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Sample records for thermal behavior study

  1. Study of ATES thermal behavior using a steady flow model

    Science.gov (United States)

    Doughty, C.; Hellstroem, G.; Tsang, C. F.; Claesson, J.

    1981-01-01

    The thermal behavior of a single well aquifer thermal energy storage system in which buoyancy flow is neglected is studied. A dimensionless formulation of the energy transport equations for the aquifer system is presented, and the key dimensionless parameters are discussed. A simple numerical model is used to generate graphs showing the thermal behavior of the system as a function of these parameters. Some comparisons with field experiments are given to illustrate the use of the dimensionless groups and graphs.

  2. Study of Lactic Acid Thermal Behavior Using Thermoanalytical Techniques

    Directory of Open Access Journals (Sweden)

    Andrea Komesu

    2017-01-01

    Full Text Available Actually, there is a growing interest in the biotechnological production of lactic acid by fermentation aiming to substitute fossil fuel routes. The development of an efficient method for its separation and purification from fermentation broth is very important to assure the economic viability of production. Due to its high reactivity and tendency to decompose at high temperatures, the study of lactic acid thermal behavior is essential for its separation processes and potential application. In the present study, differential scanning calorimetry (DSC analyses showed endothermic peaks related to the process of evaporation. Data of thermogravimetry (TG/DTG were correlated to Arrhenius and Kissinger equations to provide the evaporation kinetic parameters and used to determine the vaporization enthalpy. Activation energies were 51.08 and 48.37 kJ·mol−1 and frequency values were 859.97 and 968.81 s−1 obtained by Arrhenius and Kissinger equations, respectively. Thermogravimetry, coupled with mass spectroscopy (TG-MS, provided useful information about decomposition products when lactic acid was heated at 573 K for approximately 30 min.

  3. Kinetic study and thermal decomposition behavior of viscoelastic memory foam

    International Nuclear Information System (INIS)

    Garrido, María A.; Font, Rafael; Conesa, Juan A.

    2016-01-01

    Highlights: • The thermal degradation has been studied under three different atmospheres. • Pyrolysis and combustion kinetic models have been proposed. • Evolved products under different atmospheres have been analyzed by TG-FTIR and TG-MS. - Abstract: A systematic investigation of the thermal decomposition of viscoelastic memory foam (VMF) was performed using thermogravimetric analysis (TGA) to obtain the kinetic parameters, and thermogravimetric analysis coupled to Fourier Transformed Infrared Spectrometry (TGA-FTIR) and thermogravimetric analysis coupled to Mass Spectrometry (TGA-MS) to obtain detailed information of evolved products on pyrolysis and oxidative degradations. Two consecutive nth-order reactions were employed to correlate the experimental data from dynamic and isothermal runs performed at three different heating rates (5, 10 and 20 K/min) under an inert atmosphere. On the other hand, for the kinetic study of the oxidative decomposition, the data from combustion (synthetic air) and poor oxygen combustion (N_2:O_2 = 9:1) runs, at three heating rates and under dynamic and isothermal conditions, were correlated simultaneously. A kinetic model consisting of three consecutive reactions presented a really good correlation in all runs. TGA-FTIR analysis showed that the main gases released during the pyrolysis of VMF were determined as ether and aliphatic hydrocarbons, whereas in combustion apart from the previous gases, aldehydes, amines and CO_2 have also been detected as the main gases. These results were confirmed by the TGA-MS.

  4. Study on thermal-hydraulic behavior in supersonic steam injector

    International Nuclear Information System (INIS)

    Abe, Yutaka; Fukuichi, Akira; Kawamoto, Yujiro; Iwaki, Chikako; Narabayashi, Tadashi; Mori, Michitsugu; Ohmori, Shuichi

    2007-01-01

    Supersonic steam injector is the one of the most possible devices aiming at simplifying system and improving the safety and the credibility for next-generation nuclear reactor systems. The supersonic steam injector has dual functions of a passive jet pump without rotating machine and a compact and high efficiency heat exchanger, because it is operated by the direct contact condensation between supersonic steam and subcooled water jet. It is necessary to clarify the flow behavior in the supersonic steam injector which is governed by the complicated turbulent flow with a great shear stress of supersonic steam. However, in previous study, there is little study about the turbulent heat transfer and flow behavior under such a great shear stress at the gas-liquid interface. In the present study, turbulent flow behavior including the effect of the interface between water jet and supersonic steam is developed based on the eddy viscosity model. Radial velocity distributions and the turbulent heat transfer are calculated with the model. The calculation results are compared with the experimental results done with the transparent steam injector. (author)

  5. Study of the behavior of thermal shield support system for the French CPO series plants

    International Nuclear Information System (INIS)

    Bellet, S.; Roux, P.; Bhandari, D.R.; Schwirian, R.E.; Yu, C.; Matarazzo, J.C.; Singleton, N.R.

    1996-01-01

    Degradation/failure of thermal shield support system in PWRs has been observed in the US as well as in foreign plants. In almost all the cases, remedial actions were put in place at very high economic costs to the utilities only after the failures had occurred. This paper presents the results of a comprehensive study to predict the long term behavior of a thermal shield support system due to flow-induced vibratory loads and thermal transients. Excellent agreement from the system finite model between the measured plant test data on the barrel/thermal shield beam and shell mode frequencies and the flexure strains confirms the basic structural behavior and physics of the flow induced vibrations. Loads and stresses on the support bolts and the flexures were determined to predict the fatigue life of the components

  6. Thermal buckling behavior of defective CNTs under pre-load: A molecular dynamics study.

    Science.gov (United States)

    Mehralian, Fahimeh; Tadi Beni, Yaghoub; Kiani, Yaser

    2017-05-01

    Current study is concentrated on the extraordinary properties of defective carbon nanotubes (CNTs). The role of vacancy defects in thermal buckling response of precompressed CNTs is explored via molecular dynamics (MD) simulations. Defective CNTs are initially compressed at a certain ratio of their critical buckling strain and then undergo a uniform temperature rise. Comprehensive study is implemented on both armchair and zigzag CNTs with different vacancy defects including monovacancy, symmetric bivacancy and asymmetric bivacancy. The results reveal that defects have a pronounced impact on the buckling behavior of CNTs; interestingly, defective CNTs under compressive pre-load show higher resistance to thermal buckling than pristine ones. In the following, the buckling response of defective CNTs is shown to be dependent on the vacancy defects, location of defects and chirality. Copyright © 2017 Elsevier Inc. All rights reserved.

  7. A numerical study on thermal behavior of a D-type water-cooled steam boiler

    International Nuclear Information System (INIS)

    Moghari, M.; Hosseini, S.; Shokouhmand, H.; Sharifi, H.; Izadpanah, S.

    2012-01-01

    To achieve a precise assessment on thermal performance of a D-type water-cooled natural gas-fired boiler the present paper was aimed at determining temperature distribution of water and flue gas flows in its different heat exchange equipment. Using the zonal method to predict thermal radiation treatment in the boiler furnace and a numerical iterative approach, in which heat and fluid flow relations associated with different heat surfaces in the boiler convective zone were employed to estimate heat transfer characteristics, enabled this numerical study to obtain results in good agreement with experimental data measured in the utility site during steady state operation. A constant flow rate for a natural gas fuel of specified chemical composition was assumed to be mixed with a given excess ratio of air flow at a full boiler load. Significant results attributed to distribution of heat flux on different furnace walls and that of flue gas and water/steam temperature in different convective stages including superheater, evaporating risers and downcomers modules, and economizer were obtained. Besides the rate of heat absorption in every stage and other essential parameters in the boiler design too, inherent thermal characteristics like radiative and convective heat transfer coefficients as well as overall heat transfer conductance and effectiveness of convective stages considered as cross-flow heat exchangers were eventually presented for the given operating condition. - Highlights: ► Detailed distribution of heat flux on all of the boiler furnace walls was obtained. ► Flue gas and water thermal behaviors in different heating sections were evaluated. ► A good agreement was made between numerical results and experimental data. ► Contribution of the boiler furnace to the total thermal absorption was 39%. ► Contribution of the boiler tube banks to the total thermal absorption was 61%.

  8. Study of thermal hydraulic behavior of supercritical water flowing through fuel rod bundles

    International Nuclear Information System (INIS)

    Thakre, Sachin; Lakshmanan, S.P.; Kulkarni, Vinayak; Pandey, Manmohan

    2009-01-01

    Investigations on thermal-hydraulic behavior in Supercritical Water Reactor (SCWR) fuel assembly have obtained a significant attention in the international SCWR community because of its potential to obtain high thermal efficiency and compact design. Present work deals with CFD analysis to study the flow and heat transfer behavior of supercritical water in 4 metre long 7-pin fuel bundle using commercial CFD package ANSYS CFX for single phase steady state conditions. Considering the symmetric conditions, 1/12th part of the fuel rod bundle is taken as a domain of analysis. RNG K-epsilon model with scalable wall functions is used for modeling the turbulence behavior. Constant heat flux boundary condition is applied at the fuel rod surface. IAPWS equations of state are used to compute thermo-physical properties of supercritical water. Sharp variations in its thermo-physical properties (specific heat, density) are observed near the pseudo-critical temperature causing sharp change in heat transfer coefficient. The pseudo-critical point initially appears in the gaps among heated fuel rods, and then spreads radially outward reaching the adiabatic wall as the flow goes downstream. The enthalpy gain in the centre of the channel is much higher than that in the wall region. Non-uniformity in the circumferential distribution of surface temperature and heat transfer coefficient is observed which is in agreement with published literature. Heat transfer coefficient is high on the rod surface near the tight region and decreases as the distance between rod surfaces increases. (author)

  9. Thermal behavior studies in building using artificial neural network for non air conditioned terrace house in Malaysia

    International Nuclear Information System (INIS)

    Zainazlan Md Zain; Mohd Nasir Taib; Shahrizam Mohd Shah Baki

    2006-01-01

    Strategies to improve energy efficiency in buildings have continuously being improved and becoming more effective as new knowledge on the building behavior and technology continue to develop. Nevertheless, effort to explore for further improvement must continuously undertake to seek more energy efficient and cost effective systems. Artificial Neural Network (ANN) is currently one of the most popular mechanisms to forecast any form of behavior and phenomena. Building thermal behavior can be studied and potential for energy utilization improvement without compromising thermal comfort can be explored using ANN. This paper explores the possibility of monitoring, predicting and forecasting the thermal behavior inside a building space and the optimization of building design. Typical result of experimental data and simulated data is presented. The sample house used adopted various thermal comfort strategies like cross ventilation and space air flow consideration

  10. Study of the thermal behavior of a latent heat cold storage unit operating under frosting conditions

    International Nuclear Information System (INIS)

    Simard, A.P.; Lacroix, M.

    2003-01-01

    A study is performed of the thermal behavior of a latent heat cold storage unit operating under frosting conditions. This unit is employed to maintain the temperature inside the refrigerated compartment of a truck below 265 K. The system consists of parallel plates filled with a phase change material (PCM) that absorbs heat from the flow of warm moist air. A mathematical model for the system is first presented and, next, validated with numerical and experimental data. It is then exploited to assess the effects of design parameters and operating conditions on the performance of the system. The recommended thickness and distance separating the PCM plates are found to be 50x10 -3 and 30x10 -3 m, respectively. The results indicate that the performance of the unit is enhanced by turbulent air flow in spite of the increased pressure loss and accentuated frost growth. The unit also performs well even when the surrounding relative humidity is 100%

  11. Extraction-radiochemical study of the ion-association complex of antimony (V) with tetrazolium violet and its thermal behavior

    International Nuclear Information System (INIS)

    Kostova, S.G.; Boyanov, B.S.

    1995-01-01

    The optimum conditions for extraction of ion-associated complexes (IAS) formed from the tetrazolium salt - tetrazolium violet and Sb(V) in hydrochloric acid medium have been studied. An isotope of antimony ( 125 Sb) was used for determination of the recovery factor (R%) and distribution ratio (D S b). The thermal behavior of the antimony complex with tetrazole violet was studied using differential thermal and thermogravimetric analysis. (author) 12 refs.; 3 figs

  12. Hydration–dehydration behavior and thermodynamics of MX-80 montmorillonite studied using thermal analysis

    Energy Technology Data Exchange (ETDEWEB)

    Tajeddine, L. [CNRS-IC2MP-UMR- Hydrasa, 5 Ave Albert, Turpain, (France); Gailhanou, H.; Blanc, P.; Lassin, A.; Gaboreau, S. [BRGM, 3 Av. Claude Guillemin, BP6009, Orléans F-45060 (France); Vieillard, P., E-mail: philippe.vieillard@univ-poitiers.fr [CNRS-IC2MP-UMR- Hydrasa, 5 Ave Albert, Turpain, (France)

    2015-03-20

    Highlights: • Adsorption–desorption of water on MX-80 is determined from TGA and DTA analysis. • From DTA analysis, three types of water behavior exist at various hydration states. • Surface area of DTA allows to determine the dehydration enthalpy per mole of water. • A maximum enthalpy is 12 kJ/mol for the adsorption and desorption processes. • Enthalpy of formation of water for adsorption and desorption processes are provided. - Abstract: The thermal dehydration of natural bentonite clay MX-80 chosen as a possible future backfill material, was investigated using thermogravimetric analysis (TGA) and differential thermal analysis (DTA). The aim of this work is to provide a better understanding of the thermodynamics of the hydration–dehydration process of MX-80. The data obtained from thermogravimetry derivative curves at different relative humidities were used to determine the adsorption–desorption isotherm of MX-80. The total amount of water varies from 0.35 to 5.62 and from 0.78 to 6.12 mol adsorbed H{sub 2}O/mol of clay upon adsorption and desorption, respectively, for a RH between 11 and 91%. Furthermore, the heats released upon adsorption and desorption are not completely similar. Moreover, the analysis of DTA signals obtained at various hydration states provides insights about three types of water behavior in MX-80. Therefore, the surface area of DTA curves was taken into account to determine the dehydration enthalpy per mole of water; the values do not correlate with the amount of adsorbed water in MX-80, and the maximum enthalpy was approximately 12 kJ/mol for the adsorption and desorption studies. The values obtained were combined with the standard enthalpies of the formation of liquid water to obtain the corresponding enthalpy of the formation of water relative to dehydrated MX-80.

  13. Thermal behavior of asphalt cements

    International Nuclear Information System (INIS)

    Claudy, P.M.; Letoffe, J.M.; Martin, D.; Planche, J.P.

    1998-01-01

    Asphalt cements are highly complex mixtures of hydrocarbon molecules whose thermal behavior is of prime importance for petroleum and road industry. From DSC, the determination of several thermal properties of asphalts is given, e.g. glass-transition temperature and crystallized fraction content.The dissolution of a pure n-paraffin C n H 2n+2 in an asphalt, as seen by DSC, should be a single peak. For 20 g of these glasses change with time and temperature. The formation of the crystallized phases is superposed to the enthalpic relaxation of the glasses, making a kinetic study very difficult. (Copyright (c) 1998 Elsevier Science B.V., Amsterdam. All rights reserved.)

  14. Comparison studies of rheological and thermal behaviors of ionic liquids and nanoparticle ionic liquids.

    Science.gov (United States)

    Xu, Yiting; Zheng, Qiang; Song, Yihu

    2015-08-14

    Novel nanoparticle ionic liquids (NILs) are prepared by grafting modified nanoparticles with long-chain ionic liquids (ILs). The NIL behaves like a liquid at ambient temperature. We studied the rheological behavior of the IL and NIL over the range of 10-55 °C and found an extraordinary difference between the IL and NIL: a small content of nanosilica (7%) moderately improves the crystallinity by 7% of the poly(ethylene glycol) (PEG) segment in the IL, and it improves the dynamic moduli significantly (by 5 times at room temperature). It retards the decay temperature (by 10 °C) of the dynamic moduli during heating as well. The thermal rheological hysteresis observed during heating-cooling temperature sweeps is ascribed to the melting-recrystallization of the PEG segments. Meanwhile, the IL and NIL express accelerated crystallization behavior in comparison with the oligomeric anion. For the first time, we find that ILs and NILs are able to form nanoparticle-containing spherulites at room temperature after long time aging.

  15. MyrrhaFoam: A CFD model for the study of the thermal hydraulic behavior of MYRRHA

    Energy Technology Data Exchange (ETDEWEB)

    Koloszar, Lilla; Buckingham, Sophia; Planquart, Philippe [von Karman Institute, Chaussée de Waterloo 72, B-1640 Rhode-St-Genèse (Belgium); Keijers, Steven [SCK-CEN, Boeretang 200, 2400 Mol (Belgium)

    2017-02-15

    Highlights: • Development of a modeling approach for simulating the thermal hydraulics of heavy liquid metal nuclear reactors. • Detailed description of the modeling of each component through the MYRRHA reactor. • Detailed analysis of the flow field of the MYRRHA reactor under operating condition. • Assessment of the thermal load on the structures as well as the thermal stratification in the upper and the lower plenum. - Abstract: Numerical analysis of the thermohydraulic behavior of the innovative flexible fast spectrum research reactor, MYRRHA, under design by the Belgian Nuclear Research Center (SCK• CEN) is a very challenging task. The primary coolant of the reactor is Lead Bismuth Eutectic, LBE, which is an opaque heavy liquid metal with low Prandtl number. The simulation tool needs to involve many complex physical phenomena to be able to predict accurately the flow and thermal field in the pool type reactor. In the past few years, within the frame of a collaboration between SCK• CEN and the von Karman Institute, a new platform, MyrrhaFoam, was developed based on the open source simulation environment, OpenFOAM. The current tool can deal with incompressible buoyancy corrected steady/unsteady single phase flows. It takes into account conjugate heat transfer in the solid parts which is mandatory due to the expected high temperature gradients between the different parts of the reactor. The temperature dependent properties of LBE are also considered. MyrrhaFoam is supplemented with the most relevant thermal turbulence models for low Prandtl number liquids up to date.

  16. Thulium oxide fuel characterization study: Part 2, Environmental behavior and mechanical, thermal and chemical stability enhancement

    International Nuclear Information System (INIS)

    Nelson, C.A.

    1970-12-01

    A study was performed of the correlation between fuel form stability and exposure environment of (temperature and atmosphere). 100% Tm 2 O 3 , 80% Tm 2 O 3 /20% Yb 2 O 3 and 100% Yb 2 O 3 wafers were subjected to air, dynamic vacuum and static vacuum at temperatures to 2000 0 C for times to 100 hours. Results showed the Tm 2 O 3 /Yb 2 O 3 cubic structure to be unaffected by elemental levels of iron, aluminum, magnesium and silicon and unaffected by the environmental conditions imposed on the wafers. A second task emphasized the optimization of the thermal, mechanical and chemical stability of Tm 2 O 3 fuel forms. Enhancement was sought through process variable optimization and the addition of metal oxides to Tm 2 O 3 . CaO, TiO 2 and Al 2 O 3 were added to form a grain boundary precipitate to control fines generation. The presence of 1% additive was inadequate to depress the melting point of Tm 2 O 3 or to change the cubic crystalline structure of Tm 2 O 3 /Yb 2 O 3 . Tm 2 O 3 /Yb 2 O 3 wafers containing CaO developed a grain boundary phase that improved the resistance to fines generation. The presence of Yb 2 O 3 did not appear to measurably influence behavior

  17. Numerical study on the thermal behavior of graphene nanoplatelets/epoxy composites

    Science.gov (United States)

    Xiao, Wenkai; Zhai, Xian; Ma, Pengfei; Fan, Taotao; Li, Xiaotuo

    2018-06-01

    A three-dimensional computational model was developed using the finite element method (FEM) to evaluate the thermal behavior of graphene nanoplatelets (GNPs)/epoxy composites based on continuum mechanics. The model was validated with experimental data. The effects of the ratio of radius to thickness (Rrt) of GNPs, the interfacial thermal conductivity between GNPs and the matrix (Cgm), the contact thermal conductivity between GNPs (Cgg) and the agglomeration degree of GNPs on the thermal conductivity of composites (Kc) were quantified using this model. The results show that a larger Rrt is beneficial to Kc. GNPs could increase Kc only when the Cgm is greater than a critical value. A percolation phenomenon will occur when Cgg is larger than 1.0E8 W/(m2k) in randomly distributed GNPs/epoxy composites. The percolation effects become more obvious with the increase of Cgg and the volume fraction of GNPs. The agglomeration of GNPs has negative effects on the Kc. The higher the agglomeration degree of GNPs is, the lower Kc is. This is attributed to less beneficial interfacial areas, more inefficient contact areas, smaller Rrt and less effective connection/contact between GNPs.

  18. Thermal fatigue behavior of valves

    International Nuclear Information System (INIS)

    Moinereau, D.; Scliffet, L.; Capion, J.C.; Genette, P.

    1991-01-01

    This paper reports that valves of pressurized water reactors are exposed to thermal shocks during transient operations. The numerous thermal shock tests performed on valves on the EDF test facilities have shown the sensibility of fillets and geometrical discontinuities to thermal fatigue: cracks can appear in those areas and grow through the valve body. Valves systems designated as level 1 must be designed to withstand fatigue up to the second isolation valve: the relevant rule is specified in the paragraph B 3500 of the French RCCM code. It is a simplified method which doesn't require finite element calculations. Many valve systems have been designed according to this rule and have been operated without accident. However, in one case, important cracks were found in the fillet of a check-valve after numerous thermal shocks. Calculation of the valve's behavior according to the RCCM code to estimate the fatigue damage resulting from thermal shocks led to a low damage factor, which doesn't agree with the experimental results. This was confirmed by new testings and showed the inadequacy of B 3500 rule for thermal transients. On this base a new rule is proposed to estimate fatigue damage resulting from thermal shocks. An experimental program has been realized to validate this rule. Axisymetrical analytical mock-ups with different geometries and one check-valve in austenitic stainless steel 316 L have been submitted to hot thermal shocks of 210 degrees C magnitude

  19. Comprehensive Study on Thermal and Dynamic Mechanical Behavior of PET/PEN Blends

    Directory of Open Access Journals (Sweden)

    Hossien Ali Khonakdar

    2013-10-01

    Full Text Available The effects of interchange reactions on the crystallization, melting, and dynamic mechanical thermal behavior of poly(ethylene terephthalate/poly(ethylene naphthalate (PET/PEN blends prepared by melt mixing have been investigated. The occurrence of interchange reactions has been verified by proton nuclear magnetic resonance (1H NMR. Differential scanning calorimetry (DSC and dynamic mechanical analysis (DMA were used to study the effect of transesterification reaction on crystallinity, melting and dynamic mechanical properties of the blends. It was found that by extension of transesterification, the miscibility of the blend increased. Time and temperature of mixing were most important parameters affecting the transesterification level. On blending, the melt crystallinity of poly(ethylene terephthalate was reduced and in contrast that of poly(ethylene naphthalate was increased; where melt crystallization temperatures of both phases were depressed. A single composition-dependent glass transition peak, which was indicative of miscibility, was detected in second heating thermograms of the blends. It was observed that cold crystallization of poly(ethylene terephthalate phase decreases while that of poly(ethylene naphthalate was suppressed on blending. It was found that each phase crystallized individually and a melting point depression which was an indication of compatibility was evident at the same time. Dynamic mechanical analysis confirmed the proton nuclear magnetic resonance and differential scanning calorimetry results. The secondary viscoelastic transitions of each phase in blend samples were also probed. Increment of peak area in the loss factor has implied the miscibility of blend due to formation of poly(ethylene terephthalate/poly(ethylene naphthalate random copolymer.

  20. Study of the influence of mechanical - thermal treatments on the creep behavior of a niobium stainless steel

    International Nuclear Information System (INIS)

    Rossi, J.L.; Ferreira, P.I.

    1986-01-01

    The influence of microstructural parameters controlled by mechanical-thermal treatment |1| on the creep behavior of DIN-Werkstoff-Nr. 1.4981 stainless steel (material candidate for use as cladding of fast breeder reactor (fuel elements), is studied. The effects of the solution treatment, predeformation, predeformation puls aging and cycles of predeformation-ageing on the creep results obtained at 990 K, for apllied stresses in the range 70 MPc - 310 MPa, are discussed. (Author) [pt

  1. Molybdenum peroxo complex. Structure and thermal behavior

    Energy Technology Data Exchange (ETDEWEB)

    Segawa, Koichi; Ooga, Katsumi; Kurusu, Yasuhiko

    1984-10-01

    The molybdenum peroxide (Mo-y) prepared by oxidation of molybdenum metal with hydrogen peroxide has been studied to determine its structure and thermal behavior. Temperature programmed decomposition has been used to study the thermal stability of Mo-y. Two distinct peaks, I and II, of decomposition processes are discernible in Mo-y. Peak I corresponds to the elimination of water of crystallization and peak II to the decomposition of a peroxide ion of Mo-y. IR and UV examinations support the results of the thermal analysis. The IR band at 931 cm/sup -1/ and the UV band at 381 nm show the same thermal behavior. Both bands are attributable to the peroxide ion of Mo-y. Spectroscopic studies show that Mo-y has the tetrahedral coordination derived from the single molybdenum complex, which has double bond oxygens attached to Mo atom and has a symmetric type of peroxide ion with one water of crystallization.

  2. Study on mixing behavior in a tee piping and numerical analyses for evaluation of thermal striping

    International Nuclear Information System (INIS)

    Kamide, H.; Igarashi, M.; Kawashima, S.; Kimura, N.; Hayashi, K.

    2009-01-01

    Water experiments were carried out for thermal hydraulic aspects of thermal striping in a mixing tee, which has main to branch diameter ratio of 3. Detailed temperature and velocity fields were measured by a movable thermocouple tree and particle image velocimetry. Flow patterns in the tee were classified into three groups; wall jet, deflecting jet, and impinging jet, which had their own temperature fluctuation profiles, depending on a momentum ratio between the main and branch pipes. Non-dimensional power spectrum density (PSD) of temperature fluctuation showed a unique profile, when the momentum ratio was identical. Numerical simulation based on finite difference method showed alternative vortex development, like Karman vortex series, behind the jet from the branch pipe in the wall jet case. The prominent frequency of the temperature fluctuation in the calculation was 0.2 of St number based on the branch pipe diameter and in good agreement with the experimental results. Mixing behavior in the tee was characterized by the relatively large vortex structures defined by the diameters and the velocities in the pipes

  3. Thermal behavior of natural zeolites

    International Nuclear Information System (INIS)

    Bish, D.L.

    1993-01-01

    Thermal behavior of natural zeolites impacts their application and identification and varies significantly from zeolite to zeolite. Zeolites evolve H 2 0 upon heating, but recent data show that distinct ''types'' of water (e.g., loosely bound or tightly bound zeolitic water) do not exist. Rather water is bound primarily to extra-framework cations with a continuum of energies, giving rise to pseudocontinuous loss of water accompanied by a dynamic interaction between remaining H 2 0 molecules and extra-framework cations. These interactions in the channels of zeolites give rise to dehydration dependent on the extra-framework cation, in addition to temperature and water vapor pressure. The dehydration reaction and the extra-framework cation also affect the thermal expansion/contraction. Most zeolites undergo dehydration-induced contractions that may be anisotropic, although minor thermal expansion can be seen with some zeolites. Such contractions can be partially or completely irreversible if they involve modifications of the tetrahedral framework and/or if rehydration is sluggish. Thermally induced structural modifications are also driven initially by dehydration and the concomitant contraction and migration of extra-framework cations. Contraction is accommodated by rotations of structural units and tetrahedral cation-oxygen linkages may break. Thermal reactions that involve breaking of tetrahedral cation-oxygen bonds markedly irreversible and may be kinetically limited, producing large differences between short- and long-term heating

  4. Gas permeability and thermal behavior of polypropylene films used for packaging minimally processed fresh-cut potatoes: a case study.

    Science.gov (United States)

    Siracusa, Valentina; Blanco, Ignazio; Romani, Santina; Tylewicz, Urszula; Dalla Rosa, Marco

    2012-10-01

    This work reports an experimental study on the permeability and thermal behavior of commercial polypropylene (PP) film used for fresh-cut potatoes packaging. The permeability was tested using oxygen, carbon dioxide, nitrogen, mix of these 3 gases, normally used for modified atmosphere packaging (MAP) and Air, to understand if it would be possible to extend the shelf life of this food product designed for the catering field in respect to the packaging behavior. The temperature influence on permeability data, from 5 to 40 °C, was analyzed, before and after 4, 8, 12, 15, and 20 d of food contact, pointing out the dependence between temperature and gas transmission rate (GTR), solubility (S), diffusion coefficient (D), and time lag (t(L)) parameters. The activation energies (E) of the permeation process were determined with the different gases used in the experiments. The thermal behavior of PP film was studied by differential scanning calorimetry (DSC) and thermogravimetric analysis (TG) to well understand its thermal stability. Fourier transformed-infrared with attenuated total reflectance (FT-IR/ATR) spectroscopy was also performed in order to study the influence of the food contact on the chemical characteristics of the polymer film. The results obtained were discussed and compared each other. Studied samples showed, for all investigated gases, an increase of gas permeability and S values at higher temperature. Heat resistance classification among the sample as it is and stored in modified atmospheres was made. Finally all performed experiments have showed good polymer stability for the shelf-life storage potatoes under study. Study of packaging material was performed in a range of temperature, which can simulate the service condition to assess the suitability of a commercial polymer film for modified atmosphere packaging of fresh-cut potatoes minimally processed designed for catering purpose. © 2012 Institute of Food Technologists®

  5. Oxidation and thermal behavior of Jatropha curcas biodiesel ...

    African Journals Online (AJOL)

    The thermal and oxidation behavior is also affected adversely by the container metal. The present paper is dealing with the study of oxidation and thermal behavior of JCB with respect to different metal contents. It was found that influence of metal was detrimental to thermal and oxidation stability. Even small concentrations ...

  6. Study on the behavior of heavy metals during thermal treatment of municipal solid waste (MSW) components.

    Science.gov (United States)

    Yu, Jie; Sun, Lushi; Wang, Ben; Qiao, Yu; Xiang, Jun; Hu, Song; Yao, Hong

    2016-01-01

    Laboratory experiments were conducted to investigate the volatilization behavior of heavy metals during pyrolysis and combustion of municipal solid waste (MSW) components at different heating rates and temperatures. The waste fractions comprised waste paper (Paper), disposable chopstick (DC), garbage bag (GB), PVC plastic (PVC), and waste tire (Tire). Generally, the release trend of heavy metals from all MSW fractions in rapid-heating combustion was superior to that in low-heating combustion. Due to the different characteristics of MSW fractions, the behavior of heavy metals varied. Cd exhibited higher volatility than the rest of heavy metals. For Paper, DC, and PVC, the vaporization of Cd can reach as high as 75% at 500 °C in the rapid-heating combustion due to violent combustion, whereas a gradual increase was observed for Tire and GB. Zn and Pb showed a moderate volatilization in rapid-heating combustion, but their volatilities were depressed in slow-heating combustion. During thermal treatment, the additives such as kaolin and calcium can react or adsorb Pb and Zn forming stable metal compounds, thus decreasing their volatilities. The formation of stable compounds can be strengthened in slow-heating combustion. The volatility of Cu was comparatively low in both high and slow-heating combustion partially due to the existence of Al, Si, or Fe in residuals. Generally, in the reducing atmosphere, the volatility of Cd, Pb, and Zn was accelerated for Paper, DC, GB, and Tire due to the formation of elemental metal vapor. TG analysis also showed the reduction of metal oxides by chars forming elemental metal vapor. Cu2S was the dominant Cu species in reducing atmosphere below 900 °C, which was responsible for the low volatility of Cu. The addition of PVC in wastes may enhance the release of heavy metals, while GB and Tire may play an opposite effect. In controlling heavy metal emission, aluminosilicate- and calcium-based sorbents can be co-treated with fuels. Moreover

  7. Experimental and theoretical studies of the thermal behavior of titanium dioxide-SnO2 based composites.

    Science.gov (United States)

    Voga, G P; Coelho, M G; de Lima, G M; Belchior, J C

    2011-04-07

    In this paper we report experimental and theoretical studies concerning the thermal behavior of some organotin-Ti(IV) oxides employed as precursors for TiO(2)/SnO(2) semiconducting based composites, with photocatalytic properties. The organotin-TiO(2) supported materials were obtained by chemical reactions of SnBu(3)Cl (Bu = butyl), TiCl(4) with NH(4)OH in ethanol, in order to impregnate organotin oxide in a TiO(2) matrix. A theoretical model was developed to support experimental procedures. The kinetics parameters: frequency factor (A), activation energy, and reaction order (n) can be estimated through artificial intelligence methods. Genetic algorithm, fuzzy logic, and Petri neural nets were used in order to determine the kinetic parameters as a function of temperature. With this in mind, three precursors were prepared in order to obtain composites with Sn/TiO(2) ratios of 0% (1), 15% (2), and 30% (3) in weight, respectively. The thermal behavior of products (1-3) was studied by thermogravimetric experiments in oxygen.

  8. Thermal behavior of TAXN and TCDXM D2 collimator mask, Finite element studies

    CERN Document Server

    Sklariks, Stepans

    2015-01-01

    The objective of this project was to perform thermal loading simulations of TCDXM (D2 collimator mask) and TAXN so as to allow the preliminary evaluation of the suitability of the given parts for the upcoming high luminosity upgrade that is to be performed in LHC in the nearest future.

  9. Studies on chalcone derivatives: Complex formation, thermal behavior, stability constant and antioxidant activity

    Science.gov (United States)

    El-Sayed, Yusif S.; Gaber, M.

    2015-02-01

    The chalcone 3-[4‧-dimethylaminophenyl]-1-(2-pyridyl) prop-2-en-1-one (DMAPP) and 3-(4‧-diethylaminophenyl)-1-(2-pyridinyl) prop-2-en-1-one abbreviated as DEAPP have been synthesized and characterized with IR, 1H NMR, 13C NMR spectroscopic techniques as described previously (El-Daly et al., 2008; Gaber et al., 2009; El-Sayed, 2013). By using UV visible spectroscopy method the mole fraction ratio for copper with DMAPP and DEAPP complexes were determined and it was found to be 1:1. The stability constants of this complex have been determined by Job's method. The stability constant (Kf) of copper with DMAPP and DEAPP complexes in universal buffer pH = 3.2 was determined to be 9.9 × 104 and 5.2 × 104 respectively. The effect of Cu(II) ion on the emission spectrum of the free chalcone is also assigned. Adherence to Beer's law and Ringbom optimum concentration ranges are determined. The thermal decomposition of the metal complexes is studied by TGA technique. The kinetic parameters like activation energy, pre-exponential factor and entropy of activation are estimated. The structure of complexes was energetically optimized through molecular mechanics applying MM+ force field coupled with molecular dynamics simulation. The bond lengths and bond angles have been calculated to confirm the geometry of the ligands and their Cu(II) complexes. The mode of interaction of the chalcone to copper nanoparticles was studied. The apparent association constants of the colloidal copper nanoparticles:chalcone complexes in solution were evaluated using the spectral method and compared with the formation constant of the Cu(II) chalcone complexes. Antioxidant activity of these chalcones was evaluated by using 1,1‧-diphenyl-2-picrylhydrazyl (DPPHrad) radicals scavenging method, which showed that the antioxidant activity of DMAPP has higher value than the DEAPP. Semi-empirical study results showed that DMAPP have higher dipole moment than DEAPP [1].

  10. Internal photoemission study on charge trapping behavior in rapid thermal oxides on strained-Si/SiGe heterolayers

    International Nuclear Information System (INIS)

    Bera, M.K.; Mahata, C.; Bhattacharya, S.; Chakraborty, A.K.; Armstrong, B.M.; Gamble, H.S.; Maiti, C.K.

    2008-01-01

    A comparative study on the nature of defects and their relationship to charge trapping with enhanced photosensitivity has been investigated through magnetic resonance and internal photoemission (IPE) experiments for rapid thermal grown oxides (RTO) on strained-Si/Si 0.8 Ge 0.2 and on co-processed bulk-Si (1 0 0) substrates. Both the band and defect-related electronic states were characterized through EPR, IPE, C-V and I-V measurements under UV-illumination. Surface chemical characterization of as-grown ultrathin oxides (5-7 nm) has been performed using high-resolution XPS. Enhancement in Ge-segregation with increasing oxidation temperature is reported. Comparative studies on interface properties and leakage current behavior of rapid thermal oxides have also been studied through fabricating metal-oxide-semiconductor capacitor structures. A degraded electrical property with increasing oxidation temperature is reported. Constant voltage stressing (CVS) in the range of 5.5-7 V was used to study the breakdown characteristics of different samples. We observe a distinguishably different time-to-breakdown (t bd ) phenomenon for bulk-Si and strained-Si/SiGe samples. Whereas the oxide on bulk-Si shows a typical breakdown behavior, the RTO grown oxide on strained-Si/SiGe samples showed a quasi-or soft-breakdown with lower t bd value. It may be pointed out that quasi-breakdown may be a stronger reliability limiting factor for strained-Si/SiGe devices in the oxide thickness range studied

  11. Study on Tensile Fatigue Behavior of Thermal Butt Fusion in Safety Class III High-Density Polyethylene Buried Piping in Nuclear Power Plants

    International Nuclear Information System (INIS)

    Kim, Jong Sung; Lee, Young Ju; Oh, Young Jin

    2015-01-01

    High-density polyethylene (HDPE) piping, which has recently been applied to safety class III piping in nuclear power plants, can be butt-joined through the thermal fusion process, which heats two fused surfaces and then subject to axial pressure. The thermal fusion process generates bead shapes on the butt fusion. The stress concentrations caused by the bead shapes may reduce the fatigue lifetime. Thus, investigating the effect of the thermal butt fusion beads on fatigue behavior is necessary. This study examined the fatigue behavior of thermal butt fusion via a tensile fatigue test under stress-controlled conditions using finite element elastic stress analysis. Based on the results, the presence of thermal butt fusion beads was confirmed to reduce the fatigue lifetime in the low-cycle fatigue region while having a negligible effect in the medium- and high-cycle fatigue regions

  12. Study on Tensile Fatigue Behavior of Thermal Butt Fusion in Safety Class III High-Density Polyethylene Buried Piping in Nuclear Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jong Sung; Lee, Young Ju [Sunchon National University, Suncheon (Korea, Republic of); Oh, Young Jin [KEPCO E and C, Yongin (Korea, Republic of)

    2015-01-15

    High-density polyethylene (HDPE) piping, which has recently been applied to safety class III piping in nuclear power plants, can be butt-joined through the thermal fusion process, which heats two fused surfaces and then subject to axial pressure. The thermal fusion process generates bead shapes on the butt fusion. The stress concentrations caused by the bead shapes may reduce the fatigue lifetime. Thus, investigating the effect of the thermal butt fusion beads on fatigue behavior is necessary. This study examined the fatigue behavior of thermal butt fusion via a tensile fatigue test under stress-controlled conditions using finite element elastic stress analysis. Based on the results, the presence of thermal butt fusion beads was confirmed to reduce the fatigue lifetime in the low-cycle fatigue region while having a negligible effect in the medium- and high-cycle fatigue regions.

  13. A study of the thermal behavior of terrestrial tridymite by continuous X-ray diffraction

    Science.gov (United States)

    Smelik, Eugene A.; Reeber, Robert R.

    1990-06-01

    Phase transition behavior of two types of terrestrial tridymite; crystals from Topaz Mountain in the Thomas Range of northwestern Utah and Smith Peak in Plumas County, California; were investigated. The Topaz Mtn. samples were characterized at room temperature using optical, X-ray diffraction (Debye-Scherrer, rotation, and Laue), and transmission electron microscopy (TEM) methods. Least-squares refinement of the powder data yielded an orthorhombic cell with a = 17.072 Å, b = 9.923 Å, and c = 16.291 Å. The tridymite is designated PO-2 (nomenclature of Nukui and Nakazawa 1980). This material is complexly twinned and has severe stacking disorder parallel to [001]. Additional X-ray experiments were performed on one Plumas County crystal and four Topaz Mtn. crystals during heating from room temperature to a minimum of 320° C with one run attaining a maximum temperature of 532° C. Crystal to crystal behavior was somewhat variable suggesting kinetic barriers to transition controlled by the detailed structural state of each crystal. The Laue results indicated that the transition behavior of these multiple twinned tridymites could be conveniently divided into two classes: discontinuous and continuous. The discontinuous diffraction effects were generally associated with major structural transitions. Continuous diffraction effects involved gradual structural distortions of the tridymite framework that occurred over discrete ranges of temperature. Upon cooling, many of the minor effects were not reversible while the major transitions were reversible with some temperature hysteresis. Comparison of initial and final diffraction patterns indicated that the starting and ending structures were very similar but not identical. From the five experiments, three distinct patterns emerged based on the major transitions observed: Type I behavior (Topaz Mtn.) characterized by three major changes at 175 187° C, 283 302° C, and 348 352° C, Type II behavior (Plumas Co.) characterized

  14. Thermal hydraulic test for reactor safety system; a visualization study on flow boiling and bubble behavior

    Energy Technology Data Exchange (ETDEWEB)

    Chang, Soon Heung; Baek, Won Pil; Ban, In Cheol [Korea Advanced Institute of Science and Technology, Taejeon (Korea)

    2002-03-01

    The project contribute to understand and to clarify the physical mechanism of flow nucleate boiling and CHF phenomena through the visualization experiments. the results are useful in the development of the enhancement device of heat transfer and to enhance nuclear fuel safety 1. Visual experimental facility 2. Application method of visualization Technique 3. Visualization results of flow nucleate boiling regime - Overall Bubble Behavior on the Heated Surface - Bubble Behavior near CHF Condition - Identification of Flow Structure - Three-layer flow structure 4. Quantifying of bubble parameter through a digital image processing - Image Processing Techniques - Classification of objects and measurements of the size - Three dimensional surface plot with using the luminance 5. Development and estimation of a correlation between bubble diameter and flow parameter - The effect of system parameter on bubble diameter - The development of a bubble diameter correlation . 49 refs., 42 figs., 7 tabs. (Author)

  15. Thermal behavior studies of the homopolynuclear coordination compound iron(III) polyoxalate

    International Nuclear Information System (INIS)

    Niculescu, Mircea; Sasca, Viorel; Muntean, Cornelia; Milea, Marius-Silviu; Roşu, Dan

    2016-01-01

    Graphical abstract: - Highlights: • The thermal decomposition of [Fe(C_2O_4)(OH)(OH_2)]_n·0.3nH_2O leads to Fe_2O_3 polymorphs. • The products were analyzed using the diffuse reflectance technique, XRD, FTIR and SEM. • The product obtained at 350 °C is a mixture of γ-Fe_2O_3 (majority) and α-Fe_2O_3 phases. • Through the calcination at 800 °C the conversion of γ-Fe_2O_3 to α-Fe_2O_3 takes place. • Precursor and conditions are important for obtaining Fe_2O_3 phases as nanoparticles. - Abstract: The thermal decomposition in dynamic oxidative atmosphere of the new homopolynuclear coordination compound [Fe(C_2O_4)(OH)(OH_2)]_n·0.3nH_2O was investigated by simultaneously using TG, DTG and DTA techniques. Solid-state decomposition products formed during heating at different temperatures (350 °C, 800 °C and 1000 °C) were analyzed by physical-chemical methods, including electronic spectroscopy (diffuse reflectance technique), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM). The XRD analysis data show that the final decomposition product, namely hematite (α-Fe_2O_3), is relatively well crystallized, while SEM images reveal that the particles exhibit irregular forms, their size being widely distributed between 6 nm and 4 μm.

  16. Calibrating thermal behavior of electronics

    Science.gov (United States)

    Chainer, Timothy J.; Parida, Pritish R.; Schultz, Mark D.

    2016-05-31

    A method includes determining a relationship between indirect thermal data for a processor and a measured temperature associated with the processor, during a calibration process, obtaining the indirect thermal data for the processor during actual operation of the processor, and determining an actual significant temperature associated with the processor during the actual operation using the indirect thermal data for the processor during actual operation of the processor and the relationship.

  17. Thermal expansion behavior study of Co nanowire array with in situ x-ray diffraction and x-ray absorption fine structure techniques

    Science.gov (United States)

    Mo, Guang; Cai, Quan; Jiang, Longsheng; Wang, Wei; Zhang, Kunhao; Cheng, Weidong; Xing, Xueqing; Chen, Zhongjun; Wu, Zhonghua

    2008-10-01

    In situ x-ray diffraction and x-ray absorption fine structure techniques were used to study the structural change of ordered Co nanowire array with temperature. The results show that the Co nanowires are polycrystalline with hexagonal close packed structure without phase change up until 700 °C. A nonlinear thermal expansion behavior has been found and can be well described by a quadratic equation with the first-order thermal expansion coefficient of 4.3×10-6/°C and the second-order thermal expansion coefficient of 5.9×10-9/°C. The mechanism of this nonlinear thermal expansion behavior is discussed.

  18. Thermal fluid mixing behavior during medium break LOCA in evaluation of pressurized thermal shock

    Energy Technology Data Exchange (ETDEWEB)

    Jung, Jae Won; Bang, Young Seok; Seul, Kwang Won; Kim, Hho Jung [Korea Institute of Nuclear Safety, Taejon (Korea, Republic of)

    1998-12-31

    Thermal fluid mixing behavior during a postulated medium-size hot leg break loss of coolant accident is analyzed for the international comparative assessment study on pressurized thermal shock (PTS-ICAS) proposed by OECD-NEA. The applicability of RELAP5 code to analyze the thermal fluid mixing behavior is evaluated through a simple modeling relevant to the problem constraints. Based on the calculation result, the onset of thermal stratification is investigated using Theofanous`s empirical correlation. Sensitivity calculations using a fine node model and crossflow model are also performed to evaluate the modeling capability on multi-dimensional characteristics related to thermal fluid mixing. 6 refs., 8 figs. (Author)

  19. Thermal fluid mixing behavior during medium break LOCA in evaluation of pressurized thermal shock

    International Nuclear Information System (INIS)

    Jung, Jae Won; Bang, Young Seok; Seul, Kwang Won; Kim, Hho Jung

    1998-01-01

    Thermal fluid mixing behavior during a postulated medium-size hot leg break loss of coolant accident is analyzed for the international comparative assessment study on pressurized thermal shock (PTS-ICAS) proposed by OECD-NEA. the applicability of RELAP5 code to analyze the thermal fluid mixing behavior is evaluated through a simple modeling relevant to the problem constraints. Based on the calculation result, the onset of thermal stratification is investigated using Theofanous's empirical correlation. Sensitivity calculations using a fine node model and crossflow model are also performed to evaluate the modeling capability on multi-dimensional characteristics related to thermal fluid mixing

  20. The chemometric study of limestone physico-chemical properties and thermal behavior for application in construction composites

    Directory of Open Access Journals (Sweden)

    Radulović Dragan

    2017-01-01

    Full Text Available The limestone, as an economically sustainable and easily available basic raw material, is frequently utilized in the building industry for resolving of the environmental protection issues. The limestone is incorporated in a cementitious system either by grinding with cement clinker, or by blending with the binder during concrete production. The employing of powdery limestone as partial cement replacement gives the construction composites with properties comparable to that of conventional concrete. The study of limestone thermal behavior and its chemistry is crucial for the prognosis of the designed composites properties. In this work, the instrumental techniques (atomic emission spectroscopy, differential thermal and thermo-gravimetric analysis, Fourier transform infrared spectroscopy and the Principal component analysis were employed to discriminate and classify 22 limestone types. The PCA statistical method, as a means of spectra and experimental data fingerprinting, grouped the samples in a multi-dimensional factor space producing four graphical prognosis - one for each instrumental method. DTA/TG peak values varied the most in a short range between 830-870°C, while FTIR spectra showed the highest diversity in the 867-887 cm-1 and 1237-1647 cm-1 ranges. This research was governed by an idea to reveal whether it is possible to differentiate various limestone types and to predict the possibility of their employment in construction composites on the basis of the results of instrumental and mathematical analyses. [Project of the Serbian Ministry of Education, Science and Technological Development, Grant no. ON 172057, III 45008, TR 31055, TR 34006, and TR 34013

  1. Solid-state thermal behavior and stability studies of theophylline–citric acid cocrystals prepared by neat cogrinding or thermal treatment

    International Nuclear Information System (INIS)

    Hsu, Po-Chun; Lin, Hong-Liang; Wang, Shun-Li; Lin, Shan-Yang

    2012-01-01

    To investigate the thermal behavior of cocrystal formed between anhydrous theophylline (TP) and anhydrous citric acid (CA) by neat manual cogrinding or thermal treatment, DSC and FTIR microspectroscopy with curve-fitting analysis were applied. The physical mixture and 60-min ground mixture were stored at 55±0.5 °C/40±2% RH condition to determine their stability behavior. Typical TP–CA cocrystals were prepared by slow solvent evaporation method. Results indicate that the cogrinding process could gradually induce the cocrystal formation between TP and CA. The IR spectral peak shift from 3495 to 3512 cm −1 and the stepwise appearance of several new IR peaks at 1731, 1712, 1676, 1651, 1557 and 1265 cm −1 with cogrinding time suggest that the mechanism of TP–CA cocrystal formation was evidenced by interacting TP with CA through the intermolecular O–H···O hydrogen bonding. The stability of 60-min ground mixture of TP–CA was confirmed at 55±0.5 °C/40±2% RH condition over a storage time of 60 days. - Garphical abstract: Cogrinding, thermal and solvent-evaporation methods might easily induce the theophylline–citric acid cocrystal formation. Highlights: ► Cogrinding process could gradually induce the cocrystal formation between TP and CA. ► The TP–CA cocrystal was formed through the intermolecular O–H···O hydrogen bonding. ► The 60-min TP–CA ground mixture was similar to the solvent-evaporated cocrystal. ► The thermal-induced TP–CA cocrystal formation was confirmed by pre-heating the physical mixture to 152 °C. ► The 60-min TP–CA ground mixture was stable at accelerated condition over a storage time of 60 days.

  2. Field study on behaviors and adaptation of elderly people and their thermal comfort requirements in residential environments.

    Science.gov (United States)

    Hwang, R-L; Chen, C-P

    2010-06-01

    This study investigated the thermal sensation of elderly people in Taiwan, older than 60 years, in indoor microclimate at home, and their requirements for establishing thermal comfort. The study was conducted using both a thermal sensation questionnaire and measurement of indoor climatic parameters underlying the thermal environment. Survey results were compared with those reported by Cheng and Hwang (2008, J. Tongji Univ., 38, 817-822) for non-elders to study the variation between different age groups in requirements of indoor thermal comfort. The results show that the predominant strategy of thermal adaptation for elders was window-opening in the summer and clothing adjustment in the winter. The temperature of thermal neutrality was 25.2 degrees C and 23.2 degrees C for the summer and the winter, respectively. Logistically regressed probit modeling on percentage of predicted dissatisfied (PPD) against mean thermal sensation vote revealed that the sensation votes corresponding to a PPD of 20% were +/- 0.75 for elders, about +/- 0.10 less than the levels projected by ISO 7730 model. The range of operative temperature for 80% thermal acceptability for elders in the summer was 23.2-27.1 degrees C, narrower than the range of 23.0-28.6 degrees C reported for non-elders. This is likely a result of a difference in the selection of adaptive strategies. Taiwan in the last decade has seen a rapid growth in the elderly population in its societal structure, and as such the quality of indoor thermal comfort increasingly concerns the elderly people. This study presents the results from field-surveying elders residing in major geographical areas of Taiwan, and discusses the requirements of these elders for indoor thermal comfort in different seasons. Through a comparison with the requirements by non-elders, this study demonstrates the unique sensitivity of elders toward indoor thermal quality and the selection of adaptive strategies that need to be considered when a thermal

  3. Processing emotions in children with Moebius syndrome. A behavioral and thermal imaging study

    OpenAIRE

    Nicolini, Ylenia

    2018-01-01

    According to the “facial feedback hypothesis”, the proprioceptive feedback from facial muscles while mimicking face movements is crucial in regulating emotional experience. Facial mimicry, intended as a spontaneous reaction of individuals when observing emotional faces, plays a key role in understanding others’ facial expression of emotions. Studies on facial expression processing and emotion understanding have revealed that the neuronal bases of facial mimicry are underpinned by a mirror mec...

  4. Silica Gel Behavior Under Different EGS Chemical And Thermal Conditions: An Experimental Study

    International Nuclear Information System (INIS)

    Hunt, J.D.; Ezzedine, S.M.; Bourcier, W.; Roberts, S.

    2012-01-01

    Fractures and fracture networks are the principal pathways for migration of water and contaminants in groundwater systems, fluids in enhanced geothermal systems (EGS), oil and gas in petroleum reservoirs, carbon dioxide leakage from geological carbon sequestration, and radioactive and toxic industrial wastes from underground storage repositories. When dealing with EGS fracture networks, there are several major issues to consider, e.g., the minimization of hydraulic short circuits and losses of injected geothermal fluid to the surrounding formation, which in turn maximize heat extraction and economic production. Gel deployments to direct and control fluid flow have been extensively and successfully used in the oil industry for enhanced oil recovery. However, to the best of our knowledge, gels have not been applied to EGS to enhance heat extraction. In-situ gelling systems can either be organic or inorganic. Organic polymer gels are generally not thermostable to the typical temperatures of EGS systems. Inorganic gels, such as colloidal silica gels, however, may be ideal blocking agents for EGS systems if suitable gelation times can be achieved. In the current study, we explore colloidal silica gelation times and rheology as a function of SiO 2 concentration, pH, salt concentration, and temperature, with preliminary results in the two-phase field above 100 C. Results at 25 C show that it may be possible to choose formulations that will gel in a reasonable and predictable amount of time at the temperatures of EGS systems.

  5. Thermal and Dielectric Behavior Studies of Poly(Arylene Ether Sulfones with Sulfonated and Phosphonated Pendants

    Directory of Open Access Journals (Sweden)

    Shimoga D. Ganesh

    2016-01-01

    Full Text Available The present paper discusses the aspects of the synthesizing valeric acid based poly(ether sulfones with active carboxylic acid pendants (VALPSU from solution polymerization technique via nucleophilic displacement polycondensation reaction among 4,4′-dichlorodiphenyl sulfone (DCDPS and 4,4′-bis(4-hydroxyphenyl valeric acid (BHPA. The conditions necessary to synthesize and purify the polymer were investigated in some detail. The synthesized poly(ether sulfones comprise sulfone and ether linkages in addition to reactive carboxylic acid functionality; these active carboxylic acid functional groups were exploited to hold the phenyl sulphonic acid and phenyl phosphonic acid pendants. The phenyl sulphonic acid pendants in VALPSU were easily constructed by altering active carboxylic acid moieties by sulfanilic acid using N,N′-dicyclohexylcarbodiimide (DCC mediated mild synthetic route, whereas the latter one was built in two steps. Initially, polyphosphoric acid condensation with VALPSU by 4-bromoaniline and next straightforward palladium catalyzed synthetic route, in both of which acidic pendants are clenched by polymer backbone via amide linkage. Without impairing the primary polymeric backbone modified polymers were prepared by varying the stoichiometric ratios of respective combinations. All the polymers were physicochemically characterized and pressed into tablets; electrical contacts were established to study the dielectric properties. Finally, the influence of the acidic pendants on the dielectric properties was examined.

  6. Neuronal networks for the study of buildings thermal behavior; Redes neuronales para el estudio del comportamiento termico de edificios

    Energy Technology Data Exchange (ETDEWEB)

    Marincic, Irene [Universidad de Sonora (Mexico); Del Rio, J. Antonio [Centro Morelense de Innovacion y Transferencia Tecnologica (Mexico)

    2009-07-15

    The evaluation as well as the prediction of buildings thermal behavior involves complex calculations mainly because of its enormous number of variables, many of them difficult to determine. For this type of problems, a possibility is to resort to models of the black box type, that allow the characterization of the building with very few variables, for then to be able to predict its behavior under other circumstances, with greater certainty. One of the black box models of more and more used in diverse disciplines, is the one of the artificial neuronal networks (ANN). These can be used as an alternative method of analysis and prediction, particularly for cases in which many variables take part. In this work a preliminary study is presented that analyzes the accuracy of a model of neuronal network for the prediction of the inside temperatures of a building, given the outside temperatures. A very simple network, of 3 neurons, located in 2 layers is considered. The results of the inside temperatures obtained in the learning as well as in the prediction stage are analyzed, comparing them with the ones obtained using another model of black box previously developed by the authors, the one of the function responded in the dominion of frequencies. [Spanish] Tanto la evaluacion como la prediccion del comportamiento termico de los edificios involucra calculos complejos sobre todo por su enorme numero de variables, muchas de ellas dificiles de determinar. Para este tipo de problemas, una posibilidad es recurrir a modelos del tipo caja negra, que permiten caracterizar al edificio como muy pocas variables, para luego poder predecir su comportamiento bajo otras circunstancias, como mayor certeza. Uno de los modelos de caja negra cada vez mas utilizado en diversas disciplinas, es el de las redes neuronales artificiales (ANN). Estas pueden ser usadas como metodo alternativo de analisis y sobre todo de prediccion, particularmente para los casos en que intervienen muchas variables. En

  7. Analytical study on thermal-hydraulic behavior of transient from forced circulation to natural circulation in JRR-3

    International Nuclear Information System (INIS)

    Hirano, Masashi; Sudo, Yukio

    1986-01-01

    Transient thermal-hydraulic behaviors of the JRR-3 which is an open-pool type research reactor has been analyzed with the THYDE-P1 code. The focal point is the thermal-hydraulic behaviors related to the core flow reversal during the transition from forced circulation downflow to natural circulation upflow. In the case of a loss-of-coolant accident (LOCA), for example, the core flow reversal is expected to occur just after the water pool isolation from the primary cooling loop with a leak. The core flow reversal should cause a sudden increase in fuel temperature and a steep decrease in the departure-from-nucleate-boiling ratio (DNBR) and the phenomenon is, therefore, very important especially for safety design and evaluation of research reactors. Major purposes of the present work are to clarify physical phenomena during the transient and to identify important parameters affecting the peak fuel temperature and the minimum DNBR. The results calculated with THYDE-P1 assuming the sequences of events of the loss-of-offsite power and LOCA help us to understand the phenomena both qualitatively and quantitatively, with respect to the safety design and evaluation. (author)

  8. Fission gas behavior during fast thermal transients

    International Nuclear Information System (INIS)

    Esteves, R.G.

    1976-01-01

    The behavior of non-equilibrium fission in fuel elements undergoing fast thermal transients is analyzed. To facilitate the analysis, a new variable, the equilibrium variable (EV) is defined. This variable, together with bubble radius, completely specifies a bubble with respect to its size and equilibrium condition. The analysis is coded using a two-variable (radius and EV) multigroup numerical approximation that accepts as input the time-temperature history, the time-fission rate history, and the time-thermal gradient history of the fuel element. Studies were performed to test the code for convergence with respect to the time interval and the number of groups chosen. For a series of transient simulation studies, the measurements obtained at HEDL (microscopic examination of intragranular porosity in oxide fuel transient-tested in TREAT) are used. Two different transient histories were selected; the first, a high-temperature transient (HTT) with a peak at 2477 0 K and the second, a low-temperature transient (LTT) with a peak-temperature at 2000 0 K. The LTT was simulated for three different conditions: Bubbles were allowed to move via (a) only biased migration, (b) via random migration, and (c) via both mechanisms. The HTT was also run for both mechanisms. The agreement with HEDL microscopic observations was fair for bubbles smaller than 964 A in diameter, and poor for larger bubbles. Bubbles that grew during the heat-up part of the transient were frozen at a larger size during the cool down

  9. Effect of microscale gaseous thermal conduction on the thermal behavior of a buckled microbridge

    International Nuclear Information System (INIS)

    Wang Jiaqi; Tang Zhenan; Li Jinfeng; Zhang Fengtian

    2008-01-01

    A microbridge is a basic micro-electro-mechanical systems (MEMS) device and has great potential for application in microsensors and microactuators. The thermal behavior of a microbridge is important for designing a microbridge-based thermal microsensor or microactuator. To study the thermal behavior of a microbridge consisting of Si 3 N 4 and polysilicon with a 2 µm suspended gap between the substrate and the microbridge while the microbridge is heated by an electrical current fed through the polysilicon, a microbridge model is developed to correlate theoretically the input current and the temperature distribution under the buckling conditions, especially considering the effects of the microscale gaseous thermal conduction due to the microbridge buckling. The calculated results show that the buckling of the microbridge changes the microscale gaseous thermal conduction, and thus greatly affects the thermal behavior of the microbridge. We also evaluate the effects of initial buckling on the temperature distribution of the microbridge. The experimental results show that buckling should be taken into account if the buckling is large. Therefore, the variation in gaseous thermal conduction and the suspended gap height caused by the buckling should be considered in the design of such thermomechanical microsensors and microactuators, which requires more accurate thermal behavior

  10. Thermal expansion behavior in fabricated cellular structures

    International Nuclear Information System (INIS)

    Oruganti, R.K.; Ghosh, A.K.; Mazumder, J.

    2004-01-01

    Thermal expansion behavior of cellular structures is of interest in applications where undesirable deformation and failure are caused by thermal expansion mismatch. This report describes the role of processing-induced effects and metallurgical aspects of melt-processed cellular structures, such as a bi-material structure designed to contract on heating, as well as uni-material structures of regular and stochastic topology. This bi-material structure utilized the principle of internal geometric constraints to alter the expansion behavior of the internal ligaments to create overall contraction of the structure. Homogenization design method was used to design the structure, and fabrication was by direct metal deposition by laser melting of powder in another part of a joint effort. The degree of porosity and grain size in the fabricated structure are characterized and related to the laser deposition parameters. The structure was found to contract upon heating over a short range of temperature subsequent to which normal expansion ensued. Also examined in this report are uni-material cellular structures, in which internal constraints arise from residual stress variations caused by the fabrication process, and thereby alter their expansion characteristics. A simple analysis of thermal strain of this material supports the observed thermal expansion behavior

  11. Thermal Scanning Conductometry (TSC) as a General Method for Studying and Controlling the Phase Behavior of Conductive Physical Gels.

    Science.gov (United States)

    Bielejewski, Michal

    2018-01-23

    The thermal scanning conductometry protocol is a new approach in studying ionic gels based on low molecular weight gelators. The method is designed to follow the dynamically changing state of the ionogels, and to deliver more information and details about the subtle change of conductive properties with an increase or decrease in the temperature. Moreover, the method allows the performance of long term (i.e. days, weeks) measurements at a constant temperature to investigate the stability and durability of the system and the aging effects. The main advantage of the TSC method over classical conductometry is the ability to perform measurements during the gelation process, which was impossible with the classical method due to temperature stabilization, which usually takes a long time before the individual measurement. It is a well-known fact that to obtain the physical gel phase, the cooling stage must be fast; moreover, depending on the cooling rate, different microstructures can be achieved. The TSC method can be performed with any cooling/heating rate that can be assured by the external temperature system. In our case, we can achieve linear temperature change rates between 0.1 and approximately 10 °C/min. The thermal scanning conductometry is designed to work in cycles, continuously changing between heating and cooling stages. Such an approach allows study of the reproducibility of the thermally reversible gel-sol phase transition. Moreover, it allows the performance of different experimental protocols on the same sample, which can be refreshed to initial state (if necessary) without removal from the measuring cell. Therefore, the measurements can be performed faster, in a more efficient way, and with much higher reproducibility and accuracy. Additionally, the TSC method can be also used as a tool to manufacture the ionogels with targeted properties, like microstructure, with an instant characterization of conductive properties.

  12. Thermal-hydraulically controlled blowdown tests in the experimental facility COSIMA to study PWR fuel behavior: experimental and theoretical results

    International Nuclear Information System (INIS)

    Class, G.; Hain, K.; Meyder, R.

    1978-01-01

    The fuel behavior in the blow-down phase of a LOCA is of importance for fuel rods with high internal pressure and high rod power, because of the effects on clad failure of the small cladding deformations occurring. The operating results of the COSIMA facility show that, on the basis of the new developments for measuring technique and fuel rod simulators performed, reactor relevant blow-down performances can be conducted in a controlled and reproduceable manner. The mechanical and thermal-hydraulic states occurring in the test bed may be subject to computational checking. This permits on one hand to improve the computing models and on the other yields a confirmation of the high state of development of the available computer codes. Therefore it appears that, with the results from COSIMA and the associated theoretical work in the field of the blow-down process, difficult to treat experimentally, an essential contribution to verifying the models for accident calculations is given. The work scheduled for the next about 1 1/2 years will serve to further support the rather preliminary results and to extend the range of then application. (orig.) [de

  13. Comparative study of structural and thermal behavior of aromatic polyester;Estudo comparativo do comportamento termico e estrutral de poliesteres aromaticos

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Diego K.M., E-mail: diego_keller_1984@yahoo.com.b; Guimaraes, Danilo H.; Medeiros, Marina O. de A.; Jose, Nadia M. [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil). Inst. de Quimica; Prado, Luis A.S. de A. [Technische Universitaet Hamburg (TUHH), Harburg (Germany). Inst. of Polymer and Composites

    2009-07-01

    Aromatic polyesters have been currently used for the production of PET bottles and polymer fibers. Currently, thermodynamic study is necessary for production of polymers with mechanical properties, thermal degradation and satisfactory. Many thermodynamic properties of polymer solutions, such as solubility, swelling, and balance of the properties Colligative can be expressed in terms of interaction parameter of polymer-solvent {chi}. The present work presents the objective synthesize, characterize and assess the degree of swelling of aromatic polyesters. The polyester formed from the reaction of glycerol and terephthalic acid/phthalic, using varying molar ratios to the glycerolterephthalic acid/phthalic acid (1,0-1,0, 1,0-1,5, 1,0 -- 2.0), by mixing with mechanical agitation and by use of tin catalyst. We studied the thermal and structural behavior through techniques: FTIR, TGA, DSC, XRD, SEM and swelling test. (author)

  14. The study of the thermal behavior of solid mixtures of metakaolin and sodium hydroxide by isoconversional model-free analyzes

    Science.gov (United States)

    Gordina, Natalya E.; Prokof'ev, Valery Yu; Smirnov, Nikolay N.; Khramtsova, Alexandra P.

    2017-11-01

    Interactions in solid mixtures of 6Al2Si2O7: 12NaOH and 6Al2Si2O7: 12NaOH: 2Al2O3 under thermal treatment were studied. Ultrasonic pre-treatment of suspensions with a frequency of 22 kHz was applied. X-ray phase analysis, scanning electron microscopy, and synchronous thermal analysis were used in this research. It was shown that after evaporation of the suspensions, the hydrated LTA zeolite and sodium hydroaluminate are synthesized. During thermal treatment up to 500 °C, the adsorption water is removed first and then the dehydration of the zeolite and hydroaluminate occurs. Calcination at temperatures above 500° C leads to the synthesis of Na6Al4Si4O17 and Na8Al4Si4O18 by the interaction of metakaolin and zeolite with sodium hydroxide. At temperatures above 700 °C, the formation of mullite and nepheline occurs in the temperature range of 500-800 °C. The kinetic parameters have been calculated using Friedman analysis (differential method), Kissinger-Akahira-Sunose and Ozawa-Flynn-Wall analyzes (integral methods). It was shown that all analyzes give similar dependences of the apparent activation energy vs the conversion extent and the values of E are in the range of 70-350 kJ mol-1. It was established that ultrasonic pre-treatment allows to reduce the values of the apparent activation energy. It was discovered that the Al2O3 excess over the stoichiometry of the LTA zeolite synthesis is an inhibitor of the mullite and nepheline formation reactions.

  15. Structural in situ study of the thermal behavior of manganese dioxide materials: toward selected electrode materials for supercapacitors.

    Science.gov (United States)

    Ghodbane, Ouassim; Pascal, Jean-Louis; Fraisse, Bernard; Favier, Frédéric

    2010-12-01

    The thermal behavior of a series of MnO2 materials was investigated toward MnO2 microstructures under inert atmospheres. The byproduct formed during MnO2 heat treatments from the room temperature to 800 °C were characterized by in situ X-ray diffraction analyses. It was found that annealing spinel and ramsdellite phases caused the formation of MnO2 pyrolusite at 200 °C, Mn2O3, at 400 °C, and then Mn3O4 at higher temperatures. In the case of cryptomelane and birnessite phases, the heating process resulted in the formation of K0.51Mn0.93O2 at 600 °C, while Mn3O4 was also formed and still present up to 800 °C. Heat-treating Ni-todorokite and OMS-5 up to about 450 °C led to the formation of NiMn2O4 and NaxMnO2, respectively, and again Mn3O4 at higher temperatures. All of these structural transformations were correlated to resulting weight losses of MnO2 powders, measured by thermogravimetric analyses, during the heating process. Cyclic voltammetry measurements were performed in the presence of 0.5 M K2SO4 aqueous solution for annealed cryptomelane, K0.51Mn0.93O2, and Mn3O4-based electrodes. It was found that MnO2 cryptomelane is electrochemically stable upon heating. The long-term charge/discharge voltammetric cycling revealed that the specific capacitance of Mn3O4-based electrode is significantly improved from 14 F·g(-1) (after 20 cycles) to 123 F·g(-1) (after 500 cycles).

  16. Study of thermal behavior of vitamin D3 by pyrolysis-GC-MS in combination with boiling point-retention time correlation.

    Science.gov (United States)

    Sun, Yu'an; Liu, Baoxia; Wang, Guoqing; Zhang, Rongjie; Xie, Bing

    2005-01-01

    The thermal behavior of vitamin D3 was studied based on pyrolysis-GC-MS technique. It was pyrolyzed at 600 degrees C, 750 degrees C, 900 degrees C, respectively. The pyrolysis product were separated With an HP-5 column and identified by the NIST mass spectral search program in combination with the correlation of boiling point and retention time (BP-RT). There are totally 50 components, including mono aromatics and polycyclic aromatic hydrocarbons (PAHs), were determined. It is shown that the contents of the PAHs are increasing with the increasing of the pyrolysis temperature. The contents of the determined components vary from 0.04% to 37.08%.

  17. BEHAVIOR OF THERMAL SPRAY COATINGS AGAINST HYDROGEN ATTACK

    OpenAIRE

    Vargas, Fabio; Latorre, Guillermo; Uribe, Iván

    2003-01-01

    The behavior of nickel and chrome alloys applied as thermal spray coatings to be used as protection against embrittlement by hydrogen is studied. Coatings were applied on a carbon steel substrate, under conditions that allow obtain different crystalline structures and porosity levels, in order to determine the effect of these variables on the hydrogen permeation kinetics and as a protection means against embrittlement caused this element. In order to establish behaviors as barriers and protec...

  18. Investigation of thermal fatigue behavior of thermal barrier coating systems

    International Nuclear Information System (INIS)

    Zhu Dongming; Miller, R.A.

    1997-01-01

    In the present study, the mechanisms of fatigue crack initiation and propagation, and of coating failure under thermal loads that simulate those in diesel engines are investigated. Surface cracks initiate early and grow continuously under thermal low cycle fatigue (LCF) and high cycle fatigue (HCF) stresses. It is found that, in the absence of interfacial oxidation, the failure associated with LCF is closely related to coating sintering and creep at high temperatures. Significant LCF and HCF interactions have been observed in the thermal fatigue tests. The fatigue crack growth rate in the ceramic coating strongly depends on the characteristic HCF cycle number, N* HCF which is defined as the number of HCF cycles per LCF cycle. The crack growth rate is increased from 0.36 μm/LCF cycle for a pure LCF test to 2.8 μm/LCF cycle for a combined LCF and HCF test at N* HCF about 20 000. A surface wedging model has been proposed to account for the HCF crack growth in the coating systems. This mechanism predicts that the HCF damage effect increases with heat flux and thus with increasing surface temperature swing, thermal expansion coefficient and elastic modulus of the ceramic coating, as well as with the HCF interacting depth. Good correlation has been found between the analysis and experimental evidence. (orig.)

  19. Anisotropic Thermal Behavior of Silicone Polymer, DC 745

    Energy Technology Data Exchange (ETDEWEB)

    Adams, Jillian Cathleen [Univ. of Oregon, Eugene, OR (United States). Dept. of Chemistry; Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Torres, Joseph Angelo [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Volz, Heather Michelle [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Gallegos, Jennifer Marie [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Yang, Dali [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-09-02

    In material applications, it is important to understand how polymeric materials behave in the various environments they may encounter. One factor governing polymer behavior is processing history. Differences in fabrication will result in parts with varied or even unintended properties. In this work, the thermal expansion behavior of silicone DC 745 is studied. Thermomechanical analysis (TMA) is used to determine changes in sample dimension resulting from changes in temperature. This technique can measure thermal events such as the linear coefficient of thermal expansion (CTE), melting, glass transitions, cure shrinkage, and internal relaxations. Using a thermomechanical analyzer (Q400 TMA), it is determined that DC 745 expands anisotropically when heated. This means that the material has a different CTE depending upon which direction is being measured. In this study, TMA experiments were designed in order to confirm anisotropic thermal behavior in multiple DC 745 samples of various ages and lots. TMA parameters such as temperature ramp rate, preload force, and temperature range were optimized in order to ensure the most accurate and useful data. A better understanding of the thermal expansion of DC 745 will allow for more accurate modeling of systems using this material.

  20. Effect of Surface Impulsive Thermal Loads on Fatigue Behavior of Constant Volume Propulsion Engine Combustor Materials

    National Research Council Canada - National Science Library

    Zhu, Dongming

    2004-01-01

    .... In this study, a simulated engine test rig has been established to evaluate thermal fatigue behavior of a candidate engine combustor material, Haynes 188, under superimposed CO2 laser surface impulsive thermal loads (30 to 100 Hz...

  1. A study of growth and thermal dewetting behavior of ultra-thin gold films using transmission electron microscopy

    Directory of Open Access Journals (Sweden)

    Sudheer

    2017-07-01

    Full Text Available The growth and solid-state dewetting behavior of Au thin films (0.7 to 8.4 nm deposited on the formvar film (substrate by sputtering technique have been studied using transmission electron microscopy. The size and number density of the Au nanoparticles (NPs change with an increase in the film thickness (0.7 to 2.8 nm. Nearly spherical Au NPs are obtained for 6 nm show capability to be used as an irreversible temperature sensor with a sensitivity of ∼0.1 CAF/°C. It is observed that annealing affects the crystallinity of the Au grains in the films. The electron diffraction measurement also shows annealing induced morphological evolution in the percolated Au thin films (≥3 nm during solid-state dewetting and recrystallization of the grains.

  2. The impact of thermal wave characteristics on thermal dose distribution during thermal therapy: A numerical study

    International Nuclear Information System (INIS)

    Shih, T.-C.; Kou, H.-S.; Liauh, C.-T.; Lin, W.-L.

    2005-01-01

    The aim of this study was to investigate the effects of the propagation speed of a thermal wave in terms of the thermal relaxation time on the temperature/thermal dose distributions in living tissue during thermal therapies. The temperature field in tissue was solved by the finite difference method, and the thermal dose was calculated from the formulation proposed by Sapareto and Dewey [Int. J. Radiat. Oncol. Biol. Phys. 10, 787-800 (1984)]. Under the same total deposited energy, for a rapid heating process the time lagging behavior of the peak temperature became pronounced and the level of the peak temperature was decreased with increasing the thermal relaxation time. When the heating duration was longer than the thermal relaxation time of tissues, there was no significant difference between the thermal dose distributions with/without considering the effect of the thermal relaxation time. In other words, when the heating duration is comparable to or shorter than the thermal relaxation time of tissue, the results of the wave bioheat transfer equation (WBHTE) are fully different from that of the Pennes' bioheat transfer equation (PBHTE). Besides, for a rapid heating process the dimension of thermal lesion was still significantly affected by perfusion, because this is what is predicted by the WBHTE but not by the PBHTE, i.e., the wave feature of the temperature field cannot fully be predicted by the PBHTE

  3. MR scanning, tattoo inks, and risk of thermal burn: An experimental study of iron oxide and organic pigments: Effect on temperature and magnetic behavior referenced to chemical analysis.

    Science.gov (United States)

    Alsing, K K; Johannesen, H H; Hvass Hansen, R; Dirks, M; Olsen, O; Serup, J

    2018-05-01

    Tattooed persons examined with magnetic resonance imaging (MRI) can develop burning sensation suggested in the literature to be thermal burn from the procedure. MRI-induced thermal effect and magnetic behavior of known tattoo pigments were examined ex vivo. Magnetic resonance imaging effects on 3 commonly used commercial ink stock products marketed for cosmetic tattooing was studied. A main study tested 22 formulations based on 11 pigment raw materials, for example, one line of 11 called pastes and another called dispersions. Samples were spread in petri dishes and tested with a 0.97 T neodymium solid magnet to observe visual magnetic behavior. Before MRI, the surface temperature of the ink was measured using an infrared probe. Samples were placed in a clinical 3T scanner. Two scans were performed, that is, one in the isocenter and one 30 cm away from the center. After scanning, the surface temperature was measured again. Chemical analysis of samples was performed by mass spectroscopy. Mean temperature increase measured in the isocenter ranged between 0.14 and 0.26°C (P < .01) and in the off-center position from -0.16 to 0.21°C (P < .01). Such low increase of temperature is clinically irrelevant. Chemical analysis showed high concentrations of iron, but also nickel and chrome were found as contaminants. High concentration of iron was not associated with any increase of temperature or any physical draw or move of ink. The study could not confirm any clinically relevant temperature increase of tattoo pigments after MRI. © 2017 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

  4. Influence of PCMs on thermal behavior of building walls: experimental study using the walls of a reduced scale room

    Directory of Open Access Journals (Sweden)

    Gounni Ayoub

    2017-01-01

    Full Text Available Using Phase-Change Materials (PCM for lightweight building applications can increase equivalent thermal mass and provide energy savings. In the present experimental work, the heat transfer performance testing of some building walls, with or without PCM, is carried out using a reduced-scale cubic room (the test-cell. The cubic cell is heated by an incandescent bulb placed on its centre, and it is housed in an air-conditioned large-scale room that allows to control the ambient air temperature. The effect of the double PCM layer and of its location relatively to the outside surface of the wall is tested and discussed in terms of overall transmitted heat flux and in terms of reduction of the inside and outside surface temperatures. Findings shows that the additional inertia introduced by the PCM leads to a reduced overall heat flux transmission by the wall and to a lesser daily temperature amplitude on the surface of the wall that enhances the thermal comfort inside the building. In the next step of this work, the case of sandwich walls with air gap, and with wood and PCM layers will be considered.

  5. Influence of PCMs on thermal behavior of building walls: experimental study using the walls of a reduced scale room

    Science.gov (United States)

    Gounni, Ayoub; Tahar Mabrouk, Mohamed; Kheiri, Abdelhamid; El alami, Mustapha

    2017-11-01

    Using Phase-Change Materials (PCM) for lightweight building applications can increase equivalent thermal mass and provide energy savings. In the present experimental work, the heat transfer performance testing of some building walls, with or without PCM, is carried out using a reduced-scale cubic room (the test-cell). The cubic cell is heated by an incandescent bulb placed on its centre, and it is housed in an air-conditioned large-scale room that allows to control the ambient air temperature. The effect of the double PCM layer and of its location relatively to the outside surface of the wall is tested and discussed in terms of overall transmitted heat flux and in terms of reduction of the inside and outside surface temperatures. Findings shows that the additional inertia introduced by the PCM leads to a reduced overall heat flux transmission by the wall and to a lesser daily temperature amplitude on the surface of the wall that enhances the thermal comfort inside the building. In the next step of this work, the case of sandwich walls with air gap, and with wood and PCM layers will be considered.

  6. Lipophilic phytosterol derivatives: synthesis, thermal property and nanoemulsion behavior

    DEFF Research Database (Denmark)

    Panpipat, Worawan; Xu, Xuebing; Guo, Zheng

    Phytosterols and their esters have been reported as a cholesterol lowering agent in human. However, natural phytosterols have a low solubility in both water and fat resulting in a poor absorption in intestine. To improve the intestinal absorption and bioavailability of phytosterols, conversion...... of phytosterols into enzyme-liable lipophilic derivatives, such as fatty acid esters was one of the possible strategies. Differences in molecular structures of modified phytosterols may result in the differences in their thermal and micelling behaviors. Therefore, the objectives of this study were to improve...... the productive yield of a series of -sitosteryl fatty acid esters (C2-C18) and to investigate the thermal property and nano-emulsion behaviors of those compounds. This work reported a novel approach to synthesize phytosterol (-sitosterol as a model) fatty acid ester by employing Candida antarctica lipase...

  7. Thermal behavior of spatial structures under solar irradiation

    International Nuclear Information System (INIS)

    Liu, Hongbo; Liao, Xiangwei; Chen, Zhihua; Zhang, Qian

    2015-01-01

    The temperature, particularly the non-uniform temperature under solar irradiation, is the main load for large-span steel structures. Due the shortage of in-site temperature test in previous studies, an in-site test was conducted on the large-span steel structures under solar irradiation, which was covered by glass roof and light roof, to gain insight into the temperature distribution of steel members under glass roof or light roof. A numerical method also was presented and verified to forecast the temperature of steel member under glass roof or light roof. Based on the on-site measurement and numerical analyses conducted, the following conclusions were obtained: 1) a remarkable temperature difference exists between the steel member under glass roof and that under light roof, 2) solar irradiation has a significant effect on the temperature distribution and thermal behavior of large-span spatial structures, 3) negative thermal load is the controlling factor for member stress, and the positive thermal load is the controlling factor for nodal displacement. - Highlights: • Temperature was measured for a steel structures under glass roof and light roof. • Temperature simulation method was presented and verified. • The thermal behavior of steel structures under glass or light roof was presented

  8. Thermal fatigue behavior of thermal barrier coatings by air plasma spray

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Han Sang; Kim, Eui Hyun [Korea Electric Power Research Institute, Daejeon (Korea, Republic of); Lee, Jung Hyuk [Korea Plant Service and Engineering Co. Ltd., Incheon (Korea, Republic of)

    2008-06-15

    Effects of top coat morphology and thickness on thermal fatigue behavior of Thermal Barrier Coatings (TBC) were investigated in this study. Thermal fatigue tests were conducted on three coating specimens with different top coat morphology and thickness, and then the test data were compared via microstructures, cycles to failure, and fracture surfaces. In the air plasma spray specimens (APS1, APS2), top coat were 200 and 300 {mu}m respectively. The thickness of top coat was about 700 {mu}m in the Perpendicular Cracked Specimen (PCS). Under thermal fatigue condition at 1,100 .deg. C, the cycles to top coat failure of APS1, APS2, and PCS were 350, 560 and 480 cycles, respectively. The cracks were initiated at the interface of top coat and Thermally Grown Oxide (TGO) and propagated into TGO or top coat as the number of thermal fatigue cycles increased. For the PCS specimen, additive cracks were initiated and propagated at the starting points of perpendicular cracks in the top coat. Also, the thickness of TGO and the decrease of aluminium concentration in bond coat do not affect the cycles to failure.

  9. Thermal behavior of halogenated imidebismaleimide resins

    International Nuclear Information System (INIS)

    Mohammad, A.; Al-Halim, N.Z.

    1995-01-01

    Several new poly-halogenated malecimides, bismaleimides and therir copoly resins were synthessised thermally from their corresponding amic acids. The synthesis was accomplished by two way method (amic acid-polimide) instead of the well-known three way method (amic acid-imide-polyimide). Thermal characterization of monomers and their cured resins was achieved using differential thermal analysis (DTA), dynamic thermogravimetric analysis (TGA) and isothermal gravimetric analysis (IGA). The effect of halogen substituent, especially in the ortho postion, is clear in the imidization proces, while polymerization proceeds almost equally in all systems. Thermal properties of homo and copolymers were correlated with their chemical structures. (author). 15 refs., 4

  10. Numerical study of the thermal behavior of a new deicing road structure design with energy harvesting capabilities

    Science.gov (United States)

    Le Touz, Nicolas; Dumoulin, Jean

    2015-04-01

    Facing the heavy organisational, financial and environmental constraints imposed by usual winter maintenance salting operations, pavement engineers have been led to look for alternative solutions to avoid ice or snow deposit at pavements surface. Among the solutions, one is self-de-icing heating pavements, for which two technologies have been developed so far: one is based on embedded coils circulating a heated calorific fluid under the pavement surface; the other one relies on the use of embedded resistant electric wires. The use and operation of such systems in the world is still limited and was only confined to small road stretches or specific applications, such as bridges which are particularly sensitive to frost. One of the most significant "coil technology" example in Europe is the SERSO-System (Solar Energy recovery from road surfaces) built in 1994, on a Switzerland bridge. Many of these experiences are referenced in the technical literature, which provides state-of-the art papers (see for instance Eugster) and useful detailed information dealing with the construction and operational management of such installation. The present study is taking part of the Forever Open Road Concept addressed by the R5G: 5th Generation Road [1], one of the major project supported by IFSTTAR. It considers a different design of self-de-icing road that simplify its mode of construction and maintenance, compared to the two technologies mentioned above. It should also be noted that similar to pavements instrumented with coils, such structure could be used in the reversible way to capture the solar energy at the pavement surface during sunny days and store it, to either warm the pavement at a later stage or for exogenous needs (e.g. contribution to domestic hot water). To complete our study we also considered the use of semi-transparent pavement course wearing in place of the traditional opaque one. In the present study, a 2D model was developed using FEM approach. It combines 2

  11. Simulation and test of the thermal behavior of pressure switch

    Science.gov (United States)

    Liu, Yifang; Chen, Daner; Zhang, Yao; Dai, Tingting

    2018-04-01

    Little, lightweight, low-power microelectromechanical system (MEMS) pressure switches offer a good development prospect for small, ultra-long, simple atmosphere environments. In order to realize MEMS pressure switch, it is necessary to solve one of the key technologies such as thermal robust optimization. The finite element simulation software is used to analyze the thermal behavior of the pressure switch and the deformation law of the pressure switch film under different temperature. The thermal stress releasing schemes are studied by changing the structure of fixed form and changing the thickness of the substrate, respectively. Finally, the design of the glass substrate thickness of 2.5 mm is used to ensure that the maximum equivalent stress is reduced to a quarter of the original value, only 154 MPa when the structure is in extreme temperature (80∘C). The test results show that after the pressure switch is thermally optimized, the upper and lower electrodes can be reliably contacted to accommodate different operating temperature environments.

  12. Non-Fermi-Liquid Behavior in CeRu2Si2 at Ultralow Temperatures Studied by Thermal Expansion and Magnetostriction

    Science.gov (United States)

    Inoue, Daiki; Takama, Hiroyuki; Kaidou, Daisuke; Minegishi, Mitsuyuki; Ueno, Keisuke; Matsumoto, Koichi; Abe, Satoshi; Murayama, Shigeyuki

    2017-12-01

    We report the linear thermal expansion and magnetostriction of the heavy-fermion compound CeRu2Si2 along its a- and c-axes at temperatures down to 10 mK and in magnetic fields up to 9 T using a high-precision capacitive dilatometer. From the magnetostriction measurements, a large anisotropy between values for the coefficient of magnetostriction along the a- and c-axes was found in the Landau-Fermi-liquid (LFL) state. Non-Fermi-liquid (NFL) behavior was observed for both the linear thermal expansion below 60 mK for all applied magnetic fields and the linear magnetostriction below 0.5 T and 300 mK. The results suggest the existence of an additional pressure-driven quantum critical point (QCP), and a crossover from the NFL state to the LFL state occurs in CeRu2Si2 at ambient pressure near the QCP.

  13. ON THE THERMAL BEHAVIOR OF DIFFERENT TANNED BOVINE LEATHERS

    Directory of Open Access Journals (Sweden)

    VARGANICI Cristian-Dragoş

    2017-05-01

    Full Text Available Leather is one of the most globally spread biomaterial which is obtained by the processing of different animal skins. It encompasses a wide palette of applications, from footwear and clothing to upholsteries and different types of furniture [1], [2], [3]. The main constituent of animal skins is collagen, a supramolecular fibrillar protein in the form of a triple helix. This form endows leather with elasticity, good mechanical properties and softness. A major disadvantage resides in the inapplicability of raw animal hides, due to their microbiological instability and decay through rotting. Microbiological stability is obtained through the tanning process, characterized by protein crosslinking and drying afterwards. After tanning the leather exhibits the required properties for the desired specific applications in terms of aspect, availability and sustainability [4], [5]. The study aims to elucidate the thermal decomposition process of chrome-free tanned bovine hide (wet-white using a new product based on titanium and aluminium salts compared with the same hide tanned by chromium salts (wet-blue. The thermal behavior was studied by dynamic thermogravimetry in nitrogen atmosphere, up to 700 oC. A comparative thermal decomposition study between the different tanned bovine leathers was undertaken.

  14. Finite element approach to study the behavior of fluid distribution in the dermal regions of human body due to thermal stress

    Directory of Open Access Journals (Sweden)

    M.A. Khanday

    2015-10-01

    Full Text Available The human body is a complex structure where the balance of mass and heat transport in all tissues is necessary for its normal functioning. The stabilities of intracellular and extracellular fluids are important physiological factors responsible for homoeostasis. To estimate the effects of thermal stress on the behavior of extracellular fluid concentration in human dermal regions, a mathematical model based on diffusion equation along with appropriate boundary conditions has been formulated. Atmospheric temperature, evaporation rate, moisture concentration and other factors affecting the fluid concentration were taken into account. The variational finite element approach has been employed to solve the model and the results were interpreted graphically.

  15. Study of thermal behavior of three different housing prototypes, for a desertic climate; Estudio de comportamiento termico de tres prototipos de vivienda, para un clima desertico

    Energy Technology Data Exchange (ETDEWEB)

    Bojorquez, Gonzalo; Gallegos, Ricardo; Luna, Anibal [Universidad Autonoma de Baja Callifornia, Mexicali, Baja California (Mexico)

    2000-07-01

    The design of housing in Mexico, does not considers the thermal simulation as a support tool. This situation generates projects that are not thermally apt for the natural environment. The use of the thermal simulation to evaluate a building doesn't represents by itself the possibility of internal thermal comfort for the user, but rather it determines the saving levels of energy on air conditioning. The objective of this work is to quantitatively show how a proposal formally designed for a specific climate, plus the use of environmental strategies to adapt it to the climate, has minor climatic requirements than when these factors are not considered. For the development purposes of this work, three different housing prototypes were selected. Two of them where designed according to the climate and using environmental adequation strategies. The thermal behavior was simulated for each case, and the maximum climatic requirement was calculated according to the construction volume. In near future, the use of the thermal simulation to evaluate design proposals and existing buildings must be considered as a basic tool in Mexico, not just for specialists in the area of thermal evaluation, but for all those implicated in the architecture and construction. [Spanish] El diseno de vivienda en Mexico, no considera como herramienta de apoyo la simulacion termica, lo que genera proyectos no aptos termicamente al medio ambiente. El uso de la modelacion termica para la evaluacion de un edificio, no solo representa la posibilidad de confort termico del usuario, sino que determina el nivel de ahorro energetico por climatizacion artificial. El objetivo de este trabajo es mostrar cuantitativamente como una vivienda disenada con estrategias de adecuacion ambiental, tiene un requerimiento de climatizacion menor que aquella donde su diseno no considera el clima donde se proyecta. Para el desarrollo del trabajo se seleccionaron tres prototipos de vivienda diferentes, en dos de los cuales

  16. Thermal behavior of horizontally mixed surfaces on Mars

    Science.gov (United States)

    Putzig, Nathaniel E.; Mellon, Michael T.

    2007-11-01

    Current methods for deriving thermal inertia from spacecraft observations of planetary brightness temperature generally assume that surface properties are uniform for any given observation or co-located set of observations. As a result of this assumption and the nonlinear relationship between temperature and thermal inertia, sub-pixel horizontal heterogeneity may yield different apparent thermal inertia at different times of day or seasons. We examine the effects of horizontal heterogeneity on Mars by modeling the thermal behavior of various idealized mixed surfaces containing differing proportions of either dust, sand, duricrust, and rock or slope facets at different angles and azimuths. Latitudinal effects on mixed-surface thermal behavior are also investigated. We find large (several 100 J m -2 K -1 s -1/2) diurnal and seasonal variations in apparent thermal inertia even for small (˜10%) admixtures of materials with moderately contrasting thermal properties or slope angles. Together with similar results for layered surfaces [Mellon, M.T., Putzig, N.E., 2007. Lunar Planet. Sci. XXXVIII. Abstract 2184], this work shows that the effects of heterogeneity on the thermal behavior of the martian surface are substantial and may be expected to result in large variations in apparent thermal inertia as derived from spacecraft instruments. While our results caution against the over-interpretation of thermal inertia taken from median or average maps or derived from single temperature measurements, they also suggest the possibility of using a suite of apparent thermal inertia values derived from single observations over a range of times of day and seasons to constrain the heterogeneity of the martian surface.

  17. Synthesis and thermal behavior of double copper and potassium pyrophosphate

    International Nuclear Information System (INIS)

    Ciopec, Mihaela; Muntean, Cornelia; Negrea, Adina; Lupa, Lavinia; Negrea, Petru; Barvinschi, Paul

    2009-01-01

    This paper presents the synthesis and thermal behavior of double copper and potassium pyrophosphate, which can be used as a PK fertilizer containing copper as micronutrient. In order to find the conditions for the synthesis of this compound from copper sulphate and potassium pyrophosphate, various Cu 2+ :P 2 O 7 4- molar ratios (0:1-2:1), various molar concentrations of the solutions (0.075; 0.1; 0.15 and 0.2 mol L -1 ) and various temperatures (25, 50, 75 and 100 o C) have been used. The solid product synthesized in optimum conditions for the separation of micronutrient copper from the reaction mass (Cu 2+ :P 2 O 7 4- molar ratio 1:1, concentration 0.1 mol L -1 ) was subjected to a complex study: chemical analysis, thermal analysis, energy dispersive X-ray spectroscopy, scanning electron microscopy and X-ray diffractometry. During heating up to 1000 o C, K 2 Cu 3 (P 2 O 7 ) 2 .3H 2 O loses the crystallization water; several transformations of the phosphates also take place: the decomposition of pyrophosphates to ortho-phosphates; the transformation of ortho-phosphates; the polymerization of a fraction of ortho-phosphates to amorphous phosphates with longer chains; the reorganization of ortho-phosphates and poly-phosphates to pyrophosphates and their crystallization. The decomposition mechanism was confirmed when using the X-ray diffraction patterns of the compound, thermally treated at several temperatures.

  18. Influence of humidity on the thermal behavior of aluminum nanopowders

    International Nuclear Information System (INIS)

    Li Ying; Song Wulin; Xie Changsheng; Zeng Dawen; Wang Aihua; Hu Mulin

    2006-01-01

    Aluminum (Al) nanopowders have increasingly gained attention because of their potential incorporation in explosive and propellant mixtures. This paper reports on a qualitative study on influence of humidity on the thermal behavior of Al nanopowders and the oxidation of aluminum nanoparticles containing a passivating oxide coating. The thermal behaviors were identified by DSC-TG, and Al nanopowders were examined using high-resolution transmission electron microscopy (HRTEM) to understand the stability of the oxide coating in aluminum nanoparticles. It was found that the diameter of Al nanoparticles was in range of 10-100 nm. The original Al nanoparticles were covered by a 3 nm thick compact amorphous oxide layer. After stored for 8 weeks, the oxide layer grew up to 5 nm thick, and the oxidation diffused to the interior of Al nanoparticles. The results indicate that the reactivity of Al nanopowders is deeply influenced by the environment, especially the humidity. The higher relative humidity would accelerate the aging of the Al nanopowders. The DSC-TG results show the oxidation of Al nanoparticles occurs at least in two steps

  19. A Simplified Tool for Predicting the Thermal Behavior and the Energy Saving Potential of Ventilated Windows

    DEFF Research Database (Denmark)

    Zhang, Chen; Heiselberg, Per Kvols; Larsen, Olena Kalyanova

    2016-01-01

    Currently, the studies of ventilated windows mainly rely on complex fluid and thermal simulation software, which require extensive information, data and are very time consuming. The aim of this paper is to develop a simplified tool to assess the thermal behavior and energy performance of ventilat...

  20. Degradation Behavior of Thermal Stabilized Polyacrylonitrile Fibers

    Directory of Open Access Journals (Sweden)

    LEI Shuai

    2017-05-01

    Full Text Available In the temperature range of 300-800℃, 40%-50% of the mass lost during the processing of polyacrylonitrile based carbon fiber (PANCF. Understanding the degradation behavior will be valuable in understanding the formation mechanism of pseudo-graphite structure, and providing theoretic basis for producing high performance carbon fiber and increasing the carbonization yield. The simulation of the degradation progress was carried out on the thermogravimetric analyzer (TGA, the results show that there are two degradation steps for PAN fiber stabilized in air, and controlled by cyclization coefficient and oxygen content. The cyclization coefficient and oxygen content are effective to the density of carbon fiber by influencing the degradation behavior, which cause defects in the fiber. The higher cyclization coefficient leads to form less structural defects and higher density of the fiber; on the contrary, the higher oxygen content leads to form more structural defects and lower density of the fiber.

  1. Field Synergy Analysis and Optimization of the Thermal Behavior of Lithium Ion Battery Packs

    Directory of Open Access Journals (Sweden)

    Hongwen He

    2017-01-01

    Full Text Available In this study, a three dimensional (3D modeling has been built for a lithium ion battery pack using the field synergy principle to obtain a better thermal distribution. In the model, the thermal behavior of the battery pack was studied by reducing the maximum temperature, improving the temperature uniformity and considering the difference between the maximum and maximum temperature of the battery pack. The method is further verified by simulation results based on different environmental temperatures and discharge rates. The thermal behavior model demonstrates that the design and cooling policy of the battery pack is crucial for optimizing the air-outlet patterns of electric vehicle power cabins.

  2. Thermal expansion behaviors of Li{sub 3}AsW{sub 7}O{sub 25}. A case study for comparative Debye temperature for a large polyatomic unit cell

    Energy Technology Data Exchange (ETDEWEB)

    Mangir Murshed, M.; Gesing, Thorsten M. [Solid State Chemical Crystallography, Institute of Inorganic Chemistry and Crystallography, University of Bremen (Germany); MAPEX Center for Materials and Processes, University of Bremen (Germany); Zhao, Pei [Solid State Chemical Crystallography, Institute of Inorganic Chemistry and Crystallography, University of Bremen (Germany); Huq, Ashfia [Chemical and Engineering Materials Division, Oak Ridge National Laboratory, Oak Ridge, TN (United States)

    2018-03-01

    The thermal expansion behavior of Li{sub 3}AsW{sub 7}O{sub 25} has been studied. The temperature-dependent development of crystal structural parameters was obtained from Rietveld refinement using neutron time of flight powder diffraction data. Modeling of the lattice thermal expansion was carried out using a Grueneisen first-order approximation for the zero-pressure equation of state, where the temperature-dependent vibrational energy was calculated taking the Debye-Einstein-Anharmonicity approach. Temperature-dependent Raman spectra shed light on some selective modes with unusual anharmonicity. Debye temperatures were calculated using three different theoretical approaches, namely, thermal expansion, mean-squared isotropic atomic displacement parameter and heat capacity. Similarities as well as discrepancies between the numerical values obtained from different theoretical approaches are discussed. (copyright 2018 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  3. Thermal shock fatigue behavior of TiC/Al2O3 composite ceramics

    Institute of Scientific and Technical Information of China (English)

    SI Tingzhi; LIU Ning; ZHANG Qingan; YOU Xianqing

    2008-01-01

    The thermal shock fatigue behaviors of pure hot-pressed alumina and 30 wt. % TiC/Al2O3 composites were studied. The effect of TiC and Al2O3 starting particle size on the mechanical properties of the composites was discussed. Indentation-quench test was conducted to evaluate the effect of thermal fatigue temperature difference (ΔT) and number of thermal cycles (N) on fatigue crack growth (Δα). The mechanical properties and thermal fatigue resistance of TiC/Al2O3 composites are remarkably improved by the addition of TiC. The thermal shock fatigue of monolithic alumina and TiC/Al2O3 composites is due to a "true" cycling effect (thermal fatigue). Crack deflection and bridging are the predominant reasons for the improvement of thermal shock fatigue resistance of the composites.

  4. Fatigue threshold studies in Fe, Fe-Si, and HSLA steel: Part II. Thermally activated behavior of the effective stress intensity at threshold

    International Nuclear Information System (INIS)

    Yu, W.; Esaklul, K.; Gerberich, W.W.

    1984-01-01

    It is shown that closure mechanisms alone cannot fully explain increasing fatigue thresholds with decreasing test temperature. Implications are that fatigue crack propagation near threshold is a thermally activated process. The effective threshold stress intensity correlate to the thermal component of the flow stress. A fractographic study of the fatigue surface was performed. Water vapor in room air promotes the formation of oxide and intergranular crack growth. At lower temperatures, a brittle-type cyclic cleavage fatigue surface was observed but the ductile process persisted even at 123 K. Arrest marks found on all three modes of fatigue crack growth suggest that fatigue crack growth controlled by the subcell structure near threshold. The effective fatigue threshold may be related to the square root of (one plus the strain rate sensitivity)

  5. Studies on the Biotribological and Biological Behavior of Thermally Oxidized Ti6Al4V for Use in Artificial Cervical Disk

    Science.gov (United States)

    Wang, Song; Li, Junhui; Lu, Junzhe; Tyagi, Rajnesh; Liao, Zhenhua; Feng, Pingfa; Liu, Weiqiang

    2017-05-01

    The artificial cervical disk was simplified and considered as a ball-on-socket model with the material configuration of ultra-high molecular weight polyethylene and Ti6Al4V (PE-on-TC4). In order to improve the wear resistance, an optimized thermal oxidation (TO) coating was applied on TC4 component. The long-term wear behavior of the model was assessed in vitro using a wear simulator under 10 million cycles (MC) testing intervals. The biological behavior was investigated by bone marrow-derived mesenchymal stem cells (BMSCs) cell attachment and cell viability/proliferation assays, respectively. The total average wear rate for PE/TC4 pair was found to be 0.81 mg/MC, whereas the same was about 0.96 mg/MC for PE/TO pair. The wear rate of the metal has been neglected in comparison with that of the mating polymer. PE component was found to suffer severe damage characterized by scratches, fatigue cracks and arc-shaped wear grooves on the edge zone of ball. The dominant wear mechanism was abrasion for metal component while the dominant failure mechanism was a mix of plowing, fatigue and plastic deformation for polymer component. TO coating improved the cell attachment property of TC4, and the cell viability results were also quite good. TO coating protected TC4 from being plowed and avoided the release of toxic metal ions. However, this intensified the wear of PE component. Considering the biotribological and biological behavior in totality, TO coating could still be promising when applied in articulation surfaces.

  6. Fatigue crack growth behavior under cyclic thermal transient stress

    International Nuclear Information System (INIS)

    Ueda, Masahiro; Kano, Takashi; Yoshitoshi, Atsushi.

    1986-01-01

    Thermal fatigue tests were performed using straight pipe specimens subjected to cyclic thermal shocks of liquid sodium, and crack growth behaviors were estimated using striation patterns observed clearly on any crack surface. Crack growth rate under cyclic thermal strain reaches the maximum at one depth, and after that it decreases gradually with crack depth. The peak location of crack growth rate becomes deeper by superposition of constant primary stress. Parallel cracks co-existing in the neighborhood move the peak to shallower location and decrease the maximum crack growth rate. The equivalent stress intensity factor range calculated by Walker's formula is successfully applied to the case of negative stress ratio. Fatigue crack growth rate under cyclic thermal strain agreed well with that under the constant temperature equal to the maximum value in the thermal cycle. Simplified methods for calculating the stress intensity factor and the crack interference factor have been developed. Crack growth behavior under thermal fatigue could be well predicted using numerical analysis results. (author)

  7. Fatigue crack growth behavior under cyclic transient thermal stress

    International Nuclear Information System (INIS)

    Ueda, Masahiro; Kano, Takashi; Yoshitoshi, Atsushi.

    1987-01-01

    Thermal fatigue tests were performed using straight pipe specimens subjected to cyclic thermal shocks of liquid sodium, and crack growth behaviors were estimated using striation patterns observed clearly on any crack surface. Crack growth rate under cyclic thermal strain reaches the maximum at one depth, and after that it decreases gradually with crack depth. The peak location of crack growth rate becomes deeper by superposition of constant primary stress. Parallel cracks co-existing in the neighborhood move the peak to shallower location and decrease the maximum crack growth rate. The equivalent stress intensity factor range calculated by Walker's formula is successfully applied to the case of negative stress ratio. Fatigue crack growth rate under cyclic thermal strain agreed well with that under the constant temperature equal to the maximum value in the thermal cycle. Simplified methods for calculating the stress intensity factor and the crack interference factor have been developed. Crack growth behavior under thermal fatigue could be well predicted using numerical analysis results. (author)

  8. Anisotropic thermal expansion behaviors of copper matrix in β-eucryptite/copper composite

    International Nuclear Information System (INIS)

    Wang Lidong; Xue Zongwei; Qiao Yingjie; Fei, W.D.

    2012-01-01

    Highlights: ► The thermal expansion behaviors of Cu matrix were studied by in situ XRD. ► The expansion of Cu{1 1 1} plane is linear, that of Cu{2 0 0} is nonlinear. ► The anisotropic thermal expansion of Cu is related to the twinning of Cu matrix. ► The twinning of Cu matrix makes the CTE of the composite increasing. - Abstract: A β-eucryptite/copper composite was fabricated by spark plasma sintering process. The thermal expansion behaviors of Cu matrix of the composite were studied by in situ X-ray diffraction during heating process. The results show that Cu matrix exhibits anisotropic thermal expansion behaviors for different crystallographic directions, the expansion of Cu{1 1 1} plane is linear in the temperature range from 20 °C to 300 °C and the expansion of Cu{2 0 0} is nonlinear with a inflection at about 180 °C. The microstructures of Cu matrix before and after thermal expansion testing were investigated using transmission electronic microscope. The anisotropic thermal expansion behavior is related to the deformation twinning formed in the matrix during heating process. At the same time, the deformation twinning of Cu matrix makes the average coefficient of thermal expansion of the composite increase.

  9. Effect of Thermal Cycling on the Tensile Behavior of CF/AL Fiber Metal Laminates

    Directory of Open Access Journals (Sweden)

    Muhammad Farhan Noor

    2017-09-01

    Full Text Available The objective of this research work was to estimate the effect of thermal cycling on the tensile behavior of CARALL composites. Fiber metal laminates (FMLs, based on 2D woven carbon fabric and 2024-T3 Alclad aluminum alloy sheet, was manufactured by pressure molding technique followed by hand layup method. Before fabrication, aluminum sheets were anodized with phosphoric acid to produce micro porous alumina layer on surface. This micro-porous layer is beneficial to produce strong bonding between metal and fiber surfaces in FMLs. The effect of thermal cycling (-65 to +70ºC on the tensile behavior of Cf/Al based FML was studied. Tensile strength was increased after 10 thermal cycles, but it was slightly decreased to some extent after 30, and 50 thermal cycles. Tensile modulus also shown the similar behavior as that of tensile strength.

  10. Thermal expansion behavior of fluor-chlorapatite crystalline solutions

    Science.gov (United States)

    Hovis, G.; Harlov, D.; Gottschalk, M.; Hudacek, W.; Wildermuth, S.

    2009-04-01

    the fluor-chlorapatite series is little affected by composition. This contrasts with relationships in alkali feldspars (Hovis and coworkers, 1997, 1999), which show that K-rich feldspars expand less than Na-rich feldspars. It contrasts also with the behavior of additional AlSi3 feldspars (Hovis and others, 2008), in which room-temperature chemical expansion limits the degree to which the structure can expand thermally. It also differs from expansion in kalsilite crystalline solutions (Hovis and coworkers, 2003, 2006), which depends on K:Na ratio. Among the minerals we have studied previously, only nepheline displays expansion behavior similar to that of fluor-chlorapatite crystalline solutions in that thermal expansion shows little sensitivity to composition. In AlSi3 feldspars and kalsilite one observes a single crystallographically distinct alkali site and a dominating SiO4 tetrahedral framework that limits the vibrational characteristics of the alkali-site occupant(s). Fluor-chlorapatite crystalline solutions have no such structural framework. Moreover, the anion site in the latter changes structural character in the transition from fluorapatite to chlorapatite. This flexibility apparently allows anion vibrational characteristics, coupled with those of Ca polyhedral components, to change continuously and in a compensating manner across the series. The thermal expansion data also imply that volumes of F-Cl mixing in fluor-chlorapatite are constant from room temperature to 1000 °C. References: Cherniak, D.J. (2000) Rare earth element diffusion in apatite. Geochimica et Cosmochimica Acta 64, 3871-3885. Harlov, D.E. and Förster, H-J. (2002) High grade fluid metasomatism on both a local and regional Scale: the Seward Peninsula, Alaska and the Ivrea-Verbano Zone, Northern Italy Part II: phosphate mineral chemistry. Journal of Petrology 43, 801-824. Holland, T.J.B. and Redfern, S.A.T. (1997) Unit-cell refinement: Changing the dependent variable, and use of regression

  11. Thermal Behavior of Cylindrical Buckling Restrained Braces at Elevated Temperatures

    Directory of Open Access Journals (Sweden)

    Elnaz Talebi

    2014-01-01

    Full Text Available The primary focus of this investigation was to analyze sequentially coupled nonlinear thermal stress, using a three-dimensional model. It was meant to shed light on the behavior of Buckling Restraint Brace (BRB elements with circular cross section, at elevated temperature. Such bracing systems were comprised of a cylindrical steel core encased in a strong concrete-filled steel hollow casing. A debonding agent was rubbed on the core’s surface to avoid shear stress transition to the restraining system. The numerical model was verified by the analytical solutions developed by the other researchers. Performance of BRB system under seismic loading at ambient temperature has been well documented. However, its performance in case of fire has yet to be explored. This study showed that the failure of brace may be attributed to material strength reduction and high compressive forces, both due to temperature rise. Furthermore, limiting temperatures in the linear behavior of steel casing and concrete in BRB element for both numerical and analytical simulations were about 196°C and 225°C, respectively. Finally it is concluded that the performance of BRB at elevated temperatures was the same as that seen at room temperature; that is, the steel core yields prior to the restraining system.

  12. Thermal behavior of cylindrical buckling restrained braces at elevated temperatures.

    Science.gov (United States)

    Talebi, Elnaz; Tahir, Mahmood Md; Zahmatkesh, Farshad; Yasreen, Airil; Mirza, Jahangir

    2014-01-01

    The primary focus of this investigation was to analyze sequentially coupled nonlinear thermal stress, using a three-dimensional model. It was meant to shed light on the behavior of Buckling Restraint Brace (BRB) elements with circular cross section, at elevated temperature. Such bracing systems were comprised of a cylindrical steel core encased in a strong concrete-filled steel hollow casing. A debonding agent was rubbed on the core's surface to avoid shear stress transition to the restraining system. The numerical model was verified by the analytical solutions developed by the other researchers. Performance of BRB system under seismic loading at ambient temperature has been well documented. However, its performance in case of fire has yet to be explored. This study showed that the failure of brace may be attributed to material strength reduction and high compressive forces, both due to temperature rise. Furthermore, limiting temperatures in the linear behavior of steel casing and concrete in BRB element for both numerical and analytical simulations were about 196°C and 225°C, respectively. Finally it is concluded that the performance of BRB at elevated temperatures was the same as that seen at room temperature; that is, the steel core yields prior to the restraining system.

  13. Oxidation and thermal shock behavior of thermal barrier coated 18/10CrNi alloy with coating modifications

    Energy Technology Data Exchange (ETDEWEB)

    Guergen, Selim [Vocational School of Transportation, Anadolu University, Eskisehir (Turkmenistan); Diltemiz, Seyid Fehmi [Turkish Air Force1st Air Supply and Maintenance Center Command, Eskisehir (Turkmenistan); Kushan, Melih Cemal [Dept. of Mechanical Engineering, Eskisehir Osmangazi University, Eskisehir (Turkmenistan)

    2017-01-15

    In this study, substrates of 18/10CrNi alloy plates were initially sprayed with a Ni-21Cr-10Al-1Y bond coat and then with an yttria stabilized zirconia top coat by plasma spraying. Subsequently, plasma-sprayed Thermal barrier coatings (TBCs) were treated with two different modification methods, namely, vacuum heat treatment and laser glazing. The effects of modifications on the oxidation and thermal shock behavior of the coatings were evaluated. The effect of coat thickness on the bond strength of the coats was also investigated. Results showed enhancement of the oxidation resistance and thermal shock resistance of TBCs following modifications. Although vacuum heat treatment and laser glazing exhibited comparable results as per oxidation resistance, the former generated the best improvement in the thermal shock resistance of the TBCs. Bond strength also decreased as coat thickness increased.

  14. Thermal Behavior of Tacca leontopetaloides Starch-Based Biopolymer

    Directory of Open Access Journals (Sweden)

    Nurul Shuhada Mohd Makhtar

    2013-01-01

    Full Text Available Starch is used whenever there is a need for natural elastic properties combined with low cost of production. However, the hydrophilic properties in structural starch will decrease the thermal performance of formulated starch polymer. Therefore, the effect of glycerol, palm olein, and crude palm oil (CPO, as plasticizers, on the thermal behavior of Tacca leontopetaloides starch incorporated with natural rubber in biopolymer production was investigated in this paper. Four different formulations were performed and represented by TPE1, TPE2, TPE3, and TPE4. The compositions were produced by using two-roll mill compounding. The sheets obtained were cut into small sizes prior to thermal testing. The addition of glycerol shows higher enthalpy of diffusion in which made the material easily can be degraded, leaving to an amount of 6.6% of residue. Blending of CPO with starch (TPE3 had a higher thermal resistance towards high temperature up to 310°C and the thermal behavior of TPE2 only gave a moderate performance compared with other TPEs.

  15. The application of thermal analysis, XRD and SEM to study the hydration behavior of tricalcium silicate in the presence of a polycarboxylate superplasticizer

    International Nuclear Information System (INIS)

    Liu, Ming; Lei, Jiaheng; Guo, Liping; Du, Xiaodi; Li, Junsheng

    2015-01-01

    Highlights: • The initial hydration process of C 3 S is markedly retarded by PC. • The decomposition temperature of Ca(OH) 2 is slightly lower after PC modification. • The adsorption amount of PC on C 3 S increases progressively with the hydration time. • The size of Ca(OH) 2 crystals are changed due to the adsorption of PC. - Abstract: Hydration behavior of tricalcium silicate (C 3 S) in the presence of a polycarboxylate (PC) superplasticizer was investigated by means of isothermal calorimetry, differential thermal analysis and X-ray diffraction. In addition, the adsorption characteristics of PC and morphology change of Ca(OH) 2 crystals were also examined, respectively. The results showed that initial hydration process of C 3 S was markedly retarded by PC and the retardation effect depended on the dosage of PC. The decomposition temperature of the Ca(OH) 2 was slightly lower after PC modification. Moreover, the size of Ca(OH) 2 crystals were found to be changed due to the adsorption of PC. The results obtained in this research allowed us to gain insights into the interactions between PC and cement

  16. Dispersal, behavioral responses and thermal adaptation in Musca domestica

    DEFF Research Database (Denmark)

    Kjaersgaard, Anders; Blackenhorn, Wolf U.; Pertoldi, Cino

    were obtained with flies held for several generations in a laboratory common garden setting, therefore we suggest that exposure to and avoidance of high temperatures under natural conditions has been an important selective agent causing the suggested adaptive differentiation between the populations.......Behavioral traits can have great impact on an organism’s ability to cope with or avoidance of thermal stress, and are therefore of evolutionary importance for thermal adaptation. We compared the morphology, heat resistance, locomotor (walking and flying) activity and flight performance of three...

  17. Thermal behaviors of liquid La-based bulk metallic glasses

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, D. W.; Wang, X. D., E-mail: wangxd@zju.edu.cn, E-mail: jiangjz@zju.edu.cn; Lou, H. B.; Cao, Q. P.; Jiang, J. Z., E-mail: wangxd@zju.edu.cn, E-mail: jiangjz@zju.edu.cn [International Center for New-Structured Materials (ICNSM), Laboratory of New-Structured Materials, State Key Laboratory of Silicon Materials, and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027 (China); Wang, L. W. [Institute of Materials Science and Engineering, Lanzhou University, Lanzhou 730000 (China); Zhang, D. X. [State Key Laboratory of Modern Optical Instrumentation, Zhejiang University, Hangzhou 310027 (China)

    2014-12-14

    Thermal behaviors of liquid La-based bulk metallic glasses have been measured by using the dilatometer with a self-sealed sample cell. It is demonstrated that the strong glass forming liquid not only has the small thermal expansion coefficient but also shows the slow variation rate. Moreover, the strong glass former has relatively dense atomic packing and also small density change in the liquid state. The results suggest that the high glass forming ability of La-based metallic glasses would be closely related to the slow atomic rearrangements in liquid melts.

  18. Thermal stability of intermediate band behavior in Ti implanted Si

    Energy Technology Data Exchange (ETDEWEB)

    Olea, J.; Pastor, D.; Martil, I.; Gonzalez-Diaz, G. [Dpto. De Fisica Aplicada III (Electricidad y Electronica), Facultad de Ciencias Fisicas, Universidad Complutense de Madrid, E-28040 Madrid (Spain)

    2010-11-15

    Ti implantation in Si with very high doses has been performed. Subsequent Pulsed Laser Melting (PLM) annealing produces good crystalline lattice with electrical transport properties that are well explained by the Intermediate Band (IB) theory. Thermal stability of this new material is analyzed by means of isochronal annealing in thermodynamic equilibrium conditions at increasing temperature. A progressive deactivation of the IB behavior is shown during thermal annealing, and structural and electrical measurements are reported in order to find out the origin of this result. (author)

  19. Indoor Thermal Comfort: The Behavioral Component

    Directory of Open Access Journals (Sweden)

    Jack Barkenbus

    2013-04-01

    Full Text Available This is a study of how indoor temperature settings have changed over time in the United States based on data from the Energy Information Administration’s, Residential Energy Consumption Survey (RECS. It is shown that Americans have moderately raised indoor temperature settings during the heating season over the past thirty years. It is also shown that most Americans keep their homes relatively cool in the summertime and are generally averse to implementing temperature setbacks. It is revealed that occupants in lower-income homes tend to set their thermostats higher in winter than other income groups, but that the most intense cooling tends to take place in both low-income and high-income homes. As expected, renters tend to heat and cool more intensively than homeowners. Getting Americans to change their temperature settings in order to save energy is not easy even though it comes with the promise of financial savings. The use of programmable thermostats thus far has proved unsuccessful. Greater utilization of social marketing to achieve energy savings is suggested, as well as a renewed effort on the part of electricity suppliers to work more closely with homeowners as part of the rollout of the “smart grid”.

  20. Thermal Stress Limit Rafting Migration of Seahorses: Prediction Based on Physiological and Behavioral Responses to Thermal Stress

    Science.gov (United States)

    Qin, G.; Li, C.; Lin, Q.

    2017-12-01

    Marine fish species escape from harmful environment by migration. Seahorses, with upright posture and low mobility, could migrate from unfavorable environment by rafting with their prehensile tail. The present study was designed to examine the tolerance of lined seahorse Hippocampus erectus to thermal stress and evaluate the effects of temperature on seahorse migration. The results figured that seahorses' tolerance to thermal stress was time dependent. Acute thermal stress (30°C) increased breathing rate and HSP genes expression significantly, but didn't affect seahorse feeding behavior. Chronic thermal treatment lead to persistent high expression of HSP genes, higher breathing rate, and decreasing feeding, and final higher mortality, suggesting that seahorse cannot adapt to thermal stress by acclimation. No significant negative effects were found in seahorse reproduction in response to chronic thermal stress. Given that seahorses make much slower migration by rafting on sea surface compared to other fishes, we suggest that thermal stress might limit seahorse migration range. and the influence might be magnified by global warming in future.

  1. Fatigue threshold studies in Fe, Fe-Si, and HSLA steel: Part II. thermally activated behavior of the effective stress intensity at threshold

    Science.gov (United States)

    Yu, W.; Esaklul, K.; Gerberich, W. W.

    1984-05-01

    It is shown that closure mechanisms alone cannot fully explain increasing fatigue thresholds with decreasing test temperature for a sequence of Fe-Si binary alloys and an HSLA steel. Implications are that fatigue crack propagation near threshold is a thermally activated process. The effective threshold stress intensity, which was obtained by subtracting the closure portion from the fatigue threshold, was examined. This effective stress intensity was found to correlate very well to the thermal component of the flow stress. A detailed fractographic study of the fatigue surface was performed. Water vapor in the room air was found to promote the formation of oxide and intergranular crack growth. At lower temperature, a brittle-type cyclic cleavage fatigue surface was observed but the ductile process persisted even at 123 K. Arrest marks were found on all three modes of fatigue crack growth. The regular spacings between these lines and dislocation modeling suggested that fatigue crack growth was controlled by the subcell structure near threshold. A model based on the slip-off of dislocations was examined. From this, it is shown that the effective fatigue threshold may be related to the square root of (one plus the strain rate sensitivity).

  2. Thermal shock behavior of rare earth modified alumina ceramic composites

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Junlong; Liu, Changxia [Ludong Univ., Yantai (China). School of Transportation

    2017-05-15

    Alumina matrix ceramic composites toughened by AlTiC master alloys, diopside and rare earths were fabricated by hot-pressing and their thermal shock behavior was investigated and compared with that of monolithic alumina. Results showed that the critical thermal shock temperature (ΔT) of monolithic alumina was 400 C. However, it decreased to 300 C for alumina incorporating only AlTiC master alloys, and increased with further addition of diopside and rare earths. Improvement of thermal shock resistance was obtained for alumina ceramic composites containing 9.5 wt.% AlTiC master alloys and 0.5 wt.% rare earth additions, which was mainly attributed to the formation of elongated grains in the composites.

  3. Thermal behavior of novel hybrid inorganic-organic phosphazene polymers

    NARCIS (Netherlands)

    Bosscher, G; Wieringa, RH; Jekel, AP; vandeGrampel, JC

    The thermal behavior of the following systems have been investigated by TGA and XPS: the homopolymer of N3P3Cl4(CH3)(CH2C6H4CH=CH2) (1), copolymers of 1 with MMA and styrene, and copolymers of N3P3Cl4(i-C3H7) {C[OC(O)CH3]=CH2} (2) with MMA and styrene. Upon heating under TGA conditions the highest

  4. In situ tests for investigating thermal and mechanical rock behaviors at an underground research tunnel

    International Nuclear Information System (INIS)

    Kwon, Sangki; Cho, Won-Jin

    2013-01-01

    The understanding of the thermal and mechanical behaviors expected to be happened around an underground high-level radioactive waste (HLW) repository is important for a successful site selection, construction, operation, and closure of the repository. In this study, the thermal and mechanical behaviors of rock and rock mass were investigated from in situ borehole heater test and the studies for characterizing an excavation damaged zone (EDZ), which had been carried out at an underground research tunnel, KURT, constructed in granite for the validation of a HLW disposal concept. Thermal, mechanical, and hydraulic properties in EDZ could be predicted from various in situ and laboratory tests as well as numerical simulations. The complex thermo-mechanical coupling behavior of rock could be modeled using the rock properties. (author)

  5. New data on the thermal behavior of 14 Å tobermorite

    Energy Technology Data Exchange (ETDEWEB)

    Biagioni, Cristian [Dipartimento di Scienze della Terra, Università di Pisa, Via Santa Maria 53, I-56126 Pisa (Italy); Bonaccorsi, Elena [Dipartimento di Scienze della Terra, Università di Pisa, Via Santa Maria 53, I-56126 Pisa (Italy); Merlino, Stefano [Dipartimento di Scienze della Terra, Università di Pisa, Via Santa Maria 53, I-56126 Pisa (Italy); Bersani, Danilo [Dipartimento di Fisica, Università di Parma, Viale G.P. Usberti 7/a, I-43100 Parma (Italy)

    2013-07-15

    The thermal behavior of two specimens of 14 Å tobermorite (plombièrite) was studied in situ at the GILDA beamline (ESRF, Grenoble, France). During dehydration, plombièrite shortens its basal spacing from 14 to 11 Å, through a progressive approaching of the complex structural modules characterizing its crystal structure. Upon heating, the 11 Å phase progressively contracts its c periodicity, with its d{sub 002} varying from 11.7 to 11.3 Å. At ca. 300 °C, a 9.6 Å phase appears; it is stable up to ca. 700 °C. Above this temperature, it expands its basal spacing up to 10.2 Å, before transforming into wollastonite. Moreover, one specimen was heated at 150 °C for 4 h and the heated product, identified as 11 Å tobermorite through X-ray powder diffraction, was used to collect micro-Raman spectra. The heated product shows single chains, in contrast with the 11 Å natural specimens studied up to now in which double wollastonite-like chains occur.

  6. New data on the thermal behavior of 14 Å tobermorite

    International Nuclear Information System (INIS)

    Biagioni, Cristian; Bonaccorsi, Elena; Merlino, Stefano; Bersani, Danilo

    2013-01-01

    The thermal behavior of two specimens of 14 Å tobermorite (plombièrite) was studied in situ at the GILDA beamline (ESRF, Grenoble, France). During dehydration, plombièrite shortens its basal spacing from 14 to 11 Å, through a progressive approaching of the complex structural modules characterizing its crystal structure. Upon heating, the 11 Å phase progressively contracts its c periodicity, with its d 002 varying from 11.7 to 11.3 Å. At ca. 300 °C, a 9.6 Å phase appears; it is stable up to ca. 700 °C. Above this temperature, it expands its basal spacing up to 10.2 Å, before transforming into wollastonite. Moreover, one specimen was heated at 150 °C for 4 h and the heated product, identified as 11 Å tobermorite through X-ray powder diffraction, was used to collect micro-Raman spectra. The heated product shows single chains, in contrast with the 11 Å natural specimens studied up to now in which double wollastonite-like chains occur

  7. Thermal behavior analysis of U-Mo/Al dispersion fuel

    Energy Technology Data Exchange (ETDEWEB)

    Ryu, Ho Jin; Park, Jong Mang; Lee, Yoon Sang; Kim, Chang Kyu [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)

    2004-07-01

    According to the non-proliferation policy under the reduced enrichment for research and test reactors (RERTR) program, low enriched uranium(LEU) fuel such as uranium silicide dispersion fuels are being used in research reactors. Because of a lower enrichment higher uranium density fuels are required for some high performance research reactors. Some uranium alloys with a high uranium density such as U-Mo alloys have been considered as one of the most promising candidates for a dispersion fuel due to the good irradiation performance. An international qualification program to replace the uranium silicide dispersion fuel with U-Mo dispersion fuel is being carried out under the RERTR program. Although U-Mo powders are conventionally supplied by the mechanical comminuting of as-cast U-Mo alloys, KAERI developed a centrifugal atomization method in order to simplify the preparation process and improve the properties. The centrifugally atomized powders have a rapidly solidified gamma uranium structure and a spherical shape. During the in-reactor operation of a dispersion fuel, interdiffusion or chemical reactions between the fuel particles and the matrix occurr. Intermetallic compounds in the form of UAlx are formed as a result of the diffusional reaction. Because the intermetallic compounds are less dense than the combined reactants, the volume of the fuel element increases after the reaction. In addition to the effect on the swelling performance, the reaction layers between the U-Mo and the Al matrix induces a degradation of the thermal properties of the U-Mo/Al dispersion fuels. It is important to investigate the thermal behavior of U-Mo/Al dispersion fuel according to reaction between the fuel particles and the matrix with the burnup and linear power. In this study, a finite element analysis was used for the calculation of the temperature distribution of the U-Mo/Al dispersion fuel with a burnup and linear power. Kinetics data of the reaction layers such as the growth

  8. Thermal behavior analysis of U-Mo/Al dispersion fuel

    International Nuclear Information System (INIS)

    Ryu, Ho Jin; Park, Jong Mang; Lee, Yoon Sang; Kim, Chang Kyu

    2004-01-01

    According to the non-proliferation policy under the reduced enrichment for research and test reactors (RERTR) program, low enriched uranium(LEU) fuel such as uranium silicide dispersion fuels are being used in research reactors. Because of a lower enrichment higher uranium density fuels are required for some high performance research reactors. Some uranium alloys with a high uranium density such as U-Mo alloys have been considered as one of the most promising candidates for a dispersion fuel due to the good irradiation performance. An international qualification program to replace the uranium silicide dispersion fuel with U-Mo dispersion fuel is being carried out under the RERTR program. Although U-Mo powders are conventionally supplied by the mechanical comminuting of as-cast U-Mo alloys, KAERI developed a centrifugal atomization method in order to simplify the preparation process and improve the properties. The centrifugally atomized powders have a rapidly solidified gamma uranium structure and a spherical shape. During the in-reactor operation of a dispersion fuel, interdiffusion or chemical reactions between the fuel particles and the matrix occurr. Intermetallic compounds in the form of UAlx are formed as a result of the diffusional reaction. Because the intermetallic compounds are less dense than the combined reactants, the volume of the fuel element increases after the reaction. In addition to the effect on the swelling performance, the reaction layers between the U-Mo and the Al matrix induces a degradation of the thermal properties of the U-Mo/Al dispersion fuels. It is important to investigate the thermal behavior of U-Mo/Al dispersion fuel according to reaction between the fuel particles and the matrix with the burnup and linear power. In this study, a finite element analysis was used for the calculation of the temperature distribution of the U-Mo/Al dispersion fuel with a burnup and linear power. Kinetics data of the reaction layers such as the growth

  9. Effect of biomimetic non-smooth unit morphology on thermal fatigue behavior of H13 hot-work tool steel

    Science.gov (United States)

    Meng, Chao; Zhou, Hong; Cong, Dalong; Wang, Chuanwei; Zhang, Peng; Zhang, Zhihui; Ren, Luquan

    2012-06-01

    The thermal fatigue behavior of hot-work tool steel processed by a biomimetic coupled laser remelting process gets a remarkable improvement compared to untreated sample. The 'dowel pin effect', the 'dam effect' and the 'fence effect' of non-smooth units are the main reason of the conspicuous improvement of the thermal fatigue behavior. In order to get a further enhancement of the 'dowel pin effect', the 'dam effect' and the 'fence effect', this study investigated the effect of different unit morphologies (including 'prolate', 'U' and 'V' morphology) and the same unit morphology in different sizes on the thermal fatigue behavior of H13 hot-work tool steel. The results showed that the 'U' morphology unit had the optimum thermal fatigue behavior, then the 'V' morphology which was better than the 'prolate' morphology unit; when the unit morphology was identical, the thermal fatigue behavior of the sample with large unit sizes was better than that of the small sizes.

  10. Thermal Fatigue Behavior of Air-Plasma Sprayed Thermal Barrier Coating with Bond Coat Species in Cyclic Thermal Exposure

    Directory of Open Access Journals (Sweden)

    Ungyu Paik

    2013-08-01

    Full Text Available The effects of the bond coat species on the delamination or fracture behavior in thermal barrier coatings (TBCs was investigated using the yclic thermal fatigue and thermal-shock tests. The interface microstructures of each TBC showed a good condition without cracking or delamination after flame thermal fatigue (FTF for 1429 cycles. The TBC with the bond coat prepared by the air-plasma spray (APS method showed a good condition at the interface between the top and bond coats after cyclic furnace thermal fatigue (CFTF for 1429 cycles, whereas the TBCs with the bond coats prepared by the high-velocity oxygen fuel (HVOF and low-pressure plasma spray (LPPS methods showed a partial cracking (and/or delamination and a delamination after 780 cycles, respectively. The TBCs with the bond coats prepared by the APS, HVOF and LPPS methods were fully delaminated (>50% after 159, 36, and 46 cycles, respectively, during the thermal-shock tests. The TGO thickness in the TBCs was strongly dependent on the both exposure time and temperature difference tested. The hardness values were found to be increased only after the CFTF, and the TBC with the bond coat prepared by the APS showed the highest adhesive strength before and after the FTF.

  11. Conceptual Thermal Treatment Technologies Feasibility Study

    International Nuclear Information System (INIS)

    Suer, A.

    1996-01-01

    This report presents a conceptual Thermal Treatment Technologies Feasibility Study (FS) for the Savannah River Site (SRS) focusing exclusively on thermal treatment technologies for contaminated soil, sediment, or sludge remediation projects

  12. Thermal Expansion Behavior of Hot-Pressed Engineered Matrices

    Science.gov (United States)

    Raj, S. V.

    2016-01-01

    Advanced engineered matrix composites (EMCs) require that the coefficient of thermal expansion (CTE) of the engineered matrix (EM) matches those of the fiber reinforcements as closely as possible in order to reduce thermal compatibility strains during heating and cooling of the composites. The present paper proposes a general concept for designing suitable matrices for long fiber reinforced composites using a rule of mixtures (ROM) approach to minimize the global differences in the thermal expansion mismatches between the fibers and the engineered matrix. Proof-of-concept studies were conducted to demonstrate the validity of the concept.

  13. Transient thermal-mechanical behavior of cracked glass-cloth-reinforced epoxy laminates at low temperatures

    International Nuclear Information System (INIS)

    Shindo, Y.; Ueda, S.

    1997-01-01

    We consider the transient thermal-mechanical response of cracked G-10CR glass-cloth-reinforced epoxy laminates with temperature-dependent properties. The glass-cloth-reinforced epoxy laminates are suddenly cooled on the surfaces. A generalized plane strain finite element model is used to study the influence of warp angle and crack formation on the thermal shock behavior of two-layer woven laminates at low temperatures. Numerical calculations are carried out, and the transient temperature distribution and the thermal-mechanical stresses are shown graphically

  14. Thermal behavior and ice-table depth within the north polar erg of Mars

    Science.gov (United States)

    Putzig, Nathaniel E.; Mellon, Michael T.; Herkenhoff, Kenneth E.; Phillips, Roger J.; Davis, Brian J.; Ewer, Kenneth J.; Bowers, Lauren M.

    2014-02-01

    We fully resolve a long-standing thermal discrepancy concerning the north polar erg of Mars. Several recent studies have shown that the erg's thermal properties are consistent with normal basaltic sand overlying shallow ground ice or ice-cemented sand. Our findings bolster that conclusion by thoroughly characterizing the thermal behavior of the erg, demonstrating that other likely forms of physical heterogeneity play only a minor role, and obviating the need to invoke exotic materials. Thermal inertia as calculated from orbital temperature observations of the dunes has previously been found to be more consistent with dust-sized materials than with sand. Since theory and laboratory data show that dunes will only form out of sand-sized particles, exotic sand-sized agglomerations of dust have been invoked to explain the low values of thermal inertia. However, the polar dunes exhibit the same darker appearance and color as that of dunes found elsewhere on the planet that have thermal inertia consistent with normal sand-sized basaltic grains, whereas Martian dust deposits are generally lighter and redder. The alternative explanation for the discrepancy as a thermal effect of a shallow ice table is supported by our analysis of observations from the Mars Global Surveyor Thermal Emission Spectrometer and the Mars Odyssey Thermal Emission Imaging System and by forward modeling of physical heterogeneity. In addition, our results exclude a uniform composition of dark dust-sized materials, and they show that the thermal effects of the dune slopes and bright interdune materials evident in high-resolution images cannot account for the erg's thermal behavior.

  15. Thermal behavior and ice-table depth within the north polar erg of Mars

    Science.gov (United States)

    Putzig, Nathaniel E.; Mellon, Michael T.; Herkenhoff, Kenneth E.; Phillips, Roger J.; Davis, Brian J.; Ewer, Kenneth J.; Bowers, Lauren M.

    2014-01-01

    We fully resolve a long-standing thermal discrepancy concerning the north polar erg of Mars. Several recent studies have shown that the erg’s thermal properties are consistent with normal basaltic sand overlying shallow ground ice or ice-cemented sand. Our findings bolster that conclusion by thoroughly characterizing the thermal behavior of the erg, demonstrating that other likely forms of physical heterogeneity play only a minor role, and obviating the need to invoke exotic materials. Thermal inertia as calculated from orbital temperature observations of the dunes has previously been found to be more consistent with dust-sized materials than with sand. Since theory and laboratory data show that dunes will only form out of sand-sized particles, exotic sand-sized agglomerations of dust have been invoked to explain the low values of thermal inertia. However, the polar dunes exhibit the same darker appearance and color as that of dunes found elsewhere on the planet that have thermal inertia consistent with normal sand-sized basaltic grains, whereas Martian dust deposits are generally lighter and redder. The alternative explanation for the discrepancy as a thermal effect of a shallow ice table is supported by our analysis of observations from the Mars Global Surveyor Thermal Emission Spectrometer and the Mars Odyssey Thermal Emission Imaging System and by forward modeling of physical heterogeneity. In addition, our results exclude a uniform composition of dark dust-sized materials, and they show that the thermal effects of the dune slopes and bright interdune materials evident in high-resolution images cannot account for the erg’s thermal behavior.

  16. Hydrothermal synthesis, structural elucidation, spectroscopic studies, thermal behavior and luminescence properties of a new 3-d compound: FeAlF2(C10H8N2)(HPO4)2(H2O)

    Science.gov (United States)

    Bouzidia, Nabaa; Salah, Najet; Hamdi, Besma; Ben Salah, Abdelhamid

    2017-04-01

    The study of metal phosphate has been a proactive field of research thanks to its applied and scientific importance, especially in terms of the development of optical devices such as solid state lasers as well as optical fibers. The present paper seeks to investigate the synthesis, crystal structure, elemental analysis and properties of FeAlF2(C10H8N2)(HPO4)2(H2O) compound investigated by spectroscopic studies (FT-IR and FT-Raman), thermal behavior and luminescence. The Hirshfeld surface analysis and 2-D fingerprint plot have been performed to explore the behavior of these weak interactions and crystal cohesion. This investigation shows that the molecules are connected by hydrogen bonds of the type Osbnd H⋯O and Osbnd H⋯F. In addition, the 2,2'‒bipyridine ligand plays a significant role in the construction of 3-D supramolecular framework via π‒π stacking. FT‒IR and FT‒Raman spectra were used so as to ease the responsibilities of the vibration modes of the title compound. The thermal analysis (TGA) study shows a mass loss evolution as a temperature function. Finally, the optical properties were evaluated by photoluminescence spectroscopy.

  17. Thermal and kinetic behaviors of biomass and plastic wastes in co-pyrolysis

    International Nuclear Information System (INIS)

    Çepelioğullar, Özge; Pütün, Ayşe E.

    2013-01-01

    Graphical abstract: - Highlights: • Co-pyrolysis of biomass together with the plastic wastes in thermogravimetric analyzer. • Investigations into thermal and kinetic behaviors at high temperature regions. • Determination of the kinetic parameters. - Abstract: In this study, co-pyrolysis characteristics and kinetics of biomass-plastic blends were investigated. Cotton stalk, hazelnut shell, sunflower residue, and arid land plant Euphorbia rigida, were blended in definite ratio (1:1, w/w) with polyvinyl chloride (PVC) and polyethylene terephthalate (PET). Experiments were conducted with a heating rate of 10 °C min −1 from room temperature to 800 °C in the presence of N 2 atmosphere with a flow rate of 100 cm 3 min −1 . After thermal decomposition in TGA, a kinetic analysis was performed to fit thermogravimetric data and a detailed discussion of co-pyrolysis mechanism was achieved. Experimental results demonstrated that the structural differences between biomass and plastics directly affect their thermal decomposition behaviors. Biomass pyrolysis generally based on three main steps while plastic material’s pyrolysis mechanism resulted in two steps for PET and three steps for PVC. Also, the required activation energies needed to achieve the thermal degradation for plastic were found higher than the biomass materials. In addition, it can be concluded that the evaluation of plastic materials together with biomass created significant changes not only for the thermal behaviors but also for the kinetic behaviors

  18. Thermal behavior in the transition region between nucleate and film boiling

    International Nuclear Information System (INIS)

    Adiutori, E.F.

    1991-01-01

    The prediction of post Critical Heat Flux (CHF) behavior is complicated by the highly nonlinear thermal behavior of boiling interfaces--ie by the nonlinear nature of the boiling curve. Nonlinearity in the boiling curve can and does cause thermal instability, resulting in temperature discontinuities. Thus the prediction of post CHF behavior requires the analysis of thermal stability. This in turn requires an accurate description of thermal behavior in transition boiling. This paper determines thermal behavior in transition boiling by analysis of literature data. It also describes design features which improve post CHF performance and are reported in the literature

  19. Thermal shock behavior of toughened gadolinium zirconate/YSZ double-ceramic-layered thermal barrier coating

    International Nuclear Information System (INIS)

    Zhong, Xinghua; Zhao, Huayu; Zhou, Xiaming; Liu, Chenguang; Wang, Liang; Shao, Fang; Yang, Kai; Tao, Shunyan; Ding, Chuanxian

    2014-01-01

    Highlights: • Gd 2 Zr 2 O 7 /YSZ DCL thermal barrier coating was designed and fabricated. • The Gd 2 Zr 2 O 7 top ceramic layer was toughened by addition of nanostructured 3YSZ. • Remarkable improvement in thermal shock resistance of the DCL coating was achieved. - Abstract: Double-ceramic-layered (DCL) thermal barrier coating system comprising of toughened Gadolinium zirconate (Gd 2 Zr 2 O 7 , GZ) as the top ceramic layer and 4.5 mol% Y 2 O 3 partially-stabilized ZrO 2 (4.5YSZ) as the bottom ceramic layer was fabricated by plasma spraying and thermal shock behavior of the DCL coating was investigated. The GZ top ceramic layer was toughened by addition of nanostructured 3 mol% Y 2 O 3 partially-stabilized ZrO 2 (3YSZ) to improve fracture toughness of the matrix. The thermal shock resistance of the DCL coating was enhanced significantly compared to that of single-ceramic-layered (SCL) GZ-3YSZ composite coating, which is believed to be primarily attributed to the two factors: (i) the increase in fracture toughness of the top ceramic layer by incorporating nanostructured YSZ particles and (ii) the improvement in strain tolerance through the utilization of 4.5YSZ as the bottom ceramic layer. In addition, the failure mechanisms are mainly attributed to the still low fracture toughness of the top ceramic layer and oxidation of the bond-coat

  20. Thermal expansion behavior of empressite, AgTe: A structural study by means of in situ high-temperature single-crystal X-ray diffraction

    International Nuclear Information System (INIS)

    Bindi, Luca

    2009-01-01

    The crystal structure of empressite, AgTe, a rare silver telluride, has been investigated by in situ X-ray single-crystal diffraction methods within the temperature range 298-463 K. AgTe remains orthorhombic, space group Pmnb (Pnma as standard), and shows only normal thermal expansion over the entire temperature range. The unit-cell parameters show a gradual increase with the increase of temperature. Slight adjustments in the geometry of Ag-tetrahedra and in the crystal-chemical environment of tellurium atoms occur in a continuous way without abrupt structural changes. The coefficients of thermal expansion along various axes are: α a = 1.5 x 10 -5 K -1 , α b = 3.0 x 10 -5 K -1 , α c = 2.2 x 10 -5 K -1 , and the bulk thermal expansion coefficient α V is 5.4 x 10 -5 K -1 for the temperature range 298-463 K

  1. Thermal hydraulic behavior evaluation of tank A-101

    International Nuclear Information System (INIS)

    Ogden, D.M.

    1996-01-01

    This report describes a new evaluation conducted to help understand the thermal-hydraulic behavior of tank A-101. Prior analysis of temperature data indicated that the dome space and upper waste layer was slowly increasing in temperature increases are due to increasing ambient temperatures and termination of forced ventilation. However, this analysis also indicates that other dome cooling processes are slowly decreasing, or some slow increase in heating is occurring at the waste surface. Dome temperatures are not decreasing at the rate expected as a forced ventilation termination effects are accounted for

  2. Thermal hydraulic behavior of SCWR sliding pressure startup

    International Nuclear Information System (INIS)

    Fu Shengwei; Zhou Chong; Xu Zhihong; Yang Yanhua

    2011-01-01

    The modification to ATHLET-SC code is introduced in this paper, which realizes the simulation of trans-critical transients using two-phase model. With the modified code, the thermal-hydraulic dynamic behavior of the mixed SCWR core during the startup process is simulated. The startup process is similar to the design of SCLWR-H sliding pressure startup. The results show that maximum temperature of cladding-surface does not exceed 650℃ in the whole startup process, and the sudden change of water properties in the trans-critical transients will not cause harmful influence to the heat transfer of the fuel cladding. (authors)

  3. Experimental study on thermal-hydraulic behaviors of a pressure balanced coolant injection system for a passive safety light water reactor JPSR

    Energy Technology Data Exchange (ETDEWEB)

    Satoh, Takashi; Watanabe, Hironori; Araya, Fumimasa; Nakajima, Katsutoshi [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment; Iwamura, Takamichi; Murao, Yoshio

    1998-02-01

    A conceptual design study of a passive safety light water reactor JPSR has been performed at Japan Atomic Energy Research Institute JAERI. A pressure balanced coolant injection experiment has been carried out, with an objective to understand thermal-hydraulic characteristics of a passive coolant injection system which has been considered to be adopted to JPSR. This report summarizes experimental results and data recorded in experiment run performed in FY. 1993 and 1994. Preliminary experiments previously performed are also briefly described. As the results of the experiment, it was found that an initiation of coolant injection was delayed with increase in a subcooling in the pressure balance line. By inserting a separation device which divides the inside of core make-up tank (CMT) into several small compartments, a diffusion of a high temperature region formed just under the water surface was restrained and then a steam condensation was suppressed. A time interval from an uncovery of the pressure balance line to the initiation of the coolant injection was not related by a linear function with a discharge flow rate simulating a loss-of-coolant accident (LOCA) condition. The coolant was injected intermittently by actuation of a trial fabricated passive valve actuated by pressure difference for the present experiment. It was also found that the trial passive valve had difficulties in setting an actuation set point and vibrations noises and some fraction of the coolant was remained in CMT without effective use. A modification was proposed for resolving these problems by introducing an anti-closing mechanism. (author)

  4. Effect of moving distance of temperature distribution on thermal ratchetting behavior of a FBR reactor vessel

    International Nuclear Information System (INIS)

    Ueta, Masahiro; Douzaki, Kouji; Takahashi, Yukio; Ooka, Yuji; Osaki, Toshio; Take, Kouji.

    1992-01-01

    It should be considered in a FBR reactor vessel design that thermal ratchetting might be caused by moving axial thermal gradient, in other words, moving sodium level. The behavior and the mechanism of ratchetting have almost become clear by studies for the past several years. A simplified evaluation method for ratchetting behavior has been proposed. However, the evaluation method has been shown to be excessively conservative by testing results. In this paper, the effect of moving distance of axial temperature distributions, which is one of main factors to be considered in precise estimation of ratchetting behavior, is studied by inelastic analyses. Based on the study, it is proposed to introduce a strain reducing factor taking account of residual stresses in the region of moving axial temperature distribution to the original evaluation method. The new method has been validated by comparing the prediction with results of both testing and the original method. (author)

  5. Tribological and wear behavior of yttria stabilized zirconia thermal barrier coatings on mild steel

    International Nuclear Information System (INIS)

    Farooq, M.; Pervez, A.

    2012-01-01

    The perfection of the temperature confrontation of the engine essentials can be obtained by claim of a single ceramic thermal barrier coating (TBC) or several composite layers. Engine elements protected by TBC can work safely in elevated temperature range above 1000 degree C. Continuous endeavor to increase thermal resistance of engine the elements requires, apart from laboratory investigations, also numerical study of the different engine parts. The high temperatures and stress concentrations can act as the local sources of damage initiation and defects propagation in the form of cracks. The current study focuses the development of Yttria stabilized zirconia thermal barrier coating by Thermal spray technique. Mild steel was used as a substrate and the coating was then characterized for tribological analysis followed by the optical analysis of wear tracks and found the TBC behavior more promising then steel. (author)

  6. Phase Behavior, Thermal Stability and Rheological Properties of PPEK/PC Blends

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Phase behavior, thermal stability and rheological properties of the blends of poly(phthalazinone ether ketone) (PPEK)with bisphenol-A polycarbonate (PC) prepared by solution coprecipitation were studied using differential scanning calorimetry (DSC), Frourier-Transform IR spectroscopy (FT-IR), thermogravimetric analysis (TGA) and capillary rheometer. The DSC results indicated that PPEK/PC blends are almost immiscible in full compositions. FT-IR investigation showed that there were no apparent specific interactions between the constituent polymers. The blends keep excellent thermal stability and the addition of PC degrades the thermal stability of blends to some degree. The thermal degradation processes of the blends are much similar to that of PC. The studies on rheological properties of blends show that blending PPEK with PC is beneficial to reducing the melt viscosity and improving the appearance of PPEK.

  7. Analytic scattering kernels for neutron thermalization studies

    International Nuclear Information System (INIS)

    Sears, V.F.

    1990-01-01

    Current plans call for the inclusion of a liquid hydrogen or deuterium cold source in the NRU replacement vessel. This report is part of an ongoing study of neutron thermalization in such a cold source. Here, we develop a simple analytical model for the scattering kernel of monatomic and diatomic liquids. We also present the results of extensive numerical calculations based on this model for liquid hydrogen, liquid deuterium, and mixtures of the two. These calculations demonstrate the dependence of the scattering kernel on the incident and scattered-neutron energies, the behavior near rotational thresholds, the dependence on the centre-of-mass pair correlations, the dependence on the ortho concentration, and the dependence on the deuterium concentration in H 2 /D 2 mixtures. The total scattering cross sections are also calculated and compared with available experimental results

  8. Study of the effects of the interconnectivity of the metallic phase on the electrical and thermal behavior in alumina-ni and zirconia-ni interpenetrating phase composites (IPCs)

    International Nuclear Information System (INIS)

    Shahid, R.N.; Awais, H.B.; Mehmood, M.; Tariq, N.H.

    2007-01-01

    The addition of metallic inclusion in ceramic matrix can enhance the electrical and magnetic properties of the composite. Connectivity of conducting phase in an insulating matrix can be studied using electrical conductivity, thermal expansion, Hall Effect and by microscopic techniques. The wide range of application of such studies include, susceptor materials for induction heating, thin film resistors, gel formation permeability in porous structure and electromagnetic behavior of composites. The main phenomenon to be investigated is the insulating to conducting transition by the determination to of percolation range. This phenomenon depends on the concentration, shape, dimension and the crystallographic direction of the imbedded conducting particles. In this investigation variable concerning the percolation range of alumina- Ni and zirconia-Ni composites have been studied. The results provided the role of the size ratio of particles of matrix and the conducting phase, variation of resistance in terms of real part of impedance and thermal expansion on percolation effect. Scanning electron image have been used to study the percolation microscopically. (author)

  9. Chromium behavior during thermal treatment of MSW fly ash.

    Science.gov (United States)

    Kirk, Donald W; Chan, Chris C Y; Marsh, Hilary

    2002-02-14

    Energy-from-waste incineration has been promoted as an environmentally responsible method for handling non-recyclable waste from households. Despite the benefits of energy production, elimination of organic residues and reduction of volume of waste to be landfilled, there is concern about fly ash disposal. Fly ash from an incinerator contains toxic species such as Pb, Zn, Cd and Cr which may leach into soil and ground water if landfilled. Thermal treatment of the fly ash from municipal solid waste has been tested and proposed as a treatment option for removal of metal species such as Pb, Cd and Zn, via thermal re-volatilization. However, Cr is an element that remains in the residue of the heat treated fly ash and appears to become more soluble. This Cr solubilization is of concern if it exceeds the regulatory limit for hazardous waste. Hence, this unexpected behavior of Cr was investigated. The initial work involved microscopic characterization of Cr in untreated and thermally-treated MSW fly ash. This was followed by determining leaching characteristics using standard protocol leaching tests and characterization leaching methods (sequential extraction). Finally, a mechanism explaining the increased solubilization was proposed and tested by reactions of synthetic chemicals.

  10. Synthesis and thermal behavior of polyacrylonitrile/vinylidene chloride copolymer

    Directory of Open Access Journals (Sweden)

    Robson Fleming

    2014-06-01

    Full Text Available Polyacrylonitrile fiber encompasses a broad range of products based on acrylonitrile (AN which is readily copolymerized with a wide range of ethylenic unsaturated monomers giving rise to polymers with different characteristics and applications. Such products can be designed for cost-effective, flame and heat resistant solutions for the textile industry, aircraft and automotive markets. In the present work acrylonitrile was copolymerized with vinylidene chloride (VDC by conventional suspension polymerization process via redox system, with an initial content of 10%/mass of the VDC monomer. The copolymer average molecular weight was obtained by Gel Permeation Chromatography (GPC and by intrinsic viscosity analysis. To control the polymerization process continuously, qualitative and quantitative analysis of the chloride content in the PAN AN/VDC copolymer structure was accomplished by using X-ray fluorescence and potentiometric titration techniques. A good correlation was found between these two techniques, leading to a straightforward verification of VDC in the polymer structure. The thermal behavior of PAN AN/VDC copolymer was performed by Differential Scanning Calorimetry (DSC and Thermogravimetric Analysis (TGA. The results showed that VDC monomers exhibited a nearly stoichiometric reaction with acrylonitrile, copolymerizing about 90% of its initial mass. VDC changed significantly the polyacrylonitrile thermal behavior, decreasing the polymer degradation temperature by about 40-50°C.

  11. The diversity in thermal behavior of novel catanionic cholates: The dominant effect of quaternary ammonium centers

    International Nuclear Information System (INIS)

    Mihelj, Tea; Vojta, Danijela; Tomašić, Vlasta

    2014-01-01

    Graphical abstract: - Highlights: • Quaternary ammonium cholates characterized as crystal smectics at room temperature. • The domination of quaternary ammonium center seen through diverse thermal behavior. • Thermal changes of cholates keto–enol balance results with prevalence of one form. • Polynomial regression of isotropisation temperatures vs. dodecyl chain number. • Linear descending trend of isotropisation temperatures with higher headgroup number. - Abstract: The thermal behavior of novel catanionic compounds based on cholate anion was examined. The study explains the effect of the raising dodecyl chain number, as well as of the raising headgroup number in quaternary ammonium salts on their physico-chemical properties. The examined samples are crystal smectic phases at room temperature. Their rich and diverse thermal behavior is seen through polymorphic phase transitions, thermotropic mesomorphism of smectic nature and in some cases, kinetically managed crystallization that lasts in days. The changes of the cholates keto–enol isomer balance during thermal treatment are obtained. For both groups of samples temperatures of isotropisation and the thermodynamic parameters follow polynomial regression. Introduction of the new dodecyl chain leads to more ordered structure, while implementation the new headgroup leads to advanced polymer-like structure. The obtained results demonstrate an effort for getting and controlling the regularity of the physico-chemical and thermotropic properties for new compounds by systematic changing of cationic part of the molecule. These informations could provide in the future the easiest way for selection of potentially new and targeted applicable materials

  12. The diversity in thermal behavior of novel catanionic cholates: The dominant effect of quaternary ammonium centers

    Energy Technology Data Exchange (ETDEWEB)

    Mihelj, Tea, E-mail: tmihelj@irb.hr [Department of Physical Chemistry, Ruđer Bošković Institute, POB 180, HR-10002 Zagreb (Croatia); Vojta, Danijela [Department of Organic Chemistry and Biochemistry, Ruđer Bošković Institute, POB 180, HR-10002 Zagreb (Croatia); Tomašić, Vlasta [Department of Physical Chemistry, Ruđer Bošković Institute, POB 180, HR-10002 Zagreb (Croatia)

    2014-05-01

    Graphical abstract: - Highlights: • Quaternary ammonium cholates characterized as crystal smectics at room temperature. • The domination of quaternary ammonium center seen through diverse thermal behavior. • Thermal changes of cholates keto–enol balance results with prevalence of one form. • Polynomial regression of isotropisation temperatures vs. dodecyl chain number. • Linear descending trend of isotropisation temperatures with higher headgroup number. - Abstract: The thermal behavior of novel catanionic compounds based on cholate anion was examined. The study explains the effect of the raising dodecyl chain number, as well as of the raising headgroup number in quaternary ammonium salts on their physico-chemical properties. The examined samples are crystal smectic phases at room temperature. Their rich and diverse thermal behavior is seen through polymorphic phase transitions, thermotropic mesomorphism of smectic nature and in some cases, kinetically managed crystallization that lasts in days. The changes of the cholates keto–enol isomer balance during thermal treatment are obtained. For both groups of samples temperatures of isotropisation and the thermodynamic parameters follow polynomial regression. Introduction of the new dodecyl chain leads to more ordered structure, while implementation the new headgroup leads to advanced polymer-like structure. The obtained results demonstrate an effort for getting and controlling the regularity of the physico-chemical and thermotropic properties for new compounds by systematic changing of cationic part of the molecule. These informations could provide in the future the easiest way for selection of potentially new and targeted applicable materials.

  13. Thermal behavior variations in coating thickness using pulse phase thermography

    Energy Technology Data Exchange (ETDEWEB)

    Ranjit, Shrestha; Chung, Yoonjae; Kim, Won Tae [Kongju National University, Cheonan (Korea, Republic of)

    2016-08-15

    This paper presents a study on the use of pulsed phase thermography in the measurement of thermal barrier coating thickness with a numerical simulation. A multilayer heat transfer model was used to analyze the surface temperature response acquired from one-sided pulsed thermal imaging. The test sample comprised four layers: the metal substrate, bond coat, thermally grown oxide and the top coat. The finite element software, ANSYS, was used to model and predict the temperature distribution in the test sample under an imposed heat flux on the exterior of the TBC. The phase image was computed with the use of the software MATLAB and Thermofit Pro using a Fourier transform. The relationship between the coating thickness and the corresponding phase angle was then established with the coating thickness being expressed as a function of the phase angle. The method is successfully applied to measure the coating thickness that varied from 0.25 mm to 1.5 mm.

  14. Uncertainty and sensitivity analysis of the nuclear fuel thermal behavior

    Energy Technology Data Exchange (ETDEWEB)

    Boulore, A., E-mail: antoine.boulore@cea.fr [Commissariat a l' Energie Atomique (CEA), DEN, Fuel Research Department, 13108 Saint-Paul-lez-Durance (France); Struzik, C. [Commissariat a l' Energie Atomique (CEA), DEN, Fuel Research Department, 13108 Saint-Paul-lez-Durance (France); Gaudier, F. [Commissariat a l' Energie Atomique (CEA), DEN, Systems and Structure Modeling Department, 91191 Gif-sur-Yvette (France)

    2012-12-15

    Highlights: Black-Right-Pointing-Pointer A complete quantitative method for uncertainty propagation and sensitivity analysis is applied. Black-Right-Pointing-Pointer The thermal conductivity of UO{sub 2} is modeled as a random variable. Black-Right-Pointing-Pointer The first source of uncertainty is the linear heat rate. Black-Right-Pointing-Pointer The second source of uncertainty is the thermal conductivity of the fuel. - Abstract: In the global framework of nuclear fuel behavior simulation, the response of the models describing the physical phenomena occurring during the irradiation in reactor is mainly conditioned by the confidence in the calculated temperature of the fuel. Amongst all parameters influencing the temperature calculation in our fuel rod simulation code (METEOR V2), several sources of uncertainty have been identified as being the most sensitive: thermal conductivity of UO{sub 2}, radial distribution of power in the fuel pellet, local linear heat rate in the fuel rod, geometry of the pellet and thermal transfer in the gap. Expert judgment and inverse methods have been used to model the uncertainty of these parameters using theoretical distributions and correlation matrices. Propagation of these uncertainties in the METEOR V2 code using the URANIE framework and a Monte-Carlo technique has been performed in different experimental irradiations of UO{sub 2} fuel. At every time step of the simulated experiments, we get a temperature statistical distribution which results from the initial distributions of the uncertain parameters. We then can estimate confidence intervals of the calculated temperature. In order to quantify the sensitivity of the calculated temperature to each of the uncertain input parameters and data, we have also performed a sensitivity analysis using the Sobol' indices at first order.

  15. Thermal expansion behavior of empressite, AgTe: A structural study by means of in situ high-temperature single-crystal X-ray diffraction

    Energy Technology Data Exchange (ETDEWEB)

    Bindi, Luca [Museo di Storia Naturale, sez. di Mineralogia, Universita di Firenze, Via La Pira 4, I-50121 Firenze (Italy)], E-mail: luca.bindi@unifi.it

    2009-04-03

    The crystal structure of empressite, AgTe, a rare silver telluride, has been investigated by in situ X-ray single-crystal diffraction methods within the temperature range 298-463 K. AgTe remains orthorhombic, space group Pmnb (Pnma as standard), and shows only normal thermal expansion over the entire temperature range. The unit-cell parameters show a gradual increase with the increase of temperature. Slight adjustments in the geometry of Ag-tetrahedra and in the crystal-chemical environment of tellurium atoms occur in a continuous way without abrupt structural changes. The coefficients of thermal expansion along various axes are: {alpha}{sub a} = 1.5 x 10{sup -5} K{sup -1}, {alpha}{sub b} = 3.0 x 10{sup -5} K{sup -1}, {alpha}{sub c} = 2.2 x 10{sup -5} K{sup -1}, and the bulk thermal expansion coefficient {alpha}{sub V} is 5.4 x 10{sup -5} K{sup -1} for the temperature range 298-463 K.

  16. Numerical investigation of thermal behaviors in lithium-ion battery stack discharge

    International Nuclear Information System (INIS)

    Liu, Rui; Chen, Jixin; Xun, Jingzhi; Jiao, Kui; Du, Qing

    2014-01-01

    Highlights: • The thermal behaviors of a Li-ion battery stack have been investigated by modeling. • Parametric studies have been performed focusing on three different cooling materials. • Effects of discharge rate, ambient temperature and Reynolds number are examined. • General guidelines are proposed for the thermal management of a Li-ion battery stack. - Abstract: Thermal management is critically important to maintain the performance and prolong the lifetime of a lithium-ion (Li-ion) battery. In this paper, a two-dimensional and transient model has been developed for the thermal management of a 20-flat-plate-battery stack, followed by comprehensive numerical simulations to study the influences of ambient temperature, Reynolds number, and discharge rate on the temperature distribution in the stack with different cooling materials. The simulation results indicate that liquid cooling is generally more effective in reducing temperature compared to phase-change material, while the latter can lead to more homogeneous temperature distribution. Fast and deep discharge should be avoided, which generally yields high temperature beyond the acceptable range regardless of cooling materials. At low or even subzero ambient temperatures, air cooling is preferred over liquid cooling because heat needs to be retained rather than removed. Such difference becomes small when the ambient temperature increases to a mild level. The effects of Reynolds number are apparent in liquid cooling but negligible in air cooling. Choosing appropriate cooling material and strategy is particularly important in low ambient temperature and fast discharge cases. These findings improve the understanding of battery stack thermal behaviors and provide the general guidelines for thermal management system. The present model can also be used in developing control system to optimize battery stack thermal behaviors

  17. A contribution to the study of the thermal behavior and of the electric performance of squirrel-cage induction motors; Uma contribuicao ao estudo do comportamento termico e do desempenho eletrico de motores de inducao com rotor em gaiola

    Energy Technology Data Exchange (ETDEWEB)

    Avolio, Edwin

    1992-03-01

    A thermal-electric mathematical model for a squirrel cage induction motors which permits to specify the best motor for specific drive, under thermal and electric aspects based, only on manufacturer technical bulletins and technical information is presented. Changes of rotor parameters due Skin Effect and changes of winding resistances (both stator and rotor) with the temperature are considered. The accuracy of this model is appraised using experimental results. The thermal behavior and electric performance for some motors are obtained for continuos and intermittent duties with sinusoidal and non-sinusoidal voltages. (author)

  18. Mapping Thermal Habitat of Ectotherms Based on Behavioral Thermoregulation in a Controlled Thermal Environment

    Science.gov (United States)

    Fei, T.; Skidmore, A.; Liu, Y.

    2012-07-01

    Thermal environment is especially important to ectotherm because a lot of physiological functions rely on the body temperature such as thermoregulation. The so-called behavioural thermoregulation function made use of the heterogeneity of the thermal properties within an individual's habitat to sustain the animal's physiological processes. This function links the spatial utilization and distribution of individual ectotherm with the thermal properties of habitat (thermal habitat). In this study we modelled the relationship between the two by a spatial explicit model that simulates the movements of a lizard in a controlled environment. The model incorporates a lizard's transient body temperatures with a cellular automaton algorithm as a way to link the physiology knowledge of the animal with the spatial utilization of its microhabitat. On a larger spatial scale, 'thermal roughness' of the habitat was defined and used to predict the habitat occupancy of the target species. The results showed the habitat occupancy can be modelled by the cellular automaton based algorithm at a smaller scale, and can be modelled by the thermal roughness index at a larger scale.

  19. Influence of different temperatures on the thermal fatigue behavior and thermal stability of hot-work tool steel processed by a biomimetic couple laser technique

    Science.gov (United States)

    Meng, Chao; Zhou, Hong; Zhou, Ying; Gao, Ming; Tong, Xin; Cong, Dalong; Wang, Chuanwei; Chang, Fang; Ren, Luquan

    2014-04-01

    Three kinds of biomimetic non-smooth shapes (spot-shape, striation-shape and reticulation-shape) were fabricated on the surface of H13 hot-work tool steel by laser. We investigated the thermal fatigue behavior of biomimetic non-smooth samples with three kinds of shapes at different thermal cycle temperature. Moreover, the evolution of microstructure, as well as the variations of hardness of laser affected area and matrix were studied and compared. The results showed that biomimetic non-smooth samples had better thermal fatigue behavior compared to the untreated samples at different thermal cycle temperatures. For a given maximal temperature, the biomimetic non-smooth sample with reticulation-shape had the optimum thermal fatigue behavior, than with striation-shape which was better than that with the spot-shape. The microstructure observations indicated that at different thermal cycle temperatures the coarsening degrees of microstructures of laser affected area were different and the microstructures of laser affected area were still finer than that of the untreated samples. Although the resistance to thermal cycling softening of laser affected area was lower than that of the untreated sample, laser affected area had higher microhardness than the untreated sample at different thermal cycle temperature.

  20. Comparative evaluation of thermal decomposition behavior and thermal stability of powdered ammonium nitrate under different atmosphere conditions.

    Science.gov (United States)

    Yang, Man; Chen, Xianfeng; Wang, Yujie; Yuan, Bihe; Niu, Yi; Zhang, Ying; Liao, Ruoyu; Zhang, Zumin

    2017-09-05

    In order to analyze the thermal decomposition characteristics of ammonium nitrate (AN), its thermal behavior and stability under different conditions are studied, including different atmospheres, heating rates and gas flow rates. The evolved decomposition gases of AN in air and nitrogen are analyzed with a quadrupole mass spectrometer. Thermal stability of AN at different heating rates and gas flow rates are studied by differential scanning calorimetry, thermogravimetric analysis, paired comparison method and safety parameter evaluation. Experimental results show that the major evolved decomposition gases in air are H 2 O, NH 3 , N 2 O, NO, NO 2 and HNO 3 , while in nitrogen, H 2 O, NH 3 , NO and HNO 3 are major components. Compared with nitrogen atmosphere, lower initial and end temperatures, higher heat flux and broader reaction temperature range are obtained in air. Meanwhile, higher air gas flow rate tends to achieve lower reaction temperature and to reduce thermal stability of AN. Self-accelerating decomposition temperature of AN in air is much lower than that in nitrogen. It is considered that thermostability of AN is influenced by atmosphere, heating rate and gas flow rate, thus changes of boundary conditions will influence its thermostability, which is helpful to its safe production, storage, transportation and utilization. Copyright © 2017 Elsevier B.V. All rights reserved.

  1. Parametric study for design of thermal sleeves

    International Nuclear Information System (INIS)

    Mukherjee, A.B.; Mehra, V.K.

    1985-01-01

    Thermal sleeves are used inside nozzle in many reactor components. Basic aim in design of thermal sleeve is to arrive at a set of dimensions for gap and annulus length, which will give rise to minimum thermal gradient in the base metal of the associated nozzle. Study includes the minimisation of the thermal gradient in the crotch zone by suitable choice of gap and annulus length. Three different geometries of nozzle radii 50.00 mm., 100 mm. and 200.0 mm. are studied for single and two concentric thermal sleeves model. The paper also presents effect of parameters like velocity of flow, temperature of fluid, materials etc. on the design of thermal sleeves. (orig.)

  2. Effect of Thermal Environment on the Mechanical Behaviors of Building Marble

    Directory of Open Access Journals (Sweden)

    Haijian Su

    2018-01-01

    Full Text Available High temperature and thermal environment can influence the mechanical properties of building materials worked in the civil engineering, for example, concrete, building rock, and steel. This paper examines standard cylindrical building marble specimens (Φ50 × 100 mm that were treated with high temperatures in two different thermal environments: vacuum (VE and airiness (AE. Uniaxial compression tests were also carried out on those specimens after heat treatment to study the effect that the thermal environment has on mechanical behaviors. With an increase in temperature, the mechanical behavior of marble in this study indicates a critical temperature of 600°C. Both the peak stress and elasticity modulus were larger for the VE than they were for the AE. The thermal environment has an obvious influence on the mechanical properties, especially at temperatures of 450∼750°C. The failure mode of marble specimens under uniaxial compression is mainly affected by the thermal environment at 600°C.

  3. Thermal behavior of the Medicina 32-meter radio telescope

    Science.gov (United States)

    Pisanu, Tonino; Buffa, Franco; Morsiani, Marco; Pernechele, Claudio; Poppi, Sergio

    2010-07-01

    We studied the thermal effects on the 32 m diameter radio-telescope managed by the Institute of Radio Astronomy (IRA), Medicina, Bologna, Italy. The preliminary results show that thermal gradients deteriorate the pointing performance of the antenna. Data has been collected by using: a) two inclinometers mounted near the elevation bearing and on the central part of the alidade structure; b) a non contact laser alignment optical system capable of measuring the secondary mirror position; c) twenty thermal sensors mounted on the alidade trusses. Two series of measurements were made, the first series was performed by placing the antenna in stow position, the second series was performed while tracking a circumpolar astronomical source. When the antenna was in stow position we observed a strong correlation between the inclinometer measurements and the differential temperature. The latter was measured with the sensors located on the South and North sides of the alidade, thus indicating that the inclinometers track well the thermal deformation of the alidade. When the antenna pointed at the source we measured: pointing errors, the inclination of the alidade, the temperature of the alidade components and the subreflector position. The pointing errors measured on-source were 15-20 arcsec greater than those measured with the inclinometer.

  4. Shuttle APS propellant thermal conditioner study

    Science.gov (United States)

    Pearson, W. E.

    1971-01-01

    A study program was performed to allow selection of thermal conditioner assemblies for superheating O2 and H2 at supercritical pressures. The application was the auxiliary propulsion system (APS) for the space shuttle vehicle. The O2/H2 APS propellant feed system included propellant conditioners, of which the thermal conditioner assemblies were a part. Cryogens, pumped to pressures above critical, were directed to the thermal conditioner assembly included: (1) a gas generator assembly with ignition system and bipropellant valves, which burned superheated O2 and H2 at rich conditions; (2) a heat exchanger assembly for thermal conditioning of the cryogenic propellant; and (3) a dump nozzle for heat exchanger exhaust.

  5. Thermal behavior of the duct applied functionally graded material

    Energy Technology Data Exchange (ETDEWEB)

    Park, Jung Sun; Yoon, Dong Young; Im, Jong Bin [Hankuk Aviation Univ., Goyang (Korea, Republic of)

    2004-07-01

    In Unmanned Aerial Vehicles (UAV), the high temperature results from friction among the air, combustion of fuel in engine and combustion gas of a nozzle. The high temperature may cause serious damages in UAV structure. The Functionally Graded Material(FGM) is chosen as a material of the engine duct structure. Thermal stress analysis of FGM is performed in this paper. FGM is composed of two constituent materials that are mixed up according to the specific volume fraction distribution in order to withstand high temperature. Therefore, hoop stress, axial stress and shear stress of duct with 2 layers, 4 layers and 8 layers FGM are compared and analyzed respectively. In addition, the creep behavior of FGM used in duct structure of an engine is analyzed for better understanding of FGM characteristics.

  6. INVESTIGATION OF THERMAL BEHAVIOR OF MULTILAYERED FIRE RESISTANT STRUCTURE

    Directory of Open Access Journals (Sweden)

    R. GUOBYS

    2016-09-01

    Full Text Available This paper presents experimental and numerical investigations of thermal behavior under real fire conditions of new generation multilayered fire resistant structure (fire door, dimensions H × W × D: 2090 × 980 × 52 mm combining high strength and fire safety. This fire door consists of two steel sheets (thickness 1.5 and 0.7 mm with stone wool ( = 33 kg/m3, k = 0.037 W/mK, E = 5000 N/m2,  = 0.2 insulating layer in between. One surface of the structure was heated in fire furnace for specified period of time of 60 min. Temperature and deformation of opposite surface were measured from outside at selected measuring points during fire resistance test. Results are presented as temperature-time and thermal deformation-time graphs. Experimental results were compared with numerical temperature field simulation results obtained from SolidWorks®Simulation software. Numerical results were found to be in good agreement with experimental data. The percent differences between door temperatures from simulation and fire resistance test don’t exceed 8%. This shows that thermal behaviour of such multilayered structures can be investigated numerically, thus avoiding costly and time-consuming fire resistance tests. It is established that investigated structure should be installed in a way that places thicker steel sheet closer to the potential heat source than thinner one. It is also obtained that stone wool layer of higher density should be used to improve fire resistance of the structure.

  7. Thermal release behavior of helium from copper irradiated by He+ ions

    International Nuclear Information System (INIS)

    Yamauchi, T.; Tokura, S.; Yamanaka, S.; Miyake, M.

    1988-01-01

    Thermal release behavior of helium from copper irradiated by 20 keV He + ions with a dose of 2x10 15 to 3x10 17 ions/cm 2 has been studied. The shape of the thermal release curves and thew number of helium release peaks strongly depend on the irradiation dose. Results from SEM surface observastion after post-irradiation heating suggested that helium release caused various surface damages such as blistering, flaking, and hole formation. Helium release resulting in small holes was analyzed and helium bubble growth mechanisms are discussed. (orig.)

  8. Thermal degradation and isothermal crystalline behavior of poly(trimethylene terephthalate)

    Institute of Scientific and Technical Information of China (English)

    Jian Liu; Shu Guang Bian; Min Xiao; Shuan Jin Wang; Yue Zhong Meng

    2009-01-01

    Poly(trimethylene terephthalate)(PTT)is an excellent fiber material.Its thermal degradation and isothermal crystalline behaviors were in this study investigated using thermogravimetric analysis(TGA),thermogravimetric analysis-Fourier transform infrared spectroscopy(TGA-FTIR)analysis,differential scanning calorimetry(DSC)and X-ray diffraction(XRD).The thermal degradation mechanism of PTT follows Mclafferty rearrangement principle.The PTT with intrinsicviscosity(IV)of 0.74 dL/g has a maximum crystallinity of about 55%at 190℃,as demonstrated by DSC and XRD measurements consistently.

  9. Behavior of deep flaws in a thick-wall cylinder under thermal shock loading

    International Nuclear Information System (INIS)

    Cheverton, R.D.

    1979-01-01

    Behavior of inner-surface flaws in thick-walled vessels was studied in a 991-mm OD x 152 mm wall x 1220 mm length cylinder with toughness properties similar to those for HSST Plate. The initial temperature of 93 0 C and a thermal shock medium of liquid nitrogen (-197 0 C) were employed. The initial flaw selected was a sharp, 16 mm deep, long (1220 mm) axial crack. Crack arrest methodology was shown to be valid for deep flaws under severe thermal shock

  10. Organic tank safety project: Preliminary results of energetics and thermal behavior studies of model organic nitrate and/or nitrite mixtures and a simulated organic waste

    International Nuclear Information System (INIS)

    Scheele, R.D.; Sell, R.L.; Sobolik, J.L.; Burger, L.L.

    1995-08-01

    As a result of years of production and recovery of nuclear defense materials and subsequent waste management at the Hanford Site, organic-bearing radioactive high-level wastes (HLW) are currently stored in large (up to 3. ML) single-shell storage tanks (SSTs). Because these wastes contain both fuels (organics) and the oxidants nitrate and nitrite, rapid energetic reactions at certain conditions could occur. In support of Westinghouse Hanford Company's (WHC) efforts to ensure continued safe storage of these organic- and oxidant-bearing wastes and to define the conditions necessary for reactions to occur, we measured the thermal sensitivities and thermochemical and thermokinetic properties of mixtures of selected organics and sodium nitrate and/or nitrite and a simulated Hanford organic-bearing waste using thermoanalytical technologies. These thermoanalytical technologies are used by chemical reactivity hazards evaluation organizations within the chemical industry to assess chemical reaction hazards

  11. An Integrated Hot-Stage Microscope-Direct Analysis in Real Time-Mass Spectrometry System for Studying the Thermal Behavior of Materials.

    Science.gov (United States)

    Ashton, Gage P; Harding, Lindsay P; Parkes, Gareth M B

    2017-12-19

    This paper describes a new analytical instrument that combines a precisely temperature-controlled hot-stage with digital microscopy and Direct Analysis in Real Time-mass spectrometry (DART-MS) detection. The novelty of the instrument lies in its ability to monitor processes as a function of temperature through the simultaneous recording of images, quantitative color changes, and mass spectra. The capability of the instrument was demonstrated through successful application to four very varied systems including profiling an organic reaction, decomposition of silicone polymers, and the desorption of rhodamine B from an alumina surface. The multidimensional, real-time analytical data provided by this instrument allow for a much greater insight into thermal processes than could be achieved previously.

  12. Organic tank safety project: Preliminary results of energetics and thermal behavior studies of model organic nitrate and/or nitrite mixtures and a simulated organic waste

    Energy Technology Data Exchange (ETDEWEB)

    Scheele, R.D.; Sell, R.L.; Sobolik, J.L.; Burger, L.L.

    1995-08-01

    As a result of years of production and recovery of nuclear defense materials and subsequent waste management at the Hanford Site, organic-bearing radioactive high-level wastes (HLW) are currently stored in large (up to 3. ML) single-shell storage tanks (SSTs). Because these wastes contain both fuels (organics) and the oxidants nitrate and nitrite, rapid energetic reactions at certain conditions could occur. In support of Westinghouse Hanford Company`s (WHC) efforts to ensure continued safe storage of these organic- and oxidant-bearing wastes and to define the conditions necessary for reactions to occur, we measured the thermal sensitivities and thermochemical and thermokinetic properties of mixtures of selected organics and sodium nitrate and/or nitrite and a simulated Hanford organic-bearing waste using thermoanalytical technologies. These thermoanalytical technologies are used by chemical reactivity hazards evaluation organizations within the chemical industry to assess chemical reaction hazards.

  13. Influence of user behavior on unsatisfactory indoor thermal environment

    International Nuclear Information System (INIS)

    Yan, Biao; Long, Enshen; Meng, Xi; Zhang, Yuanze; Hou, Dongqi; Du, Xin

    2014-01-01

    Highlights: • The methodology of numerical simulation of 3D heat-flux visualization is proposed. • A full-scale model of prototype office for each influential factor was set up. • The simulation results were compared with the indoor occupant comfort levels. • The contrast of average temperature increase due to user behavior was presented. - Abstract: In areas of China that have hot summers and cold winters, the overall performance of HVAC systems in the poorly-insulated existing office buildings is generally not satisfactory, especially in extreme weather conditions. The reasons for the unsatisfactory indoor thermal environment were deduced, and to validate the findings, a methodology of numerical simulation for 3D heat-flux visualization was proposed. A full-scale model of a prototype office room was created, with representative working conditions for the characteristics of particular building. The results of the heat-flux visualization and temperature distribution showed that the overall effect was resulted from merged reasons, and that significance ranking of each reason varied when the outside environmental conditions changed. The simulation results were compared with the indoor occupant comfort levels of the volunteers who worked in the target room. Models of possible influential factors such as the outdoor temperature, opening or closing windows, and the effect of window shading devices (WSD) were set up. The influence of user behavior on indoor temperature in opening window, or not using WSD was proven to be significant in causing unfavorable indoor conditions. According to the visualized evaluation and analysis of the various factors, corresponding methods for both improving indoor thermal conditions and saving energy are proposed

  14. Spectroscopic, thermal and biological studies of coordination

    Indian Academy of Sciences (India)

    Spectroscopic, thermal and biological studies of coordination compounds of sulfasalazine drug: Mn(II), Hg(II), Cr(III), ZrO(II), VO(II) and Y(III) transition metal ... The thermal decomposition of the complexes as well as thermodynamic parameters ( *}, *, * and *) were estimated using Coats–Redfern and ...

  15. Study of thermal conductivity of multilayer insulation

    Energy Technology Data Exchange (ETDEWEB)

    Dutta, D; Sundaram, S; Nath, G K; Sethuram, N P; Chandrasekharan, T; Varadarajan, T G [Heavy Water Division, Bhabha Atomic Research Centre, Mumbai (India)

    1994-06-01

    This paper presents experimental determination of the apparent thermal conductivity of multilayer insulation for a cryogenic system. The variation of thermal conductivity with residual gas pressure is studied and the optimum vacuum for good insulating performance is determined. Evaporation loss technique for heat-inleak determination is employed. (author). 3 refs., 3 figs.

  16. Study of thermal conductivity of multilayer insulation

    International Nuclear Information System (INIS)

    Dutta, D.; Sundaram, S.; Nath, G.K.; Sethuram, N.P.; Chandrasekharan, T.; Varadarajan, T.G.

    1994-01-01

    This paper presents experimental determination of the apparent thermal conductivity of multilayer insulation for a cryogenic system. The variation of thermal conductivity with residual gas pressure is studied and the optimum vacuum for good insulating performance is determined. Evaporation loss technique for heat-inleak determination is employed. (author)

  17. Analysis of the thermal behavior of AlGaN/GaN HEMTs

    International Nuclear Information System (INIS)

    Russo, Salvatore; D’Alessandro, Vincenzo; Costagliola, Maurizio; Sasso, Grazia; Rinaldi, Niccolò

    2012-01-01

    Highlights: ► The thermal behavior of advanced multifinger AlGaN/GaN HEMTs grown on SiC is analyzed. ► The study is performed through accurate FEM simulations and DC/dynamic measurements. ► The FEM analysis is supported by an in-house tool devised for a smart mesh generation. ► Illustrative technology/layout guidelines to minimize the thermal issues are provided. - Abstract: The thermal behavior of state-of-the-art multifinger AlGaN/GaN HEMTs grown on SiC is thoroughly analyzed under steady-state and dynamic conditions. Accurate 3-D FEM simulations – based on a novel in-house tool devised to automatically build the device mesh – are performed using a commercial software to explore the influence of various layout and technological solutions on the temperature field. An in-house routine is employed to determine the Foster/Cauer networks suited to describe the dynamic heat propagation through the device structure. To conclude, various experimental techniques are employed to assess the thermal resistance and to allow the monitoring of the thermal impedance versus time of the transistors under test.

  18. Thermal fluctuations and critical behavior in a magnetized, anisotropic plasma

    International Nuclear Information System (INIS)

    Hazeltine, R. D.; Mahajan, S. M.

    2013-01-01

    Thermal fluctuations in a magnetized, anisotropic plasma are studied by applying standard methods, based on the Einstein rule, to the known thermodynamic potential of the system. It is found in particular that magnetic fluctuations become critical when the anisotropy p ∥ −p ⊥ changes sign. By examining the critical region, additional insight on the equations of state for near-critical anisotropic plasma is obtained

  19. Thermal shock behavior of platinum aluminide bond coat/electron beam-physical vapor deposited thermal barrier coatings

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Zhenhua, E-mail: zhxuciac@163.com [Beijing Institute of Aeronautical Materials, Department 5, P.O. Box 81-5, Beijing 100095 (China); Dai, Jianwei [Beijing Institute of Aeronautical Materials, Department 5, P.O. Box 81-5, Beijing 100095 (China); Niu, Jing [Shenyang Liming Aero-engine (Group) Corporation Ltd., Institute of Metallurgical Technology, Technical Center, Shengyang 110043 (China); Li, Na; Huang, Guanghong; He, Limin [Beijing Institute of Aeronautical Materials, Department 5, P.O. Box 81-5, Beijing 100095 (China)

    2014-12-25

    Highlights: • TBCs of (Ni, Pt)Al bond coat with grit blasting process and YSZ ceramic coating. • Grain boundary ridges are the sites for spallation damage initiation in TBCs. • Ridges removed, cavities formation appeared and the damage initiation deteriorated. • Damage initiation and progression at interface lead to a buckling failure. - Abstract: Thermal barrier coating systems (TBCs) including of chemical vapor deposited (Ni, Pt)Al bond coat with grit blasting process and electron beam physical vapor deposited Y{sub 2}O{sub 3}-stabilized-ZrO{sub 2} (YSZ) ceramic coating were investigated. The phase structures, surface and cross-sectional morphologies, thermal shock behaviors and residual stresses of the coatings were studied in detail. Grain boundary ridges still remain on the surface of bond coat prior to the deposition of the ceramic coating, which are shown to be the major sites for spallation damage initiation in TBCs. When these ridges are mostly removed, they appear some of cavities formation and then the damage initiation mode is deteriorated. Damage initiation and progression occurs at the bond coat to thermally grown oxide (TGO) interface leading to a buckling failure behavior. A buckle failure once started may be arrested when it runs into a region of high bond coat to TGO interface toughness. Thus, complete failure requires further loss in toughness of the bond coat to TGO interface during cooling. The suppressed cavities formation, the removed ridges at the grain boundaries, the relative high TGO to bond coat interface toughness, the uniform growth behavior of TGO thickening and the lower of the residual stress are the primary factors for prolonging the lifetime of TBCs.

  20. A study on the thermal decomposition behavior of derivatives of 1,5-diamino-1H-tetrazole (DAT): A new family of energetic heterocyclic-based salts

    International Nuclear Information System (INIS)

    Fischer, Gerd; Holl, Gerhard; Klapoetke, Thomas M.; Weigand, Jan J.

    2005-01-01

    The thermal decomposition of the highly energetic 1,5-diamino-4-methyl-1H-tetrazolium nitrate (2b), 1,5-diamino-4-methyl-1H-tetrazolium dinitramide (2c) and 1,5-diamino-4-methyl-1H-tetrazolium azide (2d) were investigated by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). Mass spectrometry and IR spectroscopy were used to identify the gaseous products. Decomposition appears in the cases of 2c and 2d to be initiated by a proton transfer to form the corresponding acid HN 3 and HN 3 O 4 whereas in the case of 2b a methyl group transfer to MeONO 2 is observed as initial process. The gaseous products after the exothermic decomposition are comparable and are in agreement of the possible decomposition pathways discussed for the corresponding compounds. For all processes, possible decomposition schemes are presented. The decomposition temperatures of 2b and 2c are significantly higher than that of 2d and were supported by evaluation the values of the activation energy according the method of Ozawa and Kissinger

  1. Studies of behavior of the fuel compound based on the U-Zr micro-heterogeneous quasialloy during cyclic thermal tests

    Science.gov (United States)

    Zaytsev, D. A.; Repnikov, V. M.; Soldatkin, D. M.; Solntsev, V. A.

    2017-11-01

    This paper provides the description of temperature cycle testing of U-Zr heterogeneous fuel composition. The composition is essentially a niobium-doped zirconium matrix with metallic uranium filaments evenly distributed over the cross section. The test samples 150 mm long had been fabricated using a fiber-filament technology. The samples were essentially two-bladed spiral mandrel fuel elements parts. In the course of experiments the following temperatures were applied: 350, 675, 780 and 1140 °C with total exposure periods equal to 200, 30, 30 and 6 hours respectively. The fuel element samples underwent post-exposure material science examination including: geometry measurements, metallographic analysis, X-ray phase analysis and electron-microscopic analysis as well as micro-hardness measurement. It has been found that no significant thermal swelling of the samples occurs throughout the whole temperature range from 350 °C up to 1140 °C. The paper presents the structural changes and redistribution of the fuel component over the fuel element cross section with rising temperature.

  2. Buckling Behavior of Cold-Formed Studs with Thermal Perforations

    Directory of Open Access Journals (Sweden)

    Garifullin Marsel

    2016-01-01

    Full Text Available Studies have shown that the optimal structural scheme for low-rise buildings that meets all regulatory requirements is a frame system. In this connection, thin-walled cold-formed steel (CFS profiles seem to be the best material for constructing light steel framed (LSF walls. The framework of LSF walls is usually constructed from CFS C-shaped profiles. To increase the thermal effectiveness of a wall, CFS profiles usually have thermal perforations and thus are called thermoprofiles. However, these openings have a negative impact on bearing capacity of profiles and require accurate evaluation. In this article a relatively new reticular-stretched thermoprofile with diamond-shaped openings is considered. The article deals with the buckling analysis of perforated CFS C-sections subjected to compression.

  3. Coupling of Mechanical Behavior of Lithium Ion Cells to Electrochemical-Thermal (ECT) Models for Battery Crush

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Chao; Santhanagopalan, Shriram; Pesaran, Ahmad; Sahraei, Elham; Wierzbicki, Tom

    2016-06-14

    Vehicle crashes can lead to crushing of the battery, damaging lithium ion battery cells and causing local shorts, heat generation, and thermal runaway. Simulating all the physics and geometries at the same time is challenging and takes a lot of effort; thus, simplifications are needed. We developed a material model for simultaneously modeling the mechanical-electrochemical-thermal behavior, which predicted the electrical short, voltage drop, and thermal runaway behaviors followed by a mechanical abuse-induced short. The effect of short resistance on the battery cell performance was studied.

  4. Flexural behavior and design of steel-plate composite (SC) walls for accident thermal loading

    Energy Technology Data Exchange (ETDEWEB)

    Booth, Peter N., E-mail: boothpn@purdue.edu [Lyles School of Civil Engineering, Purdue University, West Lafayette, IN (United States); Varma, Amit H., E-mail: ahvarma@purdue.edu [Lyles School of Civil Engineering, Purdue University, West Lafayette, IN (United States); Sener, Kadir C., E-mail: ksener@purdue.edu [Lyles School of Civil Engineering, Purdue University, West Lafayette, IN (United States); Malushte, Sanjeev R. [Bechtel Corp., Frederick, MD (United States)

    2015-12-15

    Modular steel-plate composite (SC) safety-related nuclear power plant structures must be designed to resist accident thermal and mechanical loads. The design accident thermal load represents the condition where high pressure and temperature steam is released as result of a mechanical failure and applied against the surfaces of power plant structural walls. The effect of heating and pressure can have both short and long term effects on the mechanical integrity of SC structures including degradation and cracking of concrete infill, residual stresses, and out-of-plane deformations. The purpose of this research is to study the effects of thermal and mechanical loads on the out-of-plane flexural response of SC walls and to develop simplified equations that can be used to predict behavior. Four experimental beam tests are reported that represent full-scale cross-sections of SC walls subjected to combinations of mechanical and thermal loads. The study determined that thermal loads reduce the out-of-plane flexural stiffness of SC walls. For the ambient condition, the flexural stiffness closely matches a conventional elastic cracked-transformed model, and at elevated temperatures, the stiffness is reduced to a fully-cracked flexural stiffness that only takes into account the stiffness of the steel faceplates. A method is presented for estimating the thermal curvature, ϕ{sub th}, and thermal moment, M{sub th}, resulting from unequal heating of opposing faces of an SC wall. Based on the tests in this study, the application of accident thermal loads did not result in a reduction of the flexural strength of the SC section.

  5. A-thermal elastic behavior of silicate glasses.

    Science.gov (United States)

    Rabia, Mohammed Kamel; Degioanni, Simon; Martinet, Christine; Le Brusq, Jacques; Champagnon, Bernard; Vouagner, Dominique

    2016-02-24

    Depending on the composition of silicate glasses, their elastic moduli can increase or decrease as function of the temperature. Studying the Brillouin frequency shift of these glasses versus temperature allows the a-thermal composition corresponding to an intermediate glass to be determined. In an intermediate glass, the elastic moduli are independent of the temperature over a large temperature range. For sodium alumino-silicate glasses, the a-thermal composition is close to the albite glass (NaAlSi3O8). The structural origin of this property is studied by in situ high temperature Raman scattering. The structure of the intermediate albite glass and of silica are compared at different temperatures between room temperature and 600 °C. When the temperature increases, it is shown that the high frequency shift of the main band at 440 cm(-1) in silica is a consequence of the cristobalite-like alpha-beta transformation of 6-membered rings. This effect is stronger in silica than bond elongation (anharmonic effects). As a consequence, the elastic moduli of silica increase as the temperature increases. In the albite glass, the substitution of 25% of Si(4+) ions by Al(3+) and Na(+) ions decreases the proportion of SiO2 6-membered rings responsible for the silica anomaly. The effects of the silica anomaly balance the anharmonicity in albite glass and give rise to an intermediate a-thermal glass. Different networks, formers or modifiers, can be added to produce different a-thermal glasses with useful mechanical or chemical properties.

  6. Study on thermal conductive BN/novolac resin composites

    International Nuclear Information System (INIS)

    Li, Shasha; Qi, Shuhua; Liu, Nailiang; Cao, Peng

    2011-01-01

    Highlights: → Boron nitride (BN) particles were used to modify novolac resin. → BN particles were pretreated by γ-aminopropyltriethoxysilane. → The thermal conductivity trend of composite almost agrees with the predicted data from the Maxwell-Eucken model. → At BN concentration of 80 wt.%, thermal conductivity value of composite is 4.5 times that of pure novolac resin. → Combined use of the larger and smaller particles with a mass ratio of 1:2 provides the composites with the maximum thermal conductivity among the testing systems. → The composite thermal property also increases with an increase in the BN concentration. - Abstract: In this study, γ-aminopropyltriethoxysilane-treated boron nitride (BN) particles were used to modify novolac resin. The effect of varying the BN concentration, particle size, and hybrid BN fillers with the binary particle size distribution on the thermal conductivity of the composites was investigated. Scanning electron microscopy (SEM) imaging showed homogeneously dispersed treated BN particles in the matrix. Furthermore, the thermal conductivity increased as the BN concentration was increased. This behavior was also observed when the filler size was increased. Experimentally obtained thermal conductivity values agree with the predicted data from the Maxwell-Eucken model well at less than 70 wt.% BN loading. A larger particle size BN-filled novolac resin exhibits a higher thermal conductivity than a smaller particle size BN-filled one. The combined use of 0.5 and 15 μm particles with a mass ratio of 2:1 achieved the maximum thermal conductivity among the testing systems. The thermal resistance properties of the composites were also studied.

  7. Understanding thermally activated plastic deformation behavior of Zircaloy-4

    Science.gov (United States)

    Kumar, N.; Alomari, A.; Murty, K. L.

    2018-06-01

    Understanding micromechanics of plastic deformation of existing materials is essential for improving their properties further and/or developing advanced materials for much more severe load bearing applications. The objective of the present work was to understand micromechanics of plastic deformation of Zircaloy-4, a zirconium-based alloy used as fuel cladding and channel (in BWRs) material in nuclear reactors. The Zircaloy-4 in recrystallized (at 973 K for 4 h) condition was subjected to uniaxial tensile testing at a constant cross-head velocity at temperatures in the range 293 K-1073 K and repeated stress relaxation tests at 293 K, 573 K, and 773 K. The minimum in the total elongation was indicative of dynamic strain aging phenomenon in this alloy in the intermediate temperature regime. The yield stress of the alloy was separated into effective and athermal components and the transition from thermally activated dislocation glide to athermal regime took place at around 673 K with the athermal stress estimated to be 115 MPa. The activation volume was found to be in the range of 40 b3 to 160 b3. The activation volume values and the data analyses using the solid-solution models in literature indicated dislocation-solute interaction to be a potential deformation mechanism in thermally activated regime. The activation energy calculated at 573 K was very close to that found for diffusivity of oxygen in α-Zr that was suggestive of dislocations-oxygen interaction during plastic deformation. This type of information may be helpful in alloy design in selecting different elements to control the deformation behavior of the material and impart desired mechanical properties in those materials for specific applications.

  8. Thermal loading study for FY 1995

    International Nuclear Information System (INIS)

    1996-01-01

    This report provides the results of sensitivity analyses designed to assist the test planners in focusing their in-situ measurements on parameters that appear to be important to waste isolation. Additionally, the study provides a preliminary assessment of the feasibility of certain thermal management options. A decision on thermal loading is a critical part of the scientific and engineering basis for evaluating regulatory compliance of the potential repository for waste isolation. To show, with reasonable assurance, that the natural and engineered barriers will perform adequately under expected repository conditions (thermally perturbed) will require an integrated approach based on thermal testing (laboratory, and in-situ), natural analog observations, and analytic modeling. The Office of Civilian Radioactive Waste Management needed input to assist in the planning of the thermal testing program. Additionally, designers required information on the viability of various thermal management concepts. An approximately 18-month Thermal Loading Study was conducted from March, 1994 until September 30, 1995 to address these issues. This report documents the findings of that study. 89 refs., 71 figs., 33 tabs

  9. imide, crystal structure, thermal and dielectric studies

    Indian Academy of Sciences (India)

    methyl imidazolium methylidene bis(trifluoromethanesulfonyl)imide, crystal structure, thermal and dielectric studies. BOUMEDIENE HADDAD1,2,3,∗, TAQIYEDDINE MOUMENE2, DIDIER VILLEMIN1,. JEAN-FRANÇOIS LOHIER1 and EL-HABIB ...

  10. Mechanical behavior of mullite green disks prepared by thermal consolidation with different starches

    International Nuclear Information System (INIS)

    Talou, M.H.; Tomba Martinez, A.G.; Camerucci, M.A.

    2011-01-01

    Mechanical behavior of porous green disks obtained by thermal consolidation of mullite suspensions with cassava and potato starches was studied by diametral compression testing. Disks (thickness/diameter ≤ 0.25) were prepared by thermal treatment (70-80 °C, 2h) of mullite (75 vol%)/starch (25 vol%) of suspensions (40 vol%) pre-gelled at 55-60 °C, and dried (40 °C, 24 h). Samples were characterized by porosity measurements (50-55%) and microstructural analysis (SEM). Several mechanical parameters were determined: mechanical strength, Young's modulus, strain to fracture and yield stress. Typical crack patterns were analyzed and the fractographic analysis was performed by SEM. Mechanical results were related to the developed microstructures, the behavior of the starches in aqueous suspension, and the properties of the formed gels. For comparative purposes, mullite green disks obtained by burning out the starch (650 °C, 2h) were also mechanically evaluated. (author)

  11. Modeling of Thermal Behavior of Raw Natural Gas Air Coolers

    Science.gov (United States)

    Scherbinin, S. V.; Prakhova, M. Yu; Krasnov, A. N.; Khoroshavina, E. A.

    2018-05-01

    When gas is being prepared for a long-range transportation, it passes through air cooling units (ACUs) after compressing; there, hot gas passing through finned tubes is cooled with air streams. ACU's mode of operation shall ensure a certain value of gas temperature at the ACU's outlet. At that, when cooling raw gas, temperature distribution along all the tubes shall be known to prevent local hydrate formation. The paper proposes a mathematical model allowing one to obtain a thermal field distribution inside the ACU and study influence of various factors onto it.

  12. Thermal Behavior of the Reactor Vessel Penetration Under External Vessel Cooling During a Severe Accident

    International Nuclear Information System (INIS)

    Kang, Kyoung-Ho; Park, Rae-Joon; Kim, Jong-Tae; Min, Byung-Tae; Lee, Ki-Young; Kim, Sang-Baik

    2004-01-01

    Experimental and analytical studies on the thermal behavior of reactor vessel penetration have been performed under external vessel cooling during a severe accident in the Korean next-generation reactor APR1400. Two types of tests, SUS-EXT and SUS-DRY with and without external vessel cooling, respectively, have been performed using sustained heating by an induction heater. Three tests have been carried out varying the cooling conditions at the vessel outer surface in the SUS-EXT tests. The experimental results have been thermally estimated using the LILAC computer code. The experimental results indicate that the inner surface of the vessel was ablated by the 45-mm thickness in the SUS-DRY test. Despite the total ablation of the welding material, the penetration was not ejected outside the vessel, which could be attributed to the thermal expansion of the penetration. Unlike the SUS-DRY test, the thickness of the ablation was ∼15 to 20 mm at most, so the welding was preserved in the SUS-EXT tests. It is concluded from the experimental results that the external vessel cooling highly affected the ablation configuration and the thermal behaviors of the vessel and the penetration. An increase in coolant mass flow rate from 0.047 to 0.152 kg/s had effects on the thermal behavior of the lower head vessel and penetration in the SUS-EXT tests. The LILAC analytical results on temperature distribution and ablation depth in the lower head vessel and penetration were very similar to the experimental results

  13. Surface Structures and Thermal Desorption Behaviors of Cyclopentanethiol Self-Assembled Monolayers on Au(111)

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Hun Gu; Kim, You Young; Park, Tae Sun; Noh, Jae Geun [Hanyang University, Seoul (Korea, Republic of); Park, Joon B. [Chonbuk National University, Jeonju (Korea, Republic of); Ito, Eisuke; Hara, Masahiko [RIKEN-HYU Collaboration Center, Saitama (Japan)

    2011-04-15

    The surface structures, adsorption conditions, and thermal desorption behaviors of cyclopentanethiol (CPT) self-assembled monolayers (SAMs) on Au(111) were investigated by scanning tunneling microscopy (STM), X-ray photoelectron spectroscopy (XPS), and thermal desorption spectroscopy (TDS). STM imaging revealed that although the adsorption of CPT on Au(111) at room temperature generates disordered SAMs, CPT molecules at 50 .deg. C formed well-ordered SAMs with a (2√3 x √5)R41{sup .}deg. packing structure. XPS measurements showed that CPT SAMs at room temperature were formed via chemical reactions between the sulfur atoms and gold surfaces. TDS measurements showed two dominant TD peaks for the decomposed fragments (C{sub 5}H{sub 9} {sup +}, m/e = 69) generated via C-S bond cleavage and the parent molecular species (C{sub 5}H{sub 9}SH{sup +}, m/e = 102) derived from a recombination of the chemisorbed thiolates and hydrogen atoms near 440 K. Interestingly, dimerization of sulfur atoms in n-alkanethiol SAMs usually occurs during thermal desorption and the same reaction did not happen for CPT SAMs, which may be due to the steric hindrance of cyclic rings of the CPT molecules. In this study, we demonstrated that the alicyclic ring of organic thiols strongly affected the surface structure and thermal desorption behavior of SAMs, thus providing a good method for controlling chemical and physical properties of organic thiol SAMs.

  14. Surface Structures and Thermal Desorption Behaviors of Cyclopentanethiol Self-Assembled Monolayers on Au(111)

    International Nuclear Information System (INIS)

    Kang, Hun Gu; Kim, You Young; Park, Tae Sun; Noh, Jae Geun; Park, Joon B.; Ito, Eisuke; Hara, Masahiko

    2011-01-01

    The surface structures, adsorption conditions, and thermal desorption behaviors of cyclopentanethiol (CPT) self-assembled monolayers (SAMs) on Au(111) were investigated by scanning tunneling microscopy (STM), X-ray photoelectron spectroscopy (XPS), and thermal desorption spectroscopy (TDS). STM imaging revealed that although the adsorption of CPT on Au(111) at room temperature generates disordered SAMs, CPT molecules at 50 .deg. C formed well-ordered SAMs with a (2√3 x √5)R41".deg. packing structure. XPS measurements showed that CPT SAMs at room temperature were formed via chemical reactions between the sulfur atoms and gold surfaces. TDS measurements showed two dominant TD peaks for the decomposed fragments (C_5H_9 "+, m/e = 69) generated via C-S bond cleavage and the parent molecular species (C_5H_9SH"+, m/e = 102) derived from a recombination of the chemisorbed thiolates and hydrogen atoms near 440 K. Interestingly, dimerization of sulfur atoms in n-alkanethiol SAMs usually occurs during thermal desorption and the same reaction did not happen for CPT SAMs, which may be due to the steric hindrance of cyclic rings of the CPT molecules. In this study, we demonstrated that the alicyclic ring of organic thiols strongly affected the surface structure and thermal desorption behavior of SAMs, thus providing a good method for controlling chemical and physical properties of organic thiol SAMs

  15. Correlation between thermal behavior of clays and their chemical and mineralogical composition: a review

    Science.gov (United States)

    Dwi Yanti, Evi; Pratiwi, I.

    2018-02-01

    Clay's abundance has been widely used as industrial raw materials, especially ceramic and tile industries. Utilization of these minerals needs a thermal process for producing ceramic products. Two studies conducted by Septawander et al. and Chin C et al., showed the relationship between thermal behavior of clays and their chemical and mineralogical composition. Clays are characterized by XRD analysis and thermal analysis, ranging from 1100°C to 1200°C room temperature. Specimen of raw materials of clay which is used for the thermal treatment is taken from different geological conditions and formation. In raw material, Quartz is almost present in all samples. Halloysite, montmorillonite, and feldspar are present in Tanjung Morawa raw clay. KC and MC similar kaolinite and illite are present in the samples. The research illustrates the interrelationships of clay minerals and chemical composition with their heat behavior. As the temperature of combustion increases, the sample reduces a significant weight. The minerals which have undergone a transformation phase became mullite, cristobalite or illite and quartz. Under SEM analysis, the microstructures of the samples showed irregularity in shape; changes occurred due the increase of heat.

  16. Thermal and Irradiation Creep Behavior of a Titanium Aluminide in Advanced Nuclear Plant Environments

    Science.gov (United States)

    Magnusson, Per; Chen, Jiachao; Hoffelner, Wolfgang

    2009-12-01

    Titanium aluminides are well-accepted elevated temperature materials. In conventional applications, their poor oxidation resistance limits the maximum operating temperature. Advanced reactors operate in nonoxidizing environments. This could enlarge the applicability of these materials to higher temperatures. The behavior of a cast gamma-alpha-2 TiAl was investigated under thermal and irradiation conditions. Irradiation creep was studied in beam using helium implantation. Dog-bone samples of dimensions 10 × 2 × 0.2 mm3 were investigated in a temperature range of 300 °C to 500 °C under irradiation, and significant creep strains were detected. At temperatures above 500 °C, thermal creep becomes the predominant mechanism. Thermal creep was investigated at temperatures up to 900 °C without irradiation with samples of the same geometry. The results are compared with other materials considered for advanced fission applications. These are a ferritic oxide-dispersion-strengthened material (PM2000) and the nickel-base superalloy IN617. A better thermal creep behavior than IN617 was found in the entire temperature range. Up to 900 °C, the expected 104 hour stress rupture properties exceeded even those of the ODS alloy. The irradiation creep performance of the titanium aluminide was comparable with the ODS steels. For IN617, no irradiation creep experiments were performed due to the expected low irradiation resistance (swelling, helium embrittlement) of nickel-base alloys.

  17. Three-dimensional FE analysis of the thermal-mechanical behaviors in the nuclear fuel rods

    International Nuclear Information System (INIS)

    Jiang Yijie; Cui Yi; Huo Yongzhong; Ding Shurong

    2011-01-01

    Highlights: → We establish three-dimensional finite element models for nuclear fuel rods. → The thermal-mechanical behaviors at the initial stage of burnup are obtained. → Several parameters on the in-pile performances are investigated. → The parameters have remarkable effects on the in-pile behaviors. → This study lays a foundation for optimal design and irradiation safety. - Abstract: In order to implement numerical simulation of the thermal-mechanical behaviors in the nuclear fuel rods, a three-dimensional finite element model is established. The thermal-mechanical behaviors at the initial stage of burnup in both the pellet and the cladding are obtained. Comparison of the obtained numerical results with those from experiments validates the developed finite element model. The effects of the constraint conditions, several operation and structural parameters on the thermal-mechanical performances of the fuel rod are investigated. The research results indicate that: (1) with increasing the heat generation rates from 0.15 to 0.6 W/mm 3 , the maximum temperature within the pellet increases by 99.3% and the maximum radial displacement at the outer surface of the pellet increases by 94.3%. And the maximum Mises stresses in the cladding all increase; while the maximum values of the first principal stresses within the pellet decrease as a whole; (2) with increasing the heat transfer coefficients between the cladding and the coolant, the internal temperatures reduce and the temperature gradient remains similar; when the heat transfer coefficient is lower than a critical value, the temperature change is sensitive to the heat transfer coefficient. The maximum temperature increases only 7.13% when h changes from 0.5 W/mm 2 K to 0.01 W/mm 2 K, while increases up to 54.7% when h decreases from 0.01 W/mm 2 K to 0.005 W/mm 2 K; (3) the initial gap sizes between the pellet and the cladding significantly affect the thermal-mechanical behaviors in the fuel rod; when the

  18. Comparative analysis of thermal behavior in hollow nuclear fuel pellets

    International Nuclear Information System (INIS)

    Santos, Beatriz M. dos; Alvim, Antonio C.M.

    2017-01-01

    The increase in energy demand in Brazil and in the world is a real problem and several solutions are being considered to mitigate it. Maximization of energy generation, within the safety standards of fuel resources already known, is one of them. In this respect, nuclear energy is a crucial technology to sustain energy demand on several countries. Performances of a solid cylindrical and an annular rod have been verified and compared; where it has been proven that the annular rod can reach a higher nominal power in relation to the solid one. In this paper, the temperature profiles of two distinct nuclear fuel pellets, one of them annular and the other in the shape of a hollow biconcave disc (like the cross section of a red blood cell), were compared to analyze the efficiency and safety of both. The finite differences method allowed the evaluation of the thermal behavior of these pellets, where one specific physical condition was analyzed, regarding convection and conduction at the lateral edges. The results show that the temperature profile of the hollow biconcave disc pellet is lower, about 70 deg C below, when compared to the temperature profile of the annular pellet, considering the same simulation parameters for both pellets. (author)

  19. Comparative analysis of thermal behavior in hollow nuclear fuel pellets

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Beatriz M. dos; Alvim, Antonio C.M., E-mail: bmachado@nuclear.ufrj.br, E-mail: aalvim@gmail.com [Coordenacao de Pos-Graduacao e Pesquisa de Engenharia (PEN/COPPE/UFRJ), Rio de Janeiro, RJ (Brazil). Programa de Engenharia Nuclear

    2017-11-01

    The increase in energy demand in Brazil and in the world is a real problem and several solutions are being considered to mitigate it. Maximization of energy generation, within the safety standards of fuel resources already known, is one of them. In this respect, nuclear energy is a crucial technology to sustain energy demand on several countries. Performances of a solid cylindrical and an annular rod have been verified and compared; where it has been proven that the annular rod can reach a higher nominal power in relation to the solid one. In this paper, the temperature profiles of two distinct nuclear fuel pellets, one of them annular and the other in the shape of a hollow biconcave disc (like the cross section of a red blood cell), were compared to analyze the efficiency and safety of both. The finite differences method allowed the evaluation of the thermal behavior of these pellets, where one specific physical condition was analyzed, regarding convection and conduction at the lateral edges. The results show that the temperature profile of the hollow biconcave disc pellet is lower, about 70 deg C below, when compared to the temperature profile of the annular pellet, considering the same simulation parameters for both pellets. (author)

  20. Thermal desorption spectroscopy for investigating hydrogen isotope behavior in materials

    International Nuclear Information System (INIS)

    Xia Tirui; Yang Hongguang; Zhan Qin; Han Zhibo; He Changshui

    2012-01-01

    The behavior of hydrogen isotope generated in fusion reactor materials is the key issue for safety and economic operation of fusion reactors and becomes an interesting field. In order to investigate the mechanism of hydrogen isotope such as diffusion, release and retention, a high-sensitivity thermal desorption spectroscopy (TDS) in combination with a quadruple mass spectrometer (QMS) was developed. A major technical breakthrough in ultrahigh vacuum (UHV), low hydrogen background, linear heating and sensitivity calibration of TDS system was made. UHV of l × 10 -7 Pa and low hydrogen background of l × 10 -9 Pa were obtained by combining turbo molecule pump and sputter ion pump. Specimens can be linearly heated up to 1173 K at the rate of 1 to 50 K/min under the MCGS PID software. Sensitivity calibration of the TDS system was accomplished using a special deuterium leak in the detector mode of QMS second electron multiplier. The desorption sensitivity coefficient and the minimum detection limit of deuterium desorption rate are 6.22 × l0 24 s -l · and l.24 × l0 -10 s -1 , respectively. The measurement was also routinely conducted on a specimen of standard, deuterium-containing Zr-4 alloy maintained in the laboratory, so as to validate the TDS method. (authors)

  1. Synthesis, microstructure and thermal expansion studies

    Indian Academy of Sciences (India)

    Abstract. We report on the synthesis, microstructure and thermal expansion studies on Ca0.5+/2Sr0.5+/2Zr4P6−2Si2O24 ( = 0.00 to 1.00) system which belongs to NZP family of low thermal expansion ceramics. The ceramics synthesized by co-precipitation method at lower calcination and the sintering temperatures ...

  2. Evaluation of Thermal and Thermo-mechanical Behavior of Full-scale Energy Foundations

    Science.gov (United States)

    Murphy, Kyle D.

    This study focuses on the thermo-mechanical and thermal behavior of full-scale energy foundations installed as part of two buildings recently constructed in Colorado. The soil stratigraphy at each of the sites differed, but both foundations were expected to function as primarily end-bearing elements with a tip socketed into rock. The heat exchanger configurations were also different amongst the foundations at both sites, permitting evaluation of the role of heat exchange. A common thread for both energy foundation case histories was the monitoring of the temperature and axial strain within the foundations during heat exchange operations. The first case study involves an evaluation of the long-term thermo-mechanical response of two full-scale energy foundations installed at the new Denver Housing Authority (DHA) Senior Living Facility at 1099 Osage St. in Denver, Colorado. Due to the construction schedule for this project, the thermal properties of the foundations and surrounding subsurface could not be assessed using thermal response tests. However, instrumentation was incorporated into the foundations to assess their long-term heat exchange response as well as the thermo-mechanical strains, stresses, and displacements that occurred during construction and operation of the ground-source heat pump system. The temperature changes within the foundations during heating and cooling operations over a period of approximately 600 days ranged from 9 to 32 °C, respectively. The thermal axial stresses in the foundations were calculated from the measured strains, and ranged from 3.1 MPa during heating to --1.0 MPa during cooling. These values are within reasonable limits for reinforced concrete structures. The maximum thermal axial stress was observed near the toe of both foundations, which is consistent with trends expected for end-bearing toe boundary conditions. The greatest thermal axial strains were observed near the top of the foundations (upward expansion during

  3. Scaling behavior of the thermal conductivity of width-modulated nanowires and nanofilms for heat transfer control at the nanoscale.

    Science.gov (United States)

    Zianni, Xanthippi; Jean, Valentin; Termentzidis, Konstantinos; Lacroix, David

    2014-11-21

    We report on scaling behavior of the thermal conductivity of width-modulated nanowires and nanofilms that have been studied with the phonon Monte Carlo technique. It has been found that the reduction of the thermal conductivity scales with the nanostructure transmissivity, a property entirely determined by the modulation geometry, irrespectively of the material choice. Tuning of the thermal conductivity is possible by the nanostructure width-modulation without strict limitations for the modulation profile. In addition, a very significant constriction thermal resistance due to width-discontinuity has been identified, in analogy to the contact thermal resistance between two dissimilar materials. The constriction thermal resistance also scales with the modulated nanostructure transmissivity. Our conclusions are generic indicating that a wide range of materials can be used for the modulated nanostructures. Direct heat flow control can be provided by designing the nanostructure width-modulation.

  4. CFD analysis of thermal-hydraulic behavior in SCWR typical flow channels

    International Nuclear Information System (INIS)

    Gu, H.Y.; Cheng, X.; Yang, Y.H.

    2008-01-01

    Investigations on thermal-hydraulic behavior in SCWR fuel assembly have obtained a significant attention in the international SCWR community. However, there is still a lack of understanding and ability to predict the heat transfer behavior of supercritical water. In this paper, CFD analysis is carried out to study the flow and heat transfer behavior of supercritical water in sub-channels of both square and triangular rod bundles. Effect of various parameters, e.g. thermal boundary conditions and pitch-to-diameter ratio on the thermal-hydraulic behavior is investigated. Two boundary conditions, i.e., constant heat flux at the outer surface of cladding and constant heat density in the fuel pin are applied. The results show that the structure of the secondary flow mainly depends on the rod bundle configuration as well as the pitch-to-diameter ratio, whereas, the amplitude of the secondary flow is affected by the thermal boundary conditions, as well. The secondary flow is much stronger in a square lattice than that in a triangular lattice. The turbulence behavior is similar in both square and triangular lattices. The dependence of the amplitude of the turbulent velocity fluctuation across the gap on Reynolds number becomes prominent in both lattices as the pitch-to-diameter ratio increases. The effect of thermal boundary conditions on turbulent velocity fluctuation is negligibly small. For both lattices with small pitch-to-diameter ratios (P/D < 1.3), the mixing coefficient is about 0.022. Both secondary flow and turbulent mixing show unusual behavior in the vicinity of the pseudo-critical point. Further investigation is needed. A strong circumferential non-uniformity of wall temperature and heat transfer is observed in tight lattices at constant heat flux boundary conditions, especially in square lattices. In the case with constant heat density of fuel pin, the circumferential conductive heat transfer significantly reduces the non-uniformity of circumferential

  5. From kinetic to collective behavior in thermal transport on semiconductors and semiconductor nanostructures

    International Nuclear Information System (INIS)

    Tomas, C. de; Lopeandia, A. F.; Alvarez, F. X.; Cantarero, A.

    2014-01-01

    We present a model which deepens into the role that normal scattering has on the thermal conductivity in semiconductor bulk, micro, and nanoscale samples. Thermal conductivity as a function of the temperature undergoes a smooth transition from a kinetic to a collective regime that depends on the importance of normal scattering events. We demonstrate that in this transition, the key point to fit experimental data is changing the way to perform the average on the scattering rates. We apply the model to bulk Si with different isotopic compositions obtaining an accurate fit. Then we calculate the thermal conductivity of Si thin films and nanowires by only introducing the effective size as additional parameter. The model provides a better prediction of the thermal conductivity behavior valid for all temperatures and sizes above 30 nm with a single expression. Avoiding the introduction of confinement or quantum effects, the model permits to establish the limit of classical theories in the study of the thermal conductivity in nanoscopic systems

  6. From kinetic to collective behavior in thermal transport on semiconductors and semiconductor nanostructures

    Energy Technology Data Exchange (ETDEWEB)

    Tomas, C. de; Lopeandia, A. F.; Alvarez, F. X., E-mail: xavier.alvarez@uab.cat [Department of Physics, Universitat Autònoma de Barcelona, 08193 Bellaterra, Catalonia (Spain); Cantarero, A. [Materials Science Institute, University of Valencia, P. O. Box 22085, 46071 Valencia (Spain)

    2014-04-28

    We present a model which deepens into the role that normal scattering has on the thermal conductivity in semiconductor bulk, micro, and nanoscale samples. Thermal conductivity as a function of the temperature undergoes a smooth transition from a kinetic to a collective regime that depends on the importance of normal scattering events. We demonstrate that in this transition, the key point to fit experimental data is changing the way to perform the average on the scattering rates. We apply the model to bulk Si with different isotopic compositions obtaining an accurate fit. Then we calculate the thermal conductivity of Si thin films and nanowires by only introducing the effective size as additional parameter. The model provides a better prediction of the thermal conductivity behavior valid for all temperatures and sizes above 30 nm with a single expression. Avoiding the introduction of confinement or quantum effects, the model permits to establish the limit of classical theories in the study of the thermal conductivity in nanoscopic systems.

  7. From kinetic to collective behavior in thermal transport on semiconductors and semiconductor nanostructures

    Science.gov (United States)

    de Tomas, C.; Cantarero, A.; Lopeandia, A. F.; Alvarez, F. X.

    2014-04-01

    We present a model which deepens into the role that normal scattering has on the thermal conductivity in semiconductor bulk, micro, and nanoscale samples. Thermal conductivity as a function of the temperature undergoes a smooth transition from a kinetic to a collective regime that depends on the importance of normal scattering events. We demonstrate that in this transition, the key point to fit experimental data is changing the way to perform the average on the scattering rates. We apply the model to bulk Si with different isotopic compositions obtaining an accurate fit. Then we calculate the thermal conductivity of Si thin films and nanowires by only introducing the effective size as additional parameter. The model provides a better prediction of the thermal conductivity behavior valid for all temperatures and sizes above 30 nm with a single expression. Avoiding the introduction of confinement or quantum effects, the model permits to establish the limit of classical theories in the study of the thermal conductivity in nanoscopic systems.

  8. Study on thermal wave based on the thermal mass theory

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    The conservation equations for heat conduction are established based on the concept of thermal mass.We obtain a general heat conduction law which takes into account the spatial and temporal inertia of thermal mass.The general law introduces a damped thermal wave equation.It reduces to the well-known CV model when the spatial inertia of heat flux and temperature and the temporal inertia of temperature are neglected,which indicates that the CV model only considers the temporal inertia of heat flux.Numerical simulations on the propagation and superposition of thermal waves show that for small thermal perturbation the CV model agrees with the thermal wave equation based on the thermal mass theory.For larger thermal perturbation,however,the physically impossible phenomenon pre-dicted by CV model,i.e.the negative temperature induced by the thermal wave superposition,is eliminated by the general heat conduction law,which demonstrates that the present heat conduction law based on the thermal mass theory is more reasonable.

  9. Study on thermal wave based on the thermal mass theory

    Institute of Scientific and Technical Information of China (English)

    HU RuiFeng; CAO BingYang

    2009-01-01

    The conservation equations for heat conduction are established based on the concept of thermal mass. We obtain a general heat conduction law which takes into account the spatial and temporal inertia of thermal mass. The general law introduces a damped thermal wave equation. It reduces to the well-known CV model when the spatial inertia of heat flux and temperature and the temporal inertia of temperature are neglected, which indicates that the CV model only considers the temporal inertia of heat flux. Numerical simulations on the propagation and superposition of thermal waves show that for small thermal perturbation the CV model agrees with the thermal wave equation based on the thermal mass theory. For larger thermal perturbation, however, the physically impossible phenomenon pre-dicted by CV model, i.e. the negative temperature induced by the thermal wave superposition, is eliminated by the general heat conduction law, which demonstrates that the present heat conduction law based on the thermal mass theory is more reasonable.

  10. Particulate behavior in a controlled-profile pulverized coal-fired reactor: A study of coupled turbulent particle dispersion and thermal radiation transport. Final technical progress report

    Energy Technology Data Exchange (ETDEWEB)

    Queiroz, M.; Webb, B.W.

    1996-06-01

    To aid in the evaluation and development of advanced coal-combustion models, comprehensive experimental data sets are needed containing information on both the condensed and gas phases. To address this need a series of test were initiated on a 300 kW laboratory-scale, coal-fired reactor at a single test condition using several types of instrumentation. Data collected on the reactor during the course of the test includes: gas, particle, and wall temperature profiles; radiant, total, and convective heat fluxes to the walls; particle size and velocity profiles; transmission measurements; and gas species concentrations. Solid sampling was also performed to determine carbon and total burnout. Along with the extensive experimental measurements, the particle dispersion and radiation submodels in the ACERC comprehensive 2D code were studied in detail and compared to past experimental measurements taken in the CPR. In addition to the presentation and discussion of the experimental data set, a detailed description of the measurement techniques used in collecting the data, including a discussion of the error associated with each type of measurement, is given.

  11. Thermal behavior and compatibility analysis of the new chemical entity LPSF/FZ4

    International Nuclear Information System (INIS)

    Costa, Salvana Priscylla Manso; Ramos da Silva, Keyla Emanuelle; Rocha de Medeiros, Giovanna Christinne; Rolim, Larissa Araujo; Ferreira de Oliveira, Jamerson; Carmo Alves de Lima, Maria do; Galdino, Suely Lins; Pitta, Ivan da Rocha; Neto, Pedro Jose Rolim

    2013-01-01

    Highlights: • We determined the thermal behavior of isolated LPSF/FZ4. • We used the isothermal and non-isothermal methods. • We reported the time of the stability of LPSF/FZ4 was measured in 4 months. • We also performed a compatibility study associated with excipients. • We reported the possible interactions of the prototype with lactose. - Abstract: In this study, differential scanning calorimetry and thermogravimetry were employed to determine the thermal behavior of LPSF/FZ4 isolated and associated with excipients (amide, β-cyclodextrin, cellulose, lactose, stearate of magnesium, aerosil, sodium lauryl sulfate, polysorbate and polyvinylpyrrolidone). Thus, the purity of the prototype calculated was 98%. Isothermal and non-isothermal methods were used to determine the kinetic parameters of decomposition, finding a first-reaction order and activation energy (A e ) of 98.22 kJ mol −1 . Also, the time of the stability of LPSF/FZ4 was measured in 4 months. The compatibility study showed possible interactions of the prototype with lactose due to a change in its heat of fusion, a reduction of more than 40 °C in its stability and a reduction of approximately 30% in A e of its decomposition reaction. The study demonstrated the importance of using thermal analytical methods to characterize new drugs to enable the development and quality control of pharmaceutical products

  12. Thermal behavior and compatibility analysis of the new chemical entity LPSF/FZ4

    Energy Technology Data Exchange (ETDEWEB)

    Costa, Salvana Priscylla Manso [Departamento de Ciências Farmacêuticas, Universidade Federal de Pernambuco (Brazil); Ramos da Silva, Keyla Emanuelle, E-mail: ramos.keyla@gmail.com [Departamento de Ciências Farmacêuticas, Universidade Federal de Pernambuco (Brazil); Instituto de Ciências Exatas e Tecnologia, Universidade Federal do Amazonas (Brazil); Rocha de Medeiros, Giovanna Christinne; Rolim, Larissa Araujo; Ferreira de Oliveira, Jamerson [Departamento de Ciências Farmacêuticas, Universidade Federal de Pernambuco (Brazil); Carmo Alves de Lima, Maria do; Galdino, Suely Lins; Pitta, Ivan da Rocha [Departamento de Antibióticos, Universidade Federal de Pernambuco (Brazil); Neto, Pedro Jose Rolim [Departamento de Ciências Farmacêuticas, Universidade Federal de Pernambuco (Brazil)

    2013-06-20

    Highlights: • We determined the thermal behavior of isolated LPSF/FZ4. • We used the isothermal and non-isothermal methods. • We reported the time of the stability of LPSF/FZ4 was measured in 4 months. • We also performed a compatibility study associated with excipients. • We reported the possible interactions of the prototype with lactose. - Abstract: In this study, differential scanning calorimetry and thermogravimetry were employed to determine the thermal behavior of LPSF/FZ4 isolated and associated with excipients (amide, β-cyclodextrin, cellulose, lactose, stearate of magnesium, aerosil, sodium lauryl sulfate, polysorbate and polyvinylpyrrolidone). Thus, the purity of the prototype calculated was 98%. Isothermal and non-isothermal methods were used to determine the kinetic parameters of decomposition, finding a first-reaction order and activation energy (A{sub e}) of 98.22 kJ mol{sup −1}. Also, the time of the stability of LPSF/FZ4 was measured in 4 months. The compatibility study showed possible interactions of the prototype with lactose due to a change in its heat of fusion, a reduction of more than 40 °C in its stability and a reduction of approximately 30% in A{sub e} of its decomposition reaction. The study demonstrated the importance of using thermal analytical methods to characterize new drugs to enable the development and quality control of pharmaceutical products.

  13. Thermal behaviors of mechanically activated pyrites by thermogravimetry (TG)

    International Nuclear Information System (INIS)

    Hu Huiping; Chen Qiyuan; Yin Zhoulan; Zhang Pingmin

    2003-01-01

    The thermal decompositions of mechanically activated and non-activated pyrites were studied by thermogravimetry (TG) at the heating rate of 10 K min -1 in argon. Results indicate that the initial temperature of thermal decomposition (T di ) in TG curves for mechanically activated pyrites decreases gradually with increasing the grinding time. The specific granulometric surface area (S G ), the structural disorder of mechanically activated pyrites were analyzed by X-ray diffraction laser particle size analyzer, and X-ray powder diffraction analysis (XRD), respectively. The results show that the S G of mechanically activated pyrites remains almost constant after a certain grinding time, and lattice distortions (ε) rise but the crystallite sizes (D) decrease with increasing the grinding time. All these results imply that the decrease of T di in TG curves of mechanically activated pyrites is mainly caused by the increase of lattice distortions ε and the decrease of the crystallite sizes D of mechanically activated pyrite with increasing the grinding time. The differences in the reactivity between non-activated and mechanically activated pyrites were observed using characterization of the products obtained from 1 h treatment of non-activated and mechanically activated pyrites at 713 K under inert atmosphere and characterization of non-activated and mechanically activated pyrites exposed to ambient air for a certain period

  14. Numerical model for the thermal behavior of thermocline storage tanks

    Science.gov (United States)

    Ehtiwesh, Ismael A. S.; Sousa, Antonio C. M.

    2018-03-01

    Energy storage is a critical factor in the advancement of solar thermal power systems for the sustained delivery of electricity. In addition, the incorporation of thermal energy storage into the operation of concentrated solar power systems (CSPs) offers the potential of delivering electricity without fossil-fuel backup even during peak demand, independent of weather conditions and daylight. Despite this potential, some areas of the design and performance of thermocline systems still require further attention for future incorporation in commercial CSPs, particularly, their operation and control. Therefore, the present study aims to develop a simple but efficient numerical model to allow the comprehensive analysis of thermocline storage systems aiming better understanding of their dynamic temperature response. The validation results, despite the simplifying assumptions of the numerical model, agree well with the experiments for the time evolution of the thermocline region. Three different cases are considered to test the versatility of the numerical model; for the particular type of a storage tank with top round impingement inlet, a simple analytical model was developed to take into consideration the increased turbulence level in the mixing region. The numerical predictions for the three cases are in general good agreement against the experimental results.

  15. Thermal Conductivity and Thermal Gradient Cyclic Behavior of Refractory Silicate Coatings on SiC/SiC Ceramic Matrix Composites

    Science.gov (United States)

    Zhu, Dongming; Lee, Kang N.; Miller, Robert A.

    2001-01-01

    Plasma-sprayed mullite and BSAS coatings have been developed to protect SiC/SiC ceramic matrix composites from high temperature environmental attack. In this study, thermal conductivity and thermal barrier functions of these coating systems are evaluated using a laser high-heat-flux test rig. The effects of water vapor on coating thermal conductivity and durability are studied by using alternating furnace and laser thermal gradient cyclic tests. The influence of laser high thermal-gradient cycling on coating failure modes is also investigated.

  16. Crystal structure and thermal behavior of KB3O6

    International Nuclear Information System (INIS)

    Bubnova, R.S.; Fundamenskij, V.S.; Filatov, S.K.; Polyakova, I.G.

    2004-01-01

    The structure of potassium triborate prepared in metastable state by crystallization from melt at ∼ 800 deg C was studied by the method of X-ray diffraction analysis. It was ascertained that KB 3 O 6 belongs to monoclinic crystal system, space group P2 1 /c, a = 9.319(1), b = 6.648(1), c = 21.094(2) A, β = 94.38(1) deg, Z = 12. The compound is referred to a new structural type. Anion of the structure is a single boron-oxygen frame formed by three independent rigid triborate rings of [B 3 O 5 ] - , each of them consisting of two BO 3 triangles and BO 4 tetrahedron. Phase transformations during KB 3 O 6 heating up to 800 deg C, as well as thermal expansion in the range of 20-650 deg C, were studied [ru

  17. Thermodynamic model of a thermal storage air conditioning system with dynamic behavior

    Energy Technology Data Exchange (ETDEWEB)

    Fleming, E; Wen, SY; Shi, L; da Silva, AK

    2013-12-01

    A thermodynamic model was developed to predict transient behavior of a thermal storage system, using phase change materials (PCMs), for a novel electric vehicle climate conditioning application. The main objectives of the paper are to consider the system's dynamic behavior, such as a dynamic air flow rate into the vehicle's cabin, and to characterize the transient heat transfer process between the thermal storage unit and the vehicle's cabin, while still maintaining accurate solution to the complex phase change heat transfer. The system studied consists of a heat transfer fluid circulating between either of the on-board hot and cold thermal storage units, which we refer to as thermal batteries, and a liquid-air heat exchanger that provides heat exchange with the incoming air to the vehicle cabin. Each thermal battery is a shell-and-tube configuration where a heat transfer fluid flows through parallel tubes, which are surrounded by PCM within a larger shell. The system model incorporates computationally inexpensive semianalytic solution to the conjugated laminar forced convection and phase change problem within the battery and accounts for airside heat exchange using the Number of Transfer Units (NTUs) method for the liquid-air heat exchanger. Using this approach, we are able to obtain an accurate solution to the complex heat transfer problem within the battery while also incorporating the impact of the airside heat transfer on the overall system performance. The implemented model was benchmarked against a numerical study for a melting process and against full system experimental data for solidification using paraffin wax as the PCM. Through modeling, we demonstrate the importance of capturing the airside heat exchange impact on system performance, and we investigate system response to dynamic operating conditions, e.g., air recirculation. (C) 2013 Elsevier Ltd. All rights reserved.

  18. An assessment of thermal behavior of the DUPIC fuel bundle by subchannel analysis

    International Nuclear Information System (INIS)

    Park, Jee Won.

    1997-12-01

    Thermal behavior of the standard DUPIC fuel has been assessed. The DUPIC fuel bundle has been modeled for a subchannel analysis using the ASSERT-IV code which was developed by AECL. From the calculated mixture enthalpy, equilibrium quality and void fraction distributions of the DUPIC fuel bundle, it is found that net buoyancy effect is pronounced in the central region of the DUPIC fuel bundle when compared with the standard CANDU fuel bundle. It is also found that the central region of the DUPIC fuel bundle can be cooled more efficiently than that of the standard fuel bundle. Based upon the subchannel modeling used in this study, the location of minimum CHFR in the DUPIC fuel bundle has been found to be very similar to that of the standard fuel. From the calculated mixture enthalpy distribution at the exit of the fuel channel, it is found that the mixture enthalpy and void fraction can be highest in the peripheral region of the DUPIC fuel bundle. On the other hand, the enthalpy and the void fraction was found to be highest in the central region of the standard CANDU fuel bundle at the exit of the fuel channel. Since the transverse interchange model between subchannels is important for the behavior of these variables, it is needed to put more effort in validating the transverse interchange model. For the purpose of investigating influence of thermal-hydraulic parameter variations of the DUPIC fuel bundle, four different values of the channel flow rates were used in the subchannel analysis. The effect of the channel flow reduction on thermal-hydraulic parameters have been presented. This study shows that the subchannel analysis is very useful in assessing thermal behavior of the fuel bundles in CANDU reactors. (author). 12 refs., 3 tabs., 17 figs

  19. Thermal Behavior and Free-Radical-Scavenging Activity of Phytic Acid Alone and Incorporated in Cosmetic Emulsions

    Directory of Open Access Journals (Sweden)

    André Luis Máximo Daneluti

    2015-07-01

    Full Text Available Phytic acid is a natural compound widely used as depigmenting agent in cosmetic emulsions. Few studies are available in the literature covering the stability and the antioxidating property of this substance, used alone or into emulsions. Therefore, the purpose of this work was to investigate the thermal behavior and antioxidant properties of phytic acid alone and into cosmetic emulsions. The thermal behavior of this substance was evaluated by thermogravimetry (TG/derivative thermogravimetry (DTG and differential scanning calorimetry (DSC and the free-radical-scavenging activity by 1,1-diphenyl-2-picrylhydrazyl (DPPH. TG/DTG and DSC curves allowed evaluation of the thermal behavior of phytic acid. These results showed that the substance presented four stages of mass loss. Thermal decomposition of the material initiated at 150 °C. Thermal behavior of the cosmetic emulsions detected that the addition of phytic acid decreased the thermal stability of the system. DPPH free-radical-scavenging activity showed that phytic acid incorporated into emulsion had no antioxidant capacity compared to BHT. In summary, we concluded that the thermoanalytical techniques (TG and DSC were efficient and reliable in the characterization of phytic acid alone and incorporated into cosmetic emulsions.

  20. Cold-season solar input and ambivalent thermal behavior brought by climber greenwalls

    International Nuclear Information System (INIS)

    Jim, C.Y.

    2015-01-01

    Most greenwall studies focus on cooling and energy conservation in the warm season, and tropical cold-season has received little attention. This field-experimental study in humid-subtropical Hong Kong evaluated winter thermal behavior of climber greenwalls. Orientation and weather factors regulated solar-irradiation regimes with critical impact on vegetation thermal responses. Temperature differentiation occurred mainly on sunny day, with subdued variations on cloudy and rainy days. The south greenwall on sunny day received the highest solar-energy input, bringing divergent surface temperature in three climber species. The daytime descending cooling sequence was: Control-air > Pyrostegia venusta > Bauhinia corymbosa > Ficus pumila > Control-surface. Heat-sink effect related to foliage-thickness and moisture-content influenced climber thermal responses. Exceeding a solar-irradiance threshold of 500 Wm"−"2 was a prerequisite for notable solar-warming and transpiration-cooling, bringing well-differentiated climber-surface temperature. Cooling of vegetation-surface and Anterior-ambient-air was contrasted by warming behind the greenwall. Posterior-airgap with trapped stagnant air and Posterior-concrete-surface were warmed consistently above control concrete-surface on sunny and cloudy days. This winter passive warming mechanism denotes a new dimension in thermal benefits operating behind the greenwall. The thermal-gradient can transmit heat into indoor space, with benefits on human comfort, health and energy conservation. - Highlights: • Cold-season thermal regimes and benefits of climber greenwalls in tropics was studied. • Greenwall plots were installed as a field-experiment to evaluated six related factors. • Descending cooling sequence: Pyrostegia venusta > Bauhinia corymbosa > Ficus pumila. • Solar radiation intensity and foliage heat-sink effect determined climber cooling. • Posterior airgap and Posterior concrete-surface were warmed to provide indoor

  1. Thermal behavior of latent thermal energy storage unit using two phase change materials: Effects of HTF inlet temperature

    Directory of Open Access Journals (Sweden)

    Fouzi Benmoussa

    2017-09-01

    Full Text Available This work presents a numerical study of the thermal behavior of shell-and-tube latent thermal energy storage (LTES unit using two phase change materials (PCMs. The heat transfer fluid (HTF flow through the inner tube and transfer the heat to PCMs. First, a mathematical model is developed based on the enthalpy formulation and solved through the governing equations. Second, the effects of HTF inlet temperature on the unsteady temperature evolution of PCMs, the total energy stored evolution as well as the total melting time is studied. Numerical results show that for all HTF inlet temperature, melting rate of PCM1 is the fastest and that of PCM2 is the slowest; increasing the HTF inlet temperature considerably increases the temperature evolution of PCMs. The maximum energy stored is observed in PCM2 with high melting temperature and high specific heat; heat storage capacity is large for high HTF inlet temperature. When the HTF inlet temperature increases from 338 K to 353 K, decreasing degree of melting time of PCM2 is the biggest from 1870 s to 490 s, which reduces about 73.8%; decreasing degree of melting time of PCM1 is the smallest from 530 s to 270 s, which reduces about 49.1%.

  2. Thermal behavior and mechanical properties of physically crosslinked PVA/Gelatin hydrogels.

    Science.gov (United States)

    Liu, Yurong; Geever, Luke M; Kennedy, James E; Higginbotham, Clement L; Cahill, Paul A; McGuinness, Garrett B

    2010-02-01

    Poly (vinyl alcohol)/Gelatin hydrogels are under active investigation as potential vascular cell culture biomaterials, tissue models and vascular implants. The PVA/Gelatin hydrogels are physically crosslinked by the freeze-thaw technique, which is followed by a coagulation bath treatment. In this study, the thermal behavior of the gels was examined by differential scanning calorimetry (DSC) and dynamic mechanical thermal analysis (DMTA). Rheological measurement and uniaxial tensile tests revealed key mechanical properties. The role of polymer fraction in relation to these mechanical properties is explored. Gelatin has no significant effect on the thermal behavior of PVA, which indicates that no substantial change occurs in the PVA crystallite due to the presence of gelatin. The glass transition temperature, melting temperature, degree of crystallinity, polymer fraction, storage modulus (G') and ultimate strength of one freeze-thaw cycle (1FT) hydrogels are inferior to those of 3FT hydrogels. With coagulation, both 1FT and 3FT hydrogels shifted to a lower value of T(g), melting temperature and polymer fraction are further increased and the degree of crystallinity is depressed. The mechanical properties of 1FT, but not 3FT, were strengthened with coagulation treatment. This study gives a detailed investigation of the microstructure formation of PVA/Gelatin hydrogel in each stage of physical treatments which helps us to explain the role of physical treatments in tuning their physical properties for biomechanical applications. Copyright 2009 Elsevier Ltd. All rights reserved.

  3. Thermodynamic nonequilibrium phase change behavior and thermal properties of biological solutions for cryobiology applications.

    Science.gov (United States)

    Han, Bumsoo; Bischof, John C

    2004-04-01

    Understanding the phase change behavior of biomaterials during freezing/thawing including their thermal properties at low temperatures is essential to design and improve cryobiology applications such as cryopreservation and cryosurgery. However, knowledge of phase change behavior and thermal properties of various biomaterials is still incomplete, especially at cryogenic temperatures (solutions--either water-NaCl or phosphate buffered saline (PBS)--with various chemical additives were investigated. The chemical additives studied are glycerol and raffinose as CPAs, an AFP (Type III, molecular weight = 6500), and NaCl as a cryosurgical adjuvant. The phase change behavior was investigated using a differential scanning calorimeter (DSC) and a cryomicroscope. The specific and latent heat of these solutions were also measured with the DSC. The saline solutions have two distinct phase changes--water/ice and eutectic phase changes. During freezing, eutectic solidification of both water-NaCl and PBS are significantly supercooled below their thermodynamic equilibrium eutectic temperatures. However, their melting temperatures are close to thermodynamic equilibrium during thawing. These eutectic phase changes disappear when even a small amount (0.1 M glycerol) of CPA was added, but they are still observed after the addition of an AFP. The specific heats of these solutions are close to that of ice at very low temperatures (< or = -100 degrees C) regardless of the additives, but they increase between -100 degrees C and -30 degrees C with the addition of CPAs. The amount of latent heat, which is evaluated with sample weight, generally decreases with the addition of the additives, but can be normalized to approximately 300 J/g based on the weight of water which participates in the phase change. This illustrates that thermal properties, especially latent heat, of a biomaterial should be evaluated based on the understanding of its phase change behavior. The results of the present

  4. 3-D CFD modeling and experimental testing of thermal behavior of a Li-Ion battery

    International Nuclear Information System (INIS)

    Gümüşsu, Emre; Ekici, Özgür; Köksal, Murat

    2017-01-01

    Highlights: • A thermally fully predictive 3-D CFD model is developed for Li-Ion batteries. • Complete flow field around the battery and conduction inside the battery are solved. • Macro-scale thermophysical properties and the entropic term are investigated. • Discharge rate and usage history of the battery are systematically investigated. • Reliability of the model was tested through experimental measurements. - Abstract: In this study, a 3-D computational fluid dynamics model was developed for investigating the thermal behavior of lithium ion batteries under natural convection. The model solves the complete flow field around the battery as well as conduction inside the battery using the well-known heat generation model of Bernardi et al. (1985). The model is thermally fully predictive so it requires only electrical performance parameters of the battery to calculate its temperature during discharging. Using the model, detailed investigation of the effects of the variation of the macro-scale thermophysical properties and the entropic term of the heat generation model was carried out. Results show that specific heat is a critical property that has a significant impact on the simulation results whereas thermal conductivity has relatively minor importance. Moreover, the experimental data can be successfully predicted without taking the entropic term into account in the calculation of the heat generation. The difference between the experimental and predicted battery surface temperature was less than 3 °C for all discharge rates and regardless of the usage history of the battery. The developed model has the potential to be used for the investigation of the thermal behavior of Li-Ion batteries in different packaging configurations under natural and forced convection.

  5. Simplified methods to the complete thermal and mechanical behavior of a pressure vessel during a severe accident

    International Nuclear Information System (INIS)

    Dupas, P.; Schneiter, J.R.

    1996-01-01

    EDF has developed a software package of simplified methods (proprietary ones or from literature) in order to study the thermal and mechanical behavior of a PWR pressure vessel during a severe accident involving a corium localization in the vessel lower head. Using a part of this package, the authors can evaluate for instance successively: the heat flux at the inner surface of the vessel (conductive or convective pool of corium); the thermal exchange coefficient between the vessel and the outside (dry pit or flooded pit, watertight thermal insulation or not); the complete thermal evolution of the vessel (temperature profile, melting); the possible global plastic failure of the vessel; the creep behavior in the thickness of the vessel. These simplified methods are a cost effective alternative to finite element calculations which are yet used to validate the previous methods, waiting for experimental results to come

  6. Thermodynamic model of a thermal storage air conditioning system with dynamic behavior

    International Nuclear Information System (INIS)

    Fleming, Evan; Wen, Shaoyi; Shi, Li; Silva, Alexandre K. da

    2013-01-01

    Highlights: • We developed an automotive thermal storage air conditioning system model. • The thermal storage unit utilizes phase change materials. • We use semi-analytic solution to the coupled phase change and forced convection. • We model the airside heat exchange using the NTU method. • The system model can incorporate dynamic inputs, e.g. variable inlet airflow. - Abstract: A thermodynamic model was developed to predict transient behavior of a thermal storage system, using phase change materials (PCMs), for a novel electric vehicle climate conditioning application. The main objectives of the paper are to consider the system’s dynamic behavior, such as a dynamic air flow rate into the vehicle’s cabin, and to characterize the transient heat transfer process between the thermal storage unit and the vehicle’s cabin, while still maintaining accurate solution to the complex phase change heat transfer. The system studied consists of a heat transfer fluid circulating between either of the on-board hot and cold thermal storage units, which we refer to as thermal batteries, and a liquid–air heat exchanger that provides heat exchange with the incoming air to the vehicle cabin. Each thermal battery is a shell-and-tube configuration where a heat transfer fluid flows through parallel tubes, which are surrounded by PCM within a larger shell. The system model incorporates computationally inexpensive semi-analytic solution to the conjugated laminar forced convection and phase change problem within the battery and accounts for airside heat exchange using the Number of Transfer Units (NTUs) method for the liquid–air heat exchanger. Using this approach, we are able to obtain an accurate solution to the complex heat transfer problem within the battery while also incorporating the impact of the airside heat transfer on the overall system performance. The implemented model was benchmarked against a numerical study for a melting process and against full system

  7. Diurnal Thermal Behavior of Pavements, Vegetation, and Water Pond in a Hot-Humid City

    Directory of Open Access Journals (Sweden)

    Xiaoshan Yang

    2015-12-01

    Full Text Available This study investigated the diurnal thermal behavior of several urban surfaces and landscape components, including pavements, vegetation, and a water pond. The field experiment was conducted in a university campus of Guangzhou, South China, which is characterized by a hot and humid summer. The temperature of ground surface and grass leaves and the air temperature and humidity from 0.1 to 1.5 m heights were measured for a period of 24 h under hot summer conditions. The results showed that the concrete and granite slab pavements elevated the temperature of the air above them throughout the day. In contrast, the trees and the pond lowered the air temperature near ground during the daytime but produced a slight warming effect during the nighttime. The influence of vegetation on air temperature and humidity is affected by the configurations of greenery. Compared to the open lawn, the grass shaded by trees was more effective in cooling and the mixture of shrub and grass created a stronger cooling effect during the nighttime. The knowledge of thermal behavior of various urban surfaces and landscape components is an important tool for planners and designers. If utilized properly, it can lead to climatic rehabilitation in urban areas and an improvement of the outdoor thermal environment.

  8. Composition, phase behavior and thermal stability of natural edible fat from rambutan (Nephelium lappaceum L.) seed.

    Science.gov (United States)

    Solís-Fuentes, Julio A; Camey-Ortíz, Guadalupe; Hernández-Medel, María del Rosario; Pérez-Mendoza, Francisco; Durán-de-Bazúa, Carmen

    2010-01-01

    In this paper, the chemical composition, the main physicochemical properties, phase behavior and thermal stability of rambutan (Nephelium lappaceum L.) seed fat were studied. These results showed that the almond-like decorticated seed represents 6.1% of the wet weight fruit and is: 1.22% ash, 7.80% protein, 11.6% crude fiber, 46% carbohydrates, and 33.4% fat (d.b.). The main fatty acids in the drupe fat were 40.3% oleic, 34.5% arachidic, 6.1% palmitic, 7.1% stearic, 6.3% gondoic, and 2.9% behenic; the refraction, saponification and iodine values were 1.468, 186, and 47.0, respectively. The phase behavior analysis showed relatively simple crystallization and melting profiles: crystallization showed three well-differentiated groups of triglycerides around maximum peaks at +30.8, +15.6 and -18.1 degrees C; the fat-melting curve had a range between -14.5 and +51.8 degrees C with a fusion enthalpy of 124.3 J/g. The thermal stability analyzed in an inert atmosphere of N(2) and in a normal oxidizing atmosphere, showed that in the latter, fat decomposition begins at 237.3 degrees C and concludes at 529 degrees C, with three stages of decomposition. According to these results, rambutan seed fat has physicochemical and thermal characteristics that may become interesting for specific applications in several segments of the food industry.

  9. Xenon thermal behavior in sintered titanium nitride, foreseen inert matrix for GFR

    International Nuclear Information System (INIS)

    Bes, R.

    2010-11-01

    This work concerns the generation IV future nuclear reactors such as gas-cooled fast reactor (GFR) for which refractory materials as titanium nitride (TiN) are needed to surround fuel and act as a fission product diffusion barrier. This study is about Xe thermal behavior in sintered titanium nitride. Microstructure effects on Xe behavior have been studied. In this purpose, several syntheses have been performed using different sintering temperatures and initial powder compositions. Xenon species have been introduced into samples by ionic implantation. Then, samples were annealed in temperature range from 1300 C to 1600 C, these temperatures being the accidental awaited temperature. A transport of xenon towards sample surface has been observed. Transport rate seems to be slow down when increasing sintering temperature. The composition of initial powder and the crystallographic orientation of each considered grain also influence xenon thermal behavior. Xenon release has been correlated with material oxidation during annealing. Xenon bubbles were observed. Their size is proportional with xenon concentration and increases with annealing temperature. Several mechanisms which could explain Xe intragranular mobility in TiN are proposed. In addition with experiments, very low Xe solubility in TiN has been confirmed by ab initio calculations. So, bi-vacancies were found to be the most favoured Xe incorporation sites in this material. (author)

  10. Effects of pulse current stimulation on the thermal fatigue crack propagation behavior of CHWD steel

    International Nuclear Information System (INIS)

    Lin, H.Q.; Zhao, Y.G.; Gao, Z.M.; Han, L.G.

    2008-01-01

    The fatigue crack propagating behaviors of cast hot working die (CHWD) steel untreated and treated by an electric current in the intermediate stage of thermal fatigue were investigated in the present study. The circle/elliptical heating affected zone (HAZ) was formed ahead of the notch tip on the fatigued specimens after pulse electric current stimulation. Both SEM observation and X-ray diffraction analysis revealed that pulse electric current stimulation refined grains/subgrains in the HAZs. With the prolonging of discharging duration, the grains/subgrains decreased in size and the dislocation density and microhardness increased gradually. The grain refinement and dislocation density increase played an important role in the material strengthening, which inevitably enhanced the propagation resistance and delayed the propagation of thermal fatigue cracks. Therefore, the pulse electric current stimulation was an effective method to improve the service lifetime of die material

  11. Analysis of thermal-hydrologic-mechanical behavior near an emplacement drift at Yucca Mountain

    International Nuclear Information System (INIS)

    Rutqvist, Jonny; Tsang, Chin-Fu

    2002-01-01

    A coupled thermal, hydrologic and mechanical (THM) analysis is conducted to evaluate the impact of coupled THM processes on the performance of a potential nuclear waste repository at Yucca Mountain, Nevada. The analysis considers changes in rock mass porosity, permeability, and capillary pressure caused by rock deformations during drift excavation, as well as those caused by thermo-mechanically induced rock deformations after emplacement of the heat-generating waste. The analysis consists of a detailed calibration of coupled hydraulic-mechanical rock mass properties against field experiments, followed by a prediction of the coupled thermal, hydrologic, and mechanical behavior around a potential repository drift. For the particular problem studied and parameters used, the analysis indicates that the stress-induced permeability changes will be within one order of magnitude and that these permeability changes do not significantly impact the overall flow pattern around the repository drift

  12. Electrical and thermal behavior of unsaturated soils: experimental results

    Science.gov (United States)

    Nouveau, Marie; Grandjean, Gilles; Leroy, Philippe; Philippe, Mickael; Hedri, Estelle; Boukcim, Hassan

    2016-05-01

    When soil is affected by a heat source, some of its properties are modified, and in particular, the electrical resistivity due to changes in water content. As a result, these changes affect the thermal properties of soil, i.e., its thermal conductivity and diffusivity. We experimentally examine the changes in electrical resistivity and thermal conductivity for four soils with different grain size distributions and clay content over a wide range of temperatures, from 20 to 100 °C. This temperature range corresponds to the thermal conditions in the vicinity of a buried high voltage cable or a geothermal system. Experiments were conducted at the field scale, at a geothermal test facility, and in the laboratory using geophysical devices and probing systems. The results show that the electrical resistivity decreases and the thermal conductivity increases with temperature up to a critical temperature depending on soil types. At this critical temperature, the air volume in the pore space increases with temperature, and the resulting electrical resistivity also increases. For higher temperatures , the thermal conductivity increases sharply with temperature up to a second temperature limit. Beyond it, the thermal conductivity drops drastically. This limit corresponds to the temperature at which most of the water evaporates from the soil pore space. Once the evaporation is completed, the thermal conductivity stabilizes. To explain these experimental results, we modeled the electrical resistivity variations with temperature and water content in the temperature range 20 - 100°C, showing that two critical temperatures influence the main processes occurring during heating at temperatures below 100 °C.

  13. Cellulose nanowhiskers from coconut husk fibers: effect of preparation conditions on their thermal and morphological behavior

    Science.gov (United States)

    Cellulose nanowhiskers were prepared by sulfuric acid hydrolysis from coconut husk fibers which had previously been submitted to a delignification process. The effects of preparation conditions on the thermal and morphological behavior of the nanocrystals were investigated. Cellulose nanowhisker sus...

  14. Diurnal thermal behavior of selected urban objects using remote sensing measurements

    Energy Technology Data Exchange (ETDEWEB)

    Chudnovsky, A.; Ben-Dor, E. [The Remote Sensing and GIS Laboratory, Department of Geography and Human Environment, Tel-Aviv (Israel); Saaroni, H. [Unit for Applied Climatology and Environmental Aspects, Department of Geography and Human Environment, Tel-Aviv (Israel)

    2004-07-01

    This research analyzes and summarizes some thermal behavior of various urban surfaces in time and space using high-resolution video thermal radiometer situated at a height of 103 m, in the city of Tel-Aviv. The physical properties of the various urban elements, their color, the sky view factor, street geometry, traffic loads, and anthropogenic activity are important among the factors that determine the radiant surface temperature in the urban environment. During daytime, asphalt paved roads and rooftops were found to be the warmest urban elements in our study area. In contrast, exterior walls and trees hold the highest surface temperatures at night. Open spaced surfaces that are exposed to direct solar radiation during daytime and to heat loss at night were characterized by the highest diurnal temperature range. The radiometric stationary experiment revealed the temperature differences between diverse urban coverage to be at most 10 {sup o}C; such maximum temperature differences were measured in the early noon hours. The minimal temperatures were observed just before sunrise, when the temperature contrasts (4-5 {sup o}C) were smaller than in the early noon hours. The daytime hours between 9-10 a.m. and 5-8 p.m. turned out to be problematic for remote sensing of the urban environment, because the thermal differences between different objects were found to be insignificant. A remote survey aiming to study the urban environment should be conducted twice: in the early morning hours before sunrise (5 a.m.) and in the early noon hours (12-1 p.m.). The knowledge of thermal behavior of various urban components is an important tool for designers and decision-makers. If utilized properly, it can lead to climatic rehabilitation in urban areas and a reduction of the UHI. (author)

  15. Deuterium permeation behavior of HTUPS4 steel with thermal oxidation layer

    International Nuclear Information System (INIS)

    Xu, Yu-Ping; Liu, Feng; Zhao, Si-Xiang; Li, Xiao-Chun; Wang, Jing; An, Zhong-Qing; Lu, Tao; Liu, Hao-Dong; Ding, Fang; Zhou, Hai-Shan; Luo, Guang-Nan

    2016-01-01

    The permeation behavior of creep-resistant, Al 2 O 3 -forming HTUPS austenitic stainless steels was studied using a gas driven permeation (GDP) device. The steel samples were first thermal oxidized at air condition, followed by GDP experiments. The permeability and diffusion coefficients of oxidized samples and bare 316L steels were derived and compared. In order to characterize the oxide layer, X-ray photoelectron spectroscopy was performed. An oxide layer with a thickness of 200 nm which mainly consists of Al 2 O 3 was detected.

  16. Geographic divergence in upper thermal limits across insect life stages: does behavior matter?

    Science.gov (United States)

    MacLean, Heidi J; Higgins, Jessica K; Buckley, Lauren B; Kingsolver, Joel G

    2016-05-01

    Insects with complex life cycles vary in size, mobility, and thermal ecology across life stages. We examine how differences in the capacity for thermoregulatory behavior influence geographic differences in physiological heat tolerance among egg and adult Colias butterflies. Colias adults exhibit differences in morphology (wing melanin and thoracic setal length) along spatial gradients, whereas eggs are morphologically indistinguishable. Here we compare Colias eriphyle eggs and adults from two elevations and Colias meadii from a high elevation. Hatching success and egg development time of C. eriphyle eggs did not differ significantly with the elevation of origin. Egg survival declined in response to heat-shock temperatures above 38-40 °C and egg development time was shortest at intermediate heat-shock temperatures of 33-38 °C. Laboratory experiments with adults showed survival in response to heat shock was significantly greater for Colias from higher than from lower elevation sites. Common-garden experiments at the low-elevation field site showed that C. meadii adults initiated heat-avoidance and over-heating behaviors significantly earlier in the day than C. eriphyle. Our study demonstrates the importance of examining thermal tolerances across life stages. Our findings are inconsistent with the hypothesis that thermoregulatory behavior inhibits the geographic divergence of physiological traits in mobile stages, and suggest that sessile stages may evolve similar heat tolerances in different environments due to microclimatic variability or evolutionary constraints.

  17. Experimental thermal behavior of a power plant reheater

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez, M. Manuela Prieto; Garcia, F. Javier Fernandez; Ramon, Ines Suarez [Departamento de Energia, Universidad de Oviedo, Campus de Viesques, 33204 Gijon, Asturias (Spain); Roces, Hilario Sanchez [Central Termica de Soto de Ribera, Soto de Ribera, Asturias (Spain)

    2006-04-15

    The process conditions of power plant components subjected to high pressures and temperatures are essential to determine their remaining life, availability and efficiency. It is, therefore, expedient to pay special attention to critical components, such as superheater and reheater heat exchangers, headers, and main and reheated steam lines. In this paper, on-line and off-line variables of a power plant reheater that has presented problems of thickness losses and repetitive tube fissures are studied. The fissures are associated with the effect of a thermal-mechanical mechanism. Off-line measurements were taken of the following variables: pressure, temperature, velocity and composition of the gases. On-line instrumentation was completed by the installation of specific thermocouples to ascertain the temperatures in the tubes outlet. Various angles for the fuel inlet of the burners and variations in the number and location of the working burners were also assayed. As a consequence of this analysis, it can be deduced that there are important differences in the outlet temperature of the reheater tubes that decrease for lower powers. Finally, it is pointed that a non-uniform distribution of the steam flow in the reheater might be the cause of the problem. (author)

  18. Studies in soliton behavior

    International Nuclear Information System (INIS)

    Schuur, P.C.

    1985-01-01

    The author presents a rigorous demonstration of the emergence of solitons from the KdV initial value problem with arbitrary initial function. Studying multisoliton solutions of the KdV in the general case of a nonzero reflection coefficient, he derives a new phase shift formula. He derives an estimate which indicates how well a real potential in the Zakharov-Shabat system is approximated by its reflectionless part. Moreover, the associated inverse scattering formalism is simplified considerably. He presents an asymptotic analysis of the sine-Gordon equation on right half lines almost linearly moving leftward. (Auth.)

  19. Influence of nano-AlN particles on thermal conductivity, thermal stability and cure behavior of cycloaliphatic epoxy/trimethacrylate system

    Directory of Open Access Journals (Sweden)

    2011-02-01

    Full Text Available We have prepared a series of nano-sized aluminium nitride (nano-AlN/cycloaliphatic epoxy/trimethacrylate (TMPTMA systems and investigated their morphology, thermal conductivity, thermal stability and curing behavior. Experimental results show that the thermal conductivity of composites increases with the nano-AlN filler content, the maximum value is up to 0.47 W/(m.K. Incorporation of a small amount of the nano-AlN filler into the epoxy/TMPTMA system improves the thermal stability. For instance, the thermal degradation temperature at 5% weight loss of nano-AlN/epoxy/TMPTMA system with only 1 wt% nano-AlN was improved by ~8ºC over the neat epoxy/TMPTMA system. The effect of nano-AlN particles on the cure behavior of epoxy/TMPTMA systems was studied by dynamic differential scanning calorimetry. The results showed that the addition of silane treated nano-AlN particles does not change the curing reaction mechanism and silane treated nano-AlN particles could bring positive effect on the processing of composite since it needs shorter pre-cure time and lower pre-temperature, meanwhile the increase of glass transition temperature of the nanocomposite improves the heat resistance.

  20. Thermal shock resistance behavior of a functionally graded ceramic: Effects of finite cooling rate

    Directory of Open Access Journals (Sweden)

    Zhihe Jin

    2014-01-01

    Full Text Available This work presents a semi-analytical model to explore the effects of cooling rate on the thermal shock resistance behavior of a functionally graded ceramic (FGC plate with a periodic array of edge cracks. The FGC is assumed to be a thermally heterogeneous material with constant elastic modulus and Poisson's ratio. The cooling rate applied at the FGC surface is modeled using a linear ramp function. An integral equation method and a closed form asymptotic temperature solution are employed to compute the thermal stress intensity factor (TSIF. The thermal shock residual strength and critical thermal shock of the FGC plate are obtained using the SIF criterion. Thermal shock simulations for an Al2O3/Si3N4 FGC indicate that a finite cooling rate leads to a significantly higher critical thermal shock than that under the sudden cooling condition. The residual strength, however, is relatively insensitive to the cooling rate.

  1. Effect of human behavior on economizer efficacy and thermal comfort in southern California

    Science.gov (United States)

    Lanning, TIghe Glennon

    California has set a zero net-energy conservation goal for the residential sector that is to be achieved by 2020 (California Energy Commission 2011). To reduce energy consumption in the building sector, modern buildings should fundamentally incorporate sustainable performance standards, involving renewable systems, climate-specific strategies, and consideration of a variety of users. Building occupants must operate in concert with the buildings they inhabit in order to maximize the potential of the building, its systems, and their own comfort. In climates with significant diurnal temperature swings, environmental controls designed to capitalize on this should be considered to reduce cooling-related loads. One specific strategy is the air-side economizer, which uses daily outdoor temperature swings to reduce indoor temperature swings. Traditionally a similar effect could be achieved by using thermal mass to buffer indoor temperature swings through thermal lag. Economizers reduce the amount of thermal mass typically required by naturally ventilated buildings. Fans are used to force cool nighttime air deep into the building, allowing lower mass buildings to take advantage of nighttime cooling. Economizers connect to a thermostat, and when the outdoor temperature dips below a programmed set-point the economizer draws cool air from outside, flushing out the warmed interior air. This type of system can be simulated with reasonable accuracy by energy modeling programs; however, because the system is occupant-driven (as opposed to a truly passive mass-driven system) any unpredictable occupant behavior can reduce its effectiveness and create misleading simulation results. This unpredictably has helped prevent the spread of economizers in the residential market. This study investigated to what extent human behavior affected the performance of economizer-based HVAC systems, based on physical observations, environmental data collections, and energy simulations of a residential

  2. Thermal transpiration: A molecular dynamics study

    Energy Technology Data Exchange (ETDEWEB)

    T, Joe Francis [Computational Nanotechnology Laboratory, School of Nano Science and Technology, National Institute of Technology Calicut, Kozhikode (India); Sathian, Sarith P. [Department of Applied Mechanics, Indian Institute of Technology Madras, Chennai (India)

    2014-12-09

    Thermal transpiration is a phenomenon where fluid molecules move from the cold end towards the hot end of a channel under the influence of longitudinal temperature gradient alone. Although the phenomenon of thermal transpiration is observed at rarefied gas conditions in macro systems, the phenomenon can occur at atmospheric pressure if the characteristic dimensions of the channel is less than 100 nm. The flow through these nanosized channels is characterized by the free molecular flow regimes and continuum theory is inadequate to describe the flow. Thus a non-continuum method like molecular dynamics (MD) is necessary to study such phenomenon. In the present work, MD simulations were carried out to investigate the occurance of thermal transpiration in copper and platinum nanochannels at atmospheric pressure conditions. The mean pressure of argon gas confined inside the nano channels was maintained around 1 bar. The channel height is maintained at 2nm. The argon atoms interact with each other and with the wall atoms through the Lennard-Jones potential. The wall atoms are modelled using an EAM potential. Further, separate simulations were carried out where a Harmonic potential is used for the atom-atom interaction in the platinum channel. A thermally insulating wall was introduced between the low and high temperature regions and those wall atoms interact with fluid atoms through a repulsive potential. A reduced cut off radius were used to achieve this. Thermal creep is induced by applying a temperature gradient along the channel wall. It was found that flow developed in the direction of the increasing temperature gradient of the wall. An increase in the volumetric flux was observed as the length of the cold and the hot regions of the wall were increased. The effect of temperature gradient and the wall-fluid interaction strength on the flow parameters have been studied to understand the phenomenon better.

  3. Thermal expansion studies on zircaloy-2

    International Nuclear Information System (INIS)

    Sivabharathy, M.; Senthilkumar, A.; Palanichamy, P.; Ramachandran, K.

    2016-01-01

    Zircaloy-2 and Zr-2.5% Nb alloys are widely used in the pressurized heavy water reactors (PHWR) as the material for the pressure tubes. The pressure tube operates at 573 K, 11 MPa internal pressures and is subjected to neutron flux of the order of 1013 n/cm 2 /s. These conditions lead to degradations in the pressure tube with respect to dimensional changes, deterioration in mechanical properties due to irradiation embrittlement, thereby reducing its flaw tolerance, the growth of existing flaws, which were too small or 'insignificant' at the time of installation. Physical and chemical properties of materials are also very essential in nuclear industry and the relations among them is of interest in the selection of materials when they are used in the design and manufacturing of devices particularly for atomic reactors.Studies on the relations between mechanical and thermal properties are of interest to the steel and metal industries as these would give useful information on the relation between hardness and thermal diffusivity (α) of steel. Jayakumar et al have already carried out the ultrasonic and metallographic investigations to see that all the heat-treated specimens retained essentially the martensite structure. In this present work, thermal expansion measurements on useful reactor material, Zircaloy-2 with different sample. Given a β-quenching treatment by heating to 1223 K and holding for 2 h, followed by water quenching. These specimens were then thermally aged for 1 h in the temperature range 473 to 973 K and air-cooled. For all samples, the thermal expansion was carried out and the results are correlated with ultrasonic measurements, metallographic and photoacoustic studies. (author)

  4. Acoustic and Thermal Vibrational Behavior of Rare Earth Glasses

    International Nuclear Information System (INIS)

    Senin, H. B.; Kancono, W.; Sidek, H. A. A.

    2007-01-01

    The ultrasonic wave velocity and the thermal expansion of the rare earth glasses have been measured as functions of temperature and pressure to test predictions of the soft potential model for the acoustic and thermal properties. The longitudinal ultrasonic wave velocities increase under pressure. The hydrostatic pressure derivative of the bulk modulus is positive: these glasses show a normal elastic response as compressed. However, the pressure derivative of the shear modulus is negative and small, indicating weak softening of shear modes under pressure. The results found are used to determine the Gruneisen parameters. This is to obtain the acoustic mode contribution to thermal expansion. After subtraction of the relaxation and anharmonic contributions, the temperature dependence of the shear wave ultrasound velocity follows a linear law as predicted by the Soft Potential Model

  5. Studies of thermal stratification in water pool

    International Nuclear Information System (INIS)

    Verma, P.K.; Chandraker, D.K.; Nayak, A.K.; Vijayan, P.K.

    2015-01-01

    Large water pools are used as a heat sink for various cooling systems used in industry. In context of advance nuclear reactors like AHWR, it is used as ultimate heat sink for passive systems for decay heat removal and containment cooling. This system incorporates heat exchangers submerged in the large water pool. However, heat transfer by natural convection in pool poses a problem of thermal stratification. Due to thermal stratification hot layers of water accumulate over the relatively cold one. The heat transfer performance of heat exchanger gets deteriorated as a hot fluid envelops it. In the nuclear reactors, the walls of the pool are made of concrete and it may subject to high temperature due to thermal stratification which is not desirable. In this paper, a concept of employing shrouds around the heat source is studied. These shrouds provide a bulk flow in the water pool, thereby facilitating mixing of hot and cold fluid, which eliminate stratification. The concept has been applied to the a scaled model of Gravity Driven Water Pool (GDWP) of AHWR in which Isolation Condensers (IC) tubes are submerged for decay heat removal of AHWR using ICS and thermal stratification phenomenon was predicted with and without shrouds. To demonstrate the adequacy of the effectiveness of shroud arrangement and to validate the simulation methodology of RELAP5/Mod3.2, experiments has been conducted on a scaled model of the pool with and without shroud. (author)

  6. Modelling of Thermal Behavior of Borehole Heat Exchangers of Geothermal Heat Pump Heating Systems

    Directory of Open Access Journals (Sweden)

    Gornov V.F.

    2016-01-01

    Full Text Available This article reports results of comparing the accuracy of the software package “INSOLAR.GSHP.12”, modeling non-steady thermal behavior of geothermal heat pump heating systems (GHCS and of the similar model “conventional” using finite difference methods for solving spatial non-steady problems of heat conductivity. The software package is based on the method of formulating mathematical models of thermal behavior of ground low-grade heat collection systems developed by INSOLAR group of companies. Equations of mathematical model of spatial non-steady thermal behavior of ground mass of low-grade heat collection system obtained by the developed method have been solved analytically that significantly reduced computing time spent by the software complex “INSOLAR.GSHP.12” for calculations. The method allows to turn aside difficulties associated with information uncertainty of mathematical models of the ground thermal behavior and approximation of external factors affecting the ground. Use of experimentally obtained information about the ground natural thermal behavior in the software package allows to partially take into account the whole complex of factors (such as availability of groundwater, their velocity and thermal behavior, structure and arrangement of ground layers, the Earth’s thermal background, precipitation, phase transformations of moisture in the pore space, and more, significantly influencing the formation of thermal behavior of the ground mass of a low-grade geothermal heat collection system. Numerical experiments presented in the article confirmed the high convergence of the results obtained through the software package “INSOLAR.GSHP.12” with solutions obtained by conventional finite-difference methods.

  7. Salty solutions: their effects on thermal set points in behavioral repertoires of albino rats.

    Science.gov (United States)

    Vitulli, W F; Aker, R; Howard, S W; Jones, W M; Kimball, M W; Quinn, J M

    1994-08-01

    Salt (sodium chloride) has been linked to increased blood pressure and a rise in core body temperature. The objective of this study was to investigate the role played by salt in altering behavioral thermoregulation in albino rats. Different doses of sodium chloride were administered (ip) prior to fixed-interval 2-min. schedules of microwave reinforcement in rats tested in a cold Skinner Box. Three Sprague-Dawley rats were conditioned to regulate their thermal environment with 5-sec. exposures of MW reinforcement in a repeated-measures reversal design. Friedman's non-parametric test showed significant differences among sodium chloride doses and physiologically normal saline. Post hoc sign tests showed that all doses of NaCl suppressed operant behavior for heat except 60 mg/kg. The hypothesis that sodium chloride lowers hypothalamic set point for heat was partially supported.

  8. Thermal behavior and transformation kinetics of titanium dioxide nanocrystallites prepared by coupling agents

    International Nuclear Information System (INIS)

    Chen, W.C.; Wang, Y.T.; Shih, C.J.

    2010-01-01

    Coupling agents have been widely used to retard the sintering of silver paste and minimize co-firing defects due to densification mismatch between silver and dielectrics. The thermal-decomposition and crystallization behavior of the coupling agent is a subject of great concern. To elucidate what is responsible for the oxidation, Ti organometallic compounds were calcined at different temperatures (350, 400, 500, 600 o C) for 2 h and the crystallization behavior was determined by X-ray diffraction (XRD). The activation energy for crystallization of coupling agents was studied by using isothermal methods. According to the quantitative XRD method, the values calculated by the Johnson-Mehi-Avrami equation are 134.9 kJ mol -1 . The growth morphology parameters are 1.061, 0.915, 1.016 respectively. Combining the results of DTA, XRD and TEM, it is found that formation of nanocrystallized titania accompanies the combustion of organometallic compounds.

  9. Thermal behavior and transformation kinetics of titanium dioxide nanocrystallites prepared by coupling agents

    Energy Technology Data Exchange (ETDEWEB)

    Chen, W.C. [School of Dentistry, Kaohsiung Medical University, 100 Shi-Chuan 1st Road, Kaohsiung 80708, Taiwan (China); Wang, Y.T. [Department of Medical Research and Education, Chen Hsin General Hospital, 45 Cheng-Hsin Street, Pai-Tou, Taipei 11220, Taiwan (China); Shih, C.J., E-mail: cjshih@kmu.edu.t [Department of Fragrance and Cosmetics Science, Kaohsiung Medical University, 100 Shi-Chuan1st Road, Kaohsiung 80708, Taiwan (China)

    2010-02-04

    Coupling agents have been widely used to retard the sintering of silver paste and minimize co-firing defects due to densification mismatch between silver and dielectrics. The thermal-decomposition and crystallization behavior of the coupling agent is a subject of great concern. To elucidate what is responsible for the oxidation, Ti organometallic compounds were calcined at different temperatures (350, 400, 500, 600 {sup o}C) for 2 h and the crystallization behavior was determined by X-ray diffraction (XRD). The activation energy for crystallization of coupling agents was studied by using isothermal methods. According to the quantitative XRD method, the values calculated by the Johnson-Mehi-Avrami equation are 134.9 kJ mol{sup -1}. The growth morphology parameters are 1.061, 0.915, 1.016 respectively. Combining the results of DTA, XRD and TEM, it is found that formation of nanocrystallized titania accompanies the combustion of organometallic compounds.

  10. Effect of irradiation on differential thermal properties and crystallization behavior of some lithium borate glasses

    International Nuclear Information System (INIS)

    El-Alaily, N.A.; Mohamed, R.M.

    2001-01-01

    Differential thermal properties and the crystallization behavior of binary system Li 2 O-B 2 O 3 glasses were investigated. The effects of the presence of oxides of aluminum, lead or one of the transition metals TiO 2 or V 2 O 5 or Fe 2 O 3 in the parent glass were also studied. The effects of three different heat treatments on the crystalline structure of all the studied glasses were also investigated. The results showed that all glass samples were amorphous before the heat treatment, with the most common formed phase being tetraborate Li 2 B 8 O 13 (Li 2 O-4B 2 O 3 ). The exposure of the glass samples to either gamma rays or fast neutrons resulted in considerable changes in their thermal behavior. The results also showed that T g increases for all studied glasses when subjected to irradiation either by fast neutron or gamma rays, while T c decreased only at higher doses

  11. Thermal-stress fatigue behavior of twenty-six superalloys

    Science.gov (United States)

    Bizon, P. T.; Spera, D. A.

    1976-01-01

    The comparative thermal-stress fatigue resistances of 26 nickeland cobalt-base alloys were determined by fluidized bed tests. Cycles to cracking differed by almost three orders of magnitude for these materials, with directional solidification and surface protection showing definite benefit. The alloy-coating combination with the highest thermal-stress fatigue resistance was directionally solidified NASA TAZ-8A with an RT-SP coating. Its oxidation resistance was also excellent, showing approximately a 1/2 percent weight loss after 14,000 fluidized bed cycles.

  12. Rheological behavior, chemical and physical characterization of soybean and cottonseed methyl esters submitted to thermal oxidation process

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Adriano Sant' ana; Silva, Flavio Luiz Honorato da; Lima, Ezenildo Emanuel de; Carvalho, Maria Wilma N.C. [Universidade Federal de Campina Grande (CCT/UFCG), PB (Brazil). Centro de Ciencia e Tecnologia; Dantas, Hemeval Jales; Farias, Paulo de Almeida [Universidade Federal de Campina Grande (CTRN/UFCG), PB (Brazil). Centro de Tecnologia e Recursos Naturais

    2008-07-01

    In this study the effect of antioxidant terc-butylhydroxyanisol (BHA) on the oxidative stability of soybean and cottonseed methyl esters subjected to thermal degradation at 100 deg C was studied. Soybean and cottonseed methyl esters specific mass, dynamic viscosity and rheological behavior were evaluated. According to results, antioxidant degraded samples specific mass and dynamic viscosity did not showed alterations, remaining statistically equal. Soybean and cottonseed methyl esters showed a Newtonian rheological behavior and degraded samples without adding BHA showed rheological behavior alterations. (author)

  13. Thermal behavior and failure mechanism of lithium ion cells during overcharge under adiabatic conditions

    International Nuclear Information System (INIS)

    Ye, Jiana; Chen, Haodong; Wang, Qingsong; Huang, Peifeng; Sun, Jinhua; Lo, Siuming

    2016-01-01

    Highlights: • The modified adiabatic method is used to measure the heat generation under overcharge. • Side reactions contribute 80% heat to thermal runaway in the cases with cycling rate below 1.0 C. • The inflection and maximum voltages increase linearly with the increasing current rates. • The decomposed products of cathode materials are soluble with that of SiO_x. • Lithium plating on anode is due to changes of distance between the cathode and anode. - Abstract: Cells in battery packs are easily overcharged when battery management system (BMS) is out of order, causing thermal runaway. However, the traditional calorimetry could not estimate dynamic overcharging heat release. In this study, commercial LiCoO_2 + Li(Ni_0_._5Co_0_._2Mn_0_._3)O_2/C + SiO_x cells are employed to investigate the dynamic thermal behaviors during overcharge under adiabatic condition by combining a multi-channel battery cycler with an accelerating rate calorimeter. The results indicate that overcharging with galvanostatic - potentiostatic - galvanostatic regime is more dangerous than that with galvanostatic way. Side reactions contribute 80% heat to thermal runaway in cases below 1.0 C charging rate. To prevent the thermal runaway, the effective methods should be taken within 2 min to cool down the batteries as soon as the cells pass inflection point voltage. Hereinto, the inflection and maximum voltages increase linearly with the increasing current rates. By scanning electron microscope and energy dispersive spectrometer, the decomposed products of cathode materials are suspected to be soluble with SiOx. The overcharge induced decomposition reaction of Li(Ni_0_._5Co_0_._2Mn_0_._3)O_2 is also proposed. These results can provide support for the safety designs of lithium ion batteries and BMS.

  14. The effect of Y2O3 addition on thermal shock behavior of magnesium aluminate spinel

    Directory of Open Access Journals (Sweden)

    Pošarac Milica

    2009-01-01

    Full Text Available The effect of yttria additive on the thermal shock behavior of magnesium aluminate spinel has been investigated. As a starting material we used spinel (MgAl2O4 obtained by the modified glycine nitrate procedure (MGNP. Sintered products were characterized in terms of phase analysis, densities, thermal shock, monitoring the damaged surface area in the refractory specimen during thermal shock and ultrasonic determination of the Dynamic Young modulus of elasticity. It was found that a new phase between yttria and alumina is formed, which improved thermal shock properties of the spinel refractories. Also densification of samples is enhanced by yttria addition.

  15. Thermal stability, swelling behavior and CO 2 absorption properties of Nanoscale Ionic Materials (NIMs)

    KAUST Repository

    Andrew Lin, Kun-Yi; Park, Youngjune; Petit, Camille; Park, Ah-Hyung Alissa

    2014-01-01

    © The Royal Society of Chemistry 2015. Nanoscale Ionic Materials (NIMs) consist of a nanoscale core, a corona of charged brushes tethered on the surface of the core, and a canopy of the oppositely charged species linked to the corona. Unlike conventional polymeric nanocomposites, NIMs can display liquid-like behavior in the absence of solvents, have a negligible vapor pressure and exhibit unique solvation properties. These features enable NIMs to be a promising CO2 capture material. To optimize NIMs for CO2 capture, their structure-property relationships were examined by investigating the roles of the canopy and the core in their thermal stability, and thermally- and CO2-induced swelling behaviors. NIMs with different canopy sizes and core fractions were synthesized and their thermal stability as well as thermally- and CO2-induced swelling behaviors were determined using thermogravimetry, and ATR FT-IR and Raman spectroscopies. It was found that the ionic bonds between the canopy and the corona, as well as covalent bonds between the corona and the core significantly improved the thermal stability compared to pure polymer and polymer/nanofiller mixtures. A smaller canopy size and a larger core fraction led to a greater enhancement in thermal stability. This thermal stability enhancement was responsible for the long-term thermal stability of NIMs over 100 temperature swing cycles. Owing to their ordered structure, NIMs swelled less when heated or when they adsorbed CO2 compared to their corresponding polymers. This journal is

  16. Thermal stability, swelling behavior and CO 2 absorption properties of Nanoscale Ionic Materials (NIMs)

    KAUST Repository

    Andrew Lin, Kun-Yi

    2014-11-11

    © The Royal Society of Chemistry 2015. Nanoscale Ionic Materials (NIMs) consist of a nanoscale core, a corona of charged brushes tethered on the surface of the core, and a canopy of the oppositely charged species linked to the corona. Unlike conventional polymeric nanocomposites, NIMs can display liquid-like behavior in the absence of solvents, have a negligible vapor pressure and exhibit unique solvation properties. These features enable NIMs to be a promising CO2 capture material. To optimize NIMs for CO2 capture, their structure-property relationships were examined by investigating the roles of the canopy and the core in their thermal stability, and thermally- and CO2-induced swelling behaviors. NIMs with different canopy sizes and core fractions were synthesized and their thermal stability as well as thermally- and CO2-induced swelling behaviors were determined using thermogravimetry, and ATR FT-IR and Raman spectroscopies. It was found that the ionic bonds between the canopy and the corona, as well as covalent bonds between the corona and the core significantly improved the thermal stability compared to pure polymer and polymer/nanofiller mixtures. A smaller canopy size and a larger core fraction led to a greater enhancement in thermal stability. This thermal stability enhancement was responsible for the long-term thermal stability of NIMs over 100 temperature swing cycles. Owing to their ordered structure, NIMs swelled less when heated or when they adsorbed CO2 compared to their corresponding polymers. This journal is

  17. Cyclic thermal behavior associated to the degassing process at El Hierro submarine volcano, Canary Islands.

    Science.gov (United States)

    Fraile-Nuez, E.; Santana-Casiano, J. M.; González-Dávila, M.

    2016-12-01

    One year after the ceasing of magmatic activity in the shallow submarine volcano of the island of El Hierro, significant physical-chemical anomalies produced by the degassing process as: (i) thermal anomalies increase of +0.44 °C, (ii) pH decrease of -0.034 units, (iii) total dissolved inorganic carbon, CT increase by +43.5 µmol kg-1 and (iv) total alkalinity, AT by +12.81 µmol kg-1 were still present in the area. These evidences highlight the potential role of the shallow degassing processes as a natural ecosystem-scale experiments for the study of significant effects of global change stressors on marine environments. Additionally, thermal time series obtained from a temporal yo-yo CTD study, in isopycnal components, over one of the most active points of the submarine volcano have been analyzed in order to investigate the behavior of the system. Signal processing of the thermal time series highlights a strong cyclic temperature period of 125-150 min at 99.9% confidence, due to characteristic time-scales revealed in the periodogram. These long cycles might reflect dynamics occurring within the shallow magma supply system below the island of El Hierro.

  18. Diurnal Thermal Behavior of Photovoltaic Panel with Phase Change Materials under Different Weather Conditions

    Directory of Open Access Journals (Sweden)

    Jae-Han Lim

    2017-12-01

    Full Text Available The electric power generation efficiency of photovoltaic (PV panels depends on the solar irradiation flux and the operating temperature of the solar cell. To increase the power generation efficiency of a PV system, this study evaluated the feasibility of phase change materials (PCMs to reduce the temperature rise of solar cells operating under the climate in Seoul, Korea. For this purpose, two PCMs with different phase change characteristics were prepared and the phase change temperatures and thermal conductivities were compared. The diurnal thermal behavior of PV panels with PCMs under the Seoul climate was evaluated using a 2-D transient thermal analysis program. This paper discusses the heat flow characteristics though the PV cell with PCMs and the effects of the PCM types and macro-packed PCM (MPPCM methods on the operating temperatures under different weather conditions. Selection of the PCM type was more important than the MMPCM methods when PCMs were used to enhance the performance of PV panels and the mean operating temperature of PV cell and total heat flux from the surface could be reduced by increasing the heat transfer rate through the honeycomb grid steel container for PCMs. Considering the mean operating temperature reduction of 4 °C by PCM in this study, an efficiency improvement of approximately 2% can be estimated under the weather conditions of Seoul.

  19. Study on thermal-hydraulics during a PWR reflood phase

    Energy Technology Data Exchange (ETDEWEB)

    Iguchi, Tadashi [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    1998-10-01

    In-core thermal-hydraulics during a PWR reflood phase following a large-break LOCA are quite unique in comparison with two-phase flow which has been studied widely in previous researches, because the geometry of the flow path is complicated (bundle geometry) and water is at extremely low superficial velocity and almost under stagnant condition. Hence, some phenomena realized during a PWR reflood phase are not understood enough and appropriate analytical models have not been developed, although they are important in a viewpoint of reactor safety evaluation. Therefore, author investigated some phenomena specified as important issues for quantitative prediction, i.e. (1) void fraction in a bundle during a PWR reflood phase, (2) effect of radial core power profile on reflood behavior, (3) effect of combined emergency core coolant injection on reflood behavior, and (4) the core separation into two thermal-hydraulically different regions and the in-core flow circulation behavior observed during a combined injection PWR reflood phase. Further, author made analytical models for these specified issues, and succeeded to predict reflood behaviors at representative types of PWRs, i.e.cold leg injection PWRs and Combined injection PWRs, in good accuracy. Above results were incorporated into REFLA code which is developed at JAERI, and they improved accuracy in prediction and enlarged applicability of the code. In the present study, models were intended to be utilized in a practical use, and hence these models are simplified ones. However, physical understanding on the specified issues in the present study is basic and principal for reflood behavior, and then it is considered to be used in a future advanced code development and improvement. (author). 110 refs.

  20. Structural analysis and thermal behavior of diopside-fluorapatite-wollastonite-based glasses and glass-ceramics.

    Science.gov (United States)

    Kansal, Ishu; Tulyaganov, Dilshat U; Goel, Ashutosh; Pascual, Maria J; Ferreira, José M F

    2010-11-01

    Glass-ceramics in the diopside (CaMgSi2O6)-fluorapatite (Ca5(PO4)3F)-wollastonite (CaSiO3) system are potential candidates for restorative dental and bone implant materials. The present study describes the influence of varying SiO2/CaO and CaF2/P2O5 molar ratio on the structure and thermal behavior of glass compositions in the CaO-MgO-SiO2-P2O5-Na2O-CaF2 system. The structural features and properties of the glasses were investigated by nuclear magnetic resonance (NMR), infrared spectroscopy, density measurements and dilatometry. Sintering and crystallization behavior of the glass powders were studied by hot-stage microscopy and differential thermal analysis, respectively. The microstructure and crystalline phase assemblage in the sintered glass powder compacts were studied under non-isothermal heating conditions at 825 °C. X-ray diffraction studies combined with the Rietveld-reference intensity ratio (R.I.R) method were employed to quantify the amount of amorphous and crystalline phases in the glass-ceramics, while scanning electron microscopy was used to shed some light on the microstructure of resultant glass-ceramics. An increase in CaO/SiO2 ratio degraded the sinterability of the glass powder compacts, resulting in the formation of akermanite as the major crystalline phase. On the other hand, an increase in P2O5/CaF2 ratio improved the sintering behavior of the glass-ceramics, while varying the amount of crystalline phases, i.e. diopside, fluorapatite and wollastonite. Copyright © 2010. Published by Elsevier Ltd.

  1. Space shuttle aps propellant thermal conditioner study

    Science.gov (United States)

    Fulton, D. L.

    1973-01-01

    An analytical and experimental effort was completed to evaluate a baffle type thermal conditioner for superheating O2 and H2 at supercritical pressures. The thermal conditioner consisted of a heat exchanger and an integral reactor (gas generator) operating on O2/H2 propellants. Primary emphasis was placed on the hydrogen conditioner with some effort on the oxygen conditioner and a study completed of alternate concepts for use in conditioning oxygen. A hydrogen conditioner was hot fire tested under a range of conditions to establish ignition, heat exchange and response parameters. A parallel technology task was completed to further evaluate the integral reactor and heat exchanger with the side mounted electrical spark igniter.

  2. The effects of dune slopes and material heterogeneity on the thermal behavior of dune fields in Mars' Southern Hemisphere

    Science.gov (United States)

    O'Shea, P. M.; Putzig, N. E.; Van Kooten, S.; Fenton, L. K.

    2015-12-01

    We analyzed the effects of slopes on the thermal properties of three dune fields in Mars' southern hemisphere. Although slope has important thermal effects, it is not the main driver of observed apparent thermal inertia (ATI) for these dunes. Comparing the ATI seasonal behavior as derived from Thermal Emission Spectrometer (TES) data with that modeled for compositional heterogeneities, we found that TES results correlate best with models of duricrust overlying and/or horizontally mixing with fines. We measured slopes and aspects in digital terrain models created from High Resolution Imaging Science Experiment (HiRISE) images of dunes within Proctor, Kaiser, and Wirtz craters. Using the MARSTHERM web toolset, we incorporated the slopes and aspects together with TES albedo, TES thermal inertia, surface pressure, and TES dust opacity, into models of seasonal ATI. Models that incorporate sub-pixel slopes show seasonal day and night ATI values that differ from the TES results by 0-300 J m-2 K-1 s-½. In addition, the models' day-night differences are opposite in sign from those of the TES results, indicating that factors other than slope are involved. We therefore compared the TES data to model results for a broad range of horizontally mixed and two-layered surfaces to seek other possible controls on the observed data, finding that a surface layer of higher thermal inertia is a likely contributor. However, it is clear from this study that the overall composition and morphology of the dune fields are more complex than currently available models allow. Future work will combine slopes with other model parameters such as multi-layered surfaces and lateral changes in layer thickness. Coupling these improvements with broader seasonal coverage from the Thermal Emission Imaging System (THEMIS) at more thermally favorable times of day would allow more accurate characterization of dune thermal behavior.

  3. Thermal behavior and pyrolytic degradation kinetics of polymeric mixtures from waste packaging plastics

    Directory of Open Access Journals (Sweden)

    R. Tuffi

    2018-01-01

    Full Text Available The thermal behavior and pyrolytic kinetic analysis of main waste polymers (polypropylene (PP, polyethylene film (PE, poly(ethylene terephthalate (PET, polystyrene (PS and three synthetic mixtures representing commingled postconsumer plastics wastes (CPCPWs output from material recovery facilities were studied. Thermogravimetry (TG pyrolysis experiments revealed that the thermal degradation of single polymers and the synthetic mixture enriched in PP occurred in one single step. The other two mixtures underwent a two-consecutive, partially overlapping degradation steps, whose peaks related to the first-order derivative of TG were deconvoluted into two distinct processes. Further TG experiments carried out on binary mixtures (PS/PP, PET/PP, PET/PEfilm and PP/PEfilm showed a thermal degradation reliance on composition, structure and temperatures of single polymer components. A kinetic analysis was made for each step using the Kissinger-Akahira-Sunose (KAS method, thus determining almost constant activation energy (Ea for pyrolysis of PS, PET, PP and PE film in the range 0.25<α<0.85, unlike for pyrolysis of CPCPWs, with particular reference to CPCPW1 and the second step of CPCPW2 and CPCPW3, both ascribable to degradation of PP and PE film. To account for the reliability of these values the integral isoconversional modified method developed by Vyazovkin was also applied.

  4. Solidification behavior and thermal conductivity of bulk sodium acetate trihydrate composites with thickening agents and graphite

    DEFF Research Database (Denmark)

    Dannemand, Mark; Johansen, Jakob Berg; Furbo, Simon

    2016-01-01

    Sodium acetate trihydrate is a promising phase change material for long term storage of solar thermal energy if supercooling is actively utilized. Well performing thermal energy storages need to be able to charge and discharge energy at a high rate. The relatively low thermal conductivity....... Investigations of the solidification behavior, the formation of cavities and thermal conductivity of composites based on sodium acetate trihydrate crystalizing with or without supercooling are presented in this paper. The thermal conductivity was measured with an ISOMET hot disc surface measurement probe....... Samples that crystalized without supercooling tended to form solid crystals near the heat transfer surface and cavities away from the heat transfer surface. The measured thermal conductivity was up to 0.7 W/m K in solid sodium acetate trihydrate. Samples that crystalized from supercooled state formed...

  5. Studies of planetary boundary layer by infrared thermal imagery

    Energy Technology Data Exchange (ETDEWEB)

    Albina, Bogdan; Dimitriu, Dan Gheorghe, E-mail: dimitriu@uaic.ro; Gurlui, Silviu Octavian, E-mail: dimitriu@uaic.ro [Alexandru Ioan Cuza University of Iasi, Faculty of Physics, Atmosphere Optics, Spectroscopy and Lasers Laboratory, 11 Carol I Blvd., 700506 Iasi (Romania); Cazacu, Marius Mihai [Alexandru Ioan Cuza University of Iasi, Faculty of Physics, Atmosphere Optics, Spectroscopy and Lasers Laboratory, 11 Carol I Blvd., 700506 Iasi, Romania and Department of Physics, Gheorghe Asachi Technical University of Iasi, 59A Mangeron Blvd., 700 (Romania); Timofte, Adrian [Alexandru Ioan Cuza University of Iasi, Faculty of Physics, Atmosphere Optics, Spectroscopy and Lasers Laboratory, 11 Carol I Blvd., 700506 Iasi, Romania and National Meteorological Administration, Regional Forecast Center Bacau, 1 Cuza Voda Str., 60 (Romania)

    2014-11-24

    The IR camera is a relatively novel device for remote sensing of atmospheric thermal processes from the Planetary Boundary Layer (PBL) based on measurements of the infrared radiation. Infrared radiation is energy radiated by the motion of atoms and molecules on the surface of aerosols, when their temperature is more than absolute zero. The IR camera measures directly the intensity of radiation emitted by aerosols which is converted by an imaging sensor into an electric signal, resulting a thermal image. Every image pixel that corresponds to a specific radiance is pre-processed to identify the brightness temperature. The thermal infrared imaging radiometer used in this study, NicAir, is a precision radiometer developed by Prata et al. The device was calibrated for the temperature range of 270–320 K and using a calibration table along with image processing software, important information about variations in temperature can be extracted from acquired IR images. The PBL is the lowest layer of the troposphere where the atmosphere interacts with the ground surfaces. The importance of PBL lies in the fact that it provides a finite but varying volume in which pollutants can disperse. The aim of this paper is to analyze the PBL altitude and thickness variations over Iasi region using the IR imaging camera as well as its behavior from day to night and thermal processes occurring in PBL.

  6. Study on cylindrical specimen subjected to oligocyclic thermal fatigue

    International Nuclear Information System (INIS)

    Cesari, F.; Battistella, P.; Quaranta, S.; Arduino, M.

    1993-01-01

    During the last years the development in the analysis of the thermal fatigue phenomenon was remarkable in particularly in industry. This improvement was more and more evident on the specific power of the engines, involving a general rise in the working temperature and in the stress level of oligocyclic thermal fatigue due to the start /stop of the engine. As far as this is concerned, the theoretical capabilities of the LIN (Nuclear Engineering Laboratory of Montecuccolino) has been requested in the frame of a collaboration with the IVECO Spa of Turin in view of verifying experimental data. The investigation of the thermal fatigue consequences has been undertaken by analyzing a cylindrical sample; its material was similar to that of the engine's head. Its was axially clamped in the two extremes and subjected to repeated thermal cycles. Beginning from the first experimental results supplied by IVECO, a theoretical - numerical campaign has been started in order to attempt a correct interpretation of the experimental behavior. The computer codes adopted in this study are mainly two typical FE programs (CASTEM and ANSYS) which have been carried out in parallel. First, both the physical and mechanical experimental conditions have been accurately reproduced in the model prepared for structural analysis. Second, several runs of calculations ware worked out to obtain a stress-strain description during some load - unload cycles. The material law is obviously non-linear because the strong variations in the temperature distributions cause high stress levels well above the yielding point

  7. Study of the thermal degradation of citrus seeds

    Energy Technology Data Exchange (ETDEWEB)

    Hernandez-Montoya, V. [Centro de Quimica, Instituto de Ciencias, Universidad Autonoma de Puebla, Apdo. Postal J-55, Puebla 72570, Pue (Mexico); Instituto Nacional del Carbon, CSIC, Apartado 73, E-33080 Oviedo (Spain); Montes-Moran, M.A. [Instituto Nacional del Carbon, CSIC, Apartado 73, E-33080 Oviedo (Spain); Elizalde-Gonzalez, M.P. [Centro de Quimica, Instituto de Ciencias, Universidad Autonoma de Puebla, Apdo. Postal J-55, Puebla 72570, Pue (Mexico)

    2009-09-15

    The citrus seeds are one of the principal residues in the juice industry and their utilization can decrease significantly the problems of their final disposal. In this work the thermal degradation of three Mexican citrus seeds: orange (Citrus sinensis), lemon (Citrus Limon) and grapefruit (Citrus paradisi) was studied in nitrogen atmosphere. The two components (embryo and husk) of the seeds were characterized separately. The results showed that the thermal effects are very similar between the three embryos and the three husks. The embryos show higher degradability, superior content of nitrogen and higher heating value than the husks. The thermal degradation of the components of the three seeds is completed at 600 C and it is considered to be a global process derived from the decomposition of their principal components (cellulose, hemicellulose and lignin). The results suggest that mixing the three entire seeds will not lead to a severe deviation from their individual thermal behavior and that the industry could apply them for carbonization purposes. (author)

  8. Study on cylindrical specimen subjected to oligocyclic thermal fatigue

    Energy Technology Data Exchange (ETDEWEB)

    Cesari, F; Battistella, P [Nuclear Engineering Laboratory ' Montecuccolino' , University of Bologna (Italy); Quaranta, S; Arduino, M [IVECO Engineering, Torino (Italy)

    1993-07-01

    During the last years the development in the analysis of the thermal fatigue phenomenon was remarkable in particularly in industry. This improvement was more and more evident on the specific power of the engines, involving a general rise in the working temperature and in the stress level of oligocyclic thermal fatigue due to the start /stop of the engine. As far as this is concerned, the theoretical capabilities of the LIN (Nuclear Engineering Laboratory of Montecuccolino) has been requested in the frame of a collaboration with the IVECO Spa of Turin in view of verifying experimental data. The investigation of the thermal fatigue consequences has been undertaken by analyzing a cylindrical sample; its material was similar to that of the engine's head. Its was axially clamped in the two extremes and subjected to repeated thermal cycles. Beginning from the first experimental results supplied by IVECO, a theoretical - numerical campaign has been started in order to attempt a correct interpretation of the experimental behavior. The computer codes adopted in this study are mainly two typical FE programs (CASTEM and ANSYS) which have been carried out in parallel. First, both the physical and mechanical experimental conditions have been accurately reproduced in the model prepared for structural analysis. Second, several runs of calculations ware worked out to obtain a stress-strain description during some load - unload cycles. The material law is obviously non-linear because the strong variations in the temperature distributions cause high stress levels well above the yielding point.

  9. Polychlorinated naphthalene (PCNs) behavior in the thermal destruction process of wastes containing PCNs

    Energy Technology Data Exchange (ETDEWEB)

    Noma, Y.; Sakai, Shin-ichi [National Institute for Environmental Studies, Tsukuba, Ibaraki (Japan); Giraud, R. [DuPont Engineering Technology Wilmington, DE (United States)

    2004-09-15

    Polychlorinated naphthalenes (PCNs) can compose a mixture of up to 75 congeners and eight CN homologue groups. The large-scale manufacture of PCNs and their main use from 1910 to 1980 as popular industrial compounds become a main source of environmental pollution. The production and use of PCNs were phased out in the US and Europe in the 1980s due to their toxicity and environmental persistence. Although PCNs were also banned for import and manufacture from the year 1979 in Japan, PCN wax was accidentally imported during 1998-2000 to manufacture Neoprene FB polymer, which is a special grade of synthetic rubber product. Rubber belts (FB belts) were made from Neoprene FB and used for the domestic market during 1999-2001. Large efforts recalled all FB polymer as well as finished products containing FB polymer from distribution channels. Most of the remaining finished products in the marketplace will probably be incinerated as wastes after usage in the near future. Therefore, testing was conducted using the thermal testing plant equipment in order to evaluate the emissions from thermal destruction of FB belts containing PCNs, determining TEQ emissions, studying PCNs behavior, considering the mixture effect of FB belts co-incinerated with municipal solid waste (MSW) and examining the effect of two-stage combustion and post-combustion controls. Material balances were analyzed to grasp input and output of PCNs and the destruction behaviors are examined by congener specific analysis of PCNs.

  10. Reactor thermal behaviors under kinetics parameters variations in fast reactivity insertion

    Energy Technology Data Exchange (ETDEWEB)

    Abou-El-Maaty, Talal [Reactors Department, Atomic Energy Authority, Cairo 13759 (Egypt)], E-mail: talal22969@yahoo.com; Abdelhady, Amr [Reactors Department, Atomic Energy Authority, Cairo 13759 (Egypt)

    2009-03-15

    The influences of variations in some of the kinetics parameters affecting the reactivity insertion are considered in this study, it has been accomplished in order to acquire knowledge about the role that kinetic parameters play in prompt critical transients from the safety point of view. The kinetics parameters variations are limited to the effective delayed neutron fraction ({beta}{sub eff}) and the prompt neutron generation time ({lambda}). The reactor thermal behaviors under the variations in effective delayed neutron fraction and prompt neutron generation time included, the reactor power, maximum fuel temperature, maximum clad temperature, maximum coolant temperature and the mass flux variations at the hot channel. The analysis is done for a typical swimming pool, plate type research reactor with low enriched uranium. The scram system is disabled during the accidents simulations. Calculations were done using PARET code. As a result of simulations, it is concluded that, the reactor (ETRR2) thermal behavior is considerably more sensitive to the variation in the effective delayed neutron fraction than to the variation in prompt neutron generation time and the fast reactivity insertion in both cases causes a flow expansion and contraction at the hot channel exit. The amplitude of the oscillated flow is a qualitatively increases with the decrease in both {beta}{sub eff} and {lambda}.

  11. Intrathecal huperzine A increases thermal escape latency and decreases flinching behavior in the formalin test in rats.

    Science.gov (United States)

    Park, Paula; Schachter, Steven; Yaksh, Tony

    2010-02-05

    Huperzine A (HupA) is an alkaloid isolated from the Chinese club moss Huperzia serrata and has been used for improving memory, cognitive and behavioral function in patients with Alzheimer's disease in China. It has NMDA antagonist and anticholinesterase activity and has shown anticonvulsant and antinociceptive effects in preliminary studies when administered intraperitoneally to mice. To better characterize the antinociceptive effects of HupA at the spinal level, Holtzman rats were implanted with intrathecal catheters to measure thermal escape latency using Hargreaves thermal escape testing system and flinching behavior using the formalin test. Intrathecal (IT) administration of HupA showed a dose-dependent increase in thermal escape latency with an ED50 of 0.57 microg. Atropine reversed the increase in thermal escape latency produced by 10 microg HupA, indicating an antinociceptive mechanism through muscarinic cholinergic receptors. The formalin test showed that HupA decreased flinching behavior in a dose-dependent manner. Atropine also reversed the decrease in flinching behavior caused by 10 microg HupA. A dose-dependent increase of side effects including scratching, biting, and chewing tails was observed, although antinociceptive effects were observed in doses that did not produce any adverse effects. (c) 2009 Elsevier Ireland Ltd. All rights reserved.

  12. Numerical study on lithium titanate battery thermal response under adiabatic condition

    International Nuclear Information System (INIS)

    Sun, Qiujuan; Wang, Qingsong; Zhao, Xuejuan; Sun, Jinhua; Lin, Zijing

    2015-01-01

    Highlights: • The thermal behavior of lithium titanate battery during cycling was investigated. • The temperature rate in charging was less than that of discharging in the cycling. • The temperature difference was less than 0.02 °C at 0.5 C in adiabatic condition. • The temperature distribution and thermal runaway of the battery were predicted. - Abstract: To analyze the thermal behavior of 945 mA h lithium titanate battery during charging and discharging processes, the experimental and numerical studies are performed in this work. The cathode and anode of the 945 mA h lithium titanate soft package battery are the lithium nickel–cobalt–manganese-oxide and lithium titanate, respectively. In the experiment, an Accelerating Rate Calorimeter combined with battery cycler is employed to investigate the electrochemical–thermal behavior during charge–discharge cycling under the adiabatic condition. In numerical simulation, one electrochemical-thermal model is adopted to predict the thermal response and validated with the experimental results. From both experimental and simulated results, the profile of potential and current, the heat generation, the temperature, the temperature changing rate and the temperature distribution in the cell are obtained and thermal runaway is predicted. The analysis of the electrochemical and thermal behavior is beneficial for the commercial application of lithium titanate battery in the fields of electric vehicles and hybrid electric vehicles

  13. Nuclear thermal propulsion engine cost trade studies

    International Nuclear Information System (INIS)

    Paschall, R.K.

    1993-01-01

    The NASA transportation strategy for the Mars Exploration architecture includes the use of nuclear thermal propulsion as the primary propulsion system for Mars transits. It is anticipated that the outgrowth of the NERVA/ROVER programs will be a nuclear thermal propulsion (NTP) system capable of providing the propulsion for missions to Mars. The specific impulse (Isp) for such a system is expected to be in the 870 s range. Trade studies were conducted to investigate whether or not it may be cost effective to invest in a higher performance (Isp>870 s) engine for nuclear thermal propulsion for missions to Mars. The basic cost trades revolved around the amount of mass that must be transported to low-earth orbit prior to each Mars flight and the cost to launch that mass. The mass required depended on the assumptions made for Mars missions scenarios including piloted/cargo flights, number of Mars missions, and transit time to Mars. Cost parameters included launch cost, program schedule for development and operations, and net discount rate. The results were very dependent on the assumptions that were made. Under some assumptions, higher performance engines showed cost savings in the billions of dollars; under other assumptions, the additional cost to develop higher performance engines was not justified

  14. Research on seasonal indoor thermal environment and residents' control behavior of cooling and heating systems in Korea

    Energy Technology Data Exchange (ETDEWEB)

    Bae, Chihye; Chun, Chungyoon [Department of Housing and Interior Design, College of Human Ecology, Graduate School, Yonsei University, Seoul (Korea)

    2009-11-15

    Indoor thermal environments and residents' control behavior of cooling and heating systems were investigated in Seoul, Korea and compared with the results of previous studies. Twenty-four houses in summer, six houses in autumn and 36 houses in winter were used in this study. The measurement of temperature, humidity and air conditioner usage behavior was carried out. The clo-value, thermal comfort, sensation and basic data of the houses were also investigated. The indoor thermal environment in the summer had a high temperature and a high humidity ratio compare to standard comfort zone. Most of the indoor thermal environments at the time of starting the air conditioner in the summer were out of the comfort zone. Some of the data recorded while the air conditioner was stopped were in the comfort zone, but in many cases the temperature was relatively higher than comfort zone. Most indoor climate distributions in the winter were in the comfort zone and the indoor climate in autumn coincided well with the criteria of the comfort zone. Compared with results of previous studies in these 25 years, indoor ambient average temperature in winter has increased and the comfort temperature has increased in the heating period and decreased in the cooling period. This result indicates that the development of an HVAC system has created an expectation of comfort for residents and has shifted their thermal comfort zone warmer in winter and cooler in summer. (author)

  15. Solar thermal electric power information user study

    Energy Technology Data Exchange (ETDEWEB)

    Belew, W.W.; Wood, B.L.; Marle, T.L.; Reinhardt, C.L.

    1981-02-01

    The results of a series of telephone interviews with groups of users of information on solar thermal electric power are described. These results, part of a larger study on many different solar technologies, identify types of information each group needed and the best ways to get information to each group. The report is 1 of 10 discussing study results. The overall study provides baseline data about information needs in the solar community. An earlier study identified the information user groups in the solar community and the priority (to accelerate solar energy commercialization) of getting information to each group. In the current study only high-priority groups were examined. Results from five solar thermal electric power groups of respondents are analyzed: DOE-Funded Researchers, Non-DOE-Funded Researchers, Representatives of Utilities, Electric Power Engineers, and Educators. The data will be used as input to the determination of information products and services the Solar Energy Research Institute, the Solar Energy Information Data Bank Network, and the entire information outreach community should be preparing and disseminating.

  16. Synthesis, spectroscopy, thermal studies and supramolecular ...

    Indian Academy of Sciences (India)

    TECS

    Synthesis, spectroscopy, thermal studies and supramolecular structures of two .... J = 9 Hz), 8∙13 (d, 2H, J = 9 Hz), 7∙69 (s, 1H), 7∙04. (s, 2H). ... 1H NMR (D2O): δ (in ppm); 8∙05 (d, 2H, ..... 86∙33 (2). 86∙92(1). 87∙08(2). V (Ε3). 553∙1(6). 573∙71(5). 561∙56(14). 557∙5(3) .... Mn, Co and Ni complexes.28–30 The observed inter-.

  17. Animal Studies of Addictive Behavior

    Science.gov (United States)

    Ahmed, Serge H.

    2013-01-01

    It is increasingly recognized that studying drug taking in laboratory animals does not equate to studying genuine addiction, characterized by loss of control over drug use. This has inspired recent work aimed at capturing genuine addiction-like behavior in animals. In this work, we summarize empirical evidence for the occurrence of several DSM-IV-like symptoms of addiction in animals after extended drug use. These symptoms include escalation of drug use, neurocognitive deficits, resistance to extinction, increased motivation for drugs, preference for drugs over nondrug rewards, and resistance to punishment. The fact that addiction-like behavior can occur and be studied in animals gives us the exciting opportunity to investigate the neural and genetic background of drug addiction, which we hope will ultimately lead to the development of more effective treatments for this devastating disorder. PMID:23249442

  18. Effect of grit blasting on the thermal cycling behavior of diffusion aluminide/YSZ TBCs

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Zhenhua, E-mail: zhxuciac@163.com; Huang, Guanghong; He, Limin; Mu, Rende; Wang, Kai; Dai, Jianwei

    2014-02-15

    Highlights: • TBCs including of CVD NiAl bond coat and EB-PVD YSZ ceramic coating with and without grit blasting process. • Grain boundary ridges are the sites for spallation damage initiation in aluminide/YSZ TBCs. • Ridges are removed, and no cavity formation and this damage initiation mode are suppressed. • Damage initiation and progression occurs at the bond coat to TGO interface leading to a buckling failure behavior. -- Abstract: Thermal barrier coating system (TBCs) including of chemical vapor deposited NiAl bond coat and electron beam physical vapor deposited Y{sub 2}O{sub 3}–stabilized-ZrO{sub 2} (YSZ) ceramic coating with and without grit blasting process were investigated. The phase structures, surface and cross-sectional morphologies, cyclic oxidation behaviors of these coatings were studied in detail. Grain boundary ridges form on the surface of aluminide bond coat prior to the deposition of the ceramic coating by EB-PVD, which are shown to be the sites for spallation damage initiation in aluminide/YSZ TBCs. When these ridges are removed, there is no cavity formation and this damage initiation mode is suppressed. Damage initiation and progression occurs at the bond coat to TGO interface leading to a buckling failure behavior. A buckle failure once started may be arrested when it runs into a region of high bond coat to TGO interface toughness. Thus, complete failure requires further loss in toughness of the bond coat to TGO interface with additional cycling. From the result of thermal cycling, an averaged four folds lifetime improvement can be achieved with samples after grit blasting of bond coat surface as compared with those samples existence in ridges on the bond coats’ surface.

  19. Molecular dynamics study of thermal disorder in a bicrystal model

    International Nuclear Information System (INIS)

    Nguyen, T.; Ho, P.S.; Kwok, T.; Yip, S.

    1990-01-01

    This paper studies a (310) θ = 36.86 degrees left-angle 001 right-angle symmetrical-tilt bicrystal model using an Embedded Atom Method aluminum potential. Based on explicit results obtained from the simulations regarding structural order, energy, and mobility, the authors find that their bicrystal model shows no evidence of pre-melting. Both the surface and the grain-boundary interface exhibit thermal disorder at temperatures below T m , with complete melting occurring only at, or very near, T m . Concerning the details of the onset of melting, the data show considerable disordering in the interfacial region starting at about 0.93 T m . The interfaces exhibit metastable behavior in this temperature range, and the temperature variation of the interfacial thickness suggests that the disordering induced by the interface is a continuous transition, a behavior that has been predicted by a theoretical analysis

  20. Study of thermal behavior of the adobe with the simulator DOE 2.1E; Estudio de comportamiento termico del adobe con el simulador DOE 2.1E

    Energy Technology Data Exchange (ETDEWEB)

    Luna, Anibal; Gallegos, Ricardo; Bojorquez, Gonzalo [Universidad Autonoma de Baja California, Mexicali, Baja California (Mexico)

    2000-07-01

    A thermal analysis of the envelope of one of the most used housing models for low income groups, as those offered by the Mexican Government is presented in this report. The building's thermal gain in walls was determined, using: concrete block, brick and adobe; and considering concrete of roofing, concrete floors, windows and doors equal in all the cases. The objective of this study is to know the contribution to the building's thermal load of each one of the materials applied. The calculation was conducted using the Doe 2.1E thermal simulator software, using meteorological data for the city of El Centro, California, USA. This was so, because there is no reliable weather data for the city of Mexicali, B.C., where the housing units are. Because of geographical proximity between of these cities the same data was used. The properties for each one of the three building materials were taken from specialized bibliography. It was determined that the housing built with adobe walls has thermal advantages over the units built with concrete block and brick. The adobe unit has a lower thermal load of 13% over the concrete block, and of 3.44% over the clay brick unit. [Spanish] Se presenta el analisis termico de la envolvente de uno de los modelos de casas mas utilizados en la construccion de viviendas de interes social en Mexico. Se determino la ganancia, termica del edificio por muros, aplicando: bloque de concreto, ladrillo de barro y adobe. Se considero techo, piso, ventanas y puertas iguales en todos los casos. El objetivo del estudio es conocer la distribucion de la carga termica segun los materiales aplicados. El calculo se realizo con el simulador termico DOE 2.1E con datos meteorologicos de la ciudad de El Centro, California, E. U., por no contar con datos de Mexicali, B. C.: debido a la proximidad y similitud topografica entre ambas ciudades se uso la misma informacion. Las propiedades aplicadas para cada uno de los tres materiales fueron tomadas de

  1. Behavior of mixed-oxide fuel subjected to multiple thermal transients

    International Nuclear Information System (INIS)

    Fenske, G.R.; Neimark, L.A.; Poeppel, R.B.; Hofman, G.L.

    1985-01-01

    The microstructural behavior of irradiated mixed-oxide fuel subjected to multiple, mild thermal transients was investigated using direct electrical heating. The results demonstrate that significant intergranular porosity, accompanied by large-scale (>90%) release of the retained fission gas, developed as a result of the cyclic heating. Microstructural examination of the fuel indicated that thermal-shock-induced cracking of the fuel contributed significantly to the increased swelling and gas release. 29 refs., 12 figs

  2. Behavior of mixed-oxide fuel subjected to multiple thermal transients

    International Nuclear Information System (INIS)

    Fenske, G.R.; Hofman, G.L.; Neimark, L.A.; Poeppel, R.B.

    1983-11-01

    The microstructural behavior of irradiated mixed-oxide fuel subjected to multiple, mild thermal transients was investigated using direct electrical heating. The results demonstrate that significant intergranular porosity, accompanied by large-scale (>90%) release of the retained fission gas, developed as a result of the cyclic heating. Microstructural examination of the fuel indicated that thermal-shock-induced cracking of the fuel contributed significantly to the increased swelling and gas release

  3. Comparative study of Thermal Hydraulic Analysis Codes for Pressurized Water Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Yang Hoon; Jang, Mi Suk; Han, Kee Soo [Nuclear Engineering Service and Solution Co. Ltd., Daejeon (Korea, Republic of)

    2015-05-15

    Various codes are used for the thermal hydraulic analysis of nuclear reactors. The use of some codes among these is limited by user and some codes are not even open to general person. Thus, the use of alternative code is considered for some analysis. In this study, simple thermal hydraulic behaviors are analyzed using three codes to show that alternative codes are possible for the analysis of nuclear reactors. We established three models of the simple u-tube manometer using three different codes. RELAP5 (Reactor Excursion and Leak Analysis Program), SPACE (Safety and Performance Analysis CodE for nuclear power Plants), GOTHIC (Generation of Thermal Hydraulic Information for Containments) are selected for this analysis. RELAP5 is widely used codes for the analysis of system behavior of PWRs. SPACE has been developed based on RELAP5 for the analysis of system behavior of PWRs and licensing of the code is in progress. And GOTHIC code also has been widely used for the analysis of thermal hydraulic behavior in the containment system. The internal behavior of u-tube manometer was analyzed by RELAP5, SPACE and GOTHIC codes. The general transient behavior was similar among 3 codes. However, the stabilized status of the transient period analyzed by REPAP5 was different from the other codes. It would be resulted from the different physical models used in the other codes, which is specialized for the multi-phase thermal hydraulic behavior analysis.

  4. CFD studies on thermal hydraulics of spallation targets

    International Nuclear Information System (INIS)

    Tak, N.I.; Batta, A.; Cheng, X.

    2005-01-01

    Full text of publication follows: Due to the fast advances in computer hardware as well as software in recent years, more and more interests have been aroused to use computational fluid dynamics (CFD) technology in nuclear engineering and designs. During recent many years, Forschungszentrum Karlsruhe (FZK) has been actively involved in the thermal hydraulic analysis and design of spallation targets. To understand the thermal hydraulic behaviors of spallation targets very detailed simulations are necessary because of their complex geometries, complicated boundary conditions such as spallation heat distributions, and very strict design limits. A CFD simulation is believed to be the best for this purpose even though the validation of CFD codes are not perfectly completed yet in specific topics like liquid metal heat transfer. The research activities on three spallation targets (i.e., MEGAPIE, TRADE, and XADS targets) are currently very active in Europe in order to consolidate the European ADS road-map. In the thermal hydraulics point of view, two kinds of the research activities, i.e., (1) numerical design and (2) experimental work, are required to achieve the objectives of these targets. It should be noted that CFD studies play important role on both kinds of two activities. A preliminary design of a target can be achieved by sophisticated CFD analysis and pre-and-post analyses of an experimental work using a CFD code help the design of the test section of the experiment as well as the analysis of the experimental results. The present paper gives an overview about the recent CFD studies relating to thermal hydraulics of the spallation targets recently involved in FZK. It covers numerical design studies as well as CFD studies to support experimental works. The CFX code has been adopted for the studies. Main recent results for the selected examples performed by FZK are presented and discussed with their specific lessons learned. (authors)

  5. Synthesis, characterization and thermal behavior of rare earth amido sulfonates

    International Nuclear Information System (INIS)

    Luiz, Jose Marques; Nunes, Ronaldo Spezia; Matos, Jivaldo do Rosario

    2013-01-01

    Hydrated compounds prepared in aqueous solution by reaction between amidosulfonic acid [H 3 NSO 3 ] and suspensions of rare earth hydroxycarbonates [Ln 2 (OH) x (CO 3 ) y .zH 2 O] were characterized by elemental analysis (% Ln, % N and % H), infrared spectroscopy (FTIR) and thermogravimetry (TG). The compounds presented the stoichiometry Ln(NH 2 SO 3 ) 3 .xH 2 O (where x = 1, 5, 2.0 or 3.0). The IR spectra showed absorptions characteristic of H 2 O molecules and NH 2 SO 3 groups. Degree of hydration, thermal decomposition steps and formation of stable intermediates of the type [Ln 2 (SO 4 ) 3 ] and (Ln 2 O 2 SO 4 ), besides formation of their oxides, was determined by thermogravimetry. (author)

  6. Thermal fatigue behavior of US and Russian grades of beryllium

    International Nuclear Information System (INIS)

    Watson, R.D.; Youchison, D.L.; Dombrowski, D.E.; Guiniatouline, R.N.; Kupriynov, I.B.

    1996-01-01

    A novel technique has been used to test the relative low cycle thermal fatigue resistance of different grades of US and Russian beryllium which is proposed as plasma facing armor for fusion reactor first wall, limiter, and divertor components. The 30 KW electron beam test system at Sandia National Laboratories was used to sweep the beam spot along one direction at 1 Hz. This produces a localized temperature ''spike'' of 750 degrees C for each pass of the beam. Large thermal stress in excess of the yield strength are generated due to very high spot heat flux, 250 MW/m 2 . Cyclic plastic strains on the order of 0.6% produced visible cracking on the heated surface in less than 3000 cycles. An in-vacuo fiber optic borescope was used to visually inspect the beryllium surfaces for crack initiation. Grades of US beryllium tested included: S-65C, S-65H, S-200F, S-300F-H, Sr-200, I-400, extruded high purity. HIP'd sperical powder, porous beryllium (94% and 98% dense), Be/30% BeO, Be/60% BeO, and TiBe 12 . Russian grades included: TGP-56, TShGT, DShG-200, and TShG-56. Both the number of cycles to crack initiation, and the depth of crack propagation, were measured. The most fatigue resistant grades were S-65C, DShG-200, TShGT, and TShG-56. Rolled sheet Be(SR-200) showed excellent crack propagation resistance in the plane of rolling, despite early formation of delamination cracks. Only one sample showed no evidence of surface melting, Extruded (T). Metallographic and chemical analyses are provided. Good agreement was found between the measured depth of cracks and a 2-D elastic-plastic finite element stress analysis

  7. Study on thermal properties and crystallization behavior of electron beam irradiated ethylene vinyl acetate (EVA)/waste tyre dust (WTD) blends in the presence of polyethylene graft maleic anhydride (PEgMAH)

    Energy Technology Data Exchange (ETDEWEB)

    Ramli, Syuhada; Ahmad, S. H. [School of Applied Physics, Faculty of Science and Technology, Universiti Kebangsaan (Malaysia); Ratnam, C. T. [Radiation Processing Technology Division, Malaysian Nuclear Agency (Nuclear Malaysia), Bangi, 43000 Kajang (Malaysia); Athirah, Nurul [School of Materials and Mineral Resources, USM Engineering Campus (Malaysia)

    2013-11-27

    The aim of this article is to show the effects of the electron beam irradiation dose and presence of a compatibiliser on the thermal properties and crystallinity of EVA/WTD blends. The purpose of applying electron beam radiation with doses range 50 to 200 kGy and adding a compatibiliser was to enhance the compatibility of the studied blends and at the same time to investigate the possibility of using this technique in the process of recycling polymeric materials. As the compatibilisers, the polyethylene grafted maleic anhydride (PEgMAH) was utilized, they were added at the amounts of 1-5 phr respectively. The enhancement of thermal properties was accompanied by the following effects, discussed in this article: i) an irradiated EVA/WTD blend at 200kGy was found to improve the thermal properties of EVA, ii) the addition of PEgMAH in EVA/WTD blends and the subsequent irradiation allowed prevention of degradation mechanism. iii) the ΔH{sub f} and crystallinity percentage decrease at higher PEgMAH content.

  8. Experimental study of unsteady thermally stratified flow

    International Nuclear Information System (INIS)

    Lee, Sang Jun; Chung, Myung Kyoon

    1985-01-01

    Unsteady thermally stratified flow caused by two-dimensional surface discharge of warm water into a oblong channel was investigated. Experimental study was focused on the rapidly developing thermal diffusion at small Richardson number. The basic objectives were to study the interfacial mixing between a flowing layer of warm water and an underlying body of cold water and to accumulate experimental data to test computational turbulence models. Mean velocity field measurements were carried out by using NMR-CT(Nuclear Magnetic Resonance-Computerized Tomography). It detects quantitative flow image of any desired section in any direction of flow in short time. Results show that at small Richardson number warm layer rapidly penetrates into the cold layer because of strong turbulent mixing and instability between the two layers. It is found that the transfer of heat across the interface is more vigorous than that of momentum. It is also proved that the NMR-CT technique is a very valuable tool to measure unsteady three dimensional flow field. (Author)

  9. Thermal studies on the weathering status of Lakhra coal

    International Nuclear Information System (INIS)

    Kumbher, M.; Vasandani, A.G.M.; Shah, S.W.

    2002-01-01

    Thermal studies about the weathering status of Lakhra coal were conducted using thermogravimetric (TG) and differential thermal analysis (DTA) in N/sub 2/ and air atmospheres. These studies were centered on the extent of the release of volatile matters and the determination of calorific values. The decline in these parameters, i.e. volatile matters and calorific values, cause a decline in the caking properties of coal and promote auto-ignition. The TG behavior of weathered samples in N/sub 2/ indicates a clear decline in percent moisture and volatile matters and abrupt burning of the fixed carbon. The TG curves further indicate quick decomposition of samples at various temperatures and auto-ignition with respect to time. The DTA behavior of the weathered samples in air, shows a significant difference in peak configuration, such as suppression of main endothermic peaks and shifting of shoulder peaks towards lower temperature. The N/sub 2/ atmosphere gives illusive and ill-defined events with respect to time. (author)

  10. French studies on the thermal effluents of electric power plants

    International Nuclear Information System (INIS)

    Dezes-Cadiere, H.

    1976-01-01

    This report presents a synthesis of studies made in France in the thermal effluent field: thermal power plant cooling systems, transfer and dispersion of thermal effluents in the receptive media, effects of thermal effluents on water physicochemistry and biochemistry, effects of thermal effluents on aquatic ecosystems, and, possibilities of waste heat recovery with the view of utilization in agriculture, aquaculture and district heating. A catalogue of French organizations working or having data on thermal effluents is presented, as also an alphabetical list of the contacted persons. A bibliography of French documents concerning the previously mentioned studies is finally given (193 refs.) [fr

  11. Restraint behavior of concrete under extreme thermal and hygral conditions

    International Nuclear Information System (INIS)

    Schwesinger, P.; Dommnich, F.

    1989-01-01

    Stresses due to temperature may be a considerable part of the whole loading of the structure especially in reactor vessels, chimneys and other structures. During using of this structures the heating cycle consisting of heating and cooling may be repeated for several times. On the other hand the initial load, the preloading time, the heating rate and the moisture of concrete can differ in respect of the design or utilization of the structure. The effect of this environmental factors on the restraint behavior of concrete is presented in this paper

  12. Study of Aquifer Thermal Energy Storage

    Science.gov (United States)

    Okuyama, Masaaki; Umemiya, Hiromichi; Shibuya, Ikuko; Haga, Eiji

    Yamagata University 'Aquifer Thermal Energy Storage (ATES)' is the experimental system which has been running since 1982. From the results for along terms of experiments, we obtain many important knowledge. This paper presents the accomplishments for 16 years and the characteristics of thermal energy storage in thermal energy storage well. The conclusions show as follows. 1)In recent years, the thermal recovery factor of warm energy storage well becomes almost constant at about 60%. 2) The thermal recovery factor of cool energy storage well increases gradually and becomes at about 15%. 3) Since the ferric colloidal dam is formed in aquifer, thermal recovery factor increase year after year. 4) Back wash can remove clogging for ferric colloidal dam. 5) The apparent thermal diffusivity decrease gradually due to ferric colloidal dam.

  13. Thermal stability and degradation behavior of novel wholly aromatic azo polyamide-hydrazides

    International Nuclear Information System (INIS)

    Al-Ghamdia, R.F.; Fahmib, M.M.; Mohamed, N.A.

    2005-01-01

    Thermal stability and degradation behavior of a series of novel wholly aromatic azo polyamide-hydrazides have been investigated in nitrogen and in air atmospheres using differential scanning ealorimetry, thermogravimetry, infrared spectroscopy and elemental analysis. The influences of controlled structural variations and molecular weight on the thermal stability and degradation behavior of this series of polymers have also been studied. The structural differences were achieved by varying the content of para- and meta substituted phenylene rings incorporated within this series. The polymers were prepared by a low temperature solution polycondensation reaction of p aminosalicylic acid hydrazide and an equimolar amount of 4,4-azo dibenzoyl chloride [4,4 ADBC] or 3,3-azo dibenzoyl chloride [3,3ADBC] or mixtures of various molar ratios of 4,4ADBC and 3,3ADBC in anhydrous N,N- dimethyl acetamide [DMAc] containing lithium chloride as a solvent at -10 degree C. The results clearly reveal that these polymers are characterized by high thermal stability. Their weight loss occurred in three distinctive steps. The first was small and assigned to the evaporation of absorbed moisture. The second was appreciable and was attributed to the cyclo dehydration reaction of the hydrazide groups into 1,3,4-oxadiazole rings by losing water, combined with elimination of azo groups by losing molecular nitrogen. This is not a true degradation but rather a thermo-chemical transformation reaction of the azo polyamide-hydrasdes into the corresponding polyamide-l,3,4-oxadiazoles. The third was relatively severe and sharp, particularly in air, and corresponded to the decomposition of the resulting polyamide-l, 3,4-oxadiazoles. In both degradation atmospheres, the improved resistance to high temperatures was always associated with increased content of para- phenylene moieties of the investigated polymer. Further, with exception of 160-200 degree C temperature range, where the lower molecular weight

  14. Oxidation behavior of Hf-modified platinum aluminide coatings during thermal cycling

    Directory of Open Access Journals (Sweden)

    Liya Ye

    2018-02-01

    Full Text Available Platinum aluminide coatings with different Hf contents were fabricated by using HfCl4. The oxidation kinetics and the rumpling behavior of oxide scale were investigated. After thermal cycling, the coating with 0.46 wt% Hf showed least weight gain. With the increase of Hf content, rumpling extent of the scale decreased. Meanwhile, HfO2 preferentially formed in the scale resulting in the increase of scale thickness. The oxidation of excessive Hf even caused the spallation of the scale. The results in the present study indicate that although Hf plays an important role in decreasing rumpling extent of TGO, the oxidation of Hf decreases the adhesion of the scale. Keywords: Pt-Al coating, Hf, Oxidation, Rumpling

  15. Description of the behavior of an aquifer by using continuous radon monitoring in a thermal spa

    International Nuclear Information System (INIS)

    Sainz, Carlos; Rábago, Daniel; Fuente, Ismael; Celaya, Santiago; Quindós, Luis Santiago

    2016-01-01

    Radon ( 222 Rn) levels in air and water have been analyzed continuously for almost a year in Las Caldas de Besaya thermal spa, north Spain. Radon is a naturally occurring noble gas from the decay of radium ( 226 Ra) both constituents of radioactive uranium 238 series. It has been recognized as a lung carcinogen by the World Health Organization (WHO) and International Agency for Research on Cancer (IARC). Furthermore the Royal Decree R.D 1439/2010 of November, 2010 establishes the obligation to study occupational activities where workers and, where appropriate, members of the public are exposed to inhalation of radon in workplaces such as spas. Together with radon measures several physico-chemical parameters were obtained such as pH, redox potential, electrical conductivity and air and water temperature. The devices used for the study of the temporal evolution of radon concentration have been the RTM 2100, the Radon Scout and gamma spectrometry was complementarily used to determine the transfer factor of the silicone tubes in the experimental device. Radon concentrations obtained in water and air of the spa are high, with an average of 660 Bq/l and 2900 Bq/m 3 respectively, where water is the main source of radon in the air. Radiation dose for workers and public was estimated from these levels of radon. The data showed that the thermal processes can control the behavior of radon which can be also influenced by various physical and chemical parameters such as pH and redox potential. - Highlights: • Radon in water is the major source of indoor air radon concentration in thermal facilities. • Radon in water has been used to characterize the origin of water used for treatments in a spa. • Preliminary dose assessment from radon exposure has been performed.

  16. Description of the behavior of an aquifer by using continuous radon monitoring in a thermal spa

    Energy Technology Data Exchange (ETDEWEB)

    Sainz, Carlos, E-mail: sainzc@unican.es; Rábago, Daniel; Fuente, Ismael; Celaya, Santiago; Quindós, Luis Santiago

    2016-02-01

    Radon ({sup 222}Rn) levels in air and water have been analyzed continuously for almost a year in Las Caldas de Besaya thermal spa, north Spain. Radon is a naturally occurring noble gas from the decay of radium ({sup 226}Ra) both constituents of radioactive uranium 238 series. It has been recognized as a lung carcinogen by the World Health Organization (WHO) and International Agency for Research on Cancer (IARC). Furthermore the Royal Decree R.D 1439/2010 of November, 2010 establishes the obligation to study occupational activities where workers and, where appropriate, members of the public are exposed to inhalation of radon in workplaces such as spas. Together with radon measures several physico-chemical parameters were obtained such as pH, redox potential, electrical conductivity and air and water temperature. The devices used for the study of the temporal evolution of radon concentration have been the RTM 2100, the Radon Scout and gamma spectrometry was complementarily used to determine the transfer factor of the silicone tubes in the experimental device. Radon concentrations obtained in water and air of the spa are high, with an average of 660 Bq/l and 2900 Bq/m{sup 3} respectively, where water is the main source of radon in the air. Radiation dose for workers and public was estimated from these levels of radon. The data showed that the thermal processes can control the behavior of radon which can be also influenced by various physical and chemical parameters such as pH and redox potential. - Highlights: • Radon in water is the major source of indoor air radon concentration in thermal facilities. • Radon in water has been used to characterize the origin of water used for treatments in a spa. • Preliminary dose assessment from radon exposure has been performed.

  17. Toward the Elucidation of the Competing Role of Evaporation and Thermal Decomposition in Ionic Liquids: A Multitechnique Study of the Vaporization Behavior of 1-Butyl-3-methylimidazolium Hexafluorophosphate under Effusion Conditions.

    Science.gov (United States)

    Volpe, V; Brunetti, B; Gigli, G; Lapi, A; Vecchio Ciprioti, S; Ciccioli, A

    2017-11-16

    The evaporation/decomposition behavior of the imidazolium ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate (BMImPF 6 ) was investigated in the overall temperature range 425-551 K by means of the molecular-effusion-based techniques Knudsen effusion mass loss (KEML) and Knudsen effusion mass spectrometry (KEMS), using effusion orifices of different size (from 0.2 to 3 mm in diameter). Specific effusion fluxes measured by KEML were found to depend markedly on the orifice size, suggesting the occurrence of a kinetically delayed evaporation/decomposition process. KEMS experiments revealed that other species are present in the vapor phase besides the intact ion pair BMImPF 6 (g) produced by the simple evaporation BMImPF 6 (l) = BMImPF 6 (g), with relative abundances depending on the orifice size-the larger the orifice, the larger the contribution of the BMImPF 6 (g) species. By combining KEML and KEMS results, the conclusion is drawn that in the investigated temperature range, when small effusion orifices are used, a significant part of the mass loss/volatility of BMImPF 6 is due to molecular products formed by decomposition/dissociation processes rather than to evaporated intact ion pairs. Additional experiments performed by nonisothermal thermogravimetry-differential thermal analysis (TG-DTA) further support the evidence of simultaneous evaporation/decomposition, although the conventional decomposition temperature derived from TG curves is much higher than the temperatures covered in effusion experiments. Partial pressures of the BMImPF 6 (g) species were derived from KEMS spectra and analyzed by second- and third-law methods giving a value of Δ evap H 298K ° = 145.3 ± 2.9 kJ·mol -1 for the standard evaporation enthalpy of BMImPF 6 . A comparison is done with the behavior of the 1-butyl-3-methylimidazolium bis(trifluoromethyl)sulfonylimide (BMImNTf 2 ) ionic liquid.

  18. Thermal behavior of human eye in relation with change in blood perfusion, porosity, evaporation and ambient temperature.

    Science.gov (United States)

    Rafiq, Aasma; Khanday, M A

    2016-12-01

    Extreme environmental and physiological conditions present challenges for thermal processes in body tissues including multi-layered human eye. A mathematical model has been formulated in this direction to study the thermal behavior of the human eye in relation with the change in blood perfusion, porosity, evaporation and environmental temperatures. In this study, a comprehensive thermal analysis has been performed on the multi-layered eye using Pennes' bio-heat equation with appropriate boundary and interface conditions. The variational finite element method and MATLAB software were used for the solution purpose and simulation of the results. The thermoregulatory effect due to blood perfusion rate, porosity, ambient temperature and evaporation at various regions of human eye was illustrated mathematically and graphically. The main applications of this model are associated with the medical sciences while performing laser therapy and other thermoregulatory investigation on human eye. Copyright © 2016 Elsevier Ltd. All rights reserved.

  19. Loss-of-Fluid Test findings in pressurized water reactor core's thermal-hydraulic behavior

    International Nuclear Information System (INIS)

    Russell, M.

    1983-01-01

    This paper summarizes the pressurized water reactor (PWR) core's thermal-hydraulic behavior findings from experiments performed at the Loss-of-Fluid Test (LOFT) Facility at the Idaho National Engineering Laboratory. The potential impact of these findings on the safety and economics of PWR's generation of electricity is also discussed. Reviews of eight important findings in the core's physical behavior and in experimental methods are presented with supporting evidence

  20. Thermal evolution behavior of carbides and γ′ precipitates in FGH96 superalloy powder

    International Nuclear Information System (INIS)

    Zhang Lin; Liu Hengsan; He Xinbo; Rafi-ud-din; Qu Xuanhui; Qin Mingli; Li Zhou; Zhang Guoqing

    2012-01-01

    The characteristics of rapidly solidified FGH96 superalloy powder and the thermal evolution behavior of carbides and γ′ precipitates within powder particles were investigated. It was observed that the reduction of powder size and the increase of cooling rate had transformed the solidification morphologies of atomized powder from dendrite in major to cellular structure. The secondary dendritic spacing was measured to be 1.02–2.55 μm and the corresponding cooling rates were estimated to be in the range of 1.4 × 10 4 –4.7 × 10 5 K·s −1 . An increase in the annealing temperature had rendered the phase transformation of carbides evolving from non-equilibrium MC′ carbides to intermediate transition stage of M 23 C 6 carbides, and finally to thermodynamically stable MC carbides. The superfine γ′ precipitates were formed at the dendritic boundaries of rapidly solidified superalloy powder. The coalescence, growth, and homogenization of γ' precipitates occurred with increasing annealing temperature. With decreasing cooling rate from 650 °C·K −1 to 5 °C·K −1 , the morphological development of γ′ precipitates had been shown to proceed from spheroidal to cuboidal and finally to solid state dendrites. Meanwhile, a shift had been observed from dendritic morphology to recrystallized structure between 900 °C and 1050 °C. Moreover, accelerated evolution of carbides and γ' precipitates had been facilitated by the formation of new grain boundaries which provide fast diffusion path for atomic elements. - Highlights: ► Microstructural characteristic of FGH96 superalloy powder was investigated. ► The relation between microstructure, particle size, and cooling rate was studied. ► Thermal evolution behavior of γ′ and carbides in loose FGH96 powder was studied.

  1. Thermal behavior of hazardous and radioactive metals under incineration conditions

    International Nuclear Information System (INIS)

    Seo, Y.C.; Kang, K.H.; Yang, H.C.; Park, H.H.

    1993-01-01

    The behavior of heavy metals and their effects on air pollution at temperatures up to 900 C under incineration conditions were observed. Pure metals and their oxide compounds, except arsenic, were very stable in the tested range of temperatures. However, the chlorides of some metals were evaporated or decomposed to result in gas emission to the environment at lower temperatures, while other chloride compounds were converted into their stable oxide forms. Evaporation of such compounds were analyzed using an equation of maximum evaporation flux based on the kinetic theory with a fitted parameter, α, the fraction of impinging gas molecules to the condensing surface. Values of α, were obtained in the range of 10 -6 to 10 -9 . Such volatile metal compounds and arsenic must be carefully controlled

  2. Effect of Layer-Graded Bond Coats on Edge Stress Concentration and Oxidation Behavior of Thermal Barrier Coatings

    Science.gov (United States)

    Zhu, Dongming; Ghosn, Louis J.; Miller, Robert A.

    1998-01-01

    Thermal barrier coating (TBC) durability is closely related to design, processing and microstructure of the coating Z, tn systems. Two important issues that must be considered during the design of a thermal barrier coating are thermal expansion and modulus mismatch between the substrate and the ceramic layer, and substrate oxidation. In many cases, both of these issues may be best addressed through the selection of an appropriate bond coat system. In this study, a low thermal expansion and layer-graded bond coat system, that consists of plasma-sprayed FeCoNiCrAl and FeCrAlY coatings, and a high velocity oxyfuel (HVOF) sprayed FeCrAlY coating, is developed to minimize the thermal stresses and provide oxidation resistance. The thermal expansion and oxidation behavior of the coating system are also characterized, and the strain isolation effect of the bond coat system is analyzed using the finite element method (FEM). Experiments and finite element results show that the layer-graded bond coat system possesses lower interfacial stresses. better strain isolation and excellent oxidation resistance. thus significantly improving the coating performance and durability.

  3. Thermal properties and Ising critical behavior in EuFe{sub 2}As{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Oleaga, A., E-mail: alberto.oleaga@ehu.es [Departamento de Física Aplicada I, Escuela Técnica Superior de Ingeniería, Universidad del País Vasco UPV/EHU, Alameda Urquijo s/n, 48013 Bilbao (Spain); Salazar, A. [Departamento de Física Aplicada I, Escuela Técnica Superior de Ingeniería, Universidad del País Vasco UPV/EHU, Alameda Urquijo s/n, 48013 Bilbao (Spain); Thamizhavel, A.; Dhar, S.K. [Department of Condensed Matter Physics and Material Sciences, Tata Institute of Fundamental Research, Homi Bhabha Road, Colaba, Mumbai 400 005 (India)

    2014-12-25

    Highlights: • A high resolution ac photopyroelectric calorimeter is used. • Thermal diffusivity and specific heat are measured at the phase transitions. • Latent heat is exchanged at the Fe{sup 2+} spin-ordering transition. • Eu{sup 2+} spin-ordering transition belongs to the 3D-Ising universality class. - Abstract: Specific heat and thermal diffusivity have been studied by means of a high resolution ac photopyroelectric calorimeter in the vicinity of phase transitions in EuFe{sub 2}As{sub 2}: the first one corresponding to the ordering of the Fe{sup 2+} spins concomitant to a structural transition at 188.1 K and the second one to the antiferromagnetic ordering of the Eu{sup 2+} spins at 18.4 K. The weak first order character of the first transition has been confirmed while the critical behavior of the second transition at lower temperature has been established to correspond to the 3D-Ising universality class (α{sub exp} = 0.11 ± 0.03). This is in agreement with the proposed uniaxial arrangement of the Eu{sup 2+} spins lying along the long orthorhombic axis a as reported in literature.

  4. Study on neutron irradiation behavior of beryllium as neutron multiplier

    Energy Technology Data Exchange (ETDEWEB)

    Ishitsuka, Etsuo [Japan Atomic Energy Research Inst., Oarai, Ibaraki (Japan). Oarai Research Establishment

    1998-03-01

    More than 300 tons beryllium is expected to be used as a neutron multiplier in ITER, and study on the neutron irradiation behavior of beryllium as the neutron multiplier with Japan Materials Testing Reactor (JMTR) were performed to get the engineering data for fusion blanket design. This study started as the study on the tritium behavior in beryllium neutron reflector in order to make clear the generation mechanism on tritium of JMTR primary coolant since 1985. These experiences were handed over to beryllium studies for fusion study, and overall studies such as production technology of beryllium pebbles, irradiation behavior evaluation and reprocessing technology have been started since 1990. In this presentation, study on the neutron irradiation behavior of beryllium as the neutron multiplier with JMTR was reviewed from the point of tritium release, thermal properties, mechanical properties and reprocessing technology. (author)

  5. Thermal behavior of aerosol particles from biomass burning during the BBOP campaign using transmission electron microscopy

    Science.gov (United States)

    Adachi, K.; Ishimoto, H.; Sedlacek, A. J., III; Kleinman, L. I.; Chand, D.; Hubbe, J. M.; Buseck, P. R.

    2017-12-01

    Aerosol samples were collected from wildland and agricultural biomass fires in North America during the 2013 Biomass Burning Observation Project (BBOP). We show in-situ shape and size changes and variations in the compositions of individual particles before and after heating using a transmission electron microscope (TEM). The responses of aerosol particles to heating are important for measurements of their chemical, physical, and optical properties, classification, and determination of origin. However, the thermal behavior of organic aerosol particles is largely unknown. We provide a method to analyze such thermal behavior through heating from room temperature to >600°C by using a heating holder within TEM. The results indicate that individual tar balls (TB; spherical organic material) from biomass burning retained, on average, up to 30% of their volume when heated to 600°C. Chemical analysis reveals that K and Na remained in the residues, whereas S and O were lost. In contrast to bulk sample measurements of carbonaceous particles using thermal/optical carbon analyzers, our single-particle results imply that many individual organic particles consist of multiple types of organic matter having different thermal stabilities. Our results also suggest that because of their thermal stability, some organic particles may not be detectable by using aerosol mass spectrometry or thermal/optical carbon analyzers. This result can lead to an underestimate of the abundance of TBs and other organic particles, and therefore biomass burning may have a greater influence than is currently recognized in regional and global climate models.

  6. Estimation of apparent kinetic parameters of polymer pyrolysis with complex thermal degradation behavior

    International Nuclear Information System (INIS)

    Srimachai, Taranee; Anantawaraskul, Siripon

    2010-01-01

    Full text: Thermal degradation behavior during polymer pyrolysis can typically be described using three apparent kinetic parameters (i.e., pre-exponential factor, activation energy, and reaction order). Several efficient techniques have been developed to estimate these apparent kinetic parameters for simple thermal degradation behavior (i.e., single apparent pyrolysis reaction). Unfortunately, these techniques cannot be directly extended to the case of polymer pyrolysis with complex thermal degradation behavior (i.e., multiple concurrent reactions forming single or multiple DTG peaks). In this work, we proposed a deconvolution method to determine the number of apparent reactions and estimate three apparent kinetic parameters and contribution of each reaction for polymer pyrolysis with complex thermal degradation behavior. The proposed technique was validated with the model and experimental pyrolysis data of several polymer blends with known compositions. The results showed that (1) the number of reaction and (2) three apparent kinetic parameters and contribution of each reaction can be estimated reasonably. The simulated DTG curves with estimated parameters also agree well with experimental DTG curves. (author)

  7. Investigation of Thermal Behavior for Natural Fibres Reinforced Epoxy using Thermogravimetric and Differential Scanning Calorimetric Analysis

    Directory of Open Access Journals (Sweden)

    Fauzi F.A.

    2016-01-01

    Full Text Available This paper presented the research works on the investigation of the thermal behavior of the natural fibres; i.e. pineapple leaf fibre, kenaf fibre and mengkuang fibres reinforced epoxy. The thermogravimetric analysis and differential scanning calorimetric analysis were used to measure the thermal behavior of the treated and untreated pineapple, kenaf and mengkuang fibres reinforced epoxy. The samples for both analysis were subjected to maximum temperature 600°C at the heating rate of 10°C/min. The results showed that the treated fibres show higher maximum peak temperature as compared to the untreated fibres. Additionally, the glass transition temperature showed a lower value for all treated fibre. It can be concluded that investigation of thermal properties of these natural fibres could improve the utilization of natural fibre composites in various applications i.e. sports applications.

  8. Thermal behavior of poly(2-hydroxyethyl methacrylate-bis-[trimethoxysilylpropyl]amine) networks

    International Nuclear Information System (INIS)

    Bustos Figueroa, L A; Salgado Delgado, R; García Hernandez, E; Vargas Galarza, Z; Rubio Rosas, E; Salgado Rodriguez, R

    2013-01-01

    Poly(HEMA-BisSi) networks were prepared by using acid-catalyzed sol-gel of bis-[trimethoxysilylpropyl]amine (BisSi) and free radical polymerization of 2-hydroxyethyl methacrylate (HEMA). The thermal properties of the poly(HEMA-BisSi) networks were investigated with differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The thermal behavior of these networks was also compared with homopolymers (The networks formed in both PHEMA and PBisSi gels were identified). The glass transition temperature (T g ) of PHEMA homopolymer was found as 103.74 °C. The thermal degradation of the poly(HEMA-BisSi) networks with different silica contents (e.g. 10, 15 and 25 wt%) were evaluated with use of DTG. It was observed that the thermal degradation temperature of poly(HEMA-BisSi) networks changed much with the BisSi content.

  9. Heavy metals behavior during thermal plasma vitrification of incineration residues

    International Nuclear Information System (INIS)

    Cerqueira, N.; Vandensteendam, C.; Baronnet, J.M.

    2005-01-01

    In the developed world, incineration of wastes is widely and increasingly practiced. Worldwide, a total of approximately 100 millions of tons of municipal solid waste (MSW) material is incinerated annually. Incineration of one ton of MSW leads to the formation of 30 to 50 kg of fly ash, depending on the type of incinerator. The waste disposal of these dusts already causes great problems today; they are of low bulk density, they contain high concentrations of hazardous water-soluble heavy metal compounds, organohalogen compounds (dioxines, furanes), sulfur, and chlorinated compounds. Thermal processes, based mainly on electrical arc processes, show great promise: the residues are melted at high temperature and converted in a relatively inert glass. A few tens of plants, essentially in Japan and Taiwan, have been in industrial operation for a few years. To be authorized to be dumped in a common landfill, the glassy product has to satisfy the leaching test procedure to ensure long-term durability. But to satisfy the regulation to be reused, for example as a nonhazardous standard material in road building, the glassy product would probably include contents in some heavy metals lower than critical limits. So today, there are two alternatives: the first one is to improve the heavy toxic metals evaporation to get a 'light' glassy product and to recycle separately the said separated metals; the second is on the contrary to improve the incorporation of a maximum of heavy metals into the vitreous silicate matrix. Whatever, it is highly required to control, in situ and in real time, volatility of these metals during ash melting under electrical arc. The objective of this work was to reach basic data about metals volatility under the plasma column of an electrical arc transferred on the melt: an experiment has been designed to examine the effects of processing conditions, such as melt temperature, melt composition, and furnace atmosphere, upon volatilization and glassy slag

  10. Thermal analysis studies of ammonium uranyl carbonate

    International Nuclear Information System (INIS)

    Cao Xinsheng; Ma Xuezhong; Wang Fapin; Liu Naixin; Ji Changhong

    1988-01-01

    The simultaneous thermogravimetry and differential thermal analysis of the ammonium uranyl carbonate powder were performed with heat balance in the following atmosphers: Air, Ar and Ar-8%H 2 . The thermogravimetry and differential thermal analysis curves of the ammonium uranyl carbonate powder obtained from different source were reported and discussed

  11. Thermal-hydraulic behavior on break simulation of steam generator U-tube

    International Nuclear Information System (INIS)

    Seul, Kwang Won; Bang, Young Seok; Lee, Sukho; Kim, Hho Jung

    1995-01-01

    The thermal-hydraulic behavior depending on the break simulation in a steam generator U-tube was investigated and identified the code predictability on plant responses during SGTR accident. The calculated results were compared and assessed with LSTF SB-SG-06 test data. The RELAP5/MOD3.1 code well predicted the sequence of events and the significant phenomena, such as the asymmetric loop behavior, the RCS cooldown and heat transfer by the natural circulation, and system depressurization, even though there were some differences from the experimental data. The break flowrate was found to be sensitive to the break model and affected the system behavior

  12. Influence of agronomic variables on the macronutrient and micronutrient contents and thermal behavior of mate tea leaves (Ilex paraguariensis).

    Science.gov (United States)

    Jacques, Rosângela A; Arruda, Eduardo J; de Oliveira, Lincoln C S; de Oliveira, Ana P; Dariva, Cláudio; de Oliveira, J Vladimir; Caramão, Elina B

    2007-09-05

    The influence of agronomic variables (light intensity, age of leaves, and fertilization type) on the content of macronutrients and micronutrients (potassium, calcium, sodium, magnesium, manganese, iron, zinc, and copper) of tea leaves was assessed by acid digestion, followed by flame atomic absorption spectrometry (FAAS). The thermal behavior of mate tea leaves (Ilex paraguariensis) was also studied in this work. Samples of mate (Ilex paraguariensis) were collected in an experiment conducted under agronomic control at Erva-Mate Barão Commerce and Industry LTD (Brazil). The results showed that the mineral content in mate is affected by the agronomic variables investigated. In general, the content of mineral compounds analyzed is higher for younger leaves and for plants cultivated in shadow. Thermal analysis of samples indicated a similar behavior, with three typical steps of decomposition: loss of water, degradation of low-molecular weight compounds, and degradation of residual materials.

  13. Experimental data showing the thermal behavior of a flat roof with phase change material.

    Science.gov (United States)

    Tokuç, Ayça; Başaran, Tahsin; Yesügey, S Cengiz

    2015-12-01

    The selection and configuration of building materials for optimal energy efficiency in a building require some assumptions and models for the thermal behavior of the utilized materials. Although the models for many materials can be considered acceptable for simulation and calculation purposes, the work for modeling the real time behavior of phase change materials is still under development. The data given in this article shows the thermal behavior of a flat roof element with a phase change material (PCM) layer. The temperature and energy given to and taken from the building element are reported. In addition the solid-liquid behavior of the PCM is tracked through images. The resulting thermal behavior of the phase change material is discussed and simulated in [1] A. Tokuç, T. Başaran, S.C. Yesügey, An experimental and numerical investigation on the use of phase change materials in building elements: the case of a flat roof in Istanbul, Build. Energy, vol. 102, 2015, pp. 91-104.

  14. Experimental data showing the thermal behavior of a flat roof with phase change material

    Directory of Open Access Journals (Sweden)

    Ayça Tokuç

    2015-12-01

    Full Text Available The selection and configuration of building materials for optimal energy efficiency in a building require some assumptions and models for the thermal behavior of the utilized materials. Although the models for many materials can be considered acceptable for simulation and calculation purposes, the work for modeling the real time behavior of phase change materials is still under development. The data given in this article shows the thermal behavior of a flat roof element with a phase change material (PCM layer. The temperature and energy given to and taken from the building element are reported. In addition the solid–liquid behavior of the PCM is tracked through images. The resulting thermal behavior of the phase change material is discussed and simulated in [1] A. Tokuç, T. Başaran, S.C. Yesügey, An experimental and numerical investigation on the use of phase change materials in building elements: the case of a flat roof in Istanbul, Build. Energy, vol. 102, 2015, pp. 91–104.

  15. Studies of ion implanted thermally oxidised chromium

    International Nuclear Information System (INIS)

    Muhl, S.

    1977-01-01

    The thermal oxidation of 99.99% pure chromium containing precise amounts of foreign elements has been studied and compared to the oxidation of pure chromium. Thirty-three foreign elements including all of the naturally occurring rare earth metals were ion implanted into chromium samples prior to oxidation at 750 0 C in oxygen. The role of radiation induced damage, inherent in this doping technique, has been studied by chromium implantations at various energies and doses. The repair of the damage has been studied by vacuum annealing at temperatures up to 800 0 C prior to oxidation. Many of the implants caused an inhibition of oxidation, the greatest being a 93% reduction for 2 x 10 16 ions/cm 2 of praseodymium. The distribution of the implant was investigated by the use of 2 MeV alpha backscattering and ion microprobe analysis. Differences in the topography and structure of the chromic oxide on and off the implanted area were studied using scanning electron and optical microscopy. X-ray diffraction analysis was used to investigate if a rare earth-chromium compound of a perovskite-type structure had been formed. Lastly, the electrical conductivity of chromic oxide on and off the implanted region was examined at low voltages. (author)

  16. Using thermal and spectroscopic data to investigate the thermal behavior of epinephrine

    Energy Technology Data Exchange (ETDEWEB)

    Bannach, Gilbert; Cervini, Priscila [Instituto de Quimica de Sao Carlos - IQSC/USP, C.P. 780, CEP 13560-970, Sao Carlos, SP (Brazil); Cavalheiro, Eder Tadeu Gomes, E-mail: cavalheiro@iqsc.usp.br [Instituto de Quimica de Sao Carlos - IQSC/USP, C.P. 780, CEP 13560-970, Sao Carlos, SP (Brazil); Ionashiro, Massao [Instituto de Quimica, UNESP, C.P. 355, CEP 14801-970, Araraquara, SP (Brazil)

    2010-02-20

    Epinephrine is a neurotransmitter of the catecholamine class that acts in the mammalian central nervous system. The TG-DTA curves of epinephrine showed that the anhydrous compound starts decomposition at 165 {sup o}C, under the conditions used in this work. The reflectance FTIR spectra and X-ray powder diffraction patterns of epinephrine before and after heating up to 210 {sup o}C, as well as the TG-FTIR spectra of sample heated between 30 and 600 {sup o}C, were obtained and reveled that after heating, structural changes occurred in the sample. At temperatures higher than 205 {sup o}C the thermal decomposition took place with elimination of methylamine in agreement with the first mass loss observed in the TG curve in both air and N{sub 2} atmospheres (TG = 17.0%, calcd. = 17.0%). The melting was observed at 205 {sup o}C (DTA) or 203 {sup o}C (DSC) but this process occurred overlapped with decomposition characteristic of an incongruent melting process.

  17. Thermal-hydraulic behaviors of vapor-liquid interface due to arrival of a pressure wave

    Energy Technology Data Exchange (ETDEWEB)

    Inoue, Akira; Fujii, Yoshifumi; Matsuzaki, Mitsuo [Tokyo Institute of Technology (Japan)

    1995-09-01

    In the vapor explosion, a pressure wave (shock wave) plays a fundamental role for triggering, propagation and enhancement of the explosion. Energy of the explosion is related to the magnitude of heat transfer rate from hot liquid to cold volatile one. This is related to an increasing rate of interface area and to an amount of transient heat flux between the liquids. In this study, the characteristics of transient heat transfer and behaviors of vapor film both on the platinum tube and on the hot melt tin drop, under same boundary conditions have been investigated. It is considered that there exists a fundamental mechanism of the explosion in the initial expansion process of the hot liquid drop immediately after arrival of pressure wave. The growth rate of the vapor film is much faster on the hot liquid than that on the solid surface. Two kinds of roughness were observed, one due to the Taylor instability, by rapid growth of the explosion bubble, and another, nucleation sites were observed at the vapor-liquid interface. Based on detailed observation of early stage interface behaviors after arrival of a pressure wave, the thermal fragmentation mechanism is proposed.

  18. Thermal Stress Awareness, Self-Study #18649

    Energy Technology Data Exchange (ETDEWEB)

    Chochoms, Michael [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-11-15

    Thermal stresses can expose individuals to a variety of health hazards at work, home, and play. Every year thermal stresses cause severe injuries and death to a large range of people, from elderly people in cities during summer heat waves to young people engaged in winter mountaineering. Awareness is the key to preventing the health hazards associated with thermal stresses. This course is designed for personnel at Los Alamos National Laboratory (LANL). It addresses both heat and cold stresses and discusses their factors, signs and symptoms, treatments, and controls.

  19. Thermal behavior of an experimental 2.5-kWh lithium/iron sulfide battery

    Science.gov (United States)

    Chen, C. C.; Olszanski, T. W.; Gibbard, H. F.

    1981-10-01

    The thermal energy generation and the gross thermal energy balance in the battery systems was studied. High temperature lithium/iron sulfide batteries for electric vehicle applications were developed. The preferred battery temperature range during operation and idle periods is 400 to 500 C. Thermal management is an essential part of battery design, the battery requires a thermal insulation vessel to minimize heat loss and heating and cooling systems to control temperature. Results of temperature measurements performed on a 2.5-kWh battery module, which was built to gain information for the design of larger systems are reported.

  20. Thermal Conductivity and Wear Behavior of HVOF-Sprayed Fe-Based Amorphous Coatings

    Directory of Open Access Journals (Sweden)

    Haihua Yao

    2017-10-01

    Full Text Available To protect aluminum parts in vehicle engines, metal-based thermal barrier coatings in the form of Fe59Cr12Nb5B20Si4 amorphous coatings were prepared by high velocity oxygen fuel (HVOF spraying under two different conditions. The microstructure, thermal transport behavior, and wear behavior of the coatings were characterized simultaneously. As a result, this alloy shows high process robustness during spraying. Both Fe-based coatings present dense, layered structure with porosities below 0.9%. Due to higher amorphous phase content, the coating H-1 exhibits a relatively low thermal conductivity, reaching 2.66 W/(m·K, two times lower than the reference stainless steel coating (5.85 W/(m·K, indicating a good thermal barrier property. Meanwhile, the thermal diffusivity of amorphous coatings display a limited increase with temperature up to 500 °C, which guarantees a steady and wide usage on aluminum alloy. Furthermore, the amorphous coating shows better wear resistance compared to high carbon martensitic GCr15 steel at different temperatures. The increased temperature accelerating the tribological reaction, leads to the friction coefficient and wear rate of coating increasing at 200 °C and decreasing at 400 °C.

  1. Cracking behavior of thermally aged and irradiated CF-8 cast austenitic stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Y., E-mail: Yiren_Chen@anl.gov [Argonne National Laboratory, 9700 S. Cass Ave, Argonne, IL 60439 (United States); Alexandreanu, B.; Chen, W.-Y.; Natesan, K. [Argonne National Laboratory, 9700 S. Cass Ave, Argonne, IL 60439 (United States); Li, Z.; Yang, Y. [University of Florida, Gainesville, FL 32611 (United States); Rao, A.S. [US Nuclear Regulatory Commission, 11545 Rockville Pike, Rockville, MD 20852 (United States)

    2015-11-15

    To assess the combined effect of thermal aging and neutron irradiation on the cracking behavior of CF-8 cast austenitic stainless steel, crack growth rate (CGR) and fracture toughness J-R curve tests were carried out on compact-tension specimens in high-purity water with low dissolved oxygen. Both unaged and thermally aged specimens were irradiated at ∼320 °C to 0.08 dpa. Thermal aging at 400 °C for 10,000 h apparently had no effect on the corrosion fatigue and stress corrosion cracking behavior in the test environment. The cracking susceptibility of CF-8 was not elevated significantly by neutron irradiation at 0.08 dpa. Transgranular cleavage-like cracking was the main fracture mode during the CGR tests, and a brittle morphology of delta ferrite was often seen on the fracture surfaces at the end of CGR tests. The fracture toughness J-R curve tests showed that both thermal aging and neutron irradiation can induce significant embrittlement. The loss of fracture toughness due to neutron irradiation was more pronounced in the unaged than aged specimens. After neutron irradiation, the fracture toughness values of the unaged and aged specimens were reduced to a similar level. G-phase precipitates were observed in the aged and irradiated specimens with or without prior aging. The similar microstructural changes resulting from thermal aging and irradiation suggest a common microstructural mechanism of inducing embrittlement in CF-8.

  2. Passenger thermal comfort and behavior: a field investigation in commercial aircraft cabins.

    Science.gov (United States)

    Cui, W; Wu, T; Ouyang, Q; Zhu, Y

    2017-01-01

    Passengers' behavioral adjustments warrant greater attention in thermal comfort research in aircraft cabins. Thus, a field investigation on 10 commercial aircrafts was conducted. Environment measurements were made and a questionnaire survey was performed. In the questionnaire, passengers were asked to evaluate their thermal comfort and record their adjustments regarding the usage of blankets and ventilation nozzles. The results indicate that behavioral adjustments in the cabin and the use of blankets or nozzle adjustments were employed by 2/3 of the passengers. However, the thermal comfort evaluations by these passengers were not as good as the evaluations by passengers who did not perform any adjustments. Possible causes such as differences in metabolic rate, clothing insulation and radiation asymmetry are discussed. The individual difference seems to be the most probable contributor, suggesting possibly that passengers who made adjustments had a narrower acceptance threshold or a higher expectancy regarding the cabin environment. Local thermal comfort was closely related to the adjustments and significantly influenced overall thermal comfort. Frequent flying was associated with lower ratings for the cabin environment. © 2016 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

  3. Swelling behavior of several bituminous coals and their thermally treated coals

    Energy Technology Data Exchange (ETDEWEB)

    Shui, Heng-fu; Cao, Mei-xia; Wang, Zhi-cai [Anhui University of Technology, Maanshan (China). School of Chemistry & Chemical Engineering

    2007-07-01

    The swelling behavior in different solvents of 4 bituminous coals with different ranks and their residues from extraction by CS{sub 2}/NMP mixed solvent (l:1 in volume) were measured. The change in swelling property of the four coals thermally treated at different temperature was observed. The results show that the swelling ratio decreases with increasing rank of coal. For lower rank bituminous coals the swelling ratios in polar solvent are higher than those in non-polar solvent, and this difference decreases with increasing rank. The cross-linking densities of the four residues decrease, and the swelling ratios increase compared with those of raw coals. The swelling ratios of the four thermally treated coals under 150{sup o}C in CS{sub 2} increase, suggesting the decrease in crosslinking density of them. When the thermal treatment temperature increases to 240{sup o}C, the swelling rations of the other three coals in NMP and CS{sub 2} increase again except gas coal, demonstrating the further decrease in crosslinking density. This result is coincident with the extraction yield change in the mixed solvent of the thermally treated coal. For example, the extraction yield of lean coal treated at 240{sup o}C increases from 6.9% to 17.3%. FT-IR results show the removal of oxygen group of the thermally treated coals. This may explain the increase in swelling ratio and extraction yield in the mixed solvent of coal after thermal treatment. The cross-linking density of the thermally treated coal decreases because of the break of hydrogen bonds due to removal of C = 0 and -OH oxygen groups during the thermal treatment, resulting in the increases of swelling ratio and extraction yield in the mixed solvent of thermally treated coal compared with those of raw coal. 15 refs., 3 figs., 6 tabs.

  4. Electro Thermal Chemical Gun Technology Study

    National Research Council Canada - National Science Library

    Diamond, P

    1999-01-01

    .... Michael Stroscio. Electro Thermal Chemical (ETC) gun technology refers to the use of plasma devices in place of traditional chemical ignitors to initiate the burning of high energy propellants in a controlled manner...

  5. Cure Behavior and Thermal Properties of Diepoxidized Cardanol Resin Cured by Electron Beam Process

    International Nuclear Information System (INIS)

    Cho, Donghwan; Cheon, Jinsil

    2013-01-01

    Thermal curing of epoxy resin requires high temperature, time-consuming process and the volatilization of hardener. It has known that electron beam curing of epoxy resin is a fast process and occurs at low or room temperature that help reduce residual mechanical stresses in thermosetting polymers. Diepoxidized cardanol (DEC) can be synthesized by an enzymatic method from cashew nut shell liquid (CNSL), that constitutes nearly one-third of the total nut weight. A large amount of CNSL can be formed as a byproduct of the mechanical processes used to render the cashew kerneledible and its total production approaches one million tons annually, which can be bio-degradable and replace the industrial thermosetting plastics. It is expected that DEC may be cured as in an epoxy resin, which was constituted on two epoxide group and long alkyl chain, and two-types of onium salts (cationic initiator) were used as a photo-initiator. The experimental variables of this study are type and concentration of photo-initiators and electron beam dosage. In this study, the effects of initiator type and concentration on the cure behavior and the thermal properties of DEC resin processed by using electron beam technology were studied using FT-IR, TGA, TMA, DSC, and DMA. Figure 1 is the FT-IR results, showing the change of chemical structure of pure DEC and electron beam cured DEC. The characteristic absorption peak of epoxide group appeared at 850cm -1 . The shape and the height were reduced when the sample was irradiated with electron beam. From this result, the epoxide groups is DEC were opened by electron beam and cured. After then, electron beam cured DEC was investigated the effect of forming 3-dimensional network

  6. Cure Behavior and Thermal Properties of Diepoxidized Cardanol Resin Cured by Electron Beam Process

    Energy Technology Data Exchange (ETDEWEB)

    Cho, Donghwan; Cheon, Jinsil [Kumoh National Institute of Technology, Gumi (Korea, Republic of)

    2013-07-01

    Thermal curing of epoxy resin requires high temperature, time-consuming process and the volatilization of hardener. It has known that electron beam curing of epoxy resin is a fast process and occurs at low or room temperature that help reduce residual mechanical stresses in thermosetting polymers. Diepoxidized cardanol (DEC) can be synthesized by an enzymatic method from cashew nut shell liquid (CNSL), that constitutes nearly one-third of the total nut weight. A large amount of CNSL can be formed as a byproduct of the mechanical processes used to render the cashew kerneledible and its total production approaches one million tons annually, which can be bio-degradable and replace the industrial thermosetting plastics. It is expected that DEC may be cured as in an epoxy resin, which was constituted on two epoxide group and long alkyl chain, and two-types of onium salts (cationic initiator) were used as a photo-initiator. The experimental variables of this study are type and concentration of photo-initiators and electron beam dosage. In this study, the effects of initiator type and concentration on the cure behavior and the thermal properties of DEC resin processed by using electron beam technology were studied using FT-IR, TGA, TMA, DSC, and DMA. Figure 1 is the FT-IR results, showing the change of chemical structure of pure DEC and electron beam cured DEC. The characteristic absorption peak of epoxide group appeared at 850cm{sup -1}. The shape and the height were reduced when the sample was irradiated with electron beam. From this result, the epoxide groups is DEC were opened by electron beam and cured. After then, electron beam cured DEC was investigated the effect of forming 3-dimensional network.

  7. Instrument for Study of Microbial Thermal Inactivation

    Science.gov (United States)

    Dickerson, R. W.; Read, R. B.

    1968-01-01

    An instrument was designed for the study of thermal inactivation of microorganisms using heating times of less than 1 sec. The instrument operates on the principle of rapid automatic displacement of the microorganism to and from a saturated steam atmosphere, and the operating temperature range is 50 to 90 C. At a temperature of 70 C, thermometric lag (time required to respond to 63.2% of a step change) of the fluid sample containing microorganisms was 0.12 sec. Heating time required to heat the sample to within 0.1 C of the exposure temperature was less than 1 sec, permitting exposure periods as brief as 1 sec, provided the proper corrections are made for the lethal effect of heating. The instrument is most useful for heat exposure periods of less than 5 min, and, typically, more than 500 samples can be processed for microbial inactivation determinations within an 8-hr period. Images Fig. 2 Fig. 3 Fig. 4 Fig. 5 Fig. 7 Fig. 8 PMID:4874466

  8. Curing behavior and thermal properties of trifunctional epoxy resin cured by 4, 4’-diaminodiphenyl sulfone

    Directory of Open Access Journals (Sweden)

    2009-08-01

    Full Text Available A novel trifunctional epoxy resin 4-(3, 3-dihydro-7-hydroxy-2, 4, 4-trimethyl-2H-1-benzopyran-2-yl-1, 3-benzenediol glycidyl (shorted as TMBPBTH-EPOXY was synthesized in our lab to improve thermal performance. Its curing behavior and performance were studied by using 4, 4′-diaminodiphenyl sulfone (DDS as hardener with the mass ratio of 100:41 of TMBPBTH-EPOXY and DDS. The curing activation energy was investigated by differential scanning calorimetry (DSC to be 64.0 kJ/mol estimated by Kissinger’s method and 68.7 kJ/mol estimated by Flynn-Wall-Ozawa method respectively. Thermogravimetric analyzer (TGA was used to investigate the thermal decomposition of cured compounds. It was found that when curing temperature was lower than 180°C, the thermal decomposition temperature increased with the rise of curing temperature and curing time. On the other hand, when the curing temperature was higher than 180°C, the thermal decomposition temperature went down instead with the increase of curing time that might be the over-crosslinking of TMBPBTH-EPOXY and DDS hardener. The glass transition temperature (Tg of cured TMBPBTH-EPOXY/DDS compound determined by dynamic mechanical thermal analysis (DMTA is 290.1°C.

  9. Thermal and physicochemical properties important for the long term behavior of nuclear waste glasses

    International Nuclear Information System (INIS)

    Vernaz, E.; Matzke, H.J.

    1992-01-01

    High level nuclear waste from reprocessing of spent nuclear fuel has to be solidified in a stable matrix for safe long-time storage. Vitrification in borosilicate glasses is the technique accepted worldwide. A number of different glasses was developed in different national programs. The criteria and the reasons for selecting the final compositions are briefly described. Emphasis is placed on the French product R7T7 and on thermal and physicochemical properties though glasses developed in other national projects (e.g. the German product GP 98/12 etc.) are also treated. The basic physical and mechanical properties and the chemical durability of the glass in contact with water or other aqueous solutions are described. The basic mechanisms of aqueous corrosion are discussed and the evolving modelling of the leaching process is dealt with, as well as effects of container material, backfill, etc. The thermal behavior has also been studied and extensive data exist on diffusion of glass constituents (Na) and of interesting elements of the waste such as the alkalis Rb and Cs or the actinides U and Pu, as well as on crystallization processes in the glass during storage at elevated temperatures. Emphasis is placed on the radiation stability of the glasses, based on extensive studies using short-lived actinides (e.g. Cm-244) or ion-implantation to produce the damage expected during long storage at an accelerated rate. The radiation stability is shown to be very good, if realistic damage conditions are used. The knowledge accumulated in the past years is used to evaluate and predict the long-term evolution of the glass under storage conditions

  10. Thermal expansion studies of ThW2O8 and UWO6

    International Nuclear Information System (INIS)

    Keskar, Meera; Krishnan, K.; Sali, S.K.

    2014-01-01

    Thorium and uranium oxysalts with hexavalent cations of elements of VI th group of the periodic table are important from mineralogical, environmental and technological points of view. Several molybdates and tungstates of uranium and thorium are known to have similar structural and thermo-physical properties. Earlier, thermal expansion behavior of ThMo 2 O 8 and UMoO 6 were reported from our laboratory. In the present work, thermal expansion behavior of ThW 2 O 8 and UWO 6 studied under vacuum from ambient to 1000 and 800℃, respectively using high temperature X-ray diffraction (HTXRD) technique is reported

  11. Thermal and spectroscopic studies on solid ibuprofen complexes of lighter trivalent lanthanides

    Energy Technology Data Exchange (ETDEWEB)

    Gálico, D.A.; Holanda, B.B.C.; Guerra, R.B.; Legendre, A.O.; Rinaldo, D. [UNESP – Univ Estadual Paulista, Faculdade de Ciências, Departamento de Química, São Paulo CEP 17033-260 (Brazil); Treu-Filho, O. [UNESP – Univ Estadual Paulista, Instituto de Química, São Paulo CEP 14800-900 (Brazil); Bannach, G., E-mail: gilbert@fc.unesp.br [UNESP – Univ Estadual Paulista, Faculdade de Ciências, Departamento de Química, São Paulo CEP 17033-260 (Brazil)

    2014-01-10

    Highlights: • Lighter trivalent lanthanide complexes of ibuprofen have been synthesized. • The TG-FTIR allowed the identification of propane as the gas evolved during the thermal decomposition of the neodymium compound. • The thermal analysis provided information about the composition, dehydration, thermal behavior and thermal decomposition of the samples. • The theoretical and experimental spectroscopic studies suggest that the carboxylate group of ibuprofen is coordinated to the metals by a bidentate bond. - Abstract: Solid-state compounds of general formula Ln(L){sub 3}, in which L is ibuprofen and Ln stands for trivalent La, Ce, Pr, Nd, Sm and Eu, have been synthesized. Simultaneous thermogravimetry and differential thermal analysis (TG-DTA), X-ray powder diffractometry (DRX), complexometry, Fourier-transformed infrared spectroscopy (FTIR) and thermogravimetry coupled to Fourier-transformed infrared spectroscopy (TG-FTIR) were used to characterize these compounds. The results provided information concerning the chemical composition, dehydration, coordination modes of the ligands, crystallinity of the samples, thermal behavior and thermal decomposition of the compounds. The theoretical and experimental spectroscopic studies suggest that ibuprofen coordinates through the carboxylate group as a chelating ligand.

  12. Thermal and spectroscopic studies on solid ibuprofen complexes of lighter trivalent lanthanides

    International Nuclear Information System (INIS)

    Gálico, D.A.; Holanda, B.B.C.; Guerra, R.B.; Legendre, A.O.; Rinaldo, D.; Treu-Filho, O.; Bannach, G.

    2014-01-01

    Highlights: • Lighter trivalent lanthanide complexes of ibuprofen have been synthesized. • The TG-FTIR allowed the identification of propane as the gas evolved during the thermal decomposition of the neodymium compound. • The thermal analysis provided information about the composition, dehydration, thermal behavior and thermal decomposition of the samples. • The theoretical and experimental spectroscopic studies suggest that the carboxylate group of ibuprofen is coordinated to the metals by a bidentate bond. - Abstract: Solid-state compounds of general formula Ln(L) 3 , in which L is ibuprofen and Ln stands for trivalent La, Ce, Pr, Nd, Sm and Eu, have been synthesized. Simultaneous thermogravimetry and differential thermal analysis (TG-DTA), X-ray powder diffractometry (DRX), complexometry, Fourier-transformed infrared spectroscopy (FTIR) and thermogravimetry coupled to Fourier-transformed infrared spectroscopy (TG-FTIR) were used to characterize these compounds. The results provided information concerning the chemical composition, dehydration, coordination modes of the ligands, crystallinity of the samples, thermal behavior and thermal decomposition of the compounds. The theoretical and experimental spectroscopic studies suggest that ibuprofen coordinates through the carboxylate group as a chelating ligand

  13. EPR STUDIES OF THERMALLY STERILIZED VASELINUM ALBUM.

    Science.gov (United States)

    Ramos, Paweł; Pilawa, Barbara

    2015-01-01

    Electron paramagnetic resonance (EPR) spectroscopy was used for examination of free radicals in thermally treated vaselinum album (VA). Thermal treatment in hot air as sterilization process was tested. Conditions of thermal sterilization were chosen according to the pharmaceutical norms. Vaselinum album was heated at the following conditions (T--temperature, t--time): T = 160°C and t = 120 min, T = 170°C and t = 60 min and T = 180°C and t = 30 min. The aim of this work was to determine concentration and free radical properties of thermally sterilized VA. EPR analysis for VA was done 15 min after sterilization. EPR measurements were done at room temperature. EPR spectra were recorded in the range of microwave power of 2.2-70 mW. g-Factor, amplitudes (A) and line width (ΔBpp) of the spectra were determined. The shape of the EPR spectra was analyzed. Free radical concentration (N) in the heated samples was determined. EPR spectra were not obtained for the non heated VA. EPR spectra were detected for all thermally sterilized samples. The spectra revealed complex character, their asymmetry depends on microwave power. The lowest free radicals concentration was found for the VA sterilized at 180°C during 30 min. EPR spectroscopy is proposed as the method useful for optimization of sterilization process of drugs.

  14. Communication: Minimum in the thermal conductivity of supercooled water: A computer simulation study

    Energy Technology Data Exchange (ETDEWEB)

    Bresme, F., E-mail: f.bresme@imperial.ac.uk [Chemical Physics Section, Department of Chemistry, Imperial College, London SW7 2AZ, United Kingdom and Department of Chemistry, Norwegian University of Science and Technology, Trondheim 7491 (Norway); Biddle, J. W.; Sengers, J. V.; Anisimov, M. A. [Institute for Physical Science and Technology, and Department of Chemical and Biomolecular Engineering, University of Maryland, College Park, Maryland 20742 (United States)

    2014-04-28

    We report the results of a computer simulation study of the thermodynamic properties and the thermal conductivity of supercooled water as a function of pressure and temperature using the TIP4P-2005 water model. The thermodynamic properties can be represented by a two-structure equation of state consistent with the presence of a liquid-liquid critical point in the supercooled region. Our simulations confirm the presence of a minimum in the thermal conductivity, not only at atmospheric pressure, as previously found for the TIP5P water model, but also at elevated pressures. This anomalous behavior of the thermal conductivity of supercooled water appears to be related to the maximum of the isothermal compressibility or the minimum of the speed of sound. However, the magnitudes of the simulated thermal conductivities are sensitive to the water model adopted and appear to be significantly larger than the experimental thermal conductivities of real water at low temperatures.

  15. Communication: Minimum in the thermal conductivity of supercooled water: A computer simulation study

    International Nuclear Information System (INIS)

    Bresme, F.; Biddle, J. W.; Sengers, J. V.; Anisimov, M. A.

    2014-01-01

    We report the results of a computer simulation study of the thermodynamic properties and the thermal conductivity of supercooled water as a function of pressure and temperature using the TIP4P-2005 water model. The thermodynamic properties can be represented by a two-structure equation of state consistent with the presence of a liquid-liquid critical point in the supercooled region. Our simulations confirm the presence of a minimum in the thermal conductivity, not only at atmospheric pressure, as previously found for the TIP5P water model, but also at elevated pressures. This anomalous behavior of the thermal conductivity of supercooled water appears to be related to the maximum of the isothermal compressibility or the minimum of the speed of sound. However, the magnitudes of the simulated thermal conductivities are sensitive to the water model adopted and appear to be significantly larger than the experimental thermal conductivities of real water at low temperatures

  16. Improved thermal stability and wettability behavior of thermoplastic polyurethane / barium metaborate composites

    International Nuclear Information System (INIS)

    Baştürka, Emre; Madakbaş, Seyfullah; Kahraman, Memet Vezir

    2016-01-01

    In this paper, it was targeted to the enhance thermal stability and wettability behavior of thermoplastic polyurethane (TPU) by adding barium metaborate. TPU-Barium metaborate composites were prepared by adding various proportions of barium metaborate to TPU. The chemical structures of the composites were characterised by fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) analysis. All prepared composites have extremely high Tg and thermal stability as determined from DSC and TGA analysis. All composite materials have the Tg ranging from 15 to 35 °C. The surface morphologies of the composites were investigated by a scanning electron microscopy. Mechanical properties of the samples were characterized with stress-strain test. Hydrophobicity of the samples was determined by the contact angle measurements. The obtained results proved that thermal, hydrophobic and mechanical properties were improved. (author)

  17. Transient thermal-mechanical coupling behavior analysis of mechanical seals during start-up operation

    Science.gov (United States)

    Gao, B. C.; Meng, X. K.; Shen, M. X.; Peng, X. D.

    2016-05-01

    A transient thermal-mechanical coupling model for a contacting mechanical seal during start-up has been developed. It takes into consideration the coupling relationship among thermal-mechanical deformation, film thickness, temperature and heat generation. The finite element method and multi-iteration technology are applied to solve the temperature distribution and thermal-mechanical deformation as well as their evolution behavior. Results show that the seal gap transforms from negative coning to positive coning and the contact area of the mechanical seal gradually decreases during start-up. The location of the maximum temperature and maximum contact pressure move from the outer diameter to inside diameter. The heat generation and the friction torque increase sharply at first and then decrease. Meanwhile, the contact force decreases and the fluid film force and leakage rate increase.

  18. Improved thermal stability and wettability behavior of thermoplastic polyurethane / barium metaborate composites

    Energy Technology Data Exchange (ETDEWEB)

    Baştürka, Emre; Madakbaş, Seyfullah; Kahraman, Memet Vezir, E-mail: smadakbas@marmara.edu.tr [Department of Chemistry, Marmara University, Istanbul (Turkey)

    2016-03-15

    In this paper, it was targeted to the enhance thermal stability and wettability behavior of thermoplastic polyurethane (TPU) by adding barium metaborate. TPU-Barium metaborate composites were prepared by adding various proportions of barium metaborate to TPU. The chemical structures of the composites were characterised by fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) analysis. All prepared composites have extremely high Tg and thermal stability as determined from DSC and TGA analysis. All composite materials have the Tg ranging from 15 to 35 °C. The surface morphologies of the composites were investigated by a scanning electron microscopy. Mechanical properties of the samples were characterized with stress-strain test. Hydrophobicity of the samples was determined by the contact angle measurements. The obtained results proved that thermal, hydrophobic and mechanical properties were improved. (author)

  19. Analysis of thermal demagnetization behavior of Nd–Fe–B sintered magnets using magnetic domain observation

    International Nuclear Information System (INIS)

    Takezawa, Masaaki; Ikeda, Soichiro; Morimoto, Yuji; Kabashima, Hisayuki

    2016-01-01

    We used magnetic domain observation to statistically observe the thermal demagnetization behavior of Nd–Fe–B sintered magnets at elevated temperatures up to 150 °C. Simultaneous magnetization reversal in a hundred adjacent grains occurred at 90 °C because of the magnetic interaction among the grains beyond grain boundaries in the Dysprosium (Dy)-free low-coercivity magnet. Conversely, simultaneous magnetization reversal in a hundred grains did not occur in the Dy-added high-coercivity magnets, and the demagnetizing ratio steadily increased with temperature. Furthermore, the addition of Dy induced high thermal stability by eliminating the simultaneous thermal demagnetization, which was caused by the magnetic interaction among the grains.

  20. Analysis of thermal demagnetization behavior of Nd–Fe–B sintered magnets using magnetic domain observation

    Energy Technology Data Exchange (ETDEWEB)

    Takezawa, Masaaki, E-mail: take@ele.kyutech.ac.jp; Ikeda, Soichiro; Morimoto, Yuji [Department of Applied Science for Integrated System Engineering, Faculty of Engineering, Kyushu Institute of Technology, 1-1 Sensui-cho, Tobata-ku, Kitakyushu, Fukuoka 804-8550 (Japan); Kabashima, Hisayuki [Mazda Motor Corporation,3-1, Shinchi, Fuchu-cho, Aki-gun Hiroshima 730-8670 (Japan)

    2016-05-15

    We used magnetic domain observation to statistically observe the thermal demagnetization behavior of Nd–Fe–B sintered magnets at elevated temperatures up to 150 °C. Simultaneous magnetization reversal in a hundred adjacent grains occurred at 90 °C because of the magnetic interaction among the grains beyond grain boundaries in the Dysprosium (Dy)-free low-coercivity magnet. Conversely, simultaneous magnetization reversal in a hundred grains did not occur in the Dy-added high-coercivity magnets, and the demagnetizing ratio steadily increased with temperature. Furthermore, the addition of Dy induced high thermal stability by eliminating the simultaneous thermal demagnetization, which was caused by the magnetic interaction among the grains.

  1. Experimental and theoretic investigations of thermal behavior of a seasonal water pit heat storage

    DEFF Research Database (Denmark)

    Fan, Jianhua; Huang, Junpeng; Chatzidiakos, Angelos

    Seasonal heat storages are considered essential for district heating systems because they offer flexibility for the system to integrate different fluctuating renewable energy sources. Water pit thermal storages (PTES) have been successfully implemented in solar district heating plants in Denmark....... Thermal behavior of a 75,000 m3 water pit heat storage in Marstal solar heating plant was investigated experimentally and numerically. Temperatures at different levels of the water pit storage and temperatures at different depths of the ground around the storage were monitored and analyzed. A simulation...... model of the water pit storage is built to investigate development of temperatures in and around the storage. The calculated temperatures are compared to the monitored temperatures with an aim to validate the simulation model. Thermal stratification in the water pit heat storage and its interaction...

  2. Thermal Gradient Cyclic Behavior of a Thermal/Environmental Barrier Coating System on SiC/SiC Ceramic Matrix Composites

    Science.gov (United States)

    Zhu, Dongming; Lee, Kang N.; Miller, Robert A.

    2002-01-01

    Thermal barrier and environmental barrier coatings (TBCs and EBCs) will play a crucial role in future advanced gas turbine engines because of their ability to significantly extend the temperature capability of the ceramic matrix composite (CMC) engine components in harsh combustion environments. In order to develop high performance, robust coating systems for effective thermal and environmental protection of the engine components, appropriate test approaches for evaluating the critical coating properties must be established. In this paper, a laser high-heat-flux, thermal gradient approach for testing the coatings will be described. Thermal cyclic behavior of plasma-sprayed coating systems, consisting of ZrO2-8wt%Y2O3 thermal barrier and NASA Enabling Propulsion Materials (EPM) Program developed mullite+BSAS/Si type environmental barrier coatings on SiC/SiC ceramic matrix composites, was investigated under thermal gradients using the laser heat-flux rig in conjunction with the furnace thermal cyclic tests in water-vapor environments. The coating sintering and interface damage were assessed by monitoring the real-time thermal conductivity changes during the laser heat-flux tests and by examining the microstructural changes after the tests. The coating failure mechanisms are discussed based on the cyclic test results and are correlated to the sintering, creep, and thermal stress behavior under simulated engine temperature and heat flux conditions.

  3. Modeling non-harmonic behavior of materials from experimental inelastic neutron scattering and thermal expansion measurements

    Science.gov (United States)

    Bansal, Dipanshu; Aref, Amjad; Dargush, Gary; Delaire, Olivier

    2016-09-01

    Based on thermodynamic principles, we derive expressions quantifying the non-harmonic vibrational behavior of materials, which are rigorous yet easily evaluated from experimentally available data for the thermal expansion coefficient and the phonon density of states. These experimentally-derived quantities are valuable to benchmark first-principles theoretical predictions of harmonic and non-harmonic thermal behaviors using perturbation theory, ab initio molecular-dynamics, or Monte-Carlo simulations. We illustrate this analysis by computing the harmonic, dilational, and anharmonic contributions to the entropy, internal energy, and free energy of elemental aluminum and the ordered compound \\text{FeSi} over a wide range of temperature. Results agree well with previous data in the literature and provide an efficient approach to estimate anharmonic effects in materials.

  4. Thermal and mechanical behavior of metal matrix and ceramic matrix composites

    Science.gov (United States)

    Kennedy, John M. (Editor); Moeller, Helen H. (Editor); Johnson, W. S. (Editor)

    1990-01-01

    The present conference discusses local stresses in metal-matrix composites (MMCs) subjected to thermal and mechanical loads, the computational simulation of high-temperature MMCs' cyclic behavior, an analysis of a ceramic-matrix composite (CMC) flexure specimen, and a plasticity analysis of fibrous composite laminates under thermomechanical loads. Also discussed are a comparison of methods for determining the fiber-matrix interface frictional stresses of CMCs, the monotonic and cyclic behavior of an SiC/calcium aluminosilicate CMC, the mechanical and thermal properties of an SiC particle-reinforced Al alloy MMC, the temperature-dependent tensile and shear response of a graphite-reinforced 6061 Al-alloy MMC, the fiber/matrix interface bonding strength of MMCs, and fatigue crack growth in an Al2O3 short fiber-reinforced Al-2Mg matrix MMC.

  5. Thermal cycling behavior of EB-PVD TBCs on CVD platinum modified aluminide coatings

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Zhenhua, E-mail: zhxubiam@aliyun.com; Wang, Zhankao; Huang, Guanghong; Mu, Rende; He, Limin

    2015-07-15

    Highlights: • The removed ridges at the grain boundaries with grit blasting. • The ridge, oxidation and cracking are features of damage initiation in TBCs. • Spalled location either at TGO/bond coat interface or inside of TGO layer. • The lower strain energy release rate within TGO layer can prolong of TBCs life. - Abstract: Thermal barrier coating systems (TBCs) including of chemical vapor deposited (Ni, Pt)Al bond coat with grit blasting process and electron beam physical vapor deposited Y{sub 2}O{sub 3}-stabilized-ZrO{sub 2} (YSZ) ceramic coating were investigated. The phase structures, surface and cross-sectional morphologies, cyclic oxidation behaviors and residual stresses of the TBCs were studied in detail. It was found that the fracture path traverses through the ceramic coating to TGO interface, as well as at the TGO to bond coat interface is obviously detected. The change in fracture plane occurs at grain boundaries. The ridge top spallation leads to separate of sufficient size to result in unstable fracture driven by the strain energy stored in the TGO. The bond coat can undergo a volume increase upon oxidation, so that a cavity, enlarged strictly by oxidation would be full to overflowing with TGO layer. The spalled location of the TBCs probably occurs either at the interface of TGO layer and bond coat or inside of TGO layer. The lower strain energy release rate within TGO layer during thermal cycling is beneficial to prolong of TBCs life. The lower is the compressive stress within TGO layer, the longer is the lifetime of TBCs.

  6. Macroscopic behavior of fast reactor fuel subjected to simulated thermal transients

    International Nuclear Information System (INIS)

    Fenske, G.R.; Emerson, J.E.; Savoie, F.E.

    1983-06-01

    High-speed cinematography has been used to characterize the macroscopic behavior of irradiated and unirradiated fuel subjected to thermal transients prototypical of fast reactor transients. The results demonstrate that as the cladding melts, the fuel can disperse via spallation if the fuel contains in excess of approx. 16 μmoles/gm of fission gas. Once the cladding has melted, the macroscopic behavior (time to failure and dispersive nature) was strongly influenced by the presence of volatile fission products and the heating rate

  7. Thermal energy accumulators. A bibliographical study

    International Nuclear Information System (INIS)

    Charlety, Paul

    1971-01-01

    Energy storage is a challenge, notably for spacecraft, submarines and non-polluting automotive vehicles. After a comparison of mass energies of different principles of energy accumulation (magnetic, electrostatic, solid elasticity, kinetic energy, gaseous elasticity, electro-chemistry, sensitive heat, freezing heat, fuels, radioactivity, nuclear fission or fusion, mass energy), the author discusses the choice of thermal storage, presents the main bodies used for thermal energy accumulation (molten salts such as lithium hydride or lithium salt eutectics, or other compounds such as alumina, paraffins), and gives an overview of the main theoretical problems [fr

  8. Characterization of physicochemical and thermal properties and crystallization behavior of krabok (Irvingia Malayana ) and rambutan seed fats.

    Science.gov (United States)

    Sonwai, Sopark; Ponprachanuvut, Punnee

    2012-01-01

    Fatty acid composition, physicochemical and thermal properties and crystallization behavior of fats extracted from the seeds of krabok (Irvingia Malayana) and rambutan (Nephelium lappaceum L.) trees grown in Thailand were studied and compared with cocoa butter (CB). The krabok seed fat, KSF, consisted of 46.9% lauric and 40.3% myristic acids. It exhibited the highest saponification value and slip melting point but the lowest iodine values. The three fats displayed different crystallization behavior at 25°C. KSF crystallized into a mixture of β' and pseudo-β' structures with a one-step crystallization curve and high solid fat content (SFC). The fat showed simple DSC crystallization and melting thermograms with one distinct peak. The rambutan seed fat, RSF, consisted of 42.5% arachidic and 33.1% oleic acids. Its crystallization behavior was more similar to CB than KSF, displaying a two-step crystallization curve with SFC lower than that of KSF. RSF solidified into a mixture of β' and pseudo-β' before transforming to β after 24 h. The large spherulitic microstructures were observed in both KSF and RSF. According to these results, the Thai KSF and RSF exhibited physicochemical, thermal characteristics and crystallization behavior that could be suitable for specific applications in several areas of the food, cosmetic and pharmaceutical industries.

  9. Crack propagation behavior of TiN coatings by laser thermal shock experiments

    International Nuclear Information System (INIS)

    Choi, Youngkue; Jeon, Seol; Jeon, Min-seok; Shin, Hyun-Gyoo; Chun, Ho Hwan; Lee, Youn-seoung; Lee, Heesoo

    2012-01-01

    Highlights: ► The crack propagation behavior of TiN coating after laser thermal shock experiment was observed by using FIB and TEM. ► Intercolumnar cracks between TiN columnar grains were predominant cracking mode after laser thermal shock. ► Cracks were propagated from the coating surface to the substrate at low laser pulse energy and cracks were originated at coating-substrate interface at high laser pulse energy. ► The cracks from the interface spread out transversely through the weak region of the columnar grains by repetitive laser shock. - Abstract: The crack propagation behavior of TiN coatings, deposited onto 304 stainless steel substrates by arc ion plating technique, related to a laser thermal shock experiment has been investigated using focused ion beam (FIB) and transmission electron microscopy (TEM). The ablated regions of TiN coatings by laser ablation system have been investigated under various conditions of pulse energies and number of laser pulses. The intercolumnar cracks were predominant cracking mode following laser thermal shock tests and the cracks initiated at coating surface and propagated in a direction perpendicular to the substrate under low loads conditions. Over and above those cracks, the cracks originated from coating-substrate interface began to appear with increasing laser pulse energy. The cracks from the interface also spread out transversely through the weak region of the columnar grains by repetitive laser shock.

  10. Thermal shock behavior of nano-sized SiC particulate reinforced AlON composites

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, X.J. [Department of Materials Science and Engineering, School of Materials and Metallurgy, Northeastern University, Shenyang, Liaoning 110004 (China); Department of Mechanical and Industrial Engineering, Ryerson University, Toronto, Ontario M5B 2K3 (Canada); Ru, H.Q., E-mail: ruhq@smm.neu.edu.cn [Department of Materials Science and Engineering, School of Materials and Metallurgy, Northeastern University, Shenyang, Liaoning 110004 (China); Chen, D.L., E-mail: dchen@ryerson.ca [Department of Mechanical and Industrial Engineering, Ryerson University, Toronto, Ontario M5B 2K3 (Canada); Zhang, N.; Liang, B. [Key Laboratory of Advanced Materials Manufacturing Technology of Liaoning Province, Shenyang University, Shenyang, Liaoning 110044 (China)

    2012-03-25

    Highlights: Black-Right-Pointing-Pointer Addition of nano-SiC particles enhances residual strength and critical temperature. Black-Right-Pointing-Pointer Young's modulus decreases with increasing quenching temperature. Black-Right-Pointing-Pointer Linear relationship between residual strength and thermal shock times is obtained. Black-Right-Pointing-Pointer Rougher fracture surfaces in the SiC-AlON composites are observed. - Abstract: Aluminum oxynitride (AlON) has been considered as a potential ceramic material for high-performance structural and advanced refractory applications. Thermal shock resistance is a major concern and an important performance index of high-temperature ceramics. While silicon carbide (SiC) particles have been proven to improve mechanical properties of AlON ceramic, the high-temperature thermal shock behavior was unknown. The aim of this investigation was to identify the thermal shock resistance and underlying mechanisms of AlON ceramic and 8 wt% SiC-AlON composites over a temperature range between 175 Degree-Sign C and 275 Degree-Sign C. The residual strength and Young's modulus after thermal shock decreased with increasing quenching temperature and thermal shock times due to large temperature gradients and thermal stresses caused by abrupt water-quenching. A linear relationship between the residual strength and thermal shock times was observed in both pure AlON and SiC-AlON composites. The addition of nano-sized SiC particles increased both residual strength and critical temperature from 200 Degree-Sign C in the monolithic AlON to 225 Degree-Sign C in the SiC-AlON composites due to the toughening effect, the lower coefficient of thermal expansion and higher thermal conductivity of SiC. The enhancement of the thermal shock resistance in the SiC-AlON composites was directly related to the change of fracture mode from intergranular cracking along with cleavage-type fracture in the AlON to a rougher fracture surface with ridge

  11. Comparison of thermal behavior of different PWR fuel rod simulators for LOCA experiments

    International Nuclear Information System (INIS)

    Casal, V.; Malang, S.; Rust, K.

    1982-10-01

    For experimental investigations of a loss-of-coolant accident (LOCA) of a PWR electrical heater rods are applied as thermal fuel rod simulators. To substitute heater rods from the SEMISCALE program by INTERATOM-KfK heater rods in a current experimental program at the Instituut for Energiteknikk-(OECD-Halden), the thermodynamic behavior of different heater rods during a LOCA were compared. The results show, that SEMISCALE-heater rods can be replaced by those fabricated by INTERATOM. (orig.) [de

  12. Thermal dynamic behavior during selective laser melting of K418 superalloy: numerical simulation and experimental verification

    Science.gov (United States)

    Chen, Zhen; Xiang, Yu; Wei, Zhengying; Wei, Pei; Lu, Bingheng; Zhang, Lijuan; Du, Jun

    2018-04-01

    During selective laser melting (SLM) of K418 powder, the influence of the process parameters, such as laser power P and scanning speed v, on the dynamic thermal behavior and morphology of the melted tracks was investigated numerically. A 3D finite difference method was established to predict the dynamic thermal behavior and flow mechanism of K418 powder irradiated by a Gaussian laser beam. A three-dimensional randomly packed powder bed composed of spherical particles was established by discrete element method. The powder particle information including particle size distribution and packing density were taken into account. The volume shrinkage and temperature-dependent thermophysical parameters such as thermal conductivity, specific heat, and other physical properties were also considered. The volume of fluid method was applied to reconstruct the free surface of the molten pool during SLM. The geometrical features, continuity boundaries, and irregularities of the molten pool were proved to be largely determined by the laser energy density. The numerical results are in good agreement with the experiments, which prove to be reasonable and effective. The results provide us some in-depth insight into the complex physical behavior during SLM and guide the optimization of process parameters.

  13. Thermal decomposition behaviors of magnesium borohydride doped with metal fluoride additives

    International Nuclear Information System (INIS)

    Zhang, Z.G.; Wang, H.; Liu, J.W.; Zhu, M.

    2013-01-01

    Highlights: • The decomposition proceeded through several distinct steps. • The mixed materials show a dramatically low initial hydrogen release temperature. • The additives react with the Mg–B–H compounds rather than acting as catalysts. • The reaction process was studied using an in situ TEM. - Abstract: The thermal decomposition behaviors of Magnesium borohydride [Mg(BH 4 ) 2 ] and metal fluoride doped mixtures were studied by temperature programmed desorption measurement/mass spectrometry (TPD/MS), differential scanning calorimetry (DSC) and in situ transmission electron microscope (TEM) observations. The decomposition and release of hydrogen proceeded through several distinct steps, including two polymorphic transitions, ionic Mg(BH 4 ) 2 melting with solid Mg–B–H amorphous phase formation and Mg–B–H decomposition. The addition of additives such as CaF 2 , ZnF 2 and TiF 3 resulted in a decrease in the hydrogen release temperature. ZnF 2 and TiF 3 reduced the initial hydrogen release temperature to ca. 50 °C. However, hydrogen release during the transformation from γ-Mg(BH 4 ) 2 to the amorphous Mg–B–H compounds at ca. 300 °C was only 4.5 wt.% in contrast to 9.8 wt.% for the direct decomposition of pure Mg(BH 4 ) 2 . TEM observations confirmed that ZnF 2 and TiF 3 reacted with amorphous Mg–B–H compounds rather than acting as catalysts

  14. The Effect of an Isogrid on Cryogenic Propellant Behavior and Thermal Stratification

    Science.gov (United States)

    Oliveira, Justin; Kirk, Daniel R.; Chintalapati, Sunil; Schallhorn, Paul A.; Piquero, Jorge L.; Campbell, Mike; Chase, Sukhdeep

    2007-01-01

    All models for thermal stratification available in the presentation are derived using smooth, flat plate laminar and turbulent boundary layer models. This study examines the effect of isogrid (roughness elements) on the surface of internal tank walls to mimic the effects of weight-saving isogrid, which is located on the inside of many rocket propellant tanks. Computational Fluid Dynamics (CFD) is used to study the momentum and thermal boundary layer thickness for free convection flows over a wall with generic roughness elements. This presentation makes no mention of actual isogrid sizes or of any specific tank geometry. The magnitude of thermal stratification is compared for smooth and isogrid-lined walls.

  15. Needs of thermal-hydraulic codes for analyzing hydrogen behavior of future chinese NPPs

    International Nuclear Information System (INIS)

    Zhiwei Zhou; Jianjun Xiao; Mengjia Yang

    2005-01-01

    severe accident management guidelines are therefore needed for dealing with both the in-vessel and ex-vessel phenomena, including hydrogen generation, diffusion/convection and deflagration/detonation. To develop the sophisticated thermalhydraulic codes for analyzing severe accident related hydrogen behavior of a light water reactor system is quite expensive and rather unrealistic for China along to bear the cost. Therefore, the most effective way for China to establish the design capability of analyzing severe accident for new nuclear power plant projects is to participate the international or multi-national R and D program, such as EUROATOM cost-sharing program and GEN-IV program, etc. By international cooperation, China can not only gain in most extent the successful experience of the countries with advanced technology in developing nuclear power plants, but also contribute itself most effectively in keeping the momentum of enlarging the peaceful utilization of nuclear energy in the world. Certainly, the future Chinese nuclear power market will be a significant industrial driver for developing the-state-of-the-art thermal-hydraulic codes, including hydrogen behavior analysis codes. This paper also reports some computational study on hydrogen diffusion/convection behavior in the containment related to Daya Bay NPP severe accident analysis with CFD code GASFLOW. The code validation were largely carried out in past few years in Germany and had been applied to EPR and other German NPPs. (authors)

  16. Mamey sapote seed oil (Pouteria sapota. Potential, composition, fractionation and thermal behavior

    Directory of Open Access Journals (Sweden)

    Solís-Fuentes, J. A.

    2015-03-01

    Full Text Available The chemical composition of the waste from mamey sapote (Pouteria sapota and its oil extracted from the seed (MSSO of ripe and unripe fruits, was studied. The MSSO from ripe fruits was dry-fractionated, and the thermal and phase behaviors of its fractions and their mixtures with other known natural fats were analyzed. The main components of the mamey peel and the seed were crude fiber (81.32% and fat (44.41% db, respectively. The seed oil contained oleic, stearic, palmitic and linoleic as its main fatty acids. The MSSO showed a simple thermal behavior with a broad fusion range and four maximum temperature peaks. The solid fractions showed maximum melting peaks at higher temperatures than the residual liquid. The MSSO solid fractions showed a potential for use as constituents in mixtures with other natural fats, such as cocoa butter or mango seed fat.Se estudió la composición de los residuos del zapote mamey (Pouteria sapota y del aceite extraído de la semilla (ASZM de frutos maduros e inmaduros. El ASZM de frutos maduros fue fraccionado en seco y se analizó la conducta térmica y de fase de las fracciones y mezclas de éstas con otras grasas naturales conocidas. Los principales componentes de la cáscara y de la semilla fueron fibra cruda (81.32% bs y grasa (44.41% bs, respectivamente. Los principales ácidos grasos del ASZM fueron: oleico, esteárico, palmítico y linoleico y mostró una conducta térmica simple con un intervalo de fusión amplio y cuatro máximos de temperatura. Las fracciones sólidas obtenidas presentaron máximos de fusión a temperaturas más altas que la fracción líquida residual. Las fracciones sólidas del ASZM mostraron potencialidad para usarse como constituyente en mezclas con la manteca de cacao y la grasa de la semilla de mango.

  17. Young’s modulus evaluation and thermal shock behavior of a porous SiC/cordierite composite material

    Directory of Open Access Journals (Sweden)

    Pošarac-Marković M.

    2015-01-01

    Full Text Available Porous SiC/Cordierite Composite Material with graphite content (10% was synthesized. Evaluation of Young modulus of elasticity and thermal shock behavior of these samples was presented. Thermal shock behavior was monitored using water quench test, and non destructive methods such are UPVT and image analysis were also used for accompaniment the level of destruction of the samples during water quench test. Based on the level of destruction graphical modeling of critical number of cycles was given. This approach was implemented on discussion of the influence of the graphite content on thermal stability behavior of the samples. [Projekat Ministarstva nauke Republike Srbije, br. III 45012

  18. THERMAL COMFORT IN VERNACULAR COURTYARD HOUSES: CASE STUDY -CHHATTISGARH

    OpenAIRE

    Swasti Sthapak*1, Dr. Abir Bandyopadhyay2

    2017-01-01

    The paper firstly introduces vernacular architecture and defines thermal comfort. The second section of this paper gives an account of the way vernacular houses respond to climate and achieve thermal comfort. Vernacular houses of Chhattisgarh, a central state of India are selected for this study to find the evidence that vernacular architecture is likely to be passively comfortable. Courtyards play a vital role in creating thermal comfort along with other social and cultural roles. Vernacular...

  19. Interface thermal characteristics of flip chip packages - A numerical study

    International Nuclear Information System (INIS)

    Kandasamy, Ravi; Mujumdar, A.S.

    2009-01-01

    Flip chip ball grid array (FC-BGA) packages are commonly used for high inputs/outputs (I/O) ICs; they have been proven to provide good solutions for a variety of applications to maximize thermal and electrical performance. A fundamental limitation to such devices is the thermal resistance at the top of the package, which is characterized θ JC parameter. The die-to-lid interface thermal resistance is identified as a critical issue for the thermal management of electronic packages. This paper focuses on the effect of the interface material property changes on the interface thermal resistance. The effect of package's junction to case (Theta-JC or θ JC ) thermal performance is investigated for bare die, flat lid and cup lid packages using a validated thermal model. Thermal performance of a cup or flat lid attached and bare die packages were investigated for different interface materials. Improved Theta-JC performance was observed for the large die as compared to the smaller die. Several parametric studies were carried out to understand the effects of interface bond line thickness (BLT), different die sizes, the average void size during assembly and thermal conductivity of interface materials on package thermal resistance

  20. FOREVER Experiments on Thermal and Mechanical Behavior of a Reactor Pressure Vessel during a Severe Accident

    International Nuclear Information System (INIS)

    Sehgal, B.R.; Nourgaliev, R.R.; Dinh, T.N.; Karbojian, A.; Green, J.A.; Bui, V.A.

    1999-01-01

    This paper describes the FOREVER (Failure Of Reactor Vessel Retention) experimental program, which is currently underway at the Division of Nuclear Power Safety, Royal Institute of Technology (RIT/NPS). The objectives of the FOREVER experiments are to obtain data and develop validated models (i) on the melt coolability process inside the vessel, in the presence of water (in particular, on the efficacy of the postulated gap cooling to preclude vessel failure); and (ii) on the lower head failure due to the creep process in the absence of water inside and/or outside the lower head. The facility employs 1/10.-scale carbon steel vessels of 0.4 m diameter, 15 mm thickness and 600 mm height. Up to 20 liters of binary-oxide melts with 100-300 K superheat are employed, as a simulant for the prototypic corium melt, and internal heating is provided by electrical heaters of up to 20 kW power in order to maintain the vessel wall temperatures at 1100-1200 K. Auxiliary systems are designed to provide an overpressure up to 4 MPa in the test vessel. Thus, severe accident scenarios with RCS depressurization are modeled. Creep behavior of the three-dimensional vessel, formation of the gap between the melt pool crust and the creeping vessel, and mechanisms of the gap cooling by water ingression will be the subjects of study and measurements in the FOREVER experimental program. Scaling rationale as well as pre-test analyses of the thermal and mechanical behavior of the FOREVER test vessels are presented. (authors)

  1. Experimental and numerical studies of various thermal sleeves subjected to severe cyclic thermal shocks

    International Nuclear Information System (INIS)

    Masson, J.C.; Moinereau, D.

    1990-01-01

    During the first operating years of nuclear power plants of different countries, damage was encountered on thermal sleeves used as nozzle protection. Following this discovery studies were initiated to determine the causes and to find solutions. At first a problem of vibration was found and easily solved by reducing gaps and reinforcing the welding of the sleeves. But preliminary tests with cyclic thermal shocks showed a risk of fatigue crack initiation and propagation both in the sleeve fixation and in the nozzle. Therefore a large research and development program was led principally by EDF laboratories of Les Renardieres, to demonstrate the absence of nocivity of thermal shocks during the plants life time [fr

  2. A thermal study of an encapsulated electrical transformer

    Energy Technology Data Exchange (ETDEWEB)

    Garcia, A. [Unidad Geotermia, Temixco (Mexico). Instituto de Investigaciones Electricas; Espinosa-Paredes, G. [Universidad Autonoma Metropolitana, Vicentina (Mexico). Dpto. de Ingenieria de Procesos e Hidraulica; Hernandez, I. [Centro de Sistemas de Manufactura, Nuevo Leon (Mexico). Instituto Tecnologico y de Estudios Superiores de Monterrey

    2002-11-01

    A thermal study of a 45 KVA-prototype encapsulated transformer is described. Casting resin systems were used as insulating systems for encapsulated electric transformers. Normal transformer operation is at full load and, thus the conductor and insulating system becomes hot owing to current circulation through the winding. To determine the various temperature distributions throughout the transformer, the thermal properties of the insulating system and boundary conditions must be known, so that hot spots are located via numerical modelling and maximum permissible temperatures are not attained. Results presented herein include thermal conductivity, thermal diffusivity, and specific heat capacity. Thermal conductivity was obtained experimentally by means of the line-source technique at various temperatures, between room temperature and 155{sup o}C which is the thermal limit of class F insulators. The thermal diffusivity was obtained by parameter estimation by fitting an approximate analytical model to the temperature-time data of the thermal conductivity experiment. Specific heat capacity was obtained from the definition of thermal diffusivity and the insulating-system density. In order to improve the electrical performance of the transformer criteria, a numerical simulation of the different dielectric structures was made using computer program. The boundary conditions for the thermal simulation stage were also determined experimentally from temperature test runs. Finally, in order to obtain data for thermal design, a numerical simulation of the high tension winding was carried out. The thermal simulation stage was performed at different current densities in the conductor with and without electrostatic shields to determine the temperature field and maximum attainable temperatures. Maximum transformer temperature were found to be 15-20{sup o}C below its thermal limit and a correlation of maximum temperature as function of circulating current was developed for design

  3. Structural properties, deformation behavior and thermal stability of martensitic Ti-Nb alloys

    Energy Technology Data Exchange (ETDEWEB)

    Boenisch, Matthias

    2016-06-10

    Ti-Nb alloys are characterized by a diverse metallurgy which allows obtaining a wide palette of microstructural configurations and physical properties via careful selection of chemical composition, heat treatment and mechanical processing routes. The present work aims to expand the current state of knowledge about martensite forming Ti-Nb alloys by studying 15 binary Ti-c{sub Nb}Nb (9 wt.% ≤ c{sub Nb} ≤ 44.5 wt.%) alloy formulations in terms of their structural and mechanical properties, as well as their thermal stability. The crystal structures of the martensitic phases, α{sup '} and α'', and the influence of the Nb content on the lattice (Bain) strain and on the volume change related to the β → α{sup '}/α'' martensitic transformations are analyzed on the basis of Rietveld-refinements. The magnitude of the shuffle component of the β → α{sup '}/α'' martensitic transformations is quantified in relation to the chemical composition. The largest transformation lattice strains are operative in Nb-lean alloys. Depending on the composition, both a volume dilatation and contraction are encountered and the volume change may influence whether hexagonal martensite α{sup '} or orthorhombic martensite α'' forms from β upon quenching. The mechanical properties and the deformation behavior of martensitic Ti-Nb alloys are studied by complementary methods including monotonic and cyclic uniaxial compression, nanoindentation, microhardness and impulse excitation technique. The results show that the Nb content strongly influences the mechanical properties of martensitic Ti-Nb alloys. The elastic moduli, hardness and strength are minimal in the vicinity of the limiting compositions bounding the interval in which orthorhombic martensite α'' forms by quenching. Uniaxial cyclic compressive testing demonstrates that the elastic properties of strained samples are different than those of unstrained ones

  4. Precipitation behavior in austenitic and ferritic steels during fast neutron irradiation and thermal aging*1

    Science.gov (United States)

    Kawanishi, H.; Hajima, R.; Sekimura, N.; Arai, Y.; Ishino, S.

    1988-07-01

    Precipitation behavior has been studied using a carbon extraction replica technique in Ti-modified Type 316 stainless steels (JPCA-2) and 9Cr-2Mo ferritic/martensitic steels (JFMS) irradiated to 8.1 × 10 24 n/m 2 at 873 and 673 K, respectively, in the experimental fast breeder reactor JOYO. Precipitate identification and compositional analysis were carried out on extracted replicas. The results were compared to those from the as-received steel and a control which had been given the same thermal as-treatment as the specimens received during irradiations. Carbides, Ti-sulphides and phosphides were precipitated in JPCA-2. Precipitate observed in JFMS included carbides, Laves-phases and phosphides. The precipitates in both steels were concluded to be stable under irradiation except for MC and M 6C in JPCA-2. Small MC particles were found precipitated in JPCA-2 during both irradiation and aging. Irradiation proved to promote the precipitation of M 6C in JPCA-2.

  5. Precipitation behavior in austenitic and ferritic steels during fast neutron irradiation and thermal aging

    International Nuclear Information System (INIS)

    Kawanishi, H.; Hajima, R.; Sekimura, N.; Arai, Y.; Ishino, S.

    1988-01-01

    Precipitation behavior has been studied using a carbon extraction replica technique in Ti-modified Type 316 stainless steels (JPCA-2) and 9Cr-2Mo ferritic/martensitic steels (JFMS) irradiated to 8.1x10 24 n/m 2 at 873 and 673 K, respectively, in the experimental fast breeder reactor JOYO. Precipitate identification and compositional analysis were carried out on extracted replicas. The results were compared to those from the as-received steel and a control which had been given the same thermal as-treatment as the specimens received during irradiations. Carbides, Ti-sulphides and phosphides were precipitated in JPCA-2. Precipitate observed in JFMS included carbides, Laves-phases and phosphides. The precipitates in both steels were concluded to be stable under irradiation except for MC and M 6 C in JPCA-2. Small MC particles were found precipitated in JPCA-2 during both irradiation and aging. Irradiation proved to promote the precipitation of M 6 C in JPCA-2. (orig.)

  6. Behavior of nickel-titanium instruments manufactured with different thermal treatments.

    Science.gov (United States)

    Pereira, Érika Sales Joviano; Viana, Ana Cecília Diniz; Buono, Vicente Tadeu Lopes; Peters, Ove A; Bahia, Maria Guiomar de Azevedo

    2015-01-01

    The purpose of this study was to investigate if nickel-titanium instruments with similar designs manufactured by different thermal treatments would exhibit significantly different in vitro behavior. Thirty-six instruments each of ProTaper Universal (PTU F1; Dentsply Maillefer, Ballaigues, Switzerland), ProFile Vortex (PV; Dentsply Tulsa Dental Specialties, Tulsa, OK), Vortex Blue (VB, Dentsply Tulsa Dental Specialties), and TYPHOON Infinite Flex NiTi (TYP; Clinician's Choice Dental Products, New Milford, CT) (all size 25/.06) were evaluated. Bending resistance, torsion at failure, and dynamic torsional tests were performed with the instruments (n = 12). Analysis of variance and Tukey post hoc tests were applied. Flexibility was significantly higher for TYP compared with the other 3 groups (P .05). The highest mean forces were recorded with PTU (7.02 ± 2.36 N) and the lowest with TYP (1.22 ± 0.40 N). TYP instruments were significantly more flexible than the other instruments tested. The PV group had the highest torsional strength and TYP, despite being the most flexible, showed similar torsional moments to the other instruments, whereas its angular deflection was the highest among the groups. Copyright © 2015 American Association of Endodontists. All rights reserved.

  7. Investigation of the milling-induced thermal behavior of crystalline and amorphous griseofulvin.

    Science.gov (United States)

    Trasi, Niraj S; Boerrigter, Stephan X M; Byrn, Stephen Robert

    2010-07-01

    To gain a better understanding of the physical state and the unusual thermal behavior of milled griseofulvin. Griseofulvin crystals and amorphous melt quench samples were milled in a vibrating ball mill for different times and then analyzed using differential scanning calorimetry (DSC) and powder X-ray diffraction (PXRD). Modulated DSC (mDSC) and annealing studies were done for the milled amorphous samples to further probe the effects of milling. Milling of griseofulvin crystals results in decrease in crystallinity and amorphization of the compound. A double peak is seen for crystallization in the DSC, which is also seen for the milled melt quench sample. Both enthalpy and temperature of crystallization decrease for the milled melt quenched sample. Tg is visible under the first peak with the mDSC, and annealing shows that increasing milling time results in faster crystallization upon storage. Milling of griseofulvin results in the formation of an amorphous form and not a mesophase. It increases the amount of surface created and the overall energy of the amorphous griseofulvin, which leads to a decreased temperature of crystallization. The two exotherms in the DSC are due to some particles having nuclei on the surface.

  8. A new zinc(II supramolecular square: Synthesis, crystal structure, thermal behavior and luminescence

    Directory of Open Access Journals (Sweden)

    Wang Xiu-Yan

    2015-01-01

    Full Text Available A new square-shaped Zn(II complex, namely, [Zn4(L4(phen4]•6H2O (1 (L = 2-hydroxynicotinate and phen = 1,10- phenanthroline, has been synthesized under hydrothermal condition. The crystal of 1 belongs to triclinic, space group P -1 with a = 10.773(2 Å, b = 12.641(3 Å, c = 13.573(3 Å, α = 107.44(3º, β = 102.66(3º, γ = 93.89(3°, C72H56N12O18Zn4, Mr = 1638.77, V = 1702.8(6 Å3 , Z = 1, Dc = 1.598 g/cm3 , S = 1.045, μ(MoKα = 1.475 mm-1 , F(000 = 836, R = 0.0472 and wR = 0.0919. In 1, four L ligands bridge four Zn(II atoms to form a square-shaped structure, where four phen ligands are respectively located on four corners of the square. The π-π stacking interactions extend the adjacent squares into a 1D supramolecular chain. The thermal behavior of 1 has been characterized. Moreover, its solid state luminescence property has been studied at room temperature.

  9. Caesalpinia echinata Lam. - BRAZILWOOD: THERMAL BEHAVIOR, STRUCTURAL CHARACTERISTICS, AND RESISTANCE TO BIODETERIORATION IN STATIC SYSTEMS

    Directory of Open Access Journals (Sweden)

    Ana Paula Pinto Pinheiro

    Full Text Available ABSTRACT Wood is the best-known biological material used as a raw material since the dawn of mankind until present days. As a natural and renewable composite, its lifetime is limited by the degradation of its basic elements. This degradation can be caused by chemical reactions or by biological agents capable of accelerating the process of deterioration. In this work, the wear, thermal, and micro-structural characteristics, as also the bio-degradation behavior in static systems, of the wood species Brazilwood (Caesalpinia echinata were studied under laboratory conditions in order to use these woods in design. The results show that Brazilwood has a good visual performance after abrasion test, since it has not shown any representative roughness increase. In addition, Brazilwood has high level of crystallinity of, approximately, 68% and was almost insensitive to fungi attack, forming only 5.3 x 103 CFU/mL. Besides, its texture did not change due to exposure to water or sweat.

  10. Kapitza thermal resistance studied by high-frequency photothermal radiometry

    International Nuclear Information System (INIS)

    Horny, Nicolas; Chirtoc, Mihai; Hamaoui, Georges; Fleming, Austin; Ban, Heng

    2016-01-01

    Kapitza thermal resistance is determined using high-frequency photothermal radiometry (PTR) extended for modulation up to 10 MHz. Interfaces between 50 nm thick titanium coatings and silicon or stainless steel substrates are studied. In the used configuration, the PTR signal is not sensitive to the thermal conductivity of the film nor to its optical absorption coefficient, thus the Kapitza resistance is directly determined from single thermal parameter fits. Results of thermal resistances show the significant influence of the nature of the substrate, as well as of the presence of free electrons at the interface.

  11. Thermal conductivity and thermal rectification in graphene nanoribbons: a molecular dynamics study.

    Science.gov (United States)

    Hu, Jiuning; Ruan, Xiulin; Chen, Yong P

    2009-07-01

    We have used molecular dynamics to calculate the thermal conductivity of symmetric and asymmetric graphene nanoribbons (GNRs) of several nanometers in size (up to approximately 4 nm wide and approximately 10 nm long). For symmetric nanoribbons, the calculated thermal conductivity (e.g., approximately 2000 W/m-K at 400 K for a 1.5 nm x 5.7 nm zigzag GNR) is on the similar order of magnitude of the experimentally measured value for graphene. We have investigated the effects of edge chirality and found that nanoribbons with zigzag edges have appreciably larger thermal conductivity than nanoribbons with armchair edges. For asymmetric nanoribbons, we have found significant thermal rectification. Among various triangularly shaped GNRs we investigated, the GNR with armchair bottom edge and a vertex angle of 30 degrees gives the maximal thermal rectification. We also studied the effect of defects and found that vacancies and edge roughness in the nanoribbons can significantly decrease the thermal conductivity. However, substantial thermal rectification is observed even in the presence of edge roughness.

  12. Quantification and analysis of color stability based on thermal transient behavior in white LED lamps.

    Science.gov (United States)

    Nisa Khan, M

    2017-09-20

    We present measurement and analysis of color stability over time for two categories of white LED lamps based on their thermal management scheme, which also affects their transient lumen depreciation. We previously reported that lumen depreciation in LED lamps can be minimized by properly designing the heat sink configuration that allows lamps to reach a thermal equilibrium condition quickly. Although it is well known that lumen depreciation degrades color stability of white light since color coordinates vary with total lumen power by definition, quantification and characterization of color shifts based on thermal transient behavior have not been previously reported in literature for LED lamps. Here we provide experimental data and analysis of transient color shifts for two categories of household LED lamps (from a total of six lamps in two categories) and demonstrate that reaching thermal equilibrium more quickly provides better stability for color rendering, color temperature, and less deviation of color coordinates from the Planckian blackbody locus line, which are all very important characterization parameters of color for white light. We report for the first time that a lamp's color degradation from the turn-on time primarily depends on thermal transient behavior of the semiconductor LED chip, which experiences a wavelength shift as well as a decrease in its dominant wavelength peak value with time, which in turn degrades the phosphor conversion. For the first time, we also provide a comprehensive quantitative analysis that differentiates color degradation due to the heat rise in GaN/GaInN LED chips and subsequently the boards these chips are mounted on-from that caused by phosphor heating in a white LED module. Finally, we briefly discuss why there are some inevitable trade-offs between omnidirectionality and color and luminous output stability in current household LED lamps and what will help eliminate these trade-offs in future lamp designs.

  13. A reference device for evaluating the thermal behavior of installed multilayered wall containing a phase change material

    International Nuclear Information System (INIS)

    Pagliolico, S.L.; Sassi, G.; Cascone, Y.; Bongiovanni, R.M.

    2015-01-01

    Highlights: • Thermal analysis of installed wallboards embedding phase change material layer. • Simple devices and real conditions for thermal analysis toward a standardization. • Scanning calorimetric measurements as initial condition for data regression. • Bias correction of calorimetric measurements data by installation factors. • Practical approach to identify a reliable thermal curve for capacitive wallboards. - Abstract: Thermal inertia of lightweight building envelopes can be improved including phase change materials in multilayered wallboards. The thermal modeling of buildings for design purposes needs a robust description of the thermal properties of installed phase change materials. A standard method would improve the thermal characterization of commercial products. The aim of the study is to develop a simple methodology to obtain reliable thermal data for phase change materials integrated in multilayered wallboards. The methodology modifies differential scanning calorimetry measurements on phase change material by installation factors to obtain the apparent specific heat vs. temperature for the wallboard layer embedding phase change material. Simple cubic cells were realized as reference devices to simulate a confined environment. A dynamic model of heat transfer was developed to simulate the thermal behavior of devices. Installation factors were calculated by regression of the monitored temperatures inside and outside the devices operating under real environmental conditions. The apparent specific heat of phase change material, measured by differential scanning calorimetry at different rates, resulted in a spread of curves vs. temperature. Mean curves were used as initial condition for regression. The mean calculation method did not significantly affect the installed resulted curve. A unique curve of apparent specific heat vs. temperature best fit data measured over a wide range of experimental devices and conditions. Good regression

  14. Synthesis, characterization and thermal behavior: Gd(NO3)3.6H2O to Gd2O3

    International Nuclear Information System (INIS)

    Ghonge, Darshana K.; Sheelvantra, Smita S.; Kalekar, Bhupesh B.; Raje, Naina

    2015-01-01

    Gadolinium oxide finds its application in nuclear as well as medical industry. It has been prepared from the thermal decomposition of gadolinium nitrate hexahydrate. Surface area of the synthesized compound was measured as 19 m 2 /g. EDS data shows only the presence of gadolinium and oxygen in the synthesized compound with the Gd to O ratio as calculated for Gd 2 O 3 , suggests the formation of pure Gd 2 O 3 . XRD analysis confirms the formation of pure cubic phase Gd 2 O 3 . In the absence of any report on the thermal behavior of GdNH, present studies have been carried out to understand the decomposition mechanism using simultaneous TG - DTA - EGA measurements

  15. Thermal preference, thermal tolerance and the thermal de-pendence of digestive performance in two Phrynocephalus lizards (Agamidae), with a review of species studied

    OpenAIRE

    Yanfu QU, Hong LI, Jianfang GAO, Xuefeng XU, Xiang JI

    2011-01-01

    We reported data on thermal preference, thermal tolerance and the thermal dependence of digestive performance for two Phrynocephalus lizards (P. frontalis and P. versicolor), and compared data among lizards so far studied worldwide. Mean values for selected body temperature (Tsel) and critical thermal maximum (CTMax) were greater in P. versicolor, whereas mean values for critical thermal minimum (CTMin) did not differ between the two species. The two lizards differed in food intake, but not i...

  16. Research and development studies for predicting the thermal fatigue

    International Nuclear Information System (INIS)

    Moulin, D.; Garnier, J.; Fissolo, A.; Lejeail, Y.; Stephan, J.M.; Moinereau, D.; Masson, J.

    2001-01-01

    This paper presents some studies in development or realized in the EDF and CEA laboratories, concerning the thermal fatigue damage in nuclear reactor components. The first part presents the basic principles and the methods of lifetime prediction. The second part gives some examples on sodium loop, water loop, welded junctions resistance to thermal fatigue and tests on fatigue specimen. (A.L.B.)

  17. Synthesis and thermal decomposition study of dysprosium trifluoroacetate

    DEFF Research Database (Denmark)

    Opata, Y. A.; Grivel, J.-C.

    2018-01-01

    A study of the thermal decomposition process of dysprosium trifluoroacetate hydrate under flowing argon is presented. Thermogravimetry, differential thermal analysis, evolved gas analysis and ex-situ x-ray diffraction techniques have been employed in the investigation. Three main stages were...

  18. Thermal Decompositon Studies Of Pre-Irradiated Nickel (II) Azides ...

    African Journals Online (AJOL)

    The effect of pre-irradiation on the thermal decomposition of three samples of nickel (II) azide was studied. It was found that the rates of thermal decomposition of Ni(OH)N3 increased substantially with increase in pre-irradiation dosage. The initial reaction rates change from time-dependant nucleation law for the unirradiated ...

  19. Thermal shock behavior of W-ZrC/Sc2O3 composites under two different transient events by electron and laser irradiation

    Science.gov (United States)

    Chen, Hong-Yu; Luo, Lai-Ma; Zan, Xiang; Xu, Qiu; Tokunaga, Kazutoshi; Liu, Jia-Qin; Zhu, Xiao-Yong; Cheng, Ji-Gui; Wu, Yu-Cheng

    2018-02-01

    The transient thermal shock behaviors of W-ZrC/Sc2O3 composites with different ZrC contents were evaluated using transient thermal shock test by electron and laser beams. The effects of different ZrC doping contents on the surface morphology and thermal shock resistance of W-ZrC/Sc2O3 composites were then investigated. Similarity and difference between effects of electron and laser beam transient heat loading were also discussed in this study. Repeated heat loading resulted in thermal fatigue of the irradiated W-ZrC/Sc2O3 samples by thermal stress, leading to the rough surface morphologies with cracks. After different transient thermal tests, significant surface roughening, cracks, surface melting, and droplet ejection occurred. W-2vol.%Sc2O3 sample has superior thermal properties and greater resistance to surface modifications under transient thermal shock, and with the increasing ZrC content in W alloys, thermal shock resistance of W-Zr/Sc2O3 sample tends to be unsatisfied.

  20. Thermal behavior and decomposition of cerium(III) butanoate, pentanoate and hexanoate salts upon heating in argon

    DEFF Research Database (Denmark)

    Grivel, Jean-Claude; Suarez Guevara, Maria Josefina; Yue, Zhao

    2017-01-01

    The thermal behavior and decomposition of Ce-butanoate monohydrate (Ce(C3H7CO2)3·H2O), Ce-pentanoate (Ce(C4H9CO2)3) and Ce-hexanoate (Ce(C5H11CO2)3) were studied in a flow of argon while heating at 5 °C/min. By means of several techniques such as simultaneous TG-DTA, FTIR evolved gas analysis, in...

  1. Thermal hydraulic behavior of sub-assembly local blockage in China experiment fast reactor

    International Nuclear Information System (INIS)

    Yang Zhimin

    2000-01-01

    The geometrical parameter ratio of pitch to diameter of China Experiment Fast Reactor (CEFR) subassembly is 1,167. To address the thermal hydraulic behavior of subassembly local blockage which may be caused by deformation of cladding due to severe swelling and thermal stresses and by space swirl loosening etc., the porous numerical model and SIMPLE-P code used to solve Navier-Stokes and energy equations in porous medium was developed, and the bundle experiment with 19 pins with 24 subchannels blocked in the sodium coolant was carried on in China Institute of Atomic Energy (CIAE). The comparison of code predictions against experiments (including non-blockage and ten blockage conditions) seems well. The thermal hydraulic behavior of fuel subassembly with 61 fuel pins blockage of CEFR is calculated with SIMPLE-P code. The results indicate that the maximum temperature is 815 deg. C when the blockage area is about 37% (54 central subchannels are blocked). In this case the cladding won't be damaged and no sodium coolant boiling takes place. (author)

  2. Study on corrosion of thermal power plant condenser tubes

    Energy Technology Data Exchange (ETDEWEB)

    Mohammadi, Abdolreza Rashidi; Zhaam, Ali Akbar [Niroo Research Institute, end of Poonak Bakhtari blvd., Shahrak Ghods, Tehran (Iran)

    2004-07-01

    The aim of this investigation is to study kinds of corrosion mechanisms in thermal power plant condenser tubes. Condenser is a shell and tube heat exchanger in which cooling water flows through its tubes. While the steam from low pressure turbine passes within condenser tubes, it is condensed by cooling water. The exhausted steam from low pressure turbine is condensed on external surface of condenser tubes and heat is transferred to cooling water which flow into tubes. Tubes composition is usually copper-based alloys, stainless steel or titanium. Annual damages due to corrosion cause much cost for replacement and repairing metallic equipment and installations in electric power industry. Because of existence of different contaminants in water and steam cycle, condenser tubes surfaces are exposed to corrosion. Contaminants like oxygen, carbon dioxide, chloride ion and ammonia in water and steam cycle originate several damages such as pitting and crevice corrosion, erosion, galvanic attack, SCC, condensed corrosion, de-alloying in thermal power plant condenser. The paper first states how corrosion damage takes place in condensers and then introduces types of usual alloys used in condensers and also their corrosion behavior. In continuation, a brief explanation is presented about kinds of condenser failures due to corrosion. Then, causes and locations of different mechanisms of corrosion events on condenser tubes and effects of different parameters such as composition, temperature, chloride and sulfide ion concentration, pH, water velocity and biological precipitation are examined and finally protection methods are indicated. Also some photos of tubes specimens related to power plants are studied and described in each case of mentioned mechanisms. (authors)

  3. Thermal transport in dimerized harmonic lattices: Exact solution, crossover behavior, and extended reservoirs

    Science.gov (United States)

    Chien, Chih-Chun; Kouachi, Said; Velizhanin, Kirill A.; Dubi, Yonatan; Zwolak, Michael

    2017-01-01

    We present a method for calculating analytically the thermal conductance of a classical harmonic lattice with both alternating masses and nearest-neighbor couplings when placed between individual Langevin reservoirs at different temperatures. The method utilizes recent advances in analytic diagonalization techniques for certain classes of tridiagonal matrices. It recovers the results from a previous method that was applicable for alternating on-site parameters only, and extends the applicability to realistic systems in which masses and couplings alternate simultaneously. With this analytic result in hand, we show that the thermal conductance is highly sensitive to the modulation of the couplings. This is due to the existence of topologically induced edge modes at the lattice-reservoir interface and is also a reflection of the symmetries of the lattice. We make a connection to a recent work that demonstrates thermal transport is analogous to chemical reaction rates in solution given by Kramers' theory [Velizhanin et al., Sci. Rep. 5, 17506 (2015)], 10.1038/srep17506. In particular, we show that the turnover behavior in the presence of edge modes prevents calculations based on single-site reservoirs from coming close to the natural—or intrinsic—conductance of the lattice. Obtaining the correct value of the intrinsic conductance through simulation of even a small lattice where ballistic effects are important requires quite large extended reservoir regions. Our results thus offer a route for both the design and proper simulation of thermal conductance of nanoscale devices.

  4. Thermal performance behavior of a domestic hot water solar storage tank during consumption operation

    International Nuclear Information System (INIS)

    Dehghan, A.A.; Barzegar, A.

    2011-01-01

    Transient thermal performance behavior of a vertical storage tank of a domestic solar water heating system with a mantle heat exchanger has been investigated numerically in the discharge/consumption mode. It is assumed that the tank is initially stratified during its previous heat storing/charging operation. During the discharging period, the city cold water is fed at the bottom of the tank and hot water is extracted from its top outlet port for consumption. Meanwhile, the collector loop is assumed to be active. The conservation equations in the axis-symmetric cylindrical co-ordinate have been used and discretised by employing the finite volume method. The low Reynolds number (LRN) k - ω model is utilized for treating turbulence in the fluid. The influence of the tank Grashof number, the incoming cold fluid Reynolds number and the size of the inlet port of the heat storage tank on the transient thermal characteristics of the tank is investigated and discussed. It is found that for higher values of Grashof number, the pre-established thermal stratification is well preserved during the discharging operation mode. It is also noticed that in order to have a tank with a proper thermal performance and or have least mixing inside the tank during the consumption period, the tank inflow Reynolds number and or its inflow port diameter should be kept below certain values. In these cases, the storage tank is enabling to provide proper amount of hot water with a proper temperature for consumption purposes.

  5. On the Behavior of Different PCMs in a Hot Water Storage Tank against Thermal Demands.

    Science.gov (United States)

    Porteiro, Jacobo; Míguez, José Luis; Crespo, Bárbara; de Lara, José; Pousada, José María

    2016-03-21

    Advantages, such as thermal storage improvement, are found when using PCMs (Phase Change Materials) in storage tanks. The inclusion of three different types of materials in a 60 l test tank is studied. Two test methodologies were developed, and four tests were performed following each methodology. A thermal analysis is performed to check the thermal properties of each PCM. The distributions of the water temperatures inside the test tanks are evaluated by installing four Pt-100 sensors at different heights. A temperature recovery is observed after exposing the test tank to an energy demand. An energetic analysis that takes into account the energy due to the water temperature, the energy due to the PCM and the thermal loss to the ambient environment is also presented. The percentage of each PCM that remains in the liquid state after the energy demand is obtained.

  6. On the Behavior of Different PCMs in a Hot Water Storage Tank against Thermal Demands

    Directory of Open Access Journals (Sweden)

    Jacobo Porteiro

    2016-03-01

    Full Text Available Advantages, such as thermal storage improvement, are found when using PCMs (Phase Change Materials in storage tanks. The inclusion of three different types of materials in a 60 l test tank is studied. Two test methodologies were developed, and four tests were performed following each methodology. A thermal analysis is performed to check the thermal properties of each PCM. The distributions of the water temperatures inside the test tanks are evaluated by installing four Pt-100 sensors at different heights. A temperature recovery is observed after exposing the test tank to an energy demand. An energetic analysis that takes into account the energy due to the water temperature, the energy due to the PCM and the thermal loss to the ambient environment is also presented. The percentage of each PCM that remains in the liquid state after the energy demand is obtained.

  7. Promising and Reversible Electrolyte with Thermal Switching Behavior for Safer Electrochemical Storage Devices.

    Science.gov (United States)

    Shi, Yunhui; Zhang, Qian; Zhang, Yan; Jia, Limin; Xu, Xinhua

    2018-02-28

    A major stumbling block in large-scale adoption of high-energy-density electrochemical devices has been safety issues. Methods to control thermal runaway are limited by providing a one-time thermal protection. Herein, we developed a simple and reversible thermoresponsive electrolyte system that is efficient to shutdown the current flow according to temperature changes. The thermal management is ascribed to the thermally activated sol-gel transition of methyl cellulose solution, associated with the concentration of ions that can move between isolated chains freely or be restricted by entangled molecular chains. We studied the effect of cellulose concentration, substituent types, and operating temperature on the electrochemical performance, demonstrating an obvious capacity loss up to 90% approximately of its initial value. Moreover, this is a cost-effective approach that has the potential for use in practical electrochemical storage devices.

  8. Study of Thermal Fatigue Resistance of a Composite Coating Made by a Vacuum Fusion Sintering Method

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    Thermal fatigue behavior of a Ni-base alloy chromium carbide composite coating made by a vacuum fusion sintering method are discussed. Results show that thermal fatigue behavior is associated with cyclic upper temperature and coating thickness. As the thickness of the coating decreases, the thermal fatigue resistance increases. The thermal fatigue resistance cuts down with the thermal cyclic upper temperature rising. The crack growth rate decreases with the increase in cyclic number until crack arrests. Thermal fatigue failure was not found along the interface of the coating/matrix. The tract of thermal fatigue crack cracks along the interfaces of phases.

  9. GAPCON-THERMAL-2: a computer program for calculating the thermal behavior of an oxide fuel rod

    International Nuclear Information System (INIS)

    Beyer, C.E.; Hann, C.R.; Lanning, D.D.; Panisko, F.E.; Parchen, L.J.

    1975-11-01

    A description is presented of the computer code GAPCON THERMAL-2, a light water reactor (LWR) fuel thermal performance prediction code. GAPCON-THERMAL-2, is intended to be used as a calculational tool for reactor fuel steady-state thermal performance and to provide input for accident analyses. Some models used in the code provide best estimate as well as conservative predictions. Each of the individual models in the code is based on the best available data

  10. Numerical Model and Experimental Analysis of the Thermal Behavior of Electric Radiant Heating Panels

    Directory of Open Access Journals (Sweden)

    Giovanni Ferrarini

    2018-01-01

    Full Text Available Electric radiant heating panels are frequently selected during the design phase of residential and industrial heating systems, especially for retrofit of existing buildings, as an alternative to other common heating systems, such as radiators or air conditioners. The possibility of saving living and working space and the ease of installation are the main advantages of electric radiant solutions. This paper investigates the thermal performance of a typical electric radiant panel. A climatic room was equipped with temperature sensors and heat flow meters to perform a steady state experimental analysis. For the dynamic behavior, a mathematical model was created and compared to a thermographic measurement procedure. The results showed for the steady state an efficiency of energy transformation close to one, while in a transient thermal regime the time constant to reach the steady state condition was slightly faster than the typical ones of hydronic systems.

  11. Thermal and magnetic behavior of Angustifolia Kunth bamboo fibers covered with Fe3O4 particles

    International Nuclear Information System (INIS)

    Calvo, S.; Arias, N.P.; Giraldo, O.; Rosales-Rivera, A.; Moscoso, O.

    2012-01-01

    Several Angustifolia Kunth bamboo fibers, which have been previously treated with an alkaline solution, were coated with magnetite particles. The coating of the fibers was achieved by an in-situ co-precipitation method with Fe 2+ and Fe 3+ in NaOH or NH 4 OH. The fibers were evaluated by chemical analysis using atomic absorption (A.A.) technique, structural characterization by X-ray diffraction (XRD), thermal stability with thermo-gravimetric analysis (TGA) in nitrogen at temperature range between 23 °C and 800 °C and magnetic behavior using vibrating sample magnetometry (VSM) applying a magnetic field between -27 KOe and 27 KOe at room temperature. We found that the thermal stability and magnetization depend of the synthesis method used to cover the Angustifolia Kunth bamboo fibers. In addition, an improved magnetic response was observed when NaOH solution is used to generate the magnetite coating on the fiber surface.

  12. Study of thermal and mechanical properties of PCL films

    International Nuclear Information System (INIS)

    Siqueira, A.R. de; Vieira, A.B. da Silva; Leite, I.F.

    2016-01-01

    In the current situation of the market, it is remarkable the concern for the development of materials that offer better properties and biodegradable behavior. The scientific researches seeks development and improvement of materials for applications in products increasingly biodegradable. To do so, this research aims at obtaining films composed of polymer poly(ε-caprolactone)(PCL), aliphatic polyester synthetic and biodegradable, and silicates in layers, specifically in the State of Paraiba, prepared by the method of solution. This mixture makes it possible to form different nanostructures intercalated morphology and/or exfoliated, which therefore provides improvement in the thermal properties of the final product. After analyzing the results of X-ray diffraction (XRD) was observed predominantly exfoliated morphologies to PCL films containing different silicate content and an increase in thermal stability when there was a lower concentration of clay as thermal analysis (TGA). (author)

  13. [Pd(NH{sub 3}){sub 4}]MoO{sub 4} as a precursor for Pd–Mo-containing catalysts: Thermal behavior, X-ray analysis of the thermolysis products and related catalytic studies

    Energy Technology Data Exchange (ETDEWEB)

    Gubanov, Alexander I., E-mail: gubanov@niic.nsc.su [Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Akad. Lavrentiev Prospekt 3, 630090 Novosibirsk (Russian Federation); Novosibirsk State University, Pirogova str. 2, 630090 Novosibirsk (Russian Federation); Filatov, Eugeny Yu.; Semitut, Eugeny Yu.; Smolentsev, Anton I. [Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Akad. Lavrentiev Prospekt 3, 630090 Novosibirsk (Russian Federation); Novosibirsk State University, Pirogova str. 2, 630090 Novosibirsk (Russian Federation); Snytnikov, Pavel V.; Potemkin, Dmitry I. [Novosibirsk State University, Pirogova str. 2, 630090 Novosibirsk (Russian Federation); Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Akad. Lavrentiev Prospekt 5, 630090 Novosibirsk (Russian Federation); Korenev, Sergey V. [Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Akad. Lavrentiev Prospekt 3, 630090 Novosibirsk (Russian Federation); Novosibirsk State University, Pirogova str. 2, 630090 Novosibirsk (Russian Federation)

    2013-08-20

    Highlights: • [Pd(NH{sub 3}){sub 4}]MoO{sub 4} as a precursor for Pd–Mo-containing catalysts. • Different products are formed depending on atmosphere of thermal decomposition. • Thermolysis in He atmosphere affords finely mixed two-phase nanosized system Pd–MoO{sub 2}. • Pd–MoO{sub 2} system can be a promising catalyst both in pure and supported form. - Abstract: Compound [Pd(NH{sub 3}){sub 4}]MoO{sub 4} (1) has been synthesized and characterized by IR spectroscopy, analytical data, powder and single-crystal X-ray crystallography. Thermal properties of 1 have been examined by thermogravimetry. Powder X-ray diffraction has been applied to investigate the nanosized products of thermal decomposition of the precursor in hydrogen (Pd–Mo) and helium (Pd–MoO{sub 2}) atmospheres. Pd–Mo catalysts supported with γ-Al{sub 2}O{sub 3} have been tested in oxidation of CO and H{sub 2} mixtures.

  14. Thermal studies on some new inorganic exchange materials

    International Nuclear Information System (INIS)

    Murthy, G.S.; Satyanarayana, J.; Reddy, V.N.

    1998-01-01

    The new inorganic exchangers developed in this laboratory zirconium phosphate-ammonium molybdophosphate (ZrP-AMP), titanium phosphate-ammonium molybdophosphate (TiP-AMP) and alumina-ammonium molybdophosphate (alumina-AMP) have been investigated extensively to study the removal of Cs from high level nuclear waste. As a part of these studies thermal studies on these substances have been carried out to elucidate the information on thermal stability of these exchangers. Results obtained are presented here and discussed. (author)

  15. Prior stress exposure increases pain behaviors in a rat model of full thickness thermal injury.

    Science.gov (United States)

    Nyland, Jennifer E; McLean, Samuel A; Averitt, Dayna L

    2015-12-01

    Thermal burns among individuals working in highly stressful environments, such as firefighters and military Service Members, are common. Evidence suggests that pre-injury stress may exaggerate pain following thermal injury; however current animal models of burn have not evaluated the potential influence of pre-burn stress. This sham-controlled study evaluated the influence of prior stress exposure on post-burn thermal and mechanical sensitivity in male Sprague-Dawley rats. Rats were exposed to 20 min of inescapable swim stress or sham stress once per day for three days. Exposure to inescapable swim stress (1) increased the intensity and duration of thermal hyperalgesia after subsequent burn and (2) accelerated the onset of thermal hyperalgesia and mechanical allodynia after subsequent burn. This stress-induced exacerbation of pain sensitivity was reversed by pretreatment and concurrent treatment with the serotonin-norepinephrine reuptake inhibitor (SNRI) duloxetine. These data suggest a better understanding of mechanisms by which prior stress augments pain after thermal burn may lead to improved pain treatments for burn survivors. Copyright © 2015 Elsevier Ltd and ISBI. All rights reserved.

  16. Simulation of Missing Pellet Surface thermal behavior with 3D dynamic gap element

    International Nuclear Information System (INIS)

    Kim, Hyo Chan; Yang, Yong Sik; Koo, Yang Hyun; Kang, Chang Hak; Lee Sung Uk; Yang, Dong Yol

    2014-01-01

    Most of the fuel performance codes that are able to simulate a multidimensional analysis are used to calculate the radial temperature distribution and perform a multidimensional mechanical analysis based on a one-dimensional (1D) temperature result. The FRAPCON-FRAPTRAN code system incorporates a 1D thermal module and two-dimensional (2D) mechanical module when FEM option is activated. In this method, the multidimensional gap conductance model is not required because one-dimensional thermal analysis is carried out. On the other hand, a gap conductance model for a multi-dimension should be developed in the code to perform a multidimensional thermal analysis. ALCYONE developed by CEA introduces an equivalent heat convection coefficient that represents the multidimensional gap conductance. However, the code does not employ dynamic gap conductance which is a function of gap thickness and gap characteristics in direct. The BISON code, which has been developed by INL (Idaho National Laboratory), employed a thermo-mechanical contact method that is specifically designed for tightly-coupled implicit solutions that employ Jacobian-free solution methods. Owing to tightly-coupled implicit solutions, the BISON code solves gap conductance and gap thickness simultaneously with given boundary conditions. In this paper, 3D dynamic gap element has been proposed to resolve convergence issue and nonlinear characteristic of multidimensional gap conductance. To evaluate 3D dynamic gap element module, 3D thermomechanical module using FORTRAN77 has been implemented incorporating 3D dynamic gap element. To demonstrate effect of 3D dynamic gap element, thermal behavior of missing pellet surface (MPS) has been simulated by the developed module. LWR fuel performance codes should incorporate thermo-mechanical loop to solve gap conductance problem, iteratively. However, gap conductance in multidimensional model is difficult issue owing to its nonlinearity and convergence characteristics. In

  17. Thermal and catalytic decomposition behavior of PVC mixed plastic waste with petroleum residue

    Energy Technology Data Exchange (ETDEWEB)

    Ali, Mohammad Farhat; Siddiqui, Mohammad Nahid [Department of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran 31261 (Saudi Arabia)

    2005-08-15

    The pyrolysis and hydropyrolysis of PVC mixed plastic waste alone and with petroleum residue was carried out at 150 and 350{sup o}C under N{sub 2} gas and at 430{sup o}C under 6.5MPa H{sub 2} gas pressure. The behavior of plastic waste during thermal and catalytic decomposition has also been studied in single- and two-stage reaction processes. In the individual pyrolysis process, both the petroleum residue and polystyrene (PS) undergo more than 90% conversion to liquid and gaseous products, whereas low-density polyethylene (LDPE) and high-density polyethylene (HDPE) yielded lower conversions products, and polypropylene (PP) and polyvinyl chloride (PVC) afforded somewhere a moderate to high conversion products. In a single-stage pyrolysis reaction, PVC was processed with petroleum residue at 150 and 430{sup o}C, under N{sub 2} gas for 1h at each temperature in a glass reactor. The model PVC and waste PVC showed slight variations in the products distribution obtained from the glass reactor. In two-stage process, model PVC, vacuum gas oil (VGO) and a number of different catalysts were used in a stainless steel autoclave micro tubular reactor at 350{sup o}C under the stream of N{sub 2} gas for 1h and at 430{sup o}C under 950psi (6.5MPa) H{sub 2} pressure for the duration of 2h. Significantly, different products distributions were obtained. Among the catalysts used, fluid catalytic cracking (FCC) and hydrocracking catalysts (HC-1) were most effective in producing liquid fuel (hexane soluble) materials. The study shows that the catalytic coprocessing of PVC with VGO is a feasible process by which PVC and VGO materials can be converted into transportation fuels.

  18. An analytical study on the thermal stress of mass concrete

    International Nuclear Information System (INIS)

    Yoshida, H.; Sawada, T.; Yamazaki, M.; Miyashita, T.; Morikawa, H.; Hayami, Y.; Shibata, K.

    1983-01-01

    The thermal stress in mass concrete occurs as a result of the effect associated with the heat of hydration of the cement. Sometimes, the excessive stresses cause the cracking or other tensile failure in concrete. Therefore it is becoming necessary in the design and construction of mass concrete to predict the thermal stress. The thermal stress analysis of mass concrete requires to take account of the dependence of the elastic modulus on the age of concrete as well as the stress relaxation by creep effect. The studies of those phenomena and the analytical methods have been reported so far. The paper presents the analytical method and discusses its reliability through the application of the method to the actual structure, measuring the temperatures and the thermal stresses. The method is the time dependent thermal stress analysis based on the finite element method, which takes account of creep effect, the aging of concrete and the effect of temperature variation in time. (orig./HP)

  19. Thermal behavior and kinetics assessment of ethanol/gasoline blends during combustion by thermogravimetric analysis

    International Nuclear Information System (INIS)

    3, CEP 12.516-410 Guaratinguetá, SP (Brazil); U.T.P. – Universidad Tecnológica de Pereira, Faculty of Mechanical Engineering, Pereira, Risaralda (Colombia))" data-affiliation=" (UNESP – Univ Estadual Paulista, Campus of Guaratinguetá, Department of Energy, Laboratory of Combustion and Carbon Capture LC3, CEP 12.516-410 Guaratinguetá, SP (Brazil); U.T.P. – Universidad Tecnológica de Pereira, Faculty of Mechanical Engineering, Pereira, Risaralda (Colombia))" >Rios Quiroga, Luis Carlos; 3, CEP 12.516-410 Guaratinguetá, SP (Brazil))" data-affiliation=" (UNESP – Univ Estadual Paulista, Campus of Guaratinguetá, Department of Energy, Laboratory of Combustion and Carbon Capture LC3, CEP 12.516-410 Guaratinguetá, SP (Brazil))" >Balestieri, José 3, CEP 12.516-410 Guaratinguetá, SP (Brazil))" data-affiliation=" (UNESP – Univ Estadual Paulista, Campus of Guaratinguetá, Department of Energy, Laboratory of Combustion and Carbon Capture LC3, CEP 12.516-410 Guaratinguetá, SP (Brazil))" >Antonio Perrella; 3, CEP 12.516-410 Guaratinguetá, SP (Brazil))" data-affiliation=" (UNESP – Univ Estadual Paulista, Campus of Guaratinguetá, Department of Energy, Laboratory of Combustion and Carbon Capture LC3, CEP 12.516-410 Guaratinguetá, SP (Brazil))" >Ávila, Ivonete

    2017-01-01

    Highlights: • Kinetic parameters of thermal decomposition events were obtained. • Thermal analysis was used as a tool for understanding combustion processes. • Blends would be classified using thermogravimetric analysis technics. • Synergistic effect of ethanol mixed with gasoline was studied and defined. • Relative error and activation energy values were used to analyze the synergy. - Abstract: The use of ethanol as a fuel or as an additive blended with gasoline is very important for most countries, which aim to reduce the heavy dependence on fossil fuels and mitigate greenhouse gases emission. An increased use of ethanol-gasoline blends has placed great relevance on acquiring knowledge about their physical and chemical properties. Thus, knowledge of such properties favors a better understanding of the effect of the percentage of ethanol/gasoline blends on engine performance. Thence, the present study has established a correlation between activation energy and synergetic effects, obtained by a thermal analysis, and ethanol content in gasoline for different blends in order to use this technique as a tool to classify these blends in the process in order to obtain useful energy in spark ignition engines. For such a purpose, a kinetic study has been conducted through a simultaneous thermal analysis system – TGA (thermogravimetry analysis) and DTA (differential thermal analysis) by following the methodology of non-isothermal tests. Thermogravimetric tests were performed and fuel activation energies for gasoline, ethanol, and percentages of 5, 10, 15, 20, 25, 30, 50, and 75% (%v) ethanol mixed with gasoline, which was achieved by the model free kinetics. The analysis results suggest that the theoretical curves characteristics of the thermal decomposition of ethanol-gasoline blends are rather different due to their ethanol content. Furthermore, it was observed significant interactions and synergistic effects, especially regarding those with low ethanol

  20. Comparative physical-chemical characterization of encapsulated lipid-based isotretinoin products assessed by particle size distribution and thermal behavior analyses

    Energy Technology Data Exchange (ETDEWEB)

    Guimaraes, Carla Aiolfi, E-mail: carlaaiolfi@usp.br [Department of Pharmacy, Faculty of Pharmaceutical Sciences, University of Sao Paulo, Sao Paulo, SP 05508-000 (Brazil); Menaa, Farid [Department of Dermatology, School of Medicine Wuerzburg, Wuerzburg 97080 (Germany); Fluorotronics, Inc., 1425 Russ Bvld, San Diego Technology Incubator, San Diego, CA 92101 (United States); Menaa, Bouzid, E-mail: bouzid.menaa@gmail.com [Fluorotronics, Inc., 1425 Russ Bvld, San Diego Technology Incubator, San Diego, CA 92101 (United States); Quenca-Guillen, Joyce S. [Department of Pharmacy, Faculty of Pharmaceutical Sciences, University of Sao Paulo, Sao Paulo, SP 05508-000 (Brazil); Matos, Jivaldo do Rosario [Department of Fundamental Chemistry, Institute of Chemistry, University of Sao Paulo, Sao Paulo, SP 05508-000 (Brazil); Mercuri, Lucildes Pita [Department of Exact and Earth Sciences, Federal University of Sao Paulo, Diadema, SP 09972-270 (Brazil); Braz, Andre Borges [Department of Engineering of Mines and Oil, Polytechnical School, University of Sao Paulo, SP 05508-900 (Brazil); Rossetti, Fabia Cristina [Department of Pharmaceutical Sciences, Faculty of Pharmaceutical Sciences of Ribeirao Preto, University of Sao Paulo, Ribeirao Preto, SP 14015-120 (Brazil); Kedor-Hackmann, Erika Rosa Maria; Santoro, Maria Ines Rocha Miritello [Department of Pharmacy, Faculty of Pharmaceutical Sciences, University of Sao Paulo, Sao Paulo, SP 05508-000 (Brazil)

    2010-06-10

    Isotretinoin is the drug of choice for the management of severe recalcitrant nodular acne. Nevertheless, some of its physical-chemical properties are still poorly known. Hence, the aim of our study consisted to comparatively evaluate the particle size distribution (PSD) and characterize the thermal behavior of the three encapsulated isotretinoin products in oil suspension (one reference and two generics) commercialized in Brazil. Here, we show that the PSD, estimated by laser diffraction and by polarized light microscopy, differed between the generics and the reference product. However, the thermal behavior of the three products, determined by thermogravimetry (TGA), differential thermal (DTA) analyses and differential scanning calorimetry (DSC), displayed no significant changes and were more thermostable than the isotretinoin standard used as internal control. Thus, our study suggests that PSD analyses in isotretinoin lipid-based formulations should be routinely performed in order to improve their quality and bioavailability.

  1. On some mechanisms of the effect of thermal prehistory on the behavior of silicon parameters under irradiation

    International Nuclear Information System (INIS)

    Nejmash, V.B.; Sagan, T.R.; Tsmots', V.M.; Shakhovtsov, V.I.; Shindich, V.L.

    1991-01-01

    The effect of preliminary thermal treatment (TT) in 400-1200 degC temperature range on the behavior of Si monocrystal parameters under subsequent γ-, electron and neutron irradiation is investigated. Five mechanisms of Si thermal prehistory effect on its properties are proposed: 1) decomposition of solid solutions of impurities interacting with radiation defects (RD); 2) formation of electrically active thermal defects (TD) in concentrations wich are sufficient for a significant alteration of RD charged state; 3) origination of TD, which can efficiency as aresult of the redistribution of impurities under thermal treatment; 5) formation of clusters of electrically active TD, resulting in the disturbance of electric homogeneity of Si crystal

  2. Effect of Thermal Cycling on the Tensile Behavior of Polymer Composites Reinforced by Basalt and Carbon Fibers

    Science.gov (United States)

    Khalili, S. Mohammad Reza; Najafi, Moslem; Eslami-Farsani, Reza

    2017-01-01

    The aim of the present work was to investigate the effect of thermal cycling on the tensile behavior of three types of polymer-matrix composites — a phenolic resin reinforced with woven basalt fibers, woven carbon fibers, and hybrid basalt and carbon fibers — in an ambient environment. For this purpose, tensile tests were performed on specimens previously subjected to a certain number of thermal cycles. The ultimate tensile strength of the specimen reinforced with woven basalt fibers had by 5% after thermal cycling, but the strength of the specimen with woven carbon fibers had reduced to a value by 11% higher than that before thermal cycling.

  3. Wetting and motion behaviors of water droplet on graphene under thermal-electric coupling field

    Science.gov (United States)

    Zhang, Zhong-Qiang; Dong, Xin; Ye, Hong-Fei; Cheng, Guang-Gui; Ding, Jian-Ning; Ling, Zhi-Yong

    2015-02-01

    Wetting dynamics and motion behaviors of a water droplet on graphene are characterized under the electric-thermal coupling field using classical molecular dynamics simulation method. The water droplet on graphene can be driven by the temperature gradient, while the moving direction is dependent on the electric field intensity. Concretely, the water droplet on graphene moves from the low temperature region to the high temperature region for the relatively weak electric field intensity. The motion acceleration increases with the electric field intensity on graphene, whereas the moving direction switches when the electric field intensity increases up to a threshold. The essence is the change from hydrophilic to hydrophobic for the water droplet on graphene at a threshold of the electric field intensity. Moreover, the driven force of the water droplet caused by the overall oscillation of graphene has important influence on the motion behaviors. The results are helpful to control the wettability of graphene and further develop the graphene-based fluidic nanodevices.

  4. Frequency and Thermal Behavior of Acoustic Absorption in ɛ-GaSe Crystals

    Science.gov (United States)

    Dzhafarova, S. Z.

    2018-04-01

    The paper presents results of measuring acoustic absorption in ɛ-GaSe crystals. The absorption of a longitudinal wave which propagates normal to the crystal layers, quadratically depends on frequency. However, it does not depend on temperature, i.e. it displays an Akhiezer behavior although its absolute value considerably exceeds the expected. The analysis of the frequency and thermal behavior of absorption of piezoelectric waves propagating along the layers, includes the deduction of contribution made by the interaction between waves and charge carriers. This analysis shows the linear dependence between the lattice absorption of these waves and the frequency. The linear frequency and weak temperature dependences of the acoustic absorption characterize the additional ultra-Akhiezer absorption in glasses. In our case, it can be caused by various polytypes forming in GaSe crystals which differ merely in a mutual arrangement of layers.

  5. Adaptive Thermal Comfort in Japanese Houses during the Summer Season: Behavioral Adaptation and the Effect of Humidity

    Directory of Open Access Journals (Sweden)

    Hom B. Rijal

    2015-09-01

    Full Text Available In order to clarify effect of humidity on the room temperatures reported to be comfortable, an occupant thermal comfort and behavior survey was conducted for five summers in the living rooms and bedrooms of residences in the Kanto region of Japan. We have collected 13,525 thermal comfort votes from over 239 residents of 120 homes, together with corresponding measurements of room temperature and humidity of the air. The residents were generally well-satisfied with the thermal environment of their houses, with or without the use of air-conditioning, and thus were well-adapted to their thermal conditions. The humidity was found to have very little direct effect on the comfort temperature. However, the comfort temperature was strongly related to the reported skin moisture. Behavioral adaptation such as window opening and fan use increase air movement and improve thermal comfort.

  6. Study on durability for thermal cycle of planar SOFC

    Energy Technology Data Exchange (ETDEWEB)

    Ando, Motoo; Nakata, Kei-ichi; Wakayama, Sin-ichi [Tonen Corp., Saitama (Japan)] [and others

    1996-12-31

    TONEN CORPORATION has developed planar type SOFC since 1986. We demonstrated the output of 1.3 kW in 1991 and 5.1 kW in 1995. Simultaneously we have studied how to raise electric efficiency and reliability utilizing hydrogen and propane as fuel. Durability for thermal cycle is one of the most important problems of planar SOFC to make it more practical. The planar type SOFC is made up of separator, zirconia electrolyte and glass sealant. The thermal expansion of these components are expected to be the same value, however, they still possess small differences. In this situation, a thermal cycle causes a thermal stress due to the difference of the cell components and is often followed by a rupture in cell components, therefore, the analysis of the thermal stress should give us much useful information. The thermal cycle process consists of a heating up and cooling down procedure. Zirconia electrolyte is not bonded to the separator under the condition of the initial heating up procedure, and glass sealant becomes soft or melts and glass seals spaces between the zirconia and separator. The glass sealant becomes harder with the cooling down procedure. Moreover, zirconia is tightly bonded with separator below a temperature which is defined as a constraint temperature and thermal stress also occurs. This indicates that the heating up process relaxes the thermal stress and the cooling down increases it. In this paper, we simulated dependence of the stress on the sealing configuration, thermal expansion of sealant and constraint temperature of sealant glass. Furthermore, we presented SOFC electrical properties after a thermal cycle.

  7. Block Copolymers of Macrolactones/Small Lactones by a “Catalyst-Switch” Organocatalytic Strategy. Thermal Properties and Phase Behavior

    KAUST Repository

    Ladelta, Viko

    2018-03-16

    Poly(macrolactones) (PMLs) can be considered as biodegradable alternatives of polyethylene; however, controlling the ring-opening polymerization (ROP) of macrolactone (ML) monomers remains a challenge due to their low ring strain. To overcome this problem, phosphazene (t-BuP4), a strong superbase, has to be used as catalyst. Unfortunately, the one-pot sequential block copolymerization of MLs with small lactones (SLs) is impossible since the high basicity of t-BuP4 promotes both intra- and intermolecular transesterification reactions, thus leading to random copolymers. By using ROP and the “catalyst-switch” strategy [benzyl alcohol, t-BuP4/neutralization with diphenyl phosphate/(t-BuP2)], we were able to synthesize different well-defined PML-b-PSL block copolymers (MLs: dodecalactone, ω-pentadecalactone, and ω-hexadecalactone; SLs: δ-valerolactone and ε-caprolactone). The thermal properties and the phase behavior of these block copolymers were studied by differential scanning calorimetry and X-ray diffraction spectroscopy. This study shows that the thermal properties and phase behavior of PMLs-b-PSLs are largely influenced by the PMLs block if PMLs components constitute the majority of the block copolymers.

  8. Block Copolymers of Macrolactones/Small Lactones by a “Catalyst-Switch” Organocatalytic Strategy. Thermal Properties and Phase Behavior

    KAUST Repository

    Ladelta, Viko; Kim, Joey D.; Bilalis, Panagiotis; Gnanou, Yves; Hadjichristidis, Nikolaos

    2018-01-01

    Poly(macrolactones) (PMLs) can be considered as biodegradable alternatives of polyethylene; however, controlling the ring-opening polymerization (ROP) of macrolactone (ML) monomers remains a challenge due to their low ring strain. To overcome this problem, phosphazene (t-BuP4), a strong superbase, has to be used as catalyst. Unfortunately, the one-pot sequential block copolymerization of MLs with small lactones (SLs) is impossible since the high basicity of t-BuP4 promotes both intra- and intermolecular transesterification reactions, thus leading to random copolymers. By using ROP and the “catalyst-switch” strategy [benzyl alcohol, t-BuP4/neutralization with diphenyl phosphate/(t-BuP2)], we were able to synthesize different well-defined PML-b-PSL block copolymers (MLs: dodecalactone, ω-pentadecalactone, and ω-hexadecalactone; SLs: δ-valerolactone and ε-caprolactone). The thermal properties and the phase behavior of these block copolymers were studied by differential scanning calorimetry and X-ray diffraction spectroscopy. This study shows that the thermal properties and phase behavior of PMLs-b-PSLs are largely influenced by the PMLs block if PMLs components constitute the majority of the block copolymers.

  9. Thermal fatigue behavior of C/C composites modified by SiC-MoSi2-CrSi2 coating

    International Nuclear Information System (INIS)

    Chu Yanhui; Fu Qiangang; Li Hejun; Li Kezhi

    2011-01-01

    Highlights: → The low-density C/C composites were modified by SiC-MoSi 2 -CrSi 2 multiphase coating by pack cementation. → The thermal fatigue behavior of the modified C/C composites was studied after undergoing thermal cycling for 20 times under the different environments. → The decrease of the flexural strength of the modified C/C composites during thermal cycle in air was primarily attributed to the partial oxidation of the modified C/C samples. - Abstract: Carbon/carbon (C/C) composites were modified by SiC-MoSi 2 -CrSi 2 multiphase coating by pack cementation, and their thermal fatigue behavior under thermal cycling in Ar and air environments was investigated. The modified C/C composites were characterized by scanning electron microscopy and X-ray diffraction. Results of tests show that, after 20-time thermal cycles between 1773 K and room temperature in Ar environment, the flexural strength of modified C/C samples decreased lightly and the percentage of remaining strength was 94.92%. While, after thermal cycling between 1773 K and room temperature in air for 20 times, the weight loss of modified C/C samples was 5.1%, and the flexural strength of the modified C/C samples reduced obviously and the percentage of remaining strength was only 75.22%. The fracture mode of modified C/C samples changed from a brittle behavior to a pseudo-plastic one as the service environment transformed from Ar to air. The decrease of the flexural strength during thermal cycle in air was primarily attributed to the partial oxidation of modified C/C samples.

  10. Thermal stability of the French nuclear waste glass - long term behavior modeling

    International Nuclear Information System (INIS)

    Orlhac, X.

    2000-01-01

    The thermal stability of the French nuclear waste glass was investigated experimentally and by modeling to predict its long-term evolution at low temperature. The crystallization mechanisms were analyzed by studying devitrification in the supercooled liquid. Three main crystalline phases were characterized (CaMoO 4 , CeCO 2 , ZnCr 2 O 4 ). Their crystallisation was TO 4.24 wt%, due to the low concentration of the constituent elements. The nucleation and growth curves showed that platinoid elements catalysed nucleation but did not affect growth, which was governed by volume diffusion. The criteria of classic nucleation theory were applied to determine the thermodynamic and diffusional activation energies. Viscosity measurements illustrate the analogy between the activation energy of viscous flow and diffusion, indicating control of crystallization by viscous flow phenomena. The combined action of nucleation and growth was assessed by TTT plots, revealing a crystallization equilibrium line that enables the crystallized fractions to be predicted over the long term. The authors show that hetero-genetics catalyze the transformation without modifying the maximum crystallized fraction. A kinetic model was developed to describe devitrification in the glass based on the nucleation and growth curves alone. The authors show that the low-temperature growth exhibits scale behavior (between time and temperature) similar to thermo-rheological simplicity. The analogy between the resulting activation energy and that of the viscosity was used to model growth on the basis of viscosity. After validation with a simplified (BaO 2 SiO 2 ) glass, the model was applied to the containment glass. The result indicated that the glass remained completely vitreous after a cooling scenario with the one measured at the glass core. Under isothermal conditions, several million years would be required to reach the maximum theoretical crystallization fraction. (author)

  11. Effect of carbon nanospheres on shape stabilization and thermal behavior of phase change materials for thermal energy storage

    International Nuclear Information System (INIS)

    Mehrali, Mohammad; Tahan Latibari, Sara; Mehrali, Mehdi; Mahlia, Teuku Meurah Indra; Cornelis Metselaar, Hendrik Simon

    2014-01-01

    Highlights: • Introducing novel form-stable PCM of stearic acid (SA)/carbon nanospheres (CNSs). • The highest stabilized SA content is 83 wt% in the SA/CNS composites. • Increasing thermal conductivity of composite phase change material with high amount of latent heat. - Abstract: Stearic acid (SA) is one of the main phase change materials (PCMs) for medium temperature thermal energy storage systems. In order to stabilize the shape and enhance the thermal conductivity of SA, the effects of adding carbon nanospheres (CNSs) as a carbon nanofiller were examined experimentally. The maximum mass fraction of SA retained in CNSs was found as 80 wt% without the leakage of SA in a melted state, even when it was heated over the melting point of SA. The dropping point test shows that there was clearly no liquid leakage through the phase change process at the operating temperature range of the composite PCMs. The thermal stability and thermal properties of composite PCMs were investigated with a thermogravimetric analyzer (TGA) and differential scanning calorimeter (DSC), respectively. The thermal conductivity of the SA/CNS composite was determined by the laser flash method. The thermal conductivity at 35 °C increased about 105% for the highest loading of CNS (50 wt%). The thermal cycling test proved that form-stable composite PCMs had good thermal reliability and chemical durability after 1000 cycles of melting and freezing, which is advantageous for latent heat thermal energy storage (LHTES)

  12. Thermal treatment of petroleum contaminated soils - A case study

    International Nuclear Information System (INIS)

    Bubier, T.W.; Bilello. C.M.

    1993-01-01

    Thermal treatment is a cost-effective treatment method for removing chemicals from contaminated soils. However, detailed applicability studies are lacking. The goals of this paper are to (1) present the results of a thermal treatment study and (2) discuss the specific elements which must be evaluated prior to determining whether thermal treatment is a feasible option for a remediation project. Results of data collected during a pilot study involving thermal treatment of petroleum contaminated soils at a Marine Terminal are presented. The pilot study consisted of thermally treating the C8 through C40 + (gasoline, kerosene, diesel, motor oil, bunker fuel, etc.) hydrocarbon contaminated soils at treatment temperatures ranging from 250 degrees Fahrenheit (degree F) up to 550 degrees F. The low-temperature thermal treatment unit consisted of a rotary kiln with a temperature capacity of approximately 600 degrees F, a baghouse, and a catalytic oxidizer. The soil was monitored for concentrations of petroleum hydrocarbons and volatile organic compounds before and after treatment. The results of the pilot study were used to determine if thermal treatment technology is a cost-efficient and effective option of remediating the estimated 300,000 tons of petroleum contaminated soil to acceptable cleanup levels. The low-temperature thermal treatment pilot study was effective in desorbing the short chain hydrocarbons (gasoline and diesel) but was not effective in desorbing the long-chain petroleum hydrocarbons, such as motor oils and bunker fuels, from the soil. This was primarily due to the boiling points of motor oil and bunker fuels which were higher than the temperature capacity of the pilot study treatment equipment. Additional factors that influenced the effectiveness of the desorption process included configuration of the treatment equipment, soil moisture content, soil particle size, and type and concentration of petroleum hydrocarbons

  13. Parametric study of closed wet cooling tower thermal performance

    Science.gov (United States)

    Qasim, S. M.; Hayder, M. J.

    2017-08-01

    The present study involves experimental and theoretical analysis to evaluate the thermal performance of modified Closed Wet Cooling Tower (CWCT). The experimental study includes: design, manufacture and testing prototype of a modified counter flow forced draft CWCT. The modification based on addition packing to the conventional CWCT. A series of experiments was carried out at different operational parameters. In view of energy analysis, the thermal performance parameters of the tower are: cooling range, tower approach, cooling capacity, thermal efficiency, heat and mass transfer coefficients. The theoretical study included develops Artificial Neural Network (ANN) models to predicting various thermal performance parameters of the tower. Utilizing experimental data for training and testing, the models simulated by multi-layer back propagation algorithm for varying all operational parameters stated in experimental test.

  14. Electrochemical and Thermal Studies of Prepared Conducting Chitosan Biopolymer Film

    International Nuclear Information System (INIS)

    Hlaing Hlaing Oo; Kyaw Naing; Kyaw Myo Naing; Tin Tin Aye; Nyunt Wynn

    2005-09-01

    In this paper, chitosan based conducting bipolymer films were prepared by casting and solvent evaporating technique. All prepared chitosan films were of pale yellow colour, transparent, and smooth. Sulphuric acid was chosen as the cross-linking agent. It enhanced conduction pathway in cross-linked chitosan films. Mechanical properties, solid-state, and thermal behavior of prepared chitosan fimls were studied by means of a material testing machine, powder X-ray diffractometry (XRD), thermogravimetric analysis (TG-DTG), and differential scanning calorimetry (DSC). By the XRD diffraction pattern, high molecular weight of chitosan product indicates the semi-crystalline nature, but the prepared chitosan film and doped chitosan film indicate significantly lower in crystallinity prove which of the amorphous characteristics. In addition, DSC thermogram of pure chitosan film exhibited exothermic peak around at 300 C, indicating polymer decomposition of chitosan molecules in chitosan films. Furthermore, these DSC thermograms clearly showed that while pure chitosan film display exothermal decomposition, the doped chitosan films mainly endothermic characteristics. The ionic conductivity of doped chitosan films were in the order of 10 to 10 S cm , which is in the range of semi-conductor. These results showed that cross-linked chitoson films may be used as polymer electrolyte film to fabricate solid state electrochemical cells

  15. Inverse thermal analysis method to study solidification in cast iron

    DEFF Research Database (Denmark)

    Dioszegi, Atilla; Hattel, Jesper

    2004-01-01

    Solidification modelling of cast metals is widely used to predict final properties in cast components. Accurate models necessitate good knowledge of the solidification behaviour. The present study includes a re-examination of the Fourier thermal analysis method. This involves an inverse numerical...... solution of a 1-dimensional heat transfer problem connected to solidification of cast alloys. In the analysis, the relation between the thermal state and the fraction solid of the metal is evaluated by a numerical method. This method contains an iteration algorithm controlled by an under relaxation term...... inverse thermal analysis was tested on both experimental and simulated data....

  16. Thermal dewetting behavior of polystyrene composite thin films with organic-modified inorganic nanoparticles.

    Science.gov (United States)

    Kubo, Masaki; Takahashi, Yosuke; Fujii, Takeshi; Liu, Yang; Sugioka, Ken-ichi; Tsukada, Takao; Minami, Kimitaka; Adschiri, Tadafumi

    2014-07-29

    The thermal dewetting of polystyrene composite thin films with oleic acid-modified CeO2 nanoparticles prepared by the supercritical hydrothermal synthesis method was investigated, varying the nanoparticle concentration (0-30 wt %), film thickness (approximately 50 and 100 nm), and surface energy of silanized silicon substrates on which the composite films were coated. The dewetting behavior of the composite thin films during thermal annealing was observed by an optical microscope. The presence of nanoparticles in the films affected the morphology of dewetting holes, and moreover suppressed the dewetting itself when the concentration was relatively high. It was revealed that there was a critical value of the surface energy of the substrate at which the dewetting occurred. In addition, the spatial distributions of nanoparticles in the composite thin films before thermal annealing were investigated using AFM and TEM. As a result, we found that most of nanoparticles segregated to the surface of the film, and that such distributions of nanoparticles contribute to the stabilization of the films, by calculating the interfacial potential of the films with nanoparticles.

  17. Crossover behavior of the thermal conductance and Kramers’ transition rate theory

    Science.gov (United States)

    Velizhanin, Kirill A.; Sahu, Subin; Chien, Chih-Chun; Dubi, Yonatan; Zwolak, Michael

    2015-12-01

    Kramers’ theory frames chemical reaction rates in solution as reactants overcoming a barrier in the presence of friction and noise. For weak coupling to the solution, the reaction rate is limited by the rate at which the solution can restore equilibrium after a subset of reactants have surmounted the barrier to become products. For strong coupling, there are always sufficiently energetic reactants. However, the solution returns many of the intermediate states back to the reactants before the product fully forms. Here, we demonstrate that the thermal conductance displays an analogous physical response to the friction and noise that drive the heat current through a material or structure. A crossover behavior emerges where the thermal reservoirs dominate the conductance at the extremes and only in the intermediate region are the intrinsic properties of the lattice manifest. Not only does this shed new light on Kramers’ classic turnover problem, this result is significant for the design of devices for thermal management and other applications, as well as the proper simulation of transport at the nanoscale.

  18. Thermal Stress Behavior of Micro- and Nano-Size Aluminum Films

    International Nuclear Information System (INIS)

    Hanabusa, T.; Kusaka, K.; Nishida, M.

    2008-01-01

    In-situ observation of thermal stresses in thin films deposited on silicon substrate was made by X-ray and synchrotron radiation. Specimens prepared in this experiment were micro- and nano-size thin aluminum films with and without passivation film. The thickness of the film was 1 micrometer for micro-size films and 10, 20 and 50 nanometer for nano-size films. The stress measurement in micro-size films was made by X-ray radiation whereas the measurement of nano-size films was made by synchrotron radiation. Residual stress measurement revealed tensile stresses in all as-deposited films. Thermal stresses were measured in a series of heating- and cooling-stage. Thermal stress behavior of micro-size films revealed hysteresis loop during a heating and cooling process. The width of a hysteresis loop was larger in passivated film that unpassivated film. No hysteresis loops were observed in nano-size films with SiO 2 passivation. Strengthning mechanism in thin films was discussed on a passivation film and a film thickness

  19. Thermal expansion in 3d-metal Prussian Blue Analogs-A survey study

    International Nuclear Information System (INIS)

    Adak, Sourav; Daemen, Luke L.; Hartl, Monika; Williams, Darrick; Summerhill, Jennifer; Nakotte, Heinz

    2011-01-01

    We present a comprehensive study of the structural properties and the thermal expansion behavior of 17 different Prussian Blue Analogs (PBAs) with compositions M II 3 [(M') III (CN) 6 ] 2 .nH 2 O and M II 2 [Fe II (CN) 6 ].nH 2 O, where M II =Mn, Fe, Co, Ni, Cu and Zn, (M') III =Co, Fe and n is the number of water molecules, which range from 5 to 18 for these compounds. The PBAs were synthesized via standard chemical precipitation methods, and temperature-dependent X-ray diffraction studies were performed in the temperature range between -150 deg. C (123 K) and room-temperature. The vast majority of the studied PBAs were found to crystallize in cubic structures of space groups Fm3-bar m, F4-bar 3m and Pm3-bar m. The temperature dependence of the lattice parameters was taken to compute an average coefficient of linear thermal expansion in the studied temperature range. Of the 17 compounds, 9 display negative values for the average coefficient of linear thermal expansion, which can be as large as 39.7x 1 0 -6 K -1 for Co 3 [Co(CN) 6 ] 2 .12H 2 O. All of the M II 3 [Co III (CN) 6 ] 2 .nH 2 O compounds show negative thermal expansion behavior, which correlates with the Irving-Williams series for metal complex stability. The thermal expansion behavior for the PBAs of the M II 3 [Fe III (CN) 6 ] 2 .nH 2 O family are found to switch between positive (for M=Mn, Co, Ni) and negative (M=Cu, Zn) behavior, depending on the choice of the metal cation (M). On the other hand, all of the M II 2 [Fe II (CN) 6 ].nH 2 O compounds show positive thermal expansion behavior. - Graphical Abstract: The structure of Prussian Blue analogs (PBAs) consists of two types of metal centered octahedral units connected by cyanide ligand. Lattice and interstitial water molecules are present in these framework structures. All the PBAs of the M 3 [Co(CN) 6 ] 2 .nH 2 O family show negative thermal expansion (NTE) behavior. The lattice parameters and magnitude of NTE correlates inversely with the Irving

  20. Outdoor test method to determine the thermal behavior of solar domestic water heating systems

    Energy Technology Data Exchange (ETDEWEB)

    Garcia-Valladares, O.; Pilatowsky, I. [Centro de Investigacion en Energia, Universidad Nacional Autonoma de Mexico, Privada Xochicalco, s/n, Colonia Centro, 62580 Temixco, Morelos (Mexico); Ruiz, V. [Escuela Tecnica Superior de Ingenieros, Universidad de Sevilla, Camino de los Descubrimientos, s/n, Isla de la Cartuja, 41092 Sevilla, Espana (Spain)

    2008-07-15

    The dynamics of the market, the generation of new promotion programs, fiscal incentives and many other factors are to be considered for the massive application of solar domestic water heating systems (SDWHS) mainly of the compact thermosiphon type, makes it necessary to choose simple and inexpensive procedure tests that permit to know their characteristic thermal behaviors without an official standard being necessary. Moreover, it allows the comparison among systems and offers enough and reliable information to consumers and manufacturers. In most developing countries, an official national standard for SDWHS is not available, therefore it is necessary to adopt an international test procedure in which the cost and time of implementation is very important. In this work, a simple and inexpensive test method to determine the thermal behavior of SDWHS is proposed. Even though these procedure tests do not have an official standard structure they permit, by comparing different solar systems under identical solar, ambient, and initial conditions, the experimental determination of: (a) the maximum available volume of water for solar heating; (b) water temperature increment and available thermal energy at the end of the day; (c) temperature profiles (stratification) and the average temperature in the storage tank after it is homogenized; (d) the average global thermal efficiency; (e) water temperature decrement and energy lost overnight; and (f) the relationship between hot water volume and solar collector area as function of the average heating temperature. An additional proposed test permits to know the heat losses caused by the reverse flow in the collector loop. These tests will be carried out independently of the configuration between the solar collector and the storage tank, the way the fluid circulates and the type of thermal exchange. The results of this procedure test can be very useful, firstly, for the local solar manufacturers' equipment in order to design

  1. Outdoor test method to determine the thermal behavior of solar domestic water heating systems

    International Nuclear Information System (INIS)

    Garcia-Valladares, O.; Pilatowsky, I.; Ruiz, V.

    2008-01-01

    The dynamics of the market, the generation of new promotion programs, fiscal incentives and many other factors are to be considered for the massive application of solar domestic water heating systems (SDWHS) mainly of the compact thermosiphon type, makes it necessary to choose simple and inexpensive procedure tests that permit to know their characteristic thermal behaviors without an official standard being necessary. Moreover, it allows the comparison among systems and offers enough and reliable information to consumers and manufacturers. In most developing countries, an official national standard for SDWHS is not available, therefore it is necessary to adopt an international test procedure in which the cost and time of implementation is very important. In this work, a simple and inexpensive test method to determine the thermal behavior of SDWHS is proposed. Even though these procedure tests do not have an official standard structure they permit, by comparing different solar systems under identical solar, ambient, and initial conditions, the experimental determination of: (a) the maximum available volume of water for solar heating; (b) water temperature increment and available thermal energy at the end of the day; (c) temperature profiles (stratification) and the average temperature in the storage tank after it is homogenized; (d) the average global thermal efficiency; (e) water temperature decrement and energy lost overnight; and (f) the relationship between hot water volume and solar collector area as function of the average heating temperature. An additional proposed test permits to know the heat losses caused by the reverse flow in the collector loop. These tests will be carried out independently of the configuration between the solar collector and the storage tank, the way the fluid circulates and the type of thermal exchange. The results of this procedure test can be very useful, firstly, for the local solar manufacturers' equipment in order to design and

  2. Thermal behavior of an asphalt pavement in the laboratory and in the parking lot.

    Science.gov (United States)

    Martinkauppi, J B; Mäkiranta, A; Kiijärvi, J; Hiltunen, E

    2015-01-01

    The urban, constructed areas are full of buildings and different kinds of pavements and have a noticeable lack of trees and flora. These areas are accumulating the heat from the Sun, people, vehicles, and constructions. One interesting heat collector is the asphalt pavement. How does the heat transfer to different layers under the pavement or does it? What are the temperatures under the pavement in Finland where the winter can be pretty hard? How can those temperatures be measured accurately? These are the main questions this paper gives the preliminary answers to. First the thermal behavior of asphalt and the layers beneath are researched in the laboratory and then the measurement field is bored and dug in the parking in the Western coast of Finland, 63°5'45'' N. Distributed temperature sensing method was found to be a good choice for temperature measurements. Thermal behavior of pavement has been monitored in different layers and the preliminary results have been published here. The goal of this research is to assess the applicability of asphalt pavements for heat energy collection.

  3. Effects of thermal cracking on the dynamic behavior of reinforced concrete containment structures

    International Nuclear Information System (INIS)

    Castellani, A.; Fontana, A.

    1977-01-01

    Thick concrete cylinders acted on by horizontal dynamic forces are analyzed. According to the dimensions they may simulate a containment structure or a reactor core support. In particular, the effects of thermal cracking on their dynamic behavior are investigated; up to now the tests are confined to vertical cracking which is likely to appear under a thermal gradient of approximately 35 to 45 0 C on the wall. At higher temperatures, the number and extension of these cracks increase, till a stabilized crack pattern is reached. This is the main subject of the present investigation. The horizontal forces call for a shear transmission along the crack. According to the literature, shear stresses can be transmitted by aggregate interlock, by shear friction, and by the dowel action provided by horizontal reinforcement. These effects may accomodate the shear transmission along the crack required to resist a given distribution of horizontal forces. On the other hand, the shear rigidity of the structure may be negatively affected by the cracking, depending on the crack width and distribution and on the amplitude of the applied forces. In this case a dynamic behavior of the structure is to be analyzed with proper consideration to the existing cracking

  4. Photo-response behavior of organic transistors based on thermally annealed semiconducting diketopyrrolopyrrole core

    Science.gov (United States)

    Tarsoly, Gergely; Pyo, Seungmoon

    2018-06-01

    We report the opto-electrical response of organic field-effect transistors based on a thin-film of a semiconducting diketopyrrolopyrrole (DPP) core, a popular building block for molecular semiconductors, and a polymeric gate dielectric. The thin-film of the DPP core was thermally annealed at different temperatures under N2 atmosphere to investigate the relationship between the annealing temperature and the electrical properties of the device. The results showed that the annealing process induces morphological changes in the thin film, and properly controlling the thermal annealing conditions can enhance the device performance. In addition, we also investigated in detail the photo-response behaviors by analyzing the responsivity (R) of the device with the optimally annealed DPP-core thin film under two light illumination conditions by considering the irradiance absorbed by the thin film instead of the total irradiance of the light source. We found that the proposed model could lead to a light-source-independent description of the photo-response behavior of the device, and which can be used for other applications.

  5. Analysis of Thermal-Hydraulic Behavior of CMT in the SMART-ITL Facility

    Energy Technology Data Exchange (ETDEWEB)

    Jeon, Byong Guk; Bae, Hwang; Ryu, Sung-Uk; Ryu, Hyobong; Byun, Sun-Joon; Yi, Sung-Jae; Park, Hyun-Sik [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-10-15

    SMART, an integral small modular reactor, received a standard design approval in 2012 and now extends its safety features through replacing active safety injection pumps by passive safety injection systems: core makeup tanks (CMT) and safety injection tanks (SIT). SMART-ITL has been built in a full height scale and 1/49 area and power scale. One train of CMT and SIT has been installed and their thermal-hydraulic behaviors have been identified through a series of tests. In this paper, initial condensation characteristics as well as force balance around the CMT will be discussed for a representative test. PSIS are added into SMART for better treatment of accidents with prolonged station blackout. In the SMART-ITL, the CMT and SIT are installed to evaluate their performance and a series of tests have been conducted. In this paper, the thermal-hydraulic behavior of CMT is addressed based on the experimental data, especially focusing on the issues of fierce condensation after opening of the isolation valve and driving force balance around the CMT.

  6. Effect of sun radiation on the thermal behavior of distribution transformer

    International Nuclear Information System (INIS)

    Hajidavalloo, Ebrahim; Mohamadianfard, Mohamad

    2010-01-01

    Performance and life of oil-immersed distribution transformers are strongly dependent on the oil temperature. Transformers, working in regions with high temperature and high solar radiation, usually suffer from excessive heat in summers which results in their early failures. In this paper, the effect of sun radiation on the transformer was investigated by using experimental and analytical methods. Transformer oil temperature was measured in two different modes, with and without sun shield. Effects of different parameters such as direct and indirect solar radiation on the thermal behavior of the transformer were mathematically modeled and the results were compared with experimental findings. Agreements between the experimental and numerical results show that the model can reasonably predict thermal behavior of the transformer. It was found that a sun shield has an important effect on the oil temperature reduction in summer which could be as high as 7 deg. C depending on the load ratio. The amount of temperature reduction by sun shield reduces as the load ratio of transformer increases. By installing a sun shield and reducing oil temperature, transformer life could be increased up to 24% in average.

  7. Analysis of Thermal-Hydraulic Behavior of CMT in the SMART-ITL Facility

    International Nuclear Information System (INIS)

    Jeon, Byong Guk; Bae, Hwang; Ryu, Sung-Uk; Ryu, Hyobong; Byun, Sun-Joon; Yi, Sung-Jae; Park, Hyun-Sik

    2015-01-01

    SMART, an integral small modular reactor, received a standard design approval in 2012 and now extends its safety features through replacing active safety injection pumps by passive safety injection systems: core makeup tanks (CMT) and safety injection tanks (SIT). SMART-ITL has been built in a full height scale and 1/49 area and power scale. One train of CMT and SIT has been installed and their thermal-hydraulic behaviors have been identified through a series of tests. In this paper, initial condensation characteristics as well as force balance around the CMT will be discussed for a representative test. PSIS are added into SMART for better treatment of accidents with prolonged station blackout. In the SMART-ITL, the CMT and SIT are installed to evaluate their performance and a series of tests have been conducted. In this paper, the thermal-hydraulic behavior of CMT is addressed based on the experimental data, especially focusing on the issues of fierce condensation after opening of the isolation valve and driving force balance around the CMT

  8. Thermal Behavior of an Asphalt Pavement in the Laboratory and in the Parking Lot

    Directory of Open Access Journals (Sweden)

    J. B. Martinkauppi

    2015-01-01

    Full Text Available The urban, constructed areas are full of buildings and different kinds of pavements and have a noticeable lack of trees and flora. These areas are accumulating the heat from the Sun, people, vehicles, and constructions. One interesting heat collector is the asphalt pavement. How does the heat transfer to different layers under the pavement or does it? What are the temperatures under the pavement in Finland where the winter can be pretty hard? How can those temperatures be measured accurately? These are the main questions this paper gives the preliminary answers to. First the thermal behavior of asphalt and the layers beneath are researched in the laboratory and then the measurement field is bored and dug in the parking in the Western coast of Finland, 63°5′45′′ N. Distributed temperature sensing method was found to be a good choice for temperature measurements. Thermal behavior of pavement has been monitored in different layers and the preliminary results have been published here. The goal of this research is to assess the applicability of asphalt pavements for heat energy collection.

  9. Thermal Decomposition Behaviors and Burning Characteristics of AN/Nitramine-Based Composite Propellant

    Science.gov (United States)

    Naya, Tomoki; Kohga, Makoto

    2015-04-01

    Ammonium nitrate (AN) has attracted much attention due to its clean burning nature as an oxidizer. However, an AN-based composite propellant has the disadvantages of low burning rate and poor ignitability. In this study, we added nitramine of cyclotrimethylene trinitramine (RDX) or cyclotetramethylene tetranitramine (HMX) as a high-energy material to AN propellants to overcome these disadvantages. The thermal decomposition and burning rate characteristics of the prepared propellants were examined as the ratio of AN and nitramine was varied. In the thermal decomposition process, AN/RDX propellants showed unique mass loss peaks in the lower temperature range that were not observed for AN or RDX propellants alone. AN and RDX decomposed continuously as an almost single oxidizer in the AN/RDX propellant. In contrast, AN/HMX propellants exhibited thermal decomposition characteristics similar to those of AN and HMX, which decomposed almost separately in the thermal decomposition of the AN/HMX propellant. The ignitability was improved and the burning rate increased by the addition of nitramine for both AN/RDX and AN/HMX propellants. The increased burning rates of AN/RDX propellants were greater than those of AN/HMX. The difference in the thermal decomposition and burning characteristics was caused by the interaction between AN and RDX.

  10. Thermal loading study for FY 1996. Volume 2

    International Nuclear Information System (INIS)

    1996-01-01

    The primary objective of this study was to provide recommendations for Mined Geologic Disposal System requirements affected by thermal loading that will provide sufficient definition to facilitate development of design concepts and support life cycle cost determinations. The study reevaluated and/or redefined selected thermal goals used for design and are currently contained in the requirements documents or the Controlled Design Assumption Document. The study provided recommendations as to what, if any, actions (such as edge loading and limiting of the heat variability between waste packages) are needed and must be accommodated in the design. Additionally, the study provided recommendations as to what alternative thermal loads should be maintained for continued flexibility. This report contains seven appendices: Technical basis for evaluation of thermal goals below the potential nuclear was repository at Yucca Mountain; Thermal-mechanical evaluation of the 200 C drift-wall temperature goal; Evaluation of ground stability and support; Coupled ventilation and hydrothermal evaluations; Heat flow and temperature calculations for continuously ventilated emplacement drifts; Thermal management using aging and/or waste package selection; and Waste stream evaluations

  11. Thermal Management Tools for Propulsion System Trade Studies and Analysis

    Science.gov (United States)

    McCarthy, Kevin; Hodge, Ernie

    2011-01-01

    Energy-related subsystems in modern aircraft are more tightly coupled with less design margin. These subsystems include thermal management subsystems, vehicle electric power generation and distribution, aircraft engines, and flight control. Tighter coupling, lower design margins, and higher system complexity all make preliminary trade studies difficult. A suite of thermal management analysis tools has been developed to facilitate trade studies during preliminary design of air-vehicle propulsion systems. Simulink blocksets (from MathWorks) for developing quasi-steady-state and transient system models of aircraft thermal management systems and related energy systems have been developed. These blocksets extend the Simulink modeling environment in the thermal sciences and aircraft systems disciplines. The blocksets include blocks for modeling aircraft system heat loads, heat exchangers, pumps, reservoirs, fuel tanks, and other components at varying levels of model fidelity. The blocksets have been applied in a first-principles, physics-based modeling and simulation architecture for rapid prototyping of aircraft thermal management and related systems. They have been applied in representative modern aircraft thermal management system studies. The modeling and simulation architecture has also been used to conduct trade studies in a vehicle level model that incorporates coupling effects among the aircraft mission, engine cycle, fuel, and multi-phase heat-transfer materials.

  12. Urban area thermal monitoring: Liepaja case study using satellite and aerial thermal data

    Science.gov (United States)

    Gulbe, Linda; Caune, Vairis; Korats, Gundars

    2017-12-01

    The aim of this study is to explore large (60 m/pixel) and small scale (individual building level) temperature distribution patterns from thermal remote sensing data and to conclude what kind of information could be extracted from thermal remote sensing on regular basis. Landsat program provides frequent large scale thermal images useful for analysis of city temperature patterns. During the study correlation between temperature patterns and vegetation content based on NDVI and building coverage based on OpenStreetMap data was studied. Landsat based temperature patterns were independent from the season, negatively correlated with vegetation content and positively correlated with building coverage. Small scale analysis included spatial and raster descriptor analysis for polygons corresponding to roofs of individual buildings for evaluating insulation of roofs. Remote sensing and spatial descriptors are poorly related to heat consumption data, however, thermal aerial data median and entropy can help to identify poorly insulated roofs. Automated quantitative roof analysis has high potential for acquiring city wide information about roof insulation, but quality is limited by reference data quality and information on building types, and roof materials would be crucial for further studies.

  13. Effects of Covalent Functionalization of MWCNTs on the Thermal Properties and Non-Isothermal Crystallization Behaviors of PPS Composites

    Directory of Open Access Journals (Sweden)

    Myounguk Kim

    2017-09-01

    Full Text Available In this study, a PPS/MWCNTs composite was prepared with poly(phenylene sulfide (PPS, as well as pristine and covalent functionalized multi-walled carbon nanotubes (MWCNTs via melt-blending techniques. Moreover, the dispersion of the MWCNTs on the PPS matrix was improved by covalent functionalization as can be seen from a Field-Emission Scanning Electron Microscope (FE-SEM images. The thermal properties of the PPS/MWCNTs composites were characterized using a thermal conductivity analyzer, and a differential scanning calorimeter (DSC. To analyze the crystallization behavior of polymers under conditions similar with those in industry, the non-isothermal crystallization behaviors of the PPS/MWCNTs composites were confirmed using various kinetic equations, such as the modified Avrami equation and Avrami-Ozawa combined equation. The crystallization rate of PPS/1 wt % pristine MWCNTs composite (PPSP1 was faster because of the intrinsic nucleation effect of the MWCNTs. However, the crystallization rates of the composites containing covalently-functionalized MWCNTs were slower than PPSP1 because of the destruction of the MWCNTs graphitic structure via covalent functionalization. Furthermore, the activation energies calculated by Kissinger’s method were consistently decreased by covalent functionalization.

  14. Thermal profiles, crystallization behaviors and microstructure of diacylglycerol-enriched palm oil blends with diacylglycerol-enriched palm olein.

    Science.gov (United States)

    Xu, Yayuan; Zhao, Xiaoqing; Wang, Qiang; Peng, Zhen; Dong, Cao

    2016-07-01

    To elucidate the possible interaction mechanisms between DAG-enriched oils, this study investigated how mixtures of DAG-enriched palm-based oils influenced the phase behavior, thermal properties, crystallization behaviors and the microstructure in binary fat blends. DAG-enriched palm oil (PO-DAGE) was blended with DAG-enriched palm olein (POL-DAGE) in various percentages (0%, 10%, 30%, 50%, 70%, 90%, 100%). Based on the observation of iso-solid diagram and phase diagram, the binary mixture of PO-DAGE/POL-DAGE showed a better compatibility in comparison with their corresponding original blends. DSC thermal profiles exhibited that the melting and crystallization properties of PO-DAGE/POL-DAGE were distinctively different from corresponding original blends. Crystallization kinetics revealed that PO-DAGE/POL-DAGE blends displayed a rather high crystallization rate and exhibited no spherulitic crystal growth. From the results of polarized light micrographs, PO-DAGE/POL-DAGE blends showed more dense structure with very small needle-like crystals than PO/POL. X-ray diffraction evaluation revealed when POL-DAGE was added in high contents to PO-DAGE, above 30%, β-polymorph dominated, and the mount of β' forms crystals was decreasing. Copyright © 2016 Elsevier Ltd. All rights reserved.

  15. Prestressed concrete reactor vessel thermal cylinder model study

    International Nuclear Information System (INIS)

    Callahan, J.P.; Canonico, D.A.; Richardson, M.; Corum, J.M.; Dodge, W.G.; Robinson, G.C.; Whitman, G.D.

    1977-01-01

    The thermal cylinder experiment was designed both to provide information for evaluating the capability of analytical methods to predict the time-dependent stress-strain behavior of a 1 / 6 -scale model of the barrel section of a single-cavity prestressed concrete reactor vessel and to demonstrate the structural behavior under design and off-design thermal conditions. The model was a thick-walled cylinder having a height of 1.22 m, a thickness of 0.46 m, and an outer diameter of 2.06 m. It was prestressed both axially and circumferentially and subjected to 4.83 MPa internal pressure together with a thermal crossfall imposed by heating the inner surface to 338.8 K and cooling the outer surface to 297.1 K. The initial 460 days of testing were divided into time periods that simulated prestressing, heatup, reactor operation, and shutdown. At the conclusion of the simulated operating period, the model was repressurized and subjected to localized heating at 505.4 K for 84 days to produce an off-design hot-spot condition. Comparisons of experimental data with calculated values obtained using the SAFE-CRACK finite-element computer program showed that the program was capable of predicting time-dependent behavior in a vessel subjected to normal operating conditions, but that it was unable to accurately predict the behavior during off-design hot-spot heating. Readings made using a neutron and gamma-ray backscattering moisture probe showed little, if any, migration of moisture in the concrete cross section. Destructive examination indicated that the model maintained its basic structural integrity during localized hot-spot heating

  16. A study on male homosexual behavior.

    Science.gov (United States)

    Ramachandran, R; Viswanath, Sudha; Elangovan, P; Saravanan, N

    2015-01-01

    Male homosexual behavior carries a high risk of transmitting sexually transmitted infections (STIs). Ignorance regarding the associated high risk, indulgence inspite of no natural homosexual orientation and not using protective barrier methods can affect the sexual health of adolescents and adults. (1) To assess the proportion of men who have sex with men (MSM) having a natural homosexual orientation compared to those who had acquired the homosexual behavior initially under various circumstances (such as due to certain misconceptions, fear of having heterosexual contact, peer pressure, and influence of alcohol). (2) To assess the level of awareness regarding increased risk of transmission of STIs associated with homosexual behavior and regarding protective barrier methods. After obtaining consent from the subjects, questionnaire - based interview used for obtaining data for this observational (cross-sectional) study. (1) Of the 50 subjects, only about 25% had interest in homosexual behavior prior to initial episode. (2) About 50% subjects indulged in homosexual behavior due to lack/fear of having heterosexual contact. (3) About 60% subjects believed that homosexual behavior carried relatively lower risk of acquiring STIs and 68% subjects have had unprotected contact. (4) About 70% subjects had only acquired this behavior and nearly 60% subjects were interested in heterosexual marriage and not interested in further homosexual behavior. (1) Homosexuality is a natural orientation in some and an acquired behavior in the rest. (2) If homosexual behavior is acquired, due to misconceptions, then imparting sex education and awareness regarding involved risks, and the importance of protective barrier methods will prevent ignorance driven behavior. For those with natural homosexual orientation, the importance of protective barrier methods in homosexual behavior needs emphasis.

  17. Experimental Study on Thermal Conductivity of Self-Compacting Concrete with Recycled Aggregate

    Directory of Open Access Journals (Sweden)

    María Fenollera

    2015-07-01

    Full Text Available The research focuses on the use of recycled aggregate (RA, from waste pieces generated during production in precast plants for self-compacting concrete (SCC manufactured with a double sustainable goal: recycle manufacturing waste (consumption and improvement of the thermal properties of the manufactured product (energy efficiency. For this purpose, a mechanical study to ensure technical feasibility of the concrete obtained has been conducted, as well as a thermal analysis of recycled SCC specimens of 50 N/mm2 resistance, with different RA doses (0%, 20%, 50% and 100%. The main parameters that characterize a SCC in both states, fresh (slump-flow and hard (compressive strength, have been tested; also, a qualitative analysis of the thermal conductivity using infrared thermography (IRT and quantitative analysis with heat flow meter at three temperatures 20 °C, 25 °C and 30 °C have been performed. The results suggest the existence of two different thermal behaviors: concretes with 0% and 20% of RA, and on the other hand concretes with 50% and 100% of RA. It has also demonstrated the validity of the IRT as sampling technique in estimating the thermal behavior of materials having reduced range of variation in parameters.

  18. Experimental Study on Thermal Conductivity of Self-Compacting Concrete with Recycled Aggregate

    Science.gov (United States)

    Fenollera, María; Míguez, José Luis; Goicoechea, Itziar; Lorenzo, Jaime

    2015-01-01

    The research focuses on the use of recycled aggregate (RA), from waste pieces generated during production in precast plants for self-compacting concrete (SCC) manufactured with a double sustainable goal: recycle manufacturing waste (consumption) and improvement of the thermal properties of the manufactured product (energy efficiency). For this purpose, a mechanical study to ensure technical feasibility of the concrete obtained has been conducted, as well as a thermal analysis of recycled SCC specimens of 50 N/mm2 resistance, with different RA doses (0%, 20%, 50% and 100%). The main parameters that characterize a SCC in both states, fresh (slump-flow) and hard (compressive strength), have been tested; also, a qualitative analysis of the thermal conductivity using infrared thermography (IRT) and quantitative analysis with heat flow meter at three temperatures 20 °C, 25 °C and 30 °C have been performed. The results suggest the existence of two different thermal behaviors: concretes with 0% and 20% of RA, and on the other hand concretes with 50% and 100% of RA. It has also demonstrated the validity of the IRT as sampling technique in estimating the thermal behavior of materials having reduced range of variation in parameters. PMID:28793449

  19. Experimental Study on Thermal Conductivity of Self-Compacting Concrete with Recycled Aggregate.

    Science.gov (United States)

    Fenollera, María; Míguez, José Luis; Goicoechea, Itziar; Lorenzo, Jaime

    2015-07-20

    The research focuses on the use of recycled aggregate (RA), from waste pieces generated during production in precast plants for self-compacting concrete (SCC) manufactured with a double sustainable goal: recycle manufacturing waste (consumption) and improvement of the thermal properties of the manufactured product (energy efficiency). For this purpose, a mechanical study to ensure technical feasibility of the concrete obtained has been conducted, as well as a thermal analysis of recycled SCC specimens of 50 N/mm² resistance, with different RA doses (0%, 20%, 50% and 100%). The main parameters that characterize a SCC in both states, fresh (slump-flow) and hard (compressive strength), have been tested; also, a qualitative analysis of the thermal conductivity using infrared thermography (IRT) and quantitative analysis with heat flow meter at three temperatures 20 °C, 25 °C and 30 °C have been performed. The results suggest the existence of two different thermal behaviors: concretes with 0% and 20% of RA, and on the other hand concretes with 50% and 100% of RA. It has also demonstrated the validity of the IRT as sampling technique in estimating the thermal behavior of materials having reduced range of variation in parameters.

  20. Thermal Behavior of Doubly-Fed Induction Generator Wind Turbine System during Balanced Grid Fault

    DEFF Research Database (Denmark)

    Zhou, Dao; Blaabjerg, Frede; Lau, Mogens

    2014-01-01

    Ride-through capabilities of the doubly-fed induction generator (DFIG) during grid fault have been studied a lot. However, the thermal performance of the power device during this transient period is seldom investigated. In this paper, the dynamic model for the DFIG and the influence of the rotor...

  1. Behavior of Avirulent Yersinia pestis in Liquid Whole Egg as Affected by Antimicrobials and Thermal Pasteurization

    Science.gov (United States)

    Yersinia spp. is a psychrotrophic bacterium that can grow at temperatures as low as minus two degrees Celsius, and is known to contaminate shell eggs in the United States and shell eggs and liquid egg in South America. A study was performed to determine the thermal sensitivity of avirulent Yersinia...

  2. Studies on thermal properties and thermal control effectiveness of a new shape-stabilized phase change material with high thermal conductivity

    International Nuclear Information System (INIS)

    Cheng Wenlong; Liu Na; Wu Wanfan

    2012-01-01

    In order to overcome the difficulty of conventional phase change materials (PCMs) in packaging, the shape-stabilized PCMs are proposed to be used in the electronic device thermal control. However, the conventional shape-stabilized PCMs have the drawback of lower thermal conductivity, so a new shape-stabilized PCM with high thermal conductivity, which is suitable for thermal control of electronic devices, is prepared. The thermal properties of n-octadecane-based shape-stabilized PCM are tested and analyzed. The heat storage/release performance is studied by numerical simulation. Its thermal control effect for electronic devices is also discussed. The results show that the expanded graphite (EG) can greatly improve the thermal conductivity of the material with little effect on latent heat and phase change temperature. When the mass fraction of EG is 5%, thermal conductivity has reached 1.76 W/(m K), which is over 4 times than that of the original one. Moreover, the material has larger latent heat and good thermal stability. The simulation results show that the material can have good heat storage/release performance. The analysis of the effect of thermal parameters on thermal control effect for electronic devices provides references to the design of phase change thermal control unit. - Highlights: ► A new shape-stabilized PCM with higher thermal conductivity is prepared. ► The material overcomes the packaging difficulty of traditional PCMs used in thermal control unit. ► The EG greatly improves thermal conductivity with little effect on latent heat. ► The material has high thermal stability and good heat storage/release performance. ► The effectiveness of the material for electronic device thermal control is proved.

  3. A Thermal Test System for Helmet Cooling Studies

    Directory of Open Access Journals (Sweden)

    Shaun Fitzgerald

    2018-02-01

    Full Text Available One of the primary causes of discomfort to both irregular and elite cyclists is heat entrapment by a helmet resulting in overheating and excessive sweating of the head. To accurately assess the cooling effectiveness of bicycle helmets, a heated plastic thermal headform has been developed. The construction consists of a 3D-printed headform of low thermal conductivity with an internal layer of high thermal mass that is heated to a constant uniform temperature by an electrical heating element. Testing is conducted in a wind tunnel where the heater power remains constant and the resulting surface temperature distribution is directly measured by 36 K-type thermocouples embedded within the surface of the head in conjunction with a thermal imaging camera. Using this new test system, four bicycle helmets were studied in order to measure their cooling abilities and to identify ‘hot spots’ where cooling performance is poor.

  4. Installation of aerosol behavior model into multi-dimensional thermal hydraulic analysis code AQUA

    International Nuclear Information System (INIS)

    Kisohara, Naoyuki; Yamaguchi, Akira

    1997-12-01

    The safety analysis of FBR plant system for sodium leak phenomena needs to evaluate the deposition of the aerosol particle to the components in the plant, the chemical reaction of aerosol to humidity in the air and the effect of the combustion heat through aerosol to the structural component. For this purpose, ABC-INTG (Aerosol Behavior in Containment-INTeGrated Version) code has been developed and used until now. This code calculates aerosol behavior in the gas area of uniform temperature and pressure by 1 cell-model. Later, however, more detailed calculation of aerosol behavior requires the installation of aerosol model into multi-cell thermal hydraulic analysis code AQUA. AQUA can calculate the carrier gas flow, temperature and the distribution of the aerosol spatial concentration. On the other hand, ABC-INTG can calculate the generation, deposition to the wall and flower, agglomeration of aerosol particle and figure out the distribution of the aerosol particle size. Thus, the combination of these two codes enables to deal with aerosol model coupling the distribution of the aerosol spatial concentration and that of the aerosol particle size. This report describes aerosol behavior model, how to install the aerosol model to AQUA and new subroutine equipped to the code. Furthermore, the test calculations of the simple structural model were executed by this code, appropriate results were obtained. Thus, this code has prospect to predict aerosol behavior by the introduction of coupling analysis with multi-dimensional gas thermo-dynamics for sodium combustion evaluation. (J.P.N.)

  5. Integrated thermal treatment system study -- Phase 2 results. Revision 1

    Energy Technology Data Exchange (ETDEWEB)

    Feizollahi, F.; Quapp, W.J.

    1996-02-01

    This report presents the second phase of a study on thermal treatment technologies. The study consists of a systematic assessment of nineteen thermal treatment alternatives for the contact-handled mixed low-level waste (MLLW) currently stored in the US Department of Energy complex. The treatment alternatives consist of widely varying technologies for safely destroying the hazardous organic components, reducing the volume, and preparing for final disposal of the MLLW. The alternatives considered in Phase 2 were innovative thermal treatments with nine types of primary processing units. Other variations in the study examined the effect of combustion gas, air pollution control system design, and stabilization technology for the treatment residues. The Phase 1 study examined ten initial thermal treatment alternatives. The Phase 2 systems were evaluated in essentially the same manner as the Phase 1 systems. The alternatives evaluated were: rotary kiln, slagging kiln, plasma furnace, plasma gasification, molten salt oxidation, molten metal waste destruction, steam gasification, Joule-heated vitrification, thermal desorption and mediated electrochemical oxidation, and thermal desorption and supercritical water oxidation. The quantities, and physical and chemical compositions, of the input waste used in the Phase 2 systems differ from those in the Phase 1 systems, which were based on a preliminary waste input database developed at the onset of the Integrated Thermal Treatment System study. The inventory database used in the Phase 2 study incorporates the latest US Department of Energy information. All systems, both primary treatment systems and subsystem inputs, have now been evaluated using the same waste input (2,927 lb/hr). 28 refs., 88 figs., 41 tabs.

  6. Integrated thermal treatment system study -- Phase 2 results. Revision 1

    International Nuclear Information System (INIS)

    Feizollahi, F.; Quapp, W.J.

    1996-02-01

    This report presents the second phase of a study on thermal treatment technologies. The study consists of a systematic assessment of nineteen thermal treatment alternatives for the contact-handled mixed low-level waste (MLLW) currently stored in the US Department of Energy complex. The treatment alternatives consist of widely varying technologies for safely destroying the hazardous organic components, reducing the volume, and preparing for final disposal of the MLLW. The alternatives considered in Phase 2 were innovative thermal treatments with nine types of primary processing units. Other variations in the study examined the effect of combustion gas, air pollution control system design, and stabilization technology for the treatment residues. The Phase 1 study examined ten initial thermal treatment alternatives. The Phase 2 systems were evaluated in essentially the same manner as the Phase 1 systems. The alternatives evaluated were: rotary kiln, slagging kiln, plasma furnace, plasma gasification, molten salt oxidation, molten metal waste destruction, steam gasification, Joule-heated vitrification, thermal desorption and mediated electrochemical oxidation, and thermal desorption and supercritical water oxidation. The quantities, and physical and chemical compositions, of the input waste used in the Phase 2 systems differ from those in the Phase 1 systems, which were based on a preliminary waste input database developed at the onset of the Integrated Thermal Treatment System study. The inventory database used in the Phase 2 study incorporates the latest US Department of Energy information. All systems, both primary treatment systems and subsystem inputs, have now been evaluated using the same waste input (2,927 lb/hr). 28 refs., 88 figs., 41 tabs

  7. Naturalistic Study of Truck Following Behavior

    Science.gov (United States)

    2016-04-01

    Volpe conducted the Naturalistic study of truck following behavior to gain a better understanding of how trucks follow other vehicles in the real world, with the ultimate goal of supporting the Federal Highway Administration in the development of aut...

  8. Behavioral corporate governance : four empirical studies

    NARCIS (Netherlands)

    van der Laan, G.

    2009-01-01

    This thesis consists of studies of corporate governance from a behavioral perspective. The chapters are about trust between chief executive officers (CEOs) and board chairpersons, asymmetric effects of corporate social responsibility on corporate financial performance, compliance with corporate

  9. Behavioral control and reward sensitivity in adolescents’ risk taking behavior : A longitudinal TRAILS study

    NARCIS (Netherlands)

    Peeters, M.; Oldehinkel, Tineke; Vollebergh, W.A.M.

    2017-01-01

    Neurodevelopmental theories of risk behavior hypothesize that low behavioral control in combination with high reward sensitivity explains adolescents' risk behavior. However, empirical studies examining this hypothesis while including actual risk taking behavior in adolescence are lacking. In this

  10. Behavioral Control and Reward Sensitivity in Adolescents' Risk Taking Behavior : A Longitudinal TRAILS Study

    NARCIS (Netherlands)

    Peeters, Margot; Oldehinkel, Tineke; Vollebergh, Wilma

    2017-01-01

    Neurodevelopmental theories of risk behavior hypothesize that low behavioral control in combination with high reward sensitivity explains adolescents' risk behavior. However, empirical studies examining this hypothesis while including actual risk taking behavior in adolescence are lacking. In this

  11. Thermal loading study for FY 1996. Volume 1

    International Nuclear Information System (INIS)

    1996-01-01

    The primary objective of this study was to provide recommendations for Mined Geologic Disposal System requirements affected by thermal loading that will provide sufficient definition to facilitate development of design concepts and support life cycle cost determinations. The study reevaluated and/or redefined selected thermal goals used for design and are currently contained in the requirements documents or the Controlled Design Assumption Document. The study provided recommendations as to what, if any, actions (such as edge loading and limiting of the heat variability between waste packages) are needed and must be accommodated in the design. Additionally, the study provided recommendations as to what alternative thermal loads should be maintained for continued flexibility. Section 1 provides the study objective, background, scope, and organization of the report. Section 2 documents the requirements and standards to include quality assurance (QA) requirements, any requirements used or evaluated, and the inputs and assumptions considered. Section 3 provides the analysis and recommendations for the thermal goals reevaluation. Section 4 discusses the evaluation of edge loading and provides conclusions. Section 5 provides the analyses done to establish recommendations as to what requirements need to be implemented to either limit or manage the amount of heat output variability that may occur. Section 6 discusses alternate thermal loadings; Section 7 provides the study conclusions and recommendations; Section 8 provides the references, standards, and regulations; and Section 9 contains the acronym list

  12. Non-destructive thermal wave method applied to study thermal properties of fast setting time endodontic cement

    International Nuclear Information System (INIS)

    Picolloto, A. M.; Mariucci, V. V. G.; Szpak, W.; Medina, A. N.; Baesso, M. L.; Astrath, N. G. C.; Astrath, F. B. G.; Bento, A. C.; Santos, A. D.; Moraes, J. C. S.

    2013-01-01

    The thermal wave method is applied for thermal properties measurement in fast endodontic cement (CER). This new formula is developed upon using Portland cement in gel and it was successfully tested in mice with good biocompatibility and stimulated mineralization. Recently, thermal expansion and setting time were measured, conferring to this material twice faster hardening than the well known Angelus Mineral trioxide aggregate (MTA) the feature of fast hardening (∼7 min) and with similar thermal expansion (∼12 μstrain/ °C). Therefore, it is important the knowledge of thermal properties like thermal diffusivity, conductivity, effusivity in order to match thermally the tissue environment upon its application in filling cavities of teeth. Photothermal radiometry technique based on Xe illumination was applied in CER disks 600 μm thick for heating, with prepared in four particle sizes (25, 38, 45, and 53) μm, which were added microemulsion gel with variation volumes (140, 150, 160, and 170) μl. The behavior of the thermal diffusivity CER disks shows linear decay for increase emulsion volume, and in contrast, thermal diffusivity increases with particles sizes. Aiming to compare to MTA, thermal properties of CER were averaged to get the figure of merit for thermal diffusivity as (44.2 ± 3.6) × 10 −3 cm 2 /s, for thermal conductivity (228 ± 32) mW/cm K, the thermal effusivity (1.09 ± 0.06) W s 0.5 /cm 2 K and volume heat capacity (5.2 ± 0.7) J/cm 3 K, which are in excellent agreement with results of a disk prepared from commercial MTA-Angelus (grain size < 10 μm using 57 μl of distilled water)

  13. Non-destructive thermal wave method applied to study thermal properties of fast setting time endodontic cement

    Science.gov (United States)

    Picolloto, A. M.; Mariucci, V. V. G.; Szpak, W.; Medina, A. N.; Baesso, M. L.; Astrath, N. G. C.; Astrath, F. B. G.; Santos, A. D.; Moraes, J. C. S.; Bento, A. C.

    2013-11-01

    The thermal wave method is applied for thermal properties measurement in fast endodontic cement (CER). This new formula is developed upon using Portland cement in gel and it was successfully tested in mice with good biocompatibility and stimulated mineralization. Recently, thermal expansion and setting time were measured, conferring to this material twice faster hardening than the well known Angelus Mineral trioxide aggregate (MTA) the feature of fast hardening (˜7 min) and with similar thermal expansion (˜12 μstrain/ °C). Therefore, it is important the knowledge of thermal properties like thermal diffusivity, conductivity, effusivity in order to match thermally the tissue environment upon its application in filling cavities of teeth. Photothermal radiometry technique based on Xe illumination was applied in CER disks 600 μm thick for heating, with prepared in four particle sizes (25, 38, 45, and 53) μm, which were added microemulsion gel with variation volumes (140, 150, 160, and 170) μl. The behavior of the thermal diffusivity CER disks shows linear decay for increase emulsion volume, and in contrast, thermal diffusivity increases with particles sizes. Aiming to compare to MTA, thermal properties of CER were averaged to get the figure of merit for thermal diffusivity as (44.2 ± 3.6) × 10-3 cm2/s, for thermal conductivity (228 ± 32) mW/cm K, the thermal effusivity (1.09 ± 0.06) W s0.5/cm2 K and volume heat capacity (5.2 ± 0.7) J/cm3 K, which are in excellent agreement with results of a disk prepared from commercial MTA-Angelus (grain size < 10 μm using 57 μl of distilled water).

  14. Non-destructive thermal wave method applied to study thermal properties of fast setting time endodontic cement

    Energy Technology Data Exchange (ETDEWEB)

    Picolloto, A. M.; Mariucci, V. V. G.; Szpak, W.; Medina, A. N.; Baesso, M. L.; Astrath, N. G. C.; Astrath, F. B. G.; Bento, A. C., E-mail: acbento@uem.br [Departamento de Física, Grupo de Espectroscopia Fotoacústica e Fototérmica, Universidade Estadual de Maringá – UEM, Av. Colombo 5790, 87020-900 Maringá, Paraná (Brazil); Santos, A. D.; Moraes, J. C. S. [Departamento de Física e Química, Universidade Estadual Paulista Júlio de Mesquita Filho – UNESP, Av. Brasil 56, 15385-000 Ilha Solteira, SP (Brazil)

    2013-11-21

    The thermal wave method is applied for thermal properties measurement in fast endodontic cement (CER). This new formula is developed upon using Portland cement in gel and it was successfully tested in mice with good biocompatibility and stimulated mineralization. Recently, thermal expansion and setting time were measured, conferring to this material twice faster hardening than the well known Angelus Mineral trioxide aggregate (MTA) the feature of fast hardening (∼7 min) and with similar thermal expansion (∼12 μstrain/ °C). Therefore, it is important the knowledge of thermal properties like thermal diffusivity, conductivity, effusivity in order to match thermally the tissue environment upon its application in filling cavities of teeth. Photothermal radiometry technique based on Xe illumination was applied in CER disks 600 μm thick for heating, with prepared in four particle sizes (25, 38, 45, and 53) μm, which were added microemulsion gel with variation volumes (140, 150, 160, and 170) μl. The behavior of the thermal diffusivity CER disks shows linear decay for increase emulsion volume, and in contrast, thermal diffusivity increases with particles sizes. Aiming to compare to MTA, thermal properties of CER were averaged to get the figure of merit for thermal diffusivity as (44.2 ± 3.6) × 10{sup −3} cm{sup 2}/s, for thermal conductivity (228 ± 32) mW/cm K, the thermal effusivity (1.09 ± 0.06) W s{sup 0.5}/cm{sup 2} K and volume heat capacity (5.2 ± 0.7) J/cm{sup 3} K, which are in excellent agreement with results of a disk prepared from commercial MTA-Angelus (grain size < 10 μm using 57 μl of distilled water)

  15. The oxidation behavior of classical thermal barrier coatings exposed to extreme temperature

    Directory of Open Access Journals (Sweden)

    Alina DRAGOMIRESCU

    2017-03-01

    Full Text Available Thermal barrier coatings (TBC are designed to protect metal surfaces from extreme temperatures and improve their resistance to oxidation during service. Currently, the most commonly used systems are those that have the TBC structure bond coat (BC / top coat (TC layers. The top coat layer is a ceramic layer. Oxidation tests are designed to identify the dynamics of the thermally oxide layer (TGO growth at the interface of bond coat / top coat layers, delamination mechanism and the TBC structural changes induced by thermal conditions. This paper is a short study on the evolution of aluminum oxide protective layer along with prolonged exposure to the testing temperature. There have been tested rectangular specimens of metal super alloy with four surfaces coated with a duplex thermal barrier coating system. The specimens were microscopically and EDAX analyzed before and after the tests. In order to determine the oxide type, the samples were analyzed using X-ray diffraction. The results of the investigation are encouraging for future studies. The results show a direct relationship between the development of the oxide layer and long exposure to the test temperature. Future research will focus on changing the testing temperature to compare the results.

  16. Thermal Adaptation Methods of Urban Plaza Users in Asia's Hot-Humid Regions: A Taiwan Case Study.

    Science.gov (United States)

    Wu, Chen-Fa; Hsieh, Yen-Fen; Ou, Sheng-Jung

    2015-10-27

    Thermal adaptation studies provide researchers great insight to help understand how people respond to thermal discomfort. This research aims to assess outdoor urban plaza conditions in hot and humid regions of Asia by conducting an evaluation of thermal adaptation. We also propose that questionnaire items are appropriate for determining thermal adaptation strategies adopted by urban plaza users. A literature review was conducted and first hand data collected by field observations and interviews used to collect information on thermal adaptation strategies. Item analysis--Exploratory Factor Analysis (EFA) and Confirmatory Factor Analysis (CFA)--were applied to refine the questionnaire items and determine the reliability of the questionnaire evaluation procedure. The reliability and validity of items and constructing process were also analyzed. Then, researchers facilitated an evaluation procedure for assessing the thermal adaptation strategies of urban plaza users in hot and humid regions of Asia and formulated a questionnaire survey that was distributed in Taichung's Municipal Plaza in Taiwan. Results showed that most users responded with behavioral adaptation when experiencing thermal discomfort. However, if the thermal discomfort could not be alleviated, they then adopted psychological strategies. In conclusion, the evaluation procedure for assessing thermal adaptation strategies and the questionnaire developed in this study can be applied to future research on thermal adaptation strategies adopted by urban plaza users in hot and humid regions of Asia.

  17. Thermally stimulated luminescence studies in combustion ...

    Indian Academy of Sciences (India)

    Wintec

    irradiated aluminum oxide samples were studied. A broad PL ... formance, especially when doped with carbon. A good amount of work on TSL of ... to the spectrograph through optical fibre for detection and analysis. The TSL measurements ...

  18. Study and development of new dosemeters for thermal neutrons

    International Nuclear Information System (INIS)

    Urena N, F.

    1998-01-01

    An alanine-boron compound, alanine hydroborate, was synthesized and chemically characterized to be used for thermal neutrons fluence measurements. The synthesis of the compound was made by reacting the amino acid alanine with boric acid in three different media: acidic, neutral and alkaline. Physicochemical analysis showed that the alkaline medium is favorable for the synthesis of the alanine hydroborate. The compound was evaluated as a thermal neutron fluence detector by the detection of the free radical yield upon neutron thermal irradiation by Electron Paramagnetic Resonance (EPR). The present work also studies the EPR-signal response of the three preparations to thermal neutron irradiation (φ = 5 x 10 7 n/cm 2 -s). The following EPR signal parameters of the samples were investigated: peak-to-peak signal intensity vs. thermal neutron fluence Φ = φ Δt ; where Δt = 1, 5, 10, 20, 40, 60, 80, 90, 100, 110 and 120 h. , peak-to-peak signal intensity vs. microwave power, signal fading; repeatability, batch homogeneity, stability and zero dose response. It is concluded that these new products could be used in thermal neutron fluence estimations. (Author)

  19. Integrated thermal treatment systems study. Internal review panel report

    International Nuclear Information System (INIS)

    Cudahy, J.; Escarda, T.; Gimpel, R.

    1995-04-01

    The U.S. Department of Energy (DOE) Office of Technology Development (OTD) commissioned two studies to evaluate nineteen thermal treatment technologies for treatment of DOE mixed low-level waste. These studies were called the Integrated Thermal Treatment System (ITTS) Phase I and Phase II. With the help of the DOE Office of Environmental Management (EM) Mixed Waste Focus Group, OTD formed an ITTS Internal Review Panel to review and comment on the ITTS studies. This Panel was composed of scientists and engineers from throughout the DOE complex, the U.S. Environmental Protection Agency, the California EPA, and private experts. The Panel met from November 15-18, 1994 to review the ITTS studies and to make recommendations on the most promising thermal treatment systems for DOE mixed low-level wastes and on research and development necessary to prove the performance of the technologies. This report describes the findings and presents the recommendations of the Panel

  20. Thermal fluctuation based study of aqueous deficient dry eyes by non-invasive thermal imaging.

    Science.gov (United States)

    Azharuddin, Mohammad; Bera, Sumanta Kr; Datta, Himadri; Dasgupta, Anjan Kr

    2014-03-01

    In this paper we have studied the thermal fluctuation patterns occurring at the ocular surface of the left and right eyes for aqueous deficient dry eye (ADDE) patients and control subjects by thermal imaging. We conducted our experiment on 42 patients (84 eyes) with aqueous deficient dry eyes and compared with 36 healthy volunteers (72 eyes) without any history of ocular surface disorder. Schirmer's test, Tear Break-up Time, tear Meniscus height and fluorescein staining tests were conducted. Ocular surface temperature measurement was done, using an FL-IR thermal camera and thermal fluctuation in left and right eyes was calculated and analyzed using MATLAB. The time series containing the sum of squares of the temperature fluctuation on the ocular surface were compared for aqueous deficient dry eye and control subjects. Significant statistical difference between the fluctuation patterns for control and ADDE was observed (p eyes are significantly correlated in controls but not in ADDE subjects. The possible origin of such correlation in control and lack of correlation in the ADDE subjects is discussed in the text. Copyright © 2014 Elsevier Ltd. All rights reserved.

  1. Study of thermal conductivity and thermal rectification in exponential mass graded lattices

    Energy Technology Data Exchange (ETDEWEB)

    Shah, Tejal N. [Bhavan' s Sheth R.A. College of Science, Khanpur, Ahmedabad 380 001, Gujarat (India); Gajjar, P.N., E-mail: pngajjar@rediffmail.com [Department of Physics, University School of Sciences, Gujarat University, Ahmedabad 380 009, Gujarat (India)

    2012-01-09

    Concept of exponential mass variation of oscillators along the chain length of N oscillators is proposed in the present Letter. The temperature profile and thermal conductivity of one-dimensional (1D) exponential mass graded harmonic and anharmonic lattices are studied on the basis of Fermi–Pasta–Ulam (FPU) β model. Present findings conclude that the exponential mass graded chain provide higher conductivity than that of linear mass graded chain. The exponential mass graded anharmonic chain generates the thermal rectification of 70–75% which is better than linear mass graded materials, so far. Thus instead of using linear mass graded material, the use of exponential mass graded material will be a better and genuine choice for controlling the heat flow at nano-scale. -- Highlights: ► In PRE 82 (2010) 040101, use of mass graded material as a thermal devices is explored. ► Concept of exponential mass graded material is proposed. ► The rectification obtained is about 70–75% which is better than linear mass graded materials. ► The exponential mass graded material will be a better choice for the thermal devices at nano-scale.

  2. Heat exchange studies on coconut oil cells as thermal energy storage for room thermal conditioning

    Science.gov (United States)

    Sutjahja, I. M.; Putri, Widya A.; Fahmi, Z.; Wonorahardjo, S.; Kurnia, D.

    2017-07-01

    As reported by many thermal environment experts, room air conditioning might be controlled by thermal mass system. In this paper we discuss the performance of coconut oil cells as room thermal energy storage. The heat exchange mechanism of coconut oil (CO) which is one of potential organic Phase Change Material (PCM) is studied based on the results of temperature measurements in the perimeter and core parts of cells. We found that the heat exchange performance, i.e. heat absorption and heat release processes of CO cells are dominated by heat conduction in the sensible solid from the higher temperature perimeter part to the lower temperature core part and heat convection during the solid-liquid phase transition and sensible liquid phase. The capability of heat absorption as measured by the reduction of air temperature is not influenced by CO cell size. Besides that, the application of CO as the thermal mass has to be accompanied by air circulation to get the cool sensation of the room’s occupants.

  3. Effect of gamma irradiation on mechanical, thermal and rheological behavior of HDPE filled with seaweed residues

    International Nuclear Information System (INIS)

    Catano, L.; Albano, C.; Karam, A.; Dominguez, N.; Sanchez, Y.; Gonzalez, J.

    2005-01-01

    The present work shows the results obtained during the investigation of the influence of gamma irradiation on mechanical, thermal and rheological properties of high-density polyethylene (HDPE) filled with seaweed residues (SR). The SR used was located on Venezuelan coastlines and they are composed mainly by CaCO 3 in aragonite phase. The HDPE was extruded along with the filler at different compositions (20, 30 and 40 wt.%). The composites were exposed to a 60 Co source irradiated at 25 and 100 kGy. From the obtained results, it was noticed that Young modulus remained constant with filler content. Moreover, the influence of filler content was found to be more prominent on properties like tensile stress and elongation at break. On the other hand, thermal analysis showed that filler content had no significant influence on thermal stability. Still, it is necessary to point out that low radiation doses improved thermal stability of the composites. From rheological studies it was observed a decreasing of melt flow index (MFI) by increasing the SR amount and radiation. Therefore, was determinate that high filler content composites are the best choice to be considered for biomedical and industrial applications

  4. Kinetic Monte Carlo study on the evolution of silicon surface roughness under hydrogen thermal treatment

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Gang; Wang, Yu; Wang, Junzhuan; Pan, Lijia; Yu, Linwei; Zheng, Youdou; Shi, Yi, E-mail: yshi@nju.edu.cn

    2017-08-31

    Highlights: • The KMC method is adopted to investigate the relationships between surface evolution and hydrogen thermal treatment conditions. • The reduction in surface roughness is divided into two stages at relatively low temperatures, both exhibiting exponential dependence on the time. • The optimized surface structure can be obtained by precisely adjusting thermal treatment temperatures and hydrogen pressures. - Abstract: The evolution of a two-dimensional silicon surface under hydrogen thermal treatment is studied by kinetic Monte Carlo simulations, focusing on the dependence of the migration behaviors of surface atoms on both the temperature and hydrogen pressure. We adopt different activation energies to analyze the influence of hydrogen pressure on the evolution of surface morphology at high temperatures. The reduction in surface roughness is divided into two stages, both exhibiting exponential dependence on the equilibrium time. Our results indicate that a high hydrogen pressure is conducive to obtaining optimized surfaces, as a strategy in the applications of three-dimensional devices.

  5. Effects of thermal aging on the mechanical behavior of F82H weldments

    International Nuclear Information System (INIS)

    Alamo, A.; Castaing, A.; Fontes, A.; Wident, P.

    2000-01-01

    The objective of this work is to characterize the mechanical behavior of F82H weldments, which were produced by tungsten inert gas (TIG) and electron beam (EB) processes. Tensile and impact properties were determined for both types of welds in the as-received condition and after thermal aging for 10 000 h at 400 deg. C and 550 deg. C. The mechanical properties of TIG welds and their evolution during aging is quite similar in the base metal (BM). The main difference was given by the impact energy level (upper shelf energy (USE)) of TIG joints, which is about 60% of the BM. EB welds were delivered without post-weld heat treatment. Very scattered results were obtained, particularly for impact properties

  6. Co-planar deformation and thermal propagation behavior in a bundle burst test

    International Nuclear Information System (INIS)

    Uetsuka, Hiroshi; Koizumi, Yasuo; Kawasaki, Satoru

    1980-07-01

    The probability of the suggested feedback mechanism which could lead to co-planar deformation in a bundle burst test was assessed by the data of test and the calculation based on simplified model. Following four points were evaluated. (1) The probability of local deformation during early heat up stage. (2) The relation between the characteristic of heater and the feedback mechanism. (3) Thermal propagation behavior between two adjacent rods during heat up stage. (4) The propagation of ballooning in a bundle. The probability of suggested feedback mechanism was denied in all the evaluation. The feedback mechanism suggested by Burman could not be a controlling mechanism in co-planar deformation in a bundle burst test. (author)

  7. Numerical investigation on thermal and fluid dynamic behaviors of solar chimney building systems

    International Nuclear Information System (INIS)

    Manca, O.; Nardini, S.; Romano, P.; Mihailov, E.

    2013-01-01

    Full text: Buildings as big energy-consuming systems require large amount of energy to operate. Globally, buildings are responsible for approximately 40% of total world annual energy consumption. Sustainable buildings with renewable energy systems are trying to operate independently without consumption of conventional resources. Renewable energy is a significant approach to reduce resource consumption in sustainable building. A solar chimney is essentially divided into two parts, one - the solar air heater (collector) and second - the chimney. Two configurations of solar chimney are usually used: vertical solar chimney with vertical absorber geometry, and roof solar chimney. For vertical solar chimney, vertical glass is used to gain solar heat. Designing a solar chimney includes height, width and depth of cavity, type of glazing, type of absorber, and inclusion of insulation or thermal mass. Besides these system parameters, other factors such as the location, climate, and orientation can also affect its performance. In this paper a numerical investigation on a prototypal solar chimney system integrated in a south facade of a building is presented. The analysis is carried out on a three-dimensional model in air flow and the governing equations are given in terms of k-s turbulence model. Two geometrical configurations are investigated: 1) a channel with vertical parallel walls and 2) a channel with principal walls one vertical and the other inclined. The problem is solved by means of the commercial code Ansys-Fluent and the results are performed for a uniform wall heat flux on the vertical wall is equal to 300 and 600 W/m2. Results are given in terms of wall temperature distributions, air velocity and temperature fields and transversal profiles in order to evaluate the differences between the two base configurations and thermal and fluid dynamic behaviors. Further, the ground effect on thermal performances is examined. key words: mathematical modeling, solar chimney

  8. Fracture mechanics analysis of reactor pressure vessel under pressurized thermal shock - The effect of elastic-plastic behavior and stainless steel cladding -

    International Nuclear Information System (INIS)

    Joo, Jae Hwang; Kang, Ki Ju; Jhung, Myung Jo

    2002-01-01

    Performed here is an assessment study for deterministic fracture mechanics analysis of a pressurized thermal shock (PTS). The PTS event means an event or transient in pressurized water reactors (PWRs) causing severe overcooling (thermal shock) concurrent with or followed by significant pressure in the reactor vessel. The problems consisting of two transients and 10 cracks are solved and maximum stress intensity factors and maximum allowable nil-ductility reference temperatures are calculated. Their results are compared each other to address the general characteristics between transients, crack types and analysis methods. The effects of elastic-plastic material behavior and clad coating on the inner surface are explored

  9. Numerical Methods for an Analysis of Hydrogen Behaviors Coupled with Thermal Hydraulics in a NPP Containment

    International Nuclear Information System (INIS)

    Kim, Jongtae; Park, Rae-Joon; Hong, Seong-Wan; Kim, Gun-Hong

    2016-01-01

    In a containment safety analysis, multi-dimensional characteristics in thermal hydraulics are very important because the flow paths are not confined in a large free volume of the containment. The analysis is difficult because of a difference in length scales between a characteristic length of the flow and representative length of the containment. In order to simulate hydrogen and steam behaviors in a containment during postulated severe accidents, the GASFLOW code as a multi-dimensional analysis tool for NPP containment has been used for years because of its computational efficiency. Though GASFLOW is well developed for a real NPP containment analysis, there exist shortcomings in nodalization, two-phase and turbulence models. It is based on a Cartesian or cylindrical coordinate mesh, so it is impractical to refine a mesh locally in a region with a physical or geometrical complication. In this paper, the importance of the hydrogen safety in an NPP containment and requirements of the analysis tool was described. And physical models necessary for the hydrogen safety analysis code were listed. As a member of international collaborative project HYMERES for containment thermal hydraulics, KAERI is actively participating in an analytic working group. As an analysis tool for blind benchmarkes, the analysis code described in this paper was used. From the blind benchmark analyses, it was found that the code is very promising for hydrogen safety analysis. Currently, it is proposed to develop the code collaboratively in a hydrogen safety community based on an open-source strategy

  10. Numerical Methods for an Analysis of Hydrogen Behaviors Coupled with Thermal Hydraulics in a NPP Containment

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jongtae; Park, Rae-Joon; Hong, Seong-Wan; Kim, Gun-Hong [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2016-10-15

    In a containment safety analysis, multi-dimensional characteristics in thermal hydraulics are very important because the flow paths are not confined in a large free volume of the containment. The analysis is difficult because of a difference in length scales between a characteristic length of the flow and representative length of the containment. In order to simulate hydrogen and steam behaviors in a containment during postulated severe accidents, the GASFLOW code as a multi-dimensional analysis tool for NPP containment has been used for years because of its computational efficiency. Though GASFLOW is well developed for a real NPP containment analysis, there exist shortcomings in nodalization, two-phase and turbulence models. It is based on a Cartesian or cylindrical coordinate mesh, so it is impractical to refine a mesh locally in a region with a physical or geometrical complication. In this paper, the importance of the hydrogen safety in an NPP containment and requirements of the analysis tool was described. And physical models necessary for the hydrogen safety analysis code were listed. As a member of international collaborative project HYMERES for containment thermal hydraulics, KAERI is actively participating in an analytic working group. As an analysis tool for blind benchmarkes, the analysis code described in this paper was used. From the blind benchmark analyses, it was found that the code is very promising for hydrogen safety analysis. Currently, it is proposed to develop the code collaboratively in a hydrogen safety community based on an open-source strategy.

  11. Thermal and mechanical behavior of APWR-claddings under critical heat flux conditions

    International Nuclear Information System (INIS)

    Diegele, E.; Rust, K.

    1986-10-01

    Helical grid spacers, such as three or six helical fins as integral part of the claddings, are regarded as a more convenient design for the very tight lattice of an advanced pressurized water reactor (APWR) than grid spacers usually used. Furthermore, it is expected that this spacer design allows an increased safety margin against the critical heat flux (CHF), the knowledge of which is important for design, licensing, and operation of water cooled reactors. To address the distribution of the heat flux density at the outer circumference of the cladding geometry under investigation, the temperature fields in claddings without as well with fins were calculated taking into consideration nuclear and electrically heated rods. Besides the thermal behavior of the claddings, the magnitude and distribution of thermal stresses were determined additionally. A locally increased surface heat flux up to about 40 percent was calculated for the fin bases of nuclear as well as indirect electrically heated claddings with six such helical fins. For all investigated cases, the VON MISES stresses are clearly lower than 200 MPa, implying that no plastic deformations are to be expected. The aim of this theoretical analysis is to allow a qualitative assessment of the finned tube conception and to support experimental investigations concerning the critical heat flux. (orig.) [de

  12. Review of the integrated thermal and nonthermal treatment system studies

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-08-01

    This report contains a review and evaluation of three systems analysis studies performed by LITCO on integrated thermal treatment systems and integrated nonthermal treatment systems for the remediation of mixed low-level waste stored throughout the US Department of Energy weapons complex. The review was performed by an independent team of nine researchers from the Energy and Environmental Research Center, Science Applications International Corporation, the Waste Policy Institute, and Virginia Tech. The three studies reviewed were as follows: Integrated Thermal Treatment System Study, Phase 1--issued July 1994; Integrated Thermal Treatment System Study, Phase 2--issued February 1996; and Integrated Nonthermal Treatment System Study--drafted March 1996. The purpose of this review was to (1) determine whether the assumptions of the studies were adequate to produce an unbiased review of both thermal and nonthermal systems, (2) to identify the critical areas of the studies that would benefit from further investigation, and (3) to develop a standard template that could be used in future studies to assure a sound application of systems engineering.

  13. Review of the integrated thermal and nonthermal treatment system studies

    Energy Technology Data Exchange (ETDEWEB)

    Durrani, H.A.; Schmidt, L.J.; Erickson, T.A.; Sondreal, E.A.; Erjavec, J.; Steadman, E.N.; Fabrycky, W.J.; Wilson, J.S.; Musich, M.A.

    1996-07-01

    This report analyzes three systems engineering (SE) studies performed on integrated thermal treatment systems (ITTSs) and integrated nonthermal treatment systems (INTSs) for the remediation of mixed low-level waste (MLLW) stored throughout the US Department of Energy (DOE) weapons complex. The review was performed by an independent team of nine researchers from the Energy and Environmental Research Center (EERC), Science Applications International Corporation (SAIC), the Waste Policy Institute (WPI), and Virginia Tech (VT). The three studies reviewed were as follows: Integrated Thermal Treatment System Study, Phase 1--issued July 1994; Integrated Thermal Treatment System Study, Phase 2--issued February 1996; and Integrated Nonthermal Treatment System Study--drafted March 1996. The purpose of this review was to (1) determine whether the assumptions taken in the studies might bias the resulting economic evaluations of both thermal and nonthermal systems, (2) identify the critical areas of the studies that would benefit from further investigation, and (3) develop a standard template that could be used in future studies to produce sound SE applications.

  14. Moessbauer thermal scan study of a spin crossover system

    Energy Technology Data Exchange (ETDEWEB)

    Zelis, P Mendoza; Pasquevich, G A; Sanchez, F H; Veiga, A; Cabrera, A F [Departamento de Fisica, FCE-UNLP, La Plata (Argentina); Ceolin, M [Instituto de Investigaciones FIsico-Quimicas Teoricas y Aplicadas (UNLP-CONICET), La Plata (Argentina); Coronado-Miralles, E; Monrabal-Capilla, M; Galan-Mascaros, J R, E-mail: pmendoza@fisica.unlp.edu.a [Instituto de Ciencias Moleculares, Universidad de Valencia, Valencia (Spain)

    2010-03-01

    Programmable Velocity equipment was used to perform a Moessbauer Thermal Scans to allow a quasi-continuous temperature study of the magnetic transition between the low-spin and a high-spin configurations in [Fe(Htrz){sub 2}(trz)](BF4) system. The material was studied both in bulk as in nanoparticles sample forms.

  15. Review of the integrated thermal and nonthermal treatment system studies

    International Nuclear Information System (INIS)

    1996-08-01

    This report contains a review and evaluation of three systems analysis studies performed by LITCO on integrated thermal treatment systems and integrated nonthermal treatment systems for the remediation of mixed low-level waste stored throughout the US Department of Energy weapons complex. The review was performed by an independent team of nine researchers from the Energy and Environmental Research Center, Science Applications International Corporation, the Waste Policy Institute, and Virginia Tech. The three studies reviewed were as follows: Integrated Thermal Treatment System Study, Phase 1--issued July 1994; Integrated Thermal Treatment System Study, Phase 2--issued February 1996; and Integrated Nonthermal Treatment System Study--drafted March 1996. The purpose of this review was to (1) determine whether the assumptions of the studies were adequate to produce an unbiased review of both thermal and nonthermal systems, (2) to identify the critical areas of the studies that would benefit from further investigation, and (3) to develop a standard template that could be used in future studies to assure a sound application of systems engineering

  16. Thermal, mechanical and morphological behavior of starch thermoplastic (TPS) and polycaprolactone (PCL)

    International Nuclear Information System (INIS)

    Campos, Adriana de; Marconcini, Jose M.; Mattoso, Luiz H.C.

    2011-01-01

    Thermal, mechanical and morphological properties of thermoplastic starch (TPS) and polycaprolactone (PCL) blend obtained by extrusion was studied. The results showed that TPS/PCL blends are immiscible, however it is suggested some interaction in the interphase between TPS and PCL as observed by crystallinity decrease of the blend. The PCL addition in the TPS improves the properties and decreases the cost of the blend. (author)

  17. Comparative performance study of smart structure for thermal microactuators

    Science.gov (United States)

    Yahya, Zulkarnain; Johar, Muhammad Akmal

    2017-04-01

    Thermal microactuator is one of earliest types of microactuators. Typical thermal actuators are in the form of Bimorph and Chevron structures. A bimorph thermal actuator has a complex movement direction, in arc motion and thus it is not feasible in the most MEMS designs. While Chevron actuator has a tendency to produce an off-plane movement which lead to low precision in lateral movement. A new thermal actuator design in the form of serpentine structures shows promising feature to have better performances in terms of more predictive lateral movement with smaller off-plane displacement. In MEMS chip design, areas play a critical role as it will impact with the cost of the final product. In this study, four different structures of thermal actuator were simulated using ANSYS v15. Three different set of area sizes which are 240 µm x 1000 µm, 240 µm x 1500 µm and 240 µm x 2000 µm have been analyzed. All four structures were named as Serpentine01, Serpentine02, Bimorph and Chevron. The data with regards to temperature produced by the structure and z-axis directional deformation were collected and analyzed. This paper reported the investigation result of comparison between these three types of thermal actuator structures design with a given area. From all of the result obtained, it is shown that the area 240 µm x 1500 µm showed a well balance performance in term of huge deformations and low power consumption. The Serpentine01 structure produced 16.7 µm deformation at 4mA of current. The results shows the potential of Serpentine01 structure as a new candidate for thermal microactuator for MEMS applications.

  18. Thermal comfort study of hospital workers in Malaysia.

    Science.gov (United States)

    Yau, Y H; Chew, B T

    2009-12-01

    This article presents findings of the thermal comfort study in hospitals. A field survey was conducted to investigate the temperature range for thermal comfort in hospitals in the tropics. Thermal acceptability assessment was conducted to examine whether the hospitals in the tropics met the ASHRAE Standard-55 80% acceptability criteria. A total of 114 occupants in four hospitals were involved in the study. The results of the field study revealed that only 44% of the examined locations met the comfort criteria specified in ASHRAE Standard 55. The survey also examined the predicted percentage of dissatisfied in the hospitals. The results showed that 49% of the occupants were satisfied with the thermal environments in the hospitals. The field survey analysis revealed that the neutral temperature for Malaysian hospitals was 26.4 degrees C. The comfort temperature range that satisfied 90% of the occupants in the space was in the range of 25.3-28.2 degrees C. The results from the field study suggested that a higher comfort temperature was required for Malaysians in hospital environments compared with the temperature criteria specified in ASHRAE Standard (2003). In addition, the significant deviation between actual mean vote and predicted mean vote (PMV) strongly implied that PMV could not be applied without errors in hospitals in the tropics. The new findings on thermal comfort temperature range in hospitals in the tropics could be used as an important guide for building services engineers and researchers who are intending to minimize energy usage in heating, ventilating and air conditioning systems in hospitals operating in the tropics with acceptable thermal comfort level and to improve the performance and well-being of its workers.

  19. Synthesis, thermal behavior and thermoelectric properties of disordered tellurides with structures derived from the rocksalt type

    Energy Technology Data Exchange (ETDEWEB)

    Schroeder, Thorsten

    2014-06-17

    GeBi{sub 2}Te{sub 4} is proposed as phase-change material. Nanostructures in metastable GeBi{sub 2}Te{sub 4} were obtained by high-pressure synthesis and thermal quenching, - depending on temperature and pressure different modifications were found. The differences in the electrical characteristics can be attributed to the variation of grain boundary concentration and the grain size distribution. Two synthesis approaches were used to prepare Ag{sub 3.4}In{sub 3.7}Sb{sub 76.4}Te{sub 16.5} bulk samples and studied with respect to their transport and thermal properties. A high pressure route to prepare thermoelectrics with low thermal conductivity was developed for AgIn{sub x}Sb{sub 1-x}Te{sub 2}. Disorder and and transport studies on In{sub 3}SbTe{sub 2} were performed using X-ray, neutron and electron diffraction measurements. Nanostructures in Te/Sb/Ge/Ag (TAGS) thermoelectric materials were induced by phase transitions associated with vacancy ordering. Further studies concerned solid solution series (GeTe){sub x}(LiSbTe{sub 2}){sub 2} (1 smaller or equal x smaller or equal 11) and their thermoelectric properties.

  20. Environmental/Thermal Barrier Coatings for Ceramic Matrix Composites: Thermal Tradeoff Studies

    Science.gov (United States)

    Murthy, Pappu L. M.; Brewer, David; Shah, Ashwin R.

    2007-01-01

    Recent interest in environmental/thermal barrier coatings (EBC/TBCs) has prompted research to develop life-prediction methodologies for the coating systems of advanced high-temperature ceramic matrix composites (CMCs). Heat-transfer analysis of EBC/TBCs for CMCs is an essential part of the effort. It helps establish the resulting thermal profile through the thickness of the CMC that is protected by the EBC/TBC system. This report documents the results of a one-dimensional analysis of an advanced high-temperature CMC system protected with an EBC/TBC system. The one-dimensional analysis was used for tradeoff studies involving parametric variation of the conductivity; the thickness of the EBC/TBCs, bond coat, and CMC substrate; and the cooling requirements. The insight gained from the results will be used to configure a viable EBC/TBC system for CMC liners that meet the desired hot surface, cold surface, and substrate temperature requirements.

  1. Effect of cuprous oxide with different sizes on thermal and combustion behaviors of unsaturated polyester resin.

    Science.gov (United States)

    Hou, Yanbei; Hu, Weizhao; Gui, Zhou; Hu, Yuan

    2017-07-15

    Cuprous oxide (Cu 2 O) as an effective catalyst has been applied to enhance the fire safety of unsaturated polyester resin (UPR), but the particle size influence on combustion behaviors has not been previously reported. Herein, the UPR/Cu 2 O composites (metal oxide particles with average particle-size of 10, 100, and 200nm) were successfully synthesized by thermosetting process. The effects of Cu 2 O with different sizes on thermostability and combustion behaviors of UPR were characterized by TGA, MCC, TG-IR, FTIR, and SSTF. The results revel that the addition of Cu 2 O contributes to sufficient decomposition of oxygen-containing compounds, which is beneficial to the release of nontoxic compounds. The smallest-sized Cu 2 O performs the excellent catalytic decomposition effect and promotes the complete combustion of UPR, which benefits the enhancement of fire safety. While the other additives retard pyrolysis process and yield more char residue, and thus the flame retardancy of UPR composites was improved. Therefore, catalysis plays a major role for smaller-sized particles during thermal decomposition of matrix, while flame retarded effect became gradual distinctly for the larger-sized additives. Copyright © 2017 Elsevier B.V. All rights reserved.

  2. COBRA/TRAC analysis of two-dimensional thermal-hydraulic behavior in SCTF reflood tests

    International Nuclear Information System (INIS)

    Iwamura, Takamichi; Ohnuki, Akira; Sobajima, Makoto; Adachi, Hiromichi

    1987-01-01

    The effects of radial power distribution and non-uniform upper plenum water accumulation on thermal-hydraulic behavior in the core were observed in the reflood tests with Slab Core Test Facility (SCTF). In order to examine the predictability of these two effects by a multi-dimensional analysis code, the COBRA/TRAC calculations were made. The calculated results indicated that the heat transfer enhancement in high power bundles above quench front was caused by high vapor flow rate in those bundles due to the radial power distribution. On the other hand, the heat transfer degradation in the peripheral bundles under the condition of non-uniform upper plenum water accumulation was caused by the lower flow rates of vapor and entrained liquid above the quench front in those bundles by the reason that vapor concentrated in the center bundles due to the cross flow induced by the horizontal pressure gradient in the core. The above-mentioned two-dimensional heat transfer behaviors calculated with the COBRA/TRAC code is similar to those observed in SCTF tests and therefore those calculations are useful to investigate the mechanism of the two-dimensional effects in SCTF reflood tests. (author)

  3. Thermalization of positronium in helium: A numerical study

    Energy Technology Data Exchange (ETDEWEB)

    Marjanovic, S.; Suvakov, M. [Institute of Physics, University of Belgrade, Pregrevica 118, 11080 Belgrade (Serbia); Engbrecht, J.J. [Saint Olaf College, Northfield, MN 55057 (United States); Petrovic, Z.Lj., E-mail: zoran@ipb.ac.rs [Institute of Physics, University of Belgrade, Pregrevica 118, 11080 Belgrade (Serbia)

    2012-05-15

    In this paper we present a numerical study of positronium (Ps) thermalization in pure helium (He). Recent measurements of Ps thermalization yielded data that were analyzed to produce the scattering cross-sections in helium by using energy balance equations with an assumption of a Maxwell-Boltzmann distribution (MBD) function for Ps. We have applied a Monte Carlo code to test the cross-sections. As our code was developed without any approximations for the energy distribution function we have effectively also tested the assumptions and the validity of the simple theory based on Maxwellian distributions. We present the simulation results using the simulation technique that is limited only by the accuracy of the available cross-sections. We calculate thermalization profiles for several theoretical and measured cross-sections. Also, the temporal evolution of energy distributions has been shown along with diffusion coefficients and spatial ranges of penetration. Thermalization of the initial distribution is rapid and the data follow relatively closely, those calculated in recent experiment, which supports the choice of MBD and the obtained cross-section. However the distribution function most of the time deviates from the MBD due to strong scattering. Finally, we applied the same procedure to analyze Ps thermalization in water vapor.

  4. Thermal decomposition studies of aqueous and nitric solutions of hydroxyurea

    International Nuclear Information System (INIS)

    Shekhar Kumar; Pranay Kumar Sinha; Kamachi Mudali, U.; Natarajan, R.

    2012-01-01

    Hydroxyurea and its derivatives are important nonsalt forming reductants in partitioning of uranium and plutonium in the nuclear fuel reprocessing operations. There is no experimental data available in open literature describing pressurization due to the thermal decomposition of aqueous and nitric solutions of hydroxyurea at elevated temperatures. Authors studied thermal decomposition of hydroxyurea-nitric acid system and resultant pressurization at various concentrations of nitric acid in an adiabatic calorimeter in closed-vent conditions. During these experiments, pressurization was observed. In this paper, results of these experiments have been discussed. (author)

  5. Uranyl soaps - thermal, electronic and infrared spectral study

    International Nuclear Information System (INIS)

    Solanki, A.K.; Bhandari, A.M.

    1981-01-01

    The electronic and infrared spectra and TGA thermogram of uranyl soaps (laurate, mystrate, palmitate and stearate) have been studied. The environment about the UO 2+ 2 ion would comprise two 'short bite' bidentate carboxylate groups and oxygen atoms bridging from adjacent carboxylic molecules. The uranyl soaps have UO 2+ 2 vibronic absorption (approx. equal to 22730 cm -1 ) in the range found for eight coordinate uranyl complexes. The greater resistance to thermal degradation (approx. equal to 300 0 C) of these soaps and their stepwise thermal degradation infer strong metal-ligand interaction. (orig.) [de

  6. Thermal decomposition study of manganese sulfide (MnS) nanoparticles

    Science.gov (United States)

    Tailor, Jiten P.; Khimani, Ankurkumar J.; Chaki, Sunil H.; Deshpande, M. P.

    2018-05-01

    The as-synthesized manganese sulfide (MnS) nanoparticles were used for the thermal study. The nanoparticles were synthesized by simple wet chemical route at ambient temperature. The photoelectron binding energy and chemical composition of MnS nanoparticles was analyzed by X-ray photoelectron spectroscopy (XPS). The thermogravimetric (TG), differential thermogravimetric (DTG) and differential thermal analysis (DTA) were carried out on the as-synthesized MnS nanoparticles. The thermocurves were recorded in inert N2 atmosphere in the temperature range of ambient to 1173 K. The heating rates employed were 5, 10, 15 and 20 K/min. The thermodynamic parameters like activation energy (Ea), enthalpy change (ΔH), entropy change (ΔS) and change in Gibbs free energy (ΔG) of as-synthesized MnS nanoparticles were determined using Kissinger method. The obtained XPS and thermal results are discussed.

  7. Positron annihilation studies on reactor irradiated and thermal annealed ferrocene

    International Nuclear Information System (INIS)

    Marques Netto, A.; Carvalho, R.S.; Magalhaes, W.F.; Sinisterra, R.D.

    1996-01-01

    Retention and thermal annealing following (n, γ) reaction in solid ferrocene, Fe(C 5 H 5 ) 2 , were studied by positron annihilation lifetime spectroscopy (PAL). Positronium (Ps) formation was observed in the non-irradiated compound with a probability or intensity (I 3 ) of 30%. Upon irradiation of the compound with thermal neutrons in a nuclear reactor, I 3 decreases with increasing irradiation time. Thermal treatment again increases I 3 values from 16% to 25%, revealing an important proportion of molecular reformation without variation of the ortho-positronium lifetime (τ 3 ). These results point out the major influence of the electronic structure as determining the Ps yields in the pure complex. In the irradiated and non irradiated complexes the results are satisfactorily explained on the basis of the spur model. (orig.)

  8. Thermal behavior and densification mechanism during selective laser melting of copper matrix composites: Simulation and experiments

    International Nuclear Information System (INIS)

    Dai, Donghua; Gu, Dongdong

    2014-01-01

    Highlights: • Thermal behavior and densification activity during SLM of composites are simulated. • Temperature distributions and melt pool dimensions during SLM are disclosed. • Motion behaviors of gaseous bubbles in laser induced melt pool are elucidated. • Simulation results show good agreement with the obtained experimental results. - Abstract: Simulation of temperature distribution and densification process of selective laser melting (SLM) WC/Cu composite powder system has been performed, using a finite volume method (FVM). The transition from powder to solid, the surface tension induced by temperature gradient, and the movement of laser beam power with a Gaussian energy distribution are taken into account in the physical model. The effect of the applied linear energy density (LED) on the temperature distribution, melt pool dimensions, behaviors of gaseous bubbles and resultant densification activity has been investigated. It shows that the temperature distribution is asymmetric with respect to the laser beam scanning area. The center of the melt pool does not locate at the center of the laser beam but slightly shifts towards the side of the decreasing X-axis. The dimensions of the melt pool are in sizes of hundreds of micrometers and increase with the applied LED. For an optimized LED of 17.5 kJ/m, an enhanced efficiency of gas removal from the melt pool is realized, and the maximum relative density of laser processed powder reaches 96%. As the applied LED surpasses 20 kJ/m, Marangoni flow tends to retain the entrapped gas bubbles. The flow pattern has a tendency to deposit the gas bubbles at the melt pool bottom or to agglomerate gas bubbles by the rotating flow in the melt pool, resulting in a higher porosity in laser processed powder. The relative density and corresponding pore size and morphology are experimentally acquired, which are in a good agreement with the results predicted by simulation

  9. Thermal behavior of potato starch and water-vaporization behavior of its paste controlled with amino acid and peptide-rich food materials.

    Science.gov (United States)

    Sakauchi, Satoshi; Hattori, Makoto; Yoshida, Tadashi; Yagishita, Takahiro; Ito, Koichi; Akemitsu, Shin-Ichi; Takahashi, Koji

    2010-03-01

    The particular effect of 4 kinds of amino acid and peptide-rich food material (APRM) containing different charged amino acid contents on the gelatinization and retrogradation behavior of potato starch granules and on the water-vaporization behavior was analyzed by differential scanning calorimetry, rapid viscoanalysis, x-ray diffractometry, thermal gravimetry-differential thermal analysis, and pulsed NMR. APRM with a high-charged amino acid content produced unique gelatinization and retrogradation behavior in terms of an elevated gelatinization temperature, reduced viscosity, higher setback, and lower retrograded starch melting enthalpy. The recovered x-ray diffraction intensity decreased with increasing charged amino acid content. APRM with high-charged amino acid content could provide an improved paste having easy vaporization of external water in the swollen starch granules due to the reduced swelling.

  10. Dielectric and thermal studies on gel grown strontium tartrate ...

    Indian Academy of Sciences (India)

    Administrator

    frequencies (110–700 kHz) of the applied a.c. field. It increases ... lytical studies. It is explained that crystallographic change due to polymorphic phase transition may be occur- ... inexpensive and unique method for growing crystals that show poor ... on dielectric and thermal characteristics of this material are described. 2.

  11. Comparative study of thermal insulation boards from leaf and bark ...

    African Journals Online (AJOL)

    Thus, several researches have succeeded in using these plants and agro waste fibres in developing renewable and environmentally friendly thermal insulation products. The aim of this study was to compare the performance of insulation boards made from leave and bark fibres of Pilios tigma thonningii L.in terms of density, ...

  12. Synthesis of poly(ethylene furandicarboxylate) polyester using monomers derived from renewable resources: thermal behavior comparison with PET and PEN.

    Science.gov (United States)

    Papageorgiou, George Z; Tsanaktsis, Vasilios; Bikiaris, Dimitrios N

    2014-05-07

    Poly(ethylene-2,5-furandicarboxylate) (PEF) is a new alipharomatic polyester that can be prepared from monomers derived from renewable resources like furfural and hydroxymethylfurfural. For this reason it has gained high interest recently. In the present work it was synthesized from the dimethylester of 2,5-furandicarboxylic acid and ethylene glycol by applying the two-stage melt polycondensation method. The thermal behavior of PEF was studied in comparison to its terephthalate and naphthalate homologues poly(ethylene terephthalate) (PET) and poly(ethylene naphthalate) (PEN), which were also synthesized following the same procedure. The equilibrium melting point of PEF was found to be 265 °C while the heat of fusion for the pure crystalline PEF was estimated to be about 137 J g(-1). The crystallization kinetics was analyzed using various models. PET showed faster crystallization rates than PEN and this in turn showed faster crystallization than PEF, under both isothermal and non-isothermal conditions. The spherulitic morphology of PEF during isothermal crystallization was investigated by polarized light microscopy (PLM). A large nucleation density and a small spherulite size were observed for PEF even at low supercoolings, in contrast to PET or PEN. Thermogravimetric analysis indicated that PEF is thermally stable up to 325 °C and the temperature for the maximum degradation rate was 438 °C. These values were a little lower than those for PET or PEN.

  13. Thermal annealing behavior of niobium-implanted {alpha}-Al{sub 2}O{sub 3} under reducing environment

    Energy Technology Data Exchange (ETDEWEB)

    Jianer, Zeng; Naramoto, Hiroshi; Aoki, Yasushi; Yamamoto, Shunya; Mingle, Gan; Takeshita, Hidefumi [Japan Atomic Energy Research Inst., Takasaki, Gunma (Japan). Takasaki Radiation Chemistry Research Establishment

    1997-03-01

    Thermal annealing behavior is studied in {alpha}-Al{sub 2}O{sub 3} implanted with {sup 93}Nb{sup +} using RBS/channeling technique and optical absorption spectrometry. The samples with <0001> and <112-bar0> orientations are implanted with 300 keV and 400 keV {sup 93}Nb{sup +} ions. Thermal annealing under reducing environment (Ar+3%H{sub 2}) is employed in the temperature range from 600 to 1000degC to explore unusual materials phase. The annealing up to 1000degC for an hour does not show any essential change in RBS/channeling spectra in two kinds of samples but the significant decrease in the visible region is observed in optical absorption spectra. After annealing at 1000degC for 10 hours, the recovery of the lattice damage is detected by RBS/channeling analysis especially in (112-bar0) sample. In the optical absorption spectra, new absorption envelope appears in the ultraviolet region. The results are related to the formation of niobium metal fine particles, and the sharp distribution is realized especially in (0001) sample. (author)

  14. Neurogenetics of aggressive behavior: studies in rodents.

    Science.gov (United States)

    Takahashi, Aki; Miczek, Klaus A

    2014-01-01

    Aggressive behavior is observed in many animal species, such as insects, fish, lizards, frogs, and most mammals including humans. This wide range of conservation underscores the importance of aggressive behavior in the animals' survival and fitness, and the likely heritability of this behavior. Although typical patterns of aggressive behavior differ between species, there are several concordances in the neurobiology of aggression among rodents, primates, and humans. Studies with rodent models may eventually help us to understand the neurogenetic architecture of aggression in humans. However, it is important to recognize the difference between the ecological and ethological significance of aggressive behavior (species-typical aggression) and maladaptive violence (escalated aggression) when applying the findings of aggression research using animal models to human or veterinary medicine. Well-studied rodent models for aggressive behavior in the laboratory setting include the mouse (Mus musculus), rat (Rattus norvegicus), hamster (Mesocricetus auratus), and prairie vole (Microtus ochrogaster). The neural circuits of rodent aggression have been gradually elucidated by several techniques, e.g., immunohistochemistry of immediate-early gene (c-Fos) expression, intracranial drug microinjection, in vivo microdialysis, and optogenetics techniques. Also, evidence accumulated from the analysis of gene-knockout mice shows the involvement of several genes in aggression. Here, we review the brain circuits that have been implicated in aggression, such as the hypothalamus, prefrontal cortex (PFC), dorsal raphe nucleus (DRN), nucleus accumbens (NAc), and olfactory system. We then discuss the roles of glutamate and γ-aminobutyric acid (GABA), excitatory and inhibitory amino acids in the brain, as well as their receptors, in controlling aggressive behavior, focusing mainly on recent findings. At the end of this chapter, we discuss how genes can be identified that underlie individual

  15. Theoretical and Experimental Studies of Functionalized Carbon Nanotubes for Improved Thermal Conductivity

    Science.gov (United States)

    Kerr, Alexander; Burt, Timothy; Mullen, Kieran; Glatzhofer, Daniel; Houck, Matthew; Huang, Paul

    The use of carbon nanotubes (CNTs) to improve the thermal conductivity of composite materials is thwarted by their large thermal boundary resistance. We study how to overcome this Kapitza resistance by functionalizing CNTs with mixed molecular chains. Certain configurations of chains improve the transmission of thermal vibrations through our systems by decreasing phonon mismatch between the CNTs and their surrounding matrix. Through the calculation of vibrational normal modes and Green's functions, we develop a variety of computational metrics to compare the thermal conductivity (κ) of our systems. We show how different configurations of attached chains affect the samples' κ values by varying chain identity, chain length, number of chains, and heat driver behavior. We vary the parameters to maximize κ. To validate and optimize these metrics, we perform molecular dynamics simulations for comparison. We also present experimental results of composites enhanced with CNTs and make comparisons to the theory. We observe that some composites are thermally improved with the inclusion of CNTs, while others are scarcely changed, in agreement with theoretical models. This work was supported by NSF Grant DMR-1310407.

  16. Nanostructured complex oxides as a route towards thermal behavior in artificial spin ice systems

    Science.gov (United States)

    Chopdekar, R. V.; Li, B.; Wynn, T. A.; Lee, M. S.; Jia, Y.; Liu, Z. Q.; Biegalski, M. D.; Retterer, S. T.; Young, A. T.; Scholl, A.; Takamura, Y.

    2017-07-01

    We have used soft x-ray photoemission electron microscopy to image the magnetization of single-domain L a0.7S r0.3Mn O3 nanoislands arranged in geometrically frustrated configurations such as square ice and kagome ice geometries. Upon thermal randomization, ensembles of nanoislands with strong interisland magnetic coupling relax towards low-energy configurations. Statistical analysis shows that the likelihood of ensembles falling into low-energy configurations depends strongly on the annealing temperature. Annealing to just below the Curie temperature of the ferromagnetic film (TC=338 K ) allows for a much greater probability of achieving low-energy configurations as compared to annealing above the Curie temperature. At this thermally active temperature of 325 K, the ensemble of ferromagnetic nanoislands explore their energy landscape over time and eventually transition to lower energy states as compared to the frozen-in configurations obtained upon cooling from above the Curie temperature. Thus, this materials system allows for a facile method to systematically study thermal evolution of artificial spin ice arrays of nanoislands at temperatures modestly above room temperature.

  17. Design of performance and analysis of dynamic and transient thermal behaviors on the intermediate heat exchanger for HTGR

    International Nuclear Information System (INIS)

    Mori, Michitsugu; Mizuno, Minoru; Itoh, Mitsuyoshi; Urabe, Shigemi

    1985-01-01

    The intermediate heat exchanger (IHX) is designed as the high temperature heat exchanger for HTGR (High Temperature Gas-cooled Reactor), which transmits the primary coolant helium's heat raised up to about 950 0 C in the reactor core to the secondary helium or the nuclear heat utilization. Having to meet, in addition, the requirement of the primary coolant pressure boundary as the Class-1 component, it must be secured integrity throughout the service life. This paper will show (1) the design of the thermal performance; (2) the results of the dynamic analyses of the 1.5 MWt-IHX with its comparison to the experimental data; (3) the analytical predictions of the dynamic thermal behaviors under start-up and of the transient thermal behaviors during the accident on the 25 MWt-IHX. (author)

  18. Physical and thermal behavior of cement composites reinforced with recycled waste paper fibers

    Science.gov (United States)

    Hospodarova, Viola; Stevulova, Nadezda; Vaclavik, Vojtech; Dvorsky, Tomas

    2017-07-01

    In this study, three types of recycled waste paper fibers were used to manufacture cement composites reinforced with recycled cellulosic fibers. Waste cellulosic fibers in quantity of 0.2, 0.3, and 0.5 wt.% were added to cement mixtures. Physical properties such as density, water capillarity, water absorbability and thermal conductivity of fiber cement composites were studied after 28 days of hardening. However, durability of composites was tested after their water storage up to 90 days. Final results of tested properties of fiber cement composites were compared with cement reference sample without cellulosic fibers.

  19. Main factors of thermal fatigue failure induced by thermal striping and total simulation of thermal hydraulic and structural behaviors (research report)

    International Nuclear Information System (INIS)

    Kasahara, Naoto; Muramatsu, Toshiharu

    1999-01-01

    At incomplete mixing area of high temperature and low temperature fluids near the surface of structures, temperature fluctuation of fluid gives thermal fatigue damage to wall structures. This phenomenon is called thermal striping, which becomes sometimes a critical problem in LMFR plants. Since thermal striping phenomenon is characterized by the complex thermohydraulic and thermomechanical coupled problem, conventional evaluation procedures require mock-up experiments. In order to replace them by simulation-base methods, the authors have developed numerical simulation codes and applied them to analyze a tee junction of the PHENIX secondary circuit due to thermal striping phenomenon, in the framework of the IAEA coordinated research program (CRP). Through this analysis, thermohydraulic and thermomechanical mechanism of thermal striping phenomenon was clarified, and main factors on structural integrity was extracted in each stage of thermal striping phenomenon. Furthermore, simulation base evaluation methods were proposed taking above factors of structural integrity into account. Finally, R and D problems were investigated for future development of design evaluation methods. (author)

  20. Thermal fluid dynamic behavior of coolant helium gas in a typical reactor VHTGR channel of prismatic core

    International Nuclear Information System (INIS)

    Belo, Allan Cavalcante

    2016-01-01

    The current studies about the thermal fluid dynamic behavior of the VHTGR core reactors of 4 th generation are commonly developed in 3-D analysis in CFD (computational fluid dynamics), which often requires considerable time and complex mathematical calculations for carrying out these analysis. The purpose of this project is to achieve thermal fluid dynamic analysis of flow of gas helium refrigerant in a typical channel of VHTGR prismatic core reactor evaluating magnitudes of interest such as temperature, pressure and fluid velocity and temperature distribution in the wall of the coolant channel from the development of a computer code in MATLAB considering the flow on one-dimensional channel, thereby significantly reducing the processing time of calculations. The model uses three different references to the physical properties of helium: expressions given by the KTA (German committee of nuclear safety standards), the computational tool REFPROP and a set of constant values for the entire channel. With the use of these three references it is possible to simulate the flow treating the gas both compressible and incompressible. The results showed very close values for the interest quantities and revealed that there are no significant differences in the use of different references used in the project. Another important conclusion to be observed is the independence of helium in the gas compressibility effects on thermal fluid dynamic behavior. The study also indicated that the gas undergoes no severe effects due to high temperature variations in the channel, since this goes in the channel at 914 K and exits at approximately 1263 K, which shows the excellent use of helium as a refrigerant fluid in reactor channels VHTGR. The comparison of results obtained in this work with others in the literature served to confirm the effectiveness of the one-dimensional consideration of method of gas flow in the coolant channel to replace the models made in 3-D for the pressure range and

  1. Effect of milling time on the structure, micro-hardness, and thermal behavior of amorphous/nanocrystalline TiNiCu shape memory alloys developed by mechanical alloying

    International Nuclear Information System (INIS)

    Alijani, Fatemeh; Amini, Rasool; Ghaffari, Mohammad; Alizadeh, Morteza; Okyay, Ali Kemal

    2014-01-01

    Highlights: • Potential to produce B1′ (thermal- and stress-induced) and B2 was established. • Martensitic transformation occurred without the formation of intermediate R-phase. • Formation of unwanted intermetallics during heating was hindered by milling. • During milling, microhardness was increased, then reduced, and afterward re-increased. • By milling evolution, thermal crystallization steps changed from 3 to 2. - Abstract: In the present paper, the effect of milling process on the chemical composition, structure, microhardness, and thermal behavior of Ti–41Ni–9Cu compounds developed by mechanical alloying was evaluated. The structural characteristic of the alloyed powders was evaluated by X-ray diffraction (XRD). The chemical composition homogeneity and the powder morphology and size were studied by scanning electron microscopy coupled with electron dispersive X-ray spectroscopy. Moreover, the Vickers micro-indentation hardness of the powders milled for different milling times was determined. Finally, the thermal behavior of the as-milled powders was studie