Thermal hazard assessment of AN and AN-based explosives.

Science.gov (United States)

Turcotte, R; Lightfoot, P D; Fouchard, R; Jones, D E G

2003-07-04

Ammonium nitrate (AN) is an essential ingredient in most fertilizers. It is also widely used in the commercial explosives industry. In this latter application, it is mostly mixed with fuel oil to form the most popular commercial explosive: ANFO. In both the fertilizer and the explosive industry, aqueous AN solutions (ANS) of various concentrations are processed. These solutions also form the basis of ammonium nitrate emulsion explosives (also called ammonium nitrate emulsions or ANE), which are produced either in bulk or in packaged form. For all these AN-based products, quantities of the order of 20,000kg are being manufactured, transported, stored, and processed at elevated temperatures and/or elevated pressures. Correspondingly, major accidents involving overheating of large quantities of these products have happened in several of these operations. In comparison, convenient laboratory quantities to investigate thermal decomposition properties are generally less than 1kg. As a result, in order to provide information applicable to real-life situations, any laboratory study must use techniques that minimize heat losses from the samples to their environment. In the present study, two laboratory-scale calorimeters providing an adiabatic environment were used: an accelerating rate calorimeter (ARC) and an adiabatic Dewar calorimeter (ADC). Experiments were performed on pure AN, ANFO, various ANS systems, and typical bulk and packaged ANE systems. The effects of sample mass, atmosphere, and formulation on the resulting onset temperatures were studied. A comparison of the results from the two techniques is provided and a proposed method to extrapolate these results to large-scale inventories is examined.

Thermal stability and mechanism of decomposition of emulsion explosives in the presence of pyrite.

Science.gov (United States)

Xu, Zhi-Xiang; Wang, Qian; Fu, Xiao-Qi

2015-12-30

The reaction of emulsion explosives (ammonium nitrate) with pyrite was studied using techniques of TG-DTG-DTA. TG-DSC-MS was also used to analyze samples thermal decomposition process. When a mixture of pyrite and emulsion explosives was heated at a constant heating rate of 10K/min from room temperature to 350°C, exothermic reactions occurred at about 200°C. The essence of reaction between emulsion explosives and pyrite is the reaction between ammonium nitrate and pyrite. Emulsion explosives have excellent thermal stability but it does not mean it showed the same excellent thermal stability when pyrite was added. Package emulsion explosives were more suitable to use in pyrite shale than bulk emulsion explosives. The exothermic reaction was considered to take place between ammonium nitrate and pyrite where NO, NO2, NH3, SO2 and N2O gases were produced. Based on the analysis of the gaseous, a new overall reaction was proposed, which was thermodynamically favorable. The results have significant implication in the understanding of stability of emulsion explosives in reactive mining grounds containing pyrite minerals. Copyright © 2015 Elsevier B.V. All rights reserved.

Modeling solid thermal explosion containment on reactor HNIW and HMX

International Nuclear Information System (INIS)

Lin, Chun-Ping; Chang, Chang-Ping; Chou, Yu-Chuan; Chu, Yung-Chuan; Shu, Chi-Min

2010-01-01

2,4,6,8,10,12-Hexanitro-2,4,6,8,10,12-hexaaza-isowurtzitane (HNIW), also known as CL-20 and octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX), are highly energetic materials which have been popular in national defense industries for years. This study established the models of thermal decomposition and thermal explosion hazard for HNIW and HMX. Differential scanning calorimetry (DSC) data were used for parameters determination of the thermokinetic models, and then these models were employed for simulation of thermal explosion in a 437 L barrel reactor and a 24 kg cubic box package. Experimental results indicating the best storage conditions to avoid any violent runaway reaction of HNIW and HMX were also discovered. This study also developed an efficient procedure regarding creation of thermokinetics and assessment of thermal hazards of HNIW and HMX that could be applied to ensure safe storage conditions.

Thermal stability and mechanism of decomposition of emulsion explosives in the presence of pyrite

International Nuclear Information System (INIS)

Xu, Zhi-Xiang; Wang, Qian; Fu, Xiao-Qi

2015-01-01

Highlights: • An exothermic reaction occurs at about 200 °C between pyrite and ammonium nitrate (emulsion explosives). • The essence of reaction between emulsion explosives and pyrite is reaction between ammonium nitrate and pyrite. • The excellent thermal stability of emulsion explosives does not mean it was also showed when pyrite was added. • A new overall reaction has been proposed as: • 14FeS_2(s) + 91NH_4NO_3(s) → 52NO(g) + 26SO_2(g) + 6Fe_2O_3(s) + 78NH_3(g) + 26N_2O(g) + 2FeSO_4(s) + 65H_2O(g). - Abstract: The reaction of emulsion explosives (ammonium nitrate) with pyrite was studied using techniques of TG-DTG-DTA. TG–DSC–MS was also used to analyze samples thermal decomposition process. When a mixture of pyrite and emulsion explosives was heated at a constant heating rate of 10 K/min from room temperature to 350 °C, exothermic reactions occurred at about 200 °C. The essence of reaction between emulsion explosives and pyrite is the reaction between ammonium nitrate and pyrite. Emulsion explosives have excellent thermal stability but it does not mean it showed the same excellent thermal stability when pyrite was added. Package emulsion explosives were more suitable to use in pyrite shale than bulk emulsion explosives. The exothermic reaction was considered to take place between ammonium nitrate and pyrite where NO, NO_2, NH_3, SO_2 and N_2O gases were produced. Based on the analysis of the gaseous, a new overall reaction was proposed, which was thermodynamically favorable. The results have significant implication in the understanding of stability of emulsion explosives in reactive mining grounds containing pyrite minerals.

Thermal stability and mechanism of decomposition of emulsion explosives in the presence of pyrite

Energy Technology Data Exchange (ETDEWEB)

Xu, Zhi-Xiang; Wang, Qian [School of Energy and Power Engineering, Jiangsu University, Zhenjiang 212013 (China); Fu, Xiao-Qi, E-mail: xzx19820708@163.com [School of Chemistry and Chemical Engineering, Jiangsu University Zhenjiang 212013 (China)

2015-12-30

Highlights: • An exothermic reaction occurs at about 200 °C between pyrite and ammonium nitrate (emulsion explosives). • The essence of reaction between emulsion explosives and pyrite is reaction between ammonium nitrate and pyrite. • The excellent thermal stability of emulsion explosives does not mean it was also showed when pyrite was added. • A new overall reaction has been proposed as: • 14FeS{sub 2}(s) + 91NH{sub 4}NO{sub 3}(s) → 52NO(g) + 26SO{sub 2}(g) + 6Fe{sub 2}O{sub 3}(s) + 78NH{sub 3}(g) + 26N{sub 2}O(g) + 2FeSO{sub 4}(s) + 65H{sub 2}O(g). - Abstract: The reaction of emulsion explosives (ammonium nitrate) with pyrite was studied using techniques of TG-DTG-DTA. TG–DSC–MS was also used to analyze samples thermal decomposition process. When a mixture of pyrite and emulsion explosives was heated at a constant heating rate of 10 K/min from room temperature to 350 °C, exothermic reactions occurred at about 200 °C. The essence of reaction between emulsion explosives and pyrite is the reaction between ammonium nitrate and pyrite. Emulsion explosives have excellent thermal stability but it does not mean it showed the same excellent thermal stability when pyrite was added. Package emulsion explosives were more suitable to use in pyrite shale than bulk emulsion explosives. The exothermic reaction was considered to take place between ammonium nitrate and pyrite where NO, NO{sub 2}, NH{sub 3}, SO{sub 2} and N{sub 2}O gases were produced. Based on the analysis of the gaseous, a new overall reaction was proposed, which was thermodynamically favorable. The results have significant implication in the understanding of stability of emulsion explosives in reactive mining grounds containing pyrite minerals.

Pressure Wave Measurements from Thermal Cook-Off of an HMX Based High Explosive PBX 9501

International Nuclear Information System (INIS)

Garcia, F.; Forbes, J.W.; Tarver, C.M.; Urtiew, P.A.; Greenwood, D.W.; Vandersall, K.S.

2001-01-01

A better understanding of thermal cook-off is important for safe handling and storing explosive devices. A number of safety issues exist about what occurs when a cased explosive thermally cooks off. For example, violence of the events as a function of confinement are important for predictions of collateral damage. This paper demonstrates how adjacent materials can be gauged to measure the resulting pressure wave and how this wave propagates in this adjacent material. The output pulse from the thermal cook-off explosive containing fixture is of obvious interest for assessing many scenarios

Safety engineering experiments of explosives

Energy Technology Data Exchange (ETDEWEB)

Ishikawa, Noboru

1987-07-24

The outline of large scale experiments carried out every year since 1969 to obtain fundamental data and then establish the safety engineering standards concerning the manufacturing, storage and transportation, etc. of all explosives was described. Because it becomes recently difficult to ensure the safety distance in powder magazines and powder plants, the sandwich structure with sand is thought to be suitable as the neighboring barrier walls. The special vertical structure for embankments to provide against a emergency explosion is effective to absorb the blast. Explosion behaviors such as initiating sensitivity, detonation, sympathetic detonation, and shock occurence of the ANFO explosives in place of dynamite and the slurry explosives were studied. The safety engineering standards for the manufacturing and application of explosives were studied to establish because accidents by tabacco fire are not still distinguished. Much data concerning early stage fire fighting, a large quantity of flooding and shock occurence from a assumption of ignition during machining in the propellants manufacturing plant, could be obtained. Basic studies were made to prevent pollution in blasting sites. Collected data are utilized for the safety administration after sufficient discussion. (4 figs, 2 tabs, 3 photos, 17 refs)

Thermal hazard assessment of AN and AN-based explosives

Energy Technology Data Exchange (ETDEWEB)

Turcotte, T.; Lightfoot, P. D.; Fouchard, R.; Jones, D. E. G. [Natural Resources Canada, CANMET Canadian Explosives Research Laboratory, Ottawa, ON (Canada)

2002-12-01

Ammonium-based aqeous solutions of various concentrations are processed in both the fertilizer and explosives industry, and ammonium nitrate emulsions form the basis of bulk ammonium nitrate emulsion explosives. Major accidents involving overheating of large quantities of these products are not uncommon. To provide guidance to handling large bulk quantities of these materials laboratory experiments must be carried out in such a way as to minimize heat losses from the samples. In this study experiments were performed on pure ammonium, the popular commercial explosive ANFO, various aqueous ammonium solutions and typical bulk and packaged ammonium nitrate emulsions, using two laboratory-scale calorimeters (accelerating rate calorimeter and adiabatic Dewar calorimeter). The objective of the experiments was to study the effects of sample mass, atmosphere, and formulation on the resulting onset temperatures. Result from the two techniques were compared and a method for extrapolating these results to large-scale inventories was proposed. 22 refs., 4 tabs., 14 figs.

Dimensional analysis of small-scale steam explosion experiments

International Nuclear Information System (INIS)

Huh, K.; Corradini, M.L.

1986-01-01

Dimensional analysis applied to Nelson's small-scale steam explosion experiments to determine the qualitative effect of each relevant parameter for triggering a steam explosion. According to experimental results, the liquid entrapment model seems to be a consistent explanation for the steam explosion triggering mechanism. The three-dimensional oscillatory wave motion of the vapor/liquid interface is analyzed to determine the necessary conditions for local condensation and production of a coolant microjet to be entrapped in fuel. It is proposed that different contact modes between fuel and coolant may involve different initiation mechanisms of steam explosions

First vapor explosion calculations performed with MC3D thermal-hydraulic code

Energy Technology Data Exchange (ETDEWEB)

Brayer, C.; Berthoud, G. [CEA Centre d`Etudes de Grenoble, 38 (France). Direction des Reacteurs Nucleaires

1998-01-01

This paper presents the first calculations performed with the `explosion` module of the multiphase computer code MC3D, which is devoted to the fine fragmentation and explosion phase of a fuel coolant interaction. A complete description of the physical laws included in this module is given. The fragmentation models, taking into account two fragmentation mechanisms, a thermal one and an hydrodynamic one, are also developed here. Results to some calculations to test the numerical behavior of MC3D and to test the explosion models in 1D or 2D are also presented. (author)

Influence of variable heat transfer coefficient of fireworks and crackers on thermal explosion critical ambient temperature and time to ignition

Directory of Open Access Journals (Sweden)

Guo Zerong

2016-01-01

Full Text Available To study the effect of variable heat transfer coefficient of fireworks and crackers on thermal explosion critical ambient temperature and time to ignition, considering the heat transfer coefficient as the power function of temperature, mathematical thermal explosion steady state and unsteady-state model of finite cylindrical fireworks and crackers with complex shell structures are established based on two-dimensional steady state thermal explosion theory. The influence of variable heat transfer coefficient on thermal explosion critical ambient temperature and time to ignition are analyzed. When heat transfer coefficient is changing with temperature and in the condition of natural convection heat transfer, critical ambient temperature lessen, thermal explosion time to ignition shorten. If ambient temperature is close to critical ambient temperature, the influence of variable heat transfer coefficient on time to ignition become large. For firework with inner barrel in example analysis, the critical ambient temperature of propellant is 463.88 K and the time to ignition is 4054.9s at 466 K, 0.26 K and 450.8s less than without considering the change of heat transfer coefficient respectively. The calculation results show that the influence of variable heat transfer coefficient on thermal explosion time to ignition is greater in this example. Therefore, the effect of variable heat transfer coefficient should be considered into thermal safety evaluation of fireworks to reduce potential safety hazard.

Installation for low temperature vapor explosion experiment

International Nuclear Information System (INIS)

Nilsuwankosit, Sunchai; Archakositt, Urith

2000-01-01

A preparation for the experiment on the low temperature vapor explosion was planned at the department of Nuclear Technology, Chulalongkorn University, Thailand. The objective of the experiment was to simulate the interaction between the molten fuel and the volatile cooling liquid without resorting to the high temperature. The experiment was expected to involve the injection of the liquid material at a moderate temperature into the liquid material with the very low boiling temperature in order to observe the level of the pressurization as a function of the temperatures and masses of the applied materials. For this purpose, the liquid nitrogen and the water were chosen as the coolant and the injected material for this experiment. Due to the size of the installation and the scale of the interaction, only lumped effect of various parameters on the explosion was expected from the experiment at this initial stage. (author)

mathematical model of thermal explosion, the dual variational formulation of nonlinear problem, alternative functional

Directory of Open Access Journals (Sweden)

V. S. Zarubin

2016-01-01

Full Text Available A temperature state of the solid body may depend both on the conditions of heat exchange with external environment surrounding its surface and on the energy release within the body volume, caused, for example, by the processes in nuclear reactor elements or exothermic chemical reactions, absorption of penetrating radiation energy or transformation of a part of the electrical power into heat with flowing electric current (so-called Joule heat.If with growing temperature the intensity of bulk power density increases, a limited steady temperature state can emerge at which heat extracted to the body surface and released within its volume reaches maximum. Thus, small increments of temperature lead to an increase of heat release, which can not be extracted to the body surface by conduction without further temperature increase. As a result, the steady temperature distribution in the body becomes impossible that determines the state of the thermal explosion, so named due to the fact that in this case the appropriate mathematical model predicts an unlimited temperature increase.A lot of published papers and monographs concerning the study of the combustion and explosion processes in a stationary medium analyse the thermal explosion state. The most famous papers consider a mathematical model to describe a temperature distribution in the case when heat release is because of exothermic chemical reactions the rate of which increases with temperature growth. The dependence of the chemical reaction rate on temperature is usually described by the exponential Arrhenius law, which makes it necessary to consider an essentially nonlinear mathematical model containing differential equation, which includes the term, nonlinearly rising with increasing temperature. Even with simplifying assumptions, this model allows an exact closed form solution only in the case of one-dimensional temperature distributions in the two areas of the canonical form: in the plate, infinite

Steam explosion triggering and efficiency studies

International Nuclear Information System (INIS)

Buxton, L.D.; Nelson, L.S.; Benedick, W.B.

1979-01-01

A program at Sandia Laboratories to provide relevant data on the interaction of molten LWR core materials with water is described. Two different subtasks were established. The first was the performance of laboratory-scale experiments to investigate the ability to trigger steam explosions for realistic LWR core melt simulants under a wide range of initial conditions. The second was the performance of field-scale experiments to investigate the efficiency of converting the thermal energy of the melt into mechanical work in much larger steam explosions

Background on the commercial explosive chosen for the non-proliferation experiment

Energy Technology Data Exchange (ETDEWEB)

Mammele, M.E.

1994-12-31

The requirements of the Chemical Kiloton Experiment as outlined in the original explosives bid package provided DYNO NOBEL/Alpha-Ireco, Inc. with a unique challenge. The size of the chamber, the total volume of explosives required, the chemical energy equivalent of one kiloton, the time-frame of loading the chamber, transportation, safety, were all necessary considerations in choosing this particular explosive. The rationale for choosing this particular emulsion/ANFO blend of blasting agent explosive will be presented. DYNO NOBEL INC in-house theoretical predictions as to the explosive performance potential of the blasting agent will be compared to some of the actual data acquired upon detonation. The results of this type of experiment may provide new insight as to the efficiency of the energy release of typical commercial explosives.

Detection of Nonvolatile Inorganic Oxidizer-Based Explosives from Wipe Collections by Infrared Thermal Desorption-Direct Analysis in Real Time Mass Spectrometry.

Science.gov (United States)

Forbes, Thomas P; Sisco, Edward; Staymates, Matthew

2018-05-07

Infrared thermal desorption (IRTD) was coupled with direct analysis in real time mass spectrometry (DART-MS) for the detection of both inorganic and organic explosives from wipe collected samples. This platform generated discrete and rapid heating rates that allowed volatile and semivolatile organic explosives to thermally desorb at relatively lower temperatures, while still achieving elevated temperatures required to desorb nonvolatile inorganic oxidizer-based explosives. IRTD-DART-MS demonstrated the thermal desorption and detection of refractory potassium chlorate and potassium perchlorate oxidizers, compounds difficult to desorb with traditional moderate-temperature resistance-based thermal desorbers. Nanogram to sub-nanogram sensitivities were established for analysis of a range of organic and inorganic oxidizer-based explosive compounds, with further enhancement limited by the thermal properties of the most common commercial wipe materials. Detailed investigations and high-speed visualization revealed conduction from the heated glass-mica base plate as the dominant process for heating of the wipe and analyte materials, resulting in thermal desorption through boiling, aerosolization, and vaporization of samples. The thermal desorption and ionization characteristics of the IRTD-DART technique resulted in optimal sensitivity for the formation of nitrate adducts with both organic and inorganic species. The IRTD-DART-MS coupling and IRTD in general offer promising explosive detection capabilities to the defense, security, and law enforcement arenas.

The evolution of solid density within a thermal explosion II. Dynamic proton radiography of cracking and solid consumption by burning

International Nuclear Information System (INIS)

Smilowitz, L.; Henson, B. F.; Romero, J. J.; Asay, B. W.; Saunders, A.; Merrill, F. E.; Morris, C. L.; Kwiatkowski, K.; Grim, G.; Mariam, F.; Schwartz, C. L.; Hogan, G.; Nedrow, P.; Murray, M. M.; Thompson, T. N.; Espinoza, C.; Lewis, D.; Bainbridge, J.; McNeil, W.; Rightley, P.

2012-01-01

We report proton transmission images obtained subsequent to the laser assisted thermal ignition of a sample of PBX 9501 (a plastic bonded formulation of the explosive nitramine octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX)). We describe the laser assisted thermal ignition technique as a means to synchronize a non-linear thermal ignition event while preserving the subsequent post-ignition behavior. We have obtained dynamic proton transmission images at two spatial magnifications and viewed both the radial and transverse axis of a solid cylindrical sample encased in aluminum. Images have been obtained with 3 to 15 μs temporal resolution and approximately 100 μm spatial resolution at the higher magnification. We observe case expansion from very early in the experiment, until case fragmentation. We observe spatially anisotropic features in the transmission which we attribute to cracking in the solid explosive, in agreement with previous measurements conducted on two dimensional samples with optical viewing. Digital analysis of the images also reveals spatially isotropic features which we attribute to the evolution of the loss of density by burning subsequent to thermal ignition.

The evolution of solid density within a thermal explosion II. Dynamic proton radiography of cracking and solid consumption by burning

Energy Technology Data Exchange (ETDEWEB)

Smilowitz, L.; Henson, B. F.; Romero, J. J.; Asay, B. W.; Saunders, A.; Merrill, F. E.; Morris, C. L.; Kwiatkowski, K.; Grim, G.; Mariam, F.; Schwartz, C. L.; Hogan, G.; Nedrow, P.; Murray, M. M.; Thompson, T. N.; Espinoza, C.; Lewis, D.; Bainbridge, J.; McNeil, W.; Rightley, P. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); and others

2012-05-15

We report proton transmission images obtained subsequent to the laser assisted thermal ignition of a sample of PBX 9501 (a plastic bonded formulation of the explosive nitramine octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX)). We describe the laser assisted thermal ignition technique as a means to synchronize a non-linear thermal ignition event while preserving the subsequent post-ignition behavior. We have obtained dynamic proton transmission images at two spatial magnifications and viewed both the radial and transverse axis of a solid cylindrical sample encased in aluminum. Images have been obtained with 3 to 15 {mu}s temporal resolution and approximately 100 {mu}m spatial resolution at the higher magnification. We observe case expansion from very early in the experiment, until case fragmentation. We observe spatially anisotropic features in the transmission which we attribute to cracking in the solid explosive, in agreement with previous measurements conducted on two dimensional samples with optical viewing. Digital analysis of the images also reveals spatially isotropic features which we attribute to the evolution of the loss of density by burning subsequent to thermal ignition.

Soviet experience with peaceful uses of nuclear explosions

International Nuclear Information System (INIS)

Nordyke, M.D.

1976-01-01

The Soviet Union is pursuing an active program for developing peaceful uses of nuclear explosions (PNE). They have reported 16 explosions, with applications ranging from putting out oil-well fires and stimulating oil recovery to creating instant dams and canals. The data reported generally agree with U.S. experience. Seismic data collected by western sources on explosions outside the known Soviet test sites indicate that the Soviet program is at least twice as large as they have reported. The accelerated pace of these events suggests that in some applications the Soviet PNE program is approaching routine industrial technology

Steam explosion triggering and efficiency studies

International Nuclear Information System (INIS)

Buxton, L.D.; Nelson, L.S.; Benedick, W.B.

1979-01-01

Laboratory experiments on the thermal interaction of simulated light water reactor (LWR) fuel melts and water are summarized. Their purpose was to investigate the possibility of steam explosions occurring for a range of hypothetical accident conditions. Pressure, temperature, hot liquid motion and cold liquid motion were monitored during the experiments

An effect of corium composition variations on occurrence of a steam explosion in the TROI experiments

International Nuclear Information System (INIS)

Kim, J. W.; Park, I. K.; Hong, S. W.; Min, B. T.; Shin, Y. S.; Song, J. H.; Kim, H. D.

2003-01-01

Recently series of steam explosion experiments have been performed in the TROI facility using corium melts of various compositions. The compositions (UO 2 : ZrO 2 ) of the corium were 0 : 100, 50 : 50, 70 : 30, 80 : 20 and 87 : 13 in weight percent and the mass of the corium was about 10kg. An experiment using 0 : 100 corium (pure zirconia) caused a steam explosion. An experiment using 50 : 50 corium did not cause a steam explosion while a steam spike occurred in an experiment using 70 : 30 corium which was the eutectic point of corium. A steam spike is considered to be the fact that a triggering of a steam explosion occurred but a propagation process does not occur so as to cause a weak interaction. However, the possibility of a steam explosion with this composition can not be ruled out since many steam explosions occurred in the previous experiments. In the two experiments using 80 : 20 corium, a steam spike occurred in one experiment but no steam explosion occurred in the other experiment. However, the triggerability of a steam explosion with this composition is not clear since few steam explosions occurred in the previous experiments. And no steam explosion occurred in an experiment using 87 : 13 corium of which urania content was the greatest among the experiments performed in the TROI facility. From this, the possibility of a steam explosion or a steam spike is appeared to be high in the non-mush zone. It is considered that an explosive interaction could easily occur with the eutectic composition. Since the solidification temperature around the eutectic point is low, the melt is likely to maintain its liquid state at the time of triggering so as to cause an explosive phenomenon

DETERMINING OF THERMAL STABILITY OF EXPLOSIVES FOR CIVIL USES MODERN EQUIPMENT EQUIPPED WITH AUTOMATIC TEMPERATURE AND PRESSURE

Directory of Open Access Journals (Sweden)

Gabriel VASILESCU

2015-07-01

Full Text Available Thermal stability of explosives for civil use is a key security parameter. When the explosive is exposed to high tempera-tures in a given period of time can lead to undesirable phenomena such as decomposing or even very dangerous as un-controlled detonation.

Trace level detection of explosives in solution using leidenfrost phenomenon assisted thermal desorption ambient mass spectrometry.

Science.gov (United States)

Saha, Subhrakanti; Mandal, Mridul Kanti; Chen, Lee Chuin; Ninomiya, Satoshi; Shida, Yasuo; Hiraoka, Kenzo

2013-01-01

The present paper demonstrates the detection of explosives in solution using thermal desorption technique at a temperature higher than Leidenfrost temperature of the solvent in combination with low temperature plasma (LTP) ionization. Leidenfrost temperature of a solvent is the temperature above which the solvent droplet starts levitation instead of splashing when placed on a hot metallic surface. During this desorption process, slow and gentle solvent evaporation takes place, which leads to the pre-concentration of less-volatile explosive molecules in the droplet and the explosive molecules are released at the last moment of droplet evaporation. The limits of detection for explosives studied by using this thermal desorption LTP ionization method varied in a range of 1 to 10 parts per billion (ppb) using a droplet volume of 20 μL (absolute sample amount 90-630 fmol). As LTP ionization method was applied and ion-molecule reactions took place in ambient atmosphere, various ion-molecule adduct species like [M+NO2](-), [M+NO3](-), [M+HCO3](-), [M+HCO4](-) were generated together with [M-H](-) peak. Each peak was unambiguously identified using 'Exactive Orbitrap' mass spectrometer in negative ionization mode within 3 ppm deviation compared to its exact mass. This newly developed technique was successfully applied to detect four explosives contained in the pond water and soil sample with minor sample pre-treatment and the explosives were detected with ppb levels. The present method is simple, rapid and can detect trace levels of explosives with high specificity from solutions.

Shock Initiation of Damaged Explosives

Energy Technology Data Exchange (ETDEWEB)

Chidester, S K; Vandersall, K S; Tarver, C M

2009-10-22

Explosive and propellant charges are subjected to various mechanical and thermal insults that can increase their sensitivity over the course of their lifetimes. To quantify this effect, shock initiation experiments were performed on mechanically and thermally damaged LX-04 (85% HMX, 15% Viton by weight) and PBX 9502 (95% TATB, 5% Kel-F by weight) to obtain in-situ manganin pressure gauge data and run distances to detonation at various shock pressures. We report the behavior of the HMX-based explosive LX-04 that was damaged mechanically by applying a compressive load of 600 psi for 20,000 cycles, thus creating many small narrow cracks, or by cutting wedge shaped parts that were then loosely reassembled, thus creating a few large cracks. The thermally damaged LX-04 charges were heated to 190 C for long enough for the beta to delta solid - solid phase transition to occur, and then cooled to ambient temperature. Mechanically damaged LX-04 exhibited only slightly increased shock sensitivity, while thermally damaged LX-04 was much more shock sensitive. Similarly, the insensitive explosive PBX 9502 was mechanically damaged using the same two techniques. Since PBX 9502 does not undergo a solid - solid phase transition but does undergo irreversible or 'rachet' growth when thermally cycled, thermal damage to PBX 9502 was induced by this procedure. As for LX-04, the thermally damaged PBX 9502 demonstrated a greater shock sensitivity than mechanically damaged PBX 9502. The Ignition and Growth reactive flow model calculated the increased sensitivities by igniting more damaged LX-04 and PBX 9502 near the shock front based on the measured densities (porosities) of the damaged charges.

Advancing Explosion Source Theory through Experimentation: Results from Seismic Experiments Since the Moratorium on Nuclear Testing

Science.gov (United States)

Bonner, J. L.; Stump, B. W.

2011-12-01

On 23 September 1992, the United States conducted the nuclear explosion DIVIDER at the Nevada Test Site (NTS). It would become the last US nuclear test when a moratorium ended testing the following month. Many of the theoretical explosion seismic models used today were developed from observations of hundreds of nuclear tests at NTS and around the world. Since the moratorium, researchers have turned to chemical explosions as a possible surrogate for continued nuclear explosion research. This talk reviews experiments since the moratorium that have used chemical explosions to advance explosion source models. The 1993 Non-Proliferation Experiment examined single-point, fully contained chemical-nuclear equivalence by detonating over a kiloton of chemical explosive at NTS in close proximity to previous nuclear explosion tests. When compared with data from these nearby nuclear explosions, the regional and near-source seismic data were found to be essentially identical after accounting for different yield scaling factors for chemical and nuclear explosions. The relationship between contained chemical explosions and large production mining shots was studied at the Black Thunder coal mine in Wyoming in 1995. The research led to an improved source model for delay-fired mining explosions and a better understanding of mining explosion detection by the International Monitoring System (IMS). The effect of depth was examined in a 1997 Kazakhstan Depth of Burial experiment. Researchers used local and regional seismic observations to conclude that the dominant mechanism for enhanced regional shear waves was local Rg scattering. Travel-time calibration for the IMS was the focus of the 1999 Dead Sea Experiment where a 10-ton shot was recorded as far away as 5000 km. The Arizona Source Phenomenology Experiments provided a comparison of fully- and partially-contained chemical shots with mining explosions, thus quantifying the reduction in seismic amplitudes associated with partial

Unconfined deflagrative explosions without turbulence: experiments and model

International Nuclear Information System (INIS)

Lannoy, A.

1989-01-01

This paper reviews laboratory, balloon and open field experiments which have been performed to study the deflagration regime in free air. In a first part, are considered different models available to estimate deflagrative unconfined explosions effects, without turbulence. Then, a description is given of the known performed tests, which indicate the effective scale of various experiments, their operating conditions and the type of measurements carried out. Results are presented and discussed. The influence on the explosion force of different parameters (fuel concentration gradients, flammable mixture shape and size, ignition energy) is estimated. The overall conclusion of this survey is that flammable mixtures drifting over open field and ignited, will burn with low flame speed and consequently will generate very weak pressure effects [fr

Observations of Tin/Water Thermal Explosions in a Long-Tube Geometry. Their Interpretation and Consequences for the Detonation Model

International Nuclear Information System (INIS)

Hall, R.W.; Board, S.J.; Baines, M.

1979-01-01

This paper presents details of experiments designed to test the detonation model of thermal explosions (Board et al, 1975); on this theory large-scale explosions should propagate steadily at supersonic velocities through a fuel coolant mixture, giving a yield which has been shown to depend on details of the fragmentation and heat transfer behind the shock front. Observations of propagating explosions have been reported previously. In the present work, a long-tube geometry is used since in 1D, propagation measurements are particularly easy to interpret. Also, in 2D and 3D geometries radial flow can tend to extinguish shock waves and if a single-phase region of coolant is present, pressure pulses can propagate ahead of the two-phase shock in the intermixed region. This paper describes the six experiments that all use molten tin and water mixtures. In the first four, detailed pressure measurement was the main objective; the last two are attempts at flow visualization to aid the interpretation of these. The results obtained and the implications for the detonation model are discussed. A detailed interpretation in terms of fragmentation and heat transfer processes behind the shock is attempted. The implications of the work for reactor materials are then briefly outlined

Comparing CTH simulations and experiments on explosively loaded rings

Science.gov (United States)

Braithwaite, C. H.; Aydelotte, Brady; Collins, Adam; Thadhani, Naresh; Williamson, David Martin

2012-03-01

A series of experiments were conducted on explosively loaded metallic rings for the purpose of studying fragmentation. In addition to the collection of fragments for analysis, the radial velocity of the expanding ring was measured with photon Doppler velocimetry (PDV) and the arrangement was imaged using high speed photography. Both the ring material and the material used as the explosive container were altered and the results compared with simulations performed in CTH. Good agreement was found between the simulations and the experiments. The maximum radial velocity attained was approximately 380 m/s, which was achieved through loading with a 5g PETN based charge.

Reliability analysis for thermal cutting method based non-explosive separation device

International Nuclear Information System (INIS)

Choi, Jun Woo; Hwang, Kuk Ha; Kim, Byung Kyu

2016-01-01

In order to increase the reliability of a separation device for a small satellite, a new non-explosive separation device is invented. This device is activated using a thermal cutting method with a Ni-Cr wire. A reliability analysis is carried out for the proposed non-explosive separation device by applying the Fault tree analysis (FTA) method. In the FTA results for the separation device, only ten single-point failure modes are found. The reliability modeling and analysis for the device are performed considering failure of the power supply, the Ni-Cr wire burns failure and unwinds, the holder separation failure, the balls separation failure, and the pin release failure. Ultimately, the reliability of the proposed device is calculated as 0.999989 with five Ni-Cr wire coils

Reliability analysis for thermal cutting method based non-explosive separation device

Energy Technology Data Exchange (ETDEWEB)

Choi, Jun Woo; Hwang, Kuk Ha; Kim, Byung Kyu [Korea Aerospace University, Goyang (Korea, Republic of)

2016-12-15

In order to increase the reliability of a separation device for a small satellite, a new non-explosive separation device is invented. This device is activated using a thermal cutting method with a Ni-Cr wire. A reliability analysis is carried out for the proposed non-explosive separation device by applying the Fault tree analysis (FTA) method. In the FTA results for the separation device, only ten single-point failure modes are found. The reliability modeling and analysis for the device are performed considering failure of the power supply, the Ni-Cr wire burns failure and unwinds, the holder separation failure, the balls separation failure, and the pin release failure. Ultimately, the reliability of the proposed device is calculated as 0.999989 with five Ni-Cr wire coils.

Steam explosion - physical foundations and relation to nuclear reactor safety

International Nuclear Information System (INIS)

Schumann, U.

1982-08-01

'Steam explosion' means the sudden evaporation of a fluid by heat exchange with a hotter material. Other terms are 'vapour explosion', 'thermal explosion', and 'energetic fuel-coolant interaction (FCI)'. In such an event a large fraction of the thermal energy initially stored in the hot material may possibly be converted into mechanical work. For pressurized water reactors one discusses (e.g. in risk analysis studies) a core melt-down accident during which molten fuel comes into contact with water. In the analysis of the consequences one has to investigate steam explosions. In this report an overview over the state of the knowledge is given. The overview is based on an extensive literature review. The objective of the report is to provide the basic knowledge which is required for understanding of the most important theories on the process of steam explosions. Following topics are treated: overview on steam explosion incidents, work potential, spontaneous nucleation, concept of detonation, results of some typical experiments, hydrodynamic fragmentation of drops, bubbles and jets, coarse mixtures, film-boiling, scenario of a core melt-down accident with possible steam-explosion in a pressurized water reactor. (orig.) [de

Analysis of KROTOS KS-2 and KS-4 steam explosion experiments with TEXAS-VI

Energy Technology Data Exchange (ETDEWEB)

Chen, Ronghua, E-mail: rhchen@mail.xjtu.edu.cn [State Key Laboratory of Multiphase Flow in Power Engineering, School of Nuclear Science and Technology, Xi’an Jiaotong University, Xi’an 710049 (China); Wang, Jun [Nuclear Engineering and Engineering Physics, College of Engineering, University of Wisconsin Madison, WI 53706 (United States); Su, G.H.; Qiu, Suizheng [State Key Laboratory of Multiphase Flow in Power Engineering, School of Nuclear Science and Technology, Xi’an Jiaotong University, Xi’an 710049 (China); Corradini, M.L., E-mail: Corradini@engr.wisc.edu [Nuclear Engineering and Engineering Physics, College of Engineering, University of Wisconsin Madison, WI 53706 (United States)

2016-12-01

Highlights: • The KS-2 and KS-4 steam explosion experiments were analyzed by TEXAS-VI. • The coarse mixing status up to the explosion triggering time was well predicted by TEXAS-VI. • The predicted dynamic explosion pressure was in good agreement with the experimental results. - Abstract: TEXAS-VI is a transient, three-field, one-dimensional mechanistic model for the steam explosion phenomena. A fuel solidification model and associated fragmentation criteria of the solidifying particle for both the mixing phase and explosion phase were developed and incorporated into TEXAS-VI to account for solidification. In the present study, TEXAS-VI was used to analyze the KS-2 and KS-4 steam explosion experiments, which were performed in the KROTOS facility as part of the OECD-SERENA-2 program. In the simulation, the KROTOS experimental facility was modeled as Eulerian control volumes based on the facility geometry. The molten corium jet was divided up into a series of LaGrangian master particles equal to the initial jet diameter. Both the mixing phase and the explosion phase of the experiments were simulated by TEXAS-VI. Comparison to test data indicates that the fuel jet kinematics and the vapor volume during the mixing phase were well predicted by TEXAS-VI. The TEXAS-VI prediction of the dynamic explosion pressure at different axial locations in the test was also in good agreement with the experimental results. The maximum pressure of KS-2 and KS-4 predicted by TEXAS-VI were 16.7 MPa and 41.9 MPa, respectively. The KS-4 maximum steam explosion pressure predicted by TEXAS-VI was higher than that of KS-2, which was consistent with experiment observation. The observed differences of the dynamic explosion pressure between the KS-2 and KS-4 experiments were also successfully simulated by TEXAS-VI. This suggests that TEXAS-VI is able to analyze the effect of prototypic melt compositions on the steam explosion phenomena. Additional benchmarking and evaluations are ongoing.

Steam explosions of single drops of pure and alloyed molten aluminum

International Nuclear Information System (INIS)

Nelson, L.S.

1995-01-01

Studies of steam explosion phenomena have been performed related to the hypothetical meltdown of the core and other components of aluminum alloy-fueled production reactors. Our objectives were to characterise the triggers, if any, required to initiate these explosions and to determine the energetics and chemical processes associated with these events. Three basic studies have been carried out with 1-10 g single drops of molten aluminum or aluminum-based alloys: untriggered experiments in which drops of melt were released into water; triggered experiments in which thermal-type steam explosions occurred; and one triggered experiment in which an ignition-type steam explosion occurred. In untriggered experiments, spontaneous steam explosions never occurred during the free fall through water of single drops of pure Al or of the alloys studied here. Moreover, spontaneous explosions never occurred upon or during contact of the globules with several underwater surfaces. When Li was present in the alloy, H 2 was generated as a stream of bubbles as the globules fell through the water, and also as they froze on the bottom surface of the chamber. The triggered experiments were performed with pure Al and the 6061 alloy. Bare bridgewire discharges and those focused with cylindrical reflectors produced a small first bubble that collapsed and was followed by a larger second bubble. When the bridgewire was discharged at one focus of an ellipsoidal reflector, a melt drop at the other focus triggered only very mildly in spite of a 30-fold increase in peak pressure above that of the bridgewire discharge without the reflector. Experiments were also performed with globules of high purity Al in which the melt release temperature was progressively increased. Moderate thermal-type explosions were produced over the temperature range 1273-1673 K. At about 1773 K, however, one experiment produced a brilliant flash of light and bubble growth about an order of magnitude faster than normal; it

Modeling of thermal explosion under pressure in metal ceramic systems

International Nuclear Information System (INIS)

Shapiro, M.; Dudko, V.; Skachek, B.; Matvienko, A.; Gotman, I.; Gutmanas, E.Y.

1998-01-01

The process of reactive in situ synthesis of dense ceramic matrix composites in Ti-B-C, Ti-B-N, Ti-Si-N systems is modeled. These ceramics are fabricated on the basis of compacted blends of ceramic powders, namely Ti-B 4 C and/or Ti-BN. The objectives of the project are to identify and investigate the optimal thermal conditions preferable for production of fully dense ceramic matrix composites. Towards this goal heat transfer and combustion in dense and porous ceramic blends are investigated during monotonous heating at a constant rate. This process is modeled using a heat transfer-combustion model with kinetic parameters determined from the differential thermal analysis of the experimental data. The kinetic burning parameters and the model developed are further used to describe the thermal explosion synthesis in a restrained die under pressure. It is shown that heat removal from the reaction zone affects the combustion process and the final phase composition

Detonation and fragmentation modeling for the description of large scale vapor explosions

International Nuclear Information System (INIS)

Buerger, M.; Carachalios, C.; Unger, H.

1985-01-01

The thermal detonation modeling of large-scale vapor explosions is shown to be indispensable for realistic safety evaluations. A steady-state as well as transient detonation model have been developed including detailed descriptions of the dynamics as well as the fragmentation processes inside a detonation wave. Strong restrictions for large-scale vapor explosions are obtained from this modeling and they indicate that the reactor pressure vessel would even withstand explosions with unrealistically high masses of corium involved. The modeling is supported by comparisons with a detonation experiment and - concerning its key part - hydronamic fragmentation experiments. (orig.) [de

Mechanical efficiency of the energy release during a steam explosion

International Nuclear Information System (INIS)

Krieg, R.

1997-01-01

The mechanical processes during the expansion phase of a steam explosion with intimately fragmented liquid particles is investigated based on elementary principles and analytical solutions. During a short load pulse, the different densities of the water and the melted particles lead to different velocities. After the load pulse, viscosity effects lead to a slow down of the higher velocities and to a corresponding reconversion of the kinetic energy of the mixture into thermal energy. It is shown that both effects are proportional to each other. The ratio between the residual and the applied mechanical energy is defined as the mechanical efficiency of the steam explosion. Using data typical for a steam explosion in a pressurized water reactor, mechanical efficiencies of <50% are estimated. Considering that the thermodynamic efficiencies are quite limited, the very low conversion rates from thermal energy into mechanical energy observed during steam explosion experiments can be more easily understood

Modeling a High Explosive Cylinder Experiment

Science.gov (United States)

Zocher, Marvin A.

2017-06-01

Cylindrical assemblies constructed from high explosives encased in an inert confining material are often used in experiments aimed at calibrating and validating continuum level models for the so-called equation of state (constitutive model for the spherical part of the Cauchy tensor). Such is the case in the work to be discussed here. In particular, work will be described involving the modeling of a series of experiments involving PBX-9501 encased in a copper cylinder. The objective of the work is to test and perhaps refine a set of phenomenological parameters for the Wescott-Stewart-Davis reactive burn model. The focus of this talk will be on modeling the experiments, which turned out to be non-trivial. The modeling is conducted using ALE methodology.

Disappearance of criticality in branched-chain thermal explosion with heat loss

International Nuclear Information System (INIS)

Okoya, Samuel S.

2003-09-01

In the framework of the currently developed branched-chain thermal explosion theory, the equation governing leakage through a hole of a reaction vessel is given. The critical ignition, extinction and transition temperature excess, activation energy parameter and modified Semenov's number are estimated employing this equation. We calculated numerically and obtained analytically these non-dimensional parameters with and without initiation respectively. The similar solution for Semenov model appear as a limiting case of our solution. We also obtained the ignition times. (author)

Simulation of first SERENA KROTOS steam explosion experiment

International Nuclear Information System (INIS)

Leskovar, Matjaz; Ursic, Mitja

2009-01-01

A steam explosion may occur when, during a severe reactor accident, the molten core comes into contact with the coolant water. A strong enough steam explosion in a nuclear power plant could jeopardize the containment integrity and so lead to a direct release of radioactive material to the environment. To resolve the open issues in steam explosion understanding and modeling, the OECD program SERENA Phase 2 was launched at the end of year 2007, focusing on nuclear applications. SERENA comprises an experimental program, which is being carried out in the complementary KROTOS and TROI corium facilities, accompanied by a comprehensive analytical program, where also pre- and post-test calculations are foreseen. In the paper the sensitivity post-test calculations of the first SERENA KROTOS experiment KS-1, which were performed with the code MC3D, are presented and discussed. Since the results of the SERENA tests are restricted to SERENA members, only the various calculation results are given, not comparing them to experimental measurements. Various premixing and explosion simulations were performed on a coarse and a fine numerical mesh, applying two different jet breakup models (global, local) and varying the minimum bubble diameter in the explosion simulations (0.5 mm, 5 mm). The simulations revealed that all varied parameters have a significant influence on the calculation results, as was expected since the fuel coolant interaction process is a highly complex phenomenon. The results of the various calculations are presented in comparison and the observed differences are discussed and explained. (author)

Vapor Explosions with Subcooled Freon

International Nuclear Information System (INIS)

Henry, R.E.; Fauske, Hans K.; McUmber, L.M.

1976-01-01

Explosive vapor formation accompanied by destructive shock waves, can be produced when two liquids, at much different temperatures, are brought into intimate contact. A proposed analytical model states that the interface temperature upon contact between the two liquid systems, gust be greater than or equal to the spontaneous nucleation temperature of that liquid-liquid system and that the thermal boundary layer must be sufficiently developed to support a critical size cavity. For time scales greater than 10-12 sec, the interface temperature upon contact of two semi-infinite masses, with constant thermal properties, can be related to the initial liquid temperatures. The spontaneous nucleation behavior at the interface can either be heterogeneous or homogeneous in nature. In either case, the critical size cavities, which initiate the vaporization process, are produced by local density fluctuations within the cold liquid. For homogeneous conditions, the two liquids present a well-wetted system and the vapor embryos are produced entirely within the cold liquid. For heterogeneous conditions, which result from poor, or imperfect wetting, at the liquid-liquid interface, the critical sized cavities are created at the interface at somewhat lower temperatures. A sequence of experiments, using Freon-22 and water, Freon-22 and mineral oil, and Freon-12 and mineral oil have been performed to test this spontaneous nucleation premise. For Freon-22 at its normal boiling point, the interface temperature of the water must be at least 77 deg. C before the interface temperature equals or exceeds the minimum homogeneous nucleation value of 54 deg. C and 84 deg. C before the interface temperature equals 60 deg. C where the homogeneous nucleation rate becomes truly explosive. The Freon-water test demonstrated explosive interactions for water temperatures considerably lower than this value and this was attributed to the heterogeneous nucleation characteristics of that particular system

Results of measurements of thermal interaction between molten metal and water

International Nuclear Information System (INIS)

Zyszkowski, W.

1975-10-01

The report describes results of an experimental investigation into thermal interaction of molten metals with water. The experiments were performed in two stages: the aim of the first stage was to study the general character of thermal interaction between molten metal and water and to measure the Leidenfrost temperature of the inverse Leidenfrost phenomenon. The second stage was directed to the experimental study of the triggering mechanism of thermal explosion. The experimental material gathered in this study includes: 1) transient temperature measurements in the hot material and in water, 2) measurements of pressure and reactive force combined with thermal explosion, 3) high-speed films of thermal interaction, 4) investigation results of thermal explosion debris (microscopic, mechanical, metallographical and chemical). The most significant observation is, that small jets from the main particle mass occuring 1 to 10 msec before, precede thermal explosion. (orig.) [de

Small scale thermal violence experiments for combined insensitive high explosive and booster materials

Energy Technology Data Exchange (ETDEWEB)

Rae, Philip J [Los Alamos National Laboratory; Bauer, Clare L [AWE, UK; Stennett, C [DCMT SHRIVENHAM, UK; Flower, H M [AWE, UK

2010-01-01

A small scale cook-off experiment has been designed to provide a violence metric for both booster and IHE materials, singly and in combination. The experiment has a simple, axisymmetric geometry provided by a 10 mm internal diameter cylindrical steel confinement up to 80 mm in length. Heating is applied from one end of the sample length creating pseudo 1-D heating profile and a thermal gradient across the sample(s). At the opposite end of the confinement to the heating block, a machined groove provides a point of rupture that generates a cylindrical fragment. The displacement of the external face of the fragment is detected by Heterodyne Velocimetry. Proof of concept experiments are reported focusing on HMX and TATB formulations, and are described in relation to confinement, ullage and heating profile. The development of a violence metric, based upon fragment velocity records is discussed.

Thermal explosion analysis of methyl ethyl ketone peroxide by non-isothermal and isothermal calorimetric applications

International Nuclear Information System (INIS)

Chi, Jen-Hao; Wu, Sheng-Hung; Shu, Chi-Min

2009-01-01

In the past, process incidents attributed to organic peroxides (OPs) that involved near misses, over-pressures, runaway reactions, and thermal explosions occurred because of poor training, human error, incorrect kinetic assumptions, insufficient change management, and inadequate chemical knowledge in the manufacturing process. Calorimetric applications were employed broadly to test organic peroxides on a small-scale because of their thermal hazards, such as exothermic behavior and self-accelerating decomposition in the laboratory. In essence, methyl ethyl ketone peroxide (MEKPO) is highly reactive and exothermically unstable. In recent years, it has undergone many thermal explosions and runaway reaction incidents in the manufacturing process. Differential scanning calorimetry (DSC), vent sizing package 2 (VSP2), and thermal activity monitor (TAM) were employed to analyze thermokinetic parameters and safety index. The intent of the analyses was to facilitate the use of various auto-alarm equipments to detect over-pressure, over-temperature, and hazardous materials leaks for a wide spectrum of operations. Results indicated that MEKPO decomposition is detected at low temperatures (30-40 deg. C), and the rate of decomposition was shown to exponentially increase with temperature and pressure. Determining time to maximum rate (TMR), self-accelerating decomposition temperature (SADT), maximum temperature (T max ), exothermic onset temperature (T 0 ), and heat of decomposition (ΔH d ) was essential for identifying early-stage runaway reactions effectively for industries.

Thermochemistry of mixed explosives

International Nuclear Information System (INIS)

Janney, J.L.; Rogers, R.N.

1982-01-01

In order to predict thermal hazards of high-energy materials, accurate kinetics constants must be determined. Predictions of thermal hazards for mixtures of high-energy materials require measurements on the mixtures, because interactions among components are common. A differential-scanning calorimeter (DSC) can be used to observe rate processes directly, and isothermal methods enable detection of mechanism changes. Rate-controlling processes will change as components of a mixture are depleted, and the correct depletion function must be identified for each specific stage of a complex process. A method for kinetics measurements on mixed explosives can be demonstrated with Composition B is an approximately 60/40 mixture of RDX and TNT, and is an important military explosive. Kinetics results indicate that the mator process is the decomposition of RDX in solution in TNT with a perturbation caused by interaction between the two components. It is concluded that a combination of chemical kinetics and experimental self-heating procedures provides a good approach to the production of predictive models for thermal hazards of high-energy materials. Systems involving more than one energy-contributing component can be studied. Invalid and dangerous predictive models can be detected by a failure of agreement between prediction and experiment at a specific size, shape, and density. Rates of thermal decomposition for Composition B appear to be modeled adequately for critical-temperature predictions with the following kinetics constants: E = 180.2 kJ mole -1 and Z = 4.62 X 10 16 s -1

Hydrodynamics of Explosion Experiments and Models

CERN Document Server

Kedrinskii, Valery K

2005-01-01

Hydronamics of Explosion presents the research results for the problems of underwater explosions and contains a detailed analysis of the structure and the parameters of the wave fields generated by explosions of cord and spiral charges, a description of the formation mechanisms for a wide range of cumulative flows at underwater explosions near the free surface, and the relevant mathematical models. Shock-wave transformation in bubbly liquids, shock-wave amplification due to collision and focusing, and the formation of bubble detonation waves in reactive bubbly liquids are studied in detail. Particular emphasis is placed on the investigation of wave processes in cavitating liquids, which incorporates the concepts of the strength of real liquids containing natural microinhomogeneities, the relaxation of tensile stress, and the cavitation fracture of a liquid as the inversion of its two-phase state under impulsive (explosive) loading. The problems are classed among essentially nonlinear processes that occur unde...

Study on the thermal ignition of gasoline-air mixture in underground oil depots based on experiment and numerical simulation

Science.gov (United States)

Ou, Yihong; Du, Yang; Jiang, Xingsheng; Wang, Dong; Liang, Jianjun

2010-04-01

The study on the special phenomenon, occurrence process and control mechanism of gasoline-air mixture thermal ignition in underground oil depots is of important academic and applied value for enriching scientific theories of explosion safety, developing protective technology against fire and decreasing the number of fire accidents. In this paper, the research on thermal ignition process of gasoline-air mixture in model underground oil depots tunnel has been carried out by using experiment and numerical simulation methods. The calculation result has been demonstrated by the experiment data. The five stages of thermal ignition course, which are slow oxidation stage, rapid oxidation stage, fire stage, flameout stage and quench stage, have been firstly defined and accurately descried. According to the magnitude order of concentration, the species have been divided into six categories, which lay the foundation for explosion-proof design based on the role of different species. The influence of space scale on thermal ignition in small-scale space has been found, and the mechanism for not easy to fire is that the wall reflection causes the reflux of fluids and changes the distribution of heat and mass, so that the progress of chemical reactions in the whole space are also changed. The novel mathematical model on the basis of unification chemical kinetics and thermodynamics established in this paper provides supplementary means for the analysis of process and mechanism of thermal ignition.

The effect of explosive percentage on underwater explosion energy release of hexanitrohexaazaisowurtzitane and octogen based aluminized explosives

OpenAIRE

Qingjie Jiao; Qiushi Wang; Jianxin Nie; Xueyong Guo; Wei Zhang; Wenqi Fan

2018-01-01

To control the explosion energy output by optimizing explosive components is a key requirement in a number of different application areas. The effect of different Al/O Ratio on underwater explosion of aluminized explosives has been studied detailedly. However, the effect of explosive percentage in the same Al/O Ratio is rarely researched, especially for Hexanitrohexaazaisowurtzitane (CL-20) based aluminized explosives. In this study, we performed the underwater explosion experiments with 1.2-...

Explosive Infrasonic Events: Sensor Comparison Experiment (SCE)

Energy Technology Data Exchange (ETDEWEB)

Schnurr, J. M. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Garces, M. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Rodgers, A. J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

2017-02-06

SCE (sensor comparison experiment) 1 through 4 consists of a series of four controlled above-ground explosions designed to provide new data for overpressure propagation. Infrasound data were collected by LLNL iPhones and other sensors. Origin times, locations HOB, and yields are not being released at this time and are therefore not included in this report. This preliminary report will be updated as access to additional data changes, or instrument responses are determined.

Predicting Large-scale Effects During Cookoff of Plastic-Bonded Explosives (PBX 9501 PBX 9502 and LX-14)

Energy Technology Data Exchange (ETDEWEB)

Hobbs, Michael L. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Kaneshige, Michael J. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Erikson, William W. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

2017-10-01

In this study, we have made reasonable cookoff predictions of large-scale explosive systems by using pressure-dependent kinetics determined from small-scale experiments. Scale-up is determined by properly accounting for pressure generated from gaseous decomposition products and the volume that these reactive gases occupy, e.g. trapped within the explosive, the system, or vented. The pressure effect on the decomposition rates has been determined for different explosives by using both vented and sealed experiments at low densities. Low-density explosives are usually permeable to decomposition gases and can be used in both vented and sealed configurations to determine pressure-dependent reaction rates. In contrast, explosives that are near the theoretical maximum density (TMD) are not as permeable to decomposition gases, and pressure-dependent kinetics are difficult to determine. Ignition in explosives at high densities can be predicted by using pressure-dependent rates determined from the low-density experiments as long as gas volume changes associated with bulk thermal expansion are also considered. In the current work, cookoff of the plastic-bonded explosives PBX 9501 and PBX 9502 is reviewed and new experimental work on LX-14 is presented. Reactive gases are formed inside these heated explosives causing large internal pressures. The pressure is released differently for each of these explosives. For PBX 9501, permeability is increased and internal pressure is relieved as the nitroplasticizer melts and decomposes. Internal pressure in PBX 9502 is relieved as the material is damaged by cracks and spalling. For LX-14, internal pressure is not relieved until the explosive thermally ignites. The current paper is an extension of work presented at the 26th ICDERS symposium [1].

Rock Springs Site 12 hydraulic/explosive true in situ oil shale fracturing experiment

Energy Technology Data Exchange (ETDEWEB)

Parrish, R.L.; Boade, R.R.; Stevens, A.L.; Long, A. Jr.; Turner, T.F.

1980-06-01

The experiment plan involved the creation and characterization of three horizontal hydraulic fractures, followed by the insertion and simultaneous detonation of slurry explosive in the two lower fractures. Core analyses, wellbore logging, and airflow and /sup 85/Kr tracer tests were used for site characterization and assessment of the hydraulic and explosive fracturing. Tiltmeters, wellhead pressure and flow gages, and in-formation pressure, flow and crack-opening sensors were used to monitor hydrofracture creation and explosive insertion. Explosive detonation diagnostic data were taken with stress and time-of-arrival gages and surface and in-formation accelerometers. The post-fracturing assessments indicated that: (1) hydrofracture creation and explosive insertion and detonation were accomplished essentially as planned; (2) induced fractures were randomly distributed through the shale with no extensively fractured regions or dislocation of shale; and (3) enhancement of permeability was limited to enlargement of the explosive-filled fractures.

Thermal chemical-mechanical reactive flow model of shock initiation in solid explosives

International Nuclear Information System (INIS)

Nicholls, A.L. III; Tarver, C.M.

1998-01-01

The three dimensional Arbitrary Lagrange Eulerian hydrodynamic computer code ALE3D with fully coupled thermal-chemical-mechanical material models provides the framework for the development of a physically realistic model of shock initiation and detonation of solid explosives. The processes of hot spot formation during shock compression, subsequent ignition of reaction or failure to react, growth of reaction in individual hot spots, and coalescence of reacting hot spots during the transition to detonation can now be modeled using Arrhenius chemical kinetic rate laws and heat transfer to propagate the reactive flow. This paper discusses the growth rates of reacting hot spots in HMX and TATB and their coalescence during shock to detonation transition. Hot spot deflagration rates are found to be fast enough to consume explosive particles less than 10 mm in diameter during typical shock duration times, but larger particles must fragment and create more reactive surface area in order to be rapidly consumed

Investigation of coal dust explosion hazard at the Nikola Tesla-A thermal power station

Energy Technology Data Exchange (ETDEWEB)

Golubovic, D

1987-10-01

Reports on investigations into coal dust explosion hazards in working places with high coal dust exposure, done in the Tesla-A thermal power station by Mining Institute of Belgrade specialists. Settled and floating coal dust concentrations were monitored for six months and samples analyzed for explosibility under lab conditions. Samples from transport and preparation facilities and the power station boiler house were taken. The entire plant was divided into 4 zones, depending on intensity of dust settlement and ventilation system. Coal dust generation varied from 0.3-65 g/min. Daily dust settlement ranged between 40 and 300 g/m/sup 2/. Total quantity of accumulated coal dust in the power plant ranged from 0.8-650 kg/day; 250 g/m/sup 3/ of coal dust may cause an explosion. Thus, a dangerous amount of coal dust, depending on work-site, will settle in 3.3.-21.8 days. Disturbance of settled dust may create explodable clouds. Details of measurements taken and data evaluation are included. 4 refs.

DHS small-scale safety and thermal testing of improvised explosives-comparison of testing performance

International Nuclear Information System (INIS)

Reynolds, J G; Hsu, P C; Sandstrom, M M; Brown, G W; Warner, K F; Phillips, J J; Shelley, T J; Reyes, J A

2014-01-01

One of the first steps in establishing safe handling procedures for explosives is small-scale safety and thermal (SSST) testing. To better understand the response of improvised materials or homemade explosives (HMEs) to SSST testing, 16 HME materials were compared to three standard military explosives in a proficiency-type round robin study among five laboratories-two DoD and three DOE-sponsored by DHS. The testing matrix has been designed to address problems encountered with improvised materials-powder mixtures, liquid suspensions, partially wetted solids, immiscible liquids, and reactive materials. More than 30 issues have been identified that indicate standard test methods may require modification when applied to HMEs to derive accurate sensitivity assessments needed for developing safe handling and storage practices. This paper presents a generalized comparison of the results among the testing participants, comparison of friction results from BAM (German Bundesanstalt für Materi-alprüfung) and ABL (Allegany Ballistics Laboratory) designed testing equipment, and an overview of the statistical results from the RDX (1,3,5-Trinitroperhydro-1,3,5-triazine) standard tested throughout the proficiency test.

Thermal safety characterization on PETN, PBX-9407, LX-10-2, LX-17-1 and detonator in the LLNL's P-ODTX system

Energy Technology Data Exchange (ETDEWEB)

Hsu, P. C. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Strout, S. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Reynolds, J. G. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Kahl, E. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Ellsworth, F. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Healy, T. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

2017-09-21

Incidents caused by fire and other thermal events can heat energetic materials that may lead to thermal explosion and result in structural damage and casualty. Thus, it is important to understand the response of energetic materials to thermal insults. The One-Dimensional-Time to Explosion (ODTX) system at the Lawrence Livermore National Laboratory (LLNL) has been used for decades to characterize thermal safety of energetic materials. In this study, an integration of a pressure monitoring element has been added into the ODTX system (P-ODTX) to perform thermal explosion (cook-off) experiments (thermal runaway) on PETN powder, PBX-9407, LX-10-2, LX-17-1, and detonator samples (cup tests). The P-ODTX testing generates useful data (thermal explosion temperature, thermal explosion time, and gas pressures) to assist with the thermal safety assessment of relevant energetic materials and components. This report summarizes the results of P-ODTX experiments that were performed from May 2015 to July 2017. Recent upgrades to the data acquisition system allows for rapid pressure monitoring in microsecond intervals during thermal explosion. These pressure data are also included in the report.

Research on the fundamental process of thermal-hydraulic behaviors in severe accident. Estimation of trigger condition for vapor explosion. JAERI's nuclear research promotion program, H10-027-1. Contract research

International Nuclear Information System (INIS)

Nariai, Hideki

2002-03-01

The experimental and analytical researches were conducted to study melted core material and coolant interaction including solidification and vapor explosion which is one of the most unidentified thermal hydraulic phenomena during sever accident of nuclear reactor. At first, the effect of the material properties on vapor explosion and solidification was examined to clarify the dominant factors for the spontaneous vapor explosion. Next, the interfacial phenomena of the high temperature melt material and violent boiling behavior of water at the interface was visually observed in the experiment. The interfacial phenomena were physically modeled. Finally, trigger phenomena from liquid-liquid contact to atomization were clarified through the forced collapse experiment of vapor film around a molten droplet by using pressure wave generation device. It is indicated by applying the results obtained in the present study to the actual reactor conditions that the possibility of the vapor explosion is extremely unlikely in the actual reactor accident sequence, since the surface of the molten uranium oxide is solidified in the water and the liquid-liquid contact can not be achieved. It should be noted that the decrease of the solidified temperature by metal compounds and the increase of the molten core temperature. (author)

Multiparametric Experiments and Multiparametric Setups for Metering Explosive Eruptions

Science.gov (United States)

Taddeucci, J.; Scarlato, P.; Del Bello, E.

2016-12-01

Explosive eruptions are multifaceted processes best studied by integrating a variety of observational perspectives. This need marries well with the continuous stream of new means that technological progress provides to volcanologists to parameterize these eruptions. Since decades, new technologies have been tested and integrated approaches have been attempted during so-called multiparametric experiments, i.e., short field campaigns with many, different instruments (and scientists) targeting natural laboratory volcanoes. Recently, portable multiparametric setups have been developed, including a few, highly complementary instruments to be rapidly deployed at any erupting volcano. Multiparametric experiments and setups share most of their challenges, like technical issues, site logistics, and data processing and interpretation. Our FAMoUS (FAst MUltiparametric Setup) setup pivots around coupled, high-speed imaging (visible and thermal) and acoustic (infrasonic to audible) recording, plus occasional seismic recording and sample collection. FAMoUS provided new insights on pyroclasts ejection and settling and jet noise dynamics at volcanoes worldwide. In the last years we conducted a series of BAcIO (Broadband ACquisition and Imaging Operation) experiments at Stromboli (Italy). These hosted state-of-the-art and prototypal eruption-metering technologies, including: multiple high-speed high-definition cameras for 3-D imaging; combined visible-infrared-ultraviolet imaging; in-situ and remote gas measurements; UAV aerial surveys; Doppler radar, and microphone arrays. This combined approach provides new understandings of the fundamental controls of Strombolian-style activity, and allows for crucial cross-validation of instruments and techniques. Several documentary expeditions participated in the BAcIO, attesting its tremendous potential for public outreach. Finally, sharing field work promotes interdisciplinary discussions and cooperation like nothing in the world.

Nuclear explosive driven experiments

International Nuclear Information System (INIS)

Ragan, C.E.

1981-01-01

Ultrahigh pressures are generated in the vicinity of a nuclear explosion. We have developed diagnostic techniques to obtain precise high pressures equation-of-state data in this exotic but hostile environment

ALPHA visual data collection. STX005-025: melt drop steam explosion experiments

International Nuclear Information System (INIS)

Moriyama, Kiyofumi; Yamano, Norihiro; Maruyama, Yu; Kudo, Tamotsu; Sugimoto, Jun

1999-03-01

Steam explosion is a phenomenon in which a high temperature liquid gives its internal energy to a low temperature volatile liquid extremely quickly causing rapid evaporation and shock wave generation. In the field of nuclear reactor safety research regarding severe accidents in LWRs, steam explosions involving molten fuel and coolant has been recognized as a potential threat to the integrity of the reactor containment vessel. In the ALPHA (Assessment of Loads and Performance of Containment in Hypothetical Accident) program, experiments were performed to investigate the phenomenology of vapor explosions using iron-alumina thermite melt as a simulant of molten core. This report collects the experimental results especially emphasizing the visual observations by high speed photography. (author)

Comparison of the Effects of Thermal Pretreatment, Steam Explosion and Ultrasonic Disintegration on Digestibility of Corn Stover

Directory of Open Access Journals (Sweden)

Andras Dallos

2016-06-01

Full Text Available The energy demand of the corn-based bioethanol production could be reduced using the agricultural byproducts as bioenergy feedstock for biogas digesters. The release of lignocellulosic material and therefore the acceleration of degradation processes can be achieved using thermal and mechanical pretreatments, which assist to hydrolyze the cell walls and speed the solubilization of biopolymers in biogas feedstock. This study is focused on liquid hot water, steam explosion and ultrasonic pretreatments of corn stover. The scientific contribution of this paper is a comprehensive comparison of the performance of the pretreatments by fast analytical, biochemical, anaerobic digestibility and biomethane potential tests, extended by energy consumptions and energy balance calculations.The effectiveness of pretreatments was evaluated by means of soluble chemical oxygen demand, biochemical oxygen demand and by the biogas and methane productivities. The results have shown that the thermal pretreatment, steam explosion and ultrasonic irradiation of biogas feedstock disintegrated the lignocellulosic structure, increased and accelerated the methane production and increased the cumulative biogas and methane productivity of corn stover in reference to the control during mesophilic anaerobic digestion.The energy balance demonstrated that there is an economical basis of the application of the liquid hot-compressed water pretreatments in a biogas plant. However, the steam explosion and ultrasonication are energetically not profitable for corn stover pretreatment.

Research on the fundamental process of thermal-hydraulic behaviors in severe accident. Estimation of trigger condition for vapor explosion. JAERI's nuclear research promotion program, H10-027-1. Contract research

Energy Technology Data Exchange (ETDEWEB)

Nariai, Hideki [Tsukuba Univ., Institute of Engineering Mechanics and Systems, Tsukuba, Ibaraki (Japan)

2002-03-01

The experimental and analytical researches were conducted to study melted core material and coolant interaction including solidification and vapor explosion which is one of the most unidentified thermal hydraulic phenomena during sever accident of nuclear reactor. At first, the effect of the material properties on vapor explosion and solidification was examined to clarify the dominant factors for the spontaneous vapor explosion. Next, the interfacial phenomena of the high temperature melt material and violent boiling behavior of water at the interface was visually observed in the experiment. The interfacial phenomena were physically modeled. Finally, trigger phenomena from liquid-liquid contact to atomization were clarified through the forced collapse experiment of vapor film around a molten droplet by using pressure wave generation device. It is indicated by applying the results obtained in the present study to the actual reactor conditions that the possibility of the vapor explosion is extremely unlikely in the actual reactor accident sequence, since the surface of the molten uranium oxide is solidified in the water and the liquid-liquid contact can not be achieved. It should be noted that the decrease of the solidified temperature by metal compounds and the increase of the molten core temperature. (author)

A Novel Design of Rescue Capsule considering the Pressure Characteristics and Thermal Dynamic Response with Thermomechanical Coupling Action Subjected to Gas Explosion Load

Directory of Open Access Journals (Sweden)

Xiaowei Zhai

2017-01-01

Full Text Available To ensure the structural safety and reliability of coal mine rescue capsule in disastrous surroundings after gas explosion, in this paper, the thermomechanical coupling effect on a certain structure subjected to gas explosion was analyzed, and then a novel rescue capsule with a combination of radius and square features was designed according to the underground surroundings and relevant regulations on mine rescue devices. Foremost, the coupling mechanism of thermal-fluid-solid interaction between gas explosion shock wave and rescue capsule and the thermal dynamic response of the capsule subjected to explosion load of gas/air mixture was investigated and revealed by employing LS-DYNA. The variation laws and characteristics of stress field, displacement field, and temperature field of the capsule were analyzed based on the simulation results. Results show that the structural safety, tightness, and reliability of the capsule meet the requirements of the national safety regulations. The design method presented in this work provides a new thought for design of coal mine rescue capsule.

Cause finding experiments and environmental analysis on the accident of the fire and explosion in TRP bituminization facility

International Nuclear Information System (INIS)

Fujine, Sachio; Murata, Mikio; Abe, Hitoshi

1999-09-01

This report is the summary of the cause finding experiments and environmental analysis on the accident of the fire and explosion occurred at March 11th, 1997, in TRP bituminization facility of PNC (Power Reactor and Nuclear Fuel Development Corporation). Regarding the cause finding experiments, chemical components have been analyzed for the effluent samples taken from PNC's facility, bituminized mock waste has been produced using the simulated salt effluent prepared according to the results of chemical analysis, thermal analysis and experiment of runaway exothermic reaction have been conducted using the mock waste, and the component of flammable gases emitted from the heated waste have been collected and analyzed. Regarding environmental analysis on the accident, the amount of radioactive cesium released by the accident has been calculated by the comparative analysis using the atmospheric dispersion simulation code SPEEDI with the data of environmental monitoring and the public dose has been assessed. (author)

New ANFO explosives made of ammonium nitrate of increased porosity and naphtha

Energy Technology Data Exchange (ETDEWEB)

Kutsarov, B.; Mavrodieva, R.; Ivanov, I.; Stoyanov, V.; Georgiev, N.; Krumov, I.; Katsarski, I.; Vakliev, I.

1990-01-01

Discusses results achieved by the KNIIPPI Niproruda Research Institute and the Osogovo enterprise in improving the quality of ANFO explosives. Ammonium nitrate with increased porosity was treated by water steam and wetting agents and then thermally treated. Naphtha in a quantity of up to 8% was then added to the ammonium nitrate to produce a powerful and stable explosive. The quality of explosive cartridges was tested first in the laboratory using the Schaffler apparatus. Test results were very satisfactory (better porosity, higher detonation velocity (2200-3600 m/s), better stability). Industrial experiments carried out in several underground mines also produced satisfactory results (better output in roadway drivage at lower operating cost and better safety). 8 refs.

Thermal-hydraulics of wave propagation and pressure distribution under hypothetical steam explosion conditions in the ANS reactor

Energy Technology Data Exchange (ETDEWEB)

Taleyarkhan, R.P.; Georgevich, V.; N-Valenit, S.; Kim, S.H. [Oak Ridge National Lab., TN (United States)

1995-09-01

This paper describes salient aspects of the modeling and analysis framework for evaluation of dynamic loads, wave propagation, and pressure distributions (under hypothetical steam explosion conditions) around key structural boundaries of the Advanced Neutron Source (ANS) reactor core region. A staged approach was followed, using simple thermodynamic models for bounding loads and the CTH code for evaluating realistic estimates in a staged multidimensional framework. Effects of nodalization, melt dispersal into coolant during explosion, single versus multidirectional dissipation, energy level of melt, and rate of energy deposition into coolant were studied. The importance of capturing multidimensional effects that simultaneously account for fluid-structural interactions was demonstrated. As opposed to using bounding loads from thermodynamic evaluations, it was revealed that the ANS reactor system will not be vulnerable to vertically generated missiles that threaten containment if realistic estimates of energetics are used (from CTH calculations for thermally generated steam explosions without significant aluminum ignition).

Weapons Experiments Division Explosives Operations Overview

Energy Technology Data Exchange (ETDEWEB)

Laintz, Kenneth E. [Los Alamos National Laboratory

2012-06-19

Presentation covers WX Division programmatic operations with a focus on JOWOG-9 interests. A brief look at DARHT is followed by a high level overview of explosives research activities currently being conducted within in the experimental groups of WX-Division. Presentation covers more emphasis of activities and facilities at TA-9 as these efforts have been more traditionally aligned with ongoing collaborative explosive exchanges covered under JOWOG-9.

Improve the Anaerobic Biodegradability by Copretreatment of Thermal Alkali and Steam Explosion of Lignocellulosic Waste

Directory of Open Access Journals (Sweden)

Muhammad Abdul Hanan Siddhu

2016-01-01

Full Text Available Effective alteration of the recalcitrance properties like crystallization of cellulose, lignin shield, and interlinking of lignocellulosic biomass is an ideal way to utilize the full-scale potential for biofuel production. This study exhibited three different pretreatment effects to enhance the digestibility of corn stover (CS for methane production. In this context, steam explosion (SE and thermal potassium hydroxide (KOH-60°C treated CS produced the maximal methane yield of 217.5 and 243.1 mL/gvs, which were 40.0% and 56.4% more than untreated CS (155.4 mL/gvs, respectively. Copretreatment of thermal potassium hydroxide and steam explosion (CPTPS treated CS was highly significant among all treatments and improved 88.46% (292.9 mL/gvs methane yield compared with untreated CS. Besides, CPTPS also achieved the highest biodegradability up to 68.90%. Three kinetic models very well simulated dynamics of methane production yield. Moreover, scanning electron microscopy (SEM, Fourier transform infrared (FTIR, and X-ray diffraction (XRD analyses declared the most effective changes in physicochemical properties after CPTPS pretreatment. Thus, CPTPS might be a promising approach to deconstructing the recalcitrance of lignocellulosic structure to improve the biodegradability for AD.

The reactants equation of state for the tri-amino-tri-nitro-benzene (TATB) based explosive PBX 9502

Science.gov (United States)

Aslam, Tariq D.

2017-07-01

The response of high explosives (HEs), due to mechanical and/or thermal insults, is of great importance for both safety and performance. A major component of how an HE responds to these stimuli stems from its reactant equation of state (EOS). Here, the tri-amino-tri-nitro-benzene based explosive PBX 9502 is investigated by examining recent experiments. Furthermore, a complete thermal EOS is calibrated based on the functional form devised by Wescott, Stewart, and Davis [J. Appl. Phys. 98, 053514 (2005)]. It is found, by comparing to earlier calibrations, that a variety of thermodynamic data are needed to sufficiently constrain the EOS response over a wide range of thermodynamic state space. Included in the calibration presented here is the specific heat as a function of temperature, isobaric thermal expansion, and shock Hugoniot response. As validation of the resulting model, isothermal compression and isentropic compression are compared with recent experiments.

Shot H3837: Darht's First Dual-Axis Explosive Experiment

Science.gov (United States)

Mendez, Jacob; McNeil, Wendy Vogan; Harsh, James; Hull, Lawrence

2011-06-01

Test H3837 was the first explosive shot performed in front of both flash x-ray axes at the Los Alamos Dual Axis Radiographic HydroTest (DARHT) facility. Executed in November 2009, the shot was an explosively-driven metal flyer plate in a series of experiments designed to explore equation-of-state properties of shocked materials. Imaging the initial shock wave traveling through the flyer plate, DARHT Axis II captured the range of motion from the shock front emergence in the flyer to breakout at the free surface; the Axis I pulse provided a perpendicular perspective of the shot at a time coinciding with the third pulse of Axis II. Since the days of the Manhattan Project, penetrating radiography with multiple frames from different viewing angles has remained a high-profile goal at the Laboratory. H3837 is merely the beginning of a bright future for two-axis penetrating radiography.

The effect of explosive percentage on underwater explosion energy release of hexanitrohexaazaisowurtzitane and octogen based aluminized explosives

Directory of Open Access Journals (Sweden)

Qingjie Jiao

2018-03-01

Full Text Available To control the explosion energy output by optimizing explosive components is a key requirement in a number of different application areas. The effect of different Al/O Ratio on underwater explosion of aluminized explosives has been studied detailedly. However, the effect of explosive percentage in the same Al/O Ratio is rarely researched, especially for Hexanitrohexaazaisowurtzitane (CL-20 based aluminized explosives. In this study, we performed the underwater explosion experiments with 1.2-kilogram explosives in order to investigate the explosion energy released from CL-20 and Octogen (HMX based aluminized explosives. The percentage of the explosive varied from 5% to 30% and it is shown that: the shockwave peak pressure (pm grows gradually; shock wave energy (Es continues increasing, bubble energy (Eb increases then decreases peaking at 15% for both formulas, and the total energy (E and energy release rate (η peak at 20% for CL-20 and 15% for HMX. This paper outlines the physical mechanism of Eb change under the influence of an aluminium initial reaction temperature and reaction active detonation product percentage coupling. The result shows that CL-20 is superior as a new high explosive and has promising application prospects in the regulation of explosive energy output for underwater explosives.

The effect of explosive percentage on underwater explosion energy release of hexanitrohexaazaisowurtzitane and octogen based aluminized explosives

Science.gov (United States)

Jiao, Qingjie; Wang, Qiushi; Nie, Jianxin; Guo, Xueyong; Zhang, Wei; Fan, Wenqi

2018-03-01

To control the explosion energy output by optimizing explosive components is a key requirement in a number of different application areas. The effect of different Al/O Ratio on underwater explosion of aluminized explosives has been studied detailedly. However, the effect of explosive percentage in the same Al/O Ratio is rarely researched, especially for Hexanitrohexaazaisowurtzitane (CL-20) based aluminized explosives. In this study, we performed the underwater explosion experiments with 1.2-kilogram explosives in order to investigate the explosion energy released from CL-20 and Octogen (HMX) based aluminized explosives. The percentage of the explosive varied from 5% to 30% and it is shown that: the shockwave peak pressure (pm) grows gradually; shock wave energy (Es) continues increasing, bubble energy (Eb) increases then decreases peaking at 15% for both formulas, and the total energy (E) and energy release rate (η) peak at 20% for CL-20 and 15% for HMX. This paper outlines the physical mechanism of Eb change under the influence of an aluminium initial reaction temperature and reaction active detonation product percentage coupling. The result shows that CL-20 is superior as a new high explosive and has promising application prospects in the regulation of explosive energy output for underwater explosives.

Modeling of composite synthesis in conditions of controlled thermal explosion

Science.gov (United States)

Kukta, Yaroslav; Knyazeva, Anna

2017-12-01

The paper proposes the model for the titanium-based composite synthesis from powders of titanium and carbon of non-stoichiometric composition. The model takes into account the mixture heating from chamber walls, the dependence of liquidus and solidus temperatures on the composition of reacting mixture and the formation of possible irreversible phases. The reaction retardation by the reaction product is taken into consideration in kinetic laws. As an example, the results of temperature and conversion level calculation are presented for the system Ti-C with the summary reaction for different temperatures of chamber walls heating. It was revealed that the reaction retardation being the reaction product can be the cause of incomplete conversion in the thermal explosion conditions. Non-stoichiometric composition leads to the conditions of degenerated mode when some additional heating is necessary to complete the reaction.

Search for evidence of nuclear involvement in the fatal explosion of a 'cold fusion' experiment

International Nuclear Information System (INIS)

Grant, P.M.; Whipple, R.E.; Andresen, B.D.; Russo, R.E.; Bazan, F.; Brunk, J.L.; Wong, K.M.

1995-01-01

Forensic analyses of debris from the fatal explosion of an electrochemical 'cold fusion' cell at SRI International were conducted at LLNL at the request of Cal-OSHA. One investigation focused on the possibility of conventional nuclear reaction mechanisms contributing to the total energy inventory of the incident. Selected metal components of the electrolysis apparatus were subjected to nondestructive γ-ray spectrometry with high-sensitivity, low-background Ge detector systems. The anticipated analytes in these studies were radioactivation products potentially induced in the explosion residue by either fast or thermal neutrons. The results of this investigation were negative within the temporal constraints of the incident and the analytical sensitivities of the instrumentation. (author) 5 refs.; 1 fig.; 2 tabs

Development of steam explosion simulation code JASMINE

Energy Technology Data Exchange (ETDEWEB)

Moriyama, Kiyofumi; Yamano, Norihiro; Maruyama, Yu; Kudo, Tamotsu; Sugimoto, Jun [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment; Nagano, Katsuhiro; Araki, Kazuhiro

1995-11-01

A steam explosion is considered as a phenomenon which possibly threatens the integrity of the containment vessel of a nuclear power plant in a severe accident condition. A numerical calculation code JASMINE (JAeri Simulator for Multiphase INteraction and Explosion) purposed to simulate the whole process of steam explosions has been developed. The premixing model is based on a multiphase flow simulation code MISTRAL by Fuji Research Institute Co. In JASMINE code, the constitutive equations and the flow regime map are modified for the simulation of premixing related phenomena. The numerical solution method of the original code is succeeded, i.e. the basic equations are discretized semi-implicitly, BCGSTAB method is used for the matrix solver to improve the stability and convergence, also TVD scheme is applied to capture a steep phase distribution accurately. Test calculations have been performed for the conditions correspond to the experiments by Gilbertson et al. and Angelini et al. in which mixing of solid particles and water were observed in iso-thermal condition and with boiling, respectively. (author).

Development of steam explosion simulation code JASMINE

International Nuclear Information System (INIS)

Moriyama, Kiyofumi; Yamano, Norihiro; Maruyama, Yu; Kudo, Tamotsu; Sugimoto, Jun; Nagano, Katsuhiro; Araki, Kazuhiro.

1995-11-01

A steam explosion is considered as a phenomenon which possibly threatens the integrity of the containment vessel of a nuclear power plant in a severe accident condition. A numerical calculation code JASMINE (JAeri Simulator for Multiphase INteraction and Explosion) purposed to simulate the whole process of steam explosions has been developed. The premixing model is based on a multiphase flow simulation code MISTRAL by Fuji Research Institute Co. In JASMINE code, the constitutive equations and the flow regime map are modified for the simulation of premixing related phenomena. The numerical solution method of the original code is succeeded, i.e. the basic equations are discretized semi-implicitly, BCGSTAB method is used for the matrix solver to improve the stability and convergence, also TVD scheme is applied to capture a steep phase distribution accurately. Test calculations have been performed for the conditions correspond to the experiments by Gilbertson et al. and Angelini et al. in which mixing of solid particles and water were observed in iso-thermal condition and with boiling, respectively. (author)

An Analysis of the Initiation Process of Electro-Explosive Devices

Directory of Open Access Journals (Sweden)

Paulo Cesar de Carvalho Faria

2012-03-01

Full Text Available Electro-explosive devices (an electric resistance encapsulated by a primary explosive fundamentally convert electrical energy into thermal energy, to start off an explosive chemical reaction. Obviously, the activation of those devices shall not happen by accident or, even worse, by intentional exogenous influence. From an ordinary differential equation, which describes the electro-explosive thermal behavior, a remarkable, but certainly not intuitive, dependence of the temperature response on the time constant of the heat transfer process is verified: the temperature profile dramatically changes as the time constant spans a wide range of values, from much lesser than the pulse width to much greater than the pulse period. Based on this dependence, important recommendations, concerning the efficient and safety operation of electro-explosive devices, are proposed.

Liquid explosives

CERN Document Server

Liu, Jiping

2015-01-01

The book drawing on the author's nearly half a century of energetic materials research experience intends to systematically review the global researches on liquid explosives. The book focuses on the study of the conception, explosion mechanism, properties and preparation of liquid explosives. It provides a combination of theoretical knowledge and practical examples in a reader-friendly style. The book is likely to be interest of university researchers and graduate students in the fields of energetic materials, blasting engineering and mining.

Ex-Vessel corium coolability and steam explosion energetics in nordic light water reactors

International Nuclear Information System (INIS)

Dinh, T.N.; Ma, W.M.; Karbojian, A.; Kudinov, P.; Tran, C.T.; Hansson, C.R.

2008-03-01

This report presents advances and insights from the KTH's study on corium pool heat transfer in the BWR lower head; debris bed formation; steam explosion energetics; thermal hydraulics and coolability in bottom-fed and heterogeneous debris beds. Specifically, for analysis of heat transfer in a BWR lower plenum an advanced threedimensional simulation tool was developed and validated, using a so-called effective convectivity approach and Fluent code platform. An assessment of corium retention and coolability in the reactor pressure vessel (RPV) lower plenum by means of water supplied through the Control Rod Guide Tube (CRGT) cooling system was performed. Simulant material melt experiments were performed in an intermediate temperature range (1300-1600K) on DEFOR test facility to study formation of debris beds in high and low subcooled water pools characteristic of in-vessel and ex-vessel conditions. Results of the DEFOR-E scoping experiments and related analyses strongly suggest that porous beds formed in ex-vessel from a fragmented high-temperature debris is far from homogeneous. Calculation results of bed thermal hydraulics and dryout heat flux with a two-dimensional thermal-hydraulic code give the first basis to evaluate the extent by which macro and micro inhomogeneity can enhance the bed coolability. The development and validation of a model for two-phase natural circulation through a heated porous medium and its application to the coolability analysis of bottom-fed beds enables quantification of the significant effect of dryout heat flux enhancement (by a factor of 80-160%) due to bottom coolant injection. For a qualitative and quantitative understanding of steam explosion, the SHARP system and its image processing methodology were used to characterize the dynamics of a hot liquid (melt) drop fragmentation and the volatile liquid (coolant) vaporization. The experimental results provide a basis to suggest that the melt drop preconditioning is instrumental to the

Ex-Vessel corium coolability and steam explosion energetics in nordic light water reactors

Energy Technology Data Exchange (ETDEWEB)

Dinh, T.N.; Ma, W.M.; Karbojian, A.; Kudinov, P.; Tran, C.T.; Hansson, C.R. [Royal Institute of Technology (KTH), (Sweden)

2008-03-15

This report presents advances and insights from the KTH's study on corium pool heat transfer in the BWR lower head; debris bed formation; steam explosion energetics; thermal hydraulics and coolability in bottom-fed and heterogeneous debris beds. Specifically, for analysis of heat transfer in a BWR lower plenum an advanced threedimensional simulation tool was developed and validated, using a so-called effective convectivity approach and Fluent code platform. An assessment of corium retention and coolability in the reactor pressure vessel (RPV) lower plenum by means of water supplied through the Control Rod Guide Tube (CRGT) cooling system was performed. Simulant material melt experiments were performed in an intermediate temperature range (1300-1600K) on DEFOR test facility to study formation of debris beds in high and low subcooled water pools characteristic of in-vessel and ex-vessel conditions. Results of the DEFOR-E scoping experiments and related analyses strongly suggest that porous beds formed in ex-vessel from a fragmented high-temperature debris is far from homogeneous. Calculation results of bed thermal hydraulics and dryout heat flux with a two-dimensional thermal-hydraulic code give the first basis to evaluate the extent by which macro and micro inhomogeneity can enhance the bed coolability. The development and validation of a model for two-phase natural circulation through a heated porous medium and its application to the coolability analysis of bottom-fed beds enables quantification of the significant effect of dryout heat flux enhancement (by a factor of 80-160%) due to bottom coolant injection. For a qualitative and quantitative understanding of steam explosion, the SHARP system and its image processing methodology were used to characterize the dynamics of a hot liquid (melt) drop fragmentation and the volatile liquid (coolant) vaporization. The experimental results provide a basis to suggest that the melt drop preconditioning is instrumental to

Study on Thermal Decomposition Characteristics of Ammonium Nitrate Emulsion Explosive in Different Scales

Science.gov (United States)

Wu, Qiujie; Tan, Liu; Xu, Sen; Liu, Dabin; Min, Li

2018-04-01

Numerous accidents of emulsion explosive (EE) are attributed to uncontrolled thermal decomposition of ammonium nitrate emulsion (ANE, the intermediate of EE) and EE in large scale. In order to study the thermal decomposition characteristics of ANE and EE in different scales, a large-scale test of modified vented pipe test (MVPT), and two laboratory-scale tests of differential scanning calorimeter (DSC) and accelerating rate calorimeter (ARC) were applied in the present study. The scale effect and water effect both play an important role in the thermal stability of ANE and EE. The measured decomposition temperatures of ANE and EE in MVPT are 146°C and 144°C, respectively, much lower than those in DSC and ARC. As the size of the same sample in DSC, ARC, and MVPT successively increases, the onset temperatures decrease. In the same test, the measured onset temperature value of ANE is higher than that of EE. The water composition of the sample stabilizes the sample. The large-scale test of MVPT can provide information for the real-life operations. The large-scale operations have more risks, and continuous overheating should be avoided.

Experimental simulation of microinteractions in large scale explosions

Energy Technology Data Exchange (ETDEWEB)

Chen, X.; Luo, R.; Yuen, W.W.; Theofanous, T.G. [California Univ., Santa Barbara, CA (United States). Center for Risk Studies and Safety

1998-01-01

This paper presents data and analysis of recent experiments conducted in the SIGMA-2000 facility to simulate microinteractions in large scale explosions. Specifically, the fragmentation behavior of a high temperature molten steel drop under high pressure (beyond critical) conditions are investigated. The current data demonstrate, for the first time, the effect of high pressure in suppressing the thermal effect of fragmentation under supercritical conditions. The results support the microinteractions idea, and the ESPROSE.m prediction of fragmentation rate. (author)

Contained fission explosion breeder reactor system

International Nuclear Information System (INIS)

Juhl, N.H.; Marwick, E.F.

1983-01-01

A reactor system for producing useful thermal energy and valuable isotopes, such as plutonium-239, uranium-233, and/or tritium, in which a pair of sub-critical masses of fissile and fertile actinide slugs are propelled into an ellipsoidal pressure vessel. The propelled slugs intercept near the center of the chamber where the concurring slugs become a more than prompt configuration thereby producing a fission explosion. Re-useable accelerating mechanisms are provided external of the vessel for propelling the slugs at predetermined time intervals into the vessel. A working fluid of lean molten metal slurry is injected into the chamber prior to each explosion for the attenuation of the explosion's effects, for the protection of the chamber's walls, and for the absorbtion of thermal energy and debris from the explosion. The working fluid is injected into the chamber in a pattern so as not to interfere with the flight paths of the slugs and to maximize the concentration of working fluid near the chamber's center. The heated working fluid is drained from the vessel and is used to perform useful work. Most of the debris from the explosion is collected as precipitate and is used for the manufacture of new slugs

Effects of magnesium-based hydrogen storage materials on the thermal decomposition, burning rate, and explosive heat of ammonium perchlorate-based composite solid propellant.

Science.gov (United States)

Liu, Leili; Li, Jie; Zhang, Lingyao; Tian, Siyu

2018-01-15

MgH 2 , Mg 2 NiH 4 , and Mg 2 CuH 3 were prepared, and their structure and hydrogen storage properties were determined through X-ray photoelectron spectroscopy and thermal analyzer. The effects of MgH 2 , Mg 2 NiH 4 , and Mg 2 CuH 3 on the thermal decomposition, burning rate, and explosive heat of ammonium perchlorate-based composite solid propellant were subsequently studied. Results indicated that MgH 2 , Mg 2 NiH 4 , and Mg 2 CuH 3 can decrease the thermal decomposition peak temperature and increase the total released heat of decomposition. These compounds can improve the effect of thermal decomposition of the propellant. The burning rates of the propellant increased using Mg-based hydrogen storage materials as promoter. The burning rates of the propellant also increased using MgH 2 instead of Al in the propellant, but its explosive heat was not enlarged. Nonetheless, the combustion heat of MgH 2 was higher than that of Al. A possible mechanism was thus proposed. Copyright © 2017. Published by Elsevier B.V.

Study of film boiling collapse behavior during vapor explosion

International Nuclear Information System (INIS)

Yagi, Masahiro; Yamano, Norihiro; Sugimoto, Jun; Abe, Yutaka; Adachi, Hiromichi; Kobayashi, Tomoyoshi.

1996-06-01

Possible large scale vapor explosions are safety concern in nuclear power plants during severe accident. In order to identify the occurrence of the vapor explosion and to estimate the magnitude of the induced pressure pulse, it is necessary to investigate the triggering condition for the vapor explosion. As a first step of this study, scooping analysis was conducted with a simulation code based on thermal detonation model. It was found that the pressure at the collapse of film boiling much affects the trigger condition of vapor explosion. Based on this analytical results, basic experiments were conducted to clarify the collapse conditions of film boiling on a high temperature solid ball surface. Film boiling condition was established by flooding water onto a high temperature stainless steel ball heated by a high frequency induction heater. After the film boiling was established, the pressure pulse generated by a shock tube was applied to collapse the steam film on the ball surface. As the experimental boundary conditions, materials and size of the balls, magnitude of pressure pulse and initial temperature of the carbon and stainless steel balls were varied. The transients of pressure and surface temperature were measured. It was found that the surface temperature on the balls sharply decreased when the pressure wave passed through the film on balls. Based on the surface temperature behavior, the film boiling collapse pattern was found to be categorized into several types. Especially, the pattern for stainless steel ball was categorized into three types; no collapse, collapse and reestablishment after collapse. It was thus clarified that the film boiling collapse behavior was identified by initial conditions and that the pressure required to collapse film boiling strongly depended on the initial surface temperature. The present results will provide a useful information for the analysis of vapor explosions based on the thermal detonation model. (J.P.N.)

Investigation on energetics of ex-vessel vapor explosion based on spontaneous nucleation fragmentation

International Nuclear Information System (INIS)

Liu, Jie; Koshizuka, Seiichi; Oka, Yoshiaki

2002-01-01

A computer code PROVER-I is developed for propagation phase of vapor explosion. A new thermal fragmentation model is proposed with three kinds of time scale for modeling instant fragmentation, spontaneous nucleation fragmentation and normal boiling fragmentation. The energetics of ex-vessel vapor explosion is investigated based on different fragmentation models. A higher pressure peak and a larger mechanical energy conversion ratio are obtained by spontaneous nucleation fragmentation. A smaller energy conversion ratio results from normal boiling fragmentation. When the delay time in thermal fragmentation model is near 0.0 ms, the pressure propagation behavior tends to be analogous with that in hydrodynamic fragmentation. If the delay time is longer, pressure attenuation occurs at the shock front. The high energy conversion ratio (>4%) is obtained in a small vapor volume fraction together with spontaneous nucleation fragmentation. These results are consistent with fuel-coolant interaction experiments with alumina melt. However, in larger vapor volume fraction conditions (α υ >0.3), the vapor explosion is weak. For corium melt, a coarse mixture with void fraction of more than 30% can be generated in the pre-mixing process because of its physical properties. In the mixture with such a high void fraction the energetic vapor explosion hardly takes place. (author)

Verification of fire and explosion accident analysis codes (facility design and preliminary results)

International Nuclear Information System (INIS)

Gregory, W.S.; Nichols, B.D.; Talbott, D.V.; Smith, P.R.; Fenton, D.L.

1985-01-01

For several years, the US Nuclear Regulatory Commission has sponsored the development of methods for improving capabilities to analyze the effects of postulated accidents in nuclear facilities; the accidents of interest are those that could occur during nuclear materials handling. At the Los Alamos National Laboratory, this program has resulted in three computer codes: FIRAC, EXPAC, and TORAC. These codes are designed to predict the effects of fires, explosions, and tornadoes in nuclear facilities. Particular emphasis is placed on the movement of airborne radioactive material through the gaseous effluent treatment system of a nuclear installation. The design, construction, and calibration of an experimental ventilation system to verify the fire and explosion accident analysis codes are described. The facility features a large industrial heater and several aerosol smoke generators that are used to simulate fires. Both injected thermal energy and aerosol mass can be controlled using this equipment. Explosions are simulated with H 2 /O 2 balloons and small explosive charges. Experimental measurements of temperature, energy, aerosol release rates, smoke concentration, and mass accumulation on HEPA filters can be made. Volumetric flow rate and differential pressures also are monitored. The initial experiments involve varying parameters such as thermal and aerosol rate and ventilation flow rate. FIRAC prediction results are presented. 10 figs

Steam explosions in sodium cooled breeder reactors

International Nuclear Information System (INIS)

Lundell, B.

1982-01-01

Steam explosion is considered a physical process which transport heat from molten fuel to liquid coolant so fast that the coolant starts boiling in an explosion-like manner. The arising pressure waves transform part of the thermal energy to mechanical energy. This can stress the reactor tank and threaten its hightness. The course of the explosion has not been theoretical explained. Experimental results indicate that the probability of steam explosions in a breeder reactor is small. The efficiency of the transformation of the heat of fusion into mechanical energy in substantially lower than the theoretical maximum value. The mechanical stress from the steam explosion on the reactor tank does not seem to jeopardize its tightness. (G.B.)

Comparison of the Effects of Thermal Pretreatment, Steam Explosion and Ultrasonic Disintegration on Digestibility of Corn Stover

OpenAIRE

Andras Dallos; Gyula Dörgő; Dániel Capári

2016-01-01

The energy demand of the corn-based bioethanol production could be reduced using the agricultural byproducts as bioenergy feedstock for biogas digesters. The release of lignocellulosic material and therefore the acceleration of degradation processes can be achieved using thermal and mechanical pretreatments, which assist to hydrolyze the cell walls and speed the solubilization of biopolymers in biogas feedstock. This study is focused on liquid hot water, steam explosion and ultrasonic pretrea...

Nuclear explosions and their effects

Energy Technology Data Exchange (ETDEWEB)

1958-01-01

A brief historical background is given of the development of the atomic bomb. Also included is an account of the Hiroshima-Nagasaki bombing, plus some information on the testing and production of nuclear weapons by the United States, United Kingdom, and Russia. More detailed consideration is given to the following: the scientific principles of fission and fusion explosions; the energy released in fission and the radioactivity of fission products; blast, thermal, and radiologicalal effects of nuclear explosions; long-term radiological hazards from fall-out; and genetic effects of nuclear explosions. A brief account is given of the fission chain process, the concept of critical size, and the principles of implosion as applied to nuclear explosions. Limited information is presented on the controlled release of thermonuclear energy and catalyzed fusion reaction. Discussions are included on dose rates from radiation sources inside and outside the body, the effect of nuclear explosions on the weather, and the contamination of fish and marine organisms.

Thermal stability of detonation-produced micro and nanodiamonds

Science.gov (United States)

Efremov, V. P.; Zakatilova, E. I.; Maklashova, I. V.; Shevchenko, N. V.

2018-01-01

Detonation nanodiamonds are produced at utilization of high explosives. When an explosive blasts in a water environment, the detonation products contain microdiamonds, and in a gaseous medium, nanodiamonds. It is known that with decreasing size the influence of the surface energy of particles on their properties increases. Thus, it is interesting to compare the properties of detonation nano and microdiamonds. In this study, we have examined the thermal stability of diamond materials by synchronous thermal analysis. The experiments were performed at atmospheric pressure in argon flow for different heating rates in a range from room temperature to 1500 °C. Samples of initial and annealed micro and nanomaterials were studied using electron microscopy, x-ray and x-ray-fluorescence analysis. It was established that thermal and structural properties of micro and nanodiamonds differ substantially.

The preliminary results of steam explosion experiments in TROI

International Nuclear Information System (INIS)

Song, J.H.; Park, I.K.; Chang, Y.J.; Min, B.T.; Hong, S.W.; Kim, H.D.

2001-01-01

Korea Atomic Energy Research Institute (KAERI) launched an intermediate scale steam explosion experiment named 'Test for Real corium Interaction with water (TROI)' using reactor material to investigate the effect of material composition, multi-dimensional melt-water interaction, and hydrogen generation. The melt-water interaction is confined in a pressure vessel with the multi-dimensional fuel and water pool geometry. The cold crucible technology, where the mixture of oxide powder in a water-cooled cage is heated by high frequency induction, is employed. It minimizes unwanted inclusion of impurities during the melting process. The data acquisition system and instrumentations which measure the static and dynamic pressure, temperatures of melt and water are set up. In the first series of tests using several kg of ZrO 2 , melt water interaction is made in a heated water pool at 95 Celsius degrees without triggering. A steam spike pressure at about 10 bar is observed. The morphology of debris shows that there was a mild local steam explosion. The melt water interaction was monitored by video cameras. The UO 2 tests are scheduled around March of 2001, in parallel with the improvements of the design of test facility. (authors)

Investigation of the shallow depth explosions

International Nuclear Information System (INIS)

Kamegai, M.

1976-01-01

An investigation of the nuclear explosions at shallow depth is made. A combination of an explosion code and an effects code proves to be an excellent tool for this study. A numerical simulation of ''Johnie Boy'' shows that the energy coupling to the air takes place in two stages; first by a rising mound, and then by a vented source. The thermal effects are examined for a 1 kt source at three depths of burial. The ''mushroom effect'' leaves a hot radiative plasma in the upper level and cold materials in the lower region of the debris. The temperature and the energy density of the debris can give an upper limit on the thermal output

Risk of fire and dust explosions analysis in thermal Power station of ''As Pontes''; Analisis del Riesgo de fuego y Explosion en la Central Termica As Pontes

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-07-01

Among the numerous difficulties come up in the industrial processes that operate with coal, the handling of combustible solids constitutes a priority objective because of the potential risk of fire and dust explosions that implies. The aim of this project was to determine the coal usage conditions that assure total safety in its manipulation avoiding every risks at the Thermal Power Station. Several variables had to be considered starting with the basis concept of coal, which ranges very different types, compositions and origins and studying the coal handling and operation condition on different areas in the Thermal Power Station. (Author)

High-throughput trace analysis of explosives in water by laser diode thermal desorption/atmospheric pressure chemical ionization-tandem mass spectrometry.

Science.gov (United States)

Badjagbo, Koffi; Sauvé, Sébastien

2012-07-03

Harmful explosives can accumulate in natural waters in the long term during their testing, usage, storage, and dumping and can pose a health risk to humans and the environment. For the first time, attachment of small anions to neutral molecules in laser diode thermal desorption/atmospheric pressure chemical ionization was systematically investigated for the direct determination of trace nitroaromatics, nitrate esters, and nitramine explosives in water. Using ammonium chloride as an additive improved the instrument response for all the explosives tested and promoted the formation of several characteristic adduct ions. The method performs well achieving good linearity over at least 2 orders of magnitude, with coefficients of determination greater than 0.995. The resulting limits of detection are in the range of 0.009-0.092 μg/L. River water samples were successfully analyzed by the proposed method with accuracy in the range of 96-98% and a response time of 15 s, without any further pretreatment or chromatographic separation.

Differential thermal analysis microsystem for explosive detection

DEFF Research Database (Denmark)

Olsen, Jesper Kenneth; Greve, Anders; Senesac, L.

2011-01-01

as a small silicon nitride membrane incorporating heater elements and a temperature measurement resistor. In this manuscript the DTA system is described and tested by measuring calorimetric response of 3 different kinds of explosives (TNT, RDX and PETN). This project is carried out under the framework...

Rapid thermal process by RF heating of nano-graphene layer/silicon substrate structure: Heat explosion theory approach

Science.gov (United States)

Sinder, M.; Pelleg, J.; Meerovich, V.; Sokolovsky, V.

2018-03-01

RF heating kinetics of a nano-graphene layer/silicon substrate structure is analyzed theoretically as a function of the thickness and sheet resistance of the graphene layer, the dimensions and thermal parameters of the structure, as well as of cooling conditions and of the amplitude and frequency of the applied RF magnetic field. It is shown that two regimes of the heating can be realized. The first one is characterized by heating of the structure up to a finite temperature determined by equilibrium between the dissipated loss power caused by induced eddy-currents and the heat transfer to environment. The second regime corresponds to a fast unlimited temperature increase (heat explosion). The criterions of realization of these regimes are presented in the analytical form. Using the criterions and literature data, it is shown the possibility of the heat explosion regime for a graphene layer/silicon substrate structure at RF heating.

Sorbent Film-Coated Passive Samplers for Explosives Vapour Detection Part A: Materials Optimisation and Integration with Analytical Technologies.

Science.gov (United States)

McEneff, Gillian L; Murphy, Bronagh; Webb, Tony; Wood, Dan; Irlam, Rachel; Mills, Jim; Green, David; Barron, Leon P

2018-04-11

A new thin-film passive sampler is presented as a low resource dependent and discrete continuous monitoring solution for explosives-related vapours. Using 15 mid-high vapour pressure explosives-related compounds as probes, combinations of four thermally stable substrates and six film-based sorbents were evaluated. Meta-aramid and phenylene oxide-based materials showed the best recoveries from small voids (~70%). Analysis was performed using liquid chromatography-high resolution accurate mass spectrometry which also enabled tentative identification of new targets from the acquired data. Preliminary uptake kinetics experiments revealed plateau concentrations on the device were reached between 3-5 days. Compounds used in improvised explosive devices, such as triacetone triperoxide, were detected within 1 hour and were stably retained by the sampler for up to 7 days. Sampler performance was consistent for 22 months after manufacture. Lastly, its direct integration with currently in-service explosives screening equipment including ion mobility spectrometry and thermal desorption mass spectrometry is presented. Following exposure to several open environments and targeted interferences, sampler performance was subsequently assessed and potential interferences identified. High-security building and area monitoring for concealed explosives using such cost-effective and discrete passive samplers can add extra assurance to search routines while minimising any additional burden on personnel or everyday site operation.

Simulation of TROI steam explosion behaviour using the COMETA code

International Nuclear Information System (INIS)

Arun Kumar Nayak; Hyun Sun Park; Bal Raj Sehgal; Alessandro Annunziato

2005-01-01

Full text of publication follows: During a severe accident in a nuclear reactor, the core can melt and the molten corium while interacting with water may cause an energetic fuel coolant interaction which is known as steam explosion. Such phenomena can occur inside the reactor vessel during flooding of a degraded core or when molten corium falls into the lower head filled with water. Similar phenomena may occur outside the reactor vessel when molten corium is ejected into a flooded reactor cavity or into the flooded containment after the vessel failure. The interaction of molten corium with water is one of the most complex thermal hydraulic and chemical phenomena. Recently in the TROI test series carried out at KAERI (Korean Atomic Energy Research Institute) in Korea, steam explosions were observed. In those tests, the UO 2 /ZrO 2 compositions were close to that of prototypic case. In this paper, we have numerically simulated the melt coolant interaction of TROI tests using the computer code, COMETA (Core MElt Thermalhydraulic Analysis) developed by JRC (Joint Research Center), at Ispra in Italy. The COMETA code was primarily developed to analyse, with sufficient detail, both the thermal-hydraulics and the fuel fragmentation phenomena during the melt quenching tests as conducted in the FARO facility. The code solves the conservation equations of mass, momentum and energy for the fluid using a conventional two-fluid model. Fuel fragmentation model considers the molten jet, its break up in drops and accumulation as fused-debris on the bottom. An explicit coupling between the thermal hydraulics and fuel fragmentation for the energy transfer is considered. The code has been extensively validated in the past for melt quenching in a series of experiments in the FARO facility. In this work, we first simulated the pre-mix and triggering phases of the TROI-13 tests for which the test data were available. The melt jet trajectory, void fraction and pressure profile were

Thermal explosion hazards on 18650 lithium ion batteries with a VSP2 adiabatic calorimeter

Energy Technology Data Exchange (ETDEWEB)

Jhu, Can-Yong [Doctoral Program, Graduate School of Engineering Science and Technology, National Yunlin University of Science and Technology (NYUST), 123, University Rd., Sec. 3, Douliou, Yunlin 64002, Taiwan, ROC (China); Wang, Yih-Wen, E-mail: g9410825@yuntech.edu.tw [Department of Occupational Safety and Health, Jen-Teh Junior College of Medicine, Nursing and Management, 79-9, Sha-Luen-Hu, Xi-Zhou-Li, Houlong, Miaoli 35664, Taiwan, ROC (China); Shu, Chi-Min [Doctoral Program, Graduate School of Engineering Science and Technology, National Yunlin University of Science and Technology (NYUST), 123, University Rd., Sec. 3, Douliou, Yunlin 64002, Taiwan, ROC (China); Chang, Jian-Chuang; Wu, Hung-Chun [Material and Chemical Research Laboratories, Industrial Technology Research Institute (ITRI), Rm. 222, Bldg. 77, 2F, 195, Sec. 4, Chung Hsing Rd., Chutung, Hsinchu 31040, Taiwan, ROC (China)

2011-08-15

Thermal abuse behaviors relating to adiabatic runaway reactions in commercial 18650 lithium ion batteries (LiCoO{sub 2}) are being studied in an adiabatic calorimeter, vent sizing package 2 (VSP2). We select four worldwide battery producers, Sony, Sanyo, Samsung and LG, and tested their Li-ion batteries, which have LiCoO{sub 2} cathodes, to determine their thermal instabilities and adiabatic runaway features. The charged (4.2 V) and uncharged (3.7 V) 18650 Li-ion batteries are tested using a VSP2 with a customized stainless steel test can to evaluate their thermal hazard characteristics, such as the initial exothermic temperature (T{sub 0}), the self-heating rate (dT/dt), the pressure rise rate (dP/dt), the pressure-temperature profiles and the maximum temperature (T{sub max}) and pressure (P{sub max}). The T{sub max} and P{sub max} of the charged Li-ion battery during the runaway reaction reach 903.0 {sup o}C and 1565.9 psig (pound-force per square inch gauge), respectively. This result leads to a thermal explosion, and the heat of reaction is 26.2 kJ. The thermokinetic parameters of the reaction of LiCoO{sub 2} batteries are also determined using the Arrhenius model. The thermal reaction mechanism of the Li-ion battery (pack) proved to be an important safety concern for energy storage. Additionally, use of the VSP2 to classify the self-reactive ratings of the various Li-ion batteries demonstrates a new application of the adiabatic calorimetric methodology.

Thermal explosion hazards on 18650 lithium ion batteries with a VSP2 adiabatic calorimeter

International Nuclear Information System (INIS)

Jhu, Can-Yong; Wang, Yih-Wen; Shu, Chi-Min; Chang, Jian-Chuang; Wu, Hung-Chun

2011-01-01

Thermal abuse behaviors relating to adiabatic runaway reactions in commercial 18650 lithium ion batteries (LiCoO 2 ) are being studied in an adiabatic calorimeter, vent sizing package 2 (VSP2). We select four worldwide battery producers, Sony, Sanyo, Samsung and LG, and tested their Li-ion batteries, which have LiCoO 2 cathodes, to determine their thermal instabilities and adiabatic runaway features. The charged (4.2 V) and uncharged (3.7 V) 18650 Li-ion batteries are tested using a VSP2 with a customized stainless steel test can to evaluate their thermal hazard characteristics, such as the initial exothermic temperature (T 0 ), the self-heating rate (dT/dt), the pressure rise rate (dP/dt), the pressure-temperature profiles and the maximum temperature (T max ) and pressure (P max ). The T max and P max of the charged Li-ion battery during the runaway reaction reach 903.0 o C and 1565.9 psig (pound-force per square inch gauge), respectively. This result leads to a thermal explosion, and the heat of reaction is 26.2 kJ. The thermokinetic parameters of the reaction of LiCoO 2 batteries are also determined using the Arrhenius model. The thermal reaction mechanism of the Li-ion battery (pack) proved to be an important safety concern for energy storage. Additionally, use of the VSP2 to classify the self-reactive ratings of the various Li-ion batteries demonstrates a new application of the adiabatic calorimetric methodology.

Fire and explosion hazards to flora and fauna from explosives.

Science.gov (United States)

Merrifield, R

2000-06-30

Deliberate or accidental initiation of explosives can produce a range of potentially damaging fire and explosion effects. Quantification of the consequences of such effects upon the surroundings, particularly on people and structures, has always been of paramount importance. Information on the effects on flora and fauna, however, is limited, with probably the weakest area lying with fragmentation of buildings and their effects on different small mammals. Information has been used here to gain an appreciation of the likely magnitude of the potential fire and explosion effects on flora and fauna. This is based on a number of broad assumptions and a variety of data sources including World War II bomb damage, experiments performed with animals 30-40 years ago, and more recent field trials on building break-up under explosive loading.

Excavation research with chemical explosives

Energy Technology Data Exchange (ETDEWEB)

Vandenberg, William E; Day, Walter C [U.S. Army Engineer Nuclear Cratering Group, Lawrence Radiation Laboratory, Livermore, CA (United States)

1970-05-01

The US Army Engineer Nuclear Cratering Group (NCG) is located at the Lawrence Radiation Laboratory in Livermore, California. NCG was established in 1962 and assigned responsibility for technical program direction of the Corps of Engineers Nuclear Excavation Research Program. The major part of the experimental program has been the execution of chemical explosive excavation experiments. In the past these experiments were preliminary to planned nuclear excavation experiments. The experience gained and technology developed in accomplishing these experiments has led to an expansion of NCG's research mission. The overall research and development mission now includes the development of chemical explosive excavation technology to enable the Corps of Engineers to more economically accomplish Civil Works Construction projects of intermediate size. The current and future chemical explosive excavation experiments conducted by NCG will be planned so as to provide data that can be used in the development of both chemical and nuclear excavation technology. In addition, whenever possible, the experiments will be conducted at the specific sites of authorized Civil Works Construction Projects and will be designed to provide a useful portion of the engineering structures planned in that project. Currently, the emphasis in the chemical explosive excavation program is on the development of design techniques for producing specific crater geometries in a variety of media. Preliminary results of two such experiments are described in this paper; Project Pre-GONDOLA III, Phase III, Reservoir Connection Experiment; and a Safety Calibration Series for Project TUGBOAT, a small boat harbor excavation experiment.

Excavation research with chemical explosives

International Nuclear Information System (INIS)

Vandenberg, William E.; Day, Walter C.

1970-01-01

The US Army Engineer Nuclear Cratering Group (NCG) is located at the Lawrence Radiation Laboratory in Livermore, California. NCG was established in 1962 and assigned responsibility for technical program direction of the Corps of Engineers Nuclear Excavation Research Program. The major part of the experimental program has been the execution of chemical explosive excavation experiments. In the past these experiments were preliminary to planned nuclear excavation experiments. The experience gained and technology developed in accomplishing these experiments has led to an expansion of NCG's research mission. The overall research and development mission now includes the development of chemical explosive excavation technology to enable the Corps of Engineers to more economically accomplish Civil Works Construction projects of intermediate size. The current and future chemical explosive excavation experiments conducted by NCG will be planned so as to provide data that can be used in the development of both chemical and nuclear excavation technology. In addition, whenever possible, the experiments will be conducted at the specific sites of authorized Civil Works Construction Projects and will be designed to provide a useful portion of the engineering structures planned in that project. Currently, the emphasis in the chemical explosive excavation program is on the development of design techniques for producing specific crater geometries in a variety of media. Preliminary results of two such experiments are described in this paper; Project Pre-GONDOLA III, Phase III, Reservoir Connection Experiment; and a Safety Calibration Series for Project TUGBOAT, a small boat harbor excavation experiment

Steam explosions in light water reactors

International Nuclear Information System (INIS)

1981-01-01

The report deals with a postulated accident caused by molten fuel falling into the lower plenum of the containment of a reactor. The analysis which is presented in the report shows that the thermal energy released in the resulting steam explosion is not enough to destroy the pressure vessel or the containment. The report was prepared for the Swedish Governmental Committee on steam explosion in light water reactors. It includes statements issued by internationally well-known specialists. (G.B.)

Green primary explosives: 5-nitrotetrazolato-N2-ferrate hierarchies.

Science.gov (United States)

Huynh, My Hang V; Coburn, Michael D; Meyer, Thomas J; Wetzler, Modi

2006-07-05

The sensitive explosives used in initiating devices like primers and detonators are called primary explosives. Successful detonations of secondary explosives are accomplished by suitable sources of initiation energy that is transmitted directly from the primaries or through secondary explosive boosters. Reliable initiating mechanisms are available in numerous forms of primers and detonators depending upon the nature of the secondary explosives. The technology of initiation devices used for military and civilian purposes continues to expand owing to variations in initiating method, chemical composition, quantity, sensitivity, explosive performance, and other necessary built-in mechanisms. Although the most widely used primaries contain toxic lead azide and lead styphnate, mixtures of thermally unstable primaries, like diazodinitrophenol and tetracene, or poisonous agents, like antimony sulfide and barium nitrate, are also used. Novel environmentally friendly primary explosives are expanded here to include cat[Fe(II)(NT)(3)(H(2)O)(3)], cat(2)[Fe(II)(NT)(4)(H(2)O)(2)], cat(3)[Fe(II)(NT)(5)(H(2)O)], and cat(4)[Fe(II)(NT)(6)] with cat = cation and NT(-) = 5-nitrotetrazolato-N(2). With available alkaline, alkaline earth, and organic cations as partners, four series of 5-nitrotetrazolato-N(2)-ferrate hierarchies have been prepared that provide a plethora of green primaries with diverse initiating sensitivity and explosive performance. They hold great promise for replacing not only toxic lead primaries but also thermally unstable primaries and poisonous agents. Strategies are also described for the systematic preparation of coordination complex green primaries based on appropriate selection of ligands, metals, and synthetic procedures. These strategies allow for maximum versatility in initiating sensitivity and explosive performance while retaining properties required for green primaries.

Coating and Characterization of Mock and Explosive Materials

Directory of Open Access Journals (Sweden)

Emily M. Hunt

2012-01-01

Full Text Available This project develops a method of manufacturing plastic-bonded explosives by using use precision control of agglomeration and coating of energetic powders. The energetic material coating process entails suspending either wet or dry energetic powders in a stream of inert gas and contacting the energetic powder with atomized droplets of a lacquer composed of binder and organic solvent. By using a high-velocity air stream to pneumatically convey the energetic powders and droplets of lacquer, the energetic powders are efficiently wetted while agglomerate drying begins almost immediately. The result is an energetic powder uniformly coated with binder, that is, a PBX, with a high bulk density suitable for pressing. Experiments have been conducted using mock explosive materials to examine coating effectiveness and density. Energetic materials are now being coated and will be tested both mechanically and thermally. This allows for a comprehensive comparison of the morphology and reactivity of the newly coated materials to previously manufactured materials.

Differences in coupling between chemical and nuclear explosions

International Nuclear Information System (INIS)

Glenn, L.A.

1992-01-01

The teleseismic amplitude resulting from an underground explosion is proportional to the asymptotic value of the reduced displacement potential (φ∞) or, in physical terms, to the permanent change in volume measured anywhere beyond the range at which the outgoing wave has become elastic. φ∞ decreases with increasing initial cavity size (r o ) until the cavity is large enough to preclude inelastic behavior in the surrounding rock, at which point no further decrease occurs. With nuclear explosions, φ∞ can also be reduced by decreasing the initial cavity size over a certain range. This occurs because, in this range of r 0 W -1/3 (where W is the yield) the thermal pressure in the surrounding medium increases much more slowly than does the thermal energy. With chemical explosions, by contrast, r 0 W -1/3 cannot be decreased below the fully tamped limit because the energy density is bounded above. Moreover, for the most of the cavity expansion period the ratio of specific heats of the chemical explosion products is substantially higher than the equivalent ratio in a nuclear explosion, so that the cavity pressure in the former case is higher as well and this further amplifies the differences between the two. Calculations show that the teleseismic amplitude could be as much as 50% higher for an equivalent tamped chemical explosion in salt than was observed in the SALMON nuclear event

Scanning the melting curve of tungsten by a submicrosecond wire-explosion experiment

International Nuclear Information System (INIS)

Kloss, A.; Hess, H.; Schneidenbach, H.; Grossjohann, R.

1999-01-01

Measurements of temperature and density during a wire-explosion experiment at atmospheric pressure are described. The measurements encompass a parameter range from the solid to near the critical point. The influence of a polytetra-fluoroethylene coating of the wire, necessary to prevent surface discharges, on the temperature and density measurements is investigated. The melting curve of tungsten up to 4,000 K is determined

Internal sub-sonic burning during an explosion viewed via dynamic X-ray radiography

Science.gov (United States)

Smilowitz, L.; Henson, B. F.; Oschwald, D.; Suvorova, N.; Remelius, D.

2017-10-01

We observe internal convective and conductive burn front propagation and solid consumption subsequent to thermal ignition for plastic bonded formulations of the solid organic secondary explosives octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine and 1,3,5-triamino-2,4,6-trinitrobenzene. This work describes x-ray radiographic diagnostics enabling the study of solid density in a fully encased explosive during internal burning subsequent to ignition. The result of this study is the ability to directly observe and measure rates of energy release during a thermal explosion.

Modeling the thermal deformation of TATB-based explosives. Part 1: Thermal expansion of “neat-pressed” polycrystalline TATB

Energy Technology Data Exchange (ETDEWEB)

Luscher, Darby J. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

2014-05-08

We detail a modeling approach to simulate the anisotropic thermal expansion of polycrystalline (1,3,5-triamino-2,4,6-trinitrobenzene) TATB-based explosives that utilizes microstructural information including porosity, crystal aspect ratio, and processing-induced texture. This report, the first in a series, focuses on nonlinear thermal expansion of “neat-pressed” polycrystalline TATB specimens which do not contain any binder; additional complexities related to polymeric binder and irreversible ratcheting behavior are briefly discussed, however detailed investigation of these aspects are deferred to subsequent reports. In this work we have, for the first time, developed a mesoscale continuum model relating the thermal expansion of polycrystal TATB specimens to their microstructural characteristics. A self-consistent homogenization procedure is used to relate macroscopic thermoelastic response to the constitutive behavior of single-crystal TATB. The model includes a representation of grain aspect ratio, porosity, and crystallographic texture attributed to the consolidation process. A quantitative model is proposed to describe the evolution of preferred orientation of graphitic planes in TATB during consolidation and an algorithm constructed to develop a discrete representation of the associated orientation distribution function. Analytical and numerical solutions using this model are shown to produce textures consistent with previous measurements and characterization for isostatic and uniaxial “die-pressed” specimens. Predicted thermal strain versus temperature for textured specimens are shown to be in agreement with corresponding experimental measurements. Using the developed modeling approach, several simulations have been run to investigate the influence of microstructure on macroscopic thermal expansion behavior. Results from these simulations are used to identify qualitative trends. Implications of the identified trends are discussed in the context of

Steam explosion triggering phenomena: stainless steel and corium-E simulants studied with a floodable arc melting apparatus

International Nuclear Information System (INIS)

Nelson, L.S.; Buxton, L.D.

1978-05-01

Laboratory-scale experiments on the thermal interaction of light water reactor core materials with water have been performed. Samples (10--35 g) of Type 304 stainless steel and Corium-E simulants were each flooded with approximately 1.5 litres of water to determine whether steam explosions would occur naturally. Many of the experiments also employed artificially induced pressure transients in an attempt to initiate steam explosions. Vigorous interactions were not observed when the triggering pulse was not applied, and for stainless steel the triggering pulse initiated only coarse fragmentation. Two-stage, pressure-producing interactions were triggered for an ''oxidic'' Corium-E simulant. An impulse-initiated gas release theory has been simulated to explain the initial sample fragmentation. Although the delayed second stage of the event is not fully understood, it does not appear to be readily explained with classical vapor explosion theory. Rather, some form of metastability of the melt seems to be involved

Application of factor analysis to the explosive detection

International Nuclear Information System (INIS)

Park, Yong Joon; Song, Byung Chul; Im, Hee Jung; Kim, Won Ho; Cho, Jung Hwan

2005-01-01

The detection of explosive devices hidden in airline baggage is significant problem, particularly in view of the development of modern plastic explosives which can formed into various innocent-appearing shapes and which are sufficiently powerful that small quantities can destroy an aircraft in flight. Besides, the biggest difficulty occurs from long detection time required for the explosive detection system based on thermal neutron interrogation, which involves exposing baggage to slow neutrons having energy in the order of 0.025 eV. The elemental compositions of explosives can be determined by the Neutron Induced Prompt gamma Spectroscopy (NIPS) which has been installed in Korea Atomic Energy Research Institute as a tool for the detection of explosives in passenger baggage. In this work, the factor analysis has been applied to the NIPS system to increase the signal-to-noise ratio of the prompt gamma spectrum for the detection of explosive hidden in a passenger's baggage, especially for the noisy prompt gamma spectrum obtained with short measurement time

The behavior limestone under explosive load

Science.gov (United States)

Orlov, M. Yu; Orlova, Yu N.; Bogomolov, G. N.

2016-11-01

Limestone behavior under explosive loading was investigated. The behavior of the limestone by the action of the three types of explosives, including granular, ammonite and emulsion explosives was studied in detail. The shape and diameter of the explosion craters were obtained. The observed fragments after the blast have been classified as large, medium and small fragments. Three full-scale experiments were carried out. The research results can be used as a qualitative test for the approbation of numerical methods.

The role of fragmentation mechanism in large-scale vapor explosions

International Nuclear Information System (INIS)

Liu, Jie

2003-01-01

A non-equilibrium, multi-phase, multi-component code PROVER-I is developed for propagation phase of vapor explosion. Two fragmentation models are used. The hydrodynamic fragmentation model is the same as Fletcher's one. A new thermal fragmentation model is proposed with three kinds of time scale for modeling instant fragmentation, spontaneous nucleation fragmentation and normal boiling fragmentation. The role of fragmentation mechanisms is investigated by the simulations of the pressure wave propagation and energy conversion ratio of ex-vessel vapor explosion. The spontaneous nucleation fragmentation results in a much higher pressure peak and a larger energy conversion ratio than hydrodynamic fragmentation. The instant fragmentation gives a slightly larger energy conversion ratio than spontaneous nucleation fragmentation, and the normal boiling fragmentation results in a smaller energy conversion ratio. The detailed analysis of the structure of pressure wave makes it clear that thermal detonation exists only under the thermal fragmentation circumstance. The high energy conversion ratio is obtained in a small vapor volume fraction. However, in larger vapor volume fraction conditions, the vapor explosion is weak. In a large-scale vapor explosion, the hydrodynamic fragmentation is essential when the pressure wave becomes strong, so a small energy conversion ratio is expected. (author)

Explosion of a road tanker containing liquefied natural gas

Energy Technology Data Exchange (ETDEWEB)

Planas-Cuchi, E.; Casal, J. [Universitat Politecnica de Catalunya, Catalonia (Spain). CERTEC; Gasulla, N.; Ventosa, A. [Autonomous Government of Catalonia (Spain). General Directorate for Emergencies and Civl Security

2004-07-01

The explosion of a road tanker transporting LNG (one person killed, two injured) is studied. The analysis shows that the explosion, which followed a two-step mode as for the failure of the vessel, could have been a boiling liquid expanding vapor explosion (BLEVE). The overpressure and thermal radiation have been estimated and related to the effects observed. Only a relatively small part of the energy released in the explosion was manifested in the pressure wave. The large fragments (the three pieces into which the tank was broken) and the truck motor were ejected at various distances along the tank's main axis. (author)

A review of conventional explosives detection using active neutron interrogation

International Nuclear Information System (INIS)

Whetstone, Z.D.; Kearfott, K.J.

2014-01-01

Conventional explosives are relatively easy to obtain and may cause massive harm to people and property. There are several tools employed by law enforcement to detect explosives, but these can be subverted. Active neutron interrogation is a viable alternative to those techniques, and includes: fast neutron analysis, thermal neutron analysis, pulsed fast/thermal neutron analysis, neutron elastic scatter, and fast neutron radiography. These methods vary based on neutron energy and radiation detected. A thorough review of the principles behind, advantages, and disadvantages of the different types of active neutron interrogation is presented. (author)

Direct Observation of the Phenomenology of a Solid Thermal Explosion Using Time-Resolved Proton Radiography

International Nuclear Information System (INIS)

Smilowitz, L.; Henson, B. F.; Romero, J. J.; Asay, B. W.; Schwartz, C. L.; Saunders, A.; Merrill, F. E.; Morris, C. L.; Kwiatkowski, K.; Hogan, G.; Nedrow, P.; Murray, M. M.; Thompson, T. N.; McNeil, W.; Rightley, P.; Marr-Lyon, M.

2008-01-01

We present a new phenomenology for burn propagation inside a thermal explosion based on dynamic radiography. Radiographic images were obtained of an aluminum cased solid cylindrical sample of a plastic bonded formulation of octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine. The phenomenology observed is ignition followed by cracking in the solid accompanied by the propagation of a radially symmetric front of increasing proton transmission. This is followed by a further increase in transmission through the sample, ending after approximately 100 μs. We show that these processes are consistent with the propagation of a convective burn front followed by consumption of the remaining solid by conductive particle burning

Thermal interaction of molten copper with water

International Nuclear Information System (INIS)

Zyszkowski, W.

1975-01-01

Experimental work was performed to study the thermal interaction between molten copper particles (in the range of temperature from the copper melting point to about 1800 0 C) and water from about 15-80 0 C. The transient temperatures of the copper particles and water before and during their thermal interaction were measured. The history of the phenomena was filmed by means of a high speed FASTAX camera (to 8000 f/s). Classification of the observed phenomena and description of the heat-transfer modes were derived. One among the phenomena was the thermal explosion. The necessary conditions for the thermal explosion are discussed and their physical interpretation is given. According to the hypothesis proposed, the thermal explosion occurs when the molten metal has the temperature of its solidification and the heat transfer on its surface is sufficiently intensive. The 'sharp-change' of the crystalline structure during the solidification of the molten metal is the cause of the explosion fragmentation. (author)

The surface quasiliquid melt acceleration and the role of thermodynamic phase in the thermal decomposition of crystalline organic explosives

Energy Technology Data Exchange (ETDEWEB)

Henson, Bryan F [Los Alamos National Laboratory

2010-01-01

We show that melt acceleration in the thermal decomposition of crystalline organic solids is a manifestation of the surface quasiliquid phase. We derive a single universal rate law for melt acceleration that is a simple function of the metastable liquid activity below the melting point, and has a zero order term proportional to the quasiliquid thickness. We argue that the underlying mechanisms of this model will provide a molecular definition for the stability of the class of secondary explosives.

Analysis of supercritical vapor explosions using thermal detonation wave theory

Energy Technology Data Exchange (ETDEWEB)

Shamoun, B.I.; Corradini, M.L. [Univ. of Wisconsin, Madison, WI (United States)

1995-09-01

The interaction of certain materials such as Al{sub 2}O{sub 3} with water results in vapor explosions with very high (supercritical) pressures and propagation velocities. A quasi-steady state analysis of supercritical detonation in one-dimensional multiphase flow was applied to analyze experimental data of the KROTOS (26-30) set of experiments conducted at the Joint Research Center at Ispra, Italy. In this work we have applied a new method of solution which allows for partial fragmentation of the fuel in the shock adiabatic thermodynamic model. This method uses known experiment values of the shock pressure and propagation velocity to estimate the initial mixing conditions of the experiment. The fuel and coolant were both considered compressible in this analysis. In KROTOS 26, 28, 29, and 30 the measured values of the shock pressure by the experiment were found to be higher than 25, 50, 100, and 100 Mpa respectively. Using the above data for the wave velocity and our best estimate for the values of the pressure, the predicted minimum values of the fragmented mass of the fuel were found to be 0.026. 0.04, 0.057, and 0.068 kg respectively. The predicted values of the work output corresponding to the above fragmented masses of the fuel were found to be 40, 84, 126, and 150 kJ respectively, with predicted initial void fractions of 112%, 12.5%, 8%, and 6% respectively.

Korea-France collaboration for the preparation of joint proposal for the OECD project on the steam explosion experiments

International Nuclear Information System (INIS)

Song, Jin Ho; Kim, H. D.; Kim, J. H.; Hong, S. W.; Min, B. T.; Park, I. K.

2004-07-01

There are some difficulties in design of the new reactor containment and in establishment of accident management strategy for operating reactors, since there exist a few phenomenological uncertainties in a steam explosion which occurs at the time of the interaction between the corium melt and coolant. So, the OECD/NEA recommended a research which could finalize the unsolved issues in a steam explosion and then an international collaborative research involving US, France, Germany, Japan and Korea, so called the SERENA (Steam Explosion Resolution for Nuclear Application) started in 2002. The first phase of this collaborative research is an analytical research and the second phase is planned to be an experimental research which will start in 2005. Korea and France agreed that both countries would cooperate in the second phase of the SERENA program at the specialist meetings and collaborative committee between the KAERI (Korea Atomic Energy Research Institute) and the CEA (Commissariat a l'Energie Atomique). This preparation research is performed in order to carry out the agreement between Korea and France and propose a collaborative research to the SERENA second phase. The contents of this research is to perform a collaborative research between Korea and France to propose an international collaborative research on a steam explosion research to the OECD. The scope includes the technical exchange for the construction of an international collaborative research and the preparation of a proposal for an international collaborative research for the OECD steam explosion program. Two steam explosion specialist meetings were held to discuss the technical issues in the TROI and KROTOS experiments. A formal accession and amendment agreement for the collaboration was contracted between the KAERI/KINS/CEA/IRSN. And the KAERI's capability to perform an international collaborative research was proved by advertizing the TROI test results to the USNRC/CSARP and JAERI. Also, the English

Gas pressure from a nuclear explosion in oil shale

International Nuclear Information System (INIS)

Taylor, R.W.

1975-01-01

The quantity of gas and the gas pressure resulting from a nuclear explosion in oil shale is estimated. These estimates are based on the thermal history of the rock during and after the explosion and the amount of gas that oil shale releases when heated. It is estimated that for oil shale containing less than a few percent of kerogen the gas pressure will be lower than the hydrostatic pressure. A field program to determine the effects of nuclear explosions in rocks that simulate the unique features of oil shale is recommended. (U.S.)

Radiographic x-ray flux monitoring during explosive experiments by copper activation

International Nuclear Information System (INIS)

Goosman, D.R.

1986-01-01

During radiographic experiments involving explosives, it is valuable to have a method of monitoring the x-ray flux ratio between the dynamic experiment and an x-ray taken of a static object for comparison. The standard method of monitoring with thermoluminescent detectors suffers the disadvantages of being sensitive to temperature, shock, uv radiation, cleanliness and saturation. A flux monitoring system is being studied which is not subject to any of the above disadvantages and is based upon the 63Cu(photon,n)62Cu reaction. The 62Cu has a 10 min half life and is counted by a nuclear pulse counting system within a few minutes of an explosive test. 170 microcoulomb of 19.3 MeV electrons hitting 1.18 mm of Ta produces x-rays which illuminate a 0.8mm thick by 1.6 cm diameter Cu disk placed 46 cm from the Ta. The activated Cu is placed in a counting system with a window between 400 to 600 keV and produces about 42,500 counts in the first 100 sec. counting period. Less than 0.2% of the initial activity is due to other reactions. Photo-induced neutrons in Be parts of the system are shown to produce a negligible effect in the Cu. The main disadvantage of the Cu activation is its sensitivity to electron energy. Monte-Carlo calculations of the excitation function for our accelerator are shown, along with excitation functions for three other configurations

Radiographic x-ray flux monitoring during explosive experiments by copper activation

International Nuclear Information System (INIS)

Goosman, D.R.

1986-01-01

During radiographic experiments involving explosives, it is valuable to have a method of monitoring the X-ray flux ratio between the dynamic experiment and an X-ray taken of a static object for comparison. The standard method of monitoring with thermoluminescent detectors suffers the disadvantages of being sensitive to temperature, shock, UV radiation, cleanliness and saturation. We are studying an additional flux monitoring system which is not subject to any of the above disadvantages and is based upon the 63 Cu(photon,n) 62 Cu reaction. The 62 Cu has a 10 min. half-life and is counted by a nuclear pulse-counting system within a few minutes of an explosive test. 170 MicroCoulomb of 19.3 MeV electrons hitting 1.18mm of Ta produces X-rays which illuminate a 0.8mm thick by 1.6cm diameter Cu disk placed 46cm from the Ta. The activated Cu is placed in a counting system with a window between 400-600 keV and produces about 42500 counts in the first 100 sec counting period. Less than 0.2% of the initial activity is due to other reactions. Photo-induced neutrons in Be parts of the system are shown to produce a negligible effect in the Cu. The main disadvantage of the Cu activation is its sensitivity to electron energy. Monte-Carlo calculations of the excitation function for our accelerator are shown, along with excitation functions for three other configurations

Seismic coupling of nuclear explosions

International Nuclear Information System (INIS)

Larson, D.B.

1989-01-01

The new Giant Magnet Experimental Facility employing digital recording of explosion induced motion has been constructed and successfully tested. Particle velocity and piezoresistance gage responses can be measured simultaneously thus providing the capability for determining the multi-component stress-strain history in the test material. This capability provides the information necessary for validation of computer models used in simulation of nuclear underground testing, chemical explosion testing, dynamic structural response, earth penetration response, and etc. This report discusses fully coupled and cavity decoupled explosions of the same energy (0.622 kJ) were carried out as experiments to study wave propagation and attenuation in polymethylmethacrylate (PMMA). These experiments produced particle velocity time histories at strains from 2 x 10 -3 to as low as 5.8 x 10 -6 . Other experiments in PMMA, reported recently by Stout and Larson 8 provide additional particle velocity data to strains of 10 -1

Biological consequences of atomic explosions

International Nuclear Information System (INIS)

Messerschmidt, O.

1984-01-01

After an introductory chapter of the development and properties of nuclear weapons and the events of Hiroshima and Nagasaki, this books shows the effects of atomic explosions for man: effects of the pressure wave, thermal radiation, initial nuclear radiation alone or in conjunction and possible medical help. In addition the less massive damage caused by induced radioactivity and fallout, their prevention resp. treatment and the malignant/nonmalignant late effects are discussed. A further chapter deals with the psychological and epidemiological effects of atomic explosions, the consequences for food and water supply, and the construction of shetters. The last chapter is concerned with the problem of organising medical help. (MG) [de

A DSC analysis of inverse salt-pair explosive composition

Energy Technology Data Exchange (ETDEWEB)

Babu, E. Suresh; Kaur, Sukhminder [Central Forensic Science Laboratory, Explosives Division, Ramanthapur, Hyderabad 500013 (India)

2004-02-01

Alkali nitrates are used as an ingredient in low explosive compositions and pyrotechnics. It has been suggested that alkali nitrates can form inverse salt-pair explosives with the addition of ammonium chloride. Therefore, the thermal behavior of low explosive compositions containing potassium nitrate mixed with ammonium chloride has been studied using Differential Scanning Calorimetry (DSC). Results provide information about the ion exchange reaction between these two chemical substances and the temperature region at which the formation of a cloud of salt particles of potassium chloride takes place. Furthermore, the addition of ammonium chloride quenches the flame of deflagrating compositions and causes the mixture to undergo explosive decomposition at relatively low temperatures. (Abstract Copyright [2004], Wiley Periodicals, Inc.)

Fire suppression as a thermal implosion

Science.gov (United States)

Novozhilov, Vasily

2017-01-01

The present paper discusses the possibility of the thermal implosion scenario. This process would be a reverse of the well known thermal explosion (autoignition) phenomenon. The mechanism for thermal implosion scenario is proposed which involves quick suppression of the turbulent diffusion flame. Classical concept of the thermal explosion is discussed first. Then a possible scenario for the reverse process (thermal implosion) is discussed and illustrated by a relevant mathematical model. Based on the arguments presented in the paper, thermal implosion may be observed as an unstable equilibrium point on the generalized Semenov diagram for turbulent flame, however this hypothesis requires ultimate experimental confirmation.

Progress in the development of explosives materials detectors

International Nuclear Information System (INIS)

Williams, W.D.; Conrad, F.J.; Sandlin, L.L.; Burrows, T.A.

1978-01-01

Five hand-held explosives vapor detectors (Elscint Model EXD-2, ITI Model 70, Leigh-Marsland Model S-201, Pye Dynamics Model PD.2.A, and Xonics Model GC-710) were evaluated for sensitivity to a variety of explosives, identification of false alarm agents, and general performance and maintenance characteristics. The results of this evaluation, as presented, indicate that there is no single explosives detector which is best-suited for use at all nuclear facilities. Rather, there are several site-specific elements which must be considered when choosing an explosives detector. There are several new explosives detector technologies being developed which will out-perform existing commercial equipment. Some of these new detectors may be commercially available by the end of fiscal year 1980 and will be cost-effective to purchase and operate. The following areas of explosives detection research are discussed: nitrogen-phosphorous detectors, plasma chromatography, mass spectroscopy, small animal olfactory, vapor preconcentration, nuclear quadrupole resonance, far infrared radiation imaging, nuclear magnetic resonance, thermal neutron activation, and computerized tomography

Simulation of thermal phenomena expected in fuel coolant interactions in LMFBRs

International Nuclear Information System (INIS)

Yasin, J.

1976-12-01

High pressures and mechanical work may result when thermal energy is transferred from molten fuel to the coolant in a Liquid Metal Fast Breeder Reactor core meltdown accident. Two aspects of the interaction are examined in the thesis. First, the formation of high pressure pulses termed ''Vapor Explosions,'' and second, the distribution of the molten material into smaller particles, termed ''Fragmentation'', are studied. To understand the nature of the interaction simulant materials were used. Molten bismuth, molten tin and molten glass were dropped into water under various conditions. The interactions were recorded using multiflash and high speed photographing techniques. The pressure pulses were measured using transducers and the debris was examined by photographing them with an electron microscope. It was observed that vapor explosions have thresholds which depend on the material being dropped, its temperature and the bath conditions. The vapor explosions were enhanced by stratifying the bath. It was also noticed that the intensity of the vapor explosion depends on the way the molten drop fragmented in the initial stages of the interaction. The experiments with glass showed that the mode of fragmentation is important in determining when and if a vapor explosion is to be expected. The glass fragmented extensively but without any accompanying vapor explosion. The electron microscope photographs of the glass debris showed that thermal stress and surface tension phenomenon are apparently the cause of the fragmentation

Propagation of Reactions in Thermally-damaged PBX-9501

Energy Technology Data Exchange (ETDEWEB)

Tringe, J W; Glascoe, E A; Kercher, J R; Willey, T M; Springer, H K; Greenwood, D W; Molitoris, J D; Smilowitz, L; Henson, B F; Maienschein, J L

2010-03-05

A thermally-initiated explosion in PBX-9501 (octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine) is observed in situ by flash x-ray imaging, and modeled with the LLNL multi-physics arbitrary-Lagrangian-Eulerian code ALE3D. The containment vessel deformation provides a useful estimate of the reaction pressure at the time of the explosion, which we calculate to be in the range 0.8-1.4 GPa. Closely-coupled ALE3D simulations of these experiments, utilizing the multi-phase convective burn model, provide detailed predictions of the reacted mass fraction and deflagration front acceleration. During the preinitiation heating phase of these experiments, the solid HMX portion of the PBX-9501 undergoes a {beta}-phase to {delta}-phase transition which damages the explosive and induces porosity. The multi-phase convective burn model results demonstrate that damaged particle size and pressure are critical for predicting reaction speed and violence. In the model, energetic parameters are taken from LLNL's thermochemical-kinetics code Cheetah and burn rate parameters from Son et al. (2000). Model predictions of an accelerating deflagration front are in qualitative agreement with the experimental images assuming a mode particle diameter in the range 300-400 {micro}m. There is uncertainty in the initial porosity caused by thermal damage of PBX-9501 and, thus, the effective surface area for burning. To better understand these structures, we employ x-ray computed tomography (XRCT) to examine the microstructure of PBX-9501 before and after thermal damage. Although lack of contrast between grains and binder prevents the determination of full grain size distribution in this material, there are many domains visible in thermally damaged PBX-9501 with diameters in the 300-400 {micro}m range.

GCFR thermal-hydraulic experiments

International Nuclear Information System (INIS)

Schlueter, G.; Baxi, C.B.; Dalle Donne, M.; Gat, U.; Fenech, H.; Hanson, D.; Hudina, M.

1980-01-01

The thermal-hydraulic experimental studies performed and planned for the Gas-Cooled Fast Reactor (GCFR) core assemblies are described. The experiments consist of basic studies performed to obtain correlations, and bundle experiments which provide input for code validation and design verification. These studies have been performed and are planned at European laboratories, US national laboratories, Universities in the US, and at General Atomic Company

MEMS-based Porous Silicon Preconcentrators Filled with Carbopack-B for Explosives Detection

OpenAIRE

Camara , El Hadji Malik; James , Franck; Breuil , Philippe; Pijolat , Christophe; Briand , Danick; De Rooij , Nicolaas F

2014-01-01

International audience; In this paper we report the detection of explosive compounds using a miniaturized gas preconcentrator (μGP) made of porous silicon (PS) filled in with Carbopack B as an adsorbent material. The μGP includes also a platinum heater patterned at the backside and fluidic connectors sealed on the glass cover. Our μGP is designed and optimized through fluidic and thermal simulations for meeting the requirements of trace explosives detection. The thermal mass of the device was...

Headspace concentrations of explosive vapors in containers designed for canine testing and training: theory, experiment, and canine trials.

Science.gov (United States)

Lotspeich, Erica; Kitts, Kelley; Goodpaster, John

2012-07-10

It is a common misconception that the amount of explosive is the chief contributor to the quantity of vapor that is available to trained canines. In fact, this quantity (known as odor availability) depends not only on the amount of explosive material, but also the container volume, explosive vapor pressure and temperature. In order to better understand odor availability, headspace experiments were conducted and the results were compared to theory. The vapor-phase concentrations of three liquid explosives (nitromethane, nitroethane and nitropropane) were predicted using the Ideal Gas Law for containers of various volumes that are in use for canine testing. These predictions were verified through experiments that varied the amount of sample, the container size, and the temperature. These results demonstrated that the amount of sample that is needed to saturate different sized containers is small, predictable and agrees well with theory. In general, and as expected, once the headspace of a container is saturated, any subsequent increase in sample volume will not result in the release of more vapors. The ability of canines to recognize and alert to differing amounts of nitromethane has also been studied. In particular, it was found that the response of trained canines is independent of the amount of nitromethane present, provided it is a sufficient quantity to saturate the container in which it is held. Copyright © 2012 Elsevier Ireland Ltd. All rights reserved.

High-nitrogen explosives

Energy Technology Data Exchange (ETDEWEB)

Naud, D. (Darren); Hiskey, M. A. (Michael A.); Kramer, J. F. (John F.); Bishop, R. L. (Robert L.); Harry, H. H. (Herbert H.); Son, S. F. (Steven F.); Sullivan, G. K. (Gregg K.)

2002-01-01

The syntheses and characterization of various tetrazine and furazan compounds offer a different approach to explosives development. Traditional explosives - such as TNT or RDX - rely on the oxidation of the carbon and hydrogen atoms by the oxygen carrying nitro group to produce the explosive energy. High-nitrogen compounds rely instead on large positive heats of formation for that energy. Some of these high-nitrogen compounds have been shown to be less sensitive to initiation (e.g. by impact) when compared to traditional nitro-containing explosives of similar performances. Using the precursor, 3,6-bis-(3,5-dimethylpyrazol-1-yl)-s-tetrazine (BDT), several useful energetic compounds based on the s-tetrazine system have been synthesized and studied. The compound, 3,3{prime}-azobis(6-amino-s-tetrazine) or DAAT, detonates as a half inch rate stick despite having no oxygen in the molecule. Using perfluoroacetic acid, DAAT can be oxidized to give mixtures of N-oxide isomers (DAAT03.5) with an average oxygen content of about 3.5. This energetic mixture burns at extremely high rates and with low dependency on pressure. Another tetrazine compound of interest is 3,6-diguanidino-s-tetrazine(DGT) and its dinitrate and diperchlorate salts. DGT is easily synthesized by reacting BDT with guanidine in methanol. Using Caro's acid, DGT can be further oxidized to give 3,6-diguanidino-s-tetrazine-1,4-di-N-oxide (DGT-DO). Like DGT, the di-N-oxide can react with nitric acid or perchloric acid to give the dinitrate and the diperchlorate salts. The compounds, 4,4{prime}-diamino-3,3{prime}-azoxyfurazan (DAAF) and 4,4{prime}-diamino-3,3{prime}-azofurazan (DAAzF), may have important future roles in insensitive explosive applications. Neither DAAF nor DAAzF can be initiated by laboratory impact drop tests, yet both have in some aspects better explosive performances than 1,3,5-triamino-2,4,6-trinitrobenzene TATB - the standard of insensitive high explosives. The thermal stability of DAAz

The concept of explosives malfunctioning in rock blasting

Energy Technology Data Exchange (ETDEWEB)

Liu, Q.

1993-11-01

The purpose is to identify the critical conditions that cause malfunctioning for some commonly used explosives. Experiments are described that measure sympathetic detonation, desensitization, and cut-offs for two variables: spacing and delay. Explosive malfunctioning is depicted on a delay spacing chart that has different regions. On the chart, the shape and size of each region can vary from one explosive to another. Results are presented from over 70 blasts, that were conducted in the underground drift at the CANMET Experimental Mine, to identify the malfunctioning characteristics of specific emulsion, water gel, and dynamite explosives. For each experiment, two parallel blastholes (with diameter of 32 mm and depth of 1.7 m) were drilled downwards, and full coupling was achieved. The results are presented for the three types of explosives tested. 11 refs., 7 figs.

Chemical Explosion Experiments to Improve Nuclear Test Monitoring - Developing a New Paradigm for Nuclear Test Monitoring with the Source Physics Experiments (SPE)

International Nuclear Information System (INIS)

Snelson, Catherine M.; Abbott, Robert E.; Broome, Scott T.; Mellors, Robert J.; Patton, Howard J.; Sussman, Aviva J.; Townsend, Margaret J.; Walter, William R.

2013-01-01

A series of chemical explosions, called the Source Physics Experiments (SPE), is being conducted under the auspices of the U.S. Department of Energy's National Nuclear Security Administration (NNSA) to develop a new more physics-based paradigm for nuclear test monitoring. Currently, monitoring relies on semi-empirical models to discriminate explosions from earthquakes and to estimate key parameters such as yield. While these models have been highly successful monitoring established test sites, there is concern that future tests could occur in media and at scale depths of burial outside of our empirical experience. This is highlighted by North Korean tests, which exhibit poor performance of a reliable discriminant, mb:Ms (Selby et al., 2012), possibly due to source emplacement and differences in seismic responses for nascent and established test sites. The goal of SPE is to replace these semi-empirical relationships with numerical techniques grounded in a physical basis and thus applicable to any geologic setting or depth

Vapor generation methods for explosives detection research

Energy Technology Data Exchange (ETDEWEB)

Grate, Jay W.; Ewing, Robert G.; Atkinson, David A.

2012-12-01

The generation of calibrated vapor samples of explosives compounds remains a challenge due to the low vapor pressures of the explosives, adsorption of explosives on container and tubing walls, and the requirement to manage (typically) multiple temperature zones as the vapor is generated, diluted, and delivered. Methods that have been described to generate vapors can be classified as continuous or pulsed flow vapor generators. Vapor sources for continuous flow generators are typically explosives compounds supported on a solid support, or compounds contained in a permeation or diffusion device. Sources are held at elevated isothermal temperatures. Similar sources can be used for pulsed vapor generators; however, pulsed systems may also use injection of solutions onto heated surfaces with generation of both solvent and explosives vapors, transient peaks from a gas chromatograph, or vapors generated by s programmed thermal desorption. This article reviews vapor generator approaches with emphasis on the method of generating the vapors and on practical aspects of vapor dilution and handling. In addition, a gas chromatographic system with two ovens that is configurable with up to four heating ropes is proposed that could serve as a single integrated platform for explosives vapor generation and device testing. Issues related to standards, calibration, and safety are also discussed.

Detection of plastic explosives using thermal neutron radiography

International Nuclear Information System (INIS)

Hacidume, Leo Ryoske

1999-12-01

The work aims to demonstrate the potentiality of the neutron radiography technique, allied to the computerized tomography by transmission, to both detect and visualize plastic explosive samples in several hidden conditions, using a simple scanner as a digitalisation instrument. Each tomographic essay was obtained in the J-9 channel of the Argonauta Research Reactor of IEN/CNEN, in groups of six neutron radiographic projections, performed with an angular increment of 30 deg C, in a period of time of 30 minutes for each projection. Two groups of tomographic reconstructions were generated, distinguished by the digitalisation process of the interested lines in the reconstruction plane coming from the projection groups, utilization a scanner and a microdensitometer, respectively. The reconstruction of the bi-dimensional image of the transverse section, in relation to this plane, was processed making use of the Image Reconstruction Algorithmic of an Image based on the Maximum Entropy principle (ARIEM). From the qualitative analysis of the images, we conclude that the neutron radiographic system was able to detect the explosive sample in a satisfactory way while the quantitative analysis confirmed the application effectiveness of a scanner to acquire the projection dates whose objective is only a reconnaissance. (author)

Reactive flow modeling of small scale detonation failure experiments for a baseline non-ideal explosive

Energy Technology Data Exchange (ETDEWEB)

Kittell, David E.; Cummock, Nick R.; Son, Steven F. [School of Mechanical Engineering, Purdue University, West Lafayette, Indiana 47907 (United States)

2016-08-14

Small scale characterization experiments using only 1–5 g of a baseline ammonium nitrate plus fuel oil (ANFO) explosive are discussed and simulated using an ignition and growth reactive flow model. There exists a strong need for the small scale characterization of non-ideal explosives in order to adequately survey the wide parameter space in sample composition, density, and microstructure of these materials. However, it is largely unknown in the scientific community whether any useful or meaningful result may be obtained from detonation failure, and whether a minimum sample size or level of confinement exists for the experiments. In this work, it is shown that the parameters of an ignition and growth rate law may be calibrated using the small scale data, which is obtained from a 35 GHz microwave interferometer. Calibration is feasible when the samples are heavily confined and overdriven; this conclusion is supported with detailed simulation output, including pressure and reaction contours inside the ANFO samples. The resulting shock wave velocity is most likely a combined chemical-mechanical response, and simulations of these experiments require an accurate unreacted equation of state (EOS) in addition to the calibrated reaction rate. Other experiments are proposed to gain further insight into the detonation failure data, as well as to help discriminate between the role of the EOS and reaction rate in predicting the measured outcome.

Explosion Generated Seismic Waves and P/S Methods of Discrimination from Earthquakes with Insights from the Nevada Source Physics Experiments

Science.gov (United States)

Walter, W. R.; Ford, S. R.; Pitarka, A.; Pyle, M. L.; Pasyanos, M.; Mellors, R. J.; Dodge, D. A.

2017-12-01

The relative amplitudes of seismic P-waves to S-waves are effective at identifying underground explosions among a background of natural earthquakes. These P/S methods appear to work best at frequencies above 2 Hz and at regional distances ( >200 km). We illustrate this with a variety of historic nuclear explosion data as well as with the recent DPRK nuclear tests. However, the physical basis for the generation of explosion S-waves, and therefore the predictability of this P/S technique as a function of path, frequency and event properties such as size, depth, and geology, remains incompletely understood. A goal of current research, such as the Source Physics Experiments (SPE), is to improve our physical understanding of the mechanisms of explosion S-wave generation and advance our ability to numerically model and predict them. The SPE conducted six chemical explosions between 2011 and 2016 in the same borehole in granite in southern Nevada. The explosions were at a variety of depths and sizes, ranging from 0.1 to 5 tons TNT equivalent yield. The largest were observed at near regional distances, with P/S ratios comparable to much larger historic nuclear tests. If we control for material property effects, the explosions have very similar P/S ratios independent of yield or magnitude. These results are consistent with explosion S-waves coming mainly from conversion of P- and surface waves, and are inconsistent with source-size based models. A dense sensor deployment for the largest SPE explosion allowed this conversion to be mapped in detail. This is good news for P/S explosion identification, which can work well for very small explosions and may be ultimately limited by S-wave detection thresholds. The SPE also showed explosion P-wave source models need to be updated for small and/or deeply buried cases. We are developing new P- and S-wave explosion models that better match all the empirical data. Historic nuclear explosion seismic data shows that the media in which

Relative source comparison of the NPE to underground nuclear explosions at local distances

Energy Technology Data Exchange (ETDEWEB)

Smith, A.T. [Lawrence Livermore National Lab., CA (United States)

1994-12-31

The Non-Proliferation Experiment (NPE) provides an opportunity to compare broadband characteristics of chemical to nuclear explosions at a group of local stations (4 to 40 km distant). The locations for these stations were established on bedrock to record a small partially decoupled nuclear explosion and two nearby nuclear experiments, all shots within {open_quotes}N{close_quotes} Tunnel on Rainier Mesa, Area 12. These sites were also occupied to record aftershocks from the Little Skull Mountain earthquake and chemical explosions from the USGS Sierra Experiment. To minimize calibration errors during this period, redundant instrumentation were used for each event. THe analysis emphasizes the source characteristics of the different explosions. The 300-lb chemical calibration explosion allows removal of path effects from each explosion. The NPE and nearby experiments produce very similar waveforms. The decoupled nuclear explosion and the 300-lb chemical calibration explosion show higher frequency content consistent with a higher corner frequency for the sources.

Explosive bonding and its application in the Advanced Photon Source front-end and beamline components design

International Nuclear Information System (INIS)

Shu, D.; Li, Y.; Ryding, D.; Kuzay, T.M.

1994-01-01

Explosive bonding is a bonding method in which the controlled energy of a detonating explosive is used to create a metallurgical bonding between two or more similar or dissimilar materials. Since 1991, a number of explosive-bonding joints have been designed for high-thermal-load ultrahigh-vacuum (UHV) compatible components in the Advanced Photon Source. A series of standardized explosive bonded joint units has also been designed and tested, such as: oxygen-free copper (OFHC) to stainless-steel vacuum joints for slits and shutters, GlidCop to stainless-steel vacuum joints for fixed masks, and GlidCop to OFHC thermal and mechanical joints for shutter face-plates, etc. The design and test results for the explosive bonding units to be used in the Advanced Photon Source front ends and beamlines will be discussed in this paper

Hydrocarbon production with nuclear explosives

International Nuclear Information System (INIS)

Wade Watkins, J.

1970-01-01

The tremendous energy of nuclear explosives and the small dimensions of the explosive package make an ideal combination for drill-hole explosive emplacement in deep, thick hydrocarbon deposits. Potential applications exist in fracturing low permeability natural-gas and petroleum formations for stimulating production, fracturing oil shale to permit in situ retorting, and creating storage chimneys for natural gas, liquefied petroleum gas, petroleum, petroleum products, helium, and other fluids. Calculations show, for example, that less than 100 shots per year would be needed to stabilize the natural gas reserves to production ratio. Under the Government-industry Plowshare program, two experiments, Projects Gasbuggy and Rulison, were conducted to stimulate natural gas production from low-permeability formations. Incomplete information indicates that both were technically successful. Potential problems associated with the use of nuclear explosives for underground engineering applications are radioactive contamination, maximum yield limitations, high costs of detonating contained nuclear explosives, and adverse public opinion. Results at Project Gasbuggy and other considerations indicated that the problem of radioactive contamination was about as predicted and not an insurmountable one. Also, it was demonstrated that shots at adequate depths could be detonated without appreciable damage to existing surface and subsurface buildings, natural features, and equipment. However, costs must be reduced and the public must be better informed before these techniques can be widely used in field operations. On the basis of present knowledge, the potential of nuclear-explosive stimulation of hydrocarbon production appears good. Additional field experiments will be required to adequately explore that potential. (author)

Hydrocarbon production with nuclear explosives

Energy Technology Data Exchange (ETDEWEB)

Wade Watkins, J [Petroleum Research, Bureau of Mines, U.S. Department of the Interior, Washington, DC (United States)

1970-05-01

The tremendous energy of nuclear explosives and the small dimensions of the explosive package make an ideal combination for drill-hole explosive emplacement in deep, thick hydrocarbon deposits. Potential applications exist in fracturing low permeability natural-gas and petroleum formations for stimulating production, fracturing oil shale to permit in situ retorting, and creating storage chimneys for natural gas, liquefied petroleum gas, petroleum, petroleum products, helium, and other fluids. Calculations show, for example, that less than 100 shots per year would be needed to stabilize the natural gas reserves to production ratio. Under the Government-industry Plowshare program, two experiments, Projects Gasbuggy and Rulison, were conducted to stimulate natural gas production from low-permeability formations. Incomplete information indicates that both were technically successful. Potential problems associated with the use of nuclear explosives for underground engineering applications are radioactive contamination, maximum yield limitations, high costs of detonating contained nuclear explosives, and adverse public opinion. Results at Project Gasbuggy and other considerations indicated that the problem of radioactive contamination was about as predicted and not an insurmountable one. Also, it was demonstrated that shots at adequate depths could be detonated without appreciable damage to existing surface and subsurface buildings, natural features, and equipment. However, costs must be reduced and the public must be better informed before these techniques can be widely used in field operations. On the basis of present knowledge, the potential of nuclear-explosive stimulation of hydrocarbon production appears good. Additional field experiments will be required to adequately explore that potential. (author)

Single-charge craters excavated during subsurface high-explosive experiments at Big Black Test Site, Mississippi

International Nuclear Information System (INIS)

Woodruff, W.R.; Bryan, J.B.

1978-01-01

Single-charge and row-charge subsurface cratering experiments were performed to learn how close-spacing enhances single-crater dimensions. Our first experimental phase established cratering curves for 60-lb charges of the chemical explosive. For the second phase, to be described in a subsequent report, the Row-cratering experiments were designed and executed. This data report contains excavated dimensions and auxiliary data for the single-charge cratering experiments. The dimensions for the row-charge experiments will be in the other report. Significant changes in the soil's water content appeared to cause a variability in the excavated dimensions. This variability clouded the interpretation and application of the cratering curves obtained

The fracture of concrete under explosive shock loading

International Nuclear Information System (INIS)

Watson, A.J.; Sanderson, A.J.

1982-01-01

Concrete fracture close to the point of application of high explosive shock pressures has been studied experimentally by placing an explosive charge on the edge of a concrete slab. The extent of the crushing and cracking produced by a semi cylindrical diverging plane compressive stress pulse has been measured and complementary experiments gave the pressure transmitted at an explosive to concrete interface and the stress-strain relation for concrete at explosive strain rates. (orig.) [de

TMX-U [Tandem Mirror Experiment-Upgrade] tandem-mirror thermal-barrier experiments

International Nuclear Information System (INIS)

Simonen, T.C.; Allen, S.L.; Baldwin, D.E.

1986-01-01

Thermal-barrier experiments have been carried out in the Tandem Mirror Experiment-Upgrade (TMX-U). Measurements of nonambipolar and ambipolar radial transport show that these transport processes, as well as end losses, can be controlled at modest densities and durations. Central-cell heating methods using ion-cyclotron heating (ICH) and neutral-beam injection have been demonstrated. Potential mesurements with recently developed methods indicate that deep thermal barriers can be established

Thermal stability and kinetics of decomposition of ammonium nitrate in the presence of pyrite

International Nuclear Information System (INIS)

Gunawan, Richard; Zhang Dongke

2009-01-01

The interaction between ammonium nitrate based industrial explosives and pyrite-rich minerals in mining operations can lead to the occurrence of spontaneous explosion of the explosives. In an effort to provide a scientific basis for safe applications of industrial explosives in reactive mining grounds containing pyrite, ammonium nitrate decomposition, with and without the presence of pyrite, was studied using a simultaneous Differential Scanning Calorimetry and Thermogravimetric Analyser (DSC-TGA) and a gas-sealed isothermal reactor, respectively. The activation energy and the pre-exponential factor of ammonium nitrate decomposition were determined to be 102.6 kJ mol -1 and 4.55 x 10 7 s -1 without the presence of pyrite and 101.8 kJ mol -1 and 2.57 x 10 9 s -1 with the presence of pyrite. The kinetics of ammonium nitrate decomposition was then used to calculate the critical temperatures for ammonium nitrate decomposition with and without the presence of pyrite, based on the Frank-Kamenetskii model of thermal explosion. It was shown that the presence of pyrite reduces the temperature for, and accelerates the rate of, decomposition of ammonium nitrate. It was further shown that pyrite can significantly reduce the critical temperature of ammonium nitrate decomposition, causing undesired premature detonation of the explosives. The critical temperature also decreases with increasing diameter of the blast holes charged with the explosive. The concept of using the critical temperature as indication of the thermal stability of the explosives to evaluate the risk of spontaneous explosion was verified in the gas-sealed isothermal reactor experiments.

Thermal stability and kinetics of decomposition of ammonium nitrate in the presence of pyrite.

Science.gov (United States)

Gunawan, Richard; Zhang, Dongke

2009-06-15

The interaction between ammonium nitrate based industrial explosives and pyrite-rich minerals in mining operations can lead to the occurrence of spontaneous explosion of the explosives. In an effort to provide a scientific basis for safe applications of industrial explosives in reactive mining grounds containing pyrite, ammonium nitrate decomposition, with and without the presence of pyrite, was studied using a simultaneous Differential Scanning Calorimetry and Thermogravimetric Analyser (DSC-TGA) and a gas-sealed isothermal reactor, respectively. The activation energy and the pre-exponential factor of ammonium nitrate decomposition were determined to be 102.6 kJ mol(-1) and 4.55 x 10(7)s(-1) without the presence of pyrite and 101.8 kJ mol(-1) and 2.57 x 10(9)s(-1) with the presence of pyrite. The kinetics of ammonium nitrate decomposition was then used to calculate the critical temperatures for ammonium nitrate decomposition with and without the presence of pyrite, based on the Frank-Kamenetskii model of thermal explosion. It was shown that the presence of pyrite reduces the temperature for, and accelerates the rate of, decomposition of ammonium nitrate. It was further shown that pyrite can significantly reduce the critical temperature of ammonium nitrate decomposition, causing undesired premature detonation of the explosives. The critical temperature also decreases with increasing diameter of the blast holes charged with the explosive. The concept of using the critical temperature as indication of the thermal stability of the explosives to evaluate the risk of spontaneous explosion was verified in the gas-sealed isothermal reactor experiments.

Gas explosion characterization, wave propagation (small-scale experiments)

International Nuclear Information System (INIS)

Larsen, G.C.

1985-01-01

A number of experiments have been performed with blast waves arising from the ignition of homogeneous and well defined mixtures of methane, oxygen and nitrogen, contained within spherical balloons with controlled initial dimensions. In the initial small scale experiments pressure characteristics, ground reflection phenomena and pressure distribution on box like obstacles were studied. Both configurations with one box and two closely spaced boxes have been considered, and a wave-wave interaction phenomenom was observed in the case of closely spaced obstacles. Main emphasis has been placed on the half scale field experiments. In these, the maximum flame speed has been of the order of 100 m/s, resulting in positive peak pressures of 50-100.10 2 Pa in 5 - 10 m distance from the source. The explosion process was found to be reasonable symmetric. The attenuation of the blast wave due to vegetation and the influence of obstacles as banks, walls and houses on the pressure field have been investigated. The presence of the bank and the house was felt in a zone with a length corresponding to a typical dimension of the obstacles, whereas the overall pressure field is shown to be unaffected by the type of obstacles and vegetation investigated. For the wall and house, reflection factors have been established, and some variation over the surface has been measured. The scatter of the pressure measurements is estimated for stable, neutral and unstable atmospheric conditions, and an attempt to determine the ground reflection factor has been performed. Finally the accelerations of a house exposed to the blast wave have been examined

Suppression of stratified explosive interactions

Energy Technology Data Exchange (ETDEWEB)

Meeks, M.K.; Shamoun, B.I.; Bonazza, R.; Corradini, M.L. [Wisconsin Univ., Madison, WI (United States). Dept. of Nuclear Engineering and Engineering Physics

1998-01-01

Stratified Fuel-Coolant Interaction (FCI) experiments with Refrigerant-134a and water were performed in a large-scale system. Air was uniformly injected into the coolant pool to establish a pre-existing void which could suppress the explosion. Two competing effects due to the variation of the air flow rate seem to influence the intensity of the explosion in this geometrical configuration. At low flow rates, although the injected air increases the void fraction, the concurrent agitation and mixing increases the intensity of the interaction. At higher flow rates, the increase in void fraction tends to attenuate the propagated pressure wave generated by the explosion. Experimental results show a complete suppression of the vapor explosion at high rates of air injection, corresponding to an average void fraction of larger than 30%. (author)

Explosive simulants for testing explosive detection systems

Science.gov (United States)

Kury, John W.; Anderson, Brian L.

1999-09-28

Explosives simulants that include non-explosive components are disclosed that facilitate testing of equipment designed to remotely detect explosives. The simulants are non-explosive, non-hazardous materials that can be safely handled without any significant precautions. The simulants imitate real explosives in terms of mass density, effective atomic number, x-ray transmission properties, and physical form, including moldable plastics and emulsions/gels.

A model of vulcanian explosions

International Nuclear Information System (INIS)

Woods, A.W.

1995-01-01

We present a model of the initial stages of the explosive eruption of magma from a volcanic conduit as occurs in Vulcanian style eruptions. We assume there is a volatile rich (1-10 wt%) mixture of magma, vaporised groundwater and exsolved volatiles, trapped at high pressure (1-100 atm) just below a plug in a volcanic conduit. If the plug disrupts, there is an explosive eruption in which a rarefaction wave propagates into the conduit allowing the volatile rich mixture to expand and discharge into the atmosphere ahead of the vent. Typically, the explosions are so rapid that coarse grained ejecta (>0.5 mm) do not remain in thermal equilibrium with the gas, and this leads to significantly lower velocities and temperatures than predicted by an equilibrium model. Material may erupt from the vent at speeds of 100-400 m s -1 with an initial mass flux of order 10 7 -10 9 kg s -1 , consistent with video observations of eruptions and measurements of the ballistic dispersal of large clasts. (orig.)

Shock-induced explosive chemistry in a deterministic sample configuration.

Energy Technology Data Exchange (ETDEWEB)

Stuecker, John Nicholas; Castaneda, Jaime N.; Cesarano, Joseph, III (,; ); Trott, Wayne Merle; Baer, Melvin R.; Tappan, Alexander Smith

2005-10-01

Explosive initiation and energy release have been studied in two sample geometries designed to minimize stochastic behavior in shock-loading experiments. These sample concepts include a design with explosive material occupying the hole locations of a close-packed bed of inert spheres and a design that utilizes infiltration of a liquid explosive into a well-defined inert matrix. Wave profiles transmitted by these samples in gas-gun impact experiments have been characterized by both velocity interferometry diagnostics and three-dimensional numerical simulations. Highly organized wave structures associated with the characteristic length scales of the deterministic samples have been observed. Initiation and reaction growth in an inert matrix filled with sensitized nitromethane (a homogeneous explosive material) result in wave profiles similar to those observed with heterogeneous explosives. Comparison of experimental and numerical results indicates that energetic material studies in deterministic sample geometries can provide an important new tool for validation of models of energy release in numerical simulations of explosive initiation and performance.

Effect of Nano-Magnesium Hydride on the Thermal Decomposition Behaviors of RDX

International Nuclear Information System (INIS)

Yao, M.; Chen, L.; Rao, G.; Peng, J.; Zou, J.; Zeng, X.

2013-01-01

In order to improve the detonation performance of hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) explosive, addictive with high heat values were used, and magnesium hydride (MgH 2 ) is one of the candidates. However, it is important to see whether MgH 2 is a safe addictive. In this paper, the thermal and kinetic properties of RDX and mixture of RDX/MgH 2 were investigated by differential scanning calorimeter (DSC) and accelerating rate calorimeter (ARC), respectively. The apparent activation energy (E) and frequency factor (A) of thermal explosion were calculated based on the data of DSC experiments using the Kissinger and Ozawa approaches. The results show that the addition of MgH 2 decreases both E and A of RDX, which means that the mixture of RDX/MgH 2 has a lower thermal stability than RDX, and the calculation results obtained from the ARC experiments data support this too. Besides, the most probable mechanism functions about the decomposition of RDX and RDX/MgH 2 were given in this paper which confirmed the change of the decomposition mechanism.

Monte Carlo simulation of explosive detection system based on a Deuterium-Deuterium (D-D) neutron generator.

Science.gov (United States)

Bergaoui, K; Reguigui, N; Gary, C K; Brown, C; Cremer, J T; Vainionpaa, J H; Piestrup, M A

2014-12-01

An explosive detection system based on a Deuterium-Deuterium (D-D) neutron generator has been simulated using the Monte Carlo N-Particle Transport Code (MCNP5). Nuclear-based explosive detection methods can detect explosives by identifying their elemental components, especially nitrogen. Thermal neutron capture reactions have been used for detecting prompt gamma emission (10.82MeV) following radiative neutron capture by (14)N nuclei. The explosive detection system was built based on a fully high-voltage-shielded, axial D-D neutron generator with a radio frequency (RF) driven ion source and nominal yield of about 10(10) fast neutrons per second (E=2.5MeV). Polyethylene and paraffin were used as moderators with borated polyethylene and lead as neutron and gamma ray shielding, respectively. The shape and the thickness of the moderators and shields are optimized to produce the highest thermal neutron flux at the position of the explosive and the minimum total dose at the outer surfaces of the explosive detection system walls. In addition, simulation of the response functions of NaI, BGO, and LaBr3-based γ-ray detectors to different explosives is described. Copyright © 2014 Elsevier Ltd. All rights reserved.

Preliminary experiment research of explosively driven opening switch

International Nuclear Information System (INIS)

Li Xiaolin; Chen Dongqun; Li Da; Cao Shengguang; Chen Yingcong

2010-01-01

In pulse power technology field, many loads require high current pulse with fast risetime, but sometimes, the common high current pulse powers don't satisfy request, thus there need pulse erection switches of sorts to shorten pulse risetime. Explosively driven opening switch (EDOS) is a good choice, it has simple structure and excellent performance, the primary parameters of EDOS are opening time, opening resistance, opening current and dissipation energy, which determine its performance and range for applications. For this, two kinds of EDOS are designed and manufactured, in the later experiments, the power supply is a 200 μF capacitor and the conductor is 0.03 mm copper foil, the results indicate that the two kinds of EDOS have good performance, the opening time is about 1-3 μs, the opening resistance is about 1-2 Ω, the opening current is about 24-31 kA and the average dissipation energy is about 0.125-0.34 kJ per groove, the capability of conduction current is adjusted by the thickness of conductor along with different opening current. (authors)

Hydrothermal processes above the Yellowstone magma chamber: Large hydrothermal systems and large hydrothermal explosions

Science.gov (United States)

Morgan, L.A.; Shanks, W.C. Pat; Pierce, K.L.

2009-01-01

Hydrothermal explosions are violent and dramatic events resulting in the rapid ejection of boiling water, steam, mud, and rock fragments from source craters that range from a few meters up to more than 2 km in diameter; associated breccia can be emplaced as much as 3 to 4 km from the largest craters. Hydrothermal explosions occur where shallow interconnected reservoirs of steam- and liquid-saturated fluids with temperatures at or near the boiling curve underlie thermal fields. Sudden reduction in confi ning pressure causes fluids to fl ash to steam, resulting in signifi cant expansion, rock fragmentation, and debris ejection. In Yellowstone, hydrothermal explosions are a potentially signifi cant hazard for visitors and facilities and can damage or even destroy thermal features. The breccia deposits and associated craters formed from hydrothermal explosions are mapped as mostly Holocene (the Mary Bay deposit is older) units throughout Yellowstone National Park (YNP) and are spatially related to within the 0.64-Ma Yellowstone caldera and along the active Norris-Mammoth tectonic corridor. In Yellowstone, at least 20 large (>100 m in diameter) hydrothermal explosion craters have been identifi ed; the scale of the individual associated events dwarfs similar features in geothermal areas elsewhere in the world. Large hydrothermal explosions in Yellowstone have occurred over the past 16 ka averaging ??1 every 700 yr; similar events are likely in the future. Our studies of large hydrothermal explosion events indicate: (1) none are directly associated with eruptive volcanic or shallow intrusive events; (2) several historical explosions have been triggered by seismic events; (3) lithic clasts and comingled matrix material that form hydrothermal explosion deposits are extensively altered, indicating that explosions occur in areas subjected to intense hydrothermal processes; (4) many lithic clasts contained in explosion breccia deposits preserve evidence of repeated fracturing

Thermal energy management process experiment

Science.gov (United States)

Ollendorf, S.

1984-01-01

The thermal energy management processes experiment (TEMP) will demonstrate that through the use of two-phase flow technology, thermal systems can be significantly enhanced by increasing heat transport capabilities at reduced power consumption while operating within narrow temperature limits. It has been noted that such phenomena as excess fluid puddling, priming, stratification, and surface tension effects all tend to mask the performance of two-phase flow systems in a 1-g field. The flight experiment approach would be to attack the experiment to an appropriate mounting surface with a 15 to 20 meter effective length and provide a heat input and output station in the form of heaters and a radiator. Using environmental data, the size, location, and orientation of the experiment can be optimized. The approach would be to provide a self-contained panel and mount it to the STEP through a frame. A small electronics package would be developed to interface with the STEP avionics for command and data handling. During the flight, heaters on the evaporator will be exercised to determine performance. Flight data will be evaluated against the ground tests to determine any anomalous behavior.

Thermal-Hydraulic Experiments and Modelling for Advanced Nuclear Reactor Systems

International Nuclear Information System (INIS)

Song, C. H.; Baek, W. P.; Chung, M. K.

2007-06-01

The objectives of the project are to study thermal hydraulic characteristics of advanced nuclear reactor system for evaluating key thermal-hydraulic phenomena relevant to new safety concepts. To meet the research goal, several thermal hydraulic experiments were performed and related thermal hydraulic models were developed with the experimental data which were produced through the thermal hydraulic experiments. The Followings are main research topics: - Multi-dimensional Phenomena in a Reactor Vessel Downcomer - Condensation-induced Thermal Mixing in a Pool - Development of Thermal-Hydraulic Models for Two-Phase Flow - Construction of T-H Data Base

Effects of molten material temperatures and coolant temperatures on vapor explosion

Institute of Scientific and Technical Information of China (English)

LI Tianshu; YANG Yanhua; YUAN Minghao; HU Zhihua

2007-01-01

An observable experiment facility for low-temperature molten materials to be dropped into water was set up in this study to investigate the mechanism of the vapor explosion. The effect of the fuel and coolant interaction(FCI) on the vapor explosion during the severe accidents of a fission nuclear reactor has been studied. The experiment results showed that the molten material temperature has an important effect on the vapor explosion behavior and pressure. The increase of the coolant temperature would decrease the pressure of the vapor explosion.

Research topics in explosives - a look at explosives behaviors

International Nuclear Information System (INIS)

Maienschein, J L

2014-01-01

The behaviors of explosives under many conditions - e.g., sensitivity to inadvertent reactions, explosion, detonation - are controlled by the chemical and physical properties of the explosive materials. Several properties are considered for a range of improvised and conventional explosives. Here I compare these properties across a wide range of explosives to develop an understanding of explosive behaviors. For improvised explosives, which are generally heterogeneous mixtures of ingredients, a range of studies is identified as needed to more fully understand their behavior and properties. For conventional explosives, which are generally comprised of crystalline explosive molecules held together with a binder, I identify key material properties that determine overall sensitivity, including the extremely safe behavior of Insensitive High Explosives, and discuss an approach to predicting the sensitivity or insensitivity of an explosive.

Close-in airblast from underground explosions

Energy Technology Data Exchange (ETDEWEB)

Vortman, L J [Sandia Laboratories, Albuquerque, NM (United States)

1970-05-15

Air overpressures as a function of time have been measured from surface zero to about 170 ft/lb{sup 1/3} along the ground from nuclear and chemical explosions. Charge depths varied from the surface to depths below which explosion gases are contained. A ground-shock-induced air pressure pulse is clearly distinguishable from the pulse caused by venting gases. Measured peak overpressures show reasonable agreement with the theoretical treatment by Monta. In a given medium the suppression of blast with explosion burial depth is a function of the relative distance at which the blast is observed. Rates of suppression of peak overpressure with charge burial are different for the two pulses. Rates are determined for each pulse over the range of distances at which measurements have been made of air overpressure from chemical explosions in several media. Nuclear data are available from too few shots for similar dependence on burial depth and distance to be developed, but it is clear that the gas venting peak overpressure from nuclear explosions is much more dependent on medium than that from chemical explosions. For above-ground explosions, experiment has shown that airblast from a I-kiloton nuclear explosion is equal to that from a 0.5-kiloton TNT explosion. Data on ground-shock-induced airblast is now sufficient to show that a similar relationship may exist for buried explosions. Because of medium dependence of the gas venting pulse from nuclear explosions, data from additional nuclear events will be required before a chemical/nuclear airblast equivalence can be determined for the gas-venting pulse. (author)

Modelling and simulation of gas explosions in complex geometries

Energy Technology Data Exchange (ETDEWEB)

Saeter, Olav

1998-12-31

This thesis presents a three-dimensional Computational Fluid Dynamics (CFD) code (EXSIM94) for modelling and simulation of gas explosions in complex geometries. It gives the theory and validates the following sub-models : (1) the flow resistance and turbulence generation model for densely packed regions, (2) the flow resistance and turbulence generation model for single objects, and (3) the quasi-laminar combustion model. It is found that a simple model for flow resistance and turbulence generation in densely packed beds is able to reproduce the medium and large scale MERGE explosion experiments of the Commission of European Communities (CEC) within a band of factor 2. The model for a single representation is found to predict explosion pressure in better agreement with the experiments with a modified k-{epsilon} model. This modification also gives a slightly improved grid independence for realistic gas explosion approaches. One laminar model is found unsuitable for gas explosion modelling because of strong grid dependence. Another laminar model is found to be relatively grid independent and to work well in harmony with the turbulent combustion model. The code is validated against 40 realistic gas explosion experiments. It is relatively grid independent in predicting explosion pressure in different offshore geometries. It can predict the influence of ignition point location, vent arrangements, different geometries, scaling effects and gas reactivity. The validation study concludes with statistical and uncertainty analyses of the code performance. 98 refs., 96 figs, 12 tabs.

Soudage par explosion thermique sous charge de cermets poreux à base de TiC-Ni sur substrat en acier-comportement tribologique Welding of porous TiC–Ni based cermets on substrate steel by thermal explosion under load-tribological behaviour

Directory of Open Access Journals (Sweden)

Lemboub Samia

2013-11-01

Full Text Available Dans ce travail, nous nous intéressons à l'élaboration de cermets à base de TiC-Ni par dispersion de particules de carbures, oxydes ou borures dans une matrice de nickel, grâce à la technique de l'explosion thermique sous une charge de 20 MPa. La combustion de mélanges actifs (Ti-C-Ni-An où An = Al2O3, MgO, SiC, TiB2, WC, basée sur la réaction de synthèse de TiC (ΔHf298K = −184 kJ/mole, génère des cermets complexes. Un court maintien sous charge du cermet à 1373 K, après l'explosion thermique, permet son soudage sur un substrat en acier XC55. Les cermets obtenus dans ces conditions demeurent poreux et conservent une porosité de l'ordre de 25–35 %. La densité relative du cermet, sa dureté et son comportement tribologique, dépendront de la nature de l'addition dans les mélanges de départ. Porous TiC-Ni based cermets were obtained by dispersion of carbides, oxides or borides particles in a nickel matrix thanks to the thermal explosion technique realized under a load of 20 MPa. The combustion of active mixtures (Ti-C-Ni-An where An = Al2O3, MgO, SiC, TiB2 or WC based on the titanium carbide reaction synthesis (ΔHf = −184 kJ/mol, generates porous complex cermets. After the thermal explosion, a short maintenance under load at 1373 K of the combustion product, allows at the same time the cermets welding on a carbon steel substrate. The obtained cermets under these conditions preserve a porosity of about 25–35%. The relative density, hardness and tribological behaviour of the complex cermets depend on the additions nature (An in the starting mixtures.

Inhomogeneous wire explosion in water

International Nuclear Information System (INIS)

Hwangbo, C.K.; Kong, H.J.; Lee, S.S.

1980-01-01

Inhomogeneous processes are observed in underwater copper wire explosion induced by a condensed capacitor discharge. The wire used is 0.1 mm in diameter and 10 mm long, and the capacitor of 2 μF is charged to 5 KV. A N 2 laser is used for the diagnostic of spatial extension of exploding copper vapour. The photographs obtained in this experiment show unambiguously the inhomogeneous explosion along the exploding wire. The quenching of plasma by the surrounding water inhibits the expansion of the vapour. It is believed the observed inhomogeneous explosion along the wire is located and localized around Goronkin's striae, which was first reported by Goronkin and discussed by Froengel as a pre-breakdown phenomenon. (author)

Research of thermal stability of ion exchangers

International Nuclear Information System (INIS)

Stuchlik, S.; Srnkova, J.

1983-01-01

Prior to the fixation of radioactive ion exchangers into bitumen these exchangers have to be dried. The resulting gaseous products may generate explosive mixtures. An analysis was made of the thermal stability of two types of ion exchangers, the cation exchanger KU-2-8 cS and the anion exchanger AV-17-8 cS which are used in the V-1 nuclear power plant at Jaslovske Bohunice. The thermal stability of the anion exchangers was monitored using gas chromatography at temperatures of 100, 120, 140, 160 and 180 degC and by measuring weight loss by kiln-drying at temperatures of 120, 140, 160 and 180 degC. The ion exchanger was heated for 6 hours and samples were taken continuously at one hour intervals. The thermal stability of the cation exchanger was monitored by measuring the weight loss. Gas chromatography showed the release of trimethylamine from the anion exchanger in direct dependence on temperature. The measurement of weight losses, however, only showed higher losses of released products which are explained by the release of other thermally unstable products. The analysis of the thermal stability of the cation exchanger showed the release of SO 2 and the weight loss (following correction for water content) was found only after the fourth hour of decomposition. The experiment showed that the drying of anion exchanger AV-17-8 cS may cause the formation of explosive mixtures. (J.P.)

Thermal interaction for molten tin dropped into water

Energy Technology Data Exchange (ETDEWEB)

Arakeri, V.H.; Catton, I.; Kastenberg, W.E.; Plesset, M.S.

1978-03-01

Multiflash photography with extremely short duration exposure times per flash was used to observe the interaction of molten tin dropped into a water bath. Detailed photographic evidence is presented which demonstrates that transition, or nucleate boiling, is a possible triggering mechanism for vapor explosions. It was also found that the thermal constraints required to produce vapor explosions could be relaxed by introducing a stable thermal stratification within the coolant. In the present work, the threshold value of the initial tin temperature required for vapor explosion was reduced from about 500 to 343/sup 0/C.

Comparison between the Findings from the TROI Experiments and the Sensitivity Studies by Using the TEXAS-V Code

International Nuclear Information System (INIS)

Park, I. K.; Kim, J. H.; Hong, S. W.; Min, B. T.; Hong, S. H.; Song, J. H.; Kim, H. D.

2006-01-01

Since a steam explosion may breach the integrity of a reactor vessel and containment, it is one of the most important severe accident issues. So, a lot of experimental and analytical researches on steam explosions have been performed. Although many findings from the steam explosion researches have been obtained, there still exist unsolved issues such as the explosivity of the real core material(corium) and the conversion ratio from the thermal energy to the mechanical energy. TROI experiments were carried out to provide the experimental data for these issues. The TROI experiments were performed with a prototypic material such as ZrO 2 melt and a mixture of ZrO 2 and UO 2 melt (corium). Several steam explosion codes including TEXAS-V had been developed by considering the findings in the past steam explosion experiments. However, some unique findings on steam explosions have been obtained from a series of TROI experiments. These findings should be considered in the application to a reactor safety analysis by using a computational code. In this paper, several findings from TROI experiments are discussed and the sensitivity studies on the TROI experimental parameters were conducted by using TEXAS-V code and TROI-13 test. The comparison between the TROI experimental findings and the results of the sensitivity study might allow us to know which parameter is important and which model is uncertain for steam explosions

Features of the incorporation of single and double based powders within emulsion explosives

Science.gov (United States)

Ribeiro, J. B.; Mendes, R.; Tavares, B.; Louro, C.

2014-05-01

In this work, features of the thermal and detonation behaviour of compositions resulting from the mixture of single and double based powders within ammonium nitrate based emulsion explosives are shown. Those features are portrayed through results of thermodynamic-equilibrium calculations of the detonation velocity, the chemical compatibility assessment through differential thermal analysis [DTA] and thermo gravimetric analysis [TGA], the experimental determination of the detonation velocity and a comparative evaluation of the shock sensitivity using a modified version of the "gap-test". DTA/TGA results for the compositions and for the individual components overlap until the beginning of the thermal decomposition which is an indication of the absence of formation of any new chemical species and so of the compatibility of the components of the compositions. After the beginning of the thermal decomposition it can be seen that the rate of mass loss is much higher for the compositions with powder than for the one with sole emulsion explosive. Both, theoretical and experimental, values of the detonation velocity have been shown to be higher for the powdered compositions than for the sole emulsion explosive. Shock sensitivity assessments have ended-up with a slightly bigger sensitivity for the compositions with double based powder when compared to the single based compositions or to the sole emulsion.

Features of the incorporation of single and double based powders within emulsion explosives

International Nuclear Information System (INIS)

Ribeiro, J B; Mendes, R; Tavares, B; Louro, C

2014-01-01

In this work, features of the thermal and detonation behaviour of compositions resulting from the mixture of single and double based powders within ammonium nitrate based emulsion explosives are shown. Those features are portrayed through results of thermodynamic-equilibrium calculations of the detonation velocity, the chemical compatibility assessment through differential thermal analysis [DTA] and thermo gravimetric analysis [TGA], the experimental determination of the detonation velocity and a comparative evaluation of the shock sensitivity using a modified version of the g ap-test . DTA/TGA results for the compositions and for the individual components overlap until the beginning of the thermal decomposition which is an indication of the absence of formation of any new chemical species and so of the compatibility of the components of the compositions. After the beginning of the thermal decomposition it can be seen that the rate of mass loss is much higher for the compositions with powder than for the one with sole emulsion explosive. Both, theoretical and experimental, values of the detonation velocity have been shown to be higher for the powdered compositions than for the sole emulsion explosive. Shock sensitivity assessments have ended-up with a slightly bigger sensitivity for the compositions with double based powder when compared to the single based compositions or to the sole emulsion.

Seismic coupling of nuclear explosions. Volume 2

Energy Technology Data Exchange (ETDEWEB)

Larson, D B [ed.; Defense Advanced Research Projects Agency, Arlington, VA (United States)

1989-12-31

The new Giant Magnet Experimental Facility employing digital recording of explosion induced motion has been constructed and successfully tested. Particle velocity and piezoresistance gage responses can be measured simultaneously thus providing the capability for determining the multi-component stress-strain history in the test material. This capability provides the information necessary for validation of computer models used in simulation of nuclear underground testing, chemical explosion testing, dynamic structural response, earth penetration response, and etc. This report discusses fully coupled and cavity decoupled explosions of the same energy (0.622 kJ) were carried out as experiments to study wave propagation and attenuation in polymethylmethacrylate (PMMA). These experiments produced particle velocity time histories at strains from 2 {times} 10{sup {minus}3} to as low as 5.8 {times} 10{sup {minus}6}. Other experiments in PMMA, reported recently by Stout and Larson{sup 8} provide additional particle velocity data to strains of 10{sup {minus}1}.

Modelling of vapour explosion in stratified geometrie

International Nuclear Information System (INIS)

Picchi, St.

1999-01-01

When a hot liquid comes into contact with a colder volatile liquid, one can obtain in some conditions an explosive vaporization, told vapour explosion, whose consequences can be important on neighbouring structures. This explosion needs the intimate mixing and the fine fragmentation between the two liquids. In a stratified vapour explosion, these two liquids are initially superposed and separated by a vapor film. A triggering of the explosion can induce a propagation of this along the film. A study of experimental results and existent models has allowed to retain the following main points: - the explosion propagation is due to a pressure wave propagating through the medium; - the mixing is due to the development of Kelvin-Helmholtz instabilities induced by the shear velocity between the two liquids behind the pressure wave. The presence of the vapour in the volatile liquid explains experimental propagation velocity and the velocity difference between the two fluids at the pressure wave crossing. A first model has been proposed by Brayer in 1994 in order to describe the fragmentation and the mixing of the two fluids. Results of the author do not show explosion propagation. We have therefore built a new mixing-fragmentation model based on the atomization phenomenon that develops itself during the pressure wave crossing. We have also taken into account the transient aspect of the heat transfer between fuel drops and the volatile liquid, and elaborated a model of transient heat transfer. These two models have been introduced in a multi-components, thermal, hydraulic code, MC3D. Results of calculation show a qualitative and quantitative agreement with experimental results and confirm basic options of the model. (author)

Specific experiments carried out in Germany in order to demonstrate the safety of existing structures

International Nuclear Information System (INIS)

Krutzik, Norbert

2002-01-01

Specific experiments are carried out in Germany in order to demonstrate the safety of existing NPPs. HDR research program includes operational loads testing (pressure test, pressure and temperature test, thermal shock, fatigue); extreme loads (earthquake, aircraft crash, external explosion); internal emergency loads (blowdown, hydrogen combustion, fire, thermal shock, water hammer, condensation loads)

Numerical modeling and experimental research on the movement of the explosion clouds

International Nuclear Information System (INIS)

Li Xiaoli; Zheng Yi; Liu Wei; Wu Guansheng

2011-01-01

It presents the experimental research and numerical modeling on the movement of explosion clouds. The experiment was performed under two kinds of recorder, one is high speed CCD recorder which was mainly used to record the process of the fireball when the TNT was detonated, and the other is SONY vidicon that was mainly used to record the movement of the clouds. Based on the assumption that the effects on the clouds were gravity and buoyancy, the numerical model on the thermal was established. The initial condition of the thermal that was to say the initial cloud dimension was gained through the results of the recording of the highly CCD recorder. Followed this, the results of the numerical simulation were presented. And the computational results of the rising cloud are reasonable compared to that of the experiment. Thus, it can be seen that the numerical modeling and experimental research methods presented in this paper are reasonable and it can be serve as a reference to related person. Finally, the problems about the experiment and the model are pointed to establish a more accurate model. (authors)

New Mix Explosives for Explosive Welding

Science.gov (United States)

Andreevskikh, Leonid

2011-06-01

Suggested and tested were some mix explosives--powder mixtures of a brisant high explosive (HE = RDX, PETN) and an inert diluent (baking soda)--for use in explosive welding. RDX and PETN were selected in view of their high throwing ability and low critical diameter. Since the decomposition of baking soda yields a huge amount of gaseous products, its presence ensures (even at a low HE percentage) a throwing speed that is sufficient for realization of explosive welding, at a reduced brisant action of charge. Mix chargers containing 30-70 wt % HE (the rest baking soda) have been tested experimentally and optimized. For study of possibility to reduce critical diameter of HE mixture, the mixture was prepared where HE crystal sizes did not exceed 10 μm. The tests, which were performed with this HE, revealed that the mixture detonated stably with the velocity D ~ 2 km/s, if the layer thickness was d = 2 mm. The above explosives afford to markedly diminish deformations within the oblique impact zone and thus to carry out explosive welding of hollow items and thin metallic foils.

Five-component propagation model for steam explosion analysis

International Nuclear Information System (INIS)

Yang, Y.; Moriyama, Kiyofumi; Park, H.S.; Maruyama, Yu; Sugimoto, Jun

1999-01-01

A five-field simulation code JASMINE-pro has been developed at JAERI for the calculation of the propagation and explosion phase of steam explosions. The basic equations and the constitutive relationships specifically utilized in the propagation models in the code are introduced in this paper. Some calculations simulating the KROTOS 1D and 2D steam explosion experiments are also stated in the paper to show the present capability of the code. (author)

Pressurized-thermal-shock experiments

International Nuclear Information System (INIS)

Whitman, G.D.; McCulloch, R.W.

1982-01-01

The primary objective of the ORNL pressurized-thermal-shock (PTS) experiments is to verify analytical methods that are used to predict the behavior of pressurized-water-reactor vessels under these accident conditions involving combined pressure and thermal loading. The criteria on which the experiments are based are: scale large enough to attain effective flaw border triaxial restraint and a temperature range sufficiently broad to produce a progression from frangible to ductile behavior through the wall at a given time; use of materials that can be completely characterized for analysis; stress states comparable to the actual vessel in zones of potential flaw extension; range of behavior to include cleavage initiation and arrest, cleavage initiation and arrest on the upper shelf, arrest in a high K/sub I/ gradient, warm prestressing, and entirely ductile behavior; long and short flaws with and without stainless steel cladding; and control of loads to prevent vessel burst, except as desired. A PTS test facility is under construction which will enable the establishment and control of wall temperature, cooling rate, and pressure on an intermediate test vessel (ITV) in order to simulate stress states representative of an actual reactor pressure vessel

78 FR 64246 - Commerce in Explosives; List of Explosives Materials

Science.gov (United States)

2013-10-28

..., including non-cap sensitive slurry and water gel explosives. Blasting caps. Blasting gelatin. Blasting.... Explosive conitrates. Explosive gelatins. Explosive liquids. Explosive mixtures containing oxygen-releasing... powder. [[Page 64247

Characteristics of a plasma flow field produced by a metal array bridge foil explosion

Science.gov (United States)

Junying, WU; Long, WANG; Yase, LI; Lijun, YANG; Manzoor, SULTAN; Lang, CHEN

2018-07-01

To improve the energy utilization efficiency of metal bridge foil explosion, and increase the function range of plasmas, array bridge foil explosion experiments with different structures were performed. A Schlieren photographic measurement system with a double-pulse laser source was used to observe the flow field of a bridge foil explosion. The evolution laws of plasmas and shock waves generated by array bridge foil explosions of different structures were analyzed and compared. A multi-phase flow calculation model was established to simulate the electrical exploding process of a metal bridge foil. The plasma equation of state was determined by considering the effect of the changing number of particles and Coulomb interaction on the pressure and internal energy. The ionization degree of the plasma was calculated via the Saha–Eggert equation assuming conditions of local thermal equilibrium. The exploding process of array bridge foils was simulated, and the superposition processes of plasma beams were analyzed. The variation and distribution laws of the density, temperature, pressure, and other important parameters were obtained. The results show that the array bridge foil has a larger plasma jet diameter than the single bridge foil for an equal total area of the bridge foil. We also found that the temperature, pressure, and density of the plasma jet’s center region sharply increase because of the superposition of plasma beams.

Modelling of vapour explosion in a stratified geometry

International Nuclear Information System (INIS)

Brayer, Claude

1994-01-01

A vapour explosion is the explosive vaporisation of a volatile liquid in contact with another hotter liquid. Such a violent vaporisation requires an intimate mixing and a fine fragmentation of both liquids. Based on a synthesis of published experimental results, the author of this research thesis reports the development of a new physical model which describes the explosion. In this model, the explosion propagation is due to the propagation of the pressure wave associated with this this explosion, all along the vapour film which initially separates both liquids. The author takes the presence of water in the liquid initially located over the film into account. This presence of vapour explains experimental propagation rates. Another consequence, when the pressure wave passes, is an acceleration of liquids at different rates below and above the film. The author considers that a mixture layer then forms from the point of disappearance of the film, between both liquids, and that fragmentation is due to the turbulence in this mixture layer. This fragmentation model is then introduced into an Euler thermodynamic, three-dimensional and multi-constituents code of calculation, MC3D, to study the influence of fragmentation on thermal exchanges between the various constituents on the volatile liquid vaporisation [fr

Multi-scale fracture damage associated with underground chemical explosions

Science.gov (United States)

Swanson, E. M.; Sussman, A. J.; Wilson, J. E.; Townsend, M. J.; Prothro, L. B.; Gang, H. E.

2018-05-01

Understanding rock damage induced by explosions is critical for a number of applications including the monitoring and verification of underground nuclear explosions, mine safety issues, and modeling fluid flow through fractured rock. We use core observations, televiewer logs, and thin section observations to investigate fracture damage associated with two successive underground chemical explosions (SPE2 and SPE3) in granitic rock at both the mesoscale and microscale. We compare the frequency and orientations of core-scale fractures, and the frequency of microfractures, between a pre-experiment core and three post-experiment cores. Natural fault zones and explosion-induced fractures in the vicinity of the explosive source are readily apparent in recovered core and in thin sections. Damage from faults and explosions is not always apparent in fracture frequency plots from televiewer logs, although orientation data from these logs suggests explosion-induced fracturing may not align with the pre-existing fracture sets. Core-scale observations indicate the extent of explosion-induced damage is 10.0 m after SPE2 and 6.8 m after SPE3, despite both a similar size and location for both explosions. At the microscale, damage is observed to a range distance of 10.2 ± 0.9 m after SPE2, and 16.6 ± 0.9 and 11.2 ± 0.6 in two different cores collected after SPE3. Additional explosion-induced damage, interpreted to be the result of spalling, is readily apparent near the surface, but only in the microfracture data. This depth extent and intensity of damage in the near-surface region also increased after an additional explosion. This study highlights the importance of evaluating structural damage at multiple scales for a more complete characterization of the damage, and particularly shows the importance of microscale observations for identifying spallation-induced damage.

Reactive thermal waves in energetic materials

Energy Technology Data Exchange (ETDEWEB)

Hill, Larry G [Los Alamos National Laboratory

2009-01-01

Reactive thermal waves (RTWs) arise in several energetic material applications, including self-propagating high-temperature synthesis (SHS), high explosive cookoff, and the detonation of heterogeneous explosives. In this paper I exmaine ideal RTWs, by which I mean that (1) material motion is neglected, (2) the state dependence of reaction is Arrhenius in the temperature, and (3) the reaction rate is modulated by an arbitrary mass-fraction-based reaction progress function. Numerical simulations demonstrate that one's natural intuition, which is based mainly upon experience with inert materials and which leads one to expect diffusion processes to become relatively slow after a short time period, is invalid for high energy, state-sensitive reactive systems. Instead, theory predicts that RTWs can propagate at very high speeds. This result agrees with estimates for detonating heterogeneous explosives, which indicate that RTWs must spread from hot-spot nucleation sites at rates comparable to the detonation speed in order to produce experimentally-observed reaction zone thicknesses. Using dimensionless scaling and further invoking the high activation energy approximation, I obtain an analytic formula for the steady plane RTW speed from numerical calculations. I then compute the RTW speed for real explosives, and discuss aspects of their behavior.

Thermal interaction for molten tin dropped into water

International Nuclear Information System (INIS)

Arakeri, V.H.; Catton, I.; Kastenberg, W.E.; Plesset, M.S.

1978-01-01

Multiflash photography with extremely short duration exposure times per flash has been used to observe the interaction of molten tin dropped into a water bath. Detailed photographic evidence is presented which demonstrates that transition, or nucleate boiling, is a possible triggering mechanism for vapour explosions. It was also found that the thermal constraints required to produce vapour explosions could be relaxed by introducing a stable thermal stratification within the coolant. In the present work, the threshold value of the initial tin temperature required for vapour explosion was reduced from about 500 to 343 0 C. (author)

Explosive Leidenfrost droplets

Science.gov (United States)

Colinet, Pierre; Moreau, Florian; Dorbolo, Stéphane

2017-11-01

We show that Leidenfrost droplets made of an aqueous solution of surfactant undergo a violent explosion in a wide range of initial volumes and concentrations. This unexpected behavior turns out to be triggered by the formation of a gel-like shell, followed by a sharp temperature increase. Comparing a simple model of the radial surfactant distribution inside a spherical droplet with experiments allows highlighting the existence of a critical surface concentration for the shell to form. The temperature rise (attributed to boiling point elevation with surface concentration) is a key feature leading to the explosion, instead of the implosion (buckling) scenario reported by other authors. Indeed, under some conditions, this temperature increase is shown to be sufficient to trigger nucleation and growth of vapor bubbles in the highly superheated liquid bulk, stretching the surrounding elastic shell up to its rupture limit. The successive timescales characterizing this explosion sequence are also discussed. Funding sources: F.R.S. - FNRS (ODILE and DITRASOL projects, RD and SRA positions of P. Colinet and S. Dorbolo), BELSPO (IAP 7/38 MicroMAST project).

Structures to Resist the Effects of Accidental Explosions. Volume 6. Special Considerations in Explosive Facility Design

Science.gov (United States)

1985-04-01

addition to their Inherent advantages with respect to fire protection, acoustical and thermal insulation, structural mass and resistance to flying...suspended from a monorail system. The panel is inside the shield and is not rigidly attached to the column members. Special consideration was given to...characteristic pulse emitted by an explosion to prevent actuation by other sources such as lightning, fires , etc., **ich cay occur with flash sensors. ■112

Response of Radon in a seismic calibration explosion, Israel

International Nuclear Information System (INIS)

Zafrir, H.; Steinitz, G.; Malik, U.; Haquin, G.; Gazit-Yaari, N.

2009-01-01

Radon measurements were performed at shallow levels during an in-land 20-ton seismic calibration explosion experiment, simulating a 2.6-M L earthquake, to investigate the influence of the explosive blast and the transitory seismic wave fields on the Radon transport in the country rock, adjacent to the focus of the explosion. The experiment was conducted in a basalt quarry in the northern margin of the Beit Shean valley (Israel). Five gamma-ray sensors were placed, at a depth of about 2 m, along a line located 17-150 m from the edge of the explosion zone. Measurements commenced 4 days before and continued for 9 days after the explosion with 15 min integrations. A 10-s sampling was used in the interval of several hours before and after the explosion itself. Diurnal variations of Radon, reflecting the typical variation pattern of Radon in the shallow environment, were registered before and after the explosion. No significant change in the overall Radon concentration was observed as a consequence of the main explosion as well as three smaller experimental shots (0.5-2 tons) in the 2 h prior to the calibration blast. The seismological data indicate that the transient excess pressure at the farthest Radon sensor was above 5 bar m -1 during 0.2-0.4 s, and evidently much higher at the nearest sensors, but none of the sensors responded by recording any exceptional change in the Radon concentration. Moreover the hypothesis that additional Radon may emanate from solid grains as a result of the excess local pressure exerted by the blast is also not observed. In contrast to a real earthquake event an explosion experiment has neither eventual preceding nor following geodynamic activity. Therefore the absence of significant Radon anomalies during or after the blast does not contradict assumptions, observations or conclusions as the occurrence of Radon anomalies prior or after an earthquake event due to associated long-term geodynamic processes.

Strategies for the disposition of high explosives resulting from dismantlement of nuclear weapons

International Nuclear Information System (INIS)

Pruneda, C.; Humphrey, J.

1993-03-01

Many thousands of pounds of high quality main-charge explosives will result as surplus from the dismantlement of returns from the US nuclear weapons stockpile. The method most often employed for dealing with this surplus explosive is destruction by open burning. However, open burning as a means of treating excess explosives is losing favor because of environmental concerns associated with such an uncontrolled thermal destruction process. Thus, alternative processes for treatment of excess explosives from weapon dismantlement is discussed. These alternatives include: reformulation, crystalline component recovery, chemical conversion of the crystalline component to higher value products which may have civilian or military applications and, when necessary, treatment as waste in an environmentally benign fashion

Proceedings of the fourteenth annual symposium on explosives and blasting research

Energy Technology Data Exchange (ETDEWEB)

NONE

1998-12-31

Subjects covered include: ground vibration effects on structures; open-pit blast vibration prediction; effects of velocity of detonation and gas pressurization on fragmentation in layered rock; thermal ignition for emulsion powder explosives and emulsion matrix; effect of cut-off pressure on energy partition and blast design; new burden and spacing formulae for optimum blasting; calculated risk of experiencing lightning caused unplanned detonation; predicting explosive toxic fumes; and stemming techniques for loading angled holes charged with Anfo.

Contained fissionly vaporized imploded fission explosive breeder reactor

International Nuclear Information System (INIS)

Marwick, E.F.

1978-01-01

Disclosed is a nuclear reactor system which produces useful thermal power and breeds fissile isotopes wherein large spherical complex slugs containing fissile and fertile isotopes as well as vaporizing and tamping materials are exploded seriatim in a large containing chamber having walls protected from the effects of the explosion by about two thousand tons of slurry of fissile and fertile isotopes in molten alkali metal. The slug which is slightly sub-critical prior to its entry into the centroid portion of the chamber, then becomes slightly more than prompt-critical because of the near proximity of neutron-reflecting atoms and of fissioning atoms within the slurry. The slurry is heated by explosion of the slugs and serves as a working fluid for extraction of heat energy from the reactor. Explosive debris is precipitated from the slurry and used for the fabrication of new slugs

High-temperature explosive development for geothermal well stimulation. Final report

Energy Technology Data Exchange (ETDEWEB)

Schmidt, E.W.; Mars, J.E.; Wang, C.

1978-03-31

A two-component, temperature-resistant liquid explosive called HITEX has been developed which is capable of withstanding 561/sup 0/K (550/sup 0/F) for 24 hours in a geothermal environment. The explosive is intended for the stimulation of nonproducing or marginally producing geothermal (hot dry rock, vapor-dominated or hydrothermal) reservoirs by fracturing the strata in the vicinity of a borehole. The explosive is inherently safe because it is mixed below ground downhole from two nondetonable liquid components. Development and safety tests included differential scanning calorimetry, thermal stability, minerals compatibility, drop-weight sensitivity, adiabatic compression, electrostatic discharge sensitivity, friction sensitivity, detonation arrest capability, cook-off tests, detonability at ambient and elevated pressure, detonation velocity and thin film propagation in a wedge.

TMX-U thermal-barrier experiments

International Nuclear Information System (INIS)

Simonen, T.C.; Allen, S.L.; Barter, J.D.

1988-01-01

This review of thermal-barrier experiments in the Tandem Mirror Experiment Upgrade (TMX-U) describes our progress at Lawrence Livermore National Laboratory in plasma confinement and central-cell heating. Thermal barriers in TMX-U improved axial confinement by two orders of magnitude over a limited range of densities, compared with confinement in single-cell mirrors at the same ion temperature. Our study shows that central-cell radial nonambipolar confinement scales as neoclassical theory and can be eliminated by floating the end walls. Radial ambipolar losses can also be measured and reduced. The electron energy balance is improved in tandem mirrors to near classical, resulting in T/sub e/ up to 0.28 keV. Electron cyclotron heating (ECH) efficiencies up to 42 percent, with low levels of electron microinstability, were achieved when hot electrons in the thermal barrier were heated to average betas as large as 15 percent. The hot-electron distribution is measured from X rays and is modeled by a Fokker-Planck code that includes heating from cavity radio-frequency (RF) fields. Neutral-beam injection in the central cell created average ion betas up to 5 percent with radial profiles of hot ions that are modeled accurately by a radial Fokker-Planck code. Gas fueling between two fundamental ion cyclotron heating (ICH) resonances resulted in symmetrical heating of passing ions toward both ends

The use of contained nuclear explosions to create underground reservoirs, and experience of operating these for gas condensate storage

International Nuclear Information System (INIS)

Kedrovskij, O.L.; Myasnikov, K.V.; Leonov, E.A.; Romadin, N.M.; Dorodnov, V.F.; Nikiforov, G.A.

1975-01-01

Investigations on the creation of underground reservoirs by means of nuclear explosions have been going on in the Soviet Union for many years. In this paper the authors consider three main kinds of sites or formations that can be used for constructing reservoirs by this method, namely, low-permeable rocks, worked-out mines and rock salt formations. Formulae are given for predicting the mechanical effect of an explosion in rocks, taking their strength characteristics into account. Engineering procedures are described for sealing and restoring the emplacement holes, so that they can be used for operating the underground reservoir. Experience with the contruction and operation of a 50 000 m 3 gas-condensate reservoir in a rock salt formation is described. In the appendix to the paper a method is presented for calculating the stability of spherical cavities created by nuclear explosions in rock salt, allowing for the development of elasto-plastic deformations and creep

Detection of explosives and illicit drugs using neutrons

Energy Technology Data Exchange (ETDEWEB)

Kiraly, B. E-mail: kiralyb@tigris.klte.hu; Sanami, T.; Doczi, R.; Csikai, J

2004-01-01

A procedure developed for the determination of the flux perturbation factor required for the thermal neutron activation analysis of bulky samples of unknown composition has been extended for epithermal neutrons using hydrogenous and graphite moderators. Measurements on the diffusion and backscattering of thermal neutrons in soil components were carried out for the development of novel nuclear methods in order to speed up the humanitarian demining process. Results obtained for the diffusion length were checked by MCNP-4C calculations. In addition, the effect of the weight and density of the explosives on the observation of the anomaly in the reflected thermal neutrons was examined by using different dummy landmines.

Design and construction of an explosive detection system by Tna methods, using 252Cf radioisotope source

International Nuclear Information System (INIS)

Tavakkoli Farsouli, A.

1999-01-01

Bombs concealed in luggage have threatened human life and property throughout the world's traffic. The plastic explosives could not checked by the X-ray detecting device. Thermal Neutron Activation method has been tested in the present work for non-destructive detection of explosives. A radioisotope neutron source 252 Cf and two gamma spectroscopy systems have been used as a tool to find explosives, regardless of the bomb's shape and the packing materials. The MCNP code has been used to design the neutronic section of the system. The measured thermal neutron fluxes by the gold foils in some location of the system were in good agreement with those data obtained by the MCNP code. Also, detection limits for nitrogen in various counting times were measured. The measurements show that the system is capable to detect 417 gr of HMX explosive material (158 gr nitrogen) by 10 minutes of counting time. To modify the system and to decrease the detection limits some opinions are given

Primary explosives

Energy Technology Data Exchange (ETDEWEB)

Matyas, Robert; Pachman, Jiri [Pardubice Univ. (Czech Republic). Faculty of Chemical Technology

2013-06-01

The first chapter provides background such as the basics of initiation and differences between requirements on primary explosives used in detonators and igniters. The authors then clarify the influence of physical characteristics on explosive properties, focusing on those properties required for primary explosives. Furthermore, the issue of sensitivity is discussed. All the chapters on particular groups of primary explosives are structured in the same way, including introduction, physical and chemical properties, explosive properties, preparation and documented use.

A thermodynamically based definition of fast verses slow heating in secondary explosives

Science.gov (United States)

Henson, Bryan; Smilowitz, Laura

2013-06-01

The thermal response of energetic materials is often categorized according to the rate of heating as either fast or slow, e.g. slow cook-off. Such categorizations have most often followed some operational rationale, without a material based definition. We have spent several years demonstrating that for the energetic material octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) a single mechanism of thermal response reproduces times to ignition independent of rate or means of heating over the entire range of thermal response. HMX is unique in that bulk melting is rarely observed in either thermal ignition or combustion. We have recently discovered a means of expressing this mechanism for HMX in a reduced form applicable to many secondary explosives. We will show that with this mechanism a natural definition of fast versus slow rates of heating emerges, related to the rate of melting, and we use this to illustrate why HMX does not exhibit melting, and why a number of other secondary explosives do, and require the two separate categories.

Radioactive and Other Effects of Nuclear Explosion

International Nuclear Information System (INIS)

Ilijas, B.; Cizmek, A.; Prah, M.; Medakovic, S.

2008-01-01

As a result of long lasting efforts of international community to definitely ban all test nuclear explosions, the Comprehensive Nuclear-Test-Ban Treaty (CTBT) was opened for signature in New York on 24 September 1996, when it was signed by 71 states, including Croatia. The State Office for Nuclear Safety (SONS) which, as an independent state regulatory authority has a responsibility for activities relating to nuclear safety, including the national authority over this Treaty, is actively engaged in CTBTO activities. The nuclear explosion causes a lot of effects (blast, thermal, radioactive, electromagnetic) which differs a lot in its nature, reach, lasting and other. The longest lasting aftermath is from the radioactive effects that cause a radioactive fallout and a lot of radioactive elements in the environment, created by the influence of a primary beam of radiation. Fission and fusion are the main source of radionuclide created by the nuclear explosion, and the longest lasting aftermaths are by the fission products, namely their offspring in natural disintegration chains. This can make contaminated areas inappropriate for life for very long periods. Even in the case of underground nuclear explosion (when underground cavity is formed with no effects on the surface), a leakage of radioactive gases through cracks is possible. A number of radionuclide is created by the neutron activation of elements naturally present in an environment, because a very strong neutron radiation appears in the moment of nuclear explosion. The abundance of particular radionuclide is a very much dependent of a place of performing nuclear explosion and a composition of soil or water in the vicinity.(author)

Explosive Evaporating Phenomena of Cryogenic Fluids by Direct Contacting Normal Temperature Fluids

Directory of Open Access Journals (Sweden)

T Watanabe

2016-09-01

Full Text Available Cryogenic fluids have characteristics such as thermal stratification and flashing by pressure release in storage vessel. The mixture of the extreme low temperature fluid and the normal temperature fluid becomes the cause which causes pressure vessel and piping system crush due to explosive boiling and rapid freezing. In recent years in Japan, the demand of cryogenic fluids like a LH2, LNG is increasing because of the advance of fuel cell device technology, hydrogen of engine, and stream of consciousness for environmental agreement. These fuel liquids are cryogenic fluids. On the other hand, as for fisheries as well, the use of a source of energy that environment load is small has been being a pressing need. And, the need of the ice is high, as before, for keeping freshness of marine products in fisheries. Therefore, we carried out the experiments related to promotion of evaporating cryogenic fluids and generation of ice, in the contact directly of the water and liquid nitrogen. From the results of visualization, phenomena of explosive evaporating and ice forming were observed by using video camera.

Industry potential of large scale uses for peaceful nuclear explosives

Energy Technology Data Exchange (ETDEWEB)

Russell, P L [Bureau of Mines, Denver, CO (United States)

1969-07-01

The industrial potential for peaceful uses of nuclear explosions entering a critical stage of development. Should Project Gasbuggy, an experiment to determine to what extent an underground nuclear explosion can stimulate the production of natural gas from low-permeability formations, prove a technical or economic success, a great step forward will have been made. Should other experiments now being considered in natural gas, oil shale, copper, coal, water resources, underground storage, and others, also demonstrate technical or economic advantage, it is conceivable to expect peaceful nuclear explosion to grow from our current rate of one or two experimental shots per year to hundreds of production explosions per year. This growth rate could be severely restricted or reduced to zero if public safety and environmental control cannot be exercised. (author)

Industry potential of large scale uses for peaceful nuclear explosives

International Nuclear Information System (INIS)

Russell, P.L.

1969-01-01

The industrial potential for peaceful uses of nuclear explosions entering a critical stage of development. Should Project Gasbuggy, an experiment to determine to what extent an underground nuclear explosion can stimulate the production of natural gas from low-permeability formations, prove a technical or economic success, a great step forward will have been made. Should other experiments now being considered in natural gas, oil shale, copper, coal, water resources, underground storage, and others, also demonstrate technical or economic advantage, it is conceivable to expect peaceful nuclear explosion to grow from our current rate of one or two experimental shots per year to hundreds of production explosions per year. This growth rate could be severely restricted or reduced to zero if public safety and environmental control cannot be exercised. (author)

Lower head integrity under steam explosion loads

Energy Technology Data Exchange (ETDEWEB)

Theofanous, T.G.; Yuen, W.W.; Angelini, S.; Freeman, K.; Chen, X.; Salmassi, T. [Center for Risk Studies and Safety, Univ. of California, Santa Barbara, CA (United States); Sienicki, J.J.

1998-01-01

Lower head integrity under steam explosion loads in an AP600-like reactor design is considered. The assessment is the second part of an evaluation of the in-vessel retention idea as a severe accident management concept, the first part (DOE/ID-10460) dealing with thermal loads. The assessment is conducted in terms of the Risk Oriented Accident Analysis Methodology (ROAAM), and includes the comprehensive evaluation of all relevant severe accident scenarios, melt conditions and timing of release from the core region, fully 3D mixing and explosion wave dynamics, and lower head fragility under local, dynamic loading. All of these factors and brought together in a ROAAM Probabilistic Framework to evaluate failure likelihood. The conclusion is that failure is `physically unreasonable`. (author)

CTBT calibration explosions at the Semipalatinsk test site (1997-2000)

International Nuclear Information System (INIS)

Leith, W.; Kluchko, L.J.; Knowles, C.P.; Linger, D.A.; Gabriel, L.; Belyashova, N.N.; Tukhvatulin, Sh.T.; Demin, V.N.; Konovalov, V.E.

2000-01-01

The article shows the results of experiments, conducted together by American and Kazakhstan researchers at the Semipalatinsk test site during 6 chemical calibration explosions and preparation of the seventh between 1997 and 2000. The main goal of the experiments is calibration of International Monitoring System for Comprehensive Test Ban Treaty and development of understanding of explosions as seismic sources. (author)

Analysis and modeling of flow blockage-induced steam explosion events in the High-Flux Isotope Reactor

International Nuclear Information System (INIS)

Taleyarkhan, R.P.; Georgevich, V.; Lestor, C.W.; Gat, U.; Lepard, B.L.; Cook, D.H.; Freels, J.; Chang, S.J.; Luttrell, C.; Gwaltney, R.C.; Kirkpatrick, J.

1993-01-01

This paper provides a perspective overview of the analysis and modeling work done to evaluate the threat from steam explosion loads in the High-Flux Isotope Reactor during flow blockage events. The overall workscope included modeling and analysis of core melt initiation, melt propagation, bounding and best-estimate steam explosion energetics, vessel failure from fracture, bolts failure from exceedance of elastic limits, and finally, missile evolution and transport. Aluminum ignition was neglected. Evaluations indicated that a thermally driven steam explosion with more than 65 MJ of energy insertion in the core region over several miliseconds would be needed to cause a sufficiently energetic missile with a capacity to cause early confinement failure. This amounts to about 65% of the HFIR core mass melting and participating in a steam explosion. Conservative melt propagation analyses have indicated that at most only 24% of the HFIR core mass could melt during flow blockage events under full-power conditions. Therefore, it is judged that the HFIR vessel and top head structure will be able to withstand loads generated from thermally driven steam explosions initiated by any credible flow blockage event. A substantial margin to safety was demonstrated

Charging method of water hole with ANFO explosive

Energy Technology Data Exchange (ETDEWEB)

Shimizu, Susumu

1988-02-28

It has been investigated how to charge a water hole with an inexpensive explosive for blasting. An experiment was made using the combination of a plasticized resin hose and the ANFO charger as the method for making the most of the ANFO explosive aiming at charging a hole with the explosive at a low cost without damaging the hole wall. The experimental result indicates that any water hole with spring water can be charged with the explosive using the ANFO charger combined with the plasticized resin hose. The method is superior to conventional methods in cost and workability because the working atmosphere is not aggravated and the hole wall is not damaged without using an expensive vacuum collector. Charging a blasting hole 165 mm or less in diameter with the explosive will be investigated for commercialization in future. (4 figs)

Thermal responses in underground experiments in a dome salt formation

International Nuclear Information System (INIS)

Llewellyn, G.H.

1977-01-01

To provide design information for a radwaste repository in dome salt, in-situ experiments with nonradioactive heat sources are planned. Three such experiments using electrical heat sources are scheduled to be carried out in a salt dome. The purpose of these experiments is to acquire rock mechanics data to ascertain the structural deformation due to the thermal load imposed, to study brine migration and corrosion, and to provide thermal data. A data acquisition system is provided with these experiments to monitor temperatues, heat fluxes, stresses, and ground displacement. A thermal analysis was made on models of each of these experiments. The objective of the analysis is to verify the capability of making accurate transient temperature predictions by the use of computer modeling techniques. Another purpose is to measure in-situ thermal conductivity and compare the results with measurements taken from core samples. The HEATING5 computer program was used to predict transient temperatures around the experiments for periods up to 2 years using two-dimensional and three-dimensional heat transfer models. The results of analysis are presented with the associated boundary conditions used in the individual models

Recent Advances in Understanding Large Scale Vapour Explosions

International Nuclear Information System (INIS)

Board, S.J.; Hall, R.W.

1976-01-01

In foundries, violent explosions occur occasionally when molten metal comes into contact with water. If similar explosions can occur with other materials, hazardous situations may arise for example in LNG marine transportation accidents, or in liquid cooled reactor incidents when molten UO 2 contacts water or sodium coolant. Over the last 10 years a large body of experimental data has been obtained on the behaviour of small quantities of hot material in contact with a vaporisable coolant. Such experiments generally give low energy yields, despite producing fine fragmentation of the molten material. These events have been interpreted in terms of a wide range of phenomena such as violent boiling, liquid entrainment, bubble collapse, superheat, surface cracking and many others. Many of these studies have been aimed at understanding the small scale behaviour of the particular materials of interest. However, understanding the nature of the energetic events which were the original cause for concern may also be necessary to give confidence that violent events cannot occur for these materials in large scale situations. More recently, there has been a trend towards larger experiments and some of these have produced explosions of moderately high efficiency. Although occurrence of such large scale explosions can depend rather critically on initial conditions in a way which is not fully understood, there are signs that the interpretation of these events may be more straightforward than that of the single drop experiments. In the last two years several theoretical models for large scale explosions have appeared which attempt a self contained explanation of at least some stages of such high yield events: these have as their common feature a description of how a propagating breakdown of an initially quasi-stable distribution of materials is induced by the pressure and flow field caused by the energy release in adjacent regions. These models have led to the idea that for a full

Thermal-Hydraulic Experiments and Modelling for Advanced Nuclear Reactor Systems

International Nuclear Information System (INIS)

Song, C. H.; Chung, M. K.; Park, C. K. and others

2005-04-01

The objectives of the project are to study thermal hydraulic characteristics of reactor primary system for the verification of the reactor safety and to evaluate new safety concepts of new safety design features. To meet the research goal, several thermal hydraulic experiments were performed and related thermal hydraulic models were developed with the experimental data which were produced through the thermal hydraulic experiments. Followings are main research topics; - Multi-dimensional Phenomena in a Reactor Vessel Downcomer - Condensation Load and Thermal Mixing in the IRWST - Development of Thermal-Hydraulic Models for Two-Phase Flow - Development of Measurement Techniques for Two-Phase Flow - Supercritical Reactor T/H Characteristics Analysis From the above experimental and analytical studies, new safety design features of the advanced power reactors were verified and lots of the safety issues were also resolved

Thermal-Hydraulic Experiments and Modelling for Advanced Nuclear Reactor Systems

Energy Technology Data Exchange (ETDEWEB)

Song, C. H.; Chung, M. K.; Park, C. K. and others

2005-04-15

The objectives of the project are to study thermal hydraulic characteristics of reactor primary system for the verification of the reactor safety and to evaluate new safety concepts of new safety design features. To meet the research goal, several thermal hydraulic experiments were performed and related thermal hydraulic models were developed with the experimental data which were produced through the thermal hydraulic experiments. Followings are main research topics; - Multi-dimensional Phenomena in a Reactor Vessel Downcomer - Condensation Load and Thermal Mixing in the IRWST - Development of Thermal-Hydraulic Models for Two-Phase Flow - Development of Measurement Techniques for Two-Phase Flow - Supercritical Reactor T/H Characteristics Analysis From the above experimental and analytical studies, new safety design features of the advanced power reactors were verified and lots of the safety issues were also resolved.

Raman hyperspectral imaging in conjunction with independent component analysis as a forensic tool for explosive analysis: The case of an ATM explosion.

Science.gov (United States)

Almeida, Mariana Ramos; Logrado, Lucio Paulo Lima; Zacca, Jorge Jardim; Correa, Deleon Nascimento; Poppi, Ronei Jesus

2017-11-01

In this work, Raman hyperspectral imaging, in conjunction with independent component analysis, was employed as an analytical methodology to detect an ammonium nitrate fuel oil (ANFO) explosive in banknotes after an ATM explosion experiment. The proposed methodology allows for the identification of the ANFO explosive without sample preparation or destroying the sample, at quantities as small as 70μgcm -2 . The explosive was identified following ICA data decomposition by the characteristic nitrate band at 1044cm -1 . The use of Raman hyperspectral imaging and independent component analysis shows great potential for identifying forensic samples by providing chemical and spatial information. Copyright © 2017 Elsevier B.V. All rights reserved.

Nondestructive test for assembly relationship of initiating explosive device

International Nuclear Information System (INIS)

Wang Xiangang; Zhang Chaozong; Guo Zhiping

2009-01-01

A 3D computed tomography (CT) method to inspect assembly relationship of initiating explosive device and to nondestructively evaluate assembly relationship by building geometric model from CT images was described. The experiment result proves that this method accurately inspects assembly relationship of initiating explosive device. (authors)

Gas explosions and thermal runaways during external heating abuse of commercial lithium-ion graphite-LiCoO2 cells at different levels of ageing

Science.gov (United States)

Larsson, Fredrik; Bertilsson, Simon; Furlani, Maurizio; Albinsson, Ingvar; Mellander, Bengt-Erik

2018-01-01

Commercial 6.8 Ah lithium-ion cells with different ageing/status have been abused by external heating in an oven. Prior to the abuse test, selected cells were aged either by C/2 cycling up to 300 cycles or stored at 60 °C. Gas emissions were measured by FTIR and three separate vents were identified, two well before the thermal runaway while the third occurred simultaneously with the thermal runaway releasing heavy smoke and gas. Emissions of toxic carbon monoxide (CO), hydrogen fluoride (HF) and phosphorous oxyfluoride (POF3) were detected in the third vent, regardless if there was a fire or not. All abused cells went into thermal runaway and emitted smoke and gas, the working cells also released flames as well as sparks. The dead cells were however less reactive but still underwent thermal runaway. For about half of the working cells, for all levels of cycle ageing, ignition of the accumulated battery released gases occurred about 15 s after the thermal runaway resulting in a gas explosion. The thermal runaway temperature, about 190 °C, varied somewhat for the different cell ageing/status where a weak local minimum was found for cells cycled between 100 and 200 times.

Chemical and physical modification of hemp fibres by steam explosion technology

International Nuclear Information System (INIS)

Sutka, Anna; Kukle, Silvija; Gravitis, Janis; Berzins, Agris

2013-01-01

In current research attempt has been made to analyse hemp fibres treated with steam explosion (SE) technology. Disintegration of hemp fibres separated from non-retted, dew-retted and dried stems of hemp ('Purini')[1] by alkali treatment and steam explosion (SE) were investigated. An average intensive SE in combination with the hydro-thermal and alkali after-treatment allows decreasing the diameter of hemp fibres and reduce the concentration of non-celluloses components, among them hemicelluloses, lignin, pectin, waxes and water [1;2

The Air Blast Wave from a Nuclear Explosion

Science.gov (United States)

Reines, Frederick

The sudden, large scale release of energy in the explosion of a nuclear bomb in air gives rise, in addition to nuclear emanations such as neutrons and gamma rays, to an extremely hot, rapidly expanding mass of air.** The rapidly expanding air mass has an initial temperature in the vicinity of a few hundred thousand degrees and for this reason it glows in its early stages with an intensity of many suns. It is important that the energy density in this initial "ball of fire" is of the order of 3 × 103 times that found in a detonating piece of TNT and hence that the initial stages of the large scale air motion produced by a nuclear explosion has no counterpart in an ordinary. H. E. explosion. Further, the relatively low temperatures ˜2,000°C associated with the initial stages of an H. E. detonation implies that the thermal radiation which it emits is a relatively insignificant fraction of the total energy involves. This point is made more striking when it is remembered that the thermal energy emitted by a hot object varies directly with the temperature in the Rayleigh Jeans region appropriate to the present discussion. The expansion of the air mass heated by the nuclear reaction produces, in qualitatively the same manner as in an H.E. explosion or the bursting of a high pressure balloon, an intense sharp pressure pulse, a shock wave, in the atmosphere. As the pressure pulse spreads outward it weakens due to the combined effects of divergence and the thermodynamically irreversible nature of the shock wave. The air comprising such a pressure pulse or blast wave moves first radially outward and then back towards the center as the blast wave passes. Since a permanent outward displacement of an infinite mass of air would require unlimited energy, the net outward displacement of the air distant from an explosion must approach zero with increasing distance. As the distance from the explosion is diminished the net outward displacement due to irreversible shock heating of

A review of steam explosions with special emphasis on the Swedish and Finnish BWRs. APRI 4, Phase 2 Report

Energy Technology Data Exchange (ETDEWEB)

Sehgal, B.R.; Haraldsson, H.O.; Yang, Z.L. [Sehgal Konsult, Stockholm (Sweden)

2002-04-01

The objective of the present study is to perform a critical review of ex-vessel steam explosion in Swedish and Finnish reactor containments in a hypothetical severe accident. The review performed is related to a broader program funded by APRI whose focus is related to severe accidents. A critical review of the current knowledge base on the subject is performed, including those results obtained from other studies and assessments conducted earlier under auspice of APRI. Several limiting mechanisms which may significantly impact the assessment of steam explosion loads are identified, taking into account specific reactor-design features and accident progression scenarios. In addition, generic discussion is provided on the effect of melt physical properties on the steam explosion energetics. Thermal hydraulic conditions of pre-mixture and its explosivity are evaluated using models and methods developed by the researchers at Royal Institute of Technology (RIT). The report includes a wealth of information on details with respect to quantification of vessel melt sources for ex-vessel FCIs; and with respect to the models of steam explosion premixing, triggerability and explosivity employed in the present assessment. These and other models e.g. on vessel failure, melt jet fragmentation etc. are products of the continuing research conducted at the Division of Nuclear Power Safety at RIT. The general conclusion of the present study can be summarized as: Though substantial progress have been made in premixing research verifying the mixing limit concept, there is still a need to improve jet breakup models and validate the existing models against melt jet experiments. The understanding of the triggering mechanisms is still very pool. Though various analytical models have been developed based on the thermal detonation concepts, the need still exists in both experimental and analytical research to understand better the droplet fragmentation during the explosion or propagation phase

A review of steam explosions with special emphasis on the Swedish and Finnish BWRs. APRI 4, Phase 2 Report

International Nuclear Information System (INIS)

Sehgal, B.R.; Haraldsson, H.O.; Yang, Z.L.

2002-04-01

The objective of the present study is to perform a critical review of ex-vessel steam explosion in Swedish and Finnish reactor containments in a hypothetical severe accident. The review performed is related to a broader program funded by APRI whose focus is related to severe accidents. A critical review of the current knowledge base on the subject is performed, including those results obtained from other studies and assessments conducted earlier under auspice of APRI. Several limiting mechanisms which may significantly impact the assessment of steam explosion loads are identified, taking into account specific reactor-design features and accident progression scenarios. In addition, generic discussion is provided on the effect of melt physical properties on the steam explosion energetics. Thermal hydraulic conditions of pre-mixture and its explosivity are evaluated using models and methods developed by the researchers at Royal Institute of Technology (RIT). The report includes a wealth of information on details with respect to quantification of vessel melt sources for ex-vessel FCIs; and with respect to the models of steam explosion premixing, triggerability and explosivity employed in the present assessment. These and other models e.g. on vessel failure, melt jet fragmentation etc. are products of the continuing research conducted at the Division of Nuclear Power Safety at RIT. The general conclusion of the present study can be summarized as: Though substantial progress have been made in premixing research verifying the mixing limit concept, there is still a need to improve jet breakup models and validate the existing models against melt jet experiments. The understanding of the triggering mechanisms is still very pool. Though various analytical models have been developed based on the thermal detonation concepts, the need still exists in both experimental and analytical research to understand better the droplet fragmentation during the explosion or propagation phase

Experiment on thermal insulation and sodium deposition of shield plug

International Nuclear Information System (INIS)

Hashiguchi, K.; Honda, M.; Shiratori, H.; Ozaki, O.; Suzuki, M.

1986-01-01

A series of experiments on temperature distribution and thermal insulation characteristics was conducted using a reduced scale model of LMFBR shield plug. Observation and measurement of sodium deposition were also conducted on the model after the experiment. The effect of annulus natural convection was clarified for temperature and the thermal insulation characteristics from evaluating the result. Temperature distribution analysis was conducted successfully by combining the general purpose structural analysis program NASTRAN and vertical annulus natural convection analysis program VANAC. Moreover, significant effect was substantiated for the annulus convection barrier to increase the thermal insulation performance, narrow horizontal gap structure to prevent sodium deposition and thermal insulation plates. (author)

Vapor explosion studies for nuclear and non-nuclear industries

Energy Technology Data Exchange (ETDEWEB)

Taleyarkhan, Rusi P. [Arden L. Bement, Jr. Professor Nuclear Engineering, School of Nuclear Engineering, 1290 Nuclear Engineering Building, Room 108C, Purdue University, West Lafayette, IN 47905 (United States)]. E-mail: rusi@purdue.edu

2005-05-01

Energetic melt-water explosions are a well-established contributor to risk for nuclear reactors, and even more so for the metal casting industry. In-depth studies were undertaken in an industry-national laboratory collaborative effort to understand the root causes of explosion triggering and to evaluate methods for prevention. The steam explosion triggering studies (SETS) facility was devised and implemented for deriving key insights into explosion prevention. Data obtained indicated that onset of base surface-entrapment induced explosive boiling-caused trigger shocks is a result of complex combination of surface wettability, type of coating (organic versus inorganic), degree of coating wearoff, existence of bypass pathways for pressure relief, charring and non-condensable gas (NCG) release potential. Of these parameters NCGs were found to play a preeminent role on explosion prevention by stabilizing the melt-water steam interface and acting as a shock absorber. The role of NCGs was experimentally confirmed using SETS for their effect on stable film boiling using a downward facing heated body through which gases were injected. The presence of NCGs in the steam film layer caused a significant delay in the transitioning of film-to-nucleate boiling. The role of NCGs on explosion prevention was thereafter demonstrated more directly by introducing molten metal drops into water pools with and without NCG bubbling. Whereas spontaneous and energetic explosions took place without NCG injection, only benign quenching occurred in the presence of NCGs. Gravimetric analyses of organic coatings which are known to prevent explosion onset were also found to release significant NCGs during thermal attack by melt in the presence of water. These findings offer a novel, simple, cost-effective technique for deriving fundamental insights into melt-water explosions as well as for explosion prevention under most conditions of interest to metal casting, and possibly for nuclear reactor

Experiments on interactions between zirconium-containing melt and water (ZREX). Hydrogen generation and chemical augmentation of energetics

Energy Technology Data Exchange (ETDEWEB)

Cho, D.H.; Armstrong, D.R.; Gunther, W.H. [Argonne National Lab., IL (United States); Basu, S.

1998-01-01

The results of the first data series of experiments on interactions between zirconium-containing melt and water are described. These experiments involved dropping 1-kg batches of pure zirconium or zirconium-zirconium dioxide mixture melt into a column of water. A total of nine tests were conducted, including four with pure zirconium melt and five with Zr-ZrO{sub 2} mixture melt. Explosions took place only in those tests which were externally triggered. While the extent of zirconium oxidation in the triggered experiments was quite extensive, the estimated explosion energetics were found to be very small compared to the combined thermal and chemical energy available. (author)

Liquid-liquid contact in vapor explosion

International Nuclear Information System (INIS)

Segev, A.

1978-08-01

The contact of two liquid materials, one of which is at a temperature substantially above the boiling point of the other, can lead to fast energy conversion and a subsequent shock wave. This phenomenon is called a vapor explosion. One method of producing intimate, liquid-liquid contact (which is known to be a necessary condition for vapor explosion) is a shock tube configuration. Such experiments in which water was impacted upon molten aluminum showed that very high pressures, even larger than the thermodynamic critical pressure, could occur. The mechanism by which such sharp pressure pulses are generated is not yet clear. The report describes experiments in which cold liquids (Freon-11, Freon-22, water, or butanol) were impacted upon various hot materials

Self-ignition of explosive substance. Comparison between analytical and numerical calculations in order to optimize safety in a pyrotechnic context; Auto-inflammation de substances explosives. Comparaison entre calcul analytique et numerique en vue d`une optimisation dans le domaine de la pyrotechnie

Energy Technology Data Exchange (ETDEWEB)

Gillard, Ph. [Centre National de la Recherche Scientifique (CNRS), 86 - Poitiers (France)

1998-04-01

Self-ignition of energetic material was investigated in order to optimize safety in the field of pyrotechnic applications. Two approaches were used; the first one is relative to Frank-Kamenetskii stationary thermal explosion theory. The second approach consists of a choice of some numerical solutions of heat conduction equations in a non-stationary state. Comparison between these results was carried out in order to find the numerical scheme which is the most compatible with Frank-Kamenetskii stationary thermal explosion theory. Numerical data were used for three explosive substances. One of them was studied by the author. In all cases, the numerical stationary state is in agreement with the Frank-Kamenetskii stationary thermal explosion theory, more or less accurately. From this comparison, it may be concluded that it is preferable, for this kind of problem, to use an implicit scheme with linearization of the heat source term. Explicit numerical methods, with or without the addition of the heat term with the Zinn and Mader scheme are revealed to be less accurate and to need a greater optimization of spatial and temporal meshing. (author) 7 refs.

Correlations between the disintegration of melt and the measured impulses in steam explosions

Energy Technology Data Exchange (ETDEWEB)

Froehlich, G.; Linca, A.; Schindler, M. [Univ. of Stuttgart (Germany)

1995-09-01

To find our correlations in steam explosions (melt water interactions) between the measured impulses and the disintegration of the melt, experiments were performed in three configurations i.e. stratified, entrapment and jet experiments. Linear correlations were detected between the impulse and the total surface of the fragments. Theoretical considerations point out that a linear correlation assumes superheating of a water layer around the fragments of a constant thickness during the fragmentation process to a constant temperature (here the homogeneous nucleation temperature of water was assumed) and a constant expansion velocity of the steam in the main expansion time. The correlation constant does not depend on melt temperature and trigger pressure, but it depends on the configuration of the experiment or of a scenario of an accident. Further research is required concerning the correlation constant. For analysing steam explosion accidents the explosivity is introduced. The explosivity is a mass specific impulse. The explosivity is linear correlated with the degree of fragmentation. Knowing the degree of fragmentation with proper correlation constant the explosivity can be calculated and from the explosivity combined with the total mass of fragments the impulse is obtained which can be used to an estimation of the maximum force.

Gas explosion in domestic buildings. The vented gas explosion[sub][/sub

Directory of Open Access Journals (Sweden)

Tadeusz Chyży

2014-08-01

Full Text Available In this paper, the basic information, related to the so-called vented gas explosion, has been presented. The vented explosion it is an explosion, during which the destruction of the weakest elements of the structure occurs. Through the resulting holes (decompressing surfaces can flow both combustion products and non-burned gas mixture. In consequence, reduction of the maximum explosion pressure[i] P[sub]red [/sub][/i] may be significant. Often, a gas explosion occurs inside residential buildings. In this case, natural vents are window and door openings.[b]Keywords[/b]: gas, explosion, combustion, explosion vents

Simulation of steam explosion in stratified melt-coolant configuration

International Nuclear Information System (INIS)

Leskovar, Matjaž; Centrih, Vasilij; Uršič, Mitja

2016-01-01

Highlights: • Strong steam explosions may develop spontaneously in stratified configurations. • Considerable melt-coolant premixed layer formed in subcooled water with hot melts. • Analysis with MC3D code provided insight into stratified steam explosion phenomenon. • Up to 25% of poured melt was mixed with water and available for steam explosion. • Better instrumented experiments needed to determine dominant mixing process. - Abstract: A steam explosion is an energetic fuel coolant interaction process, which may occur during a severe reactor accident when the molten core comes into contact with the coolant water. In nuclear reactor safety analyses steam explosions are primarily considered in melt jet-coolant pool configurations where sufficiently deep coolant pool conditions provide complete jet breakup and efficient premixture formation. Stratified melt-coolant configurations, i.e. a molten melt layer below a coolant layer, were up to now believed as being unable to generate strong explosive interactions. Based on the hypothesis that there are no interfacial instabilities in a stratified configuration it was assumed that the amount of melt in the premixture is insufficient to produce strong explosions. However, the recently performed experiments in the PULiMS and SES (KTH, Sweden) facilities with oxidic corium simulants revealed that strong steam explosions may develop spontaneously also in stratified melt-coolant configurations, where with high temperature melts and subcooled water conditions a considerable melt-coolant premixed layer is formed. In the article, the performed study of steam explosions in a stratified melt-coolant configuration in PULiMS like conditions is presented. The goal of this analytical work is to supplement the experimental activities within the PULiMS research program by addressing the key questions, especially regarding the explosivity of the formed premixed layer and the mechanisms responsible for the melt-water mixing. To

Droplet solidification and the potential for steam explosions

International Nuclear Information System (INIS)

Epstein, M.; Fauske, H.K.; Luangdilok, W.

2009-01-01

It is well known that under certain circumstances a mixture of coarse-hot (molten) drops in water formed from pouring a hot melt into water explodes. This so-called 'steam explosion' is generally believed to involve steam-bubble-collapse-induced fine fragmentation of the melt drops and concomitant water vaporization on a timescale that is short compared with the steam pressure relief time. Motivated by the idea put forth by Okkonen and Sehgal that rapid solidification would render UO 2 -containing (Corium) melt drops stiff and resistant to the steam-bubble-collapse-induced fragmentation required to support an explosion, here we combine solidification theory with an available theory of the stability of thin, submerged crusts subject to acceleration to predict the 'cutoff time' beyond which melt-drop fragmentation is suppressed by crust cover rigidity. Illustration calculations show that the cutoff time for Corium melt drops in water is a fraction of a second and probably shorter than the time it takes to form the explosion-prerequisite-coarse-premixture configuration of melt drops in water, while the opposite is true for the molten aluminum oxide/water system for which the window of opportunity for an explosion is predicted to be several seconds. These theoretical findings are consistent with early experiments that revealed molten uranium oxide or Corium pours into water to be non-explosive and that produced steam explosions upon pouring molten aluminum oxide into water. Also in this paper, the recent TROI Corium/water interaction experiments are examined and it is concluded that they do not contravene the earlier experimental observations that the pouring of prototypical Corium mixtures into water does not result in steam explosions with destructive potential. (author)

Surface and body waves from surface and underground explosions

International Nuclear Information System (INIS)

Kusubov, A.S.

1976-06-01

The characteristics of surface and ground waves were recorded for surface and underground explosions up to 100 tons and 40 kt in magnitude, respectively, and a preliminary analysis of these results is presented. The experiments were conducted at NTS in the Yucca Flats, Nevada. Ground motions were detected with triaxial geophones along seismic lines extending up to 16 miles from the point of explosions. A comparison of Rayleigh waves generated by surface and underground explosions in the same lake bed is presented indicating a very different behavior of surface and ground waves from the two types of explosions. The magnitude of the transverse wave for surface shots was smaller by a factor of two than its longitudinal counterpart. The dependence of apparent periods on the blast energy was not apparent at a fixed distance from the explosions. Changes in the apparent period with distance for both types of explosion are compared indicating a strong layering effect of the lake bed. The ground motion study was complimented by excavation of cavities generated by the explosions

Coulomb explosion of “hot spot”

Energy Technology Data Exchange (ETDEWEB)

Oreshkin, V. I., E-mail: oreshkin@ovpe.hcei.tsc.ru [Institute of High Current Electrons, SB, RAS, Tomsk (Russian Federation); Tomsk Polytechnic University, Tomsk (Russian Federation); Oreshkin, E. V. [P. N. Lebedev Physical Institute, RAS, Moscow (Russian Federation); Chaikovsky, S. A. [Institute of High Current Electrons, SB, RAS, Tomsk (Russian Federation); P. N. Lebedev Physical Institute, RAS, Moscow (Russian Federation); Institute of Electrophysics, UD, RAS, Ekaterinburg (Russian Federation); Artyomov, A. P. [Institute of High Current Electrons, SB, RAS, Tomsk (Russian Federation)

2016-09-15

The study presented in this paper has shown that the generation of hard x rays and high-energy ions, which are detected in pinch implosion experiments, may be associated with the Coulomb explosion of the hot spot that is formed due to the outflow of the material from the pinch cross point. During the process of material outflow, the temperature of the hot spot plasma increases, and conditions arise for the plasma electrons to become continuously accelerated. The runaway of electrons from the hot spot region results in the buildup of positive space charge in this region followed by a Coulomb explosion. The conditions for the hot spot plasma electrons to become continuously accelerated have been revealed, and the estimates have been obtained for the kinetic energy of the ions generated by the Coulomb explosion.

Coulomb explosion of “hot spot”

International Nuclear Information System (INIS)

Oreshkin, V. I.; Oreshkin, E. V.; Chaikovsky, S. A.; Artyomov, A. P.

2016-01-01

The study presented in this paper has shown that the generation of hard x rays and high-energy ions, which are detected in pinch implosion experiments, may be associated with the Coulomb explosion of the hot spot that is formed due to the outflow of the material from the pinch cross point. During the process of material outflow, the temperature of the hot spot plasma increases, and conditions arise for the plasma electrons to become continuously accelerated. The runaway of electrons from the hot spot region results in the buildup of positive space charge in this region followed by a Coulomb explosion. The conditions for the hot spot plasma electrons to become continuously accelerated have been revealed, and the estimates have been obtained for the kinetic energy of the ions generated by the Coulomb explosion.

Simulation of the chemical environment of a nuclear explosion with exploding wires

Energy Technology Data Exchange (ETDEWEB)

Meyer, Walter; Block, Oliver U.J. [Nuclear Engineering, Kansas State University, Manhattan, KS (United States)

1970-05-15

The chemical processes in an expanding underground cavity resulting from a nuclear explosion cannot be predicted or controlled as well as such physical characteristics as crater size, magnitude of the outgoing shock wave, or the extent of rock fracturing. However in most underground nuclear explosions it would be desirable to control the chemical and/or physical form and amount of radioactive fallout venting from the explosion. The high temperatures and corresponding high energy densities produced by exploding wires are sufficient to produce in the wire and material immediately surrounding it the temperature (a few thousand degrees) required to simulate the chemical environment of a nuclear explosion in the time interval just preceding the venting of the cavity. The economics and the size of exploding wire apparatus make this type of experiment readily applicable to laboratory study. Design of exploding wire circuits to obtain particular temperatures or energy densities can be completed using several different combinations of circuit and wire conditions. Since the circuit parameters, including charging voltage, capacitor bank capacitance and circuit inductance primarily determine the cost of the necessary laboratory equipment, these parameters should be selected by theoretical expressions while also considering economic factors. Wire parameters are then experimentally determined to produce the most energetic explosions with the selected circuit parameters. A theoretical method applicable to designing exploding wire circuits to produce the desired high temperatures and energy densities in the wire and surrounding sample material has been obtained. The method assumes that a thermal spike of energy is deposited in a low conductivity material (typical of the earth's crust) surrounding the wire. From the assumed temperature distribution in the surrounding sample material the energy which must be deposited in the thermal spike to produce the desired temperature and

A TNA explosives-detection system in airline baggage

Energy Technology Data Exchange (ETDEWEB)

Shea, P.; Gozani, T. (Science Applications International Corp., Santa Clara, CA (USA)); Bozorgmanesh, H. (Science Applications International Corp., San Diego, CA (USA))

1990-12-20

Existing technologies that are applied to explosives-detection in passenger baggage are briefly discussed. A system based on thermal-neutron analysis (TNA) is described. The actual performance of the system in the field on passenger bags is given. The application of the TNA in an integrated airport security system is discussed in view of the intense public debate on this issue. (orig.).

Effect of degree of subcooling on vapor explosion

International Nuclear Information System (INIS)

Xu Zhihong; Yang Yanhua; Li Tianshu

2010-01-01

In order to investigate the mechanism of the vapor explosion, an observable experiment equipment for low-temperature molten materials to be dropped into water was designed. In the experiment, molten material jet was injected into water to experimentally obtain the visualized information. This experiment results show that the degree of subcooling restrains the explosion. In order to validate the result by other aspects, the breakup experiment was conducted. Results show that the degree of water subcooling is important to melt breakup. High temperature of water is easy to increase the vapor generation during molten material falling, which decrease the drag and accelerated the molten material falling. At the same time, more vapor appear around the molten metal decrease the heat transfer amount between water and molten materials. The two experimental results coincide. (authors)

Sensitivity of numerical dispersion modeling to explosive source parameters

International Nuclear Information System (INIS)

Baskett, R.L.; Cederwall, R.T.

1991-01-01

The calculation of downwind concentrations from non-traditional sources, such as explosions, provides unique challenges to dispersion models. The US Department of Energy has assigned the Atmospheric Release Advisory Capability (ARAC) at the Lawrence Livermore National Laboratory (LLNL) the task of estimating the impact of accidental radiological releases to the atmosphere anywhere in the world. Our experience includes responses to over 25 incidents in the past 16 years, and about 150 exercises a year. Examples of responses to explosive accidents include the 1980 Titan 2 missile fuel explosion near Damascus, Arkansas and the hydrogen gas explosion in the 1986 Chernobyl nuclear power plant accident. Based on judgment and experience, we frequently estimate the source geometry and the amount of toxic material aerosolized as well as its particle size distribution. To expedite our real-time response, we developed some automated algorithms and default assumptions about several potential sources. It is useful to know how well these algorithms perform against real-world measurements and how sensitive our dispersion model is to the potential range of input values. In this paper we present the algorithms we use to simulate explosive events, compare these methods with limited field data measurements, and analyze their sensitivity to input parameters. 14 refs., 7 figs., 2 tabs

Use of artificial neural networks in drug and explosive detection through tomographic images with thermal neutrons

International Nuclear Information System (INIS)

Ferreira, Francisco J.O.; Crispim, Verginia R.; Silva, Ademir X.

2009-01-01

The artificial neural network technique was used to identify drugs and plastic explosives, from a tomography composed by a set of six neutrongraphic projections obtained in real time. Bidimensional tomographic images of samples of drugs, explosives and other materials, when digitally processed, yield the characteristic spectra of each type of material. The information contained in those spectra was then used for ANN training, the best images being obtained when the multilayer perceptron model, the back-propagation training algorithm and the Cross-validation interruption criterion were used. ANN showed to be useful in forecasting presence of drugs and explosives hitting a rate of success above 97 %. (author)

General phenomenology of underground nuclear explosions; Phenomenologie generale des explosions nucleaires souterraines

Energy Technology Data Exchange (ETDEWEB)

Derlich, S; Supiot, F [Commissariat a l' Energie Atomique, Bruyeres-le-Chatel (France). Centre d' Etudes

1969-07-01

An essentially qualitatively description is given of the phenomena related to underground nuclear explosions (explosion of a single unit, of several units in line, and simultaneous explosions). In the first chapter are described the phenomena which are common to contained explosions and to explosions forming craters (formation and propagation of a shock-wave causing the vaporization, the fusion and the fracturing of the medium). The second chapter describes the phenomena related to contained explosions (formation of a cavity with a chimney). The third chapter is devoted to the phenomenology of test explosions which form a crater; it describes in particular the mechanism of formation and the different types of craters as a function of the depth of the explosion and of the nature of the ground. The aerial phenomena connected with explosions which form a crater: shock wave in the air and focussing at a large distance, and dust clouds, are also dealt with. (authors) [French] On donne une description essentiellement qualitative des phenomenes lies aux explosions nucleaires souterraines (explosion d'un seul engin, d'engins en ligne et explosions simultanees). Dans un premier chapitre sont decrits les phenomenes communs aux explosions contenues et aux explosions formant un cratere (formation et propagation d'une onde de choc provoquant la vaporisation, la fusion et la fracturation du milieu). Le deuxieme chapitre decrit les phenomenes lies aux tirs contenus (formation d'une cavite et d'une cheminee). Le troisieme chapitre est consacre a la phenomenologie des tirs formant un cratere et decrit notamment le mecanisme de formation et les differents types de crateres en fonction de la profondeur d'explosion et de la nature du terrain. Les phenomenes aeriens lies aux explosions formant un cratere: onde de pression aerienne et focalisation a grande distance, nuages de poussieres, sont egalement abordes. (auteurs)

Time-Dependent Moment Tensors of the First Four Source Physics Experiments (SPE) Explosions

Science.gov (United States)

Yang, X.

2015-12-01

We use mainly vertical-component geophone data within 2 km from the epicenter to invert for time-dependent moment tensors of the first four SPE explosions: SPE-1, SPE-2, SPE-3 and SPE-4Prime. We employ a one-dimensional (1D) velocity model developed from P- and Rg-wave travel times for Green's function calculations. The attenuation structure of the model is developed from P- and Rg-wave amplitudes. We select data for the inversion based on the criterion that they show consistent travel times and amplitude behavior as those predicted by the 1D model. Due to limited azimuthal coverage of the sources and the mostly vertical-component-only nature of the dataset, only long-period, diagonal components of the moment tensors are well constrained. Nevertheless, the moment tensors, particularly their isotropic components, provide reasonable estimates of the long-period source amplitudes as well as estimates of corner frequencies, albeit with larger uncertainties. The estimated corner frequencies, however, are consistent with estimates from ratios of seismogram spectra from different explosions. These long-period source amplitudes and corner frequencies cannot be fit by classical P-wave explosion source models. The results motivate the development of new P-wave source models suitable for these chemical explosions. To that end, we fit inverted moment-tensor spectra by modifying the classical explosion model using regressions of estimated source parameters. Although the number of data points used in the regression is small, the approach suggests a way for the new-model development when more data are collected.

Thermal-Hydraulic Experiment Facility (THEF)

International Nuclear Information System (INIS)

Martinell, J.S.

1982-01-01

This paper provides an overview of the Thermal-Hydraulic Experiment Facility (THEF) at the Idaho National Engineering Laboratory (INEL). The overview describes the major test systems, measurements, and data acquisition system, and presents objectives, facility configuration, and results for major experimental projects recently conducted at the THEF. Plans for future projects are also discussed. The THEF is located in the Water Reactor Research Test Facility (WRRTF) area at the INEL

Experimental Studies of Thermal Interactions at AEE Winfrith

International Nuclear Information System (INIS)

Briggs, A.J.

1976-01-01

Assessment of the consequences of very severe reactor accidents in which fuel is melted involves evaluation of the nature of any thermal interaction between molten fuel or cladding and the reactor coolant. Work on these problems has been pursued in many countries, both experimentally and theoretically, but although much progress has been made there is as yet no well established theoretical description of large scale efficient thermal interactions. The need for further experimental data in this area was one of the main reasons for establishing a new range of experimental facilities at Winfrith which provide the ability to carry out experiments involving explosions under safe conditions. Experiments are set up inside a strong test cell situated in the centre of a 200 m exclusion area. Instrumentation is provided for transient measurements of pressure and strain, and for high speed cine photography. The first part of this programme started early in 1975, and is concerned with the propagation of thermal interaction through a metal/water system. This programme is not yet complete but some results of interest have been obtained. The first part of this paper will describe these experiments and discuss the significance of the results currently available. Such studies of large scale metal/water interactions should help to provide an improved understanding of the way in which propagation might occur in the reactor case, but must be complemented by experiments using reactor materials. The second stage of the Winfrith programme will study the UO 2 /Na system directly. Facilities for the production of pure uranium burning thermite charges will be commissioned early in 1976. This chemical technique for producing molten UO 2 will be used in two main types of experiment. Firstly the interaction of a two phase bubble of UO 2 with a surrounding pool of Na will be studied, extending the investigations of this kind started at AWRE Foulness. Secondly, the heat transfer rate from UO 2

Computer simulation of explosion crater in dams with different buried depths of explosive

Science.gov (United States)

Zhang, Zhichao; Ye, Longzhen

2018-04-01

Based on multi-material ALE method, this paper conducted a computer simulation on the explosion crater in dams with different buried depths of explosive using LS-DYNA program. The results turn out that the crater size increases with the increase of buried depth of explosive at first, but closed explosion cavity rather than a visible crater is formed when the buried depth of explosive increases to some extent. The soil in the explosion cavity is taken away by the explosion products and the soil under the explosion cavity is compressed with its density increased. The research can provide some reference for the anti-explosion design of dams in the future.

Electrically Driven Thermal Management: Flight Validation, Experiment Development, Future Technologies

Science.gov (United States)

Didion, Jeffrey R.

2018-01-01

Electrically Driven Thermal Management is an active research and technology development initiative incorporating ISS technology flight demonstrations (STP-H5), development of Microgravity Science Glovebox (MSG) flight experiment, and laboratory-based investigations of electrically based thermal management techniques. The program targets integrated thermal management for future generations of RF electronics and power electronic devices. This presentation reviews four program elements: i.) results from the Electrohydrodynamic (EHD) Long Term Flight Demonstration launched in February 2017 ii.) development of the Electrically Driven Liquid Film Boiling Experiment iii.) two University based research efforts iv.) development of Oscillating Heat Pipe evaluation at Goddard Space Flight Center.

A strategy for the application of steam explosion codes to reactor analysis

International Nuclear Information System (INIS)

Moriyama, Kiyofumi; Nakamura, Hideo

2006-01-01

A technical view on the strategy for the application of steam explosion codes for plant scale analysis is described. It includes assumption of triggering at the time of peak premixed melt mass, tuning of the explosion model on typical alumina steam explosion data, consideration of void and solidification effects as primary mechanism to limit the premixed mass and explosion energetics, choice of simple heat partition models affecting evaporation. The view was developed through experiences in development, verification and application of a steam explosion simulation code, JASMINE, at Japan Atomic Energy Agency (JAEA), as well as participation in OECD SERENA Phase-1 program. (author)

Study of the reactivity of an aggregative explosive sensitized by dynamical damage; Etude de la reactivite d`un explosif agregataire sensibilise par endommagement dynamique

Energy Technology Data Exchange (ETDEWEB)

Pertuis, Ch

1997-11-13

The thermal decomposition of a TATB-based explosive that have been exposed to a projectile impact, is studied in order to determine its sensitivity based on the morphological state of the damaged material. Two self-maintained thermal decomposition modes have been identified, one is a slow mode, the other is a rapid mode; four media have been differentiated in the damaged explosive: sound, porous, micro-cracked and fractured media, and thermal decomposition is studied for each media, using two experimental techniques, manometric bomb and a specifically designed strand burner. Laws giving the regression speed of each media has been established considering confinement pressure and initial temperature of the explosive. Analytical calculations yield the regression speed evolution as a function of certain parameters

THERMAL EVALUATION OF ALTERNATE SHIPPING CASK FOR GTRI EXPERIMENTS

Energy Technology Data Exchange (ETDEWEB)

Donna Post Guillen

2014-06-01

The Global Threat Reduction Initiative (GTRI) has many experiments yet to be irradiated in support of the High Performance Research Reactor fuels development program. Most of the experiments will be irradiated in the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL), then later shipped to the Hot Fuel Examination Facility (HFEF) located at the Materials and Fuels Complex for post irradiation examination. To date, the General Electric (GE)-2000 cask has been used to transport GTRI experiments between these facilities. However, the availability of the GE-2000 cask to support future GTRI experiments is at risk. In addition, the internal cavity of the GE-2000 cask is too short to accommodate shipping the larger GTRI experiments. Therefore, an alternate shipping capability is being pursued. The Battelle Energy Alliance, LLC, Research Reactor (BRR) cask has been determined to be the best alternative to the GE-2000 cask. An evaluation of the thermal performance of the BRR cask is necessary before proceeding with fabrication of the newly designed cask hardware and the development of handling, shipping, and transport procedures. This paper presents the results of the thermal evaluation of the BRR cask loaded with a representative set of fueled and non-fueled experiments. When analyzed with identical payloads, experiment temperatures were found to be lower with the BRR cask than with the GE-2000 cask. From a thermal standpoint, the BRR cask was found to be a suitable alternate to the GE-2000 cask.

Plasma Discharge Initiation of Explosives in Rock Blasting Application: A Case Study

International Nuclear Information System (INIS)

Chae, Jae-Ou; Jeong, Young-Jun; Shmelev, V M; Denicaev, A A; Poutchkov, V M; Ravi, V

2006-01-01

A plasma discharge initiation system for the explosive volumetric combustion charge was designed, investigated and developed for practical application. Laboratory scale experiments were carried out before conducting the large scale field tests. The resultant explosions gave rise to less noise, insignificant seismic vibrations and good specific explosive consumption for rock blasting. Importantly, the technique was found to be safe and environmentally friendly

Preliminary experiments using light-initiated high explosive for driving thin flyer plates

International Nuclear Information System (INIS)

Benham, R.A.

1980-02-01

Light-initiated high explosive, silver acelytide - silver-nitrate (SASN), has been used to produce simulated x ray blow-off impulse loading on reentry vehicles to study the system structural response. SASN can be used to accelerate thin flyer plates to high terminal velocities which, in turn, can deliver a pressure pulse that can be tailored to the target material. This process is important for impulse tests where both structural and material response is desired. The theories used to calculate the dynamic state of the flyer plate prior to impact are summarized. Data from several experiments are presented which indicate that thin flyer plates can be properly accelerated and that there are predictive techniques available which are adequate to calculate the motion of the flyer plate. Recommendations are made for future study that must be undertaken to make the SASN flyer plate technique usable

Effect of Ti and C particle sizes on reaction behavior of thermal explosion reaction of Cu−Ti−C system under Ar and air atmospheres

Energy Technology Data Exchange (ETDEWEB)

Liang, Yunhong; Zhao, Qian; Li, Xiujuan; Zhang, Zhihui, E-mail: zhzh@jlu.edu.cn; Ren, Luquan

2016-09-15

The thermal explosion (TE) reaction behavior of Cu−Ti−C systems with different Ti and C particle sizes was investigated under air and Ar atmospheres. It was found that increasing the Ti and C particle sizes leads to higher ignition temperatures under both atmospheres and that the maximum combustion temperature decreases with increasing C particle size. The TE reaction is much easier to activate (i.e., it has a lower ignition temperature) in air because of the heat released from Ti oxidation and nitridation and Cu oxidation reactions on the Cu−Ti−C compact surface. TiC ceramic particles are successfully prepared in the bulk Cu−Ti−C compacts under both air and Ar atmospheres through a dissolution-diffusion-precipitation mechanism. Differential thermal and thermodynamic analyses show that the TE reaction ignition process in air is mainly controlled by the Ti particle size. - Highlights: • Variation of Ti and C particle sizes affects thermal reaction (TE) behaviors. • Ignition temperature under air is much lower than that under Ar atmosphere. • Heat of oxidation and nitridation reactions reduces ignition temperature under air.

Features of the Valorization of Single and Double Based Powders for Codetonation in Emulsion Explosives

Science.gov (United States)

Ribeiro, Jose; Mendes, Ricardo; Tavares, Bruno; Louro, Cristina

2013-06-01

In this work, features of the thermal and detonation behavior of compositions resulting from the mixture of single and double based gun powder within ammonium nitrate (AN) based emulsion explosives are shown. That includes results of thermodynamic-equilibrium calculations of the detonation velocity, the chemical compatibility assessment through differential scanning calorimetry [DSC] and thermo gravimetric analysis [TGA], the experimental determination of the detonation velocity and a comparative evaluation of the shock sensitivity using a modified version of the ``gap-test''. DSC/TGA results for the compositions and for the individual components overlap until the beginning of the thermal decomposition which is an indication of the absence of formation of any new chemical specimens and so of the capability of the composition components. After the beginning of the thermal decomposition it can be seen that the rate of mass loss is much higher for the compositions with gun powder than for the sole emulsion explosive. Both, theoretical and experimental, values of the detonation velocity have shown to be higher for the powdered compositions than for the pure emulsion explosive. Shock sensitivity assessment have ended-up with a slightly bigger sensitivity for the compositions with double based gun powder when compared to the single based compositions or to the pure emulsion.

Preliminary analysis of K-DEMO thermal hydraulic system using MELCOR; Parametric study of hydrogen explosion

Energy Technology Data Exchange (ETDEWEB)

Moon, Sung Bo; Lim, Soo Min; Bang, In Cheol [UNIST, Ulsan (Korea, Republic of)

2016-10-15

K-DEMO (Korean fusion demonstration reactor) is future reactor for the commercializing the fusion power generation. The Design of K-DEMO is similar to that of ITER but the fusion energy generation is much bigger because ITER is experimental reactor. For this reason, K-DEMO uses more fusion reaction with bigger amount of tritium. Higher fusion power means more neutron generation that can irradiate the structure around fusion plasma. Fusion reactor can produce many kinds of radioactive material in the accident. Because of this hazard, preliminary safety analysis is mandatory before its construction. Concern for safety problem of accident of fusion/fission reactor has been growing after Fukushima accident which is severe accident from unexpected disaster. To model the primary heat transfer system, in this study, MARS-KS thermal hydraulic analysis is referred. Lee et al. and Kim et al. conducted thermal hydraulic analysis using MARS-KS and multiple module simulation to deal with the phenomena of first wall corrosion for each plasma pulse. This study shows the relationship between vacuum vessel rupture area and source term leakage after hydrogen explosion. For the conservative study, first wall heating is not terminated because the heating inside the vacuum vessel increase the pressure inside VV. Pressurizer, steam generator and turbine is not damaged. 6.69 kg of tritiated water (HTO) and 1 ton of dust is modeled which is ITER guideline. The entire system of K-DEMO is smaller than that of ITER. For this reason, lots of aerosol is release into environment although the safety system like DS is maintained. This result shows that the safety system of K-DEMO should use much more safety system.

Explosion bonding of dissimilar materials for fabricating APS front end components: Analysis of metallurgical and mechanical properties and UHV applications

International Nuclear Information System (INIS)

Li, Yuheng; Shu, Deming; Kuzay, T.M.

1994-01-01

The front end beamline section contains photon shutters and fixed masks. These components are made of OFHC copper and GlidCOP AL-15. Stainless steels (304 or 316) are also used for connecting photon shutters and fixed masks to other components that operate in the ultrahigh vacuum system. All these dissimilar materials need to be joined together. However, bonding these dissimilar materials is very difficult because of their different mechanical and thermal properties and incompatible metallurgical properties. Explosion bonding is a bonding method in which the controlled energy of a detonating explosive is used to create a metallurgical bond between two or more similar or dissimilar materials. No intermediate filler metal, for example, a brazing compound or soldering alloy, is needed to promote bonding, and no external heat need be applied. A study of the metallurgical and mechanical properties and YGV applications of GlidCop AL-15, OFHC copper, and 304 stainless steel explosion-bonded joints has been done. This report contains five parts: an ultrasonic examination of explosion-bonded joints and a standard setup; mechanical-property and thermal-cycle tests of GlidCop AL-15/304 stainless steel explosion-bonded joints; leak tests of a GlidCop AL-15/304 stainless steel explosion-bonded interfaces for UHV application; metallurgical examination of explosion-bonded interfaces and failure analysis, and discussion and conclusion

Understanding vented gas explosions

Energy Technology Data Exchange (ETDEWEB)

Lautkaski, R. [VTT Energy, Espoo (Finland). Energy Systems

1997-12-31

The report is an introduction to vented gas explosions for nonspecialists, particularly designers of plants for flammable gases and liquids. The phenomena leading to pressure generation in vented gas explosions in empty and congested rooms are reviewed. The four peak model of vented gas explosions is presented with simple methods to predict the values of the individual peaks. Experimental data on the external explosion of dust and gas explosions is discussed. The empirical equation relating the internal and external peak pressures in vented dust explosions is shown to be valid for gas explosion tests in 30 m{sup 3} and 550 m{sup 3} chambers. However, the difficulty of predicting the internal peak pressure in large chambers remains. Methods of explosion relief panel design and principles of vent and equipment layout to reduce explosion overpressures are reviewed. (orig.) 65 refs.

Understanding vented gas explosions

Energy Technology Data Exchange (ETDEWEB)

Lautkaski, R [VTT Energy, Espoo (Finland). Energy Systems

1998-12-31

The report is an introduction to vented gas explosions for nonspecialists, particularly designers of plants for flammable gases and liquids. The phenomena leading to pressure generation in vented gas explosions in empty and congested rooms are reviewed. The four peak model of vented gas explosions is presented with simple methods to predict the values of the individual peaks. Experimental data on the external explosion of dust and gas explosions is discussed. The empirical equation relating the internal and external peak pressures in vented dust explosions is shown to be valid for gas explosion tests in 30 m{sup 3} and 550 m{sup 3} chambers. However, the difficulty of predicting the internal peak pressure in large chambers remains. Methods of explosion relief panel design and principles of vent and equipment layout to reduce explosion overpressures are reviewed. (orig.) 65 refs.

Characterization Of High Explosives Detonations Via Laser-Induced Plasmas

Energy Technology Data Exchange (ETDEWEB)

Villa-Aleman, E. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2015-10-08

One objective of the Department of Energy’s National Security Administration is to develop technologies that can help the United States government to detect foreign nuclear weapons development activities. The realm of high explosive (HE) experiments is one of the key areas to assess the nuclear ambitions of a country. SRNL has participated in the collection of particulates from HE experiments and characterized the material with the purpose to correlate particulate matter with HE. Since these field campaigns are expensive, on-demand simulated laboratory-scale explosion experiments are needed to further our knowledge of the chemistry and particle formation in the process. Our goal is to develop an experimental test bed in the laboratory to test measurement concepts and correlate particle formation processes with the observables from the detonation fireball. The final objective is to use this knowledge to tailor our experimental setups in future field campaigns. The test bed uses pulsed laser-induced plasmas to simulate micro-explosions, with the intent to study the temporal behavior of the fireball observed in field tests. During FY15, a plan was prepared and executed which assembled two laser ablation systems, procured materials for study, and tested a Step-Scan Fourier Transform Infrared Spectrometer (SS-FTIR). Designs for a shadowgraph system for shock wave analysis, design for a micro-particulate collector from ablated pulse were accomplished. A novel spectroscopic system was conceived and a prototype system built for acquisition of spectral/temporal characterization of a high speed event such as from a high explosive detonation. Experiments and analyses will continue into FY16.

Explosive material treatment in particular the explosive compaction of powders

International Nuclear Information System (INIS)

Pruemmer, R.

1985-01-01

The constructive use of explosives in the last decades has led to new procedures in manufacturing techniques. The most important of these are explosive forming and cladding, the latter especially for the production of compound materials. The method of explosive compaction has the highest potential for further innovation. Almost theoretical densities are achievable in the green compacts as the pressure released by detonating explosives are very high. Also, the production of new conditions of materials (metastable high pressure phases) is possible. (orig.) [de

Approximating the r-process on earth with thermonuclear explosions

International Nuclear Information System (INIS)

Becker, S.A.

1992-01-01

The astrophysical r-process can be approximately simulated in certain types of thermonuclear explosions. Between 1952 and 1969 twenty-three nuclear tests were fielded by the United States which had as one of their objectives the production of heavy transuranic elements. Of these tests, fifteen were at least partially successful. Some of these shots were conducted under the project Plowshare Peaceful Nuclear Explosion Program as scientific research experiments. A review of the program, target nuclei used, and heavy element yields achieved, will be presented as well as discussion of plans for a new experiment in a future nuclear test

Understanding the shock and detonation response of high explosives at the continuum and meso scales

Science.gov (United States)

Handley, C. A.; Lambourn, B. D.; Whitworth, N. J.; James, H. R.; Belfield, W. J.

2018-03-01

The shock and detonation response of high explosives has been an active research topic for more than a century. In recent years, high quality data from experiments using embedded gauges and other diagnostic techniques have inspired the development of a range of new high-fidelity computer models for explosives. The experiments and models have led to new insights, both at the continuum scale applicable to most shock and detonation experiments, and at the mesoscale relevant to hotspots and burning within explosive microstructures. This article reviews the continuum and mesoscale models, and their application to explosive phenomena, gaining insights to aid future model development and improved understanding of the physics of shock initiation and detonation propagation. In particular, it is argued that "desensitization" and the effect of porosity on high explosives can both be explained by the combined effect of thermodynamics and hydrodynamics, rather than the traditional hotspot-based explanations linked to pressure-dependent reaction rates.

Investigation of the decomposition reaction and dust explosion characteristics of crystalline benzoyl peroxides

International Nuclear Information System (INIS)

Lu, K.-T.; Chen, T.-C.; Hu, K.-H.

2009-01-01

The benzoyl peroxide (BPO) is widely used in the chemical industry. Many catastrophes have been caused by its thermal instability or reactive incompatibility in storage or thermal decomposition reaction. Thus, its hazard characteristics have to be clearly identified. First of all, the differential scanning calorimeter (DSC) is used to measure the heat of decomposition reaction, which can contribute to understanding the reaction characteristics of benzoyl peroxide. The accelerating rate calorimeter (ARC) is used to measure the rates of temperature and pressure rises of decomposition reaction, and then the kinetics parameters are estimated. Furthermore, the MIKE 3 apparatus and the 20-l-Apparatus are used to measure and analyze the dust explosion characteristics of benzoyl peroxide under room temperature and atmospheric pressure. Finally, Semenov's thermal explosion theory is applied to investigate the critical runaway condition and the stability criterion of decomposition reaction, and to build the relationship of critical temperature, convective heat transfer coefficient, heat transfer surface area and ambient temperature. These results contribute to improving the safety in the reaction, transportation and storage processes of benzoyl peroxide

Simulation of changes in temperature and pressure fields during high speed projectiles forming by explosion

Directory of Open Access Journals (Sweden)

Marković Miloš D.

2016-01-01

Full Text Available The Research in this paper considered the temperatures fields as the consequently influenced effects appeared by plastic deformation, in the explosively forming process aimed to design Explosively Formed Projectiles (henceforth EFP. As the special payloads of the missiles, used projectiles are packaged as the metal liners, joined with explosive charges, to design explosive propulsion effect. Their final form and velocity during shaping depend on distributed temperatures in explosively driven plastic deformation process. Developed simulation model consider forming process without metal cover of explosive charge, in aim to discover liner’s dynamical correlations of effective plastic strains and temperatures in the unconstrained detonation environment made by payload construction. The temperature fields of the liner’s copper material are considered in time, as the consequence of strain/stress displacements driven by explosion environmental thermodynamically fields of pressures and temperatures. Achieved final velocities and mass loses as the expected EFP performances are estimated regarding their dynamical shaping and thermal gradients behavior vs. effective plastic strains. Performances and parameters are presented vs. process time, numerically simulated by the Autodyne software package. [Projekat Ministarstva nauke Republike Srbije, br. III-47029

Strong explosions impact on buildings representative of an industrial facility; Impact de fortes explosions sur les batiments representatifs d'une installation industrielle

Energy Technology Data Exchange (ETDEWEB)

Trelat, S

2006-12-15

The goal of this study is to focus on the analysis of blast wave damage to structures when blast wave is consequence of explosive charge detonation. The objective is to propose useful tools to predict charges on structure. All experiences are realized in laboratory. The experimental investigation consists in simulating a detonation of a stoichiometric propane-oxygen mixture at ground level or at higher altitude. The study is going to give us experimental data on blast wave effects on a structure. For that, two types of structures frequently found on industrial site are going to be used: a parallelepipedal structure and a cylindrical structure, both with known dimensions. Finally, the important point of the problem is to determine an energetic equivalence between TNT and gas used in the experiments, in order to model TNT explosions at full scale by gaseous explosions at reduced scale. (author)

A review of human thermal comfort experiments in controlled and semi-controlled environments

NARCIS (Netherlands)

Craenendonck, Van Stijn; Lauriks, Leen; Vuye, Cedric; Kampen, Jarl

2018-01-01

There are three main methods to improve thermal comfort in existing buildings: modeling, experiments and measurements. Regarding experiments, no standardized procedure exists. This article provides an answer to the question: “What is the most common practice for human thermal comfort experiments in

Thermal and orbital analysis of Earth monitoring Sun-synchronous space experiments

Science.gov (United States)

Killough, Brian D.

1990-01-01

The fundamentals of an Earth monitoring Sun-synchronous orbit are presented. A Sun-synchronous Orbit Analysis Program (SOAP) was developed to calculate orbital parameters for an entire year. The output from this program provides the required input data for the TRASYS thermal radiation computer code, which in turn computes the infrared, solar and Earth albedo heat fluxes incident on a space experiment. Direct incident heat fluxes can be used as input to a generalized thermal analyzer program to size radiators and predict instrument operating temperatures. The SOAP computer code and its application to the thermal analysis methodology presented, should prove useful to the thermal engineer during the design phases of Earth monitoring Sun-synchronous space experiments.

Apparatus and method for detecting explosives

International Nuclear Information System (INIS)

Griffith, B.

1976-01-01

An apparatus is described for use in situations such as airports to detect explosives hidden in containers (for eg. suitcases). The method involves the evaluation of the quantities of oxygen and nitrogen within the container by neutron activation analysis and the determination of whether these quantities exceed predetermined limits. The equipment includes a small sub-critical lower powered reactor for thermal (0.01 to 0.10 eV) neutron production, a radium beryllium primary source, a deuterium-tritium reactor as a high energy (> 1.06 MeV) neutron source and Geiger counter detector arrays. (UK)

Explosive coalescence of magnetic islands and explosive particle acceleration

International Nuclear Information System (INIS)

Tajima, T.; Sakai, J.I.

1985-07-01

An explosive reconnection process associated with the nonlinear evolution of the coalescence instability is found through studies of the electromagnetic particle simulation and the magnetohydrodynamic particle simulation. The explosive coalescence is a process of magnetic collapse, in which we find the magnetic and electrostatic field energies and temperatures (ion temperature in the coalescing direction, in particular) explode toward the explosion time t 0 as (t 0 - t)/sup -8/3/, (t 0 - t) -4 , and (t 0 - t)/sup -8/3/, respectively for a canonical case. Single-peak, double-peak, and triple-peak structures of magnetic energy, temperature, and electrostatic energy, respectively, are observed on the simulation as overshoot amplitude oscillations and are theoretically explained. The heuristic model of Brunel and Tajima is extended to this explosive coalescence in order to extract the basic process. Since the explosive coalescence exhibits self-similarity, a temporal universality, we theoretically search for a self-similar solution to the two-fluid plasma equations

75 FR 1085 - Commerce in Explosives; List of Explosive Materials (2009R-18T)

Science.gov (United States)

2010-01-08

... sensitive slurry and water gel explosives. Blasting caps. Blasting gelatin. Blasting powder. BTNEC [bis.... Explosive conitrates. Explosive gelatins. Explosive liquids. Explosive mixtures containing oxygen-releasing... powder. Fulminate of mercury. Fulminate of silver. Fulminating gold. Fulminating mercury. Fulminating...

75 FR 70291 - Commerce in Explosives; List of Explosive Materials (2010R-27T)

Science.gov (United States)

2010-11-17

..., including non-cap sensitive slurry and water gel explosives. Blasting caps. Blasting gelatin. Blasting.... Explosive conitrates. Explosive gelatins. Explosive liquids. Explosive mixtures containing oxygen-releasing... powder. Fulminate of mercury. Fulminate of silver. Fulminating gold. Fulminating mercury. Fulminating...

Modelling Venting and Pressure Build-up in a 18650 LCO Cell during Thermal Runaway (ABSTRACT)

DEFF Research Database (Denmark)

Coman, Paul Tiberiu; Veje, Christian; White, Ralph

Li-ion batteries are a very popular type of electric storage devices that possess high energy density when compared to the other battery chemistries. Due to this property, when operating under abusive conditions such as high ambient temperature, the batteries can experience thermal runaway, which...... may lead to fires and explosions. To prevent this, it is therefore important to model thermal runaway considering different events such as venting and the pressure development inside the battery cell, which makes the main purpose of this paper. A model consisting of the different decomposition....... By fitting the activation energies, and measuring experimentally the mass of the ejecta during thermal runaway, the model is compared and validated against an extensive experiment performed by Golukbov et al. [1] during oven heating. When analysing the results, it is found that by including the venting...

Experimental study of the thermal interaction for molten tin dropped into water

International Nuclear Information System (INIS)

Arakeri, V.H.; Catton, I.; Kastenberg, W.E.; Plesset, M.S.

1975-12-01

Multiflash photography with extremely short exposure duration times has been used to observe the interaction of molten tin dropped into a water bath. Detailed photographic evidence is presented which demonstrates that transition, or nucleate boiling, is a possible triggering mechanism for vapor explosions and fragmentation. It was also found that the thermal constraints required to produce vapor explosions could be relaxed by introducing a stable thermal stratification within the coolant. It is shown that the constraints can be relaxed sufficiently to cause vapor explosions for test conditions for which the calculated interface contact temperatures are lower than the homogeneous nucleation temperature of water. This latter finding shows that achievement of limiting coolant superheats associated with spontaneous nucleation is not the only mechanism by which vapor explosions in liquid-liquid systems are possible

Emplacement and stemming of nuclear explosives for Plowshare applications

Energy Technology Data Exchange (ETDEWEB)

Cramer, J L [Lawrence Radiation Laboratory, University of California, Livermore, CA (United States)

1970-05-15

This paper will discuss the various methods used for emplacement and design considerations that must be taken into account when the emplacement and stemming method is selected. The step-by-step field procedure will not be discussed in this paper. The task of emplacing and stemming the nuclear explosive is common to all Plowshare experiments today. All present-day applications of a nuclear explosive for Plowshare experiments require that the detonation take place some distance below the surface of the ground. This is normally done by lowering the explosive into an emplacement hole to a desired depth and then backfilling the hole with a suitable stemming material. At first glance it scenes like a very straightforward, simple task to perform. It would appear to be a task that could become a standard procedure for all experiments; however, this is not the case. In actuality, the emplacement and stemming of a nuclear explosive must almost be a custom design. It varies with the application of the experiment, i.e., cratering or underground engineering. It also varies with the condition of the hole, the available equipment to do the job, the actual purpose of the stemming, possible postshot reentry, hydrology, geology, and future production. A very important item that must always be considered is the protection of the firing and signal cables during the downhole and stemming operation. Each of these things must be considered; ignoring any one of them could jeopardize one of the objectives of the experiment or perhaps even the experiment itself. It should be emphasized that for a multiple-shot program such as would be used to develop a gas field where the geology, depths of burial etc. are the same, the emplacement and stemming operation would be standardized, as would all other parts of the program. However, for individual experiments in totally different areas, complete standardization of the emplacement and stemming is impossible.

Emplacement and stemming of nuclear explosives for Plowshare applications

International Nuclear Information System (INIS)

Cramer, J.L.

1970-01-01

This paper will discuss the various methods used for emplacement and design considerations that must be taken into account when the emplacement and stemming method is selected. The step-by-step field procedure will not be discussed in this paper. The task of emplacing and stemming the nuclear explosive is common to all Plowshare experiments today. All present-day applications of a nuclear explosive for Plowshare experiments require that the detonation take place some distance below the surface of the ground. This is normally done by lowering the explosive into an emplacement hole to a desired depth and then backfilling the hole with a suitable stemming material. At first glance it scenes like a very straightforward, simple task to perform. It would appear to be a task that could become a standard procedure for all experiments; however, this is not the case. In actuality, the emplacement and stemming of a nuclear explosive must almost be a custom design. It varies with the application of the experiment, i.e., cratering or underground engineering. It also varies with the condition of the hole, the available equipment to do the job, the actual purpose of the stemming, possible postshot reentry, hydrology, geology, and future production. A very important item that must always be considered is the protection of the firing and signal cables during the downhole and stemming operation. Each of these things must be considered; ignoring any one of them could jeopardize one of the objectives of the experiment or perhaps even the experiment itself. It should be emphasized that for a multiple-shot program such as would be used to develop a gas field where the geology, depths of burial etc. are the same, the emplacement and stemming operation would be standardized, as would all other parts of the program. However, for individual experiments in totally different areas, complete standardization of the emplacement and stemming is impossible

Environmental control for nuclear explosives

Energy Technology Data Exchange (ETDEWEB)

Lundberg, A W; Wells, W H [Lawrence Radiation Laboratory, University of California, Livermore, CA (United States)

1970-05-15

Peaceful applications introduce some new environmental considerations into the design of nuclear explosives. Much of the experience gained in weapon work can be applied, but the requirement of survival in a very deep hole is not found in any military system. We will briefly mention the overall environment and make a few comparisons with some general characteristics of the weapon environment. The major portion of this paper is devoted to the special problems of pressure and temperature found in the emplacement environment. Potential users should know where we stand with regard to survival in hostile environments in terms of feasibility and possible effects on field operations. In all applications there are several things competing for the available diameter. Given that explosives can be made to work over a range of diameters and that necessary environmental control is feasible, all further discussions can be related to the cost of providing a hole big enough to accomplish the task. The items competing for diameter are: 1) bare nuclear assembly 2) insulation and cooling system if needed 3) pressure canister 4) shielding material 5) emplacement clearance All of these must be considered with the cost of the hole in optimizing an overall design. Conditions in a particular location will affect the shielding requirements and the emplacement clearance. The nuclear assembly can vary in size, but the long development time requires that decisions be made quite early, perhaps in ignorance of the economic details of a particular application. The pressure canister is a relatively straightforward design problem that can be resolved by giving appropriate consideration to all of the design requirements. In particular for 20,000 psi pressure in the emplacement hole, a canister of heat-treated alloy steel having a yield strength of 200,000 psi and a wall thickness which is about .07 times the outside diameter is adequate and straight- forward to fabricate. The insulation and cooling

The present status of scientific applications of nuclear explosions

International Nuclear Information System (INIS)

Cowan, G.A.; Diven, B.C.

1970-01-01

This is the fourth in a series of symposia which started, in 1957 at Livermore with the purpose of examining the peaceful uses of nuclear explosives. Although principal emphasis has b een placed on technological applications, the discussions have, from the outset, included the fascinating question of scientific uses. Of the possible scientific applications which were mentioned at the 1957 meeting, the proposals which attracted most attention involved uses of nuclear explosions for research in seismology. It is interesting to note that since then a very large and stimulating body of data in the field of seismology has been collected from nuclear tests. Ideas for scientific applications of nuclear explosions go back considerably further than 1957. During the war days Otto Frisch at Los Alamos suggested that a fission bomb would provide an excellent source of fast neutrons which could be led down a vacuum pipe and used for experiments in a relatively unscattered state. This idea, reinvented, modified, and elaborated upon in the ensuing twenty-five years, provides the basis for much of the research discussed in this morning's program. In 1952 a somewhat different property of nuclear explosions, their ability to produce intense neutron exposures on internal targets and to synthesize large quantities of multiple neutron capture products, was dramatically brought to our attention by analysis of debris from the first large thermonuclear explosion (Mike) in which the elements einsteinium and fermiun were observed for the first time. The reports of the next two Plowshare symposia in 1959 and 1964 help record the fascinating development of the scientific uses of neutrons in nuclear explosions. Starting with two 'wheel' experiments in 1958 to measure symmetry of fission in 235-U resonances, the use of external beams of energy-resolved neutrons was expanded on the 'Gnome' experiment in 1961 to include the measurement of neutron capture excitation functions for 238-U, 232-Th

Liquid-liquid contact in vapor explosion. [LMFBR

Energy Technology Data Exchange (ETDEWEB)

Segev, A.

1978-08-01

The contact of two liquid materials, one of which is at a temperature substantially above the boiling point of the other, can lead to fast energy conversion and a subsequent shock wave. This phenomenon is called a vapor explosion. One method of producing intimate, liquid-liquid contact (which is known to be a necessary condition for vapor explosion) is a shock tube configuration. Such experiments in which water was impacted upon molten aluminum showed that very high pressures, even larger than the thermodynamic critical pressure, could occur. The mechanism by which such sharp pressure pulses are generated is not yet clear. The report describes experiments in which cold liquids (Freon-11, Freon-22, water, or butanol) were impacted upon various hot materials (mineral oil, silicone oil, water, mercury, molten Wood's metal or molten salt mixture).

Argonne Bubble Experiment Thermal Model Development III

Energy Technology Data Exchange (ETDEWEB)

Buechler, Cynthia Eileen [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

2018-01-11

This report describes the continuation of the work reported in “Argonne Bubble Experiment Thermal Model Development” and “Argonne Bubble Experiment Thermal Model Development II”. The experiment was performed at Argonne National Laboratory (ANL) in 2014. A rastered 35 MeV electron beam deposited power in a solution of uranyl sulfate, generating heat and radiolytic gas bubbles. Irradiations were performed at beam power levels between 6 and 15 kW. Solution temperatures were measured by thermocouples, and gas bubble behavior was recorded. The previous report2 described the Monte-Carlo N-Particle (MCNP) calculations and Computational Fluid Dynamics (CFD) analysis performed on the as-built solution vessel geometry. The CFD simulations in the current analysis were performed using Ansys Fluent, Ver. 17.2. The same power profiles determined from MCNP calculations in earlier work were used for the 12 and 15 kW simulations. The primary goal of the current work is to calculate the temperature profiles for the 12 and 15 kW cases using reasonable estimates for the gas generation rate, based on images of the bubbles recorded during the irradiations. Temperature profiles resulting from the CFD calculations are compared to experimental measurements.

The Off-Site Plowshare and Vela Uniform Programs: Assessing Potential Environmental Liabilities through an Examination of Proposed Nuclear Projects,High Explosive Experiments, and High Explosive Construction Activities Volume 1 of 3

Energy Technology Data Exchange (ETDEWEB)

Beck Colleen M,Edwards Susan R.,King Maureen L.

2011-09-01

This document presents the results of nearly six years (2002-2008) of historical research and field studies concerned with evaluating potential environmental liabilities associated with U.S. Atomic Energy Commission projects from the Plowshare and Vela Uniform Programs. The Plowshare Program's primary purpose was to develop peaceful uses for nuclear explosives. The Vela Uniform Program focused on improving the capability of detecting, monitoring and identifying underground nuclear detonations. As a result of the Project Chariot site restoration efforts in the early 1990s, there were concerns that there might be other project locations with potential environmental liabilities. The Desert Research Institute conducted archival research to identify projects, an analysis of project field activities, and completed field studies at locations where substantial fieldwork had been undertaken for the projects. Although the Plowshare and Vela Uniform nuclear projects are well known, the projects that are included in this research are relatively unknown. They are proposed nuclear projects that were not executed, proposed and executed high explosive experiments, and proposed and executed high explosive construction activities off the Nevada Test Site. The research identified 170 Plowshare and Vela Uniform off-site projects and many of these had little or no field activity associated with them. However, there were 27 projects that merited further investigation and field studies were conducted at 15 locations.

The Off-Site Plowshare and Vela Uniform Programs: Assessing Potential Environmental Liabilities through an Examination of Proposed Nuclear Projects,High Explosive Experiments, and High Explosive Construction Activities Volume 2 of 3

Energy Technology Data Exchange (ETDEWEB)

Beck Colleen M.,Edwards Susan R.,King Maureen L.

2011-09-01

This document presents the results of nearly six years (2002-2008) of historical research and field studies concerned with evaluating potential environmental liabilities associated with U.S. Atomic Energy Commission projects from the Plowshare and Vela Uniform Programs. The Plowshare Program's primary purpose was to develop peaceful uses for nuclear explosives. The Vela Uniform Program focused on improving the capability of detecting, monitoring and identifying underground nuclear detonations. As a result of the Project Chariot site restoration efforts in the early 1990s, there were concerns that there might be other project locations with potential environmental liabilities. The Desert Research Institute conducted archival research to identify projects, an analysis of project field activities, and completed field studies at locations where substantial fieldwork had been undertaken for the projects. Although the Plowshare and Vela Uniform nuclear projects are well known, the projects that are included in this research are relatively unknown. They are proposed nuclear projects that were not executed, proposed and executed high explosive experiments, and proposed and executed high explosive construction activities off the Nevada Test Site. The research identified 170 Plowshare and Vela Uniform off-site projects and many of these had little or no field activity associated with them. However, there were 27 projects that merited further investigation and field studies were conducted at 15 locations.

The Off-Site Plowshare and Vela Uniform Programs: Assessing Potential Environmental Liabilities through an Examination of Proposed Nuclear Projects,High Explosive Experiments, and High Explosive Construction Activities Volume 3 of 3

Energy Technology Data Exchange (ETDEWEB)

Beck Colleen M.,Edwards Susan R.,King Maureen L.

2011-09-01

This document presents the results of nearly six years (2002-2008) of historical research and field studies concerned with evaluating potential environmental liabilities associated with U.S. Atomic Energy Commission projects from the Plowshare and Vela Uniform Programs. The Plowshare Program's primary purpose was to develop peaceful uses for nuclear explosives. The Vela Uniform Program focused on improving the capability of detecting, monitoring and identifying underground nuclear detonations. As a result of the Project Chariot site restoration efforts in the early 1990s, there were concerns that there might be other project locations with potential environmental liabilities. The Desert Research Institute conducted archival research to identify projects, an analysis of project field activities, and completed field studies at locations where substantial fieldwork had been undertaken for the projects. Although the Plowshare and Vela Uniform nuclear projects are well known, the projects that are included in this research are relatively unknown. They are proposed nuclear projects that were not executed, proposed and executed high explosive experiments, and proposed and executed high explosive construction activities off the Nevada Test Site. The research identified 170 Plowshare and Vela Uniform off-site projects and many of these had little or no field activity associated with them. However, there were 27 projects that merited further investigation and field studies were conducted at 15 locations.

Properties and Behavior of Geopolymer Concrete Subjected to Explosive Air Blast Loading: A Review

Directory of Open Access Journals (Sweden)

Mohd Mortar Nurul Aida

2017-01-01

Full Text Available The severe damage to civilian buildings, public area, jet aircraft impact and defense target under explosive blast loading can cause a huge property loss. Most of researcher discusses the topics on design the concrete material model to sustain againts the explosive detonation. The implementation of modern reinforcement steels and fibres in ordinary Portland cement (OPC concrete matrix can reduce the extreme loading effects. However, most researchers have proved that geopolymer concrete (GPC has better mechanical properties towards high performance concrete, compared to OPC. GPC has the high early compressive strength and high ability to resist the thermal energy from explosive detonation. In addition, OPC production is less environmental friendly than geopolymer cement. Geopolymer used can lead to environmental protection besides being improved in mechanical properties. Thus, this paper highlighted on an experimental, numerical and the analytical studies cause of the explosive detonation impact to concrete structures.

Pressurized-thermal-shock experiments with thick vessels

International Nuclear Information System (INIS)

Bryan, R.H.; Nanstad, R.K.; Merkle, J.G.; Robinson, G.C.; Whitman, G.D.

1986-01-01

Information is provided on the series of pressurized-thermal-shock experiments at the Oak Ridge National Laboratory, motivated by a concern for the behavior of flaws in reactor pressure vessels having welds or shells exhibiting low upper-shelf Charpy impact energies, approx. 68J or less

A Literature Review of Shock Sensitivity Changes of TATB Due to Thermal Cycling

Energy Technology Data Exchange (ETDEWEB)

Ritter, Boyd [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); New Mexico Inst. of Mining and Technology, Socorro, NM (United States). Dept. of Mechanical Engineering

2016-07-15

Insensitive high explosives (IHEs) based on 1,3,5-triamino 2,4,6-trinitro-benzene (TATB) are the IHEs of choice for use in nuclear warheads over conventional high explosives when safety is the only consideration, because they are very insensitive to thermal or mechanical initiation stimuli. It is this inherent insensitivity to high temperatures, shock, and impact, which provides detonation design challenges when designing TATB explosive systems while at the same time providing a significant level of protection against accidental initiation. Although classified as IHE, over the past few years the focus on explosive safety has demonstrated that the shock sensitivity of TATB is influenced with respect to temperature. A number of studies have been performed on TATB and TATB formulations, plastic bonded explosives (PBX) 9502, and LX-17-01 (LX-17), which demonstrates the increase in shock sensitivity of the explosive after it has been preheated or thermally cycled over various temperature ranges. Many studies suggest the change in sensitivity is partly due to the decomposition rates of the temperature elevated TATB. Others point to the coefficient of thermal expansion, the crystalline structures of TATB and/or the combination of all factors, which create voids which can become active hot spots. During thermal cycling, TATB is known to undergo an irreversible increase in specific volume called ratchet growth. This increase in specific volume correlates to a decrease in density. This decrease in density and increase in volume, demonstrate the creations of additional void spaces which could serve as potential new initiation hot spots thus, increasing the overall sensitivity of the HE. This literature review evaluates the published works to understand why the shock sensitivity of TATB-based plastic bonded explosives (PBXs) changes with temperature.

Explosion hazard in liquid nitrogen cooled fusion systems

International Nuclear Information System (INIS)

Brereton, S.J.

1988-01-01

The explosion hazard associated with the use of liquid nitrogen in a radiation environment in fusion facilities has been investigated. The principal product of irradiating liquid nitrogen is thought to be ozone, resulting from the action of radiation on oxygen impurity. Ozone is a very unstable material, and explosions may occur as it rapidly decomposes to oxygen. Occurrences of this problem in irradiated liquid nitrogen systems are reviewed. An empirical expression, from early experiments, for the yield of ozone in liquid nitrogen-oxygen mixtures exposed to gamma radiation is employed to assess the degree of ozone explosion hazard expected at fusion facilities. The problem is investigated for the Compact Ignition Tokamak (CIT) as a particular example. 16 refs., 5 figs., 1 tab

Experimental Study of Structure/Behavior Relationship for a Metallized Explosive

Science.gov (United States)

Bukovsky, Eric; Reeves, Robert; Gash, Alexander; Glumac, Nick

2017-06-01

Metal powders are commonly added to explosive formulations to modify the blast behavior. Although detonation velocity is typically reduced compared to the neat explosive, the metal provides other benefits. Aluminum is a common additive to increase the overall energy output and high-density metals can be useful for enhancing momentum transfer to a target. Typically, metal powder is homogeneously distributed throughout the material; in this study, controlled distributions of metal powder in explosive formulations were investigated. The powder structures were printed using powder bed printing and the porous structures were filled with explosives to create bulk explosive composites. In all cases, the overall ratio between metal and explosive was maintained, but the powder distribution was varied. Samples utilizing uniform distributions to represent typical materials, discrete pockets of metal powder, and controlled, graded powder distributions were created. Detonation experiments were performed to evaluate the influence of metal powder design on the output pressure/time and the overall impulse. This work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344.

Quantum control for initiation and detection of explosives

International Nuclear Information System (INIS)

Greenfield, Margo T.; McGrane, Shawn D.; Scharff, R. Jason; Moore, David S.

2010-01-01

We employ quantum control methods towards detection and quantum controlled initiation (QCI) of energetic materials. Ultrafast pulse shaping of broadband Infrared (∼750 nm to 850 run) and ultraviolet (266 nm, 400 nm) light is utilized for control. The underlying principals behind optimal control can be utilized to both detect and initiate explosives. In each case, time dependent phase shaped electric fields drive the chemical systems towards a desired state. For optimal dynamic detection of explosives (ODD-Ex) a phase specific broadband infrared pulse is created which increases not only the sensitivity of detection but also the selectivity of an explosive's spectral signatures in a background of interferents. QCI on the other hand, seeks to initiate explosives by employing shaped ultraviolet light. QCI is ideal for use with explosive detonators as it removes the possibility of unintentional initiation from an electrical source while adding an additional safety feature, initiation only with the proper pulse shape. Quantum control experiments require: (1) the ability to phase and amplitude shape the laser pulse and (2) the ability to effectively search for the pulse shape which controls the reaction. In these adaptive experiments we utilize both global and local optimization search routines such as genetic algorithm, differential evolution, and downhill simplex. Pulse shaping the broadband IR light, produced by focusing 800 nm light through a pressurized tube of Argon, is straightforward as commercial pulse shapers are available at and around 800 nm. Pulse shaping in the UV requires a home built shaper. Our system is an acoustic optical modulator (AOM) pulse shaper in which consists of a fused silica AOM crystal placed in the Fourier plane of a 4-f zero dispersion compressor.

RX-08-HD, a low-viscosity, injection-moldable explosive for filling tortuous paths

Energy Technology Data Exchange (ETDEWEB)

Hoffman, D.M.; Jessop, E.S.; Swansiger, R.W.

1997-10-01

Cast cure, extrusion cast, and paste extrudable explosives have not been designed for transferring through long tortuous paths or into fine three dimensional shapes. To allow the crystalline explosive to flow a lubricating fluid is required. The energetic liquid ethane trinitrate (TMETN) was used as the lubricant to maximize the explosive energy. TMETN is a liquid nitrate ester which requires stabilization with conventional free radical stabilizers such as 2- nitrodiphenylamine, methyl-nitroanaline, or ethyl centrylite. Since these injection moldable explosives are expected to cure in place, a polyesterurethane binder based on polymeric isocyanate of hexamethylene diisocyanate and polycaprolactone polyols is dissolved in TMETN. The solubility of the polymer precursors in TMETN also reduces the energetic liquids sensitivity. The latent cure catalyst Dabco T-131 was used to minimize shrinkage associated with thermal expansion, reduce cost associated with oven cures, to give 4-6 hour potlife and overnight cure to handling strength. The product RX-08-HD is a new, low-viscosity, injection moldable explosive that can be extruded into complex, void-free shapes. Combined with appropriate design and other aspects of weaponization, RX-08-HD has produced outstanding results.

Steam explosion pretreatment of softwood: the effect of the explosive decompression on enzymatic digestibility.

Science.gov (United States)

Pielhop, Thomas; Amgarten, Janick; von Rohr, Philipp Rudolf; Studer, Michael H

2016-01-01

Steam explosion pretreatment has been examined in many studies for enhancing the enzymatic digestibility of lignocellulosic biomass and is currently the most common pretreatment method in commercial biorefineries. The information available about the effect of the explosive decompression on the biochemical conversion is, however, very limited, and no studies prove that the latter is actually enhanced by the explosion. Hence, it is of great value to discern between the effect of the explosion on the one hand and the steaming on the other hand, to identify their particular influences on enzymatic digestibility. The effect of the explosive decompression in the steam explosion pretreatment of spruce wood chips on their enzymatic cellulose digestibility was studied systematically. The explosion had a high influence on digestibility, improving it by up to 90 % compared to a steam pretreatment without explosion. Two factors were identified to be essentially responsible for the effect of the explosion on enzymatic digestibility: pretreatment severity and pressure difference of the explosion. A higher pretreatment severity can soften up and weaken the lignocellulose structure more, so that the explosion can better break up the biomass and decrease its particle size, which enhances its digestibility. In particular, increasing the pressure difference of the explosion leads to more defibration, a smaller particle size and a better digestibility. Though differences were found in the micro- and nanostructure of exploded and non-exploded biomass, the only influence of the explosion on digestibility was found to be the macroscopic particle size reduction. Steam explosion treatments with a high severity and a high pressure difference of the explosion lead to a comparatively high cellulose digestibility of the-typically very recalcitrant-softwood biomass. This is the first study to show that explosion can enhance the enzymatic digestibility of lignocellulosic biomass. If the

Preliminary experiments on wastes degradation by thermal plasma

International Nuclear Information System (INIS)

Cota S, G.; Pacheco S, J.; Segovia R, A.; Pena E, R.; Merlo S, L.

1996-01-01

This work presents the fundamental aspects involved in the installation and start up of an experimental equipment for the hazardous wastes degradation using the thermal plasma technology. It is mentioned about the form in which the thermal plasma is generated and the characteristics that its make to be an appropriate technology for the hazardous wastes degradation. Just as the installed structures for to realize the experiments and results of the first studies on degradation, using nylon as problem sample. (Author)

Improved explosive collection and detection with rationally assembled surface sampling materials

Energy Technology Data Exchange (ETDEWEB)

Chouyyok, Wilaiwan; Bays, J. Timothy; Gerasimenko, Aleksandr A.; Cinson, Anthony D.; Ewing, Robert G.; Atkinson, David A.; Addleman, R. Shane

2016-01-01

Sampling and detection of trace explosives is a key analytical process in modern transportation safety. In this work we have explored some of the fundamental analytical processes for collection and detection of trace level explosive on surfaces with the most widely utilized system, thermal desorption IMS. The performance of the standard muslin swipe material was compared with chemically modified fiberglass cloth. The fiberglass surface was modified to include phenyl functional groups. When compared to standard muslin, the phenyl functionalized fiberglass sampling material showed better analyte release from the sampling material as well as improved response and repeatability from multiple uses of the same swipe. The improved sample release of the functionalized fiberglass swipes resulted in a significant increase in sensitivity. Various physical and chemical properties were systematically explored to determine optimal performance. The results herein have relevance to improving the detection of other explosive compounds and potentially to a wide range of other chemical sampling and field detection challenges.

Plasma thermal energy transport: theory and experiments

International Nuclear Information System (INIS)

Coppi, B.

Experiments on the transport across the magnetic field of electron thermal energy are reviewed (Alcator, Frascati Torus). In order to explain the experimental results, a transport model is described that reconfirmed the need to have an expression for the local diffusion coefficient with a negative exponent of the electron temperature

Seismic explosion sources on an ice cap

DEFF Research Database (Denmark)

Shulgin, Alexey; Thybo, Hans

2015-01-01

crustal model can be modelled. A crucial challenge for applying the technique is to control the sources. Here, we present data that describe the efficiency of explosive sources in the ice cover. Analysis of the data shows, that the ice cap traps a significant amount of energy, which is observed......Controlled source seismic investigation of crustal structure below ice covers is an emerging technique. We have recently conducted an explosive refraction/wide-angle reflection seismic experiment on the ice cap in east-central Greenland. The data-quality is high for all shot points and a full...

A comparative study on two explosive acetone peroxides

Energy Technology Data Exchange (ETDEWEB)

Egorshev, V. Yu.; Sinditskii, V.P., E-mail: vps@rctu.ru; Smirnov, S.P.

2013-12-20

Highlights: • The most accurate heats of DADP and TATP sublimation were evaluated from experimental vapor pressures in a widened temperature range. • DADP is more volatile while more thermally stable peroxide than TATP. • DADP reveals lesser sensitivity to drop-weight impact, flame temperature, burning rate, and initiating efficiency as compared with TATP. - Abstract: Two explosive cyclic acetone peroxides, diacetone diperoxide (DADP) and triacetone triperoxide (TATP) have been studied in respect of thermal decomposition, burning behavior, impact sensitivity, and initiating efficiency. Using the glass Bourdon gauge technique, the vapor pressures of TATP and DADP were determined over the temperature range 75–144 °C and 67–120 °C, respectively. The kinetic parameters of decomposition of the peroxides in the gas phase have been obtained in the temperature interval of 140–200 °C. The decomposition of both DADP and TATP followed the first-order reaction to high degrees of decay with close activation energies of 159.2 kJ/mol (38.0 kcal/mol) and 165.8 kJ/mol (39.6 kcal/mol), respectively. The decomposition rate constants of DADP were found to be approximately 2 times less than those of TATP. The linear burning rate of DADP measured in a constant-pressure window bomb appeared to be approximately 5 times less than that of TATP. Temperature profiles in the combustion wave were measured at subatmospheric pressures with the help of thin tungsten-rhenium thermocouples. The leading reaction on combustion of both volatile peroxides was assumed to occur in the gas phase. Kinetic parameters of the leading reaction derived from the combustion data showed a good agreement with kinetic parameters of low-temperature thermal decomposition extrapolated to the high-temperature flame zone. In the drop-weight impact test, DADP appeared to be notably less sensitive peroxide than TATP. No deflagration-to-detonation transition was observed when RDX was attempted to explode by

Thermal anchoring of wires in large scale superconducting coil test experiment

International Nuclear Information System (INIS)

Patel, Dipak; Sharma, A.N.; Prasad, Upendra; Khristi, Yohan; Varmora, Pankaj; Doshi, Kalpesh; Pradhan, S.

2013-01-01

Highlights: • We addressed how thermal anchoring in large scale coil test is different compare to small cryogenic apparatus? • We did precise estimation of thermal anchoring length at 77 K and 4.2 K heat sink in large scale superconducting coil test experiment. • We addressed, the quality of anchoring without covering entire wires using Kapton/Teflon tape. • We obtained excellent results in temperature measurement without using GE Varnish by doubling estimated anchoring length. -- Abstract: Effective and precise thermal anchoring of wires in cryogenic experiment is mandatory to measure temperature in milikelvin accuracy and to avoid unnecessary cooling power due to additional heat conduction from room temperature (RT) to operating temperature (OT) through potential, field, displacement and stress measurement instrumentation wires. Instrumentation wires used in large scale superconducting coil test experiments are different compare to cryogenic apparatus in terms of unique construction and overall diameter/area due to errorless measurement in large time-varying magnetic field compare to small cryogenic apparatus, often shielded wires are used. Hence, along with other variables, anchoring techniques and required thermal anchoring length are entirely different in this experiment compare to cryogenic apparatus. In present paper, estimation of thermal anchoring length of five different types of instrumentation wires used in coils test campaign at Institute for Plasma Research (IPR), India has been discussed and some temperature measurement results of coils test campaign have been presented

Studies of the laser-induced fluorescence of explosives and explosive compositions.

Energy Technology Data Exchange (ETDEWEB)

Hargis, Philip Joseph, Jr. (,; .); Thorne, Lawrence R.; Phifer, Carol Celeste; Parmeter, John Ethan; Schmitt, Randal L.

2006-10-01

Continuing use of explosives by terrorists throughout the world has led to great interest in explosives detection technology, especially in technologies that have potential for standoff detection. This LDRD was undertaken in order to investigate the possible detection of explosive particulates at safe standoff distances in an attempt to identify vehicles that might contain large vehicle bombs (LVBs). The explosives investigated have included the common homogeneous or molecular explosives, 2,4,6-trinitrotoluene (TNT), pentaerythritol tetranitrate (PETN), cyclonite or hexogen (RDX), octogen (HMX), and the heterogeneous explosive, ammonium nitrate/fuel oil (ANFO), and its components. We have investigated standard excited/dispersed fluorescence, laser-excited prompt and delayed dispersed fluorescence using excitation wavelengths of 266 and 355 nm, the effects of polarization of the laser excitation light, and fluorescence imaging microscopy using 365- and 470-nm excitation. The four nitro-based, homogeneous explosives (TNT, PETN, RDX, and HMX) exhibit virtually no native fluorescence, but do exhibit quenching effects of varying magnitude when adsorbed on fluorescing surfaces. Ammonium nitrate and fuel oil mixtures fluoresce primarily due to the fuel oil, and, in some cases, due to the presence of hydrophobic coatings on ammonium nitrate prill or impurities in the ammonium nitrate itself. Pure ammonium nitrate shows no detectable fluorescence. These results are of scientific interest, but they provide little hope for the use of UV-excited fluorescence as a technique to perform safe standoff detection of adsorbed explosive particulates under real-world conditions with a useful degree of reliability.

Pyroshock Prediction of Ridge-Cut Explosive Bolts Using Hydrocodes

Directory of Open Access Journals (Sweden)

Juho Lee

2016-01-01

Full Text Available Pyrotechnic release devices such as explosive bolts are prevalent for many applications due to their merits: high reliability, high power-to-weight ratio, reasonable cost, and more. However, pyroshock generated by an explosive event can cause failures in electric components. Although pyroshock propagations are relatively well understood through many numerical and experimental studies, the prediction of pyroshock generation is still a very difficult problem. This study proposes a numerical method for predicting the pyroshock of a ridge-cut explosive bolt using a commercial hydrocode (ANSYS AUTODYN. A numerical model is established by integrating fluid-structure interaction and complex material models for high explosives and metals, including high explosive detonation, shock wave transmission and propagation, and stress wave propagation. To verify the proposed numerical scheme, pyroshock measurement experiments of the ridge-cut explosive bolts with two types of surrounding structures are performed using laser Doppler vibrometers (LDVs. The numerical analysis results provide accurate prediction in both the time (acceleration and frequency domains (maximax shock response spectra. In maximax shock response spectra, the peaks due to vibration modes of the structures are observed in both the experimental and numerical results. The numerical analysis also helps to identify the pyroshock generation source and the propagation routes.

Water containing explosive for big diameter use. [Slurry of ammonium nitrate and monomethyl lamine

Energy Technology Data Exchange (ETDEWEB)

Sunakawa, Tomoji; Fujita, Koichi; Kodama, Taro; Suzuki, Masahiro; Ono, Naoki

1988-05-11

This is a report concerning the design and experiment of water containing explosive which can be used as a substitute of ANFO. As the water containing explosive, slurry type was taken which consists of ammonium nitrate and monomethyl amine as main components and density of which was more than 1.2, explosion speed 4880 m/s, F value 7790 atm*L/Kg. Experiments were conducted for variuous loading length. From the result, it was recognized that at least 4.5 m of loading length was neccessary for achieving better result than the case whlen only ANFO was used. (1 fig, 1 tab)

76 FR 64974 - Commerce in Explosives; List of Explosive Materials (2011R-18T)

Science.gov (United States)

2011-10-19

... slurry and water gel explosives. Blasting caps. Blasting gelatin. Blasting powder. BTNEC [bis.... Esters of nitro-substituted alcohols. Ethyl-tetryl. Explosive conitrates. Explosive gelatins. Explosive... silver. Fulminating gold. Fulminating mercury. Fulminating platinum. Fulminating silver. G Gelatinized...

Experiments and numerical simulations of fluctuating thermal stratification in a branch pipe

Energy Technology Data Exchange (ETDEWEB)

Nakamura, Akira; Murase, Michio; Sasaki, Toru [Inst. of Nuclear Safety System Inc., Mihama, Fukui (Japan); Takenaka, Nobuyuki; Hamatani, Daisuke [Kobe Univ. (Japan)

2002-09-01

Many pipes branch off from the main pipe in plants. When the main flow in the main pipe is hotter than a branch pipe that branches off downward, the hot water penetrates into the branch pipe with the cavity flow that is induced by the main flow and causes thermal stratification. If the interface of the stratification fluctuates in an occluded branch pipe, thermal fatigue may occur in pipe wall. Some experiments and numerical simulations were conducted to elucidate the mechanism of this fluctuating thermal stratification. The vortex structures were observed in the experiments of straight or bent branch pipes. When the main flow was heated and the thermal stratification interface was at the elbow, a ''burst'' phenomenon occurred in the interface in connection with large heat fluctuation. The effects of pipe shape on the length of penetration were investigated in order to modify simulation conditions. The vortex structures and the fluctuating thermal stratification at elbow in the numerical simulation showed good agreement with experiments. (author)

A single sphere film boiling model for trigger ability and explosion potential

International Nuclear Information System (INIS)

Park, Ik Kyu; Kim, Jong Hwan; Hong, Seong Ho; Hong, Seong Wan

2012-01-01

The main causes for the controversy about the corium explosiveness are the hydrogen effect, large voided mixture, material property, poor triggering event (wrong position, weak triggering, wrong time), and low superheat due to a high melting temperature. It has been suggested that a steam explosion of the corium/water system must be suppressed due to the physical properties of corium such as high temperature, high density, multicomponent oxide melt, and low thermal conductivity. It was also claimed that the magnitude of the effect on the FCI results of corium/water systems is on the order of higher density, higher temperature, and non eutectic composition. This concept of a material effect is supported to some degree by parametric experimental results. However, the parametric results between the steam explosion pressure and the material compositions do not directly provide an understanding of the mechanism for the material difference affecting a steam explosion process, even though the sensitivity results can reveal the trends of some parameters affecting the FCI results. This concept of a material effect is supported to some degree by parametric experimental results. The parametric tests themselves also provide us with information on the effect of each initial parameter on a steam explosion. However, sensitivity studies between the steam explosion pressure and the initial value of a parameter do not directly provide an understanding of the steam explosion process. Handling the explosion res sure and initial condition without a mixing could not contribute to a code development process. We need a certain parameter for representing mixing, but we cannot measure it during the FCI tests. The particle size distribution collected after the FCI tests can be a good indicator for explaining a mixing process. In this paper, TROI tests were analyzed in view of a particle size response for various types of fuel coolant explosions. The heat losses and remnants were calculated

The present status of scientific applications of nuclear explosions

Energy Technology Data Exchange (ETDEWEB)

Cowan, G A; Diven, B C [Los Alamos Scientific Laboratory, University of California, Los Alamos, NM (United States)

1970-05-15

This is the fourth in a series of symposia which started, in 1957 at Livermore with the purpose of examining the peaceful uses of nuclear explosives. Although principal emphasis has {sup b}een placed on technological applications, the discussions have, from the outset, included the fascinating question of scientific uses. Of the possible scientific applications which were mentioned at the 1957 meeting, the proposals which attracted most attention involved uses of nuclear explosions for research in seismology. It is interesting to note that since then a very large and stimulating body of data in the field of seismology has been collected from nuclear tests. Ideas for scientific applications of nuclear explosions go back considerably further than 1957. During the war days Otto Frisch at Los Alamos suggested that a fission bomb would provide an excellent source of fast neutrons which could be led down a vacuum pipe and used for experiments in a relatively unscattered state. This idea, reinvented, modified, and elaborated upon in the ensuing twenty-five years, provides the basis for much of the research discussed in this morning's program. In 1952 a somewhat different property of nuclear explosions, their ability to produce intense neutron exposures on internal targets and to synthesize large quantities of multiple neutron capture products, was dramatically brought to our attention by analysis of debris from the first large thermonuclear explosion (Mike) in which the elements einsteinium and fermiun were observed for the first time. The reports of the next two Plowshare symposia in 1959 and 1964 help record the fascinating development of the scientific uses of neutrons in nuclear explosions. Starting with two 'wheel' experiments in 1958 to measure symmetry of fission in 235-U resonances, the use of external beams of energy-resolved neutrons was expanded on the 'Gnome' experiment in 1961 to include the measurement of neutron capture excitation functions for 238-U, 232

77 FR 58410 - Commerce in Explosives; List of Explosive Materials (2012R-10T)

Science.gov (United States)

2012-09-20

... sensitive slurry and water gel explosives. Blasting caps. Blasting gelatin. Blasting powder. BTNEC [bis.... Esters of nitro-substituted alcohols. Ethyl-tetryl. Explosive conitrates. Explosive gelatins. Explosive.... Fulminate of silver. Fulminating gold. Fulminating mercury. Fulminating platinum. Fulminating silver. G...

A review of vapor explosion information pertinent to the SRS reactors

International Nuclear Information System (INIS)

Hyder, M.L.; Allison, D.K.

1992-04-01

Vapor explosions are explosive events resulting from the mixing of two liquids, one of which is heated to a temperature well above the boiling point of the second. Under some circumstances mixing of the liquids can boil part of the lower boiling liquid so quickly that the expanding vapor generates a strong pressure wave and explosion. If the lower boiling liquid is water, as is frequently the case, the event is called a ''steam explosion''. Analyses in support of the K-Reactor Probabilistic Risk Assessment have shown that steam explosions generated by the interaction of molten reactor fuel with water contribute significantly to the risk of reactor operation at the SRS. This calculated risk incorporates a conservative treatment of the uncertainties associated with such explosions. Study of steam explosions involving molten reactor materials has been included in the Severe Accident Analysis Program (SAAP) in order to obtain a better evaluation of their importance, and, if possible, to find ways to avoid them. This paper presents a brief review and summary of steam explosion experience from literature accounts, along with the results of experimental studies from the SAAP. It concludes with an evaluation of current knowledge, and suggestions for future development. 71 refs

Recent results from TMX-U thermal barrier experiments

International Nuclear Information System (INIS)

Molvik, A.W.; Allen, S.; Barter, J.

1984-01-01

The Tandem Mirror Experiment-Upgrade (TMX-U) device was designed to study plasma confinement in a tandem mirror with thermal barriers. Previously the author reported improved axial confinement with high end-plug potentials, consistent with thermal barrier operation. Now, the existence of thermal barriers in TMX-U confirmed by measuring the axial potential profile. Specifically, measured the change in energy of a 5-keV deuterium neutral beam that is injected nearly parallel to the axis and is ionized between the barrier and the central cell. The authors found that the barrier potential is lower than the central cell potential, as required for a thermal barrier. The peak potential is at least 2.4 keV, as determined from the minimum energy of end loss ions. In addition, radial transport is reduced by the use of floating and electrodes that map to concentric cylinders in the central cell. Sloshing ions continue to be microstable

Blast from explosive evaporation of carbon dioxide : Experiment, modeling and physics

NARCIS (Netherlands)

Van der Voort, M.M.; Van den berg, A.C.; Roekaerts, D.J.E.M.; Xie, M.; De Bruijn, P.C.J.

2012-01-01

Explosive evaporation of a superheated liquid is a relevant hazard in the process industry. A vessel rupture during storage, transport or handling may lead to devastating blast effects. In order to assess the risk associated with this hazard or to design protective measures, an accurate prediction

Blast from explosive evaporation of carbon dioxide: Experiment, modeling and physics

NARCIS (Netherlands)

Voort, M.M. van der; Berg, A.C. van den; Roekaerts, D.J.E.M.; Xie, M.; Bruijn, P.C.J. de

2012-01-01

Explosive evaporation of a superheated liquid is a relevant hazard in the process industry. A vessel rupture during storage, transport or handling may lead to devastating blast effects. In order to assess the risk associated with this hazard or to design protective measures, an accurate prediction

Influence of the magnetic field in the time evolution of the solar explosion radiation in X-ray and microwaves

International Nuclear Information System (INIS)

Costa, J.E.R.

1983-01-01

It has been made a theoretical development, sel-consistent with recent models for the explosive source, applied to time delays of peak emission at different microwave frequencies, and between microwaves and hard X-ray emission. A working hipothesis has been assumed with the adoption of a growing magnetic field during the solar flare explosion, and therefore contributing to a growth in microwave emission, differential in frequency, producing delays of maximum emission towards lower microwave frequencies, and delays of microwave maximum emission with respect to hard X-rays. It has been found that these delays are consistent with a growth in the magnetic field of about 14% by assuming both thermal and non-thermal models. This variation in magnetic field has been associated to movements of thermal sources downwards in the solar atmosphere, and it has been found that the estimated velocities of displacement were consistent compared to characteristic velocities of anomalous conduction fronts of thermal models. (Author) [pt

Underground nuclear explosions

International Nuclear Information System (INIS)

Higgins, Gary H.

1970-01-01

In the Third Plowshare Symposium, held in 1964, data from a number of nuclear explosions were presented. At that time the basic elements of the nuclear explosion appeared to be well understood and relationships for predicting the gross nuclear effects were presented. Since that time, additional work has been done and many of the concepts have been extended. For example, nuclear explosions have been conducted at greater depths and with much greater yields. The physical and chemical properties of the material in which the explosions occur have been more accurately measured and related to explosion effects. Interpretation of the new information seems to indicate that the earlier relationships are valid over the ranges of energy and depths for which data is available but that effects relating to cavity and chimney sizes or fracturing had been overestimated at great depths of burst and higher yields. (author)

Underground nuclear explosions

Energy Technology Data Exchange (ETDEWEB)

Higgins, Gary H [Lawrence Radiation Laboratory, University of California, Livermore, CA (United States)

1970-05-01

In the Third Plowshare Symposium, held in 1964, data from a number of nuclear explosions were presented. At that time the basic elements of the nuclear explosion appeared to be well understood and relationships for predicting the gross nuclear effects were presented. Since that time, additional work has been done and many of the concepts have been extended. For example, nuclear explosions have been conducted at greater depths and with much greater yields. The physical and chemical properties of the material in which the explosions occur have been more accurately measured and related to explosion effects. Interpretation of the new information seems to indicate that the earlier relationships are valid over the ranges of energy and depths for which data is available but that effects relating to cavity and chimney sizes or fracturing had been overestimated at great depths of burst and higher yields. (author)

Thermal control surfaces on the MSFC LDEF experiments

International Nuclear Information System (INIS)

Wilkes, D.R.; Whitaker, A.F.; Zwiener, J.M.; Linton, R.C.; Shular, D.; Peters, P.N.; Gregory, J.C.

1992-01-01

There were five Marshall Space Flight Center (MSFC) experiments on the LDEF. Each of those experiments carried thermal control surfaces either as test samples or as operational surfaces. These materials experienced varying degrees of mechanical and optical damage. Some materials were virtually unchanged by the extended exposure while others suffered extensive degradation. The synergistic effects due to the constituents of the space environment are evident in the diversity of these material changes. The sample complement for the MSFC experiments is described along with results of the continuing analyses efforts

Analysis of the thermal fragmentation as a mechanism for the initiation of steam explosion

International Nuclear Information System (INIS)

Lamome, J.; Meignen, R.

2007-01-01

We propose a theoretical study of the film behaviour and its stability during the phenomenon of drop thermal fragmentation. We discuss the role of the various possible influences on the film collapse and instability processes. First, we discuss the possibility of simple fuel/coolant contacts as a mechanism for the drop instability. Under this assumption, we then describe and test our model on Nelson and Duda explodability maps, with a particular emphasis on the description of the film evolution. The reasonable agreement obtained allows us to analyse the effect of various parameters as the ambient pressure, subcooling and trigger pulse shape on the film behaviour in Nelson and Duda experiments. The perspectives of this work are then shortly discussed including extrapolation to more prototypic situations and the role of thermal fragmentation itself. (authors)

Theoretical investigations on the fragmentation of drops of melt with respect to the description of thermal detonations (vapor explosions) and their application in the code Frademo

International Nuclear Information System (INIS)

Burger, M.; Carachalios, C.; Kim, D.S.; Unger, H.

1986-01-01

Vapor explosions caused by the contact of molten core material with coolant are an important issue within reactor safety analysis, because they could produce an early threat to the containment during a core melt accident. The case of steady-state propagation of a detonation wave through a coarse premixture of melt and coolant represents the most severe case of a large scale vapor explosion under reactor conditions with the highest rate and largest heat release and therefore also the highest yield of mechanical energy. The present contribution starts with the description of the integral model of the detonation wave. The fragmentation processes, which are decisive for these exchange terms and the detonation process as a whole, are dealt with also. Hydrodynamic fragmentation processes as well as a thermally induced one are considered. The processes which take place inside a detonation wave, especially the fragmentation of the drops of melt and the velocity equilibration between the melt and the coolant, determine the behavior of the wave. In the present model these processes are described within a three-phase approach, considering the drops of melt, the fragments and the coolant as separate flow phases. In the frame of this work, the computer code FRADEMO has been developed. It consists of an overall description of the processes inside a steady-state detonation wave in combination with a full description of the detailed models on hydrodynamic and thermal fragmentation presented in this report. Some useful information for the potential code user is given in the appendix of the detailed report also

Spectral content of seismic movements produced by underground nuclear explosions; Contenu spectral des mouvements seismiques dus aux explosions nucleaires souterraines

Energy Technology Data Exchange (ETDEWEB)

Albaret, A; Duclaux, F [Commissariat a l' Energie Atomique, Bruyeres-le-Chatel (France). Centre d' Etudes

1969-07-01

After a summary of available data, both theoretical and experimental, concerning the spectral content of seismic movements, a description is given of the experiments carried out during the French nuclear explosions in the Sahara, and of the results obtained on the volume waves. A comparison is then made with certain American results. A new method is described for studying the amplitude spectra; it has made it possible to show that the amount of low frequencies in the spectrum increases with the power of the explosion, and decreases with the distance to the zero point and with the filtering effect of the weathered zone. A calculation is then made of the low cut-off ground filter, this giving a better representation of the initial seismic phenomenon. (authors) [French] Apres avoir resume les connaissances disponibles, aussi bien theoriques qu'experimentales, sur le contenu spectral des mouvements seismiques, on decrit les experiences effectuees a l'occasion des explosions nucleaires francaises du Sahara et les resultats obtenus sur les ondes de volume. Puis on les compare avec certains resultats americains. On decrit une nouvelle methode d'etude des spectres d'amplitudes qui montre que le spectre est d'autant plus riche en basses frequences que la puissance de l'explosion est grande, que la distance au point zero est faible et qu'il est moins filtre par la zone alteree superficielle. Puis on calcule le filtre terrain coupe-bas qui permet de donner une representation plus fidele du phenomene seismique initial. (auteurs)

Theoretical work on melt-coolant interactions (steam explosions)

International Nuclear Information System (INIS)

Arnecke, G.; Jacobs, H.; Stehle, B.; Thurnay, K.; Vaeth, L.; Lummer, M.

1995-01-01

The code IVA3 is used for modelling the physical processes related to steam explosions, i.e. the premixing phase preceding the explosion as well as the explosion itself. This code has been replaced by the updated version IVA-KA in May 1994, which encompasses all model and code improvements performed till the beginning of 1994. The following further work on and with IVA-KA has been performed: 1. Inclusion of friction at inner and outer walls, improvement on the drag model, improvement of boundary conditions for outgoing flow, optional inclusion of improved water material data, improvement of the numerical procedure, correction of coding errors. 2. Three FARO-experiments (investigating the behaviour of molten material falling into water) were recalculated with IVA-KA. The time dependent pressure increase is reproduced very well for one experiment, but is not quite satisfactory for a second one. The third one cannot be simulated satisfactorily because of the presence of metallic zirconium in the melt, which is not being modelled by IVA-KA at present. 3. One PREMIX-experiment (similar to FARO, but at 1 bar ambient pressure and with smaller amounts of melt) is also being analyzed with IVA-KA. First results show a good representation of the material distribution during the penetration of the melt into the water. 4. One of the first two QUEOS-experiments performed at KfK has been simulated with IVA-KA. Some results are well reproduced by IVA-KA, but there may be a deficiency of the drag laws. (orig./HP)

Optical pyrometry of fireballs of metalized explosives

Energy Technology Data Exchange (ETDEWEB)

Goroshin, Samuel; Frost, David L.; Levine, Jeffrey [McGill University, Mechanical Engineering, 817 Sherbrooke St. W., Montreal, Quebec, H3A 2K6 (Canada); Yoshinaka, Akio; Zhang, Fan [Defence R and D Canada - Suffield, Box 4000, Stn. Main, Medicine Hat, Alberta, T1A 8K6 (Canada)

2006-06-15

Fast-response optical diagnostics (a time-integrated spectrometer and two separate fast-response three-color pyrometers) are used to record the transient visible radiation emitted by a fireball produced when a condensed explosive is detonated. Measurement of the radiant intensity, in several narrow wavelength bands, is used to estimate the temperature of the condensed products within the fireball. For kg-scale conventional oxygen-deficient homogeneous TNT and nitromethane explosive charges, the radiant intensity reaches a maximum typically after tens of milliseconds, but the measured fireball temperature remains largely constant for more than 100 ms, at a value of about 2,000 K, consistent with predictions using equilibrium thermodynamics codes. When combustible metal particles (aluminum, magnesium or zirconium) are added to the explosive, reaction of the particles enhances the radiant energy and the fireball temperature is increased. In this case the fireball temperatures are lower than equilibrium predictions, but are consistent with measurements of particle temperature in single particle ignition experiments. (Abstract Copyright [2006], Wiley Periodicals, Inc.)

Stellar explosion

International Nuclear Information System (INIS)

Suraud, E.

1987-01-01

What is the energy source and which physical processes are powerful enough to generate this explosion which scatters the star. The knowledge progress of very dense matter allows the scenario reconstitution. An instability in the star core which is developing during milliseconds is the cause of this explosion [fr

Steam explosion studies review

International Nuclear Information System (INIS)

Hwang, Moon Kyu; Kim, Hee Dong

1999-03-01

When a cold liquid is brought into contact with a molten material with a temperature significantly higher than the liquid boiling point, an explosive interaction due to sudden fragmentation of the melt and rapid evaporation of the liquid may take place. This phenomenon is referred to as a steam explosion or vapor explosion. Depending upon the amount of the melt and the liquid involved, the mechanical energy released during a vapor explosion can be large enough to cause serious destruction. In hypothetical severe accidents which involve fuel melt down, subsequent interactions between the molten fuel and coolant may cause steam explosion. This process has been studied by many investigators in an effort to assess the likelihood of containment failure which leads to large scale release of radioactive materials to the environment. In an effort to understand the phenomenology of steam explosion, extensive studies has been performed so far. The report presents both experimental and analytical studies on steam explosion. As for the experimental studies, both small scale tests which involve usually less than 20 g of high temperature melt and medium/large scale tests which more than 1 kg of melt is used are reviewed. For the modelling part of steam explosions, mechanistic modelling as well as thermodynamic modelling is reviewed. (author)

Experiment study on thermal mixing performance of HTR-PM reactor outlet

Energy Technology Data Exchange (ETDEWEB)

Zhou, Yangping, E-mail: zhouyp@mail.tsinghua.edu.cn [Institute of Nuclear and New Energy Technology, Collaborative Innovation Center of Advanced Nuclear Energy Technology, the Key Laboratory of Advanced Reactor Engineering and Safety, Ministry of Education, Tsinghua University, Beijing 100084 (China); Hao, Pengfei [School of Aerospace, Tsinghua University, Beijing 100084 (China); Li, Fu; Shi, Lei [Institute of Nuclear and New Energy Technology, Collaborative Innovation Center of Advanced Nuclear Energy Technology, the Key Laboratory of Advanced Reactor Engineering and Safety, Ministry of Education, Tsinghua University, Beijing 100084 (China); He, Feng [School of Aerospace, Tsinghua University, Beijing 100084 (China); Dong, Yujie; Zhang, Zuoyi [Institute of Nuclear and New Energy Technology, Collaborative Innovation Center of Advanced Nuclear Energy Technology, the Key Laboratory of Advanced Reactor Engineering and Safety, Ministry of Education, Tsinghua University, Beijing 100084 (China)

2016-09-15

A model experiment is proposed to investigate the thermal mixing performance of HTR-PM reactor outlet. The design of the test facility is introduced, which is set at a scale of 1:2.5 comparing with the design of thermal mixing structure at HTR-PM reactor outlet. The test facility using air as its flow media includes inlet pipe system, electric heaters, main mixing structure, hot gas duct, exhaust pipe system and I&C system. Experiments are conducted on the test facility and the values of thermal-fluid parameters are collected and analyzed, which include the temperature, pressure and velocity of the flow as well as the temperature of the tube wall. The analysis results show the mixing efficiency of the test facility is higher than that required by the steam generator of HTR-PM, which indicates that the thermal mixing structure of HTR-PM fulfills its design requirement.

Testing the equation of state and electrical conductivity of copper by the electrical wire explosion in air: Experiment and magnetohydrodynamic simulation

International Nuclear Information System (INIS)

Barysevich, A. E.; Cherkas, S. L.

2011-01-01

We perform experiments on testing the equations of state and electrical conductivity of copper in three different regimes of copper wire electrical explosion, when the inserted energy (i) is slightly exceeded, (ii) is approximately equal, and (iii) is substantially exceeded the energy needed for the wire complete evaporation. Magnetohydrodynamic simulation is performed. The results predicted by the two different equations of state are compared with the experiment. Empirical expression for the copper electrical conductivity is presented. Parameters in this expression is fit on every of two equations of state. Map of copper conductivity is plotted.

Atmospheric emission of NOx from mining explosives: A critical review

Science.gov (United States)

Oluwoye, Ibukun; Dlugogorski, Bogdan Z.; Gore, Jeff; Oskierski, Hans C.; Altarawneh, Mohammednoor

2017-10-01

High-energy materials such as emulsions, slurries and ammonium-nitrate fuel-oil (ANFO) explosives play crucial roles in mining, quarrying, tunnelling and many other infrastructure activities, because of their excellent transport and blasting properties. These explosives engender environmental concerns, due to atmospheric pollution caused by emission of dust and nitrogen oxides (NOx) from blasts, the latter characterised by the average emission factor of 5 kg (t AN explosive)-1. This first-of-its-kind review provides a concise literature account of the formation of NOx during blasting of AN-based explosives, employed in surface operations. We estimate the total NOx emission rate from AN-based explosives as 0.05 Tg (i.e., 5 × 104 t) N per annum, compared to the total global annual anthropogenic NOx emissions of 41.3 × 106 t N y-1. Although minor in the global sense, the large localised plumes from blasting exhibit high NOx concentration (500 ppm) exceeding up to 3000 times the international standards. This emission has profound consequences at mining sites and for adjacent atmospheric environment, necessitating expensive management of exclusion zones. The review describes different types of AN energetic materials for civilian applications, and summarises the essential properties and terminologies pertaining to their use. Furthermore, we recapitulate the mechanisms that lead to the formation of the reactive nitrogen species in blasting of AN-based explosives, review their implications to atmospheric air pollution, and compare the mechanisms with those experienced in other thermal and combustion operations. We also examine the mitigation approaches, including guidelines and operational-control measures. The review discusses the abatement technologies such as the formulation of new explosive mixtures, comprising secondary fuels, spin traps and other additives, in light of their effectiveness and efficiency. We conclude the review with a summary of unresolved problems

The Soviet program for peaceful uses of nuclear explosions

International Nuclear Information System (INIS)

Nordyke, M.D.

1996-01-01

The concept of utilizing the weapons of war to serve the peaceful pursuits of mankind is as old as civilization itself. Perhaps the most famous reference to this basic desire is recorded in the Book of Micah where the great prophet Isiah called upon his people 'to turn your spears into pitchforks and your swords into plowshares.' As the scientists at Los Alamos worked on developing the world's first atomic bomb, thoughts of how this tremendous new source of energy could be used for peaceful purposes generally focused on using the thermal energy generated by the slow fission of uranium in a reactor, such as those being used to produce Plutonium to drive electric power stations. However, being scientists in a new, exciting field, it was impossible to avoid letting their minds wander from the task at hand to other scientific or non-military uses for the bombs themselves. During the Manhattan Project, Otto Frisch, one of the pioneers in the development of nuclear fission process in the 1930s, first suggested using an atomic explosion as a source for a large quantities of neutrons which could used in scientific experiments designed to expand their understanding of nuclear physics. After the war was over, many grandiose ideas appeared in the popular press on how this new source of energy should be to serve mankind. Not to be left out of the growing enthusiasm for peaceful uses of atomic energy, the Soviet Union added their visions to the public record. This document details the Soviet program for using nuclear explosions in peacetime pursuits

The Soviet program for peaceful uses of nuclear explosions

Energy Technology Data Exchange (ETDEWEB)

Nordyke, M.D.

1996-07-24

The concept of utilizing the weapons of war to serve the peaceful pursuits of mankind is as old as civilization itself. Perhaps the most famous reference to this basic desire is recorded in the Book of Micah where the great prophet Isiah called upon his people `to turn your spears into pitchforks and your swords into plowshares.` As the scientists at Los Alamos worked on developing the world`s first atomic bomb, thoughts of how this tremendous new source of energy could be used for peaceful purposes generally focused on using the thermal energy generated by the slow fission of uranium in a reactor, such as those being used to produce Plutonium to drive electric power stations. However, being scientists in a new, exciting field, it was impossible to avoid letting their minds wander from the task at hand to other scientific or non-military uses for the bombs themselves. During the Manhattan Project, Otto Frisch, one of the pioneers in the development of nuclear fission process in the 1930s, first suggested using an atomic explosion as a source for a large quantities of neutrons which could used in scientific experiments designed to expand their understanding of nuclear physics. After the war was over, many grandiose ideas appeared in the popular press on how this new source of energy should be to serve mankind. Not to be left out of the growing enthusiasm for peaceful uses of atomic energy, the Soviet Union added their visions to the public record. This document details the Soviet program for using nuclear explosions in peacetime pursuits.

Final report on the small-scale vapor-explosion experiments using a molten NaCl--H2O system

International Nuclear Information System (INIS)

Anderson, R.P.; Bova, L.

1976-04-01

Vapor explosions were produced by injecting small quantities of water into a container filled with molten NaCl. Minimum explosion efficiencies, as evaluated from reaction-impulse measurements, were relatively large. Subsurface movies showed that the explosions resulted from a two-step sequence: an initial bulk-mixing phase in which the two liquids intermix on a large scale, but remain locally separated by an insulating gas-vapor layer; and a second step, immediately following breakdown of the gas layer, during which the two liquids locally fragment, intermix, and pressurize very rapidly. The experimental results were compared with various mechanistic models that had been proposed to explain vapor explosions. Early models seemed inconsistent with the results. More recent theories suggest that vapor explosions may be caused by a nucleation limit or by dynamic mixing combined with high surface-heat-transfer rates. Both types of models are consistent with the results

Explosion of a low mass neutron star

International Nuclear Information System (INIS)

Blinnikov, S.I.; Imshennik, V.S.; Nadyozhin, D.K.; Novikov, I.D.; Polnarev, A.G.; AN SSSR, Moscow. Fizicheskij Inst.); Perevodchikova, T.V.

1990-01-01

The hydrodynamical disruption of a low mass neutron star is investigated for the case when the stellar mass becomes smaller than the minimum value, M min ≅0.1 M sun . The final phase of the process is shown to proceed explosively, leading to an expansion of all the star, with a kinetic energy of 4.8 MeV per nucleon. The results of calculations are virtually independent of the way in which the neutron star mass goes down below M min (mass exchange in a close binary stellar system, nucleon decay, or some effective mass loss due to a hypothetical decrease of the gravitational constant). The neutron star disruption is followed by a short (0.01-0.1 s) burst of thermal hard X-rays and soft gamma-rays (kT=10-100 keV) with a subsequent much more prolonged tail of radiation induced by decays of long-lived radioactive nuclides. Some fraction of the explosion energy may be emitted in the form of neutrinos. (orig.)

Similarities and differences in vapor explosion criteria

International Nuclear Information System (INIS)

Cronenberg, A.W.

1978-01-01

An overview of recent ideas pertaining to vapor explosion criteria indicates that in general sense, a consensus of opinion is emerging on the conditions applicable to explosive vaporization. Experimental and theoretical work has lead a number of investigators to the formulation of such conditions which are quite similar in many respects, although the quantitative details of the model formulation of such conditions are somewhat different. All model concepts are consistent in that an initial period of stable film boiling, separating molten fuel from coolant, is considered necessary (at least for large-scale interactions and efficient intermixing), with subsequent breakdown of film boiling due to pressure and/or thermal effects, followed by intimate fuel-coolant contact and a rapid vaporization process which is sufficient to cause shock pressurization. Although differences arise as to the conditions for and the energetics associated with film boiling destabilization and the mode and energetics of fragmentation and intermixing. However, the principal area of difference seems to be the question of what constitutes the requisite condition(s) for rapid vapor production to cause shock pressurization

Optical detection of explosives: spectral signatures for the explosive bouquet

Science.gov (United States)

Osborn, Tabetha; Kaimal, Sindhu; Causey, Jason; Burns, William; Reeve, Scott

2009-05-01

Research with canines suggests that sniffer dogs alert not on the odor from a pure explosive, but rather on a set of far more volatile species present in an explosive as impurities. Following the explosive trained canine example, we have begun examining the vapor signatures for many of these volatile impurities utilizing high resolution spectroscopic techniques in several molecular fingerprint regions. Here we will describe some of these high resolution measurements and discuss strategies for selecting useful spectral signature regions for individual molecular markers of interest.

Material properties influence on steam explosion efficiency. Prototypic versus simulant melts, eutectic versus non-eutectic melts

International Nuclear Information System (INIS)

Leskovar, M.; Mavko, B.

2006-01-01

A steam explosion may occur during a severe nuclear reactor accident if the molten core comes into contact with the coolant water. A strong enough steam explosion in a nuclear power plant could jeopardize the containment integrity and so lead to a direct release of radioactive material to the environment. Details of processes taking place prior and during the steam explosion have been experimentally studied for a number of years with adjunct efforts in modelling these processes to address the scaling of these experiments. Steam explosion experiments have shown that there are important differences of behaviour between simulant and prototypical melts, and that also at prototypical melts the fuel coolant interactions depend on the composition of the corium. In experiments with prototypic materials no spontaneous steam explosions occurred (except with an eutectic composition), whereas with simulant materials the steam explosions were triggered spontaneously. The energy conversion ratio of steam explosions with prototypic melts is at least one order of magnitude lower than the energy conversion ratio of steam explosions with simulant melts. Although the different behaviour of prototypic and simulant melts has been known for a number of years, there is no reliable explanation for these differences. Consequently it is not possible to reliably estimate whether corium would behave so non-explosive also in reactor conditions, where the mass of poured melt is nearly three orders of magnitude larger than in experimental conditions. An even more fascinating material effect was observed recently at corium experiments with eutectic and non-eutectic compositions. It turned out that eutectic corium always exploded spontaneously, whereas non-eutectic corium never exploded spontaneously. In the paper, a possible explanation of both material effects (prototypic/simulant melts, eutectic/non-eutectic corium) on the steam explosion is provided. A model for the calculation of the

Thermal decomposition of organic solvent with nitric acid in nuclear fuel reprocessing plants

Energy Technology Data Exchange (ETDEWEB)

Koike, Tadao; Nishio, Gunji; Takada, Junichi; Tukamoto, Michio; Watanabe, Kouji [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment; Miyata, Sadaichirou

1995-02-01

Since a thermal decomposition of organic solvent containing TBP (tributyl phosphate) with nitric acid and heavy metal nitrates is an exothermic reaction, it is possible to cause an explosive decomposition of TBP-complex materials formed by a nitration between the solvent and nitric acid, if the solvent involving TBP-complex is heated upto a thermal limit in an evaporator to concentrate a fuel liquid solution from the extraction process in the reprocessing plant. In JAERI, the demonstration test for explosive decomposition of TBP-complex by the nitration was performed to elucidate the safety margin of the evaporator in the event of hypothetical explosion under auspices of the Science and Technology Agency. The demonstration test was carried out by heating TBP/n-dodecane solvent mixed with nitric acid and uranium nitrate. In the test, the thermal decomposition behavior of the solvent was examined, and also a kinematic reaction constant and a heat formation of the TBP-complex decomposition were measured by the test. In the paper, a safety analysis of a model evaporator was conducted during accidental conditions under the explosive decomposition of the solvent. (author).

The control and prevention of dust explosions

Energy Technology Data Exchange (ETDEWEB)

1982-01-01

Papers presented discussed: explosion characteristics and hybrid mixtures explosion characteristics and influencing factors, propagation of dust explosions in ducts, prevention of dust explosions, desensitization, explosion-proof type of construction, explosion pressure relief, optical flame barriers, slide-valves for explosion protection, Ventex explosion barrier valves, grinding and mixing plants, spray driers, dust explosions in silos, and explosion-proof bucket elevators. One paper has been abstracted separately.

Experience base for Radioactive Waste Thermal Processing Systems: A preliminary survey

International Nuclear Information System (INIS)

Mayberry, J.; Geimer, R.; Gillins, R.; Steverson, E.M.; Dalton, D.; Anderson, G.L.

1992-04-01

In the process of considering thermal technologies for potential treatment of the Idaho National Engineering Laboratory mixed transuranic contaminated wastes, a preliminary survey of the experience base available from Radioactive Waste Thermal Processing Systems is reported. A list of known commercial radioactive waste facilities in the United States and some international thermal treatment facilities are provided. Survey focus is upon the US Department of Energy thermal treatment facilities. A brief facility description and a preliminary summary of facility status, and problems experienced is provided for a selected subset of the DOE facilities

Mass Spectrometric Analysis of Eight Common Chemical Explosives Using Ion Trap Mass Spectrometer

Energy Technology Data Exchange (ETDEWEB)

Park, Sehwan; Lee, Jihyeon; KIm, Jeongkwon [Chungnam National Univ., Daejeon (Korea, Republic of); Cho, Soo Gyeong; Goh, Eun Mee [Agency for Defense Development, Daejeon (Korea, Republic of); Lee, Sungman; Koh, Sungsuk [Sensor Tech Inc., Seoul (Korea, Republic of)

2013-12-15

Eight representative explosives (ammonium perchlorate (AP), ammonium nitrate (AN), trinitrotoluene (TNT), 2,4-dinitrotoluene (DNT), cyclonite (RDX), cyclotetramethylenetetranitramine (HMX), pentaerythritol tetranitrate (PETN), and hexanitrostilbene (HNS)) were comprehensively analyzed with an ion trap mass spectrometer in negative ion mode using direct infusion electrospray ionization. MS/MS experiments were performed to generate fragment ions from the major parent ion of each explosive. Explosives in salt forms such as AP or AN provided cluster parent ions with their own anions. Explosives with an aromatic ring were observed as either [M.H]{sup -} for TNT and DNT or [M]{sup ·-}. for HNS, while explosives without an aromatic ring such as RDX, HMX, and PETN were detected as an adduct ion with a formate anion, i. e., [M+HCOO]{sup -}. These findings provide a guideline for the rapid and accurate detection of explosives once portable MS instruments become more readily available.

Mass Spectrometric Analysis of Eight Common Chemical Explosives Using Ion Trap Mass Spectrometer

International Nuclear Information System (INIS)

Park, Sehwan; Lee, Jihyeon; KIm, Jeongkwon; Cho, Soo Gyeong; Goh, Eun Mee; Lee, Sungman; Koh, Sungsuk

2013-01-01

Eight representative explosives (ammonium perchlorate (AP), ammonium nitrate (AN), trinitrotoluene (TNT), 2,4-dinitrotoluene (DNT), cyclonite (RDX), cyclotetramethylenetetranitramine (HMX), pentaerythritol tetranitrate (PETN), and hexanitrostilbene (HNS)) were comprehensively analyzed with an ion trap mass spectrometer in negative ion mode using direct infusion electrospray ionization. MS/MS experiments were performed to generate fragment ions from the major parent ion of each explosive. Explosives in salt forms such as AP or AN provided cluster parent ions with their own anions. Explosives with an aromatic ring were observed as either [M.H] - for TNT and DNT or [M] ·- . for HNS, while explosives without an aromatic ring such as RDX, HMX, and PETN were detected as an adduct ion with a formate anion, i. e., [M+HCOO] - . These findings provide a guideline for the rapid and accurate detection of explosives once portable MS instruments become more readily available

Conversion of chemical energy in an explosive by a magnetohydrodynamic method

International Nuclear Information System (INIS)

Lebedev, E.F.; Ostashev, V.E.; Svetsov, G.A.

1983-01-01

In this paper, the authors examine different methods for realizing the MHD method for converting chemical energy of a condensed explosive into pulsed electrical energy. It is shown that explosive MHD generators, which are compact sources of powerful pulses of electrical energy, are characterized by their relative simplicity, autonomy and maneuverability of firing and they are capable of operating in the frequency-periodic mode. A number of projects have been proposed for explosive MHD generators in the megajoule range. Practical experience has been gained in creating frequency-periodic action generators as well as autonomous setups using superconducting magnetic systems. The increase in the operational efficiency of an explosive MHD generator is primarily related to increasing the magnetic Reynolds number of the flow, which can be attained, in particular, by using different schemes for accumulating the energy of the explosion. The use of a metallic liner, which expands under the pressure of the detonation products, in an explosive MHD generator is, in the practical sense, apparently hopeless. The general information available on the parameters and properties of explosive MHD generators gives a basis for concluding that this generator is a promising source of powerful energy pulses. In a certain range of parameters, it can be an alternative to the use of conventional high-energy pulse devices

Comments on thermal runaway experiments in sub-ignition tokamaks

International Nuclear Information System (INIS)

Yamazaki, K.

1982-09-01

Justification of deuterium-tritium operations is discussed from the physics viewpoint and optimal thermal runaway experiments in high-field, high-density compact tokamaks are suggested within the minimization of the induced radioactivation. (author)

Thermal-mechanical-chemical responses of polymer-bonded explosives using a mesoscopic reactive model under impact loading.

Science.gov (United States)

Wang, XinJie; Wu, YanQing; Huang, FengLei

2017-01-05

A mesoscopic framework is developed to quantify the thermal-mechanical-chemical responses of polymer-bonded explosive (PBX) samples under impact loading. A mesoscopic reactive model is developed for the cyclotetramethylenetetranitramine (HMX) crystal, which incorporates nonlinear elasticity, crystal plasticity, and temperature-dependent chemical reaction. The proposed model was implemented in the finite element code ABAQUS by the user subroutine VUMAT. A series of three-dimensional mesoscale models were constructed and calculated under low-strength impact loading scenarios from 100m/s to 600m/s where only the first wave transit is studied. Crystal anisotropy and microstructural heterogeneity are responsible for the nonuniform stress field and fluctuations of the stress wave front. At a critical impact velocity (≥300m/s), a chemical reaction is triggered because the temperature contributed by the volumetric and plastic works is sufficiently high. Physical quantities, including stress, temperature, and extent of reaction, are homogenized from those across the microstructure at the mesoscale to compare with macroscale measurements, which will advance the continuum-level models. The framework presented in this study has important implications in understanding hot spot ignition processes and improving predictive capabilities in energetic materials. Copyright © 2016 Elsevier B.V. All rights reserved.

The Importance of a Thermal Manikin as Source and Obstacle in Full-Scale Experiments

DEFF Research Database (Denmark)

Nielsen, Peter V.

The thermal manikin is normally introduced at indoor environmental measurements to obtain detailed information on thermal comfort and air quality around a person. This paper deals with the opposite situation where manikins are introduced as sources and obstacles in order to obtain reasonable...... boundary conditions in experiments with the indoor environment. In other words, how will people influence the surroundings instead of how will the surroundings influence people? The use of thermal manikins in an experiment will of course take both situations into account, however, in some experiments...

Chernobyl explosion bombshell

International Nuclear Information System (INIS)

Martin, S.; Arnott, D.

1988-01-01

It is suggested that the explosion at the Chernobyl-4 reactor in April 1986 was a nuclear explosion. The evidence for this is examined. The sequence of events at Chernobyl is looked at to see if the effects were like those from a nuclear explosion. The question of whether a United Kingdom reactor could go prompt critical is discussed. It is concluded that prompt criticality excursions are possible, but the specific Chernobyl sequence is impossible. (UK)

A study on vapor explosions

International Nuclear Information System (INIS)

Takagi, N.; Shoji, M.

1979-01-01

An experimental study was carried out for vapor explosions of molten tin falling in water. For various initial metal temperatures and subcooling of water, transient pressure of the explosions, relative frequency of the explosions and the position where the explosions occur were measured in detail. The influence of ambient pressure was also investigated. From the results, it was concluded that the vapor explosion is closely related to the collapse of a vapor film around the molten metal. (author)

Development of a Risk-Based Decision-Support-Model for Protecting an Urban Medical Center from a Nuclear Explosion

International Nuclear Information System (INIS)

Ben-Dor, G.; Shohet, I.M.; Ornai, D.; Brosh, B.

2014-01-01

Nuclear explosion is the worst man-made physical threat on the human society. The nuclear explosion includes several consequences, some of them are immediate and others are long term. The major influences are: long duration blast, extreme thermal release, nuclear radiations, and electro-magnetic pulse (EMP). Their damage range is very wide. When nuclear explosion occurs above or in an urban area it is possible that one or more medical centers will be affected. Medical centers include several layers of structures defined by their resistance capacity to the nuclear explosion influences, beginning with the structure's frame and ending with different systems and with vulnerable medical critical infrastructures such as communications, medical gas supply, etc. A comprehensive literature survey revealed that in spite of the necessity and the importance of medical centers in the daily life and especially in emergency and post nuclear explosion, there is a lack of research on this topic

Gas pollutants from detonation and combustion of industrial explosives

Energy Technology Data Exchange (ETDEWEB)

Campos, J.; Pines, A.; Gois, J.C.; Portugal, A. (University of Coimbra, Coimbra (Portugal). Mechanical Engineering Dept.)

1993-01-01

The potential hazards of fumes, from blasting operations in underground mines, have long been recognised. Beyond this normal use of explosives, there are also large amounts of energy substances which cannot be used because their life time is outdated or they are not within the minimal quality requirements. There is a lack of information concerning tests, procedures and theoretical predictions of pollutant concentrations in fumes from detonation and combustion operations with industrial explosives. The most common industrial explosives in Portugal are ammonium nitrate-fuel oil compositions (anfo), and dynamite. Recently, ammonium nitrate based emulsion explosives are more and more used in industrial applications. This paper presents the structure and fundamental thermodynamic equations of THOR computer code to calculate the combustion and detonation products (CO[sub 2], CO, H[sub 2]O, N[sub 2], O[sub 2], H[sub 2], OH, NO, H, N, O, HCN, NH[sub 3], NO[sub 2], N[sub 2]O, CH[sub 4] gases and two kinds of solid carbon - graphite and diamond) for the minimum value of Gibbs free energy, using three well known equations of state - BKW, H9 and H12. Detonation experiments are described and gas analysis discussed. Measured pollutants concentrations (CO, CO[sub 2], NO and NO[sub 2]), as a function of volume of explosion chamber, prove the dependence of expansion mechanisms on CO and NO formation and recombination and validate theoretical predictions. Incineration of explosives in a fluidised bed is described. Products composition from isobare adiabatic combustion of selected explosives has been calculated and correlated with previous calculations for a detonation regime. The obtained results demonstrate the possibility of predicting gas composition of detonation and combustion products of industrial explosives. 22 refs., 14 figs., 1 tab.

Explosively formed fuse opening switches for use in flux-compression generator circuits

International Nuclear Information System (INIS)

Goforth, J.H.; Marsh, S.P.

1990-01-01

Explosive-driven magnetic flux compression generators (explosive generators) provide for the generation of large amounts of energy compactly stored in a magnetic field. Opening switches for use in explosive generator circuits allow the energy to be used for applications requiring higher power than can be developed by the generators themselves. The authors have developed a type of opening switch that they describe as an explosively formed fuse (EEF). These switches are well suited to explosive generator circuits and provide a considerable enhancement of explosive pulsed-power capability. The authors first experiments with explosively formed fuses occurred while attempting to utilize the enhanced pressure developed in the high-pressure interaction between two detonation fronts. In these tests they attempted to use the interaction to sever conducting plates along lines perpendicular to current flow. The technique worked to some extent, and to ascertain how much advantage was gained from the high-pressure interaction, they substituted an areal detonation in place of the discrete lines required to produce lines of interaction. This paper describes the authors development effort, the state of the art, and the different manifestations of their technique

Advances in neutron based bulk explosive detection

Science.gov (United States)

Gozani, Tsahi; Strellis, Dan

2007-08-01

Neutron based explosive inspection systems can detect a wide variety of national security threats. The inspection is founded on the detection of characteristic gamma rays emitted as the result of neutron interactions with materials. Generally these are gamma rays resulting from thermal neutron capture and inelastic scattering reactions in most materials and fast and thermal neutron fission in fissile (e.g.235U and 239Pu) and fertile (e.g.238U) materials. Cars or trucks laden with explosives, drugs, chemical agents and hazardous materials can be detected. Cargo material classification via its main elements and nuclear materials detection can also be accomplished with such neutron based platforms, when appropriate neutron sources, gamma ray spectroscopy, neutron detectors and suitable decision algorithms are employed. Neutron based techniques can be used in a variety of scenarios and operational modes. They can be used as stand alones for complete scan of objects such as vehicles, or for spot-checks to clear (or validate) alarms indicated by another inspection system such as X-ray radiography. The technologies developed over the last two decades are now being implemented with good results. Further advances have been made over the last few years that increase the sensitivity, applicability and robustness of these systems. The advances range from the synchronous inspection of two sides of vehicles, increasing throughput and sensitivity and reducing imparted dose to the inspected object and its occupants (if any), to taking advantage of the neutron kinetic behavior of cargo to remove systematic errors, reducing background effects and improving fast neutron signals.

Associated-particle sealed-tube neutron probe: Detection of explosives, contraband, and nuclear materials

International Nuclear Information System (INIS)

Rhodes, E.; Dickerman, C.E.

1996-01-01

Continued research and development of the APSTNG shows the potential for practical field use of this technology for detection of explosives, contraband, and nuclear materials. The APSTNG (associated-particle sealed-tube generator) inspects the item to be examined using penetrating 14-MeV neutrons generated by the deuterium-tritium reaction inside a compact accelerator tube. An alpha detector built into the sealed tube detects the alpha-particle associated with each neutron emitted in a cone encompassing the volume to be inspected. Penetrating high-energy gamma-rays from the resulting neutron reactions identify specific nuclides inside the volume. Flight-times determined from the detection times of gamma-rays and alpha-particles separate the prompt and delayed gamma-ray spectra and allow a coarse 3-D image to be obtained of nuclides identified in the prompt spectrum. The generator and detectors can be on the same side of the inspected object, on opposite sides, or with intermediate orientations. Thus, spaces behind walls and other confined regions can be inspected. Signals from container walls can be discriminated against using the flight-time technique. No collimators or shielding are required, the neutron generator is relatively small, and commercial-grade electronics are employed. The use of 14-MeV neutrons yields a much higher cross-section for detecting nitrogen than that for systems based on thermal-neutron reactions alone, and the broad range of elements with significant 14-MeV neutron cross-sections extends explosives detection to other elements including low-nitrogen compounds, and allows detection of many other substances. Proof-of-concept experiments have been successfully performed for conventional explosives, chemical warfare agents, cocaine, and fissionable materials

Explosive compaction of aluminum oxide modified by multiwall carbon nanotubes

Science.gov (United States)

Buzyurkin, A. E.; Kraus, E. I.; Lukyanov, Ya L.

2018-04-01

This paper presents experiments and numerical research on explosive compaction of aluminum oxide powder modified by multiwall carbon nanotubes (MWCNT) and modeling of the stress state behind the shock front at shock loading. The aim of this study was to obtain a durable low-porosity compact sample. The explosive compaction technology is used in this problem because the aluminum oxide is an extremely hard and refractory material. Therefore, its compaction by traditional methods requires special equipment and considerable expenses.

Performance calculations on the ANFO explosive RX-HD

Energy Technology Data Exchange (ETDEWEB)

Souers, P.C.; Larson, D.B.; Tarver, C.M.

1994-12-31

This report presents the calculation methods utilized in asessing the detonation performance of the ammonium nitrate-fuel oil (ANFO) utilized in the non-proliferation experiment (NPE) underground explosion at te Nevada Test Site. The composition of the ANFO is discussed.

On the fallout by nuclear explosion experiment and the radioactive iodine in animal organism

International Nuclear Information System (INIS)

Tanaka, Giichiro

1974-01-01

Radioactive iodine (mainly 131 I, 132 I, 133 I, and 135 I) was measured with fallout, cow milk, human urine, and thyroid glands (human and cattles) after the first nuclear explosion experiment in China. Analysing method was determined by placing emphasis on rapidity and perfect separation from other nuclides. The detectable limit employing this method was about several p Ci. The identification of radioactive iodine was performed with a simultaneous counting type β - ray spectrometer, and 131 I, 132 I, and 133 I were identified by their half lives. 131 I in cow milk increased from around the 4th day after the experiment, and it had been detected for a month continuously, the maximum amount being 437 p Ci/l. In thyroid glands, 131 I was detected for 100 days in a milch cow, the maximum being 88, 1p Ci/g, while it was somewhat low in Japanese cows and pigs. 131 I in the thyroid gland of a human infant (accidentally died after 12 days) was 1.29p Ci/g. 131 I in human urine was 6.3p Ci/l on the 7th day. (Kobatake, H.)

Aspects regarding explosion risk assessment

Directory of Open Access Journals (Sweden)

Părăian Mihaela

2017-01-01

Full Text Available Explosive risk occurs in all activities involving flammable substances in the form of gases, vapors, mists or dusts which, in mixture with air, can generate an explosive atmosphere. As explosions can cause human losses and huge material damage, the assessment of the explosion risk and the establishment of appropriate measures to reduce it to acceptable levels according to the standards and standards in force is of particular importance for the safety and health of people and goods.There is no yet a recognized method of assessing the explosion risk, but regardless of the applied method, the likelihood of an explosive atmosphere occurrence has to be determined, together with the occurrence of an efficient ignition source and the magnitude of foreseeable consequences. In assessment processes, consequences analysis has a secondary importance since it’s likely that explosions would always involve considerable damage, starting from important material damages and up to human damages that could lead to death.The purpose of the work is to highlight the important principles and elements to be taken into account for a specific risk assessment. An essential element in assessing the risk of explosion in workplaces where explosive atmospheres may occur is technical installations and personal protective equipment (PPE that must be designed, manufactured, installed and maintained so that they cannot generate a source of ignition. Explosion prevention and protection requirements are governed by specific norms and standards, and a main part of the explosion risk assessment is related to the assessment of the compliance of the equipment / installation with these requirements.

Thermal properties of andesite from Popocatepetl and Volcán de Colima, México.

Science.gov (United States)

Cardenas-Sanchez, Enrique; De la Cruz-Reina, Servando; Varley, Nick

2015-04-01

The thermal conductivity (K), specific heat (Cp) and the coefficient of heat transfer surface (H) are the basic parameters to describe the process of cooling a volcanic rock fragment released in an explosive event. The analysis of the cooling process by conduction, convection and radiation of heat in volcanic rock fragments, has been limited to basalts, and various minerals such as olivine, pyroxene, quartz, etc. (Miao & Chen, 2014; Branlund & Hofmeister, 2012; Romine et al, 2012;. Schön, 2011; Stroberg et al, 2010;. Schatz & Simmons, 1972). There are no detailed studies on the thermal properties of the andesites, abundant in continental stratovolcanoes, and particularly susceptible from lava domes with frequent destruction processes, such as Popocatepetl and Volcan de Colima. Previously, we developed an algorithm for calculation of the grain-size distribution, degree of fragmentation, the thermal energy released and its possible correlation with Volcanic Explosive Index (VEI) from the cooling curves of fragments from vulcanian and strombolian explosions. These curves were obtained from sequences of time over incandescent deposits recorded at selected pixel thermal images of vulcanian activity in the Popocatepetl and Volcan de Colima, Mexico. However, the model was limited by the lack of thermal parameters of the andesites, forcing a first approximation using basalts data. We present a simple model for the cooling process using andesites samples from Popocatépetl and Volcan de Colima. First, the samples were subjected to a rounding process to minimize surface effects. Then, heated to 800 ° C were extracted from the muffle and cooling rate is measured. The thermal conductivity and coefficient of surface heat are determined using a thermal camera and three thermocouples embedded at various depths within the sample. An inversion method was implemented to determine the thermal properties parameters , by comparing the observed data regarding cooling model for a solid

Numerical modelling of the effect of using multi-explosives on the explosive forming of steel cones

OpenAIRE

De Vuyst, T; Kong, K; Djordjevic, N; Vignjevic, R; Campbell, JC; Hughes, K

2016-01-01

Modelling and analysis of underwater explosive forming process by using FEM and SPH formulation is presented in this work. The explosive forming of a steel cone is studied. The model setup includes a low carbon steel plate, plate holder, forming die as well as water and C4 explosive. The effect of multiple explosives on rate of targets deformation has been studied. Four different multi-explosives models have been developed and compared to the single explosive model. The formability of the ste...

Experiments on thermal conductivity in buffer materials for geologic repository

International Nuclear Information System (INIS)

Kanno, T.; Yano, T.; Wakamatsu, H.; Matsushima, E.

1989-01-01

Engineered barriers for geologic disposal for HLW are planned to consist of canister, overpack and buffer elements. One of important physical characteristics of buffer materials is determining temperature profiles within the near field in a repository. Buffer materials require high thermal conductivity to disperse radiogenic heat away to the host rock. As the buffer materials, compacted blocks of the mixture of sodium bentonite and sand have been the most promising candidate in some countries, e.g. Sweden, Switzerland and Japan. The authors have been carrying out a series of thermal dispersion experiments to evaluate thermal conductivity of bentonite/quartz sand blocks. In this study, the following two factors considered to affect thermal properties of the near field were examined: effective thermal conductivities of buffer materials, and heat transfer characteristics of the gap between overpack and buffer materials

Calorimetric studies and lessons on fires and explosions of a chemical plant producing CHP and DCPO

International Nuclear Information System (INIS)

Hsu, Jing-Ming; Su, Mao-Sheng; Huang, Chiao-Ying; Duh, Yih-Shing

2012-01-01

Highlights: ► We analyzed fire and explosion incidents in a plant producing CHP and DCPO. ► Data from calorimeters reveal causes and phenomena associated with the incidents. ► The credible worst scenario was thermal explosion. ► Incidents may be avoided by implementing DIERS methodology. - Abstract: Cumene hydroperoxide (CHP) has been used in producing phenol, dicumyl peroxide (DCPO) and as an initiator for synthesizing acrylonitrile–butadiene–styrene (ABS) resin by copolymerization in Taiwan. Four incidents of fire and explosion induced by thermal runaway reactions were occurred in a same plant producing CHP, DCPO and bis-(tert-butylperoxy isopropyl) benzene peroxide (BIBP). The fourth fire and explosion occurred in the CHP reactor that resulted in a catastrophic damage in reaction region and even spread throughout storage area. Descriptions on the occurrences of these incidents were assessed by the features of processes, reaction schemes and unexpected side reactions. Calorimetric data on thermokinetics and pressure were used for explaining the practical consequences or which the worst cases encountered in this kind of plant. Acceptable risk associated with emergency relief system design is vital for a plant producing organic peroxide. These basic data for designing an inherently safer plant can be conducted from adiabatic calorimetry. An encouraging deduction has been drawn here, these incidents may be avoided by the implementation of API RP 520, API RP 521, DIERS technology, OSHA 1910.119 and AIChE's CCPS recommended PSM elements.

Effects of frustration on explosive synchronization

Science.gov (United States)

Huang, Xia; Gao, Jian; Sun, Yu-Ting; Zheng, Zhi-Gang; Xu, Can

2016-12-01

In this study, we consider the emergence of explosive synchronization in scale-free networks by considering the Kuramoto model of coupled phase oscillators. The natural frequencies of oscillators are assumed to be correlated with their degrees and frustration is included in the system. This assumption can enhance or delay the explosive transition to synchronization. Interestingly, a de-synchronization phenomenon occurs and the type of phase transition is also changed. Furthermore, we provide an analytical treatment based on a star graph, which resembles that obtained in scale-free networks. Finally, a self-consistent approach is implemented to study the de-synchronization regime. Our findings have important implications for controlling synchronization in complex networks because frustration is a controllable parameter in experiments and a discontinuous abrupt phase transition is always dangerous in engineering in the real world.

Historical Survey: German Research on Hydrogen Peroxide/Alcohol Explosives

Energy Technology Data Exchange (ETDEWEB)

Parmeter, John E. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

2015-01-01

Discussion of HP/fuel explosives in the scientific literature dates back to at least 1927. A paper was published that year in a German journal entitled On Hydrogen Peroxide Explosives [Bamberger and Nussbaum 1927]. The paper dealt with HP/cotton/Vaseline formulations, specifically HP89/cotton/Vaseline (76/15/9) and (70/8.5/12.5). The authors performed experiments with charge masses of 250-750 g and charge diameters of 35-45 mm. This short paper provides brief discussion on the observed qualitative effects of detonations but does not report detonation velocities.

Seismic Methods of Identifying Explosions and Estimating Their Yield

Science.gov (United States)

Walter, W. R.; Ford, S. R.; Pasyanos, M.; Pyle, M. L.; Myers, S. C.; Mellors, R. J.; Pitarka, A.; Rodgers, A. J.; Hauk, T. F.

2014-12-01

Seismology plays a key national security role in detecting, locating, identifying and determining the yield of explosions from a variety of causes, including accidents, terrorist attacks and nuclear testing treaty violations (e.g. Koper et al., 2003, 1999; Walter et al. 1995). A collection of mainly empirical forensic techniques has been successfully developed over many years to obtain source information on explosions from their seismic signatures (e.g. Bowers and Selby, 2009). However a lesson from the three DPRK declared nuclear explosions since 2006, is that our historic collection of data may not be representative of future nuclear test signatures (e.g. Selby et al., 2012). To have confidence in identifying future explosions amongst the background of other seismic signals, and accurately estimate their yield, we need to put our empirical methods on a firmer physical footing. Goals of current research are to improve our physical understanding of the mechanisms of explosion generation of S- and surface-waves, and to advance our ability to numerically model and predict them. As part of that process we are re-examining regional seismic data from a variety of nuclear test sites including the DPRK and the former Nevada Test Site (now the Nevada National Security Site (NNSS)). Newer relative location and amplitude techniques can be employed to better quantify differences between explosions and used to understand those differences in term of depth, media and other properties. We are also making use of the Source Physics Experiments (SPE) at NNSS. The SPE chemical explosions are explicitly designed to improve our understanding of emplacement and source material effects on the generation of shear and surface waves (e.g. Snelson et al., 2013). Finally we are also exploring the value of combining seismic information with other technologies including acoustic and InSAR techniques to better understand the source characteristics. Our goal is to improve our explosion models

Analysis and modeling of flow-blockage-induced steam explosion events in the high-flux isotope reactor

International Nuclear Information System (INIS)

Taleyarkhan, R.P.; Georgevich, V.; Nestor, C.W.; Gat, U.; Lepard, B.L.; Cook, D.H.; Freels, J.; Chang, S.J.; Luttrell, C.; Gwaltney, R.C.

1994-01-01

This article provides a perspective overview of the analysis and modeling work done to evaluate the threat from steam explosion loads in the High-Flux Isotope Reactor (HFIR) during flow blockage events. The overall work scope included modeling and analysis of core-melt initiation, melt propagation, bounding and best-estimate steam explosion energetics, vessel failure from fracture, bolts failure from exceedance of elastic limits, and, finally, missile evolution and transport. Aluminum ignition was neglected. Evaluations indicated that a thermally driven steam explosion with more than 65 MJ of energy insertion in the core region over several milliseconds would be needed to cause a sufficiently energetic missile with a capacity to cause early confinement failure. This amounts to about 65% of the HFIR core mass melting and participating in a steam explosion. Conservative melt propagation analyses have indicated that at most only 24% of the HFIR core mass could melt during flow blockage events under full-power conditions. 19 refs., 11 figs

Does Thermal Granulation Drive Tephra Jets?

Science.gov (United States)

White, J. D.; Zimanowski, B.; Buettner, R.; Sonder, I.; Dellino, P.

2011-12-01

Surtseyan tephra jets, also called cypressoid or cock's tail plumes, comprise a characteristic mixture of ash with bombs travelling roughly ballistic paths that tip the individual fingers of the projecting jet. Jets of similar form but smaller scale are generated by littoral magma-water interactions, confirming the general inference that surtseyan tephra jets are a characteristic product of explosive magma-water interaction, and suggesting that magmatic volatiles play a subsidiary role, if any, in their formation. Surtseyan jets have been inferred to result from both intense fuel-coolant interactions, and from simple boiling of water entrained into rising magma, and little new information has become available to test these two positions since they were clearly developed in the 1980s. Recent experiments in which magma is poured into standing water have produced vigorous jetting of hot water as melt solidifies and undergoes extensive thermal granulation. We present high-resolution hi-speed video of these jets, which we see as having the following origin. As thermal granulation takes place, a fracture network advances into the melt/glass body, and water invading the cracks at the rate of propagation is heated nearly instantaneously. Vapor produced at the contact expands and drives outward through cooled cracks, condensing as it moves to the exterior of the magma body where it is emitted as a jet of hot water. In ocean ridge hydrothermal systems a diffuse crack network inducts cold water, which is heated and expelled in focused jets. Focusing of hot outflow in experiments is inferred to result, as suggested for ridge hydrothermal systems, from thermoelastic closure of cracks near the one(s) feeding the jet. From the cooled products of our experimental runs, we know that thermal contraction produces a network of curved cracks with modal spacing of 1-2 mm, which separate domains of unbroken glass. It is during growth of this crack network that cold water enters, is

Innovative nuclear thermal propulsion technology evaluation: Results of the NASA/DOE Task Team study

International Nuclear Information System (INIS)

Howe, S.; Borowski, S.; Helms, I.; Diaz, N.; Anghaie, S.; Latham, T.

1991-01-01

In response to findings from two NASA/DOE nuclear propulsion workshops held in the summer of 1990, six task teams were formed to continue evaluation of various nuclear propulsion concepts. The Task Team on Nuclear Thermal Propulsion (NTP) created the Innovative Concepts Subpanel to evaluate thermal propulsion concepts which did not utilize solid fuel. The Subpanel endeavored to evaluate each of the concepts on a ''level technological playing field,'' and to identify critical technologies, issues, and early proof-of-concept experiments. The concepts included the liquid core fission, the gas core fission, the fission foil reactors, explosively driven systems, fusion, and antimatter. The results of the studies by the panel will be provided. 13 refs., 6 figs., 2 tabs

Frictional properties of single crystals HMX, RDX and PETN explosives

International Nuclear Information System (INIS)

Wu, Y.Q.; Huang, F.L.

2010-01-01

The frictional properties of single crystals of cyclotetramethylene tetranitramine (HMX), cyclotrimethylene trinitramine (RDX) and pentaerythritol tetranitrate (PETN) secondary explosives are examined using a sensitive friction machine. The explosive crystals used for the measurements are at least 3.5 mm wide. The friction coefficients between crystals of the same explosive (i.e., HMX on HMX, etc.), crystals of different explosives (i.e., HMX on RDX, etc.), and each explosive and a well-polished gauge steel surface are determined. The frictional surfaces are also studied under an environmental scanning electron microscope (ESEM) to analyze surface microstructural changes under increasing loading forces. The friction coefficients vary considerably with increasing normal loading forces and are particularly sensitive to slider shapes, crystal roughness and the mechanical properties of both the slider and the sample. With increasing loading forces, most friction experiments show surface damage, consisting of grooves, debris, and nano-particles, on both the slider and sample. In some cases, a strong evidence of a localized molten state is found in the central region of the friction track. Possible mechanisms that affect the friction coefficient are discussed based on microscopic observations.

An Experimental Study on the Dynamics of a Single Droplet Vapor Explosion

International Nuclear Information System (INIS)

Concilio Hansson, Roberta

2010-01-01

The present study aims to develop a mechanistic understanding of the thermal-hydraulic processes in a vapor explosion, which may occur in nuclear power plants during a hypothetical severe accident involving interactions of high-temperature corium melt and volatile coolant. Over the past several decades, a large body of literature has been accumulated on vapor explosion phenomenology and methods for assessment of the related risk. Vapor explosion is driven by a rapid fragmentation of high temperature melt droplets, leading to a substantial increase of heat transfer areas and subsequent explosive evaporation of the volatile coolant. Constrained by the liquid-phase coolant, the rapid vapor production in the interaction zone causes pressurization and dynamic loading on surrounding structures. While such a general understanding has been established, the triggering mechanism and subsequent dynamic fine fragmentation have yet not been clearly understood. A few mechanistic fragmentation models have been proposed, however, computational efforts to simulate the phenomena generated a large scatter of results. Dynamics of the hot liquid (melt) droplet and the volatile liquid (coolant) are investigated in the MISTEE (Micro-Interactions in Steam Explosion Experiments) facility by performing well-controlled, externally triggered, single-droplet experiments, using a high-speed visualization system with synchronized digital cinematography and continuous X-ray radiography, called SHARP (Simultaneous High-speed Acquisition of X-ray Radiography and Photography). After an elaborate image processing, the SHARP images depict the evolution of both melt material (dispersal) and coolant (bubble dynamics), and their microscale interactions, i.e. the triggering phenomenology. The images point to coolant entrainment into the droplet surface as the mechanism for direct contact/mixing ultimately responsible for energetic interactions. Most importantly, the MISTEE data reveals an inverse

An Experimental Study on the Dynamics of a Single Droplet Vapor Explosion

Energy Technology Data Exchange (ETDEWEB)

Concilio Hansson, Roberta

2010-07-01

The present study aims to develop a mechanistic understanding of the thermal-hydraulic processes in a vapor explosion, which may occur in nuclear power plants during a hypothetical severe accident involving interactions of high-temperature corium melt and volatile coolant. Over the past several decades, a large body of literature has been accumulated on vapor explosion phenomenology and methods for assessment of the related risk. Vapor explosion is driven by a rapid fragmentation of high temperature melt droplets, leading to a substantial increase of heat transfer areas and subsequent explosive evaporation of the volatile coolant. Constrained by the liquid-phase coolant, the rapid vapor production in the interaction zone causes pressurization and dynamic loading on surrounding structures. While such a general understanding has been established, the triggering mechanism and subsequent dynamic fine fragmentation have yet not been clearly understood. A few mechanistic fragmentation models have been proposed, however, computational efforts to simulate the phenomena generated a large scatter of results. Dynamics of the hot liquid (melt) droplet and the volatile liquid (coolant) are investigated in the MISTEE (Micro-Interactions in Steam Explosion Experiments) facility by performing well-controlled, externally triggered, single-droplet experiments, using a high-speed visualization system with synchronized digital cinematography and continuous X-ray radiography, called SHARP (Simultaneous High-speed Acquisition of X-ray Radiography and Photography). After an elaborate image processing, the SHARP images depict the evolution of both melt material (dispersal) and coolant (bubble dynamics), and their microscale interactions, i.e. the triggering phenomenology. The images point to coolant entrainment into the droplet surface as the mechanism for direct contact/mixing ultimately responsible for energetic interactions. Most importantly, the MISTEE data reveals an inverse

SUPERFUND TREATABILITY CLEARINGHOUSE: INCINERATION TEST OF EXPLOSIVES CONTAMINATED SOILS AT SAVANNA ARMY DEPOT ACTIVITY, SAVANNA, ILLINOIS

Science.gov (United States)

The primary objective of these tests was to demonstrate the effectiveness of incineration as a decontamination method for explosives contaminated sails. A pilot-scale rotary kiln incinerator, manufactured by ThermAll, Inc., was used to treat both sandy and clayey...

Tracing explosive in solvent using quantum cascade laser with pulsed electric discharge system

Energy Technology Data Exchange (ETDEWEB)

Park, Seong-Wook; Tian, Chao; Martini, Rainer, E-mail: rmartini@stevens.edu [Department of Physics and Engineering Physics, Stevens Institute of Technology, 1 Castle Point on Hudson, Hoboken, New Jersey 07030 (United States); Chen, Gang [School of Optoelectronic Engineering, Chongqing University, Chongqing 400044 (China); Chen, I-chun Anderson [Newport Corporation/Oriel Instruments, 150 Long Beach Boulevard, Stratford, Connecticut 06615 (United States)

2014-11-03

We demonstrated highly sensitive detection of explosive dissolved in solvent with a portable spectroscopy system (Q-MACS) by tracing the explosive byproduct, N{sub 2}O, in combination with a pulsed electric discharge system for safe explosive decomposition. Using Octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX), the gas was monitored and analyzed by Q-MACS and the presence of the dissolved explosive clearly detected. While HMX presence could be identified directly in the air above the solutions even without plasma, much better results were achieved under the decomposition. The experiment results give an estimated detection limit of 10 ppb, which corresponds to a 15 pg of HMX.

Tracing explosive in solvent using quantum cascade laser with pulsed electric discharge system

International Nuclear Information System (INIS)

Park, Seong-Wook; Tian, Chao; Martini, Rainer; Chen, Gang; Chen, I-chun Anderson

2014-01-01

We demonstrated highly sensitive detection of explosive dissolved in solvent with a portable spectroscopy system (Q-MACS) by tracing the explosive byproduct, N 2 O, in combination with a pulsed electric discharge system for safe explosive decomposition. Using Octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX), the gas was monitored and analyzed by Q-MACS and the presence of the dissolved explosive clearly detected. While HMX presence could be identified directly in the air above the solutions even without plasma, much better results were achieved under the decomposition. The experiment results give an estimated detection limit of 10 ppb, which corresponds to a 15 pg of HMX

Large-scale thermal-shock experiments with clad and unclad steel cylinders

International Nuclear Information System (INIS)

Cheverton, R.D.

1992-01-01

Flaw behavior trends associated with pressurized-thermal-shock (PTS) loading of pressurized-water-reactor pressure vessels have been under investigation at the Oak Ridge National Laboratory for nearly 20 years. During that time, twelve thermal-shock experiments with thick-walled (152 mm) steel cylinders were conducted as a part of the investigations. The first eight experiments were conducted with unclad cylinders initially containing shallow (8--19 mm) two-dimensional and semicircular inner-surface flaws. These experiments demonstrated, in good agreement with linear elastic fracture mechanics, crack initiation and arrest, a series of initiation/arrest events with deep penetration of the wall, long crack jumps, arrest with the stress intensity factor (K I ) increasing with crack depth, extensive surface extension of an initially short and shallow (semicircular) flaw, and warm prestressing with K I ≤ 0. The remaining four experiments were conducted with clad cylinders containing initially shallow (19--24 mm) semielliptical subclad and surface flaws at the inner surface. In the first of these experiments one of six equally spaced (60 degrees) open-quotes identicalclose quotes subclad flaws extended nearly the length of the cylinder (1,220 mm) beneath the cladding (no crack extension into the cladding) and nearly 50% of the wall, radially. For the final experiment, four of the semielliptical subclad flaws that had not propagated previously were converted to surface flaws, and they experienced extensive extension beneath the cladding with no cracking of the cladding. Information from this series of thermal-shock experiments is being used in the evaluation of the PTS issue

Detection of chemical explosives using multiple photon signatures

International Nuclear Information System (INIS)

Loschke, K.W.; Dunn, W.L.

2008-01-01

Full text: A template-matching procedure to aid in rapid detection of improvised explosive devices (IEDs) is being investigated. Multiple photon-scattered and photon-induced positron annihilation radiation responses are being used as part of a photon-neutron signature-based radiation scanning (SBRS) approach (see companion reference for description of the neutron component), in an attempt to detect chemical explosives at safe standoff distances. Many past and present photon interrogation methods are based on imaging. Imaging techniques seek to determine at high special resolution the internal structure of a target of interest. Our technique simply seeks to determine if an unknown target contains a detectable amount of chemical explosives by comparing multiple responses (signatures) that depend on both density and composition of portions of a target. In the photon component, beams of photons are used to create back-streaming signatures, which are dependent on the density and composition of part of the target being interrogated. These signatures are compared to templates, which are collections of the same signatures if the interrogated volume contained a significant amount of explosives. The signature analysis produces a figure-of-merit and a standard deviation of the figure-of-merit. These two metrics are used to filter safe from dangerous targets. Experiments have been conducted that show that explosive surrogates (fertilizers) can be distinguished from several inert materials using these photon signatures, demonstrating that these signatures can be used effectively to help IEDs

High-speed imaging of explosive eruptions: applications and perspectives

Science.gov (United States)

Taddeucci, Jacopo; Scarlato, Piergiorgio; Gaudin, Damien; Capponi, Antonio; Alatorre-Ibarguengoitia, Miguel-Angel; Moroni, Monica

2013-04-01

Explosive eruptions, being by definition highly dynamic over short time scales, necessarily call for observational systems capable of relatively high sampling rates. "Traditional" tools, like as seismic and acoustic networks, have recently been joined by Doppler radar and electric sensors. Recent developments in high-speed camera systems now allow direct visual information of eruptions to be obtained with a spatial and temporal resolution suitable for the analysis of several key eruption processes. Here we summarize the methods employed to gather and process high-speed videos of explosive eruptions, and provide an overview of the several applications of these new type of data in understanding different aspects of explosive volcanism. Our most recent set up for high-speed imaging of explosive eruptions (FAMoUS - FAst, MUltiparametric Set-up,) includes: 1) a monochrome high speed camera, capable of 500 frames per second (fps) at high-definition (1280x1024 pixel) resolution and up to 200000 fps at reduced resolution; 2) a thermal camera capable of 50-200 fps at 480-120x640 pixel resolution; and 3) two acoustic to infrasonic sensors. All instruments are time-synchronized via a data logging system, a hand- or software-operated trigger, and via GPS, allowing signals from other instruments or networks to be directly recorded by the same logging unit or to be readily synchronized for comparison. FAMoUS weights less than 20 kg, easily fits into four, hand-luggage-sized backpacks, and can be deployed in less than 20' (and removed in less than 2', if needed). So far, explosive eruptions have been recorded in high-speed at several active volcanoes, including Fuego and Santiaguito (Guatemala), Stromboli (Italy), Yasur (Vanuatu), and Eyjafiallajokull (Iceland). Image processing and analysis from these eruptions helped illuminate several eruptive processes, including: 1) Pyroclasts ejection. High-speed videos reveal multiple, discrete ejection pulses within a single Strombolian

A new approach to designing reduced scale thermal-hydraulic experiments

International Nuclear Information System (INIS)

Lapa, Celso M.F.; Sampaio, Paulo A.B. de; Pereira, Claudio M.N.A.

2004-01-01

Reduced scale experiments are often employed in engineering because they are much cheaper than real scale testing. Unfortunately, though, it is difficult to design a thermal-hydraulic circuit or equipment in reduced scale capable of reproducing, both accurately and simultaneously, all the physical phenomena that occur in real scale and operating conditions. This paper presents a methodology to designing thermal-hydraulic experiments in reduced scale based on setting up a constrained optimization problem that is solved using genetic algorithms (GAs). In order to demonstrate the application of the methodology proposed, we performed some investigations in the design of a heater aimed to simulate the transport of heat and momentum in the core of a pressurized water reactor (PWR) at 100% of nominal power and non-accident operating conditions. The results obtained show that the proposed methodology is a promising approach for designing reduced scale experiments

COMMIX analysis of four constant flow thermal upramp experiments performed in a thermal hydraulic model of an advanced LMR

International Nuclear Information System (INIS)

Yarlagadda, B.S.

1989-04-01

The three-dimensional thermal hydraulics computer code COMMIX-1AR was used to analyze four constant flow thermal upramp experiments performed in the thermal hydraulic model of an advanced LMR. An objective of these analyses was the validation of COMMIX-1AR for buoyancy affected flows. The COMMIX calculated temperature histories of some thermocouples in the model were compared with the corresponding measured data. The conclusions of this work are presented. 3 refs., 5 figs

Dynamic Fracture Simulations of Explosively Loaded Cylinders

Energy Technology Data Exchange (ETDEWEB)

Arthur, Carly W. [Univ. of California, Davis, CA (United States). Dept. of Civil and Environmental Engineering; Goto, D. M. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

2015-11-30

This report documents the modeling results of high explosive experiments investigating dynamic fracture of steel (AerMet® 100 alloy) cylinders. The experiments were conducted at Lawrence Livermore National Laboratory (LLNL) during 2007 to 2008 [10]. A principal objective of this study was to gain an understanding of dynamic material failure through the analysis of hydrodynamic computer code simulations. Two-dimensional and three-dimensional computational cylinder models were analyzed using the ALE3D multi-physics computer code.

General phenomenology of underground nuclear explosions

International Nuclear Information System (INIS)

Derlich, S.; Supiot, F.

1969-01-01

An essentially qualitatively description is given of the phenomena related to underground nuclear explosions (explosion of a single unit, of several units in line, and simultaneous explosions). In the first chapter are described the phenomena which are common to contained explosions and to explosions forming craters (formation and propagation of a shock-wave causing the vaporization, the fusion and the fracturing of the medium). The second chapter describes the phenomena related to contained explosions (formation of a cavity with a chimney). The third chapter is devoted to the phenomenology of test explosions which form a crater; it describes in particular the mechanism of formation and the different types of craters as a function of the depth of the explosion and of the nature of the ground. The aerial phenomena connected with explosions which form a crater: shock wave in the air and focussing at a large distance, and dust clouds, are also dealt with. (authors) [fr

30 CFR 77.307 - Thermal dryers; location and installation; general.

Science.gov (United States)

2010-07-01

... where the heat, sparks, flames, or coal dust from the system might cause a fire or explosion. (b... LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS, SURFACE COAL MINES AND SURFACE WORK AREAS OF UNDERGROUND COAL MINES Thermal Dryers § 77.307 Thermal dryers; location and installation; general...

Sensitivities of ionic explosives

Science.gov (United States)

Politzer, Peter; Lane, Pat; Murray, Jane S.

2017-03-01

We have investigated the relevance for ionic explosive sensitivity of three factors that have been demonstrated to be related to the sensitivities of molecular explosives. These are (1) the maximum available heat of detonation, (2) the amount of free space per molecule (or per formula unit) in the crystal lattice and (3) specific features of the electrostatic potential on the molecular or ionic surface. We find that for ionic explosives, just as for molecular ones, there is an overall tendency for impact sensitivity to increase as the maximum detonation heat release is greater. This means that the usual emphasis upon designing explosives with large heats of detonation needs to be tempered somewhat. We also show that a moderate detonation heat release does not preclude a high level of detonation performance for ionic explosives, as was already demonstrated for molecular ones. Relating the free space per formula unit to sensitivity may require a modified procedure for ionic explosives; this will continue to be investigated. Finally, an encouraging start has been made in linking impact sensitivities to the electrostatic potentials on ionic surfaces, although limited so far to ammonium salts.

Preliminary Analysis of Ex-Vessel Steam Explosion using TEXAS-V code for APR1400

International Nuclear Information System (INIS)

Song, Sung Chu; Lee, Jung Jae; Cho, Yong Jin; Hwang, Taesuk

2013-01-01

The purpose of this study is to explore input development and the audit calculation using TEXAS-V code for ex-vessel steam explosion for a flooded reactor cavity of APR1400. TEXAS computational models are one of the simplified tools for simulations of fuel-coolant interaction during mixing, triggering and explosion phase. The models of TEXAS code were validated by performing the fundamental experimental investigation in the KROTOS facility at JRC, Ispra. The experiments such as KROTOS and FARO experiment are aimed at providing benchmark data to examine the effect of fuel-coolant initial conditions and mixing on explosion energetics with alumina and prototypical core material. TEXAS-V code used in this study was to analyze and predict the ex-vessel steam explosion for a reactor scale. The input deck to simulate the flooded reactor cavity of APR1400 is developed and base case calculation is performed. This study will provide a base for further study. The code will be of use for the evaluation and sensitivity study of ex-vessel steam explosion for ERVC strategy in the future studies. Analysis result of this study is similar to the result of other study. Through this study, it is found that TEXAS-V could be the used as a tool for predicting the steam explosion load on a reactor scale, as fast running computer code. In addition, TEXAS-V code could be to evaluate the impact of various uncertainties, which are not clearly understood yet, to provide a conservative envelope for the steam explosion

Preliminary Analysis of Ex-Vessel Steam Explosion using TEXAS-V code for APR1400

Energy Technology Data Exchange (ETDEWEB)

Song, Sung Chu; Lee, Jung Jae; Cho, Yong Jin; Hwang, Taesuk [Korea Institute of Nuclear Safety, Daejeon (Korea, Republic of)

2013-10-15

The purpose of this study is to explore input development and the audit calculation using TEXAS-V code for ex-vessel steam explosion for a flooded reactor cavity of APR1400. TEXAS computational models are one of the simplified tools for simulations of fuel-coolant interaction during mixing, triggering and explosion phase. The models of TEXAS code were validated by performing the fundamental experimental investigation in the KROTOS facility at JRC, Ispra. The experiments such as KROTOS and FARO experiment are aimed at providing benchmark data to examine the effect of fuel-coolant initial conditions and mixing on explosion energetics with alumina and prototypical core material. TEXAS-V code used in this study was to analyze and predict the ex-vessel steam explosion for a reactor scale. The input deck to simulate the flooded reactor cavity of APR1400 is developed and base case calculation is performed. This study will provide a base for further study. The code will be of use for the evaluation and sensitivity study of ex-vessel steam explosion for ERVC strategy in the future studies. Analysis result of this study is similar to the result of other study. Through this study, it is found that TEXAS-V could be the used as a tool for predicting the steam explosion load on a reactor scale, as fast running computer code. In addition, TEXAS-V code could be to evaluate the impact of various uncertainties, which are not clearly understood yet, to provide a conservative envelope for the steam explosion.

Nano-powder production by electrical explosion of wires

International Nuclear Information System (INIS)

Mao Zhiguo; Zou Xiaobing; Wang Xinxin; Jiang Weihua

2010-01-01

A device for nano-powder production by electrical explosion of wires was designed and built. Eight wires housed in the discharge chamber are exploded one by one before opening the chamber for the collection of the produced nano-powder. To increase the rate of energy deposition into a wire, the electrical behavior of the discharge circuit including the exploding wire was simulated. The results showed that both reducing the circuit inductance and reducing the capacitance of the energy-storage capacitor (keeping the storage energy constant) can increase the energy deposition rate. To better understand the physical processes of the nano-powder formation by the wire vapor, a Mach-Zehnder interferometer was used to record the time evolution of the wire vapor as well as the plasma. A thermal expansion lag of the dense vapor core as well as more than one times of the vapor burst was observed for the first time. Finally, nano-powders of titanium nitride, titanium dioxide, copper oxides and zinc oxide were produced by electrical explosion of wires. (authors)

Thermal Runaways in LHC Interconnections: Experiments

CERN Document Server

Willering, G P; Bottura, L; Scheuerlein, C; Verweij, A P

2011-01-01

The incident in the LHC in September 2008 occurred in an interconnection between two magnets of the 13 kA dipole circuit. This event was traced to a defect in one of the soldered joints between two superconducting cables stabilized by a copper busbar. Further investigation revealed defective joints of other types. A combination of (1) a poor contact between the superconducting cable and the copper stabilizer and (2) an electrical discontinuity in the stabilizer at the level of the connection can lead to an unprotected quench of the busbar. Once the heating power in the unprotected superconducting cable exceeds the heat removal capacity a thermal run-away occurs, resulting in a fast melt-down of the non-stabilized cable. We have performed a thorough investigation of the conditions upon which a thermal run-away in the defect can occur. To this aim, we have prepared heavily instrumented samples with well-defined and controlled defects. In this paper we describe the experiment, and the analysis of the data, and w...

Cell phone explosion.

Science.gov (United States)

Atreya, Alok; Kanchan, Tanuj; Nepal, Samata; Pandey, Bhuwan Raj

2016-03-01

Cell phone explosions and resultant burn injuries are rarely reported in the scientific literature. We report a case of cell phone explosion that occurred when a young male was listening to music while the mobile was plugged in for charging. © The Author(s) 2015.

Suppression of Vapor Explosions in a Water-Molten-Tin System by Augmentation of the Void Fraction

International Nuclear Information System (INIS)

Meeks, Michael K.; Baker, Michael C.; Bonazza, Riccardo

2000-01-01

Experiments were performed to determine the likelihood of a vapor explosion when injecting an inert gas (nitrogen) and a coolant (water) into a pool of molten metal (tin) in a large-scale chamber (∼20 kg fuel). The injection flow rates of the water and nitrogen gas were the principal experimental variables, with average water flow rates up to 0.05 x 10 -3 m 3 /s and gas flow rates ranging from 0.33 x 10 -3 to 1.67 x 10 -3 m 3 /s. Of 35 successful experiments, 11 resulted in an explosive interaction, as determined by audible signals, videotape, and accelerometer data. The main objective of the investigation was to determine the existence of a boundary between explosive and nonexplosive regions in the water-gas flow rate plane: Such a boundary was indeed identified and approximated by a straight line. Two experiments in which explosive interactions were obtained in the low water/gas flow regions after a relatively long time of coolant injection (∼5 to 10 s) demonstrate the hitherto undervalued importance of the temporal variable

A structured approach to forensic study of explosions: The TNO Inverse Explosion Analysis tool

NARCIS (Netherlands)

Voort, M.M. van der; Wees, R.M.M. van; Brouwer, S.D.; Jagt-Deutekom, M.J. van der; Verreault, J.

2015-01-01

Forensic analysis of explosions consists of determining the point of origin, the explosive substance involved, and the charge mass. Within the EU FP7 project Hyperion, TNO developed the Inverse Explosion Analysis (TNO-IEA) tool to estimate the charge mass and point of origin based on observed damage

Modelling of thermal shock experiments of carbon based materials in JUDITH

Science.gov (United States)

Ogorodnikova, O. V.; Pestchanyi, S.; Koza, Y.; Linke, J.

2005-03-01

The interaction of hot plasma with material in fusion devices can result in material erosion and irreversible damage. Carbon based materials are proposed for ITER divertor armour. To simulate carbon erosion under high heat fluxes, electron beam heating in the JUDITH facility has been used. In this paper, carbon erosion under energetic electron impact is modeled by the 3D thermomechanics code 'PEGASUS-3D'. The code is based on a crack generation induced by thermal stress. The particle emission observed in thermal shock experiments is a result of breaking bonds between grains caused by thermal stress. The comparison of calculations with experimental data from JUDITH shows good agreement for various incident power densities and pulse durations. A realistic mean failure stress has been found. Pre-heating of test specimens results in earlier onset of brittle destruction and enhanced particle loss in agreement with experiments.

Modelling of thermal shock experiments of carbon based materials in JUDITH

International Nuclear Information System (INIS)

Ogorodnikova, O.V.; Pestchanyi, S.; Koza, Y.; Linke, J.

2005-01-01

The interaction of hot plasma with material in fusion devices can result in material erosion and irreversible damage. Carbon based materials are proposed for ITER divertor armour. To simulate carbon erosion under high heat fluxes, electron beam heating in the JUDITH facility has been used. In this paper, carbon erosion under energetic electron impact is modeled by the 3D thermomechanics code 'PEGASUS-3D'. The code is based on a crack generation induced by thermal stress. The particle emission observed in thermal shock experiments is a result of breaking bonds between grains caused by thermal stress. The comparison of calculations with experimental data from JUDITH shows good agreement for various incident power densities and pulse durations. A realistic mean failure stress has been found. Pre-heating of test specimens results in earlier onset of brittle destruction and enhanced particle loss in agreement with experiments

Modelling of thermal shock experiments of carbon based materials in JUDITH

Energy Technology Data Exchange (ETDEWEB)

Ogorodnikova, O.V. [Forschungszentrum Juelich, EURATOM-Association, IWV-2, 52425 Juelich (Germany)]. E-mail: o.ogorodnikova@fz-juelich.de; Pestchanyi, S. [Forschungszentrum Karlsruhe, EURATOM-Associaton, IHM, 76021 Karlsruhe (Germany); Koza, Y. [Forschungszentrum Juelich, EURATOM-Association, IWV-2, 52425 Juelich (Germany); Linke, J. [Forschungszentrum Juelich, EURATOM-Association, IWV-2, 52425 Juelich (Germany)

2005-03-01

The interaction of hot plasma with material in fusion devices can result in material erosion and irreversible damage. Carbon based materials are proposed for ITER divertor armour. To simulate carbon erosion under high heat fluxes, electron beam heating in the JUDITH facility has been used. In this paper, carbon erosion under energetic electron impact is modeled by the 3D thermomechanics code 'PEGASUS-3D'. The code is based on a crack generation induced by thermal stress. The particle emission observed in thermal shock experiments is a result of breaking bonds between grains caused by thermal stress. The comparison of calculations with experimental data from JUDITH shows good agreement for various incident power densities and pulse durations. A realistic mean failure stress has been found. Pre-heating of test specimens results in earlier onset of brittle destruction and enhanced particle loss in agreement with experiments.

Additive model for thermal comfort generated by matrix experiment using orthogonal array

Energy Technology Data Exchange (ETDEWEB)

Hwang, Reuy-Lung [Department of Occupational Safety and Health, China Medical University, 91 Huseh-shin Road, Taichung 404 (China); Lin, Tzu-Ping [Department of Leisure Planning, National Formosa University, 64 Wen-hua Road, Huwei, Yunlin 632 (China); Liang, Han-Hsi [Department of Architecture, National United University, No. 1, Lien Da, Kung-Ching Li, Miaoli 360 (China); Yang, Kuan-Hsiug; Yeh, Tsung-Chyn [Department of Mechanical and Electro-Mechanical Engineering, National Sun Yet-Sen University, No. 91, Lien-hai Road, Kaohsiung (China)

2009-08-15

In addition to ensuring the thermal comfort of occupants, monitoring and controlling indoor thermal environments can reduce the energy consumed by air conditioning systems. This study develops an additive model for predicting thermal comfort with rapid and simple arithmetic calculations. The advantage of the additive model is its comprehensibility to administrators of air conditioning systems, who are unfamiliar with the PMV-PPD model but want to adjust an indoor environment to save energy without generating complaints of discomfort from occupants. In order to generate the additive model, a laboratory chamber experiment based on matrix experiment using orthogonal array, was performed. By applying the analysis of variance on observed thermal sensation votes and percentage of dissatisfaction, the factor effects of environmental variables that account for the additive model were determined. Additionally, the applicability of the PMV-PPD model in hot and humid climates is discussed in this study, based on experimental results. (author)

Calorimetric studies and lessons on fires and explosions of a chemical plant producing CHP and DCPO

Energy Technology Data Exchange (ETDEWEB)

Hsu, Jing-Ming; Su, Mao-Sheng; Huang, Chiao-Ying [Department of Occupational Safety and Health, Chia Nan University of Pharmacy and Science, Tainan, Taiwan, ROC (China); Duh, Yih-Shing, E-mail: yihshingduh@yahoo.com.tw [Department of Safety, Health and Environmental Engineering, National United University, No. 1 Lien-Da, Miaoli, Taiwan, ROC (China)

2012-05-30

Highlights: Black-Right-Pointing-Pointer We analyzed fire and explosion incidents in a plant producing CHP and DCPO. Black-Right-Pointing-Pointer Data from calorimeters reveal causes and phenomena associated with the incidents. Black-Right-Pointing-Pointer The credible worst scenario was thermal explosion. Black-Right-Pointing-Pointer Incidents may be avoided by implementing DIERS methodology. - Abstract: Cumene hydroperoxide (CHP) has been used in producing phenol, dicumyl peroxide (DCPO) and as an initiator for synthesizing acrylonitrile-butadiene-styrene (ABS) resin by copolymerization in Taiwan. Four incidents of fire and explosion induced by thermal runaway reactions were occurred in a same plant producing CHP, DCPO and bis-(tert-butylperoxy isopropyl) benzene peroxide (BIBP). The fourth fire and explosion occurred in the CHP reactor that resulted in a catastrophic damage in reaction region and even spread throughout storage area. Descriptions on the occurrences of these incidents were assessed by the features of processes, reaction schemes and unexpected side reactions. Calorimetric data on thermokinetics and pressure were used for explaining the practical consequences or which the worst cases encountered in this kind of plant. Acceptable risk associated with emergency relief system design is vital for a plant producing organic peroxide. These basic data for designing an inherently safer plant can be conducted from adiabatic calorimetry. An encouraging deduction has been drawn here, these incidents may be avoided by the implementation of API RP 520, API RP 521, DIERS technology, OSHA 1910.119 and AIChE's CCPS recommended PSM elements.

Plasma diagnostic techniques in thermal-barrier tandem-mirror fusion experiments

International Nuclear Information System (INIS)

Silver, E.H.; Clauser, J.F.; Carter, M.R.; Failor, B.H.; Foote, J.H.; Hornady, R.S.; James, R.A.; Lasnier, C.J.; Perkins, D.E.

1986-01-01

We review two classes of plasma diagnostic techniques used in thermal-barrier tandem-mirror fusion experiments. The emphasis of the first class is to study mirror-trapped electrons at the thermal-barrier location. The focus of the second class is to measure the spatial and temporal behavior of the plasma space potential at various axial locations. The design and operation of the instruments in these two categories are discussed and data that are representative of their performance is presented

Shock waves & explosions

CERN Document Server

Sachdev, PL

2004-01-01

Understanding the causes and effects of explosions is important to experts in a broad range of disciplines, including the military, industrial and environmental research, aeronautic engineering, and applied mathematics. Offering an introductory review of historic research, Shock Waves and Explosions brings analytic and computational methods to a wide audience in a clear and thorough way. Beginning with an overview of the research on combustion and gas dynamics in the 1970s and 1980s, the author brings you up to date by covering modeling techniques and asymptotic and perturbative methods and ending with a chapter on computational methods.Most of the book deals with the mathematical analysis of explosions, but computational results are also included wherever they are available. Historical perspectives are provided on the advent of nonlinear science, as well as on the mathematical study of the blast wave phenomenon, both when visualized as a point explosion and when simulated as the expansion of a high-pressure ...

Intermittent Explosive Disorder

Directory of Open Access Journals (Sweden)

Lut Tamam

2011-09-01

Full Text Available Intermittent explosive disorder is an impulse control disorder characterized by the occurrence of discrete episodes of failure to resist aggressive impulses that result in violent assault or destruction of property. Though the prevalence intermittent explosive disorder has been reported to be relatively rare in frontier studies on the field, it is now common opinion that intermittent explosive disorder is far more common than previously thought especially in clinical psychiatry settings. Etiological studies displayed the role of both psychosocial factors like childhood traumas and biological factors like dysfunctional neurotransmitter systems and genetics. In differential diagnosis of the disorder, disorders involving agression as a symptom such as alcohol and drug intoxication, antisocial and borderline personality disorders, personality changes due to general medical conditions and behavioral disorder should be considered. A combination of pharmacological and psychotherapeutic approaches are suggested in the treatment of the disorder. This article briefly reviews the historical background, diagnostic criteria, epidemiology, etiology and treatment of intermittent explosive disorder.

Free radical explosive composition

Science.gov (United States)

Walker, Franklin E.; Wasley, Richard J.

1979-01-01

An improved explosive composition is disclosed and comprises a major portion of an explosive having a detonation velocity between about 1500 and 10,000 meters per second and a minor amount of a getter additive comprising a compound or mixture of compounds capable of capturing or deactivating free radicals or ions under mechanical or electrical shock conditions and which is not an explosive. Exemplary getter additives are isocyanates, olefins and iodine.

The non-proliferation experiment

Energy Technology Data Exchange (ETDEWEB)

Hannon, W.J. [Lawrence Livermore National Lab., CA (United States)

1994-12-31

On September 22, 1993, the Department of Energy detonated more than 1.2 million kg of blasting agent in a tunnel in Rainier Mesa at the Nevada Test Site. The resulting explosion generated seismic, electromagnetic, and air pressure signals that were recorded on instruments deployed at distances ranging from a few meters to hundreds and, in some cases, thousands of kilometers. More than 12 organizations made measurements before, during, and after the explosions. The explosion and its associated experiments are known as the Non-Proliferation Experiment (NPE). Analyses of the measurements made during the NPE and comparisons with similar measurements made on previous nearly nuclear explosions and on a co-located smaller explosion detonated at the same site are providing basic phenomenological insights into what is potentially one of the comprehensive Test Ban Treaty (CTBT)-distinguishing between nuclear explosions and some of the many conventional explosions that occur each year. The NPE is also providing information on the use of chemical explosions to develop empirical discriminants in regions where no nuclear explosions have been recorded. In another verification application, several NPE projects are examining the utility of on-site, pre-shot, shot-time, and post-shot measurements of gas seepage, seismic activity, and other observables as a means of identifying the source of signals that appear like nuclear explosions at regional distances. Two related activities are being considered. First, challenge on-site inspections, conducted after an event has occurred, may be able to use the characteristics of phenomena that persist after the explosion to detect and identify the source of the signals that appeared ambiguous or explosion-like to remote sensors. Second, cooperative, on-site measurements made at the time of a pre-nounced conventional explosion may provide assurance that a nuclear explosion did not occur as part of or in place of the pre-announced explosion.

An experimental study of an explosively driven flat plate launcher

Science.gov (United States)

Rae, Philip; Haroz, Erik; Armstrong, Chris; Perry, Lee; M Division Team

2017-06-01

For some upcoming experiments it is desired to impact a large explosive assembly with one or more moderate diameter flat metal plates traveling at high velocity (2-3 km s-1). The time of arrival of these plates will need to carefully controlled and delayed (i.e. the time(s) of arrival known to approximately a microsecond). For this reason, producing a flyer plate from more traditional gun assemblies is not possible. Previous researchers have demonstrated the ability to throw reasonably flat metal flyers from the so-called Forest flyer geometry. The defining characteristics of this design are a carefully controlled reduction in explosive area from a larger explosive plane-wave-lens and booster pad to a smaller flyer plate to improve the planarity of the drive available and an air gap between the explosive booster and the plate to reduce the peak tensile stresses generated in the plate to suppress spalling. This experimental series comprised a number of different design variants and plate and explosive drive materials. The aim was to calibrate a predictive computational modeling capability on this kind of system in preparation for later more radical design ideas best tested in a computer before undertaking the expensive business of construction.

Effects of neutrino trapping on supernova explosions

International Nuclear Information System (INIS)

Takahara, Mariko; Sato, Katsuhiko

1982-01-01

Effects of neutrino trapping on the mass ejection from the stellar cores are investigated with the aid of a simplified equation of state under the assumption of adiabatic collapse. It is found that mass ejection becomes violent only if the ratio of the trapped leptons to baryons, Y sub(L), lies in an appropriate range. If the value of Y sub(L) lies out of this range, mass ejection is difficult. It is also shown that as the thermal stiffness of the shocked matter increases, the range necessary for the violent mass ejection becomes wider. Possibilities of supernova explosion are discussed on the basis of these results. (author)

Is the Experience of Thermal Pain Genetics Dependent?

Directory of Open Access Journals (Sweden)

Emilia Horjales-Araujo

2015-01-01

Full Text Available It is suggested that genetic variations explain a significant portion of the variability in pain perception; therefore, increased understanding of pain-related genetic influences may identify new targets for therapies and treatments. The relative contribution of the different genes to the variance in clinical and experimental pain responses remains unknown. It is suggested that the genetic contributions to pain perception vary across pain modalities. For example, it has been suggested that more than 60% of the variance in cold pressor responses can be explained by genetic factors; in comparison, only 26% of the variance in heat pain responses is explained by these variations. Thus, the selection of pain model might markedly influence the magnitude of the association between the pain phenotype and genetic variability. Thermal pain sensation is complex with multiple molecular and cellular mechanisms operating alone and in combination within the peripheral and central nervous system. It is thus highly probable that the thermal pain experience is affected by genetic variants in one or more of the pathways involved in the thermal pain signaling. This review aims to present and discuss some of the genetic variations that have previously been associated with different experimental thermal pain models.

Operational Experience from Solar Thermal Energy Projects

Science.gov (United States)

Cameron, C. P.

1984-01-01

Over the past few years, Sandia National Laboratories were involved in the design, construction, and operation of a number of DOE-sponsored solar thermal energy systems. Among the systems currently in operation are several industrial process heat projects and the Modular Industrial Solar Retrofit qualification test systems, all of which use parabolic troughs, and the Shenandoah Total Energy Project, which uses parabolic dishes. Operational experience has provided insight to both desirable and undesirable features of the designs of these systems. Features of these systems which are also relevant to the design of parabolic concentrator thermal electric systems are discussed. Other design features discussed are system control functions which were found to be especially convenient or effective, such as local concentrator controls, rainwash controls, and system response to changing isolation. Drive systems are also discussed with particular emphasis of the need for reliability and the usefulness of a manual drive capability.

Spot test kit for explosives detection

Science.gov (United States)

Pagoria, Philip F; Whipple, Richard E; Nunes, Peter J; Eckels, Joel Del; Reynolds, John G; Miles, Robin R; Chiarappa-Zucca, Marina L

2014-03-11

An explosion tester system comprising a body, a lateral flow membrane swab unit adapted to be removeably connected to the body, a first explosives detecting reagent, a first reagent holder and dispenser operatively connected to the body, the first reagent holder and dispenser containing the first explosives detecting reagent and positioned to deliver the first explosives detecting reagent to the lateral flow membrane swab unit when the lateral flow membrane swab unit is connected to the body, a second explosives detecting reagent, and a second reagent holder and dispenser operatively connected to the body, the second reagent holder and dispenser containing the second explosives detecting reagent and positioned to deliver the second explosives detecting reagent to the lateral flow membrane swab unit when the lateral flow membrane swab unit is connected to the body.

Activation experiment for concrete blocks using thermal neutrons

Science.gov (United States)

Okuno, Koichi; Tanaka, Seiichiro

2017-09-01

Activation experiments for ordinary concrete, colemanite-peridotite concrete, B4C-loaded concrete, and limestone concrete are carried out using thermal neutrons. The results reveal that the effective dose for gamma rays from activated nuclides of colemanite-peridotite concrete is lower than that for the other types of concrete. Therefore, colemanite-peridotite concrete is useful for reducing radiation exposure for workers.

Explosive X-point collapse in relativistic magnetically dominated plasma

Science.gov (United States)

Lyutikov, Maxim; Sironi, Lorenzo; Komissarov, Serguei S.; Porth, Oliver

2017-12-01

The extreme properties of the gamma-ray flares in the Crab nebula present a clear challenge to our ideas on the nature of particle acceleration in relativistic astrophysical plasma. It seems highly unlikely that standard mechanisms of stochastic type are at work here and hence the attention of theorists has switched to linear acceleration in magnetic reconnection events. In this series of papers, we attempt to develop a theory of explosive magnetic reconnection in highly magnetized relativistic plasma which can explain the extreme parameters of the Crab flares. In the first paper, we focus on the properties of the X-point collapse. Using analytical and numerical methods (fluid and particle-in-cell simulations) we extend Syrovatsky's classical model of such collapse to the relativistic regime. We find that the collapse can lead to the reconnection rate approaching the speed of light on macroscopic scales. During the collapse, the plasma particles are accelerated by charge-starved electric fields, which can reach (and even exceed) values of the local magnetic field. The explosive stage of reconnection produces non-thermal power-law tails with slopes that depend on the average magnetization . For sufficiently high magnetizations and vanishing guide field, the non-thermal particle spectrum consists of two components: a low-energy population with soft spectrum that dominates the number census; and a high-energy population with hard spectrum that possesses all the properties needed to explain the Crab flares.

Nuclear explosives and hydrocarbons

Energy Technology Data Exchange (ETDEWEB)

Cohen, P

1971-10-01

A nuclear explosive 12 in. in diam and producing very little tritium is feasible in France. Such a device would be well adapted for contained nuclear explosions set off for the purpose of hydrocarbon storage or stimulation. The different aspects of setting off the explosive are reviewed. In the particular case of gas storage in a nuclear cavity in granite, it is demonstrated that the dose of irradiation received is extremely small. (18 refs.)

Strength of the phase change materials on loading with the products of electric explosion of conductors

Science.gov (United States)

Savenkov, Georgiy; Morozov, Viktor; Kats, Victor

2018-05-01

Results of the experimentation on the destruction of the phase change materials (beeswax and paraffin) by the electric explosion of conductors are presented. The process of the explosion of copper and nickel titanium wires in both pure PCM and its mixture with nonosized additives of cuprous oxide is analyzed. The effect of this additive on the process of the expansion of the electric-discharge plasma during the electric explosion of conductors and on the strength of composite materials is demonstrated. The piezoprobe-based method of measurement of the radial pressure during samples destruction is developed. The experiments made it possible to determine the dimensions of the melting channel formed inside the samples during the explosion and the subsequent expansion of the electric-discharge plasma. The experiments are performed on the generator of short-term high-voltage pulses capable to shape the voltage of (10-24) kV.

Physicochemical analysis of explosions due to impact in mixed paste propellants

Energy Technology Data Exchange (ETDEWEB)

Dubovik, Aleksandr V. [Institute of Chemical Physics, Russian Academy of Science, 117977, Kosygin Street 4, Moscow (Russian Federation)

2005-09-01

An analysis has been performed on the impact sensitivity of paste explosive materials (PEM) with continuous physical structure containing air cavities of various sizes. It is shown that the sensitivities of PEMs based on ammonium perchlorate are strongly influenced by the extent of oxidizer decomposition during the low-temperature stages of thermal decomposition. Mechanically non-uniform PEMs are well sensitized by air bubbles of an optimum size. (Abstract Copyright [2005], Wiley Periodicals, Inc.)

Natural gas production from underground nuclear explosions

Energy Technology Data Exchange (ETDEWEB)

1965-01-01

A remote location in Rio Arriba County, NW. New Mexico, is being considered as the site for an experiment in the use of a nuclear explosive to increase production from a natural gas field. A feasibility study has been conducted by the El Paso Natural Gas Co., the U.S. Atomic Energy commission, and the U.S. Bureau of Mines. As presently conceived, a nuclear explosive would be set in an emplacement hole and detonated. The explosion would create a cylinder or ''chimney'' of collapsed rock, and a network of fractures extending beyond the chimney. The fractures are the key effect. These would consist of new fractures, enlargement of existing ones, and movement along planes where strata overlap. In addition, there are a number of intangible but important benefits that could accrue from the stimulating effect. Among these are the great increase in recoverable reserves and the deliverability of large volumes of gas during the periods of high demand. It is believed that this type of well stimulation may increase the total gas production of these low permeability natural gas fields by about 7 times the amounts now attainable.

Studies on formation of unconfined detonable vapor cloud using explosive means.

Science.gov (United States)

Apparao, A; Rao, C R; Tewari, S P

2013-06-15

Certain organic liquid fuels like hydrocarbons, hydrocarbon oxides, when dispersed in air in the form of small droplets, mix with surrounding atmosphere forming vapor cloud (aerosol) and acquire explosive properties. This paper describes the studies on establishment of conditions for dispersion of fuels in air using explosive means resulting in formation of detonable aerosols of propylene oxide and ethylene oxide. Burster charges based on different explosives were evaluated for the capability to disperse the fuels without causing ignition. Parameters like design of canister, burster tube, burster charge type, etc. have been studied based on dispersion experiments. The detonability of the aerosol formed by the optimized burster charge system was also tested. Copyright © 2013 Elsevier B.V. All rights reserved.

Review of possible peaceful applications of nuclear explosions in the national economy of the Soviet Union

International Nuclear Information System (INIS)

Witherspoon, Paul A.

1970-01-01

The following review will give some of the current thinking of Soviet scientists and engineers on the possibilities of using nuclear explosions for peaceful purposes in the Soviet Union. This review is taken from a more detailed report that was presented under the same title by Soviet participants at an information-exchange meeting that was held in Vienna between the Soviet Union and the United States in April, 1969. Aside from a very brief review of one explosion in salt, the report does not give details on nuclear explosion effects (mechanical, seismic, radiation, or thermal). Rather, the report summarizes the results of design calculations and indicates the direction of Soviet planning for a variety of industrial applications. A complete translation of this report will be published by the Division of Technical Information and Education of AEC at Oakridge. (author)

Review of possible peaceful applications of nuclear explosions in the national economy of the Soviet Union

Energy Technology Data Exchange (ETDEWEB)

Witherspoon, Paul A [University of California, Berkeley (United States)

1970-05-15

The following review will give some of the current thinking of Soviet scientists and engineers on the possibilities of using nuclear explosions for peaceful purposes in the Soviet Union. This review is taken from a more detailed report that was presented under the same title by Soviet participants at an information-exchange meeting that was held in Vienna between the Soviet Union and the United States in April, 1969. Aside from a very brief review of one explosion in salt, the report does not give details on nuclear explosion effects (mechanical, seismic, radiation, or thermal). Rather, the report summarizes the results of design calculations and indicates the direction of Soviet planning for a variety of industrial applications. A complete translation of this report will be published by the Division of Technical Information and Education of AEC at Oakridge. (author)

Emission spectroscopy of hypervelocity impacts on aluminum, organic and high-explosive targets

NARCIS (Netherlands)

Verreault, J.; Day, J.P.R.; Halswijk, W.H.C.; Loiseau, J.; Huneault, J.; Higgins, A.J.; Devir, A.D.

2015-01-01

Laboratory experiments of hypervelocity impacts on aluminum, nylon and high-explosive targets are presented. Spectral measurements of the impact flash are recorded, together with radiometric measurements to derive the temperature of the flash. Such experiments aim at demonstrating that the impact

30 CFR 77.1301 - Explosives; magazines.

Science.gov (United States)

2010-07-01

... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Explosives; magazines. 77.1301 Section 77.1301... and Blasting § 77.1301 Explosives; magazines. (a) Detonators and explosives other than blasting agents shall be stored in magazines. (b) Detonators shall not be stored in the same magazine with explosives...

High-resolution Raman Spectroscopy for the Nanostructural Characterization of Explosive Nanodiamond Precursors.

Science.gov (United States)

Deckert-Gaudig, Tanja; Pichot, Vincent; Spitzer, Denis; Deckert, Volker

2017-01-18

The specific attributes of nanodiamonds have attracted increasing interest for electronics or biomedical applications. An efficient synthetic route towards nanodiamonds is via detonation of hexolite (i.e. a mixture of TNT [2,4,6-trinitrotoluene] and RDX [1,3,5-trinitro-1,3,5-triazine]). In particular, detonation of hexolite crystallized by spray flash evaporation (SFE) yields extremely small diamonds (<4 nm). To unravel the detonation mechanism, a structural characterization of the explosives is required but is challenging due to their thermal instability. We demonstrate a combination of conventional Raman spectroscopy and tip-enhanced Raman spectroscopy (TERS) for resolving morphological and structural differences of differently prepared hexolite nanocomposites. The experiments allow for the first time a structural differentiation of individual TNT and RDX crystals and 15-20 nm sized core-shell structures, consequently providing a general approach to investigate the actual composition of mixtures on the nanometer scale. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

MC3D modelling of stratified explosion

International Nuclear Information System (INIS)

Picchi, S.; Berthoud, G.

1999-01-01

It is known that a steam explosion can occur in a stratified geometry and that the observed yields are lower than in the case of explosion in a premixture configuration. However, very few models are available to quantify the amount of melt which can be involved and the pressure peak that can be developed. In the stratified application of the MC3D code, mixing and fragmentation of the melt are explained by the growth of Kelvin Helmholtz instabilities due to the shear flow of the two phase coolant above the melt. Such a model is then used to recalculate the Frost-Ciccarelli tin-water experiment. Pressure peak, speed of propagation, bubble shape and erosion height are well reproduced as well as the influence of the inertial constraint (height of the water pool). (author)

MC3D modelling of stratified explosion

Energy Technology Data Exchange (ETDEWEB)

Picchi, S.; Berthoud, G. [DTP/SMTH/LM2, CEA, 38 - Grenoble (France)

1999-07-01

It is known that a steam explosion can occur in a stratified geometry and that the observed yields are lower than in the case of explosion in a premixture configuration. However, very few models are available to quantify the amount of melt which can be involved and the pressure peak that can be developed. In the stratified application of the MC3D code, mixing and fragmentation of the melt are explained by the growth of Kelvin Helmholtz instabilities due to the shear flow of the two phase coolant above the melt. Such a model is then used to recalculate the Frost-Ciccarelli tin-water experiment. Pressure peak, speed of propagation, bubble shape and erosion height are well reproduced as well as the influence of the inertial constraint (height of the water pool). (author)

CFD SIMULATION FOR DEMILITARIZATION OF RDX IN A ROTARY KILN BY THERMAL DECOMPOSITION

Directory of Open Access Journals (Sweden)

SI H. LEE

2017-06-01

Full Text Available Demilitarization requires the recovery and disposal of obsolete ammunition and explosives. Since open burning/detonation of hazardous waste has caused serious environmental and safety problems, thermal decomposition has emerged as one of the most feasible methods. RDX is widely used as a military explosive due to its high melting temperature and detonation power. In this work, the feasible conditions under which explosives can be safely incinerated have been investigated via a rotary kiln simulation. To solve this problem, phase change along with the reactions of RDX has been incisively analyzed. A global reaction mechanism consisting of condensed phase and gas phase reactions are used in Computational Fluid Dynamics simulation. User Defined Functions in FLUENT is utilized in this study to inculcate the reactions and phase change into the simulation. The results divulge the effect of temperature and the varying amounts of gas produced in the rotary kiln during the thermal decomposition of RDX. The result leads to the prospect of demilitarizing waste explosives to avoid the possibility of detonation.

In-vessel coolability and steam explosion in Nordic BWRs

International Nuclear Information System (INIS)

Ma, W.; Hansson, R.; Li, L.; Kudinov, P.; Cadinu, F.; Tran, C-.T.

2010-05-01

The INCOSE project is to reduce the uncertainty in quantification of steam explosion risk and in-vessel coolability in Nordic BWR plants with the cavity flooding as a severe accident management (SAM) measure. During 2009 substantial advances and new insights into physical mechanisms were gained for studies of: (i) in-vessel corium coolability - development of the methodologies to assess the efficiency of the control rod guide tube (CRGT) cooling as a potential SAM measure; (ii) debris bed coolability - characterization of the effective particle diameter of multi-size particles and qualification of friction law for two-phase flow in the beds packed with multi-size particles; and (iii) steam explosion - investigation of the effect of binary oxides mixtures properties on steam explosion. An approach for coupling of ECM/PECM models with RELAP5 was developed to enhance predictive fidelity for melt pool heat transfer. MELCOR was employed to examine the CRGT cooling efficiency by considering an entire accident scenario, and the simulation results show that the nominal flowrate (∼10kg/s) of CRGT cooling is sufficient to maintain the integrity of the vessel in a BWR of 3900 MWth, if the water injection is activated no later than 1 hour after scram. The POMECO-FL experimental data suggest that for a particulate bed packed with multi-size particles, the effective particle diameter can be represented by the area mean diameter of the particles, while at high velocity (Re>7) the effective particle diameter is closer to the length mean diameter. The pressure drop of two-phase flow through the particulate bed can be predicted by Reed's model. The steam explosion experiments performed at high melt superheat (>200oC) using oxidic mixture of WO3-CaO didn't detect an apparent difference in steam explosion energetics and preconditioning between the eutectic and noneutectic melts. This points out that the next step of MISTEE experiment will be conducted at lower superheat. (author)

Pretest thermal analysis of the Tuff Water Migration/In-Situ Heater Experiment

International Nuclear Information System (INIS)

Bulmer, B.M.

1980-02-01

This report describes the pretest thermal analysis for the Tuff Water Migration/In-Situ Heater Experiment to be conducted in welded tuff in G-tunnel, Nevada Test Site. The parametric thermal modeling considers variable boiling temperature, tuff thermal conductivity, tuff emissivity, and heater operating power. For nominal tuff properties, some near field boiling is predicted for realistic operating power. However, the extent of boiling will be strongly determined by the ambient (100% water saturated) rock thermal conductivity. In addition, the thermal response of the heater and of the tuff within the dry-out zone (i.e., bounded by boiling isotherm) is dependent on the temperature variation of rock conductivity as well as the extent of induced boiling

Study of the initiation and the escalade phases of a vapour explosion; Etude de la phase d'initiation et d'escalade d'une explosion de vapeur

Energy Technology Data Exchange (ETDEWEB)

Lamome, J

2007-09-15

The steam explosion triggering issue is discussed here by studying at the thermal fragmentation (small pressure perturbation) of a hot water droplet surrounded by a stable steam film. Fragmentation seems to be the consequence of local contacts between the droplet and the coolant. However, the exact mechanism altering the droplet following the above mentioned contacts is uncertain. After a study of the proportions in place, we realized a contact can fragment the droplet in a very short period of time. Therefore, we adopted an approach considering the contact as the explosion criteria. In order to validate this approach, we researched the explosion levels of the experimental variations based on the surrounding pressure and on the coolant's temperature. The model found again the experimental variations, the levels were found again with some uncertainty. The contact is obtained by 2 mechanisms inducing liquid's proximity: a steam film global compression due to the disturbance and the amplification of the interface defaults between the coolant and the steam. It appears it is the mechanism of global compression that explains mostly the experimental variations. Following these results, we conducted model's extrapolations in order to come as close as possible of the conditions in which steam explosion can occur on an industrial scale (i.e. in the water pressured nuclear reactors). (author)

Explosion metal welding

International Nuclear Information System (INIS)

Popoff, A.A.

1976-01-01

Process parameters pertaining to welding similar and dissimilar metals using explosives are reviewed. The discussion centers on the interrelationship of physical parameters which play a part in achieving desirable metallurgical results. Present activities in explosion metal welding at LASL are presented and shown how they related to the interests of the ERDA community

Sensitivity to friction for primary explosives.

Science.gov (United States)

Matyáš, Robert; Šelešovský, Jakub; Musil, Tomáš

2012-04-30

The sensitivity to friction for a selection of primary explosives has been studied using a small BAM friction apparatus. The probit analysis was used for the construction of a sensitivity curve for each primary explosive tested. Two groups of primary explosives were chosen for measurement (a) the most commonly used industrially produced primary explosives (e.g. lead azide, tetrazene, dinol, lead styphnate) and (b) the most produced improvised primary explosives (e.g. triacetone triperoxide, hexamethylenetriperoxide diamine, mercury fulminate, acetylides of heavy metals). A knowledge of friction sensitivity is very important for determining manipulation safety for primary explosives. All the primary explosives tested were carefully characterised (synthesis procedure, shape and size of crystals). The sensitivity curves obtained represent a unique set of data, which cannot be found anywhere else in the available literature. Copyright © 2012 Elsevier B.V. All rights reserved.

Ag-ZnO nanostructure for ANTA explosive molecule detection

Energy Technology Data Exchange (ETDEWEB)

Shaik, Ummar Pasha [Advanced Center of Research in High Energy Materials, University of Hyderabad, Hyderabad 500046 (India); Sangani, L. D. Varma [Centre for Advanced Studies in Electronics Science and Technology, School of Physics, University of Hyderabad (India); Gaur, Anshu [Department of Industrial Engineering, University of Trento, Via Sommarive9, Trento (Italy); Mohiddon, Md. Ahamad, E-mail: ahamed.vza@gmail.com [National Institute of Technology Andhra Pradesh, Tadepalliguem 534101, AP, India Phone : (+) 91-40-23134382, FAX: (+) 91-40-23010227 (India); Krishna, M. Ghanashyam [Advanced Center of Research in High Energy Materials, University of Hyderabad, Hyderabad 500046 (India); Centre for Advanced Studies in Electronics Science and Technology, School of Physics, University of Hyderabad (India); National Institute of Technology Andhra Pradesh, Tadepalliguem 534101, AP, India Phone : (+) 91-40-23134382, FAX: (+) 91-40-23010227 (India)

2016-05-23

Ag/ZnO nanostructure for surface enhanced Raman scattering application in the detection of ANTA explosive molecule is demonstrated. A highly rough ZnO microstructure was achieved by rapid thermal annealing of metallic Zn film. Different thickness Ag nanostructures are decorated over these ZnO microstructures by ion beam sputtering technique. Surface enhanced Raman spectroscopic studies carried out over Ag/ZnO substrates have shown three orders higher enhancement compared to bare Ag nanostructure deposited on the same substrate. The reasons behind such huge enhancement are discussed based on the morphology of the sample.

Zirconium hydride containing explosive composition

Science.gov (United States)

Walker, Franklin E.; Wasley, Richard J.

1981-01-01