WorldWideScience

Sample records for thermal cycling absorption

  1. Irreversibility analysis of hydrogen separation schemes in thermochemical cycles. [Condensation, physical absorption, diffusion, physical adsorption, thermal adsorption, and electrochemical separation

    Energy Technology Data Exchange (ETDEWEB)

    Cox, K.E.

    1978-01-01

    Six processes have been evaluated as regards irreversibility generation for hydrogen separation from binary gas mixtures. The results are presented as a series of plots of separation efficiency against the mol fraction hydrogen in the feed gas. Three processes, condensation, physical absorption and electrochemical separation indicate increasing efficiency with hydrogen content. The other processes, physical and thermal adsorption, and diffusion show maxima in efficiency at a hydrogen content of 50 mol percent. Choice of separation process will also depend on such parameters as condition of feed, impurity content and capital investment. For thermochemical cycles, schemes based on low temperature heat availability are preferable to those requiring a work input.

  2. Enhanced absorption cycle computer model

    Science.gov (United States)

    Grossman, G.; Wilk, M.

    1993-09-01

    Absorption heat pumps have received renewed and increasing attention in the past two decades. The rising cost of electricity has made the particular features of this heat-powered cycle attractive for both residential and industrial applications. Solar-powered absorption chillers, gas-fired domestic heat pumps, and waste-heat-powered industrial temperature boosters are a few of the applications recently subjected to intensive research and development. The absorption heat pump research community has begun to search for both advanced cycles in various multistage configurations and new working fluid combinations with potential for enhanced performance and reliability. The development of working absorption systems has created a need for reliable and effective system simulations. A computer code has been developed for simulation of absorption systems at steady state in a flexible and modular form, making it possible to investigate various cycle configurations with different working fluids. The code is based on unit subroutines containing the governing equations for the system's components and property subroutines containing thermodynamic properties of the working fluids. The user conveys to the computer an image of his cycle by specifying the different subunits and their interconnections. Based on this information, the program calculates the temperature, flow rate, concentration, pressure, and vapor fraction at each state point in the system, and the heat duty at each unit, from which the coefficient of performance (COP) may be determined. This report describes the code and its operation, including improvements introduced into the present version. Simulation results are described for LiBr-H2O triple-effect cycles, LiCl-H2O solar-powered open absorption cycles, and NH3-H2O single-effect and generator-absorber heat exchange cycles. An appendix contains the user's manual.

  3. Enhanced absorption cycle computer model. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Grossman, G.; Wilk, M. [Technion-Israel Inst. of Tech., Haifa (Israel). Faculty of Mechanical Engineering

    1993-09-01

    Absorption heat pumps have received renewed and increasing attention in the past two decades. The rising cost of electricity has made the particular features of this heat-powered cycle attractive for both residential and industrial applications. Solar-powered absorption chillers, gas-fired domestic heat pumps, and waste-heat-powered industrial temperatures boosters are a few of the applications recently subjected to intensive research and development. The absorption heat pump research community has begun to search for both advanced cycles in various multistage configurations and new working fluid combinations with potential for enhanced performance and reliability. The development of working absorptions systems has created a need for reliable and effective system simulations. A computer code has been developed for simulation of absorption systems at steady state in a flexible and modular form, making it possible to investigate various cycle configurations with different working fluids. The code is based on unit subroutines containing the governing equations for the system`s components and property subroutines containing thermodynamic properties of the working fluids. The user conveys to the computer an image of his cycle by specifying the different subunits and their interconnections. Based on this information, the program calculates the temperature, flow rate, concentration, pressure, and vapor fraction at each state point in the system, and the heat duty at each unit, from which the coefficient of performance (COP) may be determined. This report describes the code and its operation, including improvements introduced into the present version. Simulation results are described for LiBr-H{sub 2}O triple-effect cycles, LiCl-H{sub 2}O solar-powered open absorption cycles, and NH{sub 3}-H{sub 2}O single-effect and generator-absorber heat exchange cycles. An appendix contains the User`s Manual.

  4. Using lamb waves tomonitor moisture absorption thermally fatigues composite laminates

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Jae Sun; Cho, Youn Ho [School of Mechanical Engineering, Pusan National University, Busan (Korea, Republic of)

    2016-06-15

    Nondestructive evaluation for material health monitoring is important in aerospace industries. Composite laminates are exposed to heat cyclic loading and humid environment depending on flight conditions. Cyclic heat loading and moisture absorption may lead to material degradation such as matrix breaking, debonding, and delamination. In this paper, the moisture absorption ratio was investigated by measuring the Lamb wave velocity. The composite laminates were manufactured and subjected to different thermal aging cycles and moisture absorption. For various conditions of these cycles, not only changes in weight and also ultrasonic wave velocity were measured, and the Lamb wave velocity at various levels of moisture on a carbon-epoxy plate was investigated. Results from the experiment show a linear correlation between moisture absorption ratio and Lamb wave velocity at different thermal fatigue stages. The presented method can be applied as an alternative solution in the online monitoring of composite laminate moisture levels in commercial flights.

  5. Absorption heat pump cycles with NH

    NARCIS (Netherlands)

    Wang, M.; Infante Ferreira, C.A.

    2017-01-01

    Ionic liquids (ILs), as novel absorbents, draw considerable attention for their potential roles in replacing water or LiBr aqueous solutions in conventional NH3/H2O or H2O/LiBr absorption refrigeration or heat pump cycles. In this paper, performances of 9

  6. The Absorption Refrigerator as a Thermal Transformer

    Science.gov (United States)

    Herrmann, F.

    2009-01-01

    The absorption refrigerator can be considered a thermal transformer, that is, a device that is analogous to the electric transformer. The analogy is based on the correspondence between the extensive quantities, entropy and electric charge and the intensive variables, temperature and electric potential. (Contains 1 footnote and 6 figures.)

  7. On sound absorption and thermal properties of non-wovens

    OpenAIRE

    Chen Jin-Jing; Yu Hong-Qin; Guo Zheng; You Jin-Zhang; Song Wen-Fang

    2015-01-01

    Non-woven is widely used as auxiliary materials of automobile industry due to its excellent sound absorption capability and good thermal property. The paper concludes that its density greatly affects sound absorption and thermal resistance, and an aluminum evaporated film can enhance the thermal resistance.

  8. On sound absorption and thermal properties of non-wovens

    Directory of Open Access Journals (Sweden)

    Chen Jin-Jing

    2015-01-01

    Full Text Available Non-woven is widely used as auxiliary materials of automobile industry due to its excellent sound absorption capability and good thermal property. The paper concludes that its density greatly affects sound absorption and thermal resistance, and an aluminum evaporated film can enhance the thermal resistance.

  9. Overview of Ionic Liquids Used as Working Fluids in Absorption Cycles

    Directory of Open Access Journals (Sweden)

    Mehrdad Khamooshi

    2013-01-01

    Full Text Available The cycle performance of refrigeration cycles depends not only on their configuration, but also on thermodynamic properties of working pairs regularly composed of refrigerant and absorbent. The commonly used working pairs in absorption cycles are aqueous solutions of either lithium bromide water or ammonia water. However, corrosion, crystallization, high working pressure, and toxicity are their major disadvantages in industrial applications. Therefore, seeking more advantageous working pairs with good thermal stability, with minimum corrosion, and without crystallization has become the research focus in the past two decades. Ionic liquids (ILs are room-temperature melting salts that can remain in the liquid state at near or below room temperature. ILs have attracted considerable attention due to their unique properties, such as negligible vapor pressure, nonflammability, thermal stability, good solubility, low melting points, and staying in the liquid state over a wide temperature range from room temperature to about 300°C. The previously mentioned highly favorable properties of ILs motivated us for carrying out the present research and reviewing the available ILs found in the literature as the working fluids of absorption cycles. Absorption cycles contain absorption heat pumps, absorption chillers, and absorption transformers.

  10. Analysis of Decentralized Control for Absorption Cycle Heat Pumps

    DEFF Research Database (Denmark)

    Vinther, Kasper; Just Nielsen, Rene; Nielsen, Kirsten Mølgaard

    2015-01-01

    Email Print Request Permissions This paper investigates decentralized control structures for absorption cycle heat pumps and a dynamic nonlinear model of a single-effect LiBr-water absorption system is used as case study. The model has four controllable inputs, which can be used to stabilize...

  11. Thermal stress relaxation in magnesium composites during thermal cycling

    Energy Technology Data Exchange (ETDEWEB)

    Trojanova, Z.; Lukac, P. (Karlova Univ., Prague (Czech Republic)); Kiehn, J.; Kainer, K.U.; Mordike, B.L. (Technische Univ. Clausthal, Clausthal-Zellerfeld (Germany))

    1998-01-01

    It has been shown that the internal friction of Mg - Saffil metal matrix composites can be influenced by thermal stresses, if MMCc are submitted to thermal cycling between room temperature and an upper temperature of cycling. These stresses can be accommodated by generation and motion of dislocations giving the formation of the microplastic zones. The thermal stress relaxation depends on the upper temperature of cycling, the volume fraction of reinforcement and the matrix composition and can result in plastic deformation and strain hardening of the matrix without applied stress. The internal friction measurements can be used for non destructive investigation of processes which influence the mechanical properties. (orig.)

  12. Damage Assessment of Stress-Thermal Cycled high temperature

    Science.gov (United States)

    Ju, Jae-Hyung; Prochazka, Michael; Ronke, Ben; Morgan, Roger; Shin, Eugence

    2004-01-01

    We report on the characterization of bismaleimide and polyimide carbon fiber composite, microcrack development under stress thermal cycling loading. Such cycles range from cryogenic temperatures associated with cryogenic fuel (LN, LOX) containment to high temperatures of 300 degrees Celsius associated with future hypervelocity aeropropulsion systems. Microcrack development thresholds as a function of temperature range of the thermal cycle; the number of cycles; the applied stress level imposed on the composite are reported. We have conducted stress-thermal cycles on thin bismaleimide-woven carbon fiber foils for three temperature range cycles: 1. Ambient temperature - -196 degrees celsius. 2. Ambient temperature - 150 degrees Celsius; 200 degrees Celsius; 250 degrees Celsius. 3. -196 degrees Celsius - 250 degrees Celsius. The Principle findings are that the full cycles from -196 degrees Celsius to to 250 degrees Celsius cause the most significant microcrack of development. These observations indicate that the high temperature portion of the cycle under load causes fiber-matrix interface failure and subsequent exposure to higher stresses at the cryogenic, low temperature region results in composite matrix microcracking as a result of the additional stresses associate with the fiber-matrix thermal expansion mismatch. Our initial studies for 12 ply PMR-II-50 polyimide/M60JB carbon fabric [0f,90f,90f,0f,0f,90f]ls composites will be presented. The stress-thermal cycle test procedure for these will be described. Moisture absorption characteristics between cycles will be used to monitor interconnected microcrack development. The applied stress level will be 75% of the composite cryogenic (-196 degrees Celsius) ultimate strength.

  13. Ultrafast Thermal Cycling of Solar Panels

    National Research Council Canada - National Science Library

    Wall, T

    1998-01-01

    Two new cyclers that utilize a novel hybrid approach to perform fast thermal cycling of solar panels have been built and are now operational in the Mechanics and Materials Technology Center at The Aerospace Corporation...

  14. Methods and compositions for rapid thermal cycling

    Science.gov (United States)

    Beer, Neil Reginald; Benett, William J.; Frank, James M.; Deotte, Joshua R.; Spadaccini, Christopher

    2015-10-27

    The rapid thermal cycling of a material is targeted. A microfluidic heat exchanger with an internal porous medium is coupled to tanks containing cold fluid and hot fluid. Fluid flows alternately from the cold tank and the hot tank into the porous medium, cooling and heating samples contained in the microfluidic heat exchanger's sample wells. A valve may be coupled to the tanks and a pump, and switching the position of the valve may switch the source and direction of fluid flowing through the porous medium. A controller may control the switching of valve positions based on the temperature of the samples and determined temperature thresholds. A sample tray for containing samples to be thermally cycled may be used in conjunction with the thermal cycling system. A surface or internal electrical heater may aid in heating the samples, or may replace the necessity for the hot tank.

  15. Growth of Creamed TNT on Thermal Cycling

    Science.gov (United States)

    1978-07-01

    on this page): No Limitation 14. DESCRIPTORS: Explosives ; Trinitrotoluene; Growth; Thermal Cycling; Thermal Expansion; Impurities; Eutectics. T5...Apparatus 2 2. Materials 2 RESULTS 3 Series 1 3 Series 2 4 Series 3 5 Observations from Dilatometer Rprnreig 5 Surface Changes Accompanying Growth 6...filling prematures than similar rounds which have not. It was proposed that this desensitisation might be a result of the explosive expanding

  16. Standard Practice for Evaluating Solar Absorptive Materials for Thermal Applications

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2007-01-01

    1.1 This practice covers a testing methodology for evaluating absorptive materials used in flat plate or concentrating collectors, with concentrating ratios not to exceed five, for solar thermal applications. This practice is not intended to be used for the evaluation of absorptive surfaces that are (1) used in direct contact with, or suspended in, a heat-transfer liquid, (that is, trickle collectors, direct absorption fluids, etc.); (2) used in evacuated collectors; or (3) used in collectors without cover plate(s). 1.2 Test methods included in this practice are property measurement tests and aging tests. Property measurement tests provide for the determination of various properties of absorptive materials, for example, absorptance, emittance, and appearance. Aging tests provide for exposure of absorptive materials to environments that may induce changes in the properties of test specimens. Measuring properties before and after an aging test provides a means of determining the effect of the exposure. 1.3 Th...

  17. Influence of Thermal Cycling on Cryogenic Thermometers

    CERN Document Server

    Balle, C; Rieubland, Jean Michel; Suraci, A; Togny, F; Vauthier, N

    1999-01-01

    The stringent requirements on temperature control of the superconducting magnets for the Large Hadron Collider (LHC), impose that the cryogenic temperature sensors meet compelling demands such as long-term stability, radiation hardness, readout accuracy better than 5 mK at 1.8 K and compatibility with industrial control equipment. This paper presents the results concerning long-term stability of resistance temperature sensors submitted to cryogenic thermal cycles. For this task a simple test facility has been designed, constructed and put into operation for cycling simultaneously 115 cryogenic thermometers between 300 K and 4.2 K. A thermal cycle is set to last 71/4 hours: 3 hours for either cooling down or warming up the sensors and 1 respectively 1/4 hour at steady temperature conditions at each end of the temperature cycle. A Programmable Logic Controller (PLC) drives automatically this operation by reading 2 thermometers and actuating on 3 valves and 1 heater. The first thermal cycle was accomplished in a...

  18. Thermal properties of carbon black aqueous nanofluids for solar absorption

    Directory of Open Access Journals (Sweden)

    Han Dongxiao

    2011-01-01

    Full Text Available Abstract In this article, carbon black nanofluids were prepared by dispersing the pretreated carbon black powder into distilled water. The size and morphology of the nanoparticles were explored. The photothermal properties, optical properties, rheological behaviors, and thermal conductivities of the nanofluids were also investigated. The results showed that the nanofluids of high-volume fraction had better photothermal properties. Both carbon black powder and nanofluids had good absorption in the whole wavelength ranging from 200 to 2,500 nm. The nanofluids exhibited a shear thinning behavior. The shear viscosity increased with the increasing volume fraction and decreased with the increasing temperature at the same shear rate. The thermal conductivity of carbon black nanofluids increased with the increase of volume fraction and temperature. Carbon black nanofluids had good absorption ability of solar energy and can effectively enhance the solar absorption efficiency.

  19. Performance evaluation of combined ejector LiBr/H2O absorption cooling cycle

    Directory of Open Access Journals (Sweden)

    Hasan Sh. Majdi

    2016-03-01

    Full Text Available The objective of this work is to develop a computer simulation program to evaluate the performance of solar-assited combined ejector absorption (single-effect cooling system using LiBr/H2O as a working fluid and operating under steady-state conditions. The ejector possess no moving parts and is simple and reliable, which makes it attractive for combination with single-stage absorption cycle for further improvement to the system's performance. In this research, improvement to the system is achieved by utilizing the potential kinetic energy of the ejector to enhance refrigeration efficiency. The effects of the entrainment ratio of the ejector, operating temperature, on the thermal loads, and system performance have been investigated. The results showed that the evaporator and condenser loads, post-addition of the ejector, is found to be permanently higher than that in the basic cycle, which indicates a significant enhancement of the proposed cycle and the cooling capacity of the system increasing with the increase in evaporator temperature and entrainment ratio. The COP of the modified cycle is improved by up to 60 % compared with that of the basic cycle at the given condition. This process stabilizes the refrigeration system, enhanced its function, and enabled the system to work under higher condenser temperatures.

  20. Thermal noise reduction and absorption optimization via multimaterial coatings

    Science.gov (United States)

    Steinlechner, Jessica; Martin, Iain W.; Hough, Jim; Krüger, Christoph; Rowan, Sheila; Schnabel, Roman

    2015-02-01

    Future gravitational wave detectors (GWDs) such as Advanced LIGO upgrades and the Einstein Telescope are planned to operate at cryogenic temperatures using crystalline silicon (cSi) test-mass mirrors at an operation wavelength of 1550 nm. The reduction in temperature in principle provides a direct reduction in coating thermal noise, but the presently used coating stacks which are composed of silica (SiO2) and tantala (Ta2O5) show cryogenic loss peaks which results in less thermal noise improvement than might be expected. Due to low mechanical loss at low temperature amorphous silicon (aSi) is a very promising candidate material for dielectric mirror coatings and could replace Ta2O5. Unfortunately, such an aSi /SiO2 coating is not suitable for use in GWDs due to high optical absorption in aSi coatings. We explore the use of a three material based coating stack. In this multimaterial design the low absorbing Ta2O5 in the outermost coating layers significantly reduces the incident light power, while aSi is used only in the lower bilayers to maintain low optical absorption. Such a coating design would enable a reduction of Brownian thermal noise by 25%. We show experimentally that an optical absorption of only (5.3 ±0.4 ) ppm at 1550 nm should be achievable.

  1. Absorption Cycle Heat Pump Model for Control Design

    DEFF Research Database (Denmark)

    Vinther, Kasper; Just Nielsen, Rene; Nielsen, Kirsten Mølgaard

    2015-01-01

    Heat pumps have recently received increasing interest due to green energy initiatives and increasing energy prices. In this paper, a nonlinear dynamic model of a single-effect LiBr-water absorption cycle heat pump is derived for simulation and control design purposes. The model is based...... on an actual heat pump located at a larger district heating plant. The model is implemented in Modelica and is based on energy and mass balances, together with thermodynamic property functions for LiBr and water and staggered grid representations for heat exchangers. Model parameters have been fitted...... to operational data and different scenarios are simulated to investigate the operational stability of the heat pump. Finally, this paper provides suggestions and examples of derivation of lower order linear models for control design. © Copyright IEEE - All rights reserved....

  2. Research on nanosatellite thermal cycling test applicability

    Directory of Open Access Journals (Sweden)

    Li Xiyuan

    2017-01-01

    Full Text Available In order to verify the spacecraft performance in extreme temperature and vacuum, and to screen spacecraft early defect, generally spacecraft TV (Thermal Vacuum test should be carried out before launch. Designed in small size and with low cost, nanosatellite is made from a large number of COTS (Commercial off the shelf components; therefore, the test should be low-cost, simple and quick. With the intention of screen out early defects of the product in lower cost, nanosatellite developers usually use TC (Thermal Cycling test to partially replace the TV test because TV test is more expensive. However, due to the air convection, TC test is different from TV test in heat transfer characteristics, which may be over-test or short-test in TC test. This paper aims to explore the applicability of different nanosatellites in TC/TV test. Using rule number analysis method, Heat Transfer model in vacuum and ambient environment has been built to analyse the characteristics of heat transfer under different temperature and characteristic length, and to deliver the recommended limits on using TC test instead of the TV test. The CFD and test methods are applied to verify the rule number analysis above.

  3. Performance of Different Experimental Absorber Designs in Absorption Heat Pump Cycle Technologies: A Review

    Directory of Open Access Journals (Sweden)

    Jonathan Ibarra-Bahena

    2014-02-01

    Full Text Available The absorber is a major component of absorption cycle systems, and its performance directly impacts the overall size and energy supplies of these devices. Absorption cooling and heating cycles have different absorber design requirements: in absorption cooling systems, the absorber works close to ambient temperature, therefore, the mass transfer is the most important phenomenon in order to reduce the generator size; on the other hand, in heat transformer absorption systems, is important to recover the heat delivered by exothermic reactions produced in the absorber. In this paper a review of the main experimental results of different absorber designs reported in absorption heat pump cycles is presented.

  4. Absorption refrigeration cycle applied to offshore platforms; Refrigeracao por absorcao aplicada a plataformas de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Maximino Joaquim Pina [KROMAV Engenharia, Rio de Janeiro, RJ (Brazil); Pinto, Luiz Antonio Vaz; Belchior, Carlos Rodrigues Pereira [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia (COPPE)

    2004-07-01

    To produce cold from the heat seems a task unlikely or even impossible. However, absorption systems produce cooling from heat sources and it exist since the century XIX. In industrial places is very important to improve the energy use, even more in places where the activities involve great costs and incomes. Traditionally the alternatives conflict in the aspects of initial and operational costs. This paper describes the absorption systems operation and its main advantages and disadvantages, when compared to the traditional systems with compressor. The known fact that a vapor compressor system presents larger efficiency is not enough to validate it for all of the applications. In this sense, the initial and operational analysis of the costs of the absorption systems becomes interesting. In spite of, double effect absorption systems are demonstrating the evolution of the absorption cycle in order to obtain better performance. Turbo-generators and Turbo-compressors of the offshore platforms are thermal machines that reject great amount of heat in the exhaust gases. This heat is used for heating of water used in the Process Plant. The processes of separation of the mixture water-oil-gas from the well, for instance, use that heat. Even after the passage of the water in the Plant of Process, the residual heat is still enough for the use in absorption systems. A simulation is done using real data of an offshore platform. Two possible alternatives are compared under technical and economical aspects. Sensibility analysis is also performed in order to verify possible impacts of variations of electric power cost. (author)

  5. Performance of diffusion absorption refrigeration cycle with organic working fluids

    Energy Technology Data Exchange (ETDEWEB)

    Zohar, A.; Jelinek, M.; Levy, A.; Borde, I. [Pearlstone Center for Aeronautical Engineering Studies, Mechanical Engineering Department, Ben-Gurion University of the Negev, P.O. Box 653, Beer-Sheva 84105 (Israel)

    2009-09-15

    A diffusion absorption refrigeration (DAR) cycle is driven by heat and utilizes a binary solution of refrigerant and absorbent as working fluid, together with an auxiliary inert gas. Commercial DAR systems operate with ammonia-water solution and hydrogen or helium as the inert gas. In this work, the performance of a simplified DAR system working with an organic absorbent (DMAC - dimethylacetamide) and five different refrigerants and helium as inert gas was examined numerically, with the aim of lowering the generator temperature and system pressure along with a non-toxic refrigerant The refrigerants were: chlorodifluoromethane (R22), difluoromethane (R32), 2-chloro-1,1,1,2-tetrafluoroethane (R124), pentafluoroethane (R125) and 1,1,1,2-tetrafluoroethane (R134a). The results were compared with the performance of the same system working with ammonia-water and helium. Similar behavior was found for all systems, regarding the coefficient of performance (COP) and rich and poor solution concentrations as functions of generator temperature. It was found that typical generator temperature with the new substances was 150 C, yet lower COPs, higher evaporator temperatures and lower condensation temperature of about 40 C governed these systems. (author)

  6. Thermally induced nonlinear optical absorption in metamaterial perfect absorbers

    Energy Technology Data Exchange (ETDEWEB)

    Guddala, Sriram, E-mail: sguddala@iitk.ac.in; Kumar, Raghwendra; Ramakrishna, S. Anantha [Department of Physics, Indian Institute of Technology Kanpur, Kanpur 208016 (India)

    2015-03-16

    A metamaterial perfect absorber consisting of a tri-layer (Al/ZnS/Al) metal-dielectric-metal system with top aluminium nano-disks was fabricated by laser-interference lithography and lift-off processing. The metamaterial absorber had peak resonant absorbance at 1090 nm and showed nonlinear absorption for 600ps laser pulses at 1064 nm wavelength. A nonlinear saturation of reflectance was measured to be dependent on the average laser power incident and not the peak laser intensity. The nonlinear behaviour is shown to arise from the heating due to the absorbed radiation and photo-thermal changes in the dielectric properties of aluminium. The metamaterial absorber is seen to be damage resistant at large laser intensities of 25 MW/cm{sup 2}.

  7. Intermittent Solar Ammonia Absorption Cycle (ISAAC) refrigeration for lesser developed countries

    Science.gov (United States)

    Erickson, Donald C.

    1990-02-01

    The Intermittent Solar Ammonia Absorption Cycle (ISAAC) refrigerator is a solar thermal technology which provides low cost, efficient, reliable ice-making to areas without ready access to electricity. An ISAAC refrigeration system consists of a compound parabolic solar collector, two pressure vessels, a condenser, a cold box or refrigerated space, and simple connective piping -- no moving parts or electrical components. Most parts are simple construction or plumbing grade materials, locally available in many remote areas. This technology has numerous potential benefits in lesser developed countries both by providing a cheap, reliable source of ice, and, since manufacture requires only semi-skilled labor, a source of employment to the local economy. Applications include vaccine storage for health care clinics; fish, meat, and dairy product storage; and personal consumption. Importantly, this technology increases the quality of life for people in lesser developed countries without depleting fossil fuel resources or increasing the release of greenhouse gases such as CO2 and chlorofluorocarbons.

  8. Thermally regenerative hydrogen/oxygen fuel cell power cycles

    Science.gov (United States)

    Morehouse, J. H.

    1986-01-01

    Two innovative thermodynamic power cycles are analytically examined for future engineering feasibility. The power cycles use a hydrogen-oxygen fuel cell for electrical energy production and use the thermal dissociation of water for regeneration of the hydrogen and oxygen. The TDS (thermal dissociation system) uses a thermal energy input at over 2000 K to thermally dissociate the water. The other cycle, the HTE (high temperature electrolyzer) system, dissociates the water using an electrolyzer operating at high temperature (1300 K) which receives its electrical energy from the fuel cell. The primary advantages of these cycles is that they are basically a no moving parts system, thus having the potential for long life and high reliability, and they have the potential for high thermal efficiency. Both cycles are shown to be classical heat engines with ideal efficiency close to Carnot cycle efficiency. The feasibility of constructing actual cycles is investigated by examining process irreversibilities and device efficiencies for the two types of cycles. The results show that while the processes and devices of the 2000 K TDS exceed current technology limits, the high temperature electrolyzer system appears to be a state-of-the-art technology development. The requirements for very high electrolyzer and fuel cell efficiencies are seen as determining the feasbility of the HTE system, and these high efficiency devices are currently being developed. It is concluded that a proof-of-concept HTE system experiment can and should be conducted.

  9. Effect of thermal state and thermal comfort on cycling performance in the heat

    NARCIS (Netherlands)

    Schulze, E.; Daanen, H.A.M.; Levels, K.; Casadio, J.R.; Plews, D.J.; Kliding, A.E.; Siegel, R.; Laursen, P.B.

    2015-01-01

    Purpose: To determine the effect of thermal state and thermal comfort on cycling performance in the heat. Methods: Seven well-trained male triathletes completed 3 performance trials consisting of 60 min cycling at a fixed rating of perceived exertion (14) followed immediately by a 20-km time trial

  10. Fast thermal cycling-enhanced electromigration in power metallization

    NARCIS (Netherlands)

    Nguyen, Van Hieu; Salm, Cora; Krabbenborg, B.H.; Krabbenborg, B.H.; Bisschop, J.; Mouthaan, A.J.; Kuper, F.G.

    Fast thermal nterconnects used in power ICs are susceptible to short circuit failure due to a combination of fast thermal cycling and electromigration stresses. In this paper, we present a study of electromigration-induced extrusion short-circuit failure in a standard two level metallization

  11. Thermal Analysis of a Solar Powered Absorption Cooling System with Fully Mixed Thermal Storage at Startup

    Directory of Open Access Journals (Sweden)

    Camelia Stanciu

    2017-01-01

    Full Text Available A simple effect one stage ammonia-water absorption cooling system fueled by solar energy is analyzed. The considered system is composed by a parabolic trough collector concentrating solar energy into a tubular receiver for heating water. This is stored in a fully mixed thermal storage tank and used in the vapor generator of the absorption cooling system. Time dependent cooling load is considered for the air conditioning of a residential two-storey house. A parametric study is performed to analyze the operation stability of the cooling system with respect to solar collector and storage tank dimensions. The results emphasized that there is a specific storage tank dimension associated to a specific solar collector dimension that could ensure the longest continuous startup operation of the cooling system when constant mass flow rates inside the system are assumed.

  12. The Effect of New Collision-Induced Absorption Coefficients on the Early Mars Limit Cycle Hypothesis

    Science.gov (United States)

    Hayworth, B. P.; Payne, R. C.; Kasting, J. F.

    2017-11-01

    Updating the Limit Cycling (LC) Model for early Mars with new absorption coefficients to test for changes to LC behavior and to potentially lower needed concentrations of greenhouse gases. Thought will be given to the effect of LC on habitability.

  13. Absorptive capacity, technological innovation, and product life cycle: a system dynamics model

    National Research Council Canada - National Science Library

    Zou, Bo; Guo, Feng; Guo, Jinyu

    2016-01-01

    .... Based on interviews with 24 Chinese firms, this study develops a system-dynamics model that incorporates an important feedback loop among absorptive capacity, technological innovation, and product life cycle (PLC...

  14. Eutectic mixtures of some fatty acids for latent heat storage: Thermal properties and thermal reliability with respect to thermal cycling

    Energy Technology Data Exchange (ETDEWEB)

    Sari, Ahmet [Department of Chemistry, Gaziosmanpasa University, 60240 Tokat (Turkey)]. E-mail: asari@gop.edu.tr

    2006-06-15

    Accelerated thermal cycle tests have been conducted to study the change in melting temperatures and latent heats of fusion of the eutectic mixtures of lauric acid (LA)-myristic acid (MA), lauric acid (LA)-palmitic acid (PA) and myristic acid (MA)-stearic acid (SA) as latent heat storage materials. The thermal properties of these materials were determined by the differential scanning calorimetry (DSC) analysis method. The thermal reliability of the eutectic mixtures after melt/freeze cycles of 720, 1080 and 1460 was also evaluated using the DSC curves. The accelerated thermal cycle tests indicate that the melting temperatures usually tend to decrease, and the variations in the latent heats of fusion are irregular with increasing number of thermal cycles. Moreover, the probable reasons for the change in thermal properties of the eutectic mixtures after repeated thermal cycles were investigated. Fourier Transform Infrared (FT-IR) spectroscopic analysis indicates that the accelerated melt/freeze processes do not cause any degradation in the chemical structure of the mixtures. The change in thermal properties of the eutectic mixtures with increasing number of thermal cycles is only because of the presence of certain amounts of impurities in the fatty acids used in their preparation. It is concluded that the tested eutectic mixtures have reasonable thermal properties and thermal reliability as phase change materials (PCMs) for latent heat storage in any solar heating applications that include a four year utilization period.

  15. A LiBr-H2O Absorption Refrigerator Incorporating a Thermally Activated Solution Pumping Mechanism

    Directory of Open Access Journals (Sweden)

    Ian W. Eames

    2017-02-01

    Full Text Available This paper provides an illustrated description of a proposed LiBr-H2O vapour absorption refrigerator which uses a thermally activated solution pumping mechanism that combines controlled variations in generator vapour pressure with changes it produces in static-head pressure difference to circulate the absorbent solution between the generator and absorber vessels. The proposed system is different and potentially more efficient than a bubble pump system previously proposed and avoids the need for an electrically powered circulation pump found in most conventional LiBr absorption refrigerators. The paper goes on to provide a sample set of calculations that show that the coefficient of performance values of the proposed cycle are similar to those found for conventional cycles. The theoretical results compare favourably with some preliminary experimental results, which are also presented for the first time in this paper. The paper ends by proposing an outline design for an innovative steam valve, which is a key component needed to control the solution pumping mechanism.

  16. Study on durability for thermal cycle of planar SOFC

    Energy Technology Data Exchange (ETDEWEB)

    Ando, Motoo; Nakata, Kei-ichi; Wakayama, Sin-ichi [Tonen Corp., Saitama (Japan)] [and others

    1996-12-31

    TONEN CORPORATION has developed planar type SOFC since 1986. We demonstrated the output of 1.3 kW in 1991 and 5.1 kW in 1995. Simultaneously we have studied how to raise electric efficiency and reliability utilizing hydrogen and propane as fuel. Durability for thermal cycle is one of the most important problems of planar SOFC to make it more practical. The planar type SOFC is made up of separator, zirconia electrolyte and glass sealant. The thermal expansion of these components are expected to be the same value, however, they still possess small differences. In this situation, a thermal cycle causes a thermal stress due to the difference of the cell components and is often followed by a rupture in cell components, therefore, the analysis of the thermal stress should give us much useful information. The thermal cycle process consists of a heating up and cooling down procedure. Zirconia electrolyte is not bonded to the separator under the condition of the initial heating up procedure, and glass sealant becomes soft or melts and glass seals spaces between the zirconia and separator. The glass sealant becomes harder with the cooling down procedure. Moreover, zirconia is tightly bonded with separator below a temperature which is defined as a constraint temperature and thermal stress also occurs. This indicates that the heating up process relaxes the thermal stress and the cooling down increases it. In this paper, we simulated dependence of the stress on the sealing configuration, thermal expansion of sealant and constraint temperature of sealant glass. Furthermore, we presented SOFC electrical properties after a thermal cycle.

  17. Molecular Simulation of NH3/Ionic Liquid Mixtures for Absorption Heat Pump Cycles

    NARCIS (Netherlands)

    Kabra, Abhishek; Becker, T.M.; Wang, M.; Infante Ferreira, C.A.; Vlugt, T.J.H.

    2017-01-01

    Force Field based Monte Carlo (MC) simulations are conducted to predict the performance of an absorption heat pump cycle involving NH3/ionic liquid (IL) (refrigerant/absorbent) as working pair. To investigate the thermodynamic performance of the cycle, various properties such as the enthalpy of

  18. Influence of surface roughness on consecutively hydrogen absorption cycles in Ti-6Al-4V alloy

    Energy Technology Data Exchange (ETDEWEB)

    Lopez-Suarez, Alejandra [Instituto de Fisica, Universidad Nacional Autonoma de Mexico, A.P. 20-364, Mexico D.F. 01000 (Mexico)

    2010-10-15

    In the present work the influence of roughness of the material surface with hydrogen absorption in Ti-6Al-4V alloy during four hydrogenated cycles is studied. The Ti-6Al-4V alloy samples were hydrogenated during several cycles at 650 C for two hours, in 50% hydrogen and 50% argon atmospheres, 1 atm pressure and a flux of 50 cm{sup 3}/min each one. The hydrogen concentrations are measured using Elastic Recoil Detection Analysis technique; meanwhile the roughness is measured using an Atomic Force Microscope. X-ray Diffraction analysis shows changes in crystal orientation due to hydrogen absorption. The hydrogen capacity of the Ti-6Al-4V alloy is observed to be directly correlated to the surface quality of the sample during the first hydrogenation cycles, but in the fourth cycle, the hydrogen absorption is almost equal for all the samples independently of their surface roughness. (author)

  19. Effects of thermal cycling on aluminum metallization of power diodes

    DEFF Research Database (Denmark)

    Brincker, Mads; Pedersen, Kristian Bonderup; Kristensen, Peter Kjær

    2015-01-01

    Reconstruction of aluminum metallization on top of power electronic chips is a well-known wear out phenomenon under power cycling conditions. However, the origins of reconstruction are still under discussion. In the current study, a method for carrying out passive thermal cycling of power diodes...... is controlled and the device is not subjected to a current load the observed degradation of metallization and corresponding increase of resistance is purely induced by thermo-mechanical stress. A correlation between number of cycles, micro-structural evolution, and sheet resistance is found and conclusions...

  20. Weldability investigation steel P 91 by weld thermal cycle simulation

    Directory of Open Access Journals (Sweden)

    M. Dunđer

    2015-07-01

    Full Text Available This paper elaborates results of hardness and impact energy of thermal cycle simulated specimens of high-alloy steel P 91 and their dependence on cooling time from 800 to 500 °C. Results were obtained by measuring hardness HV 1 and by experimental testing of Charpy notched specimens. Metallographic analysis of samples was performed on scanning electronic microscope.

  1. A thermal-cycling method for disaggregating monoclonal antibody oligomers.

    Science.gov (United States)

    Sadavarte, Rahul H; Ghosh, Raja

    2014-03-01

    Non-native oligomeric forms of biopharmaceutical proteins are therapeutically inactive, and potentially toxic and immunogenic, and therefore undesirable in pharmaceutical formulations. Immunoglobulin G class of antibodies are known to form stable nonnative oligomers through Fab-Fab interactions. In this paper, we investigate thermal-cycling as a technique for disaggregating antibody oligomers. Aggregate containing monoclonal antibody (mAb) samples were exposed to rapid heating and cooling cycles in a thermal-cycler. The heating phase of the thermal-cycle resulted in partial unfolding of the Fab domain, leading to the release of monomer from the oligomer complexes, whereas the rapid cooling that followed led to refolding and minimized the probability of protein reaggregation. The extent of mAb oligomer disaggregation was determined by size-exclusion chromatography and hydrophobic interaction membrane chromatography, whereas protein refolding was assessed by circular dichroism spectroscopy. The thermal-cycling technique in addition to being suitable for disaggregating protein oligomer samples could also potentially be useful for studying the mechanisms of protein aggregation and disaggregation. © 2014 Wiley Periodicals, Inc. and the American Pharmacists Association.

  2. BOXTO as a real-time thermal cycling reporter dye

    Indian Academy of Sciences (India)

    PRAKASH

    BOXTO as a real-time thermal cycling reporter dye. ASHRAF I AHMAD. Department of Chemical and Biological Engineering-Molecular Biotechnology, Chalmers University of Technology,. 405 30 Göteborg, Sweden. (Fax, 46 31 773 3910; Email, ashraf.ahmad@molbiotech.chalmers.se). The unsymmetrical cyanine dyes ...

  3. Absorption coefficient of nearly transparent liquids measured using thermal lens spectrometry

    Directory of Open Access Journals (Sweden)

    H.Cabrera

    2006-01-01

    Full Text Available We use an optimized pump-probe mode-mismatched thermal lens scheme to determine the optical absorption coefficient and thermal diffusivity of ethanol, benzene, acetone, methanol, toluene and chloroform. In this scheme the excitation beam is focused in the presence of a collimated probe beam. The agreement between experimentally obtained results and values reported in the literature is good.

  4. High-speed thermal cycling system and method of use

    Science.gov (United States)

    Hansen, A.D.A.; Jaklevic, J.M.

    1996-04-16

    A thermal cycling system and method of use are described. The thermal cycling system is based on the circulation of temperature-controlled water directly to the underside of thin-walled polycarbonate plates. The water flow is selected from a manifold fed by pumps from heated reservoirs. The plate wells are loaded with typically 15-20 microliters of reagent mix for the PCR process. Heat transfer through the thin polycarbonate is sufficiently rapid that the contents reach thermal equilibrium with the water in less than 15 seconds. Complete PCR amplification runs of 40 three-step cycles have been performed in as little as 14.5 minutes, with the results showing substantially enhanced specificity compared to conventional technology requiring run times in excess of 100 minutes. The plate clamping station is designed to be amenable to robotic loading and unloading of the system. It includes a heated lid, thus eliminating the need for mineral oil overlay of the reactants. The present system includes three or more plate holder stations, fed from common reservoirs but operating with independent switching cycles. The system can be modularly expanded. 13 figs.

  5. Thermal cycling tests on surface-mount assemblies

    Science.gov (United States)

    Jennings, C. W.

    1988-03-01

    The capability of surface-mount (SM) solder joints to withstand various thermal cycle stresses was evaluated through electrical circuit resistance changes of a test pattern and by visual examination for cracks in the solder after exposure to thermal cycling. The joints connected different electrical components, primarily leadless-chip carriers (LCCs), and printed wiring-board (PWB) pads on different laminate substrates. Laminate compositions were epoxy-glass and polyimide-glass with and without copper/Invar/copper (CIC) inner layers, polyimide-quartz, epoxy-Kevlar, and polyimide-Kevlar. The most resistant joints were between small LCCs (24 and 48 pins) and polyimide-glass laminate with CIC inner layers. Processing in joint formation was found to be an important part of joint resistant. Thermal cycling was varied with respect to both time and temperature. A few resistors, capacitors, and inductors showed opens after 500 30-min cycles between -65 C and 125 C. Appreciable moisture contents were measured for laminate materials, especially those of polyimide-Kevlar after equilibration in 100 percent relative humidity at room temperature. If not removed or reduced, moisture can cause delamination in vapor-phase soldering.

  6. Thermal cycling tests on surface-mount assemblies

    Energy Technology Data Exchange (ETDEWEB)

    Jennings, C.W.

    1988-03-01

    The capability of surface-mount (SM) solder joints to withstand various thermal cycle stresses was evaluated through electrical circuit resistance changes of a test pattern and by visual examination for cracks in the solder after exposure to thermal cycling. The joints connected different electrical components, primarily leadless-chip carriers (LCCs), and printed wiring-board (PWB) pads on different laminate substrates. Laminate compositions were epoxy-glass and polyimide-glass with and without copper/Invar/copper (CIC) inner layers, polyimide-quartz, epoxy-Kevlar, and polyimide-Kevlar. The most resistant joints were between small LCCs (24 and 48 pins) and polyimide-glass laminate with CIC inner layers. Processing in joint formation was found to be an important part of joint resistant. Thermal cycling was varied with respect to both time and temperature. A few resistors, capacitors, and inductors showed opens after 500 30-min cycles between -65/degree/C and 125/degree/C. Appreciable moisture contents were measured for laminate materials, especially those of polyimide-Kevlar after equilibration in 100/percent/ relative humidity at room temperature. If not removed or reduced, moisture can cause delamination in vapor-phase soldering. 17 refs, 12 figs.,10 tabs.

  7. Performance analysis of double-effect absorption heat pump cycle using NH

    NARCIS (Netherlands)

    Wang, M.; Infante Ferreira, C.A.

    2017-01-01

    Ionic liquids (ILs), as novel absorbents, draw considerable attention for their potential roles in replacing H2O or LiBr aqueous solutions in conventional NH3/H2O or H2O/LiBr absorption chiller or heat pump cycles. In this paper, NH3/IL working pairs are proposed for implementation in parallel

  8. Performance analysis of double-effect absorption heat pump cycle using NH3/ILs pairs

    NARCIS (Netherlands)

    Wang, M.; Infante Ferreira, C.A.

    2017-01-01

    Ionic liquids (ILs), as novel absorbents, draw considerable attention for their potential roles in replacing H2O or LiBr aqueous solutions in conventional NH3/H2O or H2O/LiBr absorption chiller or heat pump cycles. In this paper, NH3/IL working pairs are proposed for implementation in parallel

  9. Electrically and thermally conductive underwater acoustically absorptive graphene/rubber nanocomposites for multifunctional applications.

    Science.gov (United States)

    Li, Ying; Xu, Fan; Lin, Zaishan; Sun, Xianxian; Peng, Qingyu; Yuan, Ye; Wang, Shasha; Yang, Zhiyu; He, Xiaodong; Li, Yibin

    2017-10-05

    Graphene is ideal filler in nanocomposites due to its unique mechanical, electrical and thermal properties. However, it is challenging to uniformly distribute the large fraction of graphene fillers into a polymer matrix because graphene is not easily functionalized. We report a novel method to introduce a large fraction of graphene into a styrene-butadiene rubber (SBR) matrix. The obtained graphene/rubber nanocomposites were mechanically enhanced, acoustically absorptive under water, and electrically and thermally conductive. The Young's modulus of the nanocomposites was enhanced by over 30 times over that for rubber. The electrical conductivity of nanocomposites was ≤219 S m-1 with 15% volume fraction of graphene content, and exhibited remarkable electromagnetic shielding efficiency of 45 dB at 8-12 GHz. The thermal conductivity of the nanocomposites was ≤2.922 W m-1 k-1, which was superior to the values of thermally conductive silicone rubber thermal interface materials. Moreover, the nanocomposites exhibited excellent underwater sound absorption (average absorption coefficient >0.8 at 6-30 kHz). Notably, the absorption performance of graphene/SBR nanocomposites increased with increasing water pressure. These multifunctional graphene/SBR nanocomposites have promising applications in electronics, thermal management and marine engineering.

  10. Thermal stress cycling of GaAs solar cells

    Science.gov (United States)

    Janousek, B. K.; Francis, R. W.; Wendt, J. P.

    1985-01-01

    A thermal cycling experiment was performed on GaAs solar cells to establish the electrical and structural integrity of these cells under the temperature conditions of a simulated low-Earth orbit of 3-year duration. Thirty single junction GaAs cells were obtained and tests were performed to establish the beginning-of-life characteristics of these cells. The tests consisted of cell I-V power output curves, from which were obtained short-circuit current, open circuit voltage, fill factor, and cell efficiency, and optical micrographs, spectral response, and ion microprobe mass analysis (IMMA) depth profiles on both the front surfaces and the front metallic contacts of the cells. Following 5,000 thermal cycles, the performance of the cells was reexamined in addition to any factors which might contribute to performance degradation. It is established that, after 5,000 thermal cycles, the cells retain their power output with no loss of structural integrity or change in physical appearance.

  11. Mir Cooperative Solar Array Project Accelerated Life Thermal Cycling Test

    Science.gov (United States)

    Hoffman, David J.; Scheiman, David A.

    1996-01-01

    The Mir Cooperative Solar Array (MCSA) project was a joint U.S./Russian effort to build a photovoltaic (PV) solar array and deliver it to the Russian space station Mir. The MCSA will be used to increase the electrical power on Mir and provide PV array performance data in support of Phase 1 of the International Space Station. The MCSA was brought to Mir by space shuttle Atlantis in November 1995. This report describes an accelerated thermal life cycle test which was performed on two samples of the MCSA. In eight months time, two MCSA solar array 'mini' panel test articles were simultaneously put through 24,000 thermal cycles. There was no significant degradation in the structural integrity of the test articles and no electrical degradation, not including one cell damaged early and removed from consideration. The nature of the performance degradation caused by this one cell is briefly discussed. As a result of this test, changes were made to improve some aspects of the solar cell coupon-to-support frame interface on the flight unit. It was concluded from the results that the integration of the U.S. solar cell modules with the Russian support structure would be able to withstand at least 24,000 thermal cycles (4 years on-orbit). This was considered a successful development test.

  12. Testing of High Thermal Cycling Stability of Low Strength Concrete as a Thermal Energy Storage Material

    Directory of Open Access Journals (Sweden)

    Chao Wu

    2016-09-01

    Full Text Available Concrete has the potential to become a solution for thermal energy storage (TES integrated in concentrating solar power (CSP systems due to its good thermal and mechanical properties and low cost of material. In this study, a low strength concrete (C20 is tested at high temperatures up to 600 °C. Specimens are thermally cycled at temperatures in the range of 400–300 °C, 500–300 °C, and 600–300 °C, which TES can reach in operation. For comparison, specimens also cycled at temperature in the range of 400–25 °C (room temperature, 500–25 °C, and 600–25 °C. It is found from the test results that cracks are not observed on the surfaces of concrete specimens until the temperature is elevated up to 500 °C. There is mechanical deterioration of concrete after exposure to high temperature, especially to high thermal cycles. The residual compressive strength of concrete after 10 thermal cycles between 600 °C and 300 °C is about 58.3%, but the specimens remain stable without spalling, indicating possible use of low strength concrete as a TES material.

  13. Simulation and parametric optimisation of thermal power plant cycles

    Directory of Open Access Journals (Sweden)

    P. Ravindra Kumar

    2016-09-01

    Full Text Available The objective of the paper is to analyse parametric studies and optimum steam extraction pressures of three different (subcritical, supercritical and ultra-supercritical coal fired power plant cycles at a particular main steam temperature of 600 °C by keeping the reheat temperature at 537 °C and condenser pressure at 0.09 bar as constant. In order to maximize the heat rate gain possible with supercritical and ultra-supercritical steam conditions, eight stages of feed water heater arrangement with single reheater is considered. The system is optimized in such a way that the percentage exergetic losses are reduced for the increase of the exergetic efficiency and higher fuel utilization. The plant cycles are simulated and optimized by using Cycle Tempo 5.0 simulation software tool. From the simulation study, it is observed that the thermal efficiency of the three different power plant cycles obtained as 41.40, 42.48 and 43.03%, respectively. The specific coal consumption for three different power plant cycles are 0.56, 0.55 and 0.54 Tonnes/MWh. The improvement in feed water temperatures at the inlet of steam generator of respective cycles are 291, 305 and 316 °C.

  14. Optimal design of solid oxide fuel cell, ammonia-water single effect absorption cycle and Rankine steam cycle hybrid system

    Science.gov (United States)

    Mehrpooya, Mehdi; Dehghani, Hossein; Ali Moosavian, S. M.

    2016-02-01

    A combined system containing solid oxide fuel cell-gas turbine power plant, Rankine steam cycle and ammonia-water absorption refrigeration system is introduced and analyzed. In this process, power, heat and cooling are produced. Energy and exergy analyses along with the economic factors are used to distinguish optimum operating point of the system. The developed electrochemical model of the fuel cell is validated with experimental results. Thermodynamic package and main parameters of the absorption refrigeration system are validated. The power output of the system is 500 kW. An optimization problem is defined in order to finding the optimal operating point. Decision variables are current density, temperature of the exhaust gases from the boiler, steam turbine pressure (high and medium), generator temperature and consumed cooling water. Results indicate that electrical efficiency of the combined system is 62.4% (LHV). Produced refrigeration (at -10 °C) and heat recovery are 101 kW and 22.1 kW respectively. Investment cost for the combined system (without absorption cycle) is about 2917 kW-1.

  15. Cryogenic Thermal Absorptance Measurements on Small-Diameter Stainless Steel Tubing

    Science.gov (United States)

    Tuttle, James; Jahromi, Amir; Canavan, Edgar; DiPirro, Michael

    2015-01-01

    The Mid Infrared Instrument (MIRI) on the James Webb Space Telescope includes a mechanical cryocooler which cools its detectors to their 6 Kelvin operating temperature. The coolant gas flows through several meters of small-diameter stainless steel tubing, which is exposed to thermal radiation from its environment. Over much of its length this tubing is gold-plated to minimize the absorption of this radiant heat. In order to confirm that the cryocooler will meet MIRI's requirements, the thermal absorptance of this tubing was measured as a function of its environment temperature. We describe the measurement technique and present the results.

  16. Evaluation Analysis of the CO2 Emission and Absorption Life Cycle for Precast Concrete in Korea

    Directory of Open Access Journals (Sweden)

    Taehyoung Kim

    2016-07-01

    Full Text Available To comply with recent international trends and initiatives, and in order to help achieve sustainable development, Korea has established a greenhouse gas (GHG emission reduction target of 37% (851 million tons of the business as usual (BAU rate by 2030. Regarding environmentally-oriented standards such as the IGCC (International Green Construction Code, there are also rising demands for the assessment on CO2 emissions during the life cycle in accordance with ISO (International Standardization Organization’s Standard 14040. At present, precast concrete (PC engineering-related studies primarily cover structural and construction aspects, including improvement of structural performance in the joint, introduction of pre-stressed concrete and development of half PC. In the manufacture of PC, steam curing is mostly used for the early-strength development of concrete. In steam curing, a large amount of CO2 is produced, causing an environmental problem. Therefore, this study proposes a method to assess CO2 emissions (including absorption throughout the PC life cycle by using a life cycle assessment (LCA method. Using the proposed assessment method, CO2 emissions during the life cycle of a precast concrete girder (PCG were assessed. In addition, CO2 absorption was assessed against a PCG using conventional carbonation and CO2 absorption-related models. As a result, the CO2 emissions throughout the life cycle of the PCG were 1365.6 (kg-CO2/1 PCG. The CO2 emissions during the production of raw materials among the CO2 emissions throughout the life cycle of the PCG were 1390 (kg-CO2/1 PCG, accounting for a high portion to total CO2 emissions (nearly 90%. In contrast, the transportation and manufacture stages were 1% and 10%, respectively, having little effect on total CO2 emissions. Among the use of the PCG, CO2 absorption was mostly decided by the CO2 diffusion coefficient and the amount of CO2 absorption by cement paste. The CO2 absorption by carbonation

  17. Absorptive capacity, technological innovation, and product life cycle: a system dynamics model.

    Science.gov (United States)

    Zou, Bo; Guo, Feng; Guo, Jinyu

    2016-01-01

    While past research has recognized the importance of the dynamic nature of absorptive capacity, there is limited knowledge on how to generate a fair and comprehensive analytical framework. Based on interviews with 24 Chinese firms, this study develops a system-dynamics model that incorporates an important feedback loop among absorptive capacity, technological innovation, and product life cycle (PLC). The simulation results reveal that (1) PLC affects the dynamic process of absorptive capacity; (2) the absorptive capacity of a firm peaks in the growth stage of PLC, and (3) the market demand at different PLC stages is the main driving force in firms' technological innovations. This study also explores a sensitivity simulation using the variables of (1) time spent in founding an external knowledge network, (2) research and development period, and (3) knowledge diversity. The sensitivity simulation results show that the changes of these three variables have a greater impact on absorptive capacity and technological innovation during growth and maturity stages than in the introduction and declining stages of PLC. We provide suggestions on how firms can adjust management policies to improve their absorptive capacity and technological innovation performance during different PLC stages.

  18. Optimizing the Environmental Performance of In Situ Thermal Remediation Technologies Using Life Cycle Assessment

    DEFF Research Database (Denmark)

    Lemming, Gitte; Nielsen, Steffen G.; Weber, Klaus

    2013-01-01

    in situ thermal remediation technologies (steam enhanced extraction, thermal conduction heating, electrical resistance heating, and radio frequency heating) in order to (1) compare the life-cycle environmental impacts and resource consumption associated with each thermal technology, and (2) identify...

  19. Using Thermal Infrared Absorption and Emission to Determine Trace Gases

    Science.gov (United States)

    Clerbaux, Cathy; Drummond, James R.; Flaud, Jean-Marie; Orphal, Johannes

    The light emerging from the top of the atmosphere in the greater part of the infrared region is thermal radiation from the Earth's surface. The resultant spectra obtained depend on the temperature difference between the emitting feature and absorbing gas. In this region the greenhouse gases, carbon dioxide, CO2, methane, CH4, ozone, O3, and water, H2O, are observed as well as carbon monoxide, CO, a product indicative of fossil fuel combustion, methanol, CH3OH, from biomass burning, and ammonia, NH3, from agriclulture. Chapter 3 describes the techniques for retrieving atmospheric abundances of these and other species from a number of satellite instruments, and concludes with suggestions for future developments.

  20. SRF Performance of CEBAF After Thermal Cycle to Ambient Temperature

    CERN Document Server

    Rimmer, Robert; Preble, Joseph P; Reece, Charles E

    2005-01-01

    In September 2003, in the wake of Hurricane Isabel, JLab was without power for four days after a tree fell on the main power lines feeding the site. This was long enough to lose insulating vacuum in the cryomodules and cryogenic systems resulting in the whole accelerator warming up and the total loss of the liquid helium inventory. This thermal cycle stressed many of the cryomodule components causing several cavities to become inoperable due to helium to vacuum leaks. At the same time the thermal cycle released years of adsorbed gas from the cold surfaces. Over the next days and weeks this gas was pumped away, the insulating vacuum was restored and the machine was cooled back down and re-commissioned. In a testament to the robustness of SRF technology, only a small loss in energy capability was apparent, although individual cavities had quite different field-emission characteristics compared to before the event. In Summer 2004 a section of the machine was again cycled to room temperature during the long maint...

  1. Development and proof-testing of advanced absorption refrigeration cycle concepts

    Energy Technology Data Exchange (ETDEWEB)

    Modahl, R.J.; Hayes, F.C. (Trane Co., La Crosse, WI (United States). Applied Unitary/Refrigeration Systems Div.)

    1992-03-01

    The overall objectives of this project are to evaluate, develop, and proof-test advanced absorption refrigeration cycles that are applicable to residential and commercial heat pumps for space conditioning. The heat pump system is to be direct-fired with natural gas and is to use absorption working fluids whose properties are known. Target coefficients of performance (COPs) are 1.6 at 47{degrees}F and 1.2 at 17{degrees} in the heating mode, and 0.7 at 95{degree}F in the cooling mode, including the effect of flue losses. The project is divided into three phases. Phase I entailed the analytical evaluation of advanced cycles and included the selection of preferred concepts for further development. Phase II involves the development and testing of critical components and of a complete laboratory breadboard version of the selected system. Phase III calls for the development of a prototype unit and is contingent on the successful completion of Phase II. This report covers Phase I work on the project. In Phase 1, 24 advanced absorption cycle/fluid combinations were evaluated, and computer models were developed to predict system performance. COP, theoretical pump power, and internal heat exchange were calculated for each system, and these calculations were used as indicators of operating and installed costs in order to rank the relative promise of each system. The highest ranking systems involve the cycle concept of absorber/generator heat exchange, generator heat exchanger/absorber heat exchange, regeneration, and resorption/desorption, in combination with the NH{sub 3}/H{sub 2}O/LiBr ternary absorption fluid mixture or with the NH{sub 3}/H{sub 2}O binary solution. Based upon these conclusions, the recommendation was made to proceed to Phase II, the laboratory breadboard proof-of- concept.

  2. Absorptance measurements of transmissive optical components by the surface thermal lensing technique

    Energy Technology Data Exchange (ETDEWEB)

    Chow, R.; Taylor, J.R.; Wu, Z.L.; Han, Y.; Tian, L.Y.

    1997-09-24

    The surface thermal lensing technique (STL) successfully resolved and measured the absorptance of transmissive optical components: near- normal angle-of-incidence anti-reflectors and beam splatters. The STL system uses an Ar ion laser to pump the components at 514.5 mn. The absorptance-induced surface deformation diffracts the HeNe probe beam into a photo-detector. The signal intensity was calibrated with a sample of known absorptance. The optical components were designed to function in a copper vapor laser (CVL) transport system, and were previously tested for absorptance with a high power CVL system at 511 rtm. To assure proper absorptance data from the STL system, the pump laser power densities were set at the operational level of the coatings, absorptance time trends were monitored, and absorptance area scans were made. Both types of transmissive optics are more stable than the CVL high reflectors that were measured in another study. Parameter studies based on Fresnel diffraction theory were also performed to optimize experimental condition. The STL system was assessed to have 10 ppb sensitivity for absorption measurement given 2 W of pump power.

  3. Thermal Cycling of Mir Cooperative Solar Array (MCSA) Test Panels

    Science.gov (United States)

    Hoffman, David J.; Scheiman, David A.

    1997-01-01

    The Mir Cooperative Solar Array (MCSA) project was a joint US/Russian effort to build a photovoltaic (PV) solar array and deliver it to the Russian space station Mir. The MCSA is currently being used to increase the electrical power on Mir and provide PV array performance data in support of Phase 1 of the International Space Station (ISS), which will use arrays based on the same solar cells used in the MCSA. The US supplied the photovoltaic power modules (PPMs) and provided technical and programmatic oversight while Russia provided the array support structures and deployment mechanism and built and tested the array. In order to ensure that there would be no problems with the interface between US and Russian hardware, an accelerated thermal life cycle test was performed at NASA Lewis Research Center on two representative samples of the MCSA. Over an eight-month period (August 1994 - March 1995), two 15-cell MCSA solar array 'mini' panel test articles were simultaneously put through 24,000 thermal cycles (+80 C to -100 C), equivalent to four years on-orbit. The test objectives, facility, procedure and results are described in this paper. Post-test inspection and evaluation revealed no significant degradation in the structural integrity of the test articles and no electrical degradation, not including one cell damaged early as an artifact of the test and removed from consideration. The interesting nature of the performance degradation caused by this one cell, which only occurred at elevated temperatures, is discussed. As a result of this test, changes were made to improve some aspects of the solar cell coupon-to-support frame interface on the flight unit. It was concluded from the results that the integration of the US solar cell modules with the Russian support structure would be able to withstand at least 24,000 thermal cycles (4 years on-orbit).

  4. Thermal cycling characteristics of plasma synthesized mullite films

    Energy Technology Data Exchange (ETDEWEB)

    Monteiro, O.R.; Hou, P.Y.; Brown, I.G. [Lawrence Berkeley National Lab., CA (United States)

    1997-12-01

    The authors have developed a plasma-based technique for the synthesis of mullite and mullite-like films on silicon carbide substrate material. The method, which they refer to as MePIIID (for Metal Plasma Immersion Ion Implantation and Deposition), uses two vacuum arc plasma sources and simultaneous pulse biasing of the substrate in a low pressure oxygen atmosphere. The Al:Si ratio can be controlled via the separate plasma guns, and the film adhesion, structure and morphology can be controlled via the ion energy which in turn is controlled by the pulse bias voltage. The films are amorphous as-deposited, and crystalline mullite is formed by subsequent annealing at 1000 C for 2 hours in air. Adhesion between the aluminum-silicon oxide film and the substrate increases after this first annealing. They have tested the behavior of films when subjected to repetitive thermal cycling between room temperature and 1100 C, and found that the films retain their adhesion and quality. Here they review the plasma synthesis technique and the characteristics of the mullite films prepared in this way, and summarize the status of the thermal cycling experiments.

  5. On the Influence of the Sample Absorptivity when Studying the Thermal Degradation of Materials

    Directory of Open Access Journals (Sweden)

    Pascal Boulet

    2015-08-01

    Full Text Available The change in absorptivity during the degradation process of materials is discussed, and its influence as one of the involved parameters in the degradation models is studied. Three materials with very different behaviors are used for the demonstration of its role: a carbon composite material, which is opaque, almost grey, a plywood slab, which is opaque and spectral-dependent and a clear PMMA slab, which is semitransparent. Data are analyzed for virgin and degraded materials at different steps of thermal degradation. It is seen that absorptivity and emissivity often reach high values in the range of 0.90–0.95 with a near-grey behavior after significant thermal aggression, but depending on the materials of interest, some significant evolution may be first observed, especially during the early stages of the degradation. Supplementary inaccuracy can come from the heterogeneity of the incident flux on the slab. As a whole, discrepancies up to 20% can be observed on the absorbed flux depending on the degradation time, mainly because of the spectral variations of the absorption and up to 10% more, depending on the position on the slab. Simple models with a constant and unique value of absorptivity may then lead to inaccuracies in the evaluation of the radiative flux absorption, with possible consequences on the pyrolysis analysis, especially for properties related to the early step of the degradation process, like the time to ignition, for example.

  6. On the Influence of the Sample Absorptivity when Studying the Thermal Degradation of Materials.

    Science.gov (United States)

    Boulet, Pascal; Brissinger, Damien; Collin, Anthony; Acem, Zoubir; Parent, Gilles

    2015-08-21

    The change in absorptivity during the degradation process of materials is discussed, and its influence as one of the involved parameters in the degradation models is studied. Three materials with very different behaviors are used for the demonstration of its role: a carbon composite material, which is opaque, almost grey, a plywood slab, which is opaque and spectral-dependent and a clear PMMA slab, which is semitransparent. Data are analyzed for virgin and degraded materials at different steps of thermal degradation. It is seen that absorptivity and emissivity often reach high values in the range of 0.90-0.95 with a near-grey behavior after significant thermal aggression, but depending on the materials of interest, some significant evolution may be first observed, especially during the early stages of the degradation. Supplementary inaccuracy can come from the heterogeneity of the incident flux on the slab. As a whole, discrepancies up to 20% can be observed on the absorbed flux depending on the degradation time, mainly because of the spectral variations of the absorption and up to 10% more, depending on the position on the slab. Simple models with a constant and unique value of absorptivity may then lead to inaccuracies in the evaluation of the radiative flux absorption, with possible consequences on the pyrolysis analysis, especially for properties related to the early step of the degradation process, like the time to ignition, for example.

  7. Diaryl-substituted norbornadienes with red-shifted absorption for molecular solar thermal energy storage.

    Science.gov (United States)

    Gray, Victor; Lennartson, Anders; Ratanalert, Phasin; Börjesson, Karl; Moth-Poulsen, Kasper

    2014-05-25

    Red-shifting the absorption of norbornadienes (NBDs), into the visible region, enables the photo-isomerization of NBDs to quadricyclanes (QCs) to be driven by sunlight. This is necessary in order to utilize the NBD-QC system for molecular solar thermal (MOST) energy storage. Reported here is a study on five diaryl-substituted norbornadienes. The introduced aryl-groups induce a significant red-shift of the UV/vis absorption spectrum of the norbornadienes, and device experiments using a solar-simulator set-up demonstrate the potential use of these compounds for MOST energy storage.

  8. Simulated Solar Flare X-Ray and Thermal Cycling Durability Evaluation of Hubble Space Telescope Thermal Control Candidate Replacement Materials

    Science.gov (United States)

    deGroh, Kim K.; Banks, Bruce A.; Sechkar, Edward A.; Scheiman, David A.

    1998-01-01

    During the Hubble Space Telescope (HST) second servicing mission (SM2), astronauts noticed that the multilayer insulation (MLI) covering the telescope was damaged. Large pieces of the outer layer of MLI (aluminized Teflon fluorinated ethylene propylene (Al-FEP)) were torn in several locations around the telescope. A piece of curled up Al-FEP was retrieved by the astronauts and was found to be severely embrittled, as witnessed by ground testing. Goddard Space Flight Center (GSFC) organized a HST MLI Failure Review Board (FRB) to determine the damage mechanism of FEP in the HST environment, and to recommend replacement insulation material to be installed on HST during the third servicing mission (SM3) in 1999. Candidate thermal control replacement materials were chosen by the FRB and tested for environmental durability under various exposures and durations. This paper describes durability testing of candidate materials which were exposed to charged particle radiation, simulated solar flare x-ray radiation and thermal cycling under load. Samples were evaluated for changes in solar absorptance and tear resistance. Descriptions of environmental exposures and durability evaluations of these materials are presented.

  9. Thermal changes in the absorption spectra of blood with supravascular infrared laser irradiation in vivo

    Science.gov (United States)

    Zalesskaya, G. A.; Astaf'eva, L. G.; Batai, L. E.

    2011-09-01

    We have studied the effect of laser radiation (λ = 1960 nm, power density from 6 to 25 W/cm2) on the absorption spectra of rat blood with supravascular irradiation. We have established that absorption of laser radiation leads to a decrease in the degree of oxygen saturation of mixed venous blood due to its heating. We have estimated the initial heating temperatures of venous blood and the surface of the irradiated tissue using an optothermal model, taking into account the characteristics of the laser radiation and the optical and thermal characteristics of the biological tissue. We consider the effect of radiation-induced thermal dissociation of oxyhemoglobin on the oxygen transport characteristics of the blood and metabolic processes.

  10. A LiBr-H2O Absorption Refrigerator Incorporating a Thermally Activated Solution Pumping Mechanism

    OpenAIRE

    Ian W. Eames

    2017-01-01

    This paper provides an illustrated description of a proposed LiBr-H2O vapour absorption refrigerator which uses a thermally activated solution pumping mechanism that combines controlled variations in generator vapour pressure with changes it produces in static-head pressure difference to circulate the absorbent solution between the generator and absorber vessels. The proposed system is different and potentially more efficient than a bubble pump system previously proposed and avoids the need f...

  11. Experimental modeling of weld thermal cycle of the heat affected zone (HAZ

    Directory of Open Access Journals (Sweden)

    J. Kulhánek

    2016-10-01

    Full Text Available Contribution deals with experimental modeling of quick thermal cycles of metal specimens. In the introduction of contribution will be presented measured graphs of thermal cycle of heat affected zone (HAZ of weld. Next will be presented experimental simulation of measured thermal cycle on the standard specimens, useable for material testing. This approach makes possible to create material structures of heat affected zone of weld, big enough for standard material testing.

  12. Thermal stability, swelling behavior and CO 2 absorption properties of Nanoscale Ionic Materials (NIMs)

    KAUST Repository

    Andrew Lin, Kun-Yi

    2014-11-11

    © The Royal Society of Chemistry 2015. Nanoscale Ionic Materials (NIMs) consist of a nanoscale core, a corona of charged brushes tethered on the surface of the core, and a canopy of the oppositely charged species linked to the corona. Unlike conventional polymeric nanocomposites, NIMs can display liquid-like behavior in the absence of solvents, have a negligible vapor pressure and exhibit unique solvation properties. These features enable NIMs to be a promising CO2 capture material. To optimize NIMs for CO2 capture, their structure-property relationships were examined by investigating the roles of the canopy and the core in their thermal stability, and thermally- and CO2-induced swelling behaviors. NIMs with different canopy sizes and core fractions were synthesized and their thermal stability as well as thermally- and CO2-induced swelling behaviors were determined using thermogravimetry, and ATR FT-IR and Raman spectroscopies. It was found that the ionic bonds between the canopy and the corona, as well as covalent bonds between the corona and the core significantly improved the thermal stability compared to pure polymer and polymer/nanofiller mixtures. A smaller canopy size and a larger core fraction led to a greater enhancement in thermal stability. This thermal stability enhancement was responsible for the long-term thermal stability of NIMs over 100 temperature swing cycles. Owing to their ordered structure, NIMs swelled less when heated or when they adsorbed CO2 compared to their corresponding polymers. This journal is

  13. Geosynthetic clay liners shrinkage under simulated daily thermal cycles.

    Science.gov (United States)

    Sarabadani, Hamid; Rayhani, Mohammad T

    2014-06-01

    Geosynthetic clay liners are used as part of composite liner systems in municipal solid waste landfills and other applications to restrict the escape of contaminants into the surrounding environment. This is attainable provided that the geosynthetic clay liner panels continuously cover the subsoil. Previous case histories, however, have shown that some geosynthetic clay liner panels are prone to significant shrinkage and separation when an overlying geomembrane is exposed to solar radiation. Experimental models were initiated to evaluate the potential shrinkage of different geosynthetic clay liner products placed over sand and clay subsoils, subjected to simulated daily thermal cycles (60°C for 8 hours and 22°C for 16 hours) modelling field conditions in which the liner is exposed to solar radiation. The variation of geosynthetic clay liner shrinkage was evaluated at specified times by a photogrammetry technique. The manufacturing techniques, the initial moisture content, and the aspect ratio (ratio of length to width) of the geosynthetic clay liner were found to considerably affect the shrinkage of geosynthetic clay liners. The particle size distribution of the subsoil and the associated suction at the geosynthetic clay liner-subsoil interface was also found to have significant effects on the shrinkage of the geosynthetic clay liner. © The Author(s) 2014.

  14. Weldability prediction of high strength steel S960QL after weld thermal cycle simulation

    Directory of Open Access Journals (Sweden)

    M. Dunđer

    2014-10-01

    Full Text Available This paper presents weld thermal cycle simulation of high strength steel S960QL, and describes influence of cooling time t8/5 on hardness and impact toughness of weld thermal cycle simulated specimens. Furthermore, it presents analysis of characteristic fractions done by electron scanning microscope which can contribute to determination of welding parameters for S960QL steel.

  15. How Thermal Fatigue Cycles Change the Rheological Behavior of Polymer Modified Bitumen?

    NARCIS (Netherlands)

    Glaoui, B.; Merbouh, M.; Van de Ven, M.F.C.; Chailleux, E.; Youcefi, A.

    2013-01-01

    The paper deals with the problem of thermal fatigue cycles phenomenon, which affects the performance of flexible pavement. The purpose of the paper is to extent the knowledge on the rheology of polymer modified bitumen which was affected by cycles of thermal fatigue. The aim of this research is to

  16. Theoretical Simulation of 87Rb Absorption Spectrum in a Thermal Cell

    CERN Document Server

    Cheng, Hong; Xin, Pei-Pei; Yuan, Cheng; Liu, Hong-Ping

    2016-01-01

    In this paper, we present a theoretical simulation of 87Rb absorption spectrum in a thermal cm-cell which is adaptive to the experimental observation. In experiment, the coupling and probe beams are configured to copropagate but perpendicular polarized, making up to five velocity selective optical pumping (VSOP) absorption dips able to be identified. A $\\Lambda$-type electromagnetically induced transparency (EIT) is also observed for each group of velocity-selected atoms. The spectrum by only sweeping the probe beam can be decomposed into a combination of Doppler-broadened background and three VSOP dips for each group of velocity-selected atoms, companied by an EIT peak. This proposed theoretical model can be used to simulate the spectrum adaptive to the experimental observation by non-linear least-square fit method. The fit for high quality of experimental observation can determine valuable transition parameters such as decaying rates and coupling beam power accurately.

  17. Rapid thermal cycling of metal-supported solid oxide fuel cellmembranes

    Energy Technology Data Exchange (ETDEWEB)

    Matus, Yuriy B.; De Jonghe, Lutgard C.; Jacobson, Craig P.; Visco, Steven J.

    2004-01-02

    Solid oxide fuel cell (SOFC) membranes were developed in which zirconia-based electrolyte thin films were supported by a composite metal/ceramic electrode, and were subjected to rapid thermal cycling between 200 and 800 C. The effects of this cycling on membrane performance were evaluated. The membranes, not yet optimized for performance, showed a peak power density of 350mW/cm2at 900 C in laboratory-sized SOFCs that was not affected by the thermal cycling. This resistance to cycling degradation is attributed to the close matching of thermal expansion coefficient of the cermet support electrode with that of the zirconia electrolyte.

  18. Modelling and Improvement of Thermal Cycling in Power Electronics for Motor Drive Applications

    DEFF Research Database (Denmark)

    Vernica, Ionut; Ma, Ke; Blaabjerg, Frede

    2016-01-01

    cycling of power devices in a motor drive application and modelling their impact on the thermal stress. The motor drive system together with the thermal cycling in the power semiconductors have been modelled, and after investigating the dynamic behavior of the system, adverse temperature swings......It is well known that the dynamical change of the thermal stress in the power devices is one of the major factors that have influences on the overall efficiency and reliability of power electronics. The main objective of this paper consists of identifying the main parameters that affect the thermal...... are identified during the acceleration and deceleration periods of the motor. The main causes for these adverse thermal cycles have been presented and, consequently, the influence of the deceleration slope, modulation technique and reactive current on the thermal cycles has been analyzed. Finally, the improved...

  19. Effect of drying method on mechanical, thermal and water absorption properties of enzymatically crosslinked gelatin hydrogels

    Directory of Open Access Journals (Sweden)

    RAYSSA C. SIMONI

    Full Text Available ABSTRACT Enzymatically crossliked gelatin hydrogel was submitted to two different drying methods: air drying and freeze drying. The resulting polymeric tridimensional arrangement (compact or porous, respectively led to different thermal and swelling properties. Significant differences (p < 0.05 on thermal and mechanical characteristics as well as swelling in non-enzymatic gastric and intestinal simulated fluids (37 ºC were detected. Water absorption data in such media was modelled according to Higuchi, Korsmeyer-Peppas, and Peppas-Sahlin equations. Freeze dried hydrogel showed Fickian diffusion behavior while air dried hydrogels presented poor adjustment to Higuchi model suggesting the importance of the relaxation mechanism at the beginning of swelling process. It was possible to conclude that the same gelatin hydrogel may be suitable to different applications depending on the drying process used.

  20. Flexible thermal cycle test equipment for concentrator solar cells

    Science.gov (United States)

    Hebert, Peter H [Glendale, CA; Brandt, Randolph J [Palmdale, CA

    2012-06-19

    A system and method for performing thermal stress testing of photovoltaic solar cells is presented. The system and method allows rapid testing of photovoltaic solar cells under controllable thermal conditions. The system and method presents a means of rapidly applying thermal stresses to one or more photovoltaic solar cells in a consistent and repeatable manner.

  1. Economic optimization of a Kalina cycle for a parabolic trough solar thermal power plant

    DEFF Research Database (Denmark)

    Modi, Anish; Kærn, Martin Ryhl; Andreasen, J. G.

    2015-01-01

    technology for the conversion of solar thermal energy into electricity. In this paper, a Kalina cycle and a steam Rankine cycle are compared in terms of the total capital investment cost for use in a parabolic trough solar thermal power plant without storage. In order to minimize the total capital investment...... cost of the Kalina cycle power plant (the solar field plus the power cycle), an optimization was performed by varying the turbine outlet pressure, the separator inlet temperature and the separator inlet ammonia mass fraction. All the heat exchangers were modelled as shell and tube type using suitable......The Kalina cycle has recently seen increased interest as a replacement for the more traditional steam Rankine cycle for geothermal, solar, ocean thermal energy conversion and waste heat recovery applications. The Kalina cycle uses a mixture of ammonia and water as the working fluid. The ammonia...

  2. Modelling the absorption refrigeration cycle using partially miscible working fluids by group contribution methods

    Science.gov (United States)

    Larkeche, O.; Meniai, A.-H.; Cachot, T.

    2012-06-01

    The present study concerns the cycle performance modelling of a particular configuration of an absorption refrigeration machine based on phase separation as well as development of a strategy for computer aided design of absorbents. The model uses predictive methods based on the group contribution concept for the computation of the thermodynamic phase equilibria involved such as liquid-liquid and vapour-liquid as well as enthalpy-concentration diagrams. The proposed absorbents computer-aided design strategy is based on the exploration of a number of structural group combinations obtained from a selected set of functional groups, according to the chemistry laws. The model was tested on four different absorbent-refrigerant pairs reported in the literature, namely (benzyl ethyl amine-glycerol), (water-hexanoic acid), (water-2-hexanone) and (water-ethyl propionate) as well as on pairs where the absorbent compound is generated by the proposed absorbent design strategy and the refrigerant is water. The results show that quite good values of the coefficient of performance (COP) can be obtained, indicating that this cycle configuration is promising and energetically efficient, mainly due to hardware savings, i.e. absence of condenser. However, other working fluid combinations have to be tested using the proposed model.

  3. The effects of deep water cycling on planetary thermal evolution

    Science.gov (United States)

    Sandu, Constantin; Lenardic, Adrian; McGovern, Patrick

    2011-12-01

    We use a parameterized convection model to investigate the effects of deep water cycling on the thermal evolution of an Earth-like planet. The model incorporates two water reservoirs, a surface and an interior mantle reservoir. Exchange between the two is calculated using a mantle convection parameterization that allows for temperature- and water-dependent mantle viscosity together with internally self-consistent degassing and regassing parameterizations. The balance between degassing and regassing depends on the average spreading rate of tectonic plates, the amount of water partitioned into melt, the thickness of a mantle melt zone, and of a hydrated layer at the top of subducting plates. Degassing scales with melt zone thickness such that an early period of extensive melting would create a drier and more viscous mantle, shifting the solidus line in a direction that would reduce the melt zone thickness and the rate of mantle heat loss. Coupling a hydrated zone thickness-dependent regassing factor to the model, to mimic water delivery to the mantle via a serpentinized layer, allows for the potential of a reversing point where the overall water flow direction switches from degassing to regassing as the mantle cools. The water effect on viscosity creates a negative feedback that tends to regulate the final amount of water in the mantle so it is not strongly dependent on the initial amount of planetary water. The final amount of water in the surface reservoir is then determined by this feedback effect together with the initial water budget of the entire planet. This implies that if the initial water budget of a planet can be estimated, from planetary formation models, then the volume of surface water can be used to estimate the volume of water in the mantle of an Earth-like planet. Applying this methodology to the Earth leads to predictions for water concentration in the Earth's mantle that are in line with geochemical and petrological constraints.

  4. Degradation of Teflon(trademark) FEP Following Charged Particle Radiation and Rapid Thermal Cycling

    Science.gov (United States)

    Townsend, Jacqueline; Powers, Charles; Viens, Michael; Ayres-Treusdell, Mary; Munoz, Bruno

    1999-01-01

    During the Second Servicing Mission (SM2) of the Hubble Space Telescope (HST) severe degradation was observed on the outer layer of the thermal control blankets. Astronaut observations and photographs revealed large cracks in the metallized Teflon(trademark) FEP (fluorinated ethylene propylene), the outer layer of the multi-layer insulation (MLI), in many locations around the telescope. In an effort to understand what elements of the space environment might cause such damage, pristine Teflon(trademark) FEP was tested for durability to radiation and thermal cycling. Specimens were subjected to electron and proton fluences comparable to those experienced by HST and were subsequently thermal cycled in a custom-built rapid thermal cycle chamber. Tensile tests of the specimens showed that radiation followed by thermal cycling significantly reduced the ultimate strength and elongation of Teflon(trademark) FEP.

  5. Degradation of Teflon(tm) FEP Following Charged Particle Radiation and Rapid Thermal Cycling

    Science.gov (United States)

    Townsend, Jacqueline; Powers, Charles; Viens, Michael; Ayres-Treusdell, Mary; Munoz, Bruno

    1998-01-01

    During the Second Servicing Mission (SM2) of the Hubble Space Telescope (HST) severe degradation was observed on the outer layer of the thermal control blankets. Astronaut observations and photographs revealed large cracks in the metallized Teflon(R) FEP (fluorinated ethylene propylene), the outer layer of the multi-layer insulation (MLI), in many locations around the telescope. In an effort to understand what elements of the space environment might cause such damage, pristine Teflon(R) FEP was tested for durability to radiation and thermal cycling. Specimens were subjected to electron and proton fluences comparable to those experienced by HST and were subsequently thermal cycled in a custom-built rapid thermal cycle chamber. Tensile tests of the specimens showed that radiation followed by thermal cycling significantly reduced the ultimate strength and elongation of Teflon(R) FEP.

  6. Thermal cycling tests of actively cooled beryllium copper joints

    Energy Technology Data Exchange (ETDEWEB)

    Roedig, M.; Duwe, R.; Linke, J.; Schuster, A.; Wiechers, B. [Forschungszentrum Juelich GmbH (Germany)

    1998-01-01

    Screening tests (steady state heating) and thermal fatigue tests with several kinds of beryllium-copper joints have been performed in an electron beam facility. Joining techniques under investigation were brazing with silver containing and silver-free braze materials, hot isostatic pressing (HIP) and diffusion bonding (hot pressing). Best thermal fatigue performance was found for the brazed samples. (author)

  7. To What Degree Thermal Cycles Affect Chalk Strength

    DEFF Research Database (Denmark)

    Livada, Tijana; Nermoen, Anders; Korsnes, Reidar Inger

    and water saturated chalk. Sixty disks of dry Kansas chalk exposed to different number of temperature cycles were tested for tensile strength using a Brazilian test. Changes in elastic properties as function of number of temperature cycles of the same chalk, but now saturated in water, were studied using...... triaxial cell experiments. For dry rock, no significant effects of temperature cycling was found on average tensile strength, however the range of the tensile failure stress is doubled for the samples exposed to 50 temperature cycles, as opposed to those to none. For water saturated cores, the temperature...

  8. Thermodynamics of the CO2–Absorption/Desorption Section in the Integrated Gasifying Combined Cycle — I. modeling

    Directory of Open Access Journals (Sweden)

    Jaroslav KOZACZKA

    2012-06-01

    Full Text Available The carbon dioxide absorption/desorption unit of the Integrated Gasifying Combined Cycle has been detailed described to formulate appropriate model equations for the processes, suitable for further thermodynamic analyzes. There are two principal technologies of the CO2–removing section, namely the absorption with the following expanding desorption process, and the absorption with the following classical plates (or packing desorption one. The physics of thermodynamic properties of the water/carbon dioxide solution have been presented thoroughly using hitherto literature data. The Henry's Law has been emphasized as the base for further thermodynamic analyzes. The numerical results of appropriate absorption/desorption units have been compiled presuming fundamental relations, which are also presented. They should be the base for their thermodynamic analyzes.

  9. Effect of Thermal Cycling on the Tensile Behavior of CF/AL Fiber Metal Laminates

    Directory of Open Access Journals (Sweden)

    Muhammad Farhan Noor

    2017-09-01

    Full Text Available The objective of this research work was to estimate the effect of thermal cycling on the tensile behavior of CARALL composites. Fiber metal laminates (FMLs, based on 2D woven carbon fabric and 2024-T3 Alclad aluminum alloy sheet, was manufactured by pressure molding technique followed by hand layup method. Before fabrication, aluminum sheets were anodized with phosphoric acid to produce micro porous alumina layer on surface. This micro-porous layer is beneficial to produce strong bonding between metal and fiber surfaces in FMLs. The effect of thermal cycling (-65 to +70ºC on the tensile behavior of Cf/Al based FML was studied. Tensile strength was increased after 10 thermal cycles, but it was slightly decreased to some extent after 30, and 50 thermal cycles. Tensile modulus also shown the similar behavior as that of tensile strength.

  10. Influence of micro-structural parameters and thermal cycling on the ...

    Indian Academy of Sciences (India)

    Keywords. Ultra high performance fibre reinforced cement-based composite; CARDIFRC; micro-structure; mechanical and fracture properties; thermal cycling. ... Author Affiliations. B L Karihaloo1. School of Engineering, Cardiff University, Cardiff, UK ...

  11. Shock tube study on the thermal decomposition of fluoroethane using infrared laser absorption detection of hydrogen fluoride.

    Science.gov (United States)

    Matsugi, Akira; Shiina, Hiroumi

    2014-08-28

    Motivated by recent shock tube studies on the thermal unimolecular decomposition of fluoroethanes, in which unusual trends have been reported for collisional energy-transfer parameters, the rate constants for the thermal decomposition of fluoroethane were investigated using a shock tube/laser absorption spectroscopy technique. The rate constants were measured behind reflected shock waves by monitoring the formation of HF by IR absorption at the R(1) transition in the fundamental vibrational band near 2476 nm using a distributed-feedback diode laser. The peak absorption cross sections of this absorption line have also been determined and parametrized using the Rautian-Sobel'man line shape function. The rate constant measurements covered a wide temperature range of 1018-1710 K at pressures from 100 to 290 kPa, and the derived rate constants were successfully reproduced by the master equation calculation with an average downward energy transfer, ⟨ΔEdown⟩, of 400 cm(-1).

  12. The Effects of Thermal Cycling on Gallium Nitride and Silicon Carbide Semiconductor Devices for Aerospace Use

    Science.gov (United States)

    Patterson, Richard L.; Hammoud, Ahmad

    2012-01-01

    Electronics designed for use in NASA space missions are required to work efficiently and reliably under harsh environment conditions. These Include radiation, extreme temperatures, thermal cycling, to name a few. Preliminary data obtained on new Gallium Nitride and Silicon Carbide power devices under exposure to radiation followed by long term thermal cycling are presented. This work was done in collaboration with GSFC and JPL in support of the NASA Electronic Parts and Packaging (NEPP) Program

  13. Models for optimum thermo-ecological criteria of actual thermal cycles

    Directory of Open Access Journals (Sweden)

    Açikkalp Emin

    2013-01-01

    Full Text Available In this study, the ecological optimization point of irreversible thermal cycles (refrigerator, heat pump and power cycles was investigated. The importance of ecological optimization is to propose a way to use fuels and energy source more efficiently because of an increasing energy need and environmental pollution. It provides this by maximizing obtained (or minimizing supplied work and minimizing entropy generation for irreversible (actual thermal cycles. In this research, ecological optimization was defined for all basic irreversible thermal cycles, by using the first and second laws of thermodynamics. Finally, the ecological optimization was defined in thermodynamic cycles and results were given to show the effects of the cycles’ ecological optimization point, efficiency, COP and power output (or input, and exergy destruction.

  14. Quantum Performance of Thermal Machines over Many Cycles

    Science.gov (United States)

    Watanabe, Gentaro; Venkatesh, B. Prasanna; Talkner, Peter; del Campo, Adolfo

    2017-02-01

    The performance of quantum heat engines is generally based on the analysis of a single cycle. We challenge this approach by showing that the total work performed by a quantum engine need not be proportional to the number of cycles. Furthermore, optimizing the engine over multiple cycles leads to the identification of scenarios with a quantum enhancement. We demonstrate our findings with a quantum Otto engine based on a two-level system as the working substance that supplies power to an external oscillator.

  15. Quantum Performance of Thermal Machines over Many Cycles.

    Science.gov (United States)

    Watanabe, Gentaro; Venkatesh, B Prasanna; Talkner, Peter; Del Campo, Adolfo

    2017-02-03

    The performance of quantum heat engines is generally based on the analysis of a single cycle. We challenge this approach by showing that the total work performed by a quantum engine need not be proportional to the number of cycles. Furthermore, optimizing the engine over multiple cycles leads to the identification of scenarios with a quantum enhancement. We demonstrate our findings with a quantum Otto engine based on a two-level system as the working substance that supplies power to an external oscillator.

  16. Thermal properties, curing characteristics and water absorption of soybean oil-based thermoset

    Directory of Open Access Journals (Sweden)

    2011-06-01

    Full Text Available Epoxidized soybean oil (ESO was successfully thermal-cured by using methylhexahydrophthalic anhydride (MHHPA curing agent, in the presence of tetraethylammonium bromide (TEAB catalyst of varied concentration (0.3–0.8 phr. The polyesterification process of ESO thermoset was proven and supported by Fourier transforms infrared spectroscopy (FTIR and gas chromatography-mass spectroscopy analysis (GC-MS. A possible chemical reaction of the MHHPA, TEAB and ESO was proposed based on the experimental work. Differential scanning calorimetry (DSC and dynamic mechanical analysis (DMA revealed that there is a positive relationship between the degree of conversion and crosslink density of ESO thermoset with TEAB concentration. The kinetics of water absorption of the ESO thermoset were found to conform to Fickian law behavior.

  17. Simulating Thermal Cycling and Isothermal Deformation Response of Polycrystalline NiTi

    Science.gov (United States)

    Manchiraju, Sivom; Gaydosh, Darrell J.; Noebe, Ronald D.; Anderson, Peter M.

    2011-01-01

    A microstructure-based FEM model that couples crystal plasticity, crystallographic descriptions of the B2-B19' martensitic phase transformation, and anisotropic elasticity is used to simulate thermal cycling and isothermal deformation in polycrystalline NiTi (49.9at% Ni). The model inputs include anisotropic elastic properties, polycrystalline texture, DSC data, and a subset of isothermal deformation and load-biased thermal cycling data. A key experimental trend is captured.namely, the transformation strain during thermal cycling is predicted to reach a peak with increasing bias stress, due to the onset of plasticity at larger bias stress. Plasticity induces internal stress that affects both thermal cycling and isothermal deformation responses. Affected thermal cycling features include hysteretic width, two-way shape memory effect, and evolution of texture with increasing bias stress. Affected isothermal deformation features include increased hardening during loading and retained martensite after unloading. These trends are not captured by microstructural models that lack plasticity, nor are they all captured in a robust manner by phenomenological approaches. Despite this advance in microstructural modeling, quantitative differences exist, such as underprediction of open loop strain during thermal cycling.

  18. Infrared absorption spectroscopy of carbon monoxide on nickel films: a low temperature thermal detection technique

    Energy Technology Data Exchange (ETDEWEB)

    Bailey, R.B.

    1978-11-01

    Sensitive vibrational spectra of carbon monoxide molecules adsorbed on evaporated nickel films have been measured by attaching a thermometer to the sample, cooling the assembly to liquid helium temperatures, and recording the temperature changes which occur when infrared radiation is absorbed. The measurements are made in an ultrahigh vacuum chamber in which the sample surface can be cleaned, heated, exposed to gas molecules and cooled to 1.6 K for the infrared measurements. The spectra of chemisorbed CO molecules are interpreted in terms of the linear and bridge adsorption sites on the nickel surface, and they show how the distribution of molecules among these sites changes when the CO coverage increases and intermolecular forces become important. The spectra of physically adsorbed molecules in both monolayer and multilayer films are also reported. Absorptions as small as five parts in 10/sup 5/ of the incident radiation can presently be detected in spectra covering broad bands of infrared frequencies with a resolution of 2 cm/sup -1/. This high sensitivity is attributable to the low noise and reduced background signal of the thermal detection scheme, to the stability of the rapid scan Fourier transform infrared spectrometer, and to the automated computerized data acquisition electronics. Better performance is expected in future experiments on single crystal samples as well as evaporated films. This will make it possible to study molecules with weaker absorptions than CO and to look for evidence of chemical reactions between different adsorbed molecules.

  19. Transient light-induced absorption in thermally reduced, periodically poled lithium niobate doped with yttrium

    Energy Technology Data Exchange (ETDEWEB)

    Schoke, Bettina; Imlau, Mirco [Physics Department, University of Osnabrueck (Germany); Merschjann, Christoph [Helmholtz-Zentrum GmbH, Berlin (Germany); Corradi, Garbor; Polgar, Katalin [Research Institute for Solid State Physics and Optics, Hungarian Academy of Sciences, Budapest (Hungary); Naumova, Inna [Physics Department, Moscow State University (Russian Federation)

    2010-07-01

    Excitation and recombination processes of small polarons are studied in thermally reduced, periodically poled LiNbO{sub 3} doped with Y (PPLN:Y). The reduction treatment creates bipolarons (Nb{sup 4+}{sub Li}:Nb{sup 4+}{sub Nb}) which are stable at room temperature. They may be dissociated optically into small bound (Nb{sub Li}{sup 4+}) and free (Nb{sub Nb}{sup 4+}) polarons (''optical gating''). The light-induced absorption arising from the population and depopulation of these centers is measured time-resolved via transient absorption spectroscopy in the blue and red spectral range after optical excitation with intense laser pulses ({lambda}=532 nm, t=8 ns). Besides dissociation and relaxation of bipolarons the investigations also indicate the presence of photo-induced hole polarons (O{sup -}) with comparatively longer lifetime. The findings can be explained by a periodic spatial modulation of the Nb{sub Li}{sup 5+} antisite concentration and of the degree of reduction. Both modulations most likely result from a periodic incorporation of Y ions on Li sites.

  20. Experimental investigation of high cycle thermal fatigue in a T-junction piping system

    Energy Technology Data Exchange (ETDEWEB)

    Selvam, P. Karthick; Kulenovic, Rudi; Laurien, Eckart [Stuttgart Univ. (Germany). Inst. of Nuclear Technology and Energy Systems (IKE)

    2015-10-15

    High cycle thermal fatigue damage of structure in the vicinity of T-junction piping systems in nuclear power plants is of importance. Mixing of coolant streams at significant temperature differences causes thermal fluctuations near piping wall leading to gradual thermal degradation. Flow mixing in a T-junction is performed. The determined factors result in bending stresses being imposed on the piping system ('Banana effect').

  1. Studies of Microwave Absorption in Liquids by Optical Heterodyne Detection of Thermally Induced Refractive Index Fluctuations.

    Science.gov (United States)

    Swicord, Mays Littleton

    This work describes the development and implementation of an optical detection method for determining the microwave absorption properties of liquids and liquid suspensions. The method employs a Mach-Zehnder interferometer illuminated with a single-frequency laser to detect fluctuations in the index of refraction of a transparent or semi-transparent substance placed in one arm of the interferometer. The fluctuations are induced by pulses of microwave energy which are introduced into the sample by a specially designed waveguide sample holder. The laser beams from the sample and reference arms of the interferometer recombine on a photodetector resulting in a heterodyne signal. This general method is called Phase Fluctuation Optical Heterodyne (PFLOH) spectroscopy. The method is theoretically capable of detecting refractive index changes of two parts in 10('12) in liquids with greater sensitivity for gases; however, experimental performance is somewhat more limited. Although there is an abundance of microwave spectroscopy literature, virtually all of it is devoted to the absorption properties of gases. There are two reasons for the lack of information on nongaseous substances. First, methods most commonly used on gases, such as absorption ratio methods, are not practical for liquids in this frequency range due to the difficulties of making accurate microwave measurements. PFLOH spectroscopy avoids this difficulty. Second, fine structure (or anomalous dispersion) in the microwave absorption spectra of liquids has been considered nonexistant or at best uninteresting. This level of interest is changing, however, due to possible biological effects of microwave radiation. A number of different types of biological responses have recently been observed and reported in animals exposed to microwave radiation. Some of these effects are clearly responses of the organism to increased local or whole body temperature levels. In some cases the response is not so clearly thermal in

  2. Thermodynamics of the CO2–Absorption/Desorption Section in the Integrated Gasifying Combined cycle — II. Analysis

    Directory of Open Access Journals (Sweden)

    Jaroslav KOZACZKA

    2012-06-01

    Full Text Available The thermodynamic analysis of the absorption/desorption section of the ICGC–cycle has been presented using the Second Law with special emphasis on the thermodynamic effectivity concept and usability for complex systems investigations. Essential problems have been discussed based on the classical bibliographical items on the subject. Numerical calculations have been accomplished using results obtained in the first part, which contained absorption and desorption modeling approach oriented onto thermodynamic analyzes. Additionally the special properties of dilute solutions, especially the CO2/water system, have been presented and the problem of the solute chemical concentration exergy change suggested.

  3. Determination of Scattering and Absorption Coefficients for Plasma-Sprayed Yttria-Stabilized Zirconia Thermal Barrier Coatings at Elevated Temperatures

    Science.gov (United States)

    Eldridge, Jeffrey I.; Spuckler, Charles M.; Markham, James R.

    2009-01-01

    The temperature dependence of the scattering and absorption coefficients for a set of freestanding plasma-sprayed 8 wt% yttria-stabilized zirconia (8YSZ) thermal barrier coatings (TBCs) was determined at temperatures up to 1360 C in a wavelength range from 1.2 micrometers up to the 8YSZ absorption edge. The scattering and absorption coefficients were determined by fitting the directional-hemispherical reflectance and transmittance values calculated by a four-flux Kubelka Munk method to the experimentally measured hemispherical-directional reflectance and transmittance values obtained for five 8YSZ thicknesses. The scattering coefficient exhibited a continuous decrease with increasing wavelength and showed no significant temperature dependence. The scattering is primarily attributed to the relatively temperature-insensitive refractive index mismatch between the 8YSZ and its internal voids. The absorption coefficient was very low (less than 1 per centimeter) at wavelengths between 2 micrometers and the absorption edge and showed a definite temperature dependence that consisted of a shift of the absorption edge to shorter wavelengths and an increase in the weak absorption below the absorption edge with increasing temperature. The shift in the absorption edge with temperature is attributed to strongly temperature-dependent multiphonon absorption. While TBC hemispherical transmittance beyond the absorption edge can be predicted by a simple exponential decrease with thickness, below the absorption edge, typical TBC thicknesses are well below the thickness range where a simple exponential decrease in hemispherical transmittance with TBC thickness is expected. [Correction added after online publication August 11, 2009: "edge to a shorter wavelengths" has been updated as edge to shorter wavelengths."

  4. The determination of kinetic parameters of LiF : Mg,Ti from thermal decaying curves of optical absorption bands

    CERN Document Server

    Yazici, A N

    2003-01-01

    In this paper, the thermal bleaching curves (TBCs) of specific optical absorption bands of LiF : Mg,Ti were measured as a function of temperature. The TBCs obtained were analysed to extract the kinetic parameters (the thermal activation energy (E) and the frequency factor (s)) of some TL glow peaks of LiF : Mg,Ti on the basis of the developed first-order kinetic model over a specified temperature region.

  5. Efficient cycles for carbon capture CLC power plants based on thermally balanced redox reactors

    KAUST Repository

    Iloeje, Chukwunwike

    2015-10-01

    © 2015 Elsevier Ltd. The rotary reactor differs from most alternative chemical looping combustion (CLC) reactor designs because it maintains near-thermal equilibrium between the two stages of the redox process by thermally coupling channels undergoing oxidation and reduction. An earlier study showed that this thermal coupling between the oxidation and reduction reactors increases the efficiency by up to 2% points when implemented in a regenerative Brayton cycle. The present study extends this analysis to alternative CLC cycles with the objective of identifying optimal configurations and design tradeoffs. Results show that the increased efficiency from reactor thermal coupling applies only to cycles that are capable of exploiting the increased availability in the reduction reactor exhaust. Thus, in addition to the regenerative cycle, the combined CLC cycle and the combined-regenerative CLC cycle are suitable for integration with the rotary reactor. Parametric studies are used to compare the sensitivity of the different cycle efficiencies to parameters like pressure ratio, turbine inlet temperature, carrier-gas fraction and purge steam generation. One of the key conclusions from this analysis is that while the optimal efficiency for regenerative CLC cycle was the highest of the three (56% at 3. bars, 1200. °C), the combined-regenerative cycle offers a trade-off that combines a reasonably high efficiency (about 54% at 12. bars, 1200. °C) with much lower gas volumetric flow rate and consequently, smaller reactor size. Unlike the other two cycles, the optimal compressor pressure ratio for the regenerative cycle is weakly dependent on the design turbine inlet temperature. For the regenerative and combined regenerative cycles, steam production in the regenerator below 2× fuel flow rate improves exhaust recovery and consequently, the overall system efficiency. Also, given that the fuel side regenerator flow is unbalanced, it is more efficient to generate steam from the

  6. Connection between maximum-work and maximum-power thermal cycles

    OpenAIRE

    Gonzalez-Ayala, Julian; Arias-Hernandez, L. A.; Angulo-Brown, F.

    2013-01-01

    We propose a new connection between maximum-power Curzon-Ahlborn thermal cycles and maximum-work reversible cycles. This linkage is built through a mapping between the exponents of a class of heat transfer laws and the exponents of a family of heat capacities depending on temperature. This connection leads to the recovery of known results and to a wide and interesting set of new results for a class of thermal cycles. Among other results we find that it is possible to use analytically closed e...

  7. Life cycle analysis of underground thermal energy storage

    NARCIS (Netherlands)

    Tomasetta, Camilla; van Ree, Derk; Griffioen, Jasper

    2015-01-01

    Underground Thermal Energy Storage (UTES) systems are used to buffer the seasonal difference between heat and cold supply and demand and, therefore, represent an interesting option to conserve energy. Even though UTES are considered environmental friendly solutions they are not completely free of

  8. Influence of creep damage on the low cycle thermal-mechanical fatigue behavior of two tantalum base alloys

    Science.gov (United States)

    Sheffler, K. D.; Doble, G. S.

    1972-01-01

    Low cycle fatigue tests have been performed on the tantalum base alloys T-111 and ASTAR 811C with synchronized, independently programmed temperature and strain cycling. The thermal-mechanical cycles applied fell into three basic categories: these were isothermal cycling, in-phase thermal cycling, and out-of-phase thermal cycling. In-phase cycling was defined as tensile deformation associated with high temperature and compressive deformation with low temperature, while out-of-phase thermal cycling was defined as the reverse case. The in-phase thermal cycling had a pronounced detrimental influence on the fatigue life of both alloys, with the life reduction being greater in the solid solution strengthened T-111 alloy than in the carbide strengthened ASTAR 811C alloy. The out-of-phase tests also showed pronounced effects on the fatigue life of both alloys, although not as dramatic.

  9. Thermal cycling for restorative materials: does a standardized protocol exist in laboratory testing? A literature review.

    Science.gov (United States)

    Morresi, Anna Lucia; D'Amario, Maurizio; Capogreco, Mario; Gatto, Roberto; Marzo, Giuseppe; D'Arcangelo, Camillo; Monaco, Annalisa

    2014-01-01

    In vitro tests continue to be an indispensable method for the initial screening of dental materials. Thermal cycling is one of the most widely used procedures to simulate the physiological aging experienced by biomaterials in clinical practice. Consequently it is routinely employed in experimental studies to evaluate materials' performance. A literature review aimed to elucidate test parameters for in vitro aging of adhesive restorations was performed. This study aims to assess whether or not a standardized protocol of thermal cycling has been acknowledged from a review of the literature. An exhaustive literature search, examining the effect of thermal cycling on restorative dental materials, was performed with electronic database and by hand. The search was restricted to studies published from 1998 to August 2013. No language restrictions were applied. The search identified 193 relevant experimental studies. Only twenty-three studies had faithfully applied ISO standard. The majority of studies used their own procedures, showing only a certain consistency within the temperature parameter (5-55°C) and a great variability in the number of cycles and dwell time chosen. A wide variation in thermal cycling parameters applied in experimental studies has been identified. The parameters selected amongst these studies seem to be done on the basis of convenience for the authors in most cases. A comparison of results between studies would appear to be impossible. The available data suggest that further investigations will be required to ultimately develop a standardized thermal cycling protocol. © 2013 Elsevier Ltd. All rights reserved.

  10. Effect of thermal cycling and disinfection on colour stability of denture base acrylic resin.

    Science.gov (United States)

    Goiato, Marcelo C; Dos Santos, Daniela M; Baptista, Gabriella T; Moreno, Amália; Andreotti, Agda M; Bannwart, Lisiane C; Dekon, Stefan F C

    2013-12-01

    The purpose of this study was to investigate the effect of thermal cycling and disinfection on the colour change of denture base acrylic resin. Four different brands of acrylic resins were evaluated (Onda Cryl, QC 20, Classico and Lucitone). All brands were divided into four groups (n = 7) determined according to the disinfection procedure (microwave, Efferdent, 4% chlorhexidine or 1% hypochlorite). The treatments were conducted three times a week for 60 days. All specimens were thermal cycled between 5 and 55°C with 30-s dwell times for 1000 cycles before and after disinfection. The specimens' colour was measured with a spectrophotometer using the CIE L*a*b* system. The evaluations were conducted at baseline (B), after first thermal cycling (T1 ), after disinfection (D) and after second thermal cycling (T2 ). Colour differences (ΔE) were calculated between T1 and B (T1 B), D and B (DB), and T2 and B (T2 B) time-points.   The samples submitted to disinfection by microwave and Efferdent exhibited the highest values of colour change. There were significant differences on colour change between the time-points, except for the Lucitone acrylic resin. The thermal cycling and disinfection procedures significantly affected the colour stability of the samples. However, all values obtained for the acrylic resins are within acceptable clinical parameters. © 2012 John Wiley & Sons A/S and The Gerodontology Society. Published by John Wiley & Sons Ltd.

  11. Effect of thermal cycling and disinfection on microhardness of acrylic resin denture base.

    Science.gov (United States)

    Goiato, Marcelo Coelho; Dos Santos, Daniela Micheline; Baptista, Gabriella Trunckle; Moreno, Amália; Andreotti, Agda Marobo; Dekon, Stéfan Fiuza de Carvalho

    2013-04-01

    The purpose of this study was to investigate the effect of thermal cycling and disinfection on the microhardness of acrylic resins denture base. Four different brands of acrylic resins were evaluated: Onda Cryl, QC 20, Classico and Lucitone. Each brand of acrylic resin was divided into four groups (n = 7) according to the disinfection method (microwave, Efferdent, 4% chlorhexidine and 1% hypochlorite). Samples were disinfected during 60 days. Before and after disinfection, samples were thermal cycled between 5-55 °C with 30-s dwell times for 1000 cycles. The microhardness was measured using a microhardener, at baseline (B), after first thermal cycling (T1), after disinfection (D) and after second thermal cycling (T2). The microhardness values of all groups reduced over time. QC-20 acrylic resin exhibited the lowest microhardness values. At B and T1 periods, the acrylic resins exhibited statistically greater microhardness values when compared to D and T2 periods. It can be concluded that the microhardness values of the acrylic resins denture base were affected by the thermal cycling and disinfection procedures. However, all microhardness values obtained herein are within acceptable clinical limits for the acrylic resins.

  12. Thermal shock cycling effect on the compressive behaviour of human teeth.

    Science.gov (United States)

    Papanicolaou, G C; Kouveliotis, G; Nikolopoulou, F; Papaefthymiou, K P; Bairami, V; Portan, D V

    2015-02-26

    All ceramic veneers are a common choice that both dentists and patients make for anterior restorations. In the framework of the present study the residual compressive behavior of the above mentioned complex structures after being thermally shock cycled was investigated. An exponential decrease in both compressive stiffness and strength with the thermal shock cycle number was observed. Experimental findings were in good agreement with predicted values. Photomicrographs obtained revealed a different failure mechanism for the pristine and cycled teeth, which is indicative of the susceptible nature of restored teeth to thermal shock. A two-dimensional finite element model designed gave a better insight upon the stress fields in response of thermal or mechanical loadings developed in the oral cavity. Copyright © 2015 Elsevier Ltd. All rights reserved.

  13. Accelerated Thermal Cycling Test of Microencapsulated Paraffin Wax/Polyaniline Made by Simple Preparation Method for Solar Thermal Energy Storage

    Directory of Open Access Journals (Sweden)

    Mohammad Mehrali

    2013-04-01

    Full Text Available Microencapsulated paraffin wax/polyaniline was prepared using a simple in situ polymerization technique, and its performance characteristics were investigated. Weight losses of samples were determined by Thermal Gravimetry Analysis (TGA. The microencapsulated samples with 23% and 49% paraffin showed less decomposition after 330 °C than with higher percentage of paraffin. These samples were then subjected to a thermal cycling test. Thermal properties of microencapsulated paraffin wax were evaluated by Differential Scanning Calorimeter (DSC. Structure stability and compatibility of core and coating materials were also tested by Fourier transform infrared spectrophotometer (FTIR, and the surface morphology of the samples are shown by Field Emission Scanning Electron Microscopy (FESEM. It has been found that the microencapsulated paraffin waxes show little change in the latent heat of fusion and melting temperature after one thousand thermal recycles. Besides, the chemical characteristics and structural profile remained constant after one thousand thermal cycling tests. Therefore, microencapsulated paraffin wax/polyaniline is a stable material that can be used for thermal energy storage systems.

  14. Development and proof-testing of advanced absorption refrigeration cycle concepts. Report on Phases 1 and 1A

    Energy Technology Data Exchange (ETDEWEB)

    Modahl, R.J.; Hayes, F.C. [Trane Co., La Crosse, WI (United States). Applied Unitary/Refrigeration Systems Div.

    1992-03-01

    The overall objectives of this project are to evaluate, develop, and proof-test advanced absorption refrigeration cycles that are applicable to residential and commercial heat pumps for space conditioning. The heat pump system is to be direct-fired with natural gas and is to use absorption working fluids whose properties are known. Target coefficients of performance (COPs) are 1.6 at 47{degrees}F and 1.2 at 17{degrees} in the heating mode, and 0.7 at 95{degree}F in the cooling mode, including the effect of flue losses. The project is divided into three phases. Phase I entailed the analytical evaluation of advanced cycles and included the selection of preferred concepts for further development. Phase II involves the development and testing of critical components and of a complete laboratory breadboard version of the selected system. Phase III calls for the development of a prototype unit and is contingent on the successful completion of Phase II. This report covers Phase I work on the project. In Phase 1, 24 advanced absorption cycle/fluid combinations were evaluated, and computer models were developed to predict system performance. COP, theoretical pump power, and internal heat exchange were calculated for each system, and these calculations were used as indicators of operating and installed costs in order to rank the relative promise of each system. The highest ranking systems involve the cycle concept of absorber/generator heat exchange, generator heat exchanger/absorber heat exchange, regeneration, and resorption/desorption, in combination with the NH{sub 3}/H{sub 2}O/LiBr ternary absorption fluid mixture or with the NH{sub 3}/H{sub 2}O binary solution. Based upon these conclusions, the recommendation was made to proceed to Phase II, the laboratory breadboard proof-of- concept.

  15. Connection between maximum-work and maximum-power thermal cycles.

    Science.gov (United States)

    Gonzalez-Ayala, Julian; Arias-Hernandez, L A; Angulo-Brown, F

    2013-11-01

    A new connection between maximum-power Curzon-Ahlborn thermal cycles and maximum-work reversible cycles is proposed. This linkage is built through a mapping between the exponents of a class of heat transfer laws and the exponents of a family of heat capacities depending on temperature. This connection leads to the recovery of known results and to a wide and interesting set of results for a class of thermal cycles. Among other results it was found that it is possible to use analytically closed expressions for maximum-work efficiencies to calculate good approaches to maximum-power efficiencies. Behind the proposed connection is an interpretation of endoreversibility hypothesis. Additionally, we suggest that certain reversible maximum-work cycles depending on working substance can be used as reversible landmarks for FTT maximum-power cycles, which also depend on working substance properties.

  16. Residual Tensile Property of Plain Woven Jute Fiber/Poly(Lactic Acid Green Composites during Thermal Cycling

    Directory of Open Access Journals (Sweden)

    Hideaki Katogi

    2016-07-01

    Full Text Available This study investigated the residual tensile properties of plain woven jute fiber reinforced poly(lactic acid (PLA during thermal cycling. Temperature ranges of thermal cycling tests were 35–45 °C and 35–55 °C. The maximum number of cycles was 103 cycles. The quasi-static tensile tests of jute fiber, PLA, and composite were conducted after thermal cycling tests. Thermal mechanical analyses of jute fiber and PLA were conducted after thermal cycling tests. Results led to the following conclusions. For temperatures of 35–45 °C, tensile strength of composite at 103 cycles decreased 10% compared to that of composite at 0 cycles. For temperatures of 35–55 °C, tensile strength and Young’s modulus of composite at 103 cycles decreased 15% and 10%, respectively, compared to that of composite at 0 cycles. Tensile properties and the coefficient of linear expansion of PLA and jute fiber remained almost unchanged after thermal cycling tests. From observation of a fracture surface, the length of fiber pull out in the fracture surface of composite at 103 cycles was longer than that of composite at 0 cycles. Therefore, tensile properties of the composite during thermal cycling were decreased, probably because of the decrease of interfacial adhesion between the fiber and resin.

  17. A graphic approach to include dissipative-like effects in reversible thermal cycles

    Science.gov (United States)

    Gonzalez-Ayala, Julian; Arias-Hernandez, Luis Antonio; Angulo-Brown, Fernando

    2017-05-01

    Since the decade of 1980's, a connection between a family of maximum-work reversible thermal cycles and maximum-power finite-time endoreversible cycles has been established. The endoreversible cycles produce entropy at their couplings with the external heat baths. Thus, this kind of cycles can be optimized under criteria of merit that involve entropy production terms. Meanwhile the relation between the concept of work and power is quite direct, apparently, the finite-time objective functions involving entropy production have not reversible counterparts. In the present paper we show that it is also possible to establish a connection between irreversible cycle models and reversible ones by means of the concept of "geometric dissipation", which has to do with the equivalent role of a deficit of areas between some reversible cycles and the Carnot cycle and actual dissipative terms in a Curzon-Ahlborn engine.

  18. Structural, thermal and optical absorption features of heavy metal oxides doped tellurite rich glasses

    Directory of Open Access Journals (Sweden)

    Kawa M. Kaky

    Full Text Available In order to improve tellurite glass stability to be applicable for optical fiber amplifier applications, glasses with the composition of (70 − xTeO2. (10ZnO. (10WO3. (5Na2O. (5TiO2. (xBi2O3 (x = 1, 2, 3, 4, and 5 mol% have been produced and characterized using the related methods. Structural properties were investigated using X-ray diffraction (XRD which confirms the non-crystalline structure and scanning electron microscopy (SEM micrographs also confirm the XRD results. The energy dispersive X-ray (EDX analysis profiles show that all the mentioned elements are present in the prepared glasses. Following the IR spectra, all the tellurium bonds such as stretching vibrations of TeO4 tbp and TeO3/TeO3+1 unit are revealed. Raman spectra confirm the presence of different functional groups, actually, it shows bands mainly in four spectral regions: R1 (65–150 cm−1, R2 (280–550 cm−1, R3 (880–950 cm−1 and R4 (916–926 cm−1 and the identified bands are assigned to respective molecular groups. The thermal study was carried out using Differential scanning calorimetry (DSC which indicates good thermal stability of the synthesized glasses with increasing Bi concentration. From the optical absorption spectra, we evaluated cut-off edge wavelengths and found increasing cutoff wavelength with an increase in Bi2O3 concentration. In the UV–Visible region, optical band gap energy and allowed transitions were investigated using three methods; direct, indirect, and absorption spectrum fitting (ASF, and band gaps from indirect and ASF were matched. Keywords: Tellurite glasses, XRD, FT-IR, Raman, TGA/DSC

  19. Modeling the absorption behavior of solar thermal collector coatings utilizing graded alpha-C:H/TiC layers.

    Science.gov (United States)

    Gruber, D P; Engel, G; Sormann, H; Schüler, A; Papousek, W

    2009-03-10

    Wavelength selective coatings are of common use in order to enhance the efficiency of devices heated by radiation such as solar thermal collectors. The use of suitable materials and the optimization of coating layer thicknesses are advisable ways to maximize the absorption. Further improvement is achievable by embedding particles in certain layers in order to modify material properties. We focus on optimizing the absorption behavior of a solar collector setup using copper as substrate, a layer of amorphous hydrogenated carbon with embedded titanium carbide particles (a-C:H/TiC), and an antireflection coating of amorphous silicon dioxide (aSiO(2)). For the setup utilizing homogeneous particle distribution, a relative absorption of 90.98% was found, while inhomogeneous particle embedding yielded 98.29%. These results are particularly interesting since until now, absorption of more than 95% was found only by using embedded Cr but not by using the more biocompatible Ti.

  20. Simulation and parametric optimisation of thermal power plant cycles

    OpenAIRE

    Kumar, P. Ravindra; Raju, V. Ramachandra; Kumar, N. Ravi

    2016-01-01

    The objective of the paper is to analyse parametric studies and optimum steam extraction pressures of three different (subcritical, supercritical and ultra-supercritical) coal fired power plant cycles at a particular main steam temperature of 600 °C by keeping the reheat temperature at 537 °C and condenser pressure at 0.09 bar as constant. In order to maximize the heat rate gain possible with supercritical and ultra-supercritical steam conditions, eight stages of feed water heater arrangement...

  1. Influence of specimens' geometry and materials on the thermal stresses in dental restorative materials during thermal cycling.

    Science.gov (United States)

    Fabris, Douglas; Souza, Júlio C M; Silva, Filipe S; Fredel, Márcio; Gasik, Michael; Henriques, Bruno

    2018-02-01

    Thermal cycling is widely used to simulate the aging of restorative materials corresponding to the changes of temperature in the oral cavity. However, test parameters present in literature vary considerably, which prevents comparison between different reports. The aim of this work is to assess the influence of the specimens' geometry and materials on the thermal stresses developed during thermal cycling tests. Finite elements method was used to simulate the conditions of thermal cycling tests for three different sample geometries: a three-points bending test sample, a cylinder rod and more complex shape of a restoration crown. Two different restorative systems were considered: all-ceramic (zirconia coupled with porcelain) and metal-ceramic (CoCrMo alloy coupled with porcelain). The stress state of each sample was evaluated throughout the test cycle. The results show that the sample geometry has great influence on the stress state, with difference of up to 230% in the maximum stress between samples of the same composition. The location of maximum stress also changed from the interface between materials to the external wall. Maximum absolute stress values were found to vary between 2 and 4MPa, which might not be critical even for ceramics. During multi-cycle testing these stresses would cause different fatigue in various locations. The zirconia-based specimens and zirconia-based restoration (crown) exhibited the most similar stress states. Thus it might be recommended to use these geometries for fast screening of the materials for this type of restorations. The selection of specimens' geometry and materials should be carefully considered when aging conditions close to clinical ones want to be simulated. Copyright © 2017 Elsevier Ltd. All rights reserved.

  2. Deep greedy learning under thermal variability in full diurnal cycles

    Science.gov (United States)

    Rauss, Patrick; Rosario, Dalton

    2017-08-01

    We study the generalization and scalability behavior of a deep belief network (DBN) applied to a challenging long-wave infrared hyperspectral dataset, consisting of radiance from several manmade and natural materials within a fixed site located 500 m from an observation tower. The collections cover multiple full diurnal cycles and include different atmospheric conditions. Using complementary priors, a DBN uses a greedy algorithm that can learn deep, directed belief networks one layer at a time and has two layers form to provide undirected associative memory. The greedy algorithm initializes a slower learning procedure, which fine-tunes the weights, using a contrastive version of the wake-sleep algorithm. After fine-tuning, a network with three hidden layers forms a very good generative model of the joint distribution of spectral data and their labels, despite significant data variability between and within classes due to environmental and temperature variation occurring within and between full diurnal cycles. We argue, however, that more questions than answers are raised regarding the generalization capacity of these deep nets through experiments aimed at investigating their training and augmented learning behavior.

  3. Test bench for thermal cycling of 10 kV silicon carbide power modules

    DEFF Research Database (Denmark)

    Sønderskov, Simon Dyhr; Jørgensen, Asger Bjørn; Maarbjerg, Anders Eggert

    2016-01-01

    This paper presents a test bench for lifetime investigation of 10 kV silicon carbide power modules. The test bench subjects high voltage switching operation to the modules while power cycling. Thus both a thermal and electrical operating point is emulated. The power cycling setup features offline...... made to validate the performance of the on-state voltage measurement and the thermal model. Issues are revealed in the form of common mode currents in gate drive supply, which should be remedied. Finally a new operating point for power cycling is suggested to better stress the power modules....... measurement of on-state voltages and direct real-time measurement of die surface temperatures, enabled by fiber optical sensors, which are built into the power modules. A thermal model of the module prototypes, based on the temperature measurements, is established. Independent verification steps have been...

  4. Study of a Liquid Plug-Flow Thermal Cycling Technique Using a Temperature Gradient-Based Actuator

    Directory of Open Access Journals (Sweden)

    Yusuke Fuchiwaki

    2014-10-01

    Full Text Available Easy-to-use thermal cycling for performing rapid and small-volume DNA amplification on a single chip has attracted great interest in the area of rapid field detection of biological agents. For this purpose, as a more practical alternative to conventional continuous flow thermal cycling, liquid plug-flow thermal cycling utilizes a thermal gradient generated in a serpentine rectangular flow microchannel as an actuator. The transit time and flow speed of the plug flow varied drastically in each temperature zone due to the difference in the tension at the interface between temperature gradients. According to thermal distribution analyses in microfluidics, the plug flow allowed for a slow heating process, but a fast cooling process. The thermal cycle of the microfluid was consistent with the recommended temperature gradient for PCR. Indeed, amplification efficiency of the plug flow was superior to continuous flow PCR, and provided an impressive improvement over previously-reported flow microchannel thermal cycling techniques.

  5. A thermal model for the seasonal nitrogen cycle on Triton

    Science.gov (United States)

    Hansen, Candice J.; Paige, David A.

    1992-01-01

    The seasonal N2-cycle model presently used to characterize such observed phenomena on Triton as atmospheric pressure and surface albedo features at the time of the Voyager encounter incorporates diurnal and seasonal subsurface heat conduction, and can account for the heat capacity of N2 frost deposits. The results obtained by this model differ from those of previous studies in that they do not predict the seasonal freezing-out of the Triton atmosphere; even for a wide range of input parameters, the bright southern polar cap is seen as rather unlikely to be N2. The results support the microphysical arguments for the presence of either dark or smooth translucent N2 frosts on the Triton surface.

  6. Effects of Radiation and Long-Term Thermal Cycling on EPC 1001 Gallium Nitride Transistors

    Science.gov (United States)

    Patterson, Richard L.; Scheick, Leif; Lauenstein, Jean-Marie; Casey, Megan; Hammoud, Ahmad

    2012-01-01

    Electronics designed for use in NASA space missions are required to work efficiently and reliably under harsh environment conditions. These include radiation, extreme temperatures, and thermal cycling, to name a few. Data obtained on long-term thermal cycling of new un-irradiated and irradiated samples of EPC1001 gallium nitride enhancement-mode transistors are presented. This work was done by a collaborative effort including GRC, GSFC, and support the NASA www.nasa.gov 1 JPL in of Electronic Parts and Packaging (NEPP) Program

  7. A study on the fracture mechanism of smart composite under thermal shock cycles using AE technique

    Energy Technology Data Exchange (ETDEWEB)

    Lee, J.K.; Lee, S.P. [School of Mechanical Engineering, Dongeui Univ., Busan (Korea); Park, Y.C. [School of Mechanical Engineering, Donga Univ., Busan (Korea)

    2005-07-01

    A smart material is used as spectacle frames and brassiere frames, and partly in medical supplies because of its shape memory effect. The smart composite can be used on the wing of an airplane instead of the existing aluminium to control crack propagation. In this study, the smart composite was fabricated by a hot press method. TiNi alloy as reinforcement and Al6061 as matrix were used, respectively. The mechanical properties of the smart composite under thermal shock cycles were evaluated. In addition, acoustic emission techniques were also used to clarify the damage behavior of the smart composite under thermal shock cycles nondestructively. (orig.)

  8. Thermal Cycling and High Temperature Reverse Bias Testing of Control and Irradiated Gallium Nitride Power Transistors

    Science.gov (United States)

    Patterson, Richard L.; Boomer, Kristen T.; Scheick, Leif; Lauenstein, Jean-Marie; Casey, Megan; Hammoud, Ahmad

    2014-01-01

    The power systems for use in NASA space missions must work reliably under harsh conditions including radiation, thermal cycling, and exposure to extreme temperatures. Gallium nitride semiconductors show great promise, but information pertaining to their performance is scarce. Gallium nitride N-channel enhancement-mode field effect transistors made by EPC Corporation in a 2nd generation of manufacturing were exposed to radiation followed by long-term thermal cycling and testing under high temperature reverse bias conditions in order to address their reliability for use in space missions. Result of the experimental work are presented and discussed.

  9. Effects of Thermal Cycling on Control and Irradiated EPC 2nd Generation GaN FETs

    Science.gov (United States)

    Patterson, Richard L.; Scheick, Leif; Lauenstein, Jean-Marie; Casey, Megan; Hammoud, Ahmad

    2013-01-01

    The power systems for use in NASA space missions must work reliably under harsh conditions including radiation, thermal cycling, and exposure to extreme temperatures. Gallium nitride semiconductors show great promise, but information pertaining to their performance is scarce. Gallium nitride N-channel enhancement-mode field effect transistors made by EPC Corporation in a 2nd generation of manufacturing were exposed to radiation followed by long-term thermal cycling in order to address their reliability for use in space missions. Results of the experimental work are presented and discussed.

  10. Thermal cycling and strain behaviour of AA6061-20% SiC(w) composite

    Energy Technology Data Exchange (ETDEWEB)

    Bonollo, F.; Ceschini, L.; Garagnani, G.L.; Persiani, F.; Zambon, A. (Padua Univ. (Italy). Dip. di Innovazione Meccanica e Gestionale Bologna Univ. (Italy). Ist. di Metallurgia Bologna Univ. (Italy). Dip. di Ingegneria delle Costruzioni Meccaniche, Nucleari, Aeronautiche e di Metallurgia)

    1992-12-01

    This paper describes a study on the effect of thermal cycling on the microstructure and mechanical properties of the fiber reinforced aluminium alloy composite, AA6061 - 20% SiC(w), tested between 100 and 450 degrees C under constant stress (0 to 30 MPa). The test specimens were obtained from extruded bars produced by powder metallurgy. Two specimen orientations were chosen and investigated - longitudinal and transverse. Thermal cycling, carried out by means of suitably designed and assembled test equipment, was aimed at the evaluation of elongation versus extrusion direction, and hardness variation (HR 330N) versus the number of cycles. The microstructural changes in the composite were analyzed by employing light microscopy, scanning electron microscopy, image analysis and transmission electron microscopy. It was observed that: thermal cycling under stress induced very high tensile elongations; significant deformations were also achieved without external loading; there was a correlation among the thermal cycling variables, specimen orientation and applied stress; a re-orientation process occurred along the applied stress direction.

  11. Effect of Thermal Cycling on the Tensile Behavior of Polymer Composites Reinforced by Basalt and Carbon Fibers

    Science.gov (United States)

    Khalili, S. Mohammad Reza; Najafi, Moslem; Eslami-Farsani, Reza

    2017-01-01

    The aim of the present work was to investigate the effect of thermal cycling on the tensile behavior of three types of polymer-matrix composites — a phenolic resin reinforced with woven basalt fibers, woven carbon fibers, and hybrid basalt and carbon fibers — in an ambient environment. For this purpose, tensile tests were performed on specimens previously subjected to a certain number of thermal cycles. The ultimate tensile strength of the specimen reinforced with woven basalt fibers had by 5% after thermal cycling, but the strength of the specimen with woven carbon fibers had reduced to a value by 11% higher than that before thermal cycling.

  12. Effects of mechanical and thermal cycling on composite and hybrid laminates with residual stresses

    Science.gov (United States)

    Daniel, I. M.; Liber, T.

    1977-01-01

    The effects of tensile load cycling and thermal cycling on residual stiffness and strength properties of the following composite and hybrid angle-ply laminates were studied: boron/epoxy, boron/polyimide, graphite/low-modulus epoxy, graphite/high-modulus epoxy, graphite/polyimide, S-glass/epoxy, graphite/Kevlar 49/epoxy, and graphite/S-glass/epoxy. Specimens of the first six types were mechanically cycled up to 90% of static strength. Those that survived 10 million cycles were tested statically to failure, and no significant changes in residual strength and modulus were noted. Specimens of all types were subjected to thermal cycling between room temperature and 411 K for the epoxy-matrix composites and 533 K for the polyimide-matrix composites. The residual strength and stiffness remained largely unchanged, except for the graphite/low-modulus epoxy, which showed reductions in both of approximately 35%. When low-temperature thermal cycling under tensile load was applied, there was a noticeable reduction in modulus and strength in the graphite/low-modulus epoxy and some strength reduction in the S-glass/epoxy.

  13. Thermal Boundary Layer Effects on Line-of-Sight Tunable Diode Laser Absorption Spectroscopy (TDLAS) Gas Concentration Measurements.

    Science.gov (United States)

    Qu, Zhechao; Werhahn, Olav; Ebert, Volker

    2018-01-01

    The effects of thermal boundary layers on tunable diode laser absorption spectroscopy (TDLAS) measurement results must be quantified when using the line-of-sight (LOS) TDLAS under conditions with spatial temperature gradient. In this paper, a new methodology based on spectral simulation is presented quantifying the LOS TDLAS measurement deviation under conditions with thermal boundary layers. The effects of different temperature gradients and thermal boundary layer thickness on spectral collisional widths and gas concentration measurements are quantified. A CO 2 TDLAS spectrometer, which has two gas cells to generate the spatial temperature gradients, was employed to validate the simulation results. The measured deviations and LOS averaged collisional widths are in very good agreement with the simulated results for conditions with different temperature gradients. We demonstrate quantification of thermal boundary layers' thickness with proposed method by exploitation of the LOS averaged the collisional width of the path-integrated spectrum.

  14. Imposed Thermal Fatigue and Post-Thermal-Cycle Wear Resistance of Biomimetic Gray Cast Iron by Laser Treatment

    Science.gov (United States)

    Sui, Qi; Zhou, Hong; Zhang, Deping; Chen, Zhikai; Zhang, Peng

    2017-08-01

    The present study aims to create coupling biomimetic units on gray cast iron substrate by laser surface treatment (LST). LSTs for single-step (LST1) and two-step (LST2) processes, were carried out on gray cast iron in different media (air and water). Their effects on microstructure, thermal fatigue, and post-thermal-cycle wear (PTW) resistance on the specimens were studied. The tests were carried out to examine the influence of crack-resistance behavior as well as the biomimetic surface on its post-thermal-cycle wear behavior and different units, with different laser treatments for comparison. Results showed that LST2 enhanced the PTW behaviors of gray cast iron, which then led to an increase in its crack resistance. Among the treated cast irons, the one treated by LST2 in air showed the lowest residual stress, due to the positive effect of the lower steepness of the thermal gradient. Moreover, the same specimen showed the best PTW performance, due to its superior crack resistance and higher hardness as a result of it.

  15. A feasible thermal-cycle screening system for cryogenic semiconductor components

    Science.gov (United States)

    Wu, Ligang; Liu, Dafu; Huang, Yimin; Zhu, Sangen; Gong, Haimei

    2005-01-01

    For the limit of its lifetime, the Stirling cooler is operated on the intermittent mode in satellite in some cases. Thus such cryogenic semiconductor components as HgCdTe mid or long wavelength infrared (IR) detectors are subjected to thousands of repeated thermal cycles from below -173°C to room temperature. Therefore, a series of experiments focused on quality, performance and reliability are essential in order to satisfy the reasonable requirements. Accordingly, a feasible thermal cycle screening system is put forward. And a vast experimental data show that thermal cycle tests play the most effective role in the environment stress screen (ESS). In this paper, we introduce the system to help to study the main failure mechanisms and improve the performance of the semiconductor components. Such main failure mechanisms as solder-ball invalidation encountered commonly in the detector modules, which is due to the large thermal expansion coefficient mismatch among different materials. The thermal cycle system is based on the principle of heat exchange. We expect HgCdTe IR detectors be cooled to lower than -173°C and heated to room temperature in a few minutes. Above all, we simulate the heating and cooling system through finite element method (FEM). As a result, the computations reveal that the IR detectors can be heated and cooled at a higher rate than expected. A consequent design of the entire system is founded on the simulation. At last, we adjust the mechanical structure of heat exchange system to the adaptive state to accomplish the ESS. The thermal cycle screening system includes an autocontrol part and a test part. The autocontrol part is adopted to realize the heat exchange between IR detectors and the environment, and the test one to inspect the temperature and electrical parameters of these detectors. And at least four IR detector samples can be screened at one time.

  16. Thermal Cycling Behavior of Quasi-Columnar YSZ Coatings Deposited by PS-PVD

    Science.gov (United States)

    Yang, Jiasheng; Zhao, Huayu; Zhong, Xinghua; Shao, Fang; Liu, Chenguang; Zhuang, Yin; Ni, Jinxing; Tao, Shunyan

    2017-01-01

    Columnar-structured thermal barrier coatings, owing to their high strain tolerance, are expected for their potential possibilities to substantially extend turbine lives and improve engine efficiencies. In this paper, plasma spray-physical vapor deposition (PS-PVD) process was used to deposit yttria partially stabilized zirconia (YSZ) coatings with quasi-columnar structures. Thermal cyclic tests on burner rigs and thermal shock tests by heating and water-quenching method were involved to evaluate the thermal cycling and thermal shock behaviors of such kind of structured thermal barrier coatings (TBCs). Evolution of the microstructures, phase composition, residual stresses and failure behaviors of quasi-columnar YSZ coatings before and after the thermal tests was investigated. The quasi-columnar coating obtained had an average life of around 623 cycles when the spallation area reached about 10% of the total coating surface during burner rig tests with the coating surface temperature of 1250 °C. Failure of the coating is mainly due to the break and pull-out of center columnar segments.

  17. Oscillatory Zoning of La- and Y- doped Titanite During Thermal Cycling Experiments

    Science.gov (United States)

    Wickland, T. D.; Glazner, A. F.

    2016-12-01

    Titanite is an important accessory mineral in silicic igneous rocks because it can hold a large proportion of the rare earth element (REE) budget compared to its modal abundance. It typically exhibits strong oscillatory zoning, suggesting variable thermal conditions or open-system addition during crystallization. We performed a set of thermal cycling experiments on La- and Y- (proxy for MREE) doped titanite in a basaltic melt and observed oscillatory zoned rims forming on preexisting, low-REE titanite seeds. Thermal cycling promotes crystal coarsening through precipitation-dissolution processes which may contribute to phenocrystic textures commonly seen in igneous rocks. Using a 1-atmosphere gas-mixing furnace, experiments were cycled ±10°C from 1220°C with a 96-minute period for 1-60 cycles. In these experiments, the number of oscillatory zones in titanite rims equaled the number of thermal cycles. Rims are typically 4-5 mm in wavelength and are euhedral compared to the core anhedral seeds. Oscillatory zones exist within sectored zones of titanite and consist of a bright and dark section determined by backscattered electron images. REE crystal/glass partition coefficients (D-values) determined by FE-microprobe reached 3 in the titanite rims and varied by 0.4 wt% across zones. D-values for Y are 2 orders of magnitude lower in experimentally grown titanite than in natural igneous titanite from silica-rich glass. Titanite incorporates large amounts (103-104 times chondrite) of REE by the coupled substitutions of Ca2+ + Ti4+ = (REE, Y)3+ + (Fe, Al) 3+. D-values negatively correlate with temperature and positively correlate with SiO2 glass content. Thus, high run temperatures and silica-poor glass ( 40 wt%) likely diminish experimental D-values. Although thermal cycling does not appear to increase REE uptake in the titanite-basalt system, it does correlate to the oscillatory zoning patterns common in igneous titanite.

  18. Speciation of methylmercury in market seafood by thermal degradation, amalgamation and atomic absorption spectroscopy.

    Science.gov (United States)

    Ruiz-de-Cenzano, Manuela; Rochina-Marco, Arancha; Cervera, M Luisa; de la Guardia, Miguel

    2014-09-01

    Sample thermal decomposition followed by mercury amalgamation and atomic absorption has been employed for the determination of methylmercury (MeHg) in fish. The method involves HBr leaching of MeHg, extraction into toluene, and back-extraction into an aqueous l-cysteine solution. Preliminary studies were focused on the extraction efficiency, losses, contaminations, and species interconversion prevention. The limit of detection was 0.018µgg(-1) (dry weight). The intraday precision for three replicate analysis at a concentration of 4.2µgg(-1) (dry weight) was 3.5 percent, similar to the interday precision according to analysis of variance (ANOVA). The accuracy was guaranteed by the use of fortified samples involving 83-105 percent recoveries, and certified reference materials TORT-2 (lobster hepatopancreas) and DORM-3 (dogfish liver), providing 107 and 98 percent recovery of certified values. The greenness of the method was also evaluated with the analytical eco-scale being obtained a final score of 73 points which means an acceptable green analysis. The method was applied to fifty-seven market samples of different fish acquired from local markets in several sampling campaigns. The content of MeHg found varied between 0.0311 and 1.24µgg(-1) (wet weight), with values that involve 33-129 percent of the total mercury content. Some considerations about food safety were also done taking into account data about Spanish fish consume and Tolerable Weekly Intake (TWI) established for MeHg. Copyright © 2014 Elsevier Inc. All rights reserved.

  19. Monitoring chemical degradation of thermally cycled glass-fibre composites using hyperspectral imaging

    Science.gov (United States)

    Papadakis, V. M.; Müller, B.; Hagenbeek, M.; Sinke, J.; Groves, R. M.

    2016-04-01

    Nowadays, the application of glass-fibre composites in light-weight structures is growing. Although mechanical characterizations of those structures are commonly performed in testing, chemical changes of materials under stresses have not yet been well documented. In the present work coupon tests and Hyperspectral Imaging (HSI) have been used to categorise possible chemical changes of glass-fibre reinforced polymers (GFRP) which are currently used in the aircraft industry. HSI is a hybrid technique that combines spectroscopy with imaging. It is able to detect chemical degradation of surfaces and has already been successfully applied in a wide range of fields including astronomy, remote sensing, cultural heritage and medical sciences. GFRP specimens were exposed to two different thermal loading conditions. One thermal loading condition was a continuous thermal exposure at 120°C for 24h, 48 h and 96h, i.e. ageing at a constant temperature. The other thermal loading condition was thermal cycling with three different numbers of cycles (4000, 8000, 12000) and two temperature ranges (0°C to 120°C and -25°C to 95°C). The effects of both conditions were measured using both HSI and interlaminar shear (ILSS) tests. No significant changes of the physical properties of the thermally cycled GFRP specimens were detected using interlaminar shear strength tests and optical microscopy. However, when using HIS, differences of the surface conditions were detected. The results showed that the different thermal loading conditions could be successfully clustered in different colours, using the HSI linear unmixing technique. Each different thermal loading condition showed a different chemical degradation level on its surface which was indicated using different colours.

  20. Synergistic effects of ultraviolet radiation, thermal cycling and atomic oxygen on altered and coated Kapton surfaces

    Science.gov (United States)

    Dever, Joyce A.; Bruckner, Eric J.; Rodriguez, Elvin

    1992-01-01

    The photovoltaic (PV) power system for Space Station Freedom (SSF) uses solar array blankets which provide structural support for the solar cells and house the electrical interconnections. In the low earth orbital (LEO) environment where SSF will be located, surfaces will be exposed to potentially damaging environmental conditions including solar ultraviolet (UV) radiation, thermal cycling, and atomic oxygen. It is necessary to use ground based tests to determine how these environmental conditions would affect the mass loss and optical properties of candidate SSF blanket materials. Silicone containing, silicone coated, and SiO(x) coated polyimide film materials were exposed to simulated LEO environmental conditions to determine their durability and whether the environmental conditions of UV, thermal cycling and oxygen atoms act synergistically on these materials. A candidate PV blanket material called AOR Kapton, a polysiloxane polyimide cast from a solution mixture, shows an improvement in durability to oxygen atoms erosion after exposure to UV radiation or thermal cycling combined with UV radiation. This may indicate that the environmental conditions react synergistically with this material, and the damage predicted by exposure to atomic oxygen alone is more severe than that which would occur in LEO where atomic oxygen, thermal cycling and UV radiation are present together.

  1. Reducing dislocations in semiconductors utilizing repeated thermal cycling during multistage epitaxial growth

    Science.gov (United States)

    Fan, John C. C.; Tsaur, Bor-Yeu; Gale, Ronald P.; Davis, Frances M.

    1986-12-30

    Dislocation densities are reduced in growing semiconductors from the vapor phase by employing a technique of interrupting growth, cooling the layer so far deposited, and then repeating the process until a high quality active top layer is achieved. The method of interrupted growth, coupled with thermal cycling, permits dislocations to be trapped in the initial stages of epitaxial growth.

  2. Mechanical and thermal cycling effects on the flexural strength of glass ceramics fused to titanium

    NARCIS (Netherlands)

    Vasquez, Vanessa; Ozcan, Mutlu; Nishioka, Renato; Souza, Rodrigo; Mesquita, Alfredo; Pavanelli, Carlos

    This study evaluated the effects of mechanical and thermal cycling on the flexural strength (ISO 9693) of three brands of ceramics fused to commercially pure titanium (cpTi). Metallic frameworks of 25 x 3 x 0.5 mm dimensions (N = 84) were cast in cpTi, followed by 150-mu m aluminum oxide airborne

  3. Measured thermal and fast neutron fluence rates for ATF-1 holders during ATR cycle 160A

    Energy Technology Data Exchange (ETDEWEB)

    Walker, B. J. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Miller, D. T. [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2017-06-06

    This report contains the thermal (2200 m/s) and fast (E>1MeV) neutron fluence rate data for the ATF-1 holders located in core for ATR Cycle 160A which were measured by the Radiation Measurements Laboratory (RML).

  4. Performance analysis of double-effect absorption heat pump cycle using NH3/ILs pairs

    OpenAIRE

    Wang, M.; Infante Ferreira, C.A.

    2017-01-01

    Ionic liquids (ILs), as novel absorbents, draw considerable attention for their potential roles in replacing H2O or LiBr aqueous solutions in conventional NH3/H2O or H2O/LiBr absorption chiller or heat pump cycles. In this paper, NH3/IL working pairs are proposed for implementation in parallel double effect heat pump systems. To investigate their performance, a property-prediction method, based on experimental heat capacities and the nonrandom two-liquid (NRTL) activity coefficient model for ...

  5. The use of absorption refrigeration systems in combined cycle power plants; Empleo de sistemas de refrigeracion por absorcion en plantas de ciclo combinado

    Energy Technology Data Exchange (ETDEWEB)

    Romero Paredes, H.; Ambriz, J.J.; Vargas, M.; Godinez, M.; Gomez, F.; Valdez, L.; Pantoja, G. [Universidad Autonoma Metropolitana, Unidad Iztapalapa, Departamento de Ingenieria de Procesos e Hidraulica, Mexico D. F. (Mexico)

    1995-12-31

    Day after day the electric power generation tends to be done in the most efficient way in order to diminish the generation costs and the rate of environmental pollution per KWh generated. This paper discusses the application of absorption refrigeration systems for the cooling of the air entering the compressor of a gas turbine in a combined cycle, in order to increase the mass air flow and with it the turbine output. The flows with remanent energy content that are not used in a combined cycle can be used for the operation of the absorption refrigeration system. This way, the required thermal energy for the cooling system is free. With this system it is possible to raise the gas turbine generation output from 5% to 25%. [Espanol] La generacion electrica dia con dia pretende realizarse de la manera mas eficiente posible con el objeto de disminuir los costos de generacion y la tasa de contaminacion ambiental por Kwh generado. En el presente trabajo se introduce la aplicacion de sistemas de refrigeracion por absorcion para el enfriamiento del aire de entrada al compresor de la turbina de gas de un ciclo combinado, con el objeto de aumentar el flujo masico del aire y con ello la potencia de salida de la turbina. Las corrientes con contenido remanente de energia termica que no se usan en una planta de ciclo combinado pueden servir para operar el sistema de refrigeracion por absorcion. De esta manera, la energia termica requerida para el sistema de enfriamiento es gratuita. Con este sistema es posible incrementar la potencia de generacion de la turbina de gas de 5 a 25%.

  6. Transport properties of MnTe films with cracks produced in thermal cycling process

    Science.gov (United States)

    Yang, Liang; Wang, Zhenhua; Zhang, Zhidong

    2017-10-01

    As a promising material in antiferromagnetic spintronics, MnTe films manifested complex characteristics according to previous reports. In this work, we investigate in details the temperature dependence of resistivity of MnTe films grown on SiO2/Si substrate and focus on the divaricating of cooling and warming resistivity-temperature (R-T) curves. It is found that such a divaricating in resistivity is associated with cracks produced in thermal cycles. By comparing the crystalline character and the morphology before and after the cycles, we verify the appearance of cracks and the release of stress in the films. Based on the temperature dependence of thermal-expansion coefficient of Si and MnTe, the origin of the cracks is the mismatched thermal-expansion coefficient ( α). The humps, which only appear in the R-T curve of the first cooling process, are attributed to the produced cracks and/or the unreleased stress.

  7. Transport properties of MnTe films with cracks produced in thermal cycling process

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Liang; Wang, Zhenhua; Zhang, Zhidong [Institute of Metal Research, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Shenyang National Laboratory for Materials Science, Shenyang (China)

    2017-10-15

    As a promising material in antiferromagnetic spintronics, MnTe films manifested complex characteristics according to previous reports. In this work, we investigate in details the temperature dependence of resistivity of MnTe films grown on SiO{sub 2}/Si substrate and focus on the divaricating of cooling and warming resistivity-temperature (R-T) curves. It is found that such a divaricating in resistivity is associated with cracks produced in thermal cycles. By comparing the crystalline character and the morphology before and after the cycles, we verify the appearance of cracks and the release of stress in the films. Based on the temperature dependence of thermal-expansion coefficient of Si and MnTe, the origin of the cracks is the mismatched thermal-expansion coefficient (α). The humps, which only appear in the R-T curve of the first cooling process, are attributed to the produced cracks and/or the unreleased stress. (orig.)

  8. Development of Thermal Performance Analysis Computer Program on Turbine Cycle of Yoggwang 3,4 Units

    Energy Technology Data Exchange (ETDEWEB)

    Hong, S.Y.; Choi, K.H.; Jee, M.H.; Chung, S.I. [Korea Electric Power Research Institute, Taejon (Korea)

    2002-07-01

    The objective of the study ''Development of Thermal Performance Analysis Computer Program on Turbine Cycle of Yonggwang 3,4 Units'' is to utilize computerized program to the performance test of the turbine cycle or the analysis of the operational status of the thermal plants. In addition, the result can be applicable to the analysis of the thermal output at the abnormal status and be a powerful tool to find out the main problems for such cases. As a results, the output of this study can supply the way to confirm the technical capability to operate the plants efficiently and to obtain the economic gains remarkably. (author). 27 refs., 73 figs., 6 tabs.

  9. Finite Element Modeling of Thermal Cycling Induced Microcracking in Carbon/Epoxy Triaxial Braided Composites

    Science.gov (United States)

    Zhang, Chao; Binienda, Wieslaw K.; Morscher, Gregory; Martin, Richard E.

    2012-01-01

    The microcrack distribution and mass change in PR520/T700s and 3502/T700s carbon/epoxy braided composites exposed to thermal cycling was evaluated experimentally. Acoustic emission was utilized to record the crack initiation and propagation under cyclic thermal loading between -55 C and 120 C. Transverse microcrack morphology was investigated using X-ray Computed Tomography. Different performance of two kinds of composites was discovered and analyzed. Based on the observations of microcrack formation, a meso-mechanical finite element model was developed to obtain the resultant mechanical properties. The simulation results exhibited a decrease in strength and stiffness with increasing crack density. Strength and stiffness reduction versus crack densities in different orientations were compared. The changes of global mechanical behavior in both axial and transverse loading conditions were studied. Keywords: Thermal cycles; Microcrack; Finite Element Model; Braided Composite

  10. Effects of High Temperature and Thermal Cycling on the Performance of Perovskite Solar Cells: Acceleration of Charge Recombination and Deterioration of Charge Extraction.

    Science.gov (United States)

    Sheikh, Arif D; Munir, Rahim; Haque, Md Azimul; Bera, Ashok; Hu, Weijin; Shaikh, Parvez; Amassian, Aram; Wu, Tom

    2017-10-11

    In this work, we investigated the effects of high operating temperature and thermal cycling on the photovoltaic (PV) performance of perovskite solar cells (PSCs) with a typical mesostructured (m)-TiO2-CH3NH3PbI3-xClx-spiro-OMeTAD architecture. After temperature-dependent grazing-incidence wide-angle X-ray scattering, in situ X-ray diffraction, and optical absorption experiments were carried out, the thermal durability of PSCs was tested by subjecting the devices to repetitive heating to 70 °C and cooling to room temperature (20 °C). An unexpected regenerative effect was observed after the first thermal cycle; the average power conversion efficiency (PCE) increased by approximately 10% in reference to the as-prepared device. This increase of PCE was attributed to the heating-induced improvement of the crystallinity and p doping in the hole transporter, spiro-OMeTAD, which promotes the efficient extraction of photogenerated carriers. However, further thermal cycles produced a detrimental effect on the PV performance of PSCs, with the short-circuit current and fill factor degrading faster than the open-circuit voltage. Similarly, the PV performance of PSCs degraded at high operation temperatures; both the short-circuit current and open-circuit voltage decreased with increasing temperature, but the temperature-dependent trend of the fill factor was the opposite. Our impedance spectroscopy analysis revealed a monotonous increase of the charge-transfer resistance and a concurrent decrease of the charge-recombination resistance with increasing temperature, indicating a high recombination of charge carriers. Our results revealed that both thermal cycling and high temperatures produce irreversible detrimental effects on the PSC performance because of the deteriorated interfacial photocarrier extraction. The present findings suggest that the development of robust charge transporters and proper interface engineering are critical for the deployment of perovskite PVs in harsh

  11. Effects of High Temperature and Thermal Cycling on the Performance of Perovskite Solar Cells: Acceleration of Charge Recombination and Deterioration of Charge Extraction

    KAUST Repository

    Sheikh, Arif D.

    2017-09-18

    In this work, we investigated the effects of high operating temperature and thermal cycling on the photovoltaic performance of perovskite solar cells (PSCs) with a typical mesostructured (m)-TiO2-CH3NH3PbI3-xClx-spiro-OMeTAD architecture. After carrying out temperature-dependent grazing incidence wide-angle X-ray scattering (GIWAXS), in-situ X-ray diffraction (XRD) and optical absorption experiments, thermal durability of PSCs was tested by subjecting the devices to repetitive heating to 70 °C and cooling to room temperature (20 °C). An unexpected regenerative effect was observed after the first thermal cycle; the average power conversion efficiency (PCE) increased by approximately 10 % in reference to the as-prepared device. This increase of PCE was attributed to the heating-induced improvement of crystallinity and p-doping in the hole-transporter, Spiro-OMeTAD, which promotes the efficient extraction of photo-generated carriers. However, further thermal cycles produced a detrimental effect on the photovoltaic performance of PSCs with short-circuit current and fill factor degrading faster than the open-circuit voltage. Similarly, the photovoltaic performance of PSCs degraded at high operation temperatures; both short-circuit current and open-circuit voltage decreased with increasing temperature, but the temperature-dependent trend of fill factor was opposite. Our impedance spectroscopy analysis revealed a monotonous increase of charge transfer resistance and a concurrent decrease of charge recombination resistance with increasing temperature, indicating high recombination of charge carriers. Our results revealed that both thermal cycling and high temperatures produce irreversible detrimental effects on the PSC performance due to the deteriorated interfacial photo-carrier extraction. The present findings suggest that development of robust charge transporters and proper interface engineering are critical for the deployment of perovskite photovoltaics in harsh

  12. Solar panel thermal cycling testing by solar simulation and infrared radiation methods

    Science.gov (United States)

    Nuss, H. E.

    1980-01-01

    For the solar panels of the European Space Agency (ESA) satellites OTS/MAROTS and ECS/MARECS the thermal cycling tests were performed by using solar simulation methods. The performance data of two different solar simulators used and the thermal test results are described. The solar simulation thermal cycling tests for the ECS/MARECS solar panels were carried out with the aid of a rotatable multipanel test rig by which simultaneous testing of three solar panels was possible. As an alternative thermal test method, the capability of an infrared radiation method was studied and infrared simulation tests for the ultralight panel and the INTELSAT 5 solar panels were performed. The setup and the characteristics of the infrared radiation unit using a quartz lamp array of approx. 15 sq and LN2-cooled shutter and the thermal test results are presented. The irradiation uniformity, the solar panel temperature distribution, temperature changing rates for both test methods are compared. Results indicate the infrared simulation is an effective solar panel thermal testing method.

  13. Effect of thermal cycling on martensitic transformation and mechanical strengthening of stainless steels – A phase-field study

    DEFF Research Database (Denmark)

    Yeddu, Hemantha Kumar; Shaw, Brian A.; Somers, Marcel A. J.

    2017-01-01

    A 3D elastoplastic phase-field model is used to study the effect of thermal cycling on martensitic transformationas well as on mechanical strengthening of both austenite and martensite in stainless steel. The results show that with an increasing number of thermal cycles, martensite becomes more...

  14. A Preliminary Study on Designing and Testing of an Absorption Refrigeration Cycle Powered by Exhaust Gas of Combustion Engine

    Science.gov (United States)

    Napitupulu, F. H.; Daulay, F. A.; Dedy, P. M.; Denis; Jecson

    2017-03-01

    In order to recover the waste heat from the exhaust gas of a combustion engine, an adsorption refrigeration cycle is proposed. This is a preliminary study on design and testing of a prototype of absorption refrigeration cycle powered by an internal combustion engine. The heat source of the cycle is a compression ignition engine which generates 122.36 W of heat in generator of the cycle. The pairs of absorbent and refrigerant are water and ammonia. Here the generator is made of a shell and tube heat exchanger with number of tube and its length are 20 and 0.69 m, respectively. In the experiments the exhaust gas, with a mass flow rate of 0.00016 kg/s, enters the generator at 110°C and leaves it at 72°C. Here, the solution is heated from 30°C to 90°C. In the evaporator, the lowest temperature can be reached is 17.9°C and COP of the system is 0.45. The main conclusion can be drawn here is that the proposed system can be used to recycle the waste heat and produced cooling. However, the COP is still low.

  15. Thermodynamic analysis of a novel compact power generation and waste heat operated absorption, ejector-jet pump refrigeration cycle

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, Anil; Kumar, Raj [YMCA University of Science and Technology, Faridabad (India)

    2014-09-15

    An R-152a ejector-jet pump refrigeration cycle and a LiBr-H{sub 2}O absorption refrigeration cycle have been integrated with a renewable energy power generator for making a proposed 'novel compact cogeneration cycle'. The exergy analysis of this proposed cycle leads to a possible performance improvement. Nearly 71.12% of the input exergy is destructed due to irreversibilities in the different components. The useful exergy output is around 7.12%. The exhaust exergy lost to the environment is 21.76%, which is lower than the exhaust energy lost 37.6% of the input energy, while the useful energy output is approximately 19.3%. The refrigerants used and the exhaust gas emissions samples are found to be favourable for reducing the global environmental related problems. The results also show that the coupling of the entrainment ratios of the ejector and jet pump has great effect on the exergy and energy efficiency.

  16. Thermal enhancement of charge and discharge cycles for adsorbed natural gas storage

    KAUST Repository

    Rahman, Kazi Afzalur

    2011-07-01

    The usage of adsorbed natural gas (ANG) storage is hindered by the thermal management during the adsorption and desorption processes. An effective thermal enhancement is thus essential for the development of the ANG technology and the motivation for this study is the investigation of a gas storage system with internal thermal control. We employed a fin-tube type heat exchanger that is placed in a pressurized cylinder. A distributed-parameter model is used for the theoretical modeling and simulations are conducted at assorted charging and discharging conditions. These studies included the transient thermal behaviours of the elements within the ANG-charged cylinder and parameters such as pressure and temperature profiles of adsorbent have been obtained during charge and discharge cycles, and results are compared with a conventional compressed methane vessel. © 2011 Elsevier Ltd. All rights reserved.

  17. Thermal Stability of Hexamethyldisiloxane (MM for High-Temperature Organic Rankine Cycle (ORC

    Directory of Open Access Journals (Sweden)

    Markus Preißinger

    2016-03-01

    Full Text Available The design of efficient Organic Rankine Cycle (ORC units for the usage of industrial waste heat at high temperatures requires direct contact evaporators without intermediate thermal oil circuits. Therefore, the thermal stability of high-temperature working fluids gains importance. In this study, the thermal degradation of hexamethyldisiloxane (MM is investigated in an electrically heated tube. Qualitative results concerning remarks on degradation products as well as quantitative results like the annual degradation rate are presented. It is shown that MM is stable up to a temperature of 300 °C with annual degradation rates of less than 3.5%. Furthermore, the break of a silicon–carbon bond can be a main chemical reaction that influences the thermal degradation. Finally, it is discussed how the results may impact the future design of ORC units.

  18. Thermal energy storage for low grade heat in the organic Rankine cycle

    Science.gov (United States)

    Soda, Michael John

    Limits of efficiencies cause immense amounts of thermal energy in the form of waste heat to be vented to the atmosphere. Up to 60% of unrecovered waste heat is classified as low or ultra-low quality, making recovery difficult or inefficient. The organic Rankine cycle can be used to generate mechanical power and electricity from these low temperatures where other thermal cycles are impractical. A variety of organic working fluids are available to optimize the ORC for any target temperature range. San Diego State University has one such experimental ORC using R245fa, and has been experimenting with multiple expanders. One limitation of recovering waste heat is the sporadic or cyclical nature common to its production. This inconsistency makes sizing heat recovery ORC systems difficult for a variety of reasons including off-design-point efficiency loss, increased attrition from varying loads, unreliable outputs, and overall system costs. Thermal energy storage systems can address all of these issues by smoothing the thermal input to a constant and reliable level and providing back-up capacity for times when the thermal input is deactivated. Multiple types of thermal energy storage have been explored including sensible, latent, and thermochemical. Latent heat storage involves storing thermal energy in the reversible phase change of a phase change material, or PCM, and can have several advantages over other modalities including energy storage density, cost, simplicity, reliability, relatively constant temperature output, and temperature customizability. The largest obstacles to using latent heat storage include heat transfer rates, thermal cycling stability, and potentially corrosive PCMs. Targeting 86°C, the operating temperature of SDSU's experimental ORC, multiple potential materials were explored and tested as potential PCMs including Magnesium Chloride Hexahydrate (MgCl2˙6H2O), Magnesium Nitrate Hexahydrate (Mg(NO3)2˙6H 2O), montan wax, and carnauba wax. The

  19. Developing a vacuum thermal stripping - acid absorption process for ammonia recovery from anaerobic digester effluent.

    Science.gov (United States)

    Ukwuani, Anayo T; Tao, Wendong

    2016-12-01

    To prevent acetoclastic methanogens from ammonia inhibition in anaerobic digestion of protein-rich substrates, ammonia needs to be removed or recovered from digestate. This paper presents an innovative ammonia recovery process that couples vacuum thermal stripping with acid absorption. Ammonia is stripped out of digestate boiling at a temperature below the normal boiling point due to vacuum. Stripped ammonia is absorbed to a sulfuric acid solution, forming ammonium sulfate crystals as a marketable product. Three common types of digestate were found to have boiling point temperature-vacuum curves similar to water. Seven combinations of boiling temperature and vacuum (50 °C 16.6 kPa, 58 °C 20.0 kPa, 65 °C 25.1 kPa, 70 °C 33.6 kPa, 80 °C 54.0 kPa, 90 °C 74.2 kPa, and 100 °C 101.3 kPa) were tested for batch stripping of ammonia in dairy manure digestate. 93.3-99.9% of ammonia was stripped in 3 h. The Lewis-Whitman model fitted ammonia stripping process well. Ammonia mass transfer coefficient was significantly higher at boiling temperature 65-100 °C and vacuum pressure 25.1-101.3 kPa than 50-58 °C and 16.6-20.0 kPa. The low ammonia saturation concentrations (0-24 mg N/L) suggested a large driving force to strip ammonia. The optimum boiling point temperature - vacuum pressure for ammonia recovery in a recirculation line of a mesophilic digester was 65 °C and 25.1 kPa, at which the ammonia mass transfer coefficient was as high as 37.3 mm/h. Installation of a demister and liquid trap could avoid negative effects of higher stripping temperature and stronger vacuum on formation of ammonium sulfate crystals. Pilot tests demonstrated that high-purity ammonium sulfate crystals could be produced by controlling sulfuric acid content and maintaining acid solution saturated with ammonium sulfate. Although volatile organic compounds such as cyclohexene were found in the final acid solutions, no volatile organic compounds were found in the recovered

  20. Failure Mechanisms of SAC/Fe-Ni Solder Joints During Thermal Cycling

    Science.gov (United States)

    Gao, Li-Yin; Liu, Zhi-Quan; Li, Cai-Fu

    2017-08-01

    Thermal cycling tests have been conducted on Sn-Ag-Cu/Fe- xNi ( x = 73 wt.% or 45 wt.%) and Sn-Ag-Cu/Cu solder joints according to the Joint Electron Device Engineering Council industrial standard to study their interfacial reliability under thermal stress. The interfacial intermetallic compounds formed for solder joints on Cu, Fe-73Ni, and Fe-45Ni were 4.5 μm, 1.7 μm, and 1.4 μm thick, respectively, after 3000 cycles, demonstrating excellent diffusion barrier effect of Fe-Ni under bump metallization (UBM). Also, two deformation modes, viz. solder extrusion and fatigue crack formation, were observed by scanning electron microscopy and three-dimensional x-ray microscopy. Solder extrusion dominated for solder joints on Cu, while fatigue cracks dominated for solder joints on Fe-45Ni and both modes were detected for those on Fe-73Ni. Solder joints on Fe-Ni presented inferior reliability during thermal cycling compared with those on Cu, with characteristic lifetime of 3441 h, 3190 h, and 1247 h for Cu, Fe-73Ni, and Fe-45Ni UBM, respectively. This degradation of the interfacial reliability for solder joints on Fe-Ni is attributed to the mismatch in coefficient of thermal expansion (CTE) at interconnection level. The CTE mismatch at microstructure level was also analyzed by electron backscatter diffraction for clearer identification of recrystallization-related deformation mechanisms.

  1. Evaluations of thermocline and half cycle figure of merit of a thermal energy storage tank

    Directory of Open Access Journals (Sweden)

    Abd Majid Mohd Amin

    2017-01-01

    Full Text Available Two main criteria that are commonly used to evaluate thermal energy storage systems are thermocline thickness and half cycle figure of merit. For the thermocline thickness, the preference is to achieve as thin as possible the thermocline thickness. While the preference for half cycle figure of merit is to achieve the value of greater than 90 per cent. These two criteria were used to evaluate a thermal storage system at University Teknologi PETRONAS district cooling plant. The capacity of the thermal energy storage tank of the plant is 10,000 RTh. Operating data was used for the evaluation. The values of evaluated thermocline thickness ranges from 2.248 meters to 5.445 meters with an average of 3.251 meters. These values are very much higher in comparison to findings of other studies. One possible reason is due to higher flow rates. For the half cycle figure of merit the evaluated values ranges from 0.9469 to 0.9847, with the average of 0.9698, which are within the acceptable range. For future work a model should be developed which could automatically evaluate both the thermocline thickness and half cycle figure of merit. This would enable both of these parameters to be continuously evaluated.

  2. Thermally Induced Ultra High Cycle Fatigue of Copper Alloys of the High Gradient Accelerating Structures

    CERN Document Server

    Heikkinen, Samuli; Wuensch, Walter

    2010-01-01

    In order to keep the overall length of the compact linear collider (CLIC), currently being studied at the European Organization for Nuclear Research (CERN), within reasonable limits, i.e. less than 50 km, an accelerating gradient above 100 MV/m is required. This imposes considerable demands on the materials of the accelerating structures. The internal surfaces of these core components of a linear accelerator are exposed to pulsed radio frequency (RF) currents resulting in cyclic thermal stresses expected to cause surface damage by fatigue. The designed lifetime of CLIC is 20 years, which results in a number of thermal stress cycles of the order of 2.33•1010. Since no fatigue data existed in the literature for CLIC parameter space, a set of three complementary experiments were initiated: ultra high cycle mechanical fatigue by ultrasound, low cycle fatigue by pulsed laser irradiation and low cycle thermal fatigue by high power microwaves, each test representing a subset of the original problem. High conductiv...

  3. Weldability examination of ASTM A 240 S41500 martensitic stainless steel by thermal cycles simulation testings

    Directory of Open Access Journals (Sweden)

    Alberto Velázquez-del Rosario

    2015-07-01

    Full Text Available The weldability assets of ASTM A 240 S41500 (ASTM A 240/A 240M martensitic stainless steel are presented through the study of the effects of single and double thermal weld cycles on mechanical properties and microstructure of base metal (BM and the artificial heat affected zone (HAZ created by thermal weld simulations. For single cycles, separate peak temperatures of 1000 ºC/12 s and 1350 ºC/12 s (cooling times: 12 s in both cases were evaluated, whilst two combinations of peak temperatures: (1350 ºC/5 s + 1000 ºC/5 s ºC and (1350 ºC/12 s + 1000 ºC/12 s ºC (cooling times: 5 s and 12 s, were applied for double cycles. Post weld heat treatment (PWHT with short and long holding times were applied and Vickers hardness, impact toughness and metallographic examinations were used in order to assess mechanical and metallographic properties in the as-simulated (no heat treated and postweld heat treated conditions. Best properties of the welded joint for double thermal weld cycles with long holding times were reached, which reveals the good weldability and applicability of the tested material in post weld heat treated conditions.

  4. Fundamental-frequency and load-varying thermal cycles effects on lifetime estimation of DFIG power converter

    DEFF Research Database (Denmark)

    Zhang, Guanguan; Zhou, Dao; Yang, Jian

    2017-01-01

    In respect to a Doubly-Fed Induction Generator (DFIG) system, its corresponding time scale varies from microsecond level of power semiconductor switching to second level of the mechanical response. In order to map annual thermal profile of the power semiconductors, different approaches have been...... adopted to handle the fundamental-frequency thermal cycles and load-varying thermal cycles. Their effects on lifetime estimation of the power device in the Back-to-Back (BTB) power converter are evaluated....

  5. FR-II Broad Absorption Line Quasars and the Life Cycle of Quasars

    Energy Technology Data Exchange (ETDEWEB)

    Gregg, M D; Becker, R H; de Vries, W

    2006-01-05

    By combining the Sloan Digitized Sky Survey Third Data Release quasar list with the VLA FIRST survey, we have identified five objects having both broad absorption lines in their optical spectra and FR-II radio morphologies. We identify an additional example of this class from the FIRST Bright Quasar Survey, J1408+3054. Including the original FR-II-BAL object, J1016+5209, brings the number of such objects to eight. These quasars are relatively rare; finding this small handful has required the 45,000-large quasar sample of SDSS. The FR-II-BAL quasars exhibit a significant anti-correlation between radio-loudness and the strength of the BAL features. This is easily accounted for by the evolutionary picture in which quasars emerge from cocoons of BAL-producing material which stifle the development of radio jets and lobes. There is no such simple explanation for the observed properties of FR-II-BALs in the unification-by-orientation model of quasars. The rarity of the FR-II-BAL class implies that the two phases do not coexist for very long in a single quasar, perhaps less than 10{sup 5} years, with the combined FR-II, high ionization broad absorption phase being even shorter by another factor of 10 or more.

  6. Theoretical study of thermally driven heat pumps based on double organic rankine cycle

    OpenAIRE

    Demierre, Jonathan; Favrat, Daniel

    2013-01-01

    Part of: Thermally driven heat pumps for heating and cooling. – Ed.: Annett Kühn – Berlin: Universitätsverlag der TU Berlin, 2013 ISBN 978-3-7983-2686-6 (print) ISBN 978-3-7983-2596-8 (online) urn:nbn:de:kobv:83-opus4-39458 [http://nbn-resolving.de/urn:nbn:de:kobv:83-opus4-39458] This study deals with a type of thermally driven heat pumps that consists of a reverse Rankine heat pump cycle, the compressor of which is driven by the turbine of a supercritical Organi...

  7. EXPERIMENTAL STUDY OF THE THERMAL BEHAVIOUR OF HYDROGEN TANKS DURING HYDROGEN CYCLING

    OpenAIRE

    DE MIGUEL ECHEVARRIA NEREA; Acosta Iborra, Beatriz; Moretto, Pietro; HARSKAMP Frederik; BONATO CHRISTIAN

    2013-01-01

    The thermal behaviour of several commercial hydrogen tanks has been studied during high pressure (70-84 MPa) hydrogen cycling. The temperature of the gas at different points inside the tank, the temperature at the bosses and the tank outer wall temperature have been measured under different filling and emptying conditions. From the experimental results, the effect of the filling rate (1.5-4 g/s) and the influence of the liner material in the thermal behaviour of the hydrogen tanks have been e...

  8. Framing the performance of heat absorption/generation and thermal radiation in chemically reactive Darcy-Forchheimer flow

    Directory of Open Access Journals (Sweden)

    T. Hayat

    Full Text Available The present work aims to report the consequences of heterogeneous-homogeneous reactions in Darcy-Forchheimer flow of Casson material bounded by a nonlinear stretching sheet of variable thickness. Nonlinear stretched surface with variable thickness is the main agent for MHD Darcy-Forchheimer flow. Impact of thermal radiation and non-uniform heat absorption/generation are also considered. Flow in porous space is characterized by Darcy-Forchheimer flow. It is assumed that the homogeneous process in ambient fluid is governed by first order kinetics and the heterogeneous process on the wall surface is given by isothermal cubic autocatalator kinetics. The governing nonlinear ordinary differential equations are solved numerically. Effects of physical variables such as thickness, Hartman number, inertia and porous, radiation, Casson, heat absorption/generation and homogeneous-heterogeneous reactions are investigated. The variations of drag force (skin friction and heat transfer rate (Nusselt numberfor different interesting variables are plotted and discussed. Keywords: Casson fluid, Variable sheet thickness, Darcy-Forchheimer flow, Homogeneous-heterogeneous reactions, Heat generation/absorption, Thermal radiation

  9. Thermal analysis of heat and power plant with high temperature reactor and intermediate steam cycle

    Directory of Open Access Journals (Sweden)

    Fic Adam

    2015-03-01

    Full Text Available Thermal analysis of a heat and power plant with a high temperature gas cooled nuclear reactor is presented. The main aim of the considered system is to supply a technological process with the heat at suitably high temperature level. The considered unit is also used to produce electricity. The high temperature helium cooled nuclear reactor is the primary heat source in the system, which consists of: the reactor cooling cycle, the steam cycle and the gas heat pump cycle. Helium used as a carrier in the first cycle (classic Brayton cycle, which includes the reactor, delivers heat in a steam generator to produce superheated steam with required parameters of the intermediate cycle. The intermediate cycle is provided to transport energy from the reactor installation to the process installation requiring a high temperature heat. The distance between reactor and the process installation is assumed short and negligable, or alternatively equal to 1 km in the analysis. The system is also equipped with a high temperature argon heat pump to obtain the temperature level of a heat carrier required by a high temperature process. Thus, the steam of the intermediate cycle supplies a lower heat exchanger of the heat pump, a process heat exchanger at the medium temperature level and a classical steam turbine system (Rankine cycle. The main purpose of the research was to evaluate the effectiveness of the system considered and to assess whether such a three cycle cogeneration system is reasonable. Multivariant calculations have been carried out employing the developed mathematical model. The results have been presented in a form of the energy efficiency and exergy efficiency of the system as a function of the temperature drop in the high temperature process heat exchanger and the reactor pressure.

  10. Thermal analysis of heat and power plant with high temperature reactor and intermediate steam cycle

    Science.gov (United States)

    Fic, Adam; Składzień, Jan; Gabriel, Michał

    2015-03-01

    Thermal analysis of a heat and power plant with a high temperature gas cooled nuclear reactor is presented. The main aim of the considered system is to supply a technological process with the heat at suitably high temperature level. The considered unit is also used to produce electricity. The high temperature helium cooled nuclear reactor is the primary heat source in the system, which consists of: the reactor cooling cycle, the steam cycle and the gas heat pump cycle. Helium used as a carrier in the first cycle (classic Brayton cycle), which includes the reactor, delivers heat in a steam generator to produce superheated steam with required parameters of the intermediate cycle. The intermediate cycle is provided to transport energy from the reactor installation to the process installation requiring a high temperature heat. The distance between reactor and the process installation is assumed short and negligable, or alternatively equal to 1 km in the analysis. The system is also equipped with a high temperature argon heat pump to obtain the temperature level of a heat carrier required by a high temperature process. Thus, the steam of the intermediate cycle supplies a lower heat exchanger of the heat pump, a process heat exchanger at the medium temperature level and a classical steam turbine system (Rankine cycle). The main purpose of the research was to evaluate the effectiveness of the system considered and to assess whether such a three cycle cogeneration system is reasonable. Multivariant calculations have been carried out employing the developed mathematical model. The results have been presented in a form of the energy efficiency and exergy efficiency of the system as a function of the temperature drop in the high temperature process heat exchanger and the reactor pressure.

  11. Effect of prolonged thermal cycling on microleakage around Class V cavities restored with glass-ceramic inserts with different coefficients of thermal expansion: an in vitro study.

    Science.gov (United States)

    Santini, Ario; Ivanovic, Vladimir; Tan, Chuei Luan; Ibbetson, Richard

    2006-10-01

    The purpose of this in vitro study was to evaluate microleakage around Class V glass-ceramic restorations of different coefficients of thermal expansion after prolonged thermal cycling. One hundred and twenty noncarious extracted human premolars (patient age range 12-20 years) were randomly assigned to three groups. Standard Class V preparations were cut in the buccal surface using customised Cerana burs, size no. 3. Glass-ceramic inserts from two manufacturers (Cerana, Nordiska Dental AB, Helsingborg, Sweden; Beta-Quartz, Hager & Werken GmbH, Duisburg, Germany) were used to restore the cavities and were luted with a hybrid, high-viscous composite (Tetric Ceram, Ivoclar Vivadent, Schaan, Liechtenstein) and a bonding agent (Excite, Ivoclar Vivadent, Schaan, Liechtenstein). A control group, without inserts, was bulk-filled with the same composite used as the luting agent. In accordance with American Dental Association guidelines, half of the preparation was in enamel, half in dentine/cementum and had a mesio-distal width of 3 mm, an occluso-gingival height of 3 mm, and a depth of 2 mm. All margins had butt joints. Sixty teeth, selected at random, were not thermal cycled; the remaining 60 teeth were thermal cycled 4000 times between water baths held at 5 degrees C and 55 degrees C and the specimens prepared and examined for microleakage using 2.0% Procion Red (ICI, Slough, UK) dye, buffered at pH7, as a marker. The results were analysed using the Kruskal-Wallis test (ANOVA) at a 95% significance level. At the occlusal margins there was no significant difference in microleakage between the three groups (P>0.5) without thermal cycling. After thermal cycling, microleakage at the occlusal margins was significantly less around cavities restored with Cerana glass-ceramic inserts versus Beta-Quartz and Tetric Ceram (Pmicroleakge between the groups before thermal cycling (P>0.5). After thermal cycling, there was significantly less microleakage between Cerana inserts and

  12. One-step fabrication of submicrostructures by low one-photon absorption direct laser writing technique with local thermal effect

    Science.gov (United States)

    Nguyen, Dam Thuy Trang; Tong, Quang Cong; Ledoux-Rak, Isabelle; Lai, Ngoc Diep

    2016-01-01

    In this work, local thermal effect induced by a continuous-wave laser has been investigated and exploited to optimize the low one-photon absorption (LOPA) direct laser writing (DLW) technique for fabrication of polymer-based microstructures. It was demonstrated that the temperature of excited SU8 photoresist at the focusing area increases to above 100 °C due to high excitation intensity and becomes stable at that temperature thanks to the use of a continuous-wave laser at 532 nm-wavelength. This optically induced thermal effect immediately completes the crosslinking process at the photopolymerized region, allowing obtain desired structures without using the conventional post-exposure bake (PEB) step, which is usually realized after the exposure. Theoretical calculation of the temperature distribution induced by local optical excitation using finite element method confirmed the experimental results. LOPA-based DLW technique combined with optically induced thermal effect (local PEB) shows great advantages over the traditional PEB, such as simple, short fabrication time, high resolution. In particular, it allowed the overcoming of the accumulation effect inherently existed in optical lithography by one-photon absorption process, resulting in small and uniform structures with very short lattice constant.

  13. Radiation and Thermal Cycling Effects on EPC1001 Gallium Nitride Power Transistors

    Science.gov (United States)

    Patterson, Richard L.; Scheick, Leif Z.; Lauenstein, Jean M.; Casey, Megan C.; Hammoud, Ahmad

    2012-01-01

    Electronics designed for use in NASA space missions are required to work efficiently and reliably under harsh environment conditions. These include radiation, extreme temperatures, and thermal cycling, to name a few. Information pertaining to performance of electronic parts and systems under hostile environments is very scarce, especially for new devices. Such data is very critical so that proper design is implemented in order to ensure mission success and to mitigate risks associated with exposure of on-board systems to the operational environment. In this work, newly-developed enhancement-mode field effect transistors (FET) based on gallium nitride (GaN) technology were exposed to various particles of ionizing radiation and to long-term thermal cycling over a wide temperature range. Data obtained on control (un-irradiated) and irradiated samples of these power transistors are presented and the results are discussed.

  14. Microstructural characterization and thermal cycling reliability of solders under isothermal aging and electrical current

    Science.gov (United States)

    Chauhan, Preeti Singh

    Solder joints on printed circuit boards provide electrical and mechanical connections between electronic devices and metallized patterns on boards. These solder joints are often the cause of failure in electronic packages. Solders age under storage and operational life conditions, which can include temperature, mechanical loads, and electrical current. Aging occurring at a constant temperature is called isothermal aging. Isothermal aging leads to coarsening of the bulk microstructure and increased interfacial intermetallic compounds at the solder-pad interface. The coarsening of the solder bulk degrades the creep properties of solders, whereas the voiding and brittleness of interfacial intermetallic compounds leads to mechanical weakness of the solder joint. Industry guidelines on solder interconnect reliability test methods recommend preconditioning the solder assemblies by isothermal aging before conducting reliability tests. The guidelines assume that isothermal aging simulates a "reasonable use period," but do not relate the isothermal aging levels with specific use conditions. Studies on the effect of isothermal aging on the thermal cycling reliability of tin-lead and tin-silver-copper solders are limited in scope, and results have been contradictory. The effect of electrical current on solder joints has been has mostly focused on current densities above 104A/cm2 with high ambient temperature (≥100oC), where electromigration, thermomigration, and Joule heating are the dominant failure mechanisms. The effect of current density below 104A/cm2 on temperature cycling fatigue of solders has not been established. This research provides the relation between isothermal aging and the thermal cycling reliability of select Sn-based solders. The Sn-based solders with 3%, 1%, and 0% silver content that have replaced tin-lead are studied and compared against tin-lead solder. The activation energy and growth exponents of the Arrhenius model for the intermetallic growth in

  15. Framing the performance of heat absorption/generation and thermal radiation in chemically reactive Darcy-Forchheimer flow

    Science.gov (United States)

    Hayat, T.; Shah, Faisal; Khan, Muhammad Ijaz; Alsaedi, A.

    The present work aims to report the consequences of heterogeneous-homogeneous reactions in Darcy-Forchheimer flow of Casson material bounded by a nonlinear stretching sheet of variable thickness. Nonlinear stretched surface with variable thickness is the main agent for MHD Darcy-Forchheimer flow. Impact of thermal radiation and non-uniform heat absorption/generation are also considered. Flow in porous space is characterized by Darcy-Forchheimer flow. It is assumed that the homogeneous process in ambient fluid is governed by first order kinetics and the heterogeneous process on the wall surface is given by isothermal cubic autocatalator kinetics. The governing nonlinear ordinary differential equations are solved numerically. Effects of physical variables such as thickness, Hartman number, inertia and porous, radiation, Casson, heat absorption/generation and homogeneous-heterogeneous reactions are investigated. The variations of drag force (skin friction) and heat transfer rate (Nusselt number) for different interesting variables are plotted and discussed.

  16. Thermal Cycling and High-Temperature Corrosion Tests of Rare Earth Silicate Environmental Barrier Coatings

    Science.gov (United States)

    Darthout, Émilien; Gitzhofer, François

    2017-12-01

    Lutetium and yttrium silicates, enriched with an additional secondary zirconia phase, environmental barrier coatings were synthesized by the solution precursor plasma spraying process on silicon carbide substrates. A custom-made oven was designed for thermal cycling and water vapor corrosion testing. The oven can test four specimens simultaneously and allows to evaluate environmental barrier performances under similar corrosion kinetics compared to turbine engines. Coatings structural evolution has been observed by SEM on the polished cross sections, and phase composition has been analyzed by XRD. All coatings have been thermally cycled between 1300 °C and the ambient temperature, without spallation, due to their porosity and the presence of additional secondary phase which increases the thermal cycling resistance. During water vapor exposure at 1200 °C, rare earth disilicates showed a good stability, which is contradictory with the literature, due to impurities—such as Si- and Al-hydroxides—in the water vapor jets. The presence of vertical cracks allowed the water vapor to reach the substrate and then to corrode it. It has been observed that thin vertical cracks induced some spallation after 24 h of corrosion.

  17. Thermal Hydraulic Analysis of 3 MW TRIGA Research Reactor of Bangladesh Considering Different Cycles of Burnup

    Directory of Open Access Journals (Sweden)

    M.H. Altaf

    2014-12-01

    Full Text Available Burnup dependent steady state thermal hydraulic analysis of TRIGA Mark-II research reactor has been carried out utilizing coupled point kinetics, neutronics and thermal hydraulics code EUREKA-2/RR. From the previous calculations of neutronics parameters including percentage burnup of individual fuel elements performed so far for 700 MWD burnt core of TRIGA reactor showed that the fuel rod predicted as hottest at the beginning of cycle (fresh core was found to remain as the hottest until 200 MWD of burn, but, with the progress of core burn, the hottest rod was found to be shifted and another rod in the core became the hottest. The present study intends to evaluate the thermal hydraulic parameters of these hottest fuel rods at different cycles of burnup, from beginning to 700 MWD core burnt considering reactor operates under steady state condition. Peak fuel centerline temperature, maximum cladding and coolant temperatures of the hottest channels were calculated. It revealed that maximum temperature reported for fuel clad and fuel centerline found to lie below their melting points which indicate that there is no chance of burnout on the fuel cladding surface and no blister in the fuel meat throughout the considered cycles of core burnt.

  18. Thermal Cycling and Isothermal Deformation Response of Polycrystalline NiTi: Simulations vs. Experiment

    Science.gov (United States)

    Manchiraju, Sivom; Gaydosh, Darrell; Benafan, Othmane; Noebe, Ronald; Vaidyanathan, Raj; Anderson, Peter M.

    2011-01-01

    A recent microstructure-based FEM model that couples crystal-based plasticity, the B2 MB190 phase transformation and anisotropic elasticity at the grain scale is calibrated to recent data for polycrystalline NiTi (49.9 at.% Ni). Inputs include anisotropic elastic properties, texture and differential scanning calorimetry data, as well as a subset of recent isothermal deformation and load-biased thermal cycling data. The model is assessed against additional experimental data. Several experimental trends are captured - in particular, the transformation strain during thermal cycling monotonically increases and reaches a peak with increasing bias stress. This is achieved, in part, by modifying the martensite hardening matrix proposed by Patoor et al. [Patoor E, Eberhardt A, Berveiller M. J Phys IV 1996;6:277]. Some experimental trends are underestimated - in particular, the ratcheting of macrostrain during thermal cycling. This may reflect a model limitation that transformation-plasticity coupling is captured on a coarse (grain) scale but not on a fine (martensitic plate) scale.

  19. Thermal Cycling and High-Temperature Corrosion Tests of Rare Earth Silicate Environmental Barrier Coatings

    Science.gov (United States)

    Darthout, Émilien; Gitzhofer, François

    2017-09-01

    Lutetium and yttrium silicates, enriched with an additional secondary zirconia phase, environmental barrier coatings were synthesized by the solution precursor plasma spraying process on silicon carbide substrates. A custom-made oven was designed for thermal cycling and water vapor corrosion testing. The oven can test four specimens simultaneously and allows to evaluate environmental barrier performances under similar corrosion kinetics compared to turbine engines. Coatings structural evolution has been observed by SEM on the polished cross sections, and phase composition has been analyzed by XRD. All coatings have been thermally cycled between 1300 °C and the ambient temperature, without spallation, due to their porosity and the presence of additional secondary phase which increases the thermal cycling resistance. During water vapor exposure at 1200 °C, rare earth disilicates showed a good stability, which is contradictory with the literature, due to impurities—such as Si- and Al-hydroxides—in the water vapor jets. The presence of vertical cracks allowed the water vapor to reach the substrate and then to corrode it. It has been observed that thin vertical cracks induced some spallation after 24 h of corrosion.

  20. Decay and termite resistance, water absorption and swelling of thermally compressed wood panels

    Science.gov (United States)

    Oner Unsal; S. Nami Kartal; Zeki Candan; Rachel A. Arango; Carol A. Clausen; Frederick Green

    2009-01-01

    This study evaluated decay and termite resistance of thermally compressed pine wood panels under pressure at either 5 or 7 MPa and either 120 or 150 °C for 1 h. Wood specimens from the panels were exposed to laboratory decay resistance by using the wood degrading fungi, Gloeophyllum trabeum and Trametes versicolor. The thermal compression process caused increases in...

  1. Measured Thermal and Fast Neutron Fluence Rates for ATF-1 Holders During ATR Cycle 157D

    Energy Technology Data Exchange (ETDEWEB)

    Smith, Larry Don [Idaho National Lab. (INL), Idaho Falls, ID (United States); Miller, David Torbet [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2016-03-01

    This report contains the thermal (2200 m/s) and fast (E>1MeV) neutron fluence rate data for the ATF-1 holders located in core for ATR Cycle 157D which were measured by the Radiation Measurements Laboratory (RML) as requested by the Power Reactor Programs (ATR Experiments) Radiation Measurements Work Order. This report contains measurements of the fluence rates corresponding to the particular elevations relative to the 80-ft. core elevation. The data in this report consist of (1) a table of the ATR power history and distribution, (2) a hard copy listing of all thermal and fast neutron fluence rates, and (3) plots of both the thermal and fast neutron fluence rates. The fluence rates reported are for the average power levels given in the table of power history and distribution.

  2. Reactive power influence on the thermal cycling of multi-MW wind power inverter

    DEFF Research Database (Denmark)

    Ma, Ke; Liserre, Marco; Blaabjerg, Frede

    2013-01-01

    In this paper the reactive power influence on the thermal cycling of power devices in grid-connected inverter for 10 MW wind turbines is investigated. Restrained by the grid codes, the allowable reactive power ranges in relation to amplitude and phase angle of the load current for a single...... converter system are first presented at different wind speeds. Furthermore, the interaction between paralleled converter systems in a wind park is also considered and analyzed. By controlling the reactive power circulated among paralleled converters, a new concept is then proposed to stabilize the thermal...... fluctuation of the power devices during wind gusts. It is concluded that the reactive power may change the thermal distribution of power devices. By properly controlling the reactive power, it is possible to achieve a more stable junction temperature in the power devices during the fluctuation of wind speed...

  3. Reactive power influence on the thermal cycling of multi-MW wind power inverter

    DEFF Research Database (Denmark)

    Ma, Ke; Liserre, Marco; Blaabjerg, Frede

    2012-01-01

    In this paper the reactive power influence on the thermal cycling of power devices in grid-connected inverter for 10 MW wind turbines is investigated. Restrained by the grid codes, the allowable reactive power ranges in relation to amplitude and phase angle of the load current for a single...... converter system are first presented at different wind speeds. Furthermore, the interaction between paralleled converter systems in a wind park is also considered and analyzed. By controlling the reactive power circulated among paralleled converters, a new concept is then proposed to stabilize the thermal...... fluctuation of the power devices during wind gusts. It is concluded that the reactive power may change the thermal distribution of power devices. By properly controlling the reactive power, it is possible to achieve a more stable junction temperature in the power devices during the fluctuation of wind speed...

  4. Three-dimensional flow of an oldroyd-B fluid with variable thermal conductivity and heat generation/absorption.

    Directory of Open Access Journals (Sweden)

    Sabir Ali Shehzad

    Full Text Available This paper looks at the series solutions of three dimensional boundary layer flow. An Oldroyd-B fluid with variable thermal conductivity is considered. The flow is induced due to stretching of a surface. Analysis has been carried out in the presence of heat generation/absorption. Homotopy analysis is implemented in developing the series solutions to the governing flow and energy equations. Graphs are presented and discussed for various parameters of interest. Comparison of present study with the existing limiting solution is shown and examined.

  5. Technical and economic feasibility of a Thermal Gradient Utilization Cycle (TGUC) power plant

    Science.gov (United States)

    Raiji, A. M.; Renfroe, D. A.; Lalk, T. R.

    Power is generated by exploiting the natural atmospheric temperature gradient. A low grade energy source is used to vaporize a fluid which rises in a pipe to a higher elevation where it is condensed. The cycle is completed by passing the condensed liquid through a turbine as it returns to the lower elevation. A digital computer model was developed and used to simulate the operation of the cycle and to conduct a parameteric study. Life cycle cost analysis and energy analyses were conducted for the specific case of a TGUC using the ambient air at the lower elevation as an energy source. Although the cycle has a low thermal efficiency and is site specific, it is technically feasible. Variations in mass flow rate of the working fluid and elevation were found to affect the cycle power output to a large extent. The investment cost of a hypothetical 10 megawatt TGUC power plant was determined to be $3,080 per kilowatt, with life cycle busbar costs of electricity ranging from 47 to 55 Mills per kilowatt hour depending on the method of financing.

  6. Thermal Cycling Behavior of Thermal Barrier Coatings with MCrAlY Bond Coat Irradiated by High-Current Pulsed Electron Beam.

    Science.gov (United States)

    Cai, Jie; Lv, Peng; Guan, Qingfeng; Xu, Xiaojing; Lu, Jinzhong; Wang, Zhiping; Han, Zhiyong

    2016-11-30

    Microstructural modifications of a thermally sprayed MCrAlY bond coat subjected to high-current pulsed electron beam (HCPEB) and their relationships with thermal cycling behavior of thermal barrier coatings (TBCs) were investigated. Microstructural observations revealed that the rough surface of air plasma spraying (APS) samples was significantly remelted and replaced by many interconnected bulged nodules after HCPEB irradiation. Meanwhile, the parallel columnar grains with growth direction perpendicular to the coating surface were observed inside these bulged nodules. Substantial Y-rich Al2O3 bubbles and varieties of nanocrystallines were distributed evenly on the top of the modified layer. A physical model was proposed to describe the evaporation-condensation mechanism taking place at the irradiated surface for generating such surface morphologies. The results of thermal cycling test showed that HCPEB-TBCs presented higher thermal cycling resistance, the spalling area of which after 200 cycles accounted for only 1% of its total area, while it was about 34% for APS-TBCs. The resulting failure mode, i.e., in particular, a mixed delamination crack path, was shown and discussed. The irradiated effects including compact remelted surface, abundant nanoparticles, refined columnar grains, Y-rich alumina bubbles, and deformation structures contributed to the formation of a stable, continuous, slow-growing, and uniform thermally grown oxide with strong adherent ability. It appeared to be responsible for releasing stress and changing the cracking paths, and ultimately greatly improving the thermal cycling behavior of HCPEB-TBCs.

  7. Thermal Modelling Analysis of Spiral Wound Supercapacitor under Constant-Current Cycling

    Science.gov (United States)

    Wang, Kai; Li, Liwei; Yin, Huaixian; Zhang, Tiezhu; Wan, Wubo

    2015-01-01

    A three-dimensional modelling approach is used to study the effects of operating and ambient conditions on the thermal behaviour of the spiral wound supercapacitor. The transient temperature distribution during cycling is obtained by using the finite element method with an implicit predictor-multicorrector algorithm. At the constant current of 2A, the results show that the maximum temperature appears in core area. After 5 cycles, the maximum temperature is 34.5°C, while in steady state, it’s up to 42.5°C. This paper further studies the relationship between the maximum temperature and charge-discharge current. The maximum temperature will be more than 60°C after 5 cycles at the current of 4A, and cooling measurements should be taken at that time. It can provide thoughts on inner temperature field distribution and structure design of the spiral wound supercapacitor in working process. PMID:26444687

  8. Thermal Modelling Analysis of Spiral Wound Supercapacitor under Constant-Current Cycling.

    Science.gov (United States)

    Wang, Kai; Li, Liwei; Yin, Huaixian; Zhang, Tiezhu; Wan, Wubo

    2015-01-01

    A three-dimensional modelling approach is used to study the effects of operating and ambient conditions on the thermal behaviour of the spiral wound supercapacitor. The transient temperature distribution during cycling is obtained by using the finite element method with an implicit predictor-multicorrector algorithm. At the constant current of 2A, the results show that the maximum temperature appears in core area. After 5 cycles, the maximum temperature is 34.5°C, while in steady state, it's up to 42.5°C. This paper further studies the relationship between the maximum temperature and charge-discharge current. The maximum temperature will be more than 60°C after 5 cycles at the current of 4A, and cooling measurements should be taken at that time. It can provide thoughts on inner temperature field distribution and structure design of the spiral wound supercapacitor in working process.

  9. Analysis of thermal cycles and microstructure of heat affected zone for a low alloy carbon steel pipe under multipass weld

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Tae Woan; Ha, Joon Wook; Kim, Dong Jin; Kim, Jeong Tae [Doosan Heavy Industries and Construction Co., Ltd., Changwon (Korea, Republic of)

    2002-03-01

    The purpose of this study is to analyze thermal cycles and to investigate microstructures of heat affected zones for a low alloy carbon steel pipe under a multipass weld. The commercial finite element code SYSWELD is used to compute thermal cycles during multipass weld. The numerical results such as thermal cycles and size of heat affected zone are compared with those of the experiment and the two results show a good agreement. In addition, the microstructure and hardness and investigated from the weldment in detail. The weakest location is founded at intercritical region near the base metal.

  10. Marginal adaptation of class V composite restorations submitted to thermal and mechanical cycling

    Directory of Open Access Journals (Sweden)

    Denise Sa Maia CASSELLI

    2013-01-01

    Full Text Available Objective This study evaluated the effect of the margin location and an adhesive system on the marginal adaptation of composite restorations. Material and Methods Class V cavities were prepared in bovine teeth with the gingival margin on the dentin and the incisal margin on the enamel. The cavities were restored with a micro-hybrid composite resin using an etch-and-rinse [Single Bond 2 (SB] or a self-etching adhesive [Clearfil SE Bond (CL]. After finishing and polishing the restorations, epoxy replicas were prepared. The marginal adaptation was analyzed using scanning electronic microscopy (SEM, 500 x magnification. The higher gap width in each margin was recorded (T0. After the first evaluation, the samples were submitted to thermal cycling (2,000 cycles of 5°C±2°C followed by 55°C±2°C – T1 and mechanical cycling (100,000 cycles of 50 kN and 2 Hz – T2. Replicas of samples were rebuilt after each cycling and analyzed under SEM. The data were submitted to Mann-Whitney, Wilcoxon and Friedman testing (α=0.05. Results The SB presented higher gaps in the dentin than the enamel, while there was no difference between the substrate for the CL. In the dentin, the CL showed better marginal sealing than the SB. The opposite occurred in the enamel. There were no significant differences between the baseline, thermal and mechanical cycling for any experimental condition. Conclusions The outcomes of the present study showed that the adhesive system and margin location have an important effect on the marginal adaptation of composite restorations.

  11. High Ultraviolet Absorption in Colloidal Gallium Nanoparticles Prepared from Thermal Evaporation

    Directory of Open Access Journals (Sweden)

    Flavio Nucciarelli

    2017-07-01

    Full Text Available New methods for the production of colloidal Ga nanoparticles (GaNPs are introduced based on the evaporation of gallium on expendable aluminum zinc oxide (AZO layer. The nanoparticles can be prepared in aqueous or organic solvents such as tetrahydrofuran in order to be used in different sensing applications. The particles had a quasi mono-modal distribution with diameters ranging from 10 nm to 80 nm, and their aggregation status depended on the solvent nature. Compared to common chemical synthesis, our method assures higher yield with the possibility of tailoring particles size by adjusting the deposition time. The GaNPs have been studied by spectrophotometry to obtain the absorption spectra. The colloidal solutions exhibit strong plasmonic absorption in the ultra violet (UV region around 280 nm, whose width and intensity mainly depend on the nanoparticles dimensions and their aggregation state. With regard to the colloidal GaNPs flocculate behavior, the water solvent case has been investigated for different pH values, showing UV-visible absorption because of the formation of NPs clusters. Using discrete dipole approximation (DDA method simulations, a close connection between the UV absorption and NPs with a diameter smaller than ~40 nm was observed.

  12. Integrated CO2, humidity and thermal control by membrane gas absorption

    NARCIS (Netherlands)

    Eckhard, F.; Feron, P.H.M.; Jacobs, P.; Savage, Ch.; Witt, J.

    1999-01-01

    In three consecutive studies the use of membrane gas absorption for the recovery of CO2, water vapour and heat has been studied by Stork and the TNO Institute of Environmental Sciences, Energy Research and Process Innovation. This work has financially been supported by ESA and the Dutch national

  13. Theoretical and experimental analysis of the vacuum pressure in a vacuum glazing after extreme thermal cycling

    Energy Technology Data Exchange (ETDEWEB)

    Fang, Yueping; Hyde, Trevor J.; Hewitt, Neil [Ulster Univ., Newtownabbey, Northern Ireland (United Kingdom). Centre for Sustainable Technologies; Eames, Philip C. [Warwick Univ., Coventry (United Kingdom). Warwick Inst. for Sustainable Energy and Resources

    2008-07-01

    Details of theoretical and experimental studies of the change in vacuum pressure within a vacuum glazing after extreme thermal cycling are presented. The vacuum glazing was fabricated at low temperature using an indium edge seal. It comprised two 4 mm thick 0.4 m by 0.4 m low-emittance glass panes separated by an array of stainless steel pillars with a diameter of 0.32 mm and a height of 0.2 mm. After thermal cycling in the temperature range -30 C to +50 C on one side of the sample, while maintaining 22 C on the other side, it was found that the glass to glass heat conductance of the sample had increased by 8.2%. The vacuum pressure within the evacuated gap was determined to have increased from 0.01 Pa to 0.15 Pa using the model of Corrucini. This is at the upper limit of the range where the effect of gas pressure on the thermal performance of vacuum glazing can be ignored. The degradation of vacuum level determined was corroborated by the change in glass surface temperatures. (orig.)

  14. Zinc absorption from milk is affected by dilution but not by thermal processing, and milk enhances absorption of Zinc from high-phytate rice in young dutch women

    NARCIS (Netherlands)

    Talsma, Elise F.; Moretti, Diego; Ly, Sou Chheng; Dekkers, Renske; Heuvel, van den Ellen G.H.M.; Fitri, Aditia; Boelsma, Esther; Stomph, Tjeerd Jan; Zeder, Christophe; Melse-Boonstra, Alida

    2017-01-01

    Background: Milk has been suggested to increase zinc absorption. The effect of processing and the ability of milk to enhance zinc absorption from other foods has not been measured directly in humans. Objective: We aimed to assess zinc absorption from 1) milk undergoing various processing and

  15. Absorption cooling device. Absorptions-Kuehlvorrichtung

    Energy Technology Data Exchange (ETDEWEB)

    Bourne, J.; Vardi, I.; Kimchi, Y.; Ben-Dror, J.

    1980-03-25

    The invention concerns improvements of absorption refrigerators, where a lithium chloride or lithium bromide/water cycle is used. According to the invention an inner separating or dividing structure between different functional parts of a machine of this type is provided. The structure contains two sections of wall, which are separated from one another by a suitable space, in order to achieve thermal insulation. This air space is provided with an opening in the direction towards the inside of the container and the opening is shielded to prevent the entry of liquids (in liquid or spray form).

  16. Research on transient thermal process of a friction brake during repetitive cycles of operation

    Science.gov (United States)

    Slavchev, Yanko; Dimitrov, Lubomir; Dimitrov, Yavor

    2017-12-01

    Simplified models are used in the classical engineering analyses of the friction brake heating temperature during repetitive cycles of operation to determine basically the maximum and minimum brake temperatures. The objective of the present work is to broaden and complement the possibilities for research through a model that is based on the classical scheme of the Newton's law of cooling and improves the studies by adding a disturbance function for a corresponding braking process. A general case of braking in non-periodic repetitive mode is considered, for which a piecewise function is defined to apply pulse thermal loads to the system. Cases with rectangular and triangular waveforms are presented. Periodic repetitive braking process is also studied using a periodic rectangular waveform until a steady thermal state is achieved. Different numerical methods such as the Euler's method, the classical fourth order Runge-Kutta (RK4) and the Runge-Kutta-Fehlberg 4-5 (RKF45) are used to solve the non-linear differential equation of the model. The constructed model allows during pre-engineering calculations to be determined effectively the time for reaching the steady thermal state of the brake, to be simulated actual braking modes in vehicles and material handling machines, and to be accounted for the thermal impact when performing fatigue calculations.

  17. A Literature Review of Shock Sensitivity Changes of TATB Due to Thermal Cycling

    Energy Technology Data Exchange (ETDEWEB)

    Ritter, Boyd [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); New Mexico Inst. of Mining and Technology, Socorro, NM (United States). Dept. of Mechanical Engineering

    2016-07-15

    Insensitive high explosives (IHEs) based on 1,3,5-triamino 2,4,6-trinitro-benzene (TATB) are the IHEs of choice for use in nuclear warheads over conventional high explosives when safety is the only consideration, because they are very insensitive to thermal or mechanical initiation stimuli. It is this inherent insensitivity to high temperatures, shock, and impact, which provides detonation design challenges when designing TATB explosive systems while at the same time providing a significant level of protection against accidental initiation. Although classified as IHE, over the past few years the focus on explosive safety has demonstrated that the shock sensitivity of TATB is influenced with respect to temperature. A number of studies have been performed on TATB and TATB formulations, plastic bonded explosives (PBX) 9502, and LX-17-01 (LX-17), which demonstrates the increase in shock sensitivity of the explosive after it has been preheated or thermally cycled over various temperature ranges. Many studies suggest the change in sensitivity is partly due to the decomposition rates of the temperature elevated TATB. Others point to the coefficient of thermal expansion, the crystalline structures of TATB and/or the combination of all factors, which create voids which can become active hot spots. During thermal cycling, TATB is known to undergo an irreversible increase in specific volume called ratchet growth. This increase in specific volume correlates to a decrease in density. This decrease in density and increase in volume, demonstrate the creations of additional void spaces which could serve as potential new initiation hot spots thus, increasing the overall sensitivity of the HE. This literature review evaluates the published works to understand why the shock sensitivity of TATB-based plastic bonded explosives (PBXs) changes with temperature.

  18. Environmental cycling of cellulosic thermal insulation and its influence on fire performance

    Science.gov (United States)

    Lawson, J. R.

    1984-08-01

    A study was conducted on climatological data for eleven cities located throughout the United States. Findings from this environmental study were used to develop conditioning cycles for a research project on the influence of environments on the fire performance of loose-fill cellulosic thermal insulation. Six cellulosic insulation materials with different compositions of fire retardant chemicals at an add-on level of 25% by weight were specially manufactured for this study. These materials were tested for fire performance using the smoldering combustion test and the attic flooring radiant panel test to establish a baseline. After the materials were exposed to the various environmental cycles, they were tested for fire performance. Results from these tests show that environmental exposure can have a significant effect on the fire performance of cellulosic insulation materials and indicates that long term fire protection provided by fire retardant compounds may be limited.

  19. Static behavior and the effects of thermal cycling in hybrid laminates

    Science.gov (United States)

    Liber, T. M.; Daniel, I. M.; Chamis, C. C.

    1977-01-01

    Static stiffness, strength and ultimate strain after thermal cycling were investigated for graphite/Kevlar 49/epoxy and graphite/S-glass/epoxy angle-ply laminates. Tensile stress-strain curves to failure and uniaxial tensile properties were determined, and theoretical predictions of modulus, Poisson's ratio and ultimate strain, based on linear lamination theory, constituent ply properties and measured strength, were made. No significant influence on tensile stress properties due to stacking sequence variations was observed. In general, specimens containing two 0-degree Kevlar or S-glass plies were found to behave linearly to failure, while specimens containing 4 0-degree Kevlar or S-glass plies showed some nonlinear behavior.

  20. Ex Situ Thermal Cycle Annealing of Molecular Beam Epitaxy Grown HgCdTe/Si Layers

    Science.gov (United States)

    2010-01-01

    matched bulk CdZnTe substrates. Recent work6 on CdTe/Si has shown that in situ thermal cycle annealing (TCA), where annealing is performed intermittently...was grown on a bulk CdZnTe substrate for comparison. The HgCdTe was grown at 185C, with a growth rate of 2 lm/h. The typical HgCdTe layer...Cd composition. The HgCdTe layers grown on bulk CdZnTe samples, which were subjected to annealing condi- tions similar to those for the HgCdTe layers

  1. Effect of Thermal Cycling on the Strength and Texture of Concrete for Nuclear Safety Structures

    Directory of Open Access Journals (Sweden)

    Š. Hošková

    2001-01-01

    Full Text Available The effect of thermal cycling (freezing and thawing on the texture and strength of two types of concrete is studied: 1. Concrete used for a containment structure at NPP Temelín (Czech Republic - so-called TEMELÍN concrete.2. Highly resistant PENLY concrete, which was used as a standard because of its high quality, proved by the research carried out in a European Commission project. The results for the two samples of concrete are compared.

  2. Effects of thermal and moisture cycling on the internal structure of stitched RTM laminates

    Science.gov (United States)

    Walker, Jeff; Roundy, Lance; Goering, Jon

    1993-01-01

    Conventional aerospace composites are strong and stiff in the directions parallel to the carbon fibers, but they are prone to delaminations and damage in the through-the-thickness directions. Recent research has shown that substantial improvements in damage tolerance are obtained from textile composites with Z-direction reinforcement provided by stitching, weaving, or braiding. Because of the mismatch in thermal and moisture expansion properties of the various material components, there is a potential for microcracks to develop in the resin matrix. These cracks can form to relieve the mechanical stresses that are generated during curing or in-service temperature cycles.

  3. Technical Feasibility Study of Thermal Energy Storage Integration into the Conventional Power Plant Cycle

    Directory of Open Access Journals (Sweden)

    Jacek D. Wojcik

    2017-02-01

    Full Text Available The current load balance in the grid is managed mainly through peaking fossil-fuelled power plants that respond passively to the load changes. Intermittency, which comes from renewable energy sources, imposes additional requirements for even more flexible and faster responses from conventional power plants. A major challenge is to keep conventional generation running closest to the design condition with higher load factors and to avoid switching off periods if possible. Thermal energy storage (TES integration into the power plant process cycle is considered as a possible solution for this issue. In this article, a technical feasibility study of TES integration into a 375-MW subcritical oil-fired conventional power plant is presented. Retrofitting is considered in order to avoid major changes in the power plant process cycle. The concept is tested based on the complete power plant model implemented in the ProTRAX software environment. Steam and water parameters are assessed for different TES integration scenarios as a function of the plant load level. The best candidate points for heat extraction in the TES charging and discharging processes are evaluated. The results demonstrate that the integration of TES with power plant cycle is feasible and provide a provisional guidance for the design of the TES system that will result in the minimal influence on the power plant cycle.

  4. Laser Soldering and Thermal Cycling Tests of Monolithic Silicon Pixel Chips

    CERN Document Server

    Strand, Frode Sneve

    2015-01-01

    An ALPIDE-1 monolithic silicon pixel sensor prototype has been laser soldered to a flex printed circuit using a novel interconnection technique using lasers. This technique is to be optimised to ensure stable, good quality connections between the sensor chips and the FPCs. To test the long-term stability of the connections, as well as study the effects on hit thresholds and noise in the sensor, it was thermally cycled in a climate chamber 1200 times. The soldered connections showed good qualities like even melting and good adhesion on pad/flex surfaces, and the chip remained in working condition for 1080 cycles. After this, a few connections failed, having cracks in the soldering tin, rendering the chip unusable. Threshold and noise characteristics seemed stable, except for the noise levels of sector 2 in the chip, for 1000 cycles in a temperature interval of "10^{\\circ}" and "50^{\\circ}" C. Still, further testing with wider temperature ranges and more cycles is needed to test the limitations of the chi...

  5. Optimisation of a Kalina cycle for a central receiver solar thermal power plant with direct steam generation

    DEFF Research Database (Denmark)

    Modi, Anish; Haglind, Fredrik

    2014-01-01

    Central receiver solar thermal power plants are regarded as one of the promising ways to generate electricity in near future. They offer the possibility of using high temperatures and pressures to achieve high efficiencies with standard power cycles. A direct steam generation approach can be used...... for a central receiver solar thermal power plant with direct steam generation. The variation in the cycle performance with respect to the turbine inlet ammonia mass fraction and pressure and a comparison of the initial investment with that of the basic Rankine cycle are also presented. Only high live steam...... for such plants for improved performance. This approach can also be combined with using advanced power cycles like the Kalina cycle, which uses a zeotropic mixture of ammonia and water instead of pure water as the working fluid. This paper presents the optimisation of a particular Kalina cycle layout...

  6. Effect of thermal radiation and suction on convective heat transfer of nanofluid along a wedge in the presence of heat generation/absorption

    Energy Technology Data Exchange (ETDEWEB)

    Kasmani, Ruhaila Md; Bhuvaneswari, M. [Centre for Foundation Studies in Science, University of Malaya, 50603 Kuala Lumpur (Malaysia); Sivasankaran, S.; Siri, Zailan [Institute of Mathematical Science, University of Malaya, 50603 Kuala Lumpur (Malaysia)

    2015-10-22

    An analysis is presented to find the effects of thermal radiation and heat generation/absorption on convection heat transfer of nanofluid past a wedge in the presence of wall suction. The governing partial differential equations are transformed into a system of ordinary differential equations using similarity transformation. The resulting system is solved numerically using a fourth-order Runge–Kutta method with shooting technique. Numerical computations are carried out for different values of dimensionless parameters to predict the effects of wedge angle, thermophoresis, Brownian motion, heat generation/absorption, thermal radiation and suction. It is found that the temperature increases significantly when the value of the heat generation/absorption parameter increases. But the opposite observation is found for the effect of thermal radiation.

  7. The effect of thermal cycling on the shear bond strength of porcelain/Ti-6Al-4V interfaces.

    Science.gov (United States)

    Sendão, Isabel A; Alves, Alexandra C; Galo, Rodrigo; Toptan, Fatih; Silva, Filipe S; Ariza, Edith

    2015-04-01

    The aim of the study was to evaluate the effect of thermal cycling on the shear bond strength of the porcelain/Ti-6Al-4V interfaces prepared by two different processing routes and metallic surface conditions. Polished and SiO2 particle abraded Ti-6Al-4V alloy and Triceram bonder porcelain were used to produce the interfaces. Porcelain-to-metal specimens were processed by conventional furnace firing and hot pressing. Thermal cycling was performed in Fusayama's artificial saliva for 5000 cycles between 5 ± 1 and 60 ± 2°C. After thermal cycling, shear bond tests were carried out by using a custom-made stainless steel apparatus. The results were analyzed using t-Student test and non-parametric Kruskal-Wallis test (p<0.01). Most of the polished-fired specimens were fractured during thermal cycling; thus, it was not possible to obtain the shear bond strength results for this group. Sandblasted-fired, polished-hot pressed, and sandblasted-hot pressed specimens presented the shear bond strength values of 76.2 ± 15.9, 52.2 ± 23.6, and 59.9 ± 22.0 MPa, respectively. Statistical analysis indicated that thermal cycling affected the polished specimens processed by firing, whereas a significant difference was not observed on the other groups. Copyright © 2015 Elsevier Ltd. All rights reserved.

  8. Effect of Thermal Cycle on the Formation of Intermetallic Compounds in Laser Welding of Aluminum-Steel Overlap Joints

    Science.gov (United States)

    Fan, J.; Thomy, C.; Vollertsen, F.

    The intermetallic compound (IMC) (or intermetallic phase layer) has a significant influence on the mechanical properties ofjoints between dissimilar metals obtained by thermal processes such as laser welding. Its formation is basically affected by thermal cycles in the joining or contact zone, where the IMC is formed. Within this study, the influence of the thermal cycle on the formation of the IMC during laser welding of an aluminum-steel (Al99.5-DC01) overlap joint was investigated. The temperature was measured directly by a thermocouple, and the weld seam was analyzed by scanning electron microscope (SEM). The influence of peak temperature, cooling time and the integral of the thermal cycle on the thickness of the IMC was identified and discussed. It was identified that cooling time has the biggest influence on the thickness of the IMC.

  9. Thermal Impact of Operating Conditions on the Performance of a Combined Cycle Gas Turbine

    Directory of Open Access Journals (Sweden)

    Thamir K. Ibrahim

    2012-08-01

    Full Text Available The combined cycle gas-turbine (CCGT power plant is a highly developed technology which generates electricalpower at high efficiencies. The first law of thermodynamics is used for energy analysis of the performance of theCCGT plant. The effects of varying the operating conditions (ambient temperature, compression ratio, turbine inlettemperature, isentropic compressor and turbine efficiencies, and mass flow rate of steam on the performance of theCCGT (overall efficiency and total output power were investigated. The programming of the performance model forCCGT was developed utilizing MATLAB software. The simulation results for CCGT show that the overall efficiencyincreases with increases in the compression ratio and turbine inlet temperature and with decreases in ambienttemperature. The total power output increases with increases in the compression ratio, ambient temperature, andturbine inlet temperature. The peak overall efficiency was reached with a higher compression ratio and low ambienttemperature. The overall efficiencies for CCGT were very high compared to the thermal efficiency of GT plants. Theoverall thermal efficiency of the CCGT quoted was around 57%; hence, the compression ratios, ambient temperature,turbine inlet temperature, isentropic compressor and turbine efficiencies, and mass flow rate of steam have a stronginfluence on the overall performance of the CCGT cycle.

  10. Theoretical and experimental analysis of the vacuum pressure in a vacuum glazing after extreme thermal cycling

    Energy Technology Data Exchange (ETDEWEB)

    Fang, Yueping; Hyde, Trevor; Hewitt, Neil [Centre for Sustainable Technologies, School of the Built Environment, University of Ulster, Newtownabbey, BT37 0QB N. Ireland (United Kingdom); Eames, Philip C. [Centre for Renewable Energy Research, University of Loughborough (United Kingdom)

    2009-09-15

    Details of theoretical and experimental studies of the change in vacuum pressure within a vacuum glazing after extreme thermal cycling are presented. The vacuum glazing was fabricated at low temperature using an indium-copper-indium edge seal. It comprised two 4 mm thick 0.4 m by 0.4 m glass panes with low-emittance coatings separated by an array of stainless steel support pillars spaced at 25 mm with a diameter of 0.4 mm and a height of 0.15 mm. Thermal cycling tests were undertaken in which the air temperature on one side of the sample was taken from -30 C to +50 C and back to -30 C 15 times while maintaining an air temperature of 22 C on the other side. After this test procedure, it was found that the glass to glass heat conductance at the centre glazing area had increased by 10.1% from which the vacuum pressure within the evacuated space was determined to have increased from the negligible level of less than 0.1 Pa to 0.16 Pa using the model of Corrucini. Previous research has shown that if the vacuum pressure is less than 0.1 Pa, the effect of conduction through the residual gas on the total glazing heat transfer is negligible. The degradation of vacuum level determined was corroborated by the change in glass surface temperatures. (author)

  11. Laser High-Cycle Thermal Fatigue of Pulse Detonation Engine Combustor Materials Tested

    Science.gov (United States)

    Zhu, Dong-Ming; Fox, Dennis S.; Miller, Robert A.

    2001-01-01

    Pulse detonation engines (PDE's) have received increasing attention for future aerospace propulsion applications. Because the PDE is designed for a high-frequency, intermittent detonation combustion process, extremely high gas temperatures and pressures can be realized under the nearly constant-volume combustion environment. The PDE's can potentially achieve higher thermodynamic cycle efficiency and thrust density in comparison to traditional constant-pressure combustion gas turbine engines (ref. 1). However, the development of these engines requires robust design of the engine components that must endure harsh detonation environments. In particular, the detonation combustor chamber, which is designed to sustain and confine the detonation combustion process, will experience high pressure and temperature pulses with very short durations (refs. 2 and 3). Therefore, it is of great importance to evaluate PDE combustor materials and components under simulated engine temperatures and stress conditions in the laboratory. In this study, a high-cycle thermal fatigue test rig was established at the NASA Glenn Research Center using a 1.5-kW CO2 laser. The high-power laser, operating in the pulsed mode, can be controlled at various pulse energy levels and waveform distributions. The enhanced laser pulses can be used to mimic the time-dependent temperature and pressure waves encountered in a pulsed detonation engine. Under the enhanced laser pulse condition, a maximum 7.5-kW peak power with a duration of approximately 0.1 to 0.2 msec (a spike) can be achieved, followed by a plateau region that has about one-fifth of the maximum power level with several milliseconds duration. The laser thermal fatigue rig has also been developed to adopt flat and rotating tubular specimen configurations for the simulated engine tests. More sophisticated laser optic systems can be used to simulate the spatial distributions of the temperature and shock waves in the engine. Pulse laser high-cycle

  12. Degradation in Mechanical and Thermal Properties of Partially Aligned CNT/Epoxy Composites due to Seawater Absorption

    Science.gov (United States)

    Saha, Sunirmal; Bal, Smrutisikha

    2017-02-01

    This literature gives an overview of the effect of water uptake on the mechanical and thermal performances of partially aligned carbon nanotube (CNT)/ epoxy (having CNTs wt.%: 0.5, 0.75 and 1) along with pure epoxy composites. Weight change behaviour of all the composites immersed in seawater for a period of six months has been recorded. The state of CNT/matrix interface is believed to be influenced due to water absorption. Reduction in flexural modulus, strength, hardness and glass transition temperature (Tg ) of the specimens have been evaluated as compared to their unexposed counterparts due to adverse effect of water absorption. Results demonstrated 35-46% reduction in flexural modulus, 43-56% decrement in flexural strength, 4-7 MPa reduction in hardness and minor deterioration in Tg values for all the composites. However, the specimen having 0.75 wt.% CNT loading, exhibited minimum reduction in properties in all aspects compared to others. Scanning electron microscopy (SEM) has been employed to study the failure mechanism of the specimens after performing the mechanical tests.

  13. Modeling electrical power absorption and thermally-induced biological tissue damage.

    Science.gov (United States)

    Zohdi, T I

    2014-01-01

    This work develops a model for thermally induced damage from high current flow through biological tissue. Using the first law of thermodynamics, the balance of energy produced by the current and the energy absorbed by the tissue are investigated. The tissue damage is correlated with an evolution law that is activated upon exceeding a temperature threshold. As an example, the Fung material model is used. For certain parameter choices, the Fung material law has the ability to absorb relatively significant amounts of energy, due to its inherent exponential response character, thus, to some extent, mitigating possible tissue damage. Numerical examples are provided to illustrate the model's behavior.

  14. Rapid freeze-drying cycle optimization using computer programs developed based on heat and mass transfer models and facilitated by tunable diode laser absorption spectroscopy (TDLAS).

    Science.gov (United States)

    Kuu, Wei Y; Nail, Steven L

    2009-09-01

    Computer programs in FORTRAN were developed to rapidly determine the optimal shelf temperature, T(f), and chamber pressure, P(c), to achieve the shortest primary drying time. The constraint for the optimization is to ensure that the product temperature profile, T(b), is below the target temperature, T(target). Five percent mannitol was chosen as the model formulation. After obtaining the optimal sets of T(f) and P(c), each cycle was assigned with a cycle rank number in terms of the length of drying time. Further optimization was achieved by dividing the drying time into a series of ramping steps for T(f), in a cascading manner (termed the cascading T(f) cycle), to further shorten the cycle time. For the purpose of demonstrating the validity of the optimized T(f) and P(c), four cycles with different predicted lengths of drying time, along with the cascading T(f) cycle, were chosen for experimental cycle runs. Tunable diode laser absorption spectroscopy (TDLAS) was used to continuously measure the sublimation rate. As predicted, maximum product temperatures were controlled slightly below the target temperature of -25 degrees C, and the cascading T(f)-ramping cycle is the most efficient cycle design. In addition, the experimental cycle rank order closely matches with that determined by modeling.

  15. Thermal analysis of a Phase Change Material for a Solar Organic Rankine Cycle

    Science.gov (United States)

    Iasiello, M.; Braimakis, K.; Andreozzi, A.; Karellas, S.

    2017-11-01

    Organic Rankine Cycle (ORC) is a promising technology for low temperature power generation, for example for the utilization of medium temperature solar energy. Since heat generated from solar source is variable throughout the day, the implementation of Thermal Energy Storage (TES) systems to guarantee the continuous operation of solar ORCs is a critical task, and Phase Change Materials (PCM) rely on latent heat to store large amounts of energy. In the present study, a thermal analysis of a PCM for a solar ORC is carried out. Three different types of PCMs are analyzed. The energy equation for the PCM is modeled by using the heat capacity method, and it is solved by employing a 1Dexplicit finite difference scheme. The solar source is modeled with a time-variable temperature boundary condition, with experimental data taken from the literature for two different solar collectors. Results are presented in terms of temperature profiles and stored energy. It has been shown that the stored energy depends on the heat source temperature, on the employed PCM and on the boundary conditions. It has been demonstrated that the use of a metal foam can drastically enhance the stored energy due to the higher overall thermal conductivity.

  16. Computational fluid dynamic (CFD) investigation of thermal uniformity in a thermal cycling based calibration chamber for MEMS

    Science.gov (United States)

    Gui, Xulong; Luo, Xiaobing; Wang, Xiaoping; Liu, Sheng

    2015-12-01

    Micro-electrical-mechanical system (MEMS) has become important for many industries such as automotive, home appliance, portable electronics, especially with the emergence of Internet of Things. Volume testing with temperature compensation has been essential in order to provide MEMS based sensors with repeatability, consistency, reliability, and durability, but low cost. Particularly, in the temperature calibration test, temperature uniformity of thermal cycling based calibration chamber becomes more important for obtaining precision sensors, as each sensor is different before the calibration. When sensor samples are loaded into the chamber, we usually open the door of the chamber, then place fixtures into chamber and mount the samples on the fixtures. These operations may affect temperature uniformity in the chamber. In order to study the influencing factors of sample-loading on the temperature uniformity in the chamber during calibration testing, numerical simulation work was conducted first. Temperature field and flow field were simulated in empty chamber, chamber with open door, chamber with samples, and chamber with fixtures, respectively. By simulation, it was found that opening chamber door, sample size and number of fixture layers all have effects on flow field and temperature field. By experimental validation, it was found that the measured temperature value was consistent with the simulated temperature value.

  17. Effect of Tube Arrangement on the Thermal Performance of a High Temperature Generator of the Absorption System

    Science.gov (United States)

    Lee, Insong; Cho, Keumnam

    The present study numerically investigated the effect of tube arrangement on the thermal performance of the high temperature generator (HTG) of a double effect LiBr-water absorption system with the cooling capacity of 210 refrigeration tons. The HTG tubes were located behind the pre-mixed surface flame burner. The HTG was consisted with a set of circular tubes and flattened tubes in series. LiBr aqueous weak solution was flowed into the HTG tube, and then turned to strong solution at the exit of the HTG tube. FLUENT, as a commercial code, was used to estimate the thermal performance of the HTG. Standard k-ɛ model was applied for the turbulent flow of combustion gas around the HTG tubes. Key parameters were the diameter of the circular tube and tube pitch ratio of flattened and circular tubes in the HTG. The combustion gas temperature was increased and its heat transfer rate was decreased as the circular tube diameter was increased, and the pitch ratios of both circular and flattened were decreased.

  18. Exergy analysis of heat exchangers in the copper-chlorine thermochemical cycle to enhance thermal effectiveness and cycle efficiency

    National Research Council Canada - National Science Library

    Orhan, Mehmet F; Dincer, Ibrahim; Rosen, Marc A

    2011-01-01

    .... For this temperature level, the copper-chlorine (Cu-Cl) cycle is one of the most promising cycles that can be integrated with nuclear reactors for hydrogen production by decomposing water into its constituents...

  19. Characterization of tin crystal orientation evolution during thermal cycling in lead-free solder joints

    Science.gov (United States)

    Zhou, Bite

    To address the long term reliability of lead-free solder joints in electronic devices during thermal cycling, the fundamental understanding of deformation mechanisms was studied using polarized light optical microscopy (PLM), electron backscatter diffraction (EBSD) in scanning electron microscopy (SEM), and synchrotron X-ray diffraction (XRD). Near-eutectic Sn-3.0(wt %) Ag-0.5(wt %) Cu (SAC305) lead-free solder joints were assessed in three different package designs: low-strain plastic ball grid array (PBGA), medium-strain fine-pitch ball grid array (BGA), and high-strain wafer-level-chip-scale package (WLCSP). The effect of microstructure evolution on solder failure is correlated with dislocation slip activities. The major failure mode in lead-free solder joints during thermal cycling that causes the electrical failure of the device is cracking in the bulk Sn near the Si chip/solder interface. Microstructure and Sn grain orientation evolution usually precedes crack development. A combined approach of both statistical analysis of a large number of solder joints, and detailed studies of individual solder balls was used to investigate the causes of fracture. Sn crystal orientation evolution and its effect on deformation was characterized in solder joints with different thermal histories, and compared with those from other package designs with different effective strain levels. The relationship between the initial dominant and localized recrystallized Sn grain orientations on crack development was investigated. It is found that in the low-strain package design, cracking is strongly correlated with Sn grain orientations with the [001] direction (c-axis) nearly aligned with the chip/solder interface. But no cracks were observed in solder balls with dominant orientations that have the c-axis normal to the interface plane. In higher-strain packages, however, cracking occurred in a variety of Sn grain orientations, and even solder balls with dominant orientations that are

  20. Influence of different treatments of the ceramic surface and thermal cycling on the bond strength of brackets to ceramic

    Directory of Open Access Journals (Sweden)

    Fernando Guerra SÁEZ

    Full Text Available Abstract Objective To evaluate in vitro the effect of different treatments of the ceramic surface and thermal cycling on the shear bond strength (SBS of metallic brackets bonded to feldspathic ceramic. Material and method Ceramic cylinders were divided into four groups (n=4 according to the treatment of ceramic surface: G1-Clearfil Ceramic Primer silane and Transbond XT (CCPT; G2-etched with 10% hydrofluoric acid (HFA for 60 s, CCP and Transbond XT (ACCPT; G3-etched with 10% HFA for 60 s, Ambar Adhesive and Transbond XT (AAAT; and, G4 - etched with 10% HFA for 60 s, RelyX Ceramic Primer silane -RCP, adhesive primer Transbond and Transbond XT (ACPPT. Brackets were bonded to the cylinders with Transbond XT and light-activated for 40 s with LED Radii Plus. All specimens were stored in deionized water at 37 °C for 24 h, and two cylinders from each group were subject to 7,000 thermal cycles in a thermal cycler (5 °C/55 °C. After storage and thermal cycling, the SBS test was performed at a crosshead speed of 1 mm/min. Data were subjected to two-way ANOVA and Tukey’s post hoc test (α=0.05. Result The SBS of ACCPT was significantly higher than the other groups (p<0.05. The specimens submitted to thermal cycling showed significantly lower SBS than those without thermal cycling (p<0.05, regardless the ceramic surface treatment. The ARI showed predominance of score 0 for all groups. Conclusion Acid etching, CCP silane and Transbond XT method obtained the best results for bracket bonding. Thermal cycling reduced SBS for all groups. Score 0 was predominant for ARI in all groups.

  1. Measuring Thermal Conductivity and Moisture Absorption of Cryo-Insulation Materials

    Science.gov (United States)

    Lambert, Michael A.

    1998-01-01

    NASA is seeking to develop thermal insulation material systems suitable for withstanding both extremely high temperatures encountered during atmospheric re-entry heating and aero- braking maneuvers, as well as extremely low temperatures existing in liquid fuel storage tanks. Currently, materials used for the high temperature insulation or Thermal Protection System (TPS) are different from the low temperature, or cryogenic insulation. Dual purpose materials are necessary to the development of reusable launch vehicles (RLV). The present Space Shuttle (or Space Transportation System, STS) employs TPS materials on the orbiter and cryo-insulation materials on the large fuel tank slung under the orbiter. The expensive fuel tank is jettisoned just before orbit is achieved and it burns up while re-entering over the Indian Ocean. A truly completely reusable launch vehicle must store aR cryogenic fuel internally. The fuel tanks will be located close to the outer surface. In fact the outer skin of the craft will probably also serve as the fuel tank enclosure, as in jet airliners. During a normal launch the combined TPS/cryo-insulation system will serve only as a low temperature insulator, since aerodynamic heating is relatively minimal during ascent to orbit. During re-entry, the combined TPS/cryo-insulation system will serve only as a high temperature insulator, since all the cryogenic fuel will have been expended in orbit. However, in the event of an.aborted launch or a forced/emergency early re-entry, the tanks will still contain fuel, and the TPS/cryo-insulation will have to serve as both low and high temperature insulation. Also, on long duration missions, such as to Mars, very effective cryo-insulation materials are needed to reduce bod off of liquid propellants, thereby reducing necessary tankage volume, weight, and cost. The conventional approach to obtaining both low and high temperature insulation, such as is employed for the X-33 and X-34 spacecraft, is to use

  2. New Triplet Sensitization Routes for Photon Upconversion: Thermally Activated Delayed Fluorescence Molecules, Inorganic Nanocrystals, and Singlet-to-Triplet Absorption.

    Science.gov (United States)

    Yanai, Nobuhiro; Kimizuka, Nobuo

    2017-10-17

    Photon upconversion based on triplet-triplet annihilation (TTA-UC) has attracted much interest because of its possible applications to renewable energy production and biological fields. In particular, the UC of near-infrared (NIR) light to visible (vis) light is imperative to overcome the Shockley-Queisser limit of single-junction photovoltaic cells, and the efficiency of photocatalytic hydrogen production from water can also be improved with the aid of vis-to-ultraviolet (UV) UC. However, both processes have met limitations in the wavelength range, efficiency, and sensitivity for weak incident light. This Account describes recent breakthroughs that solve these major problems, new triplet sensitization routes to significantly enlarge the range of conversion wavelength by minimizing the energy loss during intersystem crossing (ISC) of triplet sensitizers or bypassing the ISC process. The photochemical processes of TTA-UC in general start with the absorption of longer wavelength incident light by triplet sensitizers, which generate the triplet states via ISC. This ISC inevitably accompanies the energy loss of hundreds of millielectronvolts, which significantly limits the TTA-UC with large anti-Stokes shifts. The small S1-T1 gap of molecules showing thermally activated delayed fluorescence (TADF) allows the sensitization of emitters with the highest T1 and S1 energy levels ever employed in TTA-UC, which results in efficient vis-to-UV UC. As alternatives to molecular sensitizers in the NIR region, inorganic nanocrystals with broad NIR absorption bands have recently been shown to work as effective sensitizers for NIR-to-vis TTA-UC. Their small exchange splitting minimizes the energy loss during triplet sensitization. The modification of nanocrystal surfaces with organic acceptors via coordination bonds allows efficient energy transfer between the components and succeeding TTA processes. To remove restrictions on the energy loss during ISC, molecules with direct singlet

  3. Fast thermal cycling of acetanilide and magnesium chloride hexahydrate for indoor solar cooking

    Energy Technology Data Exchange (ETDEWEB)

    El-Sebaii, A.A.; Al-Amir, S.; Al-Marzouki, F.M.; Faidah, Adel S.; Al-Ghamdi, A.A.; Al-Heniti, S. [Physics Dept., Faculty of Science, King Abdul Aziz Univ., P.O. Box 80203, Jeddah 21589 (Saudi Arabia)

    2009-12-15

    Solar cookers are broadly divided into a direct or focusing type, indirect or box-type and advanced solar cookers. The focusing and box-type solar cookers are for outdoor applications. The advanced solar cookers have the advantage of being usable indoors and thus solve one of the problems, which impede the social acceptance of solar cookers. The advanced type solar cookers are employing additional solar units that increase the cost. Therefore, the solar cooker must contain a heat storage medium to store thermal energy for use during off-sunshine hours. The main aim of this study is to investigate the influence of the melting/solidification fast cycling of the commercial grade acetanilide C{sub 8}H{sub 9}NO (T{sub m} = 116 C) and magnesium chloride hexahydrate MgCl{sub 2}.6H{sub 2}O (T{sub m} = 116.7 C) on their thermo-physical properties; such as melting point and latent heat of fusion, to be used as storage media inside solar cookers. Five hundred cycles have been performed. The thermo-physical properties are measured using the differential scanning calorimetric technique. The compatibility of the selected phase change materials (PCMs) with the containing material is also studied via the surface investigation, using the SIM technique, of aluminum and stainless steel samples embedded in the PCM during cycling. It is inferred that acetanilide is a promising PCM for cooking indoors and during low intensity solar radiation periods with good compatibility with aluminum as a containing material. However, MgCl{sub 2}.6H{sub 2}O is not stable during its thermal cycling (even with the extra water principle) due to the phase segregation problem; therefore, it is not recommended as a storage material inside solar cookers for cooking indoors. It is also indicated that MgCl{sub 2}.6H{sub 2}O is not compatible with either aluminum or stainless steel. (author)

  4. Effect of AgCl NPs: Physical, thermal, absorption and luminescence properties

    Science.gov (United States)

    Nurhafizah, H.; Rohani, M. S.

    2017-06-01

    Silver nanoparticles (AgCl NPs) are embedded in Er3+/Nd3+ co-doped lithium niobate tellurite glasses of the form (68-x)TeO2-15Li2CO3-15Nb2O5-1Er2O3-1Nd2O3-(x)AgCl with x = 1,2 and 3 mol% via conventional melt-quenching technique. The physical properties such as density, ionic packing density, refractive index and electronic polarizability are computed utilizing the usual method. The existence of AgCl NPs with an average size of 3.7 nm is confirmed using TEM analysis. Moreover, the thermal stability and Hruby criterion of the glass decreases as the AgCl NPs content increases. The direct optical band gap are found decrease as the AgCl NPs content increase, but both indirect optical band gap and Urbach energy are found increases as AgCl NPs content increases. The luminescence spectra shows two strong emission which is the purple emission at 436 nm and red emission at 724 nm which also been observed has strong quenching due to the AgCl NPs, Er3+/Nd3+ dopant and modifier, lithium niobate which possessed magnetic penetration. These glass compositions may be potential for various applications such as solid state devices including laser.

  5. Effects of thermal cycling on surface roughness, hardness and flexural strength of polymethylmethacrylate and polyamide denture base resins.

    Science.gov (United States)

    Ayaz, Elif Aydoğan; Bağış, Bora; Turgut, Sedanur

    2015-10-16

    The purpose of this study was to evaluate the effects of thermal cycling on the surface roughness, hardness and flexural strength of denture resins. Polyamide (PA; Deflex and Valplast) and polymethylmethacrylate (PMMA; QC-20 and Acron MC) denture materials were selected. A total of 180 specimens were fabricated and then divided into 3 groups. The first group (group 1) acted as a control and was not thermocycled. The second group (group 2) was subjected to thermocycling for 10,000 cycles in artificial saliva and 5,000 cycles in distilled water. The last group (group 3) was thermocycled for 20,000 cycles in artificial saliva and 10,000 cycles in distilled water. The surface roughness were measured with a profilometer. The hardness of the resins were measured with a Vickers Hardness Tester using a 100-gf load. The flexural strength test was performed using the universal test machine with a crosshead speed of 5 mm/min. Data were analyzed using statistical software. The results of the measurements in the 3 different tests were analyzed by Kruskal-Wallis test with Bonferroni correction. Multiple comparisons were made by Conover and Wilcoxon tests. There was a significant difference between the PMMA and PA groups in terms of surface roughness, hardness and transverse strength before and after thermal cycling (p<0.001). Thermal cycling did not change the surface roughness, hardness and flexural strength values of either the PMMA or PA group (p>0.001).

  6. An expression for the atomic fluorescence and thermal-emission intensity under conditions of near saturation and arbitrary self-absorption

    NARCIS (Netherlands)

    Omenetto, N.; Winefordner, J.D.; Alkemade, C.T.J.

    An expression for the effect of self-absorption on the fluorescence and thermal emission intensities is derived by taking into account stimulated emission. A simple, idealized case is considered, consisting of a two level atomic system, in a flame, homogeneous with respect to temperature and

  7. THERMAL CYCLING UNDER LOADING OF SINGLE CRYSTAL Cu-Al-Ni AFTER AGING

    Directory of Open Access Journals (Sweden)

    Ignacio Corro

    2016-06-01

    Full Text Available In this paper, a study of single crystal Cu-14.3Al-4.1Ni (%wt subjected to thermal cycling under loading is presented. Shape memory Cu-Al-Ni has low diffusion at temperatures above room temperature. Therefore, it is interesting to know your answer in working conditions and after being aged in this temperature range. Specimens were characterized before and after aging, using a device designed by the authors. Parameters such as critical temperatures and hysteresis width, the repeatability of the curves and the type of TM induced were analyzed. These parameters have changes then the aging or contribute to that may influence the design of applications.

  8. Numerical analysis of energy piles under different boundary conditions and thermal loading cycles

    Directory of Open Access Journals (Sweden)

    Khosravi Ali

    2016-01-01

    Full Text Available The thermo- mechanical behavior of energy piles has been studied extensively in recent years. In the present study, a numerical model was adapted to study the effect of various parameters (e.g. heating/cooling temperature, head loading condition and soil stiffness on the thermo-mechanical behavior of an energy pile installed in unsaturated sandstone. The results from the simulations were compared with measurements from a thermal response test on a prototype energy pile installed beneath a 1-story building at the US Air Force Academy (USAFA in Colorado Springs, CO. A good agreement was achieved between the results obtained from the prototype and the numerical models. A parametric evaluation were also carried out which indicated the significance of the stiffness of the unsaturated sandstone and pile’s head loading condition on stress-strain response of the energy pile during heating/cooling cycles.

  9. Modeling of Thermal Cycle CI Engine with Multi-Stage Fuel Injection

    Directory of Open Access Journals (Sweden)

    Arkadiusz Jamrozik

    2017-09-01

    Full Text Available This work presents a complete thermal cycle modeling of a four-stroke diesel engine with a three-dimensional simulation program CFD - AVL Fire. The object of the simulation was the S320 Andoria engine. The purpose of the study was to determine the effect of fuel dose distribution on selected parameters of the combustion process. As a result of the modeling, time spatial pressure distributions, rate of pressure increase, heat release rate and NO and soot emission were obtained for 3 injection strategies: no division, one pilot dose and one main dose and two pilot doses and one main dose. It has been found that the use of pilot doses on the one hand reduces engine hardness and lowers NO emissions and on the other hand, increases soot emissions.

  10. Personal, closed-cycle cooling and protective apparatus and thermal battery therefor

    Science.gov (United States)

    Klett, James W.; Klett, Lynn B.

    2004-07-20

    A closed-cycle apparatus for cooling a living body includes a heat pickup body or garment which permits evaporation of an evaporating fluid, transmission of the vapor to a condenser, and return of the condensate to the heat pickup body. A thermal battery cooling source is provided for removing heat from the condenser. The apparatus requires no external power and provides a cooling system for soldiers, race car drivers, police officers, firefighters, bomb squad technicians, and other personnel who may utilize protective clothing to work in hostile environments. An additional shield layer may simultaneously provide protection from discomfort, illness or injury due to harmful atmospheres, projectiles, edged weapons, impacts, explosions, heat, poisons, microbes, corrosive agents, or radiation, while simultaneously removing body heat from the wearer.

  11. Life cycle assessment of thermal Waste-to-Energy technologies: Review and recommendations

    DEFF Research Database (Denmark)

    Astrup, Thomas Fruergaard; Tonini, Davide; Turconi, Roberto

    2015-01-01

    -studies published in 136 peer-reviewed journal articles within 1995 and 2013. The studies were evaluated with respect to critical aspects such as: (i) goal and scope definitions (e.g. functional units, system boundaries, temporal and geographic scopes), (ii) detailed technology parameters (e.g. related to waste...... composition, technology, gas cleaning, energy recovery, residue management, and inventory data), and (iii) modeling principles (e.g. energy/mass calculation principles, energy substitution, inclusion of capital goods and uncertainty evaluation). Very few of the published studies provided full and transparent......Life cycle assessment (LCA) has been used extensively within the recent decade to evaluate the environmental performance of thermal Waste-to-Energy (WtE) technologies: incineration, co-combustion, pyrolysis and gasification. A critical review was carried out involving 250 individual case...

  12. The Effect of Thermal Cycling on Crystal-Liquid Separation During Lunar Magma Ocean Differentiation

    Science.gov (United States)

    Mills, Ryan D.

    2013-01-01

    Differentiation of magma oceans likely involves a mixture of fractional and equilibrium crystallization [1]. The existence of: 1) large volumes of anorthosite in the lunar highlands and 2) the incompatible- rich (KREEP) reservoir suggests that fractional crystallization may have dominated during differentiation of the Moon. For this to have occurred, crystal fractionation must have been remarkably efficient. Several authors [e.g. 2, 3] have hypothesized that equilibrium crystallization would have dominated early in differentiation of magma oceans because of crystal entrainment during turbulent convection. However, recent numerical modeling [4] suggests that crystal settling could have occurred throughout the entire solidification history of the lunar magma ocean if crystals were large and crystal fraction was low. These results indicate that the crystal size distribution could have played an important role in differentiation of the lunar magma ocean. Here, I suggest that thermal cycling from tidal heating during lunar magma ocean crystallization caused crystals to coarsen, leading to efficient crystal-liquid separation.

  13. Effect of Microstructural Evolution on Sagging Behavior of Cold-Rolled Aluminum Foil During the Brazing Thermal Cycle

    Science.gov (United States)

    Liu, Canwei; Xue, Xili; Chen, Xin; Li, Long; Xia, Chengdong; Zhong, Zhaojun; Zhou, Dejing

    2017-11-01

    Effect of microstructural evolution on sagging behavior of aluminum foil was investigated during the brazing thermal cycle. During the brazing thermal cycle, the sagging behavior consists of three stages: slight sagging stage, accelerative sagging stage and slow sagging stage. The sagging of cold-rolled aluminum foil mainly occurs in the accelerative sagging stage, which is governed by recovery under external stress in the sagging test. The coarse recrystallized grain is responsible for the slow sagging stage by reducing grain boundary sliding. Increasing cold-rolled reduction and addition of final annealing heat treatment can improve sagging resistance by shortening recovery process during the brazing thermal cycle. Dissolution of dispersoids has few effects on sagging deformation.

  14. Simultaneous measurement of thermal diffusivity and effective infrared absorption coefficient in IR semitransparent and semiconducting n-CdMgSe crystals using photothermal radiometry

    Energy Technology Data Exchange (ETDEWEB)

    Pawlak, M., E-mail: mpawlak@fizyka.umk.pl [Institute of Physics, Faculty of Physics, Astronomy and Informatics, Nicolaus Copernicus University, Grudziądzka 5/7, Toruń (Poland); Maliński, M. [Department of Electronics and Computer Science, Koszalin University of Technology, 2 Śniadeckich St., Koszalin 75-453 (Poland)

    2015-01-10

    Highlights: • The new method of determination of the effective infrared absorption coefficient is presented. • The method can be used for transparent samples for the excitation radiation. • The effect of aluminum foil on the PTR signal in a transmission configuration is discussed. - Abstract: In this paper we propose a new procedure of simultaneous estimation of the effective infrared optical absorption coefficient and the thermal diffusivity of solid state samples using the photothermal infrared radiometry method in the transmission configuration. The proposed procedure relies on the analysis of the frequency dependent signal obtained from the samples covered with thin aluminum foil. This method can be applied for both optically opaque and transparent samples. The proposed method is illustrated with the results of the thermal diffusivity and the effective IR absorption coefficient obtained for several Cd{sub 1−x}Mg{sub x}Se crystals.

  15. Fundamental-frequency and load-varying thermal cycles effects on lifetime estimation of DFIG power converter

    DEFF Research Database (Denmark)

    Zhang, G.; Zhou, D.; Yang, J.

    2017-01-01

    In respect to a Doubly-Fed Induction Generator (DFIG) system, its corresponding time scale varies from microsecond level of power semiconductor switching to second level of the mechanical response. In order to map annual thermal profile of the power semiconductors, different approaches have been ...... adopted to handle the fundamental-frequency thermal cycles and load-varying thermal cycles. Their effects on lifetime estimation of the power device in the Back-to-Back (BTB) power converter are evaluated.......In respect to a Doubly-Fed Induction Generator (DFIG) system, its corresponding time scale varies from microsecond level of power semiconductor switching to second level of the mechanical response. In order to map annual thermal profile of the power semiconductors, different approaches have been...

  16. Effects of Thermal Cycling and Thermal Aging on the Hermeticity and Strength of Silver-Copper Oxide Air-Brazed Seals

    Energy Technology Data Exchange (ETDEWEB)

    Weil, K. Scott; Coyle, Christopher A.; Darsell, Jens T.; Xia, Gordon; Hardy, John S.

    2005-12-01

    Thermal cycle and exposure tests were conducted on ceramic-to-metal joints prepared by a new sealing technique. Known as reactive air brazing, this joining method is currently being considered for use in sealing various high-temperature solid-state electrochemical devices, including planar solid oxide fuel cells (pSOFC). In order to simulate a typical pSOFC application, test specimens were prepared by joining ceramic anode/electrolyte bilayers to washers, of the same composition as the common frame materials employed in pSOFC stacks, using a filler metal composed of 4mol% CuO in silver. The brazed samples were exposure tested at 750°C for 200, 400, and 800hrs in both simulated fuel and air environments and thermally cycled at rapid rate (75°C/min) between room temperature and 750°C for as many as fifty cycles. Subsequent joint strength testing and microstructural analysis indicated that the samples exposure tested in air displayed little degradation with respect to strength, hermeticity, or microstructure out to 800hrs of exposure. Those tested in fuel showed no change in rupture strength or loss in hermeticity after 800hrs of high-temperature exposure, but did undergo microstructural change due to the dissolution of hydrogen into the silver-based braze material. Air brazed specimens subjected to rapid thermal cycling exhibited no loss in joint strength or hermeticity, but displayed initial signs of seal delamination along the braze/electrolyte interface after 50 cycles.

  17. Effect of thermal cycle on the interfacial antiferromagnetic spin configuration and exchange bias in Ni-Mn-Sb alloy

    Directory of Open Access Journals (Sweden)

    R. L. Wang

    2012-09-01

    Full Text Available Effect of thermal cycle on the interfacial antiferromagnetic (AFM spin configuration and exchange bias in Ni50Mn36Sb14 alloy has been investigated. The results indicate thermal cycle can induce further martensitic transition from part of arrested FM phase to AFM phase, leading to the reconstruction of interfacial antiferromagnetic spin configuration. The shape of hysteresis loops at 5 K after cooling back can be tuned from a single-shifted loop to a nearly symmetric double-shifted loop gradually accompanied with exchange bias field increasing to peak value and then decreasing. The evolutions can be illustrated intuitively by a simple AFM bidomain model.

  18. Performance Evaluation of HP/ORC (Heat Pump/Organic Rankine Cycle) System with Optimal Control of Sensible Thermal Storage

    DEFF Research Database (Denmark)

    Do Carmo, Carolina Madeira Ramos; Dumont, Olivier; Nielsen, Mads Pagh

    2016-01-01

    energy in periods of no thermal energy demand and reverses the heat pump cycle to supply electrical power. A dynamic model based on empirical data of this system is used to determine the annual performance. Furthermore, this work assesses the benefits of different control strategies that address...... of the users. Results show that real load control logic can lessen the adverse effects of cycling in the compressor of the system as well as increase the thermal demand (up to 33%) and the electrical demand (max. 8.4%) covered by renewable energy (solar). However, the extension of these improvements is highly...

  19. Advanced Organic Vapor Cycles for Improving Thermal Conversion Efficiency in Renewable Energy Systems

    OpenAIRE

    Ho, Tony

    2012-01-01

    The Organic Flash Cycle (OFC) is proposed as a vapor power cycle that could potentially increase power generation and improve the utilization efficiency of renewable energy and waste heat recovery systems. A brief review of current advanced vapor power cycles including the Organic Rankine Cycle (ORC), the zeotropic Rankine cycle, the Kalina cycle, the transcritical cycle, and the trilateral flash cycle is presented. The premise and motivation for the OFC concept is that essentially by impro...

  20. The Effect of Thermal Cycling Treatments on the Thermal Stability and Mechanical Properties of a Ti-Based Bulk Metallic Glass Composite

    Directory of Open Access Journals (Sweden)

    Fan Bu

    2016-11-01

    Full Text Available The effect of thermal cycling treatments on the thermal stability and mechanical properties of a Ti48Zr20Nb12Cu5Be15 bulk metallic glass composite (BMGC has been investigated. Results show that moderate thermal cycles in a temperature range of −196 °C (cryogenic temperature, CT to 25 °C (room temperature, RT or annealing time at CT has not induced obvious changes of thermal stability and then it decreases slightly over critical thermal parameters. In addition, the dendritic second phases with a bcc structure are homogeneously embedded in the amorphous matrix; no visible changes are detected, which shows structural stability. Excellent mechanical properties as high as 1599 MPa yield strength and 34% plastic strain are obtained, and the yield strength and elastic modulus also increase gradually. The effect on the stability is analyzed quantitatively by crystallization kinetics and plastic-flow models, and indicates that the reduction of structural relaxation enthalpy, which is related to the degradation of spatial heterogeneity, reduces thermal stability but does not imperatively deteriorate the plasticity.

  1. Open cycle liquid desiccant dehumidifier and hybrid solar/electric absorption refrigeration system. Annual report, January 1993--December 1993. Calendar year 1993

    Energy Technology Data Exchange (ETDEWEB)

    Nimmo, B.G.; Thornbloom, M.D.

    1995-04-01

    This annual report presents work performed during calendar year 1993 by the Florida Solar Energy Center under contract to the US Department of Energy. Two distinctively different solar powered indoor climate control systems were analyzed: the open cycle liquid desiccant dehumidifier, and an improved efficiency absorption system which may be fired by flat plate solar collectors. Both tasks represent new directions relative to prior FSEC research in Solar Cooling and Dehumidification.

  2. Microleakage of self-etching primers after thermal and flexural load cycling.

    Science.gov (United States)

    Kubo, S; Yokota, H; Sata, Y; Hayashi, Y

    2001-06-01

    To evaluate the adhesive properties of a one-bottle self-etching primer system. 150 wedge-shaped cervical cavities on bovine teeth were restored with Clearfil Liner Bond 2 (LB), Clearfil Liner Bond 2V (LV) or Clearfil SE Bond (SE), according to the manufacturer's instructions. Twenty specimens of each adhesive system were finished 15 mins after light curing and 30 specimens were finished after a 24-hr storage period in water. From each group, 10 restorations were immediately immersed in 0.5% basic fuchsin solution and kept there for 24 hrs to examine microleakage. The other 10 restorations were thermocycled (5-60 degrees C, 15 s dwell time, 5,000 cycles), and then immersed in the dye solution. The remaining 10 specimens of the 24-hr storage group were subjected to flexural load cycling (0.5 mm labio-lingual displacement at the incisal edge, 10,000 cycles, 1 cps) prior to immersion in the dye solution. The data was analyzed using the Mann-Whitney U-test and the Kruskal-Wallis test. The tensile bond strengths of the adhesive systems to bovine enamel and dentin were also determined. The data was analyzed using the Student's t-test and ANOVA. In addition, SEM examinations were made to evaluate the effects of self-etching primers on enamel and dentin surfaces. LV and SE showed significantly better marginal sealing than LB (Pintegrity of SE did not deteriorate even after immediate finishing, thermal stresses or flexural loads. There were no significant differences in bond strengths among the adhesive systems tested. All adhesive systems showed similar bond strengths to enamel and dentin. The enamel etching patterns using LV and SE systems were obscure and difficult to assess. Although the smear plugs were not fully removed, no smear layer was observed on the treated dentin surfaces, regardless of the self-etching primer system used. Clearfil SE bond could possibly improve the clinical performance of cervical cavities.

  3. Fatigue life of fibre reinforced plastics at 295 K after thermal cycling between 295 K and 77 K

    Science.gov (United States)

    Belisario, G.; Caproni, F.; Marchetti, E.

    Results of low cycle three-point end fatigue tests at 295 K are reported. These were obtained from fibre reinforced plastics (FRP) flat specimens made of epoxy matrix reinforced with glass rovings only or glass rovings and Kevlar cloth. It is shown that previous thermal cycles between 295 K and 77 K exert an influence on the fatigue life as well on the acoustic emission results.

  4. On the performance of heat absorption/generation and thermal stratification in mixed convective flow of an Oldroyd-B fluid

    Directory of Open Access Journals (Sweden)

    Tasawar Hayat

    2017-12-01

    Full Text Available This investigation explores the thermally stratified stretchable flow of an Oldroyd-B material bounded by a linear stretched surface. Heat transfer characteristics are addressed through thermal stratification and heat generation/absorption. Formulation is arranged for mixed convection. Application of suitable transformations provides ordinary differential systems through partial differential systems. The homotopy concept is adopted for the solution of nonlinear differential systems. The influence of several arising variables on velocity and temperature is addressed. Besides this, the rate of heat transfer is calculated and presented in tabular form. It is noticed that velocity and Nusselt number increase when the thermal buoyancy parameter is enhanced. Moreover, temperature is found to decrease for larger values of Prandtl number and heat absorption parameter. Comparative analysis for limiting study is performed and excellent agreement is found.

  5. Volumetric Heat Generation and Consequence Raise in Temperature Due to Absorption of Neutrons from Thermal up to 14.9 MeV Energies

    CERN Document Server

    Massoud, E

    2003-01-01

    In this work, the heat generation rate and the consequence rise in temperature due to absorption of all neutrons from thermal energies (E<0.025) up to 14.9 MeV in water, paraffin wax, ordinary concrete and heavy concrete and heavy concrete as some selected hydrogenous materials are investigated. The neutron flux distributions are calculated by both ANISN-code and three group method in which the fast neutrons are expressed by the removal cross section concept while the other two groups (epithermal and thermal) are treated by the diffusion equation. The heat generation can be calculated from the neutron macroscopic absorption of each material or mixture multiplied by the corresponding neutron fluxes. The rise in temperature is then calculated by using both of the heat generation and the thermal conductivity of the selected materials. Some results are compared with the available experimental and theoretical data and a good agreement is achieved.

  6. Continental growth and mantle hydration as intertwined feedback cycles in the thermal evolution of Earth

    Science.gov (United States)

    Höning, Dennis; Spohn, Tilman

    2016-06-01

    A model of Earth's continental coverage and mantle water budget is discussed along with its thermal evolution. The model links a thermal evolution model based on parameterized mantle convection with a model of a generic subduction zone that includes the oceanic crust and a sedimentary layer as carriers of water. Part of the subducted water is used to produce continental crust while the remainder is subducted into the mantle. The total length of the subduction zones is calculated from the total surface area of continental crust assuming randomly distributed continents. The mantle viscosity is dependent of temperature and the water concentration. Sediments are generated by continental crust erosion, and water outgassing at mid-oceanic ridges closes the water cycle. We discuss the strongly coupled, non-linear model using a phase plane defined by the continental coverage and mantle water concentration. Fixed points are found in the phase plane at which the rates of change of both variables are zero. These fixed points evolve with time, but in many cases, three fixed points emerge of which two are stable and an intermediate point is unstable with respect to continental coverage. With initial conditions from a Monte-Carlo scheme we calculate evolution paths in the phase plane and find a large spread of final states that all have a mostly balanced water budget. The present day observed 40% continental surface coverage is found near the unstable fixed point. Our evolution model suggests that Earth's continental coverage formed early and has been stable for at least 1.5 Gyr. The effect of mantle water regassing (and mantle viscosity depending on water concentration) is found to lower the present day mantle temperature by about 120 K, but the present day mantle viscosity is affected little. The water cycle thus complements the well-known thermostat effect of viscosity and mantle temperature. Our results further suggest that the biosphere could impact the feedback cycles by

  7. Fused deposition modeling (FDM) fabricated part behavior under tensile stress, thermal cycling, and fluid pressure

    Science.gov (United States)

    Hossain, Mohammad Shojib

    using visual feedback method led to an increase in UTS of 16% in XYZ, 7% in XZY, and 22% in ZXY. The FDM fabricated parts using PC were tested under thermal cycling of -30° C to 85° C. A series of experiments were performed (e.g., tensile test, deformation of fabricated part, glass transition measurement) to evaluate the possibility of FDM fabricated parts in the harsh environment (embedded electronics, wiring in automotive industry, etc.). The UTS results showed that the results were not significantly different using statistical analysis after 150 thermal cycles while average Young's modulus increased from 1389 MPa to 1469 MPa after 150 thermal cycles. The highest warping of the specimen was found to be 78 microm which was the result of continuous thermal expansion and contraction. A sealing algorithm was developed using LabVIEW and MATLAB programming. The LabVIEW program was developed to obtain the edge information of each layer of a 3D model part. The MATLAB programming was used to gather the output information from LabVIEW and calculate the suggested RW providing least amount of gap in between rasters and contours. As a result, each layer became sealed and was able to withstand air pressure within a pressure vessel. A test specimen was fabricated according to the developed sealing algorithm parameters and used to show entirely sealed walls capable of withstanding up to 138 kPa air pressure.

  8. Investigation of a putative nitrogen cycle in a subsurface radioactive thermal spring

    Science.gov (United States)

    Gerbl, Friedrich; Breitfuss, Angelika; Weidler, Gerhard; Stan-Lotter, Helga

    2010-05-01

    Background: Previous studies on the microbial diversity [1] of the slightly radioactive thermal springs near Bad Gastein, Salzburg, Austria, suggested the occurrence of a nitrogen cycle in this subterranean environment. Microcosm experiments were performed to prove if nitrogen compounds may be used as energy sources for certain members of the microbial community of this spring Methods: 2 x 25 l of thermal mineral water were sampled and filtered through a 0.22 µm Stericup (Millipore). Filters were excised and used as inocula for one microcosm. Stable isotope probing (SIP), was performed by using labeled nitrogen compounds to identify microorganisms, which were able to use nitrogen as the only energy source. 2 x 35 ml of natural grown biofilm were collected and used also as inocula for microcosms. Incubation was carried out as batch cultures in the dark at 30 °C or 40 °C, respectively. Two different types of media were used for incubation. Ammonium, nitrite and nitrate were measured 3-4 times a week. PH-value was also measured and adjusted to ca. 7.5 - 7.7 if necessary. DNA extraction was performed after 3 and 8 weeks of incubation, followed by an isopycnic centrifugation step. Clone libraries were performed only from microcosms incubated at 40 °C. To compare putative differences between the microbial communities at 30 °C with those at 40 °C, as well as the two different media, DGGE analyses were carried out. Results: A continuous decrease of the initial amount of ammonium was detected while the amounts of nitrite and nitrate increased simultaneously. No alterations of the initial amount of ammonium and nitrite or nitrate, could be detected with negative controls. Mass spectrometric measurements demonstrated that the extracted DNA was highly labeled. Phylogenetic analysis of DNA bands obtained from CsCl gradients led to differences in archaeal and bacterial communities of microcosms, which may reflect the different composition of media. Two of the archaeal

  9. The effect of thermal cycling on the structure and properties of a Co, Cr, Ni-TaC directionally solidified eutectic composite

    Science.gov (United States)

    Dunlevey, F. M.; Wallace, J. F.

    1973-01-01

    The effect of thermal cycling on the structure and properties of a cobalt, chromium, nickel, tantalum carbide directionally solidified eutectic composite is reported. It was determined that the stress rupture properties of the alloy were decreased by the thermal cycling. The loss in stress rupture properties varied with the number of cycles with the loss in properties after about 200 cycles being relatively high. The formation of serrations and the resulting changes in the mechanical properties of the material are discussed.

  10. Ocean Thermal Energy Conversion Life Cycle Cost Assessment, Final Technical Report, 30 May 2012

    Energy Technology Data Exchange (ETDEWEB)

    Martel, Laura [Lockheed Martin, Manassas, VA (United States); Smith, Paul [John Halkyard and Associates: Glosten Associates, Houston, TX (United States); Rizea, Steven [Makai Ocean Engineering, Waimanalo, HI (United States); Van Ryzin, Joe [Makai Ocean Engineering, Waimanalo, HI (United States); Morgan, Charles [Planning Solutions, Inc., Vancouver, WA (United States); Noland, Gary [G. Noland and Associates, Inc., Pleasanton, CA (United States); Pavlosky, Rick [Lockheed Martin, Manassas, VA (United States); Thomas, Michael [Lockheed Martin, Manassas, VA (United States); Halkyard, John [John Halkyard and Associates: Glosten Associates, Houston, TX (United States)

    2012-05-30

    The Ocean Thermal Energy Conversion (OTEC) Life Cycle Cost Assessment (OLCCA) is a study performed by members of the Lockheed Martin (LM) OTEC Team under funding from the Department of Energy (DOE), Award No. DE-EE0002663, dated 01/01/2010. OLCCA objectives are to estimate procurement, operations and maintenance, and overhaul costs for two types of OTEC plants: -Plants moored to the sea floor where the electricity produced by the OTEC plant is directly connected to the grid ashore via a marine power cable (Grid Connected OTEC plants) -Open-ocean grazing OTEC plant-ships producing an energy carrier that is transported to designated ports (Energy Carrier OTEC plants) Costs are developed using the concept of levelized cost of energy established by DOE for use in comparing electricity costs from various generating systems. One area of system costs that had not been developed in detail prior to this analysis was the operations and sustainment (O&S) cost for both types of OTEC plants. Procurement costs, generally referred to as capital expense and O&S costs (operations and maintenance (O&M) costs plus overhaul and replacement costs), are assessed over the 30 year operational life of the plants and an annual annuity calculated to achieve a levelized cost (constant across entire plant life). Dividing this levelized cost by the average annual energy production results in a levelized cost of electricity, or LCOE, for the OTEC plants. Technical and production efficiency enhancements that could result in a lower value of the OTEC LCOE were also explored. The thermal OTEC resource for Oahu, Hawaii and projected build out plan were developed. The estimate of the OTEC resource and LCOE values for the planned OTEC systems enable this information to be displayed as energy supplied versus levelized cost of the supplied energy; this curve is referred to as an Energy Supply Curve. The Oahu Energy Supply Curve represents initial OTEC deployment starting in 2018 and demonstrates the

  11. Thermal design of lithium bromide-water solution vapor absorption cooling system for indirect evaporative cooling for IT pod

    Science.gov (United States)

    Sawant, Digvijay Ramkrishna

    Nowadays with increase use of internet, mobile there is increase in heat which ultimately increases the efficient cooling system of server room or IT POD. Use of traditional ways of cooling system has ultimately increased CO2 emission and depletion of CFC's are serious environmental issues which led scientific people to improve cooling techniques and eliminate use of CFC's. To reduce dependency on fossil fuels and 4environmental friendly system needed to be design. For being utilizing low grade energy source such as solar collector and reducing dependency on fossil fuel vapour absorption cooling system has shown a great driving force in today's refrigeration systems. This LiBr-water aabsorption cooling consists of five heat exchanger namely: Evaporator, Absorber, Solution Heat Exchanger, Generator, Condenser. The thermal design was done for a load of 23 kW and the procedure was described in the thesis. There are 120 servers in the IT POD emitting 196 W of heat each on full load and some of the heat was generated by the computer placed inside the IT POD. A detailed procedure has been discussed. A excel spreadsheet was to prepared with varying tube sizes to see the effect on flows and ultimately overall heat transfer coefficient.

  12. Investigation of absorptance and emissivity of thermal control coatings on Mg–Li alloys and OES analysis during PEO process

    Science.gov (United States)

    Yao, Zhongping; Xia, Qixing; Ju, Pengfei; Wang, Jiankang; Su, Peibo; Li, Dongqi; Jiang, Zhaohua

    2016-01-01

    Thermal control ceramic coatings on Mg–Li alloys have been successfully prepared in silicate electrolyte system by plasma electrolytic oxidation (PEO) method. The PEO coatings are mainly composed of crystallized Mg2SiO4 and MgO, which have typical porous structure with some bulges on the surface; OES analysis shows that the plasma temperature, which is influenced by the technique parameters, determines the formation of the coatings with different crystalline phases and morphologies, combined with “quick cooling effect” by the electrolyte; and the electron concentration is constant, which is related to the electric spark breakdown, determined by the nature of the coating and the interface of coating/electrolyte. Technique parameters influence the coating thickness, roughness and surface morphology, but do not change the coating composition in the specific PEO regime, and therefore the absorptance (αS) and emissivity (ε) of the coatings can be adjusted by the technique parameters through changing thickness and roughness in a certain degree. The coating prepared at 10 A/dm2, 50 Hz, 30 min and 14 g/L Na2SiO3 has the minimum value of αS (0.35) and the maximum value of ε (0.82), with the balance temperature of 320 K. PMID:27383569

  13. Ultrafast carrier thermalization and trapping in silicon-germanium alloy probed by extreme ultraviolet transient absorption spectroscopy.

    Science.gov (United States)

    Zürch, Michael; Chang, Hung-Tzu; Kraus, Peter M; Cushing, Scott K; Borja, Lauren J; Gandman, Andrey; Kaplan, Christopher J; Oh, Myoung Hwan; Prell, James S; Prendergast, David; Pemmaraju, Chaitanya D; Neumark, Daniel M; Leone, Stephen R

    2017-07-01

    Semiconductor alloys containing silicon and germanium are of growing importance for compact and highly efficient photonic devices due to their favorable properties for direct integration into silicon platforms and wide tunability of optical parameters. Here, we report the simultaneous direct and energy-resolved probing of ultrafast electron and hole dynamics in a silicon-germanium alloy with the stoichiometry Si0.25Ge0.75 by extreme ultraviolet transient absorption spectroscopy. Probing the photoinduced dynamics of charge carriers at the germanium M4,5-edge (∼30 eV) allows the germanium atoms to be used as reporter atoms for carrier dynamics in the alloy. The photoexcitation of electrons across the direct and indirect band gap into conduction band (CB) valleys and their subsequent hot carrier relaxation are observed and compared to pure germanium, where the Ge direct [Formula: see text] and Si0.25Ge0.75 indirect gaps ([Formula: see text]) are comparable in energy. In the alloy, comparable carrier lifetimes are observed for the X, L, and Γ valleys in the conduction band. A midgap feature associated with electrons accumulating in trap states near the CB edge following intraband thermalization is observed in the Si0.25Ge0.75 alloy. The successful implementation of the reporter atom concept for capturing the dynamics of the electronic bands by site-specific probing in solids opens a route to study carrier dynamics in more complex materials with femtosecond and sub-femtosecond temporal resolution.

  14. Phosphorus cycle in Germiston Lake. III. Seasonal patterns in the absorption, translocation and release of phosphorus by Potamogeton pectinatus L

    Energy Technology Data Exchange (ETDEWEB)

    Vermaak, J.F.; Swanepoel, J.H.; Schoonbee, H.J. (Rand Afrikaans Univ., Johannesburg (South Africa))

    1982-07-01

    The seasonal fluctuation in the phosphorus absorption, translocation, and release by the roots and shoots of Potamogeton pectinatus L. in Germiston Lake, is discussed. Shoot absorption exceeds that by the roots during spring and winter, while the reverse applies for summer and autumn. The shoots consistently release more phosphorus per plant than the roots. Both shoots and roots absorb considerably more phosphorus than what they release to the environment. This macrophyte, therefore, mainly acts as a phosphorus reservoir in Germiston Lake.

  15. Evaluation of roughness and micromorphology of epoxy paint on cobalt-chromium alloy before and after thermal cycling

    Directory of Open Access Journals (Sweden)

    Alessandra Cardoso da Silva Nascimento

    2013-04-01

    Full Text Available It has been suggested that the epoxy paint used to coat metal substrates in industrial electrostatic painting applications could also be used to mask metal clasps in removable dental prostheses (RDP. The purpose of this study was to evaluate both the influence of thermal cycling and the in vitro roughness of a surface after application of epoxy paint, as well as to assess the micromorphology of a cobalt-chromium (CoCr based metal structure. Sixty test specimens were fabricated from a CoCr alloy. The specimens were separated into three groups (n = 20 according to surface treatment: Group 1 (Pol - polished with abrasive stone and rubbers; Group 2 (Pol+Epo - polished and coated with epoxy paint; Group 3 (Epo - air-abraded with aluminum oxide particles and coated with epoxy paint. The surface roughness was evaluated before and after 1000 thermal cycles (5°C and 50°C. The surface micromorphology was verified by scanning electron microscopy (SEM. The two-way repeated measures ANOVA showed significant differences among surface treatments (p < 0.0001, but no difference was found before and after thermal cycling (p = 0.6638. The CoCr-based metal alloy surfaces treated with epoxy paint (Groups 2 and 3 were rougher than the surfaces that were only polished (Group 1. Thermal cycling did not influence surface roughness, or lead to chipping or detachment of the epoxy paint.

  16. Influence of thermal and mechanical cycling on the flexural strength of ceramics with titanium or gold alloy frameworks

    NARCIS (Netherlands)

    Oyafuso, Denise Kanashiro; Ozcan, Mutlu; Bottino, Marco Antonio; Itinoche, Marcos Koiti

    Objectives. The aim of this study was to evaluate the effect of thermal and mechanical cycling alone or in combination, on the flexural strength of ceramic and metallic frameworks cast in gold alloy or titanium. Methods. Metallic frameworks (25 mm x 3 mm x 0.5 mm) (N = 96) cast in gold alloy or

  17. Measured thermal and fast neutron fluence rates for ATF-1 holders during ATR cycle 158B/159A

    Energy Technology Data Exchange (ETDEWEB)

    Smith, Larry Don [Idaho National Lab. (INL), Idaho Falls, ID (United States); Miller, David Torbet [Idaho National Lab. (INL), Idaho Falls, ID (United States); Walker, Billy Justin [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2016-11-01

    This report contains the thermal (2200 m/s) and fast (E>1MeV) neutron fluence rate data for the ATF-1 holders located in core for ATR Cycle 158B/159A which were measured by the Radiation Measurements Laboratory (RML).

  18. Effect of bonding and bakeout thermal cycles on the properties of copper alloys irradiated at 350 degrees C

    DEFF Research Database (Denmark)

    Singh, B.N.; Edwards, D.J.; Eldrup, Morten Mostgaard

    2001-01-01

    Screening experiments were carried out to determine the effect of bonding and bakeout thermal cycles on microstructure, mechanical properties and electrical resistivity of the oxide dispersion strengthened (GlidCop, CuAl-25) and the precipitation hardened (CuCrZr, CuNiBe) copper alloys. Tensile...

  19. Characterization of Ternary NiTiPd High-Temperature Shape-Memory Alloys under Load-Biased Thermal Cycling

    Science.gov (United States)

    Bigelow, Glen S.; Padula, Santo A.; Noebe, Ronald D.; Garg, Anita; Gaydosh, Darrell

    2010-01-01

    While NiTiPd alloys have been extensively studied for proposed use in high-temperature shape-memory applications, little is known about the shape-memory response of these materials under stress. Consequently, the isobaric thermal cyclic responses of five (Ni,Pd)49.5Ti50.5 alloys with constant stoichiometry and Pd contents ranging from 15 to 46 at. pct were investigated. From these tests, transformation temperatures, transformation strain (which is proportional to work output), and unrecovered strain per cycle (a measure of dimensional instability) were determined as a function of stress for each alloy. It was found that increasing the Pd content over this range resulted in a linear increase in transformation temperature, as expected. At a given stress level, work output decreased while the amount of unrecovered strain produced during each load-biased thermal cycle increased with increasing Pd content, during the initial thermal cycles. However, continued thermal cycling at constant stress resulted in a saturation of the work output and nearly eliminated further unrecovered strain under certain conditions, resulting in stable behavior amenable to many actuator applications.

  20. Effect of thermal radiation on free convection flow and heat transfer over a truncated cone in the presence of pressure work and heat generation/absorption

    Directory of Open Access Journals (Sweden)

    Elbashbeshy E.M.A.

    2016-01-01

    Full Text Available Effect of heat generation or absorption and thermal radiation on free convection flow and heat transfer over a truncated cone in the presence of pressure work is considered. The governing boundary layer equations are reduced to non-similarity boundary layer equations and solved numerically by using Mathematica technique. Comparisons with previously published work on special cases of the problem are performed and the results are found to be in excellent agreement. The solutions are presented in terms of local skin friction, local Nusselt number, velocity and temperature profiles for values of Prandtl number, pressure work parameter, radiation parameter and heat generation or absorption parameter.

  1. Thermally moderated hollow fiber sorbent modules in rapidly cycled pressure swing adsorption mode for hydrogen purification

    KAUST Repository

    Lively, Ryan P.

    2012-10-01

    We describe thermally moderated multi-layered pseudo-monolithic hollow fiber sorbents entities, which can be packed into compact modules to provide small-footprint, efficient H2 purification/CO2 removal systems for use in on-site steam methane reformer product gas separations. Dual-layer hollow fibers are created via dry-jet, wet-quench spinning with an inner "active" core of cellulose acetate (porous binder) and zeolite NaY (69 wt% zeolite NaY) and an external sheath layer of pure cellulose acetate. The co-spun sheath layer reduces the surface porosity of the fiber and was used as a smooth coating surface for a poly(vinyl-alcohol) post-treatment, which reduced the gas permeance through the fiber sorbent by at least 7 orders of magnitude, essentially creating an impermeable sheath layer. The interstitial volume between the individual fibers was filled with a thermally-moderating paraffin wax. CO2 breakthrough experiments on the hollow fiber sorbent modules with and without paraffin wax revealed that the "passively" cooled paraffin wax module had 12.5% longer breakthrough times than the "non-isothermal" module. The latent heat of fusion/melting of the wax offsets the released latent heat of sorption/desorption of the zeolites. One-hundred rapidly cycled pressure swing adsorption cycles were performed on the "passively" cooled hollow fiber sorbents using 25 vol% CO2/75 vol% He (H2 surrogate) at 60 °C and 113 psia, resulting in a product purity of 99.2% and a product recovery of 88.1% thus achieving process conditions and product quality comparable to conventional pellet processes. Isothermal and non-isothermal dynamic modeling of the hollow fiber sorbent module and a traditional packed bed using gPROMS® indicated that the fiber sorbents have sharper fronts (232% sharper) and longer adsorbate breakthrough times (66% longer), further confirming the applicability of the new fiber sorbent approach for H2 purification. © 2012, Hydrogen Energy Publications, LLC

  2. Micro solid oxide fuel cell fabricated on porous stainless steel: a new strategy for enhanced thermal cycling ability

    Science.gov (United States)

    Kim, Kun Joong; Park, Byung Hyun; Kim, Sun Jae; Lee, Younki; Bae, Hongyeul; Choi, Gyeong Man

    2016-01-01

    Miniaturized solid oxide fuel cells (micro-SOFCs) are being extensively studied as a promising alternative to Li batteries for next generation portable power. A new micro-SOFC is designed and fabricated which shows enhanced thermal robustness by employing oxide-based thin-film electrode and porous stainless steel (STS) substrate. To deposit gas-tight thin-film electrolyte on STS, nano-porous composite oxide is proposed and applied as a new contact layer on STS. The micro-SOFC fabricated on composite oxide- STS dual layer substrate shows the peak power density of 560 mW cm−2 at 550 °C and maintains this power density during rapid thermal cycles. This cell may be suitable for portable electronic device that requires high power-density and fast thermal cycling. PMID:26928921

  3. Nanodomain Engineered (K, Na)NbO3 Lead-Free Piezoceramics: Enhanced Thermal and Cycling Reliabilities

    DEFF Research Database (Denmark)

    Yao, Fang-Zhou; Wang, Ke; Cheng, Li-Qian

    2015-01-01

    temperature fluctuation and electrical fatigue cycling. It was found that the piezoelectric coefficient d33 is temperature independent under 4 kV/mm, which can be attributed to enhanced thermal stability of electric field engineered domain configuration; whereas the electric field induced strain exhibits......The growing environmental concerns have been pushing the development of viable green alternatives for lead-based piezoceramics to be one of the priorities in functional ceramic materials. A polymorphic phase transition has been utilized to enhance piezoelectric properties of lead-free (K, Na)NbO3...... excellent fatigue resistance up to 107 sesquipolar cycles. These findings render the current material an unprecedented opportunity for actuator applications demanding improved thermal and cycling reliabilities....

  4. Energy performance and economic evaluation of heat pump/organic rankine cycle system with sensible thermal storage

    DEFF Research Database (Denmark)

    Carmo, Carolina; Dumont, Olivier; Nielsen, Mads Pagh

    2016-01-01

    that consists of a ground-source heat pump with possibility of reversing operation as an ORC power cycle combined with solar heating in a single-family building is introduced. The ORC mode enables the use of solar energy in periods of no heat energy demand and reverses the heat pump cycle to supply electrical......-life conditions knowledge, the paper considers two different sensible energy storage (TES) configurations for the reversible heat pump/organic Rankine cycle (HP/ORC) system: a buffer tank for both space heating and domestic hot water and a hot water storage tank used exclusively for domestic hot water......The interaction between electrical and thermal energy demands represent a potential area for balancing supply and demand that could contribute to the integration of intermittent renewables in energy systems. To enable the interaction between thermal and electric energy, an innovative concept...

  5. Energy Performance and Economic Evaluation of Heat Pump/Organic Rankine Cycle System with Sensible Thermal Storage

    DEFF Research Database (Denmark)

    Carmo, C.; Dumont, O.; Nielsen, M. P.

    2016-01-01

    that consists of a ground-source heat pump with possibility of reversing operation as an ORC power cycle combined with solar heating in a single-family building is introduced. The ORC mode enables the use of solar energy in periods of no heat energy demand and reverses the heat pump cycle to supply electrical......-life conditions knowledge, the paper considers two different sensible energy storage (TES) configurations for the reversible heat pump/organic Rankine cycle (HP/ORC) system: a buffer tank for both space heating and domestic hot water and a hot water storage tank used exclusively for domestic hot water......The interaction between electrical and thermal energy demands represent a potential area for balancing supply and demand that could contribute to the integration of intermittent renewables in energy systems. To enable the interaction between thermal and electric energy, an innovative concept...

  6. Energetic and exergetic analysis of Rankine cycles for solar power plants with parabolic trough and thermal storage

    Directory of Open Access Journals (Sweden)

    Cenuşă Victor-Eduard

    2016-01-01

    Full Text Available The paper analyzes the “secondary” circuit (for thermodynamic conversion of a Concentrated Solar Power (CSP plant with thermodynamic cycle, whose mirrors field supplies a thermal power, averaged over a sunny day, of about 100 MW heat. We study the case of parabolic trough solar collector using silicone oil in the “primary” circuit, which limits the peak temperature below 400 °C. The “primary” circuit uses thermal storage, allowing a delay between the power generation in rapport with the solar energy capture. We choose a water-steam cycle, type Hirn. For increasing its efficiency, it has regenerative feed water preheating and steam reheating. We compared, energetic and exergetic, two types of cycles, using a numerical model with iterative structure, developed by the authors. The results showed that the simplified design achieves practically the same thermodynamic performances with the advanced one.

  7. Multi-parameter fibre Bragg grating sensor-array for thermal vacuum cycling test

    Science.gov (United States)

    Cheng, L.; Ahlers, B.; Toet, P.; Casarosa, G.; Appolloni, M.

    2017-11-01

    strain transducer to generate strain via a dedicated feed through in the chamber. Thermocouples are used to log the temperature for comparison to the temperature FBG sensor. Extreme temperature ranges from -150°C and +70°C at a pressure down to 10-4 Pa (10-6 mbar) are covered as well as testing under ambient conditions. In total five thermal cycles during a week test are performed. The FBG temperature sensor test results performed in the ESA/ESTEC TV chamber reveal high reproducibility (within 1 °C) within the test temperature range without any evidence of hysteresis. Differences are detected to the previous calibration curve. Investigation is performed to find the cause of the discrepancy. Differences between the test set-ups are identified. Equipment of the TNO test is checked and excluded to be the cause. Additional experiments are performed. The discrepancy is most likely caused by a 'thermal shock' due to rapid cooling down to LN2 temperature, which results in a wavelength shift. Test data of the FBG strain sensor is analysed. The read-out of the FBG strain sensor varies with the temperature during the test. This can be caused by temperature induced changes in the mechanical setup (fastening of the mechanical parts) or impact of temperature to the mechanical strain transfer to the FBG. Improvements are identified and recommendations given for future activities.

  8. Structure optimisation by thermal cycling for the hydrophobic-polar lattice model of protein folding

    Science.gov (United States)

    Günther, Florian; Möbius, Arnulf; Schreiber, Michael

    2017-03-01

    The function of a protein depends strongly on its spatial structure. Therefore the transition from an unfolded stage to the functional fold is one of the most important problems in computational molecular biology. Since the corresponding free energy landscapes exhibit huge numbers of local minima, the search for the lowest-energy configurations is very demanding. Because of that, efficient heuristic algorithms are of high value. In the present work, we investigate whether and how the thermal cycling (TC) approach can be applied to the hydrophobic-polar (HP) lattice model of protein folding. Evaluating the efficiency of TC for a set of two- and three-dimensional examples, we compare the performance of this strategy with that of multi-start local search (MSLS) procedures and that of simulated annealing (SA). For this aim, we incorporated several simple but rather efficient modifications into the standard procedures: in particular, a strong improvement was achieved by also allowing energy conserving state modifications. Furthermore, the consideration of ensembles instead of single samples was found to greatly improve the efficiency of TC. In the framework of different benchmarks, for all considered HP sequences, we found TC to be far superior to SA, and to be faster than Wang-Landau sampling.

  9. The Seasonal Cycle of Water Vapour on Mars from Assimilation of Thermal Emission Spectrometer Data

    Science.gov (United States)

    Steele, Liam J.; Lewis, Stephen R.; Patel, Manish R.; Montmessin, Franck; Forget, Francois; Smith, Michael D.

    2014-01-01

    We present for the first time an assimilation of Thermal Emission Spectrometer (TES) water vapour column data into a Mars global climate model (MGCM). We discuss the seasonal cycle of water vapour, the processes responsible for the observed water vapour distribution, and the cross-hemispheric water transport. The assimilation scheme is shown to be robust in producing consistent reanalyses, and the global water vapour column error is reduced to around 2-4 pr micron depending on season. Wave activity is shown to play an important role in the water vapour distribution, with topographically steered flows around the Hellas and Argyre basins acting to increase transport in these regions in all seasons. At high northern latitudes, zonal wavenumber 1 and 2 stationary waves during northern summer are responsible for spreading the sublimed water vapour away from the pole. Transport by the zonal wavenumber 2 waves occurs primarily to the west of Tharsis and Arabia Terra and, combined with the effects of western boundary currents, this leads to peak water vapour column abundances here as observed by numerous spacecraft. A net transport of water to the northern hemisphere over the course of one Mars year is calculated, primarily because of the large northwards flux of water vapour which occurs during the local dust storm around L(sub S) = 240-260deg. Finally, outlying frost deposits that surround the north polar cap are shown to be important in creating the peak water vapour column abundances observed during northern summer.

  10. Life cycle assessment of thermal waste-to-energy technologies: review and recommendations.

    Science.gov (United States)

    Astrup, Thomas Fruergaard; Tonini, Davide; Turconi, Roberto; Boldrin, Alessio

    2015-03-01

    Life cycle assessment (LCA) has been used extensively within the recent decade to evaluate the environmental performance of thermal Waste-to-Energy (WtE) technologies: incineration, co-combustion, pyrolysis and gasification. A critical review was carried out involving 250 individual case-studies published in 136 peer-reviewed journal articles within 1995 and 2013. The studies were evaluated with respect to critical aspects such as: (i) goal and scope definitions (e.g. functional units, system boundaries, temporal and geographic scopes), (ii) detailed technology parameters (e.g. related to waste composition, technology, gas cleaning, energy recovery, residue management, and inventory data), and (iii) modeling principles (e.g. energy/mass calculation principles, energy substitution, inclusion of capital goods and uncertainty evaluation). Very few of the published studies provided full and transparent descriptions of all these aspects, in many cases preventing an evaluation of the validity of results, and limiting applicability of data and results in other contexts. The review clearly suggests that the quality of LCA studies of WtE technologies and systems including energy recovery can be significantly improved. Based on the review, a detailed overview of assumptions and modeling choices in existing literature is provided in conjunction with practical recommendations for state-of-the-art LCA of Waste-to-Energy. Copyright © 2014 Elsevier Ltd. All rights reserved.

  11. Assessment of Accrued Damage and Remaining Useful Life in Leadfree Electronics Subjected to Multiple Thermal Environments of Thermal Aging and Thermal Cycling

    Data.gov (United States)

    National Aeronautics and Space Administration — A method has been developed for prognostication of accrued prior damage in electronics subjected to overlapping sequential environments of thermal aging and thermal...

  12. Ultrafast carrier thermalization and trapping in silicon-germanium alloy probed by extreme ultraviolet transient absorption spectroscopy

    Directory of Open Access Journals (Sweden)

    Michael Zürch

    2017-07-01

    Full Text Available Semiconductor alloys containing silicon and germanium are of growing importance for compact and highly efficient photonic devices due to their favorable properties for direct integration into silicon platforms and wide tunability of optical parameters. Here, we report the simultaneous direct and energy-resolved probing of ultrafast electron and hole dynamics in a silicon-germanium alloy with the stoichiometry Si0.25Ge0.75 by extreme ultraviolet transient absorption spectroscopy. Probing the photoinduced dynamics of charge carriers at the germanium M4,5-edge (∼30 eV allows the germanium atoms to be used as reporter atoms for carrier dynamics in the alloy. The photoexcitation of electrons across the direct and indirect band gap into conduction band (CB valleys and their subsequent hot carrier relaxation are observed and compared to pure germanium, where the Ge direct ( Δ E gap , Ge , direct = 0.8   eV and Si0.25Ge0.75 indirect gaps ( Δ E gap , Si 0.25 Ge 0.75 , indirect = 0.95   eV are comparable in energy. In the alloy, comparable carrier lifetimes are observed for the X, L, and Γ valleys in the conduction band. A midgap feature associated with electrons accumulating in trap states near the CB edge following intraband thermalization is observed in the Si0.25Ge0.75 alloy. The successful implementation of the reporter atom concept for capturing the dynamics of the electronic bands by site-specific probing in solids opens a route to study carrier dynamics in more complex materials with femtosecond and sub-femtosecond temporal resolution.

  13. High-dose neutron irradiation of MgAl{sub 2}O{sub 4} spinel: effects of post-irradiation thermal annealing on EPR and optical absorption

    Energy Technology Data Exchange (ETDEWEB)

    Ibarra, A. [EURATOM/CIEMAT Fusion Association, Inst. Investigacion Basica, Av. Complutense, 22, E-28040 Madrid (Spain)]. E-mail: angel.ibarra@ciemat.es; Bravo, D. [Departamento de Fisica de Materiales, Facultad de Ciencias (C-IV), Universidad Autonoma de Madrid, Cantoblanco, E-28049 Madrid (Spain); Lopez, F.J. [Departamento de Fisica de Materiales, Facultad de Ciencias (C-IV), Universidad Autonoma de Madrid, Cantoblanco, E-28049 Madrid (Spain); Garner, F.A. [Pacific Northwest National Laboratory, Richland, WA (United States)

    2005-02-01

    Electron paramagnetic resonance (EPR) and optical absorption spectra were measured during thermal annealing of stoichiometric MgAl{sub 2}O{sub 4} spinel that was previously irradiated in the Materials Open Test Assembly in the Fast Flux Test Facility (FFTF/MOTA) at {approx}680 K to {approx}50 dpa. Both F and F{sup +} centres are to persist up to very high temperatures (over 1000 K) suggesting the operation of an annealing mechanism controlled by the thermal stability of extended defects. Using X-ray irradiation following the different annealing steps it was shown that an optical absorption band at 37,000 cm{sup -1} is related to a sharp EPR band at g = 2.0005 and that the defect causing these effects is the F{sup +} centre.

  14. Thermal radiation and heat generation/absorption effects on viscoelastic double-diffusive convection from an isothermal sphere in porous media

    Directory of Open Access Journals (Sweden)

    S. Abdul Gaffar

    2015-09-01

    Full Text Available Buoyancy-driven convective heat and mass transfer in boundary layer flow of a viscoelastic Jeffrey fluid from a permeable isothermal sphere embedded in a porous medium is studied. Thermal radiation flux and heat generation/absorption are also incorporated in the model. A non-Darcy drag force model is employed to simulate the effects of linear porous media drag and second order Forchheimer drag. The Rosseland diffusion algebraic approximation is utilized to simulate thermal radiation effects. The non-dimensionalized boundary layer equations are solved using implicit, finite-difference scheme. The influence of Darcy number (Da, Deborah number (De, ratio of relaxation to retardation times (λ, radiation parameter (F, Forchheimer inertial parameter (Λ and heat generation/absorption parameter (Δ, on normalized velocity, temperature, concentration, skin friction, heat and mass transfer rates are also studied. The present study has applications in the storage of nuclear waste materials.

  15. Effects of thermal cycling and thermal aging on the hermeticity and strength of silver-copper oxide air-brazed seals

    Energy Technology Data Exchange (ETDEWEB)

    Scott Weil, K.; Coyle, Christopher A.; Hardy, John S. [Energy Science and Technology Division, Pacific Northwest National Laboratory, Richland, WA 99352 (United States); Darsell, Jens T. [School of Mechanical and Materials Engineering, Washington State University, Pullman, WA 99164 (United States); Xia, Gordon G. [Environmental Technology Division, Pacific Northwest National Laboratory, Richland, WA 99352 (United States)

    2005-12-01

    Thermal cycle and exposure tests were conducted on ceramic-to-metal joints prepared by a new sealing technique. Known as reactive air brazing, this joining method is currently being considered for use in sealing various high-temperature solid-state electrochemical devices, including planar solid oxide fuel cells (pSOFC). In order to simulate a typical pSOFC application, test specimens were prepared by joining ceramic anode/electrolyte bilayers to metal washers, of the same composition as the common frame materials employed in pSOFC stacks, using a filler metal composed of 4mol% CuO in silver. The brazed samples were exposure tested at 750{sup o}C for 200, 400, and 800h in both simulated fuel and air environments and thermally cycled at rapid rate (75{sup o}Cmin{sup -1}) between room temperature and 750{sup o}C for as many as 50 cycles. Subsequent joint strength testing and microstructural analysis indicated that the samples exposure tested in air displayed little degradation with respect to strength, hermeticity, or microstructure out to 800h of exposure. Those tested in fuel showed no change in rupture strength or loss in hermeticity after 800h of high-temperature exposure, but did undergo microstructural change due to the dissolution of hydrogen into the silver-based braze material. Air-brazed specimens subjected to rapid thermal cycling exhibited no loss in joint strength or hermeticity, but displayed initial signs of seal delamination along the braze-electrolyte interface after 50 cycles. (author)

  16. Zinc Absorption from Milk Is Affected by Dilution but Not by Thermal Processing, and Milk Enhances Absorption of Zinc from High-Phytate Rice in Young Dutch Women.

    Science.gov (United States)

    Talsma, Elise F; Moretti, Diego; Ly, Sou Chheng; Dekkers, Renske; van den Heuvel, Ellen Ghm; Fitri, Aditia; Boelsma, Esther; Stomph, Tjeerd Jan; Zeder, Christophe; Melse-Boonstra, Alida

    2017-06-01

    Background: Milk has been suggested to increase zinc absorption. The effect of processing and the ability of milk to enhance zinc absorption from other foods has not been measured directly in humans. Objective: We aimed to assess zinc absorption from 1 ) milk undergoing various processing and preparatory steps and 2 ) from intrinsically labeled high-phytate rice consumed with milk or water. Methods: Two randomized crossover studies were conducted in healthy young women [age:18-25 y; body mass index (in kg/m 2 ): 20-25]: 1 ) a milk study ( n = 19) comparing the consumption of 800 mL full-fat ultra-high temperature (UHT) milk [heat-treated milk (HTM)], full-fat UHT milk diluted 1:1 with water [heat-treated milk and water (MW)], water, or unprocessed (raw) milk (UM), each extrinsically labeled with 67 Zn, and 2 ) a rice study ( n = 18) comparing the consumption of 90 g intrinsically 67 Zn-labeled rice with 600 mL of water [rice and water (RW)] or full-fat UHT milk [rice and milk (RM)]. The fractional absorption of zinc (FAZ) was measured with the double-isotope tracer ratio method. In vitro, we assessed zinc extraction from rice blended into water, UM, or HTM with or without phytate. Results: FAZ from HTM was 25.5% (95% CI: 21.6%, 29.4%) and was not different from UM (27.8%; 95% CI: 24.2%, 31.4%). FAZ from water was higher (72.3%; 95% CI: 68.7%, 75.9%), whereas FAZ from MW was lower (19.7%; 95% CI: 17.5%, 21.9%) than HTM and UM (both P Milk enhanced human FAZ from high-phytate rice by 62% compared with water. Diluting milk with water decreases its absorption-enhancing proprieties, whereas UHT processing does not. This trial was registered at the Dutch trial registry as NTR4267 (http://www.trialregister.nl/trialreg/admin/rctview.asp?TC=4267). © 2017 American Society for Nutrition.

  17. Characterization of the physico-chemical properties of polymeric materials for aerospace flight. [differential thermal and atomic absorption spectroscopic analysis of nickel cadmium batteries

    Science.gov (United States)

    Rock, M.

    1981-01-01

    Electrodes and electrolytes of nickel cadmium sealed batteries were analyzed. Different thermal analysis of negative and positive battery electrodes was conducted and the temperature ranges of occurrence of endotherms indicating decomposition of cadmium hydroxide and nickel hydroxide are identified. Atomic absorption spectroscopy was used to analyze electrodes and electrolytes for traces of nickel, cadmium, cobalt, and potassium. Calibration curves and data are given for each sample analyzed. Instrumentation and analytical procedures used for each method are described.

  18. Effect of Regenerative Organic Rankine Cycle (RORC on the Performance of Solar Thermal Power in Yogyakarta, Indonesia

    Directory of Open Access Journals (Sweden)

    Ghalya Pikra

    2013-07-01

    Full Text Available This paper presents effect of Regenerative Organic Rankine Cycle (RORC on the performance of solar thermal power in Yogyakarta, Indonesia. Solar thermal power is a plant that uses solar energy as heat source. Indonesia has high humidity level, so that parabolic trough is the most suitable type of solar thermal power technology to be developed, where the design is made with small focal distance. Organic Rankine Cycle (ORC is a Rankine cycle that use organic fluid as working fluid to utilize low temperature heat sources. RORC is used to increase ORC performance. The analysis was done by comparing ORC system with and without regenerator addition. Refrigerant that be used in the analysis is R123. Preliminary data was taken from the solar collector system that has been installed in Yogyakarta. The analysis shows that with 36 m total parabolic length, the resulting solar collector capacity is 63 kW, heat input/evaporator capacity is determined 26.78 kW and turbine power is 3.11 kW for ORC, and 3.38 kW for RORC. ORC thermal efficiency is 11.28% and RORC is 12.26%. Overall electricity efficiency is 4.93% for ORC, and 5.36% for RORC. With 40°C condensing temperature and evaporation at 10 bar saturated condition, efficiency of RORC is higher than ORC. Greater evaporation temperature at the same pressure (10 bar provide greater turbine power and efficiency.

  19. Effect of thermal cycling of SiC{sub f}/SiC composites on their mechanical properties

    Energy Technology Data Exchange (ETDEWEB)

    Udayakumar, A., E-mail: audayk@yahoo.com [Materials Science Division, Council of Scientific and Industrial Research – National Aerospace Laboratories, Bangalore-560 017 (India); Stalin, M.; Abhayalakshmi, M.B.; Hariharan, Ramya [Materials Science Division, Council of Scientific and Industrial Research – National Aerospace Laboratories, Bangalore-560 017 (India); Balasubramanian, M., E-mail: mbala@iitm.ac.in [Department of Metallurgical and Materials Engineering, Indian Institute of Technology Madras, Chennai-600 036 (India)

    2013-11-15

    SiC{sub f}/SiC composites are class of high temperature structural materials being developed for use in nuclear fusion and fission reactor systems because of their superior high temperature mechanical properties, low radiation damage and low induced radioactivity. Two types of 2D SiC{sub f}/SiC composites were made through isothermal and isobaric chemical vapor infiltration process using eight harness satin-woven ceramic-grades Nicalon™ fibers with boron nitride (BN) interface, namely: one with lower interface thickness and a second type with higher interface thickness. The BN interface was applied to the fiber prior to SiC matrix addition to modify the interfacial bond strength leading to better toughness and improved oxidation resistance. The density achieved was around 2.6 g/cc. The composite specimens were subjected to thermal cycling treatment using an in-house furnace. The mechanical properties such as tensile strength, fracture toughness and interfacial bond strength were also studied for all the composites before and after thermal cycling. It is seen from the results that both composites withstood thermal shocks and thermal cycling treatment. It was also concluded from the present work that good balance between load transfer and crack arresting was established.

  20. Numerical investigation of MHD free convection flow of a non-Newtonian fluid past an impulsively started vertical plate in the presence of thermal diffusion and radiation absorption

    Directory of Open Access Journals (Sweden)

    M. Umamaheswar

    2016-09-01

    Full Text Available A numerical investigation is carried out on an unsteady MHD free convection flow of a well-known non-Newtonian visco elastic second order Rivlin-Erickson fluid past an impulsively started semi-infinite vertical plate in the presence of homogeneous chemical reaction, thermal radiation, thermal diffusion, radiation absorption and heat absorption with constant mass flux. The presence of viscous dissipation is also considered at the plate under the influence of uniform transverse magnetic field. The flow is governed by a coupled nonlinear system of partial differential equations which are solved numerically by using finite difference method. The effects of various physical parameters on the flow quantities viz. velocity, temperature, concentration, Skin friction, Nusselt number and Sherwood number are studied numerically. The results are discussed with the help of graphs. We observed that the velocity decreases with an increase in magnetic field parameter, Schmidt number, and Prandtl number while it increases with an increase in Grashof number, modified Grashof number, visco-elastic parameter and Soret number. Temperature increases with an increase in radiation absorption parameter, Eckert number and visco-elastic parameter while it decreases with increasing values of radiation parameter, Prandtl number and heat absorption parameter. Concentration increases with increase in Soret number while it decreases with an increase in Schmidt number and chemical reaction parameter.

  1. Thermal performance of shallow solar pond under open cycle continuous flow heating mode for heat extraction

    Energy Technology Data Exchange (ETDEWEB)

    El-Sebaii, A.A. [Department of Physics, Faculty of Science, Tanta University, Tanta 31527 (Egypt)]. E-mail: aasebaii@yahoo.com; Aboul-Enein, S. [Department of Physics, Faculty of Science, Tanta University, Tanta 31527 (Egypt); Ramadan, M.R.I. [Department of Physics, Faculty of Science, Tanta University, Tanta 31527 (Egypt); Khallaf, A.M. [Department of Physics, Faculty of Science, Tanta University, Tanta 31527 (Egypt)

    2006-05-15

    The thermal performance of a shallow solar pond (SSP) under an open cycle continuous flow heating mode for heat extraction has been investigated. A serpentine heat exchanger (HE), either welded to the absorber plate or immersed in the pond water, has been used for extracting the heat. Suitable computer programs have been developed based on analytical solutions of the energy balance equations for the various elements of the SSP in the presence of the HE. Numerical calculations have been performed to study the effect of different operational and configurational parameters on the pond performance. In order to improve the pond performance, optimization of the various dimensions of the pond with the HE has been performed. The effects of the design parameters of the HE's tube, i.e. length L{sub he}, diameter D and mass flow rate m-bar {sub f} of the fluid flowing through the HE, on the pond performance have been investigated. The outlet temperature of the HE's fluid T{sub fo} is found to increase with increase of the HE length L{sub he}, and it decreases with increase of the mass flow rate of the HE's fluid m-bar {sub f} up to typical values for these parameters. Typical values for L{sub he} and m-bar {sub f} are found to be 4m and 0.004kg/s beyond which the change in T{sub fo} becomes insignificant. Experiments have been performed for the pond under different operational conditions with a HE welded to the absorber plate. To validate the proposed mathematical models, comparisons between experimental and theoretical results have been performed. Good agreement has been achieved.

  2. Direct Chromatin PCR (DC-PCR): Hypotonic Conditions Allow Differentiation of Chromatin States during Thermal Cycling

    Science.gov (United States)

    Vatolin, Sergei; Khan, Shahper N.; Reu, Frederic J.

    2012-01-01

    Current methods to study chromatin configuration are not well suited for high throughput drug screening since they require large cell numbers and multiple experimental steps that include centrifugation for isolation of nuclei or DNA. Here we show that site specific chromatin analysis can be achieved in one step by simply performing direct chromatin PCR (DC-PCR) on cells. The basic underlying observation was that standard hypotonic PCR buffers prevent global cellular chromatin solubilization during thermal cycling while more loosely organized chromatin can be amplified. Despite repeated heating to >90°C, 41 of 61 tested 5′ sequences of silenced genes (CDKN2A, PU.1, IRF4, FOSB, CD34) were not amplifiable while 47 could be amplified from expressing cells. Two gene regions (IRF4, FOSB) even required pre-heating of cells in isotonic media to allow this differentiation; otherwise none of 19 assayed sequences yielded PCR products. Cells with baseline expression or epigenetic reactivation gave similar DC-PCR results. Silencing during differentiation of CD34 positive cord blood cells closed respective chromatin while treatment of myeloma cells with an IRF4 transcriptional inhibitor opened a site to DC-PCR that was occupied by RNA polymerase II and NFκB as determined by ChIP. Translation into real-time PCR can not be achieved with commercial real-time PCR buffers which potently open chromatin, but even with simple ethidium bromide addition to standard PCR mastermix we were able to identify hits in small molecules screens that suppressed IRF4 expression or reactivated CDKN2A in myeloma cells using densitometry or visual inspection of PCR plates under UV light. While need in drug development inspired this work, application to genome-wide analysis appears feasible using phi29 for selective amplification of open cellular chromatin followed by library construction from supernatants since such supernatants yielded similar results as gene specific DC-PCR. PMID:22984542

  3. The Influence of Thermal Cycles on the Microstructure of Grade 92 Steel

    Science.gov (United States)

    Xu, X.; West, G. D.; Siefert, J. A.; Parker, J. D.; Thomson, R. C.

    2017-11-01

    The microstructure in the heat-affected zone (HAZ) of welds made from the 9 wt pct chromium martensitic Grade 92 steel is complex and has not yet been completely understood. There is a lack of systematic microstructural investigations to define the different regions of the microstructure across the HAZ of Grade 92 steel welds as a function of the welding process. In this study, the microstructure in the HAZ of an as-fabricated single-pass bead-on-plate weld on a parent metal of Grade 92 steel was systematically investigated by using an extensive range of electron and ion-microscopy-based techniques. A dilatometer was used to apply controlled thermal cycles to simulate the microstructures in the different regions of the HAZ. A wide range of microstructural properties in the simulated materials were then characterized and compared with the experimental observations from the weld HAZ. It was found that the microstructure in the HAZ of a single-pass Grade 92 steel weld can be categorized as a function of a decreasing peak temperature reached as (1) the completely transformed (CT) region, in which the original matrix is completely reaustenitized with complete dissolution of the pre-existing secondary precipitate particles; (2) the partially transformed (PT) region, where the original matrix is partially reaustenitized along with a partial dissolution of the secondary precipitate particles from the original matrix; and (3) the overtempered (OT) region, where the pre-existing precipitate particles coarsen. The PT region is considered to be the susceptible area for damage in the commonly reported HAZ failures in weldments constructed from these types of steels.

  4. Design, evaluation and recommedation effort relating to the modification of a residential 3-ton absorption cycle cooling unit for operation with solar energy

    Science.gov (United States)

    Merrick, R. H.; Anderson, P. P.

    1973-01-01

    The possible use of solar energy powered absorption units to provide cooling and heating of residential buildings is studied. Both, the ammonia-water and the water-lithium bromide cycles, are considered. It is shown that the air cooled ammonia water unit does not meet the criteria for COP and pump power on the cooling cycle and the heat obtained from it acting as a heat pump is at too low a temperature. If the ammonia machine is water cooled it will meet the design criteria for cooling but can not supply the heating needs. The water cooled lithium bromide unit meets the specified performance for cooling with appreciably lower generator temperatures and without a mechanical solution pump. It is recommeded that in the demonstration project a direct expansion lithium bromide unit be used for cooling and an auxiliary duct coil using the solar heated water be employed for heating.

  5. Detailed analysis of the effect of the turbine and compressor isentropic efficiency on the thermal and exergy efficiency of a Brayton cycle

    Directory of Open Access Journals (Sweden)

    Živić Marija

    2014-01-01

    Full Text Available Energy and exergy analysis of a Brayton cycle with an ideal gas is given. The irreversibility of the adiabatic processes in turbine and compressor is taken into account through their isentropic efficiencies. The net work per cycle, the thermal efficiency and the two exergy efficiencies are expressed as functions of the four dimensionless variables: the isentropic efficiencies of turbine and compressor, the pressure ratio, and the temperature ratio. It is shown that the maximal values of the net work per cycle, the thermal and the exergy efficiency are achieved when the isentropic efficiencies and temperature ratio are as high as possible, while the different values of pressure ratio that maximize the net work per cycle, the thermal and the exergy efficiencies exist. These pressure ratios increase with the increase of the temperature ratio and the isentropic efficiency of compressor and turbine. The increase of the turbine isentropic efficiency has a greater impact on the increase of the net work per cycle and the thermal efficiency of a Brayton cycle than the same increase of compressor isentropic efficiency. Finally, two goal functions are proposed for thermodynamic optimization of a Brayton cycle for given values of the temperature ratio and the compressor and turbine isentropic efficiencies. The first maximizes the sum of the net work per cycle and thermal efficiency while the second the net work per cycle and exergy efficiency. In both cases the optimal pressure ratio is closer to the pressure ratio that maximizes the net work per cycle.

  6. Performance analysis of a Kalina cycle for a central receiver solar thermal power plant with direct steam generation

    DEFF Research Database (Denmark)

    Modi, Anish; Haglind, Fredrik

    2014-01-01

    without corroding the equipment by using suitable additives with the mixture. The purpose of the study reported here was to investigate if there is any benefit of using a Kalina cycle for a direct steam generation, central receiver solar thermal power plant with high live steam temperature (450 C...... direct steam generation with water/steam as both the heat transfer fluid in the solar receivers and the cycle working fluid. This enables operating the plant with higher turbine inlet temperatures. Available literature suggests that it is feasible to use ammonia-water mixtures at high temperatures......Solar thermal power plants have attracted increasing interest in the past few years - with respect to both the design of the various plant components, and extending the operation hours by employing different types of storage systems. One approach to improve the overall plant efficiency is to use...

  7. Recent developments in thermally-driven seawater desalination: Energy efficiency improvement by hybridization of the MED and AD cycles

    KAUST Repository

    Ng, Kim Choon

    2015-01-01

    The energy, water and environment nexus is a crucial factor when considering the future development of desalination plants or industry in the water-stressed economies. New generation of desalination processes or plants has to meet the stringent environment discharge requirements and yet the industry remains highly energy efficient and sustainable when producing good potable water. Water sources, either brackish or seawater, have become more contaminated as feed while the demand for desalination capacities increase around the world. One immediate solution for energy efficiency improvement comes from the hybridization of the proven desalination processes to the newer processes of desalination: For example, the integration of the available thermally-driven to adsorption desalination (AD) cycles where significant thermodynamic synergy can be attained when cycles are combined. For these hybrid cycles, a quantum improvement in energy efficiency as well as in increase in water production can be expected. The advent of MED with AD cycles, or simply called the MEDAD cycles, is one such example where seawater desalination can be pursued and operated in cogeneration with the electricity production plants: The hybrid desalination cycles utilize only the low exergy bled-steam at low temperatures, complemented with waste exhaust or renewable solar thermal heat at temperatures between 60 and 80. °C. In this paper, the authors have reported their pioneered research on aspects of AD and related hybrid MEDAD cycles, both at theoretical models and experimental pilots. Using the cogeneration of electricity and desalination concept, the authors examined the cost apportionment of fuel cost by the quality or exergy of working steam for such cogeneration configurations.

  8. Effect of weld thermal cycle on the electrochemical corrosion of Q315NS steel in acidic solution

    Science.gov (United States)

    Zhang, Suqiang; Shu, Fengyuan; Zhao, Hongyun; Wang, Guodong; Wang, Shuai; Wang, Wenjian

    2017-04-01

    The effect of welding thermal process on the electrochemical corrosion of Q315NS in H2SO4 and HCl solution were investigated. Different weld thermal cycles with different peak temperatures were used in a Gleeble thermal-force simulation testing machine to simulate weld HAZ, and electrochemical measurements were carried out. The results demonstrate that a microstructure of granular bainite was generated in CGHAZ while others consisted of ferrite and pearlite. The electrochemical corrosion of different HAZ was different in H2SO4 and HCl, due to different microstructure. The BM and HAZs in 50 wt. % H2SO4 solution has a certain passivation behavior, while there was no passivation behavior in 3.5 wt. % HCl solution. The corrosion resistances in HAZs are inferior to that in BM. In addition, the corrosion resistance in the CGHAZ is the weakest.

  9. Phase transformations in thermally cycled Cu/ZrW2O8 composites investigated by synchrotron x-ray diffraction

    Science.gov (United States)

    Yilmaz, S.

    2002-01-01

    A Cu/ZrW2O8 metal matrix composite was thermally cycled between 298 and 591 K while being subjected to x-ray diffraction in transmission using high-intensity synchrotron radiation. The reversible allotropic phase transformations of ZrW2O8 between its two low-pressure phases and its high-pressure phase were observed within the composite bulk as a function of temperature. This observation gives experimental proof of the existence of the reversible pressure-induced phase transformation, which had been inferred indirectly from dilatometry in a previous investigation and assigned to the large thermal mismatch stresses in the composite. The volume fraction of each ZrW2O8 compound was determined from the measured diffracted intensity, and the thermal expansion behaviour of the composite was then calculated. Good agreement was found with the experimental dilatometric curve reported in a recent investigation.

  10. Evaluation of an Absorption Heat Pump to Mitigate Plant Capacity Reduction Due to Ambient Temperature Rise for an Air-Cooled Ammonia and Water Cycle: Preprint

    Energy Technology Data Exchange (ETDEWEB)

    Bharathan, D.; Nix, G.

    2001-08-06

    Air-cooled geothermal plants suffer substantial decreases in generating capacity at increased ambient temperatures. As the ambient temperature rises by 50 F above a design value of 50 F, at low brine-resource temperatures, the decrease in generating capacity can be more than 50%. This decrease is caused primarily by increased condenser pressure. Using mixed-working fluids has recently drawn considerable attention for use in power cycles. Such cycles are more readily amenable to use of absorption ''heat pumps.'' For a system that uses ammonia and water as the mixed-working fluid, this paper evaluates using an absorption heat pump to reduce condenser backpressure. At high ambient temperatures, part of the turbine exhaust vapor is absorbed into a circulating mixed stream in an absorber in series with the main condenser. This steam is pumped up to a higher pressure and heated to strip the excess vapor, which is recondensed using an additional air-cooled condenser. The operating conditions are chosen to reconstitute this condensate back to the same concentration as drawn from the original system. We analyzed two power plants of nominal 1-megawatt capacity. The design resource temperatures were 250 F and 300 F. Ambient temperature was allowed to rise from a design value of 50 F to 100 F. The analyses indicate that using an absorption heat pump is feasible. For the 300 F resource, an increased brine flow of 30% resulted in a net power increase of 21%. For the 250 F resource, the increase was smaller. However, these results are highly plant- and equipment-specific because evaluations must be carried out at off-design conditions for the condenser. Such studies should be carried out for specific power plants that suffer most from increased ambient temperatures.

  11. University of Minnesota aquifer thermal energy storage (ATES) project report on the second long-term cycle

    Energy Technology Data Exchange (ETDEWEB)

    Hoyer, M.C.; Hallgren, J.P.; Lauer, J.L.; Walton, M.; Eisenreich, S.J.; Howe, J.T.; Splettstoesser, J.F. (Minnesota Geological Survey, St. Paul, MN (United States))

    1991-12-01

    The technical feasibility of high-temperature (>100{degrees}C (>212{degrees}F)) aquifer thermal energy storage (ATES) in a deep, confined aquifer was tested in a series of experimental cycles at the University of Minnesota's St. Paul field test facility (FTF). This report describes the second long-term cycle (LT2), which was conducted from October 1986 through April 1987. Heat recovery; operational experience; and thermal, chemical, hydrologic, and geologic effects are reported. Approximately 61% of the 9.21 GWh of energy added to the 9.38 {times} 10{sup 4} m{sup 3} of ground water stored during LT2 was recovered. Temperatures of the water stored and recovered averaged 118{degrees}C (244{degrees}F) and 85{degrees}C (185{degrees}F), respectively. Results agreed with previous cycles conducted at the FTF. System operation during LT2 was nearly as planned. Operational experience from previous cycles at the FTF was extremely helpful. Ion-exchange softening of the heated and stored aquifer water prevented scaling in the system heat exchangers and the storage well, and changed the major-ion chemistry of the stored water. Sodium bicarbonate replaced magnesium and calcium bicarbonate as primary ions in the softened water. Water recovered form storage was approximately at equilibrium with respect to dissolved ions. Silica, calcium, and magnesium were significantly higher in recovered water than in injected water. Sodium was significantly lower in water recovered than in water stored.

  12. University of Minnesota aquifer thermal energy storage (ATES) project report on the second long-term cycle

    Energy Technology Data Exchange (ETDEWEB)

    Hoyer, M.C.; Hallgren, J.P.; Lauer, J.L.; Walton, M.; Eisenreich, S.J.; Howe, J.T.; Splettstoesser, J.F. [Minnesota Geological Survey, St. Paul, MN (United States)

    1991-12-01

    The technical feasibility of high-temperature [>100{degrees}C (>212{degrees}F)] aquifer thermal energy storage (ATES) in a deep, confined aquifer was tested in a series of experimental cycles at the University of Minnesota`s St. Paul field test facility (FTF). This report describes the second long-term cycle (LT2), which was conducted from October 1986 through April 1987. Heat recovery; operational experience; and thermal, chemical, hydrologic, and geologic effects are reported. Approximately 61% of the 9.21 GWh of energy added to the 9.38 {times} 10{sup 4} m{sup 3} of ground water stored during LT2 was recovered. Temperatures of the water stored and recovered averaged 118{degrees}C (244{degrees}F) and 85{degrees}C (185{degrees}F), respectively. Results agreed with previous cycles conducted at the FTF. System operation during LT2 was nearly as planned. Operational experience from previous cycles at the FTF was extremely helpful. Ion-exchange softening of the heated and stored aquifer water prevented scaling in the system heat exchangers and the storage well, and changed the major-ion chemistry of the stored water. Sodium bicarbonate replaced magnesium and calcium bicarbonate as primary ions in the softened water. Water recovered form storage was approximately at equilibrium with respect to dissolved ions. Silica, calcium, and magnesium were significantly higher in recovered water than in injected water. Sodium was significantly lower in water recovered than in water stored.

  13. Performance analysis of single stage libr-water absorption machine operated by waste thermal energy of internal combustion engine: Case study

    Science.gov (United States)

    Sharif, Hafiz Zafar; Leman, A. M.; Muthuraman, S.; Salleh, Mohd Najib Mohd; Zakaria, Supaat

    2017-09-01

    Combined heating, cooling, and power is also known as Tri-generation. Tri-generation system can provide power, hot water, space heating and air -conditioning from single source of energy. The objective of this study is to propose a method to evaluate the characteristic and performance of a single stage lithium bromide-water (LiBr-H2O) absorption machine operated with waste thermal energy of internal combustion engine which is integral part of trigeneration system. Correlations for computer sensitivity analysis are developed in data fit software for (P-T-X), (H-T-X), saturated liquid (water), saturated vapor, saturation pressure and crystallization temperature curve of LiBr-H2O Solution. Number of equations were developed with data fit software and exported into excel work sheet for the evaluation of number of parameter concerned with the performance of vapor absorption machine such as co-efficient of performance, concentration of solution, mass flow rate, size of heat exchangers of the unit in relation to the generator, condenser, absorber and evaporator temperatures. Size of vapor absorption machine within its crystallization limits for cooling and heating by waste energy recovered from exhaust gas, and jacket water of internal combustion engine also presented in this study to save the time and cost for the facilities managers who are interested to utilize the waste thermal energy of their buildings or premises for heating and air conditioning applications.

  14. Human power output during repeated sprint cycle exercise: the influence of thermal stress

    NARCIS (Netherlands)

    Ball, D.; Burrows, C.; Sargeant, A.J.

    1999-01-01

    Thermal stress is known to impair endurance capacity during moderate prolonged exercise. However, there is relatively little available information concerning the effects of thermal stress on the performance of high-intensity short-duration exercise. The present experiment examined human power output

  15. Development of a thermal scheme for a cogeneration combined-cycle unit with an SVBR-100 reactor

    Science.gov (United States)

    Kasilov, V. F.; Dudolin, A. A.; Krasheninnikov, S. M.

    2017-02-01

    At present, the prospects for development of district heating that can increase the effectiveness of nuclear power stations (NPS), cut down their payback period, and improve protection of the environment against harmful emissions are being examined in the nuclear power industry of Russia. It is noted that the efficiency of nuclear cogeneration power stations (NCPS) is drastically affected by the expenses for heat networks and heat losses during transportation of a heat carrier through them, since NPSs are usually located far away from urban area boundaries as required for radiation safety of the population. The prospects for using cogeneration power units with small or medium power reactors at NPSs, including combined-cycle units and their performance indices, are described. The developed thermal scheme of a cogeneration combined-cycle unit (CCU) with an SBVR-100 nuclear reactor (NCCU) is presented. This NCCU should use a GE 6FA gasturbine unit (GTU) and a steam-turbine unit (STU) with a two-stage district heating plant. Saturated steam from the nuclear reactor is superheated in a heat-recovery steam generator (HRSG) to 560-580°C so that a separator-superheater can be excluded from the thermal cycle of the turbine unit. In addition, supplemental fuel firing in HRSG is examined. NCCU effectiveness indices are given as a function of the ambient air temperature. Results of calculations of the thermal cycle performance under condensing operating conditions indicate that the gross electric efficiency η el NCCU gr of = 48% and N el NCCU gr = 345 MW can be achieved. This efficiency is at maximum for NCCU with an SVBR-100 reactor. The conclusion is made that the cost of NCCU installed kW should be estimated, and the issue associated with NCCUs siting with reference to urban area boundaries must be solved.

  16. Modelling of the generation phase of an absorption cooling cycle operating intermittently; Modelisation de la phase generation d'un cycle de refrigeration par absorption solaire a fonctionnement intermittent

    Energy Technology Data Exchange (ETDEWEB)

    Boukhchana, Yasmina; Fellah, Ali; Ben Brahim, Ammar [Unite de Recherche, Thermodynamique Appliquee (99/UR/11-21), Universite de Gabes, Ecole Nationale d' ingenieurs, 6072 Gabes (Tunisia)

    2011-01-15

    No abstract prepared. [French] La modelisation en regime dynamique de la phase generation d'une installation frigorifique a absorption solaire a fonctionnement intermittent utilisant le couple ammoniac/eau a ete elaboree. L'etude basee sur l'intermittence du fonctionnement a permis d'elaborer, a travers les bilans matieres et thermiques, un modele thermodynamique reliant les temperatures, les debits et les fractions massiques dans les differents compartiments. Des journees ensoleillees representatives des quatre saisons de l'annee ont ete considerees. Les variations du taux d'ensoleillement, des temperatures et des concentrations ont ete explorees. Les resultats ont montre, moyennant les hypotheses adoptees en particulier a pression de fonctionnement constante, que la demarche proposee a permis d'avoir une temperature de generation autour de 135 C et une temperature de condensation de 60 C. Ces temperatures sont atteinte par l'adaptation de la convection naturelle a l'air pour le fonctionnement du condenseur. (orig.)

  17. Seasonal redistribution of immune function in migrant shorebird: annual cycle effects override adjustments to thermal regime

    NARCIS (Netherlands)

    Buehler, D.M.; Piersma, T.; Matson, K.D.; Tieleman, B.I.

    2008-01-01

    Throughout the annual cycle, demands on competing physiological systems change, and animals must allocate resources to maximize fitness. Immune function is one such system and is important for survival. Yet detailed empirical data tracking immune function over the entire annual cycle are lacking for

  18. Long-term calcination/carbonation cycling and thermal pretreatment for CO{sub 2} capture by limestone and dolomite

    Energy Technology Data Exchange (ETDEWEB)

    Zhongxiang Chen; Hoon Sub Song; Miguel Portillo; C. Jim Lim; John R. Grace; E.J. Anthony [University of British Columbia, Vancouver, BC (Canada). Department of Chemical and Biological Engineering

    2009-03-15

    Capturing carbon dioxide is vital for the future of climate-friendly combustion, gasification, and steam-re-forming processes. Dry processes utilizing simple sorbents have great potential in this regard. Long-term calcination/carbonation cycling was carried out in an atmospheric-pressure thermogravimetric reactor. Although dolomite gave better capture than limestone for a limited number of cycles, the advantage declined over many cycles. Under some circumstances, decreasing the carbonation temperature increased the rate of reaction because of the interaction between equilibrium and kinetic factors. Limestone and dolomite, after being pretreated thermally at high temperatures (1000 or 1100{sup o}C), showed a substantial increase in calcium utilization over many calcination/carbonation cycles. Lengthening the pretreatment interval resulted in greater improvement. However, attrition was significantly greater for the pretreated sorbents. Greatly extending the duration of carbonation during one cycle was found to be capable of restoring the CO{sub 2} capture ability of sorbents to their original behavior, offering a possible means of countering the long-term degradation of calcium sorbents for dry capture of carbon dioxide. 12 refs., 12 figs., 2 tabs.

  19. Effects of bonding bakeout thermal cycles on pre- and post irradiation microstructures, physical, and mechanical properties of copper alloys

    Energy Technology Data Exchange (ETDEWEB)

    Singh, B.N.; Eldrup, M.; Toft, P.; Edwards, D.J. [Pacific Northwest National Laboratory, Richland, WA (United States)

    1996-10-01

    At present, dispersion strengthened (DS) copper is being considered as the primary candidate material for the ITER first wall and divertor components. Recently, it was agreed among the ITER parties that a backup alloy should be selected from the two well known precipitation hardened copper alloys, CuCrZr and CuNiBe. It was therefore decided to carry out screening experiments to simulate the effect of bonding and bakeout thermal cycles on microstructure, mechanical properties, and electrical resistivity of CuCrZr and CuNiBe alloys. On the basis of the results of these experiments, one of the two alloys will be selected as a backup material. Tensile specimens of CuCrZr and CuNiBe alloys were given various heat treatments corresponding to solution anneal, prime ageing, and bonding thermal cycle followed by reageing and the reactor bakeout treatment at 623K for 100 hours. Tensile specimens of the DS copper were also given the heat treatment corresponding to the bonding thermal cycle. A number of these heat treated specimens of CuCrZr, CuNiBe, and DS copper were neutron irradiated at 523K to a dose level of {approx}0.3 dpa (NRT) in the DR-3 reactor at Riso. Both unirradiated and irradiated specimens with the various heat treatments were tensile tested at 532K. The dislocation, precipitate and void microstructures and electrical resistivity of these specimens were also determined. Results of these investigations will be reported and discussed in terms of thermal and irradiation stability of precipitates and irradiation-induced precipitation and recovery of dislocation microstructure. Results show that the bonding and bakeout thermal cycles are not likely to have any serious deleterious effects on the performance of these alloys. The CuNiBe alloys were found to be susceptible to radiation-induced embrittlement, however, the exact mechanism is not yet known. It is thought that radiation-induced precipitation and segregation of the beryllium may be responsible.

  20. Heat recovery from a thermal energy storage based on the Ca(OH){sub 2}/CaO cycle

    Energy Technology Data Exchange (ETDEWEB)

    Azpiazu, M.N. [E.T.S. Ingenieros, Bilbao (Spain). Dpto. de Ingenieria Quimica y del Medio Ambiente; Morquillas, J.M. [E.T.S. Ingenieros, Bilbao (Spain). Dpto. de Maquinas y Motores Termicos; Vazquez, A. [E.S. da Marina Civil, La Coruna (Spain). Dpto. de Energia y Propulsion Maritima

    2003-04-01

    Thermal energy storage is very important in many applications related to the use of waste heat from industrial processes, renewable energies or from other sources. Thermochemical storage is very interesting for long-term storage as it can be carried out at room temperature with no energy losses. Dehydration/hydration cycle of Ca(OH){sub 2}/CaO has been applied for thermal energy storage in two types of reactors. One of them was a prototype designed by the authors, and in the other type conventional laboratory glassware was used. Parameters such as specific heats, reaction rate and enthalpy, mass losses and heat release were monitored during cycles. Although in the hydration step water is normally added in vapour phase, liquid water, at 0{sup o}C has been used in these experiences. Results indicated that the energy storage system performance showed no significant differences, when we compared several hydration/dehydration cycles. The selected chemical reaction did not exhibit a complete reversibility because complete Ca(OH){sub 2} dehydration, was not achieved. However the system could be used satisfactorily along 20 cycles at least. Heat recovery experiments showed general system behaviour during the hydration step in both types of reactors. The designed prototype was more efficient in this step. Main conclusions suggested carrying out one complete cycle at a higher dehydration temperature to recover total system reversibility. A modification of the prototype design trying to enhance heat transfer from the Ca(OH){sub 2} bed could also be proposed. (author)

  1. Numerical solution of Williamson fluid flow past a stretching cylinder and heat transfer with variable thermal conductivity and heat generation/absorption

    Directory of Open Access Journals (Sweden)

    M. Y. Malik

    2016-03-01

    Full Text Available In this article, Williamson fluid flow and heat transfer over a stretching cylinder is discussed. The thermal conductivity is assumed to be vary linearly with temperature. Heat generation/absorption effects are also taken into account. Modeled partial differential equations are converted into ordinary differential form by using appropriate transformations. Shooting method in conjunction with Runge-Kutta-Fehlberg method is used to find the solution of the problem. Moreover, the effects of different flow parameters γ, λ, ϵ, β and Pr on velocity and temperature profiles are shown graphically. Local Nusselt number and skin friction coefficient are shown in tabular and graphical form.

  2. Influence of thermal and mechanical cycling on the flexural strength of ceramics with titanium or gold alloy frameworks.

    Science.gov (United States)

    Oyafuso, Denise Kanashiro; Ozcan, Mutlu; Bottino, Marco Antonio; Itinoche, Marcos Koiti

    2008-03-01

    The aim of this study was to evaluate the effect of thermal and mechanical cycling alone or in combination, on the flexural strength of ceramic and metallic frameworks cast in gold alloy or titanium. Metallic frameworks (25 mm x 3 mm x 0.5 mm) (N=96) cast in gold alloy or commercial pure titanium (Ti cp) were obtained using acrylic templates. They were airborne particle-abraded with 150 microm aluminum oxide at the central area of the frameworks (8 mm x 3 mm). Bonding agent and opaque were applied on the particle-abraded surfaces and the corresponding ceramic for each metal was fired onto them. The thickness of the ceramic layer was standardized by positioning the frameworks in a metallic template (height: 1 mm). The specimens from each ceramic-metal combination (N=96, n=12 per group) were randomly assigned into four experimental fatigue conditions, namely water storage at 37 degrees C for 24h (control group), thermal cycling (3000 cycles, between 4 and 55 degrees C, dwell time: 10s), mechanical cycling (20,000 cycles under 10 N load, immersion in distilled water at 37 degrees C) and, thermal and mechanical cycling. A flexural strength test was performed in a universal testing machine (crosshead speed: 1.5 mm/min). Data were statistically analyzed using two-way ANOVA and Tukey's test (alpha=0.05). The mean flexural strength values for the ceramic-gold alloy combination (55+/-7.2MPa) were significantly higher than those of the ceramic-Ti cp combination (32+/-6.7 MPa) regardless of the fatigue conditions performed (pgold alloy (52+/-6.6 and 53+/-5.6 MPa, respectively) and ceramic-Ti cp combinations (29+/-6.8 and 29+/-6.8 MPa, respectively) compared to the control group (58+/-7.8 and 39+/-5.1 MPa, for gold and Ti cp, respectively) (pgold alloy frameworks exhibited a residue of ceramic material on the surface in all experimental groups. Mechanical and thermo-mechanical fatigue conditions decreased the flexural strength values for both ceramic-gold alloy and ceramic

  3. Water absorption and viscosity behaviour of thermally stable novel graft copolymer of carboxymethyl cellulose and poly(sodium 1-hydroxy acrylate).

    Science.gov (United States)

    Kumar, Bijender; Negi, Yuvraj Singh

    2018-02-01

    A novel thermally stable hydrolysed carboxymethyl cellulose-g-poly(sodium 1-hydroxy acrylate) i.e. CMC-g-PNaHA graft copolymer was synthesized from the CMC and vinyl monomer 5-methylene-2-isopropyl-1,3-dioxolan-4-one (MD) in an aqueous medium using an initiator followed by transformation of resulting CMC-g-PMD via alkaline hydrolysis. The graft copolymerization is confirmed by the Fourier transform infrared spectroscopy (FT-IR), Nuclear magnetic resonance spectroscopy (NMR) and X-ray diffractometer (XRD). The influence of the CMC and PNaHA content on the properties of the resulting hydrolysed CMC-g-PNaHA graft copolymer was investigated. In comparison with the PNaHA polymer, the resulted hydrolysed CMC-g-PNaHA grafted copolymer has improved thermal stability, water absorption properties, viscosity and weight-average molecular weight. Copyright © 2017 Elsevier Ltd. All rights reserved.

  4. Temperature-dependent absorption cross-sections in the thermal infrared bands of SF{sub 5}CF{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Rinsland, C.P. E-mail: c.p.rinsland@larc.nasa.gov; Sharpe, S.W.; Sams, R.L

    2003-12-15

    Absorption cross-sections have been measured at five temperatures between 213 and 323 K in the infrared bands of SF{sub 5}CF{sub 3}. The spectra were recorded at a resolution of 0.112 cm{sup -1} using a commercial Fourier transform infrared spectrometer and a 20 cm temperature-controlled sample cell. Samples of SF{sub 5}CF{sub 3} were pressurized with high-purity nitrogen to a total pressure of 1013.3 hPa (760 Torr). Six or more spectra with varying SF{sub 5}CF{sub 3} column amounts were analyzed at each temperature. The full spectral range of the measurements was 520-6500 cm{sup -1}, with only weak bands observed beyond 1400 cm{sup -1}. Absorption of thermal radiation in the 8-12 {mu}m atmospheric window region being important for climate change, we report here the integrated cross-sections of the significant absorption bands in that spectral region. Our results closely match room temperature values reported previously. Only small variation of the integrated absorption cross-sections with temperature was found. Our results confirm the accuracy of the previous measurements, which find SF{sub 5}CF{sub 3} important for global climate change on a per molecule basis. Absorption cross-sections derived from a single, near Doppler-limited spectrum recorded at room temperature do not show any rotational fine structure in the 700-950 cm{sup -1} region.

  5. Underwater Cycle Ergometry: Power Requirements With and Without Diver Thermal Dress

    National Research Council Canada - National Science Library

    Shykoff, B

    2009-01-01

    .... An ongoing problem has been that, although the power requirement of cycling in the water is known to be greater than that in air for the same ergometer setting, the magnitude of the difference...

  6. Limits and Optimization of Power Input or Output of Actual Thermal Cycles

    OpenAIRE

    Emin Açıkkalp; Hasan Yamık

    2013-01-01

    In classical thermodynamic, maximum power obtained from system (or minimum power supplied to system) defined as availability (exergy), but availability term is only used for reversible systems. In reality, there is no reversible system, all systems are irreversible, because reversible cycles doesn’t include constrains like time or size and they operates in quasi-equilibrium state. Purpose of this study is to define limits of the all basic thermodynamic cycles and to provide finite-time exergy...

  7. Absorption and Emission Spectroscopic Investigation of Thermal Dynamics and Photo-Dynamics of the Rhodopsin Domain of the Rhodopsin-Guanylyl Cyclase from the Nematophagous Fungus Catenaria anguillulae

    Directory of Open Access Journals (Sweden)

    Alfons Penzkofer

    2017-10-01

    Full Text Available The rhodopsin-guanylyl cyclase from the nematophagous fungus Catenaria anguillulae belongs to a recently discovered class of enzymerhodopsins and may find application as a tool in optogenetics. Here the rhodopsin domain CaRh of the rhodopsin-guanylyl cyclase from Catenaria anguillulae was studied by absorption and emission spectroscopic methods. The absorption cross-section spectrum and excitation wavelength dependent fluorescence quantum distributions of CaRh samples were determined (first absorption band in the green spectral region. The thermal stability of CaRh was studied by long-time attenuation measurements at room temperature (20.5 °C and refrigerator temperature of 3.5 °C. The apparent melting temperature of CaRh was determined by stepwise sample heating up and cooling down (obtained apparent melting temperature: 62 ± 2 °C. The photocycle dynamics of CaRh was investigated by sample excitation to the first inhomogeneous absorption band of the CaRhda dark-adapted state around 590 nm (long-wavelength tail, 530 nm (central region and 470 nm (short-wavelength tail and following the absorption spectra development during exposure and after exposure (time resolution 0.0125 s. The original protonated retinal Schiff base PRSBall-trans in CaRhda photo-converted reversibly to protonated retinal Schiff base PRSBall-trans,la1 with restructured surroundings (CaRhla1 light-adapted state, slightly blue-shifted and broadened first absorption band, recovery to CaRhda with time constant of 0.8 s and deprotonated retinal Schiff base RSB13-cis (CaRhla2 light-adapted state, first absorption band in violet to near ultraviolet spectral region, recovery to CaRhda with time constant of 0.35 s. Long-time light exposure of light-adapted CaRhla1 around 590, 530 and 470 nm caused low-efficient irreversible degradation to photoproducts CaRhprod. Schemes of the primary photocycle dynamics of CaRhda and the secondary photocycle dynamics of CaRhla1 are developed.

  8. A review of test results on solar thermal power modules with dish-mounted Stirling and Brayton cycle engines

    Science.gov (United States)

    Jaffe, Leonard D.

    1988-01-01

    This paper presents results of development tests of various solar thermal parabolic dish modules and assemblies that used dish-mounted Brayton or Stirling cycle engines for production of electric power. These tests indicate that early modules achieve net efficiencies up to 29 percent in converting sunlight to electricity, as delivered to the grid. Various equipment deficiencies were observed and a number of malfunctions occurred. The performance measurements, as well as the malfunctions and other test experience, provided information that should be of value in developing systems with improved performance and reduced maintenance.

  9. Integration of photovoltaic and concentrated solar thermal technologies for H2 production by the hybrid sulfur cycle

    Science.gov (United States)

    Liberatore, Raffaele; Ferrara, Mariarosaria; Lanchi, Michela; Turchetti, Luca

    2017-06-01

    It is widely agreed that hydrogen used as energy carrier and/or storage media may significantly contribute in the reduction of emissions, especially if produced by renewable energy sources. The Hybrid Sulfur (HyS) cycle is considered as one of the most promising processes to produce hydrogen through the water-splitting process. The FP7 project SOL2HY2 (Solar to Hydrogen Hybrid Cycles) investigates innovative material and process solutions for the use of solar heat and power in the HyS process. A significant part of the SOL2HY2 project is devoted to the analysis and optimization of the integration of the solar and chemical (hydrogen production) plants. In this context, this work investigates the possibility to integrate different solar technologies, namely photovoltaic, solar central receiver and solar troughs, to optimize their use in the HyS cycle for a green hydrogen production, both in the open and closed process configurations. The analysis carried out accounts for different combinations of geographical location and plant sizing criteria. The use of a sulfur burner, which can serve both as thermal backup and SO2 source for the open cycle, is also considered.

  10. Nanocomposite containing CaF2 nanoparticles: Thermal cycling, wear and long-term water-aging

    Science.gov (United States)

    Weir, Michael D.; Moreau, Jennifer L.; Levine, Eric D.; Strassler, Howard D.; Chow, Laurence C.; Xu, Hockin H. K.

    2012-01-01

    Objectives Fluoride (F) releasing dental restoratives are promising to promote remineralization and combat caries. The objectives of this study were to develop nanocomposite containing calcium fluoride nanoparticles (nCaF2), and to investigate the long-term mechanical durability including wear, thermal-cycling and long-term water-aging behavior. Methods Two types of fillers were used: nCaF2 with a diameter of 53 nm, and glass particles of 1.4 μm. Four composites were fabricated with fillers of: (1) 0% nCaF2 + 65% glass; (2) 10% nCaF2 + 55% glass; (3) 20% nCaF2 + 45% glass; (4) 30% nCaF2 + 35% glass. Three commercial materials were also tested. Specimens were subjected to thermal-cycling between 5 °C and 60 °C for 105 cycles, three-body wear for 4×105 cycles, and water-aging for 2 years. Results After thermal-cycling, the nCaF2 nanocomposites had flexural strengths in the range of 100-150 MPa, five times higher than the 20-30 MPa for resin-modified glass ionomer (RMGI). The wear scar depth showed an increasing trend with increasing nCaF2 filler level. Wear of nCaF2 nanocomposites was within the range of wear for commercial controls. Water-aging decreased the strength of all materials. At 2 years, flexural strength was 94 MPa for nanocomposite with 10% nCaF2, 60 MPa with 20% nCaF2, and 48 MPa with 30% nCaF2. They are 3-6 fold higher than the 15 MPa for RMGI (p nanocomposites appeared dense and solid. Significance Combining nCaF2 with glass particles yielded nanocomposites with long-term mechanical properties that were comparable to those of a commercial composite with little F release, and much better than those of RMGI controls. These strong long-term properties, together with their F release being comparable to RMGI as previously reported, indicate that the nCaF2 nanocomposites are promising for load-bearing and caries-inhibiting restorations. PMID:22429937

  11. Multiple regression models for the prediction of the maximum obtainable thermal efficiency of organic Rankine cycles

    DEFF Research Database (Denmark)

    Larsen, Ulrik; Pierobon, Leonardo; Wronski, Jorrit

    2014-01-01

    to power. In this study we propose four linear regression models to predict the maximum obtainable thermal efficiency for simple and recuperated ORCs. A previously derived methodology is able to determine the maximum thermal efficiency among many combinations of fluids and processes, given the boundary...... conditions of the process. Hundreds of optimised cases with varied design parameters are used as observations in four multiple regression analyses. We analyse the model assumptions, prediction abilities and extrapolations, and compare the results with recent studies in the literature. The models...

  12. Effect of Gaseous Impurities on Long-Term Thermal Cycling and Aging Properties of Complex Hydrides for Hydrogen Storage

    Energy Technology Data Exchange (ETDEWEB)

    Chandra, Dhanesh [Primary Contact; Lamb, Joshua; Chien, Wen-Ming; Talekar, Anjali; and Pal, Narendra

    2011-03-28

    This program was dedicated to understanding the effect of impurities on Long-Term Thermal Cycling and aging properties of Complex Hydrides for Hydrogen Storage. At the start of the program we found reversibility between Li2NH+LiH LiH+LiNH2 (yielding ~5.8 wt.%H capacity). Then we tested the effect of impurity in H2 gas by pressure cycling at 255°C; first with industrial gas containing ppm levels of O2 and H2O as major impurities. Both these impurities had a significant impact on the reversibility and decreased the capacity by 2.65 wt.%H. Further increase in number of cycles from 500 to 1100 showed only a 0.2 wt%H more weight loss, showing some capacity is still maintained after a significant number of cycles. The loss of capacity is attributed to the formation of ~55 wt% LiH and ~30% Li2O, as major contaminant phases, along with the hydride Li2NH phase; suggesting loss of nitrogen during cycling. The effect of 100 ppm H2O in H2 also showed a decrease of ~2.5 wt.%H (after 560 cycles), and 100ppm O2 in H2; a loss of ~4.1 wt.%. Methane impurity (100 ppm, 100cycles), showed a very small capacity loss of 0.9 wt.%H under similar conditions. However, when Li3N was pressure cycled with 100ppmN2-H2 there were beneficial effects were observed (255oC); the reversible capacity increased to 8.4wt.%H after 853 cycles. Furthermore, with 20 mol.%N2-H2 capacity increased to ~10 wt.%H after 516 cycles. We attribute this enhancement to the reaction of nitrogen with liquid lithium during cycling as the Gibbs free energy of formation of Li3N (Go = -98.7 kJ/mol) is more negative than that of LiH (Go = -50.3 kJ/mol). We propose that the mitigation of hydrogen capacity losses is due to the destabilization of the LiH phase that tends to accumulate during cycling. Also more Li2NH phase was found in the cycled product. Mixed Alanates (3LiNH2:Li3AlH6) showed that 7 wt% hydrogen desorbed under dynamic vacuum. Equilibrium experiments (maximum 12 bar H2) showed up to 4wt% hydrogen reversibly

  13. The effect of firing temperature on the irreversible expansion, water absorption and pore structure of a brick body during freeze-thaw cycles

    Directory of Open Access Journals (Sweden)

    Mikuláš ŠVEDA

    2013-12-01

    Full Text Available The paper deals with the monitoring of brick body in the process of volumetric freezing and thawing. The samples were fired at temperatures of 900, 1000 and 1060 °C. Attention is focused on monitoring of the irreversible expansion, water absorption and pore structure of a brick body. We found that in all cases the endpoints take place continuously, where the amount firing temperature plays a crucial role. The greatest influence of freeze/thaw cycles on the change of the pore structure was also observed at the lowest temperature. The change of the pore system during the freeze-thaw cycles occurs in such a way, that the pore volume of small pores further decreases and conversely, the pore volume of large pores increases. The knowledge gained can be used not only in the production of new but also in predicting the remaining durability of older clay roofing tiles. DOI: http://dx.doi.org/10.5755/j01.ms.19.4.2741

  14. Life cycle cost optimization of buildings with regard to energy use, thermal indoor environment and daylight

    DEFF Research Database (Denmark)

    Nielsen, Toke Rammer; Svendsen, Svend

    2002-01-01

    Buildings represent a large economical investment and have long service lives through which expenses for heating, cooling, maintenance and replacement depends on the chosen building design. Therefore, the building cost should not only be evaluated by the initial investment cost but rather...... by the life cycle cost taking all expenses in the buildings service life into consideration. Also the performance of buildings is important as the performance influences the comfort of the occupants, heating demand etc. Different performance requirements are stated in building codes, standards...... and by the customer. The influence of different design variables on life cycle cost and building performance is very complicated and the design variables can be combined in an almost unlimited number of ways. Optimization can be applied to achieve a building design with low life cycle cost and good performance...

  15. Amplitude of the diurnal temperature cycle as observed by thermal infrared and microwave radiometers

    Science.gov (United States)

    Land surface temperature (LST) is a key input to physically-based retrieval algorithms of hydrological states and fluxes, and global measurements of LST are provided by many satellite platforms. Passive microwave (MW) observations offer an alternative to conventional thermal infrared (TIR) LST retri...

  16. Thermophysical characterization and thermal cycling stability of two TCM: CaCl2 and zeolite

    NARCIS (Netherlands)

    Barreneche, C.; Fernández, A.I.; Cabeza, L.F.; Cuypers, R.

    2015-01-01

    At this moment, the global energy consumption in buildings is around 40% of the total energy consumption in developed countries. Thermal energy storage (TES) is presented as one way to address this energy-related problem proposing an alternative to reduce the gap between energy supply and energy

  17. Study on performances of colorless and transparent shape memory polyimide film in space thermal cycling, atomic oxygen and ultraviolet irradiation environments

    Science.gov (United States)

    Gao, Hui; Lan, Xin; Liu, Liwu; Xiao, Xinli; Liu, Yanju; Leng, Jinsong

    2017-09-01

    Shape memory polymers with high glass transition temperature (HSMPs) and HSMP-based deployable structures and devices, which can bear harsh operation conditions for durable applications, have attracted more and more interest in recent years. In this article, colorless and transparent shape memory polyimide (SMCTPI) films were subjected to simulated vacuum thermal cycling, atomic oxygen (AO) and ultraviolet (UV) irradiation environments up to 600 h, 556 h and 600 h for accelerated irradiation. The glass transition temperature (T g) determined by differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA) had no obvious changes after being irradiated by varying amounts of thermal cycling, AO and UV irradiation dose. After being irradiated by 50 thermal cycles, 10 × 1021 atoms cm-2 AO irradiation and 3000 ESH UV irradiation, shape recovery behaviors of SMCTPI films also had no obvious damage even if they experienced 30 shape memory cycles, while the surface morphologies and optical properties were seriously destroyed by AO irradiation, as compared with thermal cycling and UV irradiation. The tensile strength could separately maintain 122 MPa, 120 MPa and 70 MPa after 50 thermal cycles, 10 × 1021 atoms cm-2 AO irradiation and 3000 ESH UV irradiation, which shows great potential for use in aerospace structures and devices.

  18. COMBINED CYCLE GAS TURBINE FOR THERMAL POWER STATIONS: EXPERIENCE IN DESIGNING AND OPERATION, PROSPECTS IN APPLICATION

    Directory of Open Access Journals (Sweden)

    N. V. Karnitsky

    2014-01-01

    Full Text Available The paper has reviewed main world tendencies in power consumption and power system structure. Main schemes of combined cycle gas turbines have been considered in the paper. The paper contains an operational analysis of CCGT blocks that are operating within the Belarusian energy system. The analysis results have been given in tables showing main operational indices of power blocks

  19. The Effect of Thermal Cycling on the Surface Roughness of Dental Casting Investments.

    Science.gov (United States)

    1991-05-01

    refractory materials, usually silica as either quartz or cristobalite , and a binder that was a gypsum product in the form of plaster or stone. The...refractory materials <pand upon heating because of the thermal expansion of the material and the change in the crystalline state (alpha to beta ). Of the four...common stable forms of silica (quartz, tridymite, cristobalite , and fused or vitreous silica), cristobalite has the greatest expansion and lowest

  20. Technical Feasibility Study of Thermal Energy Storage Integration into the Conventional Power Plant Cycle

    OpenAIRE

    Wojcik, Jacek D.; Wang, Jihong

    2017-01-01

    The current load balance in the grid is managed mainly through peaking fossil-fuelled power plants that respond passively to the load changes. Intermittency, which comes from renewable energy sources, imposes additional requirements for even more flexible and faster responses from conventional power plants. A major challenge is to keep conventional generation running closest to the design condition with higher load factors and to avoid switching off periods if possible. Thermal energy storage...

  1. Thermophysical characterization and thermal cycling stability of two TCM: CaCl2 and zeolite

    OpenAIRE

    Barreneche Güerisoli, Camila; Fernández Renna, Ana Inés; Cabeza, Luisa F.; Cuypers, Ruud

    2015-01-01

    At this moment, the global energy consumption in buildings is around 40% of the total energy consumption in developed countries. Thermal energy storage (TES) is presented as one way to address this energyrelated problem proposing an alternative to reduce the gap between energy supply and energy demand. One way to store energy is using thermochemical materials (TCM). These types of materials allow accumulating energy through a chemical process at low temperature, almost without hea...

  2. Sensitivity analysis of a community solar system using annual cycle thermal energy storage

    Science.gov (United States)

    Baylin, F.; Monte, R.; Sillman, S.

    The objective of this research is to assess the sensitivity of design parameters for a community solar heating system having annual thermal energy storage to factors including climate, building type, community size and collector type and inclination. The system under consideration uses a large, water-filled, concrete-constructed tank for providing space heating and domestic hot water (DHW). This presentation outlines results and conclusions about system sizing; a system design study and economic analysis are underway.

  3. Power plant design with a combined cycle and double concentrated solar thermal power sources

    OpenAIRE

    Vidal i Parreu, Arnau

    2010-01-01

    The electricity has become an indispensable element of today’s society. Demand is growing continuously and the production is still based on limited sources of energy such as coal and petroleum derivate products. Environmental issues, such as global warming, and the uncertainty about the quantity of the conventional fossil fuels are forcing suppliers to find new solutions for the near future. In this assignment, concentrated solar thermal technologies for electricity generation could pla...

  4. Analyze and Improve Lifetime in 3L-NPC Inverter from Power Cycle and Thermal Balance

    DEFF Research Database (Denmark)

    Chen, Quan; Chen, Zhe; Wang, Qunjing

    2014-01-01

    Three-level Neutral-point-clamped (3L-NPC) topology is becoming a realistic alternative to the conventional one in high-voltage and high-power application. Studies show that the power cycling mean time to failure (MTTF) of the semiconductor bond wire in 3L-NPC inverter system may be very short...... and load voltage is applied to reduce power cycle and switching losses. And then, three-level active neutral point-clamped topology is taken into account to wake the most thermo stressed device. In order to validate the improve lifetime method in this paper, a 2MW 3L-NPC converter used in wind energy has...... under some common conditions. Firstly, this paper shows the impact of some key parameters on power electronic system lifetime according the analysis of semiconductor failure mechanism. Secondly, a switching frequency reduction method based on the position relationship between the flowing current...

  5. Thermal and Cycle-Life Behavior of Commercial Li-ion and Li-Polymer Cells

    Science.gov (United States)

    Zimmerman, Albert H.; Quinzio, M. V.

    2001-01-01

    Accelerated and real-time LEO cycle-life test data will be presented for a range of commercial Li-ion and Li-polymer (gel type) cells indicating the ranges of performance that can be obtained, and the performance screening tests that must be done to assure long life. The data show large performance variability between cells, as well as a highly variable degradation signature during non-cycling periods within the life tests. High-resolution Dynamic Calorimetry data will be presented showing the complex series of reactions occurring within these Li cells as they are cycled. Data will also be presented for cells being tested using an Adaptive Charge Control Algorithm (ACCA) that continuously adapts itself to changes in cell performance, operation, or environment to both find and maintain the optimum recharge over life. The ACCA has been used to prevent all unneeded overcharge for Li cells, NiCd cells and NiH2 cells. While this is important for all these cell types, it is most critical for Li-ion cells, which are not designed with electrochemical tolerance for overcharge.

  6. METHODS OF SAMPLE THERMAL MODIFICATION BY MEANS DOUBLE VAPORIZATION IN TWO STEP ATOMIZER FOR ATOMIC ABSORPTION ANALYSIS

    OpenAIRE

    Grinshtein, Ilia; Vilpan, Yuri; Saraev, Alexei; Vasilieva, Lubov

    2000-01-01

    After sample vaporization in two-step atomizer with a purged vaporizer sample vapors can be transferred into preheated or into non-heated atomizer. In the last case the atomizer walls trap the vapors and then the sample is second time vaporized and atomized by heating the atomizer. Thermal pre-treatment of a sample using this double vaporization makes possible the direct analysis of samples with strongly interfering matrices including solids. The technique was used for the direct determinatio...

  7. Relieving thermal discomfort: Effects of sprayed L-menthol on perception, performance, and time trial cycling in the heat.

    Science.gov (United States)

    Barwood, M J; Corbett, J; Thomas, K; Twentyman, P

    2015-06-01

    L-menthol stimulates cutaneous thermoreceptors and induces cool sensations improving thermal comfort, but has been linked to heat storage responses; this could increase risk of heat illness during self-paced exercise in the heat. Therefore, L-menthol application could lead to a discrepancy between behavioral and autonomic thermoregulatory drivers. Eight male participants volunteered. They were familiarized and then completed two trials in hot conditions (33.5 °C, 33% relative humidity) where their t-shirt was sprayed with CONTROL-SPRAY or MENTHOL-SPRAY after 10 km (i.e., when they were hot and uncomfortable) of a 16.1-km cycling time trial (TT). Thermal perception [thermal sensation (TS) and comfort (TC)], thermal responses [rectal temperature (Trec ), skin temperature (Tskin )], perceived exertion (RPE), heart rate, pacing (power output), and TT completion time were measured. MENTHOL-SPRAY made participants feel cooler and more comfortable and resulted in lower RPE (i.e., less exertion) yet performance was unchanged [TT completion: CONTROL-SPRAY 32.4 (2.9) and MENTHOL-SPRAY 32.7 (3.0) min]. Trec rate of increase was 1.40 (0.60) and 1.45 (0.40) °C/h after CONTROL-SPRAY and MENTHOL-SPRAY application, which were not different. Spraying L-menthol toward the end of self-paced exercise in the heat improved perception, but did not alter performance and did not increase heat illness risk. © 2015 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

  8. Influence of Thermal Cycling on Flexural Properties and Simulated Wear of Computer-aided Design/Computer-aided Manufacturing Resin Composites.

    Science.gov (United States)

    Tsujimoto, A; Barkmeier, W W; Takamizawa, T; Latta, M A; Miyazaki, M

    The purpose of this study was to evaluate the influence of thermal cycling on the flexural properties and simulated wear of computer-aided design/computer-aided manufacturing (CAD/CAM) resin composites. The six CAD/CAM resin composites used in this study were 1) Lava Ultimate CAD/CAM Restorative (LU); 2) Paradigm MZ100 (PM); 3) CERASMART (CS); 4) Shofu Block HC (SB); 5) KATANA AVENCIA Block (KA); and 6) VITA ENAMIC (VE). Specimens were divided randomly into two groups, one of which was stored in distilled water for 24 hours, and the other of which was subjected to 10,000 thermal cycles. For each material, 15 specimens from each group were used to determine the flexural strength and modulus according to ISO 6872, and 20 specimens from each group were used to examine wear using a localized wear simulation model. The test materials were subjected to a wear challenge of 400,000 cycles in a Leinfelder-Suzuki device (Alabama machine). The materials were placed in custom-cylinder stainless steel fixtures, and simulated localized wear was generated using a stainless steel ball bearing (r=2.387 mm) antagonist in a water slurry of polymethyl methacrylate beads. Simulated wear was determined using a noncontact profilometer (Proscan 2100) with Proscan and AnSur 3D software. The two-way analysis of variance of flexural properties and simulated wear of CAD/CAM resin composites revealed that material type and thermal cycling had a significant influence (p0.05) between the two factors. The flexural properties and maximum depth of wear facets of CAD/CAM resin composite were different (pinfluenced (p>0.05) by thermal cycling, except in the case of VE. The volume losses in wear facets on LU, PM, and SB after 10,000 thermal cycles were significantly higher (pinfluenced by thermal cycling.

  9. Accuracy of the thermal neutron absorption cross section measurements (based on examples of selected pulsed beam methods); Dokladnosc pomiarow przekroju czynnego absorpcji neutronow termicznych (na przykladzie wybranych metod impulsowych)

    Energy Technology Data Exchange (ETDEWEB)

    Krynicka, E. [The H. Niewodniczanski Inst. of Nuclear Physics, Cracow (Poland)

    1997-12-31

    The problem of accuracy of the thermal neutron macroscopic absorption cross section determination is discussed on examples of selected measurement methods which use non-stationary neutron fields. The computer simulation method elaborated by the author is presented as a procedure for estimating the standard deviation of the measured absorption cross section. The computer simulation method presented can be easily utilized to estimate the accuracy of measurement of various physical magnitudes. (author) 46 refs, 3 figs, 1 tab

  10. Effect of weld thermal cycle on helium bubble formation in stainless steel

    Science.gov (United States)

    Kano, F.; Nakahigashi, S.; Nakamura, H.; Uesugi, N.; Mitamura, T.; Terasawa, M.; Irie, H.; Fukuya, K.

    1998-10-01

    Helium bubble structure was examined on a helium-implanted stainless steel after applying two kinds of heat input. Helium ions were implanted on Type 304 stainless steel at 573 K from 2 to 200 appm to a peak depth of 0.5 μm from the surface. After that, weld thermal history was applied by an electron beam. The cooling rates were selected to be 370 and 680 K/s from 1023 to 773 K. TEM observation revealed that nucleation and growth of helium bubbles were strongly dependent on the cooling rate after welding and the helium concentration.

  11. Evaluation of the of thermal shock resistance of a castable containing andalusite aggregates by thermal shock cycles; Avaliacao da resistencia ao dano por choque termico por ciclagem de um concreto refratario contendo agregados de andaluzita

    Energy Technology Data Exchange (ETDEWEB)

    Garcia, G.C.R.; Santos, E.M.B.; Ribeiro, S., E-mail: girribeiro@yahoo.com.br [Universidade de Sao Paulo (DEMAR/EEL/USP), Lorena, SP (Brazil). Escola de Engenharia de. Departamento de Engenharia de Materiais; Resende, W.S. [Industrias Brasileiras de Artigos Refratarios (IBAR), Lorena, SP (Brazil); Rodrigues, J.A. [Universidade Federal de Sao Carlos (UFSCar), SP (Brazil)

    2011-07-01

    The thermal shock resistance of refractory materials is one of the most important characteristics that determine their performance in many applications, since abrupt and drastic differences in temperature can damage them. Resistance to thermal shock damage can be evaluated based on thermal cycles, i.e., successive heating and cooling cycles followed by an analysis of the drop in Young's modulus occurring in each cycle. The aim of this study was to evaluate the resistance to thermal shock damage in a commercial refractory concrete with andalusite aggregate. Concrete samples that were sintered at 1000 deg C and 1450 deg C for 5 hours to predict and were subjected to 30 thermal shock cycles, soaking in the furnace for 20 minutes at a temperature of 1000 deg C, and subsequent cooling in circulating water at 25 deg C. The results showed a decrease in Young's modulus and rupture around 72% for samples sintered at 1000 ° C, and 82% in sintered at 1450 ° C. The refractory sintered at 1450 deg C would show lower thermal shock resistance than the refractory sintered at 1000 deg C. (author)

  12. Effects of Thermal Radiation on Mixed Convection Flow of a Micropolar Fluid from an Unsteady Stretching Surface with Viscous Dissipation and Heat Generation/Absorption

    Directory of Open Access Journals (Sweden)

    Khilap Singh

    2016-01-01

    Full Text Available A numerical model is developed to examine the effects of thermal radiation on unsteady mixed convection flow of a viscous dissipating incompressible micropolar fluid adjacent to a heated vertical stretching surface in the presence of the buoyancy force and heat generation/absorption. The Rosseland approximation is used to describe the radiative heat flux in the energy equation. The model contains nonlinear coupled partial differential equations which have been converted into ordinary differential equation by using the similarity transformations. The dimensionless governing equations for this investigation are solved by Runge-Kutta-Fehlberg fourth fifth-order method with shooting technique. Numerical solutions are then obtained and investigated in detail for different interesting parameters such as the local skin-friction coefficient, wall couple stress, and Nusselt number as well as other parametric values such as the velocity, angular velocity, and temperature.

  13. Thermal conductance of interfaces with molecular layers - low temperature transient absorption study on gold nanorods supported on self assembled monolayers

    Science.gov (United States)

    Wang, Wei; Huang, Jingyu; Murphy, Catherine; Cahill, David; University of Illinois At Urbana Champaign, Department of Materials Science; Engineering Team; Department Collaboration

    2011-03-01

    While heat transfer via phonons across solid-solid boundary has been a core field in condense matter physics for many years, vibrational energy transport across molecular layers has been less well elucidated. We heat rectangular-shaped gold nanocrystals (nanorods) with Ti-sapphire femtosecond pulsed laser at their longitudinal surface plasmon absorption wavelength to watch how their temperature evolves in picoseconds transient. We observed single exponential decay behavior, which suggests that the heat dissipation is only governed by a single interfacial conductance value. The ``RC'' time constant was 300ps, corresponding to a conductance value of 95MW/ m 2 K. This interfacial conductance value is also a function of ambient temperature since at temperatures as low as 80K, which are below the Debye temperature of organic layers, several phonon modes were quenched, which shut down the dominating channels that conduct heat at room temperature.

  14. The Annual Cycle of Water Vapor on Mars as Observed by the Thermal Emission Spectrometer

    Science.gov (United States)

    Smith, Michael D.; Vondrak, Richard R. (Technical Monitor)

    2001-01-01

    Spectra taken by the Mars Global Surveyor Thermal Emission Spectrometer (TES) have been used to monitor the latitude, longitude, and seasonal dependence of water vapor for over one full Martian year (March 1999-March 2001). A maximum in water vapor abundance is observed at high latitudes during mid-summer in both hemispheres, reaching a maximum value of approximately 100 pr-micrometer in the north and approximately 50 pr-micrometer in the south. Low water vapor abundance (water vapor. The latitudinal and seasonal dependence of the decay of the northern summer water vapor maximum implies cross-equatorial transport of water to the southern hemisphere, while there is little or no corresponding transport during the decay of the southern hemisphere summer maximum. The latitude-longitude dependence of annually-averaged water vapor (corrected for topography) has a significant positive correlation with albedo and significant negative correlations with thermal inertia and surface pressure. Comparison of TES results with those retrieved from the Viking Orbiter Mars Atmospheric Water Detectors (MAWD) experiments shows some similar features, but also many significant differences. The southern hemisphere maximum observed by TES was not observed by MAWD and the large latitudinal gradient in annually-averaged water vapor observed by MAWD does not appear in the TES results.

  15. Nutrient-cycling mechanisms other than the direct absorption from soil may control forest structure and dynamics in poor Amazonian soils.

    Science.gov (United States)

    Grau, Oriol; Peñuelas, Josep; Ferry, Bruno; Freycon, Vincent; Blanc, Lilian; Desprez, Mathilde; Baraloto, Christopher; Chave, Jérôme; Descroix, Laurent; Dourdain, Aurélie; Guitet, Stéphane; Janssens, Ivan A; Sardans, Jordi; Hérault, Bruno

    2017-03-23

    Tropical forests store large amounts of biomass despite they generally grow in nutrient-poor soils, suggesting that the role of soil characteristics in the structure and dynamics of tropical forests is complex. We used data for >34 000 trees from several permanent plots in French Guiana to investigate if soil characteristics could predict the structure (tree diameter, density and aboveground biomass), and dynamics (growth, mortality, aboveground wood productivity) of nutrient-poor tropical forests. Most variables did not covary with site-level changes in soil nutrient content, indicating that nutrient-cycling mechanisms other than the direct absorption from soil (e.g. the nutrient uptake from litter, the resorption, or the storage of nutrients in the biomass), may strongly control forest structure and dynamics. Ecosystem-level adaptations to low soil nutrient availability and long-term low levels of disturbance may help to account for the lower productivity and higher accumulation of biomass in nutrient-poor forests compared to nutrient-richer forests.

  16. Product mass transfer resistance directly determined during freeze-drying cycle runs using tunable diode laser absorption spectroscopy (TDLAS) and pore diffusion model.

    Science.gov (United States)

    Kuu, Wei Y; O'Bryan, Kevin R; Hardwick, Lisa M; Paul, Timothy W

    2011-08-01

    The pore diffusion model is used to express the dry layer mass transfer resistance, [Formula: see text], as a function of the ratio r(e)/?, where r(e) is the effective pore radius and ? is the tortuosity factor of the dry layer. Using this model, the effective pore radius of the dry layer can be estimated from the sublimation rate and product temperature profiles measured during primary drying. Freeze-drying cycle runs were performed using the LyoStar II dryer (FTS Systems), with real-time sublimation rate profiles during freeze drying continuously measured by tunable diode laser absorption spectroscopy (TDLAS). The formulations chosen for demonstration of the proposed approach include 5% mannitol, 5% sucrose, 5% lactose, 3% mannitol plus 2% sucrose, and a parenteral nutrition formulation denoted VitaM12. The three different methods used for determination of the product resistance are: (1) Using both the sublimation rate and product temperature profiles, (2) using the sublimation rate profile alone, and (3) using the product temperate profile alone. Unlike the second and third methods, the computation procedure of first method does not need solution of the complex heat and mass transfer equations.

  17. Thermal-Economic Modularization of Small, Organic Rankine Cycle Power Plants for Mid-Enthalpy Geothermal Fields

    Directory of Open Access Journals (Sweden)

    Yodha Y. Nusiaputra

    2014-07-01

    Full Text Available The costs of the surface infrastructure in mid-enthalpy geothermal power systems, especially in remote areas, could be reduced by using small, modular Organic Rankine Cycle (ORC power plants. Thermal-economic criteria have been devised to standardize ORC plant dimensions for such applications. We designed a modular ORC to utilize various wellhead temperatures (120–170 °C, mass flow rates and ambient temperatures (−10–40 °C. A control strategy was developed using steady-state optimization, in order to maximize net power production at off-design conditions. Optimum component sizes were determined using specific investment cost (SIC minimization and mean cashflow (MCF maximization for three different climate scenarios. Minimizing SIC did not yield significant benefits, but MCF proved to be a much better optimization function.

  18. Thermally activated delayed fluorescence as a cycling process between excited singlet and triplet states: application to the fullerenes.

    Science.gov (United States)

    Baleizão, Carlos; Berberan-Santos, Mário N

    2007-05-28

    In efficient thermally activated delayed fluorescence (TADF) the excited chromophore alternates randomly between the singlet and triplet manifolds a large number of times before emission occurs. In this work, the average number of cycles n is obtained and is shown to have a simple experimental meaning: n+1 is the intensification factor of the prompt fluorescence intensity, owing to the occurrence of TADF. A new method of data analysis for the determination of the quantum yield of triplet formation, combining steady-state and time-resolved data in a single plot, is also presented. Application of the theoretical results to the TADF of [70]fullerenes shows a general good agreement between different methods of fluorescence analysis and allows the determination of several photophysical parameters.

  19. Deposition Time and Thermal Cycles of Fabricating Thin-wall Steel Parts by Double Electrode GMAW Based Additive Manufacturing

    Directory of Open Access Journals (Sweden)

    Yang Dongqing

    2017-01-01

    Full Text Available The deposition time for fabricating the thin-wall part as well as the peak temperature of the substrate during the process was analyzed in the double electrode gas metal arc welding (DE-GMAW based additive manufacturing (AM. The total deposition time and the interlayer idle time of the manufacturing process decreased with the increasing of the bypass current under the same interlayer temperature and the same deposition rate. The thermal cycling curves illustrated that the peak temperature of the substrate was lower in the DE-GMAW base AM under the same conditions. When depositing the thin-wall parts, the DE-GMAW based AM can reduce the heat input to the substrate and improve the fabrication efficiency, compared with the GMAW based AM.

  20. Monitoring the Degradation Process of Inconel 600 and its Aluminide Coatings under Molten Sulfate Film with Thermal Cycles by Electrochemical Measurements

    Energy Technology Data Exchange (ETDEWEB)

    Take, S.; Yoshinaga, S.; Yanagita, M.; Itoi, Y. [Oyama College, Tochigi (Japan)

    2016-12-15

    With a specially designed electrochemical cell, the changes in impedance behavior for Inconel 600 and aluminide diffusion coatings under molten sulfate film with thermal cycles (from 800 ℃ to 350 ℃) were monitored with electrochemical impedance measurements. It was found that corrosion resistance for both materials increased with lower temperatures. At the same time, the state of molten salt was also monitored successfully by measuring the changes in impedance at high frequency, which generally represents the resistance of molten salt itself. After two thermal cycles, both Inconel 600 and aluminide diffusion coatings showed excellent corrosion resistance. The results from SEM observation and EDS analysis correlated well with the results obtained by electrochemical impedance measurements. It is concluded that electrochemical impedance is very useful for monitoring the corrosion resistance of materials under molten salt film conditions even with thermal cycles.

  1. Energy losses in thermally cycled optical fibers constrained in small bend radii

    Energy Technology Data Exchange (ETDEWEB)

    Guild, Eric; Morelli, Gregg

    2012-09-23

    High energy laser pulses were fired into a 365μm diameter fiber optic cable constrained in small radii of curvature bends, resulting in a catastrophic failure. Q-switched laser pulses from a flashlamp pumped, Nd:YAG laser were injected into the cables, and the spatial intensity profile at the exit face of the fiber was observed using an infrared camera. The transmission of the radiation through the tight radii resulted in an asymmetric intensity profile with one half of the fiber core having a higher peak-to-average energy distribution. Prior to testing, the cables were thermally conditioned while constrained in the small radii of curvature bends. Single-bend, double-bend, and U-shaped eometries were tested to characterize various cable routing scenarios.

  2. Impacts of weld residual stresses and fatigue crack growth threshold on crack arrest under high-cycle thermal fluctuations

    Energy Technology Data Exchange (ETDEWEB)

    Taheri, Said, E-mail: Said.taheri@edf.fr [EDF-LAB, IMSIA, 7 Boulevard Gaspard Monge, 91120 Palaiseau Cedex (France); Julan, Emricka [EDF-LAB, AMA, 7 Boulevard Gaspard Monge, 91120 Palaiseau Cedex (France); Tran, Xuan-Van [EDF Energy R& D UK Centre/School of Mechanical, Aerospace and Civil Engineering, The University of Manchester, Manchester M13 9PL (United Kingdom); Robert, Nicolas [EDF-DPN, UNIE, Strategic Center, Saint Denis (France)

    2017-01-15

    Highlights: • For crack growth analysis, weld residual stress field must be considered through its SIF in presence of a crack. • Presence of cracks of same depth proves their arrest, where equal depth is because mean stress acts only on crack opening. • Not considering amplitudes under a fatigue crack growth threshold (FCGT) does not compensate the lack of FGCT in Paris law. • Propagation rates are close for axisymmetric and circumferential semi-elliptical cracks. - Abstract: High cycle thermal crazing has been observed in some residual heat removal (RHR) systems made of 304 stainless steel in PWR nuclear plants. This paper deals with two types of analyses including logical argumentation and simulation. Crack arrest in networks is demonstrated due to the presence of two cracks of the same depth in the network. This identical depth may be proved assuming that mean stress acts only on crack opening and that cracks are fully open during the load cycle before arrest. Weld residual stresses (WRS) are obtained by an axisymmetric simulation of welding on a tube with a chamfer. Axisymmetric and 3D parametric studies of crack growth on: representative sequences for variable amplitude thermal loading, fatigue crack growth threshold (FCGT), permanent mean stress, cyclic counting methods and WRS, are performed with Code-Aster software using XFEM methodology. The following results are obtained on crack depth versus time: the effect of WRS on crack growth cannot be determined by the initial WRS field in absence of crack, but by the associated stress intensity factor. Moreover the relation between crack arrest depth and WRS is analyzed. In the absence of FCGT Paris’s law may give a significant over-estimation of crack depth even if amplitudes of loading smaller than FCGT have not been considered. Appropriate depth versus time may be obtained using different values of FCGT, but axisymmetric simulations do not really show a possibility of arrest for shallow cracks in

  3. University of Minnesota aquifer thermal energy storage (ATES) project report on the third long-term cycle

    Energy Technology Data Exchange (ETDEWEB)

    Hoyer, M.C.; Hallgren, J.P.; Uebel, M.H.; Delin, G.N.; Eisenreich, S.J.; Sterling, R.L.

    1994-12-01

    The University of Minnesota aquifer thermal energy storage (ATES) system has been operated as a field test facility (FTF) since 1982. The objectives were to design, construct, and operate the facility to study the feasibility of high-temperature ATES in a confined aquifer. Four short-term and two long-term cycles were previously conducted, which provided a greatly increased understanding of the efficiency and geochemical effects of high-temperature aquifer thermal energy storage. The third long-term cycle (LT3) was conducted to operate the ATES system in conjunction with a real heating load and to further study the geochemical impact that heated water storage had on the aquifer. For LT3, the source and storage wells were modified so that only the most permeable portion, the Ironton-Galesville part, of the Franconia-Ironton-Galesville aquifer was used for storage. This was expected to improve storage efficiency by reducing the surface area of the heated volume and simplify analysis of water chemistry results by reducing the number of aquifer-related variables which need to be considered. During LT3, a total volume of 63.2 {times} 10{sup 3} m {sup 3} of water was injected at a rate of 54.95 m{sup 3}/hr into the storage well at a mean temperature of 104.7{degrees}C. Tie-in to the reheat system of the nearby Animal Sciences Veterinary Medicine (ASVM) building was completed after injection was completed. Approximately 66 percent (4.13 GWh) of the energy added to the aquifer was recovered. Approximately 15 percent (0.64 GWh) of the usable (10 building. Operations during heat recovery with the ASVM building`s reheat system were trouble-free. Integration into more of the ASVM (or other) building`s mechanical systems would have resulted in significantly increasing the proportion of energy used during heat recovery.

  4. Low Temperature Creep of Hot-Extruded Near-Stoichiometric NiTi Shape Memory Alloy. Part 2; Effect of Thermal Cycling

    Science.gov (United States)

    Raj, S. V.; Noebe, R. D.

    2013-01-01

    This paper is the first report on the effect prior low temperature creep on the thermal cycling behavior of NiTi. The isothermal low temperature creep behavior of near-stoichiometric NiTi between 300 and 473 K was discussed in Part I. The effect of temperature cycling on its creep behavior is reported in the present paper (Part II). Temperature cycling tests were conducted between either 300 or 373 K and 473 K under a constant applied stress of either 250 or 350 MPa with hold times lasting at each temperature varying between 300 and 700 h. Each specimen was pre-crept either at 300 or at 473 K for several months under an identical applied stress as that used in the subsequent thermal cycling tests. Irrespective of the initial pre-crept microstructures, the specimens exhibited a considerable increase in strain with each thermal cycle so that the total strain continued to build-up to 15 to 20 percent after only 5 cycles. Creep strains were immeasurably small during the hold periods. It is demonstrated that the strains in the austenite and martensite are linearly correlated. Interestingly, the differential irrecoverable strain, in the material measured in either phase decreases with increasing number of cycles, similar to the well-known Manson-Coffin relation in low cycle fatigue. Both phases are shown to undergo strain hardening due to the development of residual stresses. Plots of true creep rate against absolute temperature showed distinct peaks and valleys during the cool-down and heat-up portions of the thermal cycles, respectively. Transformation temperatures determined from the creep data revealed that the austenitic start and finish temperatures were more sensitive to the pre-crept martensitic phase than to the pre-crept austenitic phase. The results are discussed in terms of a phenomenological model, where it is suggested that thermal cycling between the austenitic and martensitic phase temperatures or vice versa results in the deformation of the austenite and

  5. Computer code system for the R and D of nuclear fuel cycle with fast reactor. 2. Development and application of analytical evaluation system for thermal striping phenomena

    Energy Technology Data Exchange (ETDEWEB)

    Muramatsu, Toshiharu [Japan Nuclear Cycle Development Inst., Oarai, Ibaraki (Japan). Oarai Engineering Center

    2001-09-01

    Fluid-structure thermal interaction phenomena characterized by stationary random temperature fluctuations, namely thermal striping are observed in the downstream region such as a T-junction piping system of liquid metal fast reactors (LMFRs). Therefore, the piping wall located in the downstream region must be protected against the stationary random thermal process, which might induce high-cycle fatigue. This paper describes the evaluation system based on numerical simulation methods consisting of three thermohydraulics computer programs AQUA, DINUS-3 and THEMIS and of three thermomechanical computer programs BEMSET, FINAS and CANIS, for the thermal striping developed at Japan Nuclear Cycle Development Institute (JNC). Verification results for each computer code and the system are also introduced based on out-of-pile experimental data using water and sodium as working fluids. (author)

  6. Thermal recycling of polystyrene and polystyrene-butadiene dissolved in a light cycle oil

    Energy Technology Data Exchange (ETDEWEB)

    Arandes, Jose M.; Erena, Javier; Olazar, Martin; Bilbao, Javier [Departamento de Ingenieria Quimica, Universidad del Pais Vasco, Apartado 644, 48080 Bilbao (Spain); Azkoiti, Miren J. [Departamento de Ingenieria Quimica y del Medio Ambiente, Universidad del Pais Vasco, Plaza de la Casilla 3, 48012 Bilbao (Spain)

    2003-12-01

    A study has been made of the cracking on a mesoporous silica of polystyrene (PS) and polystyrene-butadiene (PS-BD) dissolved in a light cycle oil (LCO) from a product stream of a commercial fluid catalytic cracking (FCC) unit. This study has been carried out in a reactor of short contact time (3 s) in the 723-823 K range. This strategy for simultaneous valorization of plastics and solvent avoids the technological problems inherent to the treatment of solid postconsumer-plastics and the limitation to heat transfer in the process of pyrolysis. The cracking of plastics has a synergistic effect on the conversion of LCO, as it contributes to increasing the yield of gasoline (C{sub 5}-C{sub 12}). The cracking of the PS/LCO blend produces high yields of styrene, whereas the cracking of the PS-BD/LCO blend produces a stream of products with petrochemical interest.

  7. Effects of Hygrothermal Cycling on the Chemical, Thermal, and Mechanical Properties of 862/W Epoxy Resin

    Science.gov (United States)

    Miller, Sandi G.; Roberts, Gary D.; Copa, Christine C.; Bail, Justin L.; Kohlman, Lee W.; Binienda, Wieslaw K.

    2011-01-01

    The hygrothermal aging characteristics of an epoxy resin were characterized over 1 year, which included 908 temperature and humidity cycles. The epoxy resin quickly showed evidence of aging through color change and increased brittleness. The influence of aging on the material s glass transition temperature (Tg) was evaluated by Differential Scanning Calorimetry (DSC) and Dynamic Mechanical Analysis (DMA). The Tg remained relatively constant throughout the year long cyclic aging profile. The chemical composition was monitored by Fourier Transform Infrared Spectroscopy (FTIR) where evidence of chemical aging and advancement of cure was noted. The tensile strength of the resin was tested as it aged. This property was severely affected by the aging process in the form of reduced ductility and embrittlement. Detailed chemical evaluation suggests many aging mechanisms are taking place during exposure to hygrothermal conditions. This paper details the influence of processes such as: advancement of cure, chemical degradation, and physical aging on the chemical and physical properties of the epoxy resin.

  8. The Effects of CaCO3 Coated Wood Free Paper Usage as Filler on Water Absorption, Mechanical and Thermal Properties of Cellulose-High Density Polyethylene Composites

    Directory of Open Access Journals (Sweden)

    Emrah PEŞMAN

    2016-11-01

    Full Text Available In this study some physical, mechanical and thermal characteristics of high density polyethylene (HDPE and CaCO3 coated/pigmented wood free paper fiber composites were investigated. The fillers used in this study were uncoated cellulose, 5.8 %, 11.5 %, 16.5 % and 23.1 % CaCO3 coated wood free paper fibers. Each filler type was mixed with HDPE at 40% by weight fiber loading. In this case, the ratio of CaCO3 in plastic composites were calculated as 0 %, 2.3 %, 4.6 %, 6.6 % and 9.2 % respectively. Increased CaCO3 ratio improved the moisture resistant, flexural and tensile strength of cellulose-HDPE composites. However, the density of the cellulose-HDPE composites increased with CaCO3 addition. Energy Dispersive Spectroscopy on Scanning Electron Microscope analysis demonstrated the uniform distribution of CaCO3 and cellulose fiber in plastic matrix. In addition, the thermal properties of fiber plastic composites were investigated. The results of Differential scanning calorimetry analysis revealed that the crystallinity of the samples decreased with increasing CaCO3 content. Consequently, this work showed that CaCO3 coated waste paper fibers could be used as reinforcing filler against water absorption in thermoplastic matrix.DOI: http://dx.doi.org/10.5755/j01.ms.22.4.14222

  9. Interstitial oxygen molecules in amorphous SiO2. I. Quantitative concentration analysis by thermal desorption, infrared photoluminescence, and vacuum-ultraviolet optical absorption

    Science.gov (United States)

    Kajihara, Koichi; Hirano, Masahiro; Uramoto, Motoko; Morimoto, Yukihiro; Skuja, Linards; Hosono, Hideo

    2005-07-01

    The amount of oxygen molecules (O2) in amorphous SiO2(a-SiO2), also called interstitial O2, was quantitatively measured by combining thermal-desorption spectroscopy (TDS) with infrared photoluminescence (PL) measurements of interstitial O2 at 1272 nm while exciting with 1064-nm Nd: yttrium aluminum garnet laser light. It was found that the amount of O2 released by the TDS measurement is proportional to the intensity decrease of the PL band, demonstrating that a-SiO2 easily emits interstitial O2 during thermal annealing in vacuum. This correlation yielded the proportionality coefficient between the absolute concentration of interstitial O2 and its PL intensity normalized against the intensity of the fundamental Raman bands of a-SiO2. This relationship was further used to determine the optical-absorption cross section of the Schumann-Runge band of the interstitial O2 located at photon energies ≳6.5eV. This band is significantly redshifted and has a larger cross section compared to that of O2 in the gas phase.

  10. Life cycle assessment of hemp cultivation and use of hemp-based thermal insulator materials in buildings.

    Science.gov (United States)

    Zampori, Luca; Dotelli, Giovanni; Vernelli, Valeria

    2013-07-02

    The aim of this research is to assess the sustainability of a natural fiber, such as hemp (Cannabis sativa), and its use as thermal insulator for building applications. The sustainability of hemp was quantified by life cycle assessment (LCA) and particular attention was given to the amount of CO2eq of the whole process, and the indicator greenhouse gas protocol (GGP) was selected to quantify CO2eq emissions. In this study also CO2 uptake of hemp was considered. Two different allocation procedures (i.e., mass and economic) were adopted. Other indicators, such as Cumulative Energy Demand (CED) and EcoIndicator99 H were calculated. The production of 1 ha yielded 15 ton of hemp, whose global warming potential (GWP100) was equal to about -26.01 ton CO2eq: the amount allocated to the technical fiber (20% of the total amount of hemp biomass) was -5.52 ton CO2eq when mass allocation was used, and -5.54 ton CO2eq when economic allocation was applied. The sustainability for building applications was quantified by considering an insulation panel made by hemp fiber (85%) and polyester fiber (15%) in 1 m(2) of wall having a thermal transmittance (U) equal to 0.2 W/m(2)_K. The environmental performances of the hemp-based panel were compared to those of a rockwool-based one.

  11. The effect of thermal cycling to 1100 degree C on the alpha (Mo) phase in directionally solidified gamma/gamma prime-alpha alloys

    Science.gov (United States)

    Harf, F. H.

    1981-01-01

    In gamma/gamma prime - alpha eutectic alloys (Ni-Mo-Al), the resistance of the alpha phase to morphological changes during thermal cycling was found to be dependent on the structure formed during directional solidification. Fine, smooth alpha fibers survived up to 1000 five minute cycles to 1100 C with minor microstructural contour changes, while coarser and irregularly shaped alpha fibers tended to spheroidize. A mechanism to explain this phenomenon is proposed. It is suggested that on heating to 1100 C, the alpha phase is likely to undergo morphological changes, until differential thermal expansion creates a stress free interface between the alpha phase and the gamma/gamma prime matrix.

  12. Impact of Total Ionizing Dose Radiation Testing and Long-Term Thermal Cycling on the Operation of CMF20120D Silicon Carbide Power MOSFET

    Science.gov (United States)

    Patterson, Richard L.; Scheidegger, Robert J.; Lauenstein, Jean-Marie; Casey, Megan; Scheick, Leif; Hammoud, Ahmad

    2013-01-01

    Power systems designed for use in NASA space missions are required to work reliably under harsh conditions including radiation, thermal cycling, and extreme temperature exposures. Silicon carbide devices show great promise for use in future power electronics systems, but information pertaining to performance of the devices in the space environment is very scarce. A silicon carbide N-channel enhancement-mode power MOSFET called the CMF20120 is of interest for use in space environments. Samples of the device were exposed to radiation followed by long-term thermal cycling to address their reliability for use in space applications. The results of the experimental work are presentd and discussed.

  13. Does thermal variability experienced at the egg stage influence life history traits across life cycle stages in a small invertebrate?

    Directory of Open Access Journals (Sweden)

    Kun Xing

    Full Text Available Although effects of thermal stability on eggs have often been considered in vertebrates, there is little data thermal stability in insect eggs even though these eggs are often exposed in nature to widely fluctuating ambient conditions. The modularity of development in invertebrates might lead to compensation across life cycle stages but this remains to be tested particularly within the context of realistic temperature fluctuations encountered in nature. We simulated natural temperate fluctuations on eggs of the worldwide cruciferous insect pest, the diamondback moth (DBM, Plutella xylostella (L., while maintaining the same mean temperature (25°C±0°C, 25±4°C, 25±6°C, 25±8°C, 25±10°C, 25±12°C and assessed egg development, survival and life history traits across developmental stages. Moderate fluctuations (25±4°C, 25±6°C did not influence performance compared to the constant temperature treatment, and none of the treatments influenced egg survival. However the wide fluctuating temperatures (25±10°C, 25±12°C slowed development time and led to an increase in pre-pupal mass, although these changes did not translate into any effects on longevity or fecundity at the adult stage. These findings indicate that environmental effects can extend across developmental stages despite the modularity of moth development but also highlight that there are few fitness consequences of the most variable thermal conditions likely to be experienced by Plutella xylostella.

  14. Model of the Evolution of Deformation Defects and Irreversible Strain at Thermal Cycling of Stressed TiNi Alloy Specimen

    Directory of Open Access Journals (Sweden)

    Volkov Aleksandr E.

    2015-01-01

    Full Text Available This microstructural model deals with simulation both of the reversible and irreversible deformation of a shape memory alloy (SMA. The martensitic transformation and the irreversible deformation due to the plastic accommodation of martensite are considered on the microscopic level. The irreversible deformation is described from the standpoint of the plastic flow theory. Isotropic hardening and kinematic hardening are taken into account and are related to the densities of scattered and oriented deformation defects. It is supposed that the phase transformation and the micro plastic deformation are caused by the generalized thermodynamic forces, which are the derivatives of the Gibbs’ potential of the two-phase body. In terms of these forces conditions for the phase transformation and for the micro plastic deformation on the micro level are formulated. The macro deformation of the representative volume of the polycrystal is calculated by averaging of the micro strains related to the evolution of the martensite Bain’s variants in each grain comprising this volume. The proposed model allowed simulating the evolution of the reversible and of the irreversible strains of a stressed SMA specimen under thermal cycles. The results show a good qualitative agreement with available experimental data. Specifically, it is shown that the model can describe a rather big irreversible strain in the first thermocycle and its fast decrease with the number of cycles.

  15. Thermal tests of a multi-tubular reactor for hydrogen production by using mixed ferrites thermochemical cycle

    Science.gov (United States)

    Gonzalez-Pardo, Aurelio; Denk, Thorsten; Vidal, Alfonso

    2017-06-01

    The SolH2 project is an INNPACTO initiative of the Spanish Ministry of Economy and Competitiveness, with the main goal to demonstrate the technological feasibility of solar thermochemical water splitting cycles as one of the most promising options to produce H2 from renewable sources in an emission-free way. A multi-tubular solar reactor was designed and build to evaluate a ferrite thermochemical cycle. At the end of this project, the ownership of this plant was transferred to CIEMAT. This paper reviews some additional tests with this pilot plant performed in the Plataforma Solar de Almería with the main goal to assess the thermal behavior of the reactor, evaluating the evolution of the temperatures inside the cavity and the relation between supplied power and reached temperatures. Previous experience with alumina tubes showed that they are very sensitive to temperature and flux gradients, what leads to elaborate an aiming strategy for the heliostat field to achieve a uniform distribution of the radiation inside the cavity. Additionally, the passing of clouds is a phenomenon that importantly affects all the CSP facilities by reducing their efficiency. The behavior of the reactor under these conditions has been studied.

  16. Thermal Capacitive Electrochemical Cycle on Carbon-Based Supercapacitor for Converting Low-grade Heat to Electricity

    Directory of Open Access Journals (Sweden)

    Xun Wang

    2017-11-01

    Full Text Available It is a great challenge to efficiently convert low-grade heat (<100°C to electricity. Currently available heat-to-current converters, such as thermoelectric generators, operating in a low-grade heat regime reach efficiencies no higher than a few percent (<3%. Herein, we illustrated a thermal capacitive electrochemical cycle (TCEC using electrochemical cell, where the connection to the hot or cold reservoirs alternates in a cyclic charging–heating–discharging–cooling mode to convert heat into electricity, which performs as an electrochemical heat engine. TCEC technology is a cost-effective method for exploiting the temperature-dependent electrostatic potential in an electric double layer (EDL at carbon electrode/electrolyte interfaces; it produces net electricity by altering the EDL thickness via heating and cooling. In this paper, TCEC on supercapacitor was confirmed on commercial supercapacitor, which showed a poor conversion efficiency. To improve the performance, we redesigned the cell by employing the pouch cell setup with activated carbon as electrode materials and homemade temperature controlling system, which boosted the efficiency from 0.5% of commercial supercapacitor to 3.05% when cycling between 10 and 65°C. A higher efficiency of 3.95% could be reached by using microwaved exfoliated graphene nanosheets (MEG and nitric acid-treated MEG, which could help in decreasing the energy loss caused by charge leakage.

  17. Effect of tooth brushing and thermal cycling on a surface change of ceromers finished with different methods.

    Science.gov (United States)

    Cho, L-R; Yi, Y-J; Heo, S-J

    2002-09-01

    This in vitro study evaluated the effect of tooth brushing and thermal cycling on the surface lustre and surface roughness of three ceromer systems treated with different surface finishing methods. The ceromers studied were: (1). Artglass, (2). Targis, (3). Sculpture and (4). the control group, Z 100. Half of the Targis and Sculpture groups were polished and the rest were coated with staining and glazing solution, respectively. All specimens were subjected to thermocycling 10000 times. Tooth brushing abrasion tests were performed in a customized tooth-brushing machine with 500 g weight applied on a back-and-forth cycle for 20000 repetitions. The lustre determined by measuring the light reflection area and the average roughness was compared between groups and between pre- and post-test values. All materials showed a lower lustre and rougher surface after thermocycling and tooth brushing (P ceromer specimens, except glazed Sculpture, showed a higher lustre and similar roughness to the control group. The post-brushing results revealed that glazed Sculpture presented discretely fallen out glaze coatings and had maximum change. However, stained Targis showed minimum change (P < 0.05) and polished Targis presented more changes than that of the staining treatment. It is therefore concluded that the glaze coatings for Sculpture don't exhibit long-term durability, while stain coatings for Targis acted like a protective layer.

  18. Viscous Dissipation and Thermal Radiation effects in MHD flow of Jeffrey Nanofluid through Impermeable Surface with Heat Generation/Absorption

    Science.gov (United States)

    Sharma, Kalpna; Gupta, Sumit

    2017-06-01

    This paper investigates steady two dimensional flow of an incompressible magnetohydrodynamic (MHD) boundary layer flow and heat transfer of nanofluid over an impermeable surface in presence of thermal radiation and viscous dissipation. By using similarity transformation, the arising governing equations of momentum, energy and nanoparticle concentration are transformed into coupled nonlinear ordinary differential equations, which are than solved by homotopy analysis method (HAM). The effect of different physical parameters, namely, Prandtl number Pr, Eckert number Ec, Magnetic parameter M, Brownian motion parameter Nb, Thermophoresis parameter Nt, Lewis parameter Le and Radiation parameter Rd on the velocity, temperature and concentration profiles along with the Nusselt number and skin friction coefficient are discussed graphically and in tabular form in details. The present results are also compared with existing limiting solutions.

  19. Life cycle monitoring of lithium-ion polymer batteries using cost-effective thermal infrared sensors with applications for lifetime prediction

    Science.gov (United States)

    Zhou, Xunfei; Malik, Anav; Hsieh, Sheng-Jen

    2017-05-01

    Lithium-ion batteries have become indispensable parts of our lives for their high-energy density and long lifespan. However, failure due to from abusive usage conditions, flawed manufacturing processes, and aging and adversely affect battery performance and even endanger people and property. Therefore, battery cells that are failing or reaching their end-of-life need to be replaced. Traditionally, battery lifetime prediction is achieved by analyzing data from current, voltage and impedance sensors. However, such a prognostic system is expensive to implement and requires direct contact. In this study, low-cost thermal infrared sensors were used to acquire thermographic images throughout the entire lifetime of small scale lithium-ion polymer batteries (410 cycles). The infrared system (non-destructive) took temperature readings from multiple batteries during charging and discharging cycles of 1C. Thermal characteristics of the batteries were derived from the thermographic images. A time-dependent and spatially resolved temperature mapping was obtained and quantitatively analyzed. The developed model can predict cycle number using the first 10 minutes of surface temperature data acquired through infrared imaging at the beginning of the cycle, with an average error rate of less than 10%. This approach can be used to correlate thermal characteristics of the batteries with life cycles, and to propose cost-effective thermal infrared imaging applications in battery prognostic systems.

  20. Four-wall turbine airfoil with thermal strain control for reduced cycle fatigue

    Science.gov (United States)

    Cambell, Christian X

    2013-09-17

    A turbine airfoil (20B) with a thermal expansion control mechanism that increases the airfoil camber (60, 61) under operational heating. The airfoil has four-wall geometry, including pressure side outer and inner walls (26, 28B), and suction side outer and inner walls (32, 34B). It has near-wall cooling channels (31F, 31A, 33F, 33A) between the outer and inner walls. A cooling fluid flow pattern (50C, 50W, 50H) in the airfoil causes the pressure side inner wall (28B) to increase in curvature under operational heating. The pressure side inner wall (28B) is thicker than walls (26, 34B) that oppose it in camber deformation, so it dominates them in collaboration with the suction side outer wall (32), and the airfoil camber increases. This reduces and relocates a maximum stress area (47) from the suction side outer wall (32) to the suction side inner wall (34B, 72) and the pressure side outer wall (26).

  1. Physical, thermal, structural and optical absorption studies of vanadyl doped magnesium oxy-chloride bismo-borate glasses

    Directory of Open Access Journals (Sweden)

    M.S. Dahiya

    2015-06-01

    Full Text Available Oxy-chloride bismuth-borate glasses with composition xMgCl2·(30 − xMgO·20Bi2O3·50B2O3 containing 2 mol% doping of V2O5 (x = 12, 15, 20, 25 and 30 are prepared by melt-quenching technique. The structural, thermal and optical behaviors are explained by analyzing the data obtained from density (D, molar volume (Vm, theoretical optical basicity (Λth, differential scanning calorimetry (DSC, FTIR and UV–vis results. A decrease in D and increase in Vm (except for sample MBV3 for which D is maximum on increasing chloride content suggests the formation of non-bridging oxygen atoms. Maximum glass transition temperature (Tg and crystallization temperature (Tx have been observed for sample MBV3. The glass stability (S and stability ratio (S/Tg have been calculated from the values of Tg and Tx and both are having maximum values for sample MBV3. Study of the FTIR spectra in the mid-IR range reveals the presence of both triangular and tetrahedral coordinated boron. The optical studies through UV–vis spectral analysis show non-sharp edge. The optical band gap (Eg is also maximum for sample MBV3.

  2. Flexural Properties of PVC/Bamboo Composites under Static and Dynamic-Thermal Conditions: Effects of Composition and Water Absorption

    Directory of Open Access Journals (Sweden)

    Shahril Anuar Bahari

    2017-01-01

    Full Text Available Polyvinyl chloride (PVC/bamboo composites have been prepared and assessed for their use in interior and exterior load-bearing applications. PVC composites were formed by compounding PVC with different bamboo particle sizes and loadings. The mechanical properties of these composites were determined at both ambient and elevated temperatures and after long-term water soaking. Analysis revealed that bamboo incorporation improved the PVC composite flexural modulus which was also observed with dynamic mechanical-thermal analysis on heating composites to ca. 70°C. Addition of 25% and 50% bamboo particles increases flexural modulus by 80% with dependency on whether fine (<75 μm or coarse (<1 mm particles were used. On water soaking to saturation, composites had water weight uptakes of 10%, with reduced flexural properties obtained for all water-soaked composites. Nonetheless, the results of this study show that PVC/bamboo composites achieve the minimum flexural performance of ASTM D 6662, indicating potential for their use in exterior applications.

  3. Loss Prediction and Thermal Analysis of Surface-Mounted Brushless AC PM Machines for Electric Vehicle Application Considering Driving Duty Cycle

    Directory of Open Access Journals (Sweden)

    Tianxun Chen

    2016-01-01

    Full Text Available This paper presents a computationally efficient loss prediction procedure and thermal analysis of surface-mounted brushless AC permanent magnet (PM machine considering the UDDS driving duty cycle by using a lumped parameters’ thermal model. The accurate prediction of loss and its variation with load are essential for thermal analysis. Employing finite element analysis (FEA to determine loss at every load point would be computationally intensive. Here, the finite element analysis and/or experiment based computationally efficient winding copper and iron loss and permanent magnet (PM power loss models are employed to calculate the electromagnetic loss at every operation point, respectively. Then, the lumped parameter thermal method is used to analyse the thermal behaviour of the driving PM machine. Experiments have been carried out to measure the temperature distribution in a motor prototype. The calculation and experiment results are compared and discussed.

  4. Fatigue failure kinetics and structural changes in lead-free interconnects due to mechanical and thermal cycling

    Science.gov (United States)

    Fiedler, Brent Alan

    Environmental and human health concerns drove European parliament to mandate the Reduction of Hazardous Substances (RoHS) for electronics. This was enacted in July 2006 and has practically eliminated lead in solder interconnects. There is concern in the electronics packaging community because modern lead-free solder is rich in tin. Presently, near-eutectic tin-silver-copper solders are favored by industry. These solders are stiffer than the lead-tin near-eutectic alloys, have a higher melting temperature, fewer slip systems, and form intermetallic compounds (IMC) with Cu, Ni and Ag, each of which tend to have a negative effect on lifetime. In order to design more reliable interconnects, the experimental observation of cracking mechanisms is necessary for the correct application of existing theories. The goal of this research is to observe the failure modes resulting from mode II strain and to determine the damage mechanisms which describe fatigue failures in 95.5 Sn- 4.0 Ag - 0.5 Cu wt% (SAC405) lead-free solder interconnects. In this work the initiation sites and crack paths were characterized for SAC405 ball-grid array (BGA) interconnects with electroless-nickel immersion-gold (ENIG) pad-finish. The interconnects were arranged in a perimeter array and tested in fully assembled packages. Evaluation methods included monotonic and displacement controlled mechanical shear fatigue tests, and temperature cycling. The specimens were characterized using metallogaphy, including optical and electron microscopy as well as energy dispersive spectroscopy (EDS) and precise real-time electrical resistance structural health monitoring (SHM). In mechanical shear fatigue tests, strain was applied by the substrates, simulating dissimilar coefficients of thermal expansion (CTE) between the board and chip-carrier. This type of strain caused cracks to initiate in the soft Sn-rich solder and grow near the interface between the solder and intermetallic compounds (IMC). The growth near

  5. The Role of Elastic and Plastic Anisotropy of Sn in Recrystallization and Damage Evolution During Thermal Cycling in SAC305 Solder Joints

    Science.gov (United States)

    Bieler, Thomas R.; Zhou, Bite; Blair, Lauren; Zamiri, Amir; Darbandi, Payam; Pourboghrat, Farhang; Lee, Tae-Kyu; Liu, Kuo-Chuan

    2012-02-01

    Because failures in lead-free solder joints occur at locations other than the most highly shear-strained regions, reliability prediction is challenging. To gain physical understanding of this phenomenon, physically based understanding of how elastic and plastic deformation anisotropy affect microstructural evolution during thermomechanical cycling is necessary. Upon solidification, SAC305 (Sn-3.0Ag-0.5Cu) solder joints are usually single or tricrystals. The evolution of microstructures and properties is characterized statistically using optical and orientation imaging microscopy. In situ synchrotron x-ray measurements during thermal cycling are used to examine how crystal orientation and thermal cycling history change strain history. Extensive characterization of a low-stress plastic ball grid array (PBGA) package design at different stages of cycling history is compared with preliminary experiments using higher-stress package designs. With time and thermal history, microstructural evolution occurs mostly from continuous recrystallization and particle coarsening that is unique to each joint, because of the specific interaction between local thermal and displacement boundary conditions and the strong anisotropic elastic, plastic, expansion, and diffusional properties of Sn crystals. The rate of development of recrystallized microstructures is a strong function of strain and aging. Cracks form at recrystallized (random) boundaries, and then percolate through recrystallized regions. Complications arising from electromigration and corrosion are also considered.

  6. The Role of Elastic and Plastic Anisotropy of Sn in Recrystallization and Damage Evolution During Thermal Cycling in SAC305 Solder Joints

    Energy Technology Data Exchange (ETDEWEB)

    Bieler, Thomas R.; Zhou, Bite; Blair, Lauren; Zamiri, Amir; Darbandi, Payam; Pourboghrat, Farhang; Lee, Tae-Kyu; Liu, Kuo-Chuan (Michigan); (Cisco)

    2013-04-08

    Because failures in lead-free solder joints occur at locations other than the most highly shear-strained regions, reliability prediction is challenging. To gain physical understanding of this phenomenon, physically based understanding of how elastic and plastic deformation anisotropy affect microstructural evolution during thermomechanical cycling is necessary. Upon solidification, SAC305 (Sn-3.0Ag-0.5Cu) solder joints are usually single or tricrystals. The evolution of microstructures and properties is characterized statistically using optical and orientation imaging microscopy. In situ synchrotron x-ray measurements during thermal cycling are used to examine how crystal orientation and thermal cycling history change strain history. Extensive characterization of a low-stress plastic ball grid array (PBGA) package design at different stages of cycling history is compared with preliminary experiments using higher-stress package designs. With time and thermal history, microstructural evolution occurs mostly from continuous recrystallization and particle coarsening that is unique to each joint, because of the specific interaction between local thermal and displacement boundary conditions and the strong anisotropic elastic, plastic, expansion, and diffusional properties of Sn crystals. The rate of development of recrystallized microstructures is a strong function of strain and aging. Cracks form at recrystallized (random) boundaries, and then percolate through recrystallized regions. Complications arising from electromigration and corrosion are also considered.

  7. Thermal cycling and electrochemical characteristics of solid oxide fuel cell supported on stainless steel with a new 3-phase composite anode

    Science.gov (United States)

    Dayaghi, Amir Masoud; Kim, Kun Joong; Kim, Sun Jae; Kim, Sunwoong; Bae, Hongyeul; Choi, Gyeong Man

    2017-06-01

    We report design, fabrication method, and fast thermal-cycling ability of solid oxide fuel cells (SOFCs) that use stainless steel (STS) as a support, and a new 3-phase anode. La and Ni co-doped SrTiO3 (La0.2Sr0.8Ti0.9Ni0.1O3-d, LSTN), replaces some of the Ni in conventional Ni-yttria stabilized zirconia (YSZ) anode; the resultant LSTN-YSZ-Ni 3-phase-composite anode is tested as a new reduction (or decomposition)-resistant anode of STS-supported SOFCs that can be co-fired with STS. A multi-layered cell with YSZ electrolyte (thickness ∼5 μm), composite anode, STS-cermet contact-layer, and STS support is designed, then fabricated by tape casting, lamination, and co-firing at 1250 °C in reducing atmosphere. The maximum power density (MPD) is 325 mW cm-2 at 650 °C; this is one of the highest among STS-supported cells fabricated by co-firing. The cell also shows stable open-circuit voltage and Ohmic resistance during 100 rapid thermal cycles between 170 and 600 °C. STS support minimizes stress and avoids cracking of electrolyte during rapid thermal cycling. The excellent MPD and stability during thermal cycles, and promising characteristics of SOFC as a power source for vehicle or mobile devices that requires rapid thermal cycles, are attributed to the new design of the cell with new anode structure.

  8. Recent trends in solar thermal sorption cooling system technology

    Directory of Open Access Journals (Sweden)

    Khaled M Bataineh

    2015-05-01

    Full Text Available Solar thermal cooling is the best alternative solution to overcome the problems associated with using nonrenewable resources. There are several thermal cooling methods developed differing from each other according to the thermodynamic cycle and type of refrigerant used. Recent developments in absorption and adsorption solar cooling systems are presented. Summarized thermodynamic modeling for both absorption and adsorption solar cooling systems is given. Brief thermal analysis among the types of solar collectors is presented. System efficiencies and optimization analysis are presented. The influences of geometrical, system configurations, and physical parameters on the performance of solar thermal sorption cooling system are investigated. The basis for the design of absorption and adsorption solar cooling systems is provided. Several case studies in different climatic conditions are presented. Economic feasibility for both systems is discussed. Comparison between the absorption and adsorption solar cooling system is summarized.

  9. Gram-scale synthesis, thermal stability, magnetic properties, and microwave absorption application of extremely small Co-C core-shell nanoparticles

    Science.gov (United States)

    Kuang, Daitao; Hou, Lizhen; Yu, Bowen; Liang, Bingbing; Deng, Lianwen; Huang, Han; Ma, Songshan; He, Jun; Wang, Shiliang

    2017-07-01

    Co-C core-shell nanoparticles have been synthesized in large quantity (in grams) by metal-organic chemical vapor deposition with analytical cobalt (III) acetylacetonate as precursor. Extremely small nanoparticles with an average core diameter of 3 nm and a shell thickness of 1-2 nm, and relatively large nanoparticles with an average core diameter of 23 nm and a shell thickness of 5-20 nm were obtained, depending on the deposition regions. The 3 nm Co nanocores are thermally stable up to 200 °C in air atmosphere, and do not exhibit visible structural and morphological changes after exposure to air at room temperature for 180 d. The extremely small core-shell nanoparticles exhibit typical superparamagnetic behaviors with a small coercivity of 5 Oe, while the relative large nanoparticles are a typical ferromagnetic material with a high coercivity of 584 Oe. In the microwave absorption tests, a low reflection loss (RL) of  -80.3 dB and large effective bandwidth (frequency range for \\text{RL}≤slant -10~ dB) of 10.1 GHz are obtained in the nanoparticle-paraffin composites with appropriate layer thicknesses and particle contents. This suggests that the as-synthesized Co-C core-shell nanoparticles have a high potential as the microwave-absorbing materials.

  10. Conceptual Design Study of a Closed Brayton Cycle Turbogenerator for Space Power Thermal-To-Electric Conversion System

    Science.gov (United States)

    Hansen, Jeff L.

    2000-01-01

    A conceptual design study was completed for a 360 kW Helium-Xenon closed Brayton cycle turbogenerator. The selected configuration is comprised of a single-shaft gas turbine engine coupled directly to a high-speed generator. The engine turbomachinery includes a 2.5:1 pressure ratio compression system with an inlet corrected flow of 0.44 kg/sec. The single centrifugal stage impeller discharges into a scroll via a vaned diffuser. The scroll routes the air into the cold side sector of the recuperator. The hot gas exits a nuclear reactor radiator at 1300 K and enters the turbine via a single-vaned scroll. The hot gases are expanded through the turbine and then diffused before entering the hot side sector of the recuperator. The single shaft design is supported by air bearings. The high efficiency shaft mounted permanent magnet generator produces an output of 370 kW at a speed of 60,000 rpm. The total weight of the turbogenerator is estimated to be only 123 kg (less than 5% of the total power plant) and has a volume of approximately 0.11 cubic meters. This turbogenerator is a key element in achieving the 40 to 45% overall power plant thermal efficiency.

  11. Surface phenomena associated with thermal cycling of copper and their impact on the service life of particle accelerator structures

    CERN Document Server

    Aicheler, Markus; Theisen, Werner; Sgobba, Stefano

    2010-01-01

    The performance of accelerating structures (AS) in the Compact LInear Collider (CLIC) is sensitive to a variety of parameters, including the surface quality of key elements of the AS. Processes which affect the surface quality are therefore of particular concern. The present work addresses surface modifications associated with thermal cycling during operation. This type of operating condition represents a specific type of fatigue loading. Four fatigue test procedures were used in the present study in order to investigate the fatigue behaviour of oxygen{free{electronic (OFE) copper, the candidate material of the CLIC-AS: conventional fatigue (CVF), ultrasonic swinger (USS), laser fatigue (LAF) and radio{frequency fatigue (RFF). During operation of the accelerator the material of the AS will be subjected to cyclic temperature changes of approx. Delta T = 56 K, from about 40° C to about 100° C. These temperature changes will result in cyclic biaxial strains in the surface of the order of epsilon(biax) = 9.2 x ...

  12. Environmental Life-Cycle Analysis of Hybrid Solar Photovoltaic/Thermal Systems for Use in Hong Kong

    Directory of Open Access Journals (Sweden)

    Tin-Tai Chow

    2012-01-01

    Full Text Available While sheet-and-tube absorber is generally recommended for flat-plate photovoltaic/thermal (PV/T collector design because of the simplicity and promising performance, the use of rectangular-channel absorber is also tested to be a good alternative. Before a new energy technology, like PV/T, is fully implemented, its environmental superiority over the competing options should be assessed, for instance, by evaluating its consumption levels throughout its production and service life. Although there have been a plenty of environmental life-cycle assessments on the domestic solar hot water systems and PV systems, the related works on hybrid solar PV/T systems have been very few. So far there is no reported work on the assessment of PV/T collector with channel-type absorber design. This paper reports an evaluation of the energy payback time and the greenhouse gas payback time of free-standing and building-integrated PV/T systems in Hong Kong. This is based on two case studies of PV/T collectors with modular channel-type aluminium absorbers. The results confirm the long-term environmental benefits of PV/T applications.

  13. The Philosophy which underlies the structural tests of a supersonic transport aircraft with particular attention to the thermal cycle

    Science.gov (United States)

    Ripley, E. L.

    1972-01-01

    The information presented is based on data obtained from the Concorde. Much of this data also applies to other supersonic transport aircraft. The design and development of the Concorde is a joint effort of the British and French, and the structural test program is shared, as are all the other activities. Vast numbers of small specimens have been tested to determine the behavior of the materials used in the aircraft. Major components of the aircraft structure, totalling almost a complete aircraft, have been made and are being tested to help the constructors in each country in the design and development of the structure. Tests on two complete airframes will give information for the certification of the aircraft. A static test was conducted in France and a fatigue test in the United Kingdom. Fail-safe tests are being made to demonstrate the crack-propagation characteristics of the structure and its residual strength. Aspects of the structural test program are described in some detail, dealing particularly with the problems associated with the thermal cycle. The biggest of these problems is the setting up of the fatigue test on the complete airframe; therefore, this is covered more extensively with a discussion about how the test time can be shortened and with a description of the practical aspects of the test.

  14. Results of scoping tests for open-cycle OTEC (ocean thermal energy conversion) components operating with seawater

    Energy Technology Data Exchange (ETDEWEB)

    Zangrando, F; Bharathan, D; Green, H J; Link, H F; Parsons, B K; Parsons, J M; Pesaran, A A [Solar Energy Research Inst., Golden, CO (USA); Panchal, C B [Argonne National Lab., IL (USA)

    1990-09-01

    This report presents comprehensive documentation of the experimental research conducted on open-cycle ocean thermal energy conversion (OC-OTEC) components operating with seawater as a working fluid. The results of this research are presented in the context of previous analysis and fresh-water testing; they provide a basis for understanding and predicting with confidence the performance of all components of an OC-OTEC system except the turbine. Seawater tests have confirmed the results that were obtained in fresh-water tests and predicted by the analytical models of the components. A sound technical basis has been established for the design of larger systems in which net power will be produced for the first time from OC-OTEC technology. Design and operation of a complete OC-OTEC system that produces power will provide sufficient confidence to warrant complete transfer of OC-OTEC technology to the private sector. Each components performance is described in a separate chapter written by the principal investigator responsible for technical aspects of the specific tests. Chapters have been indexed separately for inclusion on the data base.

  15. A Technique for Mitigating Thermal Stress and Extending Life Cycle of Power Electronic Converters Used for Wind Turbines

    Directory of Open Access Journals (Sweden)

    Canras Batunlu

    2015-11-01

    Full Text Available Over the last two decades, various models have been developed to assess and improve the reliability of power electronic conversion systems (PECs with a focus on those used for wind turbines. However, only few studies have dealt with mitigating the PECs thermo-mechanical effects on their reliability taking into account variations in wind characteristics. This work critically investigates this issue and attempts to offer a mitigating technique by, first, developing realistic full scale (FS and partial scale (PS induction generator models combined with two level back-to-back PECs. Subsequently, deriving a driving algorithm, which reduces PEC’s operating temperature by controlling its switching patterns. The developed switching procedure ensures minimum temperature fluctuations by adapting the variable DC link and system’s frequency of operation. It was found for both FS and PS topologies, that the generator side converters have higher mean junction temperatures where the grid side ones have more fluctuations on their thermal profile. The FS and PS cycling temperatures were reduced by 12 °C and 5 °C, respectively. Moreover, this led to a significant improvement in stress; approximately 27 MPa stress reduction for the FS induction generator PEC.

  16. Finite time thermodynamics of power and refrigeration cycles

    CERN Document Server

    Kaushik, Shubhash C; Kumar, Pramod

    2017-01-01

    This book addresses the concept and applications of Finite Time Thermodynamics to various thermal energy conversion systems including heat engines, heat pumps, and refrigeration and air-conditioning systems. The book is the first of its kind, presenting detailed analytical formulations for the design and optimisation of various power producing and cooling cycles including but not limited to: • Vapour power cycles • Gas power cycles • Vapour compression cycles • Vapour absorption cycles • Rankine cycle coupled refrigeration systems Further, the book addresses the thermoeconomic analysis for the optimisation of thermal cycles, an important field of study in the present age and which is characterised by multi-objective optimization regarding energy, ecology, the environment and economics. Lastly, the book provides the readers with key techniques associated with Finite Time Thermodynamics, allowing them to understand the relevance of irreversibilitie s associated with real processes and the scientific r...

  17. Effect of airborne-particle abrasion and mechanico-thermal cycling on the flexural strength of glass ceramic fused to gold or cobalt-chromium alloy.

    Science.gov (United States)

    Oliveira de Vasconcellos, Luis Gustavo; Silva, Lucas H; Reis de Vasconcellos, Luana Marotta; Balducci, Ivan; Takahashi, Fernando E; Bottino, Marco Antonio

    2011-10-01

    To evaluate the effect of airborne-particle abrasion and mechanico-thermal cycling on the flexural strength of a ceramic fused to cobalt-chromium alloy or gold alloy. Metallic bars (n = 120) were made (25 mm × 3 mm × 0.5 mm): 60 with gold alloy and 60 with Co-Cr. At the central area of the bars (8 mm × 3 mm), a layer of opaque ceramic and then two layers of glass ceramic (Vita VM13, Vita Zahnfabrick) were fired onto it (thickness: 1 mm). Ten specimens from each alloy group were randomly allocated to a surface treatment [(tungsten bur or air-particle abrasion (APA) with Al(2) O(3) at 10 mm or 20 mm away)] and mechanico-thermal cycling (no cycling or mechanically loaded 20,000 cycles; 10 N distilled water at 37°C and then thermocycled 3000 cycles; 5°C to 55°C, dwell time 30 seconds) combination. Those specimens that did not undergo mechanico-thermal cycling were stored in water (37°C) for 24 hours. Bond strength was measured using a three-point bend test, according to ISO 9693. After the flexural strength test, failure types were noted. The data were analyzed using three factor-ANOVA and Tukey's test (α= 0.05). There were no significant differences between the flexural bond strength of gold and Co-Cr groups (42.64 ± 8.25 and 43.39 ± 10.89 MPa, respectively). APA 10 and 20 mm away surface treatment (45.86 ± 9.31 and 46.38 ± 8.89 MPa, respectively) had similar mean flexural strength values, and both had significantly higher bond strength than tungsten bur treatment (36.81 ± 7.60 MPa). Mechanico-thermal cycling decreased the mean flexural strength values significantly for all six alloy-surface treatment combinations tested when compared to the control groups. The failure type was adhesive in the metal/ceramic interface for specimens surface treated only with the tungsten bur, and mixed for specimens surface treated with APA 10 and 20 mm. Considering the levels adopted in this study, the alloy did not affect the bond strength; APA with Al(2) O(3) at 10 and

  18. Method validation for control determination of mercury in fresh fish and shrimp samples by solid sampling thermal decomposition/amalgamation atomic absorption spectrometry.

    Science.gov (United States)

    Torres, Daiane Placido; Martins-Teixeira, Maristela Braga; Cadore, Solange; Queiroz, Helena Müller

    2015-01-01

    A method for the determination of total mercury in fresh fish and shrimp samples by solid sampling thermal decomposition/amalgamation atomic absorption spectrometry (TDA AAS) has been validated following international foodstuff protocols in order to fulfill the Brazilian National Residue Control Plan. The experimental parameters have been previously studied and optimized according to specific legislation on validation and inorganic contaminants in foodstuff. Linearity, sensitivity, specificity, detection and quantification limits, precision (repeatability and within-laboratory reproducibility), robustness as well as accuracy of the method have been evaluated. Linearity of response was satisfactory for the two range concentrations available on the TDA AAS equipment, between approximately 25.0 and 200.0 μg kg(-1) (square regression) and 250.0 and 2000.0 μg kg(-1) (linear regression) of mercury. The residues for both ranges were homoscedastic and independent, with normal distribution. Correlation coefficients obtained for these ranges were higher than 0.995. Limits of quantification (LOQ) and of detection of the method (LDM), based on signal standard deviation (SD) for a low-in-mercury sample, were 3.0 and 1.0 μg kg(-1), respectively. Repeatability of the method was better than 4%. Within-laboratory reproducibility achieved a relative SD better than 6%. Robustness of the current method was evaluated and pointed sample mass as a significant factor. Accuracy (assessed as the analyte recovery) was calculated on basis of the repeatability, and ranged from 89% to 99%. The obtained results showed the suitability of the present method for direct mercury measurement in fresh fish and shrimp samples and the importance of monitoring the analysis conditions for food control purposes. Additionally, the competence of this method was recognized by accreditation under the standard ISO/IEC 17025.

  19. Life Cycle Assessment of Thermal Treatment Technologies. An environmental and financial systems analysis of gasification, incineration and landfilling of waste

    Energy Technology Data Exchange (ETDEWEB)

    Assefa, Getachew; Eriksson, Ola [Royal Inst. of Tech., Stockholm (Sweden). Industrial Ecology; Jaeraas, Sven; Kusar, Henrik [Royal Inst. of Tech., Stockholm (Sweden). Chemical Technology

    2003-05-01

    A technology which is currently developed by researchers at KTH is catalytic combustion. which is one component of a gasification system. Instead of performing the combustion in the gas turbine by a flame, a catalyst is used. When the development of a new technology (as catalytic combustion) reaches a certain step where it is possible to quantify material-, energy- and capital flows, the prerequisites for performing a systems analysis is at hand. The systems analysis can be used to expand the know-how about the potential advantages of the catalytic combustion technology by highlighting its function as a component of a larger system. In this way it may be possible to point out weak points which have to be investigated more, but also strong points to emphasise the importance of further development. The aim of this project was to assess the energy turnover as well as the potential environmental impacts and economic costs of thermal treatment technologies in general and catalytic combustion in particular. By using a holistic assessment of the advantages and disadvantages of catalytic combustion of waste it was possible to identify the strengths and weaknesses of the technology under different conditions. Following different treatment scenarios have been studied: (1) Gasification with catalytic combustion, (2) Gasification with flame combustion, (3) Incineration with energy recovery and (4) Landfilling with gas collection. In the study compensatory district heating is produced by combustion. of biofuel. The power used for running the processes in the scenarios is supplied by the waste-to-energy technologies themselves while compensatory power is assumed to be produced. from natural gas. The emissions from the system studied were classified and characterised using methodology from Life Cycle Assessment into the following environmental impact categories: Global Warming Potential, Acidification Potential, Eutrophication Potential and finally Formation of Photochemical

  20. A temperature control method for shortening thermal cycling time to achieve rapid polymerase chain reaction (PCR) in a disposable polymer microfluidic device

    DEFF Research Database (Denmark)

    Bu, Minqiang; Perch-Nielsen, Ivan R.; Sørensen, Karen Skotte

    2013-01-01

    We present a temperature control method capable of effectively shortening the thermal cycling time of polymerase chain reaction (PCR) in a disposable polymer microfluidic device with an external heater and a temperature sensor. The method employs optimized temperature overshooting and undershooting...... steps to achieve a rapid ramping between the temperature steps for DNA denaturation, annealing and extension. The temperature dynamics within the microfluidic PCR chamber was characterized and the overshooting and undershooting parameters were optimized using the temperature-dependent fluorescence...

  1. A novel temperature control method for shortening thermal cycling time to achieve rapid polymerase chain reaction (PCR) in a disposable polymer microfluidic device

    DEFF Research Database (Denmark)

    Bu, Minqiang; R. Perch-Nielsen, Ivan; Sørensen, Karen Skotte

    We present a new temperature control method capable of effectively shortening the thermal cycling time of polymerase chain reaction (PCR) in a disposable polymer microfluidic device with external heater and temperature sensor. The method employs optimized temperature overshooting and undershooting...... steps to achieve a rapid ramping between the temperature steps for DNA denaturation, annealing and extension. The temperature dynamics within the microfluidic PCR chamber was characterized and the overshooting and undershooting parameters were optimized using the temperature dependent fluorescence...

  2. A study about the contribution of the α-β phase transition of quartz to thermal cycle damage of a refractory used in fluidized catalytic cracking units

    Directory of Open Access Journals (Sweden)

    A. H. A. Pereira

    2014-09-01

    Full Text Available The deterioration of refractories used in fluidized catalytic cracking units (FCC-units is responsible for high costs of maintenance for the petrochemical industry. This is commonly associated with coke deposition during the production of light hydrocarbons. However, other mechanisms responsible for causing damage may also occur, such as the generation of cracks by expansive phase transition. The aim of the work herein was to study the contribution of the a-b phase transition of quartz particles to the deterioration of a commercial aluminosilicate refractory used in a riser by the means of slow thermal cycles. Such damage may occur if the working temperature of the equipment fluctuates around the a-b transition temperature (573 °C. The current study considered the material with and without coke impregnation to evaluate the combined effect of coke presence and phase transition. To evaluate the damage, it was used the Young's modulus as a function of temperature by applying the Impulse Excitation Technique under controlled atmosphere. An equipment recently developed by the authors research group was applied. Specimens were prepared and submitted to slow thermal cycles of temperatures up to 500 °C and up to 700 °C, with a heating rate of 2 °C/min. Part of the specimens was previously impregnated with coke by a reactor using propen. To complete the evaluation, characterization by X-ray diffraction, as well as by dilatometry and scanning electron microscopy were performed. The findings of this study showed that the presence of quartz particles determine the thermo-mechanical behaviour of the material, as well as the thermocycling damage resistance. In spite of the fact that the a-b phase transition stiffens the material during the heating stage, it increases the damage by slow thermal cycling. The coke impregnation increases the resistance to slow thermal cycles, however it decreases the resistance to the damage evolution.

  3. Phosphorus cycle in Germiston Lake. II. The in vitro and in situ absorption of /sup 32/P by Potamogeton pectinatus L

    Energy Technology Data Exchange (ETDEWEB)

    Vermaak, J.F.; Swanepoel, J.H.; Schoonbee, H.J. (Rand Afrikaans Univ., Johannesburg (South Africa))

    1982-01-01

    The in vitro absorption of /sup 32/P by the organs of intact and dissected plants of the submerged freshwater macrophyte, Potamogeton pectinatus L, was investigated. /sup 32/P was absorbed by the roots, stems and leaves of intact and dissected plants under both light and dark conditions, and at both low and high phosphate concentrations. Absorption, translocation, and release of /sup 32/P by this species were also investigated using compartmentalized containers separating foliage and roots. It was found that a higher P-concentration in the root compartment (simulating natural conditions) influences absorption, translocation and release of /sup 32/P. An in situ study in Germiston Lake using /sup 32/P confirmed that the roots of P. pectinatus can absorb phosphorus from the sediment followed by its translocation to the foliage.

  4. High temperature, low cycle fatigue of copper-base alloys in argon. Part 3: Zirconium-copper; thermal-mechanical strain cycling, hold-time and notch fatigue results

    Science.gov (United States)

    Conway, J. B.; Stentz, R. H.; Berling, J. T.

    1973-01-01

    The low-cycle fatigue characteristics of smooth bar and notched bar specimens (hourglass shape) of zirconium-copper, 1/2 Hard, material (R-2 Series) were evaluated at room temperature in axial strain control. Over the fatigue life range from about 300 to 3000 cycles the ratio of fatigue life for smooth bar to fatigue life for notched bar remained constant at a value of about 6.0. Some additional hold-time data for the R-2 alloy tested in argon at 538 C are reported. An analysis of the relaxation data obtained in these hold-time tests is also reported and it is shown that these data yield a fairly consistent correlation in terms of instantaneous stress rate divided by instantaneous stress. Two thermal-mechanical strain cycling tests were also performed using a cyclic frequency of 4.5 cycles per hour and a temperature cycling interval from 260 to 538 C. The fatigue life values in these tests were noticeably lower than that observed in isothermal tests at 538 C.

  5. Thermal analysis of injection beam dump of high-intensity rapid-cycling synchrotron in J-PARC

    Science.gov (United States)

    Kamiya, J.; Saha, P. K.; Yamamoto, K.; Kinsho, M.; Nihei, T.

    2017-10-01

    The beam dump at the beam injection area in the J-PARC 3-GeV rapid cycling synchrotron (RCS) accepts beams that pass through the charge exchange foil without ideal electron stripping during the multi-turn beam injection. The injection beam dump consists of the beam pipe, beam stopper, radiation shield, and cooling mechanism. The ideal beam power into the injection beam dump is 400 W in the case of design RCS extraction beam power of 1 MW with a healthy foil, which has 99.7 % charge stripping efficiency. On the other hand, as a radiation generator, the RCS is permitted to be operated with maximum average beam power of 4 kW into the injection beam dump based on the radiation shielding calculation, in consideration of lower charge stripping efficiency due to the foil deterioration. In this research, to evaluate the health of the RCS injection beam dump system from the perspective of the heat generation, a thermal analysis was performed based on the actual configuration with sufficiently large region, including the surrounding concrete and soil. The calculated temperature and heat flux density distribution showed the validity of the mesh spacing and model range. The calculation result showed that the dumped 4 kW beam causes the temperature to increase up to 330, 400, and 140 °C at the beam pipe, beam stopper, and radiation shield, respectively. Although these high temperatures induce stress in the constituent materials, the calculated stress values were lower than the ultimate tensile strength of each material. Transient temperature analysis of the beam stopper, which simulated the sudden break of the charge stripper foil, demonstrated that one bunched beam pulse with the maximum beam power does not lead to a serious rise in the temperature of the beam stopper. Furthermore, from the measured outgassing rate of stainless steel at high temperature, the rise in beam line pressure due to additive outgassing from the heated beam pipe was estimated to have a negligible

  6. Suppression of thermal carrier escape and efficient photo-carrier generation by two-step photon absorption in InAs quantum dot intermediate-band solar cells using a dot-in-well structure

    Energy Technology Data Exchange (ETDEWEB)

    Asahi, S.; Teranishi, H.; Kasamatsu, N.; Kada, T.; Kaizu, T.; Kita, T. [Department of Electrical and Electronic Engineering, Graduate School of Engineering, Kobe University, 1-1 Rokkodai, Nada, Kobe 657-8501 (Japan)

    2014-08-14

    We investigated the effects of an increase in the barrier height on the enhancement of the efficiency of two-step photo-excitation in InAs quantum dot (QD) solar cells with a dot-in-well structure. Thermal carrier escape of electrons pumped in QD states was drastically reduced by sandwiching InAs/GaAs QDs with a high potential barrier of Al{sub 0.3}Ga{sub 0.7}As. The thermal activation energy increased with the introduction of the barrier. The high potential barrier caused suppression of thermal carrier escape and helped realize a high electron density in the QD states. We observed efficient two-step photon absorption as a result of the high occupancy of the QD states at room temperature.

  7. Emissions from cycling of thermal power plants in electricity systems with high penetration of wind power: Life cycle assessment for Ireland

    DEFF Research Database (Denmark)

    Turconi, Roberto; O'Dwyer, C.; Flynn, D.

    2014-01-01

    demand. The environmental impacts related to potential future energy systems in Ireland for 2025 with high shares of wind power were evaluated using life cycle assessment (LCA), focusing on cycling emissions (due to part-load operation and start-ups) from dispatchable generators. Part-load operations......-load electricity production shifts to a cleaner source than coal. Finally, the present study indicates that, in terms of emission reductions, the priority for Ireland is to phase out coal-based power plants. While investing in new storage capacity reduces system operating costs at high wind penetrations and limits...... significantly affect the average power plant efficiency, with all units seeing an average yearly efficiency noticeably less than optimal. In particular, load following units, on average, saw an 11% reduction. Given that production technologies are typically modeled assuming steady-state operation at full load...

  8. Thermal cycling of directly buried district heating networks - application of cumulative damage theory to some field cases

    Energy Technology Data Exchange (ETDEWEB)

    Penderos, M.

    1996-11-01

    The expected life of directly buried DH pipes is significantly influenced by temperature variations in the transported hot water. The temperature variations can lead to low cycle fatigue in the media pipe or in other parts of the pipe structure. This thesis deals with methods to study and quantify temperature variations, and with implications for the medium pipe due to temperature variations. Temperature and temperature variations are of great importance for accumulated damage. If a material is subjected to temperature variations this could lead to low cycle fatigue in the material. The rainflow method is used to calculate the equivalent number of cycles. The results from the rainflow cycle count show that at the consumer installations the largest number of equivalent cycles is on the return pipe while at the production plant the largest number of equivalent cycles is on the supply side. The conclusion of this thesis is that if there is 100 cycles, or more, there is no risk of low cycle fatigue, due to temperature variations, at the measuring points. Temperature variations that are extended in time are the ones that causes stresses to build up in the pipe. Four important factors affect the expected life of the pipes: temperature variations, extension in time of the temperature variations, the length of the pipe, and the water velocity. 25 refs, 27 figs, 2 tabs

  9. Organic Contaminants and Treatment Chemicals in Steam-Water Cycles : Thermal stability, decomposition products and flow-accelerated corrosion

    NARCIS (Netherlands)

    Moed, D.H.

    2015-01-01

    Boiler feedwater and steam have to be of high purity, because of the susceptibility of the steam-water cycle to corrosion. Organic contaminants break down in boilers by hydrothermolysis, leading to the formation of organic acid anions, which are suspected to cause corrosion of steam-water cycle

  10. Seasonal Redistribution of Immune Function in a Migrant Shorebird : Annual-Cycle Effects Override Adjustments to Thermal Regime

    NARCIS (Netherlands)

    Buehler, Deborah M.; Piersma, Theunis; Matson, Kevin D.; Tieleman, B. Irene; Demas, Greg (associate); Geber, Monica A.

    2008-01-01

    Throughout the annual cycle, demands on competing physiological systems change, and animals must allocate resources to maximize fitness. Immune function is one such system and is important for survival. Yet detailed empirical data tracking immune function over the entire annual cycle are lacking for

  11. The High Performance Shape Memory Effect (HP-SME in Ni Rich NiTi Wires: In Situ X-Ray Diffraction on Thermal Cycling

    Directory of Open Access Journals (Sweden)

    Coduri Mauro

    2015-01-01

    Full Text Available A novel approach for using Shape Memory Alloys (SMA was recently proposed and named highperformance shape memory effect (HP-SME. The HP-SME exploits the thermal cycling of stress-induced martensite for producing extremely high mechanical work with a very stable functional fatigue behaviour in Ni rich NiTi alloy. The latter was found to differ significantly from the functional fatigue behaviour observed for conventional SMA. This study was undertaken in order to elucidate the microstructural modifications at the basis of this particular feature. To this purpose, the functional fatigue was coupled to in situ Synchrotron Radiation X-Ray Diffraction, by recording patterns on wires thermally cycled by Joule effect under a constant applied stress (800 MPa. The accurate analysis the line profile XRD data suggests the accumulation of defects upon functional cycling, while the fibre texture was not observed to change. The functional fatigue exhibits a very similar behaviour as the line broadening of XRD peaks, thus suggesting the accumulation of dislocations as the origin of the mechanism of the permanent deformation.

  12. A Finite-Time Thermal Cycle Variational Optimization with a Stefan–Boltzmann Law for Three Different Criteria

    Directory of Open Access Journals (Sweden)

    Juan C. Chimal-Eguía

    2012-12-01

    Full Text Available This work shows the power of the variational approach for studying the efficiency of thermal engines in the context of the Finite Time Thermodynamics (FTT. Using an endoreversible Curzon–Ahlborn (CA heat engine as a model for actual thermal engines, three different criteria for thermal efficiency were analyzed: maximum power output, ecological function, and maximum power density. By means of this procedure, the performance of the CA heat engine with a nonlinear heat transfer law (the Stefan–Boltzmann law was studied to describe the heat exchanges between the working substance and its thermal reservoirs. The specific case of the Müser engine for all the criteria was analyzed. The results confirmed some previous findings using other procedures and additionally new results for the Müser engine performance were obtained.

  13. Conversion of coal-fired power plants to cogeneration and combined-cycle thermal and economic effectiveness

    CERN Document Server

    Bartnik, Ryszard

    2014-01-01

    This book covers methodology, calculation procedures and tools to support enterprise planning for adapting power stations to cogeneration and combined-cycle forms. It examines the optimum selection of the structure of heat exchangers in a 370 MW power block.

  14. Re-examination of the cause of the Paleocene-Eocene thermal maximum, based on global carbon-cycle modeling

    National Research Council Canada - National Science Library

    Yasukawa, Kazutaka; Nakamura, Kentaro; Kato, Yasuhiro

    2010-01-01

    .... To provide some constraints on the cause of the PETM, we re-examined the observed magnitude of the CIE, and then reconstructed the perturbation of the global carbon cycle during the PETM, using...

  15. The Effect of a Non-Gaussian Random Loading on High-Cycle Fatigue of a Thermally Post-Buckled Structure

    Science.gov (United States)

    Rizzi, Stephen A.; Behnke, marlana N.; Przekop, Adam

    2010-01-01

    High-cycle fatigue of an elastic-plastic beam structure under the combined action of thermal and high-intensity non-Gaussian acoustic loadings is considered. Such loadings can be highly damaging when snap-through motion occurs between thermally post-buckled equilibria. The simulated non-Gaussian loadings investigated have a range of skewness and kurtosis typical of turbulent boundary layer pressure fluctuations in the vicinity of forward facing steps. Further, the duration and steadiness of high excursion peaks is comparable to that found in such turbulent boundary layer data. Response and fatigue life estimates are found to be insensitive to the loading distribution, with the minor exception of cases involving plastic deformation. In contrast, the fatigue life estimate was found to be highly affected by a different type of non-Gaussian loading having bursts of high excursion peaks.

  16. The University of Minnesota aquifer thermal energy storage (ATES) field test facility -- system description, aquifer characterization, and results of short-term test cycles

    Energy Technology Data Exchange (ETDEWEB)

    Walton, M.; Hoyer, M.C.; Eisenreich, S.J.; Holm, N.L.; Holm, T.R.; Kanivetsky, R.; Jirsa, M.A.; Lee, H.C.; Lauer, J.L.; Miller, R.T.; Norton, J.L.; Runke, H. (Minnesota Geological Survey, St. Paul, MN (United States))

    1991-06-01

    Phase 1 of the Aquifer Thermal Energy Storage (ATES) Project at the University of Minnesota was to test the feasibility, and model, the ATES concept at temperatures above 100{degrees}C using a confined aquifer for the storage and recovery of hot water. Phase 1 included design, construction, and operation of a 5-MW thermal input/output field test facility (FTF) for four short-term ATES cycles (8 days each of heat injection, storage, and heat recover). Phase 1 was conducted from May 1980 to December 1983. This report describes the FTF, the Franconia-Ironton-Galesville (FIG) aquifer used for the test, and the four short-term ATES cycles. Heat recovery; operational experience; and thermal, chemical, hydrologic, and geologic effects are all included. The FTF consists of monitoring wells and the source and storage well doublet completed in the FIG aquifer with heat exchangers and a fixed-bed precipitator between the wells of the doublet. The FIG aquifer is highly layered and a really anisotropic. The upper Franconia and Ironton-Galesville parts of the aquifer, those parts screened, have hydraulic conductivities of {approximately}0.6 and {approximately}1.0 m/d, respectively. Primary ions in the ambient ground water are calcium and magnesium bicarbonate. Ambient temperature FIG ground water is saturated with respect to calcium/magnesium bicarbonate. Heating the ground water caused most of the dissolved calcium to precipitate out as calcium carbonate in the heat exchanger and precipitator. Silica, calcium, and magnesium were significantly higher in recovered water than in injected water, suggesting dissolution of some constituents of the aquifer during the cycles. Further work on the ground water chemistry is required to understand water-rock interactions.

  17. Thermal analysis of the heat recuperator of a combined cycle thermoelectric central; Analisis termico del recuperador de calor de una central termoelectrica de ciclo combinado

    Energy Technology Data Exchange (ETDEWEB)

    Romero Paredes, Hernando; Sanchez, I.; Lazcano, L. C.; Ambriz, Juan Jose; Alvarez, M. [Universidad Autonoma Metropolitana-Iztapalapa, Mexico, D. F. (Mexico); Gonzalez, O. [Comision Federal de Electricidad, Tula (Mexico)

    1996-12-31

    The thermoelectric centrals of the combined cycle type (Brayton Cycle and Rankine Cycle) present a series of opportunities to increase the efficiency of the combined cycle or of the generated power. This paper shows the methodology for the performance of energy balances in a heat recuperator (H. R.), typically employed in the combined cycle stations operating in Mexico, for the assessment of the energy harnessing in the different sections conforming a H. R. The effect of the installation of evaporative coolers and/or an absorption cooling system at the gas turbine compressor intake on the steam generation in the heat recuperator, is evaluated. This extra generation of steam is quantified for its potential use in the same absorption refrigeration system. From the assessment, it follows up that the steam generation in the H.R. is inversely proportional to the ambient temperature and that, although the increased amount of steam generated can not be harnessed in total by the steam turbine, the remaining fraction is good enough to cover the heat demand for the operation of the refrigeration system. [Espanol] Las centrales termoelectricas del tipo ciclo combinado (ciclo Brayton y ciclo Rankine) presentan un conjunto de oportunidades para incrementar la eficiencia del ciclo combinado o bien la potencia generada. En el presente trabajo se expone la metodologia para realizar los balances de energia en un recuperador de calor (R.C.) tipicamente utilizado en las Centrales de Ciclo Combinado (CCC) que operan en Mexico, para evaluar el aprovechamiento de la energia en las diferentes secciones que conforman un R.C. Se evalua el efecto que tiene la instalacion de enfriadores evaporativos y/o un sistema de enfriamiento por absorcion en la succion del compresor de la turbina de gas sobre la generacion de vapor en el recuperador de calor. Se cuantifica esta generacion extra de vapor para su posible utilizacion en el mismo sistema de refrigeracion por absorcion. De la evaluacion se

  18. Absorption heat pump system

    Science.gov (United States)

    Grossman, Gershon; Perez-Blanco, Horacio

    1984-01-01

    An improvement in an absorption heat pump cycle is obtained by adding adiabatic absorption and desorption steps to the absorber and desorber of the system. The adiabatic processes make it possible to obtain the highest temperature in the absorber before any heat is removed from it and the lowest temperature in the desorber before heat is added to it, allowing for efficient utilization of the thermodynamic availability of the heat supply stream. The improved system can operate with a larger difference between high and low working fluid concentrations, less circulation losses, and more efficient heat exchange than a conventional system.

  19. Effects of thermal radiation and magnetic field on unsteady mixed convection flow and heat transfer over an exponentially stretching surface with suction in the presence of internal heat generation/absorption

    Directory of Open Access Journals (Sweden)

    Elsayed M.A. Elbashbeshy

    2012-10-01

    Full Text Available In this paper, the problem of unsteady laminar two-dimensional boundary layer flow and heat transfer of an incompressible viscous fluid in the presence of thermal radiation, internal heat generation or absorption, and magnetic field over an exponentially stretching surface subjected to suction with an exponential temperature distribution is discussed numerically. The governing boundary layer equations are reduced to a system of ordinary differential equations. New numerical method using Mathematica has been used to solve such system after obtaining the missed initial conditions. Comparison of obtained numerical results is made with previously published results in some special cases, and found to be in a good agreement.

  20. Absorption of water vapour in the falling film of water-(LiBr + LiI + LiNO{sub 3} + LiCl) in a vertical tube at air-cooling thermal conditions

    Energy Technology Data Exchange (ETDEWEB)

    Bourouis, Mahmoud; Valles, Manel; Medrano, Marc; Coronas, Alberto [Centro de Innovacion Tecnologica en Revalorizacion Energetica y Refrigeracion, CREVER, Universitat Rovira i Virgili, Autovia de Salou, s/n, 43006, Tarragona (Spain)

    2005-05-01

    In air-cooled water-LiBr absorption chillers the working conditions in the absorber and condenser are shifted to higher temperatures and concentrations, thereby increasing the risk of crystallisation. To develop this technology, two main problems are to be addressed: the availability of new salt mixtures with wider range of solubility than water-LiBr, and advanced absorber configurations that enable to carry out simultaneously an appropriate absorption process and an effective air-cooling. One way of improving the solubility of LiBr aqueous solutions is to add other salts to create multicomponent salt solutions. The aqueous solution of the quaternary salt system (LiBr + LiI + LiNO{sub 3} + LiCl) presents favourable properties required for air-cooled absorption systems: less corrosive and crystallisation temperature about 35 K lower than that of water-LiBr.This paper presents an experimental study on the absorption of water vapour over a wavy laminar falling film of an aqueous solution of (LiBr + LiI + LiNO{sub 3} + LiCl) on the inner wall of a water-cooled smooth vertical tube. Cooling water temperatures in the range 30-45 C were selected to simulate air-cooling thermal conditions. The results are compared with those obtained in the same experimental set-up with water-LiBr solutions.The control variables for the experimental study were: absorber pressure, solution Reynolds number, solution concentration and cooling water temperature. The parameters considered to assess the absorber performance were: absorber thermal load, mass absorption flux, degree of subcooling of the solution leaving the absorber, and the falling film heat transfer coefficient.The higher solubility of the multicomponent salt solution makes possible the operation of the absorber at higher salt concentration than with the conventional working fluid water-LiBr. The absorption fluxes achieved with water-(LiBr + LiI + LiNO{sub 3} + LiCl) at a concentration of 64.2 wt% are around 60 % higher than

  1. Up-cycling waste glass to minimal water adsorption/absorption lightweight aggregate by rapid low temperature sintering: optimization by dual process-mixture response surface methodology.

    Science.gov (United States)

    Velis, Costas A; Franco-Salinas, Claudia; O'Sullivan, Catherine; Najorka, Jens; Boccaccini, Aldo R; Cheeseman, Christopher R

    2014-07-01

    Mixed color waste glass extracted from municipal solid waste is either not recycled, in which case it is an environmental and financial liability, or it is used in relatively low value applications such as normal weight aggregate. Here, we report on converting it into a novel glass-ceramic lightweight aggregate (LWA), potentially suitable for high added value applications in structural concrete (upcycling). The artificial LWA particles were formed by rapidly sintering (glass powder with clay mixes using sodium silicate as binder and borate salt as flux. Composition and processing were optimized using response surface methodology (RSM) modeling, and specifically (i) a combined process-mixture dual RSM, and (ii) multiobjective optimization functions. The optimization considered raw materials and energy costs. Mineralogical and physical transformations occur during sintering and a cellular vesicular glass-ceramic composite microstructure is formed, with strong correlations existing between bloating/shrinkage during sintering, density and water adsorption/absorption. The diametrical expansion could be effectively modeled via the RSM and controlled to meet a wide range of specifications; here we optimized for LWA structural concrete. The optimally designed LWA is sintered in comparatively low temperatures (825-835 °C), thus potentially saving costs and lowering emissions; it had exceptionally low water adsorption/absorption (6.1-7.2% w/wd; optimization target: 1.5-7.5% w/wd); while remaining substantially lightweight (density: 1.24-1.28 g.cm(-3); target: 0.9-1.3 g.cm(-3)). This is a considerable advancement for designing effective environmentally friendly lightweight concrete constructions, and boosting resource efficiency of waste glass flows.

  2. Cold vapor-solid phase microextraction using amalgamation in different Pd-based substrates combined with direct thermal desorption in a modified absorption cell for the determination of Hg by atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Romero, Vanesa; Costas-Mora, Isabel; Lavilla, Isela; Bendicho, Carlos, E-mail: bendicho@uvigo.es

    2011-02-15

    In this work, different Pd-based substrates (i.e. Pd wire, Pd-coated stainless steel wire and Pd-coated SiO{sub 2}) are tried for microextraction of Hg prior to its release into a modified quartz T-cell so as to develop a cost-effective, sensitive and easy-to-handle coupling between solid-phase microextraction (SPME) and atomic absorption spectrometry. The new design allows a direct sample injection from the SPME device into a quartz T-cell thus avoiding analyte dilution. Mercury amalgamation onto a Pd wire provided the best performance in respect to sensitivity and fiber lifetime, but Pd wires could not be implemented in the SPME device due to their poor mechanical characteristics. On the contrary, Pd-coated SiO{sub 2} fibers could be easily adapted to the typical sampling device used for SPME. Narrow time-dependent absorption signal profiles that could be integrated within 25 s were obtained. The detection limit was 90 pg mL{sup -1} of Hg, and the repeatability expressed as relative standard deviation was 4.3%.

  3. An alternative method for thermal cycling test: effect on the marginal microleakage and bond strength of dental polymer bonded to dentin

    Directory of Open Access Journals (Sweden)

    Simonides Consani

    2012-12-01

    Full Text Available This study evaluated an alternative method for thermal cycling test on the microleakage and bond strength of the polymer-dentin bond. For the microleakage test the cavities were restored with a TEGDMA+UDMA+bis-EMA composite polymer light cured for 20 s. Samples were immersed in 2% methylene blue solution for 2 h and sectioned. Microleakage scores were submitted to Kruskal-Wallis test. For the shear bond strength test the adhesive was applied to dentin, photoactivated for 10 s and the composite polymer incrementally photoactivated. Samples were submitted to shear bond strength test in a machine with a cross-head speed of 0.5 mm/min and data were submitted to ANOVA and Tukey's test. Studied groups were: 1 - without thermocycling; 2 - thermocycled at 5 ºC and 55 ºC with intermediate bath at 37 ºC; 3 - thermocycled at 5 ºC and 37 ºC; 4 - thermocycled at 37 ºC and 55 ºC; 5 - thermocycled at 5 ºC and 55 ºC (traditional test. Cold baths promoted greater microleakage when compared to control and hot bath, whereas control and hot bath were similar. Cold baths presented significant lower shear bond strength than those submitted to hot bath and control. It was concluded that the alternative method for thermal cycling test showed that cold temperatures increased the microleakage and decreased the bond strength of the polymeric adhesive.

  4. Measurement of the Residual Stresses and Investigation of Their Effects on a Hardfaced Grid Plate due to Thermal Cycling in a Pool Type Sodium-Cooled Fast Reactor

    Directory of Open Access Journals (Sweden)

    S. Balaguru

    2016-01-01

    Full Text Available In sodium-cooled fast reactors (SFR, grid plate is a critical component which is made of 316 L(N SS. It is supported on core support structure. The grid plate supports the core subassemblies and maintains their verticality. Most of the components of SFR are made of 316 L(N/304 L(N SS and they are in contact with the liquid-metal sodium which acts as a coolant. The peak operating temperature in SFR is 550°C. However, the self-welding starts at 500°C. To avoid self-welding and galling, hardfacing of the grid plate has become necessary. Nickel based cobalt-free colmonoy 5 has been identified as the hardfacing material due to its lower dose rate by Plasma Transferred Arc Welding (PTAW. This paper is concerned with the measurement and investigations of the effects of the residual stress generated due to thermal cycling on a scale-down physical model of the grid plate. Finite element analysis of the hardfaced grid plate model is performed for obtaining residual stresses using elastoplastic analysis and hence the results are validated. The effects of the residual stresses due to thermal cycling on the hardfaced grid plate model are studied.

  5. Evaluation of thermal control coatings for use on solar dynamic radiators in low earth orbit

    Science.gov (United States)

    Dever, Joyce A.; Rodriguez, Elvin; Slemp, Wayne S.; Stoyack, Joseph E.

    1991-01-01

    Thermal control coatings with high thermal emittance and low solar absorptance are needed for Space Station Freedom (SSF) solar dynamic power module radiator (SDR) surfaces for efficient heat rejection. Additionally, these coatings must be durable to low earth orbital (LEO) environmental effects of atomic oxygen, ultraviolet radiation and deep thermal cycles which occur as a result of start-up and shut-down of the solar dynamic power system. Eleven candidate coatings were characterized for their solar absorptance and emittance before and after exposure to ultraviolet (UV) radiation (200 to 400 nm), vacuum UV (VUV) radiation (100 to 200 nm) and atomic oxygen. Results indicated that the most durable and best performing coatings were white paint thermal control coatings Z-93, zinc oxide pigment in potassium silicate binder, and YB-71, zinc orthotitanate pigment in potassium silicate binder. Optical micrographs of these materials exposed to the individual environmental effects of atomic oxygen and vacuum thermal cycling showed that no surface cracking occurred.

  6. Study of the quantitative assessment method for high-cycle thermal fatigue of a T-pipe under turbulent fluid mixing based on the coupled CFD-FEM method and the rainflow counting method

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Y.; Lu, T., E-mail: likesurge@sina.com

    2016-12-01

    Highlights: • Two characteristic parameters of the temperature fluctuations are used for qualitative analysis. • A quantitative assessment method for high-cycle thermal fatigue of a T-pipe is proposed. • The time-dependent curves for the temperature and thermal stress are not always “in-phase”. • Large magnitude of thermal stresses may not mean large number of fatigue cycles. • The normalized fatigue damage rate and normalized RMS temperature are positively related. - Abstract: With the development of nuclear power and nuclear power safety, high-cycle thermal fatigue of the pipe structures induced by the flow and heat transfer of the fluid in pipes have aroused more and more attentions. Turbulent mixing of hot and cold flows in a T-pipe is a well-recognized source of thermal fatigue in piping system, and thermal fatigue is a significant long-term degradation mechanism. It is not an easy work to evaluate thermal fatigue of a T-pipe under turbulent flow mixing because of the thermal loads acting at fluid–structure interface of the pipe are so complex and changeful. In this paper, a one-way Computational Fluid Dynamics-Finite Element Method (CFD-FEM method) coupling based on the ANSYS Workbench 15.0 software has been developed to calculate transient thermal stresses with the temperature fields of turbulent flow mixing, and thermal fatigue assessment has been carried out with this obtained fluctuating thermal stresses by programming in the software platform of Matlab based on the rainflow counting method. In the thermal analysis, the normalized mean temperatures and the normalized root mean square (RMS) temperatures are obtained and compared with the experiment of the test case from the Vattenfall benchmark facility to verify the accuracy of the CFD calculation and to determine the position which thermal fatigue is most likely to occur in the T-junction. Besides, more insights have been obtained in the coupled CFD-FEM analysis and the thermal fatigue

  7. Smart Operation of Gas Turbine Combined Cycle Plants : Prediction and Improvement of Thermal Efficiency at Part Load

    NARCIS (Netherlands)

    Boksteen, S.Z.

    2014-01-01

    This thesis investigates various operational aspects of Gas Turbine Combined Cycle Power Plants (GTCC). GTCC power plants are expected to play an increasingly important role in the balancing of supply and demand in the electricity grid. Although originally meant for predominantly base load operation

  8. A life cycle cost analysis of large-scale thermal energy storage technologies for buildings using combined heat and power

    Energy Technology Data Exchange (ETDEWEB)

    Gaine, K.; Duffy, A.

    2010-07-01

    Full text: Buildings account for approximately 40% of energy consumption and greenhouse gas (GHG) emissions in developed economies, of which approximately 55% of building energy is used for heating and cooling. The reduction of building-related GHG emissions is a high international policy priority. For this reason and because there are many technical solutions for this, these polices should involve significant improvements in the uptake of small-scale energy efficient (EE) systems. However the widespread deployment of many technologies, must overcome a number of barriers, one of which is a temporal (diurnal or seasonal) mismatch between supply and demand. For example, in office applications, peak combined heat and power (CHP) thermal output may coincide with peak electrical demand in the late morning or afternoon, whereas heating may be required early in the morning. For this reason, cost-effective thermal storage solutions have the potential to improve financial performance, while simultaneously reducing associated GHG emissions. The aim of this paper is to identify existing thermal energy storage (TES) technologies and to present and asses the economic and technical performance of each for a typical large scale mixed development. Technologies identified include: Borehole Thermal Energy Storage (BTES); Aquifer Thermal Energy Storage (ATES); Pitt Thermal Energy Storage (PTES) and Energy Piles. Of these the most appropriate for large scale storage in buildings were BTES and ATES because of they are relatively cheap and are installed under a building and do not use valuable floor area A Heat transfer analyses and system simulations of a variety of BTES systems are carried out using a Finite Element Analysis package (ANSYS) and energy balance simulation software (TRNSYS) is to determine the optimal system design. Financial models for each system are developed, including capital, installation, running and maintenance costs. Using this information the unit costs of

  9. Effect of Welding Thermal Cycles on Microstructure and Mechanical Properties of Simulated Heat Affected Zone for a Weldox 1300 Ultra-High Strength Alloy Steel

    Directory of Open Access Journals (Sweden)

    Węglowski M. St.

    2016-03-01

    Full Text Available In the present study, the investigation of weldability of ultra-high strength steel has been presented. The thermal simulated samples were used to investigate the effect of welding cooling time t8/5 on microstructure and mechanical properties of heat affected zone (HAZ for a Weldox 1300 ultra-high strength steel. In the frame of these investigation the microstructure was studied by light and transmission electron microscopies. Mechanical properties of parent material were analysed by tensile, impact and hardness tests. In details the influence of cooling time in the range of 2,5 ÷ 300 sec. on hardness, impact toughness and microstructure of simulated HAZ was studied by using welding thermal simulation test. The microstructure of ultra-high strength steel is mainly composed of tempered martensite. The results show that the impact toughness and hardness decrease with increase of t8/5 under condition of a single thermal cycle in simulated HAZ. The increase of cooling time to 300 s causes that the microstructure consists of ferrite and bainite mixture. Lower hardness, for t8/5 ≥ 60 s indicated that low risk of cold cracking in HAZ for longer cooling time, exists.

  10. Numerical and experimental investigation into the subsequent thermal cycling during selective laser melting of multi-layer 316L stainless steel

    Science.gov (United States)

    Liu, Yang; Zhang, Jian; Pang, Zhicong

    2018-01-01

    Subsequent thermal cycling (STC), as the unique thermal behavior during the multi-layer manufacturing process of selective laser melting (SLM), brings about unique microstructure of the as-produced parts. A multi-layer finite element (FE) model was proposed to study the STC along with a contrast experiment. The FE simulational results show that as layer increases, the maximum temperature, dimensions and liquid lifetime of the molten pool increase, while the heating and cooling rates decrease. The maximum temperature point shifts into the molten pool, and central of molten pool shifts backward. The neighborly underlying layer can be remelted thoroughly when laser irradiates a powder layer, thus forming an excellent bonding between neighbor layers. The contrast experimental results between the single-layer and triple-layer samples show that grains in of latter become coarsen and tabular along the height direction compared with those of the former. Moreover, this effect become more serious in 2nd and 1st layers in the triple-layer sample. All the above illustrate that the STC has an significant influence on the thermal behavior during SLM process, and thus affects the microstructure of SLMed parts.

  11. Multiple thermal events in the Grenvillian orogenic cycle: geochronologic evidence from the northern Reading Prong, New York-New Jersey

    Energy Technology Data Exchange (ETDEWEB)

    Grauch, R.I.; Aleinikoff, J.N.

    1985-01-01

    The Grenville terrane of the northern Reading Prong, New York-New Jersey, has a far more complex thermal history than previously recognized. U-Pb zircon ages record at least five discrete thermal events between about 1300 and 900 Ma: (1) 1230 +/- 20 Ma--metamorphism of paragneiss; (2) 1150 +/- 30 Ma--crystallization of Storm King-type granite, protoliths of a leucogneiss, and a member of the Fordham Gneiss; (3) 1090 +/- 10 Ma--crystallization of a hornblende gneiss and the Canopus pluton; (4) 1015 +/- Ma--regional metamorphism, crystallization of the Canada Hill granite and pegmatitic alaskites; (5) 965 +/- 10 Ma--crystallization of pegmatites, formation of a monazite-xenotime rock, and closure of the U-Pb whole-rock system. Another problem that arises from these results is the past correlation throughout the Reading Prong of lithologic sequences whose zircon ages apparently do not agree. This complex sequence of Middle Proterozoic thermal events in the central Appalachians correlates fairly well with events recorded in the Grenville terrane of eastern Ontario, where at least two major orogenic events between 1300 and 900 Ma have been identified. The fit with identified events in the Adirondacks of northern New York and with Precambrian events of the southern Appalachians is not as good, but the early approx. = 1230 Ma and the late approx. = 960 Ma events seem to be present in both regions.

  12. Summary of the Effects of Two Years of Hygro-Thermal Cycling on a Carbon/Epoxy Composite Material

    Science.gov (United States)

    Kohlman, Lee W.; Binienda, Wieslaw K.; Roberts, Gary D.; Miller, Sandi G.; Pereira, J. Michael; Bail, Justin L.

    2011-01-01

    Composite materials are beginning to be used for structures in the fan section of commercial gas turbine engines. This paper explores the type of damage that could occur within one type of composite material after exposure to hygrothermal cycles (temperature/humidity cycles) that are representative of the environment in the fan section of an engine. The effect of this damage on composite material properties is measured. Chemical changes in the matrix material were limited to the exposed surface. Microcrack formation was identified in the composite material. This damage did not cause a significant reduction in tensile strength or impact penetration resistance of the composite material. Additional data is needed to assess the effect of damage on compressive strength.

  13. Test results of an organic Rankine-cycle power module for a small community solar thermal power experiment

    Science.gov (United States)

    Clark, T. B.

    1985-01-01

    The organic Rankine-cycle (ORC) power conversion assembly was tested. Qualification testing of the electrical transport subsystem was also completed. Test objectives were to verify compatibility of all system elements with emphasis on control of the power conversion assembly, to evaluate the performance and efficiency of the components, and to validate operating procedures. After 34 hours of power generation under a wide range of conditions, the net module efficiency exceeded 18% after accounting for all parasitic losses.

  14. Results of molten salt panel and component experiments for solar central receivers: Cold fill, freeze/thaw, thermal cycling and shock, and instrumentation tests

    Energy Technology Data Exchange (ETDEWEB)

    Pacheco, J.E.; Ralph, M.E.; Chavez, J.M.; Dunkin, S.R.; Rush, E.E.; Ghanbari, C.M.; Matthews, M.W.

    1995-01-01

    Experiments have been conducted with a molten salt loop at Sandia National Laboratories in Albuquerque, NM to resolve issues associated with the operation of the 10MW{sub e} Solar Two Central Receiver Power Plant located near Barstow, CA. The salt loop contained two receiver panels, components such as flanges and a check valve, vortex shedding and ultrasonic flow meters, and an impedance pressure transducer. Tests were conducted on procedures for filling and thawing a panel, and assessing components and instrumentation in a molten salt environment. Four categories of experiments were conducted: (1) cold filling procedures, (2) freeze/thaw procedures, (3) component tests, and (4) instrumentation tests. Cold-panel and -piping fill experiments are described, in which the panels and piping were preheated to temperatures below the salt freezing point prior to initiating flow, to determine the feasibility of cold filling the receiver and piping. The transient thermal response was measured, and heat transfer coefficients and transient stresses were calculated from the data. Freeze/thaw experiments were conducted with the panels, in which the salt was intentionally allowed to freeze in the receiver tubes, then thawed with heliostat beams. Slow thermal cycling tests were conducted to measure both how well various designs of flanges (e.g., tapered flanges or clamp type flanges) hold a seal under thermal conditions typical of nightly shut down, and the practicality of using these flanges on high maintenance components. In addition, the flanges were thermally shocked to simulate cold starting the system. Instrumentation such as vortex shedding and ultrasonic flow meters were tested alongside each other, and compared with flow measurements from calibration tanks in the flow loop.

  15. System analysis of central receiver concepts with high temperature thermal energy storages: Receiver technologies and storage cycles

    Science.gov (United States)

    Steiner, Peter; Schwaiger, Karl; Haider, Markus; Walter, Heimo

    2017-06-01

    Reducing the levelized cost of electricity for solar thermal electricity (STE) plants is the most important challenge of this technology. A bottleneck at state of the art STE plants is the heat storage medium (HSM) with its temperature limits. To replace the commonly used molten salt, particles like quartz sand or corundum, enabling temperatures up to 1000 °C, are proposed as new HSM. The temperature raise leads to economical challenges, which have to be analyzed more in detail. In this work two STE plant concepts based on particles as HSM are introduced and discussed to outline advantages and issues concerning this technology.

  16. Evidence for an enhanced hydrologic cycle during the Paleocene-Eocene thermal maximum from salinity variations on the New Jersey paleoshelf

    Science.gov (United States)

    Makarova, M.; Miller, K. G.; Wright, J. D.; Rosenthal, Y.; Babila, T. L.

    2016-12-01

    The Paleocene-Eocene Thermal Maximum (PETM) was an abrupt global warming event ( 5-8°C) associated with a massive injection of carbon indicated by the negative carbon isotopic excursion (CIE). Reconstructions of the hydrologic cycle during the PETM warming are especially important to understand the ocean-atmosphere system response to changing warming climate. It has been proposed that the PETM warming would have enhanced the hydrologic cycle, resulting in increased rainfall and river discharge. Here, we evaluate salinity changes along the New Jersey paleoshelf and their implications to changes in the hydrologic cycle during the PETM. We use two independent paleothermometers (Mg/Ca ratio of planktonic foraminifera and TEX86) to constrain temperature changes associated with planktonic foraminiferal δ18O variations, with the residual attributed to salinity changes. Our study at Millville, New Jersey coastal plain core (ODP Leg 174AX), shows a salinity decrease of at least 4 psu associated with the onset of the PETM, which is coherent with observations from other New Jersey cores. This implies freshening of surface and thermocline waters on the mid Atlantic margin and supports the hypothesis of an enhanced hydrologic cycle, the "Appalachian Amazon", with increased river runoff to the New Jersey paleoshelf during the PETM. The TEXL 86 temperature calibration provides the best temperature estimate (warming from 23 to 30°C vs. 30 to 35.5°C for TEXH 86) because it is the only one that yields realistic salinities. Use of the TEXH 86 calibration yields extremely high sea surface salinities ( 48 psu in the latest Paleocene) and is thus unsuitable for this location during the PETM.

  17. Central cooling: absorptive chillers

    Energy Technology Data Exchange (ETDEWEB)

    Christian, J.E.

    1977-08-01

    This technology evaluation covers commercially available single-effect, lithium-bromide absorption chillers ranging in nominal cooling capacities of 3 to 1,660 tons and double-effect lithium-bromide chillers from 385 to 1,060 tons. The nominal COP measured at operating conditions of 12 psig input steam for the single-effect machine, 85/sup 0/ entering condenser water, and 44/sup 0/F exiting chilled-water, ranges from 0.6 to 0.65. The nominal COP for the double-effect machine varies from 1.0 to 1.15 with 144 psig entering steam. Data are provided to estimate absorption-chiller performance at off-nominal operating conditions. The part-load performance curves along with cost estimating functions help the system design engineer select absorption equipment for a particular application based on life-cycle costs. Several suggestions are offered which may be useful for interfacing an absorption chiller with the remaining Integrated Community Energy System. The ammonia-water absorption chillers are not considered to be readily available technology for ICES application; therefore, performance and cost data on them are not included in this evaluation.

  18. Effect of Turf Roof Slabs on Indoor Thermal Performance in Tropical Climates: A Life Cycle Cost Approach

    Directory of Open Access Journals (Sweden)

    R. U. Halwatura

    2013-01-01

    Full Text Available Urbanization related to population growth is one of the burning issues that the world is facing today. Parallel to this, there is visible evidence of a possible energy crisis in the near future. Thus, scientists have paid attention to sustainable development methods, and in the field of building construction also, several innovations have been proposed. For example, green roof concept is one of such which is considered a viable method mainly to reduce urban heat island effect, to regain lost land spaces in cities, and to increase aesthetics in cities. The present study was aimed at investigating the impact of green roofs on indoor temperature of buildings, the effect of different types of roofs on the air conditioning loads, and the life cycle cost of buildings with different types of roofing. The study was conducted in several phases: initial small-scale models to determine the heat flow characteristics of roof top soil layers with different thicknesses, a large-scale model applying the findings of the small-scale models to determine temperature fluctuations within a building with other common roofing systems, a computer simulation to investigate air conditioning loads in a typical building with cement fiber sheets and green roof slabs, a comparative analysis of the effect of traditional type roofs and green roofs on the air conditioning loads, and finally an analysis to predict the influence of traditional type roofs and green roofs on life cycle cost of the buildings. The main findings of the study were that green roofs are able to reduce the indoor temperature of buildings and are able to achieve better heat transfer through the roof, and, thus a lower cooling load is necessary for air conditioning and has the possibility of reducing life cycle cost of a building.

  19. Development of an Organic Rankine-Cycle power module for a small community solar thermal power experiment

    Science.gov (United States)

    Kiceniuk, T.

    1985-01-01

    An organic Rankine-cycle (ORC) power module was developed for use in a multimodule solar power plant to be built and operated in a small community. Many successful components and subsystems, including the reciever, power conversion subsystem, energy transport subsystem, and control subsystem, were tested. Tests were performed on a complete power module using a test bed concentrator in place of the proposed concentrator. All major single-module program functional objectives were met and the multimodule operation presented no apparent problems. The hermetically sealed, self-contained, ORC power conversion unit subsequently successfully completed a 300-hour endurance run with no evidence of wear or operating problems.

  20. Effect of mouth-motion fatigue and thermal cycling on the marginal accuracy of partial coverage restorations made of various dental materials.

    Science.gov (United States)

    Stappert, Christian F J; Chitmongkolsuk, Somsak; Silva, Nelson R F A; Att, Wael; Strub, Joerg R

    2008-09-01

    To investigate the influence of mouth-motion fatigue on marginal-accuracy of partial-coverage-restorations-(PCRs) of various dental materials. Eighty molars were prepared equally and divided into five groups (n=16). PCRs were fabricated of following dental materials: Group-GO=Gold-Pontor-MPF(double dagger), Group-TA=Targis*, Group-EX=IPS-e.max-Press*, Group-EM=IPS-Empress*, Group-PC=ProCAD*/Cerec 3(dagger) ((double dagger)Metalor/*Ivoclar-Vivadent/(dagger)Sirona-Dental-System). Gold-PCRs were cemented conventionally. Residual 64 PCRs were adhesively luted and subjected to masticatory loading (1.2million-cycles, 1.6Hz, 49N) and thermal cycling (5 degrees C/55 degrees C, 60s, dwell-time, 5500cycles). Discrepancies in marginal-accuracy were examined on epoxy replicas (200 x magnification). Statistical analysis was performed by unpaired and paired t-tests (alpha=0.05). After cementing, marginal-accuracy (geometrical mean)[95% confidence limits] was recorded: GO-47[43-51]microm, TA-42[38-45]microm, EX-60[52-67]microm, EM-52[45-60]microm and PC-75[59-94]microm. No significant differences were found between groups GO, TA and EM. Values of Group-EX were significantly higher compared to Group-TA (p=0.04). Group-PC demonstrated significantly decreased marginal-accuracy towards groups GO (p=0.03) and TA (p=0.02). Except for Group-GO (p=0.01), no significant changes in marginal-accuracy were observed after mouth-motion fatigue and thermal cycling (GO-42[38-45]microm, TA-42[38-47]microm, EX-56[49-65]microm, EM-54[46-64]microm and PC-71[59-84]microm). However, Group-GO and Group-EM showed significant deviations in marginal-accuracy after aging (p=0.04). Marginal discrepancies of groups EX and EM were similar (p=1.0). Values of Group-PC were significantly higher when compared to groups GO (p=0.01) and TA (p=0.02). Buccal-lingual marginal discrepancies were significantly higher than mesial-distal in all groups and stages. Cast-gold-PCRs demonstrated superior marginal

  1. An initial study on modeling the global thermal and fast reactor fuel cycle mass flow using Vensim

    Energy Technology Data Exchange (ETDEWEB)

    Brinton, Samuel [Kansas State University, Mechanical Engineering, Manhattan, KS 66506 (United States)

    2008-07-01

    This study concentrated on modeling the construction and decommissioning rates of five major facilities comprising the nuclear fuel cycle: (1) current LWRs with a 60-year service life, (2) new LWRs burning MOX fuel, (3) new LWRs to replace units in the current fleet, (4) new FRs to be added to the fleet, and (5) new spent fuel reprocessing facilities. This is a mass flow mode starting from uranium ore and following it to spent forms. The visual dynamic modeling program Vensim was used to create a system of equations and variables to track the mass flows from enrichment, fabrication, burn-up, and the back-end of the fuel cycle. The scenarios considered provide estimates of the uranium ore requirements, quantities of LLW and HLW production, and the number of reprocessing facilities necessary to reduce recently reported levels of spent fuel inventory. Preliminary results indicate that the entire national spent fuel inventory produced in the next 100 years can be reprocessed with a reprocessing plant built every 11 years (small capacity) or even as low as every 23 years (large capacity). (authors)

  2. Thermodynamic analysis of a combined-cycle solar thermal power plant with manganese oxide-based thermochemical energy storage

    Directory of Open Access Journals (Sweden)

    Lei Qi

    2017-01-01

    Full Text Available We explore the thermodynamic efficiency of a solar-driven combined cycle power system with manganese oxide-based thermochemical energy storage system. Manganese oxide particles are reduced during the day in an oxygen-lean atmosphere obtained with a fluidized-bed reactor at temperatures in the range of 750–1600°C using concentrated solar energy. Reduced hot particles are stored and re-oxidized during night-time to achieve continuous power plant operation. The steady-state mass and energy conservation equations are solved for all system components to calculate the thermodynamic properties and mass flow rates at all state points in the system, taking into account component irreversibilities. The net power block and overall solar-to-electric energy conversion efficiencies, and the required storage volumes for solids and gases in the storage system are predicted. Preliminary results for a system with 100 MW nominal solar power input at a solar concentration ratio of 3000, designed for constant round-the-clock operation with 8 hours of on-sun and 16 hours of off-sun operation and with manganese oxide particles cycled between 750 and 1600°C yield a net power block efficiency of 60.0% and an overall energy conversion efficiency of 41.3%. Required storage tank sizes for the solids are estimated to be approx. 5–6 times smaller than those of state-of-the-art molten salt systems.

  3. Thermodynamic analysis of a combined-cycle solar thermal power plant with manganese oxide-based thermochemical energy storage

    Science.gov (United States)

    Lei, Qi; Bader, Roman; Kreider, Peter; Lovegrove, Keith; Lipiński, Wojciech

    2017-11-01

    We explore the thermodynamic efficiency of a solar-driven combined cycle power system with manganese oxide-based thermochemical energy storage system. Manganese oxide particles are reduced during the day in an oxygen-lean atmosphere obtained with a fluidized-bed reactor at temperatures in the range of 750-1600°C using concentrated solar energy. Reduced hot particles are stored and re-oxidized during night-time to achieve continuous power plant operation. The steady-state mass and energy conservation equations are solved for all system components to calculate the thermodynamic properties and mass flow rates at all state points in the system, taking into account component irreversibilities. The net power block and overall solar-to-electric energy conversion efficiencies, and the required storage volumes for solids and gases in the storage system are predicted. Preliminary results for a system with 100 MW nominal solar power input at a solar concentration ratio of 3000, designed for constant round-the-clock operation with 8 hours of on-sun and 16 hours of off-sun operation and with manganese oxide particles cycled between 750 and 1600°C yield a net power block efficiency of 60.0% and an overall energy conversion efficiency of 41.3%. Required storage tank sizes for the solids are estimated to be approx. 5-6 times smaller than those of state-of-the-art molten salt systems.

  4. Micro-scale thermal imaging of CO2 absorption in the thermochemical energy storage of Li metal oxides at high temperature

    Science.gov (United States)

    Morikawa, Junko; Takasu, Hiroki; Zamengo, Massimiliano; Kato, Yukitaka

    2017-05-01

    Li-Metal oxides (typical example: lithium ortho-silicate Li4SiO4) are regarded as a novel solid carbon dioxide CO2 absorbent accompanied by an exothermic reaction. At temperatures above 700°C the sorbent is regenerated with the release of the captured CO2 in an endothermic reaction. As the reaction equilibrium of this reversible chemical reaction is controllable only by the partial pressure of CO2, the system is regarded as a potential candidate for chemical heat storage at high temperatures. In this study, we applied our recent developed mobile type instrumentation of micro-scale infrared thermal imaging system to observe the heat of chemical reaction of Li4SiO4 and CO2 at temperature higher than 600°C or higher. In order to quantify the micro-scale heat transfer and heat exchange in the chemical reaction, the superimpose signal processing system is setup to determine the precise temperature. Under an ambient flow of carbon dioxide, a powder of Li4SiO4 with a diameter 50 micron started to shine caused by an exothermic chemical reaction heat above 600°C. The phenomena was accelerated with increasing temperature up to 700°C. At the same time, the reaction product lithium carbonate (Li2CO3) started to melt with endothermic phase change above 700°C, and these thermal behaviors were captured by the method of thermal imaging. The direct measurement of multiple thermal phenomena at high temperatures is significant to promote an efficient design of chemical heat storage materials. This is the first observation of the exothermic heat of the reaction of Li4SiO4 and CO2 at around 700°C by the thermal imaging method.

  5. Improvement of the management of residual waste in areas without thermal treatment facilities: A life cycle analysis of an Italian management district

    Energy Technology Data Exchange (ETDEWEB)

    Di Maria, Francesco, E-mail: francesco.dimaria@unipg.it [LAR Laboratory, Dipartimento di Ingegneria, Via G. Duranti 93, Perugia (Italy); Micale, Caterina; Morettini, Emanuela [LAR Laboratory, Dipartimento di Ingegneria, Via G. Duranti 93, Perugia (Italy); Sisani, Luciano [TSA spa, Via Case Sparse 107, Magione (Italy); Damiano, Roberto [GESENU spa, Via della Molinella 7, Perugia (Italy)

    2015-10-15

    Highlights: • LCA analysis of two option for residual waste management. • Exploitation of mechanical physical sorting facility for extracting recyclable from RMSW. • Processing the mechanically sorted organic fraction in bioreactor landfill. • Sensitivity analysis demonstrate high influence for impact assessment of substitution ratio for recycle materials. - Abstract: Starting from an existing waste management district without thermal treatment facilities, two different management scenarios for residual waste were compared by life cycle assessment (LCA). The adoption of a bioreactor landfill for managing the mechanically sorted organic fraction instead of bio-stabilization led to reduction of global warming and fresh water eutrophication by 50% and 10%, respectively. Extraction of recyclables from residual waste led to avoided emissions for particulate matter, acidification and resource depletion impact categories. Marginal energy and the amount of energy recovered from landfill gas marginally affected the LCA results. On the contrary the quality of the recyclables extracted can significantly modify the eco profile of the management schemes.

  6. In-Situ Measurement of Power Loss for Crystalline Silicon Modules Undergoing Thermal Cycling and Mechanical Loading Stress Testing: Preprint

    Energy Technology Data Exchange (ETDEWEB)

    Spataru, Sergiu; Hacke, Pater; Sera, Dezso

    2015-09-15

    We analyze the degradation of multi-crystalline silicon photovoltaic modules undergoing simultaneous thermal, mechanical, and humidity stress testing to develop a dark environmental chamber in-situ measurement procedure for determining module power loss. From the analysis we determine three main categories of failure modes associated with the module degradation consisting of: shunting, recombination losses, increased series resistance losses, and current mismatch losses associated with a decrease in photo-current generation by removal of some cell areas due to cell fractures. Based on the analysis, we propose an in-situ module power loss monitoring procedure that relies on dark current-voltage measurements taken during the stress test, and initial and final module flash testing, to determine the power degradation characteristic of the module.

  7. Correlation of Etch Pits and Dislocations in As-grown and Thermal Cycle-Annealed HgCdTe(211) Films

    Science.gov (United States)

    Vaghayenegar, M.; Jacobs, R. N.; Benson, J. D.; Stoltz, A. J.; Almeida, L. A.; Smith, David J.

    2017-08-01

    This paper reports observations of the different types of etch pits and dislocations present in thick HgCdTe (211) layers grown by molecular beam epitaxy on CdTe/Si (211) composite substrates. Dislocation analysis for as-grown and thermal cycle-annealed samples has been carried out using bright-field transmission electron microscopy. Triangular pits present in as-grown material are associated with a mixture of Frank partials and perfect dislocations, while pits with fish-eye shapes have perfect dislocations with 1/2[0\\bar{1}1] Burgers vector. The dislocations beneath skew pits are more complex as they have two different crystallographic directions, and are associated with a mixture of Shockley partials and perfect dislocations. Dislocation analysis of samples after thermal cycle annealing (TCA) shows that the majority of dislocations under the etch pits are short segments of perfect dislocations with 1/2[0\\bar{1}1] Burgers vector while the remainder are Shockley partials. The absence of fish-eye shape pits in TCA samples suggests that they are associated with mobile dislocations that have reacted during annealing, causing the overall etch pit density to be reduced. Very large pits with a density ˜2×103 cm-2 are observed in as-grown and TCA samples. These defects thread from within the CdTe buffer layer into the upper regions of the HgCdTe layers. Their depth in as-grown material is so large that it is not possible to locate and identify the underlying defects.

  8. Crenarchaeota and their role in the nitrogen cycle in a subsurface radioactive thermal spring in the Austrian Central Alps.

    Science.gov (United States)

    Weidler, Gerhard W; Gerbl, Friedrich W; Stan-Lotter, Helga

    2008-10-01

    Previous results from a 16S rRNA gene library analysis showed high diversity within the prokaryotic community of a subterranean radioactive thermal spring, the "Franz-Josef-Quelle" (FJQ) in Bad Gastein, Austria, as well as evidence for ammonia oxidation by crenarchaeota. This study reports further characterization of the community by denaturing gradient gel electrophoresis (DGGE) analysis, fluorescence in situ hybridization (FISH), and semiquantitative nitrification measurements. DGGE bands from three types of samples (filtered water, biofilms on glass slides, and naturally grown biofilms), including samples collected at two distinct times (January 2005 and July 2006), were analyzed. The archaeal community consisted mainly of Crenarchaeota of the soil-subsurface-freshwater group (group 1.1b) and showed a higher diversity than in the previous 16S rRNA gene library analysis, as was also found for crenarchaeal amoA genes. No bacterial amoA genes were detected. FISH analysis of biofilms indicated the presence of archaeal cells with an abundance of 5.3% (+/-4.5%) in the total 4',6-diamidino-2-phenylindole (DAPI)-stained community. Microcosm experiments of several weeks in duration showed a decline of ammonium that correlated with an increase of nitrite, the presence of crenarchaeal amoA genes, and the absence of bacterial amoA genes. The data suggested that only ammonia-oxidizing archaea (AOA) perform the first step of nitrification in this 45 degrees C environment. The crenarchaeal amoA gene sequences grouped within a novel cluster of amoA sequences from the database, originating from geothermally influenced environments, for which we propose the designation "thermal spring" cluster and which may be older than most AOA from soils on earth.

  9. Crenarchaeota and Their Role in the Nitrogen Cycle in a Subsurface Radioactive Thermal Spring in the Austrian Central Alps▿

    Science.gov (United States)

    Weidler, Gerhard W.; Gerbl, Friedrich W.; Stan-Lotter, Helga

    2008-01-01

    Previous results from a 16S rRNA gene library analysis showed high diversity within the prokaryotic community of a subterranean radioactive thermal spring, the “Franz-Josef-Quelle” (FJQ) in Bad Gastein, Austria, as well as evidence for ammonia oxidation by crenarchaeota. This study reports further characterization of the community by denaturing gradient gel electrophoresis (DGGE) analysis, fluorescence in situ hybridization (FISH), and semiquantitative nitrification measurements. DGGE bands from three types of samples (filtered water, biofilms on glass slides, and naturally grown biofilms), including samples collected at two distinct times (January 2005 and July 2006), were analyzed. The archaeal community consisted mainly of Crenarchaeota of the soil-subsurface-freshwater group (group 1.1b) and showed a higher diversity than in the previous 16S rRNA gene library analysis, as was also found for crenarchaeal amoA genes. No bacterial amoA genes were detected. FISH analysis of biofilms indicated the presence of archaeal cells with an abundance of 5.3% (±4.5%) in the total 4′,6-diamidino-2-phenylindole (DAPI)-stained community. Microcosm experiments of several weeks in duration showed a decline of ammonium that correlated with an increase of nitrite, the presence of crenarchaeal amoA genes, and the absence of bacterial amoA genes. The data suggested that only ammonia-oxidizing archaea (AOA) perform the first step of nitrification in this 45°C environment. The crenarchaeal amoA gene sequences grouped within a novel cluster of amoA sequences from the database, originating from geothermally influenced environments, for which we propose the designation “thermal spring” cluster and which may be older than most AOA from soils on earth. PMID:18723663

  10. Thermal intensification of microbial Fe(II)/Fe(III) redox cycling in a pristine shallow sand aquifer on the Canadian Shield.

    Science.gov (United States)

    Shirokova, V L; Enright, A M L; Kennedy, C B; Ferris, F G

    2016-12-01

    This investigation evaluates spatial relationships between summer (July) groundwater temperatures and Fe(II)/Fe(III) biogeochemical cycling over a five year period in a shallow pristine sand aquifer at Meilleurs Bay near Deep River, Ontario, Canada. A warm subsurface thermal island of 12.5-16.1 °C, compared to background conditions of 10-11 °C, was manifest in contour maps of average groundwater temperature over the study period. The warm zone coincided with an area of convergent groundwater flow, implicating horizontal heat transfer by advective convection as the reason for elevated temperatures. Additionally, high concentrations of dissolved Fe(II) and Fe(III) overlapped the warm thermal island, indicative of increased rates of bacterial Fe(II)-oxidation and Fe(III)-reduction. A depletion in the modal abundance of Fe(II)-bearing minerals, notably amphibole and biotite, inside the area of the warm thermal island was also observed, suggesting enhanced mineral dissolution owing to chemoautotrophic Fe(II)-oxidation coupled to the reduction and fixation of dissolved inorganic carbon as biomass. Throughout the aquifer, redox conditions were poised in terms of Eh and pH close to equilibrium with respect to the Fe(II)/Fe(OH)3 couple, feasibly enabling simultaneous bacterial Fe(II)-oxidation and Fe(III)-reduction with an adequate supply of electron acceptors and donors, respectively. The significance of higher groundwater temperature as a determinant of elevated dissolved Fe(II) and Fe(III) concentrations induced by thermal intensification of microbial biogeochemical activities yielded Pearson product-moment correlations in which temperature alone, as a single independent variable, explains almost 30 to nearly 60 percent of the variation in the measured dissolved Fe(II) and Fe(III) concentrations in the groundwater. These results emphasize the important influence of thermal conditions on biogeochemical processes in aquifers coupled to the development of steep

  11. Narrative absorption

    DEFF Research Database (Denmark)

    Narrative Absorption brings together research from the social sciences and Humanities to solve a number of mysteries: Most of us will have had those moments, of being totally absorbed in a book, a movie, or computer game. Typically we do not have any idea about how we ended up in such a state. No...

  12. [The stabilizing effect of enterosgel on the structural bases of membrane digestion and absorption in the small intestine in severe thermal skin burns].

    Science.gov (United States)

    Pasechka, N V

    1996-01-01

    Enterosgel effect on morphofunctional indices of the small intestine has been ascertained in experiments on animals, histochemical, electron-microscopic and morphometric methods being used. Enterosorbent in the dose of 0.3 g/kg body weight was injected orally to the guinea-pigs for 14 days. The results of the investigations prove the severe burn traumas to result in sufficient structural changes in the small intestine wall which causes impairment of membranous digestion processes and absorption of nutrients. It is to be noted that the developing burn disease results in the increase of changes severity and reaches the highest values at the stage of septicotoxemia. The enterosorbent assessed positively affects morphofunctional values of the small intestine. The enterosorbent does not enhance conventional development of the pathologic process but considerably decreases its manifestation. The enterosgel promotes the improvement of membranous digestion and absorption in the small intestine, increasing alkaline phosphatase action and rising the number of endocellular vesicles in epitheliocytes having brush margins.

  13. Thermal Cycling Life Prediction of Sn-3.0Ag-0.5Cu Solder Joint Using Type-I Censored Data

    Directory of Open Access Journals (Sweden)

    Jinhua Mi

    2014-01-01

    Full Text Available Because solder joint interconnections are the weaknesses of microelectronic packaging, their reliability has great influence on the reliability of the entire packaging structure. Based on an accelerated life test the reliability assessment and life prediction of lead-free solder joints using Weibull distribution are investigated. The type-I interval censored lifetime data were collected from a thermal cycling test, which was implemented on microelectronic packaging with lead-free ball grid array (BGA and fine-pitch ball grid array (FBGA interconnection structures. The number of cycles to failure of lead-free solder joints is predicted by using a modified Engelmaier fatigue life model and a type-I censored data processing method. Then, the Pan model is employed to calculate the acceleration factor of this test. A comparison of life predictions between the proposed method and the ones calculated directly by Matlab and Minitab is conducted to demonstrate the practicability and effectiveness of the proposed method. At last, failure analysis and microstructure evolution of lead-free solders are carried out to provide useful guidance for the regular maintenance, replacement of substructure, and subsequent processing of electronic products.

  14. Thermal cycling life prediction of Sn-3.0Ag-0.5Cu solder joint using type-I censored data.

    Science.gov (United States)

    Mi, Jinhua; Li, Yan-Feng; Yang, Yuan-Jian; Peng, Weiwen; Huang, Hong-Zhong

    2014-01-01

    Because solder joint interconnections are the weaknesses of microelectronic packaging, their reliability has great influence on the reliability of the entire packaging structure. Based on an accelerated life test the reliability assessment and life prediction of lead-free solder joints using Weibull distribution are investigated. The type-I interval censored lifetime data were collected from a thermal cycling test, which was implemented on microelectronic packaging with lead-free ball grid array (BGA) and fine-pitch ball grid array (FBGA) interconnection structures. The number of cycles to failure of lead-free solder joints is predicted by using a modified Engelmaier fatigue life model and a type-I censored data processing method. Then, the Pan model is employed to calculate the acceleration factor of this test. A comparison of life predictions between the proposed method and the ones calculated directly by Matlab and Minitab is conducted to demonstrate the practicability and effectiveness of the proposed method. At last, failure analysis and microstructure evolution of lead-free solders are carried out to provide useful guidance for the regular maintenance, replacement of substructure, and subsequent processing of electronic products.

  15. Fracture resistance of porcelain veneered zirconia crowns with exposed lingual zirconia for anterior teeth after thermal cycling: An in vitro study

    Science.gov (United States)

    Amir Rad, Fatemeh A.; Succaria, Faysal G.; Morgano, Steven M.

    2015-01-01

    Statement of problem In some clinical conditions minimally invasive complete crown tooth preparations are indicated. This is especially true when gross removal of tooth structure would weaken the remaining tooth or violate the vitality of the dental pulp. Objective The purpose of this study was to investigate the influence of (1) exposed lingual zirconia with veneered zirconia crowns, and (2) reduced lingual thickness of monolithic lithium disilicate crowns on the fracture resistance of the crowns after cyclic loading. Metal-ceramic crowns with exposed lingual metal served as controls. Materials and methods Twenty-four maxillary central incisor crowns were fabricated in identical shape on metal testing dies in 3 groups: metal-ceramic crowns (MC, n = 8), veneered zirconia crowns (VZ, n = 8), and monolithic lithium disilicate crowns (MO, n = 8). A conservative preparation design with 0.75 mm lingual clearance was used for each crown system. All crowns were cemented to their corresponding crown preparations with self-adhesive resin cement (Multilink Automix). The crowns were subjected to 1000 cycles of thermal cycling, then cyclic loading of 111 N by means of a stainless steel ball, and 50,000 cycles of loading were applied for the fatigue test. Fatigue loading was followed by a continuously increasing compressive load, at a crosshead speed of 1 mm/min until failure. The compressive load (N) required to cause failure was recorded. Means were calculated and analyzed with one-way ANOVA and the Tukey HSD test (α = .05). Results There was a significant difference between MO vs. MC (P = .0001), MO vs. VZ (P = .0001), and VZ vs. MC (P = .012). Conclusions There was a significant difference in the mean fracture resistance of MC, VZ, and MO crowns in this in vitro study. The MC group recorded the highest mean fracture strength. PMID:26082571

  16. Fracture resistance of porcelain veneered zirconia crowns with exposed lingual zirconia for anterior teeth after thermal cycling: An in vitro study.

    Science.gov (United States)

    Amir Rad, Fatemeh A; Succaria, Faysal G; Morgano, Steven M

    2015-04-01

    In some clinical conditions minimally invasive complete crown tooth preparations are indicated. This is especially true when gross removal of tooth structure would weaken the remaining tooth or violate the vitality of the dental pulp. The purpose of this study was to investigate the influence of (1) exposed lingual zirconia with veneered zirconia crowns, and (2) reduced lingual thickness of monolithic lithium disilicate crowns on the fracture resistance of the crowns after cyclic loading. Metal-ceramic crowns with exposed lingual metal served as controls. Twenty-four maxillary central incisor crowns were fabricated in identical shape on metal testing dies in 3 groups: metal-ceramic crowns (MC, n = 8), veneered zirconia crowns (VZ, n = 8), and monolithic lithium disilicate crowns (MO, n = 8). A conservative preparation design with 0.75 mm lingual clearance was used for each crown system. All crowns were cemented to their corresponding crown preparations with self-adhesive resin cement (Multilink Automix). The crowns were subjected to 1000 cycles of thermal cycling, then cyclic loading of 111 N by means of a stainless steel ball, and 50,000 cycles of loading were applied for the fatigue test. Fatigue loading was followed by a continuously increasing compressive load, at a crosshead speed of 1 mm/min until failure. The compressive load (N) required to cause failure was recorded. Means were calculated and analyzed with one-way ANOVA and the Tukey HSD test (α = .05). There was a significant difference between MO vs. MC (P = .0001), MO vs. VZ (P = .0001), and VZ vs. MC (P = .012). There was a significant difference in the mean fracture resistance of MC, VZ, and MO crowns in this in vitro study. The MC group recorded the highest mean fracture strength.

  17. Negative thermal expansion in crystals with the delafossite structure: An extended x-ray absorption fine structure study of CuScO2 and CuLaO2

    Science.gov (United States)

    Ahmed, S. I.; Dalba, G.; Fornasini, P.; Vaccari, M.; Rocca, F.; Sanson, A.; Li, J.; Sleight, A. W.

    2009-03-01

    Extended x-ray absorption fine structure has been measured at the K edge of copper in CuScO2 and CuLaO2 to investigate the local origin of negative thermal expansion (NTE) along the c axis. A positive expansion of the Cu-O bond has been measured within the entire temperature interval to be contrasted with the negative expansion of the distance between average atomic positions measured by diffraction; the inadequacy of the riding correction to diffraction data has been evidenced. The weak temperature dependence of the parallel mean-square relative displacement (MSRD) indicates a rather stiff Cu-O bond, while the large perpendicular MSRD measures an intense relative motion of copper with respect to oxygen atoms perpendicular to the c axis. The comparison between the two compounds enlightens the relevance of the correlation of perpendicular motion to quantitatively explain the apparent NTE of the Cu-O bond.

  18. Computational study of Jeffrey’s non-Newtonian fluid past a semi-infinite vertical plate with thermal radiation and heat generation/absorption

    Directory of Open Access Journals (Sweden)

    S. Abdul Gaffar

    2017-06-01

    Full Text Available The nonlinear, steady state boundary layer flow, heat and mass transfer of an incompressible non-Newtonian Jeffrey’s fluid past a semi-infinite vertical plate is examined in this article. The transformed conservation equations are solved numerically subject to physically appropriate boundary conditions using a versatile, implicit finite-difference Keller box technique. The influence of a number of emerging non-dimensional parameters, namely Deborah number (De, ratio of relaxation to retardation times (λ, Buoyancy ratio parameter (N, suction/injection parameter (fw, Radiation parameter (F, Prandtl number (Pr, Schmidt number (Sc, heat generation/absorption parameter (Δ and dimensionless tangential coordinate (ξ on velocity, temperature and concentration evolution in the boundary layer regime is examined in detail. Also, the effects of these parameters on surface heat transfer rate, mass transfer rate and local skin friction are investigated. This model finds applications in metallurgical materials processing, chemical engineering flow control, etc.

  19. Surface and in-depth characterization of lithium-ion battery cathodes at different cycle states using confocal micro-X-ray fluorescence-X-ray absorption near edge structure analysis

    Energy Technology Data Exchange (ETDEWEB)

    Menzel, Magnus; Schlifke, Annalena [Institut für Anorganische und Angewandte Chemie, Universität Hamburg, Martin-Luther-King-Platz 6, 20146 Hamburg (Germany); Falk, Mareike; Janek, Jürgen [Physikalisch-Chemisches Institut, Justus-Liebig-Universität Gießen, Heinrich-Buff-Ring 58, 35392 Gießen (Germany); Fröba, Michael, E-mail: froeba@chemie.uni-hamburg.de [Institut für Anorganische und Angewandte Chemie, Universität Hamburg, Martin-Luther-King-Platz 6, 20146 Hamburg (Germany); Fittschen, Ursula Elisabeth Adriane, E-mail: ursula.fittschen@chemie.uni-hamburg.de [Institut für Anorganische und Angewandte Chemie, Universität Hamburg, Martin-Luther-King-Platz 6, 20146 Hamburg (Germany)

    2013-07-01

    The cathode material LiNi{sub 0.5}Mn{sub 1.5}O{sub 4} for lithium-ion batteries has been studied with confocal micro-X-ray fluorescence (CMXRF) combined with X-ray absorption near edge structure (XANES) at the Mn-K edge and the Ni-K edge. This technique allows for a non-destructive, spatially resolved (x, y and z) investigation of the oxidation states of surface areas and to some extent of deeper layers of the electrode. Until now CMXRF-XANES has been applied to a limited number of applications, mainly geo-science. Here, we introduce this technique to material science applications and show its performance to study a part of a working system. A novel mesoporous LiNi{sub 0.5}Mn{sub 1.5}O{sub 4} material was cycled (charged and discharged) to investigate the effects on the oxidation states at the cathode/electrolyte interface. With this approach the degradation of Mn{sup 3+} to Mn{sup 4+} only observable at the surface of the electrode could be directly shown. The spatially resolved non-destructive analysis provides knowledge helpful for further understanding of deterioration and the development of high voltage battery materials, because of its nondestructive nature it will be also suitable to monitor processes during battery cycling. - Highlights: • The potential of confocal micro-XRF-XANES for spatial resolved species analysis in a part of a working system is shown. • The spatial resolution enables differentiation of the oxidized interface from deeper layers. • With the analytical technique confocal micro-XRF-XANES 3D in-situ analyses of working systems are feasible. • The multidimensional and nondestructive analysis of Li-ion battery cathodes is shown. • The analysis will allow for a deeper understanding of processes at interfaces in battery science and others.

  20. Shear bond strength comparison between conventional porcelain fused to metal and new functionally graded dental restorations after thermal-mechanical cycling.

    Science.gov (United States)

    Henriques, B; Gonçalves, S; Soares, D; Silva, F S

    2012-09-01

    The aim of this study was to evaluate the effect of thermo-mechanical cycling on the metal-ceramic bond strength of conventional porcelain fused to metal restorations (PFM) and new functionally graded metal-ceramic dental restorations (FGMR). Two types of specimens were produced: PFM and FGMR specimens. PFM specimens were produced by conventional PFM technique. FGMR specimens were hot pressed and prepared with a metal/ceramic composite interlayer (50 M, vol%) at the metal-ceramic interface. They were manufactured and standardized in cylindrical format and then submitted to thermal (3000, 6000 and 12,000 cycles; between 5 °C and 60 °C; dwell time: 30s) and mechanical (25,000, 50,000 and 100,000 cycles under a load of 50 N; 1.6 Hz) cycling. The shear bond strength tests were performed in a universal testing machine (crosshead speed: 0.5mm/min), using a special device to concentrate the tension at the metal-ceramic interface and the load was applied until fracture. The metal-ceramic interfaces were examined with SEM/EDS prior to and after shear tests. The Young's modulus and hardness were measured across the interfaces of both types of specimens using nanoindentation tests. Data was analyzed with Shapiro-Wilk test to test the assumption of normality. The 2-way ANOVA was used to compare shear bond strength results (pshear bond strength results than PFM specimens, irrespective of fatigue conditions. Fatigue conditions significantly (pshear bond strength results. The analysis of surface fracture revealed adhesive fracture type for PFM specimens and mixed fracture type for FGMR specimens. Nanoindentation tests showed differences in mechanical properties measured across the metal-ceramic interface for the two types of specimens, namely Young's Modulus and hardness. This study showed significantly better performance of the new functionally graded restorations relative to conventional PFM restorations, under fatigue testing conditions and for the materials tested

  1. Measurement of the rate of hydrogen peroxide thermal decomposition in a shock tube using quantum cascade laser absorption near 7.7 μm

    KAUST Repository

    Sajid, Muhammad Bilal

    2013-10-24

    Hydrogen peroxide (H2O2) is formed during hydrocarbon combustion and controls the system reactivity under intermediate temperature conditions. Here, we measured the rate of hydrogen peroxide decomposition behind reflected shock waves using midinfrared absorption of H2O 2 near 7.7 μm. We performed the experiments in diluted H 2O2/Ar mixtures between 930 and 1235 K and at three different pressures (1, 2, and 10 atm). Under these conditions, the decay of hydrogen peroxide is sensitive only to the decomposition reaction rate, H 2O2 + M → 2OH + M (k1). The second-order rate coefficient at low pressures (1 and 2 atm) did not exhibit any pressure dependence, suggesting that the reaction was in the low-pressure limit. The rate data measured at 10 atm exhibited falloff behavior. The measured decomposition rates can be expressed in Arrhenius forms as follows: k1(1 and 2 atm)=10(16.29±0.12)× exp (-21993±301/T)(cm 3 mol -1s-1) k1(10 atm)=10(15.24±0.10)× exp (-19955±247/T)(cm 3 mol -1s-1) © 2013 Wiley Periodicals, Inc.

  2. Cellulose as an adhesion agent for the synthesis of lignin aerogel with strong mechanical performance, Sound-absorption and thermal Insulation

    Science.gov (United States)

    Wang, Chao; Xiong, Ye; Fan, Bitao; Yao, Qiufang; Wang, Hanwei; Jin, Chunde; Sun, Qingfeng

    2016-08-01

    The lignin aerogels that are both high porosity and compressibility would have promising implications for bioengineering field to sound-adsorption and damping materials; however, creating this aerogel had a challenge to adhesive lignin. Here we reported cellulose as green adhesion agent to synthesize the aerogels with strong mechanical performance. Our approach—straightforwardly dissolved in ionic liquids and simply regenerated in the deionized water—causes assembly of micro-and nanoscale and even molecule level of cellulose and lignin. The resulting lignin aerogels exhibit Young’s modulus up to 25.1 MPa, high-efficiency sound-adsorption and excellent thermal insulativity. The successful synthesis of this aerogels developed a path for lignin to an advanced utilization.

  3. Absorption edge shift, optical conductivity, and energy loss function of nano thermal-evaporated N-type anatase TiO2 films

    Science.gov (United States)

    El-Nahass, M. M.; Soliman, H. S.; El-Denglawey, A.

    2016-08-01

    Thermal evaporation technique was used to deposit 263 nm of TiO2 films on a quartz substrate. XRD of powder TiO2 reveals anatase phase characterized by nanostructure with crystallite size within a range of 4-10 nm. The increase in annealing temperature (400-800 °C) increases the crystallite size up to 43.1 nm. SEM micrograph shows grains of annealed TiO2 films within nanoscale. Optical gap, refractive index, dielectric constants, porosity, ratio of carrier concentration to the effective mass, dispersion, and oscillation energy were determined as well as optical conductivity and energy loss function. All parameters are affected by annealing. Current theoretical ideas were used to discuss the obtained results.

  4. Cellulose as an adhesion agent for the synthesis of lignin aerogel with strong mechanical performance, Sound-absorption and thermal Insulation.

    Science.gov (United States)

    Wang, Chao; Xiong, Ye; Fan, Bitao; Yao, Qiufang; Wang, Hanwei; Jin, Chunde; Sun, Qingfeng

    2016-08-26

    The lignin aerogels that are both high porosity and compressibility would have promising implications for bioengineering field to sound-adsorption and damping materials; however, creating this aerogel had a challenge to adhesive lignin. Here we reported cellulose as green adhesion agent to synthesize the aerogels with strong mechanical performance. Our approach-straightforwardly dissolved in ionic liquids and simply regenerated in the deionized water-causes assembly of micro-and nanoscale and even molecule level of cellulose and lignin. The resulting lignin aerogels exhibit Young's modulus up to 25.1 MPa, high-efficiency sound-adsorption and excellent thermal insulativity. The successful synthesis of this aerogels developed a path for lignin to an advanced utilization.

  5. Method development for the control determination of mercury in seafood by solid-sampling thermal decomposition amalgamation atomic absorption spectrometry (TDA AAS).

    Science.gov (United States)

    Torres, D P; Martins-Teixeira, M B; Silva, E F; Queiroz, H M

    2012-01-01

    A very simple and rapid method for the determination of total mercury in fish samples using the Direct Mercury Analyser DMA-80 was developed. In this system, a previously weighted portion of fresh fish is combusted and the released mercury is selectively trapped in a gold amalgamator. Upon heating, mercury is desorbed from the amalgamator, an atomic absorption measurement is performed and the mercury concentration is calculated. Some experimental parameters have been studied and optimised. In this study the sample mass was about 100.0 mg. The relative standard deviation was lower than 8.0% for all measurements of solid samples. Two calibration curves against aqueous standard solutions were prepared through the low linear range from 2.5 to 20.0 ng of Hg, and the high linear range from 25.0 to 200.0 ng of Hg, for which a correlation coefficient better than 0.997 was achieved, as well as a normal distribution of the residuals. Mercury reference solutions were prepared in 5.0% v/v nitric acid medium. Lyophilised fish tissues were also analysed; however, the additional procedure had no advantage over the direct analysis of the fresh fish, and additionally increased the total analytical process time. A fish tissue reference material, IAEA-407, was analysed and the mercury concentration was in agreement with the certified value, according to the t-test at a 95% confidence level. The limit of quantification (LOQ), based on a mercury-free sample, was 3.0 µg kg(-1). This LOQ is in accordance with performance criteria required by the Commission Regulation No. 333/2007. Simplicity and high efficiency, without the need for any sample preparation procedure, are some of the qualities of the proposed method.

  6. Low absorptance porcelain-on-aluminum coating

    Science.gov (United States)

    Leggett, H.

    1979-01-01

    Porcelain thermal-control coating for aluminum sheet and foil has solar absorptance of 0.22. Specially formulated coating absorptance is highly stable, changing only 0.03 after 1,000 hours of exposure to simulated sunlight and can be applied by standard commercial methods.

  7. Thermal Vacuum/Balance Test Results of Swift BAT with Loop Heat Pipe Thermal System

    Science.gov (United States)

    Choi, Michael K.

    2004-01-01

    The Swift Burst Alert Telescope (BAT) Detector Array is thermally well coupled to eight constant conductance heat pipes (CCHPs) embedded in the Detector Array Plate PAP), and two loop heat pipes (LHPs) transport heat from the CCHPs to a radiator. The CCHPs have ammonia as the working fluid and the LHPs have propylene as the working fluid. Precision heater controllers, which have adjustable set points in flight, are used to control the LHP compensation chamber and Detector Array xA1 ASIC temperatures. The radiator has AZ-Tek's AZW-LA-II low solar absorptance white paint as the thermal coating, and is located on the anti-sun side of the spacecraft. A thermal balance (T/B) test on the BAT was successfully completed. It validated that the thermal design satisfies the temperature requirements of the BAT in the flight thermal environments. Instrument level and observatory level thermal vacuum (TN) cycling tests of the BAT Detector Array by using the LHP thermal system were successfully completed. This paper presents the results of the T/B test and T N cycling tests.

  8. Influence of thermal radiation and heat generation/absorption on MHD heat transfer flow of a micropolar fluid past a wedge considering hall and ion slip currents

    Directory of Open Access Journals (Sweden)

    Uddin Ziya

    2014-01-01

    Full Text Available In this paper a numerical model is developed to examine the effect of thermal radiation on magnetohydrodynamic heat transfer flow of a micropolar fluid past a non-conducting wedge in presence of heat source/sink. In the model it is assumed that the fluid is viscous, incompressible and electrically conducting. The Hall and ion slip effects have also been taken into consideration. The model contains highly non-linear coupled partial differential equations which have been converted into ordinary differential equation by using the similarity transformations. These equations are then solved numerically by Shooting technique along with the Runge-Kutta-Fehlberg integration scheme for entire range of parameters with appropriate boundary conditions. The effects of various parameters involved in the problem have been studied with the help of graphs. Numerical values of skin friction coefficients and Nusselt number are presented in tabular form. The results showed that the micropolar fluids are better to reduce local skin drag as compared to Newtonian fluids and the presence of heat sink increases the heat transfer rate.

  9. Absorption of some mineral salts by root system of different woody species and accumulation over a whole vegetative cycle (1963); Absorption de quelques sels par l'appareil radiculaire de differentes especes ligneuses et accumulation au cours d'un cycle vegetatif complet (1963)

    Energy Technology Data Exchange (ETDEWEB)

    Gagnaire, J.; Gerard, J.M. [Commisariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1963-07-01

    The concentration power of plant tissues and the translocation speed of mineral salts are considerably varying with the absorbed salt, the botanical species, the considered tissue and the part of the vegetative cycle. In Grenoble, with Picea excelsa, the 'true dormancy' is short (half-november, end of december). It is accompanied by a pre-dormancy period (October, half-november) and a post dormancy period (January, february, march). In vegetative period, Picea excelsa leaves are less concentrating mineral salt than Acer campestris leaves (coefficient 2 for calcium - 3 for phosphates) and Populus nigra leaves (coefficient 3 for calcium, coefficient 5 for phosphates). (author) [French] Le pouvoir de concentration de tissus vegetaux, et particulierement la vitesse de transport des sels mineraux varient beaucoup selon le sel mineral absorbe, l'espece vegetale, le tissu considere ainsi que la periode du cycle vegetatif. A Grenoble, pour les epiceas 'la dormance veritable' est courte (mi-novembre, fin decembre). Elle est encadree par des periodes de pre-dormance (octobre, mi-novembre) et de post-dormance (janvier, fevrier, mars). Pendant la periode vegetative, le pouvoir de concentration de sels mineraux des aiguilles d'epiceas est plus faible que celui des feuilles d'erables (coefficient 2 pour le calcium - coefficient 3 pour les phosphates) ou que celui des feuilles de peupliers (coefficient 3 pour le calcium - coefficient 5 pour les phosphates). (auteur)

  10. Comparing the sustainability impacts of solar thermal and natural gas combined cycle for electricity production in Mexico: Accounting for decision makers' priorities

    Science.gov (United States)

    Rodríguez-Serrano, Irene; Caldés, Natalia; Oltra, Christian; Sala, Roser

    2017-06-01

    The aim of this paper is to conduct a comprehensive sustainability assessment of the electricity generation with two alternative electricity generation technologies by estimating its economic, environmental and social impacts through the "Framework for Integrated Sustainability Assessment" (FISA). Based on a Multiregional Input Output (MRIO) model linked to a social risk database (Social Hotspot Database), the framework accounts for up to fifteen impacts across the three sustainability pillars along the supply chain of the electricity production from Solar Thermal Electricity (STE) and Natural Gas Combined Cycle (NGCC) technologies in Mexico. Except for value creation, results show larger negative impacts for NGCC, particularly in the environmental pillar. Next, these impacts are transformed into "Aggregated Sustainability Endpoints" (ASE points) as a way to support the decision making in selecting the best sustainable project. ASE points obtained are later compared to the resulting points weighted by the reported priorities of Mexican decision makers in the energy sector obtained from a questionnaire survey. The comparison shows that NGCC achieves a 1.94 times worse negative score than STE, but after incorporating decision makerś priorities, the ratio increases to 2.06 due to the relevance given to environmental impacts such as photochemical oxidants formation and climate change potential, as well as social risks like human rights risks.

  11. Resistance to radiation and concretes thermal cycles for conditioning of spent radioactive sources; Resistencia a la irradiacion y ciclos termicos de concretos para acondicionamiento de fuentes radiactivas gastadas

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez N, M.; Monroy G, F.; Gonzalez D, R. C.; Corona P, I. J.; Ortiz A, G., E-mail: fabiola.monroy@inin.gob.mx [ININ, Carretera Mexico-Toluca s/n, 52750 Ocoyoacac, Estado de Mexico (Mexico)

    2014-10-15

    In order to know the concrete type most suitable for use as a matrix of conditioning of spent radioactive sources, concrete test tubes using 4 different types of cement were prepared: CPC 30-Rs Extra, CPC 30-R Impercem, CPC 30-R Rs and CPC 30-R with two gravel sizes >30 mm and <10 mm. The concrete test tubes were subjected to testing compressive strength after 28 days of hardening and after being irradiated and subjected to thermal cycles. Subsequently they were characterized by X-ray diffraction and scanning electron microscopy, in order to evaluate whether these concretes accredited the tests set by the NOM-019-Nucl-1995. The results show that the compressive strength of the hardened concretes to 28 days presents values between 36 and 25 MPa; applying irradiation the resistance may decrease to 30% of its original strength; and if subjected to high and low temperatures the ettringite formation also causes a decrease in resistance. The results show that concretes made from cement Impercem, Cruz Azul with gravel <10 mm comply with the provisions of standard and they can be used for conditioning of spent radioactive sources. (Author)

  12. Life cycle inventory analysis of regenerative thermal oxidation of air emissions from oriented strand board facilities in Minnesota - a perspective of global climate change

    Energy Technology Data Exchange (ETDEWEB)

    Nicholson, W.J. [Potlatch Corp., San Francisco, CA (United States)

    1997-12-31

    Life cycle inventory analysis has been applied to the prospective operation of regenerative thermal oxidation (RTO) technology at oriented strand board plants at Bemidji (Line 1) and Cook, Minnesota. The net system destruction of VOC`s and carbon monoxide, and at Cook a small quantity of particulate, has a very high environmental price in terms of energy and water use, global warming potential, sulfur and nitrogen oxide emissions, solids discharged to water, and solid waste deposited in landfills. The benefit of VOC destruction is identified as minor in terms of ground level ozone at best and possibly slightly detrimental. Recognition of environmental tradeoffs associated with proposed system changes is critical to sound decision-making. There are more conventional ways to address carbon monoxide emissions than combustion in RTO`s. In an environment in which global warming is a concern, fuel supplemental combustion for environmental control does not appear warranted. Consideration of non-combustion approaches to address air emission issues at the two operations is recommended. 1 ref., 5 tabs.

  13. Effect of Zr Addition on the Microstructure and Toughness of Coarse-Grained Heat-Affected Zone with High-Heat Input Welding Thermal Cycle in Low-Carbon Steel

    Science.gov (United States)

    Shi, Ming-hao; Yuan, Xiao-guang; Huang, Hong-jun; Zhang, Si

    2017-07-01

    Microstructures and toughness of coarse-grained heat-affected zone (CGHAZ) with high-heat input welding thermal cycle in Zr-containing and Zr-free low-carbon steel were investigated by means of welding thermal cycle simulation. The specimens were subjected to a welding thermal cycle with heat inputs of 100, 400, and 800 kJ cm-1 at peak temperature of 1673 K (1400 °C) using a thermal simulator. The results indicate that excellent impact toughness at the CGHAZ was obtained in Zr-containing steel. The Zr oxide is responsible for AF transformation, providing the nucleation site for the formation AF, promoting the nucleation of AF on the multi-component inclusions. High fraction of acicular ferrite (AF) appears in Zr-containing steel, acting as an obstacle to cleavage propagation due to its high-angle grain boundary. The morphology of M-A constituents plays a key role in impact toughness of CGHAZ. Large M-A constituents with lath form can assist the micro-crack initiation and seriously decrease the crack initiation energy. The relationship of AF transformation and M-A constituents was discussed in detail.

  14. Ammonia and ammonium hydroxide sensors for ammonia/water absorption machines: Literature review and data compilation

    Energy Technology Data Exchange (ETDEWEB)

    Anheier, N.C. Jr.; McDonald, C.E.; Cuta, J.M.; Cuta, F.M.; Olsen, K.B.

    1995-05-01

    This report describes an evaluation of various sensing techniques for determining the ammonia concentration in the working fluid of ammonia/water absorption cycle systems. The purpose of this work was to determine if any existing sensor technology or instrumentation could provide an accurate, reliable, and cost-effective continuous measure of ammonia concentration in water. The resulting information will be used for design optimization and cycle control in an ammonia-absorption heat pump. PNL researchers evaluated each sensing technology against a set of general requirements characterizing the potential operating conditions within the absorption cycle. The criteria included the physical constraints for in situ operation, sensor characteristics, and sensor application. PNL performed an extensive literature search, which uncovered several promising sensing technologies that might be applicable to this problem. Sixty-two references were investigated, and 33 commercial vendors were identified as having ammonia sensors. The technologies for ammonia sensing are acoustic wave, refractive index, electrode, thermal, ion-selective field-effect transistor (ISFET), electrical conductivity, pH/colormetric, and optical absorption. Based on information acquired in the literature search, PNL recommends that follow-on activities focus on ISFET devices and a fiber optic evanescent sensor with a colormetric indicator. The ISFET and fiber optic evanescent sensor are inherently microminiature and capable of in situ measurements. Further, both techniques have been demonstrated selective to the ammonium ion (NH{sub 4}{sup +}). The primary issue remaining is how to make the sensors sufficiently corrosion-resistant to be useful in practice.

  15. Coupled dual loop absorption heat pump

    Science.gov (United States)

    Sarkisian, Paul H.; Reimann, Robert C.; Biermann, Wendell J.

    1985-01-01

    A coupled dual loop absorption system which utilizes two separate complete loops. Each individual loop operates at three temperatures and two pressures. This low temperature loop absorber and condenser are thermally coupled to the high temperature loop evaporator, and the high temperature loop condenser and absorber are thermally coupled to the low temperature generator.

  16. Warming, euxinia and sea level rise during the Paleocene-Eocene Thermal Maximum on the Gulf Coastal Plain: implications for ocean oxygenation and nutrient cycling

    Science.gov (United States)

    Sluijs, A.; van Roij, L.; Harrington, G. J.; Schouten, S.; Sessa, J. A.; LeVay, L. J.; Reichart, G.-J.; Slomp, C. P.

    2014-07-01

    The Paleocene-Eocene Thermal Maximum (PETM, ~ 56 Ma) was a ~ 200 kyr episode of global warming, associated with massive injections of 13C-depleted carbon into the ocean-atmosphere system. Although climate change during the PETM is relatively well constrained, effects on marine oxygen concentrations and nutrient cycling remain largely unclear. We identify the PETM in a sediment core from the US margin of the Gulf of Mexico. Biomarker-based paleotemperature proxies (methylation of branched tetraether-cyclization of branched tetraether (MBT-CBT) and TEX86) indicate that continental air and sea surface temperatures warmed from 27-29 to ~ 35 °C, although variations in the relative abundances of terrestrial and marine biomarkers may have influenced these estimates. Vegetation changes, as recorded from pollen assemblages, support this warming. The PETM is bracketed by two unconformities. It overlies Paleocene silt- and mudstones and is rich in angular (thus in situ produced; autochthonous) glauconite grains, which indicate sedimentary condensation. A drop in the relative abundance of terrestrial organic matter and changes in the dinoflagellate cyst assemblages suggest that rising sea level shifted the deposition of terrigenous material landward. This is consistent with previous findings of eustatic sea level rise during the PETM. Regionally, the attribution of the glauconite-rich unit to the PETM implicates the dating of a primate fossil, argued to represent the oldest North American specimen on record. The biomarker isorenieratene within the PETM indicates that euxinic photic zone conditions developed, likely seasonally, along the Gulf Coastal Plain. A global data compilation indicates that O2 concentrations dropped in all ocean basins in response to warming, hydrological change, and carbon cycle feedbacks. This culminated in (seasonal) anoxia along many continental margins, analogous to modern trends. Seafloor deoxygenation and widespread (seasonal) anoxia likely

  17. Absorption-heat-pump system

    Science.gov (United States)

    Grossman, G.; Perez-Blanco, H.

    1983-06-16

    An improvement in an absorption heat pump cycle is obtained by adding adiabatic absorption and desorption steps to the absorber and desorber of the system. The adiabatic processes make it possible to obtain the highest temperature in the absorber before any heat is removed from it and the lowest temperature in the desorber before heat is added to it, allowing for efficient utilization of the thermodynamic availability of the heat supply stream. The improved system can operate with a larger difference between high and low working fluid concentrations, less circulation losses, and more efficient heat exchange than a conventional system.

  18. Influence of homo-buffer layers and post-deposition rapid thermal annealing upon atomic layer deposition grown ZnO at 100 °C with three-pulsed precursors per growth cycle

    Science.gov (United States)

    Cheng, Yung-Chen; Yuan, Kai-Yun; Chen, Miin-Jang

    2017-10-01

    ZnO main epilayers are deposited with three-pulsed precursors in every growth cycle at 100 °C on various thicknesses of 300 °C-grown homo-buffer layers by atomic layer deposition (ALD) on sapphire substrate. Samples are treated without and with post-deposition rapid thermal annealing (RTA). Two different annealing temperatures 300 and 1000 °C are utilized in the ambience of oxygen for 5 min. Extremely low background electron concentration 8.4 × 1014 cm-3, high electron mobility 62.1 cm2/V s, and pronounced enhancement of near bandgap edge photoluminescence (PL) are achieved for ZnO main epilayer with sufficient thickness of buffer layer (200 ALD cycles) and post-deposition RTA at 1000 °C. Effective block and remove of thermally unstable mobile defects and other crystal lattice imperfections are the agents of quality promotion of ZnO thin film.

  19. Improving the refueling cycle of a WWER-1000 using cuckoo search method and thermal-neutronic coupling of PARCS v2.7, COBRA-EN and WIMSD-5B codes

    Energy Technology Data Exchange (ETDEWEB)

    Yarizadeh-Beneh, M.; Mazaheri-Beni, H.; Poursalehi, N., E-mail: n_poursalehi@sbu.ac.ir

    2016-12-15

    Highlights: • The cuckoo search algorithm is applied to the loading pattern optimization of a nuclear reactor core. • Calculations during the cycle show a good agreement between results and reference for the original LP. • Results indicate the efficient performance of cuckoo search approach coupled with thermal-neutronic solvers. • Neutronic parameters of proposed core pattern are improved relative to original core pattern. - Abstract: The fuel loading pattern optimization is an important process in the refueling design of a nuclear reactor core. Also the analysis of reactor core performance during the operation cycle can be a significant step in the core loading pattern optimization (LPO). In this work, for the first time, a new method i.e. cuckoo search algorithm (CS) has been applied to the fuel loading pattern design of Bushehr WWER-1000 core. In this regard, two objectives have been chosen for finding the best configuration including the improvement of operation cycle length associated with flattening the radial power distribution of fuel assemblies. The core pattern optimization has been performed by coupling the CS algorithm to thermal-neutronic codes including PARCS v2.7, COBRA-EN and WIMSD-5B for earning desired parameters along the operation cycle. The calculations have been done for the beginning of cycle (BOC) to the end of cycle (EOC) states. According to numerical results, the longer operation cycle for the semi-optimized loading pattern has been achieved along with less power peaking factor (PPF) in comparison to the original core pattern of Bushehr WWER-1000. Gained results confirm the efficient and suitable performance of the developed program and also the introduced CS method in the LPO of a nuclear WWER type.

  20. Carbon Dioxide Absorption Heat Pump

    Science.gov (United States)

    Jones, Jack A. (Inventor)

    2002-01-01

    A carbon dioxide absorption heat pump cycle is disclosed using a high pressure stage and a super-critical cooling stage to provide a non-toxic system. Using carbon dioxide gas as the working fluid in the system, the present invention desorbs the CO2 from an absorbent and cools the gas in the super-critical state to deliver heat thereby. The cooled CO2 gas is then expanded thereby providing cooling and is returned to an absorber for further cycling. Strategic use of heat exchangers can increase the efficiency and performance of the system.

  1. Hierarchical Decomposition Thermodynamic Approach for the Study of Solar Absorption Refrigerator Performance

    Directory of Open Access Journals (Sweden)

    Emma Berrich Betouche

    2016-03-01

    Full Text Available A thermodynamic approach based on the hierarchical decomposition which is usually used in mechanical structure engineering is proposed. The methodology is applied to an absorption refrigeration cycle. Thus, a thermodynamic analysis of the performances on solar absorption refrigerators is presented. Under the hypothesis of an endoreversible model, the effects of the generator, the solar concentrator and the solar converter temperatures, on the coefficient of performance (COP, are presented and discussed. In fact, the coefficient of performance variations, according to the ratio of the heat transfer areas of the high temperature part (the thermal engine 2 Ah and the heat transfer areas of the low temperature part (the thermal receptor Ar variations, are studied in this paper. For low values of the heat-transfer areas of the high temperature part and relatively important values of heat-transfer areas of the low temperature part as for example Ah equal to 30% of Ar, the coefficient of performance is relatively important (approximately equal to 65%. For an equal-area distribution corresponding to an area ratio Ah/Ar of 50%, the COP is approximately equal to 35%. The originality of this deduction is that it allows a conceptual study of the solar absorption cycle.

  2. Performance Degradation of Thermal Parameters during Cycle Ageing of High Energy Density Ni-Mn-Co based Lithium-Ion Battery Cells

    DEFF Research Database (Denmark)

    Stanciu, Tiberiu; Stroe, Daniel Loan; Swierczynski, Maciej Jozef

    2016-01-01

    The accelerated demand for electrifying the transportation sector, coupled with the continuous improvement of rechargeable batteries’ characteristics, have made modern high-energy Lithium-ion (Li-ion) batteries the standard choice for hybrid and electric vehicles (EVs). Consequently, Li......-ion batteries’ electrochemical and thermal characteristics are very important topics, putting them at the forefront of the research. Along with the electrical performance of Li-ion battery cells, their thermal behavior needs to be accurately predicted during operation and over the lifespan of the application...... as well, since the thermal management of the battery is crucial for the safety of the EV driver. Moreover, the thermal management system can significantly lower the degradation rate of the battery pack and thus reduce costs. In this paper, the thermal characterization of a commercially available Nickel...

  3. Thermal energy transformer

    Science.gov (United States)

    Berdahl, C. M.; Thiele, C. L. (Inventor)

    1979-01-01

    For use in combination with a heat engine, a thermal energy transformer is presented. It is comprised of a flux receiver having a first wall defining therein a radiation absorption cavity for converting solar flux to thermal energy, and a second wall defining an energy transfer wall for the heat engine. There is a heat pipe chamber interposed between the first and second walls having a working fluid disposed within the chamber and a wick lining the chamber for conducting the working fluid from the second wall to the first wall. Thermal energy is transferred from the radiation absorption cavity to the heat engine.

  4. Thermal Hyperbolic Metamaterials

    OpenAIRE

    Guo, Yu; Jacob, Zubin

    2013-01-01

    We explore the near-field radiative thermal energy transfer properties of hyperbolic metamaterials. The presence of unique electromagnetic states in a broad bandwidth leads to super-planckian thermal energy transfer between metamaterials separated by a nano-gap. We consider practical phonon-polaritonic metamaterials for thermal engineering in the mid-infrared range and show that the effect exists in spite of the losses, absorption and finite unit cell size. For thermophotovoltaic energy conve...

  5. Theoretical thermodynamics analysis of cooling cycle bu advanced gas absorption using solar energy; Analisis teorico-experimental de un ciclo de refrigeracion por absorcion avanzado gax, operando con energia solar

    Energy Technology Data Exchange (ETDEWEB)

    Gomez, V. E.; Vidal, A. S.; Garcia, C. A.; Garcia-Valladares, O.; Best, R. B.; Hernandez, J. G.; Velazquez, N. L.

    2004-07-01

    In this article a solar system of refrigeration by absorption with heat exchange generator absorber (GAX) was analyzed. A theoretical thermodynamic analysis of the energetic behavior of the GAX absorption system was made. Experimental results were obtained with generation temperatures of 190 and 220 C, the evaporation temperature was set at 9 C and temperatures of cooling fluids (air and water) were set at 30 C and 28 C, respectively. It was possible to appreciate that the GAX effect decrease whether absorber, type falling film, is operated in option of parallel flow and it was increased when the absorber was operated in option of counterflow. (Author)

  6. Warm Water Entrainment Impacts and Environmental Life Cycle Assessment of a Proposed Ocean Thermal Energy Conversion Pilot Plant Offshore Oahu, Hawaii

    Science.gov (United States)

    Hauer, Whitney Blanchard

    Ocean thermal energy conversion (OTEC) is a marine renewable energy technology that uses the temperature difference of large volumes of cold deep and warm surface seawater in tropical regions to generate electricity. One anticipated environmental impact of OTEC operations is the entrainment and subsequent mortality of ichthyoplankton (fish eggs and larvae) from the withdrawal of cold and warm seawater. The potential ichthyoplankton loss from the warm water intake was estimated for a proposed 10 MW OTEC pilot plant offshore Oahu, HI based on ambient vertical distribution data. The estimated losses due to entrainment from the warm water intake were 8.418E+02 larvae/1000 m3, 3.26E+06 larvae/day, and 1.19E+09 larvae/year. The potential entrained larvae/year is 1.86 X greater than at the Kahe Generating Station (Kapolei, HI), a 582 MW oil-fired power plant. Extrapolating to age-1 equivalence (9.2E+02 and 2.9E+02 yellowfin and skipjack tuna, respectively), the estimated yearly losses from warm water entrainment of yellowfin and skipjack tuna fish eggs and larvae represent 0.25-0.26 % and 0.09-0.11 % of Hawaii's commercial yellowfin and skipjack tuna industry in 2011 and 2012. An environmental life cycle assessment (LCA) was developed for the proposed OTEC plant operating for 20 and 40 years with availability factors of 0.85, 0.95, and 1.0 to determine the global warming potential (GWP) and cumulative energy demand (CED) impacts. For a 20 year operational OTEC plant, the GWP, CED, energy return on investment (EROI), and energy payback time (EPBT) ranged from 0.047 to 0.055 kg CO2eq/kWh, 0.678 to 0.798 MJ/kWh, 4.51 to 5.31 (unitless), and 3.77 to 4.43 years, respectively. For a 40 year operational OTEC plant, the GWP, CED, EROI, and EBPT ranged from 0.036 to 0.043 kg CO2eq/kWh, 0.527 to 0.620 MJ/kWh, 5.81 to 6.83 (unitless), and 5.85 to 6.89 years, respectively. The GWP impacts are within the range of renewable energy technologies and less than conventional electricity

  7. Simulation of an absorption cooling system

    Energy Technology Data Exchange (ETDEWEB)

    Egrican, N. (Istanbul Technical Univ. (TR). Dept. of Mechanical Engineering); Yigit, A. (Uludag Univ., Bursa (TR). Faculty of Engineering)

    1992-06-01

    We describe a finite difference solution for combined heat and mass transfer on vapor absorption into a laminar liquid film. Heat- and mass-transfer coefficients are determined by calculating temperature and concentration variations at the film. A modular computer program has been developed for absorption systems to simulate various cycle configurations. The influence of component temperatures and heat-exchanger effectiveness on cooling coefficients of performance and component heat-transfer rates has been investigated to define optimum operating conditions. (author).

  8. Elimination of the induced malfunctions and use of dynamic prognosis in a thermodynamic diagnosis system of the thermal cycling; Eliminacao das malfuncoes induzidas e utilizacao do prognostico dinamico em sistemas de diagnostico termodinamico de ciclos termicos

    Energy Technology Data Exchange (ETDEWEB)

    Silva, J.A.M.; Venturini, O.J.; Lora, E.E.S. [Universidade Federal de Itajuba (NEST/IEM/UNIFEI), MG (Brazil). Inst. de Engenharia Mecanica. Nucleo de Excelencia em Geracao Termeletrica e Distribuida], Emails: juliomendes@unifei.edu.br, osvaldo@unifei.edu.br, electo@unifei.edu.br

    2009-07-01

    The search for more efficient thermal cycles has led a growing complexity of these cycles and therefore increased the inter-relationships between the thermodynamic components. This complexity is further enhanced with the over time, due to the occurrence of both natural as early degradation in a more or less degree, of all plant components. Several methodologies have been proposed for creating system for diagnostic / prognostic with the objective to detect these degradations (defects) and quantify the gain that can be obtained in the performance indicators of thermal cycles (usually specific fuel consumption and power net) by the elimination of anomalies. Two points have been emphasized as the most difficult in the development of such systems: the distinction between the performance variation of the components due only to the point of operation outside of these project components, caused by the presence of abnormality in another component (induced malfunction) and a decrease in the performance due to the presence of anomalies in the component itself (intrinsic malfunction). The second difficulty is the quantification of the effects induced by the elimination of each of the present anomalies. This work makes use of the method of reconciliation and using individual models of each component to predict unusual behavior of the same design point. The comparison of data from the system plant information, relating to the current state and data from the models, is used to detect anomalies. The methodology is explained in detail and an application of it in a Rankine cycle is used to well understand, especially in parts for the elimination of induced malfunctions, and related to the induced changes by the elimination of each one of the anomalies.

  9. Electro-thermal Modeling for Junction Temperature Cycling-Based Lifetime Prediction of a Press-Pack IGBT 3L-NPC-VSC Applied to Large Wind Turbines

    DEFF Research Database (Denmark)

    Senturk, Osman Selcuk; Munk-Nielsen, Stig; Teodorescu, Remus

    2011-01-01

    Reliability is a critical criterion for multi-MW wind turbines, which are being employed with increasing numbers in wind power plants, since they operate under harsh conditions and have high maintenance cost due to their remote locations. In this study, the wind turbine grid-side converter...... prediction, the converter electro-thermal model including electrical, power loss, and dynamical thermal models is developed with the main focus on the thermal modeling regarding converter topology, switch technology, and physical structure. Moreover, these models are simplified for their practical...... implementation in computation platforms. Finally, the converter lifetimes for wind power profiles are predicted using the IGBT lifetime model available. Hence, the developed electrothermal model’s suitability for the lifetime predictions is shown....

  10. D-xylose absorption

    Science.gov (United States)

    ... this page: //medlineplus.gov/ency/article/003606.htm D-xylose absorption To use the sharing features on this page, please enable JavaScript. D-xylose absorption is a laboratory test to determine ...

  11. Phytases for Improved Iron Absorption

    DEFF Research Database (Denmark)

    Nielsen, Anne Veller Friis; Nyffenegger, Christian; Meyer, Anne S.

    2014-01-01

    Microbial phytases (EC 3.1.3.8) catalyse dephosphorylation of phytic acid, which is the primary storage compound for phosphorous in cereal kernels. The negatively charged phosphates in phytic acid chelate iron (Fe3+) and thus retards iron bioavailability in humans 1. Supplementation of microbial...... phytase can improve iron absorption from cereal-based diets 2. In order for phytase to catalyse iron release in vivo the phytase must be robust to low pH and proteolysis in the gastric ventricle. Our work has compared the robustness of five different microbial phytases, evaluating thermal stability...

  12. Effects of La2O3 content and particle size on the long-term stability and thermal cycling property of La2O3-dispersed SUS430 alloys for SOFC interconnect materials

    Science.gov (United States)

    Lee, Jung-Won; Mehran, Muhammad Taqi; Song, Rak-Hyun; Lee, Seung-Bok; Lee, Jong-Won; Lim, Tak-Hyoung; Park, Seok-Joo; Hong, Jong-Eun; Shim, Joon-Hyung

    2017-11-01

    We developed oxide-dispersed alloys as interconnect materials for a solid oxide fuel cell by adding La2O3 to SUS430 ferritic steels. For this purpose, we prepared two types of La2O3 with different particle sizes and added different amounts of La2O3 to SUS430 powder. Then, we mixed the powders using a high energy ball mill, so that nano-sized as well as micro-sized oxide particles were able to mix uniformly with the SUS430 powders. After preparing hexahedral green samples using uni-axial and cold isostatic presses, we were finally able to obtain oxide-dispersed alloys having high relative densities after firing at 1,400 °C under hydrogen atmosphere. The nano-sized La2O3 dispersed alloys showed properties superior to those of micro-sized dispersed alloys in terms of long-term stability and thermal cycling. Moreover, we determined the optimum amounts of added La2O3. Finally we were able to develop a new oxide-dispersed alloy showing excellent properties of low area specific resistance (16.23 mΩ cm2) after 1000 h at 800 °C, and no degradation after 10 iterations of thermal cycling under oxidizing atmosphere.

  13. Weld heat-affected zone in Ti-6Al-4V alloys. Part 1: Computer simulation of the effect of weld variables on the thermal cycles in the HAZ

    Energy Technology Data Exchange (ETDEWEB)

    Shah, A.K. [Naval Dockyard, Bombay (India). Naval Chemical and Metallurgical Lab.; Kulkarni, S.D.; Gopinathan, V. [Indian Inst. of Technology, Bombay (India). Dept. of Metallurgical Engineering; Krishnan, R. [Gas Turbine Research Establishment, Bangalore (India)

    1995-09-01

    The weld thermal cycles encountered in the HAZ of titanium alloys have been characterized using modified Rosenthal equations. The results are shown in the form of axonometric plots depicting the effect of two weld variables keeping the other variables fixed. Computer simulation results show that the heat input and the plate thickness are the major variables affecting the thermal cycles in the HAZ. The effects of changes in welding speed are reflecting in the variation in the heat input. The electrode radius has minimal effect and can be termed as the minor variable. Preheat or interpass temperatures have an intermediate effect. An increase in electrode radius or decrease in plate thickness requires large apparent displacement of the heat source above the plate surface to be incorporated in the analytical solutions. The melt pool width increases sharply with an increase in the heat input (a/v) or a decrease in plate thickness (d); however, preheat temperature (T{sub 0}) has negligible effect. The effect of weld variables on the effective heat input is also similar. The t{sub 8/5} parameter increases sharply with reducing plate thickness or increasing heat input.

  14. Performance Evaluation of a HP/ORC (Heat Pump/Organic Rankine Cycle) System with Optimal Control of Sensible Thermal Storage

    DEFF Research Database (Denmark)

    Carmo, Carolina; Nielsen, Mads P.; Elmegaard, Brian

    2016-01-01

    come to contribute to the integration of intermittent renewables.This paper describes an innovative concept that consists of the addition of an Organic Rankine Cycle (ORC) toa combined solar system coupled to a ground-source heat pump (HP) in a single-family building. The ORC enables the use of solar...

  15. Design and optimization for vehicle driving cycle of rare-earth-free SynRM based on coupled lumped thermal and magnetic networks

    OpenAIRE

    López Torres, Carlos; García Espinosa, Antonio; Riba Ruiz, Jordi-Roger; Romeral Martínez, José Luis

    2017-01-01

    This work presents a range optimization of a SynRM (synchronous reluctance motor) and a PMaSynRM (permanent-magnet-assisted synchronous reluctance motor) according to a standard driving cycle, and the solutions obtained are compared. The proposed approach avoids the use of finite element analysis (FEA) during the optimization process, thus greatly reducing the time required to obtain the optimal solution. The paper validates the optimal motors obtained in different domains, since the methodol...

  16. Solar Absorption Refrigeration System for Air-Conditioning of a Classroom Building in Northern India

    Science.gov (United States)

    Agrawal, Tanmay; Varun; Kumar, Anoop

    2015-10-01

    Air-conditioning is a basic tool to provide human thermal comfort in a building space. The primary aim of the present work is to design an air-conditioning system based on vapour absorption cycle that utilizes a renewable energy source for its operation. The building under consideration is a classroom of dimensions 18.5 m × 13 m × 4.5 m located in Hamirpur district of Himachal Pradesh in India. For this purpose, cooling load of the building was calculated first by using cooling load temperature difference method to estimate cooling capacity of the air-conditioning system. Coefficient of performance of the refrigeration system was computed for various values of strong and weak solution concentration. In this work, a solar collector is also designed to provide required amount of heat energy by the absorption system. This heat energy is taken from solar energy which makes this system eco-friendly and sustainable. A computer program was written in MATLAB to calculate the design parameters. Results were obtained for various values of solution concentrations throughout the year. Cost analysis has also been carried out to compare absorption refrigeration system with conventional vapour compression cycle based air-conditioners.

  17. Effect of thermal and thermo-mechanical cycling on the boron segregation behavior in the coarse-grained heat-affected zone of low-alloy steel

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Sanghoon; Kang, Yongjoon; Lee, Changhee, E-mail: chlee@hanyang.ac.kr

    2016-06-15

    The boron segregation behavior in the coarse-grained heat-affected zone (CGHAZ) of 10 ppm boron-added low-alloy steel during the welding cycle was investigated by taking the changes in the microstructure and hardness into account. Various CGHAZs were simulated with a Gleeble system as a function of the heat input and external stress, and the boron segregation behavior was analyzed by secondary ion mass spectrometry (SIMS) and particle tracking autoradiography (PTA). The segregation of boron was found to initially increase, and then decrease with an increase in the heat input. This is believed to be due to the back-diffusion of boron with an increase in the exposure time at high temperature after non-equilibrium grain boundary segregation. The grain boundary segregation of boron could be decreased by an external stress applied during the welding cycle. Such behavior may be due to an increase in the grain boundary area as a result of the grain size reduction induced by the external stress. - Highlights: • Boron segregation behavior in the CGHAZ of low-alloy steel during a welding cycle was investigated. • Various CGHAZs were simulated with a Gleeble system as a function of the heat input and external stress. • Boron segregation behavior was analyzed using SIMS and PTA techniques.

  18. Absorptive capacity and smart companies

    Directory of Open Access Journals (Sweden)

    Patricia Moro González

    2014-12-01

    Full Text Available Purpose: The current competitive environment is substantially modifying the organizations’ learning processes due to a global increase of available information allowing this to be transformed into knowledge. This opportunity has been exploited since the nineties by the tools of “Business Analytics” and “Business Intelligence” but, nevertheless, being integrated in the study of new organizational capacities engaged in the process of creating intelligence inside organizations is still an outstanding task. The review of the concept of absorptive capacity and a detailed study from the perspective of this new reality will be the main objective of study of this paper.Design/methodology/approach: By comparing classical absorptive capacity and absorptive capacity from the point of view of information management tools in each one of the three stages of the organizational learning cycle, some gaps of the former are overcome/fulfilled. The academic/bibliographical references provided in this paper have been obtained from ISI web of knowledge, Scopus and Dialnet data bases, supporting the state of affairs on absorptive capacity and thereafter filtering by "Business Intelligence" and "Business Analytics". Specialized websites and Business Schools` Publications there have also been included, crowning the content on information management tools used that are currently used in the strategic consulting.Findings: Our contribution to the literature is the development of "smart absorptive capacity". This is a new capacity emerging from the reformulation of the classical concept of absorptive capacity wherein some aspects of its definition that might have been omitted are emphasized. The result of this new approach is the creation of a new Theoretical Model of Organizational Intelligence, which aims to explain, within the framework of the Resources and Capabilities Theory, the competitive advantage achieved by the so-called smart companies

  19. Sprayable Phase Change Coating Thermal Protection Material

    Science.gov (United States)

    Richardson, Rod W.; Hayes, Paul W.; Kaul, Raj

    2005-01-01

    NASA has expressed a need for reusable, environmentally friendly, phase change coating that is capable of withstanding the heat loads that have historically required an ablative thermal insulation. The Space Shuttle Program currently relies on ablative materials for thermal protection. The problem with an ablative insulation is that, by design, the material ablates away, in fulfilling its function of cooling the underlying substrate, thus preventing the insulation from being reused from flight to flight. The present generation of environmentally friendly, sprayable, ablative thermal insulation (MCC-l); currently use on the Space Shuttle SRBs, is very close to being a reusable insulation system. In actual flight conditions, as confirmed by the post-flight inspections of the SRBs, very little of the material ablates. Multi-flight thermal insulation use has not been qualified for the Space Shuttle. The gap that would have to be overcome in order to implement a reusable Phase Change Coating (PCC) is not unmanageable. PCC could be applied robotically with a spray process utilizing phase change material as filler to yield material of even higher strength and reliability as compared to MCC-1. The PCC filled coatings have also demonstrated potential as cryogenic thermal coatings. In experimental thermal tests, a thin application of PCC has provided the same thermal protection as a much thicker and heavier application of a traditional ablative thermal insulation. In addition, tests have shown that the structural integrity of the coating has been maintained and phase change performance after several aero-thermal cycles was not affected. Experimental tests have also shown that, unlike traditional ablative thermal insulations, PCC would not require an environmental seal coat, which has historically been required to prevent moisture absorption by the thermal insulation, prevent environmental degradation, and to improve the optical and aerodynamic properties. In order to reduce

  20. [Study on lead absorption in pumpkin by atomic absorption spectrophotometry].

    Science.gov (United States)

    Li, Zhen-Xia; Sun, Yong-Dong; Chen, Bi-Hua; Li, Xin-Zheng

    2008-07-01

    A study was carried out on the characteristic of lead absorption in pumpkin via atomic absorption spectrophotometer. The results showed that lead absorption amount in pumpkin increased with time, but the absorption rate decreased with time; And the lead absorption amount reached the peak in pH 7. Lead and cadmium have similar characteristic of absorption in pumpkin.

  1. Coldness distribution by stabilized ice slurries. Study of the behaviour under thermal cycling; Distribution du froid par coulis de glace stabilisee. Etude du comportement sous cyclage thermique

    Energy Technology Data Exchange (ETDEWEB)

    Jacquier, D.

    2004-10-01

    The purpose of this work is to study a two-phase secondary refrigerant composed of phase-change particles suspended in a carrying liquid. This mixture has been hydraulically and thermally characterised. Moreover, some visualizations of flow patterns have been performed. Measurements of pressure losses have been realised in the case of solid state of the particles and in the case of liquid state. Heat transfer balances allowed us to show an improvement of a 1,9 factor before phase-change, in comparison with the case of a pure carrying liquid (without any particles). Flow patterns, which were theoretically specified, in function of fluid speed, have been observed experimentally. (author)

  2. First Ground-Based Infrared Solar Absorption Measurements of Free Tropospheric Methanol (CH3OH): Multidecade Infrared Time Series from Kitt Peak (31.9 deg N 111.6 deg W): Trend, Seasonal Cycle, and Comparison with Previous Measurements

    Science.gov (United States)

    Rinsland, Curtis P.; Mahieu, Emmanuel; Chiou, Linda; Herbin, Herve

    2009-01-01

    Atmospheric CH3OH (methanol) free tropospheric (2.09-14-km altitude) time series spanning 22 years has been analyzed on the basis of high-spectral resolution infrared solar absorption spectra of the strong vs band recorded from the U.S. National Solar Observatory on Kitt Peak (latitude 31.9degN, 111.6degW, 2.09-km altitude) with a 1-m Fourier transform spectrometer (FTS). The measurements span October 1981 to December 2003 and are the first long time series of CH3OH measurements obtained from the ground. The results were analyzed with SFIT2 version 3.93 and show a factor of three variations with season, a maximum at the beginning of July, a winter minimum, and no statistically significant long-term trend over the measurement time span.

  3. Optimization of absorption air-conditioning for solar energy applications

    Science.gov (United States)

    Perry, E. H.

    1976-01-01

    Improved performance of solar cooling systems using the lithium bromide water absorption cycle is investigated. Included are computer simulations of a solar-cooled house, analyses and measurements of heat transfer rates in absorption system components, and design and fabrication of various system components. A survey of solar collector convection suppression methods is presented.

  4. Energy Band Diagram near the Interface of Aluminum Oxide on p-Si Fabricated by Atomic Layer Deposition without/with Rapid Thermal Cycle Annealing Determined by Capacitance-Voltage Measurements

    Energy Technology Data Exchange (ETDEWEB)

    Satoh, N. [Department of Electrical Engineering, Kyoto University, Kyoto (Japan); Cesar, I.; Lamers, M.; Romijn, I.; Bakker, K.; Olson, C.; Oosterling Saynova, D.; Komatsu, Y.; Weeber, A. [ECN Solar Energy, Petten (Netherlands); Verbake, F.; Wiggers, M. [Philips Research, Eindhoven (Netherlands)

    2012-07-01

    We evaluated the fixed charge (Qf) and the interface state density (Dit) from the capacitance-voltage (C-V) measurement before and after rapid thermal cycle annealing (RTCA) using p-type silicon in which the passivation was performed with aluminum oxide (Al2O3) film by atomic layer deposition (ALD). From C-V measurement we obtained the surface potential (VS), accumulation and depletion width, and as a result, energy band diagrams were produced. It was determined that a barrier height of approximately 100 mV was induced by fixed negative charges in the Al2O3 layer near the interface to the p-type Si substrate. The field effect of the Al2O3 passivation layer created by RTCA strongly remains without depending on the gate voltage (VG)

  5. Tissue ultrasound absorption measurement with MRI calorimetry.

    Science.gov (United States)

    Wang, Y; Hunt, J W; Foster, F S; Plewes, D B

    1999-01-01

    The renewed interest in the use of high intensity focused ultrasound (US) for minimally invasive magnetic resonance imaging (MRI)-guided thermal therapy has stimulated a review of the interaction mechanisms of US with tissue. Although the study of tissue US properties has been conducted extensively, agreements on the measured values of tissue US absorption are poor. We propose a noninvasive approach to measure tissue US absorption based on a form of MRI calorimetry. US absorption is measured in a small tissue sample through a knowledge of the US intensity distribution incident on the tissue and an MRI measurement of total absorbed energy arising from US exposure. US absorption measurements were conducted at room temperature for ex-vivo bovine liver tissue at 1 MHz, which led to a measured US absorption coefficient of 0.058 Np/cm or 0.504 dB/cm. Because this approach is noninvasive, the experimental complications exhibited in earlier studies are not present. Furthermore, this approach can be applied over a range of frequencies, tissues, and temperatures, which will aid in understanding of biothermal effects of high intensity US to improve thermal therapy.

  6. Membrane Gas Absorption

    NARCIS (Netherlands)

    Jansen, A.E.; Klaassen, R.; Feron, P.H.M.

    1995-01-01

    Membrane gas absorption processes are absorption processes utilising hollow fibre membranes as contacting media for gas and liquid flows. The principle of operation and engineering aspects are discussed, followed by discussion of a number of typical applications. Benefits in terms of operation,

  7. Nutrition and magnesium absorption

    NARCIS (Netherlands)

    Brink, E.J.

    1992-01-01

    The influence of various nutrients present in dairy products and soybean-based products on absorption of magnesium has been investigated. The studies demonstrate that soybean protein versus casein lowers apparent magnesium absorption in rats through its phytate component. However, true

  8. Solar absorption surface panel

    Science.gov (United States)

    Santala, Teuvo J.

    1978-01-01

    A composite metal of aluminum and nickel is used to form an economical solar absorption surface for a collector plate wherein an intermetallic compound of the aluminum and nickel provides a surface morphology with high absorptance and relatively low infrared emittance along with good durability.

  9. The effect of thermal and mechanical cycling on bond strength of a ceramic to nickel-chromium (Ni-Cr) and cobalt-chromium (Co-Cr) alloys.

    Science.gov (United States)

    Vojdani, M; Shaghaghian, S; Khaledi, A; Adibi, S

    2012-01-01

    This study evaluates the effect of thermo-mechanical cycling (TMC) on the bond strength of a ceramic to three cobalt-chromium (Co-Cr) and two nickel-chromium (Ni-Cr) alloys. One hundred metal-ceramic specimens were prepared. While half of the specimens from each metal-ceramic combination (n = 10) were tested after storage in water at 37°C for 24 hours, the other half were subjected to TMC before testing. The bond strength was evaluated by the flexural strength test according to ISO 9693:1999 (E) recommendations. TMC decreased the bond strength of the tested metal-ceramic systems as compared to the water storage (control groups) (P=0.04). Although metal alloys were significantly different from each other in their bond strength with porcelain (P<0.001), the effect of TMC on the various metal-ceramic systems was not significantly different (P=0.99). It may be concluded that base metal-ceramic bond strength is affected by aging and the effect is relatively the same for all the tested porcelain-metal systems.

  10. Acoustic Droplet Vaporization for the Enhancement of Ultrasound Thermal Therapy

    Science.gov (United States)

    Zhang, Man; Fabiilli, Mario; Carson, Paul; Padilla, Frederic; Swanson, Scott; Kripfgans, Oliver; Fowlkes, Brian

    2011-01-01

    Acoustic droplet vaporization (ADV) is an ultrasound method for converting biocompatible microdroplets into microbubbles. The objective is to demonstrate that ADV bubbles can enhance high intensity focused ultrasound (HIFU) therapy by controlling and increasing energy absorption at the focus. Thermal phantoms were made with or without droplets. Compound lesions were formed in the phantoms by 5-second exposures with 5-second delays. Center to center spacing of individual lesions was 5.5 mm in either a linear pattern or a spiral pattern. Prior to the HIFU, 10 cycle tone bursts with 0.25% duty cycle were used to vaporize the droplets, forming an “acoustic trench” within 30 seconds. The transducer was then focused in the middle of the back bubble wall to form thermal lesions in the trench. All lesions were imaged optically and with 2T MRI. With the use of ADV and the acoustic trench, a uniform thermal ablation volume of 15 cm3 was achieved in 4 minutes; without ADV only less than 15% of this volume was filled. The commonly seen tadpole shape characteristic of bubble-enhanced HIFU lesions was not evident with the acoustic trench. In conclusion, ADV shows promise for the spatial control and dramatic acceleration of thermal lesion production by HIFU. PMID:21804749

  11. Modeling of the vapor cycle of Laguna Verde with the PEPSE code to conditions of thermal power licensed at present (2027 MWt); Modelado del ciclo de vapor de Laguna Verde con el codigo PEPSE a condiciones de potencia termica actualmente licenciada (2027 MWt)

    Energy Technology Data Exchange (ETDEWEB)

    Castaneda G, M. A.; Maya G, F.; Medel C, J. E.; Cardenas J, J. B.; Cruz B, H. J.; Mercado V, J. J., E-mail: miguel.castaneda01@cfe.gob.mx [Comision Federal de Electricidad, Central Nucleoelectrica Laguna Verde, Carretera Cardel-Nautla Km 42.5, Veracruz (Mexico)

    2011-11-15

    By means of the use of the performance evaluation of power system efficiencies (PEPSE) code was modeled the vapor cycle of the nuclear power station of Laguna Verde to reproduce the nuclear plant behavior to conditions of thermal power, licensed at present (2027 MWt); with the purpose of having a base line before the implementation of the project of extended power increase. The model of the gauged vapor cycle to reproduce the nuclear plant conditions makes use of the PEPSE model, design case of the vapor cycle of nuclear power station of Laguna Verde, which has as main components of the model the great equipment of the vapor cycle of Laguna Verde. The design case model makes use of information about the design requirements of each equipment for theoretically calculating the electric power of exit, besides thermodynamic conditions of the vapor cycle in different points. Starting from the design model and making use of data of the vapor cycle measured in the nuclear plant; the adjustment factors were calculated for the different equipment s of the vapor cycle, to reproduce with the PEPSE model the real vapor cycle of Laguna Verde. Once characterized the model of the vapor cycle of Laguna Verde, we can realize different sensibility studies to determine the effects macros to the vapor cycle by the variation of certain key parameters. (Author)

  12. An Alternative Approach to Non-Log-Linear Thermal Microbial Inactivation: Modelling the Number of Log Cycles Reduction with Respect to Temperature

    Directory of Open Access Journals (Sweden)

    Vasilis Panagiotis Valdramidis

    2005-01-01

    Full Text Available A mathematical approach incorporating the shoulder effect during the quantification of microbial heat inactivation is being developed based on »the number of log cycles of reduction « concept. Hereto, the heat resistance of Escherichia coli K12 in BHI broth has been quantitatively determined in a generic and accurate way by defining the time t for x log reductions in the microbial population, i.e. txD, as a function of the treatment temperature T. Survival data of the examined microorganism are collected in a range of temperatures between 52–60.6 °C. Shoulder length Sl and specific inactivation rate kmax are derived from a mathematical expression that describes a non-log-linear behaviour. The temperature dependencies of Sl and kmax are used for structuring the txD(T function. Estimation of the txD(T parameters through a global identification procedure permits reliable predictions of the time to achieve a pre-decided microbial reduction. One of the parameters of the txD(T function is proposed as »the reference minimum temperature for inactivation«. For the case study considered, a value of 51.80 °C (with a standard error, SE, of 3.47 was identified. Finally, the time to achieve commercial sterilization and pasteurization for the product at hand, i.e. BHI broth, was found to be 11.70 s (SE=5.22, and 5.10 min (SE=1.22, respectively. Accounting for the uncertainty (based on the 90 % confidence intervals, CI a fail-safe treatment of these two processes takes 20.36 s and 7.12 min, respectively.

  13. Biogeochemical Cycling

    Science.gov (United States)

    Bebout, Brad; Fonda, Mark (Technical Monitor)

    2002-01-01

    This lecture will introduce the concept of biogeochemical cycling. The roles of microbes in the cycling of nutrients, production and consumption of trace gases, and mineralization will be briefly introduced.

  14. Zeeman atomic absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Hadeishi, T.; McLaughlin, R.

    1978-08-01

    The design and development of a Zeeman atomic absorption spectrometer for trace element analysis are described. An instruction manual is included which details the operation, adjustment, and maintenance. Specifications and circuit diagrams are given. (WHK)

  15. Absorption heat pump system

    Science.gov (United States)

    Grossman, Gershon

    1984-01-01

    The efficiency of an absorption heat pump system is improved by conducting liquid from a second stage evaporator thereof to an auxiliary heat exchanger positioned downstream of a primary heat exchanger in the desorber of the system.

  16. MISSE Thermal Control Materials with Comparison to Previous Flight Experiments

    Science.gov (United States)

    Finckenor, Miria; Pippin, H. Gary; Frey, George

    2008-01-01

    Many different passive thermal control materials were flown as part of the Materials on International Space Station Experiment (MISSE), including inorganic coatings, anodized aluminum, and multi-layer insulation materials. These and other material samples were exposed to the low Earth orbital environment of atomic oxygen, ultraviolet radiation, thermal cycling, and hard vacuum, though atomic oxygen exposure was limited for some samples. Materials flown on MISSE-1 and MISSE-2 were exposed to the space environment for nearly four years. Materials flown on MISSE-3, MISSE-4, and MISSE-5 were exposed to the space environment for one year. Solar absorptance, infrared emittance, and mass measurements indicate the durability of these materials to withstand the space environment. Effects of short duration versus long duration exposure on ISS are explored, as well as comparable data from previous flight experiments, such as the Passive Optical Sample Assembly (POSA), Optical Properties Monitor (OPM), and Long Duration Exposure Facility (LDEF).

  17. Optical absorption measurement system

    Science.gov (United States)

    Draggoo, Vaughn G.; Morton, Richard G.; Sawicki, Richard H.; Bissinger, Horst D.

    1989-01-01

    The system of the present invention contemplates a non-intrusive method for measuring the temperature rise of optical elements under high laser power optical loading to determine the absorption coefficient. The method comprises irradiating the optical element with a high average power laser beam, viewing the optical element with an infrared camera to determine the temperature across the optical element and calculating the absorption of the optical element from the temperature.

  18. Advanced Fuel Cycle Economic Sensitivity Analysis

    Energy Technology Data Exchange (ETDEWEB)

    David Shropshire; Kent Williams; J.D. Smith; Brent Boore

    2006-12-01

    A fuel cycle economic analysis was performed on four fuel cycles to provide a baseline for initial cost comparison using the Gen IV Economic Modeling Work Group G4 ECON spreadsheet model, Decision Programming Language software, the 2006 Advanced Fuel Cycle Cost Basis report, industry cost data, international papers, the nuclear power related cost study from MIT, Harvard, and the University of Chicago. The analysis developed and compared the fuel cycle cost component of the total cost of energy for a wide range of fuel cycles including: once through, thermal with fast recycle, continuous fast recycle, and thermal recycle.

  19. Thermally driven microfluidic pumping via reversible shape memory polymers

    Science.gov (United States)

    Robertson, J. M.; Rodriguez, R. X.; Holmes, L. R., Jr.; Mather, P. T.; Wetzel, E. D.

    2016-08-01

    The need exists for autonomous microfluidic pumping systems that utilize environmental cues to transport fluid within a network of channels for such purposes as heat distribution, self-healing, or optical reconfiguration. Here, we report on reversible thermally driven microfluidic pumping enabled by two-way shape memory polymers. After developing a suitable shape memory polymer (SMP) through variation in the crosslink density, thin and flexible microfluidic devices were constructed by lamination of plastic films with channels defined by laser-cutting of double-sided adhesive film. SMP blisters integrated into the devices provide thermally driven pumping, while opposing elastic blisters are used to generate backpressure for reversible operation. Thermal cycling of the device was found to drive reversible fluid flow: upon heating to 60 °C, the SMP rapidly contracted to fill the surface channels with a transparent fluid, and upon cooling to 8 °C the flow reversed and the channel re-filled with black ink. Combined with a metallized backing layer, this device results in refection of incident light at high temperatures and absorption of light (at the portions covered with channels) at low temperatures. We discuss power-free, autonomous applications ranging from thermal regulation of structures to thermal indication via color change.

  20. Absorption chillers integration in a combined heat and power plant

    Energy Technology Data Exchange (ETDEWEB)

    Bruno, J. C.; Fernandez, F.; Castells, F. [Barcelona Univ., Tarragona (Spain). Dept. d`Enginyeria Quimica i Bioqumica

    1996-11-01

    Inclusion of an absorption cycle within a combined heat and power plant (CHP) was evaluated. To determine the most suitable configuration of the energy network generation system and absorption chiller, a simulation and optimization model was constructed. To validate the optimization model, a case study using actual data from existing operating plants has been used. In the case described the cooling facilities from the absorption cycle were used to lower the inlet temperature to the compressor of the gas turbine to improve the overall plant efficiency. Waste steam from the steam network was used in the generator of the absorption chiller. A reduction in steam wastes, and an improvement in overall plant efficiency was observed. A simulation model of a single effect absorption chiller, using water-lithium bromide as the working fluid pair, was used to validate the methodology. Results showed that the benefits of integrating the absorption refrigeration cycle (ARC) depends directly on the refrigeration demand, and on the benefit produced by the waste steam recovered. The increase in power generation, allowing a reduction in primary energy consumption, showed a slight economic advantage over the conventional compression cycle. 13 refs., 7. tabs., 6 figs.