WorldWideScience

Sample records for thermal emission spectra

  1. Measuring the response of canopy emissivity spectra to leaf area index variation using thermal hyperspectral data

    Science.gov (United States)

    Neinavaz, Elnaz; Darvishzadeh, Roshanak; Skidmore, Andrew K.; Groen, Thomas A.

    2016-12-01

    One of the plant biophysical factors affecting the canopy spectral reflectance of plants in the optical domain to receive research attention in recent decades is leaf area index (LAI). Although it is expected that the value of LAI affects the emission of radiation, it not known how. To our knowledge, the effect of LAI on plant canopy emissivity spectra has not yet been investigated in the thermal infrared region (TIR 8-14 μm). The overall aim of this study was to demonstrate the effect of LAI on canopy emissivity spectra of different species at the nadir position. The 279 spectral wavebands in the TIR domain were measured under controlled laboratory condition using a MIDAC spectrometer for four plant species. The corresponding LAI of each measurement was destructively calculated. We found a positive correlation between canopy emissivity spectra at various LAI values, indicating that emissivity increases concomitantly with LAI value. The canopy emissivity spectra of the four species were found to be statistically different at various wavebands even when the LAI values of the species were similar. It seems that other biophysical or biochemical factors also contribute to canopy emissivity spectra: this merits further investigation. We not only quantify the role of LAI on canopy emissivity spectra for the first time, but also demonstrate the potential of using hyperspectral thermal data to estimate LAI of plant species.

  2. Reflection and thermal emission spectra of Earth-like extrasolar planets affected by clouds

    Science.gov (United States)

    Kitzmann, Daniel; Patzer, A. B. C.; von Paris, Philip; Rauer, Heike

    Clouds can have an important impact on the radiative transfer in planetary atmospheres by absorption and scattering of the incident stellar radiation and the thermal radiation from the surface. Consequently, the planetary emission and reflection spectra are strongly affected by the presence of clouds, resulting in e.g. the concealing of thermal surface emissions or dampening of molecular absorption bands in the infrared. To study these effects, a parametrised cloud description, accounting for two different types of clouds (low-level water and high-level ice clouds) and their partial overlap has been developed. The multi-layered cloud model is based on observations in the Earth's atmosphere and has been coupled with a one-dimensional radiative-convective steady state climate model to obtain low-resolution spectra of Earth-like extrasolar planets. In this contribution the impact of multi-layered on low-resolution thermal emission and reflec-tion spectra is presented for Earth-like planets orbiting different types of central stars, with special emphasis on so-called biomarker signatures. The influence of clouds on the ability to derive information about the planetary surface temperatures from low-resolution spectra is also discussed.

  3. TIR Emissivity Spectra of Thermally Processed Sulfates, Carbonates and Phyllosilicates as Analog Materials for Asteroid Surfaces

    Science.gov (United States)

    Maturilli, A.; Helbert, J.; D'Amore, M.; Ferrari, S.

    2013-12-01

    At the Planetary Emissivity Laboratory (PEL) of the German Aerospace Center (DLR) in Berlin we are building a database of spectral measurements of several meteorites and other analogs for asteroid surfaces. Bi-directional reflectance of samples in the 1 to 100 μm spectral range, are measured by using an evacuated (10-4 bar) Bruker Vertex 80V FTIR spectrometer and a Bruker A513 reflection unit, allowing phase angles between 26° and 170°. Emissivity in the 1 to 100 μm spectral range is measured with the same instrument coupled with an external emissivity chamber, for sample temperatures ranging from low (50° C) to very high (above 800° C). We present here new measurements on sulfates, carbonates, and phyllosilicates in various grain size ranges. The setup was configured to simulate the thermal history of surface minerals on the asteroid 2008 EV5 during its revolution around the Sun. This asteroid is the scientific target of the ESA Marco Polo-R mission. The samples in vacuum (< 0.8 mbar) are measured at surface temperature around 70° C, then the same samples are heated to 220° C, and maintained at this temperature for one hour. Slowly the sample temperature is reduced back again to 70° C and a second measurement is taken. Emissivity spectra before and after thermal processing of the samples are complemented with reflectance measurements on samples fresh and after thermal processing. This comparison show us that for some minerals no spectral/structural changes appear, while others show signs of dehydration and among them some species show structural changes. We conclude that a proper spectral library of emissivity spectra for asteroid analogue materials must include thermally processed samples, reproducing the thermal evolution for the asteroid that is target of the actual investigation.

  4. Calcium pyroxenes at Mercurian surface temperatures: investigation of in-situ emissivity spectra and thermal expansion

    Science.gov (United States)

    Ferrari, S.; Nestola, F.; Helbert, J.; Maturilli, A.; D'Amore, M.; Alvaro, M.; Domeneghetti, M.; Massironi, M.; Hiesinger, H.

    2013-12-01

    The European Space Agency and Japan Aerospace Agency mission to Mercury, named BepiColombo, will carry on board the Mercury Radiometer and Thermal Infrared Spectrometer (MERTIS) that will be able to provide surface Thermal Infra-Red (TIR) emissivity spectra from 7 to 14 μm. This range of wavelengths is very useful to identify the fine-scale structural properties of several silicates. For mineral families as pyroxenes, the emissivity peak positions are good indicators of the composition. A complication in the interpretation of MERTIS data could arise from the extreme daily surface temperature range of Mercury (70 to 725 K) that significantly affects the crystal structure and density of minerals and consequently should affect the TIR spectral signature of each single mineral present on the surface of the planet. In preparation for the MERTIS data analysis, we are extensively investigating at high temperatures conditions several mineral phases potentially detectable on the surface of Mercury. Two C2/c augitic pyroxenes, with constant calcium content and very different magnesium to iron ratio, were studied by in situ high-temperature thermal infrared spectroscopy (up to 750 K) and in situ high-temperature single-crystal X-ray diffraction (up to 770 K). The emissivity spectra of the two samples show similar band center shifts of the main three bands toward lower wavenumbers with increasing temperature. Our results indicate that the center position of bands 1 and 2 is strictly dependent on temperature, whereas the center position of band 3 is a strong function of the composition regardless the temperature. These data suggest that MERTIS spectra will be able to provide indications of C2/c augitic pyroxene with different magnesium contents and will allow a correct interpretation independently on the spectra acquisition temperature.

  5. Thermal emission spectra of Mars (5.4-10.5 microns) - Evidence for sulfates, carbonates, and hydrates

    Science.gov (United States)

    Pollack, James B.; Roush, Ted; Witteborn, Fred; Bregman, Jesse; Wooden, Diane; Stoker, Carol; Toon, Owen B.

    1990-01-01

    Spectra of the Martian thermal emission in the 5.4-10.5 micron region are reported. Emission features at 7.8 and 9.7 microns are attributed to surface silicates, and an emission feature at 6.1 micron is attributed to a molecular water component of the surface material. An absorption band at 8.7 micron and a possible one at 9.8 microns is attributed to sulfate or bisulfate anions probably located at a distorted crystalline site, and an absorption band at 6.7 microns is attributed to carbonate or bicarbonate anions located in a distorted crystalline site. Spectral simulations indicate that the sulfate- and carbonate-bearing minerals are contained in the same particles of airborne dust as the dominant silicate minerals, that the dust optical depth is about 0.6 at a reference wavelength of 0.3 micron over the area of the observed spots, and that sulfates and carbonates constitute 10-15 percent and 1-3 percent by volume of the airborne dust, respectively.

  6. Investigation of the thermal behavior of emission spectra of the doped quantum wells by means of LSE model

    Directory of Open Access Journals (Sweden)

    E Abdoli

    2010-06-01

    Full Text Available Thermal variation of PL peak energy of undoped nitride semiconductor quantum well shows a successive red-blue-red shifted emission (S-shaped behavior. This behavior has been attributed to the localization of excitons at the energy minima induced by the potential fluctuations in the quantum well structure and/or interface roughness. The S-shaped behavior of PL peak position, the thermal variation of PL line width (FWHM and the integrated PL intensity as well as the localization exciton have been affected by the modulation doping level. In this paper, exciton localizations of doped and undoped nitride semiconductor quantum wells have been studied by localized states ensembles (LSE model.

  7. Infra-red reflectance and emissivity spectra of nanodiamonds

    OpenAIRE

    Maturilli, A.; Shiryaev, A. A.; Kulakova, I I; Helbert, J.

    2012-01-01

    Reflectance and emissivity spectra of nanodiamonds powder were measured in a dedicated setup at temperatures up to 873 K. The spectra are characterised by presence of sharp bands due to surface-bound functional groups. Thermal desorption of oxygen-containing groups lead to corresponding spectral changes. The maximal emissivity of nanodiamond powder reaches 0.985.

  8. Using Lava Tube Skylight Thermal Emission Spectra to Determine Lava Composition on Io: Quantitative Constraints for Observations by Future Missions to the Jovian System.

    Science.gov (United States)

    Davies, A. G.

    2008-12-01

    Deriving the composition of Io's dominant lavas (mafic or ultramafic?) is a major objective of the next missions to the jovian system. The best opportunities for making this determination are from observations of thermal emission from skylights, holes in the roof of a lava tube through which incandescent lava radiates, and Io thermal outbursts, where lava fountaining is taking place [1]. Allowing for lava cooling across the skylight, the expected thermal emission spectra from skylights of different sizes have been calculated for laminar and turbulent tube flow and for mafic and ultramafic composition lavas. The difference between the resulting mafic and ultramafic lava spectra has been quantified, as has the instrument sensitivity needed to acquire the necessary data to determine lava eruption temperature, both from Europa orbit and during an Io flyby. A skylight is an excellent target to observe lava that has cooled very little since eruption (temperatures close to lava eruption temperature. Skylights are therefore easily discernible against a cool background, and are detectable from great distances at night or with Io in eclipse with imagers covering the range 0.4 to 5.0 μm. To distinguish between ultramafic and mafic lavas, multispectral (or hyperspectral) observations with precise exposure timing and knowledge of filter response are needed in the range 0.4 to 0.8 μm, with (minimally) an additional model-constraining measurement at ~4-5 μm. As with many lava tube systems on Earth, skylights should be common on Io (for example, at Prometheus, Culann and Amirani). The possible superheating of lava prior to eruption complicates the analysis [4], but is likely to be significant only for deep- seated, often explosive, eruptions. Effusive activity at the aforementioned three locations is likely fed from shallow reservoirs [5], minimising superheating effects. This work was carried out at the Jet Propulsion Laboratory-California Institute of Technology, under

  9. Investigating the flow dynamics and chemistry of an expanding thermal plasma through CH(A-X) emission spectra

    NARCIS (Netherlands)

    Hansen, T. A. R.; Colsters, P. G. J.; M. C. M. van de Sanden,; Engeln, R.

    2011-01-01

    The gas flow in a linear plasma reactor and the plasma chemistry during hydrogenated amorphous carbon and graphite etching are investigated via time and spatially resolved measurements of the ion density and CH emission. A convolution of the ion and hydrocarbon density shows the importance of charge

  10. Palagonitic (Not Andesitic) Mars: Evidence from Thermal Emission and VNIR Spectra of Palgonitic Alteration Rinds on Basaltic Rock

    Science.gov (United States)

    Morris, R. V.; Graff, T. G.; Mertzman, S. A.; Lane, M. D.; Christensen, P. R.

    2003-01-01

    Visible and near-IR (VNIR) spectra of both Martian bright and dark regions are characterized by a ferric absorption edge extending from approx. 400 to 750 nm, with bright regions having about twice the reflectivity at 750 nm as dark regions. Between 750 nm to beyond 2000 nm, bright and dark regions have nearly constant and slightly negative spectral slopes, respectively. Depending on location, bright regions have shallow reflectivity minima in the range 850-910 nm that are attributed to ferric oxides. Similarly, dark regions have shallow reflectivity minima near approx. 950 and 1700-2000 nm that are attributed to ferrous silicate minerals (pyroxene). Among terrestrial geologic materials, the best spectral analogues for Martian bright regions are certain palagonitic tephras from Mauna Kea Volcano (Hawaii). By definition, palagonite is a "yellow or orange isotropic mineraloid formed by hydration and devitrification of basaltic glass". The ferric pigment in palagonite is nanometer-sized ferric oxide particles (np-Ox) dispersed throughout the hydrated basaltic glass matrix. The hydration state of the np-Ox particles is not known, but the best Martian spectral analogues contain allophane-like materials and not crystalline phyllosilicates.

  11. Thermal Conductivity and Raman Spectra of Carbon Fibers

    Science.gov (United States)

    Liu, Xuebo; Dong, Hua; Li, Yan; Mei, Ning

    2017-10-01

    Due to its unique physical properties, carbon fiber (CF) has been widely studied for extensive application in aerospace and machinery. In this study, the thermal diffusivity of three kinds of CF sample is characterized by the transient electrothermal technique at room temperature. By subtracting the effect of radiative losses, the effective thermal diffusivity of CFs can be calculated as 6.46× 10^{-6} m2\\cdot s^{-1}, 6.58× 10^{-6} m2\\cdot s^{-1} and 2.01× 10^{-4} m2\\cdot s^{-1}, respectively. For the first time, the emissivity coefficient of carbon fiber is calibrated as 0.78. Combined with Raman spectra and phonon scattering, we found that the better crystalline structure and low defect in CF have an obvious impact on its thermal diffusivity.

  12. Retrieval of exoplanet emission spectra with HyDRA

    Science.gov (United States)

    Gandhi, Siddharth; Madhusudhan, Nikku

    2018-02-01

    Thermal emission spectra of exoplanets provide constraints on the chemical compositions, pressure-temperature (P-T) profiles, and energy transport in exoplanetary atmospheres. Accurate inferences of these properties rely on the robustness of the atmospheric retrieval methods employed. While extant retrieval codes have provided significant constraints on molecular abundances and temperature profiles in several exoplanetary atmospheres, the constraints on their deviations from thermal and chemical equilibria have yet to be fully explored. Our present work is a step in this direction. We report HyDRA, a disequilibrium retrieval framework for thermal emission spectra of exoplanetary atmospheres. The retrieval code uses the standard architecture of a parametric atmospheric model coupled with Bayesian statistical inference using the Nested Sampling algorithm. For a given dataset, the retrieved compositions and P-T profiles are used in tandem with the GENESIS self-consistent atmospheric model to constrain layer-by-layer deviations from chemical and radiative-convective equilibrium in the observable atmosphere. We demonstrate HyDRA on the Hot Jupiter WASP-43b with a high-precision emission spectrum. We retrieve an H2O mixing ratio of log(H2O) = -3.54^{+0.82}_{-0.52}, consistent with previous studies. We detect H2O and a combined CO/CO2 at 8-sigma significance. We find the dayside P-T profile to be consistent with radiative-convective equilibrium within the 1-sigma limits and with low day-night redistribution, consistent with previous studies. The derived compositions are also consistent with thermochemical equilibrium for the corresponding distribution of P-T profiles. In the era of high precision and high resolution emission spectroscopy, HyDRA provides a path to retrieve disequilibrium phenomena in exoplanetary atmospheres.

  13. Optically stimulated luminescence emission spectra from feldspars as a function of sample temperature

    DEFF Research Database (Denmark)

    Duller, G.A.T.; Bøtter-Jensen, L.

    1997-01-01

    have been used to characterize the degree of thermal activation involved in the production of the OSL signal. Such measurements would be compromised if the emission spectra altered with temperature. In order to test whether this is a significant problem the OSL emission spectra of a number of feldspar...... samples have been measured at various sample temperatures. A small but consistent shift of the peak emission wavelength to shorter wavelengths at higher temperatures is observed. However, the magnitude of this shift is sufficiently small that it will not affect measurements of the thermal activation...... energy. A systematic difference is observed between the thermal activation energies measured when using different emission wavelengths. In particular, the thermal activation energy of the emission at 400 nm is typically 0.11 eV, while that at 570 nm from the same samples is 0.03-0.05 eV. Several possible...

  14. Thermal Emission from Structured Media

    Science.gov (United States)

    Zimmerman, Ian Andrew

    This dissertation covers a study of the use of macroscopic structure as a means of controlling thermal emission in the THz and mid-IR frequency regions. Chapter 1 presents a brief introduction to the THz frequency region and to the concept of the photonic crystal, the primary type of geometry used. Chapter 2 compares the two most common methods used to calculate the thermal emission of a structure whose components are all at the same temperature. These methods are compared in terms of the results they give and in terms of how computationally involved the methods are. The first method explored involves using Kirchhoff's law of thermal emission which equates the absorptivity and emissivity of a structure. The second method is to calculate the emission directly from the Green's function using the microscopic thermal currents given by the Fluctuation-Dissipation theorem. A derivation of the second method is given, and the equality between the two methods is proven in 1D. It is shown that the Kirchhoff's law method is much more computationally efficient, and it is therefore used for the parametric studies of the structures which make up the remainder of this document. Chapter 3 covers work done in the THz regime. In the THz frequency regime, where a historic lack of sources has in part impeded full exploration and utilization, a photonic crystal design is proposed to control the thermal emission. It is shown that using a 1D bi-layered photonic crystal, composed of alternating section of silicon wafers and vacuum sections, it is possible to tailor many narrowband emission features over a broadband frequency range. In simulation both spectral and directional thermal emission control is demonstrated, and a parametric study is performed to explore how changes in the geometry of the photonic crystal change its thermal emission signature. A description is then given of how the photonic crystal is constructed and how its thermal emission is measured using Fourier transform

  15. Constraining Hot Jupiter Atmospheric Structure and Dynamics through Doppler-shifted Emission Spectra

    Science.gov (United States)

    Zhang, Jisheng; Kempton, Eliza M.-R.; Rauscher, Emily

    2017-12-01

    We present a coupled 3D atmospheric dynamics and radiative transfer model to predict the disk-integrated thermal emission spectra of transiting exoplanets in edge-on orbits. We calculate spectra at high resolution to examine the extent to which high-resolution emission spectra are influenced by 3D atmospheric dynamics and planetary rotation and to determine whether and how we can constrain thermal structures and atmospheric dynamics through high-resolution spectroscopy. This study represents the first time that the line-of-sight geometry and resulting Doppler shifts from winds and rotation have been treated self-consistently in an emission spectrum radiative transfer model, which allows us to assess the impact of the velocity field on thermal emission spectra. We apply our model to predict emission spectra as a function of orbital phase for three hot Jupiters: HD 209458b, WASP-43b, and HD 189733b. We find net Doppler shifts in modeled spectra due to a combination of winds and rotation at a level of 1–3 km s‑1. These Doppler signatures vary in a quasi-sinusoidal pattern over the course of the planets’ orbits as the hot spots approach and recede from the observer’s viewpoint. We predict that WASP-43b produces the largest Doppler shift due to its fast rotation rate. We find that the net Doppler shift in an exoplanet’s disk-integrated thermal emission spectrum results from a complex combination of winds, rotation, and thermal structure. However, we offer a simple method that estimates the magnitude of equatorial wind speeds in hot Jupiters through measurements of net Doppler shifts and lower-resolution thermal phase curves.

  16. Palagonitic Mars from Rock Rinds to Dust: Evidence from Visible, Near-IR, and Thermal Emission Spectra of Poorly Crystalline Materials

    Science.gov (United States)

    Morris, R. V.; Graff, T. G.; Mertzman, S. A.; Lane, M. D.; Christensen, P. R.

    2003-01-01

    Visible and near-IR (VNIR) spectral data for Martian bright regions are characterized by a general shape consisting of a ferric absorption edge extending from about 400 to 750 nm and relatively constant reflectivity extending from about 750 nm to beyond 2000 nm . Among terrestrial geologic materials, the best spectral analogues are certain palagonic tephras from Mauna Kea Volcano (Hawaii). By definition, palagonite is a yellow or orange isotropic mineraloid formed by hydration and devitrification of basaltic glass. The ferric pigment in palagonite is nanometer-sized ferric oxide particles (np-Ox) dispersed throughout the hydrated basaltic glass matrix. The hydration state of the np-Ox particles is not known, and the best Martian spectral analogues contain allophane-like materials and not crystalline phyllosilicates. We show here that laboratory VNIR and TES spectra of palagonitic alteration rinds developed on basaltic rocks are spectral endmembers that provide a consistent explanation for both VNIR and TES data of Martian dark regions.

  17. Modelling of thermal-IR spectra of forsterite: application on remote sensing for Mercury

    Science.gov (United States)

    Stangarone, C.; Helbert, J.; Maturilli, A.; Tribaudino, M.; Prencipe, M.

    2017-09-01

    In this work, we study experimental thermal emissivity spectra with an innovative approach: we calculate IR spectra, with ab initio methods, of the main mineral families that presumably compose the surface of Mercury and we compare them with high temperature laboratory measurements. The measurements will be carried out at the Institute of Planetary Research, Deutschen Zentrums für Luft und Raumfahrt (DLR) Planetary Spectroscopy Laboratory (PSL). The laboratory has the unique capability to obtain emissivity measurement of samples at temperature up to 1000K, by means of a planetary emissivity chamber. The goal is to interpret the high temperature infrared (HT-IR) emissivity spectra that will be collected by the Mercury Radiometer and Thermal infrared Imaging Spectrometer (MERTIS), the spectrometer developed by DLR that will be on board of the ESA BepiColombo Mercury Planetary Orbiter (MPO)

  18. Spreadsheet-Based Program for Simulating Atomic Emission Spectra

    Science.gov (United States)

    Flannigan, David J.

    2014-01-01

    A simple Excel spreadsheet-based program for simulating atomic emission spectra from the properties of neutral atoms (e.g., energies and statistical weights of the electronic states, electronic partition functions, transition probabilities, etc.) is described. The contents of the spreadsheet (i.e., input parameters, formulas for calculating…

  19. Voyager IRIS Measurements of Triton's Thermal Emission: Impllications for Pluto?

    Science.gov (United States)

    Stansberry, John A.; Spencer, John; Linscott, Ivan

    2015-11-01

    The New Horizons Pluto encounter data set includes unique observations obtained using the Radio Science experiment to measure the night-side thermal emission at centimeter wavelengths, well beyond the emission peak (in the 70 to 100 micron range). 26 years ago the Voyager 2 Infrared Interferometer Spectrometer (IRIS) obtained spectra in the 30 - 50 micron wavelength range to try and detect thermal emission from Pluto's sibling, Triton. Conrath etal. (1989) analyzed 16 of the IRIS spectra of Triton's dayside and derived a weak limit of 36 K - 41 K. We have analysed those, and an additional 75 spectra, to refine the limits on the temperature of Triton's surface, and to explore diurnal differences in the thermal emission. Triton results from other Voyager instruments provide important constraints on our interpretation of the IRIS data, as do Spitzer measurements of Pluto's thermal emission.For unit-emissivity, average temperature is 34 K, inconsistent with the pressure of Triton's atmosphere (13 - 19 microbar), the presence of beta-phase nitrogen ice on the surface, and the likely presence ofwarm regions on the surface. The atmospheric pressure requires nitrogen ice temperatures of 37.4 K - 38.1 K, which in turn requires emissivity of 0.31--0.53. Such a low emissivity in this spectral region might be expected if the surface is dominated by nitrogen or methane ice. Averages of data subsets show evidence for brightness temperature variations across Triton's surface. Surprisingly, the data seem to indicate that Triton's nightside equatorial region was warmer than on the dayside.These Voyager results for Triton provide a useful context for interpreting New Horizons and ALMA observations of emission from Pluto in the sub-millimeter and centimeter region. JWST will be capable of detecting Triton's and Pluto's 10 - 28 micron thermal emission, although scattered light from Neptune may be an issue for the Triton. Combined with new capabilities of ALMA to measure the sub

  20. Stratospheric HBr mixing ratio obtained from far infrared emission spectra

    Science.gov (United States)

    Park, J. H.; Carli, B.; Barbis, A.

    1989-01-01

    Emission features of HBr isotopes have been identified in high-resolution FIR emission spectra obtained with a balloon-borne Fourier-transform spectrometer in the spring of 1979 at 32 deg N latitude. When six single-scan spectra at a zenith angle of 93.2 deg were averaged, two features of HBr isotopes at 50.054 and 50.069/cm were obtained with a signal-to-noise ratio of 2.5. The volume mixing ratio retrieved from the average spectrum is 2.0 x 10 to the -11th, which is assumed to be constant above 28 km, with an uncertainty of 35 percent. This stratospheric amount of HBr is about the same as the current level of tropospheric organic bromine compounds, 25 pptv. Thus HBr could be the major stratospheric bromine species.

  1. Emission spectra of pyrotechnic mixtures of heat flux simulators

    Science.gov (United States)

    Azharonok, V. V.; Kratsko, L. E.; Chubryk, N. I.; Goncharik, S. V.; Miatselskaya, N. S.; Yakshonak, P. P.; Hamayunau, V. I.

    2012-01-01

    Comprehensive optical spectroscopic studies of the combustion process of solid-state pyrotechnic mixtures based on Mg and Sr(NO3)2 have been carried out. Emission spectra of the mixtures in the ultraviolet, visible, and infrared wavelength regions have been studied under various atmospheric conditions taking into account radiation transfer in air along an optical path of observation up to 5 km long.

  2. Thermal luminescence spectra of polyamides and their Maillard reaction with reducing sugars.

    Science.gov (United States)

    Karakisawa, Taketo; Yamada, Taishi; Sekine, Masahiko; Ishii, Hiroshi; Satoh, Chikahiro; Millington, Keith R; Nakata, Munetaka

    2012-01-01

    Thermal luminescence (TL) spectra of polyamides were measured with a Fourier-transform chemiluminescence spectrometer to elucidate the emission mechanism. A TL band of ε-polylysine with a peak at 542 nm observed at 403 K was assigned to the emission due to the interaction of the -CO-NH- group with oxygen molecules by comparison with nylon-6, polyglycine, and polyalanine. When the sample was kept at 453 K, the intensity of the TL band decreased and the wavelength of the peak shifted to 602 nm, which was assigned to the emission due to the interaction of the NH2 group on the side chain with oxygen molecules by comparison with monomeric lysine. A weak emission with a peak at 668 nm was assigned to the advanced glycosylation end products (AGEs) yielded by the Maillard reaction with a catalytic amount of water. To understand this reaction and to examine the TL emission of AGEs, we measured TL spectra of mixtures of polylysine and reducing sugars such as glucose, maltose, lactose, and dextrin. The minimum temperature for TL emission, wavelength of the peak and the relative intensities of the TL emission were found to depend on the size of the sugars. Copyright © 2011 John Wiley & Sons, Ltd.

  3. MGS SAMPLER THERMAL EMISSION SPECTROMETER GLOBAL TEMPERATURE

    Data.gov (United States)

    National Aeronautics and Space Administration — This archive contains Thermal Emission Spectrometer (TES) 25-micron global surface temperature data, collected during the ANS portion of the Mars Global Surveyor...

  4. Constraining hot Jupiter’s atmospheric structure and dynamics through Doppler shifted emission spectra

    Science.gov (United States)

    Zhang, Jisheng; Kempton, Eliza; Rauscher, Emily

    2017-01-01

    In recent years, astronomers have begun successfully observing the atmospheres of extrasolar planets using ground-based telescopes equipped with spectrographs capable of observing at high spectral resolution (R~105). Such studies are capable of diagnosing the atmospheric structure, composition, and dynamics (winds and rotation) of both transiting and non-transiting exoplanets. However, few studies have examined how the 3-D atmospheric dynamics could alter the emitted light of hot Jupiters at such high spectral resolution. Here, we present a model to explore such influence on the hot Jupiters’ thermal emission spectra. Our aim is to investigate the extent to which the effects of 3-D atmospheric dynamics are imprinted on planet-averaged thermal emission spectra. We couple together a 3-D general circulation model of hot Jupiter atmospheric dynamics (Rauscher & Menou, 2012) with a radiative transfer solver to predict the planet’s disk-integrated emission spectrum as a function of its orbital phase. For the first time, we self-consistently include the effects of the line-of-sight atmospheric motions (resulting from winds and rotation) in the calculation to produce Doppler-shifted spectral line profiles that result from the atmospheric dynamics. We focus our study on three benchmark hot Jupiters, HD 189733b, HD 209458b, and WASP-43b which have been the focus of previous detailed observational studies. We find that the high-resolution Doppler shifted thermal emission spectra can be used to diagnose key properties of the dynamical atmosphere - the planet’s longitudinal temperature and wind structure, and its rotation rate.

  5. Optical emission spectra of chromium doped nanocrystalline zinc gallate

    Science.gov (United States)

    Dhak, P.; Gayen, U. K.; Mishra, S.; Pramanik, P.; Roy, A.

    2009-09-01

    Optical emission spectra of nanocrystalline zinc gallate (ZnGa2O4) and trivalent chromium ion doped zinc gallate (ZnGa2O4:Cr3+) are reported for different concentrations of the dopant ion. The measurements have been carried out over the temperature range between 77 and 296 K. The emission spectrum of nanocrystalline ZnGa2O4 shows two broad peaks. The intensity variation in these peaks, with temperature, is indicative of the effect of symmetry breaking in the electronic band structure of ZnGa2O4 in nanocrystalline samples. In addition, we find that the relative intensities of the sharp spectral lines of Cr3+ in nanocrystalline ZnGa2O4:Cr3+ are quite different from those reported for corresponding bulk samples. The spectral profiles of the so-called R1, R2, N1, and N2 lines have also been studied. The data are analyzed using crystal field theory, which includes an exchange interaction between the nearest neighbor Cr3+ pairs in ZnGa2O4. We estimate the exchange parameters for Cr3+ in nanocrystalline ZnGa2O4:Cr3+. Though, in the literature, there exist reports on optical properties of the corresponding bulk spinel, our approach and consequent results on nanocrystalline ZnGa2O4:Cr3+ are not only interesting from the physics point of view but also can be of use in nanotechnology.

  6. Laboratory technique for quantitative thermal emissivity ...

    Indian Academy of Sciences (India)

    of Earth Sciences, IIT-Bombay is currently developing pure end mineral library of mineral parti- culates (<65μm), and adding new end members to the existing ASU spectral library. The paper argues the need for considering Lunar Orbiter Thermal Emission Spectrometer (LOTES) for future. Indian Moon mission programme ...

  7. Laboratory technique for quantitative thermal emissivity ...

    Indian Academy of Sciences (India)

    This laboratory at the Department of Earth Sciences, IIT-Bombay is currently developing pure end mineral library of mineral particulates (> 65 m), and adding new end members to the existing ASU spectral library. The paper argues the need for considering Lunar Orbiter Thermal Emission Spectrometer (LOTES) for future ...

  8. Fluorescence of Bacteria, Pollens, and Naturally Occurring Airborne Particles: Excitation/Emission Spectra

    National Research Council Canada - National Science Library

    Hill, Steven C; Mayo, Michael W; Chang, Richard K

    2009-01-01

    The fluorescence intensity as a function of excitation and emission wavelengths (EEM spectra) was measured for different species of bacteria, biochemical constituents of cells, pollens, and vegetation...

  9. Standoff laser-induced thermal emission of explosives

    Science.gov (United States)

    Galán-Freyle, Nataly Y.; Pacheco-Londoño, Leonardo C.; Figueroa-Navedo, Amanda; Hernandez-Rivera, Samuel P.

    2013-05-01

    A laser mediated methodology for remote thermal excitation of analytes followed by standoff IR detection is proposed. The goal of this study was to determine the feasibility of using laser induced thermal emission (LITE) from vibrationally excited explosives residues deposited on surfaces to detect explosives remotely. Telescope based FT-IR spectral measurements were carried out to examine substrates containing trace amounts of threat compounds used in explosive devices. The highly energetic materials (HEM) used were PETN, TATP, RDX, TNT, DNT and ammonium nitrate with concentrations from 5 to 200 μg/cm2. Target substrates of various thicknesses were remotely heated using a high power CO2 laser, and their mid-infrared (MIR) thermally stimulated emission spectra were recorded. The telescope was configured from reflective optical elements in order to minimize emission losses in the MIR frequencies and to provide optimum overall performance. Spectral replicas were acquired at a distance of 4 m with an FT-IR interferometer at 4 cm- 1 resolution and 10 scans. Laser power was varied from 4-36 W at radiation exposure times of 10, 20, 30 and 60 s. CO2 laser powers were adjusted to improve the detection and identification of the HEM samples. The advantages of increasing the thermal emission were easily observed in the results. Signal intensities were proportional to the thickness of the coated surface (a function of the surface concentration), as well as the laser power and laser exposure time. For samples of RDX and PETN, varying the power and time of induction of the laser, the calculated low limit of detections were 2 and 1 μg/cm2, respectively.

  10. Analysis of the high resolution Mg XI X-ray spectra. Pt. 3. Non-thermal interpretation of some spectra

    Energy Technology Data Exchange (ETDEWEB)

    Siarkowski, M.; Sylwester, J. (Polska Akademia Nauk, Wroclaw. Centrum Badan Kosmicznych); Bromboszcs, G. (Wroclaw Univ. (Poland). Obserwatorium Astronomiczne); Korneev, V.V.; Mandelshtam, S.L.; Oparin, S.N.; Urnov, A.M.; Zhitnik, I.A. (AN SSSR, Moscow. Fizicheskij Inst.)

    1982-11-01

    In part III of the paper containing the analysis of the INTERCOSMOS 16 ADP spectra, it is shown that by assuming the existence of a small admixture (1%) of non-thermal electrons in the active-region plasma it is possible to improve the agreement between measured and calculated fluxes for some spectra. The analysis follows the suggestion contained in the paper by Karev et al. (1980).

  11. Acidic weathering of basalt and basaltic glass: 1. Near-infrared spectra, thermal infrared spectra, and implications for Mars

    Science.gov (United States)

    Horgan, Briony H. N.; Smith, Rebecca J.; Cloutis, Edward A.; Mann, Paul; Christensen, Philip R.

    2017-01-01

    Acid-leached rinds and coatings occur in volcanic environments on Earth and have been identified using orbital spectroscopy on Mars, but their development is poorly understood. We simulated long-term open-system acidic weathering in a laboratory by repeatedly rinsing and submerging crystalline and glassy basalts in pH 1 and pH 3 acidic solutions for 213 days and compared their visible/near-infrared (0.3-2.5 µm) and thermal infrared (5-50 µm) spectral characteristics to their microscopic physical and chemical properties from scanning electron microscopy (SEM). We find that while alteration at moderately low pH ( 3) can produce mineral precipitates from solution, it has very little spectral or physical effect on the underlying parent material. In contrast, alteration at very low pH ( 1) results in clear silica spectral signatures for all crystalline samples while glasses exhibit strong blue concave-up near-infrared slopes. SEM indicates that these spectral differences correspond to different modes of alteration. In glass, alteration occurs only at the surface and produces a silica-enriched leached rind, while in more crystalline samples, alteration penetrates the interior to cause dissolution and replacement by silica. We confirm that glass is more stable than crystalline basalt under long-term acidic leaching, suggesting that glass could be enriched and common in terrains on Mars that have been exposed to acidic weathering. Leached glasses are consistent with both OMEGA and Thermal Emission Spectrometer (TES) spectra of the Martian northern lowlands and may contribute to the high-silica phases detected globally in TES Surface Type 2. Thus, both glass-rich deposits and acidic weathering may have been widespread on Mars.

  12. Modeling of aircraft exhaust emissions and infrared spectra for remote measurement of nitrogen oxides

    Directory of Open Access Journals (Sweden)

    K. Beier

    Full Text Available Infrared (IR molecular spectroscopy is proposed to perform remote measurements of NOx concentrations in the exhaust plume and wake of aircraft. The computer model NIRATAM is applied to simulate the physical and chemical properties of the exhaust plume and to generate low resolution IR spectra and synthetical thermal images of the aircraft in its natural surroundings. High-resolution IR spectra of the plume, including atmospheric absorption and emission, are simulated using the molecular line-by-line radiation model FASCODE2. Simulated IR spectra of a Boeing 747-400 at cruising altitude for different axial and radial positions in the jet region of the exhaust plume are presented. A number of spectral lines of NO can be identified that can be discriminated from lines of other exhaust gases and the natural atmospheric background in the region around 5.2 µm. These lines can be used to determine NO concentration profiles in the plume. The possibility of measuring nitrogen dioxide NO2 is also discussed briefly, although measurements turn out to be substantially less likely than those of NO. This feasibility study compiles fundamental data for the optical and radiometric design of an airborne Fourier transform spectrometer and the preparation of in-flight measurements for monitoring of aircraft pollutants.

  13. Modeling of aircraft exhaust emissions and infrared spectra for remote measurement of nitrogen oxides

    Directory of Open Access Journals (Sweden)

    K. Beier

    1994-08-01

    Full Text Available Infrared (IR molecular spectroscopy is proposed to perform remote measurements of NOx concentrations in the exhaust plume and wake of aircraft. The computer model NIRATAM is applied to simulate the physical and chemical properties of the exhaust plume and to generate low resolution IR spectra and synthetical thermal images of the aircraft in its natural surroundings. High-resolution IR spectra of the plume, including atmospheric absorption and emission, are simulated using the molecular line-by-line radiation model FASCODE2. Simulated IR spectra of a Boeing 747-400 at cruising altitude for different axial and radial positions in the jet region of the exhaust plume are presented. A number of spectral lines of NO can be identified that can be discriminated from lines of other exhaust gases and the natural atmospheric background in the region around 5.2 µm. These lines can be used to determine NO concentration profiles in the plume. The possibility of measuring nitrogen dioxide NO2 is also discussed briefly, although measurements turn out to be substantially less likely than those of NO. This feasibility study compiles fundamental data for the optical and radiometric design of an airborne Fourier transform spectrometer and the preparation of in-flight measurements for monitoring of aircraft pollutants.

  14. The Slowly Varying Corona. I. Daily Differential Emission Measure Distributions Derived from EVE Spectra

    Science.gov (United States)

    Schonfeld, S. J.; White, S. M.; Hock-Mysliwiec, R. A.; McAteer, R. T. J.

    2017-08-01

    Daily differential emission measure (DEM) distributions of the solar corona are derived from spectra obtained by the Extreme-ultraviolet Variability Experiment (EVE) over a 4 yr period starting in 2010 near solar minimum and continuing through the maximum of solar cycle 24. The DEMs are calculated using six strong emission features dominated by Fe lines of charge states viii, ix, xi, xii, xiv, and xvi that sample the nonflaring coronal temperature range 0.3-5 MK. A proxy for the non-Fe xviii emission in the wavelength band around the 93.9 Å line is demonstrated. There is little variability in the cool component of the corona (T 2.0 MK) varies by more than an order of magnitude. A discontinuity in the behavior of coronal diagnostics in 2011 February-March, around the time of the first X-class flare of cycle 24, suggests fundamentally different behavior in the corona under solar minimum and maximum conditions. This global state transition occurs over a period of several months. The DEMs are used to estimate the thermal energy of the visible solar corona (of order 1031 erg), its radiative energy loss rate ((2.5-8) × {10}27 erg s-1), and the corresponding energy turnover timescale (about an hour). The uncertainties associated with the DEMs and these derived values are mostly due to the coronal Fe abundance and density and the CHIANTI atomic line database.

  15. The impact of non-thermal electrons on event horizon scale images and spectra of Sgr A*

    Science.gov (United States)

    Mao, S. Alwin; Dexter, Jason; Quataert, Eliot

    2017-04-01

    Decomposing an arbitrary electron energy distribution into sums of Maxwellian and power-law components is an efficient method to calculate synchrotron emission and absorption. We use this method to study the effect of non-thermal electrons on submillimetre images and spectra of the Galactic Centre black hole, Sgr A*. We assume a spatially uniform functional form for the electron distribution function and use a semi-analytic radiatively inefficient accretion flow and a 2D general relativistic magnetohydrodynamic snapshot as example models of the underlying accretion flow structure. We develop simple analytic models that allow us to generalize from the numerical examples. A high-energy electron component containing a small fraction (few per cent) of the total internal energy (e.g. a 'power-law tail') can produce a diffuse halo of emission, which modifies the observed image size and structure. A population of hot electrons with a larger energy fraction (e.g. resulting from a diffusion in electron energy space) can dominate the emission, so that the observed images and spectra are well approximated by considering only a single thermal component for a suitable choice of the electron temperature. We discuss the implications of these results for estimating accretion flow or black hole parameters from images and spectra, and for the identification of the black hole 'shadow' in future millimetre-very long baseline interferometry data. In particular, the location of the first minimum in visibility profiles does not necessarily correspond to the shadow size as sometimes assumed.

  16. Miniature thermal emission spectrometer for the Mars Exploration Rover

    Science.gov (United States)

    Silverman, Steven; Peralta, Richard; Christensen, Phil; Mehall, Greg

    2006-10-01

    This paper describes results of the calibration of the miniature thermal emission spectrometer (Mini-TES) being built by Raytheon Santa Barbara Remote Sensing (SBRS) under contract to Arizona State University (ASU). This paper also serves as an update to an earlier paper [R.J. Peralta, S. Silverman, D. Bates, Raytheon/Santa Barbara Remote Sensing, P. Christensen, G. Mehall, T. Tourville, R. Keehn, G. Cannon, Arizona State University, Miniature thermal emission spectrometer for the Mars Exploration Rover, Proceedings of the SPIE, vol. 4485-09, August 2001] for mission description and instrument design. Mini-TES is a single detector Fourier transform spectrometer (FTS), covering the spectral range 5 29μm at 10cm spectral resolution. Launched in June 2003, one Mini-TES instrument will fly to Mars aboard each of the two missions of NASA's Mars Exploration Rover Project (MER), named Spirit and Opportunity. Mini-TES is designed to provide a key minerological remote sensing component of the MER mission, which includes several other science instruments. The first Mini-TES unit was required to meet a two-year development schedule with proven, flight-tested instrumentation. Therefore, SBRS designed Mini-TES based on proven heritage from the successful Mars Global Surveyor (MGS) thermal emission spectrometer (TES), which was launched in 1996 and is still operational with over 500 million spectra collected to date. Mini-TES design, performance, integration onto the rovers, as well as details of the calibration are discussed. Full instrument and calibration details are the subject of an upcoming Journal of Geophysical Research Mini-TES paper by Christensen, et al.

  17. Perfect Thermal Emission by Nanoscale Transmission Line Resonators.

    Science.gov (United States)

    Liu, Baoan; Gong, Wei; Yu, Bowen; Li, Pengfei; Shen, Sheng

    2017-02-08

    Thermal radiation with a narrow-band emission spectrum is of great importance in a variety of applications such as infrared sensing, thermophotovoltaics, radiation cooling, and thermal circuits. Although resonant nanophotonic structures such as metamaterials and nanocavities have been demonstrated to achieve the narrow-band thermal emission, maximizing their radiation power toward perfect emission still remains challenging. Here, based on the recently developed quasi-normal mode theory, we prove that thermal emission from a nanoscale transmission line resonator can always be maximized by tuning the waveguiding loss of the resonator or bending the structure. By use of nanoscale transmission line resonators as basic building blocks, we experimentally demonstrate a new type of macroscopic perfect and tunable thermal emitters. Our experimental demonstration in conjunction with the general theoretical framework from the quasi-normal mode theory lays the foundation for designing tunable narrow-band thermal emitters with applications in thermal infrared light sources, thermal management, and infrared sensing and imaging.

  18. Imaging Emission Spectra with Handheld and Cellphone Cameras

    Science.gov (United States)

    Sitar, David

    2012-01-01

    As point-and-shoot digital camera technology advances it is becoming easier to image spectra in a laboratory setting on a shoestring budget and get immediate results. With this in mind, I wanted to test three cameras to see how their results would differ. Two undergraduate physics students and I used one handheld 7.1 megapixel (MP) digital Cannon…

  19. Wavelength-selective and diffuse infrared thermal emission mediated by magnetic polaritons from silicon carbide metasurfaces

    Science.gov (United States)

    Yang, Yue; Taylor, Sydney; Alshehri, Hassan; Wang, Liping

    2017-07-01

    In the present study, we experimentally demonstrate the spectrally coherent and diffuse thermal emission by exciting magnetic polaritons in SiC metasurfaces fabricated by the focused ion beam technique. Spectral emittance characterized by using an infrared microscope coupled to a Fourier transform spectrometer clearly shows a wavelength-selective emission peak as high as 0.8. Numerical simulations including emittance spectra and contour plot of electromagnetic field distribution were carried out to verify and understand the underlying mechanism of magnetic polaritons. The metasurfaces were further shown to be direction and polarization independent. The results would facilitate metasurfaces for applications like radiative thermal management and infrared sensing.

  20. [A new automated method to identify emission line star from massive spectra].

    Science.gov (United States)

    Pan, Jing-Chang; Zhang, Cai-Ming; Wei, Peng; Luo, A-Li; Zhao, Yong-Heng

    2012-06-01

    Stellar spectra are characterized by obvious absorption lines or absorption bands, while those with emission lines are usually special stars such as cataclysmic variable stars (CVs), HerbigAe/Be etc. The further study of this kind of spectra is meaningful. The present paper proposed a new method to identify emission line stars (ELS) spectra automatically. After the continuum normalization is done for the original spectral flux, line detection is made by comparing the normalized flux with the mean and standard deviation of the flux in its neighbor region The results of the experiment on massive spectra from SDSS DR8 indicate that the method can identify ELS spectra completely and accurately. Since no complex transformation and computation are involved in this method, the identifying process is fast and it is ideal for the ELS detection in large sky survey projects like LAMOST and SDSS.

  1. BET, thermal degradation, and FTIR spectras of triazine polyamine polymers

    Directory of Open Access Journals (Sweden)

    Mustafa Can

    2017-04-01

    Full Text Available Here we show effect of the polyamine polymer chain length to BET isotherms. According to IUPAC classification [1], all three polymers are fitting type 1 physical adsorption isotherm with H3 hysteresis (except for EDA having H2 hysteresis. Moreover, TG and TGA analysis of polymers triazine-ethylenediamine (EDA and triazine-triethylenetetramine (TETA are provided. Due to the similarities of the structure, main decomposition temperatures are close to each other (between 593 K and 873 K. In order to understand change of FTIR spectra with adsorption and stripping Au(III, fresh, Au(III adsorbed and recycled spectras of polymers measured. For further discussions about the effect of chain length to adsorption of Au(III onto triazine polyamine polymer particles “Au (III Uptake by Triazine Polyamine Polymers: Mechanism, Kinetic and Equilibrium Studies” Can et al. [2] (article in press.

  2. Correlation between optical emission spectra and the process ...

    Indian Academy of Sciences (India)

    Many researchers have studied H2 and H2-CH4 mixed plasma in different types of reactors such as hot filament ... and microwave power for H2–CH4 gas mixture inside a 2.45 GHz microwave plasma reactor. Tan & Grotjohn .... Optical emission spectrometer consists of sub-components like optical fibre, slit, optical filter,.

  3. Description of the RHIC p(perpendicular) spectra in a thermal model with expansion.

    Science.gov (United States)

    Broniowski, W; Florkowski, W

    2001-12-31

    The assumption of simultaneous chemical and thermal freeze-outs of the hadron gas leads to a surprisingly accurate, albeit entirely conventional, explanation of the recently measured RHIC p(perpendicular) spectra. The original thermal spectra are supplied with secondaries from cascade decays of all resonances, and subsequently folded with a suitably parametrized expansion involving longitudinal and transverse flow. The predictions of this thermal approach, with various parametrizations for the expansion, are in a striking quantitative agreement with the data in the whole available range of 0 < or = p(perpendicular) < or = 3.5 GeV.

  4. Identification of microcrystalline rocks using thermal emission spectroscopy

    Science.gov (United States)

    Hardgrove, C. J.; Rogers, D.; Glotch, T. D.; Arnold, J. A.

    2015-12-01

    High-silica deposits on Mars have been discovered from orbit (Holden Crater, Mawrth Vallis) and from landed surface missions to both Gusev Crater (Spirit) and Gale Crater (Curiosity). The character of these silica deposits can be used to understand both the depositional environment (i.e. fumarole vs. sinter) and/or diagenetic process. Initial work has shown that, in the case of opaline silica, there are differences in spectral shape that may be related to surface textural features imparted during formation or post-depositional alteration. Due to the increasing importance of understanding microcrystalline deposits on Mars, here, we study the effects of crystal size and surface roughness on thermal infrared emission spectra of micro- and macro-crystalline quartz. The spectra of chert and macro-crystalline quartz have significant differences in both spectral contrast, and in the rounded doublet between ~1000-1250 cm-1, which can shift and appear less rounded in microcrystalline samples. We find that microcrystalline minerals exhibit naturally rough surfaces compared to their macrocrystalline counterparts at the 10 micron scale; and that this roughness causes distinct spectral differences within the Reststrahlen bands. We find that surface roughness, if rough on the scale of the wavelengths where the wavelength-dependent absorption coefficient (k) is large, can cause not only decreased spectral contrast, but also substantial changes in spectral shape. The spectral shape differences are small enough that the composition of the material is still recognizable, but large enough such that a roughness effect could be detected. We find that my studying the thermal infrared spectral character of the sample, it may be possible to make general inferences about microcrystallinity, and thus aid in the potential reconstruction of sedimentary rock diagenesis.

  5. Excitation Spectra of Carbon Nuclei near η ' Emission Threshold

    Science.gov (United States)

    Itahashi, Kenta; Ayyad, Yassid; Benlliure, Jose; Brinkmann, Kai-Thomas; Friedrich, Stefan; Fujioka, Hiroyuki; Geissel, Hans; Gellanki, Jnaneswari; Guo, Chenlei; Gutz, Eric; Haettner, Emma; Harakeh, Muhsin N.; Hayano, Ryugo S.; Higashi, Yuko; Hirenzaki, Satoru; Hornung, Christine; Igarashi, Yoichi; Ikeno, Natsumi; Iwasaki, Masahiko; Jido, Daisuke; Kalantar-Nayestanaki, Nasser; Kanungo, Rituparna; Knoebel, Ronja; Kurz, Nikolaus; Metag, Volker; Mukha, Ivan; Nagae, Tomofumi; Nagahiro, Hideko; Nanova, Mariana; Nishi, Takahiro; Ong, Hooi Jin; Pietri, Stephane; Prochazka, Andrej; Rappold, Christophe; Reiter, Moritz P.; Rodríguez-Sánchez, José L.; Scheidenberger, Christoph; Simon, Haik; Sitar, Branislav; Strmen, Peter; Sun, Baohua; Suzuki, Ken; Szarka, Imrich; Takechi, Maya; Tanaka, Yoshiki K.; Tanihata, Isao; Terashima, Satoru; Watanabe, Yuni N.; Weick, Helmut; Widmann, Eberhard; Winfield, John S.; Xu, Xiaodong; Yamakami, Hiroki; Zhao, Jianwei

    We measured an excitation spectrum of 12C(p, d) reaction near the η' emission threshold using a 2.5 GeV proton beam. The measured spectrum shows no peak structures which are associated to formation of η'-mesic nuclei. Further analysis is ongoing to deduce upper limits of the formation cross section and to set constraints in the η'-nucleus interaction.

  6. [Emission spectra of hydroxyl radical generated in air corona discharge].

    Science.gov (United States)

    Sun, Ming; Wu, Yan; Zhang, Jia-Liang; Li, Jie; Wang, Ning-Hui; Wu, Jiang; Shang, Ke-Feng

    2005-01-01

    In this paper, the relative emission intensity of the 309 nm transition band of hydroxyl radical (OH) was measured by a CCD imaging spectrometer in a pin-plane corona discharge scheme of one atmosphere pressure air injected with unsaturated water vapor from the central hole of the used pins. The influences of several factors on the OH radical production were investigated by relative emission intensity measurement. The production of OH radical increased with a limited increment of water vapor concentration in the mixed gas. Compared with positive DC corona discharges, more OH radicals were generated in positive pulsed corona discharges and less in negative DC corona discharges. The spatial distribution of OH radical production was also observed. Most OH radicals were produced within the range of 5 mm off the discharge pin electrode. In conclusion, this means of optical emission spectroscopy, compared with more sophisticated laser fluorescence measurements used for plasma OH production diagnostics investigation, is simpler and more effective for characterizing the OH radical potential for pollutant oxidation.

  7. Selective thermal emission from thin-film metasurfaces

    Science.gov (United States)

    Streyer, W.; Law, S.; Mason, J.; Adams, D. C.; Rooney, G.; Jacobs, T.; Wasserman, D.

    2013-09-01

    The mid-infrared (mid-IR), as the spectral range where all finite temperature biological and mechanical objects emit thermal radiation, and where numerous molecular species have strong vibrational absorption resonances, is of significant importance for both security and sensing applications. The design of materials with engineered absorption resonances, which by Kirchoff's Law, should give strongly selective emission at the design resonance upon thermal excitation, allows for the control of the spectral character of the material's thermal emission. Designed as a thin film coating, these structures can be applied to grey-body emitters to shift the grey-body thermal emission into predetermined spectral bands, altering their appearance on a thermal imaging system. Here we demonstrate strongly selective mid-infrared absorption and thermal emission from three classes of subwavelength thin-film materials. First, we demonstrate selective thermal emission from patterned, commerciallyavailable steel films, via selective out-coupling of thermally-excited surface modes. Subsequently, we show nearperfect absorption (and strongly selective thermal emission) for wavelengths between 5 - 9μm with patterned metal-dielectric-metal structures. Finally, we demonstrate strong absorption from large area, unpatterned, thinfilm high-index dielectric coatings on highly-doped Si substrates, tunable across the mid-IR (5 - 12μm). Our results are compared to numerical simulations, as well as analytical models, with good agreement between experiments and models.

  8. Noise and Signal for Spectra of Intermittent Noiselike Emission

    Science.gov (United States)

    Gwinn, C. R.; Johnson, M. D.

    2011-05-01

    We show that intermittency of noiselike emission, after propagation through a scattering medium, affects the distribution of noise in the observed correlation function. Intermittency also affects correlation of noise among channels of the spectrum, but leaves the average spectrum, average correlation function, and distribution of noise among channels of the spectrum unchanged. Pulsars are examples of such sources: intermittent and affected by interstellar propagation. We assume that the source emits Gaussian white noise, modulated by a time envelope. Propagation convolves the resulting time series with an impulse-response function that represents effects of dispersion, scattering, and absorption. We assume that this propagation kernel is shorter than the time for an observer to accumulate a single spectrum. We show that rapidly varying intermittent emission tends to concentrate noise near the central lag of the correlation function. We derive mathematical expressions for this effect, in terms of the time envelope and the propagation kernel. We present examples, discuss effects of background noise, and compare our results with observations.

  9. Kirchhoff's Law of Thermal Emission: 150 Years

    Directory of Open Access Journals (Sweden)

    Robitaille P.-M.

    2009-10-01

    Full Text Available In this work, Kirchhoff's law (Kirchhoff G. Monatsberichte der Akademie der Wissenschaften zu Berlin, sessions of Dec. 1859, 1860, 783-787 is being revisited not only to mark its 150th anniversary but, most importantly, to highlight serious overreaching in its formulation. At the onset, Kirchhoff's law correctly outlines the equivalence between emission and absorption for an opaque object under thermal equilibrium. This same conclusion had been established earlier by Balfour Stewart (Stewart B. Trans. Royal Soc. Edinburgh, 1858, v.22(1, 1-20. However, Kirchhoff extends the treatment beyond his counterpart, stating that cavity radiation must always be black, or normal: depending only on the temperature and the frequency of observation. This universal aspect of Kirchhoff's law is without proper basis and constitutes a grave distortion of experimental reality. It is readily apparent that cavities made from arbitrary materials ($varepsilon < 1$ are never black. Their approach to such behavior is being driven either by the blackness of the detector, or by black materials placed near the cavity. Ample evidence exists that radiation in arbitrary cavities is sensitive to the relative position of the detectors. In order to fully address these issues, cavity radiation and the generalization of Kirchhoff's law are discussed. An example is then taken from electromagnetics, at microwave frequencies, to link results in the resonant cavity with those inferred from the consequences of generalization.

  10. Kirchhoff's Law of Thermal Emission: 150 Years

    Directory of Open Access Journals (Sweden)

    Robitaille P.-M.

    2009-10-01

    Full Text Available n this work, Kirchhoff’s law (Kirchhoff G. Monatsberichte der Akademie der Wis- senschaften zu Berlin , sessions of Dec. 1859, 1860, 783–787 is being revisited not only to mark its 150th anniversary but, most importantly, to highlight serious overreaching in its formulation. At the onset, Kirchhoff’s law correctly outlines the equivalence be- tween emission and absorption for an opaque object under thermal equilibrium. This same conclusion had been established earlier by Balfour Stewart (Stewart B. Trans. Royal Soc. Edinburgh , 1858, v. 22(1, 1–20. However, Kirchhoff extends the treatment beyond his counterpart, stating that cavity radiation must always be black, or normal: depending only on the temperature and the frequency of observation. This universal aspect of Kirchhoff’s law is without proper basis and constitutes a grave distortion of experimental reality. It is readily apparent that cavities made from arbitrary materials ( " < 1 are never black. Their approach to such behavior is being driven either by the blackness of the detector, or by black materials placed near the cavity. Ample evidence exists that radiation in arbitrary cavities is sensitive to the relative position of the de- tectors. In order to fully address these issues, cavity radiation and the generalization of Kirchhoff’s law are discussed. An example is then taken from electromagnetics, at microwave frequencies, to link results in the resonant cavity with those inferred from the consequences of generalization.

  11. Thermal, vibrational spectra and photoluminescence properties of the nonlinear optical material MnTeMoO6

    Science.gov (United States)

    Jin, Chengguo; Shao, Juxiang; Li, Zhen; Yang, Junsheng; Cao, Qilong; Huang, Duohui; Wan, Mingjie; Wang, Fanhou

    2015-04-01

    MnTeMoO6 is a novel nonlinear optical material in near-mid-IR region. Vibrational spectra characterization, thermal and photoluminescent properties of polycrystalline MnTeMoO6 have been investigated in this work. The results show that polycrystalline MnTeMoO6 has a relatively high melting point at 725.2 °C and exhibits superheating of crystal. The observed Raman and IR bands of MnTeMoO6 are assigned to vibrations of the Mn-O bonds, MoO4 tetrahedra, and TeO4 polyhedra. Photoluminescence measurements show that MnTeMoO6 displays a strong emission peak at 467 nm under excitation at 280 nm, and the absorption band at 0.47-0.52 μm in UV-vis spectra may be caused by photoluminescence.

  12. Mössbauer Emission-Spectra of Impurity Cobalt-57 in a Halide Matrix

    DEFF Research Database (Denmark)

    Maddock, A. G.; Williams, A. F.; Siekierska, K. E.

    1976-01-01

    The Mössbauer emission spectra of 57Co in low concentrations in KF, NaCl, NaF, LiF, and MgF2, and the effects of doping NaF and LiF with La3+ ions are reported. The monovalent halides all give similar spectra showing a broad single line or a doublet at 2.19mm/s and two overlapping doublets at 0...

  13. Study of Ultraviolet Emission Spectra in ZnO Thin Films

    Directory of Open Access Journals (Sweden)

    Y. M. Lu

    2013-01-01

    Full Text Available Photoluminescence (PL of ZnO thin films prepared on c-Al2O3 substrates by pulsed laser deposition (PLD are investigated. For all samples, roomtemperature (RT spectra show a strong band-edge ultraviolet (UV emission with a pronounced low-energy band tail. The origin of this UV emission is analyzed by the temperature dependence of PL spectra. The result shows that the UV emission at RT contains different recombination processes. At low temperature donor-bound exciton (D0X emission plays a major role in PL spectra, while the free exciton transition (FX gradually dominates the spectrum with increasing temperatures. It notes that at low temperature an emission band (FA appears in low energy side of D0X and FX and can survive up to RT. Further confirmation shows that the origin of the band FA can be attributed to the transitions of conduction band electrons to acceptors (e, A0, in which the acceptor binding energy is estimated to be approximately 121 meV. It is concluded that at room temperature UV emission originates from the corporate contributions of the free exciton and free electrons-to-acceptor transitions.

  14. Discernment of lint trash in raw cotton using multivariate analysis of excitation-emission luminescence spectra

    Science.gov (United States)

    Excitation-Emission luminescence spectra of basic (pH 12.5) phosphate buffer solution extracts were used to distinguish among botanical components of trash within seed cotton. All components were separated from whole plants removed from a field in southern New Mexico. Unfolded Principal Component An...

  15. Retrieval of leaf water content spanning the visible to thermal infrared spectra

    CSIR Research Space (South Africa)

    Ullah, S

    2014-05-01

    Full Text Available The objective of this study was to investigate the entire spectra (from visible to the thermal infrared; 0.390 µm -14.0 µm) to retrieve leaf water content in a consistent manner. Narrow-band spectral indices (calculated from all possible two band...

  16. Low thermal emissivity surfaces using AgNW thin films

    Science.gov (United States)

    Pantoja, Elisa; Bhatt, Rajendra; Liu, Anping; Gupta, Mool C.

    2017-12-01

    The properties of silver nanowire (AgNW) films in the optical and infrared spectral regime offer an interesting opportunity for a broad range of applications that require low-emissivity coatings. This work reports a method to reduce the thermal emissivity of substrates by the formation of low-emissivity AgNW coating films from solution. The spectral emissivity was characterized by thermal imaging with an FLIR camera, followed by Fourier transform infrared spectroscopy. In a combined experimental and simulation study, we provide fundamental data of the transmittance, reflectance, haze, and emissivity of AgNW thin films. Emissivity values were finely tuned by modifying the concentration of the metal nanowires in the films. The simulation models based on the transfer matrix method developed for the AgNW thin films provided optical values that show a good agreement with the measurements.

  17. Broadening of the thermal component of the prompt GRB emission due to rapid temperature evolution

    Science.gov (United States)

    Bharali, Priya; Sahayanathan, Sunder; Misra, Ranjeev; Boruah, Kalyanee

    2017-08-01

    The observations of the prompt emission of gamma ray bursts (GRB) by GLAST Burst Monitor (GBM), on board Fermi Gamma-ray Space Telescope, suggest the presence of a significant thermal spectral component, whose origin is not well understood. Recently, it has been shown that for long duration GRBs, the spectral width as defined as the logarithm of the ratio of the energies at which the spectrum falls to half its peak value, lie in the range of 0.84-1.3 with a median value of 1.07. Thus, while most of the GRB spectra are found to be too narrow to be explained by synchrotron emission from an electron distribution, they are also significantly broader than a blackbody spectrum whose width should be 0.54. Here, we consider the possibility that an intrinsic thermal spectrum from a fire-ball like model, may be observed to be broadened if the system undergoes a rapid temperature evolution. We construct a toy-model to show that for bursts with durations in the range 5-70 s, the widths of their 1 second time-averaged spectra can be at the most ≲ 0.557. Thus, while rapid temperature variation can broaden the detected spectral shape, the observed median value of ˜ 1.07 requires that there must be significant sub-photospheric emission and/or an anisotropic explosion to explain the broadening for most GRB spectra.

  18. Optical emission spectra of ZnMnO plasma produced by a pulsed laser

    Science.gov (United States)

    Uzuriaga, J.; Chamorro, J. C.; Marín, R. A.; Riascos, H.

    2012-06-01

    Optical emission lines from the plasma generated by a laser ablation process have been investigated to gather information on the nature of the chemical species present. In particular, the experiments were carried out during the laser ablation of a ZnMnO target, in presence of a controlled oxygen atmosphere. The resolved emission spectra are dominated by the atomic neutral or singly ionized emission lines from Zn species, while the Mn I line was detected in emission spectrum at 40 mTorr only. The background continuum, intensities and widths of all observed lines increased with increasing gas pressure. The electron density and electron temperature were calculated for various gas pressures. The electron density was found to increase with the increment of the argon gas pressure, whereas electron temperature decreased. The electron temperature and density are found to be similar to those obtained in the well-known pulsed laser deposition (PLD) process.

  19. Wide-field microscopic FRET imaging using simultaneous spectral unmixing of excitation and emission spectra.

    Science.gov (United States)

    Du, Mengyan; Zhang, Lili; Xie, Shusen; Chen, Tongsheng

    2016-07-11

    Simultaneous spectral unmixing of excitation and emission spectra (ExEm unmixing) has the inherent ability to resolve donor emission, fluorescence resonance energy transfer (FRET)-sensitized acceptor emission and directly excited acceptor emission. We here develop an ExEm unmixing-based quantitative FRET measurement method (EES-FRET) independent of excitation intensity and detector parameter setting. The ratio factor (rK), predetermined using a donor-acceptor tandem construct, of total acceptor absorption to total donor absorption in excitation wavelengths used is introduced for determining the concentration ratio of acceptor to donor. We implemented EES-FRET method on a wide-field microscope to image living cells expressing tandem FRET constructs with different donor-acceptor stoichiometry.

  20. Searching for Dwarf H Alpha Emission-line Galaxies within Voids III: First Spectra

    Science.gov (United States)

    Moody, J. Ward; Draper, Christian; McNeil, Stephen; Joner, Michael D.

    2017-02-01

    The presence or absence of dwarf galaxies with {M}r\\prime > -14 in low-density voids is determined by the nature of dark matter halos. To better understand what this nature is, we are conducting an imaging survey through redshifted Hα filters to look for emission-line dwarf galaxies in the centers of two nearby galaxy voids called FN2 and FN8. Either finding such dwarfs or establishing that they are not present is a significant result. As an important step in establishing the robustness of the search technique, we have observed six candidates from the survey of FN8 with the Gillett Gemini telescope and GMOS spectrometer. All of these candidates had emission, although none was Hα. The emission in two objects was the [O iii]λ4959, 5007 doublet plus Hβ, and the emission in the remaining four was the [O ii]λ3727 doublet, all from objects beyond the void. While no objects were within the void, these spectra show that the survey is capable of finding emission-line dwarfs in the void centers that are as faint as {M}r\\prime ˜ -12.4, should they be present. These spectra also show that redshifts estimated from our filtered images are accurate to several hundred km s-1 if the line is identified correctly, encouraging further work in finding ways to conduct redshift surveys through imaging alone.

  1. Statistical simulation of the energy spectra of field-emission electrons

    Science.gov (United States)

    Egorov, N. V.; Antonov, A. Yu.; Demchenko, N. S.

    2017-02-01

    Random energies of electrons that escape from the source in the course of field emission are simulated using energy spectra. A relationship of the random values of total energy and the energy related to the normal (with respect to surface) component of momentum is established. A family of quadrature formulas needed for the integration of the distribution density of particles is analyzed. A hypothesis on the compliance of selected random energies with desired distribution laws is statistically tested.

  2. Lifetime-vibrational interference effects in resonantly excited x-ray emission spectra of CO

    Energy Technology Data Exchange (ETDEWEB)

    Skytt, P.; Glans, P.; Gunnelin, K. [Uppsala Univ. (Sweden)] [and others

    1997-04-01

    The parity selection rule for resonant X-ray emission as demonstrated for O{sub 2} and N{sub 2} can be seen as an effect of interference between coherently excited degenerate localized core states. One system where the core state degeneracy is not exact but somewhat lifted was previously studied at ALS, namely the resonant X-ray emission of amino-substituted benzene (aniline). It was shown that the X-ray fluorescence spectrum resulting from excitation of the C1s at the site of the {open_quotes}aminocarbon{close_quotes} could be described in a picture separating the excitation and the emission processes, whereas the spectrum corresponding to the quasi-degenerate carbons could not. Thus, in this case it was necessary to take interference effects between the quasi-degenerate intermediate core excited states into account in order to obtain agreement between calculations and experiment. The different vibrational levels of core excited states in molecules have energy splittings which are of the same order of magnitude as the natural lifetime broadening of core excitations in the soft X-ray range. Therefore, lifetime-vibrational interference effects are likely to appear and influence the band shapes in resonant X-ray emission spectra. Lifetime-vibrational interference has been studied in non-resonant X-ray emission, and in Auger spectra. In this report the authors discuss results of selectively excited soft X-ray fluorescence spectra of molecules, where they focus on lifetime-interference effects appearing in the band shapes.

  3. Excitation-emission spectra and fluorescence quantum yields for fresh and aged biogenic secondary organic aerosols

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Hyun Ji; Laskin, Alexander; Laskin, Julia; Nizkorodov, Sergey A.

    2013-05-10

    Certain biogenic secondary organic aerosols (SOA) become absorbent and fluorescent when exposed to reduced nitrogen compounds such as ammonia, amines and their salts. Fluorescent SOA may potentially be mistaken for biological particles by detection methods relying on fluorescence. This work quantifies the spectral distribution and effective quantum yields of fluorescence of SOA generated from two monoterpenes, limonene and a-pinene, and two different oxidants, ozone (O3) and hydroxyl radical (OH). The SOA was generated in a smog chamber, collected on substrates, and aged by exposure to ~100 ppb ammonia vapor in air saturated with water vapor. Absorption and excitation-emission matrix (EEM) spectra of aqueous extracts of aged and control SOA samples were measured, and the effective absorption coefficients and fluorescence quantum yields (~0.005 for 349 nm excitation) were determined from the data. The strongest fluorescence for the limonene-derived SOA was observed for excitation = 420+- 50 nm and emission = 475 +- 38 nm. The window of the strongest fluorescence shifted to excitation = 320 +- 25 nm and emission = 425 +- 38 nm for the a-pinene-derived SOA. Both regions overlap with the excitation-emission matrix (EEM) spectra of some of the fluorophores found in primary biological aerosols. Our study suggests that, despite the low quantum yield, the aged SOA particles should have sufficient fluorescence intensities to interfere with the fluorescence detection of common bioaerosols.

  4. Extraction of Curcumin Pigment from Indonesian Local Turmeric with Its Infrared Spectra and Thermal Decomposition Properties

    Science.gov (United States)

    Nandiyanto, A. B. D.; Wiryani, A. S.; Rusli, A.; Purnamasari, A.; Abdullah, A. G.; Ana; Widiaty, I.; Hurriyati, R.

    2017-03-01

    Curcumin is one of the pigments which is used as a spice in Asian cuisine, traditional cosmetic, and medicine. Therefore, process for getting curcumin has been widely studied. Here, the purpose of this study was to demonstrate the simple method for extracting curcumin from Indonesian local turmeric and investigate the infrared spectra and thermal decomposition properties. In the experimental procedure, the washed turmeric was dissolved into an ethanol solution, and then put into a rotary evaporator to enrich curcumin concentration. The result showed that the present method is effective to isolate curcumin compound from Indonesian local turmeric. Since the process is very simple, this method can be used for home industrial application. Further, understanding the thermal decomposition properties of curcumin give information, specifically relating to the selection of treatment when curcumin must face the thermal-related process.

  5. Low temperature emission spectra of optically nonlinear N-benzyl-2-methyl-4-nitroaniline crystal

    Energy Technology Data Exchange (ETDEWEB)

    Piela, Katarzyna [Institute of Physical and Theoretical Chemistry, Wroclaw University of Technology, Wybrzeze Wyspianskiego 27, 50-370 Wroclaw (Poland); Kozankiewicz, Boleslaw [Institute of Physics, Polish Academy of Sciences, Al. Lotnikow 32/46, 02-668 Warszawa (Poland); Lipinski, Jozef [Institute of Physical and Theoretical Chemistry, Wroclaw University of Technology, Wybrzeze Wyspianskiego 27, 50-370 Wroclaw (Poland); Magdalena Szostak, M., E-mail: magdalena.m.szostak@pwr.wroc.pl [Institute of Physics, Polish Academy of Sciences, Al. Lotnikow 32/46, 02-668 Warszawa (Poland)

    2012-08-24

    Highlights: Black-Right-Pointing-Pointer Temperature dependent fluorescence and phosphorescence spectra of BNA crystal. Black-Right-Pointing-Pointer Molecular character of fluorescence in BNA crystal. Black-Right-Pointing-Pointer Vibronic structure of fluorescence is attributed to nitro group vibrations. Black-Right-Pointing-Pointer Phosphorescence originates from shallow traps depopulated above 30 K. Black-Right-Pointing-Pointer Intramolecular charge transfer enhanced by N-benzyl substitution of BNA. -- Abstract: The fluorescence and phosphorescence spectra of N-benzyl-2-methyl-4-nitroaniline (BNA) orthorhombic crystal were measured between 5 and 200 K. The fluorescence spectrum of BNA in a Shpol'skii matrix of n-heptane was also recorded at 5 K. The electronic absorption spectra parameters such as singlet and triplet state energies, dipole moments and oscillator strengths were calculated by semi-empirical and TD DFT methods. The calculated energies of singlet and triplet states and electronic transitions in the BNA molecule were compared with the experimental results. The phosphorescence decay time was estimated to be 270 ms at 5 K. It is presumed that the disappearance of vibronic structure above 30 K observed in the fluorescence spectra is caused by the nitro group vibrations while the structured phosphorescence originates from the trap states. The role of molecular shape towards emission processes in BNA crystal in terms of structure-property relationship is discussed.

  6. Comparative study of the thermal performance and emission levels ...

    African Journals Online (AJOL)

    Comparative study of the thermal performance and emission levels of an existing and modified coal/biomass burning stove. ... The stove was charged with jive (5) selected wood species and a number of parameters, such as temperature projile amI flue gas composition were measured. Experimental evidence points to an ...

  7. Quantitative absorption spectra of quantum wires measured by analysis of attenuated internal emissions

    Science.gov (United States)

    Yoshita, Masahiro; Okada, Takayuki; Akiyama, Hidefumi; Okano, Makoto; Ihara, Toshiyuki; Pfeiffer, Loren N.; West, Ken W.

    2012-03-01

    An absorption-spectroscopy method that utilizes internal emissions as the source of the probe light was used to measure the absorption spectra of quasi-one-dimensional (q-1D) excitons in T-shaped quantum wires embedded in an optical waveguide. The modal absorption area of the 1D ground-state excitons was estimated to be 0.39 eV cm-1 and was almost independent of temperature in the range 4-150 K. Quantitative evaluation using the absorption spectra revealed that the absorption cross-section per unit length at resonance peak and the spectrally integrated absorption cross-section area per unit length of the 1D ground-state excitons were 1.0 nm and 2.5 × 10-3 eV nm, respectively.

  8. Identifying Student and Teacher Difficulties in Interpreting Atomic Spectra Using a Quantum Model of Emission and Absorption of Radiation

    Science.gov (United States)

    Savall-Alemany, Francisco; Domènech-Blanco, Josep Lluís; Guisasola, Jenaro; Martínez-Torregrosa, Joaquín

    2016-01-01

    Our study sets out to identify the difficulties that high school students, teachers, and university students encounter when trying to explain atomic spectra. To do so, we identify the key concepts that any quantum model for the emission and absorption of electromagnetic radiation must include to account for the gas spectra and we then design two…

  9. Modification of Thermal Emission via Metallic Photonic Crystals

    Energy Technology Data Exchange (ETDEWEB)

    Norris, David J.; Stein, Andreas; George, Steven M.

    2012-07-30

    Photonic crystals are materials that are periodically structured on an optical length scale. It was previously demonstrated that the glow, or thermal emission, of tungsten photonic crystals that have a specific structure - known as the 'woodpile structure' - could be modified to reduce the amount of infrared radiation from the material. This ability has implications for improving the efficiency of thermal emission sources and for thermophotovoltaic devices. The study of this effect had been limited because the fabrication of metallic woodpile structures had previously required a complex fabrication process. In this project we pursued several approaches to simplify the fabrication of metallic photonic crystals that are useful for modification of thermal emission. First, we used the self-assembly of micrometer-scale spheres into colloidal crystals known as synthetic opals. These opals can then be infiltrated with a metal and the spheres removed to obtain a structure, known as an inverse opal, in which a three-dimensional array of bubbles is embedded in a film. Second, we used direct laser writing, in which the focus of an infrared laser is moved through a thin film of photoresist to form lines by multiphoton polymerization. Proper layering of such lines can lead to a scaffold with the woodpile structure, which can be coated with a refractory metal. Third, we explored a completely new approach to modified thermal emission - thin metal foils that contain a simple periodic surface pattern, as shown in Fig. 1. When such a foil is heated, surface plasmons are excited that propagate along the metal interface. If these waves strike the pattern, they can be converted into thermal emission with specific properties.

  10. Land surface emissivity retrieval from airborne hyperspectral scanner thermal infrared data over urban surfaces

    Science.gov (United States)

    Gao, C. X.; Qian, Y. G.; Wang, N.; Ma, L. L.; Jiang, X. G.

    2015-12-01

    Land surface emissivity (LSE) is a key parameter for characterizing the land surface, and is vital for a wide variety of surface-atmosphere studies. This paper retrieved LSEs of land surfaces over the city of Madrid, Spain from airborne hyperspectral scanner (AHS) thermal infrared data using temperature emissivity separation (TES) method. Six different kinds of urban surfaces: asphalt, bare soil, granite, pavement, shrub and grass pavement, were selected to evaluate the performance of the TES method in urban areas. The results demonstrate that the TES method can be successfully applied to retrieve LSEs in urban area. The six urban surfaces have similar curve shape of emissivity spectra, with the lowest emissivity in band 73, and highest in band 78; the LSE for bare soil varies significantly with spectra, approximately from 0.90 in band 72 to 0.98 in band 78, whereas the LSE for grass has the smallest spectral variation, approximately from 0.965 in band 72 to 0.974 in band 78, and the shrub presents higher LSE than other surfaces in bands 72, 73, 75-77, but a little lower in bands 78 and 79. Furthermore, it is worth noting that band 73 is suitable for discriminating different urban surfaces because large LSE differences exist in this channel for different urban surfaces.

  11. Thermal dissociation of molten KHSO4: Temperature dependence of Raman spectra and thermodynamics

    DEFF Research Database (Denmark)

    Knudsen, Christian B.; Kalampounias, Angelos G.; Fehrmann, Rasmus

    2008-01-01

    intensities with the stoichiometric coefficients, the equilibrium constant, and the thermodynamics of the reaction equilibrium is derived. The method is used-along with the temperature-dependent features of the Raman spectra-to show that the studied equilibrium 2HSO(4)(-) (1) S2O72-(1) + H2O(g) is the only......Raman spectroscopy is used to study the thermal dissociation of molten KHSO4 at temperatures of 240-450 degrees C under static equilibrium conditions. Raman spectra obtained at 10 different temperatures for the molten phase and for the vapors thereof exhibit vibrational wavenumbers and relative...... band intensities inferring the occurrence of the temperature-dependent dissociation equilibrium 2HSO(4)(-) (1) S2O72-(1) + H2O(g). The Raman data are adequate for determining the partial pressures of H2O in the gas phase above the molten mixtures. A formalism for correlating relative Raman band...

  12. Modeling the complexity of acoustic emission during intermittent plastic deformation: Power laws and multifractal spectra

    Science.gov (United States)

    Kumar, Jagadish; Ananthakrishna, G.

    2018-01-01

    Scale-invariant power-law distributions for acoustic emission signals are ubiquitous in several plastically deforming materials. However, power-law distributions for acoustic emission energies are reported in distinctly different plastically deforming situations such as hcp and fcc single and polycrystalline samples exhibiting smooth stress-strain curves and in dilute metallic alloys exhibiting discontinuous flow. This is surprising since the underlying dislocation mechanisms in these two types of deformations are very different. So far, there have been no models that predict the power-law statistics for discontinuous flow. Furthermore, the statistics of the acoustic emission signals in jerky flow is even more complex, requiring multifractal measures for a proper characterization. There has been no model that explains the complex statistics either. Here we address the problem of statistical characterization of the acoustic emission signals associated with the three types of the Portevin-Le Chatelier bands. Following our recently proposed general framework for calculating acoustic emission, we set up a wave equation for the elastic degrees of freedom with a plastic strain rate as a source term. The energy dissipated during acoustic emission is represented by the Rayleigh-dissipation function. Using the plastic strain rate obtained from the Ananthakrishna model for the Portevin-Le Chatelier effect, we compute the acoustic emission signals associated with the three Portevin-Le Chatelier bands and the Lüders-like band. The so-calculated acoustic emission signals are used for further statistical characterization. Our results show that the model predicts power-law statistics for all the acoustic emission signals associated with the three types of Portevin-Le Chatelier bands with the exponent values increasing with increasing strain rate. The calculated multifractal spectra corresponding to the acoustic emission signals associated with the three band types have a maximum

  13. MER2 MARS MINIATURE THERMAL EMISSION SPECTROMETER EMR V1.0

    Data.gov (United States)

    National Aeronautics and Space Administration — This archive contains Mars Exploration Rover Miniature Thermal Emission Spectrometer (Mini-TES) Emissivity Reduced Data Record (EMR) products and ancillary files....

  14. The Gas-Phase Spectra of Resonance-Stabilized Radicals and the Red Rectangle Emission

    Science.gov (United States)

    Chalyavi, Nahid; Troy, Tyler P.; Nakajima, Masakazu; Nauta, Klaas; Kable, Scott H.; Schmidt, Timothy W.

    2010-06-01

    Alpha aromatic radicals may explain some of the emission features of Red Rectangle (RR), a nearby protoplanetary nebulae. Erosion of amorphous hydrogenated carbon may lead to resonance-stabilized products by breaking aliphatic side-chains to aromatic ``islands''. The resulting radicals may be excited by starlight to give rise to the characteristic emissions. As a part of the ongoing Research and in order to investigate this hypothesis, the gas-phase excitation and emission spectra of some of these radicals have been identified in a molecular beam using laser induced fluorescence (LIF) spectroscopy. Resonance-stabilized 1-naphthylmethyl, 2-naphthylmethyl and acenaphthenyl radicals were produced from the discharge of 1-methylnaphthalene, 2-methylnaphthalene and acenaphthene precursors in argon, respectively. In order to determine the ground state vibrational energies of these species, their fluorescence bands were dispersed. The results are consistent with the Density Functional Theory (DFT) calculated ground state frequencies. As a complementary experiment, and to further confirm the identity of the spectral carriers, resonant two color two photon ionization (R2C2PI) spectra were also recorded. The origin bands of all these three molecules show up in the 5790 - 5840 Å range of the spectrum, the well-known RR emission region. N. J. Reilly, D. L. Kokkin, M. Nakajima, K. Nauta, S. H. Kable, and T. W. Schmidt J. Am. Chem. Soc., 130(10), 3137 (2009). T. P. Troy, M. Nakajima, N. Chalyavi, R. G. C. R. Clady, K. Nauta, S. H. Kable, and T. W. Schmidt J. Phys. Chem. A, 113, 10279 (2009).

  15. Thermal changes in the absorption spectra of blood with supravascular infrared laser irradiation in vivo

    Science.gov (United States)

    Zalesskaya, G. A.; Astaf'eva, L. G.; Batai, L. E.

    2011-09-01

    We have studied the effect of laser radiation (λ = 1960 nm, power density from 6 to 25 W/cm2) on the absorption spectra of rat blood with supravascular irradiation. We have established that absorption of laser radiation leads to a decrease in the degree of oxygen saturation of mixed venous blood due to its heating. We have estimated the initial heating temperatures of venous blood and the surface of the irradiated tissue using an optothermal model, taking into account the characteristics of the laser radiation and the optical and thermal characteristics of the biological tissue. We consider the effect of radiation-induced thermal dissociation of oxyhemoglobin on the oxygen transport characteristics of the blood and metabolic processes.

  16. Thermal Emissivity and Cigarette Coal Temperature During Smolder

    Directory of Open Access Journals (Sweden)

    Lyman CS

    2014-12-01

    Full Text Available Coal temperatures affect the burn properties of cigarettes. Thermal imaging was used to determine the average maximum surface coal temperatures during smolder of cigarettes of different tobacco types. The thermal imaging camera was calibrated against a reference blackbody. An emissivity correction was necessary since the set point temperatures of the reference blackbody did not correspond to the measured temperatures of the reference blackbody. A 0.87 camera emissivity was applied to provide accurate coal temperatures at a corrected emissivity of approximately 1. The average maximum surface coal temperatures during smolder of unfiltered single-tobacco-type cigarettes and a commercial blend cigarette were determined (with the camera lens focused parallel to the cigarette, and no discernible differences among them were found. The calculated average maximum surface coal temperature during smolder for all cigarettes was 584 AA± 15 °C. During smolder, thermocouples were used to measure the temperature of the gas phase (along the central axis of coal, and the thermal imaging camera was used to measure the temperature of the solid phase of the coal's surface. Using thermocouples, the peak coal temperatures in the center of the coal during smolder for three filtered single-tobacco-type cigarettes were 736-744 °C. Peak coal temperatures, measured by thermal imaging, on the surface of the coal (with the camera lens focused coaxially with the coal and the ash removed for the same three single-tobacco-type cigarettes had a range of 721-748 °C. There was good correspondence between the two techniques. These results confirm that during smolder the gas-phase temperature inside the coal (as measured with the thermocouple and the solid-phase temperatures beneath the ash (as measured with the camera are in near thermal equilibrium. With proper calibration, a thermal imaging system is a good alternative to thermocouples for measuring cigarette coal

  17. Spontaneous emission spectra and quantum light-matter interactions from a strongly coupled quantum dot metal-nanoparticle system

    DEFF Research Database (Denmark)

    Van Vlack, C.; Kristensen, Philip Trøst; Hughes, S.

    2012-01-01

    the dot to the detector, we demonstrate that the strong-coupling regime should be observable in the far-field spontaneous emission spectrum, even at room temperature. The vacuum-induced emission spectra show that the usual vacuum Rabi doublet becomes a rich spectral triplet or quartet with two of the four...

  18. Evaluation of potential emission spectra for the reliable classification of fluorescently coded materials

    Science.gov (United States)

    Brunner, Siegfried; Kargel, Christian

    2011-06-01

    The conservation and efficient use of natural and especially strategic resources like oil and water have become global issues, which increasingly initiate environmental and political activities for comprehensive recycling programs. To effectively reutilize oil-based materials necessary in many industrial fields (e.g. chemical and pharmaceutical industry, automotive, packaging), appropriate methods for a fast and highly reliable automated material identification are required. One non-contacting, color- and shape-independent new technique that eliminates the shortcomings of existing methods is to label materials like plastics with certain combinations of fluorescent markers ("optical codes", "optical fingerprints") incorporated during manufacture. Since time-resolved measurements are complex (and expensive), fluorescent markers must be designed that possess unique spectral signatures. The number of identifiable materials increases with the number of fluorescent markers that can be reliably distinguished within the limited wavelength band available. In this article we shall investigate the reliable detection and classification of fluorescent markers with specific fluorescence emission spectra. These simulated spectra are modeled based on realistic fluorescence spectra acquired from material samples using a modern VNIR spectral imaging system. In order to maximize the number of materials that can be reliably identified, we evaluate the performance of 8 classification algorithms based on different spectral similarity measures. The results help guide the design of appropriate fluorescent markers, optical sensors and the overall measurement system.

  19. Control of Several Emissions during Olive Pomace Thermal Degradation

    Directory of Open Access Journals (Sweden)

    Teresa Miranda

    2014-10-01

    Full Text Available Biomass plays an important role as an energy source, being an interesting alternative to fossil fuels due to its environment-friendly and sustainable characteristics. However, due to the exposure of customers to emissions during biomass heating, evolved pollutants should be taken into account and controlled. Changing raw materials or mixing them with another less pollutant biomass could be a suitable step to reduce pollution. This work studied the thermal behaviour of olive pomace, pyrenean oak and their blends under combustion using thermogravimetric analysis. It was possible to monitor the emissions released during the process by coupling mass spectrometry analysis. The experiments were carried out under non-isothermal conditions at the temperature range 25–750 °C and a heating rate of 20 °C·min−1. The following species were analysed: aromatic compounds (benzene and toluene, sulphur emissions (sulphur dioxide, 1,4-dioxin, hydrochloric acid, carbon dioxide and nitrogen oxides. The results indicated that pollutants were mainly evolved in two different stages, which are related to the thermal degradation steps. Thus, depending on the pollutant and raw material composition, different emission profiles were observed. Furthermore, intensity of the emission profiles was related, in some cases, to the composition of the precursor.

  20. DFT study of the effect of substituents on the absorption and emission spectra of Indigo

    Directory of Open Access Journals (Sweden)

    Cervantes-Navarro Francisco

    2012-07-01

    Full Text Available Abstract Background Theoretical analyses of the indigo dye molecule and its derivatives with Chlorine (Cl, Sulfur (S, Selenium (Se and Bromine (Br substituents, as well as an analysis of the Hemi-Indigo molecule, were performed using the Gaussian 03 software package. Results Calculations were performed based on the framework of density functional theory (DFT with the Becke 3- parameter-Lee-Yang-Parr (B3LYP functional, where the 6-31 G(d,p basis set was employed. The configuration interaction singles (CIS method with the same basis set was employed for the analysis of excited states and for the acquisition of the emission spectra. Conclusions The presented absorption and emission spectra were affected by the substitution position. When a hydrogen atom of the molecule was substituted by Cl or Br, practically no change in the absorbed and emitted energies relative to those of the indigo molecule were observed; however, when N was substituted by S or Se, the absorbed and emitted energies increased.

  1. Oscillating bubble concentration and its size distribution using acoustic emission spectra.

    Science.gov (United States)

    Avvaru, Balasubrahmanyam; Pandit, Aniruddha B

    2009-01-01

    New method has been proposed for the estimation of size and number density distribution of oscillating bubbles in a sonochemical reactor using acoustic emission spectra measurements. Bubble size distribution has been determined using Minnaert's equation [M. Minnaert, On musical air bubbles and sound of running water, Philanthr. Mag. 16 (1933) 235], i.e., size of oscillating bubble is inversely related to the frequency of its volume oscillations. Decomposition of the pressure signal measured by the hydrophone in frequency domain of FFT spectrum and then inverse FFT reconstruction of the signal at each frequency level has been carried out to get the information about each of the bubble/cavity oscillation event. The number mean radius of the bubble size is calculated to be in the range of 50-80 microm and it was not found to vary much with the spatial distribution of acoustic field strength of the ultrasound processor used in the work. However, the number density of the oscillating bubbles and the nature of the distribution were found to vary in different horizontal planes away from the driving transducer surface in the ultrasonic bath. A separate set of experiments on erosion assessment studies were carried out using a thin aluminium foil, revealing a phenomena of active region of oscillating bubbles at antinodal points of the stationary waves, identical to the information provided by the acoustic emission spectra at the same location in the ultrasonic bath.

  2. Tunable dual emission in visible and near-infrared spectra using Co(2+)-doped PbSe nanocrystals embedded in a chalcogenide glass matrix.

    Science.gov (United States)

    Lourenço, Sidney A; Silva, Ricardo S; Dantas, Noelio O

    2016-08-17

    Semimagnetic Pb1-xCoxSe nanocrystals were synthesized by a fusion protocol in a glass matrix and characterized by optical absorption (OA), transmission electron microscopy (TEM), and photoluminescence (PL) techniques. OA spectra and TEM images strongly indicated the formation of Pb1-xCoxSe magnetic phases in the glass system and the quantum dot size was manipulated by tuning the annealing time. The OA spectra together with crystal field theory indicate that Co(2+) is located in the tetrahedral site (Td) and the PL of the Pb1-xCoxSe nanocrystals presents characteristic recombination in the visible (∼700 nm) and near-IR (1300-1600 nm) electromagnetic spectral range. With temperature decreasing, the PL spectra, in the visible spectral range, indicate an excited-state crossover yielding PL changes from (4)T1(P) → (4)A2(F) broadband emission to (2)E(G) → (4)A2(F) narrow-line emission. This phenomenon was explained on the basis of a configurational energy model. The OA and PL spectra of PbSe:Co(2+) indicate that the localized energy transition of Co(2+) ((4)A2(F) ↔ (4)T1((4)F)) can be tuned from the band-gap energy to the conduction-band energy of PbSe NCs by changing the NC size by increasing the thermal annealing time. In the near-IR spectral range, the temperature-dependent PL spectra show that the process of thermal activation of localized electrons in Co(2+) states can be transferred to the conduction band of the NCs. This process depends on the energy distance between extended and localized states, which can be controlled by the sample annealing time.

  3. Thermal and Non-thermal emission in the Jets and Lobes of Cygnus A

    Science.gov (United States)

    De Vries, Martijn; Wise, Michael; Huppenkothen, Daniela; Nulsen, Paul; Snios, Bradford; Hardcastle, Martin

    2017-08-01

    We present a spatially-resolved, spectral analysis aimed at detecting and characterizing the non-thermal X-ray emission from the jets and lobes in the powerful radio galaxy Cygnus A based on a new, deep 1 Msec Chandra exposure. These jets and lobes are believed to be a primary means by which energy liberated by accretion onto the central supermassive black hole is transported into the outer galaxy and are integral to understanding the mechanisms that drive AGN feedback. Despite being well-studied over the years, we still do not understand how this energy is transported, the connection between the X-ray and radio structures, and the underlying emission mechanisms that produce them. The X-ray jets in Cygnus A show a clear misalignment with the radio and it has been proposed that they are either inverse Compton-emitting relics or a separate electron population emitting X-ray synchrotron emission. Previous X-ray studies of the jets and lobes have been unsuccessful in distinguishing between these possibilities largely due to the difficulty of separating any non-thermal components from thermal emission in the surrounding hot ICM at CCD spectral resolutions.In this presentation, we report on a new statistical analysis using MCMC sampling and Bayesian model selection to characterize the X-ray emission in the jets and lobes of Cygnus A. The model includes a mixture of thermal ICM emission and distinct non-thermal components from both the eastern and western jets and lobes. Our analysis clearly favors the presence of non-thermal emission and we find a distinct asymmetry with the western lobe roughly 20% fainter and with a much steeper photon index. Combining existing radio data with our X-ray fluxes and photon indices, we determine the energy densities and pressures for both synchrotron and inverse Compton (IC) emission models. For the IC model, we derive energy densities in the lobes consistent with the external pressure; however, both the eastern and western jets would be

  4. Kinetic energy spectra in thermionic emission from small tungsten cluster anions: evidence for nonclassical electron capture.

    Science.gov (United States)

    Concina, Bruno; Baguenard, Bruno; Calvo, Florent; Bordas, Christian

    2010-03-14

    The delayed electron emission from small mass-selected anionic tungsten clusters W(n)(-) has been studied for sizes in the range 9 < or = n < or = 21. Kinetic energy spectra have been measured for delays of about 100 ns after laser excitation by a velocity-map imaging spectrometer. They are analyzed in the framework of microreversible statistical theories. The low-energy behavior shows some significant deviations with respect to the classical Langevin capture model, which we interpret as possibly due to the influence of quantum dynamical effects such as tunneling through the centrifugal barrier, rather than shape effects. The cluster temperature has been extracted from both the experimental kinetic energy spectrum and the absolute decay rate. Discrepancies between the two approaches suggest that the sticking probability can be as low as a few percent for the smallest clusters.

  5. Synthetic approaches toward tungsten photonic crystals for thermal emission

    Science.gov (United States)

    Denny, Nicholas R.; Han, Sangjin; Turgeon, Ryan T.; Lytle, Justin C.; Norris, David J.; Stein, Andreas

    2005-11-01

    The efficiency of standard incandescent light sources is limited by strong thermal emission in the infrared regime. It is possible that emission of light may be more efficient when the conventional tungsten filament is replaced by metallic photonic crystals that have large photonic band gaps in the infrared and can suppress the thermal emission of blackbody emitters. One approach toward fabricating photonic crystal structures with highly ordered periodic features on an optical length scale involves colloidal crystal templating to produce inverse opals. Metallic inverse opals were synthesized using chemical vapor deposition (CVD) and wet chemical methods capable of producing granules, thin films and monolithic pieces. Thin films were prepared by infiltrating silica opal films with tungsten hexacarbonyl in a CVD process, reducing tungsten in hydrogen and removing the silica template by HF etching. A range of soluble metal precursors, including tungsten(VI) chloride, tungsten(V) ethoxide and acetylated peroxotungstic acid, were infiltrated into self-assembled, colloidal crystal arrays comprised of monodisperse poly(methyl methacrylate) (PMMA) spheres. The infiltrated composites were processed under reducing conditions to produce metallic inverse replicas of the template. The influence of processing conditions on structural properties, including thickness of skeletal walls, window openings and solid filling fraction, was studied. A monolithic tungsten inverse opal with dimensions of 0.5 × 0.5 × 0.2 cm was resistively heated in an inert atmosphere and thermal emission was observed. The wet chemical methods provide a low cost alternative to expensive nanolithographic methods for the fabrication of three-dimensional periodic metallic structures.

  6. Deriving chlorophyll fluorescence emissions of vegetation canopies from high resolution field reflectance spectra

    Science.gov (United States)

    Middleton, Elizabeth M.; Corp, Lawrence A.; Daughtry, Craig S.; Entcheva Campbell, Petya K.; Butcher, L. Maryn

    2005-11-01

    Fluorescence of foliage in the laboratory has proven more rigorous than reflectance for correlation to plant physiology. Especially useful are emissions produced from two stable red and far-red chlorophyll fluorescence (ChlF) peaks centered at 685 nm and 735 nm. Methods have been developed elsewhere to extract steady state solar induced fluorescence (SIF) from apparent reflectance of vegetation canopies/landscapes using the Fraunhofer Line Depth (FLD) principal. Our study utilized these methods in conjunction with field-acquired high spectral resolution canopy reflectance spectra obtained in 2004 and 2005 over corn crops and small tree plots of three deciduous species (red maple, tulip poplar, sweet gum). Leaf level measurements were also made of foliage which included ChlF, photosynthesis, and leaf constituents (photosynthetic pigment, carbon (C), and nitrogen (N) contents). As part of ongoing experiments, measurements were made on N application plots within corn (280, 140, 70, and 0 kg N/ha) and tree (0, 37.5, 75, 112.5, 150 kg N /ha) sites at the USDA/Agriculture Research Service in Beltsville, MD. SIF intensities for ChlF were derived directly from canopy reflectance spectra in specific narrow- band regions associated with atmospheric oxygen absorption features centered at 688 and 760 nm. The red/far-red SIF ratio (SIFratio) derived from these field reflectance spectra successfully discriminated foliar pigment ratios altered by N application rates in both corn crops. This ratio was also positively correlated to the C/N ratio at leaf and canopy levels, for the available corn data (e.g., 2004). No consistent N treatment or species differences in SIF were detected in the tree foliage, but additional 2005 data are forthcoming. This study has relevance to future passive satellite remote sensing approaches to monitoring C dynamics from space.

  7. Fine characterization rock thermal damage by acoustic emission technique

    Science.gov (United States)

    Kong, Biao; Li, Zenghua; Wang, Enyuan

    2018-02-01

    This paper examines the differences in the thermal mechanical properties and acoustic emission (AE) characteristics during the deformation and fracture of rock under the action of continuous heating and after high-temperature treatment. Using AE 3D positioning technology, the development and evolution of the internal thermal cracks and the time domain of AE signals in rock were analyzed. High-temperature treatment causes thermal damage to rock. Under the action of continuous heating, the phase characteristics of AE time series correspond to the five stages of rock thermal deformation and fracture, respectively: the micro-defect development stage, the threshold interval of rock micro-cracks, the crack initiation stage, the crack propagation stage, and the crack multistage propagation evolution. When the initial crack propagates, the crack initiation of the rock causes the AE signal to produce a sudden mutation change. Mechanical fraction characteristics during rock uniaxial compression after temperature treatment indicated that the decrease rate of the rock compressive strength, wave velocity, and elastic modulus are relatively large during uniaxial compression tests after high-temperature treatment. During the deformation and fracture of rock under loading, there is faster growth of AE counts and AE events, indicating an increase in the speed of rock deformation and fracture under loading. AE counts show obvious changes during the latter loading stages, whereas AE events show obvious changes during the loading process. The results obtained are valuable for rock thermal stability detection and evaluation in actual underground engineering.

  8. Detection of cervical cancer by fluorescence emission and stokes' shift spectra of blood and urine

    Science.gov (United States)

    Masilamani, V.; Vijmasi, T.; AlSalhi, M.; Govindarajan, K.; VijayaRaghavan, A. P.; Rai, Ram Rathan

    2011-03-01

    In this paper we present the results of a study to distinguish cervical cancer patients [ N=50] from healthy subjects [N=50] based on the Fluorescence Emission Spectra [FES] and Stokes' Shift Spectra [SSS] of blood and urine. FES was obtained from the cellular fraction of blood and urine by excitation at 400 nm. SSS was obtained from blood plasma and urine with Δλ of 70nm. In the FES of blood cellular fraction, the ratio of intensity of the two bands due to neutral porphyrin and basic porphyrin [I630 / I580] was 1 for normal controls and 3 for cervical cancers. In the SSS of plasma, the average ratio of intensity of the two bands due to tryptophan and collagen [I305 nm / I340 nm] was 1.9 for normal controls, 1.1 for early cervical cancers and 0.9 for advanced cervical cancers In the SSS of urine, the ratio of intensity of the two bands due to flavin and NADH [I450 nm / I360 nm] was 0.2 for normal controls and 0.8 for cancer patients. A discriminant analysis combining all three parameters showed a sensitivity of 80% and specificity of 78% for this technique. In this study we show that fluorescence spectroscopy of blood and urine could develop into a promising technique for non-invasive diagnosis and screening of cervical cancers and would appropriately supplement or complement currently used techniques.

  9. Non-thermal x-ray emission from wire array z-pinches

    Energy Technology Data Exchange (ETDEWEB)

    Ampleford, David [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Hansen, Stephanie B. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Jennings, Christopher Ashley [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Webb, Timothy Jay [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Harper-Slaboszewicz, V. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Loisel, Guillaume Pascal [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Flanagan, Timothy McGuire [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Bell, Kate Suzanne [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Jones, Brent M. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); McPherson, Leroy A. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Rochau, Gregory A. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Chittenden, Jeremy P. [Imperial College, London (United Kingdom); Sherlock, Mark [Imperial College, London (United Kingdom); Appelbe, Brian [Imperial College, London (United Kingdom); Giuliani, John [Naval Research Lab. (NRL), Washington, DC (United States); Ouart, Nicholas [Naval Research Lab. (NRL), Washington, DC (United States); Seely, John [Artep Inc., Ellicott City, MD (United States)

    2015-12-01

    We report on experiments demonstrating the transition from thermally-dominated K-shell line emission to non-thermal, hot-electron-driven inner-shell emission for z pinch plasmas on the Z machine. While x-ray yields from thermal K-shell emission decrease rapidly with increasing atomic number Z, we find that non-thermal emission persists with favorable Z scaling, dominating over thermal emission for Z=42 and higher (hn ≥ 17keV). Initial experiments with Mo (Z=42) and Ag (Z=47) have produced kJ-level emission in the 17-keV and 22-keV Kα lines respectively. We will discuss the electron beam properties that could excite these non - thermal lines. We also report on experiments that have attempted to control non - thermal K - shell line emission by modifying the wire array or load hardware setup.

  10. Photoacoustic emission from Au nanoparticles arrayed on thermal insulation layer.

    Science.gov (United States)

    Namura, Kyoko; Suzuki, Motofumi; Nakajima, Kaoru; Kimura, Kenji

    2013-04-08

    Efficient photoacoustic emission from Au nanoparticles on a porous SiO(2) layer was investigated experimentally and theoretically. The Au nanoparticle arrays/porous SiO(2)/SiO(2)/Ag mirror sandwiches, namely, local plasmon resonators, were prepared by dynamic oblique deposition (DOD). Photoacoustic measurements were performed on the local plasmon resonators, whose optical absorption was varied from 0.03 (3%) to 0.95 by varying the thickness of the dielectric SiO(2) layer. The sample with high absorption (0.95) emitted a sound that was eight times stronger than that emitted by graphite (0.94) and three times stronger than that emitted by the sample without the porous SiO(2) layer (0.93). The contribution of the porous SiO(2) layer to the efficient photoacoustic emission was analyzed by means of a numerical method based on a one-dimensional heat transfer model. The result suggested that the low thermal conductivity of the underlying porous layer reduces the amount of heat escaping from the substrate and contributes to the efficient photoacoustic emission from Au nanoparticle arrays. Because both the thermal conductivity and the spatial distribution of the heat generation can be controlled by DOD, the local plasmon resonators produced by DOD are suitable for the spatio-temporal modulation of the local temperature.

  11. Near Zero Emissions at 50 Percent Thermal Efficiency

    Energy Technology Data Exchange (ETDEWEB)

    None, None

    2012-12-31

    Detroit Diesel Corporation (DDC) has successfully completed a 10 year DOE sponsored heavy-duty truck engine program, hereafter referred to as the NZ-50 program. This program was split into two major phases. The first phase was called Near-Zero Emission at 50 Percent Thermal Efficiency, and was completed in 2007. The second phase was initiated in 2006, and this phase was named Advancements in Engine Combustion Systems to Enable High-Efficiency Clean Combustion for Heavy-Duty Engines. This phase was completed in September, 2010. The key objectives of the NZ-50 program for this first phase were to: Quantify thermal efficiency degradation associated with reduction of engine-out NOx emissions to the 2007 regulated level of ~1.1 g/hp-hr. Implement an integrated analytical/experimental development plan for improving subsystem and component capabilities in support of emerging engine technologies for emissions and thermal efficiency goals of the program. Test prototype subsystem hardware featuring technology enhancements and demonstrate effective application on a multi-cylinder, production feasible heavy-duty engine test-bed. Optimize subsystem components and engine controls (calibration) to demonstrate thermal efficiency that is in compliance with the DOE 2005 Joule milestone, meaning greater than 45% thermal efficiency at 2007 emission levels. Develop technology roadmap for meeting emission regulations of 2010 and beyond while mitigating the associated degradation in engine fuel consumption. Ultimately, develop technical prime-path for meeting the overall goal of the NZ-50 program, i.e., 50% thermal efficiency at 2010 regulated emissions. These objectives were successfully met during the course of the NZ-50 program. The most noteworthy achievements in this program are summarized as follows: Demonstrated technologies through advanced integrated experiments and analysis to achieve the technical objectives of the NZ-50 program with 50.2% equivalent thermal efficiency under

  12. MODELING THERMAL DUST EMISSION WITH TWO COMPONENTS: APPLICATION TO THE PLANCK HIGH FREQUENCY INSTRUMENT MAPS

    Energy Technology Data Exchange (ETDEWEB)

    Meisner, Aaron M.; Finkbeiner, Douglas P., E-mail: ameisner@fas.harvard.edu, E-mail: dfinkbeiner@cfa.harvard.edu [Department of Physics, Harvard University, 17 Oxford Street, Cambridge, MA 02138 (United States)

    2015-01-10

    We apply the Finkbeiner et al. two-component thermal dust emission model to the Planck High Frequency Instrument maps. This parameterization of the far-infrared dust spectrum as the sum of two modified blackbodies (MBBs) serves as an important alternative to the commonly adopted single-MBB dust emission model. Analyzing the joint Planck/DIRBE dust spectrum, we show that two-component models provide a better fit to the 100-3000 GHz emission than do single-MBB models, though by a lesser margin than found by Finkbeiner et al. based on FIRAS and DIRBE. We also derive full-sky 6.'1 resolution maps of dust optical depth and temperature by fitting the two-component model to Planck 217-857 GHz along with DIRBE/IRAS 100 μm data. Because our two-component model matches the dust spectrum near its peak, accounts for the spectrum's flattening at millimeter wavelengths, and specifies dust temperature at 6.'1 FWHM, our model provides reliable, high-resolution thermal dust emission foreground predictions from 100 to 3000 GHz. We find that, in diffuse sky regions, our two-component 100-217 GHz predictions are on average accurate to within 2.2%, while extrapolating the Planck Collaboration et al. single-MBB model systematically underpredicts emission by 18.8% at 100 GHz, 12.6% at 143 GHz, and 7.9% at 217 GHz. We calibrate our two-component optical depth to reddening, and compare with reddening estimates based on stellar spectra. We find the dominant systematic problems in our temperature/reddening maps to be zodiacal light on large angular scales and the cosmic infrared background anisotropy on small angular scales.

  13. Miniature Thermal Emission Spectrometer for the Mars Exploration Rovers

    Science.gov (United States)

    Christensen, Philip R.; Mehall, Greg L.; Silverman, Steven H.; Anwar, Saadat; Cannon, George; Gorelick, Noel; Kheen, Rolph; Tourville, Tom; Bates, Duane; Ferry, Steven; Fortuna, Teresa; Jeffryes, John; O'Donnell, William; Peralta, Richard; Wolverton, Thomas; Blaney, Diana; Denise, Robert; Rademacher, Joel; Morris, Richard V.; Squyres, Steven

    2003-12-01

    The Miniature Thermal Emission Spectrometer (Mini-TES) will provide remote measurements of mineralogy and thermophysical properties of the scene surrounding the Mars Exploration Rovers and guide the rovers to key targets for detailed in situ measurements by other rover experiments. The specific scientific objectives of the Mini-TES investigation are to (1) determine the mineralogy of rocks and soils, (2) determine the thermophysical properties of selected soil patches, and (3) determine the temperature profile, dust and water-ice opacity, and water vapor abundance in the lower atmospheric boundary layer. The Mini-TES is a Fourier Transform Spectrometer covering the spectral range 5-29 μm (339.50 to 1997.06 cm-1) with a spectral sample interval of 9.99 cm-1. The Mini-TES telescope is a 6.35-cm-diameter Cassegrain telescope that feeds a flat-plate Michelson moving mirror mounted on a voice-coil motor assembly. A single deuterated triglycine sulfate (DTGS) uncooled pyroelectric detector with proven space heritage gives a spatial resolution of 20 mrad; an actuated field stop can reduce the field of view to 8 mrad. Mini-TES is mounted within the rover's Warm Electronics Box and views the terrain using its internal telescope looking up the hollow shaft of the Pancam Mast Assembly (PMA) to the fixed fold mirror and rotating elevation scan mirror in the PMA head located ~1.5 m above the ground. The PMA provides a full 360°of azimuth travel and views from 30° above the nominal horizon to 50° below. An interferogram is collected every two seconds and transmitted to the Rover computer, where the Fast Fourier Transform, spectral summing, lossless compression, and data formatting are performed prior to transmission to Earth. Radiometric calibration is provided by two calibration V-groove blackbody targets instrumented with platinum thermistor temperature sensors with absolute temperature calibration of +/-0.1°C. One calibration target is located inside the PMA head; the

  14. Triton Emission Spectra in Some Target Nuclei Irradiated by Ultra-Fast Neutrons

    Science.gov (United States)

    Tel, E.; Kaplan, A.; Aydın, A.; Büyükuslu, H.; Demirkol, İ.; Arasoğlu, A.

    2010-08-01

    High-current proton accelerator technologies make use of spallation neutrons produced in ( p,xn) and ( n,xn) nuclear reactions on high-Z targets. The produced neutrons are moderated by heavy water. These moderated neutrons are subsequently captured on 3He to produce tritium via the ( n,p) reaction. Tritium self-sufficiency must be maintained for a commercial power plant. So, working out the systematics of ( n,t) reaction cross sections and triton emission differential data are important for the given reaction taking place on various nuclei at different energies. In this study, triton emission spectra by using ultra-fast neutrons (incident neutron energy >50 MeV), the ( n,xt) reactions for some target nuclei as 16O, 27Al, 56Fe, 59Co, 208Pb and 209Bi have been investigated. In the calculations, the pre-equilibrium and equilibrium effects have been used. The calculated results have been compared with the experimental data taken from the literature.

  15. [Analysis of optical emission spectra from ICP of Ar in the vicinity of plasma sheath].

    Science.gov (United States)

    Zhao, Wen-Feng; Chen, Jun-Fang; Meng, Ran

    2009-11-01

    In order to control the ion density and energy distribution in the vicinity of plasma sheath independently, the inductively coupled plasma and its glow discharge mechanism in the vicinity of plasma sheath were studied by means of optical emission spectroscopy (OES) under different RF power, different discharge and different substrate DC bias voltage. It was shown that the ion density is higher and the electron temperature is lower in the vicinity of inductively coupled plasma sheath according to the ionic line and atomic line. With changing the discharge pressure and RF power, the spectral characteristics analysis shows that the ion density in the vicinity of plasma sheath linearly increases with the RF power and rises with the pressure under the low pressure. The atomic spectral intensity of low excitation states increases rapidly. The atomic spectral intensity of high excitation states rises slowly and the intensity of ion spectrum increases not obviously. By applying the DC bias voltage to substrate, the intensity of emission spectroscopy was analyzed. The result shows that the intensity of spectra rises with the increase in positive bias voltage, while first reduces then increases with the increase in negative bias voltage, and is the weakest in the case of DC bias at -30 V. This shows that the fast ions and the electrons are the main source of energy for Ar ionization and excitation.

  16. Effect of thermal power plant emissions on Catharanthus roseus L

    Energy Technology Data Exchange (ETDEWEB)

    Khan, A.M.; Pandey, V.; Shukla, J.; Singh, N.; Yunus, M.; Singh, S.N.; Ahmad, K.J. (National Botanical Research Institute, Lucknow (India))

    1990-06-01

    Most of the industrialized nations depend largely on the combustion of fossil fuels for their energy requirements. During the past few years in India quite a few thermal power plants have been commissioned to cater to the increasing energy requirements. As most of the power plants are coal-fired, a complex mixture of several pollutants is released in the atmosphere on the combustion of coal. Leaves by virtue of their unique position on plants and their functions, experience the maximum brunt of exposure and undergo certain changes in form, structure and function with the changes in surrounding environs, and such modifications are likely to serve as markers of environmental pollution. The present paper deals with the long term exposure effects of thermal power plant emissions on Catharanthus roseus L. - a common perennial shrub, with glossy leaves and white, mauve or pink colored flowers and of great medicinal value is grown as an ornamental plant all over the country.

  17. Using Thermal Infrared Absorption and Emission to Determine Trace Gases

    Science.gov (United States)

    Clerbaux, Cathy; Drummond, James R.; Flaud, Jean-Marie; Orphal, Johannes

    The light emerging from the top of the atmosphere in the greater part of the infrared region is thermal radiation from the Earth's surface. The resultant spectra obtained depend on the temperature difference between the emitting feature and absorbing gas. In this region the greenhouse gases, carbon dioxide, CO2, methane, CH4, ozone, O3, and water, H2O, are observed as well as carbon monoxide, CO, a product indicative of fossil fuel combustion, methanol, CH3OH, from biomass burning, and ammonia, NH3, from agriclulture. Chapter 3 describes the techniques for retrieving atmospheric abundances of these and other species from a number of satellite instruments, and concludes with suggestions for future developments.

  18. Volcanic SO2 and SiF4 visualization and their ratio monitored using 2-D thermal emission spectroscopy

    Science.gov (United States)

    Stremme, W.; Krueger, A.; Harig, R.; Grutter, M.

    2011-09-01

    The composition and emission rates of volcanic gas plumes provide insight of the geologic internal activity, atmospheric chemistry, aerosol formation and radiative processes around it. Observations are necessary for public security and the aviation industry. Ground-based thermal emission infrared spectroscopy, which uses the radiation of the volcanic gas itself, allows for continuously monitoring during day and night from a save distance. We present measurements on Popocatépetl volcano based on thermal emission spectroscopy during different campaigns between 2006-2009 using a Scanning Infrared Gas Imaging System (SIGIS). The experimental set-up, measurement geometries and analytical algorithms are described. The equipment was operated from a safe distance of 12 km from the volcano at two different spectral resolutions: 0.5 and 4 cm-1. The 2-dimensional scanning capability of the instrument allows for an on-line visualization of the volcanic SO2 plume, animation and determination of its propagation speed. SiF4 was also identified in the infrared spectra recorded at both resolutions. The SiF4/SO2 molecular ratio can be calculated from each image and used as a highly useful parameter to follow changes in volcanic activity. A small Vulcanian eruption was monitored during the night of 16 to 17 November 2008 which was confirmed from the strong ash emission registered around 01:00 a.m. LST (Local Standard Time) and a pronounced SO2 cloud was registered. Enhanced SiF4/SO2 ratios were observed before and after the eruption. A validation of the results from thermal emission measurements with those from absorption spectra of the moon taken at the same time, as well as an error analysis, are presented. The inferred propagation speed from sequential imagees is used to calculate the emission rates at different distances from the crater.

  19. Modeling the thermal unfolding 2DIR spectra of a β-hairpin peptide based on the implicit solvent MD simulation.

    Science.gov (United States)

    Wu, Tianmin; Yang, Lijiang; Zhang, Ruiting; Shao, Qiang; Zhuang, Wei

    2013-07-25

    We simulated the equilibrium isotope-edited FTIR and 2DIR spectra of a β-hairpin peptide trpzip2 at a series of temperatures. The simulation was based on the configuration distributions generated using the GB(OBC) implicit solvent model and the integrated tempering sampling (ITS) technique. A soaking procedure was adapted to generate the peptide in explicit solvent configurations for the spectroscopy calculations. The nonlinear exciton propagation (NEP) method was then used to calculate the spectra. Agreeing with the experiments, the intensities and ellipticities of the isotope-shifted peaks in our simulated signals have the site-specific temperature dependences, which suggest the inhomogeneous local thermal stabilities along the peptide chain. Our simulation thus proposes a cost-effective means to understand a peptide's conformational change and related IR spectra across its thermal unfolding transition.

  20. An accurate retrieval of leaf water content from mid to thermal infrared spectra using continuous wavelet analysis

    Energy Technology Data Exchange (ETDEWEB)

    Ullah, Saleem, E-mail: ullah19488@itc.nl [Faculty of Geo-Information Science and Earth Observation (ITC), University of Twente, P.O. Box 217, 7500 AE Enschede (Netherlands); Skidmore, Andrew K. [Faculty of Geo-Information Science and Earth Observation (ITC), University of Twente, P.O. Box 217, 7500 AE Enschede (Netherlands); Naeem, Mohammad [Department of Chemistry, Abdul Wali Khan University Mardan (AWKUM), KPK (Pakistan); Schlerf, Martin [Centre de Recherche Public-Gabriel Lippmann (CRPGL), L-4422 Belvaux (Luxembourg)

    2012-10-15

    Leaf water content determines plant health, vitality, photosynthetic efficiency and is an important indicator of drought assessment. The retrieval of leaf water content from the visible to shortwave infrared spectra is well known. Here for the first time, we estimated leaf water content from the mid to thermal infrared (2.5-14.0 {mu}m) spectra, based on continuous wavelet analysis. The dataset comprised 394 spectra from nine plant species, with different water contents achieved through progressive drying. To identify the spectral feature most sensitive to the variations in leaf water content, first the Directional Hemispherical Reflectance (DHR) spectra were transformed into a wavelet power scalogram, and then linear relations were established between the wavelet power scalogram and leaf water content. The six individual wavelet features identified in the mid infrared yielded high correlations with leaf water content (R{sup 2} = 0.86 maximum, 0.83 minimum), as well as low RMSE (minimum 8.56%, maximum 9.27%). The combination of four wavelet features produced the most accurate model (R{sup 2} = 0.88, RMSE = 8.00%). The models were consistent in terms of accuracy estimation for both calibration and validation datasets, indicating that leaf water content can be accurately retrieved from the mid to thermal infrared domain of the electromagnetic radiation. -- Highlights: Black-Right-Pointing-Pointer The mid and thermal infrared spectra are sensitive to variation in leaf water content. Black-Right-Pointing-Pointer Continuous wavelet analysis detected the variation caused by leaf water content. Black-Right-Pointing-Pointer The selected wavelet features are highly correlated with leaf water content. Black-Right-Pointing-Pointer Mid wave and thermal infrared spectra have the potential to estimate leaf water content.

  1. Simulation of emission spectra from nonuniform reactive laser-induced plasmas.

    Science.gov (United States)

    Hermann, Jörg; Lorusso, Antonella; Perrone, Alessio; Strafella, Francesco; Dutouquet, Christophe; Torralba, Béatrice

    2015-11-01

    We demonstrate that chemical reactions leading to the formation of AlO radicals in plasmas produced by ablation of aluminum or Ti-sapphire with ultraviolet nanosecond laser pulses can be predicted by the model of local thermodynamic equilibrium. Therefore, emission spectra recorded with an echelle spectrometer and a gated detector were compared to the spectral radiance computed for uniform and nonuniform equilibrium plasmas. The calculations are based on analytical solutions of the radiation transfer equation. The simulations show that the plasmas produced in argon background gas are almost uniform, whereas temperature and density gradients are evidenced in air. Furthermore, chemical reactions exclusively occur in the cold plume periphery for ablation in air. The formation of AlO is negligible in argon as the plasma temperature is too large in the time interval of interest up to several microseconds. Finally, the validity of local thermodynamic equilibrium is shown to depend on time, space, and on the elemental composition. The presented conclusions are of interest for material analysis via laser-induced breakdown spectroscopy and for laser materials processing.

  2. Emission Lines of O III in The Optical and Ultraviolet Spectra of Planetary Nebulae

    Science.gov (United States)

    Crawford, F. L.; Keenan, F. P.; Aggarwal, K. M.; Aller, L. H.; Feibelman, W. A.; Fisher, Richard R. (Technical Monitor)

    2000-01-01

    Recent R-matrix calculations of electron impact excitation rates in 0 III are used to calculate electron temperature and density-dependent emission line ratios R (sub 1) = I(4363 Angstroms)/ I(4960 Angstroms + 5007 Angstroms), R (sub 2) = I(1661 Angstroms + 1667 Angstroms)/ I(4960 Angstroms + 5007 Angstroms) and R (sub 3)= I(2322 Angstroms)/ I(1661 Angstroms + 1667 Angstroms), for a range of electron temperatures (7500 less than or equal to Te less than or equal to 30 000 K) and densities (10 (exp 4) less than or equal to N (sub e) less than or equal to 10 (exp 7) per cubic centimeters) applicable to gaseous nebulae. The ratio-ratio diagrams (R (sub 1), R (sub 2)) and (R (sub 1), R (sub 3)) should, in principle, allow the simultaneous determination of T (sub e) and N (sub e) from measurements of the 0 III features in a spectrum. Plasma parameters derived for a sample of high-excitation planetary nebulae from (R (sub 1), R (sub 2)) and (R (sub 1), R (sub 3)) measurements, produced using a combination of ultraviolet spectra obtained with the International Ultraviolet Explorer (IUE) and optical data from a number of observing runs, are found to show excellent internal consistency. They also show, in general, good agreement with the values of Te and Ne estimated from other line ratios in the nebulae, therefore providing observational support for the accuracy of the theoretical ratios and hence the atomic data adopted in their derivation.

  3. Effect of microstructure of graphite on the nonreductive thermal ion emission in thermal ionization mass spectrometry.

    Science.gov (United States)

    Wei, H Z; Jiang, S Y; Xiao, Y K

    2010-02-25

    The emission behavior of polyatomic ions in the ionization source of thermal ionization mass spectrometry (TIMS) was investigated. The results suggest that the presence of a graphite promoter plays a key role for the formation and stable emission of polyatomic ions, such as M(2)X(+), M(2)BO(2)(+), Cs(2)NO(2)(+), and Cs(2)CNO(+). Our data further implied that the intensity of M(2)X(+) and M(2)BO(2)(+) increases and the emission temperature decreases with increasing cationic and anionic radius. During the boron isotopic measurement using the Cs(2)BO(2)(+)-graphite-PTIMS method, the isobaric interference ion Cs(2)CNO(+) cannot be transformed from nitrate or organic compounds containing an amide group but can be induced by the existence of trace amounts of boron because of its special electron-deficiency property (B(3+)). Characterization on the planar crystalline structure of various graphite samples with SEM, TEM, and Raman spectroscopy confirmed the relationship of the emission capacity of polyatomic ions and the crystal microstructure of graphite and provides direct evidence that graphite with a perfect parallel and equidistant layer orientation shows a beneficial effect on the emission of polyatomic ions in TIMS. The mechanism study on the formation of polyatomic ions opens the possibility to establish high precision methods for isotopic composition analysis of more nonmetal elements with the TIMS technique.

  4. Synchronized Analysis of FTIR Spectra and GCMS Chromatograms for Evaluation of the Thermally Degraded Vegetable Oils

    Directory of Open Access Journals (Sweden)

    Siong Fong Sim

    2014-01-01

    Full Text Available Fourier Transform Infrared (FTIR and Gas Chromatography Mass Spectrometry (GCMS are two common instruments used for analysis of edible oils. The output signal is often analysed on the software attached to the workstations. The processing software is usually individualised for a specific source. The output of GCMS cannot be analysed on the FTIR hence analysts often need to juggle between instruments when multiple techniques are employed. This could become exhaustive when a large dataset is involved. This paper reports a synchronised approach for analysis of signal from FTIR and GCMS. The algorithm is demonstrated on a dataset of edible oils to investigate the thermal degradation of seven types of edible oils treated at 100°C and 150°C. The synchronised routines identify peaks present in FTIR and GCMS spectra/chromatograms where the information is subsequently extracted onto peak tables for further analysis. In this study, it is found that palm based products and corn oils were relatively more stable with higher content of antioxidants tocopherols and squalene. As a conclusion, this approach allows simultaneous analysis of signal from multiple sources and samples enhancing the efficiency of the signal processing process.

  5. Tracing star formation with non-thermal radio emission

    Science.gov (United States)

    Schober, Jennifer; Schleicher, D. R. G.; Klessen, R. S.

    2017-06-01

    A key for understanding the evolution of galaxies and in particular their star formation history will be future ultradeep radio surveys. While star formation rates (SFRs) are regularly estimated with phenomenological formulas based on the local FIR-radio correlation, we present here a physically motivated model to relate star formation with radio fluxes. Such a relation holds only in frequency ranges where the flux is dominated by synchrotron emission, as this radiation originates from cosmic rays produced in supernova remnants, therefore reflecting recent star formation. At low frequencies, synchrotron emission can be absorbed by the free-free mechanism. This suppression becomes stronger with increasing number density of the gas, more precisely of the free electrons. We estimate the critical observing frequency below which radio emission is not tracing the SFR, and use the three well-studied local galaxies M51, M82, and Arp 220 as test cases for our model. If the observed galaxy is at high redshift, this critical frequency moves along with other spectral features to lower values in the observing frame. In the absence of systematic evolutionary effects, one would therefore expect that the method can be applied at lower observing frequencies for high-redshift observations. However, in case of a strong increase of the typical gas column densities towards high redshift, the increasing free-free absorption may erase the star formation signatures at low frequencies. At high radio frequencies both, free-free emission and the thermal bump, can dominate the spectrum, also limiting the applicability of this method.

  6. MER1 MARS MINIATURE THERMAL EMISSION SPECTROMETER BTR V1.0

    Data.gov (United States)

    National Aeronautics and Space Administration — This archive contains Mars Exploration Rover Miniature Thermal Emission Spectrometer (Mini-TES) Brightness Temperature Reduced Data Record (BTR) products and...

  7. MID-INFRARED ATOMIC FINE-STRUCTURE EMISSION-LINE SPECTRA OF LUMINOUS INFRARED GALAXIES: SPITZER/IRS SPECTRA OF THE GOALS SAMPLE

    Energy Technology Data Exchange (ETDEWEB)

    Inami, H. [National Optical Astronomy Observatory, Tucson, AZ 85719 (United States); Armus, L.; Stierwalt, S.; Díaz-Santos, T.; Surace, J.; Howell, J.; Marshall, J. [Spitzer Science Center, California Institute of Technology, CA 91125 (United States); Charmandaris, V. [Department of Physics and Institute of Theoretical and Computational Physics, University of Crete, GR-71003 Heraklion (Greece); Groves, B. [Max Planck Institute for Astronomy, Königstuhl 17, D-69117 Heidelberg (Germany); Kewley, L. [Research School of Astronomy and Astrophysics, The Australian National University, Cotter Road, Weston Creek, ACT 2611 (Australia); Petric, A. [Department of Astronomy, California Institute of Technology, MS 320-47, Pasadena, CA 91125 (United States); Rich, J. [The Observatories, Carnegie Institute of Washington, 813 Santa Barbara Street, Pasadena, CA 91101 (United States); Haan, S. [CSIRO Astronomy and Space Science, Marsfield, NSW 2122 (Australia); Evans, A. S. [Department of Astronomy, University of Virginia, P.O. Box 400325, Charlottesville, VA 22904 (United States); Mazzarella, J.; Lord, S. [Infrared Processing and Analysis Center, MS 100-22, California Institute of Technology, Pasadena, CA 91125 (United States); Appleton, P. [NASA Herschel Science Center, 770 South Wilson Avenue, Pasadena, CA 91125 (United States); Spoon, H. [Astronomy Department, Cornell University, Ithaca, NY 14853 (United States); Frayer, D. [National Radio Astronomy Observatory, P.O. Box 2, Green Bank, WV 24944 (United States); Matsuhara, H., E-mail: inami@noao.edu [Institute of Space and Astronautical Science, Japan Aerospace Exploration Agency (Japan); and others

    2013-11-10

    We present the data and our analysis of mid-infrared atomic fine-structure emission lines detected in Spitzer/Infrared Spectrograph high-resolution spectra of 202 local Luminous Infrared Galaxies (LIRGs) observed as part of the Great Observatories All-sky LIRG Survey (GOALS). We readily detect emission lines of [S IV], [Ne II], [Ne V], [Ne III], [S III]{sub 18.7{sub μm}}, [O IV], [Fe II], [S III]{sub 33.5{sub μm}}, and [Si II]. More than 75% of these galaxies are classified as starburst-dominated sources in the mid-infrared, based on the [Ne V]/[Ne II] line flux ratios and equivalent width of the 6.2 μm polycyclic aromatic hydrocarbon feature. We compare ratios of the emission-line fluxes to those predicted from stellar photo-ionization and shock-ionization models to constrain the physical and chemical properties of the gas in the starburst LIRG nuclei. Comparing the [S IV]/[Ne II] and [Ne III]/[Ne II] line ratios to the Starburst99-Mappings III models with an instantaneous burst history, the emission-line ratios suggest that the nuclear starbursts in our LIRGs have ages of 1-4.5 Myr, metallicities of 1-2 Z{sub ☉}, and ionization parameters of 2-8 × 10{sup 7} cm s{sup –1}. Based on the [S III]{sub 33.5{sub μm}}/[S III]{sub 18.7{sub μm}} ratios, the electron density in LIRG nuclei is typically one to a few hundred cm{sup –3}, with a median electron density of ∼300 cm{sup –3}, for those sources above the low density limit for these lines. We also find that strong shocks are likely present in 10 starburst-dominated sources of our sample. A significant fraction of the GOALS sources (80) have resolved neon emission-line profiles (FWHM ≥600 km s{sup –1}) and five show clear differences in the velocities of the [Ne III] or [Ne V] emission lines, relative to [Ne II], of more than 200 km s{sup –1}. Furthermore, six starburst and five active galactic nucleus dominated LIRGs show a clear trend of increasing line width with ionization potential

  8. State-by-state emission spectra fitting for non-equilibrium plasmas: OH spectra of surface barrier discharge at argon/water interface

    Science.gov (United States)

    Voráč, Jan; Synek, Petr; Procházka, Vojtěch; Hoder, Tomáš

    2017-07-01

    Optical emission spectroscopy applied to non-equilibrium plasmas in molecular gases can give important information on basic plasma parameters, including the rotational and vibrational temperatures and densities of the investigated radiative states. In order to precisely understand the non-equilibrium of rotational-vibrational state distribution from the investigated spectra without limiting presumptions, a state-by-state temperature-independent fitting procedure is the ideal approach. In this paper, we present a novel software tool developed for this purpose, freely available for the scientific community. The introduced tool offers a convenient way to construct Boltzmann plots even from partially overlapping spectra, in a user-friendly environment. We apply the novel software to the challenging case of OH spectra in surface streamer discharges generated from the triple-line of the argon/water/dielectrics interface. After the barrier discharge is characterised by ICCD and electrical measurements, the spatially and phase resolved rotational temperatures from N2(C-B) and OH(A-X) spectra are determined and compared. The precise analysis shows that OH(A) states with quantum numbers ≤ft({{v}\\prime}=0,~9≤slant {{N}\\prime}≤slant 13\\right) are overpopulated with respect to the found two-Boltzmann distribution. We hypothesise that fast vibrational-energy transfer is responsible for this phenomenon, observed here for the first time. Finally, the vibrational temperature of the plasma and the relative populations of hot and cold OH(A) states are quantified spatially and phase resolved.

  9. Photoluminescence emission spectra of Makrofol® DE 1-1 upon irradiation with ultraviolet radiation

    Directory of Open Access Journals (Sweden)

    M. El Ghazaly

    Full Text Available Photoluminescence (PL emission spectra of Makrofol® DE 1-1 (bisphenol-A based polycarbonate upon irradiation with ultraviolet radiation of different wavelengths were investigated. The absorption-and attenuation coefficient measurements revealed that the Makrofol® DE 1-1 is characterized by high absorbance in the energy range 6.53–4.43 eV but for a lower energy than 4.43 eV, it is approximately transparent. Makrofol® DE 1-1 samples were irradiated with ultraviolet radiation of wavelength in the range from 250 (4.28 eV to 400 (3.10 eV nm in step of 10 nm and the corresponding photoluminescence (PL emission spectra were measured with a spectrofluorometer. It is found that the integrated counts and the peak height of the photoluminescence emission (PL bands are strongly correlated with the ultraviolet radiation wavelength. They are increased at the ultraviolet radiation wavelength 280 nm and have maximum at 290 nm, thereafter they decrease and diminish at 360 nm of ultraviolet wavelength. The position of the PL emission band peak was red shifted starting from 300 nm, which increased with the increase the ultraviolet radiation wavelength. The PL bandwidth increases linearly with the increase of the ultraviolet radiation wavelength. When Makrofol® DE 1-1 is irradiated with ultraviolet radiation of short wavelength (UVC, the photoluminescence emission spectra peaks also occur in the UVC but of a relatively longer wavelength. The current new findings should be considered carefully when using Makrofol® DE 1-1 in medical applications related to ultraviolet radiation. Keywords: Photoluminescence spectra, Makrofol® DE 1-1, UV–vis spectrophotometry, Attenuation coefficient, Ultraviolet radiation

  10. Control over emissivity of zero-static-power thermal emitters based on phase changing material GST

    CERN Document Server

    Du, Kaikai; Lyu, Yanbiao; Ding, Jichao; Lu, Yue; Cheng, Zhiyuan; Qiu, Min

    2016-01-01

    Controlling the emissivity of a thermal emitter has attracted growing interest with a view towards a new generation of thermal emission devices. So far, all demonstrations have involved sustained external electric or thermal consumption to maintain a desired emissivity. Here control over the emissivity of a thermal emitter consisting of a phase changing material Ge2Sb2Te5 (GST) film on top of a metal film is demonstrated. This thermal emitter shows broad wavelength-selective spectral emissivity in the mid-infrared. The peak emissivity approaches the ideal blackbody maximum and a maximum extinction ratio of above 10dB is attainable by switching GST between the crystalline and amorphous phases. By controlling the intermediate phases, the emissivity can be continuously tuned. This switchable, tunable, wavelength-selective and thermally stable thermal emitter will pave the way towards the ultimate control of thermal emissivity in the field of fundamental science as well as for energy-harvesting and thermal contro...

  11. Excitation Emission Matrix Spectra (EEMS) of Chromophoric Dissolved Organic Matter Produced during Microbial Incubation

    Science.gov (United States)

    McDonald, N.; Nelson, N. B.; Parsons, R.

    2013-12-01

    The chromophoric or light-absorbing fraction of dissolved organic matter (CDOM) is present ubiquitously in natural waters and has a significant impact on ocean biogeochemistry, affecting photosynthesis and primary production as well direct and indirect photochemical reactions (Siegel et al., 2002; Nelson et al., 2007). It has been largely researched in the past few decades, however the exact chemical composition remains unknown. Instrumental methods of analysis including simultaneous excitation-emission fluorescence spectra have allowed for further insight into source and chemical composition. While certain excitation-emission peaks have been associated with ';marine' sources, they have not been exclusively linked to bacterial production of CDOM (Coble, 1996; Zepp et al., 2004). In this study, ';grazer diluted' seawater samples (70% 0.2μm filtered water; 30% whole water) were collected at the Bermuda Atlantic Time Series (BATS) site in the Sargasso Sea (31° 41' N; 64° 10' W) and incubated with an amendment of labile dissolved organic carbon (10μM C6H12O6), ammonium (1μM NH4Cl) and phosphate (0.1μM K2HPO4) to facilitate bacterial production. These substrates and concentrations have been previously shown to facilitate optimum bacterial and CDOM production (Nelson et al., 2004). Sample depths were chosen at 1m and 200m as water at these depths has been exposed to UV light (the Subtropical Mode Water at 200m has been subducted from the surface) and therefore has low initial concentrations of CDOM. After the samples were amended, they were incubated at in-situ temperatures in the dark for 72 hours, with bacteria counts, UV-Vis absorption and EEMS measurements taken at 6-8 hour intervals. Dissolved organic carbon (DOC) measurements were collected daily. For the surface water experiment specific bacteria populations were investigated using Fluorescence In-Situ Hybridization (FISH) analysis. Results showed a clear production of bacteria and production of CDOM, which

  12. Thermal chemiluminescence from γ-irradiated polytetrafluoroethylene and its emission mechanism: Investigation by multichannel Fourier-transform luminescence spectroscopy

    Science.gov (United States)

    Noguchi, Tsuyoshi; Yamada, Emi; Akai, Nobuyuki; Ishii, Hiroshi; Satoh, Chikahiro; Hironiwa, Takayuki; Millington, Keith R.; Nakata, Munetaka

    2014-10-01

    Thermal chemiluminescence spectra of polytetrafluoroethylene powder irradiated by γ rays in air at room temperature were measured with a multichannel Fourier-transform chemiluminescence spectrometer. The luminescence appeared immediately after heating the irradiated samples at 160, 180 and 200 °C in dry air and in N2 and then disappeared within a few minutes, whereas virgin samples showed no luminescence. The lifetime of luminescence decreased as the heating temperature increased, but the total amount of luminescence at each temperature was nearly constant. From this observation an emission mechanism was derived with the aid of ESR and IR spectroscopy.

  13. Thermal properties of sand from Thermal Emission Spectrometer (TES) and Thermal Emission Imaging System (THEMIS): Spatial variations within the Proctor Crater dune field on Mars

    Science.gov (United States)

    Fenton, Lori K.; Mellon, Michael T.

    2006-06-01

    Thermal inertia, a parameter calculated from surface temperatures obtained from spacecraft, has long been used to quantify the amount of loose, fine-grained material on the Martian surface. With little ``ground truth'' available, studies often refer to Martian dune fields to calibrate thermal inertias. The well-understood physical properties of dune sand make it an ideal basis for comparison to more complex surfaces. However, higher-resolution data sets available from the TES (Thermal Emission Spectrometer onboard Mars Global Surveyor) and THEMIS (Thermal Emission Imaging System onboard Mars Odyssey) show spatial variations in the thermal properties within dune fields, calling into question their effectiveness as controls for thermal inertia studies. In order to explain these variations, we apply a thermal model developed for TES data to a commonly investigated dune field in Noachis Terra, that on the floor of Proctor Crater. We show that in this dune field, the thermal variations on the scale of 30 J m-2 s-0.5 K-1 are present and correlate spatially with aeolian features in the dune field. These variations correspond to three types of surfaces observed in the Mars Orbital Camera Narrow Angle (MOC NA) images: (1) dune sand, (2) interdunes exposing the surface underlying the dune field, and (3) sand-covered interdunes, or dune troughs. Both the interdunes and the dune troughs have cooler nighttime temperatures than the dune sand, corresponding to lower thermal inertia values. The dune troughs may be sand-covered areas with either minor amounts of dust accumulation or a mean sand grain size lower than that of dune sand. Because fine sand grains tend to preferentially accumulate on dune crests rather than in dune troughs, the second hypothesis is considered less likely than the first. This has implications for the recent sedimentary history of the dune field: Dust accumulation in dune troughs may imply that sand saltation is not prevalent enough to scour away all of

  14. X-ray emission and photoelectron spectra of Pr0.5Sr0.5MnO3

    Science.gov (United States)

    Kurmaev, E. Z.; Korotin, M. A.; Galakhov, V. R.; Finkelstein, L. D.; Zabolotzky, E. I.; Efremova, N. N.; Lobachevskaya, N. I.; Stadler, S.; Ederer, D. L.; Callcott, T. A.; Zhou, L.; Moewes, A.; Bartkowski, S.; Neumann, M.; Matsuno, J.; Mizokawa, T.; Fujimori, A.; Mitchell, J.

    1999-05-01

    The results of measurements of x-ray photoelectron (XPS), x-ray emission (XES), and x-ray absorption spectra and local spin-density approximation band structure (LSDA) calculations of Pr0.5Sr0.5MnO3 are presented. The excitation energy dependence of Mn L2,3 and O Kα x-ray emission spectra of Pr0.5Sr0.5MnO3 is measured using tunable synchrotron radiation. The XES measurements yielded no photon energy dependence for the O Kα spectra, but the Mn L2,3 spectra yielded inelastic scattering losses of 2 and 6 eV, corresponding to features in the structure of the occupied part of the valence band. Comparing XPS and XES measurements with LSDA band-structure calculations, one concludes that the electronic structure of the compound consists mainly of Mn 3d and O 2p states. States of 3d character localized at the Mn site predominate near the top of the valence band (VB). Some differences in the Mn 3d distribution in this part of the XPS valence band and Mn L3 XES with d symmetry due to spin-selection rules that govern the Mn L3 XES. In addition, the Mn 3d states distribution is hybridized with the O 2p part of the VB. Mn L3 XES spectra were determined relative to the Fermi energy by assuming normal x-ray emission begins from the lowest level of the p5dn+1L intermediate state (which is the Mn 2p ionizatation threshold). From the local spin-density approximation, the orbital character of the Mn 3d electrons can be assigned eg symmetry at the top of the valence band T2g in the central part of the VB, and equal contributions of eg and t2g states at the bottom of the valence band.

  15. CARBON-RICH GIANT PLANETS: ATMOSPHERIC CHEMISTRY, THERMAL INVERSIONS, SPECTRA, AND FORMATION CONDITIONS

    Energy Technology Data Exchange (ETDEWEB)

    Madhusudhan, Nikku [Department of Astrophysical Sciences, Princeton University, Princeton, NJ 08544 (United States); Mousis, Olivier [Institut UTINAM, CNRS-UMR 6213, Observatoire de Besancon, BP 1615, F-25010 Besancon Cedex (France); Johnson, Torrence V. [Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109 (United States); Lunine, Jonathan I., E-mail: nmadhu@astro.princeton.edu [Department of Astronomy, Cornell University, Ithaca, NY 14853 (United States)

    2011-12-20

    The recent inference of a carbon-rich atmosphere, with C/O {>=} 1, in the hot Jupiter WASP-12b motivates the exotic new class of carbon-rich planets (CRPs). We report a detailed study of the atmospheric chemistry and spectroscopic signatures of carbon-rich giant (CRG) planets, the possibility of thermal inversions in their atmospheres, the compositions of icy planetesimals required for their formation via core accretion, and the apportionment of ices, rock, and volatiles in their envelopes. Our results show that CRG atmospheres probe a unique region in composition space, especially at high temperature (T). For atmospheres with C/O {>=} 1, and T {approx}> 1400 K in the observable atmosphere, most of the oxygen is bound up in CO, while H{sub 2}O is depleted and CH{sub 4} is enhanced by up to two or three orders of magnitude each, compared to equilibrium compositions with solar abundances (C/O = 0.54). These differences in the spectroscopically dominant species for the different C/O ratios cause equally distinct observable signatures in the spectra. As such, highly irradiated transiting giant exoplanets form ideal candidates to estimate atmospheric C/O ratios and to search for CRPs. We also find that the C/O ratio strongly affects the abundances of TiO and VO, which have been suggested to cause thermal inversions in highly irradiated hot Jupiter atmospheres. A C/O = 1 yields TiO and VO abundances of {approx}100 times lower than those obtained with equilibrium chemistry assuming solar abundances, at P {approx} 1 bar. Such a depletion is adequate to rule out thermal inversions due to TiO/VO even in the most highly irradiated hot Jupiters, such as WASP-12b. We estimate the compositions of the protoplanetary disk, the planetesimals, and the envelope of WASP-12b, and the mass of ices dissolved in the envelope, based on the observed atmospheric abundances. Adopting stellar abundances (C/O = 0.44) for the primordial disk composition and low-temperature formation conditions

  16. The Annual Cycle of Water Vapor on Mars as Observed by the Thermal Emission Spectrometer

    Science.gov (United States)

    Smith, Michael D.; Vondrak, Richard R. (Technical Monitor)

    2001-01-01

    Spectra taken by the Mars Global Surveyor Thermal Emission Spectrometer (TES) have been used to monitor the latitude, longitude, and seasonal dependence of water vapor for over one full Martian year (March 1999-March 2001). A maximum in water vapor abundance is observed at high latitudes during mid-summer in both hemispheres, reaching a maximum value of approximately 100 pr-micrometer in the north and approximately 50 pr-micrometer in the south. Low water vapor abundance (water vapor. The latitudinal and seasonal dependence of the decay of the northern summer water vapor maximum implies cross-equatorial transport of water to the southern hemisphere, while there is little or no corresponding transport during the decay of the southern hemisphere summer maximum. The latitude-longitude dependence of annually-averaged water vapor (corrected for topography) has a significant positive correlation with albedo and significant negative correlations with thermal inertia and surface pressure. Comparison of TES results with those retrieved from the Viking Orbiter Mars Atmospheric Water Detectors (MAWD) experiments shows some similar features, but also many significant differences. The southern hemisphere maximum observed by TES was not observed by MAWD and the large latitudinal gradient in annually-averaged water vapor observed by MAWD does not appear in the TES results.

  17. On the origin of green emission in zinc sulfide nanowires prepared by a thermal evaporation method

    Energy Technology Data Exchange (ETDEWEB)

    Trung, D.Q.; Tuan, N.T.; Chung, H.V. [Advanced Institute for Science and Technology (AIST), Hanoi University of Science and Technology (HUST), 01 Dai Co Viet Street, Hanoi 10000 (Viet Nam); Duong, P.H. [Institute of Materials Science (IMS), VAST, Hanoi (Viet Nam); Huy, P.T., E-mail: huy.phamthanh@hust.edu.vn [Advanced Institute for Science and Technology (AIST), Hanoi University of Science and Technology (HUST), 01 Dai Co Viet Street, Hanoi 10000 (Viet Nam)

    2014-09-15

    The optical properties and morphological features of ZnS nanowires fabricated by a thermal evaporation process have been systematically studied. We have observed both ZnS nanowires and ZnO structures in one fabrication batch. One common green emission peak in the photoluminescence spectra centered at 516–520 nm appears and is independent of the don pants of the source materials and the catalytic metals. This peak is attributed to the contribution of ZnO structures by means of X-ray diffraction and Raman spectroscopic analysis. The exponential degradation of the photoluminescence intensity of ZnS and ZnO in air under UV laser irradiation not only indicates the significant role of oxygen diffusing into ZnO structures but also provides additional confirmation regarding the degradation that occurs inside ZnS nanowires. The emission model related to defects and ligand fields that occurs in both ZnS and ZnO as a result of this fabrication approach is discussed. - Highlights: • Degradation of the PL intensity occurring in ZnS:Ag nanowires in air under UV laser irradiation. • The inset displays the direct observation at room temperature of the degradation of both components: ZnS at 448 nm and ZnO at 517 nm. • The exponential decrease implies that oxygen is diffusing into the structure.

  18. An accurate retrieval of leaf water content from mid to thermal infrared spectra using continuous wavelet analysis.

    Science.gov (United States)

    Ullah, Saleem; Skidmore, Andrew K; Naeem, Mohammad; Schlerf, Martin

    2012-10-15

    Leaf water content determines plant health, vitality, photosynthetic efficiency and is an important indicator of drought assessment. The retrieval of leaf water content from the visible to shortwave infrared spectra is well known. Here for the first time, we estimated leaf water content from the mid to thermal infrared (2.5-14.0 μm) spectra, based on continuous wavelet analysis. The dataset comprised 394 spectra from nine plant species, with different water contents achieved through progressive drying. To identify the spectral feature most sensitive to the variations in leaf water content, first the Directional Hemispherical Reflectance (DHR) spectra were transformed into a wavelet power scalogram, and then linear relations were established between the wavelet power scalogram and leaf water content. The six individual wavelet features identified in the mid infrared yielded high correlations with leaf water content (R(2)=0.86 maximum, 0.83 minimum), as well as low RMSE (minimum 8.56%, maximum 9.27%). The combination of four wavelet features produced the most accurate model (R(2)=0.88, RMSE=8.00%). The models were consistent in terms of accuracy estimation for both calibration and validation datasets, indicating that leaf water content can be accurately retrieved from the mid to thermal infrared domain of the electromagnetic radiation. Copyright © 2012 Elsevier B.V. All rights reserved.

  19. On the Diffuse Non-thermal Emission from Galaxy Clusters

    Science.gov (United States)

    Donnert, J.

    2011-07-01

    A number of galaxy clusters show complex radio emission not associable with optical counterparts. These objects are commonly classified as radio relics, radio mini halos and giant radio halos. The latter are diffuse Mpc-sized objects centred on the intra-cluster medium (ICM) and are commonly observed in merging clusters. In this work we investigate the formation of radio halos by means of astrophysical numerical simulations. Radio halos (RH) are observed in the GHz regime and show a complex broken power-law emission spectrum. This points to a population of relativistic electrons (CRe) interacting with the magnetic field present in the intra-cluster medium and emitting radio synchrotron radiation. Furthermore RH are transient phenomena, as inferred from the bimodal distribution of radio bright and radio quiet clusters found early on. Their scaling relations with thermal cluster observables breaks the self-similar model established from X-ray observations. In general, relativistic particles are injected strongly localised by shocks and galactic outflows into the ICM with a power-law spectrum. They are then subject to energy losses via inverse Compton, synchrotron, bremsstrahlung and Coulomb processes. This results in a limited lifetime of cosmic-ray electrons at synchrotron bright energies in the intra-cluster medium of ≈ 10^8 yrs. However, due to their interaction with the complex magnetic field of the ICM, it can be shown that cosmic-ray electrons have their effective diffusion speed limited to the Alven velocity in the thermal plasma. This poses a problem on the formation of radio halos, because it is unclear how the cluster-wide synchrotron bright population of CRe, necessary to make a radio halo, can be maintained under these conditions. Currently two competing models are heavily discussed to solve this problem. Hadronic (secondary) models consider the hadronic interaction of relativistic protons (CRp) with the thermal gas of the ICM. In contrast to CR

  20. Thermal emissions and climate change: Cooler options for future energy technology

    OpenAIRE

    Cowern, Nick E. B.; Ahn, Chihak

    2008-01-01

    Global warming arises from 'temperature forcing', a net imbalance between energy fluxes entering and leaving the climate system and arising within it. Humanity introduces temperature forcing through greenhouse gas emissions, agriculture, and thermal emissions from fuel burning. Up to now climate projections, neglecting thermal emissions, typically foresee maximum forcing around the year 2050, followed by a decline. In this paper we show that, if humanity's energy use grows at 1%/year, slower ...

  1. Carrier thermalization under stimulated emission in In{sub 0.17}Ga{sub 0.83}N epilayer at room temperature

    Energy Technology Data Exchange (ETDEWEB)

    Shang, Z. J.; Yang, C.; Chen, Y., E-mail: xinhezheng@ustb.edu.cn, E-mail: ychen@ee.ecnu.edu.cn; Li, B.; Sun, L.; Tang, Z. [Key Laboratory of Polar Materials and Devices, East China Normal University, Shanghai 200241 (China); Zheng, X. H., E-mail: xinhezheng@ustb.edu.cn, E-mail: ychen@ee.ecnu.edu.cn [Department of Physics, Beijing University of Science and Technology, Beijing 100083, People' s Republic of China and Suzhou Institute of Nano-Tech and Nano-Bionics (SINANO), Chinese Academy of Science, Suzhou 215123 (China); Zhao, D. G. [Institute of Semiconductors, Chinese Academy of Science, Beijing 100083 (China)

    2014-12-08

    We elucidate a strong room temperature stimulated emission (SE) of In{sub 0.17}Ga{sub 0.83}N epilayer grown by molecular beam epitaxy under the subpicosecond pulse excitation. The SE peak at 428 nm emerges on the higher energy side of the spontaneous emission in photoluminescence spectra when the excitation density exceeds the threshold of ∼3.68 mJ/cm{sup 2}. Nondegenerate transient differential reflectivity measurements show that a multi-stage carrier thermalization from excited states to localized edge states and stimulated emission dominate the decay processes of photogenerated carriers under various excitation densities. Our results indicate that the existence of phonon bottleneck effect could result in a slow thermalization process in the InGaN material even under the condition of stimulated emission.

  2. Thermal Infrared Emission Spectroscopy of Synthetic Allophane and its Potential Formation on Mars

    Science.gov (United States)

    Rampe, E. B.; Kraft, M. D.; Sharp, T. G.; Golden, D. C.; Ming, Douglas W.

    2010-01-01

    Allophane is a poorly-crystalline, hydrous aluminosilicate with variable Si/Al ratios approx.0.5-1 and a metastable precursor of clay minerals. On Earth, it forms rapidly by aqueous alteration of volcanic glass under neutral to slightly acidic conditions [1]. Based on in situ chemical measurements and the identification of alteration phases [2-4], the Martian surface is interpreted to have been chemically weathered on local to regional scales. Chemical models of altered surfaces detected by the Mars Exploration Rover Spirit in Gusev crater suggest the presence of an allophane-like alteration product [3]. Thermal infrared (TIR) spectroscopy and spectral deconvolution models are primary tools for determining the mineralogy of the Martian surface [5]. Spectral models of data from the Thermal Emission Spectrometer (TES) indicate a global compositional dichotomy, where high latitudes tend to be enriched in a high-silica material [6,7], interpreted as high-silica, K-rich volcanic glass [6,8]. However, later interpretations proposed that the high-silica material may be an alteration product (such as amorphous silica, clay minerals, or allophane) and that high latitude surfaces are chemically weathered [9-11]. A TIR spectral library of pure minerals is available for the public [12], but it does not contain allophane spectra. The identification of allophane on the Martian surface would indicate high water activity at the time of its formation and would help constrain the aqueous alteration environment [13,14]. The addition of allophane to the spectral library is necessary to address the global compositional dichotomy. In this study, we characterize a synthetic allophane by IR spectroscopy, X-ray diffraction (XRD), and transmission electron microscopy (TEM) to create an IR emission spectrum of pure allophane for the Mars science community to use in Martian spectral models.

  3. Multi-Color QWIP FPAs for Hyperspectral Thermal Emission Instruments

    Science.gov (United States)

    Soibel, Alexander; Luong, Ed; Mumolo, Jason M.; Liu, John; Rafol, Sir B.; Keo, Sam A.; Johnson, William; Willson, Dan; Hill, Cory J.; Ting, David Z.-Y.; hide

    2012-01-01

    Infrared focal plane arrays (FPAs) covering broad mid- and long-IR spectral ranges are the central parts of the spectroscopic and imaging instruments in several Earth and planetary science missions. To be implemented in the space instrument these FPAs need to be large-format, uniform, reproducible, low-cost, low 1/f noise, and radiation hard. Quantum Well Infrared Photodetectors (QWIPs), which possess all needed characteristics, have a great potential for implementation in the space instruments. However a standard QWIP has only a relatively narrow spectral coverage. A multi-color QWIP, which is compromised of two or more detector stacks, can to be used to cover the broad spectral range of interest. We will discuss our recent work on development of multi-color QWIP for Hyperspectral Thermal Emission Spectrometer instruments. We developed QWIP compromising of two stacks centered at 9 and 10.5 ?m, and featuring 9 grating regions optimized to maximize the responsivity in the individual subbands across the 7.5-12 ?m spectral range. The demonstrated 1024x1024 QWIP FPA exhibited excellent performance with operability exceeding 99% and noise equivalent differential temperature of less than 15 mK across the entire 7.5-12 ?m spectral range.

  4. A Systematic Study of the Thermal and Nonthermal Emission in the Supernova Remnant RCW 86 with Suzaku

    Science.gov (United States)

    Tsubone, Yoshio; Sawada, Makoto; Bamba, Aya; Katsuda, Satoru; Vink, Jacco

    2017-01-01

    Diffusive shock acceleration by the shockwaves in supernova remnants (SNRs) is widely accepted as the dominant source for Galactic cosmic rays. However, it is unknown what determines the maximum energy of accelerated particles. The surrounding environment could be one of the key parameters. The SNR RCW 86 shows both thermal and nonthermal X-ray emission with different spatial morphologies. These emission originate from the shock-heated plasma and accelerated electrons respectively, and their intensities reflect their density distributions. Thus, the remnant provides a suitable laboratory to test possible association between the acceleration efficiency and the environment. In this paper, we present results of spatially resolved spectroscopy of the entire remnant with Suzaku. The spacially resolved spectra are well reproduced with a combination of a power-law for synchrotron emission and a two-component optically thin thermal plasma, corresponding to the shocked interstellar medium (ISM) with kT of 0.3-0.6 keV and Fe-dominated ejecta. It is discovered that the photon index of the nonthermal component becomes smaller when decreasing the emission measure of the shocked ISM, where the shock speed has remained high. This result implies that the maximum energy of accelerated electrons in RCW 86 is higher in the low-density and higher shock speed regions.

  5. [Spectra and thermal analysis of the arc in activating flux plasma arc welding].

    Science.gov (United States)

    Chai, Guo-Ming; Zhu, Yi-Feng

    2010-04-01

    In activating flux plasma arc welding the welding arc was analyzed by spectra analysis technique, and the welding arc temperature field was measured by the infrared sensing and computer image technique. The distribution models of welding arc heat flow density of activating flux PAW welding were developed. The composition of welding arc affected by activated flux was studied, and the welding arc temperature field was studied. The results show that the spectral lines of argon atom and ionized argon atom of primary ionization are the main spectra lines of the conventional plasma welding arc. The spectra lines of weld metal are inappreciable in the spectra lines of the conventional plasma welding arc. The gas particle is the main in the conventional plasma welding arc. The conventional plasma welding arc is gas welding arc. The spectra lines of argon atom and ionized argon atom of primary ionization are intensified in the activating flux plasma welding arc, and the spectra lines of Ti, Cr and Fe elements are found in the activating flux plasma welding arc. The welding arc temperature distribution in activating flux plasma arc welding is compact, the outline of the welding arc temperature field is narrow, the range of the welding arc temperature distribution is concentrated, the welding arc radial temperature gradient is large, and the welding arc radial temperature gradient shows normal Gauss distribution.

  6. Study of the structural characteristics of a group of natural silicates by means of their K{beta} emission spectra

    Energy Technology Data Exchange (ETDEWEB)

    Torres Deluigi, Maria Torres [Departamento de Fisica, Facultad de Ciencias Fisico, Matematicas y Naturales, Universidad Nacional de San Luis, Chacabuco 917, CP 5700 San Luis (Argentina); Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET), Rivadavia 1917, CP C1033 AAJ, Buenos Aires (Argentina)], E-mail: charo@unsl.edu.ar; Strasser, Edgardo N. [Departamento de Geologia, Facultad de Ciencias Fisico, Matematicas y Naturales, Universidad Nacional de San Luis, Chacabuco 917, CP 5700 San Luis (Argentina); Vasconcellos, Marcos A.Z. [Instituto de Fisica, Universidade Federal do Rio Grande do Sul, Av. Bento Goncalves 9500, CP 15051, 91501-970 Porto Alegre, RS (Brazil); Riveros, Jose A. [Facultad de Matematica, Astronomia y Fisica, Universidad Nacional de Cordoba, Medina Allende y Haya de la Torre, CP 5000 Cordoba (Argentina); Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET), Rivadavia 1917, CP C1033 AAJ, Buenos Aires (Argentina)

    2006-04-21

    In this work, the Si K{beta} and Al K{beta} emission spectra of a group of natural silicates typical of a region in San Luis (Argentina) are described qualitatively within the frame of the Molecular Orbital (MO) theory. Since these spectra come from electron transitions from valence orbitals, they offer information on the chemical bonds that are present and on the molecular orbitals involved. The spectra were obtained by means of an electron microprobe. The energies, intensities and full-width at half-maximum (FWHM) of the lines that conform the silicon and aluminium K{beta} spectra were quantified. It was observed that an increase in the number of oxygen ions shared by the tetrahedra (SiO{sub 4}){sup 4-} caused a lineal increase in the FWHM of the Si K{beta}{sub 1,3} and Al K{beta}{sub 1,3} lines. This behavior is caused by the increase of the covalent character of the Si-O and Al-O bonds with the quantity of oxygen ions shared by the adjacent tetrahedra.

  7. The multi-resolution capability of Tchebichef moments and its applications to the analysis of fluorescence excitation-emission spectra

    Science.gov (United States)

    Li, Bao Qiong; Wang, Xue; Li Xu, Min; Zhai, Hong Lin; Chen, Jing; Liu, Jin Jin

    2018-01-01

    Fluorescence spectroscopy with an excitation-emission matrix (EEM) is a fast and inexpensive technique and has been applied to the detection of a very wide range of analytes. However, serious scattering and overlapping signals hinder the applications of EEM spectra. In this contribution, the multi-resolution capability of Tchebichef moments was investigated in depth and applied to the analysis of two EEM data sets (data set 1 consisted of valine-tyrosine-valine, tryptophan-glycine and phenylalanine, and data set 2 included vitamin B1, vitamin B2 and vitamin B6) for the first time. By means of the Tchebichef moments with different orders, the different information in the EEM spectra can be represented. It is owing to this multi-resolution capability that the overlapping problem was solved, and the information of chemicals and scatterings were separated. The obtained results demonstrated that the Tchebichef moment method is very effective, which provides a promising tool for the analysis of EEM spectra. It is expected that the applications of Tchebichef moment method could be developed and extended in complex systems such as biological fluids, food, environment and others to deal with the practical problems (overlapped peaks, unknown interferences, baseline drifts, and so on) with other spectra.

  8. Practical use of corrected fluorescence excitation and emission spectra of fluorescent proteins in Förster Resonance Energy Transfer (FRET) studies

    NARCIS (Netherlands)

    Hink, M.A.; Visser, N.V.; Borst, J.W.; Hoek, van A.; Visser, A.J.W.G.

    2003-01-01

    Corrected fluorescence excitation and emission spectra have been obtained from several enhanced variants of the green fluorescent protein (EGFP) isolated from the jellyfish Aequorea victoria, blue fluorescence protein (EBFP), cyan fluorescent protein (ECFP), EGFP and yellow fluorescent protein

  9. Suzaku Observations of Thermal and Non-Thermal X-Ray Emission from the Middle-Aged Supernova Remnant G156.2+5.7

    Science.gov (United States)

    Katsuda, Satoru; Petre, Robert; Hwang, Una; Yamaguchi, Hiroya; Mori, Koji; Tsunemi, Hiroshi

    2008-01-01

    We present results from X-ray analysis of a Galactic middle-aged supernova remnant (SNR) G156.2+5.7 which is bright and largely extended in X-ray wavelengths, showing a clear circular shape (radius approx.50'). Using the Suzaku satellite, we observed this SNR in three pointings; partially covering the northwestern (NW) rim, the eastern (E) rim, and the central portion of this SNR. In the NW rim and the central portion, we confirm that the X-ray spectra consist of soft and hard-tail emission, while in the E rim we find no significant hard-tail emission. The soft emission is well fitted by either a one-component or two-component non-equilibrium ionization (NEI) model. In the NW and E rims, a one-component (the swept-up interstellar medium) NEI model well represents the soft emission. On the other hand, in the central portion, a two-component (the interstellar medium and the metal-rich ejecta) NEI model fits the soft emission better than the one-component NEI model from a statistical point of view. The relative abundances in the ejecta component suggest that G156.2+5.7 is a remnant from a core-collapse SN explosion whose progenitor mass is less than 15 Solar Mass. The origin of the hard-tail emission detected in the NW rim and the central portion of the SNR is highly likely non-thermal synchrotron emission from relativistic electrons. In the NW rim, the relativistic electrons seems to be accelerated by a forward shock with a slow velocity of APPROX.500 km/sec.

  10. Measurement of Excitation Spectra in the 12/SUP>C 1(p ,d ) Reaction near the η' Emission Threshold

    Science.gov (United States)

    Tanaka, Y. K.; Itahashi, K.; Fujioka, H.; Ayyad, Y.; Benlliure, J.; Brinkmann, K.-T.; Friedrich, S.; Geissel, H.; Gellanki, J.; Guo, C.; Gutz, E.; Haettner, E.; Harakeh, M. N.; Hayano, R. S.; Higashi, Y.; Hirenzaki, S.; Hornung, C.; Igarashi, Y.; Ikeno, N.; Iwasaki, M.; Jido, D.; Kalantar-Nayestanaki, N.; Kanungo, R.; Knöbel, R.; Kurz, N.; Metag, V.; Mukha, I.; Nagae, T.; Nagahiro, H.; Nanova, M.; Nishi, T.; Ong, H. J.; Pietri, S.; Prochazka, A.; Rappold, C.; Reiter, M. P.; Rodríguez-Sánchez, J. L.; Scheidenberger, C.; Simon, H.; Sitar, B.; Strmen, P.; Sun, B.; Suzuki, K.; Szarka, I.; Takechi, M.; Tanihata, I.; Terashima, S.; Watanabe, Y. N.; Weick, H.; Widmann, E.; Winfield, J. S.; Xu, X.; Yamakami, H.; Zhao, J.; η-PRiME/Super-FRS Collaboration

    2016-11-01

    Excitation spectra of 11C are measured in the 12C (p ,d ) reaction near the η' emission threshold. A proton beam extracted from the synchrotron SIS-18 at GSI with an incident energy of 2.5 GeV impinges on a carbon target. The momenta of deuterons emitted at 0° are precisely measured with the fragment separator (FRS) operated as a spectrometer. In contrast to theoretical predictions on the possible existence of deeply bound η'-mesic states in carbon nuclei, no distinct structures are observed associated with the formation of bound states. The spectra are analyzed to set stringent constraints on the formation cross section and on the hitherto barely known η'-nucleus interaction.

  11. Measurement of Excitation Spectra in the ^{12}C(p,d) Reaction near the η^{'} Emission Threshold.

    Science.gov (United States)

    Tanaka, Y K; Itahashi, K; Fujioka, H; Ayyad, Y; Benlliure, J; Brinkmann, K-T; Friedrich, S; Geissel, H; Gellanki, J; Guo, C; Gutz, E; Haettner, E; Harakeh, M N; Hayano, R S; Higashi, Y; Hirenzaki, S; Hornung, C; Igarashi, Y; Ikeno, N; Iwasaki, M; Jido, D; Kalantar-Nayestanaki, N; Kanungo, R; Knöbel, R; Kurz, N; Metag, V; Mukha, I; Nagae, T; Nagahiro, H; Nanova, M; Nishi, T; Ong, H J; Pietri, S; Prochazka, A; Rappold, C; Reiter, M P; Rodríguez-Sánchez, J L; Scheidenberger, C; Simon, H; Sitar, B; Strmen, P; Sun, B; Suzuki, K; Szarka, I; Takechi, M; Tanihata, I; Terashima, S; Watanabe, Y N; Weick, H; Widmann, E; Winfield, J S; Xu, X; Yamakami, H; Zhao, J

    2016-11-11

    Excitation spectra of ^{11}C are measured in the ^{12}C(p,d) reaction near the η^{'} emission threshold. A proton beam extracted from the synchrotron SIS-18 at GSI with an incident energy of 2.5 GeV impinges on a carbon target. The momenta of deuterons emitted at 0° are precisely measured with the fragment separator (FRS) operated as a spectrometer. In contrast to theoretical predictions on the possible existence of deeply bound η^{'}-mesic states in carbon nuclei, no distinct structures are observed associated with the formation of bound states. The spectra are analyzed to set stringent constraints on the formation cross section and on the hitherto barely known η^{'}-nucleus interaction.

  12. Measurement of excitation spectra in the ${}^{12}$C$(p,d)$ reaction near the $\\eta'$ emission threshold

    CERN Document Server

    Tanaka, Y K; Fujioka, H; Ayyad, Y; Benlliure, J; Brinkmann, K -T; Friedrich, S; Geissel, H; Gellanki, J; Guo, C; Gutz, E; Haettner, E; Harakeh, M N; Hayano, R S; Higashi, Y; Hirenzaki, S; Hornung, C; Igarashi, Y; Ikeno, N; Iwasaki, M; Jido, D; Kalantar-Nayestanaki, N; Kanungo, R; Knöbel, R; Kurz, N; Metag, V; Mukha, I; Nagae, T; Nagahiro, H; Nanova, M; Nishi, T; Ong, H J; Pietri, S; Prochazka, A; Rappold, C; Reiter, M P; Rodríguez-Sánchez, J L; Scheidenberger, C; Simon, H; Sitar, B; Strmen, P; Sun, B; Suzuki, K; Szarka, I; Takechi, M; Tanihata, I; Terashima, S; Watanabe, Y N; Weick, H; Widmann, E; Winfield, J S; Xu, X; Yamakami, H; Zhao, J

    2016-01-01

    Excitation spectra of $^{11}$C were measured in the $^{12}$C$(p,d)$ reaction near the $\\eta'$ emission threshold. A proton beam extracted from the synchrotron SIS-18 at GSI with an incident energy of 2.5 GeV impinged on a carbon target. The momenta of deuterons emitted at 0 degrees were precisely measured with the fragment separator FRS operated as a spectrometer. In contrast to theoretical predictions on the possible existence of deeply bound $\\eta'$ mesic states in carbon nuclei, no distinct structures were observed associated with the formation of bound states. The spectra were analyzed to set stringent constraints on the formation cross section and on the hitherto barely-known $\\eta'$-nucleus interaction.

  13. Emissions, energy return and economics from utilizing forest residues for thermal energy compared to onsite pile burning

    Science.gov (United States)

    Greg Jones; Dan Loeffler; Edward Butler; Woodam Chung; Susan Hummel

    2010-01-01

    The emissions from delivering and burning forest treatment residue biomass in a boiler for thermal energy were compared with onsite disposal by pile-burning and using fossil fuels for the equivalent energy. Using biomass for thermal energy reduced carbon dioxide emissions on average by 39 percent and particulate matter emissions by 89 percent for boilers with emission...

  14. Power electronics solution to dust emissions from thermal power plants

    Directory of Open Access Journals (Sweden)

    Vukosavić Slobodan

    2010-01-01

    Full Text Available Thermal power stations emit significant amounts of fly ash and ultra fine particles into the atmosphere. Electrostatic precipitators (ESP or electro filters remove flying ashes and fine particles from the flue gas before passing the gas into the chimney. Maximum allowable value of dust is 50 mg/m3 and it requires that the efficiency of the ESPs better than 99 %, which calls for an increase of active surface of the electrodes, hence increasing the filter volume and the weight of steel used for the filter. In previous decades, electrostatic precipitators in thermal power plants were fed by thyristor controlled, single phase fed devices having a high degree of reliability, but with a relatively low collection efficiency, hence requiring large effective surface of the collection plates and a large weight of steel construction in order to achieve the prescribed emission limits. Collection efficiency and energy efficiency of the electrostatic precipitator can be increased by applying high frequency high voltage power supply (HF HV. Electrical engineering faculty of the University of Belgrade (ETF has developed technology and HF HV equipment for the ESP power supply. This solution was subjected to extensive experimental investigation at TE Morava from 2008 to 2010. High frequency power supply is proven to reduce emission two times in controlled conditions while increasing energy efficiency of the precipitator, compared to the conventional thyristor controlled 50Hz supply. Two high frequency high voltage unit AR70/1000 with parameters 70 kV and 1000 mA are installed at TE Morava and thoroughly testes. It was found that the HF HV power supply of the ESP at TE Morava increases collection efficiency so that emission of fine particles and flying ashes are halved, brought down to only 50 % of the emissions encountered with conventional 50 Hz thyristor driven power supplies. On the basis of this study, conclusion is drawn that the equipment comprising HF HV

  15. Hot topic: Innovative lactation-stage-dependent prediction of methane emissions from milk mid-infrared spectra.

    Science.gov (United States)

    Vanlierde, A; Vanrobays, M-L; Dehareng, F; Froidmont, E; Soyeurt, H; McParland, S; Lewis, E; Deighton, M H; Grandl, F; Kreuzer, M; Gredler, B; Dardenne, P; Gengler, N

    2015-08-01

    The main goal of this study was to develop, apply, and validate a new method to predict an indicator for CH4 eructed by dairy cows using milk mid-infrared (MIR) spectra. A novel feature of this model was the consideration of lactation stage to reflect changes in the metabolic status of the cow. A total of 446 daily CH4 measurements were obtained using the SF6 method on 142 Jersey, Holstein, and Holstein-Jersey cows. The corresponding milk samples were collected during these CH4 measurements and were analyzed using MIR spectroscopy. A first derivative was applied to the milk MIR spectra. To validate the novel calibration equation incorporating days in milk (DIM), 2 calibration processes were developed: the first was based only on CH4 measurements and milk MIR spectra (independent of lactation stage; ILS); the second included milk MIR spectra and DIM information (dependent on lactation stage; DLS) by using linear and quadratic modified Legendre polynomials. The coefficients of determination of ILS and DLS equations were 0.77 and 0.75, respectively, with standard error of calibration of 63g/d of CH4 for both calibration equations. These equations were applied to 1,674,763 milk MIR spectra from Holstein cows in the first 3 parities and between 5 and 365 DIM. The average CH4 indicators were 428, 444, and 448g/d by ILS and 444, 467, and 471g/d by DLS for cows in first, second, and third lactation, respectively. Behavior of the DLS indicator throughout the lactations was in agreement with the literature with values increasing between 0 and 100 DIM and decreasing thereafter. Conversely, the ILS indicator of CH4 emission decreased at the beginning of the lactation and increased until the end of the lactation, which differs from the literature. Therefore, the DLS indicator seems to better reflect biological processes that drive CH4 emissions than the ILS indicator. The ILS and DLS equations were applied to an independent data set, which included 59 respiration chamber

  16. Modeling of Light Emission Spectra Measured on Silicon Nanometer-Scale Diode-Antifuses

    NARCIS (Netherlands)

    Akil, N.A.; Houtsma, V.E.; Le Minh, P.; Holleman, J.; Zieren, V.; de Mooij, D.; Woerlee, P.H.; van den Berg, Albert; Wallinga, Hans

    2000-01-01

    Electroluminescence (EL) spectra of nanoscale diodes formed after gate-oxide breakdown of n+-polysilicon/oxide/p+-substrate metal–oxide–semiconductor capacitors were measured in reverse and forward bias. The nanoscale diodes, called diode antifuses, are created by the formation of a small link

  17. Neutron Capture Cross Sections and Gamma Emission Spectra from Neutron Capture on 234,236,238U Measured with DANCE

    Science.gov (United States)

    Ullmann, J. L.; Mosby, S.; Bredeweg, T. A.; Couture, A. J.; Haight, R. C.; Jandel, M.; Kawano, T.; O'Donnell, J. M.; Rundberg, R. S.; Vieira, D. J.; Wilhelmy, J. B.; Wu, C.-Y.; Becker, J. A.; Chyzh, A.; Baramsai, B.; Mitchell, G. E.; Krticka, M.

    2014-05-01

    A new measurement of the 238U(n, γ) cross section using a thin 48 mg/cm2 target was made using the DANCE detector at LANSCE over the energy range from 10 eV to 500 keV. The results confirm earlier measurements. Measurements of the gamma-ray emission spectra were also made for 238U(n, γ) as well as 234,236U(n, γ). These measurements help to constrain the radiative strength function used in the cross-section calculations.

  18. Sonoluminescence and acoustic emission spectra at different stages of cavitation zone development.

    Science.gov (United States)

    Dezhkunov, N V; Francescutto, A; Serpe, L; Canaparo, R; Cravotto, G

    2018-01-01

    The way in which a cavitation zone develops in a focused pulsed ultrasound field is studied in this work. Sonoluminescence (SL), total hydrophone output and cavitation noise spectra have been recorded across a gradual, smooth increase in applied voltage. It is shown that the cavitation zone passes through a number of stages of evolution, according to increasing ultrasound intensity, decreasing pulse period and increasing ultrasound pulse duration. Sonoluminescence is absent in the first phase and the hydrophone output spectra consists of a main line with two or three harmonics whose intensity is much lower than that of the main (fundamental) line. The second stage sees the onset of SL whose intensity increases smoothly and is accompanied by the appearance of higher harmonics and subharmonics in the cavitation noise spectra. In some cases, the wide-band (WBN) component can be seen in noise spectra during the final part of the second stage. In the third stage, SL intensity increases significantly and often quite sharply, while WBN intensity increases in the same manner. This is accompanied by a synchronous increase in the absorption of ultrasound by the cavitation zone, which is manifested in a sharp decrease in the hydrophone output. In the fourth stage, both SL and WBN intensities tend to decrease despite the increased voltage applied to the transducer. Furthermore, the fundamental line tends to decrease in strength as well, despite the increasing ultrasound intensity. The obtained results clearly identify the different stages of cavitation zone development using cavitation noise spectra analyses. We then hypothesize that three of the above stages may be responsible for three known types of ultrasound action on biological cells: damping viability, reversible cell damage (sonoporation) and irreversible damage/cytotoxicity. Copyright © 2017 Elsevier B.V. All rights reserved.

  19. Thermal Infrared Emission Spectroscopy of Synthetic Allophane and Its Potential Formation on Mars

    Science.gov (United States)

    Rampe, E. B.; Kraft, M. D.; Sharp, T. G.; Golden, D. C.; Ming, D. W.

    2010-03-01

    We synthesized allophane, a terrestrial aqueous alteration product, and measured a thermal IR emission spectrum for the public spectral library. The use of this spectrum in martian spectral models can help constrain chemical alteration environments.

  20. Super-Planckian far-zone thermal emission from asymmetric hyperbolic metamaterials

    Energy Technology Data Exchange (ETDEWEB)

    Nefedov, Igor S. [School of Electrical Engineering, Aalto University, P.O. Box 13000, 00076 Aalto (Finland); Melnikov, Leonid A. [Yuri Gagarin State Technical University of Saratov, 77 Politekhnicheskaya, 410054 Saratov (Russian Federation)

    2014-10-20

    We demonstrate the production of strong directive thermal emissions in the far-field zone of asymmetric hyperbolic metamaterials (AHMs), exceeding that predicted by Planck's limit. Asymmetry is inherent to the uniaxial medium, where the optical axis is tilted with respect to medium interfaces. The use of AHMs is shown to enhance the free-space coupling efficiency of thermally radiated waves, resulting in Super-Planckian far-field thermal emission in certain directions. This effect is impossible in usual hyperbolic materials because emission of high density of states (DOS) photons into vacuum with smaller DOS is preserved by the total internal reflection. Different plasmonic metamaterials are proposed for realizing AHM media; the thermal emission from a AHM, based on a grapheme multilayer structure, is presented, as an example.

  1. MER2 MARS MINIATURE THERMAL EMISSION SPECTROMETER RDR V1.0

    Data.gov (United States)

    National Aeronautics and Space Administration — This archive contains Mars Exploration Rover Miniature Thermal Emission Spectrometer (Mini-TES) Reduced Data Record (RDR) products and ancillary files. The Mini-TES...

  2. Diamond fly cutting of aluminum thermal infrared flat mirrors for the OSIRIS-REx Thermal Emission Spectrometer (OTES) instrument

    Science.gov (United States)

    Groppi, Christopher E.; Underhill, Matthew; Farkas, Zoltan; Pelham, Daniel

    2016-07-01

    We present the fabrication and measurement of monolithic aluminum flat mirrors designed to operate in the thermal infrared for the OSIRIS-Rex Thermal Emission Spectrometer (OTES) space instrument. The mirrors were cut using a conventional fly cutter with a large radius diamond cutting tool on a high precision Kern Evo 3-axis CNC milling machine. The mirrors were measured to have less than 150 angstroms RMS surface error.

  3. In situ, simultaneous thermal imaging and infrared molecular emission studies of solid oxide fuel cell electrodes

    Science.gov (United States)

    Kirtley, J. D.; Qadri, S. N.; Steinhurst, D. A.; Owrutsky, J. C.

    2016-12-01

    Various in situ probes of solid oxide fuel cells (SOFCs) have advanced recently to provide detailed, real time data regarding materials and chemical processes that relate to device performance and degradation. These techniques offer insights into complex fuel chemistry at the anode in particular, especially in the context of model predictions. However, cell-to-cell variations can hinder mechanistic interpretations of measurements from separate, independent techniques. The present study describes an in situ technique that for the first time simultaneously measures surface temperature changes using near infrared thermal imaging and gas species using Fourier-transform infrared emission spectra at the anodes of operating SOFCs. Electrolyte-supported SOFCs with Ni-based anodes are operated at 700 °C with internal, dry-reformed methane at 75% maximum current and at open circuit voltage (OCV) while electrochemical and optical measurements are collected. At OCV, more cooling is observed coincident with more CO reforming products. Under load, CO decreases while the anode cools less, especially near the current collectors. The extent of cooling is more sensitive to polarization for electrolyte-supported cells because their anodes are thinner relative to anode-supported cells. This study exemplifies how this duplex technique can be a useful probe of electrochemical processes in SOFCs.

  4. Vanadium Dioxide as a Natural Disordered Metamaterial: Perfect Thermal Emission and Large Broadband Negative Differential Thermal Emittance

    Science.gov (United States)

    Kats, Mikhail A.; Blanchard, Romain; Zhang, Shuyan; Genevet, Patrice; Ko, Changhyun; Ramanathan, Shriram; Capasso, Federico

    2013-10-01

    We experimentally demonstrate that a thin (approximately 150-nm) film of vanadium dioxide (VO2) deposited on sapphire has an anomalous thermal emittance profile when heated, which arises because of the optical interaction between the film and the substrate when the VO2 is at an intermediate state of its insulator-metal transition (IMT). Within the IMT region, the VO2 film comprises nanoscale islands of the metal and dielectric phases and can thus be viewed as a natural, disordered metamaterial. This structure displays “perfect” blackbodylike thermal emissivity over a narrow wavelength range (approximately 40cm-1), surpassing the emissivity of our black-soot reference. We observe large broadband negative differential thermal emittance over a >10°C range: Upon heating, the VO2-sapphire structure emits less thermal radiation and appears colder on an infrared camera. Our experimental approach allows for a direct measurement and extraction of wavelength- and temperature-dependent thermal emittance. We anticipate that emissivity engineering with thin-film geometries comprising VO2 and other thermochromic materials will find applications in infrared camouflage, thermal regulation, and infrared tagging and labeling.

  5. Vanadium Dioxide as a Natural Disordered Metamaterial: Perfect Thermal Emission and Large Broadband Negative Differential Thermal Emittance

    Directory of Open Access Journals (Sweden)

    Mikhail A. Kats

    2013-10-01

    Full Text Available We experimentally demonstrate that a thin (approximately 150-nm film of vanadium dioxide (VO_{2} deposited on sapphire has an anomalous thermal emittance profile when heated, which arises because of the optical interaction between the film and the substrate when the VO_{2} is at an intermediate state of its insulator-metal transition (IMT. Within the IMT region, the VO_{2} film comprises nanoscale islands of the metal and dielectric phases and can thus be viewed as a natural, disordered metamaterial. This structure displays “perfect” blackbodylike thermal emissivity over a narrow wavelength range (approximately 40  cm^{-1}, surpassing the emissivity of our black-soot reference. We observe large broadband negative differential thermal emittance over a >10 °C range: Upon heating, the VO_{2}-sapphire structure emits less thermal radiation and appears colder on an infrared camera. Our experimental approach allows for a direct measurement and extraction of wavelength- and temperature-dependent thermal emittance. We anticipate that emissivity engineering with thin-film geometries comprising VO_{2} and other thermochromic materials will find applications in infrared camouflage, thermal regulation, and infrared tagging and labeling.

  6. Neptune's non-thermal radio emissions - Phenomenology and source locations

    Science.gov (United States)

    Rabl, Gerald K. F.; Ladreiter, H.-P.; Rucker, Helmut O.; Kaiser, Michael L.

    1992-01-01

    During the inbound and the outbound leg of Voyager 2's encounter with Neptune, the Planetary Radio Astronomy (PRA) experiment aboard the spacecraft detected short radio bursts at frequencies within the range of about 500-1300 kHz, and broad-banded smoothly varying emission patterns within the frequency range from about 40-800 kHz. Both emissions can be described in terms of a period of 16.1 hours determining Neptune's rotation period. Furthermore, just near closest approach, a narrow-banded smoothly varying radio component was observed occurring between 600 and 800 kHz. After giving a brief overview about some general characteristics of Neptune's nonthermal radio emission, the source locations of Neptune's emission components are determined, using an offset tilted dipole model for Neptune's magnetic field. Assuming that the emission originates near the electron gyrofrequency a geometrical beaming model is developed in order to fit the observed emission episodes.

  7. Emission and absorption spectra of some bridged 1,5-benzodiazepines

    Science.gov (United States)

    Mellor, J. M.; Pathirana, R. N.; Stibbard, J. H. A.

    Absorption spectra in neutral and acidic media are reported for a series of bridged 1,5-benzodiazepines, which are unable to tautomerize. Comparison is made with non-bridged 1,5-benzodiazepines capable of tautomeric rearrangement. Both bridged and non-bridged 1,5-benzodiazepines are essentially non-fluorescent due to the "proximity effect" of interaction between singlet ηπ* and ππ* states of similar energy, a phenomenon previously recognised in six-membered nitrogen heterocycles.

  8. Emission from water vapor and absorption from other gases at 5-7.5 μm in Spitzer-IRS Spectra Of Protoplanetary Disks

    Energy Technology Data Exchange (ETDEWEB)

    Sargent, B. A. [Center for Imaging Science and Laboratory for Multiwavelength Astrophysics, Rochester Institute of Technology, 54 Lomb Memorial Drive, Rochester, NY 14623 (United States); Forrest, W.; Watson, Dan M.; Kim, K. H.; Richter, I.; Tayrien, C. [Department of Physics and Astronomy, University of Rochester, Rochester, NY 14627 (United States); D' Alessio, P.; Calvet, N. [Department of Astronomy, The University of Michigan, 500 Church Street, 830 Dennison Building, Ann Arbor, MI 48109 (United States); Furlan, E. [National Optical Astronomy Observatory, 950 North Cherry Avenue, Tucson, AZ 85719 (United States); Green, J. [Department of Astronomy, University of Texas, 1 University Station, Austin, TX 78712 (United States); Pontoppidan, K., E-mail: baspci@rit.edu [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States)

    2014-09-10

    We present spectra of 13 T Tauri stars in the Taurus-Auriga star-forming region showing emission in Spitzer Space Telescope Infrared Spectrograph 5-7.5 μm spectra from water vapor and absorption from other gases in these stars' protoplanetary disks. Seven stars' spectra show an emission feature at 6.6 μm due to the ν{sub 2} = 1-0 bending mode of water vapor, with the shape of the spectrum suggesting water vapor temperatures >500 K, though some of these spectra also show indications of an absorption band, likely from another molecule. This water vapor emission contrasts with the absorption from warm water vapor seen in the spectrum of the FU Orionis star V1057 Cyg. The other 6 of the 13 stars have spectra showing a strong absorption band, peaking in strength at 5.6-5.7 μm, which for some is consistent with gaseous formaldehyde (H{sub 2}CO) and for others is consistent with gaseous formic acid (HCOOH). There are indications that some of these six stars may also have weak water vapor emission. Modeling of these stars' spectra suggests these gases are present in the inner few AU of their host disks, consistent with recent studies of infrared spectra showing gas in protoplanetary disks.

  9. On the Absence of Non-thermal X-Ray Emission around Runaway O Stars

    Energy Technology Data Exchange (ETDEWEB)

    Toalá, J. A. [Institute of Astronomy and Astrophysics, Academia Sinica (ASIAA), Taipei 10617, Taiwan (China); Oskinova, L. M. [Institute for Physics and Astronomy, University of Potsdam, D-14476 Potsdam (Germany); Ignace, R. [Department of Physics and Astronomy, East Tennessee State University, Johnson City, TN 37614 (United States)

    2017-04-01

    Theoretical models predict that the compressed interstellar medium around runaway O stars can produce high-energy non-thermal diffuse emission, in particular, non-thermal X-ray and γ -ray emission. So far, detection of non-thermal X-ray emission was claimed for only one runaway star, AE Aur. We present a search for non-thermal diffuse X-ray emission from bow shocks using archived XMM-Newton observations for a clean sample of six well-determined runaway O stars. We find that none of these objects present diffuse X-ray emission associated with their bow shocks, similarly to previous X-ray studies toward ζ Oph and BD+43°3654. We carefully investigated multi-wavelength observations of AE Aur and could not confirm previous findings of non-thermal X-rays. We conclude that so far there is no clear evidence of non-thermal extended emission in bow shocks around runaway O stars.

  10. Acoustic emission spectra and sonochemical activity in a 36 kHz sonoreactor.

    Science.gov (United States)

    Son, Younggyu; Lim, Myunghee; Khim, Jeehyeong; Ashokkumar, Muthupandian

    2012-01-01

    During ultrasound-induced cavitation in liquids, acoustic emissions at fundamental and harmonic frequencies can be detected. The effect of acoustic emissions at harmonic frequencies on the sonochemical and sonophysical activities has not been explored, especially in large-scale sonoreactors. In this study, the acoustic emissions in the range, 0-250 kHz in a 36 kHz sonoreactor with varying liquid heights were studied and compared with the sonochemical activities. The acoustic pressures at both fundamental and harmonics decreased drastically as the liquid height was increased due to the attenuation of sound energy. It was observed that the increase in input power resulted in only an increase in the acoustic emissions at derivative frequencies such as, harmonics and subharmonics. The sonochemical activity, evaluated in terms of sonochemiluminescence and H2O2 yield, was not significantly enhanced at higher input power levels. This suggests that at higher power levels, the "extra" acoustic energy is not effectively used to generate primary cavitation activity; rather it is converted to generate acoustic emissions at harmonic and subharmonic frequencies. This is an important observation for the design of energy efficiency large-scale sonochemical reactors. Copyright © 2011 Elsevier B.V. All rights reserved.

  11. An X-Ray Reprocessing Model of Disk Thermal Emission in Type 1 Seyfert Galaxies

    Science.gov (United States)

    Chiang, James; White, Nicholas E. (Technical Monitor)

    2002-01-01

    Using a geometry consisting of a hot central Comptonizing plasma surrounded by a thin accretion disk, we model the optical through hard X-ray spectral energy distributions of the type 1 Seyfert. galaxies NGC 3516 and NGC 7469. As in the model proposed by Poutanen, Krolik, and Ryde for the X-ray binary Cygnus X-1 and later applied to Seyfert galaxies by Zdziarski, Lubifiski, and Smith, feedback between the radiation reprocessed by the disk and the thermal Comptonization emission from the hot central plasma plays a pivotal role in determining the X-ray spectrum, and as we show, the optical and ultraviolet spectra as well. Seemingly uncorrelated optical/UV and X-ray light curves, similar to those which have been observed from these objects can, in principle, be explained by variations in the size, shape, and temperature of the Comptonizing plasma. Furthermore, by positing a disk mass accretion rate which satisfies a condition for global energy balance between the thermal Comptonization luminosity and the power available from accretion, one can predict the spectral properties of the heretofore poorly measured hard X-ray continuum above approximately 50 keV in type 1 Seyfert galaxies. Conversely, forthcoming measurements of the hard X-ray continuum by more sensitive hard X-ray and soft gamma-ray telescopes, such as those aboard the International Gamma-Ray Astrophysics Laboratory (INTEGRAL) in conjunction with simultaneous optical, UV, and soft X-ray monitoring, will allow the mass accretion rates to be directly constrained for these sources in the context of this model.

  12. Emission Lines in the Near-infrared Spectra of the Infrared Quintuplet Stars in the Galactic Center

    Energy Technology Data Exchange (ETDEWEB)

    Najarro, F. [Departamento de Astrofísica, Centro de Astrobiología (CSIC-INTA), Ctra. Torrejón a Ajalvir km 4, E-28850 Torrejón de Ardoz (Spain); Geballe, T. R. [Gemini Observatory, 670 North A’ohoku Place, Hilo, HI 96720 (United States); Figer, D. F. [Center for Detectors, Rochester Institute of Technology, 74 Lomb Memorial Drive, Rochester, NY 14623 (United States); Fuente, D. de la [Instituto de Astronomía, Unidad Académica en Ensenada, Universidad Nacional Autónoma de México, Ensenada 22860, México (Mexico)

    2017-08-20

    We report the detection of a number of emission lines in the 1.0–2.4 μ m spectra of four of the five bright-infrared dust-embedded stars at the center of the Galactic center’s (GC) Quintuplet Cluster. Spectroscopy of the central stars of these objects is hampered not only by the large interstellar extinction that obscures all of the objects in the GC, but also by the large amounts of warm circumstellar dust surrounding each of the five stars. The pinwheel morphologies of the dust observed previously around two of them are indicative of Wolf–Rayet colliding wind binaries; however, infrared spectra of each of the five have until now revealed only dust continua steeply rising to long wavelengths and absorption lines and bands from interstellar gas and dust. The emission lines detected, from ionized carbon and from helium, are broad and confirm that the objects are dusty late-type carbon Wolf–Rayet stars.

  13. Experimental and theoretical study on emission spectra of a nitrogen photoionized plasma induced by intense EUV pulses

    Directory of Open Access Journals (Sweden)

    Saber Ismail

    2018-01-01

    Full Text Available Spectral lines of low-temperature nitrogen photoionized plasma were investigated. The photoionized plasma was created in the result of irradiation N2 gas using laser plasma EUV radiation pulses. The source was based on a 10J/10ns Nd:YAG (λ = 1064 nm laser system and a gas puff target. The EUV radiation pulses were collected and focused using a grazing incidence multifoil EUV collector. The emission spectra were measured in the ultraviolet and visible (UV/Vis range. It was found that the plasma emission lines in the lower region of the UV range are relativley weak. Nonetheless, a part of the spectra contains strong molecular band in the 300 - 430 nm originated from second positive and first negative systems band transitions of nitrogen. These molecular band transitions were identified using a code for study the diatomic molecules, LIFBASE. The vibrational band of Δv = 0 and ±1 transitions were significantly populated than of that with Δv = ±2 and 3 transitions. A comparison of the calculated and measured spectrum is presented. With an assumption of a local thermodynamic equilibrium (LTE, the vibrational temperature was determined from the integrated band intensities with the help of the Boltzmann plot method and compared to the temperature predicted by SPECAIR and LIFBASE simulations. A summary of the results and the variations in the vibrational temperatures was discussed.

  14. Experimental and theoretical study on emission spectra of a nitrogen photoionized plasma induced by intense EUV pulses

    Science.gov (United States)

    Saber, Ismail; Bartnik, Andrzej; Skrzeczanowski, Wojciech; Wachulak, Przemyslaw; Jarocki, Roman; Fiedorowicz, Henryk; Limpouch, Jiri

    2018-01-01

    Spectral lines of low-temperature nitrogen photoionized plasma were investigated. The photoionized plasma was created in the result of irradiation N2 gas using laser plasma EUV radiation pulses. The source was based on a 10J/10ns Nd:YAG (λ = 1064 nm) laser system and a gas puff target. The EUV radiation pulses were collected and focused using a grazing incidence multifoil EUV collector. The emission spectra were measured in the ultraviolet and visible (UV/Vis) range. It was found that the plasma emission lines in the lower region of the UV range are relativley weak. Nonetheless, a part of the spectra contains strong molecular band in the 300 - 430 nm originated from second positive and first negative systems band transitions of nitrogen. These molecular band transitions were identified using a code for study the diatomic molecules, LIFBASE. The vibrational band of Δv = 0 and ±1 transitions were significantly populated than of that with Δv = ±2 and 3 transitions. A comparison of the calculated and measured spectrum is presented. With an assumption of a local thermodynamic equilibrium (LTE), the vibrational temperature was determined from the integrated band intensities with the help of the Boltzmann plot method and compared to the temperature predicted by SPECAIR and LIFBASE simulations. A summary of the results and the variations in the vibrational temperatures was discussed.

  15. Removal of the free cysteine residue reduces irreversible thermal inactivation of feruloyl esterase: evidence from circular dichroism and fluorescence spectra.

    Science.gov (United States)

    Li, Jingjing; Zhang, Shuaibing; Yi, Zhuolin; Pei, Xiaoqiong; Wu, Zhongliu

    2015-08-01

    Feruloyl esterase A from Aspergillus niger (AnFaeA) contains three intramolecular disulfide bonds and one free cysteine at position 235. Saturated mutagenesis at Cys235 was carried out to produce five active mutants, all of which displayed unusual thermal inactivation patterns with the most residual activity achieved at 75°C, much higher than the parental AnFaeA. But their optimal reaction temperatures were lower than the parental AnFaeA. Extensive investigation into their free thiol and disulfide bond, circular dichroism spectra and fluorescence spectra revealed that the unfolding of the parental enzyme was irreversible on all the tested conditions, while that of the Cys235 mutants was reversible, and their ability to refold was highly dependent on the denaturing temperature. Mutants denatured at 75°C were able to efficiently reverse the unfolding to regain native structure during the cooling process. This study provided valid evidence that free cysteine substitutions can reduce irreversible thermal inactivation of proteins. © The Author 2015. Published by ABBS Editorial Office in association with Oxford University Press on behalf of the Institute of Biochemistry and Cell Biology, Shanghai Institutes for Biological Sciences, Chinese Academy of Sciences.

  16. Aggregation Effects on the Emission Spectra and Dynamics of Model Oligomers of MEH-PPV

    NARCIS (Netherlands)

    Sherwood, Gizelle A.; Cheng, Ryan; Smith, Timothy M.; Werner, James H.; Shreve, Andrew P.; Peteanu, Linda A.; Wildeman, Jurjen

    2009-01-01

    The effects of aggregate formation on the photophysical properties of oligomers of MEH-PPV were studied in bulk solution to better understand the effects of aggregation on the emission properties of the polymer. Nanoaggregates of oligomers from 3 to 17 repeat units in length were formed using a

  17. Thermal Performance of Hollow Clay Brick with Low Emissivity Treatment in Surface Enclosures

    Directory of Open Access Journals (Sweden)

    Roberto Fioretti

    2014-10-01

    Full Text Available External walls made with hollow clay brick or block are widely used for their thermal, acoustic and structural properties. However, the performance of the bricks frequently does not conform with the minimum legal requirements or the values required for high efficiency buildings, and for this reason, they need to be integrated with layers of thermal insulation. In this paper, the thermal behavior of hollow clay block with low emissivity treatment on the internal cavity surfaces has been investigated. The purpose of this application is to obtain a reduction in the thermal conductivity of the block by lowering the radiative heat exchange in the enclosures. The aims of this paper are to indicate a methodology for evaluating the thermal performance of the brick and to provide information about the benefits that should be obtained. Theoretical evaluations are carried out on several bricks (12 geometries simulated with two different thermal conductivities of the clay, using a finite elements model. The heat exchange procedure is implemented in accordance with the standard, so as to obtain standardized values of the thermal characteristics of the block. Several values of emissivity are hypothesized, related to different kinds of coating. Finally, the values of the thermal transmittance of walls built with the evaluated blocks have been calculated and compared. The results show how coating the internal surface of the cavity provides a reduction in the thermal conductivity of the block, of between 26% and 45%, for a surface emissivity of 0.1.

  18. Impact of Thermal Mass Oriented Measures Over CO2 Emissions Of a Thermally Insulated Lowrise Apartment Building in Izmir, Turkey

    Directory of Open Access Journals (Sweden)

    Mümine Gerçek

    2015-02-01

    Full Text Available Climate change has drawn the attention of many researchers and practitioners to focus on the methods to address the challenges in achieving low-carbon buildings and cities and in future developments. Nevertheless, few studies have explored the impacts of thermal mass applications for the lowest carbon emissions of building operational energy consumption. A comparative study of CO2 emissions due to different wall and floor compositions is presented in accordance with their lifespans for a hot-humid climate site. Aim of this study is to examine the relation between the energy oriented operations and carbon emissions of the building. Firstly, an existing low-rise building in İzmir is selected, then modelled in the dynamic simulation model software DesignBuilder v4 by synchronizing drawings with basic operational principles of the program. Furthermore, various influence factors of building envelope thermal characteristics are selected as follows: type, location, thickness and thermal specifications of materials used by keeping thermal conductivity value constant. At the end, the research presents remarkable influence of thermal mass oriented measures on reducing energy demands and carbon footprints.

  19. Employing broadband spectra and cluster analysis to assess thermal defoliation of cotton

    Science.gov (United States)

    Growers and field scouts need assistance in surveying cotton (Gossypium hirsutum L.) fields subjected to thermal defoliation to reap the benefits provided by this nonchemical defoliation method. A study was conducted to evaluate broadband spectral data and unsupervised classification as tools for s...

  20. Effects of Absorber Emissivity on Thermal Performance of a Solar Cavity Receiver

    Directory of Open Access Journals (Sweden)

    Jiabin Fang

    2014-01-01

    Full Text Available Solar cavity receiver is a key component to realize the light-heat conversion in tower-type solar power system. It usually has an aperture for concentrated sunlight coming in, and the heat loss is unavoidable because of this aperture. Generally, in order to improve the thermal efficiency, a layer of coating having high absorptivity for sunlight would be covered on the surface of the absorber tubes inside the cavity receiver. As a result, it is necessary to investigate the effects of the emissivity of absorber tubes on the thermal performance of the receiver. In the present work, the thermal performances of the receiver with different absorber emissivity were numerically simulated. The results showed that the thermal efficiency increases and the total heat loss decreases with increasing emissivity of absorber tubes. However, the thermal efficiency increases by only 1.6% when the emissivity of tubes varies from 0.2 to 0.8. Therefore, the change of absorber emissivity has slight effect on the thermal performance of the receiver. The reason for variation tendency of performance curves was also carefully analyzed. It was found that the temperature reduction of the cavity walls causes the decrease of the radiative heat loss and the convective heat loss.

  1. Programmable thermal emissivity structures based on bioinspired self-shape materials

    Science.gov (United States)

    Athanasopoulos, N.; Siakavellas, N. J.

    2015-12-01

    Programmable thermal emissivity structures based on the bioinspired self-shape anisotropic materials were developed at macro-scale, and further studied theoretically at smaller scale. We study a novel concept, incorporating materials that are capable of transforming their shape via microstructural rearrangements under temperature stimuli, while avoiding the use of exotic shape memory materials or complex micro-mechanisms. Thus, programmed thermal emissivity behaviour of a surface is achievable. The self-shape structure reacts according to the temperature of the surrounding environment or the radiative heat flux. A surface which incorporates self-shape structures can be designed to quickly absorb radiative heat energy at low temperature levels, but is simultaneously capable of passively controlling its maximum temperature in order to prevent overheating. It resembles a “game” of colours, where two or more materials coexist with different values of thermal emissivity/ absorptivity/ reflectivity. The transformation of the structure conceals or reveals one of the materials, creating a surface with programmable - and therefore, variable- effective thermal emissivity. Variable thermal emissivity surfaces may be developed with a total hemispherical emissivity ratio (ɛEff_H/ɛEff_L) equal to 28.

  2. Study of medical isotope production facility stack emissions and noble gas isotopic signature using automatic gamma-spectra analysis platform

    Science.gov (United States)

    Zhang, Weihua; Hoffmann, Emmy; Ungar, Kurt; Dolinar, George; Miley, Harry; Mekarski, Pawel; Schrom, Brian; Hoffman, Ian; Lawrie, Ryan; Loosz, Tom

    2013-04-01

    The nuclear industry emissions of the four CTBT (Comprehensive Nuclear-Test-Ban Treaty) relevant radioxenon isotopes are unavoidably detected by the IMS along with possible treaty violations. Another civil source of radioxenon emissions which contributes to the global background is radiopharmaceutical production companies. To better understand the source terms of these background emissions, a joint project between HC, ANSTO, PNNL and CRL was formed to install real-time detection systems to support 135Xe, 133Xe, 131mXe and 133mXe measurements at the ANSTO and CRL 99Mo production facility stacks as well as the CANDU (CANada Deuterium Uranium) primary coolant monitoring system at CRL. At each site, high resolution gamma spectra were collected every 15 minutes using a HPGe detector to continuously monitor a bypass feed from the stack or CANDU primary coolant system as it passed through a sampling cell. HC also conducted atmospheric monitoring for radioxenon at approximately 200 km distant from CRL. A program was written to transfer each spectrum into a text file format suitable for the automatic gamma-spectra analysis platform and then email the file to a server. Once the email was received by the server, it was automatically analysed with the gamma-spectrum software UniSampo/Shaman to perform radionuclide identification and activity calculation for a large number of gamma-spectra in a short period of time (less than 10 seconds per spectrum). The results of nuclide activity together with other spectrum parameters were saved into the Linssi database. This database contains a large amount of radionuclide information which is a valuable resource for the analysis of radionuclide distribution within the noble gas fission product emissions. The results could be useful to identify the specific mechanisms of the activity release. The isotopic signatures of the various radioxenon species can be determined as a function of release time. Comparison of 133mXe and 133Xe activity

  3. Interactive Radiative Transfer Modeling Tools to Map Volcanic Emissions with Thermal Infrared Remote Sensing

    Science.gov (United States)

    Realmuto, V. J.

    2012-12-01

    The estimation of plume composition from thermal infrared (TIR) radiance measurements is based in radiative transfer (RT) modeling. To model the observed spectra we must consider the temperature, emissivity, and elevation of the surface beneath the plume, plume altitude and thickness, and the local atmospheric temperature and humidity. Our knowledge of these parameters is never perfect, and interactive RT modeling allows us to evaluate the impact of these uncertainties on our estimates of plume composition. Interactive RT modeling has three main components: retrieval procedures for plume components, an engine for RT calculations, and a graphic user interface (GUI) to input radiance data, modify model parameters, launch retrievals, and visualize the resulting estimates of plume composition. The Jet Propulsion Laboratory (JPL), in collaboration with Spectral Sciences, Inc. (SSI), is developing a new class of tools for interactive RT modeling. We will implement RT modeling on graphics processors (GPU) to achieve a 100-fold increase in processing speed, relative to conventional CPU-based processing, and thus enable fully-interactive estimation and visualization of plume composition. The heritage for our new tools is based on the Plume Tracker toolkit, developed at JPL, and MODTRAN RT model, developed by SSI. Plume Tracker integrates retrieval procedures, interactive visualization tools, and an interface to a modified version of MODTRAN under a single GUI. Our new tools will incorporate refinements from a recent adaptation of MODTRAN to optimize modeling the radiative properties of chemical clouds. This presentation will include a review of the foundations of plume mapping in the TIR and examples of the application of Plume Tracker to ASTER, MODIS, and AIRS data. We will present an overview of our tool development effort and discuss the application of these tools to data from new and future instruments, such as the airborne Hyperspectral Thermal Emission Spectrometer

  4. Thermal-field emission flicker (1/f) noise and diffusive equilibrium density fluctuations

    Science.gov (United States)

    Gesley, Mark; Swanson, Lyn

    1988-06-01

    A model of diffusive equilibrium density fluctuations in a grand-canonical ensemble is constructed for systems of finite size. The particle number autocorrelation is developed from a Langevin-type bounded-diffusion equation. Both probe and sample geometries affect its spectrum, which factors into two terms representing the particle creation rate and diffusion according to a multidimensional Carson's theorem. The spatial decay of the kernel in the spectrum's integral equation is measured by a frequency-dependent correlation length that depends on particle lifetime, diffusivity, and probe resolution. The kernel and its transform, the mutual coherence function, collapse to the Ornstein-Zernike spatial distribution but with the new result that the classical correlation length is given by a ratio of diffusive and thermodynamic variables. For the limiting case of an unbounded system with infinite particle lifetime, Voss and Clarke's spatially correlated spectrum is rederived. However, for this ensemble a finite particle lifetime is a necessary equilibrium condition. Little's theorem is generalized when particle interactions are included. Noise-power integrals converge in all cases. Frequency exponents characterize the spectra and, when a small region is probed in a quasi-two-dimensional system, broadband 1/f noise occurs. A Lorentzian spectrum results in the limit of no diffusion. A lower length limit introduced to avoid the breakdown of the diffusion approximation at small time and space intervals can in some cases be identified with probe resolution and is measurable when a certain crossover in frequency exponents is identified. The analysis is then applied to fluctuations in the electron current, thermal field emitted from a single-crystal tungsten cathode. These are coupled to self-diffusion of surface defect adatoms on the cathode by the Fowler-Nordheim equation. Other frequency crossovers yield surface diffusivities and their activation energies, which for

  5. Effects of quantum interference in spectra of cascade spontaneous emission from multilevel systems

    Directory of Open Access Journals (Sweden)

    Makarov A.A.

    2017-01-01

    Full Text Available A general expression for the spectrum of cascade spontaneous emission from an arbitrary multilevel system is presented. Effects of the quantum interference of photons emitted in different transitions are analyzed. These effects are especially essential when the transition frequencies are close. Several examples are considered: (i Three-level system; (ii Harmonic oscillator; (iii System with equidistant levels and equal rates of the spontaneous decay for all the transitions; (iv Dicke superradiance model.

  6. Characterization of potentially habitable planets: Retrieval of atmospheric and planetary properties from emission spectra

    OpenAIRE

    von Paris, P.; P. Hedelt; Selsis, F.; F. Schreier; Trautmann, T.

    2013-01-01

    An increasing number of potentially habitable terrestrial planets and planet candidates are found by ongoing planet search programs. The search for atmospheric signatures to establish planetary habitability and the presence of life might be possible in the future. We want to quantify the accuracy of retrieved atmospheric parameters which might be obtained from infrared emission spectroscopy. We use synthetic observations of hypothetical habitable planets, constructed with a parametrized atmos...

  7. Nonmagnetic Quantum Emitters in Boron Nitride with Ultranarrow and Sideband-Free Emission Spectra.

    Science.gov (United States)

    Li, Xiangzhi; Shepard, Gabriella D; Cupo, Andrew; Camporeale, Nicolas; Shayan, Kamran; Luo, Yue; Meunier, Vincent; Strauf, Stefan

    2017-07-25

    Hexagonal boron nitride (hBN) is an emerging material in nanophotonics and an attractive host for color centers for quantum photonic devices. Here, we show that optical emission from individual quantum emitters in hBN is spatially correlated with structural defects and can display ultranarrow zero-phonon line width down to 45 μeV if spectral diffusion is effectively eliminated by proper surface passivation. We demonstrate that undesired emission into phonon sidebands is largely absent for this type of emitter. In addition, magneto-optical characterization reveals cycling optical transitions with an upper bound for the g-factor of 0.2 ± 0.2. Spin-polarized density functional theory calculations predict possible commensurate transitions between like-spin electron states, which are in excellent agreement with the experimental nonmagnetic defect center emission. Our results constitute a step toward the realization of narrowband quantum light sources and the development of spin-photon interfaces within 2D materials for future chip-scale quantum networks.

  8. Testing slim-disk models on the thermal spectra of LMC X-3

    Science.gov (United States)

    Straub, O.; Bursa, M.; Sądowski, A.; Steiner, J. F.; Abramowicz, M. A.; Kluźniak, W.; McClintock, J. E.; Narayan, R.; Remillard, R. A.

    2011-09-01

    Slim-disk models describe advective accretion flows at high luminosities, while reducing to the standard thin disk form in the low luminosity limit. We have developed a new spectral model, slimbb, within the framework of XSPEC, which describes fully relativistic slim-disk accretion and includes photon ray-tracing that starts from the disk photosphere, rather than the equatorial plane. We demonstrate the features of this model by applying it to RXTE spectra of the persistent black-hole X-ray binary LMC X-3. LMC X-3 has the virtues of exhibiting large intensity variations while maintaining itself in soft spectral states which are well described using accretion-disk models, making it an ideal candidate to test the aptness of slimbb. Our results demonstrate consistency between the low-luminosity (thin-disk) and high luminosity (slim-disk) regimes. The results also illustrate that advection alone does not solve the problem of the origin of the surprisingly soft high-luminosity spectra in LMC X-3. We show that X-ray continuum-fitting in the high accretion rate regime can powerfully test black-hole accretion disk models.

  9. Thermal Balance in Dense Molecular Clouds: Radiative Cooling Rates and Emission-Line Luminosities

    Science.gov (United States)

    Neufeld, David A.; Lepp, Stephen; Melnick, Gary J.

    1995-01-01

    We consider the radiative cooling of fully shielded molecular astrophysical gas over a wide range of temperatures ( 10 K line strengths that contribute to the total radiative cooling rate, and we have obtained example spectra for the submillimeter emission expected from molecular cloud cores. Many of the important cooling lines will be detectable using the Infrared Space Observatory and the Submillimeter Wave Astronomy Satellite.

  10. Thermal effects on arsenic emissions during coal combustion process.

    Science.gov (United States)

    Zhang, Weiqiang; Sun, Qiang; Yang, Xiuyuan

    2018-01-15

    In this study, the rate of emission of arsenic during the burning process of different kinds of coal is examined in order to study the volatile characteristics of arsenic during coal combustion which have negative effects on the ecological environment and human health. The results show that the emission rate of arsenic gradually increases with increased burning temperature, with a threshold of approximately 700°C to 800°C in the process of temperature increase. Then, the relationships among the arsenic emission rate and combustion environment, original arsenic content, combustion time, burning temperature, air flow and amount of arsenic fixing agent are discussed, and it is found that except for the original arsenic content, the rest of the factors have a nonlinear relationship with the emission rate of arsenic. That is, up to a certain level, they all contribute to the release of arsenic, and then their impact is minimal. The original arsenic content in coal is proportional to the arsenic emission rate. Therefore, taking into consideration the nonlinear relationships between factors that affect the arsenic emission rate can reduce contamination from arsenic. Copyright © 2017 Elsevier B.V. All rights reserved.

  11. [Raman spectra study of thermal transformation of nephrite cat's eye from Sichuan province].

    Science.gov (United States)

    Lu, Bao-qi; Xia, Yi-ben; Qi, Li-jian; You, Jing-lin

    2005-11-01

    Raman spectrum and X-ray powder diffraction (XRD) were used to study the process andproduct of thermal transformation of nephrite cat's eye from Sichuan province. The results indicate that upon being heated till 900 degrees C, tremolite in the nephrite cat's eye is dehydrated completely and the appearance of a new characteristic band near 671 cm(-1) indicates the form of a new product. At 1 000 degrees C, the intensity of band near 1014 cm(-1) rises obviously, and the weak bands near 573 cm(-1) and 934 cm(-1) present. Up to 1100 degrees C, the band near 1033 cm(-1) appears. All these evidences show that the final thermal transformation product is identified as Ca-Mg pyroxene which is similar to diopside both in structure and in composition. This conclusion is confirmed by XRD.

  12. Volcanic SO2 and SiF4 visualization using 2-D thermal emission spectroscopy – Part 1: Slant-columns and their ratios

    Directory of Open Access Journals (Sweden)

    M. Grutter

    2012-02-01

    Full Text Available The composition and emission rates of volcanic gas plumes provide insight of the geologic internal activity, atmospheric chemistry, aerosol formation and radiative processes around it. Observations are necessary for public security and the aviation industry. Ground-based thermal emission infrared spectroscopy, which uses the radiation of the volcanic gas itself, allows for continuously monitoring during day and night from a safe distance. We present measurements on Popocatépetl volcano based on thermal emission spectroscopy during different campaigns between 2006–2009 using a Scanning Infrared Gas Imaging System (SIGIS. The experimental set-up, measurement geometries and analytical algorithms are described. The equipment was operated from a safe distance of 12 km from the volcano at two different spectral resolutions: 0.5 and 4 cm−1. The 2-dimensional scanning capability of the instrument allows for an on-line visualization of the volcanic SO2 plume and its animation. SiF4 was also identified in the infrared spectra recorded at both resolutions. The SiF4/SO2 molecular ratio can be calculated from each image and used as a highly useful parameter to follow changes in volcanic activity. A small Vulcanian eruption was monitored during the night of 16 to 17 November 2008 and strong ash emission together with a pronounced SO2 cloud was registered around 01:00 a.m. LST (Local Standard Time. Enhanced SiF4/SO2 ratios were observed before and after the eruption. A validation of the results from thermal emission measurements with those from absorption spectra of the moon taken at the same time, as well as an error analysis, are presented. The inferred propagation speed from sequential images is used in a subsequent paper (Part 2 to calculate the emission rates at different distances from the crater.

  13. Volcanic SO2 and SiF4 visualization using 2-D thermal emission spectroscopy - Part 1: Slant-columns and their ratios

    Science.gov (United States)

    Stremme, W.; Krueger, A.; Harig, R.; Grutter, M.

    2012-02-01

    The composition and emission rates of volcanic gas plumes provide insight of the geologic internal activity, atmospheric chemistry, aerosol formation and radiative processes around it. Observations are necessary for public security and the aviation industry. Ground-based thermal emission infrared spectroscopy, which uses the radiation of the volcanic gas itself, allows for continuously monitoring during day and night from a safe distance. We present measurements on Popocatépetl volcano based on thermal emission spectroscopy during different campaigns between 2006-2009 using a Scanning Infrared Gas Imaging System (SIGIS). The experimental set-up, measurement geometries and analytical algorithms are described. The equipment was operated from a safe distance of 12 km from the volcano at two different spectral resolutions: 0.5 and 4 cm-1. The 2-dimensional scanning capability of the instrument allows for an on-line visualization of the volcanic SO2 plume and its animation. SiF4 was also identified in the infrared spectra recorded at both resolutions. The SiF4/SO2 molecular ratio can be calculated from each image and used as a highly useful parameter to follow changes in volcanic activity. A small Vulcanian eruption was monitored during the night of 16 to 17 November 2008 and strong ash emission together with a pronounced SO2 cloud was registered around 01:00 a.m. LST (Local Standard Time). Enhanced SiF4/SO2 ratios were observed before and after the eruption. A validation of the results from thermal emission measurements with those from absorption spectra of the moon taken at the same time, as well as an error analysis, are presented. The inferred propagation speed from sequential images is used in a subsequent paper (Part 2) to calculate the emission rates at different distances from the crater.

  14. Gamma-Ray Emission Spectra as a Constraint on Calculations of 234 , 236 , 238U Neutron-Capture Cross Sections

    Science.gov (United States)

    Ullmann, J. L.; Krticka, M.; Kawano, T.; Bredeweg, T. A.; Baramsai, B.; Couture, A.; Haight, R. C.; Jandel, M.; Mosby, S.; O'Donnell, J. M.; Rundberg, R. S.; Vieira, D. J.; Wilhelmy, J. B.; Becker, J. A.; Wu, C. Y.; Chyzh, A.

    2015-10-01

    Calculations of the neutron-capture cross section at low neutron energies (10 eV through 100's of keV) are very sensitive to the nuclear level density and radiative strength function. These quantities are often poorly known, especially for radioactive targets, and actual measurements of the capture cross section are usually required. An additional constraint on the calculation of the capture cross section is provided by measurements of the cascade gamma spectrum following neutron capture. Recent measurements of 234 , 236 , 238U(n, γ) emission spectra made using the DANCE 4 π BaF2 array at the Los Alamos Neutron Science Center will be presented. Calculations of gamma-ray spectra made using the DICEBOX code and of the capture cross section made using the CoH3 code will also be presented. These techniques may be also useful for calculations of more unstable nuclides. This work was performed with the support of the U.S. Department of Energy, National Nuclear Security Administration by Los Alamos National Security, LLC (Contract DE-AC52-06NA25396) and Lawrence Livermore National Security, LLC (Contract DE-AC52-07NA2734).

  15. Thermal emission in fatigue described by power laws

    Directory of Open Access Journals (Sweden)

    Gallinatti A.E.

    2010-06-01

    Full Text Available In the present work, a theoretical model proposed by the literature and focused on the relationship between microplasticizations thermal behaviour and fatigue scatter is analysed and applied to fatigue test results of standard and notched steel specimens. The same experimental data are subjected to the TCM (Two Curves Method thermographic elaboration technique, in order to quickly evaluate fatigue limit values. TCM method has been modified, aiming at interpolating thermal data referred to the region of loads upper than fatigue limit with a non linear regression law having the same mathematical structure of the theoretical model equations (power laws.

  16. Modelling The Thermal Emission From Airless Planetary Surfaces And Sub-surfaces

    Science.gov (United States)

    Leyrat, Cedric; Le Gall, A.; Stolzenbach, A.; Lellouch, E.

    2012-10-01

    Thermal emission from airless planetary bodies hold important clues on the thermo-physical and compositional characteristics of their surfaces. At short wavelengths, in the mid-infrared domain, thermal emission arises from the first layers of the regolith (a few microns). In contrast, radiometric measurements obtained at larger wavelengths can probe deeper below the surface as the material becomes more “transparent”. At such wavelengths thermal emission probes several tens of cm up to a few meters below the surface, depending on the absorbing properties of the body’s regolith. The radiometric data obtained by spacecraft can be used to constrain the electrical and thermal properties of surface bodies, thus providing clues on their physical state (roughness, porosity) and composition (dielectric constant). This will help identifying the geological endogenic or exogenic processes that have affected these bodies. Both the Cassini (NASA/ESA/ASI) and Rosetta (ESA) spacecrafts have onboard a radiometer operating at relatively large wavelengths, respectively in the microwave and sub-millimetric domains. At such wavelengths, these instruments sense the thermal emission not only from the surface but also from a section of the sub-surface of the targeted bodies. As a consequence, the interpretation of radiometric data collected over the airless icy satellites of Saturn by Cassini and over the comet 67P/Churyumov-Gerasimenko by the Rosetta orbiter requires a good knowledge of the temperature profile below the surface, down to several meters. We have developed a new thermal model of surfaces that takes into account for conductive heat transport, local variations of the insolation on both diurnal and seasonal timescales, multiple sources of heating, and geometry computations based on SPICE/NAIF kernels. This new thermal model could be used to interpret Cassini radar/radiometer data recorded over some of Saturn’s icy satellites and Miro/Rosetta future measurements of the

  17. Transformation of chlorinated paraffins to olefins during metal work and thermal exposure - Deconvolution of mass spectra and kinetics.

    Science.gov (United States)

    Schinkel, Lena; Lehner, Sandro; Knobloch, Marco; Lienemann, Peter; Bogdal, Christian; McNeill, Kristopher; Heeb, Norbert V

    2018-03-01

    Chlorinated paraffins (CPs) are high production volume chemicals widely used as additives in metal working fluids. Thereby, CPs are exposed to hot metal surfaces which may induce degradation processes. We hypothesized that the elimination of hydrochloric acid would transform CPs into chlorinated olefins (COs). Mass spectrometry is widely used to detect CPs, mostly in the selected ion monitoring mode (SIM) evaluating 2-3 ions at mass resolutions R drilling indeed induced HCl-losses. CO proportions in exposed mixtures of chlorotridecanes increased. Thermal exposure of chlorotridecanes at 160, 180, 200 and 220 °C also induced dehydrohalogenation reactions and CO proportions also increased. Deconvolution of respective mass spectra is needed to study the CP transformation kinetics without bias from CO interferences. Apparent first-order rate constants (k app ) increased up to 0.17, 0.29 and 0.46 h -1 for penta-, hexa- and heptachloro-tridecanes exposed at 220 °C. Respective half-life times (τ 1/2 ) decreased from 4.0 to 2.4 and 1.5 h. Thus, higher chlorinated paraffins degrade faster than lower chlorinated ones. In conclusion, exposure of CPs during metal drilling and thermal treatment induced HCl losses and CO formation. It is expected that CPs and COs are co-released from such processes. Full-scan mass spectra and subsequent deconvolution of interfered signals is a promising approach to tackle the CP/CO problem, in case of insufficient mass resolution. Copyright © 2017 Elsevier Ltd. All rights reserved.

  18. Ion temperatures in HIP-1 and SUMMA from charge-exchange neutral optical emission spectra

    Science.gov (United States)

    Patch, R. W.; Lauver, M. R.

    1976-01-01

    Ion temperatures were obtained from observations of the H sub alpha, D sub alpha, and He 587.6 nm lines emitted from hydrogen, deuterium, and helium plasmas in the SUMMA and HIP-1 mirror devices at Lewis Research Center. Steady state discharges were formed by applying a radially inward dc electric field between cylindrical or annular anodes and hollow cathodes located at the peaks of the mirrors. The ion temperatures were found from the Doppler broadening of the charge-exchange components of spectral lines. A statistical method was developed for obtaining scaling relations of ion temperature as a function of current, voltage, and magnetic flux density. Derivations are given that take into account triangular monochromator slit functions, loss cones, and superimposed charge-exchange processes. In addition, the Doppler broadening was found to be sensitive to the influence of drift on charge-exchange cross section. The effects of finite ion-cyclotron radius, cascading, and delayed emission are reviewed.

  19. Temperature-induced tuning of emission spectra of liquid-crystal optical microcavities

    Science.gov (United States)

    Zemánek, Pavel; Pilát, Zdeněk.; Ježek, Jan; Bernatová, Silvie; Aas, Mehdi; Kiraz, Alper; Jonáš, Alexandr

    2016-12-01

    Emulsion droplets of liquid crystals (LC) suspended in water and labeled with a suitable fluorescent dye can serve as active optofluidic microcavities, since the contrast of refractive index between the LC droplets and the surrounding aqueous medium allows excitation of whispering gallery modes (WGMs) in the droplets. In addition, such emulsion droplets can be also stably trapped in three-dimensions using optical tweezers which stabilizes the droplets while investigating their spectral characteristics. We explore various combinations of fluorescently dyed LC droplets and host liquid - surfactant systems and show that the WGM emission spectrum of an optically trapped LC droplet-based cavity can be largely and (almost) reversibly tuned by controlled changes of the ambient temperature that induce phase transitions in the LC droplets. Our results indicate feasibility of this approach for creating miniature tunable sources of coherent light.

  20. Accuracy Advances in Measuring Earth Emission Spectra for Weather and Climate

    Science.gov (United States)

    Revercomb, H. E.; Best, F. A.; Tobin, D. C.; Knuteson, R. O.; Taylor, J. K.; Gero, P.; Adler, D. P.; Pettersen, C.; Mulligan, M.

    2011-12-01

    Launch of the first component of the Joint Polar Satellite System (JPSS) in late October is expected to initiate a new series of US afternoon satellites to complement the EUMETSAT MetOp EPS morning observations. A key component is the Cross-track Infrared Sounder (CrIS) designed for advanced temperature and water vapor profiling for weather and climate applications. We have worked on getting this operational capability in space ever since conducting a Phase A instrument design in 1990, and will report on what is expected to be its highly accurate radiometric and spectral performance post launch. The expectation from thermal/vacuum testing is that the accuracy will exceed 0.2 K (k=3) brightness temperature at scene temperature for all three bands in the region from 3.5 to 15 microns. CrIS is expected to offer further confirmation of techniques that have proven to offer significant accuracy improvements for the new family of advanced sounding instruments including AIRS on NASA Aqua platform and IASI on MetOp A and that are needed in the new IR Decadal Survey measurements. CrIS and these other advanced sounders help set the stage for a new era in establishing spectrally resolved IR climate benchmark measurements from space. Here we report on being able to achieve even higher accuracy with instruments designed specifically for climate missions similar to the Decadal Survey Climate Absolute Radiance and Refractivity Observatory (CLARREO). Results will be presented from our NASA Instrument Incubator Program (IIP) effort for which a new concept for on-orbit verification and test has been developed. This system is capable of performing fundamental radiometric calibration, spectral characterization and calibration, and other key performance tests that are normally only performed prior to launch in thermal/vacuum testing. By verifying accuracy directly on-orbit, this capability should provide the ultra-high confidence in data sets needed for societal decision making.

  1. A Temperature and Emissivity Separation Technique for Thermal Hyperspectral Imagers

    Science.gov (United States)

    2005-10-01

    ISSTES algorithm. This algorithm has subsequently been studied thoroughly by Ingram and Muse [2]. In our technique, we use the downwelling irradiance...technique’s difference from ISSTES lies in the method used for selecting the right temperature and its corresponding emissivity. That difference leads to

  2. Broadband spectra of seismic survey air-gun emissions, with reference to dolphin auditory thresholds.

    Science.gov (United States)

    Goold, J C; Fish, P J

    1998-04-01

    Acoustic emissions from a 2120 cubic in air-gun array were recorded through a towed hydrophone assembly during an oil industry 2-D seismic survey off the West Wales Coast of the British Isles. Recorded seismic pulses were sampled, calibrated, and analyzed post-survey to investigate power levels of the pulses in the band 200 Hz-22 kHz at 750-m, 1-km, 2.2-km, and 8-km range from source. At 750-m range from source, seismic pulse power at the 200-Hz end of the spectrum was 140 dB re: 1 microPa2/Hz, and at the 20-kHz end of the spectrum seismic pulse power was 90 dB re: 1 microPa2/Hz. Although the background noise levels of the seismic recordings were far in excess of ambient, due to the proximity of engine, propeller, and flow sources of the ship towing the hydrophone, seismic power dominated the entire recorded bandwidth of 200 Hz-22 kHz at ranges of up to 2 km from the air-gun source. Even at 8-km range seismic power was still clearly in excess of the high background noise levels up to 8 kHz. Acoustic observations of common dolphins during preceding seismic surveys suggest that these animals avoided the immediate vicinity of the air-gun array while firing was in progress, i.e., localized disturbance occurred during seismic surveying. Although a general pattern of localized disturbance is suggested, one specific observation revealed that common dolphins were able to tolerate the seismic pulses at 1-km range from the air-gun array. Given the high broadband seismic pulse power levels across the entire recorded bandwidth, and known auditory thresholds for several dolphin species, we consider such seismic emissions to be clearly audible to dolphins across a bandwidth of tens on kilohertz, and at least out to 8-km range.

  3. Thermal spectra of the TRIGA Mark III reactor; El espectro termico del reactor TRIGA Mark III

    Energy Technology Data Exchange (ETDEWEB)

    Macias B, L.R.; Palacios G, J. [Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, 11801 Mexico D.F. (Mexico)

    1998-07-01

    The diffraction phenomenon is gave in observance of the well known Bragg law in crystalline materials and this can be performance by mean of X-rays, electrons and neutrons among others, which allows to do inside the field of each one of these techniques the obtaining of measurements focussed at each one of them. For the present work, it will be mentioned only the referring to X-ray and neutron techniques. The X-ray diffraction due to its properties just it does measurements which are known in general as superficial measurements of the sample material but for the properties of the neutrons, this diffraction it explores in volumetric form the sample material. Since the neutron diffraction process depends lots of its intensity, then it is important to know the neutron source spectra that in this case is supplied by the TRIGA Mark III reactor. Within of diffraction techniques a great number of them can be found, however some of the traditional will be mentioned such as the identification of crystalline samples, phases identification and the textures measurement. At present this last technique is founded on the dot of a minimum error and the technique of phases identification performs but not compete with that which is obtained by mean of X-rays due to this last one has a major resolution. (Author)

  4. Band structure and thermal emission of two dimentional silicon photonic crystal

    Directory of Open Access Journals (Sweden)

    meysam daneshvar

    2017-11-01

    Full Text Available In this research, we have studied the photonic band structure, optical properties and thermal emission spectrum of 2D Silicon photonic crystal with hexagonal structure. The band structure, band gap map and the gap size versus radius have been calculated by plane wave expansion method. The maximum band gap size of TE (TM polarization and the complete gap size are 51% (20% and 17% at air hole radius r=0.43a (0.50a and r=0.48a, respectively. The optical properies have been calculated by FDTD methd in the range of 1 to 10 . The thermal emission spectrum has been obtained from absorption by Kirchhoff’s law. The obtaine results show that by engineering the band structure, the thermal emission spectrum of 2D Silicon photonic crystal can be controlled in a manner that can be used in thermophotovoltaic systems.

  5. Directional features of the downshifted peak observed in HF-induced stimulated electromagnetic emission spectra obtained using an interferometer

    Directory of Open Access Journals (Sweden)

    E. D. Tereshchenko

    2006-08-01

    Full Text Available A high frequency (HF ionospheric modification experiment was carried out between 25 September and 8 October 2004, using the EISCAT HF transmitter located near Tromsø, Norway. During this experiment the spectra of the stimulated HF sideband waves (stimulated electromagnetic emission or SEE induced by the HF pump were observed using an interferometer consisting of three spaced receiving antennas with baselines both along and perpendicular to the meridian, and a multi-channel coherent receiver, installed in the vicinity of the HF facility. The transmitter operated at 4040kHz and its antenna beam was scanned to angles of 0°, 7°, 14°, and 21° south from vertical, pausing 4min at each position. This paper focuses on features of the downshifted peak (DP emission, which has not been as thoroughly studied as many of the other SEE spectral features observable within the EISCAT pump frequency range. It was found that the signal-weighted direction of the DP source region remained within 5° of magnetic zenith as the HF beam was tilted between 0 and 21° south of vertical.

  6. Disentangling random thermal motion of particles and collective expansion of source from transverse momentum spectra in high energy collisions

    Science.gov (United States)

    Wei, Hua-Rong; Liu, Fu-Hu; Lacey, Roy A.

    2016-12-01

    In the framework of a multisource thermal model, we describe experimental results of the transverse momentum spectra of final-state light flavor particles produced in gold-gold (Au-Au), copper-copper (Cu-Cu), lead-lead (Pb-Pb), proton-lead (p-Pb), and proton-proton (p -p) collisions at various energies, measured by the PHENIX, STAR, ALICE, and CMS Collaborations, by using the Tsallis-standard (Tsallis form of Fermi-Dirac or Bose-Einstein), Tsallis, and two- or three-component standard distributions which can be in fact regarded as different types of ‘thermometers’ or ‘thermometric scales’ and ‘speedometers’. A central parameter in the three distributions is the effective temperature which contains information on the kinetic freeze-out temperature of the emitting source and reflects the effects of random thermal motion of particles as well as collective expansion of the source. To disentangle both effects, we extract the kinetic freeze-out temperature from the intercept of the effective temperature (T) curve as a function of particle’s rest mass (m 0) when plotting T versus m 0, and the mean transverse flow velocity from the slope of the mean transverse momentum ( ) curve as a function of mean moving mass (\\overline{m}) when plotting versus \\overline{m}.

  7. a. Structural Perturbations of the Electronic Excited States of Zinc Complexes. B. Construction of a Thermal Modulation Emission Apparatus.

    Science.gov (United States)

    Jordan, Kevin James

    Zinc(II) complexes containing both 2,9-dimethyl -1,10,-phenanthroline and substituted benzenethiol ligands were found to crystallize in different phases. Subtle changes in emission lifetimes and bandshapes recorded over periods of months from the same batch were manifestations of slow interphase conversions. Heating the crystals to near their melting points generated the unique high temperature phases. Two phases of the benzenethiol complex were characterized by x-ray crystallography. The 2500 cm^ {-1} energy difference between the peak of the 77 K emission from the ligand-ligand charge-transfer (LLCT) transition in the two phases was considered to arise from the sensitivities of the donor orbitals to rotation of the benzene rings about the sulfur-carbon bonds. The energy of the ^3pipi^ * emission from the nitrogen heterocycle was found to be insensitive both to complexation with Zn(II) and to the presence of the LLCT transitions. The intensity decrease of the ^3pipi^ * phosphorescence in alcoholic glasses with UV exposure was related to the generation of free radicals. Multiple LLCT lifetimes and emission bands with the longer-lived components at higher energies were found in the rigid glasses. LLCT emissions from an analogous dithiol complex revealed similar characteristics. Also the relative intensities of the LLCT components were independent of excitation wavelength. These results indicated that the multiple emissions were not attributable to multiple geometrical conformations. Thermally -modulated emission (TME) spectra were obtained from compounds dispersed in rigid glasses. For bis(cis-1,2-bis(diphenylphosphino)ethylene)Rh(I) perchlorate the maximum temperature excursion was 3.5 and 4.5 K for the resistive and infra-red absorption heating methods respectively. The TME spectrum of crystalline (Cr(urea)_6) Cl_3 .3H_2O demonstrated the technique's advantages for the vibronic analysis of emissions from near-degenerate excited states. The negative signal of the

  8. Local moments and electronic correlations in Fe-based Heusler alloys: Kα x-ray emission spectra measurements

    Energy Technology Data Exchange (ETDEWEB)

    Svyazhin, Artem, E-mail: svyazhin@imp.uran.ru [M.N. Mikheev Institute of Metal Physics, Russian Academy of Sciences – Ural Division, 620990 Yekaterinburg (Russian Federation); Kurmaev, Ernst; Shreder, Elena; Shamin, Sergey [M.N. Mikheev Institute of Metal Physics, Russian Academy of Sciences – Ural Division, 620990 Yekaterinburg (Russian Federation); Sahle, Christoph J. [ESRF – The European Synchrotron, CS40220, 38043 Grenoble Cedex 9 (France)

    2016-09-15

    Heusler alloys are a property-rich class of materials, intensively investigated today from both theoretical and real-world application points of view. In this paper, we attempt to shed light on the role of electronic correlations in the Fe{sub 2}MeAl group (where Me represents all 3d elements from Ti to Ni) of Heusler alloys. For this purpose, we have investigated the local moments of iron by means of the x-ray emission spectroscopy technique. To obtain numerical values of local moments, the Kα-FWHM method has been employed for the first time. In every compound of the group, the presence of a local moment on the Fe atom was detected. As has been revealed, the values of these moments are temperature-independent, pointing to an insufficiency of a pure itinerant approach to magnetism in these alloys. We also comprehensively compare the usage of Kβ main lines and Kα spectra as tools for the probing of local moments and point out the significant advantages of the latter. - Highlights: • Local spin moments of iron in Fe{sub 2}MeAl (Me = Ti … Ni) Heusler alloys were investigated by means of x-ray emission spectroscopy. • Independence of the local moments from temperature confirms their localized nature. • A local moment value of iron in Fe{sub 2}MeAl raises with the atomic number of element Me. • The applicability of the Kα x-ray emission line for extracting local moment values of 3d elements was established.

  9. Mercury emissions control technologies for mixed waste thermal treatment

    Energy Technology Data Exchange (ETDEWEB)

    Chambers, A.; Knecht, M.; Soelberg, N.; Eaton, D. [Lockheed Martin Idaho Technologies Co., Idaho Falls, ID (United States). Idaho National Engineering and Environmental Lab.; Roberts, D.; Broderick, T. [ADA Technologies, Englewood, CO (United States)

    1997-12-31

    EPA has identified wet scrubbing at low mercury feedrates, as well as carbon adsorption via carbon injection into the offgas or via flow through fixed carbon beds, as control technologies that can be used to meet the proposed Maximum Achievable Control Technology (MACT) rule limit for mercury emissions from hazardous waste incinerators. DOE is currently funding demonstrations of gold amalgamation that may also control mercury to the desired levels. Performance data from a variety of sources was reviewed to determine ranges of achievable mercury control. Preliminary costs were estimated for using these technologies to control mercury emissions from mixed waste incineration. Mercury emissions control for mixed waste incineration may need to be more efficient than for incineration of other hazardous wastes because of higher mercury concentrations in some mixed waste streams. However, mercury control performance data for wet scrubbing and carbon adsorption is highly variable. More information is needed to demonstrate control efficiencies that are achievable under various design and operating conditions for wet scrubbing, carbon adsorption, and gold amalgamation technologies. Given certain assumptions made in this study, capital costs, operating costs, and lifecycle costs for carbon injection, carbon beds, and gold amalgamation generally vary for different assumed mercury feedrates and for different offgas flowrates. Assuming that these technologies can in fact provide the necessary mercury control performance, each of these technologies may be less costly than the others for certain mercury feedrates and the offgas flowrates.

  10. EVIDENCE OF NON-THERMAL X-RAY EMISSION FROM HH 80

    Energy Technology Data Exchange (ETDEWEB)

    López-Santiago, J. [Instituto de Matemática Interdisciplinar, S. D. Astronomía y Geodesia, Facultad de Ciencias Matemáticas, Universidad Complutense de Madrid, E-28040 Madrid (Spain); Peri, C. S.; Benaglia, P. [Instituto Argentino de Radioastronomía (IAR), CCT La Plata (CONICET), C.C.5, 1894 Villa Elisa, Buenos Aires (Argentina); Bonito, R. [Dipartimento di Fisica e Chimica, Università di Palermo, Piazza del Parlamento 1, I-90134 Palermo (Italy); Miceli, M. [INAF-Osservatorio Astronomico di Palermo, Piazza del Parlamento 1, I-90134 Palermo (Italy); Albacete-Colombo, J. F. [Universidad Nacional del COMAHUE, Monseñor Esandi y Ayacucho, 8500 Viedma, Río Negro (Argentina); De Castro, E. [Dpto. de Astrofísica y CC. de la Atmósfera, Universidad Complutense de Madrid, E-28040 Madrid (Spain)

    2013-10-20

    Protostellar jets appear at all stages of star formation when the accretion process is still at work. Jets travel at velocities of hundreds of km s{sup –1}, creating strong shocks when interacting with the interstellar medium. Several cases of jets have been detected in X-rays, typically showing soft emission. For the first time, we report evidence of hard X-ray emission possibly related to non-thermal processes not explained by previous models of the post-shock emission predicted in the jet/ambient interaction scenario. HH 80 is located at the south head of the jet associated with the massive protostar IRAS 18162-2048. It shows soft and hard X-ray emission in regions that are spatially separated, with the soft X-ray emission region situated behind the region of hard X-ray emission. We propose a scenario for HH 80 where soft X-ray emission is associated with thermal processes from the interaction of the jet with denser ambient matter and hard X-ray emission is produced by synchrotron radiation at the front shock.

  11. Thermal and Nonthermal Emissions of a Composite Flare Derived from NoRH and SDO Observations

    Science.gov (United States)

    Lee, Jeongwoo; White, Stephen M.; Jing, Ju; Liu, Chang; Masuda, Satoshi; Chae, Jongchul

    2017-12-01

    Differential emission measure (DEM) derived from the extreme ultraviolet (EUV) lines of the Atmospheric Imaging Assembly (AIA) on board the Solar Dynamic Observatory is used in the analysis of a solar flare observed by the Nobeyama Radioheliograph (NoRH). The target was a composite event consisting of an impulsive flare, SOL2015-06-21T01:42 (GOES class M2.0), and a gradual flare, SOL2015-06-21T02:36 (M2.6), for which separation of thermal plasma heating from nonthermal particle acceleration was of major interest. We have calculated the thermal free-free intensity maps with the AIA-derived DEM and compared them against the observed NoRH maps to attribute the difference to the nonthermal component. In this way, we were able to locate three distinct sources: the major source with thermal and nonthermal components mixed, a nonthermal source devoid of thermal particles, and a thermal source lacking microwave emission. Both the first and the second nonthermal sources produced impulsively rising 17 GHz intensities and moved away from the local magnetic polarization inversion lines in correlation with the flare radiation. In contrast, the thermal sources stay in fixed locations and show temporal variations of the temperature and emission measure uncorrelated with the flare radiation. We interpret these distinct properties as indicating that nonthermal sources are powered by magnetic reconnection and thermal sources passively receive energy from the nonthermal donor. The finding of these distinct properties between thermal and nonthermal sources demonstrates the microwave and EUV emission measure combined diagnostics.

  12. The thermal emission of Centaurs and trans-Neptunian objects at millimeter wavelengths from ALMA observations

    Science.gov (United States)

    Lellouch, E.; Moreno, R.; Müller, T.; Fornasier, S.; Santos-Sanz, P.; Moullet, A.; Gurwell, M.; Stansberry, J.; Leiva, R.; Sicardy, B.; Butler, B.; Boissier, J.

    2017-12-01

    The sensitivity of ALMA makes it possible to detect thermal mm/submm emission from small and/or distant solar system bodies at the sub-mJy level. While the measured fluxes are primarily sensitive to the objects' diameters, deriving precise sizes is somewhat hampered by the uncertain effective emissivity at these wavelengths. Following recent work presenting ALMA data for four trans-Neptunian objects (TNOs) with satellites, we report on ALMA 233 GHz (1.29 mm) flux measurements of four Centaurs (2002 GZ32, Bienor, Chiron, Chariklo) and two other TNOs (Huya and Makemake), sampling a range of sizes, albedos, and compositions. These thermal fluxes are combined with previously published fluxes in the mid/far infrared in order to derive their relative emissivity at radio (mm/submm) wavelengths, using the Near Earth Asteroid Standard Model (NEATM) and thermophysical models. We reassess earlier thermal measurements of these and other objects - including Pluto/Charon and Varuna - exploring, in particular, effects due to non-spherical shape and varying apparent pole orientation whenever information is available, and show that these effects can be key for reconciling previous diameter determinations and correctly estimating the spectral emissivities. We also evaluate the possible contribution to thermal fluxes of established (Chariklo) or claimed (Chiron) ring systems. For Chariklo, the rings do not impact the diameter determinations by more than 5%; for Chiron, invoking a ring system does not help in improving the consistency between the numerous past size measurements. As a general conclusion, all the objects, except Makemake, have radio emissivities significantly lower than unity. Although the emissivity values show diversity, we do not find any significant trend with physical parameters such as diameter, composition, beaming factor, albedo, or color, but we suggest that the emissivity could be correlated with grain size. The mean relative radio emissivity is found to be 0

  13. Thermal infrared emissivity spectrum and its characteristics of crude oil slick covered seawater.

    Science.gov (United States)

    Xiong, Pan; Gu, Xing-Fai; Yu, Taol; Meng, Qing-Yan; Li, Jia-Guoi; Shi, Ji-xiang; Cheng, Yang; Wang, Liang; Liu, Wen-Song; Liu, Qi-Yuei; Zhao, Li-Min

    2014-11-01

    Detecting oil slick covered seawater surface using the thermal infrared remote sensing technology exists the advantages such as: oil spill detection with thermal infrared spectrum can be performed in the nighttime which is superior to visible spectrum, the thermal infrared spectrum is superior to detect the radiation characteristics of both the oil slick and the seawater compared to the mid-wavelength infrared spectrum and which have great potential to detect the oil slick thickness. And the emissivity is the ratio of the radiation of an object at a given temperature in normal range of the temperature (260-320 K) and the blackbody radiation under the same temperature , the emissivity of an object is unrelated to the temperature, but only is dependent with the wavelength and material properties. Using the seawater taken from Bohai Bay and crude oil taken from Gudao oil production plant of Shengli Oilfield in Dongying city of Shandong Province, an experiment was designed to study the characteristics and mechanism of thermal infrared emissivity spectrum of artificial crude oil slick covered seawater surface with its thickness. During the experiment, crude oil was continuously dropped into the seawater to generate artificial oil slick with different thicknesses. By adding each drop of crude oil, we measured the reflectivity of the oil slick in the thermal infrared spectrum with the Fourier transform infrared spectrometer (102F) and then calculated its thermal infrared emissivity. The results show that the thermal infrared emissivity of oil slick changes significantly with its thickness when oil slick is relatively thin (20-120 μm), which provides an effective means for detecting the existence of offshore thin oil slick In the spectrum ranges from 8 to 10 μm and from 13. 2 to 14 μm, there is a steady emissivity difference between the seawater and thin oil slick with thickness of 20 μm. The emissivity of oil slick changes marginally with oil slick thickness and

  14. Evidence of non-thermal X-ray emission from HH 80

    OpenAIRE

    López-Santiago, J.; Peri, C.; Bonito, R.; Miceli, M.; Albacete-Colombo, J.; Benaglia, P.; De Castro, E.

    2013-01-01

    Protostellar jets appear at all stages of star formation when the accretion process is still at work. Jets travel at velocities of hundreds of km s^-1, creating strong shocks when interacting with the interstellar medium. Several cases of jets have been detected in X-rays, typically showing soft emission. For the first time, we report evidence of hard X-ray emission possibly related to non-thermal processes not explained by previous models of the post-shock emission predicted in the jet/ambie...

  15. Observational limitations of Bose-Einstein photon statistics and radiation noise in thermal emission

    Science.gov (United States)

    Lee, Y.-J.; Talghader, J. J.

    2018-01-01

    For many decades, theory has predicted that Bose-Einstein statistics are a fundamental feature of thermal emission into one or a few optical modes; however, the resulting Bose-Einstein-like photon noise has never been experimentally observed. There are at least two reasons for this: (1) Relationships to describe the thermal radiation noise for an arbitrary mode structure have yet to be set forth, and (2) the mode and detector constraints necessary for the detection of such light is extremely hard to fulfill. Herein, photon statistics and radiation noise relationships are developed for systems with any number of modes and couplings to an observing space. The results are shown to reproduce existing special cases of thermal emission and are then applied to resonator systems to discuss physically realizable conditions under which Bose-Einstein-like thermal statistics might be observed. Examples include a single isolated cavity and an emitter cavity coupled to a small detector space. Low-mode-number noise theory shows major deviations from solely Bose-Einstein or Poisson treatments and has particular significance because of recent advances in perfect absorption and subwavelength structures both in the long-wave infrared and terahertz regimes. These microresonator devices tend to utilize a small volume with few modes, a regime where the current theory of thermal emission fluctuations and background noise, which was developed decades ago for free-space or single-mode cavities, has no derived solutions.

  16. Deuterium thermal desorption and re-emission from RAFM steels

    Science.gov (United States)

    Ryabtsev, S. A.; Gasparyan, Yu M.; Harutyunyan, Z. R.; Timofeev, I. M.; Ogorodnikova, O. V.; Pisarev, A. A.

    2017-12-01

    In the present work, deuterium (D) retention and release during and after ion irradiation of reduced-activation ferritic-marthensitic steels (Eurofer) in comparison with the D retention in pure iron (Fe) was studied. The irradiation was done with 5 keV {{{{D}}}3}+ ions at room temperature at the fluence varied in the range of 1 × 1020-1 × 1022 D m-2. Thermal desorption spectroscopy (TDS) was also performed in situ in 45 min after irradiation. The D release from both materials between the end of irradiation and the start of TDS was very intensive and the integral amount of D measured during outgassing exceeded the D retention measured by TDS. An influence of surface oxidation on the D release due to contact with an environmental air was also demonstrated by comparison of in situ and ex situ TDS. The integral D retention in Eurofer was 1-2 orders of magnitude higher than in pure iron (Fe) due to the initially high concentration of defects in Eurofer. However, pre-annealing of Eurofer at 800 K reduced the defect concentration in Eurofer and, therefore, reduced the difference in the D retention in Fe and Eurofer.

  17. Galactic Latitude Dependence of Near-infrared Diffuse Galactic Light: Thermal Emission or Scattered Light?

    Science.gov (United States)

    Sano, K.; Matsuura, S.

    2017-11-01

    Near-infrared (IR) diffuse Galactic light (DGL) consists of scattered light and thermal emission from interstellar dust grains illuminated by the interstellar radiation field (ISRF). At 1.25 and 2.2 μ {{m}}, a recent observational study shows that intensity ratios of the DGL to interstellar 100 μ {{m}} dust emission steeply decrease toward high Galactic latitudes (b). In this paper, we investigate the origin(s) of the b-dependence on the basis of models of thermal emission and scattered light. Combining a thermal emission model with the regional variation of the polycyclic aromatic hydrocarbon abundance observed with Planck, we show that the contribution of the near-IR thermal emission component to the observed DGL is lower than ∼ 20 % . We also examine the b-dependence of the scattered light, assuming a plane–parallel Galaxy with smooth distributions of the ISRF and dust density along the vertical direction, and assuming a scattering phase function according to a recently developed model of interstellar dust. We normalize the scattered light intensity to the 100 μ {{m}} intensity corrected for deviation from the cosecant-b law according to the Planck observation. As the result, the present model that considers the b-dependence of dust and the ISRF properties can account for the observed b-dependence of the near-IR DGL. However, the uncertainty in the correction for the 100 μ {{m}} emission is large, and other normalizing quantities may be appropriate for a more robust analysis of the DGL.

  18. In situ probing of temperature in radio frequency thermal plasma using Yttrium ion emission lines during synthesis of yttria nanoparticles

    Science.gov (United States)

    Dhamale, G. D.; Tiwari, N.; Mathe, V. L.; Bhoraskar, S. V.; Ghorui, S.

    2017-07-01

    Particle feeding is used in the most important applications of radio frequency (r.f.) thermal plasmas like synthesis of nanoparticles and particle spheroidization. The study reports an in-situ investigation of radial distribution of temperature in such devices using yttrium ion emission lines under different rates of particle loading during synthesis of yttria nanoparticles. A number of interesting facts about the response of r.f. plasma to the rate of particle loading, hitherto unknown, are revealed. Observed phenomena are supported with experimental data from fast photographic experiments and actual synthesis results. The use of the Abel inversion technique together with simultaneous multi-track acquisition of emission spectra from different spatial locations using a CCD based spectrometer allowed us to extract accurate distribution of temperature inside the plasma in the presence of inherent instabilities. The temperature profiles of this type of plasma have been measured possibly for the first time while particles are being fed into the plasma. Observed changes in the temperature profiles as the particle feed rate increases are very significant. Reaction forces resulting from particle evaporation, and increased skin depth owing to the decrease in electrical conductivity in the edge region are proposed as the two different mechanisms to account for the observed changes in the temperature profile as the powder feed rate is increased. Quantitative analyses supporting the proposed mechanisms are presented.

  19. A Temperature and Emissivity Separation Algorithm for Landsat-8 Thermal Infrared Sensor Data

    Directory of Open Access Journals (Sweden)

    Songhan Wang

    2015-08-01

    Full Text Available On-board the Landsat-8 satellite, the Thermal Infrared Sensor (TIRS, which has two adjacent thermal channels centered roughly at 10.9 and 12.0 μm, has a great benefit for the land surface temperature (LST retrieval. The single-channel algorithm (SC and split-window algorithm (SW have been applied to retrieve the LST from TIRS data, which need the land surface emissivity (LSE as prior knowledge. Due to the big challenge of determining the LSE, this study develops a temperature and emissivity separation algorithm which can simultaneously retrieve the LST and LSE. Based on the laboratory emissivity spectrum data, the minimum-maximum emissivity difference module (MMD module for TIRS data is developed. Then, an emissivity log difference method (ELD method is developed to maintain the emissivity spectrum shape in the iterative process, which is based on the modified Wien’s approximation. Simulation results show that the root-mean-square-errors (RMSEs are below 0.7 K for the LST and below 0.015 for the LSE. Based on the SURFRAD ground measurements, further evaluation demonstrates that the average absolute error of the LST is about 1.7 K, which indicated that the algorithm is capable of retrieving the LST and LSE simultaneously from TIRS data with fairly good results.

  20. Large hydrocarbon fuel pool fires: Physical characteristics and thermal emission variations with height

    Energy Technology Data Exchange (ETDEWEB)

    Raj, Phani K. [Technology and Management Systems Inc., 102 Drake Road, Burlington, MA 01803 (United States)]. E-mail: tmsinc1981@verizon.net

    2007-02-09

    In a recent paper [P.K. Raj, Large LNG fire thermal radiation-modeling issues and hazard criteria revisited, Process Safety Progr., 24 (3) (2005)] it was shown that large, turbulent fires on hydrocarbon liquid pools display several characteristics including, pulsating burning, production of smoke, and reduced thermal radiation, with increasing size. In this paper, a semi-empirical mathematical model is proposed which considers several of these important fire characteristics. Also included in this paper are the experimental results for the variation of the fire radiance from bottom to top of the fire (and their statistical distribution) from the largest land spill LNG pool fire test conducted to date. The purpose of the model described in this paper is to predict the variation of thermal radiation output along the fire plume and to estimate the overall thermal emission from the fire as a function its size taking into consideration the smoke effects. The model utilizes experimentally measured data for different parameters and uses correlations developed from laboratory and field tests with different fuels. The fire dynamics and combustion of the fuel are modeled using known entrainment and combustion efficiency parameter values. The mean emissive power data from field tests are compared with model predictions. Model results for the average emissive powers of large, hypothetical LNG fires are indicated.

  1. Angle-Selective Reflective Filters for Exclusion of Background Thermal Emission

    Science.gov (United States)

    Sakr, Enas; Bermel, Peter

    2017-04-01

    Selective filtering of spectral and angular optical transmission has recently attracted a great deal of interest. While optical passband and stop-band spectral filters are already widely used, angle-selective transmission and reflection filtering represents a less than fully explored alternative. Nonetheless, this approach can be promising for several applications, including stray radiation minimization and background emission exclusion. In this work, a concept for angle-selective reflection filtering using guided-mode resonance coupling is proposed. Although guided-mode resonance structures are already used for spectral filtering, in this work, a variation of angle-selective reflection filtering using guided-mode resonance coupling is proposed. We investigate angle-dependent properties of such structures for potential use as angle-selective reflective filters. We utilize interference between diffraction modes to provide tunable selectivity with a sufficient angular width. Combining these structures with thermal emitters can exclude selected emission angles for spatially selective thermal emissivity reduction toward sensitive targets, as well as directionally selective emissivity exclusion for suppression of solar heating. We show a very large selective reduction of heat exchange by 99.77% between an engineered emitter and a distant receiver using just a single-groove grating and an emitting substrate in the emitter's side. Also, we show a selective reduction of heat exchange by approximately 77% between an emitter covered by engineered sets of angle-selective reflective filters and a nearby sensitive target. The suggested angle-selective structure may have applications in excluding background thermal radiation, in particular, thermal emission reduction for daytime radiative cooling, sensitive IR telescope detectors, and high-fidelity thermoluminescent spectroscopy.

  2. Enhanced performance of thermal-assisted electron field emission based on barium oxide nanowire

    Energy Technology Data Exchange (ETDEWEB)

    Cui, Yunkang [Department of Mathematics and Physics, Nanjing Institute of technology, Nanjing, 211167 (China); Chen, Jing, E-mail: chenjingmoon@gmail.com [School of Electronic Science & Engineering, Southeast University, Nanjing, 210096 (China); Zhang, Yuning; Zhang, Xiaobing; Lei, Wei; Di, Yunsong [School of Electronic Science & Engineering, Southeast University, Nanjing, 210096 (China); Zhang, Zichen, E-mail: zz241@ime.ac.cn [Integrated system for Laser applications Group, Institute of Microelectronics of Chinese Academy of Sciences, 100029, Beijing (China)

    2017-02-28

    Highlights: • A possible mechanism for thermal-assisted electric field was demonstrated. • A new path for the architecture of the novel nanomaterial and methodology for its potential application in the field emission device area was provided. • The turn-on field, the threshold field and the field emission current density were largely related to the temperature of the cathode. • The relationship between the work function of emitter material and the temperature of emitter was found. - Abstract: In this paper, thermal-assisted field emission properties of barium oxide (BaO) nanowire synthesized by a chemical bath deposition method were investigated. The morphology and composition of BaO nanowire were characterized by field emission scanning electron microscopy (FESEM), high resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SED), X-ray diffraction (XRD), and energy dispersive X-ray spectrometer (EDX) respectively. The turn-on field, threshold field and the emission current density could be affected relatively due to the thermal-assisted effect when the electric field was applied, in the meanwhile, the turn-on field for BaO nanowire was measured to be decreased from 1.12 V/μm to 0.66 V/μm when the temperature was raised from 293 K to 593 K, whereas for the threshold field was found to decrease from 3.64 V/μm to 2.12 V/μm. The improved performance was demonstrated due to the reduced work function of the BaO nanowire as the agitation temperature increasing, leading to the higher probability of electrons tunneling through the energy barrier and enhancement of the field emission properties of BaO emitters.

  3. Using Lunar Observations to Assess Terra MODIS Thermal Emissive Bands Calibration

    Science.gov (United States)

    Xiong, Xiaoxiong; Chen, Hongda

    2010-01-01

    MODIS collects data in both the reflected solar and thermal emissive regions using 36 spectral bands. The center wavelengths of these bands cover the3.7 to 14.24 micron region. In addition to using its on-board calibrators (OBC), which include a full aperture solar diffuser (SD) and a blackbody (BB), lunar observations have been scheduled on a regular basis to support both Terra and Aqua MODIS on-orbit calibration and characterization. This paper provides an overview of MODIS lunar observations and their applications for the reflective solar bands (RSB) and thermal emissive bands (TEB) with an emphasis on potential calibration improvements of MODIS band 21 at 3.96 microns. This spectral band has detectors set with low gains to enable fire detection. Methodologies are proposed and examined on the use of lunar observations for the band 21 calibration. Also presented in this paper are preliminary results derived from Terra MODIS lunar observations and remaining challenging issues.

  4. Non-intrusive measurement of emission indices. A new approach to the evaluation of infrared spectra emitted by aircraft engine exhaust gases

    Energy Technology Data Exchange (ETDEWEB)

    Lindermeir, E.; Haschberger, P.; Tank, V. [Deutsche Forschungsanstalt fuer Luft- und Raumfahrt e.V. (DLR), Wessling (Germany). Inst. fuer Optoelektronik

    1997-12-31

    A non-intrusive method is used to determine the emission indices of a research aircraft`s engine in-flight. The principle is based on the Fourier Transform Infrared Spectrometer MIROR which was specifically designed and built for operation aboard aircrafts. This device measures the spectrum of the infrared radiation emitted by the hot exhaust gas under cruise conditions. From these spectra mixing ratios and emission indices can be derived. An extension to previously applied evaluation schemes is proposed: Whereas formerly the plume was assumed a homogeneous layer of gas, temperature and concentration profiles are now introduced to the evaluation procedure. (author) 5 refs.

  5. Time-resolved emission spectra of 4-dimethylamino-4‧-cyano-stilbene and resveratrol in high viscosity solvents and silica matrices

    Science.gov (United States)

    Borowiak, Małgorzata; Grobelna, Beata; Synak, Anna; Bojarski, Piotr; Kubicki, Aleksander A.

    2013-11-01

    Time-resolved emission spectra of 4-dimethylamino-4‧-cyano-stilbene (DMACS) and 3,5,4‧-trihydroxy-stilbene (resveratrol, RSV) in propylene glycol and in rigid silica xerogel matrix at 23 °C were studied. For the polar molecule DMACS in propylene glycol, a 66 nm shift of maximum wavelength of emission spectra was observed within 1 ns after excitation, and most of the shift occurred during the first 200 ps. For resveratrol in propylene glycol no such a shift was observed. The rigid silica environment eliminates some deactivation pathways and stabilizes spectroscopic properties of both molecules. Spectral properties of nonpolar and high dipole moment molecules in viscous liquids and rigid environments are compared. Results are explained on the basis of intramolecular processes and solute-solvent relaxation, as well.

  6. Theoretical X-ray photoelectron and emission spectra of Si- and S-containing polymers by density-functional theory calculations using model molecules

    Science.gov (United States)

    Endo, K.; Shimada, S.; Ida, T.; Suhara, M.; Kurmaev, E. Z.; Moewes, A.; Chong, D. P.

    2001-04-01

    The X-ray photoelectron and emission spectra (XPS and XES) of Si- and S-containing polymers [(-Si{-CH 2-} 3) n (PCS), (-Si(CH 3)(OH)-O-) n (PMHSO), (-Si(C 6H 5)(OH)-O-) n (PTES), (-Si(C 6H 5)(OH)-O-Si(CH 3)(OH)-O-) n (PPMHSO), (-C 6H 4-O-C 6H 4-SO 2-) n (PES)] were simulated by the deMon density-functional theory (DFT) calculations using the model molecules. The theoretical valence photoelectron and C Kα X-ray emission spectra showed good accordance with some experimental ones. The combined analysis of the valence XPS and C and O Kα XES enables us to divide the observed valence electronic distribution into the individual contributions for pσ-, pπ- and non-bonding MOs of the polymers.

  7. Thermal performances and CO emissions of gas-fired cooker-top burners

    Energy Technology Data Exchange (ETDEWEB)

    Li, H.B.; Wong, T.T.; Leung, C.W. [The Hong Kong Polytechnic University, Kowloon (Hong Kong). Department of Mechanical Engineering; Probert, S.D. [Cranfield University, Bedford (United Kingdom). School of Mechanical Engineering

    2006-12-15

    Domestic cooker-top burners operate at low pressure and low Reynolds numbers. They do not usually have a flue, and are fired with impinging premixed natural-gas/air flames. There are two major considerations in using such burners, namely, poor energy utilization and indoor-air pollution. Because of the large number of cooker-top burners being used, even a slight improvement in thermal performance resulting from a better design will lead to significant reductions of domestic and commercial energy consumptions. In view of the need to raise the thermal performance and to reduce indoor-air pollution, advanced statistical experimental designs have been applied in the present study to evaluate the individual and combined effects of the major cooker-top design parameters. The experimental study was carried out using a 4-factor and 3-level Box-Behnken design-method, utilizing a premixed gas-fired impinging-flame. A cooker-top burner, with circular nozzles with an inner diameter of 3mm, was used in this experiment. Design parameters of the burner under consideration include Reynolds number, equivalence ratio, nozzle-to-plate distance, and jet-to-jet spacing. Based on an analysis of the experimental data, variations of the thermal efficiency and the carbon monoxide (CO) emission with each of the above mentioned parameters have been reported. Multiple regression models of the thermal efficiency and the CO emissions were obtained in terms of all the major design parameters. Some of the 2-factor interactions on the thermal efficiency and the CO emissions were significant. The findings are important for the designer of a fuel-efficient and environmentally-friendly cooker-top burner. (author)

  8. Spectral and angular-selective thermal emission from gallium-doped zinc oxide thin film structures

    Science.gov (United States)

    Sakr, Enas; Bermel, Peter

    2017-02-01

    Simultaneously controlling both the spectral and angular emission of thermal photons can qualitatively change the nature of thermal radiation, and offers a great potential to improve a broad range of applications, including infrared light sources and thermophotovoltaic (TPV) conversion of waste heat to electricity. For TPV in particular, frequency-selective emission is necessary for spectral matching with a photovoltaic converter, while directional emission is needed to maximize the fraction of emission reaching the receiver at large separation distances. This can allow the photovoltaics to be moved outside vacuum encapsulation. In this work, we demonstrate both directionally and spectrally-selective thermal emission for p-polarization, using a combination of an epsilon-near-zero (ENZ) thin film backed by a metal reflector, a high contrast grating, and an omnidirectional mirror. Gallium-doped zinc oxide is selected as an ENZ material, with cross-over frequency in the near-infrared. The proposed structure relies on coupling guided modes (instead of plasmonic modes) to the ENZ thin film using the high contrast grating. The angular width is thus controlled by the choice of grating period. Other off-directional modes are then filtered out using the omnidirectional mirror, thus enhancing frequency selectivity. Our emitter design maintains both a high view factor and high frequency selectivity, leading to a factor of 8.85 enhancement over a typical blackbody emitter, through a combination of a 22.26% increase in view factor and a 6.88x enhancement in frequency selectivity. This calculation assumes a PV converter five widths away from the same width emitter in 2D at 1573 K.

  9. Estimate carbon emissions from degraded permafrost with InSAR and a soil thermal model

    Science.gov (United States)

    Zhou, Z.; Liu, L.

    2016-12-01

    Climate warming, tundra fire over past decades has caused degradation in permafrost widely and quickly. Recent studies indicate that an increase in degradation could switch permafrost from a carbon sink to a source, with the potential of creating a positive feedback to anthropogenic climate warming. Unfortunately, Soil Organic Carbon (SOC) emissions from degraded permafrost unquantified, and limit our ability to understand SOC losses in arctic environments. This work will investigate recent 10 years of data already collected at the Anaktuvuk River fire (both ground and remote sensed), and will employ a soil thermal model to estimate SOC emission in this region. The model converts the increases in Active Layer Thickness (ALT), as measured by InSAR, to changes in Organic Layer Thickness (OLT), and SOC. ALOS-1/2 L-band SAR dataset will be used to produce the ATL changes over the study area. Soil prosperities (e.g. temperature at different depth, bulk density) will be used in the soil thermal model to estimate OLT changes and SOC losses. Ground measurement will validate the InSAR results and the soil thermal model. A final estimation of SOC emission will be produced in Anaktuvuk River region.

  10. DFT study of electron absorption and emission spectra of pyramidal LnPc(OAc) complexes of some lanthanide ions in the solid state.

    Science.gov (United States)

    Hanuza, J; Godlewska, P; Lisiecki, R; Ryba-Romanowski, W; Kadłubański, P; Lorenc, J; Łukowiak, A; Macalik, L; Gerasymchuk, Yu; Legendziewicz, J

    2018-01-04

    The electron absorption and emission spectra were measured for the pyramidal LnPc(OAc) complexes in the solid state and co-doped in silica glass, where Ln=Er, Eu and Ho. The theoretical electron spectra were determined from the quantum chemical DFT calculation using four approximations CAM-B3LYP/LANL2DZ, CAM-B3LYP/CC-PVDZ, B3LYP/LANL2DZ and B3LYP/CC-PVDZ. It was shown that the best agreement between the calculated and experimental structural parameters and spectroscopic data was reached for the CAM-B3LYP/LANL2DZ model. The emission spectra were measured using the excitations both in the ligand and lanthanide absorption ranges. The possibility of energy transfer between the phthalocyanine ligand and excited states of lanthanide ions was discussed. It was shown that the back energy transfer from metal states to phthalocyanine state is responsible for the observed emission of the studied complexes both in the polycrystalline state and silica glass. Copyright © 2018. Published by Elsevier B.V.

  11. Near infrared emission from molecule-like silver clusters confined in zeolite A assisted by thermal activation

    Energy Technology Data Exchange (ETDEWEB)

    Lin, Hui, E-mail: linh8112@163.com; Imakita, Kenji; Rong Gui, Sa Chu; Fujii, Minoru, E-mail: fujii@eedept.kobe-u.ac.jp [Department of Electrical and Electronic Engineering, Graduate School of Engineering, Kobe University, Rokkodai, Nada, Kobe 657-8501 (Japan)

    2014-07-07

    Strong and broad near infrared (NIR) emission peaked at ~855 nm upon optimal excitation at 342 nm has been observed from molecule-like silver clusters (MLSCs) confined in zeolite A assisted by thermal activation. To the best of our knowledge, this is the first observation of NIR emission peaked at longer than 800 nm from MLSCs confined in solid matrices. The decay time of the NIR emission is over 10 μs, which indicates that it is a spin-forbidden transition. The ~855 nm NIR emission shows strong dependence on the silver loading concentration and the thermal activation temperature.

  12. Multiple scattering and nonlinear thermal emission of Yb3+, Er3+:Y2O3 nanopowders

    Science.gov (United States)

    Redmond, S.; Rand, S. C.; Ruan, X. L.; Kaviany, M.

    2004-04-01

    Radiation transport and multiple scattering calculations are presented and compared with experimental observations to characterize light attenuation in high emissivity nanopowders irradiated with low power laser light at room temperature, and to explain the associated white light emission and the onset of melting. Using radiation tuned to an absorption resonance of Yb3+ dopants in Y2O3 nanopowder, we observed the onset of intense blackbody emission above a well-defined intensity threshold. Local melting of the compact above threshold leads to the formation of single crystal microtubes. Evidence is provided to show that two-flux transport theory and diffusion theory both significantly underestimate the absorption due to dependent, multiple scattering and that the threshold for the thermal runaway process responsible for this behavior is very sensitive to porosity of the random medium.

  13. The empirical definition of total emissivity of modern superthin liquid composite thermal insulators

    Science.gov (United States)

    Anisimov, M. V.; Rekunov, V. S.; Babuta, M. N.; Lychagin, D. V.; Kuznetsova, U. N.; Bach Lien, Nguyen Thi Hong; Ivanova, E. V.; Taalaybekov, Z. T.

    2016-11-01

    Modern world trends in the field of energy and mineral resources preservation policy involves the need for a more cost-efficient use of the Earth's natural resources, including in the field of construction industry. Using insulation modern materials would largely solve this problem. The acceptability appraisal of various advanced heat-insulating blankets is a crucial task, which requires experimental verification of total emissivity empirical definition of modern super-thin liquid composite thermal insulators and their real value definition. Method of investigation is as follows: an empirical definition of blankets emissivity using the proposed laboratory equipment, which comprises a system of "gray" bodies, thermocouple probe and a source of continuous heat flux. Total emissivity of modern super-thin liquid composite thermal insulators is experimentally determined. It amounted e = 0.89 for sample # 1, and e = 0.87 for sample # 2 at a temperature of 35-65 °C. It was found that the actual emissivity of the samples was higher than it had been declared.

  14. Thermal stability and adhesion of low-emissivity electroplated Au coatings.

    Energy Technology Data Exchange (ETDEWEB)

    Jorenby, Jeff W.; Hachman, John T., Jr.; Yang, Nancy Y. C.; Chames, Jeffrey M.; Clift, W. Miles

    2010-12-01

    We are developing a low-emissivity thermal management coating system to minimize radiative heat losses under a high-vacuum environment. Good adhesion, low outgassing, and good thermal stability of the coating material are essential elements for a long-life, reliable thermal management device. The system of electroplated Au coating on the adhesion-enhancing Wood's Ni strike and 304L substrate was selected due to its low emissivity and low surface chemical reactivity. The physical and chemical properties, interface bonding, thermal aging, and compatibility of the above Au/Ni/304L system were examined extensively. The study shows that the as-plated electroplated Au and Ni samples contain submicron columnar grains, stringers of nanopores, and/or H{sub 2} gas bubbles, as expected. The grain structure of Au and Ni are thermally stable up to 250 C for 63 days. The interface bonding is strong, which can be attributed to good mechanical locking among the Au, the 304L, and the porous Ni strike. However, thermal instability of the nanopore structure (i.e., pore coalescence and coarsening due to vacancy and/or entrapped gaseous phase diffusion) and Ni diffusion were observed. In addition, the study also found that prebaking 304L in the furnace at {ge} 1 x 10{sup -4} Torr promotes surface Cr-oxides on the 304L surface, which reduces the effectiveness of the intended H-removal. The extent of the pore coalescence and coarsening and their effect on the long-term system integrity and outgassing are yet to be understood. Mitigating system outgassing and improving Au adhesion require a further understanding of the process-structure-system performance relationships within the electroplated Au/Ni/304L system.

  15. Iapetus' near surface thermal emission modeled and constrained using Cassini RADAR Radiometer microwave observations

    Science.gov (United States)

    Le Gall, A.; Leyrat, C.; Janssen, M. A.; Keihm, S.; Wye, L. C.; West, R.; Lorenz, R. D.; Tosi, F.

    2014-10-01

    Since its arrival at Saturn, the Cassini spacecraft has had only a few opportunities to observe Iapetus, Saturn's most distant regular satellite. These observations were all made from long ranges (>100,000 km) except on September 10, 2007, during Cassini orbit 49, when the spacecraft encountered the two-toned moon during its closest flyby so far. In this pass it collected spatially resolved data on the object's leading side, mainly over the equatorial dark terrains of Cassini Regio (CR). In this paper, we examine the radiometry data acquired by the Cassini RADAR during both this close-targeted flyby (referred to as IA49-3) and the distant Iapetus observations. In the RADAR's passive mode, the receiver functions as a radiometer to record the thermal emission from planetary surfaces at a wavelength of 2.2-cm. On the cold icy surfaces of Saturn's moons, the measured brightness temperatures depend both on the microwave emissivity and the physical temperature profile below the surface down to a depth that is likely to be tens of centimeters or even a few meters. Combined with the concurrent active data, passive measurements can shed light on the composition, structure and thermal properties of planetary regoliths and thus on the processes from which they have formed and evolved. The model we propose for Iapetus' microwave thermal emission is fitted to the IA49-3 observations and reveals that the thermal inertias sensed by the Cassini Radiometer over both CR and the bright mid-to-high latitude terrains, namely Ronceveaux Terra (RT) in the North and Saragossa Terra (ST) in the South, significantly exceed those measured by Cassini's CIRS (Composite Infrared Spectrometer), which is sensitive to much smaller depths, generally the first few millimeters of the surface. This implies that the subsurface of Iapetus sensed at 2.2-cm wavelength is more consolidated than the uppermost layers of the surface. In the case of CR, a thermal inertia of at least 50 J m-2 K-1 s-1/2, and

  16. Broadband white light emission from Ce:AlN ceramics: High thermal conductivity down-converters for LED and laser-driven solid state lighting

    Directory of Open Access Journals (Sweden)

    A. T. Wieg

    2016-12-01

    Full Text Available We introduce high thermal conductivity aluminum nitride (AlN as a transparent ceramic host for Ce3+, a well-known active ion dopant. We show that the Ce:AlN ceramics have overlapping photoluminescent (PL emission peaks that cover almost the entire visible range resulting in a white appearance under 375 nm excitation without the need for color mixing. The PL is due to a combination of intrinsic AlN defect complexes and Ce3+ electronic transitions. Importantly, the peak intensities can be tuned by varying the Ce concentration and processing parameters, causing different shades of white light without the need for multiple phosphors or light sources. The Commission Internationale de l’Eclairage coordinates calculated from the measured spectra confirm white light emission. In addition, we demonstrate the viability of laser driven white light emission by coupling the Ce:AlN to a readily available frequency tripled Nd-YAG laser emitting at 355 nm. The high thermal conductivity of these ceramic down-converters holds significant promise for producing higher power white light sources than those available today.

  17. New Chandra observations of the jet in 3C273. 1. Softer X-ray than radio spectra and the X-ray emission mechanism

    Energy Technology Data Exchange (ETDEWEB)

    Jester, Sebastian; /Fermilab; Harris, D.E.; /Smithsonian Astrophys. Observ.; Marshall, H.L.; /MIT, MKI; Meisenheimer, K.; /Heidelberg, Max Planck Inst. Astron.

    2006-05-01

    The jet in 3C273 is a high-power quasar jet with radio, optical and X-ray emission whose size and brightness allow a detailed study of the emission processes acting in it. We present deep Chandra observations of this jet and analyze the spectral properties of the jet emission from radio through X-rays. We find that the X-ray spectra are significantly softer than the radio spectra in all regions of the bright part of the jet except for the first bright ''knot A'', ruling out a model in which the X-ray emission from the entire jet arises from beamed inverse-Compton scattering of cosmic microwave background photons in a single-zone jet flow. Within two-zone jet models, we find that a synchrotron origin for the jet's X-rays requires fewer additional assumptions than an inverse-Compton model, especially if velocity shear leads to efficient particle acceleration in jet flows.

  18. The investigation of the neutron emission spectra of {sup 232}Th and {sup 238}U for neutron incident energy from 2 to 18 MeV

    Energy Technology Data Exchange (ETDEWEB)

    Tel, Eyyup [Gazi University, Faculty of Arts and Science, Department of Physics, Ankara (Turkey); Sahin, Haci Mehmet [Gazi University, Faculty of Technical Education, Department of Mechanical Education, 06503 Teknikokullar, Ankara (Turkey)]. E-mail: mesahin@gazi.edu.tr; Arasoglu, Ali [Yuezuencue Yil University, Faculty of Arts and Science, Department of Physics, Van (Turkey); Aytekin, Hueseyin [Karaelmas University, Faculty of Arts and Science, Department of Physics, Zonguldak (Turkey)

    2006-03-15

    In this study, experimental neutron-emission spectra produced by (n, xn) reactions on nuclei {sup 232}Th have been compared with experimental {sup 238}U(n, xn) neutron-emission spectra from 2 to 18 MeV. Angle-integrated cross-sections in neutron induced reactions on targets {sup 238}U have been calculated at the bombarding energies from 2 to 18 MeV. In the calculations, the geometry dependent hybrid model and the cascade exciton model including the effects of pre-equilibrium have been used. In addition, we have described how multiple pre-equilibrium emissions can be included in the Feshbach-Kerman-Koonin (FKK) fully quantum-mechanical theory. By analyzing (n, xn) reaction on {sup 238}U with the incident energy from 2 to 18 MeV, the importance of multiple pre-equilibrium emission can be seen clearly. All calculated results have been compared with experimental data. The obtained results have been discussed and compared with the available experimental data and found agreement with each other.

  19. Comparison of Retrieved L2 Products from Four Successive Versions of L1B Spectra in the Thermal Infrared Band of TANSO-FTS over the Arctic Ocean

    Directory of Open Access Journals (Sweden)

    Sébastien Payan

    2017-11-01

    Full Text Available This paper concentrates on the calibration/validation of the Thermal and Near Infrared Sensor for Carbon Observation (TANSO–Fourier Transform Spectrometer (FTS spectra in the thermal infrared (TIR spectral region (B4 band over the Arctic Ocean. We have performed inter-comparisons of the retrieved L2 products from four successive versions of L1B products (V150, V160, V201, V203 to check the differences and the improvement in the spectral and radiometric calibration of TANSO-FTS spectra in the narrow spectral domain of 940–980 cm−1 covering CO2 lines of the so-called laser band in the rather clear 10.4 μm atmospheric window, allowing sounding down to the lowest atmospheric layers. To our knowledge, this is the first attempt to retrieve XCO2 from this spectral region. The period covered is the summer months (July, August, September and the years from 2009 to 2015. Internal comparisons of L1B TANSO-FTS spectra, as well as comparisons of retrieved L2 products, i.e., Tsurf (sea surface temperature or SST and the retrieved column-averaged dry air volume mixing ratio XCO2 derived with the same algorithm are presented. The overall trend in the CO2 column-averaged VMR is well captured over the six year period for Green-house Gases Observing Satellite (GOSAT, but calibration issues are still hindering the use of TANSO-FTS TIR spectra for accurate and stable XCO2 and Tsurf products. However, an internal comparison of the successive L1B versions is possible and helpful to make progress with respect to the radiometric and spectral calibration TIR spectra collected by TANSO-FTS on GOSAT.

  20. Forest treatment residues for thermal energy compared with disposal by onsite burning: Emissions and energy return

    Energy Technology Data Exchange (ETDEWEB)

    Jones, Greg; Calkin, David [Human Dimensions Science Program, Rocky Mountain Research Station, USDA Forest Service, PO Box 7669, 200 East Broadway Street, Missoula, MT 59807 (United States); Loeffler, Dan [The University of Montana, College of Forestry and Conservation, PO Box 7669, 200 East Broadway Street, Missoula, MT 59807 (United States); Chung, Woodam [The University of Montana, College of Forestry and Conservation, Missoula, MT 59812 (United States)

    2010-05-15

    Mill residues from forest industries are the source for most of the current wood-based energy in the US, approximately 2.1% of the nation's energy use in 2007. Forest residues from silvicultural treatments, which include limbs, tops, and small non-commercial trees removed for various forest management objectives, represent an additional source of woody biomass for energy. We spatially analyzed collecting, grinding, and hauling forest residue biomass on a 515,900 ha area in western Montana, US, to compare the total emissions of burning forest residues in a boiler for thermal energy with the alternatives of onsite disposal by pile-burning and using either natural gas or 2 distillate oil to produce the equivalent amount of useable energy. When compared to the pile-burn/fossil fuel alternatives, carbon dioxide emissions from the bioenergy alternative were approximately 60%, methane emissions were approximately 3%, and particulate emissions less than 10 {mu}m were 11% and 41%, respectively, for emission control and no-control boilers. Emissions from diesel consumption for collecting, grinding, and hauling biomass represented less than 5% of the total bioenergy emissions at an average haul distance of 136 km. Across the study area, an average 21 units of bioenergy were produced for each unit of diesel energy used to collect, grind, and haul biomass. Fossil fuel energy saved by the bioenergy alternative relative to the pile-burn/fossil fuel alternatives averaged 14.7-15.2 GJ t{sup -1} of biomass. (author)

  1. Predicted Fe II Spectra plus UV through sub-mm Emission Line Fluxes for Other Species Arising in Narrow Line Regions of AGNs

    Science.gov (United States)

    Verner, Ekaterina; Bruhweiler, F. C.; Wills, B. J.

    2009-01-01

    Optical and UV spectra indicate pronounced Fe II emission from multitudinous lines superposed on the underlying UV and optical continua of Seyferts and QSOs. Although the intrinsic UV of the these objects exhibit strong Fe II emission arising in higher density Broad Line Region (BLR) gas, observations at visual wavelengths indicate Fe II originating in both BLR and lower density Narrow Line Region (NLR) gas. Our modeling of observed intrinsic UV Fe II emission produces better fits with both BLR and NLR components. We have calculated a grid of photoionization models appropriate for NLR, spanning a range of number density [log (n/cm-3) = 1.0 to 8.0], photoionizing flux [log (Φ/cm-2 s-1) = 10.0-18.0], microturbulence (ξ = 0, 2, 10, and 20 km s-1), and abundance (0.1, 0.5, 1.0 and 5 times solar). These models include the effects of cooling from Fe II. The effects of Fe II cooling and the use of a 371 versus an 830-level atom for Fe II in producing the Fe II emission spectra are explored. We present predicted Fe II spectra from the UV through the IR, plus fluxes of important lines of other species from the UV through the sub-mm wavelength range. These predictions, besides being relevant for studies of Fe II in AGNs, provide predicted fluxes for important lines for upcoming missions such as Herschel and SOPHIA. These results will be made available to researchers via the World Wide Web. We acknowledge the support of the National Science Foundation through grant AST-0607465 to CUA.

  2. Tunable wideband-directive thermal emission from SiC surface using bundled graphene sheets

    Science.gov (United States)

    Inampudi, Sandeep; Mosallaei, Hossein

    2017-09-01

    Coherent thermal radiation emitters based on diffraction gratings inscribed on surface of a polar material, such as silicon carbide, always possess high angular dispersion resulting in wideband-dispersive or monochromatic-directive emission. In this paper, we identify roots of the high angular dispersion as the rapid surface phonon polariton (SPhP) resonance of the material surface and the misalignment of the dispersion curve of the diffraction orders of the grating with respect to light line. We minimize the rapid variation of SPhP resonance by compensating the material dispersion using bundled graphene sheets and mitigate the misalignment by a proper choice of the grating design. Utilizing a modified form of rigorous coupled wave analysis to simultaneously incorporate atomic-scale graphene sheets and bulk diffraction gratings, we accurately compute the emissivity profiles of the composite structure and demonstrate reduction in the angular dispersion of thermal emission from as high as 30∘ to as low as 4∘ in the SPhP dominant wavelength range of 11-12 μ m . In addition, we demonstrate that the graphene sheets via their tunable optical properties allow a fringe benefit of dynamical variation of the angular dispersion to a wide range.

  3. Removal properties of low-thermal-expansion materials with rotating-sphere elastic emission machining

    Directory of Open Access Journals (Sweden)

    Masahiko Kanaoka et al

    2007-01-01

    Full Text Available Optical mirrors used in extreme ultraviolet lithography systems require a figure accuracy and a roughness of about 0.1 nm rms. In addition, mirror substrates must be low-thermal-expansion materials. Thus, in this study, we processed two low-thermal-expansion materials, ULE [K. Hrdina, B. Hanson, P. Fenn, R. Sabia, Proc. SPIE 4688 (2002 454.] (Corning Inc. and Zerodur [I. Mitra, M.J. Davis, J. Alkemper, Rolf Müller, H. Kohlmann, L. Aschke, E. Mörsen, S. Ritter, H. Hack, W. Pannhorst, Proc. SPIE 4688 (2002 462.] (SCHOTT AG, with elastic emission machining (EEM in order to evaluate the removal properties. Consequently, we successfully calculated the respective removal rates, because removal volumes were found to be proportional to process times in EEM. Moreover, we demonstrated that the surface roughness of Zerodur is reduced to 0.1 nm rms in the spatial wavelength range from 100 μm to 1 mm.

  4. Antineutrino emission and gamma background characteristics from a thermal research reactor

    CERN Document Server

    Bui, V M; Fallot, M; Communeau, V; Cormon, S; Estienne, M; Lenoir, M; Peuvrel, N; Shiba, T; Cucoanes, A S; Elnimr, M; Martino, J; Onillon, A; Porta, A; Pronost, G; Remoto, A; Thiolliere, N; Yermia, F; Zakari-Issoufou, A -A

    2016-01-01

    The detailed understanding of the antineutrino emission from research reactors is mandatory for any high sensitivity experiments either for fundamental or applied neutrino physics, as well as a good control of the gamma and neutron backgrounds induced by the reactor operation. In this article, the antineutrino emission associated to a thermal research reactor: the OSIRIS reactor located in Saclay, France, is computed in a first part. The calculation is performed with the summation method, which sums all the contributions of the beta decay branches of the fission products, coupled for the first time with a complete core model of the OSIRIS reactor core. The MCNP Utility for Reactor Evolution code was used, allowing to take into account the contributions of all beta decayers in-core. This calculation is representative of the isotopic contributions to the antineutrino flux which can be found at research reactors with a standard 19.75\\% enrichment in $^{235}$U. In addition, the required off-equilibrium correction...

  5. Dataset of the absorption, emission and excitation spectra and fluorescence intensity graphs of fluorescent cyanine dyes for the quantification of low amounts of dsDNA

    Directory of Open Access Journals (Sweden)

    Brigitte Bruijns

    2017-02-01

    Full Text Available This article describes data related to a research article entitled “Fluorescent cyanine dyes for the quantification of low amounts of dsDNA” (B. Bruijns, R. Tiggelaar, J. Gardeniers, 2016 [1]. Six cyanine dsDNA dyes - EvaGreen, SYBR Green, PicoGreen, AccuClear, AccuBlue NextGen and YOYO-1 – are investigated and in this article the absorption spectra, as well as excitation and emission spectra, for all six researched cyanine dyes are given, all recorded under exactly identical experimental conditions. The intensity graphs, with the relative fluorescence in the presence of low amounts of dsDNA, are also provided.

  6. Implications of heavy-ion-induced satellite x-ray emission. III. Chemical effects in high resolution sulfur K/sub. cap alpha. / x-ray spectra

    Energy Technology Data Exchange (ETDEWEB)

    Vane, C.R.; Hulett, L.D. Jr.; Kahane, S.; McDaniel, F.D.; Milner, W.T.; Raman, S.; Rosseel, T.M.; Slaughter, G.G.; Varghese, S.L.; Young, J.P.

    1983-01-01

    High resolution (approx. 7 eV at 2.3 keV) sulfur K/sub ..cap alpha../ x-ray spectra have been obtained for a series of sulfur compound targets under heavy ion impact at the Holified Heavy Ion Facility. The spectra observed are dominated by a series of satellite peaks arising from varying degrees of L-shell ionization at the time of x-ray emission. Each spectral profile has been parameterized by a single variable p/sub L/, the apparent average L-shell ionization probability. Correlations are evident between p/sub L/ and the corresponding sulfur atom chemical environment. Much stronger correlations are however found for variations of some individual peak intensities with specific chemical parameters. Comparison of results for Ar/sup q+/ and Kr/sup q+/ projectiles shows that while L-shell ionization probability has increased, chemical sensitivity has apparently saturated.

  7. Spectra of stable sonoluminescence

    Science.gov (United States)

    Lewis, Stephen D.

    1992-12-01

    The continuous emission of picosecond pulses of light has been observed to originate from a bubble trapped at the pressure antinode of a resonant sound field in water and in water/glycerin mixtures. The spectra of this light in several solutions has been measured with a scanning monochrometer/photomultiplier detector system. The spectra are broadband and show strong emission in the UV region. A comparison of this measurement to two other independently produced spectra is made. The spectra are also modeled by a blackbody radiation distribution to determine an effective blackbody temperature and a size is deduced as if Sonoluminescence were characterized by blackbody radiation.

  8. Emission reduction in SI engine using ethanol – gasoline blends on thermal barrier coated pistons

    OpenAIRE

    C.Ananda Srinivasan and C.G.Saravanan

    2010-01-01

    In this study, the effects of ethanol and unleaded gasoline with Isoheptanol blends on multi- cylinder SI engine were investigated. The test fuels were prepared using 99.9% pure ethanol and unleaded gasoline with Isoheptanol blend, in the ratio of E 60 + 2.0 Isoheptanol, E 50 + 1.0 Isoheptanol. In this work the performance, emission and combustion tests were conducted in multi-cylinder petrol engine. The experimental results reveal an increase in brake thermal efficiency on the use of test fu...

  9. Effect of Thermal Treatment of Veneer on Formaldehyde Emission of Poplar Plywood

    Directory of Open Access Journals (Sweden)

    Takato Nakano

    2013-01-01

    Full Text Available A large amount of poplar plywood is now being imported into Japan from China, and as a result, formaldehyde emitted from this plywood represents an undesirable chemical that must be controlled using a chemical catching agent. The aim of this study is to find an approach to reduce the formaldehyde emission of poplar plywood using thermal treatment without employing any chemicals. The experimental results obtained show that heating veneer sheets in the temperature range of 150 °C to 170 °C effectively reduced the formaldehyde emission of plywood, without diminishing the mechanical properties of the veneer. By applying Langmuir’s theory and Hailwood-Horrobin theory to the adsorption isotherm obtained in this study, the relationship between the formaldehyde emission of plywood and the adsorption properties of veneer as a material is discussed. When veneer sheets were heated in the temperature range of 150 °C to 170 °C, the amount of hydrated water (monomolecular layer decreased slightly and that of dissolved water (polymolecular layer did not change. It is hypothesized that the formaldehyde emission of plywood is related to the condition of the adsorption site of the wood.

  10. Temperature and emissivity separation via sparse representation with thermal airborne hyperspectral imager data

    Science.gov (United States)

    Li, Chengyi; Tian, Shufang; Li, Shijie; Yin, Mei

    2016-10-01

    The thermal airborne hyperspectral imager (TASI), which has 32 channels that provide continuous spectral coverage within wavelengths of 8 to 11.5 μm, is very beneficial for land surface temperature and land surface emissivity (LSE) retrieval. In remote sensing applications, emissivity is important for features classification and temperature is important for environmental monitoring, global climate change, and target recognition studies. This paper proposed a temperature and emissivity separation method via sparse representation (SR-TES) with TASI data, which employs a sparseness differences point of view whereby the atmospheric spectrum cannot be considered SR under the LSE spectral dictionary. We built the dictionary from Johns Hopkins University's spectral library as an overcomplete base, and the dictionary learning K-SVD algorithm was adopted. The simulation results showed that SR-TES performed better than the TES algorithm in the case of noise impact, and the results from TASI data for the Liuyuan research region were reasonable; partial validation revealed a root mean square error of 0.0144 for broad emissivity, which preliminarily proves that this method is feasible.

  11. Graphene surface plasmons mediated thermal radiation

    Science.gov (United States)

    Li, Jiayu; Liu, Baoan; Shen, Sheng

    2018-02-01

    A graphene nanostructure can simultaneously serve as a plasmonic optical resonator and a thermal emitter when thermally heated up. The unique electronic and optical properties of graphene have rendered tremendous potential in the active manipulation of light and the microscopic energy transport in nanostructures. Here we show that the thermally pumped surface plasmonic modes along graphene nanoribbons could dramatically modulate their thermal emission spectra in both near- and far-fields. Based on the fluctuating surface current method implemented by the resistive boundary method, we directly calculate the thermal emission spectrum from single graphene ribbons and vertically paired graphene ribbons. Furthermore, we demonstrate that both the near- and far-field thermal emission from graphene nanostructures can be optimized by tuning the chemical potential of doped graphene. The general guideline to maximize the thermal emission is illustrated by the our recently developed theory on resonant thermal emitters modulated by quasi-normal modes.

  12. Collective non-thermal emission from an extragalactic jet interacting with stars

    Science.gov (United States)

    Vieyro, Florencia L.; Torres-Albà, Núria; Bosch-Ramon, Valentí

    2017-08-01

    Context. The central regions of galaxies are complex environments, rich in evolved and/or massive stars. For galaxies hosting an active galactic nucleus (AGN) with jets, the interaction of the jets with the winds of the stars within can lead to particle acceleration, and to extended high-energy emitting regions. Aims: We compute the non-thermal emission produced by the jet flow shocked by stellar winds on the jet scale, far from the jet-star direct interaction region. Methods: First, prescriptions for the winds of the relevant stellar populations in different types of galaxies are obtained. The scenarios adopted include galaxies with their central regions dominated by old or young stellar populations, and with jets of different power. Then, we estimate the available energy to accelerate particles in the jet shock, and compute the transport and energy evolution of the accelerated electrons, plus their synchrotron and inverse Compton emission, in the shocked flow along the jet. Results: A significant fraction of the jet energy, 0.1 - 10%, can potentially be available for the particles accelerated in jet-wind shocks in the studied cases. The non-thermal particles can produce most of the high-energy radiation on jet scales, far from the jet shock region. This high-energy emission will be strongly enhanced in jets aligned with the line of sight due to Doppler boosting effects. Conclusions: The interaction of relativistic jets with stellar winds may contribute significantly to the persistent high-energy emission in some AGNs with jets. However, in the particular case of M 87, this component seems too low to explain the observed gamma-ray fluxes.

  13. Ultra High Resolution Imaging of Enceladus Tiger Stripe Thermal Emission with Cassini CIRS

    Science.gov (United States)

    Spencer, John R.; Gorius, Nicolas; Howett, Carly; Verbiscer, Anne J.; Cassini CIRS Team

    2017-10-01

    In October 2015, Cassini flew within 48 km of Enceladus’ south pole. The spacecraft attitude was fixed during the flyby, but the roll angle of the spacecraft was chosen so that the remote sensing instrument fields of view passed over Damascus, Baghdad, and Cairo Sulci. The Composite Infrared Spectrometer (CIRS) instrument obtained a single interferometer scan during the flyby, using a special mode, enabled by a flight software update, which bypassed numerical filters to improve the fidelity of the interferograms. This generated a total of 11 interferograms, at 5 contiguous spatial locations for each of the 7 - 9 micron (FP4) and 9 - 17 micron (FP3) focal planes, and a single larger field of view for the 17 - 500 micron focal plane (FP1). Strong spikes were seen in the interferograms when crossing each of the sulci, due to the rapid passage of warm material through the field of view. For FP3 and FP4, the temporal variations of the signals from the 5 contiguous detectors can be used to generated 5-pixel-wide images of the thermal emission, which show excellent agreement between the two focal planes. FP3 and FP4 spatial resolution, limited along track by the 5 msec time sampling of the interferogram, and across track by the CIRS field of view, is a remarkable 40 x 40 meters. At this resolution, the tiger stripe thermal emission shows a large amount of structure, including both continuous emission along the fractures, discrete hot spots less than 100 meters across, and extended emission with complex structure.

  14. Prompt fission neutron spectra of sup 2 sup 3 sup 8 U(n,f) above emissive fission threshold

    CERN Document Server

    Maslov, V M; Tetereva, N A; Baba, M; Hasegawa, A; Kornilov, N; Kagalenko, A B

    2003-01-01

    Model calculations were performed to interpret prompt fission neutron spectra (PFNS) of the sup 2 sup 3 sup 8 U(n,f) reaction for incident neutron energies E sub n =6-18 MeV. Pre-fission (pre-saddle) sup 2 sup 3 sup 8 U(n,xnf) reaction neutron spectra were calculated with Hauser-Feshbach statistical model, sup 2 sup 3 sup 8 U fission and (n,xn) reaction cross-section data being described consistently. The increase of the cut-off energy of (n,nf) reaction neutron spectra with excitation energy of fissioning nucleus is described. For E sub n =6-9 MeV the low-energy PFNS component, which is due to the contribution of pre-fission (n,nf) neutrons, is compatible with measured data. Average energy of prefission (n,nf) neutrons is shown to be rather dependent on E sub n. For E sub n =13-18 MeV, a decrease of measured PFNS average neutron energies is interpreted. Spectra of neutrons, evaporated from fission fragments, were approximated as a sum of two Watt distributions. The reduced fission fragment velocity is assume...

  15. The cross sections and energy spectra of the particle emission in proton induced reaction on 204,206,207,208Pb and 209Bi

    Directory of Open Access Journals (Sweden)

    Zhang Zhengjun

    2017-01-01

    Full Text Available All cross sections of proton induced reactions, angular distributions, energy spectra and double differential cross sections of neutron, proton, deuteron, triton, helium and alpha-particle emissions for p+ 204,206,207,208Pb, 209Bi reactions are consistently calculated and analyzed at incident proton energies below 200 MeV. The optical model, the distorted wave Born approximation theory, the unified Hauser-Feshbach and exciton model which includes the improved Iwamoto-Harada model are used. Theoretically calculated results are compared with the existing experimental data.

  16. An accurate retrieval of leaf water content from mid to thermal infrared spectra using continuous wavelet analysis

    NARCIS (Netherlands)

    Ullah, S.; Skidmore, A.K.; Naeem, M.; Schlerf, M.

    2012-01-01

    Leaf water content determines plant health, vitality, photosynthetic efficiency and is an important indicator of drought assessment. The retrieval of leaf water content from the visible to shortwave infrared spectra is well known. Here for the first time, we estimated leaf water content from the mid

  17. The Equilibrium and Pre-equilibrium Triton Emission Spectra of Some Target Nuclei for ( n, xt) Reactions up to 45 MeV Energy

    Science.gov (United States)

    Tel, E.; Kaplan, A.; Aydın, A.; Özkorucuklu, S.; Büyükuslu, H.; Yıldırım, G.

    2010-08-01

    Although there have been significant research and development studies on the inertial and magnetic fusion reactor technology, there is still a long way to go to penetrate commercial fusion reactors to the energy market. Tritium self-sufficiency must be maintained for a commercial power plant. For self-sustaining (D-T) fusion driver tritium breeding ratio should be greater than 1.05. So, working out the systematics of ( n,t) reaction cross sections and triton emission differential data are important for the given reaction taking place on various nuclei at different energies. In this study, ( n,xt) reactions for some target nuclei as 16O, 27Al, 59Co and 209Bi have been investigated up to 45 MeV incident neutron energy. In the calculations of the triton emission spectra, the pre-equilibrium and equilibrium effects have been used. The calculated results have been compared with the experimental data taken from the literature.

  18. NON-THERMAL EMISSION FROM CATACLYSMIC VARIABLES: IMPLICATIONS ON ASTROPARTICLE PHYSICS

    Directory of Open Access Journals (Sweden)

    Vojtech Šimon

    2013-12-01

    Full Text Available We review the lines of evidence that some cataclysmic variables (CVs are the sources of non-thermal radiation. It was really observed in some dwarf novae in outburst, a novalike CV in the high state, an intermediate polar, polars, and classical novae (CNe during outburst. The detection of this radiation suggests the presence of highly energetic particles in these CVs. The conditions for the observability of this emission depend on the state of activity, and the system parameters. We review the processes and conditions that lead to the production of this radiation in various spectral bands, from gamma-rays including TeV emission to radio. Synchrotron and cyclotron emissions suggest the presence of strong magnetic fields in CV. In some CVs, e.g. during some dwarf nova outbursts, the magnetic field generated in the accretion disk leads to the synchrotron jets radiating in radio. The propeller effect or a shock in the case of the magnetized white dwarf (WD can lead to a strong acceleration of the particles that produce gamma-ray emission via pi0 decay; even Cherenkov radiation is possible. In addition, a gamma-ray production via pi0 decay was observed in the ejecta of an outburst of a symbiotic CN. Nuclear reactions during thermonuclear runaway in the outer layer of the WD undergoing CN outburst lead to the production of radioactive isotopes; their decay is the source of gamma-ray emission. The production of accelerated particles in CVs often has episodic character with a very small duty cycle; this makes their detection and establishing the relation of the behavior in various bands difficult.

  19. Radiometric comparison of Mars Climate Sounder and Thermal Emission spectrometer measurements

    Science.gov (United States)

    Bandfield, Joshua L.; Wolff, Michael J.; Smith, Michael D.; Schofield, John T.; McCleese, Daniel J.

    2013-07-01

    Mars Climate Sounder (MCS) nadir oriented thermal infrared and solar channel measurements are compared with Thermal Emission Spectrometer (TES) measurements across multiple Mars years. Thermal infrared measurements were compared by convolving the TES data using the MCS spectral band passes. The MCS solar channel measurements were calibrated using Compact Reconnaissance Imaging Spectrometer for Mars observations to provide the proper gain factor (3.09 × 10-3 W sr-1 m-2 μm-1). The comparisons of the datasets show that day and night surface and atmospheric temperatures are within 3 K over the course of 5 martian years, after accounting for the local time differences. Any potential interannual variations in global average temperature are masked by calibration and modeling uncertainties. Previous work attributed apparent interannual global surface and atmospheric temperature variations to major dust storm activity; however, this variation has since been attributed to a calibration error in the TES dataset that has been corrected. MCS derived Lambert albedos are slightly higher than TES measurements acquired over the same season and locations. Most of this difference can be attributed to the spectral response functions of MCS and TES. Consistent with previous work, global albedo is highly variable (˜6%) and this variability must be taken into account when determining long term global trends. Vertical aerosol distributions were also derived from the calibrated MCS visible channel limb measurements, demonstrating the utility of the MCS visible channel data for monitoring of aerosols.

  20. Impact Analysis of Air Pollutant Emission Policies on Thermal Coal Supply Chain Enterprises in China

    Directory of Open Access Journals (Sweden)

    Xiaopeng Guo

    2014-12-01

    Full Text Available Spurred by the increasingly serious air pollution problem, the Chinese government has launched a series of policies to put forward specific measures of power structure adjustment and the control objectives of air pollution and coal consumption. Other policies pointed out that the coal resources regional blockades will be broken by improving transportation networks and constructing new logistics nodes. Thermal power takes the largest part of China’s total installed power generation capacity, so these policies will undoubtedly impact thermal coal supply chain member enterprises. Based on the actual situation in China, this paper figures out how the member enterprises adjust their business decisions to satisfy the requirements of air pollution prevention and control policies by establishing system dynamic models of policy impact transfer. These dynamic analyses can help coal enterprises and thermal power enterprises do strategic environmental assessments and find directions of sustainable development. Furthermore, the policy simulated results of this paper provide the Chinese government with suggestions for policy-making to make sure that the energy conservation and emission reduction policies and sustainable energy policies can work more efficiently.

  1. Benchmark Test of Differential Emission Measure Codes and Multi-thermal Energies in Solar Active Regions

    Science.gov (United States)

    Aschwanden, Markus J.; Boerner, Paul; Caspi, Amir; McTiernan, James M.; Ryan, Daniel; Warren, Harry

    2015-10-01

    We compare the ability of 11 differential emission measure (DEM) forward-fitting and inversion methods to constrain the properties of active regions and solar flares by simulating synthetic data using the instrumental response functions of the Solar Dynamics Observatory/ Atmospheric Imaging Assembly (SDO/AIA) and EUV Variability Experiment (SDO/EVE), the Reuven Ramaty High Energy Solar Spectroscopic Imager (RHESSI), and the Geostationary Operational Environmental Satellite/ X-ray Sensor (GOES/XRS). The codes include the single-Gaussian DEM, a bi-Gaussian DEM, a fixed-Gaussian DEM, a linear spline DEM, the spatial-synthesis DEM, the Monte-Carlo Markov Chain DEM, the regularized DEM inversion, the Hinode/ X-Ray Telescope (XRT) method, a polynomial spline DEM, an EVE+GOES, and an EVE+RHESSI method. Averaging the results from all 11 DEM methods, we find the following accuracies in the inversion of physical parameters: the EM-weighted temperature Tw^{fit}/Tw^{sim}=0.9±0.1, the peak emission measure EMp^{fit}/EMp^{sim}=0.6±0.2, the total emission measure EMt^{fit}/EMt^{sim}=0.8±0.3, and the multi-thermal energies E_{th}^{fit}/EM_{th}^{approx}=1.2±0.4. We find that the AIA spatial-synthesis, the EVE+GOES, and the EVE+RHESSI method yield the most accurate results.

  2. Determining mineralogical variations of aeolian deposits using thermal infrared emissivity and linear deconvolution methods

    Science.gov (United States)

    Hubbard, Bernard E.; Hooper, Donald M.; Solano, Federico; Mars, John C.

    2018-01-01

    We apply linear deconvolution methods to derive mineral and glass proportions for eight field sample training sites at seven dune fields: (1) Algodones, California; (2) Big Dune, Nevada; (3) Bruneau, Idaho; (4) Great Kobuk Sand Dunes, Alaska; (5) Great Sand Dunes National Park and Preserve, Colorado; (6) Sunset Crater, Arizona; and (7) White Sands National Monument, New Mexico. These dune fields were chosen because they represent a wide range of mineral grain mixtures and allow us to gauge a better understanding of both compositional and sorting effects within terrestrial and extraterrestrial dune systems. We also use actual ASTER TIR emissivity imagery to map the spatial distribution of these minerals throughout the seven dune fields and evaluate the effects of degraded spectral resolution on the accuracy of mineral abundances retrieved. Our results show that hyperspectral data convolutions of our laboratory emissivity spectra outperformed multispectral data convolutions of the same data with respect to the mineral, glass and lithic abundances derived. Both the number and wavelength position of spectral bands greatly impacts the accuracy of linear deconvolution retrieval of feldspar proportions (e.g. K-feldspar vs. plagioclase) especially, as well as the detection of certain mafic and carbonate minerals. In particular, ASTER mapping results show that several of the dune sites display patterns such that less dense minerals typically have higher abundances near the center of the active and most evolved dunes in the field, while more dense minerals and glasses appear to be more abundant along the margins of the active dune fields.

  3. Gamma-Ray Emission Spectra as a Constraint on Calculations of 234,236,238U Neutron-Capture Cross Sections

    Energy Technology Data Exchange (ETDEWEB)

    Ullmann, John Leonard [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Kawano, Toshihiko [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Bredeweg, Todd Allen [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Baramsai, Bayarbadrakh [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Couture, Aaron Joseph [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Haight, Robert Cameron [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Jandel, Marian [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Mosby, Shea Morgan [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); O' Donnell, John M. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Rundberg, Robert S. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Vieira, David J. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Wilhelmy, Jerry B. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Becker, John A. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Wu, Ching-Yen [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Krticka, Milan [Charles Univ., Prague (Czech Republic)

    2015-05-28

    Neutron capture cross sections in the “continuum” region (>≈1 keV) and gamma-emission spectra are of importance to basic science and many applied fields. Careful measurements have been made on most common stable nuclides, but physicists must rely on calculations (or “surrogate” reactions) for rare or unstable nuclides. Calculations must be benchmarked against measurements (cross sections, gamma-ray spectra, and <Γγ>). Gamma-ray spectrum measurements from resolved resonances were made with 1 - 2 mg/cm2 thick targets; cross sections at >1 keV were measured using thicker targets. The results show that the shape of capture cross section vs neutron energy is not sensitive to the form of the strength function (although the magnitude is); the generalized Lorentzian E1 strength function is not sufficient to describe the shape of observed gamma-ray spectra; MGLO + “Oslo M1” parameters produces quantitative agreement with the measured 238U(n,γ) cross section; additional strength at low energies (~ 3 MeV) -- likely M1-- is required; and careful study of complementary results on low-lying giant resonance strength is needed to consistently describe observations.

  4. A Restricted Open Configuration Interaction with Singles Method To Calculate Valence-to-Core Resonant X-ray Emission Spectra: A Case Study

    Science.gov (United States)

    2017-01-01

    In this work, a new protocol for the calculation of valence-to-core resonant X-ray emission (VtC RXES) spectra is introduced. The approach is based on the previously developed restricted open configuration interaction with singles (ROCIS) method and its parametrized version, based on a ground-state Kohn–Sham determinant (DFT/ROCIS) method. The ROCIS approach has the following features: (1) In the first step approximation, many-particle eigenstates are calculated in which the total spin is retained as a good quantum number. (2) The ground state with total spin S and excited states with spin S′ = S, S ± 1, are obtained. (3) These states have a qualitatively correct multiplet structure. (4) Quasi-degenerate perturbation theory is used to treat the spin–orbit coupling operator variationally at the many-particle level. (5) Transition moments are obtained between the relativistic many-particle states. The method has shown great potential in the field of X-ray spectroscopy, in particular in the field of transition-metal L-edge, which cannot be described correctly with particle–hole theories. In this work, the method is extended to the calculation of resonant VtC RXES [alternatively referred to as 1s-VtC resonant inelastic X-ray scattering (RIXS)] spectra. The complete Kramers–Dirac–Heisenerg equation is taken into account. Thus, state interference effects are treated naturally within this protocol. As a first application of this protocol, a computational study on the previously reported VtC RXES plane on a molecular managanese(V) complex is performed. Starting from conventional X-ray absorption spectra (XAS), we present a systematic study that involves calculations and electronic structure analysis of both the XAS and non-resonant and resonant VtC XES spectra. The very good agreement between theory and experiment, observed in all cases, allows us to unravel the complicated intensity mechanism of these spectroscopic techniques as a synergic function of state

  5. Detailed analysis of hollow ions spectra from dense matter pumped by X-ray emission of relativistic laser plasma

    Energy Technology Data Exchange (ETDEWEB)

    Hansen, S. B., E-mail: sbhanse@sandia.gov, E-mail: anatolyf@hotmail.com [Sandia National Laboratories, Albuquerque, New Mexico 87123 (United States); Colgan, J.; Abdallah, J. [Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Faenov, A. Ya., E-mail: sbhanse@sandia.gov, E-mail: anatolyf@hotmail.com [Joint Institute for High Temperatures, Russian Academy of Sciences, Moscow 125412 (Russian Federation); Quantum Beam Science Directorate, Japan Atomic Energy Agency, Kyoto 619-0215 (Japan); Pikuz, S. A.; Skobelev, I. Yu. [Joint Institute for High Temperatures, Russian Academy of Sciences, Moscow 125412 (Russian Federation); Wagenaars, E.; Culfa, O.; Dance, R. J.; Tallents, G. J.; Rossall, A. K.; Woolsey, N. C. [York Plasma Institute, Department of Physics, University of York, York YO10 5DD (United Kingdom); Booth, N.; Lancaster, K. L. [Central Laser Facility, STFC Rutherford Appleton Laboratory, Didcot OX11 0QX (United Kingdom); Evans, R. G. [Department of Physics, Imperial College, London SW7 2AZ (United Kingdom); Gray, R. J.; McKenna, P. [SUPA, Department of Physics, University of Strathclyde, Glasgow G4 ONG (United Kingdom); Kaempfer, T.; Schulze, K. S. [Helmholtzinstitut Jena, Jena D-07743 (Germany); Uschmann, I. [Helmholtzinstitut Jena, Jena D-07743 (Germany); Institut für Optik und Quantenelektronic, Friedrich-Schiller-Universität Jena, Max-Wien Platz 1, Jena, D-07743 (Germany); and others

    2014-03-15

    X-ray emission from hollow ions offers new diagnostic opportunities for dense, strongly coupled plasma. We present extended modeling of the x-ray emission spectrum reported by Colgan et al. [Phys. Rev. Lett. 110, 125001 (2013)] based on two collisional-radiative codes: the hybrid-structure Spectroscopic Collisional-Radiative Atomic Model (SCRAM) and the mixed-unresolved transition arrays (MUTA) ATOMIC model. We show that both accuracy and completeness in the modeled energy level structure are critical for reliable diagnostics, investigate how emission changes with different treatments of ionization potential depression, and discuss two approaches to handling the extensive structure required for hollow-ion models with many multiply excited configurations.

  6. A Blind Search for Lyα Emission from Galaxies at z = 6-8 with Deep HST Grism Spectra

    Science.gov (United States)

    Larson, Rebecca L.; Finkelstein, Steven L.; Pirzkal, Norbert; Tilvi, Vithal; Jung, Intae; Malhotra, Sangeeta; Rhoads, James E.

    2017-06-01

    This project aims to detect Lyα emission lines from z = 6-8 galaxies spectroscopically confirm the redshifts of a large sample of galaxies and to probe the ionization state of the intergalactic medium (IGM) during the epoch of reionization. We use extremely deep data from the Faint Infrared Grism Survey (FIGS; PI: Malhotra) which is currently the most sensitive G102 grism survey, targeting the high-redshift galaxies that were discovered in the CANDELS GOODS fields (Finkelstein et al. 2015). This data set has already proven to be successful as one of these candidates, at redshift z=7.51, has been observed to have Lyα emission detectable with the HST Grism (Tilvi et al 2016). The FIGS data uses five separate roll-angles of HST in an effort to reduce the overall contamination effects of nearby galaxies. We have created a method that accounts for and removes the contamination from surrounding galaxies, and also removes any residual continuum emission from each individual spectrum. We then utilize a MCMC routine to blindly search for significant emission lines using three different methods. First, we compare the results for each galaxy across all roll angles and identify significant lines as those which are detected at the same wavelength in more than one roll angle. Second, we perform a weighted stack of all five roll angles and then search this spectrum for emission lines. Third, we perform a fit to all five roll angles simultaneously. We have found several z >7 candidates using individual methods which, if confirmed, will increase the number of confirmed galaxies at this epoch by ~50%. We have also detected an emission line at 1.03μm in one galaxy using all three of these methods and are comparing these results with broadband photometry measures. We have proposed for ground-based follow-up observations of this, and several other potential Lyα-emitting galaxies in our sample.

  7. The ground-based H, K, and L-band absolute emission spectra of HD 209458b

    OpenAIRE

    Zellem, Robert T.; Griffith, Caitlin A.; Deroo, Pieter; Swain, Mark R.; Waldmann, Ingo P.

    2014-01-01

    Here we explore the capabilities of NASA's 3.0 meter Infrared Telescope Facility (IRTF) and SpeX spectrometer and the 5.08 meter Hale telescope with the TripleSpec spectrometer with near-infrared H, K, and L-band measurements of HD 209458b's secondary eclipse. Our IRTF/SpeX data are the first absolute L-band spectroscopic emission measurements of any exoplanet other than the hot Jupiter HD 189733b. Previous measurements of HD 189733b's L-band indicate bright emission hypothesized to result fr...

  8. Thermal and Non-thermal Nature of the Soft Excess Emission from Sersic 159-03 observed with XMM-Newton

    Science.gov (United States)

    Bonamente, Massimiliano; Lieu, Richard; Mittaz, Jonathan P. D.; Kaastra, Jelle S.; Nevalainen, Jukka

    2005-01-01

    Several nearby clusters exhibit an excess of soft X-ray radiation which cannot be attributed to the hot virialized intra-cluster medium. There is no consensus to date on the origin of the excess emission: it could be either of thermal origin, or due to an inverse Compton scattering of the cosmic microwave background. Using high resolution XMM-Newton data of Sersic 159-03 we first show that strong soft excess emission is detected out to a radial distance of 0.9 Mpc. The data are interpreted using the two viable models available, i.e., by invoking a warm reservoir of thermal gas, or relativistic electrons which are part of a cosmic ray population. The thermal model leads to a better goodness-of-fit, and the emitting warm gas must be high in mass and low in metallicity.

  9. Thermal Emission of Alkali Metal Ions from Al30-Pillared Montmorillonite Studied by Mass Spectrometric Method.

    Science.gov (United States)

    Motalov, V B; Karasev, N S; Ovchinnikov, N L; Butman, M F

    2017-01-01

    The thermal emission of alkali metal ions from Al 30 -pillared montmorillonite in comparison with its natural form was studied by mass spectrometry in the temperature range 770-930 K. The measurements were carried out on a magnetic mass spectrometer MI-1201. For natural montmorillonite, the densities of the emission currents ( j ) decrease in the mass spectrum in the following sequence (T = 805 K, A/cm 2 ): K + (4.55 · 10 -14 ), Cs + (9.72 · 10 -15 ), Rb + (1.13 · 10 -15 ), Na + (1.75 · 10 -16 ), Li + (3.37 · 10 -17 ). For Al 30 -pillared montmorillonite, thermionic emission undergoes temperature-time changes. In the low-temperature section of the investigated range (770-805 K), the value of j increases substantially for all ions in comparison with natural montmorillonite (T = 805 K, A/cm 2 ): Cs + (6.47 · 10 -13 ), K + (9.44 · 10 -14 ), Na + (3.34 · 10 -15 ), Rb + (1.77 · 10 -15 ), and Li + (4.59 · 10 -16 ). A reversible anomaly is observed in the temperature range 805-832 K: with increasing temperature, the value of j of alkaline ions falls abruptly. This effect increases with increasing ionic radius of M + . After a long heating-up period, this anomaly disappears and the ln j - 1/ T dependence acquires a classical linear form. The results are interpreted from the point of view of the dependence of the efficiency of thermionic emission on the phase transformations of pillars.

  10. c2d Spitzer IRS spectra of embedded low-mass young stars : gas-phase emission lines

    NARCIS (Netherlands)

    Lahuis, F.; van Dishoeck, E. F.; Jorgensen, J. K.; Blake, G. A.; Evans, N. J.

    Context. A survey of mid-infrared gas-phase emission lines of H(2), H(2)O and various atoms toward a sample of 43 embedded low-mass young stars in nearby star-forming regions is presented. The sources are selected from the Spitzer "Cores to Disks" (c2d) legacy program. Aims. The environment of

  11. Correcting atmospheric effects in thermal ground observations for hyperspectral emissivity estimation

    Science.gov (United States)

    Timmermans, Joris; Buitrago, Maria

    2014-05-01

    Knowledge of Land surface temperature is of crucial importance in energy balance studies and environmental modeling. Accurate retrieval of land surface temperature (LST) demands detailed knowledge of the land surface emissivity. Measured radiation by remote sensing sensors to land surface temperature can only be performed using a-priori knowledge of the emissivity. Uncertainties in the retrieval of this emissivity can cause huge errors in LST estimations. The retrieval of emissivity (and LST) is per definition an underdetermined inversion, as only one observation is made while two variables are to be estimated. Several researches have therefore been performed on measuring emissivity, such as the normalized emissivity method, the temperature-emissivity separation (TES) using the minimum and maximum difference of emissivity and the use of vegetation indices. In each of these approaches atmospherically corrected radiance measurements by remote sensing sensors are correlated to ground measurements. Usually these ground measurements are performed with the ground equivalent of the remote sensing sensors; the CIMEL 312-2 has the same spectral bands as ASTER. This way parameterizations acquired this way are only usable for specific sensors and need to be redone for newer sensors. Recently hyperspectral thermal radiometers, such as the MIDAC, have been developed that can solve this problem. By using hyperspectral observations of emissivity, together with sensor simulators, ground measurements of different satellite sensor can be simulated. This facilitates the production of validation data for the different TES algorithms. However before such measurements can be performed extra steps of processing need to be performed. Atmospheric correction becomes more important in hyperspectral observations than for broadband observations, as energy levels measured per band is lower. As such the atmosphere has a relative larger contribution if bandwidths become smaller. The goal of this

  12. Increase in NOx emissions from thermal power plants in India: bottom-up inventories and satellite observations

    Science.gov (United States)

    Lu, Z.; Streets, D. G.

    2012-12-01

    Driven by rapid economic development and growing electricity demand, NOx emissions (E) from the power sector in India have increased dramatically since the mid-1990s. In this study, we present the NOx emissions from Indian public thermal power plants for the period 1996-2010 using a unit-based methodology and compare the emission estimates with the satellite observations of NO2 tropospheric vertical column densities (TVCDs) from four spaceborne instruments: GOME, SCIAMACHY, OMI, and GOME-2. Results show that NOx emissions from Indian power plants increased by at least 70% during 1996-2010. Coal-fired power plants, NOx emissions from which are not regulated in India, contribute ~96% to the total power sector emissions. A number of isolated NO2 hot spots are observed over the power plant areas, and good agreement between NO2 TVCDs and NOx emissions is found for areas dominated by power plant emissions. Average NO2 TVCDs over power plant areas were continuously increasing during the study period. We find that the ratio of ΔE/E to ΔTVCD/TVCD changed from greater than one to less than one around 2005-2008, implying that a transition of the overall NOx chemistry occurred over the power plant areas, which may cause significant impact on the atmospheric environment.ariations of NOx emissions from thermal power plants and NO2 TVCD over power plant areas for 4 NO2 instruments during 1996-2010 patial distribution of NOx emissions from thermal power plants and OMI NO2 TVCDs over India during 2005-2010

  13. Modelling the thermal X-ray emission around the Galactic centre from colliding Wolf-Rayet winds

    Science.gov (United States)

    Russell, Christopher M. P.; Wang, Q. Daniel; Cuadra, Jorge

    2017-11-01

    We compute the thermal X-ray emission from hydrodynamic simulations of the 30 Wolf-Rayet (WR) stars orbiting within a parsec of Sgr A*, with the aim of interpreting the Chandra X-ray observations of this region. The model well reproduces the spectral shape of the observations, indicating that the shocked WR winds are the dominant source of this thermal emission. The model X-ray flux is tied to the strength of the Sgr A* outflow, which clears out hot gas from the vicinity of Sgr A*. A moderate outflow best fits the present-day observations, even though this supermassive black hole (SMBH) outflow ended ~100 yr ago.

  14. Measurement of CO 2, CO, SO 2, and NO emissions from coal-based thermal power plants in India

    Science.gov (United States)

    Chakraborty, N.; Mukherjee, I.; Santra, A. K.; Chowdhury, S.; Chakraborty, S.; Bhattacharya, S.; Mitra, A. P.; Sharma, C.

    Measurements of CO 2 (direct GHG) and CO, SO 2, NO (indirect GHGs) were conducted on-line at some of the coal-based thermal power plants in India. The objective of the study was three-fold: to quantify the measured emissions in terms of emission coefficient per kg of coal and per kWh of electricity, to calculate the total possible emission from Indian thermal power plants, and subsequently to compare them with some previous studies. Instrument IMR 2800P Flue Gas Analyzer was used on-line to measure the emission rates of CO 2, CO, SO 2, and NO at 11 numbers of generating units of different ratings. Certain quality assurance (QA) and quality control (QC) techniques were also adopted to gather the data so as to avoid any ambiguity in subsequent data interpretation. For the betterment of data interpretation, the requisite statistical parameters (standard deviation and arithmetic mean) for the measured emissions have been also calculated. The emission coefficients determined for CO 2, CO, SO 2, and NO have been compared with their corresponding values as obtained in the studies conducted by other groups. The total emissions of CO 2, CO, SO 2, and NO calculated on the basis of the emission coefficients for the year 2003-2004 have been found to be 465.667, 1.583, 4.058, and 1.129 Tg, respectively.

  15. The NuSTAR view of the non-thermal emission from PSR J0437-4715

    DEFF Research Database (Denmark)

    Guillot, S.; Kaspi, V M; Archibald, Robert F.

    2016-01-01

    STAR background dominates. We measure a photon index Gamma = 1.50 +/- 0.25 (90 per cent confidence) for the power-law fit to the non-thermal emission. It had been shown that spectral models with two or three thermal components fit the XMM-Newton spectrum of PSR J0437-4715, depending on the slope of the power-law...... component, and the amount of absorption of soft X-rays. The new constraint on the high-energy emission provided by NuSTAR removes ambiguities regarding the thermal components of the emission below 3 keV. We performed a simultaneous spectral analysis of the XMM-Newton and NuSTAR data to confirm that three...... thermal components and a power law are required to fit the 0.3-20 keV emission of PSR J0437-4715. Adding a ROSAT-PSPC spectrum further confirmed this result and allowed us to better constrain the temperatures of the three thermal components. A phase-resolved analysis of the NuSTAR data revealed...

  16. Thermally enhanced field emission from a laser-illuminated tungsten tip: temperature rise of tip

    Energy Technology Data Exchange (ETDEWEB)

    Lee, M.J.G.; Reifenberger, R.; Robins, E.S.; Lindenmayr, H.G.

    1980-09-01

    Thermal field emission of electrons has been investigated from a tungsten field emitter illuminated by the focused beam of a laser operating at a range of wavelengths in the visible region of the spectrum. The temperature rise of the tip is determined as a function of the displacement of the focused spot of light along the shank, and of its polarization. The experimental data are compared with the results of a first-principle calculation of the temperature rise, based on an experimental investigation of the intensity distribution within the focused spot of light and of the geometry of the field emitter. The comparison shows that when the laser beam is focused close to the tip the temperature rise is anomalously large; evidence is presented which suggests that the temperature rise of the tip is substantially enhanced by diffraction effects.

  17. Detection of crystalline hematite mineralization on Mars by the Thermal Emission Spectrometer: evidence for near-surface water

    Science.gov (United States)

    Christensen, P.R.; Bandfield, J.L.; Clark, R.N.; Edgett, K.S.; Hamilton, V.E.; Hoefen, T.; Kieffer, H.H.; Kuzmin, R.O.; Lane, M.D.; Malin, M.C.; Morris, R.V.; Pearl, J.C.; Pearson, R.; Roush, T.L.; Ruff, S.W.; Smith, M.D.

    2000-01-01

    The Thermal Emission Spectrometer (TES) instrument on the Mars Global Surveyor (MGS) mission has discovered a remarkable accumulation of crystalline hematite (α-Fe2O3) that covers an area with very sharp boundaries approximately 350 by 350–750 km in size centered near 2°S latitude between 0° and 5°W longitude (Sinus Meridiani). Crystalline hematite is uniquely identified by the presence of fundamental vibrational absorption features centered near 300, 450, and >525 cm−1 and by the absence of silicate fundamentals in the 1000 cm−1 region. Spectral features resulting from atmospheric CO2, dust, and water ice were removed using a radiative transfer model. The spectral properties unique to Sinus Meridiani were emphasized by removing the average spectrum of the surrounding region. The depth and shape of the hematite fundamental bands show that the hematite is crystalline and relatively coarse grained (>5–10 μm). Diameters up to and greater than hundreds of micrometers are permitted within the instrumental noise and natural variability of hematite spectra. Hematite particles 30 μm diameter) to 40–60% (10 μm diameter). The hematite in Sinus Meridiani is thus distinct from the fine-grained (diameter oxide iron formations), (2) precipitation from Fe-rich hydrothermal fluids, (3) low-temperature dissolution and precipitation through mobile ground water leaching, and (4) formation of surface coatings, and the second is thermal oxidation of magnetite-rich lavas. Weathering and alteration processes, which produce nanophase and red hematite, are not consistent with the coarse, crystalline hematite observed in Sinus Meridiani. We prefer chemical precipitation models and favor precipitation from Fe-rich water on the basis of the probable association with sedimentary materials, large geographic size, distance from a regional heat source, and lack of evidence for extensive groundwater processes elsewhere on Mars. The TES results thus provide mineralogic evidence for

  18. The ultraviolet continuous and emission-line spectra of the Herbig-Haro objects HH 2 and HH 1

    Science.gov (United States)

    Boehm-Vitense, E.; Cardelli, J. A.; Nemec, J. M.; Boehm, K. H.

    1982-01-01

    Recent studies of the continuous spectrum of Herbig-Haro (HH) objects at optical and near-infrared wavelengths and the observation of continuous radiation in the ultraviolet have shown an unexpectedly steep increase of the flux toward shorter wavelengths. The present investigation provides the results of ultraviolet observations of HH 2. The obtained data are compared with the HH 1 data. It is found that HH 2 has an ultraviolet continuous and emission-line spectrum which is similar to that of HH 1. The UV line spectrum of HH 2H indicates an even somewhat larger ionization than does the HH 1 spectrum. As in HH1, the UV emission-line spectrum shows a much higher degree of ionization than that derived from the optical spectrum. Consequently, the same difficulty arises as in the case of HH 1. The complete UV plus optical spectrum cannot be explained by a single plane-parallel shock-wave model.

  19. Emission spectra of a pulse needle-to-plane corona-like discharge in conductive aqueous solution

    Czech Academy of Sciences Publication Activity Database

    Šimek, Milan; Člupek, Martin; Babický, Václav; Lukeš, Petr; Šunka, Pavel

    2012-01-01

    Roč. 21, č. 5 (2012), 055031-055031 ISSN 0963-0252 R&D Projects: GA AV ČR IAAX00430802 Institutional research plan: CEZ:AV0Z20430508 Keywords : Water * pulsed electrical breakdown * point-plane geometry * streamer propagation * corona discharge * emission spectroscopy Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 2.515, year: 2012 http://iopscience.iop.org/0963-0252/21/5/055031/pdf/0963-0252_21_5_055031.pdf

  20. The ground-based H-, K-, and L-band absolute emission spectra of HD 209458b

    Energy Technology Data Exchange (ETDEWEB)

    Zellem, Robert T.; Griffith, Caitlin A. [Lunar and Planetary Laboratory, University of Arizona, 1629 East University Boulevard, Tucson, AZ 85721 (United States); Deroo, Pieter; Swain, Mark R. [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109 (United States); Waldmann, Ingo P., E-mail: rzellem@lpl.arizona.edu [University College London, Department of Physics and Astronomy, Gower Street, London WC1E 6BT (United Kingdom)

    2014-11-20

    Here we explore the capabilities of NASA's 3.0 m Infrared Telescope Facility (IRTF) and SpeX spectrometer and the 5.08 m Hale telescope with the TripleSpec spectrometer with near-infrared H-, K-, and L-band measurements of HD 209458b's secondary eclipse. Our IRTF/SpeX data are the first absolute L-band spectroscopic emission measurements of any exoplanet other than the hot Jupiter HD 189733b. Previous measurements of HD 189733b's L band indicate bright emission hypothesized to result from non-LTE CH{sub 4} ν{sub 3} fluorescence. We do not detect a similar bright 3.3 μm feature to ∼3σ, suggesting that fluorescence does not need to be invoked to explain HD 209458b's L-band measurements. The validity of our observation and reduction techniques, which decrease the flux variance by up to 2.8 orders of magnitude, is reinforced by 1σ agreement with existent Hubble/NICMOS and Spitzer/IRAC1 observations that overlap the H, K, and L bands, suggesting that both IRTF/SpeX and Palomar/TripleSpec can measure an exoplanet's emission with high precision.

  1. Theoretical Time Dependent Thermal Neutron Spectra and Reaction Rates in H{sub 2}O and D{sub 2}O

    Energy Technology Data Exchange (ETDEWEB)

    Purohit, S.N.

    1966-04-15

    The early theoretical and experimental time dependent neutron thermalization studies were limited to the study of the transient spectrum in the diffusion period. The recent experimental measurements of the time dependent thermal neutron spectra and reaction rates, for a number of moderators, have generated considerable interest in the study of the time dependent Boltzmann equation. In this paper we present detailed results for the time dependent spectra and the reaction rates for resonance detectors using several scattering models of H{sub 2}O and D{sub 2}O. This study has been undertaken in order to interpret the integral time dependent neutron thermalization experiments in liquid moderators which have been performed at the AB Atomenergi. The proton gas and the deuteron gas models are inadequate to explain the measured reaction rates in H{sub 2}O and D{sub 2}O. The bound models of Nelkin for H{sub 2}O and of Butler for D{sub 2}O give much better agreement with the experimental results than the gas models. Nevertheless, some disagreement between theoretical and experimental results still persists. This study also indicates that the bound model of Butler and the effective mass 3. 6 gas model of Brown and St. John give almost identical reaction rates. It is also surprising to note that the calculated reaction rate for Cd for the Butler model appears to be in better agreement with the experimental results of D{sub 2}O than of the Nelkin model with H{sub 2}O experiments. The present reaction rate studies are sensitive enough so as to distinguish between the gas model and the bound model of a moderator. However, to investigate the details of a scattering law (such as the effect of the hindered rotations in H{sub 2}O and D{sub 2}O and the weights of different dynamical modes) with the help of these studies would require further theoretical as well as experimental investigations. Theoretical results can be further improved by improving the source for thermal neutrons, the

  2. Airborne emissions of carcinogens and respiratory sensitizers during thermal processing of plastics.

    Science.gov (United States)

    Unwin, John; Coldwell, Matthew R; Keen, Chris; McAlinden, John J

    2013-04-01

    Thermoplastics may contain a wide range of additives and free monomers, which themselves may be hazardous substances. Laboratory studies have shown that the thermal decomposition products of common plastics can include a number of carcinogens and respiratory sensitizers, but very little information exists on the airborne contaminants generated during actual industrial processing. The aim of this work was to identify airborne emissions during thermal processing of plastics in real-life, practical applications. Static air sampling was conducted at 10 industrial premises carrying out compounding or a range of processes such as extrusion, blown film manufacture, vacuum thermoforming, injection moulding, blow moulding, and hot wire cutting. Plastics being processed included polyvinyl chloride, polythene, polypropylene, polyethylene terephthalate, and acrylonitrile-butadiene-styrene. At each site, static sampling for a wide range of contaminants was carried out at locations immediately adjacent to the prominent fume-generating processes. The monitoring data indicated the presence of few carcinogens at extremely low concentrations, all less than 1% of their respective WEL (Workplace Exposure Limit). No respiratory sensitizers were detected at any sites. The low levels of process-related fume detected show that the control strategies, which employed mainly forced mechanical general ventilation and good process temperature control, were adequate to control the risks associated with exposure to process-related fume. This substantiates the advice given in the Health and Safety Executive's information sheet No 13, 'Controlling Fume During Plastics Processing', and its broad applicability in plastics processing in general.

  3. A case study of HF radar spectra and 630.0 nm auroral emission in the pre-midnight sector

    Directory of Open Access Journals (Sweden)

    M. Lester

    2001-03-01

    Full Text Available A comparison of HF radar backscatter observed by the CUTLASS Finland radar, meridian scanning photometer data from Longyearbyen, magnetic field variations from IMAGE stations, and particle precipitation measured by the DMSP F12 spacecraft is presented. The interval under discussion occurred in the pre-midnight local time sector, during a period of weakly northward interplanetary magnetic field. A region of HF backscatter, typically 8 degrees wide, occurred in the field of view of the CUTLASS Finland radar. A well defined gradient in the spectral width parameter was present, with mainly low (< 200 m s - 1 spectral widths in the lower latitude part of the scatter and predominantly large (> 200 ms - 1 spectral widths in the higher latitude part. The relationship between the spectral width and the red line (630.0 nm emission measured by the meridian scanning photometer is considered. The poleward border of the red line emission, which has, in the past, been proposed as being representative of the polar cap boundary, was co-located to within 1° of magnetic latitude with the gradient in spectral width for part of the interval. Statistically, large spectral widths occurred poleward of the red line emission, while small spectral widths occurred within or equatorward of the red line emission. Near simultaneous DMSP particle observations in the 20 eV to 20 keV range indicate that the poleward border of the red line emission and the gradient in spectral width occurred at the same latitude as the transition from auroral oval to polar rain particle energies. We conclude that the large spectral widths were not caused by particle precipitation associated with the auroral oval. There were two periods of special interest when the relationship between the red line and the spectral width broke down. The first of these happened during enhanced red line and green line (557.7 nm emission, with a drop out of the radar scatter and an enhanced, narrow westward

  4. Further Constraints on Thermal Quiescent X-Ray Emission from SAX J1808.4-3658

    Science.gov (United States)

    Heinke, C. O.; Jonker, P. G.; Wijnands, R.; Deloye, C. J.; Taam, R. E.

    2009-02-01

    We observed SAX J1808.4-3658 (1808), the first accreting millisecond pulsar, in deep quiescence with XMM-Newton and (near simultaneously) Gemini-South. The X-ray spectrum of 1808 is similar to that observed in quiescence in 2001 and 2006, describable by an absorbed power law with photon index 1.74 ± 0.11 and unabsorbed X-ray luminosity LX = 7.9 ± 0.7 × 1031 ergs s-1, for NH = 1.3 × 1021 cm-2. Fitting all the quiescent XMM-Newton X-ray spectra with a power law, we constrain any thermally emitting neutron star (NS) with a hydrogen atmosphere to have a temperature less than 30 eV and L NS (0.01-10 keV) history or initial NS mass in these otherwise similar systems. Based on observations obtained with XMM-Newton, an ESA science mission with instruments and contributions directly funded by ESA Member States and NASA.

  5. PARAFAC modeling of fluorescence excitation-emission spectra of fish bile for rapid en route screening of PAC exposure.

    Science.gov (United States)

    Christensen, Jan H; Tomasi, Giorgio; Strand, Jakob; Andersen, Ole

    2009-06-15

    Polycyclic aromatic compound (PAC) metabolites in fish bile can be used as biomarkers for recent environmental exposure to PACs. Here, a novel method for rapid screening of nonhydrolyzed fish bile is presented. The method is based on excitation-emission fluorescence spectroscopy combined with parallel factor analysis (PARAFAC) and may constitute an alternative to fixed wavelength fluorescence and synchronous fluorescence spectroscopy (SFS). PARAFAC was applied to excitation-emission matrices (EEMs) of bile samples of shorthorn sculpins and European eels collected in Greenland and Denmark. The EEMs were decomposed into a four-factor PARAFAC model. The comparison of the PARAFAC factors with the EEMs of PAC metabolites and amino acids suggests that two factors are related to PAC metabolites and two correspond to fluorescent residues of tryptophan and tyrosine in bile proteins. A new standardization procedure based on the mean of the scores for the biological factors was used to correct for feeding status and sample dilution and, upon such normalization, the score plots of PARAFAC factors showed a clear distinction between exposed and nonexposed fish. A good correlation was found between the factor scores and 1-hydroxypyrene equivalents determined by SFS for high contamination levels, whereas the sensitivity was better for the EEM method.

  6. Controlling electronic couplings with tunable long wavelength pulses: Study of Autler-Townes splitting and XUV emission spectra

    Science.gov (United States)

    Harkema, Nathan; Liao, Chen-Ting; Sandhu, Arvinder

    2017-04-01

    Attosecond transient absorption spectroscopy (ATAS) enables the study of excited electron dynamics with unprecedented temporal and energy resolution. Many ATAS experiments use an extreme ultraviolet (XUV) pump pulse and a near-infrared (NIR) probe fixed at the fundamental laser frequency ( 800 nm) to study the light induced effects on electronic structure of atoms and molecules. We extend the technique by using an optical parametric amplifier in one arm of our setup, which allows us to independently tune the frequency of the probe pulse from 1200 to 1800 nm. These long-wavelength pulses allow us to explore a new regime, where we can control the couplings between nearby electronic states to alter the transient absorption lineshapes in atoms. We use this technique to investigate the 4p-3s detuning dependent Autler-Townes splitting of the 4p state in Helium. Light induced Floquet structures extending into the continuum are observed in our study. We demonstrate new tunable XUV emission channels from four-wave mixing processes, and the efficiency of these emissions can be strongly enhanced through resonant couplings. The tunable IR induced electronic couplings are also used to influence the autoionization dynamics in Argon. This work is supported by NSF Grant No. PHY-1505556 and ARO Grant No. W911NF-14-1-0383.

  7. Thermal components in the early X-ray afterglows of GRBs: likely cocoon emission and constraints on the progenitors

    Science.gov (United States)

    Valan, Vlasta; Larsson, Josefin; Ahlgren, Björn

    2018-02-01

    The early X-ray afterglows of gamma-ray bursts (GRBs) are usually well described by absorbed power laws. However, in some cases, additional thermal components have been identified. The origin of this emission is debated, with proposed explanations including supernova shock breakout, emission from a cocoon surrounding the jet, as well as emission from the jet itself. A larger sample of detections is needed in order to place constraints on these different models. Here, we present a time-resolved spectral analysis of 74 GRBs observed by Swift X-ray Telescope in a search for thermal components. We report six detections in our sample, and also confirm an additional three cases that were previously reported in the literature. The majority of these bursts have a narrow range of blackbody radii around ˜2 × 1012 cm, despite having a large range of luminosities (Lpeak ˜ 1047-1051 erg s-1). This points to an origin connected to the progenitor stars, and we suggest that emission from a cocoon breaking out from a thick wind may explain the observations. For two of the bursts in the sample, an explanation in terms of late prompt emission from the jet is instead more likely. We also find that these thermal components are preferentially detected when the X-ray luminosity is low, which suggests that they may be hidden by bright afterglows in the majority of GRBs.

  8. The use of IR, magnetism, reflectance, and mass spectra together with thermal analyses in structure investigation of codeine phosphate complexes of d-block elements

    Science.gov (United States)

    Zayed, M. A.; El-shahat, M. F.; Abdullah, S. M.

    2005-06-01

    Codeine is an analgesic with uses similar to morphines, but it is of much less effect, i.e., it had a mild sedative effect; codeine is usually used as the phosphate form (Cod.P) and is often administrated by mouth with aspirin of paracetamol. Due to its serious use, if it is in large dose, attention is paid in this research to the synthesis and stereochemistry of new iron, cobalt, nickel, copper, and zinc complexes of this drug in both solution and the solid states. The spectra of these complexes in solution and the study of their stoichiometry refer to the formation of 1:1 ratio of metal (M) to ligand (L). The steriochemical structures of the solid complexes were studied on the basis of their analytical, spectroscopic, magnetic, and thermal data. Infrared spectra proved the presence of M sbnd O bonds. Magnetic susceptibility and solid reflectance spectral measurements were used to infer the structures. The prepared complexes were found to have the general formulae [ML(OH) x(H 2O) y](H 2O) zH 3PO 4, M: Co(II), Ni(II), and Cu(II), x = 1, y = 0, z = 0; M: Fe(II), x = 1, y = 2, z = 1; Fe(III), x = 2, y = 1, z = 0; Co(III), x = 0, y = 2, z = 1; Zn(II), x = 1, y = 0, z = 3; and L: (Cod.P) of the general formula C 18H 24NO 7P (anhydrate). Octahedral, tetrahedral, and square planer structures were proposed for these complexes depending upon the magnetic and reflectance data and were confirmed by detailed mass and thermal analyses comparative studies.

  9. An Optimization Scheduling Model for Wind Power and Thermal Power with Energy Storage System considering Carbon Emission Trading

    Directory of Open Access Journals (Sweden)

    Huan-huan Li

    2015-01-01

    Full Text Available Wind power has the characteristics of randomness and intermittence, which influences power system safety and stable operation. To alleviate the effect of wind power grid connection and improve power system’s wind power consumptive capability, this paper took emission trading and energy storage system into consideration and built an optimization model for thermal-wind power system and energy storage systems collaborative scheduling. A simulation based on 10 thermal units and wind farms with 2800 MW installed capacity verified the correctness of the models put forward by this paper. According to the simulation results, the introduction of carbon emission trading can improve wind power consumptive capability and cut down the average coal consumption per unit of power. The introduction of energy storage system can smooth wind power output curve and suppress power fluctuations. The optimization effects achieve the best when both of carbon emission trading and energy storage system work at the same time.

  10. PARAFAC modeling of fluorescence excitation - Emission spectra of fish bile for rapid en route screening of PAC exposure

    DEFF Research Database (Denmark)

    Christensen, Jan H.; Tomasi, Giorgio; Strand, Jakob

    2009-01-01

    . The EEMs were decomposed into a four-factor PARAFAC model. The comparison of the PARAFAC factors with the EEMs of PAC metabolites and amino acids suggests that two factors are related to PAC metabolites and two correspond to fluorescent residues of tryptophan and tyrosine in bile proteins. A new......Polycyclic aromatic compound (PAC) metabolites in fish bile can be used as biomarkers for recent environmental exposure to PACs. Here, a novel method for rapid screening of nonhydrolyzed fish bile is presented. The method is based on excitation-emission fluorescence spectroscopy combined...... standardization procedure based on the mean of the scores for the biological factors was used to correct for feeding status and sample dilution and, upon such normalization, the score plots of PARAFAC factors showed a clear distinction between exposed and nonexposed fish. A good correlation was found between...

  11. The NuSTAR View of the Non-Thermal Emission from PSR J0437-4715

    Science.gov (United States)

    Guillot, S.; Kaspi, V. M.; Archibald, R. F.; Bachetti, M.; Flynn, C.; Jankowski, F.; Bailes, M.; Boggs, S.; Christensen, F. E.; Craig, W. W.; hide 12px; height:12px; display:none; " src="images/arrow-down.gif" width="12" height="12" border="0" alt="hide" id="author_20170009872_hide">

    2016-01-01

    We present a hard X-ray Nuclear Spectroscopic Telescope Array (NuSTAR) observation of PSR J0437-4715, the nearest millisecond pulsar. The known pulsations at the apparent pulse period approximately 5.76 ms are observed with a significance of 3.7sigma, at energies up to 20 keV above which the NuSTAR background dominates. We measure a photon index gamma = 1.50 +/- 0.25(90 per cent confidence) for the power-law fit to the non-thermal emission. It had been shown that spectral models with two or three thermal components fit the XMM-Newton spectrum of PSR J0437-4715, depending on the slope of the power-law component, and the amount of absorption of soft X-rays. The new constraint on the high-energy emission provided by NuSTAR removes ambiguities regarding the thermal components of the emission below 3 keV. We performed a simultaneous spectral analysis of the XMM-Newton and NuSTAR data to confirm that three thermal components and a power law are required to fit the 0.3-20 keV emission of PSR J0437-4715. Adding a ROSAT-PSPC spectrum further confirmed this result and allowed us to better constrain the temperatures of the three thermal components. A phase resolved analysis of the NuSTAR data revealed no significant change in the photon index of the high-energy emission. This NuSTAR observation provides further impetus for future observations with the NICER mission (Neutron Star Interior Composition Explorer) whose sensitivity will provide much stricter constraints on the equation of state of nuclear matter by combining model fits to the pulsars phase-folded light curve with the pulsars well-defined mass and distance from radio timing observations.

  12. Effect of Pressure Broadening on Emission and Transmission Spectra of H2O Modeled for sub-Neptune/super-Earth exoplanets: An Application to JWST

    Science.gov (United States)

    Gharib Nezhad, Ehsan; Line, Michael R.; Lyons, James R.

    2017-10-01

    Water is the most readily detected molecule over a diverse range of exoplanet properties (solar composition hot-Jupiters to high metallicity super-earths/neptunes). It is also one of the most important sources of opacity that govern radiative energy balance. It is well known that pressure/collisional broadening significantly influences the opacity of a given molecule. Laboratory spectroscopic studies have shown that the line-broadening (i.e. Doppler, Lorentzian) is influence by several factors including temperature, pressure, dipole moment of the broadeners (or bath gases), and the rotational quantum numbers. Since absorption cross-sections (or opacities) are central to both atmospheric modeling and observational research, there is a critical need to investigate the effect of pressure line-broadening on the absorption cross-sections and subsequent influence on observed transmission and emission spectra of transiting exoplanets. Typical data-model comparisons (either forward modeling or retrieval's) generally rely upon pre-computed grids of absorption cross-sections that assume trace molecules are broadened by a solar composition mixture (e.g., mainly H2 and He as a bath gas). However, as the metallicity of a planetary atmosphere increases, as anticipated for smaller planets in the sub-Neptune-Super Earth range, broadening due to other gases (e.g., N2, CO2, H2O, CH4, CO) can become significant and the H2-He broadening is no longer appropriate. In this work, we assess the influence of different background broadeners on the absorption cross-section of water, and subsequent influence on observed transmission/emission spectra. Initial results suggest that the choice of foreign broadener can result in up to a factor of ~5 increase in pressure broadened wings of the absorption cross sections, resulting in a factor of 1.6x reduction in the atmospheric spectral modulation. Such a difference will be detectible in the hi-resolution/SNR spectra anticipated with JWST, and will

  13. Increase in NOx emissions from Indian thermal power plants during 1996-2010: unit-based inventories and multisatellite observations.

    Science.gov (United States)

    Lu, Zifeng; Streets, David G

    2012-07-17

    Driven by rapid economic development and growing electricity demand, NO(x) emissions (E) from the power sector in India have increased dramatically since the mid-1990s. In this study, we present the NO(x) emissions from Indian public thermal power plants for the period 1996-2010 using a unit-based methodology and compare the emission estimates with the satellite observations of NO(2) tropospheric vertical column densities (TVCDs) from four spaceborne instruments: GOME, SCIAMACHY, OMI, and GOME-2. Results show that NO(x) emissions from Indian power plants increased by at least 70% during 1996-2010. Coal-fired power plants, NO(x) emissions from which are not regulated in India, contribute ∼96% to the total power sector emissions, followed by gas-fired (∼4%) and oil-fired (<1%) ones. A number of isolated NO(2) hot spots are observed over the power plant areas, and good agreement between NO(2) TVCDs and NO(x) emissions is found for areas dominated by power plant emissions. Average NO(2) TVCDs over power plant areas were continuously increasing during the study period. We find that the ratio of ΔE/E to ΔTVCD/TVCD changed from greater than one to less than one around 2005-2008, implying that a transition of the overall NO(x) chemistry occurred over the power plant areas, which may cause significant impact on the atmospheric environment.

  14. Ga-In intermixing, intrinsic doping, and Wigner localization in the emission spectra of self-organized InP/GaInP quantum dots

    Science.gov (United States)

    Kapaldo, J.; Rouvimov, S.; Merz, J. L.; Oktyabrsky, S.; Blundell, S. A.; Bert, N.; Brunkov, P.; Kalyuzhnyy, N. A.; Mintairov, S. A.; Nekrasov, S.; Saly, R.; Vlasov, A. S.; Mintairov, A. M.

    2016-11-01

    We present study of structural and optical properties of InP/GaInP quantum (QDs) providing a weak quantum confinement and creating a platform to study Wigner localization (WL) effects using high spatial resolution optical spectroscopy. Self-organized QD structures were grown using metal-organic chemical phase epitaxy by using different substrate misorientations and cap layer deposition temperatures. Using transmission electron microscopy and energy dispersive x-ray spectroscopy, we demonstrated a bimodal height distribution with peaks at ~5 and ~20 nm and a control of both the lateral size distribution, peaked from ~100 to ~160 nm, and the amount of Ga-In intermixing in the QDs (up to 20%). Using photoluminescence (PL) spectroscopy in combination with circular polarization degree and time resolved micro-PL measurements, we demonstrated control of the emission energy, the intrinsic doping, and the emission decay of these In(Ga)P QDs. Using high-spatial-resolution near-field PL spectra and imaging of single dots, we demonstrated WL effects in dots having a population of up to nine electrons and a parabolic confinement down to ħω 0 ~ 1 meV. We performed a self-consistent calculation of exciton transitions using an effective mass, mean field theory with an isotropic elasticity model to describe the effect of Ga-In intermixing on the emission properties of these dots; and we used calculations of shell splitting, using mean field Hartree-Fock approach and calculations of electron density distribution using configuration interaction approach, to described effects of enhancement of WL in non-circular dots with hard-wall potentials.

  15. Giant-Planet Chemistry: Ammonium Hydrosulfide (NH4SH), Its IR Spectra and Thermal and Radiolytic Stabilities

    Science.gov (United States)

    Loeffler, Mark J.; Hudson, Reggie L.; Chanover, Nancy J.; Simon, Amy A.

    2015-01-01

    Here we present our recent studies of proton-irradiated and unirradiated ammonium hydrosulfide, NH4SH, a compound predicted to be an important tropospheric cloud component of Jupiter and other giant planets. We irradiated both crystalline and amorphous NH4SH at 10-160 K and used IR spectroscopy to observe and identify reaction products in the ice, specifically NH3 and long-chained sulfur-containing ions. Crystalline NH4SH was amorphized during irradiation at all temperatures studied with the rate being the fastest at the lowest temperatures. Irradiation of amorphous NH4SH at approximately 10-75 K showed that 60-80% of the NH4 + remained when equilibrium was reached, and that NH4SH destruction rates were relatively constant within this temperature range. Irradiations at higher temperatures produced different dose dependence and were accompanied by pressure outbursts that, in some cases, fractured the ice. The thermal stability of irradiated NH4SH was found to be greater than that of unirradiated NH4SH, suggesting that an irradiated giant-planet cloud precipitate can exist at temperatures and altitudes not previously considered.

  16. A preliminary investigation of unintentional POP emissions from thermal wire reclamation at industrial scrap metal recycling parks in China.

    Science.gov (United States)

    Nie, Zhiqiang; Zheng, Minghui; Liu, Guorui; Liu, Wenbin; Lv, Pu; Zhang, Bing; Su, Guijin; Gao, Lirong; Xiao, Ke

    2012-05-15

    Thermal wire reclamation is considered to be a potential source of unintentional persistent organic pollutants (unintentional POPs). In this study, unintentional POP concentrations, including PCDD/Fs, dioxin like PCBs (dl-PCBs), polychlorinated naphthalenes (PCNs), hexachlorobenzene (HxCBz) and pentachlorobenzene (PeCBz), were quantified in flue gas and residual ash emissions from thermal wire reclamation at scrap metal dismantling parks in Zhejiang Province, China. The total average TEQ emissions of the investigated unintentional POPs from flue gas and residual ash in two typical scrap metal recycling plants ranged from 13.1 to 48.3ngTEQNm(-3) and 0.08 to 2.8ngTEQg(-1), respectively. The dominant PCDD/F congeners were OCDD, 1,2,3,4,6,7,8-HpCDD, OCDF and 1,2,3,4,6,7,8-HpCDF, while PCB-126 and PCB-169 were the main contributors to the toxicity of the dl-PCBs. There were clear differences in the distribution dl-PCBs congeners contributing to the TEQ concentrations in the flue gas samples from the two plants. The PCN TEQs were dominated by PCN-66/67 and PCN-73. Although thermal wire reclamation in incinerators has been proposed as an alternative to open burning, there are still considerable environmental risks associated with regulated incinerators, and unintentional POP emissions from thermal wire reclamation sites need to be controlled by local government agencies. Copyright © 2012 Elsevier B.V. All rights reserved.

  17. Detection of Crystalline Hematite Mineralization on Mars by the Thermal Emission Spectrometer: Evidence for Near-surface Water

    Science.gov (United States)

    Christensen, P. R.; Bandfield, J. L.; Clark, R. N.; Edgett, K. S.; Hamilton, V. E.; Hoefen, T.; Kieffer, H. H.; Kuzmin, R. O.; Lane, M. D.; Malin, M. C.

    1999-01-01

    The Thermal Emission Spectrometer (TES) instrument on the Mars Global Surveyor (MGS) mission has discovered a remarkable accumulation of crystalline hematite ((alpha-Fe2O3) that covers an area with very sharp boundaries approximately 350 by 350-750 km in size centered near 2 S latitude between 0 and 5 W longitude (Sinus Meridiani). Crystalline hematite is uniquely identified by the presence of fundamental vibrational absorption features centered near 300, 450, and >525/cm, and by the absence of silicate fundamentals in the 1000/cm region. Spectral features resulting from atmospheric CO2, dust, and water ice were removed using a radiative transfer model. The spectral properties unique to Sinus Meridiani were emphasized by removing the average spectrum of the surrounding region. The depth and shape of the hematite fundamental bands show that the hematite is crystalline and relatively coarse grained (>5-10 micron). Diameters up to and greater than 100s of micrometers are permitted within the instrumental noise and natural variability of hematite spectra. Hematite particles 30 micron in diameter to 40-60% for unpacked 10 micron powders. The hematite in Sinus Meridiani is thus distinct from the fine-grained (diameter <5-10 micron), red, crystalline hematite considered, on the basis of visible, near-IR data, to be a minor spectral component in Martian bright regions like Olympus-Amazonis. Sinus Meridiani hematite is closely associated with a smooth, layered, friable surface that is interpreted to be sedimentary in origin. This material may be the uppermost surface in the region, indicating that it could be a late-stage sedimentary unit, or it could be a layered portion of the heavily cratered plains units. We consider five possible mechanisms for the formation of coarse-grained, crystalline hematite. These processes fall into two classes depending on whether they require a significant amount of near-surface water: (1) chemical precipitation that includes origin by (a

  18. Mid-infrared spectra of comet nuclei

    Science.gov (United States)

    Kelley, Michael S. P.; Woodward, Charles E.; Gehrz, Robert D.; Reach, William T.; Harker, David E.

    2017-03-01

    Comet nuclei and D-type asteroids have several similarities at optical and near-IR wavelengths, including near-featureless red reflectance spectra, and low albedos. Mineral identifications based on these characteristics are fraught with degeneracies, although some general trends can be identified. In contrast, spectral emissivity features in the mid-infrared provide important compositional information that might not otherwise be achievable. Jovian Trojan D-type asteroids have emissivity features strikingly similar to comet comae, suggesting that they have the same compositions and that the surfaces of the Trojans are highly porous. However, a direct comparison between a comet and asteroid surface has not been possible due to the paucity of spectra of comet nuclei at mid-infrared wavelengths. We present 5-35 μm thermal emission spectra of comets 10P/Tempel 2, and 49P/Arend-Rigaux observed with the Infrared Spectrograph on the Spitzer Space Telescope. Our analysis reveals no evidence for a coma or tail at the time of observation, suggesting the spectra are dominated by the comet nucleus. We fit each spectrum with the near-Earth asteroid thermal model (NEATM) and find sizes in agreement with previous values. However, the NEATM beaming parameters of the nuclei, 0.74-0.83, are systematically lower than the Jupiter-family comet population mean of 1.03 ± 0.11, derived from 16- and 22-μm photometry. We suggest this may be either an artifact of the spectral reduction, or the consequence of an emissivity low near 16 μm. When the spectra are normalized by the NEATM model, a weak 10-μm silicate plateau is evident, with a shape similar to those seen in mid-infrared spectra of D-type asteroids. A silicate plateau is also evident in previously published Spitzer spectra of the nucleus of comet 9P/Tempel 1. We compare, in detail, these comet nucleus emission features to those seen in spectra of the Jovian Trojan D-types (624) Hektor, (911) Agamemnon, and (1172) Aneas, as well

  19. Analysis of Saturn's Thermal Emission at 2.2-cm Wavelength: Spatial Distribution of Ammonia Vapor

    Science.gov (United States)

    Laraia, A. L.; Ingersoll, A. P.; Janssen, Michael A.; Gulkis, Samuel; Oyafuso, Fabiano A.; Allison, Michael D.

    2013-01-01

    This work focuses on determining the latitudinal structure of ammonia vapor in Saturn's cloud layer near 1.5 bars using the brightness temperature maps derived from the Cassini RADAR (Elachi et al., 2004) instrument, which works in a passive mode to measure thermal emission from Saturn at 2.2-cm wavelength. We perform an analysis of five brightness temperature maps that span epochs from 2005 to 2011, which are presented in a companion paper by Janssen et al. (2013a, this issue). The brightness temperature maps are representative of the spatial distribution of ammonia vapor, since ammonia gas is the only effective opacity source in Saturn's atmosphere at 2.2-cm wavelength. Relatively high brightness temperatures indicate relatively low ammonia relative humidity (RH), and vice versa. We compare the observed brightness temperatures to brightness temperatures computed using the Juno atmospheric microwave radiative transfer (JAMRT) program which includes both the means to calculate a tropospheric atmosphere model for Saturn and the means to carry out radiative transfer calculations at microwave frequencies. The reference atmosphere to which we compare has a 3x solar deep mixing ratio of ammonia (we use 1.352x10(exp -4) for the solar mixing ratio of ammonia vapor relative to H2; see Atreya, 2010) and is fully saturated above its cloud base. The maps are comprised of residual brightness temperatures-observed brightness temperature minus the model brightness temperature of the saturated atmosphere.

  20. The Seasonal Cycle of Water Vapour on Mars from Assimilation of Thermal Emission Spectrometer Data

    Science.gov (United States)

    Steele, Liam J.; Lewis, Stephen R.; Patel, Manish R.; Montmessin, Franck; Forget, Francois; Smith, Michael D.

    2014-01-01

    We present for the first time an assimilation of Thermal Emission Spectrometer (TES) water vapour column data into a Mars global climate model (MGCM). We discuss the seasonal cycle of water vapour, the processes responsible for the observed water vapour distribution, and the cross-hemispheric water transport. The assimilation scheme is shown to be robust in producing consistent reanalyses, and the global water vapour column error is reduced to around 2-4 pr micron depending on season. Wave activity is shown to play an important role in the water vapour distribution, with topographically steered flows around the Hellas and Argyre basins acting to increase transport in these regions in all seasons. At high northern latitudes, zonal wavenumber 1 and 2 stationary waves during northern summer are responsible for spreading the sublimed water vapour away from the pole. Transport by the zonal wavenumber 2 waves occurs primarily to the west of Tharsis and Arabia Terra and, combined with the effects of western boundary currents, this leads to peak water vapour column abundances here as observed by numerous spacecraft. A net transport of water to the northern hemisphere over the course of one Mars year is calculated, primarily because of the large northwards flux of water vapour which occurs during the local dust storm around L(sub S) = 240-260deg. Finally, outlying frost deposits that surround the north polar cap are shown to be important in creating the peak water vapour column abundances observed during northern summer.

  1. Terra and Aqua MODIS Thermal Emissive Bands On-Orbit Calibration and Performance

    Science.gov (United States)

    Xiong, Xiaoxiong; Wu, Aisheng; Wenny, Brian N.; Madhavan, Sriharsha; Wang, Zhipeng; Li, Yonghong; Chen, Na; Barnes, William L.; Salomonson, Vincent V.

    2015-01-01

    Since launch, the Moderate Resolution Imaging Spectroradiometer (MODIS) instruments on the Terra and Aqua spacecraft have operated successfully for more than 14 and 12 years, respectively. A key instrument for National Aeronautics and Space Administration Earth Observing System missions, MODIS was designed to make continuous observations for studies of Earth's land, ocean, and atmospheric properties and to extend existing data records from heritage Earth observing sensors. The 16 thermal emissive bands (TEBs) (3.75-14.24 micrometers) are calibrated on orbit using a temperature controlled blackbody (BB). Both Terra and Aqua MODIS BBs have displayed minimal drift over the mission lifetime, and the seasonal variations of the BB temperature are extremely small in Aqua MODIS. The long-term gain and noise equivalent difference in temperature performance of the 160 TEB detectors on both MODIS instruments have been well behaved and generally very stable. Small but noticeable variations of Aqua MODIS bands 33-36 (13.34-14.24 micrometer) response in recent years are primarily due to loss of temperature control margin of its passive cryoradiative cooler. As a result, fixed calibration coefficients, previously used by bands when the BB temperature is above their saturation temperatures, are replaced by the focal-plane-temperature-dependent calibration coefficients. This paper presents an overview of the MODIS TEB calibration, the on-orbit performance, and the challenging issues likely to impact the instruments as they continue operating well past their designed lifetime of six years.

  2. Structure and method for controlling the thermal emissivity of a radiating object

    Science.gov (United States)

    DeSteese, John G.; Antoniak, Zenen I.; White, Michael; Peters, Timothy J.

    2004-03-30

    A structure and method for changing or controlling the thermal emissivity of the surface of an object in situ, and thus, changing or controlling the radiative heat transfer between the object and its environment in situ, is disclosed. Changing or controlling the degree of blackbody behavior of the object is accomplished by changing or controlling certain physical characteristics of a cavity structure on the surface of the object. The cavity structure, defining a plurality of cavities, may be formed by selectively removing material(s) from the surface, selectively adding a material(s) to the surface, or adding an engineered article(s) to the surface to form a new radiative surface. The physical characteristics of the cavity structure that are changed or controlled include cavity area aspect ratio, cavity longitudinal axis orientation, and combinations thereof. Controlling the cavity area aspect ratio may be by controlling the size of the cavity surface area, the size of the cavity aperture area, or a combination thereof. The cavity structure may contain a gas, liquid, or solid that further enhances radiative heat transfer control and/or improves other properties of the object while in service.

  3. Generation and Use of Thermal Energy in the U.S. Industrial Sector and Opportunities to Reduce its Carbon Emissions

    Energy Technology Data Exchange (ETDEWEB)

    McMillan, Colin [National Renewable Energy Lab. (NREL), Golden, CO (United States); Boardman, Richard [Idaho National Lab. (INL), Idaho Falls, ID (United States); McKellar, Michael [Idaho National Lab. (INL), Idaho Falls, ID (United States); Sabharwall, Piyush [Idaho National Lab. (INL), Idaho Falls, ID (United States); Ruth, Mark [National Renewable Energy Lab. (NREL), Golden, CO (United States); Bragg-Sitton, Shannon [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2016-12-01

    This report quantifies greenhouse gas (GHG) emissions from the industrial sector and identifies opportunities for non-GHG-emitting thermal energy sources to replace the most significant GHG-emitting U.S. industries based on targeted, process-level analysis of industrial heat requirements. The intent is to provide a basis for projecting opportunities for clean energy use. This provides a prospectus for small modular nuclear reactors (including nuclear-renewable hybrid energy systems), solar industrial process heat, and geothermal energy. This report provides a complement to analysis of process-efficiency improvement by considering how clean energy delivery and use by industry could reduce GHG emissions.

  4. The Infrared Spectra of Polycyclic Aromatic Hydrocarbons with Excess Peripheral H Atoms (H(sub n)-PAHs) and their Relation to the 3.4 and 6.9 Micrometer PAH Emission Features

    Science.gov (United States)

    Sandford, Scott A.; Bernstein, Max P.; Materese, Christopher K.

    2013-01-01

    A population of polycyclic aromatic hydrocarbons (PAHs) and related materials are thought to be responsible for the family of infrared emission features that are seen towards a wide variety of astrophysical environments. A potentially important subclass of these materials are polycyclic aromatic hydrocarbons whose edges contain excess H atoms (H(sub n)-PAHs). While it has been suggested that this type of compound may be present in the interstellar population, it has been difficult to properly assess this possibility because of a lack of suitable infrared laboratory spectra to assist with analysis of the astronomical data. We present the 4000-500 cm(exp -1) (2.5-20 micrometers) infrared spectra of 23 H(sub n)-PAHs and related molecules isolated in argon matrices, under conditions suitable for use in the interpretation of astronomical data. The spectra of molecules with mixed aromatic and aliphatic domains show unique characteristics that distinguish them from their fully aromatic PAH equivalents. We discuss the changes to the spectra of these types of molecules as they transition from fully aromatic to fully aliphatic forms. The implications for the interpretation of astronomical spectra are discussed with specific emphasis on the 3.4 and 6.9 micrometer features. Laboratory data is compared with emission spectra from IRAS 21282+5050, an object with normal PAH emission features, in addition to IRAS 22272+5435 and IRAS 0496+3429, two protoplanetary nebulae with abnormally large 3.4 micrometer features. We show that 'normal' PAH emission objects contain relatively few H(sub n)-PAHs in their emitter populations, but less evolved protoplanetary nebulae may contain significant abundances of these molecules.

  5. The GOES-R Advanced Baseline Imager: detector spectral response effects on thermal emissive band calibration

    Science.gov (United States)

    Pearlman, Aaron J.; Padula, Francis; Cao, Changyong; Wu, Xiangqian

    2015-10-01

    The Advanced Baseline Imager (ABI) will be aboard the National Oceanic and Atmospheric Administration's Geostationary Operational Environmental Satellite R-Series (GOES-R) to supply data needed for operational weather forecasts and long-term climate variability studies, which depend on high quality data. Unlike the heritage operational GOES systems that have two or four detectors per band, ABI has hundreds of detectors per channel requiring calibration coefficients for each one. This increase in number of detectors poses new challenges for next generation sensors as each detector has a unique spectral response function (SRF) even though only one averaged SRF per band is used operationally to calibrate each detector. This simplified processing increases computational efficiency. Using measured system-level SRF data from pre-launch testing, we have the opportunity to characterize the calibration impact using measured SRFs, both per detector and as an average of detector-level SRFs similar to the operational version. We calculated the spectral response impacts for the thermal emissive bands (TEB) theoretically, by simulating the ABI response viewing an ideal blackbody and practically, with the measured ABI response to an external reference blackbody from the pre-launch TEB calibration test. The impacts from the practical case match the theoretical results using an ideal blackbody. The observed brightness temperature trends show structure across the array with magnitudes as large as 0.1 K for and 12 (9.61 µm), and 0.25 K for band 14 (11.2 µm) for a 300 K blackbody. The trends in the raw ABI signal viewing the blackbody support the spectral response measurements results, since they show similar trends in bands 12 (9.61µm), and 14 (11.2 µm), meaning that the spectral effects dominate the response differences between detectors for these bands. We further validated these effects using the radiometric bias calculated between calibrations using the external blackbody and

  6. Light emission from thermally generated electron-hole plasma in a field-effect soi-transistor

    CERN Document Server

    Dobrovol's'kij, V M; Nyinyidze, G K; Pavlyuk, S P

    2002-01-01

    Field-effect silicon-on-insulator (SOI) transistors are investigated at extremely high drain currents.These currents heat the silicon film of a transistor and cause the generation of thermal electron-hole plasma there.We discovered the red light emission from such a plasma.Plasma stratification and formation of lighting spots are explained by the occurrence of thermodiffusion auto solitons.

  7. THERMAL EMISSIONS SPANNING THE PROMPT AND THE AFTERGLOW PHASES OF THE ULTRA-LONG GRB 130925A

    Energy Technology Data Exchange (ETDEWEB)

    Basak, Rupal [Nicolaus Copernicus Astronomical Center, ul. Bartycka 18, 00-716 Warsaw (Poland); Rao, A. R., E-mail: rupal@camk.edu.pl, E-mail: arrao@tifr.res.in [Tata Institute of Fundamental Research, Mumbai-400005, India. (India)

    2015-07-01

    GRB 130925A is an ultra-long gamma-ray burst (GRB), and it shows clear evidence for thermal emission in the soft X-ray data of the Swift/X-ray Telescope (XRT; ∼0.5 keV), lasting until the X-ray afterglow phase. Due to the long duration of the GRB, the burst could be studied in hard X-rays with high-resolution focusing detectors (NuSTAR). The blackbody temperature, as measured by the Swift/XRT, shows a decreasing trend until the late phase (Piro et al.) whereas the high-energy data reveal a significant blackbody component during the late epochs at an order of magnitude higher temperature (∼5 keV) compared to contemporaneous low energy data (Bellm et al.). We resolve this apparent contradiction by demonstrating that a model with two black bodies and a power law (2BBPL) is consistent with the data right from the late prompt emission to the afterglow phase. Both blackbodies show a similar cooling behavior up to late times. We invoke a structured jet, having a fast spine and a slower sheath layer, to identify the location of these blackbodies. Independent of the physical interpretation, we propose that the 2BBPL model is a generic feature of the prompt emission of all long GRBs, and the thermal emission found in the afterglow phase of different GRBs reflects the lingering thermal component of the prompt emission with different timescales. We strengthen this proposal by pointing out a close similarity between the spectral evolutions of this GRB and GRB 090618, a source with significant wide band data during the early afterglow phase.

  8. Fine-Scale Ecological and Genetic Population Structure of Two Whitefish (Coregoninae) Species in the Vicinity of Industrial Thermal Emissions.

    Science.gov (United States)

    Graham, Carly F; Eberts, Rebecca L; Morgan, Thomas D; Boreham, Douglas R; Lance, Stacey L; Manzon, Richard G; Martino, Jessica A; Rogers, Sean M; Wilson, Joanna Y; Somers, Christopher M

    2016-01-01

    Thermal pollution from industrial processes can have negative impacts on the spawning and development of cold-water fish. Point sources of thermal effluent may need to be managed to avoid affecting discrete populations. Correspondingly, we examined fine-scale ecological and genetic population structure of two whitefish species (Coregonus clupeaformis and Prosopium cylindraceum) on Lake Huron, Canada, in the immediate vicinity of thermal effluent from nuclear power generation. Niche metrics using δ13C and δ15N stable isotopes showed high levels of overlap (48.6 to 94.5%) in resource use by adult fish captured in areas affected by thermal effluent compared to nearby reference locations. Isotopic niche size, a metric of resource use diversity, was 1.3- to 2.8-fold higher than reference values in some thermally affected areas, indicative of fish mixing. Microsatellite analyses of genetic population structure (Fst, STRUCTURE and DAPC) indicated that fish captured at all locations in the vicinity of the power plant were part of a larger population extending beyond the study area. In concert, ecological and genetic markers do not support the presence of an evolutionarily significant unit in the vicinity of the power plant. Thus, future research should focus on the potential impacts of thermal emissions on development and recruitment.

  9. Evaluation of VIIRS and MODIS Thermal Emissive Band Calibration Stability Using Ground Target

    Directory of Open Access Journals (Sweden)

    Sriharsha Madhavan

    2016-02-01

    Full Text Available The S-NPP Visible Infrared Imaging Radiometer Suite (VIIRS instrument, a polar orbiting Earth remote sensing instrument built using a strong MODIS background, employs a similarly designed on-board calibrating source—a V-grooved blackbody for the Thermal Emissive Bands (TEB. The central wavelengths of most VIIRS TEBs are very close to those of MODIS with the exception of the 10.7 µm channel. To ensure the long term continuity of climate data records derived using VIIRS and MODIS TEB, it is necessary to assess any systematic differences between the two instruments, including scenes with temperatures significantly lower than blackbody operating temperatures at approximately 290 K. Previous work performed by the MODIS Characterization Support Team (MCST at NASA/GSFC used the frequent observations of the Dome Concordia site located in Antarctica to evaluate the calibration stability and consistency of Terra and Aqua MODIS over the mission lifetime. The near-surface temperature measurements from an automatic weather station (AWS provide a direct reference useful for tracking the stability and determining the relative bias between the two MODIS instruments. In this study, the same technique is applied to the VIIRS TEB and the results are compared with those from the matched MODIS TEB. The results of this study show a small negative bias when comparing the matching VIIRS and Aqua MODIS TEB, implying a higher brightness temperature for S-VIIRS at the cold end. Statistically no significant drift is observed for VIIRS TEB performance over the first 3.5 years of the mission.

  10. Near-infrared Transmission and Emission Spectra of HD 209458b: Demonstrating Palomar/TripleSpec’s Capability for Exoplanet Spectroscopy

    Science.gov (United States)

    Zellem, Robert; Griffith, C. A.; Deroo, P.; Swain, M. R.; Waldmann, I.; Zhao, M.

    2012-10-01

    We present primary and secondary eclipse infrared H- and K-band emission spectra of the exoplanet HD 209458b observed with Palomar/TripleSpec. We have used a principal component analysis and bin wavelength channels in Fourier space to decrease the flux variance by ˜3 orders of magnitude resulting in a final mean variance of ˜300 ppm. Most of the secondary eclipse data points are consistent with a null detection, which renders them unusable for further constraining HD 209458b’s atmospheric chemical abundances and temperature profile. However in a few wavelength bands where Earth's atmosphere is particularly clear, we detect the exoplanet above the error levels. Here we derive an exoplanet's flux that is consistent with the Hubble/NICMOS secondary eclipse spectrum, within our achieved precision. Despite challenging data due to poor observing conditions that included clouds and autoguider failure, our data suggest that Palomar/TripleSpec has the capability to make significant spectroscopic measurements of eclipsing hot Jupiters.

  11. Vibration-rotation pattern in acetylene. II. Introduction of Coriolis coupling in the global model and analysis of emission spectra of hot acetylene around 3 μm

    Science.gov (United States)

    Amyay, Badr; Robert, Séverine; Herman, Michel; Fayt, André; Raghavendra, Balakrishna; Moudens, Audrey; Thiévin, Jonathan; Rowe, Bertrand; Georges, Robert

    2009-09-01

    A high temperature source has been developed and coupled to a high resolution Fourier transform spectrometer to record emission spectra of acetylene around 3 μm up to 1455 K under Doppler limited resolution (0.015 cm-1). The ν3-ground state (GS) and ν2+ν4+ν5 (Σu+ and Δu)-GS bands and 76 related hot bands, counting e and f parities separately, are assigned using semiautomatic methods based on a global model to reproduce all related vibration-rotation states. Significantly higher J-values than previously reported are observed for 40 known substates while 37 new e or f vibrational substates, up to about 6000 cm-1, are identified and characterized by vibration-rotation parameters. The 3 811 new or improved data resulting from the analysis are merged into the database presented by Robert et al. [Mol. Phys. 106, 2581 (2008)], now including 15 562 lines accessing vibrational states up to 8600 cm-1. A global model, updated as compared to the one in the previous paper, allows all lines in the database to be simultaneously fitted, successfully. The updates are discussed taking into account, in particular, the systematic inclusion of Coriolis interaction.

  12. Vibration-rotation pattern in acetylene. II. Introduction of Coriolis coupling in the global model and analysis of emission spectra of hot acetylene around 3 microm.

    Science.gov (United States)

    Amyay, Badr; Robert, Séverine; Herman, Michel; Fayt, André; Raghavendra, Balakrishna; Moudens, Audrey; Thiévin, Jonathan; Rowe, Bertrand; Georges, Robert

    2009-09-21

    A high temperature source has been developed and coupled to a high resolution Fourier transform spectrometer to record emission spectra of acetylene around 3 mum up to 1455 K under Doppler limited resolution (0.015 cm(-1)). The nu(3)-ground state (GS) and nu(2)+nu(4)+nu(5) (Sigma(u) (+) and Delta(u))-GS bands and 76 related hot bands, counting e and f parities separately, are assigned using semiautomatic methods based on a global model to reproduce all related vibration-rotation states. Significantly higher J-values than previously reported are observed for 40 known substates while 37 new e or f vibrational substates, up to about 6000 cm(-1), are identified and characterized by vibration-rotation parameters. The 3 811 new or improved data resulting from the analysis are merged into the database presented by Robert et al. [Mol. Phys. 106, 2581 (2008)], now including 15 562 lines accessing vibrational states up to 8600 cm(-1). A global model, updated as compared to the one in the previous paper, allows all lines in the database to be simultaneously fitted, successfully. The updates are discussed taking into account, in particular, the systematic inclusion of Coriolis interaction.

  13. Economic and Environmental Considerations for Zero-emission Transport and Thermal Energy Generation on an Energy Autonomous Island

    Directory of Open Access Journals (Sweden)

    Fontina Petrakopoulou

    2018-01-01

    Full Text Available The high cost and environmental impact of fossil-fuel energy generation in remote regions can make renewable energy applications more competitive than business-as-usual scenarios. Furthermore, energy and transport are two of the main sectors that significantly contribute to global greenhouse gas emissions. This paper focuses on the generation of thermal energy and the transport sector of a fossil fuel-based energy independent island in Greece. We evaluate (1 technologies for fully renewable thermal energy generation using building-specific solar thermal systems and (2 the replacement of the vehicle fleet of the island with electric and hydrogen-fueled vehicles. The analysis, based on economic and environmental criteria, shows that although solar thermal decreases greenhouse gases by 83%, when compared to the current diesel-based situation, it only becomes economically attractive with subsidy scenarios equal to or higher than 50%. However, in the transport sector, the sum of fuel and maintenance costs of fuel-cell and electric vehicles is found to be 45% lower than that of the current fleet, due to their approximately seven times lower fuel cost. Lastly, it will take approximately six years of use of the new vehicles to balance out the emissions of their manufacturing phase.

  14. Disk-averaged synthetic spectra of Mars.

    Science.gov (United States)

    Tinetti, Giovanna; Meadows, Victoria S; Crisp, David; Fong, William; Velusamy, Thangasamy; Snively, Heather

    2005-08-01

    The principal goal of the NASA Terrestrial Planet Finder (TPF) and European Space Agency's Darwin mission concepts is to directly detect and characterize extrasolar terrestrial (Earthsized) planets. This first generation of instruments is expected to provide disk-averaged spectra with modest spectral resolution and signal-to-noise. Here we use a spatially and spectrally resolved model of a Mars-like planet to study the detectability of a planet's surface and atmospheric properties from disk-averaged spectra. We explore the detectability as a function of spectral resolution and wavelength range, for both the proposed visible coronograph (TPFC) and mid-infrared interferometer (TPF-I/Darwin) architectures. At the core of our model is a spectrum-resolving (line-by-line) atmospheric/surface radiative transfer model. This model uses observational data as input to generate a database of spatially resolved synthetic spectra for a range of illumination conditions and viewing geometries. The model was validated against spectra recorded by the Mars Global Surveyor-Thermal Emission Spectrometer and the Mariner 9-Infrared Interferometer Spectrometer. Results presented here include disk-averaged synthetic spectra, light curves, and the spectral variability at visible and mid-infrared wavelengths for Mars as a function of viewing angle, illumination, and season. We also considered the differences in the spectral appearance of an increasingly ice-covered Mars, as a function of spectral resolution, signal-to-noise and integration time for both TPF-C and TPFI/ Darwin.

  15. Catalogue of representative meteor spectra

    Science.gov (United States)

    Vojáček, V.; Borovička, J.; Koten, P.; Spurný, P.; Štork, R.

    2015-08-01

    Aims: We present a library of low-resolution meteor spectra that includes sporadic meteors, members of minor meteor showers, and major meteor showers. These meteors are in the magnitude range from +2 to -3, corresponding to meteoroid sizes from 1 mm to 10 mm. Methods: Parallel double-station video observations allowed us to compute heliocentric orbits for all meteors. Most observations were performed during the periods of activity of major meteor showers in the years between 2006 and 2012. Spectra are classified according to relative intensities of the low-temperature emission lines of Mg, Na, and Fe. Results: Shower meteors were found to be of normal composition, except for Southern δ Aquariids and some members of the Geminid shower, neither of which have Na in the meteor spectra. Variations in Na content are typical for the Geminid shower. Three populations of Na-free mereoroids were identified. The first population are iron meteorites, which have an asteroidal-chondritic origin, but one meteoroid with low perihelion (0.11 AU) was found among the iron meteorites. The second population were Sun-approaching meteoroids in which sodium is depleted by thermal desorption. The third population were Na-free meteoroids of cometary origin. Long exposure to cosmic rays on the surface of comets in the Oort cloud and disintegration of this crust might be the origin of this population of meteoroids. Spectra (Figs. 17-30) are only, Tables 4-6 are also available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (ftp://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/580/A67

  16. THERMAL EMISSION IN THE EARLY X-RAY AFTERGLOWS OF GAMMA-RAY BURSTS: FOLLOWING THE PROMPT PHASE TO LATE TIMES

    Energy Technology Data Exchange (ETDEWEB)

    Friis, Mette [Centre for Astrophysics and Cosmology, Science Institute, University of Iceland, Dunhagi 5, 107 Reykjavik (Iceland); Watson, Darach, E-mail: mef4@hi.is, E-mail: darach@dark-cosmology.dk [Dark Cosmology Centre, Niels Bohr Institute, University of Copenhagen, Juliane Maries Vej 30, DK-2100 Copenhagen O (Denmark)

    2013-07-01

    Thermal radiation, peaking in soft X-rays, has now been detected in a handful of gamma-ray burst (GRB) afterglows and has to date been interpreted as shock break-out of the GRB's progenitor star. We present a search for thermal emission in the early X-ray afterglows of a sample of Swift bursts selected by their brightness in X-rays at early times. We identify a clear thermal component in eight GRBs and track the evolution. We show that at least some of the emission must come from highly relativistic material since two show an apparent super-luminal expansion of the thermal component. Furthermore, we determine very large luminosities and high temperatures for many of the components-too high to originate in a supernova shock break-out. Instead, we suggest that the component may be modeled as late photospheric emission from the jet, linking it to the apparently thermal component observed in the prompt emission of some GRBs at gamma-ray and hard X-ray energies. By comparing the parameters from the prompt emission and the early afterglow emission, we find that the results are compatible with the interpretation that we are observing the prompt quasi-thermal emission component in soft X-rays at a later point in its evolution.

  17. Thermal Characteristics and the Differential Emission Measure Distribution During a B8.3 Flare on 2009 July 4

    Science.gov (United States)

    Awasthi, Arun Kumar; Sylwester, Barbara; Sylwester, Janusz; Jain, Rajmal

    2016-06-01

    We investigate the evolution of the differential emission measure distribution (DEM[T]) in various phases of a B8.3 flare which occurred on 2009 July 04. We analyze the soft X-ray (SXR) emission in the 1.6-8.0 keV range, recorded collectively by the Solar Photometer in X-rays (SphinX; Polish) and the Solar X-ray Spectrometer (Indian) instruments. We conduct a comparative investigation of the best-fit DEM[T] distributions derived by employing various inversion schemes, namely, single Gaussian, power-law functions and a Withbroe-Sylwester (W-S) maximum likelihood algorithm. In addition, the SXR spectrum in three different energy bands, that is, 1.6-5.0 keV (low), 5.0-8.0 keV (high), and 1.6-8.0 keV (combined), is analyzed to determine the dependence of the best-fit DEM[T] distribution on the selection of the energy interval. The evolution of the DEM[T] distribution, derived using a W-S algorithm, reveals multi-thermal plasma during the rise to the maximum phase of the flare, and isothermal plasma in the post-maximum phase of the flare. The thermal energy content is estimated by considering the flare plasma to be (1) isothermal and (2) multi-thermal in nature. We find that the energy content during the flare, estimated using the multi-thermal approach, is in good agreement with that derived using the isothermal assumption, except during the flare maximum. Furthermore, the (multi-) thermal energy estimated while employing the low-energy band of the SXR spectrum results in higher values than that derived from the combined energy band. On the contrary, the analysis of the high-energy band of the SXR spectrum leads to lower thermal energy than that estimated from the combined energy band.

  18. Hydrothermal Alteration Maps of the Central and Southern Basin and Range Province of the United States Compiled From Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) Data

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data and Interactive Data Language (IDL) logical operator algorithms were used to map...

  19. Combined Effects of JP-8 Fuel and Ceramic Thermal Barrier Coatings on the Performance and Emissions of a DI Diesel Engine

    National Research Council Canada - National Science Library

    Klett, David

    1999-01-01

    An experimental study was conducted on the combined effects of using JP-8 Fuel in conjunction with thin thermal barrier coatings on the specific fuel consumption and emissions of UHC, NO, and smoke of a DI diesel engine...

  20. Generation and Use of Thermal Energy in the U.S. Industrial Sector and Opportunities to Reduce its Carbon Emissions

    Energy Technology Data Exchange (ETDEWEB)

    McMillan, Colin A. [National Renewable Energy Lab. (NREL), Golden, CO (United States). Strategic Energy Analysis Center; Boardman, Richard [Idaho National Lab. (INL), Idaho Falls, ID (United States); McKellar, Michael [Idaho National Lab. (INL), Idaho Falls, ID (United States); Sabharwall, Piyush [Idaho National Lab. (INL), Idaho Falls, ID (United States); Ruth, Mark [National Renewable Energy Lab. (NREL), Golden, CO (United States); Bragg-Sitton, Shannon [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2016-11-01

    The industrial sector was the third-largest source of direct U.S. greenhouse gas (GHG) emissions in 2014 behind electricity generation and transportation and accounted for roughly 20% of total emissions (EPA 2016). The Energy Information Administration (EIA) projects that total U.S. energy consumption will grow to about 108 exajoules (1 EJ = 1018 J) or 102 quads (1 quad = 1015 British thermal units) in 2025, with nearly all of the growth coming from the industrial sector (DOE 2015b). Energy consumption in the industrial sector is forecast to increase to 39.5 EJ (37.4 quads)—a 22% increase, exceeding 36% of total energy consumption in the United States. Therefore, it is imperative that industrial GHG emissions be considered in any strategy intent on achieving deep decarbonization of the energy sector as a whole. It is important to note that unlike the transportation sector and electrical grid, energy use by industry often involves direct conversion of primary energy sources to thermal and electrical energy at the point of consumption. About 52% of U.S. industrial direct GHG emissions are the result of fuel combustion (EPA 2016) to produce hot gases and steam for process heating, process reactions, and process evaporation, concentration, and drying. The heterogeneity and variations in scale of U.S. industry and the complexity of modern industrial firms’ global supply chains are among the sector’s unique challenges to minimizing its GHG emissions. A combination of varied strategies—such as energy efficiency, material efficiency, and switching to low-carbon fuels—can help reduce absolute industrial GHG emissions. This report provides a complement to process-efficiency improvement to consider how clean energy delivery and use by industry could reduce GHG emissions. Specifically, it considers the possibility of replacing fossil-fuel combustion in industry with nuclear (specifically small modular reactors [SMRs]), solar thermal (referred to

  1. Gamma-ray Spectra of Starburst Galaxies

    Science.gov (United States)

    Moncada, Roberto Jose; Paglione, Timothy

    2018-01-01

    Starburst galaxies offer a unique window into the nature of star formation, its driving forces, and the energetic interactions within the galaxy. Their supernovae enrich the surrounding environment with cosmic rays that interact with the interstellar medium and galactic magnetic fields producing gamma-rays and non-thermal radio emission. We generated gamma-ray spectra for the 7 brightest starburst galaxies using 8.6 years of Pass 8 Large Area Telescope (LAT) data from the Fermi Gamma-ray Space Telescope. In addition to new detections, we will report on the results of simultaneously modeling the gamma-ray and radio spectra. These results confirm prior studies favoring high magnetic field strengths in the starburst regions.

  2. A Multi-Channel Method for Retrieving Surface Temperature for High-Emissivity Surfaces from Hyperspectral Thermal Infrared Images.

    Science.gov (United States)

    Zhong, Xinke; Labed, Jelila; Zhou, Guoqing; Shao, Kun; Li, Zhao-Liang

    2015-06-08

    The surface temperature (ST) of high-emissivity surfaces is an important parameter in climate systems. The empirical methods for retrieving ST for high-emissivity surfaces from hyperspectral thermal infrared (HypTIR) images require spectrally continuous channel data. This paper aims to develop a multi-channel method for retrieving ST for high-emissivity surfaces from space-borne HypTIR data. With an assumption of land surface emissivity (LSE) of 1, ST is proposed as a function of 10 brightness temperatures measured at the top of atmosphere by a radiometer having a spectral interval of 800-1200 cm(-1) and a spectral sampling frequency of 0.25 cm(-1). We have analyzed the sensitivity of the proposed method to spectral sampling frequency and instrumental noise, and evaluated the proposed method using satellite data. The results indicated that the parameters in the developed function are dependent on the spectral sampling frequency and that ST of high-emissivity surfaces can be accurately retrieved by the proposed method if appropriate values are used for each spectral sampling frequency. The results also showed that the accuracy of the retrieved ST is of the order of magnitude of the instrumental noise and that the root mean square error (RMSE) of the ST retrieved from satellite data is 0.43 K in comparison with the AVHRR SST product.

  3. Probing the non-thermal emission in Abell 2146 and the Perseus cluster with the JVLA

    Science.gov (United States)

    Gendron-Marsolais, Marie-Lou; Hlavacek-Larrondo, Julie; van Weeren, Reinout; Clarke, Tracy; Intema, Huib; Russell, Helen; Edge, Alastair; Fabian, Andy; Olamaie, Malak; Rumsey, Clare; King, Lindsay; McNamara, Brian; Fecteau-Beaucage, David; Hogan, Michael; Mezcua, Mar; Taylor, Gregory; Blundell, Katherine; Sanders, Jeremy

    2018-01-01

    Jets created from accretion onto supermassive black holes release relativistic particles on large distances. These strongly affect the intracluster medium when located in the center of a brightest cluster galaxy. The hierarchical merging of subclusters and groups, from which cluster originate, also generates perturbations into the intracluster medium through shocks and turbulence, constituting a potential source of reacceleration for these particles. I will present deep multi-configuration low radio frequency observations from the Karl G. Jansky Very Large Array of two unique clusters, probing the non-thermal emission from the old particle population of the AGN outflows.Recently awarded of 550 hours of Chandra observations, Abell 2146 is one of the rare clusters undergoing a spectacular merger in the plane of the sky. Our recent deep multi-configuration JVLA 1.4 GHz observations have revealed the presence of a structure extending to 850 kpc in size, consisting of one component associated with the upstream shock and classified as a radio relic, and one associated with the subcluster core, consistent with a radio halo bounded by the bow shock. Theses structures have some of the lowest radio powers detected thus far in any cluster. The flux measurements of the halo, its morphology and measurements of the dynamical state of the cluster suggest that the halo was recently created (~ 0.3 Gyr after core passage). This makes A2146 extremely interesting to study, allowing us to probe the complete evolutionary stages of halos.I will also present results on 230-470 MHz JVLA observations of the Perseus cluster. Our observations of this nearby relaxed cool core cluster have revealed a multitude of new structures associated with the mini-halo, extending to hundreds of kpc in size. Its irregular morphology seems to be have been influenced both by the AGN activity and by the sloshing motion of the cluster’ gas. In addition, it has a filamentary structure similar to that seen in

  4. New insight on the interaction of self-activated and Mn-related emission centers in ZnS

    Science.gov (United States)

    Bacherikov, Yu Yu; Vorona, I.; Zhuk, A.; Gilchuk, A. V.; Korsunska, N.; Markevich, I.

    2017-02-01

    The photoluminescence (PL) and PL excitation (PLE) spectra of undoped and thermally doped with Mn ZnS single crystals are studied. In the PL spectra, the bands caused by Mn-related and self-activated (SA) emission centers were observed. A number of narrow peaks whose intensity enhanced with increasing Mn content were found in the PLE spectra of SA emission. The same peaks were present in the PLE spectra of the Mn-related emission band. Some of these peaks were previously observed in the absorption spectra and attributed to Mn2+ ions. The appearance of Mn-related peaks in the PLE spectra of SA emission is explained by excitation transfer from the Mn2+ ions to SA emission centers. The conditions required for this transfer and possible mechanisms of the process are discussed.

  5. Thermal infrared spectra of surface rocks. Comparison of in the laboratory, in situ, and remote sensing data; Chihyo ganseki no netsusekigaiiki bunko tokusei. Chijo sokutei data to remote sensing data no hikaku

    Energy Technology Data Exchange (ETDEWEB)

    Ninomiya, Y.; Matsunaga, T. [Geological Survey of Japan, Tsukuba (Japan)

    1996-10-01

    An ASTER (advanced spaceborne thermal emission and reflection radiometer) is one of the image sensors. It is to be installed in an earth survey polar orbit platform satellite, EOS-AM1, which is to be launched in 1998, and it is going to start its operation. Data observed by the thermal infrared remote sensing of ASTER include the spectral emissivity, and the spectral emission reflectivity which is expressed by the function of temperature. It is required to overcome technical problems how to extract the spectral emissivity from the observed data. The spectral emissivity extracted from the remote sensing data by the MMD method, measured for samples collected in Cuprite area, Nevada, and/or measured at sampled points were compared to each other and discussed. The hemisphere spectral reflectivity, which is indirect spectral emissivity, agreed well with the direct spectral emissivity. Data suggesting the establishment of Kirchhoff`s law were obtained even for the weathered samples. The spectral emissivity derived from the remote sensing data by the MMD method was in harmony with the spectral characteristics measured strictly on the ground. 14 refs., 3 figs.

  6. Double pulse laser induced breakdown spectroscopy of a solid in water: Effect of hydrostatic pressure on laser induced plasma, cavitation bubble and emission spectra

    Science.gov (United States)

    López-Claros, M.; Dell'Aglio, M.; Gaudiuso, R.; Santagata, A.; De Giacomo, A.; Fortes, F. J.; Laserna, J. J.

    2017-07-01

    There is a growing interest in the development of sensors use in exploration of the deep ocean. Techniques for the chemical analysis of submerged solids are of special interest, as they show promise for subsea mining applications where a rapid sorting of materials found in the sea bottom would improve efficiency. Laser-Induced Breakdown Spectroscopy (LIBS) has demonstrated potential for this application thanks to its unique capability of providing the atomic composition of submerged solids. Here we present a study on the parameters that affect the spectral response of metallic targets in an oceanic pressure environment. Following laser excitation of the solid, the plasma persistence and the cavitation bubble size are considerably reduced as the hydrostatic pressure increases. These effects are of particular concern in dual pulse excitation as reported here, where a careful choice of the interpulse timing is required. Shadowgraphic images of the plasma demonstrate that cavitation bubbles are formed early after the plasma onset and that the effect of hydrostatic pressure is negligible during the early stage of plasma expansion. Contrarily to what is observed at atmospheric pressure, emission spectra observed at high pressures are characterized by self-absorbed atomic lines on continuum radiation resulting from strong radiative recombination in the electron-rich confined environment. This effect is much less evident with ionic lines due to the much higher energy of the levels involved and ionization energy of ions, as well as to the lower extent of absorption effects occurring in the inner part of the plasma, where ionized species are more abundant. As a result of the smaller shorter-lived cavitation bubble, the LIBS intensity enhancement resulting from dual pulse excitation is reduced when the applied pressure increases.

  7. A New Method of Determining the Initial Size and Lorentz Factor of Gamma-Ray Burst Fireballs Using a Thermal Emission Component

    NARCIS (Netherlands)

    Pe'er, A.; Ryde, F.; Wijers, R.A.M.J.; Mészáros, P.; Rees, M.J.

    2007-01-01

    In recent years, increasing evidence has emerged for a thermal component in the gamma- and X-ray spectrum of the prompt emission phase in gamma-ray bursts. The temperature and flux of the thermal component show a characteristic break in the temporal behavior after a few seconds. We show here that

  8. An expression for the atomic fluorescence and thermal-emission intensity under conditions of near saturation and arbitrary self-absorption

    NARCIS (Netherlands)

    Omenetto, N.; Winefordner, J.D.; Alkemade, C.T.J.

    An expression for the effect of self-absorption on the fluorescence and thermal emission intensities is derived by taking into account stimulated emission. A simple, idealized case is considered, consisting of a two level atomic system, in a flame, homogeneous with respect to temperature and

  9. Laser-induced light emission from carbon nanoparticles

    Science.gov (United States)

    Osswald, S.; Behler, K.; Gogotsi, Y.

    2008-10-01

    Strong absorption of light in a broad wavelength range and poor thermal conductance between particles of carbon nanomaterials, such as nanotubes, onions, nanodiamond, and carbon black, lead to strong thermal emission (blackbody radiation) upon laser excitation, even at a very low (milliwatts) power. The lasers commonly used during Raman spectroscopy characterization of carbon can cause sample heating to very high temperatures. While conventional thermometry is difficult in the case of nanomaterials, Raman spectral features, such as the G band of graphitic carbon and thermal emission spectra were used to estimate the temperature during light emission that led to extensive graphitization and evaporation of carbon nanomaterials, indicating local temperatures exceeding 3500 °C.

  10. [Analysis of three-dimensional fluorescence overlapping spectra using differential spectra and independent component analysis].

    Science.gov (United States)

    Yu, Shao-Hui; Zhang, Yu-Jun; Zhao, Nan-Jing; Xiao, Xue; Wang, Huan-Bo; Yin, Gao-Fang

    2013-01-01

    The analysis of multi-component three-dimensional fluorescence overlapping spectra is always very difficult. In view of the advantage of differential spectra and based on the calculation principle of two-dimensional differential spectra, the three-dimensional fluorescence spectra with both excitation and emission spectra is fully utilized. Firstly, the excitation differential spectra and emission differential spectra are respectively computed after unfolding the three-dimensional fluorescence spectra. Then the excitation differential spectra and emission differential spectra of the single component are obtained by analyzing the multicomponent differential spectra using independent component analysis. In this process, the use of cubic spline increases the data points of excitation spectra, and the roughness penalty smoothing reduces the noise of emission spectra which is beneficial for the computation of differential spectra. The similarity indices between the standard spectra and recovered spectra show that independent component analysis based on differential spectra is more suitable for the component recognition of three-dimensional fluorescence overlapping spectra.

  11. Increasing thermal drying temperature of biosolids reduced nitrogen mineralisation and soil N2O emissions

    DEFF Research Database (Denmark)

    Case, Sean; Gomez Muñoz, Beatriz; Magid, Jakob

    2016-01-01

    Previous studies found that thermally dried biosolids contained more mineralisable organic nitrogen (N) than the raw or anaerobically digested (AD) biosolids they were derived from. However, the effect of thermal drying temperature on biosolid N availability is not well understood. This will be o......Previous studies found that thermally dried biosolids contained more mineralisable organic nitrogen (N) than the raw or anaerobically digested (AD) biosolids they were derived from. However, the effect of thermal drying temperature on biosolid N availability is not well understood....... This will be of importance for the value of the biosolids when used to fertilise crops. We sourced AD biosolids from a Danish waste water treatment plant (WWTP) and dried it in the laboratory at 70, 130, 190 or 250 °C to >95 % dry matter content. Also, we sourced biosolids from the WWTP dried using its in-house thermal...

  12. Five novel lanthanide complexes with 2-chloroquinoline-4-carboxylic acid and 1,10-phenanthroline: Crystal structures, molecular spectra, thermal properties and bacteriostatic activities

    Science.gov (United States)

    Wang, Ye; Jin, Cheng-Wei; He, Shu-Mei; Ren, Ning; Zhang, Jian-Jun

    2016-12-01

    Five novel lanthanide complexes [Ln2(2-ClQL)6(phen)2(H2O)2]·2H2O (Ln = Pr(1), Sm(2), Eu(3), Ho(4), Er(5)); 2-ClQL: 2-chloroquinoline-4-carboxylate; phen: 1,10-phenanthroline; were synthesized by conventional solution method at room temperature and characterized via elemental analysis, powder x-ray diffraction, Infrared spectroscopy and Raman spectrometry. The results indicate that complexes 1-5 are isostructural, and each Ln3+ ion is eight-coordinated adopting a distorted square antiprismatic molecular geometry. Binuclear complex 1 are stitched together via hydrogen bonding interactions to form 1D chains, and further to form 2D sheets by the π-π interactions. Luminescence investigation reveals that complex 3 displays strong red emission. TG/DTG-FTIR, reveal the thermal decomposition processes and products of title complexes. The bacteriostatic activities of the complexes were evaluated against Candida albicans, Escherichia coli, and Staphylococcus aureus.

  13. Cosmic Rays and Non-thermal Emission Induced by Accretion of Cool Gas onto the Galactic Disk

    Science.gov (United States)

    Inoue, Susumu; Uchiyama, Yasunobu; Arakawa, Masanori; Renaud, Matthieu; Wada, Keiichi

    2017-11-01

    On both observational and theoretical grounds, the disk of our Galaxy should be accreting cool gas with temperature ≲ {10}5 K via the halo at a rate ˜1 {{M}⊙ {yr}}-1. At least some of this accretion is mediated by high-velocity clouds (HVCs), observed to be traveling in the halo with velocities of a few 100 km s-1 and occasionally impacting the disk at such velocities, especially in the outer regions of the Galaxy. We address the possibility of particle acceleration in shocks triggered by such HVC accretion events, and the detectability of consequent non-thermal emission in the radio to gamma-ray bands and high-energy neutrinos. For plausible shock velocities ˜ 300 {km} {{{s}}}-1 and magnetic field strengths ˜ 0.3{--}10 μ {{G}}, electrons and protons may be accelerated up to ˜1-10 TeV and ˜ 30{--}{10}3 TeV, respectively, in sufficiently strong adiabatic shocks during their lifetime of ˜ {10}6 {{yr}}. The resultant pion decay and inverse Compton gamma-rays may be the origin of some unidentified Galactic GeV-TeV sources, particularly the “dark” source HESS J1503-582 that is spatially coincident with the anomalous H I structure known as “forbidden-velocity wings.” Correlation of their locations with star-forming regions may be weak, absent, or even opposite. Non-thermal radio and X-ray emission from primary and/or secondary electrons may be detectable with deeper observations. The contribution of HVC accretion to Galactic cosmic rays is subdominant, but could be non-negligible in the outer Galaxy. As the thermal emission induced by HVC accretion is likely difficult to detect, observations of such phenomena may offer a unique perspective on probing gas accretion onto the Milky Way and other galaxies.

  14. Modern techniques for the emissions control in thermal electric stations; Tecnicas modernas para el control de emisiones en centrales termoelectricas

    Energy Technology Data Exchange (ETDEWEB)

    Romo Millares, C. A. [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1995-12-31

    This paper presents the techniques and the control equipment for emissions in thermal stations that have the highest possibilities of being considered in the immediate future in the national energy panorama and the established frame for the environmental normativity. The pollutant compounds subject to revision are the nitrogen and sulfur oxides and unburned particles. [Espanol] Se presentan las tecnicas y equipos de control de emisiones para centrales termoelectricas que tienen mayores posibilidades de ser consideradas en el futuro inmediato dentro del panorama energetico nacional y el marco establecido por la normatividad ambiental. Los compuestos contaminantes sujetos a revision son los oxidos de nitrogeno y azufre y las particulas inquemadas.

  15. Electromagnetic scattering and emission by a fixed multi-particle object in local thermal equilibrium: General formalism

    Science.gov (United States)

    Mishchenko, Michael I.

    2017-10-01

    The majority of previous studies of the interaction of individual particles and multi-particle groups with electromagnetic field have focused on either elastic scattering in the presence of an external field or self-emission of electromagnetic radiation. In this paper we apply semi-classical fluctuational electrodynamics to address the ubiquitous scenario wherein a fixed particle or a fixed multi-particle group is exposed to an external quasi-polychromatic electromagnetic field as well as thermally emits its own electromagnetic radiation. We summarize the main relevant axioms of fluctuational electrodynamics, formulate in maximally rigorous mathematical terms the general scattering-emission problem for a fixed object, and derive such fundamental corollaries as the scattering-emission volume integral equation, the Lippmann-Schwinger equation for the dyadic transition operator, the multi-particle scattering-emission equations, and the far-field limit. We show that in the framework of fluctuational electrodynamics, the computation of the self-emitted component of the total field is completely separated from that of the elastically scattered field. The same is true of the computation of the emitted and elastically scattered components of quadratic/bilinear forms in the total electromagnetic field. These results pave the way to the practical computation of relevant optical observables.

  16. Dynamic mineral clouds on HD 189733b. II. Monte Carlo radiative transfer for 3D cloudy exoplanet atmospheres: combining scattering and emission spectra

    Science.gov (United States)

    Lee, G. K. H.; Wood, K.; Dobbs-Dixon, I.; Rice, A.; Helling, Ch.

    2017-05-01

    Context. As the 3D spatial properties of exoplanet atmospheres are being observed in increasing detail by current and new generations of telescopes, the modelling of the 3D scattering effects of cloud forming atmospheres with inhomogeneous opacity structures becomes increasingly important to interpret observational data. Aims: We model the scattering and emission properties of a simulated cloud forming, inhomogeneous opacity, hot Jupiter atmosphere of HD 189733b. We compare our results to available Hubble Space Telescope (HST) and Spitzer data and quantify the effects of 3D multiple scattering on observable properties of the atmosphere. We discuss potential observational properties of HD 189733b for the upcoming Transiting Exoplanet Survey Satellite (TESS) and CHaracterising ExOPlanet Satellite (CHEOPS) missions. Methods: We developed a Monte Carlo radiative transfer code and applied it to post-process output of our 3D radiative-hydrodynamic, cloud formation simulation of HD 189733b. We employed three variance reduction techniques, I.e. next event estimation, survival biasing, and composite emission biasing, to improve signal to noise of the output. For cloud particle scattering events, we constructed a log-normal area distribution from the 3D cloud formation radiative-hydrodynamic results, which is stochastically sampled in order to model the Rayleigh and Mie scattering behaviour of a mixture of grain sizes. Results: Stellar photon packets incident on the eastern dayside hemisphere show predominantly Rayleigh, single-scattering behaviour, while multiple scattering occurs on the western hemisphere. Combined scattered and thermal emitted light predictions are consistent with published HST and Spitzer secondary transit observations. Our model predictions are also consistent with geometric albedo constraints from optical wavelength ground-based polarimetry and HST B band measurements. We predict an apparent geometric albedo for HD 189733b of 0.205 and 0.229, in the

  17. Detection of Bioaerosols Using Single Particle Thermal Emission Spectroscopy (First-year Report)

    Science.gov (United States)

    2012-02-01

    Fourier heat-conduction calculations are conducted in which the characteristic cooling period is plotted as a function of particle radius based on...thermal radiance is captured using a highly efficient gold-coated Schwarzschild objective with a numeric aperture (NA) of 0.50. The broadband thermal...focusing nozzle (20). Based on a field of view (FOV) defined by the Schwarzschild objective of 500 µm, we predict a maximum integration period of Δt

  18. High-efficiency electroluminescence and amplified spontaneous emission from a thermally activated delayed fluorescent near-infrared emitter

    Science.gov (United States)

    Kim, Dae-Hyeon; D'Aléo, Anthony; Chen, Xian-Kai; Sandanayaka, Atula D. S.; Yao, Dandan; Zhao, Li; Komino, Takeshi; Zaborova, Elena; Canard, Gabriel; Tsuchiya, Youichi; Choi, Eunyoung; Wu, Jeong Weon; Fages, Frédéric; Brédas, Jean-Luc; Ribierre, Jean-Charles; Adachi, Chihaya

    2018-02-01

    Near-infrared organic light-emitting diodes and semiconductor lasers could benefit a variety of applications including night-vision displays, sensors and information-secured displays. Organic dyes can generate electroluminescence efficiently at visible wavelengths, but organic light-emitting diodes are still underperforming in the near-infrared region. Here, we report thermally activated delayed fluorescent organic light-emitting diodes that operate at near-infrared wavelengths with a maximum external quantum efficiency of nearly 10% using a boron difluoride curcuminoid derivative. As well as an effective upconversion from triplet to singlet excited states due to the non-adiabatic coupling effect, this donor-acceptor-donor compound also exhibits efficient amplified spontaneous emission. By controlling the polarity of the active medium, the maximum emission wavelength of the electroluminescence spectrum can be tuned from 700 to 780 nm. This study represents an important advance in near-infrared organic light-emitting diodes and the design of alternative molecular architectures for photonic applications based on thermally activated delayed fluorescence.

  19. Changes in BVOC emission pattern from Fagus sylvatica L. measured by thermal desorber GC-MS

    Science.gov (United States)

    Joó, É.; van Langenhove, H.; Schietse, L.; Pokorska, O.; Šimpraga, M.; Steppe, K.; Demarcke, M.; Amelynck, C.; Schoon, N.; Müller, J.-F.; Samson, R.; Dewulf, J.

    2009-04-01

    Considerable attention has been focused on biogenic volatile organic compound (BVOC) emissions from forest ecosystems because of their contribution to tropospheric oxidation processes and secondary aerosol formation [1, 2]. It became apparent that biogenic emissions show much more variation than previously assumed. In this poster we focus on the change in BVOC emission patterns from a four year old Fagus sylvatica L. during a growth chamber experiment (PAR, temperature controlled) lasting from March to November 2008. A dynamic branch enclosure system was used in our experiments. Ozone and VOC were removed from air entering the cuvette, as ozone level was found to be a critical parameter for degradation of the compounds [3]. Samples were collected on Tenax TA-Carbotrap solid phase adsorbent tubes and analyzed by TD-GC-MS. Measurements started before budburst of the tree and finished at the end of autumn. Over the entire period 33 samples have been analyzed, while 16 compounds were detected, including 10 monoterpenes (MT), 2 oxygenated-MTs, 2 sesquiterpenes (SQT), isoprene and methyl salicylate. Sabinene showed the highest emission, in an agreement with previous studies [4, 5]. Quantifiable emission appeared 21 days after budburst, and reached the highest level at the beginning of summer. MT emissions showed a clear trend in following each other. As an illustration the trend of sabinene and limonene emission is presented. In the middle of autumn phytophaga infection was observed on the tree induced by Two-spotted mite (Tetranychus urticae). New compounds appeared as a result of infection (linalool, methyl salicylate, (E,E)-α-farnesene, unknown oxygenated-MT, unknown SQT) and became dominant over sabinene, explained by the low MT emissions at this time of the year. These observations point at the importance of further investigation of BVOC emissions (especially SQTs and oxygenated-MTs) and the need for a proper quantification system of these compounds. We would like

  20. Thermal stability of octadecyltrimethylammonium bromide modified montmorillonite organoclay.

    Science.gov (United States)

    Xi, Yunfei; Zhou, Qin; Frost, Ray L; He, Hongping

    2007-07-15

    Organoclays are significant for providing a mechanism for the adsorption of organic molecules from potable water. As such their thermal stability is important. A combination of thermogravimetric analysis and infrared emission spectroscopy was used to determine this stability. Infrared emission spectroscopy (IES) was used to investigate the changes in the structure and surface characteristics of water and surfactant molecules in montmorillonite, octadecyltrimethylammonium bromide and organoclays prepared with the surfactant octadecyltrimethylammonium bromide with different surfactant loadings. These spectra collected at different temperatures give support to the results obtained from the thermal analysis and also provide additional evidence for the dehydration which is difficult to obtain by normal thermoanalytical techniques. The spectra provide information on the conformation of the surfactant molecules in the clay layers and the thermal decomposition of the organoclays. Infrared emission spectroscopy proved to be a useful tool for the study of the thermal stability of the organoclays.

  1. The analysis of the possible thermal emission at radio frequencies from an evolved supernova remnant HB 3 (G132.7+1.3: Revisited

    Directory of Open Access Journals (Sweden)

    Onić D.

    2008-01-01

    Full Text Available It has recently been reported that some of the flux density values for an evolved supernova remnant (SNR HB 3 (G132.7+1.3 are not accurate enough. In this work we therefore revised the analysis of the possible thermal emission at radio frequencies from this SNR using the recently published, corrected flux density values. A model including the sum of non-thermal (purely synchrotron and thermal (bremsstrahlung components is applied to fit the integrated radio spectrum of this SNR. The contribution of thermal component to the total volume emissivity at 1 GHz is estimated to be ≈ 37%. The ambient density is also estimated to be n ≈ 9 cm-3 for T = 104 K. Again we obtained a relatively significant presence of thermal emission at radio frequencies from the SNR, which can support interaction between SNR HB 3 and adjacent molecular cloud associated with the H ii region W3. Our model estimates for thermal component contribution to total volume emissivity at 1 GHz and ambient density are similar to those obtained earlier (≈ 40 %, ≈ 10 cm-3 . It is thus obvious that the corrected flux density values do not affect the basic conclusions.

  2. The Analysis of the Possible Thermal Emission at Radio Frequencies from an Evolved Supernova Remnant HB 3 (G132.7+1.3: Revisited

    Directory of Open Access Journals (Sweden)

    Onić, D.

    2008-12-01

    Full Text Available It has recently been reported that some of the flux density values for an evolved supernova remnant (SNR HB 3 (G132.7$+$1.3 are not accurate enough. In this work we therefore revised the analysis of the possible thermal emission at radio frequencies from this SNR using the recently published, corrected flux density values. A model including the sum of non-thermal (purely synchrotron and thermal (bremsstrahlung components is applied to fit the integrated radio spectrum of this SNR. The contribution of thermal component to the total volume emissivity at $1 mathrm{GHz}$ is estimated to be $approx37 \\%$. The ambient density is also estimated to be $napprox 9 mathrm{cm}^{-3}$ for $mathrm{T}=10^{4} mathrm{K}$. Again we obtained a relatively significant presence of thermal emission at radio frequencies from the SNR, which can support interaction between SNR HB 3 and adjacent molecular cloud associated with the mbox{H,{sc ii}} region W3. Our model estimates for thermal component contribution to total volume emissivity at $1 mathrm{GHz}$ and ambient density are similar to those obtained earlier ($approx40 \\%$, $approx10 mathrm{cm^{-3}}$. It is thus obvious that the corrected flux density values do not affect the basic conclusions.

  3. How the geysers, tidal stresses, and thermal emission across the south polar terrain of enceladus are related

    Energy Technology Data Exchange (ETDEWEB)

    Porco, Carolyn; DiNino, Daiana [CICLOPS, Space Science Institute, 4750 Walnut Street, Boulder, CO 80304 (United States); Nimmo, Francis, E-mail: Carolyn@ciclops.org [Department of Earth and Planetary Sciences, University of California, 1156 High Street, Santa Cruz, CA 95064 (United States)

    2014-09-01

    We present the first comprehensive examination of the geysering, tidal stresses, and anomalous thermal emission across the south pole of Enceladus and discuss the implications for the moon's thermal history and interior structure. A 6.5 yr survey of the moon's south polar terrain (SPT) by the Cassini imaging experiment has located ∼100 jets or geysers erupting from four prominent fractures crossing the region. Comparing these results with predictions of diurnally varying tidal stresses and with Cassini low resolution thermal maps shows that all three phenomena are spatially correlated. The coincidence of individual jets with very small (∼10 m) hot spots detected in high resolution Cassini VIMS data strongly suggests that the heat accompanying the geysers is not produced by shearing in the upper brittle layer but rather is transported, in the form of latent heat, from a sub-ice-shell sea of liquid water, with vapor condensing on the near-surface walls of the fractures. Normal stresses modulate the geysering activity, as shown in the accompanying paper; we demonstrate here they are capable of opening water-filled cracks all the way down to the sea. If Enceladus' eccentricity and heat production are in steady state today, the currently erupting material and anomalous heat must have been produced in an earlier epoch. If regional tidal heating is occurring today, it may be responsible for some of the erupting water and heat. Future Cassini observations may settle the question.

  4. Thermal effects on light emission in Yb sup 3 sup + -sensitized rare-earth doped optical glasses

    CERN Document Server

    Gouveia, E A; Gouveia-Neto, A S

    2001-01-01

    The temperature effect upon infrared-to-visible frequency upconversion fluorescence emission in off-resonance infrared excited Yb sup 3 sup + -sensitized rare-earth doped optical glasses is theoretically and experimentally investigated. We have examined samples of Er3+/Yb sup 3 sup + -codoped Ga sub 2 S sub 3 :La sub 2 O sub 3 chalcogenide glasses and germanosilicate optical fibers, and Ga2O3:La sub 2 O sub 3 chalcogenide and fluoroindate glasses codoped with Pr sup 3 sup + /Yb sup 3 sup + , excited off-resonance at 1.064 mu m. The experimental results revealed thermal induced enhancement in the visible upconversion emission intensity as the samples temperatures were increased within the range of 20 deg C to 260 deg C. The fluorescence emission enhancement is attributed to the temperature dependent multiphonon-assisted anti-Stokes excitation process of the ytterbium-sensitizer. A theoretical approach that takes into account a sensitizer temperature dependent effective absorption cross section, which depends u...

  5. Polarized Power Spectra from HERA-19 Commissioning Data: Instrument Stability

    Science.gov (United States)

    Fox Fortino, Austin; Chichura, Paul; Igarashi, Amy; Kohn, Saul; Aguirre, James; HERA Collaboration

    2018-01-01

    The Epoch of Reionization (EoR) is a key period in the universe’s history, containing the formation of the first galaxies and large scale structures. Foreground emission is the limiting factor in detecting the 21 cm emission from the Epoch of Reionization (EoR). The HERA-19 low frequency radio interferometer aims to reduce the obfuscation from the foreground emission with its dish shaped antennae. We generate polarized 2D (cylindrically averaged) power spectra from seven days of observation from the HERA-19 2016 observation season in each of the four Stokes parameters I, Q, U, and V. These power spectra serve as a potent diagnostic tool that allow us to understand the instrument stability by comparison between nominally redundant baselines, and between observations of nominally the same astrophysical sky on successive days. The power spectra are expected to vary among nominally redundant measurements due to ionosphere fluctuations and thermal changes in the electronics and instrument beam patterns, as well as other factors. In this work we investigate the stability over time of these polarized power spectra, and use them to quantify the variation due to these effects.

  6. Inequality spectra

    Science.gov (United States)

    Eliazar, Iddo

    2017-03-01

    Inequality indices are widely applied in economics and in the social sciences as quantitative measures of the socioeconomic inequality of human societies. The application of inequality indices extends to size-distributions at large, where these indices can be used as general gauges of statistical heterogeneity. Moreover, as inequality indices are plentiful, arrays of such indices facilitate high-detail quantification of statistical heterogeneity. In this paper we elevate from arrays of inequality indices to inequality spectra: continuums of inequality indices that are parameterized by a single control parameter. We present a general methodology of constructing Lorenz-based inequality spectra, apply the general methodology to establish four sets of inequality spectra, investigate the properties of these sets, and show how these sets generalize known inequality gauges such as: the Gini index, the extended Gini index, the Rényi index, and hill curves.

  7. Planck intermediate results. XXII. Frequency dependence of thermal emission from Galactic dust in intensity and polarization

    DEFF Research Database (Denmark)

    Cardoso, J. F.; Delabrouille, J.; Ganga, K.

    2015-01-01

    Planck has mapped the intensity and polarization of the sky at microwave frequencies with unprecedented sensitivity. We use these data to characterize the frequency dependence of dust emission. We make use of the Planck 353 GHz I, Q, and U Stokes maps as dust templates, and cross-correlate them w...

  8. Directional Thermal Emission and Absorption from Surface Microstructures in Metalized Plastics

    Science.gov (United States)

    2013-09-01

    units[3]. The body’s temperature, T, is expressed in Kelvin and the wavelength, λ, is expressed in micrometers (μm) to produce a spectral emissive...closing the diaphragm around preset vernier calipers. A set of reflectance measurements was in the source reference measurement configuration, described

  9. Planck 2013 results. XI. All-sky model of thermal dust emission

    DEFF Research Database (Denmark)

    Abergel, A.; Ade, P. A. R.; Aghanim, N.

    2014-01-01

    This paper presents an all-sky model of dust emission from the Planck 353, 545, and 857 GHz, and IRAS 100 mu m data. Using a modified blackbody fit to the data we present all-sky maps of the dust optical depth, temperature, and spectral index over the 353-3000 GHz range. This model is a good repr...

  10. Computational fluid dynamics (CFD) simulation of CO2 emission from a thermal power plant in an urban environment.

    Science.gov (United States)

    Toja-Silva, Francisco; Chen, Jia; Hachinger, Stephan

    2017-04-01

    Climate change, a societal challenge for the European Union, is affecting all regions in Europe and has a profound impact on society and environment. It is now clear that the present global warming period is due to the strong anthropogenic greenhouse gas (GHG) emission, occurring at an unprecedented rate. Therefore, the identification and control of the greenhouse gas sources has a great relevance. Since the GHG emissions from cities are the largest human contribution to climate change, the present investigation focuses on the urban environment. Bottom-up annual emission inventories are compiled for most countries. However, a rigorous approach requires to perform experimental measurements in order to verify the official estimates. Measurements of column-averaged dry-air mole fractions of GHG (XGHG) can be used for this. To comprehensively detect and quantify GHG emission sources, these punctual column data, however, have to be extended to the surrounding urban map, requiring a deep understanding of the gas transport. The resulting emission estimation will serve several practical purposes, e.g. the verification of official emission rates and the determination of trends in urban emissions. They will enable the administration to make targeted and economically efficient decisions about mitigation options, and help to stop unintentional and furtive releases. With this aim, this investigation presents a completely new approach to the analysis of the carbon dioxide (CO2) emissions from fossil fuel thermal power plants in urban environments by combining differential column measurements with computational fluid dynamics (CFD) simulations in order to deeply understand the experimental conditions. The case study is a natural gas-fueled cogeneration (combined heat and power, CHP) thermal power plant inside the city of Munich (Germany). The software used for the simulations (OpenFOAM) was modified in order to use the most advanced RANS turbulence modeling (i.e. Durbin) and

  11. Emission reduction in thermal processes for sewage sludge disposal; Emissionsreduzierung bei thermischen Verfahren zur Klaerschlammentsorgung

    Energy Technology Data Exchange (ETDEWEB)

    Nethe, L.P. [Maerker Umwelttechnik GmbH, Hamburg (Germany)

    1998-09-01

    Owing to the intensification of treatment processes and the construction of new sewage plants sewage arisings are due to rise considerably. The thermal treatment of sewage sludge which it has not been possible to avoid or utilise is an important and indispensable part of any sewage sludge disposal concept. If equipped with a state-of-the-art flue gas purification process that uses carbonaceous adsorbents (Sorbalit trademark), thermal treatment of sewage sludge can be regarded as an environmentally safe process technique. [Deutsch] Die anfallenden Klaerschlammengen werden durch die Intensivierung der Klaerprozesse und der Bau neuer Klaeranlagen deutlich zunehmen. Die thermische Behandlung nicht vermiedener oder verwerteter Klaerschlaemme stellt einen bedeutenden und unverzichtbaren Teil der Klaerschlamm-Entsorgungskonzepte dar. Bei Installation einer - dem Stand der Technik - entsprechenden Rauchgasreinigung mit dem Einsatz kohlenstoffhaltiger Adsorbentien (Sorbalit {sup trademark}) ist die thermische Behandlung von Klaerschlamm eine umweltsichere Verfahrenstechnik. (orig.)

  12. Impurity line emission due to thermal charge exchange in JET edge plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Maggi, C.F.; Horton, L.D.; Koenig, R.; Stamp, M. [Commission of the European Communities, Abingdon (United Kingdom). JET Joint Undertaking; Summers, H.P. [Strathclyde Univ., Glasgow (United Kingdom)

    1994-07-01

    High n-shell emission from hydrogen-like carbon (C VI, n=8-7) has been routinely observed from the plasma edge of JET. By comparing the measured spectral line intensities with the signals predicted by advanced atomic physics modelling of carbon and hydrogen radiation, integrated with modelling of the divertor and edge plasma, it is concluded that charge transfer from excited state hydrogen donors into fully stripped carbon ions can account for the observed spectral emission, but that the hydrogen distribution and to a lesser extent the carbon distribution away from the strike zone predicted by the transport model are too low. Data presented are those of three upper X-point discharges, where the target material was carbon. 5 refs., 1 fig., 3 tabs.

  13. Spectral and Spatial Coherent Emission of Thermal Radiation from Metal-Semiconductor Nanostructures

    Science.gov (United States)

    2012-03-01

    simulation programs. Further, the CST software suite includes an electromagnetic-thermal coupled simulation that enables 103 an additional...in the time domain. For all these modeling suites , it is recommended that a high performance supercomputer site be utilized to decrease simulation...Y. Gong, X. Liu, L. Wang, H. Lu and G. Wang, "Multiple responses of TPP-assisted near-perfect absorption in metal/ Fibonacci quasiperiodic photonic

  14. Atmospheric emissions and pollution from the coal-fired thermal power plants in India

    Science.gov (United States)

    Guttikunda, Sarath K.; Jawahar, Puja

    2014-08-01

    In India, of the 210 GW electricity generation capacity, 66% is derived from coal, with planned additions of 76 GW and 93 GW during the 12th and the 13th five year plans, respectively. Atmospheric emissions from the coal-fired power plants are responsible for a large burden on human health. In 2010-11, 111 plants with an installed capacity of 121 GW, consumed 503 million tons of coal, and generated an estimated 580 ktons of particulates with diameter less than 2.5 μm (PM2.5), 2100 ktons of sulfur dioxides, 2000 ktons of nitrogen oxides, 1100 ktons of carbon monoxide, 100 ktons of volatile organic compounds, and 665 million tons of carbon dioxide. These emissions resulted in an estimated 80,000 to 115,000 premature deaths and 20.0 million asthma cases from exposure to PM2.5 pollution, which cost the public and the government an estimated INR 16,000 to 23,000 crores (USD 3.2 to 4.6 billion). The emissions were estimated for the individual plants and the atmospheric modeling was conducted using CAMx chemical transport model, coupled with plume rise functions and hourly meteorology. The analysis shows that aggressive pollution control regulations such as mandating flue gas desulfurization, introduction and tightening of emission standards for all criteria pollutants, and updating procedures for environment impact assessments, are imperative for regional clean air and to reduce health impacts. For example, a mandate for installation of flue gas desulfurization systems for the operational 111 plants could reduce the PM2.5 concentrations by 30-40% by eliminating the formation of the secondary sulfates and nitrates.

  15. Emissions of polycyclic aromatic hydrocarbons from thermal pre-treatment of waste hydrodesulfurization catalysts.

    Science.gov (United States)

    Lai, Yi-Chieh; Lee, Wen-Jhy; Huang, Kuo-Lin; Huang, Hong-Hsin

    2007-09-01

    Despite increasing environmental concerns and stringent limitations on the sulfur content in fuels, many waste hydrodesulfurization (HDS) catalysts containing Co, Mo, Ni and V are generated in the petroleum refining process. To recover valuable metals in the waste HDS catalysts via hydrometallurgy, thermal treatment is usually performed first to remove contaminants (residual oil, carbon and sulfur) present on the surface of catalysts. In this study, the mass partitions of polycyclic aromatic hydrocarbons (PAHs) in different media (aqueous, particulate and gaseous) were quantified in order to determine the efficiency of three different air pollution control devices, cooling unit, filter and glass cartridge, on PAH removal. An afterburner and two furnace temperatures were used to observe the effect on the PAH contents of the treated residues. Results show that total-PAH content in treated residues decreased with the pyrolysis temperature of the primary furnace, while those generated in flue gases were destroyed by the afterburner at an efficiency of approximately 95%. In addition, the thermal process converts high molecular weight PAHs to low molecular weight PAHs, and the afterburner temperature involved (1200 degrees C) was high enough to prohibit the generation of high molecular weight PAHs (HM-PAHs), leading to the domination of low molecular weight PAHs (LM-PAHs) in flue gases, while treated residues were dominated by HM-PAHs. Finally, information on metal contents and their concentrations in the Toxicity Characteristic Leaching Procedure in waste HDS catalyst and thermal treated residues are examined as an index of the potential for metal recovery.

  16. Global Thermal Power Plants Database: Unit-Based CO2, SO2, NOX and PM2.5 Emissions in 2010

    Science.gov (United States)

    Tong, D.; Qiang, Z.; Davis, S. J.

    2016-12-01

    There are more than 30,000 thermal power plants now operating worldwide, reflecting a tremendously diverse infrastructure that includes units burning oil, natural gas, coal and biomass and ranging in capacity from 1GW. Although the electricity generated by this infrastructure is vital to economic activities across the world, it also produces more CO2 and air pollution emissions than any other industry sector. Here we present a new database of global thermal power-generating units and their emissions as of 2010, GPED (Global Power Emissions Database), including the detailed unit information of installed capacity, operation year, geographic location, fuel type and control measures for more than 70000 units. In this study, we have compiled, combined, and harmonized the available underlying data related to thermal power-generating units (e.g. eGRID of USA, CPED of China and published Indian power plants database), and then analyzed the generating capacity, capacity factor, fuel type, age, location, and installed pollution-control technology in order to determine those units with disproportionately high levels of emissions. In total, this work is of great importance for improving spatial distribution of global thermal power plants emissions and exploring their environmental impacts at global scale.

  17. Time scales and ratios of climate forcing due to thermal versus carbon dioxide emissions from fossil fuels

    Science.gov (United States)

    Zhang, Xiaochun; Caldeira, Ken

    2015-06-01

    The Earth warms both when fossil fuel carbon is oxidized to carbon dioxide and when greenhouse effect of carbon dioxide inhibits longwave radiation from escaping to space. Various important time scales and ratios comparing these two climate forcings have not previously been quantified. For example, the global and time-integrated radiative forcing from burning a fossil fuel exceeds the heat released upon combustion within 2 months. Over the long lifetime of CO2 in the atmosphere, the cumulative CO2-radiative forcing exceeds the amount of energy released upon combustion by a factor >100,000. For a new power plant, the radiative forcing from the accumulation of released CO2 exceeds the direct thermal emissions in less than half a year. Furthermore, we show that the energy released from the combustion of fossil fuels is now about 1.71% of the radiative forcing from CO2 that has accumulated in the atmosphere as a consequence of historical fossil fuel combustion.

  18. Thermal removal from near-infrared imaging spectroscopy data of the Moon

    Science.gov (United States)

    Clark, Roger N.; Pieters, Carle M.; Green, Robert O.; Boardman, J.W.; Petro, Noah E.

    2011-01-01

    In the near-infrared from about 2 μm to beyond 3 μm, the light from the Moon is a combination of reflected sunlight and emitted thermal emission. There are multiple complexities in separating the two signals, including knowledge of the local solar incidence angle due to topography, phase angle dependencies, emissivity, and instrument calibration. Thermal emission adds to apparent reflectance, and because the emission's contribution increases over the reflected sunlight with increasing wavelength, absorption bands in the lunar reflectance spectra can be modified. In particular, the shape of the 2 μm pyroxene band can be distorted by thermal emission, changing spectrally determined pyroxene composition and abundance. Because of the thermal emission contribution, water and hydroxyl absorptions are reduced in strength, lowering apparent abundances. It is important to quantify and remove the thermal emission for these reasons. We developed a method for deriving the temperature and emissivity from spectra of the lunar surface and removing the thermal emission in the near infrared. The method is fast enough that it can be applied to imaging spectroscopy data on the Moon.

  19. Measurement of the 238U neutron-capture cross section and gamma-emission spectra from 10 eV to 100 keV using the DANCE detector at LANSCE

    Energy Technology Data Exchange (ETDEWEB)

    Ullmann, John L [Los Alamos National Laboratory; Couture, A J [Los Alamos National Laboratory; Keksis, A L [Los Alamos National Laboratory; Vieira, D J [Los Alamos National Laboratory; O' Donnell, J M [Los Alamos National Laboratory; Jandel, M [Los Alamos National Laboratory; Haight, R C [Los Alamos National Laboratory; Rundberg, R S [Los Alamos National Laboratory; Kawano, T [Los Alamos National Laboratory; Chyzh, A [NORTH CAROLINA STATE UNIV; Baramsai, B [NORTH CAROLINA STATE UNIV; Wu, C Y [LLNL; Mitchell, G E [NORTH CAROLINA STATE UNIV; Becker, J A [LLNL; Krticka, M [CHARLES UNIV

    2010-01-01

    A careful new measurement of the {sup 238}U(n,{gamma}) cross section from 10 eV to 100 keV has been made using the DANCE detector at LANSCE. DANCE is a 4{pi} calorimetric scintillator array consisting of 160 BaF{sub 2} crystals. Measurements were made on a 48 mg/cm{sup 2} depleted uranium target. The cross sections are in general good agreement with previous measurements. The gamma-ray emission spectra, as a function of gamma multiplicity, were also measured and compared to model calculations.

  20. Characterisation of Damaged Tubular Composites by Acoustic Emission, Thermal Diffusivity Mapping and TSR-RGB Projection Technique

    Science.gov (United States)

    Chandarana, Neha; Lansiaux, Henri; Gresil, Matthieu

    2017-04-01

    An increase in the use of composite materials, owing to improved design and fabrication processes, has led to cost reductions in many industries. Resistance to corrosion, high specific strength, and stiffness are just a few of their many attractive properties. However, damage tolerance remains a major concern in the implementation of composites and uncertainty regarding component lifetimes can lead to over-design and under-use of such materials. A combination of non-destructive evaluation (NDE) and structural health monitoring (SHM) have shown promise in improving confidence by enabling data collection in-situ and in real time. In this work, infrared thermography (IRT) is employed for NDE of tubular composite specimens before and after impact. Four samples are impacted with energies of 5 J, 7.5 J, and 10 J by an un-instrumented falling weight set-up. Acoustic emissions (AE) are monitored using bonded piezoelectric sensors during one of the four impact tests. IRT data is used to generate diffusivity and thermal depth mappings of each sample using the thermographic signal reconstruction (TSR) red green blue (RGB) projection technique. Analysis of AE data alone for a 10 J impact suggest significant damage to the fibres and matrix; this is in good agreement with the generated thermal depth mappings for each sample, which indicate damage through multiple fibre layers. IRT and AE data are correlated and validated by optical micrographs taken along the cross section of damage.

  1. Rotationally Resolved Spitzer Spectra of Comet-Asteroid Transition Object 944 Hidalgo

    Science.gov (United States)

    Campins, Humberto; Kelley, M. S.; Fernández, Y. R.; Ziffer, J.; Licandro, J.; Emery, J.; Cruikshank, D. P.; Hergenrother, C.; Pinilla-Alonso, N.; Hargrove, K.; Clautice, D.

    2007-10-01

    Last year (Campins et al. 2006), we reported near-infrared rotational variability in ground-based spectra of comet-asteroid transition object 944 Hidalgo. Since then, we carried out a rotationally resolved study of Hidalgo at mid-infrared wavelengths using the Infrared Spectrograph (IRS) on NASA's Spitzer Space Telescope. We obtained 7 to 38 micron spectra of Hidalgo at 10 different rotational phases. These observations were carried out on July 24, 2006, when Hidalgo was at heliocentric and Spitzer-centric distances of 4.83 AU and 4.84 AU. In an initial analysis, we normalized the spectra with a thermal model fit to the continuum (which varied as the cross section of this non-spherical object changed with rotational phase). No detectable rotational variability in the emissivity was found across the wavelength range. All the spectra show clear emissions from silicates. These emissions are qualitatively similar to those seen in the spectra of Trojan asteroids (Emery et al. 2006) and in the spectrum of comet Hale-Bopp (Crovisier et al. 1997). Given the lack of emissivity variability, we averaged all our spectra and compared them with the other Spitzer spectrum of Hidalgo, which was obtained as part of the guaranteed time observations (GTO) on February 10, 2005 when Hidalgo was at heliocentric and Spitzer-centric distances of 1.96 AU and 1.71 AU. Although the 2005 spectrum has better signal-to-noise than the combined 2006 spectra, the two are identical within the uncertainties, save for changes in the thermal continuum. It is not clear why there is spectral variability in the near-infrared and not the longer wavelengths. One possible explanation is that the mineralogy across Hidalgo's surface is similar but some areas have been affected differently by space weathering, i.e., one or more collisions may have exposed fresh material on some of Hidalgo's surface.

  2. Stimulated emission from spherical particles - thermal stability of PTES-derived hybrid materials -

    Science.gov (United States)

    Yano, Tetsuji; Kitajima, Takahiro; Araya, Akinori; Shibata, Shuichi

    2002-10-01

    The effects of heat treatment on the optical quality of organic-norganic hybrid spherical particles were investigated. The spherical particles with a diameter of 6μm were prepared via sol-gel process from phenyl-tetraethyl-silane(PTES) using the vibrating orifice technique, and they showed strong oscillation signals based on the spherical resonance mode with low power threshold of the incident CW-Ar+ laser. Against the heat treatment on the slide glass plate, there were some particles which remained their spherical shape after 400°C heating depending on the condition of sol preparation. The survived particles were also found to have high photo-stability that they were not damaged from the laser irradiation of 514.5nm Ar+ light with a power >120mW/particle, while as-prepared particles were bursted by the irradiation <20mW/particles. From the measurements of micro Raman scattering spectroscopy, optical and secondary electron microscope and thermal analysis, the thermal stability of hybrid materials was considered.

  3. NC-TEST: noncontact thermal emissions screening technique for drug and alcohol detection

    Science.gov (United States)

    Prokoski, Francine J.

    1997-01-01

    Drug abuse is highly correlated with criminal behavior. The typical drug-using criminal commits hundreds of crimes per year. The crime rate cannot be significantly reduced without a reduction in the percentage of the population abusing drugs and alcohol. Accurate and timely estimation of that percentage is important for policy decisions concerning crime control, public health measures, allocation of intervention resources for prevention and treatment, projections of criminal justice needs, and the evaluation of policy effectiveness. Such estimation is particularly difficult because self reporting is unreliable; and physical testing has to date required blood or urine analysis which is expensive and invasive, with the result that too few people are tested. MIKOS Ltd. has developed a non-contact, passive technique with the potential for automatic, real- time screening for drug and alcohol use. The system utilizes thermal radiation which is spontaneously and continuously emitted by the human body. Facial thermal patterns and changes in patterns are correlated with standardized effects of specific drugs and alcohol. A portable system incorporating the collection and analysis technique can be used episodically to collect data for estimating drug and alcohol use by general unknown populations such as crowds at airports, or it can be used for repetitive routine screening of specific known groups such as airline pilots, military personnel, school children, or persons on probation or parole.

  4. Planck 2013 results. XI. All-sky model of thermal dust emission

    CERN Document Server

    Abergel, A; Aghanim, N; Alina, D; Alves, M I R; Armitage-Caplan, C; Arnaud, M; Ashdown, M; Atrio-Barandela, F; Aumont, J; Baccigalupi, C; Banday, A J; Barreiro, R B; Bartlett, J G; Battaner, E; Benabed, K; Benoît, A; Benoit-Lévy, A; Bernard, J -P; Bersanelli, M; Bielewicz, P; Bobin, J; Bock, J J; Bonaldi, A; Bond, J R; Borrill, J; Bouchet, F R; Boulanger, F; Bridges, M; Bucher, M; Burigana, C; Butler, R C; Cardoso, J -F; Catalano, A; Chamballu, A; Chary, R -R; Chiang, H C; Chiang, L -Y; Christensen, P R; Church, S; Clemens, M; Clements, D L; Colombi, S; Colombo, L P L; Combet, C; Couchot, F; Coulais, A; Crill, B P; Curto, A; Cuttaia, F; Danese, L; Davies, R D; Davis, R J; de Bernardis, P; de Rosa, A; de Zotti, G; Delabrouille, J; Delouis, J -M; Désert, F -X; Dickinson, C; Diego, J M; Dole, H; Donzelli, S; Doré, O; Douspis, M; Dupac, X; Efstathiou, G; Enßlin, T A; Eriksen, H K; Falgarone, E; Finelli, F; Forni, O; Frailis, M; Fraisse, A A; Franceschi, E; Galeotta, S; Ganga, K; Ghosh, T; Giard, M; Giardino, G; Giraud-Héraud, Y; González-Nuevo, J; Górski, K M; Gratton, S; Gregorio, A; Grenier, I A; Gruppuso, A; Guillet, V; Hansen, F K; Hanson, D; Harrison, D; Helou, G; Henrot-Versillé, S; Hernández-Monteagudo, C; Herranz, D; Hildebrandt, S R; Hivon, E; Hobson, M; Holmes, W A; Hornstrup, A; Hovest, W; Huffenberger, K M; Jaffe, A H; Jaffe, T R; Jewell, J; Joncas, G; Jones, W C; Juvela, M; Keihänen, E; Keskitalo, R; Kisner, T S; Knoche, J; Knox, L; Kunz, M; Kurki-Suonio, H; Lagache, G; Lähteenmäki, A; Lamarre, J -M; Lasenby, A; Laureijs, R J; Lawrence, C R; Leonardi, R; León-Tavares, J; Lesgourgues, J; Levrier, F; Liguori, M; Lilje, P B; Linden-Vørnle, M; López-Caniego, M; Lubin, P M; Macías-Pérez, J F; Maffei, B; Maino, D; Mandolesi, N; Maris, M; Marshall, D J; Martin, P G; Martínez-González, E; Masi, S; Massardi, M; Matarrese, S; Matthai, F; Mazzotta, P; McGehee, P; Melchiorri, A; Mendes, L; Mennella, A; Migliaccio, M; Mitra, S; Miville-Deschênes, M -A; Moneti, A; Montier, L; Morgante, G; Mortlock, D; Munshi, D; Murphy, J A; Naselsky, P; Nati, F; Natoli, P; Netterfield, C B; Nørgaard-Nielsen, H U; Noviello, F; Novikov, D; Novikov, I; Osborne, S; Oxborrow, C A; Paci, F; Pagano, L; Pajot, F; Paladini, R; Paoletti, D; Pasian, F; Patanchon, G; Perdereau, O; Perotto, L; Perrotta, F; Piacentini, F; Piat, M; Pierpaoli, E; Pietrobon, D; Plaszczynski, S; Pointecouteau, E; Polenta, G; Ponthieu, N; Popa, L; Poutanen, T; Pratt, G W; Prézeau, G; Prunet, S; Puget, J -L; Rachen, J P; Reach, W T; Rebolo, R; Reinecke, M; Remazeilles, M; Renault, C; Ricciardi, S; Riller, T; Ristorcelli, I; Rocha, G; Rosset, C; Roudier, G; Rowan-Robinson, M; Rubiño-Martín, J A; Rusholme, B; Sandri, M; Santos, D; Savini, G; Scott, D; Seiffert, M D; Shellard, E P S; Spencer, L D; Starck, J -L; Stolyarov, V; Stompor, R; Sudiwala, R; Sunyaev, R; Sureau, F; Sutton, D; Suur-Uski, A -S; Sygnet, J -F; Tauber, J A; Tavagnacco, D; Terenzi, L; Toffolatti, L; Tomasi, M; Tristram, M; Tucci, M; Tuovinen, J; Türler, M; Umana, G; Valenziano, L; Valiviita, J; Van Tent, B; Vielva, P; Villa, F; Vittorio, N; Wade, L A; Wandelt, B D; Welikala, N; Yvon, D; Zacchei, A; Zonca, A

    2014-01-01

    This paper presents an all-sky model of dust emission from the Planck 857, 545 and 353 GHz, and IRAS 100 micron data. Using a modified black-body fit to the data we present all-sky maps of the dust optical depth, temperature, and spectral index over the 353-3000 GHz range. This model is a tight representation of the data at 5 arcmin. It shows variations of the order of 30 % compared with the widely-used model of Finkbeiner, Davis, and Schlegel. The Planck data allow us to estimate the dust temperature uniformly over the whole sky, providing an improved estimate of the dust optical depth compared to previous all-sky dust model, especially in high-contrast molecular regions. An increase of the dust opacity at 353 GHz, tau_353/N_H, from the diffuse to the denser interstellar medium (ISM) is reported. It is associated with a decrease in the observed dust temperature, T_obs, that could be due at least in part to the increased dust opacity. We also report an excess of dust emission at HI column densities lower than...

  5. Densified biomass can cost-effectively mitigate greenhouse gas emissions and address energy security in thermal applications.

    Science.gov (United States)

    Wilson, Thomas O; McNeal, Frederick M; Spatari, Sabrina; G Abler, David; Adler, Paul R

    2012-01-17

    Regional supplies of biomass are currently being evaluated as feedstocks in energy applications to meet renewable portfolio (RPS) and low carbon fuel standards. We investigate the life cycle greenhouse gas (GHG) emissions and associated abatement costs resulting from using densified switchgrass for thermal and electrical energy. In contrast to the large and positive abatement costs for using biomass in electricity generation ($149/Mg CO(2)e) due to the low cost of coal and high feedstock and power plant operation costs, abatement costs for replacing fuel oil with biomass in thermal applications are large and negative (-$52 to -$92/Mg CO(2)e), resulting in cost savings. Replacing fuel oil with biomass in thermal applications results in least cost reductions compared to replacing coal in electricity generation, an alternative that has gained attention due to RPS legislation and the centralized production model most often considered in U.S. policy. Our estimates indicate a more than doubling of liquid fuel displacement when switchgrass is substituted for fuel oil as opposed to gasoline, suggesting that, in certain U.S. locations, such as the northeast, densified biomass would help to significantly decarbonize energy supply with regionally sourced feedstock, while also reducing imported oil. On the basis of supply projections from the recently released Billion Ton Report, there will be enough sustainably harvested biomass available in the northeast by 2022 to offset the entirety of heating oil demand in the same region. This will save NE consumers between $2.3 and $3.9 billion annually. Diverting the same resource to electricity generation would cost the region $7.7 billion per year. While there is great need for finding low carbon substitutes for coal power and liquid transportation fuels in the U.S., we argue that in certain regions it makes cost- (and GHG mitigation-) effective sense to phase out liquid heating fuels with locally produced biomass first.

  6. Centuries of thermal sea-level rise due to anthropogenic emissions of short-lived greenhouse gases.

    Science.gov (United States)

    Zickfeld, Kirsten; Solomon, Susan; Gilford, Daniel M

    2017-01-24

    Mitigation of anthropogenic greenhouse gases with short lifetimes (order of a year to decades) can contribute to limiting warming, but less attention has been paid to their impacts on longer-term sea-level rise. We show that short-lived greenhouse gases contribute to sea-level rise through thermal expansion (TSLR) over much longer time scales than their atmospheric lifetimes. For example, at least half of the TSLR due to increases in methane is expected to remain present for more than 200 y, even if anthropogenic emissions cease altogether, despite the 10-y atmospheric lifetime of this gas. Chlorofluorocarbons and hydrochlorofluorocarbons have already been phased out under the Montreal Protocol due to concerns about ozone depletion and provide an illustration of how emission reductions avoid multiple centuries of future TSLR. We examine the "world avoided" by the Montreal Protocol by showing that if these gases had instead been eliminated in 2050, additional TSLR of up to about 14 cm would be expected in the 21st century, with continuing contributions lasting more than 500 y. Emissions of the hydrofluorocarbon substitutes in the next half-century would also contribute to centuries of future TSLR. Consideration of the time scales of reversibility of TSLR due to short-lived substances provides insights into physical processes: sea-level rise is often assumed to follow air temperature, but this assumption holds only for TSLR when temperatures are increasing. We present a more complete formulation that is accurate even when atmospheric temperatures are stable or decreasing due to reductions in short-lived gases or net radiative forcing.

  7. First hard X-ray detection of the non-thermal emission around the Arches cluster: morphology and spectral studies with NuSTAR

    DEFF Research Database (Denmark)

    Krivonos, Roman A.; Tomsick, John A.; Bauer, Franz E.

    2014-01-01

    The Arches cluster is a young, densely packed massive star cluster in our Galaxy that shows a high level of star formation activity. The nature of the extended non-thermal X-ray emission around the cluster remains unclear. The observed bright Fe Ku line emission at 6.4 keV from material that is n......The Arches cluster is a young, densely packed massive star cluster in our Galaxy that shows a high level of star formation activity. The nature of the extended non-thermal X-ray emission around the cluster remains unclear. The observed bright Fe Ku line emission at 6.4 keV from material...... that is neutral or in a low ionization state can be produced either by X-ray photoionization or by cosmic-ray particle bombardment or both. In this paper, we report on the first detection of the extended emission around the Arches cluster above 10 keV with the NuSTAR mission, and present results on its morphology...... and spectrum. The spatial distribution of the hard X-ray emission is found to be consistent with the broad region around the cluster where the 6.4 keV line is observed. The interpretation of the hard X-ray emission within the context of the X-ray reflection model puts a strong constraint on the luminosity...

  8. Generation and Use of Thermal Energy in the Industrial Sector and Opportunities to Reduce its Carbon Emissions

    Energy Technology Data Exchange (ETDEWEB)

    McMillan, Colin [National Renewable Energy Lab. (NREL), Golden, CO (United States); Boardman, Richard [Idaho National Lab. (INL), Idaho Falls, ID (United States); McKellar, Michael [Idaho National Lab. (INL), Idaho Falls, ID (United States); Sabharwall, Piyush [Idaho National Lab. (INL), Idaho Falls, ID (United States); Ruth, Mark [National Renewable Energy Lab. (NREL), Golden, CO (United States); Bragg-Sitton, Shannon [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2016-09-01

    Changes are occurring throughout the U.S. economy, especially in regard to how energy is generated and used in the electricity, buildings, industrial, and transportation sectors. These changes are being driven by environmental and energy security concerns and by economics. The electric-sector market share of natural gas and variable renewable generation, such as wind and solar photovoltaics (PV), continues to grow. The buildings sector is evolving to meet efficiency standards, the transportation sector is evolving to meet efficiency and renewable fuels standards, and the industrial sector is evolving to reduce emissions. Those changes are driving investment and utilization strategies for generation and other assets. Nuclear and renewable energy sources are important to consider in the energy sector’s evolution because both are considered to be clean and non-carbon-emitting energy sources. The Idaho National Laboratory (INL) and the National Renewable Energy Laboratory (NREL) are jointly investigating potential synergies between technologies exploiting nuclear and renewable energy sources. The two laboratories have held several joint workshops since 2011. Those workshops brought together experts in both areas to identify synergies and potential opportunities to work together. Workshop participants identified nuclear-renewable hybrid energy systems (N-R HESs) as one of the opportunities and recommended investigating whether N-R HESs could both generate dispatchable electricity without carbon emissions and provide clean energy to industrial processes. They also recommended analyzing the potential for N-R HESs to provide dispatchable capacity to a grid with high penetrations of non-dispatchable resources and to investigate whether real inertia provided by thermal power cycles within N-R HESs provides value to the grid. This report is one of a series of reports INL and NREL are producing to investigate the technical and economic aspects of N-R HESs. Previous reports

  9. Transport in organic semiconductors in large electric fields: From thermal activation to field emission

    Science.gov (United States)

    Worne, J. H.; Anthony, J. E.; Natelson, D.

    2010-02-01

    Understanding charge transport in organic semiconductors in large electric fields is relevant to many applications. We present transport measurements in organic field-effect transistors based on poly(3-hexylthiophene) and 6,13-bis(triisopropyl-silylethynyl) (TIPS) pentacene with short channels, from room temperature down to 4.2 K. Near 300 K transport in both systems is well described by thermally assisted hopping with Poole-Frenkel-type enhancement of the mobility. At low temperatures and large gate voltages, transport in both materials becomes nearly temperature independent, crossing over into field-driven tunneling. These data, particularly in TIPS-pentacene, show that great caution must be exercised when considering more exotic (e.g., Tomonaga-Luttinger liquid) interpretations of transport.

  10. Dose dependence and thermal stability of the thermoluminescence emission in inorganic dust from mint and camomile

    Science.gov (United States)

    Gómez-Ros, J. M.; Furetta, C.; Cruz-Zaragoza, E.; Lis, M.; Torres, A.; Monsivais, G.

    2006-10-01

    The inorganic phase extracted from mint and camomile samples obtained from commercial products in Mexico was selected according to different grain sizes and exposed to 60Co gamma radiation at different doses in the range 0.5-12 kGy. Thermoluminescence (TL) glow curves show a single broad peak, centred around 175 °C for prompt readouts. X-ray diffraction analysis indicates the inorganic dust is mainly composed by quartz, Na,K-feldspars and amphiboles, which use to be characterized by TL emissions associated to continuous distribution of trapping centres. The high fading of the TL signal during the first days of storage at room temperature can be related to the shallowest part of the distribution while the deepest traps originate the asymptotic behaviour for longer storage times. The TL intensity also increases significatively with the grain size, being linear with the absorbed dose at least up to 10 kGy.

  11. Venus - The 17- to 38-micron spectrum. [atmospheric thermal emission spectrum

    Science.gov (United States)

    Reed, R. A.; Forrest, W. J.; Houck, J. R.; Pollack, J. B.

    1978-01-01

    A far-IR emission spectrum of Venus covering the wavelength range from 17 to 38 microns is examined which was obtained on five nights at an altitude of 14 km with the 30-cm telescope of the NASA Lear Jet. The spectrum is found to be characterized by an overall continuum level with noticeable absorption shortward of 20 microns and longward of 30 microns as compared with a 245-K blackbody. The continuum level is taken as implying a continuous source of opacity in the Venusian atmosphere over the entire range from 17 to 38 microns with increased opacity shortward of 20 microns and longward of 30 microns. It is shown that a haze of sulfuric acid droplets can provide the necessary opacity and explain the observed depressions. A pressure level of roughly 200 mb is deduced for this spectrum.

  12. Thick Thermal Barrier Coatings (TTBCs) for Low Emission, High Efficiency Diesel Engine Components

    Energy Technology Data Exchange (ETDEWEB)

    M. Brad Beardsley, Caterpillar Inc.; Dr. Darrell Socie, University of Illinois; Dr. Ed Redja, University of Illinois; Dr. Christopher Berndt, State University of New York at Stony Brook

    2006-03-02

    The objective of this program was to advance the fundamental understanding of thick thermal barrier coating (TTBC) systems for application to low heat rejection diesel engine combustion chambers. Previous reviews of thermal barrier coating technology concluded that the current level of understanding of coating system behavior is inadequate and the lack of fundamental understanding may impede the application of thermal barrier coating to diesel engines.(1) Areas of TTBC technology examined in this program include powder characteristics and chemistry; bond coating composition, coating design, microstructure and thickness as they affect properties, durability, and reliability; and TTBC "aging" effects (microstructural and property changes) under diesel engine operating conditions. Fifteen TTBC ceramic powders were evaluated. These powders were selected to investigate the effects of different chemistries, different manufacturing methods, lot-to-lot variations, different suppliers and varying impurity levels. Each of the fifteen materials has been sprayed using 36 parameters selected by a design of experiments (DOE) to determine the effects of primary gas (Ar and N2), primary gas flow rate, voltage, arc current, powder feed rate, carrier gas flow rate, and spraying distance. The deposition efficiency, density, and thermal conductivity of the resulting coatings were measured. A coating with a high deposition efficiency and low thermal conductivity is desired from an economic standpoint. An optimum combination of thermal conductivity and disposition efficiency was found for each lot of powder in follow-on experiments and disposition parameters were chosen for full characterization.(2) Strengths of the optimized coatings were determined using 4-point bending specimens. The tensile strength was determined using free-standing coatings made by spraying onto mild steel substrates which were subsequently removed by chemical etching. The compressive strengths of the coatings

  13. NATURE OF UNRESOLVED COMPLEX MIXTURE IN SIZE-DISTRIBUTED EMISSIONS FROM RESIDENTIAL WOOD COMBUSTION AS MEASURED BY THERMAL DESORPTION-GAS CHROMATOGRAPHY-MASS SPECTROMETRY

    Science.gov (United States)

    In this study, the unresolved complex mixture (UCM) in size resolved fine aerosol emissions from residential wood combustion (RWC) is examined. The aerosols are sorted by size in an electrical low-pressure impactor (ELPI) and subsequently analyzed by thermal desorbtion/gas chroma...

  14. DISSECTING THE POWER SOURCES OF LOW-LUMINOSITY EMISSION-LINE GALAXY NUCLEI VIA COMPARISON OF HST-STIS AND GROUND-BASED SPECTRA

    Energy Technology Data Exchange (ETDEWEB)

    Constantin, Anca; Castillo, Christopher A. [Department of Physics and Astronomy, James Madison University, Harrisonburg, VA 22807 (United States); Shields, Joseph C. [Department of Physics and Astronomy, Ohio University, Athens, OH 45701 (United States); Ho, Luis C. [Kavli Institute for Astronomy and Astrophysics, Peking University, Beijing 100871 (China); Barth, Aaron J. [Department of Physics and Astronomy, University of California, Irvine, CA 92697-4575 (United States); Filippenko, Alexei V. [Department of Astronomy, University of California, Berkeley, CA 94720-3411 (United States)

    2015-12-01

    Using a sample of ∼100 nearby line-emitting galaxy nuclei, we have built the currently definitive atlas of spectroscopic measurements of Hα and neighboring emission lines at subarcsecond scales. We employ these data in a quantitative comparison of the nebular emission in Hubble Space Telescope (HST) and ground-based apertures, which offer an order-of-magnitude difference in contrast, and provide new statistical constraints on the degree to which transition objects and low-ionization nuclear emission-line regions (LINERs) are powered by an accreting black hole at ≲10 pc. We show that while the small-aperture observations clearly resolve the nebular emission, the aperture dependence in the line ratios is generally weak, and this can be explained by gradients in the density of the line-emitting gas: the higher densities in the more nuclear regions potentially flatten the excitation gradients, suppressing the forbidden emission. The transition objects show a threefold increase in the incidence of broad Hα emission in the high-resolution data, as well as the strongest density gradients, supporting the composite model for these systems as accreting sources surrounded by star-forming activity. The narrow-line LINERs appear to be the weaker counterparts of the Type 1 LINERs, where the low accretion rates cause the disappearance of the broad-line component. The enhanced sensitivity of the HST observations reveals a 30% increase in the incidence of accretion-powered systems at z ≈ 0. A comparison of the strength of the broad-line emission detected at different epochs implies potential broad-line variability on a decade-long timescale, with at least a factor of three in amplitude.

  15. GNASH: a preequilibrium, statistical nuclear-model code for calculation of cross sections and emission spectra. [In FORTRAN for CDC 7600

    Energy Technology Data Exchange (ETDEWEB)

    Young, P.G.; Arthur, E.D.

    1977-11-01

    A new multistep Hauser--Feshbach code that includes corrections for preequilibrium effects is described. The code can calculate up to 60 decay reactions (cross sections and energy spectra) in one computation, and thereby provide considerable flexibility for handling processes with complicated reaction chains. Input parameter setup, problem output, and subroutine descriptions are given along with a sample problem calculation. A brief theoretical description is also included. 8 figures, 3 tables.

  16. Thermophysical Properties of Cold- and Vacuum Plasma-Sprayed Cu-Cr-X Alloys, NiAl and NiCrAlY Coatings I: Electrical and Thermal Conductivity, Thermal Diffusivity, and Total Hemispherical Emissivity

    Science.gov (United States)

    Raj, S. V.

    2017-10-01

    This two-part paper reports the thermophysical properties of several cold- and vacuum plasma-sprayed monolithic Cu- and Ni-based alloy coatings. Part I presents the electrical and thermal conductivity, thermal diffusivity, and total hemispherical emissivity data, while Part II reports the specific heat capacity data for these coatings. Metallic copper alloys and stoichiometric NiAl and NiCrAlY coatings were fabricated by either the cold spray or the vacuum plasma spray deposition processes for thermal property measurements between 77 and 1223 K. The temperature dependencies of the thermal conductivities, thermal diffusivities, electrical conductivities, and total hemispherical emissivities of these cold- and vacuum-sprayed monolithic coatings are reported in this paper. The electrical and thermal conductivity data correlate reasonably well for Cu-8%Cr-1%Al, Cu-23%Cr-5%Al, and NiAl in accordance with the Wiedemann-Franz (WF) law although a better fit is obtained using the Smith-Palmer relationship. The Lorentz numbers determined from the WF law are close to the theoretical value.

  17. Thermophysical Properties of Cold- and Vacuum Plasma-Sprayed Cu-Cr-X Alloys, NiAl and NiCrAlY Coatings I: Electrical and Thermal Conductivity, Thermal Diffusivity, and Total Hemispherical Emissivity

    Science.gov (United States)

    Raj, S. V.

    2017-11-01

    This two-part paper reports the thermophysical properties of several cold- and vacuum plasma-sprayed monolithic Cu- and Ni-based alloy coatings. Part I presents the electrical and thermal conductivity, thermal diffusivity, and total hemispherical emissivity data, while Part II reports the specific heat capacity data for these coatings. Metallic copper alloys and stoichiometric NiAl and NiCrAlY coatings were fabricated by either the cold spray or the vacuum plasma spray deposition processes for thermal property measurements between 77 and 1223 K. The temperature dependencies of the thermal conductivities, thermal diffusivities, electrical conductivities, and total hemispherical emissivities of these cold- and vacuum-sprayed monolithic coatings are reported in this paper. The electrical and thermal conductivity data correlate reasonably well for Cu-8%Cr-1%Al, Cu-23%Cr-5%Al, and NiAl in accordance with the Wiedemann-Franz (WF) law although a better fit is obtained using the Smith-Palmer relationship. The Lorentz numbers determined from the WF law are close to the theoretical value.

  18. Thermophysical Properties of Cold and Vacuum Plasma Sprayed Cu-Cr-X Alloys, NiAl and NiCrAlY Coatings. Part 1; Electrical and Thermal Conductivity, Thermal Diffusivity, and Total Hemispherical Emissivity

    Science.gov (United States)

    Raj, S. V.

    2017-01-01

    This two-part paper reports the thermophysical properties of several cold and vacuum plasma sprayed monolithic Cu and Ni-based alloy coatings. Part I presents the electrical and thermal conductivity, thermal diffusivity, and total hemispherical emissivity data while Part II reports the specific heat capacity data for these coatings. Metallic copper alloys, stoichiometric NiAl and NiCrAlY coatings were fabricated by either the cold sprayed or the vacuum plasma spray deposition processes for thermal property measurements between 77 and 1223 K. The temperature dependencies of the thermal conductivities, thermal diffusivities, electrical conductivities and total hemispherical emissivities of these cold and vacuum sprayed monolithic coatings are reported in this paper. The electrical and thermal conductivity data correlate reasonably well for Cu-8%Cr-1%Al, Cu-23%Cr-5%Al and NiAl in accordance with the Wiedemann-Franz (WF) law although a better fit is obtained using the Smith-Palmer relationship. The Lorentz numbers determined from the WF law are close to the theoretical value.

  19. Effect of the design of the active region of monolithic multi-color LED heterostructures on their spectra and emission efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Tsatsulnikov, A. F., E-mail: andrew@beam.ioffe.ru; Lundin, W. V.; Sakharov, A. V.; Zavarin, E. E.; Usov, S. O.; Nikolaev, A. E.; Sinitsyn, M. A. [Russian Academy of Sciences, Ioffe Physical–Technical Institute (Russian Federation); Cherkashin, N. A. [CEMES-CNRS–Université de Toulouse (France); Karpov, S. Y. [STR Group–Soft-Impact OOO (Russian Federation)

    2015-11-15

    The design features of light-emitting-diode heterostructures with a monolithic InGaN/GaN active region containing several InGaN quantum wells (QWs) emitting at different wavelengths, grown by metal-organic chemical vapor deposition, are studied. It is shown that the number of emission bands can be raised to three by increasing the number of deposited InGaN QWs with different indium contents. The emission efficiency decreases by approximately 30% with increasing number of QWs at high currents. The dependences of the optical properties of the heterostructures on the number of QWs and types of barriers between the QWs (GaN layer or InGaN/GaN short-period superlattice) are analyzed. It is demonstrated that the ratio between the intensities of the emission lines widely varies with current flowing through the structure and greatly depends on the type and width of the barriers between the QWs.

  20. Sensing Properties of a Novel Temperature Sensor Based on Field Assisted Thermal Emission.

    Science.gov (United States)

    Pan, Zhigang; Zhang, Yong; Cheng, Zhenzhen; Tong, Jiaming; Chen, Qiyu; Zhang, Jianpeng; Zhang, Jiaxiang; Li, Xin; Li, Yunjia

    2017-02-27

    The existing temperature sensors using carbon nanotubes (CNTs) are limited by low sensitivity, complicated processes, or dependence on microscopy to observe the experimental results. Here we report the fabrication and successful testing of an ionization temperature sensor featuring non-self-sustaining discharge. The sharp tips of nanotubes generate high electric fields at relatively low voltages, lowering the work function of electrons emitted by CNTs, and thereby enabling the safe operation of such sensors. Due to the temperature effect on the electron emission of CNTs, the collecting current exhibited an exponential increase with temperature rising from 20 °C to 100 °C. Additionally, a higher temperature coefficient of 0.04 K-1 was obtained at 24 V voltage applied on the extracting electrode, higher than the values of other reported CNT-based temperature sensors. The triple-electrode ionization temperature sensor is easy to fabricate and converts the temperature change directly into an electrical signal. It shows a high temperature coefficient and good application potential.

  1. Sensing Properties of a Novel Temperature Sensor Based on Field Assisted Thermal Emission

    Directory of Open Access Journals (Sweden)

    Zhigang Pan

    2017-02-01

    Full Text Available The existing temperature sensors using carbon nanotubes (CNTs are limited by low sensitivity, complicated processes, or dependence on microscopy to observe the experimental results. Here we report the fabrication and successful testing of an ionization temperature sensor featuring non-self-sustaining discharge. The sharp tips of nanotubes generate high electric fields at relatively low voltages, lowering the work function of electrons emitted by CNTs, and thereby enabling the safe operation of such sensors. Due to the temperature effect on the electron emission of CNTs, the collecting current exhibited an exponential increase with temperature rising from 20 °C to 100 °C. Additionally, a higher temperature coefficient of 0.04 K−1 was obtained at 24 V voltage applied on the extracting electrode, higher than the values of other reported CNT-based temperature sensors. The triple-electrode ionization temperature sensor is easy to fabricate and converts the temperature change directly into an electrical signal. It shows a high temperature coefficient and good application potential.

  2. Effect of Thermal Treatment on Fractals in Acoustic Emission of Rock Material

    Directory of Open Access Journals (Sweden)

    Z. Z. Zhang

    2016-01-01

    Full Text Available Acoustic emission (AE series on time and location distributions on space are all fractal during the failure process of rock material. In this paper, AE signals of heated rock samples at different temperature under uniaxial compression were captured, and the correlation fractal dimensions (CFDs of AE counts series at different stress level were calculated using Grassberger-Procaccia algorithm. The temperature effect on AE fractal behavior was revealed. The results show that as the heat temperature increases, the total AE counts are more, while the peak value is less. With the increase of external loading, the AE CFD increases fast to a peak at first and then decreases to a bottom and, after that, increases again but within a narrow range. 200°C and 800°C are two thresholds. As the heat temperature rises, the maximum CFD value and the corresponding stress level both increase from 25°C to 200°C and decrease from 200°C to 800°C and then increase again from 800°C to 1200°C. The CFD value at the failure point shows polynomial decline with rising heat temperature.

  3. Synthesis, crystal growth, thermal studies and scaled quantum chemical studies of structural and vibrational spectra of the highly efficient organic NLO crystal: 1-(4-Aminophenyl)-3-(3,4-dimethoxyphenyl)-prop-2-en-1-one

    Energy Technology Data Exchange (ETDEWEB)

    Joseph, Lynnette [Department of Physics, Bishop Moore College, Mavelikara, Alappuzha 690110, Kerala (India); Department of Physics, C.M.S College, Kottayam 686001, Kerala (India); Sajan, D., E-mail: dsajand@gmail.com [Department of Physics, Bishop Moore College, Mavelikara, Alappuzha 690110, Kerala (India); Shettigar, Venkataraya [Department of Physics, Gokhale Centenary College, Ankola 581 314, Karnataka (India); Chaitanya, K. [Key Laboratory of Soft Chemistry and Functional Materials of MOE, School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094 (China); Misra, Neeraj [Department of Physics, University of Lucknow, Lucknow 22607 (India); Sundius, Tom [Department of Physics, University of Helsinki, P.O. Box 64, FIN-00014 Helsinki (Finland); Němec, I. [Charles University in Prague, Faculty of Science, Department of Inorganic Chemistry, Hlavova 8, 128 40 Prague 2 (Czech Republic)

    2013-08-15

    A new chalcone derivative, 1-(4-aminophenyl)-3-(3,4-dimethoxyphenyl)-prop-2-en-1-one (DMAC) was synthesized and single crystals were grown by slow evaporation technique. The FT-Raman and FT-IR spectra of the sample were recorded in the region 3700–100 cm{sup −1} and 4000–400 cm{sup −1}, respectively. The spectra were interpreted with the aid of normal coordinate analysis following structure optimizations and force field calculations based on density functional theory (DFT) at the B3LYP/6-311+G(d,p) level of theory. Normal coordinate calculations were performed using the DFT force field, corrected by a recommended set of scaling factors, yielding fairly good agreement between the observed and calculated wavenumbers. DMAC is thermally stable up to 220.0 °C and optically transparent in the visible region. Information about the size, shape, charge density distribution and site of chemical reactivity of the molecule has been obtained by mapping electron density isosurface with electrostatic potential surfaces (ESP). The SHG efficiency of DMAC is observed to be 10 times that of standard urea crystal of identical particle size. - Highlights: • A chalcone derivative, DMAC has been synthesized and crystals are grown. • FT-IR and FT-Raman spectra, thermogravimetric and UV–Vis studies were carried out. • SHG effect from a centrosymmetric crystal has been reported.

  4. THEORETICAL SPECTRA OF TERRESTRIAL EXOPLANET SURFACES

    Energy Technology Data Exchange (ETDEWEB)

    Hu Renyu; Seager, Sara [Department of Earth, Atmospheric and Planetary Sciences, Massachusetts Institute of Technology, Cambridge, MA 02139 (United States); Ehlmann, Bethany L., E-mail: hury@mit.edu [Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125 (United States)

    2012-06-10

    We investigate spectra of airless rocky exoplanets with a theoretical framework that self-consistently treats reflection and thermal emission. We find that a silicate surface on an exoplanet is spectroscopically detectable via prominent Si-O features in the thermal emission bands of 7-13 {mu}m and 15-25 {mu}m. The variation of brightness temperature due to the silicate features can be up to 20 K for an airless Earth analog, and the silicate features are wide enough to be distinguished from atmospheric features with relatively high resolution spectra. The surface characterization thus provides a method to unambiguously identify a rocky exoplanet. Furthermore, identification of specific rocky surface types is possible with the planet's reflectance spectrum in near-infrared broad bands. A key parameter to observe is the difference between K-band and J-band geometric albedos (A{sub g}(K) - A{sub g}(J)): A{sub g}(K) - A{sub g}(J) > 0.2 indicates that more than half of the planet's surface has abundant mafic minerals, such as olivine and pyroxene, in other words primary crust from a magma ocean or high-temperature lavas; A{sub g}(K) - A{sub g}(J) < -0.09 indicates that more than half of the planet's surface is covered or partially covered by water ice or hydrated silicates, implying extant or past water on its surface. Also, surface water ice can be specifically distinguished by an H-band geometric albedo lower than the J-band geometric albedo. The surface features can be distinguished from possible atmospheric features with molecule identification of atmospheric species by transmission spectroscopy. We therefore propose that mid-infrared spectroscopy of exoplanets may detect rocky surfaces, and near-infrared spectrophotometry may identify ultramafic surfaces, hydrated surfaces, and water ice.

  5. Study of Thermal-Field Emission Properties and Investigation of Temperature dependent Noise in the Emission Current form vertical Carbon nanotube emitters

    KAUST Repository

    Kolekar, Sadhu

    2017-05-05

    We have investigated temperature dependent field electron emission characteristics of vertical carbon nanotubes (CNTs). The generalized expression for electron emission from well defined cathode surface is given by Millikan and Lauritsen [1] for the combination of temperature and electric field effect. The same expression has been used to explain the electron emission characteristics from vertical CNT emitters. Furthermore, this has been applied to explain the electron emission for different temperatures ranging from room temperature to 1500 K. The real-time field electron emission images at room temperature and 1500 K are recorded by using Charge Coupled Device (CCD), in order to understand the effect of temperature on electron emission spots in image morphology (as indicated by ring like structures) and electron emission spot intensity of the emitters. Moreover, the field electron emission images can be used to calculate the total number of emitters per cm2 for electron emission. The calculated number of emitters per cm2 is 4.5x107 and, the actual number emitters per cm2 present for electron emission calculated from Atomic Force Microscopy (AFM) data is 1.2x1012. The measured Current-Voltage (I-V) characteristics obey the Folwer-Nordheim (F-N) type behavior. The fluctuations in the emission current are recorded at different temperatures and, temperature dependence of power spectral density obeys power law relation s(f)=I2/f2 with that of emission current and frequency.

  6. X-ray spectra from magnetar candidates - III. Fitting SGR/AXP soft X-ray emission with non-relativistic Monte Carlo models

    NARCIS (Netherlands)

    Zane, S.; Rea, N.; Turolla, R.; Nobili, L.

    2009-01-01

    Within the magnetar scenario, the ‘twisted magnetosphere’ model appears very promising in explaining the persistent X-ray emission from soft gamma repeaters (SGRs) and anomalous X-ray pulsars (AXPs). In the first two papers of the series, we have presented a 3D Monte Carlo code for solving radiation

  7. Identification of Rocks and Their Quartz Content in Gua Musang Goldfield Using Advanced Spaceborne Thermal Emission and Reflection Radiometer Imagery

    Directory of Open Access Journals (Sweden)

    Kouame Yao

    2017-01-01

    Full Text Available Quartz is an important mineral element and the most abundant rock-forming mineral that controls the mineralogy of a reservoir. At the surface, quartz is more stable than most other rock minerals because it is made up of interlocking silica that makes it quite resistant to mechanical weathering. Quartz abundance is an indication of mineralization in many metal deposits; therefore, identification and mapping of quartz in rocks are of great value for exploration and resource potential assessments. In this study, thermal infrared (TIR bands of the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER imagery were used to identify quartz contained rocks in Gua Musang. First, the image was corrected for atmospheric effect and the study area subset for further processing. Thereafter, spectral transformation (principal component analysis (PCA was implemented on the TIR bands and the resulting principal component (PC images were analysed. The three optimal PCs were selected using the strength of spectral interaction and the eigenvalues of each band. To discriminate between quartz-rich and quartz-poor rocks, RGB false colour composite and greyscale image of one of the PCs were analysed. The result shows that volcanogenic igneous rock and carbonate sedimentary rocks of Permian formation are quartz-poor while Triassic sedimentary rock made up of organic particles and sandstone is quartz-rich. On the contrary, the quartz content in the metamorphic rock varies across the area but is richer in quartz content than the igneous and carbonate rocks. Classification of the composite image classified using maximum likelihood (ML supervised classification method produced overall accuracy and Kappa coefficient of 96.53%, and 0.95, respectively.

  8. Optical diagnostics of fullerene synthesis in the RF thermal plasma process

    Directory of Open Access Journals (Sweden)

    B. TODOROVIC-MARKOVIC

    2005-02-01

    Full Text Available In this work, the results of an optical emission study of fullerene synthesis in an inductively coupled radio frequency thermal plasma reactor are presented. The emission spectroscopy studies, based on the use of the Swan C2 (0,1 and CN (0,0 vibrational emission spectra, were carried out to determine the plasma temperature. The evaporation process of graphite powderwas observed by scanning electron microscopy.

  9. Time-dependent spectrum of thermionic emission from hot C{sub 60}

    Energy Technology Data Exchange (ETDEWEB)

    Bordas, C.; Baguenard, B.; Climen, B.; Lebeault, M.A.; Lepine, F.; Pagliarulo, F. [Lyon-1 Univ., Lab. de Spectrometrie Ionique et Moleculaire, CNRS UMR 5579, 69 - Villeurbanne (France)

    2005-07-01

    Experimental measurements of time-dependent photoelectron spectra observed in thermionic emission of hot C{sub 60} excited by multiphoton absorption are presented. Time resolved velocity-map imaging is used to record photoelectron spectra and to disentangle direct and delayed processes. The evolution of the kinetic energy distribution of thermal electrons as a function of the delay after multiphoton excitation is described within the general formalism of the detailed balance theory. Experimental spectra obtained in the near-UV are in excellent agreement with the assumption of thermal equilibrium. (authors)

  10. Absorption and Emission Spectroscopic Investigation of Thermal Dynamics and Photo-Dynamics of the Rhodopsin Domain of the Rhodopsin-Guanylyl Cyclase from the Nematophagous Fungus Catenaria anguillulae

    Directory of Open Access Journals (Sweden)

    Alfons Penzkofer

    2017-10-01

    Full Text Available The rhodopsin-guanylyl cyclase from the nematophagous fungus Catenaria anguillulae belongs to a recently discovered class of enzymerhodopsins and may find application as a tool in optogenetics. Here the rhodopsin domain CaRh of the rhodopsin-guanylyl cyclase from Catenaria anguillulae was studied by absorption and emission spectroscopic methods. The absorption cross-section spectrum and excitation wavelength dependent fluorescence quantum distributions of CaRh samples were determined (first absorption band in the green spectral region. The thermal stability of CaRh was studied by long-time attenuation measurements at room temperature (20.5 °C and refrigerator temperature of 3.5 °C. The apparent melting temperature of CaRh was determined by stepwise sample heating up and cooling down (obtained apparent melting temperature: 62 ± 2 °C. The photocycle dynamics of CaRh was investigated by sample excitation to the first inhomogeneous absorption band of the CaRhda dark-adapted state around 590 nm (long-wavelength tail, 530 nm (central region and 470 nm (short-wavelength tail and following the absorption spectra development during exposure and after exposure (time resolution 0.0125 s. The original protonated retinal Schiff base PRSBall-trans in CaRhda photo-converted reversibly to protonated retinal Schiff base PRSBall-trans,la1 with restructured surroundings (CaRhla1 light-adapted state, slightly blue-shifted and broadened first absorption band, recovery to CaRhda with time constant of 0.8 s and deprotonated retinal Schiff base RSB13-cis (CaRhla2 light-adapted state, first absorption band in violet to near ultraviolet spectral region, recovery to CaRhda with time constant of 0.35 s. Long-time light exposure of light-adapted CaRhla1 around 590, 530 and 470 nm caused low-efficient irreversible degradation to photoproducts CaRhprod. Schemes of the primary photocycle dynamics of CaRhda and the secondary photocycle dynamics of CaRhla1 are developed.

  11. Investigation of absorptance and emissivity of thermal control coatings on Mg–Li alloys and OES analysis during PEO process

    Science.gov (United States)

    Yao, Zhongping; Xia, Qixing; Ju, Pengfei; Wang, Jiankang; Su, Peibo; Li, Dongqi; Jiang, Zhaohua

    2016-01-01

    Thermal control ceramic coatings on Mg–Li alloys have been successfully prepared in silicate electrolyte system by plasma electrolytic oxidation (PEO) method. The PEO coatings are mainly composed of crystallized Mg2SiO4 and MgO, which have typical porous structure with some bulges on the surface; OES analysis shows that the plasma temperature, which is influenced by the technique parameters, determines the formation of the coatings with different crystalline phases and morphologies, combined with “quick cooling effect” by the electrolyte; and the electron concentration is constant, which is related to the electric spark breakdown, determined by the nature of the coating and the interface of coating/electrolyte. Technique parameters influence the coating thickness, roughness and surface morphology, but do not change the coating composition in the specific PEO regime, and therefore the absorptance (αS) and emissivity (ε) of the coatings can be adjusted by the technique parameters through changing thickness and roughness in a certain degree. The coating prepared at 10 A/dm2, 50 Hz, 30 min and 14 g/L Na2SiO3 has the minimum value of αS (0.35) and the maximum value of ε (0.82), with the balance temperature of 320 K. PMID:27383569

  12. Multi-parametric thermal sensing based on NIR emission of Ho(III) doped CaWO4 phosphors

    Science.gov (United States)

    Zhou, Xianju; Wang, Rongxue; Xiang, Guotao; Jiang, Sha; Li, Li; Luo, Xiaobing; Pang, Yu; Tian, Yili

    2017-04-01

    Optical thermometry based on trivalent rare earth doped materials has attracted much attention recently. This article reported the temperature dependent near infrared luminescence of Ho3+ doped in CaWO4 phosphors. A series of CaWO4:Ho3+ powders have been synthesized by high temperature solid state reaction. The XRD patterns showed that the Ho3+ ions have occupied the lattice sites of Ca2+ ions in the phosphors. The thermometry effect was demonstrated by different spectroscopic parameters through the emission intensity of Ho3+: 5I6 → 5I8 transition at ∼1190 nm, the spectral shift of the charge transfer band of W-O and the lifetime of Ho3+: 5F4, 5S2 excited state. These three optical parameters present a simple linear relation with the temperature in the range of 30-300 °C. This allows for accurate thermal sensing based on simultaneous measurement of these parameters. Results show that CaWO4:Ho3+ phosphors might be served as a potential candidate for thermometry.

  13. Vibrational spectra and lattice thermal conductivity of kesterite-structured Cu2ZnSnS4 and Cu2ZnSnSe4

    Science.gov (United States)

    Skelton, Jonathan M.; Jackson, Adam J.; Dimitrievska, Mirjana; Wallace, Suzanne K.; Walsh, Aron

    2015-04-01

    Cu2ZnSnS4 (CZTS) is a promising material for photovoltaic and thermoelectric applications. Issues with quaternary semiconductors include chemical disorder (e.g., Cu-Zn antisites) and disproportionation into secondary phases (e.g., ZnS and Cu2SnS3). To provide a reference for the pure kesterite structure, we report the vibrational spectra—including both infra-red and Raman intensities—from lattice-dynamics calculations using first-principles force constants. Three-phonon interactions are used to estimate phonon lifetimes (spectral linewidths) and thermal conductivity. CZTS exhibits a remarkably low lattice thermal conductivity, competitive with high-performance thermoelectric materials. Transition from the sulfide to selenide (Cu2ZnSnSe4) results in softening of the phonon modes and an increase in phonon lifetimes.

  14. INFRARED SPECTRA, THERMOGRAVIMETRIC ANALYSIS AND ...

    African Journals Online (AJOL)

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    characterized by melting point, molar conductivity, magnetic moment, elemental analysis, infrared spectra and thermal analyses. ... methyl-quinazolinone and the final products of the thermogravimetric analysis were recorded on a Perkin-Elmer FT-IR type ..... [Cu(CH3COO)(L)3]. CuO + 5C +12C2H2 + 4NO + NH3 + 0.5N2.

  15. Experimental study of emission Z-pinch spectra in the axial and radial directions at the Angara-5-1 facility

    Directory of Open Access Journals (Sweden)

    Alexandrov V.V.

    2017-01-01

    Full Text Available Data on the energy, power and spectra composition of the soft x-ray pulse of powerful Z-pinch plasmas in the axial and radial directions in the photon energy range of 0.02 - 2 keV are presented. The data are obtained from the analysis of experimental results on the implosion of cylindrical arrays with a diameter of 1.2 cm and a height of 1.6 cm of tungsten wires diameter of 6 μm, the linear mass of 220 μg/cm at a current in the range of 2.2 – 3.5 MA at the Angara-5-1 facility.

  16. Direct synthesis of Cu{sub 2}O-RGO nanocomposite on Cu foil by thermal evaporation method and its field emission study

    Energy Technology Data Exchange (ETDEWEB)

    Bansode, Sanjeewani; Khare, Ruchita; Harpale, Kashmira; Kolhe, Pankaj; More, Mahendra [Centre for Advanced Studies in Material Science and Solid State Physics, Department of Physics, University of Pune, Pune-411 007 (India)

    2015-06-24

    In this work, a facile one step thermal evaporation method for deposition of Cu{sub 2}O nanoparticles on RGO sheets to form Cu{sub 2}O-RGO nanocomposite is discussed. To the best of our knowledge, this is the first report on Cu{sub 2}O-RGO nanocomposite, directly grown on Cu foil by a simple thermal evaporation route. The as –prepared nanocomposite exhibits well dispersed Cu{sub 2}O nanoparticles distributed all over the graphene sheet. Field emission properties of the nanocomposite were investigated at a base pressure of 1*10{sup −8} torr. The turn on field, required to draw emission current density of 0.1µA/cm2, was found to be 3.8V/µm with a maximum emission current density of 80 µA/cm2 at an applied field of 6.8 V/µm. Moreover, the nanocomposite shows fairly good emission stability without significant degradation of emission current. The FE results seem to be encouraging, indicative of potential candidature of the Cu{sub 2}O-RGO nanocomposite emitter as an electron source for practical applications in vacuum nanoelectronic devices.

  17. Direct synthesis of Cu2O-RGO nanocomposite on Cu foil by thermal evaporation method and its field emission study

    Science.gov (United States)

    Bansode, Sanjeewani; Khare, Ruchita; Harpale, Kashmira; Kolhe, Pankaj; More, Mahendra

    2015-06-01

    In this work, a facile one step thermal evaporation method for deposition of Cu2O nanoparticles on RGO sheets to form Cu2O-RGO nanocomposite is discussed. To the best of our knowledge, this is the first report on Cu2O-RGO nanocomposite, directly grown on Cu foil by a simple thermal evaporation route. The as -prepared nanocomposite exhibits well dispersed Cu2O nanoparticles distributed all over the graphene sheet. Field emission properties of the nanocomposite were investigated at a base pressure of 1*10-8 torr. The turn on field, required to draw emission current density of 0.1µA/cm2, was found to be 3.8V/µm with a maximum emission current density of 80 µA/cm2 at an applied field of 6.8 V/µm. Moreover, the nanocomposite shows fairly good emission stability without significant degradation of emission current. The FE results seem to be encouraging, indicative of potential candidature of the Cu2O-RGO nanocomposite emitter as an electron source for practical applications in vacuum nanoelectronic devices

  18. Neutron spectra due (13)N production in a PET cyclotron.

    Science.gov (United States)

    Benavente, J A; Vega-Carrillo, H R; Lacerda, M A S; Fonseca, T C F; Faria, F P; da Silva, T A

    2015-05-01

    Monte Carlo and experimental methods have been used to characterize the neutron radiation field around PET (Positron Emission Tomography) cyclotrons. In this work, the Monte Carlo code MCNPX was used to estimate the neutron spectra, the neutron fluence rates and the ambient dose equivalent (H*(10)) in seven locations around a PET cyclotron during (13)N production. In order to validate these calculations, H*(10) was measured in three sites and were compared with the calculated doses. All the spectra have two peaks, one above 0.1MeV due to the evaporation neutrons and another in the thermal region due to the room-return effects. Despite the relatively large difference between the measured and calculated H*(10) for one point, the agreement was considered good, compared with that obtained for (18)F production in a previous work. Copyright © 2015 Elsevier Ltd. All rights reserved.

  19. Study of thermal-field emission properties and investigation of temperature dependent noise in the field emission current from vertical carbon nanotube emitters

    Science.gov (United States)

    Kolekar, Sadhu; Patole, S. P.; Patil, Sumati; Yoo, J. B.; Dharmadhikari, C. V.

    2017-10-01

    We have investigated temperature dependent field electron emission characteristics of vertical carbon nanotubes (CNTs). The generalized expression for electron emission from well-defined cathode surface is given by Millikan and Lauritsen [1] for the combination of temperature and electric field effect. The same expression has been used to explain the electron emission characteristics from vertical CNT emitters. Furthermore, this has been applied to explain the electron emission for different temperatures ranging from room temperature to 1500 K. The real-time field electron emission images at room temperature and 1500 K are recorded by using Charge Coupled Device (CCD) in order to understand the effect of temperature on distribution of electron emission spots and ring like structures in Field Emission Microscope (FEM) image. The FEM images could be used to calculate the total number of emitters per cm2 for electron emission. The calculated number of emitters per cm2 from FEM image is typically, 4.5 × 107 and the actual number emitters per cm2 present as per Atomic Force Microscopy (AFM) data is 1.2 × 1012. The measured Current-Voltage (I-V) characteristics exhibit non linear Folwer-Nordheim (F-N) type behavior. The fluctuations in the emission current were recorded at different temperatures and Fast Fourier transformed into temperature dependent power spectral density. The latter was found to obey power law relation S(f) = A(Iδ/fξ), where δ and ξ are temperature dependent current and frequency exponents respectively.

  20. Advances in photo-thermal infrared imaging microspectroscopy

    Science.gov (United States)

    Furstenberg, Robert; Kendziora, Chris; Papantonakis, Michael; Nguyen, Viet; McGill, Andrew

    2013-05-01

    There is a growing need for chemical imaging techniques in many fields of science and technology: forensics, materials science, pharmaceutical and chemical industries, just to name a few. While FTIR micro-spectroscopy is commonly used, its practical resolution limit of about 20 microns or more is often insufficient. Raman micro-spectroscopy provides better spatial resolution (~1 micron), but is not always practical because of samples exhibiting fluorescence or low Raman scattering efficiency. We are developing a non-contact and non-destructive technique we call photo-thermal infrared imaging spectroscopy (PT-IRIS). It involves photo-thermal heating of the sample with a tunable quantum cascade laser and measuring the resulting increase in thermal emission with an infrared detector. Photo-thermal emission spectra resemble FTIR absorbance spectra and can be acquired in both stand-off and microscopy configurations. Furthermore, PT-IRIS allows the acquisition of absorbance-like photo-thermal spectra in a reflected geometry, suitable for field applications and for in-situ study of samples on optically IR-opaque substrates (metals, fabrics, paint, glass etc.). Conventional FTIR microscopes in reflection mode measure the reflectance spectra which are different from absorbance spectra and are usually not catalogued in FTIR spectral libraries. In this paper, we continue developing this new technique. We perform a series of numerical simulations of the laser heating of samples during photo-thermal microscopy. We develop parameterized formulas to help the user pick the appropriate laser illumination power. We also examine the influence of sample geometry on spectral signatures. Finally, we measure and compare photo-thermal and reflectance spectra for two test samples.

  1. Ab Initio Potential Energy Surfaces for Both the Ground (X̃1A′ and Excited (A∼1A′′ Electronic States of HSiBr and the Absorption and Emission Spectra of HSiBr/DSiBr

    Directory of Open Access Journals (Sweden)

    Anyang Li

    2012-01-01

    Full Text Available Ab initio potential energy surfaces for the ground (X̃1A′ and excited (A˜A′′1 electronic states of HSiBr were obtained by using the single and double excitation coupled-cluster theory with a noniterative perturbation treatment of triple excitations and the multireference configuration interaction with Davidson correction, respectively, employing an augmented correlation-consistent polarized valence quadruple zeta basis set. The calculated vibrational energy levels of HSiBr and DSiBr of the ground and excited electronic states are in excellent agreement with the available experimental band origins. In addition, the absorption and emission spectra of HSiBr and DSiBr were calculated using an efficient single Lanczos propagation method and are in good agreement with the available experimental observations.

  2. Multidimensional Models of Type Ia Supernova Nebular Spectra: Strong Emission Lines from Stripped Companion Gas Rule Out Classic Single-degenerate Systems

    Science.gov (United States)

    Botyánszki, János; Kasen, Daniel; Plewa, Tomasz

    2018-01-01

    The classic single-degenerate model for the progenitors of Type Ia supernova (SN Ia) predicts that the supernova ejecta should be enriched with solar-like abundance material stripped from the companion star. Spectroscopic observations of normal SNe Ia at late times, however, have not resulted in definite detection of hydrogen. In this Letter, we study line formation in SNe Ia at nebular times using non-LTE spectral modeling. We present, for the first time, multidimensional radiative transfer calculations of SNe Ia with stripped material mixed in the ejecta core, based on hydrodynamical simulations of ejecta–companion interaction. We find that interaction models with main-sequence companions produce significant Hα emission at late times, ruling out these types of binaries being viable progenitors of SNe Ia. We also predict significant He I line emission at optical and near-infrared wavelengths for both hydrogen-rich or helium-rich material, providing an additional observational probe of stripped ejecta. We produce models with reduced stripped masses and find a more stringent mass limit of M st ≲ 1 × 10‑4 M ⊙ of stripped companion material for SN 2011fe.

  3. Evaluation of secondary and prompt fission neutron spectra

    Energy Technology Data Exchange (ETDEWEB)

    Porodzinskij, Yu.V.; Sukhovitskij, E.Sh. [Radiation Physics and Chemistry Problems Inst., Minsk-Sosny (Belarus)

    1997-03-01

    A simple model allowing to split neutron emission spectra into reaction partials is suggested. Predicted spectra of (n,n`{gamma}), (n,n`f), etc appear to be much harder than usually evaluated. (author)

  4. A mixed quantum-classical molecular dynamics study of anti-tetrol and syn-tetrol dissolved in liquid chloroform II: infrared emission spectra, vibrational excited-state lifetimes, and nonequilibrium hydrogen-bond dynamics.

    Science.gov (United States)

    Kwac, Kijeong; Geva, Eitan

    2013-11-21

    The effect of vibrational excitation and relaxation of the hydroxyl stretch on the hydrogen-bond structure and dynamics of stereoselectively synthesized syn-tetrol and anti-tetrol dissolved in deuterated chloroform are investigated via a mixed quantum-classical molecular dynamics simulation. Emphasis is placed on the changes in hydrogen-bond structure upon photoexcitation and the nonequilibrium hydrogen-bond dynamics that follows the subsequent relaxation from the excited to the ground vibrational state. The propensity to form hydrogen bonds is shown to increase upon photoexcitation of the hydroxyl stretch, thereby leading to a sizable red-shift of the infrared emission spectra relative to the corresponding absorption spectra. The vibrational excited state lifetimes are calculated within the framework of Fermi's golden rule and the harmonic-Schofield quantum correction factor, and found to be sensitive reporters of the underlying hydrogen-bond structure. The energy released during the relaxation from the excited to the ground state is shown to break hydrogen bonds involving the relaxing hydroxyl. The spectral signature of this nonequilibrium relaxation process is analyzed in detail.

  5. Analysis of the absorption spectra of gas emission of patients with lung cancer and chronic obstructive pulmonary disease by laser optoacoustic spectroscopy

    Science.gov (United States)

    Bukreeva, Ekaterina B.; Bulanova, Anna A.; Kistenev, Yurii V.; Kuzmin, Dmitry A.; Tuzikov, Sergei A.; Yumov, Evgenii L.

    2013-02-01

    It is important to identify patients with chronic obstructive pulmonary disease (COPD) and lung cancer in the early stages of the disease. The method of laser opto-acoustic gas analysis, in this case, can act as a promising tool for diagnostics. The material for this study were the gas emission samples collected from patients and healthy volunteers - samples of exhaled air, swabs from teeth and cheeks. A set of material was formed three groups: healthy volunteers, patients with COPD, lung cancer patients. The resulting samples were analyzed by means of laser opto-acoustic gas analyzers: with intracavity location detector (ILPA-1), with extracavity location detector (LGA-2). Presentation of the results in an easy to visual form was performed using the method of elastic maps, based on the principal component analysis. The results of analysis show potentialities of usage of laser optoacoustic spectroscopy application to assess the status of patients with chronic obstructive pulmonary disease and lung cancer.

  6. Emission mechanism of polyatomic ions Cs2Cl+ and Cs2BO2(+) in thermal ionization mass spectrometry with various carbon materials.

    Science.gov (United States)

    Wei, Hai-Zhen; Jiang, Shao-Yong; Hemming, Gary N; Yang, Jing-Hong; Xiao, Ying-Kai; Yang, Tao; Yan, Xiong; Yan, Yan

    2011-12-29

    The emission behavior of polyatomic ions Cs(2)Cl(+) and Cs(2)BO(2)(+) in the presence of various carbon materials (Graphite, Carbon, SWNTs, and Fullerenes) in the ionization source of thermal ionization mass spectrometry (TIMS) has been investigated. The emission capacity of various carbon materials are remarkably different as evidenced by the obvious discrepancy in signal intensity of polyatomic ions and accuracy/precision of boron and chlorine isotopic composition determined using Cs(2)Cl(+)-graphite-PTIMS/Cs(2)BO(2)(+)-graphite-PTIMS methods. Combined with morphology and microstructure properties of four selected carbon materials, it could be concluded that the emission behavior of the polyatomic ions strongly depends on the microstructure of the carbon materials used. A surface-induced collision mechanism for formation of such kinds of polyatomic ions in the ionization source of TIMS has been proposed based on the optimized configuration of Cs(2)BO(2)(+) and Cs(2)Cl(+) ions in the gas phase using a molecular dynamics method. The combination of the geometry of the selected carbon materials with the configuration of two polyatomic ions explains the structure effect of carbon materials on the emission behavior of polyatomic ions, where graphite samples with perfect parallels and equidistant layers ensure the capacity of emission to the maximum extent, and fullerenes worsen the emission of polyatomic ions by blocking their pathway. © 2011 American Chemical Society

  7. First Hard X-Ray Detection of the Non-Thermal Emission Around the Arches Cluster: Morphology and Spectral Studies With NuSTAR

    Science.gov (United States)

    Krivonos, Roman A.; Tomsick, John A.; Bauer, Franz E.; Baganoff, Frederick K.; Barriere, Nicolas M.; Bodaghee, Arash; Boggs, Steven E.; Christensen, Finn E.; Craig, William W.; Grefenstette, Brian W.; hide

    2014-01-01

    The Arches cluster is a young, densely packed massive star cluster in our Galaxy that shows a high level of star formation activity. The nature of the extended non-thermal X-ray emission around the cluster remains unclear. The observed bright Fe K(alpha) line emission at 6.4 keV from material that is neutral or in a low ionization state can be produced either by X-ray photoionization or by cosmic-ray particle bombardment or both. In this paper, we report on the first detection of the extended emission around the Arches cluster above 10 keV with the NuSTAR mission, and present results on its morphology and spectrum. The spatial distribution of the hard X-ray emission is found to be consistent with the broad region around the cluster where the 6.4 keV line is observed. The interpretation of the hard X-ray emission within the context of the X-ray reflection model puts a strong constraint on the luminosity of the possible illuminating hard X-ray source. The properties of the observed emission are also in broad agreement with the low-energy cosmic-ray proton excitation scenario. Key words: cosmic rays - Galaxy: center - ISM: general - X-rays: individual (Arches cluster)

  8. ZnO nanorod arrays prepared by chemical bath deposition combined with rapid thermal annealing: structural, photoluminescence and field emission characteristics

    Science.gov (United States)

    Chen, Hung-Wei; Yang, Hsi-Wen; He, Hsin-Min; Lee, Yi-Mu

    2016-01-01

    ZnO nanorod arrays were prepared by low temperature chemical bath deposition (CBD) combined with rapid thermal annealing (RTA) under different ambient conditions. The structure and morphology of the synthesized ZnO have been characterized by field-emission scanning electron microscopy (FESEM) and x-ray diffraction (XRD). The obtained ZnO samples are highly crystalline with a hexagonal wurtzite phase and also display well-aligned array structure. A pronounced effect on increased nanorod length was found for the RTA-treated ZnO as compared to the as-grown ZnO. Analysis of XRD indicates that the (0 0 2) feature peak of the as-grown ZnO was shifted towards a lower angle as compared to the peaks of RTA-treated ZnO samples due to the reduction of tensile strain along the c-axis by RTA. Photoluminescence (PL) studies reveal that the ZnO nanorod arrays receiving RTA in an O2 environment have the sharpest UV emission band and greatest intensity ratio of near band-edge emission (NBE) to deep level emission (DLE). Additionally, the effects of RTA on the field emission properties were evaluated. The results demonstrate that RTA an O2 environment can lower the turn-on field and improve the field enhancement factor. The stability of the field emission current was also tested for 4 h.

  9. Low-temperature heat capacities and Raman spectra of negative thermal expansion compounds ZrW2O8 and HfW2O8

    Science.gov (United States)

    Yamamura, Yasuhisa; Nakajima, Noriyuki; Tsuji, Toshihide; Koyano, Mikio; Iwasa, Yoshihiro; Katayama, Shin'ichi; Saito, Kazuya; Sorai, Michio

    2002-06-01

    Heat capacities of ZrW2O8 and HfW2O8 were precisely measured between 1.8 and 330 K. Heat-capacity curves of ZrW2O8 and HfW2O8 are very similar to each other. The heat capacity of HfW2O8 at low temperature is larger than that of ZrW2O8 due to atomic mass effect, but both heat capacities cross around 220 K. Raman spectra of ZrW2O8 and HfW2O8 were recorded at room temperature. Frequency distributions of lattice vibrations were estimated through an analysis of the heat capacities for ZrW2O8 and HfW2O8. It is found that the difference in the frequency distributions between ZrW2O8 and HfW2O8 arises from the different atomic mass and bond strength, and causes the different temperature dependence of the heat capacities. The properties of the optical-phonon modes with a large negative mode-Grüneisen parameter are discussed.

  10. Experimental and theoretical studies of the VUV emission and absorption spectra of H{sub 2}, HD and D{sub 2} molecules; Etude experimentale et theorique des spectres d'emission et d'absorption VUV des molecules H{sub 2}, D{sub 2} et HD

    Energy Technology Data Exchange (ETDEWEB)

    Roudjane, M

    2007-12-15

    The aim of this thesis is to carry out an experimental study of the absorption and emission spectra of the D{sub 2} and HD isotopes, with high resolution, in the VUV domain and to supplement it by a theoretical study of the excited electronic states involved in the observed transitions. The emission spectra of HD and D{sub 2} are produced by Penning discharge source operating under low pressure and are recorded in the spectral range 78 - 170 nm. The recorded spectra contains more than 20.000 lines. The analysis of the spectrum consists in identifying and assigning the lines to the electronic transitions between energy levels of the molecule. The present analysis is based on our theoretical calculations of the ro-vibrational energy levels of the excited electronic states and the transition probabilities from these states towards the energy levels of the fundamental state. The theoretical results are obtained by resolving the coupled equations between the excited electronic states B{sup 1}{sigma}{sub u}{sup 1}, B'{sup 1}{sigma}{sub u}{sup 1}, C{sup 1}{pi}{sub u}{sup 1} and D{sup 1}{pi}{sub u}{sup 1}, taking into account the nonadiabatic couplings between these states, and they are obtained in the adiabatic approximation for the excited electronic states B''B-bar{sup 1}{sigma}{sub u}{sup +}, D'{sup 1}{pi}{sub u}{sup 1} and D''{sup 1}{pi}{sub u}{sup 1}. The equations are resolved using a modern method based on the discretization variables representation method. In addition, we have carried out a study of the absorption spectra of the HD and D{sub 2} molecules.

  11. Thermal Hyperspectral Remote Sensing for Plant Species and Stress Detection

    Science.gov (United States)

    Schlerf, M.; Rock, G.; Ullah, S.; Gerhards, M.; Udelhoven, T.; Skidmore, A. K.

    2014-12-01

    Thermal infrared (TIR) spectroscopy offers a novel opportunity for measuring emissivity spectra of natural surfaces. Emissivity spectra are not directly measured, they first have to be retrieved from the raw measurements. Once retrieved, the spectra can be used, for example, to discriminate plant species or to detect plant stress. Knowledge of plant species distribution is essential for the sustainable management of ecosystems. Remote sensing of plant species has so far mostly been limited to data in the visible and near-infrared where, however, different species often reveal similar reflectance curves. Da Luz and Crowley showed in a recent paper that in the TIR plants indeed have distinct spectral features. Also with a certain species, subtle changes of emissivity in certain wavebands may occur, when biochemical compounds change due to osmotic adjustment induced by water stress. Here we show, that i) emissive imaging spectroscopy allows for reliable and accurate retrieval of plant emissivity spectra, ii) emissivity spectra are well suited to discriminate plant species, iii) a reduction in stomatal conductance (caused by stress) changes the thermal infrared signal. For 13 plant species in the laboratory and for 8 plant species in a field setup emissivity spectra were retrieved. A comparison shows, that for most species the shapes of the emissivity curves agree quite well, but that clear offsets between the two types of spectra exist. Discrimination analysis revealed that based on the lab spectra, 13 species could be distinguished with an average overall classification accuracy of 92% using the 6 best spectral bands. For the field spectra (8 species), a similar high OAA of 89% was achieved. Species discrimination is likely to be possible due to variations in the composition of the superficial epidermal layer of plant leaves and in internal chemical concentrations producing unique emissivity features. However, to date, which spectral feature is responsible for which

  12. Estimating eruption temperature from thermal emission spectra of lava fountain activity in the Erta'Ale (Ethiopia) volcano lava lake: Implications for observing Io's volcanoes

    Science.gov (United States)

    Davies, Ashley G.; Keszthelyi, Laszlo P.; McEwen, Alfred S.

    2011-01-01

    We have analysed high-spatial-resolution and high-temporal-resolution temperature measurements of the active lava lake at Erta'Ale volcano, Ethiopia, to derive requirements for measuring eruption temperatures at Io's volcanoes. Lava lakes are particularly attractive targets because they are persistent in activity and large, often with ongoing lava fountain activity that exposes lava at near-eruption temperature. Using infrared thermography, we find that extracting useful temperature estimates from remote-sensing data requires (a) high spatial resolution to isolate lava fountains from adjacent cooler lava and (b) rapid acquisition of multi-color data. Because existing spacecraft data of Io's volcanoes do not meet these criteria, it is particularly important to design future instruments so that they will be able to collect such data. Near-simultaneous data at more than two relatively short wavelengths (shorter than 1 μm) are needed to constrain eruption temperatures. Resolving parts of the lava lake or fountains that are near the eruption temperature is also essential, and we provide a rough estimate of the required image scale.

  13. Comprehensive thermal characterization using ruby R fluorescence lines of sapphire and GaNE{sub 2}-high Raman mode from Raman spectra in high-power flip-chip InGaN/GaN LEDs

    Energy Technology Data Exchange (ETDEWEB)

    Cui, M; Zhou, T F; Wang, M R; Huang, J; Huang, H J; Zhang, J P; Xu, K; Yang, H, E-mail: kxu2006@sinano.ac.cn, E-mail: tfzhou2007@sinano.ac.cn [Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou 215123 (China)

    2011-09-07

    A comprehensive temperature characterization method based on the GaNE{sub 2}-high Raman mode and sapphire ruby R fluorescence lines from Raman spectra was developed to analyse the thermal distribution and heat transfer process of high-power flip-chip InGaN/GaN LEDs (FC LEDs). Our analysis demonstrated that in addition to the known problem that the edges of mesa were always the hottest point of FC LEDs, which was due to the current crowding effect, a noteworthy temperature difference was first observed between the sapphire substrate and n-GaN when the injection current was above 300 mA. A 'heat reservoir' was suggested to occur at the interface between the sapphire and n-GaN due to poor thermal conductivity of sapphire when a large amount of heat from the hottest spot cannot be effectively transferred to the Si mount via the active region under high injection currents.

  14. Characterization of dynamic thermal control schemes and heat transfer pathways for incorporating variable emissivity electrochromic materials into a space suit heat rejection system

    Science.gov (United States)

    Massina, Christopher James

    The feasibility of conducting long duration human spaceflight missions is largely dependent on the provision of consumables such as oxygen, water, and food. In addition to meeting crew metabolic needs, water sublimation has long served as the primary heat rejection mechanism in space suits during extravehicular activity (EVA). During a single eight hour EVA, approximately 3.6 kg (8 lbm) of water is lost from the current suit. Reducing the amount of expended water during EVA is a long standing goal of space suit life support systems designers; but to date, no alternate thermal control mechanism has demonstrated the ability to completely eliminate the loss. One proposed concept is to convert the majority of a space suit's surface area into a radiator such that the local environment can be used as a radiative thermal sink for rejecting heat without mass loss. Due to natural variations in both internal (metabolic) loads and external (environmental) sink temperatures, radiative transport must be actively modulated in order to maintain an acceptable thermal balance. Here, variable emissivity electrochromic devices are examined as the primary mechanism for enabling variable heat rejection. This dissertation focuses on theoretical and empirical evaluations performed to determine the feasibility of using a full suit, variable emissivity radiator architecture for space suit thermal control. Operational envelopes are described that show where a given environment and/or metabolic load combination may or may not be supported by the evaluated thermal architecture. Key integration considerations and guidelines include determining allowable thermal environments, defining skin-to-radiator heat transfer properties, and evaluating required electrochromic performance properties. Analysis also considered the impacts of dynamic environmental changes and the architecture's extensibility to EVA on the Martian surface. At the conclusion of this work, the full suit, variable emissivity

  15. Measurement of muonium emission from silica aerogel

    CERN Document Server

    Bakule, P; Contreras, D; Esashi, M; Fujiwara, Y; Fukao, Y; Hirota, S; Iinuma, H; Ishida, K; Iwasaki, M; Kakurai, T; Kanda, S; Kawai, H; Kawamura, N; Marshall, G M; Masuda, H; Matsuda, Y; Mibe, T; Miyake, Y; Okada, S; Olchanski, K; Olin, A; Onishi, H; Saito, N; Shimomura, K; Strasser, P; Tabata, M; Tomono, D; Ueno, K; Yokoyama, K; Yoshida, S

    2013-01-01

    Emission of muonium ($\\mu^{+}e^{-}$) atoms from silica aerogel into vacuum was observed. Characteristics of muonium emission were established from silica aerogel samples with densities in the range from 29 mg cm$^{-3}$ to 178 mg cm$^{-3}$. Spectra of muonium decay times correlated with distances from the aerogel surfaces, which are sensitive to the speed distributions, follow general features expected from a diffusion process, while small deviations from a simple room-temperature thermal diffusion model are identified. The parameters of the diffusion process are deduced from the observed yields.

  16. Photobleaching response of different sources of chromophoric dissolved organic matter exposed to natural solar radiation using absorption and excitation-emission matrix spectra.

    Directory of Open Access Journals (Sweden)

    Yunlin Zhang

    Full Text Available CDOM biogeochemical cycle is driven by several physical and biological processes such as river input, biogeneration and photobleaching that act as primary sinks and sources of CDOM. Watershed-derived allochthonous (WDA and phytoplankton-derived autochthonous (PDA CDOM were exposed to 9 days of natural solar radiation to assess the photobleaching response of different CDOM sources, using absorption and fluorescence (excitation-emission matrix spectroscopy. Our results showed a marked decrease in total dissolved nitrogen (TDN concentration under natural sunlight exposure for both WDA and PDA CDOM, indicating photoproduction of ammonium from TDN. In contrast, photobleaching caused a marked increase in total dissolved phosphorus (TDP concentration for both WDA and PDA CDOM. Thus TDN:TDP ratios decreased significantly both for WDA and PDA CDOM, which partially explained the seasonal dynamic of TDN:TDP ratio in Lake Taihu. Photobleaching rate of CDOM absorption a(254, was 0.032 m/MJ for WDA CDOM and 0.051 m/MJ for PDA CDOM from days 0-9, indicating that phototransformations were initially more rapid for the newly produced CDOM from phytoplankton than for the river CDOM. Extrapolation of these values to the field indicated that 3.9%-5.1% CDOM at the water surface was photobleached and mineralized every day in summer in Lake Taihu. Photobleaching caused the increase of spectral slope, spectral slope ratio and molecular size, indicating the CDOM mean molecular weight decrease which was favorable to further microbial degradation of mineralization. Three fluorescent components were validated in parallel factor analysis models calculated separately for WDA and PDA CDOM. Our study suggests that the humic-like fluorescence materials could be rapidly and easily photobleached for WDA and PDA CDOM, but the protein-like fluorescence materials was not photobleached and even increased from the transformation of the humic-like fluorescence substance to the protein

  17. Photobleaching response of different sources of chromophoric dissolved organic matter exposed to natural solar radiation using absorption and excitation-emission matrix spectra.

    Science.gov (United States)

    Zhang, Yunlin; Liu, Xiaohan; Osburn, Christopher L; Wang, Mingzhu; Qin, Boqiang; Zhou, Yongqiang

    2013-01-01

    CDOM biogeochemical cycle is driven by several physical and biological processes such as river input, biogeneration and photobleaching that act as primary sinks and sources of CDOM. Watershed-derived allochthonous (WDA) and phytoplankton-derived autochthonous (PDA) CDOM were exposed to 9 days of natural solar radiation to assess the photobleaching response of different CDOM sources, using absorption and fluorescence (excitation-emission matrix) spectroscopy. Our results showed a marked decrease in total dissolved nitrogen (TDN) concentration under natural sunlight exposure for both WDA and PDA CDOM, indicating photoproduction of ammonium from TDN. In contrast, photobleaching caused a marked increase in total dissolved phosphorus (TDP) concentration for both WDA and PDA CDOM. Thus TDN:TDP ratios decreased significantly both for WDA and PDA CDOM, which partially explained the seasonal dynamic of TDN:TDP ratio in Lake Taihu. Photobleaching rate of CDOM absorption a(254), was 0.032 m/MJ for WDA CDOM and 0.051 m/MJ for PDA CDOM from days 0-9, indicating that phototransformations were initially more rapid for the newly produced CDOM from phytoplankton than for the river CDOM. Extrapolation of these values to the field indicated that 3.9%-5.1% CDOM at the water surface was photobleached and mineralized every day in summer in Lake Taihu. Photobleaching caused the increase of spectral slope, spectral slope ratio and molecular size, indicating the CDOM mean molecular weight decrease which was favorable to further microbial degradation of mineralization. Three fluorescent components were validated in parallel factor analysis models calculated separately for WDA and PDA CDOM. Our study suggests that the humic-like fluorescence materials could be rapidly and easily photobleached for WDA and PDA CDOM, but the protein-like fluorescence materials was not photobleached and even increased from the transformation of the humic-like fluorescence substance to the protein

  18. Changes throughout lactation in phenotypic and genetic correlations between methane emissions and milk fatty acid contents predicted from milk mid-infrared spectra.

    Science.gov (United States)

    Vanrobays, M-L; Bastin, C; Vandenplas, J; Hammami, H; Soyeurt, H; Vanlierde, A; Dehareng, F; Froidmont, E; Gengler, N

    2016-09-01

    The aim of this study was to estimate phenotypic and genetic correlations between methane production (Mp) and milk fatty acid contents of first-parity Walloon Holstein cows throughout lactation. Calibration equations predicting daily Mp (g/d) and milk fatty acid contents (g/100 dL of milk) were applied on milk mid-infrared spectra related to Walloon milk recording. A total of 241,236 predictions of Mp and milk fatty acids were used. These data were collected between 5 and 305 d in milk in 33,555 first-parity Holstein cows from 626 herds. Pedigree data included 109,975 animals. Bivariate (i.e., Mp and a fatty acid trait) random regression test-day models were developed to estimate phenotypic and genetic parameters of Mp and milk fatty acids. Individual short-chain fatty acids (SCFA) and groups of saturated fatty acids, SCFA, and medium-chain fatty acids showed positive phenotypic and genetic correlations with Mp (from 0.10 to 0.16 and from 0.23 to 0.30 for phenotypic and genetic correlations, respectively), whereas individual long-chain fatty acids (LCFA), and groups of LCFA, monounsaturated fatty acids, and unsaturated fatty acids showed null to positive phenotypic and genetic correlations with Mp (from -0.03 to 0.13 and from -0.02 to 0.32 for phenotypic and genetic correlations, respectively). However, these correlations changed throughout lactation. First, de novo individual and group fatty acids (i.e., C4:0, C6:0, C8:0, C10:0, C12:0, C14:0, SCFA group) showed low phenotypic or genetic correlations (or both) in early lactation and higher at the end of lactation. In contrast, phenotypic and genetic correlations between Mp and C16:0, which could be de novo synthetized or derived from blood lipids, were more stable during lactation. This fatty acid is the most abundant fatty acid of the saturated fatty acid and medium-chain fatty acid groups of which correlations with Mp showed the same pattern across lactation. Phenotypic and genetic correlations between Mp and C17

  19. Seasonal and Non-Seasonal Variations of Jupiter's Atmosphere from Observations of Thermal Emission, 1994-2011

    Science.gov (United States)

    Orton, G.; Fletcher, L.; Yanamandra-Fisher, P.; Greathouse, T.; Fisher, B.; Greco, J.; Wakefield, L.; Snead, E.; Boydstun, K.; Simon-Miller, A.; hide

    2012-01-01

    We analyzed mid-infrared images of Jupiter's thermal emission, covering approx.1.5 Jovian years, acquired in discrete filters between 7.8 and 24.5 microns. The behavior of stratospheric (approx.10-mbar) and tropospheric (approx.100-400 mbar) temperatures is generally consistent with predictions of seasonal variability, with differences between 100-mbar temperatures +/-50-60deg from the equator on the order of +/-2. Removing this effect, there appear to be long-term quasi-periodic variability of tropospheric temperatures, whose amplitude, phase and period depend on latitude. The behavior of temperatures in the Equatorial Zone (EZ) suggests a approx.4-6-year period with amplitude of about +/-1-1.5 K in temperature. At mid-latitudes, the periodicity is more distinct with amplitudes around +/-1.5-2.5 K and 4-8 year periods. The 4.2-year variation of stratospheric temperatures known as the quasiquadrennial oscillation or "QQO" (Leovy et al. 1991, Nature 354, 380) continued during this period. There were no variations of zonal mean temperatures associated with any of the "global upheaval" events that have produced dramatic changes of jupiter's visible appearance and cloud cover, although there are colder discrete regions associated with updrafts, e.g. the early stages of the re-darkening ("revival") of the South Equatorial Belt (SEB) in late 2010. On the other hand increases in the visible albedos ("fades") of belts are accompanied by increases in the thickness of a 700-mbar cloud layer (most likely NH3 ice) and clouds at higher pressures, together with the mixing ratio of NH3 gas near 400 mbar (above its condensation level). These quantities decrease during re-darkening ("revival") episodes, during which we note discrete features that are exceptions to the general correlation between dark albedos and minimal cloudiness. In contrast to all these changes, the meridional distribution of the 240-mbar para-H2 fraction appears to be invariant in time.

  20. Recommendations on the choice of gas analysis equipment for systems of continuous monitoring and accounting of emissions from thermal power plants

    Science.gov (United States)

    Kondrat'eva, O. E.; Roslyakov, P. V.; Burdyukov, D. A.; Khudolei, O. D.; Loktionov, O. A.

    2017-10-01

    According to Federal Law no. 219-FZ, dated July 21, 2014, all enterprises that have a significant negative impact on the environment shall continuously monitor and account emissions of harmful substances into the atmospheric air. The choice of measuring equipment that is included in continuous emission monitoring and accounting systems (CEM&ASs) is a complex technical problem; in particular, its solution requires a comparative analysis of gas analysis systems; each of these systems has its advantages and disadvantages. In addition, the choice of gas analysis systems for CEM&ASs should be maximally objective and not depend on preferences of separate experts and specialists. The technique of choosing gas analysis equipment that was developed in previous years at Moscow Power Engineering Institute (MPEI) has been analyzed and the applicability of the mathematical tool of a multiple criteria analysis to choose measuring equipment for the continuous emission monitoring and accounting system have been estimated. New approaches to the optimal choice of gas analysis equipment for systems of the continuous monitoring and accounting of harmful emissions from thermal power plants have been proposed, new criteria of evaluation of gas analysis systems have been introduced, and weight coefficients have been determined for these criteria. The results of this study served as a basis for the Preliminary National Standard of the Russian Federation "Best Available Technologies. Automated Systems of Continuous Monitoring and Accounting of Emissions of Harmful (Polluting) Substances from Thermal Power Plants into the Atmospheric Air. Basic Requirements," which was developed by the Moscow Power Engineering Institute, National Research University, in cooperation with the Council of Power Producers and Strategic Electric Power Investors Association and the All-Russia Research Institute for Materials and Technology Standardization.

  1. Reflectance and Emissivity Spectra of Graphite as Potential Darkening Agent for Mercury from the UV to the TIR and its Comparison to Remote Sensing Measurements from MESSENGER and MERTIS on BepiColombo

    Science.gov (United States)

    Maturilli, A.; Helbert, J.; D'Amore, M.; Ferrari, S.; Hiesinger, H.

    2016-12-01

    For long time Mercury was considered a planet very similar to the Moon. Both are small rocky bodies in the inner solar system with thin exospheres and no large scale traces of recent geological activity. However Mercury's surface reflects much less sunlight than the Moon. Trying to explain the reasons for this difference, significant abundances of iron and titanium (and their oxides) were proposed for the Hermean surface. But the NASA MESSENGER instruments found only small abundances of iron, confirming earlier ground-based spectroscopy observations, and virtually no titanium. Therefore neither of the elements can account for this diversity. New analysis of MESSENGER data acquired for the darkest regions of Mercury's surface suggest that the unknown darkening material could be carbon, in particular as the mineral graphite (Peplowski et al., 2016) whose abundance in the darker regions is predicted to be 1 to 3 wt% higher than the surroundings. At the Planetary Spectroscopy Laboratory (PSL) of the Institute of Planetary Research (DLR, Berlin) we measured reflectance spectra for several phase angles of graphite, from UV to TIR spectral range (0.2 to 20 µm). Samples have been measured fresh and then after successive steps of heating at 400°C in vacuum for 8 hours. Following the same procedure, reflectance spectra of Komatiite (chosen as Mercury surface simulant, after Maturilli et al., 2014) was measured alone and mixed with few % of graphite to reproduce the results from Peplowski et al (2016). The results from this experiment can be compared to the data acquired from the MDIS and the MASCS instrument onboard the NASA MESSENGER mission. The same set of samples has been measured in emissivity, in vacuum (board of the ESA BepiColombo Mercury Planetary Orbiter (MPO) scheduled for 2018.

  2. The Radio-optical Spectra of BL Lacs and Possible Relatives

    Science.gov (United States)

    Dennett-Thorpe, J.

    I consider the suggestion that, in a complete sample of flat-spectrum radio sources with available optical spectra (Marcha et al 1996), the strong emission line objects, or those with passive elliptical spectra are close relatives of the BL Lacs. New observations at four frequencies from 8 to 43GHz are presented, together with evidence for radio variability. Combined with other radio and optical data from the literature, we are able to construct the non-thermal SEDs and use these to address the questions: are the optically passive objects potentially `unrecognised' BL Lacs (either intrinsically weak and/or hidden by starlight)? What is the relationship between the surprising number of strong emission-line objects and the BL Lacs?

  3. Measurement and simulation of rotationally-resolved chemiluminescence spectra in flames

    Science.gov (United States)

    Brockhinke, A.; Krüger, J.; Heusing, M.; Letzgus, M.

    2012-06-01

    In recent years, there has been renewed interest in chemiluminescence, since it has been shown that these emissions can be used to determine flame parameters such as stoichiometry and heat release under some conditions. Even though the origin of these emissions has been known for a long time, little attention has been paid to the detailed analysis of the spectral structure. In this contribution, we present rotationally-resolved spectra of all important chemiluminescent emissions OH A-X, CH B-X, CH A-X, and C2 d-a in CH4/air flames. A numerical model based on the LASKIN ν 2 code has been developed that allows, for the first time, to accurately predict the shape of the measured spectra for all of these transitions. Reabsorption of chemiluminescence within the emitting flame is shown to be a major factor, affecting both intensity and structure of OH∗ spectra. Even in lab-scale flames, it might change the intensity of individual lines by a factor of 5. The shape of chemiluminescence spectra depends on several processes including initial state distribution and rotational and vibrational energy transfer (which, in turn, depend on the collisional environment and the temperature). It is shown that chemical reactions form OH∗ in highly excited states and that the number of collisions is not sufficient to equilibrate the initial distribution. Therefore, high apparent temperatures are necessary to describe the shape of the measured spectra. In contrast, CH∗ is formed with less excess energy and the spectral shape is very close to thermal. The rotational structure of C2^{*} is close to thermal equilibrium as well. Vibrational temperatures are, however, significantly higher than the flame temperature. Implications and perspectives for flame measurements are discussed.

  4. High-Resolution X-Ray Spectra of the Symbiotic Star SS73 17

    Science.gov (United States)

    Eze, R. N. C.; Luna, G. J. M.; Smith, R. K.

    2010-01-01

    SS73 17 was an innocuous Mira-type symbiotic star until the International Gamma-Ray Astrophysics Laboratory and Swift discovered its bright hard X-ray emission, adding it to the small class of "hard X-ray emitting symbiotics." Suzaku observations in 2006 then showed it emits three bright iron lines as well, with little to no emission in the 0.3-2.0 keV bandpass. We present here follow-up observations with the Chandra High Energy Transmission Grating and Suzaku that confirm the earlier detection of strong emission lines of Fe K(alpha) fluorescence, Fe XXV and Fe XXVI but also show significantly more soft X-ray emission. The high-resolution spectrum also shows emission lines of other highly ionized ions as Si xiv and possibly S XVI. In addition, a re-analysis of the 2006 Suzaku data using the latest calibration shows that the hard (15-50 keV) X-ray emission is brighter than previously thought and remains constant in both the 2006 and 2008 data. The G ratio calculated from the Fe xxv lines shows that these lines are thermal, not photoionized, in origin.With the exception of the hard X-ray emission, the spectra from both epochs can be fit using thermal radiation assuming a differential emission measure based on a cooling-flow model combined with a full and partial absorber. We show that acceptable fits can be obtained for all the data in the 1-10 keV band varying only the partial absorber. Based on the temperature and accretion rate, the thermal emission appears to be arising from the boundary layer between the accreting white dwarf and the accretion disk.

  5. Beyond hot Jupiters: Characterizing exoplanets below 1000 K with Spitzer and JWST emission spectroscopy

    Science.gov (United States)

    Benneke, Björn; Université de Montréal, Caltech, University of Arizona, Space Science Institute, UCSC, Harvard University

    2018-01-01

    Most thermal emission spectra of exoplanets to date have been obtained for the hot Jupiters with equilibrium temperatures above ~1500K due to their favorable eclipse depth in the NIR. Emission spectroscopy of colder planets, however, provides us with the important opportunity to understand cloud formation and atmospheric chemistry near the CH4/CO transition. In this talk, we will demonstrate JWST’s unique capabilities for these planets and discuss results from our ongoing Spitzer effort to study warm Neptunes and Jupiters.

  6. Toward Efficient and Metal-Free Emissive Devices: A Solution-Processed Host-Guest Light-Emitting Electrochemical Cell Featuring Thermally Activated Delayed Fluorescence.

    Science.gov (United States)

    Lundberg, Petter; Lindh, E Mattias; Tang, Shi; Edman, Ludvig

    2017-08-30

    The next generation of emissive devices should preferably be efficient, low-cost, and environmentally sustainable, and as such utilize all electrically generated excitons (both singlets and triplets) for the light emission, while being free from rare metals such as iridium. Here, we report on a step toward this vision through the design, fabrication, and operation of a host-guest light-emitting electrochemical cell (LEC) featuring an organic thermally activated delayed fluorescence (TADF) guest that harvests both singlet and triplet excitons for the emission. The rare-metal-free active material also consists of a polymeric electrolyte and a polymeric compatibilizer for the facilitation of a cost-efficient and scalable solution-based fabrication, and for the use of air-stable electrodes. We report that such TADF-LEC devices can deliver uniform green light emission with a maximum luminance of 228 cd m-2 when driven by a constant-current density of 770 A m-2, and 760 cd m-2 during a voltage ramp, which represents a one-order-of-magnitude improvement in comparison to previous TADF-emitting LECs.

  7. GeV γ-ray Emission Detected by Fermi-LAT Probably Associated with the Thermal Composite Supernova Remnant Kesteven 41 in a Molecular Environment

    Science.gov (United States)

    Liu, Bing; Chen, Yang; Zhang, Xiao; Zhang, Gao-Yuan; Xing, Yi; Pannuti, Thomas G.

    2015-08-01

    Hadronic emission from supernova remnant (SNR)-molecular cloud (MC) association systems has been widely regarded as a probe of shock-accelerated cosmic-ray protons. Here, we report on the detection of a γ-ray emission source with a significance of 24σ in 0.2-300 GeV, projected to lie to the northwest of the thermal composite SNR Kesteven 41, using 5.6 years of Fermi-Large Area Telescope (LAT) observation data. No significant long-term variability in the energy range 0.2-300 GeV is detected around this source. The 3σ error circle, 0.09° in radius, covers the 1720 MHz OH maser and is essentially consistent with the location of the VLSR˜ -50 km s-1 MC with which the SNR interacts. The source emission has an exponential cutoff power-law spectrum with a photon index of 1.9 ± 0.1 and a cutoff energy of 4.0+/- 0.9 GeV, and the corresponding 0.2-300 GeV luminosity is ˜ 1.3× 1036 erg s-1 at a distance of 12 kpc. There is no radio pulsar in the 3σ circle responsible for the high γ-ray luminosity. While the inverse Compton scattering scenario would lead to difficulty in the electron energy budget, the source emission can naturally be explained by the hadronic interaction between the relativistic protons accelerated by the shock of SNR Kesteven 41 and the adjacent northwestern MC. In this paper, we present a list of Galactic thermal composite SNRs detected at GeV γ-ray energies by Fermi-LAT.

  8. Investigating the effect of landfill leachates on the characteristics of dissolved organic matter in groundwater using excitation-emission matrix fluorescence spectra coupled with fluorescence regional integration and self-organizing map.

    Science.gov (United States)

    He, Xiao-Song; Fan, Qin-Dong

    2016-11-01

    For the purpose of investigating the effect of landfill leachate on the characteristics of organic matter in groundwater, groundwater samples were collected near and in a landfill site, and dissolved organic matter (DOM) was extracted from the groundwater samples and characterized by excitation-emission matrix (EEM) fluorescence spectra combined with fluorescence regional integration (FRI) and self-organizing map (SOM). The results showed that the groundwater DOM comprised humic-, fulvic-, and protein-like substances. The concentration of humic-like matter showed no obvious variation for all groundwater except the sample collected in the landfill site. Fulvic-like substance content decreased when the groundwater was polluted by landfill leachates. There were two kinds of protein-like matter in the groundwater. One kind was bound to humic-like substances, and its content did not change along with groundwater pollution. However, the other kind was present as "free" molecules or else bound in proteins, and its concentration increased significantly when the groundwater was polluted by landfill leachates. The FRI and SOM methods both can characterize the composition and evolution of DOM in the groundwater. However, the SOM analysis can identify whether protein-like moieties was bound to humic-like matter.

  9. Mercury Emissions Capture Efficiency with Activated Carbon Injection at a Russian Coal-Fired Thermal Power Plant

    Science.gov (United States)

    This EPA-led project, conducted in collaboration with UNEP, the Swedish Environmental Institute and various Russian Institutes, that demonstrates that the mercury emission control efficiencies of activated carbon injection technologies applied at a Russian power plant burning Rus...

  10. Planck early results. XX. New light on anomalous microwave emission from spinning dust grains

    DEFF Research Database (Denmark)

    Lähteenmäki, A.; Poutanen, T.; Natoli, P.

    2011-01-01

    Anomalous microwave emission (AME) has been observed by numerous experiments in the frequency range ~10-60 GHz. Using Planck maps and multi-frequency ancillary data, we have constructed spectra for two known AME regions: the Perseus and ρ Ophiuchi molecular clouds. The spectra are well fitted...... of the synchrotron, free-free, and thermal dust. We present spectra for two of the candidates; S140 and S235 are bright Hii regions that show evidence for AME, and are well fitted by spinning dust models. © ESO, 2011....

  11. Thermal carrier emission and nonradiative recombinations in nonpolar (Al,Ga)N/GaN quantum wells grown on bulk GaN

    Energy Technology Data Exchange (ETDEWEB)

    Corfdir, P.; Dussaigne, A.; Giraud, E.; Ganiere, J.-D.; Grandjean, N.; Deveaud-Pledran, B. [Institute of Condensed Matter Physics, Ecole Polytechnique Federale de Lausanne (EPFL), CH-1015 Lausanne (Switzerland); Teisseyre, H. [Institute of Physics, Polish Academy of Sciences, 02-668 Warsaw (Poland); Institute of High Pressure Physics, Polish Academy of Sciences, 01-142 Warsaw (Poland); Suski, T.; Grzegory, I. [Institute of High Pressure Physics, Polish Academy of Sciences, 01-142 Warsaw (Poland); Lefebvre, P. [Laboratoire Charles Coulomb - UMR5221 - CNRS - Universite Montpellier 2, 34095 Montpellier (France)

    2012-02-01

    We investigate, via time-resolved photoluminescence, the temperature-dependence of charge carrier recombination mechanisms in nonpolar (Al,Ga)N/GaN single quantum wells (QWs) grown via molecular beam epitaxy on the a-facet of bulk GaN crystals. We study the influence of both QW width and barrier Al content on the dynamics of excitons in the 10-320 K range. We first show that the effective lifetime of QW excitons {tau} increases with temperature, which is evidence that nonradiative mechanisms do not play any significant role in the low-temperature range. The temperature range for increasing {tau} depends on the QW width and Al content in the (Al,Ga)N barriers. For higher temperatures, we observe a reduction in the QW emission lifetime combined with an increase in the decay time for excitons in the barriers, until both exciton populations get fully thermalized. Based on analysis of the ratio between barrier and QW emission intensities, we demonstrate that the main mechanism limiting the radiative efficiency in our set of samples is related to nonradiative recombination in the (Al,Ga)N barriers of charge carriers that have been thermally emitted from the QWs.

  12. NEAR-INFRARED THERMAL EMISSION DETECTIONS OF A NUMBER OF HOT JUPITERS AND THE SYSTEMATICS OF GROUND-BASED NEAR-INFRARED PHOTOMETRY

    Energy Technology Data Exchange (ETDEWEB)

    Croll, Bryce [5525 Olund Road, Abbotsford, B.C. (Canada); Albert, Loic; Lafreniere, David [Département de physique, Université de Montréal, C.P. 6128 Succ. Centre-Ville, Montréal, QC, H3C 3J7 (Canada); Jayawardhana, Ray [Department of Physics and Astronomy, York University, Toronto, ON L3T 3R1 (Canada); Cushing, Michael [Department of Physics and Astronomy, The University of Toledo, 2801 West Bancroft Street, Toledo, OH 43606 (United States); Moutou, Claire [Canada-France-Hawaii Telescope Corporation, 65-1238 Mamalahoa Highway, Kamuela, HI 96743 (United States); Johnson, John Asher [Harvard-Smithsonian Center for Astrophysics, Institute for Theory and Computation, 60 Garden St, MS-51, Cambridge, MA 02138 (United States); Bonomo, Aldo S. [INAF-Osservatorio Astrofisico di Torino, via Osservatorio 20, I-10025 Pino Torinese (Italy); Deleuil, Magali [Aix Marseille University, CNRS, LAM (Laboratoire d' Astrophysique de Marseille), UMR 7326, F-13388 Marseille cedex 13 (France); Fortney, Jonathan, E-mail: croll@space.mit.edu [Department of Astronomy and Astrophysics, University of California, Santa Cruz, CA 95064 (United States)

    2015-03-20

    We present detections of the near-infrared thermal emission of three hot Jupiters and one brown dwarf using the Wide-field Infrared Camera (WIRCam) on the Canada-France-Hawaii Telescope (CFHT). These include Ks-band secondary eclipse detections of the hot Jupiters WASP-3b and Qatar-1b and the brown dwarf KELT-1b. We also report Y-band, K {sub CONT}-band, and two new and one reanalyzed Ks-band detections of the thermal emission of the hot Jupiter WASP-12b. We present a new reduction pipeline for CFHT/WIRCam data, which is optimized for high precision photometry. We also describe novel techniques for constraining systematic errors in ground-based near-infrared photometry, so as to return reliable secondary eclipse depths and uncertainties. We discuss the noise properties of our ground-based photometry for wavelengths spanning the near-infrared (the YJHK bands), for faint and bright stars, and for the same object on several occasions. For the hot Jupiters WASP-3b and WASP-12b we demonstrate the repeatability of our eclipse depth measurements in the Ks band; we therefore place stringent limits on the systematics of ground-based, near-infrared photometry, and also rule out violent weather changes in the deep, high pressure atmospheres of these two hot Jupiters at the epochs of our observations.

  13. Simulated Annealing Approach to the Temperature-Emissivity Separation Problem in Thermal Remote Sensing Part One: Mathematical Background

    CERN Document Server

    Morgan, John A

    2016-01-01

    The method of simulated annealing is adapted to the temperature-emissivity separation (TES) problem. A patch of surface at the bottom of the atmosphere is assumed to be a greybody emitter with spectral emissivity $\\epsilon(k)$ describable by a mixture of spectral endmembers. We prove that a simulated annealing search conducted according to a suitable schedule converges to a solution maximizing the $\\textit{A-Posteriori}$ probability that spectral radiance detected at the top of the atmosphere originates from a patch with stipulated $T$ and $\\epsilon(k)$. Any such solution will be nonunique. The average of a large number of simulated annealing solutions, however, converges almost surely to a unique Maximum A-Posteriori solution for $T$ and $\\epsilon(k)$. The limitation to a stipulated set of endmember emissivities may be relaxed by allowing the number of endmembers to grow without bound, and to be generic continuous functions of wavenumber with bounded first derivatives with respect to wavenumber.

  14. Improved peak shape fitting in alpha spectra.

    Science.gov (United States)

    Pommé, S; Caro Marroyo, B

    2015-02-01

    Peak overlap is a recurrent issue in alpha-particle spectrometry, not only in routine analyses but also in the high-resolution spectra from which reference values for alpha emission probabilities are derived. In this work, improved peak shape formulae are presented for the deconvolution of alpha-particle spectra. They have been implemented as fit functions in a spreadsheet application and optimum fit parameters were searched with built-in optimisation routines. Deconvolution results are shown for a few challenging spectra with high statistical precision. The algorithm outperforms the best available routines for high-resolution spectrometry, which may facilitate a more reliable determination of alpha emission probabilities in the future. It is also applicable to alpha spectra with inferior energy resolution. Copyright © 2014 The Authors. Published by Elsevier Ltd.. All rights reserved.

  15. China action of "Cleanup Plan for Polychlorinated Biphenyls Burial Sites": emissions during excavation and thermal desorption of a capacitor-burial site.

    Science.gov (United States)

    Yang, Bing; Zhou, Lingli; Xue, Nandong; Li, Fasheng; Wu, Guanglong; Ding, Qiong; Yan, Yunzhong; Liu, Bo

    2013-10-01

    Scarce data are available so far on emissions in a given scenario for excavation and thermal desorption, a common practice, of soils contaminated with polychlorinated biphenyls (PCBs). As part of China action of "Cleanup Plan for PCBs Burial Sites", this study roughly estimated PCBs emissions in the scenario for a capacitor-burial site. The concentrations of total PCBs (22 congeners) in soils were in the range of 2.1-16,000μg/g with a mean of 2300μg/g, among the same order of magnitude as the highest values obtained in various PCBs-contaminated sites. Only six congeners belonging to Di-, Tri-, and Tetra-CBs were observed above limits of detection in air samples in the scenario, partially which can be estimated by the USEPA air emission model. Comparing concentrations and composition profiles of PCBs in the soil and air samples further indicated a leaked source of commercial PCBs formulations of trichlorobiphenyl (China PCB no. 1). The measures taken if any to mitigate the volatilization and movement of PCBs and to minimize worker exposure were discussed for improvements of the excavation practice. Copyright © 2013 Elsevier Inc. All rights reserved.

  16. Life cycle inventory analysis of regenerative thermal oxidation of air emissions from oriented strand board facilities in Minnesota - a perspective of global climate change

    Energy Technology Data Exchange (ETDEWEB)

    Nicholson, W.J. [Potlatch Corp., San Francisco, CA (United States)

    1997-12-31

    Life cycle inventory analysis has been applied to the prospective operation of regenerative thermal oxidation (RTO) technology at oriented strand board plants at Bemidji (Line 1) and Cook, Minnesota. The net system destruction of VOC`s and carbon monoxide, and at Cook a small quantity of particulate, has a very high environmental price in terms of energy and water use, global warming potential, sulfur and nitrogen oxide emissions, solids discharged to water, and solid waste deposited in landfills. The benefit of VOC destruction is identified as minor in terms of ground level ozone at best and possibly slightly detrimental. Recognition of environmental tradeoffs associated with proposed system changes is critical to sound decision-making. There are more conventional ways to address carbon monoxide emissions than combustion in RTO`s. In an environment in which global warming is a concern, fuel supplemental combustion for environmental control does not appear warranted. Consideration of non-combustion approaches to address air emission issues at the two operations is recommended. 1 ref., 5 tabs.

  17. Improved peak shape fitting in alpha spectra

    OpenAIRE

    POMME Stefaan; CARO MARROYO BELEN

    2014-01-01

    Peak overlap is a recurrent issue ina lpha-particle spectrometry, not only in routine analyses but also in the high-resolution spectra from which reference values for alpha emission probabilities are derived. In this work, improved peak shape formulae are presented for the deconvolution of alpha-particle spectra. They have been implemented as fit functions in a spreadsheet application and optimum fit parameters were searched with built-in optimisation routines. Deconvolution results are shown...

  18. Selection and Characterization of Interesting Grism Spectra

    OpenAIRE

    Meurer, G. R.

    2006-01-01

    Observations with the ACS Wide Field Camera and G800L grism can produce thousands of spectra within a single WFC field producing a potentially rich treasure trove of information. However, the data are complicated to deal with. Here we describe algorithms to find and characterize spectra of emission line galaxies and supernovae using tools we have developed in conjunction with off the shelf software.

  19. Analysis of the radiative thermal transfer in planar multi-layer systems with various emissivity and transmissivity properties

    OpenAIRE

    Spanulescu, Sever

    2010-01-01

    The paper analyzes the radiative thermal transfer in a liquid helium cryostat with liquid nitrogen shielding. A infinite plane walls model is used for demonstrating a method for lowering the radiative heat transfer and the numerical results for two such systems are presented. Some advantages concerning the opportunity of using semi-transparent walls are analytically and numerically demonstrated.

  20. First LOFAR observations at very low frequencies of cluster-scale non-thermal emission : The case of Abell 2256

    NARCIS (Netherlands)

    van Weeren, R. J.; Rottgering, H. J. A.; Rafferty, D. A.; Pizzo, R.; Bonafede, A.; Brueggen, M.; Brunetti, G.; Ferrari, C.; Orru, E.; Heald, G.; McKean, J. P.; Tasse, C.; de Gasperin, F.; Birzan, L.; van Zwieten, J.E.; van der Tol, S.; Shulevski, A.; Jackson, N.; Offringa, A. R.; Conway, J.; Intema, H. T.; Clarke, T. E.; van Bemmel, Ilse; Miley, G. K.; White, G. J.; Hoeft, M.; Cassano, R.; Macario, G.; Morganti, R.; Wise, M. W.; Horellou, C.; Valentijn, E. A.; Wucknitz, O.; Kuijken, Koenraad; Ensslin, T. A.; Anderson, J.; Asgekar, A.; Avruch, I. M.; Beck, R.; Bell, M. E.; Bell, M. R.; Bentum, M. J.; Bernardi, G.; Best, P.; Boonstra, A-J; Brentjens, Michiel; van de Brink, R. H.; Broderick, J.; Brouw, W. N.; Butcher, H. R.; van Cappellen, W.; Ciardi, B.; Eisloeffel, J.; Falcke, H.; Fender, R.; Garrett, M. A.; Gerbers, M.; Gunst, A.; van Haarlem, M. P.; Hamaker, J. P.; Hassall, T.; Hessels, J. W. T.; Koopmans, L. V. E.; Kuper, G.; van Leeuwen, J.; Maat, P.; Millenaar, R.; Munk, H.; Nijboer, R.; Noordam, J. E.; Pandey, V. N.; Pandey-Pommier, M.; Polatidis, A.; Reich, W.; Scaife, A. M. M.; Schoenmakers, A.; Sluman, J.; Stappers, B. W.; Steinmetz, M.; Swinbank, J.; Tagger, M.; Tang, Y.; Vermeulen, R.; de Vos, M.

    Abell 2256 is one of the best known examples of a galaxy cluster hosting large-scale diffuse radio emission that is unrelated to individual galaxies. It contains both a giant radio halo and a relic, as well as a number of head-tail sources and smaller diffuse steep-spectrum radio sources. The origin

  1. Planck intermediate results. XX. Comparison of polarized thermal emission from Galactic dust with simulations of MHD turbulence

    DEFF Research Database (Denmark)

    Cardoso, J. F.; Delabrouille, J.; Ganga, K.

    2015-01-01

    Polarized emission observed by Planck HFI at 353 GHz towards a sample of nearby fields is presented, focusing on the statistics of polarization fractions p and angles ψ. The polarization fractions and column densities in these nearby fields are representative of the range of values obtained over ...

  2. Rotational analysis and deperturbation of the A2Π → X2Σ+ and B‧2Σ+ → X2Σ+ emission spectra of MgD

    Science.gov (United States)

    Motallebipour, Maryam S.; Shayesteh, Alireza

    2017-11-01

    High resolution Fourier transform emission spectra of MgD radical were analyzed, and the A2Π → X2Σ+ bands with v‧ = 2 and v‧ = 3 were rotationally assigned. Several local perturbations were observed in the A2Π and B‧2Σ+ excited states of 24MgD, and a deperturbation analysis was carried out using an appropriate Hamiltonian matrix containing off-diagonal terms connecting the vibrational levels of the two states. Dunham coefficients and band constants were determined for the A2Π and B‧2Σ+ states, along with off-diagonal parameters. The equilibrium vibrational constants ωe and ωexe have been determined to be 1155.040(6) and 16.764(4) cm-1, respectively, for the A2Π state, and 598.108(11) and 6.394(8) cm-1, for the B‧2Σ+ state. The equilibrium Mg-D distances were found to be 1.67819(3) Å and 2.59355(2) Å for the A2Π and B‧2Σ+ states, respectively. RKR potential curves were constructed for the A2Π and B‧2Σ+ states, and vibrational radial overlap integrals were computed for the perturbed levels. The off-diagonal matrix elements coupling the electronic wavefunctions of the A2Π and B‧2Σ+ states were determined independently for MgD to be a+ = 18.9 ± 0.2 cm-1 and b = 0.694 ± 0.005, in excellent agreement with those for the MgH isotopologue.

  3. Utilization of biodiesel from castor oil in gas micro turbines: thermal performance testing and emissions; Utilizacao do biodiesel de mamona em microturbinas a gas: testes de desempenho termico e emissoes

    Energy Technology Data Exchange (ETDEWEB)

    Nascimento, Marco Antonio R.; Lora, Electo Silva; Venturini, Osvaldo Jose; Maldonado, Manuel Rendon; Andrade, Rubenildo Viera; Correa Junior, Paulo Sergio Pedroso [Universidade Federal de Itajuba (UNIFEI), MG (Brazil)], Emails: marcoantonio@unifei.edu.br, electo@unifei.edu.br, osvaldo@unifei.edu.br, nrendon@unifei.edu.br, ruben@unifei.edu.br, paulocorrea@unifei.edu.br; Leite, Marco Antonio Haikal [Centro de Pesquisas Leopoldo Americo Miguez de Mello (CENPES/PETROBRAS), Rio de Janeiro, RJ (Brazil)], Email: mahaikal@petrobras.com.br

    2006-07-01

    The operation of power equipment such as a gas micro-turbine using renewable fuels is an interesting alternative when sustainability is concerned, mainly in isolated areas with abundant availability of fuels that come from biomass. Within this scenario, this article presents the results of tests regarding thermal performance and emissions of a gas micro-turbine operating with Diesel and bio diesel mixtures, showing the influence of the use of this fuel on the thermal behavior of the machine and on the emissions of gases such as CO, NO{sub x} and SO{sub 2}. The results of the experimental tests are shown in graphs, from where it can be observed that the bio diesel and its mixtures do not change the thermal behavior of the micro-turbine significantly, and at the same time, they may considerably reduce the emission of gaseous pollutants. (author)

  4. Hydrothermal alteration maps of the central and southern Basin and Range province of the United States compiled from Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data

    Science.gov (United States)

    Mars, John L.

    2013-01-01

    Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data and Interactive Data Language (IDL) logical operator algorithms were used to map hydrothermally altered rocks in the central and southern parts of the Basin and Range province of the United States. The hydrothermally altered rocks mapped in this study include (1) hydrothermal silica-rich rocks (hydrous quartz, chalcedony, opal, and amorphous silica), (2) propylitic rocks (calcite-dolomite and epidote-chlorite mapped as separate mineral groups), (3) argillic rocks (alunite-pyrophyllite-kaolinite), and (4) phyllic rocks (sericite-muscovite). A series of hydrothermal alteration maps, which identify the potential locations of hydrothermal silica-rich, propylitic, argillic, and phyllic rocks on Landsat Thematic Mapper (TM) band 7 orthorectified images, and geographic information systems shape files of hydrothermal alteration units are provided in this study.

  5. Advanced Spaceborne Thermal Emission and Reflection Radiometer Level 1 Precision Terrain Corrected Registered At-Sensor Radiance (AST_L1T) Product, algorithm theoretical basis document

    Science.gov (United States)

    Meyer, David; Siemonsma, Dawn; Brooks, Barbara; Johnson, Lowell

    2015-09-15

    This document provides an overview of the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) supplemental algorithms in conjunction with the reuse of Landsat geometric algorithms modified by the National Aeronautics and Space Administration (NASA Land Processes Distributed Active Archive Center (LP DAAC) to create an ASTER Level 1 Precision Terrain Corrected Registered At-Sensor Radiance (AST_L1T) product. Implementation of these algorithms occurs within the AST_L1T product generation executable (PGE) as part of the open source Simple, Scalable, Script-based Science Processor for Missions (S4PM) processing software subsystem. The AST_L1T algorithms include the following: Generation of the AST_L1A input product via supplemental algorithms

  6. Slope adjustment of runoff curve number (CN) using Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) Global Digital Elevation Model (GDEM) for Kuantan River Basin

    Science.gov (United States)

    Akbari, Abolghasem

    2015-10-01

    The Natural Resources Conservation Service Curve Number (NRCS-CN) method is widely used for predicting direct runoff from rainfall. It employs the hydrologic soil groups and landuse information along with period soil moisture conditions to derive NRCS-CN. This method has been well documented and available in popular rainfall-runoff models such as HEC-HMS, SWAT, SWMM and many more. The Sharply-Williams and Hank methods was used to adjust CN values provided in standard table of TR-55. The Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) Global Digital Elevation Model (GDEM) is used to derive slope map with spatial resolution of 30 m for Kuantan River Basin (KRB). The two investigated method stretches the conventional CN domain to the lower values. The study shows a successful application of remote sensing data and GIS tools in hydrological studies. The result of this work can be used for rainfall-runoff simulation and flood modeling in KRB.

  7. Thermal infrared spectroscopy and modeling of experimentally shocked plagioclase feldspars

    Science.gov (United States)

    Johnson, J. R.; Horz, F.; Staid, M.I.

    2003-01-01

    Thermal infrared emission and reflectance spectra (250-1400 cm-1; ???7???40 ??m) of experimentally shocked albite- and anorthite-rich rocks (17-56 GPa) demonstrate that plagioclase feldspars exhibit characteristic degradations in spectral features with increasing pressure. New measurements of albite (Ab98) presented here display major spectral absorptions between 1000-1250 cm-1 (8-10 ??m) (due to Si-O antisymmetric stretch motions of the silica tetrahedra) and weaker absorptions between 350-700 cm-1 (14-29 ??m) (due to Si-O-Si octahedral bending vibrations). Many of these features persist to higher pressures compared to similar features in measurements of shocked anorthite, consistent with previous thermal infrared absorption studies of shocked feldspars. A transparency feature at 855 cm-1 (11.7 ??m) observed in powdered albite spectra also degrades with increasing pressure, similar to the 830 cm-1 (12.0 ??m) transparency feature in spectra of powders of shocked anorthite. Linear deconvolution models demonstrate that combinations of common mineral and glass spectra can replicate the spectra of shocked anorthite relatively well until shock pressures of 20-25 GPa, above which model errors increase substantially, coincident with the onset of diaplectic glass formation. Albite deconvolutions exhibit higher errors overall but do not change significantly with pressure, likely because certain clay minerals selected by the model exhibit absorption features similar to those in highly shocked albite. The implication for deconvolution of thermal infrared spectra of planetary surfaces (or laboratory spectra of samples) is that the use of highly shocked anorthite spectra in end-member libraries could be helpful in identifying highly shocked calcic plagioclase feldspars.

  8. Springtime carbon emission episodes at the Gosan background site revealed by total carbon, stable carbon isotopic composition, and thermal characteristics of carbonaceous particles

    Science.gov (United States)

    Jung, J.; Kawamura, K.

    2011-11-01

    In order to investigate the emission of carbonaceous aerosols at the Gosan background super-site (33.17° N, 126.10° E) in East Asia, total suspended particles (TSP) were collected during spring of 2007 and 2008 and analyzed for particulate organic carbon, elemental carbon, total carbon (TC), total nitrogen (TN), and stable carbon isotopic composition (δ13C) of TC. The stable carbon isotopic composition of TC (δ13CTC) was found to be lowest during pollen emission episodes (range: -26.2‰ to -23.5‰, avg. -25.2 ± 0.9‰), approaching those of the airborne pollen (-28.0‰) collected at the Gosan site. Based on a carbon isotope mass balance equation, we found that ~42% of TC in the TSP samples during the pollen episodes was attributed to airborne pollen from Japanese cedar trees planted around tangerine farms in Jeju Island. A negative correlation between the citric acid-carbon/TC ratios and δ13CTC was obtained during the pollen episodes. These results suggest that citric acid emitted from tangerine fruit may be adsorbed on the airborne pollen and then transported to the Gosan site. Thermal evolution patterns of organic carbon during the pollen episodes were characterized by high OC evolution in the OC2 temperature step (450 °C). Since thermal evolution patterns of organic aerosols are highly influenced by their molecular weight, they can be used as additional information on the formation of secondary organic aerosols and the effect of aging of organic aerosols during the long-range atmospheric transport and sources of organic aerosols.

  9. Springtime carbon emission episodes at the Gosan background site revealed by total carbon, stable carbon isotopic composition, and thermal characteristics of carbonaceous particles

    Directory of Open Access Journals (Sweden)

    J. Jung

    2011-11-01

    Full Text Available In order to investigate the emission of carbonaceous aerosols at the Gosan background super-site (33.17° N, 126.10° E in East Asia, total suspended particles (TSP were collected during spring of 2007 and 2008 and analyzed for particulate organic carbon, elemental carbon, total carbon (TC, total nitrogen (TN, and stable carbon isotopic composition (δ13C of TC. The stable carbon isotopic composition of TC (δ13CTC was found to be lowest during pollen emission episodes (range: −26.2‰ to −23.5‰, avg. −25.2 ± 0.9‰, approaching those of the airborne pollen (−28.0‰ collected at the Gosan site. Based on a carbon isotope mass balance equation, we found that ~42% of TC in the TSP samples during the pollen episodes was attributed to airborne pollen from Japanese cedar trees planted around tangerine farms in Jeju Island. A negative correlation between the citric acid-carbon/TC ratios and δ13CTC was obtained during the pollen episodes. These results suggest that citric acid emitted from tangerine fruit may be adsorbed on the airborne pollen and then transported to the Gosan site. Thermal evolution patterns of organic carbon during the pollen episodes were characterized by high OC evolution in the OC2 temperature step (450 °C. Since thermal evolution patterns of organic aerosols are highly influenced by their molecular weight, they can be used as additional information on the formation of secondary organic aerosols and the effect of aging of organic aerosols during the long-range atmospheric transport and sources of organic aerosols.

  10. A MODIS-based analysis of the Val d'Agri Oil Center (South of Italy) thermal emission: an independent gas flaring estimation strategy

    Science.gov (United States)

    Pergola, Nicola; Faruolo, Mariapia; Irina, Coviello; Carolina, Filizzola; Teodosio, Lacava; Valerio, Tramutoli

    2014-05-01

    Different kinds of atmospheric pollution affect human health and the environment at local and global scale. The petroleum industry represents one of the most important environmental pollution sources, accounting for about 18% of well-to-wheels greenhouse gas (GHG) emissions. The main pollution source is represented by the flaring of gas, one of the most challenging energy and environmental problems facing the world today. The World Bank has estimated that 150 billion cubic meters of natural gas are being flared annually, that is equivalent to 30% of the European Union's gas consumption. Since 2002, satellite-based methodologies have shown their capability in providing independent and reliable estimation of gas flaring emissions, at both national and global scale. In this paper, for the first time, the potential of satellite data in estimating gas flaring volumes emitted from a single on-shore crude oil pre-treatment plant, i.e. the Ente Nazionale Idrocarburi (ENI) Val d'Agri Oil Center (COVA), located in the Basilicata Region (South of Italy), was assessed. Specifically, thirteen years of night-time Moderate Resolution Imaging Spectroradiometer (MODIS) data acquired in the medium and thermal infrared (MIR and TIR, respectively) bands were processed. The Robust Satellite Techniques (RST) approach was implemented for identifying anomalous values of the signals under investigation (i.e. the MIR-TIR difference one), associated to the COVA flares emergency discharges. Then, the Fire Radiative Power (FRP), computed for the thermal anomalies previously identified, was correlated to the emitted gas flaring volumes, available for the COVA in the period 2003 - 2009, defining a satellite based regression model for estimating COVA gas flaring emitted volumes. The used strategy and the preliminary results of this analysis will be described in detail in this work.

  11. Near-infrared Thermal Emission Detections of a Number of Hot Jupiters and the Systematics of Ground-based Near-infrared Photometry

    Science.gov (United States)

    Croll, Bryce; Albert, Loic; Jayawardhana, Ray; Cushing, Michael; Moutou, Claire; Lafreniere, David; Johnson, John Asher; Bonomo, Aldo S.; Deleuil, Magali; Fortney, Jonathan

    2015-03-01

    We present detections of the near-infrared thermal emission of three hot Jupiters and one brown dwarf using the Wide-field Infrared Camera (WIRCam) on the Canada-France-Hawaii Telescope (CFHT). These include Ks-band secondary eclipse detections of the hot Jupiters WASP-3b and Qatar-1b and the brown dwarf KELT-1b. We also report Y-band, K CONT-band, and two new and one reanalyzed Ks-band detections of the thermal emission of the hot Jupiter WASP-12b. We present a new reduction pipeline for CFHT/WIRCam data, which is optimized for high precision photometry. We also describe novel techniques for constraining systematic errors in ground-based near-infrared photometry, so as to return reliable secondary eclipse depths and uncertainties. We discuss the noise properties of our ground-based photometry for wavelengths spanning the near-infrared (the YJHK bands), for faint and bright stars, and for the same object on several occasions. For the hot Jupiters WASP-3b and WASP-12b we demonstrate the repeatability of our eclipse depth measurements in the Ks band; we therefore place stringent limits on the systematics of ground-based, near-infrared photometry, and also rule out violent weather changes in the deep, high pressure atmospheres of these two hot Jupiters at the epochs of our observations. Based on observations obtained with WIRCam, a joint project of Canada-France-Hawaii Telescope (CFHT), Taiwan, Korea, Canada, France, at the CFHT, which is operated by the National Research Council (NRC) of Canada, the Institute National des Sciences de l'Univers of the Centre National de la Recherche Scientifique of France, and the University of Hawaii.

  12. Observing the Spectra of MEarth and TRAPPIST Planets with JWST

    Science.gov (United States)

    Morley, Caroline; Kreidberg, Laura; Rustamkulov, Zafar; Robinson, Tyler D.; Fortney, Jonathan J.

    2017-10-01

    During the past two years, nine planets close to Earth in radius have been discovered around nearby M dwarfs cooler than 3300 K. These planets include the 7 planets in the TRAPPIST-1 system and two planets discovered by the MEarth survey, GJ 1132b and LHS 1140b (Dittmann et al. 2017; Berta-Thompson et al. 2015; Gillon et al. 2017). These planets are the smallest planets discovered to date that will be amenable to atmospheric characterization with JWST. They span equilibrium temperatures from ˜130 K to >500 K, and radii from 0.7 to 1.43 Earth radii. Some of these planets orbit as distances potentially amenable to surface liquid water, though the actual surface temperatures will depend strongly on the albedo of the planet and the thickness and composition of its atmosphere. The stars they orbit also vary in activity levels, from the quiet LHS 1140b host star to the more active TRAPPIST-1 host star. This set of planets will form the testbed for our first chance to study the diversity of atmospheres around Earth-sized planets. Here, we will present model spectra of these 9 planets, varying the composition and the surface pressure of the atmosphere. We base our elemental compositions on three outcomes of planetary atmosphere evolution in our own solar system: Earth, Titan, and Venus. We calculate the molecular compositions in chemical equilibrium. We present both thermal emission spectra and transmission spectra for each of these objects, and make predictions for the observability of these spectra with different instrument modes with JWST.

  13. Effect of metal stress on the thermal infrared emission of soybeans: A greenhouse experiment - Possible utility in remote sensing

    Science.gov (United States)

    Suresh, R.; Schwaller, M. R.; Foy, C. D.; Weidner, J. R.; Schnetzler, C. S.

    1989-01-01

    Manganese-sensitive forest and manganese-tolerant lee soybean cultivars were subjected to differential manganese stress in loring soil in a greenhouse experiment. Leaf temperature measurements were made using thermistors for forest and lee. Manganese-stressed plants had higher leaf temperatures than control plants in both forest and lee. Results of this experiment have potential applications in metal stress detection using remote sensing thermal infrared data over large areas of vegetation. This technique can be useful in reconnaissance mineral exploration in densely-vegetated regions where conventional ground-based methods are of little help.

  14. Dual-MWCNT Probe Thermal Sensor Assembly and Evaluation Based on Nanorobotic Manipulation inside a Field-Emission-Scanning Electron Microscope

    Directory of Open Access Journals (Sweden)

    Zhan Yang

    2015-03-01

    Full Text Available We report a thermal sensor composed of two multiwalled carbon nano-tubes (MWCNTs inside a field-emission-scanning electron microscope. The sensor was assembled using a nanorobotic manipulation system, which was used to construct a probe tip in order to detect the local environment of a single cell. An atomic force microscopy (AFM cantilever was used as a substrate; the cantilever was composed of Si3N4 and both sides were covered with a gold layer. MWCNTs were individually assembled on both sides of the AFM cantilever by employing nanorobotic manipulation. Another AFM cantilever was subsequently used as an end effector to manipulate the MWCNTs to touch each other. Electron-beam-induced deposition (EBID was then used to bond the two MWCNTs. The MWCNT probe thermal sensor was evaluated inside a thermostated container in the temperature range from 25°C to 60°C. The experimental results show the positive characteristics of the temperature coefficient of resistance (TCR.

  15. Mulifunctional Dendritic Emitter: Aggregation-Induced Emission Enhanced, Thermally Activated Delayed Fluorescent Material for Solution-Processed Multilayered Organic Light-Emitting Diodes

    Science.gov (United States)

    Matsuoka, Kenichi; Albrecht, Ken; Yamamoto, Kimihisa; Fujita, Katsuhiko

    2017-01-01

    Thermally activated delayed fluorescence (TADF) materials emerged as promising light sources in third generation organic light-emitting diodes (OLED). Much effort has been invested for the development of small molecular TADF materials and vacuum process-based efficient TADF-OLEDs. In contrast, a limited number of solution processable high-molecular weight TADF materials toward low cost, large area, and scalable manufacturing of solution processed TADF-OLEDs have been reported so far. In this context, we report benzophenone-core carbazole dendrimers (GnB, n = generation) showing TADF and aggregation-induced emission enhancement (AIEE) properties along with alcohol resistance enabling further solution-based lamination of organic materials. The dendritic structure was found to play an important role for both TADF and AIEE activities in the neat films. By using these multifunctional dendritic emitters as non-doped emissive layers, OLED devices with fully solution processed organic multilayers were successfully fabricated and achieved maximum external quantum efficiency of 5.7%.

  16. Synthesis, spectra, and theoretical investigations of the triarylamines based on 6H-indolo[2,3-b]quinoxaline.

    Science.gov (United States)

    Thomas, K R Justin; Tyagi, Payal

    2010-12-03

    Triarylamines containing a 6H-indolo[2,3-b]quinoxaline core and aromatic units such as phenyl, naphthyl, pyrene, anthracene, or fluorene have been synthesized by employing palladium-catalyzed C-N and C-C coupling reactions and characterized by optical absorption and emission spectra, electrochemical behavior, and thermal studies. Even though the electronic absorption spectra of the compounds were influenced by the nature of the peripheral amines, the emission spectra indicated close similarity for the excited states in these compounds. For the derivatives in which the amines were directly anchored on the 6H-indolo[2,3-b]quinoxaline nucleus, the emission appeared to be dominated by the state localized on the 6H-indolo[2,3-b]quinoxaline chromophore, while in the compounds containing the extended conjugation the fluorescence originated from the polyaromatic linker. The compounds displayed green or yellow emission depending on the nature of the amine segment. All of the dyes displayed one-electron quasi-reversible oxidation couple in the cyclic voltammograms, which is attributable to the oxidation of the peripheral amines at the 6H-indolo[2,3-b]quinoxaline core. An additional one-electron oxidation process observable at the high positive potentials for the compounds 7 and 8 probably arises from the oxidation of the arylthiophene segment. The enhanced thermal stability and relatively higher glass transition temperatures observed for these compounds were attributed to the presence of dipolar 6H-indolo[2,3-b]quinoxaline segment. The origin of the optical spectra and the trends observed therein were rationalized using TDDFT simulations.

  17. Infrared spectra, thermogravimetric analysis and antifungal studies ...

    African Journals Online (AJOL)

    O, FeCl3.6H2O and Cu(CH3COO)2.2H2O in a mixture of an ethanol-bidistilled water (1:1), at 60 °C. They were characterized by melting point, molar conductivity, magnetic moment, elemental analysis, infrared spectra and thermal analyses.

  18. Computer program package for PIXE spectra evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Kajfosz, J. [Institute of Nuclear Physics, Cracow (Poland)

    1992-12-31

    The computer programs described here were developed for calculating the concentrations of elements in samples analysed by the PIXE (Proton Induced X-ray Emission) method from the X-ray spectra obtained in those analyses. (author). 10 refs, 2 figs.

  19. Thermal luminescence spectroscopy chemical imaging sensor.

    Science.gov (United States)

    Carrieri, Arthur H; Buican, Tudor N; Roese, Erik S; Sutter, James; Samuels, Alan C

    2012-10-01

    The authors present a pseudo-active chemical imaging sensor model embodying irradiative transient heating, temperature nonequilibrium thermal luminescence spectroscopy, differential hyperspectral imaging, and artificial neural network technologies integrated together. We elaborate on various optimizations, simulations, and animations of the integrated sensor design and apply it to the terrestrial chemical contamination problem, where the interstitial contaminant compounds of detection interest (analytes) comprise liquid chemical warfare agents, their various derivative condensed phase compounds, and other material of a life-threatening nature. The sensor must measure and process a dynamic pattern of absorptive-emissive middle infrared molecular signature spectra of subject analytes to perform its chemical imaging and standoff detection functions successfully.

  20. Performance evaluation of non-thermal plasma on particulate matter, ozone and CO2 correlation for diesel exhaust emission reduction

    DEFF Research Database (Denmark)

    Babaie, Meisam; Davari, Pooya; Talebizadeh, Poyan

    2015-01-01

    This study is seeking to investigate the effect of non-thermal plasma technology in the abatement of particulate matter (PM) from the actual diesel exhaust. Ozone (O3) strongly promotes PM oxidation, the main product of which is carbon dioxide (CO2). PM oxidation into the less harmful product (CO2......) is the main objective whiles the correlation between PM, O3 and CO2 is considered. A dielectric barrier discharge reactor has been designed with pulsed power technology to produce plasma inside the diesel exhaust. To characterise the system under varied conditions, a range of applied voltages from 11 k...... concentration and PM removal has been found and the role of ozone in PM removal in plasma treatment of diesel exhaust has been highlighted....

  1. Thermal chemiluminescence from γ-irradiated polytetrafluoroethylene and its emission mechanism: Kinetic analysis and bond dissociation energy of fluoroperoxide group

    Science.gov (United States)

    Yamada, Emi; Noguchi, Tsuyoshi; Akai, Nobuyuki; Ishii, Hiroshi; Satoh, Chikahiro; Hironiwa, Takayuki; Millington, Keith R.; Nakata, Munetaka

    2014-11-01

    Temperature dependence of the time evolution of chemiluminescence intensity from γ-irradiated polytetrafluoroethylene was examined by heating isothermally in the range of 150 and 200 °C. Kinetic analysis was carried out to estimate the rate constants, from which the dissociation energy of the Osbnd O bond in the fluoroperoxide group was determined to be 97 ± 4 kJ mol-1, being consistent with the corresponding value for small fluorocarbon model systems obtained by quantum chemical calculations. This strongly supports the emission mechanism [sbnd CF(OOF)sbnd CF2sbnd → sbnd COsbnd CF2sbnd + OF2 + hν] proposed in our previous paper to explain chemiluminescence from the γ-irradiated polytetrafluoroethylene.

  2. CHANG-ES X: Spatially Resolved Separation of Thermal Contribution from Radio Continuum Emission in Edge-on Galaxies

    Science.gov (United States)

    Vargas, Carlos J.; Mora-Partiarroyo, Silvia Carolina; Schmidt, Philip; Rand, Richard J.; Stein, Yelena; Walterbos, René A. M.; Wang, Q. Daniel; Basu, Aritra; Patterson, Maria; Kepley, Amanda; Beck, Rainer; Irwin, Judith; Heald, George; Li, Jiangtao; Wiegert, Theresa

    2018-02-01

    We analyze the application of star formation rate calibrations using Hα and 22 μm infrared (IR) imaging data in predicting the thermal radio component for a test sample of three edge-on galaxies (NGC 891, NGC 3044, and NGC 4631) in the Continuum Halos in Nearby Galaxies—an EVLA Survey (CHANG-ES). We use a mixture of Hα and 24 μm calibration from Calzetti et al. and a linear 22 μm only calibration from Jarrett et al. on the test sample. We apply these relations on a pixel-to-pixel basis to create thermal prediction maps in the two CHANG-ES bands: L and C band (1.5 GHz and 6.0 GHz, respectively). We analyze the resulting nonthermal spectral index maps, and find a characteristic steepening of the nonthermal spectral index with vertical distance from the disk after application of all methods. We find possible evidence of extinction in the 22 μm data as compared to 70 μm Spitzer Multiband Imaging Photometer imaging in NGC 891. We analyze a larger sample of edge-on and face-on galaxy 25–100 μm flux ratios, and find that the ratios for edge-ons are systematically lower by a factor of 1.36, a result we attribute to excess extinction in the mid-IR in edge-ons. We introduce a new calibration for correcting the Hα luminosity for dust when galaxies are edge-on or very dusty.

  3. Microscopic emission and reflectance thermal infrared spectroscopy: instrumentation for quantitative in situ mineralogy of complex planetary surfaces.

    Science.gov (United States)

    Edwards, C S; Christensen, P R

    2013-04-10

    The diversity of investigations of planetary surfaces, especially Mars, using in situ instrumentation over the last decade is unprecedented in the exploration history of our solar system. The style of instrumentation that landed spacecraft can support is dependent on several parameters, including mass, power consumption, instrument complexity, cost, and desired measurement type (e.g., chemistry, mineralogy, petrology, morphology, etc.), all of which must be evaluated when deciding an appropriate spacecraft payload. We present a laboratory technique for a microscopic emission and reflectance spectrometer for the analysis of martian analog materials as a strong candidate for the next generation of in situ instruments designed to definitively assess sample mineralogy and petrology while preserving geologic context. We discuss the instrument capabilities, signal and noise, and overall system performance. We evaluate the ability of this instrument to quantitatively determine sample mineralogy, including bulk mineral abundances. This capability is greatly enhanced. Whereas the number of mineral components observed from existing emission spectrometers is high (often >5 to 10 depending on the number of accessory and alteration phases present), the number of mineral components at any microscopic measurement spot is low (typically mineralogy and atmospheric data, much in the same manner as the mini-TESs, is of significant additional value and maintains the long history of atmospheric monitoring for Mars. Miniaturization of this instrument has also been demonstrated, as the same microscope objective has been mounted to a flight-spare mini-TES. Further miniaturization of this instrument is straightforward with modern electronics, and the development of this instrument as an arm-mounted device is the end goal.

  4. Diagnosis of the local thermal equilibrium by optical emission spectroscopy in the evolution of electric discharge; Diagnostico del equilibrio termico local por espectroscopia optica de emision en la evolucion de una descarga electrica

    Energy Technology Data Exchange (ETDEWEB)

    Valdivia B, R.; Pacheco S, J.; Pacheco P, M.; Ramos F, F.; Cruz A, A. [ININ, Carretera Mexico-Toluca s/n, Ocoyoacac 52750, Estado de Mexico (Mexico); Velazquez P, S. [Instituto Tecnologico de Toluca, Av. Instituto Tecnologico s/n, Ex-Rancho la Virgen, Metepec 52140, Estado de Mexico (Mexico)

    2008-07-01

    In this work applies the technique of optical emission spectroscopy to diagnose the temperature of the species generated in plasma in the transition to glow discharge arc. Whit this diagnosis is possible to determine the local thermal equilibrium conditions of the discharge. (Author)

  5. Constraints on the Bulk Composition of Uranus from Herschel PACS and ISO LWS Photometry, SOFIA FORCAST Photometry and Spectroscopy, and Ground-Based Photometry of its Thermal Emission

    Science.gov (United States)

    Orton, Glenn; Mueller, Thomas; Burgdorf, Martin; Fletcher, Leigh; de Pater, Imke; Atreya, Sushil; Adams, Joseph; Herter, Terry; Keller, Luke; Sidher, Sunil; Sinclair, James; Fujiyoshi, Takuya

    2016-04-01

    We present thermal infrared observations of the disk of Uranus at 17-200 μm to deduce its global thermal structure and bulk composition. We combine 17-200 μm filtered photometric measurements by the Herschel PACS and ISO LWS instruments and 19-35 μm filtered photometry and spectroscopy by the SOFIA FORCAST instrument, supplemented by 17-25 μm ground-based photometric filtered imaging of Uranus. Previous analysis of infrared spectroscopic measurements of the disk of Uranus made by the Spitzer IRS instrument yielded a model for the disk-averaged temperature profile and stratospheric composition (Orton et al. 2014a Icarus 243,494; 2014b Icarus 243, 471) that were consistent with submillimeter spectroscopy by the Herschel SPIRE instrument (Swinyard et al. 2014, MNRAS 440, 3658). Our motivation to observe the 17-35 μm spectrum was to place more stringent constraints on the global para-H2 / ortho-H2 ratio in the upper troposphere and lower stratosphere than the ISO SWS results of Fouchet et al. (2003, Icarus 161, 127), who examined H2 quadrupole lines. We will discuss the consistency of these observations with a higher para-H2 fraction than implied by local thermal equilibrium, which would resolve a discrepancy between the Spitzer-based model and observations of HD lines by the Herschel PACS experiment (Feuchtgruber et al. 2013 Astron. & Astrophys. 551, A126). Constraints on the global para-H2 fraction allow for more precise analysis of the far-infrared spectrum, which is sensitive to the He:H2 ratio, a quantity that was not constrained by the Spitzer IRS spectra. The derived model, which assumed the ratio derived by the Voyager-2 IRIS/radio-science occultation experiment (Conrath et al. 1987 J. Geophys. Res. 92, 15003), is inconsistent with 70-200 μm PACS photometry (Mueller et al. 2016 Astron. & Astrophys. submittted) and ISO LWS photometric measurements. However, the model can be made consistent with the observations if the fraction of He relative to H2 were

  6. ASTER Global Emissivity Dataset, 1 kilometer, HDF5 V003

    Data.gov (United States)

    National Aeronautics and Space Administration — Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) Global Emissivity Dataset (GED) land surface temperature and emissivity (LST&E) data...

  7. ASTER Global Emissivity Dataset, 100 meter, HDF5 V003

    Data.gov (United States)

    National Aeronautics and Space Administration — Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) Global Emissivity Dataset (GED) land surface temperature and emissivity (LST&E) data...

  8. Saturn Ring Data Analysis and Thermal Modeling

    Science.gov (United States)

    Dobson, Coleman

    2011-01-01

    CIRS, VIMS, UVIS, and ISS (Cassini's Composite Infrared Specrtometer, Visual and Infrared Mapping Spectrometer, Ultra Violet Imaging Spectrometer and Imaging Science Subsystem, respectively), have each operated in a multidimensional observation space and have acquired scans of the lit and unlit rings at multiple phase angles. To better understand physical and dynamical ring particle parametric dependence, we co-registered profiles from these three instruments, taken at a wide range of wavelengths, from ultraviolet through the thermal infrared, to associate changes in ring particle temperature with changes in observed brightness, specifically with albedos inferred by ISS, UVIS and VIMS. We work in a parameter space where the solar elevation range is constrained to 12 deg - 14 deg and the chosen radial region is the B3 region of the B ring; this region is the most optically thick region in Saturn's rings. From this compilation of multiple wavelength data, we construct and fit phase curves and color ratios using independent dynamical thermal models for ring structure and overplot Saturn, Saturn ring, and Solar spectra. Analysis of phase curve construction and color ratios reveals thermal emission to fall within the extrema of the ISS bandwidth and a geometrical dependence of reddening on phase angle, respectively. Analysis of spectra reveals Cassini CIRS Saturn spectra dominate Cassini CIRS B3 Ring Spectra from 19 to 1000 microns, while Earth-based B Ring Spectrum dominates Earth-based Saturn Spectrum from 0.4 to 4 microns. From our fits we test out dynamical thermal models; from the phase curves we derive ring albedos and non-lambertian properties of the ring particle surfaces; and from the color ratios we examine multiple scattering within the regolith of ring particles.

  9. Characterizing Transiting Planets with JWST Spectra: Simulations and Retrievals

    Science.gov (United States)

    Greene, Tom; Line, Michael; Fortney, Jonathan

    2015-01-01

    There are now well over a thousand confirmed exoplanets, ranging from hot to cold and large to small worlds. JWST spectra will provide much more detailed information on the molecular constituents, chemical compositions, and thermal properties of the atmospheres of transiting planets than is now known. We explore this by modeling clear, cloudy,and high mean molecular weight atmospheres of typical hot Jupiter, warm Neptune, warm sub-Neptune, and cool super-Earth planets and then simulating their JWST transmission and emission spectra. These simulations were performed for several JWST instrument modes over 1 - 11 microns and incorporate realistic signal and noise components. We then performed state-of the art retrievals to determine how well temperatures and abundances (CO, CO2, H2O, NH3) will be constrained and over what pressures for these different planet types. Using these results, we appraise what instrument modes will be most useful for determining what properties of the different planets, and we assess how well we can constrain their compositions, CO ratios, and temperature profiles.

  10. Disk Emission from Magnetohydrodynamic Simulations of Spinning Black Holes

    Science.gov (United States)

    Schnittman, Jeremy D.; Krolik, Julian H.; Noble, Scott C.

    2016-01-01

    We present the results of a new series of global, three-dimensional, relativistic magnetohydrodynamic (MHD) simulations of thin accretion disks around spinning black holes. The disks have aspect ratios of H/R approx. 0.05 and spin parameters of a/M = 0, 0.5, 0.9, and 0.99. Using the ray-tracing code Pandurata, we generate broadband thermal spectra and polarization signatures from the MHD simulations. We find that the simulated spectra can be well fit with a simple, universal emissivity profile that better reproduces the behavior of the emission from the inner disk, compared to traditional analyses carried out using a Novikov-Thorne thin disk model. Finally, we show how spectropolarization observations can be used to convincingly break the spin-inclination degeneracy well known to the continuum-fitting method of measuring black hole spin.

  11. Thermal infrared spectroscopy of experimentally shocked anorthosite and pyroxenite: Implications for remote sensing of Mars

    Science.gov (United States)

    Johnson, J. R.; Horz, F.; Lucey, P.G.; Christensen, P.R.

    2002-01-01

    The feldspar and pyroxene mineralogies on Mars revealed by the Thermal Emission Spectrometer (TES) on Mars Global Surveyor likely record a variety of shock effects, as suggested by petrologic analyses of the Martian meteorites and the abundance of impact craters on the planet's surface. To study the effects of shock pressures on thermal infrared spectra of these minerals, we performed shock recovery experiments on orthopyroxenite and anorthosite samples from the Stillwater Complex (Montana) over peak pressures from 17 to 63 GPa. We acquired emissivity and hemispherical reflectance spectra (350-1400 cm-1; ???7-29 ??m) of both coherent chips and fine-grained powders of shocked and unshocked samples. These spectra are more directly comparable to remotely sensed data of Mars (e.g., TES) than previously acquired absorption or transmission spectra of shocked minerals. The spectra of experimentally shocked feldspar show systematic changes with increasing pressure due to depolymerization of the silica tetrahedra. For the spectra of chips, this includes the disappearance of small bands in the 500-650 cm-1 region and a strong band at 1115 cm-1, and changes in positions of a strong band near 940 cm-1 and the Christiansen feature near 1250 cm-1. Spectra of the shocked powders show the gradual disappearance of a transparency feature near 830 cm-1. Fewer changes are observed in the pyroxene spectra at pressures as high as 63 GPa. Spectra of experimentally shocked minerals will help identify more precisely the mineralogy of rocks and soils not only from TES but also from Mars instruments such as miniTES and THEMIS.

  12. Statistical properties of Fermi GBM GRBs' spectra

    Science.gov (United States)

    Rácz, István I.; Balázs, Lajos G.; Horvath, Istvan; Tóth, L. Viktor; Bagoly, Zsolt

    2018-03-01

    Statistical studies of gamma-ray burst (GRB) spectra may result in important information on the physics of GRBs. The Fermi GBM catalogue contains GRB parameters (peak energy, spectral indices, and intensity) estimated fitting the gamma-ray spectral energy distribution of the total emission (fluence, flnc), and during the time of the peak flux (pflx). Using contingency tables, we studied the relationship of the models best-fitting pflx and flnc time intervals. Our analysis revealed an ordering of the spectra into a power law - Comptonized - smoothly broken power law - Band series. This result was further supported by a correspondence analysis of the pflx and flnc spectra categorical variables. We performed a linear discriminant analysis (LDA) to find a relationship between categorical (spectral) and model independent physical data. LDA resulted in highly significant physical differences among the spectral types, that is more pronounced in the case of the pflx spectra, than for the flnc spectra. We interpreted this difference as caused by the temporal variation of the spectrum during the outburst. This spectral variability is confirmed by the differences in the low-energy spectral index and peak energy, between the pflx and flnc spectra. We found that the synchrotron radiation is significant in GBM spectra. The mean low-energy spectral index is close to the canonical value of α = -2/3 during the peak flux. However, α is ˜ -0.9 for the spectra of the fluences. We interpret this difference as showing that the effect of cooling is important only for the fluence spectra.

  13. Treatment Efficiency by means of a Nonthermal Plasma Combined with Heterogeneous Catalysis of Odoriferous Volatile Organic Compounds Emissions from the Thermal Drying of Landfill Leachates

    Directory of Open Access Journals (Sweden)

    Daniel Almarcha

    2014-01-01

    Full Text Available The objective of the present work was to assess the odoriferous volatile organic compounds depuration efficiency of an experimental nonthermal plasma coupled to a catalytic system used for odor abatement of real emissions from a leachate thermal drying plant installed in an urban solid waste landfill. VOC screening was performed by means of HRGC-MS analysis of samples taken at the inlet and at the outlet of the nonthermal plasma system. Odor concentration by means of dynamic olfactometry, total organic carbon, mercaptans, NH3, and H2S were also determined in order to assess the performance of the system throughout several days. Three plasma frequencies (100, 150, and 200 Hz and two catalyst temperatures (150°C and 50°C were also tested. Under conditions of maximum capacity of the treatment system, the results show VOC depuration efficiencies around 69%, with average depuration efficiencies between 44 and 95% depending on the chemical family of the substance. Compounds belonging to the following families have been detected in the samples: organic acids, alcohols, ketones, aldehydes, pyrazines, and reduced sulphur compounds, among others. Average total organic carbon removal efficiency was 88%, while NH3 and H2S removal efficiencies were 88% and 87%, respectively, and odor concentration abatement was 78%.

  14. Inter-Comparison of S-NPP VIIRS and Aqua MODIS Thermal Emissive Bands Using Hyperspectral Infrared Sounder Measurements as a Transfer Reference

    Directory of Open Access Journals (Sweden)

    Yonghong Li

    2016-01-01

    Full Text Available This paper compares the calibration consistency of the spectrally-matched thermal emissive bands (TEB between the Suomi National Polar-orbiting Partnership (S-NPP Visible Infrared Imaging Radiometer Suite (VIIRS and the Aqua Moderate Resolution Imaging Spectroradiometer (MODIS, using observations from their simultaneous nadir overpasses (SNO. Nearly-simultaneous hyperspectral measurements from the Aqua Atmospheric Infrared Sounder(AIRS and the S-NPP Cross-track Infrared Sounder (CrIS are used to account for existing spectral response differences between MODIS and VIIRS TEB. The comparison uses VIIRS Sensor Data Records (SDR in MODIS five-minute granule format provided by the NASA Land Product and Evaluation and Test Element (PEATE and Aqua MODIS Collection 6 Level 1 B (L1B products. Each AIRS footprint of 13.5 km (or CrIS field of view of 14 km is co-located with multiple MODIS (or VIIRS pixels. The corresponding AIRS- and CrIS-simulated MODIS and VIIRS radiances are derived by convolutions based on sensor-dependent relative spectral response (RSR functions. The VIIRS and MODIS TEB calibration consistency is evaluated and the two sensors agreed within 0.2 K in brightness temperature. Additional factors affecting the comparison such as geolocation and atmospheric water vapor content are also discussed in this paper.

  15. Algorithms for classification of astronomical object spectra

    Science.gov (United States)

    Wasiewicz, P.; Szuppe, J.; Hryniewicz, K.

    2015-09-01

    Obtaining interesting celestial objects from tens of thousands or even millions of recorded optical-ultraviolet spectra depends not only on the data quality but also on the accuracy of spectra decomposition. Additionally rapidly growing data volumes demands higher computing power and/or more efficient algorithms implementations. In this paper we speed up the process of substracting iron transitions and fitting Gaussian functions to emission peaks utilising C++ and OpenCL methods together with the NOSQL database. In this paper we implemented typical astronomical methods of detecting peaks in comparison to our previous hybrid methods implemented with CUDA.

  16. SAWYER ASTEROID SPECTRA

    Data.gov (United States)

    National Aeronautics and Space Administration — This data set contains 94 optical asteroid spectra obtained by Scott Sawyer as part of his Ph.D. dissertation at the University of Texas at Austin. Observational...

  17. The ultraviolet spectra of the Jovian aurora

    Energy Technology Data Exchange (ETDEWEB)

    Liu, W.; Dalgarno, A. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, Massachusetts 02138 (United States)

    1996-08-01

    The ultraviolet spectra of molecular hydrogen H{sub 2} due to electron impact excitation are calculated and compared with the high-resolution (0.56 A) spectra of the Jovian aurora obtained with the {ital Hubble} {ital Space} {ital Telescope} Goddard High-Resolution Spectrograph. All the observed features are reproduced by electron impact excitation emissions of H{sub 2}, and the predicted intensities agree well with the observed intensities. Accurate molecular parameters are used, and effects of secondary electrons are included. The auroral emissions are reproduced by energetic electron impact excitation of H{sub 2} with a temperature of 400{endash}600 K. Large temperature gradients occur with respect to altitude within the auroral emission regions. The auroral spectra contain a cascade contribution to the Lyman band emission from high-lying {ital E} and {ital F} states that are populated by the low-energy secondary electrons produced as the energetic auroral electrons slow down. {copyright} {ital 1996 The American Astronomical Society.}

  18. New composite spectra of Mars, 0.4-5.7 μm

    Science.gov (United States)

    Erard, Stephane; Calvin, Wendy M.

    1997-01-01

    About 15 areas were observed in the equatorial regions of Mars by the infrared spectrometers IRS (Mariner 6 and 7) and ISM (Phobos-2). The comparison between the spectra shows a remarkable consistency between two data sets acquired 20 years apart and calibrated independently. This similarity demonstrates the accuracy of ISM calibration above 2 μm, except for a possible stray light contribution above 2.6 μm, on the order of ∼1–2% of the solar flux at 2.7 μm. Most differences in spectral shapes are related to differences in spectral/spatial resolution and viewing geometries. No important variation in surface properties is detected, except for a spot in southern Arabia Terra which has a much deeper hydration feature in IRS spectra; differences in viewing geometries and spatial resolutions do not seem to account for this difference that could result from shifting or dehydration of surface materials. Composite spectra of several types of bright and dark materials are computed by modeling the thermal emission and are completed with telescopic spectra in the visible range. Modeled reflectance in the 3.0–5.7 μm range is consistent with basalts and palagonites. The bright regions and analog palagonite spectra are different from hematite in this range, but resemble several phyllosilicates. We infer that (1) although hematite dominates the spectra in the 0.4- to 2.5-μm range, the silicate-clay host is spectrally active beyond 3 μm and can be identified from this domain; (2) phyllosilicates such as montmorillonite or smectite may be abundant components of the martian soils, although the domain below 3 μm lacks the characteristic features of the most usual terrestrial clay minerals.

  19. Emission characteristics of holmium ions in fluoro-phosphate glasses for photonic applications

    Science.gov (United States)

    Babu, S.; Ratnakaram, Y. C.

    2016-05-01

    Optical properties of Ho3+ doped different fluorophosphate (FP) glasses have been synthesized and discussed. Thermal properties have been studied through differential scanning calorimetry (DSC).The Judd-Ofelt (J-O) intensity parameters Ωλ (λ= 2, 4, 6) from absorption spectra have been evaluated. Various radiative parameters have been obtained for the different excited states using J-O theory. From the emission spectra, different laser properties have been studied and discussed. The nature of decay curve analysis was performed for the 5F4(5S2) level. These glasses are expected to give interesting application in the field of photonic applications.

  20. Optical Band Gap and Thermal Diffusivity of Polypyrrole-Nanoparticles Decorated Reduced Graphene Oxide Nanocomposite Layer

    OpenAIRE

    Amir Reza Sadrolhosseini; Suraya Abdul Rashid; A. S. M. Noor; Alireza Kharazmi; H N Lim; Mohd Adzir Mahdi

    2016-01-01

    A polypyrrole-nanoparticles reduced graphene oxide nanocomposite layer was prepared using electrochemical method. The prepared samples were characterized using Fourier transform infrared spectroscopy, field emission scanning electron microscopy, and UV-visible spectroscopy. The band gap of nanocomposite layers was calculated from UV-visible spectra and the thermal diffusivity of layers was measured using a photoacoustic technique. As experimental results, the optical band gap was in the range...

  1. ULX spectra revisited: Accreting, highly magnetized neutron stars as the engines of ultraluminous X-ray sources

    Science.gov (United States)

    Koliopanos, Filippos; Vasilopoulos, Georgios; Godet, Olivier; Bachetti, Matteo; Webb, Natalie A.; Barret, Didier

    2017-12-01

    Aims: In light of recent discoveries of pulsating ultraluminous X-ray sources (ULXs) and recently introduced theoretical schemes that propose neutron stars (NSs) as the central engines of ULXs, we revisit the spectra of eighteen well known ULXs, in search of indications that favour this newly emerging hypothesis. Methods: We examine the spectra from high-quality XMM-Newton and NuSTAR observations. We use a combination of elementary black body and multicolour disk black body (MCD) models, to diagnose the predictions of classic and novel theoretical models of accretion onto NSs. We re-interpret the well established spectral characteristics of ULXs in terms of accretion onto lowly or highly magnetised NSs, and explore the resulting parameter space for consistency. Results: We confirm the previously noted presence of the low-energy (≲6 keV) spectral rollover and argue that it could be interpreted as due to thermal emission. The spectra are well described by a double thermal model consisting of a "hot" (≳1 keV) and a "cool" (≲0.7 keV) multicolour black body (MCB). Under the assumption that the "cool" MCD emission originates in a disk truncated at the neutron star magnetosphere, we find that all ULXs in our sample are consistent with accretion onto a highly magnetised (B ≳ 1012 G) neutron star. We note a strong correlation between the strength of the magnetic field, the temperature of the "hot" thermal component and the total unabsorbed luminosity. Examination of the NuSTAR data supports this interpretation and also confirms the presence of a weak, high-energy (≳15 keV) tail, most likely the result of modification of the MCB emission by inverse Compton scattering. We also note that the apparent high-energy tail, may simply be the result of mismodelling of MCB emission with an atypical temperature (T) versus radius (r) gradient, using a standard MCD model with a fixed gradient of T r-0.75. Conclusions: We have offered a new and robust physical interpretation for

  2. Solar flare impulsive phase emission observed with SDO/EVE

    Energy Technology Data Exchange (ETDEWEB)

    Kennedy, Michael B.; Milligan, Ryan O.; Mathioudakis, Mihalis; Keenan, Francis P., E-mail: mkennedy29@qub.ac.uk [Astrophysics Research Centre, School of Mathematics and Physics, Queen' s University Belfast, University Road, Belfast BT7 1NN (United Kingdom)

    2013-12-10

    Differential emission measures (DEMs) during the impulsive phase of solar flares were constructed using observations from the EUV Variability Experiment (EVE) and the Markov-Chain Monte Carlo method. Emission lines from ions formed over the temperature range log T{sub e} = 5.8-7.2 allow the evolution of the DEM to be studied over a wide temperature range at 10 s cadence. The technique was applied to several M- and X-class flares, where impulsive phase EUV emission is observable in the disk-integrated EVE spectra from emission lines formed up to 3-4 MK and we use spatially unresolved EVE observations to infer the thermal structure of the emitting region. For the nine events studied, the DEMs exhibited a two-component distribution during the impulsive phase, a low-temperature component with peak temperature of 1-2 MK, and a broad high-temperature component from 7 to 30 MK. A bimodal high-temperature component is also found for several events, with peaks at 8 and 25 MK during the impulsive phase. The origin of the emission was verified using Atmospheric Imaging Assembly images to be the flare ribbons and footpoints, indicating that the constructed DEMs represent the spatially average thermal structure of the chromospheric flare emission during the impulsive phase.

  3. A microphysically-based approach to modeling emissivity and albedo of the martian seasonal caps

    Science.gov (United States)

    Eluszkiewicz, J.; Moncet, J.-L.; Titus, T.N.; Hansen, G.B.

    2005-01-01

    A new model of albedo and emissivity of the martian seasonal caps represented as porous CO2 slabs containing spherical voids and dust particles is described. In the model, a radiative transfer model is coupled with a microphysical model in order to link changes in albedo and emissivity to changes in porosity caused by ice metamorphism. The coupled model is capable of reproducing temporal changes in the spectra of the caps taken by the Thermal Emission Spectrometer onboard the Mars Global Surveyor and it can be used as the forward model in the retrievals of the caps' physical properties (porosity, dust abundance, void and dust grain size) from the spectra. Preliminary results from such inversion studies are presented. ?? 2004 Elsevier Inc. All rights reserved.

  4. Analyzing the Spectra of Accreting X-Ray Pulsars

    Science.gov (United States)

    Wolff, Michael

    This proposal seeks funding for the analysis of accretion-powered X-ray pulsar spectra from NASA/ HEASARC archived X-ray data. Spectral modeling of accreting X-ray pulsars can tell us a great deal about the physical conditions in and near high mass X-ray binary systems. Such systems have accretion flows where plasma is initially channeled from an accretion disk by the strong neutron star magnetic field, eventually falling onto the magnetic polar cap of the neutron star compact object. Many of these accreting X-ray pulsars have X-ray spectra that consist of broad power-law continua with superposed cyclotron resonant scattering features indicating magnetic field strengths above 10^12 G. The energies of these cyclotron line features have recently been shown to vary with X-ray luminosity in a number of sources such as Her X-1 and V 0332+53, a phenomenon not well understood. Another recent development is the relatively new analytic model for the spectral continuum formation in accretion-powered pulsar systems developed by Becker & Wolff. In their formalism the accretion flows are assumed to go through radiation- dominated radiative shocks and settle onto the neutron star surface. The radiation field consists of strongly Comptonized bremsstrahlung emission from the entire plasma, Comptonized cyclotron emission from the de-excitations of Landau-excited electrons in the neutron star magnetic field, and Comptonized black-body emission from a thermal mound near the neutron star surface. We seek to develop the data analysis tools to apply this model framework to the X-ray data from a wide set of sources to make progress characterizing the basic accretion properties (e.g., magnetic field strength, plasma temperatures, polar cap size, accretion rate per unit area, dominance of bulk vs. thermal Comptonization) as well as understanding the variations of the cyclotron line energies with X-ray luminosity. The three major goals of our proposed work are as follows: In the first year

  5. Experimental studies of the NaCs 12(0+) [71Σ+] state: Spin-orbit and non-adiabatic interactions and quantum interference in the 12(0+) [71Σ+] and 11(0+) [53Π0 ] emission spectra

    Science.gov (United States)

    Faust, C.; Jones, J.; Huennekens, J.; Field, R. W.

    2017-03-01

    We present results from experimental studies of the 11(0+) and 12(0+) electronic states of the NaCs molecule. An optical-optical double resonance method is used to obtain Doppler-free excitation spectra. Selected data from the 11(0+) and 12(0+) high-lying electronic states are used to obtain Rydberg-Klein-Rees and Inverse Perturbation Approach potential energy curves. Interactions between these two electronic states are evident in the patterns observed in the bound-bound and bound-free fluorescence spectra. A model, based on two separate interaction mechanisms, is presented to describe how the wavefunctions of the two states mix. The electronic parts of the wavefunctions interact via spin-orbit coupling, while the individual rotation-vibration levels interact via a second mechanism, which is likely to be non-adiabatic coupling. A modified version of the BCONT program was used to simulate resolved fluorescence from both upper states. Parameters of the model that describe the two interaction mechanisms were varied until simulations were able to adequately reproduce experimental spectra.

  6. Experimental studies of the NaCs 12(0+) [71Σ+] state: Spin-orbit and non-adiabatic interactions and quantum interference in the 12(0+) [71Σ+] and 11(0+) [53Π0] emission spectra.

    Science.gov (United States)

    Faust, C; Jones, J; Huennekens, J; Field, R W

    2017-03-14

    We present results from experimental studies of the 11(0+) and 12(0+) electronic states of the NaCs molecule. An optical-optical double resonance method is used to obtain Doppler-free excitation spectra. Selected data from the 11(0+) and 12(0+) high-lying electronic states are used to obtain Rydberg-Klein-Rees and Inverse Perturbation Approach potential energy curves. Interactions between these two electronic states are evident in the patterns observed in the bound-bound and bound-free fluorescence spectra. A model, based on two separate interaction mechanisms, is presented to describe how the wavefunctions of the two states mix. The electronic parts of the wavefunctions interact via spin-orbit coupling, while the individual rotation-vibration levels interact via a second mechanism, which is likely to be non-adiabatic coupling. A modified version of the BCONT program was used to simulate resolved fluorescence from both upper states. Parameters of the model that describe the two interaction mechanisms were varied until simulations were able to adequately reproduce experimental spectra.

  7. Removing The Instrument Function From Fluorescence Spectra

    Science.gov (United States)

    Childs, Andrew F.

    1989-05-01

    The spectrum acquired at the sample phototnultiplier tube of a fluorescence spectrophotometer is a product of the sample spectrum and the instrument function. The determination of the instrument function and its removal from the acquired spectrum is often critical to the accurate determination of the physical properties of the sample. Methods are discussed for the determination and removal of the instrument function from excitation and emission spectra. Methods considered include quantum counters and ratio circuits for excitation correction, and emission correction against calibrated excitation systems, calibrated tungsten lamps, and NBS standard quinine sulfate.

  8. Cathodoluminescence spectra of gallium nitride nanorods.

    Science.gov (United States)

    Tsai, Chia-Chang; Li, Guan-Hua; Lin, Yuan-Ting; Chang, Ching-Wen; Wadekar, Paritosh; Chen, Quark Yung-Sung; Rigutti, Lorenzo; Tchernycheva, Maria; Julien, François Henri; Tu, Li-Wei

    2011-12-14

    Gallium nitride [GaN] nanorods grown on a Si(111) substrate at 720°C via plasma-assisted molecular beam epitaxy were studied by field-emission electron microscopy and cathodoluminescence [CL]. The surface topography and optical properties of the GaN nanorod cluster and single GaN nanorod were measured and discussed. The defect-related CL spectra of GaN nanorods and their dependence on temperature were investigated. The CL spectra along the length of the individual GaN nanorod were also studied. The results reveal that the 3.2-eV peak comes from the structural defect at the interface between the GaN nanorod and Si substrate. The surface state emission of the single GaN nanorod is stronger as the diameter of the GaN nanorod becomes smaller due to an increased surface-to-volume ratio.

  9. High Resolution Spectra of HE Detonations

    Science.gov (United States)

    1980-07-07

    region. We shall assume for present purposes that the emissivity of the detonation products of a 50 to 100 lb HE explosion is also in the viciity of... speed . Incorporated in the emulsion layers are dye forming coup- lers which react simultaneously during I , developmentto produce a separate dye S...Best Available Cop 1~EV~ AFTAC-TR-80-24 HIGH RESOLUTION SPECTRA OF HE DETONATIONS HSS Inc 2 Alfred Circle Bedford, MA 01730 7 JULY 1980 AUG 4 9D

  10. Full-Sky Map of Polycyclic Aromatic Hydrocarbons as Test for Anomalous Microwave Emission

    Science.gov (United States)

    Kogut, Alan

    Measurements of the cosmic microwave background (CMB) provide a critical test of the inflationary paradigm. Detection of the inflationary signal through its characteristic imprint on CMB polarization would have profound consequences for both cosmology and high-energy physics and is recognized as a priority in both the New Worlds, New Horizons Astrophysics Decadal Survey as well as NASA's strategic planning. A primary challenge for detecting the inflationary signal is separating the cosmic signal from competing astrophysical foregrounds within the Galaxy. Foreground emission is brighter than the expected inflationary signal in most of the sky. Detecting the inflationary signal requires subtracting the combined Galactic foregrounds to accuracy of a few percent or better. This in turn requires accurate knowledge of the frequency spectra of the individual emission components. Despite the importance of foreground subtraction, the individual spectra are not known to percent accuracy. At millimeter wavelengths where foregrounds are faintest, emission from synchrotron, free-free- and thermal dust emission are all of comparable amplitude, preventing simple determination of the individual frequency spectra. Correlation of thermal dust emission with sensitive full-sky maps at millimeter wavelengths revealed a new foreground component spatially correlated with the far-IR dust, but with intensity increasing at lower frequencies. Dubbed ``anomalous microwave emission'', this component of the interstellar medium has been tentatively identified as electric dipole emission from a population of small, rapidly rotating dust grains. The distribution and spectrum of anomalous emission are uncertain. If the very small grains responsible for spinning dust emission are not co-located with the larger grains responsible for the far-IR thermal spectrum, any analysis based on the spatial distribution of the large-grain thermal signal will miss the un-correlated component and thereby under

  11. Hard X-Ray Emission from Partially Occulted Solar Flares: RHESSI Observations in Two Solar Cycles

    Science.gov (United States)

    Effenberger, Frederic; Rubio da Costa, Fatima; Oka, Mitsuo; Saint-Hilaire, Pascal; Liu, Wei; Petrosian, Vahé; Glesener, Lindsay; Krucker, Säm

    2017-02-01

    Flares close to the solar limb, where the footpoints are occulted, can reveal the spectrum and structure of the coronal looptop source in X-rays. We aim at studying the properties of the corresponding energetic electrons near their acceleration site, without footpoint contamination. To this end, a statistical study of partially occulted flares observed with Reuven Ramaty High-Energy Solar Spectroscopic Imager is presented here, covering a large part of solar cycles 23 and 24. We perform detailed spectra, imaging, and light curve analyses for 116 flares and include contextual observations from SDO and STEREO when available, providing further insights into flare emission that were previously not accessible. We find that most spectra are fitted well with a thermal component plus a broken power-law, non-thermal component. A thin-target kappa distribution model gives satisfactory fits after the addition of a thermal component. X-ray imaging reveals small spatial separation between the thermal and non-thermal components, except for a few flares with a richer coronal source structure. A comprehensive light curve analysis shows a very good correlation between the derivative of the soft X-ray flux (from GOES) and the hard X-rays for a substantial number of flares, indicative of the Neupert effect. The results confirm that non-thermal particles are accelerated in the corona and estimated timescales support the validity of a thin-target scenario with similar magnitudes of thermal and non-thermal energy fluxes.

  12. The Radio Light Curve of the Gamma-Ray Nova in V407 CYG: Thermal Emission from the Ionized Symbiotic Envelope, Devoured from Within by the Nova Blast

    Science.gov (United States)

    Chomiuk, Laura; Krauss, Miriam I.; Rupen, Michael P.; Nelson, Thomas; Roy, Nirupam; Sokoloski, Jennifer L.; Mukai, Koji; Munari, Ulisse; Mioduszewski, Amy; Weston, Jeninfer; hide

    2012-01-01

    We present multi-frequency radio observations of the 2010 nova event in the symbiotic binary V407 Cygni, obtained with the Karl G. Jansky Very Large Array (VLA) and spanning 1.45 GHz and 17.770 days following discovery. This nova.the first ever detected in gamma rays.shows a radio light curve dominated by the wind of the Mira giant companion, rather than the nova ejecta themselves. The radio luminosity grewas the wind became increasingly ionized by the nova outburst, and faded as the wind was violently heated from within by the nova shock. This study marks the first time that this physical mechanism has been shown to dominate the radio light curve of an astrophysical transient. We do not observe a thermal signature from the nova ejecta or synchrotron emission from the shock, due to the fact that these components were hidden behind the absorbing screen of the Mira wind. We estimate a mass-loss rate for the Mira wind of .Mw approximately equals 10(exp -6) Solar mass yr(exp -1). We also present the only radio detection of V407 Cyg before the 2010 nova, gleaned from unpublished 1993 archival VLA data, which shows that the radio luminosity of the Mira wind varies by a factor of 20 even in quiescence. Although V407 Cyg likely hosts a massive accreting white dwarf, making it a candidate progenitor system for a Type Ia supernova, the dense and radially continuous circumbinary material surrounding V407 Cyg is inconsistent with observational constraints on the environments of most Type Ia supernovae.

  13. Manipulating the Electronic Excited State Energies of Pyrimidine-Based Thermally Activated Delayed Fluorescence Emitters To Realize Efficient Deep-Blue Emission.

    Science.gov (United States)

    Komatsu, Ryutaro; Ohsawa, Tatsuya; Sasabe, Hisahiro; Nakao, Kohei; Hayasaka, Yuya; Kido, Junji

    2017-02-08

    The development of efficient and robust deep-blue emitters is one of the key issues in organic light-emitting devices (OLEDs) for environmentally friendly, large-area displays or general lighting. As a promising technology that realizes 100% conversion from electrons to photons, thermally activated delayed fluorescence (TADF) emitters have attracted considerable attention. However, only a handful of examples of deep-blue TADF emitters have been reported to date, and the emitters generally show large efficiency roll-off at practical luminance over several hundreds to thousands of cd m-2, most likely because of the long delayed fluorescent lifetime (τd). To overcome this problem, we molecularly manipulated the electronic excited state energies of pyrimidine-based TADF emitters to realize deep-blue emission and reduced τd. We then systematically investigated the relationships among the chemical structure, properties, and device performances. The resultant novel pyrimidine emitters, called Ac-XMHPMs (X = 1, 2, and 3), contain different numbers of bulky methyl substituents at acceptor moieties, increasing the excited singlet (ES) and triplet state (ET) energies. Among them, Ac-3MHPM, with a high ET of 2.95 eV, exhibited a high external quantum efficiency (ηext,max) of 18% and an ηext of 10% at 100 cd m-2 with Commission Internationale de l'Eclairage chromaticity coordinates of (0.16, 0.15). These efficiencies are among the highest values to date for deep-blue TADF OLEDs. Our molecular design strategy provides fundamental guidance to design novel deep-blue TADF emitters.

  14. Noble metal recycling. Project 2: Optimization of discontinuous thermal processes (emission reduction). Final report; Edelmetallrecycling. Teilvorhaben 2: Weiterentwicklung der Verfahrenstechnik bei diskontinuierlichen thermischen Prozessen (Emissionsminderung). Abschlussbericht

    Energy Technology Data Exchange (ETDEWEB)

    Baumbach, G.; Berger, R.

    2000-10-01

    A batch operated incineration process, used for the recycling of precious metals is described in the report. The development of a new combined pyrolysis/oxidation Process is the main focus of the work. This new process has several remarkable advantages compared to traditionally used techniques. The optimisation of the process with a modern fuzzy based control technique is described in detail. The emissions of the process were reduced considerably applying the new process and the innovative control technique. Furthermore the layout of several components of the new process can be reduced in the future. The developed techniques can also be applied in other thermal processes, especially batch processes. Additionally the application of catalysts for PCDD/PCDF reduction in the flue gas upstream and downstream of the filter was investigated. Whereas the catalyst performed well, as expected, downstream of the filter, no acceptable operation was possible upstream of the filter. As the reheating downstream the filter is economically not feasible the application of catalysts is not applicable for the describe process. (orig.) [German] Die Arbeit beschreibt einen diskontinuierlichen thermischen Prozess, der zur Rueckgewinnung von Edelmetallen eingesetzt wird. Der Schwerpunkt der Arbeit liegt auf der Entwicklung eines neuartigen kombinierten Pyrolyse/Oxidations-Prozesses, der gegenueber den traditionell eingesetzten Anlagen grosse Vorteile aufweist. Die Optimierung dieses Prozesses mit Hilfe modernster Fuzzy-Regelungstechnik wird detailliert beschrieben. Mit dem neuen Verfahren und den innovativen Regelungstechniken konnten die Emissionen des Prozesses merklich gesenkt werden, ohne den Energiebedarf negativ zu beeinflussen. Ausserdem koennen zukuenftige Anlagen kleiner ausgelegt werden. Die entwickelten Verfahren koennen auch auf andere thermische Prozesse uebertragen werden. Weiterhin wurde der Einsatz von Katalysatoren zur PCDD/PCDF-Minderung im Rein- und Rohgas untersucht

  15. Alteration, slope-classified alteration, and potential lahar inundation maps of volcanoes for the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) Volcano Archive

    Science.gov (United States)

    Mars, John C.; Hubbard, Bernard E.; Pieri, David; Linick, Justin

    2015-01-01

    This study identifies areas prone to lahars from hydrothermally altered volcanic edifices on a global scale, using visible and near infrared (VNIR) and short wavelength infrared (SWIR) reflectance data from the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) and digital elevation data from the ASTER Global Digital Elevation Model (GDEM) dataset. This is the first study to create a global database of hydrothermally altered volcanoes showing quantitatively compiled alteration maps and potentially affected drainages, as well as drainage-specific maps illustrating modeled lahars and their potential inundation zones. We (1) identified and prior