though the classical game behaves the same, the quantum game exhibits different and interesting phase-transition-like behaviour.

  14. Phase-transition-like behaviour of quantum games

    International Nuclear Information System (INIS)

    Du Jiangfeng; Li Hui; Xu Xiaodong; Zhou Xianyi; Han Rongdian

    2003-01-01

    The discontinuous dependence of the properties of a quantum game on its entanglement has been shown to be very much like phase transitions viewed in the entanglement-payoff diagram (J Du et al 2002 Phys. Rev. Lett. 88 137902). In this paper we investigate such phase-transition-like behaviour of quantum games, by suggesting a method which would help to illuminate the origin of such a kind of behaviour. For the particular case of the generalized Prisoners' Dilemma, we find that, for different settings of the numerical values in the payoff table, even though the classical game behaves the same, the quantum game exhibits different and interesting phase-transition-like behaviour

  15. Gravitational radiation from first-order phase transitions

    Energy Technology Data Exchange (ETDEWEB)

    Child, Hillary L.; Giblin, John T. Jr., E-mail: childh@kenyon.edu, E-mail: giblinj@kenyon.edu [Department of Physics, Kenyon College, 201 North College Road, Gambier, OH 43022 (United States)

    2012-10-01

    It is believed that first-order phase transitions at or around the GUT scale will produce high-frequency gravitational radiation. This radiation is a consequence of the collisions and coalescence of multiple bubbles during the transition. We employ high-resolution lattice simulations to numerically evolve a system of bubbles using only scalar fields, track the anisotropic stress during the process and evolve the metric perturbations associated with gravitational radiation. Although the radiation produced during the bubble collisions has previously been estimated, we find that the coalescence phase enhances this radiation even in the absence of a coupled fluid or turbulence. We comment on how these simulations scale and propose that the same enhancement should be found at the Electroweak scale; this modification should make direct detection of a first-order electroweak phase transition easier.

  16. Phase-transition-like behaviour of quantum games

    Energy Technology Data Exchange (ETDEWEB)

    Du Jiangfeng [Department of Modern Physics, University of Science and Technology of China, Hefei, 230027 (China); Li Hui [Department of Modern Physics, University of Science and Technology of China, Hefei, 230027 (China); Xu Xiaodong [Harrison M Randall Laboratory of Physics, University of Michigan, Ann Arbor, MI 48109-1120 (United States); Zhou Xianyi [Department of Modern Physics, University of Science and Technology of China, Hefei, 230027 (China); Han Rongdian [Department of Modern Physics, University of Science and Technology of China, Hefei, 230027 (China)

    2003-06-13

    The discontinuous dependence of the properties of a quantum game on its entanglement has been shown to be very much like phase transitions viewed in the entanglement-payoff diagram (J Du et al 2002 Phys. Rev. Lett. 88 137902). In this paper we investigate such phase-transition-like behaviour of quantum games, by suggesting a method which would help to illuminate the origin of such a kind of behaviour. For the particular case of the generalized Prisoners' Dilemma, we find that, for different settings of the numerical values in the payoff table, even though the classical game behaves the same, the quantum game exhibits different and interesting phase-transition-like behaviour.

  17. Thermal analysis on organic phase change materials for heat storage applications

    Science.gov (United States)

    Lager, Daniel

    2016-07-01

    In this paper, methodologies based on thermal analysis to evaluate specific heat capacity, phase transition enthalpies, thermal cycling stability and thermal conductivity of organic phase change materials (PCMs) are discussed. Calibration routines for a disc type heat flow differential scanning calorimetry (hf-DSC) are compared and the applied heating rates are adapted due to the low thermal conductivity of the organic PCMs. An assessment of thermal conductivity measurements based on "Laser Flash Analysis" (LFA) and the "Transient Hot Bridge" method (THB) in solid and liquid state has been performed. It could be shown that a disc type hf-DSC is a useful method for measuring specific heat capacity, melting enthalpies and cycling stability of organic PCM if temperature and sensitivity calibration are adapted to the material and quantity to be measured. The LFA method shows repeatable and reproducible thermal diffusivity results in solid state and a high effort for sample preparation in comparison to THB in liquid state. Thermal conductivity results of the two applied methods show large deviations in liquid phase and have to be validated by further experiments.

  18. Structural and topological phase transitions on the German Stock Exchange

    Science.gov (United States)

    Wiliński, M.; Sienkiewicz, A.; Gubiec, T.; Kutner, R.; Struzik, Z. R.

    2013-12-01

    We find numerical and empirical evidence for dynamical, structural and topological phase transitions on the (German) Frankfurt Stock Exchange (FSE) in the temporal vicinity of the worldwide financial crash. Using the Minimal Spanning Tree (MST) technique, a particularly useful canonical tool of the graph theory, two transitions of the topology of a complex network representing the FSE were found. The first transition is from a hierarchical scale-free MST representing the stock market before the recent worldwide financial crash, to a superstar-like MST decorated by a scale-free hierarchy of trees representing the market’s state for the period containing the crash. Subsequently, a transition is observed from this transient, (meta)stable state of the crash to a hierarchical scale-free MST decorated by several star-like trees after the worldwide financial crash. The phase transitions observed are analogous to the ones we obtained earlier for the Warsaw Stock Exchange and more pronounced than those found by Onnela-Chakraborti-Kaski-Kertész for the S&P 500 index in the vicinity of Black Monday (October 19, 1987) and also in the vicinity of January 1, 1998. Our results provide an empirical foundation for the future theory of dynamical, structural and topological phase transitions on financial markets.

  19. Photothermally modulated magnetic resonance applied to the study of the magnetic phase transition in gadolinium thin films

    Energy Technology Data Exchange (ETDEWEB)

    Soffner, M.E.; Tedesco, J.C.G. [Instituto de Fisica Gleb Wataghin, Universidade Estadual de Campinas (UNICAMP), 13083-859, Campinas, SP (Brazil); Pedrochi, F. [Centro de Ciencias Sociais, Saude e Tecnologia, Universidade Federal do Maranhao, Rua Urbano Santos, s/n, Centro, 65900-000, Imperatriz, MA (Brazil); Gadioli, G.Z.; Moraes, M.A.B. de [Instituto de Fisica Gleb Wataghin, Universidade Estadual de Campinas (UNICAMP), 13083-859, Campinas, SP (Brazil); Guimaraes, A.O.; Silva, E.C. da [Laboratorio de Ciencias Fisicas, Universidade Estadual do Norte Fluminense Darcy Ribeiro, UENF, 28013-602 Campos dos Goytacazes, RJ (Brazil); Mansanares, A.M., E-mail: manoel@ifi.unicamp.br [Instituto de Fisica Gleb Wataghin, Universidade Estadual de Campinas (UNICAMP), 13083-859, Campinas, SP (Brazil)

    2012-02-29

    We explore the photothermally modulated magnetic resonance technique to investigate gadolinium thin films deposited on fused quartz substrate, as a function of thickness and thermal treatment, around the magnetic phase transition temperature. It has been observed that the maximum amplitude of the photothermally modulated magnetic resonance (PM-MR) signal takes place near the phase transition temperature, similarly to the magnetocaloric effect, for which Gd has been the prototype material. The reason is that both depend on the temperature derivative of the magnetization, which maximizes at the phase transition. Besides, there is a narrowing of transition with thermal treatment, confirming that thermal treatment stabilizes the film structure. For frequency scan measurements, the heat diffusion in a two-layer system was considered, and a depth profile study was carried out in order to investigate heterogeneities along the film thickness. From the PM-MR response as a function of the modulation frequency it was possible to estimate the thermal properties of the Gd film. Magnetization, X-ray and electron spin resonance measurements were used to complement the analysis and support the conclusions. - Highlights: Black-Right-Pointing-Pointer TC values increase with thermal treatment and film thickness. Black-Right-Pointing-Pointer PM-MR signal amplitude of the main peak is maximum at temperatures close to TC. Black-Right-Pointing-Pointer Frequency scan showed uniform film profile. Black-Right-Pointing-Pointer Gd film thermal diffusivity was found to be smaller than the bulk one.

  20. The quark-hadron phase transition and primordial nucleosynthesis

    Science.gov (United States)

    Hogan, Craig J.

    1987-01-01

    After presenting the current view of the processes taking place during the cosmological transition from 'quark soup' to normal hadron matter, attention is given to what happens to cosmological nucleosynthesis in the presence of small-scale baryon inhomogeneities. The QCD phase transition is among the plausible sources of this inhomogeneity. It is concluded that the formation of primordial 'quark nuggets' and other cold exotica requires very low entropy regions at the outset, and that even the more modest nonlinearities perturbing nucleosynthesis probably require some ingredient in addition to a quiescent, mildly supercooled transition.

  1. Crystal-liquid-gas phase transitions and thermodynamic similarity

    CERN Document Server

    Skripov, Vladimir P; Schmelzer, Jurn W P

    2006-01-01

    Professor Skripov obtained worldwide recognition with his monograph ""Metastable liquids"", published in English by Wiley & Sons. Based upon this work and another monograph published only in Russia, this book investigates the behavior of melting line and the properties of the coexisting crystal and liquid phase of simple substances across a wide range of pressures, including metastable states of the coexisting phases. The authors derive new relations for the thermodynamic similarity for liquid-vapour phase transition, as well as describing solid-liquid, liquid-vapor and liquid-liquid phase tra

  2. Phase transition and monopole production in supergravity inflation

    International Nuclear Information System (INIS)

    Kamada, Kohei; Nakayama, Kazunori

    2011-10-01

    In F-term supergravity inflation models, scalar fields other than the inflaton generically receive a Hubble induced mass, which may restore gauge symmetries during inflation and phase transitions may occur during or after inflation as the Hubble parameter decreases. We study monopole (and domain wall) production associated with such a phase transition in chaotic inflation in supergravity and obtain a severe constraint on the symmetry breaking scale which is related with the tensor-to-scalar ratio. Depending on model parameters, it is possible that monopoles are sufficiently diluted to be free from current constraints but still observable by planned experiments. (orig.)

  3. Plasticity and beyond microstructures, crystal-plasticity and phase transitions

    CERN Document Server

    Hackl, Klaus

    2014-01-01

    The book presents the latest findings in experimental plasticity, crystal plasticity, phase transitions, advanced mathematical modeling of finite plasticity and multi-scale modeling. The associated algorithmic treatment is mainly based on finite element formulations for standard (local approach) as well as for non-standard (non-local approach) continua and for pure macroscopic as well as for directly coupled two-scale boundary value problems. Applications in the area of material design/processing are covered, ranging from grain boundary effects in polycrystals and phase transitions to deep-drawing of multiphase steels by directly taking into account random microstructures.

  4. Phase transitions induced by the Aharonov-Bohm field

    International Nuclear Information System (INIS)

    Krive, I.V.; Naftulin, S.A.

    1990-07-01

    The influence of the Aharonov-Bohm flux (φ) on the order parameters of the 3-dimensional Gross-Neveu model and CP N -model in R 2 xS 1 space is considered. It is shown that the variation of flux causes the order parameter oscillations and for the small enough length of circular coordinate l c these oscillations attended with re-ordering phase transitions (i.e. the repeating transitions between the ordered and the disordered phases of the models in question). (author). 22 refs, 3 figs

  5. Magnetic Phase Transitions of CeSb. I

    DEFF Research Database (Denmark)

    Fischer, Pernille Hertz; Lebech, Bente; Meier, G.

    1978-01-01

    The magnetic ordering of the anomalous antiferromagnet CeSb, which has a NaCl crystal structure, was determined in zero applied magnetic field by means of neutron diffraction investigations of single crystals and powder. Below the Neel temperature TN of (16.1+or-0.1)K, there exist six partially...... a first-order phase transition at TN. At approximately TN/2 there is a first-order phase transition to a FCC type IA low-temperature configuration. The unusual magnetic properties of CeSb, which result from anisotropic exchange and crystalline electric field effects, resemble those of certain actinide Na...

  6. Ferroelectric phase transition in Ga2Te3 single crystals

    Science.gov (United States)

    Gamal, G. A.; Abdalrahman, M. M.; Ashraf, M. I.; Eman, H. J.

    2005-01-01

    Measurements of the electrical conductivity and Hall effect were carried out in a wide temperature range (200-500 K) for Ga2Te3 crystals. The crystals were grown in single crystalline form by making a modification of the travelling heater method technique. The measurements revealed unusual observations in the electric conductivity and Hall mobility indicating the presence of some type of phase transitions at about 430 K. So, ferroelectric behavior was examined for confirming the presence of second-order (ferroelectric) phase transition. An energy gap of 1.21 eV and depth of the impurity center of 0.11 eV were found.

  7. Extragalactic magnetic fields unlikely generated at the electroweak phase transition

    Energy Technology Data Exchange (ETDEWEB)

    Wagstaff, Jacques M.; Banerjee, Robi, E-mail: jwagstaff@hs.uni-hamburg.de, E-mail: banerjee@hs.uni-hamburg.de [Hamburger Sternwarte, University of Hamburg, Gojenbergsweg 112, 21029 Hamburg (Germany)

    2016-01-01

    In this paper we show that magnetic fields generated at the electroweak phase transition are most likely too weak to explain the void magnetic fields apparently observed today unless they have considerable helicity. We show that, in the simplest estimates, the helicity naturally produced in conjunction with the baryon asymmetry is too small to explain observations, which require a helicity fraction at least of order 10{sup −14}–10{sup −10} depending on the void fields constraint used. Therefore new mechanisms to generate primordial helicity are required if magnetic fields generated during the electroweak phase transition should explain the extragalactic fields.

  8. Phase Transitions in Sexual Populations Subject to Stabilizing Selection

    Science.gov (United States)

    Rogers, A.

    2003-04-01

    We show that a simple model of an evolving sexual population, which dates back to some of the earliest work in theoretical population genetics, exhibits an unexpected and previously unobserved phase transition between ordered and disordered states. This behavior is not present in populations evolving asexually without recombination and is thus important in any comparison of sexual and asexual populations. In order to calculate the details of the phase transition, we use techniques from statistical physics. We introduce the correlation of the population as the order parameter of the system and use maximum entropy inference to find the state of the population at any time.

  9. Molecules ionization at phase transition in warm dense hydrogen

    Science.gov (United States)

    Norman, G. E.; Saitov, I. M.

    2018-01-01

    An idea is suggested that the fluid–fluid phase transition in warm dense hydrogen is related to the partial ionization of molecules H2 with formation of molecular ions {{{H}}}2+ {{and}} {{{H}}}3+. Conventional ab initio quantum modeling is applied. Proton pair correlation functions (PCF) obtained are used for the nonconventional diagnostics of the phase transition and elucidation of its nature for temperatures 700–1500 K. Short- and long-range changes of PCFs are studied. H2 molecules ionization and molecular ions {{{H}}}2+ {{and}} {{{H}}}3+ appearance is revealed. The validity of the soft sphere model is tested for the long-range order.

  10. Dynamic phase transitions and dynamic phase diagrams of the spin-2 Blume-Capel model under an oscillating magnetic field within the effective-field theory

    Energy Technology Data Exchange (ETDEWEB)

    Ertas, Mehmet [Department of Physics, Erciyes University, 38039 Kayseri (Turkey); Institute of Science, Erciyes University, 38039 Kayseri (Turkey); Deviren, Bayram [Department of Physics, Nevsehir University, 50300 Nevsehir (Turkey); Keskin, Mustafa, E-mail: keskin@erciyes.edu.tr [Department of Physics, Erciyes University, 38039 Kayseri (Turkey)

    2012-03-15

    The dynamic phase transitions are studied in the kinetic spin-2 Blume-Capel model under a time-dependent oscillating magnetic field using the effective-field theory with correlations. The effective-field dynamic equation for the average magnetization is derived by employing the Glauber transition rates and the phases in the system are obtained by solving this dynamic equation. The nature (first- or second-order) of the dynamic phase transition is characterized by investigating the thermal behavior of the dynamic magnetization and the dynamic phase transition temperatures are obtained. The dynamic phase diagrams are constructed in the reduced temperature and magnetic field amplitude plane and are of seven fundamental types. Phase diagrams contain the paramagnetic (P), ferromagnetic-2 (F{sub 2}) and three coexistence or mixed phase regions, namely the F{sub 2}+P, F{sub 1}+P and F{sub 2}+F{sub 1}+P, which strongly depend on the crystal-field interaction (D) parameter. The system also exhibits the dynamic tricritical behavior. - Highlights: Black-Right-Pointing-Pointer Dynamic phase transitions are studied in spin-2 BC model using EFT. Black-Right-Pointing-Pointer Dynamic phase diagrams are constructed in (T/zJ, h/zJ) plane. Black-Right-Pointing-Pointer Seven fundamental types of dynamic phase diagrams are found in the system. Black-Right-Pointing-Pointer System exhibits dynamic tricritical behavior.

  11. Ground state and magnetic phase transitions of orthoferrite DyFeO3

    Science.gov (United States)

    Zhao, Z. Y.; Zhao, X.; Zhou, H. D.; Zhang, F. B.; Li, Q. J.; Fan, C.; Sun, X. F.; Li, X. G.

    2014-06-01

    Low-temperature thermal conductivity (κ), as well as magnetization (M) and electric polarization (P), of multiferroic orthoferrite DyFeO3 single crystals are studied with H ∥c. When the crystal is cooled in zero field, M, P, and κ all consistently exhibit irreversible magnetic-field dependencies. In particular, with 500 mK ultra-low-T (T mK) κ (H) shows a different irreversibility and there is only one transition when the field is swept both up and down. All the results indicate a complex low-T H-T phase diagram involving successive magnetic phase transitions of the Fe3+ spins. In particular, the ground state, obtained with cooling to sub-Kelvin temperatures in zero field, is found to be an unexplored phase.

  12. Integrated thermal treatment system study -- Phase 2 results. Revision 1

    Energy Technology Data Exchange (ETDEWEB)

    Feizollahi, F.; Quapp, W.J.

    1996-02-01

    This report presents the second phase of a study on thermal treatment technologies. The study consists of a systematic assessment of nineteen thermal treatment alternatives for the contact-handled mixed low-level waste (MLLW) currently stored in the US Department of Energy complex. The treatment alternatives consist of widely varying technologies for safely destroying the hazardous organic components, reducing the volume, and preparing for final disposal of the MLLW. The alternatives considered in Phase 2 were innovative thermal treatments with nine types of primary processing units. Other variations in the study examined the effect of combustion gas, air pollution control system design, and stabilization technology for the treatment residues. The Phase 1 study examined ten initial thermal treatment alternatives. The Phase 2 systems were evaluated in essentially the same manner as the Phase 1 systems. The alternatives evaluated were: rotary kiln, slagging kiln, plasma furnace, plasma gasification, molten salt oxidation, molten metal waste destruction, steam gasification, Joule-heated vitrification, thermal desorption and mediated electrochemical oxidation, and thermal desorption and supercritical water oxidation. The quantities, and physical and chemical compositions, of the input waste used in the Phase 2 systems differ from those in the Phase 1 systems, which were based on a preliminary waste input database developed at the onset of the Integrated Thermal Treatment System study. The inventory database used in the Phase 2 study incorporates the latest US Department of Energy information. All systems, both primary treatment systems and subsystem inputs, have now been evaluated using the same waste input (2,927 lb/hr). 28 refs., 88 figs., 41 tabs.

  13. Integrated thermal treatment system study -- Phase 2 results. Revision 1

    International Nuclear Information System (INIS)

    Feizollahi, F.; Quapp, W.J.

    1996-02-01

    This report presents the second phase of a study on thermal treatment technologies. The study consists of a systematic assessment of nineteen thermal treatment alternatives for the contact-handled mixed low-level waste (MLLW) currently stored in the US Department of Energy complex. The treatment alternatives consist of widely varying technologies for safely destroying the hazardous organic components, reducing the volume, and preparing for final disposal of the MLLW. The alternatives considered in Phase 2 were innovative thermal treatments with nine types of primary processing units. Other variations in the study examined the effect of combustion gas, air pollution control system design, and stabilization technology for the treatment residues. The Phase 1 study examined ten initial thermal treatment alternatives. The Phase 2 systems were evaluated in essentially the same manner as the Phase 1 systems. The alternatives evaluated were: rotary kiln, slagging kiln, plasma furnace, plasma gasification, molten salt oxidation, molten metal waste destruction, steam gasification, Joule-heated vitrification, thermal desorption and mediated electrochemical oxidation, and thermal desorption and supercritical water oxidation. The quantities, and physical and chemical compositions, of the input waste used in the Phase 2 systems differ from those in the Phase 1 systems, which were based on a preliminary waste input database developed at the onset of the Integrated Thermal Treatment System study. The inventory database used in the Phase 2 study incorporates the latest US Department of Energy information. All systems, both primary treatment systems and subsystem inputs, have now been evaluated using the same waste input (2,927 lb/hr). 28 refs., 88 figs., 41 tabs

  14. The electroweak phase transition in models with gauge singlets

    International Nuclear Information System (INIS)

    Ahriche, A.

    2007-01-01

    A strong first order phase transition is needed for generating the baryon asymmetry; and also to save it during the electroweak phase transition (EWPT). However this condition is not fulfilled within the Standard Model (SM), but in its extensions. It is widely believed that the existence of singlet scalars in some Standard Model extensions can easily make the EWPT strongly first order. In this work, we will examine the strength of the EWPT in the simplest extension of the SM with a real gauge singlet using the sphaleron energy at the critical temperature. We find that the phase transition is stronger by adding a singlet; and also that the criterion for a strong phase transition Ω(T c )/T c >or similar 1, where Ω = (v 2 + (x - x 0 ) 2 ) ( 1)/(2) and x(x 0 ) is the singlet vacuum expectation value in the broken (symmetric) phase, is not valid for models containing singlets, even though often used in the literature. The usual condition v c /T c >or similar 1 is more meaningful, and it is satisfied for the major part of the parameter space for physically allowed Higgs masses. Then it is convenient to study the EWPT in models with singlets that couple only to the Higgs doublets, by replacing the singlets by their vevs. (orig.)

  15. The electroweak phase transition in models with gauge singlets

    Energy Technology Data Exchange (ETDEWEB)

    Ahriche, A.

    2007-04-18

    A strong first order phase transition is needed for generating the baryon asymmetry; and also to save it during the electroweak phase transition (EWPT). However this condition is not fulfilled within the Standard Model (SM), but in its extensions. It is widely believed that the existence of singlet scalars in some Standard Model extensions can easily make the EWPT strongly first order. In this work, we will examine the strength of the EWPT in the simplest extension of the SM with a real gauge singlet using the sphaleron energy at the critical temperature. We find that the phase transition is stronger by adding a singlet; and also that the criterion for a strong phase transition {omega}(T{sub c})/T{sub c} >or similar 1, where {omega} = (v{sup 2} + (x - x{sub 0}){sup 2}){sup (}1)/(2) and x(x{sub 0}) is the singlet vacuum expectation value in the broken (symmetric) phase, is not valid for models containing singlets, even though often used in the literature. The usual condition v{sub c}/T{sub c} >or similar 1 is more meaningful, and it is satisfied for the major part of the parameter space for physically allowed Higgs masses. Then it is convenient to study the EWPT in models with singlets that couple only to the Higgs doublets, by replacing the singlets by their vevs. (orig.)

  16. Surface phase transitions in cu-based solid solutions

    Science.gov (United States)

    Zhevnenko, S. N.; Chernyshikhin, S. V.

    2017-11-01

    We have measured surface energy in two-component Cu-based systems in H2 + Ar gas atmosphere. The experiments on solid Cu [Ag] and Cu [Co] solutions show presence of phase transitions on the surfaces. Isotherms of the surface energy have singularities (the minimum in the case of copper solid solutions with silver and the maximum in the case of solid solutions with cobalt). In both cases, the surface phase transitions cause deficiency of surface miscibility: formation of a monolayer (multilayer) (Cu-Ag) or of nanoscale particles (Cu-Co). At the same time, according to the volume phase diagrams, the concentration and temperature of the surface phase transitions correspond to the solid solution within the volume. The method permits determining the rate of diffusional creep in addition to the surface energy. The temperature and concentration dependence of the solid solutions' viscosity coefficient supports the fact of the surface phase transitions and provides insights into the diffusion properties of the transforming surfaces.

  17. Extra phase noise from thermal fluctuations in nonlinear optical crystals

    DEFF Research Database (Denmark)

    César, J. E. S.; Coelho, A.S.; Cassemiro, K.N.

    2009-01-01

    We show theoretically and experimentally that scattered light by thermal phonons inside a second-order nonlinear crystal is the source of additional phase noise observed in optical parametric oscillators. This additional phase noise reduces the quantum correlations and has hitherto hindered the d...

  18. The phase transition method for SAR measurement in MRI

    Science.gov (United States)

    Romano, R.; Canonico, R.; Acernese, F.; Giordano, G.; Barone, F.

    2014-03-01

    During an MR procedure, the patient absorbs a portion of the transmitted RF energy, which may result in tissue heating and other adverse effects, such as alterations in visual, auditory and neural functions. The Specific Absorption Rate (SAR), in W/kg, is the RF power absorbed per unit mass of tissue and is one of the most important parameters related with thermal effects and acts as a guideline for MRI safety. Strict limits to the SAR levels are imposed by patient safety international regulations (CEI - EN 60601 - 2 - 33) and SAR measurements are required in order to verify its respect. The recommended methods for mean SAR measurement are quite problematic and often require a maintenance man intervention and long stop machine. For example, in the CEI recommended pulse energy method, the presence of a maintenance man is required in order to correctly connect the required instrumentation; furthermore, the procedure is complex and requires remarkable processing and calculus. Simpler are the calorimetric methods, also if in this case long acquisition times are required in order to have significant temperature variations and accurate heat capacity knowledge (CEI - EN 60601 - 2 - 33). The phase transition method is a new method to measure SAR in MRI which has the advantages to be very simple and to overcome all the typical calorimetric method problems. It does not require in gantry temperature measurements, any specific heat or heat capacity knowledge, but only mass and time measurement. Nevertheless, in order to consider this method it is necessary to verify that all deposited SAR power can be considered acquired and measured. In this paper considerations about this aspect are conducted.

  19. Relationship between thermal expansion coefficient and glass transition temperature in metallic glasses

    International Nuclear Information System (INIS)

    Kato, H.; Chen, H.-S.; Inoue, A.

    2008-01-01

    The thermal expansion coefficients of 13 metallic glasses were measured using a thermo-mechanical analyser. A unique correlation was found between the linear thermal expansion coefficient and the glass transition temperature-their product is nearly constant ∼8.24 x 10 -3 . If one assumes the Debye expression for thermal activation, the total linear thermal expansion up to glass transition temperature (T g ) is reduced to 6 x 10 -3 , nearly 25% of that at the fusion of pure metals

  20. The average action for scalar fields near phase transitions

    International Nuclear Information System (INIS)

    Wetterich, C.

    1991-08-01

    We compute the average action for fields in two, three and four dimensions, including the effects of wave function renormalization. A study of the one loop evolution equations for the scale dependence of the average action gives a unified picture of the qualitatively different behaviour in various dimensions for discrete as well as abelian and nonabelian continuous symmetry. The different phases and the phase transitions can be infered from the evolution equation. (orig.)

  1. Nuclear multifragmentation and phase transition for hot nuclei

    OpenAIRE

    Borderie, B.; Rivet, M.F.

    2008-01-01

    This review article is focused on the tremendous progress realized during the last fifteen years in the understanding of multifragmentation and its relationship to the liquid-gas phase diagram of nuclei and nuclear matter. The explosion of the whole nucleus, early predicted by Bohr [N. Bohr, Nature 137 (1936) 351], is a very complex and rich subject which continues to fascinate nuclear physicists as well as theoreticians who extend the thermodynamics of phase transitions to finite systems.

  2. Operation of transition-edge sensors with excess thermal noise

    International Nuclear Information System (INIS)

    Maasilta, I J; Kinnunen, K M; Nuottajaervi, A K; Leppaeniemi, J; Luukanen, A

    2006-01-01

    The superconducting transition-edge sensor (TES) is currently one of the most attractive choices for ultra-high resolution calorimetry in the keV x-ray band, and is being considered for future ESA and NASA missions. We have performed a study on the noise characteristics of Au/Ti bilayer TESs, at operating temperatures around ∼100 mK, with the SQUID readout at 1.5 K. Experimental results indicate that without modifications the back-action noise from the SQUID chip degrades the noise characteristics significantly. We present a simple and effective solution to the problem: by installing an extra shunt resistor which absorbs the excess radiation from the SQUID input, we have reduced the excess thermal (photon) noise power down by approximately a factor of five, allowing high resolution operation of the sensors

  3. Electric Field-Induced Phase Transitions in Ferroelectrics at Polymorphic Phase Boundaries

    Science.gov (United States)

    Iamsasri, Thanakorn

    Ferroelectric and dielectric materials are used in many applications, including capacitors, actuators, and energy harvesting. In general, the piezoelectric and dielectric properties of these materials reach a maximum at the morphotropic or polymorphic phase boundary, which lie between two different phases of the same structure type. At the phase boundary, the two coexisting phases have similar free energies. By applying external stimuli such as pressures or electric fields, the free energies of two phases can be changed, resulting in an induced phase transition. Electric field-induced phase transitions in ferroelectrics have been observed using transmission electron microscopy (TEM) and X-ray diffraction (XRD). However, there are limited studies on the field-induced phase transitions of ferroelectrics because it requires a characterization technique that can probe structural evolution under electric fields. This study investigates the field-induced phase transitions of ferroelectrics and dielectrics using a combination of synchrotron XRD techniques including in situ XRD under electric fields, high resolution XRD, and time-resolved XRD. This combination of characterization techniques allows one to observe a field-induced phase transition and also quantify it using the intensities and positions of peaks from XRD patterns. Two different material systems are investigated in this study: Li-modified Na0.5K 0.5NbO3 (LNKN) and BaTiO3-BiZn0.5Ti 0.5O3 (BT-BZT). LNKN is a ferroelectric, and BT-BZT is a relaxorferroelectric (i.e. exhibits frequency dependence of dielectric permittivity). For both LNKN and BT-BZT, the field-induced phase transition was observed only in compositions located at the polymorphic phase boundary, but never in single-phase compositions. This result shows that the field-induced phase transition is therefore closely related to the high piezoelectric properties at the phase boundary. Additionally, domain reorientation in single-phase orthorhombic LNKN

  4. Properties of hadronic matter near the phase transition

    Energy Technology Data Exchange (ETDEWEB)

    Noronha-Hostler, Jacquelyn

    2010-12-08

    According to Hagedorn, hadrons should follow an exponential mass spectrum, which the known hadrons follow only up to masses of M{approx}2 GeV. Beyond this point the mass spectrum is flat, which indicates that there are ''missing'' hadrons, that could potentially contribute significantly to experimental observables. In this thesis I investigate the influence of these ''missing'' Hagedorn states on various experimental signatures of QGP. Strangeness enhancement is considered a signal for QGP because hadronic interactions (even including multi-mesonic reactions) underpredict the hadronic yields (especially for strange particles) at the Relativistic Heavy Ion Collider, RHIC. We show here that the missing Hagedorn states provide extra degrees of freedom that can contribute to fast chemical equilibration times for a hadron gas. We develop a dynamical scheme in which possible Hagedorn states contribute to fast chemical equilibration times of X anti X pairs (where X=p, K, {lambda}, or {omega}) inside a hadron gas and just below the critical temperature. Within this scheme, we use master equations and derive various analytical estimates for the chemical equilibration times. Applying a Bjorken picture to the expanding fireball, the hadrons can, indeed, quickly chemically equilibrate for both an initial overpopulation or underpopulation of Hagedorn resonances. Our hadron resonance gas model, including the additional Hagedorn states, is used to obtain an upper bound on the shear viscosity to entropy density ratio, {eta}/s, of hadronic matter near T{sub c} that is close to 1/(4/{pi}). We show how the measured particle ratios can be used to provide non-trivial information about T{sub c} of the QCD phase transition. This is obtained by including the effects of highly massive Hagedorn resonances on statistical models, which are generally used to describe hadronic yields. The inclusion of the ''missing'' Hagedorn states

  5. Properties of hadronic matter near the phase transition

    International Nuclear Information System (INIS)

    Noronha-Hostler, Jacquelyn

    2010-01-01

    According to Hagedorn, hadrons should follow an exponential mass spectrum, which the known hadrons follow only up to masses of M∼2 GeV. Beyond this point the mass spectrum is flat, which indicates that there are ''missing'' hadrons, that could potentially contribute significantly to experimental observables. In this thesis I investigate the influence of these ''missing'' Hagedorn states on various experimental signatures of QGP. Strangeness enhancement is considered a signal for QGP because hadronic interactions (even including multi-mesonic reactions) underpredict the hadronic yields (especially for strange particles) at the Relativistic Heavy Ion Collider, RHIC. We show here that the missing Hagedorn states provide extra degrees of freedom that can contribute to fast chemical equilibration times for a hadron gas. We develop a dynamical scheme in which possible Hagedorn states contribute to fast chemical equilibration times of X anti X pairs (where X=p, K, Λ, or Ω) inside a hadron gas and just below the critical temperature. Within this scheme, we use master equations and derive various analytical estimates for the chemical equilibration times. Applying a Bjorken picture to the expanding fireball, the hadrons can, indeed, quickly chemically equilibrate for both an initial overpopulation or underpopulation of Hagedorn resonances. Our hadron resonance gas model, including the additional Hagedorn states, is used to obtain an upper bound on the shear viscosity to entropy density ratio, η/s, of hadronic matter near T c that is close to 1/(4/π). We show how the measured particle ratios can be used to provide non-trivial information about T c of the QCD phase transition. This is obtained by including the effects of highly massive Hagedorn resonances on statistical models, which are generally used to describe hadronic yields. The inclusion of the ''missing'' Hagedorn states creates a dependence of the thermal fits on the Hagedorn temperature, T H , and leads to a

  6. Problem-solving phase transitions during team collaboration

    DEFF Research Database (Denmark)

    Wiltshire, Travis; Butner, Jonathan E.; Fiore, Stephen M.

    2018-01-01

    Multiple theories of problem-solving hypothesize that there are distinct qualitative phases exhibited during effective problem-solving. However, limited research has attempted to identify when transitions between phases occur. We integrate theory on collaborative problem-solving (CPS) with dynami......Multiple theories of problem-solving hypothesize that there are distinct qualitative phases exhibited during effective problem-solving. However, limited research has attempted to identify when transitions between phases occur. We integrate theory on collaborative problem-solving (CPS......) with dynamical systems theory suggesting that when a system is undergoing a phase transition it should exhibit a peak in entropy and that entropy levels should also relate to team performance. Communications from 40 teams that collaborated on a complex problem were coded for occurrence of problem......-solving processes. We applied a sliding window entropy technique to each team's communications and specified criteria for (a) identifying data points that qualify as peaks and (b) determining which peaks were robust. We used multilevel modeling, and provide a qualitative example, to evaluate whether phases exhibit...

  7. On the thermodynamics of phase transitions in metal hydrides

    Science.gov (United States)

    di Vita, Andrea

    2012-02-01

    Metal hydrides are solutions of hydrogen in a metal, where phase transitions may occur depending on temperature, pressure etc. We apply Le Chatelier's principle of thermodynamics to a particular phase transition in TiH x , which can approximately be described as a second-order phase transition. We show that the fluctuations of the order parameter correspond to fluctuations both of the density of H+ ions and of the distance between adjacent H+ ions. Moreover, as the system approaches the transition and the correlation radius increases, we show -with the help of statistical mechanics-that the statistical weight of modes involving a large number of H+ ions (`collective modes') increases sharply, in spite of the fact that the Boltzmann factor of each collective mode is exponentially small. As a result, the interaction of the H+ ions with collective modes makes a tiny suprathermal fraction of the H+ population appear. Our results hold for similar transitions in metal deuterides, too. A violation of an -insofar undisputed-upper bound on hydrogen loading follows.

  8. The QCD phase transition. From the microscopic mechanism to signals

    International Nuclear Information System (INIS)

    Shuryak, E.V.

    1997-01-01

    This talk consists of two very different parts: the first one deals with non-perturbative QCD and physics of the chiral restoration, the second with rather low-key (and still unfinished) work aiming at obtaining EOS and other properties of hot/dense hadronic matter from data on heavy ion collisions. The microscopic mechanism for chiral restoration phase transition is a transition from randomly placed tunneling events (instantons) at low T to a set of strongly correlated tunneling-anti-tunneling events (known as instanton-anti-instanton molecules) at high T. Many features of the transition can be explained in this simple picture, especially the critical line and its dependence on quark masses. This scenario predicts qualitative change of the basic quark-quark interactions around the phase transition line, with some states (such as pion-sigma ones) probably surviving event at T > T c . In the second half of the talk experimental data on collective flow in heavy ion collision are discussed its hydro-based description and relation to equation of state (EOS). A distinct feature of the QCD phase transition region is high degree of 'softness', (small ratio pressure/energy density). (author)

  9. Thermal Protection Performance of Carbon Aerogels Filled with Magnesium Chloride Hexahydrate as a Phase Change Material

    Directory of Open Access Journals (Sweden)

    Ali Kazemi

    2014-02-01

    Full Text Available Carbon aerogels are comprised of a class of low density open-cell foams with large void space, nanometer pore size and composed of sparsely semi-colloidal nanometer sized particles forming an open porous structure. Phase change materials are those with high heat of fusion that could absorb and release a large amount of energy at the time of phase transition. These materials are mostly used as thermal energy storage materials but in addition they could serve as an obstacle for passage of heat during phase changes and this has led to their use in thermal protection systems. In this study, the effect of magnesium chloride hexahydrate, as a phase change material (melting point 115°C, on thermal properties of carbon aerogels is investigated. Thermal performance tests are designed and used for comparing the temperature-time behavior of the samples. DSC is applied to obtain the latent heat of melting of the phase change materials and the SEM tests are used to analyze the microstructure and morphology of carbon aerogels. The results show that the low percentage of phase change materials in carbon aerogels does not have any significant positive effect on carbon aerogels thermal properties. However, these properties are improved by increasing the percentage of phase change materials. With high percentage of phase change materials, a sample surface at 300°C would display an opposite surface with a significant drop in temperature increases, while at 115-200°C, with carbon aerogels, having no phase change materials, there is a severe reduction in the rate of temperature increase of the sample.

  10. Probing emergent geometry through phase transitions in free vector and matrix models

    Energy Technology Data Exchange (ETDEWEB)

    Amado, Irene; Sundborg, Bo [The Oskar Klein Centre for Cosmoparticle Physics, Department of Physics, Stockholm University,AlbaNova, 106 91 Stockholm (Sweden); Thorlacius, Larus [The Oskar Klein Centre for Cosmoparticle Physics, Department of Physics, Stockholm University,AlbaNova, 106 91 Stockholm (Sweden); Science Institute, University of Iceland, Dunhaga 3, 107 Reykjavik (Iceland); Wintergerst, Nico [The Oskar Klein Centre for Cosmoparticle Physics, Department of Physics, Stockholm University,AlbaNova, 106 91 Stockholm (Sweden)

    2017-02-01

    Boundary correlation functions provide insight into the emergence of an effective geometry in higher spin gravity duals of O(N) or U(N) symmetric field theories. On a compact manifold, the singlet constraint leads to nontrivial dynamics at finite temperature and large N phase transitions even at vanishing ’t Hooft coupling. At low temperature, the leading behavior of boundary two-point functions is consistent with propagation through a bulk thermal anti de Sitter space. Above the phase transition, the two-point function shows significant departure from thermal AdS space and the emergence of localized black hole like objects in the bulk. In adjoint models, these objects appear at length scales of order of the AdS radius, consistent with a Hawking-Page transition, but in vector models they are parametrically larger than the AdS scale. In low dimensions, we find another crossover at large distances beyond which the correlation function again takes a thermal AdS form, albeit with a temperature dependent normalization factor.

  11. Liquid-Liquid Phase Transition and Glass Transition in a Monoatomic Model System

    Directory of Open Access Journals (Sweden)

    Nicolas Giovambattista

    2010-12-01

    Full Text Available We review our recent study on the polyamorphism of the liquid and glass states in a monatomic system, a two-scale spherical-symmetric Jagla model with both attractive and repulsive interactions. This potential with a parametrization for which crystallization can be avoided and both the glass transition and the liquid-liquid phase transition are clearly separated, displays water-like anomalies as well as polyamorphism in both liquid and glassy states, providing a unique opportunity to study the interplay between the liquid-liquid phase transition and the glass transition. Our study on a simple model may be useful in understanding recent studies of polyamorphism in metallic glasses.

  12. Is there a sharp phase transition for deterministic cellular automata?

    International Nuclear Information System (INIS)

    Wootters, W.K.

    1990-01-01

    Previous work has suggested that there is a kind of phase transition between deterministic automata exhibiting periodic behavior and those exhibiting chaotic behavior. However, unlike the usual phase transitions of physics, this transition takes place over a range of values of the parameter rather than at a specific value. The present paper asks whether the transition can be made sharp, either by taking the limit of an infinitely large rule table, or by changing the parameter in terms of which the space of automata is explored. We find strong evidence that, for the class of automata we consider, the transition does become sharp in the limit of an infinite number of symbols, the size of the neighborhood being held fixed. Our work also suggests an alternative parameter in terms of which it is likely that the transition will become fairly sharp even if one does not increase the number of symbols. In the course of our analysis, we find that mean field theory, which is our main tool, gives surprisingly good predictions of the statistical properties of the class of automata we consider. 18 refs., 6 figs

  13. DECnet routing transition from PhaseIV to PhaseV/OSI in Japan

    International Nuclear Information System (INIS)

    Yuasa, F.; Hirose, H.; Ichii, S.; Karita, Y.; Miyajima, T.; Morita, Y.; Nakamura, T.

    1994-01-01

    DECnet, one of the network protocols used in world-wide HEP community, is under the way of transition to PhaseV/OSI because of lack of address space. This affects to DECnet naming, addressing and routing. The authors present the current status of the routing transition in Japan

  14. Phase transitions in coated nickel titanium arch wires: A differential ...

    Indian Academy of Sciences (India)

    Discrete crystallographic structure and absence of mul- tiple phases showed complete martensitic–austenitic transition, which authenticated the differential scanning calori- metric findings. This can earn acceptance for the new product in contemporary orthodontic practice with adequate scope for indigenization. Keywords.

  15. Quantum phase transition of a magnet in a spin bath

    DEFF Research Database (Denmark)

    Rønnow, H.M.; Parthasarathy, R.; Jensen, J.

    2005-01-01

    The excitation spectrum of a model magnetic system, LiHoF(4), was studied with the use of neutron spectroscopy as the system was tuned to its quantum critical point by an applied magnetic field. The electronic mode softening expected for a quantum phase transition was forestalled by hyperfine...

  16. High pressure phase transitions for CdSe

    Indian Academy of Sciences (India)

    Administrator

    respectively and the intermediate states between the Cmcm structure and the CsCl structure should exist. Keywords. Semiconductor; high pressure; phase transition. 1. Introduction. CdSe has become quite interesting and important because of its major applications in solar cells and other optoelec- tronic devices due to its ...

  17. Phase transitions in coated nickel titanium arch wires: A differential ...

    Indian Academy of Sciences (India)

    Abstract. Shape memory and super-elastic properties of orthodontic nickel titanium wires, which are crucial for its clinical performance are dependent on the austenitic–martensitic phase transitions in its metallic microstructure that happen as a result of temperature or stress. The objective of this study was to compare the ...

  18. Quantum chromodynamics phase transition in the early Universe ...

    Indian Academy of Sciences (India)

    number distribution of the QNs will be calculated in §2. Section 3 will be devoted to the discussion on the evolution of these nuggets to form dark matter and§4 will contain a brief conclusion. 2. The baryon number distribution of quark nuggets. The evolution of the universe during the QCD phase transition is governed by ...

  19. Shape change as entropic phase transition: A study using Jarzynski ...

    Indian Academy of Sciences (India)

    21–28. c Indian Academy of Sciences. Shape change as entropic phase transition: A study using Jarzynski relation ... cess.1–3 This occurs with enthalpic changes in the ther- modynamic system, in which the system size is ..... Ma S K 1976 Modern theory of critical phenomena. (Benjamin, Reading, MA). 3. Stanley H E 1971 ...

  20. Ultrafast Hot Electron Induced Phase Transitions in Vanadium Dioxide

    Directory of Open Access Journals (Sweden)

    Haglund R. F.

    2013-03-01

    Full Text Available The Au/Cr/VO2/Si system was investigated in pump–probe experiments. Hot-electrons generated in the Au were found to penetrate into the underlying VO2 and couple with its lattice inducing a semiconductor-to-metal phase transition in ~2 picoseconds.

  1. Luminous transmittance and phase transition temperature of VO 2 ...

    African Journals Online (AJOL)

    The phase transition temperature (τc) of the films was obtained from both the transmittance and sheet resistance against temperature curves. A change in sheet resistance of 2 to 3 orders of magnitude was observed for both undoped and Ce-doped VO2 films. Comparison between undoped and doped VO2 films revealed ...

  2. Long time behaviour of a singular phase transition model

    Czech Academy of Sciences Publication Activity Database

    Krejčí, Pavel; Sprekels, J.

    2006-01-01

    Roč. 15, č. 4 (2006), s. 1119-1135 ISSN 1078-0947 Institutional research plan: CEZ:AV0Z10190503 Keywords : phase transition * nonlocal model * integrodifferential heat equation Subject RIV: BA - General Mathematics Impact factor: 1.087, year: 2006

  3. Simple explanation for the reentrant magnetic phase transition in Pr ...

    Indian Academy of Sciences (India)

    The reentrant magnetic phase transition in Pr0.5Sr0.41Ca0.09MnO3 perovskite is explained using the Ising spin model on the square lattice with mixed ferromagnetic and antiferromagnetic exchange interactions. It is shown using numerical calculations that this effect is strongly affected by the external magnetic field and ...

  4. Fatigue and phase transition in an oscillating plate

    Czech Academy of Sciences Publication Activity Database

    Bosia, S.; Eleuteri, M.; Kopfová, J.; Krejčí, Pavel

    2014-01-01

    Roč. 435, February (2014), s. 1-3 ISSN 0921-4526 R&D Projects: GA ČR GAP201/10/2315 Institutional support: RVO:67985840 Keywords : fatigue * hysteresis * phase transitions Subject RIV: BA - General Mathematics Impact factor: 1.319, year: 2014 http://www.sciencedirect.com/science/article/pii/S0921452613006042

  5. Multifragmentation and the phase transition: A systematic study of ...

    Indian Academy of Sciences (India)

    study of the multifragmentation of 1 GeV Au, La and Kr ... Department of Physics and Chemistry, Purdue University, West Lafayette, Indiana, USA. Abstract. ... power law ( ). - , with. 25 [2] generated theoretical interest in MF in terms of a continuous phase transition. A similar power law was also predicted by Fisher [3] for.

  6. Corrosion behaviour, microstructure and phase transitions of Zn ...

    Indian Academy of Sciences (India)

    This paper is aimed at investigating the corrosion behaviour, microstructure and phase transitions of Zn-based alloys with different compositions. The corrosion tests are carried out both in acidic medium using 1 N HCl solution and in temperature dependence of thermogravimetric analysis (TGA). In the two different media, ...

  7. High-temperature phase transition in hadron matter

    International Nuclear Information System (INIS)

    Bugrij, A.I.; Trushevsky, A.A.

    1976-01-01

    A possible phase transition in hadronic systems at temperatures of few of GeV is shown in the framework of the S-matrix formulation of statistical mechanics given by Dashen, Ma, Bernstein by using Regge pole model for the scattering amplitude

  8. Wet Process Induced Phase Transited Drug Delivery System as a ...

    African Journals Online (AJOL)

    Nx 6110

    The drug release was found to be independent of the pH but dependent on the osmotic pressure of the dissolution medium. The results of in vivo toxicity studies may support the use of phase transited asymmetric membrane capsules as a means for delivery of gastro-intestinal irritant drugs in a controlled manner through ...

  9. Structure determination at room temperature and phase transition ...

    Indian Academy of Sciences (India)

    Unknown

    Structure determination at room temperature and phase transition studies above Tc in ABi4Ti4O15 (A = Ba, Sr or Pb). G NALINI and T N GURU ROW*. Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560 012, India. MS received 9 May 2002. Abstract. The room temperature structure of three ...

  10. Routing strategies in traffic network and phase transition in network ...

    Indian Academy of Sciences (India)

    3Department of Electronic Engineering, City University of Hong Kong, Hong Kong SAR,. China. *Corresponding author. ... networks. Keywords. Routing strategy; network traffic flow; hysteretic loop; phase transition from ... nication networks is to control the increasing traffic congestion and improve the efficiency of information ...

  11. Simple explanation for the reentrant magnetic phase transition in

    Indian Academy of Sciences (India)

    The reentrant magnetic phase transition in Pr0.5Sr0.41Ca0.09MnO3 perovskite is explained using the Ising spin model on the square lattice with mixed ferromagnetic and antiferromagnetic exchange interactions. It is shown using numerical calculations that this effect is strongly affected by the external magnetic field and ...

  12. Quantum chromodynamics phase transition in the early Universe ...

    Indian Academy of Sciences (India)

    A first-order quark hadron phase transition in the early Universe may lead to the formation of quark nuggets. The baryon number distribution of these quark nuggets have been calculated and it has been found that there are sizeable number of quark nuggets in the stable sector. The nuggets can clump and form bigger ...

  13. Nonlinear clustering during the BEC dark matter phase transition

    Energy Technology Data Exchange (ETDEWEB)

    Freitas, Rodolfo C. de, E-mail: rodolfo.camargo@pq.cnpq.br [Universidade Federal do Espírito Santo, Av. Fernando Ferrari, Goiabeiras, Vitória (Brazil); Instituto Federal de Educação, Ciência e Tecnologia do Espírito Santo, Avenida Vitória 1729, Jucutuquara, Vitória (Brazil); Velten, Hermano, E-mail: velten@pq.cnpq.br [Universidade Federal do Espírito Santo, Av. Fernando Ferrari, Goiabeiras, Vitória (Brazil); UMR 7332, CPT, Aix Marseille Université, 13288, Marseille (France)

    2015-12-16

    Spherical collapse of the Bose–Einstein condensate (BEC) dark matter model is studied in the Thomas–Fermi approximation. The evolution of the overdensity of the collapsed region and its expansion rate are calculated for two scenarios. We consider the case of a sharp phase transition (which happens when the critical temperature is reached) from the normal dark matter state to the condensate one and the case of a smooth first order phase transition where there is a continuous conversion of “normal” dark matter to the BEC phase. We present numerical results for the physics of the collapse for a wide range of the model’s space parameter, i.e. the mass of the scalar particle m{sub χ} and the scattering length l{sub s}. We show the dependence of the transition redshift on m{sub χ} and l{sub s}. Since small scales collapse earlier and eventually before the BEC phase transition, the evolution of collapsing halos in this limit is indeed the same in both the CDM and the BEC models. Differences are expected to appear only on the largest astrophysical scales. However, we argue that the BEC model is almost indistinguishable from the usual dark matter scenario concerning the evolution of nonlinear perturbations above typical clusters scales, i.e., ≳10{sup 14}M{sub ⊙}. This provides an analytical confirmation for recent results from cosmological numerical simulations (Schive et al., Nat Phys 10:496, 2014)

  14. Multiply Degenerate Exceptional Points and Quantum Phase Transitions

    Czech Academy of Sciences Publication Activity Database

    Borisov, D.; Růžička, František; Znojil, Miloslav

    2015-01-01

    Roč. 54, č. 12 (2015), s. 4293-4305 ISSN 0020-7748 Institutional support: RVO:61389005 Keywords : quantum mechanics * Cryptohermitian observbles * spectra and pseudospectra * real exceptional points * phase transitions Subject RIV: BE - Theoretical Physics Impact factor: 1.041, year: 2015

  15. African Transitional Justice Research Network - Phase II | IDRC ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    The African Transitional Justice Research Network (ATJRN) aims to strengthen the capacity of African researchers and civil society institutions to conduct effective human rights advocacy through the production of high-quality, locally based and targeted empirical research. Phase I of the project (102862) focused on creating ...

  16. Dry Process Induced Phase Transited Drug Delivery System: A ...

    African Journals Online (AJOL)

    An in-situ formed phase transited, nondisintegrating, controlled release, asymmetric membrane capsular system for the poorly water soluble model drug ketoprofen was developed and evaluated in vitro to assess for osmotic and controlled release and in vivo to assess the ability of the fabricated dosage form to control GI ...

  17. Electroweak phase transition and some related phenomena – a brief ...

    Indian Academy of Sciences (India)

    2016-08-24

    Aug 24, 2016 ... Abstract. In this article, we give a bird's eye view of the research on electroweak phase transition and some related phenomena, viz., cosmological baryogenesis, electroweak bubble dynamics and generation of gravi- tational waves. Our presentation revolves around the observation that a strong first-order ...

  18. Phase transition in L-alaninium oxalate by photoacoustics

    Indian Academy of Sciences (India)

    Unknown

    structural where one-dimensional hydrogen bonding struc- ture is formed and stacked to form a molecular layer. This work showed a solid to solid phase transition at. 363 K (90°C). Since these crystals were grown by slow evaporation method, they have taken care in omitting the occluded water, if any, during the growth by ...

  19. Phase transitions at finite chemical potential in grand unified theories

    International Nuclear Information System (INIS)

    Bailin, D.; Love, A.

    1984-01-01

    We discuss the circumstances in which non-zero chemical potentials might prevent symmetry restoration in phase transitions in the early universe at grand unification or partial unification scales. The general arguments are illustrated by consideration of SO(10) and SU(5) grand unified theories. (orig.)

  20. Electroweak phase transition and some related phenomena – a brief ...

    Indian Academy of Sciences (India)

    2016-08-24

    Aug 24, 2016 ... Centre for Advanced Studies, Department of Physics, The University of Burdwan, Burdwan 713 104, India ... tational waves. Our presentation revolves around the observation that a strong first-order electroweak phase transition cannot be obtained in the Standard Model for experimentally favoured Higgs ...

  1. Spin delocalization phase transition in a correlated electrons model

    International Nuclear Information System (INIS)

    Huerta, L.

    1990-11-01

    In a simplified one-site model for correlated electrons systems we show the existence of a phase transition corresponding to spin delocalization. The system becomes a solvable model and zero-dimensional functional techniques are used. (author). 7 refs, 3 figs

  2. First-order quantum phase transition in a finite system

    International Nuclear Information System (INIS)

    Leviatan, A.

    2006-01-01

    The dynamics at the critical point of a general first-order quantum phase transition in a finite system is examined from an algebraic perspective. Suitable Hamiltonians are constructed whose spectra exhibit coexistence of states corresponding to two degenerate minima in the energy surface separated by an arbitrary barrier. Explicit expressions are derived for wave functions and observables at the critical point

  3. Employment, Production and Consumption model: Patterns of phase transitions

    Czech Academy of Sciences Publication Activity Database

    Lavička, H.; Lin, L.; Novotný, Jan

    2010-01-01

    Roč. 389, č. 8 (2010), s. 1708-1720 ISSN 0378-4371 Institutional research plan: CEZ:AV0Z10480505 Keywords : EPC * Agent based model * Phase transition Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders Impact factor: 1.521, year: 2010

  4. Commensurate-commensurate magnetic phase transitions in CeSb

    DEFF Research Database (Denmark)

    Lebech, Bente; Broholm, C.; Clausen, K.

    1986-01-01

    The q=2/3 to q=4/7 commensurate-commensurate phase transition in CeSb has been studied by neutron diffraction. On cooling the commensurate wave vector q changes abruptly from 2/3 to a higher-order commensurate value (≈14/23) at T1

  5. Dissipative phase transition in the open quantum Rabi model

    Science.gov (United States)

    Hwang, Myung-Joong; Rabl, Peter; Plenio, Martin B.

    2018-01-01

    We demonstrate that the open quantum Rabi model (QRM) exhibits a second-order dissipative phase transition (DPT) and propose a method to observe this transition with trapped ions. The interplay between the ultrastrong qubit-oscillator coupling and the oscillator damping brings the system into a steady state with a diverging number of excitations, in which a DPT is allowed to occur even with a finite number of system components. The universality class of the open QRM, modified from the closed QRM by a Markovian bath, is identified by finding critical exponents and scaling functions using the Keldysh functional integral approach. We propose to realize the open QRM with two trapped ions where the coherent coupling and the rate of dissipation can be individually controlled and adjusted over a wide range. Thanks to this controllability, our work opens a possibility to investigate potentially rich dynamics associated with a dissipative phase transition.

  6. Entanglement growth during Van der Waals like phase transition

    Directory of Open Access Journals (Sweden)

    Hao Xu

    2017-09-01

    Full Text Available We address the problem of describing the coexistence state of two different black holes and Van der Waals like phase transition in Reissner–Nordström–AdS space–time. We start by a small charged black hole, then introduce a collapsing neutral thin-shell described by Vaidya metric to form a large one. The formation of the large black hole does not change the temperature and free energy of the initial state. We discuss the entanglement growing during the phase transition. The transition is always continuous and the saturation time is determined by the final state. It opens a possibility for studying the holography from excited states to excited states.

  7. Universality of phase transition dynamics: topological defects from symmetry breaking

    Energy Technology Data Exchange (ETDEWEB)

    Zurek, Wojciech H. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Del Campo, Adolfo [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2014-02-13

    In the course of a non-equilibrium continuous phase transition, the dynamics ceases to be adiabatic in the vicinity of the critical point as a result of the critical slowing down (the divergence of the relaxation time in the neighborhood of the critical point). This enforces a local choice of the broken symmetry and can lead to the formation of topological defects. The Kibble-Zurek mechanism (KZM) was developed to describe the associated nonequilibrium dynamics and to estimate the density of defects as a function of the quench rate through the transition. During recent years, several new experiments investigating formation of defects in phase transitions induced by a quench both in classical and quantum mechanical systems were carried out. At the same time, some established results were called into question. We review and analyze the Kibble-Zurek mechanism focusing in particular on this surge of activity, and suggest possible directions for further progress.

  8. Transition from boiling to two-phase forced convection

    International Nuclear Information System (INIS)

    Maroti, L.

    1985-01-01

    The paper presents a method for the prediction of the boundary points of the transition region between fully developed boiling and two-phase forced convection. It is shown that the concept for the determination of the onset of fully developed boiling can also be applied for the calculation of the point where the heat transfer is effected again by the forced convection. Similarly, the criterion for the onset of nucleate boiling can be used for the definition of the point where boiling is completely suppressed and pure two-phase forced convection starts. To calculate the heat transfer coefficient for the transition region, an equation is proposed that applies the boundary points and a relaxation function ensuring the smooth transition of the heat transfer coefficient at the boundaries

  9. Antiferromagnetic phase transition and spin correlations in NiO

    DEFF Research Database (Denmark)

    Chatterji, Tapan; McIntyre, G.J.; Lindgård, Per-Anker

    2009-01-01

    We have investigated the antiferromagnetic (AF) phase transition and spin correlations in NiO by high-temperature neutron diffraction below and above TN. We show that AF phase transition is a continuous second-order transition within our experimental resolution. The spin correlations manifested...... by the strong diffuse magnetic scattering persist well above TN530 K and could still be observed at T=800 K which is about 1.5TN. We argue that the strong spin correlations above TN are due to the topological frustration of the spins on a fcc lattice. The Néel temperature is substantially reduced...... by this process. We determined the critical exponents =0.328±0.002 and =0.64±0.03 and the Néel temperature TN=530±1 K. These critical exponents suggest that NiO should be regarded as a 3dXY system...

  10. Effects of phase transition induced density fluctuations on pulsar dynamics

    Directory of Open Access Journals (Sweden)

    Partha Bagchi

    2015-07-01

    Full Text Available We show that density fluctuations during phase transitions in pulsar cores may have non-trivial effects on pulsar timings, and may also possibly account for glitches and anti-glitches. These density fluctuations invariably lead to non-zero off-diagonal components of the moment of inertia, leading to transient wobbling of star. Thus, accurate measurements of pulsar timing and intensity modulations (from wobbling may be used to identify the specific pattern of density fluctuations, hence the particular phase transition, occurring inside the pulsar core. Changes in quadrupole moment from rapidly evolving density fluctuations during the transition, with very short time scales, may provide a new source for gravitational waves.

  11. High pressure phase transitions for CdSe

    Indian Academy of Sciences (India)

    Administrator

    3.1 Ground state structure and thermal equation of state. In the cubic zinc-blende (ZB) and hexagonal wurzite. (WZ) phases, the calculated zero-pressure equilibrium lattice constants, equilibrium cell volume V0, bulk modulus B0 and its pressure derivative Bj0 together with the available experimental (Madelung et al 1982; ...

  12. Insight into black hole phase transition from parametric solutions

    Science.gov (United States)

    Li, Dandan; Li, Shanshan; Mi, Li-Qin; Li, Zhong-Heng

    2017-12-01

    We consider the first-order phase transition of a charged anti-de Sitter black hole and introduce a new dimensionless parameter, ω =(Δ S /π Q2)2 . The parametric solutions of the two reduced volumes are obtained. Each volume is described by a piecewise analytic function. The demarcation point is located at ωd=12 (2 √{3 }-3 ). The volume function is smoothly connected at the point. We show that all properties of the coexistence curve can be studied from the two volume functions. In other words, an arbitrary reduced thermodynamic variable of the two coexisting phases is only a function of ω . Some phase diagrams are plotted by using parametric solutions. We find that, when the reduced pressure P ^>P^A (of order 7.4 ×10-4), the first-order phase transition of the black hole is similar to the van der Waals fluid. However, the similarity disappears when P ^≤P^A. At a van der Waals fluidlike stage, the values of the reduced Gibbs function and the reduced density average are equal. At a non-van der Waals fluid stage, the phase diagrams have extraordinarily rich structure. It is worth pointing out that the phase transition is very important for the low-pressure case since the pressure in essence is the cosmological constant, which is normally very small. Moreover, the thermodynamic behaviors as ω →0 are discussed, from which one can easily obtain some critical exponents and amplitudes for small-large black hole phase transitions.

  13. Quantum Phase Transition and Universal Dynamics in the Rabi Model.

    Science.gov (United States)

    Hwang, Myung-Joong; Puebla, Ricardo; Plenio, Martin B

    2015-10-30

    We consider the Rabi Hamiltonian, which exhibits a quantum phase transition (QPT) despite consisting only of a single-mode cavity field and a two-level atom. We prove QPT by deriving an exact solution in the limit where the atomic transition frequency in the unit of the cavity frequency tends to infinity. The effect of a finite transition frequency is studied by analytically calculating finite-frequency scaling exponents as well as performing a numerically exact diagonalization. Going beyond this equilibrium QPT setting, we prove that the dynamics under slow quenches in the vicinity of the critical point is universal; that is, the dynamics is completely characterized by critical exponents. Our analysis demonstrates that the Kibble-Zurek mechanism can precisely predict the universal scaling of residual energy for a model without spatial degrees of freedom. Moreover, we find that the onset of the universal dynamics can be observed even with a finite transition frequency.

  14. A supersymmetric phase transition in Josephson-tunnel-junction arrays

    International Nuclear Information System (INIS)

    Foda, O.

    1988-01-01

    The fully frustrated XY model in two dimensions exhibits a vortex-unbinding as well as an Ising transition. If the Ising transition overlaps with the critical line that ends on the vortex transition: T I ≤T V , then the model is equivalent, at the overlap temperature, to a free massless field theory of 1 boson and 1 Majorana fermion, which is a superconformal field theory, of central charge c=3/2. The model is experimentally realized in terms of an array of Josephson-tunnel junctions in a transverse magnetic field. The experiment reveals a phase transition consistent with T I =T V . Thus, at the critical temperature, the array provides a physical realization of a supersymmetric quantum field theory. (orig.)

  15. Supersymmetric phase transition in Josephson-tunnel-junction arrays

    Energy Technology Data Exchange (ETDEWEB)

    Foda, O.

    1988-08-31

    The fully frustrated XY model in two dimensions exhibits a vortex-unbinding as well as an Ising transition. If the Ising transition overlaps with the critical line that ends on the vortex transition: T/sub I/less than or equal toT/sub V/, then the model is equivalent, at the overlap temperature, to a free massless field theory of 1 boson and 1 Majorana fermion, which is a superconformal field theory, of central charge c=3/2. The model is experimentally realized in terms of an array of Josephson-tunnel junctions in a transverse magnetic field. The experiment reveals a phase transition consistent with T/sub I/=T/sub V/. Thus, at the critical temperature, the array provides a physical realization of a supersymmetric quantum field theory.

  16. Thermal inclusions: how one spin can destroy a many-body localized phase

    Science.gov (United States)

    Ponte, Pedro; Laumann, C. R.; Huse, David A.; Chandran, A.

    2017-10-01

    Many-body localized (MBL) systems lie outside the framework of statistical mechanics, as they fail to equilibrate under their own quantum dynamics. Even basic features of MBL systems, such as their stability to thermal inclusions and the nature of the dynamical transition to thermalizing behaviour, remain poorly understood. We study a simple central spin model to address these questions: a two-level system interacting with strength J with N≫1 localized bits subject to random fields. On increasing J, the system transitions from an MBL to a delocalized phase on the vanishing scale Jc(N)˜1/N, up to logarithmic corrections. In the transition region, the single-site eigenstate entanglement entropies exhibit bimodal distributions, so that localized bits are either `on' (strongly entangled) or `off' (weakly entangled) in eigenstates. The clusters of `on' bits vary significantly between eigenstates of the same sample, which provides evidence for a heterogeneous discontinuous transition out of the localized phase in single-site observables. We obtain these results by perturbative mapping to bond percolation on the hypercube at small J and by numerical exact diagonalization of the full many-body system. Our results support the arguments that the MBL phase is unstable in systems with short-range interactions and quenched randomness in dimensions d that are high but finite. This article is part of the themed issue 'Breakdown of ergodicity in quantum systems: from solids to synthetic matter'.

  17. Transition barrier at a first-order phase transition in the canonical and microcanonical ensemble

    Science.gov (United States)

    Janke, Wolfhard; Schierz, Philipp; Zierenberg, Johannes

    2017-11-01

    We compare the transition barrier that accompanies a first-order phase transition in the canonical and microcanonical ensemble. This is directly encoded in the probability distributions of standard Metropolis Monte Carlo simulations and a proper microcanonical sampling technique. For the example of droplet formation, we find that in both ensembles the transition barrier scales as expected but that the barrier is much smaller in the microcanonical ensemble. In addition its growth with system size is weaker which will enhance this difference for larger systems. We provide an intuitive physical explanation for this observation.

  18. Thermal barrier coating having high phase stability

    Science.gov (United States)

    Subramanian, Ramesh

    2001-01-01

    A device (10) comprising a substrate (22) having a deposited ceramic thermal barrier coating layer (20) characterized by a microstructure having gaps (28) where the thermal barrier coating (20) consists essentially of a pyrochlore crystal structure having a chemical formula consisting essentially of A.sup.n+.sub.2-x B.sup.m+.sub.2+x O.sub.7-y, where A is selected from the group of elements selected from La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and mixtures thereof; where B is selected from the group of elements selected from Zr, Hf, Ti and mixtures thereof; n and m are the valence of A and B respectively, and for -0.5.ltoreq.x.ltoreq.0.5, ##EQU1## and excluding the following combinations for x=0, y=0: A=La and B=Zr; A=La and B=Hf; A=Gd and B=Hf; and A=Yb and B=Ti.

  19. Low-temperature structure and the ferroelectric phase transitions in the CdTi O3 perovskite

    Science.gov (United States)

    Kennedy, Brendan J.; Zhou, Qingdi; Zhao, Shipeng; Jia, Fanhao; Ren, Wei; Knight, Kevin S.

    2017-12-01

    The paraelectric-ferroelectric transition in CdTi O3 has been monitored using high-resolution neutron diffraction data. This necessitated preparing a sample enriched in 114Cd. A subtle, but significant, anisotropy in the thermal expansion of the lattice parameters for CdTi O3 associated with the transition to the polar structure was observed. First-principles calculations are presented to understand energies, phonon dispersion, and structures of possible phases with different symmetries.

  20. Optimized broad-histogram simulations for strong first-order phase transitions: droplet transitions in the large-Q Potts model

    International Nuclear Information System (INIS)

    Bauer, Bela; Troyer, Matthias; Gull, Emanuel; Trebst, Simon; Huse, David A

    2010-01-01

    The numerical simulation of strongly first-order phase transitions has remained a notoriously difficult problem even for classical systems due to the exponentially suppressed (thermal) equilibration in the vicinity of such a transition. In the absence of efficient update techniques, a common approach for improving equilibration in Monte Carlo simulations is broadening the sampled statistical ensemble beyond the bimodal distribution of the canonical ensemble. Here we show how a recently developed feedback algorithm can systematically optimize such broad-histogram ensembles and significantly speed up equilibration in comparison with other extended ensemble techniques such as flat-histogram, multicanonical and Wang–Landau sampling. We simulate, as a prototypical example of a strong first-order transition, the two-dimensional Potts model with up to Q = 250 different states in large systems. The optimized histogram develops a distinct multi-peak structure, thereby resolving entropic barriers and their associated phase transitions in the phase coexistence region—such as droplet nucleation and annihilation, and droplet–strip transitions for systems with periodic boundary conditions. We characterize the efficiency of the optimized histogram sampling by measuring round-trip times τ(N, Q) across the phase transition for samples comprised of N spins. While we find power-law scaling of τ versus N for small Q∼ 2 , we observe a crossover to exponential scaling for larger Q. These results demonstrate that despite the ensemble optimization, broad-histogram simulations cannot fully eliminate the supercritical slowing down at strongly first-order transitions