WorldWideScience

Sample records for thermal infrared spectroscopy

  1. Broadband infrared vibrational nano-spectroscopy using thermal blackbody radiation.

    Science.gov (United States)

    O'Callahan, Brian T; Lewis, William E; Möbius, Silke; Stanley, Jared C; Muller, Eric A; Raschke, Markus B

    2015-12-14

    Infrared vibrational nano-spectroscopy based on scattering scanning near-field optical microscopy (s-SNOM) provides intrinsic chemical specificity with nanometer spatial resolution. Here we use incoherent infrared radiation from a 1400 K thermal blackbody emitter for broadband infrared (IR) nano-spectroscopy. With optimized interferometric heterodyne signal amplification we achieve few-monolayer sensitivity in phonon polariton spectroscopy and attomolar molecular vibrational spectroscopy. Near-field localization and nanoscale spatial resolution is demonstrated in imaging flakes of hexagonal boron nitride (hBN) and determination of its phonon polariton dispersion relation. The signal-to-noise ratio calculations and analysis for different samples and illumination sources provide a reference for irradiance requirements and the attainable near-field signal levels in s-SNOM in general. The use of a thermal emitter as an IR source thus opens s-SNOM for routine chemical FTIR nano-spectroscopy.

  2. Thermal Infrared Spectroscopy of Saturn and Titan from Cassini

    Science.gov (United States)

    Jennings, Donald E.; Brasunas, J. C.; Carlson, R. C.; Flasar, F. M.; Kunde, V. G.; Mamoutkine, A. A.; Nixon, A.; Pearl, J. C.; Romani, P. N.; Simon-Miller, A. A.; hide

    2009-01-01

    The Cassini spacecraft completed its nominal mission at Saturn in 2008 and began its extended mission. Cassini carries the Composite Infrared Spectrometer (CIRS); a Fourier transform spectrometer that measures the composition, thermal structure and dynamics of the atmospheres of Saturn and Titan, and also the temperatures of other moons and the rings.

  3. Thermal infrared spectroscopy and modeling of experimentally shocked plagioclase feldspars

    Science.gov (United States)

    Johnson, J. R.; Horz, F.; Staid, M.I.

    2003-01-01

    Thermal infrared emission and reflectance spectra (250-1400 cm-1; ???7???40 ??m) of experimentally shocked albite- and anorthite-rich rocks (17-56 GPa) demonstrate that plagioclase feldspars exhibit characteristic degradations in spectral features with increasing pressure. New measurements of albite (Ab98) presented here display major spectral absorptions between 1000-1250 cm-1 (8-10 ??m) (due to Si-O antisymmetric stretch motions of the silica tetrahedra) and weaker absorptions between 350-700 cm-1 (14-29 ??m) (due to Si-O-Si octahedral bending vibrations). Many of these features persist to higher pressures compared to similar features in measurements of shocked anorthite, consistent with previous thermal infrared absorption studies of shocked feldspars. A transparency feature at 855 cm-1 (11.7 ??m) observed in powdered albite spectra also degrades with increasing pressure, similar to the 830 cm-1 (12.0 ??m) transparency feature in spectra of powders of shocked anorthite. Linear deconvolution models demonstrate that combinations of common mineral and glass spectra can replicate the spectra of shocked anorthite relatively well until shock pressures of 20-25 GPa, above which model errors increase substantially, coincident with the onset of diaplectic glass formation. Albite deconvolutions exhibit higher errors overall but do not change significantly with pressure, likely because certain clay minerals selected by the model exhibit absorption features similar to those in highly shocked albite. The implication for deconvolution of thermal infrared spectra of planetary surfaces (or laboratory spectra of samples) is that the use of highly shocked anorthite spectra in end-member libraries could be helpful in identifying highly shocked calcic plagioclase feldspars.

  4. Thermal infrared spectroscopy and modeling of experimentally shocked basalts

    Science.gov (United States)

    Johnson, J. R.; Staid, M.I.; Kraft, M.D.

    2007-01-01

    New measurements of thermal infrared emission spectra (250-1400 cm-1; ???7-40 ??m) of experimentally shocked basalt and basaltic andesite (17-56 GPa) exhibit changes in spectral features with increasing pressure consistent with changes in the structure of plagioclase feldspars. Major spectral absorptions in unshocked rocks between 350-700 cm-1 (due to Si-O-Si octahedral bending vibrations) and between 1000-1250 cm-1 (due to Si-O antisymmetric stretch motions of the silica tetrahedra) transform at pressures >20-25 GPa to two broad spectral features centered near 950-1050 and 400-450 cm-1. Linear deconvolution models using spectral libraries composed of common mineral and glass spectra replicate the spectra of shocked basalt relatively well up to shock pressures of 20-25 GPa, above which model errors increase substantially, coincident with the onset of diaplectic glass formation in plagioclase. Inclusion of shocked feldspar spectra in the libraries improves fits for more highly shocked basalt. However, deconvolution models of the basaltic andesite select shocked feldspar end-members even for unshocked samples, likely caused by the higher primary glass content in the basaltic andesite sample.

  5. Thermal removal from near-infrared imaging spectroscopy data of the Moon

    Science.gov (United States)

    Clark, Roger N.; Pieters, Carle M.; Green, Robert O.; Boardman, J.W.; Petro, Noah E.

    2011-01-01

    In the near-infrared from about 2 μm to beyond 3 μm, the light from the Moon is a combination of reflected sunlight and emitted thermal emission. There are multiple complexities in separating the two signals, including knowledge of the local solar incidence angle due to topography, phase angle dependencies, emissivity, and instrument calibration. Thermal emission adds to apparent reflectance, and because the emission's contribution increases over the reflected sunlight with increasing wavelength, absorption bands in the lunar reflectance spectra can be modified. In particular, the shape of the 2 μm pyroxene band can be distorted by thermal emission, changing spectrally determined pyroxene composition and abundance. Because of the thermal emission contribution, water and hydroxyl absorptions are reduced in strength, lowering apparent abundances. It is important to quantify and remove the thermal emission for these reasons. We developed a method for deriving the temperature and emissivity from spectra of the lunar surface and removing the thermal emission in the near infrared. The method is fast enough that it can be applied to imaging spectroscopy data on the Moon.

  6. Thermal Breakdown Kinetics of 1-Ethyl-3-Methylimidazolium Ethylsulfate Measured Using Quantitative Infrared Spectroscopy.

    Science.gov (United States)

    Wheeler, Jeffrey L; Pugh, McKinley; Atkins, S Jake; Porter, Jason M

    2017-12-01

    In this work, the thermal stability of the room temperature ionic liquid (RTIL) 1-ethyl-3-methylimidazolium ethylsulfate ([EMIM][EtSO4]) is investigated using infrared (IR) spectroscopy. Quantitative IR absorption spectral data are measured for heated [EMIM][EtSO4]. Spectra have been collected between 25 ℃ and 100 ℃ using a heated optical cell. Multiple samples and cell pathlengths are used to determine quantitative values for the molar absorptivity of [EMIM][EtSO4]. These results are compared to previous computational models of the ion pair. These quantitative spectra are used to measure the rate of thermal decomposition of [EMIM][EtSO4] at elevated temperatures. The spectroscopic measurements of the rate of decomposition show that thermogravimetric methods overestimate the thermal stability of [EMIM][EtSO4].

  7. Near-near-infrared thermal lens spectroscopy to assess overtones and combination bands of sulfentrazone pesticide

    Science.gov (United States)

    Ventura, M.; Silva, J. R.; Andrade, L. H. C.; Scorza Júnior, R. P.; Lima, S. M.

    2018-01-01

    Thermal lens spectroscopy (TLS) in the near-near-infrared region was used to explore the absorptions of overtones and combination bands of sulfentrazone (SFZ) herbicide diluted in methanol. This spectroscopic region was chosen in order to guarantee that only thermal lens effect is noted during the experimental procedure. The results showed that it was possible to detect very low concentrations ( 2 ng/μL) of SFZ in methanol by determining its thermal diffusivity or the absorption coefficient due to the 3ν(NH) + 1δ(CH) combination band. This minimum SFZ concentration is the limit observed by chromatography method. The findings demonstrated that the TLS can be used for precise and accurate assessment of pesticides in ecosystems. Besides, the 3ν(NH) + 1δ(CH) combination band at 960 nm can be used as a marker for SFZ in methanol.

  8. Non-Destructive Evaluation of Polyolefin Thermal Aging Using Infrared Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Fifield, Leonard S.; Shin, Yongsoon; Simmons, Kevin L.

    2017-04-19

    Fourier transform infrared (FTIR) spectroscopy is an information-rich method that reveals chemical bonding near the surface of polymer composites. FTIR can be used to verify composite composition, identify chemical contaminants and expose composite moisture content. Polymer matrix changes due to thermal exposure including loss of additives, chain scission, oxidation and changes in crystallinity may also be determined using FTIR spectra. Portable handheld instruments using non-contact reflectance or surface contact attenuated total reflectance (ATR) may be used for non-destructive evaluation (NDE) of thermal aging in polymer and composite materials of in-service components. We report the use of ATR FTIR to track oxidative thermal aging in ethylene-propylene rubber (EPR) and chlorinated polyethylene (CPE) materials used in medium voltage nuclear power plant electrical cable insulation and jacketing. Mechanical property changes of the EPR and CPE materials with thermal degradation for correlation with FTIR data are tracked using indenter modulus (IM) testing. IM is often used as a local NDE metric of cable jacket health. The FTIR-determined carbonyl index was found to increase with IM and may be a valuable NDE metric with advantages over IM for assessing cable remaining useful life.

  9. Non-destructive evaluation of polyolefin thermal aging using infrared spectroscopy

    Science.gov (United States)

    Fifield, Leonard S.; Shin, Yongsoon; Simmons, Kevin L.

    2017-04-01

    Fourier transform infrared (FTIR) spectroscopy is an information-rich method that reveals chemical bonding near the surface of polymer composites. FTIR can be used to verify composite composition, identify chemical contaminants and expose composite moisture content. Polymer matrix changes due to thermal exposure including loss of additives, chain scission, oxidation and changes in crystallinity may also be determined using FTIR spectra. Portable handheld instruments using non-contact reflectance or surface contact attenuated total reflectance (ATR) may be used for nondestructive evaluation (NDE) of thermal aging in polymer and composite materials of in-service components. We report the use of ATR FTIR to track oxidative thermal aging in ethylene-propylene rubber (EPR) and chlorinated polyethylene (CPE) materials used in medium voltage nuclear power plant electrical cable insulation and jacketing. Mechanical property changes of the EPR and CPE materials with thermal degradation for correlation with FTIR data are tracked using indenter modulus (IM) testing. IM is often used as a local NDE metric of cable jacket health. The FTIR-determined carbonyl index was found to increase with IM and may be a valuable NDE metric with advantages over IM for assessing cable remaining useful life.

  10. Thermal Infrared Emission Spectroscopy of Synthetic Allophane and its Potential Formation on Mars

    Science.gov (United States)

    Rampe, E. B.; Kraft, M. D.; Sharp, T. G.; Golden, D. C.; Ming, Douglas W.

    2010-01-01

    Allophane is a poorly-crystalline, hydrous aluminosilicate with variable Si/Al ratios approx.0.5-1 and a metastable precursor of clay minerals. On Earth, it forms rapidly by aqueous alteration of volcanic glass under neutral to slightly acidic conditions [1]. Based on in situ chemical measurements and the identification of alteration phases [2-4], the Martian surface is interpreted to have been chemically weathered on local to regional scales. Chemical models of altered surfaces detected by the Mars Exploration Rover Spirit in Gusev crater suggest the presence of an allophane-like alteration product [3]. Thermal infrared (TIR) spectroscopy and spectral deconvolution models are primary tools for determining the mineralogy of the Martian surface [5]. Spectral models of data from the Thermal Emission Spectrometer (TES) indicate a global compositional dichotomy, where high latitudes tend to be enriched in a high-silica material [6,7], interpreted as high-silica, K-rich volcanic glass [6,8]. However, later interpretations proposed that the high-silica material may be an alteration product (such as amorphous silica, clay minerals, or allophane) and that high latitude surfaces are chemically weathered [9-11]. A TIR spectral library of pure minerals is available for the public [12], but it does not contain allophane spectra. The identification of allophane on the Martian surface would indicate high water activity at the time of its formation and would help constrain the aqueous alteration environment [13,14]. The addition of allophane to the spectral library is necessary to address the global compositional dichotomy. In this study, we characterize a synthetic allophane by IR spectroscopy, X-ray diffraction (XRD), and transmission electron microscopy (TEM) to create an IR emission spectrum of pure allophane for the Mars science community to use in Martian spectral models.

  11. Characterization of different compost extracts using Fourier-transform infrared spectroscopy (FTIR) and thermal analysis.

    Science.gov (United States)

    Carballo, Teresa; Gil, Ma Victoria; Gómez, Xiomar; González-Andrés, Fernando; Morán, Antonio

    2008-11-01

    Compost extract or "compost tea" is a liquid extract of compost obtained by mixing compost and water for a defined period of time. Compost tea contains nutrients and a range of different organisms and is applied to the soil or directly to plants with the principal aim of suppressing certain plant diseases. In addition, the application of compost tea supplies nutrients and organic matter to the soil. Thermal analysis and Fourier transform infrared spectroscopy (FTIR) are two widely applied analytical techniques for establishing the stability of compost, and although numerous studies have evaluated the capacity of compost tea to suppress plant diseases, there are no studies employing these techniques to characterize compost-tea. For the present study, 12 compost extracts were produced under varying conditions in a purpose-built reactor. Two different composts, an stable compost produced from manure and an unstable compost produced from municipal solid waste, respectively, two aeration systems (aerated and non-aerated extracts) and three temperatures (10, 20 and 30 degrees C) were used in these experiments. The extracts were freeze-dried and subsequently analysed, together with the two composts, by means of FTIR and thermal analysis. Extracts produced from high stability compost, independently of the conditions of aeration and temperature, showed very similar results. In contrast, differences among extracts produced from the unstable compost were more noticeable. However, the different conditions of aeration and temperature during the production of the extracts only explained partially these differences, since the transformations undergone by compost over the 3 months that the experiments lasted were also reflected in the composition of the extracts. In spite of everything, extraction process favoured the degradation of easily oxidizable organic matter, which was more abundant in unstable compost. This degradation was more intense for non-aerated processes, probably

  12. Infrared absorption spectroscopy of carbon monoxide on nickel films: a low temperature thermal detection technique

    Energy Technology Data Exchange (ETDEWEB)

    Bailey, R.B.

    1978-11-01

    Sensitive vibrational spectra of carbon monoxide molecules adsorbed on evaporated nickel films have been measured by attaching a thermometer to the sample, cooling the assembly to liquid helium temperatures, and recording the temperature changes which occur when infrared radiation is absorbed. The measurements are made in an ultrahigh vacuum chamber in which the sample surface can be cleaned, heated, exposed to gas molecules and cooled to 1.6 K for the infrared measurements. The spectra of chemisorbed CO molecules are interpreted in terms of the linear and bridge adsorption sites on the nickel surface, and they show how the distribution of molecules among these sites changes when the CO coverage increases and intermolecular forces become important. The spectra of physically adsorbed molecules in both monolayer and multilayer films are also reported. Absorptions as small as five parts in 10/sup 5/ of the incident radiation can presently be detected in spectra covering broad bands of infrared frequencies with a resolution of 2 cm/sup -1/. This high sensitivity is attributable to the low noise and reduced background signal of the thermal detection scheme, to the stability of the rapid scan Fourier transform infrared spectrometer, and to the automated computerized data acquisition electronics. Better performance is expected in future experiments on single crystal samples as well as evaporated films. This will make it possible to study molecules with weaker absorptions than CO and to look for evidence of chemical reactions between different adsorbed molecules.

  13. Encapsulation of paclitaxel into a bio-nanocomposite. A study combining inelastic neutron scattering to thermal analysis and infrared spectroscopy

    Science.gov (United States)

    Martins, Murillo L.; Orecchini, Andrea; Aguilera, Luis; Eckert, Juergen; Embs, Jan; Matic, Aleksander; Saeki, Margarida J.; Bordallo, Heloisa N.

    2015-01-01

    The anticancer drug paclitaxel was encapsulated into a bio-nanocomposite formed by magnetic nanoparticles, chitosan and apatite. The aim of this drug carrier is to provide a new perspective against breast cancer. The dynamics of the pure and encapsulated drug were investigated in order to verify possible molecular changes caused by the encapsulation, as well as to follow which interactions may occur between paclitaxel and the composite. Fourier transformed infrared spectroscopy, thermal analysis, inelastic and quasi-elastic neutron scattering experiments were performed. These very preliminary results suggest the successful encapsulation of the drug.

  14. Ultrafast infrared vibrational spectroscopy

    CERN Document Server

    Fayer, Michael D

    2013-01-01

    The past ten years or so have seen the introduction of multidimensional methods into infrared and optical spectroscopy. The technology of multidimensional spectroscopy is developing rapidly and its applications are spreading to biology and materials science. Edited by a recognized leader in the field and with contributions from top researchers, including experimentalists and theoreticians, this book presents the latest research methods and results and will serve as an excellent resource for other researchers.

  15. Large-Scale Production of V6O13 Cathode Materials Assisted by Thermal Gravimetric Analysis-Infrared Spectroscopy Technology.

    Science.gov (United States)

    Liang, Han-Pu; Du, Jian; Jones, Timothy G J; Lawrence, Nathan S; Meredith, Andrew W

    2016-10-05

    The kilogram-scale fabrication of V6O13 cathode materials has been notably assisted by in situ thermal gravimetric analysis (TGA)-infrared spectroscopy (IR) technology. This technology successfully identified a residue of ammonium metavanadate in commercial V6O13, which is consistent with the X-ray photoelectron spectroscopy result. Samples of V6O13 materials have been fabricated and characterized by TGA-IR, scanning electron microscopy, and X-ray diffraction. The initial testing results at 125 °C have shown that test cells containing the sample prepared at 500 °C show up to a 10% increase in the initial specific capacity in comparison with commercial V6O13.

  16. Thermal behavior of silicone rubber-based ceramizable composites characterized by Fourier transform infrared (FT-IR) spectroscopy and microcalorimetry.

    Science.gov (United States)

    Anyszka, Rafał; Bieliński, Dariusz M; Jędrzejczyk, Marcin

    2013-12-01

    Ceramizable (ceramifiable) silicone rubber-based composites are commonly used for cable insulation. These materials are able to create a protective ceramic layer during fire due to the ceramization process, which occurs at high temperature. When the temperature is increased, the polymer matrix is degraded and filler particles stick together by the fluxing agent, producing a solid, continuous ceramic phase that protects the copper wire from heat and mechanical stress. Despite increasing interest in these materials that has resulted in growing applications in the cable industry, their thermal behavior and ceramization process are still insufficiently described in the literature. In this paper, the thermal behavior of ceramizable silicone rubber-based composites is studied using microcalorimetry and Fourier transform infrared spectroscopy. The analysis of the experimental data made it possible to develop complete information on the mechanism of composite ceramization.

  17. Dust coatings on basaltic rocks and implications for thermal infrared spectroscopy of Mars

    Science.gov (United States)

    Johnson, J. R.; Christensen, P.R.; Lucey, P.G.

    2002-01-01

    Thin coatings of atmospherically deposited dust can mask the spectral characteristics of underlying surfaces on Mars from the visible to thermal infrared wavelengths, making identification of substrate and coating mineralogy difficult from lander and orbiter spectrometer data. To study the spectral effects of dust coatings, we acquired thermal emission and hemispherical reflectance spectra (5-25 μm; 2000-400 cm-1) of basaltic andesite coated with different thicknesses of air fall-deposited palagonitic soils, fine-grained ceramic clay powders, and terrestrial loess. The results show that thin coatings (10-20 μm) reduce the spectral contrast of the rock substrate substantially, consistent with previous work. This contrast reduction continues linearly with increasing coating thickness until a "saturation thickness" is reached, after which little further change is observed. The saturation thickness of the spectrally flat palagonite coatings is ~100-120 μm, whereas that for coatings with higher spectral contrast is only ~50-75 μm. Spectral differences among coated and uncoated samples correlate with measured coating thicknesses in a quadratic manner, whereas correlations with estimated surface area coverage are better fit by linear functions. Linear mixture modeling of coated samples using the rock substrate and coating materials as end-members is also consistent with their measured coating thicknesses and areal coverage. A comparison of ratios of Thermal Emission Spectrometer (TES) spectra of dark and bright intracrater and windstreak deposits associated with Radau crater suggests that the dark windstreak material may be coated with as much as 90% areal coverage of palagonitic dust. The data presented here also will help improve interpretations of upcoming mini-TES and Thermal Emission Imaging System (THEMIS) observations of coated Mars surface materials.

  18. Using Fourier Transform Near-Infrared Spectroscopy to Predict the Mechanical Properties of Thermally Modified Southern Pine Wood.

    Science.gov (United States)

    Tong, Li; Zhang, Wenbo

    2016-06-08

    This study seeks to estimate the mechanical properties of thermally modified wood (TMW) by using near-infrared (NIR) spectroscopy to measure 80 samples in three-point bending tests. Near-infrared spectra collected from the transverse, radial, and tangential sections of wood, coupled with chemometric techniques, were used to predict the mechanical properties of southern pine wood, from which NIR models were constructed based on partial least squares and corresponding cross-validation. The coefficient of determination between NIR transverse section spectra, as well as two mechanical properties of wood samples, modulus of rupture (MOR) and modulus of elasticity (MOE), were above 0.92 and greater than values for other sections. Spectral data from the transverse sections were richer than data from other sections, and thus, a model based on transverse sections better predicts the mechanical properties of wood. A close relationship between the values for mechanical properties (MOE and MOR) and the NIR spectra of thermally modified southern pine wood can be demonstrated, which provides the potential to predict the mechanical properties of untreated and thermally modified wood. © The Author(s) 2016.

  19. Thermal infrared spectroscopy of experimentally shocked anorthosite and pyroxenite: Implications for remote sensing of Mars

    Science.gov (United States)

    Johnson, J. R.; Horz, F.; Lucey, P.G.; Christensen, P.R.

    2002-01-01

    The feldspar and pyroxene mineralogies on Mars revealed by the Thermal Emission Spectrometer (TES) on Mars Global Surveyor likely record a variety of shock effects, as suggested by petrologic analyses of the Martian meteorites and the abundance of impact craters on the planet's surface. To study the effects of shock pressures on thermal infrared spectra of these minerals, we performed shock recovery experiments on orthopyroxenite and anorthosite samples from the Stillwater Complex (Montana) over peak pressures from 17 to 63 GPa. We acquired emissivity and hemispherical reflectance spectra (350-1400 cm-1; ???7-29 ??m) of both coherent chips and fine-grained powders of shocked and unshocked samples. These spectra are more directly comparable to remotely sensed data of Mars (e.g., TES) than previously acquired absorption or transmission spectra of shocked minerals. The spectra of experimentally shocked feldspar show systematic changes with increasing pressure due to depolymerization of the silica tetrahedra. For the spectra of chips, this includes the disappearance of small bands in the 500-650 cm-1 region and a strong band at 1115 cm-1, and changes in positions of a strong band near 940 cm-1 and the Christiansen feature near 1250 cm-1. Spectra of the shocked powders show the gradual disappearance of a transparency feature near 830 cm-1. Fewer changes are observed in the pyroxene spectra at pressures as high as 63 GPa. Spectra of experimentally shocked minerals will help identify more precisely the mineralogy of rocks and soils not only from TES but also from Mars instruments such as miniTES and THEMIS.

  20. Investigation of adulteration of sunflower oil with thermally deteriorated oil using Fourier transform mid-infrared spectroscopy and chemometrics

    Directory of Open Access Journals (Sweden)

    Joana Vilela

    2015-12-01

    Full Text Available Fourier transform infrared spectroscopy based on attenuated total reflectance sampling technique, combined with multivariate analysis methods was used to monitor the adulteration of pure sunflower oil (SO with thermally deteriorated oil (TDO. Contrary to published research, in this work, SO was thermally deteriorated in the absence of foodstuff. SO samples were exposed to temperatures between 125 and 225°C from 6 to 24 h. Quantification of adulteration of SO with TDO, based on principal components regression (PCR, partial least squares regression (PLS-R, and linear discriminant analysis (LDA applied to mid-infrared spectra and to their first and second derivatives is reported for the first time. Infrared frequencies associated with the biochemical differences between TDO samples deteriorated in different conditions were investigated by principal component analysis (PCA. LDA was effective in the twofold classification presence/absence of TDO in adulterated SO (with 5% V/V of less of TDO. It provided 93.7% correct classification for the calibration set and 91.3% correct classification when cross-validated. A detection limit of 1% V/V of TDO in SO was determined. Investigation of an external set of samples allowed the evaluation of the predictability of the models. The regression coefficient (R2 for prediction was 0.95 and 0.96 and the RMSE was 2.1 and 1.9% V/V when using the PCR or PLS-R models, respectively, and the first derivative of spectra. To the best of our knowledge, no investigation of adulteration of SO with TDO based on PCR, PLS-R, and LDA has been reported so far.

  1. Characterization of Thermal Oxides on 4H-SiC Epitaxial Substrates Using Fourier-Transform Infrared Spectroscopy.

    Science.gov (United States)

    Seki, Hirofumi; Yoshikawa, Masanobu; Kobayashi, Takuma; Kimoto, Tsunenobu; Ozaki, Yukihiro

    2017-05-01

    Fourier transform infrared (FT-IR) spectra were measured for thermal oxides with different electrical properties grown on 4H-SiC substrates. The peak frequency of the transverse optical (TO) phonon mode was blue-shifted by 5 cm-1 as the oxide-layer thickness decreased to 3 nm. The blue shift of the TO mode indicates interfacial compressive stress in the oxide. Comparison of data for the oxide on a SiC substrate with that for similar oxides on a Si substrate implies that the peak shift of the TO mode at the SiO2/SiC interface is larger than that of SiO2/Si, which suggests that the interfacial stress for the oxide on the SiC substrate is larger than that on the Si substrate. For the SiO2/SiC interfacial region (Fourier transform infrared spectroscopy measurements provide unique and useful information about stress and inhomogeneity at the oxide/SiC interface.

  2. Mid-infrared upconversion spectroscopy

    DEFF Research Database (Denmark)

    Tidemand-Lichtenberg, Peter; Dam, Jeppe Seidelin; Andersen, H. V.

    2016-01-01

    Mid-infrared (MIR) spectroscopy is emerging as an attractive alternative to near-infrared or visible spectroscopy. MIR spectroscopy offers a unique possibility to probe the fundamental absorption bands of a large number of gases as well as the vibrational spectra of complex molecules. In this paper...

  3. Thermal Infrared Emission Spectroscopy of Synthetic Allophane and Its Potential Formation on Mars

    Science.gov (United States)

    Rampe, E. B.; Kraft, M. D.; Sharp, T. G.; Golden, D. C.; Ming, D. W.

    2010-03-01

    We synthesized allophane, a terrestrial aqueous alteration product, and measured a thermal IR emission spectrum for the public spectral library. The use of this spectrum in martian spectral models can help constrain chemical alteration environments.

  4. Investigation of human frontal cortex under noxious thermal stimulation of temporo-mandibular joint using functional near infrared spectroscopy

    Science.gov (United States)

    Yennu, Amarnath; Rawat, Rohit; Manry, Michael T.; Gatchel, Robert; Liu, Hanli

    2013-03-01

    According to American Academy of Orofacial Pain, 75% of the U.S. population experiences painful symptoms of temporo-mandibular joint and muscle disorder (TMJMD) during their lifetime. Thus, objective assessment of pain is crucial for efficient pain management. We used near infrared spectroscopy (NIRS) as a tool to explore hemodynamic responses in the frontal cortex to noxious thermal stimulation of temporomadibular joint (TMJ). NIRS experiments were performed on 9 healthy volunteers under both low pain stimulation (LPS) and high pain stimulation (HPS), using a temperature-controlled thermal stimulator. To induce thermal pain, a 16X16 mm2 thermode was strapped onto the right TMJ of each subject. Initially, subjects were asked to rate perceived pain on a scale of 0 to 10 for the temperatures from 41°C to 47°C. For the NIRS measurement, two magnitudes of temperatures, one rated as 3 and another rated as 7, were chosen as LPS and HPS, respectively. By analyzing the temporal profiles of changes in oxy-hemoglobin concentration (HbO) using cluster-based statistical tests, we were able to identify several regions of interest (ROI), (e.g., secondary somatosensory cortex and prefrontal cortex), where significant differences (ppain, a neural-network-based classification algorithm was used. With leave-one-out cross validation from 9 subjects, the two levels of pain were identified with 100% mean sensitivity, 98% mean specificity and 99% mean accuracy to high pain. From the receiver operating characteristics curve, 0.99 mean area under curve was observed.

  5. Near-infrared spectroscopy

    Directory of Open Access Journals (Sweden)

    Virendra Jain

    2015-01-01

    Full Text Available Tissue ischaemia can be a significant contributor to increased morbidity and mortality. Conventional oxygenation monitoring modalities measure systemic oxygenation, but regional tissue oxygenation is not monitored. Near-infrared spectroscopy (NIRS is a non-invasive monitor for measuring regional oxygen saturation which provides real-time information. There has been increased interest in the clinical application of NIRS following numerous studies that show improved outcome in various clinical situations especially cardiac surgery. Its use has shown improved neurological outcome and decreased postoperative stay in cardiac surgery. Its usefulness has been investigated in various high risk surgeries such as carotid endarterectomy, thoracic surgeries, paediatric population and has shown promising results. There is however, limited data supporting its role in neurosurgical population. We strongly feel, it might play a key role in future. It has significant advantages over other neuromonitoring modalities, but more technological advances are needed before it can be used more widely into clinical practice.

  6. Semiconductor optoelectronic infrared spectroscopy

    CERN Document Server

    Hollingworth, A R

    2001-01-01

    level separation. This showed for the first time evidence of the phonon bottleneck in a working laser device. A new technique called time resolved optically detected cyclotron resonance, was used as a precursor to finding the carrier dynamics within a spatially confined quantum dot. By moving to the case of a spatial QD using an optically detected intraband resonance it was possible to measure the energy separation interband levels and conduction and valence sublevels within the dot simultaneously. Furthermore this technique has been shown that the inhomogeneous broadening of the photoluminescence spectrum is not purely affected by just size and composition. We suggest that other processes such as state occupancy, In roughing, and exciton binding energies may account for the extra energy. We use spectroscopy to study infrared optoelectronic inter and intraband semiconductor carrier dynamics. The overall aim of this thesis was to study both III-V and Pb chalcogenide material systems in order to show their futu...

  7. Detection of Allophane on Mars Through Orbital and In-Situ Thermal-Infrared Spectroscopy

    Science.gov (United States)

    Rampe, E. B.; Kraft, M. D.; Sharp, T. G.; Golden, D. C.; Ming, Douglas W.

    2011-01-01

    We have collected laboratory thermal IR spectra of the mineraloid allophane and aluminosilicate gels. Using those spectra to model regional TES spectra, we suggest that several areas of Mars contain significant amounts of allophane-like weathering products. The presence of allophane on Mars indicates that 1) significant Al sources, such as feldspar or glass, were weathered; 2) weathering on Mars produced poorly-crystalline aluminosilicates, rather than easily identifiable crystalline minerals; and 3) some Martian weathering proceeded under moderate pH environments, suggesting acid weathering is not the only major alteration mechanism on Mars.

  8. Infrared spectroscopy of stars

    Science.gov (United States)

    Merrill, K. M.; Ridgway, S. T.

    1979-01-01

    This paper reviews applications of IR techniques in stellar classification, studies of stellar photospheres, elemental and isotopic abundances, and the nature of remnant and ejected matter in near-circumstellar regions. Qualitative IR spectral classification of cool and hot stars is discussed, along with IR spectra of peculiar composite star systems and of obscured stars, and IR characteristics of stellar populations. The use of IR spectroscopy in theoretical modeling of stellar atmospheres is examined, IR indicators of stellar atmospheric composition are described, and contributions of IR spectroscopy to the study of stellar recycling of interstellar matter are summarized. The future of IR astronomy is also considered.

  9. The infrared spectroscopy in the study of the bone crystallinity thermally affected; La espectroscopia infrarroja en el estudio de la cristalinidad del hueso afectado termicamente

    Energy Technology Data Exchange (ETDEWEB)

    Medina, C.; Tiesler, V. [Universidad Autonoma de Yucatan, Facultad de Ciencias Antropoloicas. 97000 Merida, Yucatan (Mexico); Azamar, J.A.; Alvarado G, J.J.; Quintana, P. [CINVESTAV-Unidad Merida, Depto. Fisica Aplicada, Km 6 Ant. Carr. a Progreso, 97310 Merida, Yucatan (Mexico)

    2006-07-01

    Bone is made up by both organic and inorganic components. Among the latter stands out hydroxyapatite (HAP), composed by hexagonal crystallites arranged in a laminar form. The size of the hydroxyapatite crystals may be altered by different conditions, among those figures thermal exhibition, since during burning the bone eliminates organic matrix and thus promotes the crystallization process of the material. An experimental series was designed to measure crystallinity, in which pig bone remains were burnt at different temperatures and analyzed by infrared spectroscopy (FTIR). By means of analogy a comparison was made between the infrared spectra in order to compare with the ones obtained from the archaeological samples, coming from the Classic period Maya sites of Calakmul and Becan, Campeche. (Author)

  10. Landsat and Thermal Infrared Imaging

    Science.gov (United States)

    Arvidson, Terry; Barsi, Julia; Jhabvala, Murzy; Reuter, Dennis

    2012-01-01

    The purpose of this chapter is to describe the collection of thermal images by Landsat sensors already on orbit and to introduce the new thermal sensor to be launched in 2013. The chapter describes the thematic mapper (TM) and enhanced thematic mapper plus (ETM+) sensors, the calibration of their thermal bands, and the design and prelaunch calibration of the new thermal infrared sensor (TIRS).

  11. Explosive detection using infrared laser spectroscopy

    Science.gov (United States)

    Hildenbrand, J.; Herbst, J.; Wöllenstein, J.; Lambrecht, A.

    2009-01-01

    Stand-off and extractive explosive detection methods for short distances are investigated using mid-infrared laser spectroscopy. A quantum cascade laser (QCL) system for TATP-detection by open path absorption spectroscopy in the gas phase was developed. In laboratory measurements a detection limit of 5 ppm*m was achieved. For explosives with lower vapor pressure an extractive hollow fiber based measurement system was investigated. By thermal desorption gaseous TATP or TNT is introduced into a heated fiber. The small sample volume and a fast gas exchange rate enable fast detection. TNT and TATP detection levels below 100 ng are feasible even in samples with a realistic contaminant background.

  12. MgB2-Based Bolometer Array for Far Infra-Red Thermal Imaging and Fourier Transform Spectroscopy Applications

    Science.gov (United States)

    Lakew, B.; Aslam, S.; Brasunas, J.

    2012-01-01

    The mid-superconducting critical temperature (T(sub c) approximately 39 K) of the simple binary, intermetallic MgB, [1] makes it a very good candidate for the development of the next generation of electrooptical devices (e.g. [2]). In particular, recent advances in thin film deposition teclmiques to attain higb quality polycrystalline thin film MgB, deposited on SiN-Si substrates, with T(sub c) approximately 38K [3] coupled with the low voltage noise performance of the film [4] makes it higbly desirable for the development of moderately cooled bolometer arrays for integration into future space-bourne far infra-red (FIR) spectrometers and thermal mappers for studying the outer planets, their icy moons and other moons of interest in the 17-250 micrometer spectral wavelength range. Presently, commercially available pyroelectric detectors operating at 300 K have specific detectivity, D(*), around 7 x 10(exp 8) to 2 x 10(exp 9) centimeters square root of Hz/W. However, a MgB2 thin film based bolometer using a low-stress (less than 140 MPa) SiN membrane isolated from the substrate by a small thermal conductive link, operating at 38 K, promises to have two orders of magnitude higher specific detectivity [5][6].

  13. INSTRUMENTATION FOR FAR INFRARED SPECTROSCOPY.

    Energy Technology Data Exchange (ETDEWEB)

    GRIFFITHS, P.R.; HOMES, C.

    2001-05-04

    Fourier transform spectrometers developed in three distinct spectral regions in the early 1960s. Pierre Connes and his coworkers in France developed remarkably sophisticated step-scan interferometers that permitted near-infrared spectra to be measured with a resolution of better than 0.0 1 cm{sup {minus}1}. These instruments may be considered the forerunners of the step-scan interferometers made by Bruker, Bio-Rad (Cambridge, MA, USA) and Nicolet although their principal application was in the field of astronomy. Low-resolution rapid-scanning interferometers were developed by Larry Mertz and his colleagues at Block Engineering (Cambridge, MA, USA) for remote sensing. Nonetheless, the FT-IR spectrometers that are so prevalent in chemical laboratories today are direct descendants of these instruments. The interferometers that were developed for far-infrared spectrometry in Gebbie's laboratory ,have had no commercial counterparts for at least 15 years. However, it could be argued that these instruments did as much to demonstrate the power of Fourier transform spectroscopy to the chemical community as any of the instruments developed for mid- and near-infrared spectrometry. Their performance was every bit as good as today's rapid-scanning interferometers. However, the market for these instruments is so small today that it has proved more lucrative to modify rapid-scanning interferometers that were originally designed for mid-infrared spectrometry than to compete with these instruments with slow continuous scan or step-scan interferometers.

  14. Infrared thermal imaging in medicine.

    Science.gov (United States)

    Ring, E F J; Ammer, K

    2012-03-01

    This review describes the features of modern infrared imaging technology and the standardization protocols for thermal imaging in medicine. The technique essentially uses naturally emitted infrared radiation from the skin surface. Recent studies have investigated the influence of equipment and the methods of image recording. The credibility and acceptance of thermal imaging in medicine is subject to critical use of the technology and proper understanding of thermal physiology. Finally, we review established and evolving medical applications for thermal imaging, including inflammatory diseases, complex regional pain syndrome and Raynaud's phenomenon. Recent interest in the potential applications for fever screening is described, and some other areas of medicine where some research papers have included thermal imaging as an assessment modality. In certain applications thermal imaging is shown to provide objective measurement of temperature changes that are clinically significant.

  15. Drill hole logging with infrared spectroscopy

    Science.gov (United States)

    Calvin, W.M.; Solum, J.G.

    2005-01-01

    Infrared spectroscopy has been used to identify rocks and minerals for over 40 years. The technique is sensitive to primary silicates as well as alteration products. Minerals can be uniquely identified based on multiple absorption features at wavelengths from the visible to the thermal infrared. We are currently establishing methods and protocols in order to use the technique for rapid assessment of downhole lithology on samples obtained during drilling operations. Initial work performed includes spectral analysis of chip cuttings and core sections from drill sites around Desert Peak, NV. In this paper, we report on a survey of 10,000 feet of drill cuttings, at 100 foot intervals, from the San Andreas Fault Observatory at Depth (SAFOD). Data from Blue Mountain geothermal wells will also be acquired. We will describe the utility of the technique for rapid assessment of lithologic and mineralogic discrimination.

  16. Thermal Properties of Extruded Injection-Molded Polycaprolactone/Gluten Bioblends Characterized by TGA, DSC, SEM and Infrared Photoacoustic Spectroscopy

    Science.gov (United States)

    In order to determine the degree of compatibility between Polycaprolactone resin (PCL) and vital wheat gluten (VG), PCL was compounded with VG at 90:10, 80:20, 70:30, 60:40, 50:50, and 30:70. The composites were blended by extrusion followed by injection molding. Thermal, morphological, and struct...

  17. Identification of ageing biomarkers in human dermis biopsies by thermal analysis (DSC) combined with Fourier transform infrared spectroscopy (FTIR/ATR).

    Science.gov (United States)

    Tang, R; Samouillan, V; Dandurand, J; Lacabanne, C; Lacoste-Ferre, M-H; Bogdanowicz, P; Bianchi, P; Villaret, A; Nadal-Wollbold, F

    2017-11-01

    The purpose of this clinical study was to identify suitable biomarkers for a better understanding of the molecular and organizational changes in human dermis during intrinsic and extrinsic ageing. Sun-exposed and non-exposed skin biopsies were collected from twenty-eight women devised in two groups (20-30 and ≥60 years old). The hydric organization and thermal transitions were determined by Differential Scanning Calorimetry (DSC). Fourier Transform Infrared spectroscopy (FTIR) was used to identify the absorption bands of the dermis and to quantify the different absorbance ratio. The amounts of total, freezable and unfreezable water were determined. A significant increasing amount of freezable water is evidenced in sun-exposed area skin of aged group compared with young group (P=.0126). Another significant effect of extrinsic ageing (P=.0489) is the drastic decrease of fibrillary collagen, the main protein component of dermis. The only significant effect of intrinsic ageing (P=.0184) is an increase of the heat-stable fraction of collagens in dermis. DSC and FTIR are well-suited techniques to characterize human skin, giving accurate results with a high reproducibility. The combination of these techniques is useful for a better understanding of human skin modifications with intrinsic and extrinsic ageing. © 2017 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

  18. Infrared and Raman spectroscopy: principles and spectral interpretation

    National Research Council Canada - National Science Library

    Larkin, Peter

    2011-01-01

    "Infrared and Raman Spectroscopy: Principles and Spectral Interpretation explains the background, core principles and tests the readers understanding of the important techniques of Infrared and Raman Spectroscopy...

  19. Fourier Transform Infrared Spectroscopy Part III. Applications.

    Science.gov (United States)

    Perkins, W. D.

    1987-01-01

    Discusses the use of the FT-IR spectrometer in analyses that were previously avoided. Examines some of the applications of this spectroscopy with aqueous solutions, circular internal reflection, samples with low transmission, diffuse reflectance, infrared emission, and the infrared microscope. (TW)

  20. Near infrared spectroscopy and exercise

    Energy Technology Data Exchange (ETDEWEB)

    Angus, Caroline

    2002-07-01

    Near infrared spectroscopy (NIRS) provides a non-invasive method for the continuous monitoring of changes in tissue oxygenation and blood volume during aerobic exercise. During incremental exercise in adult subjects there was a positive correlation between lactate threshold (measured by blood sampling) and changes in the rate of muscle deoxygenation (measured by NIRS). However, the 7% failure rate for the NIRS test mitigated against the general use of this method. NIRS did not provide a valid method for LT determination in an adolescent population. NIRS was then used to examine whether haemodynamic changes could be a contributing factor to the mechanism underlying the cross-transfer effect. During a one-legged incremental aerobic exercise test the muscle was more deoxygenated in the exercising leg than in the non-exercising leg, consistent with oxygen consumption outstripping blood flow to the exercising limb. However, muscle blood volume increased equally in both legs. This suggests that blood flow may be raised to similar levels in both the legs; although local factors may signal an increase in blood volume, this effect is expressed in both legs. Muscle blood flow and changes in muscle blood volume were then measured directly by NIRS during an incremental one-arm aerobic exercise test. There was no significant difference in either blood volume or blood flow in the two arms at the end of the test. In the non-exercising arm changes in blood flow and blood volume were measured throughout the protocol. At higher exercise intensities, blood volume continued to rise as muscle blood flow plateaued, indicating that blood volume changes become independent of changes in blood flow. Finally, the effect of different training regimes on changes in muscle blood volume was examined. Subjects were assigned to a training group; two-arm training, one-arm training or a control group. Training did not affect blood volume changes during two-arm exercise. However, during one

  1. Low-thermal expansion infrared glass ceramics

    Science.gov (United States)

    Lam, Philip

    2009-05-01

    L2 Tech, Inc. is in development of an innovative infrared-transparent glass ceramic material with low-thermal expansion (ZrW2O8) which has Negative Thermal Expansion (NTE). The glass phase is the infrared-transparent germanate glass which has positive thermal expansion (PTE). Then glass ceramic material has a balanced thermal expansion of near zero. The crystal structure is cubic and the thermal expansion of the glass ceramic is isotropic or equal in all directions.

  2. Thermal Infrared Anomalies of Several Strong Earthquakes

    OpenAIRE

    Congxin Wei; Yuansheng Zhang; Xiao Guo; Shaoxing Hui; Manzhong Qin; Ying Zhang

    2013-01-01

    In the history of earthquake thermal infrared research, it is undeniable that before and after strong earthquakes there are significant thermal infrared anomalies which have been interpreted as preseismic precursor in earthquake prediction and forecasting. In this paper, we studied the characteristics of thermal radiation observed before and after the 8 great earthquakes with magnitude up to Ms7.0 by using the satellite infrared remote sensing information. We used new types of data and method...

  3. Thermal luminescence spectroscopy chemical imaging sensor.

    Science.gov (United States)

    Carrieri, Arthur H; Buican, Tudor N; Roese, Erik S; Sutter, James; Samuels, Alan C

    2012-10-01

    The authors present a pseudo-active chemical imaging sensor model embodying irradiative transient heating, temperature nonequilibrium thermal luminescence spectroscopy, differential hyperspectral imaging, and artificial neural network technologies integrated together. We elaborate on various optimizations, simulations, and animations of the integrated sensor design and apply it to the terrestrial chemical contamination problem, where the interstitial contaminant compounds of detection interest (analytes) comprise liquid chemical warfare agents, their various derivative condensed phase compounds, and other material of a life-threatening nature. The sensor must measure and process a dynamic pattern of absorptive-emissive middle infrared molecular signature spectra of subject analytes to perform its chemical imaging and standoff detection functions successfully.

  4. Tunable far-infrared spectroscopy

    Science.gov (United States)

    Evenson, K. M.; Jennings, D. A.; Petersen, F. R.

    1984-01-01

    Tunable, CW, far-infrared radiation has been generated by nonlinear mixing of radiation from two CO2 lasers in a metal-insulator-metal (MIM) diode. The FIR difference-frequency power radiated from the MIM diode antenna to a calibrated indium antimonide bolometer. Two-tenths of a microwatt of FIR power was generated by 250 mW from each of the CO2 lasers. The combination of lines from a waveguide CO2 laser, with its larger tuning range, with lines from CO2, N2O, and CO2 isotopic lasers promises complete coverage of the entire far-infrared band from 100 to 5000 GHz (3-200 per cm) with stepwise-tunable CW radiation. To demonstrate the usefulness of the technique, the J = 4-5 line of CO was observed at 567 GHz.

  5. FORENSIC APPLICATIONS OF INFRARED SPECTROSCOPY

    OpenAIRE

    Severcan, Feride; OZEK, Nihal Simsek

    2017-01-01

    Infrared (IR) spectroscopyhas been extensively used for the examination of trace evidence in a forensicfield since it is non-destructive, rapid, objective, operator-independent andconfirmatory technique.  Such traces canbe obtained from biological resources such as hair, blood, fingerprints andnon-biological resources such as drug, gun-shot residue etc. The fingerprintswhich is unique per person, and the age of blood stains have been analyzed efficientlyand succesfully without destru...

  6. Photo-Acoustic Spectroscopy with Infrared FEL

    CERN Document Server

    Yasumoto, Masato; Sei, Norihiro; Yamada, Kawakatsu

    2004-01-01

    Photo-acoustic spectroscopy (PAS) is a sensitive technique for measuring small absorptions of samples. In an ordinary PAS a pulse laser is used as a light source for inducing photo-acoustic signals. In our novel PAS an infrared FEL is used as the light source. The infrared FEL is continuously tunable in the wavelength with a high repetition rate. Thus, the PAS with the infrared FEL can be applied in various samples compared with the ordinary PAS. We will show the feasibility of the novel PAS.

  7. Nanoscale Infrared Spectroscopy of Biopolymeric Materials

    Science.gov (United States)

    Curtis Marcott; Michael Lo; Kevin Kjoller; Craig Prater; Roshan Shetty; Joseph Jakes; Isao Noda

    2012-01-01

    Atomic Force Microscopy (AFM) and infrared (IR) spectroscopy have been combined in a single instrument capable of producing 100 nm spatial resolution IR spectra and images. This new capability enables the spectroscopic characterization of biomaterial domains at levels not previously possible. A tunable IR laser source generating pulses on the order of 10 ns was used...

  8. Rotationally resolved infrared spectroscopy of adamantane

    NARCIS (Netherlands)

    Pirali, O.; Boudon, V.; Oomens, J.; Vervloet, M.

    2012-01-01

    We present the first rotationally resolved spectra of adamantane (C(10)H(16)) applying gas-phase Fourier transform infrared (IR) absorption spectroscopy. High-resolution IR spectra are recorded in the 334500 cm(-1)range using as source of IR radiation both synchrotron radiation (at the AILES

  9. Rotationally resolved infrared spectroscopy of adamantane

    NARCIS (Netherlands)

    Pirali, O.; Boudon, V.; Oomens, J.; Vervloet, M.

    2012-01-01

    We present the first rotationally resolved spectra of adamantane (C10H16) applying gas-phase Fourier transform infrared (IR) absorption spectroscopy. High-resolution IR spectra are recorded in the 33-4500 cm−1range using as source of IR radiation both synchrotron radiation (at the AILES beamline of

  10. Infrared spectroscopy of ionic clusters

    Energy Technology Data Exchange (ETDEWEB)

    Price, J.M. (California Univ., Berkeley, CA (USA). Dept. of Chemistry Lawrence Berkeley Lab., CA (USA))

    1990-11-01

    This thesis describes new experiments wherein the infrared vibrational predissociation spectra of a number of mass-selected ionic cluster systems have been obtained and analyzed in the 2600 to 4000 cm{sup {minus}1} region. The species studied include: the hydrated hydronium ions, H{sub 3}O{sup +} (H{sub 2}O){sub 3 {minus}10}, ammoniated ammonium ions, NH{sub 4}{sup +}(NH{sub 3}){sub 1 {minus}10} and cluster ions involving both water and ammonia around an ammonium ion core, (mixed clusters) NH{sub 4}{sup +}(NH{sub 3}){sub n}(H{sub 2}O){sub m} (n+m=4). In each case, the spectra reveal well resolved structures that can be assigned to transitions arising from the vibrational motions of both the ion core of the clusters and the surrounding neutral solvent molecules. 154 refs., 19 figs., 8 tabs.

  11. Near Infrared Spectroscopy Systems for Tissue Oximetry

    DEFF Research Database (Denmark)

    Petersen, Søren Dahl

    for other medical applications. The tissue oximeters are realised by incorporation of pn-diodes into the silicon in order to form arrays of infrared detectors. These arrays can then be used for spatially resolved spectroscopy measurements, with the targeted end user being prematurely born infant children......We present exible silicon device platforms, which combine polyimide with polydimethylsiloxane in order to add flexibility and biocompatibility to the silicon devices. The device platforms are intended as tissue oximeters, using near infrared spectroscopy, but could potentially also be used...... of aluminium oxide, as passivation on the detectors, the reverse bias current could be reduced by 30 % for small devices. Quantum efficiencies of 80- 85 % were measured for the best detectors. By using black silicon nanostructures, the reflectance from the detector surfaces could be reduced for all angles...

  12. Face recognition in the thermal infrared domain

    Science.gov (United States)

    Kowalski, M.; Grudzień, A.; Palka, N.; Szustakowski, M.

    2017-10-01

    Biometrics refers to unique human characteristics. Each unique characteristic may be used to label and describe individuals and for automatic recognition of a person based on physiological or behavioural properties. One of the most natural and the most popular biometric trait is a face. The most common research methods on face recognition are based on visible light. State-of-the-art face recognition systems operating in the visible light spectrum achieve very high level of recognition accuracy under controlled environmental conditions. Thermal infrared imagery seems to be a promising alternative or complement to visible range imaging due to its relatively high resistance to illumination changes. A thermal infrared image of the human face presents its unique heat-signature and can be used for recognition. The characteristics of thermal images maintain advantages over visible light images, and can be used to improve algorithms of human face recognition in several aspects. Mid-wavelength or far-wavelength infrared also referred to as thermal infrared seems to be promising alternatives. We present the study on 1:1 recognition in thermal infrared domain. The two approaches we are considering are stand-off face verification of non-moving person as well as stop-less face verification on-the-move. The paper presents methodology of our studies and challenges for face recognition systems in the thermal infrared domain.

  13. Thermal Infrared Anomalies of Several Strong Earthquakes

    Directory of Open Access Journals (Sweden)

    Congxin Wei

    2013-01-01

    Full Text Available In the history of earthquake thermal infrared research, it is undeniable that before and after strong earthquakes there are significant thermal infrared anomalies which have been interpreted as preseismic precursor in earthquake prediction and forecasting. In this paper, we studied the characteristics of thermal radiation observed before and after the 8 great earthquakes with magnitude up to Ms7.0 by using the satellite infrared remote sensing information. We used new types of data and method to extract the useful anomaly information. Based on the analyses of 8 earthquakes, we got the results as follows. (1 There are significant thermal radiation anomalies before and after earthquakes for all cases. The overall performance of anomalies includes two main stages: expanding first and narrowing later. We easily extracted and identified such seismic anomalies by method of “time-frequency relative power spectrum.” (2 There exist evident and different characteristic periods and magnitudes of thermal abnormal radiation for each case. (3 Thermal radiation anomalies are closely related to the geological structure. (4 Thermal radiation has obvious characteristics in abnormal duration, range, and morphology. In summary, we should be sure that earthquake thermal infrared anomalies as useful earthquake precursor can be used in earthquake prediction and forecasting.

  14. Thermal infrared anomalies of several strong earthquakes.

    Science.gov (United States)

    Wei, Congxin; Zhang, Yuansheng; Guo, Xiao; Hui, Shaoxing; Qin, Manzhong; Zhang, Ying

    2013-01-01

    In the history of earthquake thermal infrared research, it is undeniable that before and after strong earthquakes there are significant thermal infrared anomalies which have been interpreted as preseismic precursor in earthquake prediction and forecasting. In this paper, we studied the characteristics of thermal radiation observed before and after the 8 great earthquakes with magnitude up to Ms7.0 by using the satellite infrared remote sensing information. We used new types of data and method to extract the useful anomaly information. Based on the analyses of 8 earthquakes, we got the results as follows. (1) There are significant thermal radiation anomalies before and after earthquakes for all cases. The overall performance of anomalies includes two main stages: expanding first and narrowing later. We easily extracted and identified such seismic anomalies by method of "time-frequency relative power spectrum." (2) There exist evident and different characteristic periods and magnitudes of thermal abnormal radiation for each case. (3) Thermal radiation anomalies are closely related to the geological structure. (4) Thermal radiation has obvious characteristics in abnormal duration, range, and morphology. In summary, we should be sure that earthquake thermal infrared anomalies as useful earthquake precursor can be used in earthquake prediction and forecasting.

  15. Mid infrared emission spectroscopy of carbon plasma

    Science.gov (United States)

    Nemes, Laszlo; Brown, Ei Ei; Yang, Clayton S.-C.; Hommerich, Uwe

    2017-01-01

    Mid infrared time-resolved emission spectra were recorded from laser-induced carbon plasma. These spectra constitute the first study of carbon materials LIB spectroscopy in the mid infrared range. The carbon plasma was induced using a Q-switched Nd: YAG laser. The laser beam was focused to high purity graphite pellets mounted on a translation stage. Mid infrared emission from the plasma in an atmospheric pressure background gas was detected by a cooled HgCdTe detector in the range 4.4-11.6 μm, using long-pass filters. LIB spectra were taken in argon, helium and also in air. Despite a gate delay of 10 μs was used there were strong backgrounds in the spectra. Superimposed on this background broad and noisy emission bands were observed, the form and position of which depended somewhat on the ambient gas. The spectra were digitally smoothed and background corrected. In argon, for instance, strong bands were observed around 4.8, 6.0 and 7.5 μm. Using atomic spectral data by NIST it could be concluded that carbon, argon, helium and nitrogen lines from neutral and ionized atoms are very weak in this spectral region. The width of the infrared bands supports molecular origin. The infrared emission bands were thus compared to vibrational features of carbon molecules (excluding C2) of various sizes on the basis of previous carbon cluster infrared absorption and emission spectroscopic analyses in the literature and quantum chemical calculations. Some general considerations are given about the present results.

  16. Mid infrared emission spectroscopy of carbon plasma.

    Science.gov (United States)

    Nemes, Laszlo; Brown, Ei Ei; S-C Yang, Clayton; Hommerich, Uwe

    2017-01-05

    Mid infrared time-resolved emission spectra were recorded from laser-induced carbon plasma. These spectra constitute the first study of carbon materials LIB spectroscopy in the mid infrared range. The carbon plasma was induced using a Q-switched Nd: YAG laser. The laser beam was focused to high purity graphite pellets mounted on a translation stage. Mid infrared emission from the plasma in an atmospheric pressure background gas was detected by a cooled HgCdTe detector in the range 4.4-11.6μm, using long-pass filters. LIB spectra were taken in argon, helium and also in air. Despite a gate delay of 10μs was used there were strong backgrounds in the spectra. Superimposed on this background broad and noisy emission bands were observed, the form and position of which depended somewhat on the ambient gas. The spectra were digitally smoothed and background corrected. In argon, for instance, strong bands were observed around 4.8, 6.0 and 7.5μm. Using atomic spectral data by NIST it could be concluded that carbon, argon, helium and nitrogen lines from neutral and ionized atoms are very weak in this spectral region. The width of the infrared bands supports molecular origin. The infrared emission bands were thus compared to vibrational features of carbon molecules (excluding C2) of various sizes on the basis of previous carbon cluster infrared absorption and emission spectroscopic analyses in the literature and quantum chemical calculations. Some general considerations are given about the present results. Copyright © 2016 Elsevier B.V. All rights reserved.

  17. Infrared spectroscopy of weakly bound molecular ions

    Energy Technology Data Exchange (ETDEWEB)

    Yeh, Lisa I-Ching

    1988-11-01

    The infrared spectra of a series of hydrated hydronium cluster ions and of protonated ethane ion are presented. A tandem mass spectrometer is ideally suited to obtaining the spectra of such weakly bound molecular ions. Traditional absorption spectroscopy is not feasible in these situations, so the techniques described in this thesis make use of some consequence of photon absorption with higher sensitivity than simply attenuation of laser power. That consequence is dissociation. By first mass selecting the parent ion under study and then mass selecting the fragment ion formed from dissociation, the near unit detection efficiency of ion counting methods has been used to full advantage.

  18. Near-infrared spectroscopy during peripheral vascular surgery

    DEFF Research Database (Denmark)

    Eiberg, J P; Schroeder, T V; Vogt, K C

    1997-01-01

    Near-infrared spectroscopy was performed perioperatively on the dorsum of the foot in 14 patients who underwent infrainguinal bypass surgery using a prosthesis or the greater saphenous vein. Dual-wavelength continuous light spectroscopy was used to assess changes in tissue saturation before, during...... that near-infrared spectroscopy is appropriate for perioperative monitoring during vascular grafting....

  19. Interferometric near-infrared spectroscopy (Conference Presentation)

    Science.gov (United States)

    Borycki, Dawid; Kholiqov, Oybek; Chong, Shau Poh; Srinivasan, Vivek J.

    2016-03-01

    We introduce and implement interferometric near-infrared spectroscopy (iNIRS), which simultaneously extracts the optical and dynamic properties of turbid media from the analysis of the spectral interference fringe pattern. The spectral interference fringe pattern is measured using a Mach-Zehnder interferometer with a frequency swept narrow bandwidth light source such that the temporal intensity autocorrelations can be determined for all photon path lengths. This approach enables time-of-flight (TOF) resolved measurement of scatterer motion, which is a feature inaccessible in well-established diffuse correlation spectroscopy techniques. We prove this by analyzing intensity correlations of the light transmitted through diffusive fluid phantoms with photon random walks of up to 55 (approximately 110 scattering events) using laser sweep rates on the order of 100kHz. Thus, the results we present here advance diffuse optical methods by enabling simultaneous determination of depth-resolved optical properties and dynamics in highly scattering samples.

  20. Infrared thermal imaging in connective tissue diseases.

    Science.gov (United States)

    Chojnowski, Marek

    2017-01-01

    Infrared thermal imaging (IRT) is a non-invasive, non-contact technique which allows one to measure and visualize infrared radiation. In medicine, thermal imaging has been used for more than 50 years in various clinical settings, including Raynaud's phenomenon and systemic sclerosis. Imaging and quantification of surface body temperature provides an indirect measure of the microcirculation's overall performance. As such, IRT is capable of confirming the diagnosis of Raynaud's phenomenon, and, with additional cold or heat challenge, of differentiating between the primary and secondary condition. In systemic sclerosis IRT has a potential role in assessing disease activity and monitoring treatment response. Despite certain limitations, thermal imaging can find a place in clinical practice, and with the introduction of small, low-cost infrared cameras, possibly become a part of routine rheumatological evaluation.

  1. Infrared spectroscopy of mass-selected carbocations

    Energy Technology Data Exchange (ETDEWEB)

    Duncan, Michael A. [Department of Chemistry, University of Georgia, Athens, Georgia 30602 (United States)

    2015-01-22

    Small carbocations are of longstanding interest in astrophysics, but there are few measurements of their infrared spectroscopy in the gas phase at low temperature. There are fewer-still measurements of spectra across the full range of IR frequencies useful to obtain an IR signature of these ions to detect them in space. We have developed a pulsed-discharge supersonic nozzle ion source producing high densities of small carbocations at low temperatures (50–70K). We employ mass-selected photodissociation spectroscopy and the method of rare gas “tagging”, together with new broadly tunable infrared OPO lasers, to obtain IR spectra for a variety of small carbocations including C{sub 2}H{sub 3}{sup +}, C{sub 3}H{sub 3}{sup +}, C{sub 3}H{sub 5}{sup +}, protonated benzene and protonated naphthalene. Spectra in the frequency range of 600–4500 cm{sup −1} provide new IR data for these ions and evidence for the presence of co-existing isomeric structures (e.g., C{sub 3}H{sub 3}{sup +} is present as both cyclopropenyl and propargyl). Protonated naphthalene has sharp bands at 6.2, 7.7 and 8.6 microns matching prominent features in the UIR spectra.

  2. The thermal infrared continuum in solar flares

    Science.gov (United States)

    Fletcher, Lyndsay; Simoes, Paulo; Kerr, Graham Stewart; Hudson, Hugh S.; Gimenez de Castro, C. Guillermo; Penn, Matthew J.

    2017-08-01

    Observations of the Sun with the Atacama Large Millimeter Array have now started, and the thermal infrared will regularly be accessible from the NSF’s Daniel K. Inouye Solar Telescope. Motivated by the prospect of these new observations, and by recent flare detections in the mid infrared, we set out here to model and understand the source of the infrared continuum in flares, and to explore its diagnostic capability for the physical conditions in the flare atmosphere. We use the 1D radiation hydrodynamics code RADYN to calculate mid-infrared continuum emission from model atmospheres undergoing sudden deposition of energy by non-thermal electrons. We identify and characterise the main continuum thermal emission processes relevant to flare intensity enhancement in the mid- to far-infrared (2-200 micron) spectral range as free-free emission on neutrals and ions. We find that the infrared intensity evolution tracks the energy input to within a second, albeit with a lingering intensity enhancement, and provides a very direct indication of the evolution of the atmospheric ionization. The prediction of highly impulsive emission means that, on these timescales, the atmospheric hydrodynamics need not be considered in analysing the mid-IR signatures.

  3. Introduction to experimental infrared spectroscopy fundamentals and practical methods

    CERN Document Server

    Tasumi, Mitsuo; Ochiai, Shukichi

    2014-01-01

    Infrared spectroscopy is generally understood to mean the science of spectra relating to infrared radiation, namely electromagnetic waves, in the wavelength region occurring intermediately between visible light and microwaves. Measurements of infrared spectra have been providing useful information, for a variety of scientific research and industrial studies, for over half a century; this is set to continue in the foreseeable future. Introduction to Experimental Infrared Spectroscopy is intended to be a handy guide for those who have no, or limited, experience in infrared spectroscopi

  4. Mid-infrared spectroscopy in skin cancer cell type identification

    Science.gov (United States)

    Kastl, Lena; Kemper, Björn; Lloyd, Gavin R.; Nallala, Jayakrupakar; Stone, Nick; Naranjo, Valery; Penaranda, Francisco; Schnekenburger, Jürgen

    2017-07-01

    Mid infrared spectroscopy samples were developed for the analysis of skin tumor cell types and three dimensional tissue phantoms towards the application of midIR spectroscopy for fast and reliable skin cancer diagnostics.

  5. Advances in photo-thermal infrared imaging microspectroscopy

    Science.gov (United States)

    Furstenberg, Robert; Kendziora, Chris; Papantonakis, Michael; Nguyen, Viet; McGill, Andrew

    2013-05-01

    There is a growing need for chemical imaging techniques in many fields of science and technology: forensics, materials science, pharmaceutical and chemical industries, just to name a few. While FTIR micro-spectroscopy is commonly used, its practical resolution limit of about 20 microns or more is often insufficient. Raman micro-spectroscopy provides better spatial resolution (~1 micron), but is not always practical because of samples exhibiting fluorescence or low Raman scattering efficiency. We are developing a non-contact and non-destructive technique we call photo-thermal infrared imaging spectroscopy (PT-IRIS). It involves photo-thermal heating of the sample with a tunable quantum cascade laser and measuring the resulting increase in thermal emission with an infrared detector. Photo-thermal emission spectra resemble FTIR absorbance spectra and can be acquired in both stand-off and microscopy configurations. Furthermore, PT-IRIS allows the acquisition of absorbance-like photo-thermal spectra in a reflected geometry, suitable for field applications and for in-situ study of samples on optically IR-opaque substrates (metals, fabrics, paint, glass etc.). Conventional FTIR microscopes in reflection mode measure the reflectance spectra which are different from absorbance spectra and are usually not catalogued in FTIR spectral libraries. In this paper, we continue developing this new technique. We perform a series of numerical simulations of the laser heating of samples during photo-thermal microscopy. We develop parameterized formulas to help the user pick the appropriate laser illumination power. We also examine the influence of sample geometry on spectral signatures. Finally, we measure and compare photo-thermal and reflectance spectra for two test samples.

  6. Photoacoustic infrared spectroscopy of Syncrude post-extraction oil sand

    Science.gov (United States)

    Michaelian, Kirk H.; Hall, Robert H.; Kenny, Kimberly I.

    2006-06-01

    Rapid- and step-scan photoacoustic (PA) infrared spectra of three fractions of a Syncrude post-extraction oil sand were analyzed in detail in this work. The rapid-scan spectra showed that the samples were comprised primarily of kaolinite, quartz, silica, siderite, and residual hydrocarbons, and that the proportions of these constituents were different for each fraction. Depth profiling of the three post-extraction oil sands was accomplished using both rapid- and step-scan PA infrared spectroscopy. The results confirmed that kaolinite is more abundant in the near-surface region, whereas quartz and hydrocarbons are concentrated at greater depths. The modulation frequency dependence of the PA intensities for all three fractions was consistent with a model in which the samples are thermally thick; in other words, the thermal diffusion length (roughly equal to the sampling depth) was less than the particle sizes of all three samples. The results of this study are consistent with published reports on the PA infrared spectra of fine tailings generated during bitumen extraction and the spectroscopic and thermophysical characterization of clay soils and an appropriate model clay.

  7. Infrared Heterodyne Spectroscopy and its Unique Application to Planetary Studies

    Science.gov (United States)

    Kostiuk, Theodore

    2009-01-01

    Since the early 1970's the infrared heterodyne technique has evolved into a powerful tool for the study of molecular constituents, temperatures, and dynamics in planetary atmospheres. Its extremely high spectral resolution (Lambda/(Delta)Lambda/>10(exp 6)) and highly accurate frequency measurement (to 1 part in 10(exp 8)) enabled the detection of nonthermal/natural lasing phenomena on Mars and Venus; direct measurements of winds on Venus, Mars, and Titan; study of mid-infrared aurorae on Jupiter; direct measurement of species abundances on Mars (ozone, isotopic CO2), hydrocarbons on Jupiter, Saturn., Neptune, and Titan, and stratospheric composition in the Earth's stratosphere (O3, CIO, N2O, CO2 ....). Fully resolved emission and absorption line shapes measured by this method enabled the unambiguous retrieval of molecular abundances and local temperatures and thermal structure in regions not probed by other techniques. The mesosphere of Mars and thermosphere of Venus are uniquely probed by infrared heterodyne spectroscopy. Results of these studies tested and constrained photochemical and dynamical theoretical models describing the phenomena measured. The infrared heterodyne technique will be described. Highlights in its evolution to today's instrumentation and resultant discoveries will be presented, including work at Goddard Space Flight Center and the University of Koln. Resultant work will include studies supporting NASA and ESA space missions and collaborations between instrumental and theoretical groups.

  8. Buccal microbiology analyzed by infrared spectroscopy

    Science.gov (United States)

    de Abreu, Geraldo Magno Alves; da Silva, Gislene Rodrigues; Khouri, Sônia; Favero, Priscila Pereira; Raniero, Leandro; Martin, Airton Abrahão

    2012-01-01

    Rapid microbiological identification and characterization are very important in dentistry and medicine. In addition to dental diseases, pathogens are directly linked to cases of endocarditis, premature delivery, low birth weight, and loss of organ transplants. Fourier Transform Infrared Spectroscopy (FTIR) was used to analyze oral pathogens Aggregatibacter actinomycetemcomitans ATCC 29523, Aggregatibacter actinomycetemcomitans-JP2, and Aggregatibacter actinomycetemcomitans which was clinically isolated from the human blood-CI. Significant spectra differences were found among each organism allowing the identification and characterization of each bacterial species. Vibrational modes in the regions of 3500-2800 cm-1, the 1484-1420 cm-1, and 1000-750 cm-1 were used in this differentiation. The identification and classification of each strain were performed by cluster analysis achieving 100% separation of strains. This study demonstrated that FTIR can be used to decrease the identification time, compared to the traditional methods, of fastidious buccal microorganisms associated with the etiology of the manifestation of periodontitis.

  9. Infrared and THz spectroscopy of nanostructured dielectrics

    Directory of Open Access Journals (Sweden)

    Jan Petzelt

    2009-09-01

    Full Text Available Results achieved using the infrared/THz spectroscopy of various inhomogeneous dielectrics in the Department of Dielectrics, Institute of Physics, Prague, during the last decade are briefly reviewed. The discussion concerns high-permittivity ceramics with inevitable low-permittivity dead layers along the grain boundaries, relaxor ferroelectrics with highly anisotropic polar nano-regions, classical matrix-type composites, core-shell composites, filled nanoporous glasses, polycrystalline and epitaxial thin films, heterostructures and superlattices on dielectric substrates. The analysis using models based on the effective medium approach is discussed. The importance of depolarizing field and of the percolation of components on the effective ac dielectric response and the excitations contributing to it are emphasized.

  10. Thermal infrared remote sensing sensors, methods, applications

    CERN Document Server

    Kuenzer, Claudia

    2013-01-01

    This book provides a comprehensive overview of the state of the art in the field of thermal infrared remote sensing. Temperature is one of the most important physical environmental variables monitored by earth observing remote sensing systems. Temperature ranges define the boundaries of habitats on our planet. Thermal hazards endanger our resources and well-being. In this book renowned international experts have contributed chapters on currently available thermal sensors as well as innovative plans for future missions. Further chapters discuss the underlying physics and image processing techni

  11. [Identification of Dendrobium varieties by infrared spectroscopy].

    Science.gov (United States)

    Liu, Fei; Wang, Yuan-Zhong; Yang, Chun-Yan; Jin, Hang

    2014-11-01

    The difference of Dendrobium varieties were analyzed by Fourier transform infrared (FTIR) spectroscopy. The infrared spectra of 206 stems from 30 Dendrobium varieties were obtained, and showed that polysaccharides, especially fiber, were the main components in Dendrobium plants. FTIR combined with Wilks' Lambda stepwise discriminative analysis was used to identify Dendrobium varieties. The effects of spectral range and number of training samples on the discrimination results were also analysed. Two hundred eighty seven variables in the spectral range of 1 800-1 250 cm(-1) were studied, and showed that the return discrimination is 100% correct when the training samples number of each species was 2, 3, 4, 5, and 6, respectively, whereas for the remaining samples the correct rates of identification were equal to 79.4%, 91.3%, 93.0%, 98.2%, and 100%, respectively. The same discriminative analyses on five different training samples in the spectral range of 1 800-1 500, 1 500-1 250, 1 250-600, 1 250-950 and 950-650 cm(-1) were compared, which showed that the variables in the range of 1 800-1 250, 1 800-1 500 and 950-600 cm(-1) were more suitable for variety identification, and one can obtain the satisfactory result for discriminative analysis when the training sample is more than 3. Our results indicate that FTIR combined with stepwise discriminative analysis is an effective way to distinguish different Dendrobium varieties.

  12. Nonlinear infrared spectroscopy free from spectral selection

    CERN Document Server

    Paterova, Anna; Kalashnikov, Dmitry; Krivitsky, Leonid

    2016-01-01

    Infrared (IR) spectroscopy is an indispensable tool for many practical applications including material analysis and sensing. Existing IR spectroscopy techniques face challenges related to the inferior performance and the high cost of IR-grade components. Here, we develop a new method, which allows studying properties of materials in the IR range using only visible light optics and detectors. It is based on the nonlinear interference of entangled photons, generated via Spontaneous Parametric Down Conversion (SPDC). In our interferometer, the phase of the signal photon in the visible range depends on the phase of an entangled IR photon. When the IR photon is traveling through the media, its properties can be found from observations of the visible photon. We directly acquire the SPDC signal with a visible range CCD camera and use a numerical algorithm to infer the absorption coefficient and the refraction index of the sample in the IR range. Our method does not require the use of a spectrometer and a slit, thus ...

  13. Nonlinear infrared spectroscopy free from spectral selection

    Science.gov (United States)

    Paterova, Anna; Lung, Shaun; Kalashnikov, Dmitry A.; Krivitsky, Leonid A.

    2017-02-01

    Infrared (IR) spectroscopy is an indispensable tool for many practical applications including material analysis and sensing. Existing IR spectroscopy techniques face challenges related to the inferior performance and the high cost of IR-grade components. Here, we develop a new method, which allows studying properties of materials in the IR range using only visible light optics and detectors. It is based on the nonlinear interference of entangled photons, generated via Spontaneous Parametric Down Conversion (SPDC). In our interferometer, the phase of the signal photon in the visible range depends on the phase of an entangled IR photon. When the IR photon is traveling through the media, its properties can be found from observations of the visible photon. We directly acquire the SPDC signal with a visible range CCD camera and use a numerical algorithm to infer the absorption coefficient and the refraction index of the sample in the IR range. Our method does not require the use of a spectrometer and a slit, thus it allows achieving higher signal-to-noise ratio than the earlier developed method.

  14. Nonlinear infrared spectroscopy free from spectral selection.

    Science.gov (United States)

    Paterova, Anna; Lung, Shaun; Kalashnikov, Dmitry A; Krivitsky, Leonid A

    2017-02-20

    Infrared (IR) spectroscopy is an indispensable tool for many practical applications including material analysis and sensing. Existing IR spectroscopy techniques face challenges related to the inferior performance and the high cost of IR-grade components. Here, we develop a new method, which allows studying properties of materials in the IR range using only visible light optics and detectors. It is based on the nonlinear interference of entangled photons, generated via Spontaneous Parametric Down Conversion (SPDC). In our interferometer, the phase of the signal photon in the visible range depends on the phase of an entangled IR photon. When the IR photon is traveling through the media, its properties can be found from observations of the visible photon. We directly acquire the SPDC signal with a visible range CCD camera and use a numerical algorithm to infer the absorption coefficient and the refraction index of the sample in the IR range. Our method does not require the use of a spectrometer and a slit, thus it allows achieving higher signal-to-noise ratio than the earlier developed method.

  15. Synthetic infrared spectra for correlation spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Sinclair, M.B.; Butler, M.A.; Ricco, A.J.; Kravitz, S.H.; Zubrzycki, W.J.; Warren, M.E.

    1997-12-01

    As a first step toward the development of a new remote sensing technique that the authors call holographic correlation spectroscopy, they demonstrate that diffractive optics can be used to synthesize the infrared spectra of real compounds. In particular, they have designed, fabricated, and characterized a diffractive element that successfully reproduces the major features f the spectrum of gaseous HF in the region between 3,600 cm{sup {minus}1} and 4,300 cm{sup {minus}1}. The reflection-mode diffractive optic consists of 4,096 lines, each 4.5 {micro}m wide, at 16 discrete depths relative to the substrate (from 0 to 1.2 {micro}m), and was fabricated on a silicon wafer using anisotropic reactive ion-beam etching in a four-mask-level process. The authors envision the use of diffractive elements of this type to replace the cumbersome reference cells of conventional correlation spectroscopy and thereby enable a new class of compact and versatile correlation spectrometers.

  16. Photoacoustic infrared spectroscopy of polymer beads.

    Science.gov (United States)

    Wen, Qing; Michaelian, Kirk H

    2009-09-01

    Photoacoustic (PA) spectra of four types of polymer resin beads, ranging in size from 35 to 150 microm, were acquired using a Fourier transform infrared spectrometer capable of both rapid- and step-scan mirror movement. Thermal diffusion lengths were on the order of the particle sizes of the beads. The PA magnitude spectra were similar to absorption spectra; both positive- and negative-going features occurred in the phase spectra. The frequency dependences of the total PA intensities of the polymer resins and carbon black differed by a factor of about f(-0.30). The intensities of the weak bands in the ratioed spectra (resin beads/carbon black) displayed a similar dependence. Partial saturation caused a more gradual variation for the stronger bands, where the intensity is proportional to approximately f(-0.1)-f(-0.2).

  17. Development of infrared spectroscopy techniques for environmental monitoring

    Energy Technology Data Exchange (ETDEWEB)

    Sandsten, Jonas

    2000-08-01

    Infrared spectroscopy techniques have long been utilized in identifying and quantifying species of interest to us. Many of the elementary molecules in the atmosphere interact with infrared radiation through their ability to absorb and emit energy in vibrational and rotational transitions. A large variety of methods for monitoring of molecules and aerosol particles by collecting samples or by using remote sensing methods are available. The objective of the work presented in this thesis was to develop infrared spectroscopic techniques to further enhance the amount of useful information obtained from gathering spectral data. A new method for visualization and quantification of gas flows based on gas-correlation techniques was developed. Real-time imaging of gas leaks and incomplete or erratic flare combustion of ethene was demonstrated. The method relies on the thermal background as a radiation source and the gas can be visualized in absorption or in emission depending on the temperature difference. Diode laser spectroscopy was utilized to monitor three molecular species at the same time and over the same path. Two near-infrared diode lasers beams were combined in a periodically poled lithium niobate crystal and by difference-frequency generation a third beam was created, enabling simultaneous monitoring of oxygen, water vapor and methane. Models of aerosol particle cross sections were used to simulate the diffraction pattern of light scattered by fibers, spherical particles and real particles, such as pollen, through a new aerosol particle sensing prototype. The instrument, using a coupled cavity diode laser, has been designed with a ray-tracing program and the final prototype was employed for single aerosol particle sizing and identification.

  18. Teaching physics and understanding infrared thermal imaging

    Science.gov (United States)

    Vollmer, Michael; Möllmann, Klaus-Peter

    2017-08-01

    Infrared thermal imaging is a very rapidly evolving field. The latest trends are small smartphone IR camera accessories, making infrared imaging a widespread and well-known consumer product. Applications range from medical diagnosis methods via building inspections and industrial predictive maintenance etc. also to visualization in the natural sciences. Infrared cameras do allow qualitative imaging and visualization but also quantitative measurements of the surface temperatures of objects. On the one hand, they are a particularly suitable tool to teach optics and radiation physics and many selected topics in different fields of physics, on the other hand there is an increasing need of engineers and physicists who understand these complex state of the art photonics systems. Therefore students must also learn and understand the physics underlying these systems.

  19. Chemical profiling and adulteration screening of Aquilariae Lignum Resinatum by Fourier transform infrared (FT-IR) spectroscopy and two-dimensional correlation infrared (2D-IR) spectroscopy

    Science.gov (United States)

    Qu, Lei; Chen, Jian-bo; Zhang, Gui-Jun; Sun, Su-qin; Zheng, Jing

    2017-03-01

    As a kind of expensive perfume and valuable herb, Aquilariae Lignum Resinatum (ALR) is often adulterated for economic motivations. In this research, Fourier transform infrared (FT-IR) spectroscopy is employed to establish a simple and quick method for the adulteration screening of ALR. First, the principal chemical constituents of ALR are characterized by FT-IR spectroscopy at room temperature and two-dimensional correlation infrared (2D-IR) spectroscopy with thermal perturbation. Besides the common cellulose and lignin compounds, a certain amount of resin is the characteristic constituent of ALR. Synchronous and asynchronous 2D-IR spectra indicate that the resin (an unstable secondary metabolite) is more sensitive than cellulose and lignin (stable structural constituents) to the thermal perturbation. Using a certified ALR sample as the reference, the infrared spectral correlation threshold is determined by 30 authentic samples and 6 adulterated samples. The spectral correlation coefficient of an authentic ALR sample to the standard reference should be not less than 0.9886 (p = 0.01). Three commercial adulterated ALR samples are identified by the correlation threshold. Further interpretation of the infrared spectra of the adulterated samples indicates the common adulterating methods - counterfeiting with other kind of wood, adding ingredient such as sand to increase the weight, and adding the cheap resin such as rosin to increase the content of resin compounds. Results of this research prove that FT-IR spectroscopy can be used as a simple and accurate quality control method of ALR.

  20. Fourier Transform Infrared Spectroscopy and Photoacoustic Spectroscopy for Saliva Analysis.

    Science.gov (United States)

    Mikkonen, Jopi J W; Raittila, Jussi; Rieppo, Lassi; Lappalainen, Reijo; Kullaa, Arja M; Myllymaa, Sami

    2016-09-01

    Saliva provides a valuable tool for assessing oral and systemic diseases, but concentrations of salivary components are very small, calling the need for precise analysis methods. In this work, Fourier transform infrared (FT-IR) spectroscopy using transmission and photoacoustic (PA) modes were compared for quantitative analysis of saliva. The performance of these techniques was compared with a calibration series. The linearity of spectrum output was verified by using albumin-thiocyanate (SCN(-)) solution at different SCN(-) concentrations. Saliva samples used as a comparison were obtained from healthy subjects. Saliva droplets of 15 µL were applied on the silicon sample substrate, 6 drops for each specimen, and dried at 37 ℃ overnight. The measurements were carried out using an FT-IR spectrometer in conjunction with an accessory unit for PA measurements. The findings with both transmission and PA modes mirror each other. The major bands presented were 1500-1750 cm(-1) for proteins and 1050-1200 cm(-1) for carbohydrates. In addition, the distinct spectral band at 2050 cm(-1) derives from SCN(-) anions, which is converted by salivary peroxidases to hypothiocyanate (OSCN(-)). The correlation between the spectroscopic data with SCN(-) concentration (r > 0.990 for transmission and r = 0.967 for PA mode) was found to be significant (P < 0.01), thus promising to be utilized in future applications. © The Author(s) 2016.

  1. Giant Planet Interior Physics from Near-Infrared Spectroscopy

    Science.gov (United States)

    Fortney, Jonathan J.; Thorngren, Daniel; Line, Michael R.; Morley, Caroline

    2017-10-01

    Transiting planets give us excellent probes of giant exoplanet structure (from mass and radius) and atmospheres (from transit and occultation spectroscopy). However, the combined power of these observations to understand how the planetary interior structure may impact its atmosphere has not yet been fully exploited. This will change with JWST. In particular, near-infrared wavelengths have less water opacity than mid-IR wavelengths, which allows us to probe thermal emission from deeper, hotter regions of the atmosphere. In some circumstances we should be able to see thermal emission coming from below the radiative-convective boundary in the atmosphere, including the adiabat itself. This adiabat continues into the planet’s very deep interior -- the specific entropy of this adiabat sets the planetary radius at a given mass. Hot internal adiabats, which we should be able to ``see” in thermal emission, should be present for the most inflated hot Jupiters, and planets like warm Neptunes that are strongly influenced by tidal heating (e.g. GJ 436b, Morley et al. 2017). Determining the flux coming from these atmospheric depths can be an important constraint on structure models of planets that have aimed to understand giant planet bulk metal enrichment, which is an important constraint on formation models. These flux detections can also provide novel and reasonably direct constraints on planetary tidal Q for eccentric planets. We highlight how we expect JWST to open up this new window into exoplanetary physics.

  2. Infrared Reflectance Spectroscopy of Porous Silicas

    Science.gov (United States)

    Guiton, Theresa Anne

    Fourier transform infrared (FTIR) specular reflectance spectroscopy was used to examine the fundamental phonon behavior of a series of porous silicas including porous Vycor, xerogels, aerogels, and colloidal solids. The spectra were deconvoluted using Kramers-Kronig analysis techniques, and the corresponding optical constants were determined via the Fresnel equations. The resulting spectra represent the first compilation of such data for low density silicas. The porous silicas revealed unique resonance modes for the imaginary dielectric function and energy loss function. A key distinction amongst the spectra was the change in the band shape of the antisymmetric Si-O-Si stretching modes. For instance, as the porosity level of the particulate systems increased, the peak maxima of the imaginary dielectric functions shifted to higher frequencies while the peak maxima of the associated energy loss function shifted to lower frequencies. In essence, with increasing porosity, the peak maxima of the imaginary dielectric functions and the energy loss functions were converging towards frequencies intermediate to the transverse optical and longitudinal optical modes of fused silica. A similar trend was not observed for the semi-continuous silica matrices. Maxwell Garnett effective medium modeling verified that these modes were a function of the porous microstructure and can be attributed to surface phonon modes. The effect of surface phonon modes was also evident in the absorption coefficient data. However, contrary to the traditional view that changes in the absorption spectra of porous silicas are strictly due to molecular structure, this study has demonstrated that variations can be attributed--both qualitatively and quantitatively--to electrostatic screening effects of finite particles.

  3. Quantum cascade laser infrared spectroscopy of single cancer cells

    KAUST Repository

    Patel, Imran

    2017-03-27

    Quantum cascade laser infrared spectroscopy is a next generation novel imaging technique allowing high resolution spectral imaging of cells. We show after spectral pre-processing, identification of different cancer cell populations within minutes.

  4. Cerebral near infrared spectroscopy oximetry in extremely preterm infants

    DEFF Research Database (Denmark)

    Hyttel-Sørensen, Simon; Pellicer, Adelina; Alderliesten, Thomas

    2015-01-01

    OBJECTIVE: To determine if it is possible to stabilise the cerebral oxygenation of extremely preterm infants monitored by cerebral near infrared spectroscopy (NIRS) oximetry. DESIGN: Phase II randomised, single blinded, parallel clinical trial. SETTING: Eight tertiary neonatal intensive care units...

  5. Fourier transform infrared (FTIR) spectroscopy for identification of ...

    African Journals Online (AJOL)

    All FTIR spectra showed a closely similar sequence of 11 distinct bands and were assigned a range of vibrationally active chemical groups, including residual water (–OH), lipid (–CH2), cellulose (–C=O), ... Key words: Microalgae, Chlorella, Scenedesmus, Fourier transform infrared (FTIR) analysis, infrared spectroscopy.

  6. Infrared thermal models for Saturn's ring

    Science.gov (United States)

    Price, M. J.

    1976-01-01

    Infrared (10 and 20 microns) thermal emission data for Saturn's rings are discussed in terms of simple isothermal radiative transfer models of finite optical thickness. Recent brightness temperature measurements, corresponding to essentially maximum ring tilt, indicate that optical single scattering albedos less than 0.75 are required to provide sufficient heating of the ring material. Reconciliation with analyses of the optical scattering properties of the ring requires the backscattering efficiency to be even higher than for a macroscopic sphere. Historical brightness temperature measurements are used to show that no unique isothermal ring model exists. Instead, a temperature gradient perpendicular to the ring plane appears to be present.

  7. IR Cards: Inquiry-Based Introduction to Infrared Spectroscopy

    Science.gov (United States)

    Bennett, Jacqueline; Forster, Tabetha

    2010-01-01

    As infrared spectroscopy (IR) is frequently used in undergraduate organic chemistry courses, an inductive introduction to IR spectroscopy that uses index cards printed with spectra, structures, and chemical names is described. Groups of students are given an alphabetized deck of these "IR cards" to sort into functional groups. The students then…

  8. Composition of dissolved organic matter (DOM) from periodically submerged soils in the Three Gorges Reservoir areas as determined by elemental and optical analysis, infrared spectroscopy, pyrolysis-GC-MS and thermally assisted hydrolysis and methylation.

    Science.gov (United States)

    Jiang, Tao; Kaal, Joeri; Liang, Jian; Zhang, Yaoling; Wei, Shiqiang; Wang, Dingyong; Green, Nelson W

    2017-12-15

    Soil-derived dissolved organic matter (DOM) has a major influence in biogeochemical processes related to contaminant dynamics and greenhouse gas emissions, due to its reactivity and its bridging role between the soil and aquatic systems. Within the Three Gorges Reservoir (TGR, China) area, an extensive water-fluctuation zone periodically submerges the surrounding soils. Here we report a characterization study of soil-derived DOM across the TGR areas, using elemental and optical analysis, infrared spectroscopy (FTIR), pyrolysis-GC-MS (Py-GC-MS) and thermally assisted hydrolysis and methylation (THM-GC-MS). The results showed that the soil DOM from the TGR area is a mixture of "allochthonous" (i.e., plant-derived/terrigenous) and "autochthonous" (i.e., microbial) origins. The terrigenous DOM is composed primarily of phenolic and aliphatic structures from lignin and aliphatic biopolymers (i.e. cutin, suberin), respectively. Multivariate statistics differentiated between two fractions of the microbial DOM, i.e. chitin-derived, perhaps from fungi and arthropods in soil, and protein-derived, partially sourced from algal or aquatic organisms. Molecular proxies of source and degradation state were in good agreement with optical parameters such as SUVA254, the fluorescence index (FI) and the humification index (HIX). The combined use of elemental analysis, fluorescence spectroscopy, and Py-GC-MS provides rigorous and detailed DOM characterization, whereas THM-GC-MS is useful for more precise but qualitative identification of the different phenolic (cinnamyl, p-hydroxyphenyl, guaiacyl, syringyl and tannin-derived) and aliphatic materials. With the multi-methodological approach used in this study, FTIR was the least informative, in part, because of the interference of inorganic matter in the soil DOM samples. The soil DOM from the TGR's water fluctuation zone exhibited considerable compositional diversity, mainly related to the balance between DOM source (microbial- or plant

  9. A comprehensive physicochemical, thermal, and spectroscopic characterization of zinc (II) chloride using X-ray diffraction, particle size distribution, differential scanning calorimetry, thermogravimetric analysis/differential thermogravimetric analysis, ultraviolet-visible, and Fourier transform-infrared spectroscopy.

    Science.gov (United States)

    Trivedi, Mahendra Kumar; Sethi, Kalyan Kumar; Panda, Parthasarathi; Jana, Snehasis

    2017-01-01

    Zinc chloride is an important inorganic compound used as a source of zinc and has other numerous industrial applications. Unfortunately, it lacks reliable and accurate physicochemical, thermal, and spectral characterization information altogether. Hence, the authors tried to explore in-depth characterization of zinc chloride using the modern analytical technique. The analysis of zinc chloride was performed using powder X-ray diffraction (PXRD), particle size distribution, differential scanning calorimetry (DSC), thermogravimetric analysis/differential thermogravimetric analysis (TGA/DTG), ultraviolet-visible spectroscopy (UV-vis), and Fourier transform-infrared (FT-IR) analytical techniques. The PXRD patterns showed well-defined, narrow, sharp, and the significant peaks. The crystallite size was found in the range of 14.70-55.40 nm and showed average crystallite size of 41.34 nm. The average particle size was found to be of 1.123 (d10), 3.025 (d50), and 6.712 (d90) μm and average surface area of 2.71 m2/g. The span and relative span values were 5.849 μm and 1.93, respectively. The DSC thermogram showed a small endothermic inflation at 308.10°C with the latent heat (ΔH) of fusion 28.52 J/g. An exothermic reaction was observed at 449.32°C with the ΔH of decomposition 66.10 J/g. The TGA revealed two steps of the thermal degradation and lost 8.207 and 89.72% of weight in the first and second step of degradation, respectively. Similarly, the DTG analysis disclosed Tmax at 508.21°C. The UV-vis spectrum showed absorbance maxima at 197.60 nm (λmax), and FT-IR spectrum showed a peak at 511/cm might be due to the Zn-Cl stretching. These in-depth, comprehensive data would be very much useful in all stages of nutraceuticals/pharmaceuticals formulation research and development and other industrial applications.

  10. Biodegradable starch-based films containing saturated fatty acids: thermal, infrared and raman spectroscopic characterization

    Directory of Open Access Journals (Sweden)

    Marcelo M. Nobrega

    2012-01-01

    Full Text Available Biodegradable films of thermoplastic starch and poly (butylene adipate co-terephthalate (PBAT containing fatty acids were characterized thermally and with infrared and Raman spectroscopies. The symmetrical character of the benzene ring in PBAT provided a means to illustrate the difference between these spectroscopic techniques, because a band appeared in the Raman spectrum but not in the infrared. The thermal analysis showed three degradation stages related to fatty acids, starch and PBAT. The incorporation of saturated fatty acids with different molecular mass (caproic, lauric and stearic did not change the nature of the chemical bonds among the components in the blends of starch, PBAT and glycerol, according to the thermal analysis, infrared and Raman spectroscopies.

  11. Biodegradable starch-based films containing saturated fatty acids: thermal, infrared and raman spectroscopic characterization

    Directory of Open Access Journals (Sweden)

    Marcelo M. Nobrega

    Full Text Available Biodegradable films of thermoplastic starch and poly (butylene adipate co-terephthalate (PBAT containing fatty acids were characterized thermally and with infrared and Raman spectroscopies. The symmetrical character of the benzene ring in PBAT provided a means to illustrate the difference between these spectroscopic techniques, because a band appeared in the Raman spectrum but not in the infrared. The thermal analysis showed three degradation stages related to fatty acids, starch and PBAT. The incorporation of saturated fatty acids with different molecular mass (caproic, lauric and stearic did not change the nature of the chemical bonds among the components in the blends of starch, PBAT and glycerol, according to the thermal analysis, infrared and Raman spectroscopies.

  12. Near-infrared spectroscopy for cocrystal screening

    DEFF Research Database (Denmark)

    Allesø, Morten; Velaga, Sitaram; Alhalaweh, Amjad

    2008-01-01

    of pure references. In addition, Raman spectroscopy provided additional information on the crystal structure of the IND-SAC cocrystal. The broad spectral line shapes of NIR spectra make visual interpretation of the spectra difficult, and consequently, multivariate modeling by principal component analysis...... the analytical potential of NIR spectroscopy for cocrystal screening using Raman spectroscopy as a comparative method. Indomethacin was used as the parent molecule, while saccharin and l-aspartic acid were chosen as guest molecules. Molar ratios of 1:1 for each system were subjected to two types of preparative...... retained in a physical mixture with the guest molecule, while liquid-assisted cogrinding did not induce any changes in the crystal lattice. The good chemical peak selectivity of Raman spectroscopy allowed a straightforward interpretation of sample data by analyzing peak positions and comparing to those...

  13. Thermal infrared research: Where are we now?

    Science.gov (United States)

    Hatfield, J. L.; Jackson, R. D.

    1982-01-01

    The use of infrared temperatures in agriculture and hydrology is based on the energy balance equation which is used to estimate evapotranspiration and crop stress over small areas within a field as well as large areas. For its full utilization, this measurement must be combined with other spectral data collected at a time resolution sufficient to detect changes in the agricultural or hydrological systems and at a spatial resolution with enough detail to sample within individual fields. The most stringent requirement is that the data be readily available to the user. The spatial resolution necessary for IR measurements to be incorporated into evapotranspiration models to accurately estimate field and regional transpiration or measure crop stress; methods to estimate crop stress and yield over large areas and different cultivars within a species; the temporal resolution adequate for detecting crop stress or inclusion in evapotranspiration models; and ancillary parameters for estimating thermal IR measurements must be investigated.

  14. Mid infrared upconversion spectroscopy using diffuse reflectance

    DEFF Research Database (Denmark)

    Sanders, Nicolai Højer; Kehlet, Louis M.; Dam, Jeppe Seidelin

    2014-01-01

    We present a novel approach for mid infrared (mid-IR) spectral analysis using upconversion technology applied in a diffuse reflectance setup. We demonstrate experimentally that mid-IR spectral features in the 2.6-4 μm range using different test samples (e.g. zeolites) can be obtained. The results...

  15. Infrared spectroscopy of interstellar apolar ice analogs

    NARCIS (Netherlands)

    Ehrenfreund, P; Boogert, ACA; Gerakines, PA; Tielens, AGGM; van Dishoeck, EF

    1997-01-01

    Apolar ices have been observed in several regions in dense clouds and are likely dominated by molecules such as CO, CO(2) and the infrared inactive molecules O(2) and N(2). Interstellar solid CO has been well characterized by ground-based high resolution measurements. Recent ISO results showed the

  16. The Visualization of Infrared Radiation Using Thermal Sensitive Foils

    Science.gov (United States)

    Bochnícek, Zdenek

    2013-01-01

    This paper describes a set of demonstration school experiments where infrared radiation is detected using thermal sensitive foils. The possibility of using standard glass lenses for infrared imaging is discussed in detail. It is shown that with optic components made from glass, infrared radiation up to 2.5 µm of wavelength can be detected. The…

  17. Infrared Spectroscopy in the Study of Renal Lithiasis

    Science.gov (United States)

    Fernández-Almeida, Jesús; Fernández-Gacio, Ana; Marcos, Carlos F.; Fernández-Gacio, Maira

    2003-08-01

    Infrared spectroscopic analysis of urinary stones is presented as a laboratory experiment for undergraduate students studying life sciences. Infrared spectroscopy, usually combined with the observation of macroscopic and microscopic features, is the preferred tool for unequivocal determination of renal stones composition. In this paper we represent and discuss the IR spectra of some of the most common types of urinary calculi occurring in humans and domestic animals.

  18. Chemical profiling and adulteration screening of Aquilariae Lignum Resinatum by Fourier transform infrared (FT-IR) spectroscopy and two-dimensional correlation infrared (2D-IR) spectroscopy.

    Science.gov (United States)

    Qu, Lei; Chen, Jian-Bo; Zhang, Gui-Jun; Sun, Su-Qin; Zheng, Jing

    2017-03-05

    As a kind of expensive perfume and valuable herb, Aquilariae Lignum Resinatum (ALR) is often adulterated for economic motivations. In this research, Fourier transform infrared (FT-IR) spectroscopy is employed to establish a simple and quick method for the adulteration screening of ALR. First, the principal chemical constituents of ALR are characterized by FT-IR spectroscopy at room temperature and two-dimensional correlation infrared (2D-IR) spectroscopy with thermal perturbation. Besides the common cellulose and lignin compounds, a certain amount of resin is the characteristic constituent of ALR. Synchronous and asynchronous 2D-IR spectra indicate that the resin (an unstable secondary metabolite) is more sensitive than cellulose and lignin (stable structural constituents) to the thermal perturbation. Using a certified ALR sample as the reference, the infrared spectral correlation threshold is determined by 30 authentic samples and 6 adulterated samples. The spectral correlation coefficient of an authentic ALR sample to the standard reference should be not less than 0.9886 (p=0.01). Three commercial adulterated ALR samples are identified by the correlation threshold. Further interpretation of the infrared spectra of the adulterated samples indicates the common adulterating methods - counterfeiting with other kind of wood, adding ingredient such as sand to increase the weight, and adding the cheap resin such as rosin to increase the content of resin compounds. Results of this research prove that FT-IR spectroscopy can be used as a simple and accurate quality control method of ALR. Copyright © 2016 Elsevier B.V. All rights reserved.

  19. Infrared absorption spectroscopy and chemical kinetics of free radicals

    Energy Technology Data Exchange (ETDEWEB)

    Curl, R.F.; Glass, G.P. [Rice Univ., Houston, TX (United States)

    1993-12-01

    This research is directed at the detection, monitoring, and study of chemical kinetic behavior by infrared absorption spectroscopy of small free radical species thought to be important intermediates in combustion. During the last year, infrared kinetic spectroscopy using excimer laser flash photolysis and color-center laser probing has been employed to study the high resolution spectrum of HCCN, the rate constant of the reaction between ethynyl (C{sub 2}H) radical and H{sub 2} in the temperature region between 295 and 875 K, and the recombination rate of propargyl (CH{sub 2}CCH) at room temperature.

  20. Effects of plume afterburning on infrared spectroscopy

    Science.gov (United States)

    Zhu, Xijuan; Xu, Ying; Ma, Jing; Duan, Ran; Wu, Jie

    2017-10-01

    Contains H2, CO and unburned components of high-temperature plume of rocket engine, then injected into the atmosphere, continue to carry out the oxidation reaction in the plume near field region with the volume in the plume of oxygen in the air, two times burning. The afterburning is an important cause of infrared radiation intensification of propellant plume, which increases the temperature of the flame and changes the components of the gas, thus enhancing the infrared radiation intensity of the flame. [1]. Two the combustion numerical using chemical reaction mechanism involving HO2 intermediate reaction, the study confirmed that HO2 is a key intermediate, plays a decisive role to trigger early response, on afterburning temperature and flow concentration distribution effect. A finite rate chemical reaction model is used to describe the two burning phenomenon in high temperature plume[2]. In this paper, a numerical simulation of the flame flow field and radiative transfer is carried out for the afterburning phenomenon. The effects of afterburning on the composition, temperature and infrared radiation of the plume are obtained by comparison.

  1. AFM-IR: Technology and Applications in Nanoscale Infrared Spectroscopy and Chemical Imaging.

    Science.gov (United States)

    Dazzi, Alexandre; Prater, Craig B

    2016-12-13

    Atomic force microscopy-based infrared spectroscopy (AFM-IR) is a rapidly emerging technique that provides chemical analysis and compositional mapping with spatial resolution far below conventional optical diffraction limits. AFM-IR works by using the tip of an AFM probe to locally detect thermal expansion in a sample resulting from absorption of infrared radiation. AFM-IR thus can provide the spatial resolution of AFM in combination with the chemical analysis and compositional imaging capabilities of infrared spectroscopy. This article briefly reviews the development and underlying technology of AFM-IR, including recent advances, and then surveys a wide range of applications and investigations using AFM-IR. AFM-IR applications that will be discussed include those in polymers, life sciences, photonics, solar cells, semiconductors, pharmaceuticals, and cultural heritage. In the Supporting Information , the authors provide a theoretical section that reviews the physics underlying the AFM-IR measurement and detection mechanisms.

  2. Near infrared spectroscopy of food systems using a supercontinuum laser

    DEFF Research Database (Denmark)

    Ringsted, Tine

    Mid-infrared and particularly near-infrared spectroscopy is extremely useful for food analysis because they measure chemical and physical properties fast and non-destructively. The advancement of a supercontinuum light source covering the near-infrared and parts of the ultraviolet and mid......)) can be obtained, (c) that the supercontinuum light is fiber compatible i.e. it can couple directly to fibers, and (d) that the fast repetition rate of the supercontinuum pulses makes it possible to do very fast measurements. For these reasons, the supercontinuum light stands out from the commonly...... applied near- and mid-infrared incandescent light bulbs. This thesis aim to explore the utility of using a supercontinuum source in two food applications. (1) The supercontinuum light was applied for the first time to barley seeds in transmission mode in the long wavelength near-infrared region from 2260...

  3. AUTHENTICATION OF WILD AND REARED SEA BASS BY INFRARED SPECTROSCOPY NIRs (NEAR INFRARED REFLECTANCE SPECTROSCOPY

    Directory of Open Access Journals (Sweden)

    E. Novelli

    2009-09-01

    Full Text Available The aim of this study was to evaluate NIRs (Near Infrared Reflectance Spectroscopy performances in the prediction of Farmed vs.Wild production method in European sea bass. Samples collected (n=39 were submitted to analysis in order to assess chemical composition and fatty acids profile of fillets. Aliquots of wet and ground freeze-dried minced samples were scanned in duplicates (1100 to 2498 nm; 2 nm intervals in reflectance mode using a monochromator NIRsystem 5000. NIRs technique showed a satisfactory accurateness in predicting Protein, Lipids and Fatty acids profile in raw samples. Sample lyophilisation increased some predicting values (r2: coefficient of determination on cross-validation range from 0,671 to 0,992; SECV: standard error of cross-validation range from 0,864 to 2,981. Results showed that NIRs technique was able to discriminate between Wild (94,7% samples recognized and Farmed (100% samples recognized using wet muscles, and 100% for both classes on ground freeze-dried fillet.

  4. Galileo infrared imaging spectroscopy measurements at venus

    Science.gov (United States)

    Carlson, R.W.; Baines, K.H.; Encrenaz, Th.; Taylor, F.W.; Drossart, P.; Kamp, L.W.; Pollack, James B.; Lellouch, E.; Collard, A.D.; Calcutt, S.B.; Grinspoon, D.; Weissman, P.R.; Smythe, W.D.; Ocampo, A.C.; Danielson, G.E.; Fanale, F.P.; Johnson, T.V.; Kieffer, H.H.; Matson, D.L.; McCord, T.B.; Soderblom, L.A.

    1991-01-01

    During the 1990 Galileo Venus flyby, the Near Infrared Mapping Spectrometer investigated the night-side atmosphere of Venus in the spectral range 0.7 to 5.2 micrometers. Multispectral images at high spatial resolution indicate substantial cloud opacity variations in the lower cloud levels, centered at 50 kilometers altitude. Zonal and meridional winds were derived for this level and are consistent with motion of the upper branch of a Hadley cell. Northern and southern hemisphere clouds appear to be markedly different. Spectral profiles were used to derive lower atmosphere abundances of water vapor and other species.

  5. Variable Temperature Infrared Spectroscopy Investigations of Benzoic Acid Desorption from Sodium and Calcium Montmorillonite Clays.

    Science.gov (United States)

    Nickels, Tara M; Ingram, Audrey L; Maraoulaite, Dalia K; White, Robert L

    2015-12-01

    Processes involved in thermal desorption of benzoic acid from sodium and calcium montmorillonite clays are investigated by using variable temperature diffuse reflection Fourier transform infrared spectroscopy (DRIFTS). By monitoring the temperature dependence of infrared absorbance bands while heating samples, subtle changes in molecular vibrations are detected and employed to characterize specific benzoic acid adsorption sites. Abrupt changes in benzoic acid adsorption site properties occur for both clay samples at about 125 °C. Difference spectra absorbance band frequency variations indicate that adsorbed benzoic acid interacts with interlayer cations through water bridges and that these interactions can be disrupted by the presence of organic anions, in particular, benzoate.

  6. Far-Infrared Spectroscopy of Weakly Bound Hydrated Cluster Molecules

    DEFF Research Database (Denmark)

    Andersen, Jonas

    -sized molecular clusters with water by means of far-infrared and terahertz neon matrix isolation spectroscopy. The embedding of non-covalent cluster molecules in solid cryogenic neon matrices at 2.8 K ensures a high sensitivity for direct spectroscopic observations of the large-amplitude intermolecular...

  7. Infrared Spectroscopy of Divalent Zinc and Cadmium Crown Ether Systems

    NARCIS (Netherlands)

    Cooper, T. E.; Carl, D. R.; Oomens, J.; Steill, J. D.; Armentrout, P. B.

    2011-01-01

    The gas-phase structures of transition-metal dication (Zn2+ and Cd2+) complexes with varying sized crown ethers, 12-crown-4 (12c4), 15-crown-5 (15c5), and 18-crown-6 (18c6), are investigated using infrared multiple photon dissociation (IRMPD) spectroscopy and quantum mechanical calculations. The

  8. Carbon monoxide reduces near-infrared spectroscopy determined 'total' hemoglobin

    DEFF Research Database (Denmark)

    Niemann, Mads J; Sørensen, Henrik; Siebenmann, Christoph

    2017-01-01

    Carbon monoxide (CO) increases middle cerebral artery mean flow velocity (MCAVmean), but the effect of CO on the near-infrared spectroscopy (NIRS) determined cerebral oxygenation (ScO2) is not detailed. In our study, 11 non-smoking subjects breathed 100% O2 through a closed circuit. A CO2 scrubbe...

  9. Photothermal Infrared Spectroscopy of Airborne Samples with Mechanical String Resonators

    DEFF Research Database (Denmark)

    Yamada, Shoko; Schmid, Silvan; Larsen, Tom

    2013-01-01

    the mid-infrared range. As a proof-of-concept, we sample and analyze polyvinylpyrrolidone (PVP) and the IR spectrum measured by photothermal spectroscopy matches the reference IR spectrum measured by an FTIR spectrometer. We further identify the organic surface coating of airborne TiO2 nanoparticles...

  10. Quantifying cerebral hypoxia by near-infrared spectroscopy tissue oximetry

    DEFF Research Database (Denmark)

    Rasmussen, Martin B.; Eriksen, Vibeke R.; Andresen, Bjørn

    2017-01-01

    Tissue oxygenation estimated by near-infrared spectroscopy (NIRS) is a volume-weighted mean of the arterial and venous hemoglobin oxygenation. In vivo validation assumes a fixed arterial-to-venous volume-ratio (AV-ratio). Regulatory cerebro-vascular mechanisms may change the AV-ratio. We used...

  11. Near-infrared spectroscopy for monitoring muscle oxygenation

    DEFF Research Database (Denmark)

    Boushel, Robert Christopher; Piantadosi, C A

    2000-01-01

    Near-infrared spectroscopy (NIRS) is a non-invasive method for monitoring oxygen availability and utilization by the tissues. In intact skeletal muscle, NIRS allows semi-quantitative measurements of haemoglobin plus myoglobin oxygenation (tissue O2 stores) and the haemoglobin volume. Specialized...

  12. Social Perception in Infancy: A Near Infrared Spectroscopy Study

    Science.gov (United States)

    Lloyd-Fox, Sarah; Blasi, Anna; Volein, Agnes; Everdell, Nick; Elwell, Claire E.; Johnson, Mark H.

    2009-01-01

    The capacity to engage and communicate in a social world is one of the defining characteristics of the human species. While the network of regions that compose the social brain have been the subject of extensive research in adults, there are limited techniques available for monitoring young infants. This study used near infrared spectroscopy to…

  13. On-line infrared spectroscopy for bioprocess monitoring.

    Science.gov (United States)

    Landgrebe, Daniel; Haake, Claas; Höpfner, Tim; Beutel, Sascha; Hitzmann, Bernd; Scheper, Thomas; Rhiel, Martin; Reardon, Kenneth F

    2010-09-01

    One of the major aims of bioprocess engineering is the real-time monitoring of important process variables. This is the basis of precise process control and is essential for high productivity as well as the exact documentation of the overall production process. Infrared spectroscopy is a powerful analytical technique to analyze a wide variety of organic compounds. Thus, infrared sensors are ideal instruments for bioprocess monitoring. The sensors are non-invasive, have no time delay due to sensor response times, and have no influence on the bioprocess itself. No sampling is necessary, and several components can be analyzed simultaneously. In general, the direct monitoring of substrates, products, metabolites, as well as the biomass itself is possible. In this review article, insights are provided into the different applications of infrared spectroscopy for bioprocess monitoring and the complex data interpretation. Different analytical techniques are presented as well as example applications in different areas.

  14. Computing protein infrared spectroscopy with quantum chemistry.

    Science.gov (United States)

    Besley, Nicholas A

    2007-12-15

    Quantum chemistry is a field of science that has undergone unprecedented advances in the last 50 years. From the pioneering work of Boys in the 1950s, quantum chemistry has evolved from being regarded as a specialized and esoteric discipline to a widely used tool that underpins much of the current research in chemistry today. This achievement was recognized with the award of the 1998 Nobel Prize in Chemistry to John Pople and Walter Kohn. As the new millennium unfolds, quantum chemistry stands at the forefront of an exciting new era. Quantitative calculations on systems of the magnitude of proteins are becoming a realistic possibility, an achievement that would have been unimaginable to the early pioneers of quantum chemistry. In this article we will describe ongoing work towards this goal, focusing on the calculation of protein infrared amide bands directly with quantum chemical methods.

  15. Infrared spectroscopy of exoplanets: observational constraints.

    Science.gov (United States)

    Encrenaz, Thérèse

    2014-04-28

    The exploration of transiting extrasolar planets is an exploding research area in astronomy. With more than 400 transiting exoplanets identified so far, these discoveries have made possible the development of a new research field, the spectroscopic characterization of exoplanets' atmospheres, using both primary and secondary transits. However, these observations have been so far limited to a small number of targets. In this paper, we first review the advantages and limitations of both primary and secondary transit methods. Then, we analyse what kind of infrared spectra can be expected for different types of planets and discuss how to optimize the spectral range and the resolving power of the observations. Finally, we propose a list of favourable targets for present and future ground-based observations.

  16. Bird sexing by Fourier transform infrared spectroscopy

    Science.gov (United States)

    Steiner, Gerald; Bartels, Thomas; Krautwald-Junghanns, Maria-Elisabeth; Koch, Edmund

    2010-02-01

    Birds are traditionally classified as male or female based on their anatomy and plumage color as judged by the human eye. Knowledge of a bird's gender is important for the veterinary practitioner, the owner and the breeder. The accurate gender determination is essential for proper pairing of birds, and knowing the gender of a bird will allow the veterinarian to rule in or out gender-specific diseases. Several biochemical methods of gender determination have been developed for avian species where otherwise the gender of the birds cannot be determined by their physical appearances or characteristics. In this contribution, we demonstrate that FT-IR spectroscopy is a suitable tool for a quick and objective determination of the bird's gender. The method is based on differences in chromosome size. Male birds have two Z chromosomes and female birds have a W-chromosome and a Z-chromosome. Each Z-chromosome has approx. 75.000.000 bps whereas the W-chromosome has approx. 260.00 bps. This difference can be detected by FT-IR spectroscopy. Spectra were recorded from germ cells obtained from the feather pulp of chicks as well as from the germinal disk of fertilized but non-bred eggs. Significant changes between cells of male and female birds occur in the region of phosphate vibrations around 1080 and 1120 cm-1.

  17. Characterization of Modified and Polymer Coated Alumina Surfaces by Infrared Spectroscopy

    Directory of Open Access Journals (Sweden)

    Ashraf Yehia El-Naggar

    2013-01-01

    Full Text Available The prepared, modified, and coated alumina surfaces were characterized by infrared spectroscopy (FTIR to investigate the surface properties of the individual and double modified samples. FTIR helps in reporting the changes occurred in hydroxyl groups as well as the structure changes as a result of thermal treating, hydrothermal treating, silylation treating, alkali metal treating, coating, and bonding with polymer. FTIR spectroscopy represents the strength and abundance of surface acidic OH which determine the adsorption properties of polar and nonpolar sorbents. Generally, all treated samples exhibit decrease of OH groups compared with those of parent ones producing alumina surfaces of different adsorptive powers.

  18. Infrared landmine detection and thermal model analysis

    NARCIS (Netherlands)

    Schwering, P.B.W.; Kokonozi, A.; Carter, L.J.; Lensen, H.A.; Franken, E.M.

    2001-01-01

    Infrared imagers are capable of the detection of surface laid mines. Several sensor fused land mine detection systems make use of metal detectors, ground penetrating radar and infrared imagers. Infrared detection systems are sensitive to apparent temperature contrasts and their detection

  19. Nanomechanical Infrared Spectroscopy with Vibrating Filters for Pharmaceutical Analysis

    DEFF Research Database (Denmark)

    Kurek, Maksymilian; Carnoy, Matthias; Larsen, Peter Emil

    2017-01-01

    Standard infrared spectroscopy techniques are well-developed and widely used. However, they typically require milligrams of sample and can involve time-consuming sample preparation. A promising alternative is represented by nanomechanical infrared spectroscopy (NAM-IR) based on the photothermal r...... perform a chemical and morphological analysis on roughly 100 pg of sample. With an absolute estimated sensitivity of 109±15 fg, the presented method is suitable for ultrasensitive vibrational spectroscopy....... response of a nanomechanical resonator, which enables the chemical analysis of picograms of analyte directly from a liquid solution in only a few minutes. Herein, we present NAM-IR using perforated membranes (filters). The method was tested with the pharmaceutical compound indomethacin to successfully...

  20. Vibrational Spectroscopy of Intramolecular Hydrogen Bonds in the Infrared and Near-Infrared Regions

    DEFF Research Database (Denmark)

    Schrøder, Sidsel Dahl

    and 1,4-diaminobutane). Experimentally, the hydrogen bonds have been studied with vibrational spectroscopy in the infrared and near-infrared regions. The focus is primarily on spectra recorded in the near-infrared regions, which in these studies are dominated by O-H and N-H stretching overtones....... Overtone spectra have been recorded with intracavity laser photoacoustic laser spectroscopy and conventional long path absorption spectroscopy. Theoretically, a combination of electronic structure calculations and local mode models have been employed to guide the assignment of bands in the vibrational......, weak intramolecular hydrogen bonds in methyl lactate, allyl carbinol and methallyl carbinol have been identified and characterized. The effect of substitution of two hydrogen atoms on one of the methylene groups with either methyl groups or tri uoromethyl groups on the intramolecular...

  1. Proposal of novel measurement method for thermal diffusivity from infrared thermal movie

    Science.gov (United States)

    Okamoto, Yoichi; Watanabe, Shin; Ogata, Kento; Hiramatsu, Koji; Miyazaki, Hisashi; Morimoto, Jun

    2017-05-01

    A brand new thermal diffusivity measurement method was developed. In this new noncontact and absolute measurement method, thermal diffusivity was measured from infrared movie data. The model of one-dimensional thermal conduction was constructed by taking into account the thermal flow other than one-dimensional thermal conduction in the sample. On the basis of this thermal conduction model, the analytical equation for calculating thermal diffusivity was derived. A single-crystal sapphire plate was used as a test specimen for the new method. The test specimen was arranged to cause one-dimensional heat conduction. Infrared movies were taken by using an infrared camera at room temperature. Then, thermal diffusivity was numerically calculated from the acquired movie data using the analytical equation. It was experimentally demonstrated that thermal diffusivity was measured with an accuracy of around 10% error, from an infrared movie of a single-crystal sapphire sample.

  2. 3D Temperature Distribution Model Based on Thermal Infrared Image

    Directory of Open Access Journals (Sweden)

    Tong Jia

    2017-01-01

    Full Text Available This paper aims to study the construction of 3D temperature distribution reconstruction system based on binocular vision technology. Initially, a traditional calibration method cannot be directly used, because the thermal infrared camera is only sensitive to temperature. Therefore, the thermal infrared camera is calibrated separately. Belief propagation algorithm is also investigated and its smooth model is improved in terms of stereo matching to optimize mismatching rate. Finally, the 3D temperature distribution model is built based on the matching of 3D point cloud and 2D thermal infrared information. Experimental results show that the method can accurately construct the 3D temperature distribution model and has strong robustness.

  3. OBSERVED ASTEROID SURFACE AREA IN THE THERMAL INFRARED

    Energy Technology Data Exchange (ETDEWEB)

    Nugent, C. R. [Infrared Processing and Analysis Center, California Institute of Technology, Pasadena, CA 91125 (United States); Mainzer, A.; Masiero, J.; Bauer, J.; Kramer, E.; Sonnett, S. [Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109 (United States); Wright, E. L. [Department of Physics and Astronomy, University of California, Los Angeles, CA 90095 (United States); Grav, T. [Planetary Science Institute, Tucson, AZ (United States)

    2017-02-01

    The rapid accumulation of thermal infrared observations and shape models of asteroids has led to increased interest in thermophysical modeling. Most of these infrared observations are unresolved. We consider what fraction of an asteroid’s surface area contributes the bulk of the emitted thermal flux for two model asteroids of different shapes over a range of thermal parameters. The resulting observed surface in the infrared is generally more fragmented than the area observed in visible wavelengths, indicating high sensitivity to shape. For objects with low values of the thermal parameter, small fractions of the surface contribute the majority of thermally emitted flux. Calculating observed areas could enable the production of spatially resolved thermal inertia maps from non-resolved observations of asteroids.

  4. Infrared thermography: A non-invasive window into thermal physiology.

    Science.gov (United States)

    Tattersall, Glenn J

    2016-12-01

    Infrared thermography is a non-invasive technique that measures mid to long-wave infrared radiation emanating from all objects and converts this to temperature. As an imaging technique, the value of modern infrared thermography is its ability to produce a digitized image or high speed video rendering a thermal map of the scene in false colour. Since temperature is an important environmental parameter influencing animal physiology and metabolic heat production an energetically expensive process, measuring temperature and energy exchange in animals is critical to understanding physiology, especially under field conditions. As a non-contact approach, infrared thermography provides a non-invasive complement to physiological data gathering. One caveat, however, is that only surface temperatures are measured, which guides much research to those thermal events occurring at the skin and insulating regions of the body. As an imaging technique, infrared thermal imaging is also subject to certain uncertainties that require physical modelling, which is typically done via built-in software approaches. Infrared thermal imaging has enabled different insights into the comparative physiology of phenomena ranging from thermogenesis, peripheral blood flow adjustments, evaporative cooling, and to respiratory physiology. In this review, I provide background and guidelines for the use of thermal imaging, primarily aimed at field physiologists and biologists interested in thermal biology. I also discuss some of the better known approaches and discoveries revealed from using thermal imaging with the objective of encouraging more quantitative assessment. Copyright © 2016 Elsevier Inc. All rights reserved.

  5. Emerging techniques for soil analysis via mid-infrared spectroscopy

    Science.gov (United States)

    Linker, R.; Shaviv, A.

    2009-04-01

    Transmittance and diffuse reflectance (DRIFT) spectroscopy in the mid-IR range are well-established methods for soil analysis. Over the last five years, additional mid-IR techniques have been investigated, and in particular: 1. Attenuated total reflectance (ATR) Attenuated total reflectance is commonly used for analysis of liquids and powders for which simple transmittance measurements are not possible. The method relies on a crystal with a high refractive index, which is in contact with the sample and serves as a waveguide for the IR radiation. The radiation beam is directed in such a way that it hits the crystal/sample interface several times, each time penetrating a few microns into the sample. Since the penetration depth is limited to a few microns, very good contact between the sample and the crystal must be ensured, which can be achieved by working with samples close to water saturation. However, the strong absorbance of water in the mid-infrared range as well as the absorbance of some soil constituents (e.g., calcium carbonate) interfere with some of the absorbance bands of interest. This has led to the development of several post-processing methods for analysis of the spectra. The FTIR-ATR technique has been successfully applied to soil classification as well as to determination of nitrate concentration [1, 6-8, 10]. Furthermore, Shaviv et al. [12] demonstrated the possibility of using fiber optics as an ATR devise for direct determination of nitrate concentration in soil extracts. Recently, Du et al. [5] showed that it is possible to differentiate between 14N and 15N in such spectra, which opens very promising opportunities for developing FTIR-ATR based methods for investigating nitrogen transformation in soils by tracing changes in N-isotopic species. 2. Photo-acoustic spectroscopy Photoacoustic spectroscopy (PAS) is based on absorption-induced heating of the sample, which produces pressure fluctuations in a surrounding gas. These fluctuations are

  6. Estimating Clothing Thermal Insulation Using an Infrared Camera

    National Research Council Canada - National Science Library

    Lee, Jeong-Hoon; Kim, Young-Keun; Kim, Kyung-Soo; Kim, Soohyun

    2016-01-01

    In this paper, a novel algorithm for estimating clothing insulation is proposed to assess thermal comfort, based on the non-contact and real-time measurements of the face and clothing temperatures by an infrared camera...

  7. TATP and TNT detection by mid-infrared transmission spectroscopy

    Science.gov (United States)

    Herbst, Johannes; Hildenbrand, Jürgen; Wöllenstein, Jürgen; Lambrecht, Armin

    2009-05-01

    Sensitive and fast detection of explosives remains a challenge in many threat scenarios. Fraunhofer IPM works on two different detection methods using mid-infrared absorption spectroscopy in combination with quantum cascade lasers (QCL). 1. stand-off detection for a spatial distance of several meters and 2. contactless extractive sampling for short distance applications. The extractive method is based on a hollow fiber that works as gas cell and optical waveguide for the QCL light. The samples are membranes contaminated with the explosives and real background. The low vapor pressure of TNT requires a thermal desorbtion to introduce gaseous TNT and TATP into the heated fiber. The advantage of the hollow fiber setup is the resulting small sample volume. This enables a fast gas exchange rate and fast detection in the second range. The presented measurement setup achieves a detection limit of around 58 ng TNT and 26 ng TATP for 1 m hollow fiber. TATP - an explosive with a very high vapor pressure in comparison to TNT or other explosives - shows potential for an adequate concentration in gas phase under normal ambient conditions and thus the possibility of an explosive detection using open path absorption of TATP at 8 μm wavelength. In order to lower the cross sensitivities or interferents with substances with an absorption in the wavelength range of the TATP absorption the probe volume is checked synchronously by a second QCL emitting beside the target absorption wavelength. In laboratory measurements a detection limit of 5 ppm*m TATP are achieved.

  8. [Application of near-infrared spectroscopy technology in quality control of TCM manufacturing process].

    Science.gov (United States)

    Tu, Yaosheng; Liu, Jun; Zhang, Jianjun

    2011-09-01

    With the development of research in near-infrared spectroscopy technology, near-infrared spectroscopy are increasingly employed in quality control of traditional Chinese medicine (TCM) manufacturing process. The recent researches in relative field were summarized in this paper. Perspective of near-infrared spectroscopy technology in quality control of TCM manufacturing process was also presented in this paper.

  9. Coupling Raman spectroscopy and infrared thermography to evaluate energy exchanges with PCM embedded into pavement

    Science.gov (United States)

    Marchetti, Mario; Dumoulin, Jean; Ibos, Laurent; Piau, Jean-Michel; Fois, Magali; Bourson, Patrice

    2017-04-01

    Some innovative research was jointly conducted between IFSTTAR, Cerema and Universities of Paris Est Créteil and Lorraine to evaluate the energy impact of PCM embedded into pavement as a sustainable solution for both winter maintenance and summer heat mitigation. Usually, two main techniques were separately used. Raman spectroscopy and DSC helped to characterize the temperature of the phase transition and enthalpy within specific temperature variation conditions. On the other hand, infrared thermography monitored temperature variations at the pavement surface generated by the energy released or absorbed during the phase transition phenomenon. Nevertheless, there is a time phase shift which is difficult to evaluate between the moment the phase transition starts and the moment it is detected with an infrared camera. To properly identify to what extent the energy exchanges is detected and the phase shift is important or not, both Raman spectroscopy and infrared thermography were couples in one single original experiment. A PCM volume was embedded into a pavement sample. The later was thermally carefully insulated on all faces but the surface. A Raman probe was inserted into the PCM volume, while an infrared camera monitored pavement surface temperature. The whole set was submitted to air temperature variations. Raman spectra were then analyzed to identify when the phase transition took place, and thermal images when its manifestation on the surface occurred. Results were then discussed to identify the relevance of the use of PCM, while some numerical investigations conducted to search for the optimal configuration.

  10. Study on Senna alata and its different extracts by Fourier transform infrared spectroscopy and two-dimensional correlation infrared spectroscopy

    Science.gov (United States)

    Adiana, M. A.; Mazura, M. P.

    2011-04-01

    Senna alata L. commonly known as candle bush belongs to the family of Fabaceae and the plant has been reported to possess anti-inflammatory, analgesic, laxative and antiplatelet-aggregating activity. In order to develop a rapid and effective analysis method for studying integrally the main constituents in the medicinal materials and their extracts, discriminating the extracts from different extraction process, comparing the categories of chemical constituents in the different extracts and monitoring the qualities of medicinal materials, we applied Fourier transform infrared spectroscopy (FT-IR) associated with second derivative infrared spectroscopy and two-dimensional infrared correlation spectroscopy (2D-IR) to study the main constituents of S. alata and its different extracts (extracted by hexane, dichloromethane, ethyl acetate and methanol in turn). The findings indicated that FT-IR and 2D-IR can provide many holistic variation rules of chemical constituents. Use of the macroscopical fingerprint characters of FT-IR and 2D-IR spectrum can identify the main chemical constituents in medicinal materials and their extracts, but also compare the components differences among similar samples. In a conclusion, FT-IR spectroscopy combined with 2D correlation analysis provides a powerful method for the quality control of traditional medicines.

  11. Chemical structure of wood charcoal by infrared spectroscopy and multivariate analysis.

    Science.gov (United States)

    Labbé, Nicole; Harper, David; Rials, Timothy; Elder, Thomas

    2006-05-17

    In this work, the effect of temperature on charcoal structure and chemical composition is investigated for four tree species. Wood charcoal carbonized at various temperatures is analyzed by mid infrared spectroscopy coupled with multivariate analysis and by thermogravimetric analysis to characterize the chemical composition during the carbonization process. The multivariate models of charcoal were able to distinguish between species and wood thermal treatments, revealing that the characteristics of the wood charcoal depend not only on the wood species, but also on the carbonization temperature. This work demonstrates the potential of mid infrared spectroscopy in the whiskey industry, from the identification and classification of the wood species for the mellowing process to the chemical characterization of the barrels after the toasting and charring process.

  12. [Application of near infrared spectroscopy technology (NIRS) in forage field].

    Science.gov (United States)

    Yan, Xu; Bai, Shi-Qie; Yan, Jia-Jun; Gan, You-Min; Dao, Zhi-Xue

    2012-07-01

    The majority of nutrients in ruminants and other herbivores come from forages. Forage quality not only affects the growth and production efficiency of livestock, but also determines the final output and quality of livestock products. Forage quality mainly depends on nutrient concentrations and their digestibility, palatability and the level of presence of antiquality factors and mycotoxins in forage. Near infrared reflectance spectroscopy (NIRS) has been widely used in many research areas because it is a inexpensive, rapid, simple and nondestructive technique offering the potential for qualitative and quantitative analysis. The present paper briefly introduces the principle and characteristics of NIRS, detailedly expounds the application of NIRS in forage quality. In addition, other applications of near infrared spectroscopy technique in forage are also discussed, including forage breeding, identification of variety and classification by kind. This paper comprehensively reviews the status quo of application of NIRS in forage filed, in order to contribute to promoting development of NIRS in this field in China.

  13. Protein folding and misfolding shining light by infrared spectroscopy

    CERN Document Server

    Fabian, Heinz

    2012-01-01

    Infrared spectroscopy is a new and innovative technology to study protein folding/misfolding events in the broad arsenal of techniques conventionally used in this field. The progress in understanding protein folding and misfolding is primarily due to the development of biophysical methods which permit to probe conformational changes with high kinetic and structural resolution. The most commonly used approaches rely on rapid mixing methods to initiate the folding event via a sudden change in solvent conditions. Traditionally, techniques such as fluorescence, circular dichroism or visible absorption are applied to probe the process. In contrast to these techniques, infrared spectroscopy came into play only very recently, and the progress made in this field up to date which now permits to probe folding events over the time scale from picoseconds to minutes has not yet been discussed in a book. The aim of this book is to provide an overview of the developments as seen by some of the main contributors to the field...

  14. Practical guide to interpretive near-infrared spectroscopy

    CERN Document Server

    Workman, Jr, Jerry

    2007-01-01

    Containing focused, comprehensive coverage, Practical Guide to Interpretive Near-Infrared Spectroscopy gives you the tools necessary to interpret NIR spectra. The authors present extensive tables, charts, and figures with NIR absorption band assignments and structural information for a broad range of functional groups, organic compounds, and polymers. They include visual spectral representation of all major compound functional groupings and NIR frequency ranges. Organized by functional group type and chemical structure, based on standard compound classification, the chapters are easy to

  15. [Near infrared spectroscopy study on water content in turbine oil].

    Science.gov (United States)

    Chen, Bin; Liu, Ge; Zhang, Xian-Ming

    2013-11-01

    Near infrared (NIR) spectroscopy combined with successive projections algorithm (SPA) was investigated for determination of water content in turbine oil. Through the 57 samples of different water content in turbine oil scanned applying near infrared (NIR) spectroscopy, with the water content in the turbine oil of 0-0.156%, different pretreatment methods such as the original spectra, first derivative spectra and differential polynomial least squares fitting algorithm Savitzky-Golay (SG), and successive projections algorithm (SPA) were applied for the extraction of effective wavelengths, the correlation coefficient (R) and root mean square error (RMSE) were used as the model evaluation indices, accordingly water content in turbine oil was investigated. The results indicated that the original spectra with different water content in turbine oil were pretreated by the performance of first derivative + SG pretreatments, then the selected effective wavelengths were used as the inputs of least square support vector machine (LS-SVM). A total of 16 variables selected by SPA were employed to construct the model of SPA and least square support vector machine (SPA-LS-SVM). There is 9 as The correlation coefficient was 0.975 9 and the root of mean square error of validation set was 2.655 8 x 10(-3) using the model, and it is feasible to determine the water content in oil using near infrared spectroscopy and SPA-LS-SVM, and an excellent prediction precision was obtained. This study supplied a new and alternative approach to the further application of near infrared spectroscopy in on-line monitoring of contamination such as water content in oil.

  16. Characterization of Mucoadhesive Norfloxacin suspensions by fourier transform Infrared Spectroscopy

    OpenAIRE

    Subhashree Sahoo; Chandra Kanti Chakraborti; Pradipta Kumar Behera; Subash Chandra Mishra

    2011-01-01

    Till now very few formulations are available from which the drug is absorbed uniformly so that safe and effective blood level of Norfloxacin could be maintained for a prolonged period. To fulfill this requirement a controlled release mucoadhesive suspension was prepared using mucoadhesive polymers. The chemical interaction between Norfloxacin and different polymers in suspensions has been studied to know their compatibility by Fourier Transform Infrared Spectroscopy (FTIR). Ultrasonication me...

  17. [Infrared spectroscopy and XRD studies of coral fossils].

    Science.gov (United States)

    Chen, Quan-li; Zhou, Guan-min; Yin, Zuo-wei

    2012-08-01

    Coral fossil is an old remain of multicellular animal on the earth, and formed by various geological processes. The structural characteristics and compositions of the coral fossils with different color and radial texture on the surface were studied by infrared absorption spectroscopy and X-ray powder diffraction analyses. The results show that the studied coral fossils mainly are composed of SiO2, and the radial microstructure characterized by the calcareous coral cross-section is preserved. It is formed by metasomatism by SiO2. The infrared absorption spectra of the coral fossil with different color and texture are essentially the same, showing typical infrared absorption spectra of the quartz jade. XRD analysis shows that the main components of the coral fossils with different color and texture are consistent and mainly composed of SiO2 with a trace amount of other minerals and without CaCO3.

  18. Infrared spectroscopy and surface chemistry of aerosols under tropospheric conditions

    Energy Technology Data Exchange (ETDEWEB)

    Weis, D.; Ewing, G.E. [Indiana Univ., Bloomington, IN (United States)

    1995-12-31

    Liquid aerosols are generated by an atomizer under ambient conditions and sent to a 1m absorption cell for infrared spectroscopic interrogation. In the case of water aerosol, the infrared signature contains information, through Mie analysis, on the optical constants and size distribution of the particulates. For salt-containing liquid aerosol, control of relative humidity can force the phase transition to solid particulate. Aerosols of (NH{sub 4}){sub 2} SO{sub 4} having median diameters in the range 0.05 {mu}m to 0.25 {mu}m reveal details of their size, phase, and morphology through infrared spectroscopy. Finally chemical reaction of solid NaCl aerosol with NO{sub 2}, proceeding at the surface, is spectroscopically monitored as the particulates are transformed to NaNO{sub 3}.

  19. Enhancing the Responsivity of Uncooled Infrared Detectors Using Plasmonics for High-Performance Infrared Spectroscopy

    Directory of Open Access Journals (Sweden)

    Amr Shebl Ahmed

    2017-04-01

    Full Text Available A lead zirconate titanate (PZT;Pb(Zr0.52Ti0.48O3 layer embedded infrared (IR detector decorated with wavelength-selective plasmonic crystals has been investigated for high-performance non-dispersive infrared (NDIR spectroscopy. A plasmonic IR detector with an enhanced IR absorption band has been designed based on numerical simulations, fabricated by conventional microfabrication techniques, and characterized with a broadly tunable quantum cascade laser. The enhanced responsivity of the plasmonic IR detector at specific wavelength band has improved the performance of NDIR spectroscopy and pushed the limit of detection (LOD by an order of magnitude. In this paper, a 13-fold enhancement in the LOD of a methane gas sensing using NDIR spectroscopy is demonstrated with the plasmonic IR detector.

  20. Validating an infrared thermal switch as a novel access technology.

    Science.gov (United States)

    Memarian, Negar; Venetsanopoulos, Anastasios N; Chau, Tom

    2010-08-05

    Recently, a novel single-switch access technology based on infrared thermography was proposed. The technology exploits the temperature differences between the inside and surrounding areas of the mouth as a switch trigger, thereby allowing voluntary switch activation upon mouth opening. However, for this technology to be clinically viable, it must be validated against a gold standard switch, such as a chin switch, that taps into the same voluntary motion. In this study, we report an experiment designed to gauge the concurrent validity of the infrared thermal switch. Ten able-bodied adults participated in a series of 3 test sessions where they simultaneously used both an infrared thermal and conventional chin switch to perform multiple trials of a number identification task with visual, auditory and audiovisual stimuli. Participants also provided qualitative feedback about switch use. User performance with the two switches was quantified using an efficiency measure based on mutual information. User performance (p = 0.16) and response time (p = 0.25) with the infrared thermal switch were comparable to those of the gold standard. Users reported preference for the infrared thermal switch given its non-contact nature and robustness to changes in user posture. Thermal infrared access technology appears to be a valid single switch alternative for individuals with disabilities who retain voluntary mouth opening and closing.

  1. Validating an infrared thermal switch as a novel access technology

    Directory of Open Access Journals (Sweden)

    Memarian Negar

    2010-08-01

    Full Text Available Abstract Background Recently, a novel single-switch access technology based on infrared thermography was proposed. The technology exploits the temperature differences between the inside and surrounding areas of the mouth as a switch trigger, thereby allowing voluntary switch activation upon mouth opening. However, for this technology to be clinically viable, it must be validated against a gold standard switch, such as a chin switch, that taps into the same voluntary motion. Methods In this study, we report an experiment designed to gauge the concurrent validity of the infrared thermal switch. Ten able-bodied adults participated in a series of 3 test sessions where they simultaneously used both an infrared thermal and conventional chin switch to perform multiple trials of a number identification task with visual, auditory and audiovisual stimuli. Participants also provided qualitative feedback about switch use. User performance with the two switches was quantified using an efficiency measure based on mutual information. Results User performance (p = 0.16 and response time (p = 0.25 with the infrared thermal switch were comparable to those of the gold standard. Users reported preference for the infrared thermal switch given its non-contact nature and robustness to changes in user posture. Conclusions Thermal infrared access technology appears to be a valid single switch alternative for individuals with disabilities who retain voluntary mouth opening and closing.

  2. Elucidation of intermediates and mechanisms in heterogeneous catalysis using infrared spectroscopy.

    Science.gov (United States)

    Savara, Aditya; Weitz, Eric

    2014-01-01

    Infrared spectroscopy has a long history as a tool for the identification of chemical compounds. More recently, various implementations of infrared spectroscopy have been successfully applied to studies of heterogeneous catalytic reactions with the objective of identifying intermediates and determining catalytic reaction mechanisms. We discuss selective applications of these techniques with a focus on several heterogeneous catalytic reactions, including hydrogenation, deNOx, water-gas shift, and reverse-water-gas shift. The utility of using isotopic substitutions and other techniques in tandem with infrared spectroscopy is discussed. We comment on the modes of implementation and the advantages and disadvantages of the various infrared techniques. We also note future trends and the role of computational calculations in such studies. The infrared techniques considered are transmission Fourier transform infrared spectroscopy, infrared reflection-absorption spectroscopy, polarization-modulation infrared reflection-absorption spectroscopy, sum-frequency generation, diffuse reflectance infrared Fourier transform spectroscopy, attenuated total reflectance, infrared emission spectroscopy, photoacoustic infrared spectroscopy, and surface-enhanced infrared absorption spectroscopy.

  3. Near Infrared Spectroscopy: fundamentals, practical aspects and analytical applications

    Directory of Open Access Journals (Sweden)

    Pasquini Celio

    2003-01-01

    Full Text Available This paper intends to review the basic theory of Near Infrared (NIR Spectroscopy and its applications in the field of Analytical Science. It is addressed to the reader who does not have a profound knowledge of vibrational spectroscopy but wants to be introduced to the analytical potentialities of this fascinating technique and, at same time, be conscious of its limitations. Essential theory background, an outline of modern instrument design, practical aspects, and applications in a number of different fields are presented. This work does not intend to supply an intensive bibliography but refers to the most recent, significant and representative material found in the technical literature. Because this paper has been produced as consequence of the First Workshop on Near Infrared Spectroscopy, whose venue was Campinas - Brazil, as a pre-conference activity of the XI National Meeting on Analytical Chemistry (ENQA, it also depicts the state of the art of NIR spectroscopy in Brazil, pointing out the current achievements and the need to take the technology to a level consistent with this country's economical activities.

  4. Factors affecting thermal infrared images at selected field sites

    Energy Technology Data Exchange (ETDEWEB)

    Sisson, J.B.; Ferguson, J.S.

    1993-07-01

    A thermal infrared (TIR) survey was conducted to locate surface ordnance in and around the Naval Ordnance Disposal Area, and a thermal anomaly was found. This report documents studies conducted to identify the position of cause of the thermal anomaly. Also included are results of a long path Fourier transform infrared survey, soil sampling activities, soil gas surveys, and buried heater studies. The results of these studies indicated that the thermal anomaly was caused by a gravel pad, which had thermal properties different than those of the surrounding soil. Results from this investigation suggest that TIR is useful for locating surface objects having a high thermal inertia compared to the surrounding terrain, but TIR is of very limited use for characterizing buried waste or other similar buried objects at the INEL.

  5. Thermal Infrared Imaging-Based Computational Psychophysiology for Psychometrics

    Directory of Open Access Journals (Sweden)

    Daniela Cardone

    2015-01-01

    Full Text Available Thermal infrared imaging has been proposed as a potential system for the computational assessment of human autonomic nervous activity and psychophysiological states in a contactless and noninvasive way. Through bioheat modeling of facial thermal imagery, several vital signs can be extracted, including localized blood perfusion, cardiac pulse, breath rate, and sudomotor response, since all these parameters impact the cutaneous temperature. The obtained physiological information could then be used to draw inferences about a variety of psychophysiological or affective states, as proved by the increasing number of psychophysiological studies using thermal infrared imaging. This paper presents therefore a review of the principal achievements of thermal infrared imaging in computational physiology with regard to its capability of monitoring psychophysiological activity.

  6. Thermal Infrared Imaging-Based Computational Psychophysiology for Psychometrics.

    Science.gov (United States)

    Cardone, Daniela; Pinti, Paola; Merla, Arcangelo

    2015-01-01

    Thermal infrared imaging has been proposed as a potential system for the computational assessment of human autonomic nervous activity and psychophysiological states in a contactless and noninvasive way. Through bioheat modeling of facial thermal imagery, several vital signs can be extracted, including localized blood perfusion, cardiac pulse, breath rate, and sudomotor response, since all these parameters impact the cutaneous temperature. The obtained physiological information could then be used to draw inferences about a variety of psychophysiological or affective states, as proved by the increasing number of psychophysiological studies using thermal infrared imaging. This paper presents therefore a review of the principal achievements of thermal infrared imaging in computational physiology with regard to its capability of monitoring psychophysiological activity.

  7. Infrared Spectroscopy of Noh Suspended in Solid Parahydrogen: Part Two

    Science.gov (United States)

    Balabanoff, Morgan E.; Mutunga, Fredrick M.; Anderson, David T.

    2015-06-01

    The only report in the literature on the infrared spectroscopy of the parent oxynitrene NOH was performed using Ar matrix isolation spectroscopy at 10 K. In this previous study, they performed detailed isotopic studies to make definitive vibrational assignments. NOH is predicted by high-level calculations to be in a triplet ground electronic state, but the Ar matrix isolation spectra cannot be used to verify this triplet assignment. In our 2013 preliminary report, we showed that 193 nm in situ photolysis of NO trapped in solid parahydrogen can also be used to prepare the NOH molecule. Over the ensuing two years we have been studying the infrared spectroscopy of this species in more detail. The spectra reveal that NOH can undergo hindered rotation in solid parahydrogen such that we can observe both a-type and b-type rovibrational transitions for the O-H stretch vibrational mode, but only a-type for the mode assigned to the bend. In addition, both observed a-type infrared absorption features (bend and OH stretch) display fine structure; an intense central peak with weaker peaks spaced symmetrically to both lower and higher wavenumbers. The spacing between the peaks is nearly identical for both vibrational modes. We now believe this fine structure is due to spin-rotation interactions and we will present a detailed analysis of this fine structure. Currently, we are performing additional experiments aimed at making 15NOH to test these preliminary assignments. The most recent data and up-to-date analysis will be presented in this talk. G. Maier, H. P. Reisenauer, M. De Marco, Angew. Chem. Int. Ed. 38, 108-110 (1999). U. Bozkaya, J. M. Turney, Y. Yamaguchi, and H. F. Schaefer III, J. Chem. Phys. 136, 164303 (2012). David T. Anderson and Mahmut Ruzi, 68th Ohio State University International Symposium on Molecular Spectroscopy, talk TE01 (2013).

  8. An infrared spectroscopy method to detect ammonia in gastric juice.

    Science.gov (United States)

    Giovannozzi, Andrea M; Pennecchi, Francesca; Muller, Paul; Balma Tivola, Paolo; Roncari, Silvia; Rossi, Andrea M

    2015-11-01

    Ammonia in gastric juice is considered a potential biomarker for Helicobacter pylori infection and as a factor contributing to gastric mucosal injury. High ammonia concentrations are also found in patients with chronic renal failure, peptic ulcer disease, and chronic gastritis. Rapid and specific methods for ammonia detection are urgently required by the medical community. Here we present a method to detect ammonia directly in gastric juice based on Fourier transform infrared spectroscopy. The ammonia dissolved in biological liquid samples as ammonium ion was released in air as a gas by the shifting of the pH equilibrium of the ammonium/ammonia reaction and was detected in line by a Fourier transform infrared spectroscopy system equipped with a gas cell for the quantification. The method developed provided high sensitivity and selectivity in ammonia detection both in pure standard solutions and in a simulated gastric juice matrix over the range of diagnostic concentrations tested. Preliminary analyses were also performed on real gastric juice samples from patients with gastric mucosal injury and with symptoms of H. pylori infection, and the results were in agreement with the clinicopathology information. The whole analysis, performed in less than 10 min, can be directly applied on the sample without extraction procedures and it ensures high specificity of detection because of the ammonia fingerprint absorption bands in the infrared spectrum. This method could be easily used with endoscopy instrumentation to provide information in real time and would enable the endoscopist to improve and integrate gastroscopic examinations.

  9. Photoacoustic-based detector for infrared laser spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Scholz, L.; Palzer, S., E-mail: stefan.palzer@imtek.uni-freiburg.de [Department of Microsystems Engineering-IMTEK, Laboratory for Gas Sensors, University of Freiburg, Georges-Köhler-Allee 102, Freiburg 79110 (Germany)

    2016-07-25

    In this contribution, we present an alternative detector technology for use in direct absorption spectroscopy setups. Instead of a semiconductor based detector, we use the photoacoustic effect to gauge the light intensity. To this end, the target gas species is hermetically sealed under excess pressure inside a miniature cell along with a MEMS microphone. Optical access to the cell is provided by a quartz window. The approach is particularly suitable for tunable diode laser spectroscopy in the mid-infrared range, where numerous molecules exhibit large absorption cross sections. Moreover, a frequency standard is integrated into the method since the number density and pressure inside the cell are constant. We demonstrate that the information extracted by our method is at least equivalent to that achieved using a semiconductor-based photon detector. As exemplary and highly relevant target gas, we have performed direct spectroscopy of methane at the R3-line of the 2v{sub 3} band at 6046.95 cm{sup −1} using both detector technologies in parallel. The results may be transferred to other infrared-active transitions without loss of generality.

  10. Neuroimaging with functional near infrared spectroscopy: From formation to interpretation

    Science.gov (United States)

    Herrera-Vega, Javier; Treviño-Palacios, Carlos G.; Orihuela-Espina, Felipe

    2017-09-01

    Functional Near Infrared Spectroscopy (fNIRS) is gaining momentum as a functional neuroimaging modality to investigate the cerebral hemodynamics subsequent to neural metabolism. As other neuroimaging modalities, it is neuroscience's tool to understand brain systems functions at behaviour and cognitive levels. To extract useful knowledge from functional neuroimages it is critical to understand the series of transformations applied during the process of the information retrieval and how they bound the interpretation. This process starts with the irradiation of the head tissues with infrared light to obtain the raw neuroimage and proceeds with computational and statistical analysis revealing hidden associations between pixels intensities and neural activity encoded to end up with the explanation of some particular aspect regarding brain function.To comprehend the overall process involved in fNIRS there is extensive literature addressing each individual step separately. This paper overviews the complete transformation sequence through image formation, reconstruction and analysis to provide an insight of the final functional interpretation.

  11. Infrared spectroscopy and spectroscopic imaging in forensic science.

    Science.gov (United States)

    Ewing, Andrew V; Kazarian, Sergei G

    2017-01-16

    Infrared spectroscopy and spectroscopic imaging, are robust, label free and inherently non-destructive methods with a high chemical specificity and sensitivity that are frequently employed in forensic science research and practices. This review aims to discuss the applications and recent developments of these methodologies in this field. Furthermore, the use of recently emerged Fourier transform infrared (FT-IR) spectroscopic imaging in transmission, external reflection and Attenuated Total Reflection (ATR) modes are summarised with relevance and potential for forensic science applications. This spectroscopic imaging approach provides the opportunity to obtain the chemical composition of fingermarks and information about possible contaminants deposited at a crime scene. Research that demonstrates the great potential of these techniques for analysis of fingerprint residues, explosive materials and counterfeit drugs will be reviewed. The implications of this research for the examination of different materials are considered, along with an outlook of possible future research avenues for the application of vibrational spectroscopic methods to the analysis of forensic samples.

  12. Simulating Future Near-Infrared Grism Spectroscopy Using The WFC3 Infrared Spectroscopic Parallels (WISP)

    Science.gov (United States)

    Colbert, James W.; Teplitz, H. I.; Atek, H.; Bunker, A. J.; Rafelski, M.; Scarlata, C.; Ross, N.; Malkan, M. A.; Bedregal, A.; Dominguez, A.; Dressler, A.; Henry, A. L.; Martin, C. L.; Masters, D.; McCarthy, P. J.; Siana, B. D.

    2014-01-01

    We present near-infrared emission line counts and luminosity functions from the HST WFC3 Infrared Spectroscopic Parallels (WISP) program for 29 fields observed using both the G102 and G141 grism. Using these derived emission line counts we make predictions for future space missions, like WFIRST, that will make extensive use of slitless grism spectroscopy in the near-IR over large areas of sky. The WISP survey is sensitive to fainter flux levels (3-5x10^-17 ergs/s/cm2) than the near-infrared grism missions aimed at baryonic acoustic oscillation cosmology (1-4x10^-16 ergs/s/cm2), allowing us to both investigate the fainter emission lines the large area surveys will be missing and make count predictions for the deeper grism pointings that are likely to be done over smaller areas. Cumulative number counts of 0.7WISP survey.

  13. [Near-infrared Raman spectroscopy for diagnosis of gastric cancer].

    Science.gov (United States)

    Jin, Shaoqin; Mao, Hua

    2014-03-01

    To establish a method for early diagnosis of gastric cancer using near-infrared Raman spectroscopy. A rapid near-infrared Raman system was used to examine the tissue specimens of pathologically confirmed gastric cancer (33 cases), gastric precancerous lesions (27 cases), and normal gastric mucosa (45 cases). All the specimens were obtained from 105 patients undergoing gastrectomy or endoscopic biopsy of suspected gastric lesions. High-quality Raman spectra ranging from 700 to 1800 cm(-1) were acquired from the gastric tissues within 5 s. The distribution pattern of Raman spectra in gastric cancer differed significantly from those of gastric precancerous lesions and normal gastric mucosa, particularly in the spectral ranges of 853 cm(-1), 936 cm(-1), 1003 cm(-1), 1032 cm(-1), 1174 cm(-1), 1208 cm(-1), 1323 cm(-1), 1335 cm(-1), 1450 cm(-1), and 1655 cm(-1), which contained signals related to proteins, nucleic acids and lipids. The diagnostic decision algorithm based on the Raman peak intensity ratios of I1003/ I1337, I1003/I1445, I1003/I1655, and I1156/I1655 yielded remarkable differences in gastric cancer from gastric precancerous lesions and normal gastric mucosa, and the ratios were significantly higher in normal gastric tissues (Pinfrared Raman spectroscopy using PCA-LDA algorithms associated with leave- one-out and cross-validation method showed diagnostic sensitivities of 81.5%, 85.3%, and 100%, and specificities of 86.4%, 100%, and 97.4% for normal gastric mucosa, precancerous lesions and gastric cancer, respectively. near-infrared Raman spectroscopy in conjunction with intensity ratio algorithms shows the potential for noninvasive diagnosis and detection of gastric malignancy at the molecular level.

  14. Formation of the thermal infrared continuum in solar flares

    Science.gov (United States)

    Simões, Paulo J. A.; Kerr, Graham S.; Fletcher, Lyndsay; Hudson, Hugh S.; Giménez de Castro, C. Guillermo; Penn, Matt

    2017-09-01

    Aims: Observations of the Sun with the Atacama Large Millimeter Array have now started, and the thermal infrared will regularly be accessible from the NSF's Daniel K. Inouye Solar Telescope. Motivated by the prospect of these new data, and by recent flare observations in the mid infrared, we set out here to model and understand the source of the infrared continuum in flares, and to explore its diagnostic capability for the physical conditions in the flare atmosphere. Methods: We use the one-dimensional (1D) radiation hydrodynamics code RADYN to calculate mid-infrared continuum emission from model atmospheres undergoing sudden deposition of energy by non-thermal electrons. Results: We identify and characterise the main continuum thermal emission processes relevant to flare intensity enhancement in the mid- to far-infrared (2-200 μm) spectral range as free-free emission on neutrals and ions. We find that the infrared intensity evolution tracks the energy input to within a second, albeit with a lingering intensity enhancement, and provides a very direct indication of the evolution of the atmospheric ionisation. The prediction of highly impulsive emission means that, on these timescales, the atmospheric hydrodynamics need not be considered in analysing the mid-IR signatures.

  15. [Application of near infrared spectroscopy in analysis of wood properties].

    Science.gov (United States)

    Yao, Sheng; Pu, Jun-wen

    2009-04-01

    There is substantial interest in the improvement of wood properties through genetic selection or a change in silviculture prescription. Tree breeding purpose requires measurement of a large number of samples. However, traditional methods of assessing wood properties are both time consuming and destructive, limiting the numbers of samples that can be processed, so new method would be needed to find. Near infrared spectroscopy (NIR) is an advanced spectroscopic tool for nondestructive evaluation of wood and it can quickly, accurately estimate the properties of increment core, solid wood or wood meal. The present paper reviews the advances in the research on the wood chemistry properties and anatomical properties using NIR.

  16. The spotted contact binary SS ARIETIS - Spectroscopy and infrared photometry

    Science.gov (United States)

    Rainger, P. P.; Bell, S. A.; Hilditch, R. W.

    1992-02-01

    The first infrared photometry for the W-UMa system SS Ari is presented. An analysis based on medium-resolution spectroscopy presented here shows that SS Ari is a W-type system with a mass ratio of 0.33. It seems certain that the asymmetry in the published light curves and those obtained for this study can be explained by the effect of spots on one or possibly both components of the system. The precise location, size and temperature of these spots require the use of Doppler Imaging techniques in conjunction with high-quality multiband photometry.

  17. Infrared spectroscopy and hydrogen isotope geochemistry of hydrous silicate glasses

    Energy Technology Data Exchange (ETDEWEB)

    Epstein, S.; Stolper, E.

    1992-01-01

    The focus of this project is the combined appication of infrared spectroscopy and stable isotope geochemistry to the study of hydrogen-bearing species dissolved in silicate melts and glasses. We are conducting laboratory experiments aimed at determining the fractionation of D and H between melt species (OH and H{sub 2}O) and hydrous vapor and the diffusivities of these species in glasses and melts. Knowledge of these parameters is critical to understanding the behavior of hydrogen isotopes during igneous processes and hydrothermal processes. These results also could be valuable in application of glass technology to development of nuclear waste disposal strategies.

  18. Fourier transform infrared spectroscopy for analysis of kidney stones.

    Science.gov (United States)

    Khan, Aysha Habib; Imran, Sheharbano; Talati, Jamsheer; Jafri, Lena

    2018-01-01

    To compare the results of a chemical method of kidney stone analysis with the results of Fourier transform infrared (FT-IR) spectroscopy. Kidney stones collected between June and October 2015 were simultaneously analyzed by chemical and FT-IR methods. Kidney stones (n=449) were collected from patients from 1 to 81 years old. Most stones were from adults, with only 11.5% from children (aged 3-16 years) and 1.5% from children aged kidney stones can overcome many limitations associated with chemical analysis.

  19. Optical characterization of semiconductors infrared, Raman, and photoluminescence spectroscopy

    CERN Document Server

    Perkowitz, Sidney

    1993-01-01

    This is the first book to explain, illustrate, and compare the most widely used methods in optics: photoluminescence, infrared spectroscopy, and Raman scattering. Written with non-experts in mind, the book develops the background needed to understand the why and how of each technique, but does not require special knowledge of semiconductors or optics. Each method is illustrated with numerous case studies. Practical information drawn from the authors experience is given to help establish optical facilities, including commercial sources for equipment, and experimental details. For industrial sci

  20. NIRS - Near infrared spectroscopy - investigations in neurovascular diseases

    DEFF Research Database (Denmark)

    Schytz, Henrik Winther

    2015-01-01

    The purpose of this thesis was to explore and develop methods, where continuous wave near infrared spectroscopy (CW-NIRS) can be applied in different neurovascular diseases, in order to find biological markers that are useful in clinical neurology. To develop a new method to detect changes......, but this requires an acceptable LFOs variation between hemispheres and over time in the healthy brain. The second study therefore investigated day-to-day and hemispheric variations in LFOs with NIRS. It was shown that NIRS might be useful in assessing LFOs between hemispheres, as well as interhemispheric phase...

  1. Investigations into Soil Composition and Texture Using Infrared Spectroscopy (2–14 μm

    Directory of Open Access Journals (Sweden)

    Robert D. Hewson

    2012-01-01

    Full Text Available The ability of thermal and shortwave infrared spectroscopy to characterise composition and texture was evaluated using both particle size separated soil samples and natural soils. Particle size analysis and separation into clay, silt, and sand-sized soil fractions was undertaken to examine possible relationships between quartz and clay mineral spectral signatures and soil texture. Spectral indices, based on thermal infrared specular and volume scattering features, were found to discriminate clay mineral-rich soil from mostly coarser quartz-rich sandy soil and to a lesser extent from the silty quartz-rich soil. Further investigations were undertaken using spectra and information on 51 USDA and other soils within the ASTER spectral library to test the application of shortwave, mid- and thermal infrared spectral indices for the derivation of clay mineral, quartz, and organic carbon content. A nonlinear correlation between quartz content and a TIR spectral index based on the 8.62 μm was observed. Preliminary efforts at deriving a spectral index for the soil organic carbon content, based on 3.4–3.5 μm fundamental H–C stretching vibration bands, were also undertaken with limited results.

  2. A spectroelectrochemical cell for ultrafast two-dimensional infrared spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    El Khoury, Youssef; Van Wilderen, Luuk J. G. W.; Vogt, Tim; Winter, Ernst; Bredenbeck, Jens, E-mail: bredenbeck@biophysik.uni-frankfurt.org, E-mail: bredenbeck@biophysik.uni-frankfurt.de [Institut für Biophysik, Johann Wolfgang Goethe-Universität, Max-von-Laue-Strasse 1, 60438 Frankfurt (Germany)

    2015-08-15

    A spectroelectrochemical cell has been designed to combine electrochemistry and ultrafast two-dimensional infrared (2D-IR) spectroscopy, which is a powerful tool to extract structure and dynamics information on the femtosecond to picosecond time scale. Our design is based on a gold mirror with the dual role of performing electrochemistry and reflecting IR light. To provide the high optical surface quality required for laser spectroscopy, the gold surface is made by electron beam evaporation on a glass substrate. Electrochemical cycling facilitates in situ collection of ultrafast dynamics of redox-active molecules by means of 2D-IR. The IR beams are operated in reflection mode so that they travel twice through the sample, i.e., the signal size is doubled. This methodology is optimal for small sample volumes and successfully tested with the ferricyanide/ferrocyanide redox system of which the corresponding electrochemically induced 2D-IR difference spectrum is reported.

  3. Predicting rapeseed oil content with near-infrared spectroscopy

    Directory of Open Access Journals (Sweden)

    Roberta Rossato

    2013-12-01

    Full Text Available The objective of this work was to establish a calibration equation and to estimate the efficiency of near-infrared reflectance (NIR spectroscopy for evaluating rapeseed oil content in Southern Brazil. Spectral data from 124 half-sib families were correlated with oil contents determined by the chemical method. The accuracy of the equation was verified by coefficient of determination (R² of 0.92, error of calibration (SEC of 0.78, and error of performance (SEP of 1.22. The oil content of ten genotypes, which were not included in the calibration with NIR, was similar to the one obtained by the standard chemical method. NIR spectroscopy is adequate to differentiate oil content of rapeseed genotypes.

  4. Near-infrared laboratory spectroscopy of mineral chemistry: A review

    Science.gov (United States)

    Meer, Freek van der

    2018-03-01

    Spectroscopy is the science concerned with the investigation and measurement of spectra produced when materials interacts with or emits electromagnetic radiation. Commercial infrared spectrometer were designed from the 1950's onward and found their way into the pharmaceutical and chemical industries. In the 1970's and 1980's also natural sciences notably mineralogy and vegetation science started systematically to measure optical properties of leaves and minerals/rocks with spectrometers. In the last decade spectroscopy has made the step from qualitative observations of mineral classes, soil type and vegetation biomass to quantitative estimates of mineral, soil and vegetation chemistry. This resulted in geothermometers used to characterize metamorphic and hydrothermal systems and to the advent of foliar biochemistry. More research is still needed to bridge the gap between laboratory spectroscopy and field spectroscopy. Empirical studies of minerals either as soil or rock constituents (and vegetation parameters) derived from regression analysis of spectra against chemistry is important in understanding the physics of the interaction of electromagnetic radiation and matter which in turn is important in the design of future satellite missions. Physics based models and retrievals are needed to operationalize these relationships and implement them in future earth observation missions as these are more robust and easy to transfer to other areas and data sets.

  5. Distinction of three wood species by Fourier transform infrared spectroscopy and two-dimensional correlation IR spectroscopy

    Science.gov (United States)

    Huang, Anmin; Zhou, Qun; Liu, Junliang; Fei, Benhua; Sun, Suqin

    2008-07-01

    Dalbergia odorifera T. Chen, Pterocarpus santalinus L.F. and Pterocarpus soyauxii are three kinds of the most valuable wood species, which are hard to distinguish. In this paper, differentiation of D. odorifera, P. santalinus and P. soyauxii was carried out by using Fourier transform infrared spectroscopy (FT-IR), second derivative IR spectra and two-dimensional correlation infrared (2D-IR) spectroscopy. The three woods have their characteristic peaks in conventional IR spectra. For example, D. odorifera has obvious absorption peaks at 1640 and 1612 cm -1; P. santalinus has only one peak at 1614 cm -1; and P. soyauxii has one peak at 1619 cm -1 and one shoulder peak at 1597 cm -1. To enhance spectrum resolution and amplify the differences between the IR spectra of different woods, the second derivative technology was adopted to examine the three wood samples. More differences could be observed in the region of 800-1700 cm -1. Then, the thermal perturbation is applied to distinguish different wood samples in an easier way, because of the spectral resolution being enhanced by the 2D correlation spectroscopy. In the region of 1300-1800 cm -1, D. odorifera has five auto-peaks at 1518, 1575, 1594, 1620 and 1667 cm -1; P. santalinus has four auto-peaks at 1469, 1518, 1627 and 1639 cm -1 and P. soyauxii has only two auto-peaks at 1627 and 1639 cm -1. It is proved that the 2D correlation IR spectroscopy can be a new method to distinguish D. odorifera, P. santalinus and P. soyauxii.

  6. Mid-infrared absorption spectroscopy using quantum cascade lasers

    Science.gov (United States)

    Haibach, Fred; Erlich, Adam; Deutsch, Erik

    2011-06-01

    Block Engineering has developed an absorption spectroscopy system based on widely tunable Quantum Cascade Lasers (QCL). The QCL spectrometer rapidly cycles through a user-selected range in the mid-infrared spectrum, between 6 to 12 μm (1667 to 833 cm-1), to detect and identify substances on surfaces based on their absorption characteristics from a standoff distance of up to 2 feet with an eye-safe laser. It can also analyze vapors and liquids in a single device. For military applications, the QCL spectrometer has demonstrated trace explosive, chemical warfare agent (CWA), and toxic industrial chemical (TIC) detection and analysis. The QCL's higher power density enables measurements from diffuse and highly absorbing materials and substrates. Other advantages over Fourier Transform Infrared (FTIR) spectroscopy include portability, ruggedness, rapid analysis, and the ability to function from a distance through free space or a fiber optic probe. This paper will discuss the basic technology behind the system and the empirical data on various safety and security applications.

  7. Prediction of Canola Residue Characteristics Using Near-Infrared Spectroscopy

    Directory of Open Access Journals (Sweden)

    Tami L. Stubbs

    2017-01-01

    Full Text Available Little work has been done to characterize and quantify the residue traits affecting decomposition of winter and spring canola (Brassica napus L. residue in dryland farming systems of the Pacific Northwest United States. Traditional methods of characterizing residue fiber and nutrients are time-consuming and expensive and require large quantities of chemical reagents. The goal of this research was to determine whether near-infrared spectroscopy (NIRS could accurately predict neutral detergent fiber (NDF, acid detergent fiber (ADF, acid detergent lignin (ADL, carbon (C, and nitrogen (N of canola stems, litter, and roots and decomposition of canola stems. Canola residue varied in decomposition, fiber, and nutrients by year, location, and type. NIRS predictions were successful for NDF and ADF in 2011 (standard error of prediction SEP0.95 and NDF, ADF, and N in 2012 (SEP0.91. Other predictions for residue fiber and nutrient characteristics were considered moderately successful. Prediction of canola residue decomposition with NIRS was useful for screening purposes. Near-infrared spectroscopy shows promise for rapidly and reproducibly predicting some canola residue fiber and nutrient traits and may be useful for estimating residue decomposition potential in dryland conservation cropping systems.

  8. Infrared spectroscopy as a screening technique for colitis

    Science.gov (United States)

    Titus, Jitto; Ghimire, Hemendra; Viennois, Emilie; Merlin, Didier; Perera, A. G. Unil

    2017-05-01

    There remains a great need for diagnosis of inflammatory bowel disease (IBD), for which the current technique, colonoscopy, is not cost-effective and presents a non-negligible risk for complications. Attenuated Total Reflectance Fourier Transform Infrared (ATR-FTIR) spectroscopy is a new screening technique to evaluate colitis. Comparing infrared spectra of sera to study the differences between them can prove challenging due to the complexity of its biological constituents giving rise to a plethora of vibrational modes. Overcoming these inherent infrared spectral analysis difficulties involving highly overlapping absorbance peaks and the analysis of the data by curve fitting to improve the resolution is discussed. The proposed technique uses colitic and normal wild type mice dried serum to obtain ATR/FTIR spectra to effectively differentiate colitic mice from normal mice. Using this method, Amide I group frequency (specifically, alpha helix to beta sheet ratio of the protein secondary structure) was identified as disease associated spectral signature in addition to the previously reported glucose and mannose signatures in sera of chronic and acute mice models of colitis. Hence, this technique will be able to identify changes in the sera due to various diseases.

  9. Biomedical, environmental, and industrial application of fiber optical infrared spectroscopy

    Science.gov (United States)

    Afanasyeva, Natalia I.; Kolyakov, Sergei F.; Bruch, Reinhard F.; Gummuluri, Satyashree

    2000-07-01

    An advanced infrared interferometric method using fiber optics has been developed for biomedical, environmental and industrial applications. The fiberoptic Evanescent Wave Fourier Transform Infrared (FEW-FTIR) spectroscopy method has been applied to diagnostics of numerous materials including living tissue without sample preparation. This highly sensitive diagnostics tool can conduct surface and subsurface analysis at the molecular level on such diverse materials as human tissue and body fluids, plants, soil, rocks, chemicals, oil, paper and polymers nondestructively, noninvasively in vivo. Operating in the attenuated total reflection regime in the middle-infrared range, the FEW-FTIR technique provides direct contact between the fiber probe and any surface. Our fiber optical spectroscopic device is compact, portable for any application and operates up to a distance of three meters with extremely low loss and nontoxic fibers. This method allows the detection of functional chemical groups and bonds directly from a surface by soft touching of a surface for 15 sec. Applications of this method include (1) early diagnostics of precancerous conditions and other diseases, (2) sun, laser radiation and the influence of other environmental factors (water, pollution and weather), (3) quality control during manufacturing processes, in process analysis.

  10. Characterizing aeroallergens by infrared spectroscopy of fungal spores and pollen.

    Directory of Open Access Journals (Sweden)

    Boris Zimmermann

    Full Text Available Fungal spores and plant pollen cause respiratory diseases in susceptible individuals, such as asthma, allergic rhinitis and hypersensitivity pneumonitis. Aeroallergen monitoring networks are an important part of treatment strategies, but unfortunately traditional analysis is time consuming and expensive. We have explored the use of infrared spectroscopy of pollen and spores for an inexpensive and rapid characterization of aeroallergens.The study is based on measurement of spore and pollen samples by single reflectance attenuated total reflectance Fourier transform infrared spectroscopy (SR-ATR FTIR. The experimental set includes 71 spore (Basidiomycota and 121 pollen (Pinales, Fagales and Poales samples. Along with fresh basidiospores, the study has been conducted on the archived samples collected within the last 50 years.The spectroscopic-based methodology enables clear spectral differentiation between pollen and spores, as well as the separation of confamiliar and congeneric species. In addition, the analysis of the scattering signals inherent in the infrared spectra indicates that the FTIR methodology offers indirect estimation of morphology of pollen and spores. The analysis of fresh and archived spores shows that chemical composition of spores is well preserved even after decades of storage, including the characteristic taxonomy-related signals. Therefore, biochemical analysis of fungal spores by FTIR could provide economical, reliable and timely methodologies for improving fungal taxonomy, as well as for fungal identification and monitoring. This proof of principle study shows the potential for using FTIR as a rapid tool in aeroallergen studies. In addition, the presented method is ready to be immediately implemented in biological and ecological studies for direct measurement of pollen and spores from flowers and sporocarps.

  11. Interpretation of Thermal Infrared Imagery for Irrigation Water Resource Management.

    Science.gov (United States)

    Nellis, M. Duane

    1985-01-01

    Water resources play a major role in the character of agricultural development in the arid western United States. This case study shows how thermal infrared imagery, which is sensitive to radiant or heat energy, can be used to interpret crop moisture content and associated stress in irrigated areas. (RM)

  12. Infrared scanners detect thermal gradients in building walls

    Science.gov (United States)

    Kantsios, A. G.

    1979-01-01

    Presents study on ability of infrared scanner used to detect thermal gradients in outside walls of two homes in Virginia Beach, Virginia under joint effort of Langley Research Center, Virginia Energy Office and Virginia Beach Energy Conservation Pilot Project. Details how study can be used to help minimize energy loss.

  13. Sea surface temperature mapping using a thermal infrared scanner

    Digital Repository Service at National Institute of Oceanography (India)

    RameshKumar, M.R.; Pandya, R.M.; Mathur, K.M.; Charyulu, R.J.K.; Rao, L.V.G.

    1 metre water column below the sea surface. A thermal infrared scanner developed by the Space Applications Centre (ISRO), Ahmedabad was operated on board R.V. Gaveshani in April/May 1984 for mapping SST over the eastern Arabian Sea. SST values...

  14. Thermal infrared sensors for postharvest deficit irrigation of peach

    Science.gov (United States)

    California has been in a historic drought and the lack of water has been a major problem for agriculture especially for crops that depend on irrigation. A multi-year field study was carried out to demonstrate the feasibility of applying thermal infrared sensors for managing deficit irrigation in an ...

  15. Infrared thermal imaging for automated detection of diabetic foot complications

    NARCIS (Netherlands)

    van Netten, Jaap J.; van Baal, Jeff G.; Liu, Chanjuan; van der Heijden, Ferdi; Bus, Sicco A.

    2013-01-01

    Although thermal imaging can be a valuable technology in the prevention and management of diabetic foot disease, it is not yet widely used in clinical practice. Technological advancement in infrared imaging increases its application range. The aim was to explore the first steps in the applicability

  16. Infrared thermal imaging for automated detection of diabetic foot complications

    NARCIS (Netherlands)

    van Netten, Jaap J.; van Baal, Jeff G.; Liu, C.; van der Heijden, Ferdinand; Bus, Sicco A.

    Background: Although thermal imaging can be a valuable technology in the prevention and management of diabetic foot disease, it is not yet widely used in clinical practice. Technological advancement in infrared imaging increases its application range. The aim was to explore the first steps in the

  17. Infrared lens thermal effect: equivalent focal shift and calculating model

    Science.gov (United States)

    Zhang, Cheng-shuo; Shi, Zelin; Feng, Bin; Xu, Bao-shu

    2014-11-01

    It's well-know that the focal shift of infrared lens is the major factor in degeneration of imaging quality when temperature change. In order to figure out the connection between temperature change and focal shift, partial differential equations of thermal effect on light path are obtained by raytrace method, to begin with. The approximately solution of the PDEs show that focal shift is proportional to temperature change. And a formula to compute the proportional factor is given. In order to understand infrared lens thermal effect deeply, we use defocus by image plane shift at constant temperature to equivalently represent thermal effect on infrared lens. So equivalent focal shift (EFS) is defined and its calculating model is proposed at last. In order to verify EFS and its calculating model, Physical experimental platform including a motorized linear stage with built-in controller, blackbody, target, collimator, IR detector, computer and other devices is developed. The experimental results indicate that EFS make the image plane shift at constant temperature have the same influence on infrared lens as thermal effect and its calculating model is correct.

  18. Fourier Transform Infrared Spectroscopy: Part II. Advantages of FT-IR.

    Science.gov (United States)

    Perkins, W. D.

    1987-01-01

    This is Part II in a series on Fourier transform infrared spectroscopy (FT-IR). Described are various advantages of FT-IR spectroscopy including energy advantages, wavenumber accuracy, constant resolution, polarization effects, and stepping at grating changes. (RH)

  19. Agricultural applications for thermal infrared multispectral scanner data

    Science.gov (United States)

    Pelletier, R. E.; Ochoa, M. C.; Hajek, B. F.

    1985-01-01

    The use of the Thermal Infrared Multispectral Scanner (TIMS) data in agricultural landscapes is discussed. The TIMS allows for narrow-band analysis in the 8.2-11.6 micron range at spatial resolutions down to 5 meters in cell size. A coastal plain region in SE Alabama was studied using the TIMS. The crop/plant vigor, canopy density, and thermal response changes for soils obtained from thermal imagery are examined. The application of TIMS data to hydrologic and topographic issues, inventory and conservation monitoring, and the enhancement and extraction of cartographic features is described.

  20. BOOK REVIEW: Infrared Thermal Imaging: Fundamentals, Research and Applications Infrared Thermal Imaging: Fundamentals, Research and Applications

    Science.gov (United States)

    Planinsic, Gorazd

    2011-09-01

    Ten years ago, a book with a title like this would be interesting only to a narrow circle of specialists. Thanks to rapid advances in technology, the price of thermal imaging devices has dropped sharply, so they have, almost overnight, become accessible to a wide range of users. As the authors point out in the preface, the growth of this area has led to a paradoxical situation: now there are probably more infrared (IR) cameras sold worldwide than there are people who understand the basic physics behind them and know how to correctly interpret the colourful images that are obtained with these devices. My experience confirms this. When I started using the IR camera during lectures on the didactics of physics, I soon realized that I needed more knowledge, which I later found in this book. A wide range of potential readers and topical areas provides a good motive for writing a book such as this one, but it also represents a major challenge for authors, as compromises in the style of writing and choice of topics are required. The authors of this book have successfully achieved this, and indeed done an excellent job. This book addresses a wide range of readers, from engineers, technicians, and physics and science teachers in schools and universities, to researchers and specialists who are professionally active in the field. As technology in this area has made great progress in recent times, this book is also a valuable guide for those who opt to purchase an infrared camera. Chapters in this book could be divided into three areas: the fundamentals of IR thermal imaging and related physics (two chapters); IR imaging systems and methods (two chapters) and applications, including six chapters on pedagogical applications; IR imaging of buildings and infrastructure, industrial applications, microsystems, selected topics in research and industry, and selected applications from other fields. All chapters contain numerous colour pictures and diagrams, and a rich list of relevant

  1. Infrared characterization of thermal gradients on disc brakes

    Science.gov (United States)

    Panier, Stephane; Dufrenoy, Philippe; Bremond, Pierre

    2003-04-01

    The heat generated in frictional organs like brakes and clutches induces thermal distortions which may lead to localized contact areas and hot spots developments. Hot spots are high thermal gradients on the rubbing surface. They count among the most dangerous phenomena in frictional organs leading to damage, early failure and unacceptable braking performances such as brake fade or undesirable low frequency vibrations called hot judder. In this paper, an experimental study of hot spots occurrence in railway disc brakes is reported on. The aim of this study was to better classify and to explain the thermal gradients appearance on the surface of the disc. Thermograph measurements with an infrared camera have been carried out on the rubbing surface of brake discs on a full-scale test bench. The infrared system was set to take temperature readings in snap shot mode precisely synchronized with the rotation of the disc. Very short integration time allows reducing drastically haziness of thermal images. Based on thermographs, a classification of hot-spots observed in disc brakes is proposed. A detailed investigation of the most damaging thermal gradients, called macroscopic hot spots (MHS) is given. From these experimental researches, a scenario of hot spots occurrence is suggested step by step. Thanks to infrared measurements at high frequency with high resolution, observations give new highlights on the conditions of hot spots appearance. Comparison of the experimental observations with the theoretical approaches is finally discussed.

  2. Thermal analysis of nanofluids in microfluidics using an infrared camera.

    Science.gov (United States)

    Yi, Pyshar; Kayani, Aminuddin A; Chrimes, Adam F; Ghorbani, Kamran; Nahavandi, Saeid; Kalantar-zadeh, Kourosh; Khoshmanesh, Khashayar

    2012-07-21

    We present the thermal analysis of liquid containing Al(2)O(3) nanoparticles in a microfluidic platform using an infrared camera. The small dimensions of the microchannel along with the low flow rates (less than 120 μl min(-1)) provide very low Reynolds numbers of less than 17.5, reflecting practical parameters for a microfluidic cooling platform. The heat analysis of nanofluids has never been investigated in such a regime, due to the deficiencies of conventional thermal measurement systems. The infrared camera allows non-contact, three dimensional and high resolution capability for temperature profiling. The system was studied at different w/w concentrations of thermally conductive Al(2)O(3) nanoparticles and the experiments were in excellent agreement with the computational fluid dynamics (CFD) simulations.

  3. Infrared spectroscopy of nonclassical ions and their complexes

    Energy Technology Data Exchange (ETDEWEB)

    Boo, Doo Wan [Univ. of California, Berkeley, CA (United States)

    1995-01-01

    This thesis describes an infrared spectroscopic study on the structures and dynamics of the nonclassical ions and their complexes, using ion trap vibrational predissociation spectroscopy. Chapter One provides an introduction to the experimental apparatus used in this work. Chapter Two describes the previous theoretical and experimental works on the carbonium ion CH5+ and infrared spectroscopic and theoretical works on CH5+. CH5+ was predicted to scramble constantly without possessing a stable structure. In Chapter Three, the infrared spectroscopy for the molecular hydrogen solvated carbonium ions CH5+(H2)n (n=1-6) in the frequency region of 2700-4200 cm-1 are presented and compared with the results of ab initio molecular dynamics simulation on CH5+(H2)n (n=0-3). The results suggested that the scrambling of CH5+ slowed down considerably by the stabilization effects of the solvent H2 molecules, and it was completely frozen out when the first three H2 molecules were bound to the core CH5+. Chapter Four presents the complete infrared spectra for the solvated carbonium ions, CH5+(A)x(B)y (A,B=H2, Ar, N2, CH4;x,y=0-5) in the frequency region of 2500-3200 cm-1. As the binding affinities of the solvent molecules and the number of the solvent molecules in the clusters increased, the scrambling of CH5+ slowed down substantially. The structures of the solvated carbonium ions and the evidence for rapid proton transfer in CH5+(CH4) were also presented. Chapter Five presents the vib-rotational spectrum for the H-H stretching mode of the silanium ion SiH5+. The results suggested that Si

  4. Infrared

    Science.gov (United States)

    Vollmer, M.

    2013-11-01

    underlying physics. There are now at least six different disciplines that deal with infrared radiation in one form or another, and in one or several different spectral portions of the whole IR range. These are spectroscopy, astronomy, thermal imaging, detector and source development and metrology, as well the field of optical data transmission. Scientists working in these fields range from chemists and astronomers through to physicists and even photographers. This issue presents examples from some of these fields. All the papers—though some of them deal with fundamental or applied research—include interesting elements that make them directly applicable to university-level teaching at the graduate or postgraduate level. Source (e.g. quantum cascade lasers) and detector development (e.g. multispectral sensors), as well as metrology issues and optical data transmission, are omitted since they belong to fundamental research journals. Using a more-or-less arbitrary order according to wavelength range, the issue starts with a paper on the physics of near-infrared photography using consumer product cameras in the spectral range from 800 nm to 1.1 µm [1]. It is followed by a series of three papers dealing with IR imaging in spectral ranges from 3 to 14 µm [2-4]. One of them deals with laboratory courses that may help to characterize the IR camera response [2], the second discusses potential applications for nondestructive testing techniques [3] and the third gives an example of how IR thermal imaging may be used to understand cloud cover of the Earth [4], which is the prerequisite for successful climate modelling. The next two papers cover the vast field of IR spectroscopy [5, 6]. The first of these deals with Fourier transform infrared spectroscopy in the spectral range from 2.5 to 25 µm, studying e.g. ro-vibrational excitations in gases or optical phonon interactions within solids [5]. The second deals mostly with the spectroscopy of liquids such as biofuels and special

  5. Mid and thermal infrared remote sensing at the Jet Propulsion Laboratory

    Science.gov (United States)

    Johnson, William R.; Hook, Simon J.

    2016-05-01

    The mid and thermal infrared (MTIR) for the Earth surface is defined between 3 and 14µm. In the outer solar system, objects are colder and their Planck response shifts towards longer wavelengths. Hence for these objects (e.g. icy moons, polar caps, comets, Europa), the thermal IR definition usually stretches out to 50µm and beyond. Spectroscopy has been a key part of this scientific exploration because of its ability to remotely determine elemental and mineralogical composition. Many key gas species such as methane, ammonia, sulfur, etc. also have vibrational bands which show up in the thermal infrared spectrum above the background response. Over the past few decades, the Jet Propulsion Laboratory has been building up a portfolio of technology to capture the MTIR for various scientific applications. Three recent sensors are briefly reviewed: The airborne Hyperspectral thermal emission spectrometer (HyTES), the ECOsystem Spaceborne Thermal Radiometer Experiment on Space Station (ECOSTRESS) and Mars Climate Sounder (MCS)/DIVINER. Each of these sensors utilize a different technology to provide a remote sensing product based on MTIR science. For example, HyTES is a push-brooming hyperspectral imager which utilizes a large format quantum well infrared photodetector (QWIP). The goal is to transition this to a new complementary barrier infrared photodetector (CBIRD) with a similar long wave cut-off and increased sensitivity. ECOSTRESS is a push-whisk Mercury Cadmium Telluride (MCT) based high speed, multi-band, imager which will eventually observe and characterize plant/vegetation functionality and stress index from the International Space Station (ISS) across the contiguous United States (CONUS). MCS/DIVINER utilizes thermopile technology to capture the thermal emission from the polar caps and shadow regions of the moon. Each sensor utilizes specific JPL technology to capture unique science.

  6. A novel technique to monitor thermal discharges using thermal infrared imaging.

    Science.gov (United States)

    Muthulakshmi, A L; Natesan, Usha; Ferrer, Vincent A; Deepthi, K; Venugopalan, V P; Narasimhan, S V

    2013-09-01

    Coastal temperature is an important indicator of water quality, particularly in regions where delicate ecosystems sensitive to water temperature are present. Remote sensing methods are highly reliable for assessing the thermal dispersion. The plume dispersion from the thermal outfall of the nuclear power plant at Kalpakkam, on the southeast coast of India, was investigated from March to December 2011 using thermal infrared images along with field measurements. The absolute temperature as provided by the thermal infrared (TIR) images is used in the Arc GIS environment for generating a spatial pattern of the plume movement. Good correlation of the temperature measured by the TIR camera with the field data (r(2) = 0.89) make it a reliable method for the thermal monitoring of the power plant effluents. The study portrays that the remote sensing technique provides an effective means of monitoring the thermal distribution pattern in coastal waters.

  7. Near infrared spectroscopy in animal science production: principles and applications

    Directory of Open Access Journals (Sweden)

    Roberto Riovanto

    2010-01-01

    Full Text Available Near infrared (NIR is one of the techniques belonging to vibrational spectroscopy. Its radiation (750 to 2500nm interacts with organic matter, and the absorption spectrum is rich in chemical and physical information of organic molecules. In order to extract valuable information on the chemical properties of samples, it is necessary to mathematically process spectral data by chemometric tools. The most important part in the development of an NIR method is building the predicting model generally called calibration. NIR spectroscopy has several advantages over other analytical techniques: rapidity of analysis, no use of chemicals, minimal or no samples preparation, easily applicable in different work environments (on/in/at line applications. On the other hand, NIR spectroscopy has some disadvantages: low ability to predict compounds at low concentration (<0.1%, necessity of accurate analysis as reference, development of calibration models required high trained personnel, need of a large and up-to-date calibration data set (often difficult to obtain, difficulties to transfer calibration among instruments, initial high financial investments. In the feed industry, NIR spectroscopy is used for: feed composition, digestibility (in vivo, in vitro, in situ, traceability assessment (to avoid possible frauds. As far as animal products are concerned, NIR spectroscopy has been used to determine the main composition of meat, milk, fish, cheese, eggs. Furthermore, it was also used to predict some physical properties (tenderness, WHC (Water Holding Capacity, drip loss, colour and pH in meat; coagulation ability in milk; freshness, flavour and other sensorial parameters in cheese. Interesting applications of NIR spectroscopy regard issues like: determination of animal products’ authenticity and the detection of adulteration (in order to prevent frauds, discrimination PDO (Protected Designation of Origin and PGI (Protected Geographical Indication from other non

  8. Infrared spectroscopy of organoclays synthesized with the surfactant octadecyltrimethylammonium bromide

    Science.gov (United States)

    Xi, Yunfei; Ding, Zhe; He, Hongping; Frost, Ray L.

    2005-01-01

    Infrared (IR) spectroscopy using a smart endurance single bounce diamond attenuated total reflection (ATR) cell has been used to study the changes in the spectra of the surfactant octadecyltrimethylammonium (ODTMA) bromide upon intercalation into a sodium montmorillonite. The wavenumbers of bands attributed to CH-stretching and CH-bending vibrations, in general, decrease as the concentration of the surfactant measured in terms of the cation exchange capacity (CEC) up to 1.0 CEC. After this point, the bands increase approaching a value the same as that of the surfactant. Significant changes occur in the HCH deformation modes of the methyl groups of the surfactant. These changes are attributed to the methyl groups locking into the siloxane (SiO) surface of the montmorillonite. Such a concept is supported by changes in the SiO-stretching bands of the montmorillonite siloxane surface.

  9. Cerebral near infrared spectroscopy oximetry in extremely preterm infants

    DEFF Research Database (Denmark)

    Hyttel-Sorensen, Simon; Pellicer, Adelina; Alderliesten, Thomas

    2015-01-01

    OBJECTIVE: To determine if it is possible to stabilise the cerebral oxygenation of extremely preterm infants monitored by cerebral near infrared spectroscopy (NIRS) oximetry. DESIGN: Phase II randomised, single blinded, parallel clinical trial. SETTING: Eight tertiary neonatal intensive care units...... in eight European countries. PARTICIPANTS: 166 extremely preterm infants born before 28 weeks of gestation: 86 were randomised to cerebral NIRS monitoring and 80 to blinded NIRS monitoring. The only exclusion criterion was a decision not to provide life support. INTERVENTIONS: Monitoring of cerebral...... with 1.1 (0.1-23.4) %hours in the control group (P=0.98). We found no statistically significant differences between the two groups at term corrected age. No severe adverse reactions were associated with the device. CONCLUSIONS: Cerebral oxygenation was stabilised in extremely preterm infants using...

  10. Prediction of cereal feed value by near infrared spectroscopy

    DEFF Research Database (Denmark)

    Jørgensen, Johannes Ravn

    . The samples originate from available field trials over a three-year period. The chemical reference analyses are dry matter, crude protein, crude ash, crude oils and fats, EDOM, EDOMi, FEso and FEsv. All samples were ground on a laboratory mill and scans were obtained using a QFA-Flex 400 FT-NIR instrument...... and the harvest year. The feed value is described primarily by: Feed value in form of FEsv (Feed unit / kg dry matter, for piglets) and FEso (Feed unit / kg dry matter, for sows), EDOM (Enzyme Degradable Organic Matter) and EDOMi (Enzyme Degradable Organic Matter, Ileum). The chemical analysis is, however, time......-consuming and costly, and it is therefore desirable to have a rapid and less expensive method, which makes it possible to carry out more analyses in-situ. Near infra-red reflection spectroscopy (NIRS) is appropriate as a standard analysis of dry matter, total N, starch and is today used routinely by grain traders...

  11. A rheumatoid arthritis study by Fourier transform infrared spectroscopy

    Science.gov (United States)

    Carvalho, Carolina S.; Silva, Ana Carla A.; Santos, Tatiano J. P. S.; Martin, Airton A.; dos Santos Fernandes, Ana Célia; Andrade, Luís E.; Raniero, Leandro

    2012-01-01

    Rheumatoid arthritis is a systemic inflammatory disease of unknown causes and a new methods to identify it in early stages are needed. The main purpose of this work is the biochemical differentiation of sera between normal and RA patients, through the establishment of a statistical method that can be appropriately used for serological analysis. The human sera from 39 healthy donors and 39 rheumatics donors were collected and analyzed by Fourier Transform Infrared Spectroscopy. The results show significant spectral variations with p<0.05 in regions corresponding to protein, lipids and immunoglobulins. The technique of latex particles, coated with human IgG and monoclonal anti-CRP by indirect agglutination known as FR and CRP, was performed to confirm possible false-negative results within the groups, facilitating the statistical interpretation and validation of the technique.

  12. Discrimination of different Chrysanthemums with Fourier transform infrared spectroscopy

    Science.gov (United States)

    Liu, Hong-xia; Zhou, Qun; Sun, Su-qin; Bao, Hong-juan

    2008-07-01

    Use Fourier transform infrared spectroscopy (FT-IR) to analyze simultaneously the main chemical constituents in different solvent extracts of seven kinds of Chrysanthemum samples of different regions. The findings indicate that different Chrysanthemum samples have dissimilar fingerprint characters in FT-IR spectra. Such spectral technique can provide substance structural information of the complicated test samples. According to these spectral fingerprint features, we cannot only identify the main components of different extracts, but also distinguish the origins of the Chrysanthemum samples from different regions easily, which is a troublesome work by existing analytical methods. FT-IR, with the characters of speediness, good repeatability and easy operation, can be used as an effective analytical means to study the complicated system, in our research, the tradition Chinese medicines.

  13. Functional Near Infrared Spectroscopy: Watching the Brain in Flight

    Science.gov (United States)

    Harrivel, Angela; Hearn, Tristan A.

    2012-01-01

    Functional Near Infrared Spectroscopy (fNIRS) is an emerging neurological sensing technique applicable to optimizing human performance in transportation operations, such as commercial aviation. Cognitive state can be determined via pattern classification of functional activations measured with fNIRS. Operational application calls for further development of algorithms and filters for dynamic artifact removal. The concept of using the frequency domain phase shift signal to tune a Kalman filter is introduced to improve the quality of fNIRS signals in real-time. Hemoglobin concentration and phase shift traces were simulated for four different types of motion artifact to demonstrate the filter. Unwanted signal was reduced by at least 43%, and the contrast of the filtered oxygenated hemoglobin signal was increased by more than 100% overall. This filtering method is a good candidate for qualifying fNIRS signals in real time without auxiliary sensors.

  14. Brain plasticity and rehabilitation by using Near-Infrared Spectroscopy

    Directory of Open Access Journals (Sweden)

    Balconi Michela

    2016-04-01

    Full Text Available The present review elucidated the use of optical imaging technique (Near-Infrared Spectroscopy, NIRS to better explain the brain plasticity for learning mechanisms, rehabilitation and post-traumatic brain recovery. Some recent applications were discussed, with specific focus on the usability of integrated measures (such as electroencephalography, EEG-NIRS; Transcranial Magnet Stimulation, TMS-NIRS to study plasticity and its dynamic effects. NIRS-Neurofeedback and NIRS-BCI (Brain Computer Interface were also explored as possible tools to produce a specific long-lasting learning in relationship with a specific cognitive domain. Finally a proficient domain where NIRS was found to be useful to test neuroplasticity is the interpersonal brain-to-brain coupling, termed “hyperscanning”, a new emerging paradigm in neuroscience which measures brain activity from two or more people simultaneously.

  15. Polymer Characterization by Combined Chromatography-Infrared Spectroscopy

    Directory of Open Access Journals (Sweden)

    James L. Dwyer

    2011-01-01

    Full Text Available Infrared spectroscopy is widely used in the analysis and characterization of polymers. Polymer products are not a singular species, but rather, they are a population of polymer molecules varying in composition and configuration plus other added components. This paper describes instrumentation that provides the benefit or resolving polymer populations into discrete identifiable entities, by combining chromatographic separation with continuous spectra acquisition. The technology also provides a way to determine the mass distribution of discrete components across the chromatographic distribution of a sample. Various examples of application of this technology to polymer products are described. Examples include additives analysis, resolution of polymer blends, composition characterization of copolymers, analysis of degradation byproducts, and techniques of analysis of reactive polymer systems.

  16. Femtosecond infrared spectroscopy of channelrhodopsin-1 chromophore isomerization.

    Science.gov (United States)

    Stensitzki, T; Yang, Y; Muders, V; Schlesinger, R; Heberle, J; Heyne, K

    2016-07-01

    Vibrational dynamics of the retinal all-trans to 13-cis photoisomerization in channelrhodopsin-1 from Chlamydomonas augustae (CaChR1) was investigated by femtosecond visible pump mid-IR probe spectroscopy. After photoexcitation, the transient infrared absorption of C-C stretching modes was detected. The formation of the 13-cis photoproduct marker band at 1193 cm(-1) was observed within the time resolution of 0.3 ps. We estimated the photoisomerization yield to (60 ± 6) %. We found additional time constants of (0.55 ± 0.05) ps and (6 ± 1) ps, assigned to cooling, and cooling processes with a back-reaction pathway. An additional bleaching band demonstrates the ground-state heterogeneity of retinal.

  17. Femtosecond infrared spectroscopy of channelrhodopsin-1 chromophore isomerization

    Directory of Open Access Journals (Sweden)

    T. Stensitzki

    2016-07-01

    Full Text Available Vibrational dynamics of the retinal all-trans to 13-cis photoisomerization in channelrhodopsin-1 from Chlamydomonas augustae (CaChR1 was investigated by femtosecond visible pump mid-IR probe spectroscopy. After photoexcitation, the transient infrared absorption of C-C stretching modes was detected. The formation of the 13-cis photoproduct marker band at 1193 cm−1 was observed within the time resolution of 0.3 ps. We estimated the photoisomerization yield to (60 ± 6 %. We found additional time constants of (0.55 ± 0.05 ps and (6 ± 1 ps, assigned to cooling, and cooling processes with a back-reaction pathway. An additional bleaching band demonstrates the ground-state heterogeneity of retinal.

  18. Identification of Amanita mushrooms by fourier transform infrared spectroscopy

    Science.gov (United States)

    Zhao, Dezhang; Liu, Gang; Song, Dingshan; Liu, Jian-hong; Zhou, Yilan; Ou, Jiaming; Sun, Shizhong

    2006-09-01

    Amanita is one of cosmopolitan genera of basidiomycetes. This genus contains some of the most poisonous toadstools, as well as several species of the most favorite edible mushrooms. In this paper, Fourier transform infrared spectroscopy was used for obtaining vibrational spectra of the fruiting bodies of wild growing Amanita mushrooms. The results show that the mushrooms exhibit characteristic spectra, whose strong absorption bands appear at about 1655, 1076, and 1040 cm -1. The vibrational spectra indicate that the main compositions of the Amanita mushrooms are proteins and polysaccharides. The observed spectral differences might be used to discriminate different species of Amanita. It is showed that FTIR spectroscopic method is a valuable tool for rapid and nondestructive identification of Amanita mushrooms.

  19. Infrared Spectroscopy of Disilicon-Carbide Si_2C

    Science.gov (United States)

    Witsch, Daniel; Lutter, Volker; Fuchs, Guido W.; Gauss, Jürgen; Giesen, Thomas

    2017-06-01

    Small silicon and carbon containing molecules are thought to be important building blocks of interstellar grains. Some of them have been detected in circumstellar environments of late-type stars by means of rotational spectroscopy e.g., SiC, SiC_2, Si_2C, c-SiC_3, SiC_4, while centro-symmetric species, e.g., C_3, C_4, C_5, Si_2C_2, Si_2C_3, can only be detected by vibrational transitions, mainly in the infrared. In view of a new generation of high resolution infrared telescope instruments, e.g., EXES (Echelon-Cross-Echelle Spectrograph) onboard SOFIA (Observatory for Infrared Astronomy) and TEXES (Texas Echelon Cross Echelle Spectrograph) at the Gemini-North observatory, accurate laboratory data of small silicon-carbides in the infrared region are of high demand. In this talk we present first laboratory data of the Si_2C asymmetric stretching mode at 1200 cm^{-1}. A pulsed Nd:YAG-laser is used to vaporize a solid target of silicon exposed to a dilute sample of methane in helium buffer gas. Si_2C is formed in an adiabatic expansion of a supersonic jet and radiation of a quantum cascade laser is used to record rotationally resolved spectra. To date, 160 ro-vibrational lines and have been assigned to the asymmetric stretching vibration of Si_2C, and derived molecular parameters are in excellent agreement with ab initio calculations. In our global fit analysis recently published microwave laboratory data (McCarthy et al. 2015) and astronomical data (Cernicharo et al. 2015) were taken into account. Our new results allow for the identification of Si_2C by means of high resolution infrared astronomy towards the warm background of carbon-rich stars. McCarthy M.C., Baraban J.H., Changala P.B., Stanton J.F., Martin-Drumel M.A, Thorwirth S., et al., J. Chem. Phys. Lett. 6, 2107-2111 (2015). Cernicharo J., McCarthy M.C., Gottlieb C.A., Agundez M., Velilla Prieto L., Baraban J.H., et al. Astrophys. J. Lett. 806,L3 (2015).

  20. Determination of quercetins in onion (Allium cepa) using infrared spectroscopy.

    Science.gov (United States)

    Lu, Xiaonan; Ross, Carolyn F; Powers, Joseph R; Rasco, Barbara A

    2011-06-22

    The rapid quantification of flavonoid compounds in onions by attenuated total reflectance (ATR) Fourier transform infrared (FT-IR) spectroscopy combined with multivariate analysis was evaluated as a possible alternative to high-performance liquid chromatography (HPLC) analysis. Quercetin content in onion varieties (yellow, red, and sweet) was quantified using ATR FT-IR (4000 to 400 cm⁻¹) spectroscopy and HPLC methods. Quercetin-3,4'-O-diglucoside (3,4'-Qdg) and quercetin-4'-O-glucoside (4'-Qmg) comprised >80% of the total flavonol content detected in the studied varieties. The quercetin compounds (3,4'-Qdg and 4'-Qmg) and total flavonol conjugates were quantified by HPLC, and results correlated closely with ATR-IR values (R > 0.95). Cross-validated (leave-one-out) partial least-squares regression (PLSR) models successfully predicted concentrations of these quercetins. The standard errors of cross-validation (SECV) of 3,4'-Qdg and 4'-Qmg, total quercetin, and total flavonol contents of onions were 20.43, 21.18, and 21.02 mg/kg fresh weight, respectively. In addition, supervised and unsupervised segregation analyses (principal component analysis, discriminant function analysis, and soft independent modeling of class analogue) were performed to classify onion varieties on the basis of unique infrared spectral features. There was a high degree of segregation (interclass distances > 3.0) for the different types of onion. This study indicated that the IR technique could predict 3,4'-Qdg, 4'-Qmg, total quercetin, and total flavonol contents and has advantages over the traditional HPLC method in providing a valid, efficient, and cost-effective method requiring less sample preparation for the quantification of quercetins in onion.

  1. Infrared spectroscopy and microscopy in cancer research and diagnosis

    Science.gov (United States)

    Bellisola, Giuseppe; Sorio, Claudio

    2012-01-01

    Since the middle of 20th century infrared (IR) spectroscopy coupled to microscopy (IR microspectroscopy) has been recognized as a non destructive, label free, highly sensitive and specific analytical method with many potential useful applications in different fields of biomedical research and in particular cancer research and diagnosis. Although many technological improvements have been made to facilitate biomedical applications of this powerful analytical technique, it has not yet properly come into the scientific background of many potential end users. Therefore, to achieve those fundamental objectives an interdisciplinary approach is needed with basic scientists, spectroscopists, biologists and clinicians who must effectively communicate and understand each other's requirements and challenges. In this review we aim at illustrating some principles of Fourier transform (FT) Infrared (IR) vibrational spectroscopy and microscopy (microFT-IR) as a useful method to interrogate molecules in specimen by mid-IR radiation. Penetrating into basics of molecular vibrations might help us to understand whether, when and how complementary information obtained by microFT-IR could become useful in our research and/or diagnostic activities. MicroFT-IR techniques allowing to acquire information about the molecular composition and structure of a sample within a micrometric scale in a matter of seconds will be illustrated as well as some limitations will be discussed. How biochemical, structural, and dynamical information about the systems can be obtained by bench top microFT-IR instrumentation will be also presented together with some methods to treat and interpret IR spectral data and applicative examples. The mid-IR absorbance spectrum is one of the most information-rich and concise way to represent the whole “… omics” of a cell and, as such, fits all the characteristics for the development of a clinically useful biomarker. PMID:22206042

  2. Europa Composition Using Visible to Short Wavelength Infrared Spectroscopy

    Science.gov (United States)

    Blaney, Diana L.; Dalton, J. B.; Green, R. O.; Hibbits, K.; McCord, T.; Murchie, S.; Piccioni, G.; Tosi, F.

    2010-10-01

    One of the major goals of the Jupiter Europa Orbiter (JEO) is to understand the chemistry of Europa's inorganic and organic materials. Europa's surface material composition is controlled by the original materials forming Europa and by their differentiation and chemical alterations. Material is probably still being transported to the surface by active processes in the interior. At the surface, the material is exposed to the effects of vacuum and temperature, irradiated by solar UV, and bombarded by material entrained in Jupiter's magnetic field. The materials on the surface and their distributions are evidence of the processes operating, both endogenic and exogenic. These processes include effects of a subsurface liquid ocean and its chemistry; the mechanisms of material emplacement from below; and photolysis and radiolysis. Visible to Short Wavelength Infrared (VSWIR) spectroscopy is a well-understood technique for mapping key inorganic, organic, and volatile compositions on remote surfaces such as Europa. Key spectral absorption features have been detected in both the icy and the non-icy Europa materials and many important constituents of the surface have been identified or proposed (e.g. hydrated salts, sulfuric acid hydrate, organics, CO2, H2O2, SO2). The determination of planetary surface composition from remote infrared spectroscopy depends upon adequate signal-to-noise, spectral resolution, and spatial scale to distinguish the diagnostic spectral features of the compounds of interest. For icy satellites, laboratory reference spectra obtained at the temperatures of the target bodies are also required. We have compared diagnostic spectral features in cryogenic laboratory spectra of hydrated salts relevant to Europa in order to optimize detection of these materials under realistic mission conditions. Effects of spectral resolution, signal to noise ratio, and areal mixtures are explored to determine the impacts on detection. This work was carried out at the Jet

  3. Studies of planetary boundary layer by infrared thermal imagery

    Energy Technology Data Exchange (ETDEWEB)

    Albina, Bogdan; Dimitriu, Dan Gheorghe, E-mail: dimitriu@uaic.ro; Gurlui, Silviu Octavian, E-mail: dimitriu@uaic.ro [Alexandru Ioan Cuza University of Iasi, Faculty of Physics, Atmosphere Optics, Spectroscopy and Lasers Laboratory, 11 Carol I Blvd., 700506 Iasi (Romania); Cazacu, Marius Mihai [Alexandru Ioan Cuza University of Iasi, Faculty of Physics, Atmosphere Optics, Spectroscopy and Lasers Laboratory, 11 Carol I Blvd., 700506 Iasi, Romania and Department of Physics, Gheorghe Asachi Technical University of Iasi, 59A Mangeron Blvd., 700 (Romania); Timofte, Adrian [Alexandru Ioan Cuza University of Iasi, Faculty of Physics, Atmosphere Optics, Spectroscopy and Lasers Laboratory, 11 Carol I Blvd., 700506 Iasi, Romania and National Meteorological Administration, Regional Forecast Center Bacau, 1 Cuza Voda Str., 60 (Romania)

    2014-11-24

    The IR camera is a relatively novel device for remote sensing of atmospheric thermal processes from the Planetary Boundary Layer (PBL) based on measurements of the infrared radiation. Infrared radiation is energy radiated by the motion of atoms and molecules on the surface of aerosols, when their temperature is more than absolute zero. The IR camera measures directly the intensity of radiation emitted by aerosols which is converted by an imaging sensor into an electric signal, resulting a thermal image. Every image pixel that corresponds to a specific radiance is pre-processed to identify the brightness temperature. The thermal infrared imaging radiometer used in this study, NicAir, is a precision radiometer developed by Prata et al. The device was calibrated for the temperature range of 270–320 K and using a calibration table along with image processing software, important information about variations in temperature can be extracted from acquired IR images. The PBL is the lowest layer of the troposphere where the atmosphere interacts with the ground surfaces. The importance of PBL lies in the fact that it provides a finite but varying volume in which pollutants can disperse. The aim of this paper is to analyze the PBL altitude and thickness variations over Iasi region using the IR imaging camera as well as its behavior from day to night and thermal processes occurring in PBL.

  4. Infrared Thermal Imaging System on a Mobile Phone

    Directory of Open Access Journals (Sweden)

    Fu-Feng Lee

    2015-04-01

    Full Text Available A novel concept towards pervasively available low-cost infrared thermal imaging system lunched on a mobile phone (MTIS was proposed and demonstrated in this article. Through digestion on the evolutional development of milestone technologies in the area, it can be found that the portable and low-cost design would become the main stream of thermal imager for civilian purposes. As a representative trial towards this important goal, a MTIS consisting of a thermal infrared module (TIM and mobile phone with embedded exclusive software (IRAPP was presented. The basic strategy for the TIM construction is illustrated, including sensor adoption and optical specification. The user-oriented software was developed in the Android environment by considering its popularity and expandability. Computational algorithms with non-uniformity correction and scene-change detection are established to optimize the imaging quality and efficiency of TIM. The performance experiments and analysis indicated that the currently available detective distance for the MTIS is about 29 m. Furthermore, some family-targeted utilization enabled by MTIS was also outlined, such as sudden infant death syndrome (SIDS prevention, etc. This work suggests a ubiquitous way of significantly extending thermal infrared image into rather wide areas especially health care in the coming time.

  5. Infrared thermal facial image sequence registration analysis and verification

    Science.gov (United States)

    Chen, Chieh-Li; Jian, Bo-Lin

    2015-03-01

    To study the emotional responses of subjects to the International Affective Picture System (IAPS), infrared thermal facial image sequence is preprocessed for registration before further analysis such that the variance caused by minor and irregular subject movements is reduced. Without affecting the comfort level and inducing minimal harm, this study proposes an infrared thermal facial image sequence registration process that will reduce the deviations caused by the unconscious head shaking of the subjects. A fixed image for registration is produced through the localization of the centroid of the eye region as well as image translation and rotation processes. Thermal image sequencing will then be automatically registered using the two-stage genetic algorithm proposed. The deviation before and after image registration will be demonstrated by image quality indices. The results show that the infrared thermal image sequence registration process proposed in this study is effective in localizing facial images accurately, which will be beneficial to the correlation analysis of psychological information related to the facial area.

  6. Nonlinear optics in germanium mid-infrared fiber material: Detuning oscillations in femtosecond mid-infrared spectroscopy

    OpenAIRE

    Ordu, M.; Guo, J.; G. Ng Pack; Shah, P.; S. Ramachandran; Hong, M K; Ziegler, L. D.; S. N. Basu; Erramilli, S

    2017-01-01

    Germanium optical fibers hold great promise in extending semiconductor photonics into the fundamentally important mid-infrared region of the electromagnetic spectrum. The demonstration of nonlinear response in fabricated Ge fiber samples is a key step in the development of mid-infrared fiber materials. Here we report the observation of detuning oscillations in a germanium fiber in the mid-infrared region using femtosecond dispersed pump-probe spectroscopy. Detuning oscillations are observed i...

  7. Mid-Infrared Reflectance Imaging of Thermal-Barrier Coatings

    Science.gov (United States)

    Edlridge, Jeffrey I.; Martin, Richard E.

    2009-01-01

    An apparatus for mid-infrared reflectance imaging has been developed as means of inspecting for subsurface damage in thermal-barrier coatings (TBCs). The apparatus is designed, more specifically, for imaging the progression of buried delamination cracks in plasma-sprayed yttria-stabilized zirconia coatings on turbine-engine components. Progression of TBC delamination occurs by the formation of buried cracks that grow and then link together to produce eventual TBC spallation. The mid-infrared reflectance imaging system described here makes it possible to see delamination progression that is invisible to the unaided eye, and therefore give sufficiently advanced warning before delamination progression adversely affects engine performance and safety. The apparatus (see figure) includes a commercial mid-infrared camera that contains a liquid-nitrogen-cooled focal plane indium antimonide photodetector array, and imaging is restricted by a narrow bandpass centered at wavelength of 4 microns. This narrow wavelength range centered at 4 microns was chosen because (1) it enables avoidance of interfering absorptions by atmospheric OH and CO2 at 3 and 4.25 microns, respectively; and (2) the coating material exhibits maximum transparency in this wavelength range. Delamination contrast is produced in the midinfrared reflectance images because the introduction of cracks into the TBC creates an internal TBC/air-gap interface with a high diffuse reflectivity of 0.81, resulting in substantially higher reflectance of mid-infrared radiation in regions that contain buried delamination cracks. The camera is positioned a short distance (.12 cm) from the specimen. The mid-infrared illumination is generated by a 50-watt silicon carbide source positioned to the side of the mid-infrared camera, and the illumination is collimated and reflected onto the specimen by a 6.35-cm-diameter off-axis paraboloidal mirror. Because the collected images are of a steady-state reflected intensity (in

  8. Infrared absorption spectroscopy of diacetylene ions trapped in solid argon.

    Science.gov (United States)

    Szczepanski, Jan; Wang, Haiyan; Jones, Brittnee; Arrington, Caleb A; Vala, Martin T

    2005-03-07

    The C4H2+ diacetylene radical cation has been generated in a pulsed jet electrical discharge through both a diacetylene/argon mixture and an acetylene/argon mixture. The product mixture was trapped on a 12 K cryostat window and studied via Fourier transform infrared absorption spectroscopy. The diacetylene cation was also produced via low energy electron bombardment of an effusive C4H2/Ar beam. Two new infrared bands at 3201.6 and 1827.9 cm(-1) have been identified as vibrations of the diacetylene cation, viz the v4 (sigmau) (C-H stretching) and the v5(sigmau) (C[triple bond]C stretching) modes, respectively. Geometry optimization and harmonic frequency calculations, carried out at various spin unrestricted levels (B3LYP, CCSD(T)) for spin doublet structures, indicate that, in its electronic ground state X2pi(g), the C4H2+ cation is linear. Three additional new bands at 2957.5, 1693.8 and 594.5 cm(-1) have been tentatively assigned to the C-H stretching, C[triple bond]C stretching and C[triple bond]C-H (in-plane) bending modes, respectively, of the nonlinear diacetylene anion (C4H2-, X2B(u)).

  9. Aerosol collection and analysis using diffuse reflectance infrared spectroscopy

    Science.gov (United States)

    Samuels, Alan C.; Wong, Diane M.; Meyer, Gerald J.; Roelant, Geoffrey J.; Williams, Barry R.; Miles, Ronald W., Jr.; Manning, Christopher J.

    2004-08-01

    Infrared spectroscopy is routinely employed for the identification of organic molecules and, more recently, for the classification of biological materials. We have developed a sample collection method that facilitates infrared analysis of airborne particulates using a diffuse reflectance (DR) technique. Efforts are underway to extend the method to include simultaneous analysis of vapor phase organics by using adsorbent substrates compatible with the DR technique. This series of laboratory results provides proof-of-principle for both the sample collection and data collection processes. Signal processing of the DR spectra is shown to provide rapid qualitative identification of representative aerosol materials, including particulate matter commonly found in the environment. We compare the results for such materials as bacterial spores, pollens and molds, clays and dusts, smoke and soot. Background correction analysis is shown to be useful for differentiation and identification of these constituents. Issues relating to complex mixtures of environmental samples under highly variable conditions are considered. Instrumentation development and materials research are now underway with the aim of constructing a compact sampling system for near real-time monitoring of aerosol and organic pollutants. A miniature, tilt-compensated Fourier transform spectrometer will provide spectroscopic interrogation. A series of advanced digital signal processing methods are also under development to enhance the sensor package. The approach will be useful for industrial applications, chemical and biological agent detection, and environmental monitoring for chemical vapors, hazardous air pollutants, and allergens.

  10. Influence of earlobe thickness on near infrared spectroscopy

    Science.gov (United States)

    Jiang, Jingying; Wang, Tianpei; Li, Si; Li, Lin; Liu, Jiajia; Xu, Kexin

    2017-03-01

    Near-infrared spectroscopy has been recognized as a potential technology for noninvasive blood glucose sensing. However, the detected spectral signal is unstable mainly because of (1) the weak light absorption of glucose itself within NIR range, (2) the influence of temperature and individual differences of biotissue. Our previous results demonstrated that the synergistic effect of both transmittance and reflectance could enhance the strength of the detection signal. In this talk, we design a set of experiments to analyze the effect of earlobe thickness on Near Infrared spectroscopic measurement by using home-made optical fiber probe within the wavelength of 1000-1600nm. Firstly, we made a MC simulation of single-layer skin model and five-layer skin model to get the diffused transmittance spectra and diffused reflectance spectra under different optaical path lengths. And then we obtain the spectra of the earlobes from different volunteers by the same way. The experimental results showed that with the increase of the thickness,the light intensity of diffused transmittance decreases, and the light intensity of diffused reflectance remaines substantially unchanged.

  11. Dairy product analysis: identification of microorganisms by mid-infrared spectroscopy and determination of constituents by Raman spectroscopy.

    Science.gov (United States)

    Fehrmann, A; Franz, M; Hoffmann, A; Rudzik, L; Wüst, E

    1995-01-01

    Identification of microorganisms by traditional microbiological methods is time consuming. The German Federal Health Office has developed a method using mid-infrared spectroscopy to identify microorganisms rapidly. This method has been modified for application to microorganisms important in the dairy industry. Mid- and near-infrared spectroscopies are well-established methods for quantitative measurements of fat, protein, lactose, and solid content in a variety of products. A disadvantage of both methods is the huge absorption due to water; extraction of other components is complicated and can be achieved only statistically. With Raman spectroscopy, water causes less absorption. We investigated the use of Raman spectroscopy as a quantitative method for milk powder.

  12. Infrared spectroscopy: a tool for determination of the degree of conversion in dental composites

    Directory of Open Access Journals (Sweden)

    Luciene Gonçalves Palmeira Moraes

    2008-04-01

    Full Text Available Infrared spectroscopy is one of the most widely used techniques for measurement of conversion degree in dental composites. However, to obtain good quality spectra and quantitative analysis from spectral data, appropriate expertise and knowledge of the technique are mandatory. This paper presents important details to use infrared spectroscopy for determination of the conversion degree.

  13. 7 CFR 801.7 - Reference methods and tolerances for near-infrared spectroscopy (NIRS) analyzers.

    Science.gov (United States)

    2010-01-01

    ... methods and tolerances for near-infrared spectroscopy (NIRS) analyzers. (a) Reference methods. (1) The... 7 Agriculture 7 2010-01-01 2010-01-01 false Reference methods and tolerances for near-infrared spectroscopy (NIRS) analyzers. 801.7 Section 801.7 Agriculture Regulations of the Department of Agriculture...

  14. Near-infrared spectroscopy is feasible to discriminate hazelnut cultivars

    Directory of Open Access Journals (Sweden)

    Elisabetta Stella

    2013-09-01

    Full Text Available The study demonstrated the feasibility of the near infrared (NIR spectroscopy use for hazelnut-cultivar sorting. Hazelnut spectra were acquired from 600 fruit for each cultivar sample, two diffuse reflectance spectra were acquired from opposite sides of the same hazelnut. Spectral data were transformed into absorbance before the computations. A different variety of spectral pretreatments were applied to extract characteristics for the classification. An iterative Linear Discriminant Analysis (LDA algorithm was used to select a relatively small set of variables to correctly classify samples. The optimal group of features selected for each test was analyzed using Partial Least Squares Discriminant Analysis (PLS-DA. The spectral region most frequently chosen was the 1980-2060 nm range, which corresponds to best differentiation performance for a total minimum error rate lower than 1.00%. This wavelength range is generally associated with stretching and bending of the N-H functional group of amino acids and proteins. The feasibility of using NIR Spectroscopy to distinguish different hazelnut cultivars was demonstrated.

  15. Indirect absorption spectroscopy using quantum cascade lasers: mid-infrared refractometry and photothermal spectroscopy.

    Science.gov (United States)

    Pfeifer, Marcel; Ruf, Alexander; Fischer, Peer

    2013-11-04

    We record vibrational spectra with two indirect schemes that depend on the real part of the index of refraction: mid-infrared refractometry and photothermal spectroscopy. In the former, a quantum cascade laser (QCL) spot is imaged to determine the angles of total internal reflection, which yields the absorption line via a beam profile analysis. In the photothermal measurements, a tunable QCL excites vibrational resonances of a molecular monolayer, which heats the surrounding medium and changes its refractive index. This is observed with a probe laser in the visible. Sub-monolayer sensitivities are demonstrated.

  16. Design study for Thermal Infrared Multispectral Scanner (TIMS)

    Science.gov (United States)

    Stanich, C. G.; Osterwisch, F. G.; Szeles, D. M.; Houtman, W. H.

    1981-01-01

    The feasibility of dividing the 8-12 micrometer thermal infrared wavelength region into six spectral bands by an airborne line scanner system was investigated. By combining an existing scanner design with a 6 band spectrometer, a system for the remote sensing of Earth resources was developed. The elements in the spectrometer include an off axis reflective collimator, a reflective diffraction grating, a triplet germanium imaging lens, a photoconductive mercury cadmium telluride sensor array, and the mechanical assembly to hold these parts and maintain their optical alignment across a broad temperature range. The existing scanner design was modified to accept the new spectrometer and two field filling thermal reference sources.

  17. Thermal Design of a Protomodel Space Infrared Cryogenic System

    Directory of Open Access Journals (Sweden)

    Hyung Suk Yang

    2006-06-01

    Full Text Available A Protomodel Space Infrared Cryogenic System (PSICS cooled by a stirling cryocooler has been designed. The PSICS has an IR sensor inside the cold box which is cooled by a stirling cryocooler with refrigeration capacity of 500mW at 80K in a vacuum vessel. It is important to minimize the heat load so that the background thermal noise can be reduced. In order to design the cryogenic system with low heat load and to reduce the remained heat load, we have performed numerical analyses. In this paper, we present the design factors and the results obtained by the thermal analysis of the PSICS.

  18. Thermal Infrared Imaging Spectrometer - An advanced optics technology instrument

    Science.gov (United States)

    Mahoney, Colin; Labaw, Clayton; Sobel, Harold; Kahle, Anne

    1990-01-01

    Through the use of a special optical filter, the Thermal Infrared Imaging Spectrometer, an airborne multispectral IR imaging instrument operating in the thermal emission region (7.5-14 microns), will achieve signal-to-noise ratios greater than 600 with ambient temperature optics. This instrument will be used to do compositional surface mapping of the terrain, and will refine the ability to categorize rock families and types by providing much higher spectral resolution in the emission region than was previously available. Details of the optical system, the detector, the cooler system, and the support electronics are described.

  19. High-speed high-sensitivity infrared spectroscopy using mid-infrared swept lasers (Conference Presentation)

    Science.gov (United States)

    Childs, David T. D.; Groom, Kristian M.; Hogg, Richard A.; Revin, Dmitry G.; Cockburn, John W.; Rehman, Ihtesham U.; Matcher, Stephen J.

    2016-03-01

    Infrared spectroscopy is a highly attractive read-out technology for compositional analysis of biomedical specimens because of its unique combination of high molecular sensitivity without the need for exogenous labels. Traditional techniques such as FTIR and Raman have suffered from comparatively low speed and sensitivity however recent innovations are challenging this situation. Direct mid-IR spectroscopy is being speeded up by innovations such as MEMS-based FTIR instruments with very high mirror speeds and supercontinuum sources producing very high sample irradiation levels. Here we explore another possible method - external cavity quantum cascade lasers (EC-QCL's) with high cavity tuning speeds (mid-IR swept lasers). Swept lasers have been heavily developed in the near-infrared where they are used for non-destructive low-coherence imaging (OCT). We adapt these concepts in two ways. Firstly by combining mid-IR quantum cascade gain chips with external cavity designs adapted from OCT we achieve spectral acquisition rates approaching 1 kHz and demonstrate potential to reach 100 kHz. Secondly we show that mid-IR swept lasers share a fundamental sensitivity advantage with near-IR OCT swept lasers. This makes them potentially able to achieve the same spectral SNR as an FTIR instrument in a time x N shorter (N being the number of spectral points) under otherwise matched conditions. This effect is demonstrated using measurements of a PDMS sample. The combination of potentially very high spectral acquisition rates, fundamental SNR advantage and the use of low-cost detector systems could make mid-IR swept lasers a powerful technology for high-throughput biomedical spectroscopy.

  20. Estimating Clothing Thermal Insulation Using an Infrared Camera

    OpenAIRE

    Jeong-Hoon Lee; Young-Keun Kim; Kyung-Soo Kim; Soohyun Kim

    2016-01-01

    In this paper, a novel algorithm for estimating clothing insulation is proposed to assess thermal comfort, based on the non-contact and real-time measurements of the face and clothing temperatures by an infrared camera. The proposed method can accurately measure the clothing insulation of various garments under different clothing fit and sitting postures. The proposed estimation method is investigated to be effective to measure its clothing insulation significantly in different seasonal cloth...

  1. The Thermal Infrared Sensor on the Landsat Data Continuity Mission

    Science.gov (United States)

    Reuter, Dennis; Richardson, Cathy; Irons, James; Allen, Rick; Anderson, Martha; Budinoff, Jason; Casto, Gordon; Coltharp, Craig; Finneran, Paul; Forsbacka, Betsy; hide

    2010-01-01

    The Landsat Data Continuity Mission (LDCM), a joint NASA and USGS mission, is scheduled for launch in December, 2012. The LDCM instrument payload will consist of the Operational Land Imager (OLI), provided by Ball Aerospace and Technology Corporation (BATC} under contract to NASA and the Thermal Infrared Sensor (TIRS), provided by NASA's Goddard Space Flight Center (GSFC). This paper outlines the design of the TIRS instrument and gives an example of its application to monitoring water consumption by measuring evapotranspiration.

  2. Helium Tagging Infrared Photodissociation Spectroscopy of Reactive Ions.

    Science.gov (United States)

    Roithová, Jana; Gray, Andrew; Andris, Erik; Jašík, Juraj; Gerlich, Dieter

    2016-02-16

    The interrogation of reaction intermediates is key for understanding chemical reactions; however their direct observation and study remains a considerable challenge. Mass spectrometry is one of the most sensitive analytical techniques, and its use to study reaction mixtures is now an established practice. However, the information that can be obtained is limited to elemental analysis and possibly to fragmentation behavior, which is often challenging to analyze. In order to extend the available experimental information, different types of spectroscopy in the infrared and visible region have been combined with mass spectrometry. Spectroscopy of mass selected ions usually utilizes the powerful sensitivity of mass spectrometers, and the absorption of photons is not detected as such but rather translated to mass changes. One approach to accomplish such spectroscopy involves loosely binding a tag to an ion that will be removed by absorption of one photon. We have constructed an ion trapping instrument capable of reaching temperatures that are sufficiently low to enable tagging by helium atoms in situ, thus permitting infrared photodissociation spectroscopy (IRPD) to be carried out. While tagging by larger rare gas atoms, such as neon or argon is also possible, these may cause significant structural changes to small and reactive species, making the use of helium highly beneficial. We discuss the "innocence" of helium as a tag in ion spectroscopy using several case studies. It is shown that helium tagging is effectively innocent when used with benzene dications, not interfering with their structure or IRPD spectrum. We have also provided a case study where we can see that despite its minimal size there are systems where He has a huge effect. A strong influence of the He tagging was shown in the IRPD spectra of HCCl(2+) where large spectral shifts were observed. While the presented systems are rather small, they involve the formation of mixtures of isomers. We have therefore

  3. Systems Analysis for Thermal Infrared ` THz Torch' Applications

    Science.gov (United States)

    Hu, Fangjing; Sun, Jingye; Brindley, Helen E.; Liang, Xiaoxin; Lucyszyn, Stepan

    2015-05-01

    The ` THz Torch' concept was recently introduced by the authors for providing secure wireless communications over short distances within the thermal infrared (10-100 THz). Unlike conventional systems, thermal infrared can exploit front-end thermodynamics with engineered blackbody radiation. For the first time, a detailed power link budget analysis is given for this new form of wireless link. The mathematical modeling of a short end-to-end link is provided, which integrates thermodynamics into conventional signal and noise power analysis. As expected from the Friis formula for noise, it is found that the noise contribution from the pyroelectric detector dominates intrinsic noise. From output signal and noise voltage measurements, experimental values for signal-to-noise ratio (SNR) are obtained and compared with calculated predictions. As with conventional communications systems, it is shown for the first time that the measured SNR and measured bit error rate found with this thermodynamics-based system resembles classical empirical models. Our system analysis can serve as an invaluable tool for the development of thermal infrared systems, accurately characterizing each individual channel and, thus, enables the performance of multi-channel ` THz Torch' systems to be optimized.

  4. Applying infrared measurements in a measuring system for determining thermal parameters of thermal insulation materials

    Science.gov (United States)

    Chudzik, S.

    2017-03-01

    The paper presents results of research on an innovative method for determining thermal parameters of thermal insulating materials. The method is based on harmonic thermal excitations. Temperature measurements at selected points of a specimen under test are performed by means of semiconductor infrared sensors. The study also employs a 3D model of thermal diffusion. To obtain a solution of the coefficient inverse problem a method based on an artificial neural network is presented. The heat transfer coefficient on the specimen surface is estimated on the basis of a reference specimen. The validity of the adopted model of heat diffusion and the usefulness of the method proposed are verified experimentally.

  5. [Investigation of fibrous cultural materials by infrared spectroscopy].

    Science.gov (United States)

    Luo, Xi-yun; Du, Yi-ping; Shen, Mei-hua; Zhang, Wen-qing; Zhou, Xin-guang; Fang, Shu-ying; Zhang, Xuan

    2015-01-01

    Cultural fibrous material includes both important categories, i. e. textile and paper, consisting of precious cultural materials in museum, such as costume, painting, and manuscript. In recent years more and more connoisseur and conservator's concerns are, through nondestructive method, the authenticity and the ageing identification of these cultural relics especially made from fragile materials. In this research, we used attenuated total reflection infrared spectroscopy to identify five traditional textile fibers, alongside cotton, linen, wool, mulberry silk and tussah silk, and another five paper fibers alongside straw, wheat straw, long qisong, Chinese alpine rush and mulberry bar, which are commonly used for making Chinese traditional xuan paper. The research result showed that the animal fiber (wool, mulberry silk and tussah silk) and plant fiber (cotton and linen) were easier to be distinguished by comparing the peaks at 3 280 cm-1 belonging to NH stretching vibration and a serious peaks related to amide I to amide III. In the spectrum of wool, the peak at 1 076 cm-1 was assigned to the S-O stretching vibration absorption of cystine in wool structure and can be used to tell wool from silk. The spectrum of mulberry silk and tussah silk seems somewhat difficult to be identified, as well as the spectrum of cotton and linen. Five rural paper fibers all have obvious characteristic peaks at 3 330, 2 900 cm-1 which are related to OH and CH stretching vibration. In the fingerprint wavenumber range of 1 600 - 800 cm, the similar peaks also appeared at 1 370, 1 320 cm-1 and 1 162, 1 050 cm-1, both group peaks respectively are related to CH and CO vibration in the structure of cellulose and hemicellulose in paper fibers. Although there is more similarity of the infrared spectroscopy of these 5 paper fibers, some tiny difference in absorbance also can be found at 3 300 cm-1 and in the fingerprint range at 1 332, 1 203, and 1 050 cm-1 which are related to C-O-C vibration

  6. Thermal characteristics of mountain desert terrain derived from thermal infrared multispectral scanner measurements

    Science.gov (United States)

    Astling, E. G.; Quattrochi, D. A.

    1989-01-01

    The spatial and temporal variability of mountain-desert territory thermal is examined with an airborne thermal infrared multispectral scanner (TIMS). The purpose of the study is to demonstrate that inhomogeneities of the surface temperatures in the area can be adequately large to influence mesoscale circulations and the turbulence characteristics of boundary-layer flow. Ground truth measurements are compared to the TIMS imagery, with focus placed on the thermal infrared sensitivity to wet and dry soils, terrain elevation, and soil type. The results indicate that variations in the thermal features are dependent on soil type and soil moisture, and that the dependence on surface radiative temperatures on terrain elevation is apparent in daytime measurements.

  7. Thermal infrared imaging in psychophysiology: potentialities and limits.

    Science.gov (United States)

    Ioannou, Stephanos; Gallese, Vittorio; Merla, Arcangelo

    2014-10-01

    Functional infrared thermal imaging (fITI) is considered an upcoming, promising methodology in the emotional arena. Driven by sympathetic nerves, observations of affective nature derive from muscular activity subcutaneous blood flow as well as perspiration patterns in specific body parts. A review of 23 experimental procedures that employed fITI for investigations of affective nature is provided, along with the adopted experimental protocol and the thermal changes that took place on selected regions of interest in human and nonhuman subjects. Discussion is provided regarding the selection of an appropriate baseline, the autonomic nature of the thermal print, the experimental setup, methodological issues, limitations, and considerations, as well as future directions. © 2014 The Authors. Psychophysiology published by Wiley Periodicals, Inc. on behalf of Society for Psychophysiological Research.

  8. Human ear detection in the thermal infrared spectrum

    Science.gov (United States)

    Abaza, Ayman; Bourlai, Thirimachos

    2012-06-01

    In this paper the problem of human ear detection in the thermal infrared (IR) spectrum is studied in order to illustrate the advantages and limitations of the most important steps of ear-based biometrics that can operate in day and night time environments. The main contributions of this work are two-fold: First, a dual-band database is assembled that consists of visible and thermal profile face images. The thermal data was collected using a high definition middle-wave infrared (3-5 microns) camera that is capable of acquiring thermal imprints of human skin. Second, a fully automated, thermal imaging based ear detection method is developed for real-time segmentation of human ears in either day or night time environments. The proposed method is based on Haar features forming a cascaded AdaBoost classifier (our modified version of the original Viola-Jones approach1 that was designed to be applied mainly in visible band images). The main advantage of the proposed method, applied on our profile face image data set collected in the thermal-band, is that it is designed to reduce the learning time required by the original Viola-Jones method from several weeks to several hours. Unlike other approaches reported in the literature, which have been tested but not designed to operate in the thermal band, our method yields a high detection accuracy that reaches ~ 91.5%. Further analysis on our data set yielded that: (a) photometric normalization techniques do not directly improve ear detection performance. However, when using a certain photometric normalization technique (CLAHE) on falsely detected images, the detection rate improved by ~ 4%; (b) the high detection accuracy of our method did not degrade when we lowered down the original spatial resolution of thermal ear images. For example, even after using one third of the original spatial resolution (i.e. ~ 20% of the original computational time) of the thermal profile face images, the high ear detection accuracy of our method

  9. Acidic weathering of basalt and basaltic glass: 1. Near-infrared spectra, thermal infrared spectra, and implications for Mars

    Science.gov (United States)

    Horgan, Briony H. N.; Smith, Rebecca J.; Cloutis, Edward A.; Mann, Paul; Christensen, Philip R.

    2017-01-01

    Acid-leached rinds and coatings occur in volcanic environments on Earth and have been identified using orbital spectroscopy on Mars, but their development is poorly understood. We simulated long-term open-system acidic weathering in a laboratory by repeatedly rinsing and submerging crystalline and glassy basalts in pH 1 and pH 3 acidic solutions for 213 days and compared their visible/near-infrared (0.3-2.5 µm) and thermal infrared (5-50 µm) spectral characteristics to their microscopic physical and chemical properties from scanning electron microscopy (SEM). We find that while alteration at moderately low pH ( 3) can produce mineral precipitates from solution, it has very little spectral or physical effect on the underlying parent material. In contrast, alteration at very low pH ( 1) results in clear silica spectral signatures for all crystalline samples while glasses exhibit strong blue concave-up near-infrared slopes. SEM indicates that these spectral differences correspond to different modes of alteration. In glass, alteration occurs only at the surface and produces a silica-enriched leached rind, while in more crystalline samples, alteration penetrates the interior to cause dissolution and replacement by silica. We confirm that glass is more stable than crystalline basalt under long-term acidic leaching, suggesting that glass could be enriched and common in terrains on Mars that have been exposed to acidic weathering. Leached glasses are consistent with both OMEGA and Thermal Emission Spectrometer (TES) spectra of the Martian northern lowlands and may contribute to the high-silica phases detected globally in TES Surface Type 2. Thus, both glass-rich deposits and acidic weathering may have been widespread on Mars.

  10. Lithium-ion battery electrolyte emissions analyzed by coupled thermogravimetric/Fourier-transform infrared spectroscopy

    Science.gov (United States)

    Bertilsson, Simon; Larsson, Fredrik; Furlani, Maurizio; Albinsson, Ingvar; Mellander, Bengt-Erik

    2017-10-01

    In the last few years the use of Li-ion batteries has increased rapidly, powering small as well as large applications, from electronic devices to power storage facilities. The Li-ion battery has, however, several safety issues regarding occasional overheating and subsequent thermal runaway. During such episodes, gas emissions from the electrolyte are of special concern because of their toxicity, flammability and the risk for gas explosion. In this work, the emissions from heated typical electrolyte components as well as from commonly used electrolytes are characterized using FT-IR spectroscopy and FT-IR coupled with thermogravimetric (TG) analysis, when heating up to 650 °C. The study includes the solvents EC, PC, DEC, DMC and EA in various single, binary and ternary mixtures with and without the LiPF6 salt, a commercially available electrolyte, (LP71), containing EC, DEC, DMC and LiPF6 as well as extracted electrolyte from a commercial 6.8 Ah Li-ion cell. Upon thermal heating, emissions of organic compounds and of the toxic decomposition products hydrogen fluoride (HF) and phosphoryl fluoride (POF3) were detected. The electrolyte and its components have also been extensively analyzed by means of infrared spectroscopy for identification purposes.

  11. Fresh Soil Sensing using Visible and Near Infrared Spectroscopy

    Science.gov (United States)

    Maleki, M. R.

    2009-04-01

    Fast, precise and affordable soil analytical techniques are needed for the determination of soil fertility of each zone of a field in site specific land management. The objective of this poster is to demonstrate how nutrients can be estimated from fresh soil using visible (VIS) and near infrared (NIR) spectroscopy method. This could be carried out by summarizing the methodology to develop a calibration model for soil phosphorus with the VIS-NIR spectroscopy method. Obviously, it can be simply extended for other nutrients with the same methodology. A large samples set should be collected from different fields with a wide range of soil type and texture. The samples in this set should be represented a wide range of moisture content and soil nutrient which is desired to be calibrated by the spectroscopy technique. Immediately after sampling, the samples should be kept in a cold room (± 1 °C) until the time of the spectral measurement and the chemical analysis. The samples should be taken from the cold room one hour before the spectral measurement to ensure that the samples were at room temperature and no condensation occurs on the optical instruments. Each soil sample was thoroughly mixed and debris such as plant material and stones were removed. The soil sample was divided into three parts, one part for spectral measurement, another part for chemical analysis and the rest was archived. The part for chemical analysis should be examined for their soil nutrients. A small amount of soil (about 30 g) should be placed in a small plastic petridish (e.g. 7.5 mm depth and 30 mm diameter). The soil in the petridish should be first pressed and then carefully levelled in order to obtain a smooth surface for a maximum light reflectance. Soil samples should be put under the spectrophotometer. Three reflectance spectra should be measured on each soil specimen by rotating the plastic cups over 120°. Having finished measuring, the reflectance data should be put against the chemical

  12. [A simple design of functional near-infrared spectroscopy system].

    Science.gov (United States)

    Xu, Gang; Li, Xiao-li; Liu, Xiao-min

    2015-02-01

    With the development in last twenty years, functional near-infrared spectroscopy (fNIRS) is a non-invasive brain imaging technique which widely used in cognitive neuroscience studies. Based on mechanism of neurovascular coupling, increased functional neural activities in brain induce higher regional cerebral blood flow, which will cause relative concentration change of oxygenated and deoxygenated hemoglobin. In this paper, a single channel continuous wave fNIRS system based on multi-function data acquisition board was proposed. With the benefits of narrow spectral peaks and low divergence, laser diodes provided a better accuracy for measurement with optimal dual-wavelength of 690 and 830 nm. Frequency multiplexing technique was used to distinguish light sources from different emitters, and remove environmental stable interference sources such as ambient light and line power noise as well. LabVIEW was used to design graphical user interface with functionalities including source sequence schedule, auto gain setting, digital inhase and quadrature demodulation, data visualization and storage. The experimental results during holding breath and mental arithmetic task indicated that our system was capable of monitoring regional concentration change of hemoglobin in real time, and detecting activation associated with advanced brain functions.

  13. Characterization and Infrared Emission Spectroscopy of Ball Plasmoid Discharges

    Science.gov (United States)

    Dubowsky, Scott E.; McCall, Benjamin J.

    2015-06-01

    Plasmas at atmospheric pressure serve many purposes, from ionization sources for ambient mass spectrometry (AMS) to plasma-assisted wound healing. Of the many naturally occurring ambient plasmas, ball lightning is one of the least understood; there is currently no solid explanation in the literature for the formation and lifetime of natural ball lightning. With the first measurements of naturally occurring ball lightning being reported last year, we have worked to replicate the natural phenomenon in order to elucidate the physical and chemical processes by which the plasma is sustained at ambient conditions. We are able to generate ball-shaped plasmoids (self-sustaining plasmas) that are analogous to natural ball lightning using a high-voltage, high-current, pulsed DC system. Improvements to the discharge electronics used in our laboratory and characterization of the plasmoids that are generated from this system will be described. Infrared emission spectroscopy of these plasmoids reveals emission from water and hydroxyl radical -- fitting methods for these molecular species in the complex experimental spectra will be presented. Rotational temperatures for the stretching and bending modes of H2O along with that of OH will be presented, and the non-equilibrium nature of the plasmoid will be discussed in this context. Cen, J.; Yuan, P,; Xue, S. Phys. Rev. Lett. 2014, 112, 035001. Dubowsky, S.E.; Friday, D.M.; Peters, K.C.; Zhao, Z.; Perry, R.H.; McCall, B.J. Int. J. Mass Spectrom. 2015, 376, 39-45.

  14. Quantification of atmospheric formaldehyde by infrared absorption spectroscopy

    Science.gov (United States)

    Hoffnagle, John; Fleck, Derek; Rella, Chris; Kim-Hak, David

    2017-04-01

    Formaldehyde is a toxic, carcinogenic compound that can contaminate ambient air as a result of combustion or outgassing of commercial products such as adhesives used to fabricate plywood and to affix indoor carpeting. Like many small molecules, formaldehyde has an infrared absorption spectrum exhibiting bands of ro-vibrational transitions that are well resolved at low pressure and therefore well suited for optical analysis of formaldehyde concentration. We describe progress in applying cavity ring-down spectroscopy of the 2v5 band (the first overtone of the asymmetric C-H stretch, origin at 1770 nm) to the quantitative analysis of formaldehyde concentration in ambient air. Preliminary results suggest that a sensitivity of 1-2 ppb in a measurement interval of a few seconds, and 0.1-0.2 ppb in a few minutes, should be achievable with a compact, robust, and field-deployable instrument. Finally, we note that recent satellites monitoring snapshots of formaldehyde columns give insights into global formaldehyde production, migration and lifetime. The ability to monitor formaldehyde with a small and portable analyzer has the potential to aid in validation of these snapshots and to provide complementary data to show vertical dispersions with high spatial accuracy.

  15. Bundled-Optode Method in Functional Near-Infrared Spectroscopy.

    Directory of Open Access Journals (Sweden)

    Hoang-Dung Nguyen

    Full Text Available In this paper, a theory for detection of the absolute concentrations of oxy-hemoglobin (HbO and deoxy-hemoglobin (HbR from hemodynamic responses using a bundled-optode configuration in functional near-infrared spectroscopy (fNIRS is proposed. The proposed method is then applied to the identification of two fingers (i.e., little and thumb during their flexion and extension. This experiment involves a continuous-wave-type dual-wavelength (760 and 830 nm fNIRS and five healthy male subjects. The active brain locations of two finger movements are identified based on the analysis of the t- and p-values of the averaged HbOs, which are quite distinctive. Our experimental results, furthermore, revealed that the hemodynamic responses of two-finger movements are different: The mean, peak, and time-to-peak of little finger movements are higher than those of thumb movements. It is noteworthy that the developed method can be extended to 3-dimensional fNIRS imaging.

  16. Near-Infrared Spectroscopy for the Evaluation of Anesthetic Depth

    Directory of Open Access Journals (Sweden)

    Gabriela Hernandez-Meza

    2015-01-01

    Full Text Available The standard-of-care guidelines published by the American Society of Anesthesiologists (ASA recommend monitoring of pulse oximetry, blood pressure, heart rate, and end tidal CO2 during the use of anesthesia and sedation. This information can help to identify adverse events that may occur during procedures. However, these parameters are not specific to the effects of anesthetics or sedatives, and therefore they offer little, to no, real time information regarding the effects of those agents and do not give the clinician the lead-time necessary to prevent patient “awareness.” Since no “gold-standard” method is available to continuously, reliably, and effectively monitor the effects of sedatives and anesthetics, such a method is greatly needed. Investigation of the use of functional near-infrared spectroscopy (fNIRS as a method for anesthesia or sedation monitoring and for the assessment of the effects of various anesthetic drugs on cerebral oxygenation has started to be conducted. The objective of this paper is to provide a thorough review of the currently available published scientific studies regarding the use of fNIRS in the fields of anesthesia and sedation monitoring, comment on their findings, and discuss the future work required for the translation of this technology to the clinical setting.

  17. Mental fatigue detection based on the functional near infrared spectroscopy

    Science.gov (United States)

    Zhang, Zhen; Xu, Fenggang; Yang, Hanjun; Jiang, Jin; Cao, Yong; Jiao, Xuejun

    2017-02-01

    Mental fatigue can be induced by long time mental work, mental fatigue caused worse performance and accidents. As a non-invasive technique, functional near-infrared spectroscopy (fNIRS) can measure blood oxygen activity in the cerebral cortex which reflect the cognitive function of brain indirectly. Aiming at investigating whether fNIRS can measure the mental fatigue and study the spatial pattern of hemodynamic response for mental fatigue, we used three sessions of verbal 2-back working memory task for a total of 120 minutes to induce mental fatigue, 15 healthy subjects were recruited and 30 channels including prefrontal cortex (PFC) and motor cortex (MC) were measured by fNIRS. The mean oxyhemoglobin feature for 20s was extracted as well as subjective fatigue level and performance. The results showed significant increase of subjected fatigue level as well as significant decrease performance from session one to three task. With the increased level of fatigue, oxyhemoglobin in PFC increase significantly and the spatial pattern of hemodynamic response in the all 30 channels varied with task duration as well. These findings indicated the potential of fNIRS measured hemodynamic as a mental fatigue indicator.

  18. Portable Infrared Laser Spectroscopy for On-site Mycotoxin Analysis

    Science.gov (United States)

    Sieger, Markus; Kos, Gregor; Sulyok, Michael; Godejohann, Matthias; Krska, Rudolf; Mizaikoff, Boris

    2017-03-01

    Mycotoxins are toxic secondary metabolites of fungi that spoil food, and severely impact human health (e.g., causing cancer). Therefore, the rapid determination of mycotoxin contamination including deoxynivalenol and aflatoxin B1 in food and feed samples is of prime interest for commodity importers and processors. While chromatography-based techniques are well established in laboratory environments, only very few (i.e., mostly immunochemical) techniques exist enabling direct on-site analysis for traders and manufacturers. In this study, we present MYCOSPEC - an innovative approach for spectroscopic mycotoxin contamination analysis at EU regulatory limits for the first time utilizing mid-infrared tunable quantum cascade laser (QCL) spectroscopy. This analysis technique facilitates on-site mycotoxin analysis by combining QCL technology with GaAs/AlGaAs thin-film waveguides. Multivariate data mining strategies (i.e., principal component analysis) enabled the classification of deoxynivalenol-contaminated maize and wheat samples, and of aflatoxin B1 affected peanuts at EU regulatory limits of 1250 μg kg-1 and 8 μg kg-1, respectively.

  19. Application of functional near-infrared spectroscopy in psychiatry.

    Science.gov (United States)

    Ehlis, Ann-Christine; Schneider, Sabrina; Dresler, Thomas; Fallgatter, Andreas J

    2014-01-15

    Two decades ago, the introduction of functional near-infrared spectroscopy (fNIRS) into the field of neuroscience created new opportunities for investigating neural processes within the human cerebral cortex. Since then, fNIRS has been increasingly used to conduct functional activation studies in different neuropsychiatric disorders, most prominently schizophrenic illnesses, affective disorders and developmental syndromes, such as attention-deficit/hyperactivity disorder as well as normal and pathological aging. This review article provides a comprehensive overview of state of the art fNIRS research in psychiatry covering a wide range of applications, including studies on the phenomenological characterization of psychiatric disorders, descriptions of life-time developmental aspects, treatment effects, and genetic influences on neuroimaging data. Finally, methodological shortcomings as well as current research perspectives and promising future applications of fNIRS in psychiatry are discussed. We conclude that fNIRS is a valid addition to the range of neuroscientific methods available to assess neural mechanisms underlying neuropsychiatric disorders. Future research should particularly focus on expanding the presently used activation paradigms and cortical regions of interest, while additionally fostering technical and methodological advances particularly concerning the identification and removal of extracranial influences on fNIRS data as well as systematic artifact correction. Eventually, fNIRS might be a useful tool in practical psychiatric settings involving both diagnostics and the complementary treatment of psychological disorders using, for example, neurofeedback applications. Copyright © 2013 Elsevier Inc. All rights reserved.

  20. The application of near infrared spectroscopy in nutritional intervention studies

    Directory of Open Access Journals (Sweden)

    Philippa A Jackson

    2013-08-01

    Full Text Available Functional near infrared spectroscopy (NIRS is a non-invasive optical imaging technique used to monitor cerebral blood flow (CBF and by proxy neuronal activation. The use of NIRS in nutritional intervention studies is a relatively novel application of this technique, with only a small, but growing, number of trials published to date. These trials—in which the effects on CBF following administration of dietary components such as caffeine, polyphenols and omega-3 polyunsaturated fatty acids are assessed—have successfully demonstrated NIRS as a sensitive measure of change in haemodynamic response during cognitive tasks in both acute and chronic treatment intervention paradigms. The existent research in this area has been limited by the constraints of the technique itself however advancements in the measurement technology, paired with studies endeavouring increased sophistication in number and locations of channels over the head should render the use of NIRS in nutritional interventions particularly valuable in advancing our understanding of the effects of nutrients and dietary components on the brain.

  1. Synthesis, spectroscopy, thermal studies and supramolecular ...

    Indian Academy of Sciences (India)

    The chains thus formed are further cross-linked with the aid of H-donor bonds from both the free as well as the coordinated Im. Both 1 and 2 exhibit - stacking interactions. Complex 1 is thermally more stable as compared to 2, and both complexes can be dehydrated to the corresponding anhydrous complexes by heating ...

  2. Silicon-chip-based mid-infrared dual-comb spectroscopy

    CERN Document Server

    Yu, Mengjie; Griffith, Austin G; Picqué, Nathalie; Lipson, Michal; Gaeta, Alexander L

    2016-01-01

    On-chip spectroscopy that could realize real-time fingerprinting with label-free and high-throughput detection of trace molecules is one of the 'holy grails" of sensing. Such miniaturized spectrometers would greatly enable applications in chemistry, bio-medicine, material science or space instrumentation, such as hyperspectral microscopy of live cells or pharmaceutical quality control. Dual-comb spectroscopy (DCS), a recent technique of Fourier transform spectroscopy without moving parts, is particularly promising since it measures high-precision spectra in the gas phase using only a single detector. Here, we present a microresonator-based platform designed for mid-infrared (mid-IR) DCS. A single continuous-wave (CW) low-power pump source generates two mutually coherent mode-locked frequency combs spanning from 2.6 $\\mu$m to 4.1 $\\mu$m in two silicon micro-resonators. Thermal control and free-carrier injection control modelocking of each comb and tune the dual-comb parameters. The large line spacing of the co...

  3. Enhanced visible and near-infrared capabilities of the JET mirror-linked divertor spectroscopy system.

    Science.gov (United States)

    Lomanowski, B A; Meigs, A G; Conway, N J; Zastrow, K-D; Sharples, R M; Heesterman, P; Kinna, D

    2014-11-01

    The mirror-linked divertor spectroscopy diagnostic on JET has been upgraded with a new visible and near-infrared grating and filtered spectroscopy system. New capabilities include extended near-infrared coverage up to 1875 nm, capturing the hydrogen Paschen series, as well as a 2 kHz frame rate filtered imaging camera system for fast measurements of impurity (Be II) and deuterium Dα, Dβ, Dγ line emission in the outer divertor. The expanded system provides unique capabilities for studying spatially resolved divertor plasma dynamics at near-ELM resolved timescales as well as a test bed for feasibility assessment of near-infrared spectroscopy.

  4. Enhanced visible and near-infrared capabilities of the JET mirror-linked divertor spectroscopy system

    Energy Technology Data Exchange (ETDEWEB)

    Lomanowski, B. A., E-mail: b.a.lomanowski@durham.ac.uk; Sharples, R. M. [Centre for Advanced Instrumentation, Department of Physics, Durham University, Durham DH1 3LE (United Kingdom); Meigs, A. G.; Conway, N. J.; Zastrow, K.-D.; Heesterman, P.; Kinna, D. [EURATOM/CCFE Fusion Association, Culham Science Center, Abingdon OX14 3DB (United Kingdom); Collaboration: JET-EFDA Team

    2014-11-15

    The mirror-linked divertor spectroscopy diagnostic on JET has been upgraded with a new visible and near-infrared grating and filtered spectroscopy system. New capabilities include extended near-infrared coverage up to 1875 nm, capturing the hydrogen Paschen series, as well as a 2 kHz frame rate filtered imaging camera system for fast measurements of impurity (Be II) and deuterium Dα, Dβ, Dγ line emission in the outer divertor. The expanded system provides unique capabilities for studying spatially resolved divertor plasma dynamics at near-ELM resolved timescales as well as a test bed for feasibility assessment of near-infrared spectroscopy.

  5. Electrochemically induced far-infrared difference spectroscopy on metalloproteins using advanced synchrotron technology.

    Science.gov (United States)

    Vita, Nicolas; Brubach, Jean-Blaise; Hienerwadel, Rainer; Bremond, Nicolas; Berthomieu, Dorothée; Roy, Pascale; Berthomieu, Catherine

    2013-03-05

    New information on a protein's structure, intra- and intermolecular hydrogen bonds, or metal-ligand bond properties can be unraveled in the far-infrared (far-IR)-terahertz-domain (600-3 cm(-1) or 18-0.1 THz). In this study, we compare the performances of thermal sources with synchrotron far-IR to record reaction-induced Fourier transform infrared (FT-IR) difference signals with proteins in solution. Using the model protein Cu-azurin placed in a short path length electrochemical cell adapted for transmission spectroscopy in vacuum-purged optics, we show that minute spectral shifts induced by metal isotope labeling or temperature changes are detected using the far-IR beamline AILES of the synchrotron SOLEIL. On one hand, these data allow us to identify modes involving Cu-ligand vibrations and pave the way for the analysis of metal sites or metal redox states of proteins not amenable to resonance Raman spectroscopy. On another hand, small band shifts or changes in band intensity upon temperature modifications show that far-IR difference spectroscopy allows one to extract from a complex background hydrogen-bonding signatures directly relevant to the protein function. For Cu-azurin, a temperature-sensitive IR mode involving Cu(II)-His vibrations points to the role of a hydrogen bond between a Cu histidine ligand and the water solvent in tuning the Cu(II)-histidine bond properties. Furthermore, these experimental data support the possible role of a His117-water interaction in electron-transfer activity of Cu-azurin proposed by theoretical studies.

  6. Application of Raman Spectroscopy and Infrared Spectroscopy in the Identification of Breast Cancer.

    Science.gov (United States)

    Depciuch, Joanna; Kaznowska, Ewa; Zawlik, Izabela; Wojnarowska, Renata; Cholewa, Marian; Heraud, Philip; Cebulski, Józef

    2016-02-01

    Raman spectroscopy and infrared (IR) spectroscopy are both techniques that allow for the investigation of vibrating chemical particles. These techniques provide information not only about chemical particles through the identification of functional groups and spectral analysis of so-called "fingerprints", these methods allow for the qualitative and quantitative analyses of chemical substances in the sample. Both of these spectral techniques are frequently being used in biology and medicine in diagnosing illnesses and monitoring methods of therapy. The type of breast cancer found in woman is often a malignant tumor, causing 1.38 million new cases of breast cancer and 458 000 deaths in the world in 2013. The most important risk factors for breast cancer development are: sex, age, family history, specific benign breast conditions in the breast, ionizing radiation, and lifestyle. The main purpose of breast cancer screening tests is to establish early diagnostics and to apply proper treatment. Diagnoses of breast cancer are based on: (1) physical techniques (e.g., ultrasonography, mammography, elastography, magnetic resonance, positron emission tomography [PET]); (2) histopathological techniques; (3) biological techniques; and (4) optical techniques (e.g., photo acoustic imaging, fluorescence tomography). However, none of these techniques provides unique or especially revealing answers. The aim of our study is comparative spectroscopic measurements on patients with the following: normal non-cancerous breast tissue; breast cancer tissues before chemotherapy; breast cancer tissues after chemotherapy; and normal breast tissues received around the cancerous breast region. Spectra collected from breast cancer patients shows changes in amounts of carotenoids and fats. We also observed changes in carbohydrate and protein levels (e.g., lack of amino acids, changes in the concentration of amino acids, structural changes) in comparison with normal breast tissues. This fact

  7. Near infrared emission spectroscopy induced by ultrasonic irradiation.

    Science.gov (United States)

    Borges, Sivanildo Silva; Korn, Mauro; Gonzaga, Fabiano Barbieri; Pasquini, Celio

    2006-07-01

    Near infrared emission caused by ultrasonic excitation is demonstrated for the first time in this work. The instrument is constituted of an acousto-optical tunable filter-based spectrometer, an ultrasonic processor connected to a titanium alloy ultrasonic probe and a cylindrical borosilicate flask containing the sample to be excited. The radiation emitted by the sample is collected by a concave mirror and sent to the spectrometer. The effects of the position of the probe extremity in relation to a lateral entrance of the borosilicate flask and of the ultrasonic power on the emission signal were studied. The best results were obtained by positioning the probe extremity up to 2mm from the reflexive body (lateral entrance) using 30% of the full ultrasonic incident power and acquiring spectra after 5 min of sonication. The NIR emission spectra resulting from the ultrasonic excitation were in agreement with that obtained by thermal excitation. The proposed technique was utilized to study different poly(dimethylsiloxane) samples having different viscosities.

  8. Infrared thermal imaging for automated detection of diabetic foot complications.

    Science.gov (United States)

    van Netten, Jaap J; van Baal, Jeff G; Liu, Chanjuan; van der Heijden, Ferdi; Bus, Sicco A

    2013-09-01

    Although thermal imaging can be a valuable technology in the prevention and management of diabetic foot disease, it is not yet widely used in clinical practice. Technological advancement in infrared imaging increases its application range. The aim was to explore the first steps in the applicability of high-resolution infrared thermal imaging for noninvasive automated detection of signs of diabetic foot disease. The plantar foot surfaces of 15 diabetes patients were imaged with an infrared camera (resolution, 1.2 mm/pixel): 5 patients had no visible signs of foot complications, 5 patients had local complications (e.g., abundant callus or neuropathic ulcer), and 5 patients had diffuse complications (e.g., Charcot foot, infected ulcer, or critical ischemia). Foot temperature was calculated as mean temperature across pixels for the whole foot and for specified regions of interest (ROIs). No differences in mean temperature >1.5 °C between the ipsilateral and the contralateral foot were found in patients without complications. In patients with local complications, mean temperatures of the ipsilateral and the contralateral foot were similar, but temperature at the ROI was >2 °C higher compared with the corresponding region in the contralateral foot and to the mean of the whole ipsilateral foot. In patients with diffuse complications, mean temperature differences of >3 °C between ipsilateral and contralateral foot were found. With an algorithm based on parameters that can be captured and analyzed with a high-resolution infrared camera and a computer, it is possible to detect signs of diabetic foot disease and to discriminate between no, local, or diffuse diabetic foot complications. As such, an intelligent telemedicine monitoring system for noninvasive automated detection of signs of diabetic foot disease is one step closer. Future studies are essential to confirm and extend these promising early findings. © 2013 Diabetes Technology Society.

  9. Sub-Doppler tunable far-infrared spectroscopy

    Science.gov (United States)

    Inguscio, M.; Zink, L. R.; Evenson, K. M.; Jennings, D. A.

    1987-01-01

    The first experimental observations of sub-Doppler linewidths in a cell made using tunable far-infrared radiation are reported. A double-resonance scheme has been used, combining CO2-laser infrared radiation with tunable far-infrared radiation to observe a sub-Doppler line shape in an excited vibrational state of CH3OH.

  10. Infrared reflection-absorption spectroscopy and polarization-modulated infrared reflection-absorption spectroscopy studies of the aequorin langmuir monolayer.

    Science.gov (United States)

    Wang, Chengshan; Micic, Miodrag; Ensor, Mark; Daunert, Sylvia; Leblanc, Roger M

    2008-04-03

    The Langmuir monolayer of aequorin and apoaequorin was studied by infrared reflection-absorption spectroscopy (IRRAS) and polarization-modulated IRRAS techniques. The alpha-helices in the aequorin Langmuir monolayer were parallel to the air-water interface at zero surface pressure. When the surface pressure increased to 15 mN.(m-1), the alpha-helices became tilted and the turns became parallel to the air-water interface. As for apoaequorin, the alpha-helices were also parallel to the air-water interface at 0 mN.m(-1). However, the alpha-helix became tilted and the turns became parallel to the air-water interface quickly at 5 mN.m(-1). With further compression of the apoaequorin Langmuir monolayer, the orientation remained the same. The different behaviors of aequorin and apoaequorin at the air-water interface were explained by the fact that aequorin formed dimers at the air-water interface but apoaequorin was a monomer. It is more difficult for a dimer to be tilted by the compression of the Langmuir monolayer.

  11. Enhancement of multispectral thermal infrared images - Decorrelation contrast stretching

    Science.gov (United States)

    Gillespie, Alan R.

    1992-01-01

    Decorrelation contrast stretching is an effective method for displaying information from multispectral thermal infrared (TIR) images. The technique involves transformation of the data to principle components ('decorrelation'), independent contrast 'stretching' of data from the new 'decorrelated' image bands, and retransformation of the stretched data back to the approximate original axes, based on the inverse of the principle component rotation. The enhancement is robust in that colors of the same scene components are similar in enhanced images of similar scenes, or the same scene imaged at different times. Decorrelation contrast stretching is reviewed in the context of other enhancements applied to TIR images.

  12. Thermal infrared exploration in the Carlin trend, northern Nevada

    Science.gov (United States)

    Watson, K.; Kruse, F.A.; Hummer-Miller, S.

    1990-01-01

    Experimental Thermal Infrared Multispectral Scanner (TIMS) aircraft data have been acquired for the Rodeo Creek NE 7 1/2 minute quadrangle, Eureka County, northern Nevada, covering the Carlin gold mine. A simple model has been developed to extract spectral emissivities for mapping surface lithology and alteration based on the physical properties of geologic materials. Emissivity-ratio images were prepared that allow generalized lithologic discrimination, identification of areas with high silica content, and the first reported detection of the carbonate secondary rest-strahlen feature. -from Authors

  13. Non-destructive Measurement of Total Carotenoid Content in Processed Tomato Products: Infrared Lock-In Thermography, Near-Infrared Spectroscopy/Chemometrics, and Condensed Phase Laser-Based Photoacoustics—Pilot Study

    Science.gov (United States)

    Bicanic, D.; Streza, M.; Dóka, O.; Valinger, D.; Luterotti, S.; Ajtony, Zs.; Kurtanjek, Z.; Dadarlat, D.

    2015-09-01

    Carotenes found in a diversity of fruits and vegetables are among important natural antioxidants. In a study described in this paper, the total carotenoid content (TCC) in seven different products derived from thermally processed tomatoes was determined using laser photoacoustic spectroscopy (LPAS), infrared lock-in thermography (IRLIT), and near-infrared spectroscopy (NIRS) combined with chemometrics. Results were verified versus data obtained by traditional VIS spectrophotometry (SP) that served as a reference technique. Unlike SP, the IRLIT, NIRS, and LPAS require a minimum of sample preparation which enables practically direct quantification of the TCC.

  14. Terrestrial Applications of the Thermal Infrared Sensor, TIRS

    Science.gov (United States)

    Smith, Ramsey L.; Thome, Kurtis; Richardson, Cathleen; Irons, James; Reuter, Dennis

    2009-01-01

    Landsat satellites have acquired single-band thermal images since 1978. The next satellile in the heritage, Landsat Data Continuity Mission (LDCM), is scheduled to launch in December 2012. LDCM will contain the Operational Land Imager (OLI) and the Thermal Infrared Sensor (TIRS), where TIRS operates in concert with, but independently of OLI. This paper will provide an overview of the remote sensing instrument TIRS. The T1RS instrument was designed at National Aeronautics and Space Administration's (NASA) Goddard Space Flight Center (GSFC) where it will be fabricated and calibrated as well. Protecting the integrity of the Scientific Data that will be collected from TIRS played a strong role in definition of the calibration test equipment and procedures used for the optical, radiometric, and spatial calibration. The data that will be produced from LCDM will continue to be used world wide for environment monitoring and resource management.

  15. Infrared photodissociation spectroscopy of protonated acetylene and its clusters.

    Science.gov (United States)

    Douberly, G E; Ricks, A M; Ticknor, B W; McKee, W C; Schleyer, P v R; Duncan, M A

    2008-03-06

    The protonated acetylene cation, C2H3+, (also known as the vinyl cation) and the proton-bound acetylene dimer cation (C4H5+) are produced by a pulsed supersonic nozzle/pulsed electrical discharge cluster source. The parent ions are also generated with weakly attached argon "tag" atoms, e.g., C2H3+Ar and C4H5+Ar. These ions are mass selected in a specially designed reflectron time-of-flight mass spectrometer and studied with infrared laser photodissociation spectroscopy in the 800-3600 cm-1 region. Vibrational resonances are detected for both ions in the C-H stretching region. C2H3+ has a strong vibrational resonance near 2200 cm-1 assigned to the bridged proton stretch of the nonclassical ion, while C4H5+ has no such free-proton vibration. Instead, C4H5+ has resonances near 1300 cm-1, consistent with a symmetrically shared proton in a di-bridged structure. Although the shared proton structure is not the lowest energy isomer of C4H5+, this species is apparently stabilized under the supersonic beam conditions. Larger clusters containing additional acetylene units are also investigated via the elimination of acetylene. These species have new IR bands indicating that rearrangement reactions have taken place to produce core C4H5+ ions with the methyl cyclopropane cation structure and/or the protonated cyclobutadiene isomer. Ab initio (MP2) calculations provide structures and predicted spectra consistent with all of these experiments.

  16. Methanogenic activity tests by Infrared Tunable Diode Laser Absorption Spectroscopy.

    Science.gov (United States)

    Martinez-Cruz, Karla; Sepulveda-Jauregui, Armando; Escobar-Orozco, Nayeli; Thalasso, Frederic

    2012-10-01

    Methanogenic activity (MA) tests are commonly carried out to estimate the capability of anaerobic biomass to treat effluents, to evaluate anaerobic activity in bioreactors or natural ecosystems, or to quantify inhibitory effects on methanogenic activity. These activity tests are usually based on the measurement of the volume of biogas produced by volumetric, pressure increase or gas chromatography (GC) methods. In this study, we present an alternative method for non-invasive measurement of methane produced during activity tests in closed vials, based on Infrared Tunable Diode Laser Absorption Spectroscopy (MA-TDLAS). This new method was tested during model acetoclastic and hydrogenotrophic methanogenic activity tests and was compared to a more traditional method based on gas chromatography. From the results obtained, the CH(4) detection limit of the method was estimated to 60 ppm and the minimum measurable methane production rate was estimated to 1.09(.)10(-3) mg l(-1) h(-1), which is below CH(4) production rate usually reported in both anaerobic reactors and natural ecosystems. Additionally to sensitivity, the method has several potential interests compared to more traditional methods among which short measurements time allowing the measurement of a large number of MA test vials, non-invasive measurements avoiding leakage or external interferences and similar cost to GC based methods. It is concluded that MA-TDLAS is a promising method that could be of interest not only in the field of anaerobic digestion but also, in the field of environmental ecology where CH(4) production rates are usually very low. Copyright © 2012 Elsevier B.V. All rights reserved.

  17. [Study on Identification of Three Medicinal Plant Leaves from Elaeagnus Genus by Infrared Spectroscopy].

    Science.gov (United States)

    Zhang, Fei; Li, Lu-yang; Ding, Qi; Hu, Ji-qing; Long, Wei-fang; Wan, Ding-rong

    2015-01-01

    To study and identify the three species of dry medicinal plant leaves trom Elaeagnus genus (E. pungens, E. lanceolata and E. henryi) by Infrared Spectroscopy(IR). Fourier transform infrared spectroscopy and second derivative infrared spectroscopy were used to study and compare the characteristics of leaves of three Elaeagnus medicinal plants. The IR spectra and second derivative infrared spectra of the three Elaeagnus plants leaves were similar on the whole, the intensity or ratio of intensity of some absorption peaks still had certain distinctions, and the differences of the second derivative infrared spectra were more obvious. There were only slight differences between large and small leaf type of samples of Elaeagnus lanceolata; the differences of the plant leaves of one species collected in different harvest periods were far smaller than those of others belonging to the same genus. IR can be relatively reliably used for identification of the three Elaeagnus leaves.

  18. Near infrared spectroscopy for frontal lobe oxygenation during non-vascular abdominal surgery

    DEFF Research Database (Denmark)

    Sørensen, Henrik; Grocott, Hilary P; Secher, Niels H

    2016-01-01

    PURPOSE: Cerebral deoxygenation, as determined by near infrared spectroscopy (NIRS), seems to predict postoperative complications following cardiac surgery. We identify the type of non-vascular abdominal surgery associated with cerebral deoxygenation and/or hyperoxygenation, how such deviations a...

  19. Cutaneous vasoconstriction affects near-infrared spectroscopy determined cerebral oxygen saturation during administration of norepinephrine

    DEFF Research Database (Denmark)

    Sørensen, Niels Henrik Breiner; Secher, Niels H; Siebenmann, Christoph

    2012-01-01

    Perioperative optimization of spatially resolved near-infrared spectroscopy determined cerebral frontal lobe oxygenation (scO2) may reduce postoperative morbidity. Norepinephrine is routinely administered to maintain cerebral perfusion pressure and, thereby, cerebral blood flow, but norepinephrine...

  20. Infrared Spectroscopy for Studying Structure and Aging Effects in Rhamnolipid Biosurfactants

    National Research Council Canada - National Science Library

    Johannes Kiefer; Mohd Nazren Radzuan; James Winterburn

    2017-01-01

    .... In this study, we demonstrate that attenuated total reflection infrared (ATR-IR) spectroscopy is a useful tool for the analysis of biosurfactants, using rhamnolipids produced by fermentation as an example...

  1. Investigation of the phase separation of PNIPAM using infrared spectroscopy together with multivariate data analysis

    DEFF Research Database (Denmark)

    Munk, Tommy; Baldursdottir, Stefania G.; Hietala, S.

    2013-01-01

    to gain an oversight of small but systematic spectral differences anywhere within the spectra, providing further insight into structural changes and associated transformation mechanisms. In this study, the novel analytical approach of infrared spectroscopy combined with principal component analysis...

  2. Chemometrical Contributions Extending the Application of Near-Infrared and Raman Spectroscopy

    NARCIS (Netherlands)

    Groot, P.J. de

    2004-01-01

    Raman and near-infrared (NIR) reflectance spectroscopy are increasingly being applied in industry and laboratories. Examples are: investigation of interactions between DNA molecules, characterizing polymer properties, and separating demolition waste. These applications demand robust systems and

  3. ARTIFICIAL NEURAL-NETWORK PREDICTIONS OF URINARY CALCULUS COMPOSITIONS ANALYZED WITH INFRARED-SPECTROSCOPY

    NARCIS (Netherlands)

    VOLMER, M; WOLTHERS, BG; METTING, HJ; DEHAAN, THY; COENEGRACHT, PMJ; VANDERSLIK, W

    Infrared (IR) spectroscopy is used to analyze urinary calculus (renal stone) constituents. However, interpretation of IR spectra for quantifying urinary calculus constituents in mixtures is difficult, requiring expert knowledge by trained technicians. In our laboratory IR spectra of unknown calculi

  4. A study of infrared spectroscopy de-noising based on LMS adaptive filter

    Science.gov (United States)

    Mo, Jia-qing; Lv, Xiao-yi; Yu, Xiao

    2015-12-01

    Infrared spectroscopy has been widely used, but which often contains a lot of noise, so the spectral characteristic of the sample is seriously affected. Therefore the de-noising is very important in the spectrum analysis and processing. In the study of infrared spectroscopy, the least mean square (LMS) adaptive filter was applied in the field firstly. LMS adaptive filter algorithm can reserve the detail and envelope of the effective signal when the method was applied to infrared spectroscopy of breast cancer which signal-to-noise ratio (SNR) is lower than 10 dB, contrast and analysis the result with result of wavelet transform and ensemble empirical mode decomposition (EEMD). The three evaluation standards (SNR, root mean square error (RMSE) and the correlation coefficient (ρ)) fully proved de-noising advantages of LMS adaptive filter in infrared spectroscopy of breast cancer.

  5. Structural changes of wood during hydro-thermal and thermal treatments evaluated through NIR spectroscopy and principal component analysis

    Science.gov (United States)

    Popescu, Carmen-Mihaela; Navi, Parviz; Placencia Peña, María Inés; Popescu, Maria-Cristina

    2018-02-01

    Spruce wood samples were subjected to different conditions of thermal and hydro-thermal treatment by varying the temperature, relative humidity and period of exposure. The obtained treated samples were evaluated using near infrared spectroscopy (NIR), principal component analysis (PCA) and hierarchical cluster analysis (HCA) in order to evidence the structural changes which may occur during the applied treatment conditions. Following this, modification in all wood components were observed, modifications which were dependent on the temperature, amount of relative humidity and also the treatment time. Therefore, higher variations were evidenced for samples treated at higher temperatures and for longer periods. At the same time, the increase in the amount of water vapours in the medium induced a reduced rate of side chains and condensation reactions occurring in the wood structure. Further, by PCA and HCA was possible to discriminate the modifications in the wood samples according to treatment time and amount of relative humidity.

  6. High-field EPR spectroscopy of thermal donors in silicon

    DEFF Research Database (Denmark)

    Dirksen, R.; Rasmussen, F.B.; Gregorkiewicz, T.

    1997-01-01

    Thermal donors generated in p-type boron-doped Czochralski-grown silicon by a 450 degrees C heat treatment have been studied by high-field magnetic resonance spectroscopy. In the experiments conducted at a microwave frequency of 140 GHz and in a magnetic field of approximately 5 T four individual...

  7. Nonlinear optics in germanium mid-infrared fiber material: Detuning oscillations in femtosecond mid-infrared spectroscopy

    Science.gov (United States)

    Ordu, M.; Guo, J.; Ng Pack, G.; Shah, P.; Ramachandran, S.; Hong, M. K.; Ziegler, L. D.; Basu, S. N.; Erramilli, S.

    2017-09-01

    Germanium optical fibers hold great promise in extending semiconductor photonics into the fundamentally important mid-infrared region of the electromagnetic spectrum. The demonstration of nonlinear response in fabricated Ge fiber samples is a key step in the development of mid-infrared fiber materials. Here we report the observation of detuning oscillations in a germanium fiber in the mid-infrared region using femtosecond dispersed pump-probe spectroscopy. Detuning oscillations are observed in the frequency-resolved response when mid-infrared pump and probe pulses are overlapped in a fiber segment. The oscillations arise from the nonlinear frequency resolved nonlinear (χ(3)) response in the germanium semiconductor. Our work represents the first observation of coherent oscillations in the emerging field of germanium mid-infrared fiber optics.

  8. Nonlinear optics in germanium mid-infrared fiber material: Detuning oscillations in femtosecond mid-infrared spectroscopy

    Directory of Open Access Journals (Sweden)

    M. Ordu

    2017-09-01

    Full Text Available Germanium optical fibers hold great promise in extending semiconductor photonics into the fundamentally important mid-infrared region of the electromagnetic spectrum. The demonstration of nonlinear response in fabricated Ge fiber samples is a key step in the development of mid-infrared fiber materials. Here we report the observation of detuning oscillations in a germanium fiber in the mid-infrared region using femtosecond dispersed pump-probe spectroscopy. Detuning oscillations are observed in the frequency-resolved response when mid-infrared pump and probe pulses are overlapped in a fiber segment. The oscillations arise from the nonlinear frequency resolved nonlinear (χ(3 response in the germanium semiconductor. Our work represents the first observation of coherent oscillations in the emerging field of germanium mid-infrared fiber optics.

  9. Thermal Infrared Remote Sensing of the Yellowstone Geothermal System

    Science.gov (United States)

    Vaughan, R. G.; Keszthelyi, L. P.; Heasler, H.; Jaworowski, C.; Lowenstern, J. B.; Schneider, D. J.

    2009-12-01

    The Yellowstone National Park (YNP) geothermal system is one of the largest in the world, with thousands of individual thermal features ranging in size from a few centimeters to tens of meters across, (e.g., fumaroles, geysers, mud pots and hot spring pools). Together, large concentrations of these thermal features make up dozens of distinct thermal areas, characterized by sparse vegetation, hydrothermally altered rocks, and usually either sinter, travertine, or acid sulfate alteration. The temperature of these thermal features generally ranges from ~30 to ~93 oC, which is the boiling temperature of water at the elevation of Yellowstone. In-situ temperature measurements of various thermal features are sparse in both space and time, but they show a dynamic time-temperature relationship. For example, as geysers erupt and send pulses of warm water down slope, the warm water cools rapidly and is then followed by another pulse of warm water, on time scales of minutes. The total heat flux from the Park’s thermal features has been indirectly estimated from chemical analysis of Cl- flux in water flowing from Yellowstone’s rivers. We are working to provide a more direct measurement, as well as estimates of time variability, of the total heat flux using satellite multispectral thermal infrared (TIR) remote sensing data. Over the last 10 years, NASA’s orbiting ASTER and MODIS instruments have acquired hundreds and thousands of multispectral TIR images, respectively, over the YNP area. Compared with some volcanoes, Yellowstone is a relatively low-temperature geothermal system, with low thermal contrast to the non-geothermal surrounding areas; therefore we are refining existing techniques to extract surface temperature and thermal flux information. This task is complicated by issues such as, during the day, solar heated surfaces may be warmer than nearby geothermal features; and there is some topographic (elevation) influence on surface temperatures, even at night. Still

  10. Enhanced visible and near-infrared capabilities of the JET mirror-linked divertor spectroscopy system.

    OpenAIRE

    Lomanowski, B.A.; Meigs, A.G.; Conway, N. J.; Zastrow, K.-D.; Sharples, R. M.; Heesterman, P.; Kinna, D.; JET EFDA Contributors,

    2014-01-01

    The mirror-linked divertor spectroscopy diagnostic on JET has been upgraded with a new visible and near-infrared grating and filtered spectroscopy system. New capabilities include extended near-infrared coverage up to 1875 nm, capturing the hydrogen Paschen series, as well as a 2 kHz frame rate filtered imaging camera system for fast measurements of impurity (Be II) and deuterium Dα, Dβ, Dγ line emission in the outer divertor. The expanded system provides unique capabilities for studying spat...

  11. Landsat 8 Thermal Infrared Sensor Geometric Characterization and Calibration

    Directory of Open Access Journals (Sweden)

    James Storey

    2014-11-01

    Full Text Available The Landsat 8 spacecraft was launched on 11 February 2013 carrying two imaging payloads: the Operational Land Imager (OLI and the Thermal Infrared Sensor (TIRS. The TIRS instrument employs a refractive telescope design that is opaque to visible wavelengths making prelaunch geometric characterization challenging. TIRS geometric calibration thus relied heavily on on-orbit measurements. Since the two Landsat 8 payloads are complementary and generate combined Level 1 data products, the TIRS geometric performance requirements emphasize the co-alignment of the OLI and TIRS instrument fields of view and the registration of the OLI reflective bands to the TIRS long-wave infrared emissive bands. The TIRS on-orbit calibration procedures include measuring the TIRS-to-OLI alignment, refining the alignment of the three TIRS sensor chips, and ensuring the alignment of the two TIRS spectral bands. The two key TIRS performance metrics are the OLI reflective to TIRS emissive band registration accuracy, and the registration accuracy between the TIRS thermal bands. The on-orbit calibration campaign conducted during the commissioning period provided an accurate TIRS geometric model that enabled TIRS Level 1 data to meet all geometric accuracy requirements. Seasonal variations in TIRS-to-OLI alignment have led to several small calibration parameter adjustments since commissioning.

  12. Multispectral, thermal infrared satellite data for geologic applications

    Science.gov (United States)

    Blodget, H. W.; Andre, C. G.; Marcell, R.; Minor, T. B.

    1985-01-01

    The value of multispectral thermal infrared satellite data for geologic mapping was assessed, applying the principal component and canonical analysis techniques to the images of the central part of the Arabian Peninsula (a 200 x 300 km area). Low resolution thermal infrared (TIR) data from the Nimbus 5 Surface Composition Mapping Radiometer (SCMR) and the NOAA-7 Advanced Very High Resolution Radiometer (AVHRR) were used. Color images included an 8.8 micrometer (SCMR) and 3.7 and 10.8 micrometer (AVHRR-night) data, ratioed AVHRR day/night TIR data, ratioed AVHRR reflected radiation data, and transformed 8- and 10-band TIR plus reflected radiation data. The results clearly demonstrated the potential geologic value of multispectral TIR data. Igneous and metamorphic units could be separated as a class (although not from each other except for young calc-alkaline granites). Some previously unmapped extensions of mapped faults below thick sedimentary units could be delineated. No single enhancement technique displayed all the potential information, implying that they should be used together.

  13. Secure thermal infrared communications using engineered blackbody radiation.

    Science.gov (United States)

    Liang, Xiaoxin; Hu, Fangjing; Yan, Yuepeng; Lucyszyn, Stepan

    2014-06-10

    The thermal (emitted) infrared frequency bands, from 20-40 THz and 60-100 THz, are best known for applications in thermography. This underused and unregulated part of the spectral range offers opportunities for the development of secure communications. The 'THz Torch' concept was recently presented by the authors. This technology fundamentally exploits engineered blackbody radiation, by partitioning thermally-generated spectral noise power into pre-defined frequency channels; the energy in each channel is then independently pulsed modulated and multiplexing schemes are introduced to create a robust form of short-range secure communications in the far/mid infrared. To date, octave bandwidth (25-50 THz) single-channel links have been demonstrated with 380 bps speeds. Multi-channel 'THz Torch' frequency division multiplexing (FDM) and frequency-hopping spread-spectrum (FHSS) schemes have been proposed, but only a slow 40 bps FDM scheme has been demonstrated experimentally. Here, we report a much faster 1,280 bps FDM implementation. In addition, an experimental proof-of-concept FHSS scheme is demonstrated for the first time, having a 320 bps data rate. With both 4-channel multiplexing schemes, measured bit error rates (BERs) of < 10(-6) are achieved over a distance of 2.5 cm. Our approach represents a new paradigm in the way niche secure communications can be established over short links.

  14. Landsat 8 thermal infrared sensor geometric characterization and calibration

    Science.gov (United States)

    Storey, James C.; Choate, Michael J.; Moe, Donald

    2014-01-01

    The Landsat 8 spacecraft was launched on 11 February 2013 carrying two imaging payloads: the Operational Land Imager (OLI) and the Thermal Infrared Sensor (TIRS). The TIRS instrument employs a refractive telescope design that is opaque to visible wavelengths making prelaunch geometric characterization challenging. TIRS geometric calibration thus relied heavily on on-orbit measurements. Since the two Landsat 8 payloads are complementary and generate combined Level 1 data products, the TIRS geometric performance requirements emphasize the co-alignment of the OLI and TIRS instrument fields of view and the registration of the OLI reflective bands to the TIRS long-wave infrared emissive bands. The TIRS on-orbit calibration procedures include measuring the TIRS-to-OLI alignment, refining the alignment of the three TIRS sensor chips, and ensuring the alignment of the two TIRS spectral bands. The two key TIRS performance metrics are the OLI reflective to TIRS emissive band registration accuracy, and the registration accuracy between the TIRS thermal bands. The on-orbit calibration campaign conducted during the commissioning period provided an accurate TIRS geometric model that enabled TIRS Level 1 data to meet all geometric accuracy requirements. Seasonal variations in TIRS-to-OLI alignment have led to several small calibration parameter adjustments since commissioning.

  15. Atmospheric water vapor retrieval from Landsat 8 thermal infrared images

    Science.gov (United States)

    Ren, Huazhong; Du, Chen; Liu, Rongyuan; Qin, Qiming; Yan, Guangjian; Li, Zhao-Liang; Meng, Jinjie

    2015-03-01

    Atmospheric water vapor (wv) is required for the accurate retrieval of the land surface temperature from remote sensing data and other applications. This work aims to estimate wv from Landsat 8 Thermal InfraRed Sensor (TIRS) images using a new modified split-window covariance-variance ratio (MSWCVR) method on the basis of the brightness temperatures of two thermal infrared bands. Results show that the MSWCVR method can theoretically retrieve wv with an accuracy better than 0.3 g/cm2 for dry atmosphere (wv Robotic Network) ground-measured data and MODIS (Moderate Resolution Imaging Spectroradiometer) products. The results show that the retrieved wv from the TIRS data is highly correlated with the wv of AERONET and MODIS but is generally larger. This difference was probably attributed to the uncertainty of radiometric calibration and stray light coming outside from field of view of TIRS instrument in the current images. Consequently, the data quality and radiometric calibration of the TIRS data should be improved in the future.

  16. Development of a neurofeedback protocol targeting the frontal pole using near-infrared spectroscopy.

    Science.gov (United States)

    Kinoshita, Akihide; Takizawa, Ryu; Yahata, Noriaki; Homae, Fumitaka; Hashimoto, Ryuichiro; Sakakibara, Eisuke; Kawasaki, Shingo; Nishimura, Yukika; Koike, Shinsuke; Kasai, Kiyoto

    2016-11-01

    Neurofeedback has been studied with the aim of controlling cerebral activity. Near-infrared spectroscopy is a non-invasive neuroimaging technique used for measuring hemoglobin concentration changes in cortical surface areas with high temporal resolution. Thus, near-infrared spectroscopy may be useful for neurofeedback, which requires real-time feedback of repeated brain activation measurements. However, no study has specifically targeted neurofeedback, using near-infrared spectroscopy, in the frontal pole cortex. We developed an original near-infrared spectroscopy neurofeedback system targeting the frontal pole cortex. Over a single day of testing, each healthy participant (n = 24) received either correct or incorrect (Sham) feedback from near-infrared spectroscopy signals, based on a crossover design. Under correct feedback conditions, significant activation was observed in the frontal pole cortex (P = 0.000073). Additionally, self-evaluation of control and metacognitive beliefs were associated with near-infrared spectroscopy signals (P = 0.006). The neurofeedback system developed in this study might be useful for developing control of frontal pole cortex activation. © 2016 The Authors. Psychiatry and Clinical Neurosciences © 2016 Japanese Society of Psychiatry and Neurology.

  17. Interdiffusion of free and grafted poly(methylmethacrylate) with polyvinylchloride, studied by infrared spectroscopy

    NARCIS (Netherlands)

    Boven, Gert; Brinkhuis, Richard H.G.; Vorenkamp, Eltjo J.; Challa, Ger; Schouten, Arend J.

    1992-01-01

    As a guide for adhesion development between two miscible polymers, interdiffusion of these polymers was studied using external reflection and attenuated total reflection infrared spectroscopy. Using gold substrates coated with a double layer of PMMA and PVC, and s-polarized infrared light, PMMA

  18. Discriminating oat and groat kernels from other grains using near infrared spectroscopy

    Science.gov (United States)

    Oat and groats can be discriminated from other grains such as barley, wheat, rye, and triticale (non-oats) using near infrared spectroscopy. The two instruments tested were the manual version of the ARS-USDA Single Kernel Near Infrared (SKNIR) and the automated QualySense QSorter Explorer high-speed...

  19. Development of secondary cell wall in cotton fibers as examined with Fourier transform-infrared spectroscopy

    Science.gov (United States)

    Our presentation will focus on continuing efforts to examine secondary cell wall development in cotton fibers using infrared Spectroscopy. Cotton fibers harvested at 18, 20, 24, 28, 32, 36 and 40 days after flowering were examined using attenuated total reflection Fourier transform-infrared (ATR FT-...

  20. Monitoring Thermal Pollution in Rivers Downstream of Dams with Landsat ETM+ Thermal Infrared Images

    Directory of Open Access Journals (Sweden)

    Feng Ling

    2017-11-01

    Full Text Available Dams play a significant role in altering the spatial pattern of temperature in rivers and contribute to thermal pollution, which greatly affects the river aquatic ecosystems. Understanding the temporal and spatial variation of thermal pollution caused by dams is important to prevent or mitigate its harmful effect. Assessments based on in-situ measurements are often limited in practice because of the inaccessibility of water temperature records and the scarcity of gauges along rivers. By contrast, thermal infrared remote sensing provides an alternative approach to monitor thermal pollution downstream of dams in large rivers, because it can cover a large area and observe the same zone repeatedly. In this study, Landsat Enhanced Thematic Mapper Plus (ETM+ thermal infrared imagery were applied to assess the thermal pollution caused by two dams, the Geheyan Dam and the Gaobazhou Dam, located on the Qingjiang River, a tributary of the Yangtze River downstream of the Three Gorges Reservoir in Central China. The spatial and temporal characteristics of thermal pollution were analyzed with water temperatures estimated from 54 cloud-free Landsat ETM+ scenes acquired in the period from 2000 to 2014. The results show that water temperatures downstream of both dams are much cooler than those upstream of both dams in summer, and the water temperature remains stable along the river in winter, showing evident characteristic of the thermal pollution caused by dams. The area affected by the Geheyan Dam reaches beyond 20 km along the downstream river, and that affected by the Gaobazhou Dam extends beyond the point where the Qingjiang River enters the Yangtze River. Considering the long time series and global coverage of Landsat ETM+ imagery, the proposed technique in the current study provides a promising method for globally monitoring the thermal pollution caused by dams in large rivers.

  1. Infrared thermal imaging in the diagnosis of musculoskeletal injuries: a systematic review and meta-analysis.

    Science.gov (United States)

    Sanchis-Sánchez, Enrique; Vergara-Hernández, Carlos; Cibrián, Rosa M; Salvador, Rosario; Sanchis, Enrique; Codoñer-Franch, Pilar

    2014-10-01

    Musculoskeletal injuries occur frequently. Diagnostic tests using ionizing radiation can lead to problems for patients, and infrared thermal imaging could be useful when diagnosing these injuries. A systematic review was performed to determine the diagnostic accuracy of infrared thermal imaging in patients with musculoskeletal injuries. A meta-analysis of three studies evaluating stress fractures was performed and found a lack of support for the usefulness of infrared thermal imaging in musculoskeletal injuries diagnosis.

  2. Optimally designed narrowband guided-mode resonance reflectance filters for mid-infrared spectroscopy

    OpenAIRE

    Liu, Jui-Nung; Schulmerich, Matthew V.; Bhargava, Rohit; Cunningham, Brian T.

    2011-01-01

    An alternative to the well-established Fourier transform infrared (FT-IR) spectrometry, termed discrete frequency infrared (DFIR) spectrometry, has recently been proposed. This approach uses narrowband mid-infrared reflectance filters based on guided-mode resonance (GMR) in waveguide gratings, but filters designed and fabricated have not attained the spectral selectivity (≤ 32 cm−1) commonly employed for measurements of condensed matter using FT-IR spectroscopy. With the incorporation of disp...

  3. Infrared and Raman spectroscopy: principles and spectral interpretation

    National Research Council Canada - National Science Library

    Larkin, Peter

    2011-01-01

    .... The book reviews basic principles, instrumentation, sampling methods, quantitative analysis, origin of group frequencies and qualitative interpretation using generalized Infrared (IR) and Raman spectra...

  4. Oxygenation dynamics of sepsis patients undergoing far-infrared intervention based on near-infrared spectroscopy.

    Science.gov (United States)

    Chuang, Kuei-Hung; Chuang, Ming-Lung; Sia, Sung-Kien; Sun, Chia-Wei

    2017-03-01

    Near-infrared spectroscopy (NIRS; continuous wave type) is a noninvasive tool for detecting the relative change of oxyhemoglobin and deoxyhemoglobin. To make this change, intervention methods must be applied. This study determined the hemodynamics of 44 healthy participants and 35 patients with sepsis during exposure to FIR as a novel physical intervention approach. Local microcirculation of their brachioradialis was monitored during exposure and recovery through NIRS. The variations in blood flow and microvascular reaction were determined by conducting paired and unpaired t tests. The oxyhemoglobin levels of the healthy participants increased continuously, even during recovery. In contrast to expextations, the oxyhemoglobin levels of the patients plateaued after only 5 min of FIR illumination. The proposed method has potential applications for ensuring efficient treatment and facilitating doctors in diagnosing the functions of vessels in intensive care units. Mapping diagrams of HbO2 in healthy males and males with sepsis illustrated unique scenarios during the process. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. The facial expression of schizophrenic patients applied with infrared thermal facial image sequence

    National Research Council Canada - National Science Library

    Bo-Lin Jian; Chieh-Li Chen; Wen-Lin Chu; Min-Wei Huang

    2017-01-01

    .... Thus, this study used non-contact infrared thermal facial images (ITFIs) to analyze facial temperature changes evoked by different emotions in moderately and markedly ill schizophrenia patients...

  6. Analysis of Chuanxiong Rhizoma and its active components by Fourier transform infrared spectroscopy combined with two-dimensional correlation infrared spectroscopy.

    Science.gov (United States)

    Guo, Yizhen; Lv, Beiran; Wang, Jingjuan; Liu, Yang; Sun, Suqin; Xiao, Yao; Lu, Lina; Xiang, Li; Yang, Yanfang; Qu, Lei; Meng, Qinghong

    2016-01-15

    As complicated mixture systems, active components of Chuanxiong Rhizoma are very difficult to identify and discriminate. In this paper, the macroscopic IR fingerprint method including Fourier transform infrared spectroscopy (FT-IR), the second derivative infrared spectroscopy (SD-IR) and two-dimensional correlation infrared spectroscopy (2DCOS-IR), was applied to study and identify Chuanxiong raw materials and its different segmented production of HPD-100 macroporous resin. Chuanxiong Rhizoma is rich in sucrose. In the FT-IR spectra, water eluate is more similar to sucrose than the powder and the decoction. Their second derivative spectra amplified the differences and revealed the potentially characteristic IR absorption bands and combined with the correlation coefficient, concluding that 50% ethanol eluate had more ligustilide than other eluates. Finally, it can be found from 2DCOS-IR spectra that proteins were extracted by ethanol from Chuanxiong decoction by HPD-100 macroporous resin. It was demonstrated that the above three-step infrared spectroscopy could be applicable for quick, non-destructive and effective analysis and identification of very complicated and similar mixture systems of traditional Chinese medicines. Copyright © 2015 Elsevier B.V. All rights reserved.

  7. Rapid Quantitative Analysis of Forest Biomass Using Fourier Transform Infrared Spectroscopy and Partial Least Squares Regression

    Directory of Open Access Journals (Sweden)

    Gifty E. Acquah

    2016-01-01

    Full Text Available Fourier transform infrared reflectance (FTIR spectroscopy has been used to predict properties of forest logging residue, a very heterogeneous feedstock material. Properties studied included the chemical composition, thermal reactivity, and energy content. The ability to rapidly determine these properties is vital in the optimization of conversion technologies for the successful commercialization of biobased products. Partial least squares regression of first derivative treated FTIR spectra had good correlations with the conventionally measured properties. For the chemical composition, constructed models generally did a better job of predicting the extractives and lignin content than the carbohydrates. In predicting the thermochemical properties, models for volatile matter and fixed carbon performed very well (i.e., R2 > 0.80, RPD > 2.0. The effect of reducing the wavenumber range to the fingerprint region for PLS modeling and the relationship between the chemical composition and higher heating value of logging residue were also explored. This study is new and different in that it is the first to use FTIR spectroscopy to quantitatively analyze forest logging residue, an abundant resource that can be used as a feedstock in the emerging low carbon economy. Furthermore, it provides a complete and systematic characterization of this heterogeneous raw material.

  8. [Application and prospect of near infrared reflectance spectroscopy in forage analysis].

    Science.gov (United States)

    Ren, Xiu-Zhen; Guo, Hong-Ru; Jia, Yu-Shan; Ge, Gen-Tu; Wang, Kun

    2009-03-01

    Forage was the material basis of animal husbandry production, and its quality is directly related to the quality of animal products. It was very important to control the forage quality and detect the composition of forage raw materials in forage production. Predication of forage quality was often completed by the traditional and classical methods in the past, which were complex, time consuming and expensive, and could not acquire the nutritional value of forage timely. Near infrared reflectance spectroscopy was a highly efficient and rapid modern analysis technique developed in 1970's. It comprehensively applied the latest research results of computer technique, spectroscopy and chemometrics, and has been widely used in various fields owing to its unique advantages such as being timely, less expensive, non-destructive, and so on. Near infrared reflectance spectroscopy has gained more and more importance though its application to forage analysis was very late. Presently, not only conventional composition (such as moisture, dry matter, crude protein, crude fiber, crude fat, crude ash neutral detergent fiber, acid detergent fiber, etc.), but also non-conventional composition (including minerals, trace elements, enzyme and anti-nutritional factors etc. ) and anti-nutritional factors in forage were determined by means of near infrared reflectance spectroscopy. Testing and analyzing the conventional composition in forage was the traditional applied field of near infrared reflectance spectroscopy, a lot of studies of which were done and it has already been one of the standard methods of testing the conventional composition. Forage bioavaibility was also evaluated by near infrared reflectance spectroscopy, so as to assess the utilization rate and nutritional value of forage. Moreover, near infrared spectroscopy could be used successfully to predict the botanical composition in grassland and leaf/stem ratios. Near infrared spectroscopy technique and its application and

  9. Species authentication and geographical origin discrimination of herbal medicines by near infrared spectroscopy: A review

    Directory of Open Access Journals (Sweden)

    Pei Wang

    2015-10-01

    Full Text Available Near infrared (NIR spectroscopy as a rapid and nondestructive analytical technique, integrated with chemometrics, is a powerful process analytical tool for the pharmaceutical industry and is becoming an attractive complementary technique for herbal medicine analysis. This review mainly focuses on the recent applications of NIR spectroscopy in species authentication of herbal medicines and their geographical origin discrimination.

  10. NEAR-INFRARED SPECTROSCOPY OF POST-AGB STARS

    NARCIS (Netherlands)

    OUDMAIJER, RD; WATERS, LBFM; VANDERVEEN, WECJ; GEBALLE, TR

    The results of a medium resolution near-infrared spectral survey of 18 post-AGB candidate stars are presented. Most of the stars have near-infrared hydrogen lines in absorption, which is normal for their spectral types. Three stars, HD 101584, HD 179821 and HD 170756 have the CO first overtone bands

  11. Infrared Spectroscopy and Physical Chemistry of Cryogenic Aerosols

    Science.gov (United States)

    Clapp, Mannie Lee

    1995-01-01

    Infrared spectroscopy has been used as a tool for elucidating the spectroscopic and physical properties of cryogenic aerosols. Ammonia and hydrazine aerosols have been studied using this technique under conditions designed to mimic those found in the atmosphere of Jupiter. Aerosols of water ice, nitric acid and water, and sulfuric acid and water were also studied under temperature conditions similar to those found in the Earth's stratosphere. Aerosols are generated in low temperature flow cells via homogeneous and heterogeneous nucleation of the gas phase. The technique affords information on the size, composition, number density, and in some cases shape, of the particles created. Both ammonia and hydrazine aerosols were studied over the temperature range from 180 K to 110 K. Mie theory can adequately describe the observed particle spectra in most cases. Under conditions designed to enhance particle aggregation, shape effects in the 9.4 mu m absorption band of the ammonia aerosols become apparent which can be modeled well using the Discrete Dipole Approximation. Both substances can exist as supercooled liquid droplets. Ammonia particles freeze distinctly at 155 K, while hydrazine particles freeze over the temperature range from 180 K to 170 K. Spectra of aerosols which are of mixtures of ammonia and hydrazine reveal that the inclusion of hydrazine into ammonia particles affects the spectrum of the ammonia very little, while the hydrazine absorptions are strongly perturbed. Hydrazine is not very soluble in the ammonia particles, even at very low concentrations. A new technique for determining complex refractive indices from aerosol spectra has been developed and applied to water ice and crystalline hydrazine. Comparisons with previous data indicate that the method is sound and accurate. The temperature dependence of the water ice complex refractive index has been quantified and compares well with previous results as a function of temperature. No temperature

  12. Terahertz and Infrared Laboratory Spectroscopy in Support of NASA Missions

    Science.gov (United States)

    Yu, Shanshan

    2015-06-01

    The JPL molecular spectroscopy group supports NASA programs encompassing Astrophysics, Atmospheric Science, and Planetary Science. Ongoing activities include measurement and analysis of molecular spectra in the terahertz and infrared regions under conditions akin to the remote environments under study in NASA missions. This presentation will show the implementation of state-of-the-art spectroscopic techniques to fulfill spectroscopic demands of the Herschel Space Observatory and the Orbiting Carbon Observatory re-flight (OCO-2). A demonstrative example of the significantly improved frequency predictions for the H_3O^+ ground state high-J transitions will be given. This work was critical to Herschel's successful identification of highly excited metastable H_3O^+ Terahertz lines with J=K up to 11, one of the Herschel mission's many surprising observational results. The observation and subsequent laboratory work revealed that (1) these highly excited H_3O^+ lines had already been observed by European Southern Observatory's Atacama Pathfinder Experiment telescope a few years before but had been classified as U-lines; (2) the H_3O^+ number density was previously underestimated by an order of magnitude, due to ignorance of the population in the metastable states. A second example focuses on O_2, an important absorber from the microwave through the deep UV. This work is motivated by the challenge of developing an accurate and complete spectroscopic characterization of molecular oxygen across a wide frequency range for current and planned Earth atmospheric observations. Especially, OCO-2 utilizes the O_2 A-band for air mass calibration; extremely accurate O_2 molecular data, i.e., line positions with uncertainty on the order of MHz for the A-band around 13000 wn, are required to fulfill the demand of the proposed 0.25% precision for the carbon dioxide concentration retrievals. G. Pilbratt, J. Riedinger, T. Passvogel, G. Crone, D. Doyle, U. Gageur et al. A&A, 518, L1 (2010

  13. Thermal surveillance of active volcanoes. [infrared scanner recordings of thermal anomalies of Mt. Baker volcano

    Science.gov (United States)

    Friedman, J. D. (Principal Investigator)

    1974-01-01

    The author has identified the following significant results. By the end of 1973, aerial infrared scanner traverses for thermal anomaly recordings of all Cascade Range volcanoes were essentially completed. Amplitude level slices of the Mount Baker anomalies were completed and compiled at a scale of 1:24,000, thus producing, for the first time, an accurate map of the distribution and intensity of thermal activity on Mount Baker. The major thermal activity is concentrated within the crater south of the main summit and although it is characterized by intensive solfataric activity and warm ground, it is largely subglacial, causing the development of sizable glacier perforation features. The outgoing radiative flux from the east breach anomalies is sufficient to account for the volume of ice melted to form the glacier perforations. DCP station 6251 has been monitoring a thermally anomalous area on the north slope of Mount Baker. The present thermal activity of Mount Baker accounts for continuing hydrothermal alteration in the crater south of the main summit and recurrent debris avalanches from Sherman Peak on its south rim. The infrared anomalies mapped as part of the experiment SR 251 are considered the basic evidence of the subglacial heating which was the probable triggering mechanism of an avalanche down Boulder Glacier on August 20-21, 1973.

  14. Infrared spectroscopy of Mercury analogue materials under simulated Mercury surface temperature conditions

    Science.gov (United States)

    Reitze, Maximilian; Morlok, Andreas; Hiesinger, Harald; Weber, Iris; Stojic, Aleksandra

    2017-04-01

    Infrared spectroscopy is a powerful technique for the exploration of planetary surfaces with remote sensing observations [e.g., 1]. The MERTIS (Mercury Radiometer and Thermal Infrared Spectrometer) instrument onboard the BepiColombo spacecraft is designed to explore the surface mineralogy of Mercury in the wavelength region from 7 μ m to 14 μ m [2]. Mercury's surface reaches dayside temperatures of about 700 K [3]. It is well known that bondings between atoms change with temperature, resulting in infrared spectra changes with temperature [4]. In particular, rock-forming minerals like silicates show distinct absorption bands in the infrared due to molecular vibrations, for example, of Si-O bondings [4]. To accurately understand and correctly interpret returned MERTIS data, it is necessary to collect laboratory data of analogue materials under condition similar to Mercury [5]. It is known from previous investigations [5] that the Reststrahlenbands of olivine shift with temperature. In this work we report on temperature effects on Mercury analogue materials in ambient air. At the IRIS (Infrared & Raman for Interplanetary Spectroscopy) laboratory in Münster we used a Bruker VERTEX 70v IR spectrometer together with a Harrick heating stage in a Praying Mantis Diffuse Reflectance Accessory to measure mid-infrared reflectance of mineral powder samples with different grain sizes at increasing temperatures. We report on our spectral results for a natural olivine with Fo91 with a grain size range between 63 μ m and 125 μ m as well as a natural labradorite with a grain size range between 90 μ m and 125 μ m. Spectra were collected at 26, 75, 150, 200, 250, 300, and 350 degrees Celsius with a liquid nitrogen cooled MCT detector under normal ambient pressure. To ensure complete thermal equilibrium of our measured samples, we heated them to higher temperatures and subsequently cooled them to the temperatures at which the spectra were taken. For background calibration, we

  15. The MAMBA Thermal Infrared All-Sky Camera

    Science.gov (United States)

    Pier, Edward Alan; Tinn Chee Jim, Kevin; Lewis, Peter

    2015-08-01

    We are developing a system to continually and simultaneously monitor infrared atmospheric extinction along all lines of sight. This system combines a next generation radiometrically calibrated thermal all-sky camera, a weather station, and a neural net trained on historic Radiosonde profiles. Oceanit Laboratories, Inc. will market this system as an off the shelf unit. Custom-built thermal all sky cameras have previously been used on Haleakala, Cerro Tololo, and elsewhere. Except for RASICAM on Cerro Tololo, they have not been radiometrically calibrated and have been used only for qualitative cloud monitoring. The new system will have improved sky coverage, resolution, and noise properties with respect to RASICAM, and simulations show it will be able to infer atmospheric transmittance to within a few percent. The all sky camera will combine an equiresolution optical design with an off-the-shelf thermal detector and in field blackbody calibration sources to provide uniform sensitivity and radiometric accuracy across the sky at relatively low cost. Our goal is to make such systems ubiqitous at observatories around the world.

  16. PHyTIR - A Prototype Thermal Infrared Radiometer

    Science.gov (United States)

    Jau, Bruno M.; Hook, Simon J.; Johnson, William R.; Foote, Marc C.; Paine, Christopher G.; Pannell, Zack W.; Smythe, Robert F.; Kuan, Gary M.; Jakoboski, Julie K.; Eng, Bjorn T.

    2013-01-01

    This paper describes the PHyTIR (Prototype HyspIRI Thermal Infrared Radiometer) instrument, which is the engineering model for the proposed HyspIRI (Hyperspectral Infrared Imager) earth observing instrument. The HyspIRI mission would be comprised of the HyspIRI TIR (Thermal Infrared Imager), and a VSWIR (Visible Short-Wave Infra-Red Imaging Spectrometer). Both instruments would be used to address key science questions related to the earth's carbon cycle, ecosystems, climate, and solid earth properties. Data gathering of volcanic activities, earthquakes, wildfires, water use and availability, urbanization, and land surface compositions and changes, would aid the predictions and evaluations of such events and the impact they create. Even though the proposed technology for the HyspIRI imager is mature, the PHyTIR prototype is needed to advance the technology levels for several of the instrument's key components, and to reduce risks, in particular to validate 1) the higher sensitivity, spatial resolution, and higher throughput required for this focal plane array, 2) the pointing accuracy, 2) the characteristics of several spectral channels, and 4) the use of ambient temperature optics. The PHyTIR telescope consists of the focal plane assembly that is housed within a cold housing located inside a vacuum enclosure; all mounted to a bulkhead, and an optical train that consists of 3 powered mirrors; extending to both sides of the bulkhead. A yoke connects the telescope to a scan mirror. The rotating mirror enables to scan- a large track on the ground. This structure is supported by kinematic mounts, linking the telescope assembly to a base plate that would also become the spacecraft interface for HyspIRI. The focal plane's cooling units are also mounted to the base plate, as is an overall enclosure that has two viewing ports with large exterior baffles, shielding the focal plane from incoming stray light. PHyTIR's electronics is distributed inside and near the vacuum

  17. Detecting infrared luminescence and non-chemical signaling of living cells: single cell mid-IR spectroscopy in cryogenic environments

    Science.gov (United States)

    Pereverzev, Sergey

    2017-02-01

    Many life-relevant interaction energies are in IR range, and it is reasonable to believe that some biochemical reactions inside cells can results in emission of IR photons. Cells can use this emission for non-chemical and non-electrical signaling. Detecting weak infrared radiation from live cells is complicated because of strong thermal radiation background and absorption of radiation by tissues. A microfluidic device with live cells inside a vacuum cryogenic environment should suppress this background, and thereby permit observation of live cell auto-luminescence or signaling in the IR regime. One can make IR-transparent windows not emitting in this range, so only the cell and a small amount of liquid around it will emit infrared radiation. Currently mid-IR spectroscopy of single cells requires the use of a synchrotron source to measure absorption or reflection spectra. Decreasing of thermal radiation background will allow absorption and reflection spectroscopy of cells without using synchrotron light. Moreover, cell auto-luminescence can be directly measured. The complete absence of thermal background radiation for cryogenically cooled samples allows the use IR photon-sensitive detectors and obtaining single molecule sensitivity in IR photo-luminescence measurements. Due to low photon energies, photo-luminescence measurements will be non-distractive for pressures samples. The technique described here is based upon US patent 9366574.

  18. An Overview of the Evolution of Infrared Spectroscopy Applied to Bacterial Typing.

    Science.gov (United States)

    Quintelas, Cristina; Ferreira, Eugénio C; Lopes, João A; Sousa, Clara

    2018-01-01

    The sustained emergence of new declared bacterial species makes typing a continuous challenge for microbiologists. Molecular biology techniques have a very significant role in the context of bacterial typing, but they are often very laborious, time consuming, and eventually fail when dealing with very closely related species. Spectroscopic-based techniques appear in some situations as a viable alternative to molecular methods with advantages in terms of analysis time and cost. Infrared and mass spectrometry are among the most exploited techniques in this context: particularly, infrared spectroscopy emerged as a very promising method with multiple reported successful applications. This article presents a systematic review on infrared spectroscopy applications for bacterial typing, highlighting fundamental aspects of infrared spectroscopy, a detailed literature review (covering different taxonomic levels and bacterial species), advantages, and limitations of the technique over molecular biology methods and a comparison with other competing spectroscopic techniques such as MALDI-TOF MS, Raman, and intrinsic fluorescence. Infrared spectroscopy possesses a high potential for bacterial typing at distinct taxonomic levels and worthy of further developments and systematization. The development of databases appears fundamental toward the establishment of infrared spectroscopy as a viable method for bacterial typing. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  19. Hydrolysis of Baltic amber during thermal ageing--an infrared spectroscopic approach.

    Science.gov (United States)

    Pastorelli, Gianluca; Shashoua, Yvonne; Richter, Jane

    2013-04-01

    To enable conservation of amber in museums, understanding of chemical changes is crucial. While oxidation has been investigated particularly well for this natural polymer, further degradation phenomena in relation to humidity and pollutants are poorly studied or still unknown. Attenuated total reflectance-Fourier transform infrared spectroscopy was explored with regard to Baltic amber. A systematic spectroscopic survey of a wide range of thermally aged model amber samples, exposed to different microclimatic conditions, showed significant changes in their spectra. Samples aged in a humid and acidic environment or exposed to a humid and alkaline atmosphere generally exhibited a higher absorbance intensity of carbonyl groups at frequencies assigned to acids than unaged samples, samples aged in drier conditions and samples immersed in an alkaline solution. Baltic amber comprises succinate ester, which may be hydrolysed into communol and succinic acid. The survey thus provided evidence about the progress of hydrolytic reactions during degradation of Baltic amber. Infrared spectroscopy was shown to have significant potential for providing qualitative and quantitative chemical information on hydrolysis of amber, which will be of interest for the development of preventive conservation techniques for museum collections of amber objects. Copyright © 2013 Elsevier B.V. All rights reserved.

  20. Thermal conductivity of a film of single walled carbon nanotubes measured with infrared thermal imager

    Science.gov (United States)

    Feng, Ya; Inoue, Taiki; Xiang, Rong; Chiashi, Shohei; Maruyama, Shigeo

    Heat dissipation has restricted the modern miniaturization trend with the development of electronic devices. Theoretically proven to be with high axial thermal conductivity, single walled carbon nanotubes (SWNT) have long been expected to cool down the nanoscale world. Even though the tube-tube contact resistance limits the capability of heat transfer of the bulk film, the high intrinsic thermal conductivity of SWNT still glorify the application of films of SWNT network as a thermal interface material. In this work, we proposed a new method to straightly measure the thermal conductivity of SWNT film. We bridged two cantilevered Si thin plate with SWNT film, and kept a steady state heat flow in between. With the infrared camera to record the temperature distribution, the Si plates with known thermal conductivity can work as a reference to calculate the heat flux going through the SWNT film. Further, the thermal conductivity of the SWNT film can be obtained through Fourier's law after deducting the effect of thermal radiation. The sizes of the structure, the heating temperature, the vacuum degree and other crucial impact factors are carefully considered and analyzed. The author Y. F. was supported through the Advanced Integration Science Innovation Education and Research Consortium Program by the Ministry of Education, Culture, Sport, Science and Technology.

  1. Using Thermal Infrared Absorption and Emission to Determine Trace Gases

    Science.gov (United States)

    Clerbaux, Cathy; Drummond, James R.; Flaud, Jean-Marie; Orphal, Johannes

    The light emerging from the top of the atmosphere in the greater part of the infrared region is thermal radiation from the Earth's surface. The resultant spectra obtained depend on the temperature difference between the emitting feature and absorbing gas. In this region the greenhouse gases, carbon dioxide, CO2, methane, CH4, ozone, O3, and water, H2O, are observed as well as carbon monoxide, CO, a product indicative of fossil fuel combustion, methanol, CH3OH, from biomass burning, and ammonia, NH3, from agriclulture. Chapter 3 describes the techniques for retrieving atmospheric abundances of these and other species from a number of satellite instruments, and concludes with suggestions for future developments.

  2. The new airborne Thermal Infrared Multispectral Scanner (TIMS)

    Science.gov (United States)

    Kahle, A. B.

    1983-01-01

    A new airborne Thermal Infrared Multispectral Scanner (TIMS) with six bands between 8 and 12 microns is briefly characterized, and some results of remote sensing experiments are reported. The instrument has an instantaneous field of view of 2.5 milliradians, a total field of view of 80 deg, and a NE Delta T of approximately 0.1-0.3 C depending on the band. In the TIMS image of Death Valley, silica-rich rocks were easily separable from the nonsilicates. The Eureka Quartzite stood out in sharp contrast to other Ordovician and Cambrian metasediments, and Tertiary volcanic rocks were easily separable from both. Also distinguishable were various units in the fan gravels.

  3. An infrared radiation based thermal biosensor for enzymatic biochemical reactions.

    Science.gov (United States)

    Zhang, Lei; Dong, Tao; Zhao, Xinyan; Yang, Zhaochu; Pires, Nuno M M

    2012-01-01

    In this paper, a thermal biosensor based on the infrared radiation energy is proposed for calorimetric measurement of biochemical reactions. Having a good structure design combined with MEMS technology as well as employing the Si /SiGe quantum well sensing material with a high TCR and low 1/f noise, the sensor shows potentials to be high sensitive and real-time. The urea enzymatic reaction was tested to verify the performance of sensor, which demonstrates a linear detection range from 0.5mM to 150mM and a relative standard deviation less than 1%. For the sensor fabrication, wafer-level transfer bonding is a key process, which makes the integration of quantum well material and a free standing structure possible. It reduces the heat loss from the sensor to the surrounding environment.

  4. A method for accurate temperature measurement using infrared thermal camera.

    Science.gov (United States)

    Tokunaga, Tomoharu; Narushima, Takashi; Yonezawa, Tetsu; Sudo, Takayuki; Okubo, Shuichi; Komatsubara, Shigeyuki; Sasaki, Katsuhiro; Yamamoto, Takahisa

    2012-08-01

    The temperature distribution on a centre-holed thin foil of molybdenum, used as a sample and heated using a sample-heating holder for electron microscopy, was measured using an infrared thermal camera. The temperature on the heated foil area located near the heating stage of the heating holder is almost equal to the temperature on the heating stage. However, during the measurement of the temperature at the edge of the hole of the foil located farthest from the heating stage, a drop in temperature should be taken into consideration; however, so far, no method has been developed to locally measure the temperature distribution on the heated sample. In this study, a method for the accurate measurement of temperature distribution on heated samples for electron microscopy is discussed.

  5. Unmanned Ground Vehicle Perception Using Thermal Infrared Cameras

    Science.gov (United States)

    Rankin, Arturo; Huertas, Andres; Matthies, Larry; Bajracharya, Max; Assad, Christopher; Brennan, Shane; Bellutta, Paolo; Sherwin, Gary W.

    2011-01-01

    The ability to perform off-road autonomous navigation at any time of day or night is a requirement for some unmanned ground vehicle (UGV) programs. Because there are times when it is desirable for military UGVs to operate without emitting strong, detectable electromagnetic signals, a passive only terrain perception mode of operation is also often a requirement. Thermal infrared (TIR) cameras can be used to provide day and night passive terrain perception. TIR cameras have a detector sensitive to either mid-wave infrared (MWIR) radiation (3-5?m) or long-wave infrared (LWIR) radiation (8-12?m). With the recent emergence of high-quality uncooled LWIR cameras, TIR cameras have become viable passive perception options for some UGV programs. The Jet Propulsion Laboratory (JPL) has used a stereo pair of TIR cameras under several UGV programs to perform stereo ranging, terrain mapping, tree-trunk detection, pedestrian detection, negative obstacle detection, and water detection based on object reflections. In addition, we have evaluated stereo range data at a variety of UGV speeds, evaluated dual-band TIR classification of soil, vegetation, and rock terrain types, analyzed 24 hour water and 12 hour mud TIR imagery, and analyzed TIR imagery for hazard detection through smoke. Since TIR cameras do not currently provide the resolution available from megapixel color cameras, a UGV's daytime safe speed is often reduced when using TIR instead of color cameras. In this paper, we summarize the UGV terrain perception work JPL has performed with TIR cameras over the last decade and describe a calibration target developed by General Dynamics Robotic Systems (GDRS) for TIR cameras and other sensors.

  6. Development of Thermal Infrared Sensor to Supplement Operational Land Imager

    Science.gov (United States)

    Shu, Peter; Waczynski, Augustyn; Kan, Emily; Wen, Yiting; Rosenberry, Robert

    2012-01-01

    The thermal infrared sensor (TIRS) is a quantum well infrared photodetector (QWIP)-based instrument intended to supplement the Operational Land Imager (OLI) for the Landsat Data Continuity Mission (LDCM). The TIRS instrument is a far-infrared imager operating in the pushbroom mode with two IR channels: 10.8 and 12 m. The focal plane will contain three 640 512 QWIP arrays mounted onto a silicon substrate. The readout integrated circuit (ROIC) addresses each pixel on the QWIP arrays and reads out the pixel value (signal). The ROIC is controlled by the focal plane electronics (FPE) by means of clock signals and bias voltage value. The means of how the FPE is designed to control and interact with the TIRS focal plane assembly (FPA) is the basis for this work. The technology developed under the FPE is for the TIRS focal plane assembly (FPA). The FPE must interact with the FPA to command and control the FPA, extract analog signals from the FPA, and then convert the analog signals to digital format and send them via a serial link (USB) to a computer. The FPE accomplishes the described functions by converting electrical power from generic power supplies to the required bias power that is needed by the FPA. The FPE also generates digital clocking signals and shifts the typical transistor-to-transistor logic (TTL) to }5 V required by the FPA. The FPE also uses an application- specific integrated circuit (ASIC) named System Image, Digitizing, Enhancing, Controlling, And Retrieving (SIDECAR) from Teledyne Corp. to generate the clocking patterns commanded by the user. The uniqueness of the FPE for TIRS lies in that the TIRS FPA has three QWIP detector arrays, and all three detector arrays must be in synchronization while in operation. This is to avoid data skewing while observing Earth flying in space. The observing scenario may be customized by uploading new control software to the SIDECAR.

  7. Optical properties of mineral dust aerosol in the thermal infrared

    Science.gov (United States)

    Köhler, Claas H.

    2017-02-01

    The optical properties of mineral dust and biomass burning aerosol in the thermal infrared (TIR) are examined by means of Fourier Transform Infrared Spectrometer (FTIR) measurements and radiative transfer (RT) simulations. The measurements were conducted within the scope of the Saharan Mineral Dust Experiment 2 (SAMUM-2) at Praia (Cape Verde) in January and February 2008. The aerosol radiative effect in the TIR atmospheric window region 800-1200 cm-1 (8-12 µm) is discussed in two case studies. The first case study employs a combination of IASI measurements and RT simulations to investigate a lofted optically thin biomass burning layer with emphasis on its potential influence on sea surface temperature (SST) retrieval. The second case study uses ground based measurements to establish the importance of particle shape and refractive index for benchmark RT simulations of dust optical properties in the TIR domain. Our research confirms earlier studies suggesting that spheroidal model particles lead to a significantly improved agreement between RT simulations and measurements compared to spheres. However, room for improvement remains, as the uncertainty originating from the refractive index data for many aerosol constituents prohibits more conclusive results.

  8. Near infrared spectroscopy--investigations in neurovascular diseases.

    Science.gov (United States)

    Schytz, Henrik Winther

    2015-12-01

    The purpose of this thesis was to explore and develop methods, where continuous wave near infrared spectroscopy (CW-NIRS) can be applied in different neurovascular diseases, in order to find biological markers that are useful in clinical neurology. To develop a new method to detect changes in cerebral blood flow (CBF), the first study investigated a multi-source detector separation configuration and indocyanine green (ICG) as a tracer to calculate a corrected blood flow index (BFI) value. The study showed no correlation between CBF changes measured by 133Xenon single photon emission computer tomography (133Xe-SPECT) and the corrected BFI value. It was concluded, that it was not possible to obtain reliable BFI data with the ICG CW-NIRS method. NIRS measurements of low frequency oscillations (LFOs) may be a reliable method to investigate vascular alterations in neurovascular diseases, but this requires an acceptable LFOs variation between hemispheres and over time in the healthy brain. The second study therefore investigated day-to-day and hemispheric variations in LFOs with NIRS. It was shown that NIRS might be useful in assessing LFOs between hemispheres, as well as interhemispheric phase and gain directly and over time. Migraine may be associated with persistent impairment of neurovascular coupling, but there is no experimental evidence to support this. The third study therefore investigated interictal neurovascular coupling during a mental task by a Stroop test in migraine without aura (MO) patients, which is the most common type of migraine. The study showed intact neurovascular coupling in the prefrontal cortex outside of attacks in patients with MO. The fourth study aimed to investigate possible changes in LFOs amplitude following nitric oxide (NO) donor infusion in familial hemiplegic migraine (FHM), which is a rare Mendelian subtype of migraine with aura. This study showed increased LFOs amplitude only in FHM patients with co-existing common type of migraine

  9. Analysis of ecstasy in oral fluid by ion mobility spectrometry and infrared spectroscopy after liquid-liquid extraction.

    Science.gov (United States)

    Armenta, Sergio; Garrigues, Salvador; de la Guardia, Miguel; Brassier, Judit; Alcalà, Manel; Blanco, Marcelo

    2015-03-06

    We developed and evaluated two different strategies for determining abuse drugs based on (i) the analysis of saliva by ion mobility spectrometry (IMS) after thermal desorption and (ii) the joint use of IMS and infrared (IR) spectroscopy after liquid-liquid microextraction (LLME) to enable the sensitivity-enhanced detection and double confirmation of ecstasy (MDMA) abuse. Both strategies proved effective for the intended purpose. Analysing saliva by IMS after thermal desorption, which provides a limit of detection (LOD) of 160μgL(-1), requires adding 0.2M acetic acid to the sample and using the truncated negative second derivative of the ion mobility spectrum. The joint use of IMS and IR spectroscopy after LLME provides an LOD of 11μgL(-1) with the former technique and 800μgL(-1) with the latter, in addition to a limit of confirmation (LOC) of 1.5mgL(-1). Using IMS after thermal desorption simplifies the operational procedure, and using it jointly with IR spectroscopy after LLME allows double confirmation of MDMA abuse with two techniques based on different principles (viz., IMS drift times and IR spectra). Also, it affords on-site analyses, albeit at a lower throughput. Copyright © 2015 Elsevier B.V. All rights reserved.

  10. Thermal comfort of seats as visualized by infrared thermography.

    Science.gov (United States)

    Sales, Rosemary Bom Conselho; Pereira, Romeu Rodrigues; Aguilar, Maria Teresa Paulino; Cardoso, Antônio Valadão

    2017-07-01

    Published studies that deal with the question of how the temperature of chair seats influences human activities are few, but the studies considering such a factor, a function of the type of material, could contribute to improvements in the design of chairs. This study evaluates seat temperatures of 8 types of chairs made of different materials. The parts of the furniture that people come into contact with, and the thermal response of the material to heating and cooling have been evaluated. Infrared thermography was used for this, as it is a non-contact technique that does not present any type of risk in the measurement of temperatures. Seats made of synthetic leather (leatherette), wood and polyester fabric were found to have the highest temperatures, and the plywood seat showed the lowest. The study has also revealed that thermography can contribute to studies of thermal comfort of chair seats in addition to determining the most suitable material. Copyright © 2017 Elsevier Ltd. All rights reserved.

  11. Subsurface thermal coagulation of tissues using near infrared lasers

    Science.gov (United States)

    Chang, Chun-Hung Jack

    Noninvasive laser therapy is currently limited primarily to cosmetic dermatological applications such as skin resurfacing, hair removal, tattoo removal and treatment of vascular birthmarks. In order to expand applications of noninvasive laser therapy, deeper optical penetration of laser radiation in tissue as well as more aggressive cooling of the tissue surface is necessary. The near-infrared laser wavelength of 1075 nm was found to be the optimal laser wavelength for creation of deep subsurface thermal lesions in liver tissue, ex vivo, with contact cooling, preserving a surface tissue layer of 2 mm. Monte Carlo light transport, heat transfer, and Arrhenius integral thermal damage simulations were conducted at this wavelength, showing good agreement between experiment and simulations. Building on the initial results, our goal is to develop new noninvasive laser therapies for application in urology, specifically for treatment of female stress urinary incontinence (SUI). Various laser balloon probes including side-firing and diffusing fibers were designed and tested for both transvaginal and transurethral approaches to treatment. The transvaginal approach showed the highest feasibility. To further increase optical penetration depth, various types and concentrations of optical clearing agents were also explored. Three cadavers studies were performed to investigate and demonstrate the feasibility of laser treatment for SUI.

  12. Study of dilution of Spin-On Glass by Fourier transform infrared spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Dominguez, Miguel, E-mail: mdominguez@inaoep.mx [National Institute for Astrophysics, Optics and Electronics (INAOE), Electronics Department, Luis Enrique Erro No. 1, Puebla 72840 (Mexico); Rosales, Pedro; Torres, Alfonso; Moreno, Mario [National Institute for Astrophysics, Optics and Electronics (INAOE), Electronics Department, Luis Enrique Erro No. 1, Puebla 72840 (Mexico); Orduna, Abdu [CIBA-Tlaxcala, Instituto Politecnico Nacional, Tepetitla, Tlax. 90700 (Mexico)

    2012-05-31

    In this work, we study the dilution of Spin-On Glass (SOG) in order to obtain high quality SiO{sub 2} films at 200 Degree-Sign C, with optical and electrical characteristics similar to those of the thermally grown SiO{sub 2}. For the production of SiO{sub 2} films we used 2-propanol and deionized water (DI) as diluents for the SOG and we compared the electrical and optical film properties with those of the films obtained from undiluted SOG. From Fourier transform infrared spectroscopy we observed a considerable reduction of Si-OH (920 cm{sup -1}), O-H (3490 cm{sup -1}) and C-H, C-O bonds (1139 cm{sup -1}) in the films produced from SOG diluted with DI. Besides the above, the insulator breakdown field was approximately 21 MV/cm, the refractive index and the dielectric constant were close to those of the thermally grown SiO{sub 2}. Our results suggest that the film produced from SOG diluted with DI and cured at 200 Degree-Sign C is an excellent candidate to be used as insulator on flexible and large-area electronics. - Highlights: Black-Right-Pointing-Pointer Preparation of high quality silicon oxide (SiO{sub 2}) films at 200 Degree-Sign C. Black-Right-Pointing-Pointer Dilution of Spin-On Glass (SOG) solution was studied. Black-Right-Pointing-Pointer Dilution of SOG is necessary to obtain high quality films annealed at 200 Degree-Sign C. Black-Right-Pointing-Pointer n and k are close to those of the thermally grown SiO{sub 2}.

  13. All-Semiconductor Plasmonic Resonator for Surface-Enhanced Infrared Absorption Spectroscopy

    Directory of Open Access Journals (Sweden)

    Wei Wei

    2017-01-01

    Full Text Available Infrared absorption spectroscopy remains a challenge due to the weak light-matter interaction between micron-wavelengthed infrared light and nano-sized molecules. A highly doped semiconductor supports intrinsic plasmon modes at infrared frequencies, and is compatible with the current epitaxial growth processing, which makes it promising for various applications. Here, we propose an all-semiconductor plasmonic resonator to enhance the infrared absorption of the adsorbed molecules. An optical model is employed to investigate the effect of structural parameters on the spectral features of the resonator and the enhanced infrared absorption characteristics are further discussed. When a molecular layer is deposited upon the resonator, the weak molecular absorption signal can be significantly enhanced. A high enhancement factor of 470 can be achieved once the resonance wavelength of the resonator is overlapped with the desired vibrational mode of the molecules. Our study offers a promising approach to engineering semiconductor optics devices for mid-infrared sensing applications.

  14. Application of Near Infrared Spectroscopy, Intravascular Ultrasound and the Coronary Calcium Score to Predict Adverse Coronary Events

    Science.gov (United States)

    2015-10-01

    Award Number: W81XWH-11-1-0831 TITLE: Application of Near Infrared Spectroscopy , Intravascular Ultrasound and the Coronary Calcium Score to...3. DATES COVERED 26-SEP-2014 to 25-SEP-2015 4. TITLE AND SUBTITLE Application of Near Infrared Spectroscopy , Intravascular Ultrasound and the...planned. 15. SUBJECT TERMS coronary artery disease, near infrared spectroscopy , calcium scoring, intravascular ultrasound 16. SECURIY CLASSIFICATION OF

  15. Identification of anisodamine tablets by Raman and near-infrared spectroscopy with chemometrics.

    Science.gov (United States)

    Li, Lian; Zang, Hengchang; Li, Jun; Chen, Dejun; Li, Tao; Wang, Fengshan

    2014-06-05

    Vibrational spectroscopy including Raman and near-infrared (NIR) spectroscopy has become an attractive tool for pharmaceutical analysis. In this study, effective calibration models for the identification of anisodamine tablet and its counterfeit and the distinguishment of manufacturing plants, based on Raman and NIR spectroscopy, were built, respectively. Anisodamine counterfeit tablets were identified by Raman spectroscopy with correlation coefficient method, and the results showed that the predictive accuracy was 100%. The genuine anisodamine tablets from 5 different manufacturing plants were distinguished by NIR spectroscopy using partial least squares discriminant analysis (PLS-DA) models based on interval principal component analysis (iPCA) method. And the results showed the recognition rate and rejection rate were 100% respectively. In conclusion, Raman spectroscopy and NIR spectroscopy combined with chemometrics are feasible and potential tools for rapid pharmaceutical tablet discrimination. Copyright © 2014 Elsevier B.V. All rights reserved.

  16. Atomic force microscope infrared spectroscopy of griseofulvin nanocrystals.

    Science.gov (United States)

    Harrison, Aaron J; Bilgili, Ecevit A; Beaudoin, Stephen P; Taylor, Lynne S

    2013-12-03

    The goal of this work was to evaluate the ability of photothermal-induced resonance (PTIR) to measure the local infrared absorption spectra of crystalline organic drug nanoparticles embedded within solid matrices. Herein, the first reports of the chemical characterization of sub-100 nm organic crystals are described; infrared spectra of 90 nm griseofulvin particles were obtained, confirming the chemical resolution of PTIR beyond the diffraction limit. Additionally, particle size distributions via dynamic light scattering and PTIR image analysis were found to be similar, suggesting that the PTIR measurements are not significantly affected by inhomogeneous infrared absorptivity of this system. Thus as medical applications increasingly emphasize localized drug delivery via micro/nanoengineered structures, PTIR can be used to unambiguously chemically characterize drug formulations at these length scales.

  17. Far-red to near infrared emission and scattering spectroscopy for biomedical applications

    Science.gov (United States)

    Zhang, Gang

    2001-06-01

    The thesis investigates the far-red and near infrared (NIR) spectral region from biomedical tissue samples for monitoring the state of tissues. The NIR emission wing intensity is weak in comparison to the emission in the visible spectral region. The wing emission from biomedical samples has revealed meaningful information about the state of the tissues. A model is presented to explain the shape of the spectral wing based on a continuum of energy levels. The wing can be used to classify different kinds of tissues; especially it can be used to differentiate cancer part from normal human breast tissues. The research work of the far-red emission from thermal damaged tissue samples shows that the emission intensity in this spectral region is proportional to the extent of the thermal damage of the tissue. Near infrared spectral absorption method is used to investigate blood hemodynamics (perfusion and oxygenation) in brain during sleep-wake transition. The result of the research demonstrates that the continuous wave (CW) type near infrared spectroscopy (NIRS) device can be used to investigate brain blood perfusion and oxygenation with a similar precision with frequency domain (FD) type device. The human subject sleep and wake transition, has been monitored by CW type NIRS instrument with traditional electroencephalograph (EEG) method. Parallel change in oxy-Hb and deoxy-Hb is a discrete event that occurs in the transition from both sleep to wakefulness and wakefulness to sleep. These hemodynamic switches are generally about few seconds delayed from the human decided transition point between sleep and wake on the polygraph EEG recording paper. The combination of NIRS and EEG methods monitor the brain activity, gives more information about the brain activity. The sleep apnea investigation was associated with recurrent apneas, insufficient nasal continuous positive airway pressure (CPAP) and the different response of the peripheral and central compartments to breathing

  18. Provisional maps of thermal areas in Yellowstone National Park, based on satellite thermal infrared imaging and field observations

    Science.gov (United States)

    Vaughan, R. Greg; Heasler, Henry; Jaworowski, Cheryl; Lowenstern, Jacob B.; Keszthelyi, Laszlo P.

    2014-01-01

    Maps that define the current distribution of geothermally heated ground are useful toward setting a baseline for thermal activity to better detect and understand future anomalous hydrothermal and (or) volcanic activity. Monitoring changes in the dynamic thermal areas also supports decisions regarding the development of Yellowstone National Park infrastructure, preservation and protection of park resources, and ensuring visitor safety. Because of the challenges associated with field-based monitoring of a large, complex geothermal system that is spread out over a large and remote area, satellite-based thermal infrared images from the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) were used to map the location and spatial extent of active thermal areas, to generate thermal anomaly maps, and to quantify the radiative component of the total geothermal heat flux. ASTER thermal infrared data acquired during winter nights were used to minimize the contribution of solar heating of the surface. The ASTER thermal infrared mapping results were compared to maps of thermal areas based on field investigations and high-resolution aerial photos. Field validation of the ASTER thermal mapping is an ongoing task. The purpose of this report is to make available ASTER-based maps of Yellowstone’s thermal areas. We include an appendix containing the names and characteristics of Yellowstone’s thermal areas, georeferenced TIFF files containing ASTER thermal imagery, and several spatial data sets in Esri shapefile format.

  19. Spectroscopy

    DEFF Research Database (Denmark)

    Berg, Rolf W.

    This introductory booklet covers the basics of molecular spectroscopy, infrared and Raman methods, instrumental considerations, symmetry analysis of molecules, group theory and selection rules, as well as assignments of fundamental vibrational modes in molecules.......This introductory booklet covers the basics of molecular spectroscopy, infrared and Raman methods, instrumental considerations, symmetry analysis of molecules, group theory and selection rules, as well as assignments of fundamental vibrational modes in molecules....

  20. Land surface temperature retrieved from airborne multispectral scanner mid-infrared and thermal-infrared data.

    Science.gov (United States)

    Qian, Yong-Gang; Wang, Ning; Ma, Ling-Ling; Liu, Yao-Kai; Wu, Hua; Tang, Bo-Hui; Tang, Ling-Li; Li, Chuan-Rong

    2016-01-25

    Land surface temperature (LST) is one of the key parameters in the physics of land surface processes at local/global scales. In this paper, a LST retrieval method was proposed from airborne multispectral scanner data comparing one mid-infrared (MIR) channel and one thermal infrared (TIR) channel with the land surface emissivity given as a priori knowledge. To remove the influence of the direct solar radiance efficiently, a relationship between the direct solar radiance and water vapor content and the view zenith angle and solar zenith angle was established. Then, LST could be retrieved with a split-window algorithm from MIR/TIR data. Finally, the proposed algorithm was applied to the actual airborne flight data and validated with in situ measurements of land surface types in the Baotou site in China on 17 October 2014. The results demonstrate that the difference between the retrieved and in situ LST was less than 1.5 K. The bais, RMSE, and standard deviation of the retrieved LST were 0.156 K, 0.883 K, and 0.869 K, respectively, for samples.

  1. Applications of infrared photo-acoustic spectroscopy for wood samples

    Science.gov (United States)

    Mon-Lin Kuo; John F. McClelland; Siquan Luo; Po-Liang Chien; R.D. Walker; Chung-Yun Hse

    1988-01-01

    Various infrared (IR) spectroscopic techniques for the analysis of wood samples are briefly discussed. Theories and instrumentation of the newly developed photoacoustic spectroscopic (PAS) technique for measuring absorbance spectra of solids are presented. Some important applications of the PAS technique in wood science research are discussed. The application of the...

  2. High resolution mid-infrared spectroscopy based on frequency upconversion

    DEFF Research Database (Denmark)

    Dam, Jeppe Seidelin; Hu, Qi; Tidemand-Lichtenberg, Peter

    2013-01-01

    We present high resolution upconversion of incoherent infrared radiation by means of sum-frequency mixing with a laser followed by simple CCD Si-camera detection. Noise associated with upconversion is, in strong contrast to room temperature direct mid-IR detection, extremely small, thus very faint...

  3. Gemini Near-infrared Spectroscopy of Luminous z~6 Quasars

    DEFF Research Database (Denmark)

    Jiang, Linhua; Fan, Xiaohui; Vestergaard, Marianne

    2007-01-01

    We present Gemini near-infrared spectroscopic observations of six luminous quasars at z=5.8$\\sim$6.3. Five of them were observed using Gemini-South/GNIRS, which provides a simultaneous wavelength coverage of 0.9--2.5 $\\mu$m in cross dispersion mode. The other source was observed in K band with Ge...

  4. Combined autofluorescence and Raman spectroscopy method for skin tumor detection in visible and near infrared regions

    Science.gov (United States)

    Zakharov, V. P.; Bratchenko, I. A.; Artemyev, D. N.; Myakinin, O. O.; Khristoforova, Y. A.; Kozlov, S. V.; Moryatov, A. A.

    2015-07-01

    The combined application of Raman and autofluorescence spectroscopy in visible and near infrared regions for the analysis of malignant neoplasms of human skin was demonstrated. Ex vivo experiments were performed for 130 skin tissue samples: 28 malignant melanomas, 19 basal cell carcinomas, 15 benign tumors, 9 nevi and 59 normal tissues. Proposed method of Raman spectra analysis allows for malignant melanoma differentiating from other skin tissues with accuracy of 84% (sensitivity of 97%, specificity of 72%). Autofluorescence analysis in near infrared and visible regions helped us to increase the diagnostic accuracy by 5-10%. Registration of autofluorescence in near infrared region is realized in one optical unit with Raman spectroscopy. Thus, the proposed method of combined skin tissues study makes possible simultaneous large skin area study with autofluorescence spectra analysis and precise neoplasm type determination with Raman spectroscopy.

  5. Chlorococcalean microalgae Ankistrodesmus convolutes biodiesel characterization with Fourier transform-infrared spectroscopy and gas chromatography mass spectroscopy techniques

    Directory of Open Access Journals (Sweden)

    Swati SONAWANE

    2015-12-01

    Full Text Available The Chlorococcalean microalgae Ankistrodesmus convolutes was found in fresh water Godawari reservoir, Ahmednagar district of Maharashtra State, India. Microalgae are modern biomass for the production of liquid biofuel due to its high solar cultivation efficiency. The collection, harvesting and drying processes were play vital role in converting algal biomass into energy liquid fuel. The oil extraction was the important step for the biodiesel synthesis. The fatty acid methyl ester (FAME synthesis was carried through base catalyzed transesterification method. The product was analyzed by using the hyphened techniques like Fourier Transform-Infrared spectroscopy (FT-IR and Gas Chromatography Mass Spectroscopy (GCMS. FT-IR Spectroscopy was results the ester as functional group of obtained product while the Gas Chromatography Mass Spectroscopy was results the six type of fatty acid methyl ester with different concentration. Ankistrodesmus convolutes biodiesel consist of 46.5% saturated and 49.14% unsaturated FAME.

  6. Active and passive infrared spectroscopy for the detection of environmental threats

    Science.gov (United States)

    Deutsch, Erik R.; Kotidis, Petros; Zhu, Ninghui; Goyal, Anish K.; Ye, Jim; Mazurenko, Alex; Norman, Mark; Zafiriou, Kostas; Baier, Mark; Connors, Ray

    2014-05-01

    Block MEMS/Engineering develops mid-infrared spectroscopy systems based on both Fourier transform infrared (FTIR) spectrometers and quantum cascade lasers (QCLs). Our recently developed miniaturized external-cavity QCLs are widely tunable over a spectral range of >250 cm-1 and tuning can be accomplished at rates of military and commercial applications. This paper provides an overview of our FTIR and QCL systems and their defense-related applications.

  7. Application of Commercial Non-Dispersive Infrared Spectroscopy Sensors for Sub-Ambient Carbon Dioxide Detection

    Science.gov (United States)

    Swickrath, Michael J.; Anderson, Molly; McMillin, Summer; Broerman, Craig

    2012-01-01

    Monitoring carbon dioxide (CO2) concentration within a spacecraft or spacesuit is critically important to ensuring the safety of the crew. Carbon dioxide uniquely absorbs light at wavelengths of 3.95 micrometers and 4.26 micrometers. As a result, non-dispersive infrared (NDIR) spectroscopy can be employed as a reliable and inexpensive method for the quantification of CO2 within the atmosphere. A multitude of commercial off-the-shelf (COTS) NDIR sensors exist for CO2 quantification. The COTS sensors provide reasonable accuracy as long as the measurements are attained under conditions close to the calibration conditions of the sensor (typically 21.1 C (70.0 F) and 1 atmosphere). However, as pressure deviates from atmospheric to the pressures associated with a spacecraft (8.0{10.2 pounds per square inch absolute (psia)) or spacesuit (4.1{8.0 psia), the error in the measurement grows increasingly large. In addition to pressure and temperature dependencies, the infrared transmissivity through a volume of gas also depends on the composition of the gas. As the composition is not known a priori, accurate sub-ambient detection must rely on iterative sensor compensation techniques. This manuscript describes the development of recursive compensation algorithms for sub-ambient detection of CO2 with COTS NDIR sensors. In addition, the source of the exponential loss in accuracy is developed theoretically. The basis of the loss can be explained through thermal, Doppler, and Lorentz broadening effects that arise as a result of the temperature, pressure, and composition of the gas mixture under analysis. This manuscript provides an approach to employing COTS sensors at sub-ambient conditions and may also lend insight into designing future NDIR sensors for aerospace application.

  8. Surface enhanced infrared absorption spectroscopy for graphene functionalization on copper

    Czech Academy of Sciences Publication Activity Database

    Matulková, I.; Kovaříček, Petr; Šlouf, Miroslav; Němec, I.; Kalbáč, Martin

    2017-01-01

    Roč. 124, NOV 2017 (2017), s. 250-255 ISSN 0008-6223 R&D Projects: GA ČR(CZ) GA15-01953S; GA MŠk LL1301; GA MŠk(CZ) LM2015073 Grant - others:AVČR PPPLZ(CZ) L200401551; GA MŠk(CZ) CZ.02.1.01/0.0/0.0/16_013/0001821 Institutional support: RVO:61388955 ; RVO:61389013 Keywords : chemical-vapor-deposition * diazonium salts * raman-spectroscopy * covalent functionalization * seira spectroscopy * grown graphene Subject RIV: CF - Physical ; Theoretical Chemistry OBOR OECD: Physical chemistry Impact factor: 6.337, year: 2016

  9. Characterization of the functional near-infrared spectroscopy response to nociception in a pediatric population.

    Science.gov (United States)

    Olbrecht, Vanessa A; Jiang, Yifei; Viola, Luigi; Walter, Charlotte M; Liu, Hanli; Kurth, Charles D

    2018-02-01

    Near-infrared spectroscopy can interrogate functional optical signal changes in regional brain oxygenation and blood volume to nociception analogous to functional magnetic resonance imaging. This exploratory study aimed to characterize the near-infrared spectroscopy signals for oxy-, deoxy-, and total hemoglobin from the brain in response to nociceptive stimulation of varying intensity and duration, and after analgesic and neuromuscular paralytic in a pediatric population. We enrolled children 6 months-21 years during propofol sedation before surgery. The near-infrared spectroscopy sensor was placed on the forehead and nociception was produced from an electrical current applied to the wrist. We determined the near-infrared spectroscopy signal response to increasing current intensity and duration, and after fentanyl, sevoflurane, and neuromuscular paralytic. Heart rate and arm movement during electrical stimulation was also recorded. The near-infrared spectroscopy signals for oxy-, deoxy-, and total hemoglobin were calculated as optical density*time (area under curve). During electrical stimulation, nociception was evident: tachycardia and arm withdrawal was observed that disappeared after fentanyl and sevoflurane, whereas after paralytic, tachycardia persisted while arm withdrawal disappeared. The near-infrared spectroscopy signals for oxy-, deoxy-, and total hemoglobin increased during stimulation and decreased after stimulation; the areas under the curves were greater for stimulations 30 mA vs 15 mA (13.9 [5.6-22.2], P = .0021; 5.6 [0.8-10.5], P = .0254, and 19.8 [10.5-29.1], P = .0002 for HbO2 , Hb, and HbT , respectively), 50 Hz vs 1 Hz (17.2 [5.8-28.6], P = .0046; 7.5 [0.7-14.3], P = .0314, and 21.9 [4.2-39.6], P = .0177 for HbO2 , Hb, and HbT , respectively) and 45 seconds vs 15 seconds (16.3 [3.4-29.2], P = .0188 and 22.0 [7.5-36.5], P = .0075 for HbO2 and HbT , respectively); the areas under the curves were attenuated by analgesics

  10. Thin-layer infrared spectroscopic study on thermal behavior of non-phospholipid lipids and nanovesicles

    Science.gov (United States)

    Bista, Rajan K.; Bruch, Reinhard F.; Covington, Aaron M.

    2009-02-01

    °The investigation of thermal behaviors and subsequent changes in the conformational order of lipids and liposomes is of importance in understanding various phenomena such as the formation and fusion of vesicles, trans-membrane diffusion and membrane interactions with drugs and proteins. In this work, the thermal behavior of a suite of newly developed self-forming synthetic non-phospholipid (PEGylated) lipids and its nanovesicles in buffer suspensions were investigated by variable-temperature thin-layered Fourier Transform Infrared (FTIR) transmission spectroscopy. The temperature-induced infrared spectra of such lipids composed of 1,2-dimyristoyl-rac-glycerol-3-dodecaethylene glycol (GDM-12) and 1,2-distearoyl-rac-glycerol-3-triicosaethylene glycol (GDS-23) were acquired by using FTIR spectrometer in conjunction with a custom built temperature-controlled demountable liquid cell. In contrast to conventional phospholipids, these novel lipids form liposomes spontaneously upon hydration, without the supply of external activation energy. It was found that the thermal stability of the PEGylated lipids defer greatly depending upon the acyl chain-lengths as well as number of associated head group units. Particularly, GDM-12 (saturated 14 hydrocarbon chains) shows one sharp order-disorder transition with temperature increasing from 3 to 5 °C. Similarly, GDS-23 (saturated 18 hydrocarbon chains) exhibits comparatively broad order-disorder transition profiles between temperature 17 and 22 °C. However, the phase transition temperature becomes significantly higher for lipid nanovesicles formed in aqueous suspensions. The results obtained in this study may find applications in various areas including the development of lipid based substance and drug delivery systems.

  11. [Near Infrared Spectroscopy of the Cretaceous Red Beds in Inner Mongolia Dongshengmiao].

    Science.gov (United States)

    Liao, Yi-peng; Cao, Jian-jin; Wu, Zheng-quan; Luo, Song-ying; Wang, Zheng-yang

    2015-09-01

    Take the cores and surface weathered soil from the Cretaceous red beds in the western of Dongshengmiao mine of Inner Mongolia and analysis with near-infrared spectroscopy. The result shows that near-infrared spectroscopy can identify mineral quickly through the characteristic absorption peaks of each group. The Cretaceous red beds in the western of Dongshengmiao mine is argillaceous cementation, it is mainly composed of quartz, feldspar, montmorillonite, illite, chlorite, muscovite etc, the mineral composition is mainly affected by the upstream source area. The clay mineral like montmorillonite water swelling and uneven drying shrinkage expands the original crack and creates new cracks, reduces its strength, which is the mainly reason of its disintegration. According to the composition of clay mineral, we speculate its weathering process is mainly physical weathering, the climate during the weathering is cold and dry. The results can not only improve the geological feature of the mining area, but also show that the near-infrared spectroscopy technology can analyze the mineral composition of soil and rock effectively on the basis of Mineral spectroscopy, which demonstrates the feasibility of the near-infrared spectroscopy can analyze minerals in soil and rock quickly, that shows the feasibility in geology study, provides new ideas for the future research of soil and rock.

  12. Applications of thermal infrared imagery for energy conservation and environmental surveys

    Science.gov (United States)

    Carney, J. R.; Vogel, T. C.; Howard, G. E., Jr.; Love, E. R.

    1977-01-01

    The survey procedures, developed during the winter and summer of 1976, employ color and color infrared aerial photography, thermal infrared imagery, and a handheld infrared imaging device. The resulting imagery was used to detect building heat losses, deteriorated insulation in built-up type building roofs, and defective underground steam lines. The handheld thermal infrared device, used in conjunction with the aerial thermal infrared imagery, provided a method for detecting and locating those roof areas that were underlain with wet insulation. In addition, the handheld infrared device was employed to conduct a survey of a U.S. Army installation's electrical distribution system under full operating loads. This survey proved to be cost effective procedure for detecting faulty electrical insulators and connections that if allowed to persist could have resulted in both safety hazards and loss in production.

  13. Applications of Micro-Fourier Transform Infrared Spectroscopy (FTIR) in the Geological Sciences—A Review

    Science.gov (United States)

    Chen, Yanyan; Zou, Caineng; Mastalerz, Maria; Hu, Suyun; Gasaway, Carley; Tao, Xiaowan

    2015-01-01

    Fourier transform infrared spectroscopy (FTIR) can provide crucial information on the molecular structure of organic and inorganic components and has been used extensively for chemical characterization of geological samples in the past few decades. In this paper, recent applications of FTIR in the geological sciences are reviewed. Particularly, its use in the characterization of geochemistry and thermal maturation of organic matter in coal and shale is addressed. These investigations demonstrate that the employment of high-resolution micro-FTIR imaging enables visualization and mapping of the distributions of organic matter and minerals on a micrometer scale in geological samples, and promotes an advanced understanding of heterogeneity of organic rich coal and shale. Additionally, micro-FTIR is particularly suitable for in situ, non-destructive characterization of minute microfossils, small fluid and melt inclusions within crystals, and volatiles in glasses and minerals. This technique can also assist in the chemotaxonomic classification of macrofossils such as plant fossils. These features, barely accessible with other analytical techniques, may provide fundamental information on paleoclimate, depositional environment, and the evolution of geological (e.g., volcanic and magmatic) systems. PMID:26694380

  14. Applications of Micro-Fourier Transform Infrared Spectroscopy (FTIR) in the Geological Sciences--A Review.

    Science.gov (United States)

    Chen, Yanyan; Zou, Caineng; Mastalerz, Maria; Hu, Suyun; Gasaway, Carley; Tao, Xiaowan

    2015-12-18

    Fourier transform infrared spectroscopy (FTIR) can provide crucial information on the molecular structure of organic and inorganic components and has been used extensively for chemical characterization of geological samples in the past few decades. In this paper, recent applications of FTIR in the geological sciences are reviewed. Particularly, its use in the characterization of geochemistry and thermal maturation of organic matter in coal and shale is addressed. These investigations demonstrate that the employment of high-resolution micro-FTIR imaging enables visualization and mapping of the distributions of organic matter and minerals on a micrometer scale in geological samples, and promotes an advanced understanding of heterogeneity of organic rich coal and shale. Additionally, micro-FTIR is particularly suitable for in situ, non-destructive characterization of minute microfossils, small fluid and melt inclusions within crystals, and volatiles in glasses and minerals. This technique can also assist in the chemotaxonomic classification of macrofossils such as plant fossils. These features, barely accessible with other analytical techniques, may provide fundamental information on paleoclimate, depositional environment, and the evolution of geological (e.g., volcanic and magmatic) systems.

  15. Thermogravimetry-Infrared Spectroscopy Analysis of the Pyrolysis of Willow Leaves, Stems, and Branches

    Directory of Open Access Journals (Sweden)

    Zhen Liu

    2015-01-01

    Full Text Available The pyrolysis of willow samples from various plant positions was analysed using thermogravimetry-Fourier transform infrared spectroscopy (TG-FTIR. The results indicate that pyrolysis can be divided into four stages. The first stage from 30 to 120°C involves free evaporation of moisture, with a mass loss of 5%. The second stage from 120 to 200°C involves the pyrolysis of hemicellulose and unstable cellulose, with a mass loss of 4%. The third stage is from 200 to 400°C, with a weight loss of 60%, in which the chemical components of wood thermally decompose and emit heat, carbon dioxide, and so on. In the final stage, which occurs above 400°C, the pyrolysis of lignin and charring of cellulose occur, with a mass loss of 10%. Moreover, in FTIR, the samples exhibit the highest absorbance during the main pyrolysis phase, from which wood vinegar ingredients mainly arise, including CO2, H2O, CO, and small amounts of hydrocarbons, alcohols, phenols, acids, esters, and aromatic compounds. Additionally, leaves are decomposed more thoroughly before the main pyrolysis phase, whereas decomposition of branches occurs fullest during this phase. Finally, we put forward some suggestions to support further research on conversion of willow into wood vinegar products.

  16. Fourier transform infrared spectroscopy provides an evidence of papain denaturation and aggregation during cold storage.

    Science.gov (United States)

    Rašković, Brankica; Popović, Milica; Ostojić, Sanja; Anđelković, Boban; Tešević, Vele; Polović, Natalija

    2015-01-01

    Papain is a cysteine protease with wide substrate specificity and many applications. Despite its widespread applications, cold stability of papain has never been studied. Here, we used differential spectroscopy to monitor thermal denaturation process. Papain was the most stabile from 45 °C to 60 °C with ΔG°321 of 13.9±0.3 kJ/mol and Tm value of 84±1 °C. After cold storage, papain lost parts of its native secondary structures elements which gave an increase of 40% of intermolecular β-sheet content (band maximum detected at frequency of 1621 cm(-1) in Fourier transform infrared (FT-IR) spectrum) indicating the presence of secondary structures necessary for aggregation. The presence of protein aggregates after cold storage was also proven by analytical size exclusion chromatography. After six freeze-thaw cycles around 75% of starting enzyme activity of papain was lost due to cold denaturation and aggregation of unfolded protein. Autoproteolysis of papain did not cause significant loss of the protein activity. Upon the cold storage, papain underwent structural rearrangements and aggregation that correspond to other cold denatured proteins, rather than autoproteolysis which could have the commercial importance for the growing polypeptide based industry. Copyright © 2015 Elsevier B.V. All rights reserved.

  17. Applications of Micro-Fourier Transform Infrared Spectroscopy (FTIR in the Geological Sciences—A Review

    Directory of Open Access Journals (Sweden)

    Yanyan Chen

    2015-12-01

    Full Text Available Fourier transform infrared spectroscopy (FTIR can provide crucial information on the molecular structure of organic and inorganic components and has been used extensively for chemical characterization of geological samples in the past few decades. In this paper, recent applications of FTIR in the geological sciences are reviewed. Particularly, its use in the characterization of geochemistry and thermal maturation of organic matter in coal and shale is addressed. These investigations demonstrate that the employment of high-resolution micro-FTIR imaging enables visualization and mapping of the distributions of organic matter and minerals on a micrometer scale in geological samples, and promotes an advanced understanding of heterogeneity of organic rich coal and shale. Additionally, micro-FTIR is particularly suitable for in situ, non-destructive characterization of minute microfossils, small fluid and melt inclusions within crystals, and volatiles in glasses and minerals. This technique can also assist in the chemotaxonomic classification of macrofossils such as plant fossils. These features, barely accessible with other analytical techniques, may provide fundamental information on paleoclimate, depositional environment, and the evolution of geological (e.g., volcanic and magmatic systems.

  18. Discrimination of mineral waters using near infrared spectroscopy and aquaphotomics

    Directory of Open Access Journals (Sweden)

    Munćan Jelena S.

    2014-01-01

    Full Text Available Despite that water is one of the most studied materials today its dynamic properties are still not well understood. Water state in human organism is of high importance for normal healthy functioning of human body. Different kinds of water are usually classified according to its present solutes, and concentrations of these solutes, but though it is known that water molecules can form clusters around present solutes, classification of waters based on types of water molecular organization and present clusters is not present in current literature. In this study we used multivariate analysis for classification of commercial mineral waters based on their near infrared spectra (NIR. Further, we applied Aquaphotomics, a new approach for interpretation of near infrared spectra of water, which gives insight into organization of water molecules in each of these waters.

  19. Near-infrared spectroscopy of 133P/Elst-Pizarro

    Science.gov (United States)

    Rousselot, P.; Dumas, C.; Merlin, F.

    2011-01-01

    Comet 133P/Elst-Pizarro, known to be a main-belt asteroid with a cometary activity, was observed with the near-infrared integral field spectrograph SINFONI at the 8.2-m Very Large Telescope in J, H, and K bands during its 2007 perihelion passage. The goal of these observations was to attempt detection of water ice absorption bands. We present here the details of the data processing, the results of these observations, and our compositional modeling of the final spectrum. No water ice absorptions were detected within the noise of the spectrum but we show that this spectrum is compatible with a reasonable near-infrared albedo value of 7-10% and a mixture of water ice, black carbon, Tholin and silicates. This interpretation, nevertheless, is not unique.

  20. Comparing predictive ability of Laser-Induced Breakdown Spectroscopy to Near Infrared Spectroscopy for soil texture and organic carbon determination

    DEFF Research Database (Denmark)

    Knadel, Maria; Peng, Yi; Gislum, René

    and texture was tested and compared with near infrared spectroscopy (NIRS) technique and traditional laboratory analysis. Calibration models were developed on 50 topsoil samples. For all properties except silt, higher predictive ability of LIBS than NIRS models was obtained. Successful calibrations indicate......Soil organic carbon (SOC) and texture have a practical value for agronomy and the environment. Thus, alternative techniques to supplement or substitute for the expensive conventional analysis of soil are developed. Here the feasibility of laser-induced breakdown spectroscopy (LIBS) to determine SOC...

  1. Predicting Digestibilities of Alfalfa Hays with Near Infrared Reflectance Spectroscopy

    OpenAIRE

    Clark, David H.

    1985-01-01

    Forty-four alfalfa hays from different cuttings, maturities, and locations were fed to sheep in a digestion study. Subsamples of the hays along with corresponding fecal samples were ground and analyzed for dry matter, (DM), organic matter (OM), crude protein (CP), acid detergent fiber (ADF), neutral detergent fiber (NDF), and permanganate lignin. In vivo digestibility (IVDMD) were also determined fro each hay. The hay and fecal samples were scanned with a near infrared reflectance spectrop...

  2. THE INFRARED SPECTROSCOPY OF NEUTRAL POLYCYCLIC AROMATIC HYDROCARBON CLUSTERS

    Energy Technology Data Exchange (ETDEWEB)

    Ricca, Alessandra [Carl Sagan Center, SETI Institute, 189 Bernardo Avenue, Suite 100, Mountain View, CA 94043 (United States); Bauschlicher, Charles W. Jr. [Entry Systems and Technology Division, Mail Stop 230-3, NASA Ames Research Center, Moffett Field, CA 94035 (United States); Allamandola, Louis J., E-mail: Alessandra.Ricca-1@nasa.gov, E-mail: Charles.W.Bauschlicher@nasa.gov [Space Science Division, Mail Stop 245-6, NASA Ames Research Center, Moffett Field, CA 94035 (United States)

    2013-10-10

    The mid-infrared spectra of neutral homogeneous polycyclic aromatic hydrocarbon (PAH) clusters have been computed using density functional theory including an empirical correction for dispersion. The C-H out-of-plane bending modes are redshifted for all the clusters considered in this work. The magnitude of the redshift and the peak broadening are dependent on PAH size, shape, and on the PAH arrangement in the cluster.

  3. Diagnosis with near infrared spectroscopy during minimally invasive procedures

    NARCIS (Netherlands)

    R. Nachabé (Rami)

    2012-01-01

    textabstract The goal of this dissertation is to present the potential of diffuse optical spectroscopy technique to characterize and differentiate types of tissue, including dysplastic and cancerous tissues, when measuring the tissue spectra during a surgical or an interventional procedure under

  4. Diagnosis with near infrared spectroscopy during minimally invasive procedures

    NARCIS (Netherlands)

    R. Nachabé (Rami)

    2012-01-01

    textabstractThe goal of this dissertation is to present the potential of diffuse optical spectroscopy technique to characterize and differentiate types of tissue, including dysplastic and cancerous tissues, when measuring the tissue spectra during a surgical or an interventional procedure under

  5. Airborne measurement of aircraft emissions using passive infrared FT spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Haschberger, P.; Lindermeir, E.; Tank, V. [Deutsche Forschungsanstalt fuer Luft- und Raumfahrt e.V. (DLR), Wessling (Germany). Inst. fuer Optoelektronik

    1997-12-01

    For the first time emissions from aircraft jet engines where measured inflight by use of a Fourier transform infrared spectrometer. The instrument works in a non-intrusive mode observing the plume from the cabin and detecting the emitted infrared radiation. Applying nonlinear inversion techniques the concentrations and emission indices of the infrared active gas components are calculated. Besides CO, CO{sub 2}, and water vapor the separate acquisition of NO and NO{sub 2} is of special interest. For the ATTAS research aircraft as a first carrier the emission index of NO{sub x}, EI(NO{sub x}), is in the range of 5-7.5 g(NO{sub 2})/(kg fuel) with a ratio NO{sub 2}/NO{sub x} of 12-22%. The precision of the measurement system is better than 5%, the estimated accuracy depends on the species and ranges between 5-25%. This report presents a summary of the results including a comparison of measured data and ground-to-altitude correlation models. (orig.) 144 figs., 42 tabs., 497 refs.

  6. Infrared Multiple Photon Dissociation Spectroscopy Of Metal Cluster-Adducts

    Science.gov (United States)

    Cox, D. M.; Kaldor, A.; Zakin, M. R.

    1987-01-01

    Recent development of the laser vaporization technique combined with mass-selective detection has made possible new studies of the fundamental chemical and physical properties of unsupported transition metal clusters as a function of the number of constituent atoms. A variety of experimental techniques have been developed in our laboratory to measure ionization threshold energies, magnetic moments, and gas phase reactivity of clusters. However, studies have so far been unable to determine the cluster structure or the chemical state of chemisorbed species on gas phase clusters. The application of infrared multiple photon dissociation IRMPD to obtain the IR absorption properties of metal cluster-adsorbate species in a molecular beam is described here. Specifically using a high power, pulsed CO2 laser as the infrared source, the IRMPD spectrum for methanol chemisorbed on small iron clusters is measured as a function of the number of both iron atoms and methanols in the complex for different methanol isotopes. Both the feasibility and potential utility of IRMPD for characterizing metal cluster-adsorbate interactions are demonstrated. The method is generally applicable to any cluster or cluster-adsorbate system dependent only upon the availability of appropriate high power infrared sources.

  7. Fourier transform infrared and fluorescence spectroscopy for analysis of vegetable oils

    OpenAIRE

    Nigri S.; Oumeddour R.

    2013-01-01

    Fourier transform infrared (FTIR) and fluorescence spectroscopy, combined with chemometric approaches have been developed to analysis of extra virgin olive oil adulterated with pomace olive oil. The measurements were made on pure vegetable oils: extra virgin oil, pomace olive oil and that adulterated with varying concentration of pomace olive oil. Today, the application of FTIR spectroscopy has increased in food studied, and particularly has become a powerful analytical tool in the study of e...

  8. Application of near-infrared spectroscopy for monitoring and control of cell culture and fermentation

    DEFF Research Database (Denmark)

    Cervera Padrell, Albert Emili; Petersen, Nanna; Eliasson Lantz, Anna

    2009-01-01

    fusion), and the description of process trajectories. On the basis of the review, we conclude that acceptance of NIR spectroscopy as a standard monitoring tool by the fermentation industry will necessitate considerably more on-line studies using industrially relevant—and highly challenging......Near-infrared (NIR) spectroscopy can potentially provide on-line information on substrate, biomass, product, and metabolite concentrations in fermentation processes, which could be useful for improved monitoring or control. However, several factors can negatively influence the quality...

  9. Thermal Infrared Sensor (TIRS) Instrument Thermal Subsystem Design and Lessons Learned

    Science.gov (United States)

    Otero, Veronica; Mosier, Carol; Neuberger, David

    2013-01-01

    The Thermal Infrared Sensor (TIRS) is one of two instruments on the Landsat Data Continuity Mission (LDCM), which is scheduled to launch in February of 2013. The TIRS instrument was officially added to the mission later in the flow, which led to a highly aggressive schedule that became one of the main drivers during instrument development. The thermal subsystem design of the TIRS Sensor Unit is comprised of five thermal zones which range in temperature from less than 43 Kelvin to 330 Kelvin. Most zones are proportional heater controlled, and all are within a volume of 35 cu.ft. A two-stage cryocooler is used to cool the "cold stage" including three QWIP detectors to less than 43 Kelvin, and cool the "warm stage" to 105 Kelvin. The excess power dissipation from the cryocooler is rejected via ammonia transport heat pipes to a dedicated Cryocooler Radiator with embedded ammonia heat pipes. The cryogenic subsystem includes a series of shells used to radiatively and conductively isolate the cold stage from the warmer surroundings. The Optical System (telescope) is passively cooled to 180-190 Kelvin using a "thermal link" (comprised of a Flexible Conductive Thermal Strap and an APG Bar) which couples the telescope stage to a dedicated radiator with embedded ethane heat pipes. The Scene Select Mechanism, which is responsible for moving the Scene Select Mirror to three distinct positions (including Nadir, Space, and On-board Black Body Calibrator pointing), runs nominally at 278 Kelvin and is thermally isolated from the cryogenic thermal zones. The On-board Black Body Calibrator requires a dedicated radiator which allows for a temperature range of 260-330 Kelvin at the Source. The detectors are powered by the FPE Box, which is mounted to the nadir external surface of the composite honeycomb structure. There are two additional electronics boxes which are wet-mounted directly to the spacecraft shear panel, the Main Electronics Box and Cryocooler Electronics Box; thermal

  10. Estimating Clothing Thermal Insulation Using an Infrared Camera

    Directory of Open Access Journals (Sweden)

    Jeong-Hoon Lee

    2016-03-01

    Full Text Available In this paper, a novel algorithm for estimating clothing insulation is proposed to assess thermal comfort, based on the non-contact and real-time measurements of the face and clothing temperatures by an infrared camera. The proposed method can accurately measure the clothing insulation of various garments under different clothing fit and sitting postures. The proposed estimation method is investigated to be effective to measure its clothing insulation significantly in different seasonal clothing conditions using a paired t-test in 99% confidence interval. Temperatures simulated with the proposed estimated insulation value show closer to the values of actual temperature than those with individual clothing insulation values. Upper clothing’s temperature is more accurate within 3% error and lower clothing’s temperature is more accurate by 3.7%~6.2% error in indoor working scenarios. The proposed algorithm can reflect the effect of air layer which makes insulation different in the calculation to estimate clothing insulation using the temperature of the face and clothing. In future, the proposed method is expected to be applied to evaluate the customized passenger comfort effectively.

  11. A Thermal Infrared Radiation Parameterization for Atmospheric Studies

    Science.gov (United States)

    Chou, Ming-Dah; Suarez, Max J.; Liang, Xin-Zhong; Yan, Michael M.-H.; Cote, Charles (Technical Monitor)

    2001-01-01

    This technical memorandum documents the longwave radiation parameterization developed at the Climate and Radiation Branch, NASA Goddard Space Flight Center, for a wide variety of weather and climate applications. Based on the 1996-version of the Air Force Geophysical Laboratory HITRAN data, the parameterization includes the absorption due to major gaseous absorption (water vapor, CO2, O3) and most of the minor trace gases (N2O, CH4, CFCs), as well as clouds and aerosols. The thermal infrared spectrum is divided into nine bands. To achieve a high degree of accuracy and speed, various approaches of computing the transmission function are applied to different spectral bands and gases. The gaseous transmission function is computed either using the k-distribution method or the table look-up method. To include the effect of scattering due to clouds and aerosols, the optical thickness is scaled by the single-scattering albedo and asymmetry factor. The parameterization can accurately compute fluxes to within 1% of the high spectral-resolution line-by-line calculations. The cooling rate can be accurately computed in the region extending from the surface to the 0.01-hPa level.

  12. Estimating Clothing Thermal Insulation Using an Infrared Camera

    Science.gov (United States)

    Lee, Jeong-Hoon; Kim, Young-Keun; Kim, Kyung-Soo; Kim, Soohyun

    2016-01-01

    In this paper, a novel algorithm for estimating clothing insulation is proposed to assess thermal comfort, based on the non-contact and real-time measurements of the face and clothing temperatures by an infrared camera. The proposed method can accurately measure the clothing insulation of various garments under different clothing fit and sitting postures. The proposed estimation method is investigated to be effective to measure its clothing insulation significantly in different seasonal clothing conditions using a paired t-test in 99% confidence interval. Temperatures simulated with the proposed estimated insulation value show closer to the values of actual temperature than those with individual clothing insulation values. Upper clothing’s temperature is more accurate within 3% error and lower clothing’s temperature is more accurate by 3.7%~6.2% error in indoor working scenarios. The proposed algorithm can reflect the effect of air layer which makes insulation different in the calculation to estimate clothing insulation using the temperature of the face and clothing. In future, the proposed method is expected to be applied to evaluate the customized passenger comfort effectively. PMID:27005625

  13. Estimating Clothing Thermal Insulation Using an Infrared Camera.

    Science.gov (United States)

    Lee, Jeong-Hoon; Kim, Young-Keun; Kim, Kyung-Soo; Kim, Soohyun

    2016-03-09

    In this paper, a novel algorithm for estimating clothing insulation is proposed to assess thermal comfort, based on the non-contact and real-time measurements of the face and clothing temperatures by an infrared camera. The proposed method can accurately measure the clothing insulation of various garments under different clothing fit and sitting postures. The proposed estimation method is investigated to be effective to measure its clothing insulation significantly in different seasonal clothing conditions using a paired t-test in 99% confidence interval. Temperatures simulated with the proposed estimated insulation value show closer to the values of actual temperature than those with individual clothing insulation values. Upper clothing's temperature is more accurate within 3% error and lower clothing's temperature is more accurate by 3.7%~6.2% error in indoor working scenarios. The proposed algorithm can reflect the effect of air layer which makes insulation different in the calculation to estimate clothing insulation using the temperature of the face and clothing. In future, the proposed method is expected to be applied to evaluate the customized passenger comfort effectively.

  14. Thermal consequences of colour and near-infrared reflectance.

    Science.gov (United States)

    Stuart-Fox, Devi; Newton, Elizabeth; Clusella-Trullas, Susana

    2017-07-05

    The importance of colour for temperature regulation in animals remains controversial. Colour can affect an animal's temperature because all else being equal, dark surfaces absorb more solar energy than do light surfaces, and that energy is converted into heat. However, in reality, the relationship between colour and thermoregulation is complex and varied because it depends on environmental conditions and the physical properties, behaviour and physiology of the animal. Furthermore, the thermal effects of colour depend as much on absorptance of near-infrared ((NIR), 700-2500 nm) as visible (300-700 nm) wavelengths of direct sunlight; yet the NIR is very rarely considered or measured. The few available data on NIR reflectance in animals indicate that the visible reflectance is often a poor predictor of NIR reflectance. Adaptive variation in animal coloration (visible reflectance) reflects a compromise between multiple competing functions such as camouflage, signalling and thermoregulation. By contrast, adaptive variation in NIR reflectance should primarily reflect thermoregulatory requirements because animal visual systems are generally insensitive to NIR wavelengths. Here, we assess evidence and identify key research questions regarding the thermoregulatory function of animal coloration, and specifically consider evidence for adaptive variation in NIR reflectance.This article is part of the themed issue 'Animal coloration: production, perception, function and application'. © 2017 The Author(s).

  15. Spectroscopy

    CERN Document Server

    Walker, S

    1976-01-01

    The three volumes of Spectroscopy constitute the one comprehensive text available on the principles, practice and applications of spectroscopy. By giving full accounts of those spectroscopic techniques only recently introduced into student courses - such as Mössbauer spectroscopy and photoelectron spectroscopy - in addition to those techniques long recognised as being essential in chemistry teaching - sucha as e.s.r. and infrared spectroscopy - the book caters for the complete requirements of undergraduate students and at the same time provides a sound introduction to special topics for graduate students.

  16. Using the thermal infrared multispectral scanner (TIMS) to estimate surface thermal responses

    Science.gov (United States)

    Luvall, J. C.; Holbo, H. R.

    1987-01-01

    A series of measurements was conducted over the H.J. Andrews, Oregon, experimental coniferous forest, using airborne thermal infrared multispectral scanner (TIMS). Flight lines overlapped, with a 28-min time difference between flight lines. Concurrent radiosonde measurements of atmospheric profiles of air temperature and moisture were used for atmospheric radiance corrections of the TIMS data. Surface temperature differences over time between flight lines were used to develop thermal response numbers (TRNs) which characterized the thermal response (in KJ/sq m/C, where K is the measured incoming solar radiation) of the different surface types. The surface types included a mature forest (canopy dominated by dense crowns of Pseudosuga menziesii, with a secondary canopy of dense Tsuga heterophylla, and also a tall shrub layer of Acer circinatum) and a two-year-old clear-cut. The temperature distribution, within TIMS thermal images was found to reflect the surface type examined. The clear-cut surface had the lowest TRN, while mature Douglas fir the highest.

  17. A massive thermal detector for alpha and gamma spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Alessandrello, A.; Brofferio, C.; Cremonesi, O.; Fiorini, E. E-mail: ettore.fiorini@mi.infn.it; Giuliani, A.; Nucciotti, A.; Pavan, M.; Pirro, S.; Pessina, G.; Parmeggiano, S.; Previtali, E.; Vanzini, M.; Zanotti, L.; Coccia, E.; Fafone, V.; Bucci, C.; Rotilio, A

    2000-02-01

    A massive bolometer with a 760 g TeO{sub 2} crystal as energy absorber, the largest employed underground, has been realized and operated in the Gran Sasso Underground Laboratory for {gamma}- and {alpha}-ray spectroscopy. A new system of mechanical suspensions was implemented to reduce vibration and thermal noise, and special care was put to the read-out electronics. As a consequence the FWHM resolution for high-energy {gamma}-rays became comparable to that of Germanium diodes. The 4.2 keV average FWHM resolution for the 5407 keV line is the best ever obtained for {alpha} particles with any type of detector.

  18. A massive thermal detector for alpha and gamma spectroscopy

    Science.gov (United States)

    Alessandrello, A.; Brofferio, C.; Cremonesi, O.; Fiorini, E.; Giuliani, A.; Nucciotti, A.; Pavan, M.; Pirro, S.; Pessina, G.; Parmeggiano, S.; Previtali, E.; Vanzini, M.; Zanotti, L.; Coccia, E.; Fafone, V.; Bucci, C.; Rotilio, A.

    2000-02-01

    A massive bolometer with a 760 g TeO 2 crystal as energy absorber, the largest employed underground, has been realized and operated in the Gran Sasso Underground Laboratory for γ- and α-ray spectroscopy. A new system of mechanical suspensions was implemented to reduce vibration and thermal noise, and special care was put to the read-out electronics. As a consequence the FWHM resolution for high-energy γ-rays became comparable to that of Germanium diodes. The 4.2 keV average FWHM resolution for the 5407 keV line is the best ever obtained for α particles with any type of detector.

  19. Negative Thermal Expansion Coefficient of Graphene Measured by Raman Spectroscopy

    OpenAIRE

    Yoon, Duhee; Son, Young-Woo; Cheong, Heonsik

    2011-01-01

    The thermal expansion coefficient (TEC) of single-layer graphene is estimated with temperature-dependent Raman spectroscopy in the temperature range between 200 and 400 K. It is found to be strongly dependent on temperature but remains negative in the whole temperature range, with a room temperature value of -8.0x10^{-6} K^{-1}. The strain caused by the TEC mismatch between graphene and the substrate plays a crucial role in determining the physical properties of graphene, and hence its effect...

  20. Negative thermal expansion coefficient of graphene measured by Raman spectroscopy.

    Science.gov (United States)

    Yoon, Duhee; Son, Young-Woo; Cheong, Hyeonsik

    2011-08-10

    The thermal expansion coefficient (TEC) of single-layer graphene is estimated with temperature-dependent Raman spectroscopy in the temperature range between 200 and 400 K. It is found to be strongly dependent on temperature but remains negative in the whole temperature range with a room temperature value of (-8.0 ± 0.7) × 10(-6) K(-1). The strain caused by the TEC mismatch between graphene and the substrate plays a crucial role in determining the physical properties of graphene, and hence its effect must be accounted for in the interpretation of experimental data taken at cryogenic or elevated temperatures.

  1. Landsat-8 Thermal Infrared Sensor (TIRS) Vicarious Radiometric Calibration

    Science.gov (United States)

    Barsi, Julia A.; Shott, John R.; Raqueno, Nina G.; Markham, Brian L.; Radocinski, Robert G.

    2014-01-01

    Launched in February 2013, the Landsat-8 carries on-board the Thermal Infrared Sensor (TIRS), a two-band thermal pushbroom imager, to maintain the thermal imaging capability of the Landsat program. The TIRS bands are centered at roughly 10.9 and 12 micrometers (Bands 10 and 11 respectively). They have 100 m spatial resolution and image coincidently with the Operational Land Imager (OLI), also on-board Landsat-8. The TIRS instrument has an internal calibration system consisting of a variable temperature blackbody and a special viewport with which it can see deep space; a two point calibration can be performed twice an orbit. Immediately after launch, a rigorous vicarious calibration program was started to validate the absolute calibration of the system. The two vicarious calibration teams, NASA/Jet Propulsion Laboratory (JPL) and the Rochester Institute of Technology (RIT), both make use of buoys deployed on large water bodies as the primary monitoring technique. RIT took advantage of cross-calibration opportunity soon after launch when Landsat-8 and Landsat-7 were imaging the same targets within a few minutes of each other to perform a validation of the absolute calibration. Terra MODIS is also being used for regular monitoring of the TIRS absolute calibration. The buoy initial results showed a large error in both bands, 0.29 and 0.51 W/sq m·sr·micrometers or -2.1 K and -4.4 K at 300 K in Band 10 and 11 respectively, where TIRS data was too hot. A calibration update was recommended for both bands to correct for a bias error and was implemented on 3 February 2014 in the USGS/EROS processing system, but the residual variability is still larger than desired for both bands (0.12 and 0.2 W/sq m·sr·micrometers or 0.87 and 1.67 K at 300 K). Additional work has uncovered the source of the calibration error: out-of-field stray light. While analysis continues to characterize the stray light contribution, the vicarious calibration work proceeds. The additional data have

  2. Landsat-8 Thermal Infrared Sensor (TIRS Vicarious Radiometric Calibration

    Directory of Open Access Journals (Sweden)

    Julia A. Barsi

    2014-11-01

    Full Text Available Launched in February 2013, the Landsat-8 carries on-board the Thermal Infrared Sensor (TIRS, a two-band thermal pushbroom imager, to maintain the thermal imaging capability of the Landsat program. The TIRS bands are centered at roughly 10.9 and 12 μm (Bands 10 and 11 respectively. They have 100 m spatial resolution and image coincidently with the Operational Land Imager (OLI, also on-board Landsat-8. The TIRS instrument has an internal calibration system consisting of a variable temperature blackbody and a special viewport with which it can see deep space; a two point calibration can be performed twice an orbit. Immediately after launch, a rigorous vicarious calibration program was started to validate the absolute calibration of the system. The two vicarious calibration teams, NASA/Jet Propulsion Laboratory (JPL and the Rochester Institute of Technology (RIT, both make use of buoys deployed on large water bodies as the primary monitoring technique. RIT took advantage of cross-calibration opportunity soon after launch when Landsat-8 and Landsat-7 were imaging the same targets within a few minutes of each other to perform a validation of the absolute calibration. Terra MODIS is also being used for regular monitoring of the TIRS absolute calibration. The buoy initial results showed a large error in both bands, 0.29 and 0.51 W/m2·sr·μm or −2.1 K and −4.4 K at 300 K in Band 10 and 11 respectively, where TIRS data was too hot. A calibration update was recommended for both bands to correct for a bias error and was implemented on 3 February 2014 in the USGS/EROS processing system, but the residual variability is still larger than desired for both bands (0.12 and 0.2 W/m2·sr·μm or 0.87 and 1.67 K at 300 K. Additional work has uncovered the source of the calibration error: out-of-field stray light. While analysis continues to characterize the stray light contribution, the vicarious calibration work proceeds. The additional data have not changed

  3. The study of 'microsurfaces' using thermal desorption spectroscopy

    Science.gov (United States)

    Thomas, M. E.; Poppa, H.; Pound, G. M.

    1979-01-01

    The use of a newly combined ultrahigh vacuum technique for studying continuous and particulate evaporated thin films using thermal desorption spectroscopy (TDS), transmission electron microscopy (TEM), and transmission electron diffraction (TED) is discussed. It is shown that (1) CO thermal desorption energies of epitaxially deposited (111) Ni and (111) Pd surfaces agree perfectly with previously published data on bulk (111) single crystal, (2) contamination and surface structural differences can be detected using TDS as a surface probe and TEM as a complementary technique, and (3) CO desorption signals from deposited metal coverages of one-thousandth of a monolayer should be detectable. These results indicate that the chemisorption properties of supported 'microsurfaces' of metals can now be investigated with very high sensitivity. The combined use of TDS and TEM-TED experimental methods is a very powerful technique for fundamental studies in basic thin film physics and in catalysis.

  4. Quantitative assessment of pain-related thermal dysfunction through clinical digital infrared thermal imaging

    Directory of Open Access Journals (Sweden)

    Frize Monique

    2004-06-01

    Full Text Available Abstract Background The skin temperature distribution of a healthy human body exhibits a contralateral symmetry. Some nociceptive and most neuropathic pain pathologies are associated with an alteration of the thermal distribution of the human body. Since the dissipation of heat through the skin occurs for the most part in the form of infrared radiation, infrared thermography is the method of choice to study the physiology of thermoregulation and the thermal dysfunction associated with pain. Assessing thermograms is a complex and subjective task that can be greatly facilitated by computerised techniques. Methods This paper presents techniques for automated computerised assessment of thermal images of pain, in order to facilitate the physician's decision making. First, the thermal images are pre-processed to reduce the noise introduced during the initial acquisition and to extract the irrelevant background. Then, potential regions of interest are identified using fixed dermatomal subdivisions of the body, isothermal analysis and segmentation techniques. Finally, we assess the degree of asymmetry between contralateral regions of interest using statistical computations and distance measures between comparable regions. Results The wavelet domain-based Poisson noise removal techniques compared favourably against Wiener and other wavelet-based denoising methods, when qualitative criteria were used. It was shown to improve slightly the subsequent analysis. The automated background removal technique based on thresholding and morphological operations was successful for both noisy and denoised images with a correct removal rate of 85% of the images in the database. The automation of the regions of interest (ROIs delimitation process was achieved successfully for images with a good contralateral symmetry. Isothermal division complemented well the fixed ROIs division based on dermatomes, giving a more accurate map of potentially abnormal regions. The measure

  5. Quantitative assessment of pain-related thermal dysfunction through clinical digital infrared thermal imaging

    Science.gov (United States)

    Herry, Christophe L; Frize, Monique

    2004-01-01

    Background The skin temperature distribution of a healthy human body exhibits a contralateral symmetry. Some nociceptive and most neuropathic pain pathologies are associated with an alteration of the thermal distribution of the human body. Since the dissipation of heat through the skin occurs for the most part in the form of infrared radiation, infrared thermography is the method of choice to study the physiology of thermoregulation and the thermal dysfunction associated with pain. Assessing thermograms is a complex and subjective task that can be greatly facilitated by computerised techniques. Methods This paper presents techniques for automated computerised assessment of thermal images of pain, in order to facilitate the physician's decision making. First, the thermal images are pre-processed to reduce the noise introduced during the initial acquisition and to extract the irrelevant background. Then, potential regions of interest are identified using fixed dermatomal subdivisions of the body, isothermal analysis and segmentation techniques. Finally, we assess the degree of asymmetry between contralateral regions of interest using statistical computations and distance measures between comparable regions. Results The wavelet domain-based Poisson noise removal techniques compared favourably against Wiener and other wavelet-based denoising methods, when qualitative criteria were used. It was shown to improve slightly the subsequent analysis. The automated background removal technique based on thresholding and morphological operations was successful for both noisy and denoised images with a correct removal rate of 85% of the images in the database. The automation of the regions of interest (ROIs) delimitation process was achieved successfully for images with a good contralateral symmetry. Isothermal division complemented well the fixed ROIs division based on dermatomes, giving a more accurate map of potentially abnormal regions. The measure of distance between

  6. Use of Mid- and Near-Infrared Spectroscopy to Track Degradation of Polyactide Eating Utensils and Containers During Composting

    Science.gov (United States)

    Near-infrared spectroscopy (NIRS) has been used for decades for quantitative analysis of many agricultural products including forages, grains and foods, and more recently has become a powerful tool in the analysis of pharmaceutical ingredients and products. Mid-infrared spectroscopy (MIRS) has been ...

  7. Kinetic inductance detectors for far-infrared spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Barlis, A., E-mail: abarlis@physics.upenn.edu [University of Pennsylvania Department of Physics and Astronomy, Philadelphia, Pennsylvania (United States); Aguirre, J. [University of Pennsylvania Department of Physics and Astronomy, Philadelphia, Pennsylvania (United States); Stevenson, T. [NASA Goddard Space Flight Center, Greenbelt, Maryland (United States)

    2016-07-11

    The star formation mechanisms at work in the early universe remain one of the major unsolved problems of modern astrophysics. Many of the luminous galaxies present during the period of peak star formation (at redshift of about 2.5) were heavily enshrouded in dust, which makes observing their properties difficult at optical wavelengths. However, many spectral lines exist at far-infrared wavelengths that serve as tracers of star formation. Here, we describe a detector system suitable for a balloon-borne spectroscopic intensity mapping experiment at far-infrared wavelengths. The system uses lumped-element kinetic inductance detectors (KIDs), which have the potential to achieve high sensitivity and low noise levels. KIDs consist of separate capacitive and inductive elements, and use the inductive element as the radiation absorber. We describe the design considerations, fabrication process, and readout scheme for a prototype LEKID array of 1600 pixels. - Highlights: • We describe a concept for a balloon-borne telescope for far-IR wavelengths. • Telescope would use high-sensitivity kinetic inductance detectors. • Design considerations and fabrication process for prototype detectors.

  8. Is near-infrared spectroscopy clinically useful in the preterm infant?

    DEFF Research Database (Denmark)

    da Costa, Cristine Sortica; Greisen, Gorm; Austin, Topun

    2015-01-01

    Near-infrared spectroscopy (NIRS) has been used to study cerebral haemodynamics and oxygenation in the preterm infant for many years, but its use as a clinical tool has remained elusive. This has partly been due to the challenges of providing a continuous quantitative measurement that is valid...

  9. Use of near infrared spectroscopy to measure the chemical and mechanical properties of solid wood

    Science.gov (United States)

    Stephen S. Kelley; Timothy G. Rials; Rebecca Snell; Leslie H. Groom; Amie Sluiter

    2004-01-01

    Near infrared (NIR) spectroscopy (500 nm-2400 nm), coupled with multivariate analytic (MVA) statistical techniques, have been used to predict the chemical and mechanical properties of solid loblolly pine wood. The samples were selected from different radial locations and heights of three loblolly pine trees grown in Arkansas. The chemical composition and mechanical...

  10. External carotid artery flow maintains near infrared spectroscopy-determined frontal lobe oxygenation during ephedrine administration

    DEFF Research Database (Denmark)

    Sørensen, H; Rasmussen, P; Sato, K

    2014-01-01

    BACKGROUND: Phenylephrine and ephedrine affect frontal lobe oxygenation ([Formula: see text]) differently when assessed by spatially resolved near infrared spectroscopy. We evaluated the effect of phenylephrine and ephedrine on extra- vs intra-cerebral blood flow and on [Formula: see text]. METHODS...

  11. Two-dimensional infrared population transfer spectroscopy for enhancing structural markers of proteins

    NARCIS (Netherlands)

    Jansen, Thomas La Cour; Knoester, Jasper

    2008-01-01

    We propose the possibility of using vibrational population transfer to enhance the structural markers for protein motifs that occur in two-dimensional infrared spectroscopy. We demonstrate the potential of this method by calculating the spectrum of the trpzip2 beta-hairpin peptide, a system that is

  12. Use of near infrared reflectance spectroscopy (NIRS) for predicting soil fertility and historical management.

    NARCIS (Netherlands)

    Freschet, G.T.; Barthès, B.G.; Brunet, D.; Hien, E.; Masse, D.

    2011-01-01

    This study tests the potential of near infrared reflectance spectroscopy (NIRS) for predicting soil fertility and management history from topsoil (0-10 cm deep) spectra. Soil fertility was assessed by measuring the growth of a test plant, and soil management history was determined through inquiries

  13. Polyaniline: The infrared spectroscopy of conducting polymer nanotubes (IUPAC Technical Report)

    Czech Academy of Sciences Publication Activity Database

    Trchová, Miroslava; Stejskal, Jaroslav

    2011-01-01

    Roč. 83, č. 10 (2011), s. 1803-1817 ISSN 0033-4545 R&D Projects: GA MŠk LA09028 Institutional research plan: CEZ:AV0Z40500505 Keywords : aniline oligomers * fourier transform infrared (FTIR) spectroscopy * IUPAC Polymer Division Subject RIV: CD - Macromolecular Chemistry Impact factor: 2.789, year: 2011

  14. Characterisation of structure-dependent functional properties of lignin with infrared spectroscopy

    NARCIS (Netherlands)

    Boeriu, C.G.; Bravo, D.; Gosselink, R.J.A.; Dam, van J.E.G.

    2004-01-01

    Fourier-transformed infrared spectroscopy (FT-IR) was evaluated as an analytical technique for the estimation of the chemical composition and functional properties of lignin. A sample set containing various non-wood, hardwood and softwood lignins isolated by different processing technologies was

  15. Measurement of soy contents in ground beef using near-infrared spectroscopy

    Science.gov (United States)

    Models for determining contents of soy products in ground beef were developed using near-infrared (NIR) spectroscopy. Samples were prepared by mixing four kinds of soybean protein products (Arconet, toasted soy grits, Profam and textured vegetable protein (TVP)) with ground beef (content from 0%–100...

  16. Monitoring tissue oxygen availability with near infrared spectroscopy (NIRS) in health and disease

    DEFF Research Database (Denmark)

    Boushel, Robert Christopher; Langberg, H; Olesen, J

    2001-01-01

    Near infrared spectroscopy (NIRS) is becoming a widely used research instrument to measure tissue oxygen (O2) status non-invasively. Continuous-wave spectrometers are the most commonly used devices, which provide semi-quantitative changes in oxygenated and deoxygenated hemoglobin in small blood v...

  17. Fast determination of the resin and rubber content in Parthenium argentatum biomass using near infrared spectroscopy

    NARCIS (Netherlands)

    Suchat, S.; Pioch, D.; Palu, S.; Tardan, E.; Loo, van E.N.; Davrieux, F.

    2013-01-01

    Guayule (Parthenium argentatum), a plant native of semi-arid regions of northern Mexico and southern Texas, United States, is an under-used source of hypoallergenic latex, a solution to the serious latex allergy IgE problem worldwide. This study aimed to develop near infrared spectroscopy (NIRS)

  18. Near-Infrared Spectroscopy: A Promising Prehospital Tool for Management of Traumatic Brain Injury

    NARCIS (Netherlands)

    Peters, J.H.; Wageningen, B. van; Hoogerwerf, N.; Tan, E.C.T.H.

    2017-01-01

    Introduction Early identification of traumatic brain injury (TBI) is essential. Near-infrared spectroscopy (NIRS) can be used in prehospital settings for non-invasive monitoring and the diagnosis of patients who may require surgical intervention. METHODS: The handheld NIRS Infrascanner (InfraScan

  19. Screening for Breast Cancer Using Near Field Infrared Spectroscopy of a Single Strand of Hair

    National Research Council Canada - National Science Library

    Erramilli, Shyamsunder

    2001-01-01

    ... predisposition to breast cancer because of the breast of a mutation of the BRCA1 gene. We would like to develop a new method for the screening of breast cancer based on infrared spectroscopy of a single strand of human hair...

  20. Intact neurovascular coupling during executive function in migraine without aura: interictal near-infrared spectroscopy study

    DEFF Research Database (Denmark)

    Schytz, H W; Ciftçi, K; Akin, A

    2010-01-01

    An altered neurovascular coupling has been proposed in migraine. We aimed to investigate neurovascular coupling during a mental task interictally in patients with migraine without aura (MO) by near-infrared spectroscopy (NIRS). Twelve migraineurs and 12 healthy controls were included. Using NIRS...

  1. Prefrontal cortex dysfunction during cognitive tests evidenced by functional near-infrared spectroscopy.

    Science.gov (United States)

    Quaresima, Valentina; Giosuè, Patricia; Roncone, Rita; Casacchia, Massimo; Ferrari, Marco

    2009-03-31

    Prefrontal cortex oxygenation changes in response to a verbal fluency task and a visual spatial working memory task were investigated by functional near-infrared spectroscopy (fNIRS) on nine patients with schizophrenia. Four patients were reactive to both tests; five reactive to only one of the two tests, suggesting the importance of reporting fNIRS results for each individual.

  2. The use of skeletal muscle near infrared spectroscopy and a vascular occlusion test at high altitude

    NARCIS (Netherlands)

    Martin, Daniel S.; Levett, Denny Z. H.; Bezemer, Rick; Montgomery, Hugh E.; Grocott, Mike P. W.

    2013-01-01

    Abstract Martin, Daniel, Denny Levett, Rick Bezemer, Hugh Montgomery, and Mike Grocott. The use of skeletal muscle near infrared spectroscopy and a vascular occlusion test at high altitude. High Alt Med Biol 14:256-262, 2013.-Microcirculatory function, central to tissue regulation of oxygen flux,

  3. Near-infrared Spectroscopy Of NEOs: Characterization Of Targets Of The ExploreNEOs (Spitzer) Program

    NARCIS (Netherlands)

    Emery, Joshua P.; Thomas, C. A.; Trilling, D. E.; Dave, R.; Delbo, M.; Mueller, M.

    2010-01-01

    In order to complement the ExploreNEOs program, we are characterizing surface compositions of near-Earth objects (NEOs) with near-infrared (NIR) spectroscopy (0.7 to 2.5 microns). The core ExploreNEOs program is an ambitious exploration of the history of near-Earth space using NASA's Spitzer space

  4. Potential use of visible and near-infrared spectroscopy for pine ...

    African Journals Online (AJOL)

    The correct identification of pine species is necessary for proper application of wood in forest-based industries, since the quality of each species' wood depends on factors intrinsic to the material. The aim of this study was to evaluate the potential use of near-infrared and visible spectroscopy in the discrimination of pine ...

  5. Assessing cerebrovascular autoregulation in infants with necrotizing enterocolitis using near-infrared spectroscopy

    NARCIS (Netherlands)

    Schat, Trijntje E.; van der Laan, Michelle E.; Schurink, Maarten; Hulscher, Jan B. F.; Hulzebos, Christian V.; Bos, Arend F.; Kooi, Elisabeth M. W.

    BACKGROUND: We assessed cerebrovascular autoregulation (CAR) in preterm infants with definite necrotizing enterocolitis (NEC), Bell's stage 2 or 3, and infants without NEC, using near-infrared spectroscopy. We hypothesized that CAR would be more often impaired in infants with NEC compared with

  6. Nondestructive estimation of tracheid length from sections of radial wood strips by near infrared spectroscopy

    Science.gov (United States)

    Laurence R. Schimleck; P. David Jones; Gary F. Peter; F. Daniels; Alexander Clarklll

    2004-01-01

    The use of calibrated near infrared (NIR) spectroscopy for predicting tracheid length of Pinus taeda L. (loblolly pine) wood samples is described. Ten-mm sections of 14 P. taeda radial strips were selected and NIR spectra obtained from the radial longitudinal face of each section. The fibers in these sections were characterized in terms of arithmetic and length-...

  7. Ability of near infrared spectroscopy to monitor air-dry density distribution and variation of wood

    Science.gov (United States)

    Brian K. Via; Chi-Leung So; Todd F. Shupe; Michael Stine; Leslie H. Groom

    2005-01-01

    Process control of wood density with near infrared spectroscopy (NIR) would be useful for pulp mills that need to maximize pulp yield without compromising paper strength properties. If models developed from the absorbance at wavelengths in the NIR region could provide density histograms, fiber supply personnel could monitor chip density variation as the chips enter the...

  8. High resolution scanning of radial strips cut from increment cores by near infrared spectroscopy

    Science.gov (United States)

    P. David Jones; Laurence R. Schimleck; Chi-Leung So; Alexander III Clark; Richard F. Daniels

    2007-01-01

    Near infrared (NIR) spectroscopy provides a rapid method for the determination of wood properties of radial strips. The spatial resolution of the NIR measurements has generally been limited to sections 10 mm wide and as a consequence the estimation of wood properties of individual rings or within rings has not been possible. Many different NIR instruments can be used...

  9. Kinetic and mechanistic studies on the Heck reaction using real-time near infrared spectroscopy

    NARCIS (Netherlands)

    Cruz, S. C.; Aarnoutse, P. J.; Rothenberg, G.; Westerhuis, J. A.; Smilde, A. K.; Bliek, A.

    2003-01-01

    In this paper, Fourier-transform near infrared (FT- NIR) spectroscopy is used to monitor the kinetics of complex catalytic reactions in liquid phase. Gas chromatography ( GC) is used as a reference method. Spectroscopic measurements generate large amounts of data and the calibration is usually

  10. Near-infrared spectroscopy can reveal increases in brain activity related to animal-assisted therapy.

    Science.gov (United States)

    Morita, Yuka; Ebara, Fumio; Morita, Yoshimitsu; Horikawa, Etsuo

    2017-08-01

    [Purpose] Previous studies have indicated that animal-assisted therapy can promote recovery of psychological, social, and physiological function in mental disorders. This study was designed as a pilot evaluation of the use of near-infrared spectroscopy to objectively identify changes in brain activity that could mediate the effect of animal-assisted therapy. [Subjects and Methods] The participants were 20 healthy students (10 males and 10 females; age 19-21 years) of the Faculty of Agriculture, Saga University. Participants were shown a picture of a Tokara goat or shack (control) while prefrontal cortical oxygenated haemoglobin levels (representing neural activity) were measured by near-infrared spectroscopy. [Results] The prefrontal cortical near-infrared spectroscopy signal was significantly higher during viewing of the animal picture than during a rest condition or during viewing of the control picture. [Conclusion] Our results suggest that near-infrared spectroscopy can be used to objectively identify brain activity changes during human mentation regarding animals; furthermore, these preliminary results suggest the efficacy of animal-assisted therapy could be related to increased activation of the prefrontal cortex.

  11. Does depth of the frontal sinus affect near-infrared spectroscopy measurement?

    DEFF Research Database (Denmark)

    Holmgaard, Frederik; Vedel, Anne G; Langkilde, Annika

    2016-01-01

    Near-infrared spectroscopy (NIRS) is a non-invasive method that reflects real-time cerebral oxygenation (rSO2) by the use of two adhesive optodes placed on the forehead of the patient. Frontal sinuses vary anatomically and a large frontal sinus might compromise the NIRS signal since the NIRS...

  12. Examination of Bond Properties through Infrared Spectroscopy and Molecular Modeling in the General Chemistry Laboratory

    Science.gov (United States)

    Csizmar, Clifford M.; Force, Dee Ann; Warner, Don L.

    2012-01-01

    A concerted effort has been made to increase the opportunities for undergraduate students to address scientific problems employing the processes used by practicing chemists. As part of this effort, an infrared (IR) spectroscopy and molecular modeling experiment was developed for the first-year general chemistry laboratory course. In the…

  13. Regional blood flow during exercise in humans measured by near-infrared spectroscopy and indocyanine green

    DEFF Research Database (Denmark)

    Boushel, R; Langberg, Henning; Olesen, J

    2000-01-01

    Using near-infrared spectroscopy (NIRS) and the tracer indocyanine green (ICG), we quantified blood flow in calf muscle and around the Achilles tendon during plantar flexion (1-9 W). For comparison, blood flow in calf muscle was determined by dye dilution in combination with magnetic resonance...

  14. Targeted and Untargeted Detection of Skim Milk Powder Adulteration by Near-Infrared Spectroscopy

    NARCIS (Netherlands)

    Capuano, Edoardo; Boerrigter-Eenling, Rita; Koot, Alex; Ruth, van S.M.

    2015-01-01

    In the present study, near-infrared spectroscopy (NIRS) was explored as a fast and reliable screening method for the detection of adulteration of skim milk powder (SMP). Sixty genuine SMP were adulterated with acid whey (1–25 % w/w), starch (2 and 5 %) and maltodextrin (2 and 5 %) for a total of

  15. Alkali metal ion binding to glutamine and glutamine derivatives investigated by infrared action spectroscopy and theory

    NARCIS (Netherlands)

    Bush, M. F.; Oomens, J.; Saykally, R. J.; Williams, E. R.

    2008-01-01

    The gas-phase structures of alkali-metal cationized glutamine are investigated by using both infrared multiple photon dissociation (TRMPD) action spectroscopy, utilizing light generated by a free electron laser, and theory. The IRMPD spectra contain many similarities that are most consistent with

  16. Limitations and potential of spectral subtractions in fourier-transform infrared (FTIR) spectroscopy of soil samples

    Science.gov (United States)

    Soil science research is increasingly applying Fourier transform infrared (FTIR) spectroscopy for analysis of soil organic matter (SOM). However, the compositional complexity of soils and the dominance of the mineral component can limit spectroscopic resolution of SOM and other minor components. The...

  17. Phenylephrine increases near-infrared spectroscopy determined muscle oxygenation in men

    DEFF Research Database (Denmark)

    Sørensen, H.; Thomsen, J. H.; Meyer, A. S. Ps

    2017-01-01

    Phenylephrine increases mean arterial pressure (MAP) by enhanced total peripheral resistance (TPR) but near-infrared spectroscopy (NIRS) determined muscle oxygenation (SmO2) increases. We addressed that apparent paradox during supine rest and head-up tilt (HUT). Variables were determined ± phenyl...

  18. Determining the clay/organic carbon ratio by visible near infrared spectroscopy

    DEFF Research Database (Denmark)

    Knadel, Maria; Peng, Yi; Hermansen, Cecilie

    /OC ratio directly would be valuable. Visible near infrared spectroscopy (vis-NIRS) is a cost-effective method for soil analysis and was tested here for the prediction of clay/OC ratio. Soil samples from two agricultural fields in Denmark (N=115) were analyzed. Partial Least Squares regression (full cross...

  19. Near infrared spectroscopy (NIRS) to monitor tissue haemoglobin (and myoglobin) oxygenation

    NARCIS (Netherlands)

    Scheeren, T. W. L.

    2010-01-01

    Introduction: Tissue oxygenation may be monitored noninvasively by near infrared spectroscopy (NIRS) both on the thenar eminescence (muscle) and on the forehead (brain). Thenar measurement have been used to guide therapy in trauma patients ( 1 ) and to determine the prognosis of septic patients ( 2

  20. Ultrasound tagged near infrared spectroscopy does not detect hyperventilation-induced reduction in cerebral blood flow

    DEFF Research Database (Denmark)

    Lund, Anton; Secher, Niels H.; Hirasawa, Ai

    2016-01-01

    Introduction: Continuous non-invasive monitoring of cerebral blood flow (CBF) may be important during anaesthesia and several options are available. We evaluated the CerOx monitor that employs ultrasound tagged near infrared spectroscopy to estimate changes in a CBF index (CFI).Methods: Seven hea...

  1. The use of near infrared spectroscopy (NIRS) to predict the chemical ...

    African Journals Online (AJOL)

    The wet chemical analysis of feed samples is time consuming and expensive. Near infrared spectroscopy (NIRS) was developed as a rapid technique to predict the chemical composition of feeds. The prediction of accuracy of NIRS relies heavily on obtaining a calibration set which represents the variation in the main ...

  2. Citrus species and hybrids depicted by near and mid infrared spectroscopy.

    Science.gov (United States)

    Páscoa, Ricardo N M J; Moreira, Silvana; Lopes, João A; Sousa, Clara

    2018-01-31

    Citrus trees are one of the most cultivated plants around the world with high economic impact. The wide sexual compatibility among relatives gave rise to a large number of hybrids which are difficult to discriminate. This work sought to explore the ability of infrared spectroscopy to discriminate among Citrus species and/or hybrids and to contribute to the elucidation of its relatedness. Adults leaves of eighteen distinct Citrus plants were included in this work. Near and mid infrared (NIR and FTIR) leaves spectra were acquired after harvesting and a drying period of one month. Spectra were modelled by principal component analysis and partial least squares discriminant analysis. Both techniques revealed a high discrimination potential (78.5-95.9%) being the best results achieved with NIR spectroscopy and air-dried leaves (95.9%). Infrared spectroscopy was able to successfully discriminate several Citrus species and/or hybrids. Our results also contributed to enhance the insights about the studied Citrus species and/or hybrids. Despite the benefit of including additional samples, the results herein obtained clearly shown that infrared spectroscopy as a reliable technique for Citrus species and/or hybrids discrimination. This article is protected by copyright. All rights reserved.

  3. Review of multidimensional data processing approaches for Raman and infrared spectroscopy

    NARCIS (Netherlands)

    Gautam, R.; Vanga, S.; Ariese, F.

    2015-01-01

    Raman and Infrared (IR) spectroscopies provide information about the structure, functional groups and environment of the molecules in the sample. In combination with a microscope, these techniques can also be used to study molecular distributions in heterogeneous samples. Over the past few decades

  4. Nanoscale infrared spectroscopy as a non-destructive probe of extraterrestrial samples.

    Science.gov (United States)

    Dominguez, Gerardo; Mcleod, A S; Gainsforth, Zack; Kelly, P; Bechtel, Hans A; Keilmann, Fritz; Westphal, Andrew; Thiemens, Mark; Basov, D N

    2014-12-09

    Advances in the spatial resolution of modern analytical techniques have tremendously augmented the scientific insight gained from the analysis of natural samples. Yet, while techniques for the elemental and structural characterization of samples have achieved sub-nanometre spatial resolution, infrared spectral mapping of geochemical samples at vibrational 'fingerprint' wavelengths has remained restricted to spatial scales >10 μm. Nevertheless, infrared spectroscopy remains an invaluable contactless probe of chemical structure, details of which offer clues to the formation history of minerals. Here we report on the successful implementation of infrared near-field imaging, spectroscopy and analysis techniques capable of sub-micron scale mineral identification within natural samples, including a chondrule from the Murchison meteorite and a cometary dust grain (Iris) from NASA's Stardust mission. Complementary to scanning electron microscopy, energy-dispersive X-ray spectroscopy and transmission electron microscopy probes, this work evidences a similarity between chondritic and cometary materials, and inaugurates a new era of infrared nano-spectroscopy applied to small and invaluable extraterrestrial samples.

  5. Functional Near-Infrared Spectroscopy for the Assessment of Speech Related Tasks

    Science.gov (United States)

    Dieler, A. C.; Tupak, S. V.; Fallgatter, A. J.

    2012-01-01

    Over the past years functional near-infrared spectroscopy (fNIRS) has substantially contributed to the understanding of language and its neural correlates. In contrast to other imaging techniques, fNIRS is well suited to study language function in healthy and psychiatric populations due to its cheap and easy application in a quiet and natural…

  6. Prefrontal Dysfunction in Attention-Deficit/Hyperactivity Disorder as Measured by Near-Infrared Spectroscopy

    Science.gov (United States)

    Negoro, Hideki; Sawada, Masayuki; Iida, Junzo; Ota, Toyosaku; Tanaka, Shohei; Kishimoto, Toshifumi

    2010-01-01

    Recent developments in near-infrared spectroscopy (NIRS) have enabled non-invasive clarification of brain functions in psychiatric disorders with measurement of hemoglobin concentrations as cerebral blood volume. Twenty medication-naive children with attention-deficit/hyperactivity disorder (ADHD) and 20 age- and sex-matched healthy control…

  7. Application of near-infrared spectroscopy to preservative-treated wood

    Science.gov (United States)

    Chi-Leung So; Stan T. Lebow; Thomas L. Eberhardt; Leslie H. Groom; Todd F. Shupe

    2009-01-01

    Near infrared (NIR) spectroscopy is now a widely-used technique in the field of forest products, especially for physical and mechanical property determinations. This technique is also ideal for the chemical analysis of wood. There has been a growing need to find a rapid, inexpensive and reliable method to distinguish between preservative-treated and untreated waste...

  8. Process analytical chemistry in the distillation industry using near-infrared spectroscopy

    NARCIS (Netherlands)

    vandenBerg, F. W. J.; vanOsenbruggen, W. A.; Smilde, A. K.

    1997-01-01

    Process analytical chemistry is a subdiscipline of analytical chemistry devoted to chemical measurements on processes. This paper reports the results of a feasibility study on ethanol determination during the production of alcoholic beverages. In this study near-infrared spectroscopy will be used to

  9. Screening suspected counterfeit Viagra and imitations of Viagra with near-infrared spectroscopy.

    NARCIS (Netherlands)

    Vredenbregt, M J; Blok-Tip, L; Hoogerbrugge, Ronald; Barends, D M; Kaste, D de

    2006-01-01

    We describe a near-infrared spectroscopy (NIRS) method for fast-screening Viagra tablets, counterfeit Viagra tablets, and imitations of Viagra. The method can (1) check the homogeneity of a batch; (2) distinguish counterfeits and imitations from authentic Viagra; (3) screen for the presence of

  10. The use of near infra-red reflectance spectroscopy for the ...

    African Journals Online (AJOL)

    The applicability of the NIRS ryegrass calibration to other species was briefly examined by estimating the N content of Kikuyu (Penisetum clandestinum) (r = 0, 97 and SEP = 0, 277). Keywords: italian ryegrass; kikuyu; lolium multiflorum; near infra-red spectroscopy; nitrogen; plant physiology; protein; regression analysis; ...

  11. Rapid biochemical methane potential prediction of urban organic waste with near-infrared reflectance spectroscopy

    DEFF Research Database (Denmark)

    Fitamo, Temesgen Mathewos; Triolo, Jin Mi; Boldrin, Alessio

    2017-01-01

    . The aim of the present study is to develop a fast and reliable model based on near-infrared reflectance spectroscopy (NIRS) for the BMP prediction of urban organic waste (UOW). The model comprised 87 UOW samples. Additionally, 88 plant biomass samples were included, to develop a combined model predicting...

  12. Quasi-thermal noise spectroscopy: The art and the practice

    Science.gov (United States)

    Meyer-Vernet, N.; Issautier, K.; Moncuquet, M.

    2017-08-01

    Quasi-thermal noise spectroscopy is an efficient tool for measuring in situ macroscopic plasma properties in space, using a passive wave receiver at the ports of an electric antenna. This technique was pioneered on spinning spacecraft carrying very long dipole antennas in the interplanetary medium—like ISEE-3 and Ulysses—whose geometry approached a "theoretician's dream." The technique has been extended to other instruments in various types of plasmas on board different spacecraft and will be implemented on several missions in the near future. Such extensions require different theoretical modelizations, involving magnetized, drifting, or dusty plasmas with various particle velocity distributions and antennas being shorter, biased, or made of unequal wires. We give new analytical approximations of the plasma quasi-thermal noise (QTN) and study how the constraints of the real world in space can (or cannot) be compatible with plasma detection by QTN spectroscopy. We consider applications to the missions Wind, Cassini, BepiColombo, Solar Orbiter, and Parker Solar Probe.

  13. Compact Micromachined Bandpass Filters for Infrared Planetary Spectroscopy

    Science.gov (United States)

    Brown, Ari D.; Aslam, Shahid; Chervenak, James A.; Huang, Wei-Chung; Merrell, Willie; Quijada, Manuel

    2011-01-01

    The thermal instrument strawman payload of the Jupiter Europa Orbiter on the Europa Jupiter Science Mission will map out thermal anomalies, the structure, and atmospheric conditions of Europa and Jupiter within the 7-100 micron spectral range. One key requirement for the payload is that the mass cannot exceed 3.7 kg. Consequently, a new generation of light-weight miniaturized spectrometers needs to be developed. On the path toward developing these spectrometers is development of ancillary miniaturized spectroscopic components. In this paper, we present a strategy for making radiation hard and low mass FIR band pass metal mesh filters. Our strategy involves using MEMS-based fabrication techniques, which will permit the quasi-optical filter structures to be made with micron-scale precision. This will enable us to achieve tight control over both the pass band of the filter and the micromachined silicon support structure architecture, which will facilitate integration of the filters for a variety of applications.

  14. [The research progress in determining lignocellulosic content by near infrared reflectance spectroscopy technology].

    Science.gov (United States)

    Du, Juan; An, Dong; Xia, Tian; Huang, Yan-Hua; Li, Hong-Chao; Zhang, Yun-Wei

    2013-12-01

    Near infrared reflectance spectroscopy technology, as a new analytic method, can be used to determine the content of lignin, cellulose and hemi-cellulose which is faster, effective, easier to operate, and more accurate than the traditional wet chemical methods. Nowadays it has been widely used in measuring the composition of lignocelluloses in woody plant and herbaceous plant. The domestic and foreign research progress in determining the lignin, cellulose and hemi-cellulose content in woody plant ( wood and bamboo used as papermaking raw materials and wood served as potential biomass energy) and herbaceous plant (forage grass and energy grass) by near infrared reflectance spectroscopy technology is comprehensively summarized and the advances in method studies of measuring the composition of lignocelluloses by near infrared reflectance spectroscopy technology are summed up in three aspects, sample preparation, spectral data pretreatment and wavelength selection methods, and chemometric analysis respectively. Four outlooks are proposed combining the development statues of wood, forage grass and energy grass industry. First of all, the authors need to establish more feasible and applicable models for a variety of uses which can be used for more species from different areas, periods and anatomical parts. Secondly, comprehensive near infrared reflectance spectroscopy data base of grass products quality index needs to be improved to realize on-line quality and process control in grassproducts industry, which can guarantee the quality of the grass product. Thirdly, the near infrared reflectance spectroscopy quality index model of energy plant need to be built which can not only contribute to breed screening, but also improve the development of biomass industry. Besides, modeling approaches are required to be explored and perfected any further. Finally, the authors need to try our best to boost the advancement in the determination method of lignin, cellulose and hemi

  15. Applications of Infrared and Raman Spectroscopies to Probiotic Investigation

    Directory of Open Access Journals (Sweden)

    Mauricio I. Santos

    2015-07-01

    Full Text Available In this review, we overview the most important contributions of vibrational spectroscopy based techniques in the study of probiotics and lactic acid bacteria. First, we briefly introduce the fundamentals of these techniques, together with the main multivariate analytical tools used for spectral interpretation. Then, four main groups of applications are reported: (a bacterial taxonomy (Subsection 4.1; (b bacterial preservation (Subsection 4.2; (c monitoring processes involving lactic acid bacteria and probiotics (Subsection 4.3; (d imaging-based applications (Subsection 4.4. A final conclusion, underlying the potentialities of these techniques, is presented.

  16. Renal geology (quantitative renal stone analysis) by 'Fourier transform infrared spectroscopy'.

    Science.gov (United States)

    Singh, Iqbal

    2008-01-01

    To prospectively determine the precise stone composition (quantitative analysis) by using infrared spectroscopy in patients with urinary stone disease presenting to our clinic. To determine an ideal method for stone analysis suitable for use in a clinical setting. After routine and a detailed metabolic workup of all patients of urolithiasis, stone samples of 50 patients of urolithiasis satisfying the entry criteria were subjected to the Fourier transform infrared spectroscopic analysis after adequate sample homogenization at a single testing center. Calcium oxalate monohydrate and dihydrate stone mixture was most commonly encountered in 35 (71%) followed by calcium phosphate, carbonate apatite, magnesium ammonium hexahydrate and xanthine stones. Fourier transform infrared spectroscopy allows an accurate, reliable quantitative method of stone analysis. It also helps in maintaining a computerized large reference library. Knowledge of precise stone composition may allow the institution of appropriate prophylactic therapy despite the absence of any detectable metabolic abnormalities. This may prevent and or delay stone recurrence.

  17. IDENTIFICATION OF ADULTERANT AND ALCOHOL ROUTE IN BIODIESEL USING MID-INFRARED ABSORPTION SPECTROSCOPY

    Directory of Open Access Journals (Sweden)

    Maryleide Ventura da Silva

    2014-01-01

    Full Text Available Mid-infrared absorption spectroscopy was used to analyze soybean oil, ethylic and methylic soybean biodiesel, and blends prepared with soybean oil mixed with biodiesel, in order to evaluate this method as an alternative to assess oil as impurities or adulterant in biodiesel. We also aimed to determine whether the biodiesel was prepared by the ethyl or methyl routes, by inspecting the infrared spectra. The C-O functional groups between 1100 and 1200 cm-1 are different for oil and biodiesel, which allows them to be used to distinguish impurities (residual oil in biofuel. The peak C-O-C at 1017 cm-1 is characteristic for methylic biodiesel, and the peak O-C-C at 1035 cm-1 for ethylic biodiesel. These vibrational modes can therefore be used to indicate the route used to prepare the biofuel. Results indicated that infrared spectroscopy is appropriate for monitoring the quality of biofuel for commercial sale.

  18. Application of infrared spectroscopy and pyrolysis gas chromatography for characterisation of adhesive tapes

    Science.gov (United States)

    Zięba-Palus, Janina; Nowińska, Sabina; Kowalski, Rafał

    2016-12-01

    Infrared spectroscopy and pyrolysis GC/MS were applied in the comparative analysis of adhesive tapes. By providing information about the polymer composition, it was possible to classify both backings and adhesives of tapes into defined chemical classes. It was found that samples of the same type (of backings and adhesives) and similar infrared spectra can in most cases be effectively differentiated using Py-GC/MS, sometimes based only on the presence of peaks of very low intensity originating from minor components. The results obtained enabled us to draw the conclusion that Py-GC/MS appears to be a valuable analytical technique for examining tapes, which is complementary to infrared spectroscopy. Identification of pyrolysis products enables discrimination of samples. Both methods also provide crucial information that is useful for identification of adhesive tapes found at the crime scene.

  19. Trans-cranial infrared laser stimulation induces hemodynamic and metabolic response measured by broadband near infrared spectroscopy in vivo on human forehead (Conference Presentation)

    Science.gov (United States)

    Wang, Xinlong; Nalawade, Sahil Sunil; Reddy, Divya Dhandapani; Tian, Fenghua; Gonzalez-Lima, F.; Liu, Hanli

    2017-02-01

    Transcranial infrared laser stimulation (TILS) uses infrared light (lasers or LEDs) for nondestructive and non-thermal photobiomodulation on the human brain. Although TILS has shown its beneficial effects to a variety of neurological and psychological conditions, its physiological mechanism remains unknown. Cytochrome-c-oxidase (CCO), the last enzyme in the electron transportation chain, is proposed to be the primary photoacceptor of this infrared laser. In this study, we wish to validate this proposed mechanism. We applied 8 minutes in vivo TILS on the right forehead of 11 human participants with a 1064-nm laser. Broad-band near infrared spectroscopy (bb-NIRS) from 740-900nm was also employed near the TILS site to monitor hemodynamic and metabolic responses during the stimulation and 5-minute recovery period. For rigorous comparison, we also performed similar 8-min bb-NIR measurements under placebo conditions. A multi-linear regression analysis based on the modified Beer-Lambert law was performed to estimate concentration changes of oxy-hemoglobin (Δ[HbO]), deoxy-hemoglobin (Δ[Hb]), and cytochrome-c-oxidase (Δ[CCO]). We found that TILS induced significant increases of [CCO], [HbO] and a decrease of [Hb] with dose-dependent manner as compared with placebo treatments. Furthermore, strong linear relationships or interplays between [CCO] versus [HbO] and [CCO] versus [Hb] induced by TILS were observed in vivo for the first time. These relationships have clearly revealed close coupling/relationship between the hemodynamic oxygen supply and blood volume versus up-regulation of CCO induced by photobiomodulation. Our results demonstrate the tremendous potential of bb-NIRS as a non-invasive in vivo means to study photobiomodulation mechanisms and perform treatment evaluations of TILS.

  20. Non-linear calibration models for near infrared spectroscopy

    DEFF Research Database (Denmark)

    Ni, Wangdong; Nørgaard, Lars; Mørup, Morten

    2014-01-01

    -linear models on linear problems, robustness to small or medium sample sets, and robustness to pre-processing, are discussed. The results suggest that GPR and BANN are powerful and promising methods for handling linear as well as nonlinear systems, even when the data sets are moderately small. The LS......-SVM), relevance vector machines (RVM), Gaussian process regression (GPR), artificial neural network (ANN), and Bayesian ANN (BANN). In this comparison, partial least squares (PLS) regression is used as a linear benchmark, while the relationship of the methods is considered in terms of traditional calibration...... by ridge regression (RR). The performance of the different methods is demonstrated by their practical applications using three real-life near infrared (NIR) data sets. Different aspects of the various approaches including computational time, model interpretability, potential over-fitting using the non...

  1. Infrared diode laser spectroscopy of the LiO radical

    Science.gov (United States)

    Yamada, Chikashi; Hirota, Eizi

    1993-12-01

    The fundamental vibrational band of the 7LiO radical in the ground electronic state X 2Πi was observed in a region from 720 to 850 cm-1 using a source frequency modulation infrared diode laser spectrometer. Radicals were generated in a high-temperature cell by the reaction of lithium metal vapor with nitrous oxide. The observed spectrum was analyzed together with the radio-frequency and microwave spectra already reported. It was found that the vibration-rotation Hamiltonian employed in a previous paper was insufficient to fit all of the observed spectra simultaneously. The Hamiltonian was thus extended to include higher-order corrections for the centrifugal distortion and Λ-type doubling terms, and was used to derive molecular parameters.

  2. Portable microcontroller-based instrument for near-infrared spectroscopy

    Science.gov (United States)

    Giardini, Mario E.; Corti, Mario; Lago, Paolo; Gelmetti, Andrea

    2000-05-01

    Near IR Spectroscopy (NIRS) can be employed to noninvasively and continuously measure in-vivo local changes in haemodynamics and oxygenation of human tissues. In particular, the technique can be particularly useful for muscular functional monitoring. We present a portable NIRS research-grade acquisition system prototype, strictly dedicate to low-noise measurements during muscular exercise. The prototype is able to control four LED sources and a detector. Such a number of sources allows for multipoint measurements or for multi-wavelength spectroscopy of tissue constituents other than oxygen, such as cytochrome aa3 oxidation. The LEDs and the detector are mounted on separate probes, which carry also the relevant drivers and preamplifiers. By employing surface-mount technologies, probe size and weight are kept to a minimum. A single-chip mixed-signal RISC microcontroller performs source-to- detector multiplexing with a digital correlation technique. The acquired data are stored on an on-board 64 K EEPROM bank, and can be subsequently uploaded to a personal computer via serial port for further analysis. The resulting instrument is compact and lightweight. Preliminary test of the prototype on oxygen consumption during tourniquet- induced forearm ischaemia show adequate detectivity and time response.

  3. Quality control of tablets by Near Infrared (NIR)-Spectroscopy.

    Science.gov (United States)

    Petri, J; Kaunzinger, A; Niemöller, A; Karas, M

    2005-10-01

    Today, NIR-spectroscopy is an established analytical technique not only in the identification of raw materials but also in the quantification of active ingredients in tablets. In this work calibration models were set up with tablets of the same active ingredient but of miscellaneous origin and manufacturess. Consequently the tablets had different excipients and appearance. The pharmaceutical preparations used included atenolol 100 mg tablets, enalapril 20 mg tablets and acetylsalicylic acid (ASS) tablets of different dosage units. In order to proof if the calibration models set up are generally feasible the assay declared by the manufacturer was used to calculate the partial least square (PLS) calibration. With respect to enalapril tablets simultaneous analysis by HPLC, according to USP 26 was carried out. It was investigated if such methods allow a determination of active ingredients in tablets within limits of +/- 10% of declaration. It was shown that it is possible to set up calibration models to quantify active ingredients in tablets independent of adjuvants or optical appearance. Additionally it could be shown that NIR-spectroscopy is also applicable to determine the concentration of active ingredients in blister-packed tablets.

  4. [Application and recent development of research on near-infrared spectroscopy for meat quality evaluation].

    Science.gov (United States)

    Xu, Xia; Cheng, Fang; Ying, Yi-Bin

    2009-07-01

    As one of new optical detection methods, near-infrared spectroscopy (NIRS) technique has been widely used in food industry in recent years. NIRS technique is also promising for quality evaluation of meat and meat products and is characterized by its quickness, online operation and nondestructive detection. The present paper reviews the main application and recent development of research on near-infrared spectroscopy in meat industry, including components analysis, sensory quality evaluation as well as discrimination of production. It's necessary to determine the content of main chemical components in a variety of meat such as protein, fat, water etc as they exert important influence on meat quality. Sensory quality including tenderness, water holding capacity, color, and freshness is commonly evaluated by human sensory system. Thus there is an obvious potential profit to achieve online determination industrialization for meat quality. Additionally the utilization of NIRS in quality detection of common meat products is particularized in this paper. Most study of near-infrared spectroscopy technique for meat quality evaluation lays emphasis on component analysis that especially has shown a progress in the determination of protein, fat, water and part of fatty acid, which has been investigated much recently. Not any kind of sensory quality can be well predicted by NIRS as it depends on the species of meat and the limitation of this optical technique. Therein beef is the mostly used object with many reports on the evaluation of tenderness compared to other types. There is a lot of investigation for sensory quality detection of pork on water holding capacity etc. Meanwhile this review also tries to come up with some perspectives on meat quality detection with near-infrared spectroscopy according to current development trend: on the basis of deeply improving the meat detection precision, near-infrared spectroscopy technique combined with other non-detection techniques

  5. Thermal infrared images to quantify thermal ablation effects of acid and base on target tissues

    Directory of Open Access Journals (Sweden)

    Ran Liu

    2015-07-01

    Full Text Available Hyperthermia (42-46°C, treatment of tumor tissue through elevated temperature, offers several advantages including high cost-effectiveness, highly targeted ablation and fewer side effects and hence higher safety level over traditional therapies such as chemotherapy and radiotherapy. Recently, hyperthermia using heat release through exothermic acid-base neutralization comes into view owing to its relatively safe products of salt and water and highly confined ablation. However, lack of quantitative understanding of the spatial and temporal temperature profiles that are produced by simultaneous diffusion of liquid chemical and its chemical reaction within tumor tissue impedes the application of this method. This article is dedicated to quantify thermal ablation effects of acid and base both individually and as in neutralization via infrared captured thermal images. A theoretical model is used to approximate specific heat absorption rate (SAR based on experimental measurements that contrast two types of tissue, normal pork and pig liver. According to the computation, both pork and liver tissue has a higher ability in absorbing hydrochloric acid (HCl than sodium hydroxide, hence suggesting that a reduced dosage for HCl is appropriate in a surgery. The heating effect depends heavily on the properties of tissue types and amount of chemical reagents administered. Given thermal parameters such as SAR for different tissues, a computational model can be made in predicting temperature transitions which will be helpful in planning and optimizing surgical hyperthermia procedures.

  6. Thermal infrared images to quantify thermal ablation effects of acid and base on target tissues

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Ran, E-mail: jliubme@tsinghua.edu.cn, E-mail: liuran@tsinghua.edu.cn; Liu, Jing, E-mail: jliubme@tsinghua.edu.cn, E-mail: liuran@tsinghua.edu.cn [Department of Biomedical Engineering, School of Medicine, Tsinghua University, Beijing 100084 (China); Wang, Jia [Department of Biomedical Engineering, Johns Hopkins University, Baltimore, MD 21218 (United States)

    2015-07-15

    Hyperthermia (42-46°C), treatment of tumor tissue through elevated temperature, offers several advantages including high cost-effectiveness, highly targeted ablation and fewer side effects and hence higher safety level over traditional therapies such as chemotherapy and radiotherapy. Recently, hyperthermia using heat release through exothermic acid-base neutralization comes into view owing to its relatively safe products of salt and water and highly confined ablation. However, lack of quantitative understanding of the spatial and temporal temperature profiles that are produced by simultaneous diffusion of liquid chemical and its chemical reaction within tumor tissue impedes the application of this method. This article is dedicated to quantify thermal ablation effects of acid and base both individually and as in neutralization via infrared captured thermal images. A theoretical model is used to approximate specific heat absorption rate (SAR) based on experimental measurements that contrast two types of tissue, normal pork and pig liver. According to the computation, both pork and liver tissue has a higher ability in absorbing hydrochloric acid (HCl) than sodium hydroxide, hence suggesting that a reduced dosage for HCl is appropriate in a surgery. The heating effect depends heavily on the properties of tissue types and amount of chemical reagents administered. Given thermal parameters such as SAR for different tissues, a computational model can be made in predicting temperature transitions which will be helpful in planning and optimizing surgical hyperthermia procedures.

  7. Thermal infrared images to quantify thermal ablation effects of acid and base on target tissues

    Science.gov (United States)

    Liu, Ran; Wang, Jia; Liu, Jing

    2015-07-01

    Hyperthermia (42-46°C), treatment of tumor tissue through elevated temperature, offers several advantages including high cost-effectiveness, highly targeted ablation and fewer side effects and hence higher safety level over traditional therapies such as chemotherapy and radiotherapy. Recently, hyperthermia using heat release through exothermic acid-base neutralization comes into view owing to its relatively safe products of salt and water and highly confined ablation. However, lack of quantitative understanding of the spatial and temporal temperature profiles that are produced by simultaneous diffusion of liquid chemical and its chemical reaction within tumor tissue impedes the application of this method. This article is dedicated to quantify thermal ablation effects of acid and base both individually and as in neutralization via infrared captured thermal images. A theoretical model is used to approximate specific heat absorption rate (SAR) based on experimental measurements that contrast two types of tissue, normal pork and pig liver. According to the computation, both pork and liver tissue has a higher ability in absorbing hydrochloric acid (HCl) than sodium hydroxide, hence suggesting that a reduced dosage for HCl is appropriate in a surgery. The heating effect depends heavily on the properties of tissue types and amount of chemical reagents administered. Given thermal parameters such as SAR for different tissues, a computational model can be made in predicting temperature transitions which will be helpful in planning and optimizing surgical hyperthermia procedures.

  8. Near-infrared reflectance spectroscopy for predicting chemical, instrumental and sensory quality of beef.

    Science.gov (United States)

    Ripoll, G; Albertí, P; Panea, B; Olleta, J L; Sañudo, C

    2008-11-01

    The aim of this study was to assess near-infrared reflectance (NIR) spectroscopy as a tool for determining sensory and texture characteristics of beef. Chemical, instrumental, texture and sensory characteristics were predicted by near-infrared reflectance spectroscopy carried out on longissimus dorsi muscle samples from 190 young bulls. The use of first derivative gave best predictions together with NIR spectra, except for myoglobin and water holding capacity, which had an R(2) of prediction of 0.91 and 0.82, respectively, using visible and NIR spectra. Tenderness was the best-predicted variable (R(2)=0.98) demonstrating the potential of NIR spectroscopy in the prediction of sensory variables. Chemical composition variables and Warner-Bratzler shear force were predicted with an R(2) of prediction of around 0.7, but protein was not predicted with accuracy.

  9. Determination of antioxidant content and antioxidant activity in foods using infrared spectroscopy and chemometrics: a review.

    Science.gov (United States)

    Lu, Xiaonan; Rasco, Barbara A

    2012-01-01

    Developing rapid analytical methods for bioactive components and predicting both the concentration and biological availability of nutraceutical components in foods is a topic of growing interest. Here, analysis of bioactive components and total antioxidant activity in food matrices using infrared spectroscopy coupled with chemometric predictive models is described. Infrared spectroscopy offers an alternative to wet chemistry, chromatographic determination of antioxidants, and in vitro biochemical assays for assessment of antioxidant activity. Spectroscopic methods provide a technique that can be used with biological tissues without extraction, which can often lead to degradation of the antioxidant components. Sample preparation time greatly decreases and analysis time is very short once a predictive model has been developed. Spectroscopic methods can have a high degree of precision when applied to analysis of nutraceutical compound concentration and antioxidant activity in foods. This article summarizes recent advances in vibrational spectroscopy and chemometrics and applications of these methods for antioxidant detection in foods.

  10. Fourier domain target transformation analysis in the thermal infrared

    Science.gov (United States)

    Anderson, D. L.

    1993-01-01

    Remote sensing uses of principal component analysis (PCA) of multispectral images include band selection and optimal color selection for display of information content. PCA has also been used for quantitative determination of mineral types and abundances given end member spectra. The preliminary results of the investigation of target transformation PCA (TTPCA) in the fourier domain to both identify end member spectra in an unknown spectrum, and to then calculate the relative concentrations of these selected end members are presented. Identification of endmember spectra in an unknown sample has previously been performed through bandmatching, expert systems, and binary classifiers. Both bandmatching and expert system techniques require the analyst to select bands or combinations of bands unique to each endmember. Thermal infrared mineral spectra have broad spectral features which vary subtly with composition. This makes identification of unique features difficult. Alternatively, whole spectra can be used in the classification process, in which case there is not need for an expert to identify unique spectra. Use of binary classifiers on whole spectra to identify endmember components has met with some success. These techniques can be used, along with a least squares fit approach on the endmembers identified, to derive compositional information. An alternative to the approach outlined above usese target transformation in conjunction with PCA to both identify and quantify the composition of unknown spectra. Preprocessing of the library and unknown spectra into the fourier domain, and using only a specific number of the components, allows for significant data volume reduction while maintaining a linear relationship in a Beer's Law sense. The approach taken here is to iteratively calculate concentrations, reducing the number of endmember components until only non-negative concentrations remain.

  11. VO1/VO2 MARS INFRARED THERMAL MAPPER RESAMPLED DATA V1.0

    Data.gov (United States)

    National Aeronautics and Space Administration — This data set contains the Infrared Thermal Mapping (IRTM) data of Mars acquired by the Viking orbiters. The database contains the time, geometry, and radiative...

  12. Airborne Thematic Thermal InfraRed and Electro-Optical Imaging System Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The innovation is an advanced Airborne Thematic Thermal InfraRed and Electro-Optical Imaging System (ATTIREOIS). ATTIREOIS sensor payload consists of two sets of...

  13. In-Flight Calibration of the Thermal Infrared Sensor (TIRS) on the Landsat Data Continuity Mission

    Science.gov (United States)

    Thome, K.; Reuter, D.; Montanaro, M.; Hook, S.; Markham, B.

    2011-01-01

    Describe in-flight calibration for the Thermal Infrared Sensor (TIRS) (1) Overview of TIRS (2) On-orbit radiometric calibration (2a) Onboard calibrator (2b) Terrestrial sites (3) On-orbit geometric and spatial calibration

  14. Phase Retrieval on Undersampled Data from the Thermal Infrared Sensor (TIRS)

    Science.gov (United States)

    Bolcar, Matthew R.; Mentzell, Eric

    2011-01-01

    Phase retrieval was applied to under-sampled data from a thermal infrared imaging system to estimate defocus across the field of view (FOV). We compare phase retrieval estimated values to those obtained using an independent technique.

  15. Infrared absorption nano-spectroscopy using sample photoexpansion induced by tunable quantum cascade lasers.

    Science.gov (United States)

    Lu, Feng; Belkin, Mikhail A

    2011-10-10

    We report a simple technique that allows obtaining mid-infrared absorption spectra with nanoscale spatial resolution under low-power illumination from tunable quantum cascade lasers. Light absorption is detected by measuring associated sample thermal expansion with an atomic force microscope. To detect minute thermal expansion we tune the repetition frequency of laser pulses in resonance with the mechanical frequency of the atomic force microscope cantilever. Spatial resolution of better than 50 nm is experimentally demonstrated.

  16. Identification of microcrystalline rocks using thermal emission spectroscopy

    Science.gov (United States)

    Hardgrove, C. J.; Rogers, D.; Glotch, T. D.; Arnold, J. A.

    2015-12-01

    High-silica deposits on Mars have been discovered from orbit (Holden Crater, Mawrth Vallis) and from landed surface missions to both Gusev Crater (Spirit) and Gale Crater (Curiosity). The character of these silica deposits can be used to understand both the depositional environment (i.e. fumarole vs. sinter) and/or diagenetic process. Initial work has shown that, in the case of opaline silica, there are differences in spectral shape that may be related to surface textural features imparted during formation or post-depositional alteration. Due to the increasing importance of understanding microcrystalline deposits on Mars, here, we study the effects of crystal size and surface roughness on thermal infrared emission spectra of micro- and macro-crystalline quartz. The spectra of chert and macro-crystalline quartz have significant differences in both spectral contrast, and in the rounded doublet between ~1000-1250 cm-1, which can shift and appear less rounded in microcrystalline samples. We find that microcrystalline minerals exhibit naturally rough surfaces compared to their macrocrystalline counterparts at the 10 micron scale; and that this roughness causes distinct spectral differences within the Reststrahlen bands. We find that surface roughness, if rough on the scale of the wavelengths where the wavelength-dependent absorption coefficient (k) is large, can cause not only decreased spectral contrast, but also substantial changes in spectral shape. The spectral shape differences are small enough that the composition of the material is still recognizable, but large enough such that a roughness effect could be detected. We find that my studying the thermal infrared spectral character of the sample, it may be possible to make general inferences about microcrystallinity, and thus aid in the potential reconstruction of sedimentary rock diagenesis.

  17. Thermal Infrared Multispectral Scanner (TIMS): An investigator's guide to TIMS data

    Science.gov (United States)

    Palluconi, F. D.; Meeks, G. R.

    1985-01-01

    The Thermal Infrared Multispectral Scanner (TIMS) is a NASA aircraft scanner providing six channel spectral capability in the thermal infrared region of the electromagnetic spectrum. Operating in the atmospheric window region (8 to 12 micrometers) with a channel sensitivity of approximately 0.1 C, TIMS may be used whenever an accurate measure of the Earth's surface is needed. A description of this scanner is provided as well as a discussion of data acquisition and reduction.

  18. Development of models for thermal infrared radiation above and within plant canopies

    Science.gov (United States)

    Paw u, Kyaw T.

    1992-01-01

    Any significant angular dependence of the emitted longwave radiation could result in errors in remotely estimated energy budgets or evapotranspiration. Empirical data and thermal infrared radiation models are reviewed in reference to anisotropic emissions from the plant canopy. The biometeorological aspects of linking longwave models with plant canopy energy budgets and micrometeorology are discussed. A new soil plant atmosphere model applied to anisotropic longwave emissions from a canopy is presented. Time variation of thermal infrared emission measurements is discussed.

  19. Chinese vinegar classification via volatiles using long-optical-path infrared spectroscopy and chemometrics.

    Science.gov (United States)

    Dong, D; Zheng, W; Jiao, L; Lang, Y; Zhao, X

    2016-03-01

    Different brands of Chinese vinegar are similar in appearance, color and aroma, making their discrimination difficult. The compositions and concentrations of the volatiles released from different vinegars vary by raw material and brewing process and thus offer a means to discriminate vinegars. In this study, we enhanced the detection sensitivity of the infrared spectrometer by extending its optical path. We measured the infrared spectra of the volatiles from 5 brands of Chinese vinegar and observed the spectral characteristics corresponding to alcohols, esters, acids, furfural, etc. Different brands of Chinese vinegar had obviously different infrared spectra and could be classified through chemometrics analysis. Furthermore, we established classification models and demonstrated their effectiveness for classifying different brands of vinegar. This study demonstrates that long-optical-path infrared spectroscopy has the ability to discriminate Chinese vinegars with the advantages that it is fast and non-destructive and eliminates the need for sampling. Copyright © 2015 Elsevier Ltd. All rights reserved.

  20. Mesenteric near-infrared spectroscopy and risk of gastrointestinal complications in infants undergoing surgery for congenital heart disease.

    Science.gov (United States)

    Iliopoulos, Ilias; Branco, Ricardo G; Brinkhuis, Nadine; Furck, Anke; LaRovere, Joan; Cooper, David S; Pathan, Nazima

    2016-04-01

    We hypothesised that lower mesenteric near-infrared spectroscopy values would be associated with a greater incidence of gastrointestinal complications in children weighing infrared spectroscopy, central venous oxygen saturation, and arterial blood gases for 48 hours post-operatively. Enteral feeding intake, gastrointestinal complications, and markers of organ dysfunction were monitored for 7 days. A total of 50 children, with median age of 16.7 (3.2-31.6) weeks, were studied. On admission, the average mesenteric near-infrared spectroscopy value was 71±18%, and the systemic oxygen saturation was 93±7.5%. Lower admission mesenteric near-infrared spectroscopy correlated with longer time to establish enteral feeds (r=-0.58, pinfrared spectroscopy (58±18% versus 73±17%, p=0.01) and higher mesenteric arteriovenous difference of oxygen at admission [39 (23-47) % versus 19 (4-27) %, p=0.02]. Based on multiple logistic regression, admission mesenteric near-infrared spectroscopy was independently associated with gastrointestinal complications (Odds ratio, 0.95; 95% confidence interval, 0.93-0.97; p=0.03). Admission mesenteric near-infrared spectroscopy showed an area under the receiver operating characteristic curve of 0.76 to identify children who developed gastrointestinal complications, with a suggested cut-off value of 72% (78% sensitivity, 68% specificity). In this pilot study, we conclude that admission mesenteric near-infrared spectroscopy is associated with gastrointestinal complications and enteral feeding tolerance in children after cardiac surgery.

  1. Effective and efficient agricultural drainage pipe mapping with UAS thermal infrared imagery: a case study

    Science.gov (United States)

    Effective and efficient methods are needed to map agricultural subsurface drainage systems. Visible (VIS), near infrared (NIR), and/or thermal infrared (TIR) imagery obtained by unmanned aircraft systems (UAS) may provide a means for determining drainage pipe locations. Preliminary UAS surveys wit...

  2. The application of near infrared spectroscopy (NIR technique for

    Directory of Open Access Journals (Sweden)

    Sandor Barabassy

    2001-06-01

    Full Text Available The production of cow’s milk in Hungary fluctuates by 15-20 % annualy. Surplus milk is dried into powder and can also be converted to modified milk powders using techniques such as ultra filtration. From approximetely 20.000 tonnes, of all milk powder types, 3.000 tonnes, is converted using ultra filtration technology. Multivariable near infrared (NIR calibration was performed on powder mixtures of whole milk, skimmed milk, whey, retenate (protein concentrate and lactose for rapid fat, protein, lactose, water and ash content determination. More than 150 samples were prepared and measured in two NIRS labs (Scottish Agriculture College – SAC – Aberdeen and University of Horticulture and Food Science - UHFS – Budapest. The results obtained from the same samples were compared. The aims of the study were: 1. Rapid quantitative and qualitative determination of mixtures of milk powder products using NIR technique. 2. Comparison of the results achieved in Aberdeen (SAC and Budapest (UHFS institutes. The mass per cent varied between 0.0-2.8% for fat, 0.0-80% for protein, 6.6-100 % for lactose, 0.0-5.0 % for water and 0.0-8.0 % for ash. High correlation coefficients (0.97-0.99 were found for all five components.

  3. Shortwave Infrared Imaging Spectroscopy for Analysis of Ancient Paintings.

    Science.gov (United States)

    Wu, Taixia; Li, Guanghua; Yang, Zehua; Zhang, Hongming; Lei, Yong; Wang, Nan; Zhang, Lifu

    2017-05-01

    Spectral analysis is one of the main non-destructive techniques used to examine cultural relics. Hyperspectral imaging technology, especially on the shortwave infrared (SWIR) band, can clearly extract information from paintings, such as color, pigment composition, damage characteristics, and painting techniques. All of these characteristics have significant scientific and practical value in the study of ancient paintings and other relics and in their protection and restoration. In this study, an ancient painting, numbered Gu-6541, which had been found in the Forbidden City, served as a sample. A ground-based SWIR imaging spectrometer was used to produce hyperspectral images with high spatial and spectral resolution. Results indicated that SWIR imaging spectral data greatly facilitates the extraction of line features used in drafting, even using a single band image. It can be used to identify and classify mineral pigments used in paintings. These images can detect alterations and traces of daub used in painting corrections and, combined with hyperspectral data analysis methods such as band combination or principal component analysis, such information can be extracted to highlight outcomes of interest. In brief, the SWIR imaging spectral technique was found to have a highly favorable effect on the extraction of line features from drawings and on the identification of colors, classification of paintings, and extraction of hidden information.

  4. Near-Infrared Spectroscopy of Small Protonated Water Clusters

    Science.gov (United States)

    Wagner, J. Philipp; McDonald, David C., II; McCoy, Anne B.; Duncan, Michael A.

    2017-06-01

    Small protonated water clusters and their argon tagged analogues of the general formula H^{+}(H_{2}O)_{n}Ar_{m} have been generated in a pulsed electric discharge source. Clusters containing n=1-8 water molecules were mass-selected and their absorptions in the near-infrared were probed with a tunable Nd/colonYAG pumped OPA/OPA laser system in the region from 4850-7350 cm^{-1}. A doublet corresponding to overtones of the free O-H stretches of the external waters was observed around 7200 cm^{-1} that was continuously decreasing in intensity with increasing cluster size. Broad, mostly featureless absorptions were found around 5300 cm^{-1} associated with stretch/bend combinations and with the hydrogen bonded waters in the core of the clusters. Vibrational assignments were substantiated by comparison to anharmonic frequency computations via second-order vibrational perturbation theory (VPT2) at the MP2/aug-cc-pVTZ level of theory.

  5. Identification of different forms of cocaine and substances used in adulteration using near-infrared Raman spectroscopy and infrared absorption spectroscopy.

    Science.gov (United States)

    Penido, Ciro A F O; Pacheco, Marcos Tadeu T; Zângaro, Renato A; Silveira, Landulfo

    2015-01-01

    Identification of cocaine and subsequent quantification immediately after seizure are problems for the police in developing countries such as Brazil. This work proposes a comparison between the Raman and FT-IR techniques as methods to identify cocaine, the adulterants used to increase volume, and possible degradation products in samples seized by the police. Near-infrared Raman spectra (785 nm excitation, 10 sec exposure time) and FT-IR-ATR spectra were obtained from different samples of street cocaine and some substances commonly used as adulterants. Freebase powder, hydrochloride powder, and crack rock can be distinguished by both Raman and FT-IR spectroscopies, revealing differences in their chemical structure. Most of the samples showed characteristic peaks of degradation products such as benzoylecgonine and benzoic acid, and some presented evidence of adulteration with aluminum sulfate and sodium carbonate. Raman spectroscopy is better than FT-IR for identifying benzoic acid and inorganic adulterants in cocaine. © 2014 American Academy of Forensic Sciences.

  6. Infrared Spectroscopy of the H2/HD/D2-O2 Van Der Waals Complexes

    Science.gov (United States)

    Raston, Paul; Bunn, Hayley

    2016-06-01

    Hydrogen is the most abundant element in the universe and oxygen is the third, so understanding the interaction between the two in their different forms is important to understanding astrochemical processes. The interaction between H2 and O2 has been explored in low energy scattering experiments and by far infrared synchrotron spectroscopy of the van der Waals complex. The far infrared spectra suggest a parallel stacked average structure with seven bound rotationally excited states. Here, we present the far infrared spectrum of HD/D2-O2 and the mid infrared spectrum of H2-O2 at 80 K, recorded at the infrared beamline facility of the Australian Synchrotron. We observed 'sharp' peaks in the mid infrared region, corresponding to the end over end rotation of H2-O2, that are comparatively noisier than analogous peaks in the far infrared where the synchrotron light is brightest. The larger reduced mass of HD and D2 compared to H2 is expected to result in more rotational bound states and narrower bands. The latest results in our ongoing efforts to explore this system will be presented. Y. Kalugina, et al., Phys. Chem. Chem. Phys. 14, 16458 (2012) S. Chefdeville et al. Science 341, 1094 (2013) H. Bunn et al. ApJ 799, 65 (2015)

  7. Fully stabilized mid-infrared frequency comb for high-precision molecular spectroscopy.

    Science.gov (United States)

    Vainio, Markku; Karhu, Juho

    2017-02-20

    A fully stabilized mid-infrared optical frequency comb spanning from 2.9 to 3.4 µm is described in this article. The comb is based on half-harmonic generation in a femtosecond optical parametric oscillator, which transfers the high phase coherence of a fully stabilized near-infrared Er-doped fiber laser comb to the mid-infrared region. The method is simple, as no phase-locked loops or reference lasers are needed. Precise locking of optical frequencies of the mid-infrared comb to the pump comb is experimentally verified at sub-20 mHz level, which corresponds to a fractional statistical uncertainty of 2 × 10-16 at the center frequency of the mid-infrared comb. The fully stabilized mid-infrared comb is an ideal tool for high-precision molecular spectroscopy, as well as for optical frequency metrology in the mid-infrared region, which is difficult to access with other stabilized frequency comb techniques.

  8. Advances in Contactless Silicon Defect and Impurity Diagnostics Based on Lifetime Spectroscopy and Infrared Imaging

    Directory of Open Access Journals (Sweden)

    Jan Schmidt

    2007-01-01

    Full Text Available This paper gives a review of some recent developments in the field of contactless silicon wafer characterization techniques based on lifetime spectroscopy and infrared imaging. In the first part of the contribution, we outline the status of different lifetime spectroscopy approaches suitable for the identification of impurities in silicon and discuss—in more detail—the technique of temperature- and injection-dependent lifetime spectroscopy. The second part of the paper focuses on the application of infrared cameras to analyze spatial inhomogeneities in silicon wafers. By measuring the infrared signal absorbed or emitted from light-generated free excess carriers, high-resolution recombination lifetime mappings can be generated within seconds to minutes. In addition, mappings of non-recombination-active trapping centers can be deduced from injection-dependent infrared lifetime images. The trap density has been demonstrated to be an important additional parameter in the characterization and assessment of solar-grade multicrystalline silicon wafers, as areas of increased trap density tend to deteriorate during solar cell processing.

  9. Chemometric compositional analysis of phenolic compounds in fermenting samples and wines using different infrared spectroscopy techniques.

    Science.gov (United States)

    Aleixandre-Tudo, Jose Luis; Nieuwoudt, Helene; Aleixandre, Jose Luis; du Toit, Wessel

    2018-01-01

    The wine industry requires reliable methods for the quantification of phenolic compounds during the winemaking process. Infrared spectroscopy appears as a suitable technique for process control and monitoring. The ability of Fourier transform near infrared (FT-NIR), attenuated total reflectance mid infrared (ATR-MIR) and Fourier transform infrared (FT-IR) spectroscopies to predict compositional phenolic levels during red wine fermentation and aging was investigated. Prediction models containing a large number of samples collected over two vintages from several industrial fermenting tanks as well as wine samples covering a varying number of vintages were validated. FT-NIR appeared as the most accurate technique to predict the phenolic content. Although slightly less accurate models were observed, ATR-MIR and FT-IR can also be used for the prediction of the majority of phenolic measurements. Additionally, the slope and intercept test indicated a systematic error for the three spectroscopies which seems to be slightly more pronounced for HPLC generated phenolics data than for the spectrophotometric parameters. However, the results also showed that the predictions made with the three instruments are statistically comparable. The robustness of the prediction models was also investigated and discussed. Copyright © 2017 Elsevier B.V. All rights reserved.

  10. Parallel thermal analysis technology using an infrared camera for high-throughput evaluation of active pharmaceutical ingredients: a case study of melting point determination.

    Science.gov (United States)

    Kawakami, Kohsaku

    2010-09-01

    Various techniques for physical characterization of active pharmaceutical ingredients, including X-ray powder diffraction, birefringence observation, Raman spectroscopy, and high-performance liquid chromatography, can be conducted using 96-well plates. The only exception among the important characterization items is the thermal analysis, which can be a limiting step in many cases, notably when screening the crystal/salt form. In this study, infrared thermal camera technology was applied for thermal characterization of pharmaceutical compounds. The melting temperature of model compounds was determined typically within 5 min, and the obtained melting temperature values agreed well with those from differential scanning calorimetry measurements. Since many compounds can be investigated simultaneously in this infrared technology, it should be promising for high-throughput thermal analysis in the pharmaceutical developmental process.

  11. Infrared overtone spectroscopy and unimolecular decay dynamics of peroxynitrous acid

    Science.gov (United States)

    Konen, Ian M.; Pollack, Ilana B.; Li, Eunice X. J.; Lester, Marsha I.; Varner, Mychel E.; Stanton, John F.

    2005-03-01

    Peroxynitrous acid (HOONO) is generated in a pulsed supersonic expansion through recombination of photolytically generated OH and NO2 radicals. A rotationally resolved infrared action spectrum of HOONO is obtained in the OH overtone region at 6971.351(4)cm-1 (origin), providing definitive spectroscopic identification of the trans-perp (tp) conformer of HOONO. Analysis of the rotational band structure yields rotational constants for the near prolate asymmetric top, the ratio of the a-type to c-type components of the transition dipole moment for the hybrid band, and a homogeneous linewidth arising from intramolecular vibrational energy redistribution and/or dissociation. The quantum state distribution of the OH (ν =0,JOH) products from dissociation is well characterized by a microcanonical statistical distribution constrained only by the energy available to products, 1304±38cm-1. This yields a 5667±38cm-1 [16.2(1)kcalmol-1] binding energy for tp-HOONO. An equivalent available energy and corresponding binding energy are obtained from the highest observed OH product state. Complementary high level ab initio calculations are carried out in conjunction with second-order vibrational perturbation theory to predict the spectroscopic observables associated with the OH overtone transition of tp-HOONO including its vibrational frequency, rotational constants, and transition dipole moment. The same approach is used to compute frequencies and intensities of multiple quantum transitions that aid in the assignment of weaker features observed in the OH overtone region, in particular, a combination band of tp-HOONO involving the HOON torsional mode.

  12. Infrared Spectroscopy of Parent Volatiles in Comets: Implications for Astrobiology

    Science.gov (United States)

    DiSanti, Michael A.

    2010-01-01

    Current cometary orbits provide information on their recent dynamical history. However, determining a given comet's formation region from its current dynamical state alone is complicated by radial migration in the proto-planetary disk and by dynamical interactions with the growing giant planets. Because comets reside for long periods of time in the outer Solar System, the ices contained in their nuclei (native ices) retain a relatively well-preserved footprint of when and where they formed, and this in turn can provide clues to conditions in the formation epoch. As a comet approaches the Sun, sublimation of its native ices releases parent volatiles into the coma where they can be measured spectroscopically. The past to - 15 years have seen the advent of infrared spectrometers with high sensitivity between about 2.8 and 5.0 micron, enabling a taxonomy among comets based on abundances of parent volatiles (e.g., H2O, CO, CH4, C2H6, HCN, CH30H, H2CO, NH3). Such molecules are of keen interest to Astrobiology, as they include important pre-biotic species that likely were required for the emergence of life on Earth and perhaps elsewhere. Approximately 20 comets have thus far been characterized, beginning with C/1996 82 (Hyakutake) in 1996. Molecular production rates are established through comparison of observed emission line intensities with those predicted by quantum mechanical fluorescence models. Abundances of parent volatiles (relative to H2O) vary among even the relatively small number of comets sampled, with the most volatile species (CO and CH4) displaying the largest variations. Techniques developed for measuring parent volatile abundances in comets will be discussed, as will possible implications for their formation.

  13. Infrared Spectroscopy in Cancer Diagnosis and Chemotherapy Monitoring

    Science.gov (United States)

    Tolstorozhev, G. B.; Bel'kov, M. V.; Skornyakov, I. V.; Butra, V. A.; Pekhnyo, V. I.; Kozachkova, A. N.; Tsarik, N. I.; Kutsenko, I. P.; Sharykina, N. I.

    2014-07-01

    We demonstrate that IR spectroscopic analysis can be used in diagnosis and chemotherapy monitoring for cancers of various organs at the molecular level. We used Fourier transform IR spectroscopy to study human breast and thyroid tumor tissues which were removed during surgery. The characteristic frequencies of C = O stretching vibrations in the IR spectra of tissues of pathological foci were compared with data from histological examination. In the IR spectra of healthy tissues or for benign tumors, the most intense absorption bands ν(C = O) are located in the interval 1675-1650 cm-1. When malignant neoplasms are present in the organs, the intensity of the bands in this range of the spectrum is reduced, while the intensities of the absorption bands in the 1710-1680 cm-1 interval increase. We also studied lung tissue for mice of the C57B1/6 line for healthy tissue and after implantation of B-16 melanoma tumor. The IR spectra of healthy mouse lung tissue and mouse lung tissue with B-16 melanoma metastases in the region of the C = O stretching vibrations display the same differences. We found that when lung malignancy was treated with the optimal dose of a synthesized drug based on palladium complexes of methylenediphosphonic acid, the spectroscopic signs of the presence of metastases in the lungs disappear, and the IR spectrum of the lung tissue after treatment practically coincides with the spectrum of healthy lung tissue.

  14. Milk freezing point determination with infrared spectroscopy and thermistor cryoscopy method

    Directory of Open Access Journals (Sweden)

    Nataša Pintić Pukec

    2009-09-01

    Full Text Available Two analytical methods were used for determination of the freezing point on identical test raw milk samples. The aim of this research was to investigate possibility of usage infrared spectrometry method, with MilcoScan FT 6000 milk analyzer for determination of milk freezing point, comparing to results obtained by using a reference thermistor cryoscopy method with Cryoscope 4C3 analyzer. During period of four months, total of 320 milk samples were analyzed. Once a week milk samples were sampled at collection reservoirs from twenty milk producers. Milk freezing point was analyzed with each of investigated methods in three consecutive testing respectively repetition. The results of freezing point were recorded as higher by reference in comparison to infrared spectroscopy method. Mean difference from 1.31 to 5.28 m°C respectively 3.43 m°C was determined between results obtained with infrared spectroscopy and reference method. Mean repeatability results for both investigated methods showed slight difference, sr%=0.194 for the reference method and sr%=0.193 for the infrared spectrometry method. Statistically significant difference between the means of the obtained results with two different investigated methods (P>0.05; P>0,01 was not determined. The results indicate the conclusion that infrared spectroscopy method can be used for detecting adulteration of milk with water addition as screening method. Based upon the obtained results usage of infrared spectrometry method in determination of raw milk freezing point is recommended because it is faster and can be carried out with current analyzers used for determination of other milk quality parameters, for example analyzer MilkoScan FT 6000.

  15. Developments in FTIR spectroscopy of diamonds and better constraints on diamond thermal histories

    Science.gov (United States)

    Kohn, Simon; Speich, Laura; Smith, Christopher; Bulanova, Galina

    2017-04-01

    Fourier Transform Infrared (FTIR) spectroscopy is a commonly-used technique for investigating diamonds. It gives the most useful information if spatially-resolved measurements are used [1]. In this contribution we discuss the best way to acquire and present FTIR data from diamonds, using examples from Murowa (Zimbabwe), Argyle (Australia) and Machado River (Brazil). Examples of FTIR core-to-rim line scans, maps with high spatial resolution and maps with high spectral resolution that are fitted to extract the spatial variation of different nitrogen and hydrogen defects are presented. Model mantle residence temperatures are calculated from the concentration of A and B nitrogen-containing defects in the diamonds using known times of annealing in the mantle. A new, two-stage thermal annealing model is presented that better constrains the thermal history of the diamond and that of the mantle lithosphere in which the diamond resided. The effect of heterogeneity within the analysed FTIR volume is quantitatively assessed and errors in model temperatures that can be introduced by studying whole diamonds instead of thin plates are discussed. The kinetics of platelet growth and degradation will be discussed and the potential for two separate, kinetically-controlled defect reactions to be used to constrain a full thermal history of the diamond will be assessed. [1] Kohn, S.C., Speich, L., Smith, C.B. and Bulanova, G.P., 2016. FTIR thermochronometry of natural diamonds: A closer look. Lithos, 265, pp.148-158.

  16. On-line laser spectroscopy with thermal atomic beams

    CERN Document Server

    Thibault, C; De Saint-Simon, M; Duong, H T; Guimbal, P; Huber, G; Jacquinot, P; Juncar, P; Klapisch, Robert; Liberman, S; Pesnelle, A; Pillet, P; Pinard, J; Serre, J M; Touchard, F; Vialle, J L

    1981-01-01

    On-line high resolution laser spectroscopy experiments have been performed in which the light from a CW tunable dye laser interacts at right angles with a thermal atomic beam. /sup 76-98/Rb, /sup 118-145 /Cs and /sup 208-213/Fr have been studied using the ionic beam delivered by the ISOLDE on-line mass separator at CERN while /sup 30-31/Na and /sup 38-47/K have been studied by setting the apparatus directly on-line with the PS 20 GeV proton beam. The principle of the method is briefly explained and some results concerning nuclear structure are given. The hyperfine structure, spins and isotope shifts of the alkali isotopes and isomers are measured. (8 refs).

  17. Agricultural Applications and Requirements for Thermal Infrared Scanners

    Science.gov (United States)

    Wiegand, C. L.

    1971-01-01

    Some of the applications of thermal scanner data in agriculture are presented along with illustrations of some of the factors affecting the temperature of plants, soil, and water. Examples of thermal imagery are included.

  18. Acid Aging Effects on Surfaces of PTFE Gaskets Investigated by Fourier Transform Infrared Spectroscopy

    Directory of Open Access Journals (Sweden)

    L. Giorgini

    2016-09-01

    Full Text Available This paper investigates the effect of a prolonged acid and thermal attack, on the surface of PTFE by Fourier Transform Infrared Micro-Spectroscopy (FT-IR. The materials are commercialized by two alternative producers in form of Teflon tapes. These tapes are installed in process plants where tires moulds are cleaned inside a multistage ultrasonic process. In these cases, Teflon tapes, having a role of gaskets, show inexplicably phenomena of degradation in relatively short operation periods. Even considering that these gaskets are exposed to the combined effect of ultrasonic waves, temperature, humidity and acid attack, the PTFE properties of resistance nominally exclude the possibility of these severe erosion phenomena. An interesting explanation can be related to the potential presence in the cleaning solution, mainly based on sulfamic acid, of highly reactive chemical compounds, as chlorides and fluorides, originated by the disaggregation of elements from the tire composition and/or additives used as processing aids and/or by catalytic effect generated by fluorine produced by PTFE degradation. In general, up to 300 different chemical elements, both organic and inorganic, natural and synthetic, are merged in a tire. Since this composition is practically unknown, especially regarding additives and “unusual elements”, representing a secrecy of each tire manufactures, it is really complex to define the chemical composition of the cleaning solution with an appropriate precision. As a consequence, the gaskets have been treated with different mixtures of acids in the way to combine a larger range of possibilities. Thus, the FT-IR experimental characterization of PTFE surface properties followed an appropriate accelerated aging, aiming at actuating the specific mechanics of wearing as in industrial use. The different acid treatments adopted for accelerating the aging of gaskets have highlighted the different behaviour of the PTFE matrix, but

  19. Quantitative analysis of sulfathiazole polymorphs in ternary mixtures by attenuated total reflectance infrared, near-infrared and Raman spectroscopy.

    Science.gov (United States)

    Hu, Yun; Erxleben, Andrea; Ryder, Alan G; McArdle, Patrick

    2010-11-02

    The simultaneous quantitative analysis of sulfathiazole polymorphs (forms I, III and V) in ternary mixtures by attenuated total reflectance-infrared (ATR-IR), near-infrared (NIR) and Raman spectroscopy combined with multivariate analysis is reported. To reduce the effect of systematic variations, four different data pre-processing methods; multiplicative scatter correction (MSC), standard normal variate (SNV), first and second derivatives, were applied and their performance was evaluated using their prediction errors. It was possible to derive a reliable calibration model for the three polymorphic forms, in powder ternary mixtures, using a partial least squares (PLS) algorithm with SNV pre-processing, which predicted the concentration of polymorphs I, III and V. Root mean square errors of prediction (RMSEP) for ATR-IR spectra were 5.0%, 5.1% and 4.5% for polymorphs I, III and V, respectively, while NIR spectra had a RMSEP of 2.0%, 2.9%, and 2.8% and Raman spectra had a RMSEP of 3.5%, 4.1%, and 3.6% for polymorphs I, III and V, respectively. NIR spectroscopy exhibits the smallest analytical error, higher accuracy and robustness. When these advantages are combined with the greater convenience of NIR's "in glass bottle" sampling method both ATR-IR and Raman methods appear less attractive. Copyright (c) 2010 Elsevier B.V. All rights reserved.

  20. Food Safety Evaluation Based on Near Infrared Spectroscopy and Imaging: A Review.

    Science.gov (United States)

    Fu, Xiaping; Ying, Yibin

    2016-08-17

    In recent years, due to the increasing consciousness of food safety and human health, much progress has been made in developing rapid and nondestructive techniques for the evaluation of food hazards, food authentication, and traceability. Near infrared (NIR) spectroscopy and imaging techniques have gained wide acceptance in many fields because of their advantages over other analytical techniques. Following a brief introduction of NIR spectroscopy and imaging basics, this review mainly focuses on recent NIR spectroscopy and imaging applications for food safety evaluation, including (1) chemical hazards detection; (2) microbiological hazards detection; (3) physical hazards detection; (4) new technology-induced food safety concerns; and (5) food traceability. The review shows NIR spectroscopy and imaging to be effective tools that will play indispensable roles for food safety evaluation. In addition, on-line/real-time applications of these techniques promise to be a huge growth field in the near future.

  1. Near-Infrared Spectroscopy of Ethynyl Radical, C2H

    Science.gov (United States)

    Le, Anh T.; Hall, Gregory; Sears, Trevor

    2016-06-01

    The ethynyl radical, C_2H, is a reactive intermediate important in various combustion processes and also widely observed in the interstellar medium. In spite of extensive previous spectroscopic studies, the characterization of the near infrared transitions from the tilde{X}2Σ+ state to the mixed vibrational overtone and tilde{A}2Π states is incomplete. A strong band of C_2H at 7064 cm-1 was first observed in a neon matrix and assigned as the tilde{A}2Π(002)1 - tilde{X}2Σ+ transition by Forney et al. Subsequent theoretical work of Tarroni and Carter attributed the strong absorptions in this region to transitions terminating in two upper states, each a mixture of vibrationally excited tilde{X} states and different zero-order tilde{A}-state bending levels: a 2Σ+ symmetry combination of tilde{X}(0,20,3) and tilde{A}(0,3,0)0κ and a 2Π symmetry combination of tilde{X}(0,31,3) and tilde{A}(0,0,2)1. Transitions to them from the zero point level of the tilde{X} state are calculated to differ in energy by less than 10 cm-1 and to be within a factor of two in intensity. Diode laser transient absorption was used to record Doppler-limited spectra between 7020 and 7130 cm-1, using 193 nm photolysis of CF_3C_2H as a source of C_2H. Two interleaved, rotationally resolved bands were observed, consistent with a 2Σ - 2Σ transition at 7088 cm-1 and a 2Π - 2Σ transition at 7108 cm-1, in good accord with the Tarroni and Carter calculation. Progress on the assignment and fitting of the spectra will be reported. Acknowledgements: Work at Brookhaven National Laboratory was carried out under Contract No. DE-SC0012704 with the U.S. Department of Energy, Office of Science, and supported by its Division of Chemical Sciences, Geosciences, and Biosciences. D. Forney, M.E. Jacox, and W.E. Thompson, J. Mol. Spectrosc. 170, 178 (1995). R. Tarroni and S. Carter, Mol. Phys. 102, 2167 (2004)

  2. Far-infrared spectroscopy of lanthanide-based molecular magnetic materials

    Energy Technology Data Exchange (ETDEWEB)

    Haas, Sabrina

    2015-05-13

    This thesis demonstrates the applicability of far-infrared spectroscopy for the study of the crystal-field splitting of lanthanides in single-molecular magnetic materials. The far-infrared studies of three different kinds of single-molecular-magnetic materials, a single-ion magnet, a single-chain magnet and an exchange-coupled cluster, yielded a deeper understanding of the crystal-field splitting of the lanthanides in these materials. In addition, our results offered the opportunity to gain a deeper insight into the relaxation processes of these materials.

  3. Infrared and fluorescence spectroscopy for monitoring protein structure and interaction changes during cheese ripening

    OpenAIRE

    Mazerolles, Gérard; Devaux, Marie-Françoise; Duboz, Gabriel; Duployer, Marie-Hélène; Riou, Nadine; Dufour, Éric

    2001-01-01

    International audience; Sixteen experimental semi-hard cheeses, varying in moisture (42.1 to 49.8% ), protein (20.2 to 25.9% ) and fat (23.7 to 31.1% ) content, were manufactured and ripened under controlled conditions. Fluorescence (tryptophan) and mid-infrared (Amide I and II regions) spectra were collected at 1, 21, 51 and 81 days of ripening in order to test the ability of spectroscopy to highlight the molecular changes that occur during this process. The mid-infrared and fluorescence spe...

  4. Quantification of changes in skin hydration and sebum after tape stripping using infrared spectroscopy

    Science.gov (United States)

    Ezerskaia, A.; Pereira, S. F.; Urbach, H. P.; Varghese, B.

    2017-02-01

    Skin barrier function relies on well balanced water and lipid system of stratum corneum. Optimal hydration and oiliness levels are indicators of skin health and integrity. We demonstrate an accurate and sensitive depth profiling of stratum corneum sebum and hydration levels using short wave infrared spectroscopy in the spectral range around 1720 nm. We demonstrate that short wave infrared spectroscopic technique combined with tape stripping can provide morequantitative and more reliable skin barrier function information in the low hydration regime, compared to conventional biophysical methods.

  5. Infrared Spectroscopy of Transition Metal-Molecular interactions in the Gas Phase

    Energy Technology Data Exchange (ETDEWEB)

    Duncan, Michael A. [Univ. of Georgia, Athens, GA (United States)

    2008-11-14

    Transition metal-molecular complexes produced in a molecular beam are mass-selected and studied with infrared laser photodissociation spectroscopy. Metal complexes with carbon monoxide, carbon dioxide, nitrogen, water, acetylene or benzene are studied for a variety of metals. The number and intensity of infrared active bands are compared to the predictions of density functional theory calculations to derive structures, spin states and coordination numbers in these systems. These studied provide new insights into subtle details of metal-molecular interactions important in heterogeneous catalysis, metal-ligand bonding and metal ion solvation.

  6. Broadband integrated mid infrared light sources as enabling technology for point of caremid infrared spectroscopy

    Science.gov (United States)

    2017-08-20

    wavelengths is still in its infancy, resulting in mid-IR spectroscopy being currently restricted to academic proof-of- principle experiments only.
 This...journal paper has resulted. I am assuming that the author has just concentrated on finishing this thesis and has not had time to write these papers...I sincerely hope that Xiantao Jiang will find the time to write these papers.” Indeed, we are currently in the process of writing those papers in

  7. Off-axis quartz-enhanced photoacoustic spectroscopy using a pulsed nanosecond mid-infrared optical parametric oscillator.

    Science.gov (United States)

    Lassen, Mikael; Lamard, Laurent; Feng, Yuyang; Peremans, Andre; Petersen, Jan C

    2016-09-01

    A trace-gas sensor, based on quartz-enhanced photoacoustic spectroscopy (QEPAS), consisting of two acoustically coupled micro-resonators (mR) with an off-axis 20 kHz quartz tuning fork (QTF) is demonstrated. The complete acoustically coupled mR system is optimized based on finite-element simulations and is experimentally verified. The QEPAS sensor is pumped resonantly by a nanosecond pulsed single-mode mid-infrared optical parametric oscillator. The sensor is used for spectroscopic measurements on methane in the 3.1-3.5 μm wavelength region with a resolution bandwidth of 1  cm-1 and a detection limit of 0.8 ppm. An Allan deviation analysis shows that the detection limit at the optimum integration time for the QEPAS sensor is 32 ppbv at 190 s, and that the background noise is due solely to the thermal noise of the QTF.

  8. Producing Mosaiced Infrared Data on Natural Hazards for Real-time Emergency Management using UAS and Thermal Infrared Cameras

    Science.gov (United States)

    Hatfield, M. C.; Webley, P. W.; Saiet, E., II

    2015-12-01

    Unmanned aerial systems (UAS) provide a unique capability for emergency management and real-time hazard assessment with access to hazardous environments that maybe off limits for manned aircraft while reducing the risk to personnel and loss of ground assets. When dealing with hazards, such as forest fires and volcanic eruptions, there is a need to assess the location of the fire/flow front and where best to assign ground personnel to reduce the risk to local populations and infrastructure. Thermal infrared cameras provide the ideal tool to detect subtle changes in the developing fire/flow front while providing data 24/7. There are limits to the detecting capabilities of these cameras given the wavelengths used and image resolution available. Given the large thermal contrast between the hot flow front and surrounding landscape then the data can be used to map out the location and changes seen as the front of the flow/fire advances. To map the complete hazard then either the UAS has to be flown at an altitude to capture the event in one image or the data has to be mosaiced together. Higher altitudes lead to coarser resolution imagery and therefore we will show how thermal infrared data can be mosaiced to provide the highest spatial resolution map of the hazard. We will present results using different UAS and thermal cameras including adding neutral density filters to detect hotter thermal targets. Timely generation of these mosaiced maps in a real-time environment is critical for those assessing the ongoing event and we will show how these maps can be generated quickly with the necessary spatial and thermal accuracy while discussing the requirements needed to generate thermal infrared maps of the hazardous events that are both useful for quick real-time assessment and also for further investigation in research projects.

  9. New Frontiers for Applications of Thermal Infrared Imaging Devices: Computational Psychopshysiology in the Neurosciences.

    Science.gov (United States)

    Cardone, Daniela; Merla, Arcangelo

    2017-05-05

    Thermal infrared imaging has been proposed, and is now used, as a tool for the non-contact and non-invasive computational assessment of human autonomic nervous activity and psychophysiological states. Thanks to a new generation of high sensitivity infrared thermal detectors and the development of computational models of the autonomic control of the facial cutaneous temperature, several autonomic variables can be computed through thermal infrared imaging, including localized blood perfusion rate, cardiac pulse rate, breath rate, sudomotor and stress responses. In fact, all of these parameters impact on the control of the cutaneous temperature. The physiological information obtained through this approach, could then be used to infer about a variety of psychophysiological or emotional states, as proved by the increasing number of psychophysiology or neurosciences studies that use thermal infrared imaging. This paper presents a review of the principal achievements of thermal infrared imaging in computational psychophysiology, focusing on the capability of the technique for providing ubiquitous and unwired monitoring of psychophysiological activity and affective states. It also presents a summary on the modern, up-to-date infrared sensors technology.

  10. The Thermal Infrared Sensor (TIRS) on Landsat 8: Design overview and pre-launch characterization

    Science.gov (United States)

    The Thermal InfraRed Sensor (TIRS) on Landsat 8 is the latest thermal sensor in that series of missions. Unlike the previous single channel sensors, TIRS uses two channels to cover the 10-12 micron band. It is also a pushbroom imager; a departure from the previous whiskbroom approach. Nevertheles...

  11. Highly efficient and broadband mid-infrared metamaterial thermal emitter for optical gas sensing.

    Science.gov (United States)

    Gong, Yongkang; Wang, Zuobin; Li, Kang; Uggalla, Leshan; Huang, Jungang; Copner, Nigel; Zhou, Yang; Qiao, Dun; Zhu, Jiuyuan

    2017-11-01

    Development of a novel, cost-effective, and highly efficient mid-infrared light source has been identified as a major scientific and technological goal within the area of optical gas sensing. We have proposed and investigated a mid-infrared metamaterial thermal emitter based on micro-structured chromium thin film. The results demonstrate that the proposed thermal light source supports broadband and wide angular absorption of both TE- and TM-polarized light, giving rise to broadband thermal radiation with averaged emissivity of ∼0.94 in a mid-infrared atmospheric window of 8-14 μm. The proposed microphotonic concept provides a promising alternative mid-infrared source and paves the way towards novel optical gas sensing platforms for many applications.

  12. Infrared radiative properties and thermal modeling of ceramic-embedded textile fabrics.

    Science.gov (United States)

    Anderson, David M; Fessler, John R; Pooley, Matthew A; Seidel, Scott; Hamblin, Michael R; Beckham, Haskell W; Brennan, James F

    2017-03-01

    The infrared optical properties of textiles are of great importance in numerous applications, including infrared therapy and body thermoregulation. Tuning the spectral response of fabrics by the engineering of composite textile materials can produce fabrics targeted for use in these applications. We present spectroscopic data for engineered polyester fabric containing varying amounts of ceramic microparticles within the fiber core and report a spectrally-dependent shift in infrared reflectance, transmittance and absorptance. A thermal transport model is subsequently implemented to study the effect of these modified properties on the spectral distribution of infrared radiation incident upon the wearer of a garment constructed of this fabric.

  13. Fourier transform-infrared spectroscopy and Gas chromatography-mass spectroscopy: Reliable techniques for analysis of Parthenium mediated vermicompost

    Science.gov (United States)

    Rajiv, P.; Rajeshwari, Sivaraj; Venckatesh, Rajendran

    2013-12-01

    Fourier transform infrared spectroscopy (FT-IR) and Gas chromatography-mass spectroscopy have been carried out to investigate the chemical composition of Parthenium mediated vermicompost. Four different concentrations of Parthenium and cow dung mixtures were vermicomposted using the earthworms (Eudrilus eugeniae). FT-IR spectra reveal the absence of Parthenin toxin (sesquiterpene lactone) and phenols in vermicompost which was obtained from high concentration of cow dung mixed treatments. GC-MS analysis shows no phenolic compounds and predominant level of intermediate metabolites such as 4,8,12,16-Tetramethylheptadecan-4-olide (7.61%), 2-Pentadecanone, 6,10,14-trimethyl- (5.29%) and Methyl 16-methyl-heptadecanoate (4.69%) during the vermicomposting process. Spectral results indicated that Parthenin toxin and phenols can be eradicated via vermicomposting if mixed with appropriate quantity of cow dung.

  14. Ultrafast and nonlinear spectroscopy of brilliant green-based nanoGUMBOS with enhanced near-infrared emission

    Science.gov (United States)

    Karam, Tony E.; Siraj, Noureen; Zhang, Zhenyu; Ezzir, Abdulrahman F.; Warner, Isiah M.; Haber, Louis H.

    2017-10-01

    The synthesis, characterization, ultrafast dynamics, and nonlinear spectroscopy of 30 nm nanospheres of brilliant green-bis(pentafluoroethylsulfonyl)imide ([BG][BETI]) in water are reported. These thermally stable nanoparticles are derived from a group of uniform materials based on organic salts (nanoGUMBOS) that exhibit enhanced near-infrared emission compared with the molecular dye in water. The examination of ultrafast transient absorption spectroscopy results reveals that the overall excited-state relaxation lifetimes of [BG][BETI] nanoGUMBOS are longer than the brilliant green molecular dye in water due to steric hindrance of the torsional degrees of freedom of the phenyl rings around the central carbon. Furthermore, the second harmonic generation signal of [BG][BETI] nanoGUMBOS is enhanced by approximately 7 times and 23 times as compared with colloidal gold nanoparticles of the same size and the brilliant green molecular dye in water, respectively. A very clear third harmonic generation signal is observed from the [BG][BETI] nanoGUMBOS but not from either the molecular dye or the gold nanoparticles. Overall, these results show that [BG][BETI] nanoGUMBOS exhibit altered ultrafast and nonlinear spectroscopy that is beneficial for various applications including nonlinear imaging probes, biomedical imaging, and molecular sensing.

  15. Determination of the protein content in brine from salted herring using near-infrared spectroscopy

    DEFF Research Database (Denmark)

    Svensson, V.T.; Nielsen, Henrik Hauch; Bro, Rasmus

    2004-01-01

    Near-infrared reflectance (NIR) spectroscopy in the spectral range of 1000-2500 nm, was measured directly on brine from barrel salted herring, to investigate the potential of NIR as a fast method to determine the protein content. A principal component analysis performed on the NIR spectra shows two...... clearly indicate that NIR spectroscopy has a potential as a fast and noninvasive method for assessing the protein content in brine from barrel salted herring, which again may be used as an indicator for the ripening quality of barrel salted herring....

  16. Infrared and Raman spectroscopy and DFT calculations of DL amino acids: Valine and lysine hydrochloride

    Science.gov (United States)

    Paiva, F. M.; Batista, J. C.; Rêgo, F. S. C.; Lima, J. A.; Freire, P. T. C.; Melo, F. E. A.; Mendes Filho, J.; de Menezes, A. S.; Nogueira, C. E. S.

    2017-01-01

    Single crystals of DL-valine and DL-lysine hydrochloride were grown by slow evaporation method and the crystallographic structure were confirmed by X-ray diffraction experiment and Rietveld method. These two crystals have been studied by Raman spectroscopy in the 25-3600 cm-1 spectral range and by infrared spectroscopy through the interval 375-4000 cm-1 at room temperature. Experimental and theoretical vibrational spectra were compared and a complete analysis of the modes was done in terms of the Potential Energy Distribution (PED).

  17. Synergy Effect of Combining Fluorescence and Mid Infrared Fiber Spectroscopy for Kidney Tumor Diagnostics

    Directory of Open Access Journals (Sweden)

    Andrey Bogomolov

    2017-11-01

    Full Text Available Matching pairs of tumor and non-tumor kidney tissue samples of four patients were investigated ex vivo using a combination of two methods, attenuated total reflection mid infrared spectroscopy and fluorescence spectroscopy, through respectively prepared and adjusted fiber probes. In order to increase the data information content, the measurements on tissue samples in both methods were performed in the same 31 preselected positions. Multivariate data analysis revealed a synergic effect of combining the two methods for the diagnostics of kidney tumor compared to individual techniques.

  18. Moessbauer and infrared spectroscopy as a diagnostic tool for the characterization of ferric tannates

    Energy Technology Data Exchange (ETDEWEB)

    Jaen, Juan A., E-mail: jjaen@ancon.up.ac.p [Universidad de Panama, Depto. de Quimica Fisica, CITEN, Lab. No. 105, Edificio de Laboratorios Cientificos-VIP (Panama); Navarro, Cesar [Universidad de Panama, Escuela de Quimica, Facultad de Ciencias Naturales, Exactas y Tecnologia (Panama)

    2009-07-15

    Fourier transform infrared spectroscopy and Moessbauer spectroscopy are use for the characterization and qualitative analysis of hydrolysable and condensed tannates. The two classes of tannates may be differentiated from the characteristic IR pattern. Moessbauer proof that a mixture of mono- and bis-type ferric tannate complexes, and an iron(II)-tannin complex are obtained from the interaction of hydrolysable tannins (tannic acid and chestnut tannin) and condensed tannins (mimosa and quebracho) with a ferric nitrate solution. At pH 7, a partially hydrolyzed ferric tannate complex was also obtained.

  19. Research of Registration Approaches of Thermal Infrared Images and Intensity Images of Point Cloud

    Science.gov (United States)

    Liu, L.; Wei, Z.; Liu, X.; Yang, Z.

    2017-09-01

    In order to realize the analysis of thermal energy of the objects in 3D vision, the registration approach of thermal infrared images and TLS (Terrestrial Laser Scanner) point cloud was studied. The original data was pre-processed. For the sake of making the scale and brightness contrast of the two kinds of data meet the needs of basic matching, the intensity image of point cloud was produced and projected to spherical coordinate system, histogram equalization processing was done for thermal infrared image.This paper focused on the research of registration approaches of thermal infrared images and intensity images of point cloud based on SIFT EOH-SIFT and PIIFD operators. The latter of which is usually used for medical image matching with different spectral character. The comparison results of the experiments showed that PIIFD operator got much more accurate feature point correspondences compared to SIFT and EOH-SIFT operators. The thermal infrared image and intensity image also have ideal overlap results by quadratic polynomial transformation. Therefore, PIIFD can be used as the basic operator for the registration of thermal infrared images and intensity images, and the operator can also be further improved by incorporating the iteration method.

  20. RESEARCH OF REGISTRATION APPROACHES OF THERMAL INFRARED IMAGES AND INTENSITY IMAGES OF POINT CLOUD

    Directory of Open Access Journals (Sweden)

    L. Liu

    2017-09-01

    Full Text Available In order to realize the analysis of thermal energy of the objects in 3D vision, the registration approach of thermal infrared images and TLS (Terrestrial Laser Scanner point cloud was studied. The original data was pre-processed. For the sake of making the scale and brightness contrast of the two kinds of data meet the needs of basic matching, the intensity image of point cloud was produced and projected to spherical coordinate system, histogram equalization processing was done for thermal infrared image.This paper focused on the research of registration approaches of thermal infrared images and intensity images of point cloud based on SIFT,EOH-SIFT and PIIFD operators. The latter of which is usually used for medical image matching with different spectral character. The comparison results of the experiments showed that PIIFD operator got much more accurate feature point correspondences compared to SIFT and EOH-SIFT operators. The thermal infrared image and intensity image also have ideal overlap results by quadratic polynomial transformation. Therefore, PIIFD can be used as the basic operator for the registration of thermal infrared images and intensity images, and the operator can also be further improved by incorporating the iteration method.

  1. Variable Temperature Infrared Spectroscopy Studies of Aromatic Acid Adsorbate Effects on Montmorillonite Dehydration.

    Science.gov (United States)

    Ingram, Audrey L; Nickels, Tara M; Maraoulaite, Dalia K; White, Robert L

    2017-02-01

    Molecular interactions between benzoic, salicylic, and acetylsalicylic acids and water contained within montmorillonite clay interlayer spaces are characterized by using variable temperature diffuse reflection infrared Fourier transform spectroscopy (VT-DRIFTS). By using sample perturbation and difference spectroscopy, infrared (IR) spectral variations resulting from the removal of interlayer water are used to characterize aromatic acid local environment changes. Difference spectra features representing functional group perturbations are correlated with changes in IR absorptions associated with -O-H and -C = O stretching vibrations. Results suggest that adsorbate carboxylic acid functionalities participate in extensive hydrogen bonding and that the strengths of these interactions are diminished when clays are dehydrated. The nature of these interactions and their temperature-dependent properties are found to depend on adsorbate structure and concentration as well as the clay interlayer cation.

  2. Fourier-transform infrared spectroscopy (FTIR) analysis of triclinic and hexagonal birnessites

    Science.gov (United States)

    Ling, Florence T.; Post, Jeffrey E.; Heaney, Peter J.; Kubicki, James D.; Santelli, Cara M.

    2017-05-01

    The characterization of birnessite structures is particularly challenging for poorly crystalline materials of biogenic origin, and a determination of the relative concentrations of triclinic and hexagonal birnessite in a mixed assemblage has typically required synchrotron-based spectroscopy and diffraction approaches. In this study, Fourier-transform infrared spectroscopy (FTIR) is demonstrated to be capable of differentiating synthetic triclinic Na-birnessite and synthetic hexagonal H-birnessite. Furthermore, IR spectral deconvolution of peaks resulting from Mnsbnd O lattice vibrations between 400 and 750 cm- 1 yield results comparable to those obtained by linear combination fitting of synchrotron X-ray absorption fine structure (EXAFS) data when applied to known mixtures of triclinic and hexagonal birnessites. Density functional theory (DFT) calculations suggest that an infrared absorbance peak at 1628 cm- 1 may be related to OH vibrations near vacancy sites. The integrated intensity of this peak may show sensitivity to vacancy concentrations in the Mn octahedral sheet for different birnessites.

  3. Gastric cancer differentiation using Fourier transform near-infrared spectroscopy with unsupervised pattern recognition

    Science.gov (United States)

    Yi, Wei-song; Cui, Dian-sheng; Li, Zhi; Wu, Lan-lan; Shen, Ai-guo; Hu, Ji-ming

    2013-01-01

    The manuscript has investigated the application of near-infrared (NIR) spectroscopy for differentiation gastric cancer. The 90 spectra from cancerous and normal tissues were collected from a total of 30 surgical specimens using Fourier transform near-infrared spectroscopy (FT-NIR) equipped with a fiber-optic probe. Major spectral differences were observed in the CH-stretching second overtone (9000-7000 cm-1), CH-stretching first overtone (6000-5200 cm-1), and CH-stretching combination (4500-4000 cm-1) regions. By use of unsupervised pattern recognition, such as principal component analysis (PCA) and cluster analysis (CA), all spectra were classified into cancerous and normal tissue groups with accuracy up to 81.1%. The sensitivity and specificity was 100% and 68.2%, respectively. These present results indicate that CH-stretching first, combination band and second overtone regions can serve as diagnostic markers for gastric cancer.

  4. Rapid Detection of Volatile Oil in Mentha haplocalyx by Near-Infrared Spectroscopy and Chemometrics.

    Science.gov (United States)

    Yan, Hui; Guo, Cheng; Shao, Yang; Ouyang, Zhen

    2017-01-01

    Near-infrared spectroscopy combined with partial least squares regression (PLSR) and support vector machine (SVM) was applied for the rapid determination of chemical component of volatile oil content in Mentha haplocalyx. The effects of data pre-processing methods on the accuracy of the PLSR calibration models were investigated. The performance of the final model was evaluated according to the correlation coefficient (R) and root mean square error of prediction (RMSEP). For PLSR model, the best preprocessing method combination was first-order derivative, standard normal variate transformation (SNV), and mean centering, which had of 0.8805, of 0.8719, RMSEC of 0.091, and RMSEP of 0.097, respectively. The wave number variables linking to volatile oil are from 5500 to 4000 cm-1 by analyzing the loading weights and variable importance in projection (VIP) scores. For SVM model, six LVs (less than seven LVs in PLSR model) were adopted in model, and the result was better than PLSR model. The and were 0.9232 and 0.9202, respectively, with RMSEC and RMSEP of 0.084 and 0.082, respectively, which indicated that the predicted values were accurate and reliable. This work demonstrated that near infrared reflectance spectroscopy with chemometrics could be used to rapidly detect the main content volatile oil in M. haplocalyx. The quality of medicine directly links to clinical efficacy, thus, it is important to control the quality of Mentha haplocalyx. Near-infrared spectroscopy combined with partial least squares regression (PLSR) and support vector machine (SVM) was applied for the rapid determination of chemical component of volatile oil content in Mentha haplocalyx. For SVM model, 6 LVs (less than 7 LVs in PLSR model) were adopted in model, and the result was better than PLSR model. It demonstrated that near infrared reflectance spectroscopy with chemometrics could be used to rapidly detect the main content volatile oil in Mentha haplocalyx. Abbreviations used: 1(st) der: First

  5. Near-infrared-excited confocal Raman spectroscopy advances in vivo diagnosis of cervical precancer

    Science.gov (United States)

    Duraipandian, Shiyamala; Zheng, Wei; Ng, Joseph; Low, Jeffrey J. H.; Ilancheran, Arunachalam; Huang, Zhiwei

    2013-06-01

    Raman spectroscopy is a unique optical technique that can probe the changes of vibrational modes of biomolecules associated with tissue premalignant transformation. This study evaluates the clinical utility of confocal Raman spectroscopy over near-infrared (NIR) autofluorescence (AF) spectroscopy and composite NIR AF/Raman spectroscopy for improving early diagnosis of cervical precancer in vivo at colposcopy. A rapid NIR Raman system coupled with a ball-lens fiber-optic confocal Raman probe was utilized for in vivo NIR AF/Raman spectral measurements of the cervix. A total of 1240 in vivo Raman spectra [normal (n=993), dysplasia (n=247)] were acquired from 84 cervical patients. Principal components analysis (PCA) and linear discriminant analysis (LDA) together with a leave-one-patient-out, cross-validation method were used to extract the diagnostic information associated with distinctive spectroscopic modalities. The diagnostic ability of confocal Raman spectroscopy was evaluated using the PCA-LDA model developed from the significant principal components (PCs) [i.e., PC4, 0.0023% PC5, 0.00095% PC8, 0.00022%, (p<0.05)], representing the primary tissue Raman features (e.g., 854, 937, 1095, 1253, 1311, 1445, and 1654 cm-1). Confocal Raman spectroscopy coupled with PCA-LDA modeling yielded the diagnostic accuracy of 84.1% (a sensitivity of 81.0% and a specificity of 87.1%) for in vivo discrimination of dysplastic cervix. The receiver operating characteristic curves further confirmed that the best classification was achieved using confocal Raman spectroscopy compared to the composite NIR AF/Raman spectroscopy or NIR AF spectroscopy alone. This study illustrates that confocal Raman spectroscopy has great potential to improve early diagnosis of cervical precancer in vivo during clinical colposcopy.

  6. Analysis of Flavonoid in Medicinal Plant Extract Using Infrared Spectroscopy and Chemometrics

    OpenAIRE

    Lestyo Wulandari; Yuni Retnaningtyas; Nuri; Hilmia Lukman

    2016-01-01

    Infrared (IR) spectroscopy combined with chemometrics has been developed for simple analysis of flavonoid in the medicinal plant extract. Flavonoid was extracted from medicinal plant leaves by ultrasonication and maceration. IR spectra of selected medicinal plant extract were correlated with flavonoid content using chemometrics. The chemometric method used for calibration analysis was Partial Last Square (PLS) and the methods used for classification analysis were Linear Discriminant Analysis ...

  7. Infrared spectroscopy for studying structure and aging effects in rhamnolipid biosurfactants

    OpenAIRE

    Kiefer, Johannes; Radzuan, Mohd Nazren; Winterburn, James

    2017-01-01

    Biosurfactants are produced by microorganisms and represent amphiphilic compounds with polar and non-polar moieties; hence they can be used to stabilize emulsions, e.g. in the cosmetic and food sectors. Their structure and its changes when exposed to light and elevated temperature are yet to be fully understood. In this study, we demonstrate that attenuated total reflection infrared (ATR-IR) spectroscopy is a useful tool for the analysis of biosurfactants, using rhamnolipids produced by ferme...

  8. Measurement of blood glucose by infrared spectroscopy using hollow-optical fiber probe

    Science.gov (United States)

    Tanaka, Y.; Kino, S.; Matsuura, Y.

    2013-03-01

    An infrared spectroscopy system based on a hollow-optical fiber probe for measurement of blood glucose concentration is developed. The probe consists of a flexible hollow-optical fiber and an ATR prism attached at the distal end of the fiber. This flexible probe enables measurement of oral mucosa and ear lobes that have blood capillaries near the skin surface. Experimental results show that absorption peaks of blood glucose are detected by the system.

  9. Vasoconstrictor responses assessed by near-infrared spectroscopy during graded lower body negative pressure

    OpenAIRE

    Hachiya, Tesshin

    2006-01-01

    Pathients with rthostatic intolerance have difficulty during the transition from supine to upright. Even healthy people may exhibit nausea, dizziness, or headache during long periods of standing. Lower body negative pressure (LBNP) is often used to simulate orthostatic stress to elucidate orthostatic reflexes. Near-infrared spectroscopy (NIRS) is used in various research and clinical fields. NIRS monitors tissue oxygenation changes by measuring oxygenated and deoxygenated hemoglobin (Hb) and ...

  10. Near-infrared spectroscopy in schizophrenia: A possible biomarker for predicting clinical outcome and treatment response

    OpenAIRE

    Shinsuke eKoike; Yukika eNishimura; Ryu eTakizawa; Noriaki eYahata; Kiyoto eKasai

    2013-01-01

    Functional near-infrared spectroscopy (fNIRS) is a relatively new technique that can measure hemoglobin changes in brain tissues, and its use in psychiatry has been progressing rapidly. Although it has several disadvantages (e.g., relatively low spatial resolution and the possibility of shallow coverage in the depth of brain regions) compared with other functional neuroimaging techniques (e.g., functional magnetic resonance imaging and positron emission tomography), fNIRS may be a candidate i...

  11. Near-Infrared Spectroscopy in Schizophrenia: A Possible Biomarker for Predicting Clinical Outcome and Treatment Response

    OpenAIRE

    Koike, Shinsuke; NISHIMURA, Yukika; Takizawa, Ryu; Yahata, Noriaki; Kasai, Kiyoto

    2013-01-01

    Functional near-infrared spectroscopy (fNIRS) is a relatively new technique that can measure hemoglobin changes in brain tissues, and its use in psychiatry has been progressing rapidly. Although it has several disadvantages (e.g., relatively low spatial resolution and the possibility of shallow coverage in the depth of brain regions) compared with other functional neuroimaging techniques (e.g., functional magnetic resonance imaging and positron emission tomography), fNIRS may be a candidate i...

  12. Optical coherence tomography – near infrared spectroscopy system and catheter for intravascular imaging

    OpenAIRE

    Fard, Ali M.; Vacas-Jacques, Paulino; Hamidi, Ehsan; Wang, Hao; Carruth, Robert W.; Gardecki, Joseph A.; Tearney, Guillermo J.

    2013-01-01

    Owing to its superior resolution, intravascular optical coherence tomography (IVOCT) is a promising tool for imaging the microstructure of coronary artery walls. However, IVOCT does not identify chemicals and molecules in the tissue, which is required for a more complete understanding and accurate diagnosis of coronary disease. Here we present a dual-modality imaging system and catheter that uniquely combines IVOCT with diffuse near-infrared spectroscopy (NIRS) in a single dual-modality imagi...

  13. Use of near infrared spectroscopy for intramuscular fat selection in rabbits

    OpenAIRE

    ZOMEÑO, CRISTINA; HERNÁNDEZ, PILAR; BLASCO, AGUSTÍN

    2011-01-01

    The potential use of near infrared spectroscopy (NIRS) for the determination of intramuscular fat (IMF) content in rabbit selection programmes was evaluated. One hundred and thirty seven rabbits from three different synthetic lines slaughtered between 5 and 61 weeks of age were used for NIR calibration. Longissimus muscles (LM) were homogenised, freeze-dried and scanned by NIRS reflectance and total lipid content was chemically analysed. Calibration equation parameters reported appropriate...

  14. Near infrared reflectance spectroscopy for the determination of free gossypol in cottonseed meal

    OpenAIRE

    Lordelo, M.M.; Shaaban, S.A.; Dale, N.M.; Calhoun, M.C.; Vendrel, P.F.; Davis, A.J.

    2008-01-01

    Gossypol is a toxic polyphenolic compound produced by the pigment glands of the cotton plant. The free gossypol content of cottonseed meal (CSM) is commonly determined by the American Oil Chemists’ Society (AOCS) wet chemistry method. The AOCS method, however, laboratory-intensive, time-consuming, and therefore, not practical for quick field analyses. To determine if the free gossypol content of CSM could be predicted by near infrared reflectance spectroscopy (NIRS), CSM sample...

  15. Coherent two-dimensional infrared spectroscopy: Quantitative analysis of protein secondary structure in solution

    OpenAIRE

    Baiz, Carlos R.; Peng, Chunte; Reppert, Michael Earl; Jones, Kevin C; Tokmakoff, Andrei

    2011-01-01

    We present a method to quantitatively determine the secondary structure composition of globular proteins using coherent two-dimensional infrared (2DIR) spectroscopy of backbone amide I vibrations (1550–1720 cm−1). Sixteen proteins with known crystal structures were used to construct a library of 2DIR spectra, and the fraction of residues in α-helix, β-sheet, and unassigned conformations was determined by singular value decomposition (SVD) of the measured two-dimensional spectra. The method wa...

  16. Advances in near-infrared spectroscopy to study the brain of the preterm and term neonate

    DEFF Research Database (Denmark)

    Wolf, Martin; Greisen, Gorm

    2009-01-01

    This article reviews tissue oximetry and imaging to study the preterm and newborn infant brain by near-infrared spectroscopy. These two technologies are now advanced; nearly 100 reports on their use in newborn infants have been published, and commercial instruments are available. The precision...... of oximetry, however, is a limitation for its clinical use of assessing cerebral oxygenation. Imaging of brain function needs very well defined protocols for sensory stimulation as well as signal analysis to provide meaningful results....

  17. Multivariate Calibration Models for Sorghum Composition using Near-Infrared Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Wolfrum, E.; Payne, C.; Stefaniak, T.; Rooney, W.; Dighe, N.; Bean, B.; Dahlberg, J.

    2013-03-01

    NREL developed calibration models based on near-infrared (NIR) spectroscopy coupled with multivariate statistics to predict compositional properties relevant to cellulosic biofuels production for a variety of sorghum cultivars. A robust calibration population was developed in an iterative fashion. The quality of models developed using the same sample geometry on two different types of NIR spectrometers and two different sample geometries on the same spectrometer did not vary greatly.

  18. Infrared Spectroscopy and Catalysis Research: Infrared spectra of adsorbed molecules provide important information in the study of catalysis.

    Science.gov (United States)

    Eischens, R P

    1964-10-23

    The examples discussed here represent only a small part of the published work relating to infrared spectra of adsorbed molecules. The publications in this field indicate that infrared spectroscopy is being used for surface chemistry research in about 50 laboratories throughout the world. This effort is mainly devoted to problems related to catalysis, and in this field infrared spectroscopy is the most widely used physical tool for surface chemistry studies. The general acceptance of infrared spectroscopy is primarily due to the fact that it provides information which is pertinent to the understanding of surface reactions on an atomic scale. During the last decade significant progress has also been made in the classical chemical techniques of catalysis study and in utilization of physical tools which depend on phenomena of magnetism, conductivity, low-energy electron diffraction, and electron emission. Probably the most important progress has been in the field of inorganic chemistry, where dramatic advances have been made in knowledge of metal coordination compounds. Such knowledge is vital to the understanding of catalysis on metal surfaces. I believe this progress has produced an attitude of sophisticated optimism among catalysis researchers with regard to eventual understanding of heterogeneous catalysis. This attitude is closely related to the realization that there is no "secret of catalysis" which places catalytic action beyond the limits of ordinary chemical knowledge (22). This view implies that the chemical aspects of heterogeneous catalysis are not unique and that the use of solid catalysts merely provides a highly effective exposure of catalytic atoms and facilitates separation of the products from the catalyst. Many capable catalysis researchers believe that studies of homogeneous catalysis provide the most direct route for the study of heterogeneous catalysis. Obviously homogeneous reactions catalyzed by compounds containing only one or two metal atoms

  19. Diamond fly cutting of aluminum thermal infrared flat mirrors for the OSIRIS-REx Thermal Emission Spectrometer (OTES) instrument

    Science.gov (United States)

    Groppi, Christopher E.; Underhill, Matthew; Farkas, Zoltan; Pelham, Daniel

    2016-07-01

    We present the fabrication and measurement of monolithic aluminum flat mirrors designed to operate in the thermal infrared for the OSIRIS-Rex Thermal Emission Spectrometer (OTES) space instrument. The mirrors were cut using a conventional fly cutter with a large radius diamond cutting tool on a high precision Kern Evo 3-axis CNC milling machine. The mirrors were measured to have less than 150 angstroms RMS surface error.

  20. Developing a thermal characteristic index for lithology identification using thermal infrared remote sensing data

    Science.gov (United States)

    Wei, Jiali; Liu, Xiangnan; Ding, Chao; Liu, Meiling; Jin, Ming; Li, Dongdong

    2017-01-01

    In remote sensing petrology fields, studies have mainly concentrated on spectroscopy remote sensing research, and methods to identify minerals and rocks are mainly based on the analysis and enhancement of spectral features. Few studies have reported the application of thermodynamics for lithology identification. This paper aims to establish a thermal characteristic index (TCI) to explore rock thermal behavior responding to defined environmental systems. The study area is located in the northern Qinghai Province, China, on the northern edge of the Qinghai-Tibet Plateau, where mafic-ultramafic rock, quartz-rich rock, alkali granite rock and carbonate rock are well exposed; the pixel samples of these rocks and vegetation were obtained based on relevant indices and geological maps. The scatter plots of TCI indicate that mafic-ultramafic rock and quartz-rich rock can be well extracted from other surface objects when interference from vegetation is lower. On account of the complexity of environmental systems, three periods of TCI were used to construct a three-dimensional scatter plot, named the multi-temporal thermal feature space (MTTFS) model. Then, the Bayes discriminant analysis algorithm was applied to the MTTFS model to extract rocks quantitatively. The classification accuracy of mafic-ultramafic rock is more than 75% in both training data and test data, which suggests TCI can act as a sensitive indicator to distinguish rocks and the MTTFS model can accurately extract mafic-ultramafic rock from other surface objects. We deduce that the use of thermodynamics is promising in lithology identification when an effective index is constructed and an appropriated model is selected.