Models for mean bonding length, melting point and lattice thermal expansion of nanoparticle materials

Energy Technology Data Exchange (ETDEWEB)

Omar, M.S., E-mail: dr_m_s_omar@yahoo.com [Department of Physics, College of Science, University of Salahaddin-Erbil, Arbil, Kurdistan (Iraq)

2012-11-15

Graphical abstract: Three models are derived to explain the nanoparticles size dependence of mean bonding length, melting temperature and lattice thermal expansion applied on Sn, Si and Au. The following figures are shown as an example for Sn nanoparticles indicates hilly applicable models for nanoparticles radius larger than 3 nm. Highlights: ► A model for a size dependent mean bonding length is derived. ► The size dependent melting point of nanoparticles is modified. ► The bulk model for lattice thermal expansion is successfully used on nanoparticles. -- Abstract: A model, based on the ratio number of surface atoms to that of its internal, is derived to calculate the size dependence of lattice volume of nanoscaled materials. The model is applied to Si, Sn and Au nanoparticles. For Si, that the lattice volume is increases from 20 Å{sup 3} for bulk to 57 Å{sup 3} for a 2 nm size nanocrystals. A model, for calculating melting point of nanoscaled materials, is modified by considering the effect of lattice volume. A good approach of calculating size-dependent melting point begins from the bulk state down to about 2 nm diameter nanoparticle. Both values of lattice volume and melting point obtained for nanosized materials are used to calculate lattice thermal expansion by using a formula applicable for tetrahedral semiconductors. Results for Si, change from 3.7 × 10{sup −6} K{sup −1} for a bulk crystal down to a minimum value of 0.1 × 10{sup −6} K{sup −1} for a 6 nm diameter nanoparticle.

Variability of Basal Melt Beneath the Pine Island Glacier Ice Shelf, West Antarctica

Science.gov (United States)

Bindschadler, Robert; Vaughan, David G.; Vornberger, Patricia

2011-01-01

Observations from satellite and airborne platforms are combined with model calculations to infer the nature and efficiency of basal melting of the Pine Island Glacier ice shelf, West Antarctica, by ocean waters. Satellite imagery shows surface features that suggest ice-shelf-wide changes to the ocean s influence on the ice shelf as the grounding line retreated. Longitudinal profiles of ice surface and bottom elevations are analyzed to reveal a spatially dependent pattern of basal melt with an annual melt flux of 40.5 Gt/a. One profile captures a persistent set of surface waves that correlates with quasi-annual variations of atmospheric forcing of Amundsen Sea circulation patterns, establishing a direct connection between atmospheric variability and sub-ice-shelf melting. Ice surface troughs are hydrostatically compensated by ice-bottom voids up to 150m deep. Voids form dynamically at the grounding line, triggered by enhanced melting when warmer-than-average water arrives. Subsequent enlargement of the voids is thermally inefficient (4% or less) compared with an overall melting efficiency beneath the ice shelf of 22%. Residual warm water is believed to cause three persistent polynyas at the ice-shelf front seen in Landsat imagery. Landsat thermal imagery confirms the occurrence of warm water at the same locations.

Temperature Profile in Fuel and Tie-Tubes for Nuclear Thermal Propulsion Systems

Energy Technology Data Exchange (ETDEWEB)

Vishal Patel

2015-02-01

A finite element method to calculate temperature profiles in heterogeneous geometries of tie-tube moderated LEU nuclear thermal propulsion systems and HEU designs with tie-tubes is developed and implemented in MATLAB. This new method is compared to previous methods to demonstrate shortcomings in those methods. Typical methods to analyze peak fuel centerline temperature in hexagonal geometries rely on spatial homogenization to derive an analytical expression. These methods are not applicable to cores with tie-tube elements because conduction to tie-tubes cannot be accurately modeled with the homogenized models. The fuel centerline temperature directly impacts safety and performance so it must be predicted carefully. The temperature profile in tie-tubes is also important when high temperatures are expected in the fuel because conduction to the tie-tubes may cause melting in tie-tubes, which may set maximum allowable performance. Estimations of maximum tie-tube temperature can be found from equivalent tube methods, however this method tends to be approximate and overly conservative. A finite element model of heat conduction on a unit cell can model spatial dependence and non-linear conductivity for fuel and tie-tube systems allowing for higher design fidelity of Nuclear Thermal Propulsion.

Melting/solidification characteristics of paraffin based nanocomposite for thermal energy storage applications

Directory of Open Access Journals (Sweden)

Lokesh Selvam

2017-01-01

Full Text Available The present work aimed to investigate the melting and solidification characteristics of nanoparticle enhanced phase change material (NEPCM. The NEPCM were prepared using paraffin as the phase change material and multiwall carbon nanotube (MWCNT as the nanomaterial without using any dispersant. Thermal conductivity of the NEPCM was measured with respect to temperature and the measured data showed higher enhancement than the phase change material both in liquid and solid state, due to inherent high conductive and the continuous networking of the MWCNT. A reduction in solidification and melting time of 42% and 29% was achieved in the case of NEPCM with 0.9% and 0.3%, respectively. It is concluded that enhanced heat transfer characteristics of NEPCM is highly beneficial towards design and development of efficient thermal energy storage system for various applications.

Thermal analysis as an aid to forensics: Alkane melting and oxidative stability of wool

International Nuclear Information System (INIS)

Alan Riga, D.

1998-01-01

Interdisciplinary methods and thermal analytical techniques in particular are effective tools in aiding the identification and characterization of materials in question involved in civil or criminal law. Forensic material science uses systematic knowledge of the physical or material world gained through analysis, observation and experimentation. Thermal analytical data can be used to aid the legal system in interpreting technical variations in quite often a complex system.Calorimetry and thermal microscopic methods helped define a commercial product composed of alkanes that was involved in a major law suit. The solid-state structures of a number of normal alkanes have unique crystal structures. These alkanes melt and freeze below room temperature to more than 60C below zero. Mixtures of specific alkanes have attributes of pure chemicals. The X-ray diffraction structure of a mixture of alkanes is the same as a pure alkane, but the melting and freezing temperature are significantly lower than predicted. The jury ruled that the product containing n-alkanes had the appropriate melting characteristics. The thermal-physical properties made a commercial fluid truly unique and there was no advertising infringement according to the law and the jury trialA combination of thermogravimetry, differential thermal analysis, infrared spectroscopy and macrophotography were used to conduct an extensive modeling and analysis of physical evidence obtained in a mobile home fire and explosion. A person's death was allegedly linked to the misuse of a kerosene space heater. The thermal analytical techniques showed that external heating was the cause of the space heater's deformation, not a firing of the heater with gasoline and kerosene. (Copyright (c) 1998 Elsevier Science B.V., Amsterdam. All rights reserved.)

Thermal analysis as an aid to forensics: Alkane melting and oxidative stability of wool

Energy Technology Data Exchange (ETDEWEB)

Alan Riga, D. [Professor of Chemistry, Cleveland State University and TechCon Inc., 6325 Aldenham Dr., Cleveland, OH 44143-3331 (United States)

1998-12-21

Interdisciplinary methods and thermal analytical techniques in particular are effective tools in aiding the identification and characterization of materials in question involved in civil or criminal law. Forensic material science uses systematic knowledge of the physical or material world gained through analysis, observation and experimentation. Thermal analytical data can be used to aid the legal system in interpreting technical variations in quite often a complex system.Calorimetry and thermal microscopic methods helped define a commercial product composed of alkanes that was involved in a major law suit. The solid-state structures of a number of normal alkanes have unique crystal structures. These alkanes melt and freeze below room temperature to more than 60C below zero. Mixtures of specific alkanes have attributes of pure chemicals. The X-ray diffraction structure of a mixture of alkanes is the same as a pure alkane, but the melting and freezing temperature are significantly lower than predicted. The jury ruled that the product containing n-alkanes had the appropriate melting characteristics. The thermal-physical properties made a commercial fluid truly unique and there was no advertising infringement according to the law and the jury trialA combination of thermogravimetry, differential thermal analysis, infrared spectroscopy and macrophotography were used to conduct an extensive modeling and analysis of physical evidence obtained in a mobile home fire and explosion. A person's death was allegedly linked to the misuse of a kerosene space heater. The thermal analytical techniques showed that external heating was the cause of the space heater's deformation, not a firing of the heater with gasoline and kerosene. (Copyright (c) 1998 Elsevier Science B.V., Amsterdam. All rights reserved.)

On the role of thermal fluid dynamics into the evolution of porosity during selective laser melting

International Nuclear Information System (INIS)

Panwisawas, C.; Qiu, C.L.; Sovani, Y.; Brooks, J.W.; Attallah, M.M.; Basoalto, H.C.

2015-01-01

Thermal fluid dynamics and experiments have been used to study the evolution of pores during selective laser melting of Ti-6Al-4V. Scanning electron micrographs show that the morphology of pores changed from near-spherical to elongated shape as the laser scan speed increased. Computational fluid dynamics suggests that this is caused by the change of flow pattern in the melt pool which is dictated by forces such as vapour pressure, gravitational force, capillary and thermal capillary forces exerted on the metallic/gaseous interface

Thermal Expansion Properties of Fe-42Ni-Si Alloy Strips Fabricated by Melt Drag Casting Process

International Nuclear Information System (INIS)

Kim, Moo Kyum; Ahn, Yong Sik; Namkung, Jeong; Kim, Moon Chul; Kim, Yong Chan

2007-01-01

Thermal expansion property was investigated on Fe-42% Ni alloy strip added by alloying element of Si of 0∼1.5wt.%. The strip was fabricated by a melt drag casting process. Addition of Si enlarged the solid-liquid region and reduced the melting point which leads to the increase of the formability of a strip. The alloy containing 0.6 wt.% Si showed the lowest thermal expansion ratio in the temperature range between 20 to 350 .deg. C. The grain size was increased with reduction ratio and annealing temperature, which resulted in the decrease of the thermal expansion coefficient of strip. Because of grain refining by precipitation of Ni 3 Fe, the alloy strip containing 1.5 wt.% Si showed higher thermal expansion ratio compared with the alloy containing 0.6 wt.% Si

Thermal Depth Profiling Reconstruction by Multilayer Thermal Quadrupole Modeling and Particle Swarm Optimization

International Nuclear Information System (INIS)

Zhao-Jiang, Chen; Shu-Yi, Zhang

2010-01-01

A new hybrid inversion method for depth profiling reconstruction of thermal conductivities of inhomogeneous solids is proposed based on multilayer quadrupole formalism of thermal waves, particle swarm optimization and sequential quadratic programming. The reconstruction simulations for several thermal conductivity profiles are performed to evaluate the applicability of the method. The numerical simulations demonstrate that the precision and insensitivity to noise of the inversion method are very satisfactory. (condensed matter: structure, mechanical and thermal properties)

Thermal and dynamic mechanical characterization of thermoplastic polyurethane/organoclay nanocomposites prepared by melt compounding

International Nuclear Information System (INIS)

Barick, A.K.; Tripathy, D.K.

2010-01-01

Thermoplastic polyurethane (TPU) nanocomposites based on organically modified layered silicate (OMLS) were prepared by melt intercalation process followed by compression molding. Different percentage of organoclays was incorporated into the TPU matrix in order to examine the influence of the nanoscaled fillers on nanostructure morphology and material properties. The microscopic morphology of the nanocomposites was evaluated by wide angle X-ray diffraction (WAXD), transmission electron microscopy (TEM), and atomic force microscopy (AFM). The observation revealed that both nanoclay-polymer interactions and shear stress developed during melt mixing are responsible for the effectively organoclay dispersion in TPU matrix resulting intercalated/exfoliated morphology. Thermal stability of the nanocomposites measured by thermogravimetric analysis (TGA) was improved significantly with the addition of nanoclay. The differential scanning calorimetry (DSC) analysis reveals that melting point of the nanocomposites increased with incorporation of nanoclay. The dynamic mechanical properties of the TPU nanocomposites were analyzed using a dynamic mechanical thermal analyzer (DMTA), which indicates that the storage modulus (E'), loss modulus (E''), and glass transition temperature (T g ) are significantly increased with increasing nanoclay content.

A quasimechanism of melt acceleration in the thermal decomposition of crystalline organic solids

Energy Technology Data Exchange (ETDEWEB)

Henson, Bryan F [Los Alamos National Laboratory

2009-01-01

It has been know for half a century that many crystalline organic solids undergo an acceleration in the rate of thermal decomposition as the melting temperature is approached. This acceleration terminates at the melting point, exhibiting an Arrhenius-like temperature dependence in the faster decomposition rate from the liquid phase. This observation has been modeled previously using various premelting behaviors based on e.g. freezing point depression induced by decomposition products or solvent impurities. These models do not, however, indicate a mechanism for liquid formation and acceleration which is an inherent function of the bulk thermodynamics of the molecule. Here we show that such an inherent thermodynamic mechanism for liquid formation exists in the form of the so-called quasi-liquid layer at the solid surface. We explore a kinetic mechanism which describes the acceleration of rate and is a function of the free energies of sublimation and vaporization. We construct a differential rate law from these thermodynamic free energies and a normalized progress variable. We further construct a reduced variable formulation of the model which is a simple function of the metastable liquid activity below the melting point, and show that it is applicable to the observed melt acceleration in several common organic crystalline solids. A component of the differential rate law, zero order in the progress variable, is shown to be proportional to the thickness of the quasiliquid layer predicted by a recent thermodynamic theory for this phenomenon. This work therefore serves not only to provide new insight into thermal decomposition in a broad class or organic crystalline solids, but also further validates the underlying thermodynamic nature of the phenomenon of liquid formation on the molecular surface at temperatures below the melting point.

Investigation of Thermal and Viscoelastic Properties of Polymers Relevant to Hot Melt Extrusion, IV: Affinisol™ HPMC HME Polymers.

Science.gov (United States)

Gupta, Simerdeep Singh; Solanki, Nayan; Serajuddin, Abu T M

2016-02-01

Most cellulosic polymers cannot be used as carriers for preparing solid dispersion of drugs by hot melt extrusion (HME) due to their high melt viscosity and thermal degradation at high processing temperatures. Three HME-grade hydroxypropyl methylcelluloses, namely Affinisol™ HPMC HME 15 cP, Affinisol™ HPMC HME 100 cP, and Affinisol™ HPMC HME 4 M, have recently been introduced by The Dow Chemical Co. to enable the preparation of solid dispersion at lower and more acceptable processing temperatures. In the present investigation, physicochemical properties of the new polymers relevant to HME were determined and compared with that of Kollidon(®) VA 64. Powder X-ray diffraction (PXRD), modulated differential scanning calorimetry (mDSC), thermogravimetric analysis (TGA), moisture sorption, rheology, and torque analysis by melt extrusion were applied. PXRD and mDSC showed that the Affinisol™ polymers were amorphous in nature. According to TGA, the onset of degradation for all polymers was >220°C. The Affinisol™ polymers exhibited less hygroscopicity than Kollidon(®) VA 64 and another HPMC polymer, Methocel™ K100LV. The complex viscosity profiles of the Affinisol™ polymers as a function of temperature were similar. The viscosity of the Affinisol™ polymers was highly sensitive to the shear rate applied, and unlike Kollidon(®) VA 64, the viscosity decreased drastically when the angular frequency was increased. Because of the very high shear rate encountered during melt extrusion, Affinisol™ polymers showed capability of being extruded at larger windows of processing temperatures as compared to that of Kollidon(®) VA 64.

Structure and thermal expansion of Lu2O3 and Yb2O3 up to the melting points

Science.gov (United States)

Pavlik, Alfred; Ushakov, Sergey V.; Navrotsky, Alexandra; Benmore, Chris J.; Weber, Richard J. K.

2017-11-01

Knowledge of thermal expansion and high temperature phase transformations is essential for prediction and interpretation of materials behavior under the extreme conditions of high temperature and intense radiation encountered in nuclear reactors. Structure and thermal expansion of Lu2O3 and Yb2O3 were studied in oxygen and argon atmospheres up to their melting temperatures using synchrotron X-ray diffraction on laser heated levitated samples. Both oxides retained the cubic bixbyite C-type structure in oxygen and argon to melting. In contrast to fluorite-type structures, the increase in the unit cell parameter of Yb2O3 and Lu2O3 with temperature is linear within experimental error from room temperature to the melting point, with mean thermal expansion coefficients (8.5 ± 0.6) · 10-6 K-1 and (7.7 ± 0.6) · 10-6 K-1, respectively. There is no indication of a superionic (Bredig) transition in the C-type structure or of a previously suggested Yb2O3 phase transformation to hexagonal phase prior to melting.

Synergistically improved thermal conductivity of polyamide-6 with low melting temperature metal and graphite

Directory of Open Access Journals (Sweden)

Y. C. Jia

2016-08-01

Full Text Available Low melting temperature metal (LMTM-tin (Sn was introduced into polyamide-6 (PA6 and PA6/graphite composites respectively to improve the thermal conductivity of PA6 by melt processing (extruding and injection molding. After introducing Sn, the thermal conductivity of PA6/Sn was nearly constant because of the serious agglomeration of Sn. However, when 20 wt% (5.4 vol% of Sn was added into PA6 containing 50 wt% (33.3 vol% of graphite, the thermal conductivity of the composite was dramatically increased to 5.364 versus 1.852 W·(m·K–1 for the PA6/graphite composite, which suggests that the incorporation of graphite and Sn have a significant synergistic effect on the thermal conductivity improvement of PA6. What is more, the electrical conductivity of the composite increased nearly 8 orders of magnitudes after introducing both graphite and Sn. Characterization of microstructure and energy dispersive spectrum analysis (EDS indicates that the dispersion of Sn in PA6/graphite/Sn was much more uniform than that of PA6/Sn composite. According to Differential Scanning Calorimetry measurement and EDS, the uniform dispersion of Sn in PA6/graphite/Sn and the high thermal conductivity of PA6/graphite/Sn are speculated to be related with the electron transfer between graphite and Sn, which makes Sn distribute evenly around the graphite layers.

Melting and thermal history of poly(hydroxybutyrate-co-hydroxyvalerate) using step-scan DSC

International Nuclear Information System (INIS)

Gunaratne, L.M.W.K.; Shanks, R.A.

2005-01-01

Melting behaviour and crystal morphology of poly(3-hydroxybutyrate) (PHB) and its copolymer of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) with various hydroxyvalerate (HV) contents [5 wt.% (PHB5HV), 8 wt.% (PHB8HV) and 12 wt.% (PHB12HV)] have been investigated by conventional DSC, step-scan differential scanning calorimetry (SDSC) and hot-stage polarised optical microscopy (HSPOM). Crystallisation behaviour of PHB and its copolymers were investigated by SDSC. Thermal properties were investigated after different crystallisation treatments, fast, medium and slow cooling. Multiple melting peak behaviour was observed for all polymers. SDSC data revealed that PHB and its copolymers undergo melting-recrystallisation-remelting during heating, as evidenced by exothermic peaks in the IsoK baseline (non-reversing signal). An increase in degree of crystallinity due to significant melt-recrystallisation was observed for slow-cooled copolymers. PHB5HV showed different crystal morphologies for various crystallisation conditions. SDSC proved a convenient and precise method for measurement of the apparent thermodynamic specific heat (reversing signal) HSPOM results showed that the crystallisation rates and sizes of spherulites were significantly reduced as crystallisation rate increased

Ohmic ion temperature and thermal diffusivity profiles from the JET neutron emission profile monitor

Energy Technology Data Exchange (ETDEWEB)

Esposito, B. (ENEA, Frascati (Italy). Centro Ricerche Energia); Marcus, F.B.; Conroy, S.; Jarvis, O.N.; Loughlin, M.J.; Sadler, G.; Belle, P. van (Commission of the European Communities, Abingdon (United Kingdom). JET Joint Undertaking); Adams, J.M.; Watkins, N. (AEA Industrial Technology, Harwell (United Kingdom))

1993-10-01

The JET neutron emission profile monitor was used to study ohmically heated deuterium discharges. The radial profile of the neutron emissivity is deduced from the line-integral data. The profiles of ion temperature, T[sub i], and ion thermal diffusivity, [chi][sub i], are derived under steady-state conditions. The ion thermal diffusivity is higher than, and its scaling with plasma current opposite to, that predicted by neoclassical theory. (author).

Ohmic ion temperature and thermal diffusivity profiles from the JET neutron emission profile monitor

International Nuclear Information System (INIS)

Esposito, B.

1993-01-01

The JET neutron emission profile monitor was used to study ohmically heated deuterium discharges. The radial profile of the neutron emissivity is deduced from the line-integral data. The profiles of ion temperature, T i , and ion thermal diffusivity, χ i , are derived under steady-state conditions. The ion thermal diffusivity is higher than, and its scaling with plasma current opposite to, that predicted by neoclassical theory. (author)

Preparation, melting behavior and thermal stability of poly(lactic acid)/poly(propylene carbonate) blends processed by vane extruder

Energy Technology Data Exchange (ETDEWEB)

Zou, Wei, E-mail: zw55624@163.com; Chen, Rongyuan; Zhang, Haichen; Qu, Jinping, E-mail: jpqu@scut.edu.cn [National Engineering Research Center of Novel Equipment for Polymer Processing, South China University of Technology, Guangzhou 510640 (China)

2016-03-09

Poly (lactic acid) (PLA)/Poly (propylene carbonate) (PPC) blends were prepared by vane extruder which is a type of novel polymer processing extruder based on elongation force field. Scanning electron microscope (SEM), differential scanning calorimetry (DSC) and thermogravimetric (TG) were used respectively to analyze the compatibility, the melting behavior and thermal stability properties of PLA/PPC blends affected by the different content of PPC. The results showed that with the increase of the PPC content, the glass transition temperature of PLA was reduced, and the glass transition temperature of PPC was increased, which indicated that PLA and PPC had partial compatibility. The cold crystallization temperature of PLA increased with the increase of the PPC content, which showed that PPC hindered the cold crystallization process of PLA. The addition of PPC had little impact on the melting process of PLA, and the melting temperature of PLA was almost kept the same value. Thermogravimetric analysis showed that the thermal stability of PPC was worse than that of PLA, the addition of PPC reduced the thermal stability of PLA.

Experimental study of simulant melt stream-water thermal interaction in pool and narrow geometries

International Nuclear Information System (INIS)

Narayanan, K.S.; Jasmin Sudha, A.; Murthy, S.S.; Rao, E.H.V.M.; Lydia, G.; Das, S.K.; Harvey, J.; Kannan, S.E.

2005-01-01

Full text of publication follows: Small scale experiments were carried out to investigate the thermal interaction characteristics of a few kilograms of Sn Pb, Bi and Zn as hot melt, in the film boiling region of water in an attempt to simulate a coherent fuel coolant interaction during a postulated severe accident in a nuclear reactor. Melt stream solidification and detached debris generation were studied with different melt superheat up to 200 deg. C, at different coolant temperatures of 30 deg. C, 50 deg. C, 70 deg. C, 90 deg. C, in pool geometry and in long narrow coolant column. The material was heated in an Alumina crucible and poured through a hot stainless steel funnel with a nozzle diameter of 7.7 mm, into the coolant. A stainless steel plate was used to collect the solidified mass after the interaction. Temperature monitoring was done in the coolant column close to the melt stream. The melt stream movement inside the coolant was imaged using a video camera at 25 fps. Measured melt stream entry velocity was around 1.5 m/sec. For low melt superheat and low coolant temperature, solidified porous tree like structure extended from the collector plate up to the melt release point. For water temperature of 70 deg. C, the solidified bed height at the center was found to decrease with increase in the melt superheat up to 150 deg. C. Fragmentation was found to occur when the melt superheat exceeded 200 deg. C. Particle size distribution was obtained for the fragmented debris. In 1D geometry, with 50 deg. C superheat, columnar solidification was observed with no fine debris. The paper gives the details of the results obtained in the experiments and highlights the role of Rayleigh-Taylor, Kelvin-Helmholtz instabilities and the melt physical properties on the fragmentation kinetics. (authors)

Temperature simulation of thermal plasma melting furnace for disposal of radioactive waste and preliminary research of vitrification formula

International Nuclear Information System (INIS)

Lin Peng; Lu Yonghong; Xiang Wenyuan; Chen Mingzhou; Liu Xiajie; Qin Yuxin

2013-01-01

Radioactive waste treatment techniques currently used in nuclear power plant increase the volume greatly and bring much pressure on final disposal; Thermal plasma treatment as a crucial technique to reduce the waste volume is introduced. How to improve the efficiency of the plasma energy is the limiting factor of concern. In this paper, the temperature field of thermal plasma melting furnace is simulated, the maximal temperature of fixed bed melting furnace is calculated (about 1445 ℃). According to the optional fire-resistant materials, the feasibility of furnace fabrication is discussed. Vitrification formulas for three typical radioactive wastes are tested with their feasibilities being analyzed then. Finally, the prospect of thermal plasma techniques of radioactive waste is discussed, and issues for future study are raised. (authors)

Thermal Stability of Zone Melting p-Type (Bi, Sb)2Te3 Ingots and Comparison with the Corresponding Powder Metallurgy Samples

Science.gov (United States)

Jiang, Chengpeng; Fan, Xi'an; Hu, Jie; Feng, Bo; Xiang, Qiusheng; Li, Guangqiang; Li, Yawei; He, Zhu

2018-04-01

During the past few decades, Bi2Te3-based alloys have been investigated extensively because of their promising application in the area of low temperature waste heat thermoelectric power generation. However, their thermal stability must be evaluated to explore the appropriate service temperature. In this work, the thermal stability of zone melting p-type (Bi, Sb)2Te3-based ingots was investigated under different annealing treatment conditions. The effect of service temperature on the thermoelectric properties and hardness of the samples was also discussed in detail. The results showed that the grain size, density, dimension size and mass remained nearly unchanged when the service temperature was below 523 K, which suggested that the geometry size of zone melting p-type (Bi, Sb)2Te3-based materials was stable below 523 K. The power factor and Vickers hardness of the ingots also changed little and maintained good thermal stability. Unfortunately, the thermal conductivity increased with increasing annealing temperature, which resulted in an obvious decrease of the zT value. In addition, the thermal stabilities of the zone melting p-type (Bi, Sb)2Te3-based materials and the corresponding powder metallurgy samples were also compared. All evidence implied that the thermal stabilities of the zone-melted (ZMed) p-type (Bi, Sb)2Te3 ingots in terms of crystal structure, geometry size, power factor (PF) and hardness were better than those of the corresponding powder metallurgy samples. However, their thermal stabilities in terms of zT values were similar under different annealing temperatures.

Thermally conductive, electrically insulating and melt-processable polystyrene/boron nitride nanocomposites prepared by in situ reversible addition fragmentation chain transfer polymerization

International Nuclear Information System (INIS)

Huang, Xingyi; Wang, Shen; Zhu, Ming; Yang, Ke; Jiang, Pingkai; Bando, Yoshio; Golberg, Dmitri; Zhi, Chunyi

2015-01-01

Thermally conductive and electrically insulating polymer/boron nitride (BN) nanocomposites are highly attractive for various applications in many thermal management fields. However, so far most of the preparation methods for polymer/BN nanocomposites have usually caused difficulties in the material post processing. Here, an in situ grafting approach is designed to fabricate thermally conductive, electrically insulating and post-melt processable polystyrene (PS)/BN nanosphere (BNNS) nanocomposites by initiating styrene (St) on the surface functionalized BNNSs via reversible addition fragmentation chain transfer polymerization. The nanocomposites exhibit significantly enhanced thermal conductivity. For example, at a St/BN feeding ratio of 5:1, an enhancement ratio of 1375% is achieved in comparison with pure PS. Moreover, the dielectric properties of the nanocomposites show a desirable weak dependence on frequency, and the dielectric loss tangent of the nanocomposites remains at a very low level. More importantly, the nanocomposites can be subjected to multiple melt processing to form different shapes. Our method can become a universal approach to prepare thermally conductive, electrically insulating and melt-processable polymer nanocomposites with diverse monomers and nanofillers. (paper)

Thermal Conductive Heat Transfer and Partial Melting of Volatiles in Icy Moons, Asteroids, and Kuiper Belt Objects (Invited)

Science.gov (United States)

Kargel, J. S.; Furfaro, R.

2013-12-01

Thermal gradients within conductive layers of icy satellite and asteroids depend partly on heat flow, which is related to the secular decay of radioactive isotopes, to heat released by chemical phase changes, by conversion of gravitational potential energy to heat during differentiation, tidal energy dissipation, and to release of heat stored from prior periods. Thermal gradients are also dependent on the thermal conductivity of materials, which in turn depends on their composition, crystallinity, porosity, crystal fabric anisotropy, and details of their mixture with other materials. Small impurities can produce lattice defects and changes in polymerization, and thereby have a huge influence on thermal conductivity, as can cage-inclusion (clathrate) compounds. Heat flow and thermal gradients can be affected by fluid phase advection of mass and heat (in oceans or sublimating upper crusts), by refraction related to heterogeneities of thermal conductivity due to lateral variations and composition or porosity. Thermal profiles depend also on the surface temperature controlled by albedo and climate, surface relief, and latitude, orbital obliquity and surface insolation, solid state greenhouses, and endogenic heating of the surface. The thermal state of icy moon interiors and thermal gradients can be limited at depth by fluid phase advection of heat (e.g., percolating meteoric methane or gas emission), by the latent heat of phase transitions (melting, solid-state transitions, and sublimation), by solid-state convective or diapiric heat transfer, and by foundering. Rapid burial of thick volatile deposits can also affect thermal gradients. For geologically inactive or simple icy objects, most of these controls on heat flow and thermal gradients are irrelevant, but for many other icy objects they can be important, in some cases causing large lateral and depth variations in thermal gradients, large variations in heat flow, and dynamically evolving thermal states. Many of

A porous flow approach to model thermal non-equilibrium applicable to melt migration

Science.gov (United States)

Schmeling, Harro; Marquart, Gabriele; Grebe, Michael

2018-01-01

We develop an approach for heat exchange between a fluid and a solid phase of a porous medium where the temperatures of the fluid and matrix are not in thermal equilibrium. The formulation considers moving of the fluid within a resting or deforming porous matrix in an Eulerian coordinate system. The approach can be applied, for example, to partially molten systems or to brine transport in porous rocks. We start from an existing theory for heat exchange where the energy conservation equations for the fluid and the solid phases are separated and coupled by a heat exchange term. This term is extended to account for the full history of heat exchange. It depends on the microscopic geometry of the fluid phase. For the case of solid containing hot, fluid-filled channels, we derive an expression based on a time-dependent Fourier approach for periodic half-waves. On the macroscopic scale, the temporal evolution of the heat exchange leads to a convolution integral along the flow path of the solid, which simplifies considerably in case of a resting matrix. The evolution of the temperature in both phases with time is derived by inserting the heat exchange term into the energy equations. We explore the effects of thermal non-equilibrium between fluid and solid by considering simple cases with sudden temperature differences between fluid and solid as initial or boundary conditions, and by varying the fluid velocity with respect to the resting porous solid. Our results agree well with an analytical solution for non-moving fluid and solid. The temperature difference between solid and fluid depends on the Peclet number based on the Darcy velocity. For Peclet numbers larger than 1, the temperature difference after one diffusion time reaches 5 per cent of \\tilde{T} or more (\\tilde{T} is a scaling temperature, e.g. the initial temperature difference). Thus, our results imply that thermal non-equilibrium can play an important role for melt migration through partially molten systems

Thermal interaction of core melt debris with the TMI-2 baffle, core-former, and lower head structures

International Nuclear Information System (INIS)

Cronenberg, A.W.; Tolman, E.L.

1987-09-01

Recent inspection of the TMI-2 core-former baffle walls (vertical), former plates (horizontal), and lower plenum has been conducted to assess potential damage to these structures. Video observations show evidence of localized melt failure of the baffle walls, whereas fiberoptics data indicate the presence of resolidified debris on the former plates. Lower plenum inspection also confirms the presence of 20 tons or more of core debris in the lower plenum. These data indicate massive core melt relocation and the potential for melt attack on vessel structural components. This report presents analyses aimed at developing an understanding of melt relocation behavior and damage progression to TMI-2 vessel components. Thermal analysis indicates melt-through of the baffle plates, but maintenance of structural integrity of the former plates and lower head. Differences in the damage of these structures is attributed largely to differences in contact time with melt debris and pressure of water. 29 refs., 17 figs., 9 tabs

The surface quasiliquid melt acceleration and the role of thermodynamic phase in the thermal decomposition of crystalline organic explosives

Energy Technology Data Exchange (ETDEWEB)

Henson, Bryan F [Los Alamos National Laboratory

2010-01-01

We show that melt acceleration in the thermal decomposition of crystalline organic solids is a manifestation of the surface quasiliquid phase. We derive a single universal rate law for melt acceleration that is a simple function of the metastable liquid activity below the melting point, and has a zero order term proportional to the quasiliquid thickness. We argue that the underlying mechanisms of this model will provide a molecular definition for the stability of the class of secondary explosives.

Basal melting driven by turbulent thermal convection

Science.gov (United States)

Rabbanipour Esfahani, Babak; Hirata, Silvia C.; Berti, Stefano; Calzavarini, Enrico

2018-05-01

Melting and, conversely, solidification processes in the presence of convection are key to many geophysical problems. An essential question related to these phenomena concerns the estimation of the (time-evolving) melting rate, which is tightly connected to the turbulent convective dynamics in the bulk of the melt fluid and the heat transfer at the liquid-solid interface. In this work, we consider a convective-melting model, constructed as a generalization of the Rayleigh-Bénard system, accounting for the basal melting of a solid. As the change of phase proceeds, a fluid layer grows at the heated bottom of the system and eventually reaches a turbulent convection state. By means of extensive lattice-Boltzmann numerical simulations employing an enthalpy formulation of the governing equations, we explore the model dynamics in two- and three-dimensional configurations. The focus of the analysis is on the scaling of global quantities like the heat flux and the kinetic energy with the Rayleigh number, as well as on the interface morphology and the effects of space dimensionality. Independently of dimensionality, we find that the convective-melting system behavior shares strong resemblances with that of the Rayleigh-Bénard one, and that the heat flux is only weakly enhanced with respect to that case. Such similarities are understood, at least to some extent, considering the resulting slow motion of the melting front (with respect to the turbulent fluid velocity fluctuations) and its generally little roughness (compared to the height of the fluid layer). Varying the Stefan number, accounting for the thermodynamical properties of the material, also seems to have only a mild effect, which implies the possibility of extrapolating results in numerically delicate low-Stefan setups from more convenient high-Stefan ones. Finally, we discuss the implications of our findings for the geophysically relevant problem of modeling Arctic ice melt ponds.

Role of modification and melt thermal treatment processes on the microstructure and tensile properties of Al–Si alloys

International Nuclear Information System (INIS)

Samuel, A.M.; Garza-Elizondo, G.H.; Doty, H.W.; Samuel, F.H.

2015-01-01

Highlights: • High tensile strength applying the melt thermal treatment process. • Enhanced ductility by changing the Si particle morphology. • Control of the dissolution and precipitation of Mg 2 Si phase. • Establishment of the fracture mechanisms of Al–Si–Mg alloys. - Abstract: The present study was performed on an Al–7%Si–0.35%Mg alloy (A356 alloy) with the primary objective of improving the alloy performance through modification of the microstructure. Ultimate tensile strength (UTS) can be improved by the addition of strontium (Sr), superheating or Sr modified melt thermal treatment. The melt thermal treatment process alone has no apparent influence on the UTS. Both Sr-modified and Sr-modified melt thermal treatment can help to improve the percentage elongation of A356 alloy castings. A higher percentage elongation can be reached at a higher cooling rate. The effect of solution heat treatment on the tensile properties of various A356.2 alloy castings can be summed up as follows: (i) the yield strength of the A356.2 castings is significantly improved after 8 h solution heat treatment due to the precipitation of Mg 2 Si, (ii) the yield strength remains more or less the same with further increase in solution treatment time to 80 h, and (iii) the UTS is greatly improved within the first 8 h of solution heat treatment and continues up to 80 h, where this improvement is attributed to Mg 2 Si precipitation, dissolution of silicon within the Al-matrix and change in the Si particle morphology (spheroidization). The ductility of the A356.2 alloys can also be considerably enhanced with solution heat treatment (e.g. from ∼6% in the non-modified casting in the as-cast condition to ∼10% after 80 h solution treatment)

The Melting Behavior and Thermal Stability of Green Poly(L-lactic acid) with N, N, N, N'-Tetra(benzoyl) Ethylene Diamine Tetraacetic Acid Dihydrazide

International Nuclear Information System (INIS)

Cai, Y.; Qiang Xu, Q.; Ren, L.; Zhao, L.

2015-01-01

The thermal properties of green poly(L-lactic acid) (PLLA) with N, N, N, N'-tetra(benzoyl) ethylene diamine tetraacetic acid dihydrazide (NA) at different conditions were investigated. The melting behavior of PLLA/NA sample after isothermal crystallization at 100 degree C showed that the low-temperature melting peak shifted to high temperature with increasing of crystallization time. However, the high-temperature melting peak did not show any change. Meantime, the melting enthalpy of cold crystallization was higher than that of hot crystallization, and the difference between cold crystallization and hot crystallization increased from 0.31 J/g to 0.89 J/g with increasing of crystallization time. Heating or cooling rate affected the melting behavior of PLLA, the low-temperature and high-temperature melting peak shifted to low temperature with increasing of rate, and the ratio of melting peak area between low-temperature melting peak and high-temperature melting peak decreased. Thermal stability of PLLA/NA indicated that PLLA/NA only exhibited one decomposition stage as decomposition of PLLA. (author)

Oxidation effect on steel corrosion and thermal loads during corium melt in-vessel retention

Energy Technology Data Exchange (ETDEWEB)

Granovsky, V.S.; Khabensky, V.B.; Krushinov, E.V.; Vitol, S.A.; Sulatsky, A.A.; Almjashev, V.I. [Alexandrov Scientific-Research Technology Institute (NITI), Sosnovy Bor (Russian Federation); Bechta, S.V. [KTH, Stockholm (Sweden); Gusarov, V.V. [SPb State Technology University (SPbGTU), St. Petersburg (Russian Federation); Barrachin, M. [Institut de Radioprotection et de Sûreté Nucléaire (IRSN), St Paul lez Durance (France); Bottomley, P.D., E-mail: paul.bottomley@ec.europa.eu [EC-Joint Research Centre, Institute for Transuranium Elements (ITU), Karlsruhe (Germany); Fischer, M. [AREVA GmbH, Erlangen (Germany); Piluso, P. [Commissariat à l’Energie Atomique et aux Energies Alternatives (CEA), Cadarache, St Paul lez Durance (France)

2014-10-15

Highlights: • The METCOR facility simulates vessel steel corrosion in contact with corium. • Steel corrosion rates in UO{sub 2+x}–ZrO{sub 2}–FeO{sub y} coria accelerate above 1050 K. • However corrosion rates can also be limited by melt O{sub 2} supply. • The impact of this on in-vessel retention (IVR) strategy is discussed. - Abstract: During a severe accident with core meltdown, the in-vessel molten core retention is challenged by the vessel steel ablation due to thermal and physicochemical interaction of melt with steel. In accidents with oxidizing atmosphere above the melt surface, a low melting point UO{sub 2+x}–ZrO{sub 2}–FeO{sub y} corium pool can form. In this case ablation of the RPV steel interacting with the molten corium is a corrosion process. Experiments carried out within the International Scientific and Technology Center's (ISTC) METCOR Project have shown that the corrosion rate can vary and depends on both surface temperature of the RPV steel and oxygen potential of the melt. If the oxygen potential is low, the corrosion rate is controlled by the solid phase diffusion of Fe ions in the corrosion layer. At high oxygen potential and steel surface layer temperature of 1050 °C and higher, the corrosion rate intensifies because of corrosion layer liquefaction and liquid phase diffusion of Fe ions. The paper analyzes conditions under which corrosion intensification occurs and can impact on in-vessel melt retention (IVR)

Computationally efficient thermal-mechanical modelling of selective laser melting

Science.gov (United States)

Yang, Yabin; Ayas, Can

2017-10-01

The Selective laser melting (SLM) is a powder based additive manufacturing (AM) method to produce high density metal parts with complex topology. However, part distortions and accompanying residual stresses deteriorates the mechanical reliability of SLM products. Modelling of the SLM process is anticipated to be instrumental for understanding and predicting the development of residual stress field during the build process. However, SLM process modelling requires determination of the heat transients within the part being built which is coupled to a mechanical boundary value problem to calculate displacement and residual stress fields. Thermal models associated with SLM are typically complex and computationally demanding. In this paper, we present a simple semi-analytical thermal-mechanical model, developed for SLM that represents the effect of laser scanning vectors with line heat sources. The temperature field within the part being build is attained by superposition of temperature field associated with line heat sources in a semi-infinite medium and a complimentary temperature field which accounts for the actual boundary conditions. An analytical solution of a line heat source in a semi-infinite medium is first described followed by the numerical procedure used for finding the complimentary temperature field. This analytical description of the line heat sources is able to capture the steep temperature gradients in the vicinity of the laser spot which is typically tens of micrometers. In turn, semi-analytical thermal model allows for having a relatively coarse discretisation of the complimentary temperature field. The temperature history determined is used to calculate the thermal strain induced on the SLM part. Finally, a mechanical model governed by elastic-plastic constitutive rule having isotropic hardening is used to predict the residual stresses.

Thermal dynamic behavior during selective laser melting of K418 superalloy: numerical simulation and experimental verification

Science.gov (United States)

Chen, Zhen; Xiang, Yu; Wei, Zhengying; Wei, Pei; Lu, Bingheng; Zhang, Lijuan; Du, Jun

2018-04-01

During selective laser melting (SLM) of K418 powder, the influence of the process parameters, such as laser power P and scanning speed v, on the dynamic thermal behavior and morphology of the melted tracks was investigated numerically. A 3D finite difference method was established to predict the dynamic thermal behavior and flow mechanism of K418 powder irradiated by a Gaussian laser beam. A three-dimensional randomly packed powder bed composed of spherical particles was established by discrete element method. The powder particle information including particle size distribution and packing density were taken into account. The volume shrinkage and temperature-dependent thermophysical parameters such as thermal conductivity, specific heat, and other physical properties were also considered. The volume of fluid method was applied to reconstruct the free surface of the molten pool during SLM. The geometrical features, continuity boundaries, and irregularities of the molten pool were proved to be largely determined by the laser energy density. The numerical results are in good agreement with the experiments, which prove to be reasonable and effective. The results provide us some in-depth insight into the complex physical behavior during SLM and guide the optimization of process parameters.

Massively parallel digital high resolution melt for rapid and absolutely quantitative sequence profiling

Science.gov (United States)

Velez, Daniel Ortiz; Mack, Hannah; Jupe, Julietta; Hawker, Sinead; Kulkarni, Ninad; Hedayatnia, Behnam; Zhang, Yang; Lawrence, Shelley; Fraley, Stephanie I.

2017-02-01

In clinical diagnostics and pathogen detection, profiling of complex samples for low-level genotypes represents a significant challenge. Advances in speed, sensitivity, and extent of multiplexing of molecular pathogen detection assays are needed to improve patient care. We report the development of an integrated platform enabling the identification of bacterial pathogen DNA sequences in complex samples in less than four hours. The system incorporates a microfluidic chip and instrumentation to accomplish universal PCR amplification, High Resolution Melting (HRM), and machine learning within 20,000 picoliter scale reactions, simultaneously. Clinically relevant concentrations of bacterial DNA molecules are separated by digitization across 20,000 reactions and amplified with universal primers targeting the bacterial 16S gene. Amplification is followed by HRM sequence fingerprinting in all reactions, simultaneously. The resulting bacteria-specific melt curves are identified by Support Vector Machine learning, and individual pathogen loads are quantified. The platform reduces reaction volumes by 99.995% and achieves a greater than 200-fold increase in dynamic range of detection compared to traditional PCR HRM approaches. Type I and II error rates are reduced by 99% and 100% respectively, compared to intercalating dye-based digital PCR (dPCR) methods. This technology could impact a number of quantitative profiling applications, especially infectious disease diagnostics.

Laser melting of groove defect repair on high thermal conductivity steel (HTCS-150)

Science.gov (United States)

Norhafzan, B.; Aqida, S. N.; Fazliana, F.; Reza, M. S.; Ismail, I.; Khairil, C. M.

2018-02-01

This paper presents laser melting repair of groove defect on HTCS-150 surface using Nd:YAG laser system. Laser melting process was conducted using JK300HPS Nd:YAG twin lamp laser source with 1064 nm wavelength and pulsed mode. The parameters are pulse repetition frequency (PRF) that is set from 70 to 100 Hz, average power ( P A) of 50-70 W, and laser spot size of 0.7 mm. HTCS-150 samples were prepared with groove dimension of 0.3 mm width and depths of 0.5 mm using EDM wire cut. Groove defect repaired using laser melting process on groove surface area with various parameters' process. The melted surface within the groove was characterized for subsurface hardness profile, roughness, phase identification, chemical composition, and metallographic study. The roughness analysis indicates high PRF at large spot size caused high surface roughness and low surface hardness. Grain refinement of repaired layer was analyzed within the groove as a result of rapid heating and cooling. The hardness properties of modified HTCS inside the groove and the bulk surface increased two times from as received HTCS due to grain refinement which is in agreement with Hall-Petch equation. These findings are significant to parameter design of die repair for optimum surface integrity and potential for repairing crack depth and width of less than 0.5 and 0.3 mm, respectively.

Mixed oxide thermal behaviour at BOL: COMETHE III-J models and impact on power-to-melt

International Nuclear Information System (INIS)

Vliet, J. van

1979-01-01

The mixed oxide thermal behaviour at beginning of life is very important because it can impose a limitation to the fuel pin peak power, and therefore to the reactor thermal output. The relevant physical processes leading to fuel restructuring are modelled in COMETHE III-J in a kinetic way. This ensures that the temperature and power history are properly taken into account. These models are described and their impact on the calculated power to melt early in life is analysed. (author)

High through-plane thermal conduction of graphene nanoflake filled polymer composites melt-processed in an L-shape kinked tube.

Science.gov (United States)

Jung, Haejong; Yu, Seunggun; Bae, Nam-Seok; Cho, Suk Man; Kim, Richard Hahnkee; Cho, Sung Hwan; Hwang, Ihn; Jeong, Beomjin; Ryu, Ji Su; Hwang, Junyeon; Hong, Soon Man; Koo, Chong Min; Park, Cheolmin

2015-07-22

Design of materials to be heat-conductive in a preferred direction is a crucial issue for efficient heat dissipation in systems using stacked devices. Here, we demonstrate a facile route to fabricate polymer composites with directional thermal conduction. Our method is based on control of the orientation of fillers with anisotropic heat conduction. Melt-compression of solution-cast poly(vinylidene fluoride) (PVDF) and graphene nanoflake (GNF) films in an L-shape kinked tube yielded a lightweight polymer composite with the surface normal of GNF preferentially aligned perpendicular to the melt-flow direction, giving rise to a directional thermal conductivity of approximately 10 W/mK at 25 vol % with an anisotropic thermal conduction ratio greater than six. The high directional thermal conduction was attributed to the two-dimensional planar shape of GNFs readily adaptable to the molten polymer flow, compared with highly entangled carbon nanotubes and three-dimensional graphite fillers. Furthermore, our composite with its density of approximately 1.5 g/cm(3) was mechanically stable, and its thermal performance was successfully preserved above 100 °C even after multiple heating and cooling cycles. The results indicate that the methodology using an L-shape kinked tube is a new way to achieve polymer composites with highly anisotropic thermal conduction.

Supplementary Microstructural Features Induced During Laser Surface Melting of Thermally Sprayed Inconel 625 Coatings

Science.gov (United States)

Ahmed, Nauman; Voisey, K. T.; McCartney, D. G.

2014-02-01

Laser surface melting of thermally sprayed coatings has the potential to enhance their corrosion properties by incorporating favorable microstructural changes. Besides homogenizing the as-sprayed structure, laser melting may induce certain microstructural modifications (i.e., supplementary features) in addition to those that directly improve the corrosion performance. Such features, being a direct result of the laser treatment process, are described in this paper which is part of a broader study in which high velocity oxy-fuel sprayed Inconel 625 coatings on mild-steel substrates were treated with a diode laser and the modified microstructure characterized using optical and scanning electron microscopy and x-ray diffraction. The laser treated coating features several different zones, including a region with a microstructure in which there is a continuous columnar dendritic structure through a network of retained oxide stringers.

Thermal behavior and densification mechanism during selective laser melting of copper matrix composites: Simulation and experiments

International Nuclear Information System (INIS)

Dai, Donghua; Gu, Dongdong

2014-01-01

Highlights: • Thermal behavior and densification activity during SLM of composites are simulated. • Temperature distributions and melt pool dimensions during SLM are disclosed. • Motion behaviors of gaseous bubbles in laser induced melt pool are elucidated. • Simulation results show good agreement with the obtained experimental results. - Abstract: Simulation of temperature distribution and densification process of selective laser melting (SLM) WC/Cu composite powder system has been performed, using a finite volume method (FVM). The transition from powder to solid, the surface tension induced by temperature gradient, and the movement of laser beam power with a Gaussian energy distribution are taken into account in the physical model. The effect of the applied linear energy density (LED) on the temperature distribution, melt pool dimensions, behaviors of gaseous bubbles and resultant densification activity has been investigated. It shows that the temperature distribution is asymmetric with respect to the laser beam scanning area. The center of the melt pool does not locate at the center of the laser beam but slightly shifts towards the side of the decreasing X-axis. The dimensions of the melt pool are in sizes of hundreds of micrometers and increase with the applied LED. For an optimized LED of 17.5 kJ/m, an enhanced efficiency of gas removal from the melt pool is realized, and the maximum relative density of laser processed powder reaches 96%. As the applied LED surpasses 20 kJ/m, Marangoni flow tends to retain the entrapped gas bubbles. The flow pattern has a tendency to deposit the gas bubbles at the melt pool bottom or to agglomerate gas bubbles by the rotating flow in the melt pool, resulting in a higher porosity in laser processed powder. The relative density and corresponding pore size and morphology are experimentally acquired, which are in a good agreement with the results predicted by simulation

Experimental verification of agreement between thermal and real time visual melt-solid interface positions in vertical Bridgman grown germanium

Science.gov (United States)

Barber, P. G.; Fripp, A. L.; Debnam, W. J.; Woodell, G.; Berry, R. F.; Simchick, R. T.

1996-03-01

Measurements of the liquid-solid interface position during crystal growth were made by observing the discontinuity of the temperature gradient with movable thermocouples in a centerline, quartz capillary placed inside a sealed quartz ampoule of germanium in a vertical Bridgman furnace. Simultaneously, in situ, real time visual observations, using X-ray imaging technology, determined the position of the melt-solid interface. The radiographically detected interface position was several millimeters from the thermal interface position and the direction of displacement depended upon the direction of thermocouple insertion. Minimization of this spurious heat flow was achieved by using an unclad thermocouple that had each of its two wire leads entering the capillary from different ends of the furnace. Using this configuration the visual interface coincided with the thermal interface. Such observations show the utility of using in situ, real time visualization to record the melt-solid interface shape and position during crystal growth; and they suggest improvements in furnace and ampoule designs for use in high thermal gradients.

Heat transfer characteristics of thermal energy storage for PCM (phase change material) melting in horizontal tube: Numerical and experimental investigations

International Nuclear Information System (INIS)

Aadmi, Moussa; Karkri, Mustapha; El Hammouti, Mimoun

2015-01-01

This paper focuses on the experimental and numerical study of the storage and release of thermal heat during melting and solidification of PCM (phase change material). Heat transfer enhancement techniques such as the use of conductors like graphite and metal tubes have been proven to be effective. The material used for thermal energy storage systems is a composite based on epoxy resin loaded with metal hollow tubes filled with paraffin wax. Differential Scanning Calorimetry has been used for measurement of melting enthalpy and determination of heat capacity. The thermophysical properties of the prepared composite phase change material have been characterized using a new transient hot plate apparatus. The results have shown that most important thermal properties of these composites at the solid and liquid states are the ‘‘apparent’’ thermal conductivity, the heat storage capacity and the latent heat of fusion. These experimental results have been simulated using numerical Comsol ® Multiphysics 4.3 based models with success. The results of the experimental investigation are compared favorably with the numerical results and thus serve to validate the numerical approach. - Highlights: • Phase change materials based on cylindrical used as new energy storage system. • Thermophysical properties and the melting process of composites were investigated. • All experimental results have been simulated using Comsol ® Multiphysiques. • The ability to store and release the thermal energy were investigated. • Good improvement in the thermal conductivity of composites

Point, surface and volumetric heat sources in the thermal modelling of selective laser melting

Science.gov (United States)

Yang, Yabin; Ayas, Can

2017-10-01

Selective laser melting (SLM) is a powder based additive manufacturing technique suitable for producing high precision metal parts. However, distortions and residual stresses within products arise during SLM because of the high temperature gradients created by the laser heating. Residual stresses limit the load resistance of the product and may even lead to fracture during the built process. It is therefore of paramount importance to predict the level of part distortion and residual stress as a function of SLM process parameters which requires a reliable thermal modelling of the SLM process. Consequently, a key question arises which is how to describe the laser source appropriately. Reasonable simplification of the laser representation is crucial for the computational efficiency of the thermal model of the SLM process. In this paper, first a semi-analytical thermal modelling approach is described. Subsequently, the laser heating is modelled using point, surface and volumetric sources, in order to compare the influence of different laser source geometries on the thermal history prediction of the thermal model. The present work provides guidelines on appropriate representation of the laser source in the thermal modelling of the SLM process.

Empirical Retrieval of Surface Melt Magnitude from Coupled MODIS Optical and Thermal Measurements over the Greenland Ice Sheet during the 2001 Ablation Season.

Science.gov (United States)

Lampkin, Derrick; Peng, Rui

2008-08-22

Accelerated ice flow near the equilibrium line of west-central Greenland Ice Sheet (GIS) has been attributed to an increase in infiltrated surface melt water as a response to climate warming. The assessment of surface melting events must be more than the detection of melt onset or extent. Retrieval of surface melt magnitude is necessary to improve understanding of ice sheet flow and surface melt coupling. In this paper, we report on a new technique to quantify the magnitude of surface melt. Cloud-free dates of June 10, July 5, 7, 9, and 11, 2001 Moderate Resolution Imaging Spectroradiometer (MODIS) daily reflectance Band 5 (1.230-1.250μm) and surface temperature images rescaled to 1km over western Greenland were used in the retrieval algorithm. An optical-thermal feature space partitioned as a function of melt magnitude was derived using a one-dimensional thermal snowmelt model (SNTHERM89). SNTHERM89 was forced by hourly meteorological data from the Greenland Climate Network (GC-Net) at reference sites spanning dry snow, percolation, and wet snow zones in the Jakobshavn drainage basin in western GIS. Melt magnitude or effective melt (E-melt) was derived for satellite composite periods covering May, June, and July displaying low fractions (0-1%) at elevations greater than 2500m and fractions at or greater than 15% at elevations lower than 1000m assessed for only the upper 5 cm of the snow surface. Validation of E-melt involved comparison of intensity to dry and wet zones determined from QSCAT backscatter. Higher intensities (> 8%) were distributed in wet snow zones, while lower intensities were grouped in dry zones at a first order accuracy of ~ ±2%.

Study of mechanical, rheological and thermal properties of nanocomposite HMSPP (high melt strength polypropylene) with Brazilian bentonite

International Nuclear Information System (INIS)

Fermino, Danilo Marin

2011-01-01

This work concerns to the study of the mechanical, thermal and rheological behavior of the nano composite HMSPP - Polypropylene High Melt Strength (obtained at a dose of 12.5 kGy) and a bentonite clay Brazilian Paraiba, known as 'Chocolate' in concentrations of 5 and 10% by weight, comparison of to one American Clay, Cloisite 20A nanocomposite was done. Agent compatibilizer polypropylene-graft, known as maleic anhydride (PP-g-AM) was addict 3% concentration thought technique melt intercalation using a twin-screw extruder and the specimens were prepared by injection process. The mechanical behavior was evaluated by strength, flexural strength and impact tests. The thermal behavior was evaluated by the techniques of differential scanning calorimetry (DSC) and thermogravimetry (TGM). The rheological behavior was evaluated in rheometer. The morphology of the nanocomposites was studied by the technique of scanning electron microscopy (SEM). The organophilic bentonite and the nanocomposites were characterized by X-ray diffraction (XRD) and infrared (FTIR). (author)

Potential for fuel melting and cladding thermal failure during a PCM event in LWRs

International Nuclear Information System (INIS)

El-Genk, M.S.; Croucher, D.W.

1979-01-01

The primary concern in nuclear reactor safety is to ensure that no conceivable accident, whether initiated by a failure of the reactor system or by incorrect operation, will lead to a dangerous release of radiation to the environment. A number of hypothesized off-normal power or cooling conditions, generally termed as power-cooling-mismatch (PCM) accidents, are considered in the safety analysis of light water reactors (LWRs). During a PCM accident, film boiling may occur at the cladding surface and cause a rapid temperature increase in the fuel and the cladding, perhaps producing embrittlement of the zircaloy cladding by oxidation. Molten fuel may be produced at the center of the pellets, extrude radially through open cracks in the outer, unmelted portion of the pellet and relocate in the fuel-cladding gap. If the amount of extruded molten fuel is sufficient to establish contact with the cladding, which is at a high temperature during film boiling, the zircaloy cladding may melt. The present work assesses the potential for central fuel melting and thermal failure of the zircaloy cladding due to melting upon being contacted by extruded molten UO 2 -fuel during a PCM event

Formation of D- and I-shaped geochemical profiles in saucer-shaped sills due to post- emplacement magma flow induced by thermal stresses

Science.gov (United States)

Aarnes, I.; Podladchikov, Y. Y.; Neumann, E.

2007-12-01

There are still unresolved problems in the processes of emplacement and crystallization of saucer shaped sill intrusions. We use geochemistry and numerical modelling in order to constrain identify processes in mafic sill intrusions. Profiles sampled through through a saucer-shaped sill complex in the Karoo igneous province, South Africa show a variety of geochemical variations. Some variations are observed repeatedly, i.e. the D- and I-shaped profiles. D-shaped profiles are recognized by having the least evolved composition in the center (high Mg#) with more evolved composition at the upper and lower margins (low Mg#), resulting in a D-shaped Mg# profile. I- shaped profiles are recognized by having no variation in the Mg# through the profile. The formation mechanism of D-shaped profiles is enigmatic, as classical fractional crystallization theory predicts C-shapes to occur. The least evolved composition will be at the margins where crystallization initiates, and with continued cooling and crystallization the center will be progressively more evolved. Hence, we need another formation mechanism. The most common explanation for D-shaped profiles is a movement of early formed phenocrysts towards the center due to flow segregation. However, petrographical evidences from a D-shaped profile in this study show no phenocryst assemblage in the center, and the modal composition is homogeneous through the profile. We propose that differentiation is caused by a melt flow from the central parts of the sill towards the margins driven by underpressure anomalies at the margins. The underpressures develop because of strong cooling gradients at the margins, assuming no volume change due to a rigid crystal network. The less compatible elements associated with the melt phase will be transported into the margins by advection, resulting in a more evolved total system composition from a higher total melt percentage. The central parts will progressively be depleted in the less compatible

Effects of surface shape on the geometry and surface topography of the melt pool in low-power density laser melting

KAUST Repository

Kim, Youngdeuk; Kim, Wooseung

2011-01-01

The quantitative correlations between workpiece volume and melt pool geometry, as well as the flow and thermal features of the melt pool are established. Thermocapillary convections in melt pool with a deformable free surface are investigated

Can Nano-Particle Melt below the Melting Temperature of Its Free Surface Partner?

International Nuclear Information System (INIS)

Sui Xiao-Hong; Qin Shao-Jing; Wang Zong-Guo; Kang Kai; Wang Chui-Lin

2015-01-01

The phonon thermal contribution to the melting temperature of nano-particles is inspected. The discrete summation of phonon states and its corresponding integration form as an approximation for a nano-particle or for a bulk system have been analyzed. The discrete phonon energy levels of pure size effect and the wave-vector shifts of boundary conditions are investigated in detail. Unlike in macroscopic thermodynamics, the integration volume of zero-mode of phonon for a nano-particle is not zero, and it plays an important role in pure size effect and boundary condition effect. We find that a nano-particle will have a rising melting temperature due to purely finite size effect; a lower melting temperature bound exists for a nano-particle in various environments, and the melting temperature of a nano-particle with free boundary condition reaches this lower bound. We suggest an easy procedure to estimation the melting temperature, in which the zero-mode contribution will be excluded, and only several bulk quantities will be used as input. We would like to emphasize that the quantum effect of discrete energy levels in nano-particles, which is not present in early thermodynamic studies on finite size corrections to melting temperature in small systems, should be included in future researches. (condensed matter: structural, mechanical, and thermal properties)

The thermal expansion of gold: point defect concentrations and pre-melting in a face-centred cubic metal.

Science.gov (United States)

Pamato, Martha G; Wood, Ian G; Dobson, David P; Hunt, Simon A; Vočadlo, Lidunka

2018-04-01

On the basis of ab initio computer simulations, pre-melting phenomena have been suggested to occur in the elastic properties of hexagonal close-packed iron under the conditions of the Earth's inner core just before melting. The extent to which these pre-melting effects might also occur in the physical properties of face-centred cubic metals has been investigated here under more experimentally accessible conditions for gold, allowing for comparison with future computer simulations of this material. The thermal expansion of gold has been determined by X-ray powder diffraction from 40 K up to the melting point (1337 K). For the entire temperature range investigated, the unit-cell volume can be represented in the following way: a second-order Grüneisen approximation to the zero-pressure volumetric equation of state, with the internal energy calculated via a Debye model, is used to represent the thermal expansion of the 'perfect crystal'. Gold shows a nonlinear increase in thermal expansion that departs from this Grüneisen-Debye model prior to melting, which is probably a result of the generation of point defects over a large range of temperatures, beginning at T / T m > 0.75 (a similar homologous T to where softening has been observed in the elastic moduli of Au). Therefore, the thermodynamic theory of point defects was used to include the additional volume of the vacancies at high temperatures ('real crystal'), resulting in the following fitted parameters: Q = ( V 0 K 0 )/γ = 4.04 (1) × 10 -18  J, V 0 = 67.1671 (3) Å 3 , b = ( K 0 ' - 1)/2 = 3.84 (9), θ D = 182 (2) K, ( v f /Ω)exp( s f / k B ) = 1.8 (23) and h f = 0.9 (2) eV, where V 0 is the unit-cell volume at 0 K, K 0 and K 0 ' are the isothermal incompressibility and its first derivative with respect to pressure (evaluated at zero pressure), γ is a Grüneisen parameter, θ D is the Debye temperature, v f , h f and s f are the vacancy formation volume, enthalpy and entropy

Thermal Profile of the Lunar Interior Constrained by Revised Estimates of Concentrations of Heat Producing Elements

Science.gov (United States)

Fuqua-Haviland, H.; Panovska, S.; Mallik, A.; Bremner, P. M.; McDonough, W. F.

2017-12-01

Constraining the heat producing element (HPE) concentrations of the Moon is important for understanding the thermal state of the interior. The lunar HPE budget is debated to be suprachondritic [1] to chondritic [2]. The Moon is differentiated, thus, each reservoir has a distinct HPE signature complicating this effort. The thermal profile of the lunar interior has been constructed using HPE concentrations of an ordinary chondrite (U = 0.0068 ppm; Th = 0.025 ppm; K = 17 ppm) which yields a conservative low estimate [2, 3, 4]. A later study estimated the bulk lunar mantle HPE concentrations (U = 0.039 ppm; Th = 0.15 ppm; K = 212 ppm) based on measurements of Apollo pyroclastic glasses [5] assuming that these glasses represent the least fractionated, near-primary lunar mantle melts, hence, are the best proxies for capturing mantle composition. In this study, we independently validate the revised estimate by using HPE concentrations [5] to construct a conductive lunar thermal profile, or selenotherm. We compare our conductive profile to the range of valid temperatures. We demonstrate the HPE concentrations reported by [5], when used in a simple 1D spherical thermal conduction equation, yield an impossibly hot mantle with temperatures in excess of 4,000 K (Fig 1). This confirms their revised estimate is not representative of the bulk lunar mantle, and perhaps only representative of a locally enriched mantle domain. We believe that their Low-Ti avg. source estimate (Th = 0.055 ppm, Th/U=4; K/U=1700), with the least KREEP assimilation is the closest representation of the bulk lunar mantle, producing 3E-12 W/kg of heat. This estimate is close to that of the Earth (5E-12 W/kg), indicating that the bulk Earth and lunar mantles are similar in their HPE constituents. We have used the lunar mantle heat production, in conjunction with HPE estimates of the Fe-Ti-rich cumulates (high Ti-source estimate from [5]) and measurements of crustal ferroan anorthite [6], to capture the

Heat transfer enhancement in triplex-tube latent thermal energy storage system with selected arrangements of fins

Science.gov (United States)

Zhao, Liang; Xing, Yuming; Liu, Xin; Rui, Zhoufeng

2018-01-01

The use of thermal energy storage systems can effectively reduce energy consumption and improve the system performance. One of the promising ways for thermal energy storage system is application of phase change materials (PCMs). In this study, a two-dimensional numerical model is presented to investigate the heat transfer enhancement during the melting/solidification process in a triplex tube heat exchanger (TTHX) by using fluent software. The thermal conduction and natural convection are all taken into account in the simulation of the melting/solidification process. As the volume fraction of fin is kept to be a constant, the influence of proposed fin arrangement on temporal profile of liquid fraction over the melting process is studied and reported. By rotating the unit with different angle, the simulation shows that the melting time varies a little, which means that the installation error can be reduced by the selected fin arrangement. The proposed fin arrangement also can effectively reduce time of the solidification of the PCM by investigating the solidification process. To summarize, this work presents a shape optimization for the improvement of the thermal energy storage system by considering both thermal energy charging and discharging process.

Hot melt extrusion versus spray drying: hot melt extrusion degrades albendazole.

Science.gov (United States)

Hengsawas Surasarang, Soraya; Keen, Justin M; Huang, Siyuan; Zhang, Feng; McGinity, James W; Williams, Robert O

2017-05-01

The purpose of this study was to enhance the dissolution properties of albendazole (ABZ) by the use of amorphous solid dispersions. Phase diagrams of ABZ-polymer binary mixtures generated from Flory-Huggins theory were used to assess miscibility and processability. Forced degradation studies showed that ABZ degraded upon exposure to hydrogen peroxide and 1 N NaOH at 80 °C for 5 min, and the degradants were albendazole sulfoxide (ABZSX), and ABZ impurity A, respectively. ABZ was chemically stable following exposure to 1 N HCl at 80 °C for one hour. Thermal degradation profiles show that ABZ, with and without Kollidon ® VA 64, degraded at 180 °C and 140 °C, respectively, which indicated that ABZ could likely be processed by thermal processing. Following hot melt extrusion, ABZ degraded up to 97.4%, while the amorphous ABZ solid dispersion was successfully prepared by spray drying. Spray-dried ABZ formulations using various types of acids (methanesulfonic acid, sulfuric acid and hydrochloric acid) and polymers (Kollidon ® VA 64, Soluplus ® and Eudragit ® E PO) were studied. The spray-dried ABZ with methanesulfonic acid and Kollidon ® VA 64 substantially improved non-sink dissolution in acidic media as compared to bulk ABZ (8-fold), physical mixture of ABZ:Kollidon ® VA 64 (5.6-fold) and ABZ mesylate salt (1.6-fold). No degradation was observed in the spray-dried product for up to six months and less than 5% after one-year storage. In conclusion, amorphous ABZ solid dispersions in combination with an acid and polymer can be prepared by spray drying to enhance dissolution and shelf-stability, whereas those made by melt extrusion are degraded.

Computational Simulation of Thermal and Spattering Phenomena and Microstructure in Selective Laser Melting of Inconel 625

Science.gov (United States)

Özel, Tuğrul; Arısoy, Yiğit M.; Criales, Luis E.

Computational modelling of Laser Powder Bed Fusion (L-PBF) processes such as Selective laser Melting (SLM) can reveal information that is hard to obtain or unobtainable by in-situ experimental measurements. A 3D thermal field that is not visible by the thermal camera can be obtained by solving the 3D heat transfer problem. Furthermore, microstructural modelling can be used to predict the quality and mechanical properties of the product. In this paper, a nonlinear 3D Finite Element Method based computational code is developed to simulate the SLM process with different process parameters such as laser power and scan velocity. The code is further improved by utilizing an in-situ thermal camera recording to predict spattering which is in turn included as a stochastic heat loss. Then, thermal gradients extracted from the simulations applied to predict growth directions in the resulting microstructure.

Numerical study of entropy generation and melting heat transfer on MHD generalised non-Newtonian fluid (GNF): Application to optimal energy

Science.gov (United States)

Iqbal, Z.; Mehmood, Zaffar; Ahmad, Bilal

2018-05-01

This paper concerns an application to optimal energy by incorporating thermal equilibrium on MHD-generalised non-Newtonian fluid model with melting heat effect. Highly nonlinear system of partial differential equations is simplified to a nonlinear system using boundary layer approach and similarity transformations. Numerical solutions of velocity and temperature profile are obtained by using shooting method. The contribution of entropy generation is appraised on thermal and fluid velocities. Physical features of relevant parameters have been discussed by plotting graphs and tables. Some noteworthy findings are: Prandtl number, power law index and Weissenberg number contribute in lowering mass boundary layer thickness and entropy effect and enlarging thermal boundary layer thickness. However, an increasing mass boundary layer effect is only due to melting heat parameter. Moreover, thermal boundary layers have same trend for all parameters, i.e., temperature enhances with increase in values of significant parameters. Similarly, Hartman and Weissenberg numbers enhance Bejan number.

Thermal conductivity profile determination in proton-irradiated ZrC by spatial and frequency scanning thermal wave methods

International Nuclear Information System (INIS)

Jensen, C.; Chirtoc, M.; Horny, N.; Antoniow, J. S.; Pron, H.; Ban, H.

2013-01-01

Using complementary thermal wave methods, the irradiation damaged region of zirconium carbide (ZrC) is characterized by quantifiably profiling the thermophysical property degradation. The ZrC sample was irradiated by a 2.6 MeV proton beam at 600 °C to a dose of 1.75 displacements per atom. Spatial scanning techniques including scanning thermal microscopy (SThM), lock-in infrared thermography (lock-in IRT), and photothermal radiometry (PTR) were used to directly map the in-depth profile of thermal conductivity on a cross section of the ZrC sample. The advantages and limitations of each system are discussed and compared, finding consistent results from all techniques. SThM provides the best resolution finding a very uniform thermal conductivity envelope in the damaged region measuring ∼52 ± 2 μm deep. Frequency-based scanning PTR provides quantification of the thermal parameters of the sample using the SThM measured profile to provide validation of a heating model. Measured irradiated and virgin thermal conductivities are found to be 11.9 ± 0.5 W m −1 K −1 and 26.7 ±1 W m −1 K −1 , respectively. A thermal resistance evidenced in the frequency spectra of the PTR results was calculated to be (1.58 ± 0.1) × 10 −6 m 2 K W −1 . The measured thermal conductivity values compare well with the thermal conductivity extracted from the SThM calibrated signal and the spatially scanned PTR. Combined spatial and frequency scanning techniques are shown to provide a valuable, complementary combination for thermal property characterization of proton-irradiated ZrC. Such methodology could be useful for other studies of ion-irradiated materials

UNCONSTRAINED MELTING AND SOLIDIFICATION INSIDE ...

African Journals Online (AJOL)

2015-09-01

Sep 1, 2015 ... There is a large number of experimental and numerical works on melting and solidification of PCM[6-10], and also its usage as thermal management in building [11-14], electronic devices [15-16] and solar energy. [17-20].Most investigated geometries in melting and freezing process are sphere (spherical.

Nanostructure and thermal properties of melt compounded PE/clay nanocomposites filled with an organosilylated montmorillonite

Energy Technology Data Exchange (ETDEWEB)

Scarfato, Paola, E-mail: pscarfato@unisa.it [Department of Industrial Engineering, University of Salerno Via Giovanni Paolo II 132 – 84084 Fisciano (Italy); BAM - Federal Institute for Materials Research and Testing, 7.5 Technical Properties of Polymeric Materials, Unter den Eichen 87 - 12205 Berlin (Germany); Incarnato, Loredana; Di Maio, Luciano [Department of Industrial Engineering, University of Salerno Via Giovanni Paolo II 132 – 84084 Fisciano (Italy); Dittrich, Bettina; Niebergall, Ute; Böhning, Martin; Schartel, Bernhard [BAM - Federal Institute for Materials Research and Testing, 7.5 Technical Properties of Polymeric Materials, Unter den Eichen 87 - 12205 Berlin (Germany)

2015-12-17

In this work we report on the functionalization of a natural sodium montmorillonite (MMT) with (3-glycidyloxypropyl)trimethoxysilane by a silylation procedure and on its use as nanofiller in melt compounding of polyethylene nanocomposites. The obtained organosilylated clay showed higher interlayer spacing than the original MMT and higher thermal stability with respect to most of commercial organoclays modified with alkylammonium salts. Its addition (at 5wt%) to two different polyethylene matrices (a low density polyethylene, LDPE, and a high density polyethylene, HDPE), processed in a pilot-scale twin-screw extruder, allowed to produce hybrids with nanoscale dispersion of the filler, as demonstrated by X-ray diffraction. Thermogravimetric and differential scanning thermal analyses point out that the obtained nanocomposites do not show noticeable changes in the thermal behavior of both LDPE and HDPE, even if a slight reduction in the overall bulk crystallinity was observed in presence of the nanofillers.

Nanostructure and thermal properties of melt compounded PE/clay nanocomposites filled with an organosilylated montmorillonite

International Nuclear Information System (INIS)

Scarfato, Paola; Incarnato, Loredana; Di Maio, Luciano; Dittrich, Bettina; Niebergall, Ute; Böhning, Martin; Schartel, Bernhard

2015-01-01

In this work we report on the functionalization of a natural sodium montmorillonite (MMT) with (3-glycidyloxypropyl)trimethoxysilane by a silylation procedure and on its use as nanofiller in melt compounding of polyethylene nanocomposites. The obtained organosilylated clay showed higher interlayer spacing than the original MMT and higher thermal stability with respect to most of commercial organoclays modified with alkylammonium salts. Its addition (at 5wt%) to two different polyethylene matrices (a low density polyethylene, LDPE, and a high density polyethylene, HDPE), processed in a pilot-scale twin-screw extruder, allowed to produce hybrids with nanoscale dispersion of the filler, as demonstrated by X-ray diffraction. Thermogravimetric and differential scanning thermal analyses point out that the obtained nanocomposites do not show noticeable changes in the thermal behavior of both LDPE and HDPE, even if a slight reduction in the overall bulk crystallinity was observed in presence of the nanofillers

Photothermal radiometric determination of thermal diffusivity depth profiles in a dental resin

International Nuclear Information System (INIS)

MartInez-Torres, P; Alvarado-Gil, J J; Mandelis, A

2010-01-01

The depth of curing due to photopolymerization in a commercial dental resin is studied using photothermal radiometry. The sample consists of a thick layer of resin on which a thin metallic layer is deposited guaranteeing full opacity of the sample. In this case, purely thermal-wave inverse problem techniques without the interference of optical profiles can be used. Thermal profiles are obtained by heating the coating with a modulated laser beam and performing a modulation frequency scan. Before each frequency scan, photopolymerization was induced using a high power blue LED. However due to the fact that dental resins are highly light dispersive materials, the polymerization process depends strongly on the optical absorption coefficient inducing a depth dependent thermal diffusion in the sample. It is shown that using a robust depth profilometric inverse method one can reconstruct the thermal diffusivity profile of the photopolymerized resin.

Investigation on Melt-Structure-Water Interactions (MSWI) during severe accidents

Energy Technology Data Exchange (ETDEWEB)

Sehgal, B.R.; Yang, Z.L.; Dinh, T.N.; Nourgaliev, R.R.; Bui, V.A.; Haraldsson, H.O.; Li, H.X.; Konovakhin, M.; Paladino, D.; Leung, W.H [Royal Inst. of Tech., Stockholm (Sweden). Div. of Nuclear Power Safety

1999-08-01

This report is the final report for the work performed in 1998 in the research project Melt Structure Water Interactions (MSWI), under the auspices of the APRI Project, jointly funded by SKI, HSK, USNRC and the Swedish and Finnish power companies. The present report describes results of advanced analytical and experimental studies concerning melt-water-structure interactions during the course of a hypothetical severe core meltdown accident in a light water reactor (LWR). Emphasis has been placed on phenomena and properties which govern the fragmentation and breakup of melt jets and droplets, melt spreading and coolability, and thermal and mechanical loadings of a pressure vessel during melt-vessel interaction. Many of the investigations performed in support of this project have produced papers which have been published in the proceedings of technical meetings. A short summary of the results achieved in these papers is provided in this overview. Both experimental and analytical studies were performed to improve knowledge about phenomena of melt-structure-water interactions. We believe that significant technical advances have been achieved during the course of these studies. It was found that: the solidification has a strong effect on the drop deformation and breakup. Initially appearing at the drop surface and, later, thickening inwards, the solid crust layer dampens the instability waves on the drop surface and, therefore, hinders drop deformation and breakup. The drop thermal properties also affect the thermal behavior of the drop and, therefore, have impact on its deformation behavior. The jet fragmentation process is a function of many related phenomena. The fragmentation rate depends not only on the traditional parameters, e.g. the Weber number, but also on the melt physical properties, which change as the melt cools down from the liquidus to the solidus temperature. Additionally, the crust formed on the surface of the melt jet will also reduce the propensity

Investigation on Melt-Structure-Water Interactions (MSWI) during severe accidents

International Nuclear Information System (INIS)

Sehgal, B.R.; Yang, Z.L.; Dinh, T.N.; Nourgaliev, R.R.; Bui, V.A.; Haraldsson, H.O.; Li, H.X.; Konovakhin, M.; Paladino, D.; Leung, W.H

1999-08-01

This report is the final report for the work performed in 1998 in the research project Melt Structure Water Interactions (MSWI), under the auspices of the APRI Project, jointly funded by SKI, HSK, USNRC and the Swedish and Finnish power companies. The present report describes results of advanced analytical and experimental studies concerning melt-water-structure interactions during the course of a hypothetical severe core meltdown accident in a light water reactor (LWR). Emphasis has been placed on phenomena and properties which govern the fragmentation and breakup of melt jets and droplets, melt spreading and coolability, and thermal and mechanical loadings of a pressure vessel during melt-vessel interaction. Many of the investigations performed in support of this project have produced papers which have been published in the proceedings of technical meetings. A short summary of the results achieved in these papers is provided in this overview. Both experimental and analytical studies were performed to improve knowledge about phenomena of melt-structure-water interactions. We believe that significant technical advances have been achieved during the course of these studies. It was found that: the solidification has a strong effect on the drop deformation and breakup. Initially appearing at the drop surface and, later, thickening inwards, the solid crust layer dampens the instability waves on the drop surface and, therefore, hinders drop deformation and breakup. The drop thermal properties also affect the thermal behavior of the drop and, therefore, have impact on its deformation behavior. The jet fragmentation process is a function of many related phenomena. The fragmentation rate depends not only on the traditional parameters, e.g. the Weber number, but also on the melt physical properties, which change as the melt cools down from the liquidus to the solidus temperature. Additionally, the crust formed on the surface of the melt jet will also reduce the propensity

Thermal and petrologic constraints on lower crustal melt accumulation under the Salton Sea Geothermal Field

Science.gov (United States)

Karakas, Ozge; Dufek, Josef; Mangan, Margaret T.; Wright, Heather M.; Bachmann, Olivier

2017-06-01

In the Salton Sea region of southern California (USA), concurrent magmatism, extension, subsidence, and sedimentation over the past 0.5 to 1.0 Ma have led to the creation of the Salton Sea Geothermal Field (SSGF)-the second largest and hottest geothermal system in the continental United States-and the small-volume rhyolite eruptions that created the Salton Buttes. In this study, we determine the flux of mantle-derived basaltic magma that would be required to produce the elevated average heat flow and sustain the magmatic roots of rhyolite volcanism observed at the surface of the Salton Sea region. We use a 2D thermal model to show that a lower-crustal, partially molten mush containing Salton Trough, and are consistent with seismic observations. Our results indicate limited melting and assimilation of pre-existing rocks in the lower crust. Instead, we find that basalt fractionation in the lower crust produces derivative melts of andesitic to dacitic composition. Such melts are then expected to ascend and accumulate in the upper crust, where they further evolve to give rise to small-volume rhyolite eruptions (Salton Buttes) and fuel local spikes in surface heat flux as currently seen in the SSGF. Such upper crustal magma evolution, with limited assimilation of hydrothermally altered material, is required to explain the slight decrease in δ18 O values of zircons (and melts) that have been measured in these rhyolites.

Fuel Rod Melt Progression Simulation Using Low-Temperature Melting Metal Alloy

International Nuclear Information System (INIS)

Seung Dong Lee; Suh, Kune Y.; GoonCherl Park; Un Chul Lee

2002-01-01

The TMI-2 accident and various severe fuel damage experiments have shown that core damage is likely to proceed through various states before the core slumps into the lower head. Numerous experiments were conducted to address when and how the core can lose its original geometry, what geometries are formed, and in what processes the core materials are transported to the lower plenum of the reactor pressure vessel. Core degradation progresses along the line of clad ballooning, clad oxidation, material interaction, metallic blockage, molten pool formation, melt progression, and relocation to the lower head. Relocation into the lower plenum may occur from the lateral periphery or from the bottom of the core depending upon the thermal and physical states of the pool. Determining the quantities and rate of molten material transfer to the lower head is important since significant amounts of molten material relocated to the lower head can threaten the vessel integrity by steam explosion and thermal and mechanical attack of the melt. In this paper the focus is placed on the melt flow regime on a cylindrical fuel rod utilizing the LAMDA (Lumped Analysis of Melting in Degrading Assemblies) facility at the Seoul National University. The downward relocation of the molten material is a combination of the external film flow and the internal pipe flow. The heater rods are 0.8 m long and are coated by a low-temperature melting metal alloy. The electrical internal heating method is employed during the test. External heating is adopted to simulate the exothermic Zircaloy-steam reaction. Tests are conducted in several quasi-steady-state conditions. Given the variable boundary conditions including the heat flux and the water level, observation is made for the melting location, progression, and the mass of molten material. Finally, the core melt progression model is developed from the visual inspection and quantitative analysis of the experimental data. As the core material relocates

Genetic Algorithm for Opto-thermal Skin Hydration Depth Profiling Measurements

Science.gov (United States)

Cui, Y.; Xiao, Perry; Imhof, R. E.

2013-09-01

Stratum corneum is the outermost skin layer, and the water content in stratum corneum plays a key role in skin cosmetic properties as well as skin barrier functions. However, to measure the water content, especially the water concentration depth profile, within stratum corneum is very difficult. Opto-thermal emission radiometry, or OTTER, is a promising technique that can be used for such measurements. In this paper, a study on stratum corneum hydration depth profiling by using a genetic algorithm (GA) is presented. The pros and cons of a GA compared against other inverse algorithms such as neural networks, maximum entropy, conjugate gradient, and singular value decomposition will be discussed first. Then, it will be shown how to use existing knowledge to optimize a GA for analyzing the opto-thermal signals. Finally, these latest GA results on hydration depth profiling of stratum corneum under different conditions, as well as on the penetration profiles of externally applied solvents, will be shown.

Crystallization of nuclear glass under a thermal gradient: application to the self-crucible produced in the skull melting process

International Nuclear Information System (INIS)

Delattre, O.

2013-01-01

In the context of the vitrification of high level nuclear waste, a new industrial process has been launched in 2010 at the La Hague factory: The skull melting process. This setup applies thermal gradients to the melt, which leads to the formation of a solid layer of glass: the 'self-crucible'. The question would be to know whether these thermal gradients have an impact or not on the crystallization behaviour of the considered glasses in the self crucible. In order to answer that question, the crystallization of two glass compositions of nuclear interest has been investigated with an image analysis based method in isothermal and thermal gradient heat treatments conditions. The isothermal experiments allow for the quantification (growth speed, nucleation, crystallized fraction) of the crystallization of apatites (660 C-900 C) and powellites (630 C-900 C). The comparison of the results obtained through these two types of experimentations allows us to conclude that there is no impact of the thermal gradient on the crystallization of the studied glass compositions. In order to complete the image analysis study (based on surfaces), in and ex situ microtomography experiments have been performed at ESRF (Grenoble) on the ID19 beamline. This study allowed us to follow the crystallization of apatites in a simplified glass and to confirm the reliability of the image analysis method based on the analysis of surfaces. (author) [fr

Dysprosium-free melt-spun permanent magnets

International Nuclear Information System (INIS)

Brown, D N; Wu, Z; He, F; Miller, D J; Herchenroeder, J W

2014-01-01

Melt-spun NdFeB powders can be formed into a number of different types of permanent magnet for a variety of applications in electronics, automotive and clean technology industries. The melt-spinning process produces flake powder with a fine uniform array of nanoscale Nd 2 Fe 14 B grains. These powders can be net-shape formed into isotropic polymer-bonded magnets or hot formed into fully dense magnets. This paper discusses the influence of heavy rare earth elements and microstructure on the magnetic performance, thermal stability and material cost of NdFeB magnets. Evidence indicates that melt-spun nanocrystalline NdFeB magnets are less dependent on heavy rare earth elements for high-temperature performance than the alternative coarser-grained sintered NdFeB magnets. In particular, hot-pressed melt-spun magnets are an attractive low-cost solution for applications that require thermal stability up to 175–200 °C. (paper)

Dysprosium-free melt-spun permanent magnets.

Science.gov (United States)

Brown, D N; Wu, Z; He, F; Miller, D J; Herchenroeder, J W

2014-02-12

Melt-spun NdFeB powders can be formed into a number of different types of permanent magnet for a variety of applications in electronics, automotive and clean technology industries. The melt-spinning process produces flake powder with a fine uniform array of nanoscale Nd2Fe14B grains. These powders can be net-shape formed into isotropic polymer-bonded magnets or hot formed into fully dense magnets. This paper discusses the influence of heavy rare earth elements and microstructure on the magnetic performance, thermal stability and material cost of NdFeB magnets. Evidence indicates that melt-spun nanocrystalline NdFeB magnets are less dependent on heavy rare earth elements for high-temperature performance than the alternative coarser-grained sintered NdFeB magnets. In particular, hot-pressed melt-spun magnets are an attractive low-cost solution for applications that require thermal stability up to 175-200 °C.

Thermal profiles, crystallization behaviors and microstructure of diacylglycerol-enriched palm oil blends with diacylglycerol-enriched palm olein.

Science.gov (United States)

Xu, Yayuan; Zhao, Xiaoqing; Wang, Qiang; Peng, Zhen; Dong, Cao

2016-07-01

To elucidate the possible interaction mechanisms between DAG-enriched oils, this study investigated how mixtures of DAG-enriched palm-based oils influenced the phase behavior, thermal properties, crystallization behaviors and the microstructure in binary fat blends. DAG-enriched palm oil (PO-DAGE) was blended with DAG-enriched palm olein (POL-DAGE) in various percentages (0%, 10%, 30%, 50%, 70%, 90%, 100%). Based on the observation of iso-solid diagram and phase diagram, the binary mixture of PO-DAGE/POL-DAGE showed a better compatibility in comparison with their corresponding original blends. DSC thermal profiles exhibited that the melting and crystallization properties of PO-DAGE/POL-DAGE were distinctively different from corresponding original blends. Crystallization kinetics revealed that PO-DAGE/POL-DAGE blends displayed a rather high crystallization rate and exhibited no spherulitic crystal growth. From the results of polarized light micrographs, PO-DAGE/POL-DAGE blends showed more dense structure with very small needle-like crystals than PO/POL. X-ray diffraction evaluation revealed when POL-DAGE was added in high contents to PO-DAGE, above 30%, β-polymorph dominated, and the mount of β' forms crystals was decreasing. Copyright © 2016 Elsevier Ltd. All rights reserved.

Melting behaviour of raw materials and recycled stone wool waste

DEFF Research Database (Denmark)

Schultz-Falk, Vickie; Agersted, Karsten; Jensen, Peter Arendt

2018-01-01

Stone wool is a widely used material for building insulation, to provide thermal comfort along with fire stability and acoustic comfort for all types of buildings. Stone wool waste generated either during production or during renovation or demolition of buildings can be recycled back into the sto...... wool melt production. This study investigates and compares the thermal response and melting behaviour of a conventional stone wool charge and stone wool waste. The study combines differential scanning calorimetry (DSC), hot stage microscopy (HSM) and X-ray diffraction (XRD). DSC reveals...... that the conventional charge and stone wool waste have fundamentally different thermal responses, where the charge experiences gas release, phase transition and melting of the individual raw materials. The stone wool waste experiences glass transition, crystallization and finally melting. Both DSC and HSM measurements...

Thermal Simulation of the Component Rework Profile Temperature

OpenAIRE

Nurminen, Janne

2015-01-01

The aim of this study was to clarify the possibilities and feasibility of the ther-mal simulation for the modeling of the rework process. The rework process modeling could enable an easy and fast access to the component and PWB level thermally critical effects like over and under heating of the component during the rework process. The modeling could also be used as a help of the real rework profile definition at an early phase of the electrical device development. The work includes a...

Thermal expansion and strength characteristics of interatomic bonds in melts of A3 B5 (Al Sb, In Sb, Ga Sb, In As, Ga As) compounds

International Nuclear Information System (INIS)

Glazov, V.M.; Shchelikov, O.D.

1998-01-01

Temperature dependence of specific volume of the A 3 B 5 compounds melts is studied thermometrically and through the method of the penetrating γ radiation. Evaluation of melts thermal expansion coefficients under different temperatures is carried out. Estimates of the Debye characteristic temperatures and mean square dynamic shifts of atoms in the close order structure of the A 3 B 5 compounds melts are conducted on the basis of the obtained results

Effect of block composition on thermal properties and melt viscosity of poly[2-(dimethylaminoethyl methacrylate], poly(ethylene oxide and poly(propylene oxide block co-polymers

Directory of Open Access Journals (Sweden)

2011-09-01

Full Text Available To modify the rheological properties of certain commercial polymers, a set of block copolymers were synthesized through oxyanionic polymerization of 2-(dimethylaminoethyl methacrylate to the chain ends of commercial prepolymers, namely poly(ethylene oxide (PEO, poly(ethylene oxide-block-poly(propylene oxide-block-poly(ethylene oxide (PEO-PPO-PEO, and poly(propylene oxide (PPO. The formed block copolymers were analysed with size exclusion chromatography and nuclear magnetic resonance spectroscopy in order to confirm block formation. Thermal characterization of the resulting polymers was done with differential scanning calorimetry. Thermal transition points were also confirmed with rotational rheometry, which was primarily used to measure melt strength properties of the resulting block co-polymers. It was observed that the synthesised poly[2-(dimethylaminoethyl methacrylate]-block (PDM affected slightly the thermal transition points of crystalline PEO-block but the influence was stronger on amorphous PPO-blocks. Frequency sweeps measured above the melting temperatures for the materials confirmed that the pre-polymers (PEO and PEO-PPO-PEO behave as Newtonian fluids whereas polymers with a PDM block structure exhibit clear shear thinning behaviour. In addition, the PDM block increased the melt viscosity when compared with that one of the pre-polymer. As a final result, it became obvious that pre-polymers modified with PDM were in entangled form, in the melted state as well in the solidified form.

Thermal performance of a PCM thermal storage unit

Energy Technology Data Exchange (ETDEWEB)

Liu Ming; Bruno, Frank; Saman, Wasim [Sustainable Energy Centre, Inst. for Sustainable Systems and Technologies, Univ. of South Australia, Mawson Lakes, Adelaide (Australia)

2008-07-01

The thermal performance of a PCM thermal storage unit (TSU) is studied numerically and experimentally. The TSU under analysis consists of several flat slabs of phase change material (PCM) with melting temperature of -26.7 C. Liquid heat transfer fluid (HTF) passes between the slabs to charge and discharge the storage unit. A one dimensional mathematical model was employed to analyze the transient thermal behavior of the storage unit during the melting and freezing processes. The model takes into consideration the temperature variations in the wall along the flow direction of the HTF. The paper compares the experimental and numerical simulation results in terms of HTF outlet temperatures during the melting period. (orig.)

Holographic measurement of distortion during laser melting: Additive distortion from overlapping pulses

Science.gov (United States)

Haglund, Peter; Frostevarg, Jan; Powell, John; Eriksson, Ingemar; Kaplan, Alexander F. H.

2018-03-01

Laser - material interactions such as welding, heat treatment and thermal bending generate thermal gradients which give rise to thermal stresses and strains which often result in a permanent distortion of the heated object. This paper investigates the thermal distortion response which results from pulsed laser surface melting of a stainless steel sheet. Pulsed holography has been used to accurately monitor, in real time, the out-of-plane distortion of stainless steel samples melted on one face by with both single and multiple laser pulses. It has been shown that surface melting by additional laser pulses increases the out of plane distortion of the sample without significantly increasing the melt depth. The distortion differences between the primary pulse and subsequent pulses has also been analysed for fully and partially overlapping laser pulses.

LDPE and PP thermal diffusivity in molten state

OpenAIRE

Yánez, G.; Rodríguez - Pérez, M. A; Almanza, O. A.

2013-01-01

Experimental results are reported for measuring the thermal diffusivity of two polymer species: low density polyethylene (LDPE) and polypropylene (PP). Measurements were taken in unsteady state heat flow conditions around the materials' melting temperature, using a device specially constructed for this purpose. The experimental results for the sample's temperature profile (temperature gradient product) were adjusted with the theoretical results obtained by solving the heat conduction equation...

Difference in melting profiles of gamma irradiated DNA from chicken erythrocytes and from Escherichia coli B/r

International Nuclear Information System (INIS)

Kopff, J.; Miller, G.; Leyko, W.

1977-01-01

Effects of gamma irradiation on melting curves of DNA from chicken erythrocytes and Escherichia coli B/r were compared. Considerable changes, following gamma irradiation in the case of chicken erythrocytes DNA and no changes in the case of DNA from Escherichia coli B/r were observed. To explain the lack of changes in gamma irradiated samples of DNA from Escherichia coli B/r it was assumed that the original effects of irradiation were obscured by the process of renaturation of DNA. To exclude the above mentioned effect, examination of gamma irradiated DNA from Escherichia coli B/r was carried out with the addition of formaldehyde immediately after irradiation of the sample. Using this procedure changes of melting profiles of DNA from Escherichia coli B/r were demonstrated. (author)

Chemical durability of slag produced by thermal plasma melting of low-level miscellaneous solid wastes. Effects of slag composition

International Nuclear Information System (INIS)

Amakawa, Tadashi; Yasui, Shinji

2001-01-01

Low-level radioactive miscellaneous solid wastes are generated from commercial operation of nuclear power plants and will be generated from decommissioning of nuclear power plants in future. Static leaching tests were carried out in deionized water of 10degC on slag obtained by thermal plasma melting of simulating materials of the miscellaneous solids wastes with surrogate elements of radionuclides. It is found that logarithm of normalized elemental mass loss from the slag is proportional to the basicity represented by mole fractions of main structural oxides of the slag, such as SiO 2 , Al 2 O 3 , CaO, FeO and MgO. The range of static leaching rates from the slag is determined based on the above results and the basicity range of the miscellaneous solid wastes. Then we compared the leaching rates form the slag and from high level waste glasses. On these grounds, we concluded that the slag obtained by thermal plasma melting of miscellaneous solid wastes can stabilize radio-nuclides in it by no means inferior to the high level waste glasses. (author)

Thermal Stability of P-Type BiSbTe Alloys Prepared by Melt Spinning and Rapid Sintering

Directory of Open Access Journals (Sweden)

Yun Zheng

2017-06-01

Full Text Available P-type BiSbTe alloys have been widely implemented in waste heat recovery from low-grade heat sources below 600 K, which may involve assorted environments and conditions, such as long-term service, high-temperature exposure (generally 473–573 K and mechanical forces. It is important to evaluate the service performance of these materials in order to prevent possible failures in advance and extend the life cycle. In this study, p-type Bi0.5Sb1.5Te3 commercial zone-melting (ZM ingots were processed by melt spinning and subsequent plasma-activated sintering (MS-PAS, and were then subjected to vacuum-annealing at 473 and 573 K, respectively, for one week. The results show that MS-PAS samples exhibit excellent thermal stability when annealed at 473 K. However, thermal annealing at 573 K for MS-PAS specimens leads to the distinct sublimation of the element Te, which degrades the hole concentration remarkably and results in inferior thermoelectric performance. Furthermore, MS-PAS samples annealed at 473 K demonstrate a slight enhancement in flexural and compressive strengths, probably due to the reduction of residual stress induced during the sintering process. The current work guides the reliable application of p-type Bi0.5Sb1.5Te3 compounds prepared by the MS-PAS technique.

Morphology, thermal and mechanical properties of PVC/MMT nanocomposites prepared by solution blending and solution blending + melt compounding

DEFF Research Database (Denmark)

Madaleno, Liliana Andreia Oliveira; Schjødt-Thomsen, Jan; Pinto, José Cruz

2010-01-01

Two types of montmorillonite (MMT), natural sodium montmorillonite (Na-MMT) and organically modified montmorillonite (OMMT), in different amounts of 1, 2, 5, 10 and 25 phr (parts per hundred resin), were dispersed in rigid poly (vinyl chloride) by two different methods solution blending...... and solution blending + melt compounding The effects on morphology, thermal and mechanical properties of the PVC/MMT nanocomposites were studied by varying the amount of Na-MMT and OMMT in both methods SEM and XRD analysis revealed that possible intercalated and exfoliated structures were obtained in all...... prepared by solution blending + melt compounding method Experimental values for 1 and 2 phr are larger than the calculated values which directly suggest that the MMT particles are exfoliated (C) 2010 Elsevier Ltd All rights reserved...

Lattice Boltzmann model for melting with natural convection

International Nuclear Information System (INIS)

Huber, Christian; Parmigiani, Andrea; Chopard, Bastien; Manga, Michael; Bachmann, Olivier

2008-01-01

We develop a lattice Boltzmann method to couple thermal convection and pure-substance melting. The transition from conduction-dominated heat transfer to fully-developed convection is analyzed and scaling laws and previous numerical results are reproduced by our numerical method. We also investigate the limit in which thermal inertia (high Stefan number) cannot be neglected. We use our results to extend the scaling relations obtained at low Stefan number and establish the correlation between the melting front propagation and the Stefan number for fully-developed convection. We conclude by showing that the model presented here is particularly well-suited to study convection melting in geometrically complex media with many applications in geosciences

Eutectic mixtures of some fatty acids for latent heat storage: Thermal properties and thermal reliability with respect to thermal cycling

International Nuclear Information System (INIS)

Sari, Ahmet

2006-01-01

Accelerated thermal cycle tests have been conducted to study the change in melting temperatures and latent heats of fusion of the eutectic mixtures of lauric acid (LA)-myristic acid (MA), lauric acid (LA)-palmitic acid (PA) and myristic acid (MA)-stearic acid (SA) as latent heat storage materials. The thermal properties of these materials were determined by the differential scanning calorimetry (DSC) analysis method. The thermal reliability of the eutectic mixtures after melt/freeze cycles of 720, 1080 and 1460 was also evaluated using the DSC curves. The accelerated thermal cycle tests indicate that the melting temperatures usually tend to decrease, and the variations in the latent heats of fusion are irregular with increasing number of thermal cycles. Moreover, the probable reasons for the change in thermal properties of the eutectic mixtures after repeated thermal cycles were investigated. Fourier Transform Infrared (FT-IR) spectroscopic analysis indicates that the accelerated melt/freeze processes do not cause any degradation in the chemical structure of the mixtures. The change in thermal properties of the eutectic mixtures with increasing number of thermal cycles is only because of the presence of certain amounts of impurities in the fatty acids used in their preparation. It is concluded that the tested eutectic mixtures have reasonable thermal properties and thermal reliability as phase change materials (PCMs) for latent heat storage in any solar heating applications that include a four year utilization period

Multicomponent Diffusion in Experimentally Cooled Melt Inclusions

Science.gov (United States)

Saper, L.; Stolper, E.

2017-12-01

Glassy olivine-hosted melt inclusions are compositionally zoned, characterized by a boundary layer depleted in olivine-compatible components that extends into the melt inclusion from its wall. The boundary layer forms in response to crystallization of olivine and relaxes with time due to diffusive exchange with the interior of the inclusion. At magmatic temperatures, the time scale for homogenization of inclusions is minutes to hours. Preservation of compositional gradients in natural inclusions results from rapid cooling upon eruption. A model of MgO concentration profiles that couples crystal growth and diffusive relaxation of a boundary layer can be used to solve for eruptive cooling rates [1]. Controlled cooling-rate experiments were conducted to test the accuracy of the model. Mauna Loa olivine containing >80 µm melt inclusions were equilibrated at 1225°C in a 1-atm furnace for 24 hours, followed by linear cooling at rates of 102 - 105 °C/hr. High-resolution concentration profiles of 40 inclusions were obtained using an electron microprobe. The model of [1] fits the experimental data with low residuals and the best-fit cooling rates are within 30% of experimental values. The initial temperature of 1225 °C is underestimated by 65°C. The model was modified using (i) MELTS to calculate the interface melt composition as a function of temperature, and (ii) a concentration-dependent MgO diffusion coefficient using the functional form of [2]. With this calibration the best-fit starting temperatures are within 5°C of the experimental values and the best-fit cooling rates are within 20% of experimental rates. The evolution of the CaO profile during cooling is evidence for strong diffusive coupling between melt components. Because CaO is incompatible in olivine, CaO concentrations are expected to be elevated in the boundary layer adjacent to the growing olivine. Although this is observed at short time scales, as the profile evolves the CaO concentration near the

Melting of Pb clusters encapsulated in large fullerenes

International Nuclear Information System (INIS)

Delogu, Francesco

2011-01-01

Graphical abstract: Encapsulation significantly increases the melting point of nanometer-sized Pb particles with respect to the corresponding unsupported ones. Highlights: → Nanometer-sized Pb particles are encapsulated in fullerene cages. → Their thermal behavior is studied by molecular dynamics simulations. → Encapsulated particles undergo a pressure rise as temperature increases. → Encapsulated particles melt at temperatures higher than unsupported ones. - Abstract: Molecular dynamics simulations have been employed to explore the melting behavior of nanometer-sized Pb particles encapsulated in spherical and polyhedral fullerene cages of suitable size. The encapsulated particles, as well as the corresponding unsupported ones for comparison, were submitted to a gradual temperature rise. Encapsulation is shown to severely affect the thermodynamic behavior of Pb particles due to the different thermal expansion coefficients of particles and cages. This determines a volume constraint that induces a rise of pressure inside the fullerene cages, which operate for particles as rigid confinement systems. The result is that surface pre-melting and melting processes occur in encapsulated particles at temperatures higher than in unsupported ones.

Advanced One-Dimensional Entrained-Flow Gasifier Model Considering Melting Phenomenon of Ash

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Jinsu Kim

2018-04-01

Full Text Available A one-dimensional model is developed to represent the ash-melting phenomenon, which was not considered in the previous one-dimensional (1-D entrained-flow gasifier model. We include sensible heat of slag and the fusion heat of ash in the heat balance equation. To consider the melting of ash, we propose an algorithm that calculates the energy balance for three scenarios based on temperature. We also use the composition and the thermal properties of anorthite mineral to express ash. gPROMS for differential equations is used to solve this algorithm in a simulation; the results include coal conversion, gas composition, and temperature profile. Based on the Texaco pilot plant gasifier, we validate our model. Our results show good agreement with previous experimental data. We conclude that the sensible heat of slag and the fusion heat of ash must be included in the entrained flow gasifier model.

Rapakivi texture formation via disequilibrium melting in a contact partial melt zone, Antarctica

Science.gov (United States)

Currier, R. M.

2017-12-01

In the McMurdo Dry Valleys of Antarctica, a Jurassic aged dolerite sill induced partial melting of granite in the shallow crust. The melt zone can be traced in full, from high degrees of melting (>60%) along the dolerite contact, to no apparent signs of melting, 10s of meters above the contact. Within this melt zone, the well-known rapakivi texture is found, arrested in various stages of development. High above the contact, and at low degrees of melting, K-feldspar crystals are slightly rounded and unmantled. In the lower half of the melt zone, mantles of cellular textured plagioclase appear on K-feldspar, and thicken towards the contact heat source. At the highest degrees of melting, cellular-textured plagioclase completely replaces restitic K-feldspar. Because of the complete exposure and intact context, the leading models of rapakivi texture formation can be tested against this system. The previously proposed mechanisms of subisothermal decompression, magma-mixing, and hydrothermal exsolution all fail to adequately describe rapakivi generation in this melt zone. Preferred here is a closed system model that invokes the production of a heterogeneous, disequilibrium melt through rapid heating, followed by calcium and sodium rich melt reacting in a peritectic fashion with restitic K-feldspar crystals. This peritectic reaction results in the production of plagioclase of andesine-oligoclase composition—which is consistent with not just mantles in the melt zone, but globally as well. The thickness of the mantle is diffusion limited, and thus a measure of the diffusive length scale of sodium and calcium over the time scale of melting. Thermal modeling provides a time scale of melting that is consistent with the thickness of observed mantles. Lastly, the distribution of mantled feldspars is highly ordered in this melt zone, but if it were mobilized and homogenized—mixing together cellular plagioclase, mantled feldspars, and unmantled feldspars—the result would be

Holographic picture of heavy vector meson melting

Energy Technology Data Exchange (ETDEWEB)

Braga, Nelson R.F.; Diles, Saulo [Universidade Federal do Rio de Janeiro, Instituto de Fisica, Rio de Janeiro, RJ (Brazil); Martin Contreras, Miguel Angel [Universidad de los Andes, High Energy Group, Department of Physics, Bogota (Colombia)

2016-11-15

The fraction of heavy vector mesons produced in a heavy ion collision, as compared to a proton-proton collision, serves as an important indication of the formation of a thermal medium, the quark-gluon plasma. This sort of analysis strongly depends on understanding the thermal effects of a medium like the plasma on the states of heavy mesons. In particular, it is crucial to know the temperature ranges where they undergo a thermal dissociation, or melting. AdS/QCD models are know to provide an important tool for the calculation of hadronic masses, but in general are not consistent with the observation that decay constants of heavy vector mesons decrease with excitation level. It has recently been shown that this problem can be overcome using a soft wall background and introducing an extra energy parameter, through the calculation of correlation functions at a finite position of anti-de Sitter space. This approach leads to the evaluation of masses and decay constants of S wave quarkonium states with just one flavor dependent and one flavor independent parameter. Here we extend this more realistic model to finite temperatures and analyze the thermal behavior of the states 1S, 2S and 3S of bottomonium and charmonium. The corresponding spectral function exhibits a consistent picture for the melting of the states where, for each flavor, the higher excitations melt at lower temperatures. We estimate for these six states the energy ranges in which the heavy vector mesons undergo a transition from a well-defined peak in the spectral function to complete melting in the thermal medium. A very clear distinction between the heavy flavors emerges, with the bottomonium state Υ(1S) surviving a deconfinement transition at temperatures much larger than the critical deconfinement temperature of the medium. (orig.)

A unified momentum equation approach for computing thermal residual stresses during melting and solidification

Science.gov (United States)

Yeo, Haram; Ki, Hyungson

2018-03-01

In this article, we present a novel numerical method for computing thermal residual stresses from a viewpoint of fluid-structure interaction (FSI). In a thermal processing of a material, residual stresses are developed as the material undergoes melting and solidification, and liquid, solid, and a mixture of liquid and solid (or mushy state) coexist and interact with each other during the process. In order to accurately account for the stress development during phase changes, we derived a unified momentum equation from the momentum equations of incompressible fluids and elastoplastic solids. In this approach, the whole fluid-structure system is treated as a single continuum, and the interaction between fluid and solid phases across the mushy zone is naturally taken into account in a monolithic way. For thermal analysis, an enthalpy-based method was employed. As a numerical example, a two-dimensional laser heating problem was considered, where a carbon steel sheet was heated by a Gaussian laser beam. Momentum and energy equations were discretized on a uniform Cartesian grid in a finite volume framework, and temperature-dependent material properties were used. The austenite-martensite phase transformation of carbon steel was also considered. In this study, the effects of solid strains, fluid flow, mushy zone size, and laser heating time on residual stress formation were investigated.

Surface reflectance drives nest box temperature profiles and thermal suitability for target wildlife.

Directory of Open Access Journals (Sweden)

Stephen R Griffiths

Full Text Available Thermal properties of tree hollows play a major role in survival and reproduction of hollow-dependent fauna. Artificial hollows (nest boxes are increasingly being used to supplement the loss of natural hollows; however, the factors that drive nest box thermal profiles have received surprisingly little attention. We investigated how differences in surface reflectance influenced temperature profiles of nest boxes painted three different colors (dark-green, light-green, and white: total solar reflectance 5.9%, 64.4%, and 90.3% respectively using boxes designed for three groups of mammals: insectivorous bats, marsupial gliders and brushtail possums. Across the three different box designs, dark-green (low reflectance boxes experienced the highest average and maximum daytime temperatures, had the greatest magnitude of variation in daytime temperatures within the box, and were consistently substantially warmer than light-green boxes (medium reflectance, white boxes (high reflectance, and ambient air temperatures. Results from biophysical model simulations demonstrated that variation in diurnal temperature profiles generated by painting boxes either high or low reflectance colors could have significant ecophysiological consequences for animals occupying boxes, with animals in dark-green boxes at high risk of acute heat-stress and dehydration during extreme heat events. Conversely in cold weather, our modelling indicated that there are higher cumulative energy costs for mammals, particularly smaller animals, occupying light-green boxes. Given their widespread use as a conservation tool, we suggest that before boxes are installed, consideration should be given to the effect of color on nest box temperature profiles, and the resultant thermal suitability of boxes for wildlife, particularly during extremes in weather. Managers of nest box programs should consider using several different colors and installing boxes across a range of both orientations and

A 2D double-porosity model for melting and melt migration beneath mid-oceanic ridges

Science.gov (United States)

Liu, B.; Liang, Y.; Parmentier, E.

2017-12-01

Several lines of evidence suggest that the melting and melt extraction region of the MORB mantle is heterogeneous consisting of an interconnected network of high permeability dunite channels in a low porosity harzburgite or lherzolite matrix. In principle, one can include channel formation into the tectonic-scale geodynamic models by solving conservation equations for a chemically reactive and viscously deformable porous medium. Such an approach eventually runs into computational limitations such as resolving fractal-like channels that have a spectrum of width. To better understand first order features of melting and melt-rock interaction beneath MOR, we have formulated a 2D double porosity model in which we treat the triangular melting region as two overlapping continua occupied by the low-porosity matrix and interconnected high-porosity channels. We use melt productivity derived from a thermodynamic model and melt suction rate to close our problem. We use a high-order accurate numerical method to solve the conservation equations in 2D for porosity, solid and melt velocities and concentrations of chemical tracers in the melting region. We carry out numerical simulations to systematically study effects of matrix-to-channel melt suction and spatially distributed channels on the distributions of porosity and trace element and isotopic ratios in the melting region. For near fractional melting with 10 vol% channel in the melting region, the flow field of the matrix melt follows closely to that of the solid because the small porosity (exchange between the melt and the solid. The smearing effect can be approximated by dispersion coefficient. For slowly diffusing trace elements (e.g., LREE and HFSE), the melt migration induced dispersion can be as effective as thermal diffusion. Therefore, sub-kilometer scale heterogeneities of Nd and Hf isotopes are significantly damped or homogenized in the melting region.

Two-dimensional disruption thermal analysis code DREAM

International Nuclear Information System (INIS)

Yamazaki, Seiichiro; Kobayashi, Takeshi; Seki, Masahiro.

1988-08-01

When a plasma disruption takes place in a tokamak type fusion reactor, plasma facing components such as first wall and divertor/limiter are subjected to an intense heat load with very high heat flux and short duration. At the surface of the wall, temperature rapidly rises, and melting and evaporation occurs, it causes reduction of wall thickness and crack initiation/propagation. As lifetime of the components is significantly affected by them, the transient analysis in consideration of phase changes (melting/evaporation) and radiation heat loss is required in the design of these components. This paper describes the computer code DREAM developed to perform the two-dimensional transient thermal analysis that takes phase changes and radiation into account. The input and output of the code and a sample analysis on a disruption simulation experiment are also reported. The user's input manual is added as an appendix. The profiles and time variations of temperature, and melting and evaporated thicknesses of the material subjected to intense heat load can be obtained, using this computer code. This code also gives the temperature data for elastoplastic analysis with FEM structural analysis codes (ADINA, MARC, etc.) to evaluate the thermal stress and crack propagation behavior within the wall materials. (author)

Theoretical study of a melting curve for tin

International Nuclear Information System (INIS)

Feng, Xi; Ling-Cang, Cai

2009-01-01

The melting curve of Sn has been calculated using the dislocation-mediated melting model with the 'zone-linking method'. The results are in good agreement with the experimental data. According to our calculation, the melting temperature of γ-Sn at zero pressure is about 436 K obtained by the extrapolation of the method from the triple point of Sn. The results show that this calculation method is better than other theoretical methods for predicting the melting curve of polymorphic material Sn. (condensed matter: structure, thermal and mechanical properties)

Accelerated Thermal Cycling Test of Microencapsulated Paraffin Wax/Polyaniline Made by Simple Preparation Method for Solar Thermal Energy Storage.

Science.gov (United States)

Silakhori, Mahyar; Naghavi, Mohammad Sajad; Metselaar, Hendrik Simon Cornelis; Mahlia, Teuku Meurah Indra; Fauzi, Hadi; Mehrali, Mohammad

2013-04-29

Microencapsulated paraffin wax/polyaniline was prepared using a simple in situ polymerization technique, and its performance characteristics were investigated. Weight losses of samples were determined by Thermal Gravimetry Analysis (TGA). The microencapsulated samples with 23% and 49% paraffin showed less decomposition after 330 °C than with higher percentage of paraffin. These samples were then subjected to a thermal cycling test. Thermal properties of microencapsulated paraffin wax were evaluated by Differential Scanning Calorimeter (DSC). Structure stability and compatibility of core and coating materials were also tested by Fourier transform infrared spectrophotometer (FTIR), and the surface morphology of the samples are shown by Field Emission Scanning Electron Microscopy (FESEM). It has been found that the microencapsulated paraffin waxes show little change in the latent heat of fusion and melting temperature after one thousand thermal recycles. Besides, the chemical characteristics and structural profile remained constant after one thousand thermal cycling tests. Therefore, microencapsulated paraffin wax/polyaniline is a stable material that can be used for thermal energy storage systems.

Energy demand and thermal comfort of HVAC systems with thermally activated building systems as a function of user profile

Science.gov (United States)

Pałaszyńska, Katarzyna; Bandurski, Karol; Porowski, Mieczysław

2017-11-01

Thermally Activated Building Systems (TABS) are a way to use building structure as a thermal energy storage. As a result, renewable energy sources may be used more efficiently. The paper presents numerical analysis of a HVAC system with TABS energy demand and indoor thermal comfort of a representative room in a non-residential building (governmental, commercial, educational). The purpose of analysis is to investigate the influence of a user profile on system performance. The time span of the analysis is one year - a typical meteorological year. The model was prepared using a generally accepted simulation tool - TRNSYS 17. The results help to better understand the interaction of a user profile with TABS. Therefore they are important for the development of optimal control algorithms for energy efficient buildings equipped with such systems.

Thermal characterization of indirectly heated axi-symmetric solid cathode electron beam gun for melting application

International Nuclear Information System (INIS)

Prakash, B.; Gupta, S.; Malik, P.; Mishra, K.K.; Jha, M.N.; Kandaswamy, E.; Martin, M.

2015-01-01

Electron beam melting gun with indirectly heated axi-symmetric solid cathode was designed, fabricated and characterized experimentally. The thermal simulation and optical analysis of the electron gun was carried out to estimate the power required to achieve the emission temperature of the solid cathode, to obtain the temperature distribution in the assembly and the beam transportation. On the basis of the thermal simulation and electron optics, the electron gun design was finalised. The electron gun assembly was fabricated and installed in the vacuum chamber for carrying out the experiment to find the actual temperature distribution. Thermocouple and two colour pyrometer were used to measure the temperature at various locations in the electron gun. The attenuation effect of the viewing port glass of the vacuum chamber was compensated in the final reading of the temperature measured by the pyrometer. The temperature of solid cathode obtained by the experiment was found to be 2800K which is the emission temperature of solid cathode. (author)

Thermal efficiency on welding of AA6061-T6 alloy by modified indirect electric arc and current signals digitalisation

International Nuclear Information System (INIS)

Ambriz, R. R.; Barrera, G.; Garcia, R.; Lopez, V. H.

2009-01-01

The results of the thermal efficiency on welding by modified indirect electric arc technique (MIEA) [1] of the 6061- T6 aluminum alloy are presented. These values are in a range of 90 to 94 %, which depend of the preheating employed. Thermal efficiency was obtained by means of a balance energy which considers the heat input, the amount of melted mass of the welding profiles, and welding parameters during the joining, especially of the arc current data acquisition. Also, some dimensionless parameters were employed in order to determine the approximation grade of the melted pool, the heat affected zone (HAZ), and their corresponding values with the experimental results. (Author) 13 refs

Water jet intrusion into hot melt concomitant with direct-contact boiling of water

Energy Technology Data Exchange (ETDEWEB)

Sibamoto, Yasuteru [Japan Atomic Energy Research Inst., Tokai Research Establishment, Tokai, Ibaraki (Japan)

2005-08-01

Boiling of water poured on surface of high-temperature melt (molten metal or metal oxide) provides an efficient means for heat exchange or cooling of melt. The heat transfer surface area can be extended by forcing water into melt. Objectives of the present study are to elucidate key factors of the thermal and hydrodynamic interactions for the water jet injection into melt (Coolant Injection mode). Proposed applications include in in-vessel heat exchangers for liquid metal reactor and emergency measures for cooling of molten core debris in severe accidents of light water reactor. Water penetration into melt may occurs also as a result of fuel-coolant interaction (FCI) in modes other than CI, it is anticipated that the present study contributes to understand the fundamental mechanism of the FCI process. The previous works have been limited on understanding the melt-water interaction phenomena in the water-injection mode because of difficulty in experimental measurement where boiling occurs in opaque invisible hot melt unlike the melt-injection mode. We conducted visualization and measurement of melt-water-vapor multiphase flow phenomena by using a high-frame-rate neutron radiography technique and newly-developed probes. Although limited knowledge, however, has been gained even such an approach, the experimental data were analyzed deeply by comparing with the knowledge obtained from relevant matters. As a result, we succeeded in revealing several key phenomena and validity in the conditions under which stable heat transfer is established. Moreover, a non-intrusive technique for measurement of the velocity and pressure fields adjacent to a moving free surface is developed. The technique is based on the measurement of fluid surface profile, which is useful for elucidation of flow mechanism accompanied by a free surface like the present phenomena. (author)

Influence of gas-generation on melt/concrete interaction

International Nuclear Information System (INIS)

Powers, D.A.

1979-01-01

Gases formed during the interaction of a high-temperature melt with concrete are shown to stem from the thermal dehydration and decarboxylation of the concrete. The kinetics of these decomposition reactions are described. Gases within the melt cause an apparent swelling of the melt. The observed swelling is not easily correlated to the rate of gas evolution. Metallic melts cause CO 2 /CO and H 2 O liberated from the melt to be reduced to CO and hydrogen. When these gases escape from the melt they assist in aerosol formation. As the gases cool they react along a pathway whose oxygen fugacity is apparently buffered by the iron-Wuestite equilibrium. Methane is a product of the gas-phase reaction. (orig./HP) [de

Production, pathways and budgets of melts in mid-ocean ridges: An enthalpy based thermo-mechanical model

Science.gov (United States)

Mandal, Nibir; Sarkar, Shamik; Baruah, Amiya; Dutta, Urmi

2018-04-01

Using an enthalpy based thermo-mechanical model we provide a theoretical evaluation of melt production beneath mid-ocean ridges (MORs), and demonstrate how the melts subsequently develop their pathways to sustain the major ridge processes. Our model employs a Darcy idealization of the two-phase (solid-melt) system, accounting enthalpy (ΔH) as a function of temperature dependent liquid fraction (ϕ). Random thermal perturbations imposed in this model set in local convection that drive melts to flow through porosity controlled pathways with a typical mushroom-like 3D structure. We present across- and along-MOR axis model profiles to show the mode of occurrence of melt-rich zones within mushy regions, connected to deeper sources by single or multiple feeders. The upwelling of melts experiences two synchronous processes: 1) solidification-accretion, and 2) eruption, retaining a large melt fraction in the framework of mantle dynamics. Using a bifurcation analysis we determine the threshold condition for melt eruption, and estimate the potential volumes of eruptible melts (∼3.7 × 106 m3/yr) and sub-crustal solidified masses (∼1-8.8 × 106 m3/yr) on an axis length of 500 km. The solidification process far dominates over the eruption process in the initial phase, but declines rapidly on a time scale (t) of 1 Myr. Consequently, the eruption rate takes over the solidification rate, but attains nearly a steady value as t > 1.5 Myr. We finally present a melt budget, where a maximum of ∼5% of the total upwelling melt volume is available for eruption, whereas ∼19% for deeper level solidification; the rest continue to participate in the sub-crustal processes.

Angular forces and melting in bcc transition metals: A case study of molybdenum

International Nuclear Information System (INIS)

Moriarty, J.A.

1994-01-01

Both the multi-ion and effective pair potentials also permit a large amount of supercooling of the liquid before the onset of freezing. With v 2 eff a bcc structure is nucleated at freezing, while with the multi-ion potentials an amorphous glasslike structure is obtained, which appears to be related to the energetically competitive A15 structure. In our second approach to melting, the multi-ion potentials have been used to obtain accurate solid and liquid free energies from quasiharmonic lattice dynamics and MD calculations of thermal energies and pressures. The resulting ion-thermal melting curve exactly overlaps the dynamically observed melting point, indicating that no superheating of the solid occurred in our MD simulations. To obtain a full melting curve, electron-thermal contributions to the solid and liquid free energies are added in terms of the density of electronic states at the Fermi level, ρ(E F ). Here the density of states for the solid has been calculated with the linear-muffin-tin-orbital method, while for the liquid tight-binding calculations have been used to justify a simple model. In the liquid ρ(E F ) is increased dramatically over the bcc solid, and the net effect of the electron-thermal contributions is to lower the calculated melting temperatures by about a factor of 2. A full melting curve to 2 Mbar has thereby been obtained and the calculated melting properties near zero pressure are in generally good agreement with experiment

Energy demand and thermal comfort of HVAC systems with thermally activated building systems as a function of user profile

Directory of Open Access Journals (Sweden)

Pałaszyńska Katarzyna

2017-01-01

Full Text Available Thermally Activated Building Systems (TABS are a way to use building structure as a thermal energy storage. As a result, renewable energy sources may be used more efficiently. The paper presents numerical analysis of a HVAC system with TABS energy demand and indoor thermal comfort of a representative room in a non-residential building (governmental, commercial, educational. The purpose of analysis is to investigate the influence of a user profile on system performance. The time span of the analysis is one year – a typical meteorological year. The model was prepared using a generally accepted simulation tool – TRNSYS 17. The results help to better understand the interaction of a user profile with TABS. Therefore they are important for the development of optimal control algorithms for energy efficient buildings equipped with such systems.

Melt-quenched glasses of metal-organic frameworks

DEFF Research Database (Denmark)

Bennett, T.D.; Yue, Yuanzheng; Li, P.

2016-01-01

Crystalline solids dominate the field of metal−organic frameworks (MOFs), with access to the liquid and glass states of matter usually prohibited by relatively low temperatures of thermal decomposition. In this work, we give due consideration to framework chemistry and topology to expand...... of other MOFs. The glasses formed upon vitrification are chemically and structurally distinct from the three other existing categories of melt-quenched glasses (inorganic nonmetallic, organic, and metallic), and retain the basic metal−ligand connectivity of crystalline MOFs, which connects their mechanical...... the phenomenon of the melting of 3D MOFs, linking crystal chemistry to framework melting temperature and kinetic fragility of the glass-forming liquids. Here we show that melting temperatures can be lowered by altering the chemistry of the crystalline MOF state, which provides a route to facilitate the melting...

Methods for Melting Temperature Calculation

Science.gov (United States)

Hong, Qi-Jun

the melting temperature is a design criterion. We present in detail two examples of refractory materials. First, we demonstrate how key material properties that provide guidance in the design of refractory materials can be accurately determined via ab initio thermodynamic calculations in conjunction with experimental techniques based on synchrotron X-ray diffraction and thermal analysis under laser-heated aerodynamic levitation. The properties considered include melting point, heat of fusion, heat capacity, thermal expansion coefficients, thermal stability, and sublattice disordering, as illustrated in a motivating example of lanthanum zirconate (La2Zr2O7). The close agreement with experiment in the known but structurally complex compound La2Zr 2O7 provides good indication that the computation methods described can be used within a computational screening framework to identify novel refractory materials. Second, we report an extensive investigation into the melting temperatures of the Hf-C and Hf-Ta-C systems using ab initio calculations. With melting points above 4000 K, hafnium carbide (HfC) and tantalum carbide (TaC) are among the most refractory binary compounds known to date. Their mixture, with a general formula TaxHf 1-xCy, is known to have a melting point of 4215 K at the composition Ta4HfC 5, which has long been considered as the highest melting temperature for any solid. Very few measurements of melting point in tantalum and hafnium carbides have been documented, because of the obvious experimental difficulties at extreme temperatures. The investigation lets us identify three major chemical factors that contribute to the high melting temperatures. Based on these three factors, we propose and explore a new class of materials, which, according to our ab initio calculations, may possess even higher melting temperatures than Ta-Hf-C. This example also demonstrates the feasibility of materials screening and discovery via ab initio calculations for the

Crystal structure determination and thermal behavior upon melting of p-synephrine

Energy Technology Data Exchange (ETDEWEB)

Rosa, Frédéric [Unité de Technologies Chimiques et Biologiques pour la Santé, U1022 INSERM, UMR8258 CNRS, Faculté des Sciences Pharmaceutiques et Biologiques, Université Paris Descartes, Sorbonne Paris Cité, 4 Avenue de l' Observatoire, 75006 Paris (France); Négrier, Philippe [Laboratoire Ondes et Matière d' Aquitaine, Université de Bordeaux, UMR CNRS 5798, 351 cours de la Libération, 33 405 Talence Cedex (France); Corvis, Yohann [Unité de Technologies Chimiques et Biologiques pour la Santé, U1022 INSERM, UMR8258 CNRS, Faculté des Sciences Pharmaceutiques et Biologiques, Université Paris Descartes, Sorbonne Paris Cité, 4 Avenue de l' Observatoire, 75006 Paris (France); Espeau, Philippe, E-mail: philippe.espeau@parisdescartes.fr [Unité de Technologies Chimiques et Biologiques pour la Santé, U1022 INSERM, UMR8258 CNRS, Faculté des Sciences Pharmaceutiques et Biologiques, Université Paris Descartes, Sorbonne Paris Cité, 4 Avenue de l' Observatoire, 75006 Paris (France)

2016-05-20

Highlights: • The refinement of the crystal structure is achieved from X-ray powder diffraction. • P-Synephrine is revealed to be a racemic compound. • Degradation during melting can be bypassed using high DSC scan rates. • The temperature and enthalpy of melting are then proposed for this compound. - Abstract: The crystal structure of p-synephrine was solved from a high-resolution X-ray powder diffraction pattern optimized by energy-minimization calculations using the Dreiding force field. The title compound crystallizes in a monoclinic system (space group P2{sub 1}/c, Z = 4, with a = 8.8504(11) Å, b = 12.1166(15) Å, c = 9.7820(11) Å, β = 122.551(2)°, V = 884.21(19) Å{sup 3} and d = 1.256 g cm{sup −3}). Since p-synephrine degrades upon melting, its melting data were determined from DSC experiments carried out as a function of the heating rate. This method allowed determining a melting temperature and enthalpy equal to 199.8 ± 1.3 °C and 57 ± 3 kJ mol{sup −1}, respectively.

Melting and crystallization of Gesub(1-x)Tesub(x)

International Nuclear Information System (INIS)

Korzhuev, M.A.; Petrov, L.A.; Teplov, O.A.; Demenskij, G.K.

1983-01-01

The purpose of the paper is to investigate melting and crystallization processes of Gesub(1-x)Tesub(x) alloys of different composition. The alloys for investigation have been prepared from pure components using synthesis in quartz ampules during 3 hours at 1150 K with the subsequent homogenizing at 600 K during 3000 hours. Investigations have been conducted in the 750-1090 temperature range. Ranges of transformations, maximum temperature of sample heat release Tsub(max), thermal effect theta, entropy δS=theta/Tsub(max) are computed. The obtained theta and δS values agree with the data of works of other authors. Part of Ge-Te diagrams near the melting temperature, melting curves and curves of thermal degree of Atheta(T)/theta transformation during melting, crystallization and Ge separation from solid solution in alloys of different composition are presented. The results agree with phase diagram and prove mechanism of non-stoichiometric defect formation in GeTe

Study of the Formation of Eutectic Melt of Uranium and Thermal Analysis for the Salt Distillation of Uranium Deposits

International Nuclear Information System (INIS)

Park, Sung Bin; Hwang, Sung Chan; Kang, Young Ho; Park, Ki Min; Jun, Wan Gi; Lee, Han Soo; Cho, Dong Wook

2010-01-01

Uranium deposits from an electrorefining process contain about 30% salt. In order to recover pure uranium and transform it into an ingot, the salts have to be removed from the uranium deposits. Major process variables for the salt distillation process of the uranium deposits are hold temperature and vacuum pressure. Effects of the variables on the salt removal efficiency were studied in the previous study 1. By applying the Hertz-Langmuir relation to the salt evaporation of the uranium deposits, the evaporation coefficients were obtained at the various conditions. The operational conditions for achieving above 99% salt removal were deduced. The salt distilled uranium deposits tend to form the eutectic melt with iron, nickel, chromium for structural material of salt evaporator. In this study, we investigated the hold temperature limitation in order to prevent the formation of the eutectic melt between uranium and other metals. The reactions between the uranium metal and stainless steel were tested at various conditions. And for enhancing the evaporation rate of the salt and the efficient recovery of the distilled salt, the thermal analysis of the salt distiller was conducted by using commercial CFX software. From the thermal analysis, the effect of Ar gas flow on the evaporation of the salt was studied.

Temperature Profile of the Upper Mantle

International Nuclear Information System (INIS)

Anderson, O.L.

1980-01-01

Following the procedure outlined by Magnitsky [1971], thermal profiles of the upper mantle are computed by deriving the thermal gradient from the seismic data given as dv/sub s//drho used along with the values of (dv/sub s//dT9/sub p/ and (dv/sub s//dP)/sub T/ of selected minerals, measured at high temperature. The resulting values of dT/dZ are integrated from 380 km upward toward the surface, where the integrating constant is taken from Akagi and Akimoto's work, T=1400 0 C at 380 km. The resulting geotherms for minerals are used to derive geotherms for an eclogite mantle and a lherzolite mantle, with and without partial melting in the low-velocity zone. The geotherms are all subadiabatic, and some are virtually isothermal in the upper mantle. Some are characterized by a large thermal hump at the lithosphere boundary

Study of the thermal effect on silicon surface induced by ion beam from plasma focus device

Energy Technology Data Exchange (ETDEWEB)

Ahmad, Z., E-mail: pscientific5@aec.org.sy [Scientific Service Department, Atomic Energy Commission of Syria, P.O. Box: 6091, Damascus (Syrian Arab Republic); Ahmad, M. [IBA Laboratory, Atomic Energy Commission of Syria, P.O. Box: 6091, Damascus (Syrian Arab Republic); Chemistry Department, Atomic Energy Commission of Syria, P.O. Box: 6091, Damascus (Syrian Arab Republic); Al-Hawat, Sh.; Akel, M. [Physics Department, Atomic Energy Commission of Syria, P.O. Box: 6091, Damascus (Syrian Arab Republic)

2017-04-01

Structural modifications in form of ripples and cracks are induced by nitrogen ions from plasma focus on silicon surface. The investigation of such structures reveals correlation between ripples and cracks formation in peripheral region of the melt spot. The reason of such correlation and structure formation is explained as result of thermal effect. Melting and resolidification of the center of irradiated area occur within one micro second of time. This is supported by a numerical simulation used to investigate the thermal effect induced by the plasma focus ion beams on the silicon surface. This simulation provides information about the temperature profile as well as the dynamic of the thermal propagation in depth and lateral directions. In accordance with the experimental observations, that ripples are formed in latter stage after the arrival of last ion, the simulation shows that the thermal relaxation takes place in few microseconds after the end of the ion beam arrival. Additionally, the dependency of thermal propagation and relaxation on the distance of the silicon surface from the anode is presented.

Interface Shape and Convection During Solidification and Melting of Succinonitrile

Science.gov (United States)

Degroh, Henry C., III; Lindstrom, Tiffany

1994-01-01

An experimental study was conducted of the crystal growth of succinonitrile during solidification, melting, and no-growth conditions using a horizontal Bridgman furnace and square glass ampoule. For use as input boundary conditions to numerical codes, thermal profiles on the outside of the ampoule at five locations around its periphery were measured along the ampoule's length. Temperatures inside the ampoule were also measured. The shapes of the s/l interface in various two dimensional planes were quantitatively determined. Though interfaces were nondendritic and noncellular, they were not flat, but were highly curved and symmetric in only one unique longitudinal y-z plane (at x=O). The shapes of the interface were dominated by the primary longitudinal flow cell characteristic of shallow cavity flow in horizontal Bridgman; this flow cell was driven by the imposed furnace temperature gradient and caused a 'radical' thermal gradient such that the upper half of the ampoule was hotter than the bottom half. We believe that due to the strong convection, the release of latent heat does not significantly influence the thermal conditions near the interface. We hope that the interface shape and thermal data presented in this paper can be used to optimize crystal growth processes and validate numerical models.

Cellular scanning strategy for selective laser melting: Evolution of optimal grid-based scanning path & parametric approach to thermal homogeneity

DEFF Research Database (Denmark)

Mohanty, Sankhya; Tutum, Cem Celal; Hattel, Jesper Henri

2013-01-01

Selective laser melting, as a rapid manufacturing technology, is uniquely poised to enforce a paradigm shift in the manufacturing industry by eliminating the gap between job- and batch-production techniques. Products from this process, however, tend to show an increased amount of defects such as ...... strategy has been developed for processing the standard sample, one unit cell at a time, using genetic algorithms, with an objective of reducing thermal asymmetries. © 2013 SPIE....

Pavement Snow Melting

Energy Technology Data Exchange (ETDEWEB)

Lund, John W.

2005-01-01

The design of pavement snow melting systems is presented based on criteria established by ASHRAE. The heating requirements depends on rate of snow fall, air temperature, relative humidity and wind velocity. Piping materials are either metal or plastic, however, due to corrosion problems, cross-linked polyethylene pipe is now generally used instead of iron. Geothermal energy is supplied to systems through the use of heat pipes, directly from circulating pipes, through a heat exchanger or by allowing water to flow directly over the pavement, by using solar thermal storage. Examples of systems in New Jersey, Wyoming, Virginia, Japan, Argentina, Switzerland and Oregon are presented. Key words: pavement snow melting, geothermal heating, heat pipes, solar storage, Wyoming, Virginia, Japan, Argentina, Klamath Falls.

Investigation of the Dynamic Melting Process in a Thermal Energy Storage Unit Using a Helical Coil Heat Exchanger

Directory of Open Access Journals (Sweden)

Xun Yang

2017-08-01

Full Text Available In this study, the dynamic melting process of the phase change material (PCM in a vertical cylindrical tube-in-tank thermal energy storage (TES unit was investigated through numerical simulations and experimental measurements. To ensure good heat exchange performance, a concentric helical coil was inserted into the TES unit to pipe the heat transfer fluid (HTF. A numerical model using the computational fluid dynamics (CFD approach was developed based on the enthalpy-porosity method to simulate the unsteady melting process including temperature and liquid fraction variations. Temperature measurements using evenly spaced thermocouples were conducted, and the temperature variation at three locations inside the TES unit was recorded. The effects of the HTF inlet parameters were investigated by parametric studies with different temperatures and flow rate values. Reasonably good agreement was achieved between the numerical prediction and the temperature measurement, which confirmed the numerical simulation accuracy. The numerical results showed the significance of buoyancy effect for the dynamic melting process. The system TES performance was very sensitive to the HTF inlet temperature. By contrast, no apparent influences can be found when changing the HTF flow rates. This study provides a comprehensive solution to investigate the heat exchange process of the TES system using PCM.

Using Paraffin with -10 deg C to 10 deg C Melting Point for Payload Thermal Energy Storage in SpaceX Dragon Trunk

Science.gov (United States)

Choi, Michael K.

2013-01-01

A concept of using paraffin wax phase change material (PCM) with a melting point between -10 deg C and 10 deg C for payload thermal energy storage in a Space Exploration Technologies (SpaceX) Dragon trunk is presented. It overcomes the problem of limited heater power available to a payload with significant radiators when the Dragon is berthed to the International Space Station (ISS). It stores adequate thermal energy to keep a payload warm without power for 6 hours during the transfer from the Dragon to an ExPRESS logistics carrier (ELC) on the ISS.

Studies of pulsed laser melting and rapid solidification using amorphous silicon

International Nuclear Information System (INIS)

Lowndes, D.H.; Wood, R.F.

1984-06-01

Pulsed-laser melting of ion implantation-amorphized silicon layers, and subsequent solidification were studied. Measurements of the onset of melting of amorphous silicon layers and of the duration of melting, and modified melting model calculations demonstrated that the thermal conductivity, K/sub a/, of amorphous silicon is very low (K/sub a/ approx. = 0.02 W/cm-K). K/sub a/ is also the dominant parameter determining the dynamical response of amorphous silicon to pulsed laser radiation. TEM indicates that bulk (volume) nucleation occurs directly from the highly undercooled liquid silicon that can be prepared by pulsed laser melting of amorphous silicon layers at low laser energy densities. A modified thermal melting model is presented. The model calculations demonstrate that the release of latent heat by bulk nucleation occurring during the melt-in process is essential to obtaining agreement with observed depths of melting. These calculations also show that this release of latent heat accompanying bulk nucleation can result in the existence of buried molten layers of silicon in the interior of the sample after the surface has solidified. The bulk nucleation implies that the liquid-to-amorphous phase transition (produced using picosecond or uv nanosecond laser pulses) cannot be explained using purely thermodynamic considerations

The thermal properties of beeswaxes: unexpected findings.

Science.gov (United States)

Buchwald, Robert; Breed, Michael D; Greenberg, Alan R

2008-01-01

Standard melting point analyses only partially describe the thermal properties of eusocial beeswaxes. Differential scanning calorimetry (DSC) revealed that thermal phase changes in wax are initiated at substantially lower temperatures than visually observed melting points. Instead of a sharp, single endothermic peak at the published melting point of 64 degrees C, DSC analysis of Apis mellifera Linnaeus wax yielded a broad melting curve that showed the initiation of melting at approximately 40 degrees C. Although Apis beeswax retained a solid appearance at these temperatures, heat absorption and initiation of melting could affect the structural characteristics of the wax. Additionally, a more complete characterization of the thermal properties indicated that the onset of melting, melting range and heat of fusion of beeswaxes varied significantly among tribes of social bees (Bombini, Meliponini, Apini). Compared with other waxes examined, the relatively malleable wax of bumblebees (Bombini) had the lowest onset of melting and lowest heat of fusion but an intermediate melting temperature range. Stingless bee (Meliponini) wax was intermediate between bumblebee and honeybee wax (Apini) in heat of fusion, but had the highest onset of melting and the narrowest melting temperature range. The broad melting temperature range and high heat of fusion in the Apini may be associated with the use of wax comb as a free-hanging structural material, while the Bombini and Meliponini support their wax structures with exogenous materials.

Modeling of nuclear waste disposal by rock melting

International Nuclear Information System (INIS)

Heuze, F.E.

1982-04-01

Today, the favored option for disposal of high-level nuclear wastes is their burial in mined caverns. As an alternative, the concept of deep disposal by rock melting (DRM) also has received some attention. DRM entails the injection of waste, in a cavity or borehole, 2 to 3 kilometers down in the earth crust. Granitic rocks are the prime candidate medium. The high thermal loading initially will melt the rock surrounding the waste. Following resolidification, a rock/waste matrix is formed, which should provide isolation for many years. The complex thermal, mechanical, and hydraulic aspects of DRM can be studied best by means of numerical models. The models must accommodate the coupling of the physical processes involved, and the temperature dependency of the granite properties, some of which are subject to abrupt discontinuities, during α-β phase transition and melting. This paper outlines a strategy for such complex modeling

Theoretical investigations on the fragmentation of drops of melt with respect to the description of thermal detonations (vapor explosions) and their application in the code Frademo

International Nuclear Information System (INIS)

Burger, M.; Carachalios, C.; Kim, D.S.; Unger, H.

1986-01-01

Vapor explosions caused by the contact of molten core material with coolant are an important issue within reactor safety analysis, because they could produce an early threat to the containment during a core melt accident. The case of steady-state propagation of a detonation wave through a coarse premixture of melt and coolant represents the most severe case of a large scale vapor explosion under reactor conditions with the highest rate and largest heat release and therefore also the highest yield of mechanical energy. The present contribution starts with the description of the integral model of the detonation wave. The fragmentation processes, which are decisive for these exchange terms and the detonation process as a whole, are dealt with also. Hydrodynamic fragmentation processes as well as a thermally induced one are considered. The processes which take place inside a detonation wave, especially the fragmentation of the drops of melt and the velocity equilibration between the melt and the coolant, determine the behavior of the wave. In the present model these processes are described within a three-phase approach, considering the drops of melt, the fragments and the coolant as separate flow phases. In the frame of this work, the computer code FRADEMO has been developed. It consists of an overall description of the processes inside a steady-state detonation wave in combination with a full description of the detailed models on hydrodynamic and thermal fragmentation presented in this report. Some useful information for the potential code user is given in the appendix of the detailed report also

Thermal equilibrium defects in anthracene probed by positron annihilation

International Nuclear Information System (INIS)

Uedono, Akira; Tanigawa, Shoichiro; Tachibana, Masaru; Shimizu, Mikio; Satoh, Masaaki; Kojima, Kenichi; Ishibashi, Shoji; Kawano, Takao.

1996-01-01

Defects in anthracene were investigated by the positron annihilation technique. Doppler broadening profiles of the annihilation radiation and lifetime spectra of positrons were measured in the temperature range between 305 K and 516 K. The lifetime of positrons annihilated from the delocalized state was determined to be 0.306 ns around room temperature. Below the melting point, the observed temperature dependence of the line shape parameter S was explained assuming the formation energy of thermal equilibrium defects was 1 eV. Above the melting point, the pick-off annihilation of ortho-positronium in open spaces was observed, where the size of these spaces was estimated to be 0.2 nm 3 . The annihilation of positrons from the self-trapped state was also discussed. (author)

Thermal equilibrium defects in anthracene probed by positron annihilation

Energy Technology Data Exchange (ETDEWEB)

Uedono, Akira; Tanigawa, Shoichiro [Tsukuba Univ., Ibaraki (Japan). Inst. of Materials Science; Tachibana, Masaru; Shimizu, Mikio; Satoh, Masaaki; Kojima, Kenichi; Ishibashi, Shoji; Kawano, Takao

1996-06-01

Defects in anthracene were investigated by the positron annihilation technique. Doppler broadening profiles of the annihilation radiation and lifetime spectra of positrons were measured in the temperature range between 305 K and 516 K. The lifetime of positrons annihilated from the delocalized state was determined to be 0.306 ns around room temperature. Below the melting point, the observed temperature dependence of the line shape parameter S was explained assuming the formation energy of thermal equilibrium defects was 1 eV. Above the melting point, the pick-off annihilation of ortho-positronium in open spaces was observed, where the size of these spaces was estimated to be 0.2 nm{sup 3}. The annihilation of positrons from the self-trapped state was also discussed. (author)

Mechanical properties of melt-derived erbium oxide

International Nuclear Information System (INIS)

Neuman, A.D.; Blacic, M.J.; Platero, M.; Romero, R.S.; McClellan, K.J.; Petrovic, J.J.

1998-01-01

Erbium oxide (Er 2 O 3 ) is a rare earth oxide that is chemically and thermally stable and has a melting point of 2,430 C. There is relatively little information available regarding single crystal growth of erbia or the properties of erbia. In this study, erbia single crystals have been grown in a Xenon Optical Floating Zone Unit (XeOFZ) capable of melting materials at temperatures up to 3,000 C. Erbia was melt synthesized in the XeOFZ unit in a container less fashion, proving for little chance of contamination. Crystals were grown in compressed air and in reducing atmospheres. A recurring problem with melt synthesis of erbia is the appearance of flakes at the edges of the melt zone during growth; these flakes disrupt the growth process. The processing details and an initial survey of the physical properties of erbia single crystals is discussed

Shock induced melting of lead (experimental study)

International Nuclear Information System (INIS)

Mabire, Catherine; Hereil, Pierre L.

2002-01-01

To investigate melting on release of lead, two shock compression measurements have been carried out at 51 GPa. In the first one, a pyrometric measurement has been performed at the Pb/LiF interface. In the second one, the Pb/LiF interface velocity has been recorded using VISAR measurement technique. VISAR and radiance profile are in good agreement and seem to show melting on release of lead

Determination of the ion thermal diffusivity from neutron emission profiles in decay

International Nuclear Information System (INIS)

Sasao, M.; Adams, J.M.; Conroy, S.; Jarvis, O.N.; Marcus, F.B.; Sadler, G.; Belle, P. van

1994-01-01

Spatial profiles of the neutron emission from deuterium plasmas are routinely obtained at the Joint European Torus (JET) using the line-integrated signals measured with a multichannel instrument. It is shown that the manner in which these profiles relax following the termination of strong heating with neutral beam injection (NBI) permits the local thermal diffusivity (χ i ) to be obtained with an accuracy of about 20%. (author)

Modeling of Thickness and Profile Uniformity of Thermally Sprayed Coatings Deposited on Cylinders

Science.gov (United States)

Yanjun, Zhang; Wenbo, Li; Dayu, Li; Jinkun, Xiao; Chao, Zhang

2018-02-01

In thermal spraying processes, kinematic parameters of the robot play a decisive role in the coating thickness and profile. In this regard, some achievements have been made to optimize the spray trajectory on flat surfaces. However, few reports have focused on nonholonomic or variable-curvature cylindrical surfaces. The aim of this study is to investigate the correlation between the coating profile, coating thickness, and scanning step, which is determined by the radius of curvature and scanning angle. A mathematical simulation model was developed to predict the thickness of thermally sprayed coatings. Experiments were performed on cylinders with different radiuses of curvature to evaluate the predictive ability of the model.

Simulation of core melt spreading with lava: theoretical background and status of validation

International Nuclear Information System (INIS)

Allelein, H.-J.; Breest, A.; Spengler, C.

2000-01-01

The goal of this paper is to present the GRS R and D achievements and perspectives of its approach to simulate ex-vessel core melt spreading. The basic idea followed by GRS is the analogy of core melt spreading to volcanic lava flows. A fact first proposed by Robson (1967) and now widely accepted is that lava rheologically behaves as a Bingham fluid, which is characterized by yield stress and plastic viscosity. Recent experimental investigations by Epstein (1996) reveal that corium-concrete mixtures may be described as Bingham fluids. The GRS code LAVA is based on a successful lava flow model, but is adapted to prototypic corium and corium-simulation spreading. Furthermore some detailed physical models such as a thermal crust model on the free melt surface and a model for heat conduction into the substratum are added. Heat losses of the bulk, which is represented by one mean temperature, are now determined by radiation and by temperature profiles in the upper crust and in the substratum. In order to reduce the weak mesh dependence of the original algorithm, a random space method of cellular automata is integrated, which removes the mesh bias without increasing calculation time. LAVA is successfully validated against a lot of experiments using different materials spread. The validation process has shown that LAVA is a robust and fast running code to simulate corium-type spreading. LAVA provides all integral information of practical interest (spreading length, height of the melt after stabilization) and seems to be an appropriate tool for handling large core melt masses within a plant application. (orig.)

Manipulation and simulations of thermal field profiles in laser heat-mode lithography

Science.gov (United States)

Wei, Tao; Wei, Jingsong; Wang, Yang; Zhang, Long

2017-12-01

Laser heat-mode lithography is a very useful method for high-speed fabrication of large-area micro/nanostructures. To obtain nanoscale pattern structures, one needs to manipulate the thermal diffusion channels. This work reports the manipulation of the thermal diffusion in laser heat-mode lithography and provides methods to restrain the in-plane thermal diffusion and improve the out-of-plane thermal diffusion. The thermal field profiles in heat-mode resist thin films have been given. It is found that the size of the heat-spot can be decreased by decreasing the thickness of the heat-mode resist thin films, inserting the thermal conduction layers, and shortening the laser irradiation time. The optimized laser writing strategy is also given, where the in-plane thermal diffusion is completely restrained and the out-of-plane thermal diffusion is improved. The heat-spot size is almost equal to that of the laser spot, accordingly. This work provides a very important guide to laser heat-mode lithography.

Thermal, Mechanical and UV-Shielding Properties of Poly(Methyl Methacrylate/Cerium Dioxide Hybrid Systems Obtained by Melt Compounding

Directory of Open Access Journals (Sweden)

María A. Reyes-Acosta

2015-09-01

Full Text Available Thick and homogeneous hybrid film systems based on poly(methyl methacrylate (PMMA and CeO2 nanoparticles were synthesized using the melt compounding method to improve thermal stability, mechanical and UV-shielding properties, as well as to propose them for use in the multifunctional materials industry. The effect of the inorganic phase on these properties was assessed by using two different weight percentages of synthesized CeO2 nanoparticles (0.5 and 1.0 wt % with the sol–gel method and thermal treatment at different temperatures (120, 235, 400, 600 and 800 °C. Thereafter, the nanoceria powders were added to the polymer matrix by single screw extrusion. The absorption in the UV region was increased with the crystallite size of the CeO2 nanoparticles and the PMMA/CeO2 weight ratio. Due to the crystallinity of CeO2 nanoparticles, the thermal, mechanical and UV-shielding properties of the PMMA matrix were improved. The presence of CeO2 nanostructures exerts an influence on the mobility of PMMA chain segments, leading to a different glass transition temperature.

Chip-carrier thermal barrier and its impact on lateral thermal lens profile and beam parameter product in high power broad area lasers

Science.gov (United States)

Rieprich, J.; Winterfeldt, M.; Kernke, R.; Tomm, J. W.; Crump, P.

2018-03-01

High power broad area diode lasers with high optical power density in a small focus spot are in strong commercial demand. For this purpose, the beam quality, quantified via the beam parameter product (BPP), has to be improved. Previous studies have shown that the BPP is strongly affected by current-induced heating and the associated thermal lens formed within the laser stripe. However, the chip structure and module-assembly related factors that regulate the size and the shape of the thermal lens are not well known. An experimental infrared thermographic technique is used to quantify the thermal lens profile in diode lasers operating at an emission wavelength of 910 nm, and the results are compared with finite element method simulations. The analysis indicates that the measured thermal profiles can best be explained when a thermal barrier is introduced between the chip and the carrier, which is shown to have a substantial impact on the BPP and the thermal resistance. Comparable results are observed in further measurements of samples from multiple vendors, and the barrier is only observed for junction-down (p-down) mounting, consistent with the barrier being associated with the GaAs-metal transition.

Thermal integrity profiling for augered cast-in-place piles - implementation plan.

Science.gov (United States)

2017-08-01

This study was the second in a two-part research program focused on assessing the feasibility of using thermal integrity profiling (TIP) as a quality assurance tool for Augered Cast-In-Place (ACIP) piles. This was made possible by coordinating with t...

Physical mechanisms of thermal-diffusivity depth-profile generation in a hardened low-alloy Mn, Si, Cr, Mo steel reconstructed by photothermal radiometry

International Nuclear Information System (INIS)

Nicolaides, Lena; Mandelis, Andreas; Beingessner, Clare J.

2001-01-01

It is well established that in hardened steels thermal-diffusivity broadly anticorrelates with microhardness, allowing thermal-wave depth profilometry to be used as a tool to measure microhardness profiles. Nevertheless, the physical mechanisms for this anticorrelation have not been well understood. In this work, the thermal-diffusivity profiles of rough, hardened industrial steels were reconstructed after the elimination of roughness effects from the experimental data. Carburizing and quenching are widely used for the heat treatment of steel components, and it is important to understand their effects on thermal-diffusivity profiles. A thorough examination of the actual mechanism by which thermal-diffusivity depth profiles are affected by first carburizing and then quenching AISI-8620 steels was performed. It was concluded that the variation of thermal diffusivity with depth is dominated by the carbon concentration profile, whereas the absolute value of the thermal diffusivity is a function of microstructure. [copyright] 2001 American Institute of Physics

Determination of the ion thermal diffusivity from neutron emission profiles in decay

Energy Technology Data Exchange (ETDEWEB)

Sasao, M. (National Inst. for Fusion Science, Nagoya (Japan)); Adams, J.M. (AEA Industrial Technology, Harwell (United Kingdom)); Conroy, S.; Jarvis, O.N.; Marcus, F.B.; Sadler, G.; Belle, P. van (Commission of the European Communities, Abingdon (United Kingdom). JET Joint Undertaking)

1994-01-01

Spatial profiles of the neutron emission from deuterium plasmas are routinely obtained at the Joint European Torus (JET) using the line-integrated signals measured with a multichannel instrument. It is shown that the manner in which these profiles relax following the termination of strong heating with neutral beam injection (NBI) permits the local thermal diffusivity ([chi][sub i]) to be obtained with an accuracy of about 20%. (author).

Lattice thermal conductivity of silicate glasses at high pressures

Science.gov (United States)

Chang, Y. Y.; Hsieh, W. P.

2016-12-01

Knowledge of the thermodynamic and transport properties of magma holds the key to understanding the thermal evolution and chemical differentiation of Earth. The discovery of the remnant of a deep magma ocean above the core mantle boundary (CMB) from seismic observations suggest that the CMB heat flux would strongly depend on the thermal conductivity, including lattice (klat) and radiative (krad) components, of dense silicate melts and major constituent minerals around the region. Recent measurements on the krad of dense silicate glasses and lower-mantle minerals show that krad of dense silicate glasses could be significantly smaller than krad of the surrounding solid mantle phases, and therefore the dense silicate melts would act as a thermal insulator in deep lower mantle. This conclusion, however, remains uncertain due to the lack of direct measurements on the lattice thermal conductivity of silicate melts under relevant pressure-temperature conditions. Besides the CMB, magmas exist in different circumstances beneath the surface of the Earth. Chemical compositions of silicate melts vary with geological and geodynamic settings of the melts and have strong influences on their thermal properties. In order to have a better view of heat transport within the Earth, it is important to study compositional and pressure dependences of thermal properties of silicate melts. Here we report experimental results on lattice thermal conductivities of silicate glasses with basaltic and rhyolitic compositions up to Earth's lower mantle pressures using time-domain thermoreflectance coupled with diamond-anvil cell techniques. This study not only provides new data for the thermal conductivity of silicate melts in the Earth's deep interior, but is crucial for further understanding of the evolution of Earth's complex internal structure.

Determination of hydrogen in zirconium and its alloys by melt extraction under carrier gas flow using thermal conductivity cell as detector

International Nuclear Information System (INIS)

Akhtar, J.; Ahmed, M.; Mohammad, B.; Jan, S.; Waqar, F.

1987-06-01

In the production of zirconium metal and its alloys the presence of hydrogen impurity affects mechanical and corrosion resistance properties of the product. Therefore, determination of hydrogen contents of the product is necessary. Conditions for its analysis by melt extraction under carrier gas stream using thermal conductivity cell as detector were studied and optimised. The method is capable of measuring hydrogen impurity in parts per million range. (author)

Product differentiation by analysis of DNA melting curves during the polymerase chain reaction.

Science.gov (United States)

Ririe, K M; Rasmussen, R P; Wittwer, C T

1997-02-15

A microvolume fluorometer integrated with a thermal cycler was used to acquire DNA melting curves during polymerase chain reaction by fluorescence monitoring of the double-stranded DNA specific dye SYBR Green I. Plotting fluorescence as a function of temperature as the thermal cycler heats through the dissociation temperature of the product gives a DNA melting curve. The shape and position of this DNA melting curve are functions of the GC/AT ratio, length, and sequence and can be used to differentiate amplification products separated by less than 2 degrees C in melting temperature. Desired products can be distinguished from undesirable products, in many cases eliminating the need for gel electrophoresis. Analysis of melting curves can extend the dynamic range of initial template quantification when amplification is monitored with double-stranded DNA specific dyes. Complete amplification and analysis of products can be performed in less than 15 min.

Thermal property prediction and measurement of organic phase change materials in the liquid phase near the melting point

International Nuclear Information System (INIS)

O’Connor, William E.; Warzoha, Ronald; Weigand, Rebecca; Fleischer, Amy S.; Wemhoff, Aaron P.

2014-01-01

Highlights: • Liquid-phase thermal properties for five phase change materials were estimated. • Various liquid phase and phase transition thermal properties were measured. • The thermal diffusivity was found using a best path to prediction approach. • The thermal diffusivity predictive method shows 15% agreement for organic PCMs. - Abstract: Organic phase change materials (PCMs) are a popular choice for many thermal energy storage applications including solar energy, building envelope thermal barriers, and passive cooling of portable electronics. Since the extent of phase change during a heating or cooling process is dependent upon rapid thermal penetration into the PCM, accurate knowledge of the thermal diffusivity of the PCM in both solid and liquid phases is crucial. This study addresses the existing gaps in information for liquid-phase PCM properties by examining an approach that determines the best path to prediction (BPP) for the thermal diffusivity of both alkanes and unsaturated acids. Knowledge of the BPP will enable researchers to explore the influence of PCM molecular structure on bulk thermophysical properties, thereby allowing the fabrication of optimized PCMs. The BPP method determines which of the tens of thousands of combinations of 22 different available theoretical techniques provides best agreement with thermal diffusivity values based on reported or measured density, heat capacity, and thermal conductivity for each of five PCMs (heneicosane, tricosane, tetracosane, oleic acid, and linoleic acid) in the liquid phase near the melting point. Separate BPPs were calibrated for alkanes based on heneicosane and tetracosane, and for the unsaturated acids. The alkane and unsaturated acid BPPs were then tested on a variety of similar materials, showing agreement with reported/measured thermal diffusivity within ∼15% for all materials. The alkane BPP was then applied to find that increasing the length of alkane chains decreases the PCM thermal

Nuclear waste management by in-situ melting

International Nuclear Information System (INIS)

Angelo, J.A. Jr.

1976-01-01

A systematic assessment of the in-situ melting concept as an ultimate waste disposal option shows that the placement of solidifed, high-level radioactive wastes in an in-situ melting cavity with a crushed rock backfill not only eliminates the major deficiencies inherent in other in-situ melting schemes, but also satisfies reasonable criteria for ultimate disposal. In-situ melting reduces the waste isolation time requirements to several hundred years. Calculated spent fuel and processing waste afterheat values assess the role of actinide and cladding material nuclides in creating the total afterheat and provide quantitative variation with time for these values for contamporary and advanced-design fission reactors. The dominant roles of 134 Cs in thermal spectrum reactor afterheats during the first decade of cooling of the actinide nuclides in all typical waste after-heats following a century or two of cooling are identified. The spatial and temporal behavior of a spherically symmetric waste repository experiencing in-situ melting in an equal density, homogeneous medium for silicate rock and salt is controlled primarily by the overall volumetric thermal source strength, the time-dependent characteristics of the high-level wastes, and the thermophysical properties of the surrounding rock environment. Calculations were verified by experimental data. The hazard index for typical high-level wastes is dominated by the fission product nuclides for the first three centuries of decay. It is then controlled by the actinides, especially americium, which dominates for 10,000 years. With in-situ melting, the hazard index for the re-solidifed rock/waste matrix deepunderground falls below the hazard index of naturally occurring uranium ore bodies within a few hundred years, whether or not the more hazardous actinide nuclides are selectively removed from the wastes prior to storage

Thermodynamic study of sublimation, melting and vaporization of scandium(III) dipivaloylmethanate derivatives

International Nuclear Information System (INIS)

Zherikova, Kseniya V.; Zelenina, Ludmila N.; Chusova, Tamara P.; Gelfond, Nikolay V.; Morozova, Natalia B.

2016-01-01

Highlights: • Thermal properties of two volatile fluorinated Sc(III) beta-diketonates were studied. • Saturated and unsaturated vapor pressures were measured. • DSC analysis was carried out. • Sublimation, evaporation and melting enthalpies and entropies were derived. • Effect of fluorine introduction on volatility and thermal stability was established. - Abstract: The present work deals with the investigation of thermal properties of two volatile scandium(III) beta-diketonates with 2,2,6,6-tetramethyl-4-fluoro-3,5-heptanedione and 1,1,1-trifluoro-5,5-dimethyl-2,4-hexanedione which have been synthesized and purified. Using the static method with glass membrane gauge-manometer the temperature dependencies of saturated and unsaturated vapor pressure were measured for the first time. The temperatures and enthalpies of melting were measured for these compounds by differential scanning calorimetry. The standard thermodynamic characteristics of enthalpy and entropy for sublimation, vaporization and melting processes were derived.

[The measurement of thermal expansion coefficient of Co-Cr alloy fabricated by selective laser melting].

Science.gov (United States)

Tian, Xiao-mei; Zeng, Li; Wei, Bin; Huang, Yi-feng

2015-12-01

To investigate the thermal expansion coefficient of different processing parameters upon the Co-Cr alloy prepared by selective laser melting (SLM) technique, in order to provide technical support for clinical application of SLM technology. The heating curve of self-made Co-Cr alloy was protracted from room temperature to 980°C centigrade with DIL402PC thermal analysis instrument, keeping temperature rise rate and cooling rate at 5 K/min, and then the thermal expansion coefficient of 9 groups of Co-Cr alloy was measured from 20°C centigrade to 500°C centigrade and 600°C centigrade. The 9 groups thermal expansion coefficient values of Co-Cr alloy heated from 20°C centigrade to 500°C centigrade were 13.9×10(-6)/K,13.6×10(-6)/K,13.9×10(-6)/K,13.7×10(-6)/K,13.5×10(-6)/K,13.8×10(-6)/K,13.7×10(-6)/K,13.7×10(-6)/K,and 13.9×10(-6)/K, respectively; when heated from 20°C centigrade to 600°C centigrade, they were 14.2×10(-6)/K,13.9×10(-6)/K,13.8×10(-6)/K,14.0×10(-6)/K,14.1×10(-6)/K,14.1×10(-6)/K,13.9×10(-6)/K,14.2×10(-6)/K, and 13.7×10(-6)/K, respectively. The results showed that the Co-Cr alloy has good matching with the VITA VMK 95 porcelain powder and can meet the requirement of clinic use.

Effect of thermal-treatment sequence on sound absorbing and mechanical properties of porous sound-absorbing/thermal-insulating composites

Directory of Open Access Journals (Sweden)

Huang Chen-Hung

2016-01-01

Full Text Available Due to recent rapid commercial and industrial development, mechanical equipment is supplemented massively in the factory and thus mechanical operation causes noise which distresses living at home. In livelihood, neighborhood, transportation equipment, jobsite construction noises impact on quality of life not only factory noise. This study aims to preparation technique and property evaluation of porous sound-absorbing/thermal-insulating composites. Hollow three-dimensional crimp PET fibers blended with low-melting PET fibers were fabricated into hollow PET/low-melting PET nonwoven after opening, blending, carding, lapping and needle-bonding process. Then, hollow PET/low-melting PET nonwovens were laminated into sound-absorbing/thermal-insulating composites by changing sequence of needle-bonding and thermal-treatment. The optimal thermal-treated sequence was found by tensile strength, tearing strength, sound-absorbing coefficient and thermal conductivity coefficient tests of porous composites.

Grain structure evolution in Inconel 718 during selective electron beam melting

Energy Technology Data Exchange (ETDEWEB)

Helmer, H.; Bauereiß, A., E-mail: Andreas.Bauereiss@fau.de; Singer, R.F.; Körner, C.

2016-06-21

Selective electron beam melting (SEBM) is an additive manufacturing method where complex parts are built from metal powders in layers of typically 50 µm. An electron beam is used for heating (about 900 °C building temperature) and selective melting of the material. The grain structure evolution is a result of the complex thermal and hydrodynamic conditions in the melt pool. We show how different scanning strategies can be used to produce either a columnar grain structure with a high texture in building direction or an equiaxed fine grained structure. Numerical simulations of the selective melting process are applied to study the fundamental mechanisms responsible for differing grain structures. It is shown, that the direction of the thermal gradient during solidification can be altered by scanning strategies to acquire either epitaxial growth or stray grains. We show that it is possible to locally alter the grain structure of a part, thus allowing tailoring of the mechanical properties.

Strong morphological and crystallographic texture and resulting yield strength anisotropy in selective laser melted tantalum

International Nuclear Information System (INIS)

Thijs, Lore; Montero Sistiaga, Maria Luz; Wauthle, Ruben; Xie, Qingge; Kruth, Jean-Pierre; Van Humbeeck, Jan

2013-01-01

Selective laser melting (SLM) makes use of a high energy density laser beam to melt successive layers of metallic powders in order to create functional parts. The energy density of the laser is high enough to melt refractory metals like Ta and produce mechanically sound parts. Furthermore, the localized heat input causes a strong directional cooling and solidification. Epitaxial growth due to partial remelting of the previous layer, competitive growth mechanism and a specific global direction of heat flow during SLM of Ta result in the formation of long columnar grains with a 〈1 1 1〉 preferential crystal orientation along the building direction. The microstructure was visualized using both optical and scanning electron microscopy equipped with electron backscattered diffraction and the global crystallographic texture was measured using X-ray diffraction. The thermal profile around the melt pool was modeled using a pragmatic model for SLM. Furthermore, rotation of the scanning direction between different layers was seen to promote the competitive growth. As a result, the texture strength increased to as large as 4.7 for rotating the scanning direction 90° every layer. By comparison of the yield strength measured by compression tests in different orientations and the averaged Taylor factor calculated using the viscoplastic self-consistent model, it was found that both the morphological and crystallographic texture observed in SLM Ta contribute to yield strength anisotropy

Research of Snow-Melt Process on a Heated Platform

Directory of Open Access Journals (Sweden)

Vasilyev Gregory P.

2016-01-01

Full Text Available The article has shown the results of experimental researches of the snow-melt on a heated platform-near building heat-pump snow-melt platform. The near-building (yard heat pump platforms for snow melt with the area up to 10-15 m2 are a basis of the new ideology of organization of the street cleaning of Moscow from snow in the winter period which supposes the creation in the megalopolis of the «distributed snow-melt system» (DSMS using non-traditional energy sources. The results of natural experimental researches are presented for the estimation of efficiency of application in the climatic conditions of Moscow of heat pumps in the snow-melt systems. The researches were conducted on a model sample of the near-building heat-pump platform which uses the low-potential thermal energy of atmospheric air. The conducted researches have confirmed experimentally in the natural conditions the possibility and efficiency of using of atmospheric air as a source of low-potential thermal energy for evaporation of the snow-melt heat pump systems in the climatic conditions of Moscow. The results of laboratory researches of snow-melt process on a heated horizontal platform are presented. The researches have revealed a considerable dependence of efficiency of the snow-melt process on its piling mode (form-building and the organization of the process of its piling mode (form-building and the organization of the process of its (snow mass heat exchange with the surface of the heated platform. In the process of researches the effect of formation of an «ice dome» under the melting snow mass called by the fact that in case of the thickness of snow loaded on the platform more than 10 cm the water formed from the melting snow while the contact with the heating surface don’t spread on it, but soaks into the snow, wets it due to capillary effect and freezes. The formation of «ice dome» leads to a sharp increase of snow-melt period and decreases the operating

Water, lithium and trace element compositions of olivine from Lanzo South replacive mantle dunites (Western Alps): New constraints into melt migration processes at cold thermal regimes

Science.gov (United States)

Sanfilippo, Alessio; Tribuzio, Riccardo; Ottolini, Luisa; Hamada, Morihisa

2017-10-01

Replacive mantle dunites are considered to be shallow pathways for extraction of mantle melts from their source region. Dunites offer a unique possibility to unravel the compositional variability of the melts produced in the upper mantle, before mixing and crystal fractionation modify their original signature. This study includes a quantification of H2O, Li and trace elements (Ni, Mn, Co, Sc, V, Ti, Zr, Y and HREE) in olivine from large replacive dunite bodies (>20 m) within a mantle section exposed in the Western Italian Alps (Lanzo South ophiolite). On the basis of olivine, clinopyroxene and spinel compositions, these dunites were previously interpreted to be formed by melts with a MORB signature. Variations in Ni, Mn, Co and Ca contents in olivine from different dunite bodies suggested formation by different melt batches. The variable H2O and Li contents of these olivines agree with this idea. Compared to olivine from residual peridotites and olivine phenocrysts in MORB (both having H2O 1 ppm), the Lanzo South dunite olivine has high H2O (18-40 ppm) and low Li (0.35-0.83 ppm) contents. Geochemical modelling suggests that the dunite-forming melts were produced by low melting degrees of a mixed garnet-pyroxenite-peridotite mantle source, with a contribution of a garnet pyroxenite component variable from 20 to 80%. The Lanzo dunites experienced migration of melts geochemically enriched and mainly produced in the lowermost part of the melting region. Extraction of enriched melts through dunite channels are probably characteristic of cold thermal regimes, where low temperatures and a thick mantle lithosphere inhibit mixing with melts produced at shallower depths.

A Dynamic Mesh-Based Approach to Model Melting and Shape of an ESR Electrode

Science.gov (United States)

Karimi-Sibaki, E.; Kharicha, A.; Bohacek, J.; Wu, M.; Ludwig, A.

2015-10-01

This paper presents a numerical method to investigate the shape of tip and melt rate of an electrode during electroslag remelting process. The interactions between flow, temperature, and electromagnetic fields are taken into account. A dynamic mesh-based approach is employed to model the dynamic formation of the shape of electrode tip. The effect of slag properties such as thermal and electrical conductivities on the melt rate and electrode immersion depth is discussed. The thermal conductivity of slag has a dominant influence on the heat transfer in the system, hence on melt rate of electrode. The melt rate decreases with increasing thermal conductivity of slag. The electrical conductivity of slag governs the electric current path that in turn influences flow and temperature fields. The melting of electrode is a quite unstable process due to the complex interaction between the melt rate, immersion depth, and shape of electrode tip. Therefore, a numerical adaptation of electrode position in the slag has been implemented in order to achieve steady state melting. In fact, the melt rate, immersion depth, and shape of electrode tip are interdependent parameters of process. The generated power in the system is found to be dependent on both immersion depth and shape of electrode tip. In other words, the same amount of power was generated for the systems where the shapes of tip and immersion depth were different. Furthermore, it was observed that the shape of electrode tip is very similar for the systems running with the same ratio of power generation to melt rate. Comparison between simulations and experimental results was made to verify the numerical model.

Experiments and analyses on melt-structure-water interactions during severe accidents

International Nuclear Information System (INIS)

Seghal, B.R.; Dinh, T.N.; Bui, V.A.; Green, J.A.; Nourgaliev, R.R.; Okkonen, T.O.; Dinh, A.T.

1998-04-01

This report is the final report for the research project Melt Structure Water Interactions (MSWI). It describes results of analytical and experimental studies concerning MSWI during the course of a hypothetical core meltdown accident in a LWR. Emphasis has been placed on phenomena which govern vessel failure mode and timing and the mechanisms and properties which govern the fragmentation and breakup of melt jets and droplets. It was found that: 2-D effects significantly diminished the focusing effect of an overlying metallic layer on top of an oxide melt pool. This result improves the feasibility of in-vessel retention of a melt pool through external cooling of the lower head; phenomena related to hole ablation and melt discharge, in the event of vessel failure, are affected significantly by crust formation; the jet fragmentation process is a function of many related phenomena. The fragmentation rate depends not only on the traditional parameters but also on the melt physical properties, which change as the melt cools down from liquid to solid temperature; film boiling was investigated by developing a two-phase flow model and inserting it in a multi-D fluid dynamics code. It was concluded that the thickness of the film on the surface of a melt jet would be small and that the effects of the film on the process should not be large. This conclusion is contrary to the modeling employed in some other codes. The computer codes were developed and validated against the data obtained in the MSWI Project. The melt vessel interaction thermal analysis code describes the process of melt pool formation and convection and the resulting vessel thermal loadings. In addition, several innovative models were developed to describe the melt-water interaction process. The code MELT-3D treats the melt jet as a collection of particles whose movement is described with a three-dimensional Eulerian formulation. The model (SIPHRA) tracks the melt jet with an additional equation, using the

Melt electrospinning of biodegradable polyurethane scaffolds

Science.gov (United States)

Karchin, Ari; Simonovsky, Felix I.; Ratner, Buddy D.; Sanders, Joan E.

2014-01-01

Electrospinning from the melt, in contrast to from solution, is an attractive tissue engineering scaffold manufacturing process as it allows for the formation of small diameter fibers while eliminating potentially cytotoxic solvents. Despite this, there is a dearth of literature on scaffold formation via melt electrospinning. This is likely due to the technical challenges related to the need for a well-controlled high temperature setup and the difficulty in developing an appropriate polymer. In this paper, a biodegradable and thermally stable polyurethane (PU) is described specifically for use in melt electrospinning. Polymer formulations of aliphatic PUs based on (CH2)4-content diisocyanates, polycaprolactone (PCL), 1,4-butanediamine and 1,4-butanediol (BD) were evaluated for utility in the melt electrospinning process. The final polymer formulation, a catalyst-purified PU based on 1,4-butane diisocyanate, PCL and BD in a 4/1/3 molar ratio with a weight-average molecular weight of about 40 kDa, yielded a nontoxic polymer that could be readily electrospun from the melt. Scaffolds electrospun from this polymer contained point bonds between fibers and mechanical properties analogous to many in vivo soft tissues. PMID:21640853

Influence of accelerated thermal charging and discharging cycles on thermo-physical properties of organic phase change materials for solar thermal energy storage applications

International Nuclear Information System (INIS)

Raam Dheep, G.; Sreekumar, A.

2015-01-01

Highlights: • Identification of organic phase change materials namely benzamide and sebacic acid. • Thermal reliability studies on identified phase change materials. • Measurement of phase transition temperature and latent heat of fusion. • Analysis of relative percentage difference (RPD%) in heat of fusion and melting temperature of benzamide and sebacic acid. - Abstract: Integration of appropriate thermal energy storage system plays a predominant role in upgrading the efficiency of solar thermal energy devices by reducing the incongruity between energy supply and demand. Latent heat thermal energy storage based on phase change materials (PCM) is found to be the most efficient and prospective method for storage of solar thermal energy. Ensuring the thermal reliability of PCM through large number of charging (melting) and discharging (solidification) cycles is a primary prerequisite to determine the suitability of PCM for a specific thermal energy storage applications. The present study explains the experimental analysis carried out on two PCM’s namely benzamide and sebacic acid to check the compatibility of the material in solar thermal energy storage applications. The selected materials were subjected to one thousand accelerated melting and solidification cycles in order to investigate the percentage of variation at different stages on latent heat of fusion, phase transition temperature, onset and peak melting temperature. Differential Scanning Calorimeter (DSC) was used to determine the phase transition temperature and heat of fusion upon completion of every 100 thermal cycles and continued up to 1000 cycles. Relative Percentage Difference (RPD%) is calculated to find out the absolute deviation of melting temperature and latent heat of fusion with respect to zeroth cycle. The experimental study recorded a melting temperatures of benzamide and sebacic acid as 125.09 °C and 135.92 °C with latent heat of fusion of 285.1 (J/g) and 374.4 (J/g). The

Edge-melting: nanoscale key-mechanism to explain nanoparticle formation from heated TEM grids

Energy Technology Data Exchange (ETDEWEB)

Cesaria, Maura, E-mail: maura.cesaria@le.infn.it [Department of Mathematics and Physics “E. De Giorgi”, University of Salento, Via Arnesano, 73100 Lecce (Italy); Taurino, Antonietta; Catalano, Massimo [Institute for Microelectronics and Microsystems, IMM-CNR, Via Monteroni, 73100 Lecce (Italy); Caricato, Anna Paola; Martino, Maurizio [Department of Mathematics and Physics “E. De Giorgi”, University of Salento, Via Arnesano, 73100 Lecce (Italy)

2016-03-01

Graphical abstract: - Highlights: • Nanoparticle formation from metal grids explained by edge melting as key mechanism. • The inconsistency of bulk phenomenology invoking the vapor pressure is discussed. • Surface-melting and size-dependent evaporation are questioned as unsatisfactory. • Edge-melting: edges, corners, facets invoked as highly thermally unstable surfaces. • The polycrystalline nature of the really occurring metal grids is accounted for. - Abstract: In this study, we examine at both experimental and fundamental levels, the experimental evidence of nanoparticle formation in transmission electron microscopy (TEM) metal grids annealed at temperatures lower than the melting point of the corresponding metal bulk material. Our experimental investigation considers the most thermally unstable TEM grids (i.e. Cu-grids) and inspects the possible sources and mechanisms of contamination of thin films, conventionally deposited on carbon-coated Cu-grids. The investigations are supported by morphological–compositional analyses performed in different regions of the TEM sample. Then, a general model is formulated and discussed in order to explain the grid thermal instability, based on the critical role of edge-melting (i.e. melting initiated at edges and corners of the grid bars), the enhanced rate of evaporation from a liquid surface and the polycristallinity of the grid bars. Hence, we totally disregard conventional arguments such as bulk evaporation and metal vapor pressure and, in order to emphasize and clarify the alternative point of view of our model, we also overview the nano-scale melting phenomenology relevant to our discussion and survey the discrepancies reported in the literature.

Incorporation of Certain Hydrophobic Excipients in the Core of Melt ...

African Journals Online (AJOL)

Patrick Erah

incorporation of hydrophobic materials (talc or magnesium stearate) in the core of such granules may further retard .... (500mg) was filled into a capsule shell and ... of the drug particles. The effect of melt granulation on the release profiles of paracetamol is shown in Fig 1. The melt granulations displayed a retarded release.

Numerical study for enhancing the thermal conductivity of phase change material (PCM) storage using high thermal conductivity porous matrix

International Nuclear Information System (INIS)

Mesalhy, Osama; Lafdi, Khalid; Elgafy, Ahmed; Bowman, Keith

2005-01-01

In this paper, the melting process inside an irregular geometry filled with high thermal conductivity porous matrix saturated with phase change material PCM is investigated numerically. The numerical model is resting on solving the volume averaged conservation equations for mass, momentum and energy with phase change (melting) in the porous medium. The convection motion of the liquid phase inside the porous matrix is solved considering the Darcy, Brinkman and Forchiemer effects. A local thermal non-equilibrium assumption is considered due to the large difference in thermal properties between the solid matrix and PCM by applying a two energy equation model. The numerical code shows good agreement for pure PCM melting with another published numerical work. Through this study it is found that the presence of the porous matrix has a great effect on the heat transfer and melting rate of the PCM energy storage. Decreasing the porosity of the matrix increases the melting rate, but it also damps the convection motion. It is also found that the best technique to enhance the response of the PCM storage is to use a solid matrix with high porosity and high thermal conductivity

Experiments on the behaviour of thermite melt injected into sodium: Final report on the THINA test results

International Nuclear Information System (INIS)

Huber, F.; Kaiser, A.; Peppler, W.

1994-01-01

During hypothetical accidents of fast breeder reactors the core melts and part of the core material inventory is ejected into the upper coolant plenum. As a consequence, a fuel to coolant thermal interaction occurs between the melt and the sodium. A series of simulating experiments was carried out in KfK/IRS to improve the knowledge about the phenomenology of molten fuel/coolant interactions and to support theoretical work on the safety of fast breeder reactors. In the tests, a thermite melt of up to 3270 K is injected from below into a sodium pool the temperature of which is between 770 and 820 K. The masses of the melt and the sodium are about five and 150 kg, respectively. Thermal interactions have been observed to occur as a sequence of small local pressure events mainly during the melt injection. Large-scale vapour explosions have not been observed. Generally, the conversion ratios of thermal to mechanical energy have been low. (author)

Thermal properties and thermal reliability of eutectic mixtures of some fatty acids as latent heat storage materials

International Nuclear Information System (INIS)

Sari, Ahmet; Sari, Hayati; Oenal, Adem

2004-01-01

The present study deals with two subjects. The first one is to determine the thermal properties of lauric acid (LA)-stearic acid (SA), myristic acid (MA)-palmitic acid (PA) and palmitic acid (PA)-stearic acid (SA) eutectic mixtures as latent heat storage material. The properties were measured by the differential scanning calorimetry (DSC) analysis technique. The second one is to study the thermal reliability of these materials in view of the change in their melting temperatures and latent heats of fusion with respect to repeated thermal cycles. For this aim, the eutectic mixtures were subjected to 360 repeated melt/freeze cycles, and their thermal properties were measured after 0, 90,180 and 360 thermal cycles by the technique of DSC analysis. The DSC thermal analysis results show that the binary systems of LA-SA in the ratio of 75.5:24.5 wt.%, MA-PA in the ratio of 58:42 wt.% and PA-SA in the ratio of 64.2:35.8 wt.% form eutectic mixtures with melting temperatures of 37.0, 42.60 and 52.30 deg. C and with latent heats of fusion of 182.7, 169.7 and 181.7 J g -1 , respectively. These thermal properties make them possible for heat storage in passive solar heating applications with respect to climate conditions. The accelerated thermal cycle tests indicate that the changes in the melting temperatures and latent heats of fusion of the studied eutectic mixtures are not regular with increasing number of thermal cycles. However, these materials, latent heat energy storage materials, have good thermal reliability in terms of the change in their thermal properties with respect to thermal cycling for about a one year utility period

Computationally efficient thermal-mechanical modelling of selective laser melting

NARCIS (Netherlands)

Yang, Y.; Ayas, C.; Brabazon, Dermot; Naher, Sumsun; Ul Ahad, Inam

2017-01-01

The Selective laser melting (SLM) is a powder based additive manufacturing (AM) method to produce high density metal parts with complex topology. However, part distortions and accompanying residual stresses deteriorates the mechanical reliability of SLM products. Modelling of the SLM process is

Effect of poly ethylene glycol on the mechanical and thermal properties of bioactive poly(ε-caprolactone) melt extrudates for pharmaceutical applications.

Science.gov (United States)

Douglas, P; Albadarin, Ahmad B; Sajjia, M; Mangwandi, Chirangano; Kuhs, Manuel; Collins, Maurice N; Walker, Gavin M

2016-03-16

This paper investigates the effects of polyethylene glycol (PEG), on the mechanical and thermal properties of nalidixic acid/poly ε-caprolactone (NA)/PCL blends prepared by hot melt extrusion. The blends were characterized by tensile and flexural analysis, dynamic mechanical analysis, differential scanning calorimetry, thermogravimetric analysis and X-ray diffraction. Results show that loading PEG in the PCL had a detrimental effect on the tensile strength and toughness of the blends, reducing them by 20-40%. The partial miscibility of the PCL-PEG system, causes an increase in Tg. While increases in the crystallinity is attributed to the plasticisation effect of PEG and the nucleation effect of NA. The average crystal size increased by 8% upon PEG addition. Experimental data indicated that the addition of NA caused loss of the tensile strength and toughness of PCL. Thermal analysis of the PCL showed that on addition of the thermally unstable NA, thermal degradation occurred early and was autocatalytic. However, the NA did benefit from the heat shielding provided by the PCL matrix resulting in more thermally stable NA particles. Copyright © 2016 Elsevier B.V. All rights reserved.

Thermophysical properties of liquid Ni around the melting temperature from molecular dynamics simulation

Energy Technology Data Exchange (ETDEWEB)

Rozas, R. E. [Institut für Theoretische Physik II: Soft Matter, Heinrich Heine-Universität Düsseldorf, Universitätsstraße 1, 40225 Düsseldorf (Germany); Department of Physics, University of Bío-Bío, Av. Collao 1202, P.O. Box 5C, Concepción (Chile); Demiraǧ, A. D.; Horbach, J. [Institut für Theoretische Physik II: Soft Matter, Heinrich Heine-Universität Düsseldorf, Universitätsstraße 1, 40225 Düsseldorf (Germany); Toledo, P. G. [Chemical Engineering Department and Surface Analysis Laboratory (ASIF), University of Concepción, P.O. Box 160-C, Correo 3, Concepción (Chile)

2016-08-14

Thermophysical properties of liquid nickel (Ni) around the melting temperature are investigated by means of classical molecular dynamics (MD) simulation, using three different embedded atom method potentials to model the interactions between the Ni atoms. Melting temperature, enthalpy, static structure factor, self-diffusion coefficient, shear viscosity, and thermal diffusivity are compared to recent experimental results. Using ab initio MD simulation, we also determine the static structure factor and the mean-squared displacement at the experimental melting point. For most of the properties, excellent agreement is found between experiment and simulation, provided the comparison relative to the corresponding melting temperature. We discuss the validity of the Hansen-Verlet criterion for the static structure factor as well as the Stokes-Einstein relation between self-diffusion coefficient and shear viscosity. The thermal diffusivity is extracted from the autocorrelation function of a wavenumber-dependent temperature fluctuation variable.

Melt Fragmentation Characteristics of Metal Fuel with Melt Injection Mass during Initiating Phase of SFR Severe Accidents

Energy Technology Data Exchange (ETDEWEB)

Heo, Hyo; Lee, Min Ho; Bang, In Cheol [Ulsan National Institute of Science and Technology, Ulsan (Korea, Republic of); Jerng, Dong Wook [Chung-Ang Univ., Seoul (Korea, Republic of)

2016-05-15

The PGSFR has adopted the metal fuel for its inherent safety under severe accident conditions. However, this fuel type is not demonstrated clearly yet under the such severe accident conditions. Additional experiments for examining these issues should be performed to support its licensing activities. Under initiating phase of hypothetic core disruptive accident (HCDA) conditions, the molten metal could be better dispersed and fragmented into the coolant channel than in the case of using oxide fuel. This safety strategy provides negative reactivity driven by a good dispersion of melt. If the coolant channel does not sufficient coolability, the severe recriticality would occur within the core region. Thus, it is important to examine the extent of melt fragmentation. The fragmentation behaviors of melt are closely related to a formation of debris shape. Once the debris shape is formed through the fragmentation process, its coolability is determined by the porosity or thermal conductivity of the melt. There were very limited studies for transient irradiation experiments of the metal fuel. These studies were performed by Transient Reactor Test Facility (TREAT) M series tests in U.S. The TREAT M series tests provided basic information of metal fuel performance under transient conditions. The effect of melt injection mass was evaluated in terms of the fragmentation behaviors of melt. These behaviors seemed to be similar between single-pin and multi-pins failure condition. However, the more melt was agglomerated in case of multi-pins failure.

Opto-thermal moisture content and moisture depth profile measurements in organic materials

NARCIS (Netherlands)

Xiao, P.; Guo, X.; Cui, Y.Y.; Imhof, R.; Bicanic, D.D.

2004-01-01

Opto-thermal transient emission radiometry(OTTER) is a infrared remote sensing technique, which has been successfully used in in vivo skin moisture content and skin moisture depth profiling measurements.In present paper, we extend this moisture content measurement capability to analyze the moisture

Melting behaviour of gold-platinum nanoalloy clusters by molecular dynamics simulations

Energy Technology Data Exchange (ETDEWEB)

Ong, Yee Pin; Yoon, Tiem Leong [School of Physics, Universiti Sains Malaysia, 11800 USM, Penang (Malaysia); Lim, Thong Leng [Faculty of Engineering and Technology, Multimedia University, Melaka Campus, 75450 Melaka (Malaysia)

2015-04-24

The melting behavior of bimetallic gold-platinum nanoclusters is studied by applying Brownian-type isothermal molecular dynamics (MD) simulation, a program modified from the cubic coupling scheme (CCS). The process begins with the ground-state structures obtained from global minimum search algorithm and proceeds with the investigation of the effect of temperature on the thermal properties of gold-platinum nanoalloy clusters. N-body Gupta potential has been employed in order to account for the interactions between gold and platinum atoms. The ground states of the nanoalloy clusters, which are core-shell segregated, are heated until they become thermally segregated. The detailed melting mechanism of the nanoalloy clusters is studied via this approach to provide insight into the thermal stability of the nanoalloy clusters.

Importance of layer thermal conductivity on the sharpness of patterns produced by laser interference

Energy Technology Data Exchange (ETDEWEB)

Peláez, R.J., E-mail: rpelaez@io.cfmac.csic.es [Laser Processing Group, Instituto de Optica, CSIC, Serrano 121, 28006 Madrid (Spain); Afonso, C.N. [Laser Processing Group, Instituto de Optica, CSIC, Serrano 121, 28006 Madrid (Spain); Škereň, M. [Faculty of Nuclear Sciences and Physical Engineering, Czech Technical University in Prague, Brehova 7, 115 19 Prague 1 (Czech Republic); Bulíř, J. [Institute of Physics, ASCR, v.v.i., Na Slovance 2, Prague (Czech Republic)

2016-06-30

Highlights: • Temperature profile matches laser intensity profile in poor thermally conducting layers. • Patterns produced in poor thermally conducting layers have sharp interfaces. • Lateral heat flow smears the temperature profile in thermally conducting layers. • Both liquid and solid state dewetting occurs upon patterning thermally conducting layers. • The thermal conductivity of layers limits the minimum period achievable. - Abstract: In this work, we compare patterns produced in Ag layers having similar thickness in the range 8.3–10.8 nm but having different initial nanostructure, i.e. behaving either as discontinuous or continuous layers and thus having very different thermal conductivities. The patterns are produced by exposing a phase mask to an excimer laser operating at 193 nm and using a projection optics that leads to similar fringed patterns with periods in the range 6.3–6.7 μm. The layer breaks up into isolated NPs due to laser induced melting at the regions around the intensity maxima sites. The resulting fringes have sharp interfaces in the case of discontinuous layers while a variety of regions across the pattern with no sharp interfaces are produced in the case of continuous layers. The results show that while the temperature distribution across the pattern matches almost perfectly the laser beam intensity profile for the former case, it becomes smeared due to lateral heat flow for the latter case. These results provide evidences for significant heating at the intensity minima sites that lead to solid-state dewetting and will eventually limit the minimum period achievable in the case of continuous metal layers or thermally conducting layers.

The measurement of neutral beam thermal profiles on 'V'-shaped calorimeters

International Nuclear Information System (INIS)

Kamperschroer, J.H.; Lagin, L.J.; Silber, K.

1995-01-01

It is customary in high power neutral beam systems to use a V-shaped calorimeter to stop and measure the beam. With proper instrumentation, it is possible to determine both the neutral beam power and divergence. By utilizing a near-grazing angle of incidence, the area over which the beam is in contact with the surface is increased, thereby decreasing the power density over the case of normal incidence. Thermocouples on the back of the calorimeter, in conjunction with real time fitting algorithms, are used to deduce the divergence from the thermal profile. This measurement implicitly assumes that the measured profile corresponds to that of the incident beam. It is shown that such is not the case. Energetic particle reflection at near-grazing angle causes the thermal profile on the calorimeter to be more peaked than the incident distribution. The implications of this on the non-linear multiple regression technique of determining the divergence are discussed. With the aid of a reflection model, developed and applied to the beam from a typical TFTR ion source, it is shown that a peaked power density can be modelled. Neural networks are being studied as a means of supplanting the older regression technique of measuring divergence. Y-direction divergences have been successfully derived using a one-dimensional neural network

Numerical analysis on thermal characteristics and ice melting efficiency for microwave deicing vehicle

Science.gov (United States)

Wang, Can; Yang, Bo; Tan, Gangfeng; Guo, Xuexun; Zhou, Li; Xiong, Shengguang

2016-05-01

In the high latitudes, the icy patches on the road are frequently generated and have a wide distribution, which are difficult to remove and obviously affect the normal usage of the highways, bridges and airport runways. Physical deicing, such as microwave (MW) deicing, help the ice melt completely through heating mode and then the ice layer can be swept away. Though it is no pollution and no damage to the ground, the low efficiency hinders the development of MW deicing vehicle equipped without sufficient speed. In this work, the standard evaluation of deicing is put forward firstly. The intensive MW deicing is simplified to ice melting process characterized by one-dimensional slab with uniform volumetric energy generation, which results in phase transformation and interface motion between ice and water. The heating process is split into the superposition of three parts — non-heterogeneous heating for ground without phase change, heat transfer with phase change and the heat convection between top surface of ice layer and flow air. Based on the transient heat conduction theory, a mathematical model, combining electromagnetic and two-phase thermal conduction, is proposed in this work, which is able to reveal the relationship between the deicing efficiency and ambient conditions, as well as energy generation and material parameters. Using finite difference time-domain, this comprehensive model is developed to solve the moving boundary heat transfer problem in a one-dimensional structured gird. As a result, the stimulation shows the longitudinal temperature distributions in all circumstances and quantitative validation is obtained by comparing simulated temperature distributions under different conditions. In view of the best economy and fast deicing, these analytic solutions referring to the complex influence factors of deicing efficiency demonstrate the optimal matching for the new deicing design.

Phenomenological Studies on Melt-Structure-Water Interactions (MSWI) during Postulated Severe Accidents

International Nuclear Information System (INIS)

Sehgal, B.R.; Park, H.S.; Giri, A.; Karbojian, A.; Jasiulevicius, A.; Hansson, R.C.; Chikkanagoudar, U.; Shiferaw, D.; Stepanyan, A.

2004-01-01

This is the annual report for the work performed in year 2003 in the research project 'Melt-Structure-Water Interactions (MSWI) During Severe Accidents in LWRs', under the auspices of the APRI Project, jointly funded by SKI, HSK, and the Swedish and Finnish power companies. The emphasis of the work was placed on phenomena and parameters, which govern the droplet fragmentation in steam explosions, in-vessel and ex-vessel melt/debris coolability, melt pool convection, and the thermal and mechanical loadings of a pressure vessel during melt-vessel interaction. Most research projects in 2002, such as the COMECO, POMECO and MISTEE programs, were continued. An analysis of the FOREVER experiments using the RELAP code to investigate the melt coolability, bubble dynamics and bubble stability to investigate the dynamic behavior of vapor bubble during steam explosions and associated melt fragmentation, quenching boiling experiment to investigate the thermal behavior of single melt droplet were newly initiated. The SIMECO experiment to investigate the three-layer melt pool convection was restarted. The experimental facilities for these projects were fully functional during year 2003. Many of the investigations performed during the course of the MSWI project have produced papers, which have been published in the proceedings of technical meetings and Journals. Significant technical advances were achieved during the course of these studies. These were: A series of experiments on single drop steam explosions was performed to investigate the fine fragmentation process of a metallic melt drop in various thermal conditions. For the first time, transient fine fragmentation process of a melt drop during explosion phase of a steam explosion was visualized continuously and quantified. Different triggering behavior with respect to the coolant subcooling was observed. The analyses on bubble dynamics during a single drop steam explosion and vapor bubble stability estimated the dynamic

Modeling of the thermal physical process and study on the reliability of linear energy density for selective laser melting

Directory of Open Access Journals (Sweden)

Zhaowei Xiang

2018-06-01

Full Text Available A finite element model considering volume shrinkage with powder-to-dense process of powder layer in selective laser melting (SLM is established. Comparison between models that consider and do not consider volume shrinkage or powder-to-dense process is carried out. Further, parametric analysis of laser power and scan speed is conducted and the reliability of linear energy density as a design parameter is investigated. The results show that the established model is an effective method and has better accuracy allowing for the temperature distribution, and the length and depth of molten pool. The maximum temperature is more sensitive to laser power than scan speed. The maximum heating rate and cooling rate increase with increasing scan speed at constant laser power and increase with increasing laser power at constant scan speed as well. The simulation results and experimental result reveal that linear energy density is not always reliable using as a design parameter in the SLM. Keywords: Selective laser melting, Volume shrinkage, Powder-to-dense process, Numerical modeling, Thermal analysis, Linear energy density

Photothermal depth profiling: Comparison between genetic algorithms and thermal wave backscattering (abstract)

Science.gov (United States)

Li Voti, R.; Sibilia, C.; Bertolotti, M.

2003-01-01

Photothermal depth profiling has been the subject of many papers in the last years. Inverse problems on different kinds of materials have been identified, classified, and solved. A first classification has been done according to the type of depth profile: the physical quantity to be reconstructed is the optical absorption in the problems of type I, the thermal effusivity for type II, and both of them for type III. Another classification may be done depending on the time scale of the pump beam heating (frequency scan, time scan), or on its geometrical symmetry (one- or three-dimensional). In this work we want to discuss two different approaches, the genetic algorithms (GA) [R. Li Voti, C. Melchiorri, C. Sibilia, and M. Bertolotti, Anal. Sci. 17, 410 (2001); R. Li Voti, Proceedings, IV Int. Workshop on Advances in Signal Processing for Non-Destructive Evaluation of Materials, Quebec, August 2001] and the thermal wave backscattering (TWBS) [R. Li Voti, G. L. Liakhou, S. Paoloni, C. Sibilia, and M. Bertolotti, Anal. Sci. 17, 414 (2001); J. C. Krapez and R. Li Voti, Anal. Sci. 17, 417 (2001)], showing their performances and limits of validity for several kinds of photothermal depth profiling problems: The two approaches are based on different mechanisms and exhibit obviously different features. GA may be implemented on the exact heat diffusion equation as follows: one chromosome is associated to each profile. The genetic evolution of the chromosome allows one to find better and better profiles, eventually converging towards the solution of the inverse problem. The main advantage is that GA may be applied to any arbitrary profile, but several disadvantages exist; for example, the complexity of the algorithm, the slow convergence, and consequently the computer time consumed. On the contrary, TWBS uses a simplified theoretical model of heat diffusion in inhomogeneous materials. According to such a model, the photothermal signal depends linearly on the thermal effusivity

Preparation and characterization of poly(methyl methacrylate)-clay nanocomposites via melt intercalation: Effect of organoclay on thermal, mechanical and flammability properties

Energy Technology Data Exchange (ETDEWEB)

Unnikrishnan, Lakshmi; Mohanty, Smita [Laboratory for Advanced Research in Polymeric Materials (LARPM), Central Institute of Plastics Engineering and Technology, Bhubaneswar 751024 (India); Nayak, Sanjay K., E-mail: drsknayak@gmail.com [Laboratory for Advanced Research in Polymeric Materials (LARPM), Central Institute of Plastics Engineering and Technology, Bhubaneswar 751024 (India); Ali, Anwar [Laboratory for Advanced Research in Polymeric Materials (LARPM), Central Institute of Plastics Engineering and Technology, Bhubaneswar 751024 (India)

2011-05-15

Research highlights: {yields} The present work deals with preparation and characterization of poly(methyl methacrylate) nanocomposites via melt intercalation technique. {yields} The effect of various modified nanoclays on the properties of base matrix has been investigated. {yields} It was observed that compatibilization using maleic anhydride improved the performance characteristics of PMMA/layered silicate nanocomposites. - Abstract: The PMMA nanocomposites were prepared by melt processing method. The influence of organoclay loading on extent of intercalation, thermal, mechanical and flammability properties of poly(methyl methacrylate) (PMMA)-clay nanocomposites were studied. Three different organoclay modifiers with varying hydrophobicity (single tallow vs. ditallow) were investigated. The nanocomposites were characterized by using wide angle X-ray diffraction, transmission electron microscopy, thermogravimetric analysis, differential scanning calorimetry (DSC), and tensile tests. The intercalation of polymer chain within the silicate galleries was confirmed by WAXD and TEM. Mechanical properties such as tensile modulus (E), tensile strength, percentage elongation at break and impact strength were determined for nanocomposites at various clay loadings. Overall thermal stability of nanocomposites increased by 16-17 deg. C. The enhancement in T{sub g} of nanocomposite is merely by 2-4 deg. C. The incorporation of maleic anhydride as compatibilizer further enhanced all the properties indicating improved interface between PMMA and clay. The flammability characteristics were studied by determining the rate of burning and LOI.

Preparation and characterization of poly(methyl methacrylate)-clay nanocomposites via melt intercalation: Effect of organoclay on thermal, mechanical and flammability properties

International Nuclear Information System (INIS)

Unnikrishnan, Lakshmi; Mohanty, Smita; Nayak, Sanjay K.; Ali, Anwar

2011-01-01

Research highlights: → The present work deals with preparation and characterization of poly(methyl methacrylate) nanocomposites via melt intercalation technique. → The effect of various modified nanoclays on the properties of base matrix has been investigated. → It was observed that compatibilization using maleic anhydride improved the performance characteristics of PMMA/layered silicate nanocomposites. - Abstract: The PMMA nanocomposites were prepared by melt processing method. The influence of organoclay loading on extent of intercalation, thermal, mechanical and flammability properties of poly(methyl methacrylate) (PMMA)-clay nanocomposites were studied. Three different organoclay modifiers with varying hydrophobicity (single tallow vs. ditallow) were investigated. The nanocomposites were characterized by using wide angle X-ray diffraction, transmission electron microscopy, thermogravimetric analysis, differential scanning calorimetry (DSC), and tensile tests. The intercalation of polymer chain within the silicate galleries was confirmed by WAXD and TEM. Mechanical properties such as tensile modulus (E), tensile strength, percentage elongation at break and impact strength were determined for nanocomposites at various clay loadings. Overall thermal stability of nanocomposites increased by 16-17 deg. C. The enhancement in T g of nanocomposite is merely by 2-4 deg. C. The incorporation of maleic anhydride as compatibilizer further enhanced all the properties indicating improved interface between PMMA and clay. The flammability characteristics were studied by determining the rate of burning and LOI.

Ceramic plasma-sprayed coating of melting crucibles for casting metal fuel slugs

International Nuclear Information System (INIS)

Kim, Ki Hwan; Lee, Chong Tak; Lee, Chan Bock; Fielding, R.S.; Kennedy, J.R.

2013-01-01

Thermal cycling and melt reaction studies of ceramic coatings plasma-sprayed on Nb substrates were carried out to evaluate the performance of barrier coatings for metallic fuel casting applications. Thermal cycling tests of the ceramic plasma-sprayed coatings to 1450 °C showed that HfN, TiC, ZrC, and Y 2 O 3 coating had good cycling characteristics with few interconnected cracks even after 20 cycles. Interaction studies by 1550 °C melt dipping tests of the plasma-sprayed coatings also indicated that HfN and Y 2 O 3 do not form significant reaction layer between U–20 wt.% Zr melt and the coating layer. Plasma-sprayed Y 2 O 3 coating exhibited the most promising characteristics among HfN, TiC, ZrC, and Y 2 O 3 coating

Rapid and inexpensive body fluid identification by RNA profiling-based multiplex High Resolution Melt (HRM) analysis.

Science.gov (United States)

Hanson, Erin K; Ballantyne, Jack

2013-01-01

Positive identification of the nature of biological material present on evidentiary items can be crucial for understanding the circumstances surrounding a crime. However, traditional protein-based methods do not permit the identification of all body fluids and tissues, and thus molecular based strategies for the conclusive identification of all forensically relevant biological fluids and tissues need to be developed. Messenger RNA (mRNA) profiling is an example of such a molecular-based approach. Current mRNA body fluid identification assays involve capillary electrophoresis (CE) or quantitative RT-PCR (qRT-PCR) platforms, each with its own limitations. Both platforms require the use of expensive fluorescently labeled primers or probes. CE-based assays require separate amplification and detection steps thus increasing the analysis time. For qRT-PCR assays, only 3-4 markers can be included in a single reaction since each requires a different fluorescent dye. To simplify mRNA profiling assays, and reduce the time and cost of analysis, we have developed single- and multiplex body fluid High Resolution Melt (HRM) assays for the identification of common forensically relevant biological fluids and tissues. The incorporated biomarkers include IL19 (vaginal secretions), IL1F7 (skin), ALAS2 (blood), MMP10 (menstrual blood), HTN3 (saliva) and TGM4 (semen).  The HRM assays require only unlabeled PCR primers and a single saturating intercalating fluorescent dye (Eva Green). Each body-fluid-specific marker can easily be identified by the presence of a distinct melt peak. Usually, HRM assays are used to detect variants or isoforms for a single gene target. However, we have uniquely developed duplex and triplex HRM assays to permit the simultaneous detection of multiple targets per reaction. Here we describe the development and initial performance evaluation of the developed HRM assays. The results demonstrate the potential use of HRM assays for rapid, and relatively inexpensive

Reversible ultrafast melting in bulk CdSe

International Nuclear Information System (INIS)

Wu, Wenzhi; He, Feng; Wang, Yaguo

2016-01-01

In this work, transient reflectivity changes in bulk CdSe have been measured with two-color femtosecond pump-probe spectroscopy under a wide range of pump fluences. Three regions of reflectivity change with pump fluences have been consistently revealed for excited carrier density, coherent phonon amplitude, and lattice temperature. For laser fluences from 13 to 19.3 mJ/cm 2 , ultrafast melting happens in first several picoseconds. This melting process is purely thermal and reversible. A complete phase transformation in bulk CdSe may be reached when the absorbed laser energy is localized long enough, as observed in nanocrystalline CdSe

Proton NMR study of extra Virgin Olive Oil with temperature: Freezing and melting kinetics

Science.gov (United States)

Mallamace, Domenico; Longo, Sveva; Corsaro, Carmelo

2018-06-01

The thermal properties of an extra Virgin Olive Oil (eVOO) depend on its composition and indeed characterize its quality. Many studies have shown that the freezing and melting behaviors of eVOOs can serve for geographical or chemical discrimination. We use Nuclear Magnetic Resonance spectroscopy to study the evolution of the fatty acids bands as a function of temperature during freezing and melting processes. In such a way we can follow separately the variations in the thermal properties of the different molecular groups during these thermodynamic phase transitions. The data indicate that the methyl group which is at the end of every fatty chain displays the major changes during both freezing and melting processes.

A metastable liquid melted from a crystalline solid under decompression

Science.gov (United States)

Lin, Chuanlong; Smith, Jesse S.; Sinogeikin, Stanislav V.; Kono, Yoshio; Park, Changyong; Kenney-Benson, Curtis; Shen, Guoyin

2017-01-01

A metastable liquid may exist under supercooling, sustaining the liquid below the melting point such as supercooled water and silicon. It may also exist as a transient state in solid-solid transitions, as demonstrated in recent studies of colloidal particles and glass-forming metallic systems. One important question is whether a crystalline solid may directly melt into a sustainable metastable liquid. By thermal heating, a crystalline solid will always melt into a liquid above the melting point. Here we report that a high-pressure crystalline phase of bismuth can melt into a metastable liquid below the melting line through a decompression process. The decompression-induced metastable liquid can be maintained for hours in static conditions, and transform to crystalline phases when external perturbations, such as heating and cooling, are applied. It occurs in the pressure-temperature region similar to where the supercooled liquid Bi is observed. Akin to supercooled liquid, the pressure-induced metastable liquid may be more ubiquitous than we thought.

Effects of surface shape on the geometry and surface topography of the melt pool in low-power density laser melting

KAUST Repository

Kim, Youngdeuk

2011-04-15

The quantitative correlations between workpiece volume and melt pool geometry, as well as the flow and thermal features of the melt pool are established. Thermocapillary convections in melt pool with a deformable free surface are investigated with respect to surface shape and laser intensity. When the contact angle between the tangent to the top surface and the vertical wall at the hot center is acute, the free surface flattens, compared with that of the initial free surface. Otherwise, the free surface forms a bowl-like shape with a deep crater and a low peripheral rim when the contact angle at the hot center is obtuse. Increasing the workpiece volume at a fixed laser intensity and a negative radial height gradient cause linear decreases in the geometric size and magnitude of flow and temperature of the melt pool. Conversely, linear increases are observed with a positive radial height gradient. © 2011 American Institute of Chemical Engineers (AIChE).

Heat transfer in melt ponds with convection and radiative heating: observationally-inspired modelling

Science.gov (United States)

Wells, A.; Langton, T.; Rees Jones, D. W.; Moon, W.; Kim, J. H.; Wilkinson, J.

2016-12-01

Melt ponds have key impacts on the evolution of Arctic sea ice and summer ice melt. Small changes to the energy budget can have significant consequences, with a net heat-flux perturbation of only a few Watts per square metre sufficient to explain the thinning of sea ice over recent decades. Whilst parameterisations of melt-pond thermodynamics often assume that pond temperatures remain close to the freezing point, recent in-situ observations show more complex thermal structure with significant diurnal and synoptic variability. We here consider the energy budget of melt ponds and explore the role of internal convective heat transfer in determining the thermal structure within the pond in relatively calm conditions with low winds. We quantify the energy fluxes and temperature variability using two-dimensional direct numerical simulations of convective turbulence within a melt pond, driven by internal radiative heating and surface fluxes. Our results show that the convective flow dynamics are modulated by changes to the incoming radiative flux and sensible heat flux at the pond surface. The evolving pond surface temperature controls the outgoing longwave emissions from the pond. Hence the convective flow modifies the net energy balance of a melt pond, modulating the relative fractions of the incoming heat flux that is re-emitted to the atmosphere or transferred downward into the sea ice to drive melt.

Microstructure analysis of magnesium alloy melted by laser irradiation

International Nuclear Information System (INIS)

Liu, S.Y.; Hu, J.D.; Yang, Y.; Guo, Z.X.; Wang, H.Y.

2005-01-01

The effects of laser surface melting (LSM) on microstructure of magnesium alloy containing Al8.57%, Zn 0.68%, Mn0.15%, Ce0.52% were investigated. In the present work, a pulsed Nd:YAG laser was used to melt and rapidly solidify the surface of the magnesium alloy with the objective of changing microstructure and improving the corrosion resistance. The results indicate that laser-melted layer contains the finer dendrites and behaviors good resistance corrosion compared with the untreated layer. Furthermore, the absorption coefficient of the magnesium alloy has been estimated according to the numeral simulation of the thermal conditions. The formation process of fine microstructure in melted layers was investigated based on the experimental observation and the theoretical analysis. Some simulation results such as the re-solidification velocities are obtained. The phase constitutions of the melted layers determined by X-ray diffraction were β-Mg 17 Al 12 and α-Mg as well as some phases unidentified

Hydroxyl and molecular H2O diffusivity in a haploandesitic melt

Science.gov (United States)

Ni, Huaiwei; Xu, Zhengjiu; Zhang, Youxue

2013-02-01

H2O diffusion in a haploandesitic melt (a high-silica and Fe-free andesitic melt, NBO/T = 0.173) has been investigated at 1 GPa in a piston-cylinder apparatus. We adopted a double diffusion couple technique, in which one couple was composed of a nominally anhydrous glass with 0.01 wt.% H2O and a hydrous glass with 5.7 wt.% H2O, and the other contained the same nominally anhydrous glass and a hydrous glass with 3.3 wt.% H2O. Both couples were annealed in a single experimental run and hence experienced exactly the same P-T history, which is crucial for constraining the dependence of H2O diffusivity on water content. H2O concentration profiles were measured by both Fourier transform infrared (FTIR) microspectroscopy and confocal Raman microspectroscopy. Nearly identical profiles were obtained from Raman and FTIR methods for profile length >1 mm (produced at 1619-1842 K). By contrast, for profile lengths <100 μm (produced at 668-768 K), FTIR profiles show marked convolution effects compared to Raman profiles. A comparison between the short FTIR and Raman profiles indicates that the real spatial resolution (FWHM) of FTIR analyses is about 28 μm for a 7 μm wide aperture on ˜200 μm thick glasses. While the short profiles are not reliable for quantitative modeling, the long diffusion profiles at superliquidus temperatures can be fit reasonably well by a diffusivity model previously developed for felsic melts, in which molecular H2O (H2Om) is the only diffusive species and its diffusivity (D) increases exponentially with the content of total water (H2Ot). However, there is noticeable misfit of the data at low H2Ot concentrations, suggesting that OH diffusivity (DOH) cannot be neglected in this andesitic melt at high temperatures and low water contents. We hence develop a new fitting procedure that simultaneously fits both diffusion profiles from a single experimental run and accounts for the roles of both OH and H2Om diffusion. With this procedure, DOH/D is constrained

Estimation of Equivalent Thermal Conductivity for Impregnated Electrical Windings Formed from Profiled Rectangular Conductors

OpenAIRE

Ayat, Sabrina S; Wrobel, Rafal; Goss, James; Drury, David

2016-01-01

In order to improve accuracy and reduce model setting-up, and solving time in thermal analysis of electrical machines, transformers and wound passive components, the multi-material winding region is frequently homogenised. The existing winding homogenization techniques are predo-minantly focused on winding constructions with round conductors, where thermal conductivity across conductors is usually assumed to be isotropic. However, for the profiled rectangular conductors that assumption is no ...

Preparation, characterization, and thermal properties of microencapsulated phase change material for thermal energy storage

Energy Technology Data Exchange (ETDEWEB)

Alkan, Cemil; Sari, Ahmet; Karaipekli, Ali [Department of Chemistry, Gaziosmanpasa University, 60240 Tokat (Turkey); Uzun, Orhan [Department of Physics, Gaziosmanpasa University, 60240 Tokat (Turkey)

2009-01-15

This study is focused on the preparation, characterization, and determination of thermal properties of microencapsulated docosane with polymethylmethacrylate (PMMA) as phase change material for thermal energy storage. Microencapsulation of docosane has been carried out by emulsion polymerization. The microencapsulated phase change material (MEPCM) was characterized using scanning electron microscopy (SEM) and Fourier transform infrared (FT-IR) spectroscopy. Thermal properties and thermal stability of MEPCM were measured by differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). DSC analysis indicated that the docosane in the microcapsules melts at 41.0 C and crystallizes at 40.6 C. It has latent heats of 54.6 and -48.7 J/g for melting and crystallization, respectively. TGA showed that the MEPCM degraded in three distinguishable steps and had good chemical stability. Accelerated thermal cycling tests also indicated that the MEPCM had good thermal reliability. Based on all these results, it can be concluded that the microencapsulated docosane as MEPCMs have good potential for thermal energy storage purposes such as solar space heating applications. (author)

Thermal properties of a novel nanoencapsulated phase change material for thermal energy storage

Energy Technology Data Exchange (ETDEWEB)

Fuensanta, Mónica, E-mail: monica.fuensanta@aidico.es [AIDICO, Technological Institute of Construction, Camí de Castella, 4, 03660 Novelda, Alicante (Spain); Paiphansiri, Umaporn [Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz (Germany); Romero-Sánchez, María Dolores, E-mail: md.romero@aidico.es [AIDICO, Technological Institute of Construction, Camí de Castella, 4, 03660 Novelda, Alicante (Spain); Guillem, Celia; López-Buendía, Ángel M. [AIDICO, Technological Institute of Construction, Camí de Castella, 4, 03660 Novelda, Alicante (Spain); Landfester, Katharina [Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz (Germany)

2013-08-10

Highlights: • A paraffin wax RT80 was encapsulated in styrene–butyl acrylate copolymer as polymer shell using miniemulsion polymerization process to obtain a novel nanoencapsulated PCM with 80 °C melting temperature. • Nano-PCMs have high compact structure, spherical morphology and thermal stability. • The nano-PCMs have potential applications as thermal energy storage materials. - Abstract: A novel nanoencapsulation of a paraffine type phase change material, RT80, in a styrene–butyl acrylate copolymer shell using the miniemulsion polymerization process was carried out. General characteristics of the RT80 nanoparticles in terms of thermal properties, morphology, chemical composition and particle size distribution were characterized by Differential Scanning Calorimetry (DSC), Thermal Gravimetric Analysis (TGA), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), Fourier Transform Infrared Spectroscopy (FT-IR) and Dynamic Light Scattering (DLS). The influence of different monomers (styrene, butyl acrylate) and the surfactant/paraffin mass ratios on nanoparticles properties such as thermal capacity, particle size and morphology were systematically investigated. In all cases studied, encapsulation efficiency was close to 80 wt% with a particle size distribution between 52 and 112 nm and regular spherical shape and uniform structure. The amount of encapsulated paraffin achieved was comprised between 8 and 20%. Melting and crystallization heats were found to be approximately 5–25 J g{sup −1}, mainly depending on surfactant/paraffin mass ratio. Melting temperature of RT80 nanoparticles slightly decreased (1–7 °C) respect to the raw RT80. In addition, the encapsulated RT80 nanoparticles show thermal stability even after 200 thermal (heat-cooling) cycles.

Thermal properties of a novel nanoencapsulated phase change material for thermal energy storage

International Nuclear Information System (INIS)

Fuensanta, Mónica; Paiphansiri, Umaporn; Romero-Sánchez, María Dolores; Guillem, Celia; López-Buendía, Ángel M.; Landfester, Katharina

2013-01-01

Highlights: • A paraffin wax RT80 was encapsulated in styrene–butyl acrylate copolymer as polymer shell using miniemulsion polymerization process to obtain a novel nanoencapsulated PCM with 80 °C melting temperature. • Nano-PCMs have high compact structure, spherical morphology and thermal stability. • The nano-PCMs have potential applications as thermal energy storage materials. - Abstract: A novel nanoencapsulation of a paraffine type phase change material, RT80, in a styrene–butyl acrylate copolymer shell using the miniemulsion polymerization process was carried out. General characteristics of the RT80 nanoparticles in terms of thermal properties, morphology, chemical composition and particle size distribution were characterized by Differential Scanning Calorimetry (DSC), Thermal Gravimetric Analysis (TGA), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), Fourier Transform Infrared Spectroscopy (FT-IR) and Dynamic Light Scattering (DLS). The influence of different monomers (styrene, butyl acrylate) and the surfactant/paraffin mass ratios on nanoparticles properties such as thermal capacity, particle size and morphology were systematically investigated. In all cases studied, encapsulation efficiency was close to 80 wt% with a particle size distribution between 52 and 112 nm and regular spherical shape and uniform structure. The amount of encapsulated paraffin achieved was comprised between 8 and 20%. Melting and crystallization heats were found to be approximately 5–25 J g −1 , mainly depending on surfactant/paraffin mass ratio. Melting temperature of RT80 nanoparticles slightly decreased (1–7 °C) respect to the raw RT80. In addition, the encapsulated RT80 nanoparticles show thermal stability even after 200 thermal (heat-cooling) cycles

Thermal contact resistance of a particle on a substrate

International Nuclear Information System (INIS)

Tan, J.; Safa, H.; Bonin, B.

1996-01-01

It has been formerly established that field emission in RF cavities is mainly due to contamination by small micron size particles lying on the surface. When applying the RF field, these particles can melt and stick to the surface making it harder to get rid of them. In order to understand the thermal process involved, a crucial physical quantity is needed: the thermal contact resistance between the particle and the substrate. An experimental method is described to measure this quantity, with the use of a scanning electron microscope. By defocusing the beam of the SEM, one can get enough power deposited in one particle to melt it. The power level at which the particle melts gives the thermal contact resistance. Therefore, using the measured value, thermal calculations yield some hints for understanding the violent thermal processes observed in RF fields. (author)

Characterization of melt-blended graphene – poly(ether ether ketone) nanocomposite

International Nuclear Information System (INIS)

Tewatia, Arya; Hendrix, Justin; Dong, Zhizhong; Taghon, Meredith; Tse, Stephen; Chiu, Gordon; Mayo, William E.; Kear, Bernard; Nosker, Thomas; Lynch, Jennifer

2017-01-01

Using a high shear melt-processing method, graphene-reinforced polymer matrix composites (G-PMCs) were produced with good distribution and particle–matrix interaction of bi/trilayer graphene at 2 wt. % and 5 wt. % in poly ether ether ketone (2Gn-PEEK and 5Gn-PEEK). The morphology, structure, thermal properties, and mechanical properties of PEEK, 2Gn-PEEK and 5 Gn-PEEK were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), flexural mechanical testing, and dynamic mechanical analysis (DMA). Addition of graphene to PEEK induces surface crystallization, increased percent crystallinity, offers a composite that is thermally stable until 550 °C and enhances thermomechanical properties. Results show that graphene was successfully melt-blended within PEEK using this method.

Characterization of melt-blended graphene – poly(ether ether ketone) nanocomposite

Energy Technology Data Exchange (ETDEWEB)

Tewatia, Arya; Hendrix, Justin [Department of Materials Science and Engineering, Rutgers University, 607 Taylor Road, Piscataway, NJ, 08854 (United States); Dong, Zhizhong [Department of Mechanical Engineering, Rutgers University, 98 Brett Road, Piscataway, NJ 08854 (United States); Taghon, Meredith [Department of Materials Science and Engineering, Rutgers University, 607 Taylor Road, Piscataway, NJ, 08854 (United States); Tse, Stephen [Department of Mechanical Engineering, Rutgers University, 98 Brett Road, Piscataway, NJ 08854 (United States); Chiu, Gordon; Mayo, William E.; Kear, Bernard; Nosker, Thomas [Department of Materials Science and Engineering, Rutgers University, 607 Taylor Road, Piscataway, NJ, 08854 (United States); Lynch, Jennifer, E-mail: jklynch@rci.rutgers.edu [Department of Materials Science and Engineering, Rutgers University, 607 Taylor Road, Piscataway, NJ, 08854 (United States)

2017-02-15

Using a high shear melt-processing method, graphene-reinforced polymer matrix composites (G-PMCs) were produced with good distribution and particle–matrix interaction of bi/trilayer graphene at 2 wt. % and 5 wt. % in poly ether ether ketone (2Gn-PEEK and 5Gn-PEEK). The morphology, structure, thermal properties, and mechanical properties of PEEK, 2Gn-PEEK and 5 Gn-PEEK were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), flexural mechanical testing, and dynamic mechanical analysis (DMA). Addition of graphene to PEEK induces surface crystallization, increased percent crystallinity, offers a composite that is thermally stable until 550 °C and enhances thermomechanical properties. Results show that graphene was successfully melt-blended within PEEK using this method.

Observation of melting in 30 angstrom diameter CdS nanocrystals

International Nuclear Information System (INIS)

Goldstein, A.N.; Colvin, V.L.; Alivisatos, A.P.

1991-01-01

In this paper temperature dependent electron diffraction studies on 30 Angstrom diameter CdS nanocrystals are described. The linear thermal expansion coefficient of the nanocrystals is 2.75 * 10 -5 Angstrom/K, and the melting point is 575 K. These data are in contrast to bulk CdS which has a melting point of 1750 K and a linear expansion coefficient of 5.5 * 10 -6 Angstrom/K. The observed depression in the melting point of these semiconductor clusters is similar to effects observed in metals and molecular crystals, indicating that the phenomenon of reduced melting point in small systems is a general one regardless of the type of material. The observation of melting point depression in these clusters also has far reaching implications for the preparation of highly crystalline clusters of CdS, as well as for the use of these nanocrystals as precursors to thin films

Influence of Flame Retardants on the Melt Dripping Behaviour of Thermoplastic Polymers

Directory of Open Access Journals (Sweden)

Melissa Matzen

2015-08-01

Full Text Available Melt flow and dripping of the pyrolysing polymer melt can be both a benefit and a detriment during a fire. In several small-scale fire tests addressing the ignition of a defined specimen with a small ignition source, well-adjusted melt flow and dripping are usually beneficial to pass the test. The presence of flame retardants often changes the melt viscosity crucially. The influence of certain flame retardants on the dripping behaviour of four commercial polymers, poly(butylene terephthalate (PBT, polypropylene (PP, polypropylene modified with ethylene-propylene rubber (PP-EP and polyamide 6 (PA 6, is analysed based on an experimental monitoring of the mass loss due to melt dripping, drop size and drop temperature as a function of the furnace temperature applied to a rod-shaped specimen. Investigating the thermal transition (DSC, thermal and thermo-oxidative decomposition, as well as the viscosity of the polymer and collected drops completes the investigation. Different mechanisms of the flame retardants are associated with their influence on the dripping behaviour in the UL 94 test. Reduction in decomposition temperature and changed viscosity play a major role. A flow limit in flame-retarded PBT, enhanced decomposition of flame-retarded PP and PP-EP and the promotion of dripping in PA 6 are the salient features discussed.

Effect of carbon nanospheres on shape stabilization and thermal behavior of phase change materials for thermal energy storage

International Nuclear Information System (INIS)

Mehrali, Mohammad; Tahan Latibari, Sara; Mehrali, Mehdi; Mahlia, Teuku Meurah Indra; Cornelis Metselaar, Hendrik Simon

2014-01-01

Highlights: • Introducing novel form-stable PCM of stearic acid (SA)/carbon nanospheres (CNSs). • The highest stabilized SA content is 83 wt% in the SA/CNS composites. • Increasing thermal conductivity of composite phase change material with high amount of latent heat. - Abstract: Stearic acid (SA) is one of the main phase change materials (PCMs) for medium temperature thermal energy storage systems. In order to stabilize the shape and enhance the thermal conductivity of SA, the effects of adding carbon nanospheres (CNSs) as a carbon nanofiller were examined experimentally. The maximum mass fraction of SA retained in CNSs was found as 80 wt% without the leakage of SA in a melted state, even when it was heated over the melting point of SA. The dropping point test shows that there was clearly no liquid leakage through the phase change process at the operating temperature range of the composite PCMs. The thermal stability and thermal properties of composite PCMs were investigated with a thermogravimetric analyzer (TGA) and differential scanning calorimeter (DSC), respectively. The thermal conductivity of the SA/CNS composite was determined by the laser flash method. The thermal conductivity at 35 °C increased about 105% for the highest loading of CNS (50 wt%). The thermal cycling test proved that form-stable composite PCMs had good thermal reliability and chemical durability after 1000 cycles of melting and freezing, which is advantageous for latent heat thermal energy storage (LHTES)

Melting of Au and Al in nanometer Fe/Au and Fe/Al multilayers under swift heavy ions: A thermal spike study

International Nuclear Information System (INIS)

Chettah, A.; Wang, Z.G.; Kac, M.; Kucal, H.; Meftah, A.; Toulemonde, M.

2006-01-01

Knowing that Fe is sensitive to swift heavy ion irradiations whereas Au and Al are not, the behavior of nanometric metallic multilayer systems, like [Fe(3 nm)/Au(x)] y and [Fe(3 nm)/Al(x)] y with x ranging between 1 and 10 nm, were studied within the inelastic thermal spike model. In addition to the usual cylindrical geometry of energy dissipation perpendicular to the ion projectile direction, the heat transport along the ion path was implemented in the electronic and atomic sub-systems. The simulations were performed using three different values of linear energy transfer corresponding to 3 MeV/u of 208 Pb, 132 Xe and 84 Kr ions. For the Fe/Au system, evidence of appearance of a molten phase was found in the entire Au layer, provided the Au thickness is less than 7 nm and 3 nm for Pb and Xe ions, respectively. For the Fe/Al(x) system irradiated with Pb ions, the Al layers with a thickness less than 4 nm melt along the entire ion track. Surprisingly, the Fe layer does not melt if the Al thickness is larger than 2 nm, although the deposited energy surpasses the electronic stopping power threshold of track formation in Fe. For Kr ions melting does not occur in any of the multilayer systems

Effect of tellurium on viscosity and liquid structure of GaSb melts

Energy Technology Data Exchange (ETDEWEB)

Ji Leilei [School of Material Science and Engineering, Jinan University, Jinan 250022 (China); Geng Haoran [School of Material Science and Engineering, Jinan University, Jinan 250022 (China)], E-mail: mse_genghr@ujn.edu.cn; Sun Chunjing [Key Laboratory of Liquid Structure and Heredity of Materials, Ministry of Education, Shandong University, Jinan 250061 (China); Teng Xinying; Liu Yamei [School of Material Science and Engineering, Jinan University, Jinan 250022 (China)

2008-04-03

The behavior of GaSb melt with tellurium addition was investigated using viscometer and differential scanning calorimetry (DSC). Normally, the viscosity of all melts measured decreased with the increasing temperature. However, anomalous transition points were observed in the temperature dependence of viscosity for Ga-Sb-Te system. Corresponded with the abnormal points on the viscosity-temperature curves, there were thermal effect peaks on the DSC curves. Furthermore, viscous activation energy and flow units of these melts and their structural features were discussed in this paper.

Heat transfer modelling of first walls subject to plasma disruption

International Nuclear Information System (INIS)

Fillo, J.A.; Makowitz, H.

1981-01-01

A brief description of the plasma disruption problem and potential thermal consequences to the first wall is given. Thermal models reviewed include: a) melting of a solid with melt layer in place; b) melting of a solid with complete removal of melt (ablation); c) melting/vaporization of a solid; and d) vaporization of a solid but no phase change affecting the temperature profile

Analysis of soft wall AdS/QCD potentials to obtain the melting temperature of scalar hadrons

Energy Technology Data Exchange (ETDEWEB)

Vega, Alfredo; Ibanez, Adolfo [Universidad de Valparaiso, Instituto de Fisica y Astronomia, Valparaiso (Chile)

2017-11-15

We consider an analysis of potentials related to Schroedinger-type equations for scalar fields in a 5D AdS black hole background with dilaton in order to obtain melting temperatures for different hadrons in a thermal bath. The approach does not consider calculations of spectral functions, and it is easy to yield results for hadrons with an arbitrary number of constituents. We present results for scalar mesons, glueballs, hybrid mesons and tetraquarks, and we show that mesons are more resistant to being melted in a thermal bath than other scalar hadrons, and in general the melting temperature increases when hadrons contain heavy quarks. (orig.)

Magnetic viscosity and coercivity mechanisms in sintered and melt spun NdFeB

International Nuclear Information System (INIS)

Street, R.; Bingham, D.; Day, R.K.; Dunlop, J.B.

1988-01-01

Magnetic viscosity parameters kT/q(=Sv) of sintered and melt spun NdFeB vary with internal field. During initial magnetization of thermally demagnetized specimens signifiant viscosity occurs with melt spun NdFeB but is negligible with sintered NdFeB. Differences in mechanisms of magnetization account for this behaviour

Thermal contact resistance of a particle on a substrate

International Nuclear Information System (INIS)

Tan, J.; Safa, H.; Bonin, B.

1996-01-01

It has been formerly established that field emission in RF cavities is mainly die to contamination by small micron size particles lying on the surface. When applying the RF field, these particles can melt and stick to the surface making it harder to get rid of them. In order to understand the thermal process involved, a crucial physical quantity is needed: the thermal contact resistance between the particle and the substrate. In the present paper, an experimental method is described to measure this quantity, with the use of a scanning electron microscope. By defocusing the beam of the SEM, one can get enough power deposited in one particle to melt it. The power level at which the particle melts gives the thermal contact resistance. Therefore, using the measured value, thermal calculations yield some hints for understanding the violent thermal processes observed in RF fields. (author)

Numerical and experimental investigation into the subsequent thermal cycling during selective laser melting of multi-layer 316L stainless steel

Science.gov (United States)

Liu, Yang; Zhang, Jian; Pang, Zhicong

2018-01-01

Subsequent thermal cycling (STC), as the unique thermal behavior during the multi-layer manufacturing process of selective laser melting (SLM), brings about unique microstructure of the as-produced parts. A multi-layer finite element (FE) model was proposed to study the STC along with a contrast experiment. The FE simulational results show that as layer increases, the maximum temperature, dimensions and liquid lifetime of the molten pool increase, while the heating and cooling rates decrease. The maximum temperature point shifts into the molten pool, and central of molten pool shifts backward. The neighborly underlying layer can be remelted thoroughly when laser irradiates a powder layer, thus forming an excellent bonding between neighbor layers. The contrast experimental results between the single-layer and triple-layer samples show that grains in of latter become coarsen and tabular along the height direction compared with those of the former. Moreover, this effect become more serious in 2nd and 1st layers in the triple-layer sample. All the above illustrate that the STC has an significant influence on the thermal behavior during SLM process, and thus affects the microstructure of SLMed parts.

Wasteless combined aggregate-coal-fired steam-generator/melting-converter

International Nuclear Information System (INIS)

Pioro, L.S.; Pioro, I.L.

2003-01-01

A method of reprocessing coal sludge and ash into granulate for the building industry in a combined wasteless aggregate-steam-generator/melting-converter was developed and tested. The method involves melting sludge and ash from coal-fired steam-generators of power plants in a melting-converter installed under the steam-generator, with direct sludge drain from the steam generator combustion chamber. The direct drain of sludge into converter allows burnup of coal with high ash levels in the steam-generator without an additional source of ignition (natural gas, heating oil, etc.). Specific to the melting process is the use of a gas-air mixture with direct combustion inside a melt. This feature provides melt bubbling and helps to achieve maximum heat transfer from combustion products to the melt, to improve mixing, to increase rate of chemical reactions and to improve the conditions for burning the carbon residue from the sludge and ash. The 'gross' thermal efficiency of the combined aggregate is about 93% and the converter capacity is about 18 t of melt in 100 min. The experimental data for different aspects of the proposed method are presented. The effective ash/charging materials feeding system is also discussed. The reprocessed coal ash and sludge in the form of granules can be used as fillers for concretes and as additives in the production of cement, bricks and other building materials

Automated realization of the gallium melting and triple points

Science.gov (United States)

Yan, X.; Duan, Y.; Zhang, J. T.; Wang, W.

2013-09-01

In order to improve the automation and convenience of the process involved in realizing the gallium fixed points, an automated apparatus, based on thermoelectric and heat pipe technologies, was designed and developed. This paper describes the apparatus design and procedures for freezing gallium mantles and realizing gallium melting and triple points. Also, investigations on the melting behavior of a gallium melting point cell and of gallium triple point cells were carried out while controlling the temperature outside the gallium point cells at 30 °C, 30.5 °C, 31 °C, and 31.5 °C. The obtained melting plateau curves show dentate temperature oscillations on the melting plateaus for the gallium point cells when thermal couplings occurred between the outer and inner liquid-solid interfaces. The maximum amplitude of the temperature fluctuations was about 1.5 mK. Therefore, the temperature oscillations can be used to indicate the ending of the equilibrium phase transitions. The duration and amplitude of such temperature oscillations depend on the temperature difference between the setting temperature and the gallium point temperature; the smaller the temperature difference, the longer the duration of both the melting plateaus and the temperature fluctuations.

Determination of enthalpy–temperature–composition relations in incongruent-melting phase change materials

International Nuclear Information System (INIS)

Desgrosseilliers, Louis; Allred, Paul; Groulx, Dominic; White, Mary Anne

2013-01-01

This paper demonstrates that liquidus line (T-x) data can be obtained from calorimetric determinations of phase transition enthalpy profiles (H-T) for incongruent-melting phase change materials (PCMs) more efficiently than using traditional cooling curves. An accurate and reliable equilibrium mixture enthalpy model bridges the H-T and T-x gap to provide a full suite of high density H-T-x data to assist latent heat energy storage researchers to evaluate composition-dependent two-phase equilibrium processes. The proposed method is validated for T-history method H-T determinations of 1:1 diluted sodium acetate trihydrate in water, and can also be used with other laboratory calorimetric techniques used to determine the phase transition enthalpy profiles of incongruent-melting compounds. -- Highlights: • H-T data can also be used to obtain valuable liquidus region T-x data. • Applies to all incongruent-melting compounds with known thermodynamic properties. • Reduces the effort and cost of assessing full suite H-T-x data for PCMs. • Uses existing T-x or H-T data of incongruent-melting PCMs to determine the other

Effect of polymer melt wall slip on the flow balance of profile extrusion dies

Science.gov (United States)

Carneiro, Olga S.; Ferrás, Luís L.; Pinho, Fernando T.; Nóbrega, João M.

2013-04-01

This work describes the implementation of the wall slip boundary condition in an in-house developed 3D numerical code based on the Finite Volume Method. For this purpose, several phenomenological models relating the velocity and the shear stress at the wall were implemented. This new feature is verified using a simple case study, by comparing the numerical results with those obtained through the corresponding analytical solution. Then, the potentialities of the new code are illustrated performing flow simulations of a polymer melt in a complex flow channel. The results obtained show that the slip at the wall influences the flow distribution at the die flow channel outlet. Therefore, and to assess the relevance of slippage in the optimal die geometry, the automatic optimization of a die flow channel, required for the production of a specific thermoplastic profile, is performed using both the no-slip and slip boundary conditions, together with two alternative optimization strategies. It is shown that slip favors the flow balance of the dies and also other issues of its performance.

Eutectic melting temperature of the lowermost Earth's mantle

Science.gov (United States)

Andrault, D.; Lo Nigro, G.; Bolfan-Casanova, N.; Bouhifd, M.; Garbarino, G.; Mezouar, M.

2009-12-01

Partial melting of the Earth's deep mantle probably occurred at different stages of its formation as a consequence of meteoritic impacts and seismology suggests that it even continues today at the core-mantle boundary. Melts are important because they dominate the chemical evolution of the different Earth's reservoirs and more generally the dynamics of the whole planet. Unfortunately, the most critical parameter, that is the temperature profile inside the deep Earth, remains poorly constrained accross the planet history. Experimental investigations of the melting properties of materials representative of the deep Earth at relevant P-T conditions can provide anchor points to refine past and present temperature profiles and consequently determine the degree of melting at the different geological periods. Previous works report melting relations in the uppermost lower mantle region, using the multi-anvil press [1,2]. On the other hand, the pyrolite solidus was determined up to 65 GPa using optical observations in the laser-heated diamond anvil cell (LH-DAC) [3]. Finally, the melting temperature of (Mg,Fe)2SiO4 olivine is documented at core-mantle boundary (CMB) conditions by shock wave experiments [4]. Solely based on these reports, experimental data remain too sparse to draw a definite melting curve for the lower mantle in the relevant 25-135 GPa pressure range. We reinvestigated melting properties of lower mantle materials by means of in-situ angle dispersive X-ray diffraction measurements in the LH-DAC at the ESRF [5]. Experiments were performed in an extended P-T range for two starting materials: forsterite and a glass with chondrite composition. In both cases, the aim was to determine the onset of melting, and thus the eutectic melting temperatures as a function of pressure. Melting was evidenced from drastic changes of diffraction peak shape on the image plate, major changes in diffraction intensities in the integrated pattern, disappearance of diffraction rings

Diffusion of hydrous species in model basaltic melt

Science.gov (United States)

Zhang, Li; Guo, Xuan; Wang, Qinxia; Ding, Jiale; Ni, Huaiwei

2017-10-01

Water diffusion in Fe-free model basaltic melt with up to 2 wt% H2O was investigated at 1658-1846 K and 1 GPa in piston-cylinder apparatus using both hydration and diffusion couple techniques. Diffusion profiles measured by FTIR are consistent with a model in which both molecular H2O (H2Om) and hydroxyl (OH) contribute to water diffusion. OH diffusivity is roughly 13% of H2Om diffusivity, showing little dependence on temperature or water concentration. Water diffusion is dominated by the motion of OH until total H2O (H2Ot) concentration reaches 1 wt%. The dependence of apparent H2Ot diffusivity on H2Ot concentration appears to be overestimated by a previous study on MORB melt, but H2Ot diffusivity at 1 wt% H2Ot in basaltic melt is still greater than those in rhyolitic to andesitic melts. The appreciable contribution of OH to water diffusion in basaltic melt can be explained by enhanced mobility of OH, probably associated with the development of free hydroxyl bonded with network-modifying cations, as well as higher OH concentration. Calculation based on the Nernst-Einstein equation demonstrates that OH may serve as an effective charge carrier in hydrous basaltic melt, which could partly account for the previously observed strong influence of water on electrical conductivity of basaltic melt.

Ultrasound elastographic imaging of thermal lesions and temperature profiles during radiofrequency ablation

Science.gov (United States)

Techavipoo, Udomchai

Manual palpation to sense variations in tissue stiffness for disease diagnosis has been regularly performed by clinicians for centuries. However, it is generally limited to large and superficial structures and the ability of the physician performing the palpation. Imaging of tissue stiffness or elastic properties via the aid of modern imaging such as ultrasound and magnetic resonance imaging, referred to as elastography, enhances the capability for disease diagnosis. In addition, elastography could be used for monitoring tissue response to minimally invasive ablative therapies, which are performed percutaneously to destruct tumors with minimum damage to surrounding tissue. Monitoring tissue temperature during ablation is another approach to estimate tissue damage. The ultimate goal of this dissertation is to improve the image quality of elastograms and temperature profiles for visualizing thermal lesions during and after ablative therapies. Elastographic imaging of thermal lesions is evaluated by comparison of sizes, shapes, and volumes with the results obtained using gross pathology. Semiautomated segmentation of lesion boundaries on elastograms is also developed. It provides comparable results to those with manual segmentation. Elastograms imaged during radiofrequency ablation in vitro show that the impact of gas bubbles during ablation on the ability to delineate the thermal lesion is small. Two novel methods to reduce noise artifacts in elastograms, and an accurate estimation of displacement vectors are proposed. The first method applies wavelet-denoising algorithms to the displacement estimates. The second method utilizes angular compounding of the elastograms generated using ultrasound signal frames acquired from different insonification angles. These angular frames are also utilized to estimate all tissue displacement vector components in response to a deformation. These enable the generation of normal and shear strain elastograms and Poisson's ratio

Features of bicrystal growth during the directional crystallization of metal melts

Energy Technology Data Exchange (ETDEWEB)

Gubernatorov, V. V.; Sycheva, T. S., E-mail: sych@imp.uran.ru; Gundyrev, V. M.; Akshentsev, Yu. N. [Russian Academy of Sciences, M.N. Mikheev Institute of Metal Physics, Ural Branch (Russian Federation)

2017-03-15

The factors responsible for the formation of different configurations of boundaries between adjacent crystallites during their growth from melt by Bridgman and Czochralski methods have been considered by an of example Fe–20 wt % Ga alloy and Ni bicrystals. It is found that the configuration of intercrystallite boundary is related to the features of crystallite growth, caused by the strained state of intercrystallite and interphase (crystal–melt) boundaries, the difference in the linear thermal expansion coefficients of the crystallite boundaries and bulk, and the shape (geometry) of the bicrystal cross section. It is suggested that the strained state of boundaries and the formation of substructure in crystallites during directional crystallization from metal melt are significantly affected by their deformation under the melt weight.

Dense Pure Tungsten Fabricated by Selective Laser Melting

Directory of Open Access Journals (Sweden)

Dianzheng Wang

2017-04-01

Full Text Available Additive manufacturing using tungsten, a brittle material, is difficult because of its high melting point, thermal conductivity, and oxidation tendency. In this study, pure tungsten parts with densities of up to 18.53 g/cm3 (i.e., 96.0% of the theoretical density were fabricated by selective laser melting. In order to minimize balling effects, the raw polyhedral tungsten powders underwent a spheroidization process before laser consolidation. Compared with polyhedral powders, the spherical powders showed increased laser absorptivity and packing density, which helped in the formation of a continuous molten track and promoted densification.

Petrological Geodynamics of Mantle Melting II. AlphaMELTS + Multiphase Flow: Dynamic Fractional Melting

Science.gov (United States)

Tirone, Massimiliano

2018-03-01

In this second installment of a series that aims to investigate the dynamic interaction between the composition and abundance of the solid mantle and its melt products, the classic interpretation of fractional melting is extended to account for the dynamic nature of the process. A multiphase numerical flow model is coupled with the program AlphaMELTS, which provides at the moment possibly the most accurate petrological description of melting based on thermodynamic principles. The conceptual idea of this study is based on a description of the melting process taking place along a 1-D vertical ideal column where chemical equilibrium is assumed to apply in two local sub-systems separately on some spatial and temporal scale. The solid mantle belongs to a local sub-system (ss1) that does not interact chemically with the melt reservoir which forms a second sub-system (ss2). The local melt products are transferred in the melt sub-system ss2 where the melt phase eventually can also crystallize into a different solid assemblage and will evolve dynamically. The main difference with the usual interpretation of fractional melting is that melt is not arbitrarily and instantaneously extracted from the mantle, but instead remains a dynamic component of the model, hence the process is named dynamic fractional melting (DFM). Some of the conditions that may affect the DFM model are investigated in this study, in particular the effect of temperature, mantle velocity at the boundary of the mantle column. A comparison is made with the dynamic equilibrium melting (DEM) model discussed in the first installment. The implications of assuming passive flow or active flow are also considered to some extent. Complete data files of most of the DFM simulations, four animations and two new DEM simulations (passive/active flow) are available following the instructions in the supplementary material.

Relativistic self-focusing of intense laser beam in thermal collisionless quantum plasma with ramped density profile

Directory of Open Access Journals (Sweden)

S. Zare

2015-04-01

Full Text Available Propagation of a Gaussian x-ray laser beam has been analyzed in collisionless thermal quantum plasma with considering a ramped density profile. In this density profile due to the increase in the plasma density, an earlier and stronger self-focusing effect is noticed where the beam width oscillates with higher frequency and less amplitude. Moreover, the effect of the density profile slope and the initial plasma density on the laser propagation has been studied. It is found that, by increasing the initial density and the ramp slope, the laser beam focuses faster with less oscillation amplitude, smaller laser spot size and more oscillations. Furthermore, a comparison is made among the laser self-focusing in thermal quantum plasma, cold quantum plasma and classical plasma. It is realized that the laser self-focusing in the quantum plasma becomes stronger in comparison with the classical regime.

Spent oxide fuel regeneration by crystallization in molybdate melts

International Nuclear Information System (INIS)

Ustinov, O.A.; Sukhanov, L.P.; Yakunin, S.A.

2006-01-01

Paper describes a procedure to regenerate spent oxide fuel by its crystallization in molybdate melts. Paper presents the process procedures to regenerate spent fuel of both fast and thermal neutron reactors. One analyzes the advantages of the elaborated procedure [ru

Determination of the ion thermal diffusivity from neutron emission profiles in decay

International Nuclear Information System (INIS)

Sasao, M.; Adam, J.M.; Conroy, S.; Jarvis, O.N.; Marcus, F.B.; Sadler, G.; Belle, P. van

1992-01-01

Spatial profiles of neutron emission are routinely obtained at the Joint European Torus (JET) from line-integrated emissivities measured with a multi-channel instrument. It is shown that the manner in which the emission profiles relax following termination of strong heating with Neutral Beam Injection (NBI) permits the local thermal diffusivity (χ i ) to be obtained with an accuracy of about 20%. The radial profiles of χ i for small minor radius (r/a 2 /s for H-mode plasmas with plasma current I p = 3.1 MA and toroidal field B T = 2.3T. The experimental value of χ i is smallest for Z eff = 2.2 and increases weakly with increasing Z eff . The experimental results disagree by two orders of magnitude with predictions from an ion temperature gradient driven turbulence model. (author) 6 refs., 3 figs

A semi-analytical thermal modelling approach for selective laser melting

NARCIS (Netherlands)

Yang, Y.; van Keulen, A.; Ayas, C.

2018-01-01

Selective laser melting (SLM) wherein a metal part is built in a layer-by-layer manner in a powder bed is a promising and versatile way for manufacturing components with complex geometry. However, components built by SLM suffer from substantial deformation of the part and residual stresses.

Final results of the XR2-1 BWR metallic melt relocation experiment

International Nuclear Information System (INIS)

Gauntt, R.O.; Humphries, L.L.

1997-08-01

This report documents the final results of the XR2-1 boiling water reactor (BWR) metallic melt relocation experiment, conducted at Sandia National Laboratories for the U.S. Nuclear Regulatory Commission. The objective of this experiment was to investigate the material relocation processes and relocation pathways in a dry BWR core following a severe nuclear reactor accident such as an unrecovered station blackout accident. The imposed test conditions (initial thermal state and the melt generation rates) simulated the conditions for the postulated accident scenario and the prototypic design of the lower core test section (in composition and in geometry) ensured that thermal masses and physical flow barriers were modeled adequately. The experiment has shown that, under dry core conditions, the metallic core materials that melt and drain from the upper core regions can drain from the core region entirely without formation of robust coherent blockages in the lower core. Temporary blockages that suspended pools of molten metal later melted, allowing the metals to continue draining downward. The test facility and instrumentation are described in detail. The test progression and results are presented and compared to MERIS code analyses. 6 refs., 55 figs., 4 tabs

Thermal reliability test of Al-34%Mg-6%Zn alloy as latent heat storage material and corrosion of metal with respect to thermal cycling

International Nuclear Information System (INIS)

Sun, J.Q.; Zhang, R.Y.; Liu, Z.P.; Lu, G.H.

2007-01-01

The purpose of this study is to determine the thermal reliability and corrosion of the Al-34%Mg-6%Zn alloy as a latent heat energy storage material with respect to various numbers of thermal cycles. The differential scanning calorimeter (DSC) analysis technique was applied to the alloy after 0, 50, 500 and 1000 melting/solidification cycles in order to measure the melting temperatures and the latent heats of fusion of the alloy. The containment materials were stainless steel (SS304L), carbon steel (steel C20) in the corrosion tests. The DSC results indicated that the change in melting temperature for the alloy was in the range of 3.06-5.3 K, and the latent heat of fusion decreased 10.98% after 1000 thermal cycles. The results show that the investigated Al-34%Mg-6%Zn alloy has a good thermal reliability as a latent heat energy storage material with respect to thermal cycling for thermal energy storage applications in the long term in view of the small changes in the latent heat of fusion and melting temperature. Gravimetric analysis as mass loss (mg/cm 2 ), corrosion rate (mg/day) and a microscopic or metallographic investigation were performed for corrosion tests and showed that SS304L may be considered a more suitable alloy than C20 in long term thermal storage applications

The interaction of a core melt with concrete

International Nuclear Information System (INIS)

Reimann, M.; Holleck, H.; Skokan, A.; Perinic, D.

1977-01-01

In its fourth phase, a hypothetic core melt interacts with the concrete of the reactor foundation. This phase may last several days. Experimental laboratory investigations and theoretical models on the basis of model experiments aim at determining the time curve of the temperature of the core melt in order to quantify the processes up to the solidification of the melt and the end of concrete destroyal. Material interactions: 1) The two phases of the core melt, oxidic and metallic, remain separate for a long period of time. In dependence of the degree of oxidation of the system, the elemental distribution and, in particular, the fission products in the melt may be assessed. 2) The changes in the material values of the core melt in dependence of the temperature curve may be qualitatively assessed. 3) The solidification temperature of the oxidic phase of the core melt may be given in dependence of (UO 2 + ZrO 2 ) content. Thermal interactions: 1) The ratio vertical/radial erosion, which determines the cavity shape, is described in the correct order of magnitude by the extended film model. 2) The correct order of magnitude of the erosion rates is described by the concrete destruction model coupled with the film model. 3) The effects of the different concrete destruction enthalpies and concrete compositions (amount of gaseous decomposition products) may be estimated by the model calculations. (orig./HP) [de

"Chemical contraction" in rubidium-bismuth melts

Science.gov (United States)

Khairulin, R. A.; Abdullaev, R. N.; Stankus, S. V.

2017-10-01

The density and thermal expansion of liquid rubidium and rubidium-bismuth alloy containing 25.0 at % Bi were measured by the gamma-ray attenuation technique at temperatures from liquidus to 1000 K. The results of this study were compared with the data obtained by other authors. The molar volume of the Rb75Bi25 melt strongly deviates from the additivity rule for ideal solutions.

Applying of isoconversional analysis to calorimetric data on the gel melting

Science.gov (United States)

Dranca, I.; Lupascu, T.; Povar, I.

2012-02-01

The present study is concerned to the thermal stability of gelatin gels that is defined that their resistance to melting or, in other words, to the thermally stimulated transitions from gel to sol. The both sol-gel and gel-sol transitions were followed by regular Mettler-Toledo DSC 823e and stochastically modulated multi-frequency DSC (TOPEM® by Mettler-Toledo). The DSC data have been treated by using an advanced isoconversional method developed by Vyazovkin [1,2]. The method allows revealing a variation in the effective activation energy (Eα) with the extent of conversion (α). It has been discovered that an increase in the concentration of gelatin solutions causes an increase in the energy barrier to melting of non-isothermally prepared gels.

Integrated System of Thermal/Dimensional Analysis for Quality Control of Metallic Melt and Ductile Iron Casting Solidification

Science.gov (United States)

Stan, Stelian; Chisamera, Mihai; Riposan, Iulian; Neacsu, Loredana; Cojocaru, Ana Maria; Stan, Iuliana

2018-03-01

The main objective of the present work is to introduce a specific experimental instrument and technique for simultaneously evaluating cooling curves and expansion or contraction of cast metals during solidification. Contraction/expansion analysis illustrates the solidification parameters progression, according to the molten cast iron characteristics, which are dependent on the melting procedure and applied metallurgical treatments, mold media rigidity and thermal behavior [heat transfer parameters]. The first part of the paper summarizes the performance of this two-mold device. Its function is illustrated by representative shrinkage tendency results in ductile cast iron as affected by mold rigidity (green sand and furan resin sand molds) and inoculant type (FeSi-based alloys), published in part previously. The second part of the paper illustrates an application of this equipment adapted for commercial foundry use. It conducts thermal analysis and volume change measurements in a single ceramic cup so that mold media as well as solidification conditions are constants, with cast iron quality as the variable. Experiments compared gray and ductile cast iron solidification patterns. Gray iron castings are characterized by higher undercooling at the beginning and at the end of solidification and lower graphitic expansion. Typically, ductile cast iron exhibits higher graphitic, initial expansion, conducive for shrinkage formation in soft molds.

Microscale solid-state thermal diodes enabling ambient temperature thermal circuits for energy applications

KAUST Repository

Wang, Song

2017-05-10

Thermal diodes, or devices that transport thermal energy asymmetrically, analogous to electrical diodes, hold promise for thermal energy harvesting and conservation, as well as for phononics or information processing. The junction of a phase change material and phase invariant material can form a thermal diode; however, there are limited constituent materials available for a given target temperature, particularly near ambient. In this work, we demonstrate that a micro and nanoporous polystyrene foam can house a paraffin-based phase change material, fused to PMMA, to produce mechanically robust, solid-state thermal diodes capable of ambient operation with Young\\'s moduli larger than 11.5 MPa and 55.2 MPa above and below the melting transition point, respectively. Moreover, the composites show significant changes in thermal conductivity above and below the melting point of the constituent paraffin and rectification that is well-described by our previous theory and the Maxwell–Eucken model. Maximum thermal rectifications range from 1.18 to 1.34. We show that such devices perform reliably enough to operate in thermal diode bridges, dynamic thermal circuits capable of transforming oscillating temperature inputs into single polarity temperature differences – analogous to an electrical diode bridge with widespread implications for transient thermal energy harvesting and conservation. Overall, our approach yields mechanically robust, solid-state thermal diodes capable of engineering design from a mathematical model of phase change and thermal transport, with implications for energy harvesting.

GLASS MELTING PHENOMENA, THEIR ORDERING AND MELTING SPACE UTILISATION

Directory of Open Access Journals (Sweden)

Němec L.

2013-12-01

Full Text Available Four aspects of effective glass melting have been defined – namely the fast kinetics of partial melting phenomena, a consideration of the melting phenomena ordering, high utilisation of the melting space, and effective utilisation of the supplied energy. The relations were defined for the specific melting performance and specific energy consumption of the glass melting process which involve the four mentioned aspects of the process and indicate the potentials of effective melting. The quantity “space utilisation” has been treated in more detail as an aspect not considered in practice till this time. The space utilisation was quantitatively defined and its values have been determined for the industrial melting facility by mathematical modelling. The definitions of the specific melting performance and specific energy consumption have been used for assessment of the potential impact of a controlled melt flow and high space utilisation on the melting process efficiency on the industrial scale. The results have shown that even the partial control of the melt flow, leading to the partial increase of the space utilisation, may considerably increase the melting performance, whereas a decrease of the specific energy consumption was determined to be between 10 - 15 %.

Thermal History and Crystallinity of Sheet Intrusions

Science.gov (United States)

Whittington, A. G.; Nabelek, P. I.; Hofmeister, A.

2011-12-01

Magma emplaced in a sheet intrusion has two potential fates: to crystallize, or quench to glass. Rapidly chilled sheet margins are typically glassy or microcrystalline, while interiors are coarser-grained. The actual textures result from a combination of thermal history and crystallization kinetics, which are related by various feedback mechanisms. The thermal history of cooling sheet intrusions is often approximated using the analytical solution for a semi-infinite half-space, which uses constant thermal properties such as heat capacity (CP), thermal diffusivity (D) and thermal conductivity (k = DρCP), where ρ is density. In reality, both CP and D are strongly T-dependent for glasses and crystals, and melts have higher CP and lower D than crystals or glasses. Another first-order feature ignored in the analytical solution is latent heat of crystallization (ΔHxt), which can be implemented numerically as extra heat capacity over the crystallization interval. For rhyolite melts, D is ~0.5 mm2s-1 and k is ~1.5 Wm-1K-1, which are similar to those of major crustal rock types and granitic protoliths at magmatic temperatures, suggesting that changes in thermal properties accompanying partial melting of the crust should be relatively minor. Numerical models of hot (~920°C liquidus for 0.5 wt.% H2O) shallow rhyolite intrusions indicate that the key difference in thermal history between bodies that quench to obsidian, and those that crystallize, results from the release of latent heat of crystallization, which enables bodies that crystallize to remain at high temperatures for much longer times. The time to solidification is similar in both cases, however, because solidification requires cooling through the glass transition (Tg ~620°C) in the first case, and cooling only to the solidus (~770°C) in the second. For basaltic melts, D is ~0.3 mm2s-1 and k is ~1.0 Wm-1K-1, compared to ~0.6 mm2s-1 and 2.5 Wm-1K-1 for crystalline basalt or peridotite at magmatic temperatures

Fragmentation of low-melting metals by collapsing steam bubbles

International Nuclear Information System (INIS)

Benz, R.

1979-08-01

When a hot melt meets a vaporable liquid of lower temperature, explosive vaporisation of the cooler liquid may be the result. This is called a steam explosion if a substantial amount of thermal energy is converted into mechanical energy. One important step in understanding about steam explosions is to explain the surface increase of the hot melt. There are several competing fragmentation hypotheses, but so far there has been no model to describe fragmentation criteria as well as the time curve of surface increase on the basis of physical processes. An overall model is now given for one of the possible fragmentation mechanisms, i.e. the division of the melt by collapsing steam bubbles. The model estimates the surface increase of the melt on the basis of heavy supercooled boiling, the heat transfer connected with it, the transfer of mechanical energy during steam bubble collapse, and the solidification of the melt. The results of the calculations have shown that basic experimental observations, e.g. time and extent of fragmentation, are well presented in the model with regard to their order of magnitude. The model presents a qualitatively correct description of the effects of important influencing factors, e.g. supercooling of the coolant or initial temperature of the melt. (orig.) [de

Application of multicomponent medium model for numerical simulation of reactor element melting and melt relocation under severe accidents

International Nuclear Information System (INIS)

Vladimir Ya Kumaev

2005-01-01

Full text of publication follows: Numerical simulation of the melting processes is necessary in substantiating the safety of new generation reactors to determine the quantitative characteristics of the melt formed, destruction of reactor vessel and components, melt interaction processes in the melt localization systems (MLS), formation and transport of hydrogen, radioactive aerosols under severe accidents. The results of computations will be applied in developing the procedures for severe accident management and mitigation of its consequences and designing melt localization systems. The report is devoted to the development and application of the two-dimensional and three-dimensional versions of the DINCOR code intended for numerical simulation of the thermal hydraulic processes in a multicomponent medium with solid-liquid phase changes. The basic set of equations of multicomponent medium is presented. The numerical method to solve the governing equations is discussed. Some examples of two-dimensional code applications are presented. The experience of application of the code has shown that joint calculations of hydrodynamics, heat transfer, stratification and chemical interaction enable the process description accuracy to be significantly increased and the number of initial experimental data to be reduced. The multicomponent medium model can be used as the base for the development of a three-dimensional version of the code. At the same time, it was established that the models being used need be further developed. The most important problems are the following: -development of the local mathematical models of liquefaction and solidification of materials under front melting and melting due to the action of internal sources; -development of the model of incompressible components separation; -development of the models of dissolution and chemical interaction of multicomponent medium components. In conclusion possible verification of the computer code is discussed. (author)

Measuring technique of super high temperature thermal properties of reactor core materials

International Nuclear Information System (INIS)

Ono, Akira; Baba, Tetsuya; Watanabe, Hideo; Matsumoto, Tsuyoshi

1998-01-01

In this study, thermal properties of reactor core materials used for water cooled reactors and FBR were tried to develop a technique to measure their melt states at less than 3,000degC in order to contribute more correct evaluation of the reactor core behavior at severe accident. Then, a thermal property measuring method of high temperature melt by using floating method was investigated and its fundamental design was begun to investigate under a base of optimum judgement on the air flow floating throw-down method. And, in order to measure emissivity of melt specimen surface essential for correct temperature measurement using the throw down method, a spectroscopic emissivity measuring unit using an ellipsometer was prepared and induced. On the thermal properties measurement using the holding method, a specimen container to measure thermal diffusiveness of the high temperature melts by using laser flashing method was tried to prepare. (G.K.)

Assessment for Melting Temperature Measurement of Nucleic Acid by HRM.

Science.gov (United States)

Wang, Jing; Pan, Xiaoming; Liang, Xingguo

2016-01-01

High resolution melting (HRM), with a high sensitivity to distinguish the nucleic acid species with small variations, has been widely applied in the mutation scanning, methylation analysis, and genotyping. For the aim of extending HRM for the evaluation of thermal stability of nucleic acid secondary structures on sequence dependence, we investigated effects of the dye of EvaGreen, metal ions, and impurities (such as dNTPs) on melting temperature ( T m ) measurement by HRM. The accuracy of HRM was assessed as compared with UV melting method, and little difference between the two methods was found when the DNA T m was higher than 40°C. Both insufficiency and excessiveness of EvaGreen were found to give rise to a little bit higher T m , showing that the proportion of dye should be considered for precise T m measurement of nucleic acids. Finally, HRM method was also successfully used to measure T m s of DNA triplex, hairpin, and RNA duplex. In conclusion, HRM can be applied in the evaluation of thermal stability of nucleic acid (DNA or RNA) or secondary structural elements (even when dNTPs are present).

Profile consistency, anomalous electron thermal conduction, and confinement analysis of tokamak devices

International Nuclear Information System (INIS)

Qu Wenxiao

1992-01-01

Assuming that there exists a position in the tokamak plasma where the energy transport is dominated by local anomalous electron thermal conduction and taking advantage of the basic experimental result usually referred to as profile consistency, the authors obtain a more convincing approach to the description of the confinement property of tokamak devices without touching upon the physical mechanism of global plasma energy transport. 8 refs

Seismic Evidence for Possible Slab Melting from Strong Scattering Waves

Directory of Open Access Journals (Sweden)

Cheng-Horng Lin

2011-01-01

Full Text Available Slab melting in young and hot subduction zones has been studied using geochemical observations and thermal modelling, but there are few data from seismic studies to confirm slab melting. Also the detailed geometry in the deep part of the melting slab is often ambiguous in that the intraslab earthquakes within the Wadati-Benioff zone are only limited to shallower depths. To improve our understanding of both the seismic features and geometry found in a young and hot subducted slab, I analyzed anomalous moonquake-like seismograms that were generated by an intermediate-depth earthquake recorded in central Japan. For this study, possible reflected (or scattered sources were examined using detailed analyses of particle motions and a grid search for travel-time differences between the direct and later P-waves. The results show that using strong seismic scattering, slab melting is likely occurring in the deeper, flexing part of the subducted Philippine Sea plate. Because the subducted Philippine Sea plate in central Japan is young and therefore hot, partial melting might have taken place to produce abundant melting spots in the subducted slab. Melting spots, identified as ¡§bright spots,¡¨ could efficiently reflect or scatter seismic energy and generate many later phases with large amplitudes.

Melting of iron nanoparticles embedded in silica prepared by mechanical milling

International Nuclear Information System (INIS)

Ding, Peng; Ma, Ji; Cao, Hui; Liu, Yi; Wang, Lianwen; Li, Jiangong

2013-01-01

Highlights: • Melting of metallic nanoparticles was studied for some eight elements. • This slim range of materials is successfully expanded to iron. • A mechanical-milled iron–silica composite is employed. • For iron particles of 15 nm in diameter, the melting point depression is 30 K. • The measured data is in agreement with our theoretical calculations. -- Abstract: For decades, experimental studies on the size-dependent melting of metals are regretfully limited to some eight archetypal examples. In this work, to expand this slim range of materials, the melting behavior of Fe nanoparticles embedded in SiO 2 prepared by using mechanical milling are investigated. Effects of factors in sample preparation on the size, isolation and thermal stability of Fe nanoparticles are systematically studied. On this basis, the size-dependent melting of Fe is successfully traced: for Fe nanoparticles with a diameter of about 15 nm, the melting point depression is 30 °C in comparison with bulk Fe, in accordance with our recent theoretical prediction

Thermal efficiency on welding of AA6061-T6 alloy by modified indirect electric arc and current signals digitalisation; Eficiencia termica en soldadura de la aleacion AA6061-T6 por arco electrico indirecto modificado y digitalizacion de senales de intensidad de corriente

Energy Technology Data Exchange (ETDEWEB)

Ambriz, R. R.; Barrera, G.; Garcia, R.; Lopez, V. H.

2009-07-01

The results of the thermal efficiency on welding by modified indirect electric arc technique (MIEA) [1] of the 6061- T6 aluminum alloy are presented. These values are in a range of 90 to 94 %, which depend of the preheating employed. Thermal efficiency was obtained by means of a balance energy which considers the heat input, the amount of melted mass of the welding profiles, and welding parameters during the joining, especially of the arc current data acquisition. Also, some dimensionless parameters were employed in order to determine the approximation grade of the melted pool, the heat affected zone (HAZ), and their corresponding values with the experimental results. (Author) 13 refs.

Low-Frequency Internal Friction Study on the Structural Changes in Polymer Melts

International Nuclear Information System (INIS)

Xue-Bang, Wu; Qiao-Ling, Xu; Shu-Ying, Shang; Jia-Peng, Shui; Chang-Song, Liu; Zhen-Gang, Zhu

2008-01-01

With the help of the low-frequency internal friction method, we investigate the structural properties of polymer melts, such as amorphous polystyrene (PS), poly(methyl methacrylate) (PMMA), and semi-crystalline poly(ethylene oxide) (PEO). An obvious peak of relaxation type is found in each of the internal friction curves. The peak temperature T p follows the relation T p ≈ (1.15 – 1.18) T g for PS and PMMA melts, while it follows T p ≈ 1.22T m for PEO melt, with T g being the glass transition temperature and T m the melting temperature. Based on the analysis of the features of this peak, it is found that this peak is related to the liquid-liquid transition temperature T u of polymer melts. Mechanism of the liquid-liquid transition is suggested to be thermally-activated collective relaxation through cooperation. This finding may be helpful to understand the structural changes in polymer melts. In addition, the internal friction technique proves to be effective in studying dynamics in polymer melts

Parametric studies on containment thermal hydraulic loads during high pressure melt ejection in a BWR

Energy Technology Data Exchange (ETDEWEB)

Silde, A.; Lindholm, I. [VTT Energy, Espoo (Finland)

1997-12-01

The containment thermal hydraulic loads during high pressure melt ejection in a Nordic BWR are studied parametrically with the CONTAIN and the MELCOR codes. The work is part of the Nordic RAK-2 project. The containment analyses were divided into two categories according to composition of the discharged debris: metallic and oxidic debris cases. In the base case with highly metallic debris, all sources from the reactor coolant system to the containment were based on the MELCOR/BH calculation. In the base case with the oxidic debris, the source data was specified assuming that {approx} 15% of the whole core material inventory and 34,000 kg of saturated water was discharged from the reactor pressure vessel (RPV) during 30 seconds. In this case, the debris consisted mostly of oxides. The highest predicted containment pressure peaks were about 8.5 bar. In the scenarios with highly metallic debris source, very high gas temperature of about 1900 K was predicted in the pedestal, and about 1400 K in the upper drywell. The calculations with metallic debris were sensititive to model parameters, like the particle size and the parameters, which control the chemical reaction kinetics. In the scenarios with oxidic debris source, the predicted pressure peaks were comparable to the cases with the metallic debris source. The maximum gas temperatures (about 450-500 K) in the containment were, however, significantly lower than in the respective metallic debris case. The temperatures were also insensitive to parametric variations. In addition, one analysis was performed with the MELCOR code for benchmarking of the MELCOR capabilities against the more detailed CONTAIN code. The calculations showed that leak tightness of the containment penetrations could be jeopardized due to high temperature loads, if a high pressure melt ejection occurred during a severe accident. Another consequence would be an early containment venting. (au). 28 refs.

HAZARDS OF THERMAL EXPANSION FOR RADIOLOGICAL CONTAINER ENGULFED IN FIRE

Energy Technology Data Exchange (ETDEWEB)

Donna Post Guillen

2013-05-01

Fire accidents pose a serious threat to nuclear facilities. It is imperative that transport casks or shielded containers designed to transport/contain radiological materials have the ability to withstand a hypothetical fire. A numerical simulation was performed for a shielded container constructed of stainless steel and lead engulfed in a hypothetical fire as outlined by 10 CFR §71.73. The purpose of this analysis was to determine the thermal response of the container during and after the fire. The thermal model shows that after 30 minutes of fire, the stainless steel will maintain its integrity and not melt. However, the lead shielding will melt since its temperature exceeds the melting point. Due to the method of construction of the container under consideration, ample void space must be provided to allow for thermal expansion of the lead upon heating and melting, so as to not overstress the weldment.

Petrological Geodynamics of Mantle Melting I. AlphaMELTS + Multiphase Flow: Dynamic Equilibrium Melting, Method and Results

Directory of Open Access Journals (Sweden)

Massimiliano Tirone

2017-10-01

Full Text Available The complex process of melting in the Earth's interior is studied by combining a multiphase numerical flow model with the program AlphaMELTS which provides a petrological description based on thermodynamic principles. The objective is to address the fundamental question of the effect of the mantle and melt dynamics on the composition and abundance of the melt and the residual solid. The conceptual idea is based on a 1-D description of the melting process that develops along an ideal vertical column where local chemical equilibrium is assumed to apply at some level in space and time. By coupling together the transport model and the chemical thermodynamic model, the evolution of the melting process can be described in terms of melt distribution, temperature, pressure and solid and melt velocities but also variation of melt and residual solid composition and mineralogical abundance at any depth over time. In this first installment of a series of three contributions, a two-phase flow model (melt and solid assemblage is developed under the assumption of complete local equilibrium between melt and a peridotitic mantle (dynamic equilibrium melting, DEM. The solid mantle is also assumed to be completely dry. The present study addresses some but not all the potential factors affecting the melting process. The influence of permeability and viscosity of the solid matrix are considered in some detail. The essential features of the dynamic model and how it is interfaced with AlphaMELTS are clearly outlined. A detailed and explicit description of the numerical procedure should make this type of numerical models less obscure. The general observation that can be made from the outcome of several simulations carried out for this work is that the melt composition varies with depth, however the melt abundance not necessarily always increases moving upwards. When a quasi-steady state condition is achieved, that is when melt abundance does not varies significantly

Mechanism of interaction of Co-B and Fe-B melts with ceramic materials

International Nuclear Information System (INIS)

Filonov, M.R.; Anikin, D.Yu.; Pecherkin, K.A.

2003-01-01

Stability of ceramic materials has been studied in the medium of melts being rendered amorphous. Measurements of limiting wetting angle for these materials were carried out on the ceramic surface. Two conclusions were made from the results of the experiments: melt-ceramics interaction takes place mainly through the slag phase; boron nitride is the most stable ceramics for melting and pouring of melts being rendered amorphous in the air. Materials on the basis of BN were synthesized by the self-propagating high-temperature synthesis. Other refractory compounds were introduced in the ceramics composition for the purpose of improving such service properties as fire resistance, thermal resistance, mechanical strength, stability of compounds to the effect of reaction-active melts. The most promising refractory compositions were determined from the results of the studies [ru

PCR melting profile (PCR MP - a new tool for differentiation of Candida albicans strains

Directory of Open Access Journals (Sweden)

Nowak Magdalena

2009-11-01

Full Text Available Abstract Background We have previously reported the use of PCR Melting Profile (PCR MP technique based on using low denaturation temperatures during ligation mediated PCR (LM PCR for bacterial strain differentiation. The aim of the current study was to evaluate this method for intra-species differentiation of Candida albicans strains. Methods In total 123 Candida albicans strains (including 7 reference, 11 clinical unrelated, and 105 isolates from patients of two hospitals in Poland were examined using three genotyping methods: PCR MP, macrorestriction analysis of the chromosomal DNA by pulsed-field gel electrophoresis (REA-PFGE and RAPD techniques. Results The genotyping results of the PCR MP were compared with results from REA-PFGE and RAPD techniques giving 27, 26 and 25 unique types, respectively. The results showed that the PCR MP technique has at least the same discriminatory power as REA-PFGE and RAPD. Conclusion Data presented here show for the first time the evaluation of PCR MP technique for candidial strains differentiation and we propose that this can be used as a relatively simple and cheap technique for epidemiological studies in short period of time in hospital.

High-resolution melt-curve analysis of random-amplified-polymorphic-DNA markers, for the characterisation of pathogenic Leptospira

DEFF Research Database (Denmark)

Tulsiani, Suhella; Craig, S B; Graham, G C

2010-01-01

A new test for pathogenic Leptospira isolates, based on RAPD-PCR and high-resolution melt (HRM) analysis (which measures the melting temperature of amplicons in real time, using a fluorescent DNA-binding dye), has recently been developed. A characteristic profile of the amplicons can be used...... typed against 13 previously published RAPD primers, using a real-time cycler (the Corbett Life Science RotorGene 6000) and the optimised reagents from a commercial kit (Quantace SensiMix). RAPD-HRM at specific temperatures generated defining amplicon melt profiles for each of the tested serovars....... These profiles were evaluated as difference-curve graphs generated using the RotorGene software package, with a cut-off of at least 8 'U' (plus or minus). The results demonstrated that RAPD-HRM can be used to measure serovar diversity and establish identity, with a high degree of stability. The characterisation...

Development and prototype testing of MgCl 2 /graphite foam latent heat thermal energy storage system

Energy Technology Data Exchange (ETDEWEB)

Singh, Dileep; Yu, Wenhua; Zhao, Weihuan; Kim, Taeil; France, David M.; Smith, Roger K.

2018-01-01

Composites of graphite foam infiltrated with a magnesium chloride phase-change material have been developed as high-temperature thermal energy storage media for concentrated solar power applications. This storage medium provides a high thermal energy storage density, a narrow operating temperature range, and excellent heat transfer characteristics. In this study, experimental investigations were conducted on laboratory-scale prototypes with magnesium chloride/graphite foam composite as the latent heat thermal energy storage system. Prototypes were designed and built to monitor the melt front movement during the charging/discharging tests. A test loop was built to ensure the charging/discharging of the prototypes at temperatures > 700 degrees C. Repeated thermal cycling experiments were carried out on the fabricated prototypes, and the experimental temperature profiles were compared to the predicted results from numerical simulations using COMSOL Multiphysics software. Experimental results were found to be in good agreement with the simulations to validate the thermal models.

Melting Behavior of Organic Nanocrystals Grown in Sol-gel Matrices

International Nuclear Information System (INIS)

Sanz, N.; Boudet, A.; Ibanez, A.

2002-01-01

We have characterized the thermal stability of organic nanocrystals grown in the pores of sol-gel matrices. The structure has been measured with transmission electron microscopy (TEM) analysis. Depending on the nature of organic molecules and sol-gel matrices, we have modified the dye-matrix interactions and the interfacial structure between nanocrystals and gel-glasses. When the dye-matrix interactions are weak (Van der Waals' bonds), the corresponding interfacial structure observed by TEM is sharp and the nanocrystals melt below the bulk melting point. On the other hand, when the dye-matrix interactions are strong (hydrogen bonds), the interfacial structure is fuzzy and a great superheating of organic nanocrystals is observed in comparison to the bulk melting point of the dye

Impact of beryllium additions on thermal and mechanical properties of conventionally solidified and melt-spun Al–4.5 wt.%Mn–x wt.%Be (x = 0, 1, 3, 5) alloys

International Nuclear Information System (INIS)

Öz, Turan; Karaköse, Ercan; Keskin, Mustafa

2013-01-01

Highlights: • Thermal and mechanical properties of Al–Mn–Be alloys were investigated. • IQC Al–Mn–Be alloys were synthesized by the CS and MS techniques. • The volume fraction of IQC increases continuously with Be content. • The melting points of the QC i-phase were determined between 652 °C and 675 °C. • The maximum H V and σ values were found to be 124 kg/mm 2 and 458 MPa with the addition of 5% Be. - Abstract: The influence of beryllium (Be) addition on the quasicrystal-forming ability, thermal and mechanical properties of Al–4.5 wt.%Mn–x wt.%Be (x = 0, 1, 3, 5) alloys was investigated in this study. Quasicrystalline Al–Mn–Be alloys were synthesized by the conventionally casting and melt spinning techniques. The microstructures of the samples were characterized by scanning electron microscopy (SEM) and the phase composition was identified by X-ray diffractometry (XRD). The phase transition during the solidification process was studied by differential scanning calorimetry (DSC) and differential thermal analysis (DTA) under an Ar atmosphere. The mechanical properties of the conventionally solidified (CS) and melt-spun (MS) samples were measured by a Vickers micro-hardness indenter and tensile-strength tests. The Al–4.5 wt.%Mn alloy has a hexagonal structure and minor dendritic icosahedral quasicrystalline phase (IQC) precipitates surrounded by an α-Al matrix. Addition of Be into the Al–4.5 wt.%Mn alloy generates intermetallic Be 4 AlMn and IQC phases with the extinction of the hexagonal phase, and the fraction of IQC increases continuously with the increase in Be content. A considerable improvement in microhardness and tensile strength values was observed due to the addition of Be in different percentages into the composition

Determination of the ion thermal diffusivity from neutron emission profiles in decay

Energy Technology Data Exchange (ETDEWEB)

Sasao, M. (National Inst. for Fusion Science, Nagoya (Japan)); Adam, J.M. (AEA Industrial Technology, Harwell (United Kingdom)); Conroy, S.; Jarvis, O.N.; Marcus, F.B.; Sadler, G.; Belle, P. van (Commission of the European Communities, Abingdon (United Kingdom). JET Joint Undertaking)

1992-01-01

Spatial profiles of neutron emission are routinely obtained at the Joint European Torus (JET) from line-integrated emissivities measured with a multi-channel instrument. It is shown that the manner in which the emission profiles relax following termination of strong heating with Neutral Beam Injection (NBI) permits the local thermal diffusivity ([chi][sub i]) to be obtained with an accuracy of about 20%. The radial profiles of [chi][sub i] for small minor radius (r/a < 0.6) were found to be flat and to take values between 0.3 and 1.1 m[sup 2]/s for H-mode plasmas with plasma current I[sub p] = 3.1 MA and toroidal field B[sub T] = 2.3T. The experimental value of [chi][sub i] is smallest for Z[sub eff] = 2.2 and increases weakly with increasing Z[sub eff]. The experimental results disagree by two orders of magnitude with predictions from an ion temperature gradient driven turbulence model. (author) 6 refs., 3 figs.

Microstructure and properties of high chrome steel roller after laser surface melting

International Nuclear Information System (INIS)

Li Meiyan; Wang Yong; Han Bin; Zhao Weimin; Han Tao

2009-01-01

Laser surface melting of high chrome steels was achieved by a 5 kW continuous wave CO 2 laser. The microstructure of the laser surface-melted steels was investigated by scanning electron microscopy, transmission electron microscopy and X-ray diffractometry, and the hardness profiles were determined by a Vickers hardness tester. The corrosion behavior in 3.5% NaCl solution was studied by electrochemical corrosion equipment. The large carbides of high chrome steels are completely dissolved and ultrafine dendrites of austenite with submicroscopic M 23 C 6 carbides precipitation are formed in the melted zone. The austenite in the melted zone has a high tempering stability. The corrosion resistance of the laser surface-melted steels is significantly improved due to the dissolution of carbides and the increase of the alloying elements in the solid solution as well as the large amount of austenite.

Numerical analysis of temperature profile and thermal-stress during excimer laser induced heteroepitaxial growth of patterned amorphous silicon and germanium bi-layers deposited on Si(100)

Energy Technology Data Exchange (ETDEWEB)

Conde, J.C., E-mail: jconde@uvigo.e [Dpto. Fisica Aplicada, E.T.S.I.I. University of Vigo, Campus Universitario, Rua Maxwell s/n, E-36310 Vigo (Spain); Martin, E. [Dpto. de Mecanica, Maquinas y Motores Termicos y Fluidos, E.T.S.I.I. University of Vigo, Campus Universitario, Rua Maxwell s/n, E-36310 Vigo (Spain); Gontad, F.; Chiussi, S. [Dpto. Fisica Aplicada, E.T.S.I.I. University of Vigo, Campus Universitario, Rua Maxwell s/n, E-36310 Vigo (Spain); Fornarini, L. [Enea-Frascati, Via Enrico Fermi 45, I-00044 Frascati (Roma) (Italy); Leon, B. [Dpto. Fisica Aplicada, E.T.S.I.I. University of Vigo, Campus Universitario, Rua Maxwell s/n, E-36310 Vigo (Spain)

2010-02-26

A Finite Element Method (FEM) study of the coupled thermal-stress during the heteroepitaxial growth induced by excimer laser radiation of patterned amorphous hydrogenated silicon (a-Si:H) and germanium (a-Ge:H) bi-layers deposited on a Si(100) wafer is presented. The ArF (193 nm) excimer laser provides high energy densities during very short laser pulse (20 ns) provoking, at the same time, melting and solidification phenomena in the range of several tenths of nanoseconds. These phenomena play an important role during the growth of heteroepitaxial SiGe structures characterized by high Ge concentration buried under a Si rich surface. In addition, the thermal-stresses that appear before the melting and after the solidification processes can also affect to the epitaxial growth of high quality SiGe alloys in these patterned structures and, in consequence, it is necessary to predict their effects. The aim of this work is to estimate the energy threshold and the corresponding thermal-stresses in the interfaces and the borders of these patterned structures.

Numerical analysis of temperature profile and thermal-stress during excimer laser induced heteroepitaxial growth of patterned amorphous silicon and germanium bi-layers deposited on Si(100)

International Nuclear Information System (INIS)

Conde, J.C.; Martin, E.; Gontad, F.; Chiussi, S.; Fornarini, L.; Leon, B.

2010-01-01

A Finite Element Method (FEM) study of the coupled thermal-stress during the heteroepitaxial growth induced by excimer laser radiation of patterned amorphous hydrogenated silicon (a-Si:H) and germanium (a-Ge:H) bi-layers deposited on a Si(100) wafer is presented. The ArF (193 nm) excimer laser provides high energy densities during very short laser pulse (20 ns) provoking, at the same time, melting and solidification phenomena in the range of several tenths of nanoseconds. These phenomena play an important role during the growth of heteroepitaxial SiGe structures characterized by high Ge concentration buried under a Si rich surface. In addition, the thermal-stresses that appear before the melting and after the solidification processes can also affect to the epitaxial growth of high quality SiGe alloys in these patterned structures and, in consequence, it is necessary to predict their effects. The aim of this work is to estimate the energy threshold and the corresponding thermal-stresses in the interfaces and the borders of these patterned structures.

Wetting and surface tension of bismate glass melt

International Nuclear Information System (INIS)

Shim, Seung-Bo; Kim, Dong-Sun; Hwang, Seongjin; Kim, Hyungsun

2009-01-01

Lead oxide glass frits are used widely in the electronics industry for low-temperature firing. On the other hand, one of the low-sintering and low-melting lead-free glass systems available, the bismate glass system, is considered to be an alternative to lead oxide glass. In order to extend the applications of Bi 2 O 3 glasses, this study examined the thermophysical properties of low-melting Bi 2 O 3 -B 2 O 3 -ZnO-BaO-Al 2 O 3 -SiO 2 glass frits with various ZnO/B 2 O 3 ratios. The fundamental thermal properties, such as glass transition temperature and softening point, were examined by differential thermal analysis and a glass softening point determination system. The wetting angles, viscosities and surface tension of the various bismate glasses on an alumina substrate were measured using hot-stage microscopy and the sessile drop method. These thermophysical properties will be helpful in understanding the work of adhesion and the liquid spread kinetics of glass frits.

Simplified methods applied to the complete thermal and mechanical behaviour of a pressure vessel during a severe accident

International Nuclear Information System (INIS)

Dupas, P.

1996-01-01

EDF has developed a software package of simplified methods (proprietary ones from literature) in order to study the thermal and mechanical behaviour of a PWR pressure vessel during a severe accident involving a corium localization in the vessel lower head. Using a part of this package, we can evaluate for instance successively: the heat flux at the inner surface of the vessel (conductive or convective pool of corium); the thermal exchange coefficient between the vessel and the outside (dry pit or flooded pit, watertight thermal insulation or not); the complete thermal evolution of the vessel (temperature profile, melting); the possible global plastic failure of the vessel; the creep behaviour in the vessel. These simplified methods are low cost alternative to finite element calculations which are yet used to validate the previous methods, waiting for experimental results to come. (authors)

Enhanced mechanical and thermal properties of polystyrene nanocomposites prepared using organo-functionalized NiAl layered double hydroxide via melt intercalation technique

Directory of Open Access Journals (Sweden)

Kelothu Suresh

2017-06-01

Full Text Available The article reports upon the preparation and characterization of organo-functionalized NiAl layered double hydroxide (LDH-polystyrene (PS nanocomposites. Initially, pristine NiAl LDH was synthesized via the co-precipitation technique and was subsequently treated using sodium dodecyl sulfate to obtain organo-functionalized NiAl LDH (ONiAl LDH. PS nanocomposites were fabricated by melt intercalation using a twin screw extruder in presence of ONiAl LDH nanofiller (1, 3, 5, and 7 wt.%. The PS nanocomposites were characterized for their structural, thermal and mechanical properties. The dispersion and morphology of the obtained PS nanocomposites were investigated by X-ray diffraction (XRD and transmission electron microscopy (TEM. Mechanical and thermal properties of the PS nanocomposites as a function of LDH content were examined by tensile tests, thermogravimetric analysis (TGA and differential scanning calorimetry (DSC. The XRD and TEM results revealed the formation of an exfoliated structure of the PS nanocomposite with 1 wt.% ONiAl LDH loading. The maximum improvements of the mechanical and thermal properties of the nanocomposites with ONiAl LDH loading over pristine PS included tensile strength = 34.5% (1 wt.%, thermal decomposition temperatures (T15% = 27.4 °C (7 wt.%, and glass transition temperature (Tg = 4.3 °C (7 wt.%. The PS nanocomposites possessed higher mechanical strength and thermal degradation resistance compared to the pristine PS. The activation energy (Ea and reaction mechanism with respect to thermal degradation of the pristine PS and its nanocomposites were evaluated by the Coats-Redfern and Criado model, respectively.

Shock melting and vaporization of lunar rocks and minerals.

Science.gov (United States)

Ahrens, T. J.; O'Keefe, J. D.

1972-01-01

The entropy associated with the thermodynamic states produced by hypervelocity meteoroid impacts at various velocities are calculated for a series of lunar rocks and minerals and compared with the entropy values required for melting and vaporization. Taking into account shock-induced phase changes in the silicates, we calculate that iron meteorites impacting at speeds varying from 4 to 6 km/sec will produce shock melting in quartz, plagioclase, olivine, and pyroxene. Although calculated with less certainty, impact speeds required for incipient vaporization vary from 7 to 11 km/sec for the range of minerals going from quartz to periclase for aluminum (silicate-like) projectiles. The impact velocities, which are required to induce melting in a soil, are calculated to be in the range of 3 to 4 km/sec, provided thermal equilibrium is achieved in the shock state.

Melting method for radioactive solid wastes and device therefor

Energy Technology Data Exchange (ETDEWEB)

Komatsu, Masahiko; Abe, Takashi; Nakayama, Junpei; Kusamichi, Tatsuhiko; Sakamoto, Koichi

1998-11-17

Upon melting radioactive solid wastes mixed with radioactive metal wastes and non metal materials such as concrete by cold crucible high frequency induction heating, induction coils are wound around the outer circumference of a copper crucible having a water cooling structure to which radioactive solid wastes are charged. A heating sleeve formed by a material which generates heat by an induction heating function of graphite is disposed to the inside of the crucible at a height not in contact with molten metals in the crucible vertically movably. Radioactive solid wastes are melted collectively by the induction heat of the induction coils and thermal radiation and heat conduction of the heating sleeve heated by the induction heat. With such procedures, non metal materials such as concrete and radioactive metal wastes in a mixed state can be melt collectively continuously highly economically. (T.M.)

Thermal shock test of TiC and graphite

International Nuclear Information System (INIS)

Shirakawa, H.; Okamura, J.; Son, P.; Miyake, M.

1989-01-01

Thermal shock tests were performed by pulse electron beam heating on chemically vapor deposited coatings of TiC on Poco graphite, bulk TiC, and several kinds of isotropic graphite. The specimens were heated at various power densities (10-45 MW/m 2 ) for various pulse durations (1-2 s) to examine the dependence of thermal failures on heating conditions. The TiC coating on graphite suffered cracking, surface melting and evaporation by the thermal pulse. The surface melting limit, defined as F τ 1/2 , where F is the minimum power density that causes surface melting for a specified pulse duration τ, was approximately 48 MWs 1/2 /m 2 for the TiC coating. The combined-Carbon/Titanium ratio of the coating after electron beam heating decreased with increasing power density and pulse duration. The bulk TiC specimens were so brittle that they fractured at heat load conditions where the coating showed no damage. The graphite specimens showed sublimation as a principal damage mechanism by the thermal pulse, and the sublimation weight loss decreased with increasing the thermal conductivity of the specimen. It was confirmed that the TiC coating on graphite had favorable resistance to thermal shock as compared to the bulk TiC and that graphite with high thermal conductivity is promising material as a high heat flux component. (orig.)

Influence of gas generation on high-temperature melt/concrete interactions

International Nuclear Information System (INIS)

Powers, D.A.

1979-01-01

Accidents involving fuel melting and eventual contact between the high temperature melt and structural concrete may be hypothesized for both light water thermal reactors and liquid metal cooled breeder reactors. Though these hypothesized accidents have a quite low probability of occurring, it is necessary to investigate the probable natures of the accidents if an adequate assessment of the risks associated with the use of nuclear reactors is to be made. A brief description is given of a program addressing the nature of melt/concrete interactions which has been underway for three years at Sandia Laboratories. Emphasis in this program has been toward the behavior of prototypic melts of molten core materials with concrete representative of that found in existing or proposed reactors. The goals of the experimentation have been to identify phenomena particularly pertinent to questions of reactor safety, and phenomena particularly pertinent to questions of reactor safety, and provide quantitative data suitable for the purposes of risk assessment

Preparation and thermal properties characterization of carbonate salt/carbon nanomaterial composite phase change material

International Nuclear Information System (INIS)

Tao, Y.B.; Lin, C.H.; He, Y.L.

2015-01-01

Highlights: • Nanocomposite phase change materials were prepared and characterized. • Larger specific surface area is more efficient to enhance specific heat. • Columnar structure is more efficient to enhance thermal conductivity. • Thermal conductivity enhancement is the key. • Single walled carbon nanotube is the optimal nanomaterial additive. - Abstract: To enhance the performance of high temperature salt phase change material, four kinds of carbon nanomaterials with different microstructures were mixed into binary carbonate eutectic salts to prepare carbonate salt/nanomaterial composite phase change material. The microstructures of the nanomaterial and composite phase change material were characterized by scanning electron microscope. The thermal properties such as melting point, melting enthalpy, specific heat, thermal conductivity and total thermal energy storage capacity were characterized. The results show that the nanomaterial microstructure has great effects on composite phase change material thermal properties. The sheet structure Graphene is the best additive to enhance specific heat, which could be enhanced up to 18.57%. The single walled carbon nanotube with columnar structure is the best additive to enhance thermal conductivity, which could be enhanced up to 56.98%. Melting point increases but melting enthalpy decreases with nanomaterial specific surface area increase. Although the additives decrease the melting enthalpy of composite phase change material, they also enhance the specific heat. As a combined result, the additives have little effects on thermal energy storage capacity. So, for phase change material performance enhancement, more emphasis should be placed on thermal conductivity enhancement and single walled carbon nanotube is the optimal nanomaterial additive

Sugar Profile, Mineral Content, and Rheological and Thermal Properties of an Isomerized Sweet Potato Starch Syrup

OpenAIRE

Dominque, Brunson; Gichuhi, Peter N.; Rangari, Vijay; Bovell-Benjamin, Adelia C.

2013-01-01

Currently, corn is used to produce more than 85% of the world's high fructose syrup (HFS). There is a search for alternative HFS substrates because of increased food demand and shrinking economies, especially in the developing world. The sweet potato is a feasible, alternative raw material. This study isomerized a high glucose sweet potato starch syrup (SPSS) and determined its sugar profile, mineral content, and rheological and thermal properties. Rheological and thermal properties were meas...

Monte Carlo study of thermal flux profiles and body correction factors for body protein measurements of obese subjects

International Nuclear Information System (INIS)

McGregor, B.J.; Allen, B.J.

1991-01-01

In previous calculations for total body nitrogen measurements of children, the anterior/posterior thermal neutron flux profile with depth was found to be fairly flat after an initial rise. However, for obese adults significant variations are found in the flux profile with the central flux value being as low as 20% of the peak value. The significance of these flux variations is examined. Correction factors are calculated for the varying attenuation of the nitrogen and hydrogen photons by a range of obese bodies. The calculations included the effect of the thermal flux profile as well as that of an outer layer of low nitrogen content adipose tissue. The bodies are assumed to have a homogeneous hydrogen content. A study of four obese body models with varying sex and fat content shows that the correction factors do not vary much between males and females. This is surprising since the female models are assumed to have a surface fat layer twice as thick as for the male models. The correction factors are found to be only slightly sensitive to the thermal flux variations with depth. 5 refs., 1 tab., 4 figs

Emerging melt quality control solution technologies for aluminium melt

Directory of Open Access Journals (Sweden)

Arturo Pascual, Jr

2009-11-01

Full Text Available The newly developed “MTS 1500” Melt Treatment System is performing the specifi cally required melt treatment operations like degassing, cleaning, modification and/or grain refinement by an automated process in one step and at the same location. This linked process is saving time, energy and metal losses allowing - by automated dosage of the melt treatment agents - the production of a consistent melt quality batch after batch. By linking the MTS Metal Treatment System with sensors operating on-line in the melt, i.e., with a hydrogen sensor “Alspek H”, a fully automated control of parts of the process chain like degassing is possible. This technology does guarantee a pre-specifi ed and documented melt quality in each melt treatment batch. Furthermore, to ensure that castings are consistent and predictable there is a growing realization that critical parameters such as metal cleanliness must be measured prior to casting. There exists accepted methods for measuring the cleanliness of an aluminum melt but these can be both slow and costly. A simple, rapid and meaningful method of measuring and bench marking the cleanliness of an aluminum melt has been developed to offer the foundry a practical method of measuring melt cleanliness. This paper shows the structure and performance of the integrated MTS melt treatment process and documents achieved melt quality standards after degassing, cleaning, modifi cation and grain refi nement operations under real foundry conditions. It also provides an insight on a melt cleanliness measuring device “Alspek MQ” to provide foundry men better tools in meeting the increasing quality and tighter specifi cation demand from the industry.

Significance of Thermal Fluvial Incision and Bedrock Transfer due to Ice Advection on Greenland Ice Sheet Topography

Science.gov (United States)

Crozier, J. A.; Karlstrom, L.; Yang, K.

2017-12-01

Ice sheet surface topography reflects a complicated combination of processes that act directly upon the surface and that are products of ice advection. Using recently-available high resolution ice velocity, imagery, ice surface elevation, and bedrock elevation data sets, we seek to determine the domain of significance of two important processes - thermal fluvial incision and transfer of bedrock topography through the ice sheet - on controlling surface topography in the ablation zone. Evaluating such controls is important for understanding how melting of the GIS surface during the melt season may be directly imprinted in topography through supraglacial drainage networks, and indirectly imprinted through its contribution to basal sliding that affects bedrock transfer. We use methods developed by (Karlstrom and Yang, 2016) to identify supraglacial stream networks on the GIS, and use high resolution surface digital elevation models as well as gridded ice velocity and melt rate models to quantify surface processes. We implement a numerically efficient Fourier domain bedrock transfer function (Gudmundsson, 2003) to predict surface topography due to ice advection over bedrock topography obtained from radar. Despite a number of simplifying assumptions, the bedrock transfer function predicts the observed ice sheet surface in most regions of the GIS with ˜90% accuracy, regardless of the presence or absence of supraglacial drainage networks. This supports the hypothesis that bedrock is the most significant driver of ice surface topography on wavelengths similar to ice thickness. Ice surface topographic asymmetry on the GIS is common, with slopes in the direction of ice flow steeper than those faced opposite to ice flow, consistent with bedrock transfer theory. At smaller wavelengths, topography consistent with fluvial erosion by surface hydrologic features is evident. We quantify the effect of ice advection versus fluvial thermal erosion on supraglacial longitudinal stream

Metamorphism and partial melting of ordinary chondrites: Calculated phase equilibria

Science.gov (United States)

Johnson, T. E.; Benedix, G. K.; Bland, P. A.

2016-01-01

Constraining the metamorphic pressures (P) and temperatures (T) recorded by meteorites is key to understanding the size and thermal history of their asteroid parent bodies. New thermodynamic models calibrated to very low P for minerals and melt in terrestrial mantle peridotite permit quantitative investigation of high-T metamorphism in ordinary chondrites using phase equilibria modelling. Isochemical P-T phase diagrams based on the average composition of H, L and LL chondrite falls and contoured for the composition and abundance of olivine, ortho- and clinopyroxene, plagioclase and chromite provide a good match with values measured in so-called equilibrated (petrologic type 4-6) samples. Some compositional variables, in particular Al in orthopyroxene and Na in clinopyroxene, exhibit a strong pressure dependence when considered over a range of several kilobars, providing a means of recognising meteorites derived from the cores of asteroids with radii of several hundred kilometres, if such bodies existed at that time. At the low pressures (recorders of peak conditions. The intersection of isopleths of these variables may allow pressures to be quantified, even at low P, permitting constraints on the minimum size of parent asteroid bodies. The phase diagrams predict the onset of partial melting at 1050-1100 °C by incongruent reactions consuming plagioclase, clinopyroxene and orthopyroxene, whose compositions change abruptly as melting proceeds. These predictions match natural observations well and support the view that type 7 chondrites represent a suprasolidus continuation of the established petrologic types at the extremes of thermal metamorphism. The results suggest phase equilibria modelling has potential as a powerful quantitative tool in investigating, for example, progressive oxidation during metamorphism, the degree of melting and melt loss or accumulation required to produce the spectrum of differentiated meteorites, and whether the onion shell or rubble pile

A DNA Melting Exercise for a Large Laboratory Class

Science.gov (United States)

Levine, Lauren A.; Junker, Matthew; Stark, Myranda; Greenleaf, Dustin

2015-01-01

A simple and economical experimental setup is described that enables multiple individuals or groups within a laboratory class to measure the thermal melting of double stranded DNA simultaneously. The setup utilizes a basic spectrophotometer capable of measuring absorbance at 260 nm, UV plastic cuvettes, and a stirring hot plate. Students measure…

A volatile-rich Earth's core inferred from melting temperature of core materials

Science.gov (United States)

Morard, G.; Andrault, D.; Antonangeli, D.; Nakajima, Y.; Auzende, A. L.; Boulard, E.; Clark, A. N.; Lord, O. T.; Cervera, S.; Siebert, J.; Garbarino, G.; Svitlyk, V.; Mezouar, M.

2016-12-01

Planetary cores are mainly constituted of iron and nickel, alloyed with lighter elements (Si, O, C, S or H). Understanding how these elements affect the physical and chemical properties of solid and liquid iron provides stringent constraints on the composition of the Earth's core. In particular, melting curves of iron alloys are key parameter to establish the temperature profile in the Earth's core, and to asses the potential occurrence of partial melting at the Core-Mantle Boundary. Core formation models based on metal-silicate equilibration suggest that Si and O are the major light element components1-4, while the abundance of other elements such as S, C and H is constrained by arguments based on their volatility during planetary accretion5,6. Each compositional model implies a specific thermal state for the core, due to the different effect that light elements have on the melting behaviour of Fe. We recently measured melting temperatures in Fe-C and Fe-O systems at high pressures, which complete the data sets available both for pure Fe7 and other binary alloys8. Compositional models with an O- and Si-rich outer core are suggested to be compatible with seismological constraints on density and sound velocity9. However, their crystallization temperatures of 3650-4050 K at the CMB pressure of 136 GPa are very close to, if not higher than the melting temperature of the silicate mantle and yet mantle melting above the CMB is not a ubiquitous feature. This observation requires significant amounts of volatile elements (S, C or H) in the outer core to further reduce the crystallisation temperature of the core alloy below that of the lower mantle. References 1. Wood, B. J., et al Nature 441, 825-833 (2006). 2. Siebert, J., et al Science 339, 1194-7 (2013). 3. Corgne, A., et al Earth Planet. Sc. Lett. 288, 108-114 (2009). 4. Fischer, R. a. et al. Geochim. Cosmochim. Acta 167, 177-194 (2015). 5. Dreibus, G. & Palme, H. Geochim. Cosmochim. Acta 60, 1125-1130 (1995). 6. Mc

Review of melting and evaporation of fusion-reactor first walls

International Nuclear Information System (INIS)

Fillo, J.A.; Makowitz, H.

1981-01-01

The most severe thermal loading on the first wall will occur when the plasma becomes unstable resulting in a hard plasma disruption or at the end of a discharge when the plasma is dumped on the wall in a very short period of time. Hard plasma disruptions are of particular concern in future fusion reactors where the thermal energy of the plasma may reach values on the order of 300 MJ. Sufficiently high heating rates can occur to melt the first wall surface, and the temperature can increase resulting in vaporization. Thermal models are reviewed which treat these problems

Microstructure and properties of high chrome steel roller after laser surface melting

Energy Technology Data Exchange (ETDEWEB)

Li Meiyan, E-mail: lmy_102411@163.com [College of Electromechanical Engineering, China University of Petroleum, 271 Bei' er Road, Dongying 257061 (China); Wang Yong; Han Bin; Zhao Weimin; Han Tao [College of Electromechanical Engineering, China University of Petroleum, 271 Bei' er Road, Dongying 257061 (China)

2009-06-15

Laser surface melting of high chrome steels was achieved by a 5 kW continuous wave CO{sub 2} laser. The microstructure of the laser surface-melted steels was investigated by scanning electron microscopy, transmission electron microscopy and X-ray diffractometry, and the hardness profiles were determined by a Vickers hardness tester. The corrosion behavior in 3.5% NaCl solution was studied by electrochemical corrosion equipment. The large carbides of high chrome steels are completely dissolved and ultrafine dendrites of austenite with submicroscopic M{sub 23}C{sub 6} carbides precipitation are formed in the melted zone. The austenite in the melted zone has a high tempering stability. The corrosion resistance of the laser surface-melted steels is significantly improved due to the dissolution of carbides and the increase of the alloying elements in the solid solution as well as the large amount of austenite.

Simplified methods to the complete thermal and mechanical behavior of a pressure vessel during a severe accident

International Nuclear Information System (INIS)

Dupas, P.; Schneiter, J.R.

1996-01-01

EDF has developed a software package of simplified methods (proprietary ones or from literature) in order to study the thermal and mechanical behavior of a PWR pressure vessel during a severe accident involving a corium localization in the vessel lower head. Using a part of this package, the authors can evaluate for instance successively: the heat flux at the inner surface of the vessel (conductive or convective pool of corium); the thermal exchange coefficient between the vessel and the outside (dry pit or flooded pit, watertight thermal insulation or not); the complete thermal evolution of the vessel (temperature profile, melting); the possible global plastic failure of the vessel; the creep behavior in the thickness of the vessel. These simplified methods are a cost effective alternative to finite element calculations which are yet used to validate the previous methods, waiting for experimental results to come

Radiation Heat Transfer Modeling Improved for Phase-Change, Thermal Energy Storage Systems

Science.gov (United States)

Kerslake, Thomas W.; Jacqmin, David A.

1998-01-01

Spacecraft solar dynamic power systems typically use high-temperature phase-change materials to efficiently store thermal energy for heat engine operation in orbital eclipse periods. Lithium fluoride salts are particularly well suited for this application because of their high heat of fusion, long-term stability, and appropriate melting point. Considerable attention has been focused on the development of thermal energy storage (TES) canisters that employ either pure lithium fluoride (LiF), with a melting point of 1121 K, or eutectic composition lithium-fluoride/calcium-difluoride (LiF-20CaF2), with a 1040 K melting point, as the phase-change material. Primary goals of TES canister development include maximizing the phase-change material melt fraction, minimizing the canister mass per unit of energy storage, and maximizing the phase-change material thermal charge/discharge rates within the limits posed by the container structure.

Preparation of melt-spun antimicrobially modified LDH/polyolefin nanocomposite fibers.

Science.gov (United States)

Kutlu, Burak; Schröttner, Percy; Leuteritz, Andreas; Boldt, Regine; Jacobs, Enno; Heinrich, Gert

2014-08-01

Layered double hydroxide (LDH) was synthesized and organically modified with camphorsulfonic acid (CSA) and ciprofloxacin. The thermal stability of CSA was improved remarkably under LDH shielding. A minimal inhibitory concentration of free CSA against tested bacteria was determined in order to define the essential quantity in LDH modification. The modified LDHs were melt-compounded with high density polyethylene and the prepared nanocomposites were further melt-spun using a piston-type spinning device. The melt-spun fibers were tested for their antimicrobial activity against Escherichia coli, Proteus vulgaris, Pseudomonas aeruginosa, Enterobacter cloacae, Staphylococcus aureus, Staphylococcus epidermidis, and Streptococcus pyogenes. CSA integrated fibers show susceptibility against Gram-positive bacteria and ciprofloxacin integrated fibers showed activity against both Gram-positive and Gram-negative bacteria. Copyright © 2014 Elsevier B.V. All rights reserved.

Modeling of melt retention in EU-APR1400 ex-vessel core catcher

Energy Technology Data Exchange (ETDEWEB)

Granovsky, V. S.; Sulatsky, A. A.; Khabensky, V. B.; Sulatskaya, M. B. [Alexandrov Research Inst. of Technology NITI, Sosnovy Bor (Russian Federation); Gusarov, V. V.; Almyashev, V. I.; Komlev, A. A. [Saint Petersburg State Technological Univ. SPbSTU, St.Petersburg (Russian Federation); Bechta, S. [KTH, Stockholm (Sweden); Kim, Y. S. [KHNP, 1312 Gil 70, Yuseongdaero, Yuseong-gu, Daejeon (Korea, Republic of); Park, R. J.; Kim, H. Y.; Song, J. H. [KAERI, 989 Gil 111, Daedeokdaero, Yuseong-gu, Daejeon (Korea, Republic of)

2012-07-01

A core catcher is adopted in the EU-APR1400 reactor design for management and mitigation of severe accidents with reactor core melting. The core catcher concept incorporates a number of engineering solutions used in the catcher designs of European EPR and Russian WER-1000 reactors, such as thin-layer corium spreading for better cooling, retention of the melt in a water-cooled steel vessel, and use of sacrificial material (SM) to control the melt properties. SM is one of the key elements of the catcher design and its performance is critical for melt retention efficiency. This SM consists of oxide components, but the core catcher also includes sacrificial steel which reacts with the metal melt of the molten corium to reduce its temperature. The paper describes the required properties of SM. The melt retention capability of the core catcher can be confirmed by modeling the heat fluxes to the catcher vessel to show that it will not fail. The fulfillment of this requirement is demonstrated on the example of LBLOCA severe accident. Thermal and physicochemical interactions between the oxide and metal melts, interactions of the melts with SM, sacrificial steel and vessel, core catcher external cooling by water and release of non-condensable gases are modeled. (authors)

Erythritol: crystal growth from the melt.

Science.gov (United States)

Lopes Jesus, A J; Nunes, Sandra C C; Ramos Silva, M; Matos Beja, A; Redinha, J S

2010-03-30

The structural changes occurring on erythritol as it is cooled from the melt to low temperature, and then heated up to the melting point have been investigated by differential scanning calorimetry (DSC), polarized light thermal microscopy (PLTM), X-ray powder diffraction (PXRD) and Fourier transform infrared spectroscopy (FTIR). By DSC, it was possible to set up the conditions to obtain an amorphous solid, a crystalline solid, or a mixture of both materials in different proportions. Two crystalline forms have been identified: a stable and a metastable one with melting points of 117 and 104 degrees C, respectively. The fusion curve decomposition of the stable form revealed the existence of three conformational structures. The main paths of the crystallization from the melt were followed by PLTM. The texture and colour changes allowed the characterization of the different phases and transitions in which they are involved on cooling as well as on heating processes. The type of crystallization front and its velocity were also followed by microscopic observation. These observations, together with the data provided by PXRD, allowed elucidating the transition of the metastable form into the stable one. The structural changes occurring upon the cooling and subsequent heating processes, namely those arising from intermolecular hydrogen bonds, were also accompanied by infrared spectroscopy. Particular attention was given to the spectral changes occurring in the OH stretching region. Copyright (c) 2009 Elsevier B.V. All rights reserved.

Coaxial monitoring of temperature field in selective pulsed laser melting

Science.gov (United States)

Liu, Che; Chen, Zhongyun; Cao, Hongzhong; Zhou, Jianhong

2017-10-01

Selective Laser Melting is a rapid manufacturing technology which produces complex parts layer by layer. The presence of thermal stress and thermal strain in the forming process often leads to defects in the formed parts. In order to detect fabricate errors and avoid failure which caused by thermal gradient in time. An infrared thermal imager and a high speed CCD camera were applied to build a coaxial optical system for real-time monitoring the temperature distribution and changing trend of laser affected zone in SLM forming process. Molten tracks were fabricated by SLM under different laser parameters such as frequency, pulse width. And the relationship between the laser parameters and the temperature distribution were all obtained and analyzed.

The Melting Point of Palladium Using Miniature Fixed Points of Different Ceramic Materials: Part II—Analysis of Melting Curves and Long-Term Investigation

Science.gov (United States)

Edler, F.; Huang, K.

2016-12-01

Fifteen miniature fixed-point cells made of three different ceramic crucible materials (Al2O3, ZrO2, and Al2O3(86 %)+ZrO2(14 %)) were filled with pure palladium and used to calibrate type B thermocouples (Pt30 %Rh/Pt6 %Rh). A critical point by using miniature fixed points with small amounts of fixed-point material is the analysis of the melting curves, which are characterized by significant slopes during the melting process compared to flat melting plateaus obtainable using conventional fixed-point cells. The method of the extrapolated starting point temperature using straight line approximation of the melting plateau was applied to analyze the melting curves. This method allowed an unambiguous determination of an electromotive force (emf) assignable as melting temperature. The strict consideration of two constraints resulted in a unique, repeatable and objective method to determine the emf at the melting temperature within an uncertainty of about 0.1 μ V. The lifetime and long-term stability of the miniature fixed points was investigated by performing more than 100 melt/freeze cycles for each crucible of the different ceramic materials. No failure of the crucibles occurred indicating an excellent mechanical stability of the investigated miniature cells. The consequent limitation of heating rates to values below {± }3.5 K min^{-1} above 1100° C and the carefully and completely filled crucibles (the liquid palladium occupies the whole volume of the crucible) are the reasons for successfully preventing the crucibles from breaking. The thermal stability of the melting temperature of palladium was excellent when using the crucibles made of Al2O3(86 %)+ZrO2(14 %) and ZrO2. Emf drifts over the total duration of the long-term investigation were below a temperature equivalent of about 0.1 K-0.2 K.

A coupled melt-freeze temperature index approach in a one-layer model to predict bulk volumetric liquid water content dynamics in snow

Science.gov (United States)

Avanzi, Francesco; Yamaguchi, Satoru; Hirashima, Hiroyuki; De Michele, Carlo

2016-04-01

Liquid water in snow rules runoff dynamics and wet snow avalanches release. Moreover, it affects snow viscosity and snow albedo. As a result, measuring and modeling liquid water dynamics in snow have important implications for many scientific applications. However, measurements are usually challenging, while modeling is difficult due to an overlap of mechanical, thermal and hydraulic processes. Here, we evaluate the use of a simple one-layer one-dimensional model to predict hourly time-series of bulk volumetric liquid water content in seasonal snow. The model considers both a simple temperature-index approach (melt only) and a coupled melt-freeze temperature-index approach that is able to reconstruct melt-freeze dynamics. Performance of this approach is evaluated at three sites in Japan. These sites (Nagaoka, Shinjo and Sapporo) present multi-year time-series of snow and meteorological data, vertical profiles of snow physical properties and snow melt lysimeters data. These data-sets are an interesting opportunity to test this application in different climatic conditions, as sites span a wide latitudinal range and are subjected to different snow conditions during the season. When melt-freeze dynamics are included in the model, results show that median absolute differences between observations and predictions of bulk volumetric liquid water content are consistently lower than 1 vol%. Moreover, the model is able to predict an observed dry condition of the snowpack in 80% of observed cases at a non-calibration site, where parameters from calibration sites are transferred. Overall, the analysis show that a coupled melt-freeze temperature-index approach may be a valid solution to predict average wetness conditions of a snow cover at local scale.

Research opportunities in salt hydrates for thermal energy storage

Science.gov (United States)

Braunstein, J.

1983-11-01

The state of the art of salt hydrates as phase change materials for low temperature thermal energy storage is reviewed. Phase equilibria, nucleation behavior and melting kinetics of the commonly used hydrate are summarized. The development of efficient, reliable inexpensive systems based on phase change materials, especially salt hydrates for the storage (and retrieval) of thermal energy for residential heating is outlined. The use of phase change material thermal energy storage systems is not yet widespread. Additional basic research is needed in the areas of crystallization and melting kinetics, prediction of phase behavior in ternary systems, thermal diffusion in salt hydrate systems, and in the physical properties pertinent to nonequilibrium and equilibrium transformations in these systems.

Electrical conductivity and viscosity of borosilicate glasses and melts

DEFF Research Database (Denmark)

Ehrt, Doris; Keding, Ralf

2009-01-01

, 0 to 62·5 mol% B2O3, and 25 to 85 mol% SiO2. The glass samples were characterised by different methods. Refractive indices, density and thermal expansion were measured. Phase separation effects were investigated by electron microscopy. The electrical conductivity of glasses and melts were determined......Simple sodium borosilicate and silicate glasses were melted on a very large scale (35 l Pt crucible) to prepare model glasses of optical quality in order to investigate various properties depending on their structure. The composition of the glass samples varied in a wide range: 3 to 33·3 mol% Na2O...... by impedance measurements in a wide temperature range (250 to 1450°C). The activation energies were calculated by Arrhenius plots in various temperature regions: below the glass transition temperature, Tg, above the melting point, Tl, and between Tg and Tl. Viscosity measurements were carried out...

An equation of state for high pressure-temperature liquids (RTpress) with application to MgSiO3 melt

Science.gov (United States)

Wolf, Aaron S.; Bower, Dan J.

2018-05-01

The thermophysical properties of molten silicates at extreme conditions are crucial for understanding the early evolution of Earth and other massive rocky planets, which is marked by giant impacts capable of producing deep magma oceans. Cooling and crystallization of molten mantles are sensitive to the densities and adiabatic profiles of high-pressure molten silicates, demanding accurate Equation of State (EOS) models to predict the early evolution of planetary interiors. Unfortunately, EOS modeling for liquids at high P-T conditions is difficult due to constantly evolving liquid structure. The Rosenfeld-Tarazona (RT) model provides a physically sensible and accurate description of liquids but is limited to constant volume heating paths (Rosenfeld and Tarazona, 1998). We develop a high P-T EOS for liquids, called RTpress, which uses a generalized Rosenfeld-Tarazona model as a thermal perturbation to isothermal and adiabatic reference compression curves. This approach provides a thermodynamically consistent EOS which remains accurate over a large P-T range and depends on a limited number of physically meaningful parameters that can be determined empirically from either simulated or experimental datasets. As a first application, we model MgSiO3 melt representing a simplified rocky mantle chemistry. The model parameters are fitted to the MD simulations of both Spera et al. (2011) and de Koker and Stixrude (2009), recovering pressures, volumes, and internal energies to within 0.6 GPa, 0.1 Å3 , and 6 meV per atom on average (for the higher resolution data set), as well as accurately predicting liquid densities and temperatures from shock-wave experiments on MgSiO3 glass. The fitted EOS is used to determine adiabatic thermal profiles, revealing the approximate thermal structure of a fully molten magma ocean like that of the early Earth. These adiabats, which are in strong agreement for both fitted models, are shown to be sufficiently steep to produce either a center

Modelling and parameterizing the influence of tides on ice-shelf melt rates

Science.gov (United States)

Jourdain, N.; Molines, J. M.; Le Sommer, J.; Mathiot, P.; de Lavergne, C.; Gurvan, M.; Durand, G.

2017-12-01

Significant Antarctic ice sheet thinning is observed in several sectors of Antarctica, in particular in the Amundsen Sea sector, where warm circumpolar deep waters affect basal melting. The later has the potential to trigger marine ice sheet instabilities, with an associated potential for rapid sea level rise. It is therefore crucial to simulate and understand the processes associated with ice-shelf melt rates. In particular, the absence of tides representation in ocean models remains a caveat of numerous ocean hindcasts and climate projections. In the Amundsen Sea, tides are relatively weak and the melt-induced circulation is stronger than the tidal circulation. Using a regional 1/12° ocean model of the Amundsen Sea, we nonetheless find that tides can increase melt rates by up to 36% in some ice-shelf cavities. Among the processes that can possibly affect melt rates, the most important is an increased exchange at the ice/ocean interface resulting from the presence of strong tidal currents along the ice drafts. Approximately a third of this effect is compensated by a decrease in thermal forcing along the ice draft, which is related to an enhanced vertical mixing in the ocean interior in presence of tides. Parameterizing the effect of tides is an alternative to the representation of explicit tides in an ocean model, and has the advantage not to require any filtering of ocean model outputs. We therefore explore different ways to parameterize the effects of tides on ice shelf melt. First, we compare several methods to impose tidal velocities along the ice draft. We show that getting a realistic spatial distribution of tidal velocities in important, and can be deduced from the barotropic velocities of a tide model. Then, we explore several aspects of parameterized tidal mixing to reproduce the tide-induced decrease in thermal forcing along the ice drafts.

Volatile diffusion in silicate melts and its effects on melt inclusions

Directory of Open Access Journals (Sweden)

P. Scarlato

2005-06-01

Full Text Available A compendium of diffusion measurements and their Arrhenius equations for water, carbon dioxide, sulfur, fluorine, and chlorine in silicate melts similar in composition to natural igneous rocks is presented. Water diffusion in silicic melts is well studied and understood, however little data exists for melts of intermediate to basic compositions. The data demonstrate that both the water concentration and the anhydrous melt composition affect the diffusion coefficient of water. Carbon dioxide diffusion appears only weakly dependent, at most, on the volatilefree melt composition and no effect of carbon dioxide concentration has been observed, although few experiments have been performed. Based upon one study, the addition of water to rhyolitic melts increases carbon dioxide diffusion by orders of magnitude to values similar to that of 6 wt% water. Sulfur diffusion in intermediate to silicic melts depends upon the anhydrous melt composition and the water concentration. In water-bearing silicic melts sulfur diffuses 2 to 3 orders of magnitude slower than water. Chlorine diffusion is affected by both water concentration and anhydrous melt composition; its values are typically between those of water and sulfur. Information on fluorine diffusion is rare, but the volatile-free melt composition exerts a strong control on its diffusion. At the present time the diffusion of water, carbon dioxide, sulfur and chlorine can be estimated in silicic melts at magmatic temperatures. The diffusion of water and carbon dioxide in basic to intermediate melts is only known at a limited set of temperatures and compositions. The diffusion data for rhyolitic melts at 800°C together with a standard model for the enrichment of incompatible elements in front of growing crystals demonstrate that rapid crystal growth, greater than 10-10 ms-1, can significantly increase the volatile concentrations at the crystal-melt interface and that any of that melt trapped

Numerical Model based Reliability Estimation of Selective Laser Melting Process

DEFF Research Database (Denmark)

Mohanty, Sankhya; Hattel, Jesper Henri

2014-01-01

Selective laser melting is developing into a standard manufacturing technology with applications in various sectors. However, the process is still far from being at par with conventional processes such as welding and casting, the primary reason of which is the unreliability of the process. While...... of the selective laser melting process. A validated 3D finite-volume alternating-direction-implicit numerical technique is used to model the selective laser melting process, and is calibrated against results from single track formation experiments. Correlation coefficients are determined for process input...... parameters such as laser power, speed, beam profile, etc. Subsequently, uncertainties in the processing parameters are utilized to predict a range for the various outputs, using a Monte Carlo method based uncertainty analysis methodology, and the reliability of the process is established....

Controlled localised melting in silicon by high dose germanium implantation and flash lamp annealing

International Nuclear Information System (INIS)

Voelskow, Matthias; Skorupa, Wolfgang; Pezoldt, Joerg; Kups, Thomas

2009-01-01

High intensity light pulse irradiation of monocrystalline silicon wafers is usually accompanied by inhomogeneous surface melting. The aim of the present work is to induce homogeneous buried melting in silicon by germanium implantation and subsequent flash lamp annealing. For this purpose high dose, high energy germanium implantation has been employed to lower the melting temperature of silicon in a predetermined depth region. Subsequent flash lamp irradiation at high energy densities leads to local melting of the germanium rich buried layer, whereby the thickness of the molten layer depends on the irradiation energy density. During the cooling down epitaxial crystallization takes place resulting in a largely defect-free layer. The combination of buried melting and dopant segregation has the potential to produce unusually buried doping profiles or to create strained silicon structures.

One day-old chicks transport: Assessment of thermal profile in a tropical region

Directory of Open Access Journals (Sweden)

Aérica C. Nazareno

2015-07-01

Full Text Available The aim of this study was to assess the thermal profile of truck with different levels of box placement during one day-old chicks transport. An experiment was conducted through monitoring of 11 transport loads. A acclimatized truck was used in this research, with maximum capacity of 630 one day-old chicks boxes, totalizing 63,000 animals. The assessment of thermal environment was performed in 5 min intervals, through the following variables: temperature, relative humidity and specific enthalpy. The treatments were registered at two levels of the load (first rack and floor where 17 data loggers were distributed throughout the truck. The experiment used a completely randomized design and geostatistics was used for spatial dependency and Kriging interpolation. The microclimatic conditions of the truck were not as per recommended values, which confirm a heterogeneous distribution of heat and moisture in environment. Regarding the box positioning, the mean values of thermal variables associated with thermal comfort of one day-old chicks was found in the floor area. The most stressful environment for birds inside the truck was located in front and at the center of the truck.

Comparative expression profile of NOD1/2 and certain acute inflammatory cytokines in thermal-stressed cell culture model of native and crossbred cattle

Science.gov (United States)

Bhanuprakash, V.; Singh, Umesh; Sengar, Gyanendra Singh; Raja, T. V.; Sajjanar, Basavraj; Alex, Rani; Kumar, Sushil; Alyethodi, R. R.; Kumar, Ashish; Sharma, Ankur; Kumar, Suresh; Bhusan, Bharat; Deb, Rajib

2017-05-01

Thermotolerance depends mainly on the health and immune status of the animals. The variation in the immune status of the animals may alter the level of tolerance of animals exposed to heat or cold stress. The present study was conducted to investigate the expression profile of two important nucleotide binding and oligomerization domain receptors (NLRs) (NOD1 and NOD2) and their central signalling molecule RIP2 gene during in vitro thermal-stressed bovine peripheral blood mononuclear cells (PBMCs) of native (Sahiwal) and crossbred (Sahiwal X HF) cattle. We also examined the differential expression profile of certain acute inflammatory cytokines in in vitro thermal-stressed PBMC culture among native and its crossbred counterparts. Results revealed that the expression profile of NOD1/2 positively correlates with the thermal stress, signalling molecule and cytokines. Present findings also highlighted that the expression patterns during thermal stress were comparatively superior among indigenous compared to crossbred cattle which may add references regarding the better immune adaptability of Zebu cattle.

A Eutectic Melting Study of Double Wall Cladding Tubes of FeCrAl and Zircaloy-4

Energy Technology Data Exchange (ETDEWEB)

Lim, Woojin; Son, Seongmin; Lee, You Ho; Lee, Jeong Ik; Ryu, Ho Jin [Korea Advanced Institute of Science and Technology, Daejeon (Korea, Republic of); Jeong, Eun [Kyunghee University, Yongin (Korea, Republic of)

2015-10-15

The eutectic melting behavior of FeCrAl/Zircaloy-4 double wall cladding tubes was investigated by annealing at various temperatures ranging from 900 .deg. C to 1300 .deg. C. It was found that significant eutectic melting occurred after annealing at temperatures equal to or higher than 1150 .deg. C. It means that an additional diffusion barrier layer is necessary to limit the eutectic melting between FeCrAl and Zircaloy-4 alloy cladding tubes. Coating of FeCrAl layers on the Zr alloy cladding tube is being investigated for the development of accident tolerant fuel by exploiting of both the oxidation resistance of FeCrAl alloys and the neutronic advantages of Zr alloys. Coating of FeCrAl alloys on Zr alloy cladding tubes can be performed by various techniques including thermal spray, laser cladding, and co-extrusion. Son et al. also reported the fabrication of FeCrAl/Zr ally double wall cladding by the shrink fit method. For the double layered cladding tubes, the thermal expansion mismatch between the dissimilar materials, severe deformation or mechanical failure due to the evolution of thermal stresses can occur when there is a thermal cycling. In addition to the thermal stress problems, chemical compatibilities between the two different alloys should be investigated in order to check the stability and thermal margin of the double wall cladding at a high temperature. Generally, it is considered that Zr alloy cladding will maintain its mechanical integrity up to 1204 .deg. C (2200 .deg. F) to satisfy the acceptance criteria for emergency core cooling systems.

Double melting in polytetrafluoroethylene γ-irradiated above its melting point

International Nuclear Information System (INIS)

Serov, S.A.; Khatipov, S.A.; Sadovskaya, N.V.; Tereshenkov, A.V.; Chukov, N.A.

2012-01-01

Highlights: ► PTFE irradiation leads to formation of double melting peaks in DSC curves. ► This is connected to dual crystalline morphology typical for PTFE. ► Two crystalline types exist in the PTFE irradiated in the melt. - Abstract: PTFE irradiation above its melting point leads to formation of double melting and crystallization peaks in DSC curves. Splitting of melting peaks is connected to dual crystalline morphology typical for PTFE irradiated in the melt. According to electron microscopy, two crystalline types with different size and packing density exist in the irradiated PTFE.

Melting and solidification characteristics of a mixture of two types of latent heat storage material in a vessel

Science.gov (United States)

Yu, JikSu; Horibe, Akihiko; Haruki, Naoto; Machida, Akito; Kato, Masashi

2016-11-01

In this study, we investigated the fundamental melting and solidification characteristics of mannitol, erythritol, and their mixture (70 % by mass mannitol: 30 % by mass erythritol) as potential phase-change materials (PCMs) for latent heat thermal energy storage systems, specifically those pertaining to industrial waste heat, having temperatures in the range of 100-250 °C. The melting point of erythritol and mannitol, the melting peak temperature of their mixture, and latent heat were measured using differential scanning calorimetry. The thermal performance of the mannitol mixture was determined during melting and solidification processes, using a heat storage vessel with a pipe heat exchanger. Our results indicated phase-change (fusion) temperatures of 160 °C for mannitol and 113 and 150 °C for the mannitol mixture. Nondimensional correlation equations of the average heat transfer during the solidification process, as well as the temperature and velocity efficiencies of flowing silicon oil in the pipe and the phase-change material (PCM), were derived using several nondimensional parameters.

Onset and end of the summer melt season over sea ice: thermal structure and surface energy perspective from SHEBA

Energy Technology Data Exchange (ETDEWEB)

Persson, P.O.G. [University of Colorado, Cooperative Institute for Research in Environmental Sciences (CIRES), Boulder, CO (United States); National Oceanic and Atmospheric Administration/Earth Systems Research Laboratory, Physical Sciences Division (NOAA/ESRL/PSD), Boulder, CO (United States)

2012-09-15

Various measurements from the Surface Heat Flux of the Arctic Ocean (SHEBA) experiment have been combined to study structures and processes producing the onset and end of summer melt over Arctic sea ice. The analysis links the surface energy budget to free-troposphere synoptic variables, clouds, precipitation, and in-ice temperatures. The key results are (1) SHEBA melt-season transitions are associated with atmospheric synoptic events (2) onset of melt clearly occurs on May 28, while the end of melt is produced by a sequence of three atmospheric storm events over a 28-day period producing step-like reductions in the net surface energy flux. The last one occurs on August 22.; (3) melt onset is primarily due to large increases in the downwelling longwave radiation and modest decreases in the surface albedo; (4) decreases in the downwelling longwave radiation occur for all end-of-melt transition steps, while increases in surface albedo occur for the first two; (5) decreases in downwelling shortwave radiation contribute only to the first end-of-melt transition step; (6) springtime free-tropospheric warming preconditions the atmosphere-ice system for the subsequent melt onset; and (7) melt-season transitions also mark transitions in system responses to radiative energy flux changes because of invariant melt-season surface temperatures. The extensive SHEBA observations enable an understanding of the complex processes not available from other field program data. The analysis provides a basis for future testing of the generality of the results, and contributes to better physical understanding of multi-year analyses of melt-season trends from less extensive data sets. (orig.)

An Experimental Study on the Thermal Performance of Phase-Change Material and Wood-Plastic Composites for Building Roofs

Directory of Open Access Journals (Sweden)

Min Hee Chung

2017-02-01

Full Text Available We assessed the usefulness of phase-change material (PCM-based thermal plates fabricated from wood-plastic composites (WPCs in mitigating the urban heat island effect. The thermal performance of plates containing PCMs with two different melting temperatures and with two different albedo levels was evaluated. The results showed that the PCM with a melting temperature of 44 °C maintained lower surface and inner temperatures than the PCM with a melting temperature of 25 °C. Moreover, a higher surface albedo resulted in a lower surface temperature. However, the thermal performance of PCMs with different melting temperatures but the same surface albedo did not differ. Using PCM-based materials in roof finishing materials can reduce surface temperatures and improve thermal comfort.

Reducing residual stresses and deformations in selective laser melting through multi-level multi-scale optimization of cellular scanning strategy

DEFF Research Database (Denmark)

Mohanty, Sankhya; Hattel, Jesper Henri

2016-01-01

. A multilevel optimization strategy is adopted using a customized genetic algorithm developed for optimizing cellular scanning strategy for selective laser melting, with an objective of reducing residual stresses and deformations. The resulting thermo-mechanically optimized cellular scanning strategies......, a calibrated, fast, multiscale thermal model coupled with a 3D finite element mechanical model is used to simulate residual stress formation and deformations during selective laser melting. The resulting reduction in thermal model computation time allows evolutionary algorithm-based optimization of the process...

A statistical approach for predicting thermal diffusivity profiles in fusion plasmas as a transport model

International Nuclear Information System (INIS)

Yokoyama, Masayuki

2014-01-01

A statistical approach is proposed to predict thermal diffusivity profiles as a transport “model” in fusion plasmas. It can provide regression expressions for the ion and electron heat diffusivities (χ i and χ e ), separately, to construct their radial profiles. An approach that this letter is proposing outstrips the conventional scaling laws for the global confinement time (τ E ) since it also deals with profiles (temperature, density, heating depositions etc.). This approach has become possible with the analysis database accumulated by the extensive application of the integrated transport analysis suite to experiment data. In this letter, TASK3D-a analysis database for high-ion-temperature (high-T i ) plasmas in the LHD (Large Helical Device) is used as an example to describe an approach. (author)

Solvent-free preparation of polylactic acid fibers by melt electrospinning using umbrella-like spray head and alleviation of problematic thermal degradation

Directory of Open Access Journals (Sweden)

Liu Yong

2012-01-01

Full Text Available Melt electrospinning is an even simpler and safer method compared with the solution electrospinning in the production of ultra-fine fibers. Polylactic acid (PLA is a biodegradable and resorbable aliphatic ester that has received significant attention in recent years. PLA is easily degradable at high temperature in the process of melt electrospinning. High efficient fibers were made using our designed umbrella-like spray head spinning facility in this work. To find how to alleviate the problematic degradation and what factors could be relevant to degradation, temperature, relative molecular mass, Differential Scanning Calorimeter and X-ray Diffraction patterns before and after spinning were investigated and compared with each other. Results showed that fibers were facile shorten and fractured when spun at 245°C while the relative molecular mass of PLA fibers decreased markedly as compared with that spun at 210°C. To hinder the degradation, couple of experimental efforts were implemented with adding antioxidants, raising spinning voltage, lowering temperature, and reducing residence time. After such efforts, it was observed that the relative molecular mass of the PLA fibers was higher than those without inputting any efforts. The effect of antioxidant 1010 was found the most promising on the alleviation of PLA problematic thermal degradation.

A 3D Lumped Thermal Network Model for Long-term Load Profiles Analysis in High Power IGBT Modules

DEFF Research Database (Denmark)

Bahman, Amir Sajjad; Ma, Ke; Ghimire, Pramod

2016-01-01

)-based simulation is another method which is often used to analyze the steady-state thermal distribution of IGBT modules, but it is not possible to be used for long-term analysis of load profiles of power converter, which is needed for reliability assessments and better thermal design. This paper proposes a novel...... enables both accurate and fast temperature estimation of high power IGBT modules in the real loading conditions of the converter; meanwhile the critical details of the thermal dynamics and thermal distribution are also maintained. The proposed thermal model is verified by both FEM simulation......The conventional RC lumped thermal networks are widely used to estimate the temperature of power devices, but they are lack of accuracy in addressing detailed thermal behaviors/couplings in different locations and layers of the high power IGBT modules. On the other hand, Finite Element (FE...

A finite volume alternate direction implicit approach to modeling selective laser melting

DEFF Research Database (Denmark)

Hattel, Jesper Henri; Mohanty, Sankhya

2013-01-01

Over the last decade, several studies have attempted to develop thermal models for analyzing the selective laser melting process with a vision to predict thermal stresses, microstructures and resulting mechanical properties of manufactured products. While a holistic model addressing all involved...... to accurately simulate the process, are constrained by either the size or scale of the model domain. A second challenging aspect involves the inclusion of non-linear material behavior into the 3D implicit FE models. An alternating direction implicit (ADI) method based on a finite volume (FV) formulation...... is proposed for modeling single-layer and few-layers selective laser melting processes. The ADI technique is implemented and applied for two cases involving constant material properties and non-linear material behavior. The ADI FV method consume less time while having comparable accuracy with respect to 3D...

Fabrication, thermal properties and thermal stabilities of microencapsulated n-alkane with poly(lauryl methacrylate) as shell

International Nuclear Information System (INIS)

Qiu, Xiaolin; Lu, Lixin; Wang, Ju; Tang, Guoyi; Song, Guolin

2015-01-01

Highlights: • Microencapsulation of octadecane and paraffin by crosslinked poly(lauryl methacrylate). • Octadecane microcapsules have a melting enthalpy of about 118 J g −1 . • Weight loss temperatures of the microcapsules were increased by 67 °C and 28 °C. • Phase change enthalpies decreased by around 10 wt% after 500 thermal cycles. • Foams with microcapsules can be applied for passive temperature control. - Abstract: Microencapsulation of n-octadecane or paraffin with poly(lauryl methacrylate) (PLMA) shell was performed by a suspension-like polymerization. The polymer shell was crosslinked by pentaerythritol tetraacrylate (PETRA). The surface morphologies of microcapsules were investigated by scanning electron microscopy (SEM). Phase change properties, thermal reliabilities and thermal stabilities of microcapsules were determined by differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). The n-octadecane microcapsule exhibits higher melting enthalpy (118.0 J g −1 ) and crystallization enthalpy (108.3 J g −1 ) compared with the paraffin microcapsule. The thermal resistant temperatures were enhanced by more than 25 °C when n-alkanes were microencapsulated by PLMA. The PCM contents of microcapsules decreased by less than 4 wt% and 6 wt% after 500 and 1000 thermal cycles, respectively. Heat-up experiments indicated that microcapsule-treated foams exhibited upgraded thermal regulation capacities. Consequently, microencapsulated n-octadecane or paraffin with PLMA as shell possesses good potentials for heat storage and thermal regulation.

Shear-induced anisotropic plastic flow from body-centred-cubic tantalum before melting

Science.gov (United States)

Wu, Christine J.; Söderlind, Per; Glosli, James N.; Klepeis, John E.

2009-03-01

There are many structural and optical similarities between a liquid and a plastic flow. Thus, it is non-trivial to distinguish between them at high pressures and temperatures, and a detailed description of the transformation between these phenomena is crucial to our understanding of the melting of metals at high pressures. Here we report a shear-induced, partially disordered viscous plastic flow from body-centred-cubic tantalum under heating before it melts into a liquid. This thermally activated structural transformation produces a unique, one-dimensional structure analogous to a liquid crystal with the rheological characteristics of Bingham plastics. This mechanism is not specific to Ta and is expected to hold more generally for other metals. Remarkably, this transition is fully consistent with the previously reported anomalously low-temperature melting curve and thus offers a plausible resolution to a long-standing controversy about melting of metals under high pressures.

Thermal Vacuum Test of Ice as a Phase Change Material Integrated with a Radiator

Science.gov (United States)

Lee, Steve A.; Leimkuehler, Thomas O.; Stephan, Ryan; Le, Hung V.

2010-01-01

Water may be used as radiation shielding for Solar Particle Events (SPE) to protect crewmembers in the Lunar Electric Rover (LER). Because the water is already present for radiation protection, it could also provide a mass efficient solution to the vehicle's thermal control system. This water can be frozen by heat rejection from a radiator and used as a Phase Change Material (PC1V1) for thermal storage. Use of this water as a PCM can eliminate the need for a pumped fluid loop thermal control system as well as reduce the required size of the radiator. This paper describes the testing and analysis performed for the Rover Engineering Development Unit (REDU), a scaled-down version of a water PCM heat sink for the LER. The REDU was tested in a thermal-vacuum chamber at environmental temperatures similar to those of a horizontal radiator panel on the lunar surface. Testing included complete freeze and melt cycles along with scaled transient heat load profiles simulating a 24-hour day for the rover.

Melting method for miscellaneous radioactive solid waste and melting furnace

International Nuclear Information System (INIS)

Osaki, Toru; Furukawa, Hirofumi; Uda, Nobuyoshi; Katsurai, Kiyomichi

1998-01-01

A vessel containing miscellaneous solid wastes is inserted in a crucible having a releasable material on the inner surface, they are induction-heated from the outside of the crucible by way of low temperature heating coils to melt low melting point materials in the miscellaneous wastes within a temperature range at which the vessel does not melt. Then, they are induction-heated by way of high temperature heating coils to melt the vessel and not yet melted materials, those molten materials are cooled, solidified molten material and the releasable material are taken out, and then the crucible is used again. Then, the crucible can be used again, so that it can be applied to a large scaled melting furnace which treats wastes by a unit of drum. In addition, since the cleaning of the used crucible and the application of the releasable material can be conducted without interrupting the operation of the melting furnace, the operation cycle of the melting furnace can be shortened. (N.H.)

Composition, phase behavior and thermal stability of natural edible fat from rambutan (Nephelium lappaceum L.) seed.

Science.gov (United States)

Solís-Fuentes, Julio A; Camey-Ortíz, Guadalupe; Hernández-Medel, María del Rosario; Pérez-Mendoza, Francisco; Durán-de-Bazúa, Carmen

2010-01-01

In this paper, the chemical composition, the main physicochemical properties, phase behavior and thermal stability of rambutan (Nephelium lappaceum L.) seed fat were studied. These results showed that the almond-like decorticated seed represents 6.1% of the wet weight fruit and is: 1.22% ash, 7.80% protein, 11.6% crude fiber, 46% carbohydrates, and 33.4% fat (d.b.). The main fatty acids in the drupe fat were 40.3% oleic, 34.5% arachidic, 6.1% palmitic, 7.1% stearic, 6.3% gondoic, and 2.9% behenic; the refraction, saponification and iodine values were 1.468, 186, and 47.0, respectively. The phase behavior analysis showed relatively simple crystallization and melting profiles: crystallization showed three well-differentiated groups of triglycerides around maximum peaks at +30.8, +15.6 and -18.1 degrees C; the fat-melting curve had a range between -14.5 and +51.8 degrees C with a fusion enthalpy of 124.3 J/g. The thermal stability analyzed in an inert atmosphere of N(2) and in a normal oxidizing atmosphere, showed that in the latter, fat decomposition begins at 237.3 degrees C and concludes at 529 degrees C, with three stages of decomposition. According to these results, rambutan seed fat has physicochemical and thermal characteristics that may become interesting for specific applications in several segments of the food industry.

Using Pre-melted Phase Change Material to Keep Payload Warm without Power for Hours in Space

Science.gov (United States)

Choi, Michael K.

2012-01-01

During a payload transition from the transport vehicle to its worksite on the International Space Station (ISS), the payload is unpowered for up to 6 hours. Its radiator(s) will continue to radiate heat to space. It is necessary to make up the heat loss to maintain the payload temperature above the cold survival limit. Typically an interplanetary Probe has no power generation system. It relies on its battery to provide limited power for the Communication and Data Handling (C&DH) subsystem during cruise, and heater power is unavailable. It is necessary to maintain the C&DH temperature above the minimum operating limit. This paper presents a novel thermal design concept that utilizes phase change material (PCM) to store thermal energy by melting it before the payload or interplanetary Probe is unpowered. For the ISS, the PCM is melted by heaters just prior to the payload transition from the transport vehicle to its worksite. For an interplanetary Probe, the PCM is melted by heaters just prior to separation from the orbiter. The PCM releases thermal energy to keep the payload warm for several hours after power is cut off.

Melting heat transfer in boundary layer stagnation-point flow towards a stretching/shrinking sheet

International Nuclear Information System (INIS)

Bachok, Norfifah; Ishak, Anuar; Pop, Ioan

2010-01-01

An analysis is carried out to study the steady two-dimensional stagnation-point flow and heat transfer from a warm, laminar liquid flow to a melting stretching/shrinking sheet. The governing partial differential equations are converted into ordinary differential equations by similarity transformation, before being solved numerically using the Runge-Kutta-Fehlberg method. Results for the skin friction coefficient, local Nusselt number, velocity profiles as well as temperature profiles are presented for different values of the governing parameters. Effects of the melting parameter, stretching/shrinking parameter and Prandtl number on the flow and heat transfer characteristics are thoroughly examined. Different from a stretching sheet, it is found that the solutions for a shrinking sheet are non-unique.

Fatty acid profiling of raw human plasma and whole blood using direct thermal desorption combined with gas chromatography–mass spectrometry

NARCIS (Netherlands)

Akoto, L.; Vreuls, R.J.J.; Irth, H.; Pel, R.; Stellaard, F.

2008-01-01

Gas chromatography (GC) has in recent times become an important tool for the fatty acid profiling of human blood and plasma. An at-line procedure used in the fatty acid profiling of whole/intact aquatic micro-organisms without any sample preparation was adapted for this work. A direct thermal

Fatty acid profiling of raw human plasma and whole blood using direct thermal desorption combined with gas chromatography-mass spectrometry.

NARCIS (Netherlands)

Akoto, L.; Vreuls, J.J.; Irth, H.; Pel, R.; Stellaard, F.

2008-01-01

Gas chromatography (GC) has in recent times become an important tool for the fatty acid profiling of human blood and plasma. An at-line procedure used in the fatty acid profiling of whole/intact aquatic micro-organisms without any sample preparation was adapted for this work. A direct thermal

Fatty acid profiling of raw human plasma and whole blood using direct thermal desorption combined with gas chromatography-mass spectrometry

NARCIS (Netherlands)

Akoto, Lawrence; Vreuls, Rene J. J.; Irth, Hubertus; Pel, Roel; Stellaard, Frans

2008-01-01

Gas chromatography (GC) has in recent times become an important tool for the fatty acid profiling of human blood and plasma. An at-line procedure used in the fatty acid profiling of whole/intact aquatic micro-organisms without any sample preparation was adapted for this work. A direct thermal

The hardness of synthetic products obtained from cooled and crystallized basaltic melts (in Romanian)

OpenAIRE

Daniela Ogrean

2001-01-01

The Hardness of Synthetic Products Obtained from Cooled and Crystallized Basaltic Melts. Hardness is one of the main properties of the products obtained from cooled and crystallized basaltic melts under a controlled thermal regime. It influences the abrasion tear resistance of the resulted material. The microhardness measurements on the samples (bricks, boards, gutters, armour plates, tubes) indicated Vickers hardness value between 757–926 for the materials obtained from Şanovita basalts (Tim...

RADYN Simulations of Non-thermal and Thermal Models of Ellerman Bombs

Energy Technology Data Exchange (ETDEWEB)

Hong, Jie; Ding, M. D. [School of Astronomy and Space Science, Nanjing University, Nanjing 210023 (China); Carlsson, Mats, E-mail: dmd@nju.edu.cn [Institute of Theoretical Astrophysics, University of Oslo, P.O. Box 1029 Blindern, NO-0315 Oslo (Norway)

2017-08-20

Ellerman bombs (EBs) are brightenings in the H α line wings that are believed to be caused by magnetic reconnection in the lower atmosphere. To study the response and evolution of the chromospheric line profiles, we perform radiative hydrodynamic simulations of EBs using both non-thermal and thermal models. Overall, these models can generate line profiles that are similar to observations. However, in non-thermal models we find dimming in the H α line wings and continuum when the heating begins, while for the thermal models dimming occurs only in the H α line core, and with a longer lifetime. This difference in line profiles can be used to determine whether an EB is dominated by non-thermal heating or thermal heating. In our simulations, if a higher heating rate is applied, then the H α line will be unrealistically strong and there are still no clear UV burst signatures.

RADYN Simulations of Non-thermal and Thermal Models of Ellerman Bombs

Science.gov (United States)

Hong, Jie; Carlsson, Mats; Ding, M. D.

2017-08-01

Ellerman bombs (EBs) are brightenings in the Hα line wings that are believed to be caused by magnetic reconnection in the lower atmosphere. To study the response and evolution of the chromospheric line profiles, we perform radiative hydrodynamic simulations of EBs using both non-thermal and thermal models. Overall, these models can generate line profiles that are similar to observations. However, in non-thermal models we find dimming in the Hα line wings and continuum when the heating begins, while for the thermal models dimming occurs only in the Hα line core, and with a longer lifetime. This difference in line profiles can be used to determine whether an EB is dominated by non-thermal heating or thermal heating. In our simulations, if a higher heating rate is applied, then the Hα line will be unrealistically strong and there are still no clear UV burst signatures.

A thermal model for czochralski silicon crystal growth with an axial magnetic field

Science.gov (United States)

Hjellming, L. N.

1990-07-01

This paper presents a thermal model for molten silicon in a Czochralski crystal puller system with an applied uniform axial magnetic field. The melt depth is treated as continually decreasing, which affects the thermal environment of the melt and crystal. The radiative heat loss and the input heat flux are treated as functions of time, with a constraint placed on the heat lost to the crystal from the melt. As the melt motion reaches a steady state rapidly, the temperature and flow fields are treated as instantaneously steady at each melt depth. The heat transport is a mixture of conduction and convection, and by considering the crystal and crucible to be rotating with the same angular velocity, the flows driven by buoyancy and thermocapillarity are isolated and provide the convective heat transport in the melt for the range of magnetic field strengths 0.2 ≤ B ≤ 1.0T.

Development of the conductivity thermal logs based on electrical profiles; Desenvolvimento de perfil de condutividade termica a partir de perfis eletricos

Energy Technology Data Exchange (ETDEWEB)

Jesus, Carlos Luciano C. de; Lima, Olivar A.L. de; Argollo, Roberto M.; Romero, Pedro A. [Universidade Federal da Bahia, Salvador, BA (Brazil). Centro de Pesquisa em Geologia e Geofisica

2004-07-01

The thermal conductivity of the rocks is a necessary physical parameter for the calculation of the flow of heat in the terrestrial surface. The conventional methods to measure the thermal conductivity are developed in laboratory having used sample of certifications. However, these nor always are disposable by the industry of the oil, either because of difficulty operational either for its high cost. However, all the constructed wells of oil are stood geophysically, and, in the majority of the times the geophysical profiles are the only petrophysics registers of the wells, mainly when the same ones are not testified. A viable alternative for sedimentary rocks would be to determine the thermal conductivity through the electric conductivity, being this normally gotten in electric profiles of wells. As the electric conductivity and the thermal conductivity they depend on the porosity and of the texture of the rocks and these mathematically equivalents satisfy equations constituent, are intuitive to think that the same largeness can directly be correlated. Applying the same analytical theoretical procedure considered by Lima and Sharma (1990 and 1992) to describe the electric conductivity of clay-sand, we develop an expression to determine the thermal conductivity of clay-sandstone rocks. To test the applicability of this equation they had been used given of electric profile of five explore wells of the regions of Aracas and Miranga, both of the basin of Reconcavo. The results of the conversions are comparable with the ones of effected measures of thermal conductivity with the method of the bar for Carvalho (1981) in the terrigenous sequences of the Reconcavo. (author)

Ion beam surface treatment: A new capability for rapid melt and resolidification of surfaces

International Nuclear Information System (INIS)

Stinnett, R.W.; McIntyre, D.C.; Buchheit, R.G.; Greenly, J.B.; Thompson, M.O.

1994-01-01

The emerging capability to produce high average power (5--250 kW) pulsed ion beams at 0.2--2 MeV energies is enabling us to develop a new, commercial-scale thermal surface treatment technology called Ion Beam Surface Treatment (IBEST). This technique uses high energy, pulsed (≤100 ns) ion beams to directly deposit energy in the top 2--20 micrometers of the surface of any material. Depth of treatment is controllable by varying the ion energy and species. Deposition of the energy with short pulses in a thin surface layer allows melting of the layer with relatively small energies and allows rapid cooling of the melted layer by thermal diffusion into the underlying substrate. Typical cooling rates of this process (10 9 10 10 K/sec) cause rapid resolidification, resulting in production of non-equilibrium microstructures (nano-crystalline and metastable phases) that have significantly improved corrosion, wear, and hardness properties. We have conducted IBEST feasibility experiments with results confirming surface hardening, nanocrystaline grain formation, metal surface polishing, controlled melt of ceramic surfaces, and surface cleaning

Decreasing electrical resistivity of silver along the melting boundary up to 5 GPa

Science.gov (United States)

Littleton, Joshua A. H.; Secco, Richard A.; Yong, Wenjun

2018-04-01

The electrical resistivity of Ag was experimentally measured at high pressures up to 5 GPa and at temperatures up to ∼300 K above melting. The resistivity decreased as a function of pressure and increased as a function of temperature as expected and is in very good agreement with 1 atm data. Observed melting temperatures at high pressures also agree well with previous experimental and theoretical studies. The main finding of this study is that resistivity of Ag decreases along the pressure- and temperature-dependent melting boundary, in conflict with prediction of resistivity invariance. This result is discussed in terms of the dominant contribution of the increasing energy separation between the Fermi level and 4d-band as a function of pressure. Calculated from the resistivity using the Wiedemann-Franz law, the electronic thermal conductivity increased as a function of pressure and decreased as a function of temperature as expected. The decrease in the high pressure thermal conductivity in the liquid phase as a function of temperature contrasts with the behavior of the 1 atm data.

An assessment of the CORCON-MOD3 code. Part 1: Thermal-hydraulic calculations

International Nuclear Information System (INIS)

Strizhov, V.; Kanukova, V.; Vinogradova, T.; Askenov, E.; Nikulshin, V.

1996-09-01

This report deals with the subject of CORCON-Mod3 code validation (thermal-hydraulic modeling capability only) based on MCCI (molten core concrete interaction) experiments conducted under different programs in the past decade. Thermal-hydraulic calculations (i.e., concrete ablation, melt temperature, melt energy, concrete temperature, and condensible and non-condensible gas generation) were performed with the code, and compared with the data from 15 experiments, conducted at different scales using both simulant (metallic and oxidic) and prototypic melt materials, using different concrete types, and with and without an overlying water pool. Sensitivity studies were performed in a few cases involving, for example, heat transfer from melt to concrete, condensed phase chemistry, etc. Further, special analysis was performed using the ACE L8 experimental data to illustrate the differences between the experimental and the reactor conditions, and to demonstrate that with proper corrections made to the code, the calculated results were in better agreement with the experimental data. Generally, in the case of dry cavity and metallic melts, CORCON-Mod3 thermal-hydraulic calculations were in good agreement with the test data. For oxidic melts in a dry cavity, uncertainties in heat transfer models played an important role for two melt configurations--a stratified geometry with segregated metal and oxide layers, and a heterogeneous mixture. Some discrepancies in the gas release data were noted in a few cases

Tin in granitic melts: The role of melting temperature and protolith composition

Science.gov (United States)

Wolf, Mathias; Romer, Rolf L.; Franz, Leander; López-Moro, Francisco Javier

2018-06-01

Granite bound tin mineralization typically is seen as the result of extreme magmatic fractionation and late exsolution of magmatic fluids. Mineralization, however, also could be obtained at considerably less fractionation if initial melts already had enhanced Sn contents. We present chemical data and results from phase diagram modeling that illustrate the dominant roles of protolith composition, melting conditions, and melt extraction/evolution for the distribution of Sn between melt and restite and, thus, the Sn content of melts. We compare the element partitioning between leucosome and restite of low-temperature and high-temperature migmatites. During low-temperature melting, trace elements partition preferentially into the restite with the possible exception of Sr, Cd, Bi, and Pb, that may be enriched in the melt. In high-temperature melts, Ga, Y, Cd, Sn, REE, Pb, Bi, and U partition preferentially into the melt whereas Sc, V, Cr, Co, Ni, Mo, and Ba stay in the restite. This contrasting behavior is attributed to the stability of trace element sequestering minerals during melt generation. In particular muscovite, biotite, titanite, and rutile act as host phases for Sn and, therefore prevent Sn enrichment in the melt as long as they are stable phases in the restite. As protolith composition controls both the mineral assemblage and modal contents of the various minerals, protolith composition eventually also controls the fertility of a rock during anatexis, restite mineralogy, and partitioning behavior of trace metals. If a particular trace element is sequestered in a phase that is stable during partial melting, the resulting melt is depleted in this element whereas the restite becomes enriched. Melt generation at high temperature may release Sn when Sn-hosts become unstable. If melt has not been lost before the breakdown of Sn-hosts, Sn contents in the melt will increase but never will be high. In contrast, if melt has been lost before the decomposition of Sn

Comparative Study on Two Melting Simulation Methods: Melting Curve of Gold

International Nuclear Information System (INIS)

Liu Zhong-Li; Li Rui; Sun Jun-Sheng; Zhang Xiu-Lu; Cai Ling-Cang

2016-01-01

Melting simulation methods are of crucial importance to determining melting temperature of materials efficiently. A high-efficiency melting simulation method saves much simulation time and computational resources. To compare the efficiency of our newly developed shock melting (SM) method with that of the well-established two-phase (TP) method, we calculate the high-pressure melting curve of Au using the two methods based on the optimally selected interatomic potentials. Although we only use 640 atoms to determine the melting temperature of Au in the SM method, the resulting melting curve accords very well with the results from the TP method using much more atoms. Thus, this shows that a much smaller system size in SM method can still achieve a fully converged melting curve compared with the TP method, implying the robustness and efficiency of the SM method. (paper)

Changes in structure of the short-range order of the InP melt when heated

International Nuclear Information System (INIS)

Glazov, V.M.; Dovletov, K.; Nashel'skij, A.Ya.; Mamedov, M.M.

1977-01-01

An investigation of the temperature dependence of the InP viscosity has indicated an ''after-melting'' effect similar to that observed in other A 3 V 5 compounds having a sphalerite structure. The termodynamic parameters of the viscous flow of indium phosphide melt have been calculated, and a suggestion has been made on the loosening of the short-range order structure of the melt during the period preceding solidification. With the similarity in the behaviour of InP and of A 3 Sb compound melts as a basis, a suggestion has been put forward that the influence of the thermal dissociation upon the character of the changes in the short-range order structure directly after transition from the solid to the liquid phase is negligible

Thermal phase diagram of acetamide-benzoic acid and benzoic acid-phthalimide binary systems for solar thermal applications

Energy Technology Data Exchange (ETDEWEB)

Kumar, Rohitash, E-mail: dootrohit1976@gmail.com [Defence Laboratory Jodhpur, Rajasthan, India 342011, +91-2912567520 (India); Department of Physics & Center for Solar Energy, Indian Institute of Technology Jodhpur, Rajasthan, India 342011, +91-291-2449045 (India); Kumar, Ravindra [Defence Laboratory Jodhpur, Rajasthan, India 342011, +91-2912567520 (India); Dixit, Ambesh, E-mail: ambesh@iitj.ac.in [Department of Physics & Center for Solar Energy, Indian Institute of Technology Jodhpur, Rajasthan, India 342011, +91-291-2449045 (India)

2016-05-06

Thermal properties of Acetamide (AM) – Benzoic acid (BA) and Benzoic acid (BA) – Phthalimide (PM) binary eutectic systems are theoretically calculated using thermodynamic principles. We found that the binary systems of AM-BA at 67.6 : 32.4 molar ratio, BA-PM at 89.7 : 10.3 molar ratio form eutectic mixtures with melting temperatures ~ 54.5 °C and 114.3 °C respectively. Calculated latent heat of fusion for these eutectic mixtures are 191 kJ/kg and 146.5 kJ/kg respectively. These melting temperatures and heat of fusions of these eutectic mixtures make them suitable for thermal energy storage applications in solar water heating and solar cooking systems.

Synthesis by irradiation and mechanism and structural characterization study of high melt strength polypropylene

International Nuclear Information System (INIS)

Lugao, Ademar Benevolo

2004-01-01

Polypropylene molecular structure is made only by linear molecules interacting by weak forces. The resulting PP has very low melt strength (MS). MS is important to make feasible to process PP by all the transformation technologies based on the free expansion of the melt. The aim of this work was to develop a new process to synthesize PP with crosslinks and/or long chain branches, known as High Melt Strength Polypropylene (HMSPP) and to characterize its structure and synthesis mechanism. HMSPP was obtained by the irradiation of PP under a crosslinking (acetylene) atmosphere or inert or oxidative one, followed by thermal treatment for radical recombination and thermal treatment for annihilation of the remaining radicals under reactive or inert atmosphere. The results from rheological characterization showed that the highest levels of MS were obtained by conducting irradiation and thermal treatments under crosslinking atmospheres. The results for the elucidation of reaction mechanism by electron spin resonance (ESR) showed that acetylene irradiation is effective in promoting the creation of double bonds, based on the formation of polyenil radicals. The results of structural unraveling showed that radiation promotes predominantly the degradation of atactic molecules or molecules with atactic defects. These results support the hypothesis of formation of branched PP molecules based on the reaction of those fragments with the double bonds created in the PP molecules. (author)

Application of phase change materials in thermal management of electronics

International Nuclear Information System (INIS)

Kandasamy, Ravi; Wang Xiangqi; Mujumdar, Arun S.

2007-01-01

Application of a novel PCM package for thermal management of portable electronic devices was investigated experimentally for effects of various parameters e.g. power input, orientation of package, and various melting/freezing times under cyclic steady conditions. Also, a two-dimensional numerical study was made and compared the experimental results. Results show that increased power inputs increase the melting rate, while orientation of the package to gravity has negligible effect on the thermal performance of the PCM package. The thermal resistance of the device and the power level applied to the PCM package are of critical importance for design of a passive thermal control system. Comparison with numerical results confirms that PCM-based design is an excellent candidate design for transient electronic cooling applications

Experiments on interactions between zirconium-containing melt and water (ZREX). Hydrogen generation and chemical augmentation of energetics

Energy Technology Data Exchange (ETDEWEB)

Cho, D.H.; Armstrong, D.R.; Gunther, W.H. [Argonne National Lab., IL (United States); Basu, S.

1998-01-01

The results of the first data series of experiments on interactions between zirconium-containing melt and water are described. These experiments involved dropping 1-kg batches of pure zirconium or zirconium-zirconium dioxide mixture melt into a column of water. A total of nine tests were conducted, including four with pure zirconium melt and five with Zr-ZrO{sub 2} mixture melt. Explosions took place only in those tests which were externally triggered. While the extent of zirconium oxidation in the triggered experiments was quite extensive, the estimated explosion energetics were found to be very small compared to the combined thermal and chemical energy available. (author)

Seismogenic frictional melting in the magmatic column as the driving force of stick-slip motion

Science.gov (United States)

Kendrick, J. E.; Lavallee, Y.; Hirose, T.; Di Toro, G.; Hornby, A.; De Angelis, S.; Henton De Angelis, S.; Ferk, A.; Hess, K.; Leonhardt, R.; Dingwell, D. B.

2013-12-01

Lava dome eruptions subjected to high extrusion rates commonly evolve from endogenous to exogenous growth and limits to their structural stability hold catastrophic potential as explosive eruption triggers. In the conduit strain localisation in magma, accompanied by seismogenic failure, marks the onset of brittle magma ascent dynamics. The rock record of exogenous dome structures preserves vestiges of cataclastic processes and of thermal anomalies, key to unravelling subsurface processes. A combined structural, thermal and magnetic investigation of shear bands from Mount St. Helens (MSH) and Soufrière Hills volcano (SHV) reveal evidence of faulting and frictional melting within the magmatic column. High velocity rotary shear (HVR) experiments demonstrate the propensity for melting of andesitic and dacitic material (from SHV and MSH respectively) at upper conduit stress conditions. Such melting events may be linked to the step-wise extrusion of magma accompanied by repetitive long-period (LP) seismicity. Using a source duration calculated from the waveforms at seismic stations around SHV, and slip distance per drumbeat calculated from extrusion rate, frictional melting of SHV andesite in a high velocity rotary shear apparatus can be achieved at small slip distances (HVR experiments which mimic rapid velocity fluctuations in stick-slip behavior demonstrate velocity-weakening behavior of melt, with a tendency for unstable slip. We postulate that pseudotachylyte generation could be the underlying cause of stick-slip motion and associated seismic 'drumbeats', which are so commonly observed at dome-building volcanoes, allowing for a fixed spatial locus and the occurrence of 'families' of similar seismic events. We conclude that, given the ease with which melting is achieved in volcanic rocks, and considering the high ambient temperatures in volcanic conduits, frictional melting is a highly probable consequence of viscous magma ascent.

Deep pooling of low degree melts and volatile fluxes at the 85°E segment of the Gakkel Ridge: Evidence from olivine-hosted melt inclusions and glasses

Science.gov (United States)

Shaw, Alison M.; Behn, Mark D.; Humphris, Susan E.; Sohn, Robert A.; Gregg, Patricia M.

2010-01-01

We present new analyses of volatile, major, and trace elements for a suite of glasses and melt inclusions from the 85°E segment of the ultra-slow spreading Gakkel Ridge. Samples from this segment include limu o pele and glass shards, proposed to result from CO 2-driven explosive activity. The major element and volatile compositions of the melt inclusions are more variable and consistently more primitive than the glass data. CO 2 contents in the melt inclusions extend to higher values (167-1596 ppm) than in the co-existing glasses (187-227 ppm), indicating that the melt inclusions were trapped at greater depths. These melt inclusions record the highest CO 2 melt concentrations observed for a ridge environment. Based on a vapor saturation model, we estimate that the melt inclusions were trapped between seafloor depths (˜ 4 km) and ˜ 9 km below the seafloor. However, the glasses are all in equilibrium with their eruption depths, which is inconsistent with the rapid magma ascent rates expected for explosive activity. Melting conditions inferred from thermobarometry suggest relatively deep (25-40 km) and cold (1240°-1325 °C) melting conditions, consistent with a thermal structure calculated for the Gakkel Ridge. The water contents and trace element compositions of the melt inclusions and glasses are remarkably homogeneous; this is an unexpected result for ultra-slow spreading ridges, where magma mixing is generally thought to be less efficient based on the assumption that steady-state crustal magma chambers are absent in these environments. All melts can be described by a single liquid line of descent originating from a pooled melt composition that is consistent with the aggregate melt calculated from a geodynamic model for the Gakkel Ridge. These data suggest a model in which deep, low degree melts are efficiently pooled in the upper mantle (9-20 km depth), after which crystallization commences and continues during ascent and eruption. Based on our melting model

Numerical and experimental investigation of melting with internal heat generation within cylindrical enclosures

Energy Technology Data Exchange (ETDEWEB)

Amber Shrivastava; Brian Williams; Ali S. Siahpush; Bruce Savage; John Crepeau

2014-06-01

There have been significant efforts by the heat transfer community to investigate the melting phenomenon of materials. These efforts have included the analytical development of equations to represent melting, numerical development of computer codes to assist in modeling the phenomena, and collection of experimental data. The understanding of the melting phenomenon has application in several areas of interest, for example, the melting of a Phase Change Material (PCM) used as a thermal storage medium as well as the melting of the fuel bundle in a nuclear power plant during an accident scenario. The objective of this research is two-fold. First a numerical investigation, using computational fluid dynamics (CFD), of melting with internal heat generation for a vertical cylindrical geometry is presented. Second, to the best of authors knowledge, there are very limited number of engineering experimental results available for the case of melting with Internal Heat Generation (IHG). An experiment was performed to produce such data using resistive, or Joule, heating as the IHG mechanism. The numerical results are compared against the experimental results and showed favorable correlation. Uncertainties in the numerical and experimental analysis are discussed. Based on the numerical and experimental analysis, recommendations are made for future work.

Shear Melting of a Colloidal Glass

Science.gov (United States)

Eisenmann, Christoph; Kim, Chanjoong; Mattsson, Johan; Weitz, David A.

2010-01-01

We use confocal microscopy to explore shear melting of colloidal glasses, which occurs at strains of ˜0.08, coinciding with a strongly non-Gaussian step size distribution. For larger strains, the particle mean square displacement increases linearly with strain and the step size distribution becomes Gaussian. The effective diffusion coefficient varies approximately linearly with shear rate, consistent with a modified Stokes-Einstein relationship in which thermal energy is replaced by shear energy and the length scale is set by the size of cooperatively moving regions consisting of ˜3 particles.

Amphibious Magnetotelluric Investigation of the Aleutian Arc: Mantle Melt Generation and Migration beneath Okmok Caldera

Science.gov (United States)

Zelenak, G.; Key, K.; Bennington, N. L.; Bedrosian, P.

2015-12-01

Understanding the factors controlling the release of volatiles from the downgoing slab, the subsequent generation of melt in the overlying mantle wedge, the migration of melt to the crust, and its evolution and emplacement within the crust are important for advancing our understanding of arc magmatism and crustal genesis. Because melt and aqueous fluids are a few orders of magnitude more electrically conductive than unmelted peridotite, the conductivity-mapping magnetotelluric (MT) method is well-suited to imaging fluids and melt beneath arc volcanoes. Here we present conductivity results from an amphibious MT profile crossing Okmok volcano in the central Aleutian arc. The Aleutian arc is one of the most volcanically active regions in North America, making it an ideal location for studying arc magnetism. Okmok volcano, located on the northeastern portion of Umnak Island, is among the most active volcanoes in the Aleutian chain. In addition to two caldera-forming events in the Holocene, numerous eruptions in the past century indicate a robust magmatic supply. Previous coarse resolution seismic studies have inferred a crustal magma reservoir. In order to investigate the role fluids play in melting the mantle wedge, how melts ascend through the corner flow regime of the mantle wedge, how melt migrates and is stored within the upper mantle and crust, and how this impacts explosive caldera forming eruptions, we carried out an amphibious geophysical survey across the arc in June-July 2015. Twenty-nine onshore MT stations and 10 offshore stations were collected in a 3D array covering Okmok, and 43 additional offshore MT stations completed a 300 km amphibious profile starting at the trench, crossing the forearc, arc and backarc. Thirteen onshore passive seismic stations were also installed and will remain in place for one year to supplement the twelve permanent stations on the island. Data collected by this project will be used to map seismic velocity and electrical

First experimental observations on melting and chemical modification of volcanic ash during lightning interaction.

Science.gov (United States)

Mueller, S P; Helo, C; Keller, F; Taddeucci, J; Castro, J M

2018-01-23

Electrification in volcanic ash plumes often leads to syn-eruptive lightning discharges. High temperatures in and around lightning plasma channels have the potential to chemically alter, re-melt, and possibly volatilize ash fragments in the eruption cloud. In this study, we experimentally simulate temperature conditions of volcanic lightning in the laboratory, and systematically investigate the effects of rapid melting on the morphology and chemical composition of ash. Samples of different size and composition are ejected towards an artificially generated electrical arc. Post-experiment ash morphologies include fully melted spheres, partially melted particles, agglomerates, and vesiculated particles. High-speed imaging reveals various processes occurring during the short lightning-ash interactions, such as particle melting and rounding, foaming, and explosive particle fragmentation. Chemical analyses of the flash-melted particles reveal considerable bulk loss of Cl, S, P and Na through thermal vaporization. Element distribution patterns suggest convection as a key process of element transport from the interior of the melt droplet to rim where volatiles are lost. Modeling the degree of sodium loss delivers maximum melt temperatures between 3290 and 3490 K. Our results imply that natural lighting strikes may be an important agent of syn-eruptive morphological and chemical processing of volcanic ash.

Thermal behavior of latent thermal energy storage unit using two phase change materials: Effects of HTF inlet temperature

Directory of Open Access Journals (Sweden)

Fouzi Benmoussa

2017-09-01

Full Text Available This work presents a numerical study of the thermal behavior of shell-and-tube latent thermal energy storage (LTES unit using two phase change materials (PCMs. The heat transfer fluid (HTF flow through the inner tube and transfer the heat to PCMs. First, a mathematical model is developed based on the enthalpy formulation and solved through the governing equations. Second, the effects of HTF inlet temperature on the unsteady temperature evolution of PCMs, the total energy stored evolution as well as the total melting time is studied. Numerical results show that for all HTF inlet temperature, melting rate of PCM1 is the fastest and that of PCM2 is the slowest; increasing the HTF inlet temperature considerably increases the temperature evolution of PCMs. The maximum energy stored is observed in PCM2 with high melting temperature and high specific heat; heat storage capacity is large for high HTF inlet temperature. When the HTF inlet temperature increases from 338 K to 353 K, decreasing degree of melting time of PCM2 is the biggest from 1870 s to 490 s, which reduces about 73.8%; decreasing degree of melting time of PCM1 is the smallest from 530 s to 270 s, which reduces about 49.1%.

Preparation and thermal energy storage properties of paraffin/expanded graphite composite phase change material

International Nuclear Information System (INIS)

Zhang, Zhengguo; Zhang, Ni; Peng, Jing; Fang, Xiaoming; Gao, Xuenong; Fang, Yutang

2012-01-01

Highlights: ► EG was obtained by microwave irradiation to prepare the paraffin/EG composite PCM. ► Composite PCM was characterized by XRD to investigate the chemical compatibility. ► Temperature profiles of the composite PCM were obtained during thermal energy storage. -- Abstract: The paraffin/expanded graphite (EG) composite phase change material (PCM) was prepared by absorbing liquid paraffin into EG, in which paraffin was chosen as the PCM. EG was produced by microwave irradiation performed at room temperature. It was found that the EG prepared at 800 W irradiation power for 10 s exhibited the maximum sorption capacity of 92 wt% for paraffin. Scanning electron microscopy images showed that paraffin was uniformly dispersed in the pores of EG. Differential scanning calorimeter analysis indicated that the melting temperature of the composite PCM was close to that of paraffin, and its latent heat was equivalent to the calculated value based on the mass fraction of paraffin in the composite. X-ray diffraction analysis showed that the composite PCM was just a combination of paraffin with EG, and no new substance was produced. Thermal energy storage performance of the composite PCM was tested in a latent thermal energy storage (LTES) system. Transients of axial and radial temperature profiles were obtained in the LTES for the composite PCM and paraffin. The thermal energy storage charging duration for the composite PCM was reduced obviously compared to paraffin.

Application of the specific thermal properties of Ag nanoparticles to high-resolution metal patterning

International Nuclear Information System (INIS)

Son, Yong; Yeo, Junyeob; Ha, Cheol Woo; Lee, Jinhwan; Hong, Sukjoon; Nam, Koo Hyun; Yang, Dong-Yol; Ko, Seung Hwan

2012-01-01

Metal nanoparticles exhibit specific electronic, chemical and optical properties due to the thermodynamic size effect, which cannot be observed in bulk materials. Ag NPs show size dependent melting temperature depression phenomena. In this study, the thermal sintering behavior of the self-assembled monolayer protected Ag NPs has been observed using in situ transmission electron microscopy. The thermal characteristics of the Ag NPs have also been examined with a thermogravimetric analysis, a differential scanning calorimetry and a thermal conductivity measurement. These assessments have shown that the melting of the Ag NPs starts at 150 °C, which is much lower than the melting temperature of bulk silver (960 °C). The measured thermal conductivity of the Ag NPs (0.37 W/(m K)) is also lower than that of bulk silver (429 W/(m K)). These specific thermal properties of the Ag NPs can be applied to a low-temperature and a high-resolution direct-metal patterning process.

Fabrication, thermal properties and thermal stabilities of microencapsulated n-alkane with poly(lauryl methacrylate) as shell

Energy Technology Data Exchange (ETDEWEB)

Qiu, Xiaolin, E-mail: shirleyqiu2009@gmail.com [Jiangsu Key Laboratory of Advanced Food Manufacturing Equipment and Technology, School of Mechanical Engineering, Jiangnan University, Wuxi 214122 (China); Lu, Lixin; Wang, Ju [Jiangsu Key Laboratory of Advanced Food Manufacturing Equipment and Technology, School of Mechanical Engineering, Jiangnan University, Wuxi 214122 (China); Tang, Guoyi [Advanced Materials Institute and Clearer Production Key Laboratory, Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055 (China); Key Laboratory of Advanced Materials, Department of Materials Science and Engineering, Tsinghua University, Haidian District, Beijing 100084 (China); Song, Guolin [Advanced Materials Institute and Clearer Production Key Laboratory, Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055 (China)

2015-11-20

Highlights: • Microencapsulation of octadecane and paraffin by crosslinked poly(lauryl methacrylate). • Octadecane microcapsules have a melting enthalpy of about 118 J g{sup −1}. • Weight loss temperatures of the microcapsules were increased by 67 °C and 28 °C. • Phase change enthalpies decreased by around 10 wt% after 500 thermal cycles. • Foams with microcapsules can be applied for passive temperature control. - Abstract: Microencapsulation of n-octadecane or paraffin with poly(lauryl methacrylate) (PLMA) shell was performed by a suspension-like polymerization. The polymer shell was crosslinked by pentaerythritol tetraacrylate (PETRA). The surface morphologies of microcapsules were investigated by scanning electron microscopy (SEM). Phase change properties, thermal reliabilities and thermal stabilities of microcapsules were determined by differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). The n-octadecane microcapsule exhibits higher melting enthalpy (118.0 J g{sup −1}) and crystallization enthalpy (108.3 J g{sup −1}) compared with the paraffin microcapsule. The thermal resistant temperatures were enhanced by more than 25 °C when n-alkanes were microencapsulated by PLMA. The PCM contents of microcapsules decreased by less than 4 wt% and 6 wt% after 500 and 1000 thermal cycles, respectively. Heat-up experiments indicated that microcapsule-treated foams exhibited upgraded thermal regulation capacities. Consequently, microencapsulated n-octadecane or paraffin with PLMA as shell possesses good potentials for heat storage and thermal regulation.

Olivine/melt transition metal partitioning, melt composition, and melt structure—Melt polymerization and Qn-speciation in alkaline earth silicate systems

Science.gov (United States)

Mysen, Bjorn O.

2008-10-01

The two most abundant network-modifying cations in magmatic liquids are Ca 2+ and Mg 2+. To evaluate the influence of melt structure on exchange of Ca 2+ and Mg 2+ with other geochemically important divalent cations ( m-cations) between coexisting minerals and melts, high-temperature (1470-1650 °C), ambient-pressure (0.1 MPa) forsterite/melt partitioning experiments were carried out in the system Mg 2SiO 4-CaMgSi 2O 6-SiO 2 with ⩽1 wt% m-cations (Mn 2+, Co 2+, and Ni 2+) substituting for Ca 2+ and Mg 2+. The bulk melt NBO/Si-range ( NBO/Si: nonbridging oxygen per silicon) of melt in equilibrium with forsterite was between 1.89 and 2.74. In this NBO/Si-range, the NBO/Si(Ca) (fraction of nonbridging oxygens, NBO, that form bonds with Ca 2+, Ca 2+- NBO) is linearly related to NBO/Si, whereas fraction of Mg 2+- NBO bonds is essentially independent of NBO/Si. For individual m-cations, rate of change of KD( m-Mg) with NBO/Si(Ca) for the exchange equilibrium, mmelt + Mg olivine ⇌ molivine + Mg melt, is linear. KD( m-Mg) decreases as an exponential function of increasing ionic potential, Z/ r2 ( Z: formal electrical charge, r: ionic radius—here calculated with oxygen in sixfold coordination around the divalent cations) of the m-cation. The enthalpy change of the exchange equilibrium, Δ H, decreases linearly with increasing Z/ r2 [Δ H = 261(9)-81(3)· Z/ r2 (Å -2)]. From existing information on (Ca,Mg)O-SiO 2 melt structure at ambient pressure, these relationships are understood by considering the exchange of divalent cations that form bonds with nonbridging oxygen in individual Qn-species in the melts. The negative ∂ KD( m-Mg) /∂( Z/ r2) and ∂(Δ H)/∂( Z/ r2) is because increasing Z/ r2 is because the cations forming bonds with nonbridging oxygen in increasingly depolymerized Qn-species where steric hindrance is decreasingly important. In other words, principles of ionic size/site mismatch commonly observed for trace and minor elements in crystals, also

Localized melt-scan strategy for site specific control of grain size and primary dendrite arm spacing in electron beam additive manufacturing

International Nuclear Information System (INIS)

Raghavan, Narendran; Simunovic, Srdjan; Dehoff, Ryan; Plotkowski, Alex; Turner, John; Kirka, Michael; Babu, Suresh

2017-01-01

In addition to design geometry, surface roughness, and solid-state phase transformation, solidification microstructure plays a crucial role in controlling the performance of additively manufactured components. Crystallographic texture, primary dendrite arm spacing (PDAS), and grain size are directly correlated to local solidification conditions. We have developed a new melt-scan strategy for inducing site specific, on-demand control of solidification microstructure. We were able to induce variations in grain size (30 μm–150 μm) and PDAS (4 μm - 10 μm) in Inconel 718 parts produced by the electron beam additive manufacturing system (Arcam ® ). A conventional raster melt-scan resulted in a grain size of about 600 μm. The observed variations in grain size with different melt-scan strategies are rationalized using a numerical thermal and solidification model which accounts for the transient curvature of the melt pool and associated thermal gradients and liquid-solid interface velocities. The refinement in grain size at high cooling rates (>10 4  K/s) is also attributed to the potential heterogeneous nucleation of grains ahead of the epitaxially growing solidification front. The variation in PDAS is rationalized using a coupled numerical-theoretical model as a function of local solidification conditions (thermal gradient and liquid-solid interface velocity) of the melt pool.

The effects of radiative heat transfer during the melting process of a high temperature phase change material confined in a spherical shell

International Nuclear Information System (INIS)

Archibold, Antonio Ramos; Rahman, Muhammad M.; Yogi Goswami, D.; Stefanakos, Elias K.

2015-01-01

Highlights: • Analyzed effects of radiation heat transfer during melting in spherical shell. • Performed analyses to ascertain the effects of optical thickness and the Planck, Grashof and Stefan numbers. • Present correlations for melt fraction and modified Nusselt number. - Abstract: The influence of radiation heat transfer during the phase change process of a storage material has been numerically analyzed in this study. Emphasis has been placed on the thermal characterization of a single constituent storage module rather than an entire storage system, in order to precisely capture the energy exchange contributions of all the fundamental heat transfer mechanisms during the melting of a phase change material (PCM) with tailored optical properties. The equations describing the conservation of mass, momentum and energy have been solved by using the control volume discretization approach, while the radiative transfer equation (RTE) was solved by the discrete ordinate method (DOM). The enthalpy–porosity method was used to track the PCM liquid/solid interface during the process. A parametric analysis has been performed in order to ascertain the effects of the optical thickness and the Planck, Grashof and Stefan numbers on the melting rate, as well as the total and radiative heat transfer rates at the inner surface of the shell. The results show that the presence of thermal radiation enhances the melting process. Correlations for the melt fraction and modified Nusselt number are developed for application in the design process of packed bed heat exchangers for latent heat thermal energy storage

Diluted melt proton exchange slab waveguides in LiNbO3: A new fabrication and characterization method

DEFF Research Database (Denmark)

Veng, Torben; Skettrup, Torben

1997-01-01

A method of dilute-melt proton exchange employing a mixture of glycerol and KHSO4 with lithium benzoate added is used to fabricate planar waveguides in c-cut LiNbO3. With this exchange melt system the waveguide refractive index profiles can be fabricated with a high degree of reproducibility...... the waveguide refractive index profile from the measured mode indices is introduced. The main advantage of this characterization method compared with other methods is that it also applies to single-mode waveguides. Using the new characterization method we investigate in detail the relation between waveguide...

INTERACTION STUDIES OF CERAMIC VACUUM PLASMA SPRAYING FOR THE MELTING CRUCIBLE MATERIALS

Directory of Open Access Journals (Sweden)

JONG HWAN KIM

2013-10-01

Full Text Available Candidate coating materials for re-usable metallic nuclear fuel crucibles, TaC, TiC, ZrC, ZrO2, and Y2O3, were plasma-sprayed onto a niobium substrate. The microstructure of the plasma-sprayed coatings and thermal cycling behavior were characterized, and U-Zr melt interaction studies were carried out. The TaC and Y2O3 coating layers had a uniform thickness, and high density with only a few small closed pores showing good consolidation, while the ZrC, TiC, and ZrO2 coatings were not well consolidated with a considerable amount of porosity. Thermal cycling tests showed that the adhesion of the TiC, ZrC, and ZrO2 coating layers with niobium was relatively weak compared to the TaC and Y2O3 coatings. The TaC and Y2O3 coatings had better cycling characteristics with no interconnected cracks. In the interaction studies, ZrC and ZrO2 coated rods showed significant degradations after exposure to U-10 wt.% Zr melt at 1600°C for 15 min., but TaC, TiC, and Y2O3 coatings showed good compatibility with U-Zr melt.

Potato Starch/Montmorillonite-Based Nanocomposites: Water Sensitivity, Mechanical and Thermal Properties and XRD Profile Study

Directory of Open Access Journals (Sweden)

Ronak Gholami

2013-06-01

Full Text Available Studies were carried out on the effect of adding different percentages of montmorillonite (3, 5, 7 and 9% of starch weight on the physical properties of potato starch-MMT nanocomposites. Heat resistance and mechanical properties of films were measured by differential scanning calorimetry (DSC and tensile test. Nanoparticles distribution in polymer matrix was investigated using X-ray diffraction test (XRD. For investigation of water vapor resistance of film samples, moisture sorption and water vapor permeability (WVP were measured. The results showed that the distribution of nanoparticles in the polymer matrix was exfoliated. WVP in pure starch films was 2.62×10-7 g/mhPa and with the addition of 9% MMT it was reduced to 1.43×10-7 g/mhPa. With the addition of nanoclay from zero to 9%, the ultimate tensile strength of nanocomposite samples was increased from 5.9 to 6.63 MPa and strain-to-break was decreased from 34.82 to 26.83%. But the rising trend was not significant for nanocomposite samples containing low concentrations of nanoclay (0-7%. The main reasons for the enhancement of mechanical properties due to the addition of nanoclay were to establish hydrogen bonding between polymer chains and clay layers, filling the empty spaces and increase the crystalline domains. Investigation of thermal resistance of nanocomposite samples showed that they have higher thermal resistance and melting point in comparison with pure starch films. With the addition of nanoclay from zero to 9%, the melting point of film samples was increased from 218 to 232.1°C. With the addition of nanoclay, probably the mobility of amylopectin chains decreased and crystalline domains increased. Also, with increasing nanoclay content, the glass transition temperature of nanocomposite samples was increased. This result corresponded to shrinkage in free volume and thus reduction in the polymer chains mobility in amorphous regions.

Permeability and 3-D melt geometry in shear-induced high melt fraction conduits

Science.gov (United States)

Zhu, W.; Cordonnier, B.; Qi, C.; Kohlstedt, D. L.

2017-12-01

Observations of dunite channels in ophiolites and uranium-series disequilibria in mid-ocean ridge basalt suggest that melt transport in the upper mantle beneath mid-ocean ridges is strongly channelized. Formation of high melt fraction conduits could result from mechanical shear, pyroxene dissolution, and lithological partitioning. Deformation experiments (e.g. Holtzman et al., 2003) demonstrate that shear stress causes initially homogeneously distributed melt to segregate into an array of melt-rich bands, flanked by melt-depleted regions. At the same average melt fraction, the permeability of high melt fraction conduits could be orders of magnitude higher than that of their homogenous counterparts. However, it is difficult to determine the permeability of melt-rich bands. Using X-ray synchrotron microtomography, we obtained high-resolution images of 3-dimensional (3-D) melt distribution in a partially molten rock containing shear-induced high melt fraction conduits. Sample CQ0705, an olivine-alkali basalt aggregate with a nominal melt fraction of 4%, was deformed in torsion at a temperature of 1473 K and a confining pressure of 300 MPa to a shear strain of 13.3. A sub-volume of CQ0705 encompassing 3-4 melt-rich bands was imaged. Microtomography data were reduced to binary form so that solid olivine is distinguishable from basalt glass. At a spatial resolution of 160 nm, the 3-D images reveal the shape and connectedness of melt pockets in the melt-rich bands. Thin melt channels formed at grain edges are connected at large melt nodes at grain corners. Initial data analysis shows a clear preferred orientation of melt pockets alignment subparallel to the melt-rich band. We use the experimentally determined geometrical parameters of melt topology to create a digital rock with identical 3-D microstructures. Stokes flow simulations are conducted on the digital rock to obtain the permeability tensor. Using this digital rock physics approach, we determine how deformation

Thermal Characterization of Lauric-Stearic Acid/Expanded Graphite Eutectic Mixture as Phase Change Materials.

Science.gov (United States)

Zhu, Hua; Zhang, Peng; Meng, Zhaonan; Li, Ming

2015-04-01

The eutectic mixture of lauric acid (LA) and stearic acid (SA) is a desirable phase change material (PCM) due to the constant melting temperature and large latent heat. However, its poor thermal conductivity has hampered its broad utilization. In the present study, pure LA, SA and the mixtures with various mass fractions of LA-SA were used as the basic PCMs, and 10 wt% expanded graphite (EG) was added to enhance the thermal conductivities. The phase change behaviors, microstructural analysis, thermal conductivities and thermal stabilities of the mixtures of PCMs were investigated by differential scanning calorimetry (DSC), scanning electronic microscope (SEM), transient plane source (TPS) and thermogravimetric analysis (TGA), respectively. The results show that the LA-SA binary mixture of mixture ratio of 76.3 wt%: 23.7 wt% forms an eutectic mixture, which melts at 38.99 °C and has a latent heat of 159.94 J/g. The melted fatty acids are well absorbed by the porous network of EG and they have a good thermal stability. Furthermore, poor thermal conductivities can be well enhanced by the addition of EG.

Three-dimensional model of heat transport during In Situ Vitrification with melting and cool down

International Nuclear Information System (INIS)

Hawkes, G.L.

1993-01-01

A potential technology for permanent remediation of buried wastes is the In Situ Vitrification (ISV) process. This process uses electrical resistance heating to melt waste and contaminated soil in place to produce a durable, glasslike material that encapsulates and immobilizes buried wastes. The magnitude of the resulting electrical resistance heating is sufficient to cause soil melting. As the molten region grows, surface heat losses cause the soil near the surface to re solidify. This paper presents numerical results obtained by considering heat transport and melting when solving the conservation of mass and energy equations using finite element methods. A local heat source is calculated by solving the electric field equation and calculating a Joule Heat source term. The model considered is a three-dimensional model of the electrodes and surrounding soil. Also included in the model is subsidence; where the surface of the melted soil subsides due to the change in density when the soil melts. A power vs. time profile is implemented for typical ISV experiments. The model agrees well with experimental data for melt volume and melt shape

Determining the effects of thermal conductivity on epoxy molds using profiled cooling channels with metal inserts

International Nuclear Information System (INIS)

Altaf, Khurram; Rani, Abdul Ahmad Majdi; Ahmad, Faiz; Baharom, Masri; Raghavan, Vijay R.

2016-01-01

Polymer injection molds are generally manufactured with metallic materials, such as tool steel, which provide reliable working of molds and extended service life. The manufacture of injection molds with steel is a prolonged process because of the strength of steel. For a short prototype production run, one of the suitable choices could be the use of aluminum-filled epoxy material, which can produce a functional mold in a short time as compared with a conventionally machined tool. Aluminum-filled epoxy tooling is a good choice for short production runs for engineering applications, yet works best for relatively simple shapes. The advantages in relation to the fabrication of injection molds with epoxy-based materials include time saving in producing the mold, epoxy curing at ambient temperature, and ease of machining and post processing. Nevertheless, one major drawback of epoxy material is its poor thermal conductivity, which results in a relatively longer cooling time for epoxy injection molds. This study investigates some of the innovative ideas for enhancing the thermal conductivity for epoxy molds. The basic concept behind these ideas was to embed a highly thermally conductive metal insert within the mold between cavities with an innovative design of cooling channels called profiled cooling channels. This technique will increase the effective thermal conductivity of the epoxy mold, leading to the reduction in cooling time for the injection molded polymer part. Experimental analysis conducted in the current study also verified that the mold with profiled cooling channels and embedded metal insert has significantly reduced the cooling time

Determining the effects of thermal conductivity on epoxy molds using profiled cooling channels with metal inserts

Energy Technology Data Exchange (ETDEWEB)

Altaf, Khurram; Rani, Abdul Ahmad Majdi; Ahmad, Faiz; Baharom, Masri [Mechanical Engineering Dept., Universiti Teknologi PETRONAS, Bandar Seri Iskandar, Perak (Malaysia); Raghavan, Vijay R. [OYL Manufacturing, Sungai Buloh (Malaysia)

2016-11-15

Polymer injection molds are generally manufactured with metallic materials, such as tool steel, which provide reliable working of molds and extended service life. The manufacture of injection molds with steel is a prolonged process because of the strength of steel. For a short prototype production run, one of the suitable choices could be the use of aluminum-filled epoxy material, which can produce a functional mold in a short time as compared with a conventionally machined tool. Aluminum-filled epoxy tooling is a good choice for short production runs for engineering applications, yet works best for relatively simple shapes. The advantages in relation to the fabrication of injection molds with epoxy-based materials include time saving in producing the mold, epoxy curing at ambient temperature, and ease of machining and post processing. Nevertheless, one major drawback of epoxy material is its poor thermal conductivity, which results in a relatively longer cooling time for epoxy injection molds. This study investigates some of the innovative ideas for enhancing the thermal conductivity for epoxy molds. The basic concept behind these ideas was to embed a highly thermally conductive metal insert within the mold between cavities with an innovative design of cooling channels called profiled cooling channels. This technique will increase the effective thermal conductivity of the epoxy mold, leading to the reduction in cooling time for the injection molded polymer part. Experimental analysis conducted in the current study also verified that the mold with profiled cooling channels and embedded metal insert has significantly reduced the cooling time.

Transient Thermal State of an Active Braille Matrix with Incorporated Thermal Actuators by Means of Finite Element Method

Science.gov (United States)

Alutei, Alexandra-Maria; Szelitzky, Emoke; Mandru, Dan

2013-01-01

In this article the authors present the transient thermal analysis for a developed thermal linear actuator based on wax paraffin used to drive the cells of a Braille device. A numerical investigation of transient heat transfer phenomenon during paraffin melting and solidification in an encapsulated recipient has been carried out using the ANSYS…

Numerical analysis of the heating phase and densification mechanism in polymers selective laser melting process

Science.gov (United States)

Mokrane, Aoulaiche; Boutaous, M'hamed; Xin, Shihe

2018-05-01

The aim of this work is to address a modeling of the SLS process at the scale of the part in PA12 polymer powder bed. The powder bed is considered as a continuous medium with homogenized properties, meanwhile understanding multiple physical phenomena occurring during the process and studying the influence of process parameters on the quality of final product. A thermal model, based on enthalpy approach, will be presented with details on the multiphysical couplings that allow the thermal history: laser absorption, melting, coalescence, densification, volume shrinkage and on numerical implementation using FV method. The simulations were carried out in 3D with an in-house developed FORTRAN code. After validation of the model with comparison to results from literature, a parametric analysis will be proposed. Some original results as densification process and the thermal history with the evolution of the material, from the granular solid state to homogeneous melted state will be discussed with regards to the involved physical phenomena.

Effects of Melt Processing on Evolution of Structure in PEEK

Science.gov (United States)

Georgiev, Georgi; Dai, Patrick Shuanghua; Oyebode, Elizabeth; Cebe, Peggy; Capel, Malcolm

1999-01-01

We report on the effects of melt processing temperature on structure formation in Poly(ether-ether-ketone), PEEK. Real time Small Angle X-ray Scattering, SAXS, and thermal analysis are used to follow the melting behavior after various stages of processing. Assignment of peaks to structural entities within the material, the relative perfection of the crystals, and the possibility of their reorganization, are all influenced by the melt processing history. With the advent of high intensity synchrotron sources of X-radiation, polymer scientists gain a research tool which, when used along with thermal analysis, provides additional structural information about the crystals during growth and subsequent melting. PEEK is an engineering thermoplastic polymer with a very high glass transition temperature (145 C) and crystal melting point (337 C). PEEK has been the subject of recent studies by X-ray scattering in which melt and cold crystallization were followed in real-time. X-ray scattering and thermal studies have been used to address the formation of dual endothermic response which has been variously ascribed to lamellar insertion, dual crystal populations, or melting followed by re-crystallization. Another important issue is whether all of the amorphous phase is located in interlamellar regions, or alternatively whether some is located in "pockets" away from the crystalline lamellar stacks. The interpretation of scattering from lamellar stacks varies depending upon whether such amorphous pockets are formed. Some groups believe all of the amorphous phase is interlamellar. This leads to selection of a smaller thickness for the crystals. Other groups suggest that most amorphous phase is not interlamellar, and this leads to the suggestion that the crystal thickness is larger than the amorphous layer within the stacks. To investigate these ideas, we used SAXS and Differential Scanning Calorimetry to compare results of single and dual stage melt crystallization of PEEK using a

Melting point of polymers under high pressure Part I: Influence of the polymer properties

International Nuclear Information System (INIS)

Seeger, Andreas; Freitag, Detlef; Freidel, Frank; Luft, Gerhard

2004-01-01

The pressure dependence of the melting point of various polymers including homo- and copolymers (HDPE, LDPE, PP and ethylene vinyl acetate copolymers (EVA)) was investigated under nitrogen atmosphere up to 330 MPa within a high pressure differential thermal analysis cell designed by our group. The properties of the polymers (vinylacetate content, melt flow index, molecular weight, isotactic index, crystallinity, density, and frequency of branching) have been correlated with the change of the melting point under pressure (dT m /dp). It could be shown that the melting point always increases linearly with pressure up to 330 MPa. The pressure dependence was found to be in the range of 11-17 K/(100 MPa). From these results it is possible to approximate dT m /dp using the enthalpy of fusion of the polymers at ambient pressure

Thermal decomposition of barium valerate in argon

DEFF Research Database (Denmark)

Torres, P.; Norby, Poul; Grivel, Jean-Claude

2015-01-01

The thermal decomposition of barium valerate (Ba(C4H9CO2)(2)/Ba-pentanoate) was studied in argon by means of thermogravimetry, differential thermal analysis, IR-spectroscopy, X-ray diffraction and hot-stage optical microscopy. Melting takes place in two different steps, at 200 degrees C and 280...

Shear melting and high temperature embrittlement: theory and application to machining titanium.

Science.gov (United States)

Healy, Con; Koch, Sascha; Siemers, Carsten; Mukherji, Debashis; Ackland, Graeme J

2015-04-24

We describe a dynamical phase transition occurring within a shear band at high temperature and under extremely high shear rates. With increasing temperature, dislocation deformation and grain boundary sliding are supplanted by amorphization in a highly localized nanoscale band, which allows for massive strain and fracture. The mechanism is similar to shear melting and leads to liquid metal embrittlement at high temperature. From simulation, we find that the necessary conditions are lack of dislocation slip systems, low thermal conduction, and temperature near the melting point. The first two are exhibited by bcc titanium alloys, and we show that the final one can be achieved experimentally by adding low-melting-point elements: specifically, we use insoluble rare earth metals (REMs). Under high shear, the REM becomes mixed with the titanium, lowering the melting point within the shear band and triggering the shear-melting transition. This in turn generates heat which remains localized in the shear band due to poor heat conduction. The material fractures along the shear band. We show how to utilize this transition in the creation of new titanium-based alloys with improved machinability.

The dry-heat loss effect of melt-spun phase change material fibres.

Science.gov (United States)

Tjønnås, Maria Suong; Færevik, Hilde; Sandsund, Mariann; Reinertsen, Randi E

2015-01-01

Phase change materials (PCM) have the ability to store latent heat when they change phases, a property that gives clothing that incorporates PCM its cooling effect. This study investigated the effect of dry-heat loss (cooling) of a novel melt-spun PCM fibre on the basis of the area covered, mass, the latent heat of fusion and melting temperature, compared to a known PCM clothing product. PCM fibres with melting temperatures of 28.4 and 32.0°C and PCM packs with melting temperatures of 28.0 and 32.0°C were studied. The results showed that the PCM fibres had a larger initial peak cooling effect than that of the PCM packs. The duration of the cooling effect of PCM fibres was primarily dependent on the PCM mass and the latent heat of fusion capacity, and secondly on the covered area and melting temperature of the PCM. This study investigates the cooling effect of PCM fibres on a thermal manikin. The PCM fibres had a high but short-lasting cooling effect. This study contributes to the knowledge of how the body's temperature regulation may be affected by the cooling properties of clothing that incorporates PCM.

Synthesis and melting behaviour of Bi, Sn and Sn–Bi nanostructured alloy

Energy Technology Data Exchange (ETDEWEB)

Frongia, F.; Pilloni, M.; Scano, A.; Ardu, A.; Cannas, C.; Musinu, A. [Università di Cagliari, Dipartimento di Scienze Chimiche e Geologiche and Cagliari Research Unit of the National Consortium of Materials Science and Technology (INSTM), Cittadella Universitaria di Monserrato, 09042 Monserrato, CA (Italy); Borzone, G.; Delsante, S. [Department of Chemistry and Industrial Chemistry, Genoa University and Genoa Research Unit of the National Consortium of Materials Science and Technology (INSTM), Via Dodecaneso 31, I-16146 Genoa (Italy); Novakovic, R. [National Research Council (CNR), Institute for Energetics and Interphases (IENI), Via De Marini 6, 16149 Genoa (Italy); Ennas, G., E-mail: ennas@unica.it [Università di Cagliari, Dipartimento di Scienze Chimiche e Geologiche and Cagliari Research Unit of the National Consortium of Materials Science and Technology (INSTM), Cittadella Universitaria di Monserrato, 09042 Monserrato, CA (Italy)

2015-02-25

Highlights: • Aqueous solution route is used to produce Bi, Sn and Bi–Sn nanoparticles. • HRTEM revealed core–shell and Janus type structures of Bi–Sn nanoparticles. • Melting temperature depression of Bi and Bi–Sn nanoparticles were measured by DSC. • DSC data on Bi melting temperature depression agrees with theoretical values. - Abstract: Lead-free solders based on Bi–Sn bimetallic nanoclusters with eutectic composition (Bi{sub 43}Sn{sub 57}) were synthesized at low temperature by simultaneous reduction reaction from aqueous solution containing bismuth and tin chlorides, using potassium borohydride as a reducing agent. By the same processing route, pure bismuth and tin nanoparticles have also been prepared. Microstructure, morphology and composition of the samples were characterized by X-ray powder diffraction (XRD), transmission (TEM) and scanning electron microscopy (SEM). TEM images of Bi–Sn nanoparticles show average size ranging from 30 to 100 nm. Thermal behaviour of Bi–Sn nanopowders was studied by DSC (differential scanning calorimetry) and a melting temperature (135 °C) lower than that of the corresponding microcrystalline sample (139 °C) was observed. SEM micrographs of the thermally treated sample up to 400 °C show fine spherical grains in the micrometer range with finer powder particles on the surface. XRD powder diffraction analysis indicates the formation of bismuth and tin nanophases with an average particle size of 85 and 126 nm, respectively. The oxidation behaviour of the samples was also investigated. The results obtained have been analyzed in view of theoretical models describing the melting temperature depression of nanoparticles.

Thermal stability of carbon nanotubes probed by anchored tungsten nanoparticles

Directory of Open Access Journals (Sweden)

Xianlong Wei, Ming-Sheng Wang, Yoshio Bando and Dmitri Golberg

2011-01-01

Full Text Available The thermal stability of multiwalled carbon nanotubes (CNTs was studied in high vacuum using tungsten nanoparticles as miniaturized thermal probes. The particles were placed on CNTs inside a high-resolution transmission electron microscope equipped with a scanning tunneling microscope unit. The setup allowed manipulating individual nanoparticles and heating individual CNTs by applying current to them. CNTs were found to withstand high temperatures, up to the melting point of 60-nm-diameter W particles (~3400 K. The dynamics of W particles on a hot CNT, including particle crystallization, quasimelting, melting, sublimation and intradiffusion, were observed in real time and recorded as a video. Graphite layers reel off CNTs when melted or premelted W particles revolve along the tube axis.

Catalogue of generic plant states leading to core melt in PWRs: includes appendix 1: detailed description of sequences leading to core melt

International Nuclear Information System (INIS)

1996-11-01

The Task Group on thermal-hydraulic system behaviour was given a mandate from PWG 2 on Coolant System-Behaviour with the approval of CSNI to deal with the topic of Accident Management. A writing group was set up to identify generic plant states leading to core melt for pressurized water reactors (PWR) and find 'possible approaches to accident management measures' (AM-Measures) for dealing with them. From a matrix of 15 initiating events and 12 system failures (i.e. from 180 possibilities), 32 event sequences have been identified as leading to core melt. Each sequence has been divided into characteristic plant state intervals according to safety function challenges. For each of the 141 defined characteristic plant state intervals, the members of the Writing Group made proposals for AM-Measures

Modelling of pulsed electron beam induced graphite ablation: Sublimation versus melting

Science.gov (United States)

Ali, Muddassir; Henda, Redhouane

2017-12-01

Pulsed electron beam ablation (PEBA) has recently emerged as a very promising technique for the deposition of thin films with superior properties. Interaction of the pulsed electron beam with the target material is a complex process, which consists of heating, phase transition, and erosion of a small portion from the target surface. Ablation can be significantly affected by the nature of thermal phenomena taking place at the target surface, with subsequent bearing on the properties, stoichiometry and structure of deposited thin films. A two stage, one-dimensional heat conduction model is presented to describe two different thermal phenomena accounting for interaction of a graphite target with a polyenergetic electron beam. In the first instance, the thermal phenomena are comprised of heating, melting and vaporization of the target surface, while in the second instance the thermal phenomena are described in terms of heating and sublimation of the graphite surface. In this work, the electron beam delivers intense electron pulses of ∼100 ns with energies up to 16 keV and an electric current of ∼400 A to a graphite target. The temperature distribution, surface recession velocity, ablated mass per unit area, and ablation depth for the graphite target are numerically simulated by the finite element method for each case. Based on calculation findings and available experimental data, ablation appears to occur mainly in the regime of melting and vaporization from the surface.

High throughput integrated thermal characterization with non-contact optical calorimetry

Science.gov (United States)

Hou, Sichao; Huo, Ruiqing; Su, Ming

2017-10-01

Commonly used thermal analysis tools such as calorimeter and thermal conductivity meter are separated instruments and limited by low throughput, where only one sample is examined each time. This work reports an infrared based optical calorimetry with its theoretical foundation, which is able to provide an integrated solution to characterize thermal properties of materials with high throughput. By taking time domain temperature information of spatially distributed samples, this method allows a single device (infrared camera) to determine the thermal properties of both phase change systems (melting temperature and latent heat of fusion) and non-phase change systems (thermal conductivity and heat capacity). This method further allows these thermal properties of multiple samples to be determined rapidly, remotely, and simultaneously. In this proof-of-concept experiment, the thermal properties of a panel of 16 samples including melting temperatures, latent heats of fusion, heat capacities, and thermal conductivities have been determined in 2 min with high accuracy. Given the high thermal, spatial, and temporal resolutions of the advanced infrared camera, this method has the potential to revolutionize the thermal characterization of materials by providing an integrated solution with high throughput, high sensitivity, and short analysis time.

Synthesis of condensed double rubidium manganese phosphates in melts of polyphosphoric acids

International Nuclear Information System (INIS)

Guzeeva, L.S.; Tananaev, I.V.

1988-01-01

The aim of this work was to study the character of the reaction of MnO 2 and Rb 2 O with melts of polyphosphoric acids, and to establish the composition and the conditions of formation of the condensed double rubidium manganese phosphates. In the reaction of manganese and rubidium oxides with melts of polyphosphoric acids at 140-350 degree C, three types of trivalent manganese and rubidium condensed double phosphates are formed - diphosphates RbMn(H 2 P 2 O 7 ) and Rb 2 MnH 3 (P 2 O 7 ) 2 , triphosphate RbMnHP 3 O 10 and diphosphate RbMnP 2 O 7 - in addition to a double cyclotriphosphate of divalent manganese with rubidium RbMnP 3 O 9 . The thermal transformations of the compound isolated were studied. It was shown that rubidium manganese cyclotriphosphate can be obtained by the thermal decomposition of the diphosphate RbMn(H 2 P 2 O 7 ) 2

Preparation and properties of novel melt-blended halloysite nanotubes/wheat starch nanocomposites.

Science.gov (United States)

Schmitt, H; Prashantha, K; Soulestin, J; Lacrampe, M F; Krawczak, P

2012-07-01

Novel bionanocomposites based on halloysite nanotubes as nanofillers and plasticized starch as polymeric matrix were successfully prepared by melt-extrusion for the first time. Both modified and non modified halloysites were added at different weight contents. The structural, morphological, thermal and mechanical properties of plasticized starch/halloysites nanocomposites were investigated. Melt-compounding appears to be a suitable process to uniformly disperse nanotubes in the plasticized starch matrix. Interactions between plasticized starch and halloysites in the nanocomposites and microstructure modifications were monitored using Fourier transfer infrared spectroscopy, X-ray diffraction and dynamic mechanical analysis. Addition of halloysite nanotubes slightly enhances the thermal stability of starch (onset temperature of degradation delayed to higher temperatures). The tensile mechanical properties of starch are also significantly improved (up to +144% for Young's modulus and up to +29% for strength) upon addition of both modified and unmodified halloysites, interestingly without loss of ductility. Modified halloysites lead to significantly higher Young's modulus than unmodified halloysites. Copyright © 2012 Elsevier Ltd. All rights reserved.

Geotechnical modeling of high-level nuclear waste disposal by rock melting

International Nuclear Information System (INIS)

Heuze, F.E.

1981-12-01

A new strategy has been developed for the geotechnical modeling of nuclear waste disposal by rock melting (DRM). Three seeparate tasks were performed to reach this objective: a review of the four scenarios which have been proposed for DRM, to date; an evaluation of computer-based numerical models which could be used to analyze the mechanical, thermal, and hydraulic processes involved in DRM; and a critical review of rock mass properties which are relevant to the design and safety of waste disposal by rock melting. It is concluded that several geotechnical aspects of DRM can be studied realistically with current state-of-the-art model capabilities and knowledge of material properties. The next step in the feasibility study of DRM should be a best-estimate calculation of the four cavity-melt and canister-burial concepts. These new analyses will indicate the most critical areas for subsequent research

Development of foams from linear polypropylene (PP) and high melt strength polypropylene (HMSPP) polymeric blends

International Nuclear Information System (INIS)

Cardoso, Elisabeth Carvalho Leite

2009-01-01

Foamed polymers are future materials, with a comprehensive application field. They can be used in order to improve appearance of insulation structures, for example, or to reduce costs involving materials. This work address to Isotactic Polypropylene / High Melt Strength Polypropylene blends, for foams production. Rheological behavior of polymer melt, especially referring to viscosity in processing temperature, plays a decisive role in applications where dominates extensional flow, as in case of foaming. If the viscosity is very low, it will correspond to a low melt strength, as in case of linear homopolymer (Isotact PP), and the foam will be prejudiced, due to the impossibility of expansion. Otherwise, if the viscosity is very high, with a high melt strength, the foam will collapse immediately after its formation. In order to get foams with an homogeneous and defined cellular structure, there were accomplished blends, 50% in weight, between linear homopolymer (isotactic PP) and HMSPP, from PP modified as per gamma radiation, in acetylene environment and at a 12.5 kGy doses. Extrusion process used a soluble foaming methodology, according to a processing/dissolution principle, which involves the dissolution of a Physical Blowing Agent (PBA), under 30 bar pressure, homogeneously mixed with polymeric melt. Extrusion conditions, that generally involve temperature, pressure and viscoelastic material flow control were experimentally investigated to define prevalent characteristics for producing foams. Nitrogen was the used PBA and process extrusion parameters were adapted to PP, HMSPP and their 50% in weight mixtures thereof. Major PP and HMSPP characteristics were obtained via melt Index and melt strength and thermal analyses (DSC/TGA), in order to make viable and to reproduce foaming as per extrusion process. Foams cellular morphology of PP, HMSPP and their 50% in weight mixtures thereof was investigated, with and without talc addition, as nucleating agent, by using

Miscibility gap alloys with inverse microstructures and high thermal conductivity for high energy density thermal storage applications

International Nuclear Information System (INIS)

Sugo, Heber; Kisi, Erich; Cuskelly, Dylan

2013-01-01

New high energy-density thermal storage materials are proposed which use miscibility gap binary alloy systems to operate through the latent heat of fusion of one component dispersed in a thermodynamically stable matrix. Using trial systems Al–Sn and Fe–Cu, we demonstrate the development of the required inverse microstructure (low melting point phase embedded in high melting point matrix) and excellent thermal storage potential. Several other candidate systems are discussed. It is argued that such systems offer enhancement over conventional phase change thermal storage by using high thermal conductivity microstructures (50–400 W/m K); minimum volume of storage systems due to high energy density latent heat of fusion materials (0.2–2.2 MJ/L); and technical utility through adaptability to a great variety of end uses. Low (<300 °C), mid (300–400 °C) and high (600–1400 °C) temperature options exist for applications ranging from space heating and process drying to concentrated solar thermal energy conversion and waste heat recovery. -- Highlights: ► Alloys of immiscible metals are proposed as thermal storage systems. ► High latent heat of fusion per unit volume and tunable temperature are advantageous. ► Thermal storage systems with capacities of 0.2–2.2 MJ/L are identified. ► Heat delivery is via a rigid non-reactive high thermal conductivity matrix. ► The required inverse microstructures were developed for Sn–Al and Cu–Fe systems

Thermal Properties of Aliphatic Polypeptoids

KAUST Repository

Fetsch, Corinna; Luxenhofer, Robert

2013-01-01

A series of polypeptoid homopolymers bearing short (C1-C5) side chains of degrees of polymerization of 10-100 are studied with respect to thermal stability, glass transition and melting points. Thermogravimetric analysis of polypeptoids suggests

Dietary live yeast alters metabolic profiles, protein biosynthesis and thermal stress tolerance of Drosophila melanogaster.

Science.gov (United States)

Colinet, Hervé; Renault, David

2014-04-01

The impact of nutritional factors on insect's life-history traits such as reproduction and lifespan has been excessively examined; however, nutritional determinant of insect's thermal tolerance has not received a lot of attention. Dietary live yeast represents a prominent source of proteins and amino acids for laboratory-reared drosophilids. In this study, Drosophila melanogaster adults were fed on diets supplemented or not with live yeast. We hypothesized that manipulating nutritional conditions through live yeast supplementation would translate into altered physiology and stress tolerance. We verified how live yeast supplementation affected body mass characteristics, total lipids and proteins, metabolic profiles and cold tolerance (acute and chronic stress). Females fed with live yeast had increased body mass and contained more lipids and proteins. Using GC/MS profiling, we found distinct metabolic fingerprints according to nutritional conditions. Metabolite pathway enrichment analysis corroborated that live yeast supplementation was associated with amino acid and protein biosyntheses. The cold assays revealed that the presence of dietary live yeast greatly promoted cold tolerance. Hence, this study conclusively demonstrates a significant interaction between nutritional conditions and thermal tolerance. Copyright © 2014 Elsevier Inc. All rights reserved.

Characterisation of Ceramic-Coated 316LN Stainless Steel Exposed to High-Temperature Thermite Melt and Molten Sodium

Science.gov (United States)

Ravi Shankar, A.; Vetrivendan, E.; Shukla, Prabhat Kumar; Das, Sanjay Kumar; Hemanth Rao, E.; Murthy, S. S.; Lydia, G.; Nashine, B. K.; Mallika, C.; Selvaraj, P.; Kamachi Mudali, U.

2017-11-01

Currently, stainless steel grade 316LN is the material of construction widely used for core catcher of sodium-cooled fast reactors. Design philosophy for core catcher demands its capability to withstand corium loading from whole core melt accidents. Towards this, two ceramic coatings were investigated for its application as a layer of sacrificial material on the top of core catcher to enhance its capability. Plasma-sprayed thermal barrier layer of alumina and partially stabilised zirconia (PSZ) with an intermediate bond coat of NiCrAlY are selected as candidate material and deposited over 316LN SS substrates and were tested for their suitability as thermal barrier layer for core catcher. Coated specimens were exposed to high-temperature thermite melt to simulate impingement of molten corium. Sodium compatibility of alumina and PSZ coatings were also investigated by exposing samples to molten sodium at 400 °C for 500 h. The surface morphology of high-temperature thermite melt-exposed samples and sodium-exposed samples was examined using scanning electron microscope. Phase identification of the exposed samples was carried out by x-ray diffraction technique. Observation from sodium exposure tests indicated that alumina coating offers better protection compared to PSZ coating. However, PSZ coating provided better protection against high-temperature melt exposure, as confirmed during thermite melt exposure test.

Thermal decomposition of yttrium(III) valerate in argon

DEFF Research Database (Denmark)

Grivel, Jean-Claude; Yue, Zhao; Tang, Xiao

2014-01-01

The thermal decomposition of yttrium(III) valerate (Y(C4H9CO2)3) was studied in argon by means of thermogravimetry, differential thermal analysis, IR-spectroscopy, X-ray diffraction, in-situ synchrotron diffraction and hot-stage microscopy as well as room temperature optical microscopy. Melting...

Lattice stability and high-pressure melting mechanism of dense hydrogen up to 1.5 TPa

KAUST Repository

Geng, Hua Y.

2015-09-01

© 2015 American Physical Society. Lattice stability and metastability, as well as melting, are important features of the physics and chemistry of dense hydrogen. Using ab initio molecular dynamics (AIMD), the classical superheating limit and melting line of metallic hydrogen are investigated up to 1.5 TPa. The computations show that the classical superheating degree is about 100 K, and the classical melting curve becomes flat at a level of 350 K when beyond 500 GPa. This information allows us to estimate the well depth and the potential barriers that must be overcome when the crystal melts. Inclusion of nuclear quantum effects (NQE) using path integral molecular dynamics (PIMD) predicts that both superheating limit and melting temperature are lowered to below room temperature, but the latter never reaches absolute zero. Detailed analysis indicates that the melting is thermally activated, rather than driven by pure zero-point motion (ZPM). This argument was further supported by extensive PIMD simulations, demonstrating the stability of Fddd structure against liquefaction at low temperatures.

Analysis of the Tikhonov regularization to retrieve thermal conductivity depth-profiles from infrared thermography data

Science.gov (United States)

Apiñaniz, Estibaliz; Mendioroz, Arantza; Salazar, Agustín; Celorrio, Ricardo

2010-09-01

We analyze the ability of the Tikhonov regularization to retrieve different shapes of in-depth thermal conductivity profiles, usually encountered in hardened materials, from surface temperature data. Exponential, oscillating, and sigmoidal profiles are studied. By performing theoretical experiments with added white noises, the influence of the order of the Tikhonov functional and of the parameters that need to be tuned to carry out the inversion are investigated. The analysis shows that the Tikhonov regularization is very well suited to reconstruct smooth profiles but fails when the conductivity exhibits steep slopes. We check a natural alternative regularization, the total variation functional, which gives much better results for sigmoidal profiles. Accordingly, a strategy to deal with real data is proposed in which we introduce this total variation regularization. This regularization is applied to the inversion of real data corresponding to a case hardened AISI1018 steel plate, giving much better anticorrelation of the retrieved conductivity with microindentation test data than the Tikhonov regularization. The results suggest that this is a promising way to improve the reliability of local inversion methods.

Form-stable paraffin/high density polyethylene composites as solid-liquid phase change material for thermal energy storage: preparation and thermal properties

International Nuclear Information System (INIS)

Sari, Ahmet

2004-01-01

This paper deals with the preparation of paraffin/high density polyethylene (HDPE) composites as form-stable, solid-liquid phase change material (PCM) for thermal energy storage and with determination of their thermal properties. In such a composite, the paraffin (P) serves as a latent heat storage material and the HDPE acts as a supporting material, which prevents leakage of the melted paraffin because of providing structural strength. Therefore, it is named form-stable composite PCM. In this study, two kinds of paraffins with melting temperatures of 42-44 deg. C (type P1) and 56-58 deg. C (type P2) and latent heats of 192.8 and 212.4 J g -1 were used. The maximum weight percentage for both paraffin types in the PCM composites without any seepage of the paraffin in the melted state were found as high as 77%. It is observed that the paraffin is dispersed into the network of the solid HDPE by investigation of the structure of the composite PCMs using a scanning electronic microscope (SEM). The melting temperatures and latent heats of the form-stable P1/HDPE and P2/HDPE composite PCMs were determined as 37.8 and 55.7 deg. C, and 147.6 and 162.2 J g -1 , respectively, by the technique of differential scanning calorimetry (DSC). Furthermore, to improve the thermal conductivity of the form-stable P/HDPE composite PCMs, expanded and exfoliated graphite (EG) by heat treatment was added to the samples in the ratio of 3 wt.%. Thereby, the thermal conductivity was increased about 14% for the form-stable P1/HDPE and about 24% for the P2/HDPE composite PCMs. Based on the results, it is concluded that the prepared form-stable P/HDPE blends as composite type PCM have great potential for thermal energy storage applications in terms of their satisfactory thermal properties and improved thermal conductivity. Furthermore, these composite PCMs added with EG can be considered cost effective latent heat storage materials since they do not require encapsulation and extra cost to enhance

Tracking the course of the manufacturing process in selective laser melting

Science.gov (United States)

Thombansen, U.; Gatej, A.; Pereira, M.

2014-02-01

An innovative optical train for a selective laser melting based manufacturing system (SLM) has been designed under the objective to track the course of the SLM process. In this, the thermal emission from the melt pool and the geometric properties of the interaction zone are addressed by applying a pyrometer and a camera system respectively. The optical system is designed such that all three radiations from processing laser, thermal emission and camera image are coupled coaxially and that they propagate on the same optical axis. As standard f-theta lenses for high power applications inevitably lead to aberrations and divergent optical axes for increasing deflection angles in combination with multiple wavelengths, a pre-focus system is used to implement a focusing unit which shapes the beam prior to passing the scanner. The sensor system records synchronously the current position of the laser beam, the current emission from the melt pool and an image of the interaction zone. Acquired data of the thermal emission is being visualized after processing which allows an instant evaluation of the course of the process at any position of each layer. As such, it provides a fully detailed history of the product This basic work realizes a first step towards self-optimization of the manufacturing process by providing information about quality relevant events during manufacture. The deviation from the planned course of the manufacturing process to the actual course of the manufacturing process can be used to adapt the manufacturing strategy from one layer to the next. In the current state, the system can be used to facilitate the setup of the manufacturing system as it allows identification of false machine settings without having to analyze the work piece.

Thermal limiting effects in optical plasmonic waveguides

International Nuclear Information System (INIS)

Ershov, A.E.; Gerasimov, V.S.; Gavrilyuk, A.P.; Karpov, S.V.; Zakomirnyi, V.I.; Rasskazov, I.L.; Polyutov, S.P.

2017-01-01

We have studied thermal effects occurring during excitation of optical plasmonic waveguide (OPW) in the form of linear chain of spherical Ag nanoparticles by pulsed laser radiation. It was shown that heating and subsequent melting of the first irradiated particle in a chain can significantly deteriorate the transmission efficiency of OPW that is the crucial and limiting factor and continuous operation of OPW requires cooling devices. This effect is caused by suppression of particle's surface plasmon resonance due to reaching the melting point temperature. We have determined optimal excitation parameters which do not significantly affect the transmission efficiency of OPW. - Highlights: • The thermodynamic model was developed to study thermal effects at nanoscale. • Developed model considers temperature-dependent permittivity of the nanoparticles. • Thermal effects significantly suppress transmission efficiency of plasmonic chains. • Optimal parameters for stable operation of plasmonic chains were defined.

Energy Savings Through Thermally Efficient Crucible Technology: Fundamentals, Process Modeling, and Applications

Science.gov (United States)

Shi, Wenwu; Pinto, Brian

2017-12-01

Melting and holding molten metals within crucibles accounts for a large portion of total energy demand in the resource-intensive nonferrous foundry industry. Multivariate mathematical modeling aided by detailed material characterization and advancements in crucible technologies can make a significant impact in the areas of cost-efficiency and carbon footprint reduction. Key thermal properties such as conductivity and specific heat capacity were studied to understand their influence on crucible furnace energy consumption during melting and holding processes. The effects of conductivity on thermal stresses and longevity of crucibles were also evaluated. With this information, accurate theoretical models using finite element analysis were developed to study total energy consumption and melting time. By applying these findings to recent crucible developments, considerable improvements in field performance were reported and documented as case studies in applications such as aluminum melting and holding.

In vessel core melt progression phenomena

International Nuclear Information System (INIS)

Courtaud, M.

1993-01-01

For all light water reactor (LWR) accidents, including the so called severe accidents where core melt down can occur, it is necessary to determine the amount and characteristics of fission products released to the environment. For existing reactors this knowledge is used to evaluate the consequences and eventual emergency plans. But for future reactors safety authorities demand decrease risks and reactors designed in such a way that fission products are retained inside the containment, the last protective barrier. This requires improved understanding and knowledge of all accident sequences. In particular it is necessary to be able to describe the very complex phenomena occurring during in vessel core melt progression because they will determine the thermal and mechanical loads on the primary circuit and the timing of its rupture as well as the fission product source term. On the other hand, in case of vessel failure, knowledge of the physical and chemical state of the core melt will provide the initial conditions for analysis of ex-vessel core melt progression and phenomena threatening the containment. Finally a good understanding of in vessel phenomena will help to improve accident management procedures like Emergency Core Cooling System water injection, blowdown and flooding of the vessel well, with their possible adverse effects. Research and Development work on this subject was initiated a long time ago and is still in progress but now it must be intensified in order to meet the safety requirements of the next generation of reactors. Experiments, limited in scale, analysis of the TMI 2 accident which is a unique source of global information and engineering judgment are used to establish and assess physical models that can be implemented in computer codes for reactor accident analysis

The density, compressibility and seismic velocity of hydrous melts at crustal and upper mantle conditions

Science.gov (United States)

Ueki, K.; Iwamori, H.

2015-12-01

Various processes of subduction zone magmatism, such as upward migration of partial melts and fractional crystallization depend on the density of the hydrous silicate melt. The density and the compressibility of the hydrous melt are key factors for the thermodynamic calculation of phase relation of the hydrous melt, and the geophysical inversion to predict physicochemical conditions of the melting region based on the seismic velocity. This study presents a new model for the calculations of the density of the hydrous silicate melts as a function of T, P, H2O content and melt composition. The Birch-Murnaghan equation is used for the equation of state. We compile the experimentally determined densities of various hydrous melts, and optimize the partial molar volume, compressibility, thermal expansibility and its pressure derivative, and K' of the H2O component in the silicate melt. P-T ranges of the calibration database are 0.48-4.29 GPa and 1033-2073 K. As such, this model covers the P-T ranges of the entire melting region of the subduction zone. Parameter set provided by Lange and Carmichael [1990] is used for the partial molar volume and KT value of the anhydrous silicate melt. K' of anhydrous melt is newly parameterized as a function of SiO2 content. The new model accurately reproduces the experimentally determined density variations of various hydrous melts from basalt to rhyolite. Our result shows that the hydrous melt is more compressive and less dense than the anhydrous melt; with the 5 wt% of H2O in melt, density and KT decrease by ~10% and ~30% from those of the anhydrous melt, respectively. For the application of the model, we calculated the P-wave velocity of the hydrous melt. With the 5 wt% of H2O, P-wave velocity of the silicate melt decreases by >10%. Based on the melt P-wave velocity, we demonstrate the effect of the melt H2O content on the seismic velocity of the partially molten zone of the subduction zone.

Experimental and thermodynamic evaluation of the melting behavior of irradiated oxide fuels

International Nuclear Information System (INIS)

Adamson, M.G.; Aitken, E.A.; Caputi, R.W.

1985-01-01

Onset of melting is an important performance limit for irradiated UO 2 and UO 2 -based nuclear reactor fuels. Melting (solidus) temperatures are reasonably well known for starting fuel materials such as UO 2 and (U,PU)O 2 , however the influence of burnup on oxide fuel melting behavior continues to represent an area of considerable uncertainty. In this paper we report the results of a variety of melting temperature measurements on pseudo-binary fuel-fissia mixtures such as UO 2 -PUO 2 , UO 2 -CeO 2 , UO 2 -BaO, UO 2 -SrO, UO 2 -BaZrO 3 and UO 2 -SrZrO 3 . These measurements were performed using the thermal arrest technique on tungsten-encapsulated specimens. Several low melting eutectics, the existence of which had previously been inferred from post-irradiation examinations of high burnup mixed oxide fuels, were characterized in the course of the investigation. Also, an assessment of melting temperature changes in irradiated oxide fuels due to the production and incorporation of soluble oxidic fission products was performed by application of solution theory to the available pseudo-binary phase diagram data. The results of this assessment suggest that depression of oxide fuel solidus temperatures by dissolved fission products is substantially less than that indicated by earlier experimental studies. (orig.)

Thermal properties and stabilities of the eutectic mixture: 1,6-hexanediol/lauric acid as a phase change material for thermal energy storage

International Nuclear Information System (INIS)

Han, Lipeng; Ma, Guixiang; Xie, Shaolei; Sun, Jinhe; Jia, Yongzhong; Jing, Yan

2017-01-01

Highlights: • The eutectic mixture of 1,6-hexanediol/lauric acid was studied as a phase change material. • The mass fraction of 1,6-hexanediol in eutectic point is 70%. • The melting point and latent heat are measured to be 36.92 °C and 177.11 J g −1 . • The eutectic mixture showed good thermal and cyclic stabilities. - Abstract: Thermal properties and stabilities of the eutectic mixture: 1,6-hexanediol (HE) and lauric acid (LA) as a new phase change material (PCM) for latent heat thermal energy storage (TES) were investigated. Differential scanning calorimetry (DSC) results indicated that the aforementioned HE/LA mixture with eutectic composition (70/30 wt.%) was a suitable PCM in terms of melting point (T peak = 36.92 ± 0.71 °C) and latent heat of fusion (ΔH m = 177.11 ± 7.93 J g −1 ). After 1000 thermal cycles, the change in melting point for the eutectic mixture was in the range of −0.49% to −1.19%, and the change in latent heat of fusion was in the range of −0.22% to −3.24%. The eutectic mixture was thermally and chemically stable according to results of thermogravimetric analysis (TGA), volatile test and Fourier Transform Infrared (FT-IR) spectroscopic analysis. Therefore, the HE/LA eutectic mixture is an effective TES material to reduce energy consumption.

Evaluation of Melt Behavior with initial Melt Velocity under SFR Severe Accidents

Energy Technology Data Exchange (ETDEWEB)

Heo, Hyo; Bang, In Cheol [UNIST, Ulsan (Korea, Republic of); Jerng, Dong Wook [Chung-Ang Univ, Seoul (Korea, Republic of)

2015-10-15

In the current Korean sodium-cooled fast reactor (SFR) program, early dispersion of the molten metallic fuel within a subchannel is suggested as one of the inherent safety strategies for the initiating phase of hypothetical core disruptive accident (HCDA). The safety strategy provides negative reactivity driven by the melt dispersal, so it could reduce the possibility of the recriticality event under a severe triple or more fault scenario for SFR. Since the behavior of the melt dispersion is unpredictable, it depends on the accident condition, particularly core region. While the voided coolant channel region is usually developed in the inner core, the unvoided coolant channel region is formed in the outer core. It is important to confirm the fuel dispersion with the core region, but there are not sufficient existing studies for them. From the existing studies, the coolant vapor pressure is considered as one of driving force to move the melt towards outside of the core. There is a complexity of the phenomena during intermixing of the melt with the coolant after the horizontal melt injections. It is too difficult to understand the several combined mechanisms related to the melt dispersion and the fragmentation. Thus, it could be worthwhile to study the horizontal melt injections at lower temperature as a preliminary study in order to identify the melt dispersion phenomena. For this reason, it is required to clarify whether the coolant vapor pressure is the driving force of the melt dispersion with the core region. The specific conditions to be well dispersed for the molten metallic fuel were discussed in the experiments with the simulant materials. The each melt behavior was compared to evaluate the melt dispersion under the coolant void condition and the boiling condition. As the results, the following results are remarked: 1. The upward melt dispersion did not occur for a given melt and coolant temperature in the nonboiling range. Over current range of conditions

Evaluation of Melt Behavior with initial Melt Velocity under SFR Severe Accidents

International Nuclear Information System (INIS)

Heo, Hyo; Bang, In Cheol; Jerng, Dong Wook

2015-01-01

In the current Korean sodium-cooled fast reactor (SFR) program, early dispersion of the molten metallic fuel within a subchannel is suggested as one of the inherent safety strategies for the initiating phase of hypothetical core disruptive accident (HCDA). The safety strategy provides negative reactivity driven by the melt dispersal, so it could reduce the possibility of the recriticality event under a severe triple or more fault scenario for SFR. Since the behavior of the melt dispersion is unpredictable, it depends on the accident condition, particularly core region. While the voided coolant channel region is usually developed in the inner core, the unvoided coolant channel region is formed in the outer core. It is important to confirm the fuel dispersion with the core region, but there are not sufficient existing studies for them. From the existing studies, the coolant vapor pressure is considered as one of driving force to move the melt towards outside of the core. There is a complexity of the phenomena during intermixing of the melt with the coolant after the horizontal melt injections. It is too difficult to understand the several combined mechanisms related to the melt dispersion and the fragmentation. Thus, it could be worthwhile to study the horizontal melt injections at lower temperature as a preliminary study in order to identify the melt dispersion phenomena. For this reason, it is required to clarify whether the coolant vapor pressure is the driving force of the melt dispersion with the core region. The specific conditions to be well dispersed for the molten metallic fuel were discussed in the experiments with the simulant materials. The each melt behavior was compared to evaluate the melt dispersion under the coolant void condition and the boiling condition. As the results, the following results are remarked: 1. The upward melt dispersion did not occur for a given melt and coolant temperature in the nonboiling range. Over current range of conditions

Rapid Simultaneous Amplification and Detection of the MBR/JH Chromosomal Translocation by Fluorescence Melting Curve Analysis

Science.gov (United States)

Bohling, Sandra D.; King, Thomas C.; Wittwer, Carl T.; Elenitoba-Johnson, Kojo S. J.

1999-01-01

Polymerase chain reaction (PCR) amplification and product analysis for the detection of chromosomal translocations, such as the t(14;18), has traditionally been a two-step process. PCR product detection has generally entailed gel electrophoresis and/or hybridization or sequencing for confirmation of assay specificity. Using a microvolume fluorimeter integrated with a thermal cycler and a PCR-compatible double-stranded DNA (dsDNA) binding fluorescent dye (SYBR Green I), we investigated the feasibility of simultaneous thermal amplification and detection of MBR/JH translocation products by fluorescence melting curve analysis. We analyzed DNA from 30 cases of lymphoproliferative disorders comprising 19 cases of previously documented MBR/JH-positive follicle center lymphoma and 11 reactive lymphadenopathies. The samples were coded and analyzed blindly for the presence of MBR/JH translocations by fluorescence melting curve analysis. We also performed dilutional assays using the MBR/JH-positive cell line SUDHL-6. Multiplex PCR for MBR/JH and β-globin was used to simultaneously assess sample adequacy. All (100%) of the 19 cases previously determined to be MBR/JH positive by conventional PCR analysis showed a characteristic sharp decrease in fluorescence at ∼90°C by melting curve analysis after amplification. Fluorescence melting peaks obtained by plotting the negative derivative of fluorescence over temperature (−dF/dT) versus temperature (T) showed melting temperatures (Tm) at 88.85 ± 1.15°C. In addition, multiplex assays using both MBR/JH and β-globin primers yielded easily distinguishable fluorescence melting peaks at ∼90°C and 81.2°C, respectively. Dilutional assays revealed that fluorescence melting curve analysis was more sensitive than conventional PCR and agarose gel electrophoresis with ultraviolet transillumination by as much as 100-fold. Simultaneous amplification and fluorescence melting curve analysis is a simple, reliable, and sensitive method

Volatilization from borosilicate glass melts of simulated Savannah River Plant waste

International Nuclear Information System (INIS)

Wilds, G.W.

1979-01-01

Laboratory scale studies determined the rates at which the semivolatile components sodium, boron, lithium, cesium, and ruthenium volatilized from borosilicate glass melts that contained simulated Savannah River Plant waste sludge. Sodium and boric oxides volatilize as the thermally stable compound sodium metaborate, and accounted for approx. 90% of the semivolatiles that evolved. The amounts of semivolatiles that evolved increased linearly with the logarithm of the sodium content of the glass-forming mixture. Cesium volatility was slightly suppressed when titanium dioxide was added to the melt, but was unaffected when cesium was added to the melt as a cesium-loaded zeolite rather than as a cesium carbonate solution. Volatility of ruthenium was not suppressed when the glass melt was blanketed with a nonoxidizing atmosphere. Trace quantities of mercury were removed from vapor streams by adsorption onto a silver-exchanged zeolite. A bed containing silver in the ionic state removed more than 99.9% of the mercury and had a high chemisorption capacity. Beds of lead-, copper-, and copper sulfide-exchanged zeolite-X and also an unexchanged zeolite-X were tested. None of these latter beds had high removal efficiency and high chemisorption capacity

Volatilization from borosilicate glass melts of simulated Savannah River Plant waste

International Nuclear Information System (INIS)

Wilds, G.W.

1978-01-01

Laboratory scale studies determined the rates at which the semivolatile components sodium, boron, lithium, cesium, and ruthenium volatilized from borosilicate glass melts that contained simulated Savannah River Plant waste sludge. Sodium and boric oxides volatilize as the thermally stable compound sodium metaborate, and accounted for approx. 90% of the semivolatiles that evolved. The amounts of semivolatiles that evolved increased linearly with the logarithm of the sodium content of the glass-forming mixture. Cesium volatility was slightly suppressed when titanium dioxide was added to the melt, but was unaffected when cesium was added to the melt as a cesium-loaded zeolite rather than as a cesium carbonate solution. Volatility of ruthenium was not suppressed when the glass melt was blanketed with a nonoxidizing atmosphere. Trace quantities of mercury were removed from vapor streams by adsorption onto a silver-exchanged zeolite. A bed containing silver in the ionic state removed more than 99.9% of the mercury and had a high chemisorption capacity. Beds of lead-, copper-, and copper sulfide-exchanged zeolite-X and also an unexchanged zeolite-X were tested. None of these latter beds had high removal efficiency and high chemisorption capacity

Influence of Crucible Thermal Conductivity on Crystal Growth in an Industrial Directional Solidification Process for Silicon Ingots

Directory of Open Access Journals (Sweden)

Zaoyang Li

2016-01-01

Full Text Available We carried out transient global simulations of heating, melting, growing, annealing, and cooling stages for an industrial directional solidification (DS process for silicon ingots. The crucible thermal conductivity is varied in a reasonable range to investigate its influence on the global heat transfer and silicon crystal growth. It is found that the crucible plays an important role in heat transfer, and therefore its thermal conductivity can influence the crystal growth significantly in the entire DS process. Increasing the crucible thermal conductivity can shorten the time for melting of silicon feedstock and growing of silicon crystal significantly, and therefore large thermal conductivity is helpful in saving both production time and power energy. However, the high temperature gradient in the silicon ingots and the locally concave melt-crystal interface shape for large crucible thermal conductivity indicate that high thermal stress and dislocation propagation are likely to occur during both growing and annealing stages. Based on the numerical simulations, some discussions on designing and choosing the crucible thermal conductivity are presented.

Efficient analysis of mode profiles in elliptical microcavity using dynamic-thermal electron-quantum medium FDTD method.

Science.gov (United States)

Khoo, E H; Ahmed, I; Goh, R S M; Lee, K H; Hung, T G G; Li, E P

2013-03-11

The dynamic-thermal electron-quantum medium finite-difference time-domain (DTEQM-FDTD) method is used for efficient analysis of mode profile in elliptical microcavity. The resonance peak of the elliptical microcavity is studied by varying the length ratio. It is observed that at some length ratios, cavity mode is excited instead of whispering gallery mode. This depicts that mode profiles are length ratio dependent. Through the implementation of the DTEQM-FDTD on graphic processing unit (GPU), the simulation time is reduced by 300 times as compared to the CPU. This leads to an efficient optimization approach to design microcavity lasers for wide range of applications in photonic integrated circuits.

An Experimental Investigation on APR1400 Penetration Weld Failure by Metallic Melt

International Nuclear Information System (INIS)

An, Sang Mo; Ha, Kwang Soon; Kim, Hwan Yeol

2014-01-01

The penetrations are considered as the most vulnerable parts with respect to the reactor vessel failure when a core melt severe accident occurs and the corium reaches the lower head. Penetration tube failure modes can be divided into two categories; tube ejection out of the vessel lower head and rupture of the penetration tube outside the vessel. Tube ejection begins with degrading the penetration tube weld strength to zero as the weld is exposed to temperatures as high as the weld melting temperature, which is called weld failure, and then overcoming any binding force in the hole in the vessel wall that results from differential thermal expansion of the tube and vessel wall. Tube rupture assumes that the debris bed has melted the instrument tube inside the reactor and melt migrates down into the tube to a location outside the vessel wall where a pressure rupture can occur, thus breaching the pressure boundary. In the present paper, we have a focus on the tube ejection failure mode, specifically on the APR1400 weld failure by direct contact with a metallic melt. The objective is to investigate experimentally the ablation kinetics of an APR1400 penetration weld during the interactions with a metallic melt and to suggest the modification of the existing weld failure model. This paper involves the interaction experiments of two different metallic melts (metallic corium and stainless steel melts) with a weld specimen, and rough estimation of weld failure time. The interaction experiments between the metallic melts and an APR1400 penetration weld were performed to investigate the ablation kinetics of the penetration weld. Metallic corium and stainless steel melts were generated using an induction heating technique and interacted with a penetration weld specimen. The ablation rate of the weld specimen showed a range from 0.109 to 0..244 mm/s and thus the APR1400 penetration weld was estimated to be failed at hundreds of times after the interaction with the melt

Experimental results for TiO2 melting and release using cold crucible melting

International Nuclear Information System (INIS)

Hong, S. W.; Min, B. T.; Park, I. G.; Kim, H. D.

2000-01-01

To simulate the severe accident phenomena using the real reactor material which melting point is about 2,800K, the melting and release method for materials with high melting point should be developed. This paper discusses the test results for TiO 2 materials using the cold crucible melting method to study the melting and release method of actual corium. To melt and release of few kg of TiO2, the experimental facility is manufactured through proper selection of design parameters such as frequency and capacity of R.F generator, crucible size and capacity of coolant. The melting and release of TiO 2 has been successfully performed in the cold crucible of 15cm in inner diameter and 30cm in height with 30kW RF power generator of 370 KHz. In the melt delivery experiment, about 2.6kg of molten TiO2, 60% of initial charged mass, is released. Rest of it is remained in the watercage in form of the rubble crust formed at the top of crucible and melt crust formed at the interface between the water-cage and melt. Especially, in the melt release test, the location of the working coil is important to make the thin crust at the bottom of the crucible

Estimation of effect of inorganic salts on state of melts and carbamide solutions

International Nuclear Information System (INIS)

Dymnikov, N.S.; Yakunin, N.A.; Baranov, A.V.; Moryganov, A.P.

1995-01-01

The character of coordination in the systems carbamide-LiCl and carbamide-CaCl 2 has been shown on the basis of IR spectroscopy data. Interrelation between complexing in the melt carbamide-inorganic salt and thermal resistance of amide compound has been ascertained. 3 refs.; 3 figs

In-pile measurement of the thermal conductivity of irradiated metallic fuel

International Nuclear Information System (INIS)

Bauer, T.H.; Holland, J.W.

1995-01-01

Transient test data and posttest measurements from recent in-pile overpower transient experiments are used for an in situ determination of metallic fuel thermal conductivity. For test pins that undergo melting but remain intact, a technique is described that relates fuel thermal conductivity to peak pin power during the transient and a posttest measured melt radius. Conductivity estimates and their uncertainty are made for a database of four irradiated Integral Fast Reactor-type metal fuel pins of relatively low burnup (<3 at.%). In the assessment of results, averages and trends of measured fuel thermal conductivity are correlated to local burnup. Emphasis is placed on the changes of conductivity that take place with burnup-induced swelling and sodium logging. Measurements are used to validate simple empirically based analytical models that describe thermal conductivity of porous media and that are recommended for general thermal analyses of irradiated metallic fuel

Energy Saving Melting and Revert Reduction Technology (E-SMARRT): Melting Efficiency Improvement

Energy Technology Data Exchange (ETDEWEB)

Principal Investigator Kent Peaslee; Co-PI’s: Von Richards, Jeffrey Smith

2012-07-31

Steel foundries melt recycled scrap in electric furnaces and typically consume 35-100% excess energy from the theoretical energy requirement required to pour metal castings. This excess melting energy is multiplied by yield losses during casting and finishing operations resulting in the embodied energy in a cast product typically being three to six times the theoretical energy requirement. The purpose of this research project was to study steel foundry melting operations to understand energy use and requirements for casting operations, define variations in energy consumption, determine technologies and practices that are successful in reducing melting energy and develop new melting techniques and tools to improve the energy efficiency of melting in steel foundry operations.

Simulation and experiment of thermal energy management with phase change material for ageing LiFePO4 power battery

International Nuclear Information System (INIS)

Rao Zhonghao; Wang Shuangfeng; Zhang Guoqing

2011-01-01

Highlights: → We study the thermal energy management performance of ageing LiFePO 4 power battery. → 3-D modules of single cell and battery pack are formulated according to the experimental results. → Thermal resistance in the battery cell leaded to an inevitable temperature difference. → It is necessary to improve the thermal conductivity and lower the melting point of phase change material. → Thermal conductivity of phase change material and battery exist an effective proportion. - Abstract: Thermal energy management performance of ageing commercial rectangular LiFePO 4 power batteries using phase change material (PCM) and thermal behavior related to thermal conductivity between the PCM and the cell are discussed in this paper. The heat sources are simplified according to the experimental results of the cells discharged at 35 A (∼5 C). 3-D modules of a single cell and battery pack are formulated, respectively. The results show that the thermal resistance in the cell leads to an inevitable temperature difference. It is necessary to improve the thermal conductivity and to lower the melting point of the PCM for heat transfer enhancement. The PCM with a melting point lower than 45 deg. C will be more effective for heat dissipation, with a desired maximum temperature below 50 deg. C. The temperature difference in the whole unit before PCM melting will be decreased significantly. In addition, a proper k PCM :k c is necessary for a well designed battery thermal energy management system.

MELT-IIIB: an updated version of the melt code

International Nuclear Information System (INIS)

Tabb, K.K.; Lewis, C.H.; O'Dell, L.D.; Padilla, A. Jr.; Smith, D.E.; Wilburn, N.P.

1979-04-01

The MELT series is a reactor modeling code designed to investigate a wide variety of hypothetical accident conditions, particularly the transient overpower sequence. MELT-IIIB is the latest in the series

Phenomenological studies on melt-structure-water interactions (MSWI) during severe accidents

International Nuclear Information System (INIS)

Sehgal, B.R.; Yang, Z.L.; Haraldsson, H.O.; Nourgaliev, R.R.; Konovalikhin, M.; Paladino, D.; Gubaidullin, A.A.; Kolb, G.; Theerthan, A.

2000-05-01

This is the annual report for the work performed in 1999 in the research project Melt-Structure-Water Interactions During Severe Accidents in LWRs, under the auspices of the APRI Project, jointly funded by SKI, HSK, USNRC and the Swedish and Finnish power companies. The emphasis of the work is placed on phenomena and properties which govern the fragmentation and breakup of melt jets and droplets, melt spreading and coolability, and thermal and mechanical loadings of a pressure vessel during melt-vessel interaction. We believe that significant technical advances have been achieved during the course of these studies. It was found that: The coolant temperature has significant influence on the characteristics of debris fragments produced from the breakup of an oxidic melt jet. At low subcooling the fragments are relatively large and irregular compared to the smaller particles produced at high subcooling. The melt jet density has considerable effect on the fragment size produced. As the melt density increases the fragment size becomes smaller. The mass mean size of the debris changes proportionally to the square root of the coolant to melt density ratio. The melt superheat has little effect on the debris particle size distribution produced during the melt jet fragmentation. The impingement velocity of the jet has significant impact on the fragmentation process. At lower jet velocity the melt fragments agglomerate and form a cake of large size debris. When the jet velocity is increased more complete fragmentation is obtained. The scaling methodology for melt spreading, developed during 1998, has been further validated against almost all of the spreading experimental data available so far. Experimental results for the dryout heat flux of homogeneous particulate debris beds with top flooding compare well with the Lipinski correlation. For the stratified particle beds, the fine particle layer resting on the top of another particle layer dominates the dryout processes

Phenomenological studies on melt-structure-water interactions (MSWI) during severe accidents

Energy Technology Data Exchange (ETDEWEB)

Sehgal, B.R.; Yang, Z.L.; Haraldsson, H.O.; Nourgaliev, R.R.; Konovalikhin, M.; Paladino, D.; Gubaidullin, A.A.; Kolb, G.; Theerthan, A. [Royal Inst. of Tech., Stockholm (Sweden). Div. of Nuclear Power Safety

2000-05-01

This is the annual report for the work performed in 1999 in the research project Melt-Structure-Water Interactions During Severe Accidents in LWRs, under the auspices of the APRI Project, jointly funded by SKI, HSK, USNRC and the Swedish and Finnish power companies. The emphasis of the work is placed on phenomena and properties which govern the fragmentation and breakup of melt jets and droplets, melt spreading and coolability, and thermal and mechanical loadings of a pressure vessel during melt-vessel interaction. We believe that significant technical advances have been achieved during the course of these studies. It was found that: The coolant temperature has significant influence on the characteristics of debris fragments produced from the breakup of an oxidic melt jet. At low subcooling the fragments are relatively large and irregular compared to the smaller particles produced at high subcooling. The melt jet density has considerable effect on the fragment size produced. As the melt density increases the fragment size becomes smaller. The mass mean size of the debris changes proportionally to the square root of the coolant to melt density ratio. The melt superheat has little effect on the debris particle size distribution produced during the melt jet fragmentation. The impingement velocity of the jet has significant impact on the fragmentation process. At lower jet velocity the melt fragments agglomerate and form a cake of large size debris. When the jet velocity is increased more complete fragmentation is obtained. The scaling methodology for melt spreading, developed during 1998, has been further validated against almost all of the spreading experimental data available so far. Experimental results for the dryout heat flux of homogeneous particulate debris beds with top flooding compare well with the Lipinski correlation. For the stratified particle beds, the fine particle layer resting on the top of another particle layer dominates the dryout processes

Kinetics of the melting front movement in process of centrifugal induction surfacing of powder material with nanoscale modificaters

Science.gov (United States)

Sasnouski, I.; Kurylionak, A.

2018-03-01

For solving the problem of improving the powder coatings modified by nanostructure components obtained by induction surfacing method tribological characteristics it is necessary to study the kinetics of the powdered layer melting and define the minimum time of melting. For powdered layer predetermined temperature maintenance at sintering mode stage it is required to determine the temperature difference through blank thickness of the for one hundred-day of the define the warm-up swing on of the stocking up by solving the thermal conductivity stationary problem for quill (hollow) cylinder with internal heat source. Herewith, since in practice thickness of the cylinder wall is much less then its diameter and the temperature difference is comparatively small, the thermal conductivity dependence upon the temperature can be treated as negligible. As it was shown by our previous studies, in the induction heating process under powdered material centrifugal surfacing (i.e. before achieving the melting temperature) the temperature distribution in powdered layer thickness may be considered even. Hereinafter, considering the blank part induction heating process quasi-stationarity under Fo big values, it is possible to consider its internal surface heating as developing with constant velocity. As a result of development the melting front movement mathematical model in a powdered material with nanostructure modifiers the minimum surfacing time is defined. It allows to minimize negative impact of thermal influence on formation of applied coating structure, to raise productivity of the process, to lower power inputs and to ensure saving of nonferrous and high alloys by reducing the allowance for machining. The difference of developed mathematical model of melting front movement from previously known is that the surface temperature from which the heat transfer occures is a variable and varies with a time after the linear law.

Experimental investigation of hydrodynamics of melt layer during laser cutting of steel

Energy Technology Data Exchange (ETDEWEB)

Hirano, Koji; Fabbro, Remy, E-mail: hirano.koji@nsc.co.jp [PIMM Laboratory (Arts et Metiers ParisTech-CNRS), 151 Boulevard de l' Hopital 75013 Paris (France)

2011-03-16

In a laser cutting process, understanding of the hydrodynamics of melt layer is significant, because it is an important factor which controls the final quality. In this work, we observed the hydrodynamics of melt layer on a kerf front in the case of laser cutting of steel with an inert gas. The observation shows that the melt flow on the kerf front exhibits strong instability, depending on cutting velocity. In the intermediate range of velocities, the flow on the central part of the kerf front is continuous, whereas the flow along the sides is discontinuous. It is first confirmed that the instability in the side flow is the cause of striation initiation from the top part of the kerf. The origin of the instability is discussed in terms of instabilities in thermal dynamics and hydrodynamics. The proposed model shows reasonable agreement with experimental results.

Study of mechanical, rheological and thermal properties of nanocomposite HMSPP (high melt strength polypropylene) with Brazilian bentonite; Estudo das propriedades mecanicas, reologicas e termicas de nanocomposito de HMSPP (polipropileno com alta resistencia do fundido) com uma bentonita brasileira

Energy Technology Data Exchange (ETDEWEB)

Fermino, Danilo Marin

2011-07-01

This work concerns to the study of the mechanical, thermal and rheological behavior of the nano composite HMSPP - Polypropylene High Melt Strength (obtained at a dose of 12.5 kGy) and a bentonite clay Brazilian Paraiba, known as 'Chocolate' in concentrations of 5 and 10% by weight, comparison of to one American Clay, Cloisite 20A nanocomposite was done. Agent compatibilizer polypropylene-graft, known as maleic anhydride (PP-g-AM) was addict 3% concentration thought technique melt intercalation using a twin-screw extruder and the specimens were prepared by injection process. The mechanical behavior was evaluated by strength, flexural strength and impact tests. The thermal behavior was evaluated by the techniques of differential scanning calorimetry (DSC) and thermogravimetry (TGM). The rheological behavior was evaluated in rheometer. The morphology of the nanocomposites was studied by the technique of scanning electron microscopy (SEM). The organophilic bentonite and the nanocomposites were characterized by X-ray diffraction (XRD) and infrared (FTIR). (author)

Study of mechanical, rheological and thermal properties of nanocomposite HMSPP (high melt strength polypropylene) with Brazilian bentonite; Estudo das propriedades mecanicas, reologicas e termicas de nanocomposito de HMSPP (polipropileno com alta resistencia do fundido) com uma bentonita brasileira

Energy Technology Data Exchange (ETDEWEB)

Fermino, Danilo Marin

2011-07-01

This work concerns to the study of the mechanical, thermal and rheological behavior of the nano composite HMSPP - Polypropylene High Melt Strength (obtained at a dose of 12.5 kGy) and a bentonite clay Brazilian Paraiba, known as 'Chocolate' in concentrations of 5 and 10% by weight, comparison of to one American Clay, Cloisite 20A nanocomposite was done. Agent compatibilizer polypropylene-graft, known as maleic anhydride (PP-g-AM) was addict 3% concentration thought technique melt intercalation using a twin-screw extruder and the specimens were prepared by injection process. The mechanical behavior was evaluated by strength, flexural strength and impact tests. The thermal behavior was evaluated by the techniques of differential scanning calorimetry (DSC) and thermogravimetry (TGM). The rheological behavior was evaluated in rheometer. The morphology of the nanocomposites was studied by the technique of scanning electron microscopy (SEM). The organophilic bentonite and the nanocomposites were characterized by X-ray diffraction (XRD) and infrared (FTIR). (author)

Thermal Loading and Lifetime Estimation for Power Device Considering Mission Profiles in Wind Power Converter

DEFF Research Database (Denmark)

Ma, Ke; Liserre, Marco; Blaabjerg, Frede

2015-01-01

for the reliability improvement and also for cost reduction of wind power technology. Unfortunately, the existing lifetime estimation methods for the power electronic converter are not yet suitable in the wind power application, because the comprehensive mission profiles are not well specified and included......As a key component in the wind turbine system, the power electronic converter and its power semiconductors suffer from complicated power loadings related to environment, and are proven to have high failure rates. Therefore, correct lifetime estimation of wind power converter is crucial...... devices, more detailed information of the lifetime-related performance in wind power converter can be obtained. Some experimental results are also included to validate the thermal behavior of power device under different mission profiles....

Simultaneous Profiling of DNA Mutation and Methylation by Melting Analysis Using Magnetoresistive Biosensor Array

DEFF Research Database (Denmark)

Rizzi, Giovanni; Lee, Jung-Rok; Dahl, Christina

2017-01-01

specificity. Genomic (mutation) or bisulphite-treated (methylation) DNA is amplified using nondiscriminatory primers, and the amplicons are then hybridized to a giant magnetoresistive (GMR) biosensor array followed by melting curve measurements. The GMR biosensor platform offers scalable multiplexed detection...

Thermal expansion and thermal stress in the moon and terrestrial planets - Clues to early thermal history

Science.gov (United States)

Solomon, S. C.; Chaiken, J.

1976-01-01

The paper discusses how features of the surface geology of the moon and also Mars and Mercury impose constraints on the volumetric expansion or contraction of a planet and consequently provide a test of thermal history models. The moon has changed very little in volume over the last 3.8 b.y. Thermal models satisfying this constraint involve early heating and perhaps melting of the outer 200 km of the moon and an initially cold interior. Mercury has contracted by about 2 km in radius since emplacement of its present surface, so core formation must predate that surface. A hot initial temperature distribution is implied.

The WAIS Melt Monitor: An automated ice core melting system for meltwater sample handling and the collection of high resolution microparticle size distribution data

Science.gov (United States)

Breton, D. J.; Koffman, B. G.; Kreutz, K. J.; Hamilton, G. S.

2010-12-01

profiles to guide the melting process. The combination of these data allow us to analyze melt head performance, minimize outer-to-inner fraction contamination and avoid melt head flooding. The WAIS Melt Monitor system allows the collection of real-time, sub-annual microparticle and electrical conductivity data while producing and storing enough sample for traditional Coulter-Counter particle measurements as well long term acid leaching of bioactive metals (e.g., Fe, Co, Cd, Cu, Zn) prior to chemical analysis.

Thermal effects of runaway electrons in an armoured divertor

International Nuclear Information System (INIS)

Stad, R.C.L. van der.

1993-12-01

This report describes the results of a numerical thermal analysis of the heat deposition of runaway electrons accompanying plasma disruptions in a armoured divertor. The divertor concepts studied are carbon on molybdenum and beryllium on copper. The conclusion is that the runaway electrons can cause melting of the armour as well as melting of the structure and can damage the divertor severely. (orig.)

Cloud screening and melt water detection over melting sea ice using AATSR/SLSTR

Science.gov (United States)

Istomina, Larysa; Heygster, Georg

2014-05-01

With the onset of melt in the Arctic Ocean, the fraction of melt water on sea ice, the melt pond fraction, increases. The consequences are: the reduced albedo of sea ice, increased transmittance of sea ice and affected heat balance of the system with more heat passing through the ice into the ocean, which facilitates further melting. The onset of melt, duration of melt season and melt pond fraction are good indicators of the climate state of the Arctic and its change. In the absence of reliable sea ice thickness retrievals in summer, melt pond fraction retrieval from satellite is in demand as input for GCM as an indicator of melt state of the sea ice. The retrieval of melt pond fraction with a moderate resolution radiometer as AATSR is, however, a non-trivial task due to a variety of subpixel surface types with very different optical properties, which give non-unique combinations if mixed. In this work this has been solved by employing additional information on the surface and air temperature of the pixel. In the current work, a concept of melt pond detection on sea ice is presented. The basis of the retrieval is the sensitivity of AATSR reflectance channels 550nm and 860nm to the amount of melt water on sea ice. The retrieval features extensive usage of a database of in situ surface albedo spectra. A tree of decisions is employed to select the feasible family of in situ spectra for the retrieval, depending on the melt stage of the surface. Reanalysis air temperature at the surface and brightness temperature measured by the satellite sensor are analyzed in order to evaluate the melting status of the surface. Case studies for FYI and MYI show plausible retrieved melt pond fractions, characteristic for both of the ice types. The developed retrieval can be used to process the historical AATSR (2002-2012) dataset, as well as for the SLSTR sensor onboard the future Sentinel-3 mission (scheduled for launch in 2015), to keep the continuity and obtain longer time sequence

Polyethylene/synthetic boehmite alumina nanocomposites: Structure, thermal and rheological properties

Directory of Open Access Journals (Sweden)

2010-05-01

Full Text Available Synthetic boehmite alumina (BA has been incorporated up to 8 wt% in low density polyethylene (LDPE and high density polyethylene (HDPE, respectively, by melt compounding. The primary nominal particle size of these two BA grades was 40 and 60 nm, respectively. The dispersion of the BA in polyethylene (PE matrices was investigated by scanning and transmission electron microscopy techniques (SEM and TEM. The thermal (melting and crystallization, thermooxidative (oxidation induction temperature and time, and rheological behaviors of the nanocomposites were determined. It was found that BA is nanoscale dispersed in both LDPE and HDPE without any surface treatment and additional polymeric compatibilizer. BA practically did not influence the thermal (melting and crystallization and rheological properties of the parent PEs. On the other hand, BA worked as a powerful thermooxidative stabilizer for LDPE, and especially for HDPE nanocomposites.

MeltMan: Optimization, Evaluation, and Universal Application of a qPCR System Integrating the TaqMan qPCR and Melting Analysis into a Single Assay

Science.gov (United States)

Nagy, Alexander; Černíková, Lenka; Vitásková, Eliška; Křivda, Vlastimil; Dán, Ádám; Dirbáková, Zuzana; Jiřincová, Helena; Procházka, Bohumír; Sedlák, Kamil; Havlíčková, Martina

2016-01-01

In the present work, we optimised and evaluated a qPCR system integrating 6-FAM (6-carboxyfluorescein)-labelled TaqMan probes and melting analysis using the SYTO 82 (S82) DNA binding dye in a single reaction. We investigated the influence of the S82 on various TaqMan and melting analysis parameters and defined its optimal concentration. In the next step, the method was evaluated in 36 different TaqMan assays with a total of 729 paired reactions using various DNA and RNA templates, including field specimens. In addition, the melting profiles of interest were correlated with the electrophoretic patterns. We proved that the S82 is fully compatible with the FAM-TaqMan system. Further, the advantages of this approach in routine diagnostic TaqMan qPCR were illustrated with practical examples. These included solving problems with flat or other atypical amplification curves or even false negativity as a result of probe binding failure. Our data clearly show that the integration of the TaqMan qPCR and melting analysis into a single assay provides an additional control option as well as the opportunity to perform more complex analyses, get more data from the reactions, and obtain analysis results with higher confidence. PMID:27031831

Viscosity and diffusivity in melts: from unary to multicomponent systems

Science.gov (United States)

Chen, Weimin; Zhang, Lijun; Du, Yong; Huang, Baiyun

2014-05-01

Viscosity and diffusivity, two important transport coefficients, are systematically investigated from unary melt to binary to multicomponent melts in the present work. By coupling with Kaptay's viscosity equation of pure liquid metals and effective radii of diffusion species, the Sutherland equation is modified by taking the size effect into account, and further derived into an Arrhenius formula for the convenient usage. Its reliability for predicting self-diffusivity and impurity diffusivity in unary liquids is then validated by comparing the calculated self-diffusivities and impurity diffusivities in liquid Al- and Fe-based alloys with the experimental and the assessed data. Moreover, the Kozlov model was chosen among various viscosity models as the most reliable one to reproduce the experimental viscosities in binary and multicomponent melts. Based on the reliable viscosities calculated from the Kozlov model, the modified Sutherland equation is utilized to predict the tracer diffusivities in binary and multicomponent melts, and validated in Al-Cu, Al-Ni and Al-Ce-Ni melts. Comprehensive comparisons between the calculated results and the literature data indicate that the experimental tracer diffusivities and the theoretical ones can be well reproduced by the present calculations. In addition, the vacancy-wind factor in binary liquid Al-Ni alloys with the increasing temperature is also discussed. What's more, the calculated inter-diffusivities in liquid Al-Cu, Al-Ni and Al-Ag-Cu alloys are also in excellent agreement with the measured and theoretical data. Comparisons between the simulated concentration profiles and the measured ones in Al-Cu, Al-Ce-Ni and Al-Ag-Cu melts are further used to validate the present calculation method.

Potential for cladding thermal failure in LWRs during high temperature transients

International Nuclear Information System (INIS)

El Genk, M.S.

1979-01-01

The temperature increase in the fuel and the cladding during a PCM accident produces film boiling at the cladding surface which may induce zircaloy cladding failure, due to embrittlement, and fuel melting at the centerline of the fuel pellets. Molten fuel may extrude through radial cracks in the fuel and relocate in the fuel-cladding gap. Contact of extruded molten fuel with the cladding, which is at high temperature during film boiling, may induce cladding thermal failure due to melting. An assessment of central fuel melting and molten fuel extrusion into the fuel-cladding gap during a PCM accident is presented. The potential for thermal failure of the zircaloy cladding upon being contacted by molten fuel during such an accident is also analyzed and compared with the applicable experimental evidence

Effect of Topography on Subglacial Discharge and Submarine Melting During Tidewater Glacier Retreat

Science.gov (United States)

Amundson, J. M.; Carroll, D.

2018-01-01

To first order, subglacial discharge depends on climate, which determines precipitation fluxes and glacier mass balance, and the rate of glacier volume change. For tidewater glaciers, large and rapid changes in glacier volume can occur independent of climate change due to strong glacier dynamic feedbacks. Using an idealized tidewater glacier model, we show that these feedbacks produce secular variations in subglacial discharge that are influenced by subglacial topography. Retreat along retrograde bed slopes (into deep water) results in rapid surface lowering and coincident increases in subglacial discharge. Consequently, submarine melting of glacier termini, which depends on subglacial discharge and ocean thermal forcing, also increases during retreat into deep water. Both subglacial discharge and submarine melting subsequently decrease as glacier termini retreat out of deep water and approach new steady state equilibria. In our simulations, subglacial discharge reached peaks that were 6-17% higher than preretreat values, with the highest values occurring during retreat from narrow sills, and submarine melting increased by 14% for unstratified fjords and 51% for highly stratified fjords. Our results therefore indicate that submarine melting acts in concert with iceberg calving to cause tidewater glacier termini to be unstable on retrograde beds. The full impact of submarine melting on tidewater glacier stability remains uncertain, however, due to poor understanding of the coupling between submarine melting and iceberg calving.

Laser post-processing of Inconel 625 made by selective laser melting

Science.gov (United States)

Witkin, David; Helvajian, Henry; Steffeney, Lee; Hansen, William

2016-04-01

The effect of laser remelting of surfaces of as-built Selective Laser Melted (SLM) Inconel 625 was evaluated for its potential to improve the surface roughness of SLM parts. Many alloys made by SLM have properties similar to their wrought counterparts, but surface roughness of SLM-made parts is much higher than found in standard machine shop operations. This has implications for mechanical properties of SLM materials, such as a large debit in fatigue properties, and in applications of SLM, where surface roughness can alter fluid flow characteristics. Because complexity and netshape fabrication are fundamental advantages of Additive Manufacturing (AM), post-processing by mechanical means to reduce surface roughness detracts from the potential utility of AM. Use of a laser to improve surface roughness by targeted remelting or annealing offers the possibility of in-situ surface polishing of AM surfaces- the same laser used to melt the powder could be amplitude modulated to smooth the part during the build. The effects of remelting the surfaces of SLM Inconel 625 were demonstrated using a CW fiber laser (IPG: 1064 nm, 2-50 W) that is amplitude modulated with a pulse profile to induce remelting without spallation or ablation. The process achieved uniform depth of melting and improved surface roughness. The results show that with an appropriate pulse profile that meters the heat-load, surface features such as partially sintered powder particles and surface connected porosity can be mitigated via a secondary remelting/annealing event.

Thermal properties of poly(3-hydroxybutyrate)/vegetable fiber composites

Science.gov (United States)

Vitorino, Maria B. C.; Reul, Lízzia T. A.; Carvalho, Laura H.; Canedo, Eduardo L.

2015-05-01

The present work studies the thermal properties of composites of poly(3-hydroxybutyrate) (PHB) - a fully biodegradable semi-crystalline thermo-plastic obtained from renewable resources through low-impact biotechno-logical process, biocompatible and non-toxic - and vegetable fiber from the fruit (coconut) of babassu palm tree. PHB is a highly crystalline resin and this characteristic leads to suboptimal properties in some cases. Consequently, thermal properties, in particular those associated with the crystallization of the matrix, are important to judge the suitability of the compounds for specific applications. PHB/babassu composites with 0-50% load were prepared in an internal mixer. Two different types of babassu fibers with two different particle size ranges were compounded with PHB and test specimens molded by compression. Melting and crystallization behavior were studied by differential scanning calorimetry (DSC) at heating/cooling rates between 2 and 30°C/min. Several parameters, including melting point, crystallization temperature, crystallinity, and rate of crystallization, were estimated as functions of load and heating/cooling rates. Results indicate that fibers do not affect the melting process, but facilitate crystallization from the melt. Crystallization temperatures are 30 to 40°C higher for the compounds compared with the neat resin. However, the amount of fiber added has little effect on crystallinity and the degree of crystallinity is hardly affected by the load. Fiber type and initial particle size do not have a significant effect on thermal properties.

Ti(r) profiles from the JET neutron profile monitor for ohmic discharges

Energy Technology Data Exchange (ETDEWEB)

Esposito, B. (ENEA, Frascati (Italy). Centro Ricerche Energia); Marcus, F.B.; Conroy, S.; Jarvis, O.N.; Loughlin, M.J.; Sadler, G.; Belle, P. van (Commission of the European Communities, Abingdon (United Kingdom). JET Joint Undertaking); Adams, J.M.; Watkins, N. (AEA Industrial Technology, Harwell (United Kingdom))

1991-01-01

A study has been made of the neutron emissivity, using the JET neutron profile monitor, obtained for ohmically heated deuterium discharges. Both one-dimensional (1-D) best-fit inversion procedures and 2-D tomography have been used to deduce the radial profile of the neutron emission from the line-integral data. The profiles of ion temperature and ion thermal conductivity are then derived. The scaling of the ion thermal conductivity with plasma current is found to be opposite to that of neoclassical theory. (author) 4 refs., 5 figs.

Crystallization and melting behavior of nanoclay-containing polypropylene/poly(trimethylene terephthalate blends

Directory of Open Access Journals (Sweden)

S. H. Jafari

2012-02-01

Full Text Available This contribution concerns preparation and characterization of polypropylene (PP/poly(trimethylene terephthalate (PTT melt-mixed blends in the presence of organically-modified montmorillonite nanoclays and functional compatibilizers. Immiscibility and nanocomposite formation were confirmed via transmission electron microscopy. An intercalated structure was observed by wide angle X-ray diffraction technique. Crystallization, and melting characteristics were studied by differential scanning calorimetry in both isothermal and non-isothermal modes, supplemented by temperature modulated DSC (TMDSC. A concurrent crystallization was found for both polymeric components in the blends. Whereas blending favored PP crystallizability, it interrupted that of PTT. The addition compatibilizers interfered with rate, temperature, and degree of crystallization of PP and PTT. On the contrary, nanoclays incorporation increased crystallizability of each individual component. However, as for blend nanocomposite samples, the way the crystallization behavior changed was established to depend on the type of nanoclay. Based on kinetic analysis, isothermal crystallization nucleation followed athermal mechanism, while that of non-isothermal obeyed thermal mode. Addition of nanoclays shifted nucleation mechanism from athermal to thermal mode.

Effects of high hydrostatic pressure and thermal processing on bioactive compounds, antioxidant activity, and volatile profile of mulberry juice.

Science.gov (United States)

Wang, Fan; Du, Bao-Lei; Cui, Zheng-Wei; Xu, Li-Ping; Li, Chun-Yang

2017-03-01

The aim of this study was to investigate the effects of high hydrostatic pressure and thermal processing on microbiological quality, bioactive compounds, antioxidant activity, and volatile profile of mulberry juice. High hydrostatic pressure processing at 500 MPa for 10 min reduced the total viable count from 4.38 log cfu/ml to nondetectable level and completely inactivated yeasts and molds in raw mulberry juice, ensuring the microbiological safety as thermal processing at 85 ℃ for 15 min. High hydrostatic pressure processing maintained significantly (p hydrostatic pressure processing enhanced the volatile compound concentrations of mulberry juice while thermal processing reduced them in comparison with the control. These results suggested that high hydrostatic pressure processing could be an alternative to conventional thermal processing for production of high-quality mulberry juice.

Numerical study of finned heat pipe-assisted thermal energy storage system with high temperature phase change material

International Nuclear Information System (INIS)

Tiari, Saeed; Qiu, Songgang; Mahdavi, Mahboobe

2015-01-01

Highlights: • A finned heat pipe-assisted latent heat thermal energy storage system is studied. • The effects of heat pipes spacing and fins geometrical features are investigated. • Smaller heat pipes spacing and longer fins improve the melting rate. • The optimal heat pipe and fin arrangements are determined. - Abstract: In the present study, the thermal characteristics of a finned heat pipe-assisted latent heat thermal energy storage system are investigated numerically. A transient two-dimensional finite volume based model employing enthalpy-porosity technique is implemented to analyze the performance of a thermal energy storage unit with square container and high melting temperature phase change material. The effects of heat pipe spacing, fin length and numbers and the influence of natural convection on the thermal response of the thermal energy storage unit have been studied. The obtained results reveal that the natural convection has considerable effect on the melting process of the phase change material. Increasing the number of heat pipes (decreasing the heat pipe spacing) leads to the increase of melting rate and the decrease of base wall temperature. Also, the increase of fin length results in the decrease of temperature difference within the phase change material in the container, providing more uniform temperature distribution. It was also shown that number of the fins does not have a significant effect on the performance of the system

Thermal behaviour of a spherical addition to molten metals

Energy Technology Data Exchange (ETDEWEB)

Roehmen, E.

1995-05-01

This thesis presents a numerical model for describing the thermal behaviour of a spherical alloy addition when added to a melt. It is assumed that: no significant heat of solution between the alloy addition and the melt is involved, the dissolution rate is dominated by heat transfer from the melt, the heat flow into the addition is spherically symmetric, the additions have a well defined melting point, there are no solid phase transformations, heat conduction can be represented by Fourier`s law, and the heat transfer from the melt can be described by an average heat transfer coefficient. The model is validated by comparison with experimental data obtained from immersion experiments on: (1) a 4.88 cm diameter Al sphere chilled in liquid nitrogen to -196 {sup o}C and then immersed in water of 3.8 {sup o}C and 18.1 {sup o}C, (2) 4.90 cm diameter Al spheres at room temperatures immersed in molten Al of 720 {sup o}C, and (3) 3.72 cm diameter 75 wt% FeSi spheres at 150 {sup o}C immersed in molten steel of 1600 {sup o}C. The shell thickness and temperatures at the sphere centre and surface were recorded as functions of time. For model and experiment to agree, it was found that the density, specific heat and thermal conductivity of the alloy addition must depend on temperature, and an inner heat transfer resistance across the sphere-shell interphase must be included. The sensible heat of the melt that solidifies should be included in the heat balance only when the shell is expanding. The inner heat transfer resistance is shown to be very important in determining the melting/dissolution time for alloy additions that react strongly with the melt. 70 refs., 60 figs., 36 tabs.

Rheo-electrical approximate simulation of monocrystal growth from the melt

International Nuclear Information System (INIS)

Vernois, G.