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Sample records for thermal mixing process

  1. Thermal processing systems for TRU mixed waste

    International Nuclear Information System (INIS)

    Eddy, T.L.; Raivo, B.D.; Anderson, G.L.

    1992-01-01

    This paper presents preliminary ex situ thermal processing system concepts and related processing considerations for remediation of transuranic (TRU)-contaminated wastes (TRUW) buried at the Radioactive Waste Management Complex (RWMC) of the Idaho National Engineering Laboratory (INEL). Anticipated waste stream components and problems are considered. Thermal processing conditions required to obtain a high-integrity, low-leachability glass/ceramic final waste form are considered. Five practical thermal process system designs are compared. Thermal processing of mixed waste and soils with essentially no presorting and using incineration followed by high temperature melting is recommended. Applied research and development necessary for demonstration is also recommended

  2. Demonstration of a batch vacuum thermal desorption process on hazardous and mixed waste

    International Nuclear Information System (INIS)

    Palmer, C.R.; McElwee, M.; Meyers, G.

    1995-01-01

    Many different waste streams have been identified at Department of Energy (DOE) facilities as having both hazardous organic and radioactive contaminants. There is presently only one permitted facility in which to manage these materials, and that facility has only limited capacity to process solid wastes. Over the past two years, Rust has been pilot testing a new thermal desorption process that is very well suited to these wastes, and has begun permitting and design of a unit for commercial operation. This paper presents both historic and recent pilot test data on the treatment of hazardous and mixed waste. Also described is the commercial unit. Rust's patented VAC*TRAX technology takes advantage of high vacuum to reduced operating temperature for the thermal desorption of organic contaminants from waste soils, sludges and other contaminated solids. This allows for economical thermal separation on relatively small sites (30 to 5,000 m 3 of waste). VAC*TRAX employs indirect heating; this, combined with a very low carrier gas flow, results in a vent flow rate of approximately 1 m 3 /min which allows for the use of control devices that would not be practical with conventional thermal technology. The unit is therefore ideally suited to processing mixed waste, since zero radioactive emissions can be maintained. An additional benefit of the technology is that the low operating temperature allows highly effective separation to be performed well below the degradation point for the solid components of a trash type waste stream, which constitutes a large fraction of the present mixed waste inventory

  3. Thermal mixing of two miscible fluids in a T-shaped microchannel.

    Science.gov (United States)

    Xu, Bin; Wong, Teck Neng; Nguyen, Nam-Trung; Che, Zhizhao; Chai, John Chee Kiong

    2010-10-01

    In this paper, thermal mixing characteristics of two miscible fluids in a T-shaped microchannel are investigated theoretically, experimentally, and numerically. Thermal mixing processes in a T-shaped microchannel are divided into two zones, consisting of a T-junction and a mixing channel. An analytical two-dimensional model was first built to describe the heat transfer processes in the mixing channel. In the experiments, de-ionized water was employed as the working fluid. Laser induced fluorescence method was used to measure the fluid temperature field in the microchannel. Different combinations of flow rate ratios were studied to investigate the thermal mixing characteristics in the microchannel. At the T-junction, thermal diffusion is found to be dominant in this area due to the striation in the temperature contours. In the mixing channel, heat transfer processes are found to be controlled by thermal diffusion and convection. Measured temperature profiles at the T-junction and mixing channel are compared with analytical model and numerical simulation, respectively.

  4. Study on convective mixing for thermal striping phenomena. Thermal-hydraulic analyses on mixing process in parallel triple-jet and comparisons between numerical methods

    International Nuclear Information System (INIS)

    Kimura, Nobuyuki; Nishimura, Motohiko; Kamide, Hideki

    2000-03-01

    A quantitative evaluation on thermal striping, in which temperature fluctuation due to convective mixing among jets imposes thermal fatigue on structural components, is of importance for reactor safety. In the present study, a water experiment was performed on parallel triple-jet: cold jet at the center and hot jets in both sides. Three kinds of numerical analyses based on the finite difference method were carried out to compare the similarity with the experiment by use of respective different handling of turbulence such as a k-ε two equation turbulence model (k-ε Model), a low Reynolds number stress and heat flux equation model (LRSFM) and a direct numerical simulation (DNS). In the experiment, the jets were mainly mixed due to the coherent oscillation. The numerical result using k-ε Model could not reproduce the coherent oscillating motion of jets due to rolling-up fluid. The oscillations of the jets predicted by LRSFM and DNS were in good agreements with the experiment. The comparison between the coherent and random components in experimental temperature fluctuation obtained by using the phase-averaging shows that k-ε Model and LRSFM overestimated the random component and the coherent component respectively. The ratios of coherent to random components in total temperature fluctuation obtained from DNS were in good agreements with the experiment. The numerical analysis using DNS can reproduce the coherent oscillation of the jets and the coherent / random components in temperature fluctuation. The analysis using LRSFM could simulate the mixing process of the jets with the low frequency. (author)

  5. Pressure supression pool thermal mixing

    International Nuclear Information System (INIS)

    Cook, D.H.

    1984-10-01

    A model is developed and verified to describe the thermal mixing that occurs in the pressure suppression pool (PSP) of a commercial BWR. The model is designed specifically for a Mark-I containment and is intended for use in severe accident sequence analyses. The model developed in this work produces space and time dependent temperature results throughout the PSP and is useful for evaluating the bulk PSP thermal mixing, the condensation effectiveness of the PSP, and the long-term containment integrity. The model is designed to accommodate single or multiple discharging T-quenchers, a PSP circumferential circulation induced by the residual heat removal system discharge, and the thermal stratification of the pool that occurs immediately after the relief valves close. The PSP thermal mixing is verified by comparing the model-predicted temperatures to experimental temperatures that were measured in an operating BWR suppression pool. The model is then used to investigate several PSP thermal mixing problems that include the time to saturate at full relief valve flow, the temperature response to a typical stuck open relief valve scenario, and the effect of operator rotation of the relief valve discharge point

  6. Pressure suppression pool thermal mixing

    International Nuclear Information System (INIS)

    Cook, D.H.

    1984-01-01

    A model is developed and verified to describe the thermal mixing that occurs in the pressure suppression pool (PSP) of a commercial BWR. The model is designed specifically for a Mark-I containment and is intended for use in severe accident sequence analyses. The model produces space and time dependent temperature results throughout the PSP and is useful for evaluating the bulk PSP thermal mixing, the condensation effectiveness of the PSP, and the long-term containment integrity. The model is designed to accommodate single or multiple discharging T-quenchers, a PSP circumferential circulation induced by the residual heat removal system discharge, and the thermal stratification of the pool that occurs immediately after the relief valves close. The PSP thermal mixing model is verified by comparing the model predicted temperatures to experimental temperatures that were measured in an operating BWR suppression pool. The model is then used to investigate several PSP thermal mixing problems that include the time to saturate at full relief valve flow, the temperature response to a typical stuck open relief valve scenario, and the effect of operator rotation of the relief valve discharge point

  7. Reducing of thermal power energy-intensive pro-cesses costs in the mixed fodders technology

    Directory of Open Access Journals (Sweden)

    L. I. Lytkina

    2016-01-01

    Full Text Available Methodological approach to the creation of energy-efficient processes with direct involvement in the produc-tion process of heat pump technology for the preparation of of energy resources in obtaining of mixed fodders of the given particle size distribution was formed. Completed experimental and analytical studies paved the way for the development of energy efficient technolo-gies of mixed fodders with a vapor compression connection (VCHP and steam ejector (SEHP heat pumps on the closed thermody-namic schemes. It was shown that the strategy of the operational management of process parameters in the allowable technological properties of the resulting mixed fodder production does not allow a compromise between the conflicting technical and economic param-eters and let the main technical contradiction between productivity and power consumption. The control problem becomes much more complicated when there is no practical possibility of a detailed description of thermal processes occurring in the closed thermodynamic recycles based on the phenomenological laws of thermodynamics considering a balance of material and energy flows in the technologi-cal system. There is a need for adaptive control systems based on the extreme characteristics of the controlled object. The adaptation effect is achieved by obtaining information about the processes occurring in the conditions of technological line of mixed fodders pro-duction equalized particle size distribution, which allows to generate a control signal for the extreme value of the objective function. The scheme of automatic optimization ensuring continuous monitoring of the minimum value of the specific heat energy costs is proposed. It provides optimal consumption of the starting loose mixed fodder and rational strain on the line equipment.

  8. CFD simulation for thermal mixing of a SMART flow mixing header assembly

    International Nuclear Information System (INIS)

    Kim, Young In; Bae, Youngmin; Chung, Young Jong; Kim, Keung Koo

    2015-01-01

    Highlights: • Thermal mixing performance of a FMHA installed in SMART is investigated numerically. • Effects of operating condition and discharge hole configuration are examined. • FMHA performance satisfies the design requirements under various abnormal conditions. - Abstract: A flow mixing header assembly (FMHA) is installed in a system-integrated modular advanced reactor (SMART) to enhance the thermal mixing capability and create a uniform core flow distribution under both normal operation and accident conditions. In this study, the thermal mixing characteristics of the FMHA are investigated for various steam generator conditions using a commercial CFD code. Simulations include investigations for the effects of FMHA discharge flow rate differences, turbulence models, and steam generator conditions. The results of the analysis show that the FMHA works effectively for thermal mixing in various conditions and makes the temperature difference at the core inlet decrease noticeably. We verified that the mixing capability of the FMHA is excellent and satisfies the design requirement in all simulation cases tested here

  9. Experimental investigation of thermal mixing phenomena in a tee pipe

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Mei-Shiue; Hsieh, Huai-En; Zhang, Zhi-Yu; Pei, Bau-Shi [National Tsing Hua Univ., Taiwan (China). Inst. of Nuclear Engineering and Science

    2015-05-15

    T-pipe designs have been widely used in the industry. Among them, mixing of hot and cold water is a common application. In the mixing process, cold and hot fluids are respectively injected through main and branch pipes, and are mixed in the downstream area of T-tube. High temperature hot water flows through the main pipe for a long time; hence, the pipe wall is at high temperatures. The fluid injected into the branch pipe is a cooling fluid. After mixing, the wall of the main pipe is under high thermal fluctuations causing strong thermal stresses, which will eventually lead to pipe damage and water loss. Through flow rate adjustments of the branch and main pipes, when the branch/main velocity ratio was greater than 7.8, showing that cold water hit the bottom of the main pipe and created a reverse flow. This reverse flow created large thermal stresses on the wall. Hence, the branch/main velocity ratio and the hot-water-mixing phenomenon are the focus of this study.

  10. Development of the fluidized bed thermal treatment process for treating mixed waste

    International Nuclear Information System (INIS)

    Semones, G.B.; Williams, P.M.; Stiefvater, S.P.; Mitchell, D.L.; Roecker, B.D.

    1993-01-01

    A fluidized bed system is being developed at Rocky Flats for the treatment of mixed waste (a mixture of radioactive and chemically hazardous waste). The current program builds on experience gained in the 1970's and 1980's in tests with bench-scale, pilot-scale, and demonstration-scale fluidized bed systems. The system operates at low temperatures (∼ 525--600 degree C) which eliminates many of the disadvantages associated with high temperature thermal treatment processes. The process has shown the ability to destroy polychlorinated biphenyls (PCB's) with 99.9999% (''six-nines'') destruction efficiency in tests monitored by the Environmental Protection Agency (EPA). The bed makes use of in situ neutralization of acidic off-gases by incorporating sodium carbonate (Na 2 CO 3 ) in the bed media. This eliminates using wet scrubbers to treat the off-gas; these produce a high volume of secondary waste. Once in operation, it is expected that the fluidized bed process will yield up to a 40:1 reduction in the volume of the waste

  11. Thermal mixing characteritics during a postulated PTS event

    International Nuclear Information System (INIS)

    Jung, Jae Won; Bang, Young Seok; Seul, Kwang Won; Kim, Hho Jung

    1998-01-01

    The present study aims to investigate the characteristics of thermal fluid mixing during a postulated loss of coolant accident (LOCA) under two-phase flow condition using RELAP5 code. The RELAP5 code has been widely used in estimating global system thermal-hydraulic behaviors. However, the RELAP5 is not fully verified for the prediction of thermal mixing phenomena due to its limitation to the multi-dimensional behavior. Therefore, supplementary analysis is required, which can address the performance and limitation of the current RELAP5 code in predicting the thermal mixing. Another objective of this study is to compare the applicable empirical correlation (Theofanous') and the calculation of simple mixing code (REMIX) with one predicted by RELAP5. By those comparisons the capability on PTS thermal mixing of the current RELAP5 can be evaluated. In this study, thermal mixing behavior is analyzed for the task of the international comparative assessment study on PTS (PTS-ICAS) which was proposed by OECD-NEA. Through some preliminary calculations using RELAP5, the boundary conditions relevant to the problem constraints are appropriately specified with some artificial assumptions. As a calculation results, system pressure, downcomer water level, wall heat transfer coefficient, etc., are predicted as suitable for given problem constraints. From the predicted thermal hydraulic behavior, it is shown that the thermal stratification begins to start around 200 seconds after high pressure safety injection. At 400 seconds, the maximum difference in azimuthal temperature distribution at the downcomer due to thermal mixing is predicted about 150 K. Based on the comparison of the current RELAP5 prediction with the Theofanous' correlation and the REMIX calculation, it is found that thermal stratification characteristics predicted by RELAP5 is agreed in qualitative manner to the empirical correlation

  12. Does the thermal spike affect low energy ion-induced interfacial mixing?

    International Nuclear Information System (INIS)

    Suele, P.; Menyhard, M.; Nordlund, K.

    2003-01-01

    Molecular dynamics simulations have been used to obtain the three-dimensional distribution of interfacial mixing and cascade defects in Ti/Pt multilayer system due to single 1 keV Ar + impact at grazing angle of incidence. The Ti/Pt system was chosen because of its relatively high heat of mixing in the binary alloy and therefore a suitable candidate for testing the effect of heat of mixing on ion-beam mixing. However, the calculated mixing profile is not sensitive to the heat of mixing. Therefore the thermal spike model of mixing is not fully supported under these irradiation conditions. Instead we found that the majority of mixing occurs after the thermal spike during the relaxation process. These conclusions are supported by liquid, vacancy as well as adatom analysis. The interfacial mixing is in various aspects anomalous in this system: the time evolution of mixing is leading to a phase delay for Ti mixing, and Pt exhibits an unexpected double peaked mixing evolution. The reasons to these effects are discussed

  13. Thermal fatigue. Fluid-structure interaction at thermal mixing events

    International Nuclear Information System (INIS)

    Schuler, X.; Herter, K.H.; Moogk, S.; Laurien, E.; Kloeren, D.; Kulenovic, R.; Kuschewski, M.

    2012-01-01

    In the framework of the network research project ''Thermal Fatigue - Basics of the system-, outflow- and material-characteristics of piping under thermal fatigue'' funded by the German Federal Ministry of Education and Research (BMBF) fundamental numerical and experimental investigations on the material behaviour under transient thermal-mechanical stress conditions (high cycle fatigue - HCF) are carried out. The project's background and its network of scientific working groups with their individual working tasks are briefly introduced. The main focus is especially on the joint research tasks within the sub-projects of MPA and IKE which are dealing with thermal mixing of flows in a T-junction configuration and the fluidstructure- interactions (FSI). Therefore, experiments were performed with the newly established FSI test facility at MPA which enables single-phase flow experiments of water in typical power plant piping diameters (DN40 and DN80) at high pressure (maximum 75 bar) and temperatures (maximum 280 C). The experimental results serve as validation data base for numerical modelling of thermal flow mixing by means of thermo-fluid dynamics simulations applying CFD techniques and carried out by IKE as well as for modelling of thermal and mechanical loads of the piping structure by structural mechanics simulations with FEM methods which are executed by MPA. The FSI test facility will be described inclusively the applied measurement techniques, e. g. in particular the novel near-wall LED-induced Fluorescence method for non-intrusive flow temperature measurements. First experimental data and numerical results from CFD and FEM simulations of the thermal mixing of flows in the T-junction are presented.

  14. Thermal fatigue. Fluid-structure interaction at thermal mixing events

    Energy Technology Data Exchange (ETDEWEB)

    Schuler, X.; Herter, K.H.; Moogk, S. [Stuttgart Univ. (Germany). MPA; Laurien, E.; Kloeren, D.; Kulenovic, R.; Kuschewski, M. [Stuttgart Univ. (Germany). Inst. of Nuclear Technology and Energy Systems

    2012-07-01

    In the framework of the network research project ''Thermal Fatigue - Basics of the system-, outflow- and material-characteristics of piping under thermal fatigue'' funded by the German Federal Ministry of Education and Research (BMBF) fundamental numerical and experimental investigations on the material behaviour under transient thermal-mechanical stress conditions (high cycle fatigue - HCF) are carried out. The project's background and its network of scientific working groups with their individual working tasks are briefly introduced. The main focus is especially on the joint research tasks within the sub-projects of MPA and IKE which are dealing with thermal mixing of flows in a T-junction configuration and the fluidstructure- interactions (FSI). Therefore, experiments were performed with the newly established FSI test facility at MPA which enables single-phase flow experiments of water in typical power plant piping diameters (DN40 and DN80) at high pressure (maximum 75 bar) and temperatures (maximum 280 C). The experimental results serve as validation data base for numerical modelling of thermal flow mixing by means of thermo-fluid dynamics simulations applying CFD techniques and carried out by IKE as well as for modelling of thermal and mechanical loads of the piping structure by structural mechanics simulations with FEM methods which are executed by MPA. The FSI test facility will be described inclusively the applied measurement techniques, e. g. in particular the novel near-wall LED-induced Fluorescence method for non-intrusive flow temperature measurements. First experimental data and numerical results from CFD and FEM simulations of the thermal mixing of flows in the T-junction are presented.

  15. Thermal fluid mixing behavior during medium break LOCA in evaluation of pressurized thermal shock

    International Nuclear Information System (INIS)

    Jung, Jae Won; Bang, Young Seok; Seul, Kwang Won; Kim, Hho Jung

    1998-01-01

    Thermal fluid mixing behavior during a postulated medium-size hot leg break loss of coolant accident is analyzed for the international comparative assessment study on pressurized thermal shock (PTS-ICAS) proposed by OECD-NEA. the applicability of RELAP5 code to analyze the thermal fluid mixing behavior is evaluated through a simple modeling relevant to the problem constraints. Based on the calculation result, the onset of thermal stratification is investigated using Theofanous's empirical correlation. Sensitivity calculations using a fine node model and crossflow model are also performed to evaluate the modeling capability on multi-dimensional characteristics related to thermal fluid mixing

  16. Thermal fluid mixing behavior during medium break LOCA in evaluation of pressurized thermal shock

    Energy Technology Data Exchange (ETDEWEB)

    Jung, Jae Won; Bang, Young Seok; Seul, Kwang Won; Kim, Hho Jung [Korea Institute of Nuclear Safety, Taejon (Korea, Republic of)

    1998-12-31

    Thermal fluid mixing behavior during a postulated medium-size hot leg break loss of coolant accident is analyzed for the international comparative assessment study on pressurized thermal shock (PTS-ICAS) proposed by OECD-NEA. The applicability of RELAP5 code to analyze the thermal fluid mixing behavior is evaluated through a simple modeling relevant to the problem constraints. Based on the calculation result, the onset of thermal stratification is investigated using Theofanous`s empirical correlation. Sensitivity calculations using a fine node model and crossflow model are also performed to evaluate the modeling capability on multi-dimensional characteristics related to thermal fluid mixing. 6 refs., 8 figs. (Author)

  17. Hanford Site radioactive mixed waste thermal treatment initiative

    International Nuclear Information System (INIS)

    Place, B.G.; Riddelle, J.G.

    1993-03-01

    This paper is a progress report of current Westinghouse Hanford Company engineering activities related to the implementation of a program for the thermal treatment of the Hanford Site radioactive mixed waste. Topics discussed include a site-specific engineering study, the review of private sector capability in thermal treatment, and thermal treatment of some of the Hanford Site radioactive mixed waste at other US Department of Energy sites

  18. VAC*TRAX - Thermal desorption for mixed wastes

    International Nuclear Information System (INIS)

    McElwee, M.J.; Palmer, C.R.

    1995-01-01

    The patented VAC*TRAX process was designed in response to the need to remove organic constituents from mixed waste, waste that contains both a hazardous (RCRA or TSCA regulated) component and a radioactive component. Separation of the mixed waste into its hazardous and radioactive components allows for ultimate disposal of the material at existing, permitted facilities. The VAC*TRAX technology consists of a jacketed vacuum dryer followed by a condensing train. Solids are placed in the dryer and indirectly heated to temperatures as high as 260 degrees C, while a strong vacuum (down to 50 mm Hg absolute pressure) is applied to the system and the dryer is purged with a nitrogen carrier gas. The organic contaminants in the solids are thermally desorbed, swept up in the carrier gas and into the condensing train where they are cooled and recovered. The dryer is fitted with a filtration system that keeps the radioactive constituents from migrating to the condensate. As such, the waste is separated into hazardous liquid and radioactive solid components, allowing for disposal of these streams at a permitted incinerator or a radioactive materials landfill, respectively. The VAC*TRAX system is designed to be highly mobile, while minimizing the operational costs with a simple, robust process. These factors allow for treatment of small waste streams at a reasonable cost. This paper describes the VAC*TRAX thermal desorption process, as well as results from the pilot testing program. Also, the design and application of the full-scale treatment system is presented. Materials tested to date include spiked soil and debris, power plant trash and sludge contaminated with solvents, PCB contaminated soil, solvent-contaminated uranium mill-tailings, and solvent and PCB-contaminated sludge and trash. Over 70 test runs have been performed using the pilot VAC*TRAX system, with more than 80% of the tests using mixed waste as the feed material

  19. Thermal fatigue crack growth in mixing tees nuclear piping - An analytical approach

    International Nuclear Information System (INIS)

    Radu, V.

    2009-01-01

    The assessment of fatigue crack growth due to cyclic thermal loads arising from turbulent mixing presents significant challenges, principally due to the difficulty of establishing the actual loading spectrum. So-called sinusoidal methods represent a simplified approach in which the entire spectrum is replaced by a sine-wave variation of the temperature at the inner pipe surface. The need for multiple calculations in this process has lead to the development of analytical solutions for thermal stresses in a pipe subject to sinusoidal thermal loading, described in previous work performed at JRC IE Petten, The Netherlands, during the author's stage as seconded national expert. Based on these stress distributions solutions, the paper presents a methodology for assessment of thermal fatigue crack growth life in mixing tees nuclear piping. (author)

  20. Unvented thermal process for treatment of hazardous and mixed wastes

    International Nuclear Information System (INIS)

    Nelson, P.A.; Swift, W.M.

    1993-01-01

    An Unvented Thermal Process is being developed that does not release gases during the thermal treatment operation. The main unit in the process is a fluidized-bed processor containing a bed of calcined limestone (CaO), which reacts with gases given off during oxidation of organic materials. Gases that will react with CaO include CO 2 , SO 2 , HCI, HBr, and other acid gases. Water vapor formed during the oxidation process is carried off with the fluidizing gas and is removed in a condenser. Oxygen is added to the remaining gas (mainly nitrogen), which is recirculated to the oxidizer. The most flexible arrangement of equipment involves separating the processor into two units: An oxidizer, which may be any of a variety of types including standard incinerators, and a carbon dioxide sorber

  1. Heats of Mixing Using an Isothermal Titration Calorimeter: Associated Thermal Effects

    Directory of Open Access Journals (Sweden)

    Fabiola Socorro

    2009-06-01

    Full Text Available The correct determination of the energy generated or absorbed in the sample cell of an Isothermal Titration Calorimeter (ITC requires a thorough analysis of the calorimetric signal. This means the identification and quantification of any thermal effect inherent to the working method. In this work, it is carried out a review on several thermal effects, studied by us in previous work, and which appear when an ITC is used for measuring the heats of mixing of liquids in a continuous mode. These effects are due to: (i the difference between the temperature of the injected liquid and the temperature of the mixture during the mixing process, (ii the increase of the liquid volume located in the mixing cell and (iii the stirring velocity. Besides, methods for the identification and quantification of the mentioned effects are suggested.

  2. DOE evaluates nine alternative thermal technologies for treatment of mixed waste

    International Nuclear Information System (INIS)

    Anon.

    1995-01-01

    In June 1993, the U.S. Department of Energy's (DOE's) Office of Technology Development commissioned a study to evaluate 19 thermal technologies for treating DOE's mixed waste. The study was divided into two phases: Phase I evaluated ten conventional incineration techniques (primarily rotary kiln), and Phase II looked at nine innovative, alternative thermal treatment technologies. The treatment processes were evaluated as part of an integrated waste treatment system, which would include all of the facilities, equipment, and methods required to treat and dispose DOE mixed waste. The relative merits and life-cycle costs were then developed for each of the 19 waste treatment systems evaluated. The study also identified the additional research and development, demonstration, and testing/evaluation steps that would be necessary for the waste treatment systems to successfully treat DOE mixed waste. 3 tabs., 2 refs

  3. Establishment of a JSME code for the evaluation of high-cycle thermal fatigue in mixing tees

    International Nuclear Information System (INIS)

    Moriya, Shoichi; Fukuda, Toshihiko; Matsunaga, Tomoya; Hirayama, Hiroshi; Shiina, Kouji; Tanimoto, Koichi

    2004-01-01

    This paper describes a JSME code for high-cycle thermal fatigue evaluation by thermal striping in mixing tees with hot and cold water flows. The evaluation of thermal striping in a mixing tee has four steps to screen design parameters one-by-one according to the severity of the thermal load assessed from design conditions using several evaluation charts. In order to make these charts, visualization tests with acrylic pipes and temperature measurement tests with metal pipes were conducted. The influence of the configurations of mixing tees, flow velocity ratio, pipe diameter ratio and so on was examined from the results of the experiments. This paper makes a short mention of the process of providing these charts. (author)

  4. Study of thermal stratification and mixing using PIV

    International Nuclear Information System (INIS)

    Yamaji, B.; Szijarto, R.; Aszodi, A.

    2010-01-01

    Paks Nuclear Power Plant uses the REMIX code for the calculation of the coolant mixing in case of the use of high pressure injection system while stagnating flow is present. The use of the code for Russian type WWER-440 reactors needs strict conservative approach, and in several cases the accuracy and the reserves to safety margins cannot be determined now. In order to quantify and improve these characteristics experimental validation of the code is needed. An experimental program has been launched at Institute of Nuclear Techniques with the aim of investigating thermal stratification processes and the mixing of plumes in simple geometries. With the comparison and evaluation of measurement and computational fluid dynamics result computational models can be validated. For the experiments a simple hexahedral plexiglas tank (250 x 500 x 100 mm - H x L x D) was fabricated with five nozzles attached, which can be set up as inlets or outlets. With different inlet and outlet setups and temperature differences thermal stratification, plume mixing may be investigated using Particle Image Velocimetry. In the paper comparison of Particle Image Velocimetry measurements carried out on the plexiglas tank and the results of simulations will be presented. For the calculations the ANSYS CFX three-dimensional computational fluid dynamics code was used. (Authors)

  5. Experimental observations of thermal mixing characteristics in T-junction piping

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Mei-Shiue, E-mail: chenms@mx.nthu.edu.tw; Hsieh, Huai-En; Ferng, Yuh-Ming; Pei, Bau-Shi

    2014-09-15

    Highlights: • The effects of flow velocity ratio on thermal mixing phenomenon are the major parameters. • The flow velocity ratio (V{sub b}/V{sub m}) is greater than 13.6, reverse flow occurs. • The flow velocity ratio is greater than 13.7, a “good” mixing quality is achieved. - Abstract: The T-junction piping is frequently used in many industrial applications, including the nuclear plants. For a pressurized water reactor (PWR), the emergency core cooling systems (ECCS) inject cold water into the primary loops if a loss-of-coolant accident (LOCA) happens. Inappropriate mixing of the two streams with significant temperature different at a junction may cause strong thermal stresses to the downstream structures in the reactor vessel. The downstream structures may be damaged. This study is an experimental investigation into the thermal mixing effect occurring at a T-junction. A small-scale test facility was established to observe the mixing effect of flows with different temperature. Thermal mixing effect with different flow rates in the main and branch pipes are investigated by measuring the temperature distribution along the main pipe. In test condition I, we found that lower main pipe flow rate leads to better mixing effect with constant branch pipe flow rate. And in conditions II and III, higher injection flow velocity would enhance the turbulence effect which results in better thermal mixing. The results will be useful for applications with mixing fluids with different temperature.

  6. Low Thermal Pretreatment as Method for Increasing the Bioavailability of Organic Matters in Domestic Mixed Sludge

    Directory of Open Access Journals (Sweden)

    Seswoya Roslinda

    2016-01-01

    Full Text Available In practice, primary and secondary sludge are fed into anaerobic digestion. However, the microbial cell exists in secondary sludge are an unfavorable substrate for biodegradation. Thermal pretreatment is proved to increase the bioavailability of organic and improve the biodegradation subsequently. During low thermal pretreatment, both intracellular (within the microbial cell and extracellular (within the polymeric network materials were extracted. This process increases the bioavailability meaning that organic compounds are accessible to the microorganisms for their degradation. This research aims to investigate the effect of thermal pretreatment on domestic mixed sludge disintegration. Domestic mixed sludge was thermally treated at 70°C for various holding times. The pre-thermally treated domestic mixed sludge was measured for protein and carbohydrates following the Lowry Method, and Phenol-Sulphuric Acid Method respectively. DR 6000 UV-Vis spectrophotometer, DRB200 Reactor (digester and COD vial (TNT plus 822 were used for COD determination, based on Reactor Digestion Method approved by USEPA. The results showed that the organic matter in domestic mixed sludge is efficiently solubilised during thermal treatment organic matter. The higher soluble yield for each monitored parameter determined in this study indicated that low thermal pretreatment improve bioavailability.

  7. Thermal mixing in T-junction piping system concerned with high-cycle thermal fatigue in structure

    International Nuclear Information System (INIS)

    Tanaka, Masaaki; Ohshima, Hiroyuki; Monji, Hideaki

    2008-01-01

    In Japan Atomic Energy Agency (JAEA), a numerical simulation code 'MUGTHES' has been developed to investigate thermal striping phenomena caused by turbulence mixing of fluids in different temperature and to provide transient data for an evaluation method of high-cycle thermal fatigue. MUGTHES adopts Large Eddy Simulation (LES) approach to predict unsteady phenomena in thermal mixing and employs boundary fitted coordinate system to be applied to complex geometry in a power reactor. Numerical simulation of thermal striping phenomena in a T-junction piping system (T-pipe) is conducted. Boundary condition for the simulation is chosen from an existing water experiment in JAEA, named as WATLON experiment. In the numerical simulation, standard Smagorinsky model is employed as eddy viscosity model with the model coefficient of 0.14 (=Cs). Numerical results of MUGTHES are verified by the comparisons with experimental results of velocity and temperature. Through the numerical simulation in the T-pipe, applicability of MUGTHES to the thermal striping phenomena is confirmed and the characteristic large-scale eddy structure which dominates thermal mixing and may cause high-cycle thermal fatigue is revealed. (author)

  8. Design and implementation of mixing chambers to improve thermal decomposition of urea for NOX abatement

    KAUST Repository

    Lee, Junggil

    2012-10-01

    Urea-selective catalytic reduction (SCR) has been reported as the most promising technique for adherence to NOX emissions regulations. In the urea-SCR process, NH3 is generated by urea thermal decomposition and hydrolysis and is then used as a reductant of NOX in the SCR catalyst. Therefore, improving the NOX conversion efficiency of urea-SCR requires enhancement of thermal decomposition upstream of the SCR catalyst. In the present work, two types of mixing chambers were designed and fabricated to improve urea thermal decomposition, and experiments with and without a mixing chamber were carried out to analyze thermal-decomposition characteristics of urea in the exhaust pipe with respect to inlet velocity (4-12μm/s) and temperature (350°C-500°C). Urea thermal decomposition is greatly enhanced at higher gas temperatures. At an inlet velocity of 6μm/s in the A-type mixing chamber, NH3 concentrations generated along the exhaust pipe were about 171% and 157% greater than those without the mixing chamber for inlet temperatures of 400°C and 500°C, respectively. In the case of the B-type mixing chamber, NH3 concentrations generated at inlet temperatures of 400°C and 500°C were about 147% and 179% greater than those without the mixing chamber, respectively. Note that the implementation of mixing chambers significantly enhanced conversion of urea to NH3 because it increased the residence time of urea in the exhaust pipe and improved mixing between urea and exhaust gas. © 2012, Mary Ann Liebert, Inc.

  9. Thermal hazard assessment of TMCH mixed with inorganic acids

    Directory of Open Access Journals (Sweden)

    Yeh Chi-Tang

    2018-01-01

    Full Text Available 1,1-Bis(tert-butylperoxy-3,3,5-trimethylcyclohexane (TMCH is a typical peroxide with two peroxy groups that may runaway and/or explode due to mixing with inorganic acids, such as HCl, HNO3, H2SO4, or H3PO4. In this study, reactivities of TMCH mixed with the above inorganic acids were assessed by differential scanning calorimetry (DSC. Furthermore, data obtained by DSC, such as exothermic onset temperature (T0, maximum temperature (Tmax, and heat of decomposition (ΔHd could be employed to acquire thermal safety parameters. Moreover, thermal activity monitor III (TAM III was employed to investigate the thermal hazards while storing or transporting TMCH and TMCH mixed with four types of commonly used inorganic acids, here as HCl, HNO3, H2SO4, or H3PO4 under isothermal conditions. Mixing TMCH with those inorganic acids resulted in higherΔHd except H3PO4, and mixing TMCH with HCl clearly decreased T0. Therefore, the phenomena of mixing those incompatible materials with TMCH can be concluded as the worst cases in terms of contamination hazards during storage and transportation of TMCH.

  10. Experiment study on thermal mixing performance of HTR-PM reactor outlet

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, Yangping, E-mail: zhouyp@mail.tsinghua.edu.cn [Institute of Nuclear and New Energy Technology, Collaborative Innovation Center of Advanced Nuclear Energy Technology, the Key Laboratory of Advanced Reactor Engineering and Safety, Ministry of Education, Tsinghua University, Beijing 100084 (China); Hao, Pengfei [School of Aerospace, Tsinghua University, Beijing 100084 (China); Li, Fu; Shi, Lei [Institute of Nuclear and New Energy Technology, Collaborative Innovation Center of Advanced Nuclear Energy Technology, the Key Laboratory of Advanced Reactor Engineering and Safety, Ministry of Education, Tsinghua University, Beijing 100084 (China); He, Feng [School of Aerospace, Tsinghua University, Beijing 100084 (China); Dong, Yujie; Zhang, Zuoyi [Institute of Nuclear and New Energy Technology, Collaborative Innovation Center of Advanced Nuclear Energy Technology, the Key Laboratory of Advanced Reactor Engineering and Safety, Ministry of Education, Tsinghua University, Beijing 100084 (China)

    2016-09-15

    A model experiment is proposed to investigate the thermal mixing performance of HTR-PM reactor outlet. The design of the test facility is introduced, which is set at a scale of 1:2.5 comparing with the design of thermal mixing structure at HTR-PM reactor outlet. The test facility using air as its flow media includes inlet pipe system, electric heaters, main mixing structure, hot gas duct, exhaust pipe system and I&C system. Experiments are conducted on the test facility and the values of thermal-fluid parameters are collected and analyzed, which include the temperature, pressure and velocity of the flow as well as the temperature of the tube wall. The analysis results show the mixing efficiency of the test facility is higher than that required by the steam generator of HTR-PM, which indicates that the thermal mixing structure of HTR-PM fulfills its design requirement.

  11. Experience base for Radioactive Waste Thermal Processing Systems: A preliminary survey

    International Nuclear Information System (INIS)

    Mayberry, J.; Geimer, R.; Gillins, R.; Steverson, E.M.; Dalton, D.; Anderson, G.L.

    1992-04-01

    In the process of considering thermal technologies for potential treatment of the Idaho National Engineering Laboratory mixed transuranic contaminated wastes, a preliminary survey of the experience base available from Radioactive Waste Thermal Processing Systems is reported. A list of known commercial radioactive waste facilities in the United States and some international thermal treatment facilities are provided. Survey focus is upon the US Department of Energy thermal treatment facilities. A brief facility description and a preliminary summary of facility status, and problems experienced is provided for a selected subset of the DOE facilities

  12. Overview of non-thermal mixed waste treatment technologies: Treatment of mixed waste (ex situ); Technologies and short descriptions

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-07-01

    This compendium contains brief summaries of new and developing non- thermal treatment technologies that are candidates for treating hazardous or mixed (hazardous plus low-level radioactive) wastes. It is written to be all-encompassing, sometimes including concepts that presently constitute little more than informed ``ideas``. It bounds the universe of existing technologies being thought about or considered for application on the treatment of such wastes. This compendium is intended to be the very first step in a winnowing process to identify non-thermal treatment systems that can be fashioned into complete ``cradle-to-grave`` systems for study. The purpose of the subsequent systems paper studies is to investigate the cost and likely performance of such systems treating a representative sample of U.S. Department of Energy (DOE) mixed low level wastes (MLLW). The studies are called Integrated Non-thermal Treatment Systems (INTS) Studies and are being conducted by the Office of Science and Technology (OST) of the Environmental Management (EM) of the US Department of Energy. Similar studies on Integrated Thermal Treatment Systems have recently been published. These are not designed nor intended to be a ``downselection`` of such technologies; rather, they are simply a systems evaluation of the likely costs and performance of various non- thermal technologies that have been arranged into systems to treat sludges, organics, metals, soils, and debris prevalent in MLLW.

  13. Overview of non-thermal mixed waste treatment technologies: Treatment of mixed waste (ex situ); Technologies and short descriptions

    International Nuclear Information System (INIS)

    1995-07-01

    This compendium contains brief summaries of new and developing non- thermal treatment technologies that are candidates for treating hazardous or mixed (hazardous plus low-level radioactive) wastes. It is written to be all-encompassing, sometimes including concepts that presently constitute little more than informed ''ideas''. It bounds the universe of existing technologies being thought about or considered for application on the treatment of such wastes. This compendium is intended to be the very first step in a winnowing process to identify non-thermal treatment systems that can be fashioned into complete ''cradle-to-grave'' systems for study. The purpose of the subsequent systems paper studies is to investigate the cost and likely performance of such systems treating a representative sample of U.S. Department of Energy (DOE) mixed low level wastes (MLLW). The studies are called Integrated Non-thermal Treatment Systems (INTS) Studies and are being conducted by the Office of Science and Technology (OST) of the Environmental Management (EM) of the US Department of Energy. Similar studies on Integrated Thermal Treatment Systems have recently been published. These are not designed nor intended to be a ''downselection'' of such technologies; rather, they are simply a systems evaluation of the likely costs and performance of various non- thermal technologies that have been arranged into systems to treat sludges, organics, metals, soils, and debris prevalent in MLLW

  14. Thermal behavior of horizontally mixed surfaces on Mars

    Science.gov (United States)

    Putzig, Nathaniel E.; Mellon, Michael T.

    2007-11-01

    Current methods for deriving thermal inertia from spacecraft observations of planetary brightness temperature generally assume that surface properties are uniform for any given observation or co-located set of observations. As a result of this assumption and the nonlinear relationship between temperature and thermal inertia, sub-pixel horizontal heterogeneity may yield different apparent thermal inertia at different times of day or seasons. We examine the effects of horizontal heterogeneity on Mars by modeling the thermal behavior of various idealized mixed surfaces containing differing proportions of either dust, sand, duricrust, and rock or slope facets at different angles and azimuths. Latitudinal effects on mixed-surface thermal behavior are also investigated. We find large (several 100 J m -2 K -1 s -1/2) diurnal and seasonal variations in apparent thermal inertia even for small (˜10%) admixtures of materials with moderately contrasting thermal properties or slope angles. Together with similar results for layered surfaces [Mellon, M.T., Putzig, N.E., 2007. Lunar Planet. Sci. XXXVIII. Abstract 2184], this work shows that the effects of heterogeneity on the thermal behavior of the martian surface are substantial and may be expected to result in large variations in apparent thermal inertia as derived from spacecraft instruments. While our results caution against the over-interpretation of thermal inertia taken from median or average maps or derived from single temperature measurements, they also suggest the possibility of using a suite of apparent thermal inertia values derived from single observations over a range of times of day and seasons to constrain the heterogeneity of the martian surface.

  15. Thermal processing system concepts and considerations for RWMC buried waste

    International Nuclear Information System (INIS)

    Eddy, T.L.; Kong, P.C.; Raivo, B.D.; Anderson, G.L.

    1992-02-01

    This report presents a preliminary determination of ex situ thermal processing system concepts and related processing considerations for application to remediation of transuranic (TRU)-contaminated buried wastes (TRUW) at the Radioactive Waste Management Complex (RWMC) of the Idaho National Engineering Laboratory (INEL). Beginning with top-level thermal treatment concepts and requirements identified in a previous Preliminary Systems Design Study (SDS), a more detailed consideration of the waste materials thermal processing problem is provided. Anticipated waste stream elements and problem characteristics are identified and considered. Final waste form performance criteria, requirements, and options are examined within the context of providing a high-integrity, low-leachability glass/ceramic, final waste form material. Thermal processing conditions required and capability of key systems components (equipment) to provide these material process conditions are considered. Information from closely related companion study reports on melter technology development needs assessment and INEL Iron-Enriched Basalt (IEB) research are considered. Five potentially practicable thermal process system design configuration concepts are defined and compared. A scenario for thermal processing of a mixed waste and soils stream with essentially no complex presorting and using a series process of incineration and high temperature melting is recommended. Recommendations for applied research and development necessary to further detail and demonstrate the final waste form, required thermal processes, and melter process equipment are provided

  16. Thermal processing system concepts and considerations for RWMC buried waste

    Energy Technology Data Exchange (ETDEWEB)

    Eddy, T.L.; Kong, P.C.; Raivo, B.D.; Anderson, G.L.

    1992-02-01

    This report presents a preliminary determination of ex situ thermal processing system concepts and related processing considerations for application to remediation of transuranic (TRU)-contaminated buried wastes (TRUW) at the Radioactive Waste Management Complex (RWMC) of the Idaho National Engineering Laboratory (INEL). Beginning with top-level thermal treatment concepts and requirements identified in a previous Preliminary Systems Design Study (SDS), a more detailed consideration of the waste materials thermal processing problem is provided. Anticipated waste stream elements and problem characteristics are identified and considered. Final waste form performance criteria, requirements, and options are examined within the context of providing a high-integrity, low-leachability glass/ceramic, final waste form material. Thermal processing conditions required and capability of key systems components (equipment) to provide these material process conditions are considered. Information from closely related companion study reports on melter technology development needs assessment and INEL Iron-Enriched Basalt (IEB) research are considered. Five potentially practicable thermal process system design configuration concepts are defined and compared. A scenario for thermal processing of a mixed waste and soils stream with essentially no complex presorting and using a series process of incineration and high temperature melting is recommended. Recommendations for applied research and development necessary to further detail and demonstrate the final waste form, required thermal processes, and melter process equipment are provided.

  17. Thermal processes evaluation for RWMC wastes

    International Nuclear Information System (INIS)

    1991-01-01

    The objective of this activity was to provide a white paper that identifies, collects information, and presents a preliminary evaluation of ''core'' thermal technologies that could be applied to RWMC stored and buried mixed waste. This paper presents the results of the following activities: General thermal technology identification, collection of technical and cost information on each technology, identification of thermal technologies applicable to RWMC waste, evaluation of each technology as applied to RWMC waste in seven process attributes, scoring each technology on a one to five scale (five highest) in each process attribute. Reaching conclusions about the superiority of one technology over others is not advised based on this preliminary study alone. However, the highly rated technologies (i.e., overall score of 2.9 or better) are worthy of a more detailed evaluation. The next step should be a more detailed evaluation of the technologies that includes onsite visits with operational facilities, preconceptual treatment facility design analysis, and visits with developers for emerging technologies. 2 figs., 6 tabs

  18. Investigation of coolant thermal mixing within 28-element CANDU fuel bundles using the ASSERT-PV thermal hydraulics code

    International Nuclear Information System (INIS)

    Lightston, M.F.; Rock, R.

    1996-01-01

    This paper presents the results of a study of the thermal mixing of single-phase coolant in 28-element CANDU fuel bundles under steady-state conditions. The study, which is based on simulations performed using the ASSERT-PV thermal hydraulic code, consists of two main parts. In the first part the various physical mechanisms that contribute to coolant mixing are identified and their impact is isolated via ASSERT-PV simulations. The second part is concerned with development of a preliminary model suitable for use in the fuel and fuel channel code FACTAR to predict the thermal mixing that occurs between flow annuli. (author)

  19. Characterization of the solid low level mixed waste inventory for the solid waste thermal treatment activity - III

    Energy Technology Data Exchange (ETDEWEB)

    Place, B.G., Westinghouse Hanford

    1996-09-24

    The existing thermally treatable, radioactive mixed waste inventory is characterized to support implementation of the commercial, 1214 thermal treatment contract. The existing thermally treatable waste inventory has been identified using a decision matrix developed by Josephson et al. (1996). Similar to earlier waste characterization reports (Place 1993 and 1994), hazardous materials, radionuclides, physical properties, and waste container data are statistically analyzed. In addition, the waste inventory data is analyzed to correlate waste constituent data that are important to the implementation of the commercial thermal treatment contract for obtaining permits and for process design. The specific waste parameters, which were analyzed, include the following: ``dose equivalent`` curie content, polychlorinated biphenyl (PCB) content, identification of containers with PA-related mobile radionuclides (14C, 12 79Se, 99Tc, and U isotopes), tritium content, debris and non-debris content, container free liquid content, fissile isotope content, identification of dangerous waste codes, asbestos containers, high mercury containers, beryllium dust containers, lead containers, overall waste quantities, analysis of container types, and an estimate of the waste compositional split based on the thermal treatment contractor`s proposed process. A qualitative description of the thermally treatable mixed waste inventory is also provided.

  20. Multi-Wave Mixing Processes

    CERN Document Server

    Zhang, Yanpeng

    2009-01-01

    "Multi-Wave Mixing Processes - From Ultrafast Polarization Beats to Electromagnetically Induced Transparency" discusses the interactions of efficient multi-wave mixing (MWM) processes enhanced by atomic coherence in multilevel atomic systems. It covers topics in five major areas: attosecond and femtosecond polarization beats of four-wave mixing (FWM) processes; heterodyne detection of FWM, six-wave mixing (SWM) and eight-wave mixing (EWM) processes; Raman and Rayleigh enhanced polarization beats; coexistence and interactions of MWM processes via electromagnetically induced transparency(EIT); multi-dressing MWM processes. The book is intended for researchers, advanced undergraduate and graduate students in Nonlinear Optics. Dr. Yanpeng Zhang is a professor at the Key Laboratory for Physical Electronics and Devices of the Ministry of Education, Xi'an Jiaotong University. Dr. Min Xiao is a professor of Physics at University of Arkansas, Fayetteville, U.S.A.

  1. VAC*TRAX - thermal desorption for mixed wastes

    Energy Technology Data Exchange (ETDEWEB)

    McElwee, M.J.; Palmer, C.R. [RUST-Clemson Technical Center, Anderson, SC (United States)

    1995-10-01

    The patented VAC*TRAX process was designed in response to the need to remove organic constituents from mixed waste, waste that contains both a hazardous (RCRA or TSCA regulated) component and a radioactive component. Separation of the mixed waste into its hazardous and radioactive components allows for ultimate disposal of the material at existing, permitted facilities. The VAC*TRAX technology consists of a jacketed vacuum dryer followed by a condensing train. Solids are placed in the dryer and indirectly heated to temperatures as high as 2600{degrees}C, while a strong vacuum (down to 50 mm Hg absolute pressure) is applied to the system and the dryer is purged with a nitrogen carrier gas. The organic contaminants in the solids are thermally desorbed, swept up in the carrier gas and into the condensing train where they are cooled and recovered. The dryer is fitted with a filtration system that keeps the radioactive constituents from migrating to the condensate. As such, the waste is separated into hazardous liquid and radioactive solid components, allowing for disposal of these streams at a permitted incinerator or a radioactive materials landfill, respectively. The VAC*TRAX system is designed to be highly mobile, while minimizing the operational costs with a simple, robust process. These factors allow for treatment of small waste streams at a reasonable cost.

  2. Investigation of thermal quenching and abnormal thermal quenching in mixed valence Eu co-doped LaAlO{sub 3} phosphor

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Jingjing [Tianjin Key Laboratory for Photoelectric Materials and Devices, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384 (China); Zhao, Yang [China academy of civil aviation science and technology, Beijing 100028 (China); Mao, Zhiyong, E-mail: mzhy1984@163.com [Tianjin Key Laboratory for Photoelectric Materials and Devices, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384 (China); Wang, Dajian [Tianjin Key Laboratory for Photoelectric Materials and Devices, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384 (China); Bie, Lijian, E-mail: ljbie@tjut.edu.cn [Tianjin Key Laboratory for Photoelectric Materials and Devices, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384 (China)

    2017-06-15

    Temperature dependent luminescence of mixed valence Eu co-doped LaAlO{sub 3} phosphors are deeply investigated in this work. Different temperature properties of Eu{sup 2+} and Eu{sup 3+} luminescence are observed as the phosphor excited by different incident light. Eu{sup 3+} luminescence shows normal thermal quenching when excited at 320 nm and abnormal thermal quenching as the excitation light changed into 365 nm, while Eu{sup 2+} luminescence exhibits a normal thermal quenching independent on the incident excitation lights. The origin of these novel normal/abnormal thermal quenching phenomena are analyzed and discussed by the excitation-emission processes in terms of the configuration coordinate model. The presented important experimental and analysis results give insights into the temperature properties of phosphors.

  3. Application of the REMIX thermal mixing calculation program for the Loviisa reactor

    International Nuclear Information System (INIS)

    Kokkonen, I.; Tuomisto, H.

    1987-08-01

    The REMIX computer program has been validated to be used in the pressurized thermal shock study of the Loviisa reactor pressure vessel. The program has been verified against the data from the thermal and fluid mixing experiments. These experiments have been carried out in Imatran voima Oy to study thermal mixing of the high-pressure safety injection water in the Loviisa VVER-440 type pressurized water reactor. The verified REMIX-versions were applied to reactor calculations in the probabilistic pressurized thermal shock study of the Loviisa Plant

  4. Thermal destratification in small standard solar tanks due to mixing during tapping

    DEFF Research Database (Denmark)

    Andersen, Elsa; Furbo, Simon

    1999-01-01

    performance caused by mixing during draw-offs can be as high as 23% if a marketed cold-water inlet design is used. Other tested inlet designs result in a decrease of 2-3% of the yearly thermal performance caused by mixing. Based on the investigations recommendations on the design of the cold-water inlet......-off is relatively long. In order to reduce this waiting time to an acceptable level, the flow rate during draw-off is often very large – typically about 20 l/min. – at least at the start of the draw-off. As long as the flow rate during draw-off is small, the mixing rate inside the tank is small. However......, if the flow rate is large, as mentioned above, the mixing rate can be relatively large if the cold-water inlet design is poor. Mixing results in destratification in the solar tank and with that reduced thermal performance of the SDHW system. Investigations indicate that the decrease of the yearly thermal...

  5. Thermal destratification in small standard solar tanks due to mixing during tapping

    DEFF Research Database (Denmark)

    Andersen, Elsa; Furbo, Simon

    1999-01-01

    performance caused by mixing during draw-offs can be as high as 23 % if a marketed cold water inlet design is used. Other tested inlet designs result in a decrease of 2-3 % of the yearly thermal performance caused by mixing. Based on the investigations recommendations on the design of the cold water inlet......-off is relatively long. In order to reduce this waiting time to an acceptable level, the flow rate during draw-off is often very large - typically about 20 l/min - at least at the start of the draw-off. As long as the flow rate during draw-off is small, the mixing rate inside the tank is small. However, if the flow...... rate is large, as mentioned above, the mixing rate can be relatively large if the cold water inlet design is poor. Mixing results in destratification in the solar tank and with that reduced thermal performance of the SDHW system. Investigations indicate that the decrease of the yearly thermal...

  6. A thermal analysis study on proprietary quick-setting mixed binder system

    International Nuclear Information System (INIS)

    Deneanu, N.; Dulama, M.; Diaconescu, C.

    2013-01-01

    The present paper presents a study, by thermal analysis, of the hydration of a mixed binder system consist of Portland composite cement type CEM II/A-M(S-LL) 32,5 R and calcium aluminate cement type GORKAL 70, patented by the authors for embedding spent radioactive solvents. Cement hydration reactions are often affected by the presence of a spent radioactive solvent, usually retarded. This process can be monitored by thermal analysis and often quantified. The data are being used as a reference to compare the changes in the cement blend hydration during the solidification caused by the presence of the spent radioactive solvents itself or by emulsifier additives which are being availed. Detailed analysis of DTG (derivative thermo gravimetric) decomposition profiles of portlandite and carbonate enabled the evaluation of admixture-related parameters concerning portlandite formation and also indicated the behaviour of specific carbonates during the hydration process. (authors)

  7. Application of thermal technologies for processing of radioactive waste

    International Nuclear Information System (INIS)

    2006-12-01

    The primary objective of this publication is to provide an overview of the various thermal technologies for processing various solid, liquid, organic and inorganic radioactive waste streams. The advantages, limitations and operating experience of various thermal technologies are explained. This publication also goes beyond previous work on thermal processes by addressing the applicability of each technology to national or regional nuclear programmes of specific relative size (major advanced programmes, small to medium programmes, and emerging programmes with other nuclear applications). The most commonly used thermal processing technologies are reviewed, and the key factors influencing the selection of thermal technologies as part of a national waste management strategy are discussed. Accordingly, the structure and content of this publication is intended to assist decision-makers, regulators, and those charged with developing such strategies to identify and compare thermal technologies for possible inclusion in the mix of available, country-specific waste management processes. This publication can be used most effectively as an initial cutting tool to identify whether any given technology will best serve the local waste management strategy in terms of the waste generated, technical complexity, available economic resources, environmental impact considerations, and end product (output) of the technology. If multiple thermal technologies are being actively considered, this publication should be instrumental in comparing the technologies and assisting the user to reach an informed decision based on local needs, economics and priorities. A detailed set of conclusions is provided in Section 7

  8. Acetate self-mixing and direct thermal reaction for preparation of LiCoO2

    International Nuclear Information System (INIS)

    Jung, Bum-Young; Kang, Hyun-Koo; Jeong, In-Seong; Han, Kyoo-Seung; Lee, Youngil; Choo, Jaebum; Ryu, Kwang Sun

    2004-01-01

    Layered LiCoO 2 as a cathode material for rechargeable lithium battery is prepared using the acetate self-mixing method. Using this method, the preparation procedure consists of just two steps: spontaneous and homogeneous mixing of molten acetates at 80 deg. C, as well as direct thermal reaction at high temperature without any pulverization, grinding, agglomeration, particle morphology controlling, particle size controlling, and even artificial stirring of reactants. When lithium and cobalt acetates are exposed to the temperature of 80 deg. C, they can be fluidized substances by themselves without any solvents and spontaneously mixed together. In this way, layered LiCoO 2 phase is prepared by just simple heat treatment. The heating at 350 deg. C is interposed to accomplish steady intermediate phase translation without any intermittent cooling. The 7 Li MAS NMR and Raman spectra upon the thermal exposure of the reactants demonstrate the feature of the spontaneous mixing process of the molten reactants. The LiCoO 2 prepared by the acetate self-mixing method show quite prospective properties as a cathode material for lithium rechargeable battery, an initial discharge capacity of 149.5 mAh/g and the discharge capacity retention of 98.9% and 97.5% after 10 and 20 cycles, respectively

  9. Thermal-hydraulic mixing in the split-core ANS reactor design

    International Nuclear Information System (INIS)

    Dorning, R.J.J.

    1988-01-01

    A design has been proposed for the advanced neutron source (ANS) reactor that incorporates a split core, one purpose of which is to create a mixing plenum between the upper and lower cores. It was hoped that in addition to introducing various desirable neutronics features, such as decreasing the fast neutron flux contamination of thermal and cold neutron beams located in the reactor midplane, this mixing plenum would make possible higher operating powers by lowering the maximum core temperature. This lower temperature was to be achieved as a result of the mixing, of the hot D 2 O coolant exiting the upper-core channels, and the cold D 2 O leaving the large upper core bypass. It was expected that this mixing would bring about a significantly reduced lower core maximum coolant inlet temperature. The authors have carried out large-scale computer calculations to determine the extent to which this mixing occurs in current split-core design geometry, which does not incorporate baffles, mixing devices, or other design features introduced to enhance mixing. The large-scale self-consistent calculations summarized here indicate that innovative design ideas to enhance mixing will be necessary if the split-core concept is to achieve the amount of thermal mixing needed to make possible significantly higher power operation and corresponding higher flux sources

  10. CFD modeling of thermal mixing in a T-junction geometry using LES model

    Energy Technology Data Exchange (ETDEWEB)

    Ayhan, Hueseyin, E-mail: huseyinayhan@hacettepe.edu.tr [Hacettepe University, Department of Nuclear Engineering, Beytepe, Ankara 06800 (Turkey); Soekmen, Cemal Niyazi, E-mail: cemalniyazi.sokmen@hacettepe.edu.tr [Hacettepe University, Department of Nuclear Engineering, Beytepe, Ankara 06800 (Turkey)

    2012-12-15

    Highlights: Black-Right-Pointing-Pointer CFD simulations of temperature and velocity fluctuations for thermal mixing cases in T-junction are performed. Black-Right-Pointing-Pointer It is found that the frequency range of 2-5 Hz contains most of the energy; therefore, may cause thermal fatigue. Black-Right-Pointing-Pointer This study shows that RANS based calculations fail to predict a realistic mixing between the fluids. Black-Right-Pointing-Pointer LES model can predict instantaneous turbulence behavior. - Abstract: Turbulent mixing of fluids at different temperatures can lead to temperature fluctuations at the pipe material. These fluctuations, or thermal striping, inducing cyclical thermal stresses and resulting thermal fatigue, may cause unexpected failure of pipe material. Therefore, an accurate characterization of temperature fluctuations is important in order to estimate the lifetime of pipe material. Thermal fatigue of the coolant circuits of nuclear power plants is one of the major issues in nuclear safety. To investigate thermal fatigue damage, the OECD/NEA has recently organized a blind benchmark study including some of results of present work for prediction of temperature and velocity fluctuations performing a thermal mixing experiment in a T-junction. This paper aims to estimate the frequency of velocity and temperature fluctuations in the mixing region using Computational Fluid Dynamics (CFD). Reynolds Averaged Navier-Stokes and Large Eddy Simulation (LES) models were used to simulate turbulence. CFD results were compared with the available experimental results. Predicted LES results, even in coarse mesh, were found to be in well-agreement with the experimental results in terms of amplitude and frequency of temperature and velocity fluctuations. Analysis of the temperature fluctuations and the power spectrum densities (PSD) at the locations having the strongest temperature fluctuations in the tee junction shows that the frequency range of 2-5 Hz

  11. A manufacturing process for a mixed-oxide type superconducting material

    International Nuclear Information System (INIS)

    Gendre, P.; Regnier, P.; Schmirgeld-Mignot, L.; Marquet, A.

    1995-01-01

    In order to produce high temperature superconducting materials such as YBaCuO and Bi 2 Sr 2 Ca Cu 2 O 8 , a process is presented which consists in an electrodeposition on a conductive substrate of successive layers made of the metallic elements composing the superconductor, with only one element in each layer; between each layer deposition, an intermediary oxide-reaction thermal treatment is carried out; a global oxidation thermal treatment is then finally conducted to produce the mixed oxide material. Narrow superconducting transitions and high critical current densities are possible. 3 refs., 4 figs

  12. Modeling the Effect of Grain Size Mixing on Thermal Inertia Values Derived from Diurnal and Seasonal THEMIS Measurements

    Science.gov (United States)

    McCarty, C.; Moersch, J.

    2017-12-01

    Sedimentary processes have slowed over Mars' geologic history. Analysis of the surface today can provide insight into the processes that may have affected it over its history. Sub-resolved checkerboard mixtures of materials with different thermal inertias (and therefore different grain sizes) can lead to differences in thermal inertia values inferred from night and day radiance observations. Information about the grain size distribution of a surface can help determine the degree of sorting it has experienced or it's geologic maturity. Standard methods for deriving thermal inertia from measurements made with THEMIS can give values for the same location that vary by as much as 20% between scenes. Such methods make the assumption that each THEMIS pixel contains material that has uniform thermophysical properties. Here we propose that if a mixture of small and large particles is present within a pixel, the inferred thermal inertia will be strongly dominated by whichever particle is warmer at the time of the measurement because the power radiated by a surface is proportional (by the Stefan-Boltzmann law) to the fourth power of its temperature. This effect will result in a change in thermal inertia values inferred from measurements taken at different times of day and night. Therefore, we expect to see correlation between the magnitude of diurnal variations in inferred thermal inertia values and the degree of grain size mixing for a given pixel location. Preliminary work has shown that the magnitude of such diurnal variation in inferred thermal inertias is sufficient to detect geologically useful differences in grain size distributions. We hypothesize that at least some of the 20% variability in thermal inertias inferred from multiple scenes for a given location could be attributed to sub-pixel grain size mixing rather than uncertainty inherent to the experiment, as previously thought. Mapping the difference in inferred thermal inertias from day and night THEMIS

  13. Zero-Release Mixed Waste Process Facility Design and Testing

    International Nuclear Information System (INIS)

    Richard D. Boardman; John A. Deldebbio; Robert J. Kirkham; Martin K. Clemens; Robert Geosits; Ping Wan

    2004-01-01

    A zero-release off-gas cleaning system for mixed-waste thermal treatment processes has been evaluated through experimental scoping tests and process modeling. The principles can possibly be adapted to a fluidized-bed calcination or stream reforming process, a waste melter, a rotary kiln process, and possibly other waste treatment thermal processes. The basic concept of a zero-release off-gas cleaning system is to recycle the bulk of the off-gas stream to the thermal treatment process. A slip stream is taken off the off-gas recycle to separate and purge benign constituents that may build up in the gas, such as water vapor, argon, nitrogen, and CO2. Contaminants are separated from the slip stream and returned to the thermal unit for eventual destruction or incorporation into the waste immobilization media. In the current study, a standard packed-bed scrubber, followed by gas separation membranes, is proposed for removal of contaminants from the off-gas recycle slipstream. The scrub solution is continuously regenerated by cooling and precipitating sulfate, nitrate, and other salts that reach a solubility limit in the scrub solution. Mercury is also separated by the scrubber. A miscible chemical oxidizing agent was shown to effectively oxidize mercury and also NO, thus increasing their removal efficiency. The current study indicates that the proposed process is a viable option for reducing off-gas emissions. Consideration of the proposed closed-system off-gas cleaning loop is warranted when emissions limits are stringent, or when a reduction in the total gas emissions volume is desired. Although the current closed-loop appears to be technically feasible, economical considerations must be also be evaluated on a case-by-case basis

  14. Method for identification of fluid mixing zones subject to thermal fatigue damage

    International Nuclear Information System (INIS)

    Vole, O.; Beaud, F.

    2009-01-01

    High cycle thermal fatigue due to the mixing of hot and cold fluids may initiate cracking in pipes of safety related circuits. A method has been developed to identify such fluid mixing zones subjected to potential thermal fatigue damage. This method is based on a loading model and a mechanical model that depend on the main characteristics of the mixing zone and on the material properties. It is supported by a large experimental program. This method has been applied to all the mixing zones of safety related circuits of the EDF pressurised water reactors, allowing to identify sensitive zones and to apply an appropriate inspection program that ensures the control of the risk due to this damage mechanism. (authors)

  15. An assessment of thermal destruction technologies for application to Department of Energy mixed wastes

    International Nuclear Information System (INIS)

    1991-08-01

    As evidenced by the Department of Energy (DOE) Environmental Restoration and Waste Management Five-Year Plan, the Department is committing to a long-range waste management program. A category of waste that represents a sizable portion of the total DOE waste picture and also presents significant complications in management is waste that contains both hazardous and radioactive components. This category of wastes, referred to as mixed waste (MW), is present at all but a few of the Department's sites. The presence of radioactive constituents in this waste category implies that it be managed, like radioactive-only wastes, on DOE-owned property. Thermal treatment of MW's offers a variety of benefits in the final disposition of the waste. One obvious benefit is volume reduction of the waste if it contains organics because most of the organics are converted to gases and water, leaving only the inert material or ash. Another benefit is the destruction of hazardous materials by thermal conversion to simple, nonhazardous gases water. A third benefit, for some thermal technologies, is that the thermal process yields a process residue that meets disposal requirements for both hazardous and radioactive constituents without further processing. 2 refs., 47 figs., 8 tabs

  16. PPOOLEX experiments on thermal stratification and mixing

    Energy Technology Data Exchange (ETDEWEB)

    Puustinen, M.; Laine, J.; Raesaenen, A. (Lappeenranta Univ. of Technology, Nuclear Safety Research Unit (Finland))

    2009-08-15

    The results of the thermal stratification experiments in 2008 with the PPOOLEX test facility are presented. PPOOLEX is a closed vessel divided into two compartments, dry well and wet well. Extra temperature measurements for capturing different aspects of the investigated phenomena were added before the experiments. The main purpose of the experiment series was to generate verification data for evaluating the capability of GOTHIC code to predict stratification and mixing phenomena. Altogether six experiments were carried out. Heat-up periods of several thousand seconds by steam injection into the dry well compartment and from there into the wet well water pool were recorded. The initial water bulk temperature was 20 deg. C. Cooling periods of several days were included in three experiments. A large difference between the pool bottom and top layer temperature was measured when small steam flow rates were used. With higher flow rates the mixing effect of steam discharge delayed the start of stratification until the pool bulk temperature exceeded 50 deg. C. The stratification process was also different in these two cases. With a small flow rate stratification was observed only above and just below the blowdown pipe outlet elevation. With a higher flow rate over a 30 deg. C temperature difference between the pool bottom and pipe outlet elevation was measured. Elevations above the pipe outlet indicated almost linear rise until the end of steam discharge. During the cooling periods the measurements of the bottom third of the pool first had an increasing trend although there was no heat input from outside. This was due to thermal diffusion downwards from the higher elevations. Heat-up in the gas space of the wet well was quite strong, first due to compression by pressure build-up and then by heat conduction from the hot dry well compartment via the intermediate floor and test vessel walls and by convection from the upper layers of the hot pool water. The gas space

  17. PPOOLEX experiments on thermal stratification and mixing

    International Nuclear Information System (INIS)

    Puustinen, M.; Laine, J.; Raesaenen, A.

    2009-08-01

    The results of the thermal stratification experiments in 2008 with the PPOOLEX test facility are presented. PPOOLEX is a closed vessel divided into two compartments, dry well and wet well. Extra temperature measurements for capturing different aspects of the investigated phenomena were added before the experiments. The main purpose of the experiment series was to generate verification data for evaluating the capability of GOTHIC code to predict stratification and mixing phenomena. Altogether six experiments were carried out. Heat-up periods of several thousand seconds by steam injection into the dry well compartment and from there into the wet well water pool were recorded. The initial water bulk temperature was 20 deg. C. Cooling periods of several days were included in three experiments. A large difference between the pool bottom and top layer temperature was measured when small steam flow rates were used. With higher flow rates the mixing effect of steam discharge delayed the start of stratification until the pool bulk temperature exceeded 50 deg. C. The stratification process was also different in these two cases. With a small flow rate stratification was observed only above and just below the blowdown pipe outlet elevation. With a higher flow rate over a 30 deg. C temperature difference between the pool bottom and pipe outlet elevation was measured. Elevations above the pipe outlet indicated almost linear rise until the end of steam discharge. During the cooling periods the measurements of the bottom third of the pool first had an increasing trend although there was no heat input from outside. This was due to thermal diffusion downwards from the higher elevations. Heat-up in the gas space of the wet well was quite strong, first due to compression by pressure build-up and then by heat conduction from the hot dry well compartment via the intermediate floor and test vessel walls and by convection from the upper layers of the hot pool water. The gas space

  18. Numerical methods for the prediction of thermal fatigue due to turbulent mixing

    International Nuclear Information System (INIS)

    Hannink, M.H.C.; Blom, F.J.

    2011-01-01

    Research highlights: → Thermal fatigue due to turbulent mixing is caused by moving temperature spots on the pipe wall. → Passing temperature spots cause temperature fluctuations of sinusoidal nature. → Input parameters for a sinusoidal model can be obtained by linking it with a coupled CFD-FEM model. → Overconservatism of the sinusoidal method can be reduced, having more knowledge on thermal loads. - Abstract: Turbulent mixing of hot and cold flows is one of the possible causes of thermal fatigue in piping systems. Especially in primary pipework of nuclear power plants this is an important, safety related issue. Since the frequencies of the involved temperature fluctuations are generally too high to be detected well by common plant instrumentation, accurate numerical simulations are indispensable for a proper fatigue assessment. In this paper, a link is made between two such numerical methods: a coupled CFD-FEM model and a sinusoidal model. By linking these methods, more insight is obtained in the physical phenomenon causing thermal fatigue due to turbulent mixing. Furthermore, useful knowledge is acquired on the determination of thermal loading parameters, essential for reducing overconservatism, as currently present in simplified fatigue assessment methods.

  19. Influence of thermal effects induced by nonlinear absorption on four-wave mixing in silicon waveguides

    DEFF Research Database (Denmark)

    Pu, Minhao; Chen, Yaohui; Yvind, Kresten

    2014-01-01

    Influence of thermal effects induced by nonlinear absorption on four-wave mixing in silicon waveguides is investigated. A conversion bandwidth reduction up to 63% is observed in simulation due to the thermal effects.......Influence of thermal effects induced by nonlinear absorption on four-wave mixing in silicon waveguides is investigated. A conversion bandwidth reduction up to 63% is observed in simulation due to the thermal effects....

  20. Mercury removal from solid mixed waste

    International Nuclear Information System (INIS)

    Gates, D.D.; Morrissey, M.; Chava, K.K.; Chao, K.

    1994-01-01

    The removal of mercury from mixed wastes is an essential step in eliminating the temporary storage of large inventories of mixed waste throughout the Department of Energy (DOE) complex. Currently thermal treatment has been identified as a baseline technology and is being developed as part of the DOE Mixed Waste Integrated Program (MWIP). Since thermal treatment will not be applicable to all mercury containing mixed waste and the removal of mercury prior to thermal treatment may be desirable, laboratory studies have been initiated at Oak Ridge National Laboratory (ORNL) to develop alternative remediation technologies capable of removing mercury from certain mixed waste. This paper describes laboratory investigations of the KI/I 2 leaching processes to determine the applicability of this process to mercury containing solid mixed waste

  1. Mixing in thermally stratified nonlinear spin-up with uniform boundary fluxes

    International Nuclear Information System (INIS)

    Baghdasarian, Meline; Pacheco-Vega, Arturo; Pacheco, J. Rafael; Verzicco, Roberto

    2014-01-01

    Studies of stratified spin-up experiments in enclosed cylinders have reported the presence of small pockets of well-mixed fluids but quantitative measurements of the mixedness of the fluid has been lacking. Previous numerical simulations have not addressed these measurements. Here we present numerical simulations that explain how the combined effect of spin-up and thermal boundary conditions enhances or hinders mixing of a fluid in a cylinder. The energy of the system is characterized by splitting the potential energy into diabatic and adiabatic components, and measurements of efficiency of mixing are based on both, the ratio of dissipation of available potential energy to forcing and variance of temperature. The numerical simulations of the Navier–Stokes equations for the problem with different sets of thermal boundary conditions at the horizontal walls helped shed some light on the physical mechanisms of mixing, for which a clear explanation was absent

  2. Mixing in thermally stratified nonlinear spin-up with uniform boundary fluxes

    Energy Technology Data Exchange (ETDEWEB)

    Baghdasarian, Meline; Pacheco-Vega, Arturo [Department of Mechanical Engineering, California State University, Los Angeles, Los Angeles, California 90032 (United States); Pacheco, J. Rafael, E-mail: rpacheco@asu.edu [SAP Americas Inc., Scottsdale, Arizona 85251 (United States); School of Mathematical and Statistical Sciences, Arizona State University, Tempe, Arizona 85287 (United States); Environmental Fluid Dynamics Laboratories, Department of Civil Engineering and Geological Sciences, The University of Notre Dame, South Bend, Indiana 46556 (United States); Verzicco, Roberto [Dipartimento di Ingegneria Meccanica, Universita di Roma “Tor Vergata”, Via del Politecnico 1, 00133, Roma (Italy); PoF, University of Twente, 7500 AE Enschede (Netherlands)

    2014-09-15

    Studies of stratified spin-up experiments in enclosed cylinders have reported the presence of small pockets of well-mixed fluids but quantitative measurements of the mixedness of the fluid has been lacking. Previous numerical simulations have not addressed these measurements. Here we present numerical simulations that explain how the combined effect of spin-up and thermal boundary conditions enhances or hinders mixing of a fluid in a cylinder. The energy of the system is characterized by splitting the potential energy into diabatic and adiabatic components, and measurements of efficiency of mixing are based on both, the ratio of dissipation of available potential energy to forcing and variance of temperature. The numerical simulations of the Navier–Stokes equations for the problem with different sets of thermal boundary conditions at the horizontal walls helped shed some light on the physical mechanisms of mixing, for which a clear explanation was absent.

  3. Coupled large-eddy simulation of thermal mixing in a T-junction

    International Nuclear Information System (INIS)

    Kloeren, D.; Laurien, E.

    2011-01-01

    Analyzing thermal fatigue due to thermal mixing in T-junctions is part of the safety assessment of nuclear power plants. Results of two large-eddy simulations of mixing flow in a T-junction with coupled and adiabatic boundary condition are presented and compared. The temperature difference is set to 100 K, which leads to strong stratification of the flow. The main and the branch pipe intersect horizontally in this simulation. The flow is characterized by steady wavy pattern of stratification and temperature distribution. The coupled solution approach shows highly reduced temperature fluctuations in the near wall region due to thermal inertia of the wall. A conjugate heat transfer approach is necessary in order to simulate unsteady heat transfer accurately for large inlet temperature differences. (author)

  4. Processing line for industrial radiation-thermal synthesis of doped lithium ferrite powders

    Science.gov (United States)

    Surzhikov, A. P.; Galtseva, O. V.; Vasendina, E. A.; Vlasov, V. A.; Nikolaev, E. V.

    2016-02-01

    The paper considers the issues of industrial production of doped lithium ferrite powders by radiation-thermal method. A technological scheme of the processing line is suggested. The radiation-thermal technological scheme enables production of powders with technical characteristics close to the required ones under relatively low temperature annealing conditions without intermediate mixing. The optimal conditions of the radiation-thermal synthesis are achieved isothermally under irradiation by the electron beam with energy of 2.5 MeV in the temperature range of 700-750 0C within- 120 min.

  5. Mixed oxide thermal behaviour at BOL: COMETHE III-J models and impact on power-to-melt

    International Nuclear Information System (INIS)

    Vliet, J. van

    1979-01-01

    The mixed oxide thermal behaviour at beginning of life is very important because it can impose a limitation to the fuel pin peak power, and therefore to the reactor thermal output. The relevant physical processes leading to fuel restructuring are modelled in COMETHE III-J in a kinetic way. This ensures that the temperature and power history are properly taken into account. These models are described and their impact on the calculated power to melt early in life is analysed. (author)

  6. The probabilistic model of the process mixing of animal feed ingredients into a continuous mixer-reactor

    OpenAIRE

    L. I. Lytkina; A. A. Shevtsov; E. S. Shentsova; O. A. Apalikhina

    2016-01-01

    A mathematical model of the polydisperse medium mixing process reflects its stochastic features in the form of uneven distribution of phase elements on the time of their presence in apparatus, particle size, ripple retention of the apparatus, random distribution of the material and thermal phase flows of the working volume, heterogeneity of the medium physical- and chemical properties, complicated by chemical reaction. For the mathematical description of the mixing process of animal feed ingr...

  7. Elucidation of thermal hydraulic mixing mechanism in a mixing tee area with a 90-degree bend upstream and development of thermal-striping relaxation and control methods

    International Nuclear Information System (INIS)

    Sugawara, Yoshimasa; Yuki, Kazuhisa; Hashizume, Hidetoshi; Tanaka, Masa-aki; Muramatsu, Toshiharu

    2004-10-01

    In the region where two fluids with different temperatures mix, unstable fluid mixing like thermal striping occurs accompanying with unsteady temperature fluctuation of fluid. This temperature fluctuation is transported toward the surrounding area and becomes an important factor that induces thermal fatigue of structural materials, which sometimes results in crack generation of them. In fast breeder reactors that utilize liquid sodium as a coolant, the fluid temperature fluctuation could be easier to conduct toward the structural materials due to its high thermal conductivity, so that careful consideration for the thermal fatigue is required. In particular, since the low frequency band of temperature fluctuation strongly affects the thermal fatigue, evaluation and development of the relaxation and control methods for it become important issues. In this study, non-isothermal fluid mixing experiments in a T-junction area with a 90-degree bend upstream were carried out to estimate the fluid-temperature fluctuation in the vicinity of wall. The temperature fluctuations for various flow mixing conditions were measured, changing a velocity ratio and a pipe diameter ratio of a main pipe to a branch pipe to quantitatively evaluate the effect of a secondary flow on the temperature fluctuation. In addition, by analyzing both the visualization data taken by a PIV system and the temperature fluctuation data, it was attempted to construct a prediction formula for the temperature fluctuation. Our findings are summarized below. (1) Classifying the flow mixing pattern of jet flow running out from the branch pipe makes it possible to predict the maximum temperature fluctuation in the mixing area with higher accuracy by using the flow velocity ratio (0.2 -0.06 (d/D) 0.22 . Re-attachment Flow - deflecting Flow: Max(ΔTrms*)=0.64(v/V) -0.92 (d/D) 1.11 . (2) Prediction formulas for the maximum temperature fluctuation in the case of the curvature ratio of 1.0 are also constructed as

  8. Study on mixing phenomena in T-pipe junction. Experimental analysis using DNS and investigation of mixing process

    International Nuclear Information System (INIS)

    Igarashi, Minoru; Tanaka, Masaaki; Kimura, Nobuyuki; Kamide, Hideki

    2003-02-01

    In the place where hot and cold fluids are mixed, a time and spatial temperature fluctuation occurs. When this temperature fluctuation amplitude is large, it causes high cycle thermal fatigue in surrounding structure (thermal striping phenomena). Mixing area of high and low temperature fluid exists not only in an atomic power plant but also in a general plant, then, it is significant to investigate this phenomena and also to establish an evaluation rule. In Japan Nuclear Cycle Development Institute, several experiments and the improvement of the analysis methods have been carried out to understand thermal striping phenomena and also to construct an evaluation rule, which can be applied to design. Water Experiment on Fluid Mixing in T-pipe with Long Cycle Fluctuation (WATLON), aiming at examining thermal striping phenomena in a mixing tee, is performed to investigate key factors of mixing phenomena. In this study, in order to investigate the fluid mixing phenomena, temperature and flow velocity distribution were measured by movable thermocouple tree and particle image velocimetry (PIV). And the analysis using a in-house direct numerical simulation (DNS) code, DINUS-3 was performed to understand applicability of the analytical method in mixing tee. The temperature and velocity fields obtained from the DINUS-3 were in good agreement with the experimental results. And the prominent frequency of temperature fluctuation was also in good agreement. The DINUS-3 calculation simulated vortex structure in the wake region behind the branch pipe jet. The results of analysis showed that a Karman vortex generated in the wake region behind the branch pipe jet influenced the temperature fluctuation behavior in the mixing tee. And the analytical results revealed that the vortex generated in the wake region behind the branch pipe jet showed the 3-dimensional behavior. (author)

  9. Thermal annealing and recoil reactions of 128I atoms in thermal neutron activated iodate-nitrate mixed crystals

    International Nuclear Information System (INIS)

    Mishra, S.P.; Sharma, R.B.

    1983-01-01

    Recoil reaction of 128 I atoms in neutron irradiated mixed crystals (iodate-nitrate) have been studied by thermal annealing methods. The retention of 128 I (i.e. radioactivity of 128 I retained in the parent chemi cal form) decreases sharply in the beginning and then attains saturation value with the increase in concentration of nitrate. The annealing followed the usual characteristic pattern, viz., a steep rise in retention within the first few minutes and then a saturation value thereafter but these saturation values in case of mixed crystals are lower in comparison to those of pure iodate targets. The process obeys simple first order kinetics and the activation energy obtained are of lower order than those obtained in case of pure targets. The results are discussed in the light of present ideas and the role of nitrate ion and its radiolytic products have also been invoked. (author)

  10. An assessment of thermal destruction technologies for application to Department of Energy mixed wastes

    International Nuclear Information System (INIS)

    1991-08-01

    A study of known operational and emerging thermal treatment technologies was conducted for the Department of Energy's (DOE's) Office of Technology Development (OTD) through the Hazardous Waste Remedial Actions Program (HAZWRAP). This study addressed thermal treatment of mixed wastes (MWs), for which the most comprehensive set of waste has been divided into two volumes. Volume 1 contains the details and results of the technology assessments and comparisons between technologies. This volume (Volume 2) contains the comprehensive data collected on each technology, including descriptions, process and cost data, comments on advantages and deficiencies, types of waste treatable and by-products of these wastes, and reference information. 2 figs

  11. Thermal stress analysis for fatigue damage evaluation at a mixing tee

    International Nuclear Information System (INIS)

    Kamaya, Masayuki; Nakamura, Akira

    2011-01-01

    Highlights: → Thermal stress and fatigue damage have been analyzed for a mixing tee. → Fatigue damage was accumulated near boundaries of the cold spot. → It was found that fatigue damage was brought about by fluctuation of cold spot. → Simple one-dimensional analysis could derive stress for fatigue evaluation. - Abstract: Fatigue cracks have been found at mixing tees where fluids of different temperature flow in. In this study, the thermal stress at a mixing tee was calculated by the finite element method using temperature transients obtained by a fluid dynamics simulation. The simulation target was an experiment for a mixing tee, in which cold water flowed into the main pipe from a branch pipe. The cold water flowed along the main pipe wall and caused a cold spot, at which the membrane stress was relatively large. Based on the evaluated thermal stress, the magnitude of the fatigue damage was assessed according to the linear damage accumulation rule and the rain-flow procedure. Precise distributions of the thermal stress and fatigue damage could be identified. Relatively large axial stress occurred downstream from the branch pipe due to the cold spot. The variation ranges of thermal stress and fatigue damage became large near the position 20 o from the symmetry line in the circumferential direction. The position of the cold spot changed slowly in the circumferential direction, and this was the main cause of the fatigue damage. The fatigue damage was investigated for various differences in the temperature between the main and branch pipes. Since the magnitude of accumulated damage increased abruptly when the temperature difference exceeded the value corresponding to the fatigue limit, it was suggested that the stress amplitude should be suppressed less than the fatigue limit. In the thermal stress analysis for fatigue damage assessment, it was found that the detailed three-dimensional structural analysis was not required. Namely, for the current case, a one

  12. Large eddy simulation on thermal fluid mixing in a T-junction piping system

    Energy Technology Data Exchange (ETDEWEB)

    Selvam, P. Karthick; Kulenovic, R.; Laurien, E. [Stuttgart Univ. (Germany). Inst fuer Kernenergie und Energiesysteme (IKE)

    2014-11-15

    High cycle thermal fatigue damage caused in piping systems is an important problem encountered in the context of nuclear safety and lifetime management of a Nuclear Power Plant (NPP). The T-junction piping system present in the Residual Heat Removal System (RHRS) is more vulnerable to thermal fatigue cracking. In this numerical study, thermal mixing of fluids at temperature difference (?T) of 117 K between the mixing fluids is analyzed. Large Eddy Simulation (LES) is performed with conjugate heat transfer between the fluid and structure. LES is performed based on the Fluid-Structure Interaction (FSI) test facility at University of Stuttgart. The results show an intense turbulent mixing of fluids downstream of T-junction. Amplitude of temperature fluctuations near the wall region and its corresponding frequency distribution is analyzed. LES is performed using commercial CFD software ANSYS CFX 14.0.

  13. Surrogate formulations for thermal treatment of low-level mixed waste

    International Nuclear Information System (INIS)

    Stockdale, J.A.D.; Bostick, W.D.; Hoffmann, D.P.; Lee, H.T.

    1994-01-01

    The evaluation and comparison of proposed thermal treatment systems for mixed wastes can be expedited by tests in which the radioactive components of the wastes are replaced by surrogate materials chosen to mimic, as far as is possible, the chemical and physical properties of the radioactive materials of concern. In this work, sponsored by the Mixed Waste Integrated Project of the US Department of Energy, the authors have examined reported experience with such surrogates and suggest a simplified standard list of materials for use in tests of thermal treatment systems. The chief radioactive nuclides of concern in the treatment of mixed wastes are 239 Pu, 238 U, 235 U, 137 Cs, 103 Ru, 99 Tc, and 90 Sr. These nuclides are largely by-products of uranium enrichment, reactor fuel reprocessing, and weapons program activities. Cs, Ru, and Sr all have stable isotopes that can be used as perfect surrogates for the radioactive forms. Technetium exists only in radioactive form, as do plutonium and uranium. If one wishes to preclude radioactive contamination of the thermal treatment system under trial burn, surrogate elements must be chosen for these three. For technetium, the authors suggest the use of natural ruthenium, and for both plutonium and uranium, they recommend cerium. The seven radionuclides listed can therefore be simulated by a surrogate package containing stable isotopes of ruthenium, strontium, cesium, and cerium

  14. Behavior of mixed-oxide fuel subjected to multiple thermal transients

    International Nuclear Information System (INIS)

    Fenske, G.R.; Hofman, G.L.; Neimark, L.A.; Poeppel, R.B.

    1983-11-01

    The microstructural behavior of irradiated mixed-oxide fuel subjected to multiple, mild thermal transients was investigated using direct electrical heating. The results demonstrate that significant intergranular porosity, accompanied by large-scale (>90%) release of the retained fission gas, developed as a result of the cyclic heating. Microstructural examination of the fuel indicated that thermal-shock-induced cracking of the fuel contributed significantly to the increased swelling and gas release

  15. Low level mixed waste thermal treatment technical basis report

    Energy Technology Data Exchange (ETDEWEB)

    Place, B.G.

    1994-12-01

    Detailed characterization of the existing and projected Hanford Site Radioactive Mixed Waste (RMW) inventory was initiated in 1993 (Place 1993). This report presents an analysis of the existing and projected RMW inventory. The subject characterization effort continues to be in support of the following engineering activities related to thermal treatment of Hanford Site RMW: (1) Contracting for commercial thermal treatment; (2) Installation and operation of an onsite thermal treatment facility (Project W-242); (3) Treatment at another Department of Energy (DOE) site. The collation of this characterization information (data) has emphasized the establishment of a common data base for the entire existing RMW inventory so that the specification of feed streams destined for different treatment facilities can be coordinated.

  16. Low level mixed waste thermal treatment technical basis report

    International Nuclear Information System (INIS)

    Place, B.G.

    1994-12-01

    Detailed characterization of the existing and projected Hanford Site Radioactive Mixed Waste (RMW) inventory was initiated in 1993 (Place 1993). This report presents an analysis of the existing and projected RMW inventory. The subject characterization effort continues to be in support of the following engineering activities related to thermal treatment of Hanford Site RMW: (1) Contracting for commercial thermal treatment; (2) Installation and operation of an onsite thermal treatment facility (Project W-242); (3) Treatment at another Department of Energy (DOE) site. The collation of this characterization information (data) has emphasized the establishment of a common data base for the entire existing RMW inventory so that the specification of feed streams destined for different treatment facilities can be coordinated

  17. Addressing mixed waste in plutonium processing

    International Nuclear Information System (INIS)

    Christensen, D.C.; Sohn, C.L.; Reid, R.A.

    1991-01-01

    The overall goal is the minimization of all waste generated in actinide processing facilities. Current emphasis is directed toward reducing and managing mixed waste in plutonium processing facilities. More specifically, the focus is on prioritizing plutonium processing technologies for development that will address major problems in mixed waste management. A five step methodological approach to identify, analyze, solve, and initiate corrective action for mixed waste problems in plutonium processing facilities has been developed

  18. Mixed Waste Integrated Program interim evaluation report on thermal treatment technologies

    International Nuclear Information System (INIS)

    Gillins, R.L.; DeWitt, L.M.; Wollerman, A.L.

    1993-02-01

    The Mixed Waste Integrated Program (MWIP) is one of several US Department of Energy (DOE) integrated programs established to organize and coordinate throughout the DOE complex the development of technologies for treatment of specific waste categories. The goal of the MWIP is to develop and deploy appropriate technologies for -the treatment of DOE mixed low-level and alpha-contaminated wastes in order to bring all affected DOE installations and projects into compliance with environmental laws. Evaluation of treatment technologies by the MWIP will focus on meeting waste form performance requirements for disposal. Thermal treatment technologies were an early emphasis for the MWIP because thermal treatment is indicated (or mandated) for many of the hazardous constituents in DOE mixed waste and because these technologies have been widely investigated for these applications. An advisory group, the Thermal Treatment Working Group (TTWG), was formed during the program's infancy to assist the MWIP in evaluating and prioritizing thermal treatment technologies suitable for development. The results of the overall evaluation scoring indicate that the four highest-rated technologies were rotary kilns, slagging kilns, electric-arc furnaces, and plasma-arc furnaces. The four highest-rated technologies were all judged to be applicable on five of the six waste streams and are the only technologies in the evaluation with this distinction. Conclusions as to the superiority of one technology over others are not valid based on this preliminary study, although some general conclusions can be drawn

  19. Behavior of mixed-oxide fuel subjected to multiple thermal transients

    International Nuclear Information System (INIS)

    Fenske, G.R.; Neimark, L.A.; Poeppel, R.B.; Hofman, G.L.

    1985-01-01

    The microstructural behavior of irradiated mixed-oxide fuel subjected to multiple, mild thermal transients was investigated using direct electrical heating. The results demonstrate that significant intergranular porosity, accompanied by large-scale (>90%) release of the retained fission gas, developed as a result of the cyclic heating. Microstructural examination of the fuel indicated that thermal-shock-induced cracking of the fuel contributed significantly to the increased swelling and gas release. 29 refs., 12 figs

  20. T-junction cross-flow mixing with thermally driven density stratification

    Energy Technology Data Exchange (ETDEWEB)

    Kickhofel, John, E-mail: jkickhofel@gmail.com [Laboratory of Nuclear Energy Systems, ETH Zurich, Sonneggstrasse 3, 8057 Zurich (Switzerland); Prasser, Horst-Michael, E-mail: prasser@lke.mavt.ethz.ch [Laboratory of Nuclear Energy Systems, ETH Zurich, Sonneggstrasse 3, 8057 Zurich (Switzerland); Selvam, P. Karthick, E-mail: karthick.selvam@ike.uni-stuttgart.de [Institute of Nuclear Technology and Energy Systems (IKE), University of Stuttgart, Pfaffenwaldring 31, 70569 Stuttgart (Germany); Laurien, Eckart, E-mail: eckart.laurien@ike.uni-stuttgart.de [Institute of Nuclear Technology and Energy Systems (IKE), University of Stuttgart, Pfaffenwaldring 31, 70569 Stuttgart (Germany); Kulenovic, Rudi, E-mail: rudi.kulenovic@ike.uni-stuttgart.de [Institute of Nuclear Technology and Energy Systems (IKE), University of Stuttgart, Pfaffenwaldring 31, 70569 Stuttgart (Germany)

    2016-12-01

    Highlights: • Mesh sensor for realistic nuclear thermal hydraulic scenarios is demonstrated. • Flow temperature behavior across a wide range of Richardson numbers measured. • Upstream stratified flow in the T-junction results in a thermal shock scenario. • Large, stable near-wall thermal gradients exist in spite of turbulent flows. - Abstract: As a means of further elucidating turbulence- and stratification-driven thermal fatigue in the vicinity of T-junctions in nuclear power plants, a series of experiments have been conducted at the high temperature high pressure fluid–structure interaction T-junction facility of the University of Stuttgart with novel fluid measurement instrumentation. T-junction mixing with large fluid temperature gradients results in complex flow behavior, the result of density driven effects. Deionized water mixing at temperature differences of up to 232 K at 7 MPa pressure have been investigated in a T-junction with main pipe diameter 71.8 mm and branch line diameter 38.9 mm. The experiments have been performed with fixed flow rates of 0.4 kg/s in the main pipe and 0.1 kg/s in the branch line. A novel electrode-mesh sensor compatible with the DN80 PN100 pipeline upstream and downstream of the T-junction has been utilized as a temperature sensor providing a high density information in the pipe cross-section in both space and time. Additionally, in-flow and in-wall thermocouples quantify the damping of thermal fluctuations by the wall material. The results indicate that large inflow temperature differences lead to strong turbulence damping, and ultimately stable stratification extending both downstream and upstream of the T-junction resulting in large local thermal gradients.

  1. Application of thermal scanning to the study of transverse mixing in rivers

    Science.gov (United States)

    Eheart, J. W.

    1975-01-01

    Remote sensing has shown itself to be a valuable research tool in the study of transverse mixing in rivers. It is desirable, for a number of reasons, to study and predict the two-dimensional movement of pollutants in the region just downstream of a pollutant discharge point. While many of the more common pollutants do not exhibit a spectral signature, it was shown that the temperature difference between the pollutant and the receiving water could be successfully exploited by applying a mathematical model of mass transport processes to heat transport, and testing and calibrating it with thermal scanning data.

  2. Process modeling for the Integrated Thermal Treatment System (ITTS) study

    Energy Technology Data Exchange (ETDEWEB)

    Liebelt, K.H.; Brown, B.W.; Quapp, W.J.

    1995-09-01

    This report describes the process modeling done in support of the integrated thermal treatment system (ITTS) study, Phases 1 and 2. ITTS consists of an integrated systems engineering approach for uniform comparison of widely varying thermal treatment technologies proposed for treatment of the contact-handled mixed low-level wastes (MLLW) currently stored in the U.S. Department of Energy complex. In the overall study, 19 systems were evaluated. Preconceptual designs were developed that included all of the various subsystems necessary for a complete installation, from waste receiving through to primary and secondary stabilization and disposal of the processed wastes. Each system included the necessary auxiliary treatment subsystems so that all of the waste categories in the complex were fully processed. The objective of the modeling task was to perform mass and energy balances of the major material components in each system. Modeling of trace materials, such as pollutants and radioactive isotopes, were beyond the present scope. The modeling of the main and secondary thermal treatment, air pollution control, and metal melting subsystems was done using the ASPEN PLUS process simulation code, Version 9.1-3. These results were combined with calculations for the remainder of the subsystems to achieve the final results, which included offgas volumes, and mass and volume waste reduction ratios.

  3. Process modeling for the Integrated Thermal Treatment System (ITTS) study

    International Nuclear Information System (INIS)

    Liebelt, K.H.; Brown, B.W.; Quapp, W.J.

    1995-09-01

    This report describes the process modeling done in support of the integrated thermal treatment system (ITTS) study, Phases 1 and 2. ITTS consists of an integrated systems engineering approach for uniform comparison of widely varying thermal treatment technologies proposed for treatment of the contact-handled mixed low-level wastes (MLLW) currently stored in the U.S. Department of Energy complex. In the overall study, 19 systems were evaluated. Preconceptual designs were developed that included all of the various subsystems necessary for a complete installation, from waste receiving through to primary and secondary stabilization and disposal of the processed wastes. Each system included the necessary auxiliary treatment subsystems so that all of the waste categories in the complex were fully processed. The objective of the modeling task was to perform mass and energy balances of the major material components in each system. Modeling of trace materials, such as pollutants and radioactive isotopes, were beyond the present scope. The modeling of the main and secondary thermal treatment, air pollution control, and metal melting subsystems was done using the ASPEN PLUS process simulation code, Version 9.1-3. These results were combined with calculations for the remainder of the subsystems to achieve the final results, which included offgas volumes, and mass and volume waste reduction ratios

  4. Comparison between thermal annealing and ion mixing of alloyed Ni-W films on Si. I

    International Nuclear Information System (INIS)

    Pai, C.S.; Lau, S.S.; Poker, D.B.; Hung, L.S.

    1985-01-01

    The reactions between Ni-W alloys and Si substrates induced by thermal annealing and ion mixing were investigated and compared. Samples were prepared by sputtering of Ni-W alloys, both Ni-rich and W-rich, onto the Si substrates, and followed by either furnace annealing (200--900 0 C) or ion mixing (2 x 10 15 -- 4 x 10 16 86 Kr + ions/cm 2 ). The reactions were analyzed by Rutherford backscattering and x-ray diffraction (Read camera). In general, thermal annealing and ion mixing lead to similar reactions. Phase separation between Ni and W with Ni silicides formed next to the Si substrate and W silicide formed on the surface was observed for both Ni-rich and W-rich samples under thermal annealing. Phase separation was also observed for Ni-rich samples under ion mixing; however, a Ni-W-Si ternary compound was possibly formed for ion-mixed W-rich samples. These reactions were rationalized in terms of the mobilities of various atoms and the energetics of the systems

  5. Preliminary comparison of three processes of AlN oxidation: dry, wet and mixed ones

    Directory of Open Access Journals (Sweden)

    Korbutowicz R.

    2016-03-01

    Full Text Available Three methods of AlN layers oxidation: dry, wet and mixed (wet with oxygen were compared. Some physical parameters of oxidized thin films of aluminum nitride (AlN layers grown on silicon Si(1 1 1 were investigated by means Energy-Dispersive X-ray Spectroscopy (EDS and Spectroscopic Ellipsometry (SE. Three series of the thermal oxidations processes were carried out at 1012 °C in pure nitrogen as carrying gas and various gas ambients: (a dry oxidation with oxygen, (b wet oxidation with water steam and (c mixed atmosphere with various process times. All the research methods have shown that along with the rising of the oxidation time, AlN layer across the aluminum oxide nitride transforms to aluminum oxide. The mixed oxidation was a faster method than the dry or wet ones.

  6. Rapid thermal processing and beyond applications in semiconductor processing

    CERN Document Server

    Lerch, W

    2008-01-01

    Heat-treatment and thermal annealing are very common processing steps which have been employed during semiconductor manufacturing right from the beginning of integrated circuit technology. In order to minimize undesired diffusion, and other thermal budget-dependent effects, the trend has been to reduce the annealing time sharply by switching from standard furnace batch-processing (involving several hours or even days), to rapid thermal processing involving soaking times of just a few seconds. This transition from thermal equilibrium, to highly non-equilibrium, processing was very challenging a

  7. Molten salt processing of mixed wastes with offgas condensation

    International Nuclear Information System (INIS)

    Cooper, J.F.; Brummond, W.; Celeste, J.; Farmer, J.; Hoenig, C.; Krikorian, O.H.; Upadhye, R.; Gay, R.L.; Stewart, A.; Yosim, S.

    1991-01-01

    We are developing an advanced process for treatment of mixed wastes in molten salt media at temperatures of 700--1000 degrees C. Waste destruction has been demonstrated in a single stage oxidation process, with destruction efficiencies above 99.9999% for many waste categories. The molten salt provides a heat transfer medium, prevents thermal surges, and functions as an in situ scrubber to transform the acid-gas forming components of the waste into neutral salts and immobilizes potentially fugitive materials by a combination of particle wetting, encapsulation and chemical dissolution and solvation. Because the offgas is collected and assayed before release, and wastes containing toxic and radioactive materials are treated while immobilized in a condensed phase, the process avoids the problems sometimes associated with incineration processes. We are studying a potentially improved modification of this process, which treats oxidizable wastes in two stages: pyrolysis followed by catalyzed molten salt oxidation of the pyrolysis gases at ca. 700 degrees C. 15 refs., 5 figs., 1 tab

  8. Comparison of measured and predicted thermal mixing tests using improved finite difference technique

    International Nuclear Information System (INIS)

    Hassan, Y.A.; Rice, J.G.; Kim, J.H.

    1983-01-01

    The numerical diffusion introduced by the use of upwind formulations in the finite difference solution of the flow and energy equations for thermal mixing problems (cold water injection after small break LOCA in a PWR) was examined. The relative importance of numerical diffusion in the flow equations, compared to its effect on the energy equation was demonstrated. The flow field equations were solved using both first order accurate upwind, and second order accurate differencing schemes. The energy equation was treated using the conventional upwind and a mass weighted skew upwind scheme. Results presented for a simple test case showed that, for thermal mixing problems, the numerical diffusion was most significant in the energy equation. The numerical diffusion effect in the flow field equations was much less significant. A comparison of predictions using the skew upwind and the conventional upwind with experimental data from a two dimensional thermal mixing text are presented. The use of the skew upwind scheme showed a significant improvement in the accuracy of the steady state predicted temperatures. (orig./HP)

  9. Impact of a 1,000-foot thermal mixing zone on the steam electric power industry

    International Nuclear Information System (INIS)

    Veil, J.A.

    1994-04-01

    Thermal discharge requirements for power plants using once-through cooling systems are based on state water quality standards for temperatures that must be met outside of designated mixing zones. This study evaluates the impact of limiting the extent of thermal mixing zones. This study evaluates the impact of limiting the extent of thermal mixing zones to no more than 1,000 feet from the discharge point. Data were collected from 79 steam electric plants. Of the plants currently using once-through cooling systems, 74% could not meet current thermal standards at the edge of a 1,000-foot mixing zone. Of this total, 68% would retrofit cooling towers, and 6% would retrofit diffusers. The estimated nationwide capital cost for retrofitting plants that could not meet current thermal standards at the edge of a 1,000-foot mixing zone is $21.4 billion. Conversion of a plant from once-through cooling to cooling towers or addition of diffusers would result in a lower energy output from that plant. For the affected plants, the total estimated replacement cost would be $370 to $590 million per year. Some power companies would have to construct new generating capacity to meet the increased energy demand. The estimated nationwide cost of this additional capacity would be $1.2 to $4.8 billion. In addition to the direct costs associated with compliance with a 1,000-foot mixing zone limit, other secondary environmental impacts would also occur. Generation of the additional power needed would increase carbon dioxide emissions by an estimated 8.3 million tons per year. In addition, conversion from once-through cooling systems to cooling towers at affected plants would result in increased evaporation of about 2.7 million gallons of water per minute nationwide

  10. Large eddy simulation on thermal mixing of fluids in a T-junction with conjugate heat transfer

    Energy Technology Data Exchange (ETDEWEB)

    Selvam, P. Karthick, E-mail: karthick.selvam@ike.uni-stuttgart.de; Kulenovic, Rudi, E-mail: rudi.kulenovic@ike.uni-stuttgart.de; Laurien, Eckart, E-mail: eckart.laurien@ike.uni-stuttgart.de

    2015-04-01

    Highlights: • LES of fluid mixing in a T-junction at ΔT = 117 K and 123 K is performed. • Dynamical thermal stratification flow behavior downstream of T-junction. • Temperature fluctuations have maximum amplitudes of about 3.4–5.6% of ΔT. • High amplitude fluctuations occur near stratification layer in the mixing region. • Energy of temperature fluctuations mainly contained in the range 0.1–3 Hz. - Abstract: High cycle thermal fatigue failure in a nuclear power plant T-junction piping system may be caused by near-wall temperature fluctuations due to thermal mixing of hot and cold fluid streams. In the present study, thermal mixing at temperature differences (ΔT) of 117 K and 123 K between the mixing fluids is numerically investigated using Large Eddy Simulation (LES) method with the commercial Computational Fluid Dynamics (CFD) software ANSYS CFX 14.0. LES results from the study are validated with experimental data obtained from Fluid–Structure Interaction (FSI) test facility at the Materials Testing Institute (MPA), University of Stuttgart. Mass flow rate ratios (main/branch) in both cases are 4 and 6, respectively. LES results in both cases show that there is incomplete mixing of fluids and within three diameters downstream of T-junction, the mixing results in a dynamical thermal stratification flow behavior, which is maintained throughout the computational domain. Mean temperature predictions by LES show good agreement with the experimental data, whereas the root mean square (RMS) temperature fluctuations are over or understated at a few positions. The temperature fluctuations have amplitudes ranging from 0.09 to 5.6% of ΔT between the mixing fluids. Incomplete mixing of fluids and relatively lower amplitude of temperature fluctuations are mainly due to lower Reynolds number of 3670 in the cold fluid coming from the branch pipe along with buoyancy effects in the flow due to higher inflow temperature in the main pipe.

  11. Non-linear thermal engineering, chaotic advection and mixing; Thermique non-lineaire, melange et advection chaotique

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-12-31

    This conference day was jointly organized by the `university group of thermal engineering (GUT)` and the French association of thermal engineers. This book of proceedings contains 7 papers entitled: `energy spectra of a passive scalar undergoing advection by a chaotic flow`; `analysis of chaotic behaviours: from topological characterization to modeling`; `temperature homogeneity by Lagrangian chaos in a direct current flow heat exchanger: numerical approach`; ` thermal instabilities in a mixed convection phenomenon: nonlinear dynamics`; `experimental characterization study of the 3-D Lagrangian chaos by thermal analogy`; `influence of coherent structures on the mixing of a passive scalar`; `evaluation of the performance index of a chaotic advection effect heat exchanger for a wide range of Reynolds numbers`. (J.S.)

  12. Non-linear thermal engineering, chaotic advection and mixing; Thermique non-lineaire, melange et advection chaotique

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-12-31

    This conference day was jointly organized by the `university group of thermal engineering (GUT)` and the French association of thermal engineers. This book of proceedings contains 7 papers entitled: `energy spectra of a passive scalar undergoing advection by a chaotic flow`; `analysis of chaotic behaviours: from topological characterization to modeling`; `temperature homogeneity by Lagrangian chaos in a direct current flow heat exchanger: numerical approach`; ` thermal instabilities in a mixed convection phenomenon: nonlinear dynamics`; `experimental characterization study of the 3-D Lagrangian chaos by thermal analogy`; `influence of coherent structures on the mixing of a passive scalar`; `evaluation of the performance index of a chaotic advection effect heat exchanger for a wide range of Reynolds numbers`. (J.S.)

  13. Sludge thermal oxidation processes: mineral recycling, energy impact, and greenhouse effect gases release

    Energy Technology Data Exchange (ETDEWEB)

    Guibelin, Eric

    2003-07-01

    Different treatment routes have been studied for a mixed sludge: the conventional agricultural use is compared with the thermal oxidation processes, including incineration (in gaseous phase) and wet air oxidation (in liquid phase). The interest of a sludge digestion prior to the final treatment has been also considered according to the two major criteria, which are the fossil energy utilisation and the greenhouse effect gases (CO{sub 2}, CH{sub 4}, N{sub 2}O) release. Thermal energy has to be recovered on thermal processes to make these processes environmentally friendly, otherwise their main interest is to extract or destroy micropollutants and pathogens from the carbon cycle. In case of continuous energy recovery, incineration can produce more energy than it consumes. Digestion is especially interesting for agriculture: according to these two schemes, the energy final balance can also be in excess. As to wet air oxidation, it is probably one of the best way to minimize greenhouse effect gases emission. (author)

  14. Industrial application of thermal image processing and thermal control

    Science.gov (United States)

    Kong, Lingxue

    2001-09-01

    Industrial application of infrared thermography is virtually boundless as it can be used in any situations where there are temperature differences. This technology has particularly been widely used in automotive industry for process evaluation and system design. In this work, thermal image processing technique will be introduced to quantitatively calculate the heat stored in a warm/hot object and consequently, a thermal control system will be proposed to accurately and actively manage the thermal distribution within the object in accordance with the heat calculated from the thermal images.

  15. Progress Report on SAM Reduced-Order Model Development for Thermal Stratification and Mixing during Reactor Transients

    Energy Technology Data Exchange (ETDEWEB)

    Hu, R. [Argonne National Lab. (ANL), Argonne, IL (United States)

    2017-09-01

    This report documents the initial progress on the reduced-order flow model developments in SAM for thermal stratification and mixing modeling. Two different modeling approaches are pursued. The first one is based on one-dimensional fluid equations with additional terms accounting for the thermal mixing from both flow circulations and turbulent mixing. The second approach is based on three-dimensional coarse-grid CFD approach, in which the full three-dimensional fluid conservation equations are modeled with closure models to account for the effects of turbulence.

  16. Effect of Mixing Process on Polypropylene Modified Bituminous Concrete Mix Properties

    OpenAIRE

    Noor Zainab Habib; Ibrahim Kamaruddin; Madzalan Napiah; Isa Mohd Tan

    2011-01-01

    This paper presents a research conducted to investigate the effect of mixing process on polypropylene (PP) modified bitumen mixed with well graded aggregate to form modified bituminous concrete mix. Two mode of mixing, namely dry and wet with different concentration of polymer polypropylene was used with 80/100 pen bitumen, to evaluate the bituminous concrete mix properties. Three percentages of polymer varying from 1-3% by the weight of bitumen was used in this study. Three mixes namely cont...

  17. Preliminary study on acceptability of scope of thermal discharge mixing zone for nuclear power plant

    International Nuclear Information System (INIS)

    Liu Yongye; Yang Yang; Wang Liang; Chen Xiaoqiu; Liu Senlin

    2012-01-01

    Based on the situation that the existing domestic temperature control standards are not performable, the preliminary study on the acceptability of the mixing zone scope of thermal discharge for nuclear power plant was conducted in this paper, taking a coastal power station SNP as a case. The following preliminary conclusions could be drawn from the results of cluster analysis of the SNP site under different results of mathematical modeling and physical model test: 1) The influence intensity of ecological function of the SNP site seawater is small and the scope of thermal discharge mixing zone is acceptable under SNP-1 (Unit 1 and 2) operating condition; 2) the influence intensity of ecological function of the SNP site seawater is small and the scope of thermal discharge mixing zone is acceptable in spring under SNP-1 (Unit 1 and 2) and SNP-2 (Unit 3 and 4) operating condition, while the influence intensity of ecological function of the SNP site seawater is large and the scope of mixing zone is unacceptable in autumn under the same operating condition. (authors)

  18. Oil mixes omega 9, 6 and 3, enriched with seaweed, promoted reduction of thermal burned modulating NF-kB and Ki-67.

    Science.gov (United States)

    Campelo, Ana Paula Bomfim Soares; Campelo, Márcio Wilker Soares; Brito, Gerly Anne de Castro; Jamacaru, Francisco Vagnaldo Fechine; Leitão, Renata Ferreira de Carvalho; Vasconcelos, Paulo Roberto Leitão de

    2015-06-01

    To examine the effects of the oil mixes (ω-9, ω-6 and ω-3) in rats subjected to thermal burn. It was also aimed to assess whether the sources of ω3 would interfere with the effect of such mixes on the thermal injury. Thirty-six rats distributed into five groups: burned + water, burned + isolipid mix, burned + oil mix 1 (ALA), burned + oil mix 2 (ALA + EPA + DHA of fish) and burned + oil mix 3 (ALA + DHA from seaweed). The thermal injury was involving total thickness of skin. After the burns animals received the oil mixes for seven days. The lesions were evaluated by immunohistochemistry. Animals receiving mix 3 showed a smaller extension of the thermal injury as compared to those that were supplemented with other oils mixes. Expression of Ki-67 in the receiving Mix 3 increased as compared to all the other groups. Animals supplemented with mix 3 were able to inhibit NF-κB in injured tissue. Rats received oil mix in which the source of ω3 (ALA+DHA of seaweed) showed inhibition of NF-κB, increase in cell proliferation, and reduction the extension of thermal lesion.

  19. Effect of Water-Air Clearing on Thermal Mixing in IRWST Using Three-Dimensional CFD Analysis

    International Nuclear Information System (INIS)

    Ha, Jeong Hee; Lee, Doo Yong; Hong, Soon Joon; Jeong, Jae Sik; Park, Man Heung; Moon, Young Tae

    2013-01-01

    In this paper, the water-air clearing effects on thermal mixing in the IRWST were investigated with the CFD simulation. The boundary conditions for each discharge phase were obtained from the RELAP5 simulation. The flow distribution in the IRWST for the water clearing phase was reflected as the initial condition for the air clearing simulation. The flow distribution for the air clearing phase was applied as the initial condition for the steam condensation phase. The result of the steam condensation phase with the SCRM showed that the thermal mixing in the IRWST might be enhanced by the mixing effects of the water-air clearing before the steam discharge. IRWST (in-containment refueling water storage tank) is one of the advanced design features of APR1400 (Advanced Power Reactor . 1400). Connected to the Safety Depressurization and Vent System (SDVS), IRWST is designed to absorb the high energy flow from Pilot Operated Safety and Relief Valves (POSRVs) to protect the over-pressurization of the Reactor Coolant System. Due to thermal hydraulic loads induced by discharged fluids, it is crucial to understand the phenomena occur in the IRWST and thermal mixing is one of them. It has been known that the unstable steam condensation which results in oscillations and acts as the loads on the IRWST wall and structures can occur if there is a large local temperature difference. Thus, there is a regulation related to IRWST temperature distribution (difference) to be satisfied. To understand the phenomena and design the IRWST with sufficient safety margin, many experimental and numerical researches have been performed. The results of these researches showed that the CFD analysis predicts well the temperature distribution in the pool globally and can be a proper evaluation methodology to analyze the complex thermal mixing phenomena in the IRWST with a sufficiently fine mesh distribution and proper numerical models. But the previous studies have tended to focus the phenomenological

  20. Feasibility study on using imaging plates to estimate thermal neutron fluence in neutron-gamma mixed fields

    International Nuclear Information System (INIS)

    Fujibuchi, T.; Tanabe, Y.; Sakae, T.; Terunuma, T.; Isobe, T.; Kawamura, H.; Yasuoka, K.; Matsumoto, T.; Harano, H.; Nishiyama, J.; Masuda, A.; Nohtomi, A.

    2011-01-01

    In current radiotherapy, neutrons are produced in a photonuclear reaction when incident photon energy is higher than the threshold. In the present study, a method of discriminating the neutron component was investigated using an imaging plate (IP) in the neutron-gamma-ray mixed field. Two types of IP were used: a conventional IP for beta- and gamma rays, and an IP doped with Gd for detecting neutrons. IPs were irradiated in the mixed field, and the photo-stimulated luminescence (PSL) intensity of the thermal neutron component was discriminated using an expression proposed herein. The PSL intensity of the thermal neutron component was proportional to thermal neutron fluence. When additional irradiation of photons was added to constant neutron irradiation, the PSL intensity of the thermal neutron component was not affected. The uncertainty of PSL intensities was approximately 11.4 %. This method provides a simple and effective means of discriminating the neutron component in a mixed field. (authors)

  1. Rapid thermal processing by stamping

    Science.gov (United States)

    Stradins, Pauls; Wang, Qi

    2013-03-05

    A rapid thermal processing device and methods are provided for thermal processing of samples such as semiconductor wafers. The device has components including a stamp (35) having a stamping surface and a heater or cooler (40) to bring it to a selected processing temperature, a sample holder (20) for holding a sample (10) in position for intimate contact with the stamping surface; and positioning components (25) for moving the stamping surface and the stamp (35) in and away from intimate, substantially non-pressured contact. Methods for using and making such devices are also provided. These devices and methods allow inexpensive, efficient, easily controllable thermal processing.

  2. Growth, thermal and laser properties of Yb:YxLu1−xVO4 mixed crystal

    International Nuclear Information System (INIS)

    Zhong, Degao; Teng, Bing; Kong, Weijin; Li, Jianhong; Zhang, Shiming; Li, Yuyi; Cao, Lifeng; Yang, Liting; He, Linxiang; Huang, Wanxia

    2015-01-01

    New mixed crystal of Yb: Y 0.78 Lu 0.22 VO 4 with Yb ion concentration of 0.3 at% was grown by Czochralski method. Transmission synchrotron X-ray topography implies that this mixed crystal follows a rotational growth pattern. Crystal structure of this crystal was determined by X-ray diffraction. It showed that this crystal possesses a tetragonal zircon structure (ZrSiO 4 , space group I41/amd), as YVO 4 and LuVO 4 do. Thermal properties of this crystal were characterized by measuring its specific heat, thermal expansion coefficients and thermal conductivities. The specific heat was determined to be 0.500 J g −1 K −1 at 293 K. The average linear thermal expansion coefficients were calculated to be α 11 = 1.73 × 10 −6 K −1 and α 33 = 9.43 × 10 −6 K −1 , over the temperature range of 300–777 K. The thermal conductivities were calculated to be κ 11 = 5.47 W m −1 K −1 and κ 33 = 6.64 W m −1 K −1 at 303 K. Continuous-wave (cw) laser test on Yb: Y 0.78 Lu 0.22 VO 4 was conducted at room temperature in the wavelength range of 1035.7–1048.3 nm, and a 13.5% optical-to-optical efficiency was achieved. The good thermal properties of Yb:Y 0.78 Lu 0.22 VO 4 mixed crystal and its attractive cw laser performance make it very suitable for practical applications. - Highlights: • New Yb:Y 0.78 Lu 0.22 VO 4 mixed laser crystals were grown. • The thermal expansion, thermal diffusivity and specific heat were measured. • Cw laser operation was realized at room temperature in the range of 1035.7–1048.3 nm

  3. Integrated process analysis of treatment systems for mixed low level waste

    International Nuclear Information System (INIS)

    Cooley, C.R.; Schwinkendorf, W.E.; Bechtold, T.E.

    1997-10-01

    Selection of technologies to be developed for treatment of DOE's mixed low level waste (MLLW) requires knowledge and understanding of the expected costs, schedules, risks, performance, and reliability of the total engineered systems that use these technologies. Thus, an integrated process analysis program was undertaken to identify the characteristics and needs of several thermal and nonthermal systems. For purposes of comparison, all systems were conceptually designed for a single facility processing the same amount of waste at the same rate. Thirty treatment systems were evaluated ranging from standard incineration to innovative thermal systems and innovative nonthermal chemical treatment. Treating 236 million pounds of waste in 20 years through a central treatment was found to be the least costly option with total life cycle cost ranging from $2.1 billion for a metal melting system to $3.9 billion for a nonthermal acid digestion system. Little cost difference exists among nonthermal systems or among thermal systems. Significant cost savings could be achieved by working towards maximum on line treatment time per year; vitrifying the final waste residue; decreasing front end characterization segregation and sizing requirements; using contaminated soil as the vitrifying agent; and delisting the final vitrified waste form from Resource Conservation and Recovery Act (RCRA) Land Disposal Restriction (LDR) requirements

  4. Study on the dose distribution of the mixed field with thermal and epi-thermal neutrons for neutron capture therapy

    International Nuclear Information System (INIS)

    Kobayashi, Tooru; Sakurai, Yoshinori; Kanda, Keiji

    1994-01-01

    Simulation calculations using DOT 3.5 were carried out in order to confirm the characteristics of depth-dependent dose distribution in water phantom dependent on incident neutron energy. The epithermal neutrons mixed to thermal neutron field is effective improving the thermal neutron depth-dose distribution for neutron capture therapy. A feasibility study on the neutron energy spectrum shifter was performed using ANISN-JR for the KUR Heavy Water Facility. The design of the neutron spectrum shifter is feasible, without reducing the performance as a thermal neutron irradiation field. (author)

  5. Oil mixes omega 9, 6 and 3, enriched with seaweed, promoted reduction of thermal burned modulating NF-kB and Ki-67

    OpenAIRE

    Campelo, Ana Paula Bomfim Soares; Campelo, Márcio Wilker Soares; Brito, Gerly Anne de Castro; Jamacaru, Francisco Vagnaldo Fechine; Leitão, Renata Ferreira de Carvalho; Vasconcelos, Paulo Roberto Leitão de

    2015-01-01

    PURPOSE: To examine the effects of the oil mixes (ω-9, ω-6 and ω-3) in rats subjected to thermal burn. It was also aimed to assess whether the sources of ω3 would interfere with the effect of such mixes on the thermal injury.METHODS:Thirty-six rats distributed into five groups: burned + water, burned + isolipid mix, burned + oil mix 1 (ALA), burned + oil mix 2 (ALA + EPA + DHA of fish) and burned + oil mix 3 (ALA + DHA from seaweed). The thermal injury was involving total ...

  6. Purification process of natural graphite as anode for Li-ion batteries: chemical versus thermal

    Science.gov (United States)

    Zaghib, K.; Song, X.; Guerfi, A.; Rioux, R.; Kinoshita, K.

    The intercalation of Li ions in natural graphite that was purified by chemical and thermal processes was investigated. A new chemical process was developed that involved a mixed aqueous solution containing 30% H 2SO 4 and 30% NH xF y heated to 90 °C. The results of this process are compared to those obtained by heating the natural graphite from 1500 to 2400 °C in an inert environment (thermal process). The first-cycle coulombic efficiency of the purified natural graphite obtained by the chemical process is 91 and 84% after the thermal process at 2400 °C. Grinding the natural graphite before or after purification had no significant effect on electrochemical performance at low currents. However, grinding to a very small particle size before purification permitted optimization of the size distribution of the particles, which gives rise to a more homogenous electrode. The impurities in the graphite play a role as microabrasion agents during grinding which enhances its hardness and improves its mechanical properties. Grinding also modifies the particle morphology from a 2- to a 3-D structure (similar in shape to a potato). This potato-shaped natural graphite shows high reversible capacity at high current densities (about 90% at 1 C rate). Our analysis suggests that thermal processing is considerably more expensive than the chemical process to obtain purified natural graphite.

  7. Non-Thermal Treatment of Hanford Site Low-Level Mixed Waste

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-09-01

    DOE proposes to transport contact-handled LLMW from the Hanford Site to the Allied Technology Group (ATG) Mixed Waste Facility (MWF) in Richland, Washington, for non-thermal treatment and to return the treated waste to the Hanford Site for eventual land disposal. Over a 3-year period the waste would be staged to the ATG MWF, and treated waste would be returned to the Hanford Site. The ATG MWF would be located on an 18 hectare (ha) (45 acre [at]) ATG Site adjacent to ATG's licensed low-level waste processing facility at 2025 Battelle Boulevard. The ATG MWF is located approximately 0.8 kilometers (km) (0.5 miles [mi]) south of Horn Rapids Road and 1.6 km (1 mi) west of Stevens Drive. The property is located within the Horn Rapids triangle in northern Richland (Figure 2.1). The ATG MWF is to be located on the existing ATG Site, near the DOE Hanford Site, in an industrial area in the City of Richland. The effects of siting, construction, and overall operation of the MWF have been evaluated in a separate State Environmental Policy Act (SEPA) EIS (City of Richland 1998). The proposed action includes transporting the LLMW from the Hanford Site to the ATG Facility, non-thermal treatment of the LLMW at the ATG MWF, and transporting the waste from ATG back to the Hanford Site. Impacts fi-om waste treatment operations would be bounded by the ATG SEPA EIS, which included an evaluation of the impacts associated with operating the non-thermal portion of the MWF at maximum design capacity (8,500 metric tons per year) (City of Richland 1998). Up to 50 employees would be required for non-thermal treatment portion of the MWF. This includes 40 employees that would perform waste treatment operations and 10 support staff. Similar numbers were projected for the thermal treatment portion of the MWF (City of Richland 1998).

  8. The 1996 meeting of the national technical workgroup on mixed waste thermal treatment

    International Nuclear Information System (INIS)

    1996-01-01

    The National Technical Workgroup on Mixed Waste Thermal Treatment held its annual meeting in Atlanta Georgia on March 12-14, 1996. The National Technical Workgroup (NTW) and this meeting were sponsored under an interagency agreement between EPA and DOE. The 1996 Annual Meeting was hosted by US DOE Oak Ridge Operations in conjunction with Lockheed Martin Energy Systems - Center for Waste Management. A new feature of the annual meeting was the Permit Writer Panel Session which provided an opportunity for the state and federal permit writers to discuss issues and potential solutions to permitting mixed waste treatment systems. In addition, there was substantial discussion on the impacts of the Waste Combustion Performance Standards on mixed waste thermal treatment which are expected to proposed very soon. The 1996 meeting also focussed on two draft technical resource documents produced by NTW on Waste Analysis Plans and Compliance Test Procedures. Issues discussed included public involvement, waste characterization, and emission issues

  9. Mixed Field Modification of Thermally Cured Castor Oil Based Polyurethanes

    International Nuclear Information System (INIS)

    Mortley, A.

    2006-01-01

    Thermally cured polyurethanes were prepared from castor oil and hexamethylene diisocyanatee (HMDI). Due to the long aliphatic chain of the castor oil component of polyurethane, thermal curing of castor oil based polyurethane (COPU) is limited by increasing polymer viscosity. To enhance further crosslinking, COPUs were subjected to a range of accumulated doses (0.0-3.0 MGy) produced by the mixed ionizing field of the SLOWPOKE-2 research reactor. The physico-mechanical properties of COPU, unirradiated and irradiated, were characterized by mechanical tests. Increased bond formation resulting from radiation-induced crosslinking was confirmed by favorable increases in mechanical properties and by solid-state 13 C -NMR and FTIR spectra

  10. The probabilistic model of the process mixing of animal feed ingredients into a continuous mixer-reactor

    Directory of Open Access Journals (Sweden)

    L. I. Lytkina

    2016-01-01

    Full Text Available A mathematical model of the polydisperse medium mixing process reflects its stochastic features in the form of uneven distribution of phase elements on the time of their presence in apparatus, particle size, ripple retention of the apparatus, random distribution of the material and thermal phase flows of the working volume, heterogeneity of the medium physical- and chemical properties, complicated by chemical reaction. For the mathematical description of the mixing process of animal feed ingredients in the presence of chemical reaction the system of differential equations of Academician V.V. Kafarov was used. Proposed by him hypothesis based on the theory of Markov’s processes stating that "any multicomponent mixture can be considered as the result of an iterative process of mixing the two components to achieve the desired uniformity of all the ingredients in the mixture" allows us to consider a process of mixing binary composition in a paddle mixer in the form of differential equations of two ingredients concentration numerous changes until it becomes a homogenous mixture. It was found out that the mixing process of the two-component mixture is determined in a paddle mixer with a constant mixing speed and a limit (equilibrium dispersion of the ingredients in the mixture i.e. with its uniformity. Adjustment of the model parameters was carried out according to the results of experimental studies on mixing the crushed wheat with metallomagnetic impurity, which was a key (indicator component. According to the best values of the constant of the continuous mixing speed and the equilibrium disperse values of the ingredients contents, the mathematical model parameters identification was carried out. The results obtained are used to develop a new generation mixer design.

  11. Ion-beam mixing and thermal annealing of Al--Nb and Al--Ta thin films

    International Nuclear Information System (INIS)

    Rai, A.K.; Bhattacharya, R.S.; Mendiratta, M.G.; Subramanian, P.R.; Dimiduk, D.M.

    1988-01-01

    Ion-beam mixing and thermal annealing of thin, alternating layers of Al and Nb, as well as Al and Ta, were investigated by selected area diffraction and Rutherford backscattering. The individual layer thicknesses were adjusted to obtain the overall compositions as Al 3 Nb and Al 3 Ta. The films were ion mixed with 1 MeV Au + ions at a dose of 1 x 10 16 ions cm/sup -2/ . Uniform mixing and amorphization were achieved for both Al--Nb and Al--Ta systems. Equilibrium crystalline Al 3 Nb and Al 3 Ta phases were formed after annealing of ion mixed amorphous films at 400 0 C for 6 h. Unmixed films, however, remained unreacted at 400 0 C for 1 h. Partial reaction was observed in the unmixed film of Al--Nb at 400 0 C for 6 h. After annealing at 500 0 C for 1 h, a complete reaction and formation of Al 3 Nb and Al 3 Ta phases in the respective films were observed. The influence of thermodynamics on the phase formation by ion mixing and thermal annealing is discussed

  12. Solid-state reaction in Fe/V multilayers by ion beam mixing with thermal annealing

    International Nuclear Information System (INIS)

    Borges, J.F.M.; Costa, M.I. da Jr.; Teixeira, S.R.; Cunha, J.B.M. da; Alves, M.C.M.

    2001-01-01

    We report a study on the structural and magnetic properties of iron-vanadium thin films, originally grown in multilayer form [Fe(20 A)/V(20 A)] 20 , and mixed by ion beam mixing (IBM) and a subsequent thermal treatment. The samples were structurally characterised by X-ray diffraction (XRD) in the θ-2θ geometry and X-ray absorption spectroscopy (XAS). The magnetic characterisation was made using conversion electron Moessbauer spectroscopy (CEMS). The XRD result for the as-deposited multilayer shows a high-degree crystallinity, while CEMS suggests abrupt interface, since no significant contribution from vanadium in iron is observed. After the IBM and thermal treatment, the results from XRD show an FeV solid solution indexed as a bcc-disordered structure (α phase). XAS structural results are consistent with the XRD observations. CEMS results show a magnetic moment reduction for mixed samples

  13. Stress assessment in piping under synthetic thermal loads emulating turbulent fluid mixing

    Energy Technology Data Exchange (ETDEWEB)

    Costa Garrido, Oriol, E-mail: oriol.costa@ijs.si; El Shawish, Samir, E-mail: samir.elshawish@ijs.si; Cizelj, Leon, E-mail: leon.cizelj@ijs.si

    2015-03-15

    Highlights: • Generation of complex space-continuous and time-dependent temperature fields. • 1D and 3D thermo-mechanical analyses of pipes under complex surface thermal loads. • Surface temperatures and stress fluctuations are highly linearly correlated. • 1D and 3D results agree for a wide range of Fourier and Biot numbers. • Global thermo-mechanical loading promotes non-equibiaxial stress state. - Abstract: Thermal fatigue assessment of pipes due to turbulent fluid mixing in T-junctions is a rather difficult task because of the existing uncertainties and variability of induced thermal stresses. In these cases, thermal stresses arise on three-dimensional pipe structures due to complex thermal loads, known as thermal striping, acting at the fluid-wall interface. A recently developed approach for the generation of space-continuous and time-dependent temperature fields has been employed in this paper to reproduce fluid temperature fields of a case study from the literature. The paper aims to deliver a detailed study of the three-dimensional structural response of piping under the complex thermal loads arising in fluid mixing in T-junctions. Results of three-dimensional thermo-mechanical analyses show that fluctuations of surface temperatures and stresses are highly linearly correlated. Also, surface stress fluctuations, in axial and hoop directions, are almost equi-biaxial. These findings, representative on cross sections away from system boundaries, are moreover supported by the sensitivity analysis of Fourier and Biot numbers and by the comparison with standard one-dimensional analyses. Agreement between one- and three-dimensional results is found for a wide range of studied parameters. The study also comprises the effects of global thermo-mechanical loading on the surface stress state. Implemented mechanical boundary conditions develop more realistic overall system deformation and promote non-equibiaxial stresses.

  14. Thermal radiation impact in mixed convective peristaltic flow of third grade nanofluid

    Directory of Open Access Journals (Sweden)

    Sadia Ayub

    Full Text Available This paper models the peristaltic transport of magnetohydrodynamic (MHD third grade nanofluid in a curved channel with wall properties. Combined effects of heat and mass transfer are retained via mixed convection. The present analysis is made in the presence of thermal radiation and chemical reaction. No-slip effect is maintained at the boundary for the velocity, temperature and nanoparticle volume fraction. Resulting formulation is simplified by employing the assumptions of long wavelength and low Reynolds number approximations. Results of axial velocity, temperature, nanoparticle mass transfer and heat transfer are studied graphically. Results reveal increment in fluid velocity for larger values of heat transfer Grashof number. There is reduction in nanoparticle mass transfer with the increase in thermophoresis parameter. Keywords: Peristalsis, Third grade nanofluid, Curved channel, Mixed convection, Thermal radiation, Chemical reaction, Flexible walls, Numerical solutions

  15. Energy and costs scoping study for plasma pyrolysis thermal processing system

    International Nuclear Information System (INIS)

    Sherick, K.E.; Findley, J.E.

    1992-01-01

    The purpose of this study was to provide information in support of an investigation of thermal technologies as possible treatment process for buried wastes at the INEL. Material and energy balances and a cost estimate were generated for a representative plasma torch-based thermal waste treatment system operating in a pyrolysis mode. Two waste streams were selected which are representative of INEL buried wastes, large in volume, and difficult to treat by other technologies. These streams were a solidified nitrate sludge waste stream and a waste/soil mix of other buried waste components. The treatment scheme selected includes a main plasma chamber operating under pyrolyzing conditions; a plasma afterburner to provide additional residence time at high temperature to ensure complete destruction of hazardous organics; an off-gas treatment system; and a incinerator and stack to oxidize carbon monoxide to carbon dioxide and vent the clean, oxidized gases to atmosphere. The material balances generated provide materials flow and equipment duty information of sufficient accuracy to generate initial rough-order-of-magnitude (ROM) system capital and operating cost estimates for a representative plasma thermal processing system

  16. Model and measurements of linear mixing in thermal IR ground leaving radiance spectra

    Science.gov (United States)

    Balick, Lee; Clodius, William; Jeffery, Christopher; Theiler, James; McCabe, Matthew; Gillespie, Alan; Mushkin, Amit; Danilina, Iryna

    2007-10-01

    Hyperspectral thermal IR remote sensing is an effective tool for the detection and identification of gas plumes and solid materials. Virtually all remotely sensed thermal IR pixels are mixtures of different materials and temperatures. As sensors improve and hyperspectral thermal IR remote sensing becomes more quantitative, the concept of homogeneous pixels becomes inadequate. The contributions of the constituents to the pixel spectral ground leaving radiance are weighted by their spectral emissivities and their temperature, or more correctly, temperature distributions, because real pixels are rarely thermally homogeneous. Planck's Law defines a relationship between temperature and radiance that is strongly wavelength dependent, even for blackbodies. Spectral ground leaving radiance (GLR) from mixed pixels is temperature and wavelength dependent and the relationship between observed radiance spectra from mixed pixels and library emissivity spectra of mixtures of 'pure' materials is indirect. A simple model of linear mixing of subpixel radiance as a function of material type, the temperature distribution of each material and the abundance of the material within a pixel is presented. The model indicates that, qualitatively and given normal environmental temperature variability, spectral features remain observable in mixtures as long as the material occupies more than roughly 10% of the pixel. Field measurements of known targets made on the ground and by an airborne sensor are presented here and serve as a reality check on the model. Target spectral GLR from mixtures as a function of temperature distribution and abundance within the pixel at day and night are presented and compare well qualitatively with model output.

  17. Reproducibility of TL measurements in a mixed field of thermal neutrons and photons

    International Nuclear Information System (INIS)

    Fernandes, A.C.; Goncalves, I.C.; Ferro Carvalho, A.; Santos, J.; Cardoso, J.; Santos, L.; Osvay, M.

    2002-01-01

    The reproducibility of measurements performed with GR-100 (LiF:Mg,Ti) from the Solid Dosimetric Detector and Method Laboratory (DML) China, GR-107 ( 7 LiF:Mg,Ti, DML), TLD-700H ( 7 LiF:Mg,Cu,P, Harshaw) and Al 2 O 3 :Mg,Y (Hungary) in photon and mixed photon-neutron fields was investigated. Mixed-field irradiations were performed in a thermal neutron field generated at a nuclear reactor. GR-100 sensitivity decreased after mixed-field irradiations, while no significant change was found for the other materials. Using GR-100 for the dosimetry of mixed and high-intensity fields requires careful procedures. (author)

  18. Mixed Convection in Technological Reservoir of Thermal Power Station

    Directory of Open Access Journals (Sweden)

    Kuznetsov Geniy V.

    2014-01-01

    Full Text Available The problem of mixed convection of a viscous incompressible fluid in an open rectangular reservoir with inlet and outlet of mass with considering nonuniform heat sink at the external borders of the solution domain is solved. The region of the solution was limited by two vertical and by one horizontal walls of finite thickness and one free surface. The flat nonstationary mixed convection within the framework of Navier-Stokes model is examined for liquid and thermal conductivity for solid walls. Distributions of hydrodynamic parameters and temperatures with different intensity of heat sink on the outer contour of the cavity show a change in the intensity of heat sink on the region boundaries of the solution leads to scale changes in the structure of flow and temperature fields of the liquids.

  19. Contribution to the study of thermal mixing between nuclear spin systems; Contribution a l'etude du melange thermique entre systemes de spins nucleaires

    Energy Technology Data Exchange (ETDEWEB)

    Goldmann, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1967-02-15

    This work describes methods of dynamic nuclear polarization in solids based on the thermal mixing between nuclear spin systems. The description of the thermal mixing processes involves most of the fundamental aspects of the spin temperature theory. The experiments, conducted with paradichlorobenzene and para-dibromobenzene, yield a detailed confirmation of the theoretical predictions. (author) [French] Ce travail decrit des methodes de polarisation dynamique nucleaire dans les solides basees sur le melange thermique entre systemes de spins nucleaires. La description des processus de melange thermique met en jeu la plupart des aspects fondamentaux de la theorie de la temperature de spin. Les experiences, realisees avec du paradichlorobenzene et du paradibromobenzene, apportent une confirmation detaillee des previsions theoriques. (auteur)

  20. Design and implementation of mixing chambers to improve thermal decomposition of urea for NOX abatement

    KAUST Repository

    Lee, Junggil; Kim, Youngdeuk; Kim, Wooseung

    2012-01-01

    to improve urea thermal decomposition, and experiments with and without a mixing chamber were carried out to analyze thermal-decomposition characteristics of urea in the exhaust pipe with respect to inlet velocity (4-12μm/s) and temperature (350°C-500°C

  1. Characterization and recognition of mixed emotional expressions in thermal face image

    Science.gov (United States)

    Saha, Priya; Bhattacharjee, Debotosh; De, Barin K.; Nasipuri, Mita

    2016-05-01

    Facial expressions in infrared imaging have been introduced to solve the problem of illumination, which is an integral constituent of visual imagery. The paper investigates facial skin temperature distribution on mixed thermal facial expressions of our created face database where six are basic expressions and rest 12 are a mixture of those basic expressions. Temperature analysis has been performed on three facial regions of interest (ROIs); periorbital, supraorbital and mouth. Temperature variability of the ROIs in different expressions has been measured using statistical parameters. The temperature variation measurement in ROIs of a particular expression corresponds to a vector, which is later used in recognition of mixed facial expressions. Investigations show that facial features in mixed facial expressions can be characterized by positive emotion induced facial features and negative emotion induced facial features. Supraorbital is a useful facial region that can differentiate basic expressions from mixed expressions. Analysis and interpretation of mixed expressions have been conducted with the help of box and whisker plot. Facial region containing mixture of two expressions is generally less temperature inducing than corresponding facial region containing basic expressions.

  2. A Martingale Characterization of Mixed Poisson Processes.

    Science.gov (United States)

    1985-10-01

    03LA A 11. TITLE (Inciuae Security Clanafication, ",A martingale characterization of mixed Poisson processes " ________________ 12. PERSONAL AUTHOR... POISSON PROCESSES Jostification .......... . ... . . Di.;t ib,,jtion by Availability Codes Dietmar Pfeifer* Technical University Aachen Dist Special and...Mixed Poisson processes play an important role in many branches of applied probability, for instance in insurance mathematics and physics (see Albrecht

  3. Mixed thermal convection: fundamental issues and analysis of the planar case

    Directory of Open Access Journals (Sweden)

    JACQUES PADET

    2015-09-01

    Full Text Available This paper aims to renew interest on mixed thermal convection research and to emphasize three issues that arise from the present analysis: (i a clear definition of the reference temperature in the Boussinesq approximation; (ii a practical delimitation of the three convective modes, which are the forced convection (FC, mixed convection (MC and natural (or free convection (NC; (iii and, finally, a uniform description of the set FC/MC/NC in the similarity framework. The planar case, for which analytical solutions are available, allows a detailed illustration of the answers here advanced to the above issues.

  4. Temperature-dependent ion beam mixing

    International Nuclear Information System (INIS)

    Rehn, L.E.; Alexander, D.E.

    1993-08-01

    Recent work on enhanced interdiffusion rates during ion-beam mixing at elevated temperatures is reviewed. As discussed previously, expected increase in ion-beam mixing rates due to 'radiation-enhanced diffusion' (RED), i.e. the free migration of isolated vacancy and interstitial defects, is well documented in single-crystal specimens in the range of 0.4 to 0.6 of absolute melting temperature. In contrast, the increase often observed at somewhat lower temperatures during ion-beam mixing of polycrystalline specimens is not well understood. However, sufficient evidence is available to show that this increase reflects intracascade enhancement of a thermally-activated process that also occurs without irradiation. Recent evidence is presented which suggests that this process is Diffusion-induced Grain-Boundary Migration (DIGM). An important complementary conclusion is that because ion-beam mixing in single-crystal specimens exhibits no significant temperature dependence below that of RED, models that invoke only irradiation-specific phenomena, e.g., cascade-overlap, thermal-spikes, or liquid-diffusion, and hence which predict no difference in mixing behavior between single- or poly-crystalline specimens, cannot account for the existing results

  5. Proceedings of the specialists meeting on experience with thermal fatigue in LWR piping caused by mixing and stratification

    International Nuclear Information System (INIS)

    1998-01-01

    This specialists meeting on experience with thermal fatigue in LWR piping caused by mixing and stratification, was held in June 1998 in Paris. It included five sessions. Session 1: operating experience (7 papers): Historical perspective; EDF experience with local thermohydraulic phenomena in PWRs: impacts and strategies; Thermal fatigue in safety injection lines of French PWRs: technical problems, regulatory requirements, concerns about other areas; US NRC Regulatory perspective on unanticipated thermal fatigue in LWR piping; Failure to the Residual Heat Removal system suction line pipe in Genkai unit 1 caused by thermal stratification cycling; Emergency Core Cooling System pipe crack incident at Tihange unit 1; Two leakages induced by thermal stratification at the Loviisa power plant). Session 2: thermal hydraulic phenomena (5 papers): Thermal stratification in small pipes with respect to fatigue effects and so called 'Banana effect'; Thermal stratification in the surge line of the Korean next generation reactor; Thermal stratification in horizontal pipes investigated in UPTF-TRAM and HDR facilities; Research on thermal stratification in un-isolable piping of reactor pressure boundary; Thermal mixing phenomena in piping systems: 3D numerical simulation and design considerations. Session 3: response of material and structure (5 papers): Fatigue induced by thermal stratification, Results of tests and calculations of the COUFAST model; Laboratory simulation of thermal fatigue cracking as a basis for verifying life models; Thermo-mechanical analysis methods for the conception and the follow up of components submitted to thermal stratification transients; Piping analysis methods of a PWR surge line for stratified flow; The thermal stratification effect on surge lines, The VVER estimation. Session 4: monitoring aspects (4 papers): Determination of the thermal loadings affecting the auxiliary lines of the reactor coolant system in French PWR plants; Expected and

  6. Thermal physics of gas-thermal coatings formation processes. State of investigations

    International Nuclear Information System (INIS)

    Fialko, N.M.; Prokopov, V.G.; Meranova, N.O.; Borisov, Yu.S.; Korzhik, V.N.; Sherenkovskaya, G.P.; AN Ukrainskoj SSR, Kiev

    1993-01-01

    The analysis of state of investigations of gas-thermal coatings formation processes in presented. Classification of approaches to mathematical simulation of thermal phenomena studies is offered. The general characteristics of three main approaches to the analysis of heat transport processes is given. Some problems of mathematical simulation of single particle thermal interaction with solid surface are considered in details. The main physical assumptions are analysed

  7. Mixing process influence on thermal and rheological properties of NBR/SiO2 from rice husk ash

    Directory of Open Access Journals (Sweden)

    Ana Maria Furtado de Sousa

    Full Text Available Abstract Silica was extracted from rice husk ash (RHA by a sequence of reactions to produce nanosilica. Two laboratory routes, co-coagulation and spray drying, were used to incorporate the nanosilica into the rubber matrix. Samples were characterized regarding filler incorporation efficiency, thermal stability, rheological behavior and morphology. Thermogravimetric analysis showed that spray-drying was the most efficient filler incorporation process and also the presence of silica increased the thermal resistance of the rubber compound when compared to the unfilled rubber. The rheological behavior showed that NBR filled with silica presented higher elastic torque (S’, storage modulus (G’ and complex viscosity (η* than unfilled rubber. The Payne effect was also observed for the composites produced by spray-drying. In addition, the thermal behavior and Payne effect results were supported by the comparison of morphology observed by FEG-SEM analysis.

  8. Thermal destratification in small standard solar tanks due to mixing during tapping

    DEFF Research Database (Denmark)

    Andersen, Elsa; Furbo, Simon

    1999-01-01

    The aim of the project is to investigate the thermal destratification in small standard solar tanks due to mixing during tapping. Three different cold water inlet designs are tested. A model of the tested solar tank is verified. Based on the measurements and the calculations it is elucidated how...

  9. Treatment of mixed wastes by thermal plasma discharges

    International Nuclear Information System (INIS)

    Diaz A, L.V.

    2007-01-01

    The present study has as purpose to apply the technology of thermal plasma in the destruction of certain type of waste generated in the ININ. As first instance, origin, classification and disposition of the radioactive waste generated in the ININ is identified. Once identified the waste, the waste to treat is determined based on: the easiness of treating him with plasma, classification and importance. Later on, a substance or compound settles down (sample model) that serves as indicative of the waste for its physical-chemical characteristics, this is made because in the Thermal Plasma Applications Laboratory is not had the license to work with radioactive material. The sample model and the material to form the vitreous matrix are characterized before and after the treatment in order to evaluating their degradation and vitrification. During the treatment by means of the thermal plasma, the appropriate conditions are determined for the degradation and vitrification of the waste. Also, it is carried out an energy balance in the system to know the capacity to fuse the material depending the transfer of existent heat between the plasma and the material to treat. Obtaining favorable results, it thought about to climb in the project and by this way to help to solve one of the environmental problems in Mexico, as they are it the mixed wastes. (Author)

  10. Hydration of Magnesium Carbonate in a Thermal Energy Storage Process and Its Heating Application Design

    Directory of Open Access Journals (Sweden)

    Rickard Erlund

    2018-01-01

    Full Text Available First ideas of applications design using magnesium (hydro carbonates mixed with silica gel for day/night and seasonal thermal energy storage are presented. The application implies using solar (or another heat source for heating up the thermal energy storage (dehydration unit during daytime or summertime, of which energy can be discharged (hydration during night-time or winter. The applications can be used in small houses or bigger buildings. Experimental data are presented, determining and analysing kinetics and operating temperatures for the applications. In this paper the focus is on the hydration part of the process, which is the more challenging part, considering conversion and kinetics. Various operating temperatures for both the reactor and the water (storage tank are tested and the favourable temperatures are presented and discussed. Applications both using ground heat for water vapour generation and using water vapour from indoor air are presented. The thermal energy storage system with mixed nesquehonite (NQ and silica gel (SG can use both low (25–50% and high (75% relative humidity (RH air for hydration. The hydration at 40% RH gives a thermal storage capacity of 0.32 MJ/kg while 75% RH gives a capacity of 0.68 MJ/kg.

  11. Large Eddy Simulation of a thermal mixing tee in order to assess the thermal fatigue

    International Nuclear Information System (INIS)

    Galpin, J.; Simoneau, J.P.

    2011-01-01

    Highlights: → In this study, we perform a Large Eddy Simulation of a mixing tee, for which experimental thermal statistics are available. → A special methodology has been set up for comparing properly the fluctuations with the experiment. → A comparison between the Smagorinsky and the structure-function sub-grid scale model is achieved out. → Slight better predictions are obtained with the structure-function model. → The possibility to reduce the computational domain by prescribing synthetic turbulence at the inlet is tested. First results are encouraging and underline the advantage of considering this technique instead of a standard noise at the entrance of the domain. - Abstract: The present paper deals with thermal fatigue phenomenon, and more particularly with the numerical simulation using Large Eddy Simulation technique of a mixing tee, for which experimental thermal statistics are available. The sensitivity to the sub-grid scale closure is first evaluated by comparing the experimental statistics with the numerical results obtained via both the Smagorinsky and the structure-function models. Because of a difference of temporal resolution between the experiment and the simulation, the direct comparison of the fluctuations is not possible. Therefore, a methodology based on filtering the numerical results is proposed in order to achieve a proper comparison. The comparison of the numerical results with the experiment suggests that slight better predictions are obtained with the structure-function model even if the dependency of the results to the sub-grid scale model is low. Then, the possibility to reduce the fluid computational domain by prescribing synthetic turbulence at the inlet is tested. First results are encouraging and underline the advantage of considering this technique instead of a standard noise at the entrance of the domain. All the simulations are conducted with the commercial CFD code STAR-CD.

  12. Simplified methods to assess thermal fatigue due to turbulent mixing

    International Nuclear Information System (INIS)

    Hannink, M.H.C.; Timperi, A.

    2011-01-01

    Thermal fatigue is a safety relevant damage mechanism in pipework of nuclear power plants. A well-known simplified method for the assessment of thermal fatigue due to turbulent mixing is the so-called sinusoidal method. Temperature fluctuations in the fluid are described by a sinusoidally varying signal at the inner wall of the pipe. Because of limited information on the thermal loading conditions, this approach generally leads to overconservative results. In this paper, a new assessment method is presented, which has the potential of reducing the overconservatism of existing procedures. Artificial fluid temperature signals are generated by superposition of harmonic components with different amplitudes and frequencies. The amplitude-frequency spectrum of the components is modelled by a formula obtained from turbulence theory, whereas the phase differences are assumed to be randomly distributed. Lifetime predictions generated with the new simplified method are compared with lifetime predictions based on real fluid temperature signals, measured in an experimental setup of a mixing tee. Also, preliminary steady-state Computational Fluid Dynamics (CFD) calculations of the total power of the fluctuations are presented. The total power is needed as an input parameter for the spectrum formula in a real-life application. Solution of the transport equation for the total power was included in a CFD code and comparisons with experiments were made. The newly developed simplified method for generating the temperature signal is shown to be adequate for the investigated geometry and flow conditions, and demonstrates possibilities of reducing the conservatism of the sinusoidal method. CFD calculations of the total power show promising results, but further work is needed to develop the approach. (author)

  13. Thermally driven interaction of the littoral and limnetic zones by autumnal cooling processes

    Directory of Open Access Journals (Sweden)

    Kolumban HUTTER

    2005-02-01

    Full Text Available In autumn, during the transition period, shores influence the interior dynamics of large temperate lakes by the formation of horizontal water-temperature gradients between the shallow and deep areas, whilst vertical temperature gradients are smoothed by convection due to surface cooling. A simple heat budget model, based on the heat balance of the water column without horizontal advection and turbulent mixing, allows deduction of the time-dependent difference between the mean temperature within the littoral area and the temperature in the upper mixed layer. The model corroborates that littoral areas cool faster than regions distant from shores, and provides a basis for an estimation of structure of flows from the beginning of cooling process till the formation of the thermal bar. It predicts the moment in the cooling process, when the corresponding density difference between the littoral and limnetic parts reaches a maximum. For a linear initial vertical temperature profile, the time-dependent "target depth" is explicitly calculated; this is the depth in the pelagic area with a temperature, characteristic of the littoral zone. This depth is estimated as 4/3 of the (concurrent thickness of the upper mixed layer. It is shown that, for a linear initial vertical temperature profile, the horizontal temperature profile between the shore and the lake has a self-similar behavior, and the temperature difference between the littoral waters and the upper mixed off-shore layer, divided by the depth of the upper mixed layer, is an invariant of the studied process. The results are in conformity with field data.

  14. Ion-beam mixed ultra-thin cobalt suicide (CoSi2) films by cobalt sputtering and rapid thermal annealing

    Science.gov (United States)

    Kal, S.; Kasko, I.; Ryssel, H.

    1995-10-01

    The influence of ion-beam mixing on ultra-thin cobalt silicide (CoSi2) formation was investigated by characterizing the ion-beam mixed and unmixed CoSi2 films. A Ge+ ion-implantation through the Co film prior to silicidation causes an interface mixing of the cobalt film with the silicon substrate and results in improved silicide-to-silicon interface roughness. Rapid thermal annealing was used to form Ge+ ion mixed and unmixed thin CoSi2 layer from 10 nm sputter deposited Co film. The silicide films were characterized by secondary neutral mass spectroscopy, x-ray diffraction, tunneling electron microscopy (TEM), Rutherford backscattering, and sheet resistance measurements. The experi-mental results indicate that the final rapid thermal annealing temperature should not exceed 800°C for thin (micrographs of the ion-beam mixed and unmixed CoSi2 films reveals that Ge+ ion mixing (45 keV, 1 × 1015 cm-2) produces homogeneous silicide with smooth silicide-to-silicon interface.

  15. Molten salt destruction process for mixed wastes

    International Nuclear Information System (INIS)

    Upadhye, R.S.; Wilder, J.G.; Karlsen, C.E.

    1993-04-01

    We are developing an advanced two-stage process for the treatment of mixed wastes, which contain both hazardous and radioactive components. The wastes, together with an oxidant gas, such as air, are injected into a bed of molten salt comprising a mixture of sodium-, potassium-, and lithium-carbonates, with a melting point of about 580 degree C. The organic constituents of the mixed waste are destroyed through the combined effect of pyrolysis and oxidation. Heteroatoms. such as chlorine, in the mixed waste form stable salts, such as sodium chloride, and are retained in the melt. The radioactive actinides in the mixed waste are also retained in the melt because of the combined action of wetting and partial dissolution. The original process, consists of a one-stage unit, operated at 900--1000 degree C. The advanced two-stage process has two stages, one for pyrolysis and one for oxidation. The pyrolysis stage is designed to operate at 700 degree C. The oxidation stage can be operated at a higher temperature, if necessary

  16. Thermal entanglement and teleportation of a thermally mixed entangled state of a Heisenberg chain through a Werner state

    Institute of Scientific and Technical Information of China (English)

    Huang Li-Yuan; Fang Mao-Fa

    2008-01-01

    The thermal entanglement and teleportation of a thermally mixed entangled state of a two-qubit Heisenberg XXX chain under the Dzyaloshinski-Moriya (DM) anisotropic antisymmetric interaction through a noisy quantum channel given by a Werner state is investigated. The dependences of the thermal entanglement of the teleported state on the DM coupling constant, the temperature and the entanglement of the noisy quantum channel are studied in detail for both the ferromagnetic and the antiferromagnetic cases. The result shows that a minimum entanglement of the noisy quantum channel must be provided in order to realize the entanglement teleportation. The values of fidelity of the teleported state are also studied for these two cases. It is found that under certain conditions, we can transfer an initial state with a better fidelity than that for any classical communication protocol.

  17. Synthesis, characterization and thermal expansion studies on thorium-praseodymium mixed oxide solid solutions

    International Nuclear Information System (INIS)

    Panneerselvam, G.; Antony, M.P.; Srinivasan, T.G.; Vasudeva Rao, P.R.

    2010-01-01

    Full text: Thorium-praseodymium mixed oxide solid solutions containing 15, 25, 40 and 55 mole percent of praseodymia were synthesized by mixing the solutions of thorium nitrate in water and praseodymium oxide (Pr 6 O 11 ) in conc. HNO 3 . Subsequently, their hydroxides were co-precipitated by the addition of aqueous ammonia. Further the precipitate was dried at 50 deg C, calcined at 600 deg C for 4 hours and sintered at 1200 deg C for 6 h in air. X-ray diffraction measurements were performed for phase identification and lattice parameter derivation. Single-phase fluorite structure was observed for all the compositions. Bulk and theoretical densities of solid solutions were also determined by immersion and X-ray techniques. Thermal expansion coefficients and percentage linear thermal expansion of the solid solutions were determined using high temperature X-ray diffraction technique in the temperature range 300 to 1700 K for the first time. The room temperature lattice constants estimated for above compositions are 0.5578, 0.5565, 0.5545 and 0.5526 nm, respectively. The mean linear thermal expansion coefficients for the solid solutions are 15.48 x 10 -6 K -1 , 18.35 x 10 -6 K -1 , 22.65 x 10 -6 K -1 and 26.95 x 10 -6 K -1 , respectively. The percentage linear thermal expansions in this temperature range are 1.68, 1.89, 2.21 and 2.51 respectively. It is seen that the solid solutions are stable up to 1700 K. It is also seen that the effect and nature of the dopant are the important parameters influencing the thermal expansion of the ThO 2 . The lattice parameter of the solid solutions exhibited a decreasing trend with respect to praseodymia addition. The percentage linear thermal expansion of the solid solutions increases steadily with increasing temperature

  18. Quantum-CEP trademark for mixed waste processing

    International Nuclear Information System (INIS)

    Nahass, P.; Sekula-Moise, P.A.; Chanenchuk, C.A.

    1994-01-01

    No commercially available technology exists to effectively treat the hundreds of thousands of tons of mixed waste stored and generated in the United States and worldwide. Catalytic Extraction Processing (CEP) is an innovative flexible recycling technology which has inherent advantages for processing mixed wastes in a wide variety of chemical and physical forms. CEP uses a molten metal bath to completely dissociate feeds and recombine them with selected reactants to form useful products. Dissolved carbon in the metal bath creates a reducing atmosphere, readily converting hydrocarbons to synthesis gas, metals to alloys in their reduced state, and inorganics to an engineered ceramic phase. Process conditions can be manipulated to strongly favor partitioning of select radionuclides to a nonleachable vitreous phase, ready for final form disposal. Molten Metal Technology has adapted its CEP technology for radioactive processing and has delivered Quantum-CEP trademark units to customers for demonstration of mixed waste processing leading to commercial scale installations for reducing both private and government inventories. Agreements have also been reached to build commercial CEP facilities to recycle hazardous and industrial wastes

  19. Mechanical, thermal and morphological characterization of polycarbonate/oxidized carbon nanofiber composites produced with a lean 2-step manufacturing process.

    Science.gov (United States)

    Lively, Brooks; Kumar, Sandeep; Tian, Liu; Li, Bin; Zhong, Wei-Hong

    2011-05-01

    In this study we report the advantages of a 2-step method that incorporates an additional process pre-conditioning step for rapid and precise blending of the constituents prior to the commonly used melt compounding method for preparing polycarbonate/oxidized carbon nanofiber composites. This additional step (equivalent to a manufacturing cell) involves the formation of a highly concentrated solid nano-nectar of polycarbonate/carbon nanofiber composite using a solution mixing process followed by melt mixing with pure polycarbonate. This combined method yields excellent dispersion and improved mechanical and thermal properties as compared to the 1-step melt mixing method. The test results indicated that inclusion of carbon nanofibers into composites via the 2-step method resulted in dramatically reduced ( 48% lower) coefficient of thermal expansion compared to that of pure polycarbonate and 30% lower than that from the 1-step processing, at the same loading of 1.0 wt%. Improvements were also found in dynamic mechanical analysis and flexural mechanical properties. The 2-step approach is more precise and leads to better dispersion, higher quality, consistency, and improved performance in critical application areas. It is also consistent with Lean Manufacturing principles in which manufacturing cells are linked together using less of the key resources and creates a smoother production flow. Therefore, this 2-step process can be more attractive for industry.

  20. An experimental investigation of the thermal mixing in a water pool using a simplified I-sparger

    International Nuclear Information System (INIS)

    Kim, Y. S.; Jun, H. G.; Youn, Y. J.; Park, C. K.; Song, C. H.

    2004-01-01

    The SDVS (Safety Depressurization and Vent System) in the APR1400 is designed to cope with some DBEs (Design Bases Events) and beyond-DBEs related to overpressurization of the RCS (Reactor Coolant System). When the POSRV (Power Operated Safety Relief Valve) is actuated, steam from the pressurizer is discharged to the IRWST(In-containment Refueling Water Storage Tank) through I-spargers. When injected steam is condensed in the pool, it induces water motions and temperature variations in the pool, which effects on the steam jet condensation, vice versa. The B and C(Blowdown and Condensation) loop is a test facility for the thermal mixing through a steam sparger in a water pool. Thermal mixing tests provide basic understanding of the physics and some insights related to efficient pool mixing, dynamic load, and the IRWST design improvement etc

  1. Multiple-jet thermal mixing in a piping tee

    International Nuclear Information System (INIS)

    Lykoudis, P.S.; Hagar, R.C.

    1979-01-01

    Piping tees that are used to mix fluid streams at different temperatures are subjected to possibly severe thermal and mechanical stresses. There is reason to suspect that mixing in a piping tee could be improved by injecting the fluid streams into the tee through multiple jets. This paper reports the results of an experimental investigation of the effects of multiple-jet injection on mixing in a piping tee. The experimental work involves the measurement of the temperature fluctuation intensity with a hot-film sensor downstream of a simple 22.22-mm(7/8-in.)-diam tee with mixed multiple-jet injected hot and cold streams of water. The jets were provided by holes drilled in plates that partially blocked the inlet streams; 26 pairs of plates were investigated. The number of holes per plate varied from 1 to 51; the jet diameters ranged from 5 to 68% of the tee diameter. The inlet stream Reynolds number upstream of the jet plates was roughly 15 500 for each stream. The data indicated that the root mean square (rms) temperature fluctuation intensity measured at the tee outlet decreased dramatically as the jet plate cross-sectional area void fraction was decreased. When the jets emanating from the tee plates were misaligned, the reduction of the rms temperature fluctuation was not as high as when the jets were aligned. The rate of decay of the intensity downstream of the tee for most ofthe plates investigated was found to agree well with the -3/4 power decay law predicted by Corrsin's theory of scalar decay. However, unusual features in the intensity decay data were also observed, such as an increase of the intensity several diameters downstream before continuing to decay

  2. One-dimensional thermal evolution calculation based on a mixing length theory: Application to Saturnian icy satellites

    Science.gov (United States)

    Kamata, S.

    2017-12-01

    Solid-state thermal convection plays a major role in the thermal evolution of solid planetary bodies. Solving the equation system for thermal evolution considering convection requires 2-D or 3-D modeling, resulting in large calculation costs. A 1-D calculation scheme based on mixing length theory (MLT) requires a much lower calculation cost and is suitable for parameter studies. A major concern for the MLT scheme is its accuracy due to a lack of detailed comparisons with higher dimensional schemes. In this study, I quantify its accuracy via comparisons of thermal profiles obtained by 1-D MLT and 3-D numerical schemes. To improve the accuracy, I propose a new definition of the mixing length (l), which is a parameter controlling the efficiency of heat transportation due to convection. Adopting this new definition of l, I investigate the thermal evolution of Dione and Enceladus under a wide variety of parameter conditions. Calculation results indicate that each satellite requires several tens of GW of heat to possess a 30-km-thick global subsurface ocean. Dynamical tides may be able to account for such an amount of heat, though their ices need to be highly viscous.

  3. Comparison between thermal annealing and ion mixing of multilayered Ni-W films on Si. II

    International Nuclear Information System (INIS)

    Pai, C.S.; Lau, S.S.; Poker, D.B.; Hung, L.S.

    1985-01-01

    The reactions between bilayered Ni/W films and Si substrates induced by thermal annealing and ion mixing were investigated and compared. Samples were prepared by electron-beam sequential deposition of Ni and W onto the Si substrates and following by either furnace annealing (approx. 200--900 0 C) or ion mixing (approx. 2 x 10 15 -- 4 x 10 16 86 Kr + ions/cm 2 ). The reactions were analyzed by Rutherford backscattering and x-ray diffraction (Read camera). Thermal annealing of both W/Ni/Si and Ni/W/Si samples led to the formation of Ni silicide next to the Si substrate and W silicide on the sample surface (layer reversal between Ni and W in the Ni/W/Si case). Ion mixing of W/Ni/Si samples led to the formation of Ni silicide with a thin layer of Ni-W-Si mixture located at the sample surface. For Ni/W/Si samples a ternary amorphous mixture of Ni-W-Si was obtained with ion mixing. These reactions were rationalized in terms of the mobilities of various atoms and the intermixings between layers

  4. Gas flow and thermal mixing in a helically wound tube bundle

    International Nuclear Information System (INIS)

    Chiger, H.D.

    1980-07-01

    The thermal dissipation of a hot gas streak flowing across a segment of a helically wound tube bundle and the bypass flow streaming between the tubes and the bundle wall were investigated experimentally in the range of 8000 < Re < 50,000. Two different modes of creating a hot streak were employed. A planar hot streak was (1) injected at the entrance to the tube bundle and (2) generated by electrically heating several tubes past the bundle inlet. In the first case the mixing occurs in a region of lower turbulence since it occurs near the bundle inlet. In the second case the mixing occurs in a region of higher turbulence since the flow has already passed over several tube rows before the hot streak is generated

  5. A thermal mixing model of crossflow in tube bundles for use with the porous body approximation

    International Nuclear Information System (INIS)

    Ashcroft, J.; Kaminski, D.A.

    1996-06-01

    Diffusive thermal mixing in a heated tube bundle with a cooling fluid in crossflow was analyzed numerically. From the results of detailed two-dimensional models, which calculated the diffusion of heat downstream of one heated tube in an otherwise adiabatic flow field, a diffusion model appropriate for use with the porous body method was developed. The model accounts for both molecular and turbulent diffusion of heat by determining the effective thermal conductivity in the porous region. The model was developed for triangular shaped staggered tube bundles with pitch to diameter ratios between 1.10 and 2.00 and for Reynolds numbers between 1,000 and 20,000. The tubes are treated as nonconducting. Air and water were considered as working fluids. The effective thermal conductivity was found to be linearly dependent on the tube Reynolds number and fluid Prandtl number, and dependent on the bundle geometry. The porous body thermal mixing model was then compared against numerical models for flows with multiple heated tubes with very good agreement

  6. Effect of 17 x 17 fuel assembly geometry on interchannel thermal mixing

    International Nuclear Information System (INIS)

    Motley, F.E.; Wenzell, A.H.; Cadek, F.F.

    1975-01-01

    A test to determine the value of the thermal diffusion coefficient (TDC) in the 17 x 17 fuel assembly geometry was conducted. The test section was a 5 x 5 rod bundle with a radial power difference of 4.5 to 1. The rod OD and pitch are identical to the 17 x 17 fuel assembly, as is the mixing vane grid design. The value of thermal diffusion coefficient (TDC) was determined by matching the experimental exit enthalpy distribution to that predicted by the THINC computer code. The mean value of TDC for the 17 x 17 fuel assembly geometry is TDC = .059. 6 references

  7. Chemical Changes in Proteins Produced by Thermal Processing.

    Science.gov (United States)

    Dutson, T. R.; Orcutt, M. W.

    1984-01-01

    Discusses effects of thermal processing on proteins, focusing on (1) the Maillard reaction; (2) heat denaturation of proteins; (3) aggregation, precipitation, gelation, and degradation; and (4) other thermally induced protein reactions. Also discusses effects of thermal processing on muscle foods, egg proteins, fruits and vegetables, and cereal…

  8. Hydrological response and thermal effect of karst springs linked to aquifer geometry and recharge processes

    Science.gov (United States)

    Luo, Mingming; Chen, Zhihua; Zhou, Hong; Zhang, Liang; Han, Zhaofeng

    2018-03-01

    To be better understand the hydrological and thermal behavior of karst systems in South China, seasonal variations in flow, hydrochemistry and stable isotope ratios of five karst springs were used to delineate flow paths and recharge processes, and to interpret their thermal response. Isotopic data suggest that mean recharge elevations are 200-820 m above spring outlets. Springs that originate from high elevations have lower NO3 - concentrations than those originating from lower areas that have more agricultural activity. Measured Sr2+ concentrations reflect the strontium contents of the host carbonate aquifer and help delineate the spring catchment's saturated zone. Seasonal variations of NO3 - and Sr2+ concentrations are inversely correlated, because the former correlates with event water and the latter with baseflow. The mean annual water temperatures of springs were only slightly lower than the local mean annual surface temperature at the outlet elevations. These mean spring temperatures suggest a vertical gradient of 6 °C/vertical km, which resembles the adiabatic lapse rate of the Earth's stable atmosphere. Seasonal temperature variations in the springs are in phase with surface air temperatures, except for Heilongquan (HLQ) spring. Event-scale variations of thermal response are dramatically controlled by the circulation depth of karst systems, which determines the effectiveness of heat exchange. HLQ spring undergoes the deepest circulation depth of 820 m, and its thermal responses are determined by the thermally effective regulation processes at higher elevations and the mixing processes associated with thermally ineffective responses at lower elevations.

  9. Double stratification effects in chemically reactive squeezed Sutterby fluid flow with thermal radiation and mixed convection

    Directory of Open Access Journals (Sweden)

    S. Ahmad

    2018-03-01

    Full Text Available A current analysis is carried out to study theoretically the mixed convection characteristics in squeezing flow of Sutterby fluid in squeezed channel. The constitutive equation of Sutterby model is utilized to characterize the rheology of squeezing phenomenon. Flow characteristics are explored with dual stratification. In flowing fluid which contains heat and mass transport, the first order chemical reaction and radiative heat flux affect the transport phenomenon. The systems of non-linear governing equations have been modulating which then solved by mean of convergent approach (Homotopy Analysis Method. The graphs are reported and illustrated for emerging parameters. Through graphical explanations, drag force, rate of heat and mass transport are conversed for different pertinent parameters. It is found that heat and mass transport rate decays with dominant double stratified parameters and chemical reaction parameter. The present two-dimensional examination is applicable in some of the engineering processes and industrial fluid mechanics. Keywords: Squeezing flow, Sutterby fluid model, Mixed convection, Double stratification, Thermal radiation, Chemical reaction

  10. Thermal decomposition process of silver behenate

    International Nuclear Information System (INIS)

    Liu Xianhao; Lu Shuxia; Zhang Jingchang; Cao Weiliang

    2006-01-01

    The thermal decomposition processes of silver behenate have been studied by infrared spectroscopy (IR), X-ray diffraction (XRD), combined thermogravimetry-differential thermal analysis-mass spectrometry (TG-DTA-MS), transmission electron microscopy (TEM) and UV-vis spectroscopy. The TG-DTA and the higher temperature IR and XRD measurements indicated that complicated structural changes took place while heating silver behenate, but there were two distinct thermal transitions. During the first transition at 138 deg. C, the alkyl chains of silver behenate were transformed from an ordered into a disordered state. During the second transition at about 231 deg. C, a structural change took place for silver behenate, which was the decomposition of silver behenate. The major products of the thermal decomposition of silver behenate were metallic silver and behenic acid. Upon heating up to 500 deg. C, the final product of the thermal decomposition was metallic silver. The combined TG-MS analysis showed that the gas products of the thermal decomposition of silver behenate were carbon dioxide, water, hydrogen, acetylene and some small molecule alkenes. TEM and UV-vis spectroscopy were used to investigate the process of the formation and growth of metallic silver nanoparticles

  11. Tests of Parameterized Langmuir Circulation Mixing in the Oceans Surface Mixed Layer II

    Science.gov (United States)

    2017-08-11

    inertial oscillations in the ocean are governed by three-dimensional processes that are not accounted for in a one-dimensional simulation , and it was...Unlimited 52 Paul Martin (228) 688-5447 Recent large-eddy simulations (LES) of Langmuir circulation (LC) within the surface mixed layer (SML) of...used in the Navy Coastal Ocean Model (NCOM) and tested for (a) a simple wind-mixing case, (b) simulations of the upper ocean thermal structure at Ocean

  12. Study of mixing process in the IRIS downcomer

    Energy Technology Data Exchange (ETDEWEB)

    Diaz, Elizabeth; Montesinos, Maria E.; Garcia, Carlos; Rives, Ronny; Rojas, Leorlen Y., E-mail: ciazbueno@instec.cu, E-mail: mmontesi@instec.cu, E-mail: cgh@instec.cu, E-mail: rsanz@instec.cu, E-mail: leored1984@gmail.com [Instituto Superior de Tecnologias y Ciencias Aplicadas (InSTEC), La Habana (Cuba); Bezerra, Jair L.; Lira, Carlos A.B. de Oliveira, E-mail: jairbezerra@gmail.com, E-mail: cabol@ufpe.br [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil). Departamento de Energia Nuclear

    2015-07-01

    The reactivity of a water cooled reactor is controlled using control rods or boron dilution in water of the primary circuit. The Boron-10 (10B) is an efficient neutron absorber, especially when used in the absorption of thermal neutrons. Transient analysis with disabilities in the homogenization of Boron in PWR reactors becomes important as the boric acid solution is added to the primary circuit coolant in order to help control the fission rate in the reactor core. After reactor shutdown, the Boron present in coolant has the function of maintaining the reactor subcriticality. The aim of this research is to study the Boron homogenization processes in the downcomer of the IRIS nuclear reactor. It was used a test section, which represents a quarter of the interest geometry to harness the domain symmetry. By using the CFX code, the startup and shutdown were simulated in order to analyze the mixing processes in the coolant. It was evaluated the influence in the Boron homogenization of different geometrical configurations such as three different positions of coolant entrance with respect to the core holders and the variation of the dimensions of the DVI lines. This paper also analyze an event of partial loss of coolant because a coolant pump failure. (author)

  13. Transient thermal analysis for radioactive liquid mixing operations in a large-scaled tank

    International Nuclear Information System (INIS)

    Lee, S. Y.; Smith, F. G. III

    2014-01-01

    A transient heat balance model was developed to assess the impact of a Submersible Mixer Pump (SMP) on radioactive liquid temperature during the process of waste mixing and removal for the high-level radioactive materials stored in Savannah River Site (SRS) tanks. The model results will be mainly used to determine the SMP design impacts on the waste tank temperature during operations and to develop a specification for a new SMP design to replace existing longshaft mixer pumps used during waste removal. The present model was benchmarked against the test data obtained by the tank measurement to examine the quantitative thermal response of the tank and to establish the reference conditions of the operating variables under no SMP operation. The results showed that the model predictions agreed with the test data of the waste temperatures within about 10%

  14. Experimental and computational studies of thermal mixing in next generation nuclear reactors

    Science.gov (United States)

    Landfried, Douglas Tyler

    The Very High Temperature Reactor (VHTR) is a proposed next generation nuclear power plant. The VHTR utilizes helium as a coolant in the primary loop of the reactor. Helium traveling through the reactor mixes below the reactor in a region known as the lower plenum. In this region there exists large temperature and velocity gradients due to non-uniform heat generation in the reactor core. Due to these large gradients, concern should be given to reducing thermal striping in the lower plenum. Thermal striping is the phenomena by which temperature fluctuations in the fluid and transferred to and attenuated by surrounding structures. Thermal striping is a known cause of long term material failure. To better understand and predict thermal striping in the lower plenum two separate bodies of work have been conducted. First, an experimental facility capable of predictably recreating some aspects of flow in the lower plenum is designed according to scaling analysis of the VHTR. Namely the facility reproduces jets issuing into a crossflow past a tube bundle. Secondly, extensive studies investigate the mixing of a non-isothermal parallel round triple-jet at two jet-to-jet spacings was conducted. Experimental results were validation with an open source computational fluid dynamics package, OpenFOAMRTM. Additional care is given to understanding the implementation of the realizable k-a and Launder Gibson RSM turbulence Models in OpenFOAMRTM. In order to measure velocity and temperature in the triple-jet experiment a detailed investigation of temperature compensated hotwire anemometry is carried out with special concern being given to quantify the error with the measurements. Finally qualitative comparisons of trends in the experimental results and the computational results is conducted. A new and unexpected physical behavior was observed in the center jet as it appeared to spread unexpectedly for close spacings (S/Djet = 1.41).

  15. Operating cost guidelines for benchmarking DOE thermal treatment systems for low-level mixed waste

    International Nuclear Information System (INIS)

    Salmon, R.; Loghry, S.L.; Hermes, W.H.

    1994-11-01

    This report presents guidelines for estimating operating costs for use in benchmarking US Department of Energy (DOE) low-level mixed waste thermal treatment systems. The guidelines are based on operating cost experience at the DOE Toxic Substances Control Act (TSCA) mixed waste incinerator at the K-25 Site at Oak Ridge. In presenting these guidelines, it should be made clear at the outset that it is not the intention of this report to present operating cost estimates for new technologies, but only guidelines for estimating such costs

  16. Identification of an 84Sr-depleted carrier in primitive meteorites and implications for thermal processing in the solar protoplanetary disk

    DEFF Research Database (Denmark)

    Paton, Chad; Schiller, Martin; Bizzarro, Martin

    2013-01-01

    material or secondary processing of a well-mixed disk. Using stepwise acid-leaching of the Ivuna CI-chondrite, we show that unlike other nuclides such as Cr and Ti, Sr-isotope variability is the result of a carrier depleted in Sr. The carrier is most likely presolar SiC, which is known to have both high Sr......The existence of correlated nucleosynthetic heterogeneities in solar system reservoirs is now well demonstrated for numerous nuclides. However, it has proven difficult to discriminate between the two disparate processes that can explain such correlated variability: incomplete mixing of presolar...... anomalies, respectively, is not compatible with incomplete mixing of presolar material but instead suggests that the solar system's nucleosynthetic heterogeneity reflects selective thermal processing of dust. Based on vaporization experiments of SiC under nebular conditions, the lack of SiC material...

  17. Rapid thermal processing of semiconductors

    CERN Document Server

    Borisenko, Victor E

    1997-01-01

    Rapid thermal processing has contributed to the development of single wafer cluster processing tools and other innovations in integrated circuit manufacturing environments Borisenko and Hesketh review theoretical and experimental progress in the field, discussing a wide range of materials, processes, and conditions They thoroughly cover the work of international investigators in the field

  18. A method to determine stratification efficiency of thermal energy storage processes independently from storage heat losses

    DEFF Research Database (Denmark)

    Haller, M.Y.; Yazdanshenas, Eshagh; Andersen, Elsa

    2010-01-01

    process is in agreement with the first law of thermodynamics. A comparison of the stratification efficiencies obtained from experimental results of charging, standby, and discharging processes gives meaningful insights into the different mixing behaviors of a storage tank that is charged and discharged......A new method for the calculation of a stratification efficiency of thermal energy storages based on the second law of thermodynamics is presented. The biasing influence of heat losses is studied theoretically and experimentally. Theoretically, it does not make a difference if the stratification...

  19. Mixed Convection Flow along a Stretching Cylinder in a Thermally Stratified Medium

    Directory of Open Access Journals (Sweden)

    Swati Mukhopadhyay

    2012-01-01

    Full Text Available An analysis for the axisymmetric laminar boundary layer mixed convection flow of a viscous and incompressible fluid towards a stretching cylinder immersed in a thermally stratified medium is presented in this paper. Similarity transformation is employed to convert the governing partial differential equations into highly nonlinear ordinary differential equations. Numerical solutions of these equations are obtained by a shooting method. It is found that the heat transfer rate at the surface is lower for flow in a thermally stratified medium compared to that of an unstratified medium. Moreover, both the skin friction coefficient and the heat transfer rate at the surface are larger for a cylinder compared to that for a flat plate.

  20. Thermal-grating contributions to degenerate four-wave mixing in nitric oxide

    International Nuclear Information System (INIS)

    Danehy, P.M.; Paul, P.H.; Farrow, R.L.

    1995-01-01

    We report investigations of degenerate four-wave mixing (DFWM) line intensities in the A 2 Σ + left-arrow X 2 Π electronic transitions of nitric oxide. Contributions from population gratings (spatially varying perturbations in the level populations of absorbing species) and thermal gratings (spatially varying perturbations in the overall density) were distinguished and compared by several experimental and analytical techniques. For small quantities of nitric oxide in a strongly quenching buffer gas (carbon dioxide), we found that thermal-grating contributions dominated at room temperature for gas pressures of ∼0.5 atm and higher. In a nearly nonquenching buffer (nitrogen) the population-grating mechanism dominated at pressures of ∼1.0 atm and lower. At higher temperatures in an atmospheric-pressure methane/air flame, population gratings of nitric oxide also dominated. We propose a simple model for the ratio of thermal- to population-grating scattering intensities that varies as P 4 T -4.4 . Preliminary investigations of the temperature dependence and detailed studies of the pressure dependence are in agreement with this model. Measurements of the temporal evolution and the peak intensity of isolated thermal-grating signals are in detailed agreement with calculations based on a linearized hydrodynamic model [J. Opt. Soc. Am. B 12, 384 (1995)]. copyright 1995 Optical Society of America

  1. Validation of Effective Models for Simulation of Thermal Stratification and Mixing Induced by Steam Injection into a Large Pool of Water

    Directory of Open Access Journals (Sweden)

    Hua Li

    2014-01-01

    Full Text Available The Effective Heat Source (EHS and Effective Momentum Source (EMS models have been proposed to predict the development of thermal stratification and mixing during a steam injection into a large pool of water. These effective models are implemented in GOTHIC software and validated against the POOLEX STB-20 and STB-21 tests and the PPOOLEX MIX-01 test. First, the EHS model is validated against STB-20 test which shows the development of thermal stratification. Different numerical schemes and grid resolutions have been tested. A 48×114 grid with second order scheme is sufficient to capture the vertical temperature distribution in the pool. Next, the EHS and EMS models are validated against STB-21 test. Effective momentum is estimated based on the water level oscillations in the blowdown pipe. An effective momentum selected within the experimental measurement uncertainty can reproduce the mixing details. Finally, the EHS-EMS models are validated against MIX-01 test which has improved space and time resolution of temperature measurements inside the blowdown pipe. Excellent agreement in averaged pool temperature and water level in the pool between the experiment and simulation has been achieved. The development of thermal stratification in the pool is also well captured in the simulation as well as the thermal behavior of the pool during the mixing phase.

  2. Conjugate heat transfer LES of thermal mixing in a T-junction

    Energy Technology Data Exchange (ETDEWEB)

    Timperi, Antti, E-mail: antti.timperi@vtt.fi

    2014-07-01

    Highlights: • Turbulent mixing of hot and cold water in a T-junction is studied with LES including conjugate heat transfer. • The numerical simulations are in good agreement with experimental data in the bulk of the flow. • Comparison of different inlet and wall boundary conditions shows significant differences only near walls. • Effects of mesh and flow velocity on the velocity and temperature fluctuations are also considered. - Abstract: Turbulent mixing of hot and cold fluids may lead to high-cycle thermal fatigue in piping of nuclear power plants. In this work, the mixing in a T-junction experiment is studied by large-eddy simulation (LES). Conjugate heat transfer (CHT) between fluid and pipe wall is studied by replacing the plexiglass pipe of the experiment with a steel one. Different inlet and wall boundary conditions are first considered. Steady and turbulent inlets are compared, as well as adiabatic and CHT wall conditions. The turbulent inlets are created by using the vortex method which is validated for fully developed flow. The inlets are shown to have only small effect in bulk of the flow, but non-negligible effect near walls. The adiabatic and CHT cases show practically no difference in the logarithmic layer and upward, whereas near walls the difference becomes significant due to thermal inertia of the pipe wall. In bulk of the flow, the mean and fluctuating quantities show good agreement with the experiment. CHT simulations by using different meshes and flow velocities are then considered. A coarse mesh is found to yield qualitative agreement but significant errors in e.g. Reynolds stresses near walls. Temperature fluctuation intensity at the pipe inner surface is fairly similar for both meshes. Normalized profiles and spectra for different velocities are qualitatively similar, but some differences exist e.g. in distributions of wall temperature fluctuation intensity.

  3. Laser Processing of Multilayered Thermal Spray Coatings: Optimal Processing Parameters

    Science.gov (United States)

    Tewolde, Mahder; Zhang, Tao; Lee, Hwasoo; Sampath, Sanjay; Hwang, David; Longtin, Jon

    2017-12-01

    Laser processing offers an innovative approach for the fabrication and transformation of a wide range of materials. As a rapid, non-contact, and precision material removal technology, lasers are natural tools to process thermal spray coatings. Recently, a thermoelectric generator (TEG) was fabricated using thermal spray and laser processing. The TEG device represents a multilayer, multimaterial functional thermal spray structure, with laser processing serving an essential role in its fabrication. Several unique challenges are presented when processing such multilayer coatings, and the focus of this work is on the selection of laser processing parameters for optimal feature quality and device performance. A parametric study is carried out using three short-pulse lasers, where laser power, repetition rate and processing speed are varied to determine the laser parameters that result in high-quality features. The resulting laser patterns are characterized using optical and scanning electron microscopy, energy-dispersive x-ray spectroscopy, and electrical isolation tests between patterned regions. The underlying laser interaction and material removal mechanisms that affect the feature quality are discussed. Feature quality was found to improve both by using a multiscanning approach and an optional assist gas of air or nitrogen. Electrically isolated regions were also patterned in a cylindrical test specimen.

  4. Grand Junction projects office mixed-waste treatment program, VAC*TRAX mobile treatment unit process hazards analysis

    International Nuclear Information System (INIS)

    Bloom, R.R.

    1996-04-01

    The objective of this report is to demonstrate that a thorough assessment of the risks associated with the operation of the Rust Geotech patented VAC*TRAX mobile treatment unit (MTU) has been performed and documented. The MTU was developed to treat mixed wastes at the US Department of Energy (DOE) Albuquerque Operations Office sites. The MTU uses an indirectly heated, batch vacuum dryer to thermally desorb organic compounds from mixed wastes. This process hazards analysis evaluated 102 potential hazards. The three significant hazards identified involved the inclusion of oxygen in a process that also included an ignition source and fuel. Changes to the design of the MTU were made concurrent with the hazard identification and analysis; all hazards with initial risk rankings of 1 or 2 were reduced to acceptable risk rankings of 3 or 4. The overall risk to any population group from operation of the MTU was determined to be very low; the MTU is classified as a Radiological Facility with low hazards

  5. Grand Junction projects office mixed-waste treatment program, VAC*TRAX mobile treatment unit process hazards analysis

    Energy Technology Data Exchange (ETDEWEB)

    Bloom, R.R.

    1996-04-01

    The objective of this report is to demonstrate that a thorough assessment of the risks associated with the operation of the Rust Geotech patented VAC*TRAX mobile treatment unit (MTU) has been performed and documented. The MTU was developed to treat mixed wastes at the US Department of Energy (DOE) Albuquerque Operations Office sites. The MTU uses an indirectly heated, batch vacuum dryer to thermally desorb organic compounds from mixed wastes. This process hazards analysis evaluated 102 potential hazards. The three significant hazards identified involved the inclusion of oxygen in a process that also included an ignition source and fuel. Changes to the design of the MTU were made concurrent with the hazard identification and analysis; all hazards with initial risk rankings of 1 or 2 were reduced to acceptable risk rankings of 3 or 4. The overall risk to any population group from operation of the MTU was determined to be very low; the MTU is classified as a Radiological Facility with low hazards.

  6. Thermal Stir Welding: A New Solid State Welding Process

    Science.gov (United States)

    Ding, R. Jeffrey

    2003-01-01

    Thermal stir welding is a new welding process developed at NASA's Marshall Space Flight Center in Huntsville, AL. Thermal stir welding is similar to friction stir welding in that it joins similar or dissimilar materials without melting the parent material. However, unlike friction stir welding, the heating, stirring and forging elements of the process are all independent of each other and are separately controlled. Furthermore, the heating element of the process can be either a solid-state process (such as a thermal blanket, induction type process, etc), or, a fusion process (YG laser, plasma torch, etc.) The separation of the heating, stirring, forging elements of the process allows more degrees of freedom for greater process control. This paper introduces the mechanics of the thermal stir welding process. In addition, weld mechanical property data is presented for selected alloys as well as metallurgical analysis.

  7. Thermal treatment technology study and data base for Department of Energy mixed waste

    International Nuclear Information System (INIS)

    Gillins, R.L.; Steverson, E.M.; Balo, K.A.

    1991-01-01

    The Department of Energy (DOE) has a wide variety of waste streams that must be treated to meet various regulations before final disposal. One category of technologies for treating many of these waste streams is thermal treatment. A study of known thermal treatment technologies was conducted to aid DOE in the development of strategies to meet its waste management needs. The study was specifically addressed to mixed waste, but it is also applicable to hazardous and radioactive wastes. The data collected in the study, along with other waste management data, are being included in a comprehensive data base that DOE is developing. 3 refs., 1 fig

  8. Thermal effects in radiation processing

    International Nuclear Information System (INIS)

    Zagorski, Z.P.

    1985-01-01

    The balance of ionizing radiation energy incident on an object being processed is discussed in terms of energy losses, influencing the amount really absorbed. To obtain the amount of heat produced, the absorbed energy is corrected for the change in internal energy of the system and for the heat effect of secondary reactions developing after the initiation. The temperature of a processed object results from the heat evolved and from the specific heat of the material comprising the object. The csub(p) of most materials is usually much lower than that of aqueous systems and therefore temperatures after irradiation are higher. The role of low specific heat in radiation processing at cryogenic conditions is stressed. Adiabatic conditions of accelerator irradiation are contrasted with the steady state thermal conditions prevailing in large gamma sources. Among specific questions discussed in the last part of the paper are: intermediate and final temperature of composite materials, measurement of real thermal effects in situ, neutralization of undesired warming experienced during radiation processing, processing at temperatures other than ambient and administration of very high doses of radiation. (author)

  9. Thermal effects in radiation processing

    International Nuclear Information System (INIS)

    Zagorski, Z.P.

    1984-01-01

    The balance of ionizing radiation energy incident on an object being processed is discussed in terms of energy losses, influencing the amount really absorbed. To obtain the amount of heat produced, the absorbed energy is corrected for the change in internal energy of the system and for the heat effect of secondary reactions developing after the initiation. The temperature of a processed object results from the heat evolved and from the specific heat of the material comprising the object. The specific heat of most materials is usually much lower than that of aqueous systems and therefore temperatures after irradiation are higher. The role of low specific heat in radiation processing at cryogenic conditions is stressed. Adiabatic conditions of accelerator irradiation are contrasted with the steady state thermal conditions prevailing in large gamma sources. Among specific questions discussed in the last part of the paper are: intermediate and final temperature of composite materials, measurement of real thermal effects in situ, neutralization of undesired warming experienced during radiation processing, processing at temperatures other than ambient and administration of very high doses of radiation

  10. Process and Economic Optimisation of a Milk Processing Plant with Solar Thermal Energy

    DEFF Research Database (Denmark)

    Bühler, Fabian; Nguyen, Tuong-Van; Elmegaard, Brian

    2016-01-01

    . Based on the case study of a dairy factory, where first a heat integration is performed to optimise the system, a model for solar thermal process integration is developed. The detailed model is based on annual hourly global direct and diffuse solar radiation, from which the radiation on a defined......This work investigates the integration of solar thermal systems for process energy use. A shift from fossil fuels to renewable energy could be beneficial both from environmental and economic perspectives, after the process itself has been optimised and efficiency measures have been implemented...... surface is calculated. Based on hourly process stream data from the dairy factory, the optimal streams for solar thermal process integration are found, with an optimal thermal storagetank volume. The last step consists of an economic optimisation of the problem to determine the optimal size...

  11. Evaluation of thermal conductivity of heat-cured acrylic resin mixed with A1203

    Directory of Open Access Journals (Sweden)

    Ebadian B.

    2002-08-01

    Full Text Available One of the most important characteristics of denture base is thermal conductivity. This property has a major role in secretions of salivary glands and their enzymes, taste of the food and gustatory response. Polymethyl methacrylate used in prosthodontics is relatively an insulator. Different materials such as metal fillers and ceramics have been used to solve this problem. The aim of this study was the evaluation of AI2O3 effect on thermal conductivity of heat-cured acrylic resin. Acrylic resin was mixed with AI2O3 in two different weight rates (15 and 20 % of weight. So, group 1 and 2 were divided on this basis. Samples with pure acrylic resin were considered as control group. 18 cylindrical patterns were made in 9x9 mm dimensions and thermocouple wires embedded in each sample to act as conductor. The specimens were put in water with 70±1°C thermal range for 10 minutes. Then, thermal conductivity was measured. The results were analyzed with variance analysis and Dunken test. There was significant difference between thermal conductivity of all groups in all period times. It the first seconds, thermal conductivity in groups 1 and 2 were more than control group. Therefore, for developing of thermal conductivity of acrylic resin, A1203 can be used. Certainly, other characteristic of new resin should be evaluated.

  12. VARIATION IN MEAT COMPOSITION VISCOSITY DURING THE MIXING PROCESS

    Directory of Open Access Journals (Sweden)

    DANIELA IANIłCHI

    2008-10-01

    Full Text Available Animal raw material processing is directly influenced by the physical and chemical characteristics of the materials which also influence their water holding capacity. The various combinations and status of the raw materials used in the food industry determine specific behaviours that may influence the processing equipment performance and construction. The study on meat composition viscosity depending upon the added components, temperature and mixing time length, has shown that viscosity is increasing with lower added water percentage, lower mixing temperature and higher mixing time length.

  13. Effect of unit size on thermal fatigue behavior of hot work steel repaired by a biomimetic laser remelting process

    Science.gov (United States)

    Cong, Dalong; Li, Zhongsheng; He, Qingbing; Chen, Dajun; Chen, Hanbin; Yang, Jiuzhou; Zhang, Peng; Zhou, Hong

    2018-01-01

    AISI H13 hot work steel with fatigue cracks was repaired by a biomimetic laser remelting (BLR) process in the form of lattice units with different sizes. Detailed microstructural studies and microhardness tests were carried out on the units. Studies revealed a mixed microstructure containing martensite, retained austenite and carbide particles with ultrafine grain size in units. BLR samples with defect-free units exhibited superior thermal fatigue resistance due to microstructure strengthening, and mechanisms of crack tip blunting and blocking. In addition, effects of unit size on thermal fatigue resistance of BLR samples were discussed.

  14. Dynamic water vapor sorption on Mg(Ga3+)O mixed oxides: Analysis of the LDH thermal regeneration process

    International Nuclear Information System (INIS)

    Bedolla-Valdez, Zaira I.; Ramirez-Solis, Sergio; Prince, Julia; Lima, Enrique; Pfeiffer, Heriberto; Valente, Jaime S.

    2013-01-01

    Highlights: ► Ga-LDH regeneration process was analyzed varying the relative humidity. ► Ga-LDH rehydrates faster than aluminum content LDH materials. ► Gallium seems to favor diffusion processeses during LDH regeneration. - Abstract: The rehydration process of the calcined MgGa-layered double hydroxides (Ga-LDH) was analyzed at different temperatures and relative humidities. Results clearly showed that Ga-LDH sample presented an excellent regeneration kinetic, in comparison to the aluminum typical one. Different techniques such as X-ray diffraction, infrared spectroscopy and thermal analysis were used to elucidate the presented results

  15. 9 CFR 318.302 - Thermal processing.

    Science.gov (United States)

    2010-01-01

    ... 318.302 Animals and Animal Products FOOD SAFETY AND INSPECTION SERVICE, DEPARTMENT OF AGRICULTURE AGENCY ORGANIZATION AND TERMINOLOGY; MANDATORY MEAT AND POULTRY PRODUCTS INSPECTION AND VOLUNTARY... Canning and Canned Products § 318.302 Thermal processing. (a) Process schedules. Prior to the processing...

  16. Study on heat transfer characteristics in a mixing tee pipe to evaluate for thermal fatigue

    International Nuclear Information System (INIS)

    Miyoshi, Koji; Nakamura, Akira; Utanohara, Yoichi

    2016-01-01

    Thermal fatigue racking may initiate at a tee pipe where high and low temperature fluids flow in from different directions and mix. Thermal stress fluctuations are caused by movement of a hot spot on the pipe inner surface. It is important to investigate the heat transfer from the fluid to the structure around the hot spot. The heat transfer characteristic in the mixing tee pipe was investigated by tests in this study. The unsteady heat transfer coefficients around the hot spot were estimated with the fluid and wall temperature, which were measured with thermocouples. The estimated heat transfer coefficient varied from 1.2 to 3.5 times of the steady state heat transfer coefficient. The heat transfer coefficient was 2.9 times of the steady state value at the position for the maximum stress fluctuation, which was calculated with the measured wall temperature distribution. (author)

  17. Comparison of scale analysis and numerical simulation for saturated zone convective mixing processes

    International Nuclear Information System (INIS)

    Oldenburg, C.M.

    1998-01-01

    Scale analysis can be used to predict a variety of quantities arising from natural systems where processes are described by partial differential equations. For example, scale analysis can be applied to estimate the effectiveness of convective missing on the dilution of contaminants in groundwater. Scale analysis involves substituting simple quotients for partial derivatives and identifying and equating the dominant terms in an order-of-magnitude sense. For free convection due to sidewall heating of saturated porous media, scale analysis shows that vertical convective velocity in the thermal boundary layer region is proportional to the Rayleigh number, horizontal convective velocity is proportional to the square root of the Rayleigh number, and thermal boundary layer thickness is proportional to the inverse square root of the Rayleigh number. These scale analysis estimates are corroborated by numerical simulations of an idealized system. A scale analysis estimate of mixing time for a tracer mixing by hydrodynamic dispersion in a convection cell also agrees well with numerical simulation for two different Rayleigh numbers. Scale analysis for the heating-from-below scenario produces estimates of maximum velocity one-half as large as the sidewall case. At small values of the Rayleigh number, this estimate is confirmed by numerical simulation. For larger Rayleigh numbers, simulation results suggest maximum velocities are similar to the sidewall heating scenario. In general, agreement between scale analysis estimates and numerical simulation results serves to validate the method of scale analysis. Application is to radioactive repositories

  18. A new low-cost method of reclaiming mixed foundry waste sand based on wet-thermal composite reclamation

    OpenAIRE

    Fan Zitian; Liu Fuchu; Long Wei

    2014-01-01

    A lot of mixed clay-resin waste sand from large-scale iron foundries is discharged every day; so mixed waste sand reclamation in low cost and high quality has a great realistic significance. In the study to investigate the possibility of reusing two types of waste foundry sands, resin bonded sand and clay bonded sand which came from a Chinese casting factory, a new low-cost reclamation method of the mixed foundry waste sand based on the wet-thermal composite reclamation was proposed. The wast...

  19. Influence of winding construction on starter-generator thermal processes

    Science.gov (United States)

    Grachev, P. Yu; Bazarov, A. A.; Tabachinskiy, A. S.

    2018-01-01

    Dynamic processes in starter-generators features high winding are overcurrent. It can lead to insulation overheating and fault operation mode. For hybrid and electric vehicles, new high efficiency construction of induction machines windings is proposed. Stator thermal processes need be considered in the most difficult operation modes. The article describes construction features of new compact stator windings, electromagnetic and thermal models of processes in stator windings and explains the influence of innovative construction on thermal processes. Models are based on finite element method.

  20. Modelling thermal plume impacts - Kalpakkam approach

    International Nuclear Information System (INIS)

    Rao, T.S.; Anup Kumar, B.; Narasimhan, S.V.

    2002-01-01

    A good understanding of temperature patterns in the receiving waters is essential to know the heat dissipation from thermal plumes originating from coastal power plants. The seasonal temperature profiles of the Kalpakkam coast near Madras Atomic Power Station (MAPS) thermal out fall site are determined and analysed. It is observed that the seasonal current reversal in the near shore zone is one of the major mechanisms for the transport of effluents away from the point of mixing. To further refine our understanding of the mixing and dilution processes, it is necessary to numerically simulate the coastal ocean processes by parameterising the key factors concerned. In this paper, we outline the experimental approach to achieve this objective. (author)

  1. BENCH SCALE SALTSTONE PROCESS DEVELOPMENT MIXING STUDY

    Energy Technology Data Exchange (ETDEWEB)

    Cozzi, A.; Hansen, E.

    2011-08-03

    The Savannah River National Laboratory (SRNL) was requested to develop a bench scale test facility, using a mixer, transfer pump, and transfer line to determine the impact of conveying the grout through the transfer lines to the vault on grout properties. Bench scale testing focused on the effect the transfer line has on the rheological property of the grout as it was processed through the transfer line. Rheological and other physical properties of grout samples were obtained prior to and after pumping through a transfer line. The Bench Scale Mixing Rig (BSMR) consisted of two mixing tanks, grout feed tank, transfer pump and transfer hose. The mixing tanks were used to batch the grout which was then transferred into the grout feed tank. The contents of the feed tank were then pumped through the transfer line (hose) using a progressive cavity pump. The grout flow rate and pump discharge pressure were monitored. Four sampling stations were located along the length of the transfer line at the 5, 105 and 205 feet past the transfer pump and at 305 feet, the discharge of the hose. Scaling between the full scale piping at Saltstone to bench scale testing at SRNL was performed by maintaining the same shear rate and total shear at the wall of the transfer line. The results of scaling down resulted in a shorter transfer line, a lower average velocity, the same transfer time and similar pressure drops. The condition of flow in the bench scale transfer line is laminar. The flow in the full scale pipe is in the transition region, but is more laminar than turbulent. The resulting plug in laminar flow in the bench scale results in a region of no-mixing. Hence mixing, or shearing, at the bench scale should be less than that observed in the full scale, where this plug is non existent due to the turbulent flow. The bench scale tests should be considered to be conservative due to the highly laminar condition of flow that exists. Two BSMR runs were performed. In both cases, wall

  2. An overview of modeling methods for thermal mixing and stratification in large enclosures for reactor safety analysis

    Energy Technology Data Exchange (ETDEWEB)

    Haihua Zhao; Per F. Peterson

    2010-10-01

    Thermal mixing and stratification phenomena play major roles in the safety of reactor systems with large enclosures, such as containment safety in current fleet of LWRs, long-term passive containment cooling in Gen III+ plants including AP-1000 and ESBWR, the cold and hot pool mixing in pool type sodium cooled fast reactor systems (SFR), and reactor cavity cooling system behavior in high temperature gas cooled reactors (HTGR), etc. Depending on the fidelity requirement and computational resources, 0-D steady state models (heat transfer correlations), 0-D lumped parameter based transient models, 1-D physical-based coarse grain models, and 3-D CFD models are available. Current major system analysis codes either have no models or only 0-D models for thermal stratification and mixing, which can only give highly approximate results for simple cases. While 3-D CFD methods can be used to analyze simple configurations, these methods require very fine grid resolution to resolve thin substructures such as jets and wall boundaries. Due to prohibitive computational expenses for long transients in very large volumes, 3-D CFD simulations remain impractical for system analyses. For mixing in stably stratified large enclosures, UC Berkeley developed 1-D models basing on Zuber’s hierarchical two-tiered scaling analysis (HTTSA) method where the ambient fluid volume is represented by 1-D transient partial differential equations and substructures such as free or wall jets are modeled with 1-D integral models. This allows very large reductions in computational effort compared to 3-D CFD modeling. This paper will present an overview on important thermal mixing and stratification phenomena in large enclosures for different reactors, major modeling methods and their advantages and limits, potential paths to improve simulation capability and reduce analysis uncertainty in this area for advanced reactor system analysis tools.

  3. Mixing processes in high-level waste tanks. Progress report, September 15, 1996 - September 14, 1997

    International Nuclear Information System (INIS)

    Peterson, P.F.

    1997-01-01

    useful codes for predicting stratification and mixing due to fires in enclosures, but these codes are not supported by appropriate experiments for waste tanks, and do not consider mixing induced by injected jets, or the detailed distribution of fuel and oxygen concentration. The UCB Thermal Hydraulics Group model BMIX (Berkeley Mechanistic Mixing Model) is being developed to mechanistically predict mixing processes in large waste-tank volumes, where mixing processes can be driven by hot and cold vertical and horizontal surfaces and injected buoyant jets. The author is supporting the model with scaled experiments using water/salt solutions, as well as separate experiments using air with simulant fuels (helium and refrigerant-22 for hydrogen and benzene) to study the specific mixing processes which occur in waste tanks, and will also support the implementation of the code for use in waste tank operations. This year''s experimental efforts have focused on scaled water systems to study the exchange flows which occur through tank ceiling openings following loss of ventilation, as well the mixing processes that occur below the ceiling. These water experiments are providing data and insight for the modeling effort while construction of the larger air/benzene simulant experiment is underway.'

  4. Thermal processes identification using virtual instrumentation

    Directory of Open Access Journals (Sweden)

    Iosif OLAH

    2007-12-01

    Full Text Available In this paper the experimental identification problem of thermal processes is presented, in order to establish their mathematical models which permit the adoption of the automation solutions, respectively the specification of a suitable control law. With this aim in view, the authors resorted to use Virtual Instrumentation with the aid of the LabVIEW development medium. In order to solve the problem of acquisition and processing data from physical real processes, Virtual Instruments which provide at the end a mathematical model which is basis of choosing the automation equipment of the aim followed was designed and achieved. The achieved Virtual Instruments get the opportunity to be used either in student instruction field with the virtual processes identification techniques or to put the identification of some real processes to good use of diverse beneficiaries. The results of some experimental attempts which were achieved during different thermal processes, illustrate the utility of the demarches performed in this paper.

  5. Final Report: Fiscal Year 1997 demonstration of omnivorous non-thermal mixed waste treatment: Direct chemical oxidation of organic solids and liquids using peroxydisulfate

    International Nuclear Information System (INIS)

    Cooper, J.F.; Ballazs G.B.

    1998-01-01

    Direct Chemical Oxidation (DCO) is a non-thermal, ambient pressure, aqueous-based technology for the oxidative destruction of the organic components of hazardous or mixed waste streams. The process has been developed for applications in waste treatment, chemical demilitarization and decontamination at LLNL since 1992. The process uses solutions of the peroxydisulfate ion (typically sodium or ammonium salts) to completely mineralize the organics to carbon dioxide and water. The expended oxidant may be electrolytically regenerated to minimize secondary waste. The paper briefly describes: free radical and secondary oxidant formation; electrochemical regeneration; offgas stream; and throughput

  6. Final Report: Fiscal Year 1997 demonstration of omnivorous non-thermal mixed waste treatment: Direct chemical oxidation of organic solids and liquids using peroxydisulfate

    Energy Technology Data Exchange (ETDEWEB)

    Cooper, J.F.

    1998-01-01

    Direct Chemical Oxidation (DCO) is a non-thermal, ambient pressure, aqueous-based technology for the oxidative destruction of the organic components of hazardous or mixed waste streams. The process has been developed for applications in waste treatment, chemical demilitarization and decontamination at LLNL since 1992. The process uses solutions of the peroxydisulfate ion (typically sodium or ammonium salts) to completely mineralize the organics to carbon dioxide and water. The expended oxidant may be electrolytically regenerated to minimize secondary waste. The paper briefly describes: free radical and secondary oxidant formation; electrochemical regeneration; offgas stream; and throughput.

  7. Treatment of mixed wastes by thermal plasma discharges; Tratamiento de desechos mixtos por descargas de plasma termico

    Energy Technology Data Exchange (ETDEWEB)

    Diaz A, L.V.; Pacheco S, J.O.; Pacheco P, M.; Monroy G, F.; Emeterio H, M. [ININ, 52750 La Marquesa, Estado de Mexico (Mexico)]. e-mail: lauradiazarch@yahoo.com.mx

    2007-07-01

    The National Institute of Nuclear Research (ININ) uses an ion exchange resin: IRN 150 (copolymer styrene Divynilbencene) in the TRIGA Mark III reactor to absorb polluted particles with heavy metals and radioactive particles of low level. Once the capacity of filtrate of the resin is exceeded, it is replaced and considered with a mixed waste. This work is based on taking advantage of the advantages of the technique of the thermal plasma in a unique process: (high energy density 105W/cm{sup 3} high enthalpy, high reactivity chemical, high operation temperatures 6000-11500K and quick quenching 106K/s) for the degradation and vitrification of the resin IRN 150. The reactor of plasma is compact and it works to atmospheric pressure and reduced thermal inertia. Therefore, the main parameters involved during the degradation tests and vitrification are: plasma current, voltage, gas flow and distance among the electrodes. The used vitreous matrix, is obtained from a ceramic clay composed by an oxides mixture which are characterized by their good resistance to mechanical impacts and erosion caused by the water. The ceramic clay and the resin IRN 150 were analyzed before the treatment by Scanning Electron Microscopy (MEB), X-ray Diffraction (DRX), Thermal gravimetry (TGA) once vitrified the materials were also analyzed by MEB and DRX. It is obtained as a result that the material more appropriate to be used as vitreous matrix it is a ceramic clay formed by several oxides, being operated the plasma system with a current of 115A, voltage of 25V, flow of the argon gas of 5 l/m and a distance among electrodes of 10mm. With the development of the proposed technology and the material for the vitreous matrix, be rotted to try in a future a great variety of mixed waste. (Author)

  8. Experimental research of solid waste drying in the process of thermal processing

    Science.gov (United States)

    Bukhmirov, V. V.; Kolibaba, O. B.; Gabitov, R. N.

    2015-10-01

    The convective drying process of municipal solid waste layer as a polydispersed multicomponent porous structure is studied. On the base of the experimental data criterial equations for calculating heat transfer and mass transfer processes in the layer, depending on the humidity of the material, the speed of the drying agent and the layer height are obtained. These solutions are used in the thermal design of reactors for the thermal processing of multicomponent organic waste.

  9. Thermal analysis of a glass bending process

    International Nuclear Information System (INIS)

    Buonanno, G.; Dell'Isola, M.; Frattolillo, A.; Giovinco, G.

    2005-01-01

    The paper presents the thermal simulation of naturally ventilated ovens used in glass sheets hot forming for windscreen production. The determination of thermal and flow conditions in the oven and, consequently, the windshield temperature distribution is necessary both for the productive process optimisation and to assure beforehand, without any iterative tuning process, the required characteristics of the product considered. To this purpose, the authors carried out a 3D numerical simulation of the thermal interaction between the glass and the oven internal surfaces during the whole heating process inside the oven. In particular, a finite volumes method was used to take into account both the convective, conductive and radiative heat transfer in the oven. The numerical temperature distribution in the glass was validated through the comparison with the data obtained from an experimental apparatus designed and built for the purpose

  10. Thermal Properties of Asphalt Mixtures Modified with Conductive Fillers

    Directory of Open Access Journals (Sweden)

    Byong Chol Bai

    2015-01-01

    Full Text Available This paper investigates the thermal properties of asphalt mixtures modified with conductive fillers used for snow melting and solar harvesting pavements. Two different mixing processes were adopted to mold asphalt mixtures, dry- and wet-mixing, and two conductive fillers were used in this study, graphite and carbon black. The thermal conductivity was compared to investigate the effects of asphalt mixture preparing methods, the quantity, and the distribution of conductive filler on thermal properties. The combination of conductive filler with carbon fiber in asphalt mixture was evaluated. Also, rheological properties of modified asphalt binders with conductive fillers were measured using dynamic shear rheometer and bending beam rheometer at grade-specific temperatures. Based on rheological testing, the conductive fillers improve rutting resistance and decrease thermal cracking resistance. Thermal testing indicated that graphite and carbon black improve the thermal properties of asphalt mixes and the combined conductive fillers are more effective than the single filler.

  11. Integrating Thermal Tools Into the Mechanical Design Process

    Science.gov (United States)

    Tsuyuki, Glenn T.; Siebes, Georg; Novak, Keith S.; Kinsella, Gary M.

    1999-01-01

    The intent of mechanical design is to deliver a hardware product that meets or exceeds customer expectations, while reducing cycle time and cost. To this end, an integrated mechanical design process enables the idea of parallel development (concurrent engineering). This represents a shift from the traditional mechanical design process. With such a concurrent process, there are significant issues that have to be identified and addressed before re-engineering the mechanical design process to facilitate concurrent engineering. These issues also assist in the integration and re-engineering of the thermal design sub-process since it resides within the entire mechanical design process. With these issues in mind, a thermal design sub-process can be re-defined in a manner that has a higher probability of acceptance, thus enabling an integrated mechanical design process. However, the actual implementation is not always problem-free. Experience in applying the thermal design sub-process to actual situations provides the evidence for improvement, but more importantly, for judging the viability and feasibility of the sub-process.

  12. Development of a Reduced-Order Three-Dimensional Flow Model for Thermal Mixing and Stratification Simulation during Reactor Transients

    Energy Technology Data Exchange (ETDEWEB)

    Hu, Rui

    2017-09-03

    Mixing, thermal-stratification, and mass transport phenomena in large pools or enclosures play major roles for the safety of reactor systems. Depending on the fidelity requirement and computational resources, various modeling methods, from the 0-D perfect mixing model to 3-D Computational Fluid Dynamics (CFD) models, are available. Each is associated with its own advantages and shortcomings. It is very desirable to develop an advanced and efficient thermal mixing and stratification modeling capability embedded in a modern system analysis code to improve the accuracy of reactor safety analyses and to reduce modeling uncertainties. An advanced system analysis tool, SAM, is being developed at Argonne National Laboratory for advanced non-LWR reactor safety analysis. While SAM is being developed as a system-level modeling and simulation tool, a reduced-order three-dimensional module is under development to model the multi-dimensional flow and thermal mixing and stratification in large enclosures of reactor systems. This paper provides an overview of the three-dimensional finite element flow model in SAM, including the governing equations, stabilization scheme, and solution methods. Additionally, several verification and validation tests are presented, including lid-driven cavity flow, natural convection inside a cavity, laminar flow in a channel of parallel plates. Based on the comparisons with the analytical solutions and experimental results, it is demonstrated that the developed 3-D fluid model can perform very well for a wide range of flow problems.

  13. Thermal comfort of seated occupants in rooms with personalized ventilation combined with mixing or displacement ventilation

    DEFF Research Database (Denmark)

    Forejt, L.; Melikov, Arsen Krikor; Cermak, Radim

    2004-01-01

    The performance of two personalized ventilation systems combined with mixing or displacement ventilation was studied under different conditions in regard to thermal comfort of seated occupants. The cooling performance of personalized ventilation was found to be independent of room air distribution...

  14. Effect of thermal processing methods on the proximate composition ...

    African Journals Online (AJOL)

    The nutritive value of raw and thermal processed castor oil seed (Ricinus communis) was investigated using the following parameters; proximate composition, gross energy, mineral constituents and ricin content. Three thermal processing methods; toasting, boiling and soaking-and-boiling were used in the processing of the ...

  15. Exploring streamwater mixing dynamics via handheld thermal infrared imagery

    NARCIS (Netherlands)

    Antonelli, Marta; Klaus, Julian; Smettem, Keith; Teuling, Ryan; Pfister, Laurent

    2017-01-01

    Stream confluences are important hotspots of aquatic ecological processes. Water mixing dynamics at stream confluences influence physio-chemical characteristics of the stream as well as sediment mobilisation and pollutant dispersal. In this study, we investigated the potential for handheld

  16. Thermal stir welding process

    Science.gov (United States)

    Ding, R. Jeffrey (Inventor)

    2012-01-01

    A welding method is provided for forming a weld joint between first and second elements of a workpiece. The method includes heating the first and second elements to form an interface of material in a plasticized or melted state interface between the elements. The interface material is then allowed to cool to a plasticized state if previously in a melted state. The interface material, while in the plasticized state, is then mixed, for example, using a grinding/extruding process, to remove any dendritic-type weld microstructures introduced into the interface material during the heating process.

  17. Thermal food processing: new technologies and quality issues

    National Research Council Canada - National Science Library

    Sun, Da-Wen

    2012-01-01

    .... Part I, Modeling of Thermal Food Processes, discusses the thermal physical properties of foods, recent developments in heat and mass transfer, innovative modeling techniques including artificial...

  18. Alternative oxidation technologies for organic mixed waste

    International Nuclear Information System (INIS)

    Borduin, L.C.; Fewell, T.

    1998-01-01

    The Mixed Waste Focus Area (MWFA) is currently supporting the development and demonstration of several alternative oxidation technology (AOT) processes for treatment of combustible mixed low-level wastes. AOTs have been defined as technologies that destroy organic material without using open-flame reactions. AOTs include both thermal and nonthermal processes that oxidize organic wastes but operate under significantly different physical and chemical conditions than incinerators. Nonthermal processes currently being studied include Delphi DETOX and acid digestion at the Savannah River Site (SRS), and direct chemical oxidation at Lawrence Livermore National Laboratory (LLNL). All three technologies are at advanced stages of development or are entering the demonstration phase. Nonflame thermal processes include catalytic chemical oxidation, which is being developed and deployed at Lawrence Berkeley National Laboratory (LBNL), and steam reforming, a commercial process being supported by the Department of Energy (DOE). Although testing is complete on some AOT technologies, most require additional support to complete some or all of the identified development objectives. Brief descriptions, status, and planned paths forward for each of the technologies are presented

  19. Development of a higher-order finite volume method for simulation of thermal oil recovery process using moving mesh strategy

    Energy Technology Data Exchange (ETDEWEB)

    Ahmadi, M. [Heriot Watt Univ., Edinburgh (United Kingdom)

    2008-10-15

    This paper described a project in which a higher order up-winding scheme was used to solve mass/energy conservation equations for simulating steam flood processes in an oil reservoir. Thermal recovery processes are among the most complex because they require a detailed accounting of thermal energy and chemical reaction kinetics. The numerical simulation of thermal recovery processes involves localized phenomena such as saturation and temperatures fronts due to hyperbolic features of governing conservation laws. A second order accurate FV method that was improved by a moving mesh strategy was used to adjust for moving coordinates on a finely gridded domain. The Finite volume method was used and the problem of steam injection was then tested using derived solution frameworks on both mixed and moving coordinates. The benefits of using a higher-order Godunov solver instead of lower-order ones were qualified. This second order correction resulted in better resolution on moving features. Preferences of higher-order solvers over lower-order ones in terms of shock capturing is under further investigation. It was concluded that although this simulation study was limited to steam flooding processes, the newly presented approach may be suitable to other enhanced oil recovery processes such as VAPEX, SAGD and in situ combustion processes. 23 refs., 28 figs.

  20. Thermal Plasma decomposition of fluoriated greenhouse gases

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Soo Seok; Watanabe, Takayuki [Tokyo Institute of Technology, Yokohama (Japan); Park, Dong Wha [Inha University, Incheon (Korea, Republic of)

    2012-02-15

    Fluorinated compounds mainly used in the semiconductor industry are potent greenhouse gases. Recently, thermal plasma gas scrubbers have been gradually replacing conventional burn-wet type gas scrubbers which are based on the combustion of fossil fuels because high conversion efficiency and control of byproduct generation are achievable in chemically reactive high temperature thermal plasma. Chemical equilibrium composition at high temperature and numerical analysis on a complex thermal flow in the thermal plasma decomposition system are used to predict the process of thermal decomposition of fluorinated gas. In order to increase economic feasibility of the thermal plasma decomposition process, increase of thermal efficiency of the plasma torch and enhancement of gas mixing between the thermal plasma jet and waste gas are discussed. In addition, noble thermal plasma systems to be applied in the thermal plasma gas treatment are introduced in the present paper.

  1. Properties of frozen dairy desserts processed by microfluidization of their mixes.

    Science.gov (United States)

    Olson, D W; White, C H; Watson, C E

    2003-04-01

    Sensory properties and rate of meltdown of nonfat (0% fat) and low-fat (2% fat) vanilla ice creams processed either by conventional valve homogenization or microfluidization of their mixes were compared with each other and to ice cream (10% fat) processed by conventional valve homogenization. Mixes for frozen dairy desserts containing 0, 2, and 10% fat were manufactured. Some of the nonfat and low-fat ice cream mixes were processed by microfluidization at 50, 100, 150, and 200 MPa, and the remaining nonfat and low-fat ice cream mixes and all of the ice cream mix were processed by conventional valve homogenization at 13.8 MPa, first stage, and 3.4 MPa, second stage. The finished frozen and hardened products were evaluated at d 1 and 45 for meltdown rate and for flavor and body and texture by preference testing. Nonfat and low-fat ice creams that usually had a slower meltdown were produced when processing their mixes by microfluidization instead of by conventional valve homogenization. Sensory scores for the ice cream were significantly higher than sensory scores for the nonfat and low-fat ice creams, but the sensory scores for the conventional valve homogenized controls for the nonfat ice cream and low-fat ice cream were not significantly different from the sensory scores for the nonfat ice cream and low-fat ice cream processed by microfluidization of the mixes, respectively. Microfluidization produced nonfat and low-fat ice creams that usually had a slower meltdown without affecting sensory properties.

  2. Dynamic water vapor sorption on Mg(Ga{sup 3+})O mixed oxides: Analysis of the LDH thermal regeneration process

    Energy Technology Data Exchange (ETDEWEB)

    Bedolla-Valdez, Zaira I.; Ramirez-Solis, Sergio [Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito exterior s/n, Cd. Universitaria, Del. Coyoacán, CP 04510, México, DF (Mexico); Prince, Julia [Instituto Mexicano del Petróleo, Eje Central 152, CP 07730, México, DF (Mexico); Lima, Enrique [Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito exterior s/n, Cd. Universitaria, Del. Coyoacán, CP 04510, México, DF (Mexico); Pfeiffer, Heriberto, E-mail: pfeiffer@iim.unam.mx [Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito exterior s/n, Cd. Universitaria, Del. Coyoacán, CP 04510, México, DF (Mexico); Valente, Jaime S. [Instituto Mexicano del Petróleo, Eje Central 152, CP 07730, México, DF (Mexico)

    2013-02-10

    Highlights: ► Ga-LDH regeneration process was analyzed varying the relative humidity. ► Ga-LDH rehydrates faster than aluminum content LDH materials. ► Gallium seems to favor diffusion processeses during LDH regeneration. - Abstract: The rehydration process of the calcined MgGa-layered double hydroxides (Ga-LDH) was analyzed at different temperatures and relative humidities. Results clearly showed that Ga-LDH sample presented an excellent regeneration kinetic, in comparison to the aluminum typical one. Different techniques such as X-ray diffraction, infrared spectroscopy and thermal analysis were used to elucidate the presented results.

  3. Fossilization processes in siliceous thermal springs: trends in preservation along thermal gradients

    Science.gov (United States)

    Cady, S. L.; Farmer, J. D.

    1996-01-01

    To enhance our ability to extract palaeobiological and palaeoenvironmental information from ancient thermal spring deposits, we have studied the processes responsible for the development and preservation of stromatolites in modern subaerial thermal spring systems in Yellowstone National Park (USA). We investigated specimens collected from silica-depositing thermal springs along the thermal gradient using petrographic techniques and scanning electron microscopy. Although it is known that thermophilic cyanobacteria control the morphogenesis of thermal spring stromatolites below 73 degrees C, we have found that biofilms which contain filamentous thermophiles contribute to the microstructural development of subaerial geyserites that occur along the inner rims of thermal spring pools and geyser effluents. Biofilms intermittently colonize the surfaces of subaerial geyserites and provide a favoured substrate for opaline silica precipitation. We have also found that the preservation of biotically produced microfabrics of thermal spring sinters reflects dynamic balances between rates of population growth, decomposition of organic matter, silica deposition and early diagenesis. Major trends in preservation of thermophilic organisms along the thermal gradient are defined by differences in the mode of fossilization, including replacement, encrustation and permineralization.

  4. One-Dimensional Convective Thermal Evolution Calculation Using a Modified Mixing Length Theory: Application to Saturnian Icy Satellites

    Science.gov (United States)

    Kamata, Shunichi

    2018-01-01

    Solid-state thermal convection plays a major role in the thermal evolution of solid planetary bodies. Solving the equation system for thermal evolution considering convection requires 2-D or 3-D modeling, resulting in large calculation costs. A 1-D calculation scheme based on mixing length theory (MLT) requires a much lower calculation cost and is suitable for parameter studies. A major concern for the MLT scheme is its accuracy due to a lack of detailed comparisons with higher dimensional schemes. In this study, I quantify its accuracy via comparisons of thermal profiles obtained by 1-D MLT and 3-D numerical schemes. To improve the accuracy, I propose a new definition of the mixing length (l), which is a parameter controlling the efficiency of heat transportation due to convection, for a bottom-heated convective layer. Adopting this new definition of l, I investigate the thermal evolution of Saturnian icy satellites, Dione and Enceladus, under a wide variety of parameter conditions. Calculation results indicate that each satellite requires several tens of GW of heat to possess a thick global subsurface ocean suggested from geophysical analyses. Dynamical tides may be able to account for such an amount of heat, though the reference viscosity of Dione's ice and the ammonia content of Dione's ocean need to be very high. Otherwise, a thick global ocean in Dione cannot be maintained, implying that its shell is not in a minimum stress state.

  5. Thermal and solutal stratification in mixed convection three-dimensional flow of an Oldroyd-B nanofluid

    Directory of Open Access Journals (Sweden)

    Tasawar Hayat

    Full Text Available This paper investigates the double stratified effects in mixed convection three-dimensional flow of an Oldroyd-B nanofluid. The flow is due to a bidirectional stretching surface. Mathematical analysis is carried out using the temperature and concentration stratification effects. Brownian motion, thermophoresis and chemical reaction effects are also considered. The governing nonlinear boundary layer equations are first converted into the dimensionless ordinary differential equations and then solved for the convergent series solutions of velocity, temperature and nanoparticles concentration. Convergence analysis of the obtained series solutions is also checked and verified. Effects of various emerging parameters are studied in details. Numerical values of local Nusselt and Sherwood numbers are tabulated and analyzed. It is noticed that the impact of mixed convection parameter on temperature and nanoparticles concentration is quite similar. Both temperature and nanoparticles concentration are reduced for larger mixed convection parameter. Keywords: Three-dimensional flow, Oldroyd-B fluid, Nanoparticles, Mixed convection, Thermal and solutal stratification, Chemically reactive species

  6. Harvesting thermal fluctuations: Activation process induced by a nonlinear chain in thermal equilibrium

    International Nuclear Information System (INIS)

    Reigada, Ramon; Sarmiento, Antonio; Romero, Aldo H.; Sancho, J. M.; Lindenberg, Katja

    2000-01-01

    We present a model in which the immediate environment of a bistable system is a molecular chain which in turn is connected to a thermal environment of the Langevin form. The molecular chain consists of masses connected by harmonic or by anharmonic springs. The distribution, intensity, and mobility of thermal fluctuations in these chains is strongly dependent on the nature of the springs and leads to different transition dynamics for the activated process. Thus, all else (temperature, damping, coupling parameters between the chain and the bistable system) being the same, the hard chain may provide an environment described as diffusion-limited and more effective in the activation process, while the soft chain may provide an environment described as energy-limited and less effective. The importance of a detailed understanding of the thermal environment toward the understanding of the activation process itself is thus highlighted. (c) 2000 American Institute of Physics

  7. A Controlled Agitation Process for Improving Quality of Canned Green Beans during Agitation Thermal Processing.

    Science.gov (United States)

    Singh, Anika; Pratap Singh, Anubhav; Ramaswamy, Hosahalli S

    2016-06-01

    This work introduces the concept of a controlled agitation thermal process to reduce quality damage in liquid-particulate products during agitation thermal processing. Reciprocating agitation thermal processing (RA-TP) was used as the agitation thermal process. In order to reduce the impact of agitation, a new concept of "stopping agitations after sufficient development of cold-spot temperature" was proposed. Green beans were processed in No. 2 (307×409) cans filled with liquids of various consistency (0% to 2% CMC) at various frequencies (1 to 3 Hz) of RA-TP using a full-factorial design and heat penetration results were collected. Corresponding operator's process time to impart a 10-min process lethality (Fo ) and agitation time (AT) were calculated using heat penetration results. Accordingly, products were processed again by stopping agitations as per 3 agitation regimes, namely; full time agitation, equilibration time agitation, and partial time agitation. Processed products were photographed and tested for visual quality, color, texture, breakage of green beans, turbidity, and percentage of insoluble solids in can liquid. Results showed that stopping agitations after sufficient development of cold-spot temperatures is an effective way of reducing product damages caused by agitation (for example, breakage of beans and its leaching into liquid). Agitations till one-log temperature difference gave best color, texture and visual product quality for low-viscosity liquid-particulate mixture and extended agitations till equilibration time was best for high-viscosity products. Thus, it was shown that a controlled agitation thermal process is more effective in obtaining high product quality as compared to a regular agitation thermal process. © 2016 Institute of Food Technologists®

  8. Analysis of the mixing processes in the subtropical Advancetown Lake, Australia

    Science.gov (United States)

    Bertone, Edoardo; Stewart, Rodney A.; Zhang, Hong; O'Halloran, Kelvin

    2015-03-01

    This paper presents an extensive investigation of the mixing processes occurring in the subtropical monomictic Advancetown Lake, which is the main water body supplying the Gold Coast City in Australia. Meteorological, chemical and physical data were collected from weather stations, laboratory analysis of grab samples and an in-situ Vertical Profiling System (VPS), for the period 2008-2012. This comprehensive, high frequency dataset was utilised to develop a one-dimensional model of the vertical transport and mixing processes occurring along the water column. Multivariate analysis revealed that air temperature and rain forecasts enabled a reliable prediction of the strength of the lake stratification. Vertical diffusion is the main process driving vertical mixing, particularly during winter circulation. However, a high reservoir volume and warm winters can limit the degree of winter mixing, causing only partial circulation to occur, as was the case in 2013. This research study provides a comprehensive approach for understanding and predicting mixing processes for similar lakes, whenever high-frequency data are available from VPS or other autonomous water monitoring systems.

  9. Dressed Gain from the Parametrically Amplified Four-Wave Mixing Process in an Atomic Vapor

    Science.gov (United States)

    Zhang, Zhaoyang; Wen, Feng; Che, Junling; Zhang, Dan; Li, Changbiao; Zhang, Yanpeng; Xiao, Min

    2015-10-01

    With a forward cone emitting from the strong pump laser in a thermal rubidium atomic vapor, we investigate the non-degenerate parametrically amplified four-wave mixing (PA-FWM) process with dressing effects in a three-level “double-Λ” configuration both theoretically and experimentally. By seeding a weak probe field into the Stokes or anti-Stokes channel of the FWM, the gain processes are generated in the bright twin beams which are called conjugate and probe beams, respectively. However, the strong dressing effect of the pump beam will dramatically affect the gain factors both in the probe and conjugate channels, and can inevitably impose an influence on the quantum effects such as entangled degree and the quantum noise reduction between the two channels. We systematically investigate the intensity evolution of the dressed gain processes by manipulating the atomic density, the Rabi frequency and the frequency detuning. Such dressing effects are also visually evidenced by the observation of Autler-Townes splitting of the gain peaks. The investigation can contribute to the development of quantum information processing and quantum communications.

  10. Perspective of Micro Process Engineering for Thermal Food Treatment.

    Science.gov (United States)

    Mathys, Alexander

    2018-01-01

    Micro process engineering as a process synthesis and intensification tool enables an ultra-short thermal treatment of foods within milliseconds (ms) using very high surface-area-to-volume ratios. The innovative application of ultra-short pasteurization and sterilization at high temperatures, but with holding times within the range of ms would allow the preservation of liquid foods with higher qualities, thereby avoiding many unwanted reactions with different temperature-time characteristics. Process challenges, such as fouling, clogging, and potential temperature gradients during such conditions need to be assessed on a case by case basis and optimized accordingly. Owing to the modularity, flexibility, and continuous operation of micro process engineering, thermal processes from the lab to the pilot and industrial scales can be more effectively upscaled. A case study on thermal inactivation demonstrated the feasibility of transferring lab results to the pilot scale. It was shown that micro process engineering applications in thermal food treatment may be relevant to both research and industrial operations. Scaling of micro structured devices is made possible through the use of numbering-up approaches; however, reduced investment costs and a hygienic design must be assured.

  11. Mixing of Process Heels, Process Solutions and Recycle Streams: Small-Scale Simulant

    International Nuclear Information System (INIS)

    Kaplan, D.I.

    2001-01-01

    The overall objective of this small-scale simulant mixing study was to identify the processes within the Hanford Site River Protection Project - Waste Treatment Plant (RPP-WTP) that may generate precipitates and to identify the types of precipitates formed. This information can be used to identify where mixtures of various solutions will cause precipitation of solids, potentially causing operational problems such as fouling equipment or increasing the amount of High Level Waste glass produced. Having this information will help guide protocols for flushing or draining tanks, mixing internal recycle streams, and mixing waste tank supernates. This report contains the discussion and thermodynamic chemical speciation modeling of the raw data

  12. A hydro-thermo-mechanics analyze of the thermal fatigue in the mixing tee junction

    International Nuclear Information System (INIS)

    Gourdin, C.; Chapuliot, S.; Magnaud, J.P.; Payen, T.

    2003-01-01

    Work presented here, has been achieved at Cea, and is related to the comprehension of the mechanisms leading to cracking under thermal loading in the zones of mixing. The main objective of this work is to analyze, by computation, the thermal loading induced by the turbulent mixing following a tee junction and to explain how it can create cracking, from the internal skin of the component to a leakage, as it was observed in Civaux Power Plant in 1998. The phenomenon is still today not completely understood. One of the principal reasons to this partial incomprehension undoubtedly resides in the multi-field aspect of the loading and of the associated damage, utilizing three different and complementary scientific disciplines: thermohydraulics, thermomechanics and material science. The presentation proposed here, consists in connecting the analyses resulting from these various fields. The first part concentrates on thermohydraulics simulations. The choice of an adequate modeling is discussed on the basis of observed cracking in order to highlight phenomena of large scale beats, which are supposed one of the major causes leading to the failure of the structures. The second part deals with the use of the temperature fields obtained in the first part in order to carry out thermomechanical simulations. All these simulations are 3-dimensional and represent the complex geometry of Civaux RRA piping line, including a tee junction and elbows, water flow velocity. Mean and temperatures variations, mean and stresses variations are also presented. As final results make it possible to determine a map of the damage associated with these complex thermal loading. (authors)

  13. Processing of baby food using pressure-assisted thermal sterilization (PATS) and comparison with thermal treatment

    Science.gov (United States)

    Wang, Yubin; Ismail, Marliya; Farid, Mohammed

    2017-10-01

    Currently baby food is sterilized using retort processing that gives an extended shelf life. However, this type of heat processing leads to reduction of organoleptic and nutrition value. Alternatively, the combination of pressure and heat could be used to achieve sterilization at reduced temperatures. This study investigates the potential of pressure-assisted thermal sterilization (PATS) technology for baby food sterilization. Here, baby food (apple puree), inoculated with Bacillus subtilis spores was treated using PATS at different operating temperatures, pressures and times and was compared with thermal only treatment. The results revealed that the decimal reduction time of B. subtilis in PATS treatment was lower than that of thermal only treatment. At a similar spore inactivation, the retention of ascorbic acid of PATS-treated sample was higher than that of thermally treated sample. The results indicated that PATS could be a potential technology for baby food processing while minimizing quality deterioration.

  14. Mixed waste treatment using the ChemChar thermolytic detoxification technique

    Energy Technology Data Exchange (ETDEWEB)

    Kuchynka, D. [Mirage Systems, Sunnyvale, CA (United States)

    1995-10-01

    The diversity of mixed waste matrices contained at Department of Energy sites that require treatment preclude a single, universal treatment technology capable of handling sludges, solids, heterogeneous debris, aqueous and organic liquids and soils. This report describes the ChemChar thermolytic detoxification process. The process is a thermal, chemically reductive technology that converts the organic portion of mixed wastes to a synthesis gas, while simultaneously absorbing volatile inorganics on a carbon-based char.

  15. Mixed waste characterization, treatment, and disposal focus area. Technology summary

    International Nuclear Information System (INIS)

    1995-06-01

    This paper presents details about the technology development programs of the Department of Energy. In this document, waste characterization, thermal treatment processes, non-thermal treatment processes, effluent monitors and controls, development of on-site innovative technologies, and DOE business opportunities are applied to environmental restoration. The focus areas for research are: contaminant plume containment and remediation; mixed waste characterization, treatment, and disposal; high-level waste tank remediation; landfill stabilization; and decontamination and decommissioning

  16. Mixed waste characterization, treatment, and disposal focus area. Technology summary

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-06-01

    This paper presents details about the technology development programs of the Department of Energy. In this document, waste characterization, thermal treatment processes, non-thermal treatment processes, effluent monitors and controls, development of on-site innovative technologies, and DOE business opportunities are applied to environmental restoration. The focus areas for research are: contaminant plume containment and remediation; mixed waste characterization, treatment, and disposal; high-level waste tank remediation; landfill stabilization; and decontamination and decommissioning.

  17. Process for fabricating mixed-oxide powders

    International Nuclear Information System (INIS)

    Elmaleh, D.; Giraudel, A.

    1975-01-01

    A physical-chemical process for fabricating homogeneous powders suitable for sintering is described. It can be applied to the synthesis of all mixed oxides having mutually compatible and water soluble salts. As a specific example, the fabrication of lead titanate-zirconate powders used to make hot pressed ceramics is described. These ceramics show improved piezoelectric properties [fr

  18. A demonstration of applying ATS thermal screw technology to the processing of separated construction and other waste materials

    Energy Technology Data Exchange (ETDEWEB)

    Jones, D.; Golan, A.; Bosschieter, H.A.

    1991-06-01

    A demonstration was carried out by Spider Recycling, a waste haulage company, to determine how to sort, process and recycle or reuse waste disposed of by the company, using a new processing system based on the ATS thermal screw press technology. Selected loads of waste totalling one thousand tonnes from construction, sawmill, landscape and tire industries located around greater Toronto were delivered to a pilot separation and processing site and separated into piles of similar material such as wood, drywall and tires. The separated piles were drawn on as feedstock for processing through the ATS thermal screw press system to produce useable forms of product and raw material. The applications included: turning wood waste into firelogs or wood fuel; yard waste into mulch; waste drywall into gypsum powder; tires into crumb rubber; asphalt shingles into a bitumix; and mixed garbage into densified logs or flakes. Wide ranges of throughput were found depending on the material processed, material size, density, moisture content and model of the ATS thermal screw press used. It was shown that it is practical to separate selected wastes from industry and process them with the ATS machine, and that the system could probably offer recycling and reuse solutions to separable waste where product markets are available and in some cases where the operation could collect the estimated $100/tonne tipping fees available in southern Ontario. 37 figs., 20 tabs.

  19. Thermoreflectance spectroscopy—Analysis of thermal processes in semiconductor lasers

    Science.gov (United States)

    Pierścińska, D.

    2018-01-01

    This review focuses on theoretical foundations, experimental implementation and an overview of experimental results of the thermoreflectance spectroscopy as a powerful technique for temperature monitoring and analysis of thermal processes in semiconductor lasers. This is an optical, non-contact, high spatial resolution technique providing high temperature resolution and mapping capabilities. Thermoreflectance is a thermometric technique based on measuring of relative change of reflectivity of the surface of laser facet, which provides thermal images useful in hot spot detection and reliability studies. In this paper, principles and experimental implementation of the technique as a thermography tool is discussed. Some exemplary applications of TR to various types of lasers are presented, proving that thermoreflectance technique provides new insight into heat management problems in semiconductor lasers and in particular, that it allows studying thermal degradation processes occurring at laser facets. Additionally, thermal processes and basic mechanisms of degradation of the semiconductor laser are discussed.

  20. 7 CFR 58.619 - Mix processing room.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 3 2010-01-01 2010-01-01 false Mix processing room. 58.619 Section 58.619 Agriculture Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (Standards, Inspections, Marketing Practices), DEPARTMENT OF AGRICULTURE (CONTINUED) REGULATIONS AND STANDARDS UNDER THE...

  1. Stellar Evolution with Rotation: Mixing Processes in AGB Stars

    Science.gov (United States)

    Driebe, T.; Blöcker, T.

    We included diffusive angular momentum transport and rotationally induced mixing processes in our stellar evolution code and studied the influence of rotation on the evolution of intermediate mass stars (M*=2dots6 Msolar) towards and along the asymptotic giant branch (AGB). The calculations start in the fully convective pre-main sequence phase and the initial angular momentu m was adjusted such that on the zero-age main sequence vrot=200 km/ s is achieved. The diffusion coefficients for the five rotational instabilities considered (dynamical shear, secular shear, Eddington-Sweet (ES) circulation, Solberg-Høiland-instability and Goldreich-Schubert-Fricke (GSF) instability) were adopted from Heger et al. (2000, ApJ 528, 368). Mixing efficiency and sensitivity of these processes against molecular weight gradients have been determined by calibration of the main sequence width. In this study we focus on the abundance evolution of carbon. On the one hand, the surface abundance ratios of 12C/13C a nd 12C/16O at the base of the AGB were found to be ≈ 7dots 10 and ≈ 0.1, resp., being a factor of two lower than in non-rotating models. This results from the slow but continuously operating rotationally induced mixing due to the ES-circulation and the GSF-instability during the long main sequence phase. On the other hand, 13C serves as neutron source for interior s-process nucleosynthesis in AGB stars vi a 13C(α,n)16O. Herwig et al. (1997, A&A 324, L81) found that a 13C pocket is forme d in the intershell region of 3 Msolar AGB star if diffusive overshoot is considered. Our calculations show, that mixing processes due to rotation open an alternative channel for the formation of a 13C pocket as found by Langer et al. (1999, A&A 346, L37). Again, ES-circulation and GSF-instability are the predominant rotational mixing processes.

  2. Biomass conversion to hydrocarbon fuels using the MixAlco™ process at a pilot-plant scale

    International Nuclear Information System (INIS)

    Taco Vasquez, Sebastian; Dunkleman, John; Chaudhuri, Swades K.; Bond, Austin; Holtzapple, Mark T.

    2014-01-01

    Texas A and M University has built a MixAlco™ pilot plant that converts biomass to hydrocarbons (i.e., jet fuel, gasoline) using the following steps: fermentation, descumming, dewatering, thermal ketonization, distillation, hydrogenation, and oligomerization. This study describes the pilot plant and reports results from an 11-month production campaign. The focus was to produce sufficient jet fuel to be tested by the U.S. military. Because the scale was relatively small, energy-saving features were not included in the pilot plant. Further, the equipment was operated in a manner to maximize productivity even if yields were low. During the production campaign, a total of 6.015 Mg of shredded paper and 120 kg of chicken manure (dry basis) were fermented to produce 126.5 m 3 of fermentation broth with an average concentration of 12.5 kg m −3 . A total of 1582 kg of carboxylate salts were converted to 587 L of raw ketones, which were distilled and hydrogenated to 470 L of mixed alcohols ranging from C3 to C12. These alcohols, plus 300 L of alcohols made by an industrial partner (Terrabon, Inc.) were shipped to an independent contractor (General Electric) and transformed to jet fuel (∼100 L) and gasoline (∼100 L) byproduct. - Highlights: • We produce hydrocarbons from paper and chicken manure in a pilot-scale production using the MixAlco™ process. • About 100 L of jet fuel were produced for military testing. • High production rates and good product quality were preferred rather than high yields or energy efficiency. • The MixAlco™ process converted successfully lignocellulosic biomass to hydrocarbons and viable for commercial-scale production

  3. Millisecond photo-thermal process on significant improvement of supercapacitor’s performance

    International Nuclear Information System (INIS)

    Wang, Kui; Wang, Jixiao; Wu, Ying; Zhao, Song; Wang, Zhi; Wang, Shichang

    2016-01-01

    Graphical abstract: A high way for charge transfer is created by a millisecond photo-thermal process which could decrease contact resistance among nanomaterials and improve the electrochemical performances. - Highlights: • Improve conductivity among nanomaterials with a millisecond photo-thermal process. • The specific capacitance can increase about 25% with an photo-thermal process. • The circle stability and rate capability can be improved above 10% with photo-thermal process. • Provide a new way that create electron path to improve electrochemical performance. - Abstract: Supercapacitors fabricated with nanomaterials usually have high specific capacitance and excellent performance. However, the small size of nanomaterials renders a considerable limitation of the contact area among nanomaterials, which is harmful to charge carrier transfer. This fact may hinder the development and application of nanomaterials in electrochemical storage systems. Here, a millisecond photo-thermal process was introduced to create a charge carries transfer path to decrease the contact resistance among nanomaterials, and enhance the electrochemical performance of supercapacitors. Polyaniline (PANI) nanowire, as a model nanomaterial, was used to modify electrodes under different photo-thermal process conditions. The modified electrodes were characterized by scanning electronic microscopy (SEM), cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and the results were analysed by equivalent circuit simulation. These results demonstrate that the photo-thermal process can alter the morphology of PANI nanowires, lower the charge transfer resistances and thus improve the performance of electrodes. The specific capacitance increase of the modified electrodes is about 25%. The improvement of the circle stability and rate capability are above 10%. To the best of our knowledge, this is the first attempt on research the effect of photo-thermal process on the conductivity

  4. Relation of the physical and hydrobiological processes of thermal pollution

    International Nuclear Information System (INIS)

    Szolnoky, Cs.

    1981-01-01

    The process of thermal pollution of the rivers is discussed from the point of the living-space of the waters. The effects of fresh water-cooled thermal power stations on components of the biosphere of the rivers are described following the cooling process step-by-step. The characteristics of the thermal pollution of the Danube and Tisza are discussed and the effect of the Paks Nuclear Power Plant on the Danube is estimated. The regulation of the thermal pollution in the form of limiting values is proposed. (R.J.)

  5. Rubber mixing process and its relationship with bound rubber and crosslink density

    Science.gov (United States)

    Hasan, A.; Rochmadi; Sulistyo, H.; Honggokusumo, S.

    2017-06-01

    This research studied the relationship between bound rubber and crosslink density based on rubber mixing process. Bound rubber was obtained after natural rubber was masticated and mixed with rubber chemicals and filler while crosslink density was collected after rubber compound was vulcanized. Four methods are used and each method refers to four ways of incorporating carbon black during mixing. The first method, after rubber was masticated for 5 minutes, the addition of rubber chemicals and filler was done simultaneously. Rubber was masticated for 1 minute and continued mixing of rubber chemicals and filler where mixing was different from first method. This was the second method. The third method was the same as the second method but the filler used N 660 while in the second method N 330. The last method is not the same as the first and second, the rubber is only masticated for 3 minutes and then mixed with filler and followed by rubber chemicals sequentially. The results showed that bound rubber and crosslink density were influenced by mixing and mastication process. Bound rubber dropped and crosslink density was relatively stable in the first three mixing methods for increasing carbon black at the beginning of the mixing process. Bound rubber and crosslink density stated opposite results in the fourth mixing method. The higher the bound rubber the lower the crosslink density. Without regard to mixing methods, there is a non-linear relationship between bound rubber formation and crosslink density determination

  6. Mantle mixing and thermal evolution during Pangaea assembly and breakup

    Science.gov (United States)

    Rudolph, M. L.; Li, M.; Zhong, S.; Manga, M.

    2016-12-01

    Continents insulate the underlying mantle, and it has been suggested that the arrangement of the continents can have a significant effect on sub-continental mantle temperatures. Additionally, the dispersal or agglomeration of continents may affect the efficacy of continental insulation, with some studies suggesting warming of 100K beneath supercontinents. During the most recent supercontinent cycle, Pangaea was encircled by subduction, potentially creating a `curtain' of subducted material that may have prevented mixing of the sub-Pangaea mantle with the sub-Panthalassa mantle. Using 3D spherical shell geometry mantle convection simulations, we quantify the effect of insulation by continents and supercontinents. We explore the differences in model predictions for purely thermal vs. thermochemical convection, and we use tracers to quantify the exchange of material between the sub-oceanic to the sub-continental mantle.

  7. Experimental and numerical investigation of coolant mixing in a model of reactor pressure vessel down-comer and in cold leg inlets

    Directory of Open Access Journals (Sweden)

    Hutli Ezddin

    2017-01-01

    Full Text Available Thermal fatigue and pressurized thermal shock phenomena are the main problems for the reactor pressure vessel and the T-junctions both of them depend on the mixing of the coolant. The mixing process, flow and temperature distribution has been investigated experimentally using particle image velocimetry, laser induced fluorescence, and simulated by CFD tools. The obtained results showed that the ratio of flow rate between the main pipe and the branch pipe has a big influence on the mixing process. The particle image velocimetry/planar laser-induced fluorescence measurements technologies proved to be suitable for the investigation of turbulent mixing in the complicated flow system: both velocity and temperature distribution are important parameters in the determination of thermal fatigue and pressurized thermal shock. Results of the applied these techniques showed that both of them can be used as a good provider for data base and to validate CFD results.

  8. Process simulation and uncertainty analysis of plasma arc mixed waste treatment

    International Nuclear Information System (INIS)

    Ferrada, J.J.; Welch, T.D.

    1994-01-01

    Innovative mixed waste treatment subsystems have been analyzed for performance, risk, and life-cycle cost as part of the U.S. Department of Energy's (DOE)'s Mixed Waste Integrated Program (MWIP) treatment alternatives development and evaluation process. This paper concerns the analysis of mixed waste treatment system performance. Performance systems analysis includes approximate material and energy balances and assessments of operability, effectiveness, and reliability. Preliminary material and energy balances of innovative processes have been analyzed using FLOW, an object-oriented, process simulator for waste management systems under development at Oak Ridge National Laboratory. The preliminary models developed for FLOW provide rough order-of-magnitude calculations useful for sensitivity analysis. The insight gained from early modeling of these technologies approximately will ease the transition to more sophisticated simulators as adequate performance and property data become available. Such models are being developed in ASPEN by DOE's Mixed Waste Treatment Project (MWTP) for baseline and alternative flow sheets based on commercial technologies. One alternative to the baseline developed by the MWIP support groups in plasma arc treatment. This process offers a noticeable reduction in the number of process operations as compared to the baseline process because a plasma arc melter is capable of accepting a wide variety of waste streams as direct inputs (without sorting or preprocessing). This innovative process for treating mixed waste replaces several units from the baseline process and, thus, promises an economic advantage. The performance in the plasma arc furnace will directly affect the quality of the waste form and the requirements of the off-gas treatment units. The ultimate objective of MWIP is to reduce the amount of final waste produced, the cost, and the environmental impact

  9. Intercomparison of personnel dosimetry for thermal neutron dose equivalent in neutron and gamma-ray mixed fields

    International Nuclear Information System (INIS)

    Ogawa, Yoshihiro

    1985-01-01

    In order to consider the problems concerned with personnel dosimetry using film badges and TLDs, an intercomparison of personnel dosimetry, especially dose equivalent responses of personnel dosimeters to thermal neutron, was carried out in five different neutron and gamma-ray mixed fields at KUR and UTR-KINKI from the practical point of view. For the estimation of thermal neutron dose equivalent, it may be concluded that each personnel dosimeter has good performances in the precision, that is, the standard deviations in the measured values by individual dosimeter were within 24 %, and the dose equivalent responses to thermal neutron were almost independent on cadmium ratio and gamma-ray contamination. However, the relative thermal neutron dose equivalent of individual dosimeter normalized to the ICRP recommended value varied considerably and a difference of about 4 times was observed among the dosimeters. From the results obtained, it is suggested that the standardization of calibration factors and procedures is required from the practical point of radiation protection and safety. (author)

  10. Furnace for rapid thermal processing

    NARCIS (Netherlands)

    Roozeboom, F.; Duine, P.A.; Sluis, P. van der

    2001-01-01

    A Method (1) for Rapid Thermal Processing of a wafer (7), wherein the wafer (7) is heated by lamps (9), and the heat radiation is reflected by an optical switching device (15,17) which is in the reflecting state during the heating stage. During the cooling stage of the wafer (7), the heat is

  11. Study on mixing behavior in a tee piping and numerical analyses for evaluation of thermal striping

    International Nuclear Information System (INIS)

    Kamide, H.; Igarashi, M.; Kawashima, S.; Kimura, N.; Hayashi, K.

    2009-01-01

    Water experiments were carried out for thermal hydraulic aspects of thermal striping in a mixing tee, which has main to branch diameter ratio of 3. Detailed temperature and velocity fields were measured by a movable thermocouple tree and particle image velocimetry. Flow patterns in the tee were classified into three groups; wall jet, deflecting jet, and impinging jet, which had their own temperature fluctuation profiles, depending on a momentum ratio between the main and branch pipes. Non-dimensional power spectrum density (PSD) of temperature fluctuation showed a unique profile, when the momentum ratio was identical. Numerical simulation based on finite difference method showed alternative vortex development, like Karman vortex series, behind the jet from the branch pipe in the wall jet case. The prominent frequency of the temperature fluctuation in the calculation was 0.2 of St number based on the branch pipe diameter and in good agreement with the experimental results. Mixing behavior in the tee was characterized by the relatively large vortex structures defined by the diameters and the velocities in the pipes

  12. The Hybrid Treatment Process for treatment of mixed radioactive and hazardous wastes

    International Nuclear Information System (INIS)

    Ross, W.A.; Kindle, C.H.

    1992-04-01

    This paper describes a new process for treating mixed hazardous and radioactive waste, commonly called mixed waste. The process is called the Hybrid Treatment Process (HTP), so named because it is built on the 20 years of experience with vitrification of wastes in melters, and the 12 years of experience with treatment of wastes by the in situ vitrification (ISV) process

  13. Mixing Ventilation. Guide on mixing air distribution design

    DEFF Research Database (Denmark)

    Kandzia, Claudia; Kosonen, Risto; Melikov, Arsen Krikor

    In this guidebook most of the known and used in practice methods for achieving mixing air distribution are discussed. Mixing ventilation has been applied to many different spaces providing fresh air and thermal comfort to the occupants. Today, a design engineer can choose from large selection...

  14. Experimental evaluation of different mixing promoter for nuclear fuel element by means of a new thermal tracing technique

    International Nuclear Information System (INIS)

    Silin, Nicolas; Juanico, Luis; Delmastro, Dario

    2004-01-01

    In this work a new experimental method is used to experimentally evaluate the performance of different appendages promoting the turbulent mixing between the coupled subchannels of nuclear fuel elements.The method used will be introduced in another presentation and consists in the generation and measurement of small thermal traces in the refrigerating water flow between the fuel rods.Because it is suitable for heterogeneous and compact subchannels (as Argentinean fuels) with high water flows in simple and affordable tests at atmospheric pressure, this new method is specially well suited for the design of fuel elements, while it offers advantages over other methods of mixing measurement.The experiments carried out on a small test section proved that the buttons brazed to the fuel rods (similar to the 'turbulence promoters' of the Canflex fuel) had an excellent thermohydraulic performance as compared to different mixing vane designs studied.The thermal traces method developed has shown its potential as a thermohydraulic design tool for the development of advanced nuclear fuels, that eventually incorporate mixing promoter elements. In the case of CARA, and as it includes spacer grids, it could be possible to use them to incorporate these elements without the need of brazing them to the rods (as is the case in Canflex), and therefore without penalizing its integrity [es

  15. The Hybrid Treatment Process for mixed radioactive and hazardous waste treatment

    International Nuclear Information System (INIS)

    Ross, W.A.; Kindle, C.H.

    1992-06-01

    This paper describes a new process for treating mixed hazardous and radioactive waste, commonly called mixed waste. The process is called the Hybrid Treatment Process (HTP), so named because it is built on the 20 years of experience with vitrification of wastes in melters, and the 12 years of experience with treatment of wastes by the in situ vitrification (ISV) process. It also uses techniques from several additional technologies. Mixed wastes are being generated by both the US Department of Energy (DOE) and by commercial sources. The wastes are those that contain both a hazardous waste regulated under the US Environmental Protection Agency's (EPA) Resource, Conservation, and Recovery Act (RCRA) regulations and a radioactive waste with source, special nuclear, or byproduct materials. The dual regulation of the wastes increases the complexity of the treatment, handling, and storage of the waste. The DOE is the largest holder and generator of mixed waste. Its mixed wastes are classified as either high-level, transuranic (TRU), or low-level waste (LLW). High-level mixed wastes will be treated in vitrification plants. Transuranic wastes may be disposed of without treatment by obtaining a no-migration variance from the EPA. Lowlevel wastes, however, will require treatment, but treatment systems with sufficient capacity are not yet available to DOE. Various facilities are being proposed for the treatment of low-level waste. The concept described in this paper represents one option for establishing that treatment capacity

  16. Resonant four-wave mixing processes in xenon

    International Nuclear Information System (INIS)

    Yiu, Y.M.; Bonin, K.D.; McIlrath, T.J.

    1982-01-01

    Two-photon resonantly enhanced four-wave mixing processes in xenon involving the intermediate states were utilized to generate coherent VUV radiation at several discrete wavelengths between 125.9 nm and 101.8 nm. Maximum efficiencies of the order of 10-4 were achieved. The use of these processes for producing tunable VUV output with Xe is given and generation of tunable VUV using two-photon resonances in other rare gases is discussed

  17. ELECTRON IRRADIATION AND THERMAL PROCESSING OF MIXED-ICES OF POTENTIAL RELEVANCE TO JUPITER TROJAN ASTEROIDS

    International Nuclear Information System (INIS)

    Mahjoub, Ahmed; Poston, Michael J.; Hand, Kevin P.; Hodyss, Robert; Blacksberg, Jordana; Carlson, Robert W.; Ehlmann, Bethany L.; Choukroun, Mathieu; Brown, Michael E.; Eiler, John M.

    2016-01-01

    In this work we explore the chemistry that occurs during the irradiation of ice mixtures on planetary surfaces, with the goal of linking the presence of specific chemical compounds to their formation locations in the solar system and subsequent processing by later migration inward. We focus on the outer solar system and the chemical differences for ice mixtures inside and outside the stability line for H 2 S. We perform a set of experiments to explore the hypothesis advanced by Wong and Brown that links the color bimodality in Jupiter's Trojans to the presence of H 2 S in the surface of their precursors. Non-thermal (10 keV electron irradiation) and thermally driven chemistry of CH 3 OH–NH 3 –H 2 O (“without H 2 S”) and H 2 S–CH 3 OH–NH 3 –H 2 O (“with H 2 S”) ices were examined. Mid-IR analyses of ice and mass spectrometry monitoring of the volatiles released during heating show a rich chemistry in both of the ice mixtures. The “with H 2 S” mixture experiment shows a rapid consumption of H 2 S molecules and production of OCS molecules after a few hours of irradiation. The heating of the irradiated “with H 2 S” mixture to temperatures above 120 K leads to the appearance of new infrared bands that we provisionally assign to SO 2 and CS. We show that radiolysis products are stable under the temperature and irradiation conditions of Jupiter Trojan asteroids. This makes them suitable target molecules for potential future missions as well as telescope observations with a high signal-to-noise ratio. We also suggest the consideration of sulfur chemistry in the theoretical modeling aimed at understanding the chemical composition of Trojans and KOBs

  18. Monitoring non-thermal plasma processes for nanoparticle synthesis

    Science.gov (United States)

    Mangolini, Lorenzo

    2017-09-01

    Process characterization tools have played a crucial role in the investigation of dusty plasmas. The presence of dust in certain non-thermal plasma processes was first detected by laser light scattering measurements. Techniques like laser induced particle explosive evaporation and ion mass spectrometry have provided the experimental evidence necessary for the development of the theory of particle nucleation in silane-containing non-thermal plasmas. This review provides first a summary of these early efforts, and then discusses recent investigations using in situ characterization techniques to understand the interaction between nanoparticles and plasmas. The advancement of such monitoring techniques is necessary to fully develop the potential of non-thermal plasmas as unique materials synthesis and processing platforms. At the same time, the strong coupling between materials and plasma properties suggest that it is also necessary to advance techniques for the measurement of plasma properties while in presence of dust. Recent progress in this area will be discussed.

  19. Technical guide to thermal processes

    International Nuclear Information System (INIS)

    Gosse, J.

    1986-01-01

    This book is an attempt to present the necessary formulae and numerical data for research programs. The most recent data have been used wherever possible. The work is not limited merely to statements of thermal laws; emphasis has been given to the important thermodynamic ideas and to the thermophysical properties of the working fluids. It discusses the thermodynamic concepts which govern the amount of energy transferred to, or from, a system undergoing any process as well as those concepts which allow rates of heat transfer to be predicted. In the same way, mass, momentum and energy balances are presented in a single section to emphasize that the three balances must always be considered together in the analysis of a system. It has been necessary to select the information to be presented in order to provide the essential ideas of thermal analysis. This technical guide summarises the fundamental laws and the experimental data on which the engineer can base his methods of calculation in order to provide an optimum thermal design

  20. Mixed Wastes Vitrification by Transferred Plasma

    International Nuclear Information System (INIS)

    Tapia-Fabela, J.; Pacheco-Pacheco, M.; Pacheco-Sotelo, J.; Torres-Reyes, C.; Valdivia-Barrientos, R.; Benitez-Read, J.; Lopez-Callejas, R.; Ramos-Flores, F.; Boshle, S.; Zissis, G.

    2007-01-01

    Thermal plasma technology provides a stable and long term treatment of mixed wastes through vitrification processes. In this work, a transferred plasma system was realized to vitrify mixed wastes, taking advantage of its high power density, enthalpy and chemical reactivity as well as its rapid quenching and high operation temperatures. To characterize the plasma discharge, a temperature diagnostic is realized by means of optical emission spectroscopy (OES). To typify the morphological structure of the wastes samples, scanning electron microscopy (SEM), and X-ray diffraction (XRD) techniques were applied before and after the plasma treatment

  1. The direct incorporation of micro-encapsulated phase change materials in the concrete mixing process

    NARCIS (Netherlands)

    Hunger, M.; Entrop, A.G.; Mandilaras, I.; Brouwers, H.J.H.; Founti, M.; Durmisevic, E.

    2009-01-01

    The present study refers to a set of tests using different amounts of microencapsulated PCM directly mixed into self-compacting concrete. This SCC is investigated regarding its fresh and hardened properties. It will be shown that increasing PCM amounts lead to lower thermal conductivity and

  2. Treatability studies for polyethylene encapsulation of INEL low-level mixed wastes. Final report

    International Nuclear Information System (INIS)

    Lageraaen, P.R.; Patel, B.R.; Kalb, P.D.; Adams, J.W.

    1995-10-01

    Treatability studies for polyethylene encapsulation of Idaho National Engineering Laboratory (INEL) low-level mixed wastes were conducted at Brookhaven National Laboratory. The treatability work, which included thermal screening and/or processibility testing, was performed on priority candidate wastes identified by INEL to determine the applicability of polyethylene encapsulation for the solidification and stabilization of these mixed wastes. The candidate wastes selected for this preliminary study were Eutectic Salts, Ion Exchange Resins, Activated Carbons, Freon Contaminated Rags, TAN TURCO Decon 4502, ICPP Sodium Bearing Liquid Waste, and HTRE-3 Acid Spill Clean-up. Thermal screening was conducted for some of these wastes to determine the thermal stability of the wastes under expected pretreatment and processing conditions. Processibility testing to determine whether the wastes were amenable to extrusion processing included monitoring feed consistency, extruder output consistency, waste production homogeneity, and waste form performance. Processing parameters were not optimized within the scope of this study. However, based on the treatability results, polyethylene encapsulation does appear applicable as a primary or secondary treatment for most of these wastes

  3. Carotenes in processed tomato after thermal treatment

    NARCIS (Netherlands)

    Luterotti, S.; Bicanic, D.D.; Markovic, K.; Franko, M.

    2015-01-01

    This report adds to the ongoing vivid dispute on the fate of carotenes in tomato upon thermal processing. Although many papers dealing with changes in the raw tomatoes during industrial treatment have already appeared, data on the fate of finished, processed tomato products when they are

  4. Thermal process of an air column

    International Nuclear Information System (INIS)

    Lee, F.T.

    1994-01-01

    Thermal process of a hot air column is discussed based on laws of thermodynamics. The kinetic motion of the air mass in the column can be used as a power generator. Alternatively, the column can also function as a exhaust/cooler

  5. Thermal performance of fresh mixed-oxide fuel in a fast flux LMR [liquid metal reactor

    International Nuclear Information System (INIS)

    Ethridge, J.L.; Baker, R.B.

    1985-01-01

    A test was designed and irradiated to provide power-to-melt (heat generation rate necessary to initiate centerline fuel melting) data for fresh mixed-oxide UO 2 -PuO 2 fuel irradiated in a fast neutron flux under prototypic liquid metal reactor (LMR) conditions. The fuel pin parameters were selected to envelope allowable fabrication ranges and address mass production of LMR fuel using sintered-to-size techniques. The test included fuel pins with variations in fabrication technique, pellet density, fuel-to-cladding gap, Pu concentration, and fuel oxygen-to-metal ratios. The resulting data base has reestablished the expected power-to-melt in mixed-oxide fuels during initial reactor startup when the fuel temperatures are expected to be the highest. Calibration of heat transfer models of fuel pin performance codes with these data are providing more accurate capability for predicting steady-state thermal behavior of current and future mixed-oxide LMR fuels

  6. Recent developments in numerical simulation techniques of thermal recovery processes

    Energy Technology Data Exchange (ETDEWEB)

    Tamim, M. [Bangladesh University of Engineering and Technology, Bangladesh (Bangladesh); Abou-Kassem, J.H. [Chemical and Petroleum Engineering Department, UAE University, Al-Ain 17555 (United Arab Emirates); Farouq Ali, S.M. [University of Alberta, Alberta (Canada)

    2000-05-01

    Numerical simulation of thermal processes (steam flooding, steam stimulation, SAGD, in-situ combustion, electrical heating, etc.) is an integral part of a thermal project design. The general tendency in the last 10 years has been to use commercial simulators. During the last decade, only a few new models have been reported in the literature. More work has been done to modify and refine solutions to existing problems to improve the efficiency of simulators. The paper discusses some of the recent developments in simulation techniques of thermal processes such as grid refinement, grid orientation, effect of temperature on relative permeability, mathematical models, and solution methods. The various aspects of simulation discussed here promote better understanding of the problems encountered in the simulation of thermal processes and will be of value to both simulator users and developers.

  7. Probing the heat sources during thermal runaway process by thermal analysis of different battery chemistries

    Science.gov (United States)

    Zheng, Siqi; Wang, Li; Feng, Xuning; He, Xiangming

    2018-02-01

    Safety issue is very important for the lithium ion battery used in electric vehicle or other applications. This paper probes the heat sources in the thermal runaway processes of lithium ion batteries composed of different chemistries using accelerating rate calorimetry (ARC) and differential scanning calorimetry (DSC). The adiabatic thermal runaway features for the 4 types of commercial lithium ion batteries are tested using ARC, whereas the reaction characteristics of the component materials, including the cathode, the anode and the separator, inside the 4 types of batteries are measured using DSC. The peaks and valleys of the critical component reactions measured by DSC can match the fluctuations in the temperature rise rate measured by ARC, therefore the relevance between the DSC curves and the ARC curves is utilized to probe the heat source in the thermal runaway process and reveal the thermal runaway mechanisms. The results and analysis indicate that internal short circuit is not the only way to thermal runaway, but can lead to extra electrical heat, which is comparable with the heat released by chemical reactions. The analytical approach of the thermal runaway mechanisms in this paper can guide the safety design of commercial lithium ion batteries.

  8. Mixing of process heels, process solutions, and recycle streams: Results of the small-scale radioactive tests

    International Nuclear Information System (INIS)

    Lumetta, G.J.; Bramson, J.P.; Farmer III, O.T.; Greenwood, L.R.; Hoopes, F.V.; Mann, M.A.; Steele, M.J.; Steele, R.T.; Swoboda, R.G.; Urie, M.W.

    2000-01-01

    Various recycle streams will be combined with the low-activity waste (LAW) or the high-level waste (HLW) feed solutions during the processing of the Hanford tank wastes by BNFL, Inc. In addition, the LAW and HLW feed solutions will also be mixed with heels present in the processing equipment. This report describes the results of a test conducted by Battelle to assess the effects of mixing specific process streams. Observations were made regarding adverse reactions (mainly precipitation) and effects on the Tc oxidation state (as indicated by K d measurements with SuperLigreg s ign 639). The work was conducted according to test plan BNFL-TP-29953-023, Rev. 0, Small Scale Mixing of Process Heels, Solutions, and Recycle Streams. The test went according to plan, with only minor deviations from the test plan. The deviations from the test plan are discussed in the experimental section

  9. Rotating thermal flows in natural and industrial processes

    CERN Document Server

    Lappa, Marcello

    2012-01-01

    Rotating Thermal Flows in Natural and Industrial Processes provides the reader with a systematic description of the different types of thermal convection and flow instabilities in rotating systems, as present in materials, crystal growth, thermal engineering, meteorology, oceanography, geophysics and astrophysics. It expressly shows how the isomorphism between small and large scale phenomena becomes beneficial to the definition and ensuing development of an integrated comprehensive framework.  This allows the reader to understand and assimilate the underlying, quintessential mechanisms withou

  10. Thermal control system. [removing waste heat from industrial process spacecraft

    Science.gov (United States)

    Hewitt, D. R. (Inventor)

    1983-01-01

    The temperature of an exothermic process plant carried aboard an Earth orbiting spacecraft is regulated using a number of curved radiator panels accurately positioned in a circular arrangement to form an open receptacle. A module containing the process is insertable into the receptacle. Heat exchangers having broad exterior surfaces extending axially above the circumference of the module fit within arcuate spacings between adjacent radiator panels. Banks of variable conductance heat pipes partially embedded within and thermally coupled to the radiator panels extend across the spacings and are thermally coupled to broad exterior surfaces of the heat exchangers by flanges. Temperature sensors monitor the temperature of process fluid flowing from the module through the heat exchanges. Thermal conduction between the heat exchangers and the radiator panels is regulated by heating a control fluid within the heat pipes to vary the effective thermal length of the heat pipes in inverse proportion to changes in the temperature of the process fluid.

  11. Thermal and catalytic decomposition behavior of PVC mixed plastic waste with petroleum residue

    Energy Technology Data Exchange (ETDEWEB)

    Ali, Mohammad Farhat; Siddiqui, Mohammad Nahid [Department of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran 31261 (Saudi Arabia)

    2005-08-15

    The pyrolysis and hydropyrolysis of PVC mixed plastic waste alone and with petroleum residue was carried out at 150 and 350{sup o}C under N{sub 2} gas and at 430{sup o}C under 6.5MPa H{sub 2} gas pressure. The behavior of plastic waste during thermal and catalytic decomposition has also been studied in single- and two-stage reaction processes. In the individual pyrolysis process, both the petroleum residue and polystyrene (PS) undergo more than 90% conversion to liquid and gaseous products, whereas low-density polyethylene (LDPE) and high-density polyethylene (HDPE) yielded lower conversions products, and polypropylene (PP) and polyvinyl chloride (PVC) afforded somewhere a moderate to high conversion products. In a single-stage pyrolysis reaction, PVC was processed with petroleum residue at 150 and 430{sup o}C, under N{sub 2} gas for 1h at each temperature in a glass reactor. The model PVC and waste PVC showed slight variations in the products distribution obtained from the glass reactor. In two-stage process, model PVC, vacuum gas oil (VGO) and a number of different catalysts were used in a stainless steel autoclave micro tubular reactor at 350{sup o}C under the stream of N{sub 2} gas for 1h and at 430{sup o}C under 950psi (6.5MPa) H{sub 2} pressure for the duration of 2h. Significantly, different products distributions were obtained. Among the catalysts used, fluid catalytic cracking (FCC) and hydrocracking catalysts (HC-1) were most effective in producing liquid fuel (hexane soluble) materials. The study shows that the catalytic coprocessing of PVC with VGO is a feasible process by which PVC and VGO materials can be converted into transportation fuels.

  12. Thermal stability and oxidizing properties of mixed alkaline earth-alkali molten carbonates: A focus on the lithium-sodium carbonate eutectic system with magnesium additions

    International Nuclear Information System (INIS)

    Frangini, Stefano; Scaccia, Silvera

    2013-01-01

    Highlights: • TG/DSC analysis was conducted on magnesium-containing eutectic Li/Na eutectic carbonates. • Magnesium influence on the oxygen solubility properties of carbonate was also experimentally determined at 600 °C and 650 °C. • A reproducible partial decarbonation process in premelting region caused formation of magnesium oxycarbonate-like phases. • The acidobase buffering action of magnesium oxycarbonate species could explain the high basic/oxidizing properties of such carbonate melts. • A general correlation between thermal instability in premelting region and basic/oxidizing melt properties was established. - Abstract: A comparative study on thermal behavior and oxygen solubility properties of eutectic 52/48 lithium/sodium carbonate salt containing minor additions of magnesium up to 10 mol% has been made in order to determine whether a general correlation between these two properties can be found or not. Consecutive TG/DSC heating/cooling thermal cycles carried out under alternating CO 2 and N 2 gas flows allowed to assign thermal events observed in the premelting region to a partial decarbonation process of the magnesium-alkali mixed carbonates. The observed decarbonation process at 460 °C is believed to come from initial stage of thermal decomposition of magnesium carbonate resulting in the metastable formation of magnesium oxycarbonate-like phases MgO·2MgCO 3 , in a similar manner as previously reported for lanthanum. Reversible formation and decomposition of the magnesium carbonate phase has been observed under a CO 2 gas atmosphere. The intensity of the decomposition process shows a maximum for a 3 mol% MgO addition that gives also the highest oxygen solubility, suggesting therefore that instability thermal analysis in the premelting region can be considered as providing an effective measure of the basicity/oxidizing properties of alkali carbonate melts with magnesium or, in more general terms, with cations that are strong modifiers of

  13. Thermochemistry of mixed explosives

    International Nuclear Information System (INIS)

    Janney, J.L.; Rogers, R.N.

    1982-01-01

    In order to predict thermal hazards of high-energy materials, accurate kinetics constants must be determined. Predictions of thermal hazards for mixtures of high-energy materials require measurements on the mixtures, because interactions among components are common. A differential-scanning calorimeter (DSC) can be used to observe rate processes directly, and isothermal methods enable detection of mechanism changes. Rate-controlling processes will change as components of a mixture are depleted, and the correct depletion function must be identified for each specific stage of a complex process. A method for kinetics measurements on mixed explosives can be demonstrated with Composition B is an approximately 60/40 mixture of RDX and TNT, and is an important military explosive. Kinetics results indicate that the mator process is the decomposition of RDX in solution in TNT with a perturbation caused by interaction between the two components. It is concluded that a combination of chemical kinetics and experimental self-heating procedures provides a good approach to the production of predictive models for thermal hazards of high-energy materials. Systems involving more than one energy-contributing component can be studied. Invalid and dangerous predictive models can be detected by a failure of agreement between prediction and experiment at a specific size, shape, and density. Rates of thermal decomposition for Composition B appear to be modeled adequately for critical-temperature predictions with the following kinetics constants: E = 180.2 kJ mole -1 and Z = 4.62 X 10 16 s -1

  14. Mixing Ventilation

    DEFF Research Database (Denmark)

    Kandzia, Claudia; Kosonen, Risto; Melikov, Arsen Krikor

    In this guidebook most of the known and used in practice methods for achieving mixing air distribution are discussed. Mixing ventilation has been applied to many different spaces providing fresh air and thermal comfort to the occupants. Today, a design engineer can choose from large selection...

  15. Comprehensive NMR analysis of compositional changes of black garlic during thermal processing.

    Science.gov (United States)

    Liang, Tingfu; Wei, Feifei; Lu, Yi; Kodani, Yoshinori; Nakada, Mitsuhiko; Miyakawa, Takuya; Tanokura, Masaru

    2015-01-21

    Black garlic is a processed food product obtained by subjecting whole raw garlic to thermal processing that causes chemical reactions, such as the Maillard reaction, which change the composition of the garlic. In this paper, we report a nuclear magnetic resonance (NMR)-based comprehensive analysis of raw garlic and black garlic extracts to determine the compositional changes resulting from thermal processing. (1)H NMR spectra with a detailed signal assignment showed that 38 components were altered by thermal processing of raw garlic. For example, the contents of 11 l-amino acids increased during the first step of thermal processing over 5 days and then decreased. Multivariate data analysis revealed changes in the contents of fructose, glucose, acetic acid, formic acid, pyroglutamic acid, cycloalliin, and 5-(hydroxymethyl)furfural (5-HMF). Our results provide comprehensive information on changes in NMR-detectable components during thermal processing of whole garlic.

  16. Marker experiments in growth studies of Ni2Si, Pd2Si, and CrSi2 formed both by thermal annealing and by ion mixing

    International Nuclear Information System (INIS)

    Hung, L.S.; Mayer, J.W.; Pai, C.S.; Lau, S.S.

    1985-01-01

    Inert markers (evaporated tungsten and silver) were used in growth studies of silicides formed both by thermal annealing and by ion mixing in the Ni/Si, Pd/Si, and Cr/Si systems. The markers were initially imbedded inside silicides and backscattering spectrometry was used to determine the marker displacement after different processing conditions. The results obtained in thermal annealing are quite consistent with that found in previous investigations. Ni is the dominant diffusing species in Ni 2 Si, while Si is the diffusing species in CrSi 2 . In Pd 2 Si, both Pd and Si are moving species with Pd the faster of the two. In contrast, in growth of silicides by ion irradiation Si is the faster diffusing species in all three systems

  17. Scaling of Thermal Images at Different Spatial Resolution: The Mixed Pixel Problem

    Directory of Open Access Journals (Sweden)

    Hamlyn G. Jones

    2014-07-01

    Full Text Available The consequences of changes in spatial resolution for application of thermal imagery in plant phenotyping in the field are discussed. Where image pixels are significantly smaller than the objects of interest (e.g., leaves, accurate estimates of leaf temperature are possible, but when pixels reach the same scale or larger than the objects of interest, the observed temperatures become significantly biased by the background temperature as a result of the presence of mixed pixels. Approaches to the estimation of the true leaf temperature that apply both at the whole-pixel level and at the sub-pixel level are reviewed and discussed.

  18. Influence of deuterium on the magnetic susceptibility and thermal expansion of the mixed valence compound CePd3

    International Nuclear Information System (INIS)

    Weinzierl, P.; Blaschko, O.; Fratzl, P.; Krexner, G.; Ernst, G.; Hilscher, G.

    1984-01-01

    The possibility of studying mixed valent rare earth compounds by addition of interstitially solved hydrogen is discussed. First measurements of the thermal expansion and of the magnetic susceptibility of 4 K in intermediate valent CePd 3 Dsub(0.05) are presented. (orig.) [de

  19. Significance of fundamental processes of radiation chemistry in hot atom chemical processes: electron thermalization

    International Nuclear Information System (INIS)

    Nishikawa, M.

    1984-01-01

    The author briefly reviews the current understanding of the course of electron thermalization. An outline is given of the physical picture without going into mathematical details. The analogy of electron thermalization with hot atom processes is taken as guiding principle in this paper. Content: secondary electrons (generation, track structure, yields); thermalization (mechanism, time, spatial distribution); behaviour of hot electrons. (Auth.)

  20. The thermal conductivity of mixed fuel UxPu1-xO2: molecular dynamics simulations

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Xiang-Yang [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Cooper, Michael William Donald [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Stanek, Christopher Richard [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Andersson, Anders David Ragnar [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2015-10-16

    Mixed oxides (MOX), in the context of nuclear fuels, are a mixture of the oxides of heavy actinide elements such as uranium, plutonium and thorium. The interest in the UO2-PuO2 system arises from the fact that these oxides are used both in fast breeder reactors (FBRs) as well as in pressurized water reactors (PWRs). The thermal conductivity of UO2 fuel is an important material property that affects fuel performance since it is the key parameter determining the temperature distribution in the fuel, thus governing, e.g., dimensional changes due to thermal expansion, fission gas release rates, etc. For this reason it is important to understand the thermal conductivity of MOX fuel and how it differs from UO2. Here, molecular dynamics (MD) simulations are carried out to determine quantitatively, the effect of mixing on the thermal conductivity of UxPu1-xO2, as a function of PuO2 concentrations, for a range of temperatures, 300 – 1500 K. The results will be used to develop enhanced continuum thermal conductivity models for MARMOT and BISON by INL. These models express the thermal conductivity as a function of microstructure state-variables, thus enabling thermal conductivity models with closer connection to the physical state of the fuel.

  1. Initial stages of the ion beam mixing process

    International Nuclear Information System (INIS)

    Traverse, A.; Le Boite, M.G.; Nevot, L.; Pardo, B.; Corno, J.

    1987-01-01

    The grazing x-ray reflectometry technique, performed on irradiated periodic multilayers, was used to study the early stages of the ion beam mixing process. We present our first results, obtained on NiAu samples irradiated with He ions. The experimental fluence dependence of the effective diffusion coefficient is in good agreement with a calculation based on a purely ballistic process

  2. Mixing ventilation guide on mixing air distribution design

    CERN Document Server

    Kandzia, Claudia; Kosonen, Risto; Krikor Melikov, Arsen; Nielsen, Peter Vilhelm

    2013-01-01

    In this guidebook most of the known and used in practice methods for achieving mixing air distribution are discussed. Mixing ventilation has been applied to many different spaces providing fresh air and thermal comfort to the occupants. Today, a design engineer can choose from large selection of air diffusers and exhaust openings.

  3. Intraoperative boron neutron capture therapy for malignant gliomas. First clinical results of Tsukuba phase I/II trial using JAERI mixed thermal-epithermal beam

    International Nuclear Information System (INIS)

    Matsumura, A.; Yamamoto, T.; Shibata, Y.

    2000-01-01

    Since October 1999, a clinical trial of intraoperative boron neutron capture therapy (IOBNCT) is in progress at JRR-4 (Japan Research Reactor-4) in Japan Atomic Energy Research Institute (JAERI) using mixed thermal-epithermal beam (thermal neutron beam I: TNB-I). Compared to pure thermal beam (thermal neutron beam II: TNB-II), TNB-I has an improved neutron delivery into the deep region than TNB-II. The clinical protocol and the preliminary results will be discussed. (author)

  4. Process management using component thermal-hydraulic function classes

    Science.gov (United States)

    Morman, J.A.; Wei, T.Y.C.; Reifman, J.

    1999-07-27

    A process management expert system where following malfunctioning of a component, such as a pump, for determining system realignment procedures such as for by-passing the malfunctioning component with on-line speeds to maintain operation of the process at full or partial capacity or to provide safe shut down of the system while isolating the malfunctioning component. The expert system uses thermal-hydraulic function classes at the component level for analyzing unanticipated as well as anticipated component malfunctions to provide recommended sequences of operator actions. Each component is classified according to its thermal-hydraulic function, and the generic and component-specific characteristics for that function. Using the diagnosis of the malfunctioning component and its thermal hydraulic class, the expert system analysis is carried out using generic thermal-hydraulic first principles. One aspect of the invention employs a qualitative physics-based forward search directed primarily downstream from the malfunctioning component in combination with a subsequent backward search directed primarily upstream from the serviced component. Generic classes of components are defined in the knowledge base according to the three thermal-hydraulic functions of mass, momentum and energy transfer and are used to determine possible realignment of component configurations in response to thermal-hydraulic function imbalance caused by the malfunctioning component. Each realignment to a new configuration produces the accompanying sequence of recommended operator actions. All possible new configurations are examined and a prioritized list of acceptable solutions is produced. 5 figs.

  5. Process management using component thermal-hydraulic function classes

    Science.gov (United States)

    Morman, James A.; Wei, Thomas Y. C.; Reifman, Jaques

    1999-01-01

    A process management expert system where following malfunctioning of a component, such as a pump, for determining system realignment procedures such as for by-passing the malfunctioning component with on-line speeds to maintain operation of the process at full or partial capacity or to provide safe shut down of the system while isolating the malfunctioning component. The expert system uses thermal-hydraulic function classes at the component level for analyzing unanticipated as well as anticipated component malfunctions to provide recommended sequences of operator actions. Each component is classified according to its thermal-hydraulic function, and the generic and component-specific characteristics for that function. Using the diagnosis of the malfunctioning component and its thermal hydraulic class, the expert system analysis is carried out using generic thermal-hydraulic first principles. One aspect of the invention employs a qualitative physics-based forward search directed primarily downstream from the malfunctioning component in combination with a subsequent backward search directed primarily upstream from the serviced component. Generic classes of components are defined in the knowledge base according to the three thermal-hydraulic functions of mass, momentum and energy transfer and are used to determine possible realignment of component configurations in response to thermal-hydraulic function imbalance caused by the malfunctioning component. Each realignment to a new configuration produces the accompanying sequence of recommended operator actions. All possible new configurations are examined and a prioritized list of acceptable solutions is produced.

  6. 9 CFR 381.302 - Thermal processing.

    Science.gov (United States)

    2010-01-01

    ... INSPECTION AND CERTIFICATION POULTRY PRODUCTS INSPECTION REGULATIONS Canning and Canned Products § 381.302... 9 Animals and Animal Products 2 2010-01-01 2010-01-01 false Thermal processing. 381.302 Section 381.302 Animals and Animal Products FOOD SAFETY AND INSPECTION SERVICE, DEPARTMENT OF AGRICULTURE...

  7. Fabrication of mixed oxide fuel using plutonium from dismantled weapons

    International Nuclear Information System (INIS)

    Blair, H.T.; Chidester, K.; Ramsey, K.B.

    1996-01-01

    A very brief summary is presented of experimental studies performed to support the use of plutonium from dismantled weapons in fabricating mixed oxide (MOX) fuel for commercial power reactors. Thermal treatment tests were performed on plutonium dioxide powder to determine if an effective dry gallium removal process could be devised. Fabrication tests were performed to determine the effects of various processing parameters on pellet quality. Thermal tests results showed that the final gallium content is highly dependent on the treatment temperature. Fabrication tests showed that the milling process, sintering parameters, and uranium feed did effect pellet properties. 1 ref., 1 tab

  8. Heat transfer phenomena during thermal processing of liquid particulate mixtures-A review.

    Science.gov (United States)

    Singh, Anubhav Pratap; Singh, Anika; Ramaswamy, Hosahalli S

    2017-05-03

    During the past few decades, food industry has explored various novel thermal and non-thermal processing technologies to minimize the associated high-quality loss involved in conventional thermal processing. Among these are the novel agitation systems that permit forced convention in canned particulate fluids to improve heat transfer, reduce process time, and minimize heat damage to processed products. These include traditional rotary agitation systems involving end-over-end, axial, or biaxial rotation of cans and the more recent reciprocating (lateral) agitation. The invention of thermal processing systems with induced container agitation has made heat transfer studies more difficult due to problems in tracking the particle temperatures due to their dynamic motion during processing and complexities resulting from the effects of forced convection currents within the container. This has prompted active research on modeling and characterization of heat transfer phenomena in such systems. This review brings to perspective, the current status on thermal processing of particulate foods, within the constraints of lethality requirements from safety view point, and discusses available techniques of data collection, heat transfer coefficient evaluation, and the critical processing parameters that affect these heat transfer coefficients, especially under agitation processing conditions.

  9. Structurally Integrated Coatings for Wear and Corrosion (SICWC): Arc Lamp, InfraRed (IR) Thermal Processing

    Energy Technology Data Exchange (ETDEWEB)

    Mackiewicz-Ludtka, G.; Sebright, J. [Caterpillar Corp.

    2007-12-15

    The primary goal of this Cooperative Research and Development Agreement (CRADA) betwe1311 UT-Battelle (Contractor) and Caterpillar Inc. (Participant) was to develop the plasma arc lamp (PAL), infrared (IR) thermal processing technology 1.) to enhance surface coating performance by improving the interfacial bond strength between selected coatings and substrates; and 2.) to extend this technology base for transitioning of the arc lamp processing to the industrial Participant. Completion of the following three key technical tasks (described below) was necessary in order to accomplish this goal. First, thermophysical property data sets were successfully determined for composite coatings applied to 1010 steel substrates, with a more limited data set successfully measured for free-standing coatings. These data are necessary for the computer modeling simulations and parametric studies to; A.) simulate PAL IR processing, facilitating the development of the initial processing parameters; and B.) help develop a better understanding of the basic PAL IR fusing process fundamentals, including predicting the influence of melt pool stirring and heat tnmsfar characteristics introduced during plasma arc lamp infrared (IR) processing; Second, a methodology and a set of procedures were successfully developed and the plasma arc lamp (PAL) power profiles were successfully mapped as a function of PAL power level for the ORNL PAL. The latter data also are necessary input for the computer model to accurately simulate PAL processing during process modeling simulations, and to facilitate a better understand of the fusing process fundamentals. Third, several computer modeling codes have been evaluated as to their capabilities and accuracy in being able to capture and simulate convective mixing that may occur during PAL thermal processing. The results from these evaluation efforts are summarized in this report. The intention of this project was to extend the technology base and provide for

  10. Microergodicity effects on ebullition of methane modelled by Mixed Poisson process with Pareto mixing variable

    Czech Academy of Sciences Publication Activity Database

    Jordanova, P.; Dušek, Jiří; Stehlík, M.

    2013-01-01

    Roč. 128, OCT 15 (2013), s. 124-134 ISSN 0169-7439 R&D Projects: GA ČR(CZ) GAP504/11/1151; GA MŠk(CZ) ED1.1.00/02.0073 Institutional support: RVO:67179843 Keywords : environmental chemistry * ebullition of methane * mixed poisson processes * renewal process * pareto distribution * moving average process * robust statistics * sedge–grass marsh Subject RIV: EH - Ecology, Behaviour Impact factor: 2.381, year: 2013

  11. ELECTRON IRRADIATION AND THERMAL PROCESSING OF MIXED-ICES OF POTENTIAL RELEVANCE TO JUPITER TROJAN ASTEROIDS

    Energy Technology Data Exchange (ETDEWEB)

    Mahjoub, Ahmed; Poston, Michael J.; Hand, Kevin P.; Hodyss, Robert; Blacksberg, Jordana; Carlson, Robert W.; Ehlmann, Bethany L.; Choukroun, Mathieu [Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109 (United States); Brown, Michael E.; Eiler, John M., E-mail: Mahjoub.Ahmed@jpl.nasa.gov [California Institute of Technology, Division of Geological and Planetary Sciences, Pasadena, CA 91125 (United States)

    2016-04-01

    In this work we explore the chemistry that occurs during the irradiation of ice mixtures on planetary surfaces, with the goal of linking the presence of specific chemical compounds to their formation locations in the solar system and subsequent processing by later migration inward. We focus on the outer solar system and the chemical differences for ice mixtures inside and outside the stability line for H{sub 2}S. We perform a set of experiments to explore the hypothesis advanced by Wong and Brown that links the color bimodality in Jupiter's Trojans to the presence of H{sub 2}S in the surface of their precursors. Non-thermal (10 keV electron irradiation) and thermally driven chemistry of CH{sub 3}OH–NH{sub 3}–H{sub 2}O (“without H{sub 2}S”) and H{sub 2}S–CH{sub 3}OH–NH{sub 3}–H{sub 2}O (“with H{sub 2}S”) ices were examined. Mid-IR analyses of ice and mass spectrometry monitoring of the volatiles released during heating show a rich chemistry in both of the ice mixtures. The “with H{sub 2}S” mixture experiment shows a rapid consumption of H{sub 2}S molecules and production of OCS molecules after a few hours of irradiation. The heating of the irradiated “with H{sub 2}S” mixture to temperatures above 120 K leads to the appearance of new infrared bands that we provisionally assign to SO{sub 2}and CS. We show that radiolysis products are stable under the temperature and irradiation conditions of Jupiter Trojan asteroids. This makes them suitable target molecules for potential future missions as well as telescope observations with a high signal-to-noise ratio. We also suggest the consideration of sulfur chemistry in the theoretical modeling aimed at understanding the chemical composition of Trojans and KOBs.

  12. Make to stock and mix to order : choosing intermediate products in the food-processing industry

    NARCIS (Netherlands)

    Akkerman, Renzo; van der Meer, Dirk; van Donk, Dirk Pieter

    2010-01-01

    In contrast to discrete manufacturers, food-processing companies can sometimes produce the same end products in different ways: either mix first and then process, or process first and mix later. Moreover, a final product can be mixed from different raw materials or intermediates. That adds a new

  13. Spin relaxation of iron in mixed state hemoproteins

    International Nuclear Information System (INIS)

    Wajnberg, E.; Kalinowski, H.J.; Bemski, G.; Helman, J.S.

    1984-01-01

    In pure states hemoproteins the relaxation of iron depends on its spin state. It is found that in both mixed state met-hemoglobin and met-myoglobin, the low and high spin states relax through an Orbach-like process. Also, very short (approx. 1 ns) and temperature independent transverse relaxation times T 2 were estimated. This peculiar behaviour of the relaxation may result from the unusual electronic structure of mixed state hemoproteins that allows thermal equilibrium and interconversion of the spin states. (Author) [pt

  14. Basic aspects of ion beam mixing

    International Nuclear Information System (INIS)

    Averback, R.S.

    1985-07-01

    Irradiation of solids with energetic particles results in the reorganization of constituent target atoms, i.e., ion beam mixing (IM). At low temperatures, IM is characterized by prompt (10 -10 s) diffusion processes which are localized in the vicinity of the displacement cascade. Mixing at low temperatures can cause the system to depart far from the equilibrium state. At elevated temperatures, the diffusion of radiation-induced defects extends the mixing to longer times and greater distances. These delayed IM processes tend to return the system toward equilibrium. Recent experimental progress has led to a qualitative understanding of the fundamental aspects of IM in both temperature regimes. This has been achieved through systematic measurements of the influences of temperature, dose, dose-rate, cascade energy density, and chemical interactions on IM. The results of these experiments will be reviewed and compared to IM models based on collisional, thermal spike, and radiation-enhanced diffusion processes. The relation of IM to other fundamental radiation damage effects will also be discussed. 75 refs., 8 figs., 2 tabs

  15. Synthesis of functional nanocrystallites through reactive thermal plasma processing

    Directory of Open Access Journals (Sweden)

    Takamasa Ishigaki and Ji-Guang Li

    2007-01-01

    Full Text Available A method of synthesizing functional nanostructured powders through reactive thermal plasma processing has been developed. The synthesis of nanosized titanium oxide powders was performed by the oxidation of solid and liquid precursors. Quench gases, either injected from the shoulder of the reactor or injected counter to the plasma plume from the bottom of the reactor, were used to vary the quench rate, and therefore the particle size, of the resultant powders. The experimental results are well supported by numerical analysis on the effects of the quench gas on the flow pattern and temperature field of the thermal plasma as well as on the trajectory and temperature history of the particles. The plasma-synthesized TiO2 nanoparticles showed phase preferences different from those synthesized by conventional wet-chemical processes. Nanosized particles of high crystallinity and nonequilibrium chemical composition were formed in one step via reactive thermal plasma processing.

  16. Process for fabricating composite material having high thermal conductivity

    Science.gov (United States)

    Colella, Nicholas J.; Davidson, Howard L.; Kerns, John A.; Makowiecki, Daniel M.

    2001-01-01

    A process for fabricating a composite material such as that having high thermal conductivity and having specific application as a heat sink or heat spreader for high density integrated circuits. The composite material produced by this process has a thermal conductivity between that of diamond and copper, and basically consists of coated diamond particles dispersed in a high conductivity metal, such as copper. The composite material can be fabricated in small or relatively large sizes using inexpensive materials. The process basically consists, for example, of sputter coating diamond powder with several elements, including a carbide forming element and a brazeable material, compacting them into a porous body, and infiltrating the porous body with a suitable braze material, such as copper-silver alloy, thereby producing a dense diamond-copper composite material with a thermal conductivity comparable to synthetic diamond films at a fraction of the cost.

  17. EXPERIMENTAL RESEARCH OF PROCESSING OF DUMP SAND-CLAY MIXES BY THE CENTRIFUGAL AND SHOCK CRUSHING

    Directory of Open Access Journals (Sweden)

    V. V. Vorobev

    2015-01-01

    Full Text Available Results of experimental research of processing of centrifugal and shock crushing of dump sandy-clay mixes are given. Use of products of processing of received mixes in foundry production and in production of asphalt concrete mixes allows to exclude transportation of the mix to dumping.

  18. Process development of starch hydrolysis using mixing characteristics of Taylor vortices.

    Science.gov (United States)

    Masuda, Hayato; Horie, Takafumi; Hubacz, Robert; Ohmura, Naoto; Shimoyamada, Makoto

    2017-04-01

    In food industries, enzymatic starch hydrolysis is an important process that consists of two steps: gelatinization and saccharification. One of the major difficulties in designing the starch hydrolysis process is the sharp change in its rheological properties. In this study, Taylor-Couette flow reactor was applied to continuous starch hydrolysis process. The concentration of reducing sugar produced via enzymatic hydrolysis was evaluated by varying operational variables: rotational speed of the inner cylinder, axial velocity (reaction time), amount of enzyme, and initial starch content in the slurry. When Taylor vortices were formed in the annular space, efficient hydrolysis occurred because Taylor vortices improved the mixing of gelatinized starch with enzyme. Furthermore, a modified inner cylinder was proposed, and its mixing performance was numerically investigated. The modified inner cylinder showed higher potential for enhanced mixing of gelatinized starch and the enzyme than the conventional cylinder.

  19. Thermally induced growth of ZnO nanocrystals on mixed metal oxide surfaces.

    Science.gov (United States)

    Inayat, Alexandra; Makky, Ayman; Giraldo, Jose; Kuhnt, Andreas; Busse, Corinna; Schwieger, Wilhelm

    2014-06-23

    An in situ method for the growth of ZnO nanocrystals on Zn/Al mixed metal oxide (MMO) surfaces is presented. The key to this method is the thermal treatment of Zn/Al layered double hydroxides (Zn/Al LDHs) in the presence of nitrate anions, which results in partial demixing of the LDH/MMO structure and the subsequent crystallization of ZnO crystals on the surface of the forming MMO layers. In a first experimental series, thermal treatment of Zn/Al LDHs with different fractions of nitrate and carbonate in the interlayer space was examined by thermogravimetry coupled with mass spectrometry (TG-MS) and in situ XRD. In a second experimental series, Zn/Al LDHs with only carbonate in the interlayer space were thermally treated in the presence of different amounts of an external nitrate source (NH4NO3). All obtained Zn/Al MMO samples were analysed by electron microscopy, nitrogen physisorption and powder X-ray diffraction. The gas phase formed during nitrate decomposition turned out to be responsible for the formation of crystalline ZnO nanoparticles. Accordingly, both interlayer nitrate and the presence of ammonium nitrate led to the formation of supported ZnO nanocrystals with mean diameters between 100 and 400 nm, and both methods offer the possibility to tailor the amount and size of the ZnO crystals by means of the amount of nitrate. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  20. In situ treatment of mixed contaminants in groundwater: Review of candidate processes

    International Nuclear Information System (INIS)

    Korte, N.E.; Siegrist, R.L.; Ally, M.

    1994-10-01

    This document describes the screening and preliminary evaluation of candidate treatment for use in treating mixed contaminants volatile organic compounds (VOCs) and radionuclides in groundwater. Treating mixed contaminants presents unusual difficulties. Typically, VOCs are the most abundant contaminants, but the presence of radionuclides results in additional health concerns that must be addressed, usually by a treatment approach different from that used for VOCs. Furthermore, the presence of radionuclides may yield mixed solid wastes if the VOCs are treated by conventional means. These issues were specifically addressed in the evaluation of candidate treatment processes for testing in this program. Moreover, because no research or early development of a particular process would be performed, the technology review also focused on technologies that could be readily adapted and integrated for use with mixed contaminants. The objective is to couple emerging or available processes into treatment modules for use in situ. The three year project, to be completed in September 1996, includes a full-scale field demonstration. The findings reported in this document encompass all activities through the treatment process evaluations

  1. In situ treatment of mixed contaminants in groundwater: Review of candidate processes

    Energy Technology Data Exchange (ETDEWEB)

    Korte, N.E. [ed.] [Oak Ridge National Lab., Grand Junction, CO (United States); Siegrist, R.L. [ed.] [Oak Ridge National Lab., TN (United States); Ally, M. [and others

    1994-10-01

    This document describes the screening and preliminary evaluation of candidate treatment for use in treating mixed contaminants volatile organic compounds (VOCs) and radionuclides in groundwater. Treating mixed contaminants presents unusual difficulties. Typically, VOCs are the most abundant contaminants, but the presence of radionuclides results in additional health concerns that must be addressed, usually by a treatment approach different from that used for VOCs. Furthermore, the presence of radionuclides may yield mixed solid wastes if the VOCs are treated by conventional means. These issues were specifically addressed in the evaluation of candidate treatment processes for testing in this program. Moreover, because no research or early development of a particular process would be performed, the technology review also focused on technologies that could be readily adapted and integrated for use with mixed contaminants. The objective is to couple emerging or available processes into treatment modules for use in situ. The three year project, to be completed in September 1996, includes a full-scale field demonstration. The findings reported in this document encompass all activities through the treatment process evaluations.

  2. An Improvement in Thermal Modelling of Automated Tape Placement Process

    International Nuclear Information System (INIS)

    Barasinski, Anaies; Leygue, Adrien; Poitou, Arnaud; Soccard, Eric

    2011-01-01

    The thermoplastic tape placement process offers the possibility of manufacturing large laminated composite parts with all kinds of geometries (double curved i.e.). This process is based on the fusion bonding of a thermoplastic tape on a substrate. It has received a growing interest during last years because of its non autoclave abilities.In order to control and optimize the quality of the manufactured part, we need to predict the temperature field throughout the processing of the laminate. In this work, we focus on a thermal modeling of this process which takes in account the imperfect bonding existing between the different layers of the substrate by introducing thermal contact resistance in the model. This study is leaning on experimental results which inform us that the value of the thermal resistance evolves with temperature and pressure applied on the material.

  3. Mixing Processes in High-Level Waste Tanks - Final Report

    International Nuclear Information System (INIS)

    Peterson, P.F.

    1999-01-01

    The mixing processes in large, complex enclosures using one-dimensional differential equations, with transport in free and wall jets is modeled using standard integral techniques. With this goal in mind, we have constructed a simple, computationally efficient numerical tool, the Berkeley Mechanistic Mixing Model, which can be used to predict the transient evolution of fuel and oxygen concentrations in DOE high-level waste tanks following loss of ventilation, and validate the model against a series of experiments

  4. Mixed Waste Focus Area alternative oxidation technologies development and demonstration program

    International Nuclear Information System (INIS)

    Borduin, L.C.; Fewell, T.; Gombert, D.; Priebe, S.

    1998-01-01

    The Mixed Waste Focus Area (MWFA) is currently supporting the development and demonstration of several alternative oxidation technology (AOT) processes for treatment of combustible mixed low-level wastes. The impetus for this support derives from regulatory and political hurdles frequently encountered by traditional thermal techniques, primarily incinerators. AOTs have been defined as technologies that destroy organic material without using open-flame reactions. Whether thermal or nonthermal, the processes have the potential advantages of relatively low-volume gaseous emissions, generation of few or no dioxin/furan compounds, and operation at low enough temperatures that metals (except mercury) and most radionuclides are not volatilized. Technology development and demonstration are needed to confirm and realize the potential of AOTs and to compare them on an equal basis with their fully demonstrated thermal counterparts. AOTs include both thermal and nonthermal processes that oxidize organic wastes but operate under significantly different physical and chemical conditions than incinerators. Nonthermal processes currently being studied include Delphi DETOX and acid digestion at the Savannah River Site, and direct chemical oxidation at Lawrence Livermore National Laboratory. All three technologies are at advanced stages of development or are entering the demonstration phase. Nonflame thermal processes include catalytic chemical oxidation, which is being developed and deployed at Lawrence Berkeley National Laboratory, and team reforming, a commercial process being supported by Department of Energy. Related technologies include two low-flow, secondary oxidation processes (Phoenix and Thermatrix units) that have been tested at MSE, Inc., in Butte, Montana. Although testing is complete on some AOT technologies, most require additional support to complete some or all of the identified development objectives. Brief descriptions, status, and planned paths forward for each

  5. Thermal diffusion and separation of isotopes

    International Nuclear Information System (INIS)

    Fournier, Andre

    1944-01-01

    After a review of the various processes used to separate isotopes or at least to obtain mixes with a composition different from the natural proportion, this research addresses the use of thermal diffusion. The author reports a theoretical study of gas thermal diffusion and of the Clusius-Dickel method. In the second part, he reports the enrichment of methane with carbon-13, and of ammoniac with nitrogen-15. The next part reports the experimental study of thermal diffusion of liquids and solutions, and the enrichment of carbon tetra-chloride with chlorine-37. The author then proposes an overview of theories of thermal diffusion in liquid phase (hydrodynamic theory, kinetic theory, theory of caged molecules)

  6. Fe-catalyzed thermal conversion of sodium lignosulfonate to graphene

    Science.gov (United States)

    Sung Phil Mun; Zhiyong Cai; Jilei Zhang

    2013-01-01

    Sodium lignosulfonate (LS) from sulfite pulping processing was used as a carbon source to synthesize graphene. LS was mixed with Fe nanoparticles (FeNPs) as a catalyst and thermally treated at 1000 °C for 1 h. The Raman spectrum and X-ray diffraction pattern suggested that graphene sheets were formed in LS thermally treated with FeNPs (Fe-HTLS). Scanning...

  7. Radiation-thermal processes of conversion in the coals

    International Nuclear Information System (INIS)

    Mustafaev, I.I.

    2002-01-01

    Full text: The brief review, history, modern condition and bibliographic data on research of radiation-stimulated processes in coals are adduced in the report. Results of new researches of influence of gamma - radiation and accelerated electrons on pyrolysis, gasification, desulphurization, paramagnetism, adsorption and optical properties of coals in wide intervals of change of absorbed dose, dose rate, temperature, radiation type and other parameters of processes are stated. As object of researches Turkish (Yeni koy, Yatagan) and Russian (Siberia) coals were used. Specific peculiarities of influence of ionizing radiations on fossil fuels, bringing in change of their reactivity as result of destruction and polycondensation processes are considered. a)Pyrolysis: Under action of gamma-radiation and accelerated electrons the rate of thermal (t) pyrolysis grows and the ratio of radiation-thermal (rt) and thermal (t) processes: Wrt/ Wt depends on dose rate and temperature. By increase of dose rate the radiation effects grows, and at increase of temperature this effect is reduced. The influence of high rate heating of coals under pulls action of accelerated electrons on conversion degree and product composition has been established. The investigation regularities of formation liquid and gas products is resulted at radiation - thermal processing of mixtures of lignites with fuel oil. These experiments were conducted in flowing conditions in the interval of temperature T=350-500 degrees centigrade, power of the pulls accelerated electrons P=30-50 W, flow velocity of fuel oil 0,2-2 ml/minute. As a index of process were controlled conversion degree of coals, overall yield, contents and characteristic of liquid and gas products. The products of thermal treatment of these mixtures and also radiation-thermal treatment of separate components significantly less than radiation-thermal conversion of binary mixtures. It has been established that radiation effect has a positive

  8. Rubber/clay nanocomposites by combined latex compounding and melt mixing: A masterbatch process

    International Nuclear Information System (INIS)

    Tan, Jinghua; Wang, Xiaoping; Luo, Yuanfang; Jia, Demin

    2012-01-01

    Highlights: → Rubber/Ca-montmorillonite nanocomposites were prepared by the masterbatch process. → Latex compounding method is efficient to improve the Ca-montmorillonite dispersion. → Exfoliated structure was obtained in the masterbatch by latex compounding method. → Intercalated and exfoliated structures were achieved in the vulcanizate. → The properties of vulcanizate are improved by the addition of Ca-montmorillonite. -- Abstract: Rubber/Ca-montmorillonite (Ca-MMT) nanocomposites with well exfoliated Ca-MMT layers were prepared by combination of latex compounding and melt mixing. Firstly, a high Ca-MMT content masterbatch was co-coagulated by natural rubber (NR) latex and modified Ca-MMT aqueous suspension through latex compounding. The masterbatch was added in the system of styrene butadiene rubber (SBR) and epoxidized natural rubber (ENR) by melt mixing subsequently. The X-ray diffraction (XRD) and transmission electronic microscopy (TEM) results showed that intercalated and exfoliated nanocomposites were obtained by the masterbatch technique. The effects of modified Ca-MMT introduction into the rubber matrix, via the masterbatch technique, on the properties of the resulting composites were studied. It was found that the vulcanization was hindered by the incorporation of modified Ca-MMT, while mechanical performances, thermal stability and aging resistance were improved. The increasingly glass transition temperature and the storage modulus with the loading of modified Ca-MMT were measured by dynamic mechanical analysis (DMA).

  9. Fluid Structure Interaction Techniques For Extrusion And Mixing Processes

    Science.gov (United States)

    Valette, Rudy; Vergnes, Bruno; Coupez, Thierry

    2007-05-01

    This work focuses on the development of numerical techniques devoted to the simulation of mixing processes of complex fluids such as twin-screw extrusion or batch mixing. In mixing process simulation, the absence of symmetry of the moving boundaries (the screws or the rotors) implies that their rigid body motion has to be taken into account by using a special treatment We therefore use a mesh immersion technique (MIT), which consists in using a P1+/P1-based (MINI-element) mixed finite element method for solving the velocity-pressure problem and then solving the problem in the whole barrel cavity by imposing a rigid motion (rotation) to nodes found located inside the so called immersed domain, each sub-domain (screw, rotor) being represented by a surface CAD mesh (or its mathematical equation in simple cases). The independent meshes are immersed into a unique background computational mesh by computing the distance function to their boundaries. Intersections of meshes are accounted for, allowing to compute a fill factor usable as for the VOF methodology. This technique, combined with the use of parallel computing, allows to compute the time-dependent flow of generalized Newtonian fluids including yield stress fluids in a complex system such as a twin screw extruder, including moving free surfaces, which are treated by a "level set" and Hamilton-Jacobi method.

  10. Buoyancy effects in overcooling transients calculated for the NRC pressurized thermal shock study

    International Nuclear Information System (INIS)

    Theofanous, T.G.; Iyer, K.; Nourbakhsh, H.P.; Gherson, P.

    1986-05-01

    The thermal-hydraulic responses of three PWRs (Oconee, Calvert Cliffs, and H.B. Robinson), to postulated Pressurized Thermal Shock (PTS) scenarios, which were originally determined by RELAP5 and TRAC calculations, are being further developed here with regard to buoyancy/stratification effects. These three PWRs were the subject of the NRC PTS study, and the present results helped define the thermal-hydraulic conditions utilized in the fracture mechanics calculations carried out at ORNL. The computer program REMIX, which is based on the Regional Mixing Model (RMM), was the analytical tool employed, while Purdue's 1/2-Scale HPI Thermal Mixing facility provided the basis for experimental support. Important mixing and wall heat transfer regimes are delineated on the basis of these results. We conclude that stratification is important only in cases of complete loop stagnation and that mixed-convection effects are important for downcomer flow velocities below approx.0.25 m/s. The stratification is small in magnitude, however it is important in creating a recirculating flow pattern which activates the lower plenum, pump and loop seal volumes, to participate in the mixing process. This mixing process together with the heat input from the wall metal significantly impact the cooldown rates. Heat transfer in the plume region is dominated by forced convection. On the other hand, the presence of the Reactor Pressure Vessel (RPV) wall cladding and wall conduction significantly dampen the free convection effects in the low velocity, mixed-convection, regime. For the stagnant loop cases, all locations outside the plume region are included in this regime. In the presence of natural loop circulation and a uniformly distributed downcomer flow, the mixed convection regime is also expected, however, the forced convection regime can also be observed in highly asymmetric flow behavior

  11. Mixing processes in high-level waste tanks. 1998 annual progress report

    International Nuclear Information System (INIS)

    Peterson, P.F.

    1998-01-01

    Flammable gases can be generated in DOE high-level waste tanks, including radiolytic hydrogen, and during cesium precipitation from salt solutions, benzene. Under normal operating conditions the potential for deflagration or detonation from these gases is precluded by purging and ventilation systems, which remove the flammable gases and maintain a well-mixed condition in the tanks. Upon failure of the ventilation system, due to seismic or other events, however, it has proven more difficult to make strong arguments for well-mixed conditions, due to the potential for density-induced stratification which can potentially sequester fuel or oxidizer at concentrations significantly higher than average. This has complicated the task of defining the safety basis for tank operation. Waste-tank mixing processes have considerable overlap with similar large-enclosure mixing processes that occur in enclosure fires and nuclear reactor containments. Significant differences also exist, so that modeling techniques that have been developed previously can not be directly applied to waste tanks. In particular, mixing of air introduced through tank roof penetrations by buoyancy and pressure driven exchange flows, mixed convection induced by an injected high-velocity purge jet interacting with buoyancy driven flow, and onset and breakdown of stable stratification under the influence of an injected jet have not been adequately studied but are important in assessing the potential for accumulation of high-concentration pockets of fuel and oxygen. Treating these phenomena requires a combination of experiments and the development of new, more general computational models than those that have been developed for enclosure fires. U.C. Berkeley is now completing the second year of its three-year project that started in September, 1996. Excellent progress has been made in several important areas related to waste-tank ventilation and mixing processes.'

  12. Investigation of thermal hydraulic mixing mechanism in T-junction pipe with a 90-degree bend in upstream side for mitigation and controlling of thermal-striping phenomena (Joint research)

    International Nuclear Information System (INIS)

    Yuki, Kazuhisa; Hashizume, Hidetoshi; Tanaka, Masaaki; Muramatsu, Toshiharu

    2006-03-01

    In T-junction pipe, where two fluids of different temperatures mix together, temperature fluctuation is induced due to unstable fluid mixing. Since there is a possibility that high cycle thermal fatigue in structural materials is caused by this temperature fluctuation in fluid, the development of the mitigation and control techniques for the thermal fatigue is one of the most important issues in the future plant design. If a 90-degree bend exists in the upstream of T-junction pipe, a secondary flow formed in the bend makes the fluid mixing phenomena even more complex. This study aims to clarify the effects of curvature ratio of the bend on the temperature fluctuation in T-junction pipe, by the flow visualization with PIV (Particle Image Velocimetry) and the measurement of fluid temperature in the vicinity of wall with thermo couples. From the visualization, it is clarified that a jet from branch pipe swings and sways near the wall and they brings strong temperature fluctuation in comparison of the case without the 90-degree bend. In the case of the short curvature bend, in which there exists flow separation, the fluid mixing and the temperature fluctuation characteristics are completely different from those in the case of the long curvature bend. Furthermore, in the case of long curvature bend, in which the flow separation doesn't occur, there are cautionary conditions that the temperature fluctuation is maximized in a transition regime of a stratified flow and a turn-jet flow. It seems that the cause for this phenomena is the repetition of generation and disappearance of a circulating flow formed behind the jet, due to the oscillation of jet caused by an interaction between unsteady behavior of a secondary flow and the wakes formed behind the jet. In the experiments, experimental correlation equations to predict the temperature fluctuation were obtained in each flow pattern. By using these equations, it's possible to predict the suitable flow condition and piping

  13. Sol-gel route to synthesis of microporous ceramic membranes: Thermal stability of TiO2-ZrO2 mixed oxides

    International Nuclear Information System (INIS)

    Qunyin Xu; Anderson, M.A.

    1993-01-01

    In this paper concerning the synthesis of microporous ceramic membranes, the authors focus on the preparation and thermal stability of unsupported microporous TiO 2 -ZrO 2 mixed-oxide membranes. It has been observed that, by adding up to 20% ZrO 2 into TiO 2 or up to 10% TiO 2 into ZrO 2 , these microporous membranes display improved thermal stability. They can be fired up to 500 C for 0.5 h without closing micropores. However, membranes containing almost equal percentages of each component have lost microporous features and have low surface areas and low porosities. A phase diagram of a two-component TiO 2 -ZrO 2 mixed-oxide membrane has been prepared based on DTA and X-ray diffraction data in order to better understand the microstructure changes upon firing

  14. Effects of Annealing Conditions on Mixed Lead Halide Perovskite Solar Cells and Their Thermal Stability Investigation.

    Science.gov (United States)

    Yang, Haifeng; Zhang, Jincheng; Zhang, Chunfu; Chang, Jingjing; Lin, Zhenhua; Chen, Dazheng; Xi, He; Hao, Yue

    2017-07-21

    In this work, efficient mixed organic cation and mixed halide (MA 0.7 FA 0.3 Pb(I 0.9 Br 0.1 )₃) perovskite solar cells are demonstrated by optimizing annealing conditions. AFM, XRD and PL measurements show that there is a better perovskite film quality for the annealing condition at 100 °C for 30 min. The corresponding device exhibits an optimized PCE of 16.76% with V OC of 1.02 V, J SC of 21.55 mA/cm² and FF of 76.27%. More importantly, the mixed lead halide perovskite MA 0.7 FA 0.3 Pb(I 0.9 Br 0.1 )₃ can significantly increase the thermal stability of perovskite film. After being heated at 80 °C for 24 h, the PCE of the MA 0.7 FA 0.3 Pb(I 0.9 Br 0.1 )₃ device still remains at 70.00% of its initial value, which is much better than the control MAPbI₃ device, where only 46.50% of its initial value could be preserved. We also successfully fabricated high-performance flexible mixed lead halide perovskite solar cells based on PEN substrates.

  15. Chemical Changes in Carbohydrates Produced by Thermal Processing.

    Science.gov (United States)

    Hoseney, R. Carl

    1984-01-01

    Discusses chemical changes that occur in the carbohydrates found in food products when these products are subjected to thermal processing. Topics considered include browning reactions, starch found in food systems, hydrolysis of carbohydrates, extrusion cooking, processing of cookies and candies, and alterations in gums. (JN)

  16. Inactivation of Salmonella and Listeria in ground chicken breast meat during thermal processing.

    Science.gov (United States)

    Murphy, R Y; Marks, B P; Johnson, E R; Johnson, M G

    1999-09-01

    Thermal inactivation of six Salmonella spp. and Listeria innocua was evaluated in ground chicken breast and liquid medium. Survival of Salmonella and Listeria was affected by the medium composition. Under the same thermal process condition, significantly more Salmonella and Listeria survived in chicken breast meat than in 0.1% peptone-agar solution. The thermal lethality of six tested Salmonella spp. was additive in chicken meat. Survival of Listeria in chicken meat during thermal processing was not affected by the presence of the six Salmonella spp. Sample size and shape affected the inactivation of Salmonella and Listeria in chicken meat during thermal processing.

  17. Effect of normal processes on thermal conductivity of germanium ...

    Indian Academy of Sciences (India)

    Abstract. The effect of normal scattering processes is considered to redistribute the phonon momentum in (a) the same phonon branch – KK-S model and (b) between differ- ent phonon branches – KK-H model. Simplified thermal conductivity relations are used to estimate the thermal conductivity of germanium, silicon and ...

  18. Significant improvement in the thermal annealing process of optical resonators

    Science.gov (United States)

    Salzenstein, Patrice; Zarubin, Mikhail

    2017-05-01

    Thermal annealing performed during process improves the quality of the roughness of optical resonators reducing stresses at the periphery of their surface thus allowing higher Q-factors. After a preliminary realization, the design of the oven and the electronic method were significantly improved thanks to nichrome resistant alloy wires and chopped basalt fibers for thermal isolation during the annealing process. Q-factors can then be improved.

  19. Average thermal stress in the Al+SiC composite due to its manufacturing process

    International Nuclear Information System (INIS)

    Miranda, Carlos A.J.; Libardi, Rosani M.P.; Marcelino, Sergio; Boari, Zoroastro M.

    2013-01-01

    The numerical analyses framework to obtain the average thermal stress in the Al+SiC Composite due to its manufacturing process is presented along with the obtained results. The mixing of Aluminum and SiC powders is done at elevated temperature and the usage is at room temperature. A thermal stress state arises in the composite due to the different thermal expansion coefficients of the materials. Due to the particles size and randomness in the SiC distribution, some sets of models were analyzed and a statistical procedure used to evaluate the average stress state in the composite. In each model the particles position, form and size are randomly generated considering a volumetric ratio (VR) between 20% and 25%, close to an actual composite. The obtained stress field is represented by a certain number of iso stress curves, each one weighted by the area it represents. Systematically it was investigated the influence of: (a) the material behavior: linear x non-linear; (b) the carbide particles form: circular x quadrilateral; (c) the number of iso stress curves considered in each analysis; and (e) the model size (the number of particles). Each of above analyzed condition produced conclusions to guide the next step. Considering a confidence level of 95%, the average thermal stress value in the studied composite (20% ≤ VR ≤ 25%) is 175 MPa with a standard deviation of 10 MPa. Depending on its usage, this value should be taken into account when evaluating the material strength. (author)

  20. Thermodynamic and economic optimization of LNG mixed refrigerant processes

    International Nuclear Information System (INIS)

    Wang, Mengyu; Khalilpour, Rajab; Abbas, Ali

    2014-01-01

    Highlights: • We study performance and cost optimization of C3MR and DMR processes. • A new economic objective function is proposed to reduce both compression work and equipment size. • The comparison of C3MR and DMR processes is based on process configuration, performance, and cost. - Abstract: Natural gas liquefaction processes are energy and cost intensive. This paper performs thermodynamic and economic optimization of the mid-scale mixed refrigerant cycles including propane precooled mixed refrigerant (C3MR) and dual mixed refrigerant (DMR) processes. Four different objective functions in this study are selected: total shaft work consumption, total cost investment (TCI), total annualized cost (TAC), and total capital cost of compressors and main cryogenic exchangers (MCHEs). Total cost investment (TCI) is a function of two key variables: shaft work (W) and overall heat transfer coefficient and area (UA) of MCHEs. It is proposed for reducing energy consumption and simultaneously minimizing total capital expenditure (CAPEX) and operating expenditure (OPEX). Total shaft work objective function can result in a 44.5% reduction of shaft work for C3MR and a 48.6% reduction for DMR compared to their baseline values, but infinitely high UA of MCHEs. Optimal results show that total capital cost of compressors and MCHEs is more suitable than other objective functions for the objective of reducing both shaft work and UA. It reduces 14.5% of specific power for C3MR and 26.7% for DMR when achieving the relatively lower UA values than their baseline values. In addition, TCI and TAC can also reduce a certain amount of total shaft work at a finite increased UA

  1. Mixing process of a binary gas in a density stratified layer

    Energy Technology Data Exchange (ETDEWEB)

    Takeda, Tetsuaki [Japan Atomic Energy Research Inst., Oarai, Ibaraki (Japan). Oarai Research Establishment

    1997-09-01

    This study is to investigate the effect of natural convection on the mixing process by molecular diffusion in a vertical stratified layer of a binary fluid. There are many experimental and analytical studies on natural convection in the vertical fluid layer. However, there are few studies on natural convection with molecular diffusion in the vertical stratified layer of a binary gas. Experimental study has been performed on the combined phenomena of molecular diffusion and natural convection in a binary gas system to investigate the mixing process of the binary gas in a vertical slot consisting of one side heated and the other side cooled. The range of Rayleigh number based on the slot width was about 0 < Ra{sub d} < 7.5 x 10{sup 4}. The density change of the gas mixture and the temperature distribution in the slot was obtained and the mixing process when the heavier gas ingress into the vertical slot filled with the lighter gas from the bottom side of the slot was discussed. The experimental results showed that the mixing process due to molecular diffusion was affected significantly by the natural convection induced by the slightly temperature difference between both vertical walls even if a density difference by the binary gas is larger than that by the temperature difference. (author). 81 refs.

  2. Simulation of Thermal-hydraulic Process in Reactor of HTR-PM

    International Nuclear Information System (INIS)

    Zhou Kefeng; Zhou Yangping; Sui Zhe; Ma Yuanle

    2014-01-01

    This paper provides the physical process in the reactor of High Temperature Gas-cooled Reactor Pebble-bed Module (HTR-PM) and introduces the standard operation conditions. The FORTRAN code developed for the thermal hydraulic module of Full-Scale Simulator (FSS) of HTR-PM is used to simulate two typical operation transients including cold startup process and cold shutdown process. And the results were compared to the safety analysis code, namely TINTE. The good agreement indicates that the code is applicable for simulating the thermal-hydraulic process in reactor of HTR-PM. And for long time transient process, the code shows good stability and convergence. (author)

  3. Subgrid models for mass and thermal diffusion in turbulent mixing

    Energy Technology Data Exchange (ETDEWEB)

    Sharp, David H [Los Alamos National Laboratory; Lim, Hyunkyung [STONY BROOK UNIV; Li, Xiao - Lin [STONY BROOK UNIV; Gilmm, James G [STONY BROOK UNIV

    2008-01-01

    We are concerned with the chaotic flow fields of turbulent mixing. Chaotic flow is found in an extreme form in multiply shocked Richtmyer-Meshkov unstable flows. The goal of a converged simulation for this problem is twofold: to obtain converged solutions for macro solution features, such as the trajectories of the principal shock waves, mixing zone edges, and mean densities and velocities within each phase, and also for such micro solution features as the joint probability distributions of the temperature and species concentration. We introduce parameterized subgrid models of mass and thermal diffusion, to define large eddy simulations (LES) that replicate the micro features observed in the direct numerical simulation (DNS). The Schmidt numbers and Prandtl numbers are chosen to represent typical liquid, gas and plasma parameter values. Our main result is to explore the variation of the Schmidt, Prandtl and Reynolds numbers by three orders of magnitude, and the mesh by a factor of 8 per linear dimension (up to 3200 cells per dimension), to allow exploration of both DNS and LES regimes and verification of the simulations for both macro and micro observables. We find mesh convergence for key properties describing the molecular level of mixing, including chemical reaction rates between the distinct fluid species. We find results nearly independent of Reynolds number for Re 300, 6000, 600K . Methodologically, the results are also new. In common with the shock capturing community, we allow and maintain sharp solution gradients, and we enhance these gradients through use of front tracking. In common with the turbulence modeling community, we include subgrid scale models with no adjustable parameters for LES. To the authors' knowledge, these two methodologies have not been previously combined. In contrast to both of these methodologies, our use of Front Tracking, with DNS or LES resolution of the momentum equation at or near the Kolmogorov scale, but without

  4. An analytically resolved model of a potato's thermal processing using Heun functions

    Science.gov (United States)

    Vargas Toro, Agustín.

    2014-05-01

    A potato's thermal processing model is solved analytically. The model is formulated using the equation of heat diffusion in the case of a spherical potato processed in a furnace, and assuming that the potato's thermal conductivity is radially modulated. The model is solved using the method of the Laplace transform, applying Bromwich Integral and Residue Theorem. The temperatures' profile in the potato is presented as an infinite series of Heun functions. All computations are performed with computer algebra software, specifically Maple. Using the numerical values of the thermal parameters of the potato and geometric and thermal parameters of the processing furnace, the time evolution of the temperatures in different regions inside the potato are presented analytically and graphically. The duration of thermal processing in order to achieve a specified effect on the potato is computed. It is expected that the obtained analytical results will be important in food engineering and cooking engineering.

  5. Development of a novel wet oxidation process for hazardous and mixed wastes

    International Nuclear Information System (INIS)

    Dhooge, P.M.

    1994-01-01

    Many DOE waste streams and remediates contain complex and variable mixtures of organic compounds, toxic metals, and radionuclides. These materials are often dispersed in organic or inorganic matrices, such as personal protective equipment, various sludges, soils, and water. The over all objective of the effort described here is to develop a novel catalytic wet oxidation process for the treatment of these multi-component wastes, with the aim of providing a versatile, non-thermal method which will destroy hazardous organic compounds while simultaneously containing and concentrating toxic and radioactive metals for recovery or disposal in a readily stabilized matrix. The DETOX process uses a unique combination of metal catalysts to increase the rate of oxidation of organic materials. The metal catalysts are in the form of salts dissolved in a dilute acid solution. A typical catalyst composition is 60% ferric chloride, 3--4% hydrochloric acid, 0.13% platinum ions, and 0.13% ruthenium ions in a water solution. The catalyst solution is maintained at 423--473 K. Wastes are introduced into contact with the solution, where their organic portion is oxidized to carbon dioxide and water. If the organic portion is chlorinated, hydrogen chloride will be produced as a product. The process is a viable alternative to incineration for the treatment of organic mixed wastes. Estimated costs for waste treatment using the process are from $2.50/kg to $25.00/kg, depending on the size of the unit and the amount of waste processed. Process units can be mobile for on-site treatment of wastes. Results from phase 1 and 2, design and engineering studies, are described

  6. Response of six neutron survey meters in mixed fields of fast and thermal neutrons.

    Science.gov (United States)

    Kim, S I; Kim, B H; Chang, I; Lee, J I; Kim, J L; Pradhan, A S

    2013-10-01

    Calibration neutron fields have been developed at KAERI (Korea Atomic Energy Research Institute) to study the responses of commonly used neutron survey meters in the presence of fast neutrons of energy around 10 MeV. The neutron fields were produced by using neutrons from the (241)Am-Be sources held in a graphite pile and a DT neutron generator. The spectral details and the ambient dose equivalent rates of the calibration fields were established, and the responses of six neutron survey meters were evaluated. Four single-moderator-based survey meters exhibited an under-responses ranging from ∼9 to 55 %. DINEUTRUN, commonly used in fields around nuclear reactors, exhibited an over-response by a factor of three in the thermal neutron field and an under-response of ∼85 % in the mixed fields. REM-500 (tissue-equivalent proportional counter) exhibited a response close to 1.0 in the fast neutron fields and an under-response of ∼50 % in the thermal neutron field.

  7. Application of volume-weighted skew-upwind differencing to thermal and fluid mixing in the cold leg and downcomer of a PWR

    International Nuclear Information System (INIS)

    Chen, F.F.; Miao, C.C.; Chen, B.C.J.; Domanus, H.M.; Lyczkowski, R.W.; Sha, W.T.

    1983-01-01

    Upwind differencing has been the most common numerical scheme used in computational fluid flow and heat transfer in past years. However, the numerical diffusion induced by the use of upwind differencing can be significant in problems involving thermal mixing. Thermal and fluid mixing in a pressurized water reactor during high pressurized coolant injection is a typical example where numerical diffusion is significant. An improved volume-weighted skew-upwind differencing is used here to reduce numerical diffusion without overshooting or undershooting which is the major defect of original skew-upwind differencing proposed by Raithby. The basic concept of volume-weighted skew-upwind differencing is shown. Computations were performed using COMMIX-1B, an extended version of the COMMIX-1A. The experiment analyzed here is test No. 1 of the SAI experiment

  8. Viscous and thermal modelling of thermoplastic composites forming process

    Science.gov (United States)

    Guzman, Eduardo; Liang, Biao; Hamila, Nahiene; Boisse, Philippe

    2016-10-01

    Thermoforming thermoplastic prepregs is a fast manufacturing process. It is suitable for automotive composite parts manufacturing. The simulation of thermoplastic prepreg forming is achieved by alternate thermal and mechanical analyses. The thermal properties are obtained from a mesoscopic analysis and a homogenization procedure. The forming simulation is based on a viscous-hyperelastic approach. The thermal simulations define the coefficients of the mechanical model that depend on the temperature. The forming simulations modify the boundary conditions and the internal geometry of the thermal analyses. The comparison of the simulation with an experimental thermoforming of a part representative of automotive applications shows the efficiency of the approach.

  9. Four-phonon processes in the thermal conductivity of GaSb

    International Nuclear Information System (INIS)

    Aliev, M.I.; Arasly, D.G.; Guseinov, R.E.

    1978-01-01

    Phonon thermal conductivity of GaSb in the 300-700 K temperature range is studied by the light pulsed heating which is aimed at estimation of contributions of different polarized branches of acoustic oscillations into lattice thermal conductivity. The role of optico-acoustic interactions and multiphonon processes in phonon-phonon scattering at high temperatures is discussed. It is shown that the X thermal conductivity caused by the current carriers is negligibly small, and the Xsub(ph) phonon conductivity changes depending on temperature according to the Xsub(ph) approximately Tsup(-1.4) law. While calculating Xsub(ph) according to the Holland model taking into account phonon scattering on point defects the phonon thermal conductivity is given as a sum of contributions from longitudinal and transverse low-frequency Xsub(th1) and high-frequency Xsub(th2) acoustic phonons. It is established that at T>500 K Xsub(ph) is caused only by high-frequency transverse phonons and to explain the observed Xsub(ph) dependence on temperature it is necessary to introduce four-phonon process along with the three-phonon processes into intraphonon scattering

  10. Development of a virtual metrology for high-mix TFT-LCD manufacturing processes

    International Nuclear Information System (INIS)

    Chen Shan; Pan Tianhong; Jang Shishang

    2010-01-01

    Nowadays, TFT-LCD manufacturing has become a very complex process, in which many different products being manufactured with many different tools. The ability to predict the quality of product in such a high-mix system is critical to developing and maintaining a high yield. In this paper, a statistical method is proposed for building a virtual metrology model from a number of products using a high-mix manufacturing process. Stepwise regression is used to select 'key variables' that really affect the quality of the products. Multivariate analysis of covariance is also proposed for simultaneously applying the selected variables and product effect. This framework provides a systematic method of building a processing quality prediction system for a high-mix manufacturing process. The experimental results show that the proposed quality prognostic system can not only estimate the critical dimension accurately but also detect potentially faulty glasses.

  11. Multi-pass TIG welding process: simulating thermal SS304

    International Nuclear Information System (INIS)

    Harinadh, Vemanaboina; Akella, S.; Buddu, Ramesh Kumar; Edision, G.

    2015-01-01

    Welding is basic requirement in the construction of nuclear reactors, power plants and structural components development. A basic studies on various aspects of the welding is essential to ensure the stability and structural requirement conditions. The present study explored the thermo-mechanical analysis of the multipass welds of austenitic stainless steels which are widely used in fusion and fission reactor components development. A three-dimensional (3D) finite element model is developed to investigate thermally induced stress field during TIG welding process for SS304 material. The transient thermal analysis is performed to obtain the temperature history, which then is applied to the mechanical (stress) analysis. The present thermal analysis is conducted using element type DC3D8. This element type has a three dimensional thermal conduction capability and eight nodes. The 6 mm thick plated is welded with six numbers of passes. The geometry and meshed model with tetrahedral shape with volume sweep. The analysis is on TIG welding process using 3D-weld interface plug-in on ABAQUS-6.14. The results are reported in the present paper

  12. Groundwater Mixing Process Identification in Deep Mines Based on Hydrogeochemical Property Analysis

    Directory of Open Access Journals (Sweden)

    Bo Liu

    2016-12-01

    Full Text Available Karst collapse columns, as a potential water passageway for mine water inrush, are always considered a critical problem for the development of deep mining techniques. This study aims to identify the mixing process of groundwater deriving two different limestone karst-fissure aquifer systems. Based on analysis of mining groundwater hydrogeochemical properties, hydraulic connection between the karst-fissure objective aquifer systems was revealed. In this paper, piper diagram was used to calculate the mixing ratios at different sampling points in the aquifer systems, and PHREEQC Interactive model (Version 2.5, USGS, Reston, VA, USA, 2001 was applied to modify the mixing ratios and model the water–rock interactions during the mixing processes. The analysis results show that the highest mixing ratio is 0.905 in the C12 borehole that is located nearest to the #2 karst collapse column, and the mixing ratio decreases with the increase of the distance from the #2 karst collapse column. It demonstrated that groundwater of the two aquifers mixed through the passage of #2 karst collapse column. As a result, the proposed Piper-PHREEQC based method can provide accurate identification of karst collapse columns’ water conductivity, and can be applied to practical applications.

  13. Fossilization Processes in Thermal Springs

    Science.gov (United States)

    Farmer, Jack D.; Cady, Sherry; Desmarais, David J.; Chang, Sherwood (Technical Monitor)

    1995-01-01

    surfaces that produce palisade and "shrub" fabrics, respectively. At finer scales, composite fabrics are seen to consist distinctive associations of microstructures formed by the encrustation of individual cells and filaments. Composite fabrics survive the diagenetic transitions from primary opaline silica to quartz and are known from subaerial thermal spring deposits as old as Lower Carboniferous. However, fossil microorganisms tend to be rare in older deposits, and are usually preserved only where cells or sheaths have been stained by iron oxides. In subaqueous mineralizing springs at lower temperatures, early infilling leads to a more rapid and complete reduction in porosity and permeability. This process, along with the slower rates of microbial degradation at lower temperatures, creates a more favorable situation for organic matter preservation. Application of this taphonomic model to the Rhynie Chert, previously interpreted as subaerial, suggest it was probably deposited in a subaqueous spring setting at lower temperatures.

  14. Solar engineering of thermal processes

    CERN Document Server

    Duffie, John A

    2013-01-01

    The updated fourth edition of the ""bible"" of solar energy theory and applications Over several editions, Solar Engineering of Thermal Processes has become a classic solar engineering text and reference. This revised Fourth Edition offers current coverage of solar energy theory, systems design, and applications in different market sectors along with an emphasis on solar system design and analysis using simulations to help readers translate theory into practice. An important resource for students of solar engineering, solar energy, and alternative energy as well

  15. Mixed waste treatment with a mediated electrochemical process

    International Nuclear Information System (INIS)

    Hickman, R.G.; Gray, L.W.; Chiba, Z.

    1991-01-01

    The process described in this paper is intended to convert mixed waste containing toxic organic compounds (not heavy metals) to ordinary radioactive waste, which is treatable. The process achieves its goal by oxidizing hydrocarbons to CO 2 and H 2 O. Other atoms that may be present in the toxic organic generally are converted to nonhazardous anions such as sulfate and phosphate. This electro chemical conversion is performed at conditions of temperature and pressure that are just moderately above ambient conditions. Gaseous hydroxides and oxyhydroxides that are formed by many radionuclides during incineration cannot form in this process. 1 ref., 3 figs

  16. Thermal load determination in the mixing TEE impacted by a turbulent flow generated by two fluids at large gap of temperature

    International Nuclear Information System (INIS)

    Braillard, O.

    2005-01-01

    A 304L mixing tee mock-up is instrumented to assess the fluctuating temperature in the mixing area generated by two fluids (water) at large gap of temperature meet. The turbulent mixing layer impacts the structure wall and creates stresses, which lead to the damages. The case studied in this paper corresponds to the 'swinging streak' within a flow rate ratio of 25 %. The instrumentation is specifically planned to measure the fluctuating temperature in the fluid close to the internal skin and inside the wall too. This experiment is performed using a new sensor 'fluxmeter' which is non intrusive and typically designed to catch the fluctuation without any signal attenuation, within a frequency range 0-25Hz. The facility called 'Fatherino' supplies an available delta T of 70 degree C in water at 4 m/s mixture velocity in a mixing tee mock-up 50 mm in diameter. The flow features generate a large turbulent flow in the mixing layer and favour the heat flux transfer to the wall. By applying an inverse heat conduction method applied to the output data given by the fluxmeter, both the heat flux is deduced and the temperature (mean and fluctuating values) at the internal surface can be accurately determined. In addition, a calculation using the Trio U code (thermal hydraulic code) within the large eddy simulation module is computed to assess the fluid temperature distribution in the mixing area close to the internal surface. The output data in mean and standard deviation are compared with the Fatherino measurements. The comparison consists in analysing the main parameters as the mean and standard deviation in the fluid along the main axis and in a circumferential view. The mixing layer geometry and the frequency of the fluctuation are also analysed. These experiments added to the calculation allow us improving the state of the knowledge in the mixing tees and the thermal load to be used in the industrial mixing tees in operating for the long lifetime assessment or for the

  17. Mixing processes at the subsurface layer in the Amundsen Sea shelf region

    Science.gov (United States)

    Mojica, J.; Djoumna, G.; Francis, D. K.; Holland, D.

    2017-12-01

    In the Amundsen Sea shelf region, mixing processes promote an upward transport of diapycnal fluxes of heat and salt from the subsurface to the surface mixing layer. Here we estimate the diapycnal mixing rates on the Amundsen shelf from a multi-year mooring cluster and five research cruises. By applying fine-scale parameterizations, the mixing rates obtained were higher near the southern end of Pine Island glacier front and exceeded 10-2 m2s-1. The eddy diffusivity increased near the critical latitude (74o 28' S) for semi-diurnal M2 tides, which coincided with near-critical topography on the shelf. This condition favored the generation of internal waves of M2 frequency. The semi-diurnal dynamic enhanced the mixing that potentially affected the heat budget and the circulation of the modified Circumpolar Deep Water. This can be observed in the characteristics of water exchange both below the ice shelves and between the continental shelf and the ice shelf cavities. The location of the critical latitude and critical topography provided favorable conditions for the generation of internal waves. KEYWORDS: Mixing processes, diapycnal fluxes, critical latitude, Circumpolar Deep Water.

  18. Performance of thermal solvent process in Athabasca reservoir

    Energy Technology Data Exchange (ETDEWEB)

    Das, Swapan [Marathon Oil (Canada)

    2011-07-01

    In the petroleum industry, due to depletion of conventional resources and high demand operators are looking into heavy oil and bitumen production. Different recovery methods exist, some of them based on heating the reservoir and others on the use of solvent. Thermal solvent process is a combination of both: a small amount of heat is used to maintain a solvent vapor phase in the reservoir. This process has advantages, solvent is mostly recycled which increases bitumen recovery efficiency and reduces the need for fresh solvent, but it also poses challenges, such as maintaining a vapor chamber and the fact that solvent solubility might be affected by heating. The aim of this paper is to discuss these issues. Simulations and field tests were conducted on bitumen in the the Athabasca region. This paper presented a thermal solvent process and its application's results in Athabasca reservoir.

  19. Synthesis report on thermally driven coupled processes

    International Nuclear Information System (INIS)

    Hardin, E.L.

    1997-01-01

    The main purpose of this report is to document observations and data on thermally coupled processes for conditions that are expected to occur within and around a repository at Yucca Mountain. Some attempt is made to summarize values of properties (e.g., thermal properties, hydrologic properties) that can be measured in the laboratory on intact samples of the rock matrix. Variation of these properties with temperature, or with conditions likely to be encountered at elevated temperature in the host rock, is of particular interest. However, the main emphasis of this report is on direct observation of thermally coupled processes at various scales. Direct phenomenological observations are vitally important in developing and testing conceptual models. If the mathematical implementation of a conceptual model predicts a consequence that is not observed, either (1) the parameters or the boundary conditions used in the calculation are incorrect or (2) the conceptual basis of the model does not fit the experiment; in either case, the model must be revised. For example, the effective continuum model that has been used in thermohydrology studies combines matrix and fracture flow in a way that is equivalent to an assumption that water is imbibed instantaneously from fractures into adjacent, partially saturated matrix. Based on this approximation, the continuum-flow response that is analogous to fracture flow will not occur until the effective continuum is almost completely saturated. This approximation is not entirely consistent with some of the experimental data presented in this report. This report documents laboratory work and field studies undertaken in FY96 and FY97 to investigate thermally coupled processes such as heat pipes and fracture-matrix coupling. In addition, relevant activities from past years, and work undertaken outside the Yucca Mountain project are summarized and discussed. Natural and artificial analogs are also discussed to provide a convenient source of

  20. Numerical investigation of solid mixing in a fluidized bed coating process

    Science.gov (United States)

    Kenche, Venkatakrishna; Feng, Yuqing; Ying, Danyang; Solnordal, Chris; Lim, Seng; Witt, Peter J.

    2013-06-01

    Fluidized beds are widely used in many process industries including the food and pharmaceutical sectors. Despite being an intensive research area, there are no design rules or correlations that can be used to quantitatively predict the solid mixing in a specific system for a given set of operating conditions. This paper presents a numerical study of the gas and solid dynamics in a laboratory scale fluidized bed coating process used for food and pharmaceutical industries. An Eulerian-Eulerian model (EEM) with kinetic theory of granular flow is selected as the modeling technique, with the commercial computational fluid dynamics (CFD) software package ANSYS/Fluent being the numerical platform. The flow structure is investigated in terms of the spatial distribution of gas and solid flow. The solid mixing has been evaluated under different operating conditions. It was found that the solid mixing rate in the horizontal direction is similar to that in the vertical direction under the current design and operating conditions. It takes about 5 s to achieve good mixing.

  1. Correlation of Steam Generator Mixing Parameters for Severe Accident Hot-Leg Natural Circulation

    Energy Technology Data Exchange (ETDEWEB)

    Liao, Yehong; Guentay, Salih [Paul Scherrer Institut, Villigen PSI, CH-5232 (Switzerland)

    2008-07-01

    Steam generator inlet plenum mixing phenomenon with hot-leg counter-current natural circulation during a PWR station blackout severe accident is one of the important processes governing which component will fail first as a result of thermal challenge from the circulating gas with high temperature and pressure. Since steam generator tube failure represents bypass release of fission product from the reactor to environment, study of inlet plenum mixing parameters is important to risk analysis. Probability distribution functions of individual mixing parameter should be obtained from experiments or calculated by analysis. In order to perform sensitivity studies of the synergetic effects of all mixing parameters on the severe accident-induced steam generator tube failure, the distribution and correlation of these mixing parameters must be known to remove undue conservatism in thermal-hydraulic calculations. This paper discusses physical laws governing three mixing parameters in a steady state and setups the correlation among these mixing parameters. The correlation is then applied to obtain the distribution of one of the mixing parameters that has not been given in the previous CFD analysis. Using the distributions and considering the inter-dependence of the three mixing parameters, three sensitivity cases enveloping the mixing parameter uncertainties are recommended for the plant analysis. (authors)

  2. Mixed ligand lanthanide complexes with dipivaloylmethane and acetic acid

    International Nuclear Information System (INIS)

    Lyu Fehnkhua; Kuz'mina, N.P.; Mazo, G.N.; Martynenko, L.I.

    1995-01-01

    Methods of elemental, X-ray phase, thermal analyses and infrared spectroscopy were used to characterize solid products, formed in MDpm 3 -HAcet-H-hexane systems (M = Pr, Nd, Eu, Gd, Ho, Er, Yb, HDpm -dipivaloylmethane, HAcet - acetic acid). It was established that prepared mixed ligand complexes (MLC) had MDpm 2 Acet composition for all studied rare earths. Differenced in properties of cerium and yttrium rare earths are manifested in processes of MLC thermal dissociation, proceeding at low pressure and 170 deg C. 6 refs., 4 tabs

  3. Basic properties of the mixed oxides obtained by thermal decomposition of hydrotalcites containing different metallic compositions

    Energy Technology Data Exchange (ETDEWEB)

    Valente, J.S.; Figueras, F.; Gravelle, M.; Kumbhar, P.; Lopez, J.; Besse, J.P.

    2000-01-25

    Carbonated layered double hydroxides (LDHs) containing Al, Fe, or Cr in a Mg(OH){sub 2} matrix or Al dissolved in hydroxides of Mg, Cu, Ni, Co, or Zn are used as precursors of basic catalysts. Decarbonation is studied by thermal analysis. The average basic strength, evaluated by the decarbonation temperature, is related to the partial charge of oxygen in the LDHs obtained from the Sanderson theory of electronegativity. The enthalpy of adsorption of CO{sub 2} on the resulting mixed oxides is measured by calorimetry. A homogeneous surface is generally observed for CO{sub 2} adsorption, with initial heats of adsorption close to those reported for MgO. The number of sites determined by this method is proportional to the rate constants for {beta}-isophorone isomerization, suggesting that both techniques measure surface properties. The layered structure in which OH{sup {minus}} is the compensating anion can be re-formed by hydration. This process does not appreciably change the adsorption of CO{sub 2}; thus, oxygens and hydroxyls show similar basic strengths in this case.

  4. Thermally-driven Coupled THM Processes in Shales

    Science.gov (United States)

    Rutqvist, J.

    2017-12-01

    Temperature changes can trigger strongly coupled thermal-hydrological-mechanical (THM) processes in shales that are important to a number of subsurface energy applications, including geologic nuclear waste disposal and hydrocarbon extraction. These coupled processes include (1) direct pore-volume couplings, by thermal expansion of trapped pore-fluid that triggers instantaneous two-way couplings between pore fluid pressure and mechanical deformation, and (2) indirect couplings in terms of property changes, such as changes in mechanical stiffness, strength, and permeability. Direct pore-volume couplings have been studied in situ during borehole heating experiments in shale (or clay stone) formations at Mont Terri and Bure underground research laboratories in Switzerland and France. Typically, the temperature changes are accompanied with a rapid increase in pore pressure followed by a slower decrease towards initial (pre-heating) pore pressure. Coupled THM modeling of these heater tests shows that the pore pressure increases because the thermal expansion coefficient of the fluid is much higher than that of the porous clay stone. Such thermal pressurization induces fluid flow away from the pressurized area towards areas of lower pressure. The rate of pressure increase and magnitude of peak pressure depends on the rate of heating, pore-compressibility, and permeability of the shale. Modeling as well as laboratory experiments have shown that if the pore pressure increase is sufficiently large it could lead to fracturing of the shale or shear slip along pre-existing bedding planes. Another set of data and observations have been collected associated with studies related to concentrated heating and cooling of oil-shales and shale-gas formations. Heating may be used to enhance production from tight oil-shale, whereas thermal stimulation has been attempted for enhanced shale-gas extraction. Laboratory experiments on shale have shown that strength and elastic deformation

  5. Isoconversional kinetics of thermally stimulated processes

    CERN Document Server

    Vyazovkin, Sergey

    2015-01-01

    The use of isoconversional kinetic methods for analysis of thermogravimetric and calorimetric data on thermally stimulated processes is quickly growing in popularity. The purpose of this book is to create the first comprehensive resource on the theory and applications of isoconversional methodology. The book introduces the reader to the kinetics of physical and chemical condensed phase processes that occur as a result of changing temperature and discusses how isoconversional analysis can provide important kinetic insights into them. The book will help the readers to develop a better understanding of the methodology, and promote its efficient usage and successful development.

  6. Four-wave mixing and phase conjugation in plasmas

    International Nuclear Information System (INIS)

    Federici, J.F.

    1989-01-01

    Nonlinear optical effects such as Stimulated Brillouin Scattering, Stimulated Raman Scattering, self-focusing, wave-mixing, parametric mixing, etc., have a long history in plasma physics. Recently, four-wave mixing in plasmas and its applications to phase conjugation has been extensively studied. Although four-wave mixing (FWM), using various nonlinear mediums, has many practical applications in the visible regime, no successful attempt has been made to study or demonstrate FWM for wavelengths longer than 10μm. Plasmas as phase conjugate mirrors have received considerable attention since they become more efficient at longer wavelengths (far-infrared to microwave). The purpose of this thesis is to study various fundamental issues which concern the suitability of plasmas for four-wave mixing and phase conjugation. The major contributions of this thesis are the identification and study of thermal and ionization nonlinearities as potential four-wave mixing and phase conjugation mechanisms and the study of the affect of density inhomogeneities on the FWM process. Using a fluid description for the plasma, this thesis demonstrates that collisional heating generates a thermal force which substantially enhances the phase conjugate reflectivity. The prospect of using a novel ionization nonlinearity in weakly ionized plasmas for wave-mixing and phase conjugation is discussed. The ionization nonlinearity arises from localized heating of the plasma by the beat-wave. Wherever, the local temperature is increased, a plasma density grating is produced due to increased electron-impact ionization. Numerical estimates of the phase conjugate reflectivity indicate reflectivities in the range of 10 -4 -10 -3 are possible in a weakly ionized steady-state gas discharge plasma

  7. Thermal food processing: new technologies and quality issues

    National Research Council Canada - National Science Library

    Sun, Da-Wen

    2012-01-01

    .... The editor of Thermal Food Processing: New Technologies and Quality Issues presents a comprehensive reference through authors that assist in meeting this challenge by explaining the latest developments and analyzing the latest trends...

  8. Thermal-hydraulic analysis of PWR small assembly for irradiation test of CARR

    International Nuclear Information System (INIS)

    Yin Hao; Zou Yao; Liu Xingmin

    2015-01-01

    The thermal-hydraulic behaviors of the PWR 4 × 4 small assembly tested in the high temperature and high pressure loop of China Advanced Research Reactor were analyzed. The CFD method was used to carry out 3D simulation of the model, thus detailed thermal-hydraulic parameters were obtained. Firstly, the simplified model was simulated to give the 3D temperature and velocity distributions and analyze the heat transfer process. Then the whole scale small assembly model was simulated and the simulation results were compared with those of simplified rod bundle model. Its flow behavior was studied and flow mixing characteristics of the grids were analyzed, and the mixing factor of the grid was calculated and can be used for further thermal-hydraulic study. It is shown that the highest temperature of the fuel rod meets the design limit and the mixing effect of the grid is obvious. (authors)

  9. Thermal-hydraulic posttest analysis for the ANL/MCTF 3600 model heat-exchanger water test under mixed convection

    International Nuclear Information System (INIS)

    Yang, C.I.; Sha, W.T.; Kasza, K.E.

    1982-01-01

    As a result of the uncertainties in the understanding of the influence of thermal-buoyancy effects on the flow and heat transfer in Liquid Metal Fast Breeder Reactor heat exchangers and steam generators under off-normal operating conditions, an extensive experimental program is being conducted at Argonne National Laboratory to eliminate these uncertainties. Concurrently, a parallel analytical effort is also being pursued to develop a three-dimensional transient computer code (COMMIX-IHX) to study and predict heat exchanger performance under mixed, forced, and free convection conditions. This paper presents computational results from a heat exchanger simulation and compares them with the results from a test case exhibiting strong thermal buoyancy effects. Favorable agreement between experiment and code prediction is obtained

  10. The processing of aluminum gasarites via thermal decomposition of interstitial hydrides

    Science.gov (United States)

    Licavoli, Joseph J.

    Gasarite structures are a unique type of metallic foam containing tubular pores. The original methods for their production limited them to laboratory study despite appealing foam properties. Thermal decomposition processing of gasarites holds the potential to increase the application of gasarite foams in engineering design by removing several barriers to their industrial scale production. The following study characterized thermal decomposition gasarite processing both experimentally and theoretically. It was found that significant variation was inherent to this process therefore several modifications were necessary to produce gasarites using this method. Conventional means to increase porosity and enhance pore morphology were studied. Pore morphology was determined to be more easily replicated if pores were stabilized by alumina additions and powders were dispersed evenly. In order to better characterize processing, high temperature and high ramp rate thermal decomposition data were gathered. It was found that the high ramp rate thermal decomposition behavior of several hydrides was more rapid than hydride kinetics at low ramp rates. This data was then used to estimate the contribution of several pore formation mechanisms to the development of pore structure. It was found that gas-metal eutectic growth can only be a viable pore formation mode if non-equilibrium conditions persist. Bubble capture cannot be a dominant pore growth mode due to high bubble terminal velocities. Direct gas evolution appears to be the most likely pore formation mode due to high gas evolution rate from the decomposing particulate and microstructural pore growth trends. The overall process was evaluated for its economic viability. It was found that thermal decomposition has potential for industrialization, but further refinements are necessary in order for the process to be viable.

  11. Mixed Convective Fully Developed Flow in a Vertical Channel in the Presence of Thermal Radiation and Viscous Dissipation

    Directory of Open Access Journals (Sweden)

    Prasad K.V.

    2017-02-01

    Full Text Available The effect of thermal radiation and viscous dissipation on a combined free and forced convective flow in a vertical channel is investigated for a fully developed flow regime. Boussinesq and Roseseland approximations are considered in the modeling of the conduction radiation heat transfer with thermal boundary conditions (isothermal-thermal, isoflux-thermal, and isothermal-flux. The coupled nonlinear governing equations are also solved analytically using the Differential Transform Method (DTM and regular perturbation method (PM. The results are analyzed graphically for various governing parameters such as the mixed convection parameter, radiation parameter, Brinkman number and perturbation parameter for equal and different wall temperatures. It is found that the viscous dissipation enhances the flow reversal in the case of a downward flow while it counters the flow in the case of an upward flow. A comparison of the Differential Transform Method (DTM and regular perturbation method (PM methods shows the versatility of the Differential Transform Method (DTM. The skin friction and the wall temperature gradient are presented for different values of the physical parameters and the salient features are analyzed.

  12. Modelling and Control of Thermal System

    Directory of Open Access Journals (Sweden)

    Vratislav Hladky

    2014-01-01

    Full Text Available Work presented here deals with the modelling of thermal processes in a thermal system consisting of direct and indirect heat exchangers. The overal thermal properties of the medium and the system itself such as liquid mixing or heat capacity are shortly analysed and their features required for modelling are reasoned and therefore simplified or neglected. Special attention is given to modelling heat losses radiated into the surroundings through the walls as they are the main issue of the effective work with the heat systems. Final part of the paper proposes several ways of controlling the individual parts’ temperatures as well as the temperature of the system considering heating elements or flowage rate as actuators.

  13. INTERACTION OF IRON(II MIXED-LIGAND COMPLEXES WITH DNA: BASE-PAIR SPECIFICITY AND THERMAL DENATURATION STUDIES

    Directory of Open Access Journals (Sweden)

    Mudasir Mudasir

    2010-06-01

    Full Text Available A research about base-pair specificity of the DNA binding of [Fe(phen3]2+, [Fe(phen2(dip]2+ and [Fe(phen(dip2]2+ complexes and the effect of calf-thymus DNA (ct-DNA binding of these metal complexes on thermal denaturation of ct-DNA has been carried out. This research is intended to evaluate the preferential binding of the complexes to the sequence of DNA (A-T or G-C sequence and to investigate the binding strength and mode upon their interaction with DNA. Base-pair specificity of the DNA binding of the complexes was determined by comparing the equilibrium binding constant (Kb of each complex to polysynthetic DNA that contain only A-T or G-C sequence. The Kb value of the interaction was determined by spectrophotometric titration and thermal denaturation temperature (Tm was determined by monitoring the absorbance of the mixture solution of each complex and ct-DNA at λ =260 nm as temperature was elevated in the range of 25 - 100 oC. Results of the study show that in general all iron(II complexes studied exhibit a base-pair specificity in their DNA binding to prefer the relatively facile A-T sequence as compared to the G-C one. The thermal denaturation experiments have demonstrated that Fe(phen3]2+ and [Fe(phen2(dip]2+ interact weakly with double helical DNA via electrostatic interaction as indicated by insignificant changes in melting temperature, whereas [Fe(phen2(dip]2+  most probably binds to DNA in mixed modes of interaction, i.e.: intercalation and electrostatic interaction. This conclusion is based on the fact that the binding of [Fe(phen2(dip]2+ to ct-DNA moderately increase the Tm value of ct- DNA   Keywords: DNA Binding, mixed-ligand complexes

  14. Plasma Hearth Process vitrification of DOE low-level mixed waste

    International Nuclear Information System (INIS)

    Gillins, R.L.; Geimer, R.M.

    1995-01-01

    The Plasma Hearth Process (PHP) demonstration project is one of the key technology projects in the Department of Energy (DOE) Office of Technology Development Mixed Waste Focus Area. The PHP is recognized as one of the more promising solutions to DOE's mixed waste treatment needs, with potential application in the treatment of a wide variety of DOE mixed wastes. The PHP is a high temperature vitrification process using a plasma arc torch in a stationary, refractory lined chamber that destroys organics and stabilizes the residuals in a nonleaching, vitrified waste form. This technology will be equally applicable to low-level mixed wastes generated by nuclear utilities. The final waste form will be volume reduced to the maximum extent practical, because all organics will have been destroyed and the inorganics will be in a high-density, low void-space form and little or no volume-increasing glass makers will have been added. Low volume and high integrity waste forms result in low disposal costs. This project is structured to ensure that the plasma technology can be successfully employed in radioactive service. The PHP technology will be developed into a production system through a sequence of tests on several test units, both non-radioactive and radioactive. As the final step, a prototype PHP system will be constructed for full-scale radioactive waste treatment demonstration

  15. The Chevron Foil Thrust Bearing: Improved Performance Through Passive Thermal Management and Effective Lubricant Mixing

    Science.gov (United States)

    Bruckner, Robert

    2013-01-01

    An improved foil thrust bearing is described that eliminates or reduces the need for forced cooling of the bearing foils while at the same time improves the load capacity of the bearing, enhances damping, provides overload tolerance, and eliminates the high speed load capacity drop-off that plagues the current state of the art. The performance improvement demonstrated by the chevron foil thrust bearing stems from a novel trailing edge shape that splays the hot lubricant in the thin film radially, thus preventing hot lubricant carry-over into the ensuing bearing sector. Additionally, the chevron shaped trailing edge induces vortical mixing of the hot lubricant with the gas that is naturally resident within the inter-pad region of a foil thrust bearing. The elimination of hot gas carry-over in combination with the enhanced mixing has enabled a completely passive thermally managed foil bearing design. Laboratory testing at NASA has confirmed the original analysis and reduced this concept to practice.

  16. Mars Surface Heterogeneity From Variations in Apparent Thermal Inertia

    Science.gov (United States)

    Putzig, N. E.; Mellon, M. T.

    2005-12-01

    Current techniques used in the calculation of thermal inertia from observed brightness temperatures typically assume that planetary surface properties are uniform on the scale of the instrument's observational footprint. Mixed or layered surfaces may yield different apparent thermal inertia values at different seasons or times of day due to the nonlinear relationship between temperature and thermal inertia. To obtain sufficient data coverage for investigating temporal changes, we processed three Mars years of observations from the Mars Global Surveyor Thermal Emission Spectrometer and produced seasonal nightside and dayside maps of apparent thermal inertia. These maps show broad regions with seasonal and diurnal differences as large as 200 J m-2 K-1 s-½ at mid-latitudes (60°S to 60°N) and ranging up to 600 J m-2 K-1 s-½ or greater in the polar regions. Comparison of the maps with preliminary results from forward-modeling of heterogeneous surfaces indicates that much of the martian surface may be dominated by (1) horizontally mixed surfaces, such as those containing differing proportions of rocks, sand, dust, duricrust, and localized frosts; (2) higher thermal inertia layers over lower thermal inertia substrates, such as duricrust or desert pavements; and (3) lower thermal inertia layers over higher thermal inertia substrates, such as dust over sand or rocks and soils with an ice table at depth.

  17. Heat transfer simulation and retort program adjustment for thermal processing of wheat based Haleem in semi-rigid aluminum containers.

    Science.gov (United States)

    Vatankhah, Hamed; Zamindar, Nafiseh; Shahedi Baghekhandan, Mohammad

    2015-10-01

    A mixed computational strategy was used to simulate and optimize the thermal processing of Haleem, an ancient eastern food, in semi-rigid aluminum containers. Average temperature values of the experiments showed no significant difference (α = 0.05) in contrast to the predicted temperatures at the same positions. According to the model, the slowest heating zone was located in geometrical center of the container. The container geometrical center F0 was estimated to be 23.8 min. A 19 min processing time interval decrease in holding time of the treatment was estimated to optimize the heating operation since the preferred F0 of some starch or meat based fluid foods is about 4.8-7.5 min.

  18. Thermal Shock Resistance of Stabilized Zirconia/Metal Coat on Polymer Matrix Composites by Thermal Spraying Process

    Science.gov (United States)

    Zhu, Ling; Huang, Wenzhi; Cheng, Haifeng; Cao, Xueqiang

    2014-12-01

    Stabilized zirconia/metal coating systems were deposited on the polymer matrix composites by a combined thermal spray process. Effects of the thicknesses of metal layers and ceramic layer on thermal shock resistance of the coating systems were investigated. According to the results of thermal shock lifetime, the coating system consisting of 20 μm Zn and 125 μm 8YSZ exhibited the best thermal shock resistance. Based on microstructure evolution, failure modes and failure mechanism of the coating systems were proposed. The main failure modes were the formation of vertical cracks and delamination in the outlayer of substrate, and the appearance of coating spallation. The residual stress, thermal stress and oxidation of substrate near the substrate/metal layer interface were responsible for coating failure, while the oxidation of substrate near the substrate/coating interface was the dominant one.

  19. INVESTIGATION ON UTILITY OF PLASTIC WASTE AS AN ADDITIVE FOR BITUMINOUS CONCRETE USING WET PROCESS OF MIXING

    Directory of Open Access Journals (Sweden)

    Anurag Virendra Tiwari

    2017-12-01

    Full Text Available Purpose. Plastic waste has become a major environmental issue of concern due to its exponential growth due to rapid urbanization. The paper investigates utility of plastic waste as an additive for bituminous concrete using wet process of mixing. Methodology. The methodology for the present paper has been designed with complex research consisting of Marshall mix design of the bituminous mix added with plastic waste for modifying bitumen using wet process of mixing, performing the tests on the samples and analyzing the results in the form of table and figures. In the present paper LDPE and HDPE type of plastic waste are used to modify the bitumen. Finding. The results show that addition of 6 percent of bitumen improves the Marshall properties of the mix. Use of plastic to modify the bitumen not only makes the road surface more durable but also it is an eco-friendly way of proper disposal of plastic waste. Originality. The processes used for mixing the plastic waste to the bitumen are dry process and wet process. Dry process of mixing the plastic waste to the bituminous mix is most common and lot of study is carried out on its application. In the present paper wet process of mixing has not yet been studied much. Practical Value. The practical application of utilizing the plastic waste to modify bitumen in the bituminous mix improves the stability values resulting in the more durable road surface. Also the method ensures the proper disposal of plastic waste in eco-friendly way.

  20. Experimental study for thermal striping phenomena of parallel triple-jet. Effects of the difference between hot jets and cold jet in discharged temperature and velocity on convective mixing

    International Nuclear Information System (INIS)

    Kimura, Nobuyuki; Tokuhiro, A.; Miyakoshi, Hiroyuki

    1996-10-01

    Elucidation on thermal hydraulic behavior of Thermal Striping is of importance for a reactor safety, which is arisen form exit temperature difference of fuel subassemblies. Since its temperature fluctuation may cause thermal cycle fatigue on upper internal structure (UIS). A series of experiments was performed using the Thermal Striping water test facility in order to investigate the mixing phenomena on three vertical jets with exit velocity and temperature differences. The parameters were the velocity and temperature of the jets at discharge nozzles. The local velocities were measured by Ultrasound Velocity Profile (UVP) monitor and Laser Doppler Anemometry (LDA), and temperature distributions were measured by thermocouples. This report mainly examined the experimental results of temperature measurements. There is a typical region where the gradient of the temperature variation in the triple-jet: that is the Convective Mixing region. This region is independent of the discharged temperature difference, and spreads with larger velocity difference among the jets. For isovelocity discharge conditions, non-dimensional temperature fields are almost independent of discharged temperature differences within Convective Mixing region. Consequently, the effect of temperature difference is negligible compared to that of velocity difference on the flow field. There are remarkable frequencies of 2-5Hz in temperature fluctuation due to a oscillation of the central jet (cold jet) for this condition. While, for non-isovelocity discharge condition, there are no remarkable frequencies. Hence, it is clear that there is the region where a large thermal fatigue is imposed by Thermal Striping against structures of Fast Reactor. It is suggested that the structures have to be placed outside of Convective Mixing region. Also, it is considered that typical frequencies in temperature fluctuation are controlled by giving a discharge velocity difference between cold and hot jets. (J.P.N.)

  1. High-Performance Molybdenum Coating by Wire–HVOF Thermal Spray Process

    Science.gov (United States)

    Tailor, Satish; Modi, Ankur; Modi, S. C.

    2018-04-01

    Coating deposition on many industrial components with good microstructural, mechanical properties, and better wear resistance is always a challenge for the thermal spray community. A number of thermal spray methods are used to develop such promising coatings for many industrial applications, viz. arc spray, flame spray, plasma, and HVOF. All these processes have their own limitations to achieve porous free, very dense, high-performance wear-resistant coatings. In this work, an attempt has been made to overcome this limitation. Molybdenum coatings were deposited on low-carbon steel substrates using wire-high-velocity oxy-fuel (W-HVOF; WH) thermal spray system (trade name HIJET 9610®). For a comparison, Mo coatings were also fabricated by arc spray, flame spray, plasma spray, and powder-HVOF processes. As-sprayed coatings were analyzed using x-ray diffraction, scanning electron microscopy for phase, and microstructural analysis, respectively. Coating microhardness, surface roughness, and porosity were also measured. Adhesion strength and wear tests were conducted to determine the mechanical and wear properties of the as-sprayed coatings. Results show that the coatings deposited by W-HVOF have better performance in terms of microstructural, mechanical, and wear resistance properties, in comparison with available thermal spray process (flame spray and plasma spray).

  2. Single Vs Mixed Organic Cation for Low Temperature Processed Perovskite Solar Cells

    International Nuclear Information System (INIS)

    Mahmud, Md Arafat; Elumalai, Naveen Kumar; Upama, Mushfika Baishakhi; Wang, Dian; Wright, Matthew; Chan, Kah Howe; Xu, Cheng; Haque, Faiazul; Uddin, Ashraf

    2016-01-01

    Highlights: • Low temperature processed ZnO based single & mixed organic cation perovskite device. • 37% higher PCE in mixed cation perovskite solar cells (PSCs) than single cation ones. • Mixed cation PSCs exhibit significantly reduced photocurrent hysteresis. • Mixed cation PSCs demonstrate three fold higher device stability than single cation PSCs. • Electronic properties are analyzed using Electrochemical Impedance Spectroscopy. - Abstract: The present work reports a comparative study between single and mixed organic cation based MAPbI 3 and MA 0.6 FA 0.4 PbI 3 perovskite devices fabricated in conjunction with low temperature processed (<150 °C) ZnO electron transport layers. MA 0.6 FA 0.4 PbI 3 perovskite devices demonstrate 37% higher power conversion efficiency compared to MAPbI 3 perovskite devices developed on the ZnO ETL. In addition, MA 0.6 FA 0.4 PbI 3 devices exhibit very low photocurrent hysteresis and they are three-fold more stable than conventional MAPbI 3 PSCs (perovskite solar cells). An in-depth analysis on the charge transport properties in both fresh and aged devices has been carried out using electrochemical impedance spectroscopy analysis to comprehend the enhanced device stability of the mixed perovskite devices developed on the ZnO ETL. The study also investigates into the interfacial charge transfer characteristics associated with the ZnO/mixed organic cation perovskite interface and concomitant influence on the inherent electronic properties.

  3. Thermal and hydrodynamic characteristics of forced and mixed convection flow through vertical rectangular channels

    Directory of Open Access Journals (Sweden)

    Hanafi Abdalla S.

    2008-01-01

    Full Text Available This paper presents experimental and numerical studies for the case of turbulent forced and mixed convection flow of water through narrow vertical rectangular channel. The channel is composed of two parallel plates which are heated at a uniform heat flux, whereas, the other two sides of the channel are thermally insulated. The plates are of 64 mm in width, 800 mm in height, and separated from each other at a narrow gap of 2.7 mm. The Nusselt number distribution along the flow direction normalized by the Nusselt number for the case of turbulent forced convection flow is obtained experimentally with a comparison with the numerical results obtained from a commercial computer code. The quantitative determination of the nor- malized Nusselt number with respect to the dimension-less number Z = (Gr/Re21/8Pr0.5 is presented with a comparison with previous experimental results. Qualitative results are presented for the normalized temperature and velocity profiles in the transverse direction with a comparison between the forced and mixed convection flow for both the cases of upward and downward flow directions. The effect of the axial locations and the parameter Gr/Re on the variation of the normalized temperature profiles in the transverse direction for both the regions of forced and mixed convection and for both of the upward and downward flow directions are obtained. The normalized velocity profiles in the transverse directions are also determined at different inlet velocity and heat fluxes for the previous cases. It is found that the normalized Nusselt number is greater than one in the mixed convection region for both the cases of upward and downward flow and correlated well with the dimension-less parameter Z for both of the forced and mixed convection regions. The temperature profiles increase with increasing the axial location along the flow direction or the parameter Gr/Re for both of the forced and mixed convection regions, but this increase is

  4. Modeling the Bergeron-Findeisen Process Using PDF Methods With an Explicit Representation of Mixing

    Science.gov (United States)

    Jeffery, C.; Reisner, J.

    2005-12-01

    Currently, the accurate prediction of cloud droplet and ice crystal number concentration in cloud resolving, numerical weather prediction and climate models is a formidable challenge. The Bergeron-Findeisen process in which ice crystals grow by vapor deposition at the expense of super-cooled droplets is expected to be inhomogeneous in nature--some droplets will evaporate completely in centimeter-scale filaments of sub-saturated air during turbulent mixing while others remain unchanged [Baker et al., QJRMS, 1980]--and is unresolved at even cloud-resolving scales. Despite the large body of observational evidence in support of the inhomogeneous mixing process affecting cloud droplet number [most recently, Brenguier et al., JAS, 2000], it is poorly understood and has yet to be parameterized and incorporated into a numerical model. In this talk, we investigate the Bergeron-Findeisen process using a new approach based on simulations of the probability density function (PDF) of relative humidity during turbulent mixing. PDF methods offer a key advantage over Eulerian (spatial) models of cloud mixing and evaporation: the low probability (cm-scale) filaments of entrained air are explicitly resolved (in probability space) during the mixing event even though their spatial shape, size and location remain unknown. Our PDF approach reveals the following features of the inhomogeneous mixing process during the isobaric turbulent mixing of two parcels containing super-cooled water and ice, respectively: (1) The scavenging of super-cooled droplets is inhomogeneous in nature; some droplets evaporate completely at early times while others remain unchanged. (2) The degree of total droplet evaporation during the initial mixing period depends linearly on the mixing fractions of the two parcels and logarithmically on Damköhler number (Da)---the ratio of turbulent to evaporative time-scales. (3) Our simulations predict that the PDF of Lagrangian (time-integrated) subsaturation (S) goes as

  5. Code-Mixing and Code Switchingin The Process of Learning

    Directory of Open Access Journals (Sweden)

    Diyah Atiek Mustikawati

    2016-09-01

    Full Text Available This study aimed to describe a form of code switching and code mixing specific form found in the teaching and learning activities in the classroom as well as determining factors influencing events stand out that form of code switching and code mixing in question.Form of this research is descriptive qualitative case study which took place in Al Mawaddah Boarding School Ponorogo. Based on the analysis and discussion that has been stated in the previous chapter that the form of code mixing and code switching learning activities in Al Mawaddah Boarding School is in between the use of either language Java language, Arabic, English and Indonesian, on the use of insertion of words, phrases, idioms, use of nouns, adjectives, clauses, and sentences. Code mixing deciding factor in the learning process include: Identification of the role, the desire to explain and interpret, sourced from the original language and its variations, is sourced from a foreign language. While deciding factor in the learning process of code, includes: speakers (O1, partners speakers (O2, the presence of a third person (O3, the topic of conversation, evoke a sense of humour, and just prestige. The significance of this study is to allow readers to see the use of language in a multilingual society, especially in AL Mawaddah boarding school about the rules and characteristics variation in the language of teaching and learning activities in the classroom. Furthermore, the results of this research will provide input to the ustadz / ustadzah and students in developing oral communication skills and the effectiveness of teaching and learning strategies in boarding schools.

  6. Self-organization process of a magnetohydrodynamic plasma in the presence of thermal conduction

    International Nuclear Information System (INIS)

    Zhu, Shao-ping; Horiuchi, Ritoku; Sato, Tetsuya; Watanabe, K.; Hayashi, T.; Todo, Y.; Watanabe, T.H.; Kageyama, A.; Takamaru, H.

    1995-12-01

    A self-organization process of a magnetohydrodynamic(MHD) plasma with a finite thermal conductivity is investigated by means of a three-dimensional MHD simulation. With no thermal conduction an MHD system self-organizes to a non-Taylor's state in which the electric current perpendicular to the magnetic field remains comparable to the parallel electric current. In the presence of thermal conductivity the perpendicular component of electric current and the nonuniformity of thermal pressure generated by driven reconnection tend to be smoothened. Thus, the self-organized state approaches to a force-free minimum energy state under the influence of thermal conduction. Detailed energy conversion processes are also studied to find that the rapid decay of magnetic energy during the self-organization process is caused not only through the ohmic heating, but also through the work done by the j x B force. (author)

  7. Mixed Uranium/Refractory Metal Carbide Fuels for High Performance Nuclear Reactors

    International Nuclear Information System (INIS)

    Knight, Travis; Anghaie, Samim

    2002-01-01

    Single phase, solid-solution mixed uranium/refractory metal carbides have been proposed as an advanced nuclear fuel for advanced, high-performance reactors. Earlier studies of mixed carbides focused on uranium and either thorium or plutonium as a fuel for fast breeder reactors enabling shorter doubling owing to the greater fissile atom density. However, the mixed uranium/refractory carbides such as (U, Zr, Nb)C have a lower uranium densities but hold significant promise because of their ultra-high melting points (typically greater than 3700 K), improved material compatibility, and high thermal conductivity approaching that of the metal. Various compositions of (U, Zr, Nb)C were processed with 5% and 10% metal mole fraction of uranium. Stoichiometric samples were processed from the constituent carbide powders, while hypo-stoichiometric samples with carbon-to-metal (C/M) ratios of 0.92 were processed from uranium hydride, graphite, and constituent refractory carbide powders. Processing techniques of cold uniaxial pressing, dynamic magnetic compaction, sintering, and hot pressing were investigated to optimize the processing parameters necessary to produce high density (low porosity), single phase, solid-solution mixed carbide nuclear fuels for testing. This investigation was undertaken to evaluate and characterize the performance of these mixed uranium/refractory metal carbides for high performance, ultra-safe nuclear reactor applications. (authors)

  8. Lightweight Brick by Carbon Ash from The Mixed Plastic Waste Treatment Plant

    OpenAIRE

    Chen Kuo-Wei

    2016-01-01

    This study was designed to investigate the mixed plastic waste from the production of light carbon ash bricks performance. The mixed waste plastic pyrolysis process generated waste - Carbon ash. After extrusion, a Lightweight brick was made by carbon ash, additive and Cement mortar. In general, the set compressive strength and insulation effect of lightweight bricks with carbon ash proportion for significant impact. The set water absorption and thermal conductivity of lightweight bricks with ...

  9. Mixed convection boundary layer flow over a vertical surface embedded in a thermally stratified porous medium

    International Nuclear Information System (INIS)

    Ishak, Anuar; Nazar, Roslinda; Pop, Ioan

    2008-01-01

    The mixed convection boundary layer flow through a stable stratified porous medium bounded by a vertical surface is investigated. The external velocity and the surface temperature are assumed to vary as x m , where x is measured from the leading edge of the vertical surface and m is a constant. Numerical solutions for the governing Darcy and energy equations are obtained. The results indicate that the thermal stratification significantly affects the surface shear stress as well as the surface heat transfer, besides delays the boundary layer separation

  10. Mixed convection heat transfer from confined tandem square cylinders in a horizontal channel

    KAUST Repository

    Huang, Zhu

    2013-11-01

    This paper presents a numerical study on the two-dimensional laminar mixed convective flow and heat transfer around two identical isothermal square cylinders arranged in tandem and confined in a channel. The spacing between the cylinders is fixed with four widths of the cylinder and the blockage ratio and the Prandtl number are fixed at 0.1 and 0.7 respectively. The mixed convective flow and heat transfer is simulated by high accuracy multidomain pseudospectral method. The Reynolds number (Re) is studied in the range 80 ≤ Re ≤ 150, the Richardson number (Ri) demonstrating the influence of thermal buoyancy ranges from 0 to 1. Numerical results reveal that, with the thermal buoyancy effect, the mixed convective flow sheds vortex behind the cylinders and keeps periodic oscillating. The variations of characteristic quantities related to flow and heat transfer processes, such as the overall drag and lift coefficients and the Nusselt numbers, are presented and discussed. Furthermore, the influence of thermal buoyancy on the fluid flow and heat transfer are discussed and analysed. © 2013 Elsevier Ltd. All rights reserved.

  11. Thermal modeling of nickel-hydrogen battery cells operating under transient orbital conditions

    Science.gov (United States)

    Schrage, Dean S.

    1991-01-01

    An analytical study of the thermal operating characteristics of nickel-hydrogen battery cells is presented. Combined finite-element and finite-difference techniques are employed to arrive at a computationally efficient composite thermal model representing a series-cell arrangement operating in conjunction with a radiately coupled baseplate and coldplate thermal bus. An aggressive, low-mass design approach indicates that thermal considerations can and should direct the design of the thermal bus arrangement. Special consideration is given to the potential for mixed conductive and convective processes across the hydrogen gap. Results of a compressible flow model are presented and indicate the transfer process is suitably represented by molecular conduction. A high-fidelity thermal model of the cell stack (and related components) indicates the presence of axial and radial temperature gradients. A detailed model of the thermal bus reveals the thermal interaction of individual cells and is imperative for assessing the intercell temperature gradients.

  12. VII International scientific conference Radiation-thermal effects and processes in inorganic materials. Proceedings

    International Nuclear Information System (INIS)

    2010-01-01

    In the collection there are the reports of the VII International scientific conference and the VII All-Russian school-conference Radiation-thermal effects and processes in inorganic materials which were conducted on October 2-10, 2010, in Tomsk. The reports deal with new developments of charged particles high-intensity beam sources, high-temperature metrology of high-current beams and work materials, radiation-thermal stimulated effects and processes in inorganic materials, physical basics of technological processes, radiation-thermal technologies and equipment for their realization, allied branches of science and technology, specifically, nanotechnologies [ru

  13. Numerical Simulation of Two-branch Hot Gas Mixing at Reactor Outlet of HTR-PM

    International Nuclear Information System (INIS)

    Hao Pengefei; Zhou Yangping; Li Fu; Shi Lei; He Heng

    2014-01-01

    A series of two-branch model experiment has been finished to investigate the thermal mixing efficiency of the HTR-PM reactor outlet. This paper introduces the numerical simulation on the design of thermal mixing structure of HTR-PM and the test facility with Fluent software. The profiles of temperature, pressure and velocity in the mixing structure design and the test facility are discussed by comparing with the model experiment results. The numerical simulation results of the test facility have good agreement to the experiment results. In addition, the thermal-fluid characters obtained by numerical simulation show the thermal mixing structure of HTR-PM has similarity with the test facility. Finally, it is concluded that the thermal mixing design at HTR-PM reactor outlet can fulfilled the requirements for high thermal mixing efficiency and appropriate pressure drop. (author)

  14. Does case-mix based reimbursement stimulate the development of process-oriented care delivery?

    Science.gov (United States)

    Vos, Leti; Dückers, Michel L A; Wagner, Cordula; van Merode, Godefridus G

    2010-11-01

    Reimbursement based on the total care of a patient during an acute episode of illness is believed to stimulate management and clinicians to reduce quality problems like waiting times and poor coordination of care delivery. Although many studies already show that this kind of case-mix based reimbursement leads to more efficiency, it remains unclear whether care coordination improved as well. This study aims to explore whether case-mix based reimbursement stimulates development of care coordination by the use of care programmes, and a process-oriented way of working. Data for this study were gathered during the winter of 2007/2008 in a survey involving all Dutch hospitals. Descriptive and structural equation modelling (SEM) analyses were conducted. SEM reveals that adoption of the case-mix reimbursement within hospitals' budgeting processes stimulates hospitals to establish care programmes by the use of process-oriented performance measures. However, the implementation of care programmes is not (yet) accompanied by a change in focus from function (the delivery of independent care activities) to process (the delivery of care activities as being connected to a chain of interdependent care activities). This study demonstrates that hospital management can stimulate the development of care programmes by the adoption of case-mix reimbursement within hospitals' budgeting processes. Future research is recommended to confirm this finding and to determine whether the establishment of care programmes will in time indeed lead to a more process-oriented view of professionals. Copyright © 2010 Elsevier Ireland Ltd. All rights reserved.

  15. Effects Of Thermal Exchange On Material Flow During Steel Thixoextrusion Process

    International Nuclear Information System (INIS)

    Becker, Eric; Gu Guochao; Langlois, Laurent; Bigot, Regis; Pesci, Raphael

    2011-01-01

    Semisolid processing is an innovative technology for near net-shape production of components, where the metallic alloys are processed in the semisolid state. Taking advantage of the thixotropic behavior of alloys in the semisolid state, significant progress has been made in semisolid processing. However, the consequences of such behavior on the flow during thixoforming are still not completely understood. To explore and better understand the influence of the different parameters on material flow during thixoextrusion process, thixoextrusion experiments were performed using the low carbon steel C38. The billet was partially melted at high solid fraction. Effects of various process parameters including the initial billet temperature, the temperature of die, the punch speed during process and the presence of a Ceraspray layer at the interface of tool and billet were investigated through experiments and simulation. After analyzing the results thus obtained, it was identified that the aforementioned parameters mainly affect thermal exchanges between die and part. The Ceraspray layer not only plays a lubricant role, but also acts as a thermal barrier at the interface of tool and billet. Furthermore, the thermal effects can affect the material flow which is composed of various distinct zones.

  16. The effect of adiabatic and conducting wall boundary conditions on LES of a thermal mixing tee

    International Nuclear Information System (INIS)

    Howard, Richard J.A.; Pasutto, Thomas

    2009-01-01

    In this paper preliminary LES simulations are carried out of the FATHERINO mixing T junction experiment. In this experiment 80degC hot water enters a lateral steel pipe which has a diameter of D=0.054m, at a speed of 1.04m/s and meets 5degC cold water which enters a perpendicular steel pipe branch that also has a diameter D=0.054m but this time at a lower speed of 0.26m/s. The modelling of the steel pipe walls is tested by comparing adiabatic and 1D conducting wall boundary conditions. The numerical grid used contains approximately 440,000 hexahedral elements. The near wall refinement is not sufficient to resolve the near wall boundary layer (y + approx. = 32) and a standard logarithmic boundary condition is used. A method known as the synthetic eddy method is used to generate the turbulent flow at the pipe inlets. Three different LES models are used (Smagorinsky, dynamic Smagorinsky and wale) to resolve the subgrid turbulent motion beyond the wall grid. An additional test is carried out where no subgrid model is used with only the wall modelling being applied. The results show that the wale model generates much less resolved turbulence than the other cases and this model shows virtually no difference between the two methods of wall thermal modelling. The dynamic Smagorinsky model shows that, downstream of the mixing T, the lower wall remains at a lower temperature for longer when the adiabatic boundary condition is applied. The Smagorinsky model is found to produce the highest level of resolved temperature fluctuation. For this model the 1D thermal modelling approach increases the unsteadiness of both the velocity and temperature fields at the onset of the mixing and in the middle of the pipe downstream of the T junction. However near the lower wall the 1D thermal modelling approach tends to reduce the unsteadiness. The case with no subgrid modelling shows higher levels of turbulence kinetic energy but lower levels of temperature fluctuation than the cases with

  17. Thermal energy management process experiment

    Science.gov (United States)

    Ollendorf, S.

    1984-01-01

    The thermal energy management processes experiment (TEMP) will demonstrate that through the use of two-phase flow technology, thermal systems can be significantly enhanced by increasing heat transport capabilities at reduced power consumption while operating within narrow temperature limits. It has been noted that such phenomena as excess fluid puddling, priming, stratification, and surface tension effects all tend to mask the performance of two-phase flow systems in a 1-g field. The flight experiment approach would be to attack the experiment to an appropriate mounting surface with a 15 to 20 meter effective length and provide a heat input and output station in the form of heaters and a radiator. Using environmental data, the size, location, and orientation of the experiment can be optimized. The approach would be to provide a self-contained panel and mount it to the STEP through a frame. A small electronics package would be developed to interface with the STEP avionics for command and data handling. During the flight, heaters on the evaporator will be exercised to determine performance. Flight data will be evaluated against the ground tests to determine any anomalous behavior.

  18. Implementation of an Experimental Method for Coupled Subchannel Mixing Measurement

    International Nuclear Information System (INIS)

    Silin, Nicolas; Juanico, Luis; Delmastro, Dario

    2003-01-01

    In this work the application of a thermal tracing technique to the measurement of thermal turbulent mixing between coupled subchannels is presented.The experiment was carried out on a real scale model with geometry similar to nuclear fuel element rod bundles.Thermal mixing rates were measured for water flows at different Reynolds numbers

  19. The Improvement of Thermal Insulating Concrete Panel

    Directory of Open Access Journals (Sweden)

    Mohammed Ali Nasser Ali

    2018-05-01

    Full Text Available The Iraqi houses flattening the roof by a concrete panel, and because of the panels on the top directly exposed to the solar radiation become unbearably hot and cold during the summer and winter. The traditional concrete panel components are cement, sand, and aggregate, which have a poor thermal property. The usage of materials with low thermal conductivity with no negative reflects on its mechanical properties gives good improvements to the thermal properties of the concrete panel. The practical part of this work was built on a multi-stage mixing plan. In the first stage the mixing ratio based on the ratios of the sand to cement. The second stage mixing ratios based on replacing the coarse aggregate quantities with the Alabaster aggregates, and the third stage the mixing ratios based on the replacement of wood ash instead of the sand. While the fourth stage mixing ratios based on decreasing the thermal conductivity and increasing mechanical properties by adding a multilayer of a plastic net. The result shows that using a concrete panel with components (cement, sand, coarse aggregate, wood ash, and Alabaster aggregates with a mass ratio of (1:1:2:1:1 and 3-plastic layers, gives the best improvement of the thermal properties. Where, the thermal conductivity is reduced by 42% and the specific heat increased by 41.2% as compared to the traditional concrete panel mixing ratio, with mechanical properties are agreed with the Iraqi standards.

  20. Large quantity production of carbon and boron nitride nanotubes by mechano-thermal process

    International Nuclear Information System (INIS)

    Chen, Y.; Fitzgerald, J.D.; Chadderton, L.; Williams, J.S.; Campbell, S.J.

    2002-01-01

    Full text: Nanotube materials including carbon and boron nitride have excellent properties compared with bulk materials. The seamless graphene cylinders with a high length to diameter ratio make them as superstrong fibers. A high amount of hydrogen can be stored into nanotubes as future clean fuel source. Theses applications require large quantity of nanotubes materials. However, nanotube production in large quantity, fully controlled quality and low costs remains challenges for most popular synthesis methods such as arc discharge, laser heating and catalytic chemical decomposition. Discovery of new synthesis methods is still crucial for future industrial application. The new low-temperature mechano-thermal process discovered by the current author provides an opportunity to develop a commercial method for bulk production. This mechano-thermal process consists of a mechanical ball milling and a thermal annealing processes. Using this method, both carbon and boron nitride nanotubes were produced. I will present the mechano-thermal method as the new bulk production technique in the conference. The lecture will summarise main results obtained. In the case of carbon nanotubes, different nanosized structures including multi-walled nanotubes, nanocells, and nanoparticles have been produced in a graphite sample using a mechano-thermal process, consisting of I mechanical milling at room temperature for up to 150 hours and subsequent thermal annealing at 1400 deg C. Metal particles have played an important catalytic effect on the formation of different tubular structures. While defect structure of the milled graphite appears to be responsible for the formation of small tubes. It is found that the mechanical treatment of graphite powder produces a disordered and microporous structure, which provides nucleation sites for nanotubes as well as free carbon atoms. Multiwalled carbon nanotubes appear to grow via growth of the (002) layers during thermal annealing. In the case of BN

  1. The Effect of Rubber Mixing Process on The Curing Characteristics of Natural Rubber

    Directory of Open Access Journals (Sweden)

    Abu Hasan

    2013-04-01

    Full Text Available This research is aimed at studying the relationship between rubber mixing processes and curing characteristics of natural rubber. The curing characteristic analysis was carried out through a natural rubber formula having been masticated and mixed, followed by curing. As many as four mastication methods were finely applied; each respected four sequences of rubber mixing process. In the first method, rubber was masticated for 5 minutes and then rubber chemicals and carbon black N 330 were  simultaneously added. In the second and the third methods, rubber was masticated for 1 minute and then carbon blacks and rubber chemicals were also simultaneously added but using different type of fillers. In the fourth method, rubber was masticated for 3 minutes and then rubber chemicals and carbon black were subsequently added. The additions of rubber chemicals and carbon blacks to the masticated rubber were distinguished by the sequence and time allocated for each mixing process. The carbon blacks were added in two stages by which 10 phr was added first and the remaining 40 phr was added later along with oil. In another method, ratios of the carbon blacks addition (as done in the first  and the second stages were 20:30, 30:20, and 40:10. The examination results showed that rubber mixing process gave an impact on the changes of curing characteristics. They were much affected by the method of carbon black addition. The mixing temperature also had an effect on both curing time and curing rate in which the higher the mixing temperature, the lower the curing time and curing rate. Vulcanization temperature also affected the curing time and curing rate in which the higher the vulcanization temperature, the lower the curing time and the higher the curing rate. Lastly, particle size of carbon black also gave an impact on the curing time and curing rate in which the smaller the particle size, the lower the curing time and the higher the curing rate.

  2. Thermal diffusivity and thermal conductivity of (Th,U)O2 fuels

    International Nuclear Information System (INIS)

    Sengupta, A.K.; Jarvis, T.; Nair, M.R.; Ramachandran, R.; Mujumdar, S.; Purushotham, D.S.C.

    2000-05-01

    India has vast reserves of thorium (> 460,000 tons) and sustained work on all aspects of thorium utilization has been initiated. In this context work on fabrication of sintered thoria and mixed (Th,U)O 2 pellets and evaluation of their thermophysical properties have been taken up in Radiometallurgy Division. Thermal conductivity, being the most important thermal properties, has been calculated using the experimentally measured thermal diffusivity, density and literature values of specific heats for ThO 2 and thoria containing 2,4,6,10 and 20% UO 2 . Thermal diffusivity was measured experimentally by the laser flash method from 600 to 1600 deg C in vacuum. It was observed that thermal conductivity of ThO 2 and mixed (Th,U)O 2 decrease with increase in temperature. It was also observed that the conductivity decreases with increase in UO 2 content, the decrease being more at lower temperature than that at higher temperatures. Empirical relations correlating thermal conductivity to temperatures have been generated by the least square fit method and reported. (author)

  3. Visualization and measurement by image processing of thermal hydraulic phenomena by neutron radiography

    International Nuclear Information System (INIS)

    Takenaka, Nobuyuki

    1996-01-01

    Neutron Radiography was applied to visualization of thermal hydraulic phenomena and measurement was carried out by image processing the visualized images. Since attenuation of thermal neutron rays is high in ordinary liquids like water and organic fluid while it is low in most of metals, liquid flow behaviors can be visualized through a metallic wall by neutron radiography. Measurement of void fraction and flow vector field which is important to study thermal hydraulic phenomena can be carried out by image processing the images obtained by the visualization. Various two-phase and liquid metal flows were visualized by a JRR-3M thermal neutron radiography system in the present study. Multi-dimensional void fraction distributions in two-phase flows and flow vector fields in liquid metals, which are difficult to measure by the other methods, were successfully measured by image processing. It was shown that neutron radiography was efficiently applicable to study thermal hydraulic phenomena. (author)

  4. Structure peculiarities of mixed alkali silicate glasses

    International Nuclear Information System (INIS)

    Bershtein, V.A.; Gorbachev, V.V.; Egorov, V.

    1980-01-01

    The thermal porperties and structure of alkali and mixed alkali (Li, Na, K) silicate glasses by means of differential scanning calorimetry (DSC), the positron annihilation method, X-ray fluorescence and infrared (300-30 cm -1 ) spectroscopy were studied. Introduction of different alkali cations in glass results in nonadditive change in their electron structure (bond covalence degree growth) and the thermal behaviour. The different manifestations of mixed alkali effect can be explained by the lessening of long distance Coulomb interactions and strengthening the short-range forces in the mixed alkali glasses. (orig.)

  5. Composite material having high thermal conductivity and process for fabricating same

    Science.gov (United States)

    Colella, Nicholas J.; Davidson, Howard L.; Kerns, John A.; Makowiecki, Daniel M.

    1998-01-01

    A process for fabricating a composite material such as that having high thermal conductivity and having specific application as a heat sink or heat spreader for high density integrated circuits. The composite material produced by this process has a thermal conductivity between that of diamond and copper, and basically consists of coated diamond particles dispersed in a high conductivity metal, such as copper. The composite material can be fabricated in small or relatively large sizes using inexpensive materials. The process basically consists, for example, of sputter coating diamond powder with several elements, including a carbide forming element and a brazeable material, compacting them into a porous body, and infiltrating the porous body with a suitable braze material, such as copper-silver alloy, thereby producing a dense diamond-copper composite material with a thermal conductivity comparable to synthetic diamond films at a fraction of the cost.

  6. The effect of mixing order of fillers on the physical properties of EPDM

    International Nuclear Information System (INIS)

    Gul, J.; Saleemi, A.R.

    2007-01-01

    In this research the effect of mixing order of fillers on the physical properties of EPDM (Ethylene Propylene Diene Monomer) vulcanizates was studied. EPDM was compounded with other ingredients i.e. fillers, process aid, curing package etc in order to get the needed physical properties for thermal insulation. All the factors, which could affect the physical properties of EPDM vulcanizates such as quality and quantity of raw materials, storage conditions of ingredients and vulcanizates, compounding and testing facilities, mixing time, process parameters etc were kept constant except mixing order of addition of filler to EPDM. Different batches of EPDM vulcanizates with different mixing order/sequence of filler to EPDM were prepared and tested for physical properties like density, hardness, tensile strength and elongation. It was concluded that mixing order of filler to EPDM affects tensile strength, elongation and hardness and does not affect density of the EPDM vulcanizate. (author)

  7. Processes that generate and deplete liquid water and snow in thin midlevel mixed-phase clouds

    Science.gov (United States)

    Smith, Adam J.; Larson, Vincent E.; Niu, Jianguo; Kankiewicz, J. Adam; Carey, Lawrence D.

    2009-06-01

    This paper uses a numerical model to investigate microphysical, radiative, and dynamical processes in mixed-phase altostratocumulus clouds. Three cloud cases are chosen for study, each of which was observed by aircraft during the fifth or ninth Complex Layered Cloud Experiment (CLEX). These three clouds are numerically modeled using large-eddy simulation (LES). The observed and modeled clouds consist of a mixed-phase layer with a quasi-adiabatic profile of liquid, and a virga layer below that consists of snow. A budget of cloud (liquid) water mixing ratio is constructed from the simulations. It shows that large-scale ascent/descent, radiative cooling/heating, turbulent transport, and microphysical processes are all significant. Liquid is depleted indirectly via depositional growth of snow (the Bergeron-Findeisen process). This process is more influential than depletion of liquid via accretional growth of snow. Also constructed is a budget of snow mixing ratio, which turns out to be somewhat simpler. It shows that snow grows by deposition in and below the liquid (mixed-phase) layer, and sublimates in the remainder of the virga region below. The deposition and sublimation are balanced primarily by sedimentation, which transports the snow from the growth region to the sublimation region below. In our three clouds, the vertical extent of the virga layer is influenced more by the profile of saturation ratio below the liquid (mixed-phase) layer than by the mixing ratio of snow at the top of the virga layer.

  8. Two-branch Gas Experiments for Hot Gas Mixing of HTR-PM

    International Nuclear Information System (INIS)

    Zhou Yangping; Hao Pengefei; He Heng; Li Fu; Shi Lei

    2014-01-01

    A model experiment is proposed to investigate the hot gas mixing efficiency of HTR-PM reactor outlet. The test facility is introduced which is set at a scale of 1:2.5 comparing with the design of thermal mixing structure at HTR-PM reactor outlet. The test facility using air as its flow media includes inlet pipe system, electric heaters, main body of test facility, hot gas duct, exhaust pipe system and I&C system. Two-branch gas experiments are conducted on the test facility and the values of thermal-fluid parameters are collected and analyzed which include the temperature, pressure and velocity of the flow as well as the temperature of the tube wall. The analysis result shows the mixing efficiency is higher than the requirement of thermal mixing by steam generator even with conservative assumption which indicates that the design of hog gas mixing structure of HTR-PM fulfills the requirement for thermal mixing at two-branch working conditions. (author)

  9. Investigations on mixing phenomena in single-phase flow in a T-junction geometry

    International Nuclear Information System (INIS)

    Walker, C.; Simiano, M.; Zboray, R.; Prasser, H.-M.

    2009-01-01

    The paper deals with T-junction mixing experiments carried out with wire-mesh sensors. The mixing of coolant streams of different temperature in pipe junctions leads to temperature fluctuations that may cause thermal fatigue in the pipe wall. This is practical background for an increased interest in measuring and predicting the transient flow field and the turbulent mixing pattern downstream of a T-junction. Experiments were carried out at a perpendicular connection of two pipes of 51 mm inner diameter. The straight and the side branches were supplied by water of different electrical conductivity, which replaced the temperature in the thermal mixing process. A set of three wire-mesh sensors with a grid of 16 x 16 measuring points each was used to record conductivity distributions downstream of the T-junction. Besides the measurement of profiles of the time averaged mixing scalar over extended measuring domains, the high resolution in time and space of the mesh sensors allow a statistic characterization of the stochastic fluctuations of the mixing scalar in a wide range of frequencies. Information on the scale of turbulent mixing patterns is obtained by cross-correlating the signal fluctuations recorded at different locations within the measuring plane of a sensor

  10. Electro-thermal dynamic stripping process : integrating environmentalism with bitumen production

    Energy Technology Data Exchange (ETDEWEB)

    McGee, B.C.W.; McDonald, C.W. [Society of Petroleum Engineers, Canadian Section, Calgary, AB (Canada)]|[E-T Energy, Calgary, AB (Canada); Little, L. [Society of Petroleum Engineers, Canadian Section, Calgary, AB (Canada)]|[Alberta Energy Research Inst., Edmonton, AB (Canada)

    2008-10-15

    This paper presented a new method of in situ oil sands extraction developed by Calgary-based E-T Energy. The Electro-Thermal Dynamic Stripping Process (ET-DSP) uses electricity to melt oil sands deposits that are too deep for open pit mining. The energy intensity of production compares favourably with alternative thermal bitumen extraction techniques and water consumption for the process is comparatively low, with all produced water being re-injected into the producing formation without any treatment. With ET-DSP, electrodes are drilled and completed next to the oil sands formation which ensures that the electrical currents are forced to flow to the oil sands formation. The viscosity of the bitumen is lowered by the heat from the current, thereby making the fluid flow more readily into vertical extraction wells. ET-DSP uses electricity directly from the power grid, and does not produce any greenhouse gas (GHG) emissions of its own. The process has the potential to allow operators to focus on areas of oil sands reservoirs that have remained inaccessible. Field studies confirmed that the production of bitumen using this method was achieved with reduced greenhouse gas emissions as compared to other thermal recovery process. The bitumen had trace amount of sand and no emulsions. 5 refs., 5 figs.

  11. A systematic process to foster development and implementation of an emerging technology for treating DOE's mixed and hazardous wastes

    International Nuclear Information System (INIS)

    Bench, J.; Carlson, T.; Carpenter, C.; Duray, J.; Walker, R.

    1992-01-01

    An innovative approach for the successful implementation of treatment technologies is presented in this paper. This approach, which could be used on any emerging restoration technology, is described through an example, the molten salt oxidation (MSO) process, that is currently being implemented by the U. S. Department of energy (DOE). MSO is being pursued by DOE because it appears to be a promising treatment technology for many of its hazardous and mixed wastes. MSO is a noncombustion process that is basically a combination of chemical and thermal treatments and can be used as both a primary and a secondary treatment (e. g. , as a dry scrubber to treat incinerator off gases). The molten salt technology provides waste minimization and separation capabilities and is competitive with incineration for certain types of wastes. MSO also has advantages that potentially make it more acceptable to regulatory agencies and the public

  12. Study of the quantitative assessment method for high-cycle thermal fatigue of a T-pipe under turbulent fluid mixing based on the coupled CFD-FEM method and the rainflow counting method

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Y.; Lu, T., E-mail: likesurge@sina.com

    2016-12-01

    Highlights: • Two characteristic parameters of the temperature fluctuations are used for qualitative analysis. • A quantitative assessment method for high-cycle thermal fatigue of a T-pipe is proposed. • The time-dependent curves for the temperature and thermal stress are not always “in-phase”. • Large magnitude of thermal stresses may not mean large number of fatigue cycles. • The normalized fatigue damage rate and normalized RMS temperature are positively related. - Abstract: With the development of nuclear power and nuclear power safety, high-cycle thermal fatigue of the pipe structures induced by the flow and heat transfer of the fluid in pipes have aroused more and more attentions. Turbulent mixing of hot and cold flows in a T-pipe is a well-recognized source of thermal fatigue in piping system, and thermal fatigue is a significant long-term degradation mechanism. It is not an easy work to evaluate thermal fatigue of a T-pipe under turbulent flow mixing because of the thermal loads acting at fluid–structure interface of the pipe are so complex and changeful. In this paper, a one-way Computational Fluid Dynamics-Finite Element Method (CFD-FEM method) coupling based on the ANSYS Workbench 15.0 software has been developed to calculate transient thermal stresses with the temperature fields of turbulent flow mixing, and thermal fatigue assessment has been carried out with this obtained fluctuating thermal stresses by programming in the software platform of Matlab based on the rainflow counting method. In the thermal analysis, the normalized mean temperatures and the normalized root mean square (RMS) temperatures are obtained and compared with the experiment of the test case from the Vattenfall benchmark facility to verify the accuracy of the CFD calculation and to determine the position which thermal fatigue is most likely to occur in the T-junction. Besides, more insights have been obtained in the coupled CFD-FEM analysis and the thermal fatigue

  13. The electrical and thermal properties of sodium sulfate mixed with lithium sulfate, yttrium sulfate, and silicon dioxide

    International Nuclear Information System (INIS)

    Imanaka, N.; Yamaguchi, Y.; Adachi, G.; Shiokawa, J.

    1986-01-01

    Sodium sulfate mixed with lithium sulfate, yttrium sulfate, and silicon dioxide was prepared. The thermal and electrical properties of its phases were investigated. The Na 2 SO 4 -Li 2 SO 4 -Y 2 (SO 4 ) 3 SiO 2 samples are similar to the Na 2 SO 4 -I phase (a high temperature phase), which is appreciably effective for Na + ionic conduction. Phase transformation was considerably suppressed by mixing. Electromotive force (EMF) was measured, using Na 2 SO 4 -Li 2 SO 4 -Y 2 (SO 4 ) 3 -SiO 2 as a solid electrolyte, by constructing an SO 2 gas concentration cell. The measured EMF's at 823 and 773 K were in fairly good accordance with the calculated EMF's for inlet SO 2 gas concentration between 30 ppm and 1%, and 500 ppm and 0.5% respectively

  14. Nanofluid heat transfer under mixed convection flow in a tube for solar thermal energy applications.

    Science.gov (United States)

    Sekhar, Y Raja; Sharma, K V; Kamal, Subhash

    2016-05-01

    The solar flat plate collector operating under different convective modes has low efficiency for energy conversion. The energy absorbed by the working fluid in the collector system and its heat transfer characteristics vary with solar insolation and mass flow rate. The performance of the system is improved by reducing the losses from the collector. Various passive methods have been devised to aid energy absorption by the working fluid. Also, working fluids are modified using nanoparticles to improve the thermal properties of the fluid. In the present work, simulation and experimental studies are undertaken for pipe flow at constant heat flux boundary condition in the mixed convection mode. The working fluid at low Reynolds number in the mixed laminar flow range is undertaken with water in thermosyphon mode for different inclination angles of the tube. Local and average coefficients are determined experimentally and compared with theoretical values for water-based Al2O3 nanofluids. The results show an enhancement in heat transfer in the experimental range with Rayleigh number at higher inclinations of the collector tube for water and nanofluids.

  15. Thermal fatigue analysis of vertical annulus with inner rotating cylinder induced by two temperature fluid mixing

    International Nuclear Information System (INIS)

    Miyano, Hiroshi; Narabayashi, Tadashi

    2011-01-01

    Mechanical seal for nuclear reactor coolant recirculation pump must purge the cold water supply from the outside. The cold purge water is flowing into the hot water zone in the pump through a narrow gap between pump shaft and casing over. On the mixing region of the cold purge water and hot water in the narrow gap, the random level temperature fluctuation occurs on the structural metal surface of casing cover and pump shaft. Then it could lead to cyclic thermal stress and fatigue damage. The experiments and analysis have done, made clear the mechanism of generation of temperature fluctuations. Also, it was studied how to measure the structure of the mixing zone temperature control and how to prevent the occurrence of a large temperature fluctuation. In addition, it is proposed the method of evaluating a random temperature fluctuation by using the envelope curve and its fatigue by OOR counting to applying to the evaluation of the similar random fluid temperature fluctuation problems. (author)

  16. Stochastic modelling of thermal fatigue crack growth for applying in the structural reliability of nuclear piping

    International Nuclear Information System (INIS)

    Radu, V.

    2016-01-01

    The problem of thermal fatigue in mixing areas arises in nuclear piping where a turbulent mixing or vortices produce rapid fluid temperature fluctuations with random frequencies. The assessment of fatigue crack growth due to cyclic thermal loads arising from turbulent mixing presents significant challenges, principally due to the difficulty of establishing the actual loading spectrum. To apply the Stochastic approach of thermal fatigue, a frequency temperature response function is proposed. For the elastic thermal stresses distribution solutions, the magnitude of the frequency response function is first derived and checked against the prediction by FEA. The connection between SIF.s power spectral density (PSD) and temperature.s PSD is assured with SIF frequency response function modulus. The frequency of the peaks of each magnitude for KI is supposed to be a stationary narrow-band Gaussian process. The probabilities of failure are estimated by means of the Monte Carlo methods considering a limit state function. (authors)

  17. Evaluation of risk and benefit in thermal effusivity sensor for monitoring lubrication process in pharmaceutical product manufacturing.

    Science.gov (United States)

    Uchiyama, Jumpei; Kato, Yoshiteru; Uemoto, Yoshifumi

    2014-08-01

    In the process design of tablet manufacturing, understanding and control of the lubrication process is important from various viewpoints. A detailed analysis of thermal effusivity data in the lubrication process was conducted in this study. In addition, we evaluated the risk and benefit in the lubrication process by a detailed investigation. It was found that monitoring of thermal effusivity detected mainly the physical change of bulk density, which was changed by dispersal of the lubricant and the coating powder particle by the lubricant. The monitoring of thermal effusivity was almost the monitoring of bulk density, thermal effusivity could have a high correlation with tablet hardness. Moreover, as thermal effusivity sensor could detect not only the change of the conventional bulk density but also the fractional change of thermal conductivity and thermal capacity, two-phase progress of lubrication process could be revealed. However, each contribution of density, thermal conductivity, or heat capacity to thermal effusivity has the risk of fluctuation by formulation. After carefully considering the change factor with the risk to be changed by formulation, thermal effusivity sensor can be a useful tool for monitoring as process analytical technology, estimating tablet hardness and investigating the detailed mechanism of the lubrication process.

  18. Modelling of Wheat-Flour Dough Mixing as an Open-Loop Hysteretic Process

    Czech Academy of Sciences Publication Activity Database

    Anderssen, R.; Kružík, Martin

    2013-01-01

    Roč. 18, č. 2 (2013), s. 283-293 ISSN 1531-3492 R&D Projects: GA AV ČR IAA100750802 Keywords : Dissipation * Dough mixing * Rate-independent systems Subject RIV: BA - General Mathematics Impact factor: 0.628, year: 2013 http://library.utia.cas.cz/separaty/2013/MTR/kruzik-modelling of wheat-flour dough mixing as an open-loop hysteretic process.pdf

  19. Storage effects on anthocyanins, phenolics and antioxidant activity of thermally processed conventional and organic blueberries.

    Science.gov (United States)

    Syamaladevi, Roopesh M; Andrews, Preston K; Davies, Neal M; Walters, Thomas; Sablani, Shyam S

    2012-03-15

    Consumer demand for products rich in phytochemicals is increasing as a result of greater awareness of their potential health benefits. However, processed products are stored for long-term and the phytochemicals are susceptible to degradation during storage. The objective of this study was to assess the storage effects on phytochemicals in thermally processed blueberries. Thermally processed canned berries and juice/puree were analysed for phytochemicals during their long-term storage. The phytochemical retention of thermally processed blueberries during storage was not influenced by production system (conventional versus organic). During 13 months of storage, total anthocyanins, total phenolics and total antioxidant activity in canned blueberry solids decreased by up to 86, 69 and 52% respectively. In canned blueberry syrup, total anthocyanins and total antioxidant activity decreased by up to 68 and 15% respectively, while total phenolic content increased by up to 117%. Similar trends in phytochemical content were observed in juice/puree stored for 4 months. The extent of changes in phytochemicals of thermally processed blueberries during storage was significantly influenced by blanching. Long-term storage of thermally processed blueberries had varying degrees of influence on degradation of total anthocyanins, total phenolics and total antioxidant activity. Blanching before thermal processing helped to preserve the phytochemicals during storage of blueberries. Copyright © 2011 Society of Chemical Industry.

  20. Development of a thermally-intensive reactor and process for upgrading heavy crude oil

    Energy Technology Data Exchange (ETDEWEB)

    Hauptmann, E.G. [Refinery Science Corp., El Paso, TX (United States)

    2008-07-01

    This paper discussed a pilot study conducted to test the performance of a 15 bpd high thermal flux short vapor residence time reactor. The technology was comprised of a flowing, free-surface channel of molten metal salts. Heavy crude droplets were placed on the flowing surface and mixed with catalysts. A free vapor space was used to remove and condense the clean, particulate-free cracked hydrocarbon vapors. An additional process was used to remove and separate the coke, catalysts and heavy metals for further processing and recovery. Placing the heavy crude onto a hot surface caused the drops to float or sputter on the surface. As the temperature increased, the film became thinner and broke down at the Leidenfrost point. A peak heat transfer coefficient then occurred during the intense nucleate boiling at the drop surface. The heavy crude was cracked through the combined effects of rapid heating and the presence of the catalyst. The clean, cracked hydrocarbon vapors were then removed from the drops and away from the heating source. Heavy metals were removed from the liquid product and discharged from the reactor with the coke and the catalyst. It was concluded that tests conducted to evaluate the performance of the technology demonstrated that the reactor required no external fuel for continuous operation after start-up, and all process water was fully recyclable. 5 refs., 2 tabs., 9 figs.

  1. Thermodynamic analysis of tar reforming through auto-thermal reforming process

    Energy Technology Data Exchange (ETDEWEB)

    Nurhadi, N., E-mail: nurhadi@tekmira.esdm.go.id; Diniyati, Dahlia; Efendi, M. Ade Andriansyah [R& D Centre for Mineral and Coal Technology, Jln. Jend.Sudirman no. 623, Bandung. Telp. 022-6030483 (Malaysia); Istadi, I. [Department of Chemical Engineering, Diponegoro University, Jln. Jl. Prof. Soedarto, SH, Semarang (Malaysia)

    2015-12-29

    Fixed bed gasification is a simple and suitable technology for small scale power generation. One of the disadvantages of this technology is producing tar. So far, tar is not utilized yet and being waste that should be treated into a more useful product. This paper presents a thermodynamic analysis of tar conversion into gas producer through non-catalytic auto-thermal reforming technology. Tar was converted into components, C, H, O, N and S, and then reacted with oxidant such as mixture of air or pure oxygen. Thus, this reaction occurred auto-thermally and reached chemical equilibrium. The sensitivity analysis resulted that the most promising process performance occurred at flow rate of air was reached 43% of stoichiometry while temperature of process is 1100°C, the addition of pure oxygen is 40% and preheating of oxidant flow is 250°C. The yield of the most promising process performance between 11.15-11.17 kmol/h and cold gas efficiency was between 73.8-73.9%.The results of this study indicated that thermodynamically the conversion of tar into producer gas through non-catalytic auto-thermal reformingis more promising.

  2. On The Cusp of the New Spatial Challenges - The Thermal Waste Processing Plant as an Element of Urban Space

    Science.gov (United States)

    Wójtowicz-Wróbel, Agnieszka

    2017-10-01

    The goal of this paper is to answer the question about the current importance of structures associated with the thermal processing of waste within the space of Polish cities and what status can they have in the functional and spatial structure of Polish cities in the future. The construction of thermal waste processing plants in Poland is currently a new and important problem, with numerous structures of this type being built due to increasing care for the natural environment, with the introduction of legal regulations, as well as due to the possibility of obtaining large external funding for the purposes of undertaking pro-environmental spatial initiatives, etc. For this reason, the paper contains research on the increase in the number of thermal waste processing plants in Poland in recent years. The abovementioned data was compared with similar information from other European Union member states. In the group containing Polish thermal waste processing plants, research was performed regarding the stage of the construction of a plant (operating plant, plant under construction, design in a construction phase, etc.). The paper also contains a listing of the functions other than the basic form of use, which is the incineration of waste - similarly to numerous foreign examples - that the environmentally friendly waste incineration plants fulfil in Poland, dividing the additional forms of use into "hard" elements (at the design level, requiring the expansion of a building featuring new elements that are not directly associated with the basic purpose of waste processing) and soft (social, educational, promotional actions, as well as other endeavours that require human involvement, but that do not entail significant design work on the buildings itself, expanding its form of use, etc.) as well as mixed activity, which required design work, but on a relatively small scale. Research was also conducted regarding the placement of thermal waste processing plants within the

  3. Auto-Thermal Reforming Using Mixed Ion-Electronic Conducting Ceramic Membranes for a Small-Scale H2 Production Plant

    Directory of Open Access Journals (Sweden)

    Vincenzo Spallina

    2015-03-01

    Full Text Available The integration of mixed ionic electronic conducting (MIEC membranes for air separation in a small-to-medium scale unit for H2 production (in the range of 650–850 Nm3/h via auto-thermal reforming of methane has been investigated in the present study. Membranes based on mixed ionic electronic conducting oxides such as Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCF give sufficiently high oxygen fluxes at temperatures above 800 °C with high purity (higher than 99%. Experimental results of membrane permeation tests are presented and used for the reactor design with a detailed reactor model. The assessment of the H2 plant has been carried out for different operating conditions and reactor geometry and an energy analysis has been carried out with the flowsheeting software Aspen Plus, including also the turbomachines required for a proper thermal integration. A micro-gas turbine is integrated in the system in order to supply part of the electricity required in the system. The analysis of the system shows that the reforming efficiency is in the range of 62%–70% in the case where the temperature at the auto-thermal reforming membrane reactor (ATR-MR is equal to 900 °C. When the electric consumption and the thermal export are included the efficiency of the plant approaches 74%–78%. The design of the reactor has been carried out using a reactor model linked to the Aspen flowsheet and the results show that with a larger reactor volume the performance of the system can be improved, especially because of the reduced electric consumption. From this analysis it has been found that for a production of about 790 Nm3/h pure H2, a reactor with a diameter of 1 m and length of 1.8 m with about 1500 membranes of 2 cm diameter is required.

  4. Nonlinear wave-mixing processes in the extreme ultraviolet

    International Nuclear Information System (INIS)

    Misoguti, L.; Christov, I. P.; Backus, S.; Murnane, M. M.; Kapteyn, H. C.

    2005-01-01

    We present data from two-color high-order harmonic generation in a hollow waveguide, that suggest the presence of a nonlinear-optical frequency conversion process driven by extreme ultraviolet light. By combining the fundamental and second harmonic of an 800 nm laser in a hollow-core fiber, with varying relative polarizations, and by observing the pressure and power scaling of the various harmonic orders, we show that the data are consistent with a picture where we drive the process of high-harmonic generation, which in turn drives four-wave frequency mixing processes in the extreme EUV. This work promises a method for extending nonlinear optics into the extreme ultraviolet region of the spectrum using an approach that has not previously been considered, and has compelling implications for generating tunable light at short wavelengths

  5. Impaired mixed emotion processing in the right ventrolateral prefrontal cortex in schizophrenia: an fMRI study.

    Science.gov (United States)

    Szabó, Ádám György; Farkas, Kinga; Marosi, Csilla; Kozák, Lajos R; Rudas, Gábor; Réthelyi, János; Csukly, Gábor

    2017-12-08

    Schizophrenia has a negative effect on the activity of the temporal and prefrontal cortices in the processing of emotional facial expressions. However no previous research focused on the evaluation of mixed emotions in schizophrenia, albeit they are frequently expressed in everyday situations and negative emotions are frequently expressed by mixed facial expressions. Altogether 37 subjects, 19 patients with schizophrenia and 18 healthy control subjects were enrolled in the study. The two study groups did not differ in age and education. The stimulus set consisted of 10 fearful (100%), 10 happy (100%), 10 mixed fear (70% fear and 30% happy) and 10 mixed happy facial expressions. During the fMRI acquisition pictures were presented in a randomized order and subjects had to categorize expressions by button press. A decreased activation was found in the patient group during fear, mixed fear and mixed happy processing in the right ventrolateral prefrontal cortex (VLPFC) and the right anterior insula (RAI) at voxel and cluster level after familywise error correction. No difference was found between study groups in activations to happy facial condition. Patients with schizophrenia did not show a differential activation between mixed happy and happy facial expression similar to controls in the right dorsolateral prefrontal cortex (DLPFC). Patients with schizophrenia showed decreased functioning in right prefrontal regions responsible for salience signaling and valence evaluation during emotion recognition. Our results indicate that fear and mixed happy/fear processing are impaired in schizophrenia, while happy facial expression processing is relatively intact.

  6. Testing and evaluation of alternative process systems for immobilizing radioactive mixed particulate waste in cement

    International Nuclear Information System (INIS)

    Weingardt, K.M.; Weber, J.R.

    1994-03-01

    Radioactive and Hazardous Mixed Wastes have accumulated at the Department of Energy (DOE) Hanford Site in south-central Washington State. Ongoing operations and planned facilities at Hanford will also contribute to this waste stream. To meet the Resource Conservation and Recovery Act (RCRA) Land Disposal Restrictions most of this waste will need to be treated to permit disposal. In general this treatment will need to include stabilization/solidification either as a sole method or as part of a treatment train. A planned DOE facility, the Waste Receiving and Processing (WRAP) Module 2A, is scoped to provide this required treatment for containerized contact-handled (CH), mixed low-level waste (MLLW) at Hanford. An engineering development program has been conducted by Westinghouse Hanford Company (WHC) to select the best system for utilizing a cement based process in WRAP Module 2A. Three mixing processes were developed for analysis and testing; in-drum mixing, continuous mixing, and batch mixing. Some full scale tests were conducted and 55 gallon drums of solidified product were produced. These drums were core sampled and examined to evaluate mixing effectiveness. Total solids loading and the order of addition of waste and binder constituents were also varied. The highest confidence approach to meet the WRAP Module 2A waste immobilization system needs appears to be the out-of-drum batch mixing concept. This system is believed to offer the most flexibility and efficiency, given the highly variable and troublesome waste streams feeding the facility

  7. In situ vitrification of a mixed radioactive and hazardous waste site

    International Nuclear Information System (INIS)

    Campbell, B.E.; Koegler, S.S.

    1990-11-01

    A large-scale test of the in situ vitrification (ISV) process was performed on a mixed radioactive and hazardous-chemical contaminated waste site on the Hanford Site in southeastern Washington State. A mixed-waste site was selected for this large-scale test to demonstrate the applicability of ISV to mixed wastes common to many US Department of Energy (DOE) sites. In situ vitrification is a thermal process that converts contaminated soil into a durable, leach-resistant product. Electrodes are inserted into the ground. The goals of the test are to demonstrate at least 99% retention of fission products and hazardous metals in the ISV glass during the test; demonstrate the ability of the ISV off-gas treatment system to process a waste site containing significant quantities of combustible material and demonstrate the ability of ISV to vitrify the site to a depth of 20 ft or greater. The test was completed in April 1990. 5 figs

  8. Measurements of Flow Mixing at Subchannels in a Wire-Wrapped 37-Rod Bundle for a Sodium Cooled Fast Reactor

    International Nuclear Information System (INIS)

    Kim, Hyungmo; Bae, Hwang; Chang, Seok-Kyu; Choi, Sun Rock; Lee, Dong Won; Ko, Yung Joo; Choi, Hae Seob; Euh, Dong-Jin; Lee, Hyeong-Yeon

    2014-01-01

    For a safety analysis in a core thermal design of a sodium-cooled fast reactor (SFR), flow mixing characteristics at subchannels in a wire-wrapped rod bundle are very important. Wrapped wires make a cross flow in a around the fuel rod) of the fuel rod, and this effect lets flow be mixed. Experimental results of flow mixing can be meaningful for verification and validation of thermal mixing correlation in a reactor core thermo-hydraulic design code. A wire mesh sensing technique can be useful method for measuring of flow mixing characteristics. A wire mesh sensor has been traditionally used to measure the void fraction of a two-phase flow field, i.e. gas and liquid. However, it has been recently reported that the wire mesh sensor can be used successfully to recognize the flow field in liquid phase by injecting a tracing liquid with a different level of electric conductivity. This can be powerfully adapted to recognize flow mixing characteristics by wrapped wires in SFR core thermal design. In this work, we conducted the flow mixing experiments using a custom designed wire mesh sensor. To verify and validate computer codes for the SFR core thermal design, mixing experiments were conducted at a hexagonally arrayed 37-pin wire-wrapped fuel rod bundle test section. The well-designed wire mesh sensor was used to measure flow mixing characteristics. The developed post-processing method has its own merits, and flow mixing results were reasonable. In addition, by uncertainty analysis, the system errors and the random error were estimated in experiments. Therefore, the present results and methods can be used for design code verification and validation

  9. Process optimization of friction stir welding based on thermal models

    DEFF Research Database (Denmark)

    Larsen, Anders Astrup

    2010-01-01

    This thesis investigates how to apply optimization methods to numerical models of a friction stir welding process. The work is intended as a proof-of-concept using different methods that are applicable to models of high complexity, possibly with high computational cost, and without the possibility...... information of the high-fidelity model. The optimization schemes are applied to stationary thermal models of differing complexity of the friction stir welding process. The optimization problems considered are based on optimizing the temperature field in the workpiece by finding optimal translational speed....... Also an optimization problem based on a microstructure model is solved, allowing the hardness distribution in the plate to be optimized. The use of purely thermal models represents a simplification of the real process; nonetheless, it shows the applicability of the optimization methods considered...

  10. Combined TGA-MS kinetic analysis of multistep processes. Thermal decomposition and ceramification of polysilazane and polysiloxane preceramic polymers.

    Science.gov (United States)

    García-Garrido, C; Sánchez-Jiménez, P E; Pérez-Maqueda, L A; Perejón, A; Criado, José M

    2016-10-26

    The polymer-to-ceramic transformation kinetics of two widely employed ceramic precursors, 1,3,5,7-tetramethyl-1,3,5,7-tetravinylcyclotetrasiloxane (TTCS) and polyureamethylvinylsilazane (CERASET), have been investigated using coupled thermogravimetry and mass spectrometry (TG-MS), Raman, XRD and FTIR. The thermally induced decomposition of the pre-ceramic polymer is the critical step in the synthesis of polymer derived ceramics (PDCs) and accurate kinetic modeling is key to attaining a complete understanding of the underlying process and to attempt any behavior predictions. However, obtaining a precise kinetic description of processes of such complexity, consisting of several largely overlapping physico-chemical processes comprising the cleavage of the starting polymeric network and the release of organic moieties, is extremely difficult. Here, by using the evolved gases detected by MS as a guide it has been possible to determine the number of steps that compose the overall process, which was subsequently resolved using a semiempirical deconvolution method based on the Frasier-Suzuki function. Such a function is more appropriate that the more usual Gaussian or Lorentzian functions since it takes into account the intrinsic asymmetry of kinetic curves. Then, the kinetic parameters of each constituent step were independently determined using both model-free and model-fitting procedures, and it was found that the processes obey mostly diffusion models which can be attributed to the diffusion of the released gases through the solid matrix. The validity of the obtained kinetic parameters was tested not only by the successful reconstruction of the original experimental curves, but also by predicting the kinetic curves of the overall processes yielded by different thermal schedules and by a mixed TTCS-CERASET precursor.

  11. Thermal and radiation process for nano-/micro-fabrication of crosslinked PTFE

    International Nuclear Information System (INIS)

    Kobayashi, Akinobu; Oshima, Akihiro; Okubo, Satoshi; Tsubokura, Hidehiro; Takahashi, Tomohiro; Oyama, Tomoko Gowa; Tagawa, Seiichi; Washio, Masakazu

    2013-01-01

    Nano-/micro-fabrication process of crosslinked poly(tetrafluoroethylene) (RX-PTFE) is proposed as a novel method using combined process which is thermal and radiation process for fabrication of RX-PTFE (TRaf process). Nano- and micro-scale patterns of silicon wafers fabricated by EB lithography were used as the molds for TRaf process. Poly(tetrafluoroethylene) (PTFE) dispersion was dropped on the fabricated molds, and then PTFE was crosslinked with doses from 105 kGy to 1500 kGy in its molten state at 340 °C in nitrogen atmosphere. The obtained nano- and micro-structures by TRaf process were compared with those by the conventional thermal fabrication process. Average surface roughness (R a ) of obtained structures was evaluated with atomic force microscope (AFM) and scanning electron microscope (SEM). R a of obtained structures with the crosslinking dose of 600 kGy showed less than 1.2 nm. The fine nano-/micro-structures of crosslinked PTFE were successfully obtained by TRaf process

  12. Application of a thermally assisted mechanical dewatering process to biomass

    Energy Technology Data Exchange (ETDEWEB)

    Mahmoud, A.; Arlabosse, P. [Universite de Toulouse, Mines Albi, CNRS, Campus Jarlard, F-81013 Albi cedex 09 (France); Ecole des Mines Albi, Centre RAPSODEE, Campus Jarlard, F-81013 Albi (France); Fernandez, A. [Universite de Toulouse, INSA, UPS, INP, LISBP, 135 Avenue de Rangueil, F-31400 Toulouse (France); INRA, UMR792 Ingenierie des Systemes Biologiques et des Procedes, CNRS, UMR5504, F-31400 Toulouse (France)

    2011-01-15

    Thermally assisted mechanical dewatering (TAMD) is a new process for energy-efficient liquid/solids separation which enhances conventional-device efficiency. The main idea of this process is to supply a flow of heat in mechanical dewatering processes to favour the reduction of the liquid content. This is not a new idea but the proposed combination, especially the chosen operating conditions (T < 100 C and P < 3000 kPa) constitutes an original approach and a significant energy saving since the liquid is kept in liquid state. Response surface methodology was used to evaluate the effects of the processing parameters of TAMD on the final dry solids content, which is a fundamental dewatering parameter and an excellent indicator of the extent of TAMD. In this study, a two-factor central composite design was used to establish the optimum conditions for the TAMD of alfalfa biomass. Experiments were carried out on a laboratory compression cell. Experiments showed that the dewatering enhancement results only from thermal effects. With a moderate heat supply (T{sub piston} = 80 C), the dry solid content of the press cake can reach 66%, compared to 36% at ambient temperature. A significant regression model, describing changes on final dry solids content with respect to independent variables, was established with determination coefficient, R{sup 2}, greater than 88%. With an energy consumption of less than 150 kWh/m{sup 3}, the use of the TAMD process before a thermal drying process leads to an energy saving of at least 30% on the overall separation chain. (author)

  13. The analysis of thermally stimulated processes

    CERN Document Server

    Chen, R; Pamplin, Brian

    1981-01-01

    Thermally stimulated processes include a number of phenomena - either physical or chemical in nature - in which a certain property of a substance is measured during controlled heating from a 'low' temperature. Workers and graduate students in a wide spectrum of fields require an introduction to methods of extracting information from such measurements. This book gives an interdisciplinary approach to various methods which may be applied to analytical chemistry including radiation dosimetry and determination of archaeological and geological ages. In addition, recent advances are included, such

  14. Thermal conductivity and Kapitza resistance of cyanate ester epoxy mix and tri-functional epoxy electrical insulations at superfluid helium temperature

    CERN Document Server

    Pietrowicz, S; Jones, S; Canfer, S; Baudouy, B

    2012-01-01

    In the framework of the European Union FP7 project EuCARD, two composite insulation systems made of cyanate ester epoxy mix and tri-functional epoxy (TGPAP-DETDA) with S-glass fiber have been thermally tested as possible candidates to be the electrical insulation of 13 T Nb$_{3}$Sn high field magnets under development for this program. Since it is expected to be operated in pressurized superfluid helium at 1.9 K and 1 atm, the thermal conductivity and the Kapitza resistance are the most important input parameters for the thermal design of this type of magnet and have been determined in this study. For determining these thermal properties, three sheets of each material with different thicknesses varying from 245 μm to 598 μm have been tested in steady-state condition in the temperature range of 1.6 K - 2.0 K. The thermal conductivity for the tri-functional epoxy (TGPAP-DETDA) epoxy resin insulation is found to be k=[(34.2±5.5).T-(16.4±8.2)]×10-3 Wm-1K-1 and for the cyanate ester epoxy k=[(26.8±4.8).T- (9...

  15. What can recycling in thermal reactors accomplish?

    International Nuclear Information System (INIS)

    Piet, Steven J.; Matthern, Gretchen E.; Jacobson, Jacob J.

    2007-01-01

    Thermal recycle provides several potential benefits when used as stop-gap, mixed, or backup recycling to recycling in fast reactors. These three roles involve a mixture of thermal and fast recycling; fast reactors are required to some degree at some time. Stop-gap uses thermal reactors only until fast reactors are adequately deployed and until any thermal-recycle-only facilities have met their economic lifetime. Mixed uses thermal and fast reactors symbiotically for an extended period of time. Backup uses thermal reactors only if problems later develop in the fast reactor portion of a recycling system. Thermal recycle can also provide benefits when used as pure thermal recycling, with no intention to use fast reactors. However, long term, the pure thermal recycling approach is inadequate to meet several objectives. (authors)

  16. What can Recycling in Thermal Reactors Accomplish?

    International Nuclear Information System (INIS)

    Steven Piet; Gretchen E. Matthern; Jacob J. Jacobson

    2007-01-01

    Thermal recycle provides several potential benefits when used as stop-gap, mixed, or backup recycling to recycling in fast reactors. These three roles involve a mixture of thermal and fast recycling; fast reactors are required to some degree at some time. Stop-gap uses thermal reactors only until fast reactors are adequately deployed and until any thermal-recycle-only facilities have met their economic lifetime. Mixed uses thermal and fast reactors symbiotically for an extended period of time. Backup uses thermal reactors only if problems later develop in the fast reactor portion of a recycling system. Thermal recycle can also provide benefits when used as pure thermal recycling, with no intention to use fast reactors. However, long term, the pure thermal recycling approach is inadequate to meet several objectives

  17. Impacts of Subgrid Heterogeneous Mixing between Cloud Liquid and Ice on the Wegner-Bergeron-Findeisen Process and Mixed-phase Clouds in NCAR CAM5

    Science.gov (United States)

    Liu, X.; Zhang, M.; Zhang, D.; Wang, Z.; Wang, Y.

    2017-12-01

    Mixed-phase clouds are persistently observed over the Arctic and the phase partitioning between cloud liquid and ice hydrometeors in mixed-phase clouds has important impacts on the surface energy budget and Arctic climate. In this study, we test the NCAR Community Atmosphere Model Version 5 (CAM5) with the single-column and weather forecast configurations and evaluate the model performance against observation data from the DOE Atmospheric Radiation Measurement (ARM) Program's M-PACE field campaign in October 2004 and long-term ground-based multi-sensor remote sensing measurements. Like most global climate models, we find that CAM5 also poorly simulates the phase partitioning in mixed-phase clouds by significantly underestimating the cloud liquid water content. Assuming pocket structures in the distribution of cloud liquid and ice in mixed-phase clouds as suggested by in situ observations provides a plausible solution to improve the model performance by reducing the Wegner-Bergeron-Findeisen (WBF) process rate. In this study, the modification of the WBF process in the CAM5 model has been achieved with applying a stochastic perturbation to the time scale of the WBF process relevant to both ice and snow to account for the heterogeneous mixture of cloud liquid and ice. Our results show that this modification of WBF process improves the modeled phase partitioning in the mixed-phase clouds. The seasonal variation of mixed-phase cloud properties is also better reproduced in the model in comparison with the long-term ground-based remote sensing observations. Furthermore, the phase partitioning is insensitive to the reassignment time step of perturbations.

  18. Design optimization of single mixed refrigerant LNG process using a hybrid modified coordinate descent algorithm

    Science.gov (United States)

    Qyyum, Muhammad Abdul; Long, Nguyen Van Duc; Minh, Le Quang; Lee, Moonyong

    2018-01-01

    Design optimization of the single mixed refrigerant (SMR) natural gas liquefaction (LNG) process involves highly non-linear interactions between decision variables, constraints, and the objective function. These non-linear interactions lead to an irreversibility, which deteriorates the energy efficiency of the LNG process. In this study, a simple and highly efficient hybrid modified coordinate descent (HMCD) algorithm was proposed to cope with the optimization of the natural gas liquefaction process. The single mixed refrigerant process was modeled in Aspen Hysys® and then connected to a Microsoft Visual Studio environment. The proposed optimization algorithm provided an improved result compared to the other existing methodologies to find the optimal condition of the complex mixed refrigerant natural gas liquefaction process. By applying the proposed optimization algorithm, the SMR process can be designed with the 0.2555 kW specific compression power which is equivalent to 44.3% energy saving as compared to the base case. Furthermore, in terms of coefficient of performance (COP), it can be enhanced up to 34.7% as compared to the base case. The proposed optimization algorithm provides a deep understanding of the optimization of the liquefaction process in both technical and numerical perspectives. In addition, the HMCD algorithm can be employed to any mixed refrigerant based liquefaction process in the natural gas industry.

  19. The case for mixed dark matter from sterile neutrinos

    International Nuclear Information System (INIS)

    Lello, Louis; Boyanovsky, Daniel

    2016-01-01

    Sterile neutrinos are SU(2) singlets that mix with active neutrinos via a mass matrix, its diagonalization leads to mass eigenstates that couple via standard model vertices. We study the cosmological production of heavy neutrinos via standard model charged and neutral current vertices under a minimal set of assumptions: i) the mass basis contains a hierarchy of heavy neutrinos , ii) these have very small mixing angles with the active (flavor) neutrinos, iii) standard model particles, including light (active-like) neutrinos are in thermal equilibrium. If kinematically allowed, the same weak interaction processes that produce active-like neutrinos also produce the heavier species. We introduce the quantum kinetic equations that describe their production, freeze out and decay and discuss the various processes that lead to their production in a wide range of temperatures assessing their feasibility as dark matter candidates. The final distribution function at freeze-out is a mixture of the result of the various production processes. We identify processes in which finite temperature collective excitations may lead to the production of the heavy species. As a specific example, we consider the production of heavy neutrinos in the mass range M h ∼< 140 MeV from pion decay shortly after the QCD crossover including finite temperature corrections to the pion form factors and mass. We consider the different decay channels that allow for the production of heavy neutrinos showing that their frozen distribution functions exhibit effects from ''kinematic entanglement'' and argue for their viability as mixed dark matter candidates. We discuss abundance, phase space density and stability constraints and argue that heavy neutrinos with lifetime τ> 1/ H 0 freeze out of local thermal equilibrium, and conjecture that those with lifetimes τ || 1/ H 0 may undergo cascade decay into lighter DM candidates and/or inject non-LTE neutrinos into the cosmic neutrino

  20. The case for mixed dark matter from sterile neutrinos

    Energy Technology Data Exchange (ETDEWEB)

    Lello, Louis; Boyanovsky, Daniel, E-mail: lal81@pitt.edu, E-mail: boyan@pitt.edu [Department of Physics and Astronomy, University of Pittsburgh, Pittsburgh, PA 15260 (United States)

    2016-06-01

    Sterile neutrinos are SU(2) singlets that mix with active neutrinos via a mass matrix, its diagonalization leads to mass eigenstates that couple via standard model vertices. We study the cosmological production of heavy neutrinos via standard model charged and neutral current vertices under a minimal set of assumptions: i) the mass basis contains a hierarchy of heavy neutrinos , ii) these have very small mixing angles with the active (flavor) neutrinos, iii) standard model particles, including light (active-like) neutrinos are in thermal equilibrium. If kinematically allowed, the same weak interaction processes that produce active-like neutrinos also produce the heavier species. We introduce the quantum kinetic equations that describe their production, freeze out and decay and discuss the various processes that lead to their production in a wide range of temperatures assessing their feasibility as dark matter candidates. The final distribution function at freeze-out is a mixture of the result of the various production processes. We identify processes in which finite temperature collective excitations may lead to the production of the heavy species. As a specific example, we consider the production of heavy neutrinos in the mass range M {sub h} ∼< 140 MeV from pion decay shortly after the QCD crossover including finite temperature corrections to the pion form factors and mass. We consider the different decay channels that allow for the production of heavy neutrinos showing that their frozen distribution functions exhibit effects from ''kinematic entanglement'' and argue for their viability as mixed dark matter candidates. We discuss abundance, phase space density and stability constraints and argue that heavy neutrinos with lifetime τ> 1/ H {sub 0} freeze out of local thermal equilibrium, and conjecture that those with lifetimes τ || 1/ H {sub 0} may undergo cascade decay into lighter DM candidates and/or inject non-LTE neutrinos into the

  1. A Novel Approach to Enhance the Mechanical Strength and Electrical and Thermal Conductivity of Cu-GNP Nanocomposites

    Science.gov (United States)

    Saboori, Abdollah; Pavese, Matteo; Badini, Claudio; Fino, Paolo

    2018-01-01

    Copper/graphene nanoplatelet (GNP) nanocomposites were produced by a wet mixing method followed by a classical powder metallurgy technique. A qualitative evaluation of the structure of graphene after mixing indicated that wet mixing is an appropriate dispersion method. Thereafter, the effects of two post-processing techniques such as repressing-annealing and hot isostatic pressing (HIP) on density, interfacial bonding, hardness, and thermal and electrical conductivity of the nanocomposites were analyzed. Density evaluations showed that the relative density of specimens increased after the post-processing steps so that after HIPing almost full densification was achieved. The Vickers hardness of specimens increased considerably after the post-processing techniques. The thermal conductivity of pure copper was very low in the case of the as-sintered samples containing 2 to 3 pct porosity and increased considerably to a maximum value in the case of HIPed samples which contained only 0.1 to 0.2 pct porosity. Electrical conductivity measurements showed that by increasing the graphene content electrical conductivity decreased.

  2. Colosed-Loop Control of the Thermal Stir Welding Process to Enable Rapid Process/Ppart Qualification, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — Thermal Stir Welding (TSW) provides advancement over the more conventional Friction Stir Welding (C-FSW) process because it separates the primary processes variables...

  3. Closed-Loop Control of the Thermal Stir Welding Process to Enable Rapid Process/Part Qualification, Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — Thermal Stir Welding (TSW) provides advancement over the more conventional Friction Stir Welding (C-FSW) process because it separates the primary processes variables...

  4. Thermal Properties of Anionic Polyurethane Composition for Leather Finishing

    Directory of Open Access Journals (Sweden)

    Olga KOVTUNENKO

    2016-09-01

    Full Text Available Thermal properties of anionic polyurethane composition mixed with collagen product and hydrophilic sodium form of montmorillonite for use in the finishing of leather were studied by thermogravimetric method. The thermal indices of processes of thermal and thermo-oxidative destruction depending on the polyurethane composition were determined. The influence of anionic polyurethane composition on thermal behavior of chromium tanned gelatin films that imitate the leather were studied. APU composition with natural compounds increases their thermal stability both in air and in nitrogen atmosphere due to the formation of additional bonds between active groups of APU, protein and chrome tanning agent as the result of chemical reactions between organic and inorganic parts with the new structure formation.DOI: http://dx.doi.org/10.5755/j01.ms.22.3.10043

  5. The Analysis for the Effect of Mixing Vane Shape on TDC

    International Nuclear Information System (INIS)

    Moon, Kang Hoon; Park, Ho Young; Kim, Kang Hoon; Park, Eung Jun; Suh, Jung Min

    2011-01-01

    The Thermal Diffusion Coefficient (TDC) is an input parameter to subchannel code, and it is required to predict local flow conditions in a PWR fuel bundle. TDC influences on the prediction of thermal interchange or mixing of thermal energy between the hot subchannel and interconnected adjacent subchannels. The thermal mixing term in the energy equation is generally represented in terms of a non-dimensional inverse Peclet number or TDC. The parameters associated with thermal mixing can be defined as Eq.(1): TDC =Pe x De/a (1) where: Pe : Inverse Peclet Number (dimensionless) = ε/ Va De : Equivalent hydraulic diameter, in. a : Lateral flow area between channels per unit length, in 2 /in ε : Mixing coefficient, in 2 /sec V : Velocity, in/sec TDC is an important factor to evaluate thermal performance. So, flow temperature maps were obtained from the 5x5 rod bundle test section to assess the thermal performance of corresponding fuels. The flow temperatures were measured by thermocouple at the end of heated length and the centroid of subchannel. There are two typical methods to arrange the hot and cold fuel rods as shown in Fig. 1. Configuration Fig. 1(b) is adopted in this work. This paper presents how to determine the TDC and verifies whether all TDC with the effect of mixing vane shape is valid with respect to current design value

  6. Method of thermally processing superplastically formed aluminum-lithium alloys to obtain optimum strengthening

    Science.gov (United States)

    Anton, Claire E. (Inventor)

    1993-01-01

    Optimum strengthening of a superplastically formed aluminum-lithium alloy structure is achieved via a thermal processing technique which eliminates the conventional step of solution heat-treating immediately following the step of superplastic forming of the structure. The thermal processing technique involves quenching of the superplastically formed structure using static air, forced air or water quenching.

  7. Thermal, mechanical and morphological properties of poly (hydroxybutyrate and polypropylene blends after processing

    Directory of Open Access Journals (Sweden)

    Wagner Mauricio Pachekoski

    2009-06-01

    Full Text Available The ever increasing accumulation of plastic waste in the environment has motivated research on polymers that degrade rapidly after being discarded as possible substitutes for conventional inert plastics. Biodegradable polymers can be an alternative, since they have non-toxic residual products and low environmental permanence. Poly (hydroxybutyrate is a biodegradable polymer with a strong potential for industrial purposes, but its thermal instability and fragility limit its applications. Thus, an alternative to improve the processability and properties of poly (hydroxybutyrate is to mix it with another polymer, not necessarily a biodegradable one. In this work, different mixtures of poly(hydroxybutyrate or PHB and polypropylene or PP were extruded and injected. After processing, the blends were studied and their miscibility, mechanical properties and degradability in different soils were analyzed. The main results indicated that the PHB/PP blends had better mechanical properties than pure PHB, as well as improved immiscibility and higher degradation in alkaline soil. The poly-hydroxybutyrate/polypropylene blends showed a tendency for lower crystallinity and stiffness of the polymer matrix, proportional to the amount of polypropylene in the blends, rendering them less stiff and fragile. The degradation tests showed that both pure PHB and blends with 90% PHB and 10% PP were degraded, with loss of their mechanical properties and weight.

  8. Novel room-temperature-setting phosphate ceramics for stabilizing combustion products and low-level mixed wastes

    International Nuclear Information System (INIS)

    Wagh, A.S.; Singh, D.

    1994-01-01

    Argonne National Laboratory, with support from the Office of Technology in the US Department of Energy (DOE), has developed a new process employing novel, chemically bonded ceramic materials to stabilize secondary waste streams. Such waste streams result from the thermal processes used to stabilize low-level, mixed wastes. The process will help the electric power industry treat its combustion and low-level mixed wastes. The ceramic materials are strong, dense, leach-resistant, and inexpensive to fabricate. The room-temperature-setting process allows stabilization of volatile components containing lead, mercury, cadmium, chromium, and nickel. The process also provides effective stabilization of fossil fuel combustion products. It is most suitable for treating fly and bottom ashes

  9. Comparison of silicon pin diode detector fabrication processes using ion implantation and thermal doping

    International Nuclear Information System (INIS)

    Zhou, C.Z.; Warburton, W.K.

    1996-01-01

    Two processes for the fabrication of silicon p-i-n diode radiation detectors are described and compared. Both processes are compatible with conventional integrated-circuit fabrication techniques and yield very low leakage currents. Devices made from the process using boron thermal doping have about a factor of 2 lower leakage current than those using boron ion implantation. However, the boron thermal doping process requires additional process steps to remove boron skins. (orig.)

  10. Characterization of mixed Nd :LuxGd1-xVO4 laser crystals

    Science.gov (United States)

    Yu, H. H.; Zhang, H. J.; Wang, Z. P.; Wang, J. Y.; Yu, Y. G.; Cheng, X. F.; Shao, Z. S.; Jiang, M. H.; Ling, Z. C.; Xia, H. R.

    2007-06-01

    A series of laser crystals Nd :LuxGd1-xVO4 (x=0.14,0.32,0.50,0.61,0.70,0.80) was grown by the Czochralski method. The thermal properties, including the average linear thermal expansion coefficients, thermal diffusion coefficients, specific heats, and thermal conductivities, of the mixed crystals were obtained. The material constants Ms for the thermal stress resistance figure were calculated and showed that the thermal fracture limits of the mixed crystals should be comparable with that of Nd :YVO4. The polarization absorption spectra from 240to1000nm were measured at room temperature and the absorption cross sections at 809nm were calculated. Using the Judd-Ofelt theory, the theoretical radiative lifetimes were calculated and compared with the experimental results. Continuous wave laser performances were achieved with the mixed crystals at the wavelength of 1.06μm when they were pumped by a laser diode. Thermal, optical, and laser properties have shown variation as a function of x and proved that the mixed crystals are good laser materials.

  11. The interaction of horizontal eddy transport and thermal drive in the stratosphere

    Science.gov (United States)

    Salby, Murry L.; O'Sullivan, Donal; Callaghan, Patrick; Garcia, Rolando R.

    1990-01-01

    The two processes that determine the average state of the circulation; i.e., horizontal eddy transport and thermal dissipation, are examined, and the effects of their interaction on circulation and on tracer distribution in the stratosphere are investigated using barotropic calculations on the sphere. It is shown that eddy advection tends to homogenize the meridional gradient Q at low latitudes, while thermal dissipation restores the gradient after episodes of mixing.

  12. Thermal Transport and Entropy Production Mechanisms in a Turbulent Round Jet at Supercritical Thermodynamic Conditions

    Directory of Open Access Journals (Sweden)

    Florian Ries

    2017-08-01

    Full Text Available In the present paper, thermal transport and entropy production mechanisms in a turbulent round jet of compressed nitrogen at supercritical thermodynamic conditions are investigated using a direct numerical simulation. First, thermal transport and its contribution to the mixture formation along with the anisotropy of heat fluxes and temperature scales are examined. Secondly, the entropy production rates during thermofluid processes evolving in the supercritical flow are investigated in order to identify the causes of irreversibilities and to display advantageous locations of handling along with the process regimes favorable to mixing. Thereby, it turned out that (1 the jet disintegration process consists of four main stages under supercritical conditions (potential core, separation, pseudo-boiling, turbulent mixing, (2 causes of irreversibilities are primarily due to heat transport and thermodynamic effects rather than turbulence dynamics and (3 heat fluxes and temperature scales appear anisotropic even at the smallest scales, which implies that anisotropic thermal diffusivity models might be appropriate in the context of both Reynolds-averaged Navier–Stokes (RANS and large eddy simulation (LES approaches while numerically modeling supercritical fluid flows.

  13. Image processing techniques for thermal, x-rays and nuclear radiations

    International Nuclear Information System (INIS)

    Chadda, V.K.

    1998-01-01

    The paper describes image acquisition techniques for the non-visible range of electromagnetic spectrum especially thermal, x-rays and nuclear radiations. Thermal imaging systems are valuable tools used for applications ranging from PCB inspection, hot spot studies, fire identification, satellite imaging to defense applications. Penetrating radiations like x-rays and gamma rays are used in NDT, baggage inspection, CAT scan, cardiology, radiography, nuclear medicine etc. Neutron radiography compliments conventional x-rays and gamma radiography. For these applications, image processing and computed tomography are employed for 2-D and 3-D image interpretation respectively. The paper also covers main features of image processing systems for quantitative evaluation of gray level and binary images. (author)

  14. Role of thermal analysis in uranium oxide fuel fabrication process

    International Nuclear Information System (INIS)

    Balaji Rao, Y.; Yadav, R.B.

    2006-01-01

    The present paper discusses the application of thermal analysis, particularly, differential thermal analysis (Dta) at various stages of fuel fabrication process. The useful role of Dta in knowing the decomposition pattern and calcination temperature of Adu along with de-nitration temperature is explained. The decomposition pattern depends upon the type of drying process adopted for wet ADU cake (ADU C). Also, the paper highlights the utility of DTA in determining the APS and SSA of UO 2+x and U 3 O 8 powders as an alternate technique. Further, the temperature difference (ΔT max ) between the two exothermic peaks obtained in UO 2+x powder oxidation is related to sintered density of UO 2 pellets. (author)

  15. Foundations of High-Pressure Thermal Plasmas

    Science.gov (United States)

    Murphy, Anthony B.; Uhrlandt, Dirk

    2018-06-01

    An introduction to the main methods used to produce, model and measure thermal plasmas is provided, with emphasis on the differences between thermal plasmas and other types of processing plasmas. The critical properties of thermal plasmas are explained in physical terms and their importance in different applications is considered. The characteristics, and advantages and disadvantages, of the different main types of thermal plasmas (transferred and non-transferred arcs, radio-frequency inductively-coupled plasmas and microwave plasmas) are discussed. The methods by which flow is stabilized in arc plasmas are considered. The important concept of local thermodynamic equilibrium (LTE) is explained, leading into a discussion of the importance of thermophysical properties, and their calculation in LTE and two-temperature plasmas. The standard equations for modelling thermal plasmas are presented and contrasted with those used for non-equilibrium plasmas. Treatments of mixed-gas and non-LTE plasmas are considered, as well as the sheath regions adjacent to electrodes. Finally, the main methods used for electrical, optical, spectroscopic and laser diagnostics of thermal plasmas are briefly introduced, with an emphasis on the required assumptions for their reliable implementation, and the specific requirements of thermal plasmas.

  16. Implications of neutrino masses and mixing for weak processes

    International Nuclear Information System (INIS)

    Shrock, R.E.

    1981-01-01

    A general theory is presented of weak processes involving neutrinos which consistently incorporates the possibility of nonzero neutrino masses and associated lepton mixing. The theory leads to new tests for and bounds on such masses and mixing. These tests make use of (π,K)/sub l2/ decay, nuclear β decay, and μ and tau decays, among others. New experiments at SIN and KEK to apply the tests are mentioned. Further, some implications are discussed for (1) the analysis of the spectral parameters in leptonic decays to determine the Lorentz structure of the weak leptonic couplings; (2) fundamental weak interaction constants such as G/sub μ/, G/sub V/', f/sub π/, f/sub K/, V/sub uq/, q = d or s, m/sub W/, and m/sub Z/; and (3) neutrino propagation

  17. 76 FR 81363 - Temperature-Indicating Devices; Thermally Processed Low-Acid Foods Packaged in Hermetically...

    Science.gov (United States)

    2011-12-28

    ... amended FDA's regulations for thermally processed low-acid foods packaged in hermetically sealed... DEPARTMENT OF HEALTH AND HUMAN SERVICES Food and Drug Administration 21 CFR Part 113 [Docket No. FDA-2007-N-0265] (formerly 2007N-0026) Temperature-Indicating Devices; Thermally Processed Low-Acid...

  18. Optimization of thermal processing of canned mussels.

    Science.gov (United States)

    Ansorena, M R; Salvadori, V O

    2011-10-01

    The design and optimization of thermal processing of solid-liquid food mixtures, such as canned mussels, requires the knowledge of the thermal history at the slowest heating point. In general, this point does not coincide with the geometrical center of the can, and the results show that it is located along the axial axis at a height that depends on the brine content. In this study, a mathematical model for the prediction of the temperature at this point was developed using the discrete transfer function approach. Transfer function coefficients were experimentally obtained, and prediction equations fitted to consider other can dimensions and sampling interval. This model was coupled with an optimization routine in order to search for different retort temperature profiles to maximize a quality index. Both constant retort temperature (CRT) and variable retort temperature (VRT; discrete step-wise and exponential) were considered. In the CRT process, the optimal retort temperature was always between 134 °C and 137 °C, and high values of thiamine retention were achieved. A significant improvement in surface quality index was obtained for optimal VRT profiles compared to optimal CRT. The optimization procedure shown in this study produces results that justify its utilization in the industry.

  19. Thermal homogeneity of plastication processes in single-screw extruders

    Science.gov (United States)

    Bu, L. X.; Agbessi, Y.; Béreaux, Y.; Charmeau, J.-Y.

    2018-05-01

    Single-screw plastication, used in extrusion and in injection moulding, is a major way of processing commodity thermoplastics. During the plastication phase, the polymeric material is melted by the combined effects of shear-induced self-heating (viscous dissipation) and heat conduction coming from the barrel. In injection moulding, a high level of reliability is usually achieved that makes this process ideally suited to mass market production. Nonetheless, process fluctuations still appear that make moulded part quality control an everyday issue. In this work, we used a combined modelling of plastication, throughput calculation and laminar dispersion, to investigate if, and how, thermal fluctuations could propagate along the screw length and affect the melt homogeneity at the end of the metering section. To do this, we used plastication models to relate changes in processing parameters to changes in the plastication length. Moreover, a simple model of throughput calculation is used to relate the screw geometry, the polymer rheology and the processing parameters to get a good estimate of the mass flow rate. Hence, we found that the typical residence time in a single screw is around one tenth of the thermal diffusion time scale. This residence time is too short for the dispersion coefficient to reach a steady state, but too long to be able to neglect radial thermal diffusion and resort to a purely convective solution. Therefore, a full diffusion/convection problem has to be solved with a base flow described by the classic pressure and drag velocity field. Preliminary results already show the major importance of the processing parameters in the breakthrough curve of an arbitrary temperature fluctuation at the end of the metering section of injection moulding screw. When the flow back-pressure is high, the temperature fluctuation is spread more evenly with time, whereas a pressure drop in the flow will results in a breakthrough curve which presents a larger peak of

  20. Evaluation of thermal and non-thermal processing effect on non-prebiotic and prebiotic acerola juices using 1H qNMR and GC-MS coupled to chemometrics.

    Science.gov (United States)

    Alves Filho, Elenilson G; Silva, Lorena Mara A; de Brito, Edy S; Wurlitzer, Nedio Jair; Fernandes, Fabiano A N; Rabelo, Maria Cristiane; Fonteles, Thatyane V; Rodrigues, Sueli

    2018-11-01

    The effects of thermal (pasteurization and sterilization) and non-thermal (ultrasound and plasma) processing on the composition of prebiotic and non-prebiotic acerola juices were evaluated using NMR and GC-MS coupled to chemometrics. The increase in the amount of Vitamin C was the main feature observed after thermal processing, followed by malic acid, choline, trigonelline, and acetaldehyde. On the other hand, thermal processing increased the amount of 2-furoic acid, a degradation product from ascorbic acid, as well as influenced the decrease in the amount of esters and alcohols. In general, the non-thermal processing did not present relevant effect on juices composition. The addition of prebiotics (inulin and gluco-oligosaccharides) decreased the effect of processing on juices composition, which suggested a protective effect by microencapsulation. Therefore, chemometric evaluation of the 1 H qNMR and GC-MS dataset was suitable to follow changes in acerola juice under different processing. Copyright © 2018 Elsevier Ltd. All rights reserved.

  1. Fundamental limitations of non-thermal plasma processing for internal combustion engine NOx control

    International Nuclear Information System (INIS)

    Penetrante, B.M.

    1993-01-01

    This paper discusses the physics and chemistry of non-thermal plasma processing for post-combustion NO x control in internal combustion engines. A comparison of electron beam and electrical discharge processing is made regarding their power consumption, radical production, NO x removal mechanisms, and by product formation. Can non-thermal deNO x operate efficiently without additives or catalysts? How much electrical power does it cost to operate? What are the by-products of the process? This paper addresses these fundamental issues based on an analysis of the electron-molecule processes and chemical kinetics

  2. A thermal spike analysis of low energy ion activated surface processes

    International Nuclear Information System (INIS)

    Gilmore, G.M.; Haeri, A.; Sprague, J.A.

    1989-01-01

    This paper reports a thermal spike analysis utilized to predict the time evolution of energy propagation through a solid resulting from energetic particle impact. An analytical solution was developed that can predict the number of surface excitations such as desorption, diffusion or chemical reaction activated by an energetic particle. The analytical solution is limited to substrates at zero Kelvin and to materials with constant thermal diffusivities. These limitations were removed by developing a computer numerical integration of the propagation of the thermal spike through the solid and the subsequent activation of surface processes

  3. Modeling thermal inkjet and cell printing process using modified pseudopotential and thermal lattice Boltzmann methods

    Science.gov (United States)

    Sohrabi, Salman; Liu, Yaling

    2018-03-01

    Pseudopotential lattice Boltzmann methods (LBMs) can simulate a phase transition in high-density ratio multiphase flow systems. If coupled with thermal LBMs through equation of state, they can be used to study instantaneous phase transition phenomena with a high-temperature gradient where only one set of formulations in an LBM system can handle liquid, vapor, phase transition, and heat transport. However, at lower temperatures an unrealistic spurious current at the interface introduces instability and limits its application in real flow system. In this study, we proposed new modifications to the LBM system to minimize a spurious current which enables us to study nucleation dynamic at room temperature. To demonstrate the capabilities of this approach, the thermal ejection process is modeled as one example of a complex flow system. In an inkjet printer, a thermal pulse instantly heats up the liquid in a microfluidic chamber and nucleates bubble vapor providing the pressure pulse necessary to eject droplets at high speed. Our modified method can present a more realistic model of the explosive vaporization process since it can also capture a high-temperature/density gradient at nucleation region. Thermal inkjet technology has been successfully applied for printing cells, but cells are susceptible to mechanical damage or death as they squeeze out of the nozzle head. To study cell deformation, a spring network model, representing cells, is connected to the LBM through the immersed boundary method. Looking into strain and stress distribution of a cell membrane at its most deformed state, it is found that a high stretching rate effectively increases the rupture tension. In other words, membrane deformation energy is released through creation of multiple smaller nanopores rather than big pores. Overall, concurrently simulating multiphase flow, phase transition, heat transfer, and cell deformation in one unified LB platform, we are able to provide a better insight into the

  4. Modeling thermal inkjet and cell printing process using modified pseudopotential and thermal lattice Boltzmann methods.

    Science.gov (United States)

    Sohrabi, Salman; Liu, Yaling

    2018-03-01

    Pseudopotential lattice Boltzmann methods (LBMs) can simulate a phase transition in high-density ratio multiphase flow systems. If coupled with thermal LBMs through equation of state, they can be used to study instantaneous phase transition phenomena with a high-temperature gradient where only one set of formulations in an LBM system can handle liquid, vapor, phase transition, and heat transport. However, at lower temperatures an unrealistic spurious current at the interface introduces instability and limits its application in real flow system. In this study, we proposed new modifications to the LBM system to minimize a spurious current which enables us to study nucleation dynamic at room temperature. To demonstrate the capabilities of this approach, the thermal ejection process is modeled as one example of a complex flow system. In an inkjet printer, a thermal pulse instantly heats up the liquid in a microfluidic chamber and nucleates bubble vapor providing the pressure pulse necessary to eject droplets at high speed. Our modified method can present a more realistic model of the explosive vaporization process since it can also capture a high-temperature/density gradient at nucleation region. Thermal inkjet technology has been successfully applied for printing cells, but cells are susceptible to mechanical damage or death as they squeeze out of the nozzle head. To study cell deformation, a spring network model, representing cells, is connected to the LBM through the immersed boundary method. Looking into strain and stress distribution of a cell membrane at its most deformed state, it is found that a high stretching rate effectively increases the rupture tension. In other words, membrane deformation energy is released through creation of multiple smaller nanopores rather than big pores. Overall, concurrently simulating multiphase flow, phase transition, heat transfer, and cell deformation in one unified LB platform, we are able to provide a better insight into the

  5. Thermal properties of fly ash substituted slag cement waste forms for disposal of Savannah River Plant salt waste

    International Nuclear Information System (INIS)

    Roy, D.M.; Kaushal, S.; Licastro, P.H.; Langton, C.A.

    1985-01-01

    Waste processing at the Savannah River Plant will involve reconstitution of the salts (NaNO 3 , NaNO 2 , NaOH, etc.) into a concentrated solution (32 weight percent salts) followed by solidification in a cement-based waste form for burial. The stability and mechanical durability of such a 'saltstone monolith' will depend largely on the temperature reached due to heat of hydration and the thermal properties of the waste form. Fly ash has been used as an inexpensive constituent and to moderate the hydration and setting processes so as to avoid reaching prohibitively high temperatures which could cause thermal stresses. Both high-calcium and low-calcium fly ashes have been studied for this purpose. Other constituents of these mixes include granulated blast furnace slag and finely crushed limestone. Adiabatic temperature increase and thermal conductivity of these mixes have been studied and related x-ray diffraction and scanning electron microscopy studies carried out to understand the hydration process

  6. Development and demonstration of treatment technologies for the processing of US Department of Energy mixed waste

    International Nuclear Information System (INIS)

    Berry, J.B.; Bloom, G.A.; Kuchynka, D.J.

    1994-01-01

    Mixed waste is defined as waste contaminated with chemically hazardous (governed by the Resource Conservation and Recovery Act) and radioactive species [governed by US Department of Energy (DOE) orders]. The Mixed Waste Integrated Program (MWIP) is responding to the need for DOE mixed waste treatment technologies that meet these dual regulatory requirements. MWIP is developing emerging and innovative treatment technologies to determine process feasibility. Technology demonstrations will be used to determine whether processes are superior to existing technologies in reducing risk, minimizing life-cycle cost, and improving process performance. The Program also provides a forum for stakeholder and customer involvement in the technology development process. MWIP is composed of six technical areas that support a mixed-waste treatment system: (1) systems analysis, (2) materials handling, (3) chemical/physical separation, (4) waste destruction and stabilization, (5) off-gas treatment, and (6) final waste form stabilization. The status of the technical initiatives and the current research, development, and demonstration in each of these areas is described in this paper

  7. Mixed-correlated ARFIMA processes for power-law cross-correlations

    Czech Academy of Sciences Publication Activity Database

    Krištoufek, Ladislav

    2013-01-01

    Roč. 392, č. 24 (2013), s. 6484-6493 ISSN 0378-4371 R&D Projects: GA ČR GA402/09/0965 Institutional support: RVO:67985556 Keywords : power-law cross-correlations * long - term memory * econophysics Subject RIV: AH - Economics Impact factor: 1.722, year: 2013 http://library.utia.cas.cz/separaty/2013/E/kristoufek-mixed-correlated arfima processes for power-law cross-correlations.pdf

  8. Simple synthesis of Al{sub 2}O{sub 3} sphere composite from hybrid process with improved thermal stability for catalytic applications

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Regina C.R., E-mail: reginaclaudiasantos@yahoo.com.br [Department of Analytical Chemistry and Physical Chemistry, Federal University of Ceará, Campus of Pici, Fortaleza, CE, CEP: 60440-554 (Brazil); Pinheiro, Antônio N.; Leite, Edson R. [Department of Chemistry, Federal University of São Carlos, São Carlos, SP, CEP: 13560-905 (Brazil); Freire, Valder N. [Department of Physics, Federal University of Ceará, Campus of Pici, Fortaleza, CE, CEP: 60440-554 (Brazil); Longhinotti, Elisane; Valentini, Antoninho [Department of Analytical Chemistry and Physical Chemistry, Federal University of Ceará, Campus of Pici, Fortaleza, CE, CEP: 60440-554 (Brazil)

    2015-06-15

    Aluminium oxide spheres were synthesized by the hybrid process applying the biopolymer chitosan. After the calcination process the porous spheres were characterized by Chemical elemental analysis (XRF), X-ray diffraction (XRD), Scanning electron microscopy and Energy Dispersive X-ray Spectroscopy (SEM-EDS), N{sub 2} adsorption–desorption isotherms, infrared spectroscopy (IR), and CO{sub 2} temperature programmed desorption (CO{sub 2}-TPD). The effect of thermal treatment on surface properties of the oxide spheres was also evaluated by the catalytic ethanol dehydration reaction. The hybrid method produced interesting results related to the thermal stability against sintering process and consequently low decreases of surface area. The hybrid spheres calcination at 900 and 1200 °C produced a metastable phases of alumina with a high surface area, and nanometric crystallites. Additionally, the spheres of mixed silica-alumina synthesized by this method reveal the formation of porous spheres with highly acidic OH groups, which was suggested by the catalytic performance. - Highlights: • Al and Si/Al oxide spheres with promising properties are synthesized by hybrid method. • Al{sub 2}O{sub 3} spheres show high thermal stability and resistance the loss surface area. • The SiO{sub 2} addition plays an important role in the structure and porosity of the spheres. • Al{sub 2}O{sub 3} and SiO{sub 2}/Al{sub 2}O{sub 3} spheres presented a good activity to conversion ethanol. • The activity is related to the surface area and density of OH groups on surface.

  9. Fundamental study on turbulent fluid mixing characteristics in piping systems. Fundamental study on fluid mixing mechanism in T-junction areas

    International Nuclear Information System (INIS)

    Toda, Saburo; Yuki, Kazuhisa; Muramatsu, Toshiharu

    2002-03-01

    In a region where two fluids with different temperatures are mixed together, unsteady temperature fluctuation, i.e. thermal striping, occurs in going through the unstable mixing process of the fluids, and structural materials in the surrounding area may be damaged by high-cycle thermal fatigue. In this report, in order to clarify the relation between the thermal striping and temperature fluctuation of structural wall, PIV measuring system is applied to visualize the fluid mixing state in a T-junction area in which important parameters for the fluid mixing are the flow velocity and aperture ratios of a main pipe to a small pipe and an incidence angle of the small pipe to the main pipe as well as temperature difference of the two flows. As a result of visualization experiments in a isothermal field, it is confirmed that a jet-axis, which is a stream line flowing out from the center of the small pipe, vibrates unsteadily and that its behavior is strongly affected by circulating flow, Karman vortex formed behind the jet axis, and especially flow-fluctuation which exists as a background-flow in the main pipe. Especially, the frequency band of the flow-fluctuation in the main pipe almost corresponds to that of the vibration of the jet-axis where the ratio of flow rate is low. Furthermore, in order to estimate the vibration state of the jet-axis and to find out the conditions for preventing the thermal fatigue, the penetration depth of the jet-axis is generalized. From measurements of temperature fluctuation of wall, it is shown that a high power fluctuation area exists universally behind the junction point of the small pipe where the flow rate of the small pipe flow is relatively lower than that of the main pipe flow. The band of dominant frequency of the temperature fluctuation is almost the same as the flow-fluctuation and the jet-axis vibration mentioned above. In addition, visualization experiments of secondary flow formed in a 90-degree bend, which is installed

  10. Thermal treatment technology at the Idaho National Engineering Laboratory

    International Nuclear Information System (INIS)

    Hillary, J.M.

    1994-01-01

    Recent surveys of mixed wastes in interim storage throughout the 30-site Department of Energy complex indicate that only 12 of those sites account for 98% of such wastes by volume. Current inventories at the Idaho National Engineering Laboratory (INEL) account for 38% of total DOE wastes in interim storage, the largest of any single site. For a large percentage of these waste volumes, as well as the substantial amounts of buried and currently generated wastes, thermal treatment processes have been designated as the technologies of choice. Current facilities and a number of proposed strategies exist for thermal treatment of wastes of this nature at the INEL. High-level radioactive waste is solidified in the Waste Calciner Facility at the Idaho Central Processing Plant. Low-level solid wastes until recently have been processed at the Waste Experimental Reduction Facility (WERF), a compaction, size reduction, and controlled air incineration facility. WERF is currently undergoing process upgrading and RCRA Part B permitting. Recent systems studies have defined effective strategies, in the form of thermal process sequences, for treatment of wastes of the complex and heterogeneous nature in the INEL inventory. This presentation reviews the current status of operating facilities, active studies in this area, and proposed strategies for thermal treatment of INEL wastes

  11. Integrated process analyses studies on mixed low level and transuranic wastes. Summary report

    International Nuclear Information System (INIS)

    1997-12-01

    Options for integrated thermal and nonthermal treatment systems for mixed low-level waste (MLLW) are compared such as total life cycle cost (TLCC), cost sensitivities, risk, energy requirements, final waste volume, and aqueous and gaseous effluents. The comparisons were derived by requiring all conceptual systems to treat the same composition of waste with the same operating efficiency. Thus, results can be used as a general guideline for the selection of treatment and disposal concepts. However, specific applications of individual systems will require further analysis. The potential for cost saving options and the research and development opportunities are summarized

  12. Integrated process analyses studies on mixed low level and transuranic wastes. Summary report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-12-01

    Options for integrated thermal and nonthermal treatment systems for mixed low-level waste (MLLW) are compared such as total life cycle cost (TLCC), cost sensitivities, risk, energy requirements, final waste volume, and aqueous and gaseous effluents. The comparisons were derived by requiring all conceptual systems to treat the same composition of waste with the same operating efficiency. Thus, results can be used as a general guideline for the selection of treatment and disposal concepts. However, specific applications of individual systems will require further analysis. The potential for cost saving options and the research and development opportunities are summarized.

  13. Impact on DNB predictions of mixing models implemented into the three-dimensional thermal-hydraulic code Thyc

    International Nuclear Information System (INIS)

    Banner, D.

    1993-10-01

    The objective of this paper is to point out how departure from nucleate boiling (DNB) predictions can be improved by the THYC software. The EPRI/Columbia University E161 data base has been used for this study. In a first step, three thermal-hydraulic mixing models have been implemented into the code in order to obtain more accurate calculations of local void fractions at the DNB location. The three investigated models (A, B and C) are presented by growing complexity. Model A assumes a constant turbulent viscosity throughout the flow. In model B, a k-L turbulence transport equation has been implemented to model generation and decay of turbulence in the DNB test section. Model C is obtained by representing oriented transverse flows due to mixing vanes in addition to the k-L equation. A parametric study carried out with the three mixing models exhibits the most significant parameters. The occurrence of departure from nucleate boiling is then predicted by using a DNB correlation. Similar results are obtained as long as the DNB correlation is kept unchanged. In a second step, an attempt to substitute correlations by another statistical approach (pseudo-cubic thin-plate type Spline method) has been done. It is then shown that standard deviations of P/M (predicted to measured) ratios can be greatly improved by advanced statistics. (author). 7 figs., 2 tabs., 9 refs

  14. Electromagnetic mixed-waste processing system for asbestos decontamination

    International Nuclear Information System (INIS)

    1995-04-01

    The first phase of a program to develop and demonstrate a cost-effective, integrated process for remediation of asbestos-containing material that is contaminated with organics, heavy metals, and radioactive compounds was successfully completed. Laboratory scale tests were performed to demonstrate initial process viability for asbestos conversion, organics removal, and radionuclide and heavy metal removal. All success criteria for the laboratory tests were met. (1) Ohio DSI demonstrated greater than 99% asbestos conversion to amorphous solids using their commercial process. (2) KAI demonstrated 90% removal of organics from the asbestos suspension. (3) Westinghouse STC achieved the required metals removal criteria on a laboratory scale (e.g., 92% removal of uranium from solution, resin loadings of 0.6 equivalents per liter, and greater than 50% regeneration of resin in a batch test.) Using the information gained in the laboratory tests, the process was reconfigured to provide the basis for the mixed waste remediation system. An integrated process is conceptually developed, and a Phase 2 program plan is proposed to provide the bench-scale development needed in order to refine the design basis for a pilot processing system

  15. Adsorption thermal energy storage for cogeneration in industrial batch processes: Experiment, dynamic modeling and system analysis

    International Nuclear Information System (INIS)

    Schreiber, Heike; Graf, Stefan; Lanzerath, Franz; Bardow, André

    2015-01-01

    Adsorption thermal energy storage is investigated for heat supply with cogeneration in industrial batch processes. The feasibility of adsorption thermal energy storage is demonstrated with a lab-scale prototype. Based on these experiments, a dynamic model is developed and successfully calibrated to measurement data. Thereby, a reliable description of the dynamic behavior of the adsorption thermal energy storage unit is achieved. The model is used to study and benchmark the performance of adsorption thermal energy storage combined with cogeneration for batch process energy supply. As benchmark, we consider both a peak boiler and latent thermal energy storage based on a phase change material. Beer brewing is considered as an example of an industrial batch process. The study shows that adsorption thermal energy storage has the potential to increase energy efficiency significantly; primary energy consumption can be reduced by up to 25%. However, successful integration of adsorption thermal storage requires appropriate integration of low grade heat: Preferentially, low grade heat is available at times of discharging and in demand when charging the storage unit. Thus, adsorption thermal energy storage is most beneficial if applied to a batch process with heat demands on several temperature levels. - Highlights: • A highly efficient energy supply for industrial batch processes is presented. • Adsorption thermal energy storage (TES) is analyzed in experiment and simulation. • Adsorption TES can outperform both peak boilers and latent TES. • Performance of adsorption TES strongly depends on low grade heat temperature.

  16. Thermal processes of thermokarst lakes in the continuous permafrost zone of northern Siberia - observations and modeling (Lena River Delta, Siberia)

    Science.gov (United States)

    Boike, J.; Georgi, C.; Kirilin, G.; Muster, S.; Abramova, K.; Fedorova, I.; Chetverova, A.; Grigoriev, M.; Bornemann, N.; Langer, M.

    2015-10-01

    Thermokarst lakes are typical features of the northern permafrost ecosystems, and play an important role in the thermal exchange between atmosphere and subsurface. The objective of this study is to describe the main thermal processes of the lakes and to quantify the heat exchange with the underlying sediments. The thermal regimes of five lakes located within the continuous permafrost zone of northern Siberia (Lena River Delta) were investigated using hourly water temperature and water level records covering a 3-year period (2009-2012), together with bathymetric survey data. The lakes included thermokarst lakes located on Holocene river terraces that may be connected to Lena River water during spring flooding, and a thermokarst lake located on deposits of the Pleistocene Ice Complex. Lakes were covered by ice up to 2 m thick that persisted for more than 7 months of the year, from October until about mid-June. Lake-bottom temperatures increased at the start of the ice-covered period due to upward-directed heat flux from the underlying thawed sediment. Prior to ice break-up, solar radiation effectively warmed the water beneath the ice cover and induced convective mixing. Ice break-up started at the beginning of June and lasted until the middle or end of June. Mixing occurred within the entire water column from the start of ice break-up and continued during the ice-free periods, as confirmed by the Wedderburn numbers, a quantitative measure of the balance between wind mixing and stratification that is important for describing the biogeochemical cycles of lakes. The lake thermal regime was modeled numerically using the FLake model. The model demonstrated good agreement with observations with regard to the mean lake temperature, with a good reproduction of the summer stratification during the ice-free period, but poor agreement during the ice-covered period. Modeled sensitivity to lake depth demonstrated that lakes in this climatic zone with mean depths > 5 m develop

  17. The study of thermal processes in control systems of heat consumption of buildings

    Science.gov (United States)

    Tsynaeva, E.; A, Tsynaeva

    2017-11-01

    The article discusses the main thermal processes in the automated control systems for heat consumption (ACSHC) of buildings, schematic diagrams of these systems, mathematical models used for description of thermal processes in ACSHC. Conducted verification represented by mathematical models. It was found that the efficiency of the operation of ACSHC depend from the external and internal factors. Numerical study of dynamic modes of operation of ACSHC.

  18. Development of a process for co-conversion of Pu-U nitrate mixed solutions to mixed oxide powder using microwave heating method

    International Nuclear Information System (INIS)

    Koizumi, Masumichi; Ohtsuka, Katsuyuki; Ohshima, Hirofumi; Isagawa, Hiroto; Akiyama, Hideo; Todokoro, Akio; Naruki, Kaoru

    1983-01-01

    For the complete nuclear fuel cycle, the development of a process for the co-conversion of Pu-U nitrate mixed solutions to mixed oxide powder has been performed along the line of non-proliferation policy of nuclear materials. A new co-conversion process using a microwave heating method has been developed and successfully demonstrated with good results using the test unit with a capacity of 2 kg MOX/d. Through the experiments and engineering test operations, several important data have been obtained concerning the feasibility of the test unit, powder characteristics and homogeneity of the product, and impurity pickups during denitration process. The results of these experimental operations show that the co-conversion process using a microwave heating method has many excellent advantages, such as good powder characteristics of the product, good homogeneity of Pu-U oxide, simplicity of the process, minimum liquid waste, no possibility of changing the Pu/U ratio and stable operability of the plant. Since August 1979, plutonium nitrate solution transported from the Tokai Reprocessing Plant has been converted to mixed oxide powder which has the Pu/U ratio = 1. The products have been processed to the ATR ''FUGEN'' reloading fuel. Based on the successful development of the co-conversion process, the microwave heating direct denitration facility with a 10 kg MOX/d capacity has been constructed adjacent to the reprocessing plant. This facility will come into hot operation by the fall of this year. For future development of the microwave heating method, a continuous direct denitration, a vitrification of high active liquid waste and a solidification of the plutonium-contaminated waste are investigated in Power Reactor and Nuclear Fuel Development Corp. (author)

  19. Thermal conductivity of beginning-of-life uranium-plutonium mixed oxide fuel for fast reactor (Interim report)

    International Nuclear Information System (INIS)

    Inoue, Masaki; Mizuno, Tomoyasu; Asaga, Takeo

    1997-11-01

    Thermal conductivity of uranium-plutonium mixed oxide fuel for fast reactor at beginning-of-life was correlated based on the recent results in order to apply to the fuel design and the fuel performance analysis. A number of experimental results of unirradiated fuel specimens were corrected from open literatures and PNC internal reports and examined for the database. In this work two porosity correction factors were needed for high density fuel and low density fuel (around the current Monju specification). The universal porosity correction factor was not determined in this work. In the next step, theoretical and analytical considerations should be taken into account. (J.P.N.)

  20. Significant thermal energy reduction in lactic acid production process

    International Nuclear Information System (INIS)

    Mujtaba, Iqbal M.; Edreder, Elmahboub A.; Emtir, Mansour

    2012-01-01

    Lactic acid is widely used as a raw material for the production of biodegradable polymers and in food, chemical and pharmaceutical industries. The global market for lactic acid is expected to reach 259 thousand metric tons by the year 2012. For batch production of lactic acid, the traditional process includes the following steps: (i) esterification of impure lactic acid with methanol in a batch reactor to obtain methyl lactate (ester), (ii) separation of the ester in a batch distillation, (iii) hydrolysis of the ester with water in a batch reactor to produce lactic acid and (iv) separation of lactic acid (in high purity) in a batch distillation. Batch reactive distillation combines the benefit of both batch reactor and batch distillation and enhances conversion and productivity (Taylor and Krishna, 2000 ; Mujtaba and Macchietto, 1997 ). Therefore, the first and the last two steps of the lactic acid production process can be combined together in batch reactive distillation () processes. However, distillation (batch or continuous) is an energy intensive process and consumes large amount of thermal energy (via steam). This paper highlights how significant (over 50%) reduction in thermal energy consumption can be achieved for lactic acid production process by carefully controlling the reflux ratio but without compromising the product specification. In this paper, only the simultaneous hydrolysis of methyl lactate ester and the separation of lactic acid using batch reactive distillation is considered.

  1. Method of manufacturing a thermally insulating body

    Energy Technology Data Exchange (ETDEWEB)

    McWilliams, J.A.; Morgan, D.E.; Jackson, J.D.

    1988-10-11

    A method of manufacturing a microporous thermally insulating body comprises mixing together a finely divided microporous insulating material such as silica aerogel or pyrogenic silica and a solid ammonia-generating compound in particulate form, and compressing the mixture to form a thermally insulating body. The ammonia-generating compound is dispersed evenly throughout the insulating material and may comprise, for example, ammonium carbonate, ammonium acetate or urea. Preferably, the ammonia-generating compound comprises a mixture of about one third by weight of ammonium carbonate and about two thirds by weight of ammonium bicarbonate together with a small proportion of magnesium oxide. Experiments are described which illustrate the manufacturing process. 6 tabs.

  2. Thermal Stabilization FY 1999 blend plan

    Energy Technology Data Exchange (ETDEWEB)

    RISENMAY, H.R.

    1999-02-23

    This Blend Plan documents the alternate feed material items for the thermal stabilization process that will be used in place of the metal items that were originally planned to be processed. Problems with resolution of the safety basis for the metal items resulted in the decision to run material that already had an established safety basis. Various in process and scrap recovery items stored in gloveboxes, plutonium oxide and plutonium oxide mixed with uranium oxide stored in 2736-Z vaults will be processed through the stabilization furnaces until the safety basis for the metal items has been resolved. The purpose of thermal stabilization is to heat the material to 1000 degrees Celsius to drive off all volatile materials and leave the plutonium and/or uranium as oxides. The stabilized material will be sampled to determine the Loss On Ignition (LOI). The stabilized material must meet LOI of less than 0.5% to be acceptable for storage under DOE-STD-3013-94 specifications. Out of specification material will be recycled through the furnaces until the LOI limits are met.

  3. Thermal Stabilization FY 1999 blend plan

    International Nuclear Information System (INIS)

    RISENMAY, H.R.

    1999-01-01

    This Blend Plan documents the alternate feed material items for the thermal stabilization process that will be used in place of the metal items that were originally planned to be processed. Problems with resolution of the safety basis for the metal items resulted in the decision to run material that already had an established safety basis. Various in process and scrap recovery items stored in gloveboxes, plutonium oxide and plutonium oxide mixed with uranium oxide stored in 2736-Z vaults will be processed through the stabilization furnaces until the safety basis for the metal items has been resolved. The purpose of thermal stabilization is to heat the material to 1000 degrees Celsius to drive off all volatile materials and leave the plutonium and/or uranium as oxides. The stabilized material will be sampled to determine the Loss On Ignition (LOI). The stabilized material must meet LOI of less than 0.5% to be acceptable for storage under DOE-STD-3013-94 specifications. Out of specification material will be recycled through the furnaces until the LOI limits are met

  4. Thermal stabilization FY 1999 blend plan

    International Nuclear Information System (INIS)

    RISENMAY, H.R.

    1999-01-01

    This Blend Plan documents the alternate feed material items for the thermal stabilization process that will be used in place of the metal items that were originally planned to be processed. Problems with resolution of the safety basis for the metal items resulted in the decision to run material that already had an established safety basis. Various in process and scrap recovery items stored in gloveboxes, plutonium oxide and plutonium oxide mixed with uranium oxide stored in 2736-2 vaults will be processed through the stabilization furnaces until the safety basis for the metal items has been resolved. The purpose of thermal stabilization is to heat the material to 1000 degrees Celsius to drive off all volatile materials and leave the plutonium and/or uranium as oxides. The stabilized material will be sampled to determine the Loss On Ignition (LOI). The stabilized material must meet LOI of less than 0.5% to be acceptable for storage under DOE-STD-3013-94 specifications. Out of specification material will be recycled through the furnaces until the LOI limits are met

  5. Thermal stabilization FY 1999 blend plan

    Energy Technology Data Exchange (ETDEWEB)

    RISENMAY, H.R.

    1999-06-01

    This Blend Plan documents the alternate feed material items for the thermal stabilization process that will be used in place of the metal items that were originally planned to be processed. Problems with resolution of the safety basis for the metal items resulted in the decision to run material that already had an established safety basis. Various in process and scrap recovery items stored in gloveboxes, plutonium oxide and plutonium oxide mixed with uranium oxide stored in 2736-2 vaults will be processed through the stabilization furnaces until the safety basis for the metal items has been resolved. The purpose of thermal stabilization is to heat the material to 1000 degrees Celsius to drive off all volatile materials and leave the plutonium and/or uranium as oxides. The stabilized material will be sampled to determine the Loss On Ignition (LOI). The stabilized material must meet LOI of less than 0.5% to be acceptable for storage under DOE-STD-3013-94 specifications. Out of specification material will be recycled through the furnaces until the LOI limits are met.

  6. Numerical analysis of mixing process of two component gases in vertical fluid layer

    International Nuclear Information System (INIS)

    Hatori, Hirofumi; Takeda, Tetsuaki; Funatani, Shumpei

    2015-01-01

    When the depressurization accident occurs in the Very-High-Temperature Reactor (VHTR), it is expected that air enter into the reactor core. Therefore, it is important to know a mixing process of different kind of gases in the stable or unstable stratified fluid layer. Especially, it is also important to examine an influence of localized natural convection and molecular diffusion on mixing process from a viewpoint of safety. In order to research the mixing process of two component gases and flow characteristics of the localized natural convection, we have carried out numerical analysis using three dimensional CFD code. The numerical model was consisted of a storage tank and a reverse U-shaped vertical slot. They were separated by a partition plate. One side of the left vertical fluid layer was heated and the other side was cooled. The right vertical fluid layer was also cooled. The procedure of numerical analysis is as follows. Firstly, the storage tank was filled with heavy gas and the reverse U-shaped vertical slot was filled with light gas. In the left vertical fluid layer, the localized natural convection was generated by the temperature difference between the vertical walls. The flow characteristics were obtained by a steady state analysis. The unsteady state analysis was started when the partition plate was opened. The gases were mixed by molecular diffusion and natural convection. After the time elapsed, natural circulation occurred. The result obtained in this numerical analysis is as follows. The temperature difference of the left vertical fluid layer was set to 100 K. The combination of the mixed gas was nitrogen and argon. After 76 minutes elapsed, natural circulation occurred. (author)

  7. Thermal analysis on x-ray tube for exhaust process

    Science.gov (United States)

    Kumar, Rakesh; Rao Ratnala, Srinivas; Veeresh Kumar, G. B.; Shivakumar Gouda, P. S.

    2018-02-01

    It is great importance in the use of X-rays for medical purposes that the dose given to both the patient and the operator is carefully controlled. There are many types of the X- ray tubes used for different applications based on their capacity and power supplied. In present thesis maxi ray 165 tube is analysed for thermal exhaust processes with ±5% accuracy. Exhaust process is usually done to remove all the air particles and to degasify the insert under high vacuum at 2e-05Torr. The tube glass is made up of Pyrex material, 95%Tungsten and 5%rhenium is used as target material for which the melting point temperature is 3350°C. Various materials are used for various parts; during the operation of X- ray tube these waste gases are released due to high temperature which in turn disturbs the flow of electrons. Thus, before using the X-ray tube for practical applications it has to undergo exhaust processes. Initially we build MX 165 model to carry out thermal analysis, and then we simulate the bearing temperature profiles with FE model to match with test results with ±5%accuracy. At last implement the critical protocols required for manufacturing processes like MF Heating, E-beam, Seasoning and FT.

  8. US Department of Energy mixed waste characterization, treatment, and disposal focus area technical baseline development process

    International Nuclear Information System (INIS)

    Roach, J.A.; Gombert, D.

    1996-01-01

    The US Department of Energy (DOE) created the Mixed Waste Characterization, Treatment, and Disposal Focus Area (MWFA) to develop and facilitate implementation of technologies required to meet its commitments for treatment of mixed wastes under the Federal Facility Compliance Act (FFCA), and in accordance with the Land Disposal Restrictions (LDR) of the Resource Conservation and Recovery Act (RCRA). Mixed wastes include both mixed low-level waste (MLLW) and mixed transuranic (MTRU) waste. The goal of the MWFA is to develop mixed waste treatment systems to the point of implementation by the Environmental Management (EM) customer. To accomplish this goal, the MWFA is utilizing a three step process. First, the treatment system technology deficiencies were identified and categorized. Second, these identified needs were prioritized. This resulted in a list of technical deficiencies that will be used to develop a technical baseline. The third step, the Technical Baseline Development Process, is currently ongoing. When finalized, the technical baseline will integrate the requirements associated with the identified needs into the planned and ongoing environmental research and technology development activities supported by the MWFA. Completion of this three-step process will result in a comprehensive technology development program that addresses customer identified and prioritized needs. The MWFA technical baseline will be a cost-effective, technically-defensible tool for addressing and resolving DOE's mixed waste problems

  9. Reactive control processes contributing to residual switch cost and mixing cost across the adult lifespan.

    Science.gov (United States)

    Whitson, Lisa R; Karayanidis, Frini; Fulham, Ross; Provost, Alexander; Michie, Patricia T; Heathcote, Andrew; Hsieh, Shulan

    2014-01-01

    In task-switching paradigms, performance is better when repeating the same task than when alternating between tasks (switch cost) and when repeating a task alone rather than intermixed with another task (mixing cost). These costs remain even after extensive practice and when task cues enable advanced preparation (residual costs). Moreover, residual reaction time mixing cost has been consistently shown to increase with age. Residual switch and mixing costs modulate the amplitude of the stimulus-locked P3b. This mixing effect is disproportionately larger in older adults who also prepare more for and respond more cautiously on these "mixed" repeat trials (Karayanidis et al., 2011). In this paper, we analyze stimulus-locked and response-locked P3 and lateralized readiness potentials to identify whether residual switch and mixing cost arise from the need to control interference at the level of stimulus processing or response processing. Residual mixing cost was associated with control of stimulus-level interference, whereas residual switch cost was also associated with a delay in response selection. In older adults, the disproportionate increase in mixing cost was associated with greater interference at the level of decision-response mapping and response programming for repeat trials in mixed-task blocks. These findings suggest that older adults strategically recruit greater proactive and reactive control to overcome increased susceptibility to post-stimulus interference. This interpretation is consistent with recruitment of compensatory strategies to compensate for reduced repetition benefit rather than an overall decline on cognitive flexibility.

  10. Processing and fermentation of Jerusalem artichoke for ethanol production

    Energy Technology Data Exchange (ETDEWEB)

    Williams, L.A.; Ziobro, G.

    1982-01-01

    Processing and fermentation trials on Jerusalem artichoke (Helianthus tuberosus) tubers, and on pure inulin media were carried out. Acid and thermal treatments, pure and mixed cultures of yeast, and enzyme preparations were investigated. Best EtOH yields on either substrate were obtained with pH 2 thermal treatments, resulting in 131.6lEtOH/ton fresh tuber.

  11. Partitioning planning studies: Preliminary evaluation of metal and radionuclide partitioning the high-temperature thermal treatment systems

    International Nuclear Information System (INIS)

    Liekhus, K.; Grandy, J.; Chambers, A.

    1997-03-01

    A preliminary study of toxic metals and radionuclide partitioning during high-temperature processing of mixed waste has been conducted during Fiscal Year 1996 within the Environmental Management Technology Evaluation Project. The study included: (a) identification of relevant partitioning mechanisms that cause feed material to be distributed between the solid, molten, and gas phases within a thermal treatment system; (b) evaluations of existing test data from applicable demonstration test programs as a means to identify and understand elemental and species partitioning; and, (c) evaluation of theoretical or empirical partitioning models for use in predicting elemental or species partitioning in a thermal treatment system. This preliminary study was conducted to identify the need for and the viability of developing the tools capable of describing and predicting toxic metals and radionuclide partitioning in the most applicable mixed waste thermal treatment processes. This document presents the results and recommendations resulting from this study that may serve as an impetus for developing and implementing these predictive tools

  12. Partitioning planning studies: Preliminary evaluation of metal and radionuclide partitioning the high-temperature thermal treatment systems

    Energy Technology Data Exchange (ETDEWEB)

    Liekhus, K.; Grandy, J.; Chambers, A. [and others

    1997-03-01

    A preliminary study of toxic metals and radionuclide partitioning during high-temperature processing of mixed waste has been conducted during Fiscal Year 1996 within the Environmental Management Technology Evaluation Project. The study included: (a) identification of relevant partitioning mechanisms that cause feed material to be distributed between the solid, molten, and gas phases within a thermal treatment system; (b) evaluations of existing test data from applicable demonstration test programs as a means to identify and understand elemental and species partitioning; and, (c) evaluation of theoretical or empirical partitioning models for use in predicting elemental or species partitioning in a thermal treatment system. This preliminary study was conducted to identify the need for and the viability of developing the tools capable of describing and predicting toxic metals and radionuclide partitioning in the most applicable mixed waste thermal treatment processes. This document presents the results and recommendations resulting from this study that may serve as an impetus for developing and implementing these predictive tools.

  13. Frontogenesis and turbulent mixing

    Science.gov (United States)

    Zhang, S.; Chen, F.; Shang, Q.

    2017-12-01

    A hydrological investigation was conducted in the shelf of eastern Hainan island during July 2012. With the in-situ measurements from four cross-shelf sections and satellite data, the submesoscale process of the fronts are discussed in this paper, the seasonal variation characteristics of thermal front, the three-dimensional structure, dynamic characteristics of frontal and mixed characteristics in the shelf sea of eastern Hainan island. It's obviously that the thermal front has a seasonal variation: the front is strongest in winter, and decreased gradually in spring and summer. However, it fade and disappear in fall. The core region of the front also changes with the seasons, it moved southward gradually from mainly distributed in the upwelling zone and the front center is not obvious in summer. it is a typical upwelling front in summer, the near shore is compensated with the underlying low-temperature and high-sale water , while the offshore is the high-temperature and low-salinity shelf water. The thermal front distribution is located in the 100m isobaths. The frontal intensity is reduced with increasing depth, and position goes to offshore. Subsurface temperature front is significantly higher in the surface of the sea, which may cause by the heating of nearshore sea surface water and lead to the weakening horizontal temperature gradient. Dynamic characteristics of the front has a great difference in both sides. The O(1) Rossby number is positive on the dense side and negative on the light side. The maximum of along-frontal velocity is 0.45m/s and the stretching is strengthened by strong horizontal shear, also is the potential vorticity, which can trace the cross front Ekman transport. We obtained the vertical velocity with by quasi-geostrophic omega equation and grasped the ageostrophic secondary circulation. The magnitude of frontal vertical velocity is O(10-5) and causes downwelling on the dense side and upwelling on the light side, which constitute the

  14. Thermal annealing of recoil 56Mn in strontium permanganate under (n,γ) process

    International Nuclear Information System (INIS)

    Mishra, Shuddhodan P.; Vijaya

    2002-01-01

    Chemical stabilization of recoil 56 Mn in strontium permanganate (hydrous and anhydrous) has been investigated with a special reference to pre-and post-activation thermal annealing treatments. The retention of 56 Mn in neutron irradiated strontium permanganate showed significant variation on thermal annealing in both pre-and post-activation heated target. The recoil re-entry process obeys simple first order kinetics and the activation energy deduced for thermal annealing process is very low as computed by classical Arrhenius plots. The results observed are discussed in the light of existing ideas for understanding the recoil stabilization mechanism of parent reformation and the nature of precursors in permanganates. (author)

  15. Inactivation of Byssochlamys nivea ascospores in strawberry puree by high pressure, power ultrasound and thermal processing.

    Science.gov (United States)

    Evelyn; Silva, F V M

    2015-12-02

    Byssochlamys nivea is a mold that can spoil processed fruit products and produce mycotoxins. In this work, high pressure processing (HPP, 600 MPa) and power ultrasound (24 kHz, 0.33 W/mL; TS) in combination with 75°C for the inactivation of four week old B. nivea ascospores in strawberry puree for up to 30 min was investigated and compared with 75°C thermal processing alone. TS and thermal processing can activate the mold ascospores, but HPP-75°C resulted in 2.0 log reductions after a 20 min process. For a 10 min process, HPP-75°C was better than 85°C alone in reducing B. nivea spores (1.4 vs. 0.2 log reduction), demonstrating that a lower temperature in combination with HPP is more effective for spore inactivation than heat alone at a higher temperature. The ascospore inactivation by HPP-thermal, TS and thermal processing was studied at different temperatures and modeled. Faster inactivation was achieved at higher temperatures for all the technologies tested, indicating the significant role of temperature in spore inactivation, alone or combined with other physical processes. The Weibull model described the spore inactivation by 600 MPa HPP-thermal (38, 50, 60, 75°C) and thermal (85, 90°C) processing, whereas the Lorentzian model was more appropriate for TS treatment (65, 70, 75°C). The models obtained provide a useful tool to design and predict pasteurization processes targeting B. nivea ascospores. Copyright © 2015 Elsevier B.V. All rights reserved.

  16. Hillslope Discharge Analysis - Threshold Behavior and Mixing Processes

    Science.gov (United States)

    Dusek, J.; Vogel, T. N.

    2017-12-01

    Reliable quantitative prediction of temporal changes of both the soil water storage and the shallow subsurface runoff for natural forest hillslopes exhibiting high degree of subsurface heterogeneity remains a challenge. The intensity of stormflow determines to a large extent the residence time of water in a hillslope segment, thus also influencing biogeochemical processes and mass fluxes of nutrients. Stormflow, as one of the most important runoff mechanisms in headwater catchments, usually develops above the soil-bedrock interface during prominent rainfall-runoff events as saturated flow. In this study, one- and two-dimensional numerical models were used to analyze hydrological processes at an experimental forest site located in a small headwater catchment under humid temperate climate. The models are based on dual-continuum approach reflecting water flow and isotope transport through the soil matrix and preferential pathways. The threshold relationship between rainfall and stormflow as well as hysteresis in the hillslope stormflow-storage relationship were examined. The hillslope storage analysis was performed for selected individual rainfall-runoff events over the period of several consecutive growing seasons. Furthermore, temporal and spatial variations of pre-event and event water contributions to hillslope stormflow were evaluated using a two-component mass balance approach based on the synthetic oxygen-18 signatures. The results of this analysis showed a mutual interplay of components of hillslope water balance exposing a nonlinear character of the hillslope hydrological response. The results also suggested significant mixing processes in a hillslope segment, in particular mixing of pre-event and event water as well as water exchanged between the soil matrix and preferential pathways. Despite the dominant control of preferential stormflow on overall hillslope runoff response, a rapid and substantial contribution of pre-event water to hillslope runoff was

  17. Multifunctional PLA-PHB/cellulose nanocrystal films: processing, structural and thermal properties.

    Science.gov (United States)

    Arrieta, M P; Fortunati, E; Dominici, F; Rayón, E; López, J; Kenny, J M

    2014-07-17

    Cellulose nanocrystals (CNCs) synthesized from microcrystalline cellulose by acid hydrolysis were added into poly(lactic acid)-poly(hydroxybutyrate) (PLA-PHB) blends to improve the final properties of the multifunctional systems. CNC were also modified with a surfactant (CNCs) to increase the interfacial adhesion in the systems maintaining the thermal stability. Firstly, masterbatch pellets were obtained for each formulation to improve the dispersion of the cellulose structures in the PLA-PHB and then nanocomposite films were processed. The thermal stability as well as the morphological and structural properties of nanocomposites was investigated. While PHB increased the PLA crystallinity due to its nucleation effect, well dispersed CNC and CNCs not only increased the crystallinity but also improved the processability, the thermal stability and the interaction between both polymers especially in the case of the modified CNCs based PLA-PHB formulation. Likewise, CNCs were better dispersed in PLA-CNCs and PLA-PHB-CNCs, than CNC. Copyright © 2014 Elsevier Ltd. All rights reserved.

  18. RESOURCE SAVING TECHNOLOGICAL PROCESS OF LARGE-SIZE DIE THERMAL TREATMENT

    Directory of Open Access Journals (Sweden)

    L. A. Glazkov

    2009-01-01

    Full Text Available The given paper presents a development of a technological process pertaining to hardening large-size parts made of die steel. The proposed process applies a water-air mixture instead of a conventional hardening medium that is industrial oil.While developing this new technological process it has been necessary to solve the following problems: reduction of thermal treatment duration, reduction of power resource expense (natural gas and mineral oil, elimination of fire danger and increase of process ecological efficiency. 

  19. Experimental Study of Elements Promoting Mixing in Fuel Elements

    International Nuclear Information System (INIS)

    Silin, Nicolas; Juanico, Luis; Delmastro, Dario

    2003-01-01

    In the present work a thermal tracing technique is used to measure the increase of the mixing between subchannels in the presence of different mixing elements.As representative elements a spacer, a spacer with mixing vanes and turbulence promoter buttons were considered.The performance of these elements was evaluated by studying the behavior of a thermal trace in each case.Also the pressure drop for each case is presented.The results present a qualitative and quantitative guide for the application of each one of these appendages in future nuclear elements

  20. Soft sensor development for Mooney viscosity prediction in rubber mixing process based on GMMDJITGPR algorithm

    Science.gov (United States)

    Yang, Kai; Chen, Xiangguang; Wang, Li; Jin, Huaiping

    2017-01-01

    In rubber mixing process, the key parameter (Mooney viscosity), which is used to evaluate the property of the product, can only be obtained with 4-6h delay offline. It is quite helpful for the industry, if the parameter can be estimate on line. Various data driven soft sensors have been used to prediction in the rubber mixing. However, it always not functions well due to the phase and nonlinear property in the process. The purpose of this paper is to develop an efficient soft sensing algorithm to solve the problem. Based on the proposed GMMD local sample selecting criterion, the phase information is extracted in the local modeling. Using the Gaussian local modeling method within Just-in-time (JIT) learning framework, nonlinearity of the process is well handled. Efficiency of the new method is verified by comparing the performance with various mainstream soft sensors, using the samples from real industrial rubber mixing process.

  1. Mixing process in the preparation of feed pellets at technological conditions rational parametres choice

    Directory of Open Access Journals (Sweden)

    E. S. Shentsova

    2016-01-01

    Full Text Available The mixing of ingredients – the most important process step in the manufacture of fodder pellets. The technology involves using molasses (warmed to 30–40 °C as a binder. In its composition is administered a mixture of salts of trace elements (copper sulfate, zinc sulfate, cobalt carbonate, potassium iodide, ferrous sulfate, manganese sulfate, sodium selenite, vitamins, salt, magnesium oxide, feed limestone, mono calcium phosphate and lime. Research on the development of feed pellets were carried out in laboratory conditions using experimental equipment. Mixer-reactor created the conditions for heating and temperature control of mass be mixed due to the occurring chemical reaction between water contained in the molasses, and the presence of oxides of calcium and magnesium. The choice of rational parameters of the mixing process upon receipt of fodder pellets allows to provide the high quality product with minimal energy costs. The ranges of the input information factors selected with the aid of a central rotatable uniforms-planning allowed with 56 experiments in a third-multiple replication to obtain the regression equation adequately describing the mixing process. The main factors were: the content of molasses, %; the content of calcium oxide, %; frequency of rotation of the stirrer, rpm; the content of salt in the recipe, %; the temperature of blending, °C. Output factors – productivity, kg/h; energy consumption, kWh; homogeneity of mixing, %. In the result of experiments impact factors and mathematical model of the process that allows to define output parameters within chosen ranges of variation of input factors are obtained. Greatest influence – the content of molasses in the product, the lowest – content of salt in the recipe. Efficiency of mixing hard distributed components pertaining to the most important biologically active substances was evaluated. Content (% of entered of vitamins and minerals in the pellets did not differ

  2. Tailoring Mixed-Halide, Wide-Gap Perovskites via Multistep Conversion Process

    NARCIS (Netherlands)

    Bae, D.; Palmstrom, A.; Roelofs, K.; Mei, Bastian Timo; Chorkendorf, I.; Bent, S.F.; Vesborg, P.C.

    2016-01-01

    Wide-band-gap mixed-halide CH3NH3PbI3–XBrX-based solar cells have been prepared by means of a sequential spin-coating process. The spin-rate for PbI2 as well as its repetitive deposition are important in determining the cross-sectional shape and surface morphology of perovskite, and, consequently,

  3. Kinetic parameters for the thermal decomposition reactions of mixed oxides of selenium and tellurium

    International Nuclear Information System (INIS)

    Jerez, A.; Castro, A.; Pico, C.; Veiga, M.L.

    1982-01-01

    A comparative study of the thermal decomposition processes of Te 3 SeO 8 and TeSeO 4 has been carried out based on the results obtained directly by a Mettler TA 3000 apparatus and from calculations using other differential and integral methods. (orig.)

  4. High pressure pure- and mixed-gas separation of CO2/CH4 by thermally-rearranged and carbon molecular sieve membranes derived from a polyimide of intrinsic microporosity

    KAUST Repository

    Swaidan, Raja

    2013-11-01

    Natural gas sweetening, one of the most promising venues for the growth of the membrane gas separation industry, is dominated by polymeric materials with relatively low permeabilities and moderate selectivities. One strategy towards improving the gas transport properties of a polymer is enhancement of microporosity either by design of polymers of intrinsic microporosity (PIMs) or by thermal treatment of polymeric precursors. For the first time, the mixed-gas CO2/CH4 transport properties are investigated for a complete series of thermally-rearranged (TR) (440°C) and carbon molecular sieve (CMS) membranes (600, 630 and 800°C) derived from a polyimide of intrinsic microporosity (PIM-6FDA-OH). The pressure dependence of permeability and selectivity is reported up to 30bar for 1:1, CO2:CH4 mixed-gas feeds at 35°C. The TR membrane exhibited ~15% higher CO2/CH4 selectivity relative to pure-gas feeds due to reductions in mixed-gas CH4 permeability reaching 27% at 30bar. This is attributed to increased hindrance of CH4 transport by co-permeation of CO2. Interestingly, unusual increases in mixed-gas CH4 permeabilities relative to pure-gas values were observed for the CMS membranes, resulting in up to 50% losses in mixed-gas selectivity over the applied pressure range. © 2013 Elsevier B.V.

  5. In Situ Acoustic Monitoring of Thermal Spray Process Using High-Frequency Impulse Measurements

    Science.gov (United States)

    Tillmann, Wolfgang; Walther, Frank; Luo, Weifeng; Haack, Matthias; Nellesen, Jens; Knyazeva, Marina

    2018-01-01

    In order to guarantee their protective function, thermal spray coatings must be free from cracks, which expose the substrate surface to, e.g., corrosive media. Cracks in thermal spray coatings are usually formed because of tensile residual stresses. Most commonly, the crack occurrence is determined after the thermal spraying process by examination of metallographic cross sections of the coating. Recent efforts focus on in situ monitoring of crack formation by means of acoustic emission analysis. However, the acoustic signals related to crack propagation can be absorbed by the noise of the thermal spraying process. In this work, a high-frequency impulse measurement technique was applied to separate different acoustic sources by visualizing the characteristic signal of crack formation via quasi-real-time Fourier analysis. The investigations were carried out on a twin wire arc spraying process, utilizing FeCrBSi as a coating material. The impact of the process parameters on the acoustic emission spectrum was studied. Acoustic emission analysis enables to obtain global and integral information on the formed cracks. The coating morphology and coating defects were inspected using light microscopy on metallographic cross sections. Additionally, the resulting crack patterns were imaged in 3D by means of x-ray microtomography.

  6. Effect of thermal processing practices on the properties of superplastic Al-Li alloys

    Science.gov (United States)

    Hales, Stephen J.; Lippard, Henry E.

    1993-01-01

    The effect of thermal processing on the mechanical properties of superplastically formed structural components fabricated from three aluminum-lithium alloys was evaluated. The starting materials consisted of 8090, 2090, and X2095 (Weldalite(TM) 049), in the form of commercial-grade superplastic sheet. The experimental test matrix was designed to assess the impact on mechanical properties of eliminating solution heat treatment and/or cold water quenching from post-forming thermal processing. The extensive hardness and tensile property data compiled are presented as a function of aging temperature, superplastic strain and temper/quench rate for each alloy. The tensile properties of the materials following superplastic forming in two T5-type tempers are compared with the baseline T6 temper. The implications for simplifying thermal processing without degradation in properties are discussed on the basis of the results.

  7. Pitched blade impeller - an option for mixing in continuous actinide reconversion process

    International Nuclear Information System (INIS)

    Tripathi, V.M.; Suresh Kumar, K.; Sreekumar, G.; Sugilal, G.

    2016-01-01

    In nuclear fuel cycle, current methodology for Pu reconversion involves Pu(IV)-oxalate precipitation as a semi continuous/batch process mode for a predetermined volume of Pu(NO 3 ) 4 solution in a long single column with a marine propeller type stirrer. In this process the slurry is being drained from bottom of the vessel leading to a possibility of accumulation of precipitate in the vessel which is an unfavorable condition for continuous process. As continuous reconversion process is a requirement to meet high through put of reprocessing plants, the conventional process has to be improvised with reference to its slurry exit point through overflow line. Although marine propeller type stirrer ensures an axial flow, it is not a choice for uniform solid suspension in a reactor vessel. A better alternate for complete suspension of solid in tall reactor is pitched blade turbine. Moreover pitched blade impellers are effective in low bottom clearance which ensures a thorough mixing of reactants. Present study focuses on feasibility of pitched blade impeller for mixing of reactants in a continuous actinide oxalate precipitation reactor with over flow line

  8. The Effect of Thermal Lamination Processes on Colorimetric Change in Spot Colours

    Directory of Open Access Journals (Sweden)

    Eduard Galić

    2015-03-01

    Full Text Available Understanding the effect of laminating processes on spot colours is of great importance in the offset printing process, especially given the application versatility of spot colours. Laminating process, as a very common process and one of the first in a sequence of finishing processes in graphics production, can affect print’s visual impression to varying degrees. Spot colours, as mixtures of different ratios of inks, are subject to a change due to matt or gloss lamination process. The research examined the impact of thermal lamination processes on printed spot colours on different printing substrates. The degree of change on prints caused by laminating films in the thermal process was determined using spectrophotometric and densitometric methods. Particular emphasis is placed on the spot colour because of its specific characteristics. Research results are shown in charts and they are showing clearly the modality and the extent laminating processes effect the colorimetric difference in laminated and non-laminated prints. This scientific research provides objective conclusions that help in predicting the possible variations within the usage of laminating processes.

  9. Multi-criteria evaluation and priority analysis for localization equipment in a thermal power plant using the AHP (analytic hierarchy process)

    International Nuclear Information System (INIS)

    Yagmur, Levent

    2016-01-01

    Ensuring the safety of its energy supply is one of the main issues for newly industrialized/developing countries when utilizing domestic sources for electricity generation. Turkey depends heavily on imported gas to generate electricity, and the ratio of natural gas power generation to total electricity production is nearly 50%. Coal-fired thermal power plants using domestic resources are considered a good option to decrease the large amount of imported natural gas, and to supply a secure energy demand. However, electricity generation from coal-fired power plants using local lignite reserves is not adequate to maintain a secure energy mix and provide sustainable development, as Turkey does not have indigenous energy sector technology. Therefore, technology transfer and its localization are crucial for newly industrialized/developing countries such as Turkey. The aim of this study is to use the analytic hierarchy process to determine a priority analysis in relation to localization equipment for a thermal power plant. Parameters involved, such as readiness of both infrastructure and human resources, manpower as skilled labor, market potential for equipment developed by transferred technology, and competition in global/internal market, are related to localization in thermal power plant technologies, and are considered in relation to the country's technological capability, design ability, possession of materials/equipment, and ability to erect a plant. Results of analysis show that the boiler is the most important piece of equipment in this respect, and that heaters and fans are ranked after the boiler with respect to local conditions. - Highlights: • Localization of foreign technology was determined for developing countries. • An evaluation and priority analysis were performed for parts of a thermal power plant. • Analytic hierarchy process was applied for the hierarchical ordering of parts when transferring technology.

  10. Thermal annealing behaviour of sulphur-35 produced in pile-irradiated mixed crystals AlCl/sub 3/-FeCl/sub 3/

    Energy Technology Data Exchange (ETDEWEB)

    Dyakovich, V; Todorovski, D S; Kostadinova, Z D [Sofia Univ. (Bulgaria). Khimicheski Fakultet

    1983-12-19

    The regression analysis of the experimental results on the thermal annealing behaviour of /sup 35/S produced in pile-irradiated mixed crystals AlCl/sub 3/-FeCl/sub 3/ confirms some suppositions made in a previous paper. The chemical state of /sup 35/S is defined by the target prehistory and the iron concentration. The influence of Fe/sup 3 +/ can be observed indirectly through its influence on the defect structure formed.

  11. Exergy analysis on the irreversibility of rotary air preheater in thermal power plant

    International Nuclear Information System (INIS)

    Wang Hongyue; Zhao Lingling; Zhou Qiangtai; Xu Zhigao; Kim, Hyung Taek

    2008-01-01

    Energy recovery devices can have a substantial impact on process efficiency and their relevance to the problem of conservation of energy resources is generally recognized to be beyond dispute. One type of such a device, which is commonly used in thermal power plants and air conditioning systems, is the rotary air preheater. A major disadvantage of the rotary air preheater is that there is an unavoidable leakage due to carry over and pressure difference. There are gas streams involved in the heat transfer and mixing processes. There are also irreversibilities, or exergy destruction, due to mixing, pressure losses and temperature gradients. Therefore, the purpose of this research paper is based from the second law of thermodynamics, which is to build up the relationship between the efficiency of the thermal power plant and the total process of irreversibility in the rotary air preheater using exergy analysis. For this, the effects of the variation of the principal design parameters on the rotary air preheater efficiency, the exergy efficiency, and the efficiency of the thermal power plant are examined by changing a number of parameters of rotary air preheater. Furthermore, some conclusions are reached and recommendations are made so as to give insight on designing some optimal parameters

  12. Bread making properties of wheat flour supplemented with thermally processed hypoallergenic lupine flour

    Energy Technology Data Exchange (ETDEWEB)

    Guillamon, E.; Cuadrado, C.; Pedrosa, M. M.; Varela, A.; Cabellos, B.

    2010-07-01

    In recent years there has been increased interest in using lupine for human nutrition due to its nutritional properties and health benefits. Moreover, lupine is used as an ingredient in bread making because of its functional and technological properties. However, a higher number of allergic reactions to this legume have recently been reported as a consequence of a more widespread consumption of lupine-based foods. In a previous study, several thermal treatments were applied to lupine seeds and flours resulting in reduced allergenicity. In order to study how this thermal processing (autoclaving and boiling) affects the bread making properties, raw and thermally processed lupine flours were used to replace 10% of wheat flour. The effect of supplementing wheat flour with lupine flour on physical dough properties, bread structure and sensory characteristics were analysed. The results indicated that thermally-treated lupine flours, had similar bread making and sensorial properties as untreated lupine flour. These thermal treatments could increase the potential use of lupine flour as a food ingredient while reducing the risk to provoke allergic reactions. (Author) 36 refs.

  13. Advanced Signal Processing for Thermal Flaw Detection; TOPICAL

    International Nuclear Information System (INIS)

    VALLEY, MICHAEL T.; HANSCHE, BRUCE D.; PAEZ, THOMAS L.; URBINA, ANGEL; ASHBAUGH, DENNIS M.

    2001-01-01

    Dynamic thermography is a promising technology for inspecting metallic and composite structures used in high-consequence industries. However, the reliability and inspection sensitivity of this technology has historically been limited by the need for extensive operator experience and the use of human judgment and visual acuity to detect flaws in the large volume of infrared image data collected. To overcome these limitations new automated data analysis algorithms and software is needed. The primary objectives of this research effort were to develop a data processing methodology that is tied to the underlying physics, which reduces or removes the data interpretation requirements, and which eliminates the need to look at significant numbers of data frames to determine if a flaw is present. Considering the strengths and weakness of previous research efforts, this research elected to couple both the temporal and spatial attributes of the surface temperature. Of the possible algorithms investigated, the best performing was a radiance weighted root mean square Laplacian metric that included a multiplicative surface effect correction factor and a novel spatio-temporal parametric model for data smoothing. This metric demonstrated the potential for detecting flaws smaller than 0.075 inch in inspection areas on the order of one square foot. Included in this report is the development of a thermal imaging model, a weighted least squares thermal data smoothing algorithm, simulation and experimental flaw detection results, and an overview of the ATAC (Automated Thermal Analysis Code) software that was developed to analyze thermal inspection data

  14. Thermal performance of nanofluid flow in microchannels

    Energy Technology Data Exchange (ETDEWEB)

    Li Jie [Department of Mechanical and Aerospace Engineering, University of North Carolina, Campus Box 7910, Broungton Hall 4160, Raleigh, NC 27695-7910 (United States); Kleinstreuer, Clement [Department of Mechanical and Aerospace Engineering, University of North Carolina, Campus Box 7910, Broungton Hall 4160, Raleigh, NC 27695-7910 (United States)], E-mail: ck@eos.ncsu.edu

    2008-08-15

    Two effective thermal conductivity models for nanofluids were compared in detail, where the new KKL (Koo-Kleinstreuer-Li) model, based on Brownian motion induced micro-mixing, achieved good agreements with the currently available experimental data sets. Employing the commercial Navier-Stokes solver CFX-10 (Ansys Inc., Canonsburg, PA) and user-supplied pre- and post-processing software, the thermal performance of nanofluid flow in a trapezoidal microchannel was analyzed using pure water as well as a nanofluid, i.e., CuO-water, with volume fractions of 1% and 4% CuO-particles with d{sub p} = 28.6 nm. The results show that nanofluids do measurably enhance the thermal performance of microchannel mixture flow with a small increase in pumping power. Specifically, the thermal performance increases with volume fraction; but, the extra pressure drop, or pumping power, will somewhat decrease the beneficial effects. Microchannel heat sinks with nanofluids are expected to be good candidates for the next generation of cooling devices.

  15. Pushing desalination recovery to the maximum limit: Membrane and thermal processes integration

    KAUST Repository

    Shahzad, Muhammad Wakil; Burhan, Muhammad; Ng, Kim Choon

    2017-01-01

    The economics of seawater desalination processes has been continuously improving as a result of desalination market expansion. Presently, reverse osmosis (RO) processes are leading in global desalination with 53% share followed by thermally driven

  16. Circulation and mixing process in Vasishta-Godavari estuary, east coast of India

    Digital Repository Service at National Institute of Oceanography (India)

    Kumar, A.R.S.; Murty, T.V.R.; Rao, M.M.M.; Rao, V.R.; Reddy, B.S.R.

    Circulation and Mixing Process in Vasishta-Godavari Estuary, have been studied by using estuarine classification model. Analysis of salinity, salt budget, diffusion coefficients and flushing times based on salinity data of Vasishta-Godavari estuary...

  17. Mixed waste: Proceedings

    International Nuclear Information System (INIS)

    Moghissi, A.A.; Blauvelt, R.K.; Benda, G.A.; Rothermich, N.E.

    1993-01-01

    This volume contains the peer-reviewed and edited versions of papers submitted for presentation a the Second International Mixed Waste Symposium. Following the tradition of the First International Mixed Waste Symposium, these proceedings were prepared in advance of the meeting for distribution to participants. The symposium was organized by the Mixed Waste Committee of the American Society of Mechanical Engineers. The topics discussed at the symposium include: stabilization technologies, alternative treatment technologies, regulatory issues, vitrification technologies, characterization of wastes, thermal technologies, laboratory and analytical issues, waste storage and disposal, organic treatment technologies, waste minimization, packaging and transportation, treatment of mercury contaminated wastes and bioprocessing, and environmental restoration. Individual abstracts are catalogued separately for the data base

  18. Mixed waste: Proceedings

    Energy Technology Data Exchange (ETDEWEB)

    Moghissi, A.A.; Blauvelt, R.K.; Benda, G.A.; Rothermich, N.E. [eds.] [Temple Univ., Philadelphia, PA (United States). Dept. of Environmental Safety and Health

    1993-12-31

    This volume contains the peer-reviewed and edited versions of papers submitted for presentation a the Second International Mixed Waste Symposium. Following the tradition of the First International Mixed Waste Symposium, these proceedings were prepared in advance of the meeting for distribution to participants. The symposium was organized by the Mixed Waste Committee of the American Society of Mechanical Engineers. The topics discussed at the symposium include: stabilization technologies, alternative treatment technologies, regulatory issues, vitrification technologies, characterization of wastes, thermal technologies, laboratory and analytical issues, waste storage and disposal, organic treatment technologies, waste minimization, packaging and transportation, treatment of mercury contaminated wastes and bioprocessing, and environmental restoration. Individual abstracts are catalogued separately for the data base.

  19. Effects of coupled thermal, hydrological and chemical processes on nuclide transport

    International Nuclear Information System (INIS)

    Carnahan, C.L.

    1987-03-01

    Coupled thermal, hydrological and chemical processes can be classified in two categories. One category consists of the ''Onsager'' type of processes driven by gradients of thermodynamic state variables. These processes occur simultaneously with the direct transport processes. In particular, thermal osmosis, chemical osmosis and ultrafiltration may be prominent in semipermeable materials such as clays. The other category consists of processes affected indirectly by magnitudes of thermodynamic state variables. An important example of this category is the effect of temperature on rates of chemical reactions and chemical equilibria. Coupled processes in both categories may affect transport of radionuclides. Although computational models of limited extent have been constructed, there exists no model that accounts for the full set of THC-coupled processes. In the category of Onsager coupled processes, further model development and testing is severely constrained by a deficient data base of phenomenological coefficients. In the second category, the lack of a general description of effects of heterogeneous chemical reactions on permeability of porous media inhibits progress in quantitative modeling of hydrochemically coupled transport processes. Until fundamental data necessary for further model development have been acquired, validation efforts will be limited necessarily to testing of incomplete models of nuclide transport under closely controlled experimental conditions. 34 refs., 2 tabs

  20. Measurements of Flow Mixing at Subchannels in a Wire-Wrapped 61-Rod Bundle for a Sodium Cooled Fast Reactor

    International Nuclear Information System (INIS)

    Lee, Dong Won; Kim, Hyungmo; Ko, Yung Joo; Choi, Hae Seob; Euh, Dong-Jin; Jeong, Ji-Young; Lee, Hyeong-Yeon

    2015-01-01

    For a safety analysis in a core thermal design of a sodium-cooled fast reactor (SFR), flow mixing characteristics at subchannels in a wire-wrapped rod bundle are crucial factor for the design code verification and validation. Wrapped wires make a cross flow in a circumference of the fuel rod, and this effect lets flow be mixed. Therefore the sub-channel analysis method is commonly used for thermal hydraulic analysis of a SFR, a wire wrapped sub-channel type. To measure flow mixing characteristics, a wire mesh sensing technique can be useful method. A wire mesh sensor has been traditionally used to measure the void fraction of a two-phase flow field, i.e. gas and liquid. However, the recent reports that the wire mesh sensor can be used successfully to recognize the flow field in liquid phase by injecting a tracing liquid with a different level of electric conductivity. The subchannel flow characteristics analysis method is commonly used for the thermal hydraulic analysis of a SFR, a wire wrapped subchannel type. In this study, mixing experiments were conducted successfully at a hexagonally arrayed 61-pin wire-wrapped fuel rod bundle test section. Wire mesh sensor was used to measure flow mixing characteristics. The developed post-processing method has its own merits, and flow mixing results were reasonable

  1. Guideline for benchmarking thermal treatment systems for low-level mixed waste

    International Nuclear Information System (INIS)

    Hoffman, D.P.; Gibson, L.V. Jr.; Hermes, W.H.; Bastian, R.E.; Davis, W.T.

    1994-01-01

    A process for benchmarking low-level mixed waste (LLMW) treatment technologies has been developed. When used in conjunction with the identification and preparation of surrogate waste mixtures, and with defined quality assurance and quality control procedures, the benchmarking process will effectively streamline the selection of treatment technologies being considered by the US Department of Energy (DOE) for LLMW cleanup and management. Following the quantitative template provided in the benchmarking process will greatly increase the technical information available for the decision-making process. The additional technical information will remove a large part of the uncertainty in the selection of treatment technologies. It is anticipated that the use of the benchmarking process will minimize technology development costs and overall treatment costs. In addition, the benchmarking process will enhance development of the most promising LLMW treatment processes and aid in transferring the technology to the private sector. To instill inherent quality, the benchmarking process is based on defined criteria and a structured evaluation format, which are independent of any specific conventional treatment or emerging process technology. Five categories of benchmarking criteria have been developed for the evaluation: operation/design; personnel health and safety; economics; product quality; and environmental quality. This benchmarking document gives specific guidance on what information should be included and how it should be presented. A standard format for reporting is included in Appendix A and B of this document. Special considerations for LLMW are presented and included in each of the benchmarking categories

  2. Mixing during draw-off in small SDHW systems

    DEFF Research Database (Denmark)

    Andersen, Elsa; Furbo, Simon

    1998-01-01

    The aim of the project is to determine a maximum acceptable mixing rate during hot water tappings, so called draw-offs. Based on a pervious proposal for a maximum acceptable decrease of thermal performance due to mixing during draw-off, investigations are carried out in order to determine the mix...

  3. Mathematical Modelling of Thermal Process to Aquatic Environment with Different Hydrometeorological Conditions

    Directory of Open Access Journals (Sweden)

    Alibek Issakhov

    2014-01-01

    Full Text Available This paper presents the mathematical model of the thermal process from thermal power plant to aquatic environment of the reservoir-cooler, which is located in the Pavlodar region, 17 Km to the north-east of Ekibastuz town. The thermal process in reservoir-cooler with different hydrometeorological conditions is considered, which is solved by three-dimensional Navier-Stokes equations and temperature equation for an incompressible flow in a stratified medium. A numerical method based on the projection method, divides the problem into three stages. At the first stage, it is assumed that the transfer of momentum occurs only by convection and diffusion. Intermediate velocity field is solved by fractional steps method. At the second stage, three-dimensional Poisson equation is solved by the Fourier method in combination with tridiagonal matrix method (Thomas algorithm. Finally, at the third stage, it is expected that the transfer is only due to the pressure gradient. Numerical method determines the basic laws of the hydrothermal processes that qualitatively and quantitatively are approximated depending on different hydrometeorological conditions.

  4. Engineering Analysis of Thermal-Load Components in the Process of Heating of Pet Preforms

    Science.gov (United States)

    Sidorov, D. É.; Kolosov, A. E.; Kazak, I. A.; Pogorelyi, A. V.

    2018-05-01

    The influence of thermal-load components (convection, collimated and uncollimated components of infrared radiation) in the process of production of PET packaging on the heating of PET preforms has been assessed. It has been established that the collimated component of infrared radiation ensures most (up to 70%) of the thermal energy in the process of heating of a PET preform.

  5. Thermal stability of poly(3-hydroxybutyrate)/vegetable fiber composites

    Science.gov (United States)

    Cipriano, Pâmela Bento; de Sá, Mayelli Dantas; Andrade, André L. Simões; de Carvalho, Laura Hecker; Canedo, Eduardo Luis

    2015-05-01

    The present work deals with the thermal stability during and after processing of composites of poly(3-hydroxybutyrate) (PHB) - a fully biodegradable semi-crystalline thermoplastic obtained from renewable resources through low-impact biotechnological process, biocompatible and non-toxic - and vegetable fiber from the fruit (coconut) of babassu palm tree. PHB/babassu composites with 0, 5, 10 and 20% w/w load were prepared in a laboratory internal mixer. Two fractions of the mesocarp of babassu with different particle sizes were compounded with PHB and test specimens molded by compression. The effect of loading level and processing conditions on torque, temperature and mechanical energy dissipation were studied using a new engineering model. It was found that PHB degrades during processing at temperatures slightly above the melting point. To minimize thermal degradation stabilizer and chain extender additives were incorporated, with mixed results. These findings were confirmed by the dependence of the melt flow rate on the processing temperature.

  6. Experimental Study of Thermal Runaway Process of 18650 Lithium-Ion Battery

    Directory of Open Access Journals (Sweden)

    Jingjing Liu

    2017-02-01

    Full Text Available This study addresses the effects of the SOC (State of Charge and the charging–discharging process on the thermal runaway of 18650 lithium-ion batteries. A series of experiments were conducted on an electric heating and testing apparatus. The experimental results indicate that 6 W is the critical heating power for 40% SOC. With a 20 W constant heating rate, the thermal runaway initial temperature of the lithium-ion battery decreases with the increasing SOC. The final thermal runaway temperature increases with the SOC when the SOC is lower than 80%. However, a contrary conclusion was obtained when the SOC was higher than 80%. Significant mass loss, accompanied by an intense exothermic reaction, took place under a higher SOC. The critical charging current, beyond which the thermal runaway occurs, was found to be 2.6 A. The thermal runaway initial temperature decreases with the increasing charging current, while the intensity of the exothermic reaction varies inversely. Mass ejection of gas and electrolytes exists during thermal runaway when the charging current is higher than 10.4 A, below which only a large amount of gas is released. The thermal runaway initial temperature of discharging is higher than that of non-discharging.

  7. Experimental Study of Thermal Runaway Process of 18650 Lithium-Ion Battery.

    Science.gov (United States)

    Liu, Jingjing; Wang, Zhirong; Gong, Junhui; Liu, Kai; Wang, Hao; Guo, Linsheng

    2017-02-25

    This study addresses the effects of the SOC (State of Charge) and the charging-discharging process on the thermal runaway of 18650 lithium-ion batteries. A series of experiments were conducted on an electric heating and testing apparatus. The experimental results indicate that 6 W is the critical heating power for 40% SOC. With a 20 W constant heating rate, the thermal runaway initial temperature of the lithium-ion battery decreases with the increasing SOC. The final thermal runaway temperature increases with the SOC when the SOC is lower than 80%. However, a contrary conclusion was obtained when the SOC was higher than 80%. Significant mass loss, accompanied by an intense exothermic reaction, took place under a higher SOC. The critical charging current, beyond which the thermal runaway occurs, was found to be 2.6 A. The thermal runaway initial temperature decreases with the increasing charging current, while the intensity of the exothermic reaction varies inversely. Mass ejection of gas and electrolytes exists during thermal runaway when the charging current is higher than 10.4 A, below which only a large amount of gas is released. The thermal runaway initial temperature of discharging is higher than that of non-discharging.

  8. Thermal diffusivity and conductivity of thorium- uranium mixed oxides

    Science.gov (United States)

    Saoudi, M.; Staicu, D.; Mouris, J.; Bergeron, A.; Hamilton, H.; Naji, M.; Freis, D.; Cologna, M.

    2018-03-01

    Thorium-uranium oxide pellets with high densities were prepared at the Canadian Nuclear Laboratories (CNL) by co-milling, pressing, and sintering at 2023 K, with UO2 mass contents of 0, 1.5, 3, 8, 13, 30, 60 and 100%. At the Joint Research Centre, Karlsruhe (JRC-Karlsruhe), thorium-uranium oxide pellets were prepared using the spark plasma sintering (SPS) technique with 79 and 93 wt. % UO2. The thermal diffusivity of (Th1-xUx)O2 (0 ≤ x ≤ 1) was measured at CNL and at JRC-Karlsruhe using the laser flash technique. ThO2 and (Th,U)O2 with 1.5, 3, 8 and 13 wt. % UO2 were found to be semi-transparent to the infrared wavelength of the laser and were coated with graphite for the thermal diffusivity measurements. This semi-transparency decreased with the addition of UO2 and was lost at about 30 wt. % of UO2 in ThO2. The thermal conductivity was deduced using the measured density and literature data for the specific heat capacity. The thermal conductivity for ThO2 is significantly higher than for UO2. The thermal conductivity of (Th,U)O2 decreases rapidly with increasing UO2 content, and for UO2 contents of 60% and higher, the conductivity of the thorium-uranium oxide fuel is close to UO2. As the mass difference between the Th and U atoms is small, the thermal conductivity decrease is attributed to the phonon scattering enhanced by lattice strain due to the introduction of uranium in ThO2 lattice. The new results were compared to the data available in the literature and were evaluated using the classical phonon transport model for oxide systems.

  9. Recovery of recycled acrylonitrile-butadiene-styrene, through mixing with styrene-ethylene/butylene-styrene

    OpenAIRE

    Peydro, M. A.; Parres, F.; Crespo Amorós, José Enrique; Navarro Vidal, Raúl

    2013-01-01

    Recovery of recycled acrylonitrile-butadiene-styrene (ABS) through mixing with styrene-ethylene/butylene-styrene (SEBS) has been studied in this paper. To simulate recycled ABS, virgin ABS was processed through 5 cycles, at extreme processing temperatures, 220 degrees C and 260 degrees C. The virgin ABS, the virgin SEBS, the recycled ABS and the mixtures were mechanically, thermally and rheologically characterized after the various cycles of reprocessing in order to evaluate their correspondi...

  10. High dielectric permittivity and improved mechanical and thermal properties of poly(vinylidene fluoride) composites with low carbon nanotube content: effect of composite processing on phase behavior and dielectric properties.

    Science.gov (United States)

    Kumar, G Sudheer; Vishnupriya, D; Chary, K Suresh; Patro, T Umasankar

    2016-09-23

    The composite processing technique and nanofiller concentration and its functionalization significantly alter the properties of polymer nanocomposites. To realize this, multi-walled carbon nanotubes (CNT) were dispersed in a poly(vinylidene fluoride) (PVDF) matrix at carefully selected CNT concentrations by two illustrious methods, such as solution-cast and melt-mixing. Notwithstanding the processing method, CNTs induced predominantly the γ-phase in PVDF, instead of the commonly obtained β-phase upon nanofiller incorporation, and imparted significant improvements in dielectric properties. Acid-treatment of CNT improved its dispersion and interfacial adhesion significantly with PVDF, and induced a higher γ-phase content and better dielectric properties in PVDF as compared to pristine CNT. Further, the γ-phase content was found to be higher in solution-cast composites than that in melt-mixed counterparts, most likely due to solvent-induced crystallization in a controlled environment and slow solvent evaporation in the former case. However, interestingly, the melt-mixed composites showed a significantly higher dielectric constant at the onset of the CNT networked-structure as compared to the solution-cast composites. This suggests the possible role of CNT breakage during melt-mixing, which might lead to higher space-charge polarization at the polymer-CNT interface, and in turn an increased number of pseudo-microcapacitors in these composites than the solution-cast counterparts. Notably, PVDF with 0.13 vol% (volume fraction, f c  = 0.0013) of acid-treated CNTs, prepared by melt-mixing, displayed the relative permittivity of ∼217 and capacitance of ∼5430 pF, loss tangent of ∼0.4 at 1 kHz and an unprecedented figure of merit of ∼10(5). We suggest a simple hypothesis for the γ-phase formation and evolution of the high dielectric constant in these composites. Further, the high-dielectric composite film showed marked improvements in mechanical and thermal

  11. Thermal diffusion and separation of isotopes; Diffusion thermique et separation d'isotopes

    Energy Technology Data Exchange (ETDEWEB)

    Fournier, Andre

    1944-03-30

    After a review of the various processes used to separate isotopes or at least to obtain mixes with a composition different from the natural proportion, this research addresses the use of thermal diffusion. The author reports a theoretical study of gas thermal diffusion and of the Clusius-Dickel method. In the second part, he reports the enrichment of methane with carbon-13, and of ammoniac with nitrogen-15. The next part reports the experimental study of thermal diffusion of liquids and solutions, and the enrichment of carbon tetra-chloride with chlorine-37. The author then proposes an overview of theories of thermal diffusion in liquid phase (hydrodynamic theory, kinetic theory, theory of caged molecules)

  12. Dehydrohalogenation during pyrolysis of brominated flame retardant containing high impact polystyrene (HIPS-Br) mixed with polyvinylchloride (PVC)

    Energy Technology Data Exchange (ETDEWEB)

    Uddin, M.A.; Bhaskar, T.; Kaneko, J.; Muto, A.; Sakata, Y.; Matsui, T. [Okayama University, Okayama (Japan). Dept. of Applied Chemistry, Faculty of Engineering

    2002-09-01

    Dehydrohalogenation during pyrolysis of brominated flame retardant containing polystyrene (brominated high impact polystyrene (HIPS-Br)) mixed with polyvinylchloride (PVC) was carried out in a laboratory scale batch process. Thermal and catalytic degradation of HIPS-Br mixed with PVBC on carbon composite of iron oxide (TR-00301) catalyst was investigated. The thermal degradation of waste plastics (HIPS-Br/PVC) yielded liquid products with 55,000 ppm bromine and 4300 ppm chlorine content in oil. Catalytic degradation (4 g; TR-00301) of HIPS-Br/PVC waste plastics at 430{degree}C produced halogen-free clean oil, which can be used as a fuel oil or chemical feedstock. The main liquid products during catalytic degradation were benzene, toluene, styrene, ethyl benzene, {alpha}-methyl styrene, butyl benzene, 1,2-dimethyl benzene etc. The average carbon number of the liquid products produced during catalytic degradation (9.3) of waste plastics was less than that of the thermal degradation (10.4) and the density of liquid products was found to be lower during the catalytic degradation than the thermal degradation. The possibility of a single step catalytic process for the conversion of halogenated waste plastics into fuel oil with the simultaneous removal of chlorine and bromine content form the oil was demonstrated. 21 refs., 7 figs., 2 tabs.

  13. Quantities and characteristics of the contact-handled low-level mixed waste streams for the DOE complex

    International Nuclear Information System (INIS)

    Huebner, T.L.; Wilson, J.M.; Ruhter, A.H.; Bonney, S.J.

    1994-08-01

    This report supports the Integrated Thermal Treatment System (ITTS) Study initiated by the Department of Energy (DOE) Office of Technology Development (EM-50), which is a system engineering assessment of a variety of mixed waste treatment process. The DOE generates and stores large quantities of mixed wastes that are contaminated with both chemically hazardous and radioactive species. The treatment of these mixed wastes requires meeting the standards established by the Environmental Protection Agency for the specific hazardous contaminants regulated under the Resource Conservation and Recovery Act while also providing adequate control of the radionuclides. The thrust of the study is to develop preconceptual designs and life-cycle cost estimates for integrated thermal treatment systems ranging from conventional incinerators, such as rotary kiln and controlled air systems, to more innovative but not yet established technologies, such as molten salt and molten metal waste destruction systems. Prior to this engineering activity, the physical and chemical characteristics of the DOE low-level mixed waste streams to be treated must be defined or estimated. This report describes efforts to estimate the DOE waste stream characteristics

  14. Thermal hydraulic behavior of SCWR sliding pressure startup

    International Nuclear Information System (INIS)

    Fu Shengwei; Zhou Chong; Xu Zhihong; Yang Yanhua

    2011-01-01

    The modification to ATHLET-SC code is introduced in this paper, which realizes the simulation of trans-critical transients using two-phase model. With the modified code, the thermal-hydraulic dynamic behavior of the mixed SCWR core during the startup process is simulated. The startup process is similar to the design of SCLWR-H sliding pressure startup. The results show that maximum temperature of cladding-surface does not exceed 650℃ in the whole startup process, and the sudden change of water properties in the trans-critical transients will not cause harmful influence to the heat transfer of the fuel cladding. (authors)

  15. Investigation of mixing and diffusion processes in hybrid spot laser-MIG keyhole welding

    International Nuclear Information System (INIS)

    Zhou, J; Tsai, H L

    2009-01-01

    In hybrid laser-MIG keyhole welding, anti-crack elements can be added into the weld pool through a filler metal in anticipation of compensating mass loss, preventing porosity formation and improving compositional and mechanical properties of the welds. Understanding the mixing and diffusion of the filler metal in the molten pool is vital to achieve these desired objectives. In this study, mathematical models and associated numerical techniques have been developed to investigate the mixing and diffusion processes in hybrid laser-MIG keyhole welding. The transient interactions between droplets and weld pool and dynamics of the melt flow are studied. The effects of key process parameters, such as droplet size (wire diameter), droplet generation frequency (wire feed speed) and droplet impinging speed, on mixing/diffusion are systematically investigated. It was found that compositional homogeneity of the weld pool is determined by the competition between the mixing rate and the solidification rate. A small-size filler droplet together with high generation frequency can increase the latitudinal diffusion of the filler metal into the weld pool, while the large-size droplet along with the low generation frequency helps to get more uniform longitudinal diffusion. Increasing the impinging velocity of the filler droplet can improve the latitudinal diffusion of the filler metal. However, a high impinging velocity can cause a lower diffusion zone in the upper part of the welds. This study provides a good foundation for optimizing the hybrid laser-MIG keyhole welding process to achieve quality welds with desired properties.

  16. Simulation of thermal-hydraulic process in reactor of HTR-PM based on flow and heat transfer network

    International Nuclear Information System (INIS)

    Zhou Kefeng; Zhou Yangping; Sui Zhe; Ma Yuanle

    2012-01-01

    The development of HTR-PM full scale simulator (FSS) is an important part in the project. The simulation of thermal-hydraulic process in reactor is one of the key technologies in the development of FSS. The simulation of thermal-hydraulic process in reactor was studied. According to the geometry structures and the characteristics of thermal-hydraulic process in reactor, the model was setup in components construction way. Based on the established simulation method of flow and heat transfer network, a Fortran code was developed and the simulation of thermal-hydraulic process was achieved. The simulation results of 50% FP steady state, 100% FP steady state and control rod mistakenly ascension accidents were given. The verification of simulation results was carried out by comparing with the design and analysis code THERMIX. The results show that the method and model based on flow and heat transfer network can meet the requirements of FSS and reflect the features of thermal-hydraulic process in HTR-PM. (authors)

  17. Free Convection over a Permeable Horizontal Flat Plate Embedded in a Porous Medium with Radiation Effects and Mixed Thermal Boundary Conditions

    OpenAIRE

    Najiyah S. Khasi'ie; Roziena Khairuddin; Najihah Mohamed; Mohd Zuki Salleh; Roslinda Nazar; Ioan Pop

    2012-01-01

    Problem statement: In this study, the mathematical modeling of free convection boundary layer flow over a permeable horizontal flat plate embedded in a porous medium under mixed thermal boundary conditions and radiation effects is considered. Approach: The transformed boundary layer equations are solved numerically using the shooting method. Results: Numerical solutions are obtained for the wall temperature, the heat transfer coefficient, as well as the velocity and temperature profiles. The ...

  18. Development of rubber mixing process mathematical model and synthesis of control correction algorithm by process temperature mode using an artificial neural network

    Directory of Open Access Journals (Sweden)

    V. S. Kudryashov

    2016-01-01

    Full Text Available The article is devoted to the development of a correction control algorithm by temperature mode of a periodic rubber mixing process for JSC "Voronezh tire plant". The algorithm is designed to perform in the main controller a section of rubber mixing Siemens S7 CPU319F-3 PN/DP, which forms tasks for the local temperature controllers HESCH HE086 and Jumo dTRON304, operating by tempering stations. To compile the algorithm was performed a systematic analysis of rubber mixing process as an object of control and was developed a mathematical model of the process based on the heat balance equations describing the processes of heat transfer through the walls of technological devices, the change of coolant temperature and the temperature of the rubber compound mixing until discharge from the mixer chamber. Due to the complexity and nonlinearity of the control object – Rubber mixers and the availability of methods and a wide experience of this device control in an industrial environment, a correction algorithm is implemented on the basis of an artificial single-layer neural network and it provides the correction of tasks for local controllers on the cooling water temperature and air temperature in the workshop, which may vary considerably depending on the time of the year, and during prolonged operation of the equipment or its downtime. Tempering stations control is carried out by changing the flow of cold water from the cooler and on/off control of the heating elements. The analysis of the model experiments results and practical research at the main controller programming in the STEP 7 environment at the enterprise showed a decrease in the mixing time for different types of rubbers by reducing of heat transfer process control error.

  19. CFD-FEM coupling for accurate prediction of thermal fatigue

    International Nuclear Information System (INIS)

    Hannink, M.H.C.; Kuczaj, A.K.; Blom, F.J.; Church, J.M.; Komen, E.M.J.

    2009-01-01

    Thermal fatigue is a safety related issue in primary pipework systems of nuclear power plants. Life extension of current reactors and the design of a next generation of new reactors lead to growing importance of research in this direction. The thermal fatigue degradation mechanism is induced by temperature fluctuations in a fluid, which arise from mixing of hot and cold flows. Accompanied physical phenomena include thermal stratification, thermal striping, and turbulence [1]. Current plant instrumentation systems allow monitoring of possible causes as stratification and temperature gradients at fatigue susceptible locations [1]. However, high-cycle temperature fluctuations associated with turbulent mixing cannot be adequately detected by common thermocouple instrumentations. For a proper evaluation of thermal fatigue, therefore, numerical simulations are necessary that couple instantaneous fluid and solid interactions. In this work, a strategy for the numerical prediction of thermal fatigue is presented. The approach couples Computational Fluid Dynamics (CFD) and the Finite Element Method (FEM). For the development of the computational approach, a classical test case for the investigation of thermal fatigue problems is studied, i.e. mixing in a T-junction. Due to turbulent mixing of hot and cold fluids in two perpendicularly connected pipes, temperature fluctuations arise in the mixing zone downstream in the flow. Subsequently, these temperature fluctuations are also induced in the pipes. The stresses that arise due to the fluctuations may eventually lead to thermal fatigue. In the first step of the applied procedure, the temperature fluctuations in both fluid and structure are calculated using the CFD method. Subsequently, the temperature fluctuations in the structure are imposed as thermal loads in a FEM model of the pipes. A mechanical analysis is then performed to determine the thermal stresses, which are used to predict the fatigue lifetime of the structure

  20. Mixing and thermonuclear processes in stars

    International Nuclear Information System (INIS)

    Langer, Norbert; Heger, Alexander; Herwig, Falk; Wellstein, Stephan

    2001-01-01

    According to standard wisdom, six different nuclear burning stages, from hydrogen to silicon burning, can occur during the hydrostatic evolution of stars. However, several instabilities can lead to the mixing of layers with different compositions and produce non-standard composition mixtures. Those--when at high enough temperatures--burn due to nuclear reactions which are unimportant otherwise. We provide various examples of such occurrences, for different ratios of burning over mixing time scale