WorldWideScience

Sample records for thermal cycling absorption

  1. Modelling aging effects on a thermal cycling absorption process column

    Energy Technology Data Exchange (ETDEWEB)

    Laquerbe, C.; Contreras, S. [Commissariat a l' Energie Atomique - CEA/Valduc, F-21121 Is sur Tille (France); Baudouin, O. [ProSim SA, Stratege Bat. A, BP 27210, F-31672 Labege Cedex (France); Demoment, J. [Commissariat a l' Energie Atomique - CEA/Valduc, F-21121 Is sur Tille (France)

    2008-07-15

    Palladium coated on alumina is used in hydrogen separation systems operated at CEA/Valduc, and more particularly in Thermal Cycling Absorption Process columns. With such materials, tritium decay is known to induce aging effects which have direct side effects on hydrogen isotopes absorption isotherms. Furthermore in a TCAP column, aging occurs in an heterogeneous way. The possible impacts of these intrinsic material evolutions on the separation performances are investigated here through a numerical approach. (authors)

  2. Materials performance in prototype Thermal Cycling Absorption Process (TCAP) columns

    International Nuclear Information System (INIS)

    Clark, E.A.

    1992-01-01

    Two prototype Thermal Cycling Absorption Process (TCAP) columns have been metallurgically examined after retirement, to determine the causes of failure and to evaluate the performance of the column container materials in this application. Leaking of the fluid heating and cooling subsystems caused retirement of both TCAP columns, not leaking of the main hydrogen-containing column. The aluminum block design TCAP column (AHL block TCAP) used in the Advanced Hydride Laboratory, Building 773-A, failed in one nitrogen inlet tube that was crimped during fabrication, which lead to fatigue crack growth in the tube and subsequent leaking of nitrogen from this tube. The Third Generation stainless steel design TCAP column (Third generation TCAP), operated in 773-A room C-061, failed in a braze joint between the freon heating and cooling tubes (made of copper) and the main stainless steel column. In both cases, stresses from thermal cycling and local constraint likely caused the nucleation and growth of fatigue cracks. No materials compatibility problems between palladium coated kieselguhr (the material contained in the TCAP column) and either aluminum or stainless steel column materials were observed. The aluminum-stainless steel transition junction appeared to be unaffected by service in the AHL block TCAP. Also, no evidence of cracking was observed in the AHL block TCAP in a location expected to experience the highest thermal shock fatigue in this design. It is important to limit thermal stresses caused by constraint in hydride systems designed to work by temperature variation, such as hydride storage beds and TCAP columns

  3. Recent advances in SRS on hydrogen isotope separation using thermal cycling absorption process

    Energy Technology Data Exchange (ETDEWEB)

    Xiao, X.; Kit Heung, L.; Sessions, H.T. [Savannah River National Laboratory - SRNL, Aiken, SC (United States)

    2015-03-15

    TCAP (Thermal Cycling Absorption Process) is a gas chromatograph in principle using palladium in the column packing, but it is unique in the fact that the carrier gas, hydrogen, is being isotopically separated and the system is operated in a semi-continuous manner. TCAP units are used to purify tritium. The recent TCAP advances at Savannah River Site (SRS) include compressor-free concept for heating/cooling, push and pull separation using an active inverse column, and compact column design. The new developments allow significantly higher throughput and better reliability from 1/10 of the current production system's footprint while consuming 60% less energy. Various versions are derived in the meantime for external customers to be used in fusion energy projects.

  4. Thermodynamic performance optimization of the absorption-generation process in an absorption refrigeration cycle

    International Nuclear Information System (INIS)

    Chen, Yi; Han, Wei; Jin, Hongguang

    2016-01-01

    Highlights: • This paper proposes a new thermal compressor model with boost pressure ratio. • The proposed model is an effective way to optimize the absorption-generation process. • Boost pressure ratio is a key parameter in the proposed thermal compressor model. • The optimum boost pressure ratios for two typical refrigeration systems are obtained. - Abstract: The absorption refrigeration cycle is a basic cycle that establishes the systems for utilizing mid-low temperature heat sources. A new thermal compressor model with a key parameter of boost pressure ratio is proposed to optimize the absorption-generation process. The ultimate generation pressure and boost pressure ratio are used to represent the potential and operating conditions of the thermal compressor, respectively. Using the proposed thermal compressor model, the operation mechanism and requirements of the absorption refrigeration system and absorption-compression refrigeration system are elucidated. Furthermore, the two typical heat conversion systems are optimized based on the thermal compressor model. The optimum boost pressure ratios of the absorption refrigeration system and the absorption-compression refrigeration system are 0.5 and 0.75, respectively. For the absorption refrigeration system, the optimum generation temperature is 125.31 °C at the cooling water temperature of 30 °C, which is obtained by simple thermodynamic calculation. The optimized thermodynamic performance of the absorption-compression refrigeration system is 16.7% higher than that of the conventional absorption refrigeration system when the generation temperature is 100 °C. The thermal compressor model proposed in this paper is an effective method for simplifying the optimization of the thermodynamic systems involving an absorption-generation process.

  5. Using lamb waves tomonitor moisture absorption thermally fatigues composite laminates

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Jae Sun; Cho, Youn Ho [School of Mechanical Engineering, Pusan National University, Busan (Korea, Republic of)

    2016-06-15

    Nondestructive evaluation for material health monitoring is important in aerospace industries. Composite laminates are exposed to heat cyclic loading and humid environment depending on flight conditions. Cyclic heat loading and moisture absorption may lead to material degradation such as matrix breaking, debonding, and delamination. In this paper, the moisture absorption ratio was investigated by measuring the Lamb wave velocity. The composite laminates were manufactured and subjected to different thermal aging cycles and moisture absorption. For various conditions of these cycles, not only changes in weight and also ultrasonic wave velocity were measured, and the Lamb wave velocity at various levels of moisture on a carbon-epoxy plate was investigated. Results from the experiment show a linear correlation between moisture absorption ratio and Lamb wave velocity at different thermal fatigue stages. The presented method can be applied as an alternative solution in the online monitoring of composite laminate moisture levels in commercial flights.

  6. The Absorption Refrigerator as a Thermal Transformer

    Science.gov (United States)

    Herrmann, F.

    2009-01-01

    The absorption refrigerator can be considered a thermal transformer, that is, a device that is analogous to the electric transformer. The analogy is based on the correspondence between the extensive quantities, entropy and electric charge and the intensive variables, temperature and electric potential. (Contains 1 footnote and 6 figures.)

  7. The absorption refrigerator as a thermal transformer

    International Nuclear Information System (INIS)

    Herrmann, F

    2009-01-01

    The absorption refrigerator can be considered a thermal transformer, that is, a device that is analogous to the electric transformer. The analogy is based on the correspondence between the extensive quantities, entropy and electric charge and the intensive variables, temperature and electric potential

  8. Development and comparison of different advanced absorption cycles

    Energy Technology Data Exchange (ETDEWEB)

    Arh, S; Gaspersic, B [Faculty of Mechanical Engineering, Ljubjana (YU)

    1990-01-01

    A method for the calculation of the coefficient of performance for any absorption cycle is described. This method was used for the evaluation of different advanced absorption cycles working between four temperature and two or three pressure levels. Similar cycles were compared in the same temperature range with regard to the coefficient of performance, exergy efficiency and two working fluid pairs, NH{sub 3}-H{sub 2}O and H{sub 2}O-LiBr. Cycles and numerical results are presented and a computer-aided absorption cycle development system described. (author).

  9. Detailed thermodynamic analysis of a diffusion-absorption refrigeration cycle

    International Nuclear Information System (INIS)

    Taieb, Ahmed; Mejbri, Khalifa; Bellagi, Ahmed

    2016-01-01

    This paper proposes an advanced simulation model for a Diffusion-Absorption Refrigerator DAR using ammonia/water/hydrogen as working fluids, and developed to describe and predict the behavior of the device under different operating conditions. The system is supposed to be cooled with ambient air and actuated with solar hot water available at 200 °C. The DAR is first simulated for a set of basic data; a COP of 0.126 associated to a cooling capacity of 22.3 W are found. Basing on the obtained results an exergetic analysis of the system is performed which shows that the rectifier contribution to the exergy destruction is the most important with 34%. In a second step, the thermal capacities of all heat exchangers of the DAR are evaluated and the mathematical model so modified that the calculated capacities are now used as input data. A parametric study of the cycle is then carried out. The COP is found to exhibit a maximum when the heat supplied to the boiler or to the bubble pump is varied. Similar behavior is observed for variable submergence ratio. It is further noted that the COP is very sensitive to the ambient air temperature and to the absorber efficiency. - Highlights: • A detailed model of a Diffusion Absorption is developed and simulated. • Irreversibility of each component of the cycle is examined. • A modified model based on thermal capacity of components of the DAR is elaborated. • System performance is calculated over a series of practical operating conditions.

  10. Thermal cycling in multifilamentary superconducting composites

    International Nuclear Information System (INIS)

    Aragao, E.E.A. de.

    1984-01-01

    NbTi-Cu multifilamentary superconducting composites were embedded, polished, characterized by microscopic techniques, and analyzed in a qualitative and semiquantitative way by energy dispersion technique. The superconductors were submitted to thermal cycling between the ambient temperature and the boiling point of helium (4.2K), for different number of cycles. The aims were to study the correlation between the possible microstructural damages due to thermal stresses arising in the composite during cycling and the variation of properties of the material with the number of cycles as well as to verify the validity of an elastic model for thermal stresses for low temperature cycles. (author)

  11. Absorption heat cycles. An experimental and theoretical study

    International Nuclear Information System (INIS)

    Abrahamsson, K.

    1993-09-01

    A flow sheeting programme, SHPUMP, was developed for simulating different absorption heat cycles. The programme consists of ten different modules which allow the user to construct his own absorption cycle. The ten modules configurate evaporators, absorbers, generators, rectifiers, condensers, solution heat exchangers, pumps, valves, mixers and splitters. Seven basic and well established absorption cycles are available in the configuration data base of the programme. A new Carnot model is proposed heat cycles. Together with exergy analysis, general equations for the Carnot coefficient of performance and equations for thermodynamic efficiency, exergetic efficiency and exergy index, are derived, discussed and compared for both absorption heat pumps and absorption heat transformers. Utilizing SHPUMP, simulation results are presented for different configurations where absorption heat cycles are suggested to be incorporated in three different unit operations within both pulp and paper and oleochemical industries. One of the application studies reveled that an absorption heat transformer incorporated with an evaporation plant in a major pulp and paper industry, would save 18% of the total prime energy consumption in one of the evaporation plants. It was also concluded that installing an absorption heat pump in a paper drying plant would result in steam savings equivalent to 12 MW. An experimental absorption heat transformer unit operating with self-circulation has been modified and thoroughly tested. A reference heat transformer plant has been designed and installed in a major pulp and paper mill where it is directly incorporated with one of the evaporation plants. Preliminary plant operation data are presented. 72 refs, 63 figs, 33 tabs

  12. Thermal stress relaxation in magnesium composites during thermal cycling

    Energy Technology Data Exchange (ETDEWEB)

    Trojanova, Z.; Lukac, P. (Karlova Univ., Prague (Czech Republic)); Kiehn, J.; Kainer, K.U.; Mordike, B.L. (Technische Univ. Clausthal, Clausthal-Zellerfeld (Germany))

    1998-01-01

    It has been shown that the internal friction of Mg - Saffil metal matrix composites can be influenced by thermal stresses, if MMCc are submitted to thermal cycling between room temperature and an upper temperature of cycling. These stresses can be accommodated by generation and motion of dislocations giving the formation of the microplastic zones. The thermal stress relaxation depends on the upper temperature of cycling, the volume fraction of reinforcement and the matrix composition and can result in plastic deformation and strain hardening of the matrix without applied stress. The internal friction measurements can be used for non destructive investigation of processes which influence the mechanical properties. (orig.)

  13. Ultrafast Thermal Cycling of Solar Panels

    National Research Council Canada - National Science Library

    Wall, T

    1998-01-01

    Two new cyclers that utilize a novel hybrid approach to perform fast thermal cycling of solar panels have been built and are now operational in the Mechanics and Materials Technology Center at The Aerospace Corporation...

  14. Seasonal Solar Thermal Absorption Energy Storage Development.

    Science.gov (United States)

    Daguenet-Frick, Xavier; Gantenbein, Paul; Rommel, Mathias; Fumey, Benjamin; Weber, Robert; Gooneseker, Kanishka; Williamson, Tommy

    2015-01-01

    This article describes a thermochemical seasonal storage with emphasis on the development of a reaction zone for an absorption/desorption unit. The heat and mass exchanges are modelled and the design of a suitable reaction zone is explained. A tube bundle concept is retained for the heat and mass exchangers and the units are manufactured and commissioned. Furthermore, experimental results of both absorption and desorption processes are presented and the exchanged power is compared to the results of the simulations.

  15. Methods and compositions for rapid thermal cycling

    Energy Technology Data Exchange (ETDEWEB)

    Beer, Neil Reginald; Benett, William J.; Frank, James M.; Deotte, Joshua R.; Spadaccini, Christopher

    2018-04-10

    The rapid thermal cycling of a material is targeted. A microfluidic heat exchanger with an internal porous medium is coupled to tanks containing cold fluid and hot fluid. Fluid flows alternately from the cold tank and the hot tank into the porous medium, cooling and heating samples contained in the microfluidic heat exchanger's sample wells. A valve may be coupled to the tanks and a pump, and switching the position of the valve may switch the source and direction of fluid flowing through the porous medium. A controller may control the switching of valve positions based on the temperature of the samples and determined temperature thresholds. A sample tray for containing samples to be thermally cycled may be used in conjunction with the thermal cycling system. A surface or internal electrical heater may aid in heating the samples, or may replace the necessity for the hot tank.

  16. Standard Practice for Evaluating Solar Absorptive Materials for Thermal Applications

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2007-01-01

    1.1 This practice covers a testing methodology for evaluating absorptive materials used in flat plate or concentrating collectors, with concentrating ratios not to exceed five, for solar thermal applications. This practice is not intended to be used for the evaluation of absorptive surfaces that are (1) used in direct contact with, or suspended in, a heat-transfer liquid, (that is, trickle collectors, direct absorption fluids, etc.); (2) used in evacuated collectors; or (3) used in collectors without cover plate(s). 1.2 Test methods included in this practice are property measurement tests and aging tests. Property measurement tests provide for the determination of various properties of absorptive materials, for example, absorptance, emittance, and appearance. Aging tests provide for exposure of absorptive materials to environments that may induce changes in the properties of test specimens. Measuring properties before and after an aging test provides a means of determining the effect of the exposure. 1.3 Th...

  17. Thermodynamic analysis of diesel engine coupled with ORC and absorption refrigeration cycle

    International Nuclear Information System (INIS)

    Salek, Farhad; Moghaddam, Alireza Naghavi; Naserian, Mohammad Mahdi

    2017-01-01

    Highlights: • Coupling ORC and Ammonia absorption cycles with diesel engine to recover energy. • By using designed bottoming system, recovered diesel engine energy is about 10%. • By using designed bottoming system, engine efficiency will grow about 4.65%. - Abstract: In this paper, Rankine cycle and Ammonia absorption cycle are coupled with Diesel engine to recover the energy of exhaust gases. The novelty of this paper is the use of ammonia absorption refrigeration cycle bottoming Rankine cycle which coupled with diesel engine to produce more power. Bottoming system converts engine exhaust thermal energy to cooling and mechanical energy. Energy transfer process has been done by two shell and tube heat exchangers. Simulation processes have been done by programming mathematic models of cycles in EES Program. Based on results, recovered energy varies with diesel engine load. For the particular load case of current research, the use of two heat exchangers causes 0.5% decrement of engine mechanical power. However, the recovered energy is about 10% of engine mechanical power.

  18. Absorption Cycle Heat Pump Model for Control Design

    DEFF Research Database (Denmark)

    Vinther, Kasper; Just Nielsen, Rene; Nielsen, Kirsten Mølgaard

    2015-01-01

    Heat pumps have recently received increasing interest due to green energy initiatives and increasing energy prices. In this paper, a nonlinear dynamic model of a single-effect LiBr-water absorption cycle heat pump is derived for simulation and control design purposes. The model is based on an act......Heat pumps have recently received increasing interest due to green energy initiatives and increasing energy prices. In this paper, a nonlinear dynamic model of a single-effect LiBr-water absorption cycle heat pump is derived for simulation and control design purposes. The model is based...... to operational data and different scenarios are simulated to investigate the operational stability of the heat pump. Finally, this paper provides suggestions and examples of derivation of lower order linear models for control design. © Copyright IEEE - All rights reserved....

  19. A novel absorption refrigeration cycle for heat sources with large temperature change

    International Nuclear Information System (INIS)

    Yan, Xiaona; Chen, Guangming; Hong, Daliang; Lin, Shunrong; Tang, Liming

    2013-01-01

    To increase the use efficiency of available thermal energy in the waste gas/water, a novel high-efficient absorption refrigeration cycle regarded as an improved single-effect/double-lift configuration is proposed. The improved cycle using an evaporator/absorber (E/A) promotes the coefficient of performance and reduces the irreversible loss. Water–lithium bromide is used as the working pair and a simulation study under the steady working conditions is conducted. The results show that the temperature of waste gas discharged is about 20 °C lower than that of the conventional single-effect cycle and the novel cycle we proposed can achieve more cooling capacity per unit mass of waste gas/water at the simulated working conditions. -- Graphical abstract: Pressure – temperature diagram for water – lithium bromide. Highlights: ► A novel waste heat-driven absorption refrigeration cycle is presented. ► The novel cycle can reject heat at much lower temperature. ► The available temperature range of heat source of the proposed cycle is wider. ► Multiple heat sources with different temperatures can be used in the novel cycle

  20. Influence of Thermal Cycling on Cryogenic Thermometers

    CERN Document Server

    Balle, C; Rieubland, Jean Michel; Suraci, A; Togny, F; Vauthier, N

    1999-01-01

    The stringent requirements on temperature control of the superconducting magnets for the Large Hadron Collider (LHC), impose that the cryogenic temperature sensors meet compelling demands such as long-term stability, radiation hardness, readout accuracy better than 5 mK at 1.8 K and compatibility with industrial control equipment. This paper presents the results concerning long-term stability of resistance temperature sensors submitted to cryogenic thermal cycles. For this task a simple test facility has been designed, constructed and put into operation for cycling simultaneously 115 cryogenic thermometers between 300 K and 4.2 K. A thermal cycle is set to last 71/4 hours: 3 hours for either cooling down or warming up the sensors and 1 respectively 1/4 hour at steady temperature conditions at each end of the temperature cycle. A Programmable Logic Controller (PLC) drives automatically this operation by reading 2 thermometers and actuating on 3 valves and 1 heater. The first thermal cycle was accomplished in a...

  1. Analysis of Decentralized Control for Absorption Cycle Heat Pumps

    DEFF Research Database (Denmark)

    Vinther, Kasper; Just Nielsen, Rene; Nielsen, Kirsten Mølgaard

    2015-01-01

    Email Print Request Permissions This paper investigates decentralized control structures for absorption cycle heat pumps and a dynamic nonlinear model of a single-effect LiBr-water absorption system is used as case study. The model has four controllable inputs, which can be used to stabilize...... the operation of the heat pump under different load conditions. Different feasible input-output pairings are analyzed by computation of relative gain array matrices and scaled condition numbers, which indicate the best pairing choice and the potential of each input-output set. Further, it is possible...... to minimize the effect of cross couplings and improve stability with the right pairing of input and output. Simulation of selected candidate input-output pairings demonstrate that decentralized control can provide stable operation of the heat pump....

  2. Thermal properties of carbon black aqueous nanofluids for solar absorption

    Directory of Open Access Journals (Sweden)

    Han Dongxiao

    2011-01-01

    Full Text Available Abstract In this article, carbon black nanofluids were prepared by dispersing the pretreated carbon black powder into distilled water. The size and morphology of the nanoparticles were explored. The photothermal properties, optical properties, rheological behaviors, and thermal conductivities of the nanofluids were also investigated. The results showed that the nanofluids of high-volume fraction had better photothermal properties. Both carbon black powder and nanofluids had good absorption in the whole wavelength ranging from 200 to 2,500 nm. The nanofluids exhibited a shear thinning behavior. The shear viscosity increased with the increasing volume fraction and decreased with the increasing temperature at the same shear rate. The thermal conductivity of carbon black nanofluids increased with the increase of volume fraction and temperature. Carbon black nanofluids had good absorption ability of solar energy and can effectively enhance the solar absorption efficiency.

  3. Performance evaluation of combined ejector LiBr/H2O absorption cooling cycle

    Directory of Open Access Journals (Sweden)

    Hasan Sh. Majdi

    2016-03-01

    Full Text Available The objective of this work is to develop a computer simulation program to evaluate the performance of solar-assited combined ejector absorption (single-effect cooling system using LiBr/H2O as a working fluid and operating under steady-state conditions. The ejector possess no moving parts and is simple and reliable, which makes it attractive for combination with single-stage absorption cycle for further improvement to the system's performance. In this research, improvement to the system is achieved by utilizing the potential kinetic energy of the ejector to enhance refrigeration efficiency. The effects of the entrainment ratio of the ejector, operating temperature, on the thermal loads, and system performance have been investigated. The results showed that the evaporator and condenser loads, post-addition of the ejector, is found to be permanently higher than that in the basic cycle, which indicates a significant enhancement of the proposed cycle and the cooling capacity of the system increasing with the increase in evaporator temperature and entrainment ratio. The COP of the modified cycle is improved by up to 60 % compared with that of the basic cycle at the given condition. This process stabilizes the refrigeration system, enhanced its function, and enabled the system to work under higher condenser temperatures.

  4. High stability of palladium/kieselguhr composites during absorption/desorption cycling for hydrogen isotope separation

    Energy Technology Data Exchange (ETDEWEB)

    Lei, Yang, E-mail: lei.y@outlook.com; Liu, Xiaopeng; Li, Shuo; Jiang, Lijun; Zhang, Chao; Li, Shuai; He, Di; Wang, Shumao

    2016-12-15

    Highlights: • Pd/K composites with as high as 57 wt.% of Pd have been successfully prepared. • Palladium particles can be effectively packed into the pores of kieselguhr substrates. • Variation of heat-treatment temperatures hardly affect hydrogen absorption capacity and hydrogen saturation time of the Pd/K. • Anti-pulverization property of Pd/K can be improved by packing palladium into the kieselguhr internal pores and heating at 1300 °C. - Abstract: Palladium/kieselguhr (Pd/K) composites with 57 wt.% of Pd were prepared by an improved dipping and thermal decomposition method and heated at elevated temperature to reduce breakdown during hydrogenation-dehydrogenation cycles. The hydrogen absorption kinetic properties of the samples heated at different temperatures were tested under the condition of 20 °C with 100 kPa hydrogen pressure. The 1300 °C heated Pd/K composites were repeated up to 4010 absorption and desorption cycles at temperature ranges between −40 °C and 200 °C. The results show that the phase structure, hydrogen absorption capacity and hydrogen saturation time of the Pd/K were not affected by the change of heat-treated temperatures. And after heat treatment at 1300 °C, the Pd/K particles were strengthened and fraction of larger than 80 mesh were as high as 93.4%.

  5. The absorption of thermal radiation by water films

    International Nuclear Information System (INIS)

    Pearson, K.G.; Elliott, D.

    1977-04-01

    Except at the shortest wavelengths (i.e. <2μm) liquid water is relatively opaque to thermal radiation. It is also a poor reflector, reflecting back only about 2% of normal incident radiation. It is shown that when radiation falls on a plane water surface from a parallel heated surface about 93.5% of the incident radiation enters the surface, the remaining 6.5% being reflected back to the source. It is also shown that, for source temperatures up to the maximum of interest in reactor safety studies, a large fraction of the thermal radiation which enters the water is absorbed on passing through a distance approaching 0.5 mm. Since liquid water films of such thickness can be expected to exist on the pressure tubes of an SGHWR following a loss of coolant accident it follows that, irrespective of the condition of the pressure tube wall, the absorptivity of the pressure tubes will in effect be about 0.9. Data are presented for experiments performed to determine the absorptivity of water films on a polished surface whose dry absorptivity was measured to be 0.18. The presence of the water film, of estimated thickness 0.3 mm, increased the absorptivity of the surface to a value close to unity. (author)

  6. Absorption refrigeration cycle applied to offshore platforms; Refrigeracao por absorcao aplicada a plataformas de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Maximino Joaquim Pina [KROMAV Engenharia, Rio de Janeiro, RJ (Brazil); Pinto, Luiz Antonio Vaz; Belchior, Carlos Rodrigues Pereira [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia (COPPE)

    2004-07-01

    To produce cold from the heat seems a task unlikely or even impossible. However, absorption systems produce cooling from heat sources and it exist since the century XIX. In industrial places is very important to improve the energy use, even more in places where the activities involve great costs and incomes. Traditionally the alternatives conflict in the aspects of initial and operational costs. This paper describes the absorption systems operation and its main advantages and disadvantages, when compared to the traditional systems with compressor. The known fact that a vapor compressor system presents larger efficiency is not enough to validate it for all of the applications. In this sense, the initial and operational analysis of the costs of the absorption systems becomes interesting. In spite of, double effect absorption systems are demonstrating the evolution of the absorption cycle in order to obtain better performance. Turbo-generators and Turbo-compressors of the offshore platforms are thermal machines that reject great amount of heat in the exhaust gases. This heat is used for heating of water used in the Process Plant. The processes of separation of the mixture water-oil-gas from the well, for instance, use that heat. Even after the passage of the water in the Plant of Process, the residual heat is still enough for the use in absorption systems. A simulation is done using real data of an offshore platform. Two possible alternatives are compared under technical and economical aspects. Sensibility analysis is also performed in order to verify possible impacts of variations of electric power cost. (author)

  7. Thermal neutron absorption cross section of small samples

    International Nuclear Information System (INIS)

    Nghiep, T.D.; Vinh, T.T.; Son, N.N.; Vuong, T.V.; Hung, N.T.

    1989-01-01

    A modified steady method for determining the macroscopic thermal neutron absorption cross section of small samples 500 cm 3 in volume is described. The method uses a moderating block of paraffin, Pu-Be neutron source emitting 1.1x10 6 n.s. -1 , SNM-14 counter and ordinary counting equipment. The interval of cross section from 2.6 to 1.3x10 4 (10 -3 cm 2 g -1 ) was measured. The experimental data are described by calculation formulae. 7 refs.; 4 figs

  8. Gigahertz-peaked Spectra Pulsars and Thermal Absorption Model

    Energy Technology Data Exchange (ETDEWEB)

    Kijak, J.; Basu, R.; Lewandowski, W.; Rożko, K. [Janusz Gil Institute of Astronomy, University of Zielona Góra, ul. Z. Szafrana 2, PL-65-516 Zielona Góra (Poland); Dembska, M., E-mail: jkijak@astro.ia.uz.zgora.pl [DLR Institute of Space Systems, Robert-Hooke-Str. 7 D-28359 Bremen (Germany)

    2017-05-10

    We present the results of our radio interferometric observations of pulsars at 325 and 610 MHz using the Giant Metrewave Radio Telescope. We used the imaging method to estimate the flux densities of several pulsars at these radio frequencies. The analysis of the shapes of the pulsar spectra allowed us to identify five new gigahertz-peaked spectra (GPS) pulsars. Using the hypothesis that the spectral turnovers are caused by thermal free–free absorption in the interstellar medium, we modeled the spectra of all known objects of this kind. Using the model, we were able to put some observational constraints on the physical parameters of the absorbing matter, which allows us to distinguish between the possible sources of absorption. We also discuss the possible effects of the existence of GPS pulsars on future search surveys, showing that the optimal frequency range for finding such objects would be from a few GHz (for regular GPS sources) to possibly 10 GHz for pulsars and radio magnetars exhibiting very strong absorption.

  9. Thermal Cycling of Uranium Dioxide - Tungsten Cermet Fuel Specimens

    Energy Technology Data Exchange (ETDEWEB)

    Gripshover, P.J.; Peterson, J.H.

    1969-12-08

    In phase I tungsten clad cermet fuel specimens were thermal cycled, to study the effects of fuel loading, fuel particle size, stablized fuel, duplex coatings, and fabrication techniques on dimensional stability during thermal cycling. In phase II the best combination of the factors studies in phase I were combined in one specimen for evaluation.

  10. Modeling the thermal absorption factor of photovoltaic/thermal combi-panels

    International Nuclear Information System (INIS)

    Santbergen, R.; Zolingen, R.J.Ch. van

    2006-01-01

    In a photovoltaic/thermal combi-panel solar cells generate electricity while residual heat is extracted to be used for tap water heating or room heating. In such a panel the entire solar spectrum can be used in principle. Unfortunately long wavelength solar irradiance is poorly absorbed by the semiconductor material in standard solar cells. A computer model was developed to determine the thermal absorption factor of crystalline silicon solar cells. It was found that for a standard untextured solar cell with a silver back contact a relatively large amount of long wavelength irradiance is lost by reflection resulting in an absorption factor of only 74%. The model was then used to investigate ways to increase this absorption factor. One way is absorbing long wavelength irradiance in a second absorber behind a semi-transparent solar cell. According to the model this will increase the total absorption factor to 87%. The second way is to absorb irradiance in the back contact of the solar cell by using rough interfaces in combination with a non-standard metal as back contact. Theoretically the absorption factor can then be increased to 85%

  11. Effective thermal neutron absorption cross section for heterogeneous mixture

    International Nuclear Information System (INIS)

    Gabanska, B.; Igielski, A.; Krynicka-Drozdowicz, E.; Woznicka, U.

    1989-01-01

    The first estimations (basing on Umiastowski's theory) of the influence of the sample heterogeneity of the effective thermal neutron absorption cross section were compared with the results obtained for the homogeneous mixture which components and concentration were the same as those of the heterogeneous sample. An experiment was prepared to determine how good this estimate is. Three artificial heterogeneous cylindrical samples (2R = H = 9 cm) were manufactured from pure silver cylinders embedded in plexiglass, keeping the Ag content and varying the size of cylinders (2R = H = 1.0 cm, 0.6 cm and 0.4 cm). Calculations performed show that the experimental effect of the sample heterogeneity can be significant. 5 figs., 5 tabs, 11 refs. (author)

  12. Intermittent Solar Ammonia Absorption Cycle (ISAAC) refrigeration for lesser developed countries

    Science.gov (United States)

    Erickson, Donald C.

    1990-02-01

    The Intermittent Solar Ammonia Absorption Cycle (ISAAC) refrigerator is a solar thermal technology which provides low cost, efficient, reliable ice-making to areas without ready access to electricity. An ISAAC refrigeration system consists of a compound parabolic solar collector, two pressure vessels, a condenser, a cold box or refrigerated space, and simple connective piping -- no moving parts or electrical components. Most parts are simple construction or plumbing grade materials, locally available in many remote areas. This technology has numerous potential benefits in lesser developed countries both by providing a cheap, reliable source of ice, and, since manufacture requires only semi-skilled labor, a source of employment to the local economy. Applications include vaccine storage for health care clinics; fish, meat, and dairy product storage; and personal consumption. Importantly, this technology increases the quality of life for people in lesser developed countries without depleting fossil fuel resources or increasing the release of greenhouse gases such as CO2 and chlorofluorocarbons.

  13. Effects of thermal motion on electromagnetically induced absorption

    International Nuclear Information System (INIS)

    Tilchin, E.; Wilson-Gordon, A. D.; Firstenberg, O.

    2011-01-01

    We describe the effect of thermal motion and buffer-gas collisions on a four-level closed N system interacting with strong pump(s) and a weak probe. This is the simplest system that experiences electromagnetically induced absorption (EIA) due to transfer of coherence via spontaneous emission from the excited state to the ground state. We investigate the influence of Doppler broadening, velocity-changing collisions (VCC), and phase-changing collisions (PCC) with a buffer gas on the EIA spectrum of optically active atoms. In addition to exact expressions, we present an approximate solution for the probe absorption spectrum, which provides physical insight into the behavior of the EIA peak due to VCC, PCC, and the wave-vector difference between the pump and probe beams. VCC are shown to produce a wide pedestal at the base of the EIA peak, which is scarcely affected by the pump-probe angular deviation, whereas the sharp central EIA peak becomes weaker and broader due to the residual Doppler-Dicke effect. Using diffusionlike equations for the atomic coherences and populations, we construct a spatial-frequency filter for a spatially structured probe beam and show that Ramsey narrowing of the EIA peak is obtained for beams of finite width.

  14. Influence of thermal effects induced by nonlinear absorption on four-wave mixing in silicon waveguides

    DEFF Research Database (Denmark)

    Pu, Minhao; Chen, Yaohui; Yvind, Kresten

    2014-01-01

    Influence of thermal effects induced by nonlinear absorption on four-wave mixing in silicon waveguides is investigated. A conversion bandwidth reduction up to 63% is observed in simulation due to the thermal effects.......Influence of thermal effects induced by nonlinear absorption on four-wave mixing in silicon waveguides is investigated. A conversion bandwidth reduction up to 63% is observed in simulation due to the thermal effects....

  15. Thermal cycling fatigue of organic thermal interface materials using a thermal-displacement measurement technique

    Science.gov (United States)

    Steill, Jason Scott

    The long term reliability of polymer-based thermal interface materials (TIM) is essential for modern electronic packages which require robust thermal management. The challenge for today's materials scientists and engineers is to maximize the heat flow from integrated circuits through a TIM and out the heat sink. Thermal cycling of the electronic package and non-uniformity in the heat flux with respect to the plan area can lead to void formation and delamination which re-introduces inefficient heat transfer. Measurement and understanding at the nano-scale is essential for TIM development. Finding and documenting the evolution of the defects is dependent upon a full understanding of the thermal probes response to changing environmental conditions and the effects of probe usage. The response of the thermal-displacement measurement technique was dominated by changes to the environment. Accurate measurement of the thermal performance was hindered by the inability to create a model system and control the operating conditions. This research highlights the need for continued study into the probe's thermal and mechanical response using tightly controlled test conditions.

  16. Thermally regenerative hydrogen/oxygen fuel cell power cycles

    Science.gov (United States)

    Morehouse, J. H.

    1986-01-01

    Two innovative thermodynamic power cycles are analytically examined for future engineering feasibility. The power cycles use a hydrogen-oxygen fuel cell for electrical energy production and use the thermal dissociation of water for regeneration of the hydrogen and oxygen. The TDS (thermal dissociation system) uses a thermal energy input at over 2000 K to thermally dissociate the water. The other cycle, the HTE (high temperature electrolyzer) system, dissociates the water using an electrolyzer operating at high temperature (1300 K) which receives its electrical energy from the fuel cell. The primary advantages of these cycles is that they are basically a no moving parts system, thus having the potential for long life and high reliability, and they have the potential for high thermal efficiency. Both cycles are shown to be classical heat engines with ideal efficiency close to Carnot cycle efficiency. The feasibility of constructing actual cycles is investigated by examining process irreversibilities and device efficiencies for the two types of cycles. The results show that while the processes and devices of the 2000 K TDS exceed current technology limits, the high temperature electrolyzer system appears to be a state-of-the-art technology development. The requirements for very high electrolyzer and fuel cell efficiencies are seen as determining the feasbility of the HTE system, and these high efficiency devices are currently being developed. It is concluded that a proof-of-concept HTE system experiment can and should be conducted.

  17. Parametric analysis for a new combined power and ejector-absorption refrigeration cycle

    International Nuclear Information System (INIS)

    Wang Jiangfeng; Dai Yiping; Zhang Taiyong; Ma Shaolin

    2009-01-01

    A new combined power and ejector-absorption refrigeration cycle is proposed, which combines the Rankine cycle and the ejector-absorption refrigeration cycle, and could produce both power output and refrigeration output simultaneously. This combined cycle, which originates from the cycle proposed by authors previously, introduces an ejector between the rectifier and the condenser, and provides a performance improvement without greatly increasing the complexity of the system. A parametric analysis is conducted to evaluate the effects of the key thermodynamic parameters on the cycle performance. It is shown that heat source temperature, condenser temperature, evaporator temperature, turbine inlet pressure, turbine inlet temperature, and basic solution ammonia concentration have significant effects on the net power output, refrigeration output and exergy efficiency of the combined cycle. It is evident that the ejector can improve the performance of the combined cycle proposed by authors previously.

  18. Développement d'un nouveau thermo-transformateur à absorption-démixtion : optimisation conjointe du cycle et du mélange de travail

    OpenAIRE

    Noubli , Halima

    2010-01-01

    This work is a study of a new type of Absorption-Demixing Heat Transformer (ADHT), using a mixture exhibiting a miscibility gap at low temperature. In this cycle, the separation step is performed by settling obtained after cooling the mixture. The separation is then energetically free and enables to reach thermal yields higher than those obtained for classical absorption heat transformers where separation is done by distillation.In order to find suitable working mixtures to reach temperature ...

  19. Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles

    Science.gov (United States)

    Cassano, Anthony A.

    1985-01-01

    A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs.

  20. Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles

    Science.gov (United States)

    Cassano, A.A.

    1985-07-02

    A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs. 3 figs.

  1. Performance analysis of an absorption double-effect cycle for power and cold generation using ammonia/lithium nitrate

    International Nuclear Information System (INIS)

    Ventas, R.; Lecuona, A.; Vereda, C.; Rodriguez-Hidalgo, M.C.

    2017-01-01

    Highlights: • Two-stage double-effect cycle for combined power and cooling with flexibility. • Ammonia/lithium nitrate as solution for the absorption cycle. • Efficiency, when only producing power, of 19.5% for a generation temperature of 173 °C. • When combined cooling and power COP = 0.53 and electric efficiency of 5% for a generation temperature of 140 °C. • Better efficiencies than conventional double-effect cycles. - Abstract: The performance of a two-stage double-effect absorption machine for combined power and cold generation is proposed and studied theoretically, generating innovative schemes. The ammonia/lithium nitrate solution allows this cycle, consuming either solar thermal or residual heat. The machine is represented by means of a thermodynamic steady-state cycle. First, only power generation and only cold production are separately studied as function of the main internal temperatures, introducing the concepts of mixed and unmixed vapour and of virtual temperatures for allowing comparison. The results indicate that for producing power the efficiency of the cycle increases when rising the maximum pressure while for producing cold is the contrary. The maximum efficiency obtained for only power production with no superheating is 19.5% at a high generation temperature of 173 °C and at a moderate 20.3 bars of maximum pressure. The solution crystallization avoids a higher efficiency. The combined power and cooling cycle allows adapting the energy production to cold demand or to power demand by splitting the vapour generated. At a generation temperature of 132 °C, when splitting the vapour generated into half for power and half for cooling, the cycle obtains an electric efficiency of 6.5% and a COP of 0.52. This cycle is compared to a conventional double-effect cycle configured in parallel flow, obtaining the same electric efficiency but with a 32% higher COP.

  2. Solar thermal organic rankine cycle for micro-generation

    Science.gov (United States)

    Alkahli, N. A.; Abdullah, H.; Darus, A. N.; Jalaludin, A. F.

    2012-06-01

    The conceptual design of an Organic Rankine Cycle (ORC) driven by solar thermal energy is developed for the decentralized production of electricity of up to 50 kW. Conventional Rankine Cycle uses water as the working fluid whereas ORC uses organic compound as the working fluid and it is particularly suitable for low temperature applications. The ORC and the solar collector will be sized according to the solar flux distribution in the Republic of Yemen for the required power output of 50 kW. This will be a micro power generation system that consists of two cycles, the solar thermal cycle that harness solar energy and the power cycle, which is the ORC that generates electricity. As for the solar thermal cycle, heat transfer fluid (HTF) circulates the cycle while absorbing thermal energy from the sun through a parabolic trough collector and then storing it in a thermal storage to increase system efficiency and maintains system operation during low radiation. The heat is then transferred to the organic fluid in the ORC via a heat exchanger. The organic fluids to be used and analyzed in the ORC are hydrocarbons R600a and R290.

  3. Fast thermal cycling-enhanced electromigration in power metallization

    NARCIS (Netherlands)

    Nguyen, Van Hieu; Salm, Cora; Krabbenborg, B.H.; Krabbenborg, B.H.; Bisschop, J.; Mouthaan, A.J.; Kuper, F.G.

    Fast thermal nterconnects used in power ICs are susceptible to short circuit failure due to a combination of fast thermal cycling and electromigration stresses. In this paper, we present a study of electromigration-induced extrusion short-circuit failure in a standard two level metallization

  4. Effects of thermal cycling on aluminum metallization of power diodes

    DEFF Research Database (Denmark)

    Brincker, Mads; Pedersen, Kristian Bonderup; Kristensen, Peter Kjær

    2015-01-01

    Reconstruction of aluminum metallization on top of power electronic chips is a well-known wear out phenomenon under power cycling conditions. However, the origins of reconstruction are still under discussion. In the current study, a method for carrying out passive thermal cycling of power diodes...

  5. Engine cycle design considerations for nuclear thermal propulsion systems

    International Nuclear Information System (INIS)

    Pelaccio, D.G.; Scheil, C.M.; Collins, J.T.

    1993-01-01

    A top-level study was performed which addresses nuclear thermal propulsion system engine cycle options and their applicability to support future Space Exploration Initiative manned lunar and Mars missions. Technical and development issues associated with expander, gas generator, and bleed cycle near-term, solid core nuclear thermal propulsion engines are identified and examined. In addition to performance and weight the influence of the engine cycle type on key design selection parameters such as design complexity, reliability, development time, and cost are discussed. Representative engine designs are presented and compared. Their applicability and performance impact on typical near-term lunar and Mars missions are shown

  6. Eutectic mixtures of some fatty acids for latent heat storage: Thermal properties and thermal reliability with respect to thermal cycling

    International Nuclear Information System (INIS)

    Sari, Ahmet

    2006-01-01

    Accelerated thermal cycle tests have been conducted to study the change in melting temperatures and latent heats of fusion of the eutectic mixtures of lauric acid (LA)-myristic acid (MA), lauric acid (LA)-palmitic acid (PA) and myristic acid (MA)-stearic acid (SA) as latent heat storage materials. The thermal properties of these materials were determined by the differential scanning calorimetry (DSC) analysis method. The thermal reliability of the eutectic mixtures after melt/freeze cycles of 720, 1080 and 1460 was also evaluated using the DSC curves. The accelerated thermal cycle tests indicate that the melting temperatures usually tend to decrease, and the variations in the latent heats of fusion are irregular with increasing number of thermal cycles. Moreover, the probable reasons for the change in thermal properties of the eutectic mixtures after repeated thermal cycles were investigated. Fourier Transform Infrared (FT-IR) spectroscopic analysis indicates that the accelerated melt/freeze processes do not cause any degradation in the chemical structure of the mixtures. The change in thermal properties of the eutectic mixtures with increasing number of thermal cycles is only because of the presence of certain amounts of impurities in the fatty acids used in their preparation. It is concluded that the tested eutectic mixtures have reasonable thermal properties and thermal reliability as phase change materials (PCMs) for latent heat storage in any solar heating applications that include a four year utilization period

  7. Rapid thermal cycling of new technology solar array blanket coupons

    Science.gov (United States)

    Scheiman, David A.; Smith, Bryan K.; Kurland, Richard M.; Mesch, Hans G.

    1990-01-01

    NASA Lewis Research Center is conducting thermal cycle testing of a new solar array blanket technologies. These technologies include test coupons for Space Station Freedom (SSF) and the advanced photovoltaic solar array (APSA). The objective of this testing is to demonstrate the durability or operational lifetime of the solar array interconnect design and blanket technology within a low earth orbit (LEO) or geosynchronous earth orbit (GEO) thermal cycling environment. Both the SSF and the APSA array survived all rapid thermal cycling with little or no degradation in peak performance. This testing includes an equivalent of 15 years in LEO for SSF test coupons and 30 years of GEO plus ten years of LEO for the APSA test coupon. It is concluded that both the parallel gap welding of the SSF interconnects and the soldering of the APSA interconnects are adequately designed to handle the thermal stresses of space environment temperature extremes.

  8. Study on durability for thermal cycle of planar SOFC

    Energy Technology Data Exchange (ETDEWEB)

    Ando, Motoo; Nakata, Kei-ichi; Wakayama, Sin-ichi [Tonen Corp., Saitama (Japan)] [and others

    1996-12-31

    TONEN CORPORATION has developed planar type SOFC since 1986. We demonstrated the output of 1.3 kW in 1991 and 5.1 kW in 1995. Simultaneously we have studied how to raise electric efficiency and reliability utilizing hydrogen and propane as fuel. Durability for thermal cycle is one of the most important problems of planar SOFC to make it more practical. The planar type SOFC is made up of separator, zirconia electrolyte and glass sealant. The thermal expansion of these components are expected to be the same value, however, they still possess small differences. In this situation, a thermal cycle causes a thermal stress due to the difference of the cell components and is often followed by a rupture in cell components, therefore, the analysis of the thermal stress should give us much useful information. The thermal cycle process consists of a heating up and cooling down procedure. Zirconia electrolyte is not bonded to the separator under the condition of the initial heating up procedure, and glass sealant becomes soft or melts and glass seals spaces between the zirconia and separator. The glass sealant becomes harder with the cooling down procedure. Moreover, zirconia is tightly bonded with separator below a temperature which is defined as a constraint temperature and thermal stress also occurs. This indicates that the heating up process relaxes the thermal stress and the cooling down increases it. In this paper, we simulated dependence of the stress on the sealing configuration, thermal expansion of sealant and constraint temperature of sealant glass. Furthermore, we presented SOFC electrical properties after a thermal cycle.

  9. Ocean Thermal Energy Conversion Using Double-Stage Rankine Cycle

    Directory of Open Access Journals (Sweden)

    Yasuyuki Ikegami

    2018-03-01

    Full Text Available Ocean Thermal Energy Conversion (OTEC using non-azeotropic mixtures such as ammonia/water as working fluid and the multistage cycle has been investigated in order to improve the thermal efficiency of the cycle because of small ocean temperature differences. The performance and effectiveness of the multistage cycle are barely understood. In addition, previous evaluation methods of heat exchange process cannot clearly indicate the influence of the thermophysical characteristics of the working fluid on the power output. Consequently, this study investigated the influence of reduction of the irreversible losses in the heat exchange process on the system performance in double-stage Rankine cycle using pure working fluid. Single Rankine, double-stage Rankine and Kalina cycles were analyzed to ascertain the system characteristics. The simple evaluation method of the temperature difference between the working fluid and the seawater is applied to this analysis. From the results of the parametric performance analysis it can be considered that double-stage Rankine cycle using pure working fluid can reduce the irreversible losses in the heat exchange process as with the Kalina cycle using an ammonia/water mixture. Considering the maximum power efficiency obtained in the study, double-stage Rankine and Kalina cycles can improve the power output by reducing the irreversible losses in the cycle.

  10. Absorption cycle commercial refrigerator using wood burning cook stove; Geladeira de absorcao acionada por fogao a lenha

    Energy Technology Data Exchange (ETDEWEB)

    Pereira, Jose Tomaz Vieira; Martins, Gilberto [Universidade Estadual de Campinas, SP (Brazil). Faculdade de Engenharia Mecanica. Dept. de Energia

    1991-12-31

    The current utilization of wood burning cook stoves in Brazil and the socio-economical profile of their users were surveyed. A traditional heavy-mass wood-burning cook stove was studied as a thermal equipment. Simple changes in the geometry of the combustion chamber were suggested to improve the cooking efficiency. A closed two-phase thermosyphon using water as working fluid was designed, built and connected between the combustion chamber of the cook stove and a depressurized absorption refrigeration system to determine the heat flux and the temperature level. A commercial refrigerator unit, using the absorption cycle, was coupled with the wood stove through the thermosyphon. The overall results of the coupling point to successful country-side applications. (author) 12 refs., 9 figs., 4 tabs.

  11. Thermodynamic analysis of absorption refrigeration cycles using the second law of thermodynamics method

    Energy Technology Data Exchange (ETDEWEB)

    Aphornratana, S; Eames, I W [Sheffield Univ. (United Kingdom). Dept. of Mechanical and Process Engineering

    1995-05-01

    The paper provides an easy to follow description of the second law (of thermodynamics) method as applied to a single-effect absorption refrigerator cycle. Results are presented in a novel graphical format, which aids insight and understanding of those factors that most affect the performance of absorption refrigerators, and which in turn provides strong indicators for the direction of future research. A novel method of calculating the entropy of lithium bromide solutions is offered. (author)

  12. Standard GAX versus hybrid GAX absorption refrigeration cycle: From the view point of thermoeconomics

    International Nuclear Information System (INIS)

    Mehr, A.S.; Zare, V.; Mahmoudi, S.M.S.

    2013-01-01

    Highlights: • The SGAX cycle is found to be thermoeconomically efficient compared to HGAX cycle. • The HGAX cycle has higher COP and exergy efficiency compared to SGAX cycle. • Minimum product cost is found 180.5 $/GJ and 159.1 $/GJ for HGAX and SGAX, respectively. - Abstract: The main goal of this research is to compare thermoeconomic performance of a GAX absorption cycle and a hybrid GAX absorption cycle in which a compressor is employed to raise the absorber pressure. In order to do this, the ammonia–water standard GAX (SGAX) and hybrid GAX (HGAX) absorption refrigeration cycles are investigated and optimized from the viewpoints of thermodynamics and economics. Parametric studies are carried out and with the help of genetic algorithm (GA), the cycles’ performance is optimized based on the COP and exergy efficiency as well as the cost of unit product. Results indicate that although, compared to the GAX cycle, the HGAX cycle demonstrates a better performance from the view points of both the first and second laws of thermodynamics, the unit product cost for the HGAX cycle is higher. At the optimum operating conditions, the cost of unit product for the HGAX cycle is calculated as 180.5 $/GJ while the corresponding value for the SGAX cycle is obtained as 159.1 $/GJ. Also, the exergoeconomic analyses unfold that the condenser has the lowest exergoeconomic factor, f, in both the systems. In addition, inspired from nature, a new graphical plot is proposed to illustrate the fuel cost, product cost, capital investment and operating and maintenance cost and cost rates associated with the exergy destruction and losses within the system’s components

  13. A treatment of thermal efficiency improvement in the Brayton cycle

    International Nuclear Information System (INIS)

    Fujii, Terushige; Akagawa, Koji; Nakanishi, Shigeyasu; Inoue, Kiyoshi; Ishigai, Seikan.

    1982-01-01

    So far, as the working fluid for power-generating plants, mainly water and air (combustion gas) have been used. In this study, in regeneration and isothermal compression processes being considered as the means for the efficiency improvement in Brayton cycle, the investigation of equivalent graphical presentation method with T-S diagrams, the introduction of the new characteristic number expressing the possibility of thermal efficiency improvement by regeneration, and the investigation of the effect of the difference of working fluid on thermal efficiency were carried out. Next, as the cycle approximately realizing isothermal compression process with condensation process, the super-critical pressure cycle with liquid phase compression was rated, and four working fluids, NH 3 , SO 2 , CO 2 and H 2 O were examined as perfect gas and real gas. The advantage of CO 2 regeneration for the thermal efficiency improvement was clarified by using the dimensionless characteristic number. The graphical presentation of effective work, the thermal efficiency improvement by regeneration, the thermal efficiency improvement by making compression process isothermal, the effect on thermal efficiency due to various factors and working fluids, the characteristic number by regeneration, and the application to real working fluids are reported. (Kako, I.)

  14. Modeling of a Von Platen-Munters diffusion absorption refrigeration cycle

    Science.gov (United States)

    Agostini, Bruno; Agostini, Francesco; Habert, Mathieu

    2016-09-01

    This article presents a thermodynamical model of a Von-Platen diffusion absorption refrigeration cycle for power electronics applications. It is first validated by comparison with data available in the literature for the classical water-ammonia-helium cycle for commercial absorption fridges. Then new operating conditions corresponding to specific ABB applications, namely high ambient temperature and new organic fluids combinations compatible with aluminium are simulated and discussed. The target application is to cool power electronics converters in harsh environments with high ambient temperature by providing refrigeration without compressor, for passive components losses of about 500 W, with a compact and low cost solution.

  15. Thermo- economical consideration of Regenerative organic Rankine cycle coupling with the absorption chiller systems incorporated in the trigeneration system

    International Nuclear Information System (INIS)

    Anvari, Simin; Taghavifar, Hadi; Parvishi, Alireza

    2017-01-01

    Highlights: • A new trigeneration cycle was studied from a new viewpoint of exergoeconomic and thermodynamic. • Organic Rankine and refrigeration cycles are used for recovery waste heat of cogeneration system. • Application of trigeneration cycles is advantageous in economical and thermodynamic aspects. - Abstract: In this paper, a combined cooling, heating and power cycle is proposed consisting of three sections of gas turbine and heat recovery steam generator cycle, Regenerative organic Rankine cycle, and absorption refrigeration cycle. This trigeneration cycle is subjected to a thorough thermodynamic and exergoeconomic analysis. The principal goal followed in the investigation is to address the thermodynamic and exergoeconomic of a trigeneration cycle from a new prospective such that the economic and thermodynamic viability of incorporating Regenerative organic Rankine cycle, and absorption refrigeration cycle to the gas turbine and heat recovery steam generator cycle is being investigated. Thus, the cost-effectiveness of the introduced method can be studied and further examined. The results indicate that adding Regenerative organic Rankine cycle to gas turbine and heat recovery steam generator cycle leads to 2.5% increase and the addition of absorption refrigeration cycle to the gas turbine and heat recovery steam generator/ Regenerative Organic Rankine cycle would cause 0.75% increase in the exergetic efficiency of the entire cycle. Furthermore, from total investment cost of the trigeneration cycle, only 5.5% and 0.45% results from Regenerative organic Rankine cycle and absorption refrigeration cycles, respectively.

  16. Weldability investigation steel P 91 by weld thermal cycle simulation

    Directory of Open Access Journals (Sweden)

    M. Dunđer

    2015-07-01

    Full Text Available This paper elaborates results of hardness and impact energy of thermal cycle simulated specimens of high-alloy steel P 91 and their dependence on cooling time from 800 to 500 °C. Results were obtained by measuring hardness HV 1 and by experimental testing of Charpy notched specimens. Metallographic analysis of samples was performed on scanning electronic microscope.

  17. Enhancement of LNG plant propane cycle through waste heat powered absorption cooling

    International Nuclear Information System (INIS)

    Rodgers, P.; Mortazavi, A.; Eveloy, V.; Al-Hashimi, S.; Hwang, Y.; Radermacher, R.

    2012-01-01

    In liquefied natural gas (LNG) plants utilizing sea water for process cooling, both the efficiency and production capacity of the propane cycle decrease with increasing sea water temperature. To address this issue, several propane cycle enhancement approaches are investigated in this study, which require minimal modification of the existing plant configuration. These approaches rely on the use of gas turbine waste heat powered water/lithium bromide absorption cooling to either (i) subcool propane after the propane cycle condenser, or (ii) reduce propane cycle condensing pressure through pre-cooling of condenser cooling water. In the second approach, two alternative methods of pre-cooling condenser cooling water are considered, which consist of an open sea water loop, and a closed fresh water loop. In addition for all cases, three candidate absorption chiller configurations are evaluated, namely single-effect, double-effect, and cascaded double- and single-effect chillers. The thermodynamic performance of each propane cycle enhancement scheme, integrated in an actual LNG plant in the Persian Gulf, is evaluated using actual plant operating data. Subcooling propane after the propane cycle condenser is found to improve propane cycle total coefficient of performance (COP T ) and cooling capacity by 13% and 23%, respectively. The necessary cooling load could be provided by either a single-effect, double-effect or cascaded and single- and double-effect absorption refrigeration cycle recovering waste heat from a single gas turbine operated at full load. Reducing propane condensing pressure using a closed fresh water condenser cooling loop is found result in propane cycle COP T and cooling capacity enhancements of 63% and 22%, respectively, but would require substantially higher capital investment than for propane subcooling, due to higher cooling load and thus higher waste heat requirements. Considering the present trend of short process enhancement payback periods in the

  18. New waste heat district heating system with combined heat and power based on absorption heat exchange cycle in China

    International Nuclear Information System (INIS)

    Sun Fangtian; Fu Lin; Zhang Shigang; Sun Jian

    2012-01-01

    A new waste heat district heating system with combined heat and power based on absorption heat exchange cycle (DHAC) was developed to increase the heating capacity of combined heat and power (CHP) through waste heat recovery, and enhance heat transmission capacity of the existing primary side district heating network through decreasing return water temperature by new type absorption heat exchanger (AHE). The DHAC system and a conventional district heating system based on CHP (CDH) were analyzed in terms of both thermodynamics and economics. Compared to CDH, the DHAC increased heating capacity by 31% and increased heat transmission capacity of the existing primary side district heating network by 75%. The results showed that the exergetic efficiency of DHAC was 10.41% higher and the product exergy monetary cost was 36.6¥/GJ less than a CHD. DHAC is an effective way to increase thermal utilization factor of CHP, and to reduce district heating cost. - Highlights: ► Absorption heat pumps are used to recover waste heat in CHP. ► Absorption heat exchanger can reduce exergy loss in the heat transfer process. ► New waste heat heating system (DHAC) can increase heating capacity of CHP by 31%. ► DHAC can enhance heat transmission capacity of the primary pipe network by 75%. ► DHAC system has the higher exergetic efficiency and the better economic benefit.

  19. Absorption of plant-incorporated nuclear fuel cycle elements from the gastro-intestinal tract

    International Nuclear Information System (INIS)

    Sullivan, M.F.; Garland, T.R.; Cataldo, D.A.; Schreckhise, R.G.

    1979-01-01

    Soybean plants (Glycine max cv Williams) grown hydroponically on solutions containing ammonium pertechnetate ( 95 Tcsup(m)O - 4 ) were fed to rats (omnivores) and guinea pigs (herbivores). Absorption of plant-incorporated technetium was compared with absorption of inorganic 95 Tcsup(m) from a gavaged solution or with absorption of 95 Tcsup(m) added to non-radioactive soybean tissues. In a second study absorption of plutonium from alfalfa (Medicago sativa cv Ladak) grown on soil amended with either 238 Pu nitrate or 238 Pu-DTPA was compared with absorption of gavaged 238 Pu solutions and 238 Pu mixed with non-radioactive alfalfa. Incorporation of 95 Tcsup(m) into soybean tissues resulted in decreased absorption by both animal species. In contrast, incorporation of 238 Pu in alfalfa resulted in an increased absorption when compared with controls that were administered inorganic 238 Pu. These results suggest that organic binding may alter, in either direction, absorption of nuclear fuel cycle elements. (author)

  20. A comparative analysis of rankine and absorption power cycles from exergoeconomic viewpoint

    International Nuclear Information System (INIS)

    Shokati, Naser; Ranjbar, Faramarz; Yari, Mortaza

    2014-01-01

    Highlights: • The Rankine and absorption power cycles are compared from exergoeconomic viewpoint. • The LiBr–H 2 O cycle has the highest unit cost of electricity produced by turbine. • The LiBr–H 2 O cycle has the lowest exergy destruction cost rate. • In LiBr–H 2 O cycle, the generator has the maximum value regarding (C-dot) D,k +(C-dot) L,k +(Z-dot) k . - Abstract: In this paper LiBr–H 2 O and NH 3 –H 2 O absorption power cycles and Rankine cycle which produce 1 MW electrical power in same conditions of heat sources are compared from exergoeconomic point of view. Exergoeconomic analysis is performed using the specific exergy costing (SPECO) method. The results show that among these cycles, although the LiBr–H 2 O cycle has the highest first law efficiency, but unit cost of electricity produced by turbine for LiBr–H 2 O cycle is more than that for Rankine cycle. This value is lowest for the NH 3 –H 2 O cycle. Moreover, the NH 3 –H 2 O cycle has the highest and the LiBr–H 2 O cycle has the lowest exergy destruction cost rate. The generator, the absorber and the boiler in all considered cycles have the maximum value of sum of cost rate associated with capital investment, operating and maintenance, exergy destruction and exergy losses. Therefore, these components should be taken into consideration from exergoeconomic viewpoint. In parametric study, it is observed that in the constant generator temperature, as the generator pressure increases, unit cost of power produced by turbine for LiBr–H 2 O and Rankine cycles decreases. This value for Rankine cycle is lower than for LiBr–H 2 O cycle whereas Rankine cycle efficiency is less than the efficiency of LiBr–H 2 O cycle. Also, in LiBr–H 2 O cycle, at constant temperature of the generator, the value of exergy destruction cost rate is minimized and exergoeconomic factor is maximized at particular values of generator pressure and the more absorber pressure results the minimum value of

  1. A review of chemical heat pumps, thermodynamic cycles and thermal energy storage technologies for low grade heat utilisation

    International Nuclear Information System (INIS)

    Chan, C.W.; Ling-Chin, J.; Roskilly, A.P.

    2013-01-01

    A major cause of energy inefficiency is a result of the generation of waste heat and the lack of suitable technologies for cost-effective utilisation of low grade heat in particular. The market potential for surplus/waste heat from industrial processes in the UK is between 10 TWh and 40 TWh, representing a significant potential resource which has remained unexploited to date. This paper reviews selected technologies suitable for utilisation of waste heat energy, with specific focus on low grade heat, including: (i) chemical heat pumps, such as adsorption and absorption cycles for cooling and heating; (ii) thermodynamic cycles, such as the organic Rankine cycle (ORC), the supercritical Rankine cycle (SRC) and the trilateral cycle (TLC), to produce electricity, with further focus on expander and zeotropic mixtures, and (iii) thermal energy storage, including sensible and latent thermal energy storages and their corresponding media to improve the performance of low grade heat energy systems. - Highlights: ► The review of various thermal technologies for the utilisation of under exploited low grade heat. ► The analyses of the absorption and adsorption heat pumps possibly with performance enhancement additives. ► The analyses of thermal energy storage technologies (latent and sensible) for heat storage. ► The analyses of low temperature thermodynamic cycles to maximise power production.

  2. The influence of diffusion absorption refrigeration cycle configuration on the performance

    International Nuclear Information System (INIS)

    Zohar, A.; Jelinek, M.; Levy, A.; Borde, I.

    2007-01-01

    Based on a full thermodynamic model for ammonia-water diffusion absorption refrigeration (DAR) cycle with hydrogen as the auxiliary inert gas, the performance of two fundamental configurations of a DAR cycle, with and without condensate sub-cooling prior to the evaporator entrance, were studied and compared. The performances of the two cycles were examined parametrically by computer simulations. Mass and energy conservation equations were developed for each component of the cycles and solved numerically. It was found that the DAR cycle without condensate sub-cooling shows higher COP of 14-20% in compare with the DAR cycle with the condensate sub-cooling, but it occurs at higher evaporator temperature of about 15 deg. C

  3. Thermal cycling behaviour and thermal stability of uranium-molybdenum alloys of low molybdenum content

    International Nuclear Information System (INIS)

    Decours, J.; Fabrique, B.; Peault, O.

    1963-01-01

    We have studied the behaviour during thermal cycling of as-cast U-Mo alloys whose molybdenum content varies from 0.5 to 3 per cent; results are given concerning grain stability during extended heat treatments and the effect of treatments combining protracted heating with thermal cycling. The thermal cycling treatments were carried out at 550, 575, 600 and 625 deg C for 1000 cycles; the protracted heating experiments were done at 550, 575, 600 and 625 deg C for 2000 hours (4000 hrs at 625 deg C). The 0.5 per cent alloy resists much better to the thermal cycling than does the non-alloyed uranium. This resistance is, however, much lower than that of alloys containing over l per cent, even at 550 deg C it improves after a heat treatment for grain-refining. Alloys of over 1.1 per cent have a very good resistance to a cycling treatment even at 625 deg C, and this behaviour improves with increasing concentrations up to 3 per cent. An increase in the temperature up to the γ-phase has few disadvantages provided that it is followed by rapid cooling (50 to 100 deg C/min). The α grain is fine, the γ-phase is of the modular form, and the behaviour during a thermal cycling treatment is satisfactory. If this cooling is slow (15 deg /hr) the α-grain is coarse and cycling treatment behaviour is identical to that of the 0.5 per cent alloy. The protracted heat treatments showed that the α-grain exhibits satisfactory stability after 2000 hours at 575, 600 and 625 deg C, and after 4000 hours at 625 deg C. A heat cycling treatment carried out after these tests affects only very little the behaviour of these alloys during cycling. (authors) [fr

  4. Absorption coefficient of nearly transparent liquids measured using thermal lens spectrometry

    Directory of Open Access Journals (Sweden)

    H.Cabrera

    2006-01-01

    Full Text Available We use an optimized pump-probe mode-mismatched thermal lens scheme to determine the optical absorption coefficient and thermal diffusivity of ethanol, benzene, acetone, methanol, toluene and chloroform. In this scheme the excitation beam is focused in the presence of a collimated probe beam. The agreement between experimentally obtained results and values reported in the literature is good.

  5. Performance analysis of double-effect absorption heat pump cycle using NH

    NARCIS (Netherlands)

    Wang, M.; Infante Ferreira, C.A.

    2017-01-01

    Ionic liquids (ILs), as novel absorbents, draw considerable attention for their potential roles in replacing H2O or LiBr aqueous solutions in conventional NH3/H2O or H2O/LiBr absorption chiller or heat pump cycles. In this paper, NH3/IL working pairs are proposed for implementation in parallel

  6. Hydriding and structural characteristics of thermally cycled and cold-worked V-0.5 at.%C alloy

    International Nuclear Information System (INIS)

    Chandra, Dhanesh; Sharma, Archana; Chellappa, Raja; Cathey, William N.; Lynch, Franklin E.; Bowman, Robert C.; Wermer, Joseph R.; Paglieri, Stephen N.

    2008-01-01

    High pressure hydrides of V 0.995 C 0.005 were thermally cycled between β 2 - and γ-phases hydrides for potential use in cryocoolers/heat pumps for space applications. The effect of addition of carbon to vanadium, on the plateau enthalpies of the high pressure β 2 + γ region is minimal. This is in contrast to the calculated plateau enthalpies for low pressure (α + β 1 ) mixed phases which showed a noticeable lowering of the values. Thermal cycling between β 2 -and γ-phase hydrides increased the absorption pressures but desorption pressure did not change significantly and the free energy loss due to hysteresis also increased. Hydriding of the alloy with prior cold-work increased the pressure hysteresis significantly and lowered the hydrogen capacity. In contrast to the alloy without any prior straining (as-cast), desorption pressure of the alloy with prior cold-work also decreased significantly. Microstrains, 2 > 1/2 , in the β 2 -phase lattice of the thermally cycled hydrides decreased after 778 cycles and the domain sizes increased. However, in the γ-phase, both the microstrains and the domain sizes decreased after thermal cycling indicating no particle size effect. The dehydrogenated α-phase after 778 thermal cycles also showed residual microstrains in the lattice, similar to those observed in intermetallic hydrides. The effect of thermal cycling (up to 4000 cycles between β 2 - and γ-phases) and cold working on absorption/desorption pressures, hydrogen storage capacity, microstrains, long-range strains, and domain sizes of β 2 - and γ-phase hydrides of V 0.995 C 0.005 alloys are presented

  7. GNPS 18-months fuel cycles core thermal hydraulic design

    International Nuclear Information System (INIS)

    Liu Changwen; Zhou Zhou

    2002-01-01

    GNPS begins to implement the 18-month fuel cycles from the initial annual reload at cycle 9, thus the initial core thermal hydraulic design is not valid any more. The new critical heat flux (CHF) correlation, FC, which is developed by Framatome, is used in the design, and the generalized statistical methodology (GSM) instead of the initial deterministic methodology is used to determine the DNBR design limit. As the AFA 2G and AFA 3G are mixed loaded in the transition cycle, it will result that the minimum DNBR in the mixed core is less than that of AFA 3G homogenous core, the envelop mixed core DNBR penalty is given. Consequently the core physical limit for mixed core and equilibrium cycles, and the new over temperature ΔT overpower ΔT are determined

  8. Thermal cycling behaviour of lanthanum zirconate as EB-PVD thermal barrier coating

    International Nuclear Information System (INIS)

    Bobzin, K.; Lugscheider, E.; Bagcivan, N.

    2006-01-01

    Thermal cycling tests with two different EB-PVD thermal barrier coatings (TBC) were performed in a furnace cycle test. The results of these tests showed an increase of endurable cycle number when pyrochloric La 2 Zr 2 O 7 was used as TBC. 1865 cycles were reached with La 2 Zr 2 O 7 and 1380 cycles with 7 weigth-% yttria stabilised zirconia (YSZ) EB-PVD TBC. Additional investigation was made with scanning electron microscope (SEM) to investigate morphology and to determine chemical composition by electron dispersive x-ray spectroscopy (EDS) analysis. X-Ray diffraction was performed to analyze structural constitution of deposited coatings. (Abstract Copyright [2006], Wiley Periodicals, Inc.)

  9. High-speed thermal cycling system and method of use

    Science.gov (United States)

    Hansen, A.D.A.; Jaklevic, J.M.

    1996-04-16

    A thermal cycling system and method of use are described. The thermal cycling system is based on the circulation of temperature-controlled water directly to the underside of thin-walled polycarbonate plates. The water flow is selected from a manifold fed by pumps from heated reservoirs. The plate wells are loaded with typically 15-20 microliters of reagent mix for the PCR process. Heat transfer through the thin polycarbonate is sufficiently rapid that the contents reach thermal equilibrium with the water in less than 15 seconds. Complete PCR amplification runs of 40 three-step cycles have been performed in as little as 14.5 minutes, with the results showing substantially enhanced specificity compared to conventional technology requiring run times in excess of 100 minutes. The plate clamping station is designed to be amenable to robotic loading and unloading of the system. It includes a heated lid, thus eliminating the need for mineral oil overlay of the reactants. The present system includes three or more plate holder stations, fed from common reservoirs but operating with independent switching cycles. The system can be modularly expanded. 13 figs.

  10. Increasing thermal efficiency of Rankine cycles by using refrigeration cycles: A theoretical analysis

    International Nuclear Information System (INIS)

    Sarr, Joachim-André Raymond; Mathieu-Potvin, François

    2016-01-01

    Highlights: • A new stratagem is proposed to improve thermal efficiency of Rankine cycles. • Three new configurations are optimized by means of numerical simulations. • The Rankine-1SCR design is advantageous for 1338 different fluid combinations. • The Rankine-2SCR design is advantageous for 772 different fluid combinations. • The Rankine-3SCR design is advantageous for 768 different fluid combinations. - Abstract: In this paper, three different modifications of the basic Rankine thermodynamic cycle are proposed. The objective is to increase the thermal efficiency of power systems based on Rankine cycles. The three new systems are named “Rankine-1SCR”, “Rankine-2SCR”, and “Rankine-3SCR” cycles, and they consist of linking a refrigeration cycle to the basic Rankine cycle. The idea is to use the refrigeration cycle to create a low temperature heat sink for the Rankine cycle. These three new power plant configurations are modeled and optimized with numerical tools, and then they are compared with the basic Rankine cycle. The objective function is the thermal efficiency of the systems (i.e., net power output (kW) divided by heat rate (kW) entering the system), and the design variables are the operating temperatures within the systems. Among the 84 × 84 (i.e., 7056) possible combinations of working and cooling fluids investigated in this paper, it is shown that: (i) the Rankine-1SCR system is advantageous for 1338 different fluid combinations, (ii) the Rankine-2SCR system is advantageous for 772 different fluid combinations, and (iii) the Rankine-3SCR system is advantageous for 768 different fluid combinations.

  11. Frequency and Thermal Behavior of Acoustic Absorption in ɛ-GaSe Crystals

    Science.gov (United States)

    Dzhafarova, S. Z.

    2018-04-01

    The paper presents results of measuring acoustic absorption in ɛ-GaSe crystals. The absorption of a longitudinal wave which propagates normal to the crystal layers, quadratically depends on frequency. However, it does not depend on temperature, i.e. it displays an Akhiezer behavior although its absolute value considerably exceeds the expected. The analysis of the frequency and thermal behavior of absorption of piezoelectric waves propagating along the layers, includes the deduction of contribution made by the interaction between waves and charge carriers. This analysis shows the linear dependence between the lattice absorption of these waves and the frequency. The linear frequency and weak temperature dependences of the acoustic absorption characterize the additional ultra-Akhiezer absorption in glasses. In our case, it can be caused by various polytypes forming in GaSe crystals which differ merely in a mutual arrangement of layers.

  12. Failure of sheathed thermocouples due to thermal cycling

    International Nuclear Information System (INIS)

    Anderson, R.L.; Ludwig, R.L.

    1982-03-01

    Open circuit failures (up to 100%) in small-diameter thermocouples used in electrically heated nuclear fuel rod simulator prototypes during thermal cycling tests were investigated to determine the cause(s) of the failures. The experiments conducted to determine the relative effects of differential thermal expansion, wire size, grain size, and manufacturing technology are described. It was concluded that the large grain size and embrittlement which result from certain common manufacturing annealing and drawing procedures were a major contributing factor in the breakage of the thermocouple wires

  13. Environmental Impacts of Solar Thermal Systems with Life Cycle Assessment

    OpenAIRE

    De Laborderie , Alexis; Puech , Clément; Adra , Nadine; Blanc , Isabelle; Beloin-Saint-Pierre , Didier; Padey , Pierryves; Payet , Jérôme; Sie , Marion; Jacquin , Philippe

    2011-01-01

    Available on: http://www.ep.liu.se/ecp/057/vol14/002/ecp57vol14_002.pdf; International audience; Solar thermal systems are an ecological way of providing domestic hot water. They are experiencing a rapid growth since the beginning of the last decade. This study characterizes the environmental performances of such installations with a life-cycle approach. The methodology is based on the application of the international standards of Life Cycle Assessment. Two types of systems are presented. Fir...

  14. Absorption Refrigeration Cycles with Ammonia-Ionic Liquid Working Pairs Studied by Molecular Simulation.

    Science.gov (United States)

    Becker, Tim M; Wang, Meng; Kabra, Abhishek; Jamali, Seyed Hossein; Ramdin, Mahinder; Dubbeldam, David; Infante Ferreira, Carlos A; Vlugt, Thijs J H

    2018-04-18

    For absorption refrigeration, it has been shown that ionic liquids have the potential to replace conventional working pairs. Due to the huge number of possibilities, conducting lab experiments to find the optimal ionic liquid is infeasible. Here, we provide a proof-of-principle study of an alternative computational approach. The required thermodynamic properties, i.e., solubility, heat capacity, and heat of absorption, are determined via molecular simulations. These properties are used in a model of the absorption refrigeration cycle to estimate the circulation ratio and the coefficient of performance. We selected two ionic liquids as absorbents: [emim][Tf 2 N], and [emim][SCN]. As refrigerant NH 3 was chosen due to its favorable operating range. The results are compared to the traditional approach in which parameters of a thermodynamic model are fitted to reproduce experimental data. The work shows that simulations can be used to predict the required thermodynamic properties to estimate the performance of absorption refrigeration cycles. However, high-quality force fields are required to accurately predict the cycle performance.

  15. Absorption Refrigeration Cycles with Ammonia–Ionic Liquid Working Pairs Studied by Molecular Simulation

    Science.gov (United States)

    2018-01-01

    For absorption refrigeration, it has been shown that ionic liquids have the potential to replace conventional working pairs. Due to the huge number of possibilities, conducting lab experiments to find the optimal ionic liquid is infeasible. Here, we provide a proof-of-principle study of an alternative computational approach. The required thermodynamic properties, i.e., solubility, heat capacity, and heat of absorption, are determined via molecular simulations. These properties are used in a model of the absorption refrigeration cycle to estimate the circulation ratio and the coefficient of performance. We selected two ionic liquids as absorbents: [emim][Tf2N], and [emim][SCN]. As refrigerant NH3 was chosen due to its favorable operating range. The results are compared to the traditional approach in which parameters of a thermodynamic model are fitted to reproduce experimental data. The work shows that simulations can be used to predict the required thermodynamic properties to estimate the performance of absorption refrigeration cycles. However, high-quality force fields are required to accurately predict the cycle performance. PMID:29749996

  16. Aerosol absorption measurement with a sinusoidal phase modulating fiber optic photo thermal interferometer

    Science.gov (United States)

    Li, Shuwang; Shao, Shiyong; Mei, Haiping; Rao, Ruizhong

    2016-10-01

    Aerosol light absorption plays an important role in the earth's atmosphere direct and semi-direct radiate forcing, simultaneously, it also has a huge influence on the visibility impairment and laser engineering application. Although various methods have been developed for measuring aerosol light absorption, huge challenge still remains in precision, accuracy and temporal resolution. The main reason is that, as a part of aerosol light extinction, aerosol light absorption always generates synchronously with aerosol light scattering, and unfortunately aerosol light scattering is much stronger in most cases. Here, a novel photo-thermal interferometry is proposed only for aerosol absorption measurement without disturbance from aerosol scattering. The photo-thermal interferometry consists of a sinusoidal phase-modulating single mode fiber-optic interferometer. The thermal dissipation, caused by aerosol energy from photo-thermal conversion when irritated by pump laser through interferometer, is detected. This approach is completely insensitive to aerosol scattering, and the single mode fiber-optic interferometer is compact, low-cost and insensitive to the polarization shading. The theory of this technique is illustrated, followed by the basic structure of the sinusoidal phase-modulating fiber-optic interferometer and demodulation algorithms. Qualitative and quantitative analysis results show that the new photo-thermal interference is a potential approach for aerosol absorption detection and environmental pollution detection.

  17. Optimal design of solid oxide fuel cell, ammonia-water single effect absorption cycle and Rankine steam cycle hybrid system

    Science.gov (United States)

    Mehrpooya, Mehdi; Dehghani, Hossein; Ali Moosavian, S. M.

    2016-02-01

    A combined system containing solid oxide fuel cell-gas turbine power plant, Rankine steam cycle and ammonia-water absorption refrigeration system is introduced and analyzed. In this process, power, heat and cooling are produced. Energy and exergy analyses along with the economic factors are used to distinguish optimum operating point of the system. The developed electrochemical model of the fuel cell is validated with experimental results. Thermodynamic package and main parameters of the absorption refrigeration system are validated. The power output of the system is 500 kW. An optimization problem is defined in order to finding the optimal operating point. Decision variables are current density, temperature of the exhaust gases from the boiler, steam turbine pressure (high and medium), generator temperature and consumed cooling water. Results indicate that electrical efficiency of the combined system is 62.4% (LHV). Produced refrigeration (at -10 °C) and heat recovery are 101 kW and 22.1 kW respectively. Investment cost for the combined system (without absorption cycle) is about 2917 kW-1.

  18. Evaluation Analysis of the CO2 Emission and Absorption Life Cycle for Precast Concrete in Korea

    Directory of Open Access Journals (Sweden)

    Taehyoung Kim

    2016-07-01

    Full Text Available To comply with recent international trends and initiatives, and in order to help achieve sustainable development, Korea has established a greenhouse gas (GHG emission reduction target of 37% (851 million tons of the business as usual (BAU rate by 2030. Regarding environmentally-oriented standards such as the IGCC (International Green Construction Code, there are also rising demands for the assessment on CO2 emissions during the life cycle in accordance with ISO (International Standardization Organization’s Standard 14040. At present, precast concrete (PC engineering-related studies primarily cover structural and construction aspects, including improvement of structural performance in the joint, introduction of pre-stressed concrete and development of half PC. In the manufacture of PC, steam curing is mostly used for the early-strength development of concrete. In steam curing, a large amount of CO2 is produced, causing an environmental problem. Therefore, this study proposes a method to assess CO2 emissions (including absorption throughout the PC life cycle by using a life cycle assessment (LCA method. Using the proposed assessment method, CO2 emissions during the life cycle of a precast concrete girder (PCG were assessed. In addition, CO2 absorption was assessed against a PCG using conventional carbonation and CO2 absorption-related models. As a result, the CO2 emissions throughout the life cycle of the PCG were 1365.6 (kg-CO2/1 PCG. The CO2 emissions during the production of raw materials among the CO2 emissions throughout the life cycle of the PCG were 1390 (kg-CO2/1 PCG, accounting for a high portion to total CO2 emissions (nearly 90%. In contrast, the transportation and manufacture stages were 1% and 10%, respectively, having little effect on total CO2 emissions. Among the use of the PCG, CO2 absorption was mostly decided by the CO2 diffusion coefficient and the amount of CO2 absorption by cement paste. The CO2 absorption by carbonation

  19. Absorptive capacity, technological innovation, and product life cycle: a system dynamics model.

    Science.gov (United States)

    Zou, Bo; Guo, Feng; Guo, Jinyu

    2016-01-01

    While past research has recognized the importance of the dynamic nature of absorptive capacity, there is limited knowledge on how to generate a fair and comprehensive analytical framework. Based on interviews with 24 Chinese firms, this study develops a system-dynamics model that incorporates an important feedback loop among absorptive capacity, technological innovation, and product life cycle (PLC). The simulation results reveal that (1) PLC affects the dynamic process of absorptive capacity; (2) the absorptive capacity of a firm peaks in the growth stage of PLC, and (3) the market demand at different PLC stages is the main driving force in firms' technological innovations. This study also explores a sensitivity simulation using the variables of (1) time spent in founding an external knowledge network, (2) research and development period, and (3) knowledge diversity. The sensitivity simulation results show that the changes of these three variables have a greater impact on absorptive capacity and technological innovation during growth and maturity stages than in the introduction and declining stages of PLC. We provide suggestions on how firms can adjust management policies to improve their absorptive capacity and technological innovation performance during different PLC stages.

  20. Thermodynamic and economic studies of two new high efficient power-cooling cogeneration systems based on Kalina and absorption refrigeration cycles

    International Nuclear Information System (INIS)

    Rashidi, Jouan; Ifaei, Pouya; Esfahani, Iman Janghorban; Ataei, Abtin; Yoo, Chang Kyoo

    2016-01-01

    Highlights: • Proposing two new power and cooling cogeneration systems based on absorption chillers and Kalina cycles. • Model-based comparison through thermodynamic and economic standpoints. • Investigating sensitivity of system performance and costs to the key parameters. • Reducing total annual costs of the base system up to 8% by cogeneration. • Increasing thermal efficiency up to 4.9% despite of cooling generation. - Abstract: Two new power and cooling cogeneration systems based on Kalina cycle (KC) and absorption refrigeration cycle (AC) are proposed and studied from thermodynamic and economic viewpoints. The first proposed system, Kalina power-cooling cycle (KPCC), combines the refrigerant loop of the water-ammonia absorption chiller, consisting of an evaporator and two throttling valves with the KC. A portion of the KC mass flow enters the evaporator to generate cooling after being condensed in the KPCC system. KPCC is a flexible system adapting power and cooling cogeneration to the demand. The second proposed system, Kalina lithium bromide absorption chiller cycle (KLACC), consists of the KC and a single effect lithium bromide-water absorption chiller (AC_L_i_B_r_-_w_a_t_e_r). The KC subsystem discharges heat to the AC_L_i_B_r_-_w_a_t_e_r desorber before condensing in the condenser. The performance and economic aspects of both proposed systems are analyzed and compared with the stand alone KC. A parametric analysis is conducted to evaluate the sensitivity of efficiencies and the generated power and cooling quantities to the key operating variables. The results showed that, thermal efficiency and total annual costs decreased by 5.6% and 8% for KPCC system but increased 4.9% and 58% for KLACC system, respectively. Since the power-cooling efficiency of KLACC is 42% higher than KPCC it can be applied where the aim is cooling generation without considering economic aspects.

  1. Simulation and parametric optimisation of thermal power plant cycles

    Directory of Open Access Journals (Sweden)

    P. Ravindra Kumar

    2016-09-01

    Full Text Available The objective of the paper is to analyse parametric studies and optimum steam extraction pressures of three different (subcritical, supercritical and ultra-supercritical coal fired power plant cycles at a particular main steam temperature of 600 °C by keeping the reheat temperature at 537 °C and condenser pressure at 0.09 bar as constant. In order to maximize the heat rate gain possible with supercritical and ultra-supercritical steam conditions, eight stages of feed water heater arrangement with single reheater is considered. The system is optimized in such a way that the percentage exergetic losses are reduced for the increase of the exergetic efficiency and higher fuel utilization. The plant cycles are simulated and optimized by using Cycle Tempo 5.0 simulation software tool. From the simulation study, it is observed that the thermal efficiency of the three different power plant cycles obtained as 41.40, 42.48 and 43.03%, respectively. The specific coal consumption for three different power plant cycles are 0.56, 0.55 and 0.54 Tonnes/MWh. The improvement in feed water temperatures at the inlet of steam generator of respective cycles are 291, 305 and 316 °C.

  2. Testing of High Thermal Cycling Stability of Low Strength Concrete as a Thermal Energy Storage Material

    Directory of Open Access Journals (Sweden)

    Chao Wu

    2016-09-01

    Full Text Available Concrete has the potential to become a solution for thermal energy storage (TES integrated in concentrating solar power (CSP systems due to its good thermal and mechanical properties and low cost of material. In this study, a low strength concrete (C20 is tested at high temperatures up to 600 °C. Specimens are thermally cycled at temperatures in the range of 400–300 °C, 500–300 °C, and 600–300 °C, which TES can reach in operation. For comparison, specimens also cycled at temperature in the range of 400–25 °C (room temperature, 500–25 °C, and 600–25 °C. It is found from the test results that cracks are not observed on the surfaces of concrete specimens until the temperature is elevated up to 500 °C. There is mechanical deterioration of concrete after exposure to high temperature, especially to high thermal cycles. The residual compressive strength of concrete after 10 thermal cycles between 600 °C and 300 °C is about 58.3%, but the specimens remain stable without spalling, indicating possible use of low strength concrete as a TES material.

  3. Preparation of rock samples for measurement of the thermal neutron macroscopic absorption cross-section

    International Nuclear Information System (INIS)

    Czubek, J.A.; Burda, J.; Drozdowicz, K.; Igielski, A.; Kowalik, W.; Krynicka-Drozdowicz, E.; Woznicka, U.

    1986-03-01

    Preparation of rock samples for the measurement of the thermal neutron macroscopic absorption cross-section in small cylindrical two-region systems by a pulsed technique is presented. Requirements which should be fulfilled during the preparation of the samples due to physical assumptions of the method are given. A cylindrical vessel is filled with crushed rock and saturated with a medium strongly absorbing thermal neutrons. Water solutions of boric acid of well-known macroscopic absorption cross-section are used. Mass contributions of the components in the sample are specified. This is necessary for the calculation of the thermal neutron macroscopic absorption cross-section of the rock matrix. The conditions necessary for assuring the required accuracy of the measurement are given and the detailed procedure of preparation of the rock sample is described. (author)

  4. Two-stage double-effect ammonia/lithium nitrate absorption cycle

    International Nuclear Information System (INIS)

    Ventas, R.; Lecuona, A.; Vereda, C.; Legrand, M.

    2016-01-01

    Highlights: • A two stage double effect cycle with NH3-LiNO3 is proposed. • The cycle operates at lower pressures than conventional. • Adiabatic absorber offers better performance than the diabatic version. • Evaporator external inlet temperatures higher than −10 °C avoids crystallization. • Maximum COP is 1.25 for driving water inlet temperature of 100 C. - Abstract: The two-stage configuration of a double-effect absorption cycle using ammonia/lithium nitrate as working fluid is studied by means of a thermodynamic model. The maximum pressure of this cycle configuration is the same as the single-effect cycle, up to 15.8 bars, being an advantage over the double-effect conventional configuration with three pressure levels that exhibits much higher maximum pressure. The performance of the cycle and the limitation imposed by crystallization of the working fluid is determined for both adiabatic and diabatic absorber cycles. Both cycles offer similar COP; however the adiabatic variant shows a larger margin against crystallization. This cycle can produce cold for external inlet evaporator temperatures down to −10 °C, but for this limit the crystallization could happen at high inlet generator temperatures. The maximum COP can be 1.25 for an external inlet generator temperature of 100 °C. This cycle shows a better COP than a typical double effect cycle with in-parallel configuration for the range of the moderate temperatures under study and using the same working fluid. Comparisons with double effect cycles using H_2O/LiBr and NH_3/H_2O as working fluids are also offered, highlighting the present configurations advantages regarding COP, evaporation and condensation temperatures as well as crystallization.

  5. Cryogenic Thermal Absorptance Measurements on Small-Diameter Stainless Steel Tubing

    Science.gov (United States)

    Tuttle, James; Jahromi, Amir; Canavan, Edgar; DiPirro, Michael

    2015-01-01

    The Mid Infrared Instrument (MIRI) on the James Webb Space Telescope includes a mechanical cryocooler which cools its detectors to their 6 Kelvin operating temperature. The coolant gas flows through several meters of small-diameter stainless steel tubing, which is exposed to thermal radiation from its environment. Over much of its length this tubing is gold-plated to minimize the absorption of this radiant heat. In order to confirm that the cryocooler will meet MIRI's requirements, the thermal absorptance of this tubing was measured as a function of its environment temperature. We describe the measurement technique and present the results.

  6. SRF Performance of CEBAF After Thermal Cycle to Ambient Temperature

    CERN Document Server

    Rimmer, Robert; Preble, Joseph P; Reece, Charles E

    2005-01-01

    In September 2003, in the wake of Hurricane Isabel, JLab was without power for four days after a tree fell on the main power lines feeding the site. This was long enough to lose insulating vacuum in the cryomodules and cryogenic systems resulting in the whole accelerator warming up and the total loss of the liquid helium inventory. This thermal cycle stressed many of the cryomodule components causing several cavities to become inoperable due to helium to vacuum leaks. At the same time the thermal cycle released years of adsorbed gas from the cold surfaces. Over the next days and weeks this gas was pumped away, the insulating vacuum was restored and the machine was cooled back down and re-commissioned. In a testament to the robustness of SRF technology, only a small loss in energy capability was apparent, although individual cavities had quite different field-emission characteristics compared to before the event. In Summer 2004 a section of the machine was again cycled to room temperature during the long maint...

  7. SRF Performance of CEBAF After Thermal Cycle to Ambient Temperature

    International Nuclear Information System (INIS)

    Robert Rimmer; Jay Benesch; Joseph Preble; Charles Reece

    2005-01-01

    In September 2003, in the wake of Hurricane Isabel, JLab was without power for four days after a tree fell on the main power lines feeding the site. This was long enough to lose insulating vacuum in the cryomodules and cryogenic systems resulting in the whole accelerator warming up and the total loss of the liquid helium inventory. This thermal cycle stressed many of the cryomodule components causing several cavities to become inoperable due to helium to vacuum leaks. At the same time the thermal cycle released years of adsorbed gas from the cold surfaces. Over the next days and weeks this gas was pumped away, the insulating vacuum was restored and the machine was cooled back down and re-commissioned. In a testament to the robustness of SRF technology, only a small loss in energy capability was apparent, although individual cavities had quite different field-emission characteristics compared to before the event. In Summer 2004 a section of the machine was again cycled to room temperature during the long maintenance shutdown. We report on the overall SRF performance of the machine after these major disturbances and on efforts to characterize and optimize the new behavior for high-energy running

  8. Thermal cycling and vibration response for PREPP concrete waste forms

    International Nuclear Information System (INIS)

    Nielson, R.M.; Welch, J.M.

    1983-06-01

    The Process Experimental Pilot Plant (PREPP) will process those transuranic wastes which do not satisfy the Waste Isolation Pilot Plant (WIPP) Waste Acceptance Criteria. Since these wastes will contain considerable quantities of combustible materials, incineration will be an integral part of the treatment process. Four basic types of PREPP ash wastes have been identified. The four types are designated high metal box waste, combustible waste, average waste, and inorganic sludge. In this process, the output of the incinerator is a mixture of ash and shredded noncombustible material (principally metals) which is separated into two sizes, -1/4 inch (under-size waste) and reverse arrow 1/4 inch (oversize waste). These wastes are solidified with hydraulic cement in 55-gallon drums. Simulated PREPP waste forms prepared by Colorado School of Mines Research Institute were subjected to thermal cycling and vibration testing to demonstrate compliance with the WIPP immobilization criterion. Although actual storage and transport conditions are expected to vary somewhat from those utilized in the testing protocol, the generation of only very small amounts of particulate suggests that the immobilization criterion should be routinely met for similar waste form formulations and production procedures. However, the behavior of waste forms containing significant quantities of off-gas scrubber sludge or considerably higher waste loadings may differ. Limited thermal cycling and vibration testing of prototype waste forms should be conducted if the final formulations or production methods used for actual waste forms differ appreciably from those tested in this study. If such testing is conducted, consideration should be given to designing the experiment to accommodate a larger number of thermal cycles more representative of the duration of storage expected

  9. Thermal power generation during heat cycle near room temperature

    Science.gov (United States)

    Shibata, Takayuki; Fukuzumi, Yuya; Kobayashi, Wataru; Moritomo, Yutaka

    2018-01-01

    We demonstrate that a sodium-ion secondary battery (SIB)-type thermocell consisting of two types of Prussian blue analogue (PBA) with different electrochemical thermoelectric coefficients (S EC ≡ ∂V/∂T V and T are the redox potential and temperature, respectively) produces electrical energy during heat cycles. The device produces an electrical energy of 2.3 meV/PBA per heat cycle between 295 K (= T L) and 323 K (= T H). The ideal thermal efficiency (η = 1.0%), which is evaluated using the heat capacity (C = 4.16 meV/K) of ideal Na2Co[Fe(CN)6], reaches 11% of the Carnot efficiency (ηth = 8.7%). Our SIB-type thermocell is a promising thermoelectric device that harvests waste heat near room temperature.

  10. Property changes of some hydrogen storage alloys upon hydrogen absorption-desorption cycling

    International Nuclear Information System (INIS)

    Park, C.N.; Cho, S.W.; Choi, J.

    2005-01-01

    Hydrogen absorption-desorption cycling induced by pressure change in a closed system were carried out with LaNi 5 , La 0.7 Ce 0.3 Ni 4 Cu and TiFe 0.9 Ni 0.1 alloys. PC isotherms measured during the cycling showed some changes in hydrogen storage capacity, plateau pressure and hysteresis of the alloys. The half capacity life of LaNi 5 alloy can be projected as 70,000 cycles for room temperature pressure cycling. When La 0.7 Ce 0.3 Ni 4 Cu alloy was pressure cycled both of the plateau pressures were decreased significantly and continuously. TiFe 0.9 Ni 0.1 alloy showed a good resistance to cyclic degradation. Heat treatments of the degraded alloys under 1 atm of hydrogen gas recovered most of the hydrogen storage properties to the initial level even though they were degraded again more rapidly upon subsequent cycling. (orig.)

  11. Simultaneous Absorptance and Thermal-Diffusivity Determination of Optical Components with Laser Calorimetry Technique

    Science.gov (United States)

    Wang, Yanru; Li, Bincheng

    2012-11-01

    The laser calorimetry (LCA) technique is used to determine simultaneously the absorptances and thermal diffusivities of optical components. An accurate temperature model, in which both the finite thermal conductivity and the finite sample size are taken into account, is employed to fit the experimental temperature data measured with an LCA apparatus for a precise determination of the absorptance and thermal diffusivity via a multiparameter fitting procedure. The uniqueness issue of the multiparameter fitting is discussed in detail. Experimentally, highly reflective (HR) samples prepared with electron-beam evaporation on different substrates (BK7, fused silica, and Ge) are measured with LCA. For the HR-coated sample on a fused silica substrate, the absorptance is determined to be 15.4 ppm, which is close to the value of 17.6 ppm, determined with a simplified temperature model recommended in the international standard ISO11551. The thermal diffusivity is simultaneously determined via multiparameter fitting to be approximately 6.63 × 10-7 m2 · s-1 with a corresponding square variance of 4.8 × 10-4. The fitted thermal diffusivity is in reasonably good agreement with the literature value (7.5 × 10-7 m2 · s -1). Good agreement is also obtained for samples with BK7 and Ge substrates.

  12. Cycle Trades for Nuclear Thermal Rocket Propulsion Systems

    Science.gov (United States)

    White, C.; Guidos, M.; Greene, W.

    2003-01-01

    Nuclear fission has been used as a reliable source for utility power in the United States for decades. Even in the 1940's, long before the United States had a viable space program, the theoretical benefits of nuclear power as applied to space travel were being explored. These benefits include long-life operation and high performance, particularly in the form of vehicle power density, enabling longer-lasting space missions. The configurations for nuclear rocket systems and chemical rocket systems are similar except that a nuclear rocket utilizes a fission reactor as its heat source. This thermal energy can be utilized directly to heat propellants that are then accelerated through a nozzle to generate thrust or it can be used as part of an electricity generation system. The former approach is Nuclear Thermal Propulsion (NTP) and the latter is Nuclear Electric Propulsion (NEP), which is then used to power thruster technologies such as ion thrusters. This paper will explore a number of indirect-NTP engine cycle configurations using assumed performance constraints and requirements, discuss the advantages and disadvantages of each cycle configuration, and present preliminary performance and size results. This paper is intended to lay the groundwork for future efforts in the development of a practical NTP system or a combined NTP/NEP hybrid system.

  13. Thermal cycling characteristics of plasma synthesized mullite films

    Energy Technology Data Exchange (ETDEWEB)

    Monteiro, O.R.; Hou, P.Y.; Brown, I.G. [Lawrence Berkeley National Lab., CA (United States)

    1997-12-01

    The authors have developed a plasma-based technique for the synthesis of mullite and mullite-like films on silicon carbide substrate material. The method, which they refer to as MePIIID (for Metal Plasma Immersion Ion Implantation and Deposition), uses two vacuum arc plasma sources and simultaneous pulse biasing of the substrate in a low pressure oxygen atmosphere. The Al:Si ratio can be controlled via the separate plasma guns, and the film adhesion, structure and morphology can be controlled via the ion energy which in turn is controlled by the pulse bias voltage. The films are amorphous as-deposited, and crystalline mullite is formed by subsequent annealing at 1000 C for 2 hours in air. Adhesion between the aluminum-silicon oxide film and the substrate increases after this first annealing. They have tested the behavior of films when subjected to repetitive thermal cycling between room temperature and 1100 C, and found that the films retain their adhesion and quality. Here they review the plasma synthesis technique and the characteristics of the mullite films prepared in this way, and summarize the status of the thermal cycling experiments.

  14. Thermal modeling of cylindrical lithium ion battery during discharge cycle

    International Nuclear Information System (INIS)

    Jeon, Dong Hyup; Baek, Seung Man

    2011-01-01

    Highlights: → Transient and thermo-electric finite element analysis (FEA) of cylindrical lithium ion (Li-ion) battery was presented. → This model provides the thermal behavior of Li-ion battery during discharge cycle. → A LiCoO 2 /C battery at various discharge rates was investigated. → The contribution of heat source due to joule heating was significant at a high discharge rate. → The contribution of heat source due to entropy change was dominant at a low discharge rate. - Abstract: Transient and thermo-electric finite element analysis (FEA) of cylindrical lithium ion (Li-ion) battery was presented. The simplified model by adopting a cylindrical coordinate was employed. This model provides the thermal behavior of Li-ion battery during discharge cycle. The mathematical model solves conservation of energy considering heat generations due to both joule heating and entropy change. A LiCoO 2 /C battery at various discharge rates was investigated. The temperature profile from simulation had similar tendency with experiment. The temperature profile was decomposed with contributions of each heat sources and was presented at several discharge rates. It was found that the contribution of heat source due to joule heating was significant at a high discharge rate, whereas that due to entropy change was dominant at a low discharge rate. Also the effect of cooling condition and the LiNiCoMnO 2 /C battery were analyzed for the purpose of temperature reduction.

  15. On the Influence of the Sample Absorptivity when Studying the Thermal Degradation of Materials

    Directory of Open Access Journals (Sweden)

    Pascal Boulet

    2015-08-01

    Full Text Available The change in absorptivity during the degradation process of materials is discussed, and its influence as one of the involved parameters in the degradation models is studied. Three materials with very different behaviors are used for the demonstration of its role: a carbon composite material, which is opaque, almost grey, a plywood slab, which is opaque and spectral-dependent and a clear PMMA slab, which is semitransparent. Data are analyzed for virgin and degraded materials at different steps of thermal degradation. It is seen that absorptivity and emissivity often reach high values in the range of 0.90–0.95 with a near-grey behavior after significant thermal aggression, but depending on the materials of interest, some significant evolution may be first observed, especially during the early stages of the degradation. Supplementary inaccuracy can come from the heterogeneity of the incident flux on the slab. As a whole, discrepancies up to 20% can be observed on the absorbed flux depending on the degradation time, mainly because of the spectral variations of the absorption and up to 10% more, depending on the position on the slab. Simple models with a constant and unique value of absorptivity may then lead to inaccuracies in the evaluation of the radiative flux absorption, with possible consequences on the pyrolysis analysis, especially for properties related to the early step of the degradation process, like the time to ignition, for example.

  16. On the Influence of the Sample Absorptivity when Studying the Thermal Degradation of Materials.

    Science.gov (United States)

    Boulet, Pascal; Brissinger, Damien; Collin, Anthony; Acem, Zoubir; Parent, Gilles

    2015-08-21

    The change in absorptivity during the degradation process of materials is discussed, and its influence as one of the involved parameters in the degradation models is studied. Three materials with very different behaviors are used for the demonstration of its role: a carbon composite material, which is opaque, almost grey, a plywood slab, which is opaque and spectral-dependent and a clear PMMA slab, which is semitransparent. Data are analyzed for virgin and degraded materials at different steps of thermal degradation. It is seen that absorptivity and emissivity often reach high values in the range of 0.90-0.95 with a near-grey behavior after significant thermal aggression, but depending on the materials of interest, some significant evolution may be first observed, especially during the early stages of the degradation. Supplementary inaccuracy can come from the heterogeneity of the incident flux on the slab. As a whole, discrepancies up to 20% can be observed on the absorbed flux depending on the degradation time, mainly because of the spectral variations of the absorption and up to 10% more, depending on the position on the slab. Simple models with a constant and unique value of absorptivity may then lead to inaccuracies in the evaluation of the radiative flux absorption, with possible consequences on the pyrolysis analysis, especially for properties related to the early step of the degradation process, like the time to ignition, for example.

  17. The Reverse Thermal Effect in Epoxy Resins and Moisture Absorption in Semi-Interpenetrating Polymer Networks.

    Science.gov (United States)

    El-Sa'Ad, Leila

    1989-12-01

    termed the "reverse thermal effect". The swelling results suggested that it is more tightly bound water in the polymer which takes part in the reverse thermal effect. The absorption results for the Semi-Interpenetrating Polymer Networks suggested that the two key parameters which affected the moisture uptake were the morphology of the network and the percentage of epoxy resin in the system.

  18. Diaryl-substituted norbornadienes with red-shifted absorption for molecular solar thermal energy storage.

    Science.gov (United States)

    Gray, Victor; Lennartson, Anders; Ratanalert, Phasin; Börjesson, Karl; Moth-Poulsen, Kasper

    2014-05-25

    Red-shifting the absorption of norbornadienes (NBDs), into the visible region, enables the photo-isomerization of NBDs to quadricyclanes (QCs) to be driven by sunlight. This is necessary in order to utilize the NBD-QC system for molecular solar thermal (MOST) energy storage. Reported here is a study on five diaryl-substituted norbornadienes. The introduced aryl-groups induce a significant red-shift of the UV/vis absorption spectrum of the norbornadienes, and device experiments using a solar-simulator set-up demonstrate the potential use of these compounds for MOST energy storage.

  19. The effect of spheroidizing by thermal cycling in low concentration Cr-Mo alloy steel

    International Nuclear Information System (INIS)

    Yun, H.S.; Kang, C.Y.

    1979-01-01

    An intensive study was carried out on spheroidizing of pearlite (Sph) and number of spherical carbide in proeutectoid ferrite (No/100) of low concentration Cr-Mo steel with thermal cycling. Physical and mechanical properties of steel containing 0.33 % C with thermal cycling were compared with those of low concentration Cr-Mo steel with thermal cycling. The effect of normal heat treatment and cooling rate on spheroidizing of pearlite and precipitation of fine spherical carbide in the steels were investigated. The results obtained were as follows: 1) Thermal cycling of low concentration Cr-Mo steel promoted the spheroidizing of pearlite compared with that of steel without Cr and Mo to steel had significant effect on spheroidizing of pearlite. 2) Number of fine spherical carbides of low concentration Cr-Mo steel with thermal cycling was over 5 times to that of fine spherical carbides of hypoeutectoid steel with thermal cycling. 3) Spheroidizing of pearlite and number of fine spherical carbide in proeutectoid ferrite of low concentration Cr-Mo steel with increasing thermal cycle and cooling rate. 4) Hardness of steel with thermal cycling was decreased. However, low concentration Cr-Mo steel had little decreasing rate in hardness with increasing thermal cycle on the basis of 100 times in thermal cycle. Therefore, toughness was considered to be increased with increasing spheroidizing of pearlite without changing mechanical properties. (author)

  20. Effect of thermal state and thermal comfort on cycling performance in the heat.

    Science.gov (United States)

    Schulze, Emiel; Daanen, Hein A M; Levels, Koen; Casadio, Julia R; Plews, Daniel J; Kilding, Andrew E; Siegel, Rodney; Laursen, Paul B

    2015-07-01

    To determine the effect of thermal state and thermal comfort on cycling performance in the heat. Seven well-trained male triathletes completed 3 performance trials consisting of 60 min cycling at a fixed rating of perceived exertion (14) followed immediately by a 20-km time trial in hot (30°C) and humid (80% relative humidity) conditions. In a randomized order, cyclists either drank ambient-temperature (30°C) fluid ad libitum during exercise (CON), drank ice slurry (-1°C) ad libitum during exercise (ICE), or precooled with iced towels and ice slurry ingestion (15 g/kg) before drinking ice slurry ad libitum during exercise (PC+ICE). Power output, rectal temperature, and ratings of thermal comfort were measured. Overall mean power output was possibly higher in ICE (+1.4%±1.8% [90% confidence limit]; 0.4> smallest worthwhile change [SWC]) and likely higher PC+ICE (+2.5%±1.9%; 1.5>SWC) than in CON; however, no substantial differences were shown between PC+ICE and ICE (unclear). Time-trial performance was likely enhanced in ICE compared with CON (+2.4%±2.7%; 1.4>SWC) and PC+ICE (+2.9%±3.2%; 1.9>SWC). Differences in mean rectal temperature during exercise were unclear between trials. Ratings of thermal comfort were likely and very likely lower during exercise in ICE and PC+ICE, respectively, than in CON. While PC+ICE had a stronger effect on mean power output compared with CON than ICE did, the ICE strategy enhanced late-stage time-trial performance the most. Findings suggest that thermal comfort may be as important as thermal state for maximizing performance in the heat.

  1. Optical absorption and thermal transport of individual suspended carbon nanotube bundles.

    Science.gov (United States)

    Hsu, I-Kai; Pettes, Michael T; Bushmaker, Adam; Aykol, Mehmet; Shi, Li; Cronin, Stephen B

    2009-02-01

    A focused laser beam is used to heat individual single-walled carbon nanotube bundles bridging two suspended microthermometers. By measurement of the temperature rise of the two thermometers, the optical absorption of 7.4-10.3 nm diameter bundles is found to be between 0.03 and 0.44% of the incident photons in the 0.4 microm diameter laser spot. The thermal conductance of the bundle is obtained with the additional measurement of the temperature rise of the nanotubes in the laser spot from shifts in the Raman G band frequency. According to the nanotube bundle diameter determined by transmission electron microscopy, the thermal conductivity is obtained.

  2. Measurements of the effective thermal neutron absorption cross-section in multi-grain models

    International Nuclear Information System (INIS)

    Drozdowicz, K.; Gabanska, B.; Igielski, A.; Krynicka, E.; Schneider, K.; Woznicka, U.

    2005-01-01

    The effective macroscopic absorption cross-section Σ a eff of thermal neutrons in a grained medium differs from the corresponding cross-section Σ a hom in the homogeneous medium consisting of the same components, contributing in the same amounts. The ratio of these cross-sections defines the grain parameter, G, which is a measure of heterogeneity of the system for neutron absorption. Heterogeneous models have been built as two- or three-component systems (Ag, Cu and Co 3 O 4 grains distributed in a regular grid in Plexiglas, in various proportions between them). The effective absorption cross-section has been measured and the experimental grain parameter has been found for each model. The obtained values are in the interval 0.34 < G < 0.58, while G = 1 means the homogeneous material. (author)

  3. Study of Physical Properties of SiCw/Al Composites During Unloaded Thermal Cycling

    Institute of Scientific and Technical Information of China (English)

    ZHAO Xin-ming; TIAN zhi-gang; CHENG hua; ZHU Xiao-gang; CHEN Wen-li

    2004-01-01

    The thermal expansion coefficient of SiCw/Al composites squeeze cast during unloaded thermal cycling was determined and analyzed. The study had shown that the thermal expansion coefficient of SiCw/Al composites reduced greatly with temperature raising. The thermal expansion coefficient of artificial ageing treatment SiCw/Al composites during unloaded thermal cycling reduced gradually, while the thermal expansion coefficient of squeezing SiCw/Al composites increased gradually. In addition, the thermal expansion coefficient of SiCw/Al composites reduced drastically with fiber fraction increasing.

  4. Crack propagation under thermal cycling loading inducing a thermal gradient in the specimen thickness

    International Nuclear Information System (INIS)

    Le, H.N.

    2009-05-01

    This study aims to figure out the crack growth phenomenon by thermal fatigue induced by thermal gradient through thickness of specimen. Firstly, an experimental facility has been developed: a rectangular parallelepiped specimen is subjected to thermal cycling between 350 C and 100 C; the specimen is freed to expand and contract. Two semi-circular notches (0,1 mm depth and 4 mm length) have been machined on the surface of the specimen. A series of interrupted tests has been carried out to characterize and quantify the crack growth in depth and surface of the pre-existing crack. Next, a three-dimensional crack growth simulation has been implemented in ABAQUS. Automation using Python was used to simulate the propagation of a crack under thermal cycling, with re-meshing at crack front after each calculation step. No assumption has been taken on the crack front during the crack propagation. A comparison with test results showed very good agreement on the evolution of crack front shape and on the kinetics of propagation on the edge and the heart of pre-existing crack. An analytical approach was also developed based on the calculation of stress intensity factors (SIC). A two-dimensional approach was first introduced enabling us to better understand the influence of various thermal and geometric parameters. Finally, a three dimensional approach, with an elliptical assumption crack shape during the propagation, leading to a prediction of crack growth on the surface and in depth which is very similar to that obtained numerically, but with computational time much lower. (author)

  5. Dimetrodon: Processor-level Preventive Thermal Management via Idle Cycle Injection

    OpenAIRE

    Reddi, Vijay Janapa; Gandhi, Sanjay; Brooks, David M.; Seltzer, Margo I.; Bailis, Peter

    2011-01-01

    Processor-level dynamic thermal management techniques have long targeted worst-case thermal margins. We examine the thermal-performance trade-offs in average-case, preventive thermal management by actively degrading application performance to achieve long-term thermal control. We propose Dimetrodon, the use of idle cycle injection, a flexible, per-thread technique, as a preventive thermal management mechanism and demonstrate its efficiency compared to hardware techniques in a commodity operatin...

  6. Experimental modeling of weld thermal cycle of the heat affected zone (HAZ

    Directory of Open Access Journals (Sweden)

    J. Kulhánek

    2016-10-01

    Full Text Available Contribution deals with experimental modeling of quick thermal cycles of metal specimens. In the introduction of contribution will be presented measured graphs of thermal cycle of heat affected zone (HAZ of weld. Next will be presented experimental simulation of measured thermal cycle on the standard specimens, useable for material testing. This approach makes possible to create material structures of heat affected zone of weld, big enough for standard material testing.

  7. Modeling the thermal absorption factor of photovoltaic/thermal combi-panels

    NARCIS (Netherlands)

    Santbergen, R.; Zolingen, van R.J.C.

    2006-01-01

    In a photovoltaic/thermal combi-panel solar cells generate electricity while residual heat is extracted to be used for tap water heating or room heating. In such a panel the entire solar spectrum can be used in principle. Unfortunately long wavelength solar irradiance is poorly absorbed by the

  8. Thermal stability, swelling behavior and CO 2 absorption properties of Nanoscale Ionic Materials (NIMs)

    KAUST Repository

    Andrew Lin, Kun-Yi; Park, Youngjune; Petit, Camille; Park, Ah-Hyung Alissa

    2014-01-01

    © The Royal Society of Chemistry 2015. Nanoscale Ionic Materials (NIMs) consist of a nanoscale core, a corona of charged brushes tethered on the surface of the core, and a canopy of the oppositely charged species linked to the corona. Unlike conventional polymeric nanocomposites, NIMs can display liquid-like behavior in the absence of solvents, have a negligible vapor pressure and exhibit unique solvation properties. These features enable NIMs to be a promising CO2 capture material. To optimize NIMs for CO2 capture, their structure-property relationships were examined by investigating the roles of the canopy and the core in their thermal stability, and thermally- and CO2-induced swelling behaviors. NIMs with different canopy sizes and core fractions were synthesized and their thermal stability as well as thermally- and CO2-induced swelling behaviors were determined using thermogravimetry, and ATR FT-IR and Raman spectroscopies. It was found that the ionic bonds between the canopy and the corona, as well as covalent bonds between the corona and the core significantly improved the thermal stability compared to pure polymer and polymer/nanofiller mixtures. A smaller canopy size and a larger core fraction led to a greater enhancement in thermal stability. This thermal stability enhancement was responsible for the long-term thermal stability of NIMs over 100 temperature swing cycles. Owing to their ordered structure, NIMs swelled less when heated or when they adsorbed CO2 compared to their corresponding polymers. This journal is

  9. Thermal stability, swelling behavior and CO 2 absorption properties of Nanoscale Ionic Materials (NIMs)

    KAUST Repository

    Andrew Lin, Kun-Yi

    2014-11-11

    © The Royal Society of Chemistry 2015. Nanoscale Ionic Materials (NIMs) consist of a nanoscale core, a corona of charged brushes tethered on the surface of the core, and a canopy of the oppositely charged species linked to the corona. Unlike conventional polymeric nanocomposites, NIMs can display liquid-like behavior in the absence of solvents, have a negligible vapor pressure and exhibit unique solvation properties. These features enable NIMs to be a promising CO2 capture material. To optimize NIMs for CO2 capture, their structure-property relationships were examined by investigating the roles of the canopy and the core in their thermal stability, and thermally- and CO2-induced swelling behaviors. NIMs with different canopy sizes and core fractions were synthesized and their thermal stability as well as thermally- and CO2-induced swelling behaviors were determined using thermogravimetry, and ATR FT-IR and Raman spectroscopies. It was found that the ionic bonds between the canopy and the corona, as well as covalent bonds between the corona and the core significantly improved the thermal stability compared to pure polymer and polymer/nanofiller mixtures. A smaller canopy size and a larger core fraction led to a greater enhancement in thermal stability. This thermal stability enhancement was responsible for the long-term thermal stability of NIMs over 100 temperature swing cycles. Owing to their ordered structure, NIMs swelled less when heated or when they adsorbed CO2 compared to their corresponding polymers. This journal is

  10. Study of thermal treatments and irradiation on natural amethyst by optical absorption

    International Nuclear Information System (INIS)

    Dotto, C.T.

    1987-01-01

    Thermal treatment effects on the samples of amethyst from Minas Gerais and Rio Grande do Sul, through optical absorption measurements, are studied. The effects of cobalt 60 gama ray radiation on the amethyst from Minas Gerais through optical absorption measurements, are studied. The optical absorption spectra shows a basic line and bands in 10,500 cm -1 (k), in 18,300 cm -1 (θ) and in 28,000 cm -1 (ζ). The correlation between thermal treatment effects and radiation effects shows that the θ and ζ bands belongs to a same center and the k band to another center. The basic line vanishes by thermal treatments at 270 0 C. The analyses of the isothermal treatment decay and dose-curve reveal a complex kinetics, suggesting that the kinetic mechanisms involve the electron (s) and hole (s) migration in the lattice. The amethyst from Minas Gerais after being discolored at 470 0 C and irradiated again shows that the optical absorption bands don't recover the original absorbance, suggesting the existence of iron diffusion mechanisms in the lattice. After being isothermally annealed the amethyst from Rio Grande do Sul above 400 0 C temperature yield a yellow-brown color, probably due to the formation of Fe 2 O 3 precipitate. We suggest the this formation is due to iron diffusion and pre-existent oxygen vacancies. This model is reinforced through the observation the amethyst from Minas Gerais, isothermally treated at 470 0 C in highly reducing, also gets a yellow-brown color. (author) [pt

  11. Evaluation of ionic liquids as absorbents for ammonia absorption refrigeration cycles using COSMO-based process simulations

    Energy Technology Data Exchange (ETDEWEB)

    Ruiz, E.; Ferro, V.R., E-mail: victor.ferro@uam.es; Riva, J. de; Moreno, D.; Palomar, J.

    2014-06-01

    Highlights: • NH{sub 3}–IL absorption cycles are modeled by COSMO-based Aspen simulations. • Proposed a priori computational approach is validated using experimental data. • Cycle performance was analyzed for conventional and task-specific ILs. • IL solvents with high NH{sub 3} absorption capacity improve the cycle performance. • Using IL mixtures is revealed as promising alternative in NH{sub 3} absorption applications. - Abstract: COSMO-based process simulations with Aspen Plus/Aspen HYSYS are used, for the first time, to a priori estimate the thermodynamic performance of ammonia absorption refrigeration cycles using ionic liquids as absorbents. This allows not only broadening the criteria set used to select/design ionic liquids with optimized properties to be used in that role, but also evaluating innovative strategies to improve the cycle’s performances. COSMO-RS method provides the information required for both creating the ionic liquid non-database components and specifying the COSMOSAC property model to perform Aspen Plus calculations. The computational procedure used here gives at the same time reasonable good property predictions of the vapor (refrigerant) and the condensed (ammonia + ionic liquid) phases as well as physically consistent estimations of the cycle’s performance under different conditions. Current results agree with those previously reported in the literature for several ionic liquid-based systems taken for comparison. In addition, task-specific ionic liquids, with improved properties for ammonia absorption, and also binary ionic liquid mixtures are considered in the analysis. It is obtained that ionic liquids showing higher ammonia absorption capacity among the considered absorbents simultaneously provide the best cycle’s performances. The cycle performances vary in relatively wide intervals depending on the ammonia concentration in the (refrigerant + absorbent) solutions. This behavior is strongly modulated by the ammonia

  12. Evaluation of ionic liquids as absorbents for ammonia absorption refrigeration cycles using COSMO-based process simulations

    International Nuclear Information System (INIS)

    Ruiz, E.; Ferro, V.R.; Riva, J. de; Moreno, D.; Palomar, J.

    2014-01-01

    Highlights: • NH 3 –IL absorption cycles are modeled by COSMO-based Aspen simulations. • Proposed a priori computational approach is validated using experimental data. • Cycle performance was analyzed for conventional and task-specific ILs. • IL solvents with high NH 3 absorption capacity improve the cycle performance. • Using IL mixtures is revealed as promising alternative in NH 3 absorption applications. - Abstract: COSMO-based process simulations with Aspen Plus/Aspen HYSYS are used, for the first time, to a priori estimate the thermodynamic performance of ammonia absorption refrigeration cycles using ionic liquids as absorbents. This allows not only broadening the criteria set used to select/design ionic liquids with optimized properties to be used in that role, but also evaluating innovative strategies to improve the cycle’s performances. COSMO-RS method provides the information required for both creating the ionic liquid non-database components and specifying the COSMOSAC property model to perform Aspen Plus calculations. The computational procedure used here gives at the same time reasonable good property predictions of the vapor (refrigerant) and the condensed (ammonia + ionic liquid) phases as well as physically consistent estimations of the cycle’s performance under different conditions. Current results agree with those previously reported in the literature for several ionic liquid-based systems taken for comparison. In addition, task-specific ionic liquids, with improved properties for ammonia absorption, and also binary ionic liquid mixtures are considered in the analysis. It is obtained that ionic liquids showing higher ammonia absorption capacity among the considered absorbents simultaneously provide the best cycle’s performances. The cycle performances vary in relatively wide intervals depending on the ammonia concentration in the (refrigerant + absorbent) solutions. This behavior is strongly modulated by the ammonia absorption

  13. Measurement of the thorium absorption cross section shape near thermal energy (LWBR development program)

    International Nuclear Information System (INIS)

    Green, L.

    1976-11-01

    The shape of the thorium absorption cross section near thermal energies was investigated. This shape is dominated by one or more negative energy resonances whose parameters are not directly known, but must be inferred from higher energy data. Since the integral quantity most conveniently describing the thermal cross section shape is the Westcottg-factor, effort was directed toward establishing this quantity to high precision. Three nearly independent g-factor estimates were obtained from measurements on a variety of foils in three different neutron spectra provided by polyethylene-moderated neutrons from a 252 Cf source and from irradiations in the National Bureau of Standards ''Standard Thermal Neutron Density.'' The weighted average of the three measurements was 0.993 +- 0.004. This is in good agreement with two recent evaluations and supports the adequacy of the current cross section descriptions

  14. Coefficient of Performance Optimization of Single-Effect Lithium-Bromide Absorption Cycle Heat Pumps

    DEFF Research Database (Denmark)

    Vinther, Kasper; Just Nielsen, Rene; Nielsen, Kirsten Mølgaard

    2015-01-01

    In this paper, we investigate the coefficient of performance (COP) of a LiBr absorption cycle heat pump under different operating conditions. The investigation is carried out using a dynamical model fitted against data recorded from an actual heat pump used for district heating in S......⊘nderborg, Denmark. Since the model is too complex to study analytically, we vary different input variables within the permissible operating range of the heat pump and evaluate COP at the resulting steady-state operating points. It is found that the best set-point for each individual input is located at an extreme......-state operation of the heat pump, while avoiding crystallization issues....

  15. Thermal characteristics of combined thermoelectric generator and refrigeration cycle

    International Nuclear Information System (INIS)

    Yilbas, Bekir S.; Sahin, Ahmet Z.

    2014-01-01

    Highlights: • TEM location in between the evaporator and condenser results in low coefficient of performance. • TEM location in between condenser and its ambient improves coefficient of performance of the combined system. • High temperature ratio enhances coefficient of performance of combined system. • Certain values of parameters enhance combined system performance. - Abstract: A combined thermal system consisting of a thermoelectric generator and a refrigerator is considered and the effect of location of the thermoelectric generator, in the refrigeration cycle, on the performance characteristics of the combined system is investigated. The operating conditions and their influence on coefficient of performance of the combined system are examined through introducing the dimensionless parameters, such as λ(λ = Q HTE /Q H , where Q HTE is heat transfer to the thermoelectric generator from the condenser, Q H is the total heat transfer from the condenser to its ambient), temperature ratio (θ L = T L /T H , where T L is the evaporator temperature and T H is the condenser temperature), r C (r C = C L /C H , where C L is the thermal capacitance due to heat transfer to evaporator and C H , is the thermal capacitance due to heat rejected from the condenser), θ W (θ W = T W /T H , where T W is the ambient temperature), θ C (θ C = T C /T H , where T C is the cold space temperature). It is found that the location of the thermoelectric generator in between the condenser and the evaporator decreases coefficient of performance of the combined system. Alternatively, the location of thermoelectric device in between the condenser and its ambient enhances coefficient of performance of the combined system. The operating parameters has significant effect on the performance characteristics of the combined system; in which case temperature ratio (θ L ) within the range of 0.68–0.70, r C = 2.5, θ W = 0.85, and θ C = 0.8 improve coefficient of performance of the

  16. Determination of absorption coefficient based on laser beam thermal blooming in gas-filled tube.

    Science.gov (United States)

    Hafizi, B; Peñano, J; Fischer, R; DiComo, G; Ting, A

    2014-08-01

    Thermal blooming of a laser beam propagating in a gas-filled tube is investigated both analytically and experimentally. A self-consistent formulation taking into account heating of the gas and the resultant laser beam spreading (including diffraction) is presented. The heat equation is used to determine the temperature variation while the paraxial wave equation is solved in the eikonal approximation to determine the temporal and spatial variation of the Gaussian laser spot radius, Gouy phase (longitudinal phase delay), and wavefront curvature. The analysis is benchmarked against a thermal blooming experiment in the literature using a CO₂ laser beam propagating in a tube filled with air and propane. New experimental results are presented in which a CW fiber laser (1 μm) propagates in a tube filled with nitrogen and water vapor. By matching laboratory and theoretical results, the absorption coefficient of water vapor is found to agree with calculations using MODTRAN (the MODerate-resolution atmospheric TRANsmission molecular absorption database) and HITRAN (the HIgh-resolution atmospheric TRANsmission molecular absorption database).

  17. Geosynthetic clay liners shrinkage under simulated daily thermal cycles.

    Science.gov (United States)

    Sarabadani, Hamid; Rayhani, Mohammad T

    2014-06-01

    Geosynthetic clay liners are used as part of composite liner systems in municipal solid waste landfills and other applications to restrict the escape of contaminants into the surrounding environment. This is attainable provided that the geosynthetic clay liner panels continuously cover the subsoil. Previous case histories, however, have shown that some geosynthetic clay liner panels are prone to significant shrinkage and separation when an overlying geomembrane is exposed to solar radiation. Experimental models were initiated to evaluate the potential shrinkage of different geosynthetic clay liner products placed over sand and clay subsoils, subjected to simulated daily thermal cycles (60°C for 8 hours and 22°C for 16 hours) modelling field conditions in which the liner is exposed to solar radiation. The variation of geosynthetic clay liner shrinkage was evaluated at specified times by a photogrammetry technique. The manufacturing techniques, the initial moisture content, and the aspect ratio (ratio of length to width) of the geosynthetic clay liner were found to considerably affect the shrinkage of geosynthetic clay liners. The particle size distribution of the subsoil and the associated suction at the geosynthetic clay liner-subsoil interface was also found to have significant effects on the shrinkage of the geosynthetic clay liner. © The Author(s) 2014.

  18. How Thermal Fatigue Cycles Change the Rheological Behavior of Polymer Modified Bitumen?

    NARCIS (Netherlands)

    Glaoui, B.; Merbouh, M.; Van de Ven, M.F.C.; Chailleux, E.; Youcefi, A.

    2013-01-01

    The paper deals with the problem of thermal fatigue cycles phenomenon, which affects the performance of flexible pavement. The purpose of the paper is to extent the knowledge on the rheology of polymer modified bitumen which was affected by cycles of thermal fatigue. The aim of this research is to

  19. Weldability prediction of high strength steel S960QL after weld thermal cycle simulation

    Directory of Open Access Journals (Sweden)

    M. Dunđer

    2014-10-01

    Full Text Available This paper presents weld thermal cycle simulation of high strength steel S960QL, and describes influence of cooling time t8/5 on hardness and impact toughness of weld thermal cycle simulated specimens. Furthermore, it presents analysis of characteristic fractions done by electron scanning microscope which can contribute to determination of welding parameters for S960QL steel.

  20. Theoretical thermodynamic analysis of Rankine power cycle with thermal driven pump

    International Nuclear Information System (INIS)

    Lakew, Amlaku Abie; Bolland, Olav; Ladam, Yves

    2011-01-01

    Highlights: → The work is focused on theoretical aspects of thermal driven pump (TDP) Rankine cycle. → The mechanical pump is replaced by thermal driven pump. → Important parameters of thermal driven pump Rankine cycle are investigated. → TDP Rankine cycle produce more power but it requires additional low grade heat. - Abstract: A new approach to improve the performance of supercritical carbon dioxide Rankine cycle which uses low temperature heat source is presented. The mechanical pump in conventional supercritical carbon dioxide Rankine cycle is replaced by thermal driven pump. The concept of thermal driven pump is to increase the pressure of a fluid in a closed container by supplying heat. A low grade heat source is used to increase the pressure of the fluid instead of a mechanical pump, this increase the net power output and avoid the need for mechanical pump which requires regular maintenance and operational cost. The thermal driven pump considered is a shell and tube heat exchanger where the working fluid is contained in the tube, a tube diameter of 5 mm is chosen to reduce the heating time. The net power output of the Rankine cycle with thermal driven pump is compared to that of Rankine cycle with mechanical pump and it is observed that the net power output is higher when low grade thermal energy is used to pressurize the working fluid. The thermal driven pump consumes additional heat at low temperature (60 o C) to pressurize the working fluid.

  1. Thermodynamic analysis of a combined gas turbine, ORC cycle and absorption refrigeration for a CCHP system

    International Nuclear Information System (INIS)

    Mohammadi, Amin; Kasaeian, Alibakhsh; Pourfayaz, Fathollah; Ahmadi, Mohammad Hossein

    2017-01-01

    Highlights: • Thermodynamic analysis of a hybrid CCHP system. • Sensitivity analysis is performed on the most important parameters of the system. • Pressure ratio and gas turbine inlet temperature are the most effective parameters. - Abstract: Hybrid power systems are gained more attention due to their better performance and higher efficiency. Widespread use of these systems improves environmental situation as they reduce the amount of fossil fuel consumption. In this paper a hybrid system composed of a gas turbine, an ORC cycle and an absorption refrigeration cycle is proposed as a combined cooling, heating and power system for residential usage. Thermodynamic analysis is applied on the system. Also a parametric analysis is carried out to investigate the effect of different parameters on the system performance and output cooling, heating and power. The results show that under design conditions, the proposed plant can produce 30 kW power, 8 kW cooling and almost 7.2 ton hot water with an efficiency of 67.6%. Moreover, parametric analysis shows that pressure ratio and gas turbine inlet temperature are the most important and influential parameters. After these two, ORC turbine inlet temperature is the most effective parameter as it can change both net output power and energy efficiency of the system.

  2. Thermal neutron absorption cross-section for small samples (experiments in cylindrical geometry)

    International Nuclear Information System (INIS)

    Czubek, J.A.; Drozdowicz, K.; Igielski, A.; Krynicka-Drozdowicz, E.; Woznicka, U.

    1982-01-01

    Measurement results for thermal neutron macroscopic absorption cross-sections Σsub(a)1 when applying the cylindrical sample-moderator system are presented. Experiments for liquid (water solutions of H 3 BO 3 ) and solid (crushed basalts) samples are reported. Solid samples have been saturated with the H 3 BO 3 ''poisoning'' solution. The accuracy obtained for the determination of the absorption cross-section of the solid material was σ(Σsub(ma))=(1.2+2.2) c.u. in the case when porosity was measured with the accuracy of σ(phi)=0.001+0.002. The dispersion of the Σsub(ma) data obtained for basalts (taken from different quarries) was higher than the accuracy of the measurement. All experimental data for the fundamental decay constants lambda 0 together with the whole information about the samples are given. (author)

  3. Effect of nanoclay on thermal, mechanical and liquid absorption properties of epoxy-clay nanocomposite

    International Nuclear Information System (INIS)

    Nguyen Cong Quyen; Nguyen Pham Duy Linh; Bui Chuong; Doan Thi Yen Oanh

    2015-01-01

    Composite materials based on epoxy DER 331 hot cured by MHHPA with several contents of nanoclay I28E were prepared and characterized by TEM and SEM. Results showed that the nanostructures were created in two levels: intercalated structure and nanoparticles (cluster). The interaction between nanoclay and epoxy matrix was evaluated by properties such as: liquid absorption, TGA and DMA. It was shown that nanostructures of cluster, as well as the hydrophobic behavior of material with the presence of nanoclay have dominant effect to liquid absorption. Otherwise, the thermal stability was affected mainly by intercalation structure. Results of DMA showed that the interaction of epoxy-clay was strongly destroyed at the temperature higher than material Tg. (author)

  4. Determination of cadmium in zinc ores by thermal neutron absorption analysis

    International Nuclear Information System (INIS)

    De Norre, L.; Op de Beeck, J.; Hoste, J.

    1983-01-01

    A method has been developed for routine determination of cadmium in zinc ores by thermal neutron absorption analysis, based on the attenuation of a thermal neutron flux passing through a neutron absorbing material. The thermal neutron flux in related to the 52 V activity induced in a vanadium detector, surrounded by pellets pressed from a mixture of powdered material with graphite. Besides cadmium, also the major constituents zinc, iron and sulfur contribute significantly to the total attenuation of the thermal neutron flux. Calibration lines for these elements are worked out. All irradiations are carried out for 200 s in the partially thermalized neutron flux of a 5 Ci 227 Ac-Be isotope neutron source. After a decay of 30 s, the 52 V activity of the vanadium detector is measured for 400 s with a NaI(Tl) scintillation detector. The analysis sequence, including the computation of the results from the counting data, is automated by means of a LSI-11 Microprocessor with 12Kx16 bit memory. Zinc ores, containing 0.02 to 1.45% cadmium, have been analyzed with a precision ranging from 12.6% to 0.54%, resp. As a test for the reliability of the method, two NBS standard reference materials were analyzed in the same way as the zinc ore samples. (author)

  5. Ammonia-lithium nitrate absorption chiller with an integrated low-pressure compression booster cycle for low driving temperatures

    International Nuclear Information System (INIS)

    Ventas, R.; Lecuona, A.; Zacarias, A.; Venegas, M.

    2010-01-01

    Single-effect absorption refrigeration hybridized with mechanical vapor compression in a vapor circuit is known as the absorption cycle with an integrated booster compressor. In this study, the compressor is located between the evaporator and the absorber. This paper presents a numerical model of this cycle with ammonia-lithium nitrate solution as the working pair. It is based on UA-ΔT lm models for separate regions of plate-type heat exchangers. The results are offered as a function of external circuit flow parameters. Different pressure ratios of the compressor were tested for a wide range of hot water driving temperatures (55-95 deg. C), showing that low values are more beneficial. This cycle allows for working at lower driving temperatures than the single-effect cycle, with low electricity consumption. At the same driving temperature, the capacity is augmented with an increased compressor pressure ratio, thus allowing for demand matching of the cooling. This cycle, operating with hot water at 67 deg. C with a pressure ratio of 2.0, has the capacity of a single-effect absorption cycle at 94 deg. C. The electrical COP was found to be higher than that in an ammonia vapor compression cycle for comprehensive working conditions.

  6. [Effect of thermal cycling on surface microstructure of different light-curing composite resins].

    Science.gov (United States)

    Lv, Da; Liu, Kai-Lei; Yao, Yao; Zhang, Wei-Sheng; Liao, Chu-Hong; Jiang, Hong

    2015-04-01

    To evaluate the effect of thermal cycling on surface microstructure of different light-curing composite resins. A nanofilled composite (Z350) and 4 microhybrid composites (P60, Z250, Spectrum, and AP-X) were fabricated from lateral to center to form cubic specimens. The lateral surfaces were abrased and polished before water storage and 40 000 thermal cycles (5/55 degrees celsius;). The mean surface roughness (Ra) were measured and compared before and after thermal cycling, and the changes of microstructure were observed under scanning electron microscope (SEM). Significant decreases of Ra were observed in the composites, especially in Spectrum (from 0.164±0.024 µm to 0.140±0.017 µm, Presins, and fissures occurred on Z350 following the thermal cycling. Water storage and thermal cycling may produce polishing effect on composite resins and cause fissures on nanofilled composite resins.

  7. Transient thermal effect, nonlinear refraction and nonlinear absorption properties of graphene oxide sheets in dispersion.

    Science.gov (United States)

    Zhang, Xiao-Liang; Liu, Zhi-Bo; Li, Xiao-Chun; Ma, Qiang; Chen, Xu-Dong; Tian, Jian-Guo; Xu, Yan-Fei; Chen, Yong-Sheng

    2013-03-25

    The nonlinear refraction (NLR) properties of graphene oxide (GO) in N, N-Dimethylformamide (DMF) was studied in nanosecond, picosecond and femtosecond time regimes by Z-scan technique. Results show that the dispersion of GO in DMF exhibits negative NLR properties in nanosecond time regime, which is mainly attributed to transient thermal effect in the dispersion. The dispersion also exhibits negative NLR in picosecond and femtosecond time regimes, which are arising from sp(2)- hybridized carbon domains and sp(3)- hybridized matrix in GO sheets. To illustrate the relations between NLR and nonlinear absorption (NLA), NLA properties of the dispersion were also studied in nanosecond, picosecond and femtosecond time regimes.

  8. Effects of water-absorption and thermal drift on a polymeric photonic crystal slab sensor

    DEFF Research Database (Denmark)

    Sørensen, Kristian Tølbøl; Ingvorsen, Charlotte Bonde; Nielsen, Line Hagner

    2018-01-01

    of resonant reflection during absorption, by monitoring the release of water using ellipsometry, and by rigorous coupled-wave analysis (RCWA). The approach presented here enables monitoring of water uptake and thermal fluctuations, for drift-free, high-performance operation of a polymeric PCS sensor....... with additional challenges, besides those relating to temperature-variations, which must be considered in any refractive index based method: The polymeric waveguide core was found to swell by ?0.3% as water absorbed into the waveguide core over ?1.5 h. This was investigated by monitoring the wavelength...

  9. Moisture absorption characteristics of the Orbiter thermal protection system and methods used to prevent water ingestion

    Science.gov (United States)

    Schomburg, C.; Dotts, R. L.; Tillian, D. J.

    1983-01-01

    The Space Shuttle Orbiter's silica tile Thermal Protection System (TPS) is beset by the moisture absorption problems inherently associated with low density, highly porous insulation systems. Attention is presently given to the comparative success of methods for the minimization and/or prevention of water ingestion by the TPS tiles, covering the development of water-repellent agents and their tile application techniques, flight test program results, and materials improvements. The use of external films for rewaterproofing of the TPS tiles after each mission have demonstrated marginal to unacceptable performance. By contrast, a tile interior waterproofing agent has shown promise.

  10. Pressure Measurement in Supersonic Air Flow by Differential Absorptive Laser-Induced Thermal Acoustics

    Science.gov (United States)

    Hart, Roger C.; Herring, Gregory C.; Balla, Robert J.

    2007-01-01

    Nonintrusive, off-body flow barometry in Mach-2 airflow has been demonstrated in a large-scale supersonic wind tunnel using seedless laser-induced thermal acoustics (LITA). The static pressure of the gas flow is determined with a novel differential absorption measurement of the ultrasonic sound produced by the LITA pump process. Simultaneously, stream-wise velocity and static gas temperature of the same spatially-resolved sample volume were measured with this nonresonant time-averaged LITA technique. Mach number, temperature and pressure have 0.2%, 0.4%, and 4% rms agreement, respectively, in comparison with known free-stream conditions.

  11. Research of waste heat energy efficiency for absorption heat pump recycling thermal power plant circulating water

    Science.gov (United States)

    Zhang, Li; Zhang, Yu; Zhou, Liansheng; E, Zhijun; Wang, Kun; Wang, Ziyue; Li, Guohao; Qu, Bin

    2018-02-01

    The waste heat energy efficiency for absorption heat pump recycling thermal power plant circulating water has been analyzed. After the operation of heat pump, the influences on power generation and heat generation of unit were taken into account. In the light of the characteristics of heat pump in different operation stages, the energy efficiency of heat pump was evaluated comprehensively on both sides of benefits belonging to electricity and benefits belonging to heat, which adopted the method of contrast test. Thus, the reference of energy efficiency for same type projects was provided.

  12. Mercury speciation in environmental solid samples using thermal release technique with atomic absorption detection

    Energy Technology Data Exchange (ETDEWEB)

    Shuvaeva, Olga V. [Institute of Inorganic Chemistry, Academician Lavrent' ev Prospect 3, 630090 Novosbirsk (Russian Federation)], E-mail: olga@che.nsk.su; Gustaytis, Maria A.; Anoshin, Gennadii N. [Institute of Geology and Mineralogy, Siberian Branch of Russian Academy of Sciences, Koptyug Prospect 3, 630090 Novosibirsk (Russian Federation)

    2008-07-28

    A sensitive and very simple method for determination of mercury species in solid samples has been developed involving thermal release analysis in combination with atomic absorption (AAS) detection. The method allows determination of mercury(II) chloride, methylmercury and mercury sulfide at the level of 0.70, 0.35 and 0.20 ng with a reproducibility of the results of 14, 25 and 18%, respectively. The accuracy of the developed assay has been estimated using certified reference materials and by comparison of the results with those of an independent method. The method has been applied for Hg species determination in original samples of lake sediments and plankton.

  13. Flexible thermal cycle test equipment for concentrator solar cells

    Science.gov (United States)

    Hebert, Peter H [Glendale, CA; Brandt, Randolph J [Palmdale, CA

    2012-06-19

    A system and method for performing thermal stress testing of photovoltaic solar cells is presented. The system and method allows rapid testing of photovoltaic solar cells under controllable thermal conditions. The system and method presents a means of rapidly applying thermal stresses to one or more photovoltaic solar cells in a consistent and repeatable manner.

  14. Experimental study of a thermochemical compressor for an absorption/compression hybrid cycle

    International Nuclear Information System (INIS)

    Ventas, R.; Vereda, C.; Lecuona, A.; Venegas, M.

    2012-01-01

    Highlights: ► Experimental study of a thermochemical compressor for absorption/compression cycle. ► Spray adiabatic absorber using NH 3 –LiNO 3 solution working fluid. ► It is able to operate between 57 and 110 °C varying concentration between 0.46 and 0.59. ► The increase of absorber pressure decreases the circulation ratio. ► The numerical model performed agrees with the experimental results. -- Abstract: An experimental study of a thermochemical compressor with ammonia–lithium nitrate solution as working fluid has been carried out. This compressor incorporates a single-pass adiabatic absorber and all the heat exchangers are of the plate type: absorber subcooler, generator and solution heat exchanger. The thermochemical compressor has been studied as part of a single-effect absorption chiller hybridized with an in-series low-pressure compression booster. The adiabatic absorber uses fog jet injectors. The generator hot water temperatures for the external driving flow are in the range of 57–110 °C and the absorber pressures range between 429 and 945 kPa. Experimental results are compared with a numerical model showing a high agreement. The performance of the thermochemical compressor, evaluated through the circulation ratio, improves for higher absorber pressures, indicating the potential of pressure boosting. For the same circulation ratio, the driving hot water inlet temperature decreases with the rise of the absorber pressure. The thermochemical compressor, based on an adiabatic absorber, can produce refrigerant with very low driving temperatures, between 57 and 70 °C, what is interesting for solar cooling applications and very low temperature residual heat recovery. Efficiencies and cooling power are offered when this hybrid thermochemical compressor is implemented in a chiller, showing the effect of different operating parameters.

  15. Experimental investigation on charging and discharging performance of absorption thermal energy storage system

    International Nuclear Information System (INIS)

    Zhang, Xiaoling; Li, Minzhi; Shi, Wenxing; Wang, Baolong; Li, Xianting

    2014-01-01

    Highlights: • A prototype of ATES using LiBr/H 2 O was designed and built. • Charging and discharging performances of ATES system were investigated. • ESE and ESD for cooling, domestic hot water and heating were obtained. - Abstract: Because of high thermal storage density and little heat loss, absorption thermal energy storage (ATES) is known as a potential thermal energy storage (TES) technology. To investigate the performance of the ATES system with LiBr–H 2 O, a prototype with 10 kW h cooling storage capacity was designed and built. The experiments demonstrated that charging and discharging processes are successful in producing 7 °C chilled water, 65 °C domestic hot water, or 43 °C heating water to meet the user’s requirements. Characteristics such as temperature, concentration and power variation of the ATES system during charging and discharging processes were investigated. The performance of the ATES system for supplying cooling, heating or domestic hot water was analyzed and compared. The results indicate that the energy storage efficiencies (ESE) for cooling, domestic hot water and heating are 0.51, 0.97, 1.03, respectively, and the energy storage densities (ESD) for cooling, domestic hot water and heating reach 42, 88, 110 kW h/m 3 , respectively. The performance is better than those of previous TES systems, which proves that the ATES system using LiBr–H 2 O may be a good option for thermal energy storage

  16. Performance of one and a half-effect absorption cooling cycle of H2O/LiBr system

    International Nuclear Information System (INIS)

    Wang Jianzhao; Zheng Danxing

    2009-01-01

    The performances of half-effect, single-effect and double-effect H 2 O/LiBr absorption cooling cycles were analyzed, and it was found that there is an obvious blank for generation temperature between the maximum generation temperature of the single-effect cycle and the minimum generation temperature of the double-effect cycle. It was proposed that the one and a half-effect (1.5-effect) cycle can fill up the blank perfectly. The state of the art in the 1.5-effect cycles was reviewed and analyzed, and two new configurations of 1.5-effect cycles were proposed. Three configurations of 1.5-effect cycles, which are suitable for H 2 O/LiBr as working fluids, were selected to be analyzed in detail. The 1.5-effect cycle shows the optimum performance at the foregoing blank of generation temperature. For example, under the conditions of evaporation temperature t E is 5 deg. C, and condensation temperature t C is 42 deg. C, and absorption temperature t A is 37 deg. C, the optimum range of generation temperature t G for the 1.5-effect cycle is from 110 deg. C to 140 deg. C. The coefficient of performance of the 1.5-effect cycle is about 1.0, which is more than 30% higher than that of the single-effect cycle at the same condition. The effects of the efficiency of solution heat exchanger, the generation temperature, the absorption temperature (or the condensation temperature) and the evaporation temperature on the performances of the three configurations of 1.5-effect cycle were analyzed. It was shown that the configuration II, which is composed with a high-temperature single-effect subcycle and a low-temperature half-effect subcycle, has the highest coefficient of performance and the best operational flexibility. Among the four parameters analyzed, the performances of 1.5-effect cycles are most sensitive to the change of absorption temperature (or condensation temperature), and then to the change of generation temperature.

  17. Experimental investigation on photothermal properties of nanofluids for direct absorption solar thermal energy systems

    International Nuclear Information System (INIS)

    He, Qinbo; Wang, Shuangfeng; Zeng, Shequan; Zheng, Zhaozhi

    2013-01-01

    Highlights: • The factors affecting the transmittance of Cu–H 2 O nanofluids were studied with UV–Vis–NIR spectrophotometer. • The optical properties of Cu–H 2 O nanofluids were studied through the theoretical model. • The Cu–H 2 O nanofluids can enhance the absorption ability for solar energy. - Abstract: In this article, Cu–H 2 O nanofluids were prepared through two-step method. The transmittance of nanofluids over solar spectrum (250–2500 nm) was measured by the UV–Vis–NIR spectrophotometer based on integrating sphere principle. The factors influencing transmittance of nanofluids, such as particle size, mass fraction and optical path were investigated. The extinction coefficients measured experimentally were compared with the theoretical calculation value. Meanwhile, the photothermal properties of nanofluids were also investigated. The experimental results show that the transmittance of Cu–H 2 O nanofluids is much less than that of deionized water, and decreases with increasing nanoparticle size, mass fraction and optical depth. The highest temperature of Cu–H 2 O nanofluids (0.1 wt.%) can increased up to 25.3% compared with deionized water. The good absorption ability of Cu–H 2 O nanofluids for solar energy indicates that it is suitable for direct absorption solar thermal energy systems

  18. Non-destructive studies of fuel pellets by neutron resonance absorption radiography and thermal neutron radiography

    Energy Technology Data Exchange (ETDEWEB)

    Tremsin, A.S., E-mail: ast@ssl.berkeley.edu [University of California, Berkeley, CA 94720 (United States); Vogel, S.C.; Mocko, M.; Bourke, M.A.M.; Yuan, V.; Nelson, R.O.; Brown, D.W. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Feller, W.B. [NOVA Scientific, Inc., 10 Picker Rd., Sturbridge, MA 01566 (United States)

    2013-09-15

    Many isotopes in nuclear materials exhibit strong peaks in neutron absorption cross sections in the epithermal energy range (1–1000 eV). These peaks (often referred to as resonances) occur at energies specific to particular isotopes, providing a means of isotope identification and concentration measurements. The high penetration of epithermal neutrons through most materials is very useful for studies where samples consist of heavy-Z elements opaque to X-rays and sometimes to thermal neutrons as well. The characterization of nuclear fuel elements in their cladding can benefit from the development of high resolution neutron resonance absorption imaging (NRAI), enabled by recently developed spatially-resolved neutron time-of-flight detectors. In this technique the neutron transmission of the sample is measured as a function of spatial location and of neutron energy. In the region of the spectra that borders the resonance energy for a particular isotope, the reduction in transmission can be used to acquire an image revealing the 2-dimensional distribution of that isotope within the sample. Provided that the energy of each transmitted neutron is measured by the neutron detector used and the irradiated sample possesses neutron absorption resonances, then isotope-specific location maps can be acquired simultaneously for several isotopes. This can be done even in the case where samples are opaque or have very similar transmission for thermal neutrons and X-rays or where only low concentrations of particular isotopes are present (<0.1 atom% in some cases). Ultimately, such radiographs of isotope location can be utilized to measure isotope concentration, and can even be combined to produce three-dimensional distributions using tomographic methods. In this paper we present the proof-of-principle of NRAI and transmission Bragg edge imaging performed at Flight Path 5 (FP5) at the LANSCE pulsed, moderated neutron source of Los Alamos National Laboratory. A set of urania mockup

  19. Thermal cycle efficiency of the indirect combined HTGR-GT power generation system

    Energy Technology Data Exchange (ETDEWEB)

    Muto, Yasushi [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    1996-02-01

    High thermal efficiency of 50% could be expected in a power generation system coupling a high temperature gas-cooled reactor(HTGR) with a closed cycle gas turbine(GT). There are three candidate systems such as a direct cycle(DC), an indirect cycle(ICD) and an indirect combined cycle(IDCC). The IDCC could solve many problems in both the DC and the IDC and consists of a primary circuit and a secondary circuit where a topping cycle is a Brayton cycle and a bottoming cycle is a steam cycle. In this report, the thermal cycle efficiency of the IDCC is examined regarding configurations of components and steam pressure. It has been shown that there are two types of configurations, that is, a perfect cascade type and a semi-cascade one and the latter can be further classified into Case A, Case B and Case C. The conditions achieving the maximum thermal cycle efficiency were revealed for these cases. In addition, the optimum system configurations were proposed considering the thermal cycle efficiency, safety and plant arrangement. (author).

  20. Stress hysteresis during thermal cycling of plasma-enhanced chemical vapor deposited silicon oxide films

    Science.gov (United States)

    Thurn, Jeremy; Cook, Robert F.

    2002-02-01

    The mechanical response of plasma-enhanced chemical vapor deposited SiO2 to thermal cycling is examined by substrate curvature measurement and depth-sensing indentation. Film properties of deposition stress and stress hysteresis that accompanied thermal cycling are elucidated, as well as modulus, hardness, and coefficient of thermal expansion. Thermal cycling is shown to result in major plastic deformation of the film and a switch from a compressive to a tensile state of stress; both athermal and thermal components of the net stress alter in different ways during cycling. A mechanism of hydrogen incorporation and release from as-deposited silanol groups is proposed that accounts for the change in film properties and state of stress.

  1. Experimental study on a project with CHP system basing on absorption cycles

    International Nuclear Information System (INIS)

    Sun, Jian; Fu, Lin; Sun, Fangtian; Zhang, Shigang

    2014-01-01

    A new heat recovery system for the CHP (combined heating and power) is presented, and HRU (heat recovery unit) and AHE (absorption heat exchanger) are invented to improve the total energy efficiency of the conventional CHP system by more than 20%, which are installed at the thermal power plant and the heating substation separately. The HRU could recover the low grade heat of exhausted steam from the turbine directly, and the AHE could decrease the temperature of back water of primary pipe to a lower temperature than that of secondary pipe without changing the flow rate of secondary pipe. A large demonstration project employing this technology has been built in Datong of China. And experimental results of HRU and AHE are presented to evaluate this system. - Highlights: • The total energy efficiency of CHP could by increased by more than 20%. • Temperature of back water of primary pipe could be lower than that of secondary pipe. • Heating capacity of primary pipe could be increased significantly. • Low grade heat of exhausted steam from turbine could be recovered directly

  2. Analysis of ammonia/water and ammonia/salt mixture absorption cycles for refrigeration purposes in fishing ships

    International Nuclear Information System (INIS)

    Táboas, Francisco; Bourouis, Mahmoud; Vallès, Manel

    2014-01-01

    In this work, the use of waste heat energy of jacket water in diesel engines of fishing ships was analysed for use as a heat source for absorption refrigeration systems. The thermodynamic simulation of an absorption refrigeration cycle with three different working fluid mixtures that use ammonia as a refrigerant was carried out. This analysis was assessed in terms of the cooling demand and cycle performance as a function of the evaporator, condenser and generator temperatures. Moreover, the need for rectifying the vapour stream leaving the generator was analysed together with the drag of the fraction of non-evaporated liquid to the absorber. The results show that the NH 3 /(LiNO 3  + H 2 O) and NH 3 /LiNO 3 fluid mixtures have higher values of COP as compared to NH 3 /H 2 O fluid mixture, the differences being more pronounced at low generation temperatures. If the activation temperature is set to 85 °C, the minimum evaporation temperatures that can be achieved are −18.8 °C for the cycle with NH 3 /LiNO 3 , −17.5 °C for the cycle with NH 3 /(LiNO 3  + H 2 O) cycle and −13.7 °C for the NH 3 /H 2 O cycle at a condensing temperature of 25 °C. Also, for the NH 3 /(LiNO 3  + H 2 O) fluid mixture, it has been demonstrated that the absorption refrigeration cycle can be operated without a distillation column and in this case the water content in the refrigerant stream entering the evaporator is less than 1.5% in weight at the operating conditions selected. - Highlights: •Ammonia absorption systems can provide refrigeration necessities for fishing ships. •Absorption refrigeration systems reduce the energy consumption of fishing ships. •The NH 3 /(LiNO 3  + H 2 O) mixture is recommended for absorption refrigeration cycles

  3. Quantitative consideration for the tempering effect during multi-pass thermal cycle in HAZ of low-alloy steel

    International Nuclear Information System (INIS)

    Yu, Lina; Nakabayashi, Yuma; Saida, Kazuyoshi; Mochizuki, Masahito; Nishimoto, Kazutoshi; Kameyama, Masashi; Hirano, Shinro; Chigusa, Naoki

    2011-01-01

    A new Thermal Cycle Tempering Parameter (TCTP) to deal with the tempering effect during multi-pass thermal cycles has been proposed by extending Larson-Miller parameter (LMP). Experimental result revealed that the hardness in synthetic HAZ of the low alloy steel subjected to multi tempering thermal cycles has a good linear relationship with TCTP. By using this relationship, the hardness of the low-alloy steel reheated with tempering thermal cycles can be predicted when the original hardness is known. (author)

  4. Signatures of Hot Molecular Hydrogen Absorption from Protoplanetary Disks. I. Non-thermal Populations

    Energy Technology Data Exchange (ETDEWEB)

    Hoadley, Keri; France, Kevin; Arulanantham, Nicole; Loyd, R. O. Parke; Kruczek, Nicholas, E-mail: keri.hoadley@colorado.edu [Laboratory for Atmospheric and Space Physics (LASP), University of Colorado Space Science Building (SPSC), 3665 Discovery Drive, Boulder, CO 80303 (United States)

    2017-09-01

    The environment around protoplanetary disks (PPDs) regulates processes that drive the chemical and structural evolution of circumstellar material. We perform a detailed empirical survey of warm molecular hydrogen (H{sub 2}) absorption observed against H i-Ly α (Ly α : λ 1215.67) emission profiles for 22 PPDs, using archival Hubble Space Telescope ultraviolet (UV) spectra to identify H{sub 2} absorption signatures and quantify the column densities of H{sub 2} ground states in each sightline. We compare thermal equilibrium models of H{sub 2} to the observed H{sub 2} rovibrational level distributions. We find that, for the majority of targets, there is a clear deviation in high-energy states ( T {sub exc} ≳ 20,000 K) away from thermal equilibrium populations ( T (H{sub 2}) ≳ 3500 K). We create a metric to estimate the total column density of non-thermal H{sub 2} ( N (H{sub 2}){sub nLTE}) and find that the total column densities of thermal ( N (H{sub 2})) and N (H{sub 2}){sub nLTE} correlate for transition disks and targets with detectable C iv-pumped H{sub 2} fluorescence. We compare N (H{sub 2}) and N (H{sub 2}){sub nLTE} to circumstellar observables and find that N (H{sub 2}){sub nLTE} correlates with X-ray and far-UV luminosities, but no correlations are observed with the luminosities of discrete emission features (e.g., Ly α , C iv). Additionally, N (H{sub 2}) and N (H{sub 2}){sub nLTE} are too low to account for the H{sub 2} fluorescence observed in PPDs, so we speculate that this H{sub 2} may instead be associated with a diffuse, hot, atomic halo surrounding the planet-forming disk. We create a simple photon-pumping model for each target to test this hypothesis and find that Ly α efficiently pumps H{sub 2} levels with T {sub exc} ≥ 10,000 K out of thermal equilibrium.

  5. Thermal cycling tests of actively cooled beryllium copper joints

    Energy Technology Data Exchange (ETDEWEB)

    Roedig, M.; Duwe, R.; Linke, J.; Schuster, A.; Wiechers, B. [Forschungszentrum Juelich GmbH (Germany)

    1998-01-01

    Screening tests (steady state heating) and thermal fatigue tests with several kinds of beryllium-copper joints have been performed in an electron beam facility. Joining techniques under investigation were brazing with silver containing and silver-free braze materials, hot isostatic pressing (HIP) and diffusion bonding (hot pressing). Best thermal fatigue performance was found for the brazed samples. (author)

  6. Modelling and Improvement of Thermal Cycling in Power Electronics for Motor Drive Applications

    DEFF Research Database (Denmark)

    Vernica, Ionut; Ma, Ke; Blaabjerg, Frede

    2016-01-01

    It is well known that the dynamical change of the thermal stress in the power devices is one of the major factors that have influences on the overall efficiency and reliability of power electronics. The main objective of this paper consists of identifying the main parameters that affect the thermal...... are identified during the acceleration and deceleration periods of the motor. The main causes for these adverse thermal cycles have been presented and, consequently, the influence of the deceleration slope, modulation technique and reactive current on the thermal cycles has been analyzed. Finally, the improved...

  7. Evaluation of the of thermal shock resistance of a castable containing andalusite aggregates by thermal shock cycles

    International Nuclear Information System (INIS)

    Garcia, G.C.R.; Santos, E.M.B.; Ribeiro, S.; Rodrigues, J.A.

    2011-01-01

    The thermal shock resistance of refractory materials is one of the most important characteristics that determine their performance in many applications, since abrupt and drastic differences in temperature can damage them. Resistance to thermal shock damage can be evaluated based on thermal cycles, i.e., successive heating and cooling cycles followed by an analysis of the drop in Young's modulus occurring in each cycle. The aim of this study was to evaluate the resistance to thermal shock damage in a commercial refractory concrete with andalusite aggregate. Concrete samples that were sintered at 1000 deg C and 1450 deg C for 5 hours to predict and were subjected to 30 thermal shock cycles, soaking in the furnace for 20 minutes at a temperature of 1000 deg C, and subsequent cooling in circulating water at 25 deg C. The results showed a decrease in Young's modulus and rupture around 72% for samples sintered at 1000 ° C, and 82% in sintered at 1450 ° C. The refractory sintered at 1450 deg C would show lower thermal shock resistance than the refractory sintered at 1000 deg C. (author)

  8. X-ray absorption spectroscopy study on the thermal and hydrazine reduction of graphene oxide

    International Nuclear Information System (INIS)

    Liang, Xianqing; Wang, Yu; Zheng, Huiyuan; Wu, Ziyu

    2014-01-01

    Highlights: • XAS study of GO and reduced GO was performed. • Detailed evolution of the electronic structures and chemical bonding of GO was revealed. • A new efficient route for the reduction of GO is proposed. - Abstract: X-ray absorption spectroscopy (XAS) was applied to systemically investigate the deoxygenation of graphene oxide (GO) via annealing and hydrazine treatment. Detailed evolution of the electronic structures and chemical bonding of GO was presented. The enhanced intensity of π * resonance and the appearance of splitting σ * resonance in C K-edge XAS spectra suggest high extents of recoveries of π-conjugation upon reduction using thermal annealing or hydrazine. Experimental results revealed that the carboxyl as well as epoxide and hydroxyl groups on the surface of GO were thermally reduced first, followed by the more difficult removal of carbonyl and cyclic ether groups at higher temperatures. The hydrazine reduction could remove epoxide, hydroxyl and carboxyl groups effectively, whereas the carbonyl groups were partially reduced with the incorporation of nitrogen species simultaneously. The residual oxygen functional groups on hydrazine-reduced GO could be further removed after modest thermal annealing. It was proposed that a combination of both types of reductions would give the best deoxygenation efficiency for the production of graphene

  9. Thermal cycling influence on microstructural characterization of alloys with high nickel content

    International Nuclear Information System (INIS)

    Abrudeanu, M.; Gradin, O.; Vulpe, S. C.; Ohai, D.

    2013-01-01

    The IV nuclear energy generation systems are aimed at making revolutionary improvements in economics, safety and reliability, and sustainability. To achieve these goals, Generation IV systems will operate at higher temperatures and in higher radiation fields. This paper shows the thermal cycling influences on microstructure and hardness of nickel based alloys: Incoloy 800 HT and Inconel 617. These alloys were meekly at a thermal cycling of 25, 50, 75 and 100 cycles. The temperature range of a cycle was between 400 O C and 700 O C. Nickel base alloys develop their properties by solid solution and/or precipitation strengthening. (authors)

  10. To What Degree Thermal Cycles Affect Chalk Strength

    DEFF Research Database (Denmark)

    Livada, Tijana; Nermoen, Anders; Korsnes, Reidar Inger

    triaxial cell experiments. For dry rock, no significant effects of temperature cycling was found on average tensile strength, however the range of the tensile failure stress is doubled for the samples exposed to 50 temperature cycles, as opposed to those to none. For water saturated cores, the temperature......Chalk reservoirs could potentially undergo destabilization as the result of repeated cold water injection into a hot reservoir during water flooding. Preliminary results of an ongoing study are presented in this paper, which compare the impact of temperature cycling on mechanical behavior on dry...... and water saturated chalk. Sixty disks of dry Kansas chalk exposed to different number of temperature cycles were tested for tensile strength using a Brazilian test. Changes in elastic properties as function of number of temperature cycles of the same chalk, but now saturated in water, were studied using...

  11. New method of thermal cycling stability test of phase change material

    Directory of Open Access Journals (Sweden)

    Putra Nandy

    2017-01-01

    Full Text Available Phase Change Material (PCM is the most promising material as thermal energy storage nowadays. As thermal energy storage, examination on endurance of material for long-term use is necessary to be carried out. Therefore, thermal cycling test is performed to ensure thermal stability of PCM. This study have found a new method on thermal cycling test of PCM sample by using thermoelectric as heating and cooling element. RT 22 HC was used as PCM sample on this thermal cycling test. The new method had many advantages compared to some references of the same test. It just needed a small container for PCM sample. The thermoelectric could release heat to PCM sample and absorb heat from PCM sample uniformly, respectively, was called as heating and cooling process. Hence, thermoelectric had to be supported by a relay control device to change its polarity so it could heat and cool PCM sample alternately and automatically. On the other hand, the thermoelectric was cheap, easy to be found and available in markets. It can be concluded that new method of thermal cycling test by using thermoelectric as source of heating and cooling can be a new reference for performing thermal cycling test on PCM.

  12. Study of an ejector-absorption refrigeration cycle with an adaptable ejector nozzle for different working conditions

    International Nuclear Information System (INIS)

    Vereda, C.; Ventas, R.; Lecuona, A.; Venegas, M.

    2012-01-01

    Highlights: ► An absorption refrigeration cycle with an ejector device at the absorber inlet is presented. ► This cycle is able to reduce up to 9 °C the temperature of onset of refrigerant generation without extra energy consumption. ► At very low driving temperatures it allows increasing the cooling capacity. ► The ejector device proposed has a partially variable geometry and we study its influence on the cycle performances. -- Abstract: This paper presents a numerical model of an ejector-absorption (single-effect) refrigeration cycle with ammonia–lithium nitrate solution as working fluid, operating under steady-state conditions. In this cycle, the ejector is located at the absorber inlet replacing the solution expansion valve. The liquid–gas ejector entrains refrigerant vapor from the evaporator; this way the absorber pressure becomes higher than the evaporator pressure without any additional energy consumption. The objective of this numerical model is to evaluate the influence of the ejector geometry on the cycle performances and to determine the range of the heat source temperature in which it is convenient to use a practical ejector in the absorption cycle. The simulation is based on UA-ΔT lm models for separate heat transfer regions in a novel implementation using plate-type heat exchangers and this way the results are offered as a function of the external temperatures. This study focuses on evaluating the feasibility of an ejector whose nozzle area is adjustable while the rest of the ejector dimensions are fixed, thus being more feasible than complete variable geometry ejectors. The cycle performance is reported for different mixing tube constant diameters. Results of the simulation show that the use of an ejector allows, among others, to decrease the activation temperature approximately 9 °C in respect to the conventional single-effect absorption cycle and increasing the COP for moderate temperatures. The variable ejector nozzle geometry is

  13. Effect of Thermal Cycling on the Tensile Behavior of CF/AL Fiber Metal Laminates

    Directory of Open Access Journals (Sweden)

    Muhammad Farhan Noor

    2017-09-01

    Full Text Available The objective of this research work was to estimate the effect of thermal cycling on the tensile behavior of CARALL composites. Fiber metal laminates (FMLs, based on 2D woven carbon fabric and 2024-T3 Alclad aluminum alloy sheet, was manufactured by pressure molding technique followed by hand layup method. Before fabrication, aluminum sheets were anodized with phosphoric acid to produce micro porous alumina layer on surface. This micro-porous layer is beneficial to produce strong bonding between metal and fiber surfaces in FMLs. The effect of thermal cycling (-65 to +70ºC on the tensile behavior of Cf/Al based FML was studied. Tensile strength was increased after 10 thermal cycles, but it was slightly decreased to some extent after 30, and 50 thermal cycles. Tensile modulus also shown the similar behavior as that of tensile strength.

  14. Efficient cycles for carbon capture CLC power plants based on thermally balanced redox reactors

    KAUST Repository

    Iloeje, Chukwunwike; Zhao, Zhenlong; Ghoniem, Ahmed F.

    2015-01-01

    undergoing oxidation and reduction. An earlier study showed that this thermal coupling between the oxidation and reduction reactors increases the efficiency by up to 2% points when implemented in a regenerative Brayton cycle. The present study extends

  15. Thermodynamics of the CO2–Absorption/Desorption Section in the Integrated Gasifying Combined cycle — II. Analysis

    Directory of Open Access Journals (Sweden)

    Jaroslav KOZACZKA

    2012-06-01

    Full Text Available The thermodynamic analysis of the absorption/desorption section of the ICGC–cycle has been presented using the Second Law with special emphasis on the thermodynamic effectivity concept and usability for complex systems investigations. Essential problems have been discussed based on the classical bibliographical items on the subject. Numerical calculations have been accomplished using results obtained in the first part, which contained absorption and desorption modeling approach oriented onto thermodynamic analyzes. Additionally the special properties of dilute solutions, especially the CO2/water system, have been presented and the problem of the solute chemical concentration exergy change suggested.

  16. Simulation of the compressor-assisted triple-effect H{sub 2}O/LiBr absorption cooling cycles

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jin Soo; Ziegler, F. [Bavarian Center for Applied Energy Research, Garching (Germany); Lee, Huen [Korea Advanced Inst. of Science and Technology, Taejon (Korea). Dept. of Chemical Engineering

    2002-03-01

    The construction of a triple-effect absorption cooling machine using the lithium bromide-based working fluid is strongly limited by the corrosion problem caused by the high generator temperature. In this study four compressor-assisted H{sub 2}O/LiBr cooling cycles were suggested to solve the problem by lowering the generator temperature of the basic theoretical triple-effect cycle. Each cycle includes one compressor at a different state point to elevate the pressure of the refrigerant vapor up to a useful condensation temperature. Cycle simulations were carried out to investigate both a basic triple-effect cycle and four compressor-assisted cycles. All types of compressor-assisted cycles were found to be operable with a significantly lowered generator temperature. The temperature decrements increase with elevated compression ratios. This means that, if a part of energy input is changed from heat to mechanical energy, the machine can be operated in a favorable region of generator temperature not to cause corrosion problems. In order to obtain 40 K of generator temperature decrement (from 475.95 K) for all cycles, 3-5% of cooling capacity equivalent mechanical energies were required for operating the compressor. A great advantage of the investigated triple-effect cycles is that the conventionally used H{sub 2}O/LiBr solution can be used as a working fluid without the danger of corrosion or without integrating multiple solution circuits.(author)

  17. Comparison of different models for the determination of the absorption and scattering coefficients of thermal barrier coatings

    International Nuclear Information System (INIS)

    Wang, Li; Eldridge, Jeffrey I.; Guo, S.M.

    2014-01-01

    The thermal radiative properties of thermal barrier coatings (TBCs) are becoming more important as the inlet temperatures of advanced gas-turbine engines are continuously being pushed higher in order to improve efficiency. To determine the absorption and scattering coefficients of TBCs, four-flux, two-flux and Kubelka–Munk models were introduced and used to characterize the thermal radiative properties of plasma-sprayed yttria-stabilized zirconia (YSZ) coatings. The results show that the absorption coefficient of YSZ is extremely low for wavelengths 200 μm suggests that when the coating thickness is larger than around twice the average scattering distance, the collimated flux can be simply treated as a diffuse flux inside the coating, and thus the two-flux model can be used to determine the absorption and scattering coefficients as a simplification of the four-flux model

  18. Joint Removal Implications : Thermal Analysis and Life-Cycle Cost

    Science.gov (United States)

    2018-04-01

    Deck joints are causing significant bridge deterioration and maintenance problems for Departments of Transportation (DOTs). Colorado State University researchers partnered with the Colorado DOT to analyze the effects of temperature change and thermal...

  19. Models for optimum thermo-ecological criteria of actual thermal cycles

    Directory of Open Access Journals (Sweden)

    Açikkalp Emin

    2013-01-01

    Full Text Available In this study, the ecological optimization point of irreversible thermal cycles (refrigerator, heat pump and power cycles was investigated. The importance of ecological optimization is to propose a way to use fuels and energy source more efficiently because of an increasing energy need and environmental pollution. It provides this by maximizing obtained (or minimizing supplied work and minimizing entropy generation for irreversible (actual thermal cycles. In this research, ecological optimization was defined for all basic irreversible thermal cycles, by using the first and second laws of thermodynamics. Finally, the ecological optimization was defined in thermodynamic cycles and results were given to show the effects of the cycles’ ecological optimization point, efficiency, COP and power output (or input, and exergy destruction.

  20. The Effects of Thermal Cycling on Gallium Nitride and Silicon Carbide Semiconductor Devices for Aerospace Use

    Science.gov (United States)

    Patterson, Richard L.; Hammoud, Ahmad

    2012-01-01

    Electronics designed for use in NASA space missions are required to work efficiently and reliably under harsh environment conditions. These Include radiation, extreme temperatures, thermal cycling, to name a few. Preliminary data obtained on new Gallium Nitride and Silicon Carbide power devices under exposure to radiation followed by long term thermal cycling are presented. This work was done in collaboration with GSFC and JPL in support of the NASA Electronic Parts and Packaging (NEPP) Program

  1. Structural, thermal and optical absorption features of heavy metal oxides doped tellurite rich glasses

    Directory of Open Access Journals (Sweden)

    Kawa M. Kaky

    Full Text Available In order to improve tellurite glass stability to be applicable for optical fiber amplifier applications, glasses with the composition of (70 − xTeO2. (10ZnO. (10WO3. (5Na2O. (5TiO2. (xBi2O3 (x = 1, 2, 3, 4, and 5 mol% have been produced and characterized using the related methods. Structural properties were investigated using X-ray diffraction (XRD which confirms the non-crystalline structure and scanning electron microscopy (SEM micrographs also confirm the XRD results. The energy dispersive X-ray (EDX analysis profiles show that all the mentioned elements are present in the prepared glasses. Following the IR spectra, all the tellurium bonds such as stretching vibrations of TeO4 tbp and TeO3/TeO3+1 unit are revealed. Raman spectra confirm the presence of different functional groups, actually, it shows bands mainly in four spectral regions: R1 (65–150 cm−1, R2 (280–550 cm−1, R3 (880–950 cm−1 and R4 (916–926 cm−1 and the identified bands are assigned to respective molecular groups. The thermal study was carried out using Differential scanning calorimetry (DSC which indicates good thermal stability of the synthesized glasses with increasing Bi concentration. From the optical absorption spectra, we evaluated cut-off edge wavelengths and found increasing cutoff wavelength with an increase in Bi2O3 concentration. In the UV–Visible region, optical band gap energy and allowed transitions were investigated using three methods; direct, indirect, and absorption spectrum fitting (ASF, and band gaps from indirect and ASF were matched. Keywords: Tellurite glasses, XRD, FT-IR, Raman, TGA/DSC

  2. Structural, thermal and optical absorption features of heavy metal oxides doped tellurite rich glasses

    Science.gov (United States)

    Kaky, Kawa M.; Lakshminarayana, G.; Baki, S. O.; Kityk, I. V.; Taufiq-Yap, Y. H.; Mahdi, M. A.

    In order to improve tellurite glass stability to be applicable for optical fiber amplifier applications, glasses with the composition of (70 - x)TeO2. (10)ZnO. (10)WO3. (5)Na2O. (5)TiO2. (x)Bi2O3 (x = 1, 2, 3, 4, and 5 mol%) have been produced and characterized using the related methods. Structural properties were investigated using X-ray diffraction (XRD) which confirms the non-crystalline structure and scanning electron microscopy (SEM) micrographs also confirm the XRD results. The energy dispersive X-ray (EDX) analysis profiles show that all the mentioned elements are present in the prepared glasses. Following the IR spectra, all the tellurium bonds such as stretching vibrations of TeO4 tbp and TeO3/TeO3+1 unit are revealed. Raman spectra confirm the presence of different functional groups, actually, it shows bands mainly in four spectral regions: R1 (65-150) cm-1, R2 (280-550) cm-1, R3 (880-950) cm-1 and R4 (916-926) cm-1 and the identified bands are assigned to respective molecular groups. The thermal study was carried out using Differential scanning calorimetry (DSC) which indicates good thermal stability of the synthesized glasses with increasing Bi concentration. From the optical absorption spectra, we evaluated cut-off edge wavelengths and found increasing cutoff wavelength with an increase in Bi2O3 concentration. In the UV-Visible region, optical band gap energy and allowed transitions were investigated using three methods; direct, indirect, and absorption spectrum fitting (ASF), and band gaps from indirect and ASF were matched.

  3. Cardboard Based Packaging Materials as Renewable Thermal Insulation of Buildings: Thermal and Life Cycle Performance

    OpenAIRE

    Čekon, Miroslav; Struhala, Karel; Slávik, Richard

    2017-01-01

    Cardboard based packaging components represent a material with a significant potential of renewable exploitation in buildings. This study presents the results of thermal and environmental analysis of existing packaging materials compared with standard conventional thermal insulations. Experimental measurements were performed to identify the thermal performance of studied cardboard packaging materials. Real-size samples were experimentally tested in laboratory measurements. The thermal resi...

  4. A non-conventional interpretation of thermal regeneration in steam cycles

    International Nuclear Information System (INIS)

    Bracco, Stefano; Damiani, Lorenzo

    2012-01-01

    Highlights: ► A better understanding of the concept of thermal regeneration in steam cycles. ► Use of a system composed by a non-regenerative cycle and several reverse cycles. ► Calculation of the heat pumps coefficients of performance. ► New interesting formulations of the regenerative cycle efficiency. -- Abstract: The paper aims to contribute to a better understanding of the thermodynamic concept of heat regeneration in steam power plants with a finite number of bleedings. A regenerative Rankine cycle is compared to a complex system (CHC – complete hybrid cycle) composed by one non-regenerative Rankine cycle (HEC – hybrid engine cycle) and more reverse cycles (RCs – reverse cycles), as many as the number of the bleedings, able to pump heat from the condenser to a series of surface feedwater heaters, disposed upstream of the steam plant boiler. The COPs (coefficients of performance) of the heat pumps are evaluated, and new interesting formulations of the efficiency of the regenerative steam cycle are proposed. In particular a steam cycle with two bleedings is analyzed, neglecting heat losses and pressure drops in the boiler and considering irreversibility only along the expansion line of the steam turbine and into the feedwater heaters. The efficiency and the work of the regenerative cycle are compared to the analogous values of the CHC cycle composed by one simple steam cycle (HEC) and two heat pump cycles (RCs), with steam as the working fluid. The two reverse cycles are considered completely reversible and raising heat from the condenser temperature to the bled steam condensing temperature. The paper shows the most significant results of the study in order to analyze the regenerative cycle and the CHC cycle in comparison with the non-regenerative Rankine cycle; in particular, the analysis is focused on the evaluation of the useful work, the heat supplied and the heat rejected for the examined cycles.

  5. The correlations between natural elements (K, U, Th) concentrations and thermal neutron absorption cross-section value (Σa) for rock samples of Carpatia area

    International Nuclear Information System (INIS)

    Swakon, J.; Cywicka-Jakiel, T.; Drozdowicz, E.; Gabanska, B.; Loskiewicz, J.; Woznicka, U.

    1991-01-01

    The paper presents a study of correlations between concentrations of potassium, uranium and thorium and thermal neutron absorption cross section in rock samples. This knowledge of correlation should help in recognizing the expansion ways and accumulation places of the elements responsible of high thermal neutron absorption cross section in some geological environments. The correlations show the existence of connections between the thermal neutron absorption cross section value and natural radioactivity elements concentration in rocks. The results confirm the existence of correlations between natural radioactive elements concentrations (particularly thorium) and thermal neutron absorption cross - section value in some rocks. (author). 12 refs, 23 figs, 6 tabs

  6. Determination of Scattering and Absorption Coefficients for Plasma-Sprayed Yttria-Stabilized Zirconia Thermal Barrier Coatings at Elevated Temperatures

    Science.gov (United States)

    Eldridge, Jeffrey I.; Spuckler, Charles M.; Markham, James R.

    2009-01-01

    The temperature dependence of the scattering and absorption coefficients for a set of freestanding plasma-sprayed 8 wt% yttria-stabilized zirconia (8YSZ) thermal barrier coatings (TBCs) was determined at temperatures up to 1360 C in a wavelength range from 1.2 micrometers up to the 8YSZ absorption edge. The scattering and absorption coefficients were determined by fitting the directional-hemispherical reflectance and transmittance values calculated by a four-flux Kubelka Munk method to the experimentally measured hemispherical-directional reflectance and transmittance values obtained for five 8YSZ thicknesses. The scattering coefficient exhibited a continuous decrease with increasing wavelength and showed no significant temperature dependence. The scattering is primarily attributed to the relatively temperature-insensitive refractive index mismatch between the 8YSZ and its internal voids. The absorption coefficient was very low (less than 1 per centimeter) at wavelengths between 2 micrometers and the absorption edge and showed a definite temperature dependence that consisted of a shift of the absorption edge to shorter wavelengths and an increase in the weak absorption below the absorption edge with increasing temperature. The shift in the absorption edge with temperature is attributed to strongly temperature-dependent multiphonon absorption. While TBC hemispherical transmittance beyond the absorption edge can be predicted by a simple exponential decrease with thickness, below the absorption edge, typical TBC thicknesses are well below the thickness range where a simple exponential decrease in hemispherical transmittance with TBC thickness is expected. [Correction added after online publication August 11, 2009: "edge to a shorter wavelengths" has been updated as edge to shorter wavelengths."

  7. Experimental investigation of high cycle thermal fatigue in a T-junction piping system

    Energy Technology Data Exchange (ETDEWEB)

    Selvam, P. Karthick; Kulenovic, Rudi; Laurien, Eckart [Stuttgart Univ. (Germany). Inst. of Nuclear Technology and Energy Systems (IKE)

    2015-10-15

    High cycle thermal fatigue damage of structure in the vicinity of T-junction piping systems in nuclear power plants is of importance. Mixing of coolant streams at significant temperature differences causes thermal fluctuations near piping wall leading to gradual thermal degradation. Flow mixing in a T-junction is performed. The determined factors result in bending stresses being imposed on the piping system ('Banana effect').

  8. APPLICATION OF POLYURETHANE FOAM FOR IMPACT ABSORPTION AND THERMAL INSULATION FOR RADIOACTIVE MATERIALS PACKAGINGS

    International Nuclear Information System (INIS)

    Smith, A; Glenn Abramczyk, G; Paul Blanton, P; Steve Bellamy, S; William Daugherty, W; Sharon Williamson, S

    2007-01-01

    Polyurethane foam has been widely used as an impact absorbing and thermal insulating material for large radioactive materials packages, since the 1980's. With the adoption of the regulatory crush test requirement, for smaller packages, polyurethane foam has been adopted as a replacement for cane fiberboard, because of its ability to withstand the crush test. Polyurethane foam is an engineered material whose composition is much more closely controlled than that of cane fiberboard. In addition, the properties of the foam can be controlled by controlling the density of the foam. The conditions under which the foam is formed, whether confined or unconfined have an affect on foam properties. The study reported here reviewed the application of polyurethane foam in RAM packagings and compared property values reported in the literature with published property values and test results for foam specimens taken from a prototype 9977 packaging. The study confirmed that, polyurethane foam behaves in a predictable and consistent manner and fully satisfies the functional requirements for impact absorption and thermal insulation

  9. Efficient cycles for carbon capture CLC power plants based on thermally balanced redox reactors

    KAUST Repository

    Iloeje, Chukwunwike

    2015-10-01

    © 2015 Elsevier Ltd. The rotary reactor differs from most alternative chemical looping combustion (CLC) reactor designs because it maintains near-thermal equilibrium between the two stages of the redox process by thermally coupling channels undergoing oxidation and reduction. An earlier study showed that this thermal coupling between the oxidation and reduction reactors increases the efficiency by up to 2% points when implemented in a regenerative Brayton cycle. The present study extends this analysis to alternative CLC cycles with the objective of identifying optimal configurations and design tradeoffs. Results show that the increased efficiency from reactor thermal coupling applies only to cycles that are capable of exploiting the increased availability in the reduction reactor exhaust. Thus, in addition to the regenerative cycle, the combined CLC cycle and the combined-regenerative CLC cycle are suitable for integration with the rotary reactor. Parametric studies are used to compare the sensitivity of the different cycle efficiencies to parameters like pressure ratio, turbine inlet temperature, carrier-gas fraction and purge steam generation. One of the key conclusions from this analysis is that while the optimal efficiency for regenerative CLC cycle was the highest of the three (56% at 3. bars, 1200. °C), the combined-regenerative cycle offers a trade-off that combines a reasonably high efficiency (about 54% at 12. bars, 1200. °C) with much lower gas volumetric flow rate and consequently, smaller reactor size. Unlike the other two cycles, the optimal compressor pressure ratio for the regenerative cycle is weakly dependent on the design turbine inlet temperature. For the regenerative and combined regenerative cycles, steam production in the regenerator below 2× fuel flow rate improves exhaust recovery and consequently, the overall system efficiency. Also, given that the fuel side regenerator flow is unbalanced, it is more efficient to generate steam from the

  10. A Peltier thermal cycling unit for radiopharmaceutical synthesis

    International Nuclear Information System (INIS)

    McKinney, C.J.; Nader, M.W.

    2001-01-01

    We have investigated the use of Peltier devices to rapidly cycle the temperature of reaction vessels in a radiopharmaceutical synthesis system. Peltier devices have the advantage that they can be actively cooled as well as heated, allowing precise and rapid control of vessel temperatures. Reaction vessel temperatures of between -6 deg. C and 110 deg. C have been obtained with commercially available devices with reasonable cycle times. Two devices have been used as the basis for a general purpose, two-pot synthesis system for production of [ 11 C] compounds such as raclopride

  11. The determination of kinetic parameters of LiF : Mg,Ti from thermal decaying curves of optical absorption bands

    CERN Document Server

    Yazici, A N

    2003-01-01

    In this paper, the thermal bleaching curves (TBCs) of specific optical absorption bands of LiF : Mg,Ti were measured as a function of temperature. The TBCs obtained were analysed to extract the kinetic parameters (the thermal activation energy (E) and the frequency factor (s)) of some TL glow peaks of LiF : Mg,Ti on the basis of the developed first-order kinetic model over a specified temperature region.

  12. Thermal mixing in T-junction piping system concerned with high-cycle thermal fatigue in structure

    International Nuclear Information System (INIS)

    Tanaka, Masaaki; Ohshima, Hiroyuki; Monji, Hideaki

    2008-01-01

    In Japan Atomic Energy Agency (JAEA), a numerical simulation code 'MUGTHES' has been developed to investigate thermal striping phenomena caused by turbulence mixing of fluids in different temperature and to provide transient data for an evaluation method of high-cycle thermal fatigue. MUGTHES adopts Large Eddy Simulation (LES) approach to predict unsteady phenomena in thermal mixing and employs boundary fitted coordinate system to be applied to complex geometry in a power reactor. Numerical simulation of thermal striping phenomena in a T-junction piping system (T-pipe) is conducted. Boundary condition for the simulation is chosen from an existing water experiment in JAEA, named as WATLON experiment. In the numerical simulation, standard Smagorinsky model is employed as eddy viscosity model with the model coefficient of 0.14 (=Cs). Numerical results of MUGTHES are verified by the comparisons with experimental results of velocity and temperature. Through the numerical simulation in the T-pipe, applicability of MUGTHES to the thermal striping phenomena is confirmed and the characteristic large-scale eddy structure which dominates thermal mixing and may cause high-cycle thermal fatigue is revealed. (author)

  13. Plastic response of thin films due to thermal cycling

    NARCIS (Netherlands)

    Nicola, L.; van der Giessen, E.; Needleman, A.; Ahzi, S; Cherkaoui, M; Khaleel, MA; Zbib, HM; Zikry, MA; Lamatina, B

    2004-01-01

    Discrete dislocation simulations of thin films on semi-infinite substrates under cyclic thermal loading are presented. The thin film is modelled as a two-dimensional single crystal under plane strain conditions. Dislocations of edge character can be generated from initially present sources and glide

  14. Hydraulic performance of compacted clay liners under simulated daily thermal cycles.

    Science.gov (United States)

    Aldaeef, A A; Rayhani, M T

    2015-10-01

    Compacted clay liners (CCLs) are commonly used as hydraulic barriers in several landfill applications to isolate contaminants from the surrounding environment and minimize the escape of leachate from the landfill. Prior to waste placement in landfills, CCLs are often exposed to temperature fluctuations which can affect the hydraulic performance of the liner. Experimental research was carried out to evaluate the effects of daily thermal cycles on the hydraulic performance of CCLs under simulated landfill conditions. Hydraulic conductivity tests were conducted on different soil specimens after being exposed to various thermal and dehydration cycles. An increase in the CCL hydraulic conductivity of up to one order of magnitude was recorded after 30 thermal cycles for soils with low plasticity index (PI = 9.5%). However, medium (PI = 25%) and high (PI = 37.2%) plasticity soils did not show significant hydraulic deviation due to their self-healing potential. Overlaying the CCL with a cover layer minimized the effects of daily thermal cycles, and maintained stable hydraulic performance in the CCLs even after exposure to 60 thermal cycles. Wet-dry cycles had a significant impact on the hydraulic aspect of low plasticity CCLs. However, medium and high plasticity CCLs maintained constant hydraulic performance throughout the test intervals. The study underscores the importance of protecting the CCL from exposure to atmosphere through covering it by a layer of geomembrane or an interim soil layer. Copyright © 2015 Elsevier Ltd. All rights reserved.

  15. Avoiding thermal striping damage: Experimentally-based design procedures for high-cycle thermal fatigue

    International Nuclear Information System (INIS)

    Betts, C.; Judd, A.M.; Lewis, M.W.J.

    1994-01-01

    In the coolant circuits of a liquid metal cooled reactor (LMR), where there is turbulent mixing of coolant streams at different temperatures, there are temperature fluctuations in the fluid. If an item of the reactor structure is immersed in this fluid it will, because of the good heat transfer from the flowing liquid metal, experience surface temperature fluctuations which will induce dynamic surface strains. It is necessary to design the reactor so that these temperature fluctuations do not, over the life of the plant, cause damage. The purpose of this paper is to describe design procedures to prevent damage of this type. Two such procedures are given, one to prevent the initiation of defects in a nominally defect-free structure or to allow initiation only at the end of the component life, and the other to prevent significant growth of undetectable pre-existing defects of the order of 0.2 to 0.4 mm in depth. Experimental validation of these procedures is described, and the way they can be applied in practice is indicated. To set the scene the paper starts with a brief summary of cases in which damage of this type, or the need to avoid such damage, have had important effects on reactor operation. Structural damage caused by high-cycle thermal fatigue has had a significant adverse influence on the operation of LMRs on several occasions. It is necessary to eliminate the risk of such damage at the design stage. In the absence of detailed knowledge of the temperature history to which it will be subject, an LMR structure can be designed so that, if it is initially free of defects more than 0.1 mm deep, no such defects will be initiated by high-cycle fatigue. This can be done by ensuring that the maximum source temperature difference in the liquid metal is less than a limiting value, which depends on temperature. The limit is very low, however, and likely to be restrictive. This method, by virtue of its safety margin, takes into account pre-existing surface crack

  16. The thermal neutron absorption cross-sections, resonance integrals and resonance parameters of silicon and its stable isotopes

    International Nuclear Information System (INIS)

    Story, J.S.

    1969-09-01

    The data available up to the end of November 1968 on the thermal neutron absorption cross-sections, resonance absorption integrals, and resonance parameters of silicon and its stable isotopes are collected and discussed. Estimates are given of the mean spacing of the energy levels of the compound nuclei near the neutron binding energy. It is concluded that the thermal neutron absorption cross-section and resonance absorption integral of natural silicon are not well established. The data on these two parameters are somewhat correlated, and three different assessments of the resonance integral are presented which differ over-all by a factor of 230. Many resonances have been detected by charged particle reactions which have not yet been observed in neutron cross-section measurements. One of these resonances of Si 2 8, at E n = 4 ± 5 keV might account for the large resonance integral which is derived, very uncertainly, from integral data. The principal source of the measured resonance integral of Si 3 0 has not yet been located. The thermal neutron absorption cross-section of Si 2 8 appears to result mainly from a negative energy resonance, possibly the resonance at E n = - 59 ± 5 keV detected by the Si 2 8 (d,p) reaction. (author)

  17. A comparison of neutron resonance absorption in thermal reactor lattices in the AUS neutronics code system with Monte Carlo calculations

    International Nuclear Information System (INIS)

    Robinson, G.S.

    1985-08-01

    The calculation of resonance shielding by the subgroup method, as incorporated in the MIRANDA module of the AUS neutronics code system, is compared with Monte Carlo calculatons for a number of thermal reactor lattices. For the large range of single rod and rod cluster lattices considered, AUS results for resonance absorption were high by up to two per cent

  18. Analysis of thermal cycles and working fluids for power generation in space

    International Nuclear Information System (INIS)

    Tarlecki, Jason; Lior, Noam; Zhang Na

    2007-01-01

    Production of power in space for terrestrial use is of great interest in view of the rapidly rising power demand and its environmental impacts. Space also offers a very low temperature, making it a perfect heat sink for power plants, thus offering much higher efficiencies. This paper focuses on the evaluation and analysis of thermal Brayton, Ericsson and Rankine power cycles operating at space conditions on several appropriate working fluids. Under the examined conditions, the thermal efficiency of Brayton cycles reaches 63%, Ericsson 74%, and Rankine 85%. These efficiencies are significantly higher than those for the computed or real terrestrial cycles: by up to 45% for the Brayton, and 17% for the Ericsson; remarkably 44% for the Rankine cycle even when compared with the best terrestrial combined cycles. From the considered working fluids, the diatomic gases (N 2 and H 2 ) produce somewhat better efficiencies than the monatomic ones in the Brayton and Rankine cycles. The Rankine cycles require radiator areas that are larger by up to two orders of magnitude than those required for the Brayton and Ericsson cycles. The results of the analysis of the sensitivity of the cycle performance parameters to major parameters such as turbine inlet temperature and pressure ratio are presented, equations or examining the effects of fluid properties on the radiator area and pressure drop were developed, and the effects of the working fluid properties on cycle efficiency and on the power production per unit radiator area were explored to allow decisions on the optimal choice of working fluids

  19. Accelerated Thermal Cycling Test of Microencapsulated Paraffin Wax/Polyaniline Made by Simple Preparation Method for Solar Thermal Energy Storage.

    Science.gov (United States)

    Silakhori, Mahyar; Naghavi, Mohammad Sajad; Metselaar, Hendrik Simon Cornelis; Mahlia, Teuku Meurah Indra; Fauzi, Hadi; Mehrali, Mohammad

    2013-04-29

    Microencapsulated paraffin wax/polyaniline was prepared using a simple in situ polymerization technique, and its performance characteristics were investigated. Weight losses of samples were determined by Thermal Gravimetry Analysis (TGA). The microencapsulated samples with 23% and 49% paraffin showed less decomposition after 330 °C than with higher percentage of paraffin. These samples were then subjected to a thermal cycling test. Thermal properties of microencapsulated paraffin wax were evaluated by Differential Scanning Calorimeter (DSC). Structure stability and compatibility of core and coating materials were also tested by Fourier transform infrared spectrophotometer (FTIR), and the surface morphology of the samples are shown by Field Emission Scanning Electron Microscopy (FESEM). It has been found that the microencapsulated paraffin waxes show little change in the latent heat of fusion and melting temperature after one thousand thermal recycles. Besides, the chemical characteristics and structural profile remained constant after one thousand thermal cycling tests. Therefore, microencapsulated paraffin wax/polyaniline is a stable material that can be used for thermal energy storage systems.

  20. Residual Tensile Property of Plain Woven Jute Fiber/Poly(Lactic Acid Green Composites during Thermal Cycling

    Directory of Open Access Journals (Sweden)

    Hideaki Katogi

    2016-07-01

    Full Text Available This study investigated the residual tensile properties of plain woven jute fiber reinforced poly(lactic acid (PLA during thermal cycling. Temperature ranges of thermal cycling tests were 35–45 °C and 35–55 °C. The maximum number of cycles was 103 cycles. The quasi-static tensile tests of jute fiber, PLA, and composite were conducted after thermal cycling tests. Thermal mechanical analyses of jute fiber and PLA were conducted after thermal cycling tests. Results led to the following conclusions. For temperatures of 35–45 °C, tensile strength of composite at 103 cycles decreased 10% compared to that of composite at 0 cycles. For temperatures of 35–55 °C, tensile strength and Young’s modulus of composite at 103 cycles decreased 15% and 10%, respectively, compared to that of composite at 0 cycles. Tensile properties and the coefficient of linear expansion of PLA and jute fiber remained almost unchanged after thermal cycling tests. From observation of a fracture surface, the length of fiber pull out in the fracture surface of composite at 103 cycles was longer than that of composite at 0 cycles. Therefore, tensile properties of the composite during thermal cycling were decreased, probably because of the decrease of interfacial adhesion between the fiber and resin.

  1. Residual Tensile Property of Plain Woven Jute Fiber/Poly(Lactic Acid) Green Composites during Thermal Cycling.

    Science.gov (United States)

    Katogi, Hideaki; Takemura, Kenichi; Akiyama, Motoki

    2016-07-14

    This study investigated the residual tensile properties of plain woven jute fiber reinforced poly(lactic acid) (PLA) during thermal cycling. Temperature ranges of thermal cycling tests were 35-45 °C and 35-55 °C. The maximum number of cycles was 10³ cycles. The quasi-static tensile tests of jute fiber, PLA, and composite were conducted after thermal cycling tests. Thermal mechanical analyses of jute fiber and PLA were conducted after thermal cycling tests. Results led to the following conclusions. For temperatures of 35-45 °C, tensile strength of composite at 10³ cycles decreased 10% compared to that of composite at 0 cycles. For temperatures of 35-55 °C, tensile strength and Young's modulus of composite at 10³ cycles decreased 15% and 10%, respectively, compared to that of composite at 0 cycles. Tensile properties and the coefficient of linear expansion of PLA and jute fiber remained almost unchanged after thermal cycling tests. From observation of a fracture surface, the length of fiber pull out in the fracture surface of composite at 10³ cycles was longer than that of composite at 0 cycles. Therefore, tensile properties of the composite during thermal cycling were decreased, probably because of the decrease of interfacial adhesion between the fiber and resin.

  2. High-frequency thermal-electrical cycles for pyroelectric energy conversion

    International Nuclear Information System (INIS)

    Bhatia, Bikram; Damodaran, Anoop R.; Cho, Hanna; Martin, Lane W.; King, William P.

    2014-01-01

    We report thermal to electrical energy conversion from a 150 nm thick BaTiO 3 film using pyroelectric cycles at 1 kHz. A microfabricated platform enables temperature and electric field control with temporal resolution near 1 μs. The rapid electric field changes as high as 11 × 10 5  kV/cm-s, and temperature change rates as high as 6 × 10 5  K/s allow exploration of pyroelectric cycles in a previously unexplored operating regime. We investigated the effect of phase difference between electric field and temperature cycles, and electric field and temperature change rates on the electrical energy generated from thermal-electrical cycles based on the pyroelectric Ericsson cycle. Complete thermodynamic cycles are possible up to the highest cycle rates tested here, and the energy density varies significantly with phase shifts between temperature and electric field waveforms. This work could facilitate the design and operation of pyroelectric cycles at high cycle rates, and aid in the design of new pyroelectric systems

  3. A thermal model for the seasonal nitrogen cycle on Triton

    Science.gov (United States)

    Hansen, Candice J.; Paige, David A.

    1992-01-01

    The seasonal N2-cycle model presently used to characterize such observed phenomena on Triton as atmospheric pressure and surface albedo features at the time of the Voyager encounter incorporates diurnal and seasonal subsurface heat conduction, and can account for the heat capacity of N2 frost deposits. The results obtained by this model differ from those of previous studies in that they do not predict the seasonal freezing-out of the Triton atmosphere; even for a wide range of input parameters, the bright southern polar cap is seen as rather unlikely to be N2. The results support the microphysical arguments for the presence of either dark or smooth translucent N2 frosts on the Triton surface.

  4. Thermodynamic analysis of a novel exhaust heat-driven non-adiabatic ejection-absorption refrigeration cycle using R290/oil mixture

    International Nuclear Information System (INIS)

    Li, Keqiao; Cai, Dehua; Liu, Yue; Jiang, Jingkai; Sun, Wei; He, Guogeng

    2017-01-01

    Graphical abstract: A novel air-cooled non-adiabatic ejection-absorption refrigeration cycle using R290/refrigeration oil has been thermodynamically analyzed. Influences of the ejector and the non-adiabatic absorber applications on the system performance and other system operation parameters have been investigated. The simulation results will be of great help to the miniaturization and practical application of the air-cooled absorption refrigeration system. - Highlights: • A novel air-cooled non-adiabatic ejection-absorption refrigeration cycle is proposed. • Influences of the ejector and the air-cooled non-adiabatic absorber applications on the system performance are investigated. • Variations of system performance and other system operation parameters are investigated. • R290/refrigeration oil mixture used as working pairs is analyzed. - Abstract: This paper thermodynamically analyzes a novel air-cooled non-adiabatic ejection-absorption refrigeration cycle with R290/oil mixture driven by exhaust heat. An ejector located at the upstream of the non-adiabatic absorber is employed to improve the cycle performance. Variations of COP, circulation ratio and component heat load of the system as a function of generating temperature, pressure ratio, absorption temperature, condensing temperature and evaporating temperature have been investigated in this work. The simulation results show that, compared with the conventional absorption refrigeration cycle, this non-adiabatic ejection-absorption refrigeration cycle has higher absorption efficiency, better performance, wider working condition range and lower total heat load and its COP can reach as high as 0.5297. The implementation of the ejector and the non-adiabatic absorber helps to realize the miniaturization and wider application of the absorption refrigeration system. In addition, R290/oil mixture is a kind of highly potential working pairs for absorption refrigeration.

  5. Exergetic comparison of two different cooling technologies for the power cycle of a thermal power plant

    International Nuclear Information System (INIS)

    Blanco-Marigorta, Ana M.; Victoria Sanchez-Henriquez, M.; Pena-Quintana, Juan A.

    2011-01-01

    Exergetic analysis is without any doubt a powerful tool for developing, evaluating and improving an energy conversion system. In the present paper, two different cooling technologies for the power cycle of a 50 MWe solar thermal power plant are compared from the exergetic viewpoint. The Rankine cycle design is a conventional, single reheat design with five closed and one open extraction feedwater heaters. The software package GateCycle is used for the thermodynamic simulation of the Rankine cycle model. The first design configuration uses a cooling tower while the second configuration uses an air cooled condenser. With this exergy analysis we identify the location, magnitude and the sources or thermodynamic inefficiencies in this thermal system. This information is very useful for improving the overall efficiency of the power system and for comparing the performance of both technologies.

  6. Economic optimization of a Kalina cycle for a parabolic trough solar thermal power plant

    DEFF Research Database (Denmark)

    Modi, Anish; Kærn, Martin Ryhl; Andreasen, J. G.

    2015-01-01

    -water mixture evaporates and condenses with a temperature glide, thus providing a better match with the heat source/sink temperature profile. This better match results in reduced thermal irreversibility, but at the cost of relatively larger heat exchanger areas. The parabolic trough collector is the most mature...... heat transfer correlations, and appropriate cost functions were used to estimate the costs for the various plant components. The optimal capital investment costs were determined for several values of the turbine inlet ammonia mass fraction and among the compared cases, the Kalina cycle has the minimum......The Kalina cycle has recently seen increased interest as a replacement for the more traditional steam Rankine cycle for geothermal, solar, ocean thermal energy conversion and waste heat recovery applications. The Kalina cycle uses a mixture of ammonia and water as the working fluid. The ammonia...

  7. Absorption Refrigeration Cycles with Ammonia-Ionic Liquid Working Pairs Studied by Molecular Simulation

    NARCIS (Netherlands)

    Becker, T.M.; Wang, M.; Kabra, Abhishek; Jamali, S.H.; Ramdin, M.; Dubbeldam, D.; Infante Ferreira, C.A.; Vlugt, T.J.H.

    2018-01-01

    For absorption refrigeration, it has been shown that ionic liquids have the potential to replace conventional working pairs. Due to the huge number of possibilities, conducting lab experiments to find the optimal ionic liquid is infeasible. Here, we provide a proof-of-principle study of an

  8. Effects of Thermal Cycling on Control and Irradiated EPC 2nd Generation GaN FETs

    Science.gov (United States)

    Patterson, Richard L.; Scheick, Leif; Lauenstein, Jean-Marie; Casey, Megan; Hammoud, Ahmad

    2013-01-01

    The power systems for use in NASA space missions must work reliably under harsh conditions including radiation, thermal cycling, and exposure to extreme temperatures. Gallium nitride semiconductors show great promise, but information pertaining to their performance is scarce. Gallium nitride N-channel enhancement-mode field effect transistors made by EPC Corporation in a 2nd generation of manufacturing were exposed to radiation followed by long-term thermal cycling in order to address their reliability for use in space missions. Results of the experimental work are presented and discussed.

  9. Thermal Cycling and High Temperature Reverse Bias Testing of Control and Irradiated Gallium Nitride Power Transistors

    Science.gov (United States)

    Patterson, Richard L.; Boomer, Kristen T.; Scheick, Leif; Lauenstein, Jean-Marie; Casey, Megan; Hammoud, Ahmad

    2014-01-01

    The power systems for use in NASA space missions must work reliably under harsh conditions including radiation, thermal cycling, and exposure to extreme temperatures. Gallium nitride semiconductors show great promise, but information pertaining to their performance is scarce. Gallium nitride N-channel enhancement-mode field effect transistors made by EPC Corporation in a 2nd generation of manufacturing were exposed to radiation followed by long-term thermal cycling and testing under high temperature reverse bias conditions in order to address their reliability for use in space missions. Result of the experimental work are presented and discussed.

  10. Effects of Radiation and Long-Term Thermal Cycling on EPC 1001 Gallium Nitride Transistors

    Science.gov (United States)

    Patterson, Richard L.; Scheick, Leif; Lauenstein, Jean-Marie; Casey, Megan; Hammoud, Ahmad

    2012-01-01

    Electronics designed for use in NASA space missions are required to work efficiently and reliably under harsh environment conditions. These include radiation, extreme temperatures, and thermal cycling, to name a few. Data obtained on long-term thermal cycling of new un-irradiated and irradiated samples of EPC1001 gallium nitride enhancement-mode transistors are presented. This work was done by a collaborative effort including GRC, GSFC, and support the NASA www.nasa.gov 1 JPL in of Electronic Parts and Packaging (NEPP) Program

  11. Mineralogical control on thermal damage and the presence of a thermal Kaiser effect during temperature-cycling experiments

    Science.gov (United States)

    Browning, J.; Daoud, A.; Meredith, P. G.; Mitchell, T. M.

    2017-12-01

    Volcanic and geothermal systems are in part controlled by the mechanical and thermal stresses acting on them and so it is important to understand the response of volcanic rocks to thermo-mechanical loading. One such response is the well-known `Kaiser stress-memory' effect observed under cyclic mechanical loading. By contrast, the presence of an analogous `Kaiser temperature-memory effect' during cyclic thermal loading has received little attention. We have therefore explored the possibility of a Kaiser temperature-memory effect using three igneous rocks of different composition, grain size and origin; Slaufrudalur Granophyre (SGP), Nea Kameni Andesite (NKA) and Seljadalur Basalt (SB). We present results from a series of thermal stressing experiments in which acoustic emissions (AE) were recorded contemporaneously with changing temperature. Samples of each rock were subjected to both a single heating and cooling cycle to a maximum temperature of 900 °C and multiple heating/cooling cycles to peak temperatures of 350°C, 500°C, 700°C and 900 °C (all at a constant rate of 1°C/min on heating and a natural cooling rate of memory effect in SGP, but not in either NKA and SB. We further find that the vast majority of thermal crack damage is generated upon cooling in the finer grained materials (NKA and SB), but that substantial thermal crack damage is generated during heating in the coarser grained SGP. The total amount of crack damage generated due to heating or cooling is dependent on the mineral composition and, most importantly, the grain size and arrangement, as well as the maximum temperature to which the rock is exposed. Knowledge of thermal stress history and the presence of a Kaiser temperature-memory effect is potentially important in understanding magma chamber dynamics, where the cyclic nature of mechanical and thermal inflation and deflation can lead to sequential accumulation of damage, potentially leading to critical rupture.

  12. Estimating the power efficiency of the thermal power plant modernization by using combined-cycle technologies

    International Nuclear Information System (INIS)

    Hovhannisyan, L.S.; Harutyunyan, N.R.

    2013-01-01

    The power efficiency of the thermal power plant (TPP) modernization by using combined-cycle technologies is introduced. It is shown that it is possible to achieve the greatest decrease in the specific fuel consumption at modernizing the TPP at the expense of introducing progressive 'know-how' of the electric power generation: for TPP on gas, it is combined-cycle, gas-turbine superstructures of steam-power plants and gas-turbines with heat utilization

  13. Development potential for thermal reactors and their fuel cycles

    International Nuclear Information System (INIS)

    Rogers, J.T.; Dodds, H.L. Jr.; Florido, P.C.; Gat, U.; Kondo, S.; Spinks, N.S.

    1997-01-01

    Water-cooled reactors represent the only types which have reached widespread commercial use up to the present day. Given the plentiful supply of uranium in the world today, this situation might be expected to continue for some time into the future. Nevertheless, for different reasons several countries consider that either new reactor types should be developed or that existing types should be improved substantially. The predominant reason in the short term is to improve the competitive position of nuclear energy supply versus fossil energy. In the longer term, regional and national fuel supply independence may become the dominant driving forces. This paper outlines several possible means for responding to these driving forces. It is not meant to include an exhaustive list of all possibilities, but only to illustrate some alternative routes. These routes range from enhancement of existing reactor concepts to combination of nuclear with fossil systems, and finally to the introduction of radically new thermal reactor concepts. Each of these has its obvious advantages and disadvantages and will come forward or will recede depending on technical feasibility, economics, long-term sustainability, and national policy. (author)

  14. Energy audit: thermal power, combined cycle, and cogeneration plants

    Energy Technology Data Exchange (ETDEWEB)

    Abbi, Yash Pal

    2012-07-01

    The availability of fossil fuels required for power plants is reducing and their costs increasing rapidly. This gives rise to increase in the cost of generation of electricity. But electricity regulators have to control the price of electricity so that consumers are not stressed with high costs. In addition, environmental considerations are forcing power plants to reduce CO2 emissions. Under these circumstances, power plants are constantly under pressure to improve the efficiency of operating plants, and to reduce fuel consumption. In order to progress in this direction, it is important that power plants regularly audit their energy use in terms of the operating plant heat rate and auxiliary power consumption. The author attempts to refresh the fundamentals of the science and engineering of thermal power plants, establish its link with the real power plant performance data through case studies, and further develop techno-economics of the energy efficiency improvement measures. This book will rekindle interest in energy audits and analysis of the data for designing and implementation of energy conservation measures on a continuous basis.

  15. Effect of Thermal Cycling on the Tensile Behavior of Polymer Composites Reinforced by Basalt and Carbon Fibers

    Science.gov (United States)

    Khalili, S. Mohammad Reza; Najafi, Moslem; Eslami-Farsani, Reza

    2017-01-01

    The aim of the present work was to investigate the effect of thermal cycling on the tensile behavior of three types of polymer-matrix composites — a phenolic resin reinforced with woven basalt fibers, woven carbon fibers, and hybrid basalt and carbon fibers — in an ambient environment. For this purpose, tensile tests were performed on specimens previously subjected to a certain number of thermal cycles. The ultimate tensile strength of the specimen reinforced with woven basalt fibers had by 5% after thermal cycling, but the strength of the specimen with woven carbon fibers had reduced to a value by 11% higher than that before thermal cycling.

  16. Open cycle ocean thermal energy conversion system structure

    Science.gov (United States)

    Wittig, J. Michael

    1980-01-01

    A generally mushroom-shaped, open cycle OTEC system and distilled water producer which has a skirt-conduit structure extending from the enlarged portion of the mushroom to the ocean. The enlarged part of the mushroom houses a toroidal casing flash evaporator which produces steam which expands through a vertical rotor turbine, partially situated in the center of the blossom portion and partially situated in the mushroom's stem portion. Upon expansion through the turbine, the motive steam enters a shell and tube condenser annularly disposed about the rotor axis and axially situated beneath the turbine in the stem portion. Relatively warm ocean water is circulated up through the radially outer skirt-conduit structure entering the evaporator through a radially outer portion thereof, flashing a portion thereof into motive steam, and draining the unflashed portion from the evaporator through a radially inner skirt-conduit structure. Relatively cold cooling water enters the annular condenser through the radially inner edge and travels radially outwardly into a channel situated along the radially outer edge of the condenser. The channel is also included in the radially inner skirt-conduit structure. The cooling water is segregated from the potable, motive steam condensate which can be used for human consumption or other processes requiring high purity water. The expansion energy of the motive steam is partially converted into rotational mechanical energy of the turbine rotor when the steam is expanded through the shaft attached blades. Such mechanical energy drives a generator also included in the enlarged mushroom portion for producing electrical energy. Such power generation equipment arrangement provides a compact power system from which additional benefits may be obtained by fabricating the enclosing equipment, housings and component casings from low density materials, such as prestressed concrete, to permit those casings and housings to also function as a floating

  17. Thermal Boundary Layer Effects on Line-of-Sight Tunable Diode Laser Absorption Spectroscopy (TDLAS) Gas Concentration Measurements.

    Science.gov (United States)

    Qu, Zhechao; Werhahn, Olav; Ebert, Volker

    2018-06-01

    The effects of thermal boundary layers on tunable diode laser absorption spectroscopy (TDLAS) measurement results must be quantified when using the line-of-sight (LOS) TDLAS under conditions with spatial temperature gradient. In this paper, a new methodology based on spectral simulation is presented quantifying the LOS TDLAS measurement deviation under conditions with thermal boundary layers. The effects of different temperature gradients and thermal boundary layer thickness on spectral collisional widths and gas concentration measurements are quantified. A CO 2 TDLAS spectrometer, which has two gas cells to generate the spatial temperature gradients, was employed to validate the simulation results. The measured deviations and LOS averaged collisional widths are in very good agreement with the simulated results for conditions with different temperature gradients. We demonstrate quantification of thermal boundary layers' thickness with proposed method by exploitation of the LOS averaged the collisional width of the path-integrated spectrum.

  18. The use of absorption refrigeration systems in combined cycle power plants; Empleo de sistemas de refrigeracion por absorcion en plantas de ciclo combinado

    Energy Technology Data Exchange (ETDEWEB)

    Romero Paredes, H.; Ambriz, J.J.; Vargas, M.; Godinez, M.; Gomez, F.; Valdez, L.; Pantoja, G. [Universidad Autonoma Metropolitana, Unidad Iztapalapa, Departamento de Ingenieria de Procesos e Hidraulica, Mexico D. F. (Mexico)

    1995-12-31

    Day after day the electric power generation tends to be done in the most efficient way in order to diminish the generation costs and the rate of environmental pollution per KWh generated. This paper discusses the application of absorption refrigeration systems for the cooling of the air entering the compressor of a gas turbine in a combined cycle, in order to increase the mass air flow and with it the turbine output. The flows with remanent energy content that are not used in a combined cycle can be used for the operation of the absorption refrigeration system. This way, the required thermal energy for the cooling system is free. With this system it is possible to raise the gas turbine generation output from 5% to 25%. [Espanol] La generacion electrica dia con dia pretende realizarse de la manera mas eficiente posible con el objeto de disminuir los costos de generacion y la tasa de contaminacion ambiental por Kwh generado. En el presente trabajo se introduce la aplicacion de sistemas de refrigeracion por absorcion para el enfriamiento del aire de entrada al compresor de la turbina de gas de un ciclo combinado, con el objeto de aumentar el flujo masico del aire y con ello la potencia de salida de la turbina. Las corrientes con contenido remanente de energia termica que no se usan en una planta de ciclo combinado pueden servir para operar el sistema de refrigeracion por absorcion. De esta manera, la energia termica requerida para el sistema de enfriamiento es gratuita. Con este sistema es posible incrementar la potencia de generacion de la turbina de gas de 5 a 25%.

  19. The use of absorption refrigeration systems in combined cycle power plants; Empleo de sistemas de refrigeracion por absorcion en plantas de ciclo combinado

    Energy Technology Data Exchange (ETDEWEB)

    Romero Paredes, H; Ambriz, J J; Vargas, M; Godinez, M; Gomez, F; Valdez, L; Pantoja, G [Universidad Autonoma Metropolitana, Unidad Iztapalapa, Departamento de Ingenieria de Procesos e Hidraulica, Mexico D. F. (Mexico)

    1996-12-31

    Day after day the electric power generation tends to be done in the most efficient way in order to diminish the generation costs and the rate of environmental pollution per KWh generated. This paper discusses the application of absorption refrigeration systems for the cooling of the air entering the compressor of a gas turbine in a combined cycle, in order to increase the mass air flow and with it the turbine output. The flows with remanent energy content that are not used in a combined cycle can be used for the operation of the absorption refrigeration system. This way, the required thermal energy for the cooling system is free. With this system it is possible to raise the gas turbine generation output from 5% to 25%. [Espanol] La generacion electrica dia con dia pretende realizarse de la manera mas eficiente posible con el objeto de disminuir los costos de generacion y la tasa de contaminacion ambiental por Kwh generado. En el presente trabajo se introduce la aplicacion de sistemas de refrigeracion por absorcion para el enfriamiento del aire de entrada al compresor de la turbina de gas de un ciclo combinado, con el objeto de aumentar el flujo masico del aire y con ello la potencia de salida de la turbina. Las corrientes con contenido remanente de energia termica que no se usan en una planta de ciclo combinado pueden servir para operar el sistema de refrigeracion por absorcion. De esta manera, la energia termica requerida para el sistema de enfriamiento es gratuita. Con este sistema es posible incrementar la potencia de generacion de la turbina de gas de 5 a 25%.

  20. Influence of thermal cycling on flexural properties of composites reinforced with unidirectional silica-glass fibers.

    Science.gov (United States)

    Meriç, Gökçe; Ruyter, I Eystein

    2008-08-01

    The purpose was to investigate the effect of water storage and thermal cycling on the flexural properties of differently sized unidirectional fiber-reinforced composites (FRCs) containing different quantities of fibers. The effect of fiber orientation on the thermal expansion of FRCs as well as how the stresses in the composites can be affected was considered. An experimental polymeric base material was reinforced with silica-glass fibers. The cleaned and silanized fibers were sized with either linear PBMA-size or crosslinked PMMA-size. For the determination of flexural properties and water uptake, specimens were processed with various quantities of differently sized unidirectional fibers. Water uptake of FRC was measured. Water immersed specimens were thermally cycled for 500 and 12,000 cycles (5 degrees C/55 degrees C). Flexural properties of "dry" and wet specimens with and without thermal cycling were determined by a three-point bending test. The linear coefficients of thermal expansion (LCTE) for FRC samples with different fiber orientations were determined using a thermomechanical analyzer. Water uptake of the FRC specimens increased with a decrease in fiber content of the FRC. Flexural properties of FRCs improved with increasing fiber content, whereas the flexural properties were not influenced significantly by water and thermal cycling. Fiber orientation had different effects on LCTE of FRCs. Unidirectional FRCs had two different LCTE in longitudinal and transverse directions whereas bidirectional FRCs had similar LCTE in two directions and a higher one in the third direction. The results of the study suggest that the surface-treated unidirectional silica-glass FRC can be used for long-term clinical applications in the oral cavity.

  1. Thermal cycling effects on adhesion of resin-bovine enamel junction among different composite resins.

    Science.gov (United States)

    Chen, Wen-Cheng; Ko, Chia-Ling; Wu, Hui-Yu; Lai, Pei-Ling; Shih, Chi-Jen

    2014-10-01

    Thermal cycling is used to mimic the changes in oral cavity temperature experienced by composite resins when used clinically. The purpose of this study is to assess the thermal cycling effects of in-house produced composite resin on bonding strength. The dicalcium phosphate anhydrous filler surfaces are modified using nanocrystals and silanization (w/NP/Si). The resin is compared with commercially available composite resins Filtek Z250, Z350, and glass ionomer restorative material GIC Fuji-II LC (control). Different composite resins were filled into the dental enamel of bovine teeth. The bond force and resin-enamel junction graphical structures of the samples were determined after thermal cycling between 5 and 55°C in deionized water for 600 cycles. After thermal cycling, the w/NP/Si 30wt%, 50wt% and Filtek Z250, Z350 groups showed higher shear forces than glass ionomer GIC, and w/NP/Si 50wt% had the highest shear force. Through SEM observations, more of the fillings with w/NP/Si 30wt% and w/NP/Si 50wt% groups flowed into the enamel tubule, forming closed tubules with the composite resins. The push-out force is proportional to the resin flow depth and uniformity. The push-out tubule pore and resin shear pattern is the most uniform and consistent in the w/NP/Si 50wt% group. Accordingly, this developed composite resin maintains great mechanical properties after thermal cycling. Thus, it has the potential to be used in a clinical setting when restoring non-carious cervical lesions. Copyright © 2014 Elsevier Ltd. All rights reserved.

  2. Imposed Thermal Fatigue and Post-Thermal-Cycle Wear Resistance of Biomimetic Gray Cast Iron by Laser Treatment

    Science.gov (United States)

    Sui, Qi; Zhou, Hong; Zhang, Deping; Chen, Zhikai; Zhang, Peng

    2017-08-01

    The present study aims to create coupling biomimetic units on gray cast iron substrate by laser surface treatment (LST). LSTs for single-step (LST1) and two-step (LST2) processes, were carried out on gray cast iron in different media (air and water). Their effects on microstructure, thermal fatigue, and post-thermal-cycle wear (PTW) resistance on the specimens were studied. The tests were carried out to examine the influence of crack-resistance behavior as well as the biomimetic surface on its post-thermal-cycle wear behavior and different units, with different laser treatments for comparison. Results showed that LST2 enhanced the PTW behaviors of gray cast iron, which then led to an increase in its crack resistance. Among the treated cast irons, the one treated by LST2 in air showed the lowest residual stress, due to the positive effect of the lower steepness of the thermal gradient. Moreover, the same specimen showed the best PTW performance, due to its superior crack resistance and higher hardness as a result of it.

  3. Optimizing the Environmental Performance of In Situ Thermal Remediation Technologies Using Life Cycle Assessment

    DEFF Research Database (Denmark)

    Lemming, Gitte; Nielsen, Steffen G.; Weber, Klaus

    2013-01-01

    In situ thermal remediation technologies provide efficient and reliable cleanup of contaminated soil and groundwater, but at a high cost of environmental impacts and resource depletion due to the large amounts of energy and materials consumed. This study provides a detailed investigation of four...... in situ thermal remediation technologies (steam enhanced extraction, thermal conduction heating, electrical resistance heating, and radio frequency heating) in order to (1) compare the life-cycle environmental impacts and resource consumption associated with each thermal technology, and (2) identify...... improvements is a 10 to 21% decrease in environmental impacts and an 8 to 20% decrease in resource depletion depending on the thermal remediation technology considered. The energy consumption was found to be the main contributor to most types of environmental impacts; this will, however, depend...

  4. Modelling LiBr-H2O solution concentration/crystallization of low thermal-powered absorption air conditioning system

    International Nuclear Information System (INIS)

    Abdullah, M.O.

    2000-01-01

    A computer model is developed to predict the concentration of lithium bromide - water (LiBr-H 2 O) solution for used in low thermal energy-driven absorption air conditioning plants design. The computer program is capable to alert the users from undesirable solidification or crystallization zones. Good agreements between simulated concentration and experimental data from standard chart/table have been obtained. (Author)

  5. Improved thermal cycling durability and PCR compatibility of polymer coated quantum dot

    International Nuclear Information System (INIS)

    Xun Zhe; Guan Yifu; Zhao Xiaoyun

    2013-01-01

    Quantum dots have experienced rapid development in imaging, labeling and sensing in medicine and life science. To be suitable for polymerase chain reaction (PCR) assay, we have tested QD thermal cycling durability and compatibility, which have not been addressed in previous reports. In this study, we synthesized CdSe/ZnS QDs with a surface modification with high-MW amphiphilic copolymers and observed that Mg 2+ ions in the PCR reaction could induce the QDs to precipitate and reduce their fluorescence signal significantly after thermal cycling. To overcome this problem, we used mPEG2000 to conjugate the QD surface for further protection, and found that this modification enables QDs to endure 40 thermal cycles in the presence of other components essential for PCR reactions. We have also identified that QDs have different effects on rTaq and Ex Taq polymerization systems. A high QD concentration could apparently reduce the PCR efficiency, but this inhibition was relieved significantly in the Ex PCR system as the concentration of Ex Taq polymerase was increased. Real-time PCR amplification results showed that QDs could provide a sufficiently measurable fluorescence signal without excessively inhibiting the DNA amplification. Based on this improved thermal cycling durability and compatibility with the PCR system, QDs have the potential to be developed as stable fluorescent sensors in PCR and real-time PCR amplification. (paper)

  6. Measured thermal and fast neutron fluence rates for ATF-1 holders during ATR cycle 160A

    International Nuclear Information System (INIS)

    Walker, B. J.; Miller, D. T.

    2017-01-01

    This report contains the thermal (2200 m/s) and fast (E>1MeV) neutron fluence rate data for the ATF-1 holders located in core for ATR Cycle 160A which were measured by the Radiation Measurements Laboratory (RML).

  7. 'Crud' detection and evaluation during the Embalse nuclear power plant's thermal cycle for powers of 100%

    International Nuclear Information System (INIS)

    Fernandez, A.; Rosales, A.H.; Mura, V.R.; Sentupery, C.; Rascon, H.

    1987-01-01

    This paper describes the 'crud' measurements performed during the Embalse nuclear power plant's thermal cycle for a power of 100% (645 MWe) under different purification conditions. The aim of this work is to optimize the four steam generators' tube plate cleaning in function of the sweeping produced by their purification. (Author)

  8. Mechanical and thermal cycling effects on the flexural strength of glass ceramics fused to titanium

    NARCIS (Netherlands)

    Vasquez, Vanessa; Ozcan, Mutlu; Nishioka, Renato; Souza, Rodrigo; Mesquita, Alfredo; Pavanelli, Carlos

    This study evaluated the effects of mechanical and thermal cycling on the flexural strength (ISO 9693) of three brands of ceramics fused to commercially pure titanium (cpTi). Metallic frameworks of 25 x 3 x 0.5 mm dimensions (N = 84) were cast in cpTi, followed by 150-mu m aluminum oxide airborne

  9. Observations on thermally cycled 20% Cr/25% Ni/Nb stabilised stainless steel

    International Nuclear Information System (INIS)

    Lobb, R.C.

    1984-06-01

    A variety of optical and electron techniques, such as optical metallography, scanning electron microscopy and electron probe microanalysis, have been used to study the morphology and composition of oxides formed on 20 Cr/25 Ni/Nb stainless steel during oxidation at 850 0 C and subsequent thermal cycling in simulated reactor gas. (author)

  10. A reliability model for interlayer dielectric cracking during fast thermal cycling

    NARCIS (Netherlands)

    Nguyen, Van Hieu; Salm, Cora; Krabbenborg, B.H.; Krabbenborg, B.H.; Bisschop, J.; Mouthaan, A.J.; Kuper, F.G.; Ray, Gary W.; Smy, Tom; Ohta, Tomohiro; Tsujimura, Manabu

    2003-01-01

    Interlayer dielectric (ILD) cracking can result in short circuits of multilevel interconnects. This paper presents a reliability model for ILD cracking induced by fast thermal cycling (FTC) stress. FTC tests have been performed under different temperature ranges (∆T) and minimum temperatures (Tmin).

  11. Measured thermal and fast neutron fluence rates for ATF-1 holders during ATR cycle 160A

    Energy Technology Data Exchange (ETDEWEB)

    Walker, B. J. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Miller, D. T. [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2017-06-06

    This report contains the thermal (2200 m/s) and fast (E>1MeV) neutron fluence rate data for the ATF-1 holders located in core for ATR Cycle 160A which were measured by the Radiation Measurements Laboratory (RML).

  12. Improvement in performance of a direct solar-thermally driven diffusion-absorption refrigerator; Leistungssteigerung einer direkt solarthermisch angetriebenen Diffusions-Absorptionskaeltemaschine

    Energy Technology Data Exchange (ETDEWEB)

    Schmid, Fabian; Bierling, Bernd; Spindler, Klaus [Stuttgart Univ. (Germany). Inst. fuer Thermodynamik und Waermetechnik (ITW)

    2012-07-01

    The diffusion-absorption refrigeration process offers the possibility of a wear-free refrigeration system without electricity and noise. At the Institute for Thermodynamics and Thermal Engineering (Stuttgart, Federal Republic of Germany), a decentralized solar refrigeration system is developed based on this process. The expeller and the thermosiphon pump of this process are integrated in the collector, and thus are heated directly. The diffusion-absorption refrigeration process also can be used for domestic water heating by means of a second cycle in the collector. A cooling capacity of 400 W is to be achieved for each solar collector (2.5 m{sup 2}). Several refrigeration systems can be modular interconnected for higher cooling capacities. As part of the DKV Conference 2011, the construction of the plant, the first measurement data and results were presented. Since then, both the cooling capacity and the coefficient of performance of the diffusion-absorption refrigeration system could be increased significantly. For this, solvent heat exchanger, evaporator, absorber and gas heat exchanger have been optimized in terms of system efficiency. In addition, a stable system operation could be achieved by means of a bypass line. About this line, an exaggerated refrigerant already is removed in the solvent heat exchanger. In addition, a condensate pre-cooler was integrated in order to increase the efficiency. For a detailed investigation of the auxiliary gas cycle facilities, the volume flow and the concentration of the auxiliary gas circuit were examined under utilization of an ultrasonic sensor. In order to evaluate the influence factors by means of a parametric study, the mass transfer in the auxiliary gas circuit was simulated using the two-fluid model. The results of these studies, the current system configuration and the current results are presented in the contribution under consideration.

  13. Performance analysis of an integrated gas-, steam- and organic fluid-cycle thermal power plant

    International Nuclear Information System (INIS)

    Oko, C.O.C.; Njoku, I.H.

    2017-01-01

    This paper presents the performance analysis of an existing combined cycle power plant augmented with a waste heat fired organic Rankine cycle power plant for extra power generation. This was achieved by performing energy and exergy analysis of the integrated gas-, steam- and organic fluid-cycle thermal power plant (IPP). Heat source for the subcritical organic Rankine cycle (ORC) was the exhaust flue gases from the heat recovery steam generators of a 650 MW natural gas fired combined cycle power plant. The results showed that extra 12.4 MW of electricity was generated from the attached ORC unit using HFE7100 as working fluid. To select ORC working fluid, ten isentropic fluids were screened and HFE7100 produced the highest net power output and cycle efficiency. Exergy and energy efficiencies of the IPP improved by 1.95% and 1.93%, respectively. The rate of exergy destruction in the existing combined cycle plant was highest in the combustion chamber, 59%, whereas in the ORC, the highest rate of exergy destruction occurred in the evaporator, 62%. Simulations showed exergy efficiency of the IPP decreased with increasing ambient temperature. Exit stack flue gas temperature reduced from 126 °C in the combined cycle power plant to 100 °C in the integrated power plant. - Highlights: • Combined cycle plant retrofitted with ORC produced extra 12.4 MW electric power. • ORC is powered with low temperature flue gas from an existing combined cycle plant. • Exergy destruction rate in integrated plant(IPP) is less than in combined plant. • Exit stack temperature of the IPP has less environmental thermal pollution. • Exergy and energy efficiencies of the IPP improved by 1.95% and 1.93%, respectively.

  14. Thermal-CFD Analysis of Combined Solar-Nuclear Cycle Systems.

    Energy Technology Data Exchange (ETDEWEB)

    Fathi, Nima [Univ. of New Mexico, Albuquerque, NM (United States); McDaniel, Patrick [Univ. of New Mexico, Albuquerque, NM (United States); Vorobieff, Peter [Univ. of New Mexico, Albuquerque, NM (United States); de Oliveira, Cassiano [Univ. of New Mexico, Albuquerque, NM (United States); Rodriguez, Salvador B. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Aleyasin, Seyed Sobhan [Univ. of Manitoba (Canada)

    2015-09-01

    The aim of this paper is evaluating the efficiency of a novel combined solar-nuclear cycle. CFD-Thermal analysis is performed to apply the available surplus heat from the nuclear cycle and measure the available kinetic energy of air for the turbine of a solar chimney power plant system (SCPPS). The presented idea helps to decrease the thermal pollution and handle the water shortage supply for water plant by replacing the cooling tower by solar chimney power plant to get the surplus heat from the available warm air in the secondary loop of the reactor. By applying this idea to a typical 1000 MW nuclear power plant with a 0.33 thermal efficiency, we can increase it to 0.39.

  15. Development of Thermal Performance Analysis Computer Program on Turbine Cycle of Yoggwang 3,4 Units

    Energy Technology Data Exchange (ETDEWEB)

    Hong, S.Y.; Choi, K.H.; Jee, M.H.; Chung, S.I. [Korea Electric Power Research Institute, Taejon (Korea)

    2002-07-01

    The objective of the study ''Development of Thermal Performance Analysis Computer Program on Turbine Cycle of Yonggwang 3,4 Units'' is to utilize computerized program to the performance test of the turbine cycle or the analysis of the operational status of the thermal plants. In addition, the result can be applicable to the analysis of the thermal output at the abnormal status and be a powerful tool to find out the main problems for such cases. As a results, the output of this study can supply the way to confirm the technical capability to operate the plants efficiently and to obtain the economic gains remarkably. (author). 27 refs., 73 figs., 6 tabs.

  16. Thermal and isothermal low cycle fatigue of MANET I and II

    International Nuclear Information System (INIS)

    Petersen, C.; Schmitt, R.; Garnier, D.

    1996-01-01

    Structural components of a DEMO-blanket are subjected during service to alternating thermal and mechanical stresses as a consequence of the pulsed reactor operation. Of particular concern is the fatigue endurance of martensitic steels like MANET under cyclic strains and stresses produced by these temperature changes. In order to design such structures, operating under combined mechanical and thermal cycling, fatigue life has to be calculated with reasonable accuracy. This paper proposes a description of thermal and isothermal mechanical low-cycle fatigue of MANET I and II steels using a single damage model, including plastic strain, temperature and strain rate as variables. This model presents notable advantages for the designer. As it corresponds to a single and continuous 'fatigue strength surface', it enables a reliable interpolation to be made throughout the studied domain of strains and temperatures, and allows for a reasonable extrapolation out of this domain, provided that no different metallurgical phenomena occur. (orig.)

  17. Finite Element Modeling of Thermal Cycling Induced Microcracking in Carbon/Epoxy Triaxial Braided Composites

    Science.gov (United States)

    Zhang, Chao; Binienda, Wieslaw K.; Morscher, Gregory; Martin, Richard E.

    2012-01-01

    The microcrack distribution and mass change in PR520/T700s and 3502/T700s carbon/epoxy braided composites exposed to thermal cycling was evaluated experimentally. Acoustic emission was utilized to record the crack initiation and propagation under cyclic thermal loading between -55 C and 120 C. Transverse microcrack morphology was investigated using X-ray Computed Tomography. Different performance of two kinds of composites was discovered and analyzed. Based on the observations of microcrack formation, a meso-mechanical finite element model was developed to obtain the resultant mechanical properties. The simulation results exhibited a decrease in strength and stiffness with increasing crack density. Strength and stiffness reduction versus crack densities in different orientations were compared. The changes of global mechanical behavior in both axial and transverse loading conditions were studied. Keywords: Thermal cycles; Microcrack; Finite Element Model; Braided Composite

  18. Transport properties of MnTe films with cracks produced in thermal cycling process

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Liang; Wang, Zhenhua; Zhang, Zhidong [Institute of Metal Research, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Shenyang National Laboratory for Materials Science, Shenyang (China)

    2017-10-15

    As a promising material in antiferromagnetic spintronics, MnTe films manifested complex characteristics according to previous reports. In this work, we investigate in details the temperature dependence of resistivity of MnTe films grown on SiO{sub 2}/Si substrate and focus on the divaricating of cooling and warming resistivity-temperature (R-T) curves. It is found that such a divaricating in resistivity is associated with cracks produced in thermal cycles. By comparing the crystalline character and the morphology before and after the cycles, we verify the appearance of cracks and the release of stress in the films. Based on the temperature dependence of thermal-expansion coefficient of Si and MnTe, the origin of the cracks is the mismatched thermal-expansion coefficient (α). The humps, which only appear in the R-T curve of the first cooling process, are attributed to the produced cracks and/or the unreleased stress. (orig.)

  19. Effects of High Temperature and Thermal Cycling on the Performance of Perovskite Solar Cells: Acceleration of Charge Recombination and Deterioration of Charge Extraction

    KAUST Repository

    Sheikh, Arif D.

    2017-09-18

    In this work, we investigated the effects of high operating temperature and thermal cycling on the photovoltaic performance of perovskite solar cells (PSCs) with a typical mesostructured (m)-TiO2-CH3NH3PbI3-xClx-spiro-OMeTAD architecture. After carrying out temperature-dependent grazing incidence wide-angle X-ray scattering (GIWAXS), in-situ X-ray diffraction (XRD) and optical absorption experiments, thermal durability of PSCs was tested by subjecting the devices to repetitive heating to 70 °C and cooling to room temperature (20 °C). An unexpected regenerative effect was observed after the first thermal cycle; the average power conversion efficiency (PCE) increased by approximately 10 % in reference to the as-prepared device. This increase of PCE was attributed to the heating-induced improvement of crystallinity and p-doping in the hole-transporter, Spiro-OMeTAD, which promotes the efficient extraction of photo-generated carriers. However, further thermal cycles produced a detrimental effect on the photovoltaic performance of PSCs with short-circuit current and fill factor degrading faster than the open-circuit voltage. Similarly, the photovoltaic performance of PSCs degraded at high operation temperatures; both short-circuit current and open-circuit voltage decreased with increasing temperature, but the temperature-dependent trend of fill factor was opposite. Our impedance spectroscopy analysis revealed a monotonous increase of charge transfer resistance and a concurrent decrease of charge recombination resistance with increasing temperature, indicating high recombination of charge carriers. Our results revealed that both thermal cycling and high temperatures produce irreversible detrimental effects on the PSC performance due to the deteriorated interfacial photo-carrier extraction. The present findings suggest that development of robust charge transporters and proper interface engineering are critical for the deployment of perovskite photovoltaics in harsh

  20. Solar panel thermal cycling testing by solar simulation and infrared radiation methods

    Science.gov (United States)

    Nuss, H. E.

    1980-01-01

    For the solar panels of the European Space Agency (ESA) satellites OTS/MAROTS and ECS/MARECS the thermal cycling tests were performed by using solar simulation methods. The performance data of two different solar simulators used and the thermal test results are described. The solar simulation thermal cycling tests for the ECS/MARECS solar panels were carried out with the aid of a rotatable multipanel test rig by which simultaneous testing of three solar panels was possible. As an alternative thermal test method, the capability of an infrared radiation method was studied and infrared simulation tests for the ultralight panel and the INTELSAT 5 solar panels were performed. The setup and the characteristics of the infrared radiation unit using a quartz lamp array of approx. 15 sq and LN2-cooled shutter and the thermal test results are presented. The irradiation uniformity, the solar panel temperature distribution, temperature changing rates for both test methods are compared. Results indicate the infrared simulation is an effective solar panel thermal testing method.

  1. Structural-Phase Transformations of CuZn Alloy Under Thermal-Impact Cycling

    Science.gov (United States)

    Potekaev, A. I.; Chaplygina, A. A.; Kulagina, V. V.; Chaplygin, P. A.; Starostenkov, M. D.; Grinkevich, L. S.

    2017-02-01

    Using the Monte Carlo method, special features of structural - phase transformations in β-brass are investigated during thermal impact using thermal cycling as an example (a number of successive order - disorder and disorder - order phase transitions in the course of several heating - cooling cycles). It is shown that a unique hysteresis is observed after every heating and cooling cycle, whose presence indicates irreversibility of the processes, which suggests a difference in the structural - phase states both in the heating and cooling stages. A conclusion is drawn that the structural - phase transformations in the heating and cooling stages occur within different temperature intervals, where the thermodynamic stimuli of one or the other structural - phase state are low. This is also demonstrated both in the plots of configurational energy, long- and short-range order parameter, atomic structure variations, and structural - phase state distributions. Simultaneously, there coexist ordered and disordered phases and a certain collection of superstructure domains. This implies the presence of low - stability states in the vicinity of the order - disorder phase transition. The results of investigations demonstrate that the structural - phase transitions within two successive heating and cooling cycles at the same temperature are different in both stages. These changes, though not revolutionary, occur in every cycle and decrease with the increasing cycle number. In fact, the system undergoes training with a tendency towards a certain sequence of structural - phase states.

  2. Effect of thermal cycling on martensitic transformation and mechanical strengthening of stainless steels – A phase-field study

    DEFF Research Database (Denmark)

    Yeddu, Hemantha Kumar; Shaw, Brian A.; Somers, Marcel A. J.

    2017-01-01

    A 3D elastoplastic phase-field model is used to study the effect of thermal cycling on martensitic transformationas well as on mechanical strengthening of both austenite and martensite in stainless steel. The results show that with an increasing number of thermal cycles, martensite becomes more...

  3. Preliminary investigation of biological resistance, water absorption and swelling of thermally compressed pine wood panels

    Science.gov (United States)

    Oner Unsal; S. Nami Kartal; Zeki Candan; Rachel Arango; Carol A. Clausen; Frederick Green

    2008-01-01

    Wood can be modified by compressive, thermal and chemical treatments. Compression of wood under thermal conditions is resulted in densification of wood. This study evaluated decay and termite resistance of thermally compressed pine wood panels at either 5 or 7 MPa and at either 120 or 150°C for one hour. The process caused increases in density and decreases in...

  4. Thermal enhancement of charge and discharge cycles for adsorbed natural gas storage

    KAUST Repository

    Rahman, Kazi Afzalur

    2011-07-01

    The usage of adsorbed natural gas (ANG) storage is hindered by the thermal management during the adsorption and desorption processes. An effective thermal enhancement is thus essential for the development of the ANG technology and the motivation for this study is the investigation of a gas storage system with internal thermal control. We employed a fin-tube type heat exchanger that is placed in a pressurized cylinder. A distributed-parameter model is used for the theoretical modeling and simulations are conducted at assorted charging and discharging conditions. These studies included the transient thermal behaviours of the elements within the ANG-charged cylinder and parameters such as pressure and temperature profiles of adsorbent have been obtained during charge and discharge cycles, and results are compared with a conventional compressed methane vessel. © 2011 Elsevier Ltd. All rights reserved.

  5. Thermal Stability of Hexamethyldisiloxane (MM for High-Temperature Organic Rankine Cycle (ORC

    Directory of Open Access Journals (Sweden)

    Markus Preißinger

    2016-03-01

    Full Text Available The design of efficient Organic Rankine Cycle (ORC units for the usage of industrial waste heat at high temperatures requires direct contact evaporators without intermediate thermal oil circuits. Therefore, the thermal stability of high-temperature working fluids gains importance. In this study, the thermal degradation of hexamethyldisiloxane (MM is investigated in an electrically heated tube. Qualitative results concerning remarks on degradation products as well as quantitative results like the annual degradation rate are presented. It is shown that MM is stable up to a temperature of 300 °C with annual degradation rates of less than 3.5%. Furthermore, the break of a silicon–carbon bond can be a main chemical reaction that influences the thermal degradation. Finally, it is discussed how the results may impact the future design of ORC units.

  6. Thermal energy storage for low grade heat in the organic Rankine cycle

    Science.gov (United States)

    Soda, Michael John

    Limits of efficiencies cause immense amounts of thermal energy in the form of waste heat to be vented to the atmosphere. Up to 60% of unrecovered waste heat is classified as low or ultra-low quality, making recovery difficult or inefficient. The organic Rankine cycle can be used to generate mechanical power and electricity from these low temperatures where other thermal cycles are impractical. A variety of organic working fluids are available to optimize the ORC for any target temperature range. San Diego State University has one such experimental ORC using R245fa, and has been experimenting with multiple expanders. One limitation of recovering waste heat is the sporadic or cyclical nature common to its production. This inconsistency makes sizing heat recovery ORC systems difficult for a variety of reasons including off-design-point efficiency loss, increased attrition from varying loads, unreliable outputs, and overall system costs. Thermal energy storage systems can address all of these issues by smoothing the thermal input to a constant and reliable level and providing back-up capacity for times when the thermal input is deactivated. Multiple types of thermal energy storage have been explored including sensible, latent, and thermochemical. Latent heat storage involves storing thermal energy in the reversible phase change of a phase change material, or PCM, and can have several advantages over other modalities including energy storage density, cost, simplicity, reliability, relatively constant temperature output, and temperature customizability. The largest obstacles to using latent heat storage include heat transfer rates, thermal cycling stability, and potentially corrosive PCMs. Targeting 86°C, the operating temperature of SDSU's experimental ORC, multiple potential materials were explored and tested as potential PCMs including Magnesium Chloride Hexahydrate (MgCl2˙6H2O), Magnesium Nitrate Hexahydrate (Mg(NO3)2˙6H 2O), montan wax, and carnauba wax. The

  7. Failure Mechanisms of SAC/Fe-Ni Solder Joints During Thermal Cycling

    Science.gov (United States)

    Gao, Li-Yin; Liu, Zhi-Quan; Li, Cai-Fu

    2017-08-01

    Thermal cycling tests have been conducted on Sn-Ag-Cu/Fe- xNi ( x = 73 wt.% or 45 wt.%) and Sn-Ag-Cu/Cu solder joints according to the Joint Electron Device Engineering Council industrial standard to study their interfacial reliability under thermal stress. The interfacial intermetallic compounds formed for solder joints on Cu, Fe-73Ni, and Fe-45Ni were 4.5 μm, 1.7 μm, and 1.4 μm thick, respectively, after 3000 cycles, demonstrating excellent diffusion barrier effect of Fe-Ni under bump metallization (UBM). Also, two deformation modes, viz. solder extrusion and fatigue crack formation, were observed by scanning electron microscopy and three-dimensional x-ray microscopy. Solder extrusion dominated for solder joints on Cu, while fatigue cracks dominated for solder joints on Fe-45Ni and both modes were detected for those on Fe-73Ni. Solder joints on Fe-Ni presented inferior reliability during thermal cycling compared with those on Cu, with characteristic lifetime of 3441 h, 3190 h, and 1247 h for Cu, Fe-73Ni, and Fe-45Ni UBM, respectively. This degradation of the interfacial reliability for solder joints on Fe-Ni is attributed to the mismatch in coefficient of thermal expansion (CTE) at interconnection level. The CTE mismatch at microstructure level was also analyzed by electron backscatter diffraction for clearer identification of recrystallization-related deformation mechanisms.

  8. Re-austenitisation of chromium-bearing pressure vessel steels during the weld thermal cycle

    International Nuclear Information System (INIS)

    Dunne, Druce; Li, Huijun; Jones, Christopher

    2013-01-01

    Steels with chromium contents between 0.5 and 12 wt% are commonly used for fabrication of creep resistant pressure vessels (PV) for the power generation industry. Most of these steels are susceptible to Type IV creep failure in the intercritical and/ or grain refined regions of the heat affected zone (HAZ) of the parent metal. The re-austenitisation process plays a central role in establishing the transformed microstructures and the creep resistance of the various sub-zones of the HAZ. The high alloy content and the presence of alloy-rich carbides in the as-supplied parent plate can significantly retard the kinetics of transformation to austenite, resulting in both incomplete austenitisation and inhomogeneous austenite. Overlapping weld thermal cycles in multi-pass welds add further complexity to the progressive development of microstructure over the course of the welding process. In order to clarify structural evolution, thermal simulation has been used to study the effects of successive thermal cycles on the structures and properties of the HAZ of 2.25Cr-1Mo steel. The results showed that, before post-weld heat treatment (PWHT), the HAZ microstructures and properties, particularly in doubly reheated sub-zones, were highly heterogeneous and differed markedly from those of the base steel. It is concluded that close control of the thermal cycle by pre-heat, weld heat input and post-heat is necessary to obtain a heat affected zone with microstructures and properties compatible with those of the base plate.

  9. Thermally Induced Ultra High Cycle Fatigue of Copper Alloys of the High Gradient Accelerating Structures

    CERN Document Server

    Heikkinen, Samuli; Wuensch, Walter

    2010-01-01

    In order to keep the overall length of the compact linear collider (CLIC), currently being studied at the European Organization for Nuclear Research (CERN), within reasonable limits, i.e. less than 50 km, an accelerating gradient above 100 MV/m is required. This imposes considerable demands on the materials of the accelerating structures. The internal surfaces of these core components of a linear accelerator are exposed to pulsed radio frequency (RF) currents resulting in cyclic thermal stresses expected to cause surface damage by fatigue. The designed lifetime of CLIC is 20 years, which results in a number of thermal stress cycles of the order of 2.33•1010. Since no fatigue data existed in the literature for CLIC parameter space, a set of three complementary experiments were initiated: ultra high cycle mechanical fatigue by ultrasound, low cycle fatigue by pulsed laser irradiation and low cycle thermal fatigue by high power microwaves, each test representing a subset of the original problem. High conductiv...

  10. Weldability examination of ASTM A 240 S41500 martensitic stainless steel by thermal cycles simulation testings

    Directory of Open Access Journals (Sweden)

    Alberto Velázquez-del Rosario

    2015-07-01

    Full Text Available The weldability assets of ASTM A 240 S41500 (ASTM A 240/A 240M martensitic stainless steel are presented through the study of the effects of single and double thermal weld cycles on mechanical properties and microstructure of base metal (BM and the artificial heat affected zone (HAZ created by thermal weld simulations. For single cycles, separate peak temperatures of 1000 ºC/12 s and 1350 ºC/12 s (cooling times: 12 s in both cases were evaluated, whilst two combinations of peak temperatures: (1350 ºC/5 s + 1000 ºC/5 s ºC and (1350 ºC/12 s + 1000 ºC/12 s ºC (cooling times: 5 s and 12 s, were applied for double cycles. Post weld heat treatment (PWHT with short and long holding times were applied and Vickers hardness, impact toughness and metallographic examinations were used in order to assess mechanical and metallographic properties in the as-simulated (no heat treated and postweld heat treated conditions. Best properties of the welded joint for double thermal weld cycles with long holding times were reached, which reveals the good weldability and applicability of the tested material in post weld heat treated conditions.

  11. Optical absorption study of radiation and thermal effects in Brazilian samples of spodumene

    International Nuclear Information System (INIS)

    Isotani, S.; Fujii, A.T.; Antonini, R.; Furtado, W.

    1988-03-01

    A detailed analysis of the optical absorption spectra of five varieties of Brazilian spodumene is presented. The samples were submitted to heat treatments and irradiated with gamma rays, x radiation, electrons and ultraviolet light. (M.C.K.) [pt

  12. Thermal modelling of Li-ion polymer battery for electric vehicle drive cycles

    Science.gov (United States)

    Chacko, Salvio; Chung, Yongmann M.

    2012-09-01

    Time-dependent, thermal behaviour of a lithium-ion (Li-ion) polymer cell has been modelled for electric vehicle (EV) drive cycles with a view to developing an effective battery thermal management system. The fully coupled, three-dimensional transient electro-thermal model has been implemented based on a finite volume method. To support the numerical study, a high energy density Li-ion polymer pouch cell was tested in a climatic chamber for electric load cycles consisting of various charge and discharge rates, and a good agreement was found between the model predictions and the experimental data. The cell-level thermal behaviour under stressful conditions such as high power draw and high ambient temperature was predicted with the model. A significant temperature increase was observed in the stressful condition, corresponding to a repeated acceleration and deceleration, indicating that an effective battery thermal management system would be required to maintain the optimal cell performance and also to achieve a full battery lifesapn.

  13. Framing the performance of heat absorption/generation and thermal radiation in chemically reactive Darcy-Forchheimer flow

    Directory of Open Access Journals (Sweden)

    T. Hayat

    Full Text Available The present work aims to report the consequences of heterogeneous-homogeneous reactions in Darcy-Forchheimer flow of Casson material bounded by a nonlinear stretching sheet of variable thickness. Nonlinear stretched surface with variable thickness is the main agent for MHD Darcy-Forchheimer flow. Impact of thermal radiation and non-uniform heat absorption/generation are also considered. Flow in porous space is characterized by Darcy-Forchheimer flow. It is assumed that the homogeneous process in ambient fluid is governed by first order kinetics and the heterogeneous process on the wall surface is given by isothermal cubic autocatalator kinetics. The governing nonlinear ordinary differential equations are solved numerically. Effects of physical variables such as thickness, Hartman number, inertia and porous, radiation, Casson, heat absorption/generation and homogeneous-heterogeneous reactions are investigated. The variations of drag force (skin friction and heat transfer rate (Nusselt numberfor different interesting variables are plotted and discussed. Keywords: Casson fluid, Variable sheet thickness, Darcy-Forchheimer flow, Homogeneous-heterogeneous reactions, Heat generation/absorption, Thermal radiation

  14. A novel Carnot-based cycle for ocean thermal energy conversion

    International Nuclear Information System (INIS)

    Semmari, Hamza; Stitou, Driss; Mauran, Sylvain

    2012-01-01

    A thermodynamic engine cycle can be implemented by exploiting the temperature difference existing between the warm surface seawater and cold deep seawater. It employs a working fluid that evaporates by warm seawater, produces work in an expander device, such as a gas turbine and finally condenses by cold deep seawater. A new Carnot-based cycle for OTEC applications, called CAPILI cycle is presented. In this new engine cycle, work is produced by the movement of an inert liquid through a hydraulic turbine. This inert liquid characterized by a very low saturation pressure and immiscibility with the working fluid, acts as a liquid piston that moves alternately between two insulated cylinders. The insulated cylinders are connected alternately to an evaporator and a condenser, each of them operates at different pressure and temperature levels. A performance study which consists in a steady state energy balance is realised first to select the most suitable working fluid for this specific application. It was found that the best fluid is the HFC refrigerant R134a. A dynamic modelling based on the concept of equivalent Gibbs system is carried out to appreciate the dynamic behaviour and the performances of this new thermal conversion process. -- Highlights: ► A novel Carnot-based cycle operating with a liquid piston is investigated for OTEC application. ► The most suitable working fluid giving the best performances is found to be the HFC R134a. ► The performances of this new thermal process are evaluated using a dynamic modelling. ► A thermal efficiency of 1.9% can be obtained by exploiting seawater temperature difference of 20 °C. ► A net cycle efficiency of 1.2% is achieved considering a net to gross power production ratio of 61%.

  15. Martensitic transformation in an intergranular corrosion area of austenitic stainless steel during thermal cycling

    International Nuclear Information System (INIS)

    La Fontaine, Alexandre; Yen, Hung-Wei; Trimby, Patrick; Moody, Steven; Miller, Sarah; Chensee, Martin; Ringer, Simon; Cairney, Julie

    2014-01-01

    An oxidation-assisted martensitic phase transformation was observed in an austenitic stainless steel after thermal cycling up to 970 °C in air in a solar thermal steam reformer. The intergranular corrosion areas were investigated by electron backscatter diffraction (EBSD), transmission Kikuchi diffraction (TKD) and transmission electron microscopy (TEM). The structural-and-chemical maps revealed that within intergranular corrosion areas this martensitic transformation primarily occurs in oxidation-induced chromium-depleted zones, rather than due to only sensitization. This displacive transformation may also play a significant role in the rate at which intergranular corrosion takes place

  16. Thermal analysis of heat and power plant with high temperature reactor and intermediate steam cycle

    Directory of Open Access Journals (Sweden)

    Fic Adam

    2015-03-01

    Full Text Available Thermal analysis of a heat and power plant with a high temperature gas cooled nuclear reactor is presented. The main aim of the considered system is to supply a technological process with the heat at suitably high temperature level. The considered unit is also used to produce electricity. The high temperature helium cooled nuclear reactor is the primary heat source in the system, which consists of: the reactor cooling cycle, the steam cycle and the gas heat pump cycle. Helium used as a carrier in the first cycle (classic Brayton cycle, which includes the reactor, delivers heat in a steam generator to produce superheated steam with required parameters of the intermediate cycle. The intermediate cycle is provided to transport energy from the reactor installation to the process installation requiring a high temperature heat. The distance between reactor and the process installation is assumed short and negligable, or alternatively equal to 1 km in the analysis. The system is also equipped with a high temperature argon heat pump to obtain the temperature level of a heat carrier required by a high temperature process. Thus, the steam of the intermediate cycle supplies a lower heat exchanger of the heat pump, a process heat exchanger at the medium temperature level and a classical steam turbine system (Rankine cycle. The main purpose of the research was to evaluate the effectiveness of the system considered and to assess whether such a three cycle cogeneration system is reasonable. Multivariant calculations have been carried out employing the developed mathematical model. The results have been presented in a form of the energy efficiency and exergy efficiency of the system as a function of the temperature drop in the high temperature process heat exchanger and the reactor pressure.

  17. Heat dissipation by blood circulation and airway tissue heat absorption in a canine model of inhalational thermal injury.

    Science.gov (United States)

    Wan, Jiangbo; Zhang, Guoan; Qiu, Yuxuan; Wen, Chunquan; Fu, Tairan

    2016-05-01

    This study aimed to further explore heat dissipation by blood circulation and airway tissue heat absorption in an inhalational thermal injury model. Twelve adult male Beagle dogs were divided into four groups to inhale heated air for 10min: the control group, group I (100.5°C), group II (161.5°C), and group III (218°C). The relative humidity and temperature of the inhaled heated air were measured in the heating tube and trachea, as were blood temperatures and flow velocities in both common jugular veins. Formulas were used to calculate the total heat quantity reduction of the heated air, heat dissipation by the blood, and airway tissue heat absorption. The blood temperatures of both the common jugular veins increased by 0.29°C±0.07°C to 2.96°C±0.24°C and the mean blood flow volume after injury induction was about 1.30-1.74 times greater than before injury induction. The proportions of heat dissipated by the blood and airway tissue heat absorption were 68.92%±14.88% and 31.13%±14.87%, respectively. The heat dissipating ability of the blood circulation was demonstrated and improved upon along with tissue heat absorption owing to increased regional blood flow. Copyright © 2015 Elsevier Ltd and ISBI. All rights reserved.

  18. Multispecies breath analysis faster than a single respiratory cycle by optical-feedback cavity-enhanced absorption spectroscopy

    Science.gov (United States)

    Ventrillard-Courtillot, Irene; Gonthiez, Thierry; Clerici, Christine; Romanini, Daniel

    2009-11-01

    We demonstrate a first application, of optical-feedback cavity-enhanced absorption spectroscopy (OF-CEAS) to breath analysis in a medical environment. Noninvasive monitoring of trace species in exhaled air was performed simultaneous to spirometric measurements on patients at Bichat Hospital (Paris). The high selectivity of the OF-CEAS spectrometer and a time response of 0.3 s (limited by sample flow rate) allowed following the evolution of carbon monoxide and methane concentrations during individual respiratory cycles, and resolving variations among different ventilatory patterns. The minimum detectable absorption on this time scale is about 3×10-10 cm-1. At the working wavelength of the instrument (2.326 μm), this translates to concentration detection limits of ~1 ppbv (45 picomolar, or ~1.25 μg/m3) for CO and 25 ppbv for CH4, well below concentration values found in exhaled air. This same instrument is also able to provide measurement of NH3 concentrations with a detection limit of ~10 ppbv however, at present, memory effects do not allow its measurement on fast time scales.

  19. One-step fabrication of submicrostructures by low one-photon absorption direct laser writing technique with local thermal effect

    Science.gov (United States)

    Nguyen, Dam Thuy Trang; Tong, Quang Cong; Ledoux-Rak, Isabelle; Lai, Ngoc Diep

    2016-01-01

    In this work, local thermal effect induced by a continuous-wave laser has been investigated and exploited to optimize the low one-photon absorption (LOPA) direct laser writing (DLW) technique for fabrication of polymer-based microstructures. It was demonstrated that the temperature of excited SU8 photoresist at the focusing area increases to above 100 °C due to high excitation intensity and becomes stable at that temperature thanks to the use of a continuous-wave laser at 532 nm-wavelength. This optically induced thermal effect immediately completes the crosslinking process at the photopolymerized region, allowing obtain desired structures without using the conventional post-exposure bake (PEB) step, which is usually realized after the exposure. Theoretical calculation of the temperature distribution induced by local optical excitation using finite element method confirmed the experimental results. LOPA-based DLW technique combined with optically induced thermal effect (local PEB) shows great advantages over the traditional PEB, such as simple, short fabrication time, high resolution. In particular, it allowed the overcoming of the accumulation effect inherently existed in optical lithography by one-photon absorption process, resulting in small and uniform structures with very short lattice constant.

  20. Radiation and Thermal Cycling Effects on EPC1001 Gallium Nitride Power Transistors

    Science.gov (United States)

    Patterson, Richard L.; Scheick, Leif Z.; Lauenstein, Jean M.; Casey, Megan C.; Hammoud, Ahmad

    2012-01-01

    Electronics designed for use in NASA space missions are required to work efficiently and reliably under harsh environment conditions. These include radiation, extreme temperatures, and thermal cycling, to name a few. Information pertaining to performance of electronic parts and systems under hostile environments is very scarce, especially for new devices. Such data is very critical so that proper design is implemented in order to ensure mission success and to mitigate risks associated with exposure of on-board systems to the operational environment. In this work, newly-developed enhancement-mode field effect transistors (FET) based on gallium nitride (GaN) technology were exposed to various particles of ionizing radiation and to long-term thermal cycling over a wide temperature range. Data obtained on control (un-irradiated) and irradiated samples of these power transistors are presented and the results are discussed.

  1. An integrated solar thermal power system using intercooled gas turbine and Kalina cycle

    International Nuclear Information System (INIS)

    Peng, Shuo; Hong, Hui; Jin, Hongguang; Wang, Zhifeng

    2012-01-01

    A new solar tower thermal power system integrating the intercooled gas turbine top cycle and the Kalina bottoming cycle is proposed in the present paper. The thermodynamic performance of the proposed system is investigated, and the irreversibility of energy conversion is disclosed using the energy–utilization diagram method. On the top cycle of the proposed system, the compressed air after being intercooled is heated at 1000 °C or higher at the solar tower receiver and is used to drive the gas turbine to generate power. The ammonia–water mixture as the working substance of the bottom cycle recovers the waste heat from the gas turbine to generate power. A concise analytical formula of solar-to-electric efficiency of the proposed system is developed. As a result, the peak solar-to-electric efficiency of the proposed system is 27.5% at a gas turbine inlet temperature of 1000 °C under the designed solar direct normal irradiance of 800 W/m 2 . Compared with a conventional solar power tower plant, the proposed integrated system conserves approximately 69% of consumed water. The results obtained in the current study provide an approach to improve solar-to-electric efficiency and offer a potential to conserve water for solar thermal power plants in arid area. -- Highlights: ► An Integrated Solar Thermal Power System is modeled. ► A formula forecasting the thermodynamic performance is proposed. ► The irreversibility of energy conversion is disclosed using an energy utilization method. ► The effect of key operational parameters on thermal performance is examined.

  2. Decay and termite resistance, water absorption and swelling of thermally compressed wood panels

    Science.gov (United States)

    Oner Unsal; S. Nami Kartal; Zeki Candan; Rachel A. Arango; Carol A. Clausen; Frederick Green

    2009-01-01

    This study evaluated decay and termite resistance of thermally compressed pine wood panels under pressure at either 5 or 7 MPa and either 120 or 150 °C for 1 h. Wood specimens from the panels were exposed to laboratory decay resistance by using the wood degrading fungi, Gloeophyllum trabeum and Trametes versicolor. The thermal compression process caused increases in...

  3. Thermal Cycling and High-Temperature Corrosion Tests of Rare Earth Silicate Environmental Barrier Coatings

    Science.gov (United States)

    Darthout, Émilien; Gitzhofer, François

    2017-12-01

    Lutetium and yttrium silicates, enriched with an additional secondary zirconia phase, environmental barrier coatings were synthesized by the solution precursor plasma spraying process on silicon carbide substrates. A custom-made oven was designed for thermal cycling and water vapor corrosion testing. The oven can test four specimens simultaneously and allows to evaluate environmental barrier performances under similar corrosion kinetics compared to turbine engines. Coatings structural evolution has been observed by SEM on the polished cross sections, and phase composition has been analyzed by XRD. All coatings have been thermally cycled between 1300 °C and the ambient temperature, without spallation, due to their porosity and the presence of additional secondary phase which increases the thermal cycling resistance. During water vapor exposure at 1200 °C, rare earth disilicates showed a good stability, which is contradictory with the literature, due to impurities—such as Si- and Al-hydroxides—in the water vapor jets. The presence of vertical cracks allowed the water vapor to reach the substrate and then to corrode it. It has been observed that thin vertical cracks induced some spallation after 24 h of corrosion.

  4. Thermal Cycle Reliability and Failure Mechanisms of CCGA and PBGA Assemblies with and without Corner Staking

    Science.gov (United States)

    Ghaffarian, Reza

    2008-01-01

    Area array packages (AAPs) with 1.27 mm pitch have been the packages of choice for commercial applications; they are now starting to be implemented for use in military and aerospace applications. Thermal cycling characteristics of plastic ball grid array (PBGA) and chip scale package assemblies, because of their wide usage for commercial applications, have been extensively reported on in literature. Thermal cycling represents the on-off environmental condition for most electronic products and therefore is a key factor that defines reliability.However, very limited data is available for thermal cycling behavior of ceramic packages commonly used for the aerospace applications. For high reliability applications, numerous AAPs are available with an identical design pattern both in ceramic and plastic packages. This paper compares assembly reliability of ceramic and plastic packages with the identical inputs/outputs(I/Os) and pattern. The ceramic package was in the form of ceramic column grid array (CCGA) with 560 I/Os peripheral array with the identical pad design as its plastic counterpart.

  5. Endurance of lead-free assembly under board level drop test and thermal cycling

    Energy Technology Data Exchange (ETDEWEB)

    Xia Yanghua [State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050 (China)], E-mail: xia_yanghua@hotmail.com; Xie Xiaoming [State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050 (China)

    2008-06-12

    The reliability of lead-free electronic assemblies under board level drop test and thermal cycling was investigated. TSOP (thin small outline package) devices with FeNi leads were reflow soldered on FR4 PCB (printed circuit board) with Sn3.0Ag0.5Cu (wt%) solder. The effects of different PCB finishes (organic solderability preservative (OSP) and electroless nickel immersion gold (ENIG)) on the reliability performance were studied. The results show that the assemblies with ENIG finishes reveal better reliability performance than its OSP counterparts under drop test, however, the OSP samples outperform those with ENIG finishes under thermal cycling. The failure mechanism is different under these two test conditions: the solder joints fracture into the intermetallic compounds (IMCs) layer under drop test, and cracks initiate in the bulk solder under thermal cycling. The surface finishes have an effect on the failure mode. The propagation of crack in the ENIG case is along the device/solder interface, while in the case of OSP, the crack extends parallel to the solder/PCB interface.

  6. Sensitivity of LWR fuel cycle costs to uncertainties in detailed thermal cross sections

    International Nuclear Information System (INIS)

    Ryskamp, J.M.; Becker, M.; Harris, D.R.

    1979-01-01

    Cross sections averaged over the thermal energy (< 1 or 2 eV) group have been shown to have an important economic role for light-water reactors. Cost implications of thermal cross section uncertainties at the few-group level were reported earlier. When it has been determined that costs are sensitive to a specific thermal-group cross section, it becomes desirable to determine how specific energy-dependent cross sections influence fuel cycle costs. Multigroup cross-section sensitivity coefficients vary with fuel exposure. By changing the shape of a cross section displayed on a view-tube through an interactive graphics system, one can compute the change in few-group cross section using the exposure dependent sensitivity coefficients. With the changed exposure dependent few-group cross section, a new fuel cycle cost is computed by a sequence of batch depletion, core analysis, and fuel batch cost code modules. Fuel cycle costs are generally most sensitive to cross section uncertainties near the peak of the hardened Maxwellian flux

  7. Determination of the thermal neutron absorption cross section for rock samples by a single measurement of the time decay constant

    International Nuclear Information System (INIS)

    Krynicka, E.

    1993-01-01

    A calibration method for the determination of the thermal neutron macroscopic mass absorption cross section for rock samples is presented. The standard deviation of the final results is discussed in detail. A big advantage of the presented method is that the calibration curves have been found using the results obtained for a variety of natural rock samples of different stratigraphies and lithologies measured by Czubek's methods. An important part of the paper is a through analysis of the standard deviation of the final result. (author). 13 refs, 11 figs, 5 tabs

  8. Measured Thermal and Fast Neutron Fluence Rates for ATF-1 Holders During ATR Cycle 157D

    Energy Technology Data Exchange (ETDEWEB)

    Smith, Larry Don [Idaho National Lab. (INL), Idaho Falls, ID (United States); Miller, David Torbet [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2016-03-01

    This report contains the thermal (2200 m/s) and fast (E>1MeV) neutron fluence rate data for the ATF-1 holders located in core for ATR Cycle 157D which were measured by the Radiation Measurements Laboratory (RML) as requested by the Power Reactor Programs (ATR Experiments) Radiation Measurements Work Order. This report contains measurements of the fluence rates corresponding to the particular elevations relative to the 80-ft. core elevation. The data in this report consist of (1) a table of the ATR power history and distribution, (2) a hard copy listing of all thermal and fast neutron fluence rates, and (3) plots of both the thermal and fast neutron fluence rates. The fluence rates reported are for the average power levels given in the table of power history and distribution.

  9. Improvement of chemical control in the water-steam cycle of thermal power plants

    International Nuclear Information System (INIS)

    Rajakovic-Ognjanovic, Vladana N.; Zivojinovic, Dragana Z.; Grgur, Branimir N.; Rajakovic, Ljubinka V.

    2011-01-01

    A more effective chemical control in the water-steam cycle (WSC) of thermal power plants (TPP) is proposed in this paper. Minimization of corrosion effects by the production of ultra pure water and its strict control is the basis of all the investigated processes. The research involved the analysis of water samples in the WSC through key water quality parameters and by the most convenient analytical tools. The necessity for the stricter chemical control is demonstrated through a concrete example of the TPP Nikola Tesla, Serbia. After a thorough analysis of the chemical control system of the WSC, diagnostic and control parameters were chosen for continuous systematic measurements. Sodium and chloride ions were recognized as the ions which indicate the corrosion potential of the water and give insight into the proper production and maintenance of water within the WSC. Chemical transformations of crucial corrosion elements, iron and silica, were considered and related to their quantitative values. - Research highlights: → The more effective chemical control in the water-steam cycle of thermal power plant Nikola Tesla, Serbia. → In chemical control the diagnostic and control parameters were optimized and introduced for the systematic measurements in the water-steam cycle. → Sodium and chloride ions were recognized as ions which indicate corrosion potential of water and give insight to proper function of production and maintenance of water within water-team cycle. → Chemical transformations of crucial corrosion elements, iron and silica are considered and related with their quantitative values.

  10. Numerical Simulation Procedure for Modeling TGO Crack Propagation and TGO Growth in Thermal Barrier Coatings upon Thermal-Mechanical Cycling

    Directory of Open Access Journals (Sweden)

    Ding Jun

    2014-01-01

    Full Text Available This paper reports a numerical simulation procedure to model crack propagation in TGO layer and TGO growth near a surface groove in metal substrate upon multiple thermal-mechanical cycles. The material property change method is employed to model TGO formation cycle by cycle, and the creep properties for constituent materials are also incorporated. Two columns of repeated nodes are placed along the interface of the potential crack, and these nodes are bonded together as one node at a geometrical location. In terms of critical crack opening displacement criterion, onset of crack propagation in TGO layer has been determined by finite element analyses in comparison with that without predefined crack. Then, according to the results from the previous analyses, the input values for the critical failure parameters for the subsequent analyses can be decided. The robust capabilities of restart analysis in ABAQUS help to implement the overall simulation for TGO crack propagation. The comparison of the TGO final deformation profile between numerical and experimental observation shows a good agreement indicating the correctness and effectiveness of the present procedure, which can guide the prediction of the failure in TGO for the future design and optimization for TBC system.

  11. Microstructure analysis and damage patterns of thermally cycled Ti–49.7Ni (at.%) wires

    International Nuclear Information System (INIS)

    Karhu, Marjaana; Lindroos, Tomi

    2012-01-01

    Long-term behaviour and fatigue endurance are the key issues in the utilization of SMA actuators, but systematic research work is still needed in this field. This study concentrates on the effects of three major design parameters on the long-term behaviour of binary Ti–49.7Ni-based actuators: the effect of the temperature interval used on thermal cycling, the effect of the stress level used and the effect of the heat-treatment state of the wire used. The long-term behaviour of the wires was studied in a custom-built fatigue test frame in which the wires were thermally cycled under a constant stress level. Before the fatigue testing, a series of heat treatments was carried out to generate optimal actuator properties for the wires. This paper concentrates on the systematic fractographic analysis of the fatigue fractured Ti–49.7Ni wires. The aim was to discover the relationships between the macro-scale behaviour and the microstructural changes of the material. During thermal cycling the surfaces of the Ti–49.7Ni wires were examined with an optical microscope. Clear connections between the detected surface defects and fracture nucleation sites were not established. Multiple cracks were initiated and grew during thermal cycling. SEM examinations showed that the fracture surfaces can be divided into different and separate zones: a smooth surface region with radial marks indicating the fatigue crack propagation area, a rougher ductile fracture surface region area and the roughest surface region on the interface of these two surfaces. It was detected that the size of the crack propagation area is related to the fatigue lives of the thermally cycled wires. Surface cracking and subsequent crack growth proved to be responsible for the accumulation of fatigue damage in the studied wires. It was detected from the fracture surface cross-sections that cracks were not initiated at the oxide layer. The major factor for nucleating the surface cracking and then shortening the

  12. The direct determination of HgS by thermal desorption coupled with atomic absorption spectrometry

    Czech Academy of Sciences Publication Activity Database

    Coufalík, Pavel; Zvěřina, O.; Komárek, J.

    2016-01-01

    Roč. 118, APR (2016), s. 1-5 ISSN 0584-8547 Institutional support: RVO:68081715 Keywords : mercury * HgS * thermal desorption Subject RIV: CB - Analytical Chemistry, Separation Impact factor: 3.241, year: 2016

  13. Molecular Entropy, Thermal Efficiency, and Designing of Working Fluids for Organic Rankine Cycles

    Science.gov (United States)

    Wang, Jingtao; Zhang, Jin; Chen, Zhiyou

    2012-06-01

    A shortage of fossil energy sources boosts the utilization of renewable energy. Among numerous novel techniques, recovering energy from low-grade heat sources through power generation via organic Rankine cycles (ORCs) is one of the focuses. Properties of working fluids are crucial for the ORC's performance. Many studies have been done to select proper working fluids or to design new working fluids. However, no researcher has systematically investigated the relationship between molecular structures and thermal efficiencies of various working fluids for an ideal ORC. This paper has investigated the interrelations of molecular structures, molecular entropies, and thermal efficiencies of various working fluids for an ideal ORC. By calculating thermal efficiencies and molecular entropies, we find that the molecular entropy is the most appropriate thermophysical property of a working fluid to determine how much energy can be converted into work and how much cannot in a system. Generally speaking, working fluids with low entropies will generally have high thermal efficiency for an ideal ORC. Based on this understanding, the direct interrelations of molecular structures and entropies provide an explicit interrelation between molecular structures and thermal efficiencies, and thus provide an insightful direction for molecular design of novel working fluids for ORCs.

  14. Adaptability of Brayton cycle conversion systems to fast, epithermal and thermal spectrum space nuclear reactors

    International Nuclear Information System (INIS)

    Tilliette, Z.P.

    1988-01-01

    The two French Government Agencies C.N.E.S. (Centre National d'Etudes Spatiales) and C.E.A. (Commissariat a l'Energie Atomique) are carrying out joint preliminary studies on space nuclear power systems for future ARIANE 5 launch vehicle applications. The Brayton cycle is the reference conversion system, whether the heat source is a liquid metal-cooled (NaK, Na or Li) reactor or a gas-cooled direct cycle concept. The search for an adequate utilization of this energy conversion means has prompted additional evaluations featuring the definition of satisfactory cycle conditions for these various kinds of reactor concepts. In addition to firstly studied fast and epithermal spectrum ones, thermal spectrum reactors can offer an opportunity of bringing out some distinctive features of the Brayton cycle, in particular for the temperature conditioning of the efficient metal hydrides (ZrH, Li/sub 7/H) moderators. One of the purposes of the paper is to confirm the potential of long lifetime ZrH moderated reactors associated with a gas cycle and to assess the thermodynamical consequences for both Nak(Na)-cooled or gas-cooled nuclear heat sources. This investigation is complemented by the definition of appropriate reactor arrangements which could be presented on a further occasion

  15. Data on thermal conductivity, water vapour permeability and water absorption of a cementitious mortar containing end-of-waste plastic aggregates

    OpenAIRE

    Di Maio, Luciano; Coppola, Bartolomeo; Courard, Luc; Michel, Frédéric; Incarnato, Loredana; Scarfato, Paola

    2018-01-01

    The data presented in this article are related to the research article entitled “Hygro-thermal and durability properties of a lightweight mortar made with foamed plastic waste aggregates ” (Coppola et al., 2018). This article focuses the attention on thermal conductivity, water vapour permeability and water absorption of a lightweight cementitious mortar containing foamed end-of-waste plastic aggregates, produced via foam extrusion process. Thermal conductivity, water vapour permeability ...

  16. Design of absorption system water-ammonia by using solar radiation as thermal source

    Energy Technology Data Exchange (ETDEWEB)

    Cavalcanti, Eduardo J. Cidade; Souza, Luiz Guilherme Meira [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil). Centro de Tecnlogia. Dept. de Engenharia Mecanica], E-mails: educanti@gmail.com, lguilherme@dem.ufrn.br

    2010-07-01

    An absorption refrigeration system with the single effect of par ammonia water with 1.758 kW (1 / 2 RT) cooling capacity was designed. The system was operating under conditions of 5 degree C evaporation and 45 degree C condensation temperature. The absorption system has a heat exchanger to improve performance. The heat source is the cylinder parabolic solar concentrator (CPC). The design of the concentrator was estimated based on experimental data of the pilot plant built in the Solar Energy Laboratory, Federal University of Rio Grande do Norte. The thermodynamic model with heat and mass transfer was made to the project areas of heat exchange (absorber) and consequent construction of the system. The rectifying column was modeling assuming that liquid is in equilibrium with the vapor state in all plate. The results should show the dimensions of the compact and allows a future assessment of the operational cost. (author)

  17. A liquid-He cryostat for structural and thermal disorder studies by X-ray absorption.

    Science.gov (United States)

    Bouamrane, F; Ribbens, M; Fonda, E; Adjouri, C; Traverse, A

    2003-07-01

    A new device operating from 4.2 to 300 K is now installed on the hard X-ray station of the DCI ring in LURE in order to measure absorption coefficients. This liquid-He bath device has three optical windows. One allows the incident beam to impinge on the sample, one located at 180 degrees with respect to the sample allows transmitted beams to be detected, and another located at 90 degrees is used to detect emitted photons. Total electron yield detection mode is also possible thanks to a specific sample holder equipped with an electrode that collects the charges created by the emitted electrons in the He gas brought from the He bath around the sample. The performance of the cryostat is described by measurements of the absorption coefficients versus the temperature for Cu and Co foils. For comparison, the absorption coefficient is also measured for Cu clusters. As expected from dimension effects, the Debye temperature obtained for the clusters is lower than that of bulk Cu.

  18. Influence of accelerated thermal charging and discharging cycles on thermo-physical properties of organic phase change materials for solar thermal energy storage applications

    International Nuclear Information System (INIS)

    Raam Dheep, G.; Sreekumar, A.

    2015-01-01

    Highlights: • Identification of organic phase change materials namely benzamide and sebacic acid. • Thermal reliability studies on identified phase change materials. • Measurement of phase transition temperature and latent heat of fusion. • Analysis of relative percentage difference (RPD%) in heat of fusion and melting temperature of benzamide and sebacic acid. - Abstract: Integration of appropriate thermal energy storage system plays a predominant role in upgrading the efficiency of solar thermal energy devices by reducing the incongruity between energy supply and demand. Latent heat thermal energy storage based on phase change materials (PCM) is found to be the most efficient and prospective method for storage of solar thermal energy. Ensuring the thermal reliability of PCM through large number of charging (melting) and discharging (solidification) cycles is a primary prerequisite to determine the suitability of PCM for a specific thermal energy storage applications. The present study explains the experimental analysis carried out on two PCM’s namely benzamide and sebacic acid to check the compatibility of the material in solar thermal energy storage applications. The selected materials were subjected to one thousand accelerated melting and solidification cycles in order to investigate the percentage of variation at different stages on latent heat of fusion, phase transition temperature, onset and peak melting temperature. Differential Scanning Calorimeter (DSC) was used to determine the phase transition temperature and heat of fusion upon completion of every 100 thermal cycles and continued up to 1000 cycles. Relative Percentage Difference (RPD%) is calculated to find out the absolute deviation of melting temperature and latent heat of fusion with respect to zeroth cycle. The experimental study recorded a melting temperatures of benzamide and sebacic acid as 125.09 °C and 135.92 °C with latent heat of fusion of 285.1 (J/g) and 374.4 (J/g). The

  19. Useful work and the thermal efficiency in the ideal Lenolr cycle with regenerative preheating

    Science.gov (United States)

    Georgiou, Demos P.

    2000-11-01

    In the existing thermal engine concepts negative work transfer (usually needed to drive a compression process) is supplied by the work produced by the engine itself. The remaining difference (i.e., the net work transfer) becomes the useful work, since it is available for external consumption. The thermal efficiency is the parameter that compares this against the heat input into the system. It forms the main optimization parameter in any engine design. The objective of the present study is to show that for the case of the Lenoir cycle with regenerative preheating the entire positive work is available for external consumption, since the negative (i.e., the compression) work is supplied by the atmospheric air. Not only this, but, during the compression process and due to the pressure difference across the two sides of the moving piston, an additional (useful) work transfer may be generated. Thus, the proposed power plant may be considered as a combination of a thermal engine and a wind turbine. In the ideal cycle limit (at least), the total amount of useful work exceeds the heat entering the system. This leads to the definition of a new parameter for the efficiency (called the technical efficiency), which compares the combined positive work transfer (i.e., the useful one) against the heat entering the system and which may exceed the 100% level.

  20. Texture development and strain hysteresis in a NiTi shape-memory alloy during thermal cycling under load

    International Nuclear Information System (INIS)

    Ye, B.; Majumdar, B.S.; Dutta, I.

    2009-01-01

    Thermal cycling experiments were conducted on a NiTi shape-memory alloy at different constant applied stresses below the yield strength of the martensite. The mechanical strain response manifested as strain hysteresis loops, whose range was proportional to the applied stress. In situ neutron diffraction experiments show that the strain hysteresis occurs as a result of the establishment of a stress-dependent crystallographic texture of the martensite during the first cool-down from austenite, and thereafter repeated during thermal cycling under the same load. This texture is found to depend on the stress during the thermal cycling experiments. A strain-pole map is derived and shown to explain the observed texture during thermal cycling. The strain-pole methodology is shown to work with similar martensitic transformations in other material systems.

  1. WESF cesium capsule behavior at high temperature or during thermal cycling

    International Nuclear Information System (INIS)

    Tingey, G.L.; Gray, W.J.; Shippell, R.J.; Katayama, Y.B.

    1985-06-01

    Double-walled stainless steel (SS) capsules prepared for storage of radioactive 137 Cs from defense waste are now being considered for use as sources for commercial irradiation. Cesium was recovered at B-plant from the high-level radioactive waste generated during processing of defense nuclear fuel. It was then purified, converted to the chloride form, and encapsulated at the Hanford Waste Encapsulation and Storage Facility (WESF). The molten cesium chloride salt was encapsulated by pouring it into the inner of two concentric SS cylinders. Each cylinder was fitted with a SS end cap that was welded in place by inert gas-tungsten arc welding. The capsule configuration and dimensions are shown in Figure 1. In a recent review of the safety of these capsules, Tingey, Wheelwright, and Lytle (1984) indicated that experimental studies were continuing to produce long-term corrosion data, to reaffirm capsule integrity during a 90-min fire where capsule temperatures reached 800 0 C, to monitor mechanical properties as a function of time, and to assess the effects of thermal cycling due to periodic transfer of the capsules from a water storage pool to the air environment of an irradiator facility. This report covers results from tests that simulated the effects of the 90-min fire and from thermal cycling actual WESF cesium capsules for 3845 cycles over a period of six months. 11 refs., 39 figs., 9 tabs

  2. Resistance of heat resisting steels and alloys to thermal and mechanical low-cycle fatigue

    International Nuclear Information System (INIS)

    Tulyakov, G.A.

    1980-01-01

    Carried out is a comparative evalUation of resistance of different materials to thermocyclic deformation and fracture on the base of the experimental data on thermal and mechanical low-cycle fatigUe. Considered are peculiarities of thermal fatigue resistance depending on strength and ductility of the material. It is shown, that in the range of the cycle small numbers before the fracture preference is given to the high-ductility cyclically strengthening austenitic steels of 18Cr-10Ni type with slight relation of yield strength to the σsub(0.2)/σsub(B) tensile strength Highly alloyed strength chromium-nickel steels, as well as cyclically destrengthening perlitic and ferritic steels with stronger σsub(0.2)/σsub(B) relation as compared with simple austenitic steels turn to be more long-lived in the range of the cycle great numbers berore fracture. Perlitic steels are stated to have the lowest parameter values of the K crack growth intensity under the similar limiting conditions of the experiment, while steels and alloys with austenite structure-higher values of the K parameter

  3. Thermal reliability test of Al-34%Mg-6%Zn alloy as latent heat storage material and corrosion of metal with respect to thermal cycling

    International Nuclear Information System (INIS)

    Sun, J.Q.; Zhang, R.Y.; Liu, Z.P.; Lu, G.H.

    2007-01-01

    The purpose of this study is to determine the thermal reliability and corrosion of the Al-34%Mg-6%Zn alloy as a latent heat energy storage material with respect to various numbers of thermal cycles. The differential scanning calorimeter (DSC) analysis technique was applied to the alloy after 0, 50, 500 and 1000 melting/solidification cycles in order to measure the melting temperatures and the latent heats of fusion of the alloy. The containment materials were stainless steel (SS304L), carbon steel (steel C20) in the corrosion tests. The DSC results indicated that the change in melting temperature for the alloy was in the range of 3.06-5.3 K, and the latent heat of fusion decreased 10.98% after 1000 thermal cycles. The results show that the investigated Al-34%Mg-6%Zn alloy has a good thermal reliability as a latent heat energy storage material with respect to thermal cycling for thermal energy storage applications in the long term in view of the small changes in the latent heat of fusion and melting temperature. Gravimetric analysis as mass loss (mg/cm 2 ), corrosion rate (mg/day) and a microscopic or metallographic investigation were performed for corrosion tests and showed that SS304L may be considered a more suitable alloy than C20 in long term thermal storage applications

  4. Infrared absorption study of ammonium uranates and uranium oxide powders formed during their thermal decomposition

    International Nuclear Information System (INIS)

    Rofail, N.H.; ELfekey, S.A.

    1992-01-01

    Ammonium uranates (AU) were precipitated from a nuclear-pure uranyl nitrate solution using different precipitating agents. IR spectra of the obtained uranates and oxides formed during their thermal decomposition have been studied. The results indicated that the precipitating agent, mode of stirring, washing and calcining temperature are important factors for a specific oxide formation.4 FIG., 3 TAB

  5. Multi-objective optimization of a continuous thermally regenerative electrochemical cycle for waste heat recovery

    International Nuclear Information System (INIS)

    Long, Rui; Li, Baode; Liu, Zhichun; Liu, Wei

    2015-01-01

    An optimization analysis of a continuous TREC (thermally regenerative electrochemical cycle) was conducted with maximum power output and exergy efficiency as the objective functions simultaneously. For comparison, the power output, exergy efficiency, and thermal efficiency under the corresponding single-objective optimization schematics were also calculated. Under different optimization methods it was observed that the power output and the thermal efficiency increase with increasing inlet temperature of the heat source, whereas the exergy efficiency increases with increasing inlet temperature, reaches a maximum value, and then decreases. Results revealed that the optimal power output under the multi-objective optimization turned out to be slightly less than that obtained under the single-objective optimization for power output. However, the exergy and thermal efficiencies were much greater. Furthermore, the thermal exergy and exergy efficiency by single-objective optimization for energy efficiency shows no dominant advantage than that obtained under multi-objective optimization, comparing with the increase amplitude of the power output. This suggests that the multi-objective optimization could coordinate well both the power output and the exergy efficiency of the TREC system, and may serve as a more promising guide for operating and designing TREC systems. - Highlights: • An optimal analysis of a continuous TREC is conducted based on multi-objective optimization. • Performance under corresponding single-objective optimizations has also been calculated and compared. • Power under multi-objective optimization is slightly less than the maximum power. • Exergy and thermal efficiencies are much larger than that under the single-objective optimization.

  6. Pile oscillator measurements of thermal absorption cross sections of Al, Mg, Fe and Cu

    International Nuclear Information System (INIS)

    Carre, J.C.; Vidal, R.

    1964-01-01

    The phase oscillation technique used at ZOE has the property of reducing of a marked factor the effect of neutron scattering by the sample. The absorption cross sections of poorly absorbing and highly scattering materials have been measured; for neutrons of 2,200 m/s, the following values are obtained: 229 ± 3 mb for Al; 64.2 ± 1.5 mb for Mg, 2.53 ± 0.03 b for Fe and 3.74 ± 0.04 b for Cu. (authors) [fr

  7. Research on transient thermal process of a friction brake during repetitive cycles of operation

    Science.gov (United States)

    Slavchev, Yanko; Dimitrov, Lubomir; Dimitrov, Yavor

    2017-12-01

    Simplified models are used in the classical engineering analyses of the friction brake heating temperature during repetitive cycles of operation to determine basically the maximum and minimum brake temperatures. The objective of the present work is to broaden and complement the possibilities for research through a model that is based on the classical scheme of the Newton's law of cooling and improves the studies by adding a disturbance function for a corresponding braking process. A general case of braking in non-periodic repetitive mode is considered, for which a piecewise function is defined to apply pulse thermal loads to the system. Cases with rectangular and triangular waveforms are presented. Periodic repetitive braking process is also studied using a periodic rectangular waveform until a steady thermal state is achieved. Different numerical methods such as the Euler's method, the classical fourth order Runge-Kutta (RK4) and the Runge-Kutta-Fehlberg 4-5 (RKF45) are used to solve the non-linear differential equation of the model. The constructed model allows during pre-engineering calculations to be determined effectively the time for reaching the steady thermal state of the brake, to be simulated actual braking modes in vehicles and material handling machines, and to be accounted for the thermal impact when performing fatigue calculations.

  8. Rate equations modeling for hydrogen inventory studies during a real tokamak material thermal cycle

    Energy Technology Data Exchange (ETDEWEB)

    Bonnin, X., E-mail: xavier.bonnin@iter.org [LSPM-CNRS, Université Paris 13, Sorbonne Paris Cité, 99 avenue Jean-Baptiste Clément, F-93430 Villetaneuse (France); Hodille, E. [IRFM, CEA-Cadarache, F-13108 St-Paul-Lez-Durance (France); Ning, N. [LSPM-CNRS, Université Paris 13, Sorbonne Paris Cité, 99 avenue Jean-Baptiste Clément, F-93430 Villetaneuse (France); Sang, C. [School of Physics and Optoelectronics Technology, Dalian University of Technology, Dalian 116024 (China); Grisolia, Ch. [IRFM, CEA-Cadarache, F-13108 St-Paul-Lez-Durance (France)

    2015-08-15

    Prediction and control of tritium inventory in plasma-facing components (PFCs) is a critical nuclear safety issue for ITER and future fusion devices. This goal can be achieved through rate equations models as presented here. We calibrate our models with thermal desorption spectrometry results to obtain a validated set of material parameters relevant to hydrogen inventory processes in bulk tungsten. The best fits are obtained with two intrinsic trap types, deep and shallow, and an extrinsic trap created by plasma irradiation and plastic deformation of the tungsten matrix associated with blister formation. We then consider a realistic cycle of plasma discharges consisting of 400 s of plasma exposure followed by a resting period of 1000 s, repeating for several hours. This cycle is then closed by a long “overnight” period, thus providing an estimate of the amount of tritium retained in the PFCs after a full day of standard operation.

  9. Separation and prediction of irrecoverable strain components of concrete during the first thermal cycle

    International Nuclear Information System (INIS)

    Khoury, G.A.

    1993-01-01

    Strains of three AGR type concretes were measured during the first heat cycle and their relative thermal stability determined. It was possible to isolate for the first time the shrinkage and creep components for the period during heating-up. Predictions of the residual strains for the loaded specimens can be made by simple superposition of creep and shrinkage components up to a certain critical temperature, which for basalt concrete is about 500 deg. C and limestone concrete is about 200-300 deg. C. Above the critical temperature, it is necessary to add a 'cracking component'. (author)

  10. Thermal energy storage for organic Rankine cycle solar dynamic space power systems

    Science.gov (United States)

    Heidenreich, G. R.; Parekh, M. B.

    An organic Rankine cycle-solar dynamic power system (ORC-SDPS) comprises a concentrator, a radiator, a power conversion unit, and a receiver with a thermal energy storage (TES) subsystem which charges and discharges energy to meet power demands during orbital insolation and eclipse periods. Attention is presently given to the criteria used in designing and evaluating an ORC-SDPS TES, as well as the automated test facility employed. It is found that a substantial data base exists for the design of an ORC-SDPS TES subsystem.

  11. Effects of mechanical and thermal load cycling on micro tensile bond strength of clearfil SE bond to superficial dentin

    Directory of Open Access Journals (Sweden)

    Ali Reza Daneshkazemi

    2013-01-01

    Full Text Available Background: Certain studies have been conducted on the effects of mechanical and thermal load cycling on the microtensile bond strength (microTBS of composites to dentin, but the results were different. The authors therefore decided to evaluate these effects on the bonding of Clearfil SE bond to superficial dentin. Materials and Methods: Flat dentinal surface of 42 molar teeth were bonded to Filtek-Z250 resin composite by Clearfil SE bond. The teeth were randomly divided into 7 groups and exposed to different mechanical and thermal load cycling. Thermocycling was at 5-55°C and mechanical load cycling was created with a force of 125 N and 0.5 Hz. Then, the teeth were sectioned and shaped to hour glass form and subjected to microTBS testing at a speed of 0.5 mm/min. The results were statistically analyzed by computer with three-way analysis of variance and T-test at P < 0.05 significant. To evaluate the location and mode of failure, the specimens were observed under the stereomicroscope. Then, one of the specimens in each group was evaluated under Scanning Electron Microscopy (SEM for mode of failure. Results: All of the study groups had a significantly lower microTBS as compared to the control group ( P < 0.001. There was no statistically significant difference between mechanical cycling with 50K (kilo = 1000 cycles, and 50K mechanical cycles plus 1K thermal cycles. Most of the fractures in the control group were of adhesive type and this type of fracture increased after exposure to mechanical and thermal load cycling. Conclusion: Thermal and mechanical load cycling had significant negative effects on microTBS and the significant effects of mechanical load cycling started to be significant at 100K cycles.

  12. A Literature Review of Shock Sensitivity Changes of TATB Due to Thermal Cycling

    Energy Technology Data Exchange (ETDEWEB)

    Ritter, Boyd [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); New Mexico Inst. of Mining and Technology, Socorro, NM (United States). Dept. of Mechanical Engineering

    2016-07-15

    Insensitive high explosives (IHEs) based on 1,3,5-triamino 2,4,6-trinitro-benzene (TATB) are the IHEs of choice for use in nuclear warheads over conventional high explosives when safety is the only consideration, because they are very insensitive to thermal or mechanical initiation stimuli. It is this inherent insensitivity to high temperatures, shock, and impact, which provides detonation design challenges when designing TATB explosive systems while at the same time providing a significant level of protection against accidental initiation. Although classified as IHE, over the past few years the focus on explosive safety has demonstrated that the shock sensitivity of TATB is influenced with respect to temperature. A number of studies have been performed on TATB and TATB formulations, plastic bonded explosives (PBX) 9502, and LX-17-01 (LX-17), which demonstrates the increase in shock sensitivity of the explosive after it has been preheated or thermally cycled over various temperature ranges. Many studies suggest the change in sensitivity is partly due to the decomposition rates of the temperature elevated TATB. Others point to the coefficient of thermal expansion, the crystalline structures of TATB and/or the combination of all factors, which create voids which can become active hot spots. During thermal cycling, TATB is known to undergo an irreversible increase in specific volume called ratchet growth. This increase in specific volume correlates to a decrease in density. This decrease in density and increase in volume, demonstrate the creations of additional void spaces which could serve as potential new initiation hot spots thus, increasing the overall sensitivity of the HE. This literature review evaluates the published works to understand why the shock sensitivity of TATB-based plastic bonded explosives (PBXs) changes with temperature.

  13. Performance analysis of absorption heat transformer cycles using ionic liquids based on imidazolium cation as absorbents with 2,2,2-trifluoroethanol as refrigerant

    International Nuclear Information System (INIS)

    Ayou, Dereje S.; Currás, Moisés R.; Salavera, Daniel; García, Josefa; Bruno, Joan C.; Coronas, Alberto

    2014-01-01

    Highlights: • TFE + [emim][BF 4 ] (or [bmim][BF 4 ]) absorption heat transformer cycles are studied. • Influence of various operating conditions on cycle’s performance is investigated. • Performance comparisons with H 2 O + LiBr and TFE + TEGDME cycles are done. • Enthalpy data for TFE + [emim][BF 4 ] (or [bmim][BF 4 ]) liquid mixtures are calculated. • TFE + [emim][BF 4 ] (or [bmim][BF 4 ]) cycles have higher gross temperature lift (GTL). - Abstract: A detailed thermodynamic performance analysis of a single-stage absorption heat transformer and double absorption heat transformer cycles using new working pairs composed of ionic liquids (1-ethyl-3-methylimidazolium tetrafluoroborate ([emim][BF 4 ]) and 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF 4 ])) as absorbent and 2,2,2-trifluoroethanol (TFE) as refrigerant has been studied. Several performance indicators were used to evaluate and compare the performance of the cycles using the TFE + [emim][BF 4 ] and TFE + [bmim][BF 4 ] working pairs with the conventional H 2 O + LiBr and organic TFE + TEGDME working pairs. The obtained results show that the ionic liquid based working pairs are suitable candidates to replace the conventional H 2 O + LiBr working pairs in order to avoid the disadvantages associated with it mainly crystallization and corrosion and also they perform better (higher gross temperature lift) than TFE + TEGDME working pair at several operating conditions considered in this work

  14. Laser Soldering and Thermal Cycling Tests of Monolithic Silicon Pixel Chips

    CERN Document Server

    Strand, Frode Sneve

    2015-01-01

    An ALPIDE-1 monolithic silicon pixel sensor prototype has been laser soldered to a flex printed circuit using a novel interconnection technique using lasers. This technique is to be optimised to ensure stable, good quality connections between the sensor chips and the FPCs. To test the long-term stability of the connections, as well as study the effects on hit thresholds and noise in the sensor, it was thermally cycled in a climate chamber 1200 times. The soldered connections showed good qualities like even melting and good adhesion on pad/flex surfaces, and the chip remained in working condition for 1080 cycles. After this, a few connections failed, having cracks in the soldering tin, rendering the chip unusable. Threshold and noise characteristics seemed stable, except for the noise levels of sector 2 in the chip, for 1000 cycles in a temperature interval of "10^{\\circ}" and "50^{\\circ}" C. Still, further testing with wider temperature ranges and more cycles is needed to test the limitations of the chi...

  15. Technical Feasibility Study of Thermal Energy Storage Integration into the Conventional Power Plant Cycle

    Directory of Open Access Journals (Sweden)

    Jacek D. Wojcik

    2017-02-01

    Full Text Available The current load balance in the grid is managed mainly through peaking fossil-fuelled power plants that respond passively to the load changes. Intermittency, which comes from renewable energy sources, imposes additional requirements for even more flexible and faster responses from conventional power plants. A major challenge is to keep conventional generation running closest to the design condition with higher load factors and to avoid switching off periods if possible. Thermal energy storage (TES integration into the power plant process cycle is considered as a possible solution for this issue. In this article, a technical feasibility study of TES integration into a 375-MW subcritical oil-fired conventional power plant is presented. Retrofitting is considered in order to avoid major changes in the power plant process cycle. The concept is tested based on the complete power plant model implemented in the ProTRAX software environment. Steam and water parameters are assessed for different TES integration scenarios as a function of the plant load level. The best candidate points for heat extraction in the TES charging and discharging processes are evaluated. The results demonstrate that the integration of TES with power plant cycle is feasible and provide a provisional guidance for the design of the TES system that will result in the minimal influence on the power plant cycle.

  16. Fast thermal cycling of acetanilide and magnesium chloride hexahydrate for indoor solar cooking

    International Nuclear Information System (INIS)

    El-Sebaii, A.A.; Al-Amir, S.; Al-Marzouki, F.M.; Faidah, Adel S.; Al-Ghamdi, A.A.; Al-Heniti, S.

    2009-01-01

    Solar cookers are broadly divided into a direct or focusing type, indirect or box-type and advanced solar cookers. The focusing and box-type solar cookers are for outdoor applications. The advanced solar cookers have the advantage of being usable indoors and thus solve one of the problems, which impede the social acceptance of solar cookers. The advanced type solar cookers are employing additional solar units that increase the cost. Therefore, the solar cooker must contain a heat storage medium to store thermal energy for use during off-sunshine hours. The main aim of this study is to investigate the influence of the melting/solidification fast cycling of the commercial grade acetanilide C 8 H 9 NO (T m = 116 deg. C) and magnesium chloride hexahydrate MgCl 2 .6H 2 O (T m = 116.7 deg. C) on their thermo-physical properties; such as melting point and latent heat of fusion, to be used as storage media inside solar cookers. Five hundred cycles have been performed. The thermo-physical properties are measured using the differential scanning calorimetric technique. The compatibility of the selected phase change materials (PCMs) with the containing material is also studied via the surface investigation, using the SIM technique, of aluminum and stainless steel samples embedded in the PCM during cycling. It is inferred that acetanilide is a promising PCM for cooking indoors and during law intensity solar radiation periods with good compatibility with aluminum as a containing material. However, MgCl 2 .6H 2 O is not stable during its thermal cycling (even with the extra water principle) due to the phase segregation problem; therefore, it is not recommended as a storage material inside solar cookers for cooking indoors. It is also indicated that MgCl 2 .6H 2 O is not compatible with either aluminum or stainless steel.

  17. Analysis of transition to fuel cycle system with continuous recycling in fast and thermal reactors - 5060

    International Nuclear Information System (INIS)

    Passereini, S.; Feng, B.; Fei, T.; Kim, T.K.; Taiwo, T.A.; Brown, N.R.; Cuadra, A.

    2015-01-01

    A recent Evaluation and Screening study of nuclear fuel cycle options identified a few groups of options as most promising. One of these most promising Evaluation Groups (EGs) is characterized by the continuous recycling of uranium (U) and transuranics (TRU) with natural uranium feed in both fast and thermal critical reactors. This evaluation group, designated as EG30, is represented by an example fuel cycle option that employs a two-technology, two-stage fuel cycle system. The first stage involves the continuous recycling of co-extracted U/TRU in Sodium-cooled Fast Reactors (SFRs) with metallic fuel and breeding ratio greater than 1. The second stage involves the use of the surplus TRU in Mixed Oxide (MOX) fuel in Pressurized Water Reactors that are MOX-capable (MOX-PWRs). This paper presents and discusses preliminary fuel cycle analysis results from the fuel cycle codes VISION and DYMOND for the transition to this fuel cycle option from the current once-through cycle in the United States (U.S.) that consists of Light Water Reactors (LWRs) that only use conventional UO 2 fuel. The analyses in this paper are applicable for a constant 100 GWe capacity, roughly the size of the U.S. nuclear fleet. Two main strategies for the transition to EG30 were analyzed: 1) deploying both SFRs and MOX-PWRs in parallel or 2) deploying them in series with the SFR fleet first. With an estimated retirement schedule for the existing LWRs, an assumed reactor lifetime of 60 years, and no growth, the nuclear system fully transitions to the new fuel cycle within 100 years for both strategies without SFR fuel shortages. Compared to the once-through cycle, transition to the SFR/MOX-PWR fleet with continuous recycle was shown to offer significant reductions in uranium consumption and waste disposal requirements. In addition, these initial calculations revealed a few notable modeling and strategy questions regarding how recycled resources are allocated, reactors that can switch between

  18. Rapid freeze-drying cycle optimization using computer programs developed based on heat and mass transfer models and facilitated by tunable diode laser absorption spectroscopy (TDLAS).

    Science.gov (United States)

    Kuu, Wei Y; Nail, Steven L

    2009-09-01

    Computer programs in FORTRAN were developed to rapidly determine the optimal shelf temperature, T(f), and chamber pressure, P(c), to achieve the shortest primary drying time. The constraint for the optimization is to ensure that the product temperature profile, T(b), is below the target temperature, T(target). Five percent mannitol was chosen as the model formulation. After obtaining the optimal sets of T(f) and P(c), each cycle was assigned with a cycle rank number in terms of the length of drying time. Further optimization was achieved by dividing the drying time into a series of ramping steps for T(f), in a cascading manner (termed the cascading T(f) cycle), to further shorten the cycle time. For the purpose of demonstrating the validity of the optimized T(f) and P(c), four cycles with different predicted lengths of drying time, along with the cascading T(f) cycle, were chosen for experimental cycle runs. Tunable diode laser absorption spectroscopy (TDLAS) was used to continuously measure the sublimation rate. As predicted, maximum product temperatures were controlled slightly below the target temperature of -25 degrees C, and the cascading T(f)-ramping cycle is the most efficient cycle design. In addition, the experimental cycle rank order closely matches with that determined by modeling.

  19. Effect of thermal radiation and suction on convective heat transfer of nanofluid along a wedge in the presence of heat generation/absorption

    Energy Technology Data Exchange (ETDEWEB)

    Kasmani, Ruhaila Md; Bhuvaneswari, M. [Centre for Foundation Studies in Science, University of Malaya, 50603 Kuala Lumpur (Malaysia); Sivasankaran, S.; Siri, Zailan [Institute of Mathematical Science, University of Malaya, 50603 Kuala Lumpur (Malaysia)

    2015-10-22

    An analysis is presented to find the effects of thermal radiation and heat generation/absorption on convection heat transfer of nanofluid past a wedge in the presence of wall suction. The governing partial differential equations are transformed into a system of ordinary differential equations using similarity transformation. The resulting system is solved numerically using a fourth-order Runge–Kutta method with shooting technique. Numerical computations are carried out for different values of dimensionless parameters to predict the effects of wedge angle, thermophoresis, Brownian motion, heat generation/absorption, thermal radiation and suction. It is found that the temperature increases significantly when the value of the heat generation/absorption parameter increases. But the opposite observation is found for the effect of thermal radiation.

  20. Radiative and Thermal Impacts of Smoke Aerosol Longwave Absorption during Fires in the Moscow Region in Summer 2010

    Science.gov (United States)

    Gorchakova, I. A.; Mokhov, I. I.; Anikin, P. P.; Emilenko, A. S.

    2018-03-01

    The aerosol longwave radiative forcing of the atmosphere and heating rate of the near-surface aerosol layer are estimated for the extreme smoke conditions in the Moscow region in summer 2010. Thermal radiation fluxes in the atmosphere are determined using the integral transmission function and semiempirical aerosol model developed on the basis of standard aerosol models and measurements at the Zvenigorod Scientific Station, Obukhov Institute of Atmospheric Physics, Russian Academy of Sciences. The aerosol radiative forcing reached 33 W/m2 at the lower atmospheric boundary and ranged between-1.0 and 1.0 W/m2 at the upper atmospheric boundary. The heating rate of the 10-m atmospheric layer near surface was up to 0.2 K/h during the maximum smoke conditions on August 7-9. The sensitivity of the aerosol longwave radiative forcing to the changes in the aerosol absorption coefficient and aerosol optical thickness are estimated.

  1. Simulation study of the thermal and the thermoelastic effects induced by pulsed laser absorption in human skin

    Science.gov (United States)

    Kim, Jae-Young; Jang, Kyungmin; Yang, Seung-Jin; Baek, Jun-Hyeok; Park, Jong-Rak; Yeom, Dong-Il; Kim, Ji-Sun; Kim, Hyung-Sik; Jun, Jae-Hoon; Chung, Soon-Cheol

    2016-04-01

    We studied the thermal and the mechanical effects induced by pulsed laser absorption in human skin by numerically solving the heat-transfer and the thermoelastic wave equations. The simulation of the heat-transfer equation yielded the spatiotemporal distribution of the temperature increase in the skin, which was then used in the driving term of the thermoelastic wave equation. We compared our simulation results for the temperature increase and the skin displacements with the measured and numerical results, respectively. For the comparison, we used a recent report by Jun et al. [Sci. Rep. 5, 11016 (2015)], who measured in vivo skin temperature and performed numerical simulation of the thermoelastic wave equation using a simple assumption about the temporal evolution of the temperature distribution, and found their results to be in good agreement with our results. In addition, we obtained solutions for the stresses in the human skin and analyzed their dynamic behaviors in detail.

  2. Characterization of coarse bainite transformation in low carbon steel during simulated welding thermal cycles

    Energy Technology Data Exchange (ETDEWEB)

    Lan, Liangyun, E-mail: lanly@me.neu.edu.cn [School of Mechanical Engineering and Automation, Northeastern University, Shenyang 110819 (China); State Key Laboratory of Rolling Technology and Automation, Northeastern University, Shenyang 110819 (China); Kong, Xiangwei [School of Mechanical Engineering and Automation, Northeastern University, Shenyang 110819 (China); Qiu, Chunlin [State Key Laboratory of Rolling Technology and Automation, Northeastern University, Shenyang 110819 (China)

    2015-07-15

    Coarse austenite to bainite transformation in low carbon steel under simulated welding thermal cycles was morphologically and crystallographically characterized by means of optical microscope, transmission electron microscope and electron backscattered diffraction technology. The results showed that the main microstructure changes from a mixture of lath martensite and bainitic ferrite to granular bainite with the increase in cooling time. The width of bainitic laths also increases gradually with the cooling time. For a welding thermal cycle with relatively short cooling time (e.g. t{sub 8/5} is 30 s), the main mode of variant grouping at the scale of individual prior austenite grains changes from Bain grouping to close-packed plane grouping with the progress of phase transformation, which results in inhomogeneous distribution of high angle boundaries. As the cooling time is increased, the Bain grouping of variants becomes predominant mode, which enlarges the effective grain size of product phase. - Highlights: • Main microstructure changes and the width of lath structure increases with cooling time. • Variant grouping changes from Bain zone to close-packed plane grouping with the transformation. • The change of variant grouping results in uneven distribution of high angle grain boundary. • Bain grouping is main mode for large heat input, which lowers the density of high angle boundary.

  3. Characterization of coarse bainite transformation in low carbon steel during simulated welding thermal cycles

    International Nuclear Information System (INIS)

    Lan, Liangyun; Kong, Xiangwei; Qiu, Chunlin

    2015-01-01

    Coarse austenite to bainite transformation in low carbon steel under simulated welding thermal cycles was morphologically and crystallographically characterized by means of optical microscope, transmission electron microscope and electron backscattered diffraction technology. The results showed that the main microstructure changes from a mixture of lath martensite and bainitic ferrite to granular bainite with the increase in cooling time. The width of bainitic laths also increases gradually with the cooling time. For a welding thermal cycle with relatively short cooling time (e.g. t 8/5 is 30 s), the main mode of variant grouping at the scale of individual prior austenite grains changes from Bain grouping to close-packed plane grouping with the progress of phase transformation, which results in inhomogeneous distribution of high angle boundaries. As the cooling time is increased, the Bain grouping of variants becomes predominant mode, which enlarges the effective grain size of product phase. - Highlights: • Main microstructure changes and the width of lath structure increases with cooling time. • Variant grouping changes from Bain zone to close-packed plane grouping with the transformation. • The change of variant grouping results in uneven distribution of high angle grain boundary. • Bain grouping is main mode for large heat input, which lowers the density of high angle boundary

  4. Optimization of low temperature solar thermal electric generation with Organic Rankine Cycle in different areas

    International Nuclear Information System (INIS)

    Jing, Li; Gang, Pei; Jie, Ji

    2010-01-01

    The presented low temperature solar thermal electric generation system mainly consists of compound parabolic concentrators (CPC) and the Organic Rankine Cycle (ORC) working with HCFC-123. A novel design is proposed to reduce heat transfer irreversibility between conduction oil and HCFC-123 in the heat exchangers while maintaining the stability of electricity output. Mathematical formulations are developed to study the heat transfer and energy conversion processes and the numerical simulation is carried out based on distributed parameters. Annual performances of the proposed system in different areas of Canberra, Singapore, Bombay, Lhasa, Sacramento and Berlin are simulated. The influences of the collector tilt angle adjustment, the connection between the heat exchangers and the CPC collectors, and the ORC evaporation temperature on the system performance are investigated. The results indicate that the three factors have a major impact on the annual electricity output and should be the key points of optimization. And the optimized system shows that: (1) The annual received direct irradiance can be significantly increased by two or three times optimal adjustments even when the CPC concentration ratio is smaller than 3.0. (2) Compared with the traditional single-stage collectors, two-stage collectors connected with the heat exchangers by two thermal oil cycles can improve the collector efficiency by 8.1-20.9% in the simultaneous processes of heat collection and power generation. (3) On the use of the market available collectors the optimal ORC evaporation temperatures in most of the simulated areas are around 120 C. (author)

  5. Monte Carlo simulations of the detailed iron absorption line profiles from thermal winds in X-ray binaries

    Science.gov (United States)

    Tomaru, Ryota; Done, Chris; Odaka, Hirokazu; Watanabe, Shin; Takahashi, Tadayuki

    2018-05-01

    Blueshifted absorption lines from highly ionized iron are seen in some high inclination X-ray binary systems, indicating the presence of an equatorial disc wind. This launch mechanism is under debate, but thermal driving should be ubiquitous. X-ray irradiation from the central source heats disc surface, forming a wind from the outer disc where the local escape velocity is lower than the sound speed. The mass-loss rate from each part of the disc is determined by the luminosity and spectral shape of the central source. We use these together with an assumed density and velocity structure of the wind to predict the column density and ionization state, then combine this with a Monte Carlo radiation transfer to predict the detailed shape of the absorption (and emission) line profiles. We test this on the persistent wind seen in the bright neutron star binary GX 13+1, with luminosity L/LEdd ˜ 0.5. We approximately include the effect of radiation pressure because of high luminosity, and compute line features. We compare these to the highest resolution data, the Chandra third-order grating spectra, which we show here for the first time. This is the first physical model for the wind in this system, and it succeeds in reproducing many of the features seen in the data, showing that the wind in GX13+1 is most likely a thermal-radiation driven wind. This approach, combined with better streamline structures derived from full radiation hydrodynamic simulations, will allow future calorimeter data to explore the detail wind structure.

  6. MERCURY QUANTIFICATION IN SOILS USING THERMAL DESORPTION AND ATOMIC ABSORPTION SPECTROMETRY: PROPOSAL FOR AN ALTERNATIVE METHOD OF ANALYSIS

    Directory of Open Access Journals (Sweden)

    Liliane Catone Soares

    2015-08-01

    Full Text Available Despite the considerable environmental importance of mercury (Hg, given its high toxicity and ability to contaminate large areas via atmospheric deposition, little is known about its activity in soils, especially tropical soils, in comparison with other heavy metals. This lack of information about Hg arises because analytical methods for determination of Hg are more laborious and expensive compared to methods for other heavy metals. The situation is even more precarious regarding speciation of Hg in soils since sequential extraction methods are also inefficient for this metal. The aim of this paper is to present a technique of thermal desorption associated with atomic absorption spectrometry, TDAAS, as an efficient tool for quantitative determination of Hg in soils. The method consists of the release of Hg by heating, followed by its quantification by atomic absorption spectrometry. It was developed by constructing calibration curves in different soil samples based on increasing volumes of standard Hg2+ solutions. Performance, accuracy, precision, and quantification and detection limit parameters were evaluated. No matrix interference was detected. Certified reference samples and comparison with a Direct Mercury Analyzer, DMA (another highly recognized technique, were used in validation of the method, which proved to be accurate and precise.

  7. Recombination properties of diode structures by study of thermal emission beyond the fundamental absorption band

    International Nuclear Information System (INIS)

    Piotrowski, T; Wȩgrzecki, M; Czerwinski, A; Teslenko, G I; Malyutenko, O Y; Malyutenko, V K

    2014-01-01

    The study presents the possibilities of applying the measurement of spatial and temporal distribution of thermal radiation of a p-n junction structure located in a homogeneous temperature field higher than the ambient temperature, modulated by the presence of excess carriers injected through the junction, to determine surface recombination velocity at the injecting contact of the diode emitter and to measure the diffusion length in the base. Good agreement was obtained between the experimental results and calculations based on solutions of the transport equations.

  8. ICRF Wave Propagation and Absorption in Plasmas with Non-thermal Populations

    International Nuclear Information System (INIS)

    Dumont, R.J.; Phillips, C.K.; Smithe, D.N.

    2002-01-01

    Some results obtained with the one dimensional, all orders, full wave code METS, which has been successfully employed in the past to describe a number of experiments, are reported. By using massively parallel computers, this code has been extended to handle non-thermal populations. Various physical situations, in which non-Maxwellian species are expected to be encountered, are studied, such as simultaneous neutral beam injection and high harmonic fast wave electron heating or ion cyclotron resonance heating in the presence of fusion products

  9. Passive residual energy utilization system in thermal cycles on water-cooled power reactors

    International Nuclear Information System (INIS)

    Placco, Guilherme M.; Guimaraes, Lamartine N.F.; Santos, Rubens S. dos

    2013-01-01

    This work presents a concept of a residual energy utilization in nuclear plants thermal cycles. After taking notice of the causes of the Fukushima nuclear plant accident, an idea arose to adapt a passive thermal circuit as part of the ECCS (Emergency Core Cooling System). One of the research topics of IEAv (Institute for Advanced Studies), as part of the heat conversion of a space nuclear power system is a passive multi fluid turbine. One of the main characteristics of this device is its passive capability of staying inert and be brought to power at moments notice. During the first experiments and testing of this passive device, it became clear that any small amount of gas flow would generate power. Given that in the first stages of the Fukushima accident and even during the whole event there was plenty availability of steam flow that would be the proper condition to make the proposed system to work. This system starts in case of failure of the ECCS, including loss of site power, loss of diesel generators and loss of the battery power. This system does not requires electricity to run and will work with bleed steam. It will generate enough power to supply the plant safety system avoiding overheating of the reactor core produced by the decay heat. This passive system uses a modified Tesla type turbine. With the tests conducted until now, it is possible to ensure that the operation of this new turbine in a thermal cycle is very satisfactory and it performs as expected. (author)

  10. Effect of long-term storage of LWR spent fuel on Pu-thermal fuel cycle

    International Nuclear Information System (INIS)

    Kurosawa, Masayoshi; Naito, Yoshitaka; Suyama, Kenya; Itahara, Kuniyuki; Suzuki, Katsuo; Hamada, Koji

    1998-01-01

    According to the Long-term Program for Research, Development and Utilization of Nuclear Energy (June, 1994) in Japan, the Rokkasho Reprocessing Plant will be operated shortly after the year 2000, and the planning of the construction of the second commercial plant will be decided around 2010. Also, it is described that spent fuel storage has a positive meaning as an energy resource for the future utilization of Pu. Considering the balance between the increase of spent fuels and the domestic reprocessing capacity in Japan, it can be expected that the long-term storage of UO 2 spent fuels will be required. Then, we studied the effect of long-term storage of spent fuels on Pu-thermal fuel cycle. The burnup calculation were performed on the typical Japanese PWR fuel, and the burnup and criticality calculations were carried out on the Pu-thermal cores with MOX fuel. Based on the results, we evaluate the influence of extending the spent fuel storage term on the criticality safety, shielding design of the reprocessing plant and the core life time of the MOX core, etc. As the result of this work on long-term storage of LWR spent fuels, it becomes clear that there are few demerits regarding the lifetime of a MOX reactor core, and that there are many merits regarding the safety aspects of the fuel cycle facilities. Furthermore, long-term storage is meaningful as energy storage for effective utilization of Pu to be improved by technological innovation in future, and it will allow for sufficient time for the important policymaking of nuclear fuel cycle establishment in Japan. (author)

  11. Low cycle thermal fatigue testing of beryllium grades for ITER plasma facing components

    International Nuclear Information System (INIS)

    Watson, R.D.; Youchison, D.L.; Dombrowski, D.E.; Guiniatouline, R.N.; Kupriynov, I.B.

    1996-01-01

    A novel technique has been used to test the relative low cycle thermal fatigue resistance of different grades of US and Russian beryllium, which is proposed as plasma facing armor for fusion reactor first wall, limiter, and divertor components. The 30 kW electron beam test system at Sandia National Laboratories was used to sweep the beam spot along one direction at 1 Hz. This produces a localized temperature ''spike'' of 750 degree C for each pass of the beam. Large thermal stresses in excess of the yield strength are generated due to very high spot heat flux, 250 MW/m 2 . Cyclic plastic strains on the order of 0.6% produced visible cracking on the heated surface in less than 3000 cycles. An in-vacuo fiber optic borescope was used to visually inspect the beryllium surfaces for crack initiation. Grades of US beryllium tested included: S-65C, S- 65H, S-200F, S-200F-H, SR-200, I-400, extruded high purity, HIP'd spherical powder, porous beryllium (94% and 98% dense), Be/30% BeO, Be/60% BeO, and TiBe 12 . Russian grades included: TGP-56, TShGT, DShG-200, and TShG-56. Both the number of cycles to crack initiation, and the depth of crack propagation, were measured. The most fatigue resistant grades were S-65C, DShG-200, TShGT, and TShG-56. Rolled sheet Be (SR-200) showed excellent crack propagation resistance in the plane of rolling, despite early formation of delamination cracks. Only one sample showed no evidence of surface melting, Extruded (T). Metallographic and chemical analyses are provided. Good agreement was found between the measured depth of cracks and a 2-D elastic-plastic finite element stress analysis

  12. Thermal hydraulic and power cycle analysis of liquid lithium blanket designs

    International Nuclear Information System (INIS)

    Misra, B.; Stevens, H.C.; Maroni, V.A.

    1977-01-01

    Thermal hydraulic and power cycle analyses were performed for the first-wall and blanket systems of tokamak-type fusion reactors under a typical set of design and operating conditions. The analytical results for lithium-cooled blanket cells show that with stainless steel as construction material and with no divertor present, the maximum allowable neutron wall loading is approximately 2 MW/m 2 and is limited by thermal stress criteria. With vanadium alloy as construction material and no divertor present, the maximum allowable neutron wall loading is approximately 8 MW/m 2 and is limited by an interplay of constraints imposed on the maximum allowable structural temperature and the minimum allowable coolant inlet temperature. With a divertor these wall loadings can be increased by from 40 to 90 percent. The cost of the vanadium system is found to be competitive with the stainless steel system because of the higher allowable structural temperatures and concomitant higher thermal efficiencies afforded by the vanadium alloys

  13. Thermal analysis of a Phase Change Material for a Solar Organic Rankine Cycle

    Science.gov (United States)

    Iasiello, M.; Braimakis, K.; Andreozzi, A.; Karellas, S.

    2017-11-01

    Organic Rankine Cycle (ORC) is a promising technology for low temperature power generation, for example for the utilization of medium temperature solar energy. Since heat generated from solar source is variable throughout the day, the implementation of Thermal Energy Storage (TES) systems to guarantee the continuous operation of solar ORCs is a critical task, and Phase Change Materials (PCM) rely on latent heat to store large amounts of energy. In the present study, a thermal analysis of a PCM for a solar ORC is carried out. Three different types of PCMs are analyzed. The energy equation for the PCM is modeled by using the heat capacity method, and it is solved by employing a 1Dexplicit finite difference scheme. The solar source is modeled with a time-variable temperature boundary condition, with experimental data taken from the literature for two different solar collectors. Results are presented in terms of temperature profiles and stored energy. It has been shown that the stored energy depends on the heat source temperature, on the employed PCM and on the boundary conditions. It has been demonstrated that the use of a metal foam can drastically enhance the stored energy due to the higher overall thermal conductivity.

  14. Output power analyses for the thermodynamic cycles of thermal power plants

    International Nuclear Information System (INIS)

    Sun Chen; Cheng Xue-Tao; Liang Xin-Gang

    2014-01-01

    Thermal power plant is one of the important thermodynamic devices, which is very common in all kinds of power generation systems. In this paper, we use a new concept, entransy loss, as well as exergy destruction, to analyze the single reheating Rankine cycle unit and the single stage steam extraction regenerative Rankine cycle unit in power plants. This is the first time that the concept of entransy loss is applied to the analysis of the power plant Rankine cycles with reheating and steam extraction regeneration. In order to obtain the maximum output power, the operating conditions under variant vapor mass flow rates are optimized numerically, as well as the combustion temperatures and the off-design flow rates of the flue gas. The relationship between the output power and the exergy destruction rate and that between the output power and the entransy loss rate are discussed. It is found that both the minimum exergy destruction rate and the maximum entransy loss rate lead to the maximum output power when the combustion temperature and heat capacity flow rate of the flue gas are prescribed. Unlike the minimum exergy destruction rate, the maximum entransy loss rate is related to the maximum output power when the highest temperature and heat capacity flow rate of the flue gas are not prescribed. (general)

  15. Computational fluid dynamic (CFD) investigation of thermal uniformity in a thermal cycling based calibration chamber for MEMS

    Science.gov (United States)

    Gui, Xulong; Luo, Xiaobing; Wang, Xiaoping; Liu, Sheng

    2015-12-01

    Micro-electrical-mechanical system (MEMS) has become important for many industries such as automotive, home appliance, portable electronics, especially with the emergence of Internet of Things. Volume testing with temperature compensation has been essential in order to provide MEMS based sensors with repeatability, consistency, reliability, and durability, but low cost. Particularly, in the temperature calibration test, temperature uniformity of thermal cycling based calibration chamber becomes more important for obtaining precision sensors, as each sensor is different before the calibration. When sensor samples are loaded into the chamber, we usually open the door of the chamber, then place fixtures into chamber and mount the samples on the fixtures. These operations may affect temperature uniformity in the chamber. In order to study the influencing factors of sample-loading on the temperature uniformity in the chamber during calibration testing, numerical simulation work was conducted first. Temperature field and flow field were simulated in empty chamber, chamber with open door, chamber with samples, and chamber with fixtures, respectively. By simulation, it was found that opening chamber door, sample size and number of fixture layers all have effects on flow field and temperature field. By experimental validation, it was found that the measured temperature value was consistent with the simulated temperature value.

  16. Speciation of mercury in soils and sediments by thermal evaporation and cold vapor atomic absorption

    International Nuclear Information System (INIS)

    Bombach, G.; Bombach, K.; Klemm, W.

    1994-01-01

    Evaporation studies of mercury in several chemical compounds, soils, and sediments with a high content of organic matter indicate that a quantitative release is possible at temperatures as low as 400 C. The desorption behaviour from a gold column is not influenced. Only from samples with a thermal prehistory, such as brown coal ash, did mercury evaporate at higher temperatures. Qualitative conclusions can be derived about the content of metallic mercury as well as mercury associated with organic matter or sulfide. A comparison of the analytical results obtained by using the evaporation technique or by dissolving using a mixture of conc. HCl and HNO 3 shows good agreement; the advantages of the evaporation technique are obvious at very low mercury concentrations. (orig.)

  17. Effects of variations in coating materials and process conditions on the thermal cycle properties of NiCrAlY/YSZ thermal barrier coatings

    Energy Technology Data Exchange (ETDEWEB)

    Tang Feng [Department of Chemical Engineering and Materials Science, University of California, Davis, CA 95616 (United States)]. E-mail: ftang@ucdavis.edu; Ajdelsztajn, Leonardo [Department of Chemical Engineering and Materials Science, University of California, Davis, CA 95616 (United States); Kim, George E. [Perpetual Technologies, Montreal, Que., H3E 1T8 (Canada); Provenzano, Virgil [National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States); Schoenung, Julie M. [Department of Chemical Engineering and Materials Science, University of California, Davis, CA 95616 (United States)

    2006-06-15

    Thermal cycle tests were conducted on a variety of thermal barrier coating (TBC) specimens with bond coats that had been prepared in different ways. Variables include: (1) different thermal spray processes (high velocity oxy-fuel (HVOF) spray and low pressure plasma spray (LPPS)) (2) different feedstock powder (gas-atomized and cryomilled) (3) the introduction of nano-sized alumina additives (particles and whiskers) and (4) with and without a post-spray vacuum heat treatment. The results show that the cryomilling of the NiCrAlY powder and the post-spray heat treatment in vacuum can both lead to significant improvement in the thermal cycle lifetime of the TBCs. The TBC specimens with LPPS bond coats also generally showed longer lifetimes than those with HVOF bond coats. In contrast, the intentional dispersion of alumina particles or whiskers in the NiCrAlY powders during cryomilling did not result in the further improvement of the lifetime of the TBCs. Microstructural evolution, including the thermally grown oxide (TGO) formation, the distribution of the dispersoids in the bond coat, the internal oxidation of the bond coat, the bond coat shrinkage during the thermal cycle tests and the reduction of the ZrO{sub 2} in the top coat during the heat treatment in vacuum, was investigated.

  18. One thousand thermal cycles of magnesium chloride hexahydrate as a promising PCM for indoor solar cooking

    International Nuclear Information System (INIS)

    El-Sebaii, A.A.; Al-Heniti, S.; Al-Agel, F.; Al-Ghamdi, A.A.; Al-Marzouki, F.

    2011-01-01

    Research highlights: → Solar cookers must contain a PCM for cooking indoors. → MgCl 2 .6H 2 O when it cycled in a sealed container. → MgCl 2 .6H 2 O shows maximum of 0.1-3.5 o C of supercooling. → MgCl 2 .6H 2 O is a promising PCM for thermal energy storage. -- Abstract: Cooking is the major necessity for people all over the world. It accounts for a major share of energy consumption in developing countries. There is a critical need for the development of alternative, appropriate, affordable methods of cooking for use in developing countries. There is a history for solar cooking since 1650 where they are broadly divided into direct or focusing type, box-type and indirect or advanced solar cookers. The advanced solar cookers have the advantage of being usable indoors and thus solve one of the problems, which impede the social acceptance of solar cookers. The advanced type solar cookers are employing additional solar units that increase the cost. Therefore, the solar cooker must contain a heat storage medium to store thermal energy for use during off-sunshine hours. The main aim of this paper is to investigate the influence of the melting/solidification fast thermal cycling of commercial grade magnesium chloride hexahydrate (MgCl 2 .6H 2 O) on its thermo-physical properties; such as melting point and latent heat of fusion, to be used as a storage medium inside solar cookers. One thousand cycles have been performed in a sealed container under the extra water principle. The thermo-physical properties are measured using the differential scanning calorimetric technique. It is indicated that MgCl 2 .6H 2 O with the extra water principle and hermetically sealing of the container is a promising phase change material (PCM) for cooking indoors and during law intensity solar radiation periods. It is also found from the melting/solidification behavior of MgCl 2 .6H 2 O that it is solidify almost without supercooling; except in few cases where it showed maximum of 0

  19. Effect of long-term hydrogen absorption/desorption cycling on hydrogen storage properties of MmNi3.55Co0.75Mn0.4Al0.3

    International Nuclear Information System (INIS)

    Li, S.L.; Chen, W.; Chen, D.M.; Yang, K.

    2009-01-01

    The effect of a long-term hydrogen absorption/desorption cycling up to 2000 cycles on the hydrogen storage properties of MmNi 3.55 Co 0.75 Mn 0.4 Al 0.3 alloy was investigated. The pressure-composition (PC) isotherms for absorption/desorption and absorption kinetics were measured at 338 K, 353 K and 368 K both after initial activation and 2000 cycles. X-ray diffraction analysis revealed that the alloy had a homogeneous hexagonal CaCu 5 type structure and kept this structure even after 2000 hydrogen absorption/desorption cycles. It is found that the absorption/desorption plateau pressures were lowered, the storage capacity and the absorption kinetics were slightly degraded and the hysteresis loss was increased at all the investigated temperatures after 2000 cycles. It is also found that the particle size after 2000 cycles was much smaller compared to that after initial activation. The change of the hydrogen absorption/desorption properties of the alloy after 2000 cycles has been explained by considering the crystal structure, disproportionation property, pulverization of the sample and the impurities in the charging hydrogen employed in cycling

  20. Fast thermal cycling of acetanilide and magnesium chloride hexahydrate for indoor solar cooking

    Energy Technology Data Exchange (ETDEWEB)

    El-Sebaii, A.A.; Al-Amir, S.; Al-Marzouki, F.M.; Faidah, Adel S.; Al-Ghamdi, A.A.; Al-Heniti, S. [Physics Dept., Faculty of Science, King Abdul Aziz Univ., P.O. Box 80203, Jeddah 21589 (Saudi Arabia)

    2009-12-15

    Solar cookers are broadly divided into a direct or focusing type, indirect or box-type and advanced solar cookers. The focusing and box-type solar cookers are for outdoor applications. The advanced solar cookers have the advantage of being usable indoors and thus solve one of the problems, which impede the social acceptance of solar cookers. The advanced type solar cookers are employing additional solar units that increase the cost. Therefore, the solar cooker must contain a heat storage medium to store thermal energy for use during off-sunshine hours. The main aim of this study is to investigate the influence of the melting/solidification fast cycling of the commercial grade acetanilide C{sub 8}H{sub 9}NO (T{sub m} = 116 C) and magnesium chloride hexahydrate MgCl{sub 2}.6H{sub 2}O (T{sub m} = 116.7 C) on their thermo-physical properties; such as melting point and latent heat of fusion, to be used as storage media inside solar cookers. Five hundred cycles have been performed. The thermo-physical properties are measured using the differential scanning calorimetric technique. The compatibility of the selected phase change materials (PCMs) with the containing material is also studied via the surface investigation, using the SIM technique, of aluminum and stainless steel samples embedded in the PCM during cycling. It is inferred that acetanilide is a promising PCM for cooking indoors and during low intensity solar radiation periods with good compatibility with aluminum as a containing material. However, MgCl{sub 2}.6H{sub 2}O is not stable during its thermal cycling (even with the extra water principle) due to the phase segregation problem; therefore, it is not recommended as a storage material inside solar cookers for cooking indoors. It is also indicated that MgCl{sub 2}.6H{sub 2}O is not compatible with either aluminum or stainless steel. (author)

  1. Thermal, mechanical, and moisture absorption properties of egg white protein bioplastics with natural rubber and glycerol.

    Science.gov (United States)

    Jones, Alexander; Zeller, Mark Ashton; Sharma, Suraj

    2013-07-03

    Petroleum-based plastics have many drawbacks: the large amount of energy required to produce the plastic, the waste generated as a result of plastic production, and the accumulation of waste due to slow degradation rate. It is because of these negative attributes of conventional plastic use that attention is being focused on environmentally friendly plastics from alternative sources. Albumin protein provides one possible source of raw material, with inherent antimicrobial properties that may make it suitable for medical applications. We conducted this study to investigate the various bioplastic properties of the albumin with the use of three plasticizers - water, glycerol, and natural rubber latex. Based on results, 75:25 albumin-water, 75:25 albumin-glycerol, and 80:20 albumin-natural rubber were the best blending ratios for each plasticizer for a subsequent time study to determine water stability, with the 80:20 albumin-natural rubber blend ratio having possessed the best thermal, tensile, and viscoelastic properties overall.

  2. Effect of AgCl NPs: Physical, thermal, absorption and luminescence properties

    Science.gov (United States)

    Nurhafizah, H.; Rohani, M. S.

    2017-06-01

    Silver nanoparticles (AgCl NPs) are embedded in Er3+/Nd3+ co-doped lithium niobate tellurite glasses of the form (68-x)TeO2-15Li2CO3-15Nb2O5-1Er2O3-1Nd2O3-(x)AgCl with x = 1,2 and 3 mol% via conventional melt-quenching technique. The physical properties such as density, ionic packing density, refractive index and electronic polarizability are computed utilizing the usual method. The existence of AgCl NPs with an average size of 3.7 nm is confirmed using TEM analysis. Moreover, the thermal stability and Hruby criterion of the glass decreases as the AgCl NPs content increases. The direct optical band gap are found decrease as the AgCl NPs content increase, but both indirect optical band gap and Urbach energy are found increases as AgCl NPs content increases. The luminescence spectra shows two strong emission which is the purple emission at 436 nm and red emission at 724 nm which also been observed has strong quenching due to the AgCl NPs, Er3+/Nd3+ dopant and modifier, lithium niobate which possessed magnetic penetration. These glass compositions may be potential for various applications such as solid state devices including laser.

  3. Precipitate evolution in underaged Al-Mg-Si alloy during thermal cycling between 25 deg. C and 65 deg. C

    International Nuclear Information System (INIS)

    Uan, J.-Y.; Cho, C.-Y.; Chen, Z.-M.; Lin, J.-K.

    2006-01-01

    The evolution of metastable precipitates and the aging response in underaged Al-Mg-Si alloy during environmental temperature cycling was investigated using transmission electron microscopy (TEM) and hardness tests. After the alloy underwent thermal cycling between 25 deg. C and 65 deg. C, the hardness tests revealed that hardness decreased slightly, rather than following a concave downward curve, with the cycle times. Needle-shaped G.P. zones transformed during the environmental thermal cycling. The fraction of the zones declined sharply from almost 100% to only approximately 10% after 90 cycles, accompanied by an increase in the fraction of lath-shaped precipitates and the formation of β'' precipitates in the matrix. The precipitate developed with the 25-65 deg. C cycling time as follows: needle-shaped G.P. zones → lath-shaped ppt + β'' ppt + needle-shaped G.P. zones → lath-shaped ppt + β'' ppt + rod-shaped ppt + needle-shaped G.P. zones. Therefore, three or four precipitates coexisted in the underaged alloy following prolonged cycling. The formation of a limited number of β'' precipitates and the presence of a rod-shaped phase in the alloy during environmental temperature cycling reduced the hardness as the cycle time increases

  4. Oxidation behavior of Hf-modified platinum aluminide coatings during thermal cycling

    Directory of Open Access Journals (Sweden)

    Liya Ye

    2018-02-01

    Full Text Available Platinum aluminide coatings with different Hf contents were fabricated by using HfCl4. The oxidation kinetics and the rumpling behavior of oxide scale were investigated. After thermal cycling, the coating with 0.46 wt% Hf showed least weight gain. With the increase of Hf content, rumpling extent of the scale decreased. Meanwhile, HfO2 preferentially formed in the scale resulting in the increase of scale thickness. The oxidation of excessive Hf even caused the spallation of the scale. The results in the present study indicate that although Hf plays an important role in decreasing rumpling extent of TGO, the oxidation of Hf decreases the adhesion of the scale. Keywords: Pt-Al coating, Hf, Oxidation, Rumpling

  5. Thermal cycling tests on Li4SiO4 and beryllium pebbles

    International Nuclear Information System (INIS)

    Dalle Donne, M.; Norajitra, P.; Weisenburger, A.

    1995-01-01

    The European B.O.T. Demo-relevant solid breeder blanket is based on the use of beds of beryllium and Li 4 SiO 4 pebbles. Particularly dangerous for the pebble integrity are the rapid temperature changes which could occur, for instance, by a sudden blanket power shut-down. A series of thermal cycle tests have been performed for various beds of beryllium and Li 4 SiO 4 pebbles. No breaking was observed in the beryllium pebbles, however the Li 4 SiO 4 pebbles broke by temperature rates of change of about -50 C/sec independently on pebbles size and lithium enrichment. This value is considerably higher than the peak temperature rates of change expected in the blanket. (orig.)

  6. The Effect of Thermal Cycling on Crystal-Liquid Separation During Lunar Magma Ocean Differentiation

    Science.gov (United States)

    Mills, Ryan D.

    2013-01-01

    Differentiation of magma oceans likely involves a mixture of fractional and equilibrium crystallization [1]. The existence of: 1) large volumes of anorthosite in the lunar highlands and 2) the incompatible- rich (KREEP) reservoir suggests that fractional crystallization may have dominated during differentiation of the Moon. For this to have occurred, crystal fractionation must have been remarkably efficient. Several authors [e.g. 2, 3] have hypothesized that equilibrium crystallization would have dominated early in differentiation of magma oceans because of crystal entrainment during turbulent convection. However, recent numerical modeling [4] suggests that crystal settling could have occurred throughout the entire solidification history of the lunar magma ocean if crystals were large and crystal fraction was low. These results indicate that the crystal size distribution could have played an important role in differentiation of the lunar magma ocean. Here, I suggest that thermal cycling from tidal heating during lunar magma ocean crystallization caused crystals to coarsen, leading to efficient crystal-liquid separation.

  7. Thermal stability of chloroform in the steam condensate cycle of CANDU-PHW nuclear power plant

    International Nuclear Information System (INIS)

    Lepine, Louis; Gilbert, Roland; Ouellet, Lorenzo

    1992-01-01

    Analysis of samples taken at the Gentilly 2 (Quebec) CANDU-PHW (CANadian Deuterium Uranium - Pressurized Heavy Water) plant after chlorination and demineralization revealed the presence of all four trihalomethanes (THMs) (CHCl 3 , CHBrCl 2 , CHBr 2 Cl and CHBr 3 ) and other unidentified halogenated volatile compounds. Among the THMs, chloroform was the major contaminant. A study of its thermal stability in water at different temperatures confirmed the degradation of the CHCl 3 molecule according to the equation CHCl 3 + H2O → CO + 3 HCl. The reaction follows first order kinetics and has an activation energy of 100 kJ/mol. The estimated half-life is six seconds at 260 deg C, the maximum temperature of the steam condensate cycle

  8. Reliability of lead-free solder joints with different PCB surface finishes under thermal cycling

    Energy Technology Data Exchange (ETDEWEB)

    Xia Yanghua [State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050 (China)], E-mail: xia_yanghua@hotmail.com; Xie Xiaoming [State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050 (China)

    2008-04-24

    The reliability of lead-free electronic assemblies under thermal cycling was investigated. Thin small outline package (TSOP) devices with FeNi leads were reflow soldered on FR4 PCB (printed circuit board) with Sn3.0Ag0.5Cu (wt%) solder. The effects of different PCB finishes (organic solderability preservative (OSP) and electroless nickel immersion gold (ENIG)) were studied. The results show that OSP finish reveals better performance than its ENIG counterparts. The crack originates at the fringe of heel fillet in both cases. The propagation of crack in the ENIG case is along the device/solder interface, while in the case of OSP, the crack extends parallel to the solder/PCB interface. When the OSP finishes are employed, many Cu6Sn5 precipitates form inside the bulk solder and have a strengthening effect on the solder joint, resulting in better reliability performance as compared to those with ENIG finishes.

  9. Effect of the combined stress on the life of components under thermal cycling conditions

    International Nuclear Information System (INIS)

    Zuchowski, R.; Zietkowski, L.

    1987-01-01

    The life of structural components subjected to temperature changes is affected, among other factors, by the nature of the stress field. If life prediction for axially stressed components can be accomplished with a number of well established techniques, the behaviour under a complex state of stress and varying temperature conditions still is the object of intensive research. The present study was aimed at assessing the influence of the stress field upon the life of specimens made of chromium-nickel H23N18 steel under thermal cycling conditions. The designation of steel is in accordance with Polish Standards. The experiments were made on thin-walled tubular specimens loaded with various combinations of a static axial force and a static torque. (orig./GL)

  10. An expression for the atomic fluorescence and thermal-emission intensity under conditions of near saturation and arbitrary self-absorption

    NARCIS (Netherlands)

    Omenetto, N.; Winefordner, J.D.; Alkemade, C.T.J.

    An expression for the effect of self-absorption on the fluorescence and thermal emission intensities is derived by taking into account stimulated emission. A simple, idealized case is considered, consisting of a two level atomic system, in a flame, homogeneous with respect to temperature and

  11. Study of cyclic thermal aging of tube type receivers as a function of the duration of the cycle

    Science.gov (United States)

    Setien, Eneko; Fernández-Reche, Jesús; Ariza, María Jesús; Álvarez-de-Lara, Mónica

    2017-06-01

    The tube type receivers are exposed to variable duration cyclic operating conditions, which can jeopardize its reliability, and make it hard to estimate its long term performance. The designers have to deal with this problem and estimate the receiver long term performance based on the poor available litterature and the data sheets of the material. In order to help the designer better estimate the performance of the receivers, in this paper the cyclic thermal aging is analyzed as a function of the cycle duration. For this purpose, coated and uncoated Inconel alloy 625 tubular samples, similar to those used in the commercial receivers, are cyclically aged with different thermal cycle duration. The aging of these samples has been analyzed by means of oxidation kinetics, microstructure examination and mechanical and optical properties. The effect of the thermal cycle duration is studied and discussed by comparison of the results.

  12. Simultaneous measurement of thermal diffusivity and effective infrared absorption coefficient in IR semitransparent and semiconducting n-CdMgSe crystals using photothermal radiometry

    Energy Technology Data Exchange (ETDEWEB)

    Pawlak, M., E-mail: mpawlak@fizyka.umk.pl [Institute of Physics, Faculty of Physics, Astronomy and Informatics, Nicolaus Copernicus University, Grudziądzka 5/7, Toruń (Poland); Maliński, M. [Department of Electronics and Computer Science, Koszalin University of Technology, 2 Śniadeckich St., Koszalin 75-453 (Poland)

    2015-01-10

    Highlights: • The new method of determination of the effective infrared absorption coefficient is presented. • The method can be used for transparent samples for the excitation radiation. • The effect of aluminum foil on the PTR signal in a transmission configuration is discussed. - Abstract: In this paper we propose a new procedure of simultaneous estimation of the effective infrared optical absorption coefficient and the thermal diffusivity of solid state samples using the photothermal infrared radiometry method in the transmission configuration. The proposed procedure relies on the analysis of the frequency dependent signal obtained from the samples covered with thin aluminum foil. This method can be applied for both optically opaque and transparent samples. The proposed method is illustrated with the results of the thermal diffusivity and the effective IR absorption coefficient obtained for several Cd{sub 1−x}Mg{sub x}Se crystals.

  13. Ion irradiation and thermal cycling tests of TiC coatings

    International Nuclear Information System (INIS)

    Yamanaka, S.; Ohara, H.; Son, P.; Miyake, M.

    1984-01-01

    Ion irradiation of TiC coatings prepared by diffusion annealing was performed with 20-40 keV He + ions for different doses at room temperature. The polished TiCsub(0.99) coatings irradiated with 40 keV He + ions showed the surface damage and erosion due to blistering and exfoliation above a dose of 1.8x10 17 ions/cm 2 , whereas no change in the surface morphology could be detected for the as-prepared coatings up to a dose of 1.4x10 18 ions/cm 2 . The results suggested that surface erosion due to blistering can be effectively reduced on the rough surface of the as-prepared TiC coating. The average blister diameter in the polished TiCsub(0.99) coating increased with increasing projectile energy. For the 40 keV He + ion irradiation of the polished TiCsub(0.5) coatings, general features in blisters were similar to those observed for the TiCsub(0.99) coatings, but the critical dose for blistering shifted to a higher value in comparison with the polished TiCsub(0.99) coating. Thermal cycling between 500 and 1200 0 C caused serious surface damage for the TiCsub(0.99) coating irradiated with 40 keV He + ions below the critical dose for blistering, while the coating with surface damage due to blistering showed no significant change in the surface topography after thermal cycling. (orig.)

  14. Effect of grit blasting on the thermal cycling behavior of diffusion aluminide/YSZ TBCs

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Zhenhua, E-mail: zhxuciac@163.com; Huang, Guanghong; He, Limin; Mu, Rende; Wang, Kai; Dai, Jianwei

    2014-02-15

    Highlights: • TBCs including of CVD NiAl bond coat and EB-PVD YSZ ceramic coating with and without grit blasting process. • Grain boundary ridges are the sites for spallation damage initiation in aluminide/YSZ TBCs. • Ridges are removed, and no cavity formation and this damage initiation mode are suppressed. • Damage initiation and progression occurs at the bond coat to TGO interface leading to a buckling failure behavior. -- Abstract: Thermal barrier coating system (TBCs) including of chemical vapor deposited NiAl bond coat and electron beam physical vapor deposited Y{sub 2}O{sub 3}–stabilized-ZrO{sub 2} (YSZ) ceramic coating with and without grit blasting process were investigated. The phase structures, surface and cross-sectional morphologies, cyclic oxidation behaviors of these coatings were studied in detail. Grain boundary ridges form on the surface of aluminide bond coat prior to the deposition of the ceramic coating by EB-PVD, which are shown to be the sites for spallation damage initiation in aluminide/YSZ TBCs. When these ridges are removed, there is no cavity formation and this damage initiation mode is suppressed. Damage initiation and progression occurs at the bond coat to TGO interface leading to a buckling failure behavior. A buckle failure once started may be arrested when it runs into a region of high bond coat to TGO interface toughness. Thus, complete failure requires further loss in toughness of the bond coat to TGO interface with additional cycling. From the result of thermal cycling, an averaged four folds lifetime improvement can be achieved with samples after grit blasting of bond coat surface as compared with those samples existence in ridges on the bond coats’ surface.

  15. Fundamental-frequency and load-varying thermal cycles effects on lifetime estimation of DFIG power converter

    DEFF Research Database (Denmark)

    Zhang, G.; Zhou, D.; Yang, J.

    2017-01-01

    In respect to a Doubly-Fed Induction Generator (DFIG) system, its corresponding time scale varies from microsecond level of power semiconductor switching to second level of the mechanical response. In order to map annual thermal profile of the power semiconductors, different approaches have been ...... adopted to handle the fundamental-frequency thermal cycles and load-varying thermal cycles. Their effects on lifetime estimation of the power device in the Back-to-Back (BTB) power converter are evaluated.......In respect to a Doubly-Fed Induction Generator (DFIG) system, its corresponding time scale varies from microsecond level of power semiconductor switching to second level of the mechanical response. In order to map annual thermal profile of the power semiconductors, different approaches have been...

  16. Evaluation of Electroless-Nickel Plated Polypropylene under Thermal Cycling and Mechanical Tests

    Directory of Open Access Journals (Sweden)

    O.O. Ajibola

    2016-09-01

    Full Text Available The electroless-nickel composite (ENC consisting of bright metallic electroless-nickel (EN and dull electroless-nickel-phosphorus (EN-P were deposited on the polypropylene (PP substrate from the sodium hypophosphite baths. The ENC plated specimens were subjected to abrasive wear-adhesion test of 1750, 3500, 7000 and 14000 cycles; thermal cycle-adhesion tests, and tensile strength and creep tests. The deposition of ENC influenced the strength and creep strain properties of the PP. The maximum stress σ of 118 (MPa was obtained from EN-PP specimen at strain  of 0.1 mm/mm as compared with the PP having stress σ of 36 (MPa at strain  of 0.07 mm/mm before failure The surface appearances and microstructures of ENC film on PP substrates were examined under the higher resolution metallurgical microscope with digital camera and microscopic camera. The composition of ENC film was characterized using Scanning Electron Microscopy and Energy Dispersive X-Ray analyses (Jeol JSM-7600F Field Emission SEM/EDX, The micrographs and spectra lines data generated were used to interpret the results.

  17. Efficiency Study of a Commercial Thermoelectric Power Generator (TEG) Under Thermal Cycling

    Science.gov (United States)

    Hatzikraniotis, E.; Zorbas, K. T.; Samaras, I.; Kyratsi, Th.; Paraskevopoulos, K. M.

    2010-09-01

    Thermoelectric generators (TEGs) make use of the Seebeck effect in semiconductors for the direct conversion of heat to electrical energy. The possible use of a device consisting of numerous TEG modules for waste heat recovery from an internal combustion (IC) engine could considerably help worldwide efforts towards energy saving. However, commercially available TEGs operate at temperatures much lower than the actual operating temperature range in the exhaust pipe of an automobile, which could cause structural failure of the thermoelectric elements. Furthermore, continuous thermal cycling could lead to reduced efficiency and lifetime of the TEG. In this work we investigate the long-term performance and stability of a commercially available TEG under temperature and power cycling. The module was subjected to sequential hot-side heating (at 200°C) and cooling for long times (3000 h) in order to measure changes in the TEG’s performance. A reduction in Seebeck coefficient and an increase in resistivity were observed. Alternating-current (AC) impedance measurements and scanning electron microscope (SEM) observations were performed on the module, and results are presented and discussed.

  18. Thermal Conductivity Changes Due to Degradation of Cathode Film Subjected to Charge-Discharge Cycles in a Li Ion Battery

    Science.gov (United States)

    Jagannadham, K.

    2018-05-01

    A battery device with graphene platelets as anode, lithium nickel manganese oxide as cathode, and solid-state electrolyte consisting of layers of lithium phosphorous oxynitride and lithium lanthanum titanate is assembled on the stainless steel substrate. The battery in a polymer enclosure is subjected to several electrical tests consisting of charge and discharge cycles at different current and voltage levels. Thermal conductivity of the cathode layer is determined at the end of charge-discharge cycles using transient thermoreflectance. The microstructure and composition of the cathode layer and the interface between the cathode, the anode, and the electrolyte are characterized using scanning electron microscopy and elemental mapping. The decrease in the thermal conductivity of the same cathode observed after each set of electrical test cycles is correlated with the volume changes and formation of low ionic and thermal conductivity lithium oxide and lithium oxychloride at the interface and along porous regions. The interface between the metal current collector and the cathode is also found to be responsible for the increase in thermal resistance. The results indicate that changes in the thermal conductivity of the electrodes provide a measure of the resistance to heat transfer and degradation of ionic transport in the cathode accompanying the charge-discharge cycles in the batteries.

  19. Use of Guided Acoustic Waves to Assess the Effects of Thermal-Mechanical Cycling on Composite Stiffness

    Science.gov (United States)

    Seale, Michael D.; Madaras, Eric I.

    2000-01-01

    The introduction of new, advanced composite materials into aviation systems requires it thorough understanding of the long-term effects of combined thermal and mechanical loading. As part of a study to evaluate the effects of thermal-mechanical cycling, it guided acoustic (Lamb) wave measurement system was used to measure the bending and out-of-plane stiffness coefficients of composite laminates undergoing thermal-mechanical loading. The system uses a pulse/receive technique that excites an antisymmetric Lamb mode and measures the time-of-flight over a wide frequency range. Given the material density and plate thickness, the bending and out-of-plane shear stiffnesses are calculated from a reconstruction of the velocity dispersion curve. A series of 16 and 32-ply composite laminates were subjected to it thermal-mechanical loading profile in load frames equipped with special environmental chambers. The composite systems studied were it graphite fiber reinforced amorphous thermoplastic polyimide and it graphite fiber reinforced bismaleimide thermoset. The samples were exposed to both high and low temperature extremes its well as high and low strain profiles. The bending and out-of-plane stiffnesses for composite sample that have undergone over 6,000 cycles of thermal-mechanical loading are reported. The Lamb wave generated elastic stiffness results have shown decreases of up to 20% at 4,936 loading cycles for the graphite/thermoplastic samples and up to 64% at 4,706 loading cycles for the graphite/thermoset samples.

  20. Evaluation of the properties of anodized aluminum 6061 subjected to thermal cycling treatment using electrochemical impedance spectroscopy (EIS)

    Energy Technology Data Exchange (ETDEWEB)

    Huang Yuelong [Corrosion and Environmental Effects Laboratory (CEEL), Mork Family Department of Chemical Engineering and Materials Science, University of Southern California, Los Angeles, CA 90089-0241 (United States); Shih Hong [Lam Research Corporation, 4400 Cushing Parkway, Fremont, CA 94538 (United States)], E-mail: hong.shih@lamrc.com; Daugherty, John [Lam Research Corporation, 4400 Cushing Parkway, Fremont, CA 94538 (United States); Mansfeld, Florian [Corrosion and Environmental Effects Laboratory (CEEL), Mork Family Department of Chemical Engineering and Materials Science, University of Southern California, Los Angeles, CA 90089-0241 (United States)], E-mail: mansfeld@usc.edu

    2009-10-15

    The corrosion resistance of anodized Al 6061 produced by two different anodizing and sealing processes was evaluated for 30 days during exposure to 3.5 wt% NaCl using EIS. Thermal cycling treatments at 120, 160 and 200 deg. C have been applied for the two types of samples. The degradation of the properties of the anodized layers has been determined by thorough analysis of the EIS data for control samples and samples that had undergone thermal cycling. Scanning electron microscopy has been used to evaluate the damage to the anodized aluminum layers due to thermal cycling. It was found that the thermal treatment produced considerable damage of both the porous layer and the barrier layer. The EIS data suggest that some cracks extended into the bare metal. The damage of the oxide layers increased with increasing thermal cycling temperature for both types of samples. Self-sealing of the porous layer and the barrier layer occurred during immersion in NaCl.

  1. Effect of thermal mass on life cycle primary energy balances of a concrete- and a wood-frame building

    International Nuclear Information System (INIS)

    Dodoo, Ambrose; Gustavsson, Leif; Sathre, Roger

    2012-01-01

    Highlights: ► The effect of thermal mass on life cycle primary energy balance of concrete and wood building is analyzed. ► A concrete building has slightly lower space heating demand than a wood alternative. ► Still, a wood building has a lower life cycle primary energy use than a concrete alternative. ► The influence of thermal mass on space heating energy use for buildings in Nordic climate is small. -- Abstract: In this study we analyze the effect of thermal mass on space heating energy use and life cycle primary energy balances of a concrete- and a wood-frame building. The analysis includes primary energy use during the production, operation, and end-of-life phases. Based on hour-by-hour dynamic modeling of heat flows in building mass configurations we calculate the energy saving benefits of thermal mass during the operation phase of the buildings. Our results indicate that the energy savings due to thermal mass is small and varies with the climatic location and energy efficiency levels of the buildings. A concrete-frame building has slightly lower space heating demand than a wood-frame alternative, due to the higher thermal mass of concrete-based materials. Still, a wood-frame building has a lower life cycle primary energy balance than a concrete-frame alternative. This is due primarily to the lower production primary energy use and greater bioenergy recovery benefits of the wood-frame buildings. These advantages outweigh the energy saving benefits of thermal mass. We conclude that the influence of thermal mass on space heating energy use for buildings located in Nordic climate is small and that wood-frame buildings with cogeneration based district heating would be an effective means of reducing primary energy use in the built environment.

  2. Efficient cycle jumping techniques for the modelling of materials and structures under cyclic mechanical and thermal loading

    International Nuclear Information System (INIS)

    Dunne, F.P.E.; Hayhurst, D.R.

    1994-01-01

    Highly efficient cycle jumping algorithms have been developed for the calculation of stress and damage histories for both cyclic mechanical and cycle thermal loading. The techniques have been shown to be suitable for cyclic plasticity; creep-cyclic plasticity interaction; and creep dominated material behaviour. The cycle jumping algorithms have been validated by comparison of the predictions made using both the cycle jumping technique, and the full calculation involving the integration of the equations around all cycles. Excellent agreement has been achieved, and significant reductions in computer processing time of up to 90% have been obtained by using the cycle jumping technique. A further cycle jumping technique has been developed for full component analysis, using a viscoplastic damage finite element solver, which enables stress redistribution to be modelled. The behaviour and lifetime of a slag tap component has been predicted when subjected to cyclic thermal loading. Cyclic plasticity damage and micro-crack initiation is predicted to occur at the water cooling duct after 2.974 cycles, with damage and micro-crack evolution arresting after 60.000. (author). 18 refs., 13 figs., 4 photos

  3. Improvement of high voltage cycling performance and thermal stability of lithium-ion cells by use of a thiophene additive

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Ki-Soo; Sun, Yang-Kook; Kim, Dong-Won [Department of Chemical Engineering, Hanyang University, Seungdong-gu, Seoul 133-791 (Korea); Noh, Jaegeun [Department of Chemistry, Hanyang University, Seungdong-gu, Seoul 133-791 (Korea); Song, Kwang Soup [Advanced Medical Device Center, Korea Electrotechnology, Research Institute, Ansan, Gyeonggi-do 426-170 (Korea)

    2009-10-15

    This study demonstrates that the addition of thiophene improves the cycle life of lithium-ion cells at high voltage. Electrochemical impedance spectroscopy results suggest that addition of thiophene significantly suppresses the increase of the charge transfer resistance that occurs during cycling up to high voltage. Differential scanning calorimetric studies showed that the thermal stability of fully charged LiCoO{sub 2} cathode was also enhanced in the presence of thiophene. (author)

  4. Fatigue life of fibre reinforced plastics at 295 K after thermal cycling between 295 K and 77 K

    Science.gov (United States)

    Belisario, G.; Caproni, F.; Marchetti, E.

    Results of low cycle three-point end fatigue tests at 295 K are reported. These were obtained from fibre reinforced plastics (FRP) flat specimens made of epoxy matrix reinforced with glass rovings only or glass rovings and Kevlar cloth. It is shown that previous thermal cycles between 295 K and 77 K exert an influence on the fatigue life as well on the acoustic emission results.

  5. Continental growth and mantle hydration as intertwined feedback cycles in the thermal evolution of Earth

    Science.gov (United States)

    Höning, Dennis; Spohn, Tilman

    2016-06-01

    A model of Earth's continental coverage and mantle water budget is discussed along with its thermal evolution. The model links a thermal evolution model based on parameterized mantle convection with a model of a generic subduction zone that includes the oceanic crust and a sedimentary layer as carriers of water. Part of the subducted water is used to produce continental crust while the remainder is subducted into the mantle. The total length of the subduction zones is calculated from the total surface area of continental crust assuming randomly distributed continents. The mantle viscosity is dependent of temperature and the water concentration. Sediments are generated by continental crust erosion, and water outgassing at mid-oceanic ridges closes the water cycle. We discuss the strongly coupled, non-linear model using a phase plane defined by the continental coverage and mantle water concentration. Fixed points are found in the phase plane at which the rates of change of both variables are zero. These fixed points evolve with time, but in many cases, three fixed points emerge of which two are stable and an intermediate point is unstable with respect to continental coverage. With initial conditions from a Monte-Carlo scheme we calculate evolution paths in the phase plane and find a large spread of final states that all have a mostly balanced water budget. The present day observed 40% continental surface coverage is found near the unstable fixed point. Our evolution model suggests that Earth's continental coverage formed early and has been stable for at least 1.5 Gyr. The effect of mantle water regassing (and mantle viscosity depending on water concentration) is found to lower the present day mantle temperature by about 120 K, but the present day mantle viscosity is affected little. The water cycle thus complements the well-known thermostat effect of viscosity and mantle temperature. Our results further suggest that the biosphere could impact the feedback cycles by

  6. Volumetric Heat Generation and Consequence Raise in Temperature Due to Absorption of Neutrons from Thermal up to 14.9 MeV Energies

    CERN Document Server

    Massoud, E

    2003-01-01

    In this work, the heat generation rate and the consequence rise in temperature due to absorption of all neutrons from thermal energies (E<0.025) up to 14.9 MeV in water, paraffin wax, ordinary concrete and heavy concrete and heavy concrete as some selected hydrogenous materials are investigated. The neutron flux distributions are calculated by both ANISN-code and three group method in which the fast neutrons are expressed by the removal cross section concept while the other two groups (epithermal and thermal) are treated by the diffusion equation. The heat generation can be calculated from the neutron macroscopic absorption of each material or mixture multiplied by the corresponding neutron fluxes. The rise in temperature is then calculated by using both of the heat generation and the thermal conductivity of the selected materials. Some results are compared with the available experimental and theoretical data and a good agreement is achieved.

  7. The Effect of Thermal Cycling Treatments on the Thermal Stability and Mechanical Properties of a Ti-Based Bulk Metallic Glass Composite

    Directory of Open Access Journals (Sweden)

    Fan Bu

    2016-11-01

    Full Text Available The effect of thermal cycling treatments on the thermal stability and mechanical properties of a Ti48Zr20Nb12Cu5Be15 bulk metallic glass composite (BMGC has been investigated. Results show that moderate thermal cycles in a temperature range of −196 °C (cryogenic temperature, CT to 25 °C (room temperature, RT or annealing time at CT has not induced obvious changes of thermal stability and then it decreases slightly over critical thermal parameters. In addition, the dendritic second phases with a bcc structure are homogeneously embedded in the amorphous matrix; no visible changes are detected, which shows structural stability. Excellent mechanical properties as high as 1599 MPa yield strength and 34% plastic strain are obtained, and the yield strength and elastic modulus also increase gradually. The effect on the stability is analyzed quantitatively by crystallization kinetics and plastic-flow models, and indicates that the reduction of structural relaxation enthalpy, which is related to the degradation of spatial heterogeneity, reduces thermal stability but does not imperatively deteriorate the plasticity.

  8. Fused deposition modeling (FDM) fabricated part behavior under tensile stress, thermal cycling, and fluid pressure

    Science.gov (United States)

    Hossain, Mohammad Shojib

    using visual feedback method led to an increase in UTS of 16% in XYZ, 7% in XZY, and 22% in ZXY. The FDM fabricated parts using PC were tested under thermal cycling of -30° C to 85° C. A series of experiments were performed (e.g., tensile test, deformation of fabricated part, glass transition measurement) to evaluate the possibility of FDM fabricated parts in the harsh environment (embedded electronics, wiring in automotive industry, etc.). The UTS results showed that the results were not significantly different using statistical analysis after 150 thermal cycles while average Young's modulus increased from 1389 MPa to 1469 MPa after 150 thermal cycles. The highest warping of the specimen was found to be 78 microm which was the result of continuous thermal expansion and contraction. A sealing algorithm was developed using LabVIEW and MATLAB programming. The LabVIEW program was developed to obtain the edge information of each layer of a 3D model part. The MATLAB programming was used to gather the output information from LabVIEW and calculate the suggested RW providing least amount of gap in between rasters and contours. As a result, each layer became sealed and was able to withstand air pressure within a pressure vessel. A test specimen was fabricated according to the developed sealing algorithm parameters and used to show entirely sealed walls capable of withstanding up to 138 kPa air pressure.

  9. Modelling and simulation of an absorption cycle with a blow pump; Modellierung und Simulation eines Absorptionskreislaufes mit einer Blasenpumpe

    Energy Technology Data Exchange (ETDEWEB)

    Buecherl, Markus

    2011-07-01

    Diffusion-absorption refrigerators are commonly operated with ammonia and water. If a ionic liquid with negligible vapour pressure is substituted for water, the rectifier will be unnecessary. In the context of a diploma thesis, a diffusion-absorption refrigerator with a blower pump and ammonia and a ionic liquid as working fluid was modelled and simulated. For this, three models were selected from the relevant literature and compared. Changes in COP as a result of varied operating parameters were investigated as well. It was shown that it is possible, in principle, to operate a diffusion-absorption refrigerator with a ionic liquid. [German] Diffusions-Absorptions-Kaeltemaschinen werden in der Regel mit dem Arbeitsstoffpaar Ammoniak-Wasser betrieben. Ersetzt man das Absorptionsmittel Wasser gegen eine ionische Fluessigkeit, die nur einen vernachlaessigbaren Dampfdruck besitzt, kann man den Rektifikator einsparen. Im Rahmen einer Diplomarbeit wurde eine Diffusions-Absorptions-Kaeltemaschine mit einer Blasenpumpe und dem Arbeitsstoffpaar Ammoniak-Ionische Fluessigkeit modelliert und simuliert. Hierfuer wurden drei Modelle aus der Literatur ausgewaehlt. Diese Modelle wurden untereinander verglichen. Ausserdem wurde die Veraenderung des COP bei der Variation der Betriebsparameter fuer diese Berechnungsmodelle untersucht. Es konnte gezeigt werden, dass es prinzipiell moeglich ist, eine Diffusions-Absorptions-Kaeltemaschine mit ionischer Fluessigkeit zu betreiben.

  10. Thermodynamic and design considerations of organic Rankine cycles in combined application with a solar thermal gas turbine

    Science.gov (United States)

    Braun, R.; Kusterer, K.; Sugimoto, T.; Tanimura, K.; Bohn, D.

    2013-12-01

    Concentrated Solar Power (CSP) technologies are considered to provide a significant contribution for the electric power production in the future. Different kinds of technologies are presently in operation or under development, e.g. parabolic troughs, central receivers, solar dish systems and Fresnel reflectors. This paper takes the focus on central receiver technologies, where the solar radiation is concentrated by a field of heliostats in a receiver on the top of a tall tower. To get this CSP technology ready for the future, the system costs have to reduce significantly. The main cost driver in such kind of CSP technologies are the huge amount of heliostats. To reduce the amount of heliostats, and so the investment costs, the efficiency of the energy conversion cycle becomes an important issue. An increase in the cycle efficiency results in a decrease of the solar heliostat field and thus, in a significant cost reduction. The paper presents the results of a thermodynamic model of an Organic Rankine Cycle (ORC) for combined cycle application together with a solar thermal gas turbine. The gas turbine cycle is modeled with an additional intercooler and recuperator and is based on a typical industrial gas turbine in the 2 MW class. The gas turbine has a two stage radial compressor and a three stage axial turbine. The compressed air is preheated within a solar receiver to 950°C before entering the combustor. A hybrid operation of the gas turbine is considered. In order to achieve a further increase of the overall efficiency, the combined operation of the gas turbine and an Organic Rankine Cycle is considered. Therefore an ORC has been set up, which is thermally connected to the gas turbine cycle at two positions. The ORC can be coupled to the solar-thermal gas turbine cycle at the intercooler and after the recuperator. Thus, waste heat from different cycle positions can be transferred to the ORC for additional production of electricity. Within this investigation

  11. Thermal analysis of supercritical CO{sub 2} power cycles: Assessment of their suitability to the forthcoming sodium fast reactors

    Energy Technology Data Exchange (ETDEWEB)

    Perez-Pichel, G.D., E-mail: gdp@icai.es [Rafael Marino Chair on New Energy Technologies, Comillas Pontifical University, Madrid (Spain); Linares, J.I. [Rafael Marino Chair on New Energy Technologies, Comillas Pontifical University, Madrid (Spain); Herranz, L.E.; Moratilla, B.Y. [Unit of Nuclear Safety Research, CIEMAT, Madrid (Spain)

    2012-09-15

    Highlights: Black-Right-Pointing-Pointer This paper investigates the potential use of S-CO{sub 2} cycles in SFRs. Black-Right-Pointing-Pointer A wide range of configurations have been explored. Black-Right-Pointing-Pointer It is feasible to reach a thermal efficiency as high as 43.5%. Black-Right-Pointing-Pointer A sensitivity analysis together with an exergy study have been done. Black-Right-Pointing-Pointer Potential use in SFRs of recompression S-CO{sub 2} cycles for their balance of plant. - Abstract: Sodium fast reactors (SFRs) potential to meet Gen. IV requirements is broadly acknowledged worldwide. The scientific and technological experience accumulated by operating test reactors and, even, by running commercial reactors, makes them be considered as the closest Gen. IV option in the near future. In the past their balance of plant has been always based on Rankine cycles. This paper investigates the potential use of supercritical recompression CO{sub 2} cycles (S-CO{sub 2}) in SFRs on the basis of the working parameters foreseen within the European Sodium Fast Reactor (ESFR) project. A wide range of configurations have been explored, from the simplest one to combined cycles (with organic Rankine cycles, ORC), and a comparison has been set in terms of thermal efficiency. As a result, it has been found out that the most basic configuration could reach a thermal efficiency as high as 43.31%, which is comparable to that obtained through super-critical Rankine cycles proposed elsewhere. A sensitivity analysis together with an exergy study of this configuration, pointed the pre-cooler and IHX{sub Na-CO{sub 2}} as key components in the cycle performance. These results highlight a main conclusion: the potential use in SFRs of recompression S-CO{sub 2} cycles for their balance of plant, whenever a sound and extensive database is built-up on S-CO{sub 2} turbo-machinery and IHX performance.

  12. Thermal analysis of supercritical CO2 power cycles: Assessment of their suitability to the forthcoming sodium fast reactors

    International Nuclear Information System (INIS)

    Pérez-Pichel, G.D.; Linares, J.I.; Herranz, L.E.; Moratilla, B.Y.

    2012-01-01

    Highlights: ► This paper investigates the potential use of S-CO 2 cycles in SFRs. ► A wide range of configurations have been explored. ► It is feasible to reach a thermal efficiency as high as 43.5%. ► A sensitivity analysis together with an exergy study have been done. ► Potential use in SFRs of recompression S-CO 2 cycles for their balance of plant. - Abstract: Sodium fast reactors (SFRs) potential to meet Gen. IV requirements is broadly acknowledged worldwide. The scientific and technological experience accumulated by operating test reactors and, even, by running commercial reactors, makes them be considered as the closest Gen. IV option in the near future. In the past their balance of plant has been always based on Rankine cycles. This paper investigates the potential use of supercritical recompression CO 2 cycles (S-CO 2 ) in SFRs on the basis of the working parameters foreseen within the European Sodium Fast Reactor (ESFR) project. A wide range of configurations have been explored, from the simplest one to combined cycles (with organic Rankine cycles, ORC), and a comparison has been set in terms of thermal efficiency. As a result, it has been found out that the most basic configuration could reach a thermal efficiency as high as 43.31%, which is comparable to that obtained through super-critical Rankine cycles proposed elsewhere. A sensitivity analysis together with an exergy study of this configuration, pointed the pre-cooler and IHX Na–CO 2 as key components in the cycle performance. These results highlight a main conclusion: the potential use in SFRs of recompression S-CO 2 cycles for their balance of plant, whenever a sound and extensive database is built-up on S-CO 2 turbo-machinery and IHX performance.

  13. Thermal neutron absorption cross-section measured on rock samples and brines in the Institute of Nuclear Physics

    International Nuclear Information System (INIS)

    Czubek, J.A.; Drozdowicz, K.; Krynicka-Drozdowicz, E.; Igielski, A.; Woznicka, U.

    1983-01-01

    In consecutive measurements the rock sample (having a fixed and well known shape -in our case it is a sphere or a cylinder and the sample is powdered or liquid) is enveloped in shells of a plexiglass moderator (the neutron parameters of which are known) of variable thickness and irradiated with the pulsed beam of fast neutrons. The die-away rate of thermal neutrons escaping from the whole system is measured. The absorption cross-section of the sample is found as the intersection of the experimental curve (i.e. die -away rate vs thickness of the moderator) with the theoretical one. The theoretical curve is calculated for a given moderator under the assumption of a constant value of the neutron flux inside the sample. This method is independent of the value of the transport cross-section of the sample. It has been checked on artificial materials with a well known elemental composition (liquid or solid) and on the natural brines and rock samples (basalts and dolomite). A special method of calculation of the variance of the measurement has been established. It is based on the multiple computer simulations of all experimental data used in the computation. The one standard deviation of our methods is of the order of 1 up to 3 capture units (1 c.u. = 10 -3 cm -1 ). The volume of the sample needed is of the order of 500ccm. (author)

  14. Ocean Thermal Energy Conversion Life Cycle Cost Assessment, Final Technical Report, 30 May 2012

    Energy Technology Data Exchange (ETDEWEB)

    Martel, Laura [Lockheed Martin, Manassas, VA (United States); Smith, Paul [John Halkyard and Associates: Glosten Associates, Houston, TX (United States); Rizea, Steven [Makai Ocean Engineering, Waimanalo, HI (United States); Van Ryzin, Joe [Makai Ocean Engineering, Waimanalo, HI (United States); Morgan, Charles [Planning Solutions, Inc., Vancouver, WA (United States); Noland, Gary [G. Noland and Associates, Inc., Pleasanton, CA (United States); Pavlosky, Rick [Lockheed Martin, Manassas, VA (United States); Thomas, Michael [Lockheed Martin, Manassas, VA (United States); Halkyard, John [John Halkyard and Associates: Glosten Associates, Houston, TX (United States)

    2012-05-30

    The Ocean Thermal Energy Conversion (OTEC) Life Cycle Cost Assessment (OLCCA) is a study performed by members of the Lockheed Martin (LM) OTEC Team under funding from the Department of Energy (DOE), Award No. DE-EE0002663, dated 01/01/2010. OLCCA objectives are to estimate procurement, operations and maintenance, and overhaul costs for two types of OTEC plants: -Plants moored to the sea floor where the electricity produced by the OTEC plant is directly connected to the grid ashore via a marine power cable (Grid Connected OTEC plants) -Open-ocean grazing OTEC plant-ships producing an energy carrier that is transported to designated ports (Energy Carrier OTEC plants) Costs are developed using the concept of levelized cost of energy established by DOE for use in comparing electricity costs from various generating systems. One area of system costs that had not been developed in detail prior to this analysis was the operations and sustainment (O&S) cost for both types of OTEC plants. Procurement costs, generally referred to as capital expense and O&S costs (operations and maintenance (O&M) costs plus overhaul and replacement costs), are assessed over the 30 year operational life of the plants and an annual annuity calculated to achieve a levelized cost (constant across entire plant life). Dividing this levelized cost by the average annual energy production results in a levelized cost of electricity, or LCOE, for the OTEC plants. Technical and production efficiency enhancements that could result in a lower value of the OTEC LCOE were also explored. The thermal OTEC resource for Oahu, Hawaii and projected build out plan were developed. The estimate of the OTEC resource and LCOE values for the planned OTEC systems enable this information to be displayed as energy supplied versus levelized cost of the supplied energy; this curve is referred to as an Energy Supply Curve. The Oahu Energy Supply Curve represents initial OTEC deployment starting in 2018 and demonstrates the

  15. Performance analysis of a Kalina cycle for a central receiver solar thermal power plant with direct steam generation

    International Nuclear Information System (INIS)

    Modi, Anish; Haglind, Fredrik

    2014-01-01

    Solar thermal power plants have attracted increasing interest in the past few years – with respect to both the design of the various plant components, and extending the operation hours by employing different types of storage systems. One approach to improve the overall plant efficiency is to use direct steam generation with water/steam as both the heat transfer fluid in the solar receivers and the cycle working fluid. This enables operating the plant with higher turbine inlet temperatures. Available literature suggests that it is feasible to use ammonia-water mixtures at high temperatures without corroding the equipment by using suitable additives with the mixture. The purpose of the study reported here was to investigate if there is any benefit of using a Kalina cycle for a direct steam generation, central receiver solar thermal power plant with high live steam temperature (450 °C) and pressure (over 100 bar). Thermodynamic performance of the Kalina cycle in terms of the plant exergy efficiency was evaluated and compared with a simple Rankine cycle. The rates of exergy destruction for the different components in the two cycles were also calculated and compared. The results suggest that the simple Rankine cycle exhibits better performance than the Kalina cycle when the heat input is only from the solar receiver. However, when using a two-tank molten-salt storage system as the primary source of heat input, the Kalina cycle showed an advantage over the simple Rankine cycle because of about 33 % reduction in the storage requirement. The solar receiver showed the highest rate of exergy destruction for both the cycles. The rates of exergy destruction in other components of the cycles were found to be highly dependent on the amount of recuperation, and the ammonia mass fraction and pressure at the turbine inlet. - Highlights: •Kalina cycle for a central receiver solar thermal power plant with direct steam generation. •Rankine cycle shows better plant exergy

  16. Optimisation of a Kalina cycle for a central receiver solar thermal power plant with direct steam generation

    DEFF Research Database (Denmark)

    Modi, Anish; Haglind, Fredrik

    2014-01-01

    Central receiver solar thermal power plants are regarded as one of the promising ways to generate electricity in near future. They offer the possibility of using high temperatures and pressures to achieve high efficiencies with standard power cycles. A direct steam generation approach can be used...

  17. Characterization of Ternary NiTiPd High-Temperature Shape-Memory Alloys under Load-Biased Thermal Cycling

    Science.gov (United States)

    Bigelow, Glen S.; Padula, Santo A.; Noebe, Ronald D.; Garg, Anita; Gaydosh, Darrell

    2010-01-01

    While NiTiPd alloys have been extensively studied for proposed use in high-temperature shape-memory applications, little is known about the shape-memory response of these materials under stress. Consequently, the isobaric thermal cyclic responses of five (Ni,Pd)49.5Ti50.5 alloys with constant stoichiometry and Pd contents ranging from 15 to 46 at. pct were investigated. From these tests, transformation temperatures, transformation strain (which is proportional to work output), and unrecovered strain per cycle (a measure of dimensional instability) were determined as a function of stress for each alloy. It was found that increasing the Pd content over this range resulted in a linear increase in transformation temperature, as expected. At a given stress level, work output decreased while the amount of unrecovered strain produced during each load-biased thermal cycle increased with increasing Pd content, during the initial thermal cycles. However, continued thermal cycling at constant stress resulted in a saturation of the work output and nearly eliminated further unrecovered strain under certain conditions, resulting in stable behavior amenable to many actuator applications.

  18. Measured thermal and fast neutron fluence rates for ATF-1 holders during ATR cycle 158B/159A

    Energy Technology Data Exchange (ETDEWEB)

    Smith, Larry Don [Idaho National Lab. (INL), Idaho Falls, ID (United States); Miller, David Torbet [Idaho National Lab. (INL), Idaho Falls, ID (United States); Walker, Billy Justin [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2016-11-01

    This report contains the thermal (2200 m/s) and fast (E>1MeV) neutron fluence rate data for the ATF-1 holders located in core for ATR Cycle 158B/159A which were measured by the Radiation Measurements Laboratory (RML).

  19. Optimization and experimental validation of a thermal cycle that maximizes entropy coefficient fisher identifiability for lithium iron phosphate cells

    Science.gov (United States)

    Mendoza, Sergio; Rothenberger, Michael; Hake, Alison; Fathy, Hosam

    2016-03-01

    This article presents a framework for optimizing the thermal cycle to estimate a battery cell's entropy coefficient at 20% state of charge (SOC). Our goal is to maximize Fisher identifiability: a measure of the accuracy with which a parameter can be estimated. Existing protocols in the literature for estimating entropy coefficients demand excessive laboratory time. Identifiability optimization makes it possible to achieve comparable accuracy levels in a fraction of the time. This article demonstrates this result for a set of lithium iron phosphate (LFP) cells. We conduct a 24-h experiment to obtain benchmark measurements of their entropy coefficients. We optimize a thermal cycle to maximize parameter identifiability for these cells. This optimization proceeds with respect to the coefficients of a Fourier discretization of this thermal cycle. Finally, we compare the estimated parameters using (i) the benchmark test, (ii) the optimized protocol, and (iii) a 15-h test from the literature (by Forgez et al.). The results are encouraging for two reasons. First, they confirm the simulation-based prediction that the optimized experiment can produce accurate parameter estimates in 2 h, compared to 15-24. Second, the optimized experiment also estimates a thermal time constant representing the effects of thermal capacitance and convection heat transfer.

  20. Thermally moderated hollow fiber sorbent modules in rapidly cycled pressure swing adsorption mode for hydrogen purification

    KAUST Repository

    Lively, Ryan P.; Bessho, Naoki; Bhandari, Dhaval A.; Kawajiri, Yoshiaki; Koros, William J.

    2012-01-01

    We describe thermally moderated multi-layered pseudo-monolithic hollow fiber sorbents entities, which can be packed into compact modules to provide small-footprint, efficient H2 purification/CO2 removal systems for use in on-site steam methane reformer product gas separations. Dual-layer hollow fibers are created via dry-jet, wet-quench spinning with an inner "active" core of cellulose acetate (porous binder) and zeolite NaY (69 wt% zeolite NaY) and an external sheath layer of pure cellulose acetate. The co-spun sheath layer reduces the surface porosity of the fiber and was used as a smooth coating surface for a poly(vinyl-alcohol) post-treatment, which reduced the gas permeance through the fiber sorbent by at least 7 orders of magnitude, essentially creating an impermeable sheath layer. The interstitial volume between the individual fibers was filled with a thermally-moderating paraffin wax. CO2 breakthrough experiments on the hollow fiber sorbent modules with and without paraffin wax revealed that the "passively" cooled paraffin wax module had 12.5% longer breakthrough times than the "non-isothermal" module. The latent heat of fusion/melting of the wax offsets the released latent heat of sorption/desorption of the zeolites. One-hundred rapidly cycled pressure swing adsorption cycles were performed on the "passively" cooled hollow fiber sorbents using 25 vol% CO2/75 vol% He (H2 surrogate) at 60 °C and 113 psia, resulting in a product purity of 99.2% and a product recovery of 88.1% thus achieving process conditions and product quality comparable to conventional pellet processes. Isothermal and non-isothermal dynamic modeling of the hollow fiber sorbent module and a traditional packed bed using gPROMS® indicated that the fiber sorbents have sharper fronts (232% sharper) and longer adsorbate breakthrough times (66% longer), further confirming the applicability of the new fiber sorbent approach for H2 purification. © 2012, Hydrogen Energy Publications, LLC

  1. On the effect of brazing thermal cycle on the properties of niobium and its alloys

    International Nuclear Information System (INIS)

    Grishin, V.L.; Cherkasov, A.F.

    1975-01-01

    The effect of the main parameters of the soldering thermal cycle on the properties of Nb and its alloys was studied by heating the samples under modelled conditions of soldering. The studies were made on commercial VN-niobium, alloys of the Nb-Mo-Zr system VN2A, VN2AEHM) and alloys of the Nb-Mo-Zr-C system (VN5AEH,VN5A). The degree of a preliminary plastic deformation of samples 0.3 to 0.8 mm thick made up 60 to 80%. The heating was made in vacuum (10 -4 to 5x10 -5 mm Hg) or in argon by passing the electric current across the samples. After heating a metallographic study and X-ray electron-probe analysis were made. The studies have shown that the changes in the heating rate result in a proportional change in the recrystallization initiation temperature. At a heating rate 300 deg C/s the recrystallization initiation temperature of commercial Nb is 930 to 960 deg as soon as the heating rate increases up to 900 deg/c the recrystallization initiation temperature rises up to about 1200 deg C. The heating temperature effect on the mechanical characteristics of commercial Nb and alloys VN2, VN2AEH and VN5AEH is shown. It is found that soldered joints of Nb and its alloys could be made of good quality when observing the thermal cycles ensuring the minimum softening of the base material. The main factors affecting the properties of Nb and alloy-VN2 are the heating temperature and the extent of a preliminary cold deformation. In a more deformed material the annealing results in the activation of the recrystallization processes. The production of high-strength soldered joints of commercial Nb is possible at the soldering temperature equal to 1100 deg C, but of Nb-Mo-Zr alloys-at 1200 to 1300 deg C and hold-up periods not exceeding one hour. A heterophase structure of alloys of the Nb-Mo-Zr-C system and the presence of Mo- and Zr-carbide phases in them result in a considerable hardening of the alloys and the increase in their recrystallization temperature. The usage of alloys

  2. Thermally moderated hollow fiber sorbent modules in rapidly cycled pressure swing adsorption mode for hydrogen purification

    KAUST Repository

    Lively, Ryan P.

    2012-10-01

    We describe thermally moderated multi-layered pseudo-monolithic hollow fiber sorbents entities, which can be packed into compact modules to provide small-footprint, efficient H2 purification/CO2 removal systems for use in on-site steam methane reformer product gas separations. Dual-layer hollow fibers are created via dry-jet, wet-quench spinning with an inner "active" core of cellulose acetate (porous binder) and zeolite NaY (69 wt% zeolite NaY) and an external sheath layer of pure cellulose acetate. The co-spun sheath layer reduces the surface porosity of the fiber and was used as a smooth coating surface for a poly(vinyl-alcohol) post-treatment, which reduced the gas permeance through the fiber sorbent by at least 7 orders of magnitude, essentially creating an impermeable sheath layer. The interstitial volume between the individual fibers was filled with a thermally-moderating paraffin wax. CO2 breakthrough experiments on the hollow fiber sorbent modules with and without paraffin wax revealed that the "passively" cooled paraffin wax module had 12.5% longer breakthrough times than the "non-isothermal" module. The latent heat of fusion/melting of the wax offsets the released latent heat of sorption/desorption of the zeolites. One-hundred rapidly cycled pressure swing adsorption cycles were performed on the "passively" cooled hollow fiber sorbents using 25 vol% CO2/75 vol% He (H2 surrogate) at 60 °C and 113 psia, resulting in a product purity of 99.2% and a product recovery of 88.1% thus achieving process conditions and product quality comparable to conventional pellet processes. Isothermal and non-isothermal dynamic modeling of the hollow fiber sorbent module and a traditional packed bed using gPROMS® indicated that the fiber sorbents have sharper fronts (232% sharper) and longer adsorbate breakthrough times (66% longer), further confirming the applicability of the new fiber sorbent approach for H2 purification. © 2012, Hydrogen Energy Publications, LLC

  3. Thermal cycling behavior of EB-PVD TBCs on CVD platinum modified aluminide coatings

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Zhenhua, E-mail: zhxubiam@aliyun.com; Wang, Zhankao; Huang, Guanghong; Mu, Rende; He, Limin

    2015-07-15

    Highlights: • The removed ridges at the grain boundaries with grit blasting. • The ridge, oxidation and cracking are features of damage initiation in TBCs. • Spalled location either at TGO/bond coat interface or inside of TGO layer. • The lower strain energy release rate within TGO layer can prolong of TBCs life. - Abstract: Thermal barrier coating systems (TBCs) including of chemical vapor deposited (Ni, Pt)Al bond coat with grit blasting process and electron beam physical vapor deposited Y{sub 2}O{sub 3}-stabilized-ZrO{sub 2} (YSZ) ceramic coating were investigated. The phase structures, surface and cross-sectional morphologies, cyclic oxidation behaviors and residual stresses of the TBCs were studied in detail. It was found that the fracture path traverses through the ceramic coating to TGO interface, as well as at the TGO to bond coat interface is obviously detected. The change in fracture plane occurs at grain boundaries. The ridge top spallation leads to separate of sufficient size to result in unstable fracture driven by the strain energy stored in the TGO. The bond coat can undergo a volume increase upon oxidation, so that a cavity, enlarged strictly by oxidation would be full to overflowing with TGO layer. The spalled location of the TBCs probably occurs either at the interface of TGO layer and bond coat or inside of TGO layer. The lower strain energy release rate within TGO layer during thermal cycling is beneficial to prolong of TBCs life. The lower is the compressive stress within TGO layer, the longer is the lifetime of TBCs.

  4. THE THERMAL PROPERTIES OF SOLAR FLARES OVER THREE SOLAR CYCLES USING GOES X-RAY OBSERVATIONS

    International Nuclear Information System (INIS)

    Ryan, Daniel F.; Gallagher, Peter T.; Milligan, Ryan O.; Dennis, Brian R.; Kim Tolbert, A.; Schwartz, Richard A.; Alex Young, C.

    2012-01-01

    Solar flare X-ray emission results from rapidly increasing temperatures and emission measures in flaring active region loops. To date, observations from the X-Ray Sensor (XRS) on board the Geostationary Operational Environmental Satellite (GOES) have been used to derive these properties, but have been limited by a number of factors, including the lack of a consistent background subtraction method capable of being automatically applied to large numbers of flares. In this paper, we describe an automated Temperature and Emission measure-Based Background Subtraction method (TEBBS), that builds on the methods of Bornmann. Our algorithm ensures that the derived temperature is always greater than the instrumental limit and the pre-flare background temperature, and that the temperature and emission measure are increasing during the flare rise phase. Additionally, TEBBS utilizes the improved estimates of GOES temperatures and emission measures from White et al. TEBBS was successfully applied to over 50,000 solar flares occurring over nearly three solar cycles (1980-2007), and used to create an extensive catalog of the solar flare thermal properties. We confirm that the peak emission measure and total radiative losses scale with background subtracted GOES X-ray flux as power laws, while the peak temperature scales logarithmically. As expected, the peak emission measure shows an increasing trend with peak temperature, although the total radiative losses do not. While these results are comparable to previous studies, we find that flares of a given GOES class have lower peak temperatures and higher peak emission measures than previously reported. The TEBBS database of flare thermal plasma properties is publicly available at http://www.SolarMonitor.org/TEBBS/.

  5. Integrated sound absorption in thermally activated concrete ceilings - acoustic and thermal effectiveness of sound-absorber strips spaced at intervals; Integrierte Schallabsorption in thermisch aktivierten Betondecken - akustische und thermische Wirksamkeit periodischer Schallabsorberstreifen

    Energy Technology Data Exchange (ETDEWEB)

    Drotleff, Horst; Wack, Roman; Leistner, Philip; Holm, Andreas; Ziegler, Matthias; Sedlbauer, Klaus [Fraunhofer-Institut fuer Bauphysik IBP, Stuttgart (Germany)

    2011-10-15

    From the perspectives of energy as well as indoor climate, thermally activated concrete ceilings make sense. Used in office buildings, however, their drawback becomes apparent: they are acoustically reflective. The conventional approaches use sound-absorbing suspended sails and absorber baffles or heat-conducting sound absorbers embedded in large areas of the concrete. In this paper, an alternative approach is presented and is evaluated acoustically and thermally. A few strips of sound absorber, arranged at intervals, are mounted flush into the concrete ceiling. To calculate the sound-absorption spectrum, an already widely publicised model (the Rayleigh approach) is used. It predicts the sound-absorption spectrum for normal sound incidence very well. For diffuse sound incidence, the difference to reverberation chamber measurements is greater, presumably because of the edge effect. The sound- absorption coefficient of the design can be tuned by skilful choice of the strip geometry, and it is significantly higher than the expected average value for the surface. On the one hand, the thermal efficiency of the components is determined by comparing the heat fluxes in the ceilings with absorber strips to an untreated reference ceiling. On the other hand, the indoor climate is investigated using a room model for office rooms of both solid and lightweight constructions. The influence of the strips (proportion of absorber area 20 %) on the thermal efficiency and indoor climate is low. Two absorber materials are examined in the strip approach: open-cell foam glass and a micro-perforated metallic absorber. While the metallic absorber displays thermal advantages, its sound absorption spectrum - even at high surface-coverage proportions - exhibits a much lower absorption coefficient than, for example, open-cell foam glass strips with only 20 % ceiling coverage. A demonstration in situ shows the potential of the absorber strips spaced at intervals. However, the method chosen in

  6. Numerical simulation of displacement instabilities of surface grooves on an alumina forming alloy during thermal cycling oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Li, Feng Xun; Kang, Ki Ju [Chonnam National University, Gwangju (Korea, Republic of); Ding, Jun [Chongqing University of Technology, Chongqing (China)

    2009-08-15

    Displacement instability of the thermally grown oxide (TGO) is a fundamental source of failure in thermal barrier systems. In this work, a finite element analysis has been performed to analyze the displacement instability occurring at a heat resistant metal with superficial TGO subjected to thermal cycling. Lateral and in-plane growth of the TGO which happens during high temperature is simulated by means of material property change from the substrate metal to the TGO. Most of the material properties including the TGO growth are based on the results experimentally obtained in-house. Results of the finite element analyses agree well with the experimental observation, which proves the accuracy and validity of this simulation. The technique will be useful for future work on more complicated phenomena such as deformation under thermo-mechanical cycling

  7. Transient thermal model of passenger car's cabin and implementation to saturation cycle with alternative working fluids

    International Nuclear Information System (INIS)

    Lee, Hoseong; Hwang, Yunho; Song, Ilguk; Jang, Kilsang

    2015-01-01

    A transient thermal model of a passenger car's cabin is developed to investigate the dynamic behavior of cabin thermal conditions. The model is developed based on a lumped-parameter model and solved using integral methods. Solar radiation, engine heat through the firewall, and engine heat to the air ducts are all considered. Using the thermal model, transient temperature profiles of the interior mass and cabin air are obtained. This model is used to investigate the transient behavior of the cabin under various operating conditions: the recirculation mode in the idling state, the fresh air mode in the idling state, the recirculation mode in the driving state, and fresh air mode in the driving state. The developed model is validated by comparing with experimental data and is within 5% of deviation. The validated model is then applied for evaluating the mobile air conditioning system's design. The study found that a saturation cycle concept (four-stage cycle with two-phase refrigerant injection) could improve the system efficiency by 23.9% and reduce the power consumption by 19.3%. Lastly, several alternative refrigerants are applied and their performance is discussed. When the saturation cycle concept is applied, R1234yf MAC (mobile air conditioning) shows the largest COP (coefficient of performance) improvement and power consumption reduction. - Highlights: • The transient thermal model of the passenger car cabin is developed. • The developed model is validated with experimental data and showed 5% deviation. • Saturation cycle concept is applied to the developed cabin model. • There is 24% COP improvement by applying the saturation cycle concept. • R1234yf showed the highest potential when it is applied to the saturation cycle.

  8. Multi-parameter fibre Bragg grating sensor-array for thermal vacuum cycling test

    Science.gov (United States)

    Cheng, L.; Ahlers, B.; Toet, P.; Casarosa, G.; Appolloni, M.

    2017-11-01

    strain transducer to generate strain via a dedicated feed through in the chamber. Thermocouples are used to log the temperature for comparison to the temperature FBG sensor. Extreme temperature ranges from -150°C and +70°C at a pressure down to 10-4 Pa (10-6 mbar) are covered as well as testing under ambient conditions. In total five thermal cycles during a week test are performed. The FBG temperature sensor test results performed in the ESA/ESTEC TV chamber reveal high reproducibility (within 1 °C) within the test temperature range without any evidence of hysteresis. Differences are detected to the previous calibration curve. Investigation is performed to find the cause of the discrepancy. Differences between the test set-ups are identified. Equipment of the TNO test is checked and excluded to be the cause. Additional experiments are performed. The discrepancy is most likely caused by a 'thermal shock' due to rapid cooling down to LN2 temperature, which results in a wavelength shift. Test data of the FBG strain sensor is analysed. The read-out of the FBG strain sensor varies with the temperature during the test. This can be caused by temperature induced changes in the mechanical setup (fastening of the mechanical parts) or impact of temperature to the mechanical strain transfer to the FBG. Improvements are identified and recommendations given for future activities.

  9. Thermal performance analysis of Brayton cycle with waste heat recovery boiler for diesel engines of offshore oil production facilities

    International Nuclear Information System (INIS)

    Liu, Xianglong; Gong, Guangcai; Wu, Yi; Li, Hangxin

    2016-01-01

    Highlights: • Comparison of Brayton cycle with WHRB adopted in diesel engines with and without fans by thermal performance. • Waste heat recovery technology for FPSO. • The thermoeconomic analysis for the heat recovery for FPSO. - Abstract: This paper presents the theoretical analysis and on-site testing on the thermal performance of the waste heat recovery system for offshore oil production facilities, including the components of diesel engines, thermal boilers and waste heat boilers. We use the ideal air standard Brayton cycle to analyse the thermal performance. In comparison with the traditional design, the fans at the engine outlet of the waste heat recovery boiler is removed due to the limited space of the offshore platform. The cases with fan and without fan are compared in terms of thermal dynamics performance, energy efficiency and thermo-economic index of the system. The results show that the application of the WHRB increases the energy efficiency of the whole system, but increases the flow resistance in the duct. It is proved that as the waste heat recovery boiler takes the place of the thermal boiler, the energy efficiency of whole system without fan is slightly reduced but heat recovery efficiency is improved. This research provides an important guidance to improve the waste heat recovery for offshore oil production facilities.

  10. Thermal expansion behavior study of Co nanowire array with in situ x-ray diffraction and x-ray absorption fine structure techniques

    Science.gov (United States)

    Mo, Guang; Cai, Quan; Jiang, Longsheng; Wang, Wei; Zhang, Kunhao; Cheng, Weidong; Xing, Xueqing; Chen, Zhongjun; Wu, Zhonghua

    2008-10-01

    In situ x-ray diffraction and x-ray absorption fine structure techniques were used to study the structural change of ordered Co nanowire array with temperature. The results show that the Co nanowires are polycrystalline with hexagonal close packed structure without phase change up until 700 °C. A nonlinear thermal expansion behavior has been found and can be well described by a quadratic equation with the first-order thermal expansion coefficient of 4.3×10-6/°C and the second-order thermal expansion coefficient of 5.9×10-9/°C. The mechanism of this nonlinear thermal expansion behavior is discussed.

  11. Zinc Absorption from Milk Is Affected by Dilution but Not by Thermal Processing, and Milk Enhances Absorption of Zinc from High-Phytate Rice in Young Dutch Women.

    Science.gov (United States)

    Talsma, Elise F; Moretti, Diego; Ly, Sou Chheng; Dekkers, Renske; van den Heuvel, Ellen Ghm; Fitri, Aditia; Boelsma, Esther; Stomph, Tjeerd Jan; Zeder, Christophe; Melse-Boonstra, Alida

    2017-06-01

    Background: Milk has been suggested to increase zinc absorption. The effect of processing and the ability of milk to enhance zinc absorption from other foods has not been measured directly in humans. Objective: We aimed to assess zinc absorption from 1 ) milk undergoing various processing and preparatory steps and 2 ) from intrinsically labeled high-phytate rice consumed with milk or water. Methods: Two randomized crossover studies were conducted in healthy young women [age:18-25 y; body mass index (in kg/m 2 ): 20-25]: 1 ) a milk study ( n = 19) comparing the consumption of 800 mL full-fat ultra-high temperature (UHT) milk [heat-treated milk (HTM)], full-fat UHT milk diluted 1:1 with water [heat-treated milk and water (MW)], water, or unprocessed (raw) milk (UM), each extrinsically labeled with 67 Zn, and 2 ) a rice study ( n = 18) comparing the consumption of 90 g intrinsically 67 Zn-labeled rice with 600 mL of water [rice and water (RW)] or full-fat UHT milk [rice and milk (RM)]. The fractional absorption of zinc (FAZ) was measured with the double-isotope tracer ratio method. In vitro, we assessed zinc extraction from rice blended into water, UM, or HTM with or without phytate. Results: FAZ from HTM was 25.5% (95% CI: 21.6%, 29.4%) and was not different from UM (27.8%; 95% CI: 24.2%, 31.4%). FAZ from water was higher (72.3%; 95% CI: 68.7%, 75.9%), whereas FAZ from MW was lower (19.7%; 95% CI: 17.5%, 21.9%) than HTM and UM (both P zinc from rice with HTM than from rice with water at various phytate concentrations. Conclusions: Milk enhanced human FAZ from high-phytate rice by 62% compared with water. Diluting milk with water decreases its absorption-enhancing proprieties, whereas UHT processing does not. This trial was registered at the Dutch trial registry as NTR4267 (http://www.trialregister.nl/trialreg/admin/rctview.asp?TC=4267). © 2017 American Society for Nutrition.

  12. Parameters of Models of Structural Transformations in Alloy Steel Under Welding Thermal Cycle

    Science.gov (United States)

    Kurkin, A. S.; Makarov, E. L.; Kurkin, A. B.; Rubtsov, D. E.; Rubtsov, M. E.

    2017-05-01

    A mathematical model of structural transformations in an alloy steel under the thermal cycle of multipass welding is suggested for computer implementation. The minimum necessary set of parameters for describing the transformations under heating and cooling is determined. Ferritic-pearlitic, bainitic and martensitic transformations under cooling of a steel are considered. A method for deriving the necessary temperature and time parameters of the model from the chemical composition of the steel is described. Published data are used to derive regression models of the temperature ranges and parameters of transformation kinetics in alloy steels. It is shown that the disadvantages of the active visual methods of analysis of the final phase composition of steels are responsible for inaccuracy and mismatch of published data. The hardness of a specimen, which correlates with some other mechanical properties of the material, is chosen as the most objective and reproducible criterion of the final phase composition. The models developed are checked by a comparative analysis of computational results and experimental data on the hardness of 140 alloy steels after cooling at various rates.

  13. Structural changes in complex steels with 12 % Cr during welding thermal cycle

    International Nuclear Information System (INIS)

    Ul'yanova, N.V.; Kurnosova, N.D.

    1981-01-01

    The structural changes in the heat affected zones of welded steam tubes of the 12Kh11V2MF and 18Kh12VMBFR steels, are investigated. A short-time heating of thin samples up to 1300-900 deg C with the aim of imitating the thermal welding cycle permits to determine temperatures of specific region formation in heat affeced zones of 12% Cr steels. The difference in the amounts and structure of σ-ferrite and γ-phase in these regions is established. A ''tongue'' nature of γ-phase grain growth is found in the temperature range of 1150-1100 deg C, while at 1300-1250 deg C σ-ferrite growth with the formation of saw-shape boundaries is observed. It is shown that tensile properties of imitated heat affected zone of 12Kh12VMBFP steel increase with heating temperature with the insignificant plasticity decrease. Impact strength on longitudinal samples decreases but remains higher than that determined by specifications [ru

  14. The Seasonal Cycle of Water Vapour on Mars from Assimilation of Thermal Emission Spectrometer Data

    Science.gov (United States)

    Steele, Liam J.; Lewis, Stephen R.; Patel, Manish R.; Montmessin, Franck; Forget, Francois; Smith, Michael D.

    2014-01-01

    We present for the first time an assimilation of Thermal Emission Spectrometer (TES) water vapour column data into a Mars global climate model (MGCM). We discuss the seasonal cycle of water vapour, the processes responsible for the observed water vapour distribution, and the cross-hemispheric water transport. The assimilation scheme is shown to be robust in producing consistent reanalyses, and the global water vapour column error is reduced to around 2-4 pr micron depending on season. Wave activity is shown to play an important role in the water vapour distribution, with topographically steered flows around the Hellas and Argyre basins acting to increase transport in these regions in all seasons. At high northern latitudes, zonal wavenumber 1 and 2 stationary waves during northern summer are responsible for spreading the sublimed water vapour away from the pole. Transport by the zonal wavenumber 2 waves occurs primarily to the west of Tharsis and Arabia Terra and, combined with the effects of western boundary currents, this leads to peak water vapour column abundances here as observed by numerous spacecraft. A net transport of water to the northern hemisphere over the course of one Mars year is calculated, primarily because of the large northwards flux of water vapour which occurs during the local dust storm around L(sub S) = 240-260deg. Finally, outlying frost deposits that surround the north polar cap are shown to be important in creating the peak water vapour column abundances observed during northern summer.

  15. GEM, Fuel Cycle Cost and Economics for Thermal Reactor, Present Worth Analysis

    International Nuclear Information System (INIS)

    Hughes, J.A.; Hang, D.F.

    1974-01-01

    1- Description of problem or function: GEM is used to predict fuel cycle costs for any type nuclear system (i.e., BWR, HTGR, PWR, LMFBR, GCFR,... ). The current version is limited to thermal reactors. GEM is designed for production use by large utilities which have several reactor types on their system. GEM has been written so as to accommodate all major fuel management activities undertaken by a utility - (1) fuel bid analysis, (2) evaluation of actual day to day operation, and (3) system simulation and optimization studies. 2 - Method of solution: Costs are calculated using present-worth techniques and continuous compounding. The equations are based on an investor-owned utility capitalization structure which easily covers the range of industrial, private, and public (government) owned utilities. Three distinct types of analysis (cash flow, allocated costs, yearly cash flow) are performed, each yielding identical results. Using these as a basis many other analyses are undertaken. 3 - Restrictions on the complexity of the problem: Dimensions of all arrays are carried as variables throughout the analysis. The maximum size of each array is set by the user in program MAIN. Current values are set so that maxima are: 50 batches per case study, 20 year batch life, 30 year case study, 120 batch burn time-steps, 20 individual payments (sales) associated with each cost component

  16. Fiber-reinforced composite analysis using optical coherence tomography after mechanical and thermal cycling

    Science.gov (United States)

    Kyotoku, B. B. C.; Braz, A. K. S.; Braz, R.; Gomes, A. S. L.

    2007-02-01

    Fiber-reinforced composites are new materials which have been used for a variety of dental applications, including tooth splinting, replacement of missing teeth, treatment of dental emergencies, reinforcement of resin provisional fixed prosthodontic restorations, orthodontic retention, and other clinical applications. Different fiber types are available, but little clinical information has been disseminated. The traditional microscopy investigation, most commonly used to study this material, is a destructive technique, which requires specimen sectioning and are essentially surface measurements. On the basis of these considerations, the aim of this research is to analyze the interior of a dental sample reinforced with fiber after a mechanical and thermal cycling to emulate oral conditions using optical coherence tomography (OCT). The device we are using is a home built Fourier domain OCT working at 800 nm with 6 μm resolution. The results are compared with microscopy images to validate OCT as a working method. In long term, fractures allow bacterial invasion provoking plaque and calculus formation that can cause caries and periodontal disease. Therefore, non invasive imaging of the bridge fiber enables the possibility of periodic clinical evaluation to ensure the patient health. Furthermore, OCT images can provide a powerful method for quantitative analysis of crack propagation, and can potentially be used for in vivo assessment.

  17. Resistance to radiation and concretes thermal cycles for conditioning of spent radioactive sources

    International Nuclear Information System (INIS)

    Gonzalez N, M.; Monroy G, F.; Gonzalez D, R. C.; Corona P, I. J.; Ortiz A, G.

    2014-10-01

    In order to know the concrete type most suitable for use as a matrix of conditioning of spent radioactive sources, concrete test tubes using 4 different types of cement were prepared: CPC 30-Rs Extra, CPC 30-R Impercem, CPC 30-R Rs and CPC 30-R with two gravel sizes >30 mm and <10 mm. The concrete test tubes were subjected to testing compressive strength after 28 days of hardening and after being irradiated and subjected to thermal cycles. Subsequently they were characterized by X-ray diffraction and scanning electron microscopy, in order to evaluate whether these concretes accredited the tests set by the NOM-019-Nucl-1995. The results show that the compressive strength of the hardened concretes to 28 days presents values between 36 and 25 MPa; applying irradiation the resistance may decrease to 30% of its original strength; and if subjected to high and low temperatures the ettringite formation also causes a decrease in resistance. The results show that concretes made from cement Impercem, Cruz Azul with gravel <10 mm comply with the provisions of standard and they can be used for conditioning of spent radioactive sources. (Author)

  18. Thermodynamic simulation of ammonia-water absorption refrigeration system

    Directory of Open Access Journals (Sweden)

    Sathyabhama A.

    2008-01-01

    Full Text Available The ammonia-water absorption refrigeration system is attracting increasing research interests, since the system can be powered by waste thermal energy, thus reducing demand on electricity supply. The development of this technology demands reliable and effective system simulations. In this work, a thermodynamic simulation of the cycle is carried out to investigate the effects of different operating variables on the performance of the cycle. A computer program in C language is written for the performance analysis of the cycle.

  19. Establishment of a JSME code for the evaluation of high-cycle thermal fatigue in mixing tees

    International Nuclear Information System (INIS)

    Moriya, Shoichi; Fukuda, Toshihiko; Matsunaga, Tomoya; Hirayama, Hiroshi; Shiina, Kouji; Tanimoto, Koichi

    2004-01-01

    This paper describes a JSME code for high-cycle thermal fatigue evaluation by thermal striping in mixing tees with hot and cold water flows. The evaluation of thermal striping in a mixing tee has four steps to screen design parameters one-by-one according to the severity of the thermal load assessed from design conditions using several evaluation charts. In order to make these charts, visualization tests with acrylic pipes and temperature measurement tests with metal pipes were conducted. The influence of the configurations of mixing tees, flow velocity ratio, pipe diameter ratio and so on was examined from the results of the experiments. This paper makes a short mention of the process of providing these charts. (author)

  20. Assessment of Accrued Damage and Remaining Useful Life in Leadfree Electronics Subjected to Multiple Thermal Environments of Thermal Aging and Thermal Cycling

    Data.gov (United States)

    National Aeronautics and Space Administration — A method has been developed for prognostication of accrued prior damage in electronics subjected to overlapping sequential environments of thermal aging and thermal...

  1. Comparison of the Organic Flash Cycle (OFC) to other advanced vapor cycles for intermediate and high temperature waste heat reclamation and solar thermal energy

    International Nuclear Information System (INIS)

    Ho, Tony; Mao, Samuel S.; Greif, Ralph

    2012-01-01

    The Organic Flash Cycle (OFC) is proposed as a vapor power cycle that could potentially improve the efficiency with which high and intermediate temperature finite thermal sources are utilized. The OFC's aim is to improve temperature matching and reduce exergy losses during heat addition. A theoretical investigation is conducted using high accuracy equations of state such as BACKONE, Span–Wagner, and REFPROP in a detailed thermodynamic and exergetic analysis. The study examines 10 different aromatic hydrocarbons and siloxanes as potential working fluids. Comparisons are drawn between the OFC and an optimized basic Organic Rankine Cycle (ORC), a zeotropic Rankine cycle using a binary ammonia-water mixture, and a transcritical CO 2 cycle. Results showed aromatic hydrocarbons to be the better suited working fluid for the ORC and OFC due to higher power output and less complex turbine designs. Results also showed that the single flash OFC achieves comparable utilization efficiencies to the optimized basic ORC. Although the OFC improved heat addition exergetic efficiency, this advantage was negated by irreversibilities introduced during flash evaporation. A number of potentially significant improvements to the OFC are possible though which includes using a secondary flash stage or replacing the throttling valve with a two-phase expander. -- Highlights: ► The Organic Flash Cycle (OFC) is proposed to improve temperature matching. ► Ten aromatic hydrocarbon and siloxane working fluids are considered. ► Accurate equations of state explicit in Helmholtz energy are used in the analysis. ► The OFC is compared to basic ORCs, zeotropic, and transcritical cycles. ► The OFC achieves comparable power output to the optimized basic ORC.

  2. Thermal cycling in LWR components in OECD-NEA member countries - CSNI integrity and ageing working group

    International Nuclear Information System (INIS)

    Faidy, Claude; Chapuliot, Stephane; Mathet, Eric

    2005-01-01

    Thermal cycling is a widespread and recurring problem in nuclear power plants worldwide. Several incidents with leakage of primary water inside the containment challenged the integrity of NPPs although no release outside of containment occurred. Thermal cycling was not taken into account at the design stage. Regulatory bodies, utilities and researchers have to address it for their operating plants. It is a complex phenomenon that involves and links thermal hydraulic, fracture mechanic, materials and plant operation. Thermal cycling is connected either to operating transients (low cycle fatigue) or to complex phenomenon like stratification, vortex and mixing (low and high cycle fatigue). The former is covered by existing rules and codes. The latter is partially addressed by national rules and constitutes the subject of this report. In 2002, the Committee on the Safety of Nuclear Installations (CSNI) requested the working group on the integrity of reactor components and structures (IAGE WG) to prepare a program of work on thermal cycling to provide information to NEA member countries on operational experience, regulatory policies, countermeasures in place, current status of research and development, and to identify areas where research is needed both at national and international levels. The working group proposed a 3 fold program that covered: - Review of operating experience, regulatory framework, countermeasures and current research; - Benchmark to assess calculation capabilities in NEA member countries for crack initiation and propagation under a cyclic thermal loading, and ultimately to develop screening criteria to identify susceptible components; results of the benchmark were published in 2005; - Organisation of an international conference in cooperation with the EPRI and the USNRC on fatigue of reactor components. This conference reviews progress in the areas and provides a forum for discussion and exchange of information between high level experts. The

  3. Design, evaluation and recommedation effort relating to the modification of a residential 3-ton absorption cycle cooling unit for operation with solar energy

    Science.gov (United States)

    Merrick, R. H.; Anderson, P. P.

    1973-01-01

    The possible use of solar energy powered absorption units to provide cooling and heating of residential buildings is studied. Both, the ammonia-water and the water-lithium bromide cycles, are considered. It is shown that the air cooled ammonia water unit does not meet the criteria for COP and pump power on the cooling cycle and the heat obtained from it acting as a heat pump is at too low a temperature. If the ammonia machine is water cooled it will meet the design criteria for cooling but can not supply the heating needs. The water cooled lithium bromide unit meets the specified performance for cooling with appreciably lower generator temperatures and without a mechanical solution pump. It is recommeded that in the demonstration project a direct expansion lithium bromide unit be used for cooling and an auxiliary duct coil using the solar heated water be employed for heating.

  4. Generic Repository Concepts and Thermal Analysis for Advanced Fuel Cycles - 12477

    Energy Technology Data Exchange (ETDEWEB)

    Hardin, Ernest [Sandia National Laboratories, P.O. Box 5800 MS 0736, Albuquerque, NM 87185 (United States); Blink, James [Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, CA 94551-0808 (United States); Carter, Joe [Savannah River National Laboratory, Savannah River Site, Aiken, SC 29808 (United States); Fratoni, Massimiliano; Greenberg, Harris; Sutton, Mark [Lawrence Livermore National Laboratory (United States); Howard, Robert [Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, TN 37831 (United States)

    2012-07-01

    A geologic disposal concept for spent nuclear fuel (SNF) or high-level waste (HLW) consists of three components: waste inventory, geologic setting, and concept of operations. A set of reference geologic disposal concepts has been developed by the U.S. Department of Energy (DOE), Used Fuel Disposition campaign. Reference concepts are identified for crystalline rock, clay/shale, bedded salt, and deep borehole (crystalline basement) geologic settings. These were analyzed for waste inventory cases representing a range of waste types that could be produced by advanced nuclear fuel cycles. Concepts of operation consisting of emplacement mode, repository layout, and engineered barrier descriptions, were selected based on international progress. All of these disposal concepts are enclosed emplacement modes, whereby waste packages are in direct contact with encapsulating engineered or natural materials. Enclosed modes have less capacity to dissipate heat than open modes such as that proposed for a repository at Yucca Mountain. Thermal analysis has identified important relationships between waste package size and capacity, and the duration of surface decay storage needed to meet temperature limits for different disposal concepts. For the crystalline rock and clay/shale repository concepts, a waste package surface temperature limit of 100 deg. C was assumed to prevent changes in clay-based buffer material or clay-rich host rock. Surface decay storage of 50 to 100 years is needed for disposal of high-burnup LWR SNF in 4-PWR packages, or disposal of HLW glass from reprocessing LWR uranium oxide (UOX) fuel. High-level waste (HLW) from reprocessing of metal fuel used in a fast reactor could be disposed after decay storage of 50 years or less. For disposal in salt the rock thermal conductivity is significantly greater, and higher temperatures (200 deg. C) can be tolerated at the waste package surface. Decay storage of 10 years or less is needed for high-burnup LWR SNF in 4-PWR

  5. Use of polyethylene glycol for the improvement of the cycling stability of bischofite as thermal energy storage material

    International Nuclear Information System (INIS)

    Gutierrez, Andrea; Ushak, Svetlana; Galleguillos, Hector; Fernandez, Angel; Cabeza, Luisa F.; Grágeda, Mario

    2015-01-01

    Highlights: • Bischofite as phase change material for TES is studied. • Thermophysical properties of bischofite mixtures with PEG were determined. • The aim was to improve the cycling stability of bischofite. • The heating and cooling during 30 cycles were measured. • The most stable sample was bischofite + 5% PEG 2 000. - Abstract: Bischofite is a by-product of the non-metallic mining industry. It has been evaluated as phase change material in thermal energy storage, but it shows little cycling stability, therefore in this paper the mixture of bischofite with an additive was studied. Since polyethylene glycol (PEG) is a PCM itself, in this paper PEG (with different molecular weights) is used as additive in a PCM (bischofite) to improve its thermal behaviour. Results show that adding 5% PEG 2 000 to bischofite gives a more cycling stable PCM without affecting its melting temperature neither decreasing significantly its heat of fusion. This research shows that mixing an inorganic PCM with an organic additive can be a good option to improve the thermal performance of the PCM

  6. Damage assessment of low-cycle fatigue by crack growth prediction. Fatigue life under cyclic thermal stress

    International Nuclear Information System (INIS)

    Kamaya, Masayuki

    2013-01-01

    The number of cycles to failure of specimens in fatigue tests can be estimated by predicting crack growth. Under a cyclic thermal stress caused by fluctuation of fluid temperature, due to the stress gradient in the thickness direction, the estimated fatigue life differs from that estimated for mechanical fatigue tests. In this paper, the influence of crack growth under cyclic thermal loading on the fatigue life was investigated. First, the thermal stress was derived by superposing analytical solutions, and then, the stress intensity factor was obtained by the weight function method. It was shown that the thermal stress depended not on the rate of the fluid temperature change but on the rise time, and the magnitude of the stress was increased as the rise time was decreased. The stress intensity factor under the cyclic thermal stress was smaller than that under the uniform stress distribution. The change in the stress intensity factor with the crack depth did not depend on the heat transfer coefficient and only slightly depended on the rise time. The estimated fatigue life under the cyclic thermal loading could be 1.6 times longer than that under the uniform stress distribution. The critical size for the fatigue life determination was assumed to be 3 mm for fatigue test specimens of 10 mm diameter. By evaluating the critical size by structural integrity analyses, the fatigue life was increased and the effect of the critical size on the fatigue life was more pronounced for the cyclic thermal stress. (author)

  7. Damage assessment of low-cycle fatigue by crack growth prediction. Fatigue life under cyclic thermal stress

    International Nuclear Information System (INIS)

    Kamaya, Masayuki

    2013-01-01

    The number of cycles to failure of specimens in fatigue tests can be estimated by predicting crack growth. Under a cyclic thermal stress caused by fluctuation of fluid temperature, due to the stress gradient in the thickness direction, the estimated fatigue life differs from that estimated for mechanical fatigue tests. In this paper, the influence of crack growth under cyclic thermal loading on the fatigue life was investigated. First, the thermal stress was derived by superposing analytical solutions, and then, the stress intensity factor was obtained by the weight function method. It was shown that the thermal stress depended not on the rate of the fluid temperature change but on the rise time, and the magnitude of the stress was increased as the rise time was decreased. The stress intensity factor under the cyclic thermal stress was smaller than that under the uniform stress distribution. The change in the stress intensity factor with the crack depth was almost the same regardless of the rise time. The estimated fatigue life under the cyclic thermal loading could be 1.6 times longer than that under the uniform stress distribution. The critical size for the fatigue life determination was assumed to be 3 mm for fatigue test specimens of 10 mm diameter. By evaluating the critical size by structural integrity analyses, the fatigue life was increased and the effect of the critical size on the fatigue life was more pronounced for the cyclic thermal stress. (author)

  8. Thermal enhancement of charge and discharge cycles for adsorbed natural gas storage

    KAUST Repository

    Rahman, Kazi Afzalur; Loh, Wai Soong; Chakraborty, Anutosh; Saha, Bidyut Baran; Chun, Won Gee; Ng, Kim Choon

    2011-01-01

    The usage of adsorbed natural gas (ANG) storage is hindered by the thermal management during the adsorption and desorption processes. An effective thermal enhancement is thus essential for the development of the ANG technology and the motivation

  9. The arctic seasonal cycle of total column CO2 and CH4 from ground-based solar and lunar FTIR absorption spectrometry

    Directory of Open Access Journals (Sweden)

    M. Buschmann

    2017-07-01

    Full Text Available Solar absorption spectroscopy in the near infrared has been performed in Ny-Ålesund (78.9° N, 11.9° E since 2002; however, due to the high latitude of the site, the sun is below the horizon from October to March (polar night and no solar absorption measurements are possible. Here we present a novel method of retrieving the total column dry-air mole fractions (DMFs of CO2 and CH4 using moonlight in winter. Measurements have been taken during the polar nights from 2012 to 2016 and are validated with TCCON (Total Carbon Column Observing Network measurements by solar and lunar absorption measurements on consecutive days and nights during spring and autumn. The complete seasonal cycle of the DMFs of CO2 and CH4 is presented and a precision of up to 0.5 % is achieved. A comparison of solar and lunar measurements on consecutive days during day and night in March 2013 yields non-significant biases of 0. 66 ± 4. 56 ppm for xCO2 and −1. 94 ± 20. 63 ppb for xCH4. Additionally a model comparison has been performed with data from various reanalysis models.

  10. Life cycle energy metrics and CO 2 credit analysis of a hybrid photovoltaic/thermal greenhouse dryer

    OpenAIRE

    P. Barnwal; G. N. Tiwari

    2008-01-01

    In this paper, life cycle energy metrics, such as energy payback time (EPBT), energy production factor (EPF) and life cycle conversion efficiency (LCCE), and mitigation of CO 2 emissions for a hybrid photovoltaic/thermal (PV/T) greenhouse dryer have been analyzed. The hybrid PV/T greenhouse (roof type even span) dryer, designed and constructed at Solar Energy Park, Indian Institute of Technology, New Delhi (28°35′N, 77°12′E, 216 m above MSL), India, has a 2.50 m × 2.60 m floor area, 1.80 m ce...

  11. Thermal performance of shallow solar pond under open cycle continuous flow heating mode for heat extraction

    Energy Technology Data Exchange (ETDEWEB)

    El-Sebaii, A.A. [Department of Physics, Faculty of Science, Tanta University, Tanta 31527 (Egypt)]. E-mail: aasebaii@yahoo.com; Aboul-Enein, S. [Department of Physics, Faculty of Science, Tanta University, Tanta 31527 (Egypt); Ramadan, M.R.I. [Department of Physics, Faculty of Science, Tanta University, Tanta 31527 (Egypt); Khallaf, A.M. [Department of Physics, Faculty of Science, Tanta University, Tanta 31527 (Egypt)

    2006-05-15

    The thermal performance of a shallow solar pond (SSP) under an open cycle continuous flow heating mode for heat extraction has been investigated. A serpentine heat exchanger (HE), either welded to the absorber plate or immersed in the pond water, has been used for extracting the heat. Suitable computer programs have been developed based on analytical solutions of the energy balance equations for the various elements of the SSP in the presence of the HE. Numerical calculations have been performed to study the effect of different operational and configurational parameters on the pond performance. In order to improve the pond performance, optimization of the various dimensions of the pond with the HE has been performed. The effects of the design parameters of the HE's tube, i.e. length L{sub he}, diameter D and mass flow rate m-bar {sub f} of the fluid flowing through the HE, on the pond performance have been investigated. The outlet temperature of the HE's fluid T{sub fo} is found to increase with increase of the HE length L{sub he}, and it decreases with increase of the mass flow rate of the HE's fluid m-bar {sub f} up to typical values for these parameters. Typical values for L{sub he} and m-bar {sub f} are found to be 4m and 0.004kg/s beyond which the change in T{sub fo} becomes insignificant. Experiments have been performed for the pond under different operational conditions with a HE welded to the absorber plate. To validate the proposed mathematical models, comparisons between experimental and theoretical results have been performed. Good agreement has been achieved.

  12. Modeling the small-scale dish-mounted solar thermal Brayton cycle

    Science.gov (United States)

    Le Roux, Willem G.; Meyer, Josua P.

    2016-05-01

    The small-scale dish-mounted solar thermal Brayton cycle (STBC) makes use of a sun-tracking dish reflector, solar receiver, recuperator and micro-turbine to generate power in the range of 1-20 kW. The modeling of such a system, using a turbocharger as micro-turbine, is required so that optimisation and further development of an experimental setup can be done. As a validation, an analytical model of the small-scale STBC in Matlab, where the net power output is determined from an exergy analysis, is compared with Flownex, an integrated systems CFD code. A 4.8 m diameter parabolic dish with open-cavity tubular receiver and plate-type counterflow recuperator is considered, based on previous work. A dish optical error of 10 mrad, a tracking error of 1° and a receiver aperture area of 0.25 m × 0.25 m are considered. Since the recuperator operates at a very high average temperature, the recuperator is modeled using an updated ɛ-NTU method which takes heat loss to the environment into consideration. Compressor and turbine maps from standard off-the-shelf Garrett turbochargers are used. The results show that for the calculation of the steady-state temperatures and pressures, there is good comparison between the Matlab and Flownex results (within 8%) except for the recuperator outlet temperature, which is due to the use of different ɛ-NTU methods. With the use of Matlab and Flownex, it is shown that the small-scale open STBC with an existing off-the-shelf turbocharger could generate a positive net power output with solar-to-mechanical efficiency of up to 12%, with much room for improvement.

  13. Mitochondrial DNA polymerase editing mutation, PolgD257A, disturbs stem-progenitor cell cycling in the small intestine and restricts excess fat absorption.

    Science.gov (United States)

    Fox, Raymond G; Magness, Scott; Kujoth, Gregory C; Prolla, Tomas A; Maeda, Nobuyo

    2012-05-01

    Changes in intestinal absorption of nutrients are important aspects of the aging process. To address this issue, we investigated the impact of accelerated mitochondrial DNA mutations on the stem/progenitor cells in the crypts of Lieberkühn in mice homozygous for a mitochondrial DNA polymerase gamma mutation, Polg(D257A), that exhibit accelerated aging phenotype. As early as 3-7 mo of age, the small intestine was significantly enlarged in the PolgD257A mice. The crypts of the PolgD257A mice contained 20% more cells than those of their wild-type littermates and exhibited a 10-fold increase in cellular apoptosis primarily in the stem/progenitor cell zones. Actively dividing cells were proportionally increased, yet a significantly smaller proportion of cells was in the S phase of the cell cycle. Stem cell-derived organoids from PolgD257A mice failed to develop fully in culture and exhibited fewer crypt units, indicating an impact of the mutation on the intestinal epithelial stem/progenitor cell maintenance. In addition, epithelial cell migration along the crypt-villus axis was slowed and less organized, and the ATP content in the villi was significantly reduced. On a high-fat, high-carbohydrate diet, PolgD257A mice showed significantly restricted absorption of excess lipids accompanied by an increase in fecal steatocrits. We conclude that the PolgD257A mutation causes cell cycle dysregulation in the crypts leading to the age-associated changes in the morphology of the small intestine and contributes to the restricted absorption of dietary lipids.

  14. Evaluation of an Absorption Heat Pump to Mitigate Plant Capacity Reduction Due to Ambient Temperature Rise for an Air-Cooled Ammonia and Water Cycle: Preprint

    International Nuclear Information System (INIS)

    Bharathan, D.; Nix, G.

    2001-01-01

    Air-cooled geothermal plants suffer substantial decreases in generating capacity at increased ambient temperatures. As the ambient temperature rises by 50 F above a design value of 50 F, at low brine-resource temperatures, the decrease in generating capacity can be more than 50%. This decrease is caused primarily by increased condenser pressure. Using mixed-working fluids has recently drawn considerable attention for use in power cycles. Such cycles are more readily amenable to use of absorption ''heat pumps.'' For a system that uses ammonia and water as the mixed-working fluid, this paper evaluates using an absorption heat pump to reduce condenser backpressure. At high ambient temperatures, part of the turbine exhaust vapor is absorbed into a circulating mixed stream in an absorber in series with the main condenser. This steam is pumped up to a higher pressure and heated to strip the excess vapor, which is recondensed using an additional air-cooled condenser. The operating conditions are chosen to reconstitute this condensate back to the same concentration as drawn from the original system. We analyzed two power plants of nominal 1-megawatt capacity. The design resource temperatures were 250 F and 300 F. Ambient temperature was allowed to rise from a design value of 50 F to 100 F. The analyses indicate that using an absorption heat pump is feasible. For the 300 F resource, an increased brine flow of 30% resulted in a net power increase of 21%. For the 250 F resource, the increase was smaller. However, these results are highly plant- and equipment-specific because evaluations must be carried out at off-design conditions for the condenser. Such studies should be carried out for specific power plants that suffer most from increased ambient temperatures

  15. Effects of vacuum thermal cycling on mechanical and physical properties of high performance carbon/bismaleimide composite

    International Nuclear Information System (INIS)

    Yu Qi; Chen Ping; Gao Yu; Mu Jujie; Chen Yongwu; Lu Chun; Liu Dong

    2011-01-01

    Highlights: → The level of cross-links was improved to a certain extent. → The thermal stability was firstly improved and then decreased. → The transverse and longitudinal CTE were both determined by the degree of interfacial debonding. → The mass loss ratio increases firstly and then reaches a plateau value. → The surface morphology was altered and the surface roughness increased firstly and then decreased. → The transverse tensile strength was reduced. → The flexural strength increased firstly and then decreased to a plateau value. → The ILSS increased firstly and then decreased to a plateau value. - Abstract: The aim of this article was to investigate the effects of vacuum thermal cycling on mechanical and physical properties of high performance carbon/bismaleimide (BMI) composites used in aerospace. The changes in dynamic mechanical properties and thermal stability were characterized by dynamic mechanical analysis (DMA) and thermogravimetric analysis (TGA), respectively. The changes in linear coefficient of thermal expansion (CTE) were measured in directions perpendicular and parallel to the fiber direction, respectively. The outgassing behavior of the composites were examined. The evolution of surface morphology and surface roughness were observed by atomic force microscopy (AFM). Changes in mechanical properties including transverse tensile strength, flexural strength and interlaminar shear strength (ILSS) were measured. The results indicated that the vacuum thermal cycling could improve the crosslinking degree and the thermal stability of resin matrix to a certain extent, and induce matrix outgassing and thermal stress, thereby leading to the mass loss and the interfacial debonding of the composite. The degradation in transverse tensile strength was caused by joint effects of the matrix outgassing and the interfacial debonding, while the changes in flexural strength and ILSS were affected by a competing effect between the crosslinking degree

  16. Recent developments in thermally-driven seawater desalination: Energy efficiency improvement by hybridization of the MED and AD cycles

    KAUST Repository

    Ng, Kim Choon

    2015-01-01

    The energy, water and environment nexus is a crucial factor when considering the future development of desalination plants or industry in the water-stressed economies. New generation of desalination processes or plants has to meet the stringent environment discharge requirements and yet the industry remains highly energy efficient and sustainable when producing good potable water. Water sources, either brackish or seawater, have become more contaminated as feed while the demand for desalination capacities increase around the world. One immediate solution for energy efficiency improvement comes from the hybridization of the proven desalination processes to the newer processes of desalination: For example, the integration of the available thermally-driven to adsorption desalination (AD) cycles where significant thermodynamic synergy can be attained when cycles are combined. For these hybrid cycles, a quantum improvement in energy efficiency as well as in increase in water production can be expected. The advent of MED with AD cycles, or simply called the MEDAD cycles, is one such example where seawater desalination can be pursued and operated in cogeneration with the electricity production plants: The hybrid desalination cycles utilize only the low exergy bled-steam at low temperatures, complemented with waste exhaust or renewable solar thermal heat at temperatures between 60 and 80. °C. In this paper, the authors have reported their pioneered research on aspects of AD and related hybrid MEDAD cycles, both at theoretical models and experimental pilots. Using the cogeneration of electricity and desalination concept, the authors examined the cost apportionment of fuel cost by the quality or exergy of working steam for such cogeneration configurations.

  17. Performance Evaluation of HP/ORC (Heat Pump/Organic Rankine Cycle) System with Optimal Control of Sensible Thermal Storage

    DEFF Research Database (Denmark)

    Do Carmo, Carolina Madeira Ramos; Dumont, Olivier; Nielsen, Mads Pagh

    2016-01-01

    In energy systems with high share of renewable energy sources, like wind and solar power, it is paramount to deal with their intrinsic variability. The interaction between electric and thermal energy (heating and cooling) demands represent a potential area for balancing supply and demand that could...... come to contribute to the integration of intermittent renewables.This paper describes an innovative concept that consists of the addition of an Organic Rankine Cycle (ORC) to a combined solar system coupled to a ground-source heat pump (HP) in a single-family building. The ORC enables the use of solar...... energy in periods of no thermal energy demand and reverses the heat pump cycle to supply electrical power. A dynamic model based on empirical data of this system is used to determine the annual performance. Furthermore, this work assesses the benefits of different control strategies that address...

  18. Effect of thermal cycling on the microstructure of a directionally solidified Fe, Cr, Al-TaC eutectic alloy

    Science.gov (United States)

    Harf, F. H.; Tewari, S. N.

    1977-01-01

    Cylindrical bars (1.2 cm diameter) of Fe-13.6Cr-3.7Al-9TaC (wt %) eutectic alloy were directionally solidified in a modified Bridgman type furnace at 1 cm/h. The alloy microstructure consisted of aligned TaC fibers imbedded in a bcc Fe-Cr-Al matrix. Specimens of the alloy were thermally cycled from 1100 to 425 C in a burner rig. The effects of 1800 thermal cycles on the microstructure was examined by scanning electron microscopy, revealing a zig-zag shape of TaC fibers aligned parallel to the growth direction. The mechanism of carbide solution and reprecipitation on the (111) easy growth planes, suggested previously to account for the development of irregular serrations in Co-Cr-Ni matrix alloys, is believed to be responsible for these zig-zag surfaces.

  19. Detailed analysis of the effect of the turbine and compressor isentropic efficiency on the thermal and exergy efficiency of a Brayton cycle

    Directory of Open Access Journals (Sweden)

    Živić Marija

    2014-01-01

    Full Text Available Energy and exergy analysis of a Brayton cycle with an ideal gas is given. The irreversibility of the adiabatic processes in turbine and compressor is taken into account through their isentropic efficiencies. The net work per cycle, the thermal efficiency and the two exergy efficiencies are expressed as functions of the four dimensionless variables: the isentropic efficiencies of turbine and compressor, the pressure ratio, and the temperature ratio. It is shown that the maximal values of the net work per cycle, the thermal and the exergy efficiency are achieved when the isentropic efficiencies and temperature ratio are as high as possible, while the different values of pressure ratio that maximize the net work per cycle, the thermal and the exergy efficiencies exist. These pressure ratios increase with the increase of the temperature ratio and the isentropic efficiency of compressor and turbine. The increase of the turbine isentropic efficiency has a greater impact on the increase of the net work per cycle and the thermal efficiency of a Brayton cycle than the same increase of compressor isentropic efficiency. Finally, two goal functions are proposed for thermodynamic optimization of a Brayton cycle for given values of the temperature ratio and the compressor and turbine isentropic efficiencies. The first maximizes the sum of the net work per cycle and thermal efficiency while the second the net work per cycle and exergy efficiency. In both cases the optimal pressure ratio is closer to the pressure ratio that maximizes the net work per cycle.

  20. Fracture resistance of metal-free composite crowns-effects of fiber reinforcement, thermal cycling, and cementation technique.

    Science.gov (United States)

    Lehmann, Franziska; Eickemeyer, Grit; Rammelsberg, Peter

    2004-09-01

    The improved mechanical properties of contemporary composites have resulted in their extensive use for the restoration of posterior teeth. However, the influence of fiber reinforcement, cementation technique, and physical stress on the fracture resistance of metal-free crowns is unknown. This in vitro study evaluated the effect of fiber reinforcement, physical stress, and cementation methods on the fracture resistance of posterior metal-free Sinfony crowns. Ninety-six extracted human third molars received a standardized tooth preparation: 0.5-mm chamfer preparation and occlusal reduction of 1.3 to 1.5 mm. Sinfony (nonreinforced crowns, n=48) and Sinfony-Vectris (reinforced crowns, n=48) crowns restoring original tooth contour were prepared. Twenty-four specimens of each crown type were cemented, using either glass ionomer cement (GIC) or resin cement. Thirty-two crowns (one third) were stored in humidity for 48 hours. Another third was exposed to 10,000 thermal cycles (TC) between 5 degrees C and 55 degrees C. The remaining third was treated with thermal cycling and mechanical loading (TCML), consisting of 1.2 million axial loads of 50 N. The artificial crowns were then vertically loaded with a steel sphere until failure occurred. Significant differences in fracture resistance (N) between experimental groups were assessed by nonparametric Mann-Whitney U-test (alpha=.05). Fifty percent of the Sinfony and Sinfony-Vectris crowns cemented with glass ionomer cement loosened after thermal cycling. Thermal cycling resulted in a significant reduction in the mean fracture resistance for Sinfony crowns cemented with GIC, from 2037 N to 1282 N (P=.004). Additional fatigue produced no further effects. Fiber reinforcement significantly increased fracture resistance, from 1555 N to 2326 N (P=.001). The minimal fracture resistance was above 600 N for all combinations of material, cement and loading. Fracture resistance of metal-free Sinfony crowns was significantly increased by

  1. University of Minnesota Aquifer Thermal Energy Storage (ATES) project report on the first long-term cycle

    Science.gov (United States)

    Walton, M.

    1991-10-01

    The technical feasibility of high-temperature (greater than 100 C) aquifer thermal energy storage (IOTAS) in a deep, confined aquifer was tested in a series of experimental cycles at the University of Minnesota's St. Paul field test facility (FTF). This report describes the additions to the FTF for the long-term cycles and the details of the first long-term cycle (LT1) that was conducted from November 1984 through May 1985. Heat recovery; operational experience; and thermal, chemical, hydrologic, and geologic aspects of LT1 are reported. The permits for long-term cycles required the addition of a monitoring well 30.5 m from the storage well for monitoring near the edge of the thermally affected area and allowed the addition of a cation-exchange water softener to enable continuous operation during the injection phase. Approximately 62 percent of the 9.47 GWh of energy added to the 9.21 x 10(exp 4) cu m of ground water stored in the aquifer LT1 was recovered. Ion-exchange water softening of the heated and stored ground water prevented scaling in the system heat exchangers and the storage well and changed the major-ion chemistry of the stored water. Temperatures at the storage horizons in site monitoring wells reached as high as 108 C during the injection phase of LT1. Following heat recovery, temperatures were less than 30 C at the same locations. Less permeable horizons underwent slow temperature changes. No thermal or chemical effects were observed at the remote monitoring site.

  2. Pre- and post-irradiation properties of copper alloys at 250 deg. C following bonding and bakeout thermal cycles

    International Nuclear Information System (INIS)

    Singh, B.N.; Edwards, D.J.; Eldrup, M.; Toft, P.

    1997-01-01

    Screening experiments were carried out to investigate the effect of bonding and bakeout thermal cycles on microstructure, mechanical properties and electrical resistivity of the oxide dispersion strengthened (GlidCop, CuAl-25) and the precipitation hardened (CuCrZr, CuNiBe) copper alloys. Tensile specimens of CuCrZr and CuNiBe alloys were given various heat treatments corresponding to solution anneal, prime-ageing, and bonding thermal treatment followed by re-ageing and the reactor bakeout treatment at 350 deg. C for 100 h. Tensile specimens of CuAl-25 were given the heat treatment corresponding to the bonding thermal cycle. A number of heat treated specimens were neuron irradiated at 250 deg. C to a dose level of ∼ 0.3 dpa in the DR-3 reactor at Risoe. Both unirradiated and irradiated specimens with various heat treatments were tensile tested at 250 deg. C. The microstructure and electrical resistivity of these specimens were determined in the unirradiated as well as irradiated conditions. The post-deformation microstructure of the irradiated specimens was also investigated. The fracture surfaces of both unirradiated and irradiated specimens were examined. Results of these investigations are reported in the present report. The main effect of the bonding thermal cycle heat treatment was a slight decrease in strength of CuCrZr and CuNiBe alloys. The strength of CuAl-25, on the other hand, remained almost unaltered. The post irradiation tests at 250 deg. C showed a severe loss of ductility in the case of CuNiBe alloy. The irradiated CuAl-25 and CuCrZr specimens, on the other hand, exhibited a reasonable amount of uniform elongation. The results are briefly discussed in terms of thermal and irradiation stability of precipitates and particles and irradiation-induced segregation, precipitation and recovery of dislocation microstructure. (au) 7 tabs., 28 ills., 15 refs

  3. Measured thermal and fast neutron fluence rates, ATR Cycle 102-A, 11/28/93 thru 1/16/94

    International Nuclear Information System (INIS)

    Murray, R.K.; Rogers, J.W.

    1994-02-01

    This report contains the thermal (2,200 m/s) and fast (E > 1MeV) neutron fluence rate data for ATR Cycle 102-A which were measured by the Radiation Measurements Laboratory (RML) as requested by the Power Reactor Programs (ATR Experiments) Radiation Measurements Work Order. This report contains fluence rate values corresponding to the particular elevations (relative to the 80 ft. core elevation) where the measurements were taken. The data in this report consists of (1) a table of the ATR power history and distribution, (2) a hard copy listing of all thermal and fast neutron fluence rates, (3) plots of both the thermal and fast neutron fluence rates, and (4) a magnetic record (3.5 inch diskette) containing a listing of only the fast neutron fluence rates, their assigned elevations and proper header identification of all monitor positions contained herein. The fluence rates reported are for the average power levels given in the table of power history and distribution. All ''H'' holder monitoring wires for this cycle are 54 inches long. All ''SR'' holder monitor wires for this cycle are 55 inches long. This length allows measurement of the full core region and makes the first count elevation 24.73 inches above core midplane. Due to the safety rod problems in the west lobe, ''BR'' holders were used in the W-1, 2, 3, and 4 positions. All ''BR'' holder monitor wires for this cycle are 56.25 inches long. The distance from the end of the wires to the first count position was 4.25 inches for all wires counted from this cycle

  4. Bond Coat Engineering Influence on the Evolution of the Microstructure, Bond Strength, and Failure of TBCs Subjected to Thermal Cycling

    Science.gov (United States)

    Lima, R. S.; Nagy, D.; Marple, B. R.

    2015-01-01

    Different types of thermal spray systems, including HVOF (JP5000 and DJ2600-hybrid), APS (F4-MB and Axial III), and LPPS (Oerlikon Metco system) were employed to spray CoNiCrAlY bond coats (BCs) onto Inconel 625 substrates. The chemical composition of the BC powder was the same in all cases; however, the particle size distribution of the powder employed with each torch was that specifically recommended for the torch. For optimization purposes, these BCs were screened based on initial evaluations of roughness, porosity, residual stress, relative oxidation, and isothermal TGO growth. A single type of standard YSZ top coat was deposited via APS (F4MB) on all the optimized BCs. The TBCs were thermally cycled by employing a furnace cycle test (FCT) (1080 °C-1 h—followed by forced air cooling). Samples were submitted to 10, 100, 400, and 1400 cycles as well as being cycled to failure. The behavior of the microstructures, bond strength values (ASTM 633), and the TGO evolution of these TBCs, were investigated for the as-sprayed and thermally cycled samples. During FCT, the TBCs found to be both the best and poorest performing and had their BCs deposited via HVOF. The results showed that engineering low-oxidized BCs does not necessarily lead to an optimal TBC performance. Moreover, the bond strength values decrease significantly only when the TBC is about to fail (top coat spall off) and the as-sprayed bond strength values cannot be used as an indicator of TBC performance.

  5. Measured thermal and fast neutron fluence rates ATR Cycle 99-A, November 23, 1992--January 23, 1993

    International Nuclear Information System (INIS)

    Murray, R.K.; Rogers, J.W.

    1993-03-01

    This report contains the thermal (2200 m/s) and fast (E>me) neutron fluence rate data for ATR Cycle 99-A which were measured by the Radiation Measurements Laboratory (RML) as requested by the Power ReactorPrograms (ATR Experiments) Radiation Measurements Work Order. This report contains fluence rate values corresponding to the particular elevations (relative to the 80 ft. core elevation) where the measurements were taken. The data in this report consists of (1) a table of the ATR power history and distribution, (2) a hard copy listing of all thermal and fast neutron fluence rates, (3) plots of both the thermal and fast neutron fluence rates, and (4) a magnetic record (3.5 inch diskette) containing a listing of only the fast neutron fluence rates, their assigned elevations and proper header identification of all monitor positions contained herein. The fluence rates reported are for the average power levels given in the table of power history and distribution. All ''H'' holder monitor wires for this cycle are 54 inches long. All ''SR'' holder monitor wires for this cycle are 55 inches long. This length allows measurement of the full core region and makes the first count elevation 24.73 inches above core midplane. Due to the safety rod problems in the west lobe, ''BR'' holders were used in the W-1, 2, 3, and 4 positions. All ''BR'' holder monitor wires for this cycle are 56.25 inches long. The distance from the end of the wires to the first count position was 4.25 inches for all wires counted from this cycle

  6. Effect of thermal cycling on the transformation temperature ranges of a Ni-Ti shape memory alloy

    International Nuclear Information System (INIS)

    Paula, A.S.; Canejo, J.P.H.G.; Martins, R.M.S.; Braz Fernandes, F.M.

    2003-01-01

    Shape memory alloys (SMA) represents a class of metallic materials that has the capability of recovering a previously defined initial shape when subject to an adequate thermomechanical treatment. The present work aims to study the influence of thermal cycles on the transition temperatures of a Ni-Ti alloy. In this system, small variations around the equiatomic composition give rise to significant transformation temperature variations ranging from 173 to 373 K. SMA usually presents the shape memory effect after an annealing treatment at ca. 973 K. The optimisation of the thermomechanical treatment will allow to 'tune' the material to different transformation temperature ranges from the same starting material, just by changing the processing conditions. Differential scanning calorimeter (DSC) and in situ high-temperature X-ray diffraction (XRD) have been used to identify the transformation temperatures and the phases that are present after different thermal cycles. The results concerning a series of thermal cycles with different heating and cooling rates (from 1.67x10 -2 to 1.25x10 -1 K/s) and different holding temperatures (from 473 to 1033 K) are presented

  7. Measured thermal and fast neutron fluence rates ATR Cycle 101-B, October 11, 1993--November 27, 1993

    International Nuclear Information System (INIS)

    Murray, R.K.; Rogers, J.W.

    1994-01-01

    This report contains the thermal (2200 m/s) and fast (E>lMeV) neutron fluence rate data for ATR Cycle 101-B which were measured by the Radiation Measurements Laboratory (RML) as requested by the Power Reactor Programs (ATR Experiments) Radiation Measurements Work Order. This report contains fluence rate values corresponding to the particular elevations (relative to the 80 ft. core elevation) where the measurements were taken. The data in this report consists of (1) a table of the ATR power history and distribution, (2) a hard copy listing of all thermal and fast neutron fluence rates, (3) plots of both the thermal and fast neutron fluence rates, and (4) a magnetic record (3.5 inch diskette) containing a listing of only the fast neutron fluence rates, their assigned elevations proper header identification of all monitor positions contained herein

  8. Effect of bonding and bakeout thermal cycles on the properties of copper alloys irradiated at 350 deg. C

    International Nuclear Information System (INIS)

    Singh, B.N.; Eldrup, M.; Toft, P.; Edwards, D.J.

    1997-02-01

    Screening experiments were carried out to investigate the effect of bonding and bakeout thermal cycles on microstructure, mechanical properties and electrical resistivity of the oxide dispersion strengthened (GlidCop, CuAl-25) and the precipitation hardened (CuCrZr, CuNiBe) cooper alloys. Tensile specimens of CuCrZr and CuNiBe alloys were given various heat treatments corresponding to solution anneal, prime-ageing, and bonding thermal treatment followed by re-ageing and the reactor bakeout treatment at 350 deg. C for 100 h. Tensile specimens of CuAl-25 were given the heat treatment corresponding to the bonding thermal cycle. A number of heat treated specimens were neutron irradiated at 350 deg. C to a dose level of ∼ 0.3 dpa in the DR-3 reactor at Risoe. Both unirradiated and irradiated specimens with various heat treatments were tensile tested at 350 deg. C. The microstructure and electrical resistivity of these specimens were determined in the unirradiated as well as irradiated conditions. The post-deformation microstructure of the irradiated specimens was also investigated. The fracture surfaces of both unirradiated and irradiated specimens were examined. Results of these investigations are reported in the present report. The results are briefly discussed in terms of thermal and irradiation stability of precipitates and particles and irradiation-induced segregation, precipitation and recovery of dislocation microstructure. (au) 6 tabs., 24 ills., 9 refs

  9. Exergy based parametric analysis of a combined reheat regenerative thermal power plant and water–LiBr vapor absorption refrigeration system

    International Nuclear Information System (INIS)

    Gogoi, T.K.; Talukdar, K.

    2014-01-01

    Highlights: • Exergy analysis of a combined power–absorption cooling system is provided. • Exergetic efficiency of the power cycle and absorption cooling system are calculated. • Irreversibility in each component and total system irreversibility are calculated. • Effect of operating parameters on exergetic performance and irreversibility is analyzed. • Optimum operating parameters are identified based on energy and exergy based results. - Abstract: In this paper, exergy analysis of a combined reheat regenerative steam turbine (ST) based power cycle and water–LiBr vapor absorption refrigeration system (VARS) is presented. Exergetic efficiency of the power cycle and VARS, energy utilization factor (EUF) of the combined system (CS) and irreversibility in each system component are calculated. The effect of fuel flow rate, boiler pressure, cooling capacity and VARS components’ temperature on performance, component and total system irreversibility is analyzed. The second law based results indicate optimum performance at 150 bar boiler pressure and VARS generator, condenser, evaporator and absorber temperature of 80 °C, 37.5 °C, 15 °C and 35 °C respectively. The present exergy based results conform well to the first law based results obtained in a previous analysis done on the same combined system. Irreversibility distribution among various power cycle components shows the highest irreversibility in the cooling tower. Irreversibility of the exhaust flue gas leaving the boiler and the boiler are the next major contributors. Among the VARS components, exergy destruction in the generator is the highest followed by irreversibility contribution of the absorber, condenser and the evaporator

  10. Thermal cycling tests of 1st wall mock-ups with beryllium/CuCrZr bonding

    International Nuclear Information System (INIS)

    Uda, M.; Iwadachi, T.; Uchida, M.; Yamada, H.; Nakamichi, M.; Kawamura, H.

    2004-01-01

    The innovative bonding technology between beryllium and CuCrZr with Hot Isostatic Pressing (HIP) has been proposed for the manufacturing of the ITER first wall. In the next step, thermal cycling test of first wall mock-ups manufactured with the bonding technology, were carried out under the ITER heat load condition. The test condition is 1000 cycles of On and Off under 5 MW/m 2 , and two types of the mock-up were manufactured for evaluation of the effects on HIP temperature (520 degree C and 610 degree C). The tensile properties of the bonding were also evaluated in room temperature and 200 degree C. As for the results of the thermal cycling tests, the temperature near the bonding interface were scarcely any change up to 1000 cycles, and obvious damage of the mock-up was not detected under the tests. As for the results of the tensile tests in 200 degree C, the test pieces of the HIP bonding at 610 degree C were broken in parent CuCrZr material, not broken in the bonding interface. (author)

  11. Performance analysis of single stage libr-water absorption machine operated by waste thermal energy of internal combustion engine: Case study

    Science.gov (United States)

    Sharif, Hafiz Zafar; Leman, A. M.; Muthuraman, S.; Salleh, Mohd Najib Mohd; Zakaria, Supaat

    2017-09-01

    Combined heating, cooling, and power is also known as Tri-generation. Tri-generation system can provide power, hot water, space heating and air -conditioning from single source of energy. The objective of this study is to propose a method to evaluate the characteristic and performance of a single stage lithium bromide-water (LiBr-H2O) absorption machine operated with waste thermal energy of internal combustion engine which is integral part of trigeneration system. Correlations for computer sensitivity analysis are developed in data fit software for (P-T-X), (H-T-X), saturated liquid (water), saturated vapor, saturation pressure and crystallization temperature curve of LiBr-H2O Solution. Number of equations were developed with data fit software and exported into excel work sheet for the evaluation of number of parameter concerned with the performance of vapor absorption machine such as co-efficient of performance, concentration of solution, mass flow rate, size of heat exchangers of the unit in relation to the generator, condenser, absorber and evaporator temperatures. Size of vapor absorption machine within its crystallization limits for cooling and heating by waste energy recovered from exhaust gas, and jacket water of internal combustion engine also presented in this study to save the time and cost for the facilities managers who are interested to utilize the waste thermal energy of their buildings or premises for heating and air conditioning applications.

  12. X-ray absorption spectroscopy study of the LixFePO4 cathode during cycling using a novel electrochemical in situ reaction cell

    International Nuclear Information System (INIS)

    Deb, A.; Bergmann, U.; Cairns, E.L.; California Univ., Berkeley, CA; Cramer, S.P.; California Univ., Davis, CA

    2004-01-01

    The extraction and insertion of lithium in LiFePO 4 has been investigated in practical Li-ion intercalation electrodes for Li-ion batteries using Fe K-edge X-ray absorption spectroscopy (XAS). A versatile electrochemical in situ reaction cell was utilized, specifically designed for long-term X-ray experiments on battery electrodes during the lithium-extraction/insertion process in electrode materials for Li-ion batteries. The electrode contained about 7.7 mg of LiFePO 4 on a 20 μm-thick Al foil. In order to determine the charge compensation mechanism and structural perturbations occurring in the system during cycling, in situ X-ray absorption fine-structure spectroscopy (XAFS) measurements were conducted on the cell at a moderate rate using typical Li-ion battery operating voltages (3.0-4.1 V versus Li/Li + ).XAS studies of the LiFePO 4 electrode measured at the initial state (LiFePO 4 ) showed iron to be in the Fe(II) state corresponding to the initial state (0.0 mAh) of the battery, whereas in the delithiated state (FePO 4 ) iron was found to be in the FE(III) state corresponding to the final charged state (3 m Ah) of the battery. The X-ray absorption near-edge structure (XANES) region of the XAS spectra revealed a high-spin configuration for the two states [Fe(II), d 6 and Fe(III), d 5 ]. The XAFS data analysis confirmed that the olivine structure of the LeFePO 4 and FePO 4 is retained by the electrodes, which is in agreement with the X-ray diffraction observations on these compounds. The XAFS data that were collected continuously during cycling revealed details about the response of the cathode to Li insertion and extraction. These measurements on the LiFePO 4 cathode show that the material retains good structural short-range order leading to superior cycling

  13. Absorption of some mineral salts by root system of different woody species and accumulation over a whole vegetative cycle (1963)

    International Nuclear Information System (INIS)

    Gagnaire, J.; Gerard, J.M.

    1963-01-01

    The concentration power of plant tissues and the translocation speed of mineral salts are considerably varying with the absorbed salt, the botanical species, the considered tissue and the part of the vegetative cycle. In Grenoble, with Picea excelsa, the 'true dormancy' is short (half-november, end of december). It is accompanied by a pre-dormancy period (October, half-november) and a post dormancy period (January, february, march). In vegetative period, Picea excelsa leaves are less concentrating mineral salt than Acer campestris leaves (coefficient 2 for calcium - 3 for phosphates) and Populus nigra leaves (coefficient 3 for calcium, coefficient 5 for phosphates). (author) [fr

  14. Influence of Glycidyl Methacrylate Grafting on the Mechanical, Water Absorption, and Thermal Properties of Recycled High-Density Polyethylene/Rubber Seed Shell Particle Composites

    Directory of Open Access Journals (Sweden)

    Kaimeng Xu

    2016-01-01

    Full Text Available Rubber seed shell (RSS was modified by grafting treatment using glycidyl methacrylate (GMA at various concentrations. The RSS was then used to reinforce high-density polyethylene (HDPE. The effects of modification on the mechanical, water absorption, and thermal properties of the RSS/HDPE composites were studied using a mechanical testing instrument, weighing method, Vicat softening temperature (VST testing, thermogravimetry, and dynamic mechanical analysis. The results showed that the GMA grafting produced an improvement in the flexural and tensile properties of the composites. The water absorption rate of the composites also had an obvious decrease. While a slight increase in VST was found, the various concentrations of GMA showed no improvement in VST. GMA modification also could elevate the thermal stability of the composites at the initial decomposition stage. The optimum grafting concentration of GMA (2.5% led to the lowest thermal weight loss (37.07% and 26.56% during the first and second decomposition stages. The E’ values of the composites had a significant increase with the addition of GMA. There were two peaks of tan δ for the untreated samples, but the modified samples exhibited a shift in the transition peak at higher temperatures; moreover, the second peak disappeared.

  15. Human power output during repeated sprint cycle exercise: the influence of thermal stress

    NARCIS (Netherlands)

    Ball, D.; Burrows, C.; Sargeant, A.J.

    1999-01-01

    Thermal stress is known to impair endurance capacity during moderate prolonged exercise. However, there is relatively little available information concerning the effects of thermal stress on the performance of high-intensity short-duration exercise. The present experiment examined human power output

  16. Application of neutron absorption method of the analysis on thermal neutrons for the control of substances and products containing boron in a nuclear power engineering and industry

    International Nuclear Information System (INIS)

    Chuev, A.G.; Kiryanov, G.I.; Shagov, S.V.; Shtan, A.S.; Titov, V.V.

    2002-01-01

    Nuclear physical methods of analysis using the absorption effect of ionising radiation should satisfy the following requirements for industrial practice. First, the ionising radiation should have a high penetrating ability in the environment examined to ensure a representative nature of the data and reliability of the analysis. Secondly, the absorption degree of radiation should be sufficient to maintain the sensitivity and accuracy of the measurements. In addition, to keep the necessary selectivity, the neutron absorption analysis on thermal neutrons is applied on chemical elements and their isotopes with an anomalously high absorption cross section about 10 2 - 10 4 barn. To such elements belong Gd, Sm, B, Cd, Hg and others. Based on the exponential law of absorption for thermal neutrons, an analytical expression was obtained for the concentration of the element analyzed in dependence on the flow of the elapsed neutrons. A number of interfering factors such as the matrix effect of the filling agent, scattering of neutrons, dispersion of the density and of the temperature of the environment, and background radiation have to be taken into account. Owing to the difference between the experimental calibration dependence and the exponential one, the methods of its mathematical approximation, for example, polynomial function and partially hyperbolic one are considered. The scheme realisation of the method is feasible in geometry 'on passage' and 'on reflection' of the neutron flow. Radionuclide Pu-Be sources are preferred as the neutron sources based on nuclear reactions of the (α,n) type. Detectors used for registration of slow neutrons are gas discharge corona 3 He-filled counters. Hydrogen-containing substances with good scattering properties are utilised as the fast neutron moderators. The neutron absorption method has found wide application in the nuclear power engineering and atomic industry. This method is intended for continuous automatic monitoring of

  17. Influence of thermal treatment and γ-radiation on absorption, luminescence and scintillation properties of Lu3Al5O12:Ce single crystalline films

    International Nuclear Information System (INIS)

    Zorenko, Yu.; Pavlyk, B.; Turchak, R.; Zorenko, T.; Gorbenko, V.; Konstankevych, I.; Savchyn, V.; Voznyak, T.

    2007-01-01

    The influence of thermal treatment (TT) and irradiation by γ-quanta ( 60 Co, 1.25 MeV) in the range of absorbed doses 10 6 -10 8 R on the absorption, luminescence and light yield (LY) of scintillators based on Lu 3 Al 5 O 12 :Ce (LuAG:Ce) single crystalline films (SCF) grown by LPE from the Pb-based flux is studied. It has been shown that transformation of the Fe 3+ ↔Fe 2+ and Pb 2+ ↔Pb 4+ valent states of iron and lead trace impurities cause the change in the optical absorption of SCF induced by the TT in air and vacuum in the range of annealing temperatures of 800-1200 0 C. Possible types of radiation defects in LuAG:Ce SCF induced by γ-radiation are analyzed

  18. Variants of Regenerated Fissile Materials Usage in Thermal Reactors as the First Stage of Fuel Cycle Closing

    Science.gov (United States)

    Andrianova, E. A.; Tsibul'skiy, V. F.

    2017-12-01

    At present, 240 000 t of spent nuclear fuel (SF) has been accumulated in the world. Its long-term storage should meet safety conditions and requires noticeable finances, which grow every year. Obviously, this situation cannot exist for a long time; in the end, it will require a final decision. At present, several variants of solution of the problem of SF management are considered. Since most of the operating reactors and those under construction are thermal reactors, it is reasonable to assume that the structure of the nuclear power industry in the near and medium-term future will be unchanged, and it will be necessary to utilize plutonium in thermal reactors. In this study, different strategies of SF management are compared: open fuel cycle with long-term SF storage, closed fuel cycle with MOX fuel usage in thermal reactors and subsequent long-term storage of SF from MOX fuel, and closed fuel cycle in thermal reactors with heterogeneous fuel arrangement. The concept of heterogeneous fuel arrangement is considered in detail. While in the case of traditional fuel it is necessary to reprocess the whole amount of spent fuel, in the case of heterogeneous arrangement, it is possible to separate plutonium and 238U in different fuel rods. In this case, it is possible to achieve nearly complete burning of fissile isotopes of plutonium in fuel rods loaded with plutonium. These fuel rods with burned plutonium can be buried after cooling without reprocessing. They would contain just several percent of initially loaded plutonium, mainly even isotopes. Fuel rods with 238U alone should be reprocessed in the usual way.

  19. Light absorption during alkali atom-noble gas atom interactions at thermal energies: a quantum dynamics treatment.

    Science.gov (United States)

    Pacheco, Alexander B; Reyes, Andrés; Micha, David A

    2006-10-21

    The absorption of light during atomic collisions is treated by coupling electronic excitations, treated quantum mechanically, to the motion of the nuclei described within a short de Broglie wavelength approximation, using a density matrix approach. The time-dependent electric dipole of the system provides the intensity of light absorption in a treatment valid for transient phenomena, and the Fourier transform of time-dependent intensities gives absorption spectra that are very sensitive to details of the interaction potentials of excited diatomic states. We consider several sets of atomic expansion functions and atomic pseudopotentials, and introduce new parametrizations to provide light absorption spectra in good agreement with experimentally measured and ab initio calculated spectra. To this end, we describe the electronic excitation of the valence electron of excited alkali atoms in collisions with noble gas atoms with a procedure that combines l-dependent atomic pseudopotentials, including two- and three-body polarization terms, and a treatment of the dynamics based on the eikonal approximation of atomic motions and time-dependent molecular orbitals. We present results for the collision induced absorption spectra in the Li-He system at 720 K, which display both atomic and molecular transition intensities.

  20. Assessing the potential of hybrid fossil–solar thermal plants for energy policy making: Brayton cycles

    International Nuclear Information System (INIS)

    Bernardos, Eva; López, Ignacio; Rodríguez, Javier; Abánades, Alberto

    2013-01-01

    This paper proposes a first study in-depth of solar–fossil hybridization from a general perspective. It develops a set of useful parameters for analyzing and comparing hybrid plants, it studies the case of hybridizing Brayton cycles with current solar technologies and shows a tentative extrapolation of the results to integrated combined cycle systems (ISCSS). In particular, three points have been analyzed: the technical requirements for solar technologies to be hybridized with Brayton cycles, the temperatures and pressures at which hybridization would produce maximum power per unit of fossil fuel, and their mapping to current solar technologies and Brayton cycles. Major conclusions are that a hybrid plant works in optimum conditions which are not equal to those of the solar or power blocks considered independently, and that hybridizing at the Brayton cycle of a combined cycle could be energetically advantageous. -- Highlights: •We model a generic solar–fossil hybrid Brayton cycle. •We calculate the operating conditions for maximum ratio power/fuel consumption. •Best hybrid plant conditions are not the same as solar or power blocks separately. •We study potential for hybridization with current solar technologies. •Hybridization at the Brayton in a combined cycle may achieve high power/fuel ratio

  1. Experimentation of a LiBr–H2O absorption process for long-term solar thermal storage: Prototype design and first results

    International Nuclear Information System (INIS)

    N'Tsoukpoe, K.E.; Le Pierrès, N.; Luo, L.

    2013-01-01

    The long-term thermal storage by absorption process studied in this paper is devoted to building heating. A demonstrative prototype that can store 8 kWh of heat and produce a heating power of 1 kW has been designed and built. It has been tested in static and dynamic operating conditions, which are compatible with domestic solar thermal and heating plants. The process operating principle, the prototype design and first experimental results are presented and discussed in this contribution. The charging process has been proved successful. The observed power during the charging phases is satisfactory, according to the process design for a real plant (2–5 kW). Absorption during discharging phase is also verified. Discharging tests show that absorption operates in conditions that could allow house heating as the absorber outlet solution temperature can reach 40 °C. However, some problems related to the absorber design have not allowed observing the heat recovery by the heat transfer fluid as expected. Some avenues are explored prior to a new and more appropriate design and eventually a new operating mode. Various aspects such as the use of a heat and mass transfer enhancement additive and stratification in the solution storage tank have also been addressed. - Highlights: ► A long-term thermal storage prototype is tested under practical conditions. ► For the prototype design, a separate reactor is used with integrated components. ► The observed powers during the charging phases are satisfactory (2–5 kW). ► Following crystallisation phases, discharging tests enabled the crystal dissolution. ► Absorber temperature that could allow house heating (up to 40°C) has been observed

  2. Coherent hole burning and Mollow absorption effects in the cycling transition Fe=0↔Fg=1 subject to a magnetic field

    International Nuclear Information System (INIS)

    Gu Ying; Sun Qingqing; Gong Qihuang

    2004-01-01

    With saturation and probing by circularly polarized fields, quantum coherence effects are investigated for the cycling transition F e =0↔F g =1, which is subject to a linearly polarized field and a magnetic field. The saturation field is applied to the case of maximum coherence between the drive Rabi frequency and magnetic field, corresponding to the electromagnetically induced absorption (EIA) with negative dispersion found by Gu et al. For a small saturation Rabi frequency, holes are burned in two Autler-Towns peaks outside two symmetric electromagnetically induced transparency windows due to the two-photon resonance. However, when the saturation Rabi frequency is comparable with the drive Rabi frequency, holes caused by the coherent population oscillation appear in the EIA spectrum. Finally, when the saturation Rabi frequency is large enough, several emission peaks are observed due to the Mollow absorption effects. Furthermore, the dispersion at the pump-probe detuning center is kept negative with an increase in saturation field, which is a precursor of superluminal light propagation

  3. Interfacial Shear Strength Evaluation of Pinewood Residue/High-Density Polyethylene Composites Exposed to UV Radiation and Moisture Absorption-Desorption Cycles

    Directory of Open Access Journals (Sweden)

    Soledad C. Pech-Cohuo

    2016-03-01

    Full Text Available In outdoor applications, the mechanical performance of wood-plastic composites (WPCs is affected by UV radiation, facilitating moisture intake and damaging the wood-polymer interfacial region. The purpose of this study was to evaluate the effect of moisture absorption-desorption cycles (MADCs, and the exposure to UV radiation on the interfacial shear strength (IFSS of WPCs with 40% pinewood residue and 60% high-density polyethylene. One of the WPCs incorporated 5% coupling agent (CA with respect to wood content. The IFSS was evaluated following the Iosipescu test method. The specimens were exposed to UV radiation using an accelerated weathering test device and subsequently subjected to four MADCs. Characterization was also performed by scanning electron microscopy (SEM and Fourier transform infrared spectroscopy (FTIR. The absorption and desorption of moisture was slower in non-UV-irradiated WPCs, particularly in those with the CA. The UV radiation did not significantly contribute to the loss of the IFSS. Statistically, the CA had a favorable effect on the IFSS. Exposure of the samples to MADCs contributed to reduce the IFSS. The FTIR showed lignin degradation and the occurrence of hydrolysis reactions after exposure to MADCs. SEM confirmed that UV radiation did not significantly affect the IFSS.

  4. Effects of bonding bakeout thermal cycles on pre- and post irradiation microstructures, physical, and mechanical properties of copper alloys

    Energy Technology Data Exchange (ETDEWEB)

    Singh, B.N.; Eldrup, M.; Toft, P.; Edwards, D.J. [Pacific Northwest National Laboratory, Richland, WA (United States)

    1996-10-01

    At present, dispersion strengthened (DS) copper is being considered as the primary candidate material for the ITER first wall and divertor components. Recently, it was agreed among the ITER parties that a backup alloy should be selected from the two well known precipitation hardened copper alloys, CuCrZr and CuNiBe. It was therefore decided to carry out screening experiments to simulate the effect of bonding and bakeout thermal cycles on microstructure, mechanical properties, and electrical resistivity of CuCrZr and CuNiBe alloys. On the basis of the results of these experiments, one of the two alloys will be selected as a backup material. Tensile specimens of CuCrZr and CuNiBe alloys were given various heat treatments corresponding to solution anneal, prime ageing, and bonding thermal cycle followed by reageing and the reactor bakeout treatment at 623K for 100 hours. Tensile specimens of the DS copper were also given the heat treatment corresponding to the bonding thermal cycle. A number of these heat treated specimens of CuCrZr, CuNiBe, and DS copper were neutron irradiated at 523K to a dose level of {approx}0.3 dpa (NRT) in the DR-3 reactor at Riso. Both unirradiated and irradiated specimens with the various heat treatments were tensile tested at 532K. The dislocation, precipitate and void microstructures and electrical resistivity of these specimens were also determined. Results of these investigations will be reported and discussed in terms of thermal and irradiation stability of precipitates and irradiation-induced precipitation and recovery of dislocation microstructure. Results show that the bonding and bakeout thermal cycles are not likely to have any serious deleterious effects on the performance of these alloys. The CuNiBe alloys were found to be susceptible to radiation-induced embrittlement, however, the exact mechanism is not yet known. It is thought that radiation-induced precipitation and segregation of the beryllium may be responsible.

  5. Measured thermal and fast neutron fluence rates, ATR Cycle 100-BC, April 23, 1993--May 13, 1993

    International Nuclear Information System (INIS)

    Smith, L.D.; Murray, R.K.; Rogers, J.W.

    1993-07-01

    This report contains the thermal (2200 m/s) and fast (E>1MeV) neutron fluence rate data for ATR Cycle 100-BC which were measured by the Radiation Measurements Laboratory (RML) as requested by the Power Reactor Programs (ATR Experiments) Radiation Measurements Work Order. This report contains fluence rate values corresponding to the particular elevations (relative to the 80 ft. core elevation) where the measurements were taken. The data in this report consists of (1) a table of the ATR power history and distribution, (2) a hard copy listing of all thermal and fast neutron fluence rates, (3) plots of both the thermal and fast neutron fluence rates, and (4) a magnetic record (3.5 inch diskette) containing a listing of only the fast neutron fluence rates, their assigned elevations and proper header identification of all monitor positions contained herein. The fluence rates reported are for the average power levels given in the table of power history and distribution. All open-quotes Hclose quotes holder monitor wires for this cycle are 54 inches long. All open-quotes SRclose quotes holder monitor wires for this cycle are 55 inches long. This length allows measurement of the full core region and makes the first count elevation 24.73 inches above core midplane. Due to the safety rod problems in the west lobe, open-quotes BRclose quotes holders were used in the W-1, 2, 3, and 4 positions. All open-quotes BRclose quotes holder monitor wires for this cycle are 56.25 inches long. The distance from the end of the wires to the first count position was 4.25 inches for all wires counted from this cycle. The results from the measurements in the W-1, 2, 3, 4 monitor positions indicate that the safety rod followers were rotated to a different azimuthal orientation relative to the normal orientation. The results indicate that the rotation was counterclockwise from their normal orientation. This is the same condition observed starting with Cycle 99-B

  6. Exergy analysis of a combined vapor power cycle and boiler flue gas driven double effect water–LiBr absorption refrigeration system

    International Nuclear Information System (INIS)

    Talukdar, K.; Gogoi, T.K.

    2016-01-01

    Highlights: • A combined vapor power and double effect water–LiBr absorption refrigeration system is proposed. • The flue gas of the power cycle boiler is the heat source for the double effect refrigeration system. • Energy and exergy analyses are performed to evaluate performance of the combined system. • Effect of high pressure generator temperature on combined system performance is highlighted. • Comparison is provided with a single effect absorption system integrated combined system. - Abstract: A combined vapor power cycle (PC) and double effect water–LiBr absorption refrigeration system (ARS) is proposed in this study. The boiler leaving flue gas of the PC is the heat source for the high pressure generator (HPG) of the double effect ARS. Exergy analysis of the proposed system is performed to show the performance variation of both the topping PC and the bottoming ARS with changing HPG temperature from 120 °C to 150 °C. Further the performance of double effect ARS integrated combined power and cooling system is compared with a similar system integrated with a single effect ARS. HPG temperature of the double effect ARS and generator temperature of the single effect ARS are considered as 120 °C and 80 °C respectively. Results show that the power and efficiency of the topping PC decreases with HPG temperature due to reduction in steam generation rate in the boiler. COP and exergy efficiency of the double effect ARS also reduces with increasing HPG temperature. The irreversible losses in the PC components decrease while the total irreversibility of the combined power and cooling system increases with HPG temperature due to increase in exergy loss with the HPG leaving flue gas and irreversibility of the ARS components. PC performance does not vary much due to replacement of the double effect ARS with the single effect ARS, however higher COP and exergy efficiency of the double effect system are achieved with much lower irreversible losses in the

  7. Underwater Cycle Ergometry: Power Requirements With and Without Diver Thermal Dress

    National Research Council Canada - National Science Library

    Shykoff, B

    2009-01-01

    .... An ongoing problem has been that, although the power requirement of cycling in the water is known to be greater than that in air for the same ergometer setting, the magnitude of the difference...

  8. A comparison of advanced thermal cycles suitable for upgrading existing power plant

    International Nuclear Information System (INIS)

    Heyen, G.; Kalitventzeff, B.

    1999-01-01

    In view of the constant growth of electricity usage and public pressure to reduce the dependence on nuclear power plants in the energy supply, solutions are sought to increase the capacity of power plants using fossil fuels. Highly efficient cycles are available: gas turbines combined with waste heat boilers and steam cycles are able to achieve efficiencies above 50-55%. However building new plants requires a large amount of capital.Alternative proposals are based on upgrades of existing plants : capital savings are expected by reusing part of the facilities. In the present study, three parallel proposals are compared on the basis of exergy efficiency; cost of investment and flexibility of operation are also discussed. They are compared with classical Rankine cycle and state of the art combined cycles. (Copyright (c) 1999 Elsevier Science B.V., Amsterdam. All rights reserved.)

  9. Controlling successive ionic layer absorption and reaction cycles to optimize silver nanoparticle-induced localized surface plasmon resonance effects on the paper strip

    Science.gov (United States)

    Lee, Jae-Chul; Kim, Wansun; Park, Hun-Kuk; Choi, Samjin

    2017-03-01

    This study investigates why a silver nanoparticle (SNP)-induced surface-enhanced Raman scattering (SERS) paper chip fabricated at low successive ionic layer absorption and reaction (SILAR) cycles leads to a high SERS enhancement factor (7 × 108) with an inferior nanostructure and without generating a hot spot effect. The multi-layered structure of SNPs on cellulose fibers, verified by magnified scanning electron microscopy (SEM) and analyzed by a computational simulation method, was hypothesized as the reason. The pattern of simulated local electric field distribution with respect to the number of SILAR cycles showed good agreement with the experimental Raman intensity, regardless of the wavelength of the excitation laser sources. The simulated enhancement factor at the 785-nm excitation laser source (2.8 × 109) was 2.5 times greater than the experimental enhancement factor (1.1 × 109). A 532-nm excitation laser source exhibited the highest maximum local electric field intensity (1.9 × 1011), particularly at the interparticle gap called a hot spot. The short wavelength led to a strong electric field intensity caused by strong electromagnetic coupling arising from the SNP-induced local surface plasmon resonance (LSPR) effects through high excitation energy. These findings suggest that our paper-based SILAR-fabricated SNP-induced LSPR model is valid for understanding SNP-induced LSPR effects.

  10. The effect of firing temperature on the irreversible expansion, water absorption and pore structure of a brick body during freeze-thaw cycles

    Directory of Open Access Journals (Sweden)

    Mikuláš ŠVEDA

    2013-12-01

    Full Text Available The paper deals with the monitoring of brick body in the process of volumetric freezing and thawing. The samples were fired at temperatures of 900, 1000 and 1060 °C. Attention is focused on monitoring of the irreversible expansion, water absorption and pore structure of a brick body. We found that in all cases the endpoints take place continuously, where the amount firing temperature plays a crucial role. The greatest influence of freeze/thaw cycles on the change of the pore structure was also observed at the lowest temperature. The change of the pore system during the freeze-thaw cycles occurs in such a way, that the pore volume of small pores further decreases and conversely, the pore volume of large pores increases. The knowledge gained can be used not only in the production of new but also in predicting the remaining durability of older clay roofing tiles. DOI: http://dx.doi.org/10.5755/j01.ms.19.4.2741

  11. Thermal and pseudoelastic cycling in Cu-14.1Al-4.2Ni (wt%) single crystals

    International Nuclear Information System (INIS)

    Gastien, R.; Corbellani, C.E.; Sade, M.; Lovey, F.C.

    2005-01-01

    Thermally and stress induced martensitic transformations between β and a mixture of martensitic structures, β' and γ', were studied in Cu-14.1Al-4.2Ni (wt%) single crystals. In this way information on the relative stability between β' and γ' martensites, compared to the β phase, was obtained. The measurement of electrical resistance as a function of temperature was used to follow the evolution of thermally induced transitions. The stress induced transformations were analyzed in the small temperature range at which the pseudoelastic behavior between β and a mixture of both martensites plays the main role. A clear inhibition of the γ' martensite is detected as the number of cycles increases, no matter which thermodynamic coordinate is varied to induce the phase transition, i.e., temperature or stress. An evaluation of the magnitude of the relative stabilization of the β' martensite compared with γ' was obtained by a suitably designed experiment

  12. Propagation of internal stresses in composite materials during heating and cooling according to thermal cycles of welding

    International Nuclear Information System (INIS)

    Gukasyan, L.E.; Belov, V.V.

    1977-01-01

    Investigations of free thermal expansion of a composite material, of fibre and matrix during welding thermal cycle make it possible to estimate mean internal strain and stress in the composite components, as well as the residual internal stress and strain present in the composite material after manufacturing. The samples investigated consisted of nickel-chromium EhI445 alloy, reinforced by tungsten-rhenium alloy fibres. As the composite material was cooled and heated in course of welding, the stress and strain changed their sign twice, the first time upon heating, the second time upon cooling. After complete cooling of the composite material residual stresses in the fibre stay at the proportionality level, while those in the matrix are lower. Experimental evidence of internal stress and strain appearing in the composite material during heating are fairly consistent with calculations in the elastic region, if account is taken of the temperature of internal residual stress relaxation upon heating

  13. Nanodomain Engineered (K, Na)NbO3 Lead-Free Piezoceramics: Enhanced Thermal and Cycling Reliabilities

    DEFF Research Database (Denmark)

    Yao, Fang-Zhou; Wang, Ke; Cheng, Li-Qian

    2015-01-01

    - based materials, accepting the drawbacks of high temperature and cycling instabilities. Here, we present that CaZrO3-modified (K, Na)NbO3 piezoceramics not only possess excellent performance at ambient conditions benefiting from nanodomain engineering, but also exhibit superior stability against......The growing environmental concerns have been pushing the development of viable green alternatives for lead-based piezoceramics to be one of the priorities in functional ceramic materials. A polymorphic phase transition has been utilized to enhance piezoelectric properties of lead-free (K, Na)NbO3...... temperature fluctuation and electrical fatigue cycling. It was found that the piezoelectric coefficient d33 is temperature independent under 4 kV/mm, which can be attributed to enhanced thermal stability of electric field engineered domain configuration; whereas the electric field induced strain exhibits...

  14. Evaluation of the energy efficiency of combined cycle gas turbine. Case study of Tashkent thermal power plant, Uzbekistan

    International Nuclear Information System (INIS)

    Aminov, Zarif; Nakagoshi, Nobukazu; Xuan, Tran Dang; Higashi, Osamu; Alikulov, Khusniddin

    2016-01-01

    Highlights: • The combined cycle power plant (CCPP) has a steam turbine and a gas turbine. • Fossil fuel savings and reduction of the CCGT of was evaluated. • The performance of a three pressure CCGT is modelled under different modes. • Energy efficiency of the combined cycle was 58.28%. • An annual reduction of 1760.18 tNO_x/annum and 981.25 ktCO_2/annum can be achieved. - Abstract: The power generation of Tashkent Thermal Power Plant (TPP) is based on conventional power units. Moreover, the facility suffers from limited efficiency in electricity generation. The plant was constructed during the Soviet era. Furthermore, the power plant is being used for inter-hour power generation regulation. As a result, the efficiency can be reduced by increasing specific fuel consumption. This research focuses on the evaluation of the energy efficiency of the combined cycle gas turbine (CCGT) for the Tashkent TPP. Specifically, the objective is an evaluation of fossil fuel savings and reduction of CO_2 and NO_x emissions with the using CCGT technology at conventional power plant. The proposed combined cycle power plant (CCPP) includes an existing steam turbine (ST) with 160 MW capacity, heat recovery steam generator (HRSG), and gas turbine (GT) technology with 300 MW capacity. The performance of a three pressure CCGT is modelled under different modes. As a result, the efficiency of the combined cycle was evaluated at 58.28%, while the conventional cycle had an efficiency of 34.5%. We can achieve an annual reduction of 1760.18 tNO_x/annum and 981.25 ktCO_2/annum.

  15. A review of test results on solar thermal power modules with dish-mounted Stirling and Brayton cycle engines

    Science.gov (United States)

    Jaffe, Leonard D.

    1988-01-01

    This paper presents results of development tests of various solar thermal parabolic dish modules and assemblies that used dish-mounted Brayton or Stirling cycle engines for production of electric power. These tests indicate that early modules achieve net efficiencies up to 29 percent in converting sunlight to electricity, as delivered to the grid. Various equipment deficiencies were observed and a number of malfunctions occurred. The performance measurements, as well as the malfunctions and other test experience, provided information that should be of value in developing systems with improved performance and reduced maintenance.

  16. Effect of bonding and bakeout thermal cycles on the properties of copper alloys irradiated at 350 degrees C

    DEFF Research Database (Denmark)

    Singh, B.N.; Edwards, D.J.; Eldrup, Morten Mostgaard

    2001-01-01

    Screening experiments were carried out to determine the effect of bonding and bakeout thermal cycles on microstructure, mechanical properties and electrical resistivity of the oxide dispersion strengthened (GlidCop, CuAl-25) and the precipitation hardened (CuCrZr, CuNiBe) copper alloys. Tensile...... results are described and their salient features discussed. The most significant effect of neutron irradiation is a severe loss of ductility in the case of CuNiBe alloys. (C) 2001 Elsevier Science B.V. All rights reserved....

  17. A review of test results on solar thermal power modules with dish-mounted Stirling and Brayton cycle engines

    Science.gov (United States)

    Jaffe, Leonard D.

    1988-11-01

    This paper presents results of development tests of various solar thermal parabolic dish modules and assemblies that used dish-mounted Brayton or Stirling cycle engines for production of electric power. These tests indicate that early modules achieve net efficiencies up to 29 percent in converting sunlight to electricity, as delivered to the grid. Various equipment deficiencies were observed and a number of malfunctions occurred. The performance measurements, as well as the malfunctions and other test experience, provided information that should be of value in developing systems with improved performance and reduced maintenance.

  18. Integration of photovoltaic and concentrated solar thermal technologies for H2 production by the hybrid sulfur cycle

    Science.gov (United States)

    Liberatore, Raffaele; Ferrara, Mariarosaria; Lanchi, Michela; Turchetti, Luca

    2017-06-01

    It is widely agreed that hydrogen used as energy carrier and/or storage media may significantly contribute in the reduction of emissions, especially if produced by renewable energy sources. The Hybrid Sulfur (HyS) cycle is considered as one of the most promising processes to produce hydrogen through the water-splitting process. The FP7 project SOL2HY2 (Solar to Hydrogen Hybrid Cycles) investigates innovative material and process solutions for the use of solar heat and power in the HyS process. A significant part of the SOL2HY2 project is devoted to the analysis and optimization of the integration of the solar and chemical (hydrogen production) plants. In this context, this work investigates the possibility to integrate different solar technologies, namely photovoltaic, solar central receiver and solar troughs, to optimize their use in the HyS cycle for a green hydrogen production, both in the open and closed process configurations. The analysis carried out accounts for different combinations of geographical location and plant sizing criteria. The use of a sulfur burner, which can serve both as thermal backup and SO2 source for the open cycle, is also considered.

  19. Effect of Gaseous Impurities on Long-Term Thermal Cycling and Aging Properties of Complex Hydrides for Hydrogen Storage

    Energy Technology Data Exchange (ETDEWEB)

    Chandra, Dhanesh [Primary Contact; Lamb, Joshua; Chien, Wen-Ming; Talekar, Anjali; and Pal, Narendra

    2011-03-28

    This program was dedicated to understanding the effect of impurities on Long-Term Thermal Cycling and aging properties of Complex Hydrides for Hydrogen Storage. At the start of the program we found reversibility between Li2NH+LiH LiH+LiNH2 (yielding ~5.8 wt.%H capacity). Then we tested the effect of impurity in H2 gas by pressure cycling at 255°C; first with industrial gas containing ppm levels of O2 and H2O as major impurities. Both these impurities had a significant impact on the reversibility and decreased the capacity by 2.65 wt.%H. Further increase in number of cycles from 500 to 1100 showed only a 0.2 wt%H more weight loss, showing some capacity is still maintained after a significant number of cycles. The loss of capacity is attributed to the formation of ~55 wt% LiH and ~30% Li2O, as major contaminant phases, along with the hydride Li2NH phase; suggesting loss of nitrogen during cycling. The effect of 100 ppm H2O in H2 also showed a decrease of ~2.5 wt.%H (after 560 cycles), and 100ppm O2 in H2; a loss of ~4.1 wt.%. Methane impurity (100 ppm, 100cycles), showed a very small capacity loss of 0.9 wt.%H under similar conditions. However, when Li3N was pressure cycled with 100ppmN2-H2 there were beneficial effects were observed (255oC); the reversible capacity increased to 8.4wt.%H after 853 cycles. Furthermore, with 20 mol.%N2-H2 capacity increased to ~10 wt.%H after 516 cycles. We attribute this enhancement to the reaction of nitrogen with liquid lithium during cycling as the Gibbs free energy of formation of Li3N (Go = -98.7 kJ/mol) is more negative than that of LiH (Go = -50.3 kJ/mol). We propose that the mitigation of hydrogen capacity losses is due to the destabilization of the LiH phase that tends to accumulate during cycling. Also more Li2NH phase was found in the cycled product. Mixed Alanates (3LiNH2:Li3AlH6) showed that 7 wt% hydrogen desorbed under dynamic vacuum. Equilibrium experiments (maximum 12 bar H2) showed up to 4wt% hydrogen reversibly

  20. Life cycle cost optimization of buildings with regard to energy use, thermal indoor environment and daylight

    DEFF Research Database (Denmark)

    Nielsen, Toke Rammer; Svendsen, Svend

    2002-01-01

    by the life cycle cost taking all expenses in the buildings service life into consideration. Also the performance of buildings is important as the performance influences the comfort of the occupants, heating demand etc. Different performance requirements are stated in building codes, standards......Buildings represent a large economical investment and have long service lives through which expenses for heating, cooling, maintenance and replacement depends on the chosen building design. Therefore, the building cost should not only be evaluated by the initial investment cost but rather...... and by the customer. The influence of different design variables on life cycle cost and building performance is very complicated and the design variables can be combined in an almost unlimited number of ways. Optimization can be applied to achieve a building design with low life cycle cost and good performance...

  1. Comparative energy analysis on a new regenerative Brayton cycle

    International Nuclear Information System (INIS)

    Goodarzi, M.

    2016-01-01

    Highlights: • New regenerative Brayton cycle has been introduced. • New cycle has higher thermal efficiency and lower exhausted heat per output power. • Regenerator may remain useful in the new cycle even at high pressure ratio. • New regenerative Brayton cycle is suggested for low pressure ratio operations. - Abstract: Gas turbines are frequently used for power generation. Brayton cycle is the basis for gas turbine operation and developing the alternative cycles. Regenerative Brayton cycle is a developed cycle for basic Brayton cycle with higher thermal efficiency at low to moderate pressure ratios. A new regenerative Brayton cycle has been introduced in the present study. Energy analysis has been conducted on ideal cycles to compare them from the first law of thermodynamics viewpoint. Comparative analyses showed that the new regenerative Brayton cycle has higher thermal efficiency than the original one at the same pressure ratio, and also lower heat absorption and exhausted heat per unite output power. Computed results show that new cycle improves thermal efficiency from 12% to 26% relative to the original regenerative Brayton cycle in the range of studied pressure ratios. Contrary to the original regenerative Brayton cycle, regenerator remains useful in the new regenerative Brayton cycle even at higher pressure ratio.

  2. Investigation of Water Absorption and Diffusion in Microparticles Containing Xylitol to Provide a Cooling Effect by Thermal Analysis

    Science.gov (United States)

    Salaün, F.; Bedek, G.; Devaux, E.; Dupont, D.; Deranton, D.

    2009-08-01

    Polyurethane microparticles containing xylitol as a sweat sensor system were prepared by interfacial polymerization. The structural and thermal properties of the resultant microparticles were studied. The surface morphology and chemical structure of microparticles were investigated using an optical microscope (OM) and a Fourier-transform infrared spectroscope (FTIR), respectively. The thermal properties of samples were investigated by thermogravimetric analysis (TGA) and by differential scanning calorimetry (DSC). Thus, two types of microparticles were synthesized by varying the percentage of monomers introduced. The obtained morphology is directly related to the synthesis conditions. DSC analysis indicated that the mass content of crystalline xylitol was up to 63.8 %, which resulted in a high enthalpy of dilution of 127.7 J · g-1. Furthermore, the water release rate monitored by TGA analysis was found to be faster from the microparticles than from raw xylitol. Thus, the microparticles could be applied for thermal energy storage and moisture sensor enhancement.

  3. Influence of Absorption of Thermal Radiation in the Surface Water Film on the Characteristics and Ignition Conditions

    Directory of Open Access Journals (Sweden)

    Syrodoy Samen V.

    2016-01-01

    Full Text Available The results of the mathematical modeling of homogeneous particle ignition process of coal-water fuel covered with water film have been presented in article. The set co-occurring physical (inert heating, evaporation of water film and thermochemical (thermal degradation, inflammation process have been considered. Heat inside the film has been considered as the model of radiation-conductive heat transfer. Delay times have been determined according to the results of numerical modeling of the ignition. It has been shown that the water film can have a significant impact on performance and the ignition conditions. It has been found that heating main fuel layer occurs in the process of evaporation of water film. For this reason, the next (after the evaporation of the water film thermal preparation (coal heating, thermal decomposition of the organic part of the fuel and inflammation occur faster.

  4. Reactive power influence on the thermal cycling of multi-MW wind power inverter

    DEFF Research Database (Denmark)

    Ma, Ke; Liserre, Marco; Blaabjerg, Frede

    2012-01-01

    converter system are first presented at different wind speeds. Furthermore, the interaction between paralleled converter systems in a wind park is also considered and analyzed. By controlling the reactive power circulated among paralleled converters, a new concept is then proposed to stabilize the thermal...

  5. Effect of Thermal Cycling on Zinc Antimonide Thin Film Thermoelectric Characteristics

    DEFF Research Database (Denmark)

    Mirhosseini, M.; Rezania, A.; Rosendahl, L.

    2017-01-01

    In this study, performance and stability of zinc antimonide thin film thermoelectric sample is analyzed under transient thermal conditions. The thermoelectric materials are deposited on glass based substrate where the heat flow is parallel with the thermoelectric element length. The specimen...

  6. Thermophysical characterization and thermal cycling stability of two TCM: CaCl2 and zeolite

    NARCIS (Netherlands)

    Barreneche, C.; Fernández, A.I.; Cabeza, L.F.; Cuypers, R.

    2015-01-01

    At this moment, the global energy consumption in buildings is around 40% of the total energy consumption in developed countries. Thermal energy storage (TES) is presented as one way to address this energy-related problem proposing an alternative to reduce the gap between energy supply and energy

  7. Thermal behavior of J-aggregates in a Langmuir-Blodgett film of pure merocyanine dye investigated by UV-visible and IR absorption spectroscopy.

    Science.gov (United States)

    Hirano, Yoshiaki; Tateno, Shinsuke; Maio, Ari; Ozaki, Yukihiro

    2009-03-05

    We have characterized the structure of J-aggregate in a Langmuir-Blodgett film of pure merocyanine dye (MS18) fabricated under an aqueous subphase containing a cadmium ion (Cd2+) and have investigated its thermal behavior by UV-visible and IR absorption spectroscopy in the range from 25 to 250 degrees C with a continuous scan. The results of both UV-visible and IR absorption spectra indicate that temperature-dependent changes in the MS18 aggregation state in the pure MS18 system are closely and mildly linked with the MS18 intramolecular charge transfer and the behavior of the packing, orientation, conformation, and thermal mobility of MS18 hydrocarbon chain, respectively. The J-aggregate in the pure MS18 system dissociates from 25 to 150 degrees C, and the dissociation temperature at 150 degrees C is higher by 50 degrees C than that in the previous MS18- arachidic acid (C20) binary system. The lower dissociation temperature in the binary system originates from the fact that temperature-dependent structural disorder of cadmium arachidate (CdC20), being phase-separated from MS18, has an influence on the dissociation of J-aggregate. From 160 to 180 degrees C, thermally induced blue-shifted bands, caused by the oligomeric MS18 aggregation, appear at around 520 nm in the pure MS18 system by contraries, regardless of the lack of driving force by the melting phenomenon of CdC20. The temperature at which the 520 nm bands occur is in good agreement with the melting point (160 degrees C) of hydrocarbon chain in MS18 with Cd2+, whereas its chromophore part is clearly observed to melt near 205 degrees C by UV-visible spectra. Therefore, it is suggested that the driving force that induces the 520 nm band in the pure MS18 system arises from the partial melting of hydrocarbon chain in MS18 with Cd2+.

  8. Multiple regression models for the prediction of the maximum obtainable thermal efficiency of organic Rankine cycles

    DEFF Research Database (Denmark)

    Larsen, Ulrik; Pierobon, Leonardo; Wronski, Jorrit

    2014-01-01

    Much attention is focused on increasing the energy efficiency to decrease fuel costs and CO2 emissions throughout industrial sectors. The ORC (organic Rankine cycle) is a relatively simple but efficient process that can be used for this purpose by converting low and medium temperature waste heat ...

  9. COMBINED CYCLE GAS TURBINE FOR THERMAL POWER STATIONS: EXPERIENCE IN DESIGNING AND OPERATION, PROSPECTS IN APPLICATION

    Directory of Open Access Journals (Sweden)

    N. V. Karnitsky

    2014-01-01

    Full Text Available The paper has reviewed main world tendencies in power consumption and power system structure. Main schemes of combined cycle gas turbines have been considered in the paper. The paper contains an operational analysis of CCGT blocks that are operating within the Belarusian energy system. The analysis results have been given in tables showing main operational indices of power blocks

  10. Optimization of Brayton cycles for low-to-moderate grade thermal energy sources

    International Nuclear Information System (INIS)

    Rovira, Antonio; Muñoz-Antón, Javier; Montes, María José; Martínez-Val, José María

    2013-01-01

    Future electricity generation will involve low or moderate temperature technologies. In such a scenario, optimisation of thermodynamic cycles will be a key task. This work presents a systematic analysis to find the operating regime where Brayton cycles reach the highest efficiency, using real substances and given heat source and sink temperatures. Several configurations using fluids close to its critical point at the compressor inlet are considered. Irreversibility sources are carefully analysed, as well as the type of working fluid. The analysis is performed by means of a theoretical approach to obtain some trends, which are afterwards validated with real gases. Results show that the efficiency and the specific work improve if the compressor inlet is close to the critical point. Furthermore, these cycles are less sensitive to pressure drops and politropic efficiencies than those working with ideal gases. The above features are more evident when the ratio of heat source and heat sink temperatures is low. The selection of the gas becomes a fundamental issue in this quest. Critical temperature should be close to ambient temperature, low critical pressure is advisable and the R/c p factor measured at the ideal gas condition should be low to further enhance the efficiency. - Highlights: • Performance analysis of Brayton cycles with the compressor inlet close to the critical point. • Cycles are not very sensitive to pressure drops and isentropic efficiencies of the compressor. • Gas selection becomes important, regarding the critical pressure and temperature as well as the kind of fluid. • R/c p factor measured at the ideal gas condition should be as low as possible

  11. Analysis of environmental effect of hybrid solar-assisted desalination cycle in Sirdarya Thermal Power Plant, Uzbekistan

    International Nuclear Information System (INIS)

    Alikulov, Khusniddin; Xuan, Tran Dang; Higashi, Osamu; Nakagoshi, Nobukazu; Aminov, Zarif

    2017-01-01

    Highlights: • A hybrid solar-assisted desalination cycle was designed and stimulated. • Maximum of 21,064.00 kW effective solar heat can be achieved. • The use of parabolic-trough collectors in the Multi Effect Distillation is potential. • The cycle can be applied in other regions with high Direct Normal Irradiation. - Abstract: This study was to investigate possible reduction of fossil fuel consumption and carbon dioxide emission in one of energy sectors of Sirdarya Thermal Power Plant (TPP), Uzbekistan. A hybrid solar-assisted desalination cycle has been designed and simulated for partially supplying saturated steam with 200 °C, 8 bar, and 32 t/h parameters to a Multi Effect Distillation (MED) process in the Sirdarya Thermal Power Plant. The outcome of the parental design model stated that maximum, 21,064.00 kW effective solar heat can be achieved, which is equivalent to 31.76 t/h of saturated steam with 200 °C and 8 bar parameters. Total saved fossil fuel in each month proved that it is possible to reduce fossil fuel (heavy oil and natural gas) consumption with 59.64, 95.24, 389.96, and 298.26 tons during available Direct Normal Irradiation (DNI) by using parabolic-trough collectors. Moreover, the above-mentioned fossil fuel savings accounted for CO_2 reduction with amounts of 182.50, 255.46, 1045.87 & 799.96 tons per each consistent month. Findings proved that integration of parabolic-trough collectors into the MED process is feasible in terms of high DNI availability and demand for retrofitting old existing heat-consuming facilities in Sirdarya Thermal Power Plant. Besides, the cycle also can be applied in other regions of Uzbekistan with high DNI for generating solar heat. Therefore, conducted study is eligible to be applied on the research site by taking into account of sufficient meteorological data and required steam parameters.

  12. The efficiency of an open-cavity tubular solar receiver for a small-scale solar thermal Brayton cycle

    International Nuclear Information System (INIS)

    Le Roux, W.G.; Bello-Ochende, T.; Meyer, J.P.

    2014-01-01

    Highlights: • Results show efficiencies of a low-cost stainless steel tubular cavity receiver. • Optimum ratio of 0.0035 is found for receiver aperture area to concentrator area. • Smaller receiver tube and higher mass flow rate increase receiver efficiency. • Larger tube and smaller mass flow rate increase second law efficiency. • Large-tube receiver performs better in the small-scale solar thermal Brayton cycle. - Abstract: The first law and second law efficiencies are determined for a stainless steel closed-tube open rectangular cavity solar receiver. It is to be used in a small-scale solar thermal Brayton cycle using a micro-turbine with low compressor pressure ratios. There are many different variables at play to model the air temperature increase of the air running through such a receiver. These variables include concentrator shape, concentrator diameter, concentrator rim angle, concentrator reflectivity, concentrator optical error, solar tracking error, receiver aperture area, receiver material, effect of wind, receiver tube diameter, inlet temperature and mass flow rate through the receiver. All these variables are considered in this paper. The Brayton cycle requires very high receiver surface temperatures in order to be successful. These high temperatures, however, have many disadvantages in terms of heat loss from the receiver, especially radiation heat loss. With the help of ray-tracing software, SolTrace, and receiver modelling techniques, an optimum receiver-to-concentrator-area ratio of A′ ≈ 0.0035 was found for a concentrator with 45° rim angle, 10 mrad optical error and 1° tracking error. A method to determine the temperature profile and net heat transfer rate along the length of the receiver tube is presented. Receiver efficiencies are shown in terms of mass flow rate, receiver tube diameter, pressure drop, maximum receiver surface temperature and inlet temperature of the working fluid. For a 4.8 m diameter parabolic dish, the

  13. Absorption and stimulated emission between the electronic states of C and C_2 radicals in an expanding thermal plasma

    NARCIS (Netherlands)

    Otorbaev, D.K.; Sanden, van de M.C.M.; Buuron, A.J.M.; Schram, D.C.

    1995-01-01

    Using the method of reabsorption the absolute densities of argon, atomic and molecular carbon are determined during the deposition of amorphous hydrogenated (diamond-like) carbon coatings by an expanding thermal are plasma. Depending on the gas mixture argon/methane or argon/acetylene and the manner

  14. Thermal diffusion of chlorine in uranium dioxide studied by secondary ion mass spectrometry and X-ray absorption spectroscopy

    Science.gov (United States)

    Pipon, Y.; Toulhoat, N.; Moncoffre, N.; Raimbault, L.; Scheidegger, A. M.; Farges, F.; Carlot, G.

    2007-05-01

    In a nuclear reactor, 35Cl present as an impurity in the nuclear fuel is activated by thermal neutron capture. During interim storage or geological disposal of the nuclear fuel, 36Cl may be released from the fuel to the geo/biosphere and contribute significantly to the 'instant release fraction'. In order to elucidate the diffusion mechanisms, both irradiation and thermal effects must be assessed. This paper deals with the thermal diffusion of chlorine in depleted UO2. For this purpose, sintered UO2 pellets were implanted with 37Cl at an ion fluence of 1013 cm-2 and successively annealed in the 1175-1475 K temperature range. The implanted chlorine is used to simulate the behaviour of the displaced one due to recoil and to interactions with the fission fragments during reactor operation. The behaviour of the pristine and the implanted chlorine was investigated during thermal annealing. SIMS and μ-XAS (at the Cl-K edge) analyses show that: the thermal migration of implanted chlorine becomes significant at 1275 K; this temperature and the calculated activation energy of 4.3 eV points out the great ability of chlorine to migrate in UO2 at relatively low temperatures, the behaviour of the implanted chlorine which aggregates into 'hot spots' during annealing before its effusion is clearly different from that of the pristine one which remains homogenously distributed after annealing, the 'hot spot' and the pristine chlorine seem to be in different structural environments. Both types of chlorine are assumed to have a valence state of -I, the comparison between an U2O2Cl5 reference compound and the pristine chlorine environment shows a contribution of the U2O2Cl5 to the pristine chlorine.

  15. Thermal diffusion of chlorine in uranium dioxide studied by secondary ion mass spectrometry and X-ray absorption spectroscopy

    International Nuclear Information System (INIS)

    Pipon, Y.; Toulhoat, N.; Moncoffre, N.; Raimbault, L.; Scheidegger, A.M.; Farges, F.; Carlot, G.

    2007-01-01

    In a nuclear reactor, 35 Cl present as an impurity in the nuclear fuel is activated by thermal neutron capture. During interim storage or geological disposal of the nuclear fuel, 36 Cl may be released from the fuel to the geo/biosphere and contribute significantly to the 'instant release fraction'. In order to elucidate the diffusion mechanisms, both irradiation and thermal effects must be assessed. This paper deals with the thermal diffusion of chlorine in depleted UO 2 . For this purpose, sintered UO 2 pellets were implanted with 37 Cl at an ion fluence of 10 13 cm -2 and successively annealed in the 1175-1475K temperature range. The implanted chlorine is used to simulate the behaviour of the displaced one due to recoil and to interactions with the fission fragments during reactor operation. The behaviour of the pristine and the implanted chlorine was investigated during thermal annealing. SIMS and μ-XAS (at the Cl-K edge) analyses show that: (1) the thermal migration of implanted chlorine becomes significant at 1275K; this temperature and the calculated activation energy of 4.3eV points out the great ability of chlorine to migrate in UO 2 at relatively low temperatures; (2) the behaviour of the implanted chlorine which aggregates into 'hot spots' during annealing before its effusion is clearly different from that of the pristine one which remains homogenously distributed after annealing; (3) the 'hot spot' and the pristine chlorine seem to be in different structural environments. Both types of chlorine are assumed to have a valence state of -I; (4) the comparison between an U 2 O 2 Cl 5 reference compound and the pristine chlorine environment shows a contribution of the U 2 O 2 Cl 5 to the pristine chlorine

  16. Effect of Thermal cycles and Dimensions of the Geometry on Residual stress of the Alumina-Kovar Joint

    Science.gov (United States)

    Mishra, Srishti; Pal, Snehanshu; Karak, Swapan Kumar; Shah, Sejal; Venakata Nagaraju, M.; Chakraborty, Arun Kumar

    2018-03-01

    Finite element method is employed to determine the effect of variation of residual stress with dimension and the stress generated under its working condition along the Kovar. 3 different dimensions of Alumina-Kovar joint with height to diameter ratio of 3/10, using TiCuSil as a filler material. Transient Structural Analysis is carried out for three different dimensions (diameter × height) (i) 60mm × 20mm (Geometry 1) (ii) 90mm × 20mm (Geometry 2) (iii) 120mm × 20mm (Geometry 3). A comparative study has been carried out between the residual stresses developed in the brazed joint that have undergone 5 thermal cycles subsequent to brazing and that between the brazed joint. The heating and cooling rates from the brazed temperature is 10°C/up to room temperature. The brazing temperature and holding time considered for the analysis are 900°C and 10 minutes. Representative Volume Element (RVE) model is used for simulation. Sparse Matrix Direct Solver method is used to evaluate the results, using Augmented Lagrange method formulation in the contact region. All the simulations are performed in ANSYS Workbench 15.0, using solver target Mechanical APDL. From, the above simulations it is observed high concentration of residual stress is observed along the filler region i.e. in between Alumina and Kovar, as a result of difference in coefficient of thermal expansion between Alumina and Kovar. The residual stress decreases with increasing dimensions of the geometry and upon application of thermal cycles, subsequent to brazing.

  17. Thermal radiation and heat generation/absorption aspects in third grade magneto-nanofluid over a slendering stretching sheet with Newtonian conditions

    Science.gov (United States)

    Qayyum, Sajid; Hayat, Tasawar; Alsaedi, Ahmed

    2018-05-01

    Mathematical modeling for magnetohydrodynamic (MHD) radiative flow of third grade nano-material bounded by a nonlinear stretching sheet with variable thickness is introduced. The sheet moves with nonlinear velocity. Definitions of thermal radiation and heat generation/absorption are utilized in the energy expression. Intention in present investigation is to develop a model for nanomaterial comprising Brownian motion and thermophoresis phenomena. Newtonian conditions for heat and mass species are imposed. Governing equations of the locally similar flow are attempted through a homotopic technique and behaviors of involved variables on the flow fields are displayed graphically. It is revealed that increasing values of thermal conjugate variable corresponds to high temperature. Numerical investigation are explored to obtain the results of skin friction coefficient and local Nusselt and Sherwood numbers. It is revealed that velocity field reduces in the frame of magnetic variable while reverse situation is observed due to mixed convection parameter. Here qualitative behaviors of thermal field and heat transfer rate are opposite for thermophoresis variable. Moreover nanoparticle concentration and local Sherwood number via Brownian motion parameter are opposite.

  18. Operating conditions of an open and direct solar thermal Brayton cycle with optimised cavity receiver and recuperator

    International Nuclear Information System (INIS)

    Le Roux, W.G.; Bello-Ochende, T.; Meyer, J.P.

    2011-01-01

    The small-scale open and direct solar thermal Brayton cycle with recuperator has several advantages, including low cost, low operation and maintenance costs and it is highly recommended. The main disadvantages of this cycle are the pressure losses in the recuperator and receiver, turbomachine efficiencies and recuperator effectiveness, which limit the net power output of such a system. The irreversibilities of the solar thermal Brayton cycle are mainly due to heat transfer across a finite temperature difference and fluid friction. In this paper, thermodynamic optimisation is applied to concentrate on these disadvantages in order to optimise the receiver and recuperator and to maximise the net power output of the system at various steady-state conditions, limited to various constraints. The effects of wind, receiver inclination, rim angle, atmospheric temperature and pressure, recuperator height, solar irradiance and concentration ratio on the optimum geometries and performance were investigated. The dynamic trajectory optimisation method was applied. Operating points of a standard micro-turbine operating at its highest compressor efficiency and a parabolic dish concentrator diameter of 16 m were considered. The optimum geometries, minimum irreversibility rates and maximum receiver surface temperatures of the optimised systems are shown. For an environment with specific conditions and constraints, there exists an optimum receiver and recuperator geometry so that the system produces maximum net power output. -- Highlights: → Optimum geometries exist such that the system produces maximum net power output. → Optimum operating conditions are shown. → Minimum irreversibility rates and minimum entropy generation rates are shown. → Net power output was described in terms of total entropy generation rate. → Effects such as wind, recuperator height and irradiance were investigated.

  19. Influence of Thermal Aging on Tensile and Low Cycle Fatigue Behavior of Type 316LN Austenitic Stainless Steel Weld Joint

    Science.gov (United States)

    Suresh Kumar, T.; Nagesha, A.; Ganesh Kumar, J.; Parameswaran, P.; Sandhya, R.

    2018-05-01

    Influence of short-term thermal aging on the low-cycle fatigue (LCF) behavior of 316LN austenitic stainless steel weld joint with 0.07 wt pct N has been investigated. Prior thermal exposure was found to improve the fatigue life compared with the as-welded condition. Besides, the treatment also imparted a softening effect on the weld metal, leading to an increase in the ductility of the weld joint which had a bearing on the cyclic stress response. The degree of cyclic hardening was seen to increase after aging. Automated ball-indentation (ABI) technique was employed toward understanding the mechanical properties of individual zones across the weld joint. It was observed that the base metal takes most of the applied cyclic strain during LCF deformation in the as-welded condition. In the aged condition, however, the weld also participates in the cyclic deformation. The beneficial effect of thermal aging on cyclic life is attributed to a reduction in the severity of the metallurgical notch leading to a restoration of ductility of the weld region. The transformation of δ-ferrite to σ-phase during the aging treatment was found to influence the location of crack initiation. Fatigue cracks were found to initiate in the base metal region of the joint in most of the testing conditions. However, embrittlement in the weld metal caused a shift in the point of crack initiation with increasing strain amplitude under LCF.

  20. Thermal cycling damage evolution of a thermal barrier coating and the influence of substrate creep, interface roughness and pre-oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Schweda, Mario; Beck, Tilmann; Singheiser, Lorenz [Forschungszentrum Juelich GmbH (DE). Inst. fuer Energie- und Klimaforschung (IEK), Werkstoffstruktur und Eigenschaften (IEK-2)

    2012-01-15

    The influence of roughness profile shape, roughness depth, bond coat creep strength and pre-oxidation on the thermal cycling damage evolution and lifetime of a plasma-sprayed ZrO{sub 2} thermal barrier coating system was investigated. A simplified model system was used where FeCrAlY substrates simulated the bond coat. Substrate creep was varied by using the oxide dispersoid strengthened alloy MA956 and the conventional material Fecralloy. Stochastic 3- and periodic 2-dimensional roughness profiles were produced by sand blasting and high speed turning. Damage evolution is significantly influenced by substrate creep with a trend to higher lifetimes for the fast creeping substrate. Pre-oxidation has no influence. Lifetimes of the periodically profiled samples are up to 100 times lower than these of stochastically profiled samples. In the case of periodically profiled samples, the highest lifetime was reached for the highest roughness depth combined with local undercuttings in the roughness profile. For stochastically profiled samples the influence of roughness depth could not be determined due to the wide lifetime scatter. (orig.)

  1. Analyze and Improve Lifetime in 3L-NPC Inverter from Power Cycle and Thermal Balance

    DEFF Research Database (Denmark)

    Chen, Quan; Chen, Zhe; Wang, Qunjing

    2014-01-01

    Three-level Neutral-point-clamped (3L-NPC) topology is becoming a realistic alternative to the conventional one in high-voltage and high-power application. Studies show that the power cycling mean time to failure (MTTF) of the semiconductor bond wire in 3L-NPC inverter system may be very short...... under some common conditions. Firstly, this paper shows the impact of some key parameters on power electronic system lifetime according the analysis of semiconductor failure mechanism. Secondly, a switching frequency reduction method based on the position relationship between the flowing current...... and load voltage is applied to reduce power cycle and switching losses. And then, three-level active neutral point-clamped topology is taken into account to wake the most thermo stressed device. In order to validate the improve lifetime method in this paper, a 2MW 3L-NPC converter used in wind energy has...

  2. Thermal efficiency improvement in high output diesel engines a comparison of a Rankine cycle with turbo-compounding

    International Nuclear Information System (INIS)

    Weerasinghe, W.M.S.R.; Stobart, R.K.; Hounsham, S.M.

    2010-01-01

    Thermal management, in particular, heat recovery and utilisation in internal combustion engines result in improved fuel economy, reduced emissions, fast warm up and optimized cylinder head temperatures. turbo-compounding is a heat recovery technique that has been successfully used in medium and large scale engines. Heat recovery to a secondary fluid and expansion is used in large scale engines, such as in power plants in the form of heat recovery steam generators (HRSG) . The present paper presents a thermodynamic analysis of turbo-compounding and heat recovery and utilisation through a fluid power cycle, a technique that is also applicable to medium and small scale engines. In a fluid power cycle, the working fluid is stored in a reservoir and expanded subsequently. The reservoir acts as an energy buffer that improves the overall efficiency, significantly. This paper highlights the relative advantage of exhaust heat secondary power cycles over turbo-compounding with the aid of MATLAB based QSS Toolbox simulation results. Steam has been selected as the working fluid in this work for its superior heat capacity over organic fluids and gases.

  3. Experimental study of refrigeration performance based on linear Fresnel solar thermal photovoltaic system

    Science.gov (United States)

    Song, Jinghui; Yuan, Hui; Xia, Yunfeng; Kan, Weimin; Deng, Xiaowen; Liu, Shi; Liang, Wanlong; Deng, Jianhua

    2018-03-01

    This paper introduces the working principle and system constitution of the linear Fresnel solar lithium bromide absorption refrigeration cycle, and elaborates several typical structures of absorption refrigeration cycle, including single-effect, two-stage cycle and double-effect lithium bromide absorption refrigeration cycle A 1.n effect absorption chiller system based on the best parameters was introduced and applied to a linear Fresnel solar absorption chiller system. Through the field refrigerator performance test, the results show: Based on this heat cycle design and processing 1.n lithium bromide absorption refrigeration power up to 35.2KW, It can meet the theoretical expectations and has good flexibility and reliability, provides guidance for the use of solar thermal energy.

  4. The effects of stacking sequence and thermal cycling on the flexural properties of laminate composites of aluminium-epoxy/basalt-glass fibres

    Science.gov (United States)

    Abdollahi Azghan, Mehdi; Eslami-Farsani, Reza

    2018-02-01

    The current study aimed at investigating the effects of different stacking sequences and thermal cycling on the flexural properties of fibre metal laminates (FMLs). FMLs were composed of two aluminium alloy 2024-T3 sheets and epoxy polymer-matrix composites that have four layers of basalt and/or glass fibres with five different stacking sequences. For FML samples the thermal cycle time was about 6 min for temperature cycles from 25 °C to 115 °C. Flexural properties of samples evaluated after 55 thermal cycles and compared to non-exposed samples. Surface modification of aluminium performed by electrochemical treatment (anodizing) method and aluminium surfaces have been examined by scanning electron microscopy (SEM). Also, the flexural failure mechanisms investigated by the optical microscope study of fractured surfaces. SEM images indicated that the porosity of the aluminium surface increased after anodizing process. The findings of the present study showed that flexural modulus were maximum for basalt fibres based FML, minimum for glass fibres based FML while basalt/glass fibres based FML lies between them. Due to change in the failure mechanism of basalt/glass fibres based FMLs that have glass fibres at outer layer of the polymer composite, the flexural strength of this FML is lower than glass and basalt fibres based FML. After thermal cycling, due to the good thermal properties of basalt fibres, flexural properties of basalt fibres based FML structures decreased less than other composites.

  5. Influence of cycling thermal loading on brazed composites for fusion applications

    International Nuclear Information System (INIS)

    Smid, I.; Kny, E.; Kneringer, G.; Reheis, N.

    1995-01-01

    Reactor grade graphite and molybdenum (TZM) were brazed with different high temperature brazes. The resulting tiles had a size of 50 x 50 mm 2 with a graphite thickness of 10 mm and a TZM thickness of 5 mm. The brazed composites have been tested in electron beam simulation for their thermal fatigue properties. The parameters of these tests were chosen to match NET design specifications for normal operation and 'slow' peak energy deposition. The resulting damage and microstructural changes on the graphites and the brazes are discussed. Additional information is supplied on X-ray diffraction data proving the presence of different phases in the brazes. (author)

  6. Thermal conductance of interfaces with molecular layers - low temperature transient absorption study on gold nanorods supported on self assembled monolayers

    Science.gov (United States)

    Wang, Wei; Huang, Jingyu; Murphy, Catherine; Cahill, David; University of Illinois At Urbana Champaign, Department of Materials Science; Engineering Team; Department Collaboration

    2011-03-01

    While heat transfer via phonons across solid-solid boundary has been a core field in condense matter physics for many years, vibrational energy transport across molecular layers has been less well elucidated. We heat rectangular-shaped gold nanocrystals (nanorods) with Ti-sapphire femtosecond pulsed laser at their longitudinal surface plasmon absorption wavelength to watch how their temperature evolves in picoseconds transient. We observed single exponential decay behavior, which suggests that the heat dissipation is only governed by a single interfacial conductance value. The ``RC'' time constant was 300ps, corresponding to a conductance value of 95MW/ m 2 K. This interfacial conductance value is also a function of ambient temperature since at temperatures as low as 80K, which are below the Debye temperature of organic layers, several phonon modes were quenched, which shut down the dominating channels that conduct heat at room temperature.

  7. Frequency up-shift in the stimulated thermal scattering under two-photon absorption in liquids and colloids of metal nanoparticles

    Science.gov (United States)

    Smetanin, I. V.; Erokhin, A. I.; Baranov, A. N.

    2018-07-01

    We report the results of the experimental and theoretical study of stimulated temperature scattering in toluene and hexane solutions of Ag-nanoparticles, as well as in pure toluene in the two-photon absorption regime. A four-wave mixing scheme with two counter-propagating pump waves of the same frequency is utilised to demonstrate the lasing effect and the amplification of the backscattered anti-Stokes signal. For the first time, we have measured anti-Stokes spectral shifts which turn out to appreciably exceed the Rayleigh line widths in those liquids. It is shown that the amplification effect is provided predominantly by thermally induced coherent polarisation oscillations, while the dynamic interference temperature grating causes the formation of a self-induced optical cavity inside the interaction region.

  8. Effects of Thermal Radiation on Mixed Convection Flow of a Micropolar Fluid from an Unsteady Stretching Surface with Viscous Dissipation and Heat Generation/Absorption

    Directory of Open Access Journals (Sweden)

    Khilap Singh

    2016-01-01

    Full Text Available A numerical model is developed to examine the effects of thermal radiation on unsteady mixed convection flow of a viscous dissipating incompressible micropolar fluid adjacent to a heated vertical stretching surface in the presence of the buoyancy force and heat generation/absorption. The Rosseland approximation is used to describe the radiative heat flux in the energy equation. The model contains nonlinear coupled partial differential equations which have been converted into ordinary differential equation by using the similarity transformations. The dimensionless governing equations for this investigation are solved by Runge-Kutta-Fehlberg fourth fifth-order method with shooting technique. Numerical solutions are then obtained and investigated in detail for different interesting parameters such as the local skin-friction coefficient, wall couple stress, and Nusselt number as well as other parametric values such as the velocity, angular velocity, and temperature.

  9. Dual Solutions in a Boundary Layer Flow of a Power Law Fluid over a Moving Permeable Flat Plate with Thermal Radiation, Viscous Dissipation and Heat Generation/Absorption

    Directory of Open Access Journals (Sweden)

    Aftab Ahmed

    2018-01-01

    Full Text Available The aim of the present study is to investigate the combined effects of the thermal radiation, viscous dissipation, suction/injection and internal heat generation/absorption on the boundary layer flow of a non-Newtonian power law fluid over a semi infinite permeable flat plate moving in parallel or reversely to a free stream. The resulting system of partial differential equations (PDEs is first transformed into a system of coupled nonlinear ordinary differential equations (ODEs which are then solved numerically by using the shooting technique. It is found that the dual solutions exist when the flat plate and the free stream move in the opposite directions. Dimensionless boundary layer velocity and temperature distributions are plotted and discussed for various values of the emerging physical parameters. Finally, the tables of the relevant boundary derivatives are presented for some values of the governing physical parameters.

  10. A Novel Organic Rankine Cycle System with Improved Thermal Stability and Low Global Warming Fluids

    Directory of Open Access Journals (Sweden)

    Panesar Angad S

    2014-07-01

    Full Text Available This paper proposes a novel Organic Rankine Cycle (ORC system for long haul truck application. Rather than typical tail pipe heat recovery configurations, the proposed setup exploits the gaseous streams that are already a load on the engine cooling module. The system uses dual loops connected only by the Exhaust Gas Recirculation (EGR stream. A water blend study is conducted to identify suitable mixtures for the High Temperature (HT loop, while the Low Temperature (LT loop utilises a Low Global Warming (GWP Hydrofluoroether.

  11. The Annual Cycle of Water Vapor on Mars as Observed by the Thermal Emission Spectrometer

    Science.gov (United States)

    Smith, Michael D.; Vondrak, Richard R. (Technical Monitor)

    2001-01-01

    Spectra taken by the Mars Global Surveyor Thermal Emission Spectrometer (TES) have been used to monitor the latitude, longitude, and seasonal dependence of water vapor for over one full Martian year (March 1999-March 2001). A maximum in water vapor abundance is observed at high latitudes during mid-summer in both hemispheres, reaching a maximum value of approximately 100 pr-micrometer in the north and approximately 50 pr-micrometer in the south. Low water vapor abundance (water vapor. The latitudinal and seasonal dependence of the decay of the northern summer water vapor maximum implies cross-equatorial transport of water to the southern hemisphere, while there is little or no corresponding transport during the decay of the southern hemisphere summer maximum. The latitude-longitude dependence of annually-averaged water vapor (corrected for topography) has a significant positive correlation with albedo and significant negative correlations with thermal inertia and surface pressure. Comparison of TES results with those retrieved from the Viking Orbiter Mars Atmospheric Water Detectors (MAWD) experiments shows some similar features, but also many significant differences. The southern hemisphere maximum observed by TES was not observed by MAWD and the large latitudinal gradient in annually-averaged water vapor observed by MAWD does not appear in the TES results.

  12. Evaluation of the of thermal shock resistance of a castable containing andalusite aggregates by thermal shock cycles; Avaliacao da resistencia ao dano por choque termico por ciclagem de um concreto refratario contendo agregados de andaluzita

    Energy Technology Data Exchange (ETDEWEB)

    Garcia, G.C.R.; Santos, E.M.B.; Ribeiro, S., E-mail: girribeiro@yahoo.com.br [Universidade de Sao Paulo (DEMAR/EEL/USP), Lorena, SP (Brazil). Escola de Engenharia de. Departamento de Engenharia de Materiais; Resende, W.S. [Industrias Brasileiras de Artigos Refratarios (IBAR), Lorena, SP (Brazil); Rodrigues, J.A. [Universidade Federal de Sao Carlos (UFSCar), SP (Brazil)

    2011-07-01

    The thermal shock resistance of refractory materials is one of the most important characteristics that determine their performance in many applications, since abrupt and drastic differences in temperature can damage them. Resistance to thermal shock damage can be evaluated based on thermal cycles, i.e., successive heating and cooling cycles followed by an analysis of the drop in Young's modulus occurring in each cycle. The aim of this study was to evaluate the resistance to thermal shock damage in a commercial refractory concrete with andalusite aggregate. Concrete samples that were sintered at 1000 deg C and 1450 deg C for 5 hours to predict and were subjected to 30 thermal shock cycles, soaking in the furnace for 20 minutes at a temperature of 1000 deg C, and subsequent cooling in circulating water at 25 deg C. The results showed a decrease in Young's modulus and rupture around 72% for samples sintered at 1000 ° C, and 82% in sintered at 1450 ° C. The refractory sintered at 1450 deg C would show lower thermal shock resistance than the refractory sintered at 1000 deg C. (author)

  13. Use of thermal cycling to reduce adhesion of OTS coated coated MEMS cantilevers

    Science.gov (United States)

    Ali, Shaikh M.; Phinney, Leslie M.

    2003-01-01

    °Microelectromechanical systems (MEMS) have enormous potential to contribute in diverse fields such as automotive, health care, aerospace, consumer products, and biotechnology, but successful commercial applications of MEMS are still small in number. Reliability of MEMS is a major impediment to the commercialization of laboratory prototypes. Due to the multitude of MEMS applications and the numerous processing and packaging steps, MEMS are exposed to a variety of environmental conditions, making the prediction of operational reliability difficult. In this paper, we investigate the effects of operating temperature on the in-use adhesive failure of electrostatically actuated MEMS microcantilevers coated with octadecyltrichlorosilane (OTS) films. The cantilevers are subjected to repeated temperature cycles and electrostatically actuated at temperatures between 25°C and 300°C in ambient air. The experimental results indicate that temperature cycling of the OTS coated cantilevers in air reduces the sticking probability of the microcantilevers. The sticking probability of OTS coated cantilevers was highest during heating, which decreased during cooling, and was lowest during reheating. Modifications to the OTS release method to increase its yield are also discussed.

  14. Deposition Time and Thermal Cycles of Fabricating Thin-wall Steel Parts by Double Electrode GMAW Based Additive Manufacturing

    Directory of Open Access Journals (Sweden)

    Yang Dongqing

    2017-01-01

    Full Text Available The deposition time for fabricating the thin-wall part as well as the peak temperature of the substrate during the process was analyzed in the double electrode gas metal arc welding (DE-GMAW based additive manufacturing (AM. The total deposition time and the interlayer idle time of the manufacturing process decreased with the increasing of the bypass current under the same interlayer temperature and the same deposition rate. The thermal cycling curves illustrated that the peak temperature of the substrate was lower in the DE-GMAW base AM under the same conditions. When depositing the thin-wall parts, the DE-GMAW based AM can reduce the heat input to the substrate and improve the fabrication efficiency, compared with the GMAW based AM.

  15. Thermal-Economic Modularization of Small, Organic Rankine Cycle Power Plants for Mid-Enthalpy Geothermal Fields

    Directory of Open Access Journals (Sweden)

    Yodha Y. Nusiaputra

    2014-07-01

    Full Text Available The costs of the surface infrastructure in mid-enthalpy geothermal power systems, especially in remote areas, could be reduced by using small, modular Organic Rankine Cycle (ORC power plants. Thermal-economic criteria have been devised to standardize ORC plant dimensions for such applications. We designed a modular ORC to utilize various wellhead temperatures (120–170 °C, mass flow rates and ambient temperatures (−10–40 °C. A control strategy was developed using steady-state optimization, in order to maximize net power production at off-design conditions. Optimum component sizes were determined using specific investment cost (SIC minimization and mean cashflow (MCF maximization for three different climate scenarios. Minimizing SIC did not yield significant benefits, but MCF proved to be a much better optimization function.

  16. Long-period Intensity Pulsations in Coronal Loops Explained by Thermal Non-equilibrium Cycles

    Energy Technology Data Exchange (ETDEWEB)

    Froment, C.; Auchère, F.; Bocchialini, K.; Buchlin, E.; Solomon, J. [Institut d’Astrophysique Spatiale, CNRS, Univ. Paris-Sud, Université Paris-Saclay, Bât. 121, F-91405 Orsay cedex (France); Aulanier, G. [LESIA, Observatoire de Paris, PSL Research University, CNRS, Sorbonne Universités, UPMC Univ. Paris 06, Univ. Paris Diderot, Sorbonne Paris Cité, 5 place Jules Janssen, F-92195 Meudon (France); Mikić, Z., E-mail: clara.froment@astro.uio.no [Predictive Science, Inc., San Diego, CA 92121 (United States)

    2017-02-01

    In solar coronal loops, thermal non-equilibrium (TNE) is a phenomenon that can occur when the heating is both highly stratified and quasi-constant. Unambiguous observational identification of TNE would thus permit us to strongly constrain heating scenarios. While TNE is currently the standard interpretation of coronal rain, the long-term periodic evolution predicted by simulations has never been observed. However, the detection of long-period intensity pulsations (periods of several hours) has been recently reported with the Solar and Heliospheric Observatory /EIT, and this phenomenon appears to be very common in loops. Moreover, the three intensity-pulsation events that we recently studied with the Solar Dynamics Observatory /Atmospheric Imaging Assembly (AIA) show strong evidence for TNE in warm loops. In this paper, a realistic loop geometry from linear force-free field (LFFF) extrapolations is used as input to 1D hydrodynamic simulations. Our simulations show that, for the present loop geometry, the heating has to be asymmetrical to produce TNE. We analyze in detail one particular simulation that reproduces the average thermal behavior of one of the pulsating loop bundle observed with AIA. We compare the properties of this simulation with those deduced from the observations. The magnetic topology of the LFFF extrapolations points to the presence of sites of preferred reconnection at one footpoint, supporting the presence of asymmetric heating. In addition, we can reproduce the temporal large-scale intensity properties of the pulsating loops. This simulation further strengthens the interpretation of the observed pulsations as signatures of TNE. This consequently provides important information on the heating localization and timescale for these loops.

  17. Impacts of weld residual stresses and fatigue crack growth threshold on crack arrest under high-cycle thermal fluctuations

    International Nuclear Information System (INIS)

    Taheri, Said; Julan, Emricka; Tran, Xuan-Van; Robert, Nicolas

    2017-01-01

    Highlights: • For crack growth analysis, weld residual stress field must be considered through its SIF in presence of a crack. • Presence of cracks of same depth proves their arrest, where equal depth is because mean stress acts only on crack opening. • Not considering amplitudes under a fatigue crack growth threshold (FCGT) does not compensate the lack of FGCT in Paris law. • Propagation rates are close for axisymmetric and circumferential semi-elliptical cracks. - Abstract: High cycle thermal crazing has been observed in some residual heat removal (RHR) systems made of 304 stainless steel in PWR nuclear plants. This paper deals with two types of analyses including logical argumentation and simulation. Crack arrest in networks is demonstrated due to the presence of two cracks of the same depth in the network. This identical depth may be proved assuming that mean stress acts only on crack opening and that cracks are fully open during the load cycle before arrest. Weld residual stresses (WRS) are obtained by an axisymmetric simulation of welding on a tube with a chamfer. Axisymmetric and 3D parametric studies of crack growth on: representative sequences for variable amplitude thermal loading, fatigue crack growth threshold (FCGT), permanent mean stress, cyclic counting methods and WRS, are performed with Code-Aster software using XFEM methodology. The following results are obtained on crack depth versus time: the effect of WRS on crack growth cannot be determined by the initial WRS field in absence of crack, but by the associated stress intensity factor. Moreover the relation between crack arrest depth and WRS is analyzed. In the absence of FCGT Paris’s law may give a significant over-estimation of crack depth even if amplitudes of loading smaller than FCGT have not been considered. Appropriate depth versus time may be obtained using different values of FCGT, but axisymmetric simulations do not really show a possibility of arrest for shallow cracks in

  18. Impacts of weld residual stresses and fatigue crack growth threshold on crack arrest under high-cycle thermal fluctuations

    Energy Technology Data Exchange (ETDEWEB)

    Taheri, Said, E-mail: Said.taheri@edf.fr [EDF-LAB, IMSIA, 7 Boulevard Gaspard Monge, 91120 Palaiseau Cedex (France); Julan, Emricka [EDF-LAB, AMA, 7 Boulevard Gaspard Monge, 91120 Palaiseau Cedex (France); Tran, Xuan-Van [EDF Energy R& D UK Centre/School of Mechanical, Aerospace and Civil Engineering, The University of Manchester, Manchester M13 9PL (United Kingdom); Robert, Nicolas [EDF-DPN, UNIE, Strategic Center, Saint Denis (France)

    2017-01-15

    Highlights: • For crack growth analysis, weld residual stress field must be considered through its SIF in presence of a crack. • Presence of cracks of same depth proves their arrest, where equal depth is because mean stress acts only on crack opening. • Not considering amplitudes under a fatigue crack growth threshold (FCGT) does not compensate the lack of FGCT in Paris law. • Propagation rates are close for axisymmetric and circumferential semi-elliptical cracks. - Abstract: High cycle thermal crazing has been observed in some residual heat removal (RHR) systems made of 304 stainless steel in PWR nuclear plants. This paper deals with two types of analyses including logical argumentation and simulation. Crack arrest in networks is demonstrated due to the presence of two cracks of the same depth in the network. This identical depth may be proved assuming that mean stress acts only on crack opening and that cracks are fully open during the load cycle before arrest. Weld residual stresses (WRS) are obtained by an axisymmetric simulation of welding on a tube with a chamfer. Axisymmetric and 3D parametric studies of crack growth on: representative sequences for variable amplitude thermal loading, fatigue crack growth threshold (FCGT), permanent mean stress, cyclic counting methods and WRS, are performed with Code-Aster software using XFEM methodology. The following results are obtained on crack depth versus time: the effect of WRS on crack growth cannot be determined by the initial WRS field in absence of crack, but by the associated stress intensity factor. Moreover the relation between crack arrest depth and WRS is analyzed. In the absence of FCGT Paris’s law may give a significant over-estimation of crack depth even if amplitudes of loading smaller than FCGT have not been considered. Appropriate depth versus time may be obtained using different values of FCGT, but axisymmetric simulations do not really show a possibility of arrest for shallow cracks in

  19. Middle atmospheric thermal structures in Eastern and Western hemispheres over a solar cycle

    International Nuclear Information System (INIS)

    Mohanakumar, K.; Devanarayanan, S.

    1987-01-01

    Temperature variations of the 25-60 km region of the atmosphere over stations in the Eastern and Western Hemispheres were compared for an 11-year solar cycle period (1971-1981). The temperature of the two hemispheres did not show similar variations at the same height and time. A cross-correlation analysis between the variations in temperature of the two hemispheres showed insignificant correlation, except at 30 km over the tropics and at 40 km over the midlatitude. Up to 40 km, the temperature changes in the two hemispheres are identical. At higher levels, Western Hemispheric temperatures were higher than those of the Eastern Hemisphere. The diurnal variation of minor constituents and their vertical transport in the middle atmosphere might be responsible for the differences in temperature observed in the two hemispheres. (author)

  20. Low Temperature Creep of Hot-Extruded Near-Stoichiometric NiTi Shape Memory Alloy. Part 2; Effect of Thermal Cycling

    Science.gov (United States)

    Raj, S. V.; Noebe, R. D.

    2013-01-01

    This paper is the first report on the effect prior low temperature creep on the thermal cycling behavior of NiTi. The isothermal low temperature creep behavior of near-stoichiometric NiTi between 300 and 473 K was discussed in Part I. The effect of temperature cycling on its creep behavior is reported in the present paper (Part II). Temperature cycling tests were conducted between either 300 or 373 K and 473 K under a constant applied stress of either 250 or 350 MPa with hold times lasting at each temperature varying between 300 and 700 h. Each specimen was pre-crept either at 300 or at 473 K for several months under an identical applied stress as that used in the subsequent thermal cycling tests. Irrespective of the initial pre-crept microstructures, the specimens exhibited a considerable increase in strain with each thermal cycle so that the total strain continued to build-up to 15 to 20 percent after only 5 cycles. Creep strains were immeasurably small during the hold periods. It is demonstrated that the strains in the austenite and martensite are linearly correlated. Interestingly, the differential irrecoverable strain, in the material measured in either phase decreases with increasing number of cycles, similar to the well-known Manson-Coffin relation in low cycle fatigue. Both phases are shown to undergo strain hardening due to the development of residual stresses. Plots of true creep rate against absolute temperature showed distinct peaks and valleys during the cool-down and heat-up portions of the thermal cycles, respectively. Transformation temperatures determined from the creep data revealed that the austenitic start and finish temperatures were more sensitive to the pre-crept martensitic phase than to the pre-crept austenitic phase. The results are discussed in terms of a phenomenological model, where it is suggested that thermal cycling between the austenitic and martensitic phase temperatures or vice versa results in the deformation of the austenite and

  1. The Effects of CaCO3 Coated Wood Free Paper Usage as Filler on Water Absorption, Mechanical and Thermal Properties of Cellulose-High Density Polyethylene Composites

    Directory of Open Access Journals (Sweden)

    Emrah PEŞMAN

    2016-11-01

    Full Text Available In this study some physical, mechanical and thermal characteristics of high density polyethylene (HDPE and CaCO3 coated/pigmented wood free paper fiber composites were investigated. The fillers used in this study were uncoated cellulose, 5.8 %, 11.5 %, 16.5 % and 23.1 % CaCO3 coated wood free paper fibers. Each filler type was mixed with HDPE at 40% by weight fiber loading. In this case, the ratio of CaCO3 in plastic composites were calculated as 0 %, 2.3 %, 4.6 %, 6.6 % and 9.2 % respectively. Increased CaCO3 ratio improved the moisture resistant, flexural and tensile strength of cellulose-HDPE composites. However, the density of the cellulose-HDPE composites increased with CaCO3 addition. Energy Dispersive Spectroscopy on Scanning Electron Microscope analysis demonstrated the uniform distribution of CaCO3 and cellulose fiber in plastic matrix. In addition, the thermal properties of fiber plastic composites were investigated. The results of Differential scanning calorimetry analysis revealed that the crystallinity of the samples decreased with increasing CaCO3 content. Consequently, this work showed that CaCO3 coated waste paper fibers could be used as reinforcing filler against water absorption in thermoplastic matrix.DOI: http://dx.doi.org/10.5755/j01.ms.22.4.14222

  2. Computer code system for the R and D of nuclear fuel cycle with fast reactor. 2. Development and application of analytical evaluation system for thermal striping phenomena

    International Nuclear Information System (INIS)

    Muramatsu, Toshiharu

    2001-01-01

    Fluid-structure thermal interaction phenomena characterized by stationary random temperature fluctuations, namely thermal striping are observed in the downstream region such as a T-junction piping system of liquid metal fast reactors (LMFRs). Therefore, the piping wall located in the downstream region must be protected against the stationary random thermal process, which might induce high-cycle fatigue. This paper describes the evaluation system based on numerical simulation methods consisting of three thermohydraulics computer programs AQUA, DINUS-3 and THEMIS and of three thermomechanical computer programs BEMSET, FINAS and CANIS, for the thermal striping developed at Japan Nuclear Cycle Development Institute (JNC). Verification results for each computer code and the system are also introduced based on out-of-pile experimental data using water and sodium as working fluids. (author)

  3. Assessment of cumulative damage by using ultrasonic C-scan on carbon fiber/epoxy composites under thermal cycling

    Directory of Open Access Journals (Sweden)

    Marcos Yutaka Shiino

    2012-08-01

    Full Text Available In recent years, structural composites manufactured by carbon fiber/epoxy laminates have been employed in large scale in aircraft industries. These structures require high strength under severe temperature changes of -56° until 80 °C. Regarding this scenario, the aim of this research was to reproduce thermal stress in the laminate plate developed by temperature changes and tracking possible cumulative damages on the laminate using ultrasonic C-scan inspection. The evaluation was based on attenuation signals and the C-scan map of the composite plate. The carbon fiber/epoxy plain weave laminate underwent temperatures of -60° to 80 °C, kept during 10 minutes and repeated for 1000, 2000, 3000 and 4000 times. After 1000 cycles, the specimens were inspected by C-scanning. A few changes in the laminate were observed using the inspection methodology only in specimens cycled 3000 times, or so. According to the found results, the used temperature range did not present enough conditions to cumulative damage in this type of laminate, which is in agreement with the macro - and micromechanical theory.

  4. Thermal Capacitive Electrochemical Cycle on Carbon-Based Supercapacitor for Converting Low-grade Heat to Electricity

    Directory of Open Access Journals (Sweden)

    Xun Wang

    2017-11-01

    Full Text Available It is a great challenge to efficiently convert low-grade heat (<100°C to electricity. Currently available heat-to-current converters, such as thermoelectric generators, operating in a low-grade heat regime reach efficiencies no higher than a few percent (<3%. Herein, we illustrated a thermal capacitive electrochemical cycle (TCEC using electrochemical cell, where the connection to the hot or cold reservoirs alternates in a cyclic charging–heating–discharging–cooling mode to convert heat into electricity, which performs as an electrochemical heat engine. TCEC technology is a cost-effective method for exploiting the temperature-dependent electrostatic potential in an electric double layer (EDL at carbon electrode/electrolyte interfaces; it produces net electricity by altering the EDL thickness via heating and cooling. In this paper, TCEC on supercapacitor was confirmed on commercial supercapacitor, which showed a poor conversion efficiency. To improve the performance, we redesigned the cell by employing the pouch cell setup with activated carbon as electrode materials and homemade temperature controlling system, which boosted the efficiency from 0.5% of commercial supercapacitor to 3.05% when cycling between 10 and 65°C. A higher efficiency of 3.95% could be reached by using microwaved exfoliated graphene nanosheets (MEG and nitric acid-treated MEG, which could help in decreasing the energy loss caused by charge leakage.

  5. Thermal tests of a multi-tubular reactor for hydrogen production by using mixed ferrites thermochemical cycle

    Science.gov (United States)

    Gonzalez-Pardo, Aurelio; Denk, Thorsten; Vidal, Alfonso

    2017-06-01

    The SolH2 project is an INNPACTO initiative of the Spanish Ministry of Economy and Competitiveness, with the main goal to demonstrate the technological feasibility of solar thermochemical water splitting cycles as one of the most promising options to produce H2 from renewable sources in an emission-free way. A multi-tubular solar reactor was designed and build to evaluate a ferrite thermochemical cycle. At the end of this project, the ownership of this plant was transferred to CIEMAT. This paper reviews some additional tests with this pilot plant performed in the Plataforma Solar de Almería with the main goal to assess the thermal behavior of the reactor, evaluating the evolution of the temperatures inside the cavity and the relation between supplied power and reached temperatures. Previous experience with alumina tubes showed that they are very sensitive to temperature and flux gradients, what leads to elaborate an aiming strategy for the heliostat field to achieve a uniform distribution of the radiation inside the cavity. Additionally, the passing of clouds is a phenomenon that importantly affects all the CSP facilities by reducing their efficiency. The behavior of the reactor under these conditions has been studied.

  6. Integrated solar thermal Brayton cycles with either one or two regenerative heat exchangers for maximum power output

    International Nuclear Information System (INIS)

    Jansen, E.; Bello-Ochende, T.; Meyer, J.P.

    2015-01-01

    The main objective of this paper is to optimise the open-air solar-thermal Brayton cycle by considering the implementation of the second law of thermodynamics and how it relates to the design of the heat exchanging components within it. These components included one or more regenerators (in the form of cross-flow heat exchangers) and the receiver of a parabolic dish concentrator where the system heat was absorbed. The generation of entropy was considered as it was associated with the destruction of exergy or available work. The dimensions of some components were used to optimise the cycles under investigation. EGM (Entropy Generation Minimisation) was employed to optimise the system parameters by considering their influence on the total generation of entropy (destruction of exergy). Various assumptions and constraints were considered and discussed. The total entropy generation rate and irreversibilities were determined by considering the individual components and ducts of the system, as well as their respective inlet and outlet conditions. The major system parameters were evaluated as functions of the mass flow rate to allow for a proper discussion of the system performance. The performances of both systems were investigated, and characteristics were listed for both. Finally, a comparison is made to shed light on the differences in performance. - Highlights: • Implementation of the second law of thermodynamics. • Design of heat exchanging and collecting equipment. • Utilisation of Entropy Generation Minimization. • Presentation of a multi-objective optimization. • Raise efficiency with more regeneration

  7. Model of the Evolution of Deformation Defects and Irreversible Strain at Thermal Cycling of Stressed TiNi Alloy Specimen

    Directory of Open Access Journals (Sweden)

    Volkov Aleksandr E.

    2015-01-01

    Full Text Available This microstructural model deals with simulation both of the reversible and irreversible deformation of a shape memory alloy (SMA. The martensitic transformation and the irreversible deformation due to the plastic accommodation of martensite are considered on the microscopic level. The irreversible deformation is described from the standpoint of the plastic flow theory. Isotropic hardening and kinematic hardening are taken into account and are related to the densities of scattered and oriented deformation defects. It is supposed that the phase transformation and the micro plastic deformation are caused by the generalized thermodynamic forces, which are the derivatives of the Gibbs’ potential of the two-phase body. In terms of these forces conditions for the phase transformation and for the micro plastic deformation on the micro level are formulated. The macro deformation of the representative volume of the polycrystal is calculated by averaging of the micro strains related to the evolution of the martensite Bain’s variants in each grain comprising this volume. The proposed model allowed simulating the evolution of the reversible and of the irreversible strains of a stressed SMA specimen under thermal cycles. The results show a good qualitative agreement with available experimental data. Specifically, it is shown that the model can describe a rather big irreversible strain in the first thermocycle and its fast decrease with the number of cycles.

  8. Effects of the plastic deformation and thermal cycles on the mechanical properties of fully recrystallized Zircaloy-4

    International Nuclear Information System (INIS)

    Litvack, Nicolas

    2005-01-01

    The development of crystallographic texture in a product depends, for a given material, of its fabrication history. In our case, the evolution of that texture results from a combination of cold working and thermal cycles applied together or separately. In the present work, cold working levels ranging from 50 % to approximately 90 % and different heat treatment cycles has been applied to Zircaloy-4 sheets and tubes. Using X-ray diffraction techniques and the direct pole figure method, the evolution of crystallographic texture has been analyzed for each fabrication route. We observed that cold working levels up to 90 % without intermediate annealing heat treatment do not change significantly the classic angle between basal pole and the normal/radial direction of the product (φ ≅ ± 25 degrees). Furthermore, the application of intermediate cold working levels (50 % - 60 %) and more than two intermediate annealing heat treatments exhibits a marked modification of the basal pole orientation. The basal poles appear now parallel to the normal direction (φ ≅ 0 degrees) of the product. Additionally, the crystallographic texture change observed with X-ray procedures was evaluated by the measure of anisotropic parameters R and P. The results here obtained will be use in the future as a basis for the design of a fabrication route capable to obtain in a HPTR process, seamless calandria tubes strengthened by crystallographic texture. (author) [es

  9. Does thermal variability experienced at the egg stage influence life history traits across life cycle stages in a small invertebrate?

    Directory of Open Access Journals (Sweden)

    Kun Xing

    Full Text Available Although effects of thermal stability on eggs have often been considered in vertebrates, there is little data thermal stability in insect eggs even though these eggs are often exposed in nature to widely fluctuating ambient conditions. The modularity of development in invertebrates might lead to compensation across life cycle stages but this remains to be tested particularly within the context of realistic temperature fluctuations encountered in nature. We simulated natural temperate fluctuations on eggs of the worldwide cruciferous insect pest, the diamondback moth (DBM, Plutella xylostella (L., while maintaining the same mean temperature (25°C±0°C, 25±4°C, 25±6°C, 25±8°C, 25±10°C, 25±12°C and assessed egg development, survival and life history traits across developmental stages. Moderate fluctuations (25±4°C, 25±6°C did not influence performance compared to the constant temperature treatment, and none of the treatments influenced egg survival. However the wide fluctuating temperatures (25±10°C, 25±12°C slowed development time and led to an increase in pre-pupal mass, although these changes did not translate into any effects on longevity or fecundity at the adult stage. These findings indicate that environmental effects can extend across developmental stages despite the modularity of moth development but also highlight that there are few fitness consequences of the most variable thermal conditions likely to be experienced by Plutella xylostella.

  10. Impact of Total Ionizing Dose Radiation Testing and Long-Term Thermal Cycling on the Operation of CMF20120D Silicon Carbide Power MOSFET

    Science.gov (United States)

    Patterson, Richard L.; Scheidegger, Robert J.; Lauenstein, Jean-Marie; Casey, Megan; Scheick, Leif; Hammoud, Ahmad

    2013-01-01

    Power systems designed for use in NASA space missions are required to work reliably under harsh conditions including radiation, thermal cycling, and extreme temperature exposures. Silicon carbide devices show great promise for use in future power electronics systems, but information pertaining to performance of the devices in the space environment is very scarce. A silicon carbide N-channel enhancement-mode power MOSFET called the CMF20120 is of interest for use in space environments. Samples of the device were exposed to radiation followed by long-term thermal cycling to address their reliability for use in space applications. The results of the experimental work are presentd and discussed.

  11. Four-wall turbine airfoil with thermal strain control for reduced cycle fatigue

    Science.gov (United States)

    Cambell, Christian X

    2013-09-17

    A turbine airfoil (20B) with a thermal expansion control mechanism that increases the airfoil camber (60, 61) under operational heating. The airfoil has four-wall geometry, including pressure side outer and inner walls (26, 28B), and suction side outer and inner walls (32, 34B). It has near-wall cooling channels (31F, 31A, 33F, 33A) between the outer and inner walls. A cooling fluid flow pattern (50C, 50W, 50H) in the airfoil causes the pressure side inner wall (28B) to increase in curvature under operational heating. The pressure side inner wall (28B) is thicker than walls (26, 34B) that oppose it in camber deformation, so it dominates them in collaboration with the suction side outer wall (32), and the airfoil camber increases. This reduces and relocates a maximum stress area (47) from the suction side outer wall (32) to the suction side inner wall (34B, 72) and the pressure side outer wall (26).

  12. The determination of resistance of marble to thermal and moisture cycles: relevance and limits of the recent European natural stone standard

    Science.gov (United States)

    Bellopede, Rossana; Castelletto, Eleonora; Marini, Paola; Zichella, Lorena

    2015-04-01

    The recent European standard EN 16306:2013 specifies laboratory methodology on the determination of the resistance to thermal and moisture cycling of marble for cladding of building façades. In particular measurements of bowing and flexural strength should be performed before and at the end of the ageing cycles. Bowing is measured on specimens of dimension 30*100*400mm exposed to moisture from beneath and heating (gradually till 80°C) on the upper face. The flexural strength should be measured both on reference and on exposed specimens in order to assess the variation of mechanical properties. Additional non-destructive tests are foreseen but are not compulsory for the standard. Moreover, the Annex A of the EN 16306, contains a guidance of the limit values that could be useful for the building planner for façade panels dimensioning. Different varieties of marble (two from Italy, one from Greece and three from Portugal) have been tested by means of this laboratory ageing test. Non-destructive tests such as the measurements of Ultrasonic Pulse Velocity (UPV), porosity, and water absorption have been executed together with the conventional flexural strength test. Image analysis on thin sections soaked with methylene blue have been analysed to further investigate the correlation between porosity and tendency to bowing. Base on the results obtained, some consideration on the decrease of mechanical resistance and the bowing in relation to the variety of marble tested and the limit values indicated the Annex A of EN 16306 can be drawn. Besides, from the data analysed a deepened discussion has been made. It is known that bowing and rapid strength loss occur in some varieties of marble when used as exterior cladding but further considerations can be made: bowing and flexural strength are correlate and in which way? Often the bowing is related to the decrease of flexural strength but it happens that there is a decrease in the mechanical resistance of the stone also

  13. Thermal and microstructural modelling in weld heat-affected zones. Part I: thermal cycles; Modelizacion termica y microestructural de la zona afectada por el calor en la soldadura. Parte I: ciclos termicos

    Energy Technology Data Exchange (ETDEWEB)

    Ribera, J.M.; Prado, J.M. [Departamento de Ciencia de los Materiales e Ingenieria Metalurgica Universidad Politecnica de Cataluna, Barcelona (Spain)

    1995-12-31

    After a review about theoretical concepts involved in heat transfer, the ``double ellipsoid`` model is proposed which will be useful to simulate the welding heat input accurately. The different steps to perform an analysis using the Finite Elements Method (FEM) are described in order to compute the transient temperature field for any point of interest, and the transfer equations are solved numerically for several welding situations. The thermal cycles are obtained and so it will be possible to understand the metallurgical behavior that takes place in weld heat affected zones. In addition the effects of different welding parameters on the shape of the computed thermal cycles are shown. (Author) 5 refs.

  14. Modeling of the vapor cycle of Laguna Verde with the PEPSE code to conditions of thermal power licensed at present (2027 MWt)

    International Nuclear Information System (INIS)

    Castaneda G, M. A.; Maya G, F.; Medel C, J. E.; Cardenas J, J. B.; Cruz B, H. J.; Mercado V, J. J.

    2011-11-01

    By means of the use of the performance evaluation of power system efficiencies (PEPSE) code was modeled the vapor cycle of the nuclear power station of Laguna Verde to reproduce the nuclear plant behavior to conditions of thermal power, licensed at present (2027 MWt); with the purpose of having a base line before the implementation of the project of extended power increase. The model of the gauged vapor cycle to reproduce the nuclear plant conditions makes use of the PEPSE model, design case of the vapor cycle of nuclear power station of Laguna Verde, which has as main components of the model the great equipment of the vapor cycle of Laguna Verde. The design case model makes use of information about the design requirements of each equipment for theoretically calculating the electric power of exit, besides thermodynamic conditions of the vapor cycle in different points. Starting from the design model and making use of data of the vapor cycle measured in the nuclear plant; the adjustment factors were calculated for the different equipment s of the vapor cycle, to reproduce with the PEPSE model the real vapor cycle of Laguna Verde. Once characterized the model of the vapor cycle of Laguna Verde, we can realize different sensibility studies to determine the effects macros to the vapor cycle by the variation of certain key parameters. (Author)

  15. Thermal cycling reliability of Cu/SnAg double-bump flip chip assemblies for 100 μm pitch applications

    Science.gov (United States)

    Son, Ho-Young; Kim, Ilho; Lee, Soon-Bok; Jung, Gi-Jo; Park, Byung-Jin; Paik, Kyung-Wook

    2009-01-01

    A thick Cu column based double-bump flip chip structure is one of the promising alternatives for fine pitch flip chip applications. In this study, the thermal cycling (T/C) reliability of Cu/SnAg double-bump flip chip assemblies was investigated, and the failure mechanism was analyzed through the correlation of T/C test and the finite element analysis (FEA) results. After 1000 thermal cycles, T/C failures occurred at some Cu/SnAg bumps located at the edge and corner of chips. Scanning acoustic microscope analysis and scanning electron microscope observations indicated that the failure site was the Cu column/Si chip interface. It was identified by a FEA where the maximum stress concentration was located during T/C. During T/C, the Al pad between the Si chip and a Cu column bump was displaced due to thermomechanical stress. Based on the low cycle fatigue model, the accumulation of equivalent plastic strain resulted in thermal fatigue deformation of the Cu column bumps and ultimately reduced the thermal cycling lifetime. The maximum equivalent plastic strains of some bumps at the chip edge increased with an increased number of thermal cycles. However, equivalent plastic strains of the inner bumps did not increase regardless of the number of thermal cycles. In addition, the z-directional normal plastic strain ɛ22 was determined to be compressive and was a dominant component causing the plastic deformation of Cu/SnAg double bumps. As the number of thermal cycles increased, normal plastic strains in the perpendicular direction to the Si chip and shear strains were accumulated on the Cu column bumps at the chip edge at low temperature region. Thus it was found that the Al pad at the Si chip/Cu column interface underwent thermal fatigue deformation by compressive normal strain and the contact loss by displacement failure of the Al pad, the main T/C failure mode of the Cu/SnAg flip chip assembly, then occurred at the Si chip/Cu column interface shear strain deformation

  16. Technical feasibility of the electrode ionization process for the makeup water treatment system of the thermal cycle of the CAREM-25 nuclear power plant

    International Nuclear Information System (INIS)

    Ramilo, Lucia B.; Chocron, Mauricio

    2003-01-01

    In thermal cycles of PWRs nuclear power plants with once-through steam generators as the CAREM-25, makeup water of very high purity is required to minimizing the induction of corrosion phenomena, fundamentally in the steam generators and other thermal cycle components. The makeup water treatment systems include several stages, of which the demineralization is the purification stage. The required makeup water purity is obtained in this stage. Historically, ultrapure water systems were based completely on ion exchange technology. Now, the electrode ionization process (EDI) has replaced the ion exchange technology used traditionally in the demineralization stage. Continuous demineralization in an EDI stack consists of three coupled processes: ion exchange, continuous ion removal by transport through the ion exchange resin and membranes into the concentrate stream, continuous regeneration by hydrogen and hydroxyl ions derived from the water splitting reaction and driven by the applied direct current. EDI process allows to obtain ultrapure water, with practically no use of chemical reagents and with technologies of continuous process. The objective of this work is the analysis of the electrode ionization process (EDI) for its implementation in the makeup water treatment system of the thermal cycle of the CAREM-25 nuclear power plant. The obtained results allow to assure the technical feasibility of implementation of the electrode ionization process, EDI, in the makeup water treatment system of the thermal cycle of this Argentinean nuclear power plant. (author)

  17. Effects of High Temperature and Thermal Cycling on the Performance of Perovskite Solar Cells: Acceleration of Charge Recombination and Deterioration of Charge Extraction

    KAUST Repository

    Sheikh, Arif D.; Munir, Rahim; Haque, Mohammed; Bera, Ashok; Hu, Weijin; Shaikh, Parvez Abdul Ajij; Amassian, Aram; Wu, Tao

    2017-01-01

    In this work, we investigated the effects of high operating temperature and thermal cycling on the photovoltaic performance of perovskite solar cells (PSCs) with a typical mesostructured (m)-TiO2-CH3NH3PbI3-xClx-spiro-OMeTAD architecture. After

  18. Recent developments in thermally-driven seawater desalination: Energy efficiency improvement by hybridization of the MED and AD cycles

    KAUST Repository

    Ng, Kim Choon; Thu, Kyaw; Oh, Seungjin; Ang, Li; Shahzad, Muhammad Wakil; Ismail, Azhar Bin

    2015-01-01

    -driven to adsorption desalination (AD) cycles where significant thermodynamic synergy can be attained when cycles are combined. For these hybrid cycles, a quantum improvement in energy efficiency as well as in increase in water production can be expected. The advent

  19. Energetic and financial investigation of a stand-alone solar-thermal Organic Rankine Cycle power plant

    International Nuclear Information System (INIS)

    Tzivanidis, Christos; Bellos, Evangelos; Antonopoulos, Kimon A.

    2016-01-01

    Highlights: • A stand-alone solar driven Organic Rankine Cycle is optimized parametrically. • The system is optimized energetically and financially. • Nine working fluids are tested with cyclohexane to be the most suitable. • A collecting area of 25,000 m"2 parabolic trough collectors is the optimum solution. • The maximum IRR is 13.46% and the payback period is about 9 years. - Abstract: The use of solar thermal energy for electricity production is a clean and sustainable way to cover the increasing energy needs of our society. The most mature technology for capturing solar energy in high temperature levels is the parabolic trough collectors (PTC). In this study, an Organic Rankine Cycle (ORC) coupled with PTC is analyzed parametrically in order to be optimized financially and energetically. The first step is the thermodynamic investigation of the ORC by using various working fluids. The second step is the energetic and financial investigation of the total system which includes the solar field, the storage tank and the ORC module. By testing many combinations of collecting areas and storage tank volumes, finally cyclohexane proved to be the most suitable working fluid for producing 1 MW_e_l with PTC. Specifically, in the optimum situation a solar field of 25,000 m"2 with storage tank of about 300 m"3 leads to a payback period of 9 years and to an internal rate of return (IRR) equal to 13.46%. Moreover, an economic comparison for different commercial collectors is presented, with Eurotrough ET-150 being the financially optimum solution for this case study.

  20. Thaumarchaeal ammonium oxidation and evidence for a nitrogen cycle in a subsurface radioactive thermal spring in the Austrian Central Alps

    Directory of Open Access Journals (Sweden)

    Friedrich Wolfgang Gerbl

    2014-05-01

    Full Text Available Previous studies had suggested the presence of ammonium oxidizing Thaumarchaeota as well as nitrite oxidizing Bacteria in the subsurface spring called Franz Josef Quelle (FJQ, a slightly radioactive thermal mineral spring with a temperature of 43.6 - 47oC near the alpine village of Bad Gastein, Austria. The microbiological consortium of the FJQ was investigated for its utilization of nitrogen compounds and the putative presence of a subsurface nitrogen cycle. Microcosm experiments made with samples from the spring water, containing planktonic microorganisms, or from biofilms, were used in this study. Three slightly different media, enriched with vitamins and trace elements, and two incubation temperatures (30 and 40oC, respectively were employed. Under aerobic conditions, high rates of conversion of ammonium to nitrite, as well as nitrite to nitrate were measured. Under oxygen-limited conditions nitrate was converted to gaseous compounds. Stable isotope probing with 15NH4Cl or (15NH42SO4 as sole energy sources revealed incorporation of 15N into community DNA. Genomic DNA as well as RNA were extracted from all microcosms. The following genes or fragments of genes were successfully amplified, cloned and sequenced by standard PCR from DNA extracts: Ammonia monooxygenase subunit A (amoA, nitrite oxidoreductase subunits A and B (nxrA and nxrB, nitrate reductase (narG, nitrite reductase (nirS, nitric oxide reductases (cnorB and qnorB, nitrous oxide reductase (nosZ. Reverse transcription of extracted total RNA and real-time PCR suggested the expression of each of those genes. Nitrogen fixation (as probed with nifH and nifD was not detected. However, a geological origin of NH4+ in the water of the FJQ cannot be excluded, considering the silicate, granite and gneiss containing environment. The data suggested the operation of a nitrogen cycle in the subsurface environment of the FJQ.

  1. Thaumarchaeal ammonium oxidation and evidence for a nitrogen cycle in a subsurface radioactive thermal spring in the Austrian Central Alps.

    Science.gov (United States)

    Gerbl, Friedrich W; Weidler, Gerhard W; Wanek, Wolfgang; Erhardt, Angelika; Stan-Lotter, Helga

    2014-01-01

    Previous studies had suggested the presence of ammonium oxidizing Thaumarchaeota as well as nitrite oxidizing Bacteria in the subsurface spring called Franz Josef Quelle (FJQ), a slightly radioactive thermal mineral spring with a temperature of 43.6-47°C near the alpine village of Bad Gastein, Austria. The microbiological consortium of the FJQ was investigated for its utilization of nitrogen compounds and the putative presence of a subsurface nitrogen cycle. Microcosm experiments made with samples from the spring water, containing planktonic microorganisms, or from biofilms, were used in this study. Three slightly different media, enriched with vitamins and trace elements, and two incubation temperatures (30 and 40°C, respectively) were employed. Under aerobic conditions, high rates of conversion of ammonium to nitrite, as well as nitrite to nitrate were measured. Under oxygen-limited conditions nitrate was converted to gaseous compounds. Stable isotope probing with (15)NH4Cl or ((15)NH4)2SO4as sole energy sources revealed incorporation of (15)N into community DNA. Genomic DNA as well as RNA were extracted from all microcosms. The following genes or fragments of genes were successfully amplified, cloned and sequenced by standard PCR from DNA extracts: Ammonia monooxygenase subunit A (amoA), nitrite oxidoreductase subunits A and B (nxrA and nxrB), nitrate reductase (narG), nitrite reductase (nirS), nitric oxide reductases (cnorB and qnorB), nitrous oxide reductase (nosZ). Reverse transcription of extracted total RNA and real-time PCR suggested the expression of each of those genes. Nitrogen fixation (as probed with nifH and nifD) was not detected. However, a geological origin of NH(+) 4 in the water of the FJQ cannot be excluded, considering the silicate, granite and gneiss containing environment. The data suggested the operation of a nitrogen cycle in the subsurface environment of the FJQ.

  2. Finite time thermodynamics of power and refrigeration cycles

    CERN Document Server

    Kaushik, Shubhash C; Kumar, Pramod

    2017-01-01

    This book addresses the concept and applications of Finite Time Thermodynamics to various thermal energy conversion systems including heat engines, heat pumps, and refrigeration and air-conditioning systems. The book is the first of its kind, presenting detailed analytical formulations for the design and optimisation of various power producing and cooling cycles including but not limited to: • Vapour power cycles • Gas power cycles • Vapour compression cycles • Vapour absorption cycles • Rankine cycle coupled refrigeration systems Further, the book addresses the thermoeconomic analysis for the optimisation of thermal cycles, an important field of study in the present age and which is characterised by multi-objective optimization regarding energy, ecology, the environment and economics. Lastly, the book provides the readers with key techniques associated with Finite Time Thermodynamics, allowing them to understand the relevance of irreversibilitie s associated with real processes and the scientific r...

  3. Results of scoping tests for open-cycle OTEC (ocean thermal energy conversion) components operating with seawater

    Energy Technology Data Exchange (ETDEWEB)

    Zangrando, F; Bharathan, D; Green, H J; Link, H F; Parsons, B K; Parsons, J M; Pesaran, A A [Solar Energy Research Inst., Golden, CO (USA); Panchal, C B [Argonne National Lab., IL (USA)

    1990-09-01

    This report presents comprehensive documentation of the experimental research conducted on open-cycle ocean thermal energy conversion (OC-OTEC) components operating with seawater as a working fluid. The results of this research are presented in the context of previous analysis and fresh-water testing; they provide a basis for understanding and predicting with confidence the performance of all components of an OC-OTEC system except the turbine. Seawater tests have confirmed the results that were obtained in fresh-water tests and predicted by the analytical models of the components. A sound technical basis has been established for the design of larger systems in which net power will be produced for the first time from OC-OTEC technology. Design and operation of a complete OC-OTEC system that produces power will provide sufficient confidence to warrant complete transfer of OC-OTEC technology to the private sector. Each components performance is described in a separate chapter written by the principal investigator responsible for technical aspects of the specific tests. Chapters have been indexed separately for inclusion on the data base.

  4. Surface phenomena associated with thermal cycling of copper and their impact on the service life of particle accelerator structures

    CERN Document Server

    Aicheler, Markus; Theisen, Werner; Sgobba, Stefano

    2010-01-01

    The performance of accelerating structures (AS) in the Compact LInear Collider (CLIC) is sensitive to a variety of parameters, including the surface quality of key elements of the AS. Processes which affect the surface quality are therefore of particular concern. The present work addresses surface modifications associated with thermal cycling during operation. This type of operating condition represents a specific type of fatigue loading. Four fatigue test procedures were used in the present study in order to investigate the fatigue behaviour of oxygen{free{electronic (OFE) copper, the candidate material of the CLIC-AS: conventional fatigue (CVF), ultrasonic swinger (USS), laser fatigue (LAF) and radio{frequency fatigue (RFF). During operation of the accelerator the material of the AS will be subjected to cyclic temperature changes of approx. Delta T = 56 K, from about 40° C to about 100° C. These temperature changes will result in cyclic biaxial strains in the surface of the order of epsilon(biax) = 9.2 x ...

  5. Effects of thermal cycle annealing on reduction of defect density in lattice-mismatched InGaAs solar cells

    International Nuclear Information System (INIS)

    Sasaki, T.; Arafune, K.; Lee, H.S.; Ekins-Daukes, N.J.; Tanaka, S.; Ohshita, Y.; Yamaguchi, M.

    2006-01-01

    Lattice-mismatched In 0.16 Ga 0.84 As solar cells were grown on GaAs substrates using graded In x Ga 1- x As buffer layers and homogenous In 0.16 Ga 0.84 As buffer layers. The indium composition x in the graded buffer changed from 0% to 16% continuously. Thermal cycle annealing (TCA) was performed after the growth of the graded buffer layers. The effects of TCA on the solar cell open-circuit voltage and quantum efficiency have been investigated. The minority carrier lifetime is observed to increase in the p-type In 0.16 Ga 0.84 As layer after applying the TCA process. Electron-beam-induced current microscopy also shows a related reduction in dislocation density in the p-type In 0.16 Ga 0.84 As layer after TCA processing. Cross-sectional transmission electron microscopy performed on the graded buffer layer suggests that the strain present in the cell layers is reduced after the TCA process, implying that the TCA treatment promotes strain relaxation in the graded buffer layers

  6. A Technique for Mitigating Thermal Stress and Extending Life Cycle of Power Electronic Converters Used for Wind Turbines

    Directory of Open Access Journals (Sweden)

    Canras Batunlu

    2015-11-01

    Full Text Available Over the last two decades, various models have been developed to assess and improve the reliability of power electronic conversion systems (PECs with a focus on those used for wind turbines. However, only few studies have dealt with mitigating the PECs thermo-mechanical effects on their reliability taking into account variations in wind characteristics. This work critically investigates this issue and attempts to offer a mitigating technique by, first, developing realistic full scale (FS and partial scale (PS induction generator models combined with two level back-to-back PECs. Subsequently, deriving a driving algorithm, which reduces PEC’s operating temperature by controlling its switching patterns. The developed switching procedure ensures minimum temperature fluctuations by adapting the variable DC link and system’s frequency of operation. It was found for both FS and PS topologies, that the generator side converters have higher mean junction temperatures where the grid side ones have more fluctuations on their thermal profile. The FS and PS cycling temperatures were reduced by 12 °C and 5 °C, respectively. Moreover, this led to a significant improvement in stress; approximately 27 MPa stress reduction for the FS induction generator PEC.

  7. Conceptual Design Study of a Closed Brayton Cycle Turbogenerator for Space Power Thermal-To-Electric Conversion System

    Science.gov (United States)

    Hansen, Jeff L.

    2000-01-01

    A conceptual design study was completed for a 360 kW Helium-Xenon closed Brayton cycle turbogenerator. The selected configuration is comprised of a single-shaft gas turbine engine coupled directly to a high-speed generator. The engine turbomachinery includes a 2.5:1 pressure ratio compression system with an inlet corrected flow of 0.44 kg/sec. The single centrifugal stage impeller discharges into a scroll via a vaned diffuser. The scroll routes the air into the cold side sector of the recuperator. The hot gas exits a nuclear reactor radiator at 1300 K and enters the turbine via a single-vaned scroll. The hot gases are expanded through the turbine and then diffused before entering the hot side sector of the recuperator. The single shaft design is supported by air bearings. The high efficiency shaft mounted permanent magnet generator produces an output of 370 kW at a speed of 60,000 rpm. The total weight of the turbogenerator is estimated to be only 123 kg (less than 5% of the total power plant) and has a volume of approximately 0.11 cubic meters. This turbogenerator is a key element in achieving the 40 to 45% overall power plant thermal efficiency.

  8. Effect of thermal aging on the low cycle fatigue behavior of Z3CN20.09M cast duplex stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Weifeng [School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072 (China); Xue, Fei [Suzhou Nuclear Power Research Institute, Suzhou 215004 (China); Tian, Yang [School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072 (China); Yu, Dunji, E-mail: djyu@tju.edu.cn [School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072 (China); Yu, Weiwei [Suzhou Nuclear Power Research Institute, Suzhou 215004 (China); Chen, Xu [School of Ch